WorldWideScience

Sample records for excess absorbed light

  1. Slow light in saturable absorbers

    OpenAIRE

    Macke, Bruno; Ségard, Bernard

    2008-01-01

    International audience; In connection with the experiments recently achieved on doped crystals, biological samples, doped optical fibers and semiconductor heterostructures, we revisit the theory of the propagation of a pulse-modulated light in a saturable absorber. Explicit analytical expressions of the transmitted pulse are obtained, enabling us to determine the parameters optimizing the time-delay of the transmitted pulse with respect to the incident pulse. We finally compare the maximum fr...

  2. Spectrophotometry of Thin Films of Light-Absorbing Particles.

    Science.gov (United States)

    Binks, Bernard P; Fletcher, Paul D I; Johnson, Andrew J; Marinopoulos, Ioannis; Crowther, Jonathan M; Thompson, Michael A

    2017-04-18

    Thin films of dispersions of light-absorbing solid particles or emulsions containing a light-absorbing solute all have a nonuniform distribution of light-absorbing species throughout the sample volume. This results in nonuniform light absorption over the illuminated area, which causes the optical absorbance, as measured using a conventional specular UV-vis spectrophotometer, to deviate from the Beer-Lambert relationship. We have developed a theoretical model to account for the absorbance properties of such films, which are shown to depend on the size and volume fraction of the light-absorbing particles plus other sample variables. We have compared model predictions with measured spectra for samples consisting of emulsions containing a dissolved light-absorbing solute. Using no adjustable parameters, the model successfully predicts the behavior of nonuniform, light-absorbing emulsion films with varying values of droplet size, volume fraction, and other parameters.

  3. Bridges, Lights, and Hubris: Examples of Excessive Light Pollution

    Science.gov (United States)

    Upgren, A. R.

    2000-12-01

    Recently many new lighting projects have been planned, frequently for the purpose of bringing attention to a tower or bridge, with the intent of promoting it as a tourist attraction. Examples of this form of light pollution are illustrated here. Many proceed with plans to mount new floodlights pointed upward with most of the light shining directly up into the sky. At least three of the more excessive among them have been tabled or aborted upon objections by members of the International Dark-Sky Association and other environmental groups. Opposition to the most ill-conceived of these plans centers on waste of money and energy, excessive fatalities among migratory birds, damage to the aesthetic beauty and study of the night sky, and (near seacoasts) damage to the nesting and hatching of sea turtles. Constructive opposition to lighting excess and glare may include the substitution of tracer lights, such as the ones that adorn the great suspension bridges of New York and San Francisco. Tracer lights using full-cutoff shielding outline a structure much as lights on a Christmas tree delineate its shape, but floodlights in the mix render a washed-out effect similar to a Christmas tree in broad daylight. The AAS Committee on Light Pollution, Radio Interference, and Space Debris encourages a greater role for the Society in coordinating opposition to such projects, which is too often local and inexperienced.

  4. Light absorbing carbon emissions from commercial shipping

    Science.gov (United States)

    Lack, Daniel; Lerner, Brian; Granier, Claire; Baynard, Tahllee; Lovejoy, Edward; Massoli, Paola; Ravishankara, A. R.; Williams, Eric

    2008-07-01

    Extensive measurements of the emission of light absorbing carbon aerosol (LAC) from commercial shipping are presented. Vessel emissions were sampled using a photoacoustic spectrometer in the Gulf of Mexico region. The highest emitters (per unit fuel burnt) are tug boats, thus making significant contributions to local air quality in ports. Emission of LAC from cargo and non cargo vessels in this study appears to be independent of engine load. Shipping fuel consumption data (2001) was used to calculate a global LAC contribution of 133(+/-27) Ggyr-1, or ~1.7% of global LAC. This small fraction could have disproportionate effects on both air quality near port areas and climate in the Arctic if direct emissions of LAC occur in that region due to opening Arctic sea routes. The global contribution of this LAC burden was investigated using the MOZART model. Increases of 20-50 ng m-3 LAC (relative increases up to 40%) due to shipping occur in the tropical Atlantic, Indonesia, central America and the southern regions of South America and Africa.

  5. Oil droplets as light absorbents in seawater

    Science.gov (United States)

    Otremba, Zbigniew

    2007-07-01

    This paper presents spectra of light absorption coefficient of oil-in-water emulsion, derived using the Mie theory. In order to achieve that concentration of oil, degree of oil dispersion in seawater as well as spectra of light absorption coefficient and refractive index of chosen oils must be known. A significant role of the size distribution of oil droplets has been revealed: light absorption coefficient of emulsion increases with the rate of dispersion.

  6. Photophoretic trampoline - Interaction of single airborne absorbing droplets with light

    CERN Document Server

    Esseling, Michael; Alpmann, Christina; Denz, Cornelia

    2012-01-01

    We present the light-induced manipulation of absorbing liquid droplets in air. Ink droplets from a printer cartridge are used to demonstrate that absorbing liquids - just like their solid counterparts - can interact with regions of high light intensity due to the photophoretic force. It is shown that droplets follow a quasi-ballistic trajectory after bouncing off a high intensity light sheet. We estimate the intensities necessary for this rebound of airborne droplets and change the droplet trajectories through a variation of the manipulating light field.

  7. Wheeler-Feynman Absorbers on the Light Horizon

    CERN Document Server

    Lear, C W

    2016-01-01

    Early Wheeler-Feynman absorber theories invoke both retarded and advanced electromagnetic waves for photon emission and absorption in order to remove problems involving lack of radiative damping during electron acceleration. Subsequent inquiries have suggested that only certain cosmologies would allow such a retarded-advanced wave mechanism to exist. These include quasi-steady state cosmologies and exclude flat, expanding Friedman-type cosmologies. Key to the exclusion process is a diminishing density of future absorbers in an ever-expanding universe. Such absorbers would be expected to be real electromagnetically interacting particles. However future virtual absorber sites, if they exist, would not be so diminished. Such sites would be plentiful on the future light horizon, receding from the source at the speed of light. The present treatment proposes that virtual absorption sites are present at every point in spacetime, and are characterized by the Fresnel-Kirchhoff diffraction integral. On the future light...

  8. Broadband light-induced absorbance change in multilayer graphene.

    Science.gov (United States)

    Obraztsov, Petr A; Rybin, Maxim G; Tyurnina, Anastasia V; Garnov, Sergey V; Obraztsova, Elena D; Obraztsov, Alexander N; Svirko, Yuri P

    2011-04-13

    We report the ultrafast light-induced absorbance change in CVD-grown multilayer graphene. Using femtosecond pump-probe measurements in 1100-1800 nm spectral range, we revealed broadband absorbance change when the probe photon energy was higher than that of the pump photon. The observed phenomenon is interpreted in terms of the Auger recombination and impact ionization playing a significant role in the dynamics of photoexcited carriers in graphene.

  9. RF Electromagnetic Field Treatment of Tetragonal Kesterite CZTSSe Light Absorbers

    Science.gov (United States)

    Semenenko, Mykola O.; Babichuk, Ivan S.; Kyriienko, Oleksandr; Bodnar, Ivan V.; Caballero, Raquel; Leon, Maximo

    2017-06-01

    In this work, we propose a method to improve electro-optical and structural parameters of light-absorbing kesterite materials. It relies on the application of weak power hydrogen plasma discharges using electromagnetic field of radio frequency range, which improves homogeneity of the samples. The method allows to reduce strain of light absorbers and is suitable for designing solar cells based on multilayered thin film structures. Structural characteristics of tetragonal kesterite Cu2ZnSn(S, Se)4 structures and their optical properties were studied by Raman, infrared, and reflectance spectroscopies. They revealed a reduction of the sample reflectivity after RF treatment and a modification of the energy band structure.

  10. Metallic Light Absorbers Produced by Femtosecond Laser Pulses

    Directory of Open Access Journals (Sweden)

    Anatoliy Y. Vorobyev

    2010-01-01

    Full Text Available Using high-intensity femtosecond laser pulses for surface structuring, technologically important metallic light absorbers (dark Au, W, and Ti alloy with absorption of about 85–95% over a broad wavelength range from ultraviolet to infrared were produced. It was found that the enhanced absorption of the dark metals is caused by a rich variety of nano-/microscale surface structures. The dark metals produced in this study may find a variety of applications in the fields of renewable energy and energy efficiency, such as thermophotovoltaics, solar energy absorbers, thermal radiation sources, and radiative heat transfer devices.

  11. Absorbent products for light urinary incontinence in women.

    Science.gov (United States)

    Fader, M; Cottenden, A M; Getliffe, K

    2007-04-18

    Incontinence is a common and embarrassing problem which has a profound effect on social and psychological well-being. Many people wear absorbent products to contain urine leakage and protect their clothes. It can be difficult to define light urinary incontinence because urine volumes, flow and frequency rates may vary substantially whilst still being considered 'light'. Light incontinence may encompass occasional (monthly) leaks of very small amounts (e.g. 1 g to 2 g) up to frequent leaks (several times per day) of larger amounts (e.g. 20 g to 50 g). A practical definition is urine loss that can be contained within a small absorbent pad (typically 50 g to 500 g; ISO 1996). To assess the effectiveness of different types of absorbent product designs for women with light urinary incontinence. We searched the Cochrane Incontinence Group Specialised Trials Register (3 May 2006) and the reference lists of relevant articles were perused. TYPES OF STUDIES: All randomised or quasi-randomised trials of absorbent products for women with light urinary incontinence. Women with light urinary incontinence. TYPES OF INTERVENTION: Absorbent products (disposable insert pads, menstrual pads, washable pants with integral pad, washable insert pads) suitable for light incontinence. Two review authors assessed the methodological quality of potentially eligible studies and independently extracted data from the included trial. One study with 85 participants met the selection criteria. This trial studied all the absorbent product designs included in this review. Data were presented on all included outcomes. For preventing leakage, for preference and for overall acceptability disposable insert pads are better than disposable menstrual pads which are better than washable pants with integral pad which are better than washable insert pads. There is no strong evidence that either disposables or washables are better for skin health. The disposable insert is the most expensive design and there is

  12. Light-induced electrohydrodynamic instability in plasmonically absorbing gold nanofluids

    Science.gov (United States)

    Shrestha, Sujan; Dominguez-Juarez, Jorge Luis; Vuong, Luat T.

    2017-06-01

    Plasmonically absorbing nanofluids exhibit light-induced electrokinetics. We measure an electrical response to the light-induced Rayleigh-Bénard-Marangoni convective instabilities in gold-polyvinylpyrrolidone (PVP) nanoparticles (NPs) suspended in isopropanol and water. Microampere current oscillations are measured and attributed to the presence of the Au-PVP NPs with negative zeta potential, in correspondence with the accompanying thermal lens oscillations and a nanofluid thermoelectric effect. The measured electrical oscillations represent an electrohydrodynamic stability driven by light, one among many that should be observed with plasmonic nanoparticles in liquids.

  13. Light pollution: the possible consequences of excessive illumination on retina.

    Science.gov (United States)

    Contín, M A; Benedetto, M M; Quinteros-Quintana, M L; Guido, M E

    2016-02-01

    Light is the visible part of the electromagnetic radiation within a range of 380-780 nm; (400-700 on primates retina). In vertebrates, the retina is adapted to capturing light photons and transmitting this information to other structures in the central nervous system. In mammals, light acts directly on the retina to fulfill two important roles: (1) the visual function through rod and cone photoreceptor cells and (2) non-image forming tasks, such as the synchronization of circadian rhythms to a 24 h solar cycle, pineal melatonin suppression and pupil light reflexes. However, the excess of illumination may cause retinal degeneration or accelerate genetic retinal diseases. In the last century human society has increased its exposure to artificial illumination, producing changes in the Light/Dark cycle, as well as in light wavelengths and intensities. Although, the consequences of unnatural illumination or light pollution have been underestimated by modern society in its way of life, light pollution may have a strong impact on people's health. The effects of artificial light sources could have direct consequences on retinal health. Constant exposure to different wavelengths and intensities of light promoted by light pollution may produce retinal degeneration as a consequence of photoreceptor or retinal pigment epithelium cells death. In this review we summarize the different mechanisms of retinal damage related to the light exposure, which generates light pollution.

  14. Control of light absorbance using plasmonic grating based perfect absorber at visible and near-infrared wavelengths.

    Science.gov (United States)

    Nguyen, Duc Minh; Lee, Dasol; Rho, Junsuk

    2017-06-01

    Conventional metamaterial absorbers have multilayer designs, where the dielectric interlayer is sandwiched between a top patterned metallic structure and bottom metallic film. Here, we demonstrate that a highly polarization-sensitive perfect absorber canbe realized by replacing the bottom metallic film with a plasmonic grating. Designs for broadband and narrowband of wavelength are proposed and numerically investigated. The designed absorbers perform high light absorption, which is above 90% over the wavelength range of 0.4-1.4 µm for the broadband absorber and 98% for the absorption peak in case of the narrowband design, with a specific polarization of incident light. We find that the absorption is tunable by changing the polarization. Such absorbers offer new approach for active control of light absorbance with strong impacts for solar energy harvesting, light emitting and sensing.

  15. How to distinguish scattered and absorbed light from re-emitted light for white LEDs?

    NARCIS (Netherlands)

    Meretska, Maryna; Lagendijk, Aart; Thyrrestrup Nielsen, Henri; Mosk, Allard; IJzerman, Wilbert; Vos, Willem L.

    2017-01-01

    We have studied the light transport through phosphor diffuser plates that are used in commercial solid-state lighting modules (Fortimo). These polymer plates contain YAG:Ce+3 phosphor particles that scatter, absorb and re-emit incident light in the visible wavelength range (400-700 nm). To

  16. Light Absorbers and Catalysts for Solar to Fuel Conversion

    Science.gov (United States)

    Kornienko, Nikolay I.

    Increasing fossil fuel consumption and the resulting consequences to the environment has propelled research into means of utilizing alternative, clean energy sources. Solar power is among the most promising of renewable energy sources but must be converted into an energy dense medium such as chemical bonds to render it useful for transport and energy storage. Photoelectrochemistry (PEC), the splitting of water into oxygen and hydrogen fuel or reducing CO 2 to hydrocarbon fuels via sunlight is a promising approach towards this goal. Photoelectrochemical systems are comprised of several components, including light absorbers and catalysts. These parts must all synergistically function in a working device. Therefore, the continual development of each component is crucial for the overall goal. For PEC systems to be practical for large scale use, the must be efficient, stable, and composed of cost effective components. To this end, my work focused on the development of light absorbing and catalyst components of PEC solar to fuel converting systems. In the direction of light absorbers, I focused of utilizing Indium Phosphide (InP) nanowires (NWs) as photocathodes. I first developed synthetic techniques for InP NW solution phase and vapor phase growth. Next, I developed light absorbing photocathodes from my InP NWs towards PEC water splitting cells. I studied cobalt sulfide (CoSx) as an earth abundant catalyst for the reductive hydrogen evolution half reaction. Using in situ spectroscopic techniques, I elucidated the active structure of this catalyst and offered clues to its high activity. In addition to hydrogen evolution catalysts, I established a new generation of earth abundant catalysts for CO2 reduction to CO fuel/chemical feedstock. I first worked with molecularly tunable homogeneous catalysts that exhibited high selectivity for CO2 reduction in non-aqueous media. Next, in order to retain molecular tunability while achieving stability and efficiency in aqueous

  17. Wideband perfect coherent absorber based on white-light cavity

    Science.gov (United States)

    Kotlicki, Omer; Scheuer, Jacob

    2015-03-01

    Coherent Perfect Absorbers (CPAs) are optical cavities which can be described as time-reversed lasers where light waves that enter the cavity, coherently interfere and react with the intra-cavity losses to yield perfect absorption. In contrast to lasers, which benefit from high coherency and narrow spectral linewidths, for absorbers these properties are often undesirable as absorption at a single frequency is highly susceptible to spectral noise and inappropriate for most practical applications. Recently, a new class of cavities, characterized by a spectrally wide resonance has been proposed. Such resonators, often referred to as White Light Cavities (WLCs), include an intra-cavity superluminal phase element, designed to provide a phase response with a slope that is opposite in sign and equal in magnitude to that of light propagation through the empty cavity. Consequently, the resonance phase condition in WLCs is satisfied over a band of frequencies providing a spectrally wide resonance. WLCs have drawn much attention due to their attractiveness for various applications such as ultra-sensitive sensors and optical buffering components. Nevertheless, WLCs exhibit inherent losses that are often undesirable. Here we introduce a simple wideband CPA device that is based on the WLC concept along with a complete analytical analysis. We present analytical and FDTD simulations of a practical, highly compact (12µm), Silicon based WLC-CPA that exhibits a flat and wide absorption profile (40nm) and demonstrate its usefulness as an optical pulse terminator (>35db isolation) and an all optical modulator that span the entire C-Band and exhibit high immunity to spectral noise.

  18. Metabolic acclimation to excess light intensity in Chlamydomonas reinhardtii.

    Science.gov (United States)

    Davis, Maria C; Fiehn, Oliver; Durnford, Dion G

    2013-07-01

    There are several well-described acclimation responses to excess light in green algae but the effect on metabolism has not been thoroughly investigated. This study examines the metabolic changes during photoacclimation to high-light (HL) stress in Chlamydomonas reinhardtii using nuclear magnetic resonance and mass spectrometry. Using principal component analysis, a clear metabolic response to HL intensity was observed on global metabolite pools, with major changes in the levels of amino acids and related nitrogen metabolites. Amino acid pools increased during short-term photoacclimation, but were especially prominent in HL-acclimated cultures. Unexpectedly, we observed an increase in mitochondrial metabolism through downstream photorespiratory pathways. The expression of two genes encoding key enzymes in the photorespiratory pathway, glycolate dehydrogenase and malate synthase, were highly responsive to the HL stress. We propose that this pathway contributes to metabolite pools involved in nitrogen assimilation and may play a direct role in photoacclimation. Our results suggest that primary and secondary metabolism is highly pliable and plays a critical role in coping with the energetic imbalance during HL exposure and a necessary adjustment to support an increased growth rate that is an effective energy sink for the excess reducing power generated during HL stress. © 2013 John Wiley & Sons Ltd.

  19. Slow and Fast Light in an Electro-Absorber

    DEFF Research Database (Denmark)

    Öhman, Filip; Bermejo Ramirez, Andres; Sales, Salvador

    2006-01-01

    We demonstrate controllable and large time delay in cascaded semiconductor saturable absorbers and amplifiers. The possibility of further increasing the tuneable phase shift by utilizing field screening effects in the quantum well absorber is demonstrated.......We demonstrate controllable and large time delay in cascaded semiconductor saturable absorbers and amplifiers. The possibility of further increasing the tuneable phase shift by utilizing field screening effects in the quantum well absorber is demonstrated....

  20. HOT DUST OBSCURED GALAXIES WITH EXCESS BLUE LIGHT: DUAL AGN OR SINGLE AGN UNDER EXTREME CONDITIONS?

    Energy Technology Data Exchange (ETDEWEB)

    Assef, R. J.; Diaz-Santos, T. [Núcleo de Astronomía de la Facultad de Ingeniería, Universidad Diego Portales, Av. Ejército Libertador 441, Santiago (Chile); Walton, D. J.; Brightman, M. [Space Radiation Laboratory, California Institute of Technology, Pasadena, CA 91125 (United States); Stern, D.; Eisenhardt, P. R. M.; Tsai, C.-W. [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Mail Stop 169-236, Pasadena, CA 91109 (United States); Alexander, D. [Department of Physics, Durham University, Durham DH1 3LE (United Kingdom); Bauer, F. [Departamento de Astronomía y Astrofísica, Pontificia Universidad Católica de Chile, Casilla 306, Santiago 22 (Chile); Blain, A. W. [Physics and Astronomy, University of Leicester, 1 University Road, Leicester LE1 7RH (United Kingdom); Finkelstein, S. L. [The University of Texas at Austin, 2515 Speedway, Stop C1400, Austin, TX 78712 (United States); Hickox, R. C. [Department of Physics and Astronomy, Dartmouth College, 6127 Wilder Laboratory, Hanover, NH 03755 (United States); Wu, J. W., E-mail: roberto.assef@mail.udp.cl [UCLA Astronomy, P.O. Box 951547, Los Angeles, CA 90095-1547 (United States)

    2016-03-10

    Hot dust-obscured galaxies (Hot DOGs) are a population of hyper-luminous infrared galaxies identified by the Wide-field Infrared Survey Explorer (WISE) mission from their very red mid-IR colors, and characterized by hot dust temperatures (T > 60 K). Several studies have shown clear evidence that the IR emission in these objects is powered by a highly dust-obscured active galactic nucleus (AGN) that shows close to Compton-thick absorption at X-ray wavelengths. Thanks to the high AGN obscuration, the host galaxy is easily observable, and has UV/optical colors usually consistent with those of a normal galaxy. Here we discuss a sub-population of eight Hot DOGs that show enhanced rest-frame UV/optical emission. We discuss three scenarios that might explain the excess UV emission: (i) unobscured light leaked from the AGN by reflection over the dust or by partial coverage of the accretion disk; (ii) a second unobscured AGN in the system; or (iii) a luminous young starburst. X-ray observations can help discriminate between these scenarios. We study in detail the blue excess Hot DOG WISE J020446.13–050640.8, which was serendipitously observed by Chandra/ACIS-I for 174.5 ks. The X-ray spectrum is consistent with a single, hyper-luminous, highly absorbed AGN, and is strongly inconsistent with the presence of a secondary unobscured AGN. Based on this, we argue that the excess blue emission in this object is most likely either due to reflection or a co-eval starburst. We favor the reflection scenario as the unobscured star formation rate needed to power the UV/optical emission would be ≳1000 M{sub ⊙} yr{sup −1}. Deep polarimetry observations could confirm the reflection hypothesis.

  1. Photophysics and light-activated biocidal activity of visible-light-absorbing conjugated oligomers.

    Science.gov (United States)

    Parthasarathy, Anand; Goswami, Subhadip; Corbitt, Thomas S; Ji, Eunkyung; Dascier, Dimitri; Whitten, David G; Schanze, Kirk S

    2013-06-12

    The photophysical properties of three cationic π-conjugated oligomers were correlated with their visible light activated biocidal activity vs S. aureus. The oligomers contain three arylene units (terthiophene, 4a; thiophene-benzotriazole-thiophene, 4b; thiophene-benzothiadiazole-thiophene, 4c) capped on each end by cationic -(CH2)3NMe3(+) groups. The oligomers absorb in the visible region due to their donor-acceptor-donor electronic structure. Oligomers 4a and 4b have high intersystem crossing and singlet oxygen sensitization efficiency, but 4c has a very low intersystem crossing efficiency and it does not sensitize singlet oxygen. The biocidal activity of the oligomers under visible light varies in the order 4a > 4b ≈ 4c.

  2. [Effects of excess Mn on photosynthesis characteristics in cucumber under different light intensity].

    Science.gov (United States)

    Shi, Qinghua; Zhu, Zhujun; Ying, Quansheng; Qian, Qiongqiu

    2005-06-01

    By a solution culture experiment, this paper studied the effects of excess Mn on the growth, chlorophyll content, chlorophyll fluorescence parameters and photosynthesis of cucumber under different light intensity. The results indicated that excess Mn inhibited plant growth, which was more obvious under high light intensity than under low light intensity. The primary maximum photochemical efficiency of PSII (v/Fm), quantum efficiency of non-cyclic electron transport of PSII (phiPSII), and photochemical quenching (qP) were significantly decreased in excess Mn treatment under high light intensity, while no significant effects on Fv/Fm and qP were observed under low light intensity. Excess Mn, particularly under high light intensity, decreased net photosynthetic rate (Pn) and stomatal conductance (Gs). Excess Mn increased intracellular CO2 (Ci) under high light intensity and decreased Ci under low light intensity, while stomatal limitation value (Ls) was just reverse to Ci. It could be concluded that the decrease of Pn in excess Mn treatment was not resulted from stomatal limitation under high light intensity, but was true under low light intensity.

  3. III-V semiconductor resonators: A new strategy for broadband light perfect absorbers

    Science.gov (United States)

    Liu, Xiaoshan; Chen, Jian; Liu, Jiasong; Huang, Zhenping; Yu, Meidong; Pan, Pingping; Liu, Zhengqi

    2017-11-01

    Broadband light perfect absorbers (BPAs) are desirable for applications in numerous optoelectronics devices. In this work, a semiconductor-based broadband light perfect absorber (S-BPA) has been numerically demonstrated by utilizing plasmonlike resonances of high-index semiconductor resonators. A maximal absorption of 99.7% is observed in the near-infrared region. By taking the absorption above 80% into account, the spectral bandwidth reaches 340 nm. The absorption properties mainly originate from the optical cavity modes induced by the cylinder resonators and ultrathin semiconductor film. These optical properties and simple structural features can maintain the absorber platform with wide applications in semiconductor optoelectronics.

  4. Photophoretic trampoline—Interaction of single airborne absorbing droplets with light

    Science.gov (United States)

    Esseling, Michael; Rose, Patrick; Alpmann, Christina; Denz, Cornelia

    2012-09-01

    We present the light-induced manipulation of absorbing liquid droplets in air. Ink droplets from a printer cartridge are used to demonstrate that absorbing liquids—just like their solid counterparts—can interact with regions of high light intensity due to the photophoretic force. It is shown that droplets follow a quasi-ballistic trajectory after bouncing off a high intensity light sheet. We estimate the intensities necessary for this rebound of airborne droplets and change the droplet trajectories through a variation of the manipulating light field.

  5. Absorbance based light emitting diode optical sensors and sensing devices

    OpenAIRE

    Dermot Diamond; Martina O’Toole

    2008-01-01

    The ever increasing demand for in situ monitoring of health, environment and security has created a need for reliable, miniaturised sensing devices. To achieve this, appropriate analytical devices are required that possess operating characteristics of reliability, low power consumption, low cost, autonomous operation capability and compatibility with wireless communications systems. The use of light emitting diodes (LEDs) as light sources is one strategy, which has been successfully applied i...

  6. Absorbance Based Light Emitting Diode Optical Sensors and Sensing Devices.

    Science.gov (United States)

    O'Toole, Martina; Diamond, Dermot

    2008-04-07

    The ever increasing demand for in situ monitoring of health, environment and security has created a need for reliable, miniaturised sensing devices. To achieve this, appropriate analytical devices are required that possess operating characteristics of reliability, low power consumption, low cost, autonomous operation capability and compatibility with wireless communications systems. The use of light emitting diodes (LEDs) as light sources is one strategy, which has been successfully applied in chemical sensing. This paper summarises the development and advancement of LED based chemical sensors and sensing devices in terms of their configuration and application, with the focus on transmittance and reflectance absorptiometric measurements.

  7. Ambient-light-absorbing screen for front projection

    Science.gov (United States)

    Hilborn, E. H.

    1970-01-01

    Screen permits front surface projection of collimated light beam under conditions of high extraneous illumination. Screen has high reflective efficiency over any desired viewing area. Its optical properties are maintained when moisture droplets are present on the external front planar surface. Surface is easily cleaned and maintained.

  8. Optical closure study on light-absorbing aerosols

    Science.gov (United States)

    Petzold, Andreas; Bundke, Ulrich; Freedman, Andrew; Onasch, Timothy B.; Massoli, Paola; Andrews, Elizabeth; Hallar, Anna G.

    2014-05-01

    The in situ measurement of atmospheric aerosol optical properties is an important component of quantifying climate change. In particular, the in-situ measurement of the aerosol single-scattering albedo (SSA), which is the ratio of aerosol scattering to aerosol extinction, is identified as a key challenge in atmospheric sciences and climate change research. Ideally, the complete set of aerosol optical properties is measured through optical closure studies which simultaneous measure aerosol extinction, scattering and absorption coefficients. The recent development of new optical instruments have made real-time in situ optical closure studies attainable, however, many of these instruments are state-of-the-art but not practical for routine monitoring. In our studies we deployed a suit of well-established and recently developed instruments including the cavity attenuated phase shift (CAPS) method for aerosol light extinction, multi-angle absorption photometer (MAAP) and particle soot absorption photometer (PSAP) for aerosol light absorption, and an integrating nephelometer (NEPH) for aerosol light scattering measurements. From these directly measured optical properties we calculated light absorption from extinction minus scattering (difference method), light extinction from scattering plus absorption, and aerosol single-scattering albedo from combinations CAPS + MAAP, NEPH + PSAP, NEPH + MAAP, CAPS + NEPH. Closure studies were conducted for laboratory-generated aerosols composed of various mixtures of black carbon (Regal 400R pigment black, Cabot Corp.) and ammonium sulphate, urban aerosol (Billerica, MA), and background aerosol (Storm Peak Lab.). Key questions addressed in our closure studies are: (1) how well can we measure aerosol light absorption by various methods, and (2) how well can we measure the aerosol single-scattering albedo by various instrument combinations? In particular we investigated (3) whether the combination of a CAPS and NEPH provides a reasonable

  9. Multilayer tungsten-alumina-based broadband light absorbers for high-temperature applications

    DEFF Research Database (Denmark)

    Chirumamilla, Manohar; Roberts, Alexander; Ding, Fei

    2016-01-01

    for the fabricated MIM resonator. Excellent thermal stability of the absorber is demonstrated at high operating temperatures (800 °C). The experimental broadband absorption spectra show good agreement with simulations. The resonator with 12 nm top tungsten and 100 nm alumina spacer film shows absorbance above 95...... the potential for a wide range of applications, including the use in commonly used infrared bands or absorbers for (solar) thermo-photovoltaic energy conversion, where high absorbance and simultaneously low (thermal) re-radiation is of paramount importance.......Efficient broadband absorption of visible and near-infrared light by low quality-factor metal-insulator-metal (MIM) resonators using refractory materials is reported. Omnidirectional absorption of incident light for broad angles of incidence and polarization insensitivity are observed...

  10. Biocidal activity of a light-absorbing fluorescent conjugated polyelectrolyte.

    Science.gov (United States)

    Lu, Liangde; Rininsland, Frauke H; Wittenburg, Shannon K; Achyuthan, Komandoor E; McBranch, Duncan W; Whitten, David G

    2005-10-25

    Herein we describe studies that indicate a cationic conjugated polyelectrolyte shows biocidal activity against gram-negative bacteria (Escherichia coli, E. coli, BL21, with plasmids for Azurin and ampicillin resistance) and gram-positive bacterial spores (Bacillus anthracis, Sterne, B. anthracis, Sterne). These studies were carried out with aqueous suspensions of the conjugated polyelectrolyte, with the polyelectrolyte in supported formats and with samples in which the conjugated polyelectrolyte was coated on the bacteria. The results are interesting in that the biocidal activity is light-induced and appears effective due to the ability of the conjugated polyelectrolyte to form a surface coating on both types of bacteria. The effects observed here should be general and suggest that a range of conjugated polyelectrolytes in different formulations may provide a useful new class of biocides for both dark and light-activated applications.

  11. Coherent light absorbing by concrete during its hardening

    Science.gov (United States)

    Gorsky, Mykhaylo P.; Maksimyak, Peter P.

    2018-01-01

    In this work changes of concrete reflection coefficient during its hydration were investigated theoretically and experimentally. Diffuse approximation method for concrete light-scattering description during hydration was used and its results were compared with received experimental data. Calculation of scattered and absorption sections for set of particles is described in details. Introduced optical diagnostics method allows performing earlier hydration stages diagnostics of concrete hardening process in comparison with other methods and predicting mechanical properties of produced concrete.

  12. Two mechanisms for dissipation of excess light in monomeric and trimeric light-harvesting complexes

    Energy Technology Data Exchange (ETDEWEB)

    Dall' Osto, Luca [Univ. di Verona, Verona (Italy). Dipartimento di Biotecnologie; Cazzaniga, Stefano [Univ. di Verona, Verona (Italy). Dipartimento di Biotecnologie; Bressan, Mauro [Univ. di Verona, Verona (Italy). Dipartimento di Biotecnologie; Paleček, David [Lund Univ. (Sweden). Dept. of Chemical Physics; Židek, Karel [Lund Univ. (Sweden). Dept. of Chemical Physics; Niyogi, Krishna K. [Univ. of California, Berkeley, CA (United States). Howard Hughes Medical Inst., Dept. of Plant and Microbial Biology; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Biophysics and Integrated Bioimaging Division; Fleming, Graham R. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Biophysics and Integrated Bioimaging Division; Univ. of California, Berkeley, CA (United States). Dept. of Chemistry, Graduate Group in Applied Science and Technology; Zigmantas, Donatas [Lund Univ. (Sweden). Dept. of Chemical Physics; Bassi, Roberto [Univ. di Verona, Verona (Italy). Dipartimento di Biotecnologie; Consiglio Nazionale delle Ricerche (CNR), Firenze (Italy). Istituto per la Protezione delle Piante (IPP)

    2017-04-10

    Oxygenic photoautotrophs require mechanisms for rapidly matching the level of chlorophyll excited states from light harvesting with the rate of electron transport from water to carbon dioxide. These photoprotective reactions prevent formation of reactive excited states and photoinhibition. The fastest response to excess illumination is the so-called non-photochemical quenching which, in higher plants, requires the luminal pH sensor PsbS and other yet unidentified components of the photosystem II antenna. Both trimeric light-harvesting complex II (LHCII) and monomeric LHC proteins have been indicated as site(s) of the heat-dissipative reactions. Different mechanisms have been proposed: Energy transfer to a lutein quencher in trimers, formation of a zeaxanthin radical cation in monomers. Here, we report on the construction of a mutant lacking all monomeric LHC proteins but retaining LHCII trimers. Its non-photochemical quenching induction rate was substantially slower with respect to the wild type. A carotenoid radical cation signal was detected in the wild type, although it was lost in the mutant. Here, we conclude that non-photochemical quenching is catalysed by two independent mechanisms, with the fastest activated response catalysed within monomeric LHC proteins depending on both zeaxanthin and lutein and on the formation of a radical cation. Trimeric LHCII was responsible for the slowly activated quenching component whereas inclusion in supercomplexes was not required. Finally, this latter activity does not depend on lutein nor on charge transfer events, whereas zeaxanthin was essential.

  13. On seeing yellow: the case for, and against, short-wavelength light-absorbing intraocular lenses.

    Science.gov (United States)

    Simunovic, Matthew P

    2012-07-01

    The normal human crystalline lens absorbs UV and short-wavelength visible electromagnetic radiation. Early intraocular lenses (IOLs) permitted the transmission of such radiation to the retina following cataract extraction. Experimental studies of the absorption profile of the crystalline lens and animal studies demonstrating the deleterious effects of short-wavelength radiation on the retina led to the development of UV-absorbing, and later, short-wavelength light-absorbing (SLA) IOLs. Short-wavelength light-absorbing IOLs were designed to mimic the absorption properties of the normal crystalline lens by absorbing some short-wavelength light in addition to UV radiation; however, debate continues regarding the relative merits of such lenses over UV-absorbing IOLs. Advocates of SLA IOLs suggest that they may theoretically offer increased photoprotection and decreased glare sensitivity and draw on in vitro, animal, and limited clinical studies that infer possible benefits. Detractors suggest that there is no direct evidence supporting a role for SLA IOLs in preventing retinal dysfunction in humans and suggest that they may have negative effects on color perception, scotopic vision, and circadian rhythms. This article examines the theoretical and empirical evidence for, and against, such lenses.

  14. Lidar remote sensing of laser-induced incandescence on light absorbing particles in the atmosphere.

    Science.gov (United States)

    Miffre, Alain; Anselmo, Christophe; Geffroy, Sylvain; Fréjafon, Emeric; Rairoux, Patrick

    2015-02-09

    Carbon aerosol is now recognized as a major uncertainty on climate change and public health, and specific instruments are required to address the time and space evolution of this aerosol, which efficiently absorbs light. In this paper, we report an experiment, based on coupling lidar remote sensing with Laser-Induced-Incandescence (LII), which allows, in agreement with Planck's law, to retrieve the vertical profile of very low thermal radiation emitted by light-absorbing particles in an urban atmosphere over several hundred meters altitude. Accordingly, we set the LII-lidar formalism and equation and addressed the main features of LII-lidar in the atmosphere by numerically simulating the LII-lidar signal. We believe atmospheric LII-lidar to be a promising tool for radiative transfer, especially when combined with elastic backscattering lidar, as it may then allow a remote partitioning between strong/less light absorbing carbon aerosols.

  15. Broadband light absorber based on porous alumina structure covered with ultrathin iridium film

    Science.gov (United States)

    Fang, Bo; Yang, Chenying; Pang, Chenlei; Shen, Weidong; Zhang, Xing; Zhang, Yueguang; Yuan, Wenjia; Liu, Xu

    2017-04-01

    In this letter, we propose a broadband absorber with high efficiency by an atomic layer depositing nanometer iridium (Ir) film onto a porous anodic alumina (PAA) template. The average absorption is able to achieve as high as 93.4% from 400 to 1100 nm and the absorption efficiency can reach up to 96.8% for the improved structure of the quadrangular frustum pyramid array. Not only the hexagonal latticed structures of the PAA template but also many similar structures based on gratings or holes with the square latticed or other latticed mode can realize the broadband high absorption efficiency. The light absorbed within the Ir/Glass interface and the sidewalls of PAA by the light funneling effect both contribute to the broadband absorption with high efficiency. This absorber, described in this paper, can be manufactured with a low-cost and large-area manner and has potential applications in fields of light harvesting, imaging, etc.

  16. Ultra-light weight undamped tuned dynamic absorber for cryogenically cooled infrared electro-optic payload

    Science.gov (United States)

    Veprik, Alexander; Babitsky, Vladimir

    2017-04-01

    Attenuation of tonal cryocooler induced vibration in infrared electro-optical payloads may be achieved by using of Tuned Dynamic Absorber (TDA) which is, generally speaking, a passive, weakly damped mass-spring system the resonant frequency of which is precisely matched with the driving frequency. Added TDA results in a favorable modification of the frequency response functions of combined structure. In particular, a favorable antiresonant notch appears at the frequency of tonal excitation along with the adjacent secondary resonance, the width and depth of which along with its closeness to the secondary resonance are strongly dependent on the mass and damping ratios. Using heavier TDA favorably results in wider and deeper antiresonant notch along with increased gap between antiresonant and resonant frequencies. Lowering damping in TDA favorably results in deepening the antiresonant notch. The weight of TDA is usually subjected to tight design constrains. Use of lightweight TDA not only diminishes the attainable performance but also complicates the procedure of frequency matching. Along these lines, even minor frequency deviations may negate the TDA performance and even result in TDA failure in case of resonant build up. The authors are presenting theoretical and practical aspects of designing and constructing ultra-light weight TDA in application to vibration attenuation of electro-optical infrared payload relying on Split Stirling linear cryocooler, the driving frequency of which is fixed and may be accurately tuned and maintained using a digital controller over the entire range of working conditions and lifetime; the lack of mass ratio is compensated by minimizing the damping ratio. In one particular case, in excess of 100-fold vibration attenuation has been achieved by adding as little as 5% to the payload weight.

  17. Excess diffuse light absorption in upper mesophyll limits CO2 drawdown and depresses photosynthesis

    Science.gov (United States)

    Sun-grown and shade-grown leaves of some species absorb direct and diffuse light differently. Sun-grown leaves can photosynthesize ~10-15% less under diffuse compared to direct irradiance, while shade-grown leaves do not exhibit this sensitivity. In this study, we investigate if the spatial differen...

  18. Exploring Light’s Interactions with Bubbles and Light Absorbers in Photoelectrochemical Devices using Ray Tracing

    Energy Technology Data Exchange (ETDEWEB)

    Stevens, John Colby [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). The Joint Center for Artificial Photosynthesis; Univ. of California, Berkeley, CA (United States). Dept. of Mechanical Engineering

    2012-12-01

    Ray tracing was used to perform optical optimization of arrays of photovoltaic microrods and explore the interaction between light and bubbles of oxygen gas on the surface of the microrods. The incident angle of light was varied over a wide range. The percent of incident light absorbed by the microrods and reflected by the bubbles was computed over this range. It was found that, for the 10 μm diameter, 100 μm tall SrTiO3 microrods simulated in the model, the optimal center-­to-­center spacing was 14 μm for a square grid. This geometry produced 75% average and 90% maximum absorbance. For a triangular grid using the same microrods, the optimal center-­to-­center spacing was 14 μm. This geometry produced 67% average and 85% maximum absorbance. For a randomly laid out grid of 5 μm diameter, 100 μm tall SrTiO3 microrods with an average center-­to-­center spacing of 20 μm, the average absorption was 23% and the maximum absorption was 43%. For a 50% areal coverage fraction of bubbles on the absorber surface, between 2%-­20% of the incident light energy was reflected away from the rods by the bubbles, depending upon incident angle and bubble morphology.

  19. Great light absorption enhancement in a graphene photodetector integrated with a metamaterial perfect absorber.

    Science.gov (United States)

    Song, Shichao; Chen, Qin; Jin, Lin; Sun, Fuhe

    2013-10-21

    A novel graphene photodetector with graphene embedded in a metamaterial perfect absorber (MPA) is proposed and its light absorption property is numerically investigated. Absorption above 40% in graphene is obtained, which is over 17 times that of a bare monolayer graphene. Both horizontally and vertically cascaded MPAs integrated with graphene are also investigated.

  20. [Enhanced visible-light absorbance of nanosized AgI/TiO2 by using calcination combined with light irradiation].

    Science.gov (United States)

    Liang, Zhu; Ni, Jin-Ren

    2009-07-15

    With the aim to enhance visible-light absorbance, calcination combined with light irradiation was used to modify nanosized AgI/TiO2. UV-Vis spectrum curves indicated that the modified sample exhibited an intense absorption in the whole visible light range and a spectrum shifted from 465 nm to 800 nm, and that absorbance at 500 nm was improved three times as much as that of the reported pertinent material. XRD analytic results demonstrated that calcined AgI/TiO2 possessed more rutile phase with reduced band gap from 2.89 eV to 2.81 eV, and that the following xenon-light irradiation further enhanced the relative contents of anatase TiO2, rutile TiO2 and AgI accompanied with produced AgCl phase, leading to the decrease in band gap to 1.55 eV. Formation of AgCl and increases in the relative contents of rutile TiO2 and AgI should take the main responsibilities for the decrease in the band gap and enlargement of visible-light absorbance. Additionally, it was confirmed that only the spectrum absorption of the calcined AgI/TiO2 could be improved by light irradiation, and that ultraviolet light played more role than visible part during the light irradiation. Moreover, it was proposed here that two or more silver halides supported on TiO2 could show more capabilities to stimulate visible-light activation of TiO2.

  1. Ultra-thin broadband nanostructured insulator-metal-insulator-metal plasmonic light absorber.

    Science.gov (United States)

    Hubarevich, Aliaksandr; Kukhta, Aliaksandr; Demir, Hilmi Volkan; Sun, Xiaowei; Wang, Hong

    2015-04-20

    An ultra-thin nanostructured plasmonic light absorber with an insulator-metal-insulator-metal (IMIM) architecture is designed and numerically studied. The IMIM structure is capable to absorb up to about 82.5% of visible light in a broad wavelength range of 300-750 nm. The absorption by the bottom metal is only 6% of that of the top metal. The results show that the IMIM architecture has weak dependence of the angle of the incident light. Interestingly, by varying the top insulator material the optical absorption spectrum can be shifted more than 180 nm as compared to the conventional air-metal-insulator-metal structure. The IMIM structure can be applied for different plasmonic devices with improved performance.

  2. Measurements of light-absorbing particles on the glaciers in the Cordillera Blanca, Peru

    Science.gov (United States)

    Schmitt, C. G.; All, J. D.; Schwarz, J. P.; Arnott, W. P.; Cole, R. J.; Lapham, E.; Celestian, A.

    2015-02-01

    Glaciers in the tropical Andes have been rapidly losing mass since the 1970s. In addition to the documented increase in temperature, increases in light-absorbing particles deposited on glaciers could be contributing to the observed glacier loss. Here we report on measurements of light-absorbing particles sampled from glaciers during three surveys in the Cordillera Blanca Mountains in Peru. During three research expeditions in the dry seasons (May-August) of 2011, 2012 and 2013, 240 snow samples were collected from 15 mountain peaks over altitudes ranging from 4800 to nearly 6800 m. Several mountains were sampled each of the 3 years and some mountains were sampled multiple times during the same year. Collected snow samples were melted and filtered in the field then later analyzed using the Light Absorption Heating Method (LAHM), a new technique that measures the ability of particles on filters to absorb visible light. LAHM results have been calibrated using filters with known amounts of fullerene soot, a common industrial surrogate for black carbon (BC). As sample filters often contain dust in addition to BC, results are presented in terms of effective black carbon (eBC). During the 2013 survey, snow samples were collected and kept frozen for analysis with a Single Particle Soot Photometer (SP2). Calculated eBC mass from the LAHM analysis and the SP2 refractory black carbon (rBC) results were well correlated (r2 = 0.92). These results indicate that a substantial portion of the light-absorbing particles in the more polluted regions were likely BC. The 3 years of data show that glaciers in the Cordillera Blanca Mountains close to human population centers have substantially higher levels of eBC (as high as 70 ng g-1) than remote glaciers (as low as 2.0 ng g-1 eBC), indicating that population centers can influence local glaciers by sourcing BC.

  3. Measurements of light absorbing particulates on the glaciers in the Cordillera Blanca, Peru

    Science.gov (United States)

    Schmitt, C. G.; All, J. D.; Schwarz, J. P.; Arnott, W. P.; Cole, R. J.; Lapham, E.; Celestian, A.

    2014-10-01

    Glaciers in the tropical Andes have been rapidly losing mass since the 1970s. In addition to the documented increase in air temperature, increases in light absorbing particulates deposited on glaciers could be contributing to the observed glacier loss. Here we report on measurements of light absorbing particulates sampled from glaciers during three surveys in the Cordillera Blanca in Peru. During three research expeditions in the dry seasons (May-August) of 2011, 2012 and 2013, two hundred and forty snow samples were collected from fifteen mountain peaks over altitudes ranging from 4800 to nearly 6800 m. Several mountains were sampled each of the three expeditions and some mountains were sampled multiple times during the same expedition. Collected snow samples were melted and filtered in the field then later analyzed using the Light Absorption Heating Method (LAHM), a new technique that measures the ability of particulates on filters to absorb visible light. LAHM results have been calibrated using filters with known amounts of fullerene soot, a common industrial surrogate for black carbon (BC). As sample filters often contain dust in addition to BC, results are presented in terms of effective Black Carbon (eBC). During the 2013 survey, snow samples were collected and kept frozen for analysis with a Single Particle Soot Photometer (SP2). Calculated eBC mass from the filter analysis and the SP2 refractory Black Carbon (rBC) results were well correlated (r2 = 0.92). These results indicate that a substantial portion of the light absorbing particulates in the more polluted areas were likely BC. The three years of data show that glaciers in the Cordillera Blanca Mountains close to human population centers have substantially higher levels of eBC (as high as 70 ng g-1) than remote glaciers (as low as 2.0 ng g-1 eBC), indicating that population centers can influence local glaciers by sourcing BC.

  4. Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols

    Directory of Open Access Journals (Sweden)

    M. O. Andreae

    2006-01-01

    Full Text Available Although the definition and measurement techniques for atmospheric 'black carbon' ('BC' or 'elemental carbon'' ('EC' have long been subjects of scientific controversy, the recent discovery of light-absorbing carbon that is not black ('brown carbon, Cbrown' makes it imperative to reassess and redefine the components that make up light-absorbing carbonaceous matter (LAC in the atmosphere. Evidence for the atmospheric presence of Cbrown comes from (1 spectral aerosol light absorption measurements near specific combustion sources, (2 observations of spectral properties of water extracts of continental aerosol, (3 laboratory studies indicating the formation of light-absorbing organic matter in the atmosphere, and (4 indirectly from the chemical analogy of aerosol species to colored natural humic substances. We show that brown carbon may severely bias measurements of 'BC' and 'EC' over vast parts of the troposphere, especially those strongly polluted by biomass burning, where the mass concentration of Cbrown is high relative to that of soot carbon. Chemical measurements to determine 'EC' are biased by the refractory nature of Cbrown as well as by complex matrix interferences. Optical measurements of 'BC' suffer from a number of problems: (1 many of the presently used instruments introduce a substantial bias into the determination of aerosol light absorption, (2 there is no unique conversion factor between light absorption and 'EC' or 'BC' concentration in ambient aerosols, and (3 the difference in spectral properties between the different types of LAC, as well as the chemical complexity of Cbrown, lead to several conceptual as well as practical complications. We also suggest that due to the sharply increasing absorption of Cbrown towards the UV, single-wavelength light absorption measurements may not be adequate for the assessment of absorption of solar radiation in the troposphere. We discuss the possible consequences of these effects for our

  5. Infrared light-absorbing gold/gold sulfide nanoparticles induce cell death in esophageal adenocarcinoma

    Science.gov (United States)

    Li, Yan; Gobin, Andre M; Dryden, Gerald W; Kang, Xinqin; Xiao, Deyi; Li, Su Ping; Zhang, Guandong; Martin, Robert CG

    2013-01-01

    Gold nanoparticles and near infrared-absorbing light are each innocuous to tissue but when combined can destroy malignant tissue while leaving healthy tissue unharmed. This study investigated the feasibility of photothermal ablation therapy for esophageal adenocarcinoma using chitosan-coated gold/gold sulfide (CS-GGS) nanoparticles. A rat esophagoduodenal anastomosis model was used for the in vivo ablation study, and three human esophageal cell lines were used to study the response of cancer cells and benign cells to near infrared light after treatment with CS-GGS. The results indicate that both cancerous tissue and cancer cells took up more gold nanoparticles and were completely ablated after exposure to near infrared light. The benign tissue and noncancerous cells showed less uptake of these nanoparticles, and remained viable after exposure to near infrared light. CS-GGS nanoparticles could provide an optimal endoluminal therapeutic option for near infrared light ablation of esophageal cancer. PMID:23818775

  6. Total absorption of visible light in ultra-thin weakly-absorbing semiconductor gratings

    CERN Document Server

    Sturmberg, Björn C P; Choi, Duk-Yong; White, Thomas P; Botten, Lindsay C; Dossou, Kokou B; Poulton, Christopher G; Catchpole, Kylie R; McPhedran, Ross C; de Sterke, C Martijn

    2016-01-01

    The perfect absorption of light in subwavelength thickness layers generally relies on exotic materials, metamaterials or thick metallic gratings. Here we demonstrate that total light absorption can be achieved in ultra-thin gratings composed of conventional materials, including relatively weakly-absorbing semiconductors, which are compatible with optoelectronic applications such as photodetectors and optical modulators. We fabricate a 41 nm thick antimony sulphide grating structure that has a measured absorptance of A = 99.3% at a visible wavelength of 591 nm, in excellent agreement with theory. We infer that the absorption within the grating is A = 98.7%, with only A = 0.6% within the silver mirror. A planar reference sample absorbs A = 7.7% at this wavelength.

  7. Literature search on Light Water Reactor (LWR) fuel and absorber rod fabrication, 1960--1976

    Energy Technology Data Exchange (ETDEWEB)

    Sample, C R [comp.

    1977-02-01

    A literature search was conducted to provide information supporting the design of a conceptual Light Water Reactor (LWR) Fuel Fabrication plant. Emphasis was placed on fuel processing and pin bundle fabrication, effects of fuel impurities and microstructure on performance and densification, quality assurance, absorber and poison rod fabrication, and fuel pin welding. All data have been taken from publicly available documents, journals, and books. This work was sponsored by the Finishing Processes-Mixed Oxide (MOX) Fuel Fabrication Studies program at HEDL.

  8. Optical properties and aging of light-absorbing secondary organic aerosol

    Directory of Open Access Journals (Sweden)

    J. Liu

    2016-10-01

    Full Text Available The light-absorbing organic aerosol (OA commonly referred to as “brown carbon” (BrC has attracted considerable attention in recent years because of its potential to affect atmospheric radiation balance, especially in the ultraviolet region and thus impact photochemical processes. A growing amount of data has indicated that BrC is prevalent in the atmosphere, which has motivated numerous laboratory and field studies; however, our understanding of the relationship between the chemical composition and optical properties of BrC remains limited. We conducted chamber experiments to investigate the effect of various volatile organic carbon (VOC precursors, NOx concentrations, photolysis time, and relative humidity (RH on the light absorption of selected secondary organic aerosols (SOA. Light absorption of chamber-generated SOA samples, especially aromatic SOA, was found to increase with NOx concentration, at moderate RH, and for the shortest photolysis aging times. The highest mass absorption coefficient (MAC value is observed from toluene SOA products formed under high-NOx conditions at moderate RH, in which nitro-aromatics were previously identified as the major light-absorbing compounds. BrC light absorption is observed to decrease with photolysis time, correlated with a decline of the organic nitrate fraction of SOA. SOA formed from mixtures of aromatics and isoprene absorb less visible (Vis and ultraviolet (UV light than SOA formed from aromatic precursors alone on a mass basis. However, the mixed SOA absorption was underestimated when optical properties were predicted using a two-product SOA formation model, as done in many current climate models. Further investigation, including analysis on detailed mechanisms, are required to explain the discrepancy.

  9. Mode of coaction between blue/UV light and light absorbed by phytochrome in light-mediated anthocyanin formation in the milo (Sorghum vulgare Pers.) seedling

    OpenAIRE

    Oelmüller, Ralf; Mohr, Hans

    1985-01-01

    Anthocyanin formation in milo (Sorghum vulgare Pers.) seedlings (coleoptile, mesocotyl, taproot) occurs only in white light and blue/UV light (BL/UV), while red light (RL) and far-RL are totally ineffective. However, after a BL/UV pretreatment, the participation of phytochrome can be demonstrated. With a short-wavelength light source [peak emission in longwave UV (UV-A)], the mode of coaction between BL/UV and light absorbed by phytochrome (RL) was studied with the following principal results...

  10. Application of B{sub 4}C/Al{sub 2}O{sub 3} Burnable Absorber Rod to Control Excess Reactivity of SMR

    Energy Technology Data Exchange (ETDEWEB)

    Muth, Boravy; Hah, C. J. [KEPCO International Nuclear Graduate School, Ulsan (Korea, Republic of)

    2016-10-15

    Soluble boron in a nuclear reactor coolant is one of the methods to control excess reactivity of the reactor. However, the use of soluble boron also causes some negative effects such as corrosion, more-positive tendency of Moderator Temperature Coefficient (MTC) and the requirement of Chemical Volume Control System (CVCS). One of the conceptual design features of SMR having been developed in Korea is soluble boron- free reactor to eliminate those drawbacks. Control rods and Burnable Absorber (BA) rods can be other methods than soluble to control excess reactivity. WABA (Wet Annular Burnable Absorber) and PYREX are such type. The other type is IFBA (Integral Fuel Burnable Absorber) in which fuel pellet surface is coated with BA. This paper compares nuclear characteristics of three types of BA as well as SLOBA in terms of k-infinite vs. burnup and explain design basis of SLOBA. This paper also presents the application of SLOBA rods to control long-term excess reactivity of SMR. The SMR loaded with SLOBA rods has been developed for the past few years in Korean. It is named as Bandi-50 with design features of 180 MWth, 37 FAs, fuel assembly height of 200 cm. Soluble-boron-free is one of nuclear design requirements of Bandi-50 and is achieved by controlling excess reactivity of the SMR using BAs and control rods only. To achieve this design requirement, LP is carefully determined in such way that CBC should be as low as possible. Fuel assembly cross-sections are generated by CASMO-3, and core depletion calculations are performed by MASTER.

  11. Energy, Electron Transfer and Photocatalytic Reactions of Visible Light Absorbing Transition Metal Complexes

    Energy Technology Data Exchange (ETDEWEB)

    Schmehl, Russell H. [Tulane Univ., New Orleans, LA (United States)

    2016-03-02

    This is the final technical report for a project carried out at Tulane University of New Orleans that describes the development of light induced (solar) reactions geared toward decomposing water into its component elements : hydrogen and oxygen. Much of the work involved optimizing systems for absorbing visible light and undergoing light promoted reactions to generate very strong reducing agents that are capable of reacting with water to produce hydrogen. Additional portions of the research were collaborative efforts to put the strong reducing agents to work in reaction with hydrogen generation catalysts prepared elsewhere. Time resolved laser spectroscopic methods were used to evaluate the light induced reactions and characterize very reactive intermediate substances formed during the reactions.

  12. White-Light-Induced Collective Heating of Gold Nanocomposite/Bombyx mori Silk Thin Films with Ultrahigh Broadband Absorbance.

    Science.gov (United States)

    Tsao, Shao Hsuan; Wan, Dehui; Lai, Yu-Sheng; Chang, Ho-Ming; Yu, Chen-Chieh; Lin, Keng-Te; Chen, Hsuen-Li

    2015-12-22

    This paper describes a systematic investigation of the phenomenon of white-light-induced heating in silk fibroin films embedded with gold nanoparticles (Au NPs). The Au NPs functioned to develop an ultrahigh broadband absorber, allowing white light to be used as a source for photothermal generation. With an increase of the Au content in the composite films, the absorbance was enhanced significantly around the localized surface plasmon resonance (LSPR) wavelength, while non-LSPR wavelengths were also increased dramatically. The greater amount of absorbed light increased the rate of photoheating. The optimized composite film exhibited ultrahigh absorbances of approximately 95% over the spectral range from 350 to 750 nm, with moderate absorbances (>60%) at longer wavelengths (750-1000 nm). As a result, the composite film absorbed almost all of the incident light and, accordingly, converted this optical energy to local heat. Therefore, significant temperature increases (ca. 100 °C) were readily obtained when we irradiated the composite film under a light-emitting diode or halogen lamp. Moreover, such composite films displayed linear light-to-heat responses with respect to the light intensity, as well as great photothermal stability. A broadband absorptive film coated on a simple Al/Si Schottky diode displayed a linear, significant, stable photo-thermo-electronic effect in response to varying the light intensity.

  13. Revisiting light stringy states in view of the 750 GeV diphoton excess

    Directory of Open Access Journals (Sweden)

    Pascal Anastasopoulos

    2016-10-01

    Full Text Available We investigate light massive string states that appear at brane intersections. They replicate the massless spectrum in a richer fashion and may be parametrically lighter than standard Regge excitations. We identify the first few physical states and determine their BRST invariant vertex operators. In the supersymmetric case we reconstruct the super-multiplet structure. We then compute some simple interactions, such as the decay rate of a massive scalar or vector into two massless fermions. Finally we suggest an alternative interpretation of the 750 GeV diphoton excess at LHC in terms of a light massive string state, a replica of the Standard Model Higgs.

  14. Revisiting light stringy states in view of the 750 GeV diphoton excess

    Energy Technology Data Exchange (ETDEWEB)

    Anastasopoulos, Pascal, E-mail: pascal@hep.itp.tuwien.ac.at [Technische Universität Wien, Institut für Theoretische Physik, A-1040 Vienna (Austria); Bianchi, Massimo, E-mail: massimo.bianchi@roma2.infn.it [Dipartimento di Fisica and Sezione I.N.F.N., Università di Roma “Tor Vergata”, Via della Ricerca Scientifica 1, 00133 Roma (Italy)

    2016-10-15

    We investigate light massive string states that appear at brane intersections. They replicate the massless spectrum in a richer fashion and may be parametrically lighter than standard Regge excitations. We identify the first few physical states and determine their BRST invariant vertex operators. In the supersymmetric case we reconstruct the super-multiplet structure. We then compute some simple interactions, such as the decay rate of a massive scalar or vector into two massless fermions. Finally we suggest an alternative interpretation of the 750 GeV diphoton excess at LHC in terms of a light massive string state, a replica of the Standard Model Higgs.

  15. Synthesis and photophysics of a red-light absorbing supramolecular chromophore system.

    Science.gov (United States)

    Rombouts, Jeroen A; Ravensbergen, Janneke; Frese, Raoul N; Kennis, John T M; Ehlers, Andreas W; Slootweg, J Chris; Ruijter, Eelco; Lammertsma, Koop; Orru, Romano V A

    2014-08-11

    In search of supramolecular antenna systems for light-harvesting applications, we report on a short and effective synthesis of a fused NDI-zinc-salphen-based chromophore (salphen = bis-salicylimide phenylene) and its photophysical properties. A supramolecular recognition motif is embedded into the chromophoric π-system of this compound. The fused π-chromophore behaves as one pigment, absorbs light between 600 and 750 nm and displays a modest Stokes shift. Upon binding pyridines, the compound (DATZnS) does not change its redox potentials, does not undergo any internal excited state quenching and does not appreciably alter its excited state lifetime. These notable properties define DATZnS as an alternative to porphyrin-based components used in supramolecular light-harvesting architectures. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Source attribution of insoluble light-absorbing particles in seasonal snow across northern China

    Directory of Open Access Journals (Sweden)

    R. Zhang

    2013-06-01

    Full Text Available Seasonal snow samples obtained at 46 sites in 6 provinces of China in January and February 2010 were analyzed for a suite of chemical species and these data are combined with previously determined concentrations of insoluble light-absorbing particles (ILAP, including all particles that absorb light in the 650–700 nm wavelength interval. The ILAP, together with 14 other analytes, are used as input to a positive matrix factorization (PMF receptor model to explore the sources of ILAP in the snow. The PMF analysis for ILAP sources is augmented with backward trajectory cluster analysis and the geographic locations of major source areas for the three source types. The two analyses are consistent and indicate that three factors/sources were responsible for the measured light absorption of snow: a soil dust source, an industrial pollution source, and a biomass and / or biofuel burning source. Soil dust was the main source of the ILAP, accounting for ~53% of ILAP on average.

  17. Modeling Transport and Processing of Light Absorbing Aerosols Deposited on the Greenland Ice Sheet in 2013

    Science.gov (United States)

    Polashenski, C.; Thomas, J. L.; Soja, A. J.; Dibb, J. E.; Choi, H. D.; Flanner, M.; Bergin, M.; Casey, K.; Chen, J.; Courville, Z.; Raut, J. C.; Shafer, M. M.; Ward, J. L.; Wiedinmyer, C.

    2016-12-01

    The processes that result in aerosol deposition within the Arctic are important for understanding how mid-latitude pollution impacts and modifies the natural Arctic environment. Aerosol deposition is a dominant source of light-absorbing impurities, including black carbon, found in Arctic ice and snow. Trace amounts of light absorbing impurities in snow are important because they are used to interpret past pollution trends (e.g. fire frequency) using ice cores and because they have important climate impacts (warming) due to their modification of snow and ice albedo. Here, we focus on the role of biomass burning in controlling the amount of black carbon deposited on the Greenland ice sheet. Biomass burning is known to modify the Arctic aerosol burden, but large uncertainties remain with respect to the specific processes and impacts. In this presentation, a specific case of light absorbing aerosol deposition to the Greenland ice sheet is studied by combining extensive snow pit measurements with simulations using the regional model WRF-Chem. Light absorbing impurities were measured in snow pits (in 2014) and snow accumulation rates (2013-2014) were monitored at several remote sites on the Greenland ice sheet as part of the SAGE project. The largest black carbon deposition quantity measured was traced to a snow accumulation event that occurred in early August 2013, which included snow deposition having 2-4 cm water equivalent with BC concentrations of up to 40ng/g . In order to understand the origin and identify the processes controlling the observed deposition event, the regional model WRF-Chem is used (run from 17 July - 5 August 2013). The model simulation includes anthropogenic and fire emissions in North America as well as transport and chemical/physical transport processes for both trace gases and aerosols. Model results show that the observed deposition event can be traced to fires burning in northern Canada in late July 2013. The processes controlling aerosol

  18. Dose determination with nitro blue tetrazolium containing radiochromic dye films by measuring absorbed and reflected light

    DEFF Research Database (Denmark)

    Kovács, A.; Baranyai, M.; Wojnárovits, L.

    2000-01-01

    Tetrazolium salts as heterocyclic organic compounds are known to form highly coloured, water insoluble formazans by reduction, which can be utilized in radiation processing dosimetry. Radiochromic films containing nitro blue tetrazolium dissolved in a polymer matrix were found suitable for dose...... determination in a wide dose range both by absorbance and reflectance measurements. The concept of measuring reflected light from dose labels has been discussed earlier and emerged recently due to the requirement of introducing semiquantitative label dose indicators for quarantine control. The usefulness...

  19. Self-action of continuous laser radiation and Pearcey diffraction in a water suspension with light-absorbing particles

    DEFF Research Database (Denmark)

    Angelsky, O. V.; Bekshaev, A. Ya.; Maksimyak, P. P.

    2014-01-01

    Water suspension of light-absorbing nano-sized particles is an example of a medium in which non-linear effects are present at moderate light intensities favorable for optical treatment of organic and biological objects. We study experimentally the phenomena emerging in a thin layer of such a medium...... under the action of inhomogeneous light field formed due to the Pearcey diffraction pattern near a microlens focus. In this high-gradient field, the light energy absorbed by the particles induces inhomogeneous distribution of the medium refraction index, which results in observable self...

  20. Slow light in saturable absorbers: Progress in the resolution of a controversy

    Science.gov (United States)

    Macke, Bruno; Razdobreev, Igor; Ségard, Bernard

    2017-06-01

    There are two opposing models in the analysis of the slow transmission of light pulses through saturable absorbers. The canonical incoherent bleaching model simply explains the slow transmission by combined effects of saturation and of noninstantaneous response of the medium resulting in absorption of the front part of the incident pulse larger than that of its rear. The second model, referred to as the coherent-population-oscillations (CPO) model, considers light beams whose intensity is slightly pulse modulated and attributes the time delay of the transmitted pulse to a reduction of the group velocity. We point out some inconsistencies in the CPO model and show that the two models lie in reality on the same hypotheses, the equations derived in the duly rectified CPO model being local expressions of the integral equations obtained in the incoherent bleaching model. When intense pulses without background are used, the CPO model, based on linearized equations, breaks down. The incoherent bleaching model then predicts that the transmitted light should vanish when the intensity of the incident light is strictly zero. This point is confirmed by the experiments that we have performed on ruby with square-wave incident pulses and we show that the whole shape of the observed pulses agrees with that derived analytically by means of the incoherent bleaching model. We also determine in this model the corresponding evolution of the fluorescence light, which seems to have been evidenced in other experiments.

  1. Colloidal metasurfaces displaying near-ideal and tunable light absorbance in the infrared.

    Science.gov (United States)

    Rozin, Matthew J; Rosen, David A; Dill, Tyler J; Tao, Andrea R

    2015-06-23

    Metasurfaces are ultrathin, two-dimensional arrays of subwavelength resonators that have been demonstrated to control the flow of light in ways that are otherwise unattainable with natural materials. These arrays are typically composed of metallic Ag or Au nanostructures shaped like split rings, nanowire pairs or nanorods (commonly referred to as meta-atoms) that are arranged to produce a collective optical response spanning an impressive range of properties, from the perfect absorption of incident light to superresolution imaging. However, metasurfaces pose major challenges in their fabrication over large areas, which can be prohibitively expensive and time consuming using conventional nanolithography techniques. Here we show that differently shaped colloidal nanocrystals can be organized into metasurface architectures using robust, scalable assembly methods. These metasurfaces exhibit extreme in-plane electromagnetic coupling that is strongly dependent on nanocrystal size, shape and spacing. Colloidal metasurfaces that display near-ideal electromagnetic absorbance can be tuned from the visible into the mid-infrared wavelengths.

  2. Novel multi-chromophor light absorber concepts for DSSCs for efficient electron injection

    Energy Technology Data Exchange (ETDEWEB)

    Schuetz, Robert; Strothkaemper, Christian; Bartelt, Andreas; Hannappel, Thomas; Eichberger, Rainer [Helmholtz-Zentrum Berlin fuer Materialien und Energie, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Fasting, Carlo [Institut fuer Organische Chemie, Freie Universitaet Berlin, Takustrasse 3, 14195 Berlin (Germany); Thomas, Inara [Helmholtz-Zentrum Berlin fuer Materialien und Energie, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Institut fuer Organische Chemie, Freie Universitaet Berlin, Takustrasse 3, 14195 Berlin (Germany)

    2011-07-01

    Dye sensitized solar cells (DSSCs) operate by injecting electrons from the excited state of a light-harvesting dye into the continuum of conduction band states of a wide bandgap semiconductor. The light harvesting efficiency of pure organic dyes is limited by a narrow spectral electronic transition. A beneficial broad ground state absorption in the VIS region can be achieved by applying a single molecular dye system with multiple chromophors involving a Foerster resonance energy transfer (FRET) mechanism for an efficient electron injection. A model donor acceptor dye system capable for FRET chemically linked to colloidal TiO{sub 2} and ZnO nanorod surfaces was investigated in UHV environment. We used VIS/NIR femtosecond transient absorption spectroscopy and optical pump terahertz probe spectroscopy to study the charge injection dynamics of the antenna system. Different chromophors attached to a novel scaffold/anchor system connecting the organic absorber unit to the metal oxide semiconductor were probed.

  3. Calibration of a multi-pass photoacoustic spectrometer cell using light-absorbing aerosols

    Science.gov (United States)

    Bluvshtein, Nir; Flores, J. Michel; He, Quanfu; Segre, Enrico; Segev, Lior; Hong, Nina; Donohue, Andrea; Hilfiker, James N.; Rudich, Yinon

    2017-03-01

    The multi-pass photoacoustic spectrometer (PAS) is an important tool for the direct measurement of light absorption by atmospheric aerosol. Accurate PAS measurements heavily rely on accurate calibration of their signal. Ozone is often used for calibrating PAS instruments by relating the photoacoustic signal to the absorption coefficient measured by an independent method such as cavity ring down spectroscopy (CRD-S), cavity-enhanced spectroscopy (CES) or an ozone monitor. We report here a calibration method that uses measured absorption coefficients of aerosolized, light-absorbing organic materials and offer an alternative approach to calibrate photoacoustic aerosol spectrometers at 404 nm. To implement this method, we first determined the complex refractive index of nigrosin, an organic dye, using spectroscopic ellipsometry and then used this well-characterized material as a standard material for PAS calibration.

  4. Distribution of light-absorbing impurities in snow of glacier on Mt. Yulong, southeastern Tibetan Plateau

    Science.gov (United States)

    Niu, Hewen; Kang, Shichang; Zhang, Yulan; Shi, Xiaoyi; Shi, Xiaofei; Wang, Shijin; Li, Gang; Yan, Xingguo; Pu, Tao; He, Yuanqing

    2017-11-01

    Insoluble light-absorbing impurities (ILAIs) in surface snow of glacier reduce snow albedo and accelerate glacier melt. In order to assess effects of ILAIs on glacier melt, we present the first results from field measurements of ILAIs, including black carbon (BC) and dust in snowpacks of glacier on Mt. Yulong, southeastern Tibetan Plateau (TP). Amplification factors because of snow melt were calculated for BC and dust concentrations in surface snow, and melt scavenging rates, effects of ILAIs on snow spectral albedo, and associated radiative forcing (RF) were estimated. Melt amplification generally appeared to be confined to the top few centimeters of the snowpack, and our results indicated that BC was more efficiently scavenged with meltwater than the other insoluble light-absorbers (e.g., dust). Absorbing impurities reduced snow spectral albedo more with larger particulate grain radius (re). Spectral albedo reduction was investigated using the SNow ICe Aerosol Radiative (SNICAR) model. Albedo reduction for 1200 ng g- 1 of BC in Mt. Yulong snow was 0.075 for snow with re = 500 compared with re = 200 μm. If dust (51.37 ppm) was the only impurity in the snowpack, the spectral albedo reduction would be only 0.03, and the associated RF was 42.76 W m- 2. For a BC and dust mixed scenario, the spectral albedo was substantially reduced (0.11 ± 0.03), and the associated RF (145.23 W m- 2) was more than three times larger than that for the dust-only scenario. BC in snow is an active factor controlling snow albedo and snow-ice RF. Further observational studies are needed to quantify the contribution of BC and dust to albedo reduction and glacier melt and to characterize the variation of glacier RF.

  5. Electromagnetically induced transparency of a plasmonic metamaterial light absorber based on multilayered metallic nanoparticle sheets.

    Science.gov (United States)

    Okamoto, Koichi; Tanaka, Daisuke; Degawa, Ryo; Li, Xinheng; Wang, Pangpang; Ryuzaki, Sou; Tamada, Kaoru

    2016-11-08

    In this study, we observed the peak splitting of absorption spectra for two-dimensional sheets of silver nanoparticles due to the electromagnetically induced transparency (EIT) effect. This unique optical phenomenon was observed for the multilayered nanosheets up to 20 layers on a metal substrate, while this phenomenon was not observed on a transparent substrate. The wavelength and intensities of the split peaks depend on the number of layers, and the experimental results were well reproduced by the calculation of the Transfer-Matrix method by employing the effective medium approximation. The Ag nanosheets used in this study can act as a plasmonic metamaterial light absorber, which has a such large oscillator strength. This phenomenon is a fundamental optical property of a thin film on a metal substrate but has never been observed because native materials do not have a large oscillator strength. This new type of EIT effect using a plasmonic metamaterial light absorber presents the potential for the development of future optic and photonic technologies.

  6. Light-absorbing secondary organic material formed by glyoxal in aqueous aerosol mimics

    Directory of Open Access Journals (Sweden)

    E. L. Shapiro

    2009-04-01

    Full Text Available Light-absorbing and high-molecular-weight secondary organic products were observed to result from the reaction of glyoxal in mildly acidic (pH=4 aqueous inorganic salt solutions mimicking aqueous tropospheric aerosol particles. High-molecular-weight (500–600 amu products were observed when ammonium sulfate ((NH42SO4 or sodium chloride (NaCl was present in the aqueous phase. The products formed in (NH42SO4 or ammonium nitrate (NH4NO3 solutions absorb light at UV and visible wavelengths. Substantial absorption at 300–400 nm develops within two hours, and absorption between 400–600 nm develops within days. Pendant drop tensiometry measurements show that the products are not surface-active. The experimental results along with ab initio predictions of the UV/Vis absorption of potential products suggest a mechanism involving the participation of the ammonium ion. If similar products are formed in atmospheric aerosol particles, they could change the optical properties of the seed aerosol over its lifetime.

  7. Light-induced changes within photosystem II protects Microcoleus sp. in biological desert sand crusts against excess light.

    Directory of Open Access Journals (Sweden)

    Itzhak Ohad

    Full Text Available The filamentous cyanobacterium Microcoleus vaginatus, a major primary producer in desert biological sand crusts, is exposed to frequent hydration (by early morning dew followed by desiccation during potentially damaging excess light conditions. Nevertheless, its photosynthetic machinery is hardly affected by high light, unlike "model" organisms whereby light-induced oxidative stress leads to photoinactivation of the oxygen-evolving photosystem II (PSII. Field experiments showed a dramatic decline in the fluorescence yield with rising light intensity in both drying and artificially maintained wet plots. Laboratory experiments showed that, contrary to "model" organisms, photosynthesis persists in Microcoleus sp. even at light intensities 2-3 times higher than required to saturate oxygen evolution. This is despite an extensive loss (85-90% of variable fluorescence and thermoluminescence, representing radiative PSII charge recombination that promotes the generation of damaging singlet oxygen. Light induced loss of variable fluorescence is not inhibited by the electron transfer inhibitors 3-(3,4-dichlorophenyl-1,1-dimethylurea (DCMU, 2,5-dibromo-3-methyl-6-isopropylbenzoquinone (DBMIB, nor the uncoupler carbonyl cyanide-p-trifluoromethoxyphenylhydrazone (FCCP, thus indicating that reduction of plastoquinone or O(2, or lumen acidification essential for non-photochemical quenching (NPQ are not involved. The rate of Q(A (- re-oxidation in the presence of DCMU is enhanced with time and intensity of illumination. The difference in temperatures required for maximal thermoluminescence emissions from S(2/Q(A (- (Q band, 22 degrees C and S(2,3/Q(B (- (B band, 25 degrees C charge recombinations is considerably smaller in Microcoleus as compared to "model" photosynthetic organisms, thus indicating a significant alteration of the S(2/Q(A (- redox potential. We propose that enhancement of non-radiative charge recombination with rising light intensity may reduce

  8. Rapid Recovery Gene Downregulation during Excess-Light Stress and Recovery in Arabidopsis.

    Science.gov (United States)

    Crisp, Peter A; Ganguly, Diep R; Smith, Aaron B; Murray, Kevin D; Estavillo, Gonzalo M; Searle, Iain; Ford, Ethan; Bogdanović, Ozren; Lister, Ryan; Borevitz, Justin O; Eichten, Steven R; Pogson, Barry J

    2017-08-01

    Stress recovery may prove to be a promising approach to increase plant performance and, theoretically, mRNA instability may facilitate faster recovery. Transcriptome (RNA-seq, qPCR, sRNA-seq, and PARE) and methylome profiling during repeated excess-light stress and recovery was performed at intervals as short as 3 min. We demonstrate that 87% of the stress-upregulated mRNAs analyzed exhibit very rapid recovery. For instance, HSP101 abundance declined 2-fold every 5.1 min. We term this phenomenon rapid recovery gene downregulation (RRGD), whereby mRNA abundance rapidly decreases promoting transcriptome resetting. Decay constants (k) were modeled using two strategies, linear and nonlinear least squares regressions, with the latter accounting for both transcription and degradation. This revealed extremely short half-lives ranging from 2.7 to 60.0 min for 222 genes. Ribosome footprinting using degradome data demonstrated RRGD loci undergo cotranslational decay and identified changes in the ribosome stalling index during stress and recovery. However, small RNAs and 5'-3' RNA decay were not essential for recovery of the transcripts examined, nor were any of the six excess light-associated methylome changes. We observed recovery-specific gene expression networks upon return to favorable conditions and six transcriptional memory types. In summary, rapid transcriptome resetting is reported in the context of active recovery and cellular memory. © 2017 American Society of Plant Biologists. All rights reserved.

  9. Global convergence of maixmum light use efficiency using fraction of PAR absorbed by chlorophyll

    Science.gov (United States)

    Zhang, Y.; Xiao, X.; Cescatti, A.; Wolf, S.; Wu, J.; Wu, X.; Gioli, B.; Wohlfahrt, G.; Zhou, S.; Steinbrecher, R.; Gough, C. M.

    2016-12-01

    The efficiency that plants utilize light for photosynthesis has been long established and been used for simple light use efficiency (LUE) models to estimate gross primary production (GPP) from site level to global scales. However, the LUE can be defined at different scales which cause a large variation of maximum LUE values across different models and ecosystem types. Here we use solar-induced chlorophyll fluorescence (SIF) as a proxy of photosynthetically active radiation (PAR) absorbed by chlorophyll (APARchl) and derived an estimation of fraction of APARchl (fPARchl) from four remote sensing based optical vegetation activity indicators (OVAIs). By comparing this fPARchl estimation with eddy flux based GPP from 136 sites, we found that the maximum daily LUE tends to converge to a common value ignorance of the biome types. The seasonal variation of LUEPAR (GPP/PAR) in tropical forest where little environmental limits presents can also be tracked by the change of fPARchl. This global convergence can be used to build simple models to estimate GPP and to constrain process-based models using satellite observations.

  10. Temperature effect of natural organic extraction upon light absorbance in dye-sensitized solar cells

    Science.gov (United States)

    Suhaimi, Suriati; Mohamed Siddick, Siti Zubaidah; Retnasamy, Vithyacharan; Abdul Wahid, Mohamad Halim; Ahmad Hambali, Nor Azura Malini; Mohamad Shahimin, Mukhzeer

    2017-02-01

    Natural organic dyes contain pigments which when safely extracted from plants have the potential to be used as a sensitizer while promising a low-cost fabrication, environmental friendly dye-sensitized solar cells (DSSCs). Ardisia, Bawang Sabrang, Harum Manis mango, Oxalis Triangularis and Rosella showed different absorption peaks when the extraction process were carried out at different temperatures. Hence, these were used as the basis to determine the conversion efficiency against the dyes extracting temperature. In this study, all dyes extracted in water have shown the best performance at a temperature of 100°C except for Harum Manis mango, while in ethanol, the optimum temperature was obtained between the room temperature, 25°C and 50°C. The absorption spectrum in water showed a broader absorption wavelength vis-à-vis ethanol solvent that resulted in the absorption peak for Ardisia, Harum Manis mango and Rosella between 450 nm and 550 nm. The highest conversion efficiency is observed to be achieved by Oxalis Triangularis extracted in water solution at 100°C, which was approximately 0.96% which corresponds to the broader absorbance trends in the literature. Thus, the optimum condition for extracting temperature for dyes in water and ethanol is room temperature and boiling points of water. Hence, Ardisia, Bawang Sabrang, Harum Manis mango, Oxalis Triangularis and Rosella can be an as alternative source for photosensitizer, and the impacts of temperature upon the light absorbance can be further investigated to produce the ultimate natural dye based solar cells.

  11. Spatiotemporal distribution of light-absorbing carbon and its relationship to other atmospheric pollutants in Stockholm

    Directory of Open Access Journals (Sweden)

    P. Krecl

    2011-11-01

    Full Text Available Carbon-containing particles have deleterious effects on both Earth's climate and human health. In Europe, the main sources of light-absorbing carbon (LAC emissions are the transport (67% and residential (25% sectors. Information on the spatiotemporal variability of LAC particles in urban areas is relevant for air quality management and to better diagnose the population exposure to these particles. This study reports on results of an intensive field campaign conducted at four sites (two kerbside stations, one urban background site and a rural station in Stockholm, Sweden, during the spring 2006. Light-absorbing carbon mass (MLAC concentrations were measured with custom-built Particle Soot Absorption Photometers (PSAP. The spatiotemporal variability of MLAC concentrations was explored by examining correlation coefficients (R, coefficients of divergence (COD, and diurnal patterns at all sites. Simultaneous measurements of NOx, PM10, PM2.5, and meteorological variables were also carried out at the same locations to help characterize the LAC emission sources.

    Hourly mean (± standard deviation MLAC concentrations ranged from 0.36±0.50 at the rural site to 5.39±3.60 μg m−3 at the street canyon site. Concentrations of LAC between urban sites were poorly correlated even for daily averages (R<0.70, combined with highly heterogeneously distributed concentrations (COD>0.30 even at spatial scales of few kilometers. This high variability is connected to the distribution of emission sources and processes contributing to the LAC fraction at these sites. At urban sites, MLAC tracked NOx levels and traffic density well and mean MLAC/PM2.5 ratios were larger (26–38% than at the background sites (4–10%. The results suggest that vehicle exhaust emissions are the main responsible for the high M

  12. Light scattering by coated sphere immersed in absorbing medium: a comparison between the FDTD and analytic solutions

    Energy Technology Data Exchange (ETDEWEB)

    Sun Wenbo E-mail: w.sun@larc.nasa.gov; Loeb, Norman G.; Fu Qiang

    2004-02-01

    A recently developed finite-difference time domain scheme is examined using the exact analytic solutions for light scattering by a coated sphere immersed in an absorbing medium. The relative differences are less than 1% in the extinction, scattering, and absorption efficiencies and less than 5% in the scattering phase functions. The definition of apparent single-scattering properties is also discussed.

  13. Mobility of Chromophores Absorbing Light in the 320-420 nm Range in Transparent and Cataract Lens Tissue

    Science.gov (United States)

    Halets-Bui, I. V.; Sukhodol, A. A.; Shcharbin, D. G.

    2014-11-01

    We have analyzed the spectral and kinetic characteristics of phosphorescence at room temperature on a millisecond time scale for transparent and cataract lens tissues. We have studied the nature of the change (with age and with cataract development in the lens tissues) in the molecular mobility of the products absorbing light in the 320-420 nm range.

  14. Light Absorbing Carbon Emissions from Commercial Shipping: Impacts for Local Air quality and the Arctic

    Science.gov (United States)

    Lack, D. A.; Lerner, B.; Granier, C.; Massoli, P.; Baynard, T.; Lovejoy, E.; Ravishankara, A.; Williams, E.

    2007-12-01

    Emissions of light absorbing carbon (LAC) are a major uncertainty when considering the climatic effect of this aerosol. LAC contributes to direct radiative warming, can affect cloud formation and dynamics and can alter the albedo of snow and ice. Commercial shipping vessels contribute significant amounts of LAC to the atmosphere by burning residual fuels with little emissions regulation. Knowledge of the actual emissions of LAC from shipping is highly uncertain yet critical to help constrain budgets of LAC. This is of particular concern in populated port areas where continuous loading operations can contribute to adverse air quality and in regions like the Arctic that will become exposed to larger volumes of shipping traffic as sea ice retreats. A single directly-measured emission factor from shipping has previously been reported. Here we present an extensive set of measurements of the emission characteristics of LAC from commercial shipping. We show that the highest emitters (mass of LAC per unit fuel burnt) are tug boats, thus making significant contributions to local air quality in major ports, and that emission of LAC is unrelated to primary emissions of NOX and SO2. Using 2001 shipping fuel consumption data we calculate a global LAC contribution from shipping of 133 Gg yr-1, or ~ 1.7 % of global LAC. The optical characteristics of these emissions are also discussed. We also present results from global transport modeling of the estimated impact of increases in commercial shipping through Arctic sea lanes.

  15. Perovskite oxides for visible-light-absorbing ferroelectric and photovoltaic materials.

    Science.gov (United States)

    Grinberg, Ilya; West, D Vincent; Torres, Maria; Gou, Gaoyang; Stein, David M; Wu, Liyan; Chen, Guannan; Gallo, Eric M; Akbashev, Andrew R; Davies, Peter K; Spanier, Jonathan E; Rappe, Andrew M

    2013-11-28

    Ferroelectrics have recently attracted attention as a candidate class of materials for use in photovoltaic devices, and for the coupling of light absorption with other functional properties. In these materials, the strong inversion symmetry breaking that is due to spontaneous electric polarization promotes the desirable separation of photo-excited carriers and allows voltages higher than the bandgap, which may enable efficiencies beyond the maximum possible in a conventional p-n junction solar cell. Ferroelectric oxides are also stable in a wide range of mechanical, chemical and thermal conditions and can be fabricated using low-cost methods such as sol-gel thin-film deposition and sputtering. Recent work has shown how a decrease in ferroelectric layer thickness and judicious engineering of domain structures and ferroelectric-electrode interfaces can greatly increase the current harvested from ferroelectric absorber materials, increasing the power conversion efficiency from about 10(-4) to about 0.5 per cent. Further improvements in photovoltaic efficiency have been inhibited by the wide bandgaps (2.7-4 electronvolts) of ferroelectric oxides, which allow the use of only 8-20 per cent of the solar spectrum. Here we describe a family of single-phase solid oxide solutions made from low-cost and non-toxic elements using conventional solid-state methods: [KNbO3]1 - x[BaNi1/2Nb1/2O3 - δ]x (KBNNO). These oxides exhibit both ferroelectricity and a wide variation of direct bandgaps in the range 1.1-3.8 electronvolts. In particular, the x = 0.1 composition is polar at room temperature, has a direct bandgap of 1.39 electronvolts and has a photocurrent density approximately 50 times larger than that of the classic ferroelectric (Pb,La)(Zr,Ti)O3 material. The ability of KBNNO to absorb three to six times more solar energy than the current ferroelectric materials suggests a route to viable ferroelectric semiconductor-based cells for solar energy conversion and

  16. Note: Investigation of a null measurement of optical absorbance using a pulse width modulated light-emitting diode.

    Science.gov (United States)

    Rusak, David A; Kawka, Ernest A; Trexler, E Brady

    2010-01-01

    We examined the possibility of making a null measurement of optical absorbance by using pulse-width modulation to control the intensity of a light-emitting diode (LED). This type of measurement is intriguing because the instrumental sources of noise are different from those in the traditional absorbance measurement. Our experiment employed phototransistor detectors and a RC integrator to measure the amount of light being transmitted. However, instead of measuring the ratio of the detector voltages for a blank and sample, we measured the ratio of the LED duty cycles required to give the same detector voltage for a blank and a sample. Using this method, it is presumed that the same amount of light reaches the detector during measurement of the blank and sample.

  17. Modeling investigation of light-absorbing aerosols in the Amazon Basin during the wet season

    Directory of Open Access Journals (Sweden)

    Q. Wang

    2016-11-01

    Full Text Available We use a global chemical transport model (GEOS-Chem to interpret observed light-absorbing aerosols in Amazonia during the wet season. Observed aerosol properties, including black carbon (BC concentration and light absorption, at the Amazon Tall Tower Observatory (ATTO site in the central Amazon have relatively low background levels but frequently show high peaks during the study period of January–April 2014. With daily temporal resolution for open fire emissions and modified aerosol optical properties, our model successfully captures the observed variation in fine/coarse aerosol and BC concentrations as well as aerosol light absorption and its wavelength dependence over the Amazon Basin. The source attribution in the model indicates the important influence of open fire on the observed variances of aerosol concentrations and absorption, mainly from regional sources (northern South America and from northern Africa. The contribution of open fires from these two regions is comparable, with the latter becoming more important in the late wet season. The analysis of correlation and enhancement ratios of BC versus CO suggests transport times of < 3 days for regional fires and  ∼  11 days for African plumes arriving at ATTO during the wet season. The model performance of long-range transport of African plumes is also evaluated with observations from AERONET, MODIS, and CALIOP. Simulated absorption aerosol optical depth (AAOD averaged over the wet season is lower than 0.0015 over the central Amazon, including the ATTO site. We find that more than 50 % of total absorption at 550 nm is from BC, except for the northeastern Amazon and the Guianas, where the influence of dust becomes significant (up to 35 %. The brown carbon contribution is generally between 20 and 30 %. The distribution of absorption Ångström exponents (AAE suggests more influence from fossil fuel combustion in the southern part of the basin (AAE  ∼  1 but more

  18. Submicron-resolution photoacoustic microscopy of endogenous light-absorbing biomolecules

    Science.gov (United States)

    Zhang, Chi

    Photoacoustic imaging in biomedicine has the unique advantage of probing endogenous light absorbers at various length scales with a 100% relative sensitivity. Among the several modalities of photoacoustic imaging, optical-resolution photoacoustic microscopy (OR-PAM) can achieve high spatial resolution, on the order of optical wavelength, at targets fluorescent markers, label-free PAM avoids the major concerns that the fluorescent labeling probes may disturb the function of biomolecules and may have an insufficient density. This dissertation aims to advance label-free OR-PAM to the subcellular scale. The first part of this dissertation describes the technological advancement of PAM yielding high spatial resolution in 3D. The lateral resolution was improved by using optical objectives with high numerical apertures for optical focusing. The axial resolution was improved by using broadband ultrasonic transducers for ultrasound detection. We achieved 220 nm lateral resolution in transmission mode, 0.43 microm lateral resolution in reflection mode, 7.6 microm axial resolution in normal tissue, and 5.8 microm axial resolution with silicone oil immersion/injection. The achieved lateral resolution and axial resolution were the finest reported at the time. With high-resolution in 3D, PAM was demonstrated to resolve cellular and subcellular structures in vivo, such as red blood cells and melanosomes in melanoma cells. Compared with previous PAM systems, our high-resolution PAM could resolve capillaries in mouse ears more clearly. As an example application, we demonstrated intracellular temperature imaging, assisted by fluorescence signal detection, with sub-degree temperature resolution and sub-micron lateral resolution. The second part of this dissertation describes the exploration of endogenous light-absorbing biomolecules for PAM. We demonstrated cytochromes and myoglobin as new absorption contrasts for PAM and identified the corresponding optimal wavelengths for imaging

  19. Integrated light collimating system for extended optical-path-length absorbance detection in microchip-based capillary electrophoresis.

    Science.gov (United States)

    Ro, Kyung Won; Lim, Kwanseop; Shim, Bong Chu; Hahn, Jong Hoon

    2005-08-15

    We have developed an integrated light collimating system with a microlens and a pair of slits for extended optical path length absorbance detection in a capillary electrophoresis (CE) microchip. The collimating system is made of the same material as the chip, poly(dimethylsiloxane) (PDMS), and it is integrated into the chip during the molding of the CE microchannels. In this microchip, the centers of an extended 500-microm detection cell and two optical fibers are self-aligned, and a planoconvex microlens (r = 50 microm) for light collimation is placed in front of a light-delivering fiber. To block stray light, two rectangular apertures, realized by a specially designed three-dimensional microchannel, are made on each end of the detection cell. In comparison to conventional extended detection cell having no collimator, the percentage of stray radiation readout fraction in the collimator integrated detection cell is significantly reduced from 31.6 to 3.8%. The effective optical path length is increased from 324 to 460 microm in the collimator integrated detection cell. The detection sensitivity is increased by 10 times in the newly developed absorbance detection cell as compared to an unextended, 50-microm-long detection cell. The concentration detection limit (S/N = 3) for fluorescein in the collimator integrated detection cell is 1.2 microM at the absorbance detection limit of 0.001 AU.

  20. Ultra-broadband Tunable Resonant Light Trapping in a Two-dimensional Randomly Microstructured Plasmonic-photonic Absorber

    Science.gov (United States)

    Liu, Zhengqi; Liu, Long; Lu, Haiyang; Zhan, Peng; Du, Wei; Wan, Mingjie; Wang, Zhenlin

    2017-03-01

    Recently, techniques involving random patterns have made it possible to control the light trapping of microstructures over broad spectral and angular ranges, which provides a powerful approach for photon management in energy efficiency technologies. Here, we demonstrate a simple method to create a wideband near-unity light absorber by introducing a dense and random pattern of metal-capped monodispersed dielectric microspheres onto an opaque metal film; the absorber works due to the excitation of multiple optical and plasmonic resonant modes. To further expand the absorption bandwidth, two different-sized metal-capped dielectric microspheres were integrated into a densely packed monolayer on a metal back-reflector. This proposed ultra-broadband plasmonic-photonic super absorber demonstrates desirable optical trapping in dielectric region and slight dispersion over a large incident angle range. Without any effort to strictly control the spatial arrangement of the resonant elements, our absorber, which is based on a simple self-assembly process, has the critical merits of high reproducibility and scalability and represents a viable strategy for efficient energy technologies.

  1. Impacts of light-absorbing impurities on snow and their quantification with bidirectional reflectance measurements

    Science.gov (United States)

    Gritsevich, Maria; Peltoniemi, Jouni; Meinander, Outi; Dagsson-Waldhauserová, Pavla; Zubko, Nataliya; Hakala, Teemu; Virkkula, Aki; Svensson, Jonas; de Leeuw, Gerrit

    2017-04-01

    rate gets faster than the diffusion rate (under condition of warm outside temperatures), as it was observed at the end of the experiment reported here, dark material starts accumulating into the surface [5]. The BC deposited on snow at warm temperatures initiates rapid melting process and may cause dramatic changes on the snow surface. References 1 Peltoniemi J.I., Hakala T., Suomalainen J., Honkavaara E., Markelin L., Gritsevich M., Eskelinen J., Jaanson P., Ikonen E. (2014): Technical notes: A detailed study for the provision of measurement uncertainty and traceability for goniospectrometers. Journal of Quantitative Spectroscopy & Radiative Transfer 146, 376-390, http://dx.doi.org/10.1016/j.jqsrt.2014.04.011 2 Zubko N., Gritsevich M., Zubko E., Hakala T., Peltoniemi J.I. (2016): Optical measurements of chemically heterogeneous particulate surfaces // Journal of Quantitative Spectroscopy and Radiative Transfer, 178, 422-431, http://dx.doi.org/10.1016/j.jqsrt.2015.12.010 3 Peltoniemi J.I., Gritsevich M., Hakala T., Dagsson-Waldhauserová P., Arnalds Ó., Anttila K., Hannula H.-R., Kivekäs N., Lihavainen H., Meinander O., Svensson J., Virkkula A., de Leeuw G. (2015): Soot on snow exper- iment: bidirectional reflectance factor measurements of contaminated snow // The Cryosphere, 9, 2323-2337, http://dx.doi.org/10.5194/tc-9-2323-2015 4 Svensson J., Virkkula A., Meinander O., Kivekäs N., Hannula H.-R., Järvinen O., Peltoniemi J.I., Gritsevich M., Heikkilä A., Kontu A., Neitola K., Brus D., Dagsson-Waldhauserova P., Anttila K., Vehkamäki M., Hienola A., de Leeuw G. & Lihavainen H. (2016): Soot-doped natural snow and its albedo — results from field experiments. Boreal Environment Research, 21, 481-503, http://www.borenv.net/BER/pdfs/preprints/Svensson1498.pdf 5 Meinander O., Kontu A., Virkkula A., Arola A., Backman L., Dagsson-Waldhauserová P., Järvinen O., Manninen T., Svensson J., de Leeuw G., and Leppäranta M. (2014): Brief communication: Light-absorbing

  2. A multilayer physically based snowpack model simulating direct and indirect radiative impacts of light-absorbing impurities in snow

    Science.gov (United States)

    Tuzet, Francois; Dumont, Marie; Lafaysse, Matthieu; Picard, Ghislain; Arnaud, Laurent; Voisin, Didier; Lejeune, Yves; Charrois, Luc; Nabat, Pierre; Morin, Samuel

    2017-11-01

    Light-absorbing impurities (LAIs) decrease snow albedo, increasing the amount of solar energy absorbed by the snowpack. Its most intuitive and direct impact is to accelerate snowmelt. Enhanced energy absorption in snow also modifies snow metamorphism, which can indirectly drive further variations of snow albedo in the near-infrared part of the solar spectrum because of the evolution of the near-surface snow microstructure. New capabilities have been implemented in the detailed snowpack model SURFEX/ISBA-Crocus (referred to as Crocus) to account for impurities' deposition and evolution within the snowpack and their direct and indirect impacts. Once deposited, the model computes impurities' mass evolution until snow melts out, accounting for scavenging by meltwater. Taking advantage of the recent inclusion of the spectral radiative transfer model TARTES (Two-stream Analytical Radiative TransfEr in Snow model) in Crocus, the model explicitly represents the radiative impacts of light-absorbing impurities in snow. The model was evaluated at the Col de Porte experimental site (French Alps) during the 2013-2014 snow season against in situ standard snow measurements and spectral albedo measurements. In situ meteorological measurements were used to drive the snowpack model, except for aerosol deposition fluxes. Black carbon (BC) and dust deposition fluxes used to drive the model were extracted from simulations of the atmospheric model ALADIN-Climate. The model simulates snowpack evolution reasonably, providing similar performances to our reference Crocus version in terms of snow depth, snow water equivalent (SWE), near-surface specific surface area (SSA) and shortwave albedo. Since the reference empirical albedo scheme was calibrated at the Col de Porte, improvements were not expected to be significant in this study. We show that the deposition fluxes from the ALADIN-Climate model provide a reasonable estimate of the amount of light-absorbing impurities deposited on the

  3. Mode of coaction between blue/UV light and light absorbed by phytochrome in light-mediated anthocyanin formation in the milo (Sorghum vulgare Pers.) seedling.

    Science.gov (United States)

    Oelmüller, R; Mohr, H

    1985-09-01

    Anthocyanin formation in milo (Sorghum vulgare Pers.) seedlings (coleoptile, mesocotyl, taproot) occurs only in white light and blue/UV light (BL/UV), while red light (RL) and far-RL are totally ineffective. However, after a BL/UV pretreatment, the participation of phytochrome can be demonstrated. With a short-wavelength light source [peak emission in longwave UV (UV-A)], the mode of coaction between BL/UV and light absorbed by phytochrome (RL) was studied with the following principal results. (i) As soon as the seedling becomes competent to respond to UV-A (with regard to anthocyanin formation), the involvement of phytochrome can be detected. (ii) A 5-min pulse of UV-A has a strong effect on the anthocyanin synthesis in the milo mesocotyl. This effect is fully reversible if a long-wavelength far-RL pulse (RG9 light) is given immediately after the UV-A light pulse. (iii) When seedlings treated with 5 min of UV-A and 5 min of RG9 light are kept in darkness for 3 hr and then transferred to RL, anthocyanin appears. (iv) In continuous UV-A treatment, anthocyanin accumulation starts after a lag phase of 3.5 hr (25 degrees C). A RL pretreatment prior to the onset of UV-A treatment strongly increases anthocyanin accumulation in UV-A, though the lag phase is not affected. Moreover, a RL pretreatment does not affect the time course for escape from reversibility in UV-A. It is concluded from these data that BL/UV cannot mediate induction of anthocyanin synthesis in the absence of P(fr), the active form of phytochrome that absorbs maximally in the far-red. Rather, the action of BL/UV must be considered to establish responsiveness of the anthocyanin-producing mechanism to P(fr). P(fr) operates in this system via two different channels. As the effector of the terminal response, it sets in motion the signal-response chain that eventually leads to the appearance of anthocyanin. This is a slow process with a lag phase of the order of 3.5 hr. The second function of P(fr) is to

  4. A computational model for heterogeneous heating during pulsed laser irradiation of polymers doped with light-absorbing microparticles

    DEFF Research Database (Denmark)

    Marla, Deepak; Zhang, Yang; Jabbaribehnam, Mirmasoud

    2016-01-01

    Doping of polymers with light-absorbing microparticles to increase their optical properties is a commonly used pre-treatment technique in laser processing of polymers. The presence of these particles plays an important role during laser heating of the polymer that influences its surface character......Doping of polymers with light-absorbing microparticles to increase their optical properties is a commonly used pre-treatment technique in laser processing of polymers. The presence of these particles plays an important role during laser heating of the polymer that influences its surface...... characteristics. This work presents a study based on a computational model of laser heating of polymer doped with light-absorbing microparticles accounting for the heterogeneous nature of heating. The work aims at gaining a fundamental insight into the nature of the heating process and to understand the role...... of microparticles. The results suggest that apart from the laser intensity and pulse duration, the properties of the microparticles including their size and distribution also play an important role during the laser heating of polymers....

  5. Light-absorbing impurities accelerate glacier melt in the Central Tibetan Plateau.

    Science.gov (United States)

    Li, Xiaofei; Kang, Shichang; He, Xiaobo; Qu, Bin; Tripathee, Lekhendra; Jing, Zhefan; Paudyal, Rukumesh; Li, Yang; Zhang, Yulan; Yan, Fangping; Li, Gang; Li, Chaoliu

    2017-06-01

    Light-absorbing impurities (LAIs), such as organic carbon (OC), black carbon (BC), and mineral dust (MD) deposited on the glacier surface can reduce albedo, thus accelerating the glacier melt. Surface fresh snow, aged snow, granular ice, and snowpits samples were collected between August 2014 and October 2015 on the Xiao Dongkemadi (XDKMD) glacier (33°04'N, 92°04'E) in the central Tibetan Plateau (TP). The spatiotemporal variations of LAIs concentrations in the surface snow/ice were observed to be consistent, differing mainly in magnitudes. LAIs concentrations were found to be in the order: granular ice>snowpit>aged snow>fresh snow, which must be because of post-depositional effects and enrichment. In addition, more intense melting led to higher LAIs concentrations exposed to the surface at a lower elevation, suggesting a strong negative relationship between LAIs concentrations and elevation. The scavenging efficiencies of OC and BC were same (0.07±0.02 for OC, 0.07±0.01 for BC), and the highest enrichments was observed in late September and August for surface snow and granular ice, respectively. Meanwhile, as revealed by the changes in the OC/BC ratios, intense glacier melt mainly occurred between August and October. Based on the SNow ICe Aerosol Radiative (SNICAR) model simulations, BC and MD in the surface snow/ice were responsible for about 52%±19% and 25%±14% of the albedo reduction, while the radiative forcing (RF) were estimated to be 42.74±40.96Wm -2 and 21.23±22.08Wm -2 , respectively. Meanwhile, the highest RF was observed in the granular ice, suggesting that the exposed glaciers melt and retreat more easily than the snow distributed glaciers. Furthermore, our results suggest that BC was the main forcing factor compared with MD in accelerating glacier melt during the melt season in the Central TP. Copyright © 2017 Elsevier B.V. All rights reserved.

  6. The use of a black pigment polyimide, DARC300, as a light absorber on an optical sensor

    Science.gov (United States)

    Gehoski, K. A.; Holm, P. M.; Boggess, K. A.; Scott, C. J.

    2007-03-01

    In the design and fabrication of arrayed opto-electronic detection devices, it is critical to provide optical isolation between the individual array cells to prevent optical crosstalk between channels and contribution from stray light that would otherwise result in degraded signal-to-noise performance. To accomplish this, the light incident between the cells' optical apertures and around the periphery of the array must be blocked from entering the active semiconductor layers. One approach has been to use an opaque layer of metal, but this can lead to reflections and light trapping and ultimate absorption of this stray light in device active regions. Another approach is to use an absorbing material to block stray light. DARC300, a registered trademark of Brewer Science, is an optically absorbing, photo-definable polyimide designed for exactly this purpose. Presented here are the results of the DARC300 blocking layers, including a review of the process development and issues addressed along the way. The most prevalent issues with the DARC300 were the remnants of black pigments after develop, and the insufficiently developed features. A normalized spectral response of a 4-channel, fixed cavity, Fabry-Perot micro spectrometers, with and without the optical blocking layer between cells and around the periphery of the array are shown to greatly enhance device performance with the use of the DARC300 layer.

  7. The physical properties of black carbon and other light-absorbing material emitted from prescribed fires in the United States

    Science.gov (United States)

    McMeeking, G. R.; Kreidenweis, S. M.; Yokelson, R. J.; Sullivan, A. P.; Lee, T.; Collett, J. L.; Fortner, E.; Onasch, T. B.; Akagi, S. K.; Taylor, J.; Coe, H.

    2012-12-01

    Black carbon (BC) aerosol emitted from fires absorbs light, leading to visibility degradation as well as regional and global climate impacts. Fires also emit a wide range of trace gases and particulates that can interact with emitted BC and alter its optical properties and atmospheric lifetime. Non-BC particulate species emitted by fires can also scatter and absorb light, leading to additional effects on visibility. Recent work has shown that certain organic species can absorb light strongly at shorter wavelengths, giving it a brown or yellow color. This material has been classified as brown carbon, though it is not yet well defined. Land managers must find a balance between the negative impacts of prescribed fire emissions on visibility and air quality and the need to prevent future catastrophic wildfire as well as manage ecosystems for habitat restoration or other purposes. This decision process requires accurate assessments of the visibility impacts of fire emissions, including BC and brown carbon, which in turn depend on their optical properties. We present recent laboratory and aircraft measurements of black carbon and aerosol optical properties emitted from biomass burning. All measurement campaigns included a single particle soot photometer (SP2) instrument capable of providing size-resolved measurements of BC mass and number distributions and mixing state, which are needed to separate the BC and brown carbon contributions to total light absorption. The laboratory experiments also included a three-wavelength photoacoustic spectrometer that provided accurate measurements of aerosol light absorption. The laboratory systems also characterized emissions after they had been treated with a thermal denuder to remove semi-volatile coatings, allowing an assessment of the role of non-BC coatings on bulk aerosol optical properties. Emissions were also aged in an environmental smog chamber to examine the role of secondary aerosol production on aerosol optical properties.

  8. SU-F-J-56: The Connection Between Cherenkov Light Emission and Radiation Absorbed Dose in Proton Irradiated Phantoms

    Energy Technology Data Exchange (ETDEWEB)

    Darafsheh, A; Kassaee, A; Finlay, J [University of Pennsylvania, Philadelphia, PA (United States); Taleei, R [UT Southwestern Medical Center, Dallas, TX (United States)

    2016-06-15

    Purpose: Range verification in proton therapy is of great importance. Cherenkov light follows the photon and electron energy deposition in water phantom. The purpose of this study is to investigate the connection between Cherenkov light generation and radiation absorbed dose in a water phantom irradiated with proton beams. Methods: Monte Carlo simulation was performed by employing FLUKA Monte Carlo code to stochastically simulate radiation transport, ionizing radiation dose deposition, and Cherenkov radiation in water phantoms. The simulations were performed for proton beams with energies in the range 50–600 MeV to cover a wide range of proton energies. Results: The mechanism of Cherenkov light production depends on the initial energy of protons. For proton energy with 50–400 MeV energy that is below the threshold (∼483 MeV in water) for Cherenkov light production directly from incident protons, Cherenkov light is produced mainly from the secondary electrons liberated as a result of columbic interactions with the incident protons. For proton beams with energy above 500 MeV, in the initial depth that incident protons have higher energy than the Cherenkov light production threshold, the light has higher intensity. As the slowing down process results in lower energy protons in larger depths in the water phantom, there is a knee point in the Cherenkov light curve vs. depth due to switching the Cherenkov light production mechanism from primary protons to secondary electrons. At the end of the depth dose curve the Cherenkov light intensity does not follow the dose peak because of the lack of high energy protons to produce Cherenkov light either directly or through secondary electrons. Conclusion: In contrast to photon and electron beams, Cherenkov light generation induced by proton beams does not follow the proton energy deposition specially close to the end of the proton range near the Bragg peak.

  9. Excess Diffuse Light Absorption in Upper Mesophyll Limits CO2 Drawdown and Depresses Photosynthesis.

    Science.gov (United States)

    Earles, J Mason; Théroux-Rancourt, Guillaume; Gilbert, Matthew E; McElrone, Andrew J; Brodersen, Craig R

    2017-06-01

    In agricultural and natural systems, diffuse light can enhance plant primary productivity due to deeper penetration into and greater irradiance of the entire canopy. However, for individual sun-grown leaves from three species, photosynthesis is actually less efficient under diffuse compared with direct light. Despite its potential impact on canopy-level productivity, the mechanism for this leaf-level diffuse light photosynthetic depression effect is unknown. Here, we investigate if the spatial distribution of light absorption relative to electron transport capacity in sun- and shade-grown sunflower (Helianthus annuus) leaves underlies its previously observed diffuse light photosynthetic depression. Using a new one-dimensional porous medium finite element gas-exchange model parameterized with light absorption profiles, we found that weaker penetration of diffuse versus direct light into the mesophyll of sun-grown sunflower leaves led to a more heterogenous saturation of electron transport capacity and lowered its CO2 concentration drawdown capacity in the intercellular airspace and chloroplast stroma. This decoupling of light availability from photosynthetic capacity under diffuse light is sufficient to generate an 11% decline in photosynthesis in sun-grown but not shade-grown leaves, primarily because thin shade-grown leaves similarly distribute diffuse and direct light throughout the mesophyll. Finally, we illustrate how diffuse light photosynthetic depression could overcome enhancement in canopies with low light extinction coefficients and/or leaf area, pointing toward a novel direction for future research. © 2017 American Society of Plant Biologists. All Rights Reserved.

  10. The combination effect of hindered amine light stabilizers with UV absorbers on the radiation resistance of polypropylene

    Science.gov (United States)

    Jia, Haishun; Wang, Huiliang; Chen, Wenxiu

    2007-07-01

    The UV absorber 2-(2'-hydroxy-3',5'-dipentyl-phenyl) benzotriazole (Tinuvin 328) shows excellent stabilizing effectiveness in the γ-ray-induced degradation of polypropylene (PP). Antagonism was observed when hindered amine light stabilizers were used with benzotriazole type UV absorbers. The carbonyl index and hydroxyl index, the hydroperoxide concentration, the mass change and the relative concentration of alkyl free radicals of irradiated samples were measured. Tinuvin 328 could effectively inhibit the formation of alkyl free radicals in PP under γ-irradiation, and it is possibly the fundamental reason for its high stabilizing efficiency. A mechanism of dissipating radiation energy for Tinuvin 328 was proposed. Some reactions yet unknown between the two stabilizers decreased their stabilizing effectiveness.

  11. Reducing uncertainties associated with filter-based optical measurements of light absorbing carbon particles with chemical information

    Directory of Open Access Journals (Sweden)

    J. E. Engström

    2011-08-01

    Full Text Available The presented filter-based optical method for determination of soot (light absorbing carbon or Black Carbon, BC can be implemented in the field under primitive conditions and at low cost. This enables researchers with small economical means to perform monitoring at remote locations, especially in the Asia where it is much needed.

    One concern when applying filter-based optical measurements of BC is that they suffer from systematic errors due to the light scattering of non-absorbing particles co-deposited on the filter, such as inorganic salts and mineral dust. In addition to an optical correction of the non-absorbing material this study provides a protocol for correction of light scattering based on the chemical quantification of the material, which is a novelty. A newly designed photometer was implemented to measure light transmission on particle accumulating filters, which includes an additional sensor recording backscattered light. The choice of polycarbonate membrane filters avoided high chemical blank values and reduced errors associated with length of the light path through the filter.

    Two protocols for corrections were applied to aerosol samples collected at the Maldives Climate Observatory Hanimaadhoo during episodes with either continentally influenced air from the Indian/Arabian subcontinents (winter season or pristine air from the Southern Indian Ocean (summer monsoon. The two ways of correction (optical and chemical lowered the particle light absorption of BC by 63 to 61 %, respectively, for data from the Arabian Sea sourced group, resulting in median BC absorption coefficients of 4.2 and 3.5 Mm−1. Corresponding values for the South Indian Ocean data were 69 and 97 % (0.38 and 0.02 Mm−1. A comparison with other studies in the area indicated an overestimation of their BC levels, by up to two orders of magnitude. This raises the necessity for chemical correction protocols on optical filter

  12. Study of ultraviolet-visible light absorbance of exfoliated graphite forms

    OpenAIRE

    S. Uran; A. Alhani; Silva, C.

    2017-01-01

    Despite the fact that there have been many studies of graphite exfoliation, none really addresses the issue of starting form of graphite. To address this issue various graphite forms (solid, powder and sooth) and graphite oxide (powder) are exfoliated in acetonitrile and studied via ultraviolet-visible (UV-Vis) spectroscopy. In different graphite forms two major absorbance peaks are observed at 223 nm and 273 nm corresponding to graphene oxide and graphene dispersions, respectively. The inten...

  13. Super-hydrophilic copper sulfide films as light absorbers for efficient solar steam generation under one sun illumination

    Science.gov (United States)

    Guo, Zhenzhen; Ming, Xin; Wang, Gang; Hou, Baofei; Liu, Xinghang; Mei, Tao; Li, Jinhua; Wang, Jianying; Wang, Xianbao

    2018-02-01

    Solar steam technology is one of the simplest, most direct and effective ways to harness solar energy through water evaporation. Here, we report the development using super-hydrophilic copper sulfide (CuS) films with double-layer structures as light absorbers for solar steam generation. In the double-layer structure system, a porous mixed cellulose ester (MCE) membrane is used as a supporting layer, which enables water to get into the CuS light absorbers through a capillary action to provide continuous water during solar steam generation. The super-hydrophilic property of the double-layer system (CuS/MCE) leads to a thinner water film close to the air-water interface where the surface temperature is sufficiently high, leading to more efficient evaporation (∼80 ± 2.5%) under one sun illumination. Furthermore, the evaporation efficiencies still keep a steady value after 15 cycles of testing. The super-hydrophilic CuS film is promising for practical application in water purification and evaporation as a light absorption material.

  14. Arctic climate response to forcing from light-absorbing particles in snow and sea ice in CESM

    Directory of Open Access Journals (Sweden)

    N. Goldenson

    2012-09-01

    Full Text Available The presence of light-absorbing aerosol particles deposited on arctic snow and sea ice influences the surface albedo, causing greater shortwave absorption, warming, and loss of snow and sea ice, lowering the albedo further. The Community Earth System Model version 1 (CESM1 now includes the radiative effects of light-absorbing particles in snow on land and sea ice and in sea ice itself. We investigate the model response to the deposition of black carbon and dust to both snow and sea ice. For these purposes we employ a slab ocean version of CESM1, using the Community Atmosphere Model version 4 (CAM4, run to equilibrium for year 2000 levels of CO2 and fixed aerosol deposition. We construct experiments with and without aerosol deposition, with dust or black carbon deposition alone, and with varying quantities of black carbon and dust to approximate year 1850 and 2000 deposition fluxes. The year 2000 deposition fluxes of both dust and black carbon cause 1–2 °C of surface warming over large areas of the Arctic Ocean and sub-Arctic seas in autumn and winter and in patches of Northern land in every season. Atmospheric circulation changes are a key component of the surface-warming pattern. Arctic sea ice thins by on average about 30 cm. Simulations with year 1850 aerosol deposition are not substantially different from those with year 2000 deposition, given constant levels of CO2. The climatic impact of particulate impurities deposited over land exceeds that of particles deposited over sea ice. Even the surface warming over the sea ice and sea ice thinning depends more upon light-absorbing particles deposited over land. For CO2 doubled relative to year 2000 levels, the climate impact of particulate impurities in snow and sea ice is substantially lower than for the year 2000 equilibrium simulation.

  15. Excess LIGHT contributes to placental impairment, increased secretion of vasoactive factors, hypertension, and proteinuria in preeclampsia.

    Science.gov (United States)

    Wang, Wei; Parchim, Nicholas F; Iriyama, Takayuki; Luo, Renna; Zhao, Cheng; Liu, Chen; Irani, Roxanna A; Zhang, Weiru; Ning, Chen; Zhang, Yujin; Blackwell, Sean C; Chen, Lieping; Tao, Lijian; Hicks, M John; Kellems, Rodney E; Xia, Yang

    2014-03-01

    Preeclampsia, a prevalent hypertensive disorder of pregnancy, is believed to be secondary to uteroplacental ischemia. Accumulating evidence indicates that hypoxia-independent mediators, including inflammatory cytokines and growth factors, are associated with preeclampsia, but it is unclear whether these signals directly contribute to placental damage and disease development in vivo. We report that LIGHT, a novel tumor necrosis factor superfamily member, is significantly elevated in the circulation and placentas of preeclamptic women compared with normotensive pregnant women. Injection of LIGHT into pregnant mice induced placental apoptosis, small fetuses, and key features of preeclampsia, hypertension and proteinuria. Mechanistically, using neutralizing antibodies specific for LIGHT receptors, we found that LIGHT receptors herpes virus entry mediator and lymphotoxin β receptor are required for LIGHT-induced placental impairment, small fetuses, and preeclampsia features in pregnant mice. Accordingly, we further revealed that LIGHT functions through these 2 receptors to induce secretion of soluble fms-like tyrosine kinase-1 and endothelin-1, 2 well-accepted pathogenic factors in preeclampsia, and thereby plays an important role in hypertension and proteinuria in pregnant mice. Lastly, we extended our animal findings to human studies and demonstrated that activation of LIGHT receptors resulted in increased apoptosis and elevation of soluble fms-like tyrosine kinase-1 secretion in human placental villous explants. Overall, our human and mouse studies show that LIGHT signaling is a previously unrecognized pathway responsible for placental apoptosis, elevated secretion of vasoactive factors, and subsequent maternal features of preeclampsia, and reveal new therapeutic opportunities for the management of the disease.

  16. The 750 GeV diphoton excess as a first light on supersymmetry breaking

    Directory of Open Access Journals (Sweden)

    J.A. Casas

    2016-08-01

    Full Text Available One of the most exciting explanations advanced for the recent diphoton excess found by ATLAS and CMS is in terms of sgoldstino decays: a signal of low-energy supersymmetry-breaking scenarios. The sgoldstino, a scalar, couples directly to gluons and photons, with strength related to gaugino masses, that can be of the right magnitude to explain the excess. However, fitting the suggested resonance width, Γ≃45 GeV, is not so easy. In this paper we explore efficient possibilities to enhance the sgoldstino width, via the decay into two Higgses, two Higgsinos and through mixing between the sgoldstino and the Higgs boson. In addition, we present an alternative and more efficient mechanism to generate a mass splitting between the scalar and pseudoscalar components of the sgoldstino, which has been suggested as an interesting alternative explanation to the apparent width of the resonance.

  17. Replication of the Apparent Excess Heat Effect in a Light Water-Potassium Carbonate-Nickel Electrolytic Cell

    Science.gov (United States)

    Niedra, Janis M.; Myers, Ira T.; Fralick, Gustave C.; Baldwin, Richard S.

    1996-01-01

    Replication of experiments claiming to demonstrate excess heat production in light water-Ni-K2CO3 electrolytic cells was found to produce an apparent excess heat of 11 W maximum, for 60 W electrical power into the cell. Power gains range from 1.06 to 1.68. The cell was operated at four different dc current levels plus one pulsed current run at 1 Hz, 10% duty cycle. The 28 liter cell used in these verification tests was on loan from a private corporation whose own tests with similar cells are documented to produce 50 W steady excess heat for a continuous period exceeding hundreds of days. The apparent excess heat can not be readily explained either in terms of nonlinearity of the cell's thermal conductance at a low temperature differential or by thermoelectric heat pumping. However, the present data do admit efficient recombination of dissolved hydrogen-oxygen as an ordinary explanation. Calorimetry methods and heat balance calculations for the verification tests are described. Considering the large magnitude of benefit if this effect is found to be a genuine new energy source, a more thorough investigation of evolved heat in the nickel-hydrogen system in both electrolytic and gaseous loading cells remains warranted.

  18. Study of ultraviolet-visible light absorbance of exfoliated graphite forms

    Directory of Open Access Journals (Sweden)

    S. Uran

    2017-03-01

    Full Text Available Despite the fact that there have been many studies of graphite exfoliation, none really addresses the issue of starting form of graphite. To address this issue various graphite forms (solid, powder and sooth and graphite oxide (powder are exfoliated in acetonitrile and studied via ultraviolet-visible (UV-Vis spectroscopy. In different graphite forms two major absorbance peaks are observed at 223 nm and 273 nm corresponding to graphene oxide and graphene dispersions, respectively. The intensity change of the peaks refers to the layer number change. The intensity ratios of these peaks give information about the concentration of the exfoliation products. We observed that graphite oxide sample has the thinnest graphene dispersions among the compared samples, whereas graphite rod has the thickest. It appears that few layer graphene oxide dispersions exist more in graphite sooth and graphite oxide samples. Graphite oxide UV-Vis spectrum reveals two new absorbance peaks at 312 nm and 361 nm in addition to the graphene oxide and graphene dispersion peaks. To our knowledge these peaks were not observed before. We think that these new peaks are formed due to conjugated polyenes that affect π → π* plasmon peak.

  19. Study of ultraviolet-visible light absorbance of exfoliated graphite forms

    Science.gov (United States)

    Uran, S.; Alhani, A.; Silva, C.

    2017-03-01

    Despite the fact that there have been many studies of graphite exfoliation, none really addresses the issue of starting form of graphite. To address this issue various graphite forms (solid, powder and sooth) and graphite oxide (powder) are exfoliated in acetonitrile and studied via ultraviolet-visible (UV-Vis) spectroscopy. In different graphite forms two major absorbance peaks are observed at 223 nm and 273 nm corresponding to graphene oxide and graphene dispersions, respectively. The intensity change of the peaks refers to the layer number change. The intensity ratios of these peaks give information about the concentration of the exfoliation products. We observed that graphite oxide sample has the thinnest graphene dispersions among the compared samples, whereas graphite rod has the thickest. It appears that few layer graphene oxide dispersions exist more in graphite sooth and graphite oxide samples. Graphite oxide UV-Vis spectrum reveals two new absorbance peaks at 312 nm and 361 nm in addition to the graphene oxide and graphene dispersion peaks. To our knowledge these peaks were not observed before. We think that these new peaks are formed due to conjugated polyenes that affect π → π* plasmon peak.

  20. Absorbance detector for high-performance liquid chromatography based on light-emitting diodes for the deep-ultraviolet range.

    Science.gov (United States)

    Bomastyk, Benjamin; Petrovic, Igor; Hauser, Peter C

    2011-06-17

    A HPLC-detector has been designed which employs light-emitting diodes in the deep-UV-range below 300 nm as wavelength specific radiation sources and special UV-photodiodes for measuring the signal. A monochromator is therefore not needed. The design features a beam splitter and a reference photodiode, precision mechanics for adjustment of the light beams and electronics for stabilization of the LED-current. The processing of the photodiode currents is carried out with a high performance log-ratio amplifier which allows direct absorbance measurements. The optical and electronic performance of the detector was characterised and high precision over several absorbance units was obtained. Testing of analytical separation methods in isocratic as well as gradient modes employing UV-detection at 255 and 280 nm showed a very similar performance to a commercial photodiode-array detector used in the fixed wavelength mode in terms of linearity, precision and detection limits. The chief advantages of the new device are small size, low power consumption, and low cost. Copyright © 2011 Elsevier B.V. All rights reserved.

  1. Raman Spectroscopy of Single Light-Absorbing Carbonaceous Particles Levitated in Air Using an Annular Laser Beam.

    Science.gov (United States)

    Uraoka, Masaru; Maegawa, Keisuke; Ishizaka, Shoji

    2017-12-05

    A laser trapping technique is a powerful means to investigate the physical and chemical properties of single aerosol particles in a noncontact manner. However, optical trapping of strongly light-absorbing particles such as black carbon or soot is quite difficult because the repulsive force caused by heat is orders of magnitude larger than the attractive force of radiation pressure. In this study, a laser trapping and Raman microspectroscopy system using an annular laser beam was constructed to achieve noncontact levitation of single light-absorbing particles in air. Single acetylene carbon black or candle soot particles were arbitrarily selected with a glass capillary connected to a three-axis oil hydraulic micromanipulator and introduced into a minute space surrounded by a repulsive force at the focal point of an objective lens. Using the developed system, we achieved optical levitation of micrometer-sized carbonaceous particles and observation of their Raman spectra in air. Furthermore, we demonstrated in situ observations of changes in the morphology and chemical composition of optically trapped carbonaceous particles in air, which were induced by heterogeneous oxidation reactions with ozone and hydroxyl radicals.

  2. Modeling and simulation of experimentally fabricated QDSSC using ZnS as light absorbing and blocking layer

    Science.gov (United States)

    Mehrabian, Masood; Dalir, Sina

    2017-07-01

    Abstract—Two main factors which limit the power conversion efficiency of solar cells are light absorption and recombination processes. In photovoltaic (PV) devices, low energy photons cannot be absorbed and excite electrons from valance band to conduction band, hence do not contribute to the current. On the other hand, high energy photons cannot be efficiently used due to a poor match to the energy gap. Existence of charge recombination in PV devices causes the low conversion performance, which is indicated by the low open-circuit voltage ( V OC ). Using a blocking layer in system could effectively reduce the recombination of charge carriers. In this study, we simulated a solar cell with ITO/ZnO/P3HT&PCBM/Ag structure. To prevent the charge recombination, a ZnS QD layer was used which acts as a light absorbing and a recombination blocking layer in the ITO/ZnO film/ZnS QD/P3HT&PCBM/Ag structure. The simulated J- V characteristics of solar cells showed a close match with the experimental results. Simulate data showed an increase of conversion efficiency in ZnS QDSSC from 1.71 to 3.10%, which is relatively 81.28% increase.

  3. The response of Hordeum spontaneum desert ecotype to drought and excessive light intensity is characterized by induction of O2 dependent photochemical activity and anthocyanin accumulation.

    Science.gov (United States)

    Eppel, Amir; Keren, Nir; Salomon, Eitan; Volis, Sergei; Rachmilevitch, Shimon

    2013-03-01

    The goal of the current research was to study the role of anthocyanin accumulation, O(2)-related photochemical processes and non-photochemical quenching (NPQ) in the response of desert and Mediterranean plants to drought and excessive light. Plants of Hordeum spontaneum were collected from Mediterranean and desert environments and were subjected to terminal drought for 25 days and then measured for PSII yield at 2 and 21% O(2), NPQ, net carbon assimilation, stomatal conductance, leaf relative water content (LRWC), anthocyanin concentration and leaf absorbance. Under terminal drought, LRWC, carbon assimilation and stomatal conductance decreased similarly and significantly in both the Mediterranean and the desert ecotypes. Anthocyanin accumulated more in the desert ecotype than in the Mediterranean ecotype. NPQ increased more in the Mediterranean ecotype as compared with the desert ecotype. PSII yield decreased significantly in the Mediterranean ecotype under drought and was much lower than in the desert ecotype under drought. The relatively high PSII yield under drought in the desert ecotype was O(2) dependent. The response of the H. spontaneum ecotype from a desert environment to drought stress was characterized by anthocyanin accumulation and induction of O(2) dependent photochemical activity, while the response of the Mediterranean ecotype was based on a higher induction of NPQ. Copyright © 2012 Elsevier Ireland Ltd. All rights reserved.

  4. Laser generation of shock waves in a water suspension with light-absorbing particles.

    Science.gov (United States)

    Besaga, Vira R; Maksimyak, Andrew P; Maksimyak, Peter P

    2014-04-01

    We report the generation of shock waves in a disperse medium with absorbing particles of black pigment in the water using continuous laser radiation. As a result of the experimental investigation it was found that the illuminating beam diameter growth at the constant laser power results in the decrease of the signals' modulation frequencies, improving their stability and increasing their amplitudes. In turn, the decrease of the signal's modulation frequency is caused by the growth of time, which is needed for heating the medium to the critical temperature of cavitation. Improving the stability and the increase of optical and acoustic signal amplitudes take place, due to the growth of the medium volume and hence the number of pigment particles that participate in cavitation.

  5. Absorbance detector based on a deep UV light emitting diode for narrow-column HPLC.

    Science.gov (United States)

    Bui, Duy Anh; Bomastyk, Benjamin; Hauser, Peter C

    2013-10-01

    A detector for miniaturized HPLC based on deep UV emitting diodes and UV photodiodes was constructed. The measurement is accomplished by the transverse passage of the radiation from the light-emitting diode (LED) through fused-silica tubing with an internal diameter of 250 μm. The optical cell allows flexible alignment of the LED, tubing, and photodiode for optimization of the light throughput and has an aperture to block stray light. A beam splitter was employed to direct part of the emitted light to a reference photodiode and the Lambert-Beer law was emulated with a log-ratio amplifier circuitry. The detector was tested with two LEDs with emission bands at 280 and 255 nm and showed noise levels as low as 0.25 and 0.22 mAU, respectively. The photometric device was employed successfully in separations using a column of 1 mm inner diameter in isocratic as well as gradient elution. Good linearities over three orders of magnitude in concentration were achieved, and the precision of the measurements was better than 1% in all cases. Detection down to the low micromolar range was possible. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Absorbance detector for capillary electrophoresis based on light-emitting diodes and photodiodes for the deep-ultraviolet range.

    Science.gov (United States)

    Bui, Duy Anh; Hauser, Peter C

    2015-11-20

    A new absorbance detector for capillary electrophoresis featuring relatively high intensity light-emitting diodes as radiation sources and photodiodes for the deep-UV range was developed. The direct relationship of absorbance values and concentrations was obtained by emulating Lambert-Beer's law with the application of a beam splitter to obtain a reference signal and a log-ratio amplifier circuitry. The performance of the cell was investigated at 255 nm with the detection of sulfanilic, 4-nitrobenzoic, 4-hydroxybenzoic and 4-aminobenzoic acid and the indirect detection of acetate, propionate, butyrate and caproate using benzoate as the displacement dye molecule. Vanillic acid, L-tyrosine and DL-tryptophan as well as the sulfonamides sulfamerazine, sulfathiazole and sulfamethazine were determined at 280 nm. Good linearities over 3 orders of magnitude were obtained. The noise level recorded was as low as 50 μAU and the drift typically <200 μAU/5 min. Copyright © 2015 Elsevier B.V. All rights reserved.

  7. Instrumentation and method for measuring NIR light absorbed in tissue during MR imaging in medical NIRS measurements

    Science.gov (United States)

    Myllylä, Teemu S.; Sorvoja, Hannu S. S.; Nikkinen, Juha; Tervonen, Osmo; Kiviniemi, Vesa; Myllylä, Risto A.

    2011-07-01

    Our goal is to provide a cost-effective method for examining human tissue, particularly the brain, by the simultaneous use of functional magnetic resonance imaging (fMRI) and near-infrared spectroscopy (NIRS). Due to its compatibility requirements, MRI poses a demanding challenge for NIRS measurements. This paper focuses particularly on presenting the instrumentation and a method for the non-invasive measurement of NIR light absorbed in human tissue during MR imaging. One practical method to avoid disturbances in MR imaging involves using long fibre bundles to enable conducting the measurements at some distance from the MRI scanner. This setup serves in fact a dual purpose, since also the NIRS device will be less disturbed by the MRI scanner. However, measurements based on long fibre bundles suffer from light attenuation. Furthermore, because one of our primary goals was to make the measuring method as cost-effective as possible, we used high-power light emitting diodes instead of more expensive lasers. The use of LEDs, however, limits the maximum output power which can be extracted to illuminate the tissue. To meet these requirements, we improved methods of emitting light sufficiently deep into tissue. We also show how to measure NIR light of a very small power level that scatters from the tissue in the MRI environment, which is characterized by strong electromagnetic interference. In this paper, we present the implemented instrumentation and measuring method and report on test measurements conducted during MRI scanning. These measurements were performed in MRI operating rooms housing 1.5 Tesla-strength closed MRI scanners (manufactured by GE) in the Dept. of Diagnostic Radiology at the Oulu University Hospital.

  8. Origin of the low-mass electron pair excess in light nucleus-nucleus collisions

    Science.gov (United States)

    Agakichiev, G.; Balanda, A.; Belver, D.; Belyaev, A. V.; Blanco, A.; Böhmer, M.; Boyard, J. L.; Braun-Munzinger, P.; Cabanelas, P.; Castro, E.; Chernenko, S.; Christ, T.; Destefanis, M.; Díaz, J.; Dohrmann, F.; Dybczak, A.; Fabbietti, L.; Fateev, O. V.; Finocchiaro, P.; Fonte, P.; Friese, J.; Fröhlich, I.; Galatyuk, T.; Garzón, J. A.; Gernhäuser, R.; Gil, A.; Gilardi, C.; Göbel, K.; Golubeva, M.; González-Díaz, D.; Guber, F.; Hennino, T.; Holzmann, R.; Iori, I.; Ivashkin, A.; Jurkovic, M.; Kämpfer, B.; Karavicheva, T.; Kirschner, D.; Koenig, I.; Koenig, W.; Kolb, B. W.; Kotte, R.; Krizek, F.; Krücken, R.; Kühn, W.; Kugler, A.; Kurepin, A.; Lang, S.; Lange, J. S.; Lapidus, K.; Liu, T.; Lopes, L.; Lorenz, M.; Maier, L.; Mangiarotti, A.; Markert, J.; Metag, V.; Michalska, B.; Michel, J.; Morinière, E.; Mousa, J.; Müntz, C.; Naumann, L.; Otwinowski, J.; Pachmayer, Y. C.; Palka, M.; Parpottas, Y.; Pechenov, V.; Pechenova, O.; Pietraszko, J.; Przygoda, W.; Ramstein, B.; Reshetin, A.; Rustamov, A.; Sadovsky, A.; Salabura, P.; Schmah, A.; Schwab, E.; Sobolev, Yu. G.; Spataro, S.; Spruck, B.; Ströbele, H.; Stroth, J.; Sturm, C.; Sudol, M.; Tarantola, A.; Teilab, K.; Tlusty, P.; Traxler, M.; Trebacz, R.; Tsertos, H.; Wagner, V.; Weber, M.; Wisniowski, M.; Wojcik, T.; Wüstenfeld, J.; Yurevich, S.; Zanevsky, Y. V.; Zhou, P.; HADES Collaboration

    2010-06-01

    We report measurements of electron pair production in elementary p+p and d+p reactions at 1.25 GeV/u with the HADES spectrometer. For the first time, the electron pairs were reconstructed for n+p reactions by detecting the proton spectator from the deuteron breakup. We find that the yield of electron pairs with invariant mass M>0.15 GeV/c2 is about an order of magnitude larger in n+p reactions as compared to p+p. A comparison to model calculations demonstrates that the production mechanism is not sufficiently described yet. The electron pair spectra measured in C+C reactions are compatible with a superposition of elementary n+p and p+p collisions, leaving little room for additional electron pair sources in such light collision systems.

  9. Highly predictable photosynthetic production in natural macroalgal communities from incoming and absorbed light

    DEFF Research Database (Denmark)

    Middelboe, Anne Lise; Sand-Jensen, Kaj; Binzer, Thomas

    2006-01-01

    height and species richness. The close relationship of community photosynthesis to irradiance is due to the fact that (1) large differences in thallus photosynthesis of individual species are averaged out in communities composed of several species, (2) seasonal replacement of species keeps communities......Photosynthesis-irradiance relationships of macroalgal communities and thalli of dominant species in shallow coastal Danish waters were measured over a full year to test how well community production can be predicted from environmental (incident irradiance and temperature) and community variables...... (canopy absorptance, species number and thallus metabolism). Detached thalli of dominant species performed optimally at different times of the year, but showed no general seasonal changes in photosynthetic features. Production capacity of communities at high light varied only 1.8-fold over the year...

  10. Crash compatibility between cars and light trucks: benefits of lowering front-end energy-absorbing structure in SUVs and pickups.

    Science.gov (United States)

    Baker, Bryan C; Nolan, Joseph M; O'Neill, Brian; Genetos, Alexander P

    2008-01-01

    Passenger vehicles are designed to absorb crash energy in frontal crashes through deformation or crush of energy-absorbing structures forward of the occupant compartment. In collisions between cars and light trucks (i.e., pickups and SUVs), however, the capacity of energy-absorption structures may not be fully utilized because mismatches often exist between the heights of these structures in the colliding vehicles. In 2003 automakers voluntarily committed to new design standards aimed at reducing the height mismatches between cars and light trucks. By September 2009 all new light trucks will have either the primary front structure (typically the frame rails) or a secondary structure connected to the primary structure low enough to interact with the primary structures in cars, which for most cars is about the height of the front bumper. To estimate the overall benefit of the voluntary commitment, the real-world crash experience of light trucks already meeting the height-matching criteria was compared with that of light trucks not meeting the criteria for 2000-2003 model light trucks in collisions with passenger cars during calendar years 2001-2004. The estimated benefits of lower front energy-absorbing structure were a 19 percent reduction (pcar drivers in front-to-front crashes with light trucks and a 19 percent reduction (pcar drivers in front-to-driver-side crashes with light trucks.

  11. Properties of black carbon and other insoluble light-absorbing particles in seasonal snow of northwestern China

    Science.gov (United States)

    Pu, Wei; Wang, Xin; Wei, Hailun; Zhou, Yue; Shi, Jinsen; Hu, Zhiyuan; Jin, Hongchun; Chen, Quanliang

    2017-05-01

    A large field campaign was conducted and 284 snow samples were collected at 38 sites in Xinjiang Province and 6 sites in Qinghai Province across northwestern China from January to February 2012. A spectrophotometer combined with chemical analysis was used to measure the insoluble light-absorbing particles (ILAPs) and chemical components in seasonal snow. The results indicate that the cleanest snow was found in northeastern Xinjiang along the border of China, and it presented an estimated black carbon (CBCest) of approximately 5 ng g-1. The dirtiest snow presented a CBCest of approximately 450 ng g-1 near industrial cities in Xinjiang. Overall, the CBCest of most of the snow samples collected in this campaign was in the range of 10-150 ng g-1. Vertical variations in the snowpack ILAPs indicated a probable shift in emission sources with the progression of winter. An analysis of the fractional contributions to absorption implied that organic carbon (OC) dominated the 450 nm absorption in Qinghai, while the contributions from BC and OC were comparable in Xinjiang. Finally, a positive matrix factorization (PMF) model was run to explore the sources of particulate light absorption, and the results indicated an optimal three-factor/source solution that included industrial pollution, biomass burning, and soil dust.

  12. Absorbance detector for high performance liquid chromatography based on a deep-UV light-emitting diode at 235nm.

    Science.gov (United States)

    da Silveira Petruci, João Flavio; Liebetanz, Michael G; Cardoso, Arnaldo Alves; Hauser, Peter C

    2017-08-25

    In this communication, we describe a flow-through optical absorption detector for HPLC using for the first time a deep-UV light-emitting diode with an emission band at 235nm as light source. The detector is also comprised of a UV-sensitive photodiode positioned to enable measurement of radiation through a flow-through cuvette with round aperture of 1mm diameter and optical path length of 10mm, and a second one positioned as reference photodiode; a beam splitter and a power supply. The absorbance was measured and related to the analyte concentration by emulating the Lambert-Beer law with a log-ratio amplifier circuitry. This detector showed noise levels of 0.30mAU, which is comparable with our previous LED-based detectors employing LEDs at 280 and 255nm. The detector was coupled to a HPLC system and successfully evaluated for the determination of the anti-diabetic drugs pioglitazone and glimepiride in an isocratic separation and the benzodiazepines flurazepam, oxazepam and clobazam in a gradient elution. Good linearities (r>0.99), a precision better than 0.85% and limits of detection at sub-ppm levels were achieved. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Identification of light absorbing oligomers from glyoxal and methylglyoxal aqueous processing: a comparative study at the molecular level

    Science.gov (United States)

    Finessi, Emanuela; Hamilton, Jacqueline; Rickard, Andrew; Baeza-Romero, Maria; Healy, Robert; Peppe, Salvatore; Adams, Tom; Daniels, Mark; Ball, Stephen; Goodall, Iain; Monks, Paul; Borras, Esther; Munoz, Amalia

    2014-05-01

    Numerous studies point to the reactive uptake of gaseous low molecular weight carbonyls onto atmospheric waters (clouds/fog droplets and wet aerosols) as an important SOA formation route not yet included in current models. However, the evaluation of these processes is challenging because water provides a medium for a complex array of reactions to take place such as self-oligomerization, aldol condensation and Maillard-type browning reactions in the presence of ammonium salts. In addition to adding to SOA mass, aqueous chemistry products have been shown to include light absorbing, surface-active and high molecular weight oligomeric species, and can therefore affect climatically relevant aerosol properties such as light absorption and hygroscopicity. Glyoxal (GLY) and methylglyoxal (MGLY) are the gaseous carbonyls that have perhaps received the most attention to date owing to their ubiquity, abundance and reactivity in water, with the majority of studies focussing on bulk physical properties. However, very little is known at the molecular level, in particular for MGLY, and the relative potential of these species as aqueous SOA precursors in ambient air is still unclear. We have conducted experiments with both laboratory solutions and chamber-generated particles to simulate the aqueous processing of GLY and MGLY with ammonium sulphate (AS) under typical atmospheric conditions and investigated their respective aging products. Both high performance liquid chromatography coupled with UV-Vis detection and ion trap mass spectrometry (HPLC-DAD-MSn) and high resolution mass spectrometry (FTICRMS) have been used for molecular identification purposes. Comprehensive gas chromatography with nitrogen chemiluminescence detection (GCxGC-NCD) has been applied for the first time to these systems, revealing a surprisingly high number of nitrogen-containing organics (ONs), with a large extent of polarities. GCxGC-NCD proved to be a valuable tool to determine overall amount and rates of

  14. Measurement of the light absorbing properties of diesel exhaust particles using a three-wavelength photoacoustic spectrometer

    Science.gov (United States)

    Guo, Xuesong; Nakayama, Tomoki; Yamada, Hiroyuki; Inomata, Satoshi; Tonokura, Kenichi; Matsumi, Yutaka

    2014-09-01

    Diesel-exhaust particles (DEP) are one of the main anthropogenic sources of black carbon (BC) and organic matter (OM). Understanding the optical properties of DEP, including the enhancement of light absorption by BC due to coating and light absorption by OM, is important for evaluating the climate impact of DEP. In this study, a three-wavelength photoacoustic soot spectrometer (405, 532, and 781 nm) was used to investigate the wavelength-dependent optical properties of DEP emitted from a diesel engine vehicle running on a chassis dynamometer in transient driving mode (JE-05) and at a constant speed (either idling or driving at 70 km/h). Optical properties were measured after passing the diluted exhaust through a heater, set at 20, 47, or 300 °C (transient driving mode) or between 20 and 400 °C (constant driving mode). The OM accounted for, on average, ∼40 and ∼35% of the total mass concentration of DEP during the transient and constant driving modes, respectively. In transient driving mode, enhancements of scattering coefficients at 20 and 47 °C, and of the mass concentration of organics, were observed during the high-speed driving period (∼80 km/h) corresponding to driving on a highway. No difference was observed in the absorption coefficients between heated and unheated particles at 781 nm for either the transient (including the high-speed driving period) or constant driving modes. These results indicate a lack of enhancement due to the lensing effect, possibly because the BC was mainly mixed externally with the OM or because it was located at the edges of particles under these experimental conditions. Contributions to total light absorption at 405 nm by the OM were estimated by comparing the wavelength dependence of the absorption coefficients with and without heating. A significant contribution by light-absorbing OM (20 ± 7%) to total light absorption at 405 nm was observed during the high-speed driving period of the JE-05 mode, while the

  15. The effects of emission control strategies on light-absorbing carbon emissions from a modern heavy-duty diesel engine.

    Science.gov (United States)

    Robinson, Michael A; Olson, Michael R; Liu, Z Gerald; Schauer, James J

    2015-06-01

    Control of atmospheric black carbon (BC) and brown carbon (BrC) has been proposed as an important pathway to climate change mitigation, but sources of BC and BrC are still not well understood. In order to better identify the role of modern heavy-duty diesel engines on the production of BC and BrC, emissions from a heavy-duty diesel engine operating with different emission control strategies were examined using a source dilution sampling system. The effect of a diesel oxidation catalyst (DOC) and diesel particulate filter (DPF) on light-absorbing carbon (LAC) was evaluated at three steady-state engine operation modes: idle, 50% speed and load, and 100% speed and load. LAC was measured with four different engine configurations: engine out, DOC out, DPF out, and engine out with an altered combustion calibration. BC and BrC emission rates were measured with the Aethalometer (AE-31). EC and BC emission rates normalized to the mass of CO₂emitted increased with increasing engine speed and load. Emission rates normalized to brake-specific work did not exhibit similar trends with speed and load, but rather the highest emission rate was measured at idle. EC and OC emissions were reduced by 99% when the DOC and DPF architecture was applied. The application of a DPF was equally effective at removing 99% of the BC fraction of PM, proving to be an important control strategy for both LAC and PM. BC emissions were unexpectedly increased across the DOC, seemingly due to a change aerosol optical properties. Removal of exhaust gas recirculation (EGR) flow due to simulated EGR cooler failure caused a large increase in OC and BrC emission rates at idle, but had limited influence during high load operation. LAC emissions proved to be sensitive to the same control strategies effective at controlling the total mass of diesel PM. In the context of black carbon emissions, very small emission rates of brown carbon were measured over a range of control technologies and engine operating

  16. A feasibility study of mapping light-absorbing carbon using a taxi fleet as a mobile platform

    Directory of Open Access Journals (Sweden)

    Patricia Krecl

    2014-04-01

    Full Text Available Carbon-containing particles are associated with adverse health effects, and their light-absorbing fractions were recently estimated to be the second largest contributor to global warming after carbon dioxide. Knowledge on the spatiotemporal variability of light-absorbing carbon (LAC particles in urban areas is relevant for air quality management and to better diagnose the population exposure to these particles. This work reports on the first mobile LAC mass concentrations (MLAC measured on-board four taxis in the Stockholm metropolitan area in November 2011. On average, concentrations were higher and more variable during daytime (median of 1.9 µg m−3 and median absolute deviation of 2.3 µg m−3. Night-time (21:00–05:00 measurements were very similar for all road types and also compared to levels monitored at an urban background fixed site (median of 0.9 µg m−3. We observed a large intra-urban variability in concentrations, with maxima levels inside road tunnels (median and 95th percentile of 7.5 and 40.1 µg m−3, respectively. Highways presented the second ranked concentrations (median and 95th percentile of 3.2 and 9.7 µg m−3, respectively associated with highest vehicle speed (median of 65 km h−1, traffic rates (median of 62 000 vehicles day−1 and 1500 vehicles h−1 and diesel vehicles share (7–10% when compared to main roads, canyon streets, and local roads. Multiple regression modelling identified hourly traffic rate and MLAC concentration measured at an urban background site as the best predictors of on-road concentrations, but explained only 25% of the observed variability. This feasibility study proved to be a time- and cost-effective approach to map out ambient MLAC concentrations in Stockholm and more research is required to represent the distribution in other periods of the year. Simultaneous monitoring of other pollutants, closely correlated to MLAC levels in traffic-polluted environments, and including video

  17. In situ aerosol optics in Reno, NV, USA during and after the summer 2008 California wildfires and the influence of absorbing and non-absorbing organic coatings on spectral light absorption

    Directory of Open Access Journals (Sweden)

    M. Gyawali

    2009-10-01

    Full Text Available Hundreds of wildfires in Northern California were sparked by lightning during the summer of 2008, resulting in downwind smoke for the months of June and July. Comparisons are reported for aerosol optics measurements in Reno, Nevada made during the very smoky month of July and the relatively clean month of August. Photoacoustic instruments equipped with integrating nephelometers were used to measure aerosol light scattering and absorption coefficients at wavelengths of 405 nm and 870 nm, revealing a strong variation of aerosol light absorption with wavelength. Insight on fuels burned is gleaned from comparison of Ångström exponents of absorption (AEA versus single scattering albedo (SSA of the ambient measurements with laboratory biomass smoke measurements for many fuels. Measurements during the month of August, which were largely unaffected by fire smoke, exhibit surprisingly low AEA for aerosol light absorption when the SSA is highest, again likely as a consequence of the underappreciated wavelength dependence of aerosol light absorption by particles coated with non-absorbing organic and inorganic matter. Coated sphere calculations were used to show that AEA as large as 1.6 are possible for wood smoke even with non-absorbing organic coatings on black carbon cores, suggesting care be exercised when diagnosing AEA.

  18. Search for scalar dark matter via pseudoscalar portal interactions in light of the Galactic Center gamma-ray excess

    Science.gov (United States)

    Yang, Kwei-Chou

    2018-01-01

    In light of the observed Galactic center gamma-ray excess, we investigate a simplified model, for which the scalar dark matter interacts with quarks through a pseudoscalar mediator. The viable regions of the parameter space, that can also account for the relic density and evade the current searches, are identified, if the low-velocity dark matter annihilates through an s -channel off shell mediator mostly into b ¯b , and/or annihilates directly into two hidden on shell mediators, which subsequently decay into the quark pairs. These two kinds of annihilations are s wave. The projected monojet limit set by the high luminosity LHC sensitivity could constrain the favored parameter space, where the mediator's mass is larger than the dark matter mass by a factor of 2. We show that the projected sensitivity of 15-year Fermi-LAT observations of dwarf spheroidal galaxies can provide a stringent constraint on the most parameter space allowed in this model. If the on shell mediator channel contributes to the dark matter annihilation cross sections over 50%, this model with a lighter mediator can be probed in the projected PICO-500L experiment.

  19. Effects of a hindered amine light stabilizer and a UV light absorber used in maxillofacial elastomers on human gingival epithelial cells and fibroblasts.

    Science.gov (United States)

    Tipton, David A; Lewis, J West

    2008-09-01

    Ultraviolet light absorber (UVA) and hindered amine light stabilizer (HALS) retard sun-induced pigment degradation in silicone elastomeric maxillofacial prostheses. HALS inhibits polymer degradation and UVA dissipates UV radiation. Their effects on oral cells are unknown. The purpose of this study was to evaluate the effects of UVA and HALS on membrane integrity, viability, and proliferation of human gingival fibroblasts and epithelial cells. Tinuvin 123 (HALS) and Tinuvin 213 (UVA) were assessed for cytotoxicity, individually and in a 1:1 ratio (used in elastomers; HALS/UVA). The cells were exposed to HALS, UVA, or HALS/UVA (or control media containing only the diluent), and colorimetric assays measured membrane damage, viability, and proliferation. The data (% cytotoxicity or % control) were analyzed using 3-way cross-classified fixed effects ANOVA (alpha=.05). HALS did not negatively affect either cell type. UVA or HALS/UVA (>or= approximately 0.004%) decreased viability by >or=90% in both cell lines; lower concentrations decreased activity in epithelial cells while increasing it in fibroblasts. UVA or HALS/UVA damaged membranes of both cell lines, but epithelial cells were more resistant. UVA or HALS/UVA inhibited proliferation of both cell types similarly. There was a slight synergistic effect of HALS and UVA on membrane damage in both cell lines, but generally not on other parameters. Although it is unknown if HALS or UVA leaches from silicone elastomers in vivo, these data suggest that relative resistance of epithelial cells to UVA-induced membrane damage, and UVA's stimulation of fibroblast viability at some concentrations, might provide some protective effect.

  20. Characterization of light-absorbing carbon particles at three altitudes in East Asian outflow by transmission electron microscopy

    Directory of Open Access Journals (Sweden)

    J. Zhu

    2013-07-01

    Full Text Available The morphology, microstructure, and composition of the submicron fraction of individual light-absorbing carbon (LAC particles collected by research aircraft during the ACE-Asia (Asian Pacific Regional Aerosol Characterization Experiment project above the Yellow Sea at altitudes of 120, 450 and 1500 m are investigated by transmission electron microscopy (TEM, and energy dispersive X-ray spectroscopy (EDS. Two types of carbonaceous particles, small spherule soot with graphitic spherules and amorphous carbonaceous spheres (brown carbon, are found at all altitudes in high concentration. For soot particles, emphasis of the study is on the component subparticles (spherules. The nanoscopic structures of the small spherule soot show no significant difference at three altitudes although the size distribution of primary spherules showed that 70% of the total volume lies in the ranges 30–50, 50–85 and 30–50 nm, respectively. For the amorphous carbonaceous spheres, 70% of the total volume from three altitudes lies in the range 200–350, 160–470 and 150–320 nm, respectively. Within the size fraction studied (submicron, with most particles in the range 50 to 500 nm the number concentration ratios of the amorphous carbonaceous spheres to primary spherules in soot at altitudes of 120, 450 and 1500 m are about 1, 1.5 and 10, respectively and their volume ratios are about 260, 50 and 1400. Lower relative concentrations of large spherule soot with intermediate graphitic structure were observed at 120 m. Also, low relative number concentrations of carbon cenospheres were observed at 120 and 1500 m. A key result of the study is that in vertically stratified outflow from East Asia, the character of LAC may have strong variance with altitude thus resulting in optical characteristics that vary with altitude. Also, apparent "aging" of LAC deduced from samples at multiple ground stations may instead reflect differences in the original carbon aerosols.

  1. Characterization of light-absorbing carbon particles at three altitudes in East Asian outflow by transmission electron microscopy

    Science.gov (United States)

    Zhu, J.; Crozier, P. A.; Anderson, J. R.

    2013-07-01

    The morphology, microstructure, and composition of the submicron fraction of individual light-absorbing carbon (LAC) particles collected by research aircraft during the ACE-Asia (Asian Pacific Regional Aerosol Characterization Experiment) project above the Yellow Sea at altitudes of 120, 450 and 1500 m are investigated by transmission electron microscopy (TEM), and energy dispersive X-ray spectroscopy (EDS). Two types of carbonaceous particles, small spherule soot with graphitic spherules and amorphous carbonaceous spheres (brown carbon), are found at all altitudes in high concentration. For soot particles, emphasis of the study is on the component subparticles (spherules). The nanoscopic structures of the small spherule soot show no significant difference at three altitudes although the size distribution of primary spherules showed that 70% of the total volume lies in the ranges 30-50, 50-85 and 30-50 nm, respectively. For the amorphous carbonaceous spheres, 70% of the total volume from three altitudes lies in the range 200-350, 160-470 and 150-320 nm, respectively. Within the size fraction studied (submicron, with most particles in the range 50 to 500 nm) the number concentration ratios of the amorphous carbonaceous spheres to primary spherules in soot at altitudes of 120, 450 and 1500 m are about 1, 1.5 and 10, respectively and their volume ratios are about 260, 50 and 1400. Lower relative concentrations of large spherule soot with intermediate graphitic structure were observed at 120 m. Also, low relative number concentrations of carbon cenospheres were observed at 120 and 1500 m. A key result of the study is that in vertically stratified outflow from East Asia, the character of LAC may have strong variance with altitude thus resulting in optical characteristics that vary with altitude. Also, apparent "aging" of LAC deduced from samples at multiple ground stations may instead reflect differences in the original carbon aerosols.

  2. Measurements of light-absorbing particles in snow across the Arctic, North America, and China: Effects on surface albedo

    Science.gov (United States)

    Dang, Cheng; Warren, Stephen G.; Fu, Qiang; Doherty, Sarah J.; Sturm, Matthew; Su, Jing

    2017-10-01

    Using field observations, we perform radiative transfer calculations on snowpacks in the Arctic, China, and North America to quantify the impact of light-absorbing particles (LAPs) on snow albedo and its sensitivity to different factors. For new snow, the regional-averaged albedo reductions caused by all LAPs in the Arctic, North America, and China are 0.009, 0.012, and 0.077, respectively, of which the albedo reductions caused by black carbon (BC) alone are 0.005, 0.005, and 0.031, corresponding to a positive radiative forcing of 0.06, 0.3, and 3 W m-2. For the same particulate concentrations, the albedo reduction for old melting snow is larger than that of new snow by a factor of 2; this leads to 3-8 times larger radiative forcing, in part due to higher solar irradiance in the melting season. These calculations used ambient snowpack properties; if all snowpacks were instead assumed to be optically thick, the albedo reduction would be 20-50% larger for new snow in the Arctic and North America and 120-300% larger for old snow. Accounting for non-BC LAPs reduces the albedo reduction by BC in the Arctic, North America, and China by 32%, 29%, and 70%, respectively, for new snow and 11%, 7%, and 51% for old snow. BC-in-snow albedo reduction computed using a two-layer model agrees reasonably with that computed using a multilayer model. Biases in BC concentration or snow depth often lead to nonlinear biases in BC-induced albedo reduction.

  3. Light-absorbing impurities in a southern Tibetan Plateau glacier: Variations and potential impact on snow albedo and radiative forcing

    Science.gov (United States)

    Li, Xiaofei; Kang, Shichang; Zhang, Guoshuai; Qu, Bin; Tripathee, Lekhendra; Paudyal, Rukumesh; Jing, Zhefan; Zhang, Yulan; Yan, Fangping; Li, Gang; Cui, Xiaoqing; Xu, Rui; Hu, Zhaofu; Li, Chaoliu

    2018-02-01

    Light-absorbing impurities (LAIs), such as organic carbon (OC), black carbon (BC), and mineral dust (MD), deposited on the surface snow of glacier can reduce the surface albedo. As there exists insufficient knowledge to completely characterize LAIs variations and difference in LAIs distributions, it is essential to investigate the behaviors of LAIs and their influence on the glaciers across the Tibetan Plateau (TP). Therefore, surface snow and snowpit samples were collected during September 2014 to September 2015 from Zhadang (ZD) glacier in the southern TP to investigate the role of LAIs in the glacier. LAIs concentrations were observed to be higher in surface aged snow than in the fresh snow possibly due to post-depositional processes such as melting or sublimation. The LAIs concentrations showed a significant spatial distribution and marked negative relationship with elevation. Impurity concentrations varied significantly with depth in the vertical profile of the snowpit, with maximum LAIs concentrations frequently occurred in the distinct dust layers which were deposited in non-monsoon, and the bottom of snowpit due to the eluviation in monsoon. Major ions in snowpit and backward trajectory analysis indicated that regional activities and South Asian emissions were the major sources. According to the SNow ICe Aerosol Radiative (SNICAR) model, the average simulated albedo caused by MD and BC in aged snow collected on 31 May 2015 accounts for about 13% ± 3% and 46% ± 2% of the albedo reduction. Furthermore, we also found that instantaneous RF caused by MD and BC in aged snow collected on 31 May 2015 varied between 4-16 W m- 2 and 7-64 W m- 2, respectively. The effect of BC exceeds that of MD on albedo reduction and instantaneous RF in the study area, indicating that BC played a major role on the surface of the ZD glacier.

  4. The formation of light absorbing insoluble organic compounds from the reaction of biomass burning precursors and Fe(III)

    Science.gov (United States)

    Lavi, Avi; Lin, Peng; Bhaduri, Bhaskar; Laskin, Alexander; Rudich, Yinon

    2017-04-01

    Dust particles and volatile organic compounds from fuel or biomass burning are two major components that affect air quality in urban polluted areas. We characterized the products from the reaction of soluble Fe(III), a reactive transition metal originating from dust particles dissolution processes, with phenolic compounds , namely, guaiacol, syringol, catechol, o- and p- cresol that are known products of incomplete fuel and biomass combustion but also from other natural sources such as humic compounds degradation. We found that under acidic conditions comparable to those expected on a dust particle surface, phenolic compounds readily react with dissolved Fe(III), leading to the formation of insoluble polymeric compounds. We characterized the insoluble products by x-ray photoelectron microscopy, UV-Vis spectroscopy, mass spectrometry, elemental analysis and thermo-gravimetric analysis. We found that the major chromophores formed are oligomers (from dimers to pentamers) of the reaction precursors that efficiently absorb light between 300nm and 500nm. High variability of the mass absorption coefficient of the reaction products was observed with catechol and guaiacol showing high absorption at the 300-500nm range that is comparable to that of brown carbon (BrC) from biomass burning studies. The studied reaction is a potential source for the in-situ production of secondary BrC material under dark conditions. Our results suggest a reaction path for the formation of bio-available iron in coastal polluted areas where dust particles mix with biomass burning pollution plumes. Such mixing can occur, for instance in the coast of West Africa or North Africa during dust and biomass burning seasons

  5. The Effects of UV Light on the Chemical and Mechanical Properties of a Transparent Epoxy-Diamine System in the Presence of an Organic UV Absorber

    Science.gov (United States)

    Nikafshar, Saeid; Zabihi, Omid; Ahmadi, Mojtaba; Mirmohseni, Abdolreza; Taseidifar, Mojtaba; Naebe, Minoo

    2017-01-01

    Despite several excellent properties including low shrinkage, good chemical resistance, curable at low temperatures and the absence of byproducts or volatiles, epoxy resins are susceptible to ultra violet (UV) damage and their durability is reduced substantially when exposed to outdoor environments. To overcome this drawback, UV absorbers have been usually used to decrease the rate of UV degradation. In this present study, the effects of UV light on the chemical, mechanical and physical properties of cured epoxy structure, as well as the effect of an organic UV absorber, Tinuvin 1130, on the epoxy properties were investigated. Chemical changes in a cured epoxy system as a result of the presence and absence of Tinuvin 1130 were determined using Fourier transform infrared spectroscopy (FT-IR) analyses. The effect of Tinuvin 1130 on the surface morphology of the epoxy systems was also investigated by scanning electron microscopy (SEM) imaging. Additionally, the glass transition temperatures (Tg) before and during UV radiation were measured. After an 800 h UV radiation, mechanical test results revealed that the lack of the UV absorber can lead to a ~30% reduction in tensile strength. However, in the presence of Tinuvin 1130, the tensile strength was reduced only by ~11%. It was hypothesized that the use of Tinuvin 1130, as an organic UV absorber in the epoxy-amine system, could decrease the undesirable effects, arising from exposure to UV light. PMID:28772538

  6. Picosecond blue light pulse generation by frequency doubling of a gain-switched GaAlAs laser diode with saturable absorbers

    Energy Technology Data Exchange (ETDEWEB)

    Ohya, J.; Tohmon, G.; Yamamoto, K.; Taniuchi, T. (Semiconductor Research Center, Matsushita Electric Industrial Co., Ltd., Moriguchi, Osaka 570, (JapaN)); Kume, M. (Electronics Research Laboratory, Matsushita Electronics Corporation, Takatsuki, Osaka 569, (Japan))

    1990-06-04

    Picosecond blue light pulse generation by frequency doubling of a gain-switched GaAlAs laser diode in a proton-exchanged MgO:LiNbO{sub 3} waveguide is reported. High-peak fundamental pulse power of 1.23 W is obtained by employing a laser diode with saturable absorbers. Blue light pulse of 7.88 mW maximum peak power and 28.7 ps pulse width is generated in the form of Cherenkov radiation.

  7. Diffraction of intensity-modulated light in strongly scattering media in the presence of a "semi-infinite" absorbing or reflecting plane bounded by a straight edge

    Science.gov (United States)

    Fishkin, Joshua B.; Gratton, Enrico

    1992-04-01

    A simple model is developed, based on the diffusion approximation to the linear transport equation, which gives analytic expressions that describe the coherent propagation of sinusoidally intensity-modulated light through a strongly scattering, low absorbing, homogeneous, infinite medium in terms of the interaction coefficients of the medium. Previously, the analytical multiform solutions to Laplace's equation and the Helmholtz equation were derived respectively by Sommerfeld and Carslaw in their studies of electrostatics, sound, and heat to model intensity modulated light in the presence of an absorbing or reflecting `semi-infinite' plane bounded by a straight edge that is immersed in an infinite, strongly scattering, low absorbing, homogeneous medium. The model predictions are in good agreement with the present results of experiments performed on media consisting of IntralipidTM and skim milk emulsions containing minute quantities of black India ink and with Monte Carlo simulations. These studies provide a theoretical basis for the understanding of photon diffusion in tissues and allow the determination of conditions to obtain maximum resolution and penetration.

  8. Investigating the effect and uncertainties of light absorbing impurities in snow and ice on snow melt and discharge generation using a hydrologic catchment model and satellite data

    Science.gov (United States)

    Matt, Felix; Burkhart, John F.

    2017-04-01

    Light absorbing impurities in snow and ice (LAISI) originating from atmospheric deposition enhance snow melt by increasing the absorption of short wave radiation. The consequences are a shortening of the snow cover duration due to increased snow melt and, with respect to hydrologic processes, a temporal shift in the discharge generation. However, the magnitude of these effects as simulated in numerical models have large uncertainties, originating mainly from uncertainties in the wet and dry deposition of light absorbing aerosols, limitations in the model representation of the snowpack, and the lack of observable variables required to estimate model parameters and evaluate the simulated variables connected with the representation of LAISI. This leads to high uncertainties in the additional energy absorbed by the snow due to the presence of LAISI, a key variable in understanding snowpack energy-balance dynamics. In this study, we assess the effect of LAISI on snow melt and discharge generation and the involved uncertainties in a high mountain catchment located in the western Himalayas by using a distributed hydrological catchment model with focus on the representation of the seasonal snow pack. The snow albedo is hereby calculated from a radiative transfer model for snow, taking the increased absorption of short wave radiation by LAISI into account. Meteorological forcing data is generated from an assimilation of observations and high resolution WRF simulations, and LAISI mixing ratios from deposition rates of Black Carbon simulated with the FLEXPART model. To asses the quality of our simulations and the related uncertainties, we compare the simulated additional energy absorbed by the snow due to the presence of LAISI to the MODIS Dust Radiative Forcing in Snow (MODDRFS) algorithm satellite product.

  9. True-time delay by slow light in a semiconductor waveguide with alternating amplifying and absorbing sections

    DEFF Research Database (Denmark)

    Öhman, Filip; Mørk, Jesper

    2006-01-01

    Modeling of slow light in a semiconductor waveguide with alternating gain and absorption sections demonstrate an increase in time delay by concatenating segments. A true-time delay is predicted over a large bandwidth at high frequency.......Modeling of slow light in a semiconductor waveguide with alternating gain and absorption sections demonstrate an increase in time delay by concatenating segments. A true-time delay is predicted over a large bandwidth at high frequency....

  10. Simultaneous Retrieval of Effective Refractive Index and Density from Size Distribution and Light Scattering Data: Weakly-Absorbing Aerosol

    Energy Technology Data Exchange (ETDEWEB)

    Kassianov, Evgueni I.; Barnard, James C.; Pekour, Mikhail S.; Berg, Larry K.; Shilling, John E.; Flynn, Connor J.; Mei, Fan; Jefferson, Anne

    2014-10-01

    We propose here a novel approach for retrieving in parallel the effective density and real refractive index of weakly absorbing aerosol from optical and size distribution measurements. Here we define “weakly absorbing” as aerosol single-scattering albedos that exceed 0.95 at 0.5 um.The required optical measurements are the scattering coefficient and the hemispheric backscatter fraction, obtained in this work from an integrating nephelometer. The required size spectra come from a Scanning Mobility Particle Sizer and an Aerodynamic Particle Sizer. The performance of this approach is first evaluated using a sensitivity study with synthetically generated but measurement-related inputs. The sensitivity study reveals that the proposed approach is robust to random noise; additionally the uncertainties of the retrieval are almost linearly proportional to the measurement errors, and these uncertainties are smaller for the real refractive index than for the effective density. Next, actual measurements are used to evaluate our approach. These measurements include the optical, microphysical, and chemical properties of weakly absorbing aerosol which are representative of a variety of coastal summertime conditions observed during the Two-Column Aerosol Project (TCAP; http://campaign.arm.gov/tcap/). The evaluation includes calculating the root mean square error (RMSE) between the aerosol characteristics retrieved by our approach, and the same quantities calculated using the conventional volume mixing rule for chemical constituents. For dry conditions (defined in this work as relative humidity less than 55%) and sub-micron particles, a very good (RMSE~3%) and reasonable (RMSE~28%) agreement is obtained for the retrieved real refractive index (1.49±0.02) and effective density (1.68±0.21), respectively. Our approach permits discrimination between the retrieved aerosol characteristics of sub-micron and sub-10micron particles. The evaluation results also reveal that the

  11. An interference coating of metamaterial as an ultrathin light absorber in the violet-to-infrared regime.

    Science.gov (United States)

    Jen, Yi-Jun; Lin, Meng-Jie; Wu, Huang-Ming; Liao, Hung-Sheng; Dai, Jia-Wei

    2013-04-22

    A metamaterial with brief and ultrathin structure performs high efficiency in light absorption. An upright aluminum nanorod array (Al NRA) is obliquely deposited, measured, and analyzed its optical property. The Al NRA performs high efficiency of light absorption and low reflectance simultaneously. Based on the measured refractive index and impedances, the wave propagation through the Al NRA is traced to demonstrate the destructive interference that leads to antireflection. According to the analysis of wave tracing, an Al semicontinuous film with thickness of 15nm is introduced under an Al NRA with thickness of only 245nm as a brief and thin two-layered structure. The broadband and polarization-independent light absorption is measured over the violet-to-infrared regime.

  12. Photodynamic therapy with decacationic [60]fullerene monoadducts: effect of a light absorbing electron-donor antenna and micellar formulation.

    Science.gov (United States)

    Yin, Rui; Wang, Min; Huang, Ying-Ying; Huang, Huang-Chiao; Avci, Pinar; Chiang, Long Y; Hamblin, Michael R

    2014-05-01

    We report the synthesis and anticancer photodynamic properties of two new decacationic fullerene (LC14) and red light-harvesting antenna-fullerene conjugated monoadduct (LC15) derivatives. The antenna of LC15 was attached covalently to C60>with distance of only synthesis and the photodynamic properties of two new derivatives for cancer treatment; one is a decacationic fullerene (LC14) and the other is a red light-harvesting antenna-fullerene conjugated monoadduct (LC15) utilizing a HeLa cell model. Copyright © 2014 Elsevier Inc. All rights reserved.

  13. Photodynamic therapy with decacationic [60]fullerene monoadducts: effect of a light absorbing electron-donor antenna and micellar formulation

    Science.gov (United States)

    Yin, Rui; Wang, Min; Huang, Ying-Ying; Huang, Huang-Chiao; Avci, Pinar; Chiang, Long Y; Hamblin, Michael R

    2014-01-01

    We report the synthesis and anticancer photodynamic properties of two new decacationic fullerene (LC14) and red light-harvesting antenna-fullerene conjugated monoadduct (LC15) derivatives. The antenna of LC15 was attached covalently to C60> with distance of only <3.0 Ǻ to facilitate ultrafast intramolecular photoinduced-electron-transfer (for type-I photochemistry) and photon absorption at longer wavelengths. Because LC15 was hydrophobic we compared formulation in CremophorEL micelles with direct dilution from dimethylacetamide. LC14 produced more 1O2 than LC15, while LC15 produced much more HO· than LC14 as measured by specific fluorescent probes. When delivered by DMA, LC14 killed more HeLa cells than LC15 when excited by UVA light, while LC15 killed more cells when excited by white light consistent with the antenna effect. However LC15 was more effective than LC14 when delivered by micelles regardless of the excitation light. Micellar delivery produced earlier apoptosis and damage to the endoplasmic reticulum as well as to lysosomes and mitochondria. PMID:24333585

  14. The Effects of Brazilian Green Propolis against Excessive Light-Induced Cell Damage in Retina and Fibroblast Cells

    Directory of Open Access Journals (Sweden)

    Hiromi Murase

    2013-01-01

    Full Text Available Background. We investigated the effects of Brazilian green propolis and its constituents against white light- or UVA-induced cell damage in mouse retinal cone-cell line 661W or human skin-derived fibroblast cells (NB1-RGB. Methods. Cell damage was induced by 3,000lx white light for 24 h or 4/10 J/cm2 UVA exposure. Cell viability was assessed by Hoechst33342 and propidium iodide staining or by tetrazolium salt (WST-8 cell viability assay. The radical scavenging activity of propolis induced by UVA irradiation in NB1-RGB cells was measured using a reactive-oxygen-species- (ROS- sensitive probe CM-H2DCFDA. Moreover, the effects of propolis on the UVA-induced activation of p38 and extracellular signal-regulated kinase (ERK were examined by immunoblotting. Results. Treatment with propolis and two dicaffeoylquinic acids significantly inhibited the decrease in cell viability induced by white light in 661W. Propolis and its constituents inhibited the decrease in cell viability induced by UVA in NB1-RGB. Moreover, propolis suppressed the intracellular ROS production by UVA irradiation. Propolis also inhibited the levels of phosphorylated-p38 and ERK by UVA irradiation. Conclusion. Brazilian green propolis may become a major therapeutic candidate for the treatment of AMD and skin damage induced by UV irradiation.

  15. Anisotropic Spin Transport and Strong Visible-Light Absorbance in Few-Layer SnSe and GeSe.

    Science.gov (United States)

    Shi, Guangsha; Kioupakis, Emmanouil

    2015-10-14

    SnSe and GeSe are layered compound semiconductors that can be exfoliated to form two-dimensional materials. In this work, we use predictive calculations based on density functional and many-body perturbation theory to study the electronic and optical properties of single-layer, double-layer, and bulk SnSe and GeSe. The fundamental band gap is direct in single-layer and double-layer GeSe, but indirect in single-layer and double-layer SnSe. Moreover, the interplay of spin-orbit coupling and lack of inversion symmetry in the monolayer structures results in anisotropic spin splitting of the energy bands, with potential applications in directionally dependent spin transport. We also show that single-layer and double-layer SnSe and GeSe exhibit unusually strong optical absorbance in the visible range. Our results suggest that single-layer and double-layer SnSe and GeSe are promising materials for ultrathin-film photovoltaic applications with theoretical upper bounds to the conversion efficiency that approach the efficiency records realized in organic and dye-sensitized solar cells.

  16. Xanthopterin in the Oriental hornet (Vespa orientalis): light absorbance is increased with maturation of yellow pigment granules.

    Science.gov (United States)

    Plotkin, Marian; Volynchik, Stanislav; Ermakov, Natalya Y; Benyamini, Avishai; Boiko, Yulia; Bergman, David J; Ishay, Jacob S

    2009-01-01

    The Oriental hornet bears both brown and yellow colors on its cuticle. The brown component is contributed by the pigment melanin, which is dispersed in the brown cuticle and provides protection against insolation, while the yellow-colored part contains within pockets in the cuticle granules possessing a yellow pigment. These yellow granules (YG) are formed about 2 days prior to eclosion of the imago, and their production continues for about 3 days posteclosion. Xanthopterin is the main component of the granule and lends it its yellow color. Xanthopterin produces a characteristic excitation/emission maximum at 386/456 nm. Characterization by use of mass spectrometry showed the compound to have a molecular ion of 179, as expected from xanthopterin. Spectroscopic examination of the absorption of an entire stripe of yellow cuticle in the course of its metamorphosis revealed that the absorption steadily increases throughout the process to a maximal level of absorption about 3 days posteclosion. In the absence of the YG, the cuticle is permeable to the passage of all wavelengths within the visible range and to the UV range (290-750 nm) in all age groups of hornets. The newly ecloded hornets depart the nest to engage in activities requiring exposure to insolation only as the process of granule formation terminates, namely, when the layer of YG in the cuticle suffices to absorb all the harmful UV radiation.

  17. Enhancement of near-infrared detectability from InGaZnO thin film transistor with MoS2 light absorbing layer

    Science.gov (United States)

    Pak, Sang Woo; Chu, Dongil; Song, Da Ye; Kyo Lee, Seung; Kim, Eun Kyu

    2017-11-01

    We report an enhancement of near-infrared (NIR) detectability from amorphous InGaZnO (α-IGZO) thin film transistor in conjunction with randomly distributed molybdenum disulfide (MoS2) flakes. The electrical characteristics of the α-IGZO grown by radio-frequency magnetron sputtering exhibit high effective mobility exceeding 15 cm2 V‑1 s‑1 and current on/off ratio up to 107. By taking advantages of the high quality α-IGZO and MoS2 light absorbing layer, photodetection spectra are able to extend from ultra-violet to NIR range. The α-IGZO channel detector capped by MoS2 show a photo-responsivity of approximately 14.9 mA W‑1 at 1100 nm wavelength, which is five times higher than of the α-IGZO device without MoS2 layer.

  18. Excessive somnolence

    Directory of Open Access Journals (Sweden)

    Stella Tavares

    Full Text Available Excessive somnolence can be quite a incapacitating manifestation, and is frequently neglected by physicians and patients. This article reviews the determinant factors, the evaluation and quantification of diurnal somnolence, and the description and treatment of the main causes of excessive somnolence.

  19. Excessive somnolence.

    Science.gov (United States)

    Tavares, S; Alóe, F; Gentil, V; Scaff, M

    1996-01-01

    Excessive somnolence can be quite a incapacitating manifestation, and is frequently neglected by physicians and patients. This article reviews the determinant factors, the evaluation and quantification of diurnal somnolence, and the description and treatment of the main causes of excessive somnolence.

  20. Blue LED light as a new hygienic problem

    OpenAIRE

    V.A. Kaptsov; V.N. Deinego

    2016-01-01

    The conditions for the formation of an excess dose of blue light produced by the LED lighting were examined. It is shown that light-biological safety assessment carried out in accordance with GOST R IEC 62471-2013 need to be clarified, taking into account changes in the pupil of eye’s diameters when LED lighting and spatial distribution of the light-absorbing blue light (460 nm) of the pigment in the macula influences it. Methodical principles of calculation of an excess dose of blue light in...

  1. Synthesis and characterization of visible light absorbing (GaN)(1-x)(ZnO)x semiconductor nanorods.

    Science.gov (United States)

    Reinert, Alexandra A; Payne, Candace; Wang, Limin; Ciston, James; Zhu, Yimei; Khalifah, Peter G

    2013-08-05

    Although the (GaN)(1-x)(ZnO)x solid solution is one of the most effective systems for driving overall solar water splitting with visible light, its quantum yield for overall water splitting using visible light photons has not yet reached ten percent. Understanding and controlling the nanoscale morphology of this system may allow its overall conversion efficiency to be raised to technologically relevant levels. We describe the use a Ga2O3(ZnO)16 precursor phase in the synthesis of this phase which naturally results in the production of arrays of nanorods with favorable diameters (∼100 nm) and band gaps (∼2.5 eV). Substantial absorption within the band gap is observed, part of which is found to follow the E(-3) scaling characteristic of free carriers scattered by ionized impurity sites. Compositional analysis suggests that a substantial quantity of cation vacancies (∼3%) may be present in some samples. The typical nanorod growth direction and dominant {1011} facet for powders in this system have been identified through electron microscopy methods, leading to the conclusion that polarity may play an important role in the high photoactivity of this family of wurtzite semiconductors.

  2. Light-absorbing soluble organic aerosol in Los Angeles and Atlanta: A contrast in secondary organic aerosol

    Science.gov (United States)

    Zhang, Xiaolu; Lin, Ying-Hsuan; Surratt, Jason D.; Zotter, Peter; Prévôt, Andre S. H.; Weber, Rodney J.

    2011-11-01

    Light absorption spectra and carbon mass of fine particle water-soluble components were measured during the summer of 2010 in the Los Angeles (LA) basin, California, and Atlanta, Georgia. Fresh LA secondary organic carbon had a consistent brown color and a bulk absorption per soluble carbon mass at 365 nm that was 4 to 6 times higher than freshly-formed Atlanta soluble organic carbon. Radiocarbon measurements of filter samples show that LA secondary organic aerosol (SOA) was mainly from fossil carbon and chemical analysis of aqueous filter extracts identified nitro-aromatics as one component of LA brown SOA. Interpreting soluble brown carbon as a property of freshly-formed anthropogenic SOA, the difference in absorption per carbon mass between these two cities suggests most fresh secondary water-soluble organic carbon formed within Atlanta is not from an anthropogenic process similar to LA. Contrasting emissions of biogenic volatile organic compounds may account for these differences.

  3. A newly isolated Chlorella sp. from desert sand crusts exhibits a unique resistance to excess light intensity.

    Science.gov (United States)

    Treves, Haim; Raanan, Hagai; Finkel, Omri M; Berkowicz, Simon M; Keren, Nir; Shotland, Yoram; Kaplan, Aaron

    2013-12-01

    We recently isolated a small green alga from a biological sand crust (BSC) in the NW Negev, Israel. Based on its 18S rRNA and rbcL genes, it is a close relative of Chlorella sorokiniana and of certain strains of C. vulgaris and C. variabilis, but differs substantially in many aspects from C. sorokiniana. Because the classification of Chlorellales is still not resolved, we designated this species as C. ohadii (Trebouxiophyceae) in honor of Professor Itzhak Ohad. Under controlled laboratory conditions, C. ohadii showed marked structural and photosynthetic performance changes, depending on the carbon source used during growth, as well as remarkable resistance to photoinhibition. CO2 -dependent O2 evolution was not affected even when exposed to a light intensity of 3500 μmole photons m(-2)  s(-1) , over 1.5 times the maximal intensity reached at the BSC surface, whereas the variable fluorescence declined sharply. We briefly discuss the use of fluorescence to assess photosynthetic rate and the implications of this finding for the assessment of global BSCs activity. © 2013 Federation of European Microbiological Societies. Published by John Wiley & Sons Ltd. All rights reserved.

  4. Perovskite semiconductor La(Ni{sub 0.75}W{sub 0.25})O{sub 3} nanoparticles for visible-light-absorbing photocatalytic material

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Lei; Xie, Hongde, E-mail: xiehongde@suda.edu.cn; Pu, Yinfu; Huang, Yanlin [Soochow University, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science (China); Qin, Lin; Seo, Hyo Jin, E-mail: hjseo@pknu.ac.kr [Pukyong National University, Department of Physics and Interdisciplinary Program of Biomedical, Mechanical & Electrical Engineering (Korea, Republic of)

    2017-01-15

    La(Ni{sub 0.75}W{sub 0.25})O{sub 3} perovskite oxide was prepared via the sol–gel Pechini route. The pure crystalline phase was verified via X-ray diffraction measurements and Rietveld structure refinements. Some measurements were applied to characterize the surface of the nanoparticles such as transmission electron microscopy, scanning electron microscope, energy-dispersive X-ray spectroscopy, specific surface area, and X-ray photo-electron spectroscopy measurements. The optical measurement confirmed that this perovskite oxide can absorb the visible light presenting low band energy of 2.41 eV. The d–d allowed transitions in Ni{sup 2+}-O octahedral have great contributions to the narrow band-gap. The Ni{sup 2+}-containing perovskite was applied as a photocatalyst showing the desirable photodegradation ability for methylene blue solutions under the excitation of visible-light. The photocatalysis activities were discussed in the relationship with its special perovskite-type structure such as the NiO{sub 6} color centers and multivalent cation ions etc.

  5. The 8Be excess and search for the X → e+e− decay of a new light boson with NA64 detector

    CERN Document Server

    Gninenko, Sergei

    2017-01-01

    The X → e+e− decay of a new short-lived neutral boson X with a mass mX = 16.7 MeV and coupling to electrons in the range 10−4 < εe < 10−3 could explain the excess of e+e− pairs recently observed in the excited 8Be nucleus decays. If such X’s exist, they could be searched for in a light-shining-through-a-wall experiment with a high energy electron beam. The electron energy absorption in a calorimeter (WCAL) is accompanied by the emission of bremsstrahlung X’s in the reaction eZ → eZX of electrons scattering on nuclei due to the e−X coupling. A part of the primary beam energy is deposited in the WCAL, while the rest of the energy is transmitted by the X through the ”WCAL wall” and deposited in another downstream calorimeter ECAL by the e+e− pair from the X → e+e− decay in flight. Thus, the X’s could be observed by looking for an excess of events with the two-shower signature generated by a single high energy electron in the WCAL and ECAL. In October 2016 NA64 took a short ru...

  6. High Photon-to-Current Conversion in Solar Cells Based on Light-Absorbing Silver Bismuth Iodide.

    Science.gov (United States)

    Zhu, Huimin; Pan, Mingao; Johansson, Malin B; Johansson, Erik M J

    2017-06-22

    Here, a lead-free silver bismuth iodide (AgI/BiI 3 ) with a crystal structure with space group R3‾ m is investigated for use in solar cells. Devices based on the silver bismuth iodide deposited from solution on top of TiO 2 and the conducting polymer poly(3-hexylthiophene-2,5-diyl) (P3HT) as a hole-transport layer are prepared and the photovoltaic performance is very promising with a power conversion efficiency over 2 %, which is higher than the performance of previously reported bismuth-halide materials for solar cells. Photocurrent generation is observed between 350 and 700 nm, and the maximum external quantum efficiency is around 45 %. The results are compared to solar cells based on the previously reported material AgBi 2 I 7 , and we observe a clearly higher performance for the devices with the new silver and bismuth iodides composition and different crystal structure. The X-ray diffraction spectrum of the most efficient silver bismuth iodide material shows a hexagonal crystal structure with space group R3‾ m, and from the light absorption spectrum we obtain an indirect band gap energy of 1.62 eV and a direct band gap energy of 1.85 eV. This report shows the possibility for finding new structures of metal-halides efficient in solar cells and points out new directions for further exploration of lead-free metal-halide solar cells. © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

  7. Sound Absorbers

    Science.gov (United States)

    Fuchs, H. V.; Möser, M.

    Sound absorption indicates the transformation of sound energy into heat. It is, for instance, employed to design the acoustics in rooms. The noise emitted by machinery and plants shall be reduced before arriving at a workplace; auditoria such as lecture rooms or concert halls require a certain reverberation time. Such design goals are realised by installing absorbing components at the walls with well-defined absorption characteristics, which are adjusted for corresponding demands. Sound absorbers also play an important role in acoustic capsules, ducts and screens to avoid sound immission from noise intensive environments into the neighbourhood.

  8. Parameterization of light scattering for solving the inverse problem of determining the concentrations of the principal light scattering and absorbing admixtures in shelf waters

    Directory of Open Access Journals (Sweden)

    Vadim N. Pelevin

    2001-12-01

    Full Text Available A method for estimating the water backscattering coefficient was put forward on the basis of experimental data of diffuse attenuation coefficient for downwelling irradiance and irradiance reflectance. Calculations were carried out for open sea waters of different types and the spectral dependencies were found ("anomalous" spectra and explained. On this basis, a new model of light backscattering on particles in the sea is proposed. This model may be useful for modelling remote sensing reflectance spectra in order to solve the inverse problems of estimating the concentration of natural admixtures in shelf waters.

  9. Temperature Dependence of Light-Induced Absorbance Changes Associated with Chlorophyll Photooxidation in Manganese-Depleted Core Complexes of Photosystem II.

    Science.gov (United States)

    Zabelin, A A; Shkuropatova, V A; Shkuropatov, A Ya; Shuvalov, V A

    2015-10-01

    Mid-infrared (4500-1150 cm(-1)) absorbance changes induced by continuous illumination of Mn-depleted core complexes of photosystem II (PSII) from spinach in the presence of exogenous electron acceptors (potassium ferricyanide and silicomolybdate) were studied by FTIR difference spectroscopy in the temperature range 100-265 K. The FTIR difference spectrum for photooxidation of the chlorophyll dimer P680 was determined from the set of signals associated with oxidation of secondary electron donors (β-carotene, chlorophyll) and reduction of the primary quinone QA. On the basis of analysis of the temperature dependence of the P680(+)/P680 FTIR spectrum, it was concluded that frequencies of 13(1)-keto-C=O stretching modes of neutral chlorophyll molecules PD1 and PD2, which constitute P680, are similar to each other, being located at ~1700 cm(-1). This together with considerable difference between the stretching mode frequencies of keto groups of PD1(+) and PD2(+) cations (1724 and 1709 cm(-1), respectively) is in agreement with a literature model (Okubo et al. (2007) Biochemistry, 46, 4390-4397) suggesting that the positive charge in the P680(+) dimer is mainly localized on one of the two chlorophyll molecules. A partial delocalization of the charge between the PD1 and PD2 molecules in P680(+) is supported by the presence of a characteristic electronic intervalence band at ~3000 cm(-1). It is shown that a bleaching band at 1680 cm(-1) in the P680(+)/P680 FTIR spectrum does not belong to P680. A possible origin of this band is discussed, taking into account the temperature dependence (100-265 K) of light-induced absorbance changes of PSII core complexes in the visible spectral region from 620 to 720 nm.

  10. Au nanorod design as light-absorber in the first and second biological near-infrared windows for in vivo photothermal therapy.

    Science.gov (United States)

    Tsai, Ming-Fong; Chang, Shih-Hui Gilbert; Cheng, Fong-Yu; Shanmugam, Vijayakumar; Cheng, Yu-Sheng; Su, Chia-Hao; Yeh, Chen-Sheng

    2013-06-25

    Photothermal cancer therapy using near-infrared (NIR) laser radiation is an emerging treatment. In the NIR region, two biological transparency windows are located in 650-950 nm (first NIR window) and 1000-1350 nm (second NIR window) with optimal tissue transmission obtained from low scattering and energy absorption, thus providing maximum radiation penetration through tissue and minimizing autofluorescence. To date, intensive effort has resulted in the generation of various methods that can be used to shift the absorbance of nanomaterials to the 650-950 nm NIR regions for studying photoinduced therapy. However, NIR light absorbers smaller than 100 nm in the second NIR region have been scant. We report that a Au nanorod (NR) can be designed with a rod-in-shell (rattle-like) structure smaller than 100 nm that is tailored to be responsive to the first and second NIR windows, in which we can perform hyperthermia-based therapy. In vitro performance clearly displays high efficacy in the NIR photothermal destruction of cancer cells, showing large cell-damaged area beyond the laser-irradiated area. This marked phenomenon has made the rod-in-shell structure a promising hyperthermia agent for the in vivo photothermal ablation of solid tumors when activated using a continuous-wave 808 m (first NIR window) or a 1064 nm (second NIR window) diode laser. We tailored the UV-vis-NIR spectrum of the rod-in-shell structure by changing the gap distance between the Au NR core and the AuAg nanoshell, to evaluate the therapeutic effect of using a 1064 nm diode laser. Regarding the first NIR window with the use of an 808 nm diode laser, rod-in-shell particles exhibit a more effective anticancer efficacy in the laser ablation of solid tumors compared to Au NRs.

  11. A new method to determine the mixing state of light absorbing carbonaceous using the measured aerosol optical properties and number size distributions

    Directory of Open Access Journals (Sweden)

    N. Ma

    2012-03-01

    Full Text Available In this paper, the mixing state of light absorbing carbonaceous (LAC was investigated with a two-parameter aerosol optical model and in situ aerosol measurements at a regional site in the North China Plain (NCP. A closure study between the hemispheric backscattering fraction (HBF measured by an integrating nephelometer and that calculated with a modified Mie model was conducted. A new method was proposed to retrieve the ratio of the externally mixed LAC mass to the total mass of LAC (rext-LAC based on the assumption that the ambient aerosol particles were externally mixed and consisted of a pure LAC material and a core-shell morphology in which the core is LAC and the shell is a less absorbing material. A Monte Carlo simulation was applied to estimate the overall influences of input parameters of the algorithm to the retrieved rext-LAC. The diurnal variation of rext-LAC was analyzed and the PartMC-MOSAIC model was used to simulate the variation of the aerosol mixing state. Results show that, for internally mixed particles, the assumption of core-shell mixture is more appropriate than that of homogenous mixture which has been widely used in aerosol optical calculations. A significant diurnal pattern of the retrieved rext-LAC was found, with high values during the daytime and low values at night. The consistency between the retrieved rext-LAC and the model results indicates that the diurnal variation of LAC mixing state is mainly caused by the diurnal evolution of the mixing layer.

  12. Syntheses, structures and photoelectrochemical properties of three water-stable, visible light absorbing mental-organic frameworks based on tetrakis(4-carboxyphenyl)silane and 1,4-bis(pyridyl)benzene mixed ligands

    Science.gov (United States)

    Guo, Tiantian; Yang, Xiaowei; Li, Ruyan; Liu, Xiaoyu; Gao, Yanling; Dai, Zhihui; Fang, Min; Liu, Hong-Ke; Wu, Yong

    2017-09-01

    Photovoltaics (PV), which directly convert solar energy into electricity generally using semiconductors, offer a practical and sustainable solution to the current energy shortage and environmental pollution crisis. Photovoltaic applications of metal-organic frameworks (MOFs) belong to a relatively new area of research. Given that UV light accounts for only 4% while visible light contributes 43% of solar energy, it is rather imperative to develop semiconductors with narrow band gaps so that they could absorb visible light. In this work, three water-stable, narrow band semiconducting MOFs of [Cu(H2TCS)(H2O)] (1), [Co(H2TCS)(BPB)] (2) and [Ni(H2TCS)(BPB)] (3) were synthesized using tetrakis(4-carboxyphenyl)silane (H4TCS) and 1,4-bis (pyridyl)benzene (BPB) in water, and structurally characterized by single-crystal X-ray diffractions. MOF 1 has a 2D structure. MOF 2 and 3 are isostructrual and have 3D frameworks formed by interwoven 2D layers. All three MOFs are stable in acidic water solutions and can be stable in water for 7 days. MOFs 1-3 absorb UV and visible light and have band gaps of 0.50, 1.77 and 1.49 eV, respectively. Rapid and stable photocurrent responses of MOFs 1-3 under UV and visible light illuminations are observed. This work demonstrates that using electron rich Cu2+, Co2+, or Ni2+ as metal nodes can effectively decrease the band gaps of MOFs to make them absorbing visible light. To increase the conjugation in the linker is generally considered to be the method to decrease the band gap of MOFs. The conjugation in H4TCS is not significant and this ligand basically only absorbs UV light. However, by using electron rich Cu2+ ions as metal nodes, the prepared [Cu(H2TCS)(H2O)]·H2O (1) absorbs broadly in the visible light region. Thus, this work suggests that by using electron rich Cu2+, many narrow-band semiconductor MOFs can be prepared even by using ligands which only absorbs UV light.

  13. Enantiomeric Excesses Induced in Amino Acids by Ultraviolet Circularly Polarized Light Irradiation of Extraterrestrial Ice Analogs: A Possible Source of Asymmetry for Prebiotic Chemistry

    Science.gov (United States)

    Modica, Paola; Meinert, Cornelia; de Marcellus, Pierre; Nahon, Laurent; Meierhenrich, Uwe J.; Le Sergeant d'Hendecourt, Louis

    2014-06-01

    The discovery of meteoritic amino acids with enantiomeric excesses of the L-form (ee L) has suggested that extraterrestrial organic materials may have contributed to prebiotic chemistry and directed the initial occurrence of the ee L that further led to homochirality of amino acids on Earth. A proposed mechanism for the origin of ee L in meteorites involves an asymmetric photochemistry of extraterrestrial ices by UV circularly polarized light (CPL). We have performed the asymmetric synthesis of amino acids on achiral extraterrestrial ice analogs by VUV CPL, investigating the chiral asymmetry transfer at two different evolutionary stages at which the analogs were irradiated (regular ices and/or organic residues) and at two different photon energies (6.6 and 10.2 eV). We identify 16 distinct amino acids and precisely measure the L-enantiomeric excesses using the enantioselective GC × GC-TOFMS technique in five of them: α-alanine, 2,3-diaminopropionic acid, 2-aminobutyric acid, valine, and norvaline, with values ranging from ee L = -0.20% ± 0.14% to ee L = -2.54% ± 0.28%. The sign of the induced ee L depends on the helicity and the energy of CPL, but not on the evolutionary stage of the samples, and is the same for all five considered amino acids. Our results support an astrophysical scenario in which the solar system was formed in a high-mass star-forming region where icy grains were irradiated during the protoplanetary phase by an external source of CPL of a given helicity and a dominant energy, inducing a stereo-specific photochemistry.

  14. Enantiomeric excesses induced in amino acids by ultraviolet circularly polarized light irradiation of extraterrestrial ice analogs: A possible source of asymmetry for prebiotic chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Modica, Paola; De Marcellus, Pierre; D' Hendecourt, Louis Le Sergeant [Univ. Paris-Sud, Institut d' Astrophysique Spatiale, UMR 8617, F-91405 Orsay (France); Meinert, Cornelia; Meierhenrich, Uwe J. [Univ. Nice Sophia Antipolis, Institut de Chimie de Nice, UMR 7272 CNRS, F-06108 Nice (France); Nahon, Laurent, E-mail: laurent.nahon@synchrotron-soleil.fr, E-mail: ldh@ias.u-psud.fr [Synchrotron SOLEIL, F-91192 Gif-sur-Yvette (France)

    2014-06-10

    The discovery of meteoritic amino acids with enantiomeric excesses of the L-form (ee {sub L}) has suggested that extraterrestrial organic materials may have contributed to prebiotic chemistry and directed the initial occurrence of the ee {sub L} that further led to homochirality of amino acids on Earth. A proposed mechanism for the origin of ee {sub L} in meteorites involves an asymmetric photochemistry of extraterrestrial ices by UV circularly polarized light (CPL). We have performed the asymmetric synthesis of amino acids on achiral extraterrestrial ice analogs by VUV CPL, investigating the chiral asymmetry transfer at two different evolutionary stages at which the analogs were irradiated (regular ices and/or organic residues) and at two different photon energies (6.6 and 10.2 eV). We identify 16 distinct amino acids and precisely measure the L-enantiomeric excesses using the enantioselective GC × GC-TOFMS technique in five of them: α-alanine, 2,3-diaminopropionic acid, 2-aminobutyric acid, valine, and norvaline, with values ranging from ee {sub L} = –0.20% ± 0.14% to ee {sub L} = –2.54% ± 0.28%. The sign of the induced ee {sub L} depends on the helicity and the energy of CPL, but not on the evolutionary stage of the samples, and is the same for all five considered amino acids. Our results support an astrophysical scenario in which the solar system was formed in a high-mass star-forming region where icy grains were irradiated during the protoplanetary phase by an external source of CPL of a given helicity and a dominant energy, inducing a stereo-specific photochemistry.

  15. Automated Phase Mapping with AgileFD and its Application to Light Absorber Discovery in the V-Mn-Nb Oxide System.

    Science.gov (United States)

    Suram, Santosh K; Xue, Yexiang; Bai, Junwen; Le Bras, Ronan; Rappazzo, Brendan; Bernstein, Richard; Bjorck, Johan; Zhou, Lan; van Dover, R Bruce; Gomes, Carla P; Gregoire, John M

    2017-01-09

    Rapid construction of phase diagrams is a central tenet of combinatorial materials science with accelerated materials discovery efforts often hampered by challenges in interpreting combinatorial X-ray diffraction data sets, which we address by developing AgileFD, an artificial intelligence algorithm that enables rapid phase mapping from a combinatorial library of X-ray diffraction patterns. AgileFD models alloying-based peak shifting through a novel expansion of convolutional nonnegative matrix factorization, which not only improves the identification of constituent phases but also maps their concentration and lattice parameter as a function of composition. By incorporating Gibbs' phase rule into the algorithm, physically meaningful phase maps are obtained with unsupervised operation, and more refined solutions are attained by injecting expert knowledge of the system. The algorithm is demonstrated through investigation of the V-Mn-Nb oxide system where decomposition of eight oxide phases, including two with substantial alloying, provides the first phase map for this pseudoternary system. This phase map enables interpretation of high-throughput band gap data, leading to the discovery of new solar light absorbers and the alloying-based tuning of the direct-allowed band gap energy of MnV2O6. The open-source family of AgileFD algorithms can be implemented into a broad range of high throughput workflows to accelerate materials discovery.

  16. Multiple-band light absorber via combining the fundamental mode and multiple splitting modes of the 3-order response of metamaterial resonator

    Science.gov (United States)

    Wang, Ben-Xin; Xie, Qin; Dong, Guangxi; Huang, Wei-Qing

    2017-12-01

    We present a rather simple metamaterial design consisted of only a rectangle-shape patch structure with a very small air strip on it to realize triple-band absorption at terahertz frequency. Results prove that three narrow-band absorption peaks are obtained at frequencies of 0.94 THz, 2.44 THz, and 2.85 THz, and the average absorption rates of the three peaks are 97.00%. The resonance at 0.94 THz is attributed to the fundamental mode (or 1-order) response of the metamaterial, while the last two modes are due to the two splitting modes of the 3-order response. The parameter changes of the small air strip in the rectangle-shape patch structure have large influence on the absorption performance of the metamaterial, in particular of the last two modes. Importantly, quad-band absorption can be obtained by introducing one more air strip in the rectangle-shape patch structure. It is found that the first resonance peak is derived from the 1-order response, whereas the last three modes stem from the three splitting modes of the 3-order response of the metamaterial. The combination of the 1-order resonance and multiple splitting modes of the 3-order response provides new design method to realize multiple-band light absorbers.

  17. Enhancement of Near-Infrared Detectability from InGaZnO Thin Film Transistor with MoS2 Light Absorbing Layer.

    Science.gov (United States)

    Pak, Sang Woo; Chu, Dongil; Song, Da Ye; Lee, Seung Kyo; Kim, Eun Kyu

    2017-10-02

    We report an enhancement of near-infrared detectability from amorphous InGaZnO (ɑ-IGZO) thin film transistor in conjunction with randomly distributed molybdenum disulfide (MoS2) flakes. The electrical characteristics of the ɑ-IGZO grown by radio-frequency magnetron sputtering exhibit high effective mobility exceeding 15 cm2V-1s-1 and current on/off ratio up to 107. By taking advantages of the high quality ɑ-IGZO and MoS2 light absorbing layer, photodetection spectra are able to extend from ultra-violet to near-infrared range. The ɑ-IGZO channel detector capped by MoS2 show a photo-responsivity of approximately 14.9 mA/W at 1100-nm-wavelength, which is five times higher than of the ɑ-IGZO device without MoS2 layer. © 2017 IOP Publishing Ltd.

  18. Energy absorber

    Energy Technology Data Exchange (ETDEWEB)

    Heyen, J.

    1980-03-04

    The collection of solar energy, radiated onto roofs, is the goal of this invention, to supply a heating system. The invention is based on the utilization of sealing webs. The prefered material for such energy absorbers is ethylen-copolymer-bitumen. Two each of the bitumen sheets are bonded together to form a bag flown through bag the heat transfer medium. The bag simultaneously serves for roof sealing.

  19. Estimating light use efficiency by linking flux tower data and fraction of absorbed PAR at chlorophyll level (FAPARchl) derived from daily MODIS observations

    Science.gov (United States)

    Zhang, Q.; Middleton, E.; Margolis, H.; Drolet, G.; Barr, A.; Black, T.

    2008-12-01

    We used daily MODIS imagery obtained over 2001-2005 to analyze the seasonal and interannual photosynthetic light use efficiency (LUE) of the Southern Old Aspen (SOA) flux tower site located near the southern limit of the boreal forest in Saskatchewan, Canada. This forest stand extends for at least 3 km in all directions from the flux tower. The MODIS daily reflectance products have resolution of 500 m at nadir and > 500 m at off-nadir. To obtain the spectral characteristics of a standardized land area to compare with tower measurements, we scaled up the nominal 500 m MODIS products to an area of 2.5 km × 2.5 km (5×5 MODIS 500 m grid cells). We then used the 5×5 scaled-up MODIS products in a coupled canopy-leaf radiative transfer model, PROSAIL-2, to estimate the fraction of photosynthetically active radiation (PAR) absorbed by the photosynthetically active part of the canopy dominated by chlorophyll (FAPARchl) versus that absorbed by the whole canopy (FAPARcanopy). From the tower measurements, we determined 90-minute averages for APAR and LUE for the physiologically active foliage (APARchl, LUEchl) and for the entire canopy (APARcanopy, LUEcanopy). The flux tower measurements of GEP were strongly related to the MODIS-derived estimates of APARchl (r2 = 0.78) but weakly related to APARcanopy (r2 = 0.33). Gross LUE (slope of GEP:APAR) between 2001 and 2005 for LUEchl was 0.0241 μ mol C μ mol -1 PPFD whereas LUEcanopy was 36% lower. Inter-annual variability in growing season (DOY 152-259) LUEchl (μ mol C μ mol -1 PPFD) ranged from 0.0225 in 2003 to 0.0310 in 2004. The five year time series of growing season LUEchl corresponded well with both the seasonal phase and amplitude of LUE from the tower measurements. We conclude that LUEchl derived from MODIS observations could provide a useful input to land surface models for improved estimates of ecosystem carbon dynamics.

  20. Universal metamaterial absorbe

    CERN Document Server

    Smaali, Rafik; Moreau, Antoine; Taliercio, Thierry; Centeno, Emmanuel

    2016-01-01

    We propose a design for an universal absorber, characterized by a resonance frequency that can be tuned from visible to microwave frequencies independently of the choice of the metal and the dielectrics involved. An almost resonant perfect absorption up to 99.8 % is demonstrated at resonance for all polarization states of light and for a very wide angular aperture. These properties originate from a magnetic Fabry-Perot mode that is confined in a dielectric spacer of $\\lambda/100$ thickness by a metamaterial layer and a mirror. An extraordinary large funneling through nano-slits explains how light can be trapped in the structure. Simple scaling laws can be used as a recipe to design ultra-thin perfect absorbers whatever the materials and the desired resonance wavelength, making our design truly universal.

  1. In-situ measurements of light-absorbing impurities in snow of glacier on Mt. Yulong and implications for radiative forcing estimates.

    Science.gov (United States)

    Niu, Hewen; Kang, Shichang; Shi, Xiaofei; Paudyal, Rukumesh; He, Yuanqing; Li, Gang; Wang, Shijin; Pu, Tao; Shi, Xiaoyi

    2017-03-01

    The Tibetan Plateau (TP) or the third polar cryosphere borders geographical hotspots for discharges of black carbon (BC). BC and dust play important roles in climate system and Earth's energy budget, particularly after they are deposited on snow and glacial surfaces. BC and dust are two kinds of main light-absorbing impurities (LAIs) in snow and glaciers. Estimating concentrations and distribution of LAIs in snow and glacier ice in the TP is of great interest because this region is a global hotspot in geophysical research. Various snow samples, including surface aged-snow, superimposed ice and snow meltwater samples were collected from a typical temperate glacier on Mt. Yulong in the snow melt season in 2015. The samples were determined for BC, Organic Carbon (OC) concentrations using an improved thermal/optical reflectance (DRI Model 2001) method and gravimetric method for dust concentrations. Results indicated that the LAIs concentrations were highly elevation-dependent in the study area. Higher contents and probably greater deposition at relative lower elevations (generally snow of glacier gradually increased as snow melting progressed. Evaluations of the relative absorption of BC and dust displayed that the impact of dust on snow albedo and radiative forcing (RF) is substantially larger than BC, particularly when dust contents are higher. This was verified by the absorption factor, which was albedo reduction to be in the range of 2% to nearly 10% during the snow melting season, and the mean snow albedo reduction was 4.63%, hence for BC contents ranging from 281 to 894ngg -1 in snow of a typical temperate glacier on Mt. Yulong, the associated instantaneous RF will be 76.38-146.96Wm -2 . Further research is needed to partition LAIs induced glacial melt, modeling researches in combination with long-term in-situ observations of LAIs in glaciers is also urgent needed in the future work. Copyright © 2017 Elsevier B.V. All rights reserved.

  2. Reactive oxygen species and transcript analysis upon excess light treatment in wild-type Arabidopsis thaliana vs a photosensitive mutant lacking zeaxanthin and lutein

    Directory of Open Access Journals (Sweden)

    Roncaglia Enrica

    2011-04-01

    Full Text Available Abstract Background Reactive oxygen species (ROS are unavoidable by-products of oxygenic photosynthesis, causing progressive oxidative damage and ultimately cell death. Despite their destructive activity they are also signalling molecules, priming the acclimatory response to stress stimuli. Results To investigate this role further, we exposed wild type Arabidopsis thaliana plants and the double mutant npq1lut2 to excess light. The mutant does not produce the xanthophylls lutein and zeaxanthin, whose key roles include ROS scavenging and prevention of ROS synthesis. Biochemical analysis revealed that singlet oxygen (1O2 accumulated to higher levels in the mutant while other ROS were unaffected, allowing to define the transcriptomic signature of the acclimatory response mediated by 1O2 which is enhanced by the lack of these xanthophylls species. The group of genes differentially regulated in npq1lut2 is enriched in sequences encoding chloroplast proteins involved in cell protection against the damaging effect of ROS. Among the early fine-tuned components, are proteins involved in tetrapyrrole biosynthesis, chlorophyll catabolism, protein import, folding and turnover, synthesis and membrane insertion of photosynthetic subunits. Up to now, the flu mutant was the only biological system adopted to define the regulation of gene expression by 1O2. In this work, we propose the use of mutants accumulating 1O2 by mechanisms different from those activated in flu to better identify ROS signalling. Conclusions We propose that the lack of zeaxanthin and lutein leads to 1O2 accumulation and this represents a signalling pathway in the early stages of stress acclimation, beside the response to ADP/ATP ratio and to the redox state of both plastoquinone pool. Chloroplasts respond to 1O2 accumulation by undergoing a significant change in composition and function towards a fast acclimatory response. The physiological implications of this signalling specificity are

  3. Blue LED light as a new hygienic problem

    Directory of Open Access Journals (Sweden)

    V.A. Kaptsov

    2016-03-01

    Full Text Available The conditions for the formation of an excess dose of blue light produced by the LED lighting were examined. It is shown that light-biological safety assessment carried out in accordance with GOST R IEC 62471-2013 need to be clarified, taking into account changes in the pupil of eye’s diameters when LED lighting and spatial distribution of the light-absorbing blue light (460 nm of the pigment in the macula influences it. Methodical principles of calculation of an excess dose of blue light in the spectrum of LED lighting comparing to sunlight are presented. It is indicated that today in the USA and Japan the concept of LED lighting has changed and LED white light been developed to minimize disturbances of health risks. This concept applies not only to general lighting in the United States, but also to monitors and car headlights.

  4. Multiple Types of Light Absorbing Carbon Aerosol in East Asian Outflow: Variatons in Morphology and Internal Structure as Characterized by Transmission Electron Microscopy

    Science.gov (United States)

    Anderson, J. R.; Alexander, D. T.; Crozier, P. A.

    2010-12-01

    The importance of light absorbing carbon (LAC) aerosols to climate forcing is well established, but such aerosols are typically treated in climate models as uniform in optical properties. When examined by electron microscopy, however, LAC aerosols from regions with significant anthropogenic pollution show a wide variety of morphologies and internal structures. Electron energy loss spectral analysis to date on brown carbon and black carbon, albeit limited, suggests a linkage between internal structure and fundamental optical properties. Some of these LAC varieties can be easily defined as distinct “types” and other varieties show a continuum of variation within which general “types” can be defined. The data discussed here are from a research flight of the NCAR C-130 aircraft flown in April 2001 above the Yellow Sea during the ACE-Asia project. Perhaps the most common LAC type is “soot”, branched and chainlike aggregates of carbonaceous spherules. The spherule size in East Asian soot particles is 20-60 nm in many cases, but soot with large spherules (100 nm or larger) are also present. Spherule size is a “source effect” and not something altered during transport and aging. Some laboratory studies have suggested that as soot ages, the aggregates become more compact, but in these aerosols both compact and open soot particles coexist and compact soot is known to be the initial LAC product under some combustion conditions. In cases where the spherule size of the compact soot is different from that of open-structured soot, clearly the compact soot is not an aged form of the latter. Variability of ordering of the graphene sheets that make up the spherules is also a source effect. The more ordered soot particles consist of graphene sheets that curve concentrically, onion-like, around the spherule center, probably indicative of a high degree of carbonization that accompanies high temperature combustion. There is a range of ordering from highly ordered down to

  5. Partitioning the contribution of light absorbing impurities to albedo reductions on Plaine Morte Glacier, Swiss Alps using a novel Hysperspectral Microscopy method

    Science.gov (United States)

    Dal Farra, Anna; Schwikowski, Margit; Kaspari, Susan

    2017-04-01

    The presence of light absorbing impurities (LAI) plays an important role in reducing a glacier's surface albedo, contributing to accelerated glacier melt. LAI include black carbon, mineral dust and organic (humic) substances. We investigated the role of LAI on glacier melt of Glacier de la Plaine Morte (7.88 km2 area) in the Swiss Alps. More than 90% of the Plaine Morte surface lies between 2650 and 2800 m a.s.l.; the low and narrow elevation range results in the glacier being particularly susceptible to melt. The glacier melt over the last 10 years (-1.7 mw.e. yr-1 on average) was almost double compared to the Alpine average. Plaine Morte has been almost entirely snow free in summer for the last 8 years, and has consequently accumulated a layer of LAI on the exposed surface after snow melt. The aim of this project is to: determine the relative abundances of the three classes of LAI, their spatial distribution on the glacier's surface, and to identify the relative contribution of each LAI to albedo reductions. Snow samples were collected at 110 sites that were spatially distributed on the glacier's surface. Relative quantities of elemental carbon (EC), organic carbon (OC) and mineral dust were determined for all samples collected with a thermal optical analyser; which combusts the sample separating OC and EC in the combustion process by their temperature (what is not combusted is considered mineral dust). The mineral composition, examined with X-ray diffractometry, indicated that local rock is the major source of mineral dust. Through an innovative hyperspectral imaging spectrometric technique developed for this purpose, a characteristic reflectance spectrum was defined for each of the three classes of LAI. Comparing the characteristic spectra, we determined to what extent black carbon, humic substances and minerals might be able to contribute to a lower albedo. Taking into account the average relative abundances on the glacier, we obtained that in the case of

  6. Role of silicon excess in Er-doped silicon-rich nitride light emitting devices at 1.54 μm

    Energy Technology Data Exchange (ETDEWEB)

    Ramírez, J. M., E-mail: jmramirez@el.ub.edu; Berencén, Y.; Garrido, B. [MIND-IN2UB, Department Electrònica, Universitat de Barcelona, Martí i Franquès 1, Barcelona 08028 (Spain); Cueff, S. [Institut des Nanotechnologies de Lyon, École Centrale de Lyon, Écully 69134 (France); Labbé, C. [Centre de Recherche sur les Ions, les Matériaux et la Photonique (CIMAP), UMR 6252 CNRS/CEA/Ensicaen/UCBN, Caen 14050 (France)

    2014-08-28

    Erbium-doped silicon-rich nitride electroluminescent thin-films emitting at 1.54 μm have been fabricated and integrated within a metal-oxide-semiconductor structure. By gradually varying the stoichiometry of the silicon nitride, we uncover the role of silicon excess on the optoelectronic properties of devices. While the electrical transport is mainly enabled in all cases by Poole-Frenkel conduction, power efficiency and conductivity are strongly altered by the silicon excess content. Specifically, the increase in silicon excess remarkably enhances the conductivity and decreases the charge trapping; however, it also reduces the power efficiency. The main excitation mechanism of Er{sup 3+} ions embedded in silicon-rich nitrides is discussed. The optimum Si excess that balances power efficiency, conductivity, and charge trapping density is found to be close to 16%.

  7. Metamaterial saturable absorber mirror.

    Science.gov (United States)

    Dayal, Govind; Ramakrishna, S Anantha

    2013-02-01

    We propose a metamaterial saturable absorber mirror at midinfrared wavelengths that can show a saturation of absorption with intensity of incident light and switch to a reflecting state. The design consists of an array of circular metallic disks separated by a thin film of vanadium dioxide (VO(2)) from a continuous metallic film. The heating due to the absorption in the absorptive state causes the VO(2) to transit to a metallic phase from the low temperature insulating phase. The metamaterial switches from an absorptive state (R≃0.1%) to a reflective state (R>95%) for a specific threshold intensity of the incident radiation corresponding to the phase transition of VO(2), resulting in the saturation of absorption in the metamaterial. The computer simulations show over 99.9% peak absorbance, a resonant bandwidth of about 0.8 μm at 10.22 μm wavelengths, and saturation intensity of 140 mW cm(-2) for undoped VO(2) at room temperature. We also carried out numerical simulations to investigate the effects of localized heating and temperature distribution by solving the heat diffusion problem.

  8. Lighting

    Data.gov (United States)

    Federal Laboratory Consortium — Lighting Systems Test Facilities aid research that improves the energy efficiency of lighting systems. • Gonio-Photometer: Measures illuminance from each portion of...

  9. Light

    DEFF Research Database (Denmark)

    Prescott, N.B.; Kristensen, Helle Halkjær; Wathes, C.M.

    2004-01-01

    This chapter presents the effect of artificial light environments (light levels, colour, photoperiod and flicker) on the welfare of broilers in terms of vision, behaviour, lameness and mortality......This chapter presents the effect of artificial light environments (light levels, colour, photoperiod and flicker) on the welfare of broilers in terms of vision, behaviour, lameness and mortality...

  10. II–IV–V2 and III–III–V2 Polytypes as Light Absorbers for Single Junction and Tandem Photovoltaic Devices

    DEFF Research Database (Denmark)

    Pandey, Mohnish; Kuhar, Korina; Jacobsen, Karsten Wedel

    2017-01-01

    of the polymorphs, the space can be extended by tuning the atomic structure as well. Using electronic structure calculations, we explore chalcopyrite, kesterite, and wurtzite polymorphs of II–IV–V2 and III–III–V2 materials for light absorption especially in the visiblerange. Based on the thermodynamic stability...

  11. Bend-absorbing clamp

    Science.gov (United States)

    Abbott, J. R.; Valencia, B., Jr.

    1979-01-01

    Compact, inexpensive clamp for flexible cables or rigid tubes absorbs vibrations and other motion. It accomodates wide range of dimensions, and saves space by eliminating pigtails or bellows commonly used to absorb linear movement or vibrations

  12. Properties of the ferroelectric visible light absorbing semiconductors: Sn2P2S6 and Sn2P2Se6

    Science.gov (United States)

    Li, Yuwei; Singh, David J.

    2017-12-01

    Ferroelectrics with suitable band gaps have recently attracted attention as candidate solar absorbing materials for photovoltaics. The inversion symmetry breaking may promote the separation of photoexcited carriers and allow voltages higher than the band gap. However, these effects are not fully understood, in part because of a lack of suitable model systems for studying these effects in detail. Here, we report properties of ferroelectric Sn2P2S6 and Sn2P2Se6 using first principles calculations. Results are given for the electronic structure, carrier pocket shapes, optical absorption, and transport. We find indirect band gaps of 2.20 eV and 1.55 eV, respectively, and favorable band structures for carrier transport, including both holes and electrons. Strong absorption is found above the direct gaps of 2.43 eV and 1.76 eV. Thus these compounds may serve as useful model systems for understanding photovoltaic effects in ferroelectric semiconductors.

  13. Epidermal UV-A absorbance and whole-leaf flavonoid composition in pea respond more to solar blue light than to solar UV radiation.

    Science.gov (United States)

    Siipola, Sari M; Kotilainen, Titta; Sipari, Nina; Morales, Luis O; Lindfors, Anders V; Robson, T Matthew; Aphalo, Pedro J

    2015-05-01

    Plants synthesize phenolic compounds in response to certain environmental signals or stresses. One large group of phenolics, flavonoids, is considered particularly responsive to ultraviolet (UV) radiation. However, here we demonstrate that solar blue light stimulates flavonoid biosynthesis in the absence of UV-A and UV-B radiation. We grew pea plants (Pisum sativum cv. Meteor) outdoors, in Finland during the summer, under five types of filters differing in their spectral transmittance. These filters were used to (1) attenuate UV-B; (2) attenuate UV-B and UV-A radiation signals that extend into the visible region of the solar spectrum. Furthermore, solar blue light instead of solar UV-B radiation can be the main regulator of phenolic compound accumulation in plants that germinate and develop outdoors. © 2014 John Wiley & Sons Ltd.

  14. Can a Satellite-Derived Estimate of the Fraction of PAR Absorbed by Chlorophyll (FAPAR(sub chl)) Improve Predictions of Light-Use Efficiency and Ecosystem Photosynthesis for a Boreal Aspen Forest?

    Science.gov (United States)

    Zhang, Qingyuan; Middleton, Elizabeth M.; Margolis, Hank A.; Drolet, Guillaume G.; Barr, Alan A.; Black, T. Andrew

    2009-01-01

    Gross primary production (GPP) is a key terrestrial ecophysiological process that links atmospheric composition and vegetation processes. Study of GPP is important to global carbon cycles and global warming. One of the most important of these processes, plant photosynthesis, requires solar radiation in the 0.4-0.7 micron range (also known as photosynthetically active radiation or PAR), water, carbon dioxide (CO2), and nutrients. A vegetation canopy is composed primarily of photosynthetically active vegetation (PAV) and non-photosynthetic vegetation (NPV; e.g., senescent foliage, branches and stems). A green leaf is composed of chlorophyll and various proportions of nonphotosynthetic components (e.g., other pigments in the leaf, primary/secondary/tertiary veins, and cell walls). The fraction of PAR absorbed by whole vegetation canopy (FAPAR(sub canopy)) has been widely used in satellite-based Production Efficiency Models to estimate GPP (as a product of FAPAR(sub canopy)x PAR x LUE(sub canopy), where LUE(sub canopy) is light use efficiency at canopy level). However, only the PAR absorbed by chlorophyll (a product of FAPAR(sub chl) x PAR) is used for photosynthesis. Therefore, remote sensing driven biogeochemical models that use FAPAR(sub chl) in estimating GPP (as a product of FAPAR(sub chl x PAR x LUE(sub chl) are more likely to be consistent with plant photosynthesis processes.

  15. Low band gap S,N-heteroacene-based oligothiophenes as hole-transporting and light absorbing materials for efficient perovskite-based solar cells

    KAUST Repository

    Qin, Peng

    2014-07-15

    Novel low band gap oligothiophenes incorporating S,N-heteropentacene central units were developed and used as hole-transport materials (HTMs) in solid-state perovskite-based solar cells. In addition to appropriate electronic energy levels, these materials show high photo-absorptivity in the low energy region, and thus can contribute to the light harvesting of the solar spectrum. Solution-processed CH3NH3PbI3-based devices using these HTMs achieved power conversion efficiencies of 9.5-10.5% in comparison with 7.6% obtained by reference devices without HTMs. Photoinduced absorption spectroscopy gave further insight into the charge transfer behavior between photoexcited perovskites and the HTMs. This journal is © the Partner Organisations 2014.

  16. Thin film absorber for a solar collector

    Science.gov (United States)

    Wilhelm, William G.

    1985-01-01

    This invention pertains to energy absorbers for solar collectors, and more particularly to high performance thin film absorbers. The solar collectors comprising the absorber of this invention overcome several problems seen in current systems, such as excessive hardware, high cost and unreliability. In the preferred form, the apparatus features a substantially rigid planar frame with a thin film window bonded to one planar side of the frame. An absorber in accordance with the present invention is comprised of two thin film layers that are sealed perimetrically. In a preferred embodiment, thin film layers are formed from a metal/plastic laminate. The layers define a fluid-tight planar envelope of large surface area to volume through which a heat transfer fluid flows. The absorber is bonded to the other planar side of the frame. The thin film construction of the absorber assures substantially full envelope wetting and thus good efficiency. The window and absorber films stress the frame adding to the overall strength of the collector.

  17. Methods for absorbing neutrons

    Science.gov (United States)

    Guillen, Donna P [Idaho Falls, ID; Longhurst, Glen R [Idaho Falls, ID; Porter, Douglas L [Idaho Falls, ID; Parry, James R [Idaho Falls, ID

    2012-07-24

    A conduction cooled neutron absorber may include a metal matrix composite that comprises a metal having a thermal neutron cross-section of at least about 50 barns and a metal having a thermal conductivity of at least about 1 W/cmK. Apparatus for providing a neutron flux having a high fast-to-thermal neutron ratio may include a source of neutrons that produces fast neutrons and thermal neutrons. A neutron absorber positioned adjacent the neutron source absorbs at least some of the thermal neutrons so that a region adjacent the neutron absorber has a fast-to-thermal neutron ratio of at least about 15. A coolant in thermal contact with the neutron absorber removes heat from the neutron absorber.

  18. Ti3C2 MXene co-catalyst on metal sulfide photo-absorbers for enhanced visible-light photocatalytic hydrogen production

    Science.gov (United States)

    Ran, Jingrun; Gao, Guoping; Li, Fa-Tang; Ma, Tian-Yi; Du, Aijun; Qiao, Shi-Zhang

    2017-01-01

    Scalable and sustainable solar hydrogen production through photocatalytic water splitting requires highly active and stable earth-abundant co-catalysts to replace expensive and rare platinum. Here we employ density functional theory calculations to direct atomic-level exploration, design and fabrication of a MXene material, Ti3C2 nanoparticles, as a highly efficient co-catalyst. Ti3C2 nanoparticles are rationally integrated with cadmium sulfide via a hydrothermal strategy to induce a super high visible-light photocatalytic hydrogen production activity of 14,342 μmol h−1 g−1 and an apparent quantum efficiency of 40.1% at 420 nm. This high performance arises from the favourable Fermi level position, electrical conductivity and hydrogen evolution capacity of Ti3C2 nanoparticles. Furthermore, Ti3C2 nanoparticles also serve as an efficient co-catalyst on ZnS or ZnxCd1−xS. This work demonstrates the potential of earth-abundant MXene family materials to construct numerous high performance and low-cost photocatalysts/photoelectrodes. PMID:28045015

  19. Light

    CERN Document Server

    Robertson, William C

    2003-01-01

    Why is left right and right left in the mirror? Baffled by the basics of reflection and refraction? Wondering just how the eye works? If you have trouble teaching concepts about light that you don t fully grasp yourself, get help from a book that s both scientifically accurate and entertaining with Light. By combining clear explanations, clever drawings, and activities that use easy-to-find materials, this book covers what science teachers and parents need to know to teach about light with confidence. It uses ray, wave, and particle models of light to explain the basics of reflection and refraction, optical instruments, polarization of light, and interference and diffraction. There s also an entire chapter on how the eye works. Each chapter ends with a Summary and Applications section that reinforces concepts with everyday examples. Whether you need a deeper understanding of how light bends or a good explanation of why the sky is blue, you ll find Light more illuminating and accessible than a college textbook...

  20. Multispectral metamaterial absorber

    OpenAIRE

    Grant, James; McCrindle, I.J.H.; Li, C; D. R. S. Cumming

    2014-01-01

    We present the simulation, implementation, and measurement of a multispectral metamaterial absorber (MSMMA) and show that we can realize a simple absorber structure that operates in the mid-IR and terahertz (THz) bands. By embedding an IR metamaterial absorber layer into a standard THz metamaterial absorber stack, a narrowband resonance is induced at a wavelength of 4.3 μm. This resonance is in addition to the THz metamaterial absorption resonance at 109 μm (2.75 THz). We demonstrate the inhe...

  1. Multispectral metamaterial absorber.

    Science.gov (United States)

    Grant, J; McCrindle, I J H; Li, C; Cumming, D R S

    2014-03-01

    We present the simulation, implementation, and measurement of a multispectral metamaterial absorber (MSMMA) and show that we can realize a simple absorber structure that operates in the mid-IR and terahertz (THz) bands. By embedding an IR metamaterial absorber layer into a standard THz metamaterial absorber stack, a narrowband resonance is induced at a wavelength of 4.3 μm. This resonance is in addition to the THz metamaterial absorption resonance at 109 μm (2.75 THz). We demonstrate the inherent scalability and versatility of our MSMMA by describing a second device whereby the MM-induced IR absorption peak frequency is tuned by varying the IR absorber geometry. Such a MSMMA could be coupled with a suitable sensor and formed into a focal plane array, enabling multispectral imaging.

  2. Light

    CERN Document Server

    Ditchburn, R W

    1963-01-01

    This classic study, available for the first time in paperback, clearly demonstrates how quantum theory is a natural development of wave theory, and how these two theories, once thought to be irreconcilable, together comprise a single valid theory of light. Aimed at students with an intermediate-level knowledge of physics, the book first offers a historical introduction to the subject, then covers topics such as wave theory, interference, diffraction, Huygens' Principle, Fermat's Principle, and the accuracy of optical measurements. Additional topics include the velocity of light, relativistic o

  3. Excessive Daytime Sleepiness

    Directory of Open Access Journals (Sweden)

    Yavuz Selvi

    2016-06-01

    Full Text Available Excessive daytime sleepiness is one of the most common sleep-related patient symptoms, with preva-lence in the community estimated to be as high as 18%. Patients with excessive daytime sleepiness may exhibit life threatening road and work accidents, social maladjustment, decreased academic and occupational performance and have poorer health than comparable adults. Thus, excessive daytime sleepiness is a serious condition that requires investigation, diagnosis and treatment primarily. As with most medical condition, evaluation of excessive daytime sleepiness begins a precise history and various objective and subjective tools have been also developed to assess excessive daytime sleepiness. The most common causes of excessive daytime sleepiness are insufficient sleep hygiene, chronic sleep deprivation, medical and psychiatric conditions and sleep disorders, such as obstructive sleep apnea, medications, and narcolepsy. Treatment option should address underlying contributors and promote sleep quantity by ensuring good sleep hygiene. [Psikiyatride Guncel Yaklasimlar - Current Approaches in Psychiatry 2016; 8(2: 114-132

  4. Microstructure characterization of hydrothermally synthesized PANI/V2O5·nH2O heterojunction photocatalyst for visible light induced photodegradation of organic pollutants and non-absorbing colorless molecules.

    Science.gov (United States)

    Kundu, Samapti; Satpati, Biswarup; Kar, Tanusree; Pradhan, Swapan Kumar

    2017-10-05

    Polyaniline intercalated vanadium oxide xerogel (PV) hybrid nanocomposite (NC) with novel structure has been successfully synthesized through a simple hydrothermal route. Detailed structure and microstructure characterization of PV NC is illustrated through Rietveld refinement of XRD data and FESEM/HRTEM images. Both FTIR and XPS spectra confirm the presence of PANI and water molecules within the NC and partial reduction of V5+ to V4+, corroborating with the results of XRD pattern analysis. Core-shell structure of PV NC, where PANI sheath layer acts as a shell covering around V2O5·nH2O crystalline core is confirmed from HRTEM images. Successive morphological changes of PV NC with different reaction time have been revealed from FESEM images. UV-vis spectra also confirm the formation of PV NC. Intercalation of water and PANI layers into V2O5·nH2O layer leads to a structural phase transition from orthorhombic to monoclinic phase due to substantial increase in interplanar spacing of (00l) of orthorhombic V2O5. The photocatalytic property of the as synthesized PV NC has been reported for the first time, with a promising photocatalytic activity for the degradation of organic dye, Rhodamine B (RhB) under visible light irradiation. It is attributed to a synergic effect in between PANI and V2O5·nH2O xerogel. The photocatalyst also shows remarkable real visible light photocatalytic activity with non-absorbing colorless test molecules like phenol and antibiotic kanamycin. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. Internal absorber solar collector

    Science.gov (United States)

    Sletten, Carlyle J.; Herskovitz, Sheldon B.; Holt, F. S.; Sletten, E. J.

    1981-01-01

    Thin solar collecting panels are described made from arrays of small rod collectors consisting of a refracting dielectric rod lens with an absorber imbedded within it and a reflecting mirror coated on the back side of the dielectric rod. Non-tracking collector panels on vertical walls or roof tops receive approximately 90% of solar radiation within an acceptance zone 60.degree. in elevation angle by 120.degree. or more in the azimuth sectors with a collector concentration ratio of approximately 3.0. Miniaturized construction of the circular dielectric rods with internal absorbers reduces the weight per area of glass, plastic and metal used in the collector panels. No external parts or insulation are needed as heat losses are low due to partial vacuum or low conductivity gas surrounding heated portions of the collector. The miniature internal absorbers are generally made of solid copper with black selective surface and the collected solar heat is extracted at the collector ends by thermal conductivity along the absorber rods. Heat is removed from end fittings by use of liquid circulants. Several alternate constructions are provided for simplifying collector panel fabrication and for preventing the thermal expansion and contraction of the heated absorber or circulant tubes from damaging vacuum seals. In a modified version of the internal absorber collector, oil with temperature dependent viscosity is pumped through a segmented absorber which is now composed of closely spaced insulated metal tubes. In this way the circulant is automatically diverted through heated portions of the absorber giving higher collector concentration ratios than theoretically possible for an unsegmented absorber.

  6. Light-absorbing Components in Lake Superior

    Science.gov (United States)

    2010-01-01

    representing on average 72% of the total PAVm at each of the sites {Table 2). Such particles have terrigenous origins ( Peng et al., 2009). The SAX...of acooM. aNAP· and PAVm in the 2006 survey are consistent with terrigenous sources of these constituents, though the details are doubtless subject...to substantial variations. For example, Budd (2004) resolved extensive spring-time sediment plumes in the Keweenaw region of Lake Superior through

  7. TOMS Absorbing Aerosol Index

    Data.gov (United States)

    Washington University St Louis — TOMS_AI_G is an aerosol related dataset derived from the Total Ozone Monitoring Satellite (TOMS) Sensor. The TOMS aerosol index arises from absorbing aerosols such...

  8. Diphoton excess through dark mediators

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Chien-Yi [Department of Physics and Astronomy, University of Victoria,Victoria, BC V8P 5C2 (Canada); Perimeter Institute for Theoretical Physics,Waterloo, ON N2J 2W9 (Canada); Lefebvre, Michel [Department of Physics and Astronomy, University of Victoria,Victoria, BC V8P 5C2 (Canada); Pospelov, Maxim [Department of Physics and Astronomy, University of Victoria,Victoria, BC V8P 5C2 (Canada); Perimeter Institute for Theoretical Physics,Waterloo, ON N2J 2W9 (Canada); Zhong, Yi-Ming [C.N. Yang Institute for Theoretical Physics, Stony Brook University,Stony Brook, New York 11794 (United States)

    2016-07-12

    Preliminary ATLAS and CMS results from the first 13 TeV LHC run have encountered an intriguing excess of events in the diphoton channel around the invariant mass of 750 GeV. We investigate a possibility that the current excess is due to a heavy resonance decaying to light metastable states, which in turn give displaced decays to very highly collimated e{sup +}e{sup −} pairs. Such decays may pass the photon selection criteria, and successfully mimic the diphoton events, especially at low counts. We investigate two classes of such models, characterized by the following underlying production and decay chains: gg→S→A{sup ′}A{sup ′}→(e{sup +}e{sup −})(e{sup +}e{sup −}) and qq̄→Z{sup ′}→sa→(e{sup +}e{sup −})(e{sup +}e{sup −}), where at the first step a heavy scalar, S, or vector, Z{sup ′}, resonances are produced that decay to light metastable vectors, A{sup ′}, or (pseudo-)scalars, s and a. Setting the parameters of the models to explain the existing excess, and taking the ATLAS detector geometry into account, we marginalize over the properties of heavy resonances in order to derive the expected lifetimes and couplings of metastable light resonances. We observe that in the case of A{sup ′}, the suggested range of masses and mixing angles ϵ is within reach of several new-generation intensity frontier experiments.

  9. Absorbance and fluorescence studies on porphyrin Nanostructures ...

    African Journals Online (AJOL)

    The aim of this work was to study some photophysical properties of PNR for application as light harvester in dye sensitized solar cells. These properties included absorbance, fluorescence, and fluorescence quantum yield and lifetime. The results of Transmission Electron Microscope (TEM) images showed the formation of ...

  10. Prevention of excess gain.

    Science.gov (United States)

    Stevens, J; Truesdale, K P; Wang, C-H; Cai, J

    2009-11-01

    Obesity prevention trials are designed to promote healthy weight. The success of these trials is often assessed using one of three metrics--means, incidence or prevalence. In this study, we point out conceptual shortcomings of these metrics and introduce an alternative that we call 'excess gain'. A mathematical demonstration using simulated data shows a scenario in which the statistical power of excess gain compares favorably with that of incidence and prevalence. Prevention of excess gain communicates an easily understood public health message that is applicable to all individuals regardless of weight status.

  11. Nanostructured light-absorbing crystalline CuIn{sub (1–x)}Ga{sub x}Se{sub 2} thin films grown through high flux, low energy ion irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Hall, Allen J.; Hebert, Damon; Rockett, Angus A. [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 1304 W. Green St., Urbana, Illinois 61801 (United States); Shah, Amish B. [Center for Microanalysis of Materials, Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, 104 South Goodwin Ave, Urbana, Illinois 61801 (United States); Bettge, Martin [Chemical Sciences and Engineering, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, Illinois 60438 (United States)

    2013-10-21

    A hybrid effusion/sputtering vacuum system was modified with an inductively coupled plasma (ICP) coil enabling ion assisted physical vapor deposition of CuIn{sub 1−x}Ga{sub x}Se{sub 2} thin films on GaAs single crystals and stainless steel foils. With <80 W rf power to the ICP coil at 620–740 °C, film morphologies were unchanged compared to those grown without the ICP. At low temperature (600–670 °C) and high rf power (80–400 W), a light absorbing nanostructured highly anisotropic platelet morphology was produced with surface planes dominated by (112){sub T} facets. At 80–400 W rf power and 640–740 °C, both interconnected void and small platelet morphologies were observed while at >270 W and above >715 °C nanostructured pillars with large inter-pillar voids were produced. The latter appeared black and exhibited a strong (112){sub T} texture with interpillar twist angles of ±8°. Application of a negative dc bias of 0–50 V to the film during growth was not found to alter the film morphology or stoichiometry. The results are interpreted as resulting from the plasma causing strong etching favoring formation of (112){sub T} planes and preferential nucleation of new grains, balanced against conventional thermal diffusion and normal growth mechanisms at higher temperatures. The absence of effects due to applied substrate bias suggests that physical sputtering or ion bombardment effects were minimal. The nanostructured platelet and pillar films were found to exhibit less than one percent reflectivity at angles up to 75° from the surface normal.

  12. Absorbance enhancement in microplate wells for improved-sensitivity biosensors

    OpenAIRE

    Suárez, Guillaume; Santschi, Christian; Plateel, Gregory; Martin Olivier, J.; Riediker, Michael

    2014-01-01

    A generic optical biosensing strategy was developed that relies on the absorbance enhancement phenomenon occurring in a multiple scattering matrix. Experimentally, inserts made of glass fiber membrane were placed into microplate wells in order to significantly lengthen the trajectory of the incident light through the sample and therefore increase the corresponding absorbance. Enhancement factor was calculated by comparing the absorbance values measured for a given amount of dye with and witho...

  13. Excess wind power

    DEFF Research Database (Denmark)

    Østergaard, Poul Alberg

    2005-01-01

    analyses it is analysed how excess productions are better utilised; through conversion into hydrogen of through expansion of export connections thereby enabling sales. The results demonstrate that particularly hydrogen production is unviable under current costs but transmission expansion could...

  14. An omnidirectional electromagnetic absorber made of metamaterials

    Energy Technology Data Exchange (ETDEWEB)

    Cheng Qiang; Cui Tiejun; Jiang Weixiang; Cai Bengeng, E-mail: tjcui@seu.edu.c [State Key Laboratory of Millimeter Waves, Department of Radio Engineering, Southeast University, Nanjing 210096 (China)

    2010-06-15

    In a recent theoretical work by Narimanov and Kildishev (2009 Appl. Phys. Lett. 95 041106) an optical omnidirectional light absorber based on metamaterials was proposed, in which theoretical analysis and numerical simulations showed that all optical waves hitting the absorber are trapped and absorbed. Here we report the first experimental demonstration of an omnidirectional electromagnetic absorber in the microwave frequency. The proposed device is composed of non-resonant and resonant metamaterial structures, which can trap and absorb electromagnetic waves coming from all directions spirally inwards without any reflections due to the local control of electromagnetic fields. It is shown that the absorption rate can reach 99 per cent in the microwave frequency. The all-directional full absorption property makes the device behave like an 'electromagnetic black body', and the wave trapping and absorbing properties simulate, to some extent, an 'electromagnetic black hole.' We expect that such a device could be used as a thermal emitting source and to harvest electromagnetic waves.

  15. Durability of Polymeric Glazing and Absorber Materials

    Energy Technology Data Exchange (ETDEWEB)

    Jorgensen, G.; Terwilliger, K.; Bingham, C.; Lindquist, C.; Milbourne, M.

    2005-11-01

    The Solar Heating and Lighting Program has set the goal of reducing the cost of solar water heating systems by at least 50%. An attractive approach to such large cost reduction is to replace glass and metal parts with less-expensive, lighter-weight, more-integrated polymeric components. The key challenge with polymers is to maintain performance and assure requisite durability for extended lifetimes. We have begun evaluation of several new UV-screened polycarbonate sheet glazing constructions. This has involved interactions with several major polymer industry companies to obtain improved candidate samples. Proposed absorber materials were tested for UV resistance, and appear adequate for unglazed ICS absorbers.

  16. Aperiodic-metamaterial-based absorber

    OpenAIRE

    Quanlong Yang; Xieyu Chen; Yanfeng Li; Xueqian Zhang; Yuehong Xu; Zhen Tian; Chunmei Ouyang; Jianqiang Gu; Jiaguang Han; Weili Zhang

    2017-01-01

    The periodic-metamaterial-based perfect absorber has been studied broadly. Conversely, if the unit cell in the metamaterial-based absorber is arranged aperiodically (aperiodic-metamaterial-based absorber), how does it perform? Inspired by this, here we present a systematic study of the aperiodic-metamaterial-based absorber. By investigating the response of metamaterial absorbers based on periodic, Fibonacci, Thue-Morse, and quasicrystal lattices, we found that aperiodic-metamaterial-based abs...

  17. Solar concentrator/absorber

    Science.gov (United States)

    Von Tiesenhausen, G. F.

    1976-01-01

    Collector/energy converter, consisting of dual-slope optical concentrator and counterflow thermal energy absorber, is attached to multiaxis support structure. Efficient over wide range of illumination levels, device may be used to generate high temperature steam, serve as solar powered dryer, or power absorption cycle cooler.

  18. Liquid crystal tunable metamaterial absorber.

    Science.gov (United States)

    Shrekenhamer, David; Chen, Wen-Chen; Padilla, Willie J

    2013-04-26

    We present an experimental demonstration of electronically tunable metamaterial absorbers in the terahertz regime. By incorporation of active liquid crystal into strategic locations within the metamaterial unit cell, we are able to modify the absorption by 30% at 2.62 THz, as well as tune the resonant absorption over 4% in bandwidth. Numerical full-wave simulations match well to experiments and clarify the underlying mechanism, i.e., a simultaneous tuning of both the electric and magnetic response that allows for the preservation of the resonant absorption. These results show that fundamental light interactions of surfaces can be dynamically controlled by all-electronic means and provide a path forward for realization of novel applications.

  19. Excessive crying in infants

    Directory of Open Access Journals (Sweden)

    Ricardo Halpern

    2016-06-01

    Full Text Available ABSTRACT Objective: Review the literature on excessive crying in young infants, also known as infantile colic, and its effects on family dynamics, its pathophysiology, and new treatment interventions. Data source: The literature review was carried out in the Medline, PsycINFO, LILACS, SciELO, and Cochrane Library databases, using the terms “excessive crying,” and “infantile colic,” as well technical books and technical reports on child development, selecting the most relevant articles on the subject, with emphasis on recent literature published in the last five years. Summary of the findings: Excessive crying is a common symptom in the first 3 months of life and leads to approximately 20% of pediatric consultations. Different prevalence rates of excessive crying have been reported, ranging from 14% to approximately 30% in infants up to 3 months of age. There is evidence linking excessive crying early in life with adaptive problems in the preschool period, as well as with early weaning, maternal anxiety and depression, attention deficit hyperactivity disorder, and other behavioral problems. Several pathophysiological mechanisms can explain these symptoms, such as circadian rhythm alterations, central nervous system immaturity, and alterations in the intestinal microbiota. Several treatment alternatives have been described, including behavioral measures, manipulation techniques, use of medication, and acupuncture, with controversial results and effectiveness. Conclusion: Excessive crying in the early months is a prevalent symptom; the pediatrician's attention is necessary to understand and adequately manage the problem and offer support to exhausted parents. The prescription of drugs of questionable action and with potential side effects is not a recommended treatment, except in extreme situations. The effectiveness of dietary treatments and use of probiotics still require confirmation. There is incomplete evidence regarding alternative

  20. Optimal Sound Absorbing Structures

    CERN Document Server

    Yang, Min; Fu, Caixing; Sheng, Ping

    2016-01-01

    Causal nature of the acoustic response, for any materials or structures, dictates an inequality that relates the absorption spectrum of the sample to its thickness. We present a general recipe for constructing sound-absorbing structures that can attain near-equality for the causal relation with very high absorption performance; such structures are denoted optimal. Our strategy involves using carefully designed acoustic metamaterials as backing to a thin layer of conventional sound absorbing material, e.g., acoustic sponge. By using this design approach, we have realized a 12 cm-thick structure that exhibits broadband, near-perfect flat absorption spectrum starting at around 400 Hz. From the causal relation, the calculated minimum sample thickness is 11.5 cm for the observed absorption spectrum. We present the theory that underlies such absorption performance, involving the evanescent waves and their interaction with a dissipative medium, and show the excellent agreement with the experiment.

  1. Reducing Excessive Television Viewing.

    Science.gov (United States)

    Jason, Leonard A.; Rooney-Rebeck, Patty

    1984-01-01

    A youngster who excessively watched television was placed on a modified token economy: earned tokens were used to activate the television for set periods of time. Positive effects resulted in the child's school work, in the amount of time his family spent together, and in his mother's perception of family social support. (KH)

  2. HIV Excess Cancers JNCI

    Science.gov (United States)

    In 2010, an estimated 7,760 new cancers were diagnosed among the nearly 900,000 Americans known to be living with HIV infection. According to the first comprehensive study in the United States, approximately half of these cancers were in excess of what wo

  3. Excessive prices as abuse of dominance?

    DEFF Research Database (Denmark)

    la Cour, Lisbeth; Møllgaard, Peter

    2007-01-01

    firm abused its position by charging excessive prices. We also test whether tightening of the Danish competition act has altered the pricing behaviour on the market. We discuss our results in the light of a Danish competition case against the dominant cement producer that was abandoned by the authority...

  4. Absorbable and biodegradable polymers

    CERN Document Server

    Shalaby, Shalaby W

    2003-01-01

    INTRODUCTION NOTES: Absorbable/Biodegradable Polymers: Technology Evolution. DEVELOPMENT AND APPLICATIONOF NEW SYSTEMS: Segmented Copolyesters with Prolonged Strength Retention Profiles. Polyaxial Crystalline Fiber-Forming Copolyester. Polyethylene Glycol-Based Copolyesters. Cyanoacrylate-Based Systems as Tissue Adhesives. Chitosan-Based Systems. Hyaluronic Acid-Based Systems. DEVELOPMENTS IN PREPARATIVE, PROCESSING, AND EVALUATION METHODS: New Approaches to the Synthesis of Crystalline. Fiber-Forming Aliphatic Copolyesters. Advances in Morphological Development to Tailor the Performance of Me

  5. Review of Plasmonic Nanocomposite Metamaterial Absorber

    Directory of Open Access Journals (Sweden)

    Mehdi Keshavarz Hedayati

    2014-02-01

    Full Text Available Plasmonic metamaterials are artificial materials typically composed of noble metals in which the features of photonics and electronics are linked by coupling photons to conduction electrons of metal (known as surface plasmon. These rationally designed structures have spurred interest noticeably since they demonstrate some fascinating properties which are unattainable with naturally occurring materials. Complete absorption of light is one of the recent exotic properties of plasmonic metamaterials which has broadened its application area considerably. This is realized by designing a medium whose impedance matches that of free space while being opaque. If such a medium is filled with some lossy medium, the resulting structure can absorb light totally in a sharp or broad frequency range. Although several types of metamaterials perfect absorber have been demonstrated so far, in the current paper we overview (and focus on perfect absorbers based on nanocomposites where the total thickness is a few tens of nanometer and the absorption band is broad, tunable and insensitive to the angle of incidence. The nanocomposites consist of metal nanoparticles embedded in a dielectric matrix with a high filling factor close to the percolation threshold. The filling factor can be tailored by the vapor phase co-deposition of the metallic and dielectric components. In addition, novel wet chemical approaches are discussed which are bio-inspired or involve synthesis within levitating Leidenfrost drops, for instance. Moreover, theoretical considerations, optical properties, and potential application of perfect absorbers will be presented.

  6. Review of Plasmonic Nanocomposite Metamaterial Absorber.

    Science.gov (United States)

    Hedayati, Mehdi Keshavarz; Faupel, Franz; Elbahri, Mady

    2014-02-14

    Plasmonic metamaterials are artificial materials typically composed of noble metals in which the features of photonics and electronics are linked by coupling photons to conduction electrons of metal (known as surface plasmon). These rationally designed structures have spurred interest noticeably since they demonstrate some fascinating properties which are unattainable with naturally occurring materials. Complete absorption of light is one of the recent exotic properties of plasmonic metamaterials which has broadened its application area considerably. This is realized by designing a medium whose impedance matches that of free space while being opaque. If such a medium is filled with some lossy medium, the resulting structure can absorb light totally in a sharp or broad frequency range. Although several types of metamaterials perfect absorber have been demonstrated so far, in the current paper we overview (and focus on) perfect absorbers based on nanocomposites where the total thickness is a few tens of nanometer and the absorption band is broad, tunable and insensitive to the angle of incidence. The nanocomposites consist of metal nanoparticles embedded in a dielectric matrix with a high filling factor close to the percolation threshold. The filling factor can be tailored by the vapor phase co-deposition of the metallic and dielectric components. In addition, novel wet chemical approaches are discussed which are bio-inspired or involve synthesis within levitating Leidenfrost drops, for instance. Moreover, theoretical considerations, optical properties, and potential application of perfect absorbers will be presented.

  7. The otherness of sexuality: excess.

    Science.gov (United States)

    Stein, Ruth

    2008-03-01

    The present essay, the second of a series of three, aims at developing an experience-near account of sexuality by rehabilitating the idea of excess and its place in sexual experience. It is suggested that various types of excess, such as excess of excitation (Freud), the excess of the other (Laplanche), excess beyond symbolization and the excess of the forbidden object of desire (Leviticus; Lacan) work synergistically to constitute the compelling power of sexuality. In addition to these notions, further notions of excess touch on its transformative potential. Such notions address excess that shatters psychic structures and that is actively sought so as to enable new ones to evolve (Bersani). Work is quoted that regards excess as a way of dealing with our lonely, discontinuous being by using the "excessive" cosmic energy circulating through us to achieve continuity against death (Bataille). Two contemporary analytic thinkers are engaged who deal with the object-relational and intersubjective vicissitudes of excess.

  8. Polymers used to absorb fats and oils: A concept

    Science.gov (United States)

    Marsh, H. E., Jr.

    1974-01-01

    One approach to problem of excessive oils and fats is to develop method by which oil is absorbed into solid mixture for elimination as solid waste. Materials proposed for these purposes are cross-linked (network) polymers that have high affinity for aliphatic substances, i. e., petroleum, animal, and vegetable oils.

  9. Absorber for terahertz radiation management

    Science.gov (United States)

    Biallas, George Herman; Apeldoorn, Cornelis; Williams, Gwyn P.; Benson, Stephen V.; Shinn, Michelle D.; Heckman, John D.

    2015-12-08

    A method and apparatus for minimizing the degradation of power in a free electron laser (FEL) generating terahertz (THz) radiation. The method includes inserting an absorber ring in the FEL beam path for absorbing any irregular THz radiation and thus minimizes the degradation of downstream optics and the resulting degradation of the FEL output power. The absorber ring includes an upstream side, a downstream side, and a plurality of wedges spaced radially around the absorber ring. The wedges form a scallop-like feature on the innermost edges of the absorber ring that acts as an apodizer, stopping diffractive focusing of the THz radiation that is not intercepted by the absorber. Spacing between the scallop-like features and the shape of the features approximates the Bartlett apodization function. The absorber ring provides a smooth intensity distribution, rather than one that is peaked on-center, thereby eliminating minor distortion downstream of the absorber.

  10. Exchanging Ohmic losses in metamaterial absorbers with useful optical absorption for photovoltaics.

    Science.gov (United States)

    Vora, Ankit; Gwamuri, Jephias; Pala, Nezih; Kulkarni, Anand; Pearce, Joshua M; Güney, Durdu Ö

    2014-05-09

    Using metamaterial absorbers, we have shown that metallic layers in the absorbers do not necessarily constitute undesired resistive heating problem for photovoltaics. Tailoring the geometric skin depth of metals and employing the natural bulk absorbance characteristics of the semiconductors in those absorbers can enable the exchange of undesired resistive losses with the useful optical absorbance in the active semiconductors. Thus, Ohmic loss dominated metamaterial absorbers can be converted into photovoltaic near-perfect absorbers with the advantage of harvesting the full potential of light management offered by the metamaterial absorbers. Based on experimental permittivity data for indium gallium nitride, we have shown that between 75%-95% absorbance can be achieved in the semiconductor layers of the converted metamaterial absorbers. Besides other metamaterial and plasmonic devices, our results may also apply to photodectors and other metal or semiconductor based optical devices where resistive losses and power consumption are important pertaining to the device performance.

  11. Exchanging Ohmic Losses in Metamaterial Absorbers with Useful Optical Absorption for Photovoltaics

    Science.gov (United States)

    Vora, Ankit; Gwamuri, Jephias; Pala, Nezih; Kulkarni, Anand; Pearce, Joshua M.; Güney, Durdu Ö.

    2014-01-01

    Using metamaterial absorbers, we have shown that metallic layers in the absorbers do not necessarily constitute undesired resistive heating problem for photovoltaics. Tailoring the geometric skin depth of metals and employing the natural bulk absorbance characteristics of the semiconductors in those absorbers can enable the exchange of undesired resistive losses with the useful optical absorbance in the active semiconductors. Thus, Ohmic loss dominated metamaterial absorbers can be converted into photovoltaic near-perfect absorbers with the advantage of harvesting the full potential of light management offered by the metamaterial absorbers. Based on experimental permittivity data for indium gallium nitride, we have shown that between 75%–95% absorbance can be achieved in the semiconductor layers of the converted metamaterial absorbers. Besides other metamaterial and plasmonic devices, our results may also apply to photodectors and other metal or semiconductor based optical devices where resistive losses and power consumption are important pertaining to the device performance. PMID:24811322

  12. Corrosion resistant neutron absorbing coatings

    Science.gov (United States)

    Choi, Jor-Shan [El Cerrito, CA; Farmer, Joseph C [Tracy, CA; Lee, Chuck K [Hayward, CA; Walker, Jeffrey [Gaithersburg, MD; Russell, Paige [Las Vegas, NV; Kirkwood, Jon [Saint Leonard, MD; Yang, Nancy [Lafayette, CA; Champagne, Victor [Oxford, PA

    2012-05-29

    A method of forming a corrosion resistant neutron absorbing coating comprising the steps of spray or deposition or sputtering or welding processing to form a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material. Also a corrosion resistant neutron absorbing coating comprising a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material.

  13. Break-up of metal tube makes one-time shock absorber, bars rebound

    Science.gov (United States)

    Hathaway, M.; Mc Gehee, J. R.; Zavada, E.

    1964-01-01

    A frangible metal tube has the capability to dissipate the energy generated when a vehicle lands with excessive velocity. The tube is so placed that, at impact, it is forced against a die and, as it fragments, energy is absorbed.

  14. A Perfect Terahertz Metamaterial Absorber

    OpenAIRE

    Bagheri, Alireza; Moradi, Gholamreza

    2015-01-01

    In this paper the design for an absorbing metamaterial with near unity absorbance in terahertz region is presented. The absorber's unit cell structure consists of two metamaterial resonators that couple to electric and magnetic fields separately. The structure allows us to maximize absorption by varying dielectric material and thickness and, hence the effective electrical permittivity and magnetic permeability.

  15. Excessive crying in infants

    Directory of Open Access Journals (Sweden)

    Ricardo Halpern

    2016-05-01

    Conclusion: Excessive crying in the early months is a prevalent symptom; the pediatrician's attention is necessary to understand and adequately manage the problem and offer support to exhausted parents. The prescription of drugs of questionable action and with potential side effects is not a recommended treatment, except in extreme situations. The effectiveness of dietary treatments and use of probiotics still require confirmation. There is incomplete evidence regarding alternative treatments such as manipulation techniques, acupuncture, and use of the herbal supplements and behavioral interventions.

  16. ACTIVATION PARAMETERS AND EXCESS THERMODYANAMIC ...

    African Journals Online (AJOL)

    Applying these data, viscosity-B-coefficients, activation parameters (Δμ10≠) and (Δμ20≠) and excess thermodynamic functions, viz., excess molar volume (VE), excess viscosity, ηE and excess molar free energy of activation of flow, (GE) were calculated. The value of interaction parameter, d, of Grunberg and Nissan ...

  17. Solar radiation absorbing material

    Science.gov (United States)

    Googin, John M.; Schmitt, Charles R.; Schreyer, James M.; Whitehead, Harlan D.

    1977-01-01

    Solar energy absorbing means in solar collectors are provided by a solar selective carbon surface. A solar selective carbon surface is a microporous carbon surface having pores within the range of 0.2 to 2 micrometers. Such a surface is provided in a microporous carbon article by controlling the pore size. A thermally conductive substrate is provided with a solar selective surface by adhering an array of carbon particles in a suitable binder to the substrate, a majority of said particles having diameters within the range of about 0.2-10 microns.

  18. A modular wideband sound absorber

    Science.gov (United States)

    Plumb, G. D.

    The absorption coefficients were measured of various depths of RW2 grade Rockwool laid directly on the floor of the ISO-Standard reverberation room at BBC Research Department. The Rockwool was very effective as a wideband sound absorber. A new absorber was designed and tested, having the dimensions of the existing BBC type A modular absorbers and containing RW2 Rockwool. The new absorber has a smoother absorption coefficient curve, a less complicated construction, and weighs less than the existing BBC wideband absorber (type A8/A9). It has been named type A11 and has an equivalent performance to that of BBC type A2 and A3 absorbers combined. It complements, very well, the performance of the A10 very low frequency absorber, described in a companion Report (BBC RD No. 1992/10).

  19. Variability of the soft X-ray excess in IRAS 13224-3809

    Science.gov (United States)

    Kammoun, E.; Papadakis, I.; Sabra, B.

    2016-06-01

    We study the soft excess variability of the narrow line Seyfert 1 galaxy IRAS 13224-3809. We applied the `flux-flux plot' (FFP) method to the five archival XMM-Newton observations. We found that the FFPs are highly affected by the choice of the light curves' time bin size, due to the fast and large amplitude variations, and the intrinsic non-linear flux-flux relations in this source. We constructed FFPs in 11 energy bands below 1.7 keV, and considered the 1.7-3 keV band, as representative of the primary emission. The FFPs are well fitted by a `power-law plus a constant' model. The constants are positive in three out of five observations, consistent with zero in one observation, and negative below 1 keV in another. The best-fit slopes are flatter than unity at energies below ˜ 0.9 keV, suggesting the presence of intrinsic spectral variability. A power-law-like primary component, variable in flux and spectral slope (Γ∝ N_{PL}^{0.1}) and a soft-excess component, varying with the primary continuum (F_{excess}∝ F_{primary}^{0.46}), can explain the FFPs. In fact, this can create positive `constants', even when a stable spectral component does not exist. The negative and null constants, unexplainable by spectral variability, may signify the presence of an intrinsic variable, warm absorber.

  20. Cryometry and excess functions of the adduct of light fullerene c 60 and arginine - c 60(c 6H 12nan 4o 2) 8H 8 aqueous solutions

    OpenAIRE

    MATUZENKO M. YU.; SHESTOPALOVA A.A.; SEMENOV K.N.; CHARYKOV N.A.; KESKINOV V.A.

    2015-01-01

    Cryometry investigation of C 60(C 6H 12NaN 4O 2) H 2O solutions was made over concentrations ranging from 0.1 10 g of fullerene-arginine adduct per 1 dm 3. Freezing point depression was measured for these aqueous solutions. Excess functions for water and fullerene-arginine adduct activities, activity coefficients and excess Gibbs energy of the solutions were calculated. All solutions demonstrate huge deviations from ideality. The last fact, to our opinion, is caused by the very specific hiera...

  1. Skeletal light-scattering accelerates bleaching response in reef-building corals.

    Science.gov (United States)

    Swain, Timothy D; DuBois, Emily; Gomes, Andrew; Stoyneva, Valentina P; Radosevich, Andrew J; Henss, Jillian; Wagner, Michelle E; Derbas, Justin; Grooms, Hannah W; Velazquez, Elizabeth M; Traub, Joshua; Kennedy, Brian J; Grigorescu, Arabela A; Westneat, Mark W; Sanborn, Kevin; Levine, Shoshana; Schick, Mark; Parsons, George; Biggs, Brendan C; Rogers, Jeremy D; Backman, Vadim; Marcelino, Luisa A

    2016-03-21

    At the forefront of ecosystems adversely affected by climate change, coral reefs are sensitive to anomalously high temperatures which disassociate (bleaching) photosynthetic symbionts (Symbiodinium) from coral hosts and cause increasingly frequent and severe mass mortality events. Susceptibility to bleaching and mortality is variable among corals, and is determined by unknown proportions of environmental history and the synergy of Symbiodinium- and coral-specific properties. Symbiodinium live within host tissues overlaying the coral skeleton, which increases light availability through multiple light-scattering, forming one of the most efficient biological collectors of solar radiation. Light-transport in the upper ~200 μm layer of corals skeletons (measured as 'microscopic' reduced-scattering coefficient, μ'(S,m)), has been identified as a determinant of excess light increase during bleaching and is therefore a potential determinant of the differential rate and severity of bleaching response among coral species. Here we experimentally demonstrate (in ten coral species) that, under thermal stress alone or combined thermal and light stress, low-μ'(S,m) corals bleach at higher rate and severity than high-μ'(S,m) corals and the Symbiodinium associated with low-μ'(S,m) corals experience twice the decrease in photochemical efficiency. We further modelled the light absorbed by Symbiodinium due to skeletal-scattering and show that the estimated skeleton-dependent light absorbed by Symbiodinium (per unit of photosynthetic pigment) and the temporal rate of increase in absorbed light during bleaching are several fold higher in low-μ'(S,m) corals. While symbionts associated with low-[Formula: see text] corals receive less total light from the skeleton, they experience a higher rate of light increase once bleaching is initiated and absorbing bodies are lost; further precipitating the bleaching response. Because microscopic skeletal light-scattering is a robust predictor

  2. Thin-film absorber for a solar collector

    Energy Technology Data Exchange (ETDEWEB)

    Wilhelm, W.G.

    1982-02-09

    This invention pertains to energy absorbers for solar collectors, and more particularly to high performance thin film absorbers. The solar collectors comprising the absorber of this invention overcome several problems seen in current systems, such as excessive hardware, high cost and unreliability. In the preferred form, the apparatus features a substantially rigid planar frame with a thin film window bonded to one planar side of the frame. An absorber in accordance with the present invention is comprised of two thin film layers that are sealed perimetrically. In a preferred embodiment, thin film layers are formed from a metal/plastic laminate. The layers define a fluid-tight planar envelope of large surface area to volume through which a heat transfer fluid flows. The absorber is bonded to the other planar side of the frame. The thin film construction of the absorber assures substantially full envelope wetting and thus good efficiency. The window and absorber films stress the frame adding to the overall strength of the collector.

  3. Metamaterial electromagnetic wave absorbers.

    Science.gov (United States)

    Watts, Claire M; Liu, Xianliang; Padilla, Willie J

    2012-06-19

    The advent of negative index materials has spawned extensive research into metamaterials over the past decade. Metamaterials are attractive not only for their exotic electromagnetic properties, but also their promise for applications. A particular branch-the metamaterial perfect absorber (MPA)-has garnered interest due to the fact that it can achieve unity absorptivity of electromagnetic waves. Since its first experimental demonstration in 2008, the MPA has progressed significantly with designs shown across the electromagnetic spectrum, from microwave to optical. In this Progress Report we give an overview of the field and discuss a selection of examples and related applications. The ability of the MPA to exhibit extreme performance flexibility will be discussed and the theory underlying their operation and limitations will be established. Insight is given into what we can expect from this rapidly expanding field and future challenges will be addressed. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Dual broadband metamaterial absorber.

    Science.gov (United States)

    Kim, Young Ju; Yoo, Young Joon; Kim, Ki Won; Rhee, Joo Yull; Kim, Yong Hwan; Lee, YoungPak

    2015-02-23

    We propose polarization-independent and dual-broadband metamaterial absorbers at microwave frequencies. This is a periodic meta-atom array consisting of metal-dielectric-multilayer truncated cones. We demonstrate not only one broadband absorption from the fundamental magnetic resonances but additional broadband absorption in high-frequency range using the third-harmonic resonance, by both simulation and experiment. In simulation, the absorption was over 90% in 3.93-6.05 GHz, and 11.64-14.55 GHz. The corresponding experimental absorption bands over 90% were 3.88-6.08 GHz, 9.95-10.46 GHz and 11.86-13.84 GHz, respectively. The origin of absorption bands was elucidated. Furthermore, it is independent of polarization angle owing to the multilayered circular structures. The design is scalable to smaller size for the infrared and the visible ranges.

  5. Control system design for the deethanizer absorber tower pressure in the light end unit of the Nico Lopez refinery; Diseno del sistema de control para la presion en la torre absorvedora deetanizadora de la unidad de finales ligeros de la refineria Nico Lopez

    Energy Technology Data Exchange (ETDEWEB)

    Morales Corral, Camilo [Refineria Nico Lopez, Ciudad Habana (Cuba)]. E-mail: Camilo.morales@refhab.cupet.cu; Pedre Mendoza, Isabel [DAISA, Ciudad Habana (Cuba)]. E-mail: Isabel@daisa.copextel.com.cu; Garcini Leal, Hector J. [Instituto Superior Politecnico Jose A. Echeverria, La Habana (Cuba)]. E-mail: garcini,novi@electrica.cujae.edu.cu; Fernandez, Luis M. [Instituto de Cibernetica, Matematica y Fisica, La Habana (Cuba)]. E-mail: luis@icmf.inf.cu; Benitez Gonzalez, Ivon Oristela [Instituto Superior Politecnico Jose A. Echeverria, La Habana (Cuba)

    2010-11-15

    This paper is about pressure feed forward control. It is for an absorber tower of the Light End Unit. This one is in the Havana Oil Refinery. Control loop was designed using identification technic and simulation software. Moreover the design control loop has been validated and his quality has been determined. [Spanish] En el presente trabajo se aborda un control anticipatorio de presion. Fue desarrollado para la torre absorvedora de la Unidad de Finales Ligeros. La cual pertenece a la refineria de La Habana. Fue disenado un lazo de control empleando tecnicas de identificacion y programas de simulacion. Ademas el lazo disenado es validado y se determina su calidad.

  6. Aperiodic-metamaterial-based absorber

    Directory of Open Access Journals (Sweden)

    Quanlong Yang

    2017-09-01

    Full Text Available The periodic-metamaterial-based perfect absorber has been studied broadly. Conversely, if the unit cell in the metamaterial-based absorber is arranged aperiodically (aperiodic-metamaterial-based absorber, how does it perform? Inspired by this, here we present a systematic study of the aperiodic-metamaterial-based absorber. By investigating the response of metamaterial absorbers based on periodic, Fibonacci, Thue-Morse, and quasicrystal lattices, we found that aperiodic-metamaterial-based absorbers could display similar absorption behaviors as the periodic one in one hand. However, their absorption behaviors show different tendency depending on the thicknesses of the spacer. Further studies on the angle and polarization dependence of the absorption behavior are also presented.

  7. Aperiodic-metamaterial-based absorber

    Science.gov (United States)

    Yang, Quanlong; Chen, Xieyu; Li, Yanfeng; Zhang, Xueqian; Xu, Yuehong; Tian, Zhen; Ouyang, Chunmei; Gu, Jianqiang; Han, Jiaguang; Zhang, Weili

    2017-09-01

    The periodic-metamaterial-based perfect absorber has been studied broadly. Conversely, if the unit cell in the metamaterial-based absorber is arranged aperiodically (aperiodic-metamaterial-based absorber), how does it perform? Inspired by this, here we present a systematic study of the aperiodic-metamaterial-based absorber. By investigating the response of metamaterial absorbers based on periodic, Fibonacci, Thue-Morse, and quasicrystal lattices, we found that aperiodic-metamaterial-based absorbers could display similar absorption behaviors as the periodic one in one hand. However, their absorption behaviors show different tendency depending on the thicknesses of the spacer. Further studies on the angle and polarization dependence of the absorption behavior are also presented.

  8. Topiramate Induced Excessive Sialorrhea

    Directory of Open Access Journals (Sweden)

    Ersel Dag

    2015-11-01

    Full Text Available It is well-known that drugs such as clozapine and lithium can cause sialorrhea. On the other hand, topiramate has not been reported to induce sialorrhea. We report a case of a patient aged 26 who was given antiepileptic and antipsychotic drugs due to severe mental retardation and intractable epilepsy and developed excessive sialorrhea complaint after the addition of topiramate for the control of seizures. His complaints continued for 1,5 years and ended after giving up topiramate. We presented this case since it was a rare sialorrhea case induced by topiramate. Clinicians should be aware of the possibility of sialorrhea development which causes serious hygiene and social problems when they want to give topiramate to the patients using multiple drugs.

  9. Infrared perfect absorber based on nanowire metamaterial cavities.

    Science.gov (United States)

    He, Yingran; Deng, Huixu; Jiao, Xiangyang; He, Sailing; Gao, Jie; Yang, Xiaodong

    2013-04-01

    An infrared perfect absorber based on a gold nanowire metamaterial cavities array on a gold ground plane is designed. The metamaterial made of gold nanowires embedded in an alumina host exhibits an effective permittivity with strong anisotropy, which supports cavity resonant modes of both electric dipole and magnetic dipole. The impedance of the cavity modes matches the incident plane wave in free space, leading to nearly perfect light absorption. The incident optical energy is efficiently converted into heat so that the local temperature of the absorber will increase. Results show that the designed absorber is polarization-insensitive and nearly omnidirectional for the incident angle.

  10. Excessive zinc ingestion: A reversible cause of sideroblastic anemia and bone marrow depression

    Energy Technology Data Exchange (ETDEWEB)

    Broun, E.R.; Greist, A.; Tricot, G.; Hoffman, R. (Indiana Univ. School of Medicine, Indianapolis (USA))

    1990-09-19

    Two patients with sideroblastic anemia secondary to zinc-induced copper deficiency absorbed excess zinc secondary to oral ingestion. The source of excess zinc was a zinc supplement in one case; in the other, ingested coins. In each case, the sideroblastic anemia was corrected promptly after removal of the source of excess zinc. These two cases emphasize the importance of recognizing this clinical entity, since the myelodysplastic features are completely reversible.

  11. Excessive zinc ingestion. A reversible cause of sideroblastic anemia and bone marrow depression.

    Science.gov (United States)

    Broun, E R; Greist, A; Tricot, G; Hoffman, R

    1990-09-19

    Two patients with sideroblastic anemia secondary to zinc-induced copper deficiency absorbed excess zinc secondary to oral ingestion. The source of excess zinc was a zinc supplement in one case; in the other, ingested coins. In each case, the sideroblastic anemia was corrected promptly after removal of the source of excess zinc. These two cases emphasize the importance of recognizing this clinical entity, since the myelodysplastic features are completely reversible.

  12. Episodic Excessive Blinking in Children.

    Science.gov (United States)

    Mali, Yasmin Poustchi; Simon, John W; Chaudhri, Imran; Zobal-Ratner, Jitka; Barry, Gerard P

    2016-01-01

    Many children present with excessive blinking. Categorization, associated conditions, and prognosis are controversial. All children with excessive blinking were reviewed, excluding those with known uveitis, glaucoma, or obvious eyelid abnormalities. Parents were telephoned for follow-up. No ocular pathology was identified in 31 of 34 children with excessive blinking (91%). Parents were able to report a specific cause of blinking in 7 (21%). In 24 of 34 (71%), parents reported complete resolution of excessive blinking. No new ophthalmologic diagnoses were uncovered on follow-up. Episodes of excessive blinking rarely indicate neurologic disorders and frequently resolve spontaneously. Copyright 2016, SLACK Incorporated.

  13. Multiple-Path-Length Optical Absorbance Cell

    Science.gov (United States)

    2001-01-01

    An optical absorbance cell that offers a selection of multiple optical path lengths has been developed as part of a portable spectrometric instrument that measures absorption spectra of small samples of water and that costs less than does a conventional, non-portable laboratory spectrometer. The instrument is intended, more specifically, for use in studying colored dissolved organic matter (CDOM) in seawater, especially in coastal regions. Accurate characterization of CDOM is necessary for building bio-optical mathematical models of seawater. The multiple path lengths of the absorption cell afford a wide range of sensitivity needed for measuring the optical absorbances associated with the wide range of concentrations of CDOM observed in nature. The instrument operates in the wavelength range of 370 to 725 nm. The major subsystems of the instrument (see figure) include a color-balanced light source; the absorption cell; a peristaltic pump; a high-precision, low-noise fiber optic spectrometer; and a laptop or other personal computer. A fiber-optic cable transmits light from the source to the absorption cell. Other optical fibers transmit light from the absorption cell to the spectrometer,

  14. Leaf absorbance and photosynthesis

    Science.gov (United States)

    Schurer, Kees

    1994-01-01

    The absorption spectrum of a leaf is often thought to contain some clues to the photosynthetic action spectrum of chlorophyll. Of course, absorption of photons is needed for photosynthesis, but the reverse, photosynthesis when there is absorption, is not necessarily true. As a check on the existence of absorption limits we measured spectra for a few different leaves. Two techniques for measuring absorption have been used, viz. the separate determination of the diffuse reflectance and the diffuse transmittance with the leaf at a port of an integrating sphere and the direct determination of the non-absorbed fraction with the leaf in the sphere. In a cross-check both methods yielded the same results for the absorption spectrum. The spectrum of a Fuchsia leaf, covering the short-wave region from 350 to 2500 nm, shows a high absorption in UV, blue and red, the well known dip in the green and a steep fall-off at 700 nm. Absorption drops to virtually zero in the near infrared, with subsequent absorptions, corresponding to the water absorption bands. In more detailed spectra, taken at 5 nm intervals with a 5 nm bandwidth, differences in chlorophyll content show in the different depths of the dip around 550 nm and in a small shift of the absorption edge at 700 nm. Spectra for Geranium (Pelargonium zonale) and Hibiscus (with a higher chlorophyll content) show that the upper limit for photosynthesis can not be much above 700 nm. No evidence, however, is to be seen of a lower limit for photosynthesis and, in fact, some experiments down to 300 nm still did not show a decrease of the absorption although it is well recognized that no photosynthesis results with 300 nm wavelengths.

  15. [Performance of desulfurizing absorbent of roasted navajoite].

    Science.gov (United States)

    Chen, Fang; Yang, Chun-ping; Gan, Hai-ming; Wu, Ting; Chen, Hai-lin; Chen, Hong; Xu, Ke-hui; Xie, Geng-xin

    2010-04-01

    An innovative flue gas desulfurization (FGD) coupling process was proposed in this study to overcome the problems in wet-type limestone/lime processes which include fouling, clogging, and difficulty of selling the by-products and the problems in traditional process for vanadium extraction from navajoite ore such as excessive consumption of sulfuric acid and emissions of pollutants. The performance of a jet bubbling reactor (JBR) at pilot-scale was evaluated using navajoite ore produced in the process of extracting vanadium pentoxide as desulfurization absorbent. Results showed that navajoite ore slurry achieved better desulfurization performance than limestone slurry. When the inlet flue gas pressure drop was 3.0 kPa, the gas flow was about 2350 m3 x h(-1) and the pH of the navajoite ore slurry was higher than 4.5, the desulfurization efficiency was stable about 90%. The SO2 removal efficiency appeared to increase along with the increasing of absorbent cycle-index. The efficiency of the second circulation was improved 3.5% compared to the first circulation. After an operating duration of 40 minutes, the leaching rate of vanadium pentoxide was about 20%, and reached 60% when the by-products were leached with 5% dilute sulfuric acid for 10 hours. The by-product from this process not only could be used to produce vanadium pentoxide which is a valuable industrial product, but also could significantly overcome the pollution problem existing in the traditional refining process of vanadium pentoxide when navajoite ore is used as the feed material. This FGD process using roasted navajoite slurry as absorbent is environmental sound and cost-effective, and shows the potential for application in the field of flue gas desulfurization as well as hydrometallurgy.

  16. Broadband planar multilayered absorbers tuned by VO2 phase transition

    Science.gov (United States)

    Peng, Hao; Ji, Chunhui; Lu, Lulu; Li, Zhe; Li, Haoyang; Wang, Jun; Wu, Zhiming; Jiang, Yadong; Xu, Jimmy; Liu, Zhijun

    2017-08-01

    The metal-insulator transition makes vanadium dioxide an attractive material for developing reconfigurable optoelectronic components. Here we report on dynamically tunable broadband absorbers consisting of planar multilayered thin films. By thermally triggering the phase transition of vanadium dioxide, the effective impedance of multilayered structures is tuned in or out of the condition of impedance matching to free-space, leading to switchable broadband absorptions. Two types of absorbers are designed and demonstrated by using either the insulating or metallic state of vanadium dioxide at the impedance matched condition. The planar multilayered absorbers exhibit tunable absorption bands over the wavelength ranges of 5-9.3 μm and 3.9-8.2 μm, respectively. A large modulation depth up to 88% is measured. The demonstrated broadband absorbance tunability is of potential interest for reconfigurable bolometric sensing, camouflaging, and modulation of mid-infrared lights.

  17. Tunable enhanced optical absorption of graphene using plasmonic perfect absorbers

    Energy Technology Data Exchange (ETDEWEB)

    Cai, Yijun [Institute of Optoelectronic Technology, Department of Electronic Engineering, Xiamen University, Xiamen 361005 (China); Institute of Electromagnetics and Acoustics, Department of Electronic Science, Xiamen University, Xiamen 361005 (China); Zhu, Jinfeng, E-mail: nanoantenna@hotmail.com [Institute of Electromagnetics and Acoustics, Department of Electronic Science, Xiamen University, Xiamen 361005 (China); Liu, Qing Huo [Department of Electrical and Computer Engineering, Duke University, Durham, North Carolina 27708 (United States)

    2015-01-26

    Enhancement and manipulation of light absorption in graphene is a significant issue for applications of graphene-based optoelectronic devices. In order to achieve this purpose in the visible region, we demonstrate a design of a graphene optical absorber inspired by metal-dielectric-metal metamaterial for perfect absorption of electromagnetic waves. The optical absorbance ratios of single and three atomic layer graphene are enhanced up to 37.5% and 64.8%, respectively. The graphene absorber shows polarization-dependence and tolerates a wide range of incident angles. Furthermore, the peak position and bandwidth of graphene absorption spectra are tunable in a wide wavelength range through a specific structural configuration. These results imply that graphene in combination with plasmonic perfect absorbers have a promising potential for developing advanced nanophotonic devices.

  18. Reusable collapsible impact energy absorber

    Energy Technology Data Exchange (ETDEWEB)

    Alghamdi, A.A.A. [Dept. of Mechanical Engineering, King Abdulaziz Univ., Jeddah (Saudi Arabia)

    2003-07-01

    In this paper experimental study of plastic deformation of aluminum frusta when reinverted is presented. Effects of changing the angle of frustum as well as frustum wall thickness on the absorbed energy are investigated. The details of the experimental plastic inversion and reinversion are given. Obtained results show that it is possible to use the inverted aluminum frusta several times, thus they are reusable collapsible absorbers. (orig.)

  19. Nanoscale infrared (IR) spectroscopy and imaging of structural lipids in human stratum corneum using an atomic force microscope to directly detect absorbed light from a tunable IR laser source.

    Science.gov (United States)

    Marcott, Curtis; Lo, Michael; Kjoller, Kevin; Domanov, Yegor; Balooch, Guive; Luengo, Gustavo S

    2013-06-01

    An atomic force microscope (AFM) and a tunable infrared (IR) laser source have been combined in a single instrument (AFM-IR) capable of producing ~200-nm spatial resolution IR spectra and absorption images. This new capability enables IR spectroscopic characterization of human stratum corneum at unprecendented levels. Samples of normal and delipidized stratum corneum were embedded, cross-sectioned and mounted on ZnSe prisms. A pulsed tunable IR laser source produces thermomechanical expansion upon absorption, which is detected through excitation of contact resonance modes in the AFM cantilever. In addition to reducing the total lipid content, the delipidization process damages the stratum corneum morphological structure. The delipidized stratum corneum shows substantially less long-chain CH2 -stretching IR absorption band intensity than normal skin. AFM-IR images that compare absorbances at 2930/cm (lipid) and 3290/cm (keratin) suggest that regions of higher lipid concentration are located at the perimeter of corneocytes in the normal stratum corneum. © 2013 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  20. Measuring Excess Noise in SDL's

    Science.gov (United States)

    Katzberg, S. J.; Kowitz, H. R.; Rowland, C. W.; Shull, T. A.; Ruggles, S. L.; Matthews, L. F.

    1983-01-01

    New instrument gives quantitive information on "excess noise" in semiconductor-diode laser (SDL's). By proper selection of detector, instrument tests any SDL from visible wavelengths through thermal infrared. Lasers determine excess noise in SKL source by measuring photocurrent generated in photodetector exposed first to reference laser then to SKL under test.

  1. Perfect selective metamaterial solar absorbers.

    Science.gov (United States)

    Wang, Hao; Wang, Liping

    2013-11-04

    In this work, we numerically investigate the radiative properties of metamaterial nanostructures made of two-dimensional tungsten gratings on a thin dielectric spacer and an opaque tungsten film from UV to mid-infrared region as potential selective solar absorbers. The metamaterial absorber with single-sized tungsten patches exhibits high absorptance in the visible and near-infrared region due to several mechanisms such as surface plasmon polaritons, magnetic polaritons, and intrinsic bandgap absorption of tungsten. Geometric effects on the resonance wavelengths and the absorptance spectra are studied, and the physical mechanisms are elucidated in detail. The absorptance could be further enhanced in a broader spectral range with double-sized metamaterial absorbers. The total solar absorptance of the optimized metamaterial absorbers at normal incidence could be more than 88%, while the total emittance is less than 3% at 100°C, resulting in total photon-to-heat conversion efficiency of 86% without any optical concentration. Moreover, the metamaterial solar absorbers exhibit quasi-diffuse behaviors as well as polarization independence. The results here will facilitate the design of novel highly efficient solar absorbers to enhance the performance of various solar energy conversion systems.

  2. Full light absorption in single arrays of spherical nanoparticles

    OpenAIRE

    Ra'di, Y.; Asadchy, V. S.; Kosulnikov, S. U.; Omelyanovich, M. M.; Morits, D.; Osipov, A. V.; Simovski, C. R.; Tretyakov, S.A.

    2015-01-01

    In this paper we show that arrays of core-shell nanoparticles function as effective thin absorbers of light. In contrast to known metamaterial absorbers, the introduced absorbers are formed by single planar arrays of spherical inclusions and enable full absorption of light incident on either or both sides of the array. We demonstrate possibilities for realizing different kinds of symmetric absorbers, including resonant, ultra-broadband, angularly selective, and all-angle absorbers. The physic...

  3. Superluminal pulse reflection from a weakly absorbing dielectric slab.

    Science.gov (United States)

    Wang, Li-Gang; Zhu, Shi-Yao

    2006-07-15

    Group delay for a reflected light pulse from a weakly absorbing dielectric slab is theoretically investigated, and large negative group delay is found for weak absorption near a resonance of the slab [Re(kd)=mpi]. The group delay for both the reflected and transmitted pulses will be saturated with an increase of the absorption.

  4. Tungsten based anisotropic metamaterial as an ultra-broadband absorber

    DEFF Research Database (Denmark)

    Lin, Yinyue; Cui, Yanxia; Ding, Fei

    2017-01-01

    : We show theoretically that an array of tungsten/germanium anisotropic nano-cones placed on top of a reflective substrate can absorb light at the wavelength range from 0.3 μm to 9 μm with an average absorption efficiency approaching 98%. It is found that the excitation of multiple orders of slow...

  5. Visible light absorbance enhanced by nitrogen embedded in the surface layer of Mn-doped sodium niobate crystals, detected by ultra violet - visible spectroscopy, x-ray photoelectron spectroscopy, and electric conductivity tests

    Science.gov (United States)

    Molak, A.; Pilch, M.

    2016-05-01

    Sodium niobate crystals doped with manganese ions, Na(NbMn)O3, were annealed in a nitrogen N2 flow at 600, 670, and 930 K. It was verified that simultaneous doping with Mn ions and annealing in nitrogen enhanced the photocatalytic features of sodium niobate. The transmission in the ultraviolet-visible range was measured at room temperature. The absorbance edge is in the range from 3.4 to 2.3 eV. The optical band gap Egap = 1.2-1.3 eV was evaluated using the Tauc relation. Crystals annealed at 670 K and 930 K exhibited an additional shift of the absorption edge of ˜20-40 nm toward longer wavelengths. The optical energy gap narrowed as a result of the superimposed effect of Mn and N co-doping. The x-ray photoelectron spectroscopy test showed that N ions incorporated into the surface layer. The valence band consisted of O 2p states hybridized with Nb 4d, Mn 3d, and N 2s states. The disorder detected in the surroundings of Nb and O ions decreased due to annealing. The binding energy of oxygen ions situated within the surface layer was EB ≈ 531 eV. The other contributions were assigned to molecular contamination. The contribution centered at 535.5 eV vanished after annealing at 600 K and 670 K. The contribution centered at 534 eV vanished after annealing at 930 K. The N2 annealing partly removed carbonates from the surfaces of the samples. In the 480-950 K range, the electric conductivity activation energy, Ea = 0.7-1.2 eV, was comparable with the optical Egap. The electric permittivity showed dispersion in the 0.1-800 kHz range that corresponds to the occurrence of defects.

  6. Does Excessive Pronation Cause Pain?

    DEFF Research Database (Denmark)

    Olesen, Christian Gammelgaard; Nielsen, RG; Rathleff, M

    Excessive pronation could be an inborn abnormality or an acquired foot disorder caused by overuse, inadequate supported shoes or inadequate foot training. When the muscles and ligaments of the foot are insufficient it can cause an excessive pronation of the foot. The current treatment consist...... of antipronation shoes or insoles, which latest was studied by Kulce DG., et al (2007). So far there have been no randomized controlled studies showing methods that can measure the effect of treatments with insoles. Some of the excessive pronation patients recieve antipronation training often if the patient...

  7. Additive manufacturing of RF absorbers

    Science.gov (United States)

    Mills, Matthew S.

    The ability of additive manufacturing techniques to fabricate integrated electromagnetic absorbers tuned for specific radio frequency bands within structural composites allows for unique combinations of mechanical and electromagnetic properties. These composites and films can be used for RF shielding of sensitive electromagnetic components through in-plane and out-of-plane RF absorption. Structural composites are a common building block of many commercial platforms. These platforms may be placed in situations in which there is a need for embedded RF absorbing properties along with structural properties. Instead of adding radar absorbing treatments to the external surface of existing structures, which adds increased size, weight and cost; it could prove to be advantageous to integrate the microwave absorbing properties directly into the composite during the fabrication process. In this thesis, a method based on additive manufacturing techniques of composites structures with prescribed electromagnetic loss, within the frequency range 1 to 26GHz, is presented. This method utilizes screen printing and nScrypt micro dispensing to pattern a carbon based ink onto low loss substrates. The materials chosen for this study will be presented, and the fabrication technique that these materials went through to create RF absorbing structures will be described. The calibration methods used, the modeling of the RF structures, and the applications in which this technology can be utilized will also be presented.

  8. Electronically Switchable Broadband Metamaterial Absorber.

    Science.gov (United States)

    Lee, Dongju; Jeong, Heijun; Lim, Sungjoon

    2017-07-07

    In this study, the novel electronically switchable broadband metamaterial absorber, using a PIN diode, is proposed. The unit cell of the absorber was designed with a Jerusalem-cross resonator and an additive ring structure, based on the FR-4 dielectric substrate. Chip resistors and PIN diodes were used to provide both a broadband characteristic and a switching capability. To satisfy the polarization insensitivity, the unit cell was designed as a symmetrical structure, including the DC bias network, electronic devices, and conductor patterns. The performance of the proposed absorber was verified using full-wave simulation and measurements. When the PIN diode was in the ON state, the proposed absorber had a 90% absorption bandwidth from 8.45-9.3 GHz. Moreover, when the PIN diode was in the OFF state, the 90% absorption bandwidth was 9.2-10.45 GHz. Therefore, the absorption band was successfully switched between the low-frequency band and the high-frequency band as the PIN diode was switched between the ON and OFF states. Furthermore, the unit cell of the proposed absorber was designed as a symmetrical structure, and its performance showed insensitivity with respect to the polarization angle.

  9. Carbon Absorber Retrofit Equipment (CARE)

    Energy Technology Data Exchange (ETDEWEB)

    Klein, Eric [Neumann Systems Group, Incorporated, Colorado Springs, CO (United States)

    2015-12-23

    During Project DE-FE0007528, CARE (Carbon Absorber Retrofit Equipment), Neumann Systems Group (NSG) designed, installed and tested a 0.5MW NeuStream® carbon dioxide (CO2) capture system using the patented NeuStream® absorber equipment and concentrated (6 molal) piperazine (PZ) as the solvent at Colorado Springs Utilities’ (CSU’s) Martin Drake pulverized coal (PC) power plant. The 36 month project included design, build and test phases. The 0.5MW NeuStream® CO2 capture system was successfully tested on flue gas from both coal and natural gas combustion sources and was shown to meet project objectives. Ninety percent CO2 removal was achieved with greater than 95% CO2product purity. The absorbers tested support a 90% reduction in absorber volume compared to packed towers and with an absorber parasitic power of less than 1% when configured for operation with a 550MW coal plant. The preliminary techno-economic analysis (TEA) performed by the Energy and Environmental Research Center (EERC) predicted an over-the-fence cost of $25.73/tonne of CO2 captured from a sub-critical PC plant.

  10. Visible light absorbance enhanced by nitrogen embedded in the surface layer of Mn-doped sodium niobate crystals, detected by ultra violet - visible spectroscopy, x-ray photoelectron spectroscopy, and electric conductivity tests

    Energy Technology Data Exchange (ETDEWEB)

    Molak, A., E-mail: andrzej.molak@us.edu.pl; Pilch, M. [Institute of Physics, University of Silesia, ul. Uniwersytecka 4, 40-007 Katowice (Poland)

    2016-05-28

    Sodium niobate crystals doped with manganese ions, Na(NbMn)O{sub 3}, were annealed in a nitrogen N{sub 2} flow at 600, 670, and 930 K. It was verified that simultaneous doping with Mn ions and annealing in nitrogen enhanced the photocatalytic features of sodium niobate. The transmission in the ultraviolet-visible range was measured at room temperature. The absorbance edge is in the range from 3.4 to 2.3 eV. The optical band gap E{sub gap} = 1.2–1.3 eV was evaluated using the Tauc relation. Crystals annealed at 670 K and 930 K exhibited an additional shift of the absorption edge of ∼20–40 nm toward longer wavelengths. The optical energy gap narrowed as a result of the superimposed effect of Mn and N co-doping. The x-ray photoelectron spectroscopy test showed that N ions incorporated into the surface layer. The valence band consisted of O 2p states hybridized with Nb 4d, Mn 3d, and N 2s states. The disorder detected in the surroundings of Nb and O ions decreased due to annealing. The binding energy of oxygen ions situated within the surface layer was E{sub B} ≈ 531 eV. The other contributions were assigned to molecular contamination. The contribution centered at 535.5 eV vanished after annealing at 600 K and 670 K. The contribution centered at 534 eV vanished after annealing at 930 K. The N{sub 2} annealing partly removed carbonates from the surfaces of the samples. In the 480–950 K range, the electric conductivity activation energy, E{sub a} = 0.7–1.2 eV, was comparable with the optical E{sub gap}. The electric permittivity showed dispersion in the 0.1–800 kHz range that corresponds to the occurrence of defects.

  11. Inferring absorbing organic carbon content from AERONET data

    Directory of Open Access Journals (Sweden)

    A. Arola

    2011-01-01

    Full Text Available Black carbon, light-absorbing organic carbon (often called "brown carbon" and mineral dust are the major light-absorbing aerosols. Currently the sources and formation of brown carbon aerosol in particular are not well understood. In this study we estimated the amount of light–absorbing organic carbon and black carbon from AERONET measurements. We find that the columnar absorbing organic carbon (brown carbon levels in biomass burning regions of South America and Africa are relatively high (about 15–20 mg m−2 during biomass burning season, while the concentrations are significantly lower in urban areas in US and Europe. However, we estimated significant absorbing organic carbon amounts from the data of megacities of newly industrialized countries, particularly in India and China, showing also clear seasonality with peak values up to 30–35 mg m−2 during the coldest season, likely caused by the coal and biofuel burning used for heating. We also compared our retrievals with the modeled organic carbon by the global Oslo CTM for several sites. Model values are higher in biomass burning regions than AERONET-based retrievals, while the opposite is true in urban areas in India and China.

  12. Thin Perfect Absorbers for Electromagnetic Waves: Theory, Design, and Realizations

    Science.gov (United States)

    Ra'di, Y.; Simovski, C. R.; Tretyakov, S. A.

    2015-03-01

    With recent advances in nanophotonics and nanofabrication, considerable progress has been achieved in realizations of thin composite layers designed for full absorption of incident electromagnetic radiation, from microwaves to the visible. If the layer is structured at a subwavelength scale, thin perfect absorbers are usually called "metamaterial absorbers," because these composite structures are designed to emulate some material responses not reachable with any natural material. On the other hand, many thin absorbing composite layers were designed and used already in the time of the introduction of radar technology, predominantly as a means to reduce radar visibility of targets. In view of a wide variety of classical and new topologies of optically thin metamaterial absorbers and plurality of applications, there is a need for a general, conceptual overview of the fundamental mechanisms of full absorption of light or microwave radiation in thin layers. Here, we present such an overview in the form of a general theory of thin perfectly absorbing layers. Possible topologies of perfect metamaterial absorbers are classified based on their fundamental operational principles. For each of the identified classes, we provide design equations and give examples of particular realizations. The concluding section provides a summary and gives an outlook on future developments in this field.

  13. Wideband-Switchable Metamaterial Absorber Using Injected Liquid Metal.

    Science.gov (United States)

    Kim, Hyung Ki; Lee, Dongju; Lim, Sungjoon

    2016-08-22

    Metamaterial absorbers can provide good solutions for radar-cross-section (RCS) reduction. In spite of their attractive features of thinness, lightness, and low cost, resonant metamaterial absorbers have a drawback of narrow bandwidth. For practical radar applications, wideband absorbers are necessary. In this paper, we propose a wideband-switchable metamaterial absorber using liquid metal. In order to reduce RCS both for X-band and C-band, the switchable Jerusalem cross (JC) resonator is introduced. The JC resonator consists of slotted circular rings, chip resistors, and microfluidic channels. The JC resonator is etched on a flexible printed circuit board (FPCB), and the microfluidic channels are laser-etched on a polydimethylsiloxane (PDMS) material. The proposed absorber can switch the absorption frequency band by injecting a liquid metal alloy into the channels. The performance of the absorber was demonstrated through full-wave simulation and through measurements employing prototypes. The experimental results showed absorption ratios of over 90% from 7.43 GHz to 14.34 GHz, and from 5.62 GHz to 7.3 GHz, with empty channels and liquid metal-filled channels, respectively. Therefore, the absorption band was successfully switched between the C-band (4-8 GHz) and the X-band (8-12 GHz) by injecting liquid metal eutectic gallium indium alloy (EGaIn) into the channels.

  14. Wideband-Switchable Metamaterial Absorber Using Injected Liquid Metal

    Science.gov (United States)

    Kim, Hyung Ki; Lee, Dongju; Lim, Sungjoon

    2016-08-01

    Metamaterial absorbers can provide good solutions for radar-cross-section (RCS) reduction. In spite of their attractive features of thinness, lightness, and low cost, resonant metamaterial absorbers have a drawback of narrow bandwidth. For practical radar applications, wideband absorbers are necessary. In this paper, we propose a wideband-switchable metamaterial absorber using liquid metal. In order to reduce RCS both for X-band and C-band, the switchable Jerusalem cross (JC) resonator is introduced. The JC resonator consists of slotted circular rings, chip resistors, and microfluidic channels. The JC resonator is etched on a flexible printed circuit board (FPCB), and the microfluidic channels are laser-etched on a polydimethylsiloxane (PDMS) material. The proposed absorber can switch the absorption frequency band by injecting a liquid metal alloy into the channels. The performance of the absorber was demonstrated through full-wave simulation and through measurements employing prototypes. The experimental results showed absorption ratios of over 90% from 7.43 GHz to 14.34 GHz, and from 5.62 GHz to 7.3 GHz, with empty channels and liquid metal-filled channels, respectively. Therefore, the absorption band was successfully switched between the C-band (4-8 GHz) and the X-band (8-12 GHz) by injecting liquid metal eutectic gallium indium alloy (EGaIn) into the channels.

  15. Does Excessive Pronation Cause Pain?

    DEFF Research Database (Denmark)

    Mølgaard, Carsten Møller; Olesen Gammelgaard, Christian; Nielsen, R. G.

    2008-01-01

    Excessive pronation could be an inborn abnormality or an acquired foot disorder caused by overuse, inadequate supported shoes or inadequate foot training. When the muscles and ligaments of the foot are insufficient it can cause an excessive pronation of the foot. The current treatment consist of ...... pronation patients recieve antipronation training often if the patient is in pain but wanted to investigate if it was possible to measure a change in foot posture after af given treatment....

  16. Polarization insensitive terahertz metamaterial absorber.

    Science.gov (United States)

    Grant, J; Ma, Y; Saha, S; Lok, L B; Khalid, A; Cumming, D R S

    2011-04-15

    We present the simulation, implementation, and measurement of a polarization insensitive resonant metamaterial absorber in the terahertz region. The device consists of a metal/dielectric-spacer/metal structure allowing us to maximize absorption by varying the dielectric material and thickness and, hence, the effective electrical permittivity and magnetic permeability. Experimental absorption of 77% and 65% at 2.12 THz (in the operating frequency range of terahertz quantum cascade lasers) is observed for a spacer of polyimide or silicon dioxide respectively. These metamaterials are promising candidates as absorbing elements for thermally based terahertz imaging.

  17. Ultraviolet light-absorbing and emitting diodes consisting of a p-type transparent-semiconducting NiO film deposited on an n-type GaN homoepitaxial layer

    Science.gov (United States)

    Nakai, Hiroshi; Sugiyama, Mutsumi; Chichibu, Shigefusa F.

    2017-05-01

    Gallium nitride (GaN) and related (Al,Ga,In)N alloys provide practical benefits in the production of light-emitting diodes (LEDs) and laser diodes operating in ultraviolet (UV) to green wavelength regions. However, obtaining low resistivity p-type AlN or AlGaN of large bandgap energies (Eg) is a critical issue in fabricating UV and deep UV-LEDs. NiO is a promising candidate for useful p-type transparent-semiconducting films because its Eg is 4.0 eV and it can be doped into p-type conductivity of sufficiently low resistivity. By using these technologies, heterogeneous junction diodes consisting of a p-type transparent-semiconducting polycrystalline NiO film on an n-type single crystalline GaN epilayer on a low threading-dislocation density, free-standing GaN substrate were fabricated. The NiO film was deposited by using the conventional RF-sputtering method, and the GaN homoepitaxial layer was grown by metalorganic vapor phase epitaxy. They exhibited a significant photovoltaic effect under UV light and also exhibited an electroluminescence peak at 3.26 eV under forward-biased conditions. From the conduction and valence band (EV) discontinuities, the NiO/GaN heterointerface is assigned to form a staggered-type (TYPE-II) band alignment with the EV of NiO higher by 2.0 eV than that of GaN. A rectifying property that is consistent with the proposed band diagram was observed in the current-voltage characteristics. These results indicate that polycrystalline NiO functions as a hole-extracting and injecting layer of UV optoelectronic devices.

  18. PREPARATION AND PROPERTIES OF ABSORBABLE FIBERS FROM L-LACTIDE COPOLYMERS

    NARCIS (Netherlands)

    PENNING, JP; PENNINGS, AJ

    1993-01-01

    Absorbable fibres have been prepared from various copolymers Of L-lactide with either D-lactide or epsilon-caprolactone. The lower crystallinity of these copolymers, compared with the homopolymer, is desirable in the light of their potential use as an absorbable suture material and has a pronounced

  19. Shining light on radiation detection and energy transfer : Triazole ligands used for detection of radiation and lanthanide binding

    NARCIS (Netherlands)

    Dijkstra, Peter

    2016-01-01

    Some substances, fluorophores, absorb light and then emit that light again as fluorescence. Apart from absorption of light, some of these substances can also emit light after having absorbed energy from radiation. A substance which can absorb radiation and emit the energy as light is called a

  20. Thin wideband absorber with optimal thickness

    OpenAIRE

    Kazemzadeh, Alireza

    2010-01-01

    The known methods for designing nonmagnetic absorbers usually aim for either the reduction of total thickness or increase of absorption bandwidth by sacrificing the other parameter. The conventional circuit analog absorbers aim for large bandwidths whereas the newly proposed meta-material or optimized geometry designs try to reduce the thickness of the absorber. By the aid of the capacitive circuit absorber approach, an optimal method for designing thin absorbers with practical bandwidths is...

  1. Oil and fat absorbing polymers

    Science.gov (United States)

    Marsh, H. E., Jr. (Inventor)

    1977-01-01

    A method is described for forming a solid network polymer having a minimal amount of crosslinking for use in absorbing fats and oils. The polymer remains solid at a swelling ratio in oil or fat of at least ten and provides an oil absorption greater than 900 weight percent.

  2. Absorbing-and-diffusing coating

    OpenAIRE

    Tkalich, N. V.; Mokeev, Yu. G.; Onipko, A. F.; Vashchenko, V. F.; Topchev, M. D.; Glebov, V. V.; Ivanchenko, Dmitrij D.; Kolchigin, Nikolay N.; Yevdokimov, V. V.

    2003-01-01

    The paper presents the results of complex experimental research of the absorbing-and-diffusing material "Contrast". It is shown to be an efficient wideband-camouflage material in the radiolocation and the video bands. Ways for improving the material characteristics are outlined.

  3. Backside absorbing layer microscopy: Watching graphene chemistry.

    Science.gov (United States)

    Campidelli, Stéphane; Abou Khachfe, Refahi; Jaouen, Kevin; Monteiller, Jean; Amra, Claude; Zerrad, Myriam; Cornut, Renaud; Derycke, Vincent; Ausserré, Dominique

    2017-05-01

    The rapid rise of two-dimensional nanomaterials implies the development of new versatile, high-resolution visualization and placement techniques. For example, a single graphene layer becomes observable on Si/SiO2 substrates by reflected light under optical microscopy because of interference effects when the thickness of silicon oxide is optimized. However, differentiating monolayers from bilayers remains challenging, and advanced techniques, such as Raman mapping, atomic force microscopy (AFM), or scanning electron microscopy (SEM) are more suitable to observe graphene monolayers. The first two techniques are slow, and the third is operated in vacuum; hence, in all cases, real-time experiments including notably chemical modifications are not accessible. The development of optical microscopy techniques that combine the speed, large area, and high contrast of SEM with the topological information of AFM is therefore highly desirable. We introduce a new widefield optical microscopy technique based on the use of previously unknown antireflection and absorbing (ARA) layers that yield ultrahigh contrast reflection imaging of monolayers. The BALM (backside absorbing layer microscopy) technique can achieve the subnanometer-scale vertical resolution, large area, and real-time imaging. Moreover, the inverted optical microscope geometry allows its easy implementation and combination with other techniques. We notably demonstrate the potentiality of BALM by in operando imaging chemical modifications of graphene oxide. The technique can be applied to the deposition, observation, and modification of any nanometer-thick materials.

  4. Application of Metamaterial in Perfect Absorber

    Directory of Open Access Journals (Sweden)

    ZHANG Yong

    2016-11-01

    Full Text Available Electromagnetic response of metamaterials is not only determined by its component materials but also the microstructure and arrangements of its resonant elements. The perfect absorber prepared by metamaterial (PMA can realize 100% absorption in specific frequency bands by designing reasonable structures of resonators. PMA can be applied in many domains, such as stealth material, frequency selective surface, terahertz imaging, micro antenna, intelligent communication, detection and regulation of electromagnetic wave because of its flexible designing, adjustable response, strong absorption, broad band, thin thickness, light mass. Based on the present study situation at home and abroad, we summarized the development, structure, preparation and test of PMA. In order to gain a more profound and comprehensive understanding on PMA, we also explored its trends, prospects and urgent problems. Proactive and intelligent PMA with multi functions and new PMA prepared by new material and new process are the future development trends.

  5. Bioinspired phase-separated disordered nanostructures for thin photovoltaic absorbers.

    Science.gov (United States)

    Siddique, Radwanul H; Donie, Yidenekachew J; Gomard, Guillaume; Yalamanchili, Sisir; Merdzhanova, Tsvetelina; Lemmer, Uli; Hölscher, Hendrik

    2017-10-01

    The wings of the black butterfly, Pachliopta aristolochiae, are covered by micro- and nanostructured scales that harvest sunlight over a wide spectral and angular range. Considering that these properties are particularly attractive for photovoltaic applications, we analyze the contribution of these micro- and nanostructures, focusing on the structural disorder observed in the wing scales. In addition to microspectroscopy experiments, we conduct three-dimensional optical simulations of the exact scale structure. On the basis of these results, we design nanostructured thin photovoltaic absorbers of disordered nanoholes, which combine efficient light in-coupling and light-trapping properties together with a high angular robustness. Finally, inspired by the phase separation mechanism of self-assembled biophotonic nanostructures, we fabricate these bioinspired absorbers using a scalable, self-assembly patterning technique based on the phase separation of binary polymer mixture. The nanopatterned absorbers achieve a relative integrated absorption increase of 90% at a normal incident angle of light to as high as 200% at large incident angles, demonstrating the potential of black butterfly structures for light-harvesting purposes in thin-film solar cells.

  6. Molecular dynamics of the diatom thylakoid membrane under different light conditions.

    Science.gov (United States)

    Lepetit, Bernard; Goss, Reimund; Jakob, Torsten; Wilhelm, Christian

    2012-03-01

    During the last years significant progress was achieved in unraveling molecular characteristics of the thylakoid membrane of different diatoms. With the present review it is intended to summarize the current knowledge about the structural and functional changes within the thylakoid membrane of diatoms acclimated to different light conditions. This aspect is addressed on the level of the organization and regulation of light-harvesting proteins, the dissipation of excessively absorbed light energy by the process of non-photochemical quenching, and the lipid composition of diatom thylakoid membranes. Finally, a working hypothesis of the domain formation of the diatom thylakoid membrane is presented to highlight the most prominent differences of heterokontic thylakoids in comparison to vascular plants and green algae during the acclimation to low and high light conditions.

  7. Photoluminescence-based quality control for thin film absorber layers of photovoltaic devices

    Science.gov (United States)

    Repins, Ingrid L.; Kuciauskas, Darius

    2015-07-07

    A time-resolved photoluminescence-based system providing quality control during manufacture of thin film absorber layers for photovoltaic devices. The system includes a laser generating excitation beams and an optical fiber with an end used both for directing each excitation beam onto a thin film absorber layer and for collecting photoluminescence from the absorber layer. The system includes a processor determining a quality control parameter such as minority carrier lifetime of the thin film absorber layer based on the collected photoluminescence. In some implementations, the laser is a low power, pulsed diode laser having photon energy at least great enough to excite electron hole pairs in the thin film absorber layer. The scattered light may be filterable from the collected photoluminescence, and the system may include a dichroic beam splitter and a filter that transmit the photoluminescence and remove scattered laser light prior to delivery to a photodetector and a digital oscilloscope.

  8. Insight into magnetorheological shock absorbers

    CERN Document Server

    Gołdasz, Janusz

    2015-01-01

    This book deals with magnetorheological fluid theory, modeling and applications of automotive magnetorheological dampers. On the theoretical side a review of MR fluid compositions and key factors affecting the characteristics of these fluids is followed by a description of existing applications in the area of vibration isolation and flow-mode shock absorbers in particular. As a majority of existing magnetorheological devices operates in a so-called flow mode a critical review is carried out in that regard. Specifically, the authors highlight common configurations of flow-mode magnetorheological shock absorbers, or so-called MR dampers that have been considered by the automotive industry for controlled chassis applications. The authors focus on single-tube dampers utilizing a piston assembly with one coil or multiple coils and at least one annular flow channel in the piston.

  9. Digital Alloy Absorber for Photodetectors

    Science.gov (United States)

    Hill, Cory J. (Inventor); Ting, David Z. (Inventor); Gunapala, Sarath D. (Inventor)

    2016-01-01

    In order to increase the spectral response range and improve the mobility of the photo-generated carriers (e.g. in an nBn photodetector), a digital alloy absorber may be employed by embedding one (or fraction thereof) to several monolayers of a semiconductor material (insert layers) periodically into a different host semiconductor material of the absorber layer. The semiconductor material of the insert layer and the host semiconductor materials may have lattice constants that are substantially mismatched. For example, this may performed by periodically embedding monolayers of InSb into an InAsSb host as the absorption region to extend the cutoff wavelength of InAsSb photodetectors, such as InAsSb based nBn devices. The described technique allows for simultaneous control of alloy composition and net strain, which are both key parameters for the photodetector operation.

  10. A randomised controlled trial of absorbable versus non-absorbable sutures for skin closure after open carpal tunnel release.

    LENUS (Irish Health Repository)

    Theopold, C

    2012-05-01

    We compared the aesthetic outcome of scars after closure of open carpal tunnel incisions with either absorbable 4-0 Vicryl Rapide or non-absorbable 4-0 Novafil. Patients were recruited in a randomized controlled trial and scars were scored at 6 weeks using a modified Patient and Observer Scar Assessment Scale. Scores demonstrated differences only for pain, vascularity and cross-hatching between both groups, though none of these were statistically significant. The dissolving and falling out of Vicryl Rapide was significantly more comfortable than removal of 4-0 Novafil sutures, assessed on a numerical analogue scale. There was no difference in infection rate between both study groups, supporting overall the use of Vicryl Rapide for the closure of palmar hand incisions, in light of the convenience and cost savings associated with absorbable sutures.

  11. Excessive masturbation after epilepsy surgery.

    Science.gov (United States)

    Ozmen, Mine; Erdogan, Ayten; Duvenci, Sirin; Ozyurt, Emin; Ozkara, Cigdem

    2004-02-01

    Sexual behavior changes as well as depression, anxiety, and organic mood/personality disorders have been reported in temporal lobe epilepsy (TLE) patients before and after epilepsy surgery. The authors describe a 14-year-old girl with symptoms of excessive masturbation in inappropriate places, social withdrawal, irritability, aggressive behavior, and crying spells after selective amygdalohippocampectomy for medically intractable TLE with hippocampal sclerosis. Since the family members felt extremely embarrassed, they were upset and angry with the patient which, in turn, increased her depressive symptoms. Both her excessive masturbation behavior and depressive symptoms remitted within 2 months of psychoeducative intervention and treatment with citalopram 20mg/day. Excessive masturbation is proposed to be related to the psychosocial changes due to seizure-free status after surgery as well as other possible mechanisms such as Kluver-Bucy syndrome features and neurophysiologic changes associated with the cessation of epileptic discharges. This case demonstrates that psychiatric problems and sexual changes encountered after epilepsy surgery are possibly multifactorial and in adolescence hypersexuality may be manifested as excessive masturbation behavior.

  12. Acoustic Properties of Absorbent Asphalts

    Science.gov (United States)

    Trematerra, Amelia; Lombardi, Ilaria

    2017-08-01

    Road traffic is one of the greater cause of noise pollution in urban centers; a prolonged exposure to this source of noise disturbs populations subjected to it. In this paper is reported a study on the absorbent coefficients of asphalt. The acoustic measurements are carried out with a impedance tube (tube of Kundt). The sample are measured in three conditions: with dry material (traditional), “wet” asphalt and “dirty” asphalt.

  13. Absorbance enhancement in microplate wells for improved-sensitivity biosensors.

    Science.gov (United States)

    Suárez, Guillaume; Santschi, Christian; Plateel, Gregory; Martin, Olivier J F; Riediker, Michael

    2014-06-15

    A generic optical biosensing strategy was developed that relies on the absorbance enhancement phenomenon occurring in a multiple scattering matrix. Experimentally, inserts made of glass fiber membrane were placed into microplate wells in order to significantly lengthen the trajectory of the incident light through the sample and therefore increase the corresponding absorbance. Enhancement factor was calculated by comparing the absorbance values measured for a given amount of dye with and without the absorbance-enhancing inserts in the wells. Moreover, the dilution of dye in solutions with different refractive indices (RI) clearly revealed that the enhancement factor increased with the ΔRI between the membrane and the surrounding medium, reaching a maximum value (EF>25) when the membranes were dried. On this basis, two H2O2-biosensing systems were developed based on the biofunctionalization of the glass fiber inserts either with cytochrome c or horseradish peroxidase (HRP) and the analytical performances were systematically compared with the corresponding bioassay in solution. The efficiency of the absorbance-enhancement approach was particularly clear in the case of the cytochrome c-based biosensor with a sensitivity gain of 40 folds and wider dynamic range. Therefore, the developed strategy represents a promising way to convert standard colorimetric bioassays into optical biosensors with improved sensitivity. Copyright © 2014 Elsevier B.V. All rights reserved.

  14. Crying - excessive (0-6 months)

    Science.gov (United States)

    ... provider will check the infant's growth and development. Antibiotics may be prescribed if the baby has a bacterial infection. Alternative Names Infants - excessive crying; Well child - excessive crying ...

  15. Nepal Ambient Monitoring and Source Testing Experiment (NAMaSTE: emissions of trace gases and light-absorbing carbon from wood and dung cooking fires, garbage and crop residue burning, brick kilns, and other sources

    Directory of Open Access Journals (Sweden)

    C. E. Stockwell

    2016-09-01

    Full Text Available The Nepal Ambient Monitoring and Source Testing Experiment (NAMaSTE campaign took place in and around the Kathmandu Valley and in the Indo-Gangetic Plain (IGP of southern Nepal during April 2015. The source characterization phase targeted numerous important but undersampled (and often inefficient combustion sources that are widespread in the developing world such as cooking with a variety of stoves and solid fuels, brick kilns, open burning of municipal solid waste (a.k.a. trash or garbage burning, crop residue burning, generators, irrigation pumps, and motorcycles. NAMaSTE produced the first, or rare, measurements of aerosol optical properties, aerosol mass, and detailed trace gas chemistry for the emissions from many of the sources. This paper reports the trace gas and aerosol measurements obtained by Fourier transform infrared (FTIR spectroscopy, whole-air sampling (WAS, and photoacoustic extinctiometers (PAX; 405 and 870 nm based on field work with a moveable lab sampling authentic sources. The primary aerosol optical properties reported include emission factors (EFs for scattering and absorption coefficients (EF Bscat, EF Babs, in m2 kg−1 fuel burned, single scattering albedos (SSAs, and absorption Ångström exponents (AAEs. From these data we estimate black and brown carbon (BC, BrC emission factors (g kg−1 fuel burned. The trace gas measurements provide EFs (g kg−1 for CO2, CO, CH4, selected non-methane hydrocarbons up to C10, a large suite of oxygenated organic compounds, NH3, HCN, NOx, SO2, HCl, HF, etc. (up to ∼ 80 gases in all. The emissions varied significantly by source, and light absorption by both BrC and BC was important for many sources. The AAE for dung-fuel cooking fires (4.63 ± 0.68 was significantly higher than for wood-fuel cooking fires (3.01 ± 0.10. Dung-fuel cooking fires also emitted high levels of NH3 (3.00 ± 1.33 g kg−1, organic acids (7.66 ± 6.90 g kg−1, and HCN

  16. Nepal Ambient Monitoring and Source Testing Experiment (NAMaSTE): emissions of trace gases and light-absorbing carbon from wood and dung cooking fires, garbage and crop residue burning, brick kilns, and other sources

    Science.gov (United States)

    Stockwell, Chelsea E.; Christian, Ted J.; Goetz, J. Douglas; Jayarathne, Thilina; Bhave, Prakash V.; Praveen, Puppala S.; Adhikari, Sagar; Maharjan, Rashmi; DeCarlo, Peter F.; Stone, Elizabeth A.; Saikawa, Eri; Blake, Donald R.; Simpson, Isobel J.; Yokelson, Robert J.; Panday, Arnico K.

    2016-09-01

    The Nepal Ambient Monitoring and Source Testing Experiment (NAMaSTE) campaign took place in and around the Kathmandu Valley and in the Indo-Gangetic Plain (IGP) of southern Nepal during April 2015. The source characterization phase targeted numerous important but undersampled (and often inefficient) combustion sources that are widespread in the developing world such as cooking with a variety of stoves and solid fuels, brick kilns, open burning of municipal solid waste (a.k.a. trash or garbage burning), crop residue burning, generators, irrigation pumps, and motorcycles. NAMaSTE produced the first, or rare, measurements of aerosol optical properties, aerosol mass, and detailed trace gas chemistry for the emissions from many of the sources. This paper reports the trace gas and aerosol measurements obtained by Fourier transform infrared (FTIR) spectroscopy, whole-air sampling (WAS), and photoacoustic extinctiometers (PAX; 405 and 870 nm) based on field work with a moveable lab sampling authentic sources. The primary aerosol optical properties reported include emission factors (EFs) for scattering and absorption coefficients (EF Bscat, EF Babs, in m2 kg-1 fuel burned), single scattering albedos (SSAs), and absorption Ångström exponents (AAEs). From these data we estimate black and brown carbon (BC, BrC) emission factors (g kg-1 fuel burned). The trace gas measurements provide EFs (g kg-1) for CO2, CO, CH4, selected non-methane hydrocarbons up to C10, a large suite of oxygenated organic compounds, NH3, HCN, NOx, SO2, HCl, HF, etc. (up to ˜ 80 gases in all). The emissions varied significantly by source, and light absorption by both BrC and BC was important for many sources. The AAE for dung-fuel cooking fires (4.63 ± 0.68) was significantly higher than for wood-fuel cooking fires (3.01 ± 0.10). Dung-fuel cooking fires also emitted high levels of NH3 (3.00 ± 1.33 g kg-1), organic acids (7.66 ± 6.90 g kg-1), and HCN (2.01 ± 1.25 g kg-1), where the latter could

  17. Plasmonic titanium nitride nanostructures for perfect absorbers

    DEFF Research Database (Denmark)

    Guler, Urcan; Li, Wen-Wei; Kinsey, Nathaniel

    2013-01-01

    We propose a metamaterial based perfect absorber in the visible region, and investigate the performance of titanium nitride as an alternative plasmonic material. Numerical and experimental results reveal that titanium nitride performs better than gold as a plasmonic absorbing material...

  18. Substitution of the wall of the trachea by absorbable synthetic material.

    Science.gov (United States)

    Greve, H

    1988-02-01

    Synthetic, absorbable tissue proved to supply a valuable "interim support" for an orderly reconstruction of the wall of the trachea during the first three months following surgery. This is in general the result of experiments in which the use of implanted Polyglactin 910 as a substitute material for the tracheal wall of rats and rabbits was tested. Additionally the possibilities for satisfactory stabilization of the tracheal wall by means of Polydioxanon, another synthetic substance, which is absorbed more slowly, were investigated. The experiments were performed in a total of 30 rats and 70 rabbits. Initial attempts to substitute the entire circumference of the tracheal wall in the area of the neck by synthetics resulted in excessive difficulties post-surgically. Frequently substantial stenoses, obstructing respiration, developed. Consequently, patches of substitute material, covering more than half of the circumference of the trachea, were applied. The periods of survival of the animals ranged from one to 23 weeks. Following autopsy and macroscopical inspection, selected specimens were examined histologically by means of light microscopes and scanning electron microscopes. Evaluation of the samples showed progressive lining of the inner surface of the prosthetic patches with connective tissue and subsequent covering with squamous cell epithelium. On the average, approximately six weeks after surgery, ciliated columnar epithelium resembling normal respiratory mucosa developed. Gradually the synthetic fabric was replaced by dense connective tissue, which finally contained newly generated hyaline cartilage also. The very slow rate of dissolution of the polydioxanone material provided sufficient time for the formation of a new, stratified wall of the trachea, maintaining sufficient clearance in the tracheal lumen.

  19. Excess plutonium disposition using ALWR technology

    Energy Technology Data Exchange (ETDEWEB)

    Phillips, A. (ed.); Buckner, M.R.; Radder, J.A.; Angelos, J.G.; Inhaber, H.

    1993-02-01

    The Office of Nuclear Energy of the Department of Energy chartered the Plutonium Disposition Task Force in August 1992. The Task Force was created to assess the range of practicable means of disposition of excess weapons-grade plutonium. Within the Task Force, working groups were formed to consider: (1) storage, (2) disposal,and(3) fission options for this disposition,and a separate group to evaluate nonproliferation concerns of each of the alternatives. As a member of the Fission Working Group, the Savannah River Technology Center acted as a sponsor for light water reactor (LWR) technology. The information contained in this report details the submittal that was made to the Fission Working Group of the technical assessment of LWR technology for plutonium disposition. The following aspects were considered: (1) proliferation issues, (2) technical feasibility, (3) technical availability, (4) economics, (5) regulatory issues, and (6) political acceptance.

  20. Sustainable composite super absorbents made from polysaccharides

    OpenAIRE

    Ye, Zhuoliang; Tang, Mi; Hong, Xiaoting; K. S. Hui

    2016-01-01

    Compared to traditional super absorbent polymers using raw materials from petrochemical industry, natural polymer absorbents are more favorable because they are sustainable and biodegradable. In this study, composite absorbents were developed by crosslinking carrageenan with sodium alginate using calcium chloride. Effect of composition on absorption was tested. Absorption was improved by increasing carrageenan content. The super absorbent exhibited the maximal swelling ratio of 13.1 g/g in 0....

  1. Porphyrin Based Near Infrared-Absorbing Materials for Organic Photovoltaics

    Science.gov (United States)

    Zhong, Qiwen

    The conservation and transformation of energy is essential to the survival of mankind, and thus concerns every modern society. Solar energy, as an everlasting source of energy, holds one of the key solutions to some of the most urgent problems the world now faces, such as global warming and the oil crisis. Advances in technologies utilizing clean, abundant solar energy, could be the steering wheel of our societies. Solar cells, one of the major advances in converting solar energy into electricity, are now capturing people's interest all over the globe. While solar cells have been commercially available for many years, the manufacturing of solar cells is quite expensive, limiting their broad based implementation. The cost of solar cell based electricity is 15-50 cents per kilowatt hour (¢/kwh), depending on the type of solar cell, compared to 0.7 ¢/kwh for fossil fuel based electricity. Clearly, decreasing the cost of electricity from solar cells is critical for their wide spread deployment. This will require a decrease in the cost of light absorbing materials and material processing used in fabricating the cells. Organic photovoltaics (OPVs) utilize organic materials such as polymers and small molecules. These devices have the advantage of being flexible and lower cost than conventional solar cells built from inorganic semiconductors (e.g. silicon). The low cost of OPVs is tied to lower materials and fabrication costs of organic cells. However, the current power conversion efficiencies of OPVs are still below 15%, while convention crystalline Si cells have efficiencies of 20-25%. A key limitation in OPVs today is their inability to utilize the near infrared (NIR) portion of the solar spectrum. This part of the spectrum comprises nearly half of the energy in sunlight that could be used to make electricity. The first and foremost step in conversion solar energy conversion is the absorption of light, which nature has provided us optimal model of, which is

  2. Severe rhabdomyolysis after excessive bodybuilding.

    Science.gov (United States)

    Finsterer, J; Zuntner, G; Fuchs, M; Weinberger, A

    2007-12-01

    A 46-year-old male subject performed excessive physical exertion during 4-6 h in a studio for body builders during 5 days. He was not practicing sport prior to this training and denied the use of any aiding substances. Despite muscle aching already after 1 day, he continued the exercises. After the last day, he recognized tiredness and cessation of urine production. Two days after discontinuation of the training, a Herpes simplex infection occurred. Because of acute renal failure, he required hemodialysis. There were absent tendon reflexes and creatine kinase (CK) values up to 208 274 U/L (normal: <170 U/L). After 2 weeks, CK had almost normalized and, after 4 weeks, hemodialysis was discontinued. Excessive muscle training may result in severe, hemodialysis-dependent rhabdomyolysis. Triggering factors may be prior low fitness level, viral infection, or subclinical metabolic myopathy.

  3. 10 CFR 904.9 - Excess capacity.

    Science.gov (United States)

    2010-01-01

    ... Marketing § 904.9 Excess capacity. (a) If the Uprating Program results in Excess Capacity, Western shall be entitled to such Excess Capacity to integrate the operation of the Boulder City Area Projects and other... 10 Energy 4 2010-01-01 2010-01-01 false Excess capacity. 904.9 Section 904.9 Energy DEPARTMENT OF...

  4. 12 CFR 925.23 - Excess stock.

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 7 2010-01-01 2010-01-01 false Excess stock. 925.23 Section 925.23 Banks and... BANKS Stock Requirements § 925.23 Excess stock. (a) Sale of excess stock. Subject to the restriction in paragraph (b) of this section, a member may purchase excess stock as long as the purchase is approved by the...

  5. Broadband polarization-independent perfect absorber using a phase-change metamaterial at visible frequencies.

    Science.gov (United States)

    Cao, Tun; Wei, Chen-wei; Simpson, Robert E; Zhang, Lei; Cryan, Martin J

    2014-02-04

    We report a broadband polarization-independent perfect absorber with wide-angle near unity absorbance in the visible regime. Our structure is composed of an array of thin Au squares separated from a continuous Au film by a phase change material (Ge2Sb2Te5) layer. It shows that the near perfect absorbance is flat and broad over a wide-angle incidence up to 80° for either transverse electric or magnetic polarization due to a high imaginary part of the dielectric permittivity of Ge2Sb2Te5. The electric field, magnetic field and current distributions in the absorber are investigated to explain the physical origin of the absorbance. Moreover, we carried out numerical simulations to investigate the temporal variation of temperature in the Ge2Sb2Te5 layer and to show that the temperature of amorphous Ge2Sb2Te5 can be raised from room temperature to > 433 K (amorphous-to-crystalline phase transition temperature) in just 0.37 ns with a low light intensity of 95 nW/μm(2), owing to the enhanced broadband light absorbance through strong plasmonic resonances in the absorber. The proposed phase-change metamaterial provides a simple way to realize a broadband perfect absorber in the visible and near-infrared (NIR) regions and is important for a number of applications including thermally controlled photonic devices, solar energy conversion and optical data storage.

  6. Design of metamaterial surfaces with broadband absorbance.

    Science.gov (United States)

    Wu, Chihhui; Shvets, Gennady

    2012-02-01

    A simple design paradigm for making broadband ultrathin plasmonic absorbers is introduced. The absorber's unit cell is composed of subunits of various sizes, resulting in nearly 100% absorbance at multiple adjacent frequencies and high absorbance over a broad frequency range. A simple theoretical model for designing broadband absorbers is presented. It uses a single-resonance model to describe the optical response of each subunit and employs the series circuit model to predict the overall response. Validity of the circuit model relies on short propagation lengths of the surface plasmons.

  7. Multi-channel coherent perfect absorbers

    KAUST Repository

    Bai, Ping

    2016-05-18

    The absorption efficiency of a coherent perfect absorber usually depends on the phase coherence of the incident waves on the surfaces. Here, we present a scheme to create a multi-channel coherent perfect absorber in which the constraint of phase coherence is loosened. The scheme has a multi-layer structure such that incident waves in different channels with different angular momenta can be simultaneously and perfectly absorbed. This absorber is robust in achieving high absorption efficiency even if the incident waves become "incoherent" and possess "random" wave fronts. Our work demonstrates a unique approach to designing highly efficient metamaterial absorbers. © CopyrightEPLA, 2016.

  8. Graphene based salisbury screen for terahertz absorber

    Science.gov (United States)

    Min Woo, Jeong; Kim, Min-Sik; Woong Kim, Hyun; Jang, Jae-Hyung

    2014-02-01

    A graphene-based, multiband absorber operating in terahertz (THz) frequency range was demonstrated. Graphene film was transferred onto the top of a flexible polymer substrate backed with a gold reflector. The graphene acts as a resistive film that partially attenuates and reflects THz waves. The destructive interference between THz waves reflected from graphene and backside reflector gives rise to perfect absorbance at multiple frequencies. To enhance the absorbance on/off ratio (AR), the conductivity of graphene was varied using a chemical doping method. The resulting p-doped, graphene-based THz absorber exhibited absorbance at maxima and AR higher than 0.95 and 25 dB, respectively.

  9. Toroidal-dipole induced plasmonic perfect absorber

    Science.gov (United States)

    Li, Jie; Wang, Ying-hua; Jin, Ren-chao; Li, Jia-qi; Dong, Zheng-gao

    2017-12-01

    We present a new kind of perfect absorber which roots in a toroidal dipole resonance. The toroidal metastructure consists of a metallic circular groove with a depth asymmetry, which couples to the toroidal dipole field in the near-infrared region and thus realizes nearly unit absorbance, acting as a perfect absorber. Moreover, this absorber owns a high sensitivity of 609.6 nm/RIU to the dielectric surroundings. Furthermore, by tuning the geometric parameters, both the toroidal dipole resonance and perfect absorbance characteristics are insensitive to the circular groove width, providing profound fabrication tolerance in future experiments.

  10. Light Absorption Coefficients for Soluble Species in Snow, Dome C, Antarctica, Version 1

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set contains light absorption coefficients for soluble chromophores (light-absorbing chemicals) and concentrations of hydrogen peroxide (HOOH) and nitrate...

  11. Simplified Production of Organic Compounds Containing High Enantiomer Excesses

    Science.gov (United States)

    Cooper, George W. (Inventor)

    2015-01-01

    The present invention is directed to a method for making an enantiomeric organic compound having a high amount of enantiomer excesses including the steps of a) providing an aqueous solution including an initial reactant and a catalyst; and b) subjecting said aqueous solution simultaneously to a magnetic field and photolysis radiation such that said photolysis radiation produces light rays that run substantially parallel or anti-parallel to the magnetic field passing through said aqueous solution, wherein said catalyst reacts with said initial reactant to form the enantiomeric organic compound having a high amount of enantiomer excesses.

  12. Photosynthetic Properties and Potentials for Improvement of Photosynthesis in Pale Green Leaf Rice under High Light Conditions.

    Science.gov (United States)

    Gu, Junfei; Zhou, Zhenxiang; Li, Zhikang; Chen, Ying; Wang, Zhiqin; Zhang, Hao; Yang, Jianchang

    2017-01-01

    Light is the driving force of plant growth, providing the energy required for photosynthesis. However, photosynthesis is also vulnerable to light-induced damage caused by the production of reactive oxygen species (ROS). Plants have therefore evolved various protective mechanisms such as non-photochemical quenching (NPQ) to dissipate excessively absorbed solar energy as heat; however, photoinhibition and NPQ represent a significant loss in solar energy and photosynthetic efficiency, which lowers the yield potential in crops. To estimate light capture and light energy conversion in rice, a genotype with pale green leaves (pgl) and a normally pigmented control (Z802) were subjected to high (HL) and low light (LL). Chlorophyll content, light absorption, chloroplast micrographs, abundance of light-harvesting complex (LHC) binding proteins, electron transport rates (ETR), photochemical and non-photochemical quenching, and generation of ROS were subsequently examined. Pgl had a smaller size of light-harvesting chlorophyll antenna and absorbed less photons than Z802. NPQ and the generation of ROS were also low, while photosystem II efficiency and ETR were high, resulting in improved photosynthesis and less photoinhibition in pgl than Z802. Chlorophyll synthesis and solar conversion efficiency were higher in pgl under HL compared to LL treatment, while Z802 showed an opposite trend due to the high level of photoinhibition under HL. In Z802, excessive absorption of solar energy not only increased the generation of ROS and NPQ, but also exacerbated the effects of increases in temperature, causing midday depression in photosynthesis. These results suggest that photosynthesis and yield potential in rice could be enhanced by truncated light-harvesting chlorophyll antenna size.

  13. Photosynthetic Properties and Potentials for Improvement of Photosynthesis in Pale Green Leaf Rice under High Light Conditions

    Directory of Open Access Journals (Sweden)

    Junfei Gu

    2017-06-01

    Full Text Available Light is the driving force of plant growth, providing the energy required for photosynthesis. However, photosynthesis is also vulnerable to light-induced damage caused by the production of reactive oxygen species (ROS. Plants have therefore evolved various protective mechanisms such as non-photochemical quenching (NPQ to dissipate excessively absorbed solar energy as heat; however, photoinhibition and NPQ represent a significant loss in solar energy and photosynthetic efficiency, which lowers the yield potential in crops. To estimate light capture and light energy conversion in rice, a genotype with pale green leaves (pgl and a normally pigmented control (Z802 were subjected to high (HL and low light (LL. Chlorophyll content, light absorption, chloroplast micrographs, abundance of light-harvesting complex (LHC binding proteins, electron transport rates (ETR, photochemical and non-photochemical quenching, and generation of ROS were subsequently examined. Pgl had a smaller size of light-harvesting chlorophyll antenna and absorbed less photons than Z802. NPQ and the generation of ROS were also low, while photosystem II efficiency and ETR were high, resulting in improved photosynthesis and less photoinhibition in pgl than Z802. Chlorophyll synthesis and solar conversion efficiency were higher in pgl under HL compared to LL treatment, while Z802 showed an opposite trend due to the high level of photoinhibition under HL. In Z802, excessive absorption of solar energy not only increased the generation of ROS and NPQ, but also exacerbated the effects of increases in temperature, causing midday depression in photosynthesis. These results suggest that photosynthesis and yield potential in rice could be enhanced by truncated light-harvesting chlorophyll antenna size.

  14. Excess Early Mortality in Schizophrenia

    DEFF Research Database (Denmark)

    Laursen, Thomas Munk; Nordentoft, Merete; Mortensen, Preben Bo

    2014-01-01

    Schizophrenia is often referred to as one of the most severe mental disorders, primarily because of the very high mortality rates of those with the disorder. This article reviews the literature on excess early mortality in persons with schizophrenia and suggests reasons for the high mortality...... as well as possible ways to reduce it. Persons with schizophrenia have an exceptionally short life expectancy. High mortality is found in all age groups, resulting in a life expectancy of approximately 20 years below that of the general population. Evidence suggests that persons with schizophrenia may...

  15. The impact of absorbed photons on antimicrobial photodynamic efficacy

    Directory of Open Access Journals (Sweden)

    Fabian eCieplik

    2015-07-01

    Full Text Available Due to increasing resistance of pathogens towards standard antimicrobial procedures, alternative approaches that are capable of inactivating pathogens are necessary in support of regular modalities. In this instance, the photodynamic inactivation of bacteria (PIB may be a promising alternative. For clinical application of PIB it is essential to ensure appropriate comparison of given photosensitizer (PS-light source systems, which is complicated by distinct absorption and emission characteristics of given PS and their corresponding light sources, respectively.Consequently, in the present study two strategies for adjustment of irradiation parameters are evaluated: (i matching energy doses applied by respective light sources (common practice and (ii by development and application of a formula for adjusting the numbers of photons absorbed by PS upon irradiation by their corresponding light sources. Since according to the photodynamic principle one PS molecule is excited by the absorption of one photon, this formula allows comparison of photodynamic efficacy of distinct PS per excited molecule.In light of this, the antimicrobial photodynamic efficacy of recently developed PS SAPYR was compared to that of clinical standard PS Methylene Blue (MB regarding inactivation of monospecies biofilms formed by Enterococcus faecalis and Actinomyces naeslundii whereby evaluating both adjustment strategies.PIB with SAPYR exhibited CFU-reductions of 5.1 log10 and 6.5 log10 against E. faecalis and A. naeslundii, respectively, which is declared as a disinfectant efficacy. In contrast, the effect of PIB with MB was smaller when the applied energy dose was adjusted compared to SAPYR (CFU-reductions of 3.4 log10 and 4.2 log10 against E. faecalis and A. naeslundii, or there was even no effect at all when the number of absorbed photons was adjusted compared to SAPYR. Since adjusting the numbers of absorbed photons is the more precise and adequate method from a

  16. Excessive hoarding in Parkinson's disease.

    Science.gov (United States)

    O'Sullivan, Sean S; Djamshidian, Atbin; Evans, Andrew H; Loane, Clare M; Lees, Andrew J; Lawrence, Andrew D

    2010-06-15

    Hoarding is seen in several psychiatric conditions, but has not been specifically assessed in Parkinson's disease (PD). This study investigates hoarding tendency amongst patients with PD, and its association with impulsive-compulsive spectrum behaviors (ICBs). We compare clinical features, measures of hoarding, impulse buying, self-control, obsessive-compulsive symptoms, depression, and anxiety in 39 patients with PD with ICBs (PD + ICB), 61 patients with PD without ICBs (PD - ICB), and 50 healthy controls. A much higher proportion of PD + ICB (27.8%) than PD - ICB (3.5%) were hoarders (P = 0.001). 6% of healthy controls were hoarders. Compulsive shoppers scored higher than other varieties of ICB on excessive acquisition measures. Hoarding correlated positively with impulsive buying, obsessive-compulsive symptoms, PD duration, and negatively with self-control measures. Using multivariate regression analyzes, the presence of ICBs and measures of impulsive buying were the only variables independently associated with hoarding in PD. The association of hoarding with other ICBs and low trait impulse control suggests that excessive hoarding is related to the spectrum of impulsive behaviors in PD. (c) 2010 Movement Disorder Society.

  17. ARCHITECTURE OF A CHARGE-TRANSFER STATE REGULATING LIGHT HARVESTING IN A PLANT ANTENNA PROTEIN

    Energy Technology Data Exchange (ETDEWEB)

    Fleming, Graham; Ahn, Tae Kyu; Avenson, Thomas J.; Ballottari, Matteo; Cheng, Yuan-Chung; Niyogi, Krishna K.; Bassi, Roberto; Fleming, Graham R.

    2008-04-02

    Energy-dependent quenching of excess absorbed light energy (qE) is a vital mechanism for regulating photosynthetic light harvesting in higher plants. All of the physiological characteristics of qE have been positively correlated with charge-transfer between coupled chlorophyll and zeaxanthin molecules in the light-harvesting antenna of photosystem II (PSII). In this work, we present evidence for charge-transfer quenching in all three of the individual minor antenna complexes of PSII (CP29, CP26, and CP24), and we conclude that charge-transfer quenching in CP29 involves a de-localized state of an excitonically coupled chlorophyll dimer. We propose that reversible conformational changes in CP29 can `tune? the electronic coupling between the chlorophylls in this dimer, thereby modulating the energy of the chlorophylls-zeaxanthin charge-transfer state and switching on and off the charge-transfer quenching during qE.

  18. Energy-Absorbing Beam Member

    Science.gov (United States)

    Littell, Justin D. (Inventor)

    2017-01-01

    An energy-absorbing (EA) beam member and having a cell core structure is positioned in an aircraft fuselage proximate to the floor of the aircraft. The cell core structure has a length oriented along a width of the fuselage, a width oriented along a length of the fuselage, and a depth extending away from the floor. The cell core structure also includes cell walls that collectively define a repeating conusoidal pattern of alternating respective larger and smaller first and second radii along the length of the cell core structure. The cell walls slope away from a direction of flight of the aircraft at a calibrated lean angle. An EA beam member may include the cell core structure and first and second plates along the length of the cell core structure on opposite edges of the cell material.

  19. Optical absorbers based on strong interference in ultra-thin films

    CERN Document Server

    Kats, Mikhail A

    2016-01-01

    Optical absorbers find uses in a wide array of applications across the electromagnetic spectrum, including photovoltaic and photochemical cells, photodetectors, optical filters, stealth technology, and thermal light sources. Recent efforts have sought to reduce the footprint of optical absorbers, conventionally based on graded structures or Fabry-Perot-type cavities, by using the emerging concepts of plasmonics, metamaterials, and metasurfaces. Unfortunately, these new absorber designs require patterning on subwavelength length scales, and are therefore impractical for many large-scale optical and optoelectronic devices. In this article, we summarize recent progress in the development of optical absorbers based on lossy films with thicknesses significantly smaller than the incident optical wavelength. These structures have a small footprint and require no nanoscale patterning. We outline the theoretical foundation of these absorbers based on "ultra-thin-film interference", including the concepts of loss-induc...

  20. OLED lighting devices having multi element light extraction and luminescence conversion layer

    Science.gov (United States)

    Krummacher, Benjamin Claus; Antoniadis, Homer

    2010-11-16

    An apparatus such as a light source has a multi element light extraction and luminescence conversion layer disposed over a transparent layer of the light source and on the exterior of said light source. The multi-element light extraction and luminescence conversion layer includes a plurality of light extraction elements and a plurality of luminescence conversion elements. The light extraction elements diffuses the light from the light source while luminescence conversion elements absorbs a first spectrum of light from said light source and emits a second spectrum of light.

  1. Graphene metamaterial for multiband and broadband terahertz absorber

    Science.gov (United States)

    Gao, Runmei; Xu, Zongcheng; Ding, Chunfeng; Wu, Liang; Yao, Jianquan

    2015-12-01

    In this paper, we present the efficient design of functional graphene thin film metamaterial on a metal-plane separated by a thick dielectric layer. Perfect absorption is characterized by the complete suppression of incident and reflected light and complete dissipation of incident energy. We investigate the properties of graphene metamaterials and demonstrate multiband absorbers that have five absorption bands, using silicon interlayers, in the 0-2.2 THz range. The absorption rate reached up to 99.9% at a frequency of 1.08 THz, and the quality factor was 6.98 for a 0.14 THz bandwidth. We present a novel theoretical interpretation based on standing wave field theory, which shows that coherent superposition of the incident and reflection rays produce stationary waves, and the field energy localized inside the thick spacers and dissipated through the metal-planes. Thus, light was effectively trapped in the metamaterial absorbers with negligible near-field interactions, causing high absorption. The theory developed here explains all features observed in multiband metamaterial absorbers and therefore provides a profound understanding of the underlying physical mechanisms.

  2. Semiconductor nanowire optical antenna solar absorbers.

    Science.gov (United States)

    Cao, Linyou; Fan, Pengyu; Vasudev, Alok P; White, Justin S; Yu, Zongfu; Cai, Wenshan; Schuller, Jon A; Fan, Shanhui; Brongersma, Mark L

    2010-02-10

    Photovoltaic (PV) cells can serve as a virtually unlimited clean source of energy by converting sunlight into electrical power. Their importance is reflected in the tireless efforts that have been devoted to improving the electrical and structural properties of PV materials. More recently, photon management (PM) has emerged as a powerful additional means to boost energy conversion efficiencies. Here, we demonstrate an entirely new PM strategy that capitalizes on strong broad band optical antenna effects in one-dimensional semiconductor nanostructures to dramatically enhance absorption of sunlight. We show that the absorption of sunlight in Si nanowires (Si NWs) can be significantly enhanced over the bulk. The NW's optical properties also naturally give rise to an improved angular response. We propose that by patterning the silicon layer in a thin film PV cell into an array of NWs, one can boost the absorption for solar radiation by 25% while utilizing less than half of the semiconductor material (250% increase in the light absorption per unit volume of material). These results significantly advance our understanding of the way sunlight is absorbed by one-dimensional semiconductor nanostructures and provide a clear, intuitive guidance for the design of efficient NW solar cells. The presented approach is universal to any semiconductor and a wide range of nanostructures; as such, it provides a new PV platform technology.

  3. A Six-Fold Symmetric Metamaterial Absorber

    OpenAIRE

    Álvarez, Humberto Fernández; Gómez, María de Cos; Las-Heras, Fernando

    2015-01-01

    A novel microwave metamaterial absorber design is introduced along with its manufacturing and characterization. Significant results considering both bandwidth and angular stability are achieved. Parametric analysis and simplified equivalent circuit are provided to give an insight on the key elements influencing the absorber performance. In addition, the constitutive parameters of the effective medium model are obtained and related to the absorber resonant behavior. Moreover, a new thinner an...

  4. Multiband Negative Permittivity Metamaterials and Absorbers

    Directory of Open Access Journals (Sweden)

    Yiran Tian

    2013-01-01

    Full Text Available Design and characteristics of multiband negative permittivity metamaterial and its absorber configuration are presented in this paper. The proposed multiband metamaterial is composed of a novel multibranch resonator which can possess four electric resonance frequencies. It is shown that, by controlling the length of the main branches of such resonator, the resonant frequencies and corresponding absorbing bands of metamaterial absorber can be shifted in a large frequency band.

  5. A Multilayer Rubber Board Radar Absorbing Material

    OpenAIRE

    He, Shan; LI Yehua; Zhou, Chun

    2016-01-01

    Based on the theory of impedance matching, a multilayer absorbing material with the "pitfall" structure was designed. The multilayer absorbing material with 5 layers was obtained by optimization of the schemes, and the material shows 2 absorbing peaks in the broadband of 2~18 GHz frequencies. The peak in high frequencies can be adjusted with no effect on the peak in low frequencies through changing the thickness of the fifth layer. The changes of input impedances were displayed by analyzing t...

  6. The effects of excessive humidity.

    Science.gov (United States)

    Williams, R B

    1998-06-01

    Humidification devices and techniques can expose the airway mucosa to a wide range of gas temperatures and humidities, some of which are excessive and may cause injury. Humidified gas is a carrier of both water and energy. The volume of water in the gas stream depends on whether the water is in a molecular form (vapor), particulate form (aerosol), or bulk form (liquid). The energy content of gas stream is the sum of the sensible heat (temperature) of the air and any water droplets in it and the heat of vaporization (latent energy) of any water vapor present. Latent heat energy is much larger than sensible heat energy, so saturated air contains much more energy than dry air. Thus every breath contains a water volume and energy (thermal) challenge to the airway mucosa. When the challenge exceeds the homeostatic mechanisms airway dysfunction begins, starting at the cellular and secretion level and progressing to whole airway function. A large challenge will result in quick progression of dysfunction. Early dysfunction is generally reversible, however, so large challenges with short exposure times may not cause irreversible injury. The mechanisms of airway injury owing to excess water are not well studied. The observation of its effects lends itself to some general conclusions, however. Alterations in the ventilation-perfusion ratio, decrease in vital capacity and compilance, and atelectasis are suggestive of partial or full occlusion of small airways. Changes in surface tension and alveolar-arterial oxygen gradient are consistent with flooding of alveoli. There also may be osmotic challenges to mucosal cell function as evidenced by the different reaction rates with hyper- and hypotonic saline. The reaction to nonisotonic saline also may partly explain increases in specific airway resistance. Aerosolized water and instilled water may be hazardous because of their demonstrated potential for delivering excessive water to the airway. Their use for airway humidification or

  7. Monte Carlo simulation for the prediction of precision of absorbance measurements with a miniature CCD spectrometer

    OpenAIRE

    Tsaousoglou, E. P.; Bolis, S. D.; Efstathiou, C. E.

    2003-01-01

    The precision characteristics of the absorbance measurements obtained with a low-cost miniature spectrometer incorporating an array detector were evaluated. Uncertainties in absorbance measurements were due to a combination of non-uniform light intensity and detector response over the wavelength range examined (350-850 nm), in conjunction with the digitization of the intensity indications and the intrinsic noise of the detecting elements. The precision characteristics are presented as contour...

  8. A Six-Fold Symmetric Metamaterial Absorber.

    Science.gov (United States)

    Fernández Álvarez, Humberto; de Cos Gómez, María Elena; Las-Heras, Fernando

    2015-04-03

    A novel microwave metamaterial absorber design is introduced along with its manufacturing and characterization. Significant results considering both bandwidth and angular stability are achieved. Parametric analysis and simplified equivalent circuit are provided to give an insight on the key elements influencing the absorber performance. In addition, the constitutive parameters of the effective medium model are obtained and related to the absorber resonant behavior. Moreover, a new thinner and more flexible absorber version, preserving broad bandwidth and angular insensitive performance, is simulated, and an 8 × 8 unit-cells prototype is manufactured and measured for a limited angular margin in an anechoic chamber.

  9. A Six-Fold Symmetric Metamaterial Absorber

    Directory of Open Access Journals (Sweden)

    Humberto Fernández Álvarez

    2015-04-01

    Full Text Available A novel microwave metamaterial absorber design is introduced along with its manufacturing and characterization. Significant results considering both bandwidth and angular stability are achieved. Parametric analysis and simplified equivalent circuit are provided to give an insight on the key elements influencing the absorber performance. In addition, the constitutive parameters of the effective medium model are obtained and related to the absorber resonant behavior. Moreover, a new thinner and more flexible absorber version, preserving broad bandwidth and angular insensitive performance, is simulated, and an 8 × 8 unit-cells prototype is manufactured and measured for a limited angular margin in an anechoic chamber.

  10. Radiative properties of scattering and absorbing dense media: theory and experimental study

    Energy Technology Data Exchange (ETDEWEB)

    Hespel, Laurent; Mainguy, Stephane; Greffet, J.-J

    2003-03-01

    We investigate the validity of the radiative transfer equation to model transmission of light through an absorbing and scattering medium. Assuming that radiative transfer equation is valid, the inverse scattering problem for non-polarized radiative transfer in one-dimensional absorbing and scattering media is solved using a parameter identification method. We discuss how to identify the albedo, phase function and extinction coefficient of the medium. We present experimental data that confirm that this approach is robust and can be used to make reliable predictions of the behavior of scattering absorbing systems.

  11. 10 CFR 904.10 - Excess energy.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 4 2010-01-01 2010-01-01 false Excess energy. 904.10 Section 904.10 Energy DEPARTMENT OF ENERGY GENERAL REGULATIONS FOR THE CHARGES FOR THE SALE OF POWER FROM THE BOULDER CANYON PROJECT Power Marketing § 904.10 Excess energy. (a) If excess Energy is determined by the United States to be available...

  12. 7 CFR 985.56 - Excess oil.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 8 2010-01-01 2010-01-01 false Excess oil. 985.56 Section 985.56 Agriculture... HANDLING OF SPEARMINT OIL PRODUCED IN THE FAR WEST Order Regulating Handling Volume Limitations § 985.56 Excess oil. Oil of any class in excess of a producer's applicable annual allotment shall be identified as...

  13. 43 CFR 426.12 - Excess land.

    Science.gov (United States)

    2010-10-01

    ... 43 Public Lands: Interior 1 2010-10-01 2010-10-01 false Excess land. 426.12 Section 426.12 Public Lands: Interior Regulations Relating to Public Lands BUREAU OF RECLAMATION, DEPARTMENT OF THE INTERIOR ACREAGE LIMITATION RULES AND REGULATIONS § 426.12 Excess land. (a) The process of designating excess and...

  14. Excess water dynamics in hydrotalcite: QENS study

    Indian Academy of Sciences (India)

    Abstract. Results of the quasi-elastic neutron scattering (QENS) measurements on the dynamics of excess water in hydrotalcite sample with varied content of excess water are reported. Translational motion of excess water can be best described by random transla- tional jump diffusion model. The observed increase in ...

  15. Conciliating SUSY with the Z-peaked excess

    Directory of Open Access Journals (Sweden)

    Mitsou Vasiliki A.

    2016-01-01

    Full Text Available The ATLAS experiment observed an excess at the 3σ level in the channel of Z boson, jets and high missing transverse momentum in the full 2012 dataset at 8 TeV while searching for SUSY. The question arises whether the abundance and the kinematical features of this excess are compatible with the yet unconstrained supersymmetric realm, respecting at the same time the measured Higgs boson properties and dark matter density. By trying to explain this signal with SUSY we find that only relatively light gluinos together with a heavy neutralino NLSP decaying predominantly to a Z boson plus a light gravitino could reproduce the excess. We construct an explicit general gauge mediation model able to match the observed signal. More sophisticated models could also reproduce the signal, as long as it features light gluinos, or heavy particles with a strong production cross section, producing at least one Z boson in its decay chain. The implications of our findings for the Run II at LHC with the scaling on the Z peak, as well as for the direct search of gluinos and other SUSY particles, are also discussed.

  16. Device for absorbing mechanical shock

    Science.gov (United States)

    Newlon, C.E.

    1979-08-29

    This invention is a comparatively inexpensive but efficient shock-absorbing device having special application to the protection of shipping and storage cylinders. In a typical application, two of the devices are strapped to a cylinder to serve as saddle-type supports for the cylinder during storage and to protect the cylinder in the event it is dropped during lifting or lowering operations. In its preferred form, the invention includes a hardwood plank whose grain runs in the longitudinal direction. The basal portion of the plank is of solid cross-section, whereas the upper face of the plank is cut away to form a concave surface fittable against the sidewall of a storage cylinder. The concave surface is divided into a series of segments by transversely extending, throughgoing relief slots. A layer of elastomeric material is positioned on the concave face, the elastomer being extrudable into slots when pressed against the segments by a preselected pressure characteristic of a high-energy impact. The compressive, tensile, and shear properties of the hardwood and the elastomer are utilized in combination to provide a surprisingly high energy-absorption capability.

  17. Light sheet microscopy reveals more gradual light attenuation in light green versus dark green soybean leaves

    Science.gov (United States)

    Light wavelengths preferentially absorbed by chlorophyll (chl) often display steep absorption gradients. This oversaturates photosynthesis in upper chloroplasts and deprives lower chloroplasts of blue and red light, causing a steep gradient in carbon fixation. Reducing chl content could create a mor...

  18. Absorbing Property of Multi-layered Short Carbon Fiber Absorbing Coating

    OpenAIRE

    Liu, Zhaohui; Tao, Rui; Ban, Guodong; Luo, Ping

    2017-01-01

    The radar absorbing coating was prepared with short carbon fiber asabsorbent and waterborne polyurethane (WPU) as matrix resin. The coating’s absorbing property was tested with vectornetwork analyzer, using aramid honeycomb as air layer which was matched withcarbon fiber coating. The results demonstrate that the single-layered carbonfiber absorbing coating presented relatively poor absorbing property when thelayer was thin, and the performance was slightly improved after the matched airlayer ...

  19. Ultra-wideband microwave absorber by connecting multiple absorption bands of two different-sized hyperbolic metamaterial waveguide arrays

    OpenAIRE

    Yin, Xiang; Long, Chang; Li, Junhao; Zhu, Hua; Chen, Lin; Guan, Jianguo; Li, Xun

    2015-01-01

    Microwave absorbers have important applications in various areas including stealth, camouflage, and antenna. Here, we have designed an ultra-broadband light absorber by integrating two different-sized tapered hyperbolic metamaterial (HMM) waveguides, each of which has wide but different absorption bands due to broadband slow-light response, into a unit cell. Both the numerical and experimental results demonstrate that in such a design strategy, the low absorption bands between high absorption...

  20. Absorbed radiation dose on LHC interconnects

    CERN Document Server

    Versaci, R; Vlachoudis, V; CERN. Geneva. ATS Department

    2011-01-01

    Here we present the results of our FLUKA simulations devoted to the evaluation of the peak dose absorbed by the busbar insulator in the LHC Interaction Region 7 interconnects. The peak dose absorbed by the cold magnet coils are also presented.

  1. A Flexible Metamaterial Terahertz Perfect Absorber

    Science.gov (United States)

    Chen, X. R.; Zheng, Y. W.; Qin, L. M.; Wei, G. C.; Qin, Z. P.; Zhang, N. G.; Liu, K.; Li, S. Z.; Wang, S. X.

    2017-12-01

    We designed a THz matematerial absorber using metallic wires (MWs) and split resonant rings (SRRs). This matematerial absorber exhibits perfect absorption which up to 96% at 4.03 THz and is capable of wrapped around objects because of flexible polyimide dielectric substrate.

  2. Tuned mass absorber on a flexible structure

    DEFF Research Database (Denmark)

    Krenk, Steen; Høgsberg, Jan Becker

    2014-01-01

    The classic design of a tuned mass absorber is based on a simple two-mass analogy in which the tuned mass is connected to the structural mass with a spring and a viscous damper. In a flexible multi-degree-of-freedom structure the tuned mass absorber is typically introduced to provide damping of a...

  3. An ultrathin dual-band metamaterial absorber

    Science.gov (United States)

    Zhang, Yong; Duan, Junping; Zhang, Wendong; Wang, Wanjun; Zhang, Binzhen

    2016-10-01

    The design and preparation of an ultrathin dual-band metamaterial absorber whose resonant frequency located at radar wave (20 GHz-60 GHz) is presented in this paper. The absorber is composed of a 2-D periodic sandwich featured with two concentric annuluses. The influence on the absorber's performance produced by resonant cell's structure size and material parameters was numerically simulated and analyzed based on the standard full wave finite integration technology in CST. Laser ablation process was adopted to prepare the designed absorber on epoxy resin board coated with on double plane of copper with a thickness that is 1/30 and 1/50 of the resonant wavelength at a resonant frequency of 30.51 GHz and 48.15 GHz. The full width at half maximum (FWHM) reached 2.2 GHz and 2.35 GHz and the peak of the absorptance reached 99.977%. The ultrathin absorber is nearly omnidirectional for all polarizations. The test results of prepared sample testify the designed absorber's excellent absorbing performance forcefully. The absorber expands inspirations of radar stealth in military domain due to its flexible design, cost-effective and other outstanding properties.

  4. 21 CFR 872.6050 - Saliva absorber.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Saliva absorber. 872.6050 Section 872.6050 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES DENTAL DEVICES Miscellaneous Devices § 872.6050 Saliva absorber. (a) Identification. A saliva...

  5. Sleepiness or excessive daytime somnolence.

    Science.gov (United States)

    Edd, Ethel Mitty; Flores, Sandi

    2009-01-01

    Excessive daytime somnolence (EDS) is associated with age-related changes, environment, circadian rhythm or sleep pattern disorder, insomnia, medications, lifestyle factors, depression, pain, and illness. The notion of "sleep architecture" connotes a structure that describes the sleep cycle (i.e., stages) and wakefulness during a single sleep period-that is, rapid eye movement (REM) and non-REM sleep. Circadian rhythms perform a variety of functions including regulation of the quality and distribution of the stages of sleep. Insomnia includes delayed sleep onset as well as premature wakening; sleep is nonrestorative. Comorbidities associated with insomnia are Alzheimer's disease and other dementias, delirium, depression, congestive heart failure, chronic obstructive pulmonary disease, gastroesophageal reflux disease, pain, degenerative diseases of the neurological system, and sleep apnea. Continuous inadequate sleep affects cognitive function, physical performance, overall well-being, and quality of life. There is a greater risk of falls from insomnia than is the use of hypnotics to manage it. Sleep disruption among older adults is underrecognized and undertreated. Assessment using valid tools can be performed rapidly. There are a variety of treatment options, including sleep hygiene and pharmacological and alternative modalities.

  6. Principles of light energy management

    Energy Technology Data Exchange (ETDEWEB)

    Davis, N. [Growth Chambers, Chagrin Falls, OH (United States)

    1994-12-31

    A review is presented on methods to minimize the effects of excess energy associated with lighting systems for plant growth. Information on lamp efficiencies and methods for separating and collecting unwanted heat is included.

  7. Full light absorption in single arrays of spherical nanoparticles

    CERN Document Server

    Ra'di, Y; Kosulnikov, S U; Omelyanovich, M M; Morits, D; Osipov, A V; Simovski, C R; Tretyakov, S A

    2015-01-01

    In this paper we show that arrays of core-shell nanoparticles function as effective thin absorbers of light. In contrast to known metamaterial absorbers, the introduced absorbers are formed by single planar arrays of spherical inclusions and enable full absorption of light incident on either or both sides of the array. We demonstrate possibilities for realizing different kinds of symmetric absorbers, including resonant, ultra-broadband, angularly selective, and all-angle absorbers. The physical principle behind these designs is explained considering balanced electric and magnetic responses of unit cells. Photovoltaic devices and thermal emitters are the two most important potential applications of the proposed designs.

  8. Comparison of disposable diapers with fluff absorbent and fluff plus absorbent polymers: effects on skin hydration, skin pH, and diaper dermatitis.

    Science.gov (United States)

    Davis, J A; Leyden, J J; Grove, G L; Raynor, W J

    1989-06-01

    Diaper dermatitis results from the action of a number of physical and chemical factors on the skin. While its etiology is complex, there is agreement that prolonged contact between wet diapers and the skin leading to excessive hydration of the stratum corneum and reduced barrier function is a primary factor. Recent research also indicates that pH elevation resulting from ammonia production increases the probability of skin damage due to fecal enzyme activity. New diapers containing absorbent polymers blended with cellulose fluff in the absorbent core have been developed. The absorbent polymer binds fluids and controls pH in the diaper environment. To assess the effectiveness of these diapers, a clinical study was conducted with approximately 150 infants over 15 weeks, using fluff diapers and absorbent polymer diapers. The results clearly showed that the diapers with absorbent polymer provide a better skin environment than those with fluff only with respect to lower skin wetness and pH control (instrumental measurements). In addition, the clinicians' grades indicated a directional reduction in diaper rash severity.

  9. Absorbable Meshes in Inguinal Hernia Surgery

    DEFF Research Database (Denmark)

    Öberg, Stina; Andresen, Kristoffer; Rosenberg, Jacob

    2017-01-01

    PURPOSE: Absorbable meshes used in inguinal hernia repair are believed to result in less chronic pain than permanent meshes, but concerns remain whether absorbable meshes result in an increased risk of recurrence. The aim of this study was to present an overview of the advantages and limitations...... of fully absorbable meshes for the repair of inguinal hernias, focusing mainly on postoperative pain and recurrence. METHODS: This systematic review with meta-analyses is based on searches in PubMed, Embase, Cochrane, and Psychinfo. Included study designs were case series, cohort studies, randomized...... controlled trials (RCTs), and non-RCTs. Studies had to include adult patients undergoing an inguinal hernia repair with a fully absorbable mesh. RESULTS: The meta-analyses showed no difference in recurrence rates (median 18 months follow-up) and chronic pain rates (1 year follow-up) between absorbable...

  10. A Multilayer Rubber Board Radar Absorbing Material

    Directory of Open Access Journals (Sweden)

    HE Shan

    2016-08-01

    Full Text Available Based on the theory of impedance matching, a multilayer absorbing material with the "pitfall" structure was designed. The multilayer absorbing material with 5 layers was obtained by optimization of the schemes, and the material shows 2 absorbing peaks in the broadband of 2~18 GHz frequencies. The peak in high frequencies can be adjusted with no effect on the peak in low frequencies through changing the thickness of the fifth layer. The changes of input impedances were displayed by analyzing the impedance chart. The prepared multilayer absorbing material was named JB-5, which processes the reflectivity no more than -12 dB in 6~17 GHz with the thickness no more than 5 mm and a good performance of standing the environment. The absorbing material can be produced in laboratory and pasted on surfaces of target with special adhesive by trimmed into required shapes so as to reduce the reflection of electromagnetic waves effectively.

  11. [Absorbed doses in dental radiology].

    Science.gov (United States)

    Bianchi, S D; Roccuzzo, M; Albrito, F; Ragona, R; Anglesio, S

    1996-01-01

    The growing use of dento-maxillo-facial radiographic examinations has been accompanied by the publication of a large number of studies on dosimetry. A thorough review of the literature is presented in this article. Most studies were carried out on tissue equivalent skull phantoms, while only a few were in vivo. The aim of the present study was to evaluate in vivo absorbed doses during Orthopantomography (OPT). Full Mouth Periapical Examination (FMPE) and Intraoral Tube Panoramic Radiography (ITPR). Measurements were made on 30 patients, reproducing clinical conditions, in 46 anatomical sites, with 24 intra- and 22 extra-oral thermoluminiscent dosimeters (TLDS). The highest doses were measured, in orthopantomography, at the right mandibular angle (1899 mu Gy) in FMPE on the right naso-labial fold (5640 mu Gy and in ITPR on the palatal surface of the left second upper molar (1936 mu Gy). Intraoral doses ranged from 21 mu Gy, in orthopantomography, to 4494 mu Gy in FMPE. Standard errors ranged from 142% in ITPR to 5% in orthopantomography. The highest rate of standard errors was found in FMPE and ITPR. The data collected in this trial are in agreement with others in major literature reports. Disagreements are probably due to different exam acquisition and data collections. Such differences, presented comparison in several sites, justify lower doses in FMPE and ITPR. Advantages and disadvantages of in vivo dosimetry of the maxillary region are discussed, the former being a close resemblance to clinical conditions of examination and the latter the impossibility of collecting values in depth of tissues. Finally, both ITPR and FMPE required lower doses than expected, and can be therefore reconsidered relative to their radiation risk.

  12. 75 FR 27572 - Monthly Report of Excess Income and Annual Report of Uses of Excess Income

    Science.gov (United States)

    2010-05-17

    ... URBAN DEVELOPMENT Monthly Report of Excess Income and Annual Report of Uses of Excess Income AGENCY... subject proposal. Project owners are permitted to retain Excess Income for projects under terms and conditions established by HUD. Owners must request to retain some or all of their Excess Income. The request...

  13. Design of a nonlinear torsional vibration absorber

    Science.gov (United States)

    Tahir, Ammaar Bin

    Tuned mass dampers (TMD) utilizing linear spring mechanisms to mitigate destructive vibrations are commonly used in practice. A TMD is usually tuned for a specific resonant frequency or an operating frequency of a system. Recently, nonlinear vibration absorbers attracted attention of researchers due to some potential advantages they possess over the TMDs. The nonlinear vibration absorber, or the nonlinear energy sink (NES), has an advantage of being effective over a broad range of excitation frequencies, which makes it more suitable for systems with several resonant frequencies, or for a system with varying excitation frequency. Vibration dissipation mechanism in an NES is passive and ensures that there is no energy backflow to the primary system. In this study, an experimental setup of a rotational system has been designed for validation of the concept of nonlinear torsional vibration absorber with geometrically induced cubic stiffness nonlinearity. Dimensions of the primary system have been optimized so as to get the first natural frequency of the system to be fairly low. This was done in order to excite the dynamic system for torsional vibration response by the available motor. Experiments have been performed to obtain the modal parameters of the system. Based on the obtained modal parameters, the design optimization of the nonlinear torsional vibration absorber was carried out using an equivalent 2-DOF modal model. The optimality criterion was chosen to be maximization of energy dissipation in the nonlinear absorber attached to the equivalent 2-DOF system. The optimized design parameters of the nonlinear absorber were tested on the original 5-DOF system numerically. A comparison was made between the performance of linear and nonlinear absorbers using the numerical models. The comparison showed the superiority of the nonlinear absorber over its linear counterpart for the given set of primary system parameters as the vibration energy dissipation in the former is

  14. Multimodal tuned dynamic absorber for split Stirling linear cryocooler

    Science.gov (United States)

    Veprik, A.; Tuito, A.

    2017-02-01

    Forthcoming low size, weight, power and price split Stirling linear cryocoolers may rely on electro-dynamically driven single-piston compressors and pneumatically driven expanders interconnected by the configurable transfer line. For compactness, compressor and expander units may be placed in a side-by-side manner, thus producing tonal vibration export comprising force and moment components. In vibration sensitive applications, this may result in excessive angular line of sight jitter and translational defocusing affecting the image quality. The authors present Multimodal Tuned Dynamic Absorber (MTDA), having one translational and two tilting modes essentially tuned to the driving frequency. The dynamic reactions (force and moment) produced by such a MTDA are simultaneously counterbalancing force and moment vibration export produced by the cryocooler. The authors reveal the design details, the method of fine modal tuning and outcomes of numerical simulation on attainable performance.

  15. Acclimation responses to high light by Guazuma ulmifolia Lam. (Malvaceae) leaves at different stages of development.

    Science.gov (United States)

    Calzavara, A K; Rocha, J S; Lourenço, G; Sanada, K; Medri, C; Bianchini, E; Pimenta, J A; Stolf-Moreira, R; Oliveira, H C

    2017-09-01

    The re-composition of deforested environments requires the prior acclimation of seedlings to full sun in nurseries. Seedlings can overcome excess light either through the acclimation of pre-existing fully expanded leaves or through the development of new leaves that are acclimated to the new light environment. Here, we compared the acclimation capacity of mature (MatL, fully expanded at the time of transfer) and newly expanded (NewL, expanded after the light shift) leaves of Guazuma ulmifolia Lam. (Malvaceae) seedlings to high light. The seedlings were initially grown under shade and then transferred to full sunlight. MatL and NewL were used for chlorophyll fluorescence and gas exchange analyses, pigment extraction and morpho-anatomical measurements. After the transfer of seedlings to full sun, the MatL persisted and acclimated to some extent to the new light condition, since they underwent alterations in some morpho-physiological traits and maintained a functional electron transport chain and positive net photosynthesis rate. However, long-term exposure to high light led to chronic photoinhibition in MatL, which could be related to the limited plasticity of leaf morpho-anatomical attributes. However, the NewL showed a high capacity to use the absorbed energy in photochemistry and dissipate excess energy harmlessly, attributes that were favoured by the high structural plasticity exhibited by these leaves. Both the maintenance of mature, photosynthetically active leaves and the production of new leaves with a high capacity to cope with excess energy were important for acclimation of G. ulmifolia seedlings. © 2017 German Botanical Society and The Royal Botanical Society of the Netherlands.

  16. Integrated optical NIR-evanescent wave absorbance sensorfor chemical analysis.

    Science.gov (United States)

    Bürck, J; Zimmermann, B; Mayer, J; Ache, H J

    1996-01-01

    A new, long-path integrated optical (IO) sensor for the detection of non-polar organic substances is described. The sensing layer deposited on a planar multimode IO structure is built by a suitable silicone polymer with lower refractive index (RI). It acts as a hydrophobic matrix for the reversible enrichment of non-polar organic contaminants from water or air. Light from the near-infrared (NIR) range is coupled into the planar structure and the evanescent wave part of the light field penetrating into the silicone layer interacts with the enriched organic species. As a result, light is absorbed at the characteristic frequencies of the corresponding C-H, N-H or O-H overtone and combination band vibrations of the analytes. To perform evanescent field absorbance (EFA) measurements, the arc-shaped strip waveguide structure of 172 mm interaction length was adapted to a tungsten-halogen lamp and an InGaAs diode array spectrograph over gradient index fibers. Dimethyl-co-methly(phenyl)polysiloxanes with varying degrees of phenylation were prepared and used as sensitive coating materials for the IO structure. Light attenuation in the arc-shaped waveguides is high and typical insertion losses in the range of 14-18 dB were obtained. When the coated sensors were brought in contact with aqueous samples, the light transmission decreases, which is due to the formation of H(2)O micro-emulsions in the silicone superstrates. Nevertheless, after reaching constant light transmissions, absorbance spectra of aqueous trichloroethene samples were successfully collected. For gas measurements, where water cross sensitivity problems are absent, the sensitivity of the IO device for trichloroethene was tested as a function of the RI of the silicone superstrate. The slope of the TCE calibration function increases by a factor of 10 by using a poly(methylphenylsiloxane) layer with a RI of 1.449 instead of poly(dimethylsiloxane) (RI: 1.41). A comparison of the IO-EFA and an earlier developed fiber

  17. Vibration analysis on compact car shock absorber

    Science.gov (United States)

    Tan, W. H.; Cheah, J. X.; Lam, C. K.; Lim, E. A.; Chuah, H. G.; Khor, C. Y.

    2017-10-01

    Shock absorber is a part of the suspension system which provides comfort experience while driving. Resonance, a phenomenon where forced frequency is coinciding with the natural frequency has significant effect on the shock absorber itself. Thus, in this study, natural frequencies of the shock absorber in a 2 degree-of-freedom system were investigated using Wolfram Mathematica 11, CATIA, and ANSYS. Both theoretical and simulation study how will the resonance affect the car shock absorber. The parametric study on the performance of shock absorber also had been conducted. It is found that the failure tends to occur on coil sprung of the shock absorber before the body of the shock absorber is fail. From mathematical modelling, it can also be seen that higher vibration level occurred on un-sprung mass compare to spring mass. This is due to the weight of sprung mass which could stabilize as compared with the weight of un-sprung mass. Besides that, two natural frequencies had been obtained which are 1.0 Hz and 9.1 Hz for sprung mass and un-sprung mass respectively where the acceleration is recorded as maximum. In conclusion, ANSYS can be used to validate with theoretical results with complete model in order to match with mathematical modelling.

  18. Compressive light field displays.

    Science.gov (United States)

    Wetzstein, Gordon; Lanman, Douglas; Hirsch, Matthew; Heidrich, Wolfgang; Raskar, Ramesh

    2012-01-01

    Light fields are the multiview extension of stereo image pairs: a collection of images showing a 3D scene from slightly different perspectives. Depicting high-resolution light fields usually requires an excessively large display bandwidth; compressive light field displays are enabled by the codesign of optical elements and computational-processing algorithms. Rather than pursuing a direct "optical" solution (for example, adding one more pixel to support the emission of one additional light ray), compressive displays aim to create flexible optical systems that can synthesize a compressed target light field. In effect, each pixel emits a superposition of light rays. Through compression and tailored optical designs, fewer display pixels are necessary to emit a given light field than a direct optical solution would require.

  19. Calculating light & lighting

    NARCIS (Netherlands)

    Nederhoff, E.M.; Marcelis, L.F.M.

    2010-01-01

    Lighting in a greenhouse is surrounded by questions. How much light to supply and when?. What intensity and light sum to aim for? Is it radiation, light growlight, PAR, photons or quanta? How much is joule, watt, lux?. What does wavelength, nanometer, spectrum, UV, IR and NIR mean?

  20. Optimization of the impact multi-mass vibration absorbers

    Directory of Open Access Journals (Sweden)

    Ivan Kernytskyy

    2017-09-01

    Full Text Available The problem of attaching dynamic vibration absorber (DVA to a discrete multi-degree-of-freedom or continuous structure has been outlined in many papers and monographs. An impact damping system can overcome some limitations by impact as the damping medium and impact mass interaction as the damping mechanism. The paper contemplates the provision of DVA with the several of the impact masses. Such originally designed absorbers reduce vibration selectively in maximum vibration mode without introducing vibration in other modes. An impact damper is a passive control device which takes the form of a freely moving mass, constrained by stops attached to the structure under control, i.e. the primary structure. The damping results from the exchange of momentum during impacts between the mass and the stops as the structure vibrates. The paper contemplates the provision of the impact multi-mass DVA’s with masses collisions for additional damping. For some cases of DVA optimization such a design seems more effective than conventional multi-mass DVA with independent mass moving. A technique is developed to give the optimal DVA’s for the elimination of excessive vibration in harmonic stochastic and impact loaded systems.

  1. Microwave diode switchable metamaterial reflector/absorber

    Science.gov (United States)

    Xu, Wangren; Sonkusale, Sameer

    2013-07-01

    We embed diodes as active circuit elements within a metamaterial to implement a switchable metamaterial reflector/absorber at microwave frequencies. Diodes are placed in series with the unit cells of the metamaterial array. This results in just a pair of control lines to actively tune all the diodes in a metamaterial. Diodes can be tuned on and off to switch the function of the metamaterial between a perfect absorber and a reflector. The design, simulation, and experimental results of a switchable reflector/absorber in 2-6 GHz range are presented.

  2. Absorbed dose by a CMOS in radiotherapy

    Energy Technology Data Exchange (ETDEWEB)

    Borja H, C. G.; Valero L, C. Y.; Guzman G, K. A.; Banuelos F, A.; Hernandez D, V. M.; Vega C, H. R. [Universidad Autonoma de Zacatecas, Unidad Academica de Estudios Nucleares, Calle Cipres No. 10, Fracc. La Penuela, 98068 Zacatecas (Mexico); Paredes G, L. C., E-mail: candy_borja@hotmail.com [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2011-10-15

    Absorbed dose by a complementary metal oxide semiconductor (CMOS) circuit as part of a pacemaker, has been estimated using Monte Carlo calculations. For a cancer patient who is a pacemaker carrier, scattered radiation could damage pacemaker CMOS circuits affecting patient's health. Absorbed dose in CMOS circuit due to scattered photons is too small and therefore is not the cause of failures in pacemakers, but neutron calculations shown an absorbed dose that could cause damage in CMOS due to neutron-hydrogen interactions. (Author)

  3. Conformal metamaterial absorber for curved surface.

    Science.gov (United States)

    Jang, Youngsoo; Yoo, Minyeong; Lim, Sungjoon

    2013-10-07

    In this paper, three different unit cells are designed on the basis split-ring-cross resonators, and each unit cell has an absorption rate greater than 90% at incident angles of 0°, 30°, and 45°, respectively. They are non-periodically placed in three different zones on the curved surface. Therefore, the proposed conformal metamaterial absorber can achieve a high absorption rate. The performance of the proposed absorber is compared with that of a metallic curved surface and a conformal metamaterial absorber with the same unit cells.

  4. Graphene and Graphene Metamaterials for Terahertz Absorbers

    DEFF Research Database (Denmark)

    Andryieuski, Andrei; Pizzocchero, Filippo; Booth, Tim

    2013-01-01

    Graphene, due to the possibility to tune its conductivity, is the promising material for a range of the terahertz (THz) applications, such as tunable reflectors, absorbers, modulators, filters and polarization converters. Subwavelength structuring of graphene in order to form metamaterials allows...... for even more control over the THz waves. In this poster presentation I will show an elegant way to describe the graphene metamaterials and the design of graphene based absorbers. I will also present our recent experimental results on the graphene absorbers characterization....

  5. Understanding the trade-offs of thinner binary mask absorbers

    Science.gov (United States)

    Tirapu-Azpiroz, Jaione; McIntyre, Gregory; Faure, Tom; Halle, Scott; Hibbs, Michael; Wagner, Alfred; Lai, Kafai; Gallagher, Emily; Brunner, Timothy

    2010-09-01

    Mask topography is only one of the challenges for extending 193nm immersion lithography to 22nm and beyond. Migration to binary but thinner mask absorbers, from the previously employed attenuated phase-shift mask (attnPSM) technology, traded a tolerable loss in contrast for better mask making performance and reduced electromagnetic field (EMF) impact [1]. The relentless technological advances in 193nm lithography required to enable 22nm technology, however, continue to drive the dimensions of mask features deep into sub-wavelength scale. In this regime, residual mask EMF effects can still degrade the imaging performance of critical mask patterns, often in the form of featuredependent biasing and shifts of the plane of best focus that shrink the common process window and magnify the impact of mask errors. In this paper we investigate the potential benefits in EMF effects mitigation provided by further thinning the mask absorber to the minimum possible while retaining the required opacity. This study was motivated by the narrower process variability bands observed on a 22nm structure with high EMF sensitivity, when computed with rigorous EMF simulations using a thinner absorber. Resist measurements on wafers exposed with the same EMF sensitive structure built on either the standard binary mask or the thinner sample, confirmed the lower sensitivity to mask topography of the latter while also providing a significant process window improvement. We further observed that thinner topography allowed for a smaller topography induced bias, resulting in improved mask manufacturability with less risk for mask corrections to be limited by mask manufacturability rules such as small assist features and small corner to corner gaps. Thinning the absorber, however, is typically accompanied by an increase in reflectivity of the mask blank which may influence the nature of stray light in the imaging system. To understand the consequences of increasing the blank reflectivity, a double

  6. Ultra-wideband microwave absorber by connecting multiple absorption bands of two different-sized hyperbolic metamaterial waveguide arrays

    Science.gov (United States)

    Yin, Xiang; Long, Chang; Li, Junhao; Zhu, Hua; Chen, Lin; Guan, Jianguo; Li, Xun

    2015-10-01

    Microwave absorbers have important applications in various areas including stealth, camouflage, and antenna. Here, we have designed an ultra-broadband light absorber by integrating two different-sized tapered hyperbolic metamaterial (HMM) waveguides, each of which has wide but different absorption bands due to broadband slow-light response, into a unit cell. Both the numerical and experimental results demonstrate that in such a design strategy, the low absorption bands between high absorption bands with a single-sized tapered HMM waveguide array can be effectively eliminated, resulting in a largely expanded absorption bandwidth ranging from 2.3 to 40 GHz. The presented ultra-broadband light absorber is also insensitive to polarization and robust against incident angle. Our results offer a further step in developing practical artificial electromagnetic absorbers, which will impact a broad range of applications at microwave frequencies.

  7. Ultra-wideband microwave absorber by connecting multiple absorption bands of two different-sized hyperbolic metamaterial waveguide arrays.

    Science.gov (United States)

    Yin, Xiang; Long, Chang; Li, Junhao; Zhu, Hua; Chen, Lin; Guan, Jianguo; Li, Xun

    2015-10-19

    Microwave absorbers have important applications in various areas including stealth, camouflage, and antenna. Here, we have designed an ultra-broadband light absorber by integrating two different-sized tapered hyperbolic metamaterial (HMM) waveguides, each of which has wide but different absorption bands due to broadband slow-light response, into a unit cell. Both the numerical and experimental results demonstrate that in such a design strategy, the low absorption bands between high absorption bands with a single-sized tapered HMM waveguide array can be effectively eliminated, resulting in a largely expanded absorption bandwidth ranging from 2.3 to 40 GHz. The presented ultra-broadband light absorber is also insensitive to polarization and robust against incident angle. Our results offer a further step in developing practical artificial electromagnetic absorbers, which will impact a broad range of applications at microwave frequencies.

  8. Freshwater DOM quantity and quality from a two-component model of UV absorbance

    Science.gov (United States)

    Carter, Heather T.; Tipping, Edward; Koprivnjak, Jean-Francois; Miller, Matthew P.; Cookson, Brenda; Hamilton-Taylor, John

    2012-01-01

    We present a model that considers UV-absorbing dissolved organic matter (DOM) to consist of two components (A and B), each with a distinct and constant spectrum. Component A absorbs UV light strongly, and is therefore presumed to possess aromatic chromophores and hydrophobic character, whereas B absorbs weakly and can be assumed hydrophilic. We parameterised the model with dissolved organic carbon concentrations [DOC] and corresponding UV spectra for c. 1700 filtered surface water samples from North America and the United Kingdom, by optimising extinction coefficients for A and B, together with a small constant concentration of non-absorbing DOM (0.80 mg DOC L-1). Good unbiased predictions of [DOC] from absorbance data at 270 and 350 nm were obtained (r2 = 0.98), the sum of squared residuals in [DOC] being reduced by 66% compared to a regression model fitted to absorbance at 270 nm alone. The parameterised model can use measured optical absorbance values at any pair of suitable wavelengths to calculate both [DOC] and the relative amounts of A and B in a water sample, i.e. measures of quantity and quality. Blind prediction of [DOC] was satisfactory for 9 of 11 independent data sets (181 of 213 individual samples).

  9. Slow-light enhancement of Beer-Lambert-Bouguer absorption

    DEFF Research Database (Denmark)

    Mortensen, Asger; Xiao, Sanshui

    2007-01-01

    We theoretically show how slow light in an optofluidic environment facilitates enhanced light-matter interactions, by orders of magnitude. The proposed concept provides strong opportunities for improving existing miniaturized chemical absorbance cells for Beer-Lambert-Bouguer absorption measureme......We theoretically show how slow light in an optofluidic environment facilitates enhanced light-matter interactions, by orders of magnitude. The proposed concept provides strong opportunities for improving existing miniaturized chemical absorbance cells for Beer-Lambert-Bouguer absorption...

  10. Slow Light at High Frequencies in an Amplifying Semiconductor Waveguide

    DEFF Research Database (Denmark)

    Öhman, Filip; Yvind, Kresten; Mørk, Jesper

    2006-01-01

    We demonstrate slow-down of a modulated light signal in a semiconductor waveguide. Concatenated amplifying and absorbing sections simultaneously achieve both amplification and a controllable time delay at 15 GHz.......We demonstrate slow-down of a modulated light signal in a semiconductor waveguide. Concatenated amplifying and absorbing sections simultaneously achieve both amplification and a controllable time delay at 15 GHz....

  11. Metrology with nonclassical light

    Science.gov (United States)

    Schubert, Max

    1990-07-01

    In 1963 Glauber /Phys. Rev. 130, 2529 and 131, 2766/ published a basic theoretical study that revealed the broad variety of possible photon states. Later on a quantum-statistical analysis showed that states with classical analog (this light Is termed classical light) as well as states without classical analog (so-called nonclassical light) can occur. Following the definition given by Teich, Saleh, and Perina /JOSAB2 (1985) 275) nonclassical light exhibits one or more of the attributes squeezed, antibunched, sub-Poissonian, what is connected with a negative value of the field-fluctuation excess, the bunching excess, or the Poisson excess. These negative values mean quantum fluctuations below the classical standard quantum limits of ideal laser light; thus, nonclassical light may yield an essential improvement of the optical measurement accuracy, in particular of the signal-to-noise ratio. There exists a common property of the three attributes concerning the Glauber-Sudarshan representation P(c ), which is the real weight function belonging to the incoherent mixture (density operators) of Glauber states with different complex amplitudes. In the case of classical light P(o‡ ) is a positive definite function, whereas nonclassical light requires a nonpositive definite function P(o.), which cannot be interpreted as a proper probability distribution - as it is possible in the case of light with a classical analog /M. Schubert, Ann. d. Phys. 4k (1987) 53/. In addition to its possible important applications nonclassical light yields a deep insight into the quantum nature of the radiation field.

  12. An ultra-broadband multilayered graphene absorber

    KAUST Repository

    Amin, Muhammad

    2013-01-01

    An ultra-broadband multilayered graphene absorber operating at terahertz (THz) frequencies is proposed. The absorber design makes use of three mechanisms: (i) The graphene layers are asymmetrically patterned to support higher order surface plasmon modes that destructively interfere with the dipolar mode and generate electromagnetically induced absorption. (ii) The patterned graphene layers biased at different gate voltages backedup with dielectric substrates are stacked on top of each other. The resulting absorber is polarization dependent but has an ultra-broadband of operation. (iii) Graphene\\'s damping factor is increased by lowering its electron mobility to 1000cm 2=Vs. Indeed, numerical experiments demonstrate that with only three layers, bandwidth of 90% absorption can be extended upto 7THz, which is drastically larger than only few THz of bandwidth that can be achieved with existing metallic/graphene absorbers. © 2013 Optical Society of America.

  13. Research on a multiband metamaterial absorber

    Science.gov (United States)

    Yu, Xiebin; Song, Yaoliang; Fan, Shicheng

    2017-10-01

    This paper describes the design of a multiband metamaterial absorber based on double-gap sheet metal and takes it into simulation by CST microwave studio. The results of simulation show that the metamaterial absorber achieves absorption rate up to 99.6%, 99.8%, 99.9% and 93.5% at 4.64 GHz, 8.67 GHz, 13.93 GHz and 18.53 GHz respectively. The thickness of the metamaterial absorber is just 3.3%, 6.3%, 10.0% and 13.3% of its working wavelength respectively. Finally, the absorption mechanism is analyzed by using the surface current,surface charge and the impedance matching theory. This metamaterial absorber has potential application in multifrequency radar, electromagnetic compatibility of complex electronic platform and so on.

  14. Space Compatible Radar Absorbing Materials Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR Phase 1 project shall investigate novel radar absorbing materials (RAM) for use in space or simulated space environments. These materials are lightweight...

  15. Optically Modulated Multiband Terahertz Perfect Absorber

    DEFF Research Database (Denmark)

    Seren, Huseyin R.; Keiser, George R.; Cao, Lingyue

    2014-01-01

    response of resonant metamaterials continues to be a challengingendeavor. Resonant perfect absorbers have flourished as one of the mostpromising metamaterial devices with applications ranging from power har-vesting to terahertz imaging. Here, an optically modulated resonant perfectabsorber is presented...

  16. Actual behaviour of a ball vibration absorber

    Czech Academy of Sciences Publication Activity Database

    Pirner, Miroš

    2002-01-01

    Roč. 90, č. 8 (2002), s. 987-1005 ISSN 0167-6105 R&D Projects: GA ČR(CZ) GV103/96/K034 Institutional support: RVO:68378297 Keywords : TV towers * wind-excited vibrations * vibration absorbers * pendulum absorber Subject RIV: JM - Building Engineering Impact factor: 0.513, year: 2002 http://www.sciencedirect.com/science/article/pii/S0167610502002155#

  17. Multilayer Radar Absorbing Non-Woven Material

    Science.gov (United States)

    Dedov, A. V.; Nazarov, V. G.

    2016-06-01

    We study the electrical properties of multilayer radar absorbing materials obtained by adding nonwoven sheets of dielectric fibers with an intermediate layer of electrically conductive carbon fibers. Multilayer materials that absorb electromagnetic radiation in a wide frequency range are obtained by varying the content of the carbon fibers. The carbon-fiber content dependent mechanism of absorption of electromagnetic radiation by sheets and multilayer materials is considered.

  18. Energy-Absorbing Passenger Seat for Aircraft

    Science.gov (United States)

    Eichelberger, C. P.; Alfaro-Bou, E.; Fasanella, E. L.

    1987-01-01

    Development of energy-absorbing passenger seat, designed to minimize injury in commercial-aircraft crash, part of joint FAA/NASA controlledimpact flight test of transport-category commercial aircraft. Modified seat mechanism collapses under heavy load to absorb impact energy and thereby protect passenger. Results of simulation tests indicate probability of passenger survival high. Proposed seat mechanism mitigates passenger injuries by reducing impact forces in crash.

  19. Porous absorber for solar air heaters

    Energy Technology Data Exchange (ETDEWEB)

    Finch, J.A.

    1980-09-10

    A general discussion of the factors affecting solar collector performance is presented. Bench scale tests done to try to determine the heat transfer characteristics of various screen materials are explained. The design, performance, and evaluation of a crude collector with a simple screen stack absorber is treated. The more sophisticated absorber concept, and its first experimental approximation is examined. A short summary of future plans for the collector concept is included. (MHR)

  20. The design of broadband radar absorbing surfaces

    OpenAIRE

    Go, Han Suk

    1990-01-01

    Approved for public release, distribution unlimited There has been a growing and widespread interest in radar-absorbing material technology. As the name implies, radar absorbing materials or RAM's are coatings whose electric and magnetic properties have been selected to allow the absorption of microwave energy at discrete or broadband frequencies. In military applications low radar cross section (RCS) of a vehicle may be required in order to escape detection while a covert mission is being...

  1. Semiconductor saturable absorbers for ultrafast terahertz signals

    OpenAIRE

    Hoffmann, Matthias C.; Turchinovich, Dmitry

    2010-01-01

    We demonstrate saturable absorber behavior of n-type semiconductors GaAs, GaP, and Ge in the terahertz THz frequency range at room temperature using nonlinear THz spectroscopy. The saturation mechanism is based on a decrease in electron conductivity of semiconductors at high electron momentum states, due to conduction band onparabolicity and scattering into satellite valleys in strong THz fields. Saturable absorber parameters, such as linear and nonsaturable transmission, and saturation fluen...

  2. Semiconductor saturable absorbers for ultrafast THz signals

    DEFF Research Database (Denmark)

    Hoffmann, Matthias C.; Turchinovich, Dmitry

    We demonstrate saturable absorber behavior of n-type semiconductors in the THz frequency range using nonlinear THz spectroscopy. Further, we observe THz pulse shortening and increase of the group refractive index at high field strengths.......We demonstrate saturable absorber behavior of n-type semiconductors in the THz frequency range using nonlinear THz spectroscopy. Further, we observe THz pulse shortening and increase of the group refractive index at high field strengths....

  3. Semiconductor saturable absorbers for ultrafast terahertz signals

    OpenAIRE

    Hoffmann, Matthias C.; Turchinovich, Dmitry

    2010-01-01

    We demonstrate saturable absorber behavior of n-type semiconductorsGaAs,GaP, and Ge in the terahertz (THz) frequency range at room temperature using nonlinear THz spectroscopy. The saturation mechanism is based on a decrease in electron conductivity of semiconductors at high electron momentum states, due to conduction band nonparabolicity and scattering into satellite valleys in strong THz fields. Saturable absorber parameters, such as linear and nonsaturable transmission, and saturation flue...

  4. Novel solar absorber surfaces with organic pigments

    OpenAIRE

    Nunes, Clarisse; Brites, Maria João; Mendes, J. Farinha; Prates, Manuel João Lopes; Alexandre, J.; Ferreira, M.; Martins, A. J.; Teixeira, V.; V. Carneiro; M. J. Carvalho

    2008-01-01

    This paper presents results of application of natural and synthetic organic pigments in selective solar absorber coatings. Some of these photo excite pigments were tested like solar radiation absorber pigments in paint coatings and others as a form to increase the absorption of solar radiation in titanium oxide monolayer selective coatings produced by reactive magnetron sputtering. Morphologic aspects and optical properties are discussed as a function of deposition parameters and of formulati...

  5. A dual band terahertz metamaterial absorber

    Energy Technology Data Exchange (ETDEWEB)

    Tao Hu; Fan Kebin; Zhang Xin [Department of Mechanical Engineering, Boston University, Boston, MA 02215 (United States); Bingham, C M; Shrekenhamer, D; Padilla, W J [Department of Physics, Boston College, Chestnut Hill, MA 02467 (United States); Pilon, D; Strikwerda, A C; Averitt, R D, E-mail: xinz@bu.ed, E-mail: raveritt@physics.bu.ed [Department of Physics, Boston University, Boston, MA 02215 (United States)

    2010-06-09

    We present the design, fabrication and characterization of a dual band metamaterial absorber which experimentally shows two distinct absorption peaks of 0.85 at 1.4 THz and 0.94 at 3.0 THz. The dual band absorber consists of a dual band electric-field-coupled (ELC) resonator and a metallic ground plane, separated by an 8 {mu}m dielectric spacer. Fine tuning of the two absorption resonances is achieved by individually adjusting each ELC resonator geometry.

  6. On the physical limit of radar absorbers

    OpenAIRE

    Karlsson, Anders; Kazemzadeh, Alireza

    2010-01-01

    A previous investigation has shown that at normal angle of incidence, the integral of the reflectance over wavelength is bounded for a flat metal backed absorber. The bound is applicable to any absorber made of linear, time-invariant, causal and passive materials. We generalize the physical bound to arbitrary angle of incidence and polarization. Different design examples and numerical calculations are provided to investigate the inequalities. It is shown that the theoretical limit for TE pola...

  7. A Wedge Absorber Experiment at MICE

    Energy Technology Data Exchange (ETDEWEB)

    Neuffer, David [Fermilab; Mohayai, Tanaz [IIT, Chicago; Rogers, Chris [Rutherford; Snopok, Pavel [IIT, Chicago; Summers, Don [Mississippi U.

    2017-05-01

    Emittance exchange mediated by wedge absorbers is required for longitudinal ionization cooling and for final transverse emittance minimization for a muon collider. A wedge absorber within the MICE beam line could serve as a demonstration of the type of emittance exchange needed for 6-D cooling, including the configurations needed for muon colliders, as well as configurations for low-energy muon sources. Parameters for this test are explored in simulation and possible experimental configurations with simulated results are presented.

  8. Mixed stops and the ATLAS on-Z excess

    Science.gov (United States)

    Collins, Jack H.; Dror, Jeff Asaf; Farina, Marco

    2015-11-01

    The ATLAS experiment has recently observed a 3 σ excess in a channel with a leptonically decaying Z , jets, and ETmiss . It is tantalizing to interpret the signal as the first sign of a natural supersymmetric spectrum. We study such a possibility in a minimal model containing light stops and a neutralino lightest supersymmetric particle. The signal is characterized by a novel topology (compared to previous attempts) where the Z is emitted from a colored particle in the first step of a decay chain, namely t˜2→t˜1Z , which is characteristic of mixed stops. We show that the excess is compatible with a compressed stop spectrum and is not excluded by any other relevant search, finding some regions of parameter space with signal strength within 1 σ of that measured by the ATLAS Collaboration. In addition, we notice that the corresponding CMS search could be prone to background contamination in unexpected topologies of this kind.

  9. Perfect terahertz absorber using fishnet based metafilm

    Energy Technology Data Exchange (ETDEWEB)

    Azad, Abul Kalam [Los Alamos National Laboratory; Shchegolkov, Dmitry Yu [Los Alamos National Laboratory; Chen, Houtong [Los Alamos National Laboratory; Taylor, Antoinette [Los Alamos National Laboratory; Smirnova, E I [Los Alamos National Laboratory; O' Hara, John F [Los Alamos National Laboratory

    2009-01-01

    We present a perfect terahertz (THz) absorber working for a broad-angle of incidence. The two fold symmetry of rectangular fishnet structure allows either complete absorption or mirror like reflection depending on the polarization of incident the THz beam. Metamaterials enable the ability to control the electromagnetic wave in a unique fashion by designing the permittivity or permeability of composite materials with desired values. Although the initial idea of metamaterials was to obtain a negative index medium, however, the evolution of metamaterials (MMs) offers a variety of practically applicable devices for controlling electromagnetic wave such as tunable filters, modulators, phase shifters, compact antenna, absorbers, etc. Terahertz regime, a crucial domain of the electromagnetic wave, is suffering from the scarcity of the efficient devices and might take the advantage of metamaterials. Here, we demonstrate design, fabrication, and characterization of a terahertz absorber based on a simple fishnet metallic film separated from a ground mirror plane by a dielectric spacer. Such absorbers are in particular important for bolometric terahertz detectors, high sensitivity imaging, and terahertz anechoic chambers. Recently, split-ring-resonators (SRR) have been employed for metamaterial-based absorbers at microwave and THz frequencies. The experimental demonstration reveals that such absorbers have absorptivity close to unity at resonance frequencies. However, the downside of these designs is that they all employ resonators of rather complicated shape with many fine parts and so they are not easy to fabricate and are sensitive to distortions.

  10. Multi-band terahertz metasurface absorber

    Science.gov (United States)

    Wang, Xuying; Wang, Qingmin; Dong, Guoyan; Hao, Yanan; Lei, Ming; Bi, Ke

    2017-12-01

    A terahertz metasurface perfect absorber with multi-band performance is demonstrated. The absorber is composed of a ground plane and four split-ring resonators (SRRs) with different dimensions, separated by a dielectric spacer. The numerical simulation results illustrate that the proposed absorber has four distinct absorption peaks at resonance frequencies of 4.24, 5.66, 7.22, and 8.97 THz, with absorption rates of 96.8%, 99.3%, 97.3%, and 99.9%, respectively. Moreover, the corresponding full width at half-maximum (FWHM) values are about 0.27, 0.35, 0.32, and 0.42 THz, respectively, which are much broader than those of previously reported absorbers. Besides, the calculated magnetic field distributions allow us to understand the absorption mechanism in detail. The effects of incident angle and azimuthal angle on the absorber are also investigated. The results show that the proposed absorber is partially sensitive to the incident angle, which makes this design promising for practical applications in terahertz imagers and detectors.

  11. Radar Absorbing Materials for Cube Stealth Satellite

    Science.gov (United States)

    Micheli, D.; Pastore, R.; Vricella, A.; Marchetti, M.

    A Cube Stealth Satellite is proposed for potential applications in defense system. Particularly, the faces of the satellite exposed to the Earth are made of nanostructured materials able to absorb radar surveillance electromagnetic waves, conferring stealth capability to the cube satellite. Microwave absorbing and shielding material tiles are proposed using composite materials consisting in epoxy-resin and carbon nanotubes filler. The electric permittivity of the composite nanostructured materials is measured and discussed. Such data are used by the modeling algorithm to design the microwave absorbing and the shielding faces of the cube satellite. The electromagnetic modeling takes into account for several incidence angles (0-80°), extended frequency band (2-18 GHz), and for the minimization of the electromagnetic reflection coefficient. The evolutionary algorithm used for microwave layered microwave absorber modeling is the recently developed Winning Particle Optimization. The mathematical model of the absorbing structure is finally experimentally validated by comparing the electromagnetic simulation to the measurement of the manufactured radar absorber tile. Nanostructured composite materials manufacturing process and electromagnetic reflection measurements methods are described. Finally, a finite element method analysis of the electromagnetic scattering by cube stealth satellite is performed.

  12. Excessive libido in a woman with rabies.

    OpenAIRE

    Dutta, J. K.

    1996-01-01

    Rabies is endemic in India in both wildlife and humans. Human rabies kills 25,000 to 30,000 persons every year. Several types of sexual manifestations including excessive libido may develop in cases of human rabies. A laboratory proven case of rabies in an Indian woman who manifested excessive libido is presented below. She later developed hydrophobia and died.

  13. Understand Your Risk for Excessive Blood Clotting

    Science.gov (United States)

    ... Vascular Health Peripheral Artery Disease Venous Thromboembolism Aortic Aneurysm More Understand Your Risk for Excessive Blood Clotting Updated:Nov 2,2015 Many factors can lead to excessive blood clotting, leading to limited or blocked blood flow. Blood clots can travel to the arteries or ...

  14. Bladder calculus presenting as excessive masturbation.

    Science.gov (United States)

    De Alwis, A C D; Senaratne, A M R D; De Silva, S M P D; Rodrigo, V S D

    2006-09-01

    Masturbation in childhood is a normal behaviour which most commonly begins at 2 months of age, and peaks at 4 years and in adolescence. However excessive masturbation causes anxiety in parents. We describe a boy with a bladder calculus presenting as excessive masturbation.

  15. 30 CFR 57.6902 - Excessive temperatures.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Excessive temperatures. 57.6902 Section 57.6902... Requirements-Surface and Underground § 57.6902 Excessive temperatures. (a) Where heat could cause premature... shall— (1) Measure an appropriate number of blasthole temperatures in order to assess the specific mine...

  16. 30 CFR 56.6902 - Excessive temperatures.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Excessive temperatures. 56.6902 Section 56.6902... Requirements § 56.6902 Excessive temperatures. (a) Where heat could cause premature detonation, explosive... an appropriate number of blasthole temperatures in order to assess the specific mine conditions prior...

  17. Excess Based Allocation of Risk Capital

    NARCIS (Netherlands)

    van Gulick, G.; De Waegenaere, A.M.B.; Norde, H.W.

    2010-01-01

    In this paper we propose a new rule to allocate risk capital to portfolios or divisions within a firm. Specifically, we determine the capital allocation that minimizes the excesses of sets of portfolios in lexicographical sense. The excess of a set of portfolios is defined as the expected loss of

  18. The excessively crying infant : etiology and treatment

    NARCIS (Netherlands)

    Akhnikh, S.; Engelberts, A.C.; Sleuwen, B.E. van; Hoir, M.P. L’; Benninga, M.A.

    2014-01-01

    Excessive crying, often described as infantile colic, is the cause of 10% to 20% of all early pediatrician visits of infants aged 2 weeks to 3 months. Although usually benign and selflimiting, excessive crying is associated with parental exhaustion and stress. However, and underlying organic cause

  19. Triboson interpretations of the ATLAS diboson excess

    CERN Document Server

    Aguilar-Saavedra, J.A.

    2015-01-01

    The ATLAS excess in fat jet pair production is kinematically compatible with the decay of a heavy resonance into two gauge bosons plus an extra particle. This possibility would explain the absence of such a localised excess in the analogous CMS analysis of fat dijet final states, as well as the negative results of diboson resonance searches in the semi-leptonic decay modes.

  20. COP1/SPA ubiquitin ligase complexes repress anthocyanin accumulation under low light and high light conditions.

    Science.gov (United States)

    Maier, Alexander; Hoecker, Ute

    2015-01-01

    In Arabidopsis and many other plant species, anthocyanin pigments accumulate only after light exposure and not in darkness. Excess light of very high fluence rates leads to a further, very strong increase in anthocyanin levels. How excess light is sensed is not well understood. Here, we show that mutations in the key repressor of light signaling, the COP1/SPA complex, cause a strong hyperaccumulation of anthocyanins not only under normal light but also under excess, high light conditions. Hence, normal light signaling via COP1/SPA is required to prevent hyperaccumulation of anthocyanins under these high light conditions. However, since cop1 and spa mutants show a similar high-light responsiveness of anthocyanin accumulation as the wild type it remains to be resolved whether COP1/SPA is directly involved in the high-light response itself.

  1. Effectiveness of Nivea Sunscreen under Ultraviolet Light

    Directory of Open Access Journals (Sweden)

    Piset Virachunya

    2008-01-01

    Full Text Available The relationship between a sunscreen’s SPF and its absorbance for UV light of wavelength 240 to 320 was investigated. The investigation was conducted by diluting sunscreens with SPF's of 20, 30 and 50 and placing the solution in a spectrophotometer where the absorbance was measured under UVA, UVB and UVC light. It was shown that the sunscreen was effective over the whole range of wavelengths, with increased effectiveness at wavelengths 240 and 300. The results also show that as the SPF increased, the absorbance increased proportionally.

  2. Effectiveness of Nivea Sunscreen under Ultraviolet Light

    Directory of Open Access Journals (Sweden)

    Piset Virachunya

    2008-01-01

    Full Text Available The relationship between a sunscreen’s SPF and its absorbance for UV light of wavelength 240 to 320 was investigated. The investigation was conducted by diluting sunscreens with SPFs of 20, 30 and 50 and placing the solution in a spectrophotometer where the absorbance was measured under UVA, UVB and UVC light. It was shown that the sunscreen was effective over the whole range of wavelengths, with increased effectiveness at wavelengths 240 and 300. The results also show that as the SPF increased, the absorbance increased proportionally.

  3. SCL-90-R and 16PF profiles of senior high school students with excessive internet use.

    Science.gov (United States)

    Yang, Chang-Kook; Choe, Byeong-Moo; Baity, Matthew; Lee, Jeong-Hyeong; Cho, Jin-Seok

    2005-06-01

    To investigate the psychiatric symptomatology and personality characteristics of Korean senior high school students considered to use the Internet to excess. We administered a questionnaire packet to students that included 4 measures. These measures included a questionnaire on Internet use patterns during the previous month, the Internet Addiction Test (IAT), the Symptom Checklist-90-R (SCL-90-R), and the Sixteen Personality Factor Questionnaire (16PF). A total of 328 students, aged 15 to 19 years, participated in the study. Students were divided into 4 Internet user groups according to their IAT total scores: nonusers (n = 59, 18.0%), minimal users (n = 155, 47.3%), moderate users (n = 98, 29.9%), and excessive users (n = 16, 4.9%). The SCL-90-R showed that the excessive users group, when compared with the other groups in this study, reported the highest levels of symptomatology. The 16PF also revealed that excessive users were easily affected by feeling, emotionally less stable, imaginative, absorbed in thought, self-sufficient, experimenting, and preferred their own decisions. This study suggests that senior high school students who use the Internet to excess report and subsequently exhibit significantly more psychiatric symptoms than students who use the Internet less frequently. In addition, excessive users appear to have a distinctive personality profile when compared with nonusers, minimal, and moderate users.

  4. Wide-angle infrared metamaterial absorber with near-unity absorbance

    Science.gov (United States)

    Guo, Linyang; Ma, Xiaohui; Zou, Yonggang; Zhang, Ran; Wang, Jia'an; Zhang, Da

    2018-01-01

    A wide-angle infrared perfect metamaterial absorber is experimentally verified. The perfect metamaterial absorber shows polarization-independent at normal incidence and displays high absorption rate at a large angle of incidence. The absorption property of the proposed metamaterial absorber is sensitive to the change of refractive index of environmental mediums. An absorption sensor scheme is proposed by combining the concept of the perfect metamaterial absorber and the variation of the refractive index of the environmental medium. Measured results indicate that the proposed absorption sensor scheme achieves high FOM values with different surrounding mediums (air, water, and glucose solution).

  5. Synthesis and properties of polyamide–Ag2S composite based solar energy absorber surfaces

    NARCIS (Netherlands)

    Krylovaa, Valentina; Baltrusaitis, Jonas

    2013-01-01

    Silver sulfide (Ag2S), an efficient solar light absorber, was synthesized using a modified chemical bath deposition (CBD) method and polyamide 6 (PA) as a host material via solution phase reaction between AgNO3 and Na2S2O3. X-ray diffraction (XRD) data showed a single, α-Ag2S (acanthite),

  6. Principles of light energy management

    Science.gov (United States)

    Davis, N.

    1994-01-01

    Six methods used to minimize excess energy effects associated with lighting systems for plant growth chambers are reviewed in this report. The energy associated with wall transmission and chamber operating equipment and the experimental requirements, such as fresh air and internal equipment, are not considered here. Only the energy associated with providing and removing the energy for lighting is considered.

  7. 26 CFR 54.4979-1 - Excise tax on certain excess contributions and excess aggregate contributions.

    Science.gov (United States)

    2010-04-01

    ... 26 Internal Revenue 17 2010-04-01 2010-04-01 false Excise tax on certain excess contributions and excess aggregate contributions. 54.4979-1 Section 54.4979-1 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) MISCELLANEOUS EXCISE TAXES (CONTINUED) PENSION EXCISE TAXES § 54.4979-1 Excise tax on certain excess...

  8. Innovative energy absorbing devices based on composite tubes

    Science.gov (United States)

    Tiwari, Chandrashekhar

    Analytical and experimental study of innovative load limiting and energy absorbing devices are presented here. The devices are based on composite tubes and can be categorized in to two groups based upon the energy absorbing mechanisms exhibited by them, namely: foam crushing and foam fracturing. The device based on foam crushing as the energy absorbing mechanism is composed of light weight elastic-plastic foam filling inside an angle ply composite tube. The tube is tailored to have a high Poisson’s ratio (>20). Upon being loaded the device experiences large transverse contraction resulting in rapid decrease in diameter. At a certain axial load the foam core begins to crush and energy is dissipated. This device is termed as crush tube device. The device based upon foam shear fracture as the energy absorbing mechanism involves an elastic-plastic core foam in annulus of two concentric extension-twist coupled composite tubes with opposite angles of fibers. The core foam is bonded to the inner and outer tube walls. Upon being loaded axially, the tubes twist in opposite directions and fracture the core foam in out of plane shear and thus dissipate the energy stored. The device is termed as sandwich core device (SCD). The devices exhibit variations in force-displacement characteristics with changes in design and material parameters, resulting in wide range of energy absorption capabilities. A flexible matrix composite system was selected, which was composed of high stiffness carbon fibers as reinforcements in relatively low stiffness polyurethane matrix, based upon large strain to failure capabilities and large beneficial elastic couplings. Linear and non-linear analytical models were developed encapsulating large deformation theory of the laminated composite shells (using non-linear strain energy formulation) to the fracture mechanics of core foam and elastic-plastic deformation theory of the foam filling. The non-linear model is capable of including material and

  9. COMPARISON OF ABSORBABLE EXTRA LONG TERM POLY HYDROXY BUTYRATE SUTURE VS NON ABSORBABLE (POLYPROPYLENE) SUTURE FOR ABDOMINAL WALL CLOSURE

    National Research Council Canada - National Science Library

    Mallikarjun; Vinay Sagar; Kiran

    2015-01-01

    ... . patients are divided into group I includes 102 patients with continuous technique using non absorbable polypropylene, group II includes 91 patients with interrupted technique using non absorbable...

  10. An extremely wideband and lightweight metamaterial absorber.

    Science.gov (United States)

    Shen, Yang; Pei, Zhibin; Pang, Yongqiang; Wang, Jiafu; Zhang, Anxue; Qu, Shaobo

    2015-06-14

    This paper presents a three-dimensional microwave metamaterial absorber based on the stand-up resistive film patch array. The absorber has wideband absorption, lightweight, and polarization-independent properties. Our design comes from the array of unidirectional stand-up resistive film patches backed by a metallic plane, which can excite multiple standing wave modes. By rolling the resistive film patches as a square enclosure, we obtain the polarization-independent property. Due to the multiple standing wave modes, the most incident energy is dissipated by the resistive film patches, and thus, the ultra-wideband absorption can be achieved by overlapping all the absorption modes at different frequencies. Both the simulated and experimental results show that the absorber possesses a fractional bandwidth of 148.2% with the absorption above 90% in the frequency range from 3.9 to 26.2 GHz. Moreover, the proposed absorber is extremely lightweight. The areal density of the fabricated sample is about 0.062 g/cm 2 , which is approximately equivalent to that of eight stacked standard A4 office papers. It is expected that our proposed absorber may find potential applications such as electromagnetic interference and stealth technologies.

  11. An extremely wideband and lightweight metamaterial absorber

    Science.gov (United States)

    Shen, Yang; Pei, Zhibin; Pang, Yongqiang; Wang, Jiafu; Zhang, Anxue; Qu, Shaobo

    2015-06-01

    This paper presents a three-dimensional microwave metamaterial absorber based on the stand-up resistive film patch array. The absorber has wideband absorption, lightweight, and polarization-independent properties. Our design comes from the array of unidirectional stand-up resistive film patches backed by a metallic plane, which can excite multiple standing wave modes. By rolling the resistive film patches as a square enclosure, we obtain the polarization-independent property. Due to the multiple standing wave modes, the most incident energy is dissipated by the resistive film patches, and thus, the ultra-wideband absorption can be achieved by overlapping all the absorption modes at different frequencies. Both the simulated and experimental results show that the absorber possesses a fractional bandwidth of 148.2% with the absorption above 90% in the frequency range from 3.9 to 26.2 GHz. Moreover, the proposed absorber is extremely lightweight. The areal density of the fabricated sample is about 0.062 g/cm2, which is approximately equivalent to that of eight stacked standard A4 office papers. It is expected that our proposed absorber may find potential applications such as electromagnetic interference and stealth technologies.

  12. Identifying the perfect absorption of metamaterial absorbers

    Science.gov (United States)

    Duan, G.; Schalch, J.; Zhao, X.; Zhang, J.; Averitt, R. D.; Zhang, X.

    2018-01-01

    We present a detailed analysis of the conditions that result in unity absorption in metamaterial absorbers to guide the design and optimization of this important class of functional electromagnetic composites. Multilayer absorbers consisting of a metamaterial layer, dielectric spacer, and ground plane are specifically considered. Using interference theory, the dielectric spacer thickness and resonant frequency for unity absorption can be numerically determined from the functional dependence of the relative phase shift of the total reflection. Further, using transmission line theory in combination with interference theory we obtain analytical expressions for the unity absorption resonance frequency and corresponding spacer layer thickness in terms of the bare resonant frequency of the metamaterial layer and metallic and dielectric losses within the absorber structure. These simple expressions reveal a redshift of the unity absorption frequency with increasing loss that, in turn, necessitates an increase in the thickness of the dielectric spacer. The results of our analysis are experimentally confirmed by performing reflection-based terahertz time-domain spectroscopy on fabricated absorber structures covering a range of dielectric spacer thicknesses with careful control of the loss accomplished through water absorption in a semiporous polyimide dielectric spacer. Our findings can be widely applied to guide the design and optimization of the metamaterial absorbers and sensors.

  13. Oxygen absorbers in food preservation: a review.

    Science.gov (United States)

    Cichello, Simon Angelo

    2015-04-01

    The preservation of packaged food against oxidative degradation is essential to establish and improve food shelf life, customer acceptability, and increase food security. Oxygen absorbers have an important role in the removal of dissolved oxygen, preserving the colour, texture and aroma of different food products, and importantly inhibition of food spoilage microbes. Active packaging technology in food preservation has improved over decades mostly due to the sealing of foods in oxygen impermeable package material and the quality of oxygen absorber. Ferrous iron oxides are the most reliable and commonly used oxygen absorbers within the food industry. Oxygen absorbers have been transformed from sachets of dried iron-powder to simple self-adhesive patches to accommodate any custom size, capacity and application. Oxygen concentration can be effectively lowered to 100 ppm, with applications spanning a wide range of food products and beverages across the world (i.e. bread, meat, fish, fruit, and cheese). Newer molecules that preserve packaged food materials from all forms of degradation are being developed, however oxygen absorbers remain a staple product for the preservation of food and pharmaceutical products to reduce food wastage in developed nations and increased food security in the developing & third world.

  14. Predictors of excessive use of social media and excessive online gaming in Czech teenagers.

    Science.gov (United States)

    Spilková, Jana; Chomynová, Pavla; Csémy, Ladislav

    2017-12-01

    Background and aims Young people's involvement in online gaming and the use of social media are increasing rapidly, resulting in a high number of excessive Internet users in recent years. The objective of this paper is to analyze the situation of excessive Internet use among adolescents in the Czech Republic and to reveal determinants of excessive use of social media and excessive online gaming. Methods Data from secondary school students (N = 4,887) were collected within the 2015 European School Survey Project on Alcohol and Other Drugs. Logistic regression models were constructed to describe the individual and familial discriminative factors and the impact of the health risk behavior of (a) excessive users of social media and (b) excessive players of online games. Results The models confirmed important gender-specific distinctions - while girls are more prone to online communication and social media use, online gaming is far more prevalent among boys. The analysis did not indicate an influence of family composition on both the excessive use of social media and on excessive online gaming, and only marginal effects for the type of school attended. We found a connection between the excessive use of social media and binge drinking and an inverse relation between excessive online gaming and daily smoking. Discussion and conclusion The non-existence of significant associations between family environment and excessive Internet use confirmed the general, widespread of this phenomenon across the social and economic strata of the teenage population, indicating a need for further studies on the topic.

  15. UV absorbance of a bioengineered corneal stroma substitute in the 240-400 nm range.

    Science.gov (United States)

    Ionescu, Ana-Maria; de la Cruz Cardona, Juan; González-Andrades, Miguel; Alaminos, Miguel; Campos, Antonio; Hita, Enrique; del Mar Pérez, María

    2010-08-01

    To determine the UV absorbance of a bioengineered human corneal stroma construct based on fibrin and fibrin-agarose scaffolds in the 240-400 nm range. Three types of artificial substitutes of the human corneal stroma were developed by tissue engineering using fibrin and fibrin with 0.1% and 0.2% agarose scaffolds with human keratocytes immersed within. After 28 days of culture, the UV absorbance of each sample was determined using a spectrophotometer. The thickness of corneal stroma samples was determined by light microscope. For all the 3 types of corneal stroma substitutes studied, the range of the UV absorbance values was similar to that of the native human corneal stroma, although the fibrin with 0.1% agarose stroma substitute had the best UV filtering properties. The higher UV absorbance of the artificial substitute of the human corneal stroma was in the UV-B and -A ranges, suggesting that these artificial tissues could have potential clinical usefulness and proper UV light-absorption capabilities. Our data suggest that the bioengineered human corneal substitute of fibrin with 0.1% agarose is an effective absorber of harmful UV radiation and could therefore be potentially useful.

  16. Experimental realization of ultrathin, double-sided metamaterial perfect absorber at terahertz gap through stochastic design process.

    Science.gov (United States)

    Huang, Tsung-Yu; Tseng, Ching-Wei; Yeh, Ting-Tso; Yeh, Tien-Tien; Luo, Chih-Wei; Akalin, Tahsin; Yen, Ta-Jen

    2015-12-22

    We design and demonstrate a flexible, ultrathin and double-sided metamaterial perfect absorber (MPA) at 2.39 terahertz (THz), which enables excellent light absorbance under incidences from two opposite sides. Herein, the MPA is fabricated on a λ0/10.1-thick flexible polyethylene terephthalate substrate of εr = 2.75 × (1 + 0.12i), sandwiched by two identical randomized metallic patterns by our stochastic design process. Such an MPA provides tailored permittivity and permeability to approach the impedance of free space for minimizing reflectance and a great imaginary part of the refractive index for reducing transmittance and finally results in high absorbance. Both experimental measurement and numerical simulation are in a good agreement. The flexible, ultrathin and double-sided MPA significantly differs from traditional quarter-wavelength absorbers and other single-sided perfect absorbers, paving a way toward practical THz applications in thermal emission, sensing and imaging, communications, stealth technique, and even energy harvesting.

  17. Optical analysis of solar energy tubular absorbers.

    Science.gov (United States)

    Saltiel, C; Sokolov, M

    1982-11-15

    The energy absorbed by a solar energy tubular receiver element for a single incident ray is derived. Two types of receiver elements were analyzed: (1) an inner tube with an absorbing coating surrounded by a semitransparent cover tube, and (2) a semitransparent inner tube filled with an absorbing fluid surrounded by a semitransparent cover tube. The formation of ray cascades in the semitransparent tubes is considered. A numerical simulation to investigate the influence of the angle of incidence, sizing, thickness, and coefficient of extinction of the tubes was performed. A comparison was made between receiver elements with and without cover tubes. Ray tracing analyses in which rays were followed within the tubular receiver element as well as throughout the rest of the collector were performed for parabolic and circular trough concentrating collectors.

  18. Broadband graphene-based metamaterial absorbers

    Science.gov (United States)

    Liu, Chang; Qi, Limei; Zhang, Xu

    2018-01-01

    In this paper, a new type of broadband tunable metamaterial absorber is proposed. The structure consists of a single-layer ring graphene and a metal ground plane separated by a dielectric spacer. The graphene rings are connected each other to be easily tuned by the voltage. In addition, this absorber is polarization-independent at normal incidence due to the symmetric pattern of the unit cell. Results reveal the bandwidth of 90% absorption reaches to 2.25 THz for a single-ring structure. The bandwidth of 90% absorption increases to 3.2 THz by combining two similar rings with different sizes in one unit cell. The physical mechanism of the single-ring and dual-ring absorbers are given based on the impedance matching theory.

  19. Absorbed Energy in Ship Collisions and Grounding

    DEFF Research Database (Denmark)

    Pedersen, Preben Terndrup; Zhang, Shengming

    1998-01-01

    is that the absorbed energy does not depend on the arrangement of the structure, the material properties, and the damage mode.The purpose of the present paper is to establish a new simple relation between the absorbed energy and the destroyed material volume, which can be used as a design tool for analysis of ship......Minorsky's well-known empirical formula, which relates the absorbed energy to the destroyed material volume, has been widely used in analyses of high energy collision and grounding accidents for nearly 40 years. The advantage of the method is its apparent simplcity. Obviously, its drawback...... collisions and grounding. The developed expressions reflect the structural arrangement, the material properties and different damage patterns.The present method is validated against a large number of existing experimental results and detailed numerical simulation results. Applications to full-sale ship...

  20. Ferrite HOM Absorber for the RHIC ERL

    Energy Technology Data Exchange (ETDEWEB)

    Hahn,H.; Choi, E.M.; Hammons, L.

    2008-10-01

    A superconducting Energy Recovery Linac is under construction at Brookhaven National Laboratory to serve as test bed for RHIC upgrades. The damping of higher-order modes in the superconducting five-cell cavity for the Energy-Recovery linac at RHIC is performed exclusively by two ferrite absorbers. The ferrite properties have been measured in ferrite-loaded pill box cavities resulting in the permeability values given by a first-order Debye model for the tiled absorber structure and an equivalent permeability value for computer simulations with solid ring dampers. Measured and simulated results for the higher-order modes in the prototype copper cavity are discussed. First room-temperature measurements of the finished niobium cavity are presented which confirm the effective damping of higher-order modes in the ERL. by the ferrite absorbers.

  1. Broadband graphene-based metamaterial absorbers

    Directory of Open Access Journals (Sweden)

    Chang Liu

    2018-01-01

    Full Text Available In this paper, a new type of broadband tunable metamaterial absorber is proposed. The structure consists of a single-layer ring graphene and a metal ground plane separated by a dielectric spacer. The graphene rings are connected each other to be easily tuned by the voltage. In addition, this absorber is polarization-independent at normal incidence due to the symmetric pattern of the unit cell. Results reveal the bandwidth of 90% absorption reaches to 2.25 THz for a single-ring structure. The bandwidth of 90% absorption increases to 3.2 THz by combining two similar rings with different sizes in one unit cell. The physical mechanism of the single-ring and dual-ring absorbers are given based on the impedance matching theory.

  2. Explaining CMS lepton excesses with supersymmetry

    CERN Multimedia

    CERN. Geneva; Prof. Allanach, Benjamin

    2014-01-01

    1) Kostas Theofilatos will give an introduction to CMS result 2) Ben Allanach: Several CMS analyses involving di-leptons have recently reported small 2.4-2.8 sigma local excesses: nothing to get too excited about, but worth keeping an eye on nonetheless. In particular, a search in the $lljj p_T$(miss) channel, a search for $W_R$ in the $lljj$ channel and a di-leptoquark search in the $lljj$ channel and $ljj p_T$(miss) channel have all yielded small excesses. We interpret the first excess in the MSSM, showing that the interpretation is viable in terms of other constraints, despite only having squark masses of around 1 TeV. We can explain the last three excesses with a single R-parity violating coupling that predicts a non-zero contribution to the neutrinoless double beta decay rate.

  3. Genetics Home Reference: aromatase excess syndrome

    Science.gov (United States)

    ... Ogata T. Genomic basis of aromatase excess syndrome: recombination- and replication-mediated rearrangements leading to CYP19A1 overexpression. ... 2013 Oct 18. Citation on PubMed More from Genetics Home Reference Bulletins Rare Disease Day 2018 Darwin ...

  4. Prevention of modern teenager's computer excessive gambling

    OpenAIRE

    Shamsutdinova, D.

    2011-01-01

    This article is devoted to the prevention of young people's excessive gambling. The article organized and convincingly derived the prevention strategies dependent gaming behavior among young people and teenagers.

  5. Excessive deforestation of Gishwati Mountainous forest ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    sigp1. Excessive deforestation of Gishwati. Mountainous forest & biodiversity changes. Introduction. The Change in Forest cover in. Rwanda is result of the high growth of population density. The latter has doubled between 1978 and 2002. Over.

  6. Phospholipids as Biomarkers for Excessive Alcohol Use

    Science.gov (United States)

    2017-03-01

    of SM and LPC and the amount of alcohol consumption during the past month. The proposal has both scientific and practical significance in... alcohol use (EAU). Drinking becomes excessive when it causes or elevates the risk for alcohol -related problems or complicates the management of other...the quantity of alcohol consumption during the past month. 2. KEYWORDS: Excessive alcohol use, lipidomics, timeline follow back 3. ACCOMPLISHMENTS

  7. Romanian welfare state between excess and failure

    Directory of Open Access Journals (Sweden)

    Cristina Ciuraru-Andrica

    2012-12-01

    Full Text Available Timely or not, our issue can bring back to life some prolific discussions, sometimes diametrical. We strike the social assistance, where, at this moment, is still uncertain if, once unleashed the excess, the failure will come inevitably or there is a “Salvation Ark”. However, the difference between the excess and the failure of the welfare state is almost intangible, the reason of his potential failure being actually the abuses made until the start of depression.

  8. Organizational Inertia and Excessive Product Proliferation

    OpenAIRE

    Sakuraki, Rie

    2015-01-01

    This study investigates the internal factors of excessive product proliferation. Since empirical literature on product over-proliferation focused on how to optimize existing product portfolio, the causes of excessive product proliferation have so far attracted little attention. This study employs a case study of Shiseido, a famous Japanese cosmetics company, with particular attention to product proliferation in the Shiseido chain store channel, because external factors are mostly absent from ...

  9. The hard X-ray perspective on the soft X-ray excess

    Energy Technology Data Exchange (ETDEWEB)

    Vasudevan, Ranjan V.; Mushotzky, Richard F.; Reynolds, Christopher S.; Lohfink, Anne M.; Zoghbi, Abderahmen [Department of Astronomy, University of Maryland, College Park, MD 20742-2421 (United States); Fabian, Andrew C. [Institute of Astronomy, Madingley Road, Cambridge CB3 0HA (United Kingdom); Gallo, Luigi C. [Department of Astronomy and Physics, Saint Mary' s University, 923 Robie Street, Halifax, Nova Scotia B3H 3C3 (Canada); Walton, Dominic, E-mail: ranjan@astro.umd.edu [Cahill Centre for Astronomy and Astrophysics, California Institute of Technology, Pasadena, CA 91125 (United States)

    2014-04-10

    The X-ray spectra of many active galactic nuclei exhibit a 'soft excess' below 1 keV, whose physical origin remains unclear. Diverse models have been suggested to account for it, including ionized reflection of X-rays from the inner part of the accretion disk, ionized winds/absorbers, and Comptonization. The ionized reflection model suggests a natural link between the prominence of the soft excess and the Compton reflection hump strength above 10 keV, but it has not been clear what hard X-ray signatures, if any, are expected from the other soft X-ray candidate models. Additionally, it has not been possible up until recently to obtain high-quality simultaneous measurements of both soft and hard X-ray emission necessary to distinguish these models but upcoming joint XMM-NuSTAR programs provide precisely this opportunity. In this paper, we present an extensive analysis of simulations of XMM-NuSTAR observations, using two candidate soft excess models as inputs, to determine whether such campaigns can disambiguate between them by using hard and soft X-ray observations in tandem. The simulated spectra are fit with the simplest 'observer's model' of a blackbody and neutral reflection to characterize the strength of the soft and hard excesses. A plot of the strength of the hard excess against the soft excess strength provides a diagnostic plot which allows the soft excess production mechanism to be determined in individual sources and samples using current state-of-the-art and next generation hard X-ray enabled observatories. This approach can be straightforwardly extended to other candidate models for the soft excess.

  10. Segmental neurofibromatosis presenting with congenital excessive skin folds.

    Science.gov (United States)

    Helfand, Alexander M; Nouriel, Ariella; Zisquit, Jonah; Barzilai, Aviv; Greenberger, Shoshana

    2015-04-01

    Segmental neurofibromatosis (SNF) is a rare type of neurofibromatosis (NF-1) resulting from post-zygotic somatic mutations in the neurofibromin gene that leads to mosaicism. Reported manifestations of SNF include neurofibromas, freckling, or café-au-lait spots limited to a single body region or limb. We present a 5-month-old male referred to our clinic for evaluation of congenital excessive skin folds on the back. A mildly erythematous, poorly demarcated soft plaque was noted, consisting of excessive skin folds. A cluster of light brown hyperpigmented macules was seen overlying the plaque. A punch biopsy of the plaque confirmed a diagnosis of neurofibroma. Further investigation ruled out other manifestations of NF-1. The early onset of our patient's neurofibroma and its gross appearance with redundant skin folds are all unusual features. To our knowledge, congenital excessive skin folds found in a single tumor have not been previously described in the literature as a manifestation of SNF. Clinicians should be educated about the possibility of congenital localized skin folds in association with SNF in order to identify the disease in infancy and monitor any changes in neurofibroma pathology.

  11. LINEAR MODEL FOR NON ISOSCELES ABSORBERS.

    Energy Technology Data Exchange (ETDEWEB)

    BERG,J.S.

    2003-05-12

    Previous analyses have assumed that wedge absorbers are triangularly shaped with equal angles for the two faces. In this case, to linear order, the energy loss depends only on the position in the direction of the face tilt, and is independent of the incoming angle. One can instead construct an absorber with entrance and exit faces facing rather general directions. In this case, the energy loss can depend on both the position and the angle of the particle in question. This paper demonstrates that and computes the effect to linear order.

  12. Polarization insensitive, broadband terahertz metamaterial absorber.

    Science.gov (United States)

    Grant, James; Ma, Yong; Saha, Shimul; Khalid, Ata; Cumming, David R S

    2011-09-01

    We present the simulation, implementation, and measurement of a polarization insensitive broadband resonant terahertz metamaterial absorber. By stacking metal-insulator layers with differing structural dimensions, three closely positioned resonant peaks are merged into one broadband absorption spectrum. Greater than 60% absorption is obtained across a frequency range of 1.86 THz where the central resonance frequency is 5 THz. The FWHM of the device is 48%, which is two and half times greater than the FWHM of a single layer structure. Such metamaterials are promising candidates as absorbing elements for bolometric terahertz imaging.

  13. Absorbing Aerosols Workshop, January 20-21, 2016

    Energy Technology Data Exchange (ETDEWEB)

    Nasiri, Shaima [Brookhaven National Lab. (BNL), Upton, NY (United States); Williamson, Ashley [Brookhaven National Lab. (BNL), Upton, NY (United States); Cappa, Christopher D. [Univ. of California, Berkeley, CA (United States); Kotamarthi, Davis Rao [Argonne National Lab. (ANL), Argonne, IL (United States); Sedlacek, Arthur J. [Brookhaven National Lab. (BNL), Upton, NY (United States); Flynn, Conner [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lewis, Ernie [Brookhaven National Lab. (BNL), Upton, NY (United States); McComiskey, Allison [National Oceanic and Atmospheric Administration (NOAA), Boulder, CO (United States); Riemer, Nicole [Univ. of Illinois, Chicago, IL (United States)

    2016-07-01

    A workshop was held at DOE Headquarters on January 20-21, 2016 during which experts within and outside DOE were brought together to identify knowledge gaps in modeling and measurement of the contribution of absorbing aerosols (AA) to radiative forcing. Absorbing aerosols refer to those aerosols that absorb light, whereby they both reduce the amount of sunlight reaching the surface (direct effect) and heat their surroundings. By doing so, they modify the vertical distribution of heat in the atmosphere and affect atmospheric thermodynamics and stability, possibly hastening cloud drop evaporation, and thereby affecting cloud amount, formation, dissipation and, ultimately, precipitation. Deposition of AA on snow and ice reduces surface albedo leading to accelerated melt. The most abundant AA type is black carbon (BC), which results from combustion of fossil fuel and biofuel. The other key AA types are brown carbon (BrC), which also results from combustion of fossil fuel and biofuel, and dust (crustal material). Each of these sources may result from, and be strongly influenced by, anthropogenic activities. The properties and amounts of AA depend upon various factors, primarily fuel source and burn conditions (e.g., internal combustion engine, flaming or smoldering wildfire), vegetation type (in the case of BC and BrC), and in the case of dust, soil type and ground cover (i.e., vegetation, snow, etc.). After emission, AA undergo chemical processing in the atmosphere that affects their physical and chemical properties. Thus, attribution of sources of AA, and understanding processes AA undergo during their atmospheric lifetimes, are necessary to understand how they will behave in a changing climate.

  14. Investigation of alternate mask absorbers in EUV lithography

    Science.gov (United States)

    Burkhardt, Martin

    2017-03-01

    In order to succeed with such low-k1 lithography at EUV wavelength, we need to be able to print a grating at high contrast similar to ArF immersion tools, where a contrast exceeding 0.95 is achieved routinely. All 2d printing is composed of interference of x and y-directed diffraction orders and high contrast in 2d thus depends on such 1d grating contrast. Any low-k1 imaging will use either dipole or some other sort of extreme off-axis illumination such as cross-quad (cQuad). The two relevant magnitudes for any high contrast are the intrinsic contrast due to a monopole, and the spatial shift of the two images that are generated by the two monopoles making up the dipole exposure. In EUV with current absorbers, high contrast can currently only be achieved using monopole illumination, a technique that does not lend itself to process integration due to removal of wafer side telecentricity and resulting overlay problems at all but preferred pitch. For dipole illumination at low-k1 pitches, we collect only 0th order light and only one 1st diffracted order for each pole. This means that for a dipole at the resolution limit, the final image for horizontal l/s patterns consists of only four incident waves, one TE and one TM wave for each of the poles. In this paper, we screen absorber by n and k values. In the process, we introduce phasor notation in order to gain insight into the behavior of the absorber and try to understand the metrics. We investigate intrinsic contrast and image blur due to monopole image shift.

  15. Mode-locking based on a zero-area pulse formation in a laser with a coherent absorber

    CERN Document Server

    Arkhipov, Mikhail V; Kalinichev, Alexey A; Babuskin, Ihar; Rosanov, Nikolai N; Arkhipov, Rostislav M

    2016-01-01

    We observe experimentally a mode-locking in a continuous narrow-band tunable dye laser with molecular iodine absorber cells, which transitions have large phase relaxation time T2. We show that the mode-locking arises due to coherent interaction of light with the absorbing medium leading to Rabi oscillations, so that zero-area (0{\\pi}-) pulses in the absorber are formed. Such mode-locking regime is different to most typical passive modelocking mechanisms where saturation plays the main role.

  16. Impacts of Snow Darkening by Absorbing Aerosols on Eurasian Climate

    Science.gov (United States)

    Kim, Kyu-Myong; Lau, William K M.; Yasunari, Teppei J.; Kim, Maeng-Ki; Koster, Randal D.

    2016-01-01

    The deposition of absorbing aerosols on snow surfaces reduces snow-albedo and allows snowpack to absorb more sunlight. This so-called snow darkening effect (SDE) accelerates snow melting and leads to surface warming in spring. To examine the impact of SDE on weather and climate during late spring and early summer, two sets of NASA GEOS-5 model simulations with and without SDE are conducted. Results show that SDE-induced surface heating is particularly pronounced in Eurasian regions where significant depositions of dust transported from the North African deserts, and black carbon from biomass burning from Asia and Europe occur. In these regions, the surface heating due to SDE increases surface skin temperature by 3-6 degrees Kelvin near the snowline in spring. Surface energy budget analysis indicates that SDE-induced excess heating is associated with a large increase in surface evaporation, subsequently leading to a significant reduction in soil moisture, and increased risks of drought and heat waves in late spring to early summer. Overall, we find that rainfall deficit combined with SDE-induced dry soil in spring provide favorable condition for summertime heat waves over large regions of Eurasia. Increased frequency of summer heat waves with SDE and the region of maximum increase in heat-wave frequency are found along the snow line, providing evidence that early snowmelt by SDE may increase the risks of extreme summer heat wave. Our results suggest that climate models that do not include SDE may significantly underestimate the effect of global warming over extra-tropical continental regions.

  17. High efficiency light source using solid-state emitter and down-conversion material

    Science.gov (United States)

    Narendran, Nadarajah; Gu, Yimin; Freyssinier, Jean Paul

    2010-10-26

    A light emitting apparatus includes a source of light for emitting light; a down conversion material receiving the emitted light, and converting the emitted light into transmitted light and backward transmitted light; and an optic device configured to receive the backward transmitted light and transfer the backward transmitted light outside of the optic device. The source of light is a semiconductor light emitting diode, a laser diode (LD), or a resonant cavity light emitting diode (RCLED). The down conversion material includes one of phosphor or other material for absorbing light in one spectral region and emitting light in another spectral region. The optic device, or lens, includes light transmissive material.

  18. [What nosographic framework for excessive tanning?].

    Science.gov (United States)

    Petit, A; Karila, L; Lejoyeux, M

    2014-04-01

    Socially valorised tanning, like other forms of behaviour, can take on an addictive aspect. Excessive tanning, defined by the presence of impulsivity and repetition of tanning that leads to personal distress, is a psychiatric disorder that has only recently been recognized. This finding is based on the observations of many dermatologists who report an addictive relationship in their patients with tanning cabins despite announcement of the diagnosis of malignant melanoma. This article attempts to synthesize the existing literature on excessive tanning and addiction to investigate possible associations. This review focuses on the prevalence, clinical features, aetiology, and treatment of this disorder. The literature review was conducted from 1983 to 2012, using PubMed, Google Scholar, EMBASE, and PsycInfo, using the following keywords alone or combined: Tanning, Addiction, Sunbeds, Skin cancer prevention, and Treatment. We investigated different models to determine how excessive tanning met these criteria. Excessive Tanning was described in the 2000s by an American dermatologist, Carolyn Heckman. Wartham et al. were the first to have proposed a theoretical framework for addiction to sunbathing, as well as two scales (m CAGE and m DSM IV) for the diagnosis and to assess the degree of addiction. These diagnostic criteria describe the craving like-symptoms, the feeling of losing control, or the continuation of the behavior despite knowledge of negative consequences. Excessive Tanning is not present in the classifications of the DSM or ICD, but may be related to Addiction, Obsessive-Compulsive Disorder, Impulse control disorders, Anorexia, or Body Dysmorphic Disorder. Excessive tanning can be included in the spectrum of behavioural addictions due its clinical characteristics in common with classics addictive disorders. They are a variety of other models, which may offer an explanation for or insight into tanning behaviour. Further studies must be controlled, notably on

  19. Plasmonic black gold by adiabatic nanofocusing and absorption of light in ultra-sharp convex grooves

    National Research Council Canada - National Science Library

    Søndergaard, Thomas; Novikov, Sergey M; Holmgaard, Tobias; Eriksen, René L; Beermann, Jonas; Han, Zhanghua; Pedersen, Kjeld; Bozhevolnyi, Sergey I

    2012-01-01

    Excitation of localized and delocalized surface plasmon resonances can be used for turning excellent reflectors of visible light, such as gold and silver, into efficient absorbers, whose wavelength...

  20. Selective mass transfer in a membrane absorber

    Science.gov (United States)

    Okunev, A. Yu.; Laguntsov, N. I.

    2006-09-01

    A theoretical study of selective mass transfer in a plane-frame membrane absorber (contactor) has been made. A mathematical model of the process has been developed and the process of purification of a gas mixture depending on the flow parameters, the membrane, and the feeding-mixture composition has been studied with its help.

  1. Electromagnetic and microwave absorbing properties of hollow ...

    Indian Academy of Sciences (India)

    Keywords. Nanomaterials; nanospheres; CVD; electric; magnetic; microwave absorption properties. 1. Introduction. In recent years, microwave absorbing materials have attracted considerable attention because it is an essential part of a stealthy defense system for all military platforms, either as aircraft, sea or land vehicles.

  2. Metamaterial Absorber Based Multifunctional Sensor Application

    Science.gov (United States)

    Ozer, Z.; Mamedov, A. M.; Ozbay, E.

    2017-02-01

    In this study metamaterial based (MA) absorber sensor, integrated with an X-band waveguide, is numerically and experimentally suggested for important application including pressure, density sensing and marble type detecting applications based on rectangular split ring resonator, sensor layer and absorber layer that measures of changing in the dielectric constant and/or the thickness of a sensor layer. Changing of physical, chemical or biological parameters in the sensor layer can be detected by measuring the resonant frequency shifting of metamaterial absorber based sensor. Suggested MA based absorber sensor can be used for medical, biological, agricultural and chemical detecting applications in microwave frequency band. We compare the simulation and experimentally obtained results from the fabricated sample which are good agreement. Simulation results show that the proposed structure can detect the changing of the refractive indexes of different materials via special resonance frequencies, thus it could be said that the MA-based sensors have high sensitivity. Additionally due to the simple and tiny structures it could be adapted to other electronic devices in different sizes.

  3. Can polar bear hairs absorb environmental energy?

    Directory of Open Access Journals (Sweden)

    He Ji-Huan

    2011-01-01

    Full Text Available A polar bear (Ursus maritimus has superior ability to survive in harsh Arctic regions, why does the animal have such an excellent thermal protection? The present paper finds that the unique labyrinth cavity structure of the polar bear hair plays an important role. The hair can not only prevent body temperature loss but can also absorb energy from the environment.

  4. a solid absorbent for solar refrigeration

    African Journals Online (AJOL)

    user

    ABSTRACT. The thermophysical properties of 'Nsukkanut', - a CaCl2/CaSO4 absorbent mixture used in solid absorption solar refrigeration [1], were studied in this report. The transient experimental technique of Beck and Al-Araji. [12] was used in determining the effective thermal conductivity, specific heat and bulk thermal ...

  5. Moving core beam energy absorber and converter

    Science.gov (United States)

    Degtiarenko, Pavel V.

    2012-12-18

    A method and apparatus for the prevention of overheating of laser or particle beam impact zones through the use of a moving-in-the-coolant-flow arrangement for the energy absorbing core of the device. Moving of the core spreads the energy deposition in it in 1, 2, or 3 dimensions, thus increasing the effective cooling area of the device.

  6. MODELING AND SIMULATION OF INDUSTRIAL FORMALDEHYDE ABSORBERS

    NARCIS (Netherlands)

    WINKELMAN, JGM; SIJBRING, H; BEENACKERS, AACM; DEVRIES, ET

    1992-01-01

    The industrially important process of formaldehyde absorption in water constitutes a case of multicomponent mass transfer with multiple reactions and considerable heat effects. A stable solution algorithm is developed to simulate the performance of industrial absorbers for this process using a

  7. The design of broadband radar absorbing surfaces

    Science.gov (United States)

    Suk, Go H.

    1990-09-01

    There has been a growing and widespread interest in radar absorbing material technology. As the name implies, radar absorbing materials or RAM's are coatings whose electric and magnetic properties have been selected to allow the absorption of microwave energy at discrete or broadband frequencies. In military applications low radar cross section (RCS) of a vehicle may be required in order to escape detection while a covert mission is being carried on. These requirements have led to the very low observable or stealth technology that reduces the probability of detection of an aircraft. The design of radar absorbing materials is limited by constraints on the allowable volume and weight of the surface coating, and it is difficult to design a broadband radar absorbing structure in limited volume. This thesis investigates the use of lossy dielectric materials of high dielectric permittivity in multilayer composites for the production of low radar cross section (RCS). The analysis is done by computing the plane wave reflection coefficient at the exterior surface of the composite coating by means of a computer program which selects layer parameters which determine low reflection coefficients for electromagnetic radiation under constraint of limited layer thickness as well as maximum frequency bandwidth.

  8. Tunable metamaterial dual-band terahertz absorber

    Science.gov (United States)

    Luo, C. Y.; Li, Z. Z.; Guo, Z. H.; Yue, J.; Luo, Q.; Yao, G.; Ji, J.; Rao, Y. K.; Li, R. K.; Li, D.; Wang, H. X.; Yao, J. Q.; Ling, F. R.

    2015-11-01

    We report a design of a temperature controlled tunable dual band terahertz absorber. The compact single unit cell consists of two nested closed square ring resonators and a layer metallic separated by a substrate strontium titanate (STO) dielectric layer. It is found that the absorber has two distinctive absorption peaks at frequencies 0.096 THz and 0.137 THz, whose peaks are attained 97% and 75%. Cooling the absorber from 400 K to 250 K causes about 25% and 27% shift compared to the resonance frequency of room temperature, when we cooling the temperature to 150 K, we could attained both the two tunabilities exceeding 53%. The frequency tunability is owing to the variation of the dielectric constant of the low-temperature co-fired ceramic (LTCC) substrate. The mechanism of the dual band absorber is attributed to the overlapping of dual resonance frequencies, and could be demonstrated by the distributions of the electric field. The method opens up avenues for designing tunable terahertz devices in detection, imaging, and stealth technology.

  9. Semiconductor saturable absorbers for ultrafast terahertz signals

    DEFF Research Database (Denmark)

    Hoffmann, Matthias C.; Turchinovich, Dmitry

    2010-01-01

    We demonstrate saturable absorber behavior of n-type semiconductors GaAs, GaP, and Ge in the terahertz THz frequency range at room temperature using nonlinear THz spectroscopy. The saturation mechanism is based on a decrease in electron conductivity of semiconductors at high electron momentum...

  10. Tungsten based Anisotropic Metamaterial as an Ultra-broadband Absorber

    CERN Document Server

    Lin, Yinyue; Ding, Fei; Fung, Kin Hung; Ji, Ting; Li, Dongdong; Hao, Yuying

    2016-01-01

    The trapped rainbow effect has been mostly found on tapered anisotropic metamaterials (MMs) made of low loss noble metals, such as gold, silver, etc. In this work, we demonstrate that an anisotropic MM waveguide made of high loss metal tungsten can also support the trapped rainbow effect similar to the noble metal based structure. We show theoretically that an array of tungsten/germanium anisotropic nano-cones placed on top of a reflective substrate can absorb light at the wavelength range from 0.3 micrometer to 9 micrometer with an average absorption efficiency approaching 98%. It is found that the excitation of multiple orders of slow-light resonant modes is responsible for the efficient absorption at wavelengths longer than 2 micrometer, and the anti-reflection effect of tapered lossy material gives rise to the near perfect absorption at shorter wavelengths. The absorption spectrum suffers a small dip at around 4.2 micrometer where the first order and second order slow-light modes get overlapped, but we ca...

  11. Neutron absorbers and methods of forming at least a portion of a neutron absorber

    Science.gov (United States)

    Guillen, Donna P; Porter, Douglas L; Swank, W David; Erickson, Arnold W

    2014-12-02

    Methods of forming at least a portion of a neutron absorber include combining a first material and a second material to form a compound, reducing the compound into a plurality of particles, mixing the plurality of particles with a third material, and pressing the mixture of the plurality of particles and the third material. One or more components of neutron absorbers may be formed by such methods. Neutron absorbers may include a composite material including an intermetallic compound comprising hafnium aluminide and a matrix material comprising pure aluminum.

  12. Active microwave absorber with the dual-ability of dividable modulation in absorbing intensity and frequency

    Directory of Open Access Journals (Sweden)

    Xiaoyu Wu

    2013-02-01

    Full Text Available We present the design, fabrication and experimental demonstration of an electrically active absorber at microwave frequency. Unlike those proposed before, simulation and experiment data present that its working frequency and absorbing intensity can be both but separately controlled. The electromagnetic coupling analysis reveals that the feature arises from the dividable frequency and amplitude modulation on an active magnetic resonator controlled by varactor and pin diodes. Such separable modulating behaviors are further confirmed by the equivalent LC circuit model. It is believed that this will be an important step towards smart application of active absorber.

  13. Antidepressant induced excessive yawning and indifference

    Directory of Open Access Journals (Sweden)

    Bruno Palazzo Nazar

    2015-03-01

    Full Text Available Introduction Antidepressant induced excessive yawning has been described as a possible side effect of pharmacotherapy. A syndrome of indifference has also been described as another possible side effect. The frequency of those phenomena and their physiopathology are unknown. They are both considered benign and reversible after antidepressant discontinuation but severe cases with complications as temporomandibular lesions, have been described. Methods We report two unprecedented cases in which excessive yawning and indifference occurred simultaneously as side effects of antidepressant therapy, discussing possible physiopathological mechanisms for this co-occurrence. Case 1: A male patient presented excessive yawning (approximately 80/day and apathy after venlafaxine XR treatment. Symptoms reduced after a switch to escitalopram, with a reduction to 50 yawns/day. Case 2: A female patient presented excessive yawning (approximately 25/day and inability to react to environmental stressors with desvenlafaxine. Conclusion Induction of indifference and excessive yawning may be modulated by serotonergic and noradrenergic mechanisms. One proposal to unify these side effects would be enhancement of serotonin in midbrain, especially paraventricular and raphe nucleus.

  14. Photoacoustic holographic imaging of absorbers embedded in silicone.

    Science.gov (United States)

    Olsson, Erik; Gren, Per; Sjödahl, Mikael

    2011-06-10

    Light absorbing objects embedded in silicone have been imaged using photoacoustic digital holography. The photoacoustic waves were generated using a pulsed Nd:YAG laser, λ=1064  nm, and pulse length=12  ns. When the waves reached the silicone surface, they were measured optically along a line using a scanning laser vibrometer. The acoustic waves were then digitally reconstructed using a holographic algorithm. The laser vibrometer is proven to be sensitive enough to measure the surface velocity due to photoacoustic waves generated from laser pulses with a fluence allowed for human tissue. It is also shown that combining digital holographic reconstructions for different acoustic wavelengths provides images with suppressed noise and improved depth resolution. The objects are imaged at a depth of 16.5  mm with a depth resolution of 0.5  mm.

  15. Non-Hermitian engineering of synthetic saturable absorbers

    CERN Document Server

    Teimourpour, M H; Srinivasan, K; El-Ganainy, R

    2016-01-01

    We introduce a new type of synthetic saturable absorbers based on quantum inspired photonic arrays whose linear light transport characteristics can be derived via bosonic algebra. We demonstrate that the interplay between optical Kerr nonlinearity, interference effects and non-Hermiticity through radiation loss leads to a nonlinear optical filtering response with two distinct regimes of small and large optical transmissions. More interestingly, we show that the boundary between these two regimes can be very sharp. The threshold optical intensity that marks this abrupt "phase transition" and its steepness can be engineered by varying the number of the guiding elements. The practical feasibility of these structures as well as their potential applications in laser systems and optical signal processing are also discussed.

  16. [Effects of NO3- stress on photosynthetic rate, photochemical efficiency of PS II and light energy allocation in cucumber seedling leaves].

    Science.gov (United States)

    Su, Xiu-Rong; Wang, Xiu-Feng; Yang, Feng-Juan; Wei, Min

    2007-07-01

    This paper studied the effects of different NO3- concentration on the photosynthetic rate, photochemical efficiency, and absorbed light energy allocation in cucumber seedling leaves. The results indicated that when the available NO3- concentration in the medium was low (14-98 mmol NO3- x L(-1)), an appropriate supplement of NO3- could enhance the capability of cucumber leaves in capturing light energy, and promote the photosynthesis. However, with further increase of NO3-, the photochemical efficiency of PS II decreased, electron transfer restrained, and net photosynthetic rate as well as the absorbed light energy used in photochemical reaction of PS II decreased. At the same time, the light energy used in antenna heat dissipation increased, while the photochemical efficiency decreased. After treated with 140 and 182 mmol NO3- x L(-1) for 6 days, the photosynthetic rate (P(n)) was decreased by 35% and 78%, respectively, maximal PS II efficiency at open centers in the absence of NPQ (F(v)/F(m)), antenna efficiency at open centers in the presence of NPQ (F(v)'/F(m)'), actual PS II efficiency (phi (PSII ) and photochemical quenching (q(P)) were lower, non-photochemical quenching (NPQ) was higher, and the deviation from full balance between PS I and PS II (beta/alpha - 1) was improved significantly, compared with the control. The fluctuant ranges of these chlorophyll fluorescence parameters were increased at higher NO3- concentration, compared with those at lower NO3- concentration. The absorbed light energy allocated to the photochemical reaction of PS II (P) was reduced by high light intensity and high NO3- concentration. Meanwhile, the proportion allocated in antenna heat dissipation (D) increased significantly. Antenna heat dissipation was the main way for excessive energy dissipation.

  17. Conversion of light energy in algal culture

    NARCIS (Netherlands)

    Oorschot, van J.L.P.

    1955-01-01

    The conversion of light energy in algal culture was quantitatively studied under various growth conditions. Absorbed light energy during growth and energy fixed in organic material were estimated. The efficiency of the conversion was expressed as percentage of fixed energy (calculated from estimates

  18. Impact of light color on photobioreactor productivity

    NARCIS (Netherlands)

    Mooij, de T.; Vries, de Guus; Latsos, Christos; Wijffels, R.H.; Janssen, M.G.J.

    2016-01-01

    Microalgae perform photosynthesis at a high efficiency under low light conditions. However, under bright sunlight, it is difficult to achieve a high photosynthetic efficiency, because cells absorb more light energy than can be converted to biochemical energy. Consequently microalgae dissipate part

  19. Limiting law excess sum rule for polyelectrolytes.

    Science.gov (United States)

    Landy, Jonathan; Lee, YongJin; Jho, YongSeok

    2013-11-01

    We revisit the mean-field limiting law screening excess sum rule that holds for rodlike polyelectrolytes. We present an efficient derivation of this law that clarifies its region of applicability: The law holds in the limit of small polymer radius, measured relative to the Debye screening length. From the limiting law, we determine the individual ion excess values for single-salt electrolytes. We also consider the mean-field excess sum away from the limiting region, and we relate this quantity to the osmotic pressure of a dilute polyelectrolyte solution. Finally, we consider numerical simulations of many-body polymer-electrolyte solutions. We conclude that the limiting law often accurately describes the screening of physical charged polymers of interest, such as extended DNA.

  20. Stable high-power saturable absorber based on polymer-black-phosphorus films

    Science.gov (United States)

    Mao, Dong; Li, Mingkun; Cui, Xiaoqi; Zhang, Wending; Lu, Hua; Song, Kun; Zhao, Jianlin

    2018-01-01

    Black phosphorus (BP), a rising two-dimensional material with a layer-number-dependent direct bandgap of 0.3-1.5 eV, is very interesting for optoelectronics applications from near- to mid-infrared wavebands. In the atmosphere, few-layer BP tends to be oxidized or degenerated during interacting with lasers. Here, we fabricate few-layer BP nanosheets based on a liquid exfoliation method using N-methylpyrrolidone as the dispersion liquid. By incorporating BP nanosheets with polymers (polyvinyl alcohol or high-melting-point polyimide), two flexible filmy BP saturable absorbers are fabricated to realize passive mode locking in erbium-doped fiber lasers. The polymer-BP saturable absorber, especially the polyimide-BP saturable absorber, can prevent the oxidation or water-induced etching under high-power laser illuminations, providing a promising candidate for Q-switchers, mode lockers, and light modulators.

  1. Photoacoustic Determination of Non-radiative Relaxation Time of Absorbing Centers in Maize Seeds

    Science.gov (United States)

    Domínguez-Pacheco, A.; Hernández-Aguilar, C.; Cruz-Orea, A.

    2017-07-01

    Using non-destructive photothermal techniques, it is possible to characterize non-homogenous materials to obtain its optical and thermal properties through photoacoustic spectroscopy (PAS). In photoacoustic (PA) phenomena, there are transient states of thermal excitation, when samples absorb the incident light; these states manifest an excitation process that generates the PA signal, being in direct relation with the non-radiative relaxation times with the sample absorbent centers. The objective of this study was to determine the non-radiative relaxation times associated with different absorbent centers of corn seeds ( Zea mays L.), by using PAS. A frequency scan was done at different wavelengths (350 nm, 470 nm and 650 nm) in order to obtain the non-radiative relaxation times with different types of maize seeds.

  2. A THz plasmonics perfect absorber and Fabry-Perot cavity mechanism (Conference Presentation)

    Science.gov (United States)

    Zhou, Jiangfeng; Bhattarai, Khagendra; Silva, Sinhara; Jeon, Jiyeon; Kim, Junoh; Lee, Sang Jun; Ku, Zahyun

    2016-10-01

    The plasmonic metamaterial perfect absorber (MPA) is a recently developed branch of metamaterial which exhibits nearly unity absorption within certain frequency range.[1-6] The optically thin MPA possesses characteristic features of angular-independence, high Q-factor and strong field localization that have inspired a wide range of applications including electromagnetic wave absorption,[3, 7, 8] spatial[6] and spectral[5] modulation of light,[9] selective thermal emission,[9] thermal detecting[10] and refractive index sensing for gas[11] and liquid[12, 13] targets. In this work, we demonstrate a MPA working at terahertz (THz) regime and characterize it using an ultrafast THz time-domain spectroscopy (THz-TDS). Our study reveal an ultra-thin Fabry-Perot cavity mechanism compared to the impedance matching mechanism widely adopted in previous study [1-6]. Our results also shows higher-order resonances when the cavities length increases. These higher order modes exhibits much larger Q-factor that can benefit potential sensing and imaging applications. [1] C. M. Watts, X. L. Liu, and W. J. Padilla, "Metamaterial Electromagnetic Wave Absorbers," Advanced Materials, vol. 24, pp. 98-120, Jun 19 2012. [2] M. Hedayati, F. Faupel, and M. Elbahri, "Review of Plasmonic Nanocomposite Metamaterial Absorber," Materials, vol. 7, pp. 1221-1248, 2014. [3] N. I. Landy, S. Sajuyigbe, J. J. Mock, D. R. Smith, and W. J. Padilla, "Perfect metamaterial absorber," Physical Review Letters, vol. 100, p. 207402, May 23 2008. [4] H. R. Seren, G. R. Keiser, L. Cao, J. Zhang, A. C. Strikwerda, K. Fan, et al., "Optically Modulated Multiband Terahertz Perfect Absorber," Advanced Optical Materials, vol. 2, pp. 1221-1226, 2014. [5] D. Shrekenhamer, J. Montoya, S. Krishna, and W. J. Padilla, "Four-Color Metamaterial Absorber THz Spatial Light Modulator," Advanced Optical Materials, vol. 1, pp. 905-909, 2013. [6] S. Savo, D. Shrekenhamer, and W. J. Padilla, "Liquid Crystal Metamaterial Absorber Spatial

  3. The High Price of Excessive Alcohol Consumption

    Centers for Disease Control (CDC) Podcasts

    2011-10-17

    This podcast is based on the October 2011 release of a report estimating the economic cost of excessive drinking. Excessive alcohol consumption cost the U. S. $223.5 billion in 2006, or about $1.90 per drink. Over three-quarters (76%) of these costs were due to binge drinking, defined as consuming 4 or more alcoholic beverages per occasion for women or 5 or more drinks per occasion for men.  Created: 10/17/2011 by National Center for Chronic Disease Prevention and Health Promotion.   Date Released: 10/17/2011.

  4. Contrast induced hyperthyroidism due to iodine excess

    Science.gov (United States)

    Mushtaq, Usman; Price, Timothy; Laddipeerla, Narsing; Townsend, Amanda; Broadbridge, Vy

    2009-01-01

    Iodine induced hyperthyroidism is a thyrotoxic condition caused by exposure to excessive iodine. Historically this type of hyperthyroidism has been described in areas of iodine deficiency. With advances in medicine, iodine induced hyperthyroidism has been observed following the use of drugs containing iodine—for example, amiodarone, and contrast agents used in radiological imaging. In elderly patients it is frequently difficult to diagnose and control contrast related hyperthyroidism, as most of these patients do not always present with typical signs and symptoms of hyperthyroidism. Treatment can be very challenging as drugs commonly used to treat hyperthyroidism have little effect on already formed thyroid hormone due to iodine excess. PMID:22053166

  5. Effects of Excessive Dietary Phosphorus Intake on Bone Health.

    Science.gov (United States)

    Vorland, Colby J; Stremke, Elizabeth R; Moorthi, Ranjani N; Hill Gallant, Kathleen M

    2017-08-24

    The purpose of this review is to provide an overview of dietary phosphorus, its sources, recommended intakes, and its absorption and metabolism in health and in chronic kidney disease and to discuss recent findings in this area with a focus on the effects of inorganic phosphate additives in bone health. Recent findings show that increasing dietary phosphorus through inorganic phosphate additives has detrimental effects on bone and mineral metabolism in humans and animals. There is new data supporting an educational intervention to limit phosphate additives in patients with chronic kidney disease to control serum phosphate. The average intake of phosphorus in the USA is well above the recommended dietary allowance. Inorganic phosphate additives, which are absorbed at a high rate, account for a substantial and likely underestimated portion of this excessive intake. These additives have negative effects on bone metabolism and present a prime opportunity to lower total phosphorus intake in the USA. Further evidence is needed to confirm whether lowering dietary phosphorus intake would have beneficial effects to improve fracture risk.

  6. Optimization of a bolometer detector for ITER based on Pt absorber on SiN membrane

    Energy Technology Data Exchange (ETDEWEB)

    Meister, H.; Eich, T.; Endstrasser, N.; Giannone, L.; Kannamueller, M.; Kling, A.; Koll, J.; Trautmann, T. [Max-Planck-Institut fuer Plasmaphysik, EURATOM Association, Boltzmannstr. 2, D-85748 Garching (Germany); Detemple, P.; Schmitt, S. [Institut fuer Mikrotechnik Mainz GmbH, Carl-Zeiss-Str. 18-20, D-55129 Mainz (Germany); Collaboration: ASDEX Upgrade Team

    2010-10-15

    Any plasma diagnostic in ITER must be able to operate at temperatures in excess of 200 deg. C and neutron loads corresponding to 0.1 dpa over its lifetime. To achieve this aim for the bolometer diagnostic, a miniaturized metal resistor bolometer detector based on Pt absorbers galvanically deposited on SiN membranes is being developed. The first two generations of detectors featured up to 4.5 {mu}m thick absorbers. Results from laboratory tests are presented characterizing the dependence of their calibration constants under thermal loads up to 450 deg. C. Several detectors have been tested in ASDEX Upgrade providing reliable data but also pointing out the need for further optimization. A laser trimming procedure has been implemented to reduce the mismatch in meander resistances below 1% for one detector and the thermal drifts from this mismatch.

  7. Design Guidelines for Ferrite Absorbers Submitted to RF-induced Heating

    CERN Document Server

    Bertarelli, A

    2013-01-01

    The use of ferrite absorbers is one of the most effective means of damping potentially harmful high order RF modes, which may lead to beam instabilities and excessive power losses in accelerator devices. However, the power deposited on ferrite absorbers themselves maylead to ferrite exceeding its Curie temperature, losing its damping properties. An evaluation of the ferrite capability to dissipate deposited heat is hence of paramount importance for the safe design of particle accelerator devices. In this paper, figures of merit are proposed to assess the maximum specific power allowed on a generic ferrite tile, before it reaches its Curie temperature. Due to its inherent brittleness, sufficient contact pressure between ferrite and its housing, allowing heat transmission by conduction, can hardly be applied. A semi-analytical study is thus performed, assuming that ferrite is evacuating heat solely through radiation. The described method is then exemplified in the case of the BPM-embedded tertiary collimator (T...

  8. Realisation of 3D metamaterial perfect absorber structures by direct laser writing

    Science.gov (United States)

    Fanyaeu, I.; Mizeikis, V.

    2017-02-01

    We report design, fabrication and optical properties of 3D electromagnetic metamaterial structures applicable as perfect absorbers (PA) at mid infra-red frequencies. PA architecture consisting of single-turn metallic helices arranged in a periodic two-dimensional array enables polarization-invariant perfect absorption within a considerable range of incidence angles. The absorber structure is all-metallic, and in principle does not require metallic ground plane, which permits optical transparency at frequencies away from the PA resonance. The samples were fabricated by preparing their dielectric templates using Direct Laser Write technique in photoresist, and metalisation by gold sputtering. Resonant absorption in excess of 90% was found at the resonant wavelength of 7.7 μm in accordance with numerical modelling. Similar PA structures may prove useful for harvesting and conversion of infrared energy as well as narrow-band thermal emission and detection.

  9. Effect of the bio-absorbent on the microwave absorption property of the flaky CIPs/rubber absorbers

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Yang; Xu, Yonggang, E-mail: xuyonggang221@163.com; Cai, Jun; Yuan, Liming; Zhang, Deyuan

    2015-09-01

    Microwave absorbing composites filled with flaky carbonyl iron particles (CIPs) and the bio-absorbent were prepared by using a two-roll mixer and a vulcanizing machine. The electromagnetic (EM) parameters were measured by a vector network analyzer and the reflection loss (RL) was measured by the arch method in the frequency range of 1–4 GHz. The uniform dispersion of the absorbents was verified by comparing the calculated RL with the measured one. The results confirm that as the bio-absorbent was added, the permittivity was increased due to the volume content of absorbents, and the permeability was enlarged owing to the volume content of CIPs and interactions between the two absorbents. The composite filled with bio-absorbents achieved an excellent absorption property at a thickness of 1 mm (minimum RL reaches −7.8 dB), and as the RL was less than −10 dB the absorption band was widest (2.1–3.8 GHz) at a thickness of 2 mm. Therefore, the bio-absorbent is a promising additive candidate on fabricating microwave absorbing composites with a thinner thickness and wider absorption band. - Graphical abstract: Morphology of composites filled with flaky CIPs and the bio-absorbent. The enhancement of bio-absorbent on the electromagnetic absorption property of composites filled with flaky carbonyl iron particles (CIPs) is attributed to the interaction of the two absorbents. The volume content of the FCMPs with the larger shape CIPs play an important role in this effects, the composites filled with irons and bio-absorbents can achieve wider-band and thinner-thickness absorbing materials. - Highlights: • Absorbers filled with bio-absorbents and CIPs was fabricated. • Bio-absorbents enhanced the permittivity and permeability of the composites. • The absorbent interactions play a key role in the enhancement mechanism. • Bio-absorbents enhanced the composite RL in 1–4 GHz.

  10. Active packaging using ethylene absorber to extend shelf-life

    Energy Technology Data Exchange (ETDEWEB)

    Ponce, Patricia; Carbonari, Guilherme L.R.; Lugao, Ademar B. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)], e-mail: patponce@iq.usp.br, e-mail: guilacaz@uol.com.br, e-mail: ablugao@ipen.br

    2009-07-01

    Ethylene gas is a plant hormone which is produced by fruits and vegetables during ripening and it is also found in the environment. It plays an essential role in normal ripening, but excessive exposure can radically reduce the shelf-life of the product, in some cases inducing undesirable reactions such as development of bitter flavors and loss of chlorophyll (yellowing of greens). The objectives of our work were: to test an active packaging of polyvinyl alcohol (PVA) for apple stored; to test the effect of ethylene absorber agent, impregnated in plastic film, to reduce decay of fresh apple; to study the influence of radiation on the barrier properties, mechanical properties and biodegradability of PVA films. This study evaluated the effect of coating produced from PVA and polyol (glycerol and sorbitol) as plasticizer on apple conservation (75 deg F (24 deg C); 70%RH). The coated product was analyzed for mass loss, color alterations and fungi. The PVA films were produced by casting process (dehydration of a filmogenic solution on Petriplastic dishes) and were irradiated at low doses of 2, 5 and 10 kGy, commonly used in food irradiation. The resulting films were transparent and homogeneous. The active packaged fruits presented higher acceptance, lower microbiological growth, less alterations in acidity, lower weight loss rate during the storage time and an extended shelf-life as compared to the control fruits (without plastic films). (author)

  11. Background model systematics for the Fermi GeV excess

    Energy Technology Data Exchange (ETDEWEB)

    Calore, Francesca; Cholis, Ilias; Weniger, Christoph

    2015-03-01

    The possible gamma-ray excess in the inner Galaxy and the Galactic center (GC) suggested by Fermi-LAT observations has triggered a large number of studies. It has been interpreted as a variety of different phenomena such as a signal from WIMP dark matter annihilation, gamma-ray emission from a population of millisecond pulsars, or emission from cosmic rays injected in a sequence of burst-like events or continuously at the GC. We present the first comprehensive study of model systematics coming from the Galactic diffuse emission in the inner part of our Galaxy and their impact on the inferred properties of the excess emission at Galactic latitudes 2° < |b| < 20° and 300 MeV to 500 GeV. We study both theoretical and empirical model systematics, which we deduce from a large range of Galactic diffuse emission models and a principal component analysis of residuals in numerous test regions along the Galactic plane. We show that the hypothesis of an extended spherical excess emission with a uniform energy spectrum is compatible with the Fermi-LAT data in our region of interest at 95% CL. Assuming that this excess is the extended counterpart of the one seen in the inner few degrees of the Galaxy, we derive a lower limit of 10.0° (95% CL) on its extension away from the GC. We show that, in light of the large correlated uncertainties that affect the subtraction of the Galactic diffuse emission in the relevant regions, the energy spectrum of the excess is equally compatible with both a simple broken power-law of break energy E(break) = 2.1 ± 0.2 GeV, and with spectra predicted by the self-annihilation of dark matter, implying in the case of bar bb final states a dark matter mass of m(χ)=49(+6.4)(-)(5.4)  GeV.

  12. Use of Wedge Absorbers in MICE

    Energy Technology Data Exchange (ETDEWEB)

    Neuffer, D. [Fermi National Accelerator Lab. (FNAL), Batavia, IL (United States); Summers, D. [Univ. of Mississippi, Oxford, MS (United States); Mohayai, T. [Fermi National Accelerator Lab. (FNAL), Batavia, IL (United States); IIT, Chicago, IL (United States); Snopok, P. [Fermi National Accelerator Lab. (FNAL), Batavia, IL (United States); IIT, Chicago, IL (United States); Rogers, C. [Science and Technology Facilities Council (STFC), Oxford (United Kingdom). Rutherford Appleton Lab. (RAL)

    2017-03-01

    Wedge absorbers are needed to obtain longitudinal cooling in ionization cooling. They also can be used to obtain emittance exchanges between longitudinal and transverse phase space. There can be large exchanges in emittance, even with single wedges. In the present note we explore the use of wedge absorbers in the MICE experiment to obtain transverse–longitudinal emittance exchanges within present and future operational conditions. The same wedge can be used to explore “direct” and “reverse” emittance exchange dynamics, where direct indicates a configuration that reduces momentum spread and reverse is a configuration that increases momentum spread. Analytical estimated and ICOOL and G4BeamLine simulations of the exchanges at MICE parameters are presented. Large exchanges can be obtained in both reverse and direct configurations.

  13. Absorbing Software Testing into the Scrum Method

    Science.gov (United States)

    Tuomikoski, Janne; Tervonen, Ilkka

    In this paper we study, how to absorb software testing into the Scrum method. We conducted the research as an action research during the years 2007-2008 with three iterations. The result showed that testing can and even should be absorbed to the Scrum method. The testing team was merged into the Scrum teams. The teams can now deliver better working software in a shorter time, because testing keeps track of the progress of the development. Also the team spirit is higher, because the Scrum team members are committed to the same goal. The biggest change from test manager’s point of view was the organized Product Owner Team. Test manager don’t have testing team anymore, and in the future all the testing tasks have to be assigned through the Product Backlog.

  14. Theory of metasurface based perfect absorbers

    Science.gov (United States)

    Alaee, Rasoul; Albooyeh, Mohammad; Rockstuhl, Carsten

    2017-12-01

    Based on an analytic approach, we present a theoretical review on the absorption, scattering, and extinction of both dipole scatterers and regular arrays composed of such scatterers i.e. metasurfaces. Besides offering a tutorial by outlining the maximum absorption limit for electrically/magnetically resonant dipole particles/metasurfaces, we give an educative analytical approach to their analysis. Moreover, we put forward the analysis of two known alternatives in providing perfect absorbers out of electrically and or magnetically resonant metasurfaces; one is based on the simultaneous presence of both electric and magnetic responses in so called Huygens metasurfaces while the other is established upon the presence of a back reflector in so called Salisbury absorbers. Our work is supported by several numerical examples to clarify the discussions in each stage.

  15. Disposable Diaper Absorbency: Improvements via Advanced Designs.

    Science.gov (United States)

    Helmes, C Tucker; O'Connor, Robert; Sawyer, Larry; Young, Sharon

    2014-08-01

    Absorbency effectiveness in diapers has improved significantly in recent years with the advent of new ingredient combinations and advanced design features. With these features, many leading products maintain their dryness performance overnight. Considering the importance of holding liquid away from the skin, ongoing research in diaper construction focuses on strategies to increase the effectiveness to capture liquid and help avoid rewetting of infant skin. The layout and design of a disposable diaper allows for distribution of absorbency features where they can provide the optimal benefit. Clinical evidence indicates materials can keep moisture away from the skin in the diapered area, helping maintain proper skin hydration, minimizing irritation, and contributing to reduced rates of diaper rash. © The Author(s) 2014.

  16. Fluorescence of dyes in solutions with high absorbance. Inner filter effect correction.

    Science.gov (United States)

    Fonin, Alexander V; Sulatskaya, Anna I; Kuznetsova, Irina M; Turoverov, Konstantin K

    2014-01-01

    Fluorescence is a proven tool in all fields of knowledge, including biology and medicine. A significant obstacle in its use is the nonlinearity of the dependence of the fluorescence intensity on fluorophore concentration that is caused by the so-called primary inner filter effect. The existing methods for correcting the fluorescence intensity are hard to implement in practice; thus, it is generally considered best to use dilute solutions. We showed that correction must be performed always. Furthermore, high-concentration solutions (high absorbance) are inherent condition in studying of the photophysical properties of fluorescent dyes and the functionally significant interactions of biological macromolecules. We proposed an easy to use method to correct the experimentally recorded total fluorescence intensity and showed that informative component of fluorescence intensity numerically equals to the product of the absorbance and the fluorescence quantum yield of the object. It is shown that if dye molecules do not interact with each other and there is no reabsorption (as for NATA) and spectrofluorimeter provides the proportionality of the detected fluorescence intensity to the part of the absorbed light (that is possible for spectrofluorimeter with horizontal slits) then the dependence of experimentally detected total fluorescence intensity of the dye on its absorbance coincides with the calculated dependence and the correction factor for eliminating the primary inner filter effect can be calculated on the basis of solution absorbance. It was experimentally shown for NATA fluorescence in the wide range of absorbance (at least up to 60). For ATTO-425, which fluorescence and absorption spectra overlap, the elimination of the primary and secondary filter effects and additional spectral analysis allow to conclude that the most probable reason of the deviation of experimentally detected fluorescence intensity dependence on solution absorbance from the calculated dependence

  17. Perfectly Reflectionless Omnidirectional Absorbers and Electromagnetic Horizons

    OpenAIRE

    Sainath, Kamalesh; Teixeira, Fernando L.

    2014-01-01

    We demonstrate the existence of metamaterial blueprints describing, and fundamental limitations concerning, perfectly reflectionless omnidirectional electromagnetic absorbers (PR-OEMA). Previous attempts to define PR-OEMA blueprints have led to active (gain), rather than passive, media. We explain this fact and unveil new, distinct limitations of true PR-OEMA devices, including the appearance of an "electromagnetic horizon" on physical solutions. As practical alternatives we introduce alterna...

  18. 2D Saturable Absorbers for Fibre Lasers

    Directory of Open Access Journals (Sweden)

    Robert I. Woodward

    2015-11-01

    Full Text Available Two-dimensional (2D nanomaterials are an emergent and promising platform for future photonic and optoelectronic applications. Here, we review recent progress demonstrating the application of 2D nanomaterials as versatile, wideband saturable absorbers for Q-switching and mode-locking fibre lasers. We focus specifically on the family of few-layer transition metal dichalcogenides, including MoS2, MoSe2 and WS2.

  19. Profilometric and SEM analyses of composite surfaces after excess cement removal

    Directory of Open Access Journals (Sweden)

    Jevremović Danimir P.

    2012-01-01

    Full Text Available Composite cements are widely used in dentistry, due to their positive characteristics (bond strength, color, low solubility etc.. However, removal of the cement presents one of the drawbacks of their use, since incomplete removal might cause bacterial adhesion, gingival irritation and subsequent inflammation. The aim of this study was to investigate surface characteristics of the composite cements after different ways of excess removal, by means of profilometric and SEM analysis. Thirty leucite reinforced ceramic specimens were divided into three groups, based on the manner of excess cement removal: Group 1 (polished: excess was fully polymerized for 40 s, then removed; Group 2 (cleaned: excess was removed with a cotton roll, after which cement was fully polymerized for 40 s; Group 3 (pre-polymerized: excess was light cured for 5 s, after which cement excess was broken with an instrument and then fully polymerized for 40 s. Surface roughness was measured using a surface profilometer. Subsequently, specimens were inspected by a scanning electron microscope. The data were statistically analyzed. The examination of variants of average values proved the statistically significant difference in the height of average values per group, p<0.0001; the statistically significantly highest values were for the pre-polymerized group, whereas the statistically significantly lowest values were for the polished group. Results of this study show that utmost attention has to be paid to the excess removal procedure, since surface roughness parameters directly depend on the choice of the applied technique.

  20. 34 CFR 300.16 - Excess costs.

    Science.gov (United States)

    2010-07-01

    ... 34 Education 2 2010-07-01 2010-07-01 false Excess costs. 300.16 Section 300.16 Education Regulations of the Offices of the Department of Education (Continued) OFFICE OF SPECIAL EDUCATION AND REHABILITATIVE SERVICES, DEPARTMENT OF EDUCATION ASSISTANCE TO STATES FOR THE EDUCATION OF CHILDREN WITH...

  1. Excessive Positivism in Person-Centered Planning

    Science.gov (United States)

    Holburn, Steve; Cea, Christine D.

    2007-01-01

    This paper illustrates the positivistic nature of person-centered planning (PCP) that is evident in the planning methods employed, the way that individuals with disabilities are described, and in portrayal of the outcomes of PCP. However, a confluence of factors can lead to manifestation of excessive positivism that does not serve PCP…

  2. Excessive daytime sleepiness, nocturnal sleep duration and ...

    African Journals Online (AJOL)

    Background and objectives. Short nocturnal sleep duration resulting in sleep debt may be a cause of excessive daytime sleepiness (EDS). Severity of depression (psychopathology) has been found to be directly related to EDS. There is an association between sleep duration and mental health, so there may therefore be an ...

  3. Surface temperature excess in heterogeneous catalysis

    NARCIS (Netherlands)

    Zhu, L.

    2005-01-01

    In this dissertation we study the surface temperature excess in heterogeneous catalysis. For heterogeneous reactions, such as gas-solid catalytic reactions, the reactions take place at the interfaces between the two phases: the gas and the solid catalyst. Large amount of reaction heats are released

  4. Origin of excess 176Hf in meteorites

    DEFF Research Database (Denmark)

    Thrane, Kristine; Connelly, James; Bizzarro, Martin

    2010-01-01

    with Lu/Hf elemental ratios in meteorites older than similar to 4.56 Ga meteorites unresolved. We attribute (176)Hf excess in older meteorites to an accelerated decay of (176)Lu caused by excitation of the long-lived (176)Lu ground state to a short-lived (176m)Lu isomer. The energy needed to cause...

  5. Excessive nitrogen and phosphorus in European rivers

    NARCIS (Netherlands)

    Blaas, Harry; Kroeze, Carolien

    2016-01-01

    Rivers export nutrients to coastal waters. Excess nutrient export may result in harmful algal blooms and hypoxia, affecting biodiversity, fisheries, and recreation. The purpose of this study is to quantify for European rivers (1) the extent to which N and P loads exceed levels that minimize the

  6. Excessive infant crying : definitions determine risk groups

    NARCIS (Netherlands)

    Reijneveld, SA; Brugman, E; Hirasing, RA

    We assessed risk groups for excessive infant crying using 10 published definitions, in 3179 children aged 1-6 months (response: 96.5%). Risk groups regarding parental employment, living area, lifestyle, and obstetric history varied by definition. This may explain the existence of conflicting

  7. Low excess air operations of oil boilers

    Energy Technology Data Exchange (ETDEWEB)

    Butcher, T.A.; Celebi, Y.; Litzke, Wai Lin [Brookhaven National Labs., Upton, NY (United States)

    1997-09-01

    To quantify the benefits which operation at very low excess air operation may have on heat exchanger fouling BNL has recently started a test project. The test allows simultaneous measurement of fouling rate, flue gas filterable soot, flue gas sulfuric acid content, and flue gas sulfur dioxide.

  8. Effects of Absorber Emissivity on Thermal Performance of a Solar Cavity Receiver

    Directory of Open Access Journals (Sweden)

    Jiabin Fang

    2014-01-01

    Full Text Available Solar cavity receiver is a key component to realize the light-heat conversion in tower-type solar power system. It usually has an aperture for concentrated sunlight coming in, and the heat loss is unavoidable because of this aperture. Generally, in order to improve the thermal efficiency, a layer of coating having high absorptivity for sunlight would be covered on the surface of the absorber tubes inside the cavity receiver. As a result, it is necessary to investigate the effects of the emissivity of absorber tubes on the thermal performance of the receiver. In the present work, the thermal performances of the receiver with different absorber emissivity were numerically simulated. The results showed that the thermal efficiency increases and the total heat loss decreases with increasing emissivity of absorber tubes. However, the thermal efficiency increases by only 1.6% when the emissivity of tubes varies from 0.2 to 0.8. Therefore, the change of absorber emissivity has slight effect on the thermal performance of the receiver. The reason for variation tendency of performance curves was also carefully analyzed. It was found that the temperature reduction of the cavity walls causes the decrease of the radiative heat loss and the convective heat loss.

  9. Absorbance of retinal oil droplets of the budgerigar: sex, spatial and plumage morph-related variation.

    Science.gov (United States)

    Knott, Ben; Bowmaker, James K; Berg, Mathew L; Bennett, Andrew T D

    2012-01-01

    Intraspecific variation in photoreceptor physiology is known in several vertebrate taxa, but is currently unknown in birds, despite many avian traits varying intraspecifically, and avian visual ecology encompassing a wide range of environments and visual stimuli, which might influence spectral sensitivity. Avian retinal photoreceptors contain light absorbing carotenoid-rich oil droplets that affect vision. Carotenoids are also important plumage components. However, our understanding of the regulation of carotenoids in oil droplets remains rudimentary. Among birds, Melopsittacus undulatus has probably the best-studied colour vision, shows profound intraspecific variation in plumage colour, and increased plasma carotenoids during moult. We used microspectrophotometry to determine whether a relationship exists between oil droplet carotenoid concentration and plumage pigmentation, and tested for sex and spatial variation in droplet absorbance across the retina. Absorbance of one variety of P-type droplets was higher in males. No relationship was found between droplet absorbance and plumage colour. We found a spatial pattern of droplets absorbance across the retina that matched a pattern found in another parrot, and other avian species. Our work provides insights into the development and maintenance of retinal oil droplets and suggests a common mechanism and function for carotenoid deposition in the retina across bird species.

  10. Mechanisms to absorb load in amputee running.

    Science.gov (United States)

    Strike, Siobhan C; Wickett, Oliver; Schoeman, Marlene; Diss, Ceri E

    2012-09-01

    We aimed to determine if a shock absorbing pylon (SAP) influenced the ground reaction force characteristics and the shock absorbing mechanisms compared to a rigid pylon (Rigid) during the loading phase in running. To determine if the SAP influences the mechanisms of loading compared to the Rigid condition. A convenience sample of transtibial amputees participated in a laboratory-based study. The prosthetic set-up was randomly altered fd\\sdsd. Five recreationally active male transtibial amputees age: 18-50 years; mean mass: 86.7 ± 17.5 kg; height: 1.77 ± 0.07 m) volunteered from a population-based sample. They completed a within-participant-designed study assessing a SAP and a Rigid condition during running. Kinematic and kinetic data were collected during two sessions following a one-week customization period. Loading rate, peak vertical and horizontal ground reaction forces and the time to each measure along with knee and hip angular displacement, absorbing powers and work done between the SAP and Rigid conditions were not systematically affected by the prosthetic condition. The effect of the SAP was minimal and inconsistent in the loading phase, with only some amputees presenting higher and others with lower values for the tested variables.

  11. Photosystem II cycle activity and alternative electron transport in the diatom Phaeodactylum tricornutum under dynamic light conditions and nitrogen limitation.

    Science.gov (United States)

    Wagner, Heiko; Jakob, Torsten; Lavaud, Johann; Wilhelm, Christian

    2016-05-01

    Alternative electron sinks are an important regulatory mechanism to dissipate excessively absorbed light energy particularly under fast changing dynamic light conditions. In diatoms, the cyclic electron transport (CET) around Photosystem II (PS II) is an alternative electron transport pathway (AET) that contributes to avoidance of overexcitation under high light illumination. The combination of nitrogen limitation and high-intensity irradiance regularly occurs under natural conditions and is expected to force the imbalance between light absorption and the metabolic use of light energy. The present study demonstrates that under N limitation, the amount of AET and the activity of CETPSII in the diatom Phaeodactylum tricornutum were increased. Thereby, the activity of CETPSII was linearly correlated with the amount of AET rates. It is concluded that CETPSII significantly contributes to AET in P. tricornutum. Surprisingly, CETPSII was found to be activated already at the end of the dark period under N-limited conditions. This coincided with a significantly increased degree of reduction of the plastoquinone (PQ) pool. The analysis of the macromolecular composition of cells of P. tricornutum under N-limited conditions revealed a carbon allocation in favor of carbohydrates during the light period and their degradation during the dark phase. A possible linkage between the activity of CETPSII and degree of reduction of the PQ pool on the one side and the macromolecular changes on the other is discussed.

  12. SEM, EDS, PL and absorbance study of CdTe thin films grown by CSS method

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez-Torres, M.E.; Silva-Gonzalez, R.; Gracia-Jimenez, J.M. [Instituto de Fisica, BUAP, Apdo. Postal J-48, San Manuel, 72570 Puebla, Pue. (Mexico); Casarrubias-Segura, G. [CIE- UNAM, 62580 Temixco, Morelos (Mexico)

    2006-09-22

    Oxygen-doped CdTe films were grown on conducting glass substrates by the close spaced sublimation (CSS) method and characterized using SEM, EDS, photoluminescence (PL) and absorbance. A significant change in the polycrystalline morphology is observed when the oxygen proportion is increased in the deposition atmosphere. The EDS analysis showed that all samples are nonstoichiometric with excess Te. The PL spectra show emission bands associated with Te vacancies (V{sub Te}), whose intensities decrease as the oxygen proportion in the CSS chamber is increased. The oxygen impurities occupy Te vacancies and modify the surfaces states, improving the nonradiative process. (author)

  13. Reuse of the Reflective Light and the Recycle Heat Energy in Concentrated Photovoltaic System

    Directory of Open Access Journals (Sweden)

    Hsin-Chien Chen

    2013-01-01

    Full Text Available A complex solar unit with microcrystalline silicon solar cells placed around the centered GaAs triple junction solar cell has been proposed and carried out. With the same illumination area and intensity, the total resultant power shows that the excess microcrystalline silicon solar cells increase the total output power by 13.2% by absorbing the reflective light from the surface of optical collimators. Furthermore, reusing the residual heat energy generated from the above-mentioned mechanism helps to increase the output power by around 14.1%. This mechanism provides a simple method to enhance the utility rate of concentrated photovoltaic (CPV system. Such concept can be further applied to the aerospace industry and the development of more efficient CPV solar energy applications.

  14. A novel wideband optical absorber based on all-metal 2D gradient nanostructures

    Science.gov (United States)

    Gong, Jianhao; Yang, Fulong; Zhang, Xiaoping

    2017-11-01

    Recently, all-metal nanostructures for perfect absorption of light have attracted much attention due to their excellent plasmonic and photonic properties, but only narrow absorption bands were obtained in previous studies. In this paper, a new kind of metallic metasurface with wideband absorption of visible light is designed, which consists only of a gold nanotriangle array on the opaque metal substrate. By combining different resonant modes in the gradual-changed triangular nanostructure, the wide absorption waveband in visible region from 378 to 626 nm is achieved with more than 90% absorptivity. We demonstrate that the absorption property of the nanostructure can be controlled by tuning the cell size and incident angle. In addition, a metallic trapezoidal grating structure is proposed which can also realize wideband light absorption. This research provides a novel strategy in designing wideband metamaterial absorbers for visible light based on all-metal nanostructures which have great potential applications in light energy harvesting and photoelectric conversion.

  15. A universal design to realize a tunable perfect absorber from infrared to microwaves

    Science.gov (United States)

    Smaali, Rafik; Omeis, Fatima; Moreau, Antoine; Taliercio, Thierry; Centeno, Emmanuel

    2016-09-01

    We propose a design for an universal absorber, characterized by a resonance frequency that can be tuned from visible to microwave frequencies independently of the choice of the metal and the dielectrics involved. An almost perfect absorption up to 99.8% is demonstrated at resonance for all polarization states of light and for a very wide angular aperture. These properties originate from a magnetic Fabry-Perot mode that is confined in a dielectric spacer of λ/100 thickness by a metamaterial layer and a mirror. An extraordinary large funneling through nano-slits explains how light can be trapped in the structure. Simple scaling laws can be used as a recipe to design ultra-thin perfect absorbers whatever the materials and the desired resonance wavelength, making our design truly universal.

  16. A universal design to realize a tunable perfect absorber from infrared to microwaves.

    Science.gov (United States)

    Smaali, Rafik; Omeis, Fatima; Moreau, Antoine; Taliercio, Thierry; Centeno, Emmanuel

    2016-09-07

    We propose a design for an universal absorber, characterized by a resonance frequency that can be tuned from visible to microwave frequencies independently of the choice of the metal and the dielectrics involved. An almost perfect absorption up to 99.8% is demonstrated at resonance for all polarization states of light and for a very wide angular aperture. These properties originate from a magnetic Fabry-Perot mode that is confined in a dielectric spacer of λ/100 thickness by a metamaterial layer and a mirror. An extraordinary large funneling through nano-slits explains how light can be trapped in the structure. Simple scaling laws can be used as a recipe to design ultra-thin perfect absorbers whatever the materials and the desired resonance wavelength, making our design truly universal.

  17. Laser post-processing of halide perovskites for enhanced photoluminescence and absorbance

    Science.gov (United States)

    Tiguntseva, E. Y.; Saraeva, I. N.; Kudryashov, S. I.; Ushakova, E. V.; Komissarenko, F. E.; Ishteev, A. R.; Tsypkin, A. N.; Haroldson, R.; Milichko, V. A.; Zuev, D. A.; Makarov, S. V.; Zakhidov, A. A.

    2017-11-01

    Hybrid halide perovskites have emerged as one of the most promising type of materials for thin-film photovoltaic and light-emitting devices. Further boosting their performance is critically important for commercialization. Here we use femtosecond laser for post-processing of organo-metalic perovskite (MAPbI3) films. The high throughput laser approaches include both ablative silicon nanoparticles integration and laser-induced annealing. By using these techniques, we achieve strong enhancement of photoluminescence as well as useful light absorption. As a result, we observed experimentally 10-fold enhancement of absorbance in a perovskite layer with the silicon nanoparticles. Direct laser annealing allows for increasing of photoluminescence over 130%, and increase absorbance over 300% in near-IR range. We believe that the developed approaches pave the way to novel scalable and highly effective designs of perovskite based devices.

  18. Radiation absorbed dose during special extra-oral radiography

    Science.gov (United States)

    Farag, Hamed I.; Abdel Latif, Zeinab A. S.; Hamed, Abdel Fattah A.

    1996-05-01

    The absorbed dose from radiographic examinations of adult patients using extra-oral dental radiography as lateral-oblique and postero-anterior views was examined. The absorbed dose at various sites in the head and neck was measured with thermoluminescent dosimeters (TLD). The maximum absorbed dose for both radiographic views is located at the point of entry. The absorbed doses in the various sites are compared and discussed in both techniques.

  19. Research of the dynamics of a magnetic fluid dynamic absorber

    Energy Technology Data Exchange (ETDEWEB)

    Bashtovoi, V.G. E-mail: bashv@reol1.itmo.by; Kabachnikov, D.N.; Kolobov, A.Y.; Samoylov, V.B.; Vikoulenkov, A.V

    2002-11-01

    A new type of shock absorber using a magnetic fluid drop with the permanent magnet inside as a working element is investigated in this paper. Movement of the working element inside the body of the absorber under the influence of external oscillatory inertia forces leads to a viscous dissipation of the oscillating system energy. A theoretical model and some characteristics of the absorber are presented. This type of dynamic absorber is used nowadays in spacecraft technology.

  20. Multilayered wideband absorbers for oblique angle of incidence

    OpenAIRE

    Kazemzadeh, Alireza; Karlsson, Anders

    2010-01-01

    Design procedures of Jaumann and circuit analog absorbers are mostly formulated for normal angle of incidence. Only a few design methods considering oblique angle of incidence are published. The published methods are restricted to single resistive layer circuit analog absorbers or multilayered Jaumann absorbers with low permittivity spacers. General design procedures are developed in this paper for multilayered Jaumann and capacitive circuit absorbers. By expanding the scan and frequency comp...

  1. Spectroscopic Classification of IR-Excess IRAS Sources

    Science.gov (United States)

    Willenbrink, Kathryn A.; Hrivnak, Bruce; Volk, Kevin; Su, Kate Y. L.

    2018-01-01

    We have carried out classification spectroscopy (R~2000) of a sample of about 100 IRAS sources with excess flux at 20 microns. These were obtained with the KPNO 2.1 m and the Steward Observatory 2.3 m telescopes. Our main interest is the identification or confirmation of post-AGB objects. A number of them are indeed post-AGB, including proto-planetary nebulae. These range from K to B types, with the later showing hydrogen emission and in some cases other emission lines. Others appear to be M giants or main sequence stars, plus a couple of pre-main sequence stars. Some of the sample have previous classifications, which we list for comparison. The post-AGB stars are being monitored for light variability. This research has been supported by the NSF (most recently AST-1413660).

  2. Average [O II]nebular emission associated with Mg II absorbers: Dependence on Fe II absorption

    Science.gov (United States)

    Joshi, Ravi; Srianand, Raghunathan; Petitjean, Patrick; Noterdaeme, Pasquier

    2018-01-01

    We investigate the effect of Fe II equivalent width (W2600) and fibre size on the average luminosity of [O II]λλ3727,3729 nebular emission associated with Mg II absorbers (at 0.55 ≤ z ≤ 1.3) in the composite spectra of quasars obtained with 3 and 2 arcsec fibres in the Sloan Digital Sky Survey. We confirm the presence of strong correlations between [O II] luminosity (L_{[O II]}) and equivalent width (W2796) and redshift of Mg II absorbers. However, we show L_{[O II]} and average luminosity surface density suffers from fibre size effects. More importantly, for a given fibre size the average L_{[O II]} strongly depends on the equivalent width of Fe II absorption lines and found to be higher for Mg II absorbers with R ≡W2600/W2796 ≥0.5. In fact, we show the observed strong correlations of L_{[O II]} with W2796 and z of Mg II absorbers are mainly driven by such systems. Direct [O II] detections also confirm the link between L_{[O II]} and R. Therefore, one has to pay attention to the fibre losses and dependence of redshift evolution of Mg II absorbers on W2600 before using them as a luminosity unbiased probe of global star formation rate density. We show that the [O II] nebular emission detected in the stacked spectrum is not dominated by few direct detections (i.e., detections ≥3σ significant level). On an average the systems with R ≥0.5 and W2796 ≥2Å are more reddened, showing colour excess E(B - V) ˜ 0.02, with respect to the systems with R <0.5 and most likely traces the high H I column density systems.

  3. Light Converting Inorganic Phosphors for White Light-Emitting Diodes

    Directory of Open Access Journals (Sweden)

    Chiao-Wen Yeh

    2010-03-01

    Full Text Available White light-emitting diodes (WLEDs have matched the emission efficiency of florescent lights and will rapidly spread as light source for homes and offices in the next 5 to 10 years. WLEDs provide a light element having a semiconductor light emitting layer (blue or near-ultraviolet (nUV LEDs and photoluminescence phosphors. These solid-state LED lamps, rather than organic light emitting diode (OLED or polymer light-emitting diode (PLED, have a number of advantages over conventional incandescent bulbs and halogen lamps, such as high efficiency to convert electrical energy into light, reliability and long operating lifetime. To meet with the further requirement of high color rendering index, warm light with low color temperature, high thermal stability and higher energy efficiency for WLEDs, new phosphors that can absorb excitation energy from blue or nUV LEDs and generate visible emissions efficiently are desired. The criteria of choosing the best phosphors, for blue (450-480 nm and nUV (380-400 nm LEDs, strongly depends on the absorption and emission of the phosphors. Moreover, the balance of light between the emission from blue-nUV LEDs and the emissions from phosphors (such as yellow from Y3Al5O12:Ce3+ is important to obtain white light with proper color rendering index and color temperature. Here, we will review the status of phosphors for LEDs and prospect the future development.

  4. 21 CFR 886.3300 - Absorbable implant (scleral buckling method).

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Absorbable implant (scleral buckling method). 886... SERVICES (CONTINUED) MEDICAL DEVICES OPHTHALMIC DEVICES Prosthetic Devices § 886.3300 Absorbable implant (scleral buckling method). (a) Identification. An absorbable implant (scleral buckling method) is a device...

  5. 21 CFR 878.4840 - Absorbable polydioxanone surgical suture.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Absorbable polydioxanone surgical suture. 878.4840... polydioxanone surgical suture. (a) Identification. An absorbable polydioxanone surgical suture is an absorbable... for the device is FDA's “Class II Special Controls Guidance Document: Surgical Sutures; Guidance for...

  6. Graphene metamaterials based tunable terahertz absorber: effective surface conductivity approach.

    Science.gov (United States)

    Andryieuski, Andrei; Lavrinenko, Andrei V

    2013-04-08

    In this paper we present the efficient design of functional thin-film metamaterial devices with the effective surface conductivity approach. As an example, we demonstrate a graphene based perfect absorber. After formulating the requirements to the perfect absorber in terms of surface conductivity we investigate the properties of graphene wire medium and graphene fishnet metamaterials and demonstrate both narrowband and broadband tunable absorbers.

  7. Graphene metamaterials based tunable terahertz absorber: effective surface conductivity approach

    DEFF Research Database (Denmark)

    Andryieuski, Andrei; Lavrinenko, Andrei

    2013-01-01

    In this paper we present the efficient design of functional thin-film metamaterial devices with the effective surface conductivity approach. As an example, we demonstrate a graphene based perfect absorber. After formulating the requirements to the perfect absorber in terms of surface conductivity...... we investigate the properties of graphene wire medium and graphene fishnet metamaterials and demonstrate both narrowband and broadband tunable absorbers....

  8. Personalized Recommendation via Suppressing Excessive Diffusion

    Directory of Open Access Journals (Sweden)

    Guilin Chen

    2017-01-01

    Full Text Available Efficient recommendation algorithms are fundamental to solve the problem of information overload in modern society. In physical dynamics, mass diffusion is a powerful tool to alleviate the long-standing problems of recommendation systems. However, popularity bias and redundant similarity have not been adequately studied in the literature, which are essentially caused by excessive diffusion and will lead to similarity estimation deviation and recommendation performance degradation. In this paper, we penalize the popular objects by appropriately dividing the popularity of objects and then leverage the second-order similarity to suppress excessive diffusion. Evaluation on three real benchmark datasets (MovieLens, Amazon, and RYM by 10-fold cross-validation demonstrates that our method outperforms the mainstream baselines in accuracy, diversity, and novelty.

  9. ILLUSION OF EXCESSIVE CONSUMPTION AND ITS EFFECTS

    Directory of Open Access Journals (Sweden)

    MUNGIU-PUPĂZAN MARIANA CLAUDIA

    2015-12-01

    Full Text Available The aim is to explore, explain and describe this phenomenon to a better understanding of it and also the relationship between advertising and the consumer society members. This paper aims to present an analysis of excessive and unsustainable consumption, the evolution of a phenomenon, and the ability to find a way to combat. Unfortunately, studies show that this tendency to accumulate more than we need to consume excess means that almost all civilizations fined and placed dogmatic among the values that children learn early in life. This has been perpetuated since the time when the goods or products does not get so easy as today. Anti-consumerism has emerged in response to this economic system, not on the long term. We are witnessing the last two decades to establish a new phase of consumer capitalism: society hiperconsumtion.

  10. Conservative treatment of excessive anterior pelvic tilt

    DEFF Research Database (Denmark)

    Brekke, Anders Falk

    , DK-5000 Odense C, Denmark ABSTRACT (1795 anslag) Background: Excessive anterior pelvic tilt has been linked to pain and dysfunction of the hip and pelvic region. Conservative treatment (e.g. manual therapy and physical training) is suggested in correcting the tilt and eventually related symptoms...... demonstrated a significant reduction in anterior pelvic tilt. The two studies intervening on symptomatic subjects demonstrated a significant reduction in pain and disability, respectively. Conclusions: Very low quality of evidence suggests that further studies are needed to clarify whether conservative......Conservative treatment of excessive anterior pelvic tilt: A systematic review Anders Falk Brekke1,2,3, Søren Overgaard1,2, Asbjørn Hróbjartsson4, Anders Holsgaard-Larsen1,2 1Orthopaedic Research Unit, Department of Orthopaedic Surgery and Traumatology, Odense University Hospital 2Department...

  11. Neurological manifestations of excessive alcohol consumption.

    Science.gov (United States)

    Planas-Ballvé, Anna; Grau-López, Laia; Morillas, Rosa María; Planas, Ramón

    2017-12-01

    This article reviews the different acute and chronic neurological manifestations of excessive alcohol consumption that affect the central or peripheral nervous system. Several mechanisms can be implicated depending on the disorder, ranging from nutritional factors, alcohol-related toxicity, metabolic changes and immune-mediated mechanisms. Recognition and early treatment of these manifestations is essential given their association with high morbidity and significantly increased mortality. Copyright © 2017 Elsevier España, S.L.U., AEEH y AEG. All rights reserved.

  12. Tendon rupture associated with excessive smartphone gaming.

    Science.gov (United States)

    Gilman, Luke; Cage, Dori N; Horn, Adam; Bishop, Frank; Klam, Warren P; Doan, Andrew P

    2015-06-01

    Excessive use of smartphones has been associated with injuries. A 29-year-old, right hand-dominant man presented with chronic left thumb pain and loss of active motion from playing a Match-3 puzzle video game on his smartphone all day for 6 to 8 weeks. On physical examination, the left extensor pollicis longus tendon was not palpable, and no tendon motion was noted with wrist tenodesis. The thumb metacarpophalangeal range of motion was 10° to 80°, and thumb interphalangeal range of motion was 30° to 70°. The clinical diagnosis was rupture of the left extensor pollicis longus tendon. The patient subsequently underwent an extensor indicis proprius (1 of 2 tendons that extend the index finger) to extensor pollicis longus tendon transfer. During surgery, rupture of the extensor pollicis longus tendon was seen between the metacarpophalangeal and wrist joints. The potential for video games to reduce pain perception raises clinical and social considerations about excessive use, abuse, and addiction. Future research should consider whether pain reduction is a reason some individuals play video games excessively, manifest addiction, or sustain injuries associated with video gaming.

  13. [Mortality attributable to excess weight in Spain].

    Science.gov (United States)

    Martín-Ramiro, José Javier; Álvarez-Martín, Elena; Gil-Prieto, Ruth

    2014-06-16

    Estimate the mortality attributable to higher than optimal body mass index in the Spanish population in 2006. Excess body weight prevalence data were obtained from the 2006 National Health Survey, while data on associated mortality were extracted from the National Statistic Institute. Population attributable fractions were applied and mortality attributable to higher than optimal body mass index was calculated for people between 35 and 79 years. In 2006, among the Spanish population aged 35-79 years, 25,671 lives (16,405 males and 9,266 women) were lost due to higher than optimal body mass index. Mortality attributable was 15.8% of total deaths in males and 14.8% in women, but if we refer to those causes where excess body weight is a risk factor, it is about a 30% of mortality (31.6% in men and 28% in women). The most important individual cause was cardiovascular disease (58%), followed by cancer. The individual cause with a major contribution to deaths was type 2 diabetes; nearly 70% in males and 80% in women. Overweight accounted for 54.9% deaths in men and 48.6% in women. Excess body weight is a major public health problem, with an important associated mortality. Attributable deaths are a useful tool to know the real situation and to monitor for disease control interventions. Copyright © 2013 Elsevier España, S.L. All rights reserved.

  14. Earnings Quality Measures and Excess Returns.

    Science.gov (United States)

    Perotti, Pietro; Wagenhofer, Alfred

    2014-06-01

    This paper examines how commonly used earnings quality measures fulfill a key objective of financial reporting, i.e., improving decision usefulness for investors. We propose a stock-price-based measure for assessing the quality of earnings quality measures. We predict that firms with higher earnings quality will be less mispriced than other firms. Mispricing is measured by the difference of the mean absolute excess returns of portfolios formed on high and low values of a measure. We examine persistence, predictability, two measures of smoothness, abnormal accruals, accruals quality, earnings response coefficient and value relevance. For a large sample of US non-financial firms over the period 1988-2007, we show that all measures except for smoothness are negatively associated with absolute excess returns, suggesting that smoothness is generally a favorable attribute of earnings. Accruals measures generate the largest spread in absolute excess returns, followed by smoothness and market-based measures. These results lend support to the widespread use of accruals measures as overall measures of earnings quality in the literature.

  15. Structure of Light-Harvesting Aggregates in Individual Chlorosomes

    NARCIS (Netherlands)

    Guenther, Lisa M.; Jendrny, Marc; Bloemsma, Erik A.; Tank, Marcus; Oostergetel, Gert T.; Bryant, Donald A.; Knoester, Jasper; Koehler, Juergen

    2016-01-01

    Among all photosynthetic organisms, green bacteria have evolved one of the most efficient light-harvesting antenna, the chlorosome, that contains hundreds of thousands of bacteriochlorophyll molecules, allowing these bacteria to grow photosynthetically by absorbing only a few photons per

  16. Bond strength of resin composite to light activated bleached enamel

    African Journals Online (AJOL)

    2015-09-02

    , resin bonding, tooth bleaching. Date of Acceptance: ... The energy absorbed from the light accelerates the oxidation–reduction reaction.[12]. Bleaching treatment is frequently recommended before porcelain restorations or ...

  17. The diatom Phaeodactylum tricornutum adjusts nonphotochemical fluorescence quenching capacity in response to dynamic light via fine-tuned Lhcx and xanthophyll cycle pigment synthesis.

    Science.gov (United States)

    Lepetit, Bernard; Gélin, Gautier; Lepetit, Mariana; Sturm, Sabine; Vugrinec, Sascha; Rogato, Alessandra; Kroth, Peter G; Falciatore, Angela; Lavaud, Johann

    2017-04-01

    Diatoms contain a highly flexible capacity to dissipate excessively absorbed light by nonphotochemical fluorescence quenching (NPQ) based on the light-induced conversion of diadinoxanthin (Dd) into diatoxanthin (Dt) and the presence of Lhcx proteins. Their NPQ fine regulation on the molecular level upon a shift to dynamic light conditions is unknown. We investigated the regulation of Dd + Dt amount, Lhcx gene and protein synthesis and NPQ capacity in the diatom Phaeodactylum tricornutum after a change from continuous low light to 3 d of sine (SL) or fluctuating (FL) light conditions. Four P. tricornutum strains with different NPQ capacities due to different expression of Lhcx1 were included. All strains responded to dynamic light comparably, independently of initial NPQ capacity. During SL, NPQ capacity was strongly enhanced due to a gradual increase of Lhcx2 and Dd + Dt amount. During FL, cells enhanced their NPQ capacity on the first day due to increased Dd + Dt, Lhcx2 and Lhcx3; already by the second day light acclimation was accomplished. While quenching efficiency of Dt was strongly lowered during SL conditions, it remained high throughout the whole FL exposure. Our results highlight a more balanced and cost-effective photoacclimation strategy of P. tricornutum under FL than under SL conditions. © 2016 The Authors. New Phytologist © 2016 New Phytologist Trust.

  18. DHCAL with Minimal Absorber: Measurements with Positrons

    CERN Document Server

    Freund, B; Repond, J.; Schlereth, J.; Xia, L.; Dotti, A.; Grefe, C.; Ivantchenko, V.; Antequera, J.Berenguer; Calvo Alamillo, E.; Fouz, M.C.; Marin, J.; Puerta-Pelayo, J.; Verdugo, A.; Brianne, E.; Ebrahimi, A.; Gadow, K.; Göttlicher, P.; Günter, C.; Hartbrich, O.; Hermberg, B.; Irles, A.; Krivan, F.; Krüger, K.; Kvasnicka, J.; Lu, S.; Lutz, B.; Morgunov, V.; Provenza, A.; Reinecke, M.; Sefkow, F.; Schuwalow, S.; Tran, H.L.; Garutti, E.; Laurien, S.; Matysek, M.; Ramilli, M.; Schroeder, S.; Bilki, B.; Norbeck, E.; Northacker, D.; Onel, Y.; Cvach, J.; Gallus, P.; Havranek, M.; Janata, M.; Kovalcuk, M.; Kvasnicka, J.; Lednicky, D.; Marcisovsky, M.; Polak, I.; Popule, J.; Tomasek, L.; Tomasek, M.; Sicho, P.; Smolik, J.; Vrba, V.; Zalesak, J.; van Doren, B.; Wilson, G.W.; Kawagoe, K.; Hirai, H.; Sudo, Y.; Suehara, T.; Sumida, H.; Takada, S.; Tomita, T.; Yoshioka, T.; Bilokin, S.; Bonis, J.; Cornebise, P.; Pöschl, R.; Richard, F.; Thiebault, A.; Zerwas, D.; Hostachy, J.Y.; Morin, L.; Besson, D.; Chadeeva, M.; Danilov, M.; Markin, O.; Popova, E.; Gabriel, M.; Goecke, P.; Kiesling, C.; Kolk, N.van der; Simon, F.; Szalay, M.; Corriveau, F.; Blazey, G.C.; Dyshkant, A.; Francis, K.; Zutshi, V.; Kotera, K.; Ono, H.; Takeshita, T.; Ieki, S.; Kamiya, Y.; Ootani, W.; Shibata, N.; Jeans, D.; Komamiya, S.; Nakanishi, H.

    2016-01-01

    In special tests, the active layers of the CALICE Digital Hadron Calorimeter prototype, the DHCAL, were exposed to low energy particle beams, without being interleaved by absorber plates. The thickness of each layer corresponded approximately to 0.29 radiation lengths or 0.034 nuclear interaction lengths, defined mostly by the copper and steel skins of the detector cassettes. This paper reports on measurements performed with this device in the Fermilab test beam with positrons in the energy range of 1 to 10 GeV. The measurements are compared to simulations based on GEANT4 and a standalone program to emulate the detailed response of the active elements.

  19. Ultra-broadband microwave metamaterial absorber

    Science.gov (United States)

    Ding, Fei; Cui, Yanxia; Ge, Xiaochen; Jin, Yi; He, Sailing

    2012-03-01

    A microwave ultra-broadband polarization-independent metamaterial absorber is demonstrated. It is composed of a periodic array of metal-dielectric multilayered quadrangular frustum pyramids. These pyramids possess resonant absorption modes at multi-frequencies, of which the overlapping leads to the total absorption of the incident wave over an ultra-wide spectral band. The experimental absorption at normal incidence is above 90% in the frequency range of 7.8-14.7 GHz, and the absorption is kept large when the incident angle is smaller than 60°. The experimental results agree well with the numerical simulation.

  20. Loss of protons in thin absorbers

    CERN Document Server

    Renberg, P U; Measday, D F; Pepin, M; Serre, Claude; Schwaller, P

    1972-01-01

    Proton losses due to nuclear inelastic interactions have been measured in Al and Cu absorbers of thicknesses less than half the proton range, for incident proton energies of 250 and 560 MeV. It is shown that the data can be used to obtain absorption corrections in proton counter telescopes for other energies in this energy interval. The absorption correction would be found from the loss calculated from the proton reaction cross-sections by multiplying by an experimentally determined ratio which is given by the present measurement. (5 refs).