Optical properties, luminescence quenching mechanism and radiation hardness of Eu-doped GaN red powder phosphor

International Nuclear Information System (INIS)

Jadwisienczak, W.; Wisniewski, K.; Spencer, M.; Thomas, T.; Ingram, D.

2010-01-01

We report on the luminescence quenching mechanism of Eu-doped GaN powder phosphor produced with a low-cost, high yield rapid-ammonothermal method. We have studied as-synthesized and acid rinsed Eu-doped GaN powders with the Eu concentration of ∼0.5 at.%. The Eu-doped GaN photoluminescence (PL) was investigated with 325 nm excitation wavelength at hydrostatic pressures up to 7.7 GPa in temperature range between 12 K and 300 K. The room temperature integrated Eu 3+ ion PL intensity from acid rinsed material is a few times stronger than from the as-synthesized material. The temperature dependent PL studies revealed that the thermal quenching of the dominant Eu 3+ ion transition ( 5 D 0 → 7 F 2 ) at 622 nm is stronger in the chemically modified phosphor indicating more efficient coupling between the Eu 3+ ion and passivated GaN powder grains. Furthermore, it was found that thermal quenching of Eu 3+ ion emission intensity can be completely suppressed in studied materials by applied pressure. This is due to stronger localization of bound exciton on Eu 3+ ion trap induced by hydrostatic pressure. Furthermore, the effect of 2 MeV oxygen irradiation on the PL properties has been investigated for highly efficient Eu-doped GaN phosphor embedded in KBr-GaN:Eu 3+ composite. Fairly good radiation damage resistance was obtained for 1.7 x 10 12 to 5 x 10 13 cm -2 oxygen fluence. Preliminary data indicate that Eu-doped GaN powder phosphor can be considered for devices in a radiation environment.

Cooperation Mechanisms To Achieve Eu Renewable Targets

DEFF Research Database (Denmark)

Klinge Jacobsen, Henrik; Pade, Lise-Lotte; Schröder, Sascha Thorsten

2014-01-01

targets. Furthermore, countries might find themselves competing for investment in a market with limited capital available. In both cases, the cost-efficiency of the renewable support policies is reduced compared to a coordinated solution. Barriers for joint support such as network regulation regarding......There are considerable benefits from cooperating among member states on meeting the 2020 renewable energy sources (RES) targets. Today countries are supporting investments in renewable energy by many different types of support schemes and with different levels of support. The EU has opened...... for cooperation mechanisms such as joint support schemes for promoting renewable energy to meet the 2020 targets. The potential coordination benefits, with more efficient localisation and composition of renewable investment, can be achieved by creating new areas/sub-segments of renewable technologies where...

Charge compensation mechanisms in favor of the incorporation of the Eu3+ ion into the ZnO host lattice

Science.gov (United States)

Baira, M.; Bekhti-Siad, A.; Hebali, K.; Bouhani-Benziane, H.; Sahnoun, M.

2018-05-01

Eu3+ doped phosphors with charge compensation are potential candidates of red emitting phosphors for lamp applications. Charge compensation improves the luminescence performance of the material. The charge compensation can most probably be achieved by three possible mechanisms: (a) two Zn2+ ions are replaced by one Eu3+ ions and one monovalent cation, 2Zn2+ →Eu3++ Li+, where Li+ is acting as a charge compensator; (b) the charge compensation is provided by a zinc vacancy (VZn) defects, 3Zn2+ → 2Eu3++ VZn, the subscript Zn denotes an ion in a normal zinc site in the lattice; (c) two Zn2+ ions are replaced by one Eu3+ ions with the presence of interstitial oxygen (Oi), 2Zn2+ → 2Eu3++ Oi. Electronic structures of the crystals corresponding to the three models are evaluated by the first-principles quantum mechanical calculations based on the density functional theory. It is found that the charge compensator defects make Eu3+ doping in ZnO energetically more favorable. They break the local symmetry around the Eu3+ ion and lead to deep states below the empty upper band, the conduction band that could facilitate intra-4f shell transitions, which can obviously improve the emission intensity of Eu3+-doped ZnO. Therefore, the effect of these defects on the host crystals electronic band states relative to the Eu3+ states is reported, since both electron transfer and electronically energy transfer processes enhance the performance of optoelectronic devices based on this material. These theoretical insights are helpful for designing rare-earth doped oxide materials with high photoluminescence (PL) performance.

Mechanism of luminescent enhancement in Ba{sub 2}GdNbO{sub 6}:Eu{sup 3+} perovskite by Li{sup +} co-doping

Energy Technology Data Exchange (ETDEWEB)

Rezende, Marcos Vinicius dos Santos [Departamento de Física, Universidade Federal de Sergipe, 49500-000, Itabaiana, SE (Brazil); Valério, Mario Ernesto Giroldo [Departamento de Física, Universidade Federal de Sergipe, 49100-000 São Cristóvão, SE (Brazil); Mouta, Rodolpho; Diniz, Eduardo Moraes [Departamento de Física, CCET, Universidade Federal do Maranhão, 65085-580 São Luís, MA (Brazil); Paschoal, Carlos William de Araujo, E-mail: paschoal@ufma.br [Departamento de Física, CCET, Universidade Federal do Maranhão, 65085-580 São Luís, MA (Brazil); Department of Materials Science and Engineering, University of California Berkeley, 94720-1760 Berkeley, CA (United States); Department of Physics, University of California Berkeley, 94720-7300 Berkeley, CA (United States)

2015-02-15

We investigated the Li{sup +} ion incorporation in Ba{sub 2}GdNbO{sub 6}:Eu{sup 3+} perovskite by atomistic simulations based on energy minimization. We predicted the most probable sites occupied by Eu{sup 3+} and Li{sup +} ions and the related charge-compensation mechanisms involved into these substitutions. The results show that the Eu{sup 3+} and Li{sup +} ions are incorporated mainly at the Gd{sup 3+} site. In the Li{sup +} ion case, there is a charge compensation by Nb{sub Gd}{sup •} {sup •} antisite. The crystal field parameters and the transition levels for the Eu{sup 3+} ion in the BGN:Eu{sup 3+} were calculated with basis on the simulated local symmetry of the Eu{sup 3+} site. The results show that the mechanism of luminescent properties enhancement is the symmetry distortion induced by the Li{sup +} co-doping. - Highlights: • We performed a full defect calculations in Ba{sub 2}GdNbO{sub 6} double perovskite. • We modeled with excellent agreement the optical transition of Ba{sub 2}GdNbO{sub 6}:Eu{sup 3+} crystal. • We explained the mechanism of luminescent enhancement in Ba{sub 2}GdNbO{sub 6}:Eu{sup 3+} perovskite by Li{sup +} co-doping.

Transparency Under Scrutiny: Information Disclosure in Global Environmental Governance.

NARCIS (Netherlands)

Gupta, A.

2008-01-01

Although transparency is a key concept of our times, it remains a relatively understudied phenomenon in global environmental politics. The link between transparency and accountable, legitimate and effective governance is assumed, yet the nature and workings of this link require further scrutiny.

EU's lille sikkerhedsnet

DEFF Research Database (Denmark)

Rangvid, Jesper

2014-01-01

I forrige uge indgik EU-kommissionen og EU-Parlamentet en aftale om en fælles afviklingsmekanisme i bank-unionen (Single Resolution Mechanism; SRM). ... Så på trods af mere kapital, nye bail-in regler og afviklingsfonden tror jeg ikke, at det kan udelukkes, at fremtidige "bankredninger" kan...... nødvendigøre statslige midler. Hertil er fonden trods alt for begrænset. ... Proceduren er, at ECB indstiller til SRM's bestyrelse, at en bank skal afvikles, hvorefter EU-kommissionen og nationale tilsynsmyndigheder involveres....

EU Commission participation in the Troika mission: is there a European Union price to pay?

Directory of Open Access Journals (Sweden)

Antonio Goucha Soares

2015-06-01

Full Text Available The article is intended to debate two questions regarding the involvement of the Commission in the Troika's action: firstly, considering the nature of financial assistance programs, it aims to discuss the effect of the Commission's participation in Troika negotiations on the balance of power of the EU institutions; and secondly, the article raises the issue of the Commission's liability for the results achieved by the financial assistance program, taking into account the extent of the conditions imposed, as well as the intensity of scrutiny by the Troika.

Positive mood can increase or decrease message scrutiny: the hedonic contingency view of mood and message processing.

Science.gov (United States)

Wegener, D T; Petty, R E; Smith, S M

1995-07-01

Currently dominant explanations of mood effects on persuasive message processing (i.e., cognitive capacity and feelings as information) predict that happy moods lead to less message scrutiny than neutral or sad moods. The hedonic contingency view (D. T. Wegener & R. E. Petty, 1994) predicts that happy moods can sometimes be associated with greater message processing activity because people in a happy mood are more attentive than neutral or sad people to the hedonic consequences of their actions. Consistent with this view, Experiment 1 finds that a happy mood can lead to greater message scrutiny than a neutral mood when the message is not mood threatening. Experiment 2 finds that a happy mood leads to greater message scrutiny than a sad mood when an uplifting message is encountered, but to less message scrutiny when a depressing message is encountered.

The EU pledge for responsible marketing of food and beverages to children: implementation in food companies.

Science.gov (United States)

Jensen, J D; Ronit, K

2015-08-01

Increasing political pressure on the food industry's marketing activities stimulated the formation of the collective EU Pledge for responsible marketing of foods and beverages to children. The objective of the study is to evaluate the commitments made by companies in joining the pledge for the purpose of assessing its effectiveness in regulating signatory companies' marketing activities. Data on company commitments in relation to the EU Pledge were collected, analyzed and recalculated in order to enable comparison across companies and with general nutritional recommendations. Data on companies' product portfolio and market orientation were collected from their most recent available annual reports. Data on the companies' product profiles were generated via review of the companies' main websites. Similar data were generated for a reference group of companies outside the EU Pledge. Compared with a reference group of large food and beverage companies, EU Pledge signatory companies have a public image strongly based on products with appeal to children. The EU Pledge sets common standards for regulating signatory companies' marketing behaviour towards children. Further scrutiny of the companies' stated commitments revealed considerable variation in their actual content and in their de facto bindingness on the companies' marketing behavior--for example, in the definition of target audience for advertising or in nutritional characteristics making products eligible for advertising to children. In order for voluntary self-regulation schemes such as the EU Pledge to be a credible alternative to public regulation of marketing behaviour, more transparency and stringency are needed.

EU Law and Mass Internet Metadata Surveillance in the Post-Snowden Era

Directory of Open Access Journals (Sweden)

Nora Ni Loideain

2015-09-01

Full Text Available Legal frameworks exist within democracies to prevent the misuse and abuse of personal data that law enforcement authorities obtain from private communication service providers. The fundamental rights to respect for private life and the protection of personal data underpin this framework within the European Union. Accordingly, the protection of the principles and safeguards required by these rights is key to ensuring that the oversight of State surveillance powers is robust and transparent. Furthermore, without the robust scrutiny of independent judicial review, the principles and safeguards guaranteed by these rights may become more illusory than real. Following the Edward Snowden revelations, major concerns have been raised worldwide regarding the legality, necessity and proportionality standards governing these laws. In 2014, the highest court in the EU struck down the legal framework that imposed a mandatory duty on communication service providers to undertake the mass retention of metadata for secret intelligence and law enforcement authorities across the EU. This article considers the influence of the Snowden revelations on this landmark judgment. Subsequently, the analysis explores the significance of this ruling for the future reform of EU law governing metadata surveillance and its contribution to the worldwide debate on indiscriminate and covert monitoring in the post-Snowden era.

Fossil fuel subsidies and the new EU Climate and Energy Governance Mechanism

International Nuclear Information System (INIS)

Sartor, Oliver; Spencer, Thomas

2016-07-01

There is currently no dedicated process to track the extent of fossil fuel subsidies, nor to ensure that Member States phase them out. This situation is inconsistent with the European Union's stated decarbonization and energy efficiency dimensions under the Energy Union. The EU is therefore in need of an alternative process for tracking and ensuring the phase-out of fossil fuel subsidies by the Member States. The new Energy Union governance mechanism presents an opportunity for creating this alternative. Providing the right price signals is essential part of the policy mix that is needed to achieve Europe's climate policy goals. Phasing out fossil fuel subsidies in the EU is an important part of aligning energy prices with the EU's climate and energy goals. Depending on how they are measured, combined fossil fuel subsidies in the EU range from 39 to over euro 200 billion per annum (European Commission, 2014). They therefore constitute a significant source of incoherence between the EU's climate mitigation and fiscal policies for energy. However, there has recently been mixed progress in addressing fossil fuel subsidies in Europe. For instance, under the Europe 2020 Strategy, Member States had committed to begin developing plans for phasing out fossil fuel subsidies by 2020. Progress on implementing these plans was supposed to be monitored under the European Semester. However, the decision was taken to remove the focus on energy and fossil fuel subsidies from the European Semester in 2015. As yet, no new system for governing the phase-out of fossil fuel subsidies has been advanced, leaving the question of fossil fuel subsidy reform in limbo. The advent of the EU's Energy Union project creates an opportunity for putting the phase-out of fossil fuel subsidies back on track in Europe. This could be done by including requirements for national goal setting on specific kinds of fossil fuel subsidies in a dedicated sub-section of the National Climate and Energy Plans

Unpacking the mechanisms of the EU ‘throughput’ governance legitimacy

DEFF Research Database (Denmark)

Chatzopoulou, Sevasti

2015-01-01

The proliferation of EU agencies, referred to as agencification phenomenon, constitutes a significant EU institutional innovation. Agencification aimed to provide information, promote efficiency, decrease politicization and generate standards based on specialised technical knowledge. However...... this article claims that in order to assess the overall legitimacy of the EU regulatory governance through agencies, the ‘throughput’ criterion needs to be considered. Although important, the ‘input’ (politics) and ‘output’ (policy) criteria fail to capture what happens within the actual governance (process...

Anti-tumor activity of self-charged (Eu,Ca):WO3 and Eu:CaWO4 nanoparticles

International Nuclear Information System (INIS)

Lin, Cao; Cong, Wang; De'An, Pan; Jiexin, Cao; Ping, Che; Volinsky, Alex A.

2012-01-01

Non-stoichiometric (Eu,Ca):WO 3 and Eu:CaWO 4 nanoparticles with anti-tumor activity are synthesized in a sol-gel method by adding excessive Eu 3+ and Ca 2+ ions to tungsten oxide crystal structure. Colorimetric assay shows that 10 nm (Eu,Ca):WO 3 and Eu:CaWO 4 nanoparticles can effectively inhibit growth of mammary cancer cells without any harm to normal cells. Nanoparticles are characterized by X-ray diffraction, high resolution transmission electron microscopy and fluorescence optical spectrometry. Nanomaterials, insoluble in synthesized water, have complicated self-charging surfaces that trap mammary cancer cells. Surface self-charging effect is suggested as the inhibition mechanism. (author)

EU-Russia Cultural Relations

Directory of Open Access Journals (Sweden)

Elena Sidorova

2014-05-01

Full Text Available This article analyzes the link between culture and diplomacy between Russia and the European Union, and shows the importance of cultural relations. It examines the common space of science, education and culture introduced at the 2003 EU-Russia Summit in St. Petersburg and the application of the principles of this concept that were established at the 2005 EU-Russia Summit in Moscow. It then considers EU-Russia collaboration on humanitarian action and the challenges that both parties face in this sphere. It also explains the formation of EU domestic and foreign cultural policy, and the role of European institutions and states in cultural affairs and diplomacy, as well as key elements and mechanisms of contemporary Russian foreign cultural policy. In addition, the article focuses on the European side of post-Soviet EU-Russia cultural relations. This cultural collaboration is defined as a competitive neighbourhood. EU and Russian interests collide: while Europeans try to promote their values, norms and standards within the framework of the European Neighbourhood Policy, Russia seeks to culturally influence and engage in this region for geostrategic and historical reasons. Finally, the article assesses the prospects for the EU-Russia cultural relations and emphasizes the role of ideology in improving such relations.

A multi-level analysis of the EU linking directive process: the controversial connection between EU and global climate policy

Energy Technology Data Exchange (ETDEWEB)

Flaam, Karoline Haegstad

2007-10-15

Despite initial scepticism in the EU towards the Kyoto Protocol's project mechanisms (the CDM and JI), the 'Linking Directive' was adopted in October 2004, connecting the EU emissions trading scheme with the project mechanisms. Not only was the Linking Directive settled remarkably quickly, the decision-making process also left a more liberal text, with fewer restrictions on the use of the project mechanisms, as compared to the initial directive proposal. This report examines possible explanations to this puzzle, evaluating whether Member State preferences, EU institutions or external influence from the climate regime best can contribute to understanding the process. On the basis of the analysis of written sources stemming from the decision-making process, as well as seven in-depth interviews, the report finds that Member State preferences were the main driver in the Linking Directive process. This gives support to the intergovernmentalist mantra, that Member States are the main decision-makers in the EU. It also challenges much recent research claiming that EU policy-making is increasingly being taken out of the hands of the nation-state and into supranational actors such as the Commission and the European Parliament. (author). 41 refs., figs., tabs

A multi-level analysis of the EU linking directive process: the controversial connection between EU and global climate policy

Energy Technology Data Exchange (ETDEWEB)

Flaam, Karoline Haegstad

2007-10-15

Despite initial scepticism in the EU towards the Kyoto Protocol's project mechanisms (the CDM and JI), the 'Linking Directive' was adopted in October 2004, connecting the EU emissions trading scheme with the project mechanisms. Not only was the Linking Directive settled remarkably quickly, the decision-making process also left a more liberal text, with fewer restrictions on the use of the project mechanisms, as compared to the initial directive proposal. This report examines possible explanations to this puzzle, evaluating whether Member State preferences, EU institutions or external influence from the climate regime best can contribute to understanding the process. On the basis of the analysis of written sources stemming from the decision-making process, as well as seven in-depth interviews, the report finds that Member State preferences were the main driver in the Linking Directive process. This gives support to the intergovernmentalist mantra, that Member States are the main decision-makers in the EU. It also challenges much recent research claiming that EU policy-making is increasingly being taken out of the hands of the nation-state and into supranational actors such as the Commission and the European Parliament. (author). 41 refs., figs., tabs

EU Action against Climate Change. EU emissions trading. An open scheme promoting global innovation

International Nuclear Information System (INIS)

2005-01-01

The European Union is committed to global efforts to reduce the greenhouse gas emissions from human activities that threaten to cause serious disruption to the world's climate. Building on the innovative mechanisms set up under the Kyoto Protocol to the 1992 United Nations Framework Convention on Climate Change (UNFCCC) - joint implementation, the clean development mechanism and international emissions trading - the EU has developed the largest company-level scheme for trading in emissions of carbon dioxide (CO2), making it the world leader in this emerging market. The emissions trading scheme started in the 25 EU Member States on 1 January 2005

The Interparliamentary Conference on the CFSP/CSDP: A new forum for the Oireachtas in Irish and EU foreign policy?

DEFF Research Database (Denmark)

Butler, Graham

2015-01-01

and legislatures in the policy domains of foreign affairs, security and defence, compounded by the loss of institutional influence experienced by national parliaments as a result of the European integration process, interparliamentarianism within the EU has seen significant growth over the past number of years...... questions whether such interparliamentary activity in its current state is worth the effort at all. Nonetheless, the paper concludes that given the extremely weak position the Oireachtas finds itself in when it comes to oversight and scrutiny by parliamentary committees, Irish members of the IPC on the CFSP...

The effect of self-scrutiny on improving women’s self-esteem: A case study of Esfahan women

Directory of Open Access Journals (Sweden)

Farzaneh Monjezi

2013-04-01

Full Text Available The proposed study of this paper investigates the effect of self-scrutiny on improving women’s self-esteem among 50 women who live in city of Esfahan, Iran. There are five hypotheses associated with the proposed study of this paper, which investigate whether teaching self-scrutiny skills increase women’s total, educational-vocational, general, social and family self-esteem. The proposed study of this paper uses three groups of pre-test post-test and control groups and it has been executed among 50 women aged 20-35 who lived in city of Esfahan, Iran based on Coopersmith questionnaire. The results of ANOVA test confirm all five hypotheses of this survey. In other words, scrutiny skills increase women’s total, educational-vocational, general, social and family self-esteem after control group participate in our training programs.

Eliminating national borders as labour market barriers in the EU

NARCIS (Netherlands)

van Lieshout, Harm

2012-01-01

This paper addresses one important mechanism through which the EU tries to improve the operation of its labour markets: the opening up of national borders for free worker movement within the EU. Free worker movement is a fundamental EU right; but EU enlargement begged the question of how and when to

Reducing Greenhouse Gas Emissions in India. Financial mechanisms and opportunities for EU-India collaboration

Energy Technology Data Exchange (ETDEWEB)

Atteridge, Aaron; Nilsson Axberg, Goeran; Goel, Nitu; Kumar, Atul; Lazarus, Michael; Ostwald, Madelene; Polycarp, Clifford; Tollefsen, Petter; Torvanger, Asbjoern; Upadhyaya, Prabhat; Zetterberg, Lars

2009-10-15

This report illuminates potential areas for collaboration between the EU and India on actions that reduce greenhouse gas emissions in India. If human-induced climate change is to have any hope of being limited to 2 degrees, it is essential that ways are found to address rapidly rising greenhouse gas emissions in India, as elsewhere. This is a challenging proposition: even though India's per capita emissions are very low, her 1.15 billion people are collectively a major source of greenhouse gas emissions. This fact, coupled with the immediate task of tackling widespread poverty, means that the international community must play a major role in providing financial and technological resources to support India's domestic efforts. As India's 2008 National Action Plan on Climate Change recognises, tackling the country's greenhouse gas emissions means not least finding ways to transform a rapidly growing energy sector. International financial mechanisms such as the Clean Development Mechanism and the Global Environment Facility have been unable to deliver the scale of transformative change needed to shift India's emissions trajectory. While the Indian government has already initiated some ambitious policy measures - particularly pertaining to solar energy and energy efficiency- the effectiveness of international finance mechanisms and other forms of international partnership will be crucial in determining the success of greenhouse gas mitigation efforts. The EU India Summit is held a month before COP15 negotiations in Copenhagen. While this provides challenges in terms of seeking concrete agreements on questions of finance, it is also an important opportunity to devise complementary efforts outside the UNFCCC process. Genuine, productive collaboration could not only be used to foster the sorts of transformative changes that are needed in India's growing economy but could also create a spirit of cooperation that spills over into UNFCCC

Can EU Act as a Democracy Promoter? Analysing the Democratization Demand and Supply in Turkey - EU Relations

OpenAIRE

Çiğdem Üstün

2017-01-01

The EU’s role to assist Turkey in its democratization efforts has been debated during Turkey’s candidacy. However, in the second decade of the 21st century, this role of the EU lost its visibility while Turkey seemed to lose its interest in reform movements. This paper, inspired by Pevehouse, defines the EU as a supplier of democratization mechanisms and Turkey as an actor in need. Although lack of enthusiasm and disengagement have come to characterize Turkey-EU relations, this study aims to ...

Can EU Act as a Democracy Promoter? Analysing the Democratization Demand and Supply in Turkey - EU Relations

Directory of Open Access Journals (Sweden)

Çiğdem Üstün

2017-06-01

Full Text Available The EU’s role to assist Turkey in its democratization efforts has been debated during Turkey’s candidacy. However, in the second decade of the 21st century, this role of the EU lost its visibility while Turkey seemed to lose its interest in reform movements. This paper, inspired by Pevehouse, defines the EU as a supplier of democratization mechanisms and Turkey as an actor in need. Although lack of enthusiasm and disengagement have come to characterize Turkey-EU relations, this study aims to demonstrate that there are differences between the governing and the opposition actors’ views on the EU and its role in the democratization of Turkey. Data collected from the speeches of opposition parties’ parliamentarians between 1 January 2011 and 31 August 2016 demonstrates the similarities observed in these parties’ concerns regarding democratic practices and the perception of the EU as an actor strengthening democracy, while indicating that the EU, as a supplier, overlooked their concerns during the process.

Plastic scintillators with {beta}-diketone Eu complexes for high ionizing radiation detection

Energy Technology Data Exchange (ETDEWEB)

Adadurov, A.F., E-mail: adadurov@isma.kharkov.ua [Institute for Scintillating Materials, NAN of Ukraine, Lenin Avenue 60, 61001 Kharkov (Ukraine); Zhmurin, P.N.; Lebedev, V.N.; Kovalenko, V.N. [Institute for Scintillating Materials, NAN of Ukraine, Lenin Avenue 60, 61001 Kharkov (Ukraine)

2011-10-15

Luminescent and scintillation properties of polystyrene-based plastic scintillators with {beta}-diketone Eu complexes are investigated. A scintillator with dibenzoylmethane Eu complex containing two phenyl groups demonstrates the maximum scintillating efficiency. It is shown that plastic scintillators efficiency is dramatically decreased if {beta}-diketone derivatives contain no phenyl groups as substituents. This fact can be explained by exciplex mechanism of energy transfer from a matrix to Eu complex. - Highlights: > Fluorescent properties of polystyrene scintillators with {beta}-diketone complexes of Eu were studied. > Scintillating efficiency is increased with the number of phenyl groups in Eu complex. > This is related to exciplex mechanism of energy transfer from a polymer matrix to Eu complex.

Facile preparation and formation mechanism of Sr2Si5N8:Eu2+ red-emitting phosphors

Science.gov (United States)

Wang, Yang; Wang, Yunli; Wang, Ming; Shao, Yiran; Zhu, Yingchun

2018-05-01

The red-emitting Sr2Si5N8:Eu2+ phosphors have been synthesized in a new facile process using (oxy)nitride precursors by inductive calcination under N2 atmosphere at ordinary pressure. Different from the prevailing methods, lower cost raw materials, simpler pretreatment, without harsh conditions and a shorter reaction time are achieved. It was found that red-emitting Sr2Si5N8:Eu2+ phosphors were synthesized with high crystallinity and purity after 1 h inductive calcination. The formation mechanism was characterized by XRD, SEM, TEM and Fluorescence microscopy. It was demonstrated that a hexagonal mesophase of Sr-doped α-Si3N4 was primarily formed in the reaction process, which transformed into the final product of the orthorhombic Sr2Si5N8:Eu2+ phosphors. During the reaction process, the color of the samples transforms from greenish-yellow to orange and eventually to red. The as-prepared phosphors have a wide excitation in the range of 250 ∼ 570 nm which matches blue light chips and give a red-light emission peaking at 610 nm. The results indicate a promising prospect for a simple, efficient and inexpensive way to prepare Sr2Si5N8:Eu2+ phosphors for blue/UV-based warm-white LEDs and other fluorescent applications.

EU Climate Change Exhibition Held

Institute of Scientific and Technical Information of China (English)

2008-01-01

<正>On April 25, the CPAFFC, the China-EU Association (CEUA) and the Delegation of the European Commission to China jointly held the opening ceremony for the EU Exhibition on Climate Change in the CPAFFC. He Luli, former vice chairperson of the NPC Standing Committee and honorary president of the CEUA, Jose Manuel Barroso, president of the European Commission, and Li Jianping, vice president of the CPAFFC, attended the opening ceremony and made speeches. Honorary President He Luli highly praised the achievements made by China and the EU in their longtime cooperation of mutual benefits in various fields including environmental protection. She said, for many years China and EU have both committed to the development of all-round strategic partnership and establishment of a multi-level mechanism of political dialogue. She expressed, with increasing enthusiasm the CEUA would continue to actively carry out nongovernmental exchanges between China and the EU, and promote cooperation between the two sides in the fields of economy, society, environmental protection, science and technology, culture, etc.

Plastic scintillators with β-diketone Eu complexes for high ionizing radiation detection

International Nuclear Information System (INIS)

Adadurov, A.F.; Zhmurin, P.N.; Lebedev, V.N.; Kovalenko, V.N.

2011-01-01

Luminescent and scintillation properties of polystyrene-based plastic scintillators with β-diketone Eu complexes are investigated. A scintillator with dibenzoylmethane Eu complex containing two phenyl groups demonstrates the maximum scintillating efficiency. It is shown that plastic scintillators efficiency is dramatically decreased if β-diketone derivatives contain no phenyl groups as substituents. This fact can be explained by exciplex mechanism of energy transfer from a matrix to Eu complex. - Highlights: → Fluorescent properties of polystyrene scintillators with β-diketone complexes of Eu were studied. → Scintillating efficiency is increased with the number of phenyl groups in Eu complex. → This is related to exciplex mechanism of energy transfer from a polymer matrix to Eu complex.

Synthesis and luminescent properties of Eu{sup 3+}/Eu{sup 2+} co-doped calcium aluminosilicate glass–ceramics

Energy Technology Data Exchange (ETDEWEB)

Bouchouicha, H. [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France); Panczer, G., E-mail: gerard.panczer@univ-lyon1.fr [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France); Ligny, D. de [Universität Erlangen-Nürnberg, Department Werkstoffwissenschaften, Lehrstuhl für Glas und Keramik, D-91058 Erlangen (Germany); Guyot, Y. [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France); Baesso, M.L. [Departemento de Fisica, Universidade Estadual de Maringa, 87020-900 Maringa, PR (Brazil); Andrade, L.H.C.; Lima, S.M. [Grupo de Espectroscopia Óptica e Fototérmica, Universidade Estadual de Mato Grosso do Sul – UEMS, C.P. 351, Dourados, MS (Brazil); Ternane, R. [Laboratoire d' Application de la Chimie aux Ressources et Substances Naturelles et à l' Environnement (LACReSNE), Université de Carthage, Faculté des Sciences de Bizerte, 7021 Zarzouna, Bizerte (Tunisia)

2016-01-15

Eu{sup 3+} and Eu{sup 2+} co-doped calcium aluminosilicate glass–ceramics have been prepared by devitrification of calcium aluminosilicate glass using heat-treatment. Control of crystallization in the glass–ceramics was studied by X-ray diffraction (XRD) and Raman spectroscopy. The results showed that crystalline phases in glass–ceramic belong to the family of melilite Ca{sub 2}Mg{sub 0.25}Al{sub 1.5}Si{sub 1.25}O{sub 7} as the major phase and anorthite CaAl{sub 2}Si{sub 2}O{sub 8} as the minor phase. Luminescent properties were investigated by emission; lifetime and the color points were calculated. Emission spectra showed that Eu{sup 2+} entered into the crystalline phase in a two steps mechanism: first as Eu{sup 3+} which is then reduced to Eu{sup 2+}. This incorporation in the crystal enhanced Eu{sup 2+} emission with increasing time of heat-treatment and therefore crystallization. - Highlights: • Crystallization of doped glass–ceramics by heat-treatment controlled by microRaman. • Crystalline phases consist of melilite and anorthite. • Eu{sup 3+} and Eu{sup 2+} emissions characterized by their lifetime and color indexes. • Crystallization process modified efficiently the emission color point.

The photoluminescence/excitation (PL/E) spectroscopy of Eu-implanted GaN

KAUST Repository

O'Donnell, Kevin Peter

2011-05-01

Several distinct luminescent centres form in GaN samples doped with Eu. One centre, Eu2, recently identified as the isolated, substitutional Eu impurity, EuGa, is dominant in ion-implanted samples annealed under very high pressures (1 GPa) of N2. According to structural determinations, such samples exhibit an essentially complete removal of lattice damage caused by the implantation process. A second centre, Eu1, probably comprising EuGa in association with an intrinsic lattice defect, produces a more complex emission spectrum. In addition there are several unidentified features in the 5D0 to 7F2 spectral region near 620 nm. We can readily distinguish Eu1 and Eu2 by their excitation spectra, in particular through their different sensitivities to above-gap and below-gap excitation. The present study extends recent work on photoluminescence/ excitation (PL/E) spectroscopy of Eu1 and Eu2 to arrive at an understanding of these mechanisms in terms of residual optically active defect concentrations. We also report further on the \\'host-independent\\' excitation mechanism that is active in the case of a prominent minority centre. The relevance of this work to the operation of the red GaN:Eu light-emitting diode is discussed. © 2010 Elsevier B.V. All rights reserved.

The photoluminescence/excitation (PL/E) spectroscopy of Eu-implanted GaN

KAUST Repository

O'Donnell, Kevin Peter; Roqan, Iman S.; Wang, Ke; Lorenz, Katharina; Alves, Eduardo Jorge; Boćkowski, Michał X.

2011-01-01

Several distinct luminescent centres form in GaN samples doped with Eu. One centre, Eu2, recently identified as the isolated, substitutional Eu impurity, EuGa, is dominant in ion-implanted samples annealed under very high pressures (1 GPa) of N2. According to structural determinations, such samples exhibit an essentially complete removal of lattice damage caused by the implantation process. A second centre, Eu1, probably comprising EuGa in association with an intrinsic lattice defect, produces a more complex emission spectrum. In addition there are several unidentified features in the 5D0 to 7F2 spectral region near 620 nm. We can readily distinguish Eu1 and Eu2 by their excitation spectra, in particular through their different sensitivities to above-gap and below-gap excitation. The present study extends recent work on photoluminescence/ excitation (PL/E) spectroscopy of Eu1 and Eu2 to arrive at an understanding of these mechanisms in terms of residual optically active defect concentrations. We also report further on the 'host-independent' excitation mechanism that is active in the case of a prominent minority centre. The relevance of this work to the operation of the red GaN:Eu light-emitting diode is discussed. © 2010 Elsevier B.V. All rights reserved.

Review of the impact of the Ukraine-EU free trade agreement on manufacturing industries (mechanical engineering, chemical and light industry

Directory of Open Access Journals (Sweden)

Olga Usenko

2007-03-01

Full Text Available The article gives a definition to the concept of ‘deep integration’ taken by the Ukrainian Government as a framework concept for the establishment of a Ukraine-EU free trade area. The paper uses the term ‘deep free trade’ or ‘free trade area +’. It offers a review of the Ukrainian economy and its readiness to open such industries as mechanical engineering, chemical and light industry to free trade with the EU. It examines which cooperative steps might be taken in the sectors in question in the framework of a free trade area by identifying specific features of those sectors in Ukraine and the EU through SWOT analysis and review of certain provisions in relevant agreements between the EU and other countries. It proposes to forecast the possible impact of a free trade area on stakeholders’ position regarding the agreement by using the ‘stakeholder approach’ (identifying and classifying interest groups and the European Commission’s method of ‘impact assessment’. Based on the results of this research, conclusions are made concerning the fundamental negotiation principles for talks between Ukraine and the EU as to the economic and trade component of the new ‘enhanced agreement.

High-Precision Measurement of Eu/Eu* in Geological Glasses via LA-ICP-MS Analysis

Science.gov (United States)

Tang, Ming; McDonough, William F.; Arevalo, Ricardo, Jr.

2014-01-01

Elemental fractionation during laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis has been historically documented between refractory and volatile elements. In this work, however, we observed fractionation between light rare earth elements (LREEs) and heavy rare earth elements (HREEs) when using ablation strategies involving large spot sizes (greater than 100 millimeters) and line scanning mode. In addition: (1) ion yields decrease when using spot sizes above 100 millimeters; (2) (Eu/Eu*)(sub raw) (i.e. Europium anomaly) positively correlates with carrier gas (He) flow rate, which provides control over the particle size distribution of the aerosol reaching the ICP; (3) (Eu/Eu*)(sub raw) shows a positive correlation with spot size, and (4) the changes in REE signal intensity, induced by the He flow rate change, roughly correlate with REE condensation temperatures. The REE fractionation is likely driven by the slight but significant difference in their condensation temperatures. Large particles may not be completely dissociated in the ICP and result in preferential evaporation of the less refractory LREEs and thus non-stoichiometric particle-ion conversion. This mechanism may also be responsible for Sm-Eu-Gd fractionation as Eu is less refractory than Sm and Gd. The extent of fractionation depends upon the particle size distribution of the aerosol, which in turn is influenced by the laser parameters and matrix. Ablation pits and lines defined by low aspect ratios produce a higher proportion of large particles than high aspect ratio ablation, as confirmed by measurements of particle size distribution in the laser induced aerosol. Therefore, low aspect ratio ablation introduces particles that cannot be decomposed and/or atomized by the ICP and thus results in exacerbated elemental fractionation. Accurate quantification of REE concentrations and Eu/Eu* requires reduction of large particle production during laser ablation. For the reference

Search for unobserved transitions in "1"4"2Eu

International Nuclear Information System (INIS)

Ali, Sajad; Rajbanshi, S.; Bisoi, Abhijit

2016-01-01

In order to understand the excitation mechanisms responsible for the generation of high spin states in this mass region we have studied "1"4"2Eu nucleus. The high spin states of the "1"4"2Eu was reported earlier by M. Piiparinen et al. Based on this experimental data, they have proposed a level scheme of "1"4"2Eu. The motivation of current work is to remove the remaining incompleteness of the previously reported level scheme of "1"4"2Eu

Controversial EU deportation programme subjected to academic scrutiny

DEFF Research Database (Denmark)

Lemberg-Pedersen, Martin; McClelland, Ian

2013-01-01

On 3 May 2013, the Refugee Studies Centre hosted a workshop in Oxford, co-convened by Martin Lemberg-Pedersen (University of Copenhagen) and Dawn Chatty (RSC), to shed light on the little-publicised European Return Platform for Unaccompanied Minors (ERPUM)...

Should the EU climate policy framework be reformed?

Directory of Open Access Journals (Sweden)

David ELLISON

2011-12-01

Full Text Available Though to-date the European Union (EU has played the most significant leadership role in international negotiations to reduce greenhouse gas (GHG emissions, the emission-reducing performance of individual EU Member states has for many been less than stellar. Several EU15 Member states continue to raise rather than lower emissions. Analysing the most successful policy instruments, this paper argues EU policy efforts could benefit from three important innovations. The following strategies – the adoption of an EU-wide FIT (feed-in tariff, an EU-wide carbon tax and more flexibility in the trading of carbon credits – could significantly improve emission reductions, their relative cost-efficiency and spread burden-sharing more evenly across technologies and Member states. This raises important questions, both about the effectiveness of EU and Kyoto-style commitments, as well as the EU Emission Trading Scheme (ETS. The commitment strategy, and in particular the EU ETS mechanism, have had the smallest impact on emission reductions. The proposed set of strategies could make a far greater contribution to future EU efforts and potentially lock in the impressive progress already made. Such a policy shift, if successful, would also greatly enhance the EU’s already significant credibility and bargaining power in international climate negotiations.

From EuCARD to EuCARD-2

CERN Multimedia

Chaudron, M

2013-01-01

The one word that best describes the spirit of the EuCARD ’13 event (see here) that took place from 10 to 14 June at CERN is "collaboration". The event brought together more than 180 accelerator specialists from all over the world to celebrate the conclusion of the EuCARD project and to kick off its successor, EuCARD-2.   EuCARD-2 brings a global view to particle accelerator research in order to address challenges for future generations of accelerators. The project officially began on 1 May 2013 and will run for four years. With a total budget of €23.4 million, including an €8 million EU contribution, it will build upon the success of EuCARD and push it into an even more innovative regime. EuCARD-2 aims to significantly enhance multidisciplinary R&D for European accelerators and will actively contribute to the development of a European Research Area in accelerator science. This will be accomplished by promoting complementary expertise, cross-d...

EU Udbudsretten

DEFF Research Database (Denmark)

Poulsen, Sune Troels; Jakobsen, Peter Stig; Kalsmose-Hjelmborg, Simon Evers

I bogen, som er en 2. udgave, analyseres EU udbudsdirektiv for offentlige myndigheder og EU's forsyningsvirksomhedsdirektiv. I analyserne inddrages EU-domstolens domme, afgørelser fra Kalgenævnet for Udbud, domme fra danske domstole samt litteratur på dansk og engelsk.......I bogen, som er en 2. udgave, analyseres EU udbudsdirektiv for offentlige myndigheder og EU's forsyningsvirksomhedsdirektiv. I analyserne inddrages EU-domstolens domme, afgørelser fra Kalgenævnet for Udbud, domme fra danske domstole samt litteratur på dansk og engelsk....

Essential EU Climate Law

NARCIS (Netherlands)

Woerdman, Edwin; Roggenkamp, Martha; Holwerda, Marijn

2015-01-01

This innovative textbook takes a broad approach to EU climate law and presents all available legal instruments to combat climate change, ranging from greenhouse gas emissions trading to the use of renewable energy sources and energy efficiency mechanisms. After providing a definition of climate law,

It’s not the Fish that Stinks! EU Trade Relations with Morocco under the Scrutiny of the General Court of the European Union

Directory of Open Access Journals (Sweden)

Sandra Hummelbrunner

2016-09-01

Full Text Available The EU’s international agreements with Morocco on trade in agricultural and fishery products have drawn criticism due to their application to the disputed territory of Western Sahara, a territory that remains on the list of non-self-governing territories to be decolonised in accordance with the right of self-determination of the indigenous Sahrawi people. Recently, the Sahrawi liberation movement Front Polisario brought an action for annulment before the General Court of the European Union (GC against the Council Decision approving the conclusion of one such agreement, alleging multiple violations of European and international legal norms. Interestingly, although the GC concurred by annulling the Decision insofar as it applies to Western Sahara, it chose to exclusively base its judgment on EU fundamental rights, invoking the EU’s failure to ensure that the fundamental rights of the Sahrawi people were not infringed by applying the agreements to Western Sahara. By summarily setting aside Front Polisario’s other claims, several relevant questions of applicable international and European law, which warrant further discussion, remain. This article examines these questions using the GC’s judgment in Front Polisario, thereby combining general matters of international and European law with the specific circumstances of the EU-Morocco relations and Western Sahara.

Optical spectroscopy and optical waveguide fabrication in Eu3+ and Eu3+/Tb3+ doped zinc–sodium–aluminosilicate glasses

International Nuclear Information System (INIS)

Caldiño, U.; Speghini, A.; Berneschi, S.; Bettinelli, M.; Brenci, M.; Pasquini, E.; Pelli, S.; Righini, G.C.

2014-01-01

Optical and spectroscopic properties of 2.0% Eu(PO 3 ) 3 singly doped and 5.0% Tb(PO 3 ) 3 –2.0% Eu(PO 3 ) 3 codoped zinc–sodium–aluminosilicate glasses were investigated. Reddish-orange light emission, with x=0.64 and y=0.36 CIE1931 chromaticity coordinates, is obtained in the europium singly doped glass excited at 393 nm. Such chromaticity coordinates are close to those (0.67,0.33) standard of the National Television System Committee for the red phosphor. When the sodium–zinc–aluminosilicate glass is co-doped with Tb 3+ and Eu 3+ , reddish-orange light emission, with (0.61,0.37) CIE1931 chromaticity coordinates, is obtained upon Tb 3+ excitation at 344 nm. This reddish-orange luminescence is generated mainly by 5 D 0 → 7 F 1 and 5 D 0 → 7 F 2 emissions of Eu 3+ , europium being sensitized by terbium through a non-radiative energy transfer. From an analysis of the Tb 3+ emission decay curves it is inferred that the Tb 3+ →Eu 3+ energy transfer might take place between Tb 3+ and Eu 3+ clusters through a short-range interaction mechanism, so that an electric dipole–quadrupole interaction appears to be the most probable transfer mechanism. The efficiency of this energy transfer is about 62% upon excitation at 344 nm. In the singly doped and codoped glasses multimode optical waveguides were successfully produced by Ag + –Na + ion exchange, and they could be characterized at various wavelengths. -- Highlights: • Reddish-orange light emission can be generated from Tb 3+ and Eu 3+ codoped zinc–sodium–aluminosilicate glasses excited at 344 nm. • The Eu 3+ is sensitized by Tb 3+ through a non-radiative energy transfer. • Highly multimode waveguides can be fabricated by diluted silver–sodium exchange. • This type of AlGaN LEDs pumped glass phosphors might be useful for generation of reddish-orange light

EU's CO2 trade a high risk project

International Nuclear Information System (INIS)

Wellander, Dag

2003-01-01

The uncertainty about the planned CO 2 trade of the European Union (EU) is very great. For the possible buyers in this politically created market the risks may be great and difficult to assess. The most effective way of forcing a reduction of emissions is trading emission licences. But this requires taking a stand on issues of very unpleasant nature. And the Kyoto protocol evades these questions, it is a thin document right from the beginning. Trade in emission licences is one of the three so-called flexible mechanisms of the Kyoto agreement. The second mechanism is joint implementation in which one industrialized country carries out emission reduction actions in another industrialized country. The third is the mechanism of clean development, in which one industrialized country takes remedial actions in a developing country. It is unclear how these mechanisms are to act in accordance with each other, both in the Kyoto Protocol and on the level of the EU. The biggest and most fundamental uncertainty, both on the EU and global levels, relates to the fact that the partners have not decided how to define the right of ownership of emissions of a certain size

Quantitative study of energy-transfer mechanism in Eu,O-codoped GaN by time-resolved photoluminescence spectroscopy

Science.gov (United States)

Inaba, Tomohiro; Kojima, Takanori; Yamashita, Genki; Matsubara, Eiichi; Mitchell, Brandon; Miyagawa, Reina; Eryu, Osamu; Tatebayashi, Jun; Ashida, Masaaki; Fujiwara, Yasufumi

2018-04-01

In order to investigate the excitation processes in Eu,O-codoped GaN (GaN:Eu,O), the time-resolved photoluminescence signal including the rising part is analyzed. A rate equation is developed based upon a model for the excitation processes in GaN:Eu to fit the experimental data. The non-radiative recombination rate of the trap state in the GaN host, the energy transfer rate between the Eu3+ ions and the GaN host, the radiative transition probability of Eu3+ ion, as well as the ratio of the number of luminescent sites (OMVPE 4α and OMVPE 4β), are simultaneously determined. It is revealed and quantified that radiative transition probability of the Eu ion is the bottleneck for the enhancement of light output from GaN:Eu. We also evaluate the effect of the growth conditions on the luminescent efficiency of GaN:Eu quantitatively, and find the correlation between emission intensity of GaN:Eu and the fitting parameters introduced in our model.

Costs of compliance with EU regulations and competitiveness of the EU dairy sector

NARCIS (Netherlands)

Bezlepkina, I.; Jongeneel, R.; Brouwer, F.M.; Dillen, K.; Meister, A.; Winsten, J.; Roest, de K.; Demont, M.

2008-01-01

The introduction of cross-compliance mechanism in the European Union with its 2003 CAPreform might affect the costs of production and thus competitiveness of the EU. Little evidence is available to asses the costs of compliance with regulations and it implication for trade. In this study a farm

Concentration quenching of Eu{sup 2+} doped Ca{sub 2}BO{sub 3}Cl

Energy Technology Data Exchange (ETDEWEB)

Seed Ahmed, H.A.A. [Department of Physics, University of the Free State, Bloemfontein, ZA 9300 (South Africa); Department of Physics, University of Khartoum, Khartoum (Sudan); Swart, H.C. [Department of Physics, University of the Free State, Bloemfontein, ZA 9300 (South Africa); Bergman, Peber [Department of Physics, Chemistry and Biology, Linköping University, Linköping (Sweden); Kroon, R.E., E-mail: KroonRE@Uufs.ac.za [Department of Physics, University of the Free State, Bloemfontein, ZA 9300 (South Africa)

2016-03-15

Highlights: • Ca{sub 2}BO{sub 3}Cl doped with Eu{sup 2+} prepared by solid state reaction. • Concentration quenching studied by intensity and lifetime measurements. • Accurate determination of the critical transfer distance. • Interaction mechanism verified to be dipole–dipole interactions. - Abstract: With the aim of determining the concentration quenching mechanism of Eu{sup 2+} doped Ca{sub 2}BO{sub 3}Cl, a series of phosphors with a varied Eu{sup 2+} concentration (Ca{sub 2−x}BO{sub 3}Cl:xEu{sup 2+}) was synthesized by the solid state reaction method. The phase structure was determined by X-ray diffraction. Photoluminescence (PL) measurements showed broad excitation and emission signatures of the allowed f–d transition of Eu{sup 2+} ions. The PL emission intensity was found to be increased by increasing the concentration of Eu{sup 2+} ions up to x = 0.03 and then decreased as a result of the concentration quenching effect. The lifetime of the emission from the Eu{sup 2+} ions was measured and the decrease in the lifetime with increasing Eu{sup 2+} concentration confirmed that non-radiative energy transfer occurred between Eu{sup 2+} ions. From the luminescence data, the value of the critical transfer distance was calculated as 1.5 nm and the corresponding concentration quenching mechanism was verified to be a dipole–dipole interaction.

The EU agencies’ role in policy diffusion beyond the EU

DEFF Research Database (Denmark)

Chatzopoulou, Sevasti

and health quality within the risk assessment. This paper shows that the EU agencies develop various entrepreneurial methods and that they actively promote policy diffusion beyond the EU through socialisation and learning within international arrangements and collaborations. However, variations......The extensive literature on the EU agencies has mainly focused on their role in the harmonisation and expansion of regulatory standards within the EU. This paper joins this literature and investigates the role of EU agencies in policy diffusion beyond the EU borders. To operationalise this...

EU Banking Union: Lessons for non-eurozone transition countries

Directory of Open Access Journals (Sweden)

Šoškić Dejan

2015-01-01

Full Text Available Eurozone has gone through turmoil of sovereign debt crisis just after the detrimental effect of global financial crises of 2007/2008. Sovereign debt crisis of the eurozone was caused by bank-sovereign interdependence and lack of fiscal union in the eurozone. Financial fragmentation in the eurozone financial markets was an immediate outcome. Banking union of the EU is a regulatory and institutional remedy for main financial problems of the eurozone post global financial crisis. It is clear signal that lessons have been learned from the two crises. Stricter regulation (single rule book aims to increase the quality of banks. Single Supervisory Mechanism (SRM, and Single Resolution Mechanism (SRM aim to unify and better the standards of supervision and resolution in the EU. With emphasis on bail-ins, and EU level backstops, bank-sovereign interdependence should be dismantled and chances of financial crisis reoccurrence with huge costs for taxpayers should be significantly lower. There are important elements of Banking Union that could be introduced in non-eurozone transition countries both members and nonmembers of the EU.

Enhanced Cooperation - the New Trend of the EU Development

Directory of Open Access Journals (Sweden)

Lyudmila O. Babynina

2014-01-01

Full Text Available The article is dedicated to implementation of the enhanced cooperation in the EU. Actually two such projects are шn progress (the law applicable to divorce and legal separation and unitary patent protection and other two are under discussionffmandai transaction tax and European Public Prosecutor's Office. Active use of the enhanced cooperation recently shows that such kind of the promoting integration is more and more required in the EU. However its implementation can jeopardize the principles of the EU functioning and undermine the status of the institutions in the integration process. This mechanism can also be used in order to exclude the discordant states from integration process instead of traditional search of compromises. This argument is based on analysis of the implementation conditions of the project on the unitary patent protection. At the same time the projects of the enhanced cooperation obviously make the interaction in different spheres more efficient. In addition they can be used for testing the new types of cooperation. That's why the search for an optimal balance between promotion integration through the mechanism of enhanced cooperation and preserving the unity of the EU should be considered as main goal by participants of the integration process. Otherwise the gradual separation on the vanguard group may lead to EU division. Nevertheless taking into consideration enlargement of the EU and its diversity, the enhanced cooperation Should be used onlyas "extreme measure".

Antitrust rules and Intellectual Property Rights in the EU and the US – Towards convergence?

Directory of Open Access Journals (Sweden)

Mario Todino

2014-07-01

Full Text Available In light of the exponential increase of the number of investigations raising the issue of how to reconcile competition rules and Intellectual Property Rights (IPRs, it is now clear that the area of Antitrust/IP intersection is becoming the battleground of antitrust enforcers around the Globe. In some areas inherently prone to market power accumulation, antitrust rules tend to clash with IPRs and prevail over the latter, for the intensity in the application of competition rules increasingly depends on the strength of the IPRs at stake, as well as on the sector involved. Information Communication Technology and Pharmaceuticals are the sectors most affected by this trend, as they both display specific market features calling for intensive antitrust scrutiny. Surprisingly enough, in these areas the EU and the US agencies are heading towards convergence, in light of the decisions taken in cases such as the judicial injunctions sought by FRAND-pledged SEPs holders and the reverse settlements in the Pharma sector. The purpose of this article is to show that in those areas more exposed to tension between antitrust and IP rules, there is an increasing level of convergence between the US and the EU. In particular, it is submitted that, like in the EU, the US is departing from the traditional symmetry principle under which antitrust rules are applied to IPRs exactly the same way as other property rights. In this new framework, inconsistency is more likely to come from the enforcement activity of NCAs across Europe.

New reddish-orange and greenish-yellow light emitting phosphors: Eu3+ and Tb3+/Eu3+ in sodium germanate glass

International Nuclear Information System (INIS)

Álvarez, E.; Zayas, Ma. E.; Alvarado-Rivera, J.; Félix-Domínguez, F.; Duarte-Zamorano, R.P.; Caldiño, U.

2014-01-01

A spectroscopic analysis of sodium germanate glasses activated with Eu 3+ , Tb 3+ and Eu 3+ /Tb 3+ is performed from their photoluminescence spectra and decay times. In the Eu 3+ -singly doped glass reddish-orange light emission, with x=0.64 and y=0.35 CIE1931 chromaticity coordinates, is obtained upon Eu 3+ excitation at 393 nm. Such chromaticity coordinates are close to those (0.67, 0.33) proposed by the National Television Standard Committee for the red phosphor. When the sodium germanate glass is co-doped with Tb 3+ and Eu 3+ greenish-yellow light emission, with (0.41, 0.46) CIE1931 chromaticity coordinates, is obtained upon Tb 3+ excitation at 344 nm. Such greenish-yellow luminescence is due mainly to the terbium 5 D 4 → 7 F 6,5 and europium 5 D 0 → 7 F 1,2 emissions, Eu 3+ being sensitized by Tb 3+ through a non-radiative energy transfer. The non-radiative nature of this energy transfer is inferred from the increase in the decay rate of the Tb 3+ emission when the glass is co-doped with Eu 3+ . From an analysis of the Tb 3+ emission decay time curves it is inferred that such energy transfer might take place between Tb 3+ and Eu 3+ clusters through a short-range interaction mechanism. - Highlights: • Sodium germanate glasses are optically activated with Eu 3+ (GNE) and Tb 3+ /Eu 3+ (GNTE). • Reddish-orange light (0.64, 0.35) is generated by GNE pumped with 393 nm light. • Greenish-yellow light (0.41, 0.46) is generated by GNTE pumped with 344 nm light. • Non-radiative energy transfer Tb 3+ →Eu 3+ takes place in GNTE

Femtosecond laser-induced reduction in Eu-doped sodium borate glasses

Energy Technology Data Exchange (ETDEWEB)

Lim, Ki-Soo [Department of Physics and Basic Science Research Institute, Chungbuk National University, Cheongju 361-763 (Korea, Republic of)]. E-mail: kslim@chungbuk.ac.kr; Lee, Sunkyun [Department of Physics and Basic Science Research Institute, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Trinh, Minh-Tuan [Department of Physics and Basic Science Research Institute, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Kim, Suk-Ho [Department of Physics and Basic Science Research Institute, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Lee, Myeongkyu [Departent of Materials Science and Engineering, Yonsei University, 134 Shinchon-dong, Seoul 120-749 (Korea, Republic of); Hamilton, Douglas S. [Department of Physics, University of Connecticut, Storrs, CT 06269 (United States); Gibson, George N. [Department of Physics, University of Connecticut, Storrs, CT 06269 (United States)

2007-01-15

In this work, we report permanent reduction of Eu{sup 3+} to Eu{sup 2+} in sodium borate glasses by irradiation of near-infrared femtosecond laser. Glass composition of sodium borate was 85B{sub 2}O{sub 3}-15Na{sub 2}O. The glasses were doped with 0.05, 0.1, and 0.5 mol% Eu{sub 2}O{sub 3}. Absorption and fluorescence dynamics were studied to investigate valence state change of europium ions and the energy transfer between Eu{sup 2+} and Eu{sup 3+} ions. As the femtosecond laser intensity or exposure time increases, the emission band at 400 nm becomes stronger. However, the photoreduction efficiency decreases as the dopant concentration increases. We discuss the photoreduction mechanism under multiphoton absorption.

Selective intake of potassium from K-bearing silicate minerals by sunflower and upland rice inferred from Eu anomaly. Implication for weathering as a direct consequence of plant physiology

International Nuclear Information System (INIS)

Akagi, Tasuku; Saito, Sakura; Watanabe, Shin-ichi; Sugiyama, Megumi; Ae, Noriharu

2006-01-01

Two crops (sunflower and upland rice) cultivated using three K-bearing minerals and KCl by Sugiyama and Ae (2000) were analyzed for rare earth elements (REEs). The two crops had been reported by them to general more available silica in soil (especially in the case of sunflower) and absorbed silica in plants (especially in the case of upland rice) than that available originally in soil. The K-bearing minerals included biotite, muscovite, and K-feldspar. The REE patterns of individual crop specimens exhibited different extents of Eu anomaly; upland rice exhibited more varying extent of Eu anomaly than sunflower. It is inferred that REEs released from the K-bearing minerals had a longer contact with soil in the case of sunflower than in the case of upland rice. By the scrutiny of the extent of the Eu anomaly, it was found that upland rice took in K and REEs from all the K-bearing minerals, including hardly-soluble feldspar. Eu anomaly can be a good proxy of sources of inorganic nutrients in plants as well as of the directness of absorption of the nutrients. When the present results are viewed from a different angle, they endorse that plant-induced weathering is equivalent to physiological action of plants. (author)

Optically active centers in Eu implanted, Eu in situ doped GaN, and Eu doped GaN quantum dots

International Nuclear Information System (INIS)

Bodiou, L.; Braud, A.; Doualan, J.-L.; Moncorge, R.; Park, J. H.; Munasinghe, C.; Steckl, A. J.; Lorenz, K.; Alves, E.; Daudin, B.

2009-01-01

A comparison is presented between Eu implanted and Eu in situ doped GaN thin films showing that two predominant Eu sites are optically active around 620 nm in both types of samples with below and above bandgap excitation. One of these sites, identified as a Ga substitutional site, is common to both types of Eu doped GaN samples despite the difference in the GaN film growth method and in the doping technique. High-resolution photoluminescence (PL) spectra under resonant excitation reveal that in all samples these two host-sensitized sites are in small amount compared to the majority of Eu ions which occupy isolated Ga substitutional sites and thus cannot be excited through the GaN host. The relative concentrations of the two predominant host-sensitized Eu sites are strongly affected by the annealing temperature for Eu implanted samples and by the group III element time opening in the molecular beam epitaxy growth. Red luminescence decay characteristics for the two Eu sites reveal different excitation paths. PL dynamics under above bandgap excitation indicate that Eu ions occupying a Ga substitutional site are either excited directly into the 5 D 0 level or into higher excited levels such as 5 D 1 , while Eu ions sitting in the other site are only directly excited into the 5 D 0 level. These differences are discussed in terms of the spectral overlap between the emission band of a nearby bound exciton and the absorption bands of Eu ions. The study of Eu doped GaN quantum dots reveals the existence of only one type of Eu site under above bandgap excitation, with Eu PL dynamics features similar to Eu ions in Ga substitutional sites

Transportforskning i EU

DEFF Research Database (Denmark)

Leleur, Steen

1996-01-01

Artiklen giver en gennemgang af aktuelle EU transportforskningsemner samt nogle synspunkter og erfaringer baseret på deltagelse i EU forskningsprojekter.......Artiklen giver en gennemgang af aktuelle EU transportforskningsemner samt nogle synspunkter og erfaringer baseret på deltagelse i EU forskningsprojekter....

Magnetism and superconductivity in Eu-based iron pnictides

Energy Technology Data Exchange (ETDEWEB)

Zapf, Sina [1. Physikalisches Institut, Universitaet Stuttgart (Germany)

2015-07-01

EuFe{sub 2}As{sub 2} is an extraordinary parent compound of the iron pnictides, as it exhibits at low temperatures - additional to the Fe spin density wave - long-range magnetic order of the Eu{sup 2+} local moments. Nevertheless, bulk superconductivity around 30 K can be induced by mechanical pressure or chemical substitution. In this talk we review the remarkable interplay of unconventional superconductivity, itinerant and local magnetism in Eu based iron pnictides. We focus on the appearance of a re-entrant spin glass phase that coexists with superconductivity and an indirect magneto-elastic coupling, enabling the persistent magnetic detwinning by small magnetic fields.

Estimating broad-brush rebound effects for household energy consumption in the EU 28 countries and Norway: some policy implications of Odyssee data

International Nuclear Information System (INIS)

Galvin, Ray

2014-01-01

Currently there is a strong policy commitment in European Union (EU) and Organisation for Economic Co-operation and Development (OECD) countries to increase the energy efficiency of residential buildings, and it is widely assumed that this will naturally and automatically reduce domestic energy consumption. However, other factors such as fuel prices, wages, attitudes and lifestyles also influence energy consumption. This paper calculates broad-brush rebound effects based on changes in energy efficiency and energy consumption in each of the 28 EU countries plus Norway, for the years 2000–2011. In doing so, it tests how well the assumption of energy efficiency leading to energy reduction stands up to scrutiny in these lands. It uses the EU’s Odyssee database for efficiency and consumption figures and a commonly employed econometric definition of the rebound effect as an energy-efficiency elasticity. Most older EU lands show rebound effects in the expected range of 0–50%. However, the range for newer EU countries is 100–550%, suggesting that energy efficiency increases are not a good predictor of energy consumption. A more in-depth look at one country, Germany, suggests these results underestimate the rebound effect significantly. This also identifies research needs for specific energy consumption determinants in each country, to find more precisely what is driving consumption levels. - Highlights: • Policymakers frequently link energy efficiency gains with energy consumption falls. • Household energy rebound effects are calculated for EU lands using Odyssee data. • Most older EU lands show results in the range of 0–50% but newer lands show 100–552%. • Energy efficiency gains are not always a reliable predictor of energy consumption. • Targeted research could explore why consumption is often so unrelated to efficiency

Exploring the EU ETS beyond 2020. A first assessment of the EU Commission's proposal for Phase IV of the EU ETS (2021-2030). COPEC Research Program: the Coordination of EU Policies on Energy and CO2 with the EU ETS by 2030

International Nuclear Information System (INIS)

Jalard, Matthieu; Alberola, Emilie; Afriat, Marion; Vaidyula, Manasvini; Dahan, Lara; Cail, Sylvain; Cassisa, Cyril; Keramidas, Kimon; Coussy, Paula; Portenart, Philomene

2015-11-01

This report, written in partnership with I4CE and IFPen, provides the first complete and comprehensive assessment of the EU Commission's proposal and its coherence with the 2030 Framework for Climate and Energy policies, demonstrating that: 1 - Re-calibrating the EU ETS requires considering its interactions with complementary climate and energy policies by 2030. Interactions between different policies may induce additional costs vis-a-vis an optimal transition to a low-carbon economy. 2 - Introducing the Market Stability Reserve is necessary to support the ambition of the EU ETS. Guaranteeing MSR effectiveness calls for a governing framework to be established before 2030. 3 - The free allocation mechanism for Phase IV requires more flexible and targeted allocation to sectors most exposed to carbon leakage risk. 4 - Expanding the EU ETS scope with the inclusion of the road transport sector may not necessarily be the most cost-effective way to achieve the GHG 2030 target. 5 - Considering the large scale of ETS auction revenues by 2030, the use of ETS proceeds by the European Commission and by Member States constitutes an increasingly relevant funding source to support decarbonization efforts in non-ETS sectors and to finance R and D in low carbon technologies

X-ray photoemission spectroscopy investigation of CaTiO3:Eu for luminescence property: effect of Eu3+ ion

International Nuclear Information System (INIS)

Wang, Kaichen; Zhao, Baijun; Gao, Lu

2016-01-01

Graphical abstract: The influence on the photoluminescent performance due to the electronic structure change in Eu-doped CaTiO 3 of the specific core-level and valence band spectrum via X-ray photoemission spectroscopy were characterized. - Highlights: • Single phase CaTiO 3 and CaTiO 3 : Eu crystals were prepared under mild hydrothermal method. • Crystal structure, doping level and the relations to their luminescent property were discussed. • Charge compensation mechanism was discussed via valance band spectrum by XPS. - Abstract: Charge compensation of on-site Eu 4f–5d transition that determines the luminescent performance was confirmed with valance band spectrum. Influence of photoelectrons from CaTiO 3 : Eu to the corresponding luminescent performance was discussed based on the crystal structure, doping level and the relations to their luminescent property. This paper is important to further optimize the luminescent performance for improving the efficiency and reducing the cost in light emitting diode industry.

Barriers to the EU Single Services Market

Directory of Open Access Journals (Sweden)

Ol'ga V. Biryukova

2015-01-01

Full Text Available The EU has the most developed liberalization mechanism in services trade within the framework of an economic bloc. The system of supranational institutions, which decisions are binding upon member states, contributes to a high level of liberalization of trade in services in the EU. However, the creation of a single market for services hasn't completed at all. The reasons are following: not all basic principles for single market are fully applied, and a service is a very specific object for international trade. Financial-economic crisis caused a new wave of protectionism in different countries, which has reflected in the preservation of old and the emergence of new barriers to trade in services within the EU. Integration of services in the Union is accompanied by important trade initiatives at the multilateral level. In the World Trade Organization EU countries negotiate a new agreement on trade in services, and offer provisions which providing transparency, deepening liberalization and investor protection for foreign investors in the market, will also complement and foster the Transatlantic Trade and Investment Partnership (TTIP EU - USA. Russia is only the fourth among most important partners of the EU in trade in services. At the same time the European Union remains a key Russian partner in trade in services and in goods. There is a considerable potential for growth in this sphere for both partners.

Concentration quenching of Eu2+ in a thermal-stable yellow phosphor Ca2BO3Cl:Eu2+ for LED application

International Nuclear Information System (INIS)

Zhang Xinguo; Zhang Jilin; Dong Zhiyue; Shi Jianxin; Gong Menglian

2012-01-01

A piece-shaped phosphor Ca 2 BO 3 Cl: Eu 2+ was synthesized by solid-state reaction method. This phosphor exhibited wide absorption in ultra-violet and visible range, and bright yellow emission band centering at 570 nm. The concentration quenching mechanism was verified to be a dipole–dipole interaction, and its critical transfer distance was about 17 Å by both calculated crystal structural method and experimental spectral method. This phosphor has a good thermal stability with a quenching temperature (T 1/2 ) of 200 °C. Yellow and white LEDs were fabricated with this phosphor and near UV chips, and the yellow LED has a high color purity of 97.0% and promising current tolerant property, while the white LED shows a luminous efficiency of 11.68 lm/W. - Highlights: ► Broadband excitable and strong yellow-emitting Ca 2 BO 3 Cl: Eu 2+ phosphor is obtained by solid state reaction. ► Concentration quenching mechanism of Ca 2 BO 3 Cl: Eu 2+ is dipole–dipole interaction. ► Quenching temperature (T 1/2 ) of Ca 2 BO 3 Cl: Eu 2+ is at 200 °C. ► As synthesized material can be used for LED phosphor application.

A Strategy for Synthesizing CaZnOS:Eu{sup 2+} Phosphor and Comparison of Optical Properties with CaS:Eu{sup 2+}

Energy Technology Data Exchange (ETDEWEB)

Qiu, Zhongxian; Rong, Chunying; Zhou, Wenli; Zhang, Jilin; Li, Chengzhi; Yu, Liping; Liu, Shubin; Lian, Shixun, E-mail: shixunlian@gmail.com

2014-01-15

Graphical abstract: Pure-phase CaZnOS:Eu{sup 2+},Ce{sup 3+}phosphor with good chemical and thermal stability can be synthesized by co-doping with Ce{sup 3+} as deoxidizer rather than reduction atmosphere. The broad bluish-green excitation and broad red emission show it is a better phosphor than CaS:Eu{sup 2+} for white LED and for sunlight harvesting of plants. -- Highlights: • Pure-phase phosphor CaZnOS:Eu{sup 2+} was synthesized by co-doping with Ce{sup 3+} as deoxidizer. • Energy transfer mechanism from Ce{sup 3+} to Eu{sup 2+} in CaZnOS host is proposed. • CaZnOS:Eu{sup 2+}, Ce{sup 3+} phosphor has good chemical and thermal stability performance. • The similarities and differences between CaZnOS:Eu{sup 2+} and CaS:Eu{sup 2+} were analyzed. • The green excitation and red emission show superior solar harvesting for plants. -- Abstract: The red-emitting phosphor CaZnOS:Eu{sup 2+} was synthesized from CaCO{sub 3}, ZnS, Eu{sub 2}O{sub 3} and CeCl{sub 3} by controlling the sintering condition. It was found that Ce{sup 3+} ions can play a role of reductant to contribute to the formation of Eu{sup 2+} in CaZnOS matrix under inert protective atmosphere. While the gas flow changed to H{sub 2}/N{sub 2}, the product turned to CaS easily. XRD, photoluminescence spectra, UV–vis and IR absorption spectra were evaluated to investigate the origin of the distinctions of the optical properties and stabilities between the two divalent europium ions doped phosphors CaZnOS:Eu{sup 2+} and CaS:Eu{sup 2+}. The similarities and differences between them were analyzed.

151Eu nuclear resonant inelastic scattering of Eu3Pd20Ge6

International Nuclear Information System (INIS)

Tsutsui, S.; Yoda, Y.; Kobayashi, Y.; Higashitaniguchi, S.; Seto, M.; Kitagawa, J.; Takabatake, T.

2010-01-01

151 Eu nuclear resonant inelastic scattering of Eu 3 Pd 20 Ge 6 . The Eu partial phonon density of states (DOS) in Eu 3 Pd 20 Ge 6 are investigated using 151 Eu nuclear resonance inelastic scattering (NRIS). 151 Eu NRIS was carried out at BL09XU of SPring-8. Significant temperature dependence was found in the partial phonon DOS. Judging from the valence change at the Eu 4a site and the comparison with the ab initio calculation of Eu 3 Pd 20 Ge 6 , the change of the Eu DOS is caused by the electronic states. On the other hand, significant acoustic contribution was found even at the guest site of the Eu ones. In addition, slower average velocity than transverse sound velocity was obtained by Eu partial phonon DOS. Considering that heat is carried by the acoustic phonon in materials, the present results demonstrate that the moderate thermal insulation in Eu 3 Pd 20 Ge 6 is connected with the observation of slow average sound velocity at the Eu sites. (K.F.)

The total neutron cross-sections of 151Eu, 153Eu and Eu below 1 eV

International Nuclear Information System (INIS)

Adib, M.; Maayouf, R.M.A.; Abdel-Kawy, A.; Ashry, A.; Hamouda, I.

1980-12-01

Total neutron cross-section measurements have been carried out for natural Eu and its stable isotopes in the energy range from 3 meV-1 eV. The measurements were performed using two time-of-flight spectrometers installed in front of two of the horizontal channels of the ET-RR-1 reactor. The following results have been obtained: sigmasub(α)( 151 Eu) = 9180+-150 b at 0.0253 eV; sigmasub(α)( 153 Eu) = 375+-20 b at 0.0253 eV; sigmasub(α)(Eu) = 4600+-120 b at 0.0253 eV

Theoretical principles and practice of EU regional policy monitoring

Directory of Open Access Journals (Sweden)

Viktoriia Olіinyk

2014-09-01

Full Text Available The paper explores the practice of monitoring and evaluating regional development policy in the European Union, as well as impact thereof on key indicators of economic and social development both in separate regions and in the EU as a whole. The authors analyzed developments in the regional policy monitoring practice, while also identified peculiarities characteristic of the monitoring process regarding implementation of development programmes and determined main stages of evaluation. The paper specifies basic difficulties in setting up the system of monitoring and evaluating achievement of objectives and coordination of regional programmes. The authors described major disparity in economic and social development of the EU Member States under their development programmes as well as determined main indicators of EU regional disparities. Principles, instruments and mechanisms for monitoring EU regional policy were also defined. The paper analyzes changes in the EU regional development paradigm focusing on the priorities for concentrating financial resources and instruments in terms of cohesion policy

EU Emission Trading - better job second time around?

International Nuclear Information System (INIS)

Schleich, Joachim |; Betz, Regina; Rogge, Karoline |

2007-01-01

The EU Emission Trading Scheme (EU ETS) for CO 2 -emissions from energy and industry installations reflects a paradigm shift towards market-based instruments for environmental policy in the EU. The centerpieces of the EU ETS are National Allocation Plans (NAPs), which individual Member States (MS) design for each phase. NAPs state the total quantity of allowances available in each period (ET-budget) and determine how MS allocate allowances to individual installations. The NAPs thus govern investments and innovation in energy efficient technologies and the energy sector. In terms of distribution, they predetermine winners and losers. In this paper we analyze and evaluate 25 NAPs submitted to the European Commission (EC) for phase 2 (2008-2012) of the EU ETS. At the macro level, we assess whether the submitted ET-budgets are stringent, and whether they imply a cost-efficient split of the required emission reductions between the EU ETS sectors (energy and industry) and the remaining sectors (transportation, tertiary and households). Comparing the submitted ET-budgets with those already approved by the EC suggests that the EC's decisions significantly improved the effectiveness and economic efficiency of the EU ETS. But given the high share of Kyoto Mechanisms companies are allowed to use, the EU ETS is unlikely to require substantial emission reductions within the EU. At the micro level, we assess (across countries and phases) the allocation methods for existing and new installations, for closures and for clean technologies. A comparison of the NAPs for the second phase and the first phase (2005-2007) provides insights into the (limited) adaptability and flexibility of the scheme. The findings provide guidance for the future design of the EU ETS and applications to other sectors and regions

Phosphor thermometry: On the synthesis and characterisation of Y{sub 3}Al{sub 5}O{sub 12}:Eu (YAG:Eu) and YAlO{sub 3}:Eu (YAP:Eu)

Energy Technology Data Exchange (ETDEWEB)

Kissel, T. [Fachgebiet Reaktive Strömungen und Messtechnik (RSM), Center of Smart Interfaces (CSI), Technische Universität Darmstadt, Petersenstraße 32, 64287 Darmstadt (Germany); Brübach, J., E-mail: bruebach@ekt.tu-darmstadt.de [Fachgebiet Reaktive Strömungen und Messtechnik (RSM), Center of Smart Interfaces (CSI), Technische Universität Darmstadt, Petersenstraße 32, 64287 Darmstadt (Germany); Euler, M. [Fachgebiet Reaktive Strömungen und Messtechnik (RSM), Center of Smart Interfaces (CSI), Technische Universität Darmstadt, Petersenstraße 32, 64287 Darmstadt (Germany); Frotscher, M.; Litterscheid, C.; Albert, B. [Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Petersenstraße 18, 64287 Darmstadt (Germany); Dreizler, A. [Fachgebiet Reaktive Strömungen und Messtechnik (RSM), Center of Smart Interfaces (CSI), Technische Universität Darmstadt, Petersenstraße 32, 64287 Darmstadt (Germany)

2013-07-15

With regard to phosphor thermometry, the materials Y{sub 3}Al{sub 5}O{sub 12}:Eu (YAG:Eu) and YAlO{sub 3}:Eu (YAP:Eu) were synthesised and characterised in order to substitute the commonly used thermographic phosphor Y{sub 2}O{sub 3}:Eu, whose temperature sensitive luminescence lifetime exhibits a strong and most often undesirable cross-sensitivity to the oxygen concentration of the surrounding gas phase. The synthesis is outlined in detail and the crystallographic structure was characterised by X-ray diffraction. In a second step, the luminescence properties following pulsed UV laser excitation were determined. In this context, the emission spectra and the temperature lifetime characteristics were monitored. For Y{sub 3}Al{sub 5}O{sub 12}:Eu and YAlO{sub 3}:Eu, temperature sensitive ranges of 1000 K–1470 K and 850 K–1300 K were identified. Contrary to Y{sub 2}O{sub 3}:Eu, both materials do show much lower cross-sensitivities to the oxygen concentration of the surrounding gas phase. - Highlights: ► Y{sub 3}Al{sub 5}O{sub 12}:Eu and YAlO{sub 3}:Eu were synthesised and characterised. ► The synthesis is outlined and the crystallographic structure was characterised. ► Emission spectra and the temperature lifetime characteristics were monitored. ► Compared to Y{sub 2}O{sub 3}:Eu lower sensitivities to the oxyg. conc. of the gas phase emerged.

Preparation, photoluminescent properties and luminescent dynamics of BaAlF5:Eu2+ nanophosphors

International Nuclear Information System (INIS)

Zhang, Wei; Hua, Ruinian; Liu, Tianqing; Zhao, Jun; Na, Liyan; Chen, Baojiu

2014-01-01

Graphical abstract: Rice-shaped BaAlF 5 :Eu 2+ nanophosphors were synthesized via one-pot hydrothermal process. The as-prepared BaAlF 5 :Eu 2+ are composed of many particles with an average diameter of 40 nm. When excited at 260 nm, the sharp line emission located at 361 nm of Eu 2+ was observed. The optimum doping concentration of Eu 2+ was confirmed to be 5 mol%. The strong ultraviolet emission of Eu 2+ ions in BaAlF 5 :Eu 2+ nanoparticles suggests that these nanoparticles may have potential applications for sensing, solid-state lasers and spectrometer calibration. - Highlights: • BaAlF 5 :Eu 2+ nanophosphors were synthesized via a mild hydrothermal process. • The Van and Huang models were used to research the mechanism of concentration quenching. • The optimum doping concentration of Eu2+ was confirmed to be 5 mol%. - Abstract: Eu 2+ -doped BaAlF 5 nanophosphors were synthesized via a facile one-pot hydrothermal method. The final products were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and photoluminescence (PL) spectroscopy. XRD results showed that the prepared samples are single-phase. The FE-SEM and TEM images indicated that the prepared BaAlF 5 :Eu 2+ nanophosphors are composed of many rice-shaped particles with an average diameter of 40 nm. When excited at 260 nm, BaAlF 5 :Eu 2+ nanophosphors exhibit the sharp line emissions of Eu 2+ at room temperature. The optimum doping concentration of Eu 2+ was confirmed to be 5 mol%. The Van and Huang models were used to study the mechanism of concentration quenching and the electric dipole–dipole interaction between Eu 2+ can be deduced to be a dominant for quenching fluorescence in BaAlF 5 :Eu 2+ nanophosphors. The strong ultraviolet emission of Eu 2+ in BaAlF 5 :Eu 2+ nanophosphors suggests that these nanoparticles may have potential applications for sensing, spectrometer calibration and solid-state lasers

EU Budgetary Dynamics

DEFF Research Database (Denmark)

Citi, Manuele

2013-01-01

In this article I study the long-term evolution of the main categories of expenditure of the European Union (EU) budget (1984-2011). The aim is to assess the extent to which the EU is affected by a structural form of policy inertia, and to investigate the general pattern of policy stability...... and change in the EU in light of the two models of policy dynamics currently existing in the literature: the incrementalist model and the punctuated equilibrium model. The analysis of long series of original data extracted from the EU budget shows that EU policies do not evolve following an incrementalist...

EU Energy Law. Volume 4. The EU Greenhouse Gas Emissions Trading Scheme

International Nuclear Information System (INIS)

Delbeke, J.; Hartridge, O.; Lefevere, J.; Meadows, D.; Runge-Metzger, A.; Slingenberg, Y.; Vainio, M.; Vis, P.; Zapfel, P.

2006-06-01

Gives valuable insights in the why's, how's, trade-offs, and critical design choices of the Emission Trading System of the European Union (EU ETS). The chapters deal with (1) The EU ETS: the result of a decade of policy action on the economic dimension of EU environmental policy; (2) The international climate policy developments of the 1990s: UNFCCC, the Kyoto Protocol, the Marrakech Agreements and the EU's Kyoto ratification decision; (3) Emissions trading: What is it? Design options and misconceptions; (4) The EU ETS Directive 2003/87/EEC explained; (5) The EU ETS Linking Directive explained; (6) The economic efficiency benefits of the EU ETS; (7) The NAP I experience; (8) The key importance of the Registry Regulation and of solid monitoring and verification; and (9) The potential role of the EU ETS for the elaboration of the post-2012 international climate regime. Conclusions are in chapter 10

Optical spectroscopy and optical waveguide fabrication in Eu{sup 3+} and Eu{sup 3+}/Tb{sup 3+} doped zinc–sodium–aluminosilicate glasses

Energy Technology Data Exchange (ETDEWEB)

Caldiño, U., E-mail: cald@xanum.uam.mx [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, P.O. Box 55-534, 09340 México D.F. (Mexico); Speghini, A. [Dipartimento di Biotecnologie, Università di Verona and INSTM, UdR Verona, Strada Le Grazie 15, I-37314 Verona (Italy); Istituto di Fisica Applicata Nello Carrara, C.N.R., Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze) (Italy); Berneschi, S. [Istituto di Fisica Applicata Nello Carrara, C.N.R., Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze) (Italy); Bettinelli, M. [Dipartimento di Biotecnologie, Università di Verona and INSTM, UdR Verona, Strada Le Grazie 15, I-37314 Verona (Italy); Brenci, M. [Istituto di Fisica Applicata Nello Carrara, C.N.R., Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze) (Italy); Pasquini, E. [Istituto di Fisica Applicata Nello Carrara, C.N.R., Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze) (Italy); Dipartimento di Fisica e Astronomia, Università di Firenze, Via Sansone 1, 50019 Sesto Fiorentino (Firenze) (Italy); Pelli, S. [Istituto di Fisica Applicata Nello Carrara, C.N.R., Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze) (Italy); Righini, G.C. [Istituto di Fisica Applicata Nello Carrara, C.N.R., Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze) (Italy); Museo Storico della Fisica e Centro Studi e Ricerche “Enrico Fermi”, Piazza del Viminale 2, 00184 Roma (Italy)

2014-03-15

Optical and spectroscopic properties of 2.0% Eu(PO{sub 3}){sub 3} singly doped and 5.0% Tb(PO{sub 3}){sub 3}–2.0% Eu(PO{sub 3}){sub 3} codoped zinc–sodium–aluminosilicate glasses were investigated. Reddish-orange light emission, with x=0.64 and y=0.36 CIE1931 chromaticity coordinates, is obtained in the europium singly doped glass excited at 393 nm. Such chromaticity coordinates are close to those (0.67,0.33) standard of the National Television System Committee for the red phosphor. When the sodium–zinc–aluminosilicate glass is co-doped with Tb{sup 3+} and Eu{sup 3+}, reddish-orange light emission, with (0.61,0.37) CIE1931 chromaticity coordinates, is obtained upon Tb{sup 3+} excitation at 344 nm. This reddish-orange luminescence is generated mainly by {sup 5}D{sub 0}→{sup 7}F{sub 1} and {sup 5}D{sub 0} →{sup 7}F{sub 2} emissions of Eu{sup 3+}, europium being sensitized by terbium through a non-radiative energy transfer. From an analysis of the Tb{sup 3+} emission decay curves it is inferred that the Tb{sup 3+}→Eu{sup 3+} energy transfer might take place between Tb{sup 3+} and Eu{sup 3+} clusters through a short-range interaction mechanism, so that an electric dipole–quadrupole interaction appears to be the most probable transfer mechanism. The efficiency of this energy transfer is about 62% upon excitation at 344 nm. In the singly doped and codoped glasses multimode optical waveguides were successfully produced by Ag{sup +}–Na{sup +} ion exchange, and they could be characterized at various wavelengths. -- Highlights: • Reddish-orange light emission can be generated from Tb{sup 3+} and Eu{sup 3+} codoped zinc–sodium–aluminosilicate glasses excited at 344 nm. • The Eu{sup 3+} is sensitized by Tb{sup 3+} through a non-radiative energy transfer. • Highly multimode waveguides can be fabricated by diluted silver–sodium exchange. • This type of AlGaN LEDs pumped glass phosphors might be useful for generation of reddish-orange light.

The effects of Eu-concentrations on the luminescent properties of SrF2:Eu nanophosphor

International Nuclear Information System (INIS)

Yagoub, M.Y.A.; Swart, H.C.; Noto, L.L.; O’Connel, J.H.; Lee, M.E.; Coetsee, E.

2014-01-01

SrF 2 :Eu nanophosphors were successfully synthesized by the hydrothermal method. The structure of the nanophosphors was investigated with x-ray diffraction. The average crystallite size calculated using the Scherrer equation was in the range of 7.0 nm. The photoluminescence of Eu doped as-prepared SrF 2 nanophosphors were studied using different excitation sources. The samples showed emission from both the Eu oxidation states, Eu 2+ and Eu 3+ . At low Eu concentrations the emission from Eu 2+ centered at 416 nm was more dominant. While the narrow band of Eu 3+ emission intensity increased with an increase in the Eu concentration. High resolution x-ray photoelectron spectroscopy results indicated that the Eu was indeed in both Eu 2+ and Eu 3+ valance states. The presence of Eu 2+ and Eu 3+ in the system largely enhanced the response of the Eu 3+ under ultraviolet excitation. The time of flight-secondary ion mass spectrometry results suggested that the energy transfer between two ions was likely to occur. The relative photoluminescence intensity of the Eu 2+ rapidly decreased with an increasing laser beam irradiating time. This result would make the current Eu 2+ doped SrF 2 samples unsuitable candidates for several applications, such as white light-emitting diodes and wavelength conversion films for silicon photovoltaic cells. - Highlights: • SrF 2 : Eu nanophosphors were successfully synthesised (hydrothermal technique). • PL and XPS results showed enhanced absorption response of Eu 3+ UV excitation. • Eu concentrations more than 5 mol% improved fluorescence emission. • TOF-SIMS results suggested that the energy transfer from Eu 2+ to Eu 3+ is dominant

Analysis of the EU policy package on climate change and renewables

International Nuclear Information System (INIS)

Capros, Pantelis; Mantzos, Leonidas; Parousos, Leonidas; Tasios, Nikolaos; Klaassen, Ger; Van Ierland, Tom

2011-01-01

In 2009 the EU decided to reduce greenhouse gas emissions at least by 20% in 2020 compared to 1990 and to supply 20% of energy needs by 2020 from renewable energy sources. This paper uses an energy model coupled with a non-CO 2 greenhouse gas model to assess the range of policy options that were debated to meet both targets. Policy options include trading of renewable targets, carbon trading in power plants and industry and the use of the Clean Development Mechanism to improve cost-efficiency. The models also examined fairness by analysing the distribution of emission reduction in the non-emission trading sector, the distribution of CO 2 allowances in the emission trading sector and the reallocation of renewable targets across Member States. The overall costs of meeting both targets range from 0.4% to 0.6% of GDP in 2020 for the EU as a whole. The redistribution mechanisms employed significantly improve fairness compared to a cost-effective solution. - Research highlights: → Meeting the EU's greenhouse gas and renewable targets costs 0.4-0.6% of GDP. → Trading national targets for renewable energy reduces costs. → Carbon trading in power plants and industry and CDM also lowers costs. → The redistribution mechanisms agreed by the EU significantly improve fairness.

The total neutron cross-sections of 151Eu, 153Eu and Eu below 1 eV

International Nuclear Information System (INIS)

Adib, M.; Maayouf, R.M.A.; Abdel-Kawy, A.; Ashry, A.; Hamouda, I.

1981-01-01

Total neutron cross-section measurements have been carried out for natural Eu and its stable isotopes in the energy range from 3 meV to 1 eV. The measurements were performed using two time-of-flight spectrometers installed in front of two of the horizontal channels of the ET-RR-1 reactor. The following results have been obtained: sigmasub(a) ( 151 Eu) = (9180 +- 150) b at 0.0253 eV, sigmasub(s) ( 153 Eu) = (375 +- 20) b at 0.0253 eV, sigmasub(d) (Eu) = (4600 +- 120) b at 0.0253 eV. The contribution of the resonance to the total neutron cross-sections, in the thermal region, was calculated using the single-level Breit-Wigner formula. (orig.)

Energy transfer induced Eu{sup 3+} photoluminescence enhancement in tellurite glass

Energy Technology Data Exchange (ETDEWEB)

Stambouli, W. [Laboratoire des Materiaux Mineraux et leurs Applications, Centre National de Recherches en Sciences des Materiaux, B.P. 95, Hammam-Lif 2050 (Tunisia); Elhouichet, H., E-mail: habib.elhouichet@fst.rnu.tn [Laboratoire des Materiaux Mineraux et leurs Applications, Centre National de Recherches en Sciences des Materiaux, B.P. 95, Hammam-Lif 2050 (Tunisia); Departement de Physique, Faculte des Sciences de Tunis, Universite de Tunis-ElManar ElManar 2092, Tunis (Tunisia); Gelloz, B. [Graduate School of Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Nakacho, Koganei, 184-8588 Tokyo (Japan); Ferid, M. [Laboratoire des Materiaux Mineraux et leurs Applications, Centre National de Recherches en Sciences des Materiaux, B.P. 95, Hammam-Lif 2050 (Tunisia); Koshida, N. [Graduate School of Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Nakacho, Koganei, 184-8588 Tokyo (Japan)

2012-01-15

In this work, structural, thermal and optical properties of Eu{sup 3+} doped TeO{sub 2}-La{sub 2}O{sub 3}-TiO{sub 2} glass were investigated. The differential scanning calorimetry (DSC) measurements reveal an important stability factor {Delta}T=143.52 K, which indicates the good thermal and mechanical stabilities of tellurite glass. From the absorption spectrum, the optical band gap was found to be direct with E{sub g}=3.23 eV. The temperature dependences of photoluminescence (PL) properties of Eu-doped and Eu-Tb codoped tellurite glass are investigated. As the temperature increases from 7 to 300 K, both the PL intensity and the PL lifetime relative to the {sup 5}D{sub 2}{yields}{sup 7}F{sub 0} are nearly constant below 230 K and then an enhancement takes place. This anomalous feature is attributed to the thermally activated carrier transfer process from charged intrinsic defects states to Eu{sup 3+} energy levels. By co-doping tellurite glasses with Eu and Tb, a strong Eu{sup 3+} PL enhancement is shown due to excitation transfer from Tb{sup 3+} and intrinsic defects to Eu ions. - Highlights: > TeO{sub 2}-La{sub 2}O{sub 3}-TiO{sub 2} glass doped Eu{sup 3+} with good thermal stability elaborated. > PL evolution of Eu{sup 3+} with temperature shows a non-conventional behavior. > Thermally activated carrier transfer from intrinsic defects states to Eu{sup 3+} shown. > Strong Eu{sup 3+} PL enhancement is shown in Eu-Tb codoped glass.

Synthesis and tunable luminescent properties of Eu-doped Ca2NaSiO4F – Coexistence of the Eu2+ and Eu3+ centers

Directory of Open Access Journals (Sweden)

Mubiao Xie

Full Text Available Novel phosphors Ca2NaSiO4F:Eu were synthesized successfully by the conventional solid-state method in CO atmosphere, and their spectroscopic properties in UV−vis region were investigated. The photoluminescence properties show that Eu3+ ions were partially reduced to Eu2+ in Ca2NaSiO4F. As a result of radiation and re-absorption energy transfer from Eu2+ to Eu3+, both Eu2+ bluish-green emission at around 520 nm and Eu3+ red emission are observed in the emission spectra under the n-UV light excitation. Furthermore, the ratio between Eu2+ and Eu3+ emissions varies with increasing content of overall Eu. Because relative intensity of the red component from Eu3+ became systematically stronger, white light emission can be realized by combining the emission of Eu2+ and Eu3+ in a single host lattice under n-UV light excitation. These results indicate that the Ca2NaSiO4F:Eu phosphors have potential applications as a n-UV convertible phosphor for light-emitting diodes. Keywords: Phosphors, Luminescence, White LED, Optical materials

26 CFR 1.414(r)-6 - Qualified separate line of business-administrative scrutiny requirement-individual determinations.

Science.gov (United States)

2010-04-01

...-administrative scrutiny requirement-individual determinations. 1.414(r)-6 Section 1.414(r)-6 Internal Revenue... Pension, Profit-Sharing, Stock Bonus Plans, Etc. § 1.414(r)-6 Qualified separate line of business... determined under § 1.414(r)-3) that does not satisfy any of the safe harbors in § 1.414(r)-5 for a testing...

Strategic neighbourhood: EU-Europe versus EU-East

OpenAIRE

Rahr, Alexander

2004-01-01

"Russia and the EU are the strongest actors on the European continent of the 21st century. Will the strategic partnership between the EU and Russia unite the entire continent under a 'common European home' or will the continent be split in two? Russia joining the rest of Europe is set to proceed initially through the Energy Alliance." (author's abstract)

Rebalancing EU Interest Representation? Assocative Democracy and EU funding of Civil Society Organizations

NARCIS (Netherlands)

Sanchez Salgado, R.

2014-01-01

European Union (EU) funding of civil society organizations (CSOs) is a substantial and important part of EU governance, but study of such funding is scarce and theoretically underdeveloped. To fill this gap, this article analyzes the main features of EU funding of CSOs and its effects on the EU

The effects of Eu-concentrations on the luminescent properties of SrF{sub 2}:Eu nanophosphor

Energy Technology Data Exchange (ETDEWEB)

Yagoub, M.Y.A.; Swart, H.C.; Noto, L.L. [Department of Physics, University of the Free State, PO Box 339, Bloemfontein ZA9300 (South Africa); O’Connel, J.H.; Lee, M.E. [Department of Physics and Centre for HRTEM, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth ZA6031 (South Africa); Coetsee, E., E-mail: CoetseeE@ufs.ac.za [Department of Physics, University of the Free State, PO Box 339, Bloemfontein ZA9300 (South Africa)

2014-12-15

SrF{sub 2}:Eu nanophosphors were successfully synthesized by the hydrothermal method. The structure of the nanophosphors was investigated with x-ray diffraction. The average crystallite size calculated using the Scherrer equation was in the range of 7.0 nm. The photoluminescence of Eu doped as-prepared SrF{sub 2} nanophosphors were studied using different excitation sources. The samples showed emission from both the Eu oxidation states, Eu{sup 2+} and Eu{sup 3+}. At low Eu concentrations the emission from Eu{sup 2+} centered at 416 nm was more dominant. While the narrow band of Eu{sup 3+} emission intensity increased with an increase in the Eu concentration. High resolution x-ray photoelectron spectroscopy results indicated that the Eu was indeed in both Eu{sup 2+} and Eu{sup 3+} valance states. The presence of Eu{sup 2+} and Eu{sup 3+} in the system largely enhanced the response of the Eu{sup 3+} under ultraviolet excitation. The time of flight-secondary ion mass spectrometry results suggested that the energy transfer between two ions was likely to occur. The relative photoluminescence intensity of the Eu{sup 2+} rapidly decreased with an increasing laser beam irradiating time. This result would make the current Eu{sup 2+} doped SrF{sub 2} samples unsuitable candidates for several applications, such as white light-emitting diodes and wavelength conversion films for silicon photovoltaic cells. - Highlights: • SrF{sub 2}: Eu nanophosphors were successfully synthesised (hydrothermal technique). • PL and XPS results showed enhanced absorption response of Eu{sup 3+} UV excitation. • Eu concentrations more than 5 mol% improved fluorescence emission. • TOF-SIMS results suggested that the energy transfer from Eu{sup 2+} to Eu{sup 3+} is dominant.

Reform of the EU's climate policy. Small step or big hit?; Reform der EU-Klimapolitik. Kleiner Schritt oder grosser Wurf?

Energy Technology Data Exchange (ETDEWEB)

Janssen, Matthias; Peichert, Patrick; Perner, Jens; Riechmann, Christoph [Frontier Economics Ltd., Koeln (Germany)

2015-11-15

Emissions trading listed as a flexible mechanism under the Kyoto Protocol is regarded as a market economy way in climate protection. Since 2005 the European Emissions Trading System (EU ETS) is the central climate policy instrument for reducing the emissions of greenhouse gases, in particular for carbon dioxide (CO{sub 2}). For years, however, the CO{sub 2} price is too low to direct the politically and socially targeted technical innovations in the electricity sector and the industry. The article analyses the temporary and structural causes of this problem, highlights the EU's reform efforts and points to areas of activity, the basis of which the EU ETS may act in the future as a central instrument for climate protection in the European Union. [German] Der im Kyoto-Protokoll als flexibler Mechanismus aufgefuehrte Emissionshandel gilt als marktwirtschaftlicher Weg in den Klimaschutz. Das Europaeische Emissionshandelssystem (EU ETS) ist seit 2005 das zentrale klimapolitische Instrument zur Senkung des Ausstosses von Treibhausgasen, insbesondere fuer Kohlenstoffdioxid (CO{sub 2}). Seit Jahren ist der CO{sub 2}-Preis jedoch zu gering, um die politisch und gesellschaftlich angestrebten technischen Innovationen im Stromsektor und der Industrie zu lenken. Der Artikel untersucht die temporaeren und strukturellen Ursachen dieses Problems, beleuchtet die Reformbestrebungen der EU und zeigt Handlungsfelder auf, anhand derer das EU ETS auch in Zukunft als zentrales Instrument fuer Klimaschutz in der Europaeischen Union fungieren kann.

Legal aspects of the EU policy on irregular immigration

Directory of Open Access Journals (Sweden)

Voinikov Vadim

2015-12-01

Full Text Available This article addresses the issues pertaining to the adoption and development of legislation on irregular migration in the context of uncontrolled growth in the number of immigrants from North Africa and the Middle East to the EU. The article attempts at studying the EU legislation on irregular migration, classifying it, and analysing the prospects of EU migration legislation in the light of an increase in irregular immigration into the EU. The author systematises, classifies the current EU legislation on irregular immigration, and analyses the conditions, in which this legislation was developed. Using the legislation analysis method, the author proposes the following system of EU legislation on irregular immigration: rules preventing assistance to irregular immigration, rules preventing employment of irregular immigrants, rules on the return of irregular migrants and readmission, rules on border control, and rules on collaboration with third countries. The author pays special attention to analysing the current state of irregular immigration to the EU, which was dubbed the ‘greatest migration crisis in Europe’. The conclusion is that the European Union succeeded in the development of pioneering legislation on irregular immigration, which can serve as the basis for reception by other states. However, changes in the political and economic situation in the EU’s southern borderlands made the current legal mechanisms incapable of withstanding new threats. It necessitates a radical reform of the legislation on irregular immigration.

New reddish-orange and greenish-yellow light emitting phosphors: Eu{sup 3+} and Tb{sup 3+}/Eu{sup 3+} in sodium germanate glass

Energy Technology Data Exchange (ETDEWEB)

Álvarez, E. [Departamento de Física, Universidad de Sonora (UNISON), Boulevard Luis Encinas y Rosales s/n, Hermosillo 83000, Sonora (Mexico); Zayas, Ma. E. [Departamento de Investigación en Física, Universidad de Sonora (UNISON), Boulevard Luis Encinas y Rosales s/n, Hermosillo 83000, Sonora (Mexico); Alvarado-Rivera, J. [Departamento de Física, Universidad de Sonora (UNISON), Boulevard Luis Encinas y Rosales s/n, Hermosillo 83000, Sonora (Mexico); Félix-Domínguez, F. [Departamento de Física, Universidad de Sonora (UNISON), Boulevard Luis Encinas y Rosales s/n, Hermosillo 83000, Sonora (Mexico); Centro de investigación en Materiales Avanzados, S.C. Miguel de Cervantes 120, Complejo industrial Chihuahua, Chihuahua 31109, Chihuahua (Mexico); Duarte-Zamorano, R.P. [Departamento de Física, Universidad de Sonora (UNISON), Boulevard Luis Encinas y Rosales s/n, Hermosillo 83000, Sonora (Mexico); Caldiño, U., E-mail: cald@xanum.uam.mx [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, PO Box 55-534, México City 09340, Distrito Federal (Mexico)

2014-09-15

A spectroscopic analysis of sodium germanate glasses activated with Eu{sup 3+}, Tb{sup 3+} and Eu{sup 3+}/Tb{sup 3+} is performed from their photoluminescence spectra and decay times. In the Eu{sup 3+}-singly doped glass reddish-orange light emission, with x=0.64 and y=0.35 CIE1931 chromaticity coordinates, is obtained upon Eu{sup 3+} excitation at 393 nm. Such chromaticity coordinates are close to those (0.67, 0.33) proposed by the National Television Standard Committee for the red phosphor. When the sodium germanate glass is co-doped with Tb{sup 3+} and Eu{sup 3+} greenish-yellow light emission, with (0.41, 0.46) CIE1931 chromaticity coordinates, is obtained upon Tb{sup 3+} excitation at 344 nm. Such greenish-yellow luminescence is due mainly to the terbium {sup 5}D{sub 4}→{sup 7}F{sub 6,5} and europium {sup 5}D{sub 0}→{sup 7}F{sub 1,2} emissions, Eu{sup 3+} being sensitized by Tb{sup 3+} through a non-radiative energy transfer. The non-radiative nature of this energy transfer is inferred from the increase in the decay rate of the Tb{sup 3+} emission when the glass is co-doped with Eu{sup 3+}. From an analysis of the Tb{sup 3+} emission decay time curves it is inferred that such energy transfer might take place between Tb{sup 3+} and Eu{sup 3+} clusters through a short-range interaction mechanism. - Highlights: • Sodium germanate glasses are optically activated with Eu{sup 3+} (GNE) and Tb{sup 3+}/Eu{sup 3+} (GNTE). • Reddish-orange light (0.64, 0.35) is generated by GNE pumped with 393 nm light. • Greenish-yellow light (0.41, 0.46) is generated by GNTE pumped with 344 nm light. • Non-radiative energy transfer Tb{sup 3+}→Eu{sup 3+} takes place in GNTE.

Economic disparities between EU states and regions

Directory of Open Access Journals (Sweden)

Ion CIUREA

2010-05-01

Full Text Available EU has 27 Member States representing a community and a market of 493million citizens, which creates further economic and social disparities between thestates and their 271 regions. In a region in four, the GDP (gross domestic product percapita is 75% below the average for the EU-27. Based on the concepts of solidarity andcohesion, regional policy of the European Union favors reducing structural disparitiesbetween EU regions, the balanced development of the community and promoting aneffective equality of opportunity between people. Over the past 50 years, Europeancooperation has helped build highways, sewage plants, bridges, laboratories forbiotechnology. She helped to revive urban areas and neglected activities, throughcountless projects in the poorest regions of the Union.. Two key values: solidarity andcohesion, underlying these projects and the regional policy of the European Union. Theeconomic, social and territorial cohesion will always be at the heart of Europe Strategy2020, a key mechanism for achieving the priorities for a smart growth, sustainable andinclusive in the Member States and regions.

Enlarging the EU's internal energy market: Why would third countries accept EU rule export?

International Nuclear Information System (INIS)

Prange-Gstoehl, Heiko

2009-01-01

Why would countries without a membership perspective seek integration into the EU's internal energy market? One major element of the EU's external energy policy is the export of EU energy norms and regulations to neighbourhood countries and beyond. A core legal instrument the EU uses in this context is the Energy Community Treaty (ECT). The ECT goes both geographically and regarding its depth significantly beyond neighbourhood or association policies, addressing potentially also countries in the 'far neighbourhood' and aiming at the creation of a Single Market for energy with these countries. While, however, EU candidate countries are obliged to adopt the 'acquis' before accessing the EU and therefore comply to EU rules already before they enter the Club, I argue that countries with no or only a vague membership perspective - i.e. countries where the EU cannot apply the 'conditionality' - approach (e.g., ENP countries)-aim at deeper integration with the EU because they are either eager to demonstrate their capability and potential to become part of the Club, they seek greater independence from a regional hegemon or they envisage significant economic gains as common norms, rules and standards are likely to increase economic exchange with the EU.

Economic relations EU-China - the mechanism that the European Union outlines the position of the economic actor

Directory of Open Access Journals (Sweden)

Loredana JITARU

2017-10-01

Full Text Available Both the EU and China face a number of challenges. The EU has reached the pinnacle of international identity and is going through a rather difficult process of rethinking it. Regarding China, this actor goes through a phase of rethinking its economic growth model, namely the transition from an economy based, in greater extent on exports and investment to an economic growth based on stimulating domestic consumption. In this context, in order to meet the challenges of the third millennium and beyond, the two actors need to strengthen their cooperative relations as they are vital in solving the challenges of this millennium. This paper aims to provide an overview of EU-China economic relations and to analyse the impact of these relations on the EU economy.

Total neutron cross-sections of /sup 151/Eu, /sup 153/Eu and Eu below 1 eV

Energy Technology Data Exchange (ETDEWEB)

Adib, M.; Maayouf, R.M.A.; Abdel-Kawy, A.; Ashry, A.; Hamouda, I.

1981-01-01

Total neutron cross-section measurements have been carried out for natural Eu and its stable isotopes in the energy range from 3 meV to 1 eV. The measurements were performed using two time-of-flight spectrometers installed in front of two of the horizontal channels of the ET-RR-1 reactor. The following results have been obtained: sigmasub(a) (/sup 151/Eu) = (9180 +- 150) b at 0.0253 eV, sigmasub(s) (/sup 153/Eu) = (375 +- 20) b at 0.0253 eV, sigmasub(d) (Eu) = (4600 +- 120) b at 0.0253 eV. The contribution of the resonance to the total neutron cross-sections, in the thermal region, was calculated using the single-level Breit-Wigner formula.

Cooperation mechanisms of the EU renewable energy directive and flexible mechanisms of the Kyoto Protocol: comparison and lessons learnt. Working paper

Energy Technology Data Exchange (ETDEWEB)

Frieden, Dorian; Tuerk, Andreas; Steiner, Daniel

2013-07-15

This working paper discusses similarities and differences between the cooperation mechanisms of the EU renewable energy directive (RES directive) and the flexible mechanisms of the Kyoto Protocol. The cooperation mechanisms allow the (virtual) trade of renewable energy and were introduced with the RES directive to provide Member States (MS) with greater flexibility to achieve their national targets for renewable energy sources (RES). A similar kind of flexibility is known from the flexible mechanisms of the Kyoto Protocol which aim at the cost efficient achievement of emission reduction targets. Lessons learned from the Kyoto mechanisms may allow conclusions to be drawn on the design and implementation of the renewable energy cooperation mechanisms. This paper first gives an overview of the cooperation mechanisms regarding their potential, advantages and disadvantages, barriers and preconditions. This is followed by a brief explanation of and a systematic comparison with the flexible mechanisms of the Kyoto Protocol – Joint Implementation (JI); Clean Development Mechanism (CDM); and International Emissions Trading (IET). A gamut of factors influenced the success of the Kyoto mechanisms in general and in specific national contexts. Therefore, it is not possible to directly transfer past experiences with the Kyoto mechanisms to the capability of specific nations to make use of the renewable energy cooperation mechanisms. A comparison of specific features, such as the mechanism type (transfer, project-based, support scheme), price building and specific barriers can, however, help anticipate the possible dynamics and challenges of the cooperation mechanisms. Experiences with the Kyoto mechanisms show that predictions based on supply-demand analysis were valid only to a limited extent and that specific factors such as institutional capacity constraints or legal uncertainties delayed or prevented the use of the mechanisms in some cases. Similarly, for the cooperation

Eestimaa.eu kuulub lätlasele ja riik.eu hollandlasele / Mikk Salu

Index Scriptorium Estoniae

Salu, Mikk, 1975-

2006-01-01

Zone Medias eu domeeninimesid registreeriva Jaanus Puttingu hinnangul on Eesti riik olnud passiivne EL-i domeeninime .eu sisaldavate lehekülgede kaitsmisel, sajad Eestile olulised domeeninimed on juba nii siinsete kui ka piiritaguste inimeste käes. Lisa: Rahvaliit.eu kuulub kinnisvaraportaalile

Preparation of EuSe nanoparticles from Eu(III) complex containing selenides

International Nuclear Information System (INIS)

Adachi, Taka-aki; Tanaka, Atsushi; Hasegawa, Yasuchika; Kawai, Tsuyoshi

2008-01-01

The EuSe nanoparticles were prepared by the thermal reduction of Europium nitrate with new organic selenium compound, tetraphenylphosphonium diphenylphosphinediselenide (PPh 4 )(Se 2 P(C 6 H 5 ) 2 ), for the first time. EuSe nanoparticles were identified by the X-ray diffraction (XRD), the transmission electron microscope (TEM) and the energy dispersive X-ray spectroscopy (EDX) measurements. The average size of the EuSe nanoparticles was found to be 19 nm. The energy gap in EuSe nanoparticles of 19 nm was estimated by edge of absorption band, giving the energy gap of 1.86 eV

Induced spin-polarization of EuS at room temperature in Ni/EuS multilayers

Energy Technology Data Exchange (ETDEWEB)

Poulopoulos, P., E-mail: poulop@upatras.gr [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Materials Science Department, University of Patras, 26504 Patras (Greece); Goschew, A.; Straub, A.; Fumagalli, P. [Institut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Kapaklis, V.; Wolff, M. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Delimitis, A. [Chemical Process and Energy Resources Institute (CPERI), Centre for Research and Technology Hellas (CERTH), 57001 Thermi, Thessaloniki (Greece); Wilhelm, F.; Rogalev, A. [European Synchrotron Radiation Facility (ESRF), B.P.220, 38043 Grenoble (France); Pappas, S. D. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden)

2014-03-17

Ni/EuS multilayers with excellent multilayer sequencing are deposited via e-beam evaporation on the native oxide of Si(100) wafers at 4 × 10{sup −9} millibars. The samples have very small surface and interface roughness and show sharp interfaces. Ni layers are nanocrystalline 4–8 nm thick and EuS layers are 2–4 nm thick and are either amorphous or nanocrystalline. Unlike for Co/EuS multilayers, all Eu ions are in divalent (ferromagnetic) state. We show a direct antiferromagnetic coupling between EuS and Ni layers. At room temperature, the EuS layers are spin-polarized due to the proximity of Ni. Therefore, Ni/EuS is a candidate for room-temperature spintronics applications.

Thermodynamic assessment of EuBr2 unary and LiBr-EuBr2 and NaBr-EuBr2 binary systems

International Nuclear Information System (INIS)

Gong, Weiping; Gaune-Escard, Marcelle

2009-01-01

As a basis for the design and development of molten salt mixtures, thermodynamic calculations of the phase diagrams and thermodynamic properties were carried out on the EuBr 2 unary and LiBr-EuBr 2 and NaBr-EuBr 2 binary systems over a wide temperature and composition range, respectively. The Gibbs energy of EuBr 2 was evaluated using an independent polynomial to fit the experimental heat capacity, the thermodynamic parameters for each phase in the LiBr-EuBr 2 and NaBr-EuBr 2 systems were optimized by using available experimental information on phase diagrams. A regular substitutional solution model for the liquid phase and Neumann-Kopp rule for the stoichiometric compound LiEu 2 Br 5 were adopted to reproduce the experimental data with reasonable excess Gibbs energy. Comparisons between the calculated phase diagrams and thermodynamic quantities show that all reliable experimental information is satisfactorily accounted for by the present thermodynamic description. Some thermodynamic properties were predicted to check the suitability of the present calculation.

Byg EU om

DEFF Research Database (Denmark)

Nedergaard, Peter

2017-01-01

Der argumenteres for en række påstande vedrørende en mulig ombygning af EU med henblik på at håndtere den krise, som unionen står i. Grundlæggende for dem alle er, at enten ombygges EU på disse områder, eller også smuldrer samarbejdet. Et internationalt samarbejde som EU kollapser ikke; det mister...

EU Enlargement

DEFF Research Database (Denmark)

Pedersen, Peder J.; Pytlikova, Mariola

We look at migration flows from 8 Central and Eastern European Countries (CEECs) to 5 Nordic countries over the years 1985 - 2005 and we can exploit a natural experiment that arose from the fact that while Sweden opened its labour market from the day one of the 2004 EU enlargement, the other Nordic...... countries chose a transition period in relation to the "new" EU members. We employ a differences-in-differences estimator in our analysis. The results show that the estimated effect of the opening of Swedish labour market in 2004 on migration is insignificantly different from zero. Further, we...... are interested in the overall effect of the "EU entry" on migration. Therefore we look at migration flows from CEECs during the first round EU enlargement towards CEECs in 2004 and compare them with migration flows from Bulgaria and Romania. We again used a DD estimator in our analysis. The estimated effect...

EuO and Gd-doped EuO thin films. Epitaxial growth and properties

International Nuclear Information System (INIS)

Sutarto, Ronny

2009-01-01

Europium oxide (EuO) based materials exhibit a wealth of spectacular phenomena, including half-metallic ferromagnetism, metal-insulator transition, colossal magneto-resistance, large magneto-optical Kerr effect, tunable ferromagnetic ordering temperatures, and large and long-lived photo-induced conductivity. These extraordinary properties make EuO an ideal candidate for implementation in device applications, in particular, for spintronics. Most of the work in the past has been carried out on bulk EuO, but for device applications it is preferred to have the EuO in thin lm form. A urry of studies have therefore emerged in the last decade in order to explore a wide variety of preparation routes and to investigate the properties of the resulting EuO thin films. A recent highlight is the demonstration that doped EuO films can be fabricated on Si and GaN, thereby exhibiting the expected spin-polarized transport effects. Nevertheless, it is still far from a trivial task to prepare EuO thin films with well de ned properties. For bulk EuO, it is already known that stoichiometry is the key issue, and that the presence of small amounts of defects or impurities quickly lead to very large deviations of the material properties. In fact, to make bulk EuO to be stoichiometric one needs temperatures as high as 1800 C. It is obvious that such high temperatures are not compatible with device engineering processes. The preparation of thin films must therefore involve much lower temperatures, preferably not higher than 400-500 C. The consequences are very dear. It turned out that many of the recent studies on EuO thin films are suffering from sample quality problems, due to the presence of, e.g., trivalent Eu species (Eu 3 O 4 , Eu 2 O 3 ), oxygen vacancies, or even Eu metal clusters. Controlled doping of the EuO with trivalent rare-earth ions is also not trivial, since most often even the actual doping concentrations were not known. In fact, one could also question in this respect the

EuO and Gd-doped EuO thin films. Epitaxial growth and properties

Energy Technology Data Exchange (ETDEWEB)

Sutarto, Ronny

2009-07-06

Europium oxide (EuO) based materials exhibit a wealth of spectacular phenomena, including half-metallic ferromagnetism, metal-insulator transition, colossal magneto-resistance, large magneto-optical Kerr effect, tunable ferromagnetic ordering temperatures, and large and long-lived photo-induced conductivity. These extraordinary properties make EuO an ideal candidate for implementation in device applications, in particular, for spintronics. Most of the work in the past has been carried out on bulk EuO, but for device applications it is preferred to have the EuO in thin lm form. A urry of studies have therefore emerged in the last decade in order to explore a wide variety of preparation routes and to investigate the properties of the resulting EuO thin films. A recent highlight is the demonstration that doped EuO films can be fabricated on Si and GaN, thereby exhibiting the expected spin-polarized transport effects. Nevertheless, it is still far from a trivial task to prepare EuO thin films with well de ned properties. For bulk EuO, it is already known that stoichiometry is the key issue, and that the presence of small amounts of defects or impurities quickly lead to very large deviations of the material properties. In fact, to make bulk EuO to be stoichiometric one needs temperatures as high as 1800 C. It is obvious that such high temperatures are not compatible with device engineering processes. The preparation of thin films must therefore involve much lower temperatures, preferably not higher than 400-500 C. The consequences are very dear. It turned out that many of the recent studies on EuO thin films are suffering from sample quality problems, due to the presence of, e.g., trivalent Eu species (Eu{sub 3}O{sub 4}, Eu{sub 2}O{sub 3}), oxygen vacancies, or even Eu metal clusters. Controlled doping of the EuO with trivalent rare-earth ions is also not trivial, since most often even the actual doping concentrations were not known. In fact, one could also question in

Harmful effect of arbitration dispute settlement EU intra bits to the legal order of the European Union

Directory of Open Access Journals (Sweden)

Vukadinović Radovan D.

2017-01-01

Full Text Available The issue of interpreting and applying intra BITs, especially in cases where their solutions conflict with EU law or international law, are a reflection of the still unresolved relationship between EU law and international law. Despite the exceptional theoretical significance, the issue of hierarchy is, first and foremost, a political issue. The answer to it defines the legal nature of the EU and the direction of its further development: as a sui generis federal community or a regional community of a confederal type. In the legal theory, the opinion on sui generis and the autonomous legal order of the EU is prevalent. This was also confirmed by the Court of Justice in a series of cases. However, the analyzed decisions of investment arbitrations engaged on the basis of the ISDS mechanism call into question such a position. Arbiters believe that the rights and obligations of the BIT should be interpreted in accordance with the rules of international law and that, in the event of a conflict with EU law, priority should be given to the rules of international public law. For this reason, the European Commission and the Court of Justice only see the existence of ISDS clauses in the BITs as a threat to the preservation of the unity and autonomy of the EU legal order, because their activation is jeopardized by the 'interpretative monopoly' of the Court of Justice entrusted with the decision of previous issues to ensure unity of rights EU. The fact that the question of the effect of the ISDS mechanism is not only of theoretical importance is testified by the fact that the EU negotiations on a new generation of trade and investment agreements are examining proposals to establish a more democratic and transparent multilateral international judicial mechanism in place of the existing mechanism.

Free allocation in the European Emissions Trading System (EU ETS): identifying efficient mechanisms through to 2030

International Nuclear Information System (INIS)

Jalard, Matthieu; Alberola, Emilie

2015-11-01

In a world with asymmetrical climate policies, the conclusions of the European Council of October 2014 agreed on continuing the allocation of free CO 2 emissions allowances beyond 2020 to industrial sectors in the EU ETS. This statement has been confirmed in the European Commission's proposal to revise EU ETS directive for phase IV disclosed in July 2015. The stated objective is to ensure that the most efficient industrial installations do not face undue carbon costs which would lead to carbon leakages. Furthermore, free allocations should not undermine the incentive to cut CO 2 emissions, lead to distortions or windfall profits and reduce the auctioning share of allowances. From 2013 to 2020, the allocation of free allowances has been defined according to harmonized European rules based on benchmarks (carbon intensity targets) and historical output adjusted to the free allocation cap by applying the Cross-Sectoral Correction Factor (CSCF). What would be the impact of pursuing the current mechanism through to 2030? Does the EU Commissions' proposal of 15 July respond to the Council's requirements? Which alternative mechanisms could do so? This study examines four scenarios and their potential consequences. - Scenario 1 continues the current free allocation mechanism until 2030. The volume of free allocations thus calculated would be higher than the available free allocation cap and would need to be reduced by a Cross-Sectoral Correction Factor (CSCF) of 66% in 2030. Carbon costs would thus increase for all installations, regardless their exposure to carbon leakages, reducing the protection of most exposed sectors, while widely allocating sectors with limited exposure. - Scenario 2 analyses the proposal to implement an allocation mechanism based on recent industrial output combined with appropriate updating of benchmarks. This allocation method is more effective in combating carbon leakage, as it gives clearer incentive to maintain domestic production

Photoionization behavior of Eu2+-doped BaMgSiO4 long-persisting phosphor upon UV irradiation

International Nuclear Information System (INIS)

Li, Y.; Wang, Y.; Gong, Y.; Xu, X.; Zhang, F.

2011-01-01

Highlights: → Photoionization behavior of BaMgSiO 4 :Eu 2+ long persistent phosphor upon UV irradiation. → Green phosphorescence was obtained from BaMgSiO 4 :Eu 2+ . → The ionization of Eu 2+ to Eu 3+ was observed in BaMgSiO 4 :Eu 2+ . → The photogenerated Eu 3+ cannot change back to its divalent state at room temperature. → The phosphorescence is associated with the formation forming Eu 3+ -e - pairs. - Abstract: The fluorescence, phosphorescence and thermoluminescence properties of Eu-doped BaMgSiO 4 phosphors sintered in air and in a reducing atmosphere were investigated. Phosphorescence of phosphor sintered in a reducing atmosphere can last for 1.5 h at a recognizable intensity level, whereas phosphorescence of air-sintered phosphor can only persist for 6 min. In addition, a distinction between the shape of the fluorescence spectrum and its corresponding phosphorescence spectrum is observed in the former case. Ionization of Eu 2+ to Eu 3+ upon UV irradiation is observed in the phosphor prepared in a reducing atmosphere, but there is no indication that the photogenerated Eu 3+ cannot change back to its divalent state at room temperature after the excitation source is switched off. In addition, phosphor sintered in a reducing atmosphere shows photochromism upon UV irradiation. No such photoionization and photochromism behavior is observed for the air-sintered phosphor. A possible Eu 2+ photoionization mechanism is constructed on the basis of these experimental observations. The photoionization mechanism presented can also successfully explain the fluorescence and phosphorescence behavior of Eu in BaMgSiO 4 .

The quest for a European civic culture : The EU and EU Citizenship in policies and practices of citizenship education in seven EU member states

NARCIS (Netherlands)

Bakker, W.E.; van der Kolk, M.; Berkeley, Dominic; Koska, Viktor

2017-01-01

Since the Treaty of Maastricht (1992) all nationals of EU member states hold EU citizenship too. EU citizens hold EU citizenship rights in addition to their national rights. These rights include civil, social, economic and political rights. Holding these rights does not guarantee actual

DFT investigation on electronic, magnetic, mechanical and thermodynamic properties under pressure of some EuMO3 (M  =  Ga, In) perovskites

Science.gov (United States)

Dar, Sajad Ahmad; Srivastava, Vipul; Sakalle, Umesh Kumar; Parey, Vanshree; Pagare, Gitanjali

2017-10-01

The structural, electronic, magnetic and elastic properties of cubic EuMO3 (M  =  Ga, In) perovskites has been successfully predicted within well accepted density functional theory using full potential linearized augmented plane wave (FP-LAPW). The structural study reveals ferromagnetic stability for both the compounds. The Hubbard correlation (GGA+U) calculated spin polarized electronic band and density of states presents half-metallic nature for both the compounds. The magnetic moments calculated with different approximations were found to be approximately 6 µ B for EuGaO3 and approximately 7 µ B for EuInO3. The three independent elastic constants (C 11, C 12, C 44) have been used for the prediction of mechanical properties like Young modulus (Y), Shear modulus (G), Poisson ratio (ν), Anisotropic factor (A) under pressure. The B/G ratio presents the ductile nature for both compounds. The thermodynamic parameters like specific heat capacity, thermal expansion, Grüneisen parameter and Debye temperature etc have also been analyzed in the temperature range 0-900 K and pressure range from 0 to 30 GPa.

2002 electricity statistics: EU and EU+

International Nuclear Information System (INIS)

Anon.

2003-01-01

Electricity generation in the European Union (EU) decreased by 0,7% in the period of 2001 to 2002, reaching 2521,3 billion kWh. Developments varied in different countries. Conventional thermal power plants generated 1340,1 billion kWh, which corresponds to a 53.0% share in the total generation and an increase by 2.7% over the level in the previous year. Generation in nuclear power plants increased by 2.7% to 855.5 billion kWh, which corresponds to a 33,8% share in EU-wide generation. Hydroelectric plants and other plants supplied 15.2% less electricity. Eurostat statistics do not differentiate these data any further. The volume of 332.2 kWh is tantamount to a 13.1% share. In the new EU member countries and the candidate countries, electricity generation showed a moderate increase by 0.4% and 2.1%, respectively. While generation both in conventional power plants and in other plants decreased, a considerable increase is shown for nuclear power generation of +13.5% and +10.6%, respectively [de

Composition dependence of the optical and structural properties of Eu-doped oxyfluoride glasses

International Nuclear Information System (INIS)

Zhu, Chaofeng; Wu, Dongqun; Zhang, Yanfei; Zhang, Meimei; Yue, Yuanzheng

2015-01-01

Highlights: • Eu doped oxyfluoride glasses for LED applications are studied. • Conversion of Eu 3+ to Eu 2+ is realized in the glasses prepared in air atmosphere. • CaF 2 crystals formed during melt cooling enhance the conversion of Eu 3+ to Eu 2+ . • Content of CaF 2 crystals can be controlled by adjusting base glass compositions. - Abstract: Europium doped oxyfluoride glasses were prepared by the melt quenching method for the light emitting diodes applications. The optical and structural properties of these glasses were studied by means of photoluminescence spectra, Commission Internationale de L’Eclairage chromaticity coordinates, X-ray diffraction, and Fourier transform infrared spectra. We find that the spontaneous reduction of Eu 3+ to Eu 2+ is realized by Eu 3+ ions occupying the sites of Ca 2+ in the glasses prepared in air atmosphere. The Eu 3+ to Eu 2+ conversion efficiency, optical performances and structure of the glasses strongly depend on the base glass compositions. For certain base glass compositions, CaF 2 crystals can form during the melt cooling process, and thereby enhance the conversion from Eu 3+ to Eu 2+ . The formation of CaF 2 crystals can be suppressed by adding CaO, Al 2 O 3 and B 2 O 3 , but enhanced by adding Na 2 O and K 2 O in glass compositions. Finally, we propose a mechanism to explain how the glass structure affects the reduction of Eu ions as well as optical properties of the glasses

Red/blue-shift dual-directional regulation of α-(Ca, Sr)2SiO4:Eu(2+) phosphors resulting from the incorporation content of Eu(2+)/Sr(2+) ions.

Science.gov (United States)

Lu, Zhijuan; Mao, Zhiyong; Chen, Jingjing; Wang, Dajian

2015-09-21

In this work, tunable emission from green to red and the inverse tuning from red to green in α-(Ca, Sr)2SiO4:Eu(2+) phosphors were demonstrated magically by varying the incorporation content of Eu(2+) and Sr(2+) ions, respectively. The tunable emission properties and the tuning mechanism of red-shift resulting from the Eu(2+) content as well as that of blue-shift induced by the Sr(2+) content were investigated in detail. As a result of fine-controlling the incorporation content of Eu(2+), the emission peak red-shifts from 541 nm to 640 nm. On the other hand, the emission peak inversely blue-shifts from 640 nm to 546 nm through fine-adjusting the incorporation content of Sr(2+). The excellent tuning characteristics for α-(Ca, Sr)2SiO4:Eu(2+) phosphors presented in this work exhibited their various application prospects in solid-state lighting combining with a blue chip or a near-UV chip.

Lost in Implementation: EU Law Application in Albanian Legal System

Directory of Open Access Journals (Sweden)

Hajdini Bojana

2017-06-01

Full Text Available Considering the growing importance of the researchers in the area of Europeanization in the candidate countries, the purpose of this paper is to analyse whether, and to what extent EU as a legal normative power has influenced Albania to approximate existing and future legislation and to ensure proper implementation. The paper argues that the Europeanization process is pushing Albania toward greater convergence with EU acquis by developing a modern legal framework. However, the paper points out that weak implementation has hampered the application of EU law in Albania due to: a weak bureaucracy or uneven distribution of human capacities; b the lack of an established practice of consultation with interest groups on specific draft legislation, and c the inability to put in sound planning mechanisms and to carry out a realistic assessment. The paper concludes that effective adjustment of Albanian legal system with EU norms requires cooperation between different actors involved in the approximation and implementation process.

Preparation, photoluminescent properties and luminescent dynamics of BaAlF{sub 5}:Eu{sup 2+} nanophosphors

Energy Technology Data Exchange (ETDEWEB)

Zhang, Wei [Stem Cell and Tissue Engineering Laboratory, Dalian University of Technology, Dalian, Liaoning 116023 (China); College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Hua, Ruinian, E-mail: rnhua@dlnu.edu.cn [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Liu, Tianqing, E-mail: liutq@dlut.edu.cn [Stem Cell and Tissue Engineering Laboratory, Dalian University of Technology, Dalian, Liaoning 116023 (China); Zhao, Jun [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); Na, Liyan [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Chen, Baojiu [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China)

2014-12-15

Graphical abstract: Rice-shaped BaAlF{sub 5}:Eu{sup 2+} nanophosphors were synthesized via one-pot hydrothermal process. The as-prepared BaAlF{sub 5}:Eu{sup 2+} are composed of many particles with an average diameter of 40 nm. When excited at 260 nm, the sharp line emission located at 361 nm of Eu{sup 2+} was observed. The optimum doping concentration of Eu{sup 2+} was confirmed to be 5 mol%. The strong ultraviolet emission of Eu{sup 2+} ions in BaAlF{sub 5}:Eu{sup 2+} nanoparticles suggests that these nanoparticles may have potential applications for sensing, solid-state lasers and spectrometer calibration. - Highlights: • BaAlF{sub 5}:Eu{sup 2+} nanophosphors were synthesized via a mild hydrothermal process. • The Van and Huang models were used to research the mechanism of concentration quenching. • The optimum doping concentration of Eu2+ was confirmed to be 5 mol%. - Abstract: Eu{sup 2+}-doped BaAlF{sub 5} nanophosphors were synthesized via a facile one-pot hydrothermal method. The final products were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and photoluminescence (PL) spectroscopy. XRD results showed that the prepared samples are single-phase. The FE-SEM and TEM images indicated that the prepared BaAlF{sub 5}:Eu{sup 2+} nanophosphors are composed of many rice-shaped particles with an average diameter of 40 nm. When excited at 260 nm, BaAlF{sub 5}:Eu{sup 2+} nanophosphors exhibit the sharp line emissions of Eu{sup 2+} at room temperature. The optimum doping concentration of Eu{sup 2+} was confirmed to be 5 mol%. The Van and Huang models were used to study the mechanism of concentration quenching and the electric dipole–dipole interaction between Eu{sup 2+} can be deduced to be a dominant for quenching fluorescence in BaAlF{sub 5}:Eu{sup 2+} nanophosphors. The strong ultraviolet emission of Eu{sup 2+} in BaAlF{sub 5}:Eu{sup 2+} nanophosphors suggests that

Concentration quenching of Eu{sup 2+} in a thermal-stable yellow phosphor Ca{sub 2}BO{sub 3}Cl:Eu{sup 2+} for LED application

Energy Technology Data Exchange (ETDEWEB)

Zhang Xinguo; Zhang Jilin; Dong Zhiyue; Shi Jianxin [State Key Laboratory of Optoelectronic Materials and Technologies, Ministry of Education Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275 (China); Gong Menglian, E-mail: cesgml@mail.sysu.edu.cn [State Key Laboratory of Optoelectronic Materials and Technologies, Ministry of Education Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275 (China)

2012-04-15

A piece-shaped phosphor Ca{sub 2}BO{sub 3}Cl: Eu{sup 2+} was synthesized by solid-state reaction method. This phosphor exhibited wide absorption in ultra-violet and visible range, and bright yellow emission band centering at 570 nm. The concentration quenching mechanism was verified to be a dipole-dipole interaction, and its critical transfer distance was about 17 A by both calculated crystal structural method and experimental spectral method. This phosphor has a good thermal stability with a quenching temperature (T{sub 1/2}) of 200 Degree-Sign C. Yellow and white LEDs were fabricated with this phosphor and near UV chips, and the yellow LED has a high color purity of 97.0% and promising current tolerant property, while the white LED shows a luminous efficiency of 11.68 lm/W. - Highlights: Black-Right-Pointing-Pointer Broadband excitable and strong yellow-emitting Ca{sub 2}BO{sub 3}Cl: Eu{sup 2+} phosphor is obtained by solid state reaction. Black-Right-Pointing-Pointer Concentration quenching mechanism of Ca{sub 2}BO{sub 3}Cl: Eu{sup 2+} is dipole-dipole interaction. Black-Right-Pointing-Pointer Quenching temperature (T{sub 1/2}) of Ca{sub 2}BO{sub 3}Cl: Eu{sup 2+} is at 200 Degree-Sign C. Black-Right-Pointing-Pointer As synthesized material can be used for LED phosphor application.

Ukraine Between The EU And The CES In Global Instability

Directory of Open Access Journals (Sweden)

Svitlana Radzievska

2013-01-01

Full Text Available The article reviews functioning and development of the European Union (EU and the Common Economic Space (CES in the global instability and substantiates the equal significance of Ukraine’s integration with these regional associations in today’s environment. This conclusion is based upon the current state of Ukraine’s trade and economic relations with the countries taking part in these integration associations, and the probability of: 1 the EU’s abstaining from admitting new members until the EU structure improves, or admitting new members while changing the mechanism of interaction within the EU and setting more stringent admission criteria, 2 changes in the terms of trade of Ukraine with the CES member states due to its transformation into the Eurasian Economic Community (EEC.

STATE REGULATION OF FRANCHISING IN THE EU MEMBER COUNTRIES

Directory of Open Access Journals (Sweden)

Solomiya Ohinok

2015-11-01

Full Text Available In despite of extensive research of franchising in the scientific community, there are a lot of unresolved issues relating to franchising, in particular its regulation at the national level and at the level of the European Union that is why the purpose of the paper is to summarise and present the difference between state regulation of franchising in the EU member states and to research the basic principles of state regulation of franchising in the EU also to analyze legislation of the franchise relationship. Methodology. The survey is based on a comparison of data from all EU member countries and analisis of the legal framework of each country in particular and in general EU legislation. The article is devoted to a detailed analysis of main features of the franchise business in Europe. The mechanism of implementation of franchise relations between EU member states are studied. Government regulation of franchising in the EU member states are investigated. The rate of growth of franchising in Europe are analized. Results. By comparing different state laws and regulations of franchising we have identified the most effective and productive. We divided counties into two groups due to their regulation of franchising: countries which do not have a special government regulation of franchising; the countries which have state regulation of franchising; countries which have government regulation of franchising and it is governed by EU law, countries in which regulation is carried out in accordance with EU law. Thus, results of the survey showed that government regulation of franchising, as well as its regulation at the level of EU institutions have a positive impact on the development of franchising relationships. Practical implications of the results of the paper will help to develop well known network of franchise bussiness without legislative interference. Value/originality. It is first time we have grouped countries due to the main aspects of state

Creating EU law judges

DEFF Research Database (Denmark)

Mayoral Diaz-Asensio, Juan Antonio; Jaremba, Urszula; Nowak, Tobias

2014-01-01

The judicial protection system in the European Union (EU) is premised on the fact that national judges are supposed to act as decentralized EU judges. This role is exercised through tools enshrined in, inter alia, primacy, direct and indirect effect of EU law, and the preliminary ruling procedure...

X-ray enhancement of CsI:Eu{sup 2+} radioluminescence

Energy Technology Data Exchange (ETDEWEB)

Leblans, P., E-mail: paul.leblans@agfa.com [Agfa-HealthCare NV, Septestraat 27, B-2640 Mortsel (Belgium); Struye, L.; Elen, S.; Mans, I. [Agfa-HealthCare NV, Septestraat 27, B-2640 Mortsel (Belgium); Vrielinck, H.; Callens, F. [Electron Magnetic Resonance Research Group, Department of Solid State Sciences, Ghent University, Krijgslaan 281-S1, B-9000 Gent (Belgium)

2015-09-15

CsI:Eu{sup 2+} needle crystal layers were produced by Physical Vapour Deposition (PVD). The luminescence properties were studied before and after thermal anneal. It was shown by Electron Paramagnetic Resonance (EPR) that annealing produces Eu{sup 2+} monomer centres, probably starting from Eu clusters in the needle crystalline layers. These centres seem structurally very similar to the Eu{sup 2+} monomer centres in annealed CsBr:Eu{sup 2+} needle layers. They give rise to a narrow luminescence band peaking at about 450 nm (2.76 eV) at room temperature, both under X-ray and UV excitation. The luminescence intensity of as-deposited layers is low. Annealing enhances photo- and radioluminescence on average by a factor of 1.5–3. Surprisingly, further sensitization of radioluminescence with a factor of up to 7 is possible by exposing the annealed needle layers to X-rays or UV, while in contrast, UV excited luminescence is slightly reduced. X-ray enhancement thus leads to a structured scintillator with a conversion efficiency of about 42,000 photons/MeV upon X-ray excitation. A similar radioluminescence enhancement is observed for annealed CsI:Eu{sup 2+} fine powder, but not for large single crystals or conglomerated polycrystals. The measurements and observations are consistent with Eu{sup 2+} monomer centres stabilized by water molecules. These molecules are incorporated via annealing, and that this happens when the morphology is such that water can diffuse throughout the volume of the crystals. The presence of stabilized Eu{sup 2+} monomers is necessary to enhance radioluminescence by X-ray exposure. A mechanism is proposed for the phenomenon.

Tendances Carbone no. 78 'Reforming the EU ETS: give it some work'

International Nuclear Information System (INIS)

Sartor, Oliver; Berghmans, Nicolas; Stephan, Nicolas

2013-01-01

Among the publications of CDC Climat Research, 'Tendances Carbone' bulletin specifically studies the developments of the European market for CO 2 allowances. This issue addresses the following points: The Carbon Market Report published last November by the European Commission launched a debate on structural measures to sustainably address the EU ETS's large surplus and sets out six options for measures which could do so: (a) increasing the EU reduction target to 30% in 2020, (b) retiring a number of allowances in phase 3, (c) early revision of the annual linear reduction factor, (d) extension of the EU ETS to other sectors, (e) limit access to international credits, (f) discretionary price management mechanisms. To assess these options, we must ask: what needs to be improved about the EU ETS's current design?

The EU Decarbonisation Roadmap 2050—What way to walk?

International Nuclear Information System (INIS)

Hübler, Michael; Löschel, Andreas

2013-01-01

We carry out a detailed computable general equilibrium (CGE) analysis of the EU Decarbonisation Roadmap 2050 on a macroeconomic and on a sectoral level. Herein, we study a Reference scenario that implements existing EU policies as well as 3 unilateral and 3 global climate action scenarios. We identify global climate action with international emissions trading and the full equalisation of CO 2 prices across all (EU) sectors as an economically reasonable policy option to avoid additional costs of the Decarbonisation Roadmap to a large extent. This policy option may include CDM (Clean Development Mechanism in the sense of ‘where’-flexibility) in an extended form if there are countries without emissions caps. Moreover, we identify diverse sectoral effects in terms of output, investment, emissions and international competitiveness. We conclude that the successful realisation of the EU Decarbonisation Roadmap probably requires a wise and joint consideration of technology, policy design and sectoral aspects. - Highlights: ► We extend the CGE model PACE until 2050 and include energy technologies. ► We assess the newest EU Decarbonisation Roadmap in six policy scenarios. ► Global action with ETS and CDM credits from non-participants create low(est) costs. ► Mitigation costs can strongly increase at CO 2 reductions around 80%. ► The policy effects vary strongly across EU sectors

GAUGING THE VERTICAL SPECIALIZATION IN EU TRADE

Directory of Open Access Journals (Sweden)

IULIA MONICA OEHLER-SINCAI

2014-11-01

Full Text Available The purpose of this paper is threefold. First, we review the mechanisms and determinants of vertical specialization (VS, as this has gradually become the dominant characteristic of international trade. Second, we underline that there is a rich literature regarding VS in EU trade, at aggregate and individual levels and research is advancing together with the instruments used to measure trade in value added. Third, our investigation brings to the forefront a classification of EU countries according to their GVC participation index, taking into consideration both upstream and downstream links. As a conclusion, the VS analyses help us better understand the interconnectedness among countries and industries by means of foreign direct investment, trade, labour migration and technology transfer.

Neutron Scattering from Heisenberg Ferromagnets EuO and EuS

DEFF Research Database (Denmark)

Als-Nielsen, Jens Aage; Dietrich, O. W.; Passell, L.

1976-01-01

Neutron scattering has been used to study the magnetic ordering process in the isotropic exchange coupled ferromagnets EuO and EuS. Quantities investigated include the critical coefficients B and F+ and the critical exponents β, ν, and γ describing respectively the temperature dependence...

Degradation mechanisms of the blue-emitting phosphor BaMgAl{sub 10}O{sub 17}:Eu{sup 2+} under baking and VUV-irradiating treatments

Energy Technology Data Exchange (ETDEWEB)

Zhang Shuxiu E-mail: shuxiu_zhang@dyden.co.jp; Kono, Toshihiko; Ito, Akira; Yasaka, Taketo; Uchiike, Heiju

2004-01-01

The luminescent properties of an Eu{sup 2+}-activated hexagonal aluminate, BaMgAl{sub 10}O{sub 17} (BAM), were studied under 147- and 254-nm excitations. The BAM samples were thermally treated by baking and then irradiated in vacuum ultraviolet (VUV) rays. The results show that the emission efficiency of Eu{sup 2+} in BAM under 147-nm excitation degraded seriously after baking or VUV-irradiating treatments, while no significant degradation was observed under 254-nm excitation. The degree of degradation depended on the excitation wavelength, and the absorption edge of the BAM host was suggested to be close to 175 nm (7.2 eV). The differences between the thermal-induced and the VUV-irradiation-induced degradations, and their mechanisms are discussed for the color plasma display applications.

U(VI) and Eu(III) ion sorption in the interface solution-phosphate solids: Structural study and mechanisms

International Nuclear Information System (INIS)

Drot, Romuald

1998-01-01

As part of the storage of nuclear wastes in a deep underground disposal, radionuclides sorption on geological or engineered barriers is one of the most important factor which could enhance retardation. Thus, the knowledge of such mechanisms is needed. For this purpose, we chose to experimentally define sorption equilibria before performing simulation of retention data. Several phosphate compounds are potential candidates as engineered barrier additives. We considered Th 4 (PO 4 ) 4 P 2 O 7 , Zr 2 O(PO 4 ) 2 which allow to study the effect of PO 4 and P 2 O 7 groups separately. Eu(III) and U(IV) ions were used as structural probes in order to simulate actinides (III) and (VI) behavior. X-ray powder diffraction, IR spectroscopy and electron probe microanalysis were used to characterized the synthesized solids. Electrophoretic measurements showed an amphoteric behavior of surface sites. Moreover, laser spectro-fluorimetry experiments indicated that no diffusion phenomena of the sorbed ion inside the solid occurs. Thus, we considered that a surface complexation model should be applied. Laser spectro-fluorimetry and XPS allowed to determine the nature of surface sites. ZrP 2 O 7 presents only one single site (P 2 O 7 groups) whereas Th 4 (PO 4 ) 4 P 2 O 7 and Zr 2 O(PO 4 ) 2 admit two types of sites (PO 4 /P 2 O 7 and PO 4 /oxo groups, respectively). Sorbed species were identified using laser spectro-fluorimetry which indicate that, in KNO 3 0.5 M medium and for a known surface site, there are two surface complexes for U(VI) (sorption of UO 2+ 2 et de UO 2 NO + 3 species) and only one for Eu(III) (sorption of EuNO 2+ 3 ). They are linked to the substrate as bidentate inner sphere complexes (EXAFS study). Surface acidity constants were determined by simulation of potentiometric titration curves obtained for each solid suspension using FITEQL code (CCM). As sorption equilibria were defined, experimental retention data simulation was performed with respect to structural

National Courts and EU Law

DEFF Research Database (Denmark)

approaches and theories originating from law, political science, sociology and economics. The first section addresses issues relating to judicial dialogue and EU legal mandates, the second looks at the topic of EU law in national courts and the third considers national courts’ roles in protecting fundamental......, National Courts and EU Law will hold strong appeal for scholars and students in the fields of EU law, social sciences and humanities. It will also be of use to legal practitioners interested in the issue of judicial application of EU law....

152Eu decay

International Nuclear Information System (INIS)

Artamonova, K.P.; Vinogradov, V.M.; Grigor'ev, E.P.; Zolotavin, A.V.; Makarov, V.M.; Sergeev, V.O.; Usynko, T.M.

1978-01-01

The purpose of this paper is the measurement of the relative intensities of the most intensive conversion lines of 152 Eu, the determination of as reliable as possible magnitudes of the intensities of γ-quanta using all the available data on γ-radiation of 152 Eu, the measurement of the interval conversion coefficients (ICC) for the most intensive γ-transitions, the determination of the probabilities of the 152 Eu β-decays to the 152 Sm and 152 Gd levels. The conversion lines of the most intensive γ-transitions in the 152 Eu decay are studied and the corresponding ICC are measured on the beta-spectrometers of π√2 and UMB type. The balance for the γ-transitions in the 152 Sm and 152 Gd daughter nuclei are presented. This balance is used to determine the absolute intensities of γ-rays (in terms of the percentage of the 152 Eu decays) and the probabilities of β-transitions to the levels of daughter nuclei. More accurate data on γ-rays and conversion electrons obtained can be used for the calibration of gamma and beta spectrometers

The EU vs. Russia in the foreign policy discourse of Armenia: the fragility of normative power or the power of Russian coercion?

Directory of Open Access Journals (Sweden)

Aram TERZYAN

2017-12-01

Full Text Available Constructivist-driven conventional wisdom posits that ideas and beliefs are pivotal to shaping foreign policy trajectories. Thus, the explanatory power ascribed to material forces falls back on ideas and cultural practices (Wendt, 1999. Whereas the case of Armenia, characterized by the co-existence of European foreign policy identity with Russia-led foreign policy preferences suggests that identity and beliefs may well be outweighed by material forces. This paper seeks to explain the evolution of how the European Union (EU and Russia have been conceptualised within the foreign policy discourse of Armenia. The study relies on the critical discourse analysis of relevant speeches and statements of Armenia’s foreign policy-makers and, particularly, on those of the President. It scrutinizes the core notions and discursive structures, employed in the Armenian foreign policy discourse for justifying the choice of the Russia-led path. It suggests that Armenia’s deviation from the identity driven path towards the EU has been broadly justified in terms of the country’s economic and, particularly, security needs, which prompted to treat Russia as an indispensable ally. Yet, a closer scrutiny of external constraints indicates that Russian coercive policy left little room for Armenia to achieve a Russian-European balance.

EU Food Health Law

DEFF Research Database (Denmark)

Edinger, Wieke Willemijn Huizing

to human health because of other factors, such as their nutritional composition. The growing prevalence of obesity and non-communicable diseases are examples of contemporary health challenges that are difficult to fit into the rather narrow concept of food safety risks in the GFL. The conclusion is that EU...... of harmonising measures that could facilitate a better consumer protection from non-safety health risks at the EU level. The EU legislature should use this legislative competence to fill in the regulatory grey area. Two possible ways forward to better integrate food health into the EU food law framework...

Policy options for carbon taxation in the EU

International Nuclear Information System (INIS)

Laurent, Eloi; Le Cacheux, Jacques

2010-06-01

Even though the EU clearly leads the global fight against climate change and despite the additional reduction in emissions due to the global crisis and European recession, the ambitious objectives flagged in the '20-20-20 by 2020' strategy and 'climate-energy package' are probably out of reach if a more resolute and consistent policy of carbon taxation is not rapidly put in place. First, the EU is not as 'virtuous' as it may seem, and shows signs of a 'fatigue' in mitigating climate change; this is explained by the weak incentive structure of current climate institutions, due to both narrow coverage and insufficient stringency of the European 'Emission Trading Scheme' (ETS) - the European 'carbon market'-, and to excessive reliance on emission standards combined with weak energy taxation. Fears of losing competitiveness are a major argument against imposing a higher carbon price on industries, feeding tax competition both within the EU and vis-a-vis the rest of the world. Though not fully satisfactory, the Commission's recent proposal (a revision of the 2003 energy taxation directive introducing floors on national excises based on carbon content) would help solving the intra-EU conundrum. Alternatively, an extension of the EU ETS to households and the transport sector via the 'upstream' inclusion of fossil fuel dealers would also be a feasible solution. In order to answer the 'carbon leakage' argument and to send appropriate price signals to European consumers on extra-EU imports, a border adjustment mechanism - carbon levy or inclusion of importers into the EU ETS - is also necessary. Ultimately though, in order to make sure that economic agents face a uniform carbon price, a generalized carbon tax, in the form of a European 'Carbon Added Tax' (ECAT), would be the most effective instrument in the fight against climate change, as well as the pillar of a thorough tax

The Parliamentary Legitimacy of the European Union: The Role of the States General within the European Union

NARCIS (Netherlands)

Besselink, Leonard F.M.; Mourik, Brecht van

2012-01-01

This article presents the state of play in the Netherlands with regard to parliamentary scrutiny in EU decision-making. Although the States General have all in all dealt with EU decision-making fairly actively, this contribution makes clear that Parliament's activity has not been able to offset the

Russian energy in the EU market: Bolstered institutionsand their effects

International Nuclear Information System (INIS)

Romanova, Tatiana

2014-01-01

The article examines institutional changes in EU–Russian energy relations since 2000. The article explores the ability of transformed institutions to limit the politicisation of energy and to reconcile the EU competitive-market approach with Russian state capitalism. More specifically, the article focuses on changes in intergovernmental, transgovernmental and transnational interactions. The article demonstrates that the gradual strengthening of transgovernmental and transnational institutions has inhibited the politicisation of energy relations and facilitated regulative cooperation between the EU and Russia. However, the potential of shared institutions is constrained by internal institutions on both sides. In Russia, these obstacles are insufficient top-down delegation of responsibilities in the government and its great power aspirations. In the EU, key barriers include inter-institutional rivalries, the EU’s propensity to impose its legislation on external partners and the integration of energy policy with foreign policy. The article presents several policy implications. First, it is futile to institutionally impose the regulative paradigm of one partner on the other; rather, mutual dialogue is needed. Thus, institutions should be structured appropriately. Second, current depoliticisation will require the involvement of not only the EU and Russia but also transit countries, such as Ukraine. Third, transgovernmental and transnational cooperation should be nurtured because this is a useful channel for both information exchange and a regulative convergence of policy implementing mechanisms. Finally, this incremental regulative convergence is the only option available today for the EU and Russia; this is also a way to further depoliticise energy relations. - Highlights: • EU and Russia developed transgovernmental and transnational energy institutions. • It allowed them to face energy challenges: depoliticisation and market construction. • Internal EU and

Multicolor Tunable Luminescence Based on Tb3+/Eu3+ Doping through a Facile Hydrothermal Route.

Science.gov (United States)

Wang, Chao; Zhou, Ting; Jiang, Jing; Geng, Huiyuan; Ning, Zhanglei; Lai, Xin; Bi, Jian; Gao, Daojiang

2017-08-09

Ln 3+ -doped fluoride is a far efficient material for realizing multicolor emission, which plays an important part in full-color displays, biolabeling, and MRI. However, studies on the multicolor tuning properties of Ln 3+ -doped fluoride are mainly concentrated on a complicated process using three or more dopants, and the principle of energy transfer mechanism is still unclear. Herein, multicolor tunable emission is successfully obtained only by codoping with Tb 3+ and Eu 3+ ions in β-NaGdF 4 submicrocrystals via a facile hydrothermal route. Our work reveals that various emission colors can be obtained and tuned from red, orange-red, pink, and blue-green to green under single excitation energy via codoping Tb 3+ and Eu 3+ with rationally changed Eu 3+ /Tb 3+ molar ratio due to the energy transfer between Tb 3+ and Eu 3+ ions in the β-NaGdF 4 host matrix. Meanwhile, the energy transfer mechanism in β-NaGdF 4 : x Eu 3+ /y Tb 3+ (x + y = 5 mol %) submicrocrystals is investigated. Our results evidence the potential of the dopants' distribution density as an effective way for analyzing energy transfer and multicolor-controlled mechanism in other rare earth fluoride luminescence materials. Discussions on the multicolor luminescence under a certain dopant concentration based on single host and wavelength excitation are essential toward the goal of the practical applications in the field of light display systems and optoelectronic devices.

Optical spectroscopy of Eu3+ doped Th(MoO4)2

International Nuclear Information System (INIS)

Keskar, Meera; Phatak, Rohan; Gupta, Santhosh; Natarajan, V.

2014-01-01

Eu 3+ is often used as a structural probe, because of the relative simplicity of its energy-level structure and dependence on its site symmetry in the host material. The phonon energy of the host for rare-earth ions is a crucial factor to be considered for developing luminescent materials.Thorium molybdate can satisfy both low phonon energy environment for rare-earth ions and good chemical and mechanical stabilities for practical use. Thus Eu 3+ doped Th(MoO 4 ) 2 are expected to be a good promising optical materials. To the best of our knowledge, there is no report on optical spectroscopy of Eu 3+ doped thorium molybdate and thus work has been carried out and discussed in this paper

OpenLaws.eu

NARCIS (Netherlands)

Wass, C.; Dini, P.; Eiser, T.; Heistracher, T.J.; Lampoltshammer, T.J.; Marcon, G.; Sageder, C.; Tsiavos, P.; Winkels, R.; Schweighofer, E.; Kummer, F.; Hötzendorfer, W.

2013-01-01

The OPENLAWS.eu project aims to linking existing laws, cases and legal literature throughout the EU and member states and potentially worldwide and at adding new user-friendly functionality for a higher productivity. Furthermore, the project should make it possible to easily publish new legal

EU Transparency Register

NARCIS (Netherlands)

Mańko, R.; Thiel, M.; Bauer, E.

2014-01-01

Widespread lobbying in the EU institutions has led to criticism regarding the transparency and accountability of the EU's decision-making process. In response to these concerns, the Parliament set up its transparency register in 1995, followed by the Commission in 2008. The two institutions merged

Economic impacts of EU climate policy until 2020; EU:n ilmastopolitiikan talousvaikutukset vuoteen 2020

Energy Technology Data Exchange (ETDEWEB)

Rantala, O. E-mail: olavi.rantala@etla.fi

2012-07-01

The study evaluates the impacts of EU climate policy on the emission allowance price, electricity prices, the competitiveness of industry and macroeconomic developments in the third EU emission trading period 2013-2020. The economic impacts of climate policy on Finland are compared to the impacts on the entire EU area. It turns out that due to its cold climate and heating energy demand, higher export intensity of the economy and higher energy intensity of the industry Finland pays a higher price for EU climate policy in terms of output and employment losses than the EU on average. The study examines the macroeconomic effects of climate policy also in the more distant future, assuming that climate policy is tightened further in the 2020s. Climate policy implemented by emission trading means that the long-term economic growth in the EU area depends essentially on emission-free electricity production, and no longer on other growth factors, such as the labour supply and productivity growth. (orig.)

Cathodoluminescence properties of yttrium aluminum garnet doped with Eu2+ and Eu3+ ions

International Nuclear Information System (INIS)

Trofimov, A. N.; Petrova, M. A.; Zamoryanskaya, M. V.

2007-01-01

Yttrium aluminium garnet (YAG) doped with Eu 2+ and Eu 3+ ions is very interesting as a phosphor for conversion of light-emitting diode light for white light sources. The europium ion occupies the structural position of yttrium in yttrium aluminium garnet and has valence state Eu 3+ . Our sample was doped with Zr 4+ , which is why some of the europium ions had valence state Eu 2+ . As a rule, luminescence of Eu 3+ ions is observed in the orange and red range of spectrum. The luminescence of Eu 2+ in yttrium aluminum garnet is characterized by an intensive broad band with maximum of intensity at about 560 nm (green color). In this work, we studied the intensity and decay time dependences on europium concentration, and the influence of excitation power density on the cathodoluminescence of the sample. The most interesting result is the change of visible cathodoluminescence color in dependence on the density of the exciting power

Negative pressure driven valence instability of Eu in cubic Eu0.4La0.6Pd3

International Nuclear Information System (INIS)

Pandey, Abhishek; Mazumdar, Chandan; Ranganathan, R

2009-01-01

We report the change in the valency of Eu-ions in the binary intermetallic cubic compound EuPd 3 induced by La doping at rare-earth sites. Doping of La generates negative chemical pressure in the lattice, resulting in a significant increase of the lattice parameter without altering the simple-cubic structure of the compound. Results of dc-magnetic measurements suggest that this increase in the lattice parameter is associated with the valence transition of Eu-ions from Eu 3+ to a mixed-valent state. As Eu 2+ -ions possess a large magnetic moment, this valence transition significantly modifies the magnetic behavior of the compound. In contrast to introducing boron at the vacant body center site of the unit cell to change the valency of Eu-ions, as in the case of EuPd 3 B, our results suggest it can also be altered by doping a rare-earth ion of larger size at the lattice site of Eu in EuPd 3 .

Understanding the differing governance of EU emissions trading and renewable: feedback mechanisms and policy entrepreneurs

Energy Technology Data Exchange (ETDEWEB)

Boasson, Elin Lerum; Wettestad, Joergen

2010-04-15

This paper presents a comparative study of two central EU climate policies: the revised Emissions Trading System (ETS), and the revised Renewable Energy Directive (RES). Both were originally developed in the early 2000s and revised policies were adopted in December 2008. While the ETS from 2013 on will have a quite centralized and market-streamlined design, the revised RES stands forward as a more decentralized and technology-focused policy. Differing institutional feed-back mechanisms and related roles of policy entrepreneurs can shed considerable light on these policy differences. Due to member states' cautiousness and contrary to the preferences of the Commission, the initial ETS was designed as a rather decentralized and 'politicized' market system, creating a malfunctioning institutional dynamic. In the revision process, the Commission skillfully highlighted this ineffective dynamic to win support for a much more centralized and market-streamlined approach. In the case of RES, national technology-specific support schemes and the strong links between the renewable industry and member states promoted the converse outcome: decentralization and technology development. Members of the European Parliament utilized these mechanisms through policy networking, while the Commission successfully used developments within the global climate regime to induce some degree of centralization. (Author)

Synthesis and characterization of a liquid Eu precursor (EuCppm2) allowing for valence control of Eu ions doped into GaN by organometallic vapor phase epitaxy

International Nuclear Information System (INIS)

Mitchell, Brandon; Koizumi, Atsushi; Nunokawa, Takumi; Wakamatsu, Ryuta; Lee, Dong-gun; Saitoh, Yasuhisa; Timmerman, Dolf; Kuboshima, Yoshinori; Mogi, Takayuki; Higashi, Shintaro; Kikukawa, Kaoru; Ofuchi, Hironori; Honma, Tetsuo; Fujiwara, Yasufumi

2017-01-01

A liquid Eu precursor, bis(normal-propyl-tetramethylcyclopentadienyl)europium has been synthesized. This precursor exists as a liquid at temperatures higher than 49 °C, has a moderately high vapor pressure, contains no oxygen in its molecular structure, and can be distilled to high purity. These properties make it ideal for doping using a chemical vapor or atomic layer deposition method, and provide a degree of control previously unavailable. As a precursor the Eu exists in the divalent valance state, however, once doped into GaN by organometallic vapor phase epitaxy, the room-temperature photoluminescence of the Eu-doped GaN exhibited the typical red emission due to the intra-4f shell transition of trivalent Eu. After variation of the growth temperature, it was found that divalent Eu could be stabilized in the GaN matrix. By tuning the Fermi level through donor doping, the ratio of Eu 2+ to Eu 3+ could be controlled. The change in valence state of the Eu ions was confirmed using X-ray absorption near-edge structure. - Highlights: • A liquid Eu precursor was synthesized and its properties were characterized. • Precursor has a low melting point and a moderately high vapor pressure. • Does not contain oxygen in its molecular structure. • Eu can changed its valance state when incorporated into GaN. • Valence state of Eu in GaN can be controlled by donor doping.

Photoluminescence, energy transfer and tunable color of Ce(3+), Tb(3+) and Eu(2+) activated oxynitride phosphors with high brightness.

Science.gov (United States)

Lü, Wei; Huo, Jiansheng; Feng, Yang; Zhao, Shuang; You, Hongpeng

2016-06-21

New tuneable light-emitting Ca3Al8Si4O17N4:Ce(3+)/Tb(3+)/Eu(2+) oxynitride phosphors with high brightness have been prepared. When doped with trivalent cerium or divalent europium they present blue luminescence under UV excitation. The energy transfer from Ce(3+) to Tb(3+) and Ce(3+) to Eu(2+) ions is deduced from the spectral overlap between Ce(3+) emission and Tb(3+)/Eu(2+) excitation spectra. The energy-transfer efficiencies and corresponding mechanisms are discussed in detail, and the mechanisms of energy transfer from the Ce(3+) to Tb(3+) and Ce(3+) to Eu(2+) ions are demonstrated to be a dipole-quadrupole and dipole-dipole mechanism, respectively, by the Inokuti-Hirayama model. The International Commission on Illumination value of color tuneable emission as well as luminescence quantum yield (23.8-80.6%) can be tuned by controlling the content of Ce(3+), Tb(3+) and Eu(2+). All results suggest that they are suitable for UV light-emitting diode excitation.

Database Security and the Problem of Polyinstantiation: a moral scrutiny

Directory of Open Access Journals (Sweden)

Mikko Siponen

2002-11-01

Full Text Available In the area of computer security the problem of polyinstantiation is widely recognized. The research on polyinstantiation can be considered morally questionable, since it involves lying. This being the case, a moral scrutiny on the problem of polyinstantiation is warranted. The morality of polyinstantiation shall be critically analysed from the viewpoint of a moral philosophical framework. The moral philosophical framework used includes 1 Kantian ethics, 2 the universality theses advocated by Hare, Rawls, Gewirth, Jewish-Christian ethics, and Confucian ethics, 3 utilitarianism, and 4 Theory of Information Ethics (IE by Floridi. The result of this analysis suggests that research and practice on polyinstantiation is morally questionable, at least in the light of the chosen moral philosophical theories. The aim of the paper is not, however, to deem polyinstantiation as morally wrong altogether, but to provide researchers and practitioners with tools and insights for analyzing the morality of polyinstantiation in different cases. Moreover, the results suggest that, as far as polyinstantiation is concerned, traditional ethics theories seem to be at least as adequate as IE.

EU Industrial Policy

DEFF Research Database (Denmark)

Pellegrin, Julie; Giorgetti, Maria Letizia; Jensen, Camilla

Following disregard in the 1980s, industrial policy has recently attracted policy attention at EU level. The objective of this study provided by Policy Department A at the request of the ITRE Committee, is to establish the state of the art of a coordinated and integrated EU industrial policy...

Differences and similarities between the EU and non-EU citizens

Directory of Open Access Journals (Sweden)

Iris Dhamo

2017-03-01

Full Text Available Initially, the European Union had a purely economic connotation, as his intent was the free movement of factors of production, in order to create a competitive internal market and achieving a rational distribution of resources. For this reason, the individual was seen simply as a worker and for this purpose the first aspects that are disciplined within the EU are those contained in this sphere. In the Treaty of Rome, which established the European Economic Community (EEC, the freedom of free movement was reserved for only a few special categories of workers, who were active subjects economically, since what resulted essential at the time was the creation of an internal market. Later the Maastricht Treaty, on one side marks the transition from the EEC to the EU, on the other presents for the first time the "European citizenship", making the free movement an autonomous right of every citizen belonging to a Member State. In this way the free movement is exercised not only for the economic purposes of the Treaties. In December 2000 the Charter of Fundamental Rights or the Charter of Nice was compiled and signed, which defines that the EU seeks to promote a balanced development and ensures free movement of persons, goods, services and capital, and also the freedom of residence. Main objective of this manuscript is an analysis of the differences and similarities between the EU and non-EU citizens.

Contribution of Eu ions on the precipitation of silver nanoparticles in Ag-Eu co-doped borate glasses

International Nuclear Information System (INIS)

Jiao, Qing; Qiu, Jianbei; Zhou, Dacheng; Xu, Xuhui

2014-01-01

Graphical abstract: - Highlights: • Silver nanoparticles are precipitated from the borate glasses during the melting process without any further heat treatment. • The reduction of Eu 3+ ions to Eu 2+ ions is presented in this material. • The intensity of Ag + luminescence. • The introduction of Eu ions accelerated the reaction between Eu 2+ ions and silver ions inducing the silver clusters formation. - Abstract: Ag + doped sodium borate glasses with different Eu ions concentration were prepared by the melt-quenching method. The absorption at about 410 nm which was caused by the surface plasmon resonance (SPR) of Ag nanoparticles (NPs) is promoted with increasing of Eu ions concentration. Meanwhile, the luminescent spectra showed that the emission intensity of Ag + decreased while that of the Ag aggregates increased simultaneously. The results indicated that the Ag ions intend to form the high-polymeric state such as Ag aggregates and nanoparticles with increasing of europium ions. Owing to the self-reduction of Eu 3+ to Eu 2+ in our glass system, it revealed that Ag + has been reduced by the neighboring Eu 2+ which leads to the formation of Ag aggregates and the precipitation of Ag NPs in the matrix. In addition, energy transfer (ET) process from Ag + /Ag aggregates to the Eu 3+ was investigated for the enhancement of Eu 3+ luminescence

Paradigms for EU Law and the Limits of Delegation. The Case of EU Agencies

OpenAIRE

Simoncini Marta

2017-01-01

This article questions the idea that the EU is a pure regulatory power based on supranational delegation of competence from the Member States. It claims the insufficiency of this single paradigm to explain the developments of EU law and the need to integrate it with recognition of the constitutional foundations of EU law.

Magnetic oxide heterostructures. EuO on cubic oxides and on silicon

International Nuclear Information System (INIS)

Caspers, Christian

2013-01-01

strained EuO thin film shows a Poisson ratio of ν EuO ∼ 0. The tensile strain reduces the Curie temperature significantly by 12.3 K. The MCD effect provides an advanced magnetic characterization: the MCD asymmetries in Eu core-level photoemission reveal a larger reduction due to the tensile strain than obtained from bulk-averaging SQUID measurements. Thus, the mechanism of tensile strain on intra-atomic exchange (indicated by MCD) is significantly different than on the spin order of the 4f 7 shell (indicated by SQUID). Experiments on EuO by MCD, thereby, reveal exciting perspectives for studying fundamental magnetic properties of EuO. In the second part of this thesis, we explore how to integrate EuO directly with Si (001). We focus on interface engineering of structural and chemical properties of the EuO/Si (001) spin-functional heterointerface. In response to the extremely high chemical reactivity and pronounced surface kinetics of Eu, EuO, and Si during EuO synthesis at elevated temperatures, we initially conduct a thermodynamic analysis of the EuO/Si interface. In this way, we decide to investigate three in situ passivation techniques for the Si (001) surface, in order to prevent metallic and oxide contaminations at the EuO/Si interface. both being main antagonists for spin-selective tunneling. We conduct a comprehensive optimization study of the EuO/Si heterointerface by tuning the passivation parameters of the Si (001) surface and the growth parameters of EuO. Using HAXPES, we evaluate Si and Eu core-level spectra and determine the minimum of interface contaminants as d opt (SiO x ) = 0.69 nm concomitant with d opt (EuSi 2 ) = 0.20 nm, both of which are clearly in the subnanometer regime. In conclusion, our ultrathin EuO/Si (001) heterostructures reveal a high chemical quality of the spinfunctional interface, combined with magnetic properties of the EuO layer akin to bulk. By selected interface passivation methods, we achieve a reduction of residual contaminations

Sorption of Eu(III) to Kaolinite in the Presence of Humic Acids

International Nuclear Information System (INIS)

Shin, Hyun Sang; Harn, Yoon I; Oh, Se Jin

2010-05-01

The sorption of europium(Eu(III)) onto kaolinite and the influence of humic acids over a range of pH 3 ∼ 11 has been studied by batch adsorption experiment (V/m = 250:1 mL/g, CEu(III) = 1x10 -5 mol/L, C HA = 5 ∼ 50 mg/L, PCO 2 = 10 -3.5 atm). The concentrations of HA and Eu(III) in aqueous phase were measured by UV absorbance at 254 nm(e.g., UV 254 ) and ICP-MS after microwave digestion for HA removals, respectively. Results showed that the HA sorption onto kaolinite was decreased with increasing pH and their sorption isotherms fit well with the Langmuir adsorption model (except pH 3). Maximum amount(q max ) for the HA sorption at pH 4 to 11 was ranged from 4.73 to 0.47 mg/g. Europium adsorption onto the kaolinite in the absence of HA was typical, showing an increases with pH and a distinct adsorption edge at pH 3 to 5. However in the presence of HA, Eu adsorption to kaolinite was significantly affected. HA was shown to enhance Eu adsorption in the acidic pH range (pH 3 ∼ 4) due to the formation of additional binding sites for Eu coming from HA adsorbed onto kaolinite surface, but reduce Eu adsorption in the intermediate and high pH above 6 due to the formation of aqueous Eu-HA complexes. The results on the ternary interaction of kaolinite-Eu-HA are compared with those on the binary system of kaolinite-HA and kaolinite-Eu and adsorption mechanism with pH was discussed

EU 2004 Declaration. EU policy workshop development of offshore wind energy. Background document

International Nuclear Information System (INIS)

De Bruijne, R.

2004-09-01

Participants of the Dutch EU Presidency's 'EU Policy Workshop on the development of offshore wind energy' published this Declaration that called for action at the EU Transport, Energy and Telecom Council on November 29, 2004. The Declaration lists a series of action points on three main issues relating to the development of offshore wind energy in Europe: market development; environment; and grid integration of large scale offshore wind

PROPERTIES OF Eu3+ LUMINESCENCE IN THE MONOCLINIC Ba2MgSi2O7

Directory of Open Access Journals (Sweden)

Shansh an Yao

2011-09-01

Full Text Available Red-emitting phosphors Ba2-xMgSi2O7: Eux3+ was prepared by combustion-assisted synthesis method and an efficient red emission under near-ultraviolet (UV was observed. The luminescence and crystallinity were investigated using luminescence spectrometry and X-ray diffractometer. The emission spectrum shows that the most intense peak is located at 614 nm, which corresponds to the 5D0 → 7F2 transitions of Eu3+. The phosphor has two main excitation peaks located at 394 and 465 nm, which match the emission of UV and blue light-emitting diodes, respectively. The effect of Eu3+ concentration on the emission spectrum of Ba2MgSi2O7:Eu3+ phosphor was studied. The results showed that the emission intensity increased with increasing Eu3+ concentration, and then decreased because of concentration quenching. The critical quenching concentration of Eu3+ in Ba2MgSi2O7: Eu3+ phosphor is about 0.05 mol. The mechanism of concentration quenching of Ba2MgSi2O7: Eu3+ luminescence is energy transfer between Eu3+ ions casued by the dipole-dipole interaction.

The EU Arbitration Convention : An evaluating assessment of the governance and functioning of the EU Arbitration Convention

NARCIS (Netherlands)

Pit, Harm Mark

2017-01-01

The EU Arbitration Convention An evaluating assessment of the governance and functioning of the EU Arbitration Convention Summary for non-experts The EU Arbitration Convention is a convention between EU Member States to eliminate double taxation arising from – for tax purposes – transfer pricing

Paradigms for EU Law and the Limits of Delegation. The Case of EU Agencies

Directory of Open Access Journals (Sweden)

Simoncini Marta

2017-11-01

Full Text Available This article questions the idea that the EU is a pure regulatory power based on supranational delegation of competence from the Member States. It claims the insufficiency of this single paradigm to explain the developments of EU law and the need to integrate it with recognition of the constitutional foundations of EU law.

Radiation defects in SrB4O7:Eu2+ crystals

International Nuclear Information System (INIS)

Yavetskiy, R.P.; Dolzhenkova, E.F.; Tolmachev, A.V.; Parkhomenko, S.V.; Baumer, V.N.; Prosvirnin, A.L.

2007-01-01

Radiation-induced defects in SrB 4 O 7 :Eu 2+ (0.033 at.%) single crystal irradiated with γ and X-ray quanta has been studied. The induced optical absorption in the 400-700 nm region has been ascribed to F + centers. The Eu 2+ ions have been shown to act simultaneously as traps and as radiative recombination centers of charge carriers. Basing on the thermally stimulated luminescence (TSL), optical absorption and photoluminescence studies of SrB 4 O 7 :Eu 2+ crystals, a TSL mechanism has been proposed associated with the decay of F + centers being in non-equivalent crystallographic positions followed by radiative recombination of charge carriers on europium ions. Various positions of localization of the radiation-induced defects in the SrB 4 O 7 crystal structure have been discussed

Energy transfer between the Eu2+ dipole and aggregate centers in CsBr:Eu crystals

International Nuclear Information System (INIS)

Zorenko, Yu.; Turchak, R.; Voznjak, T.

2007-01-01

The energy transfer between the Eu 2+ -V Cs dipole centers and presumable CsEuBr 3 aggregate centers has been studied in CsBr:Eu crystals by means of investigation of their time-resolved emission spectra and luminescence decay kinetics at 300 K

Managing intra-EU mobility-do WHO principles of ethical recruitment have relevance?

Science.gov (United States)

Kovács, Réka; Girasek, Edmond; Kovács, Eszter; Aszalós, Zoltán; Eke, Edit; Ragány, Károly; Cserháti, Zoltán; Szócska, Miklós

2017-11-09

The WHO Global Code of Practice on the International Recruitment of Health Personnel provides for guidance in health workforce management and cooperation in the international context. This article aims to examine whether the principles of the voluntary WHO Global Code of Practice can be applied to trigger health policy decisions within the EU zone of free movement of persons. In the framework of the Joint Action on European Health Workforce Planning and Forecasting project (Grant Agreement: JA EUHWF 20122201 (see healthworkforce.eu)), focus group discussions were organised with over 30 experts representing ministries, universities and professional and international organisations. Ideas were collected about the applicability of the principles and with the aim to find EU law compatible, relevant solutions using a qualitative approach based on a standardised, semi-structured interview guide and pre-defined statements. Based on implementation practices summarised, focus group experts concluded that positive effects of adhering to the Code can be identified and useful ideas-compatible with EU law-exist to manage intra-EU mobility. The most relevant areas for intervention include bilateral cooperations, better use of EU financial resources, improved retention and integration policies and better data flow and monitoring. Improving retention is of key importance; however, ethical considerations should also apply within the EU. Compensation of source countries can be a solution to further elaborate on when developing EU financial mechanisms. Intra-EU circular mobility might be feasible and made more transparent if directed by tailor-made, institutional-level bilateral cooperations adjusted to different groups and profiles of health professionals. Integration policies should be improved as discrimination still exists when offering jobs despite the legal environment facilitating the recognition of professional qualifications. A system of feedback on registration

Intra-EU Direct Investment and Enlargement

Directory of Open Access Journals (Sweden)

Festa Andrea

2015-03-01

Full Text Available This paper examines the determinants of the intra-EU direct investment (IDI into the New Member States (NMS using a panel dataset of bilateral capital flows for the period 1993-2013. It is found out by using a simple gravity model that EU membership is the most important determinant. Unlike previous studies including non-EU countries, the distance is insignificant, which is caused by proximity of these countries to one another. A separate analysis focused on subgroups of accession countries gives some evidence that even when size of their economy, distance, institutional quality and EU accession are taken into account, Central European countries receive more IDI than the Baltic and the Balkan states. On the contrary to that, the analysis restricted to the Balkan countries which have joined the EU shows the inexistence of a negative Balkans effect in attracting foreign investment. This finding is relevant because previous studies demonstrate a persistent negative Balkans effect for non-EU Balkan countries and suggests a crucial impact of the EU accession in determining the intra-EU capital flows.

Border tax adjustments and the EU-ETS. A quantitative assessment

International Nuclear Information System (INIS)

Manders, T.; Veenendaal, P.

2008-10-01

If the EU stands alone in adopting climate policy and imposes a strict emissions ceiling, competitiveness of EU energy-intensive sectors will be affected negatively. Relocation of EU energy-intensive firms to countries with a lax regime also leads to carbon leakage. However, when use is made of the opportunities of the Clean Development Mechanism these impacts are very modest. Border tax adjustments (BTAs) to 'level the playing field' between domestic and foreign producers may be considered to address the concerns about both competitiveness and carbon leakage. It is far from clear whether these measures are WTO-proof. Simulations show that both an import levy and an export refund restore competitiveness to a certain extent. BTAs may lower the costs for energy-intensive sectors, but induce higher costs for other sectors. This paper uses a general equilibrium model to quantify and assess the implications of a number of policy scenarios

FEATURES OF WTO DISPUTE SETTLEMENT. THE STANDING OF THE EU

Directory of Open Access Journals (Sweden)

Costin Horia Rogoveanu

2010-09-01

Full Text Available The WTO has an innovative system of dispute settlement, with the following features: sui-generis, integrated, resolving the disputes according to the WTO agreements, excluding unilateral solutions, interstate system. These features are detailed in the present article. Another level of analysis concerns the standing of the EU in the WTO, in general, and in the Geneva proceedings for dispute settlement, in particular. Generated by the quality of the European Communities statute as an original member of the Organisation, the EU has become one of the main users of the WTO dispute settlement system. One of the main challenges of the WTO dispute settlement mechanism is the implementation of decisions. In view of the cases assessed, while the execution record of the EU is a quite satisfactory one, it is apparent that implementation of decisions in more intricate cases creates difficulties at the Union level.

Photoluminescence and thermoluminescence properties of Eu2+ doped and Eu2+ ,Dy3+ co-doped Ba2 MgSi2 O7 phosphors.

Science.gov (United States)

Sao, Sanjay Kumar; Brahme, Nameeta; Bisen, D P; Tiwari, Geetanjali

2016-11-01

In this work, we report the preparation, characterization, comparison and luminescence mechanisms of Eu 2 + -doped and Eu 2 + ,Dy 3 + -co-doped Ba 2 MgSi 2 O 7 (BMSO) phosphors. Prepared phosphors were synthesized via a high temperature solid-state reaction method. All prepared phosphors appeared white. The phase structure, particle size, and elemental analysis were analyzed using X-ray diffraction (XRD), transmission electron microscopy (TEM) and energy-dispersive X-ray (EDX) analysis. The luminescence properties of the phosphors were investigated by thermoluminescence (TL) and photoluminescence (PL). The PL excitation and emission spectra of Ba 2 MgSi 2 O 7 :Eu 2 + showed the peak to be around 381 nm and 490 nm respectively. The PL excitation spectrum of Ba 2 MgSi 2 O 7 :Eu 2 + Dy 3 + showed the peak to be around 341 nm and 388 nm, and the emission spectrum had a broad band around 488 nm. These emissions originated from the 4f 6 5d 1 to 4f 7 transition of Eu 2 + . TL analysis revealed that the maximum TL intensity was found at 5 mol% of Eu 2 + doping in Ba 2 MgSi 2 O 7 phosphors after 15 min of ultraviolet (UV) light exposure. TL intensity was increased when Dy 3 + ions were co-doped in Ba 2 MgSi 2 O 7 :Eu 2 + and maximum TL intensity was observed for 2 mol% of Dy 3 + . TL emission spectra of Ba 1.95 MgSi 2 O 7 :0.05Eu 2 + and Ba 1.93 MgSi 2 O 7 :0.05Eu 2 + ,0.02Dy 3 + phosphors were found at 500 nm. TL intensity increased with UV exposure time up to 15 min, then decreased for the higher UV radiation dose for both Eu doping and Eu,Dy co-doping. The trap depths were calculated to be 0.54 eV for Ba 1.95 MgSi 2 O 7 :0.05Eu 2 + and 0.54 eV and 0.75 eV for Ba 1.93 MgSi 2 O 7 :0.05Eu 2 + ,0.02Dy 3 + phosphors. It was observed that co-doping with small amounts of Dy 3 + enhanced the thermoluminescence properties of Ba 2 MgSi 2 O 7 phosphor. Copyright © 2016 John Wiley & Sons, Ltd. [Correction added on 5 April 2016, after first online publication: The

Gaps in EU Foreign Policy

DEFF Research Database (Denmark)

Larsen, Henrik

of Capability-Expectations Gap in the study of European foreign policy. Through examples from relevant literature, Larsen not only demonstrates how this concept sets up standards for the EU as a foreign policy actor (that are not met by most other international actors) but also shows how this curtails analysis...... of EU foreign policy. The author goes on to discuss how the widespread use of the concept of ‘gap' affects the way in which EU foreign policy has been studied; and that it always produces the same result: the EU is an unfulfilled actor outside the realm of “normal” actors in IR. This volume offers new...... perspectives on European foreign policy research and advice and serves as an invaluable resource for students of EU foreign policy and, more broadly, European Studies....

Russia-EU energy efficiency cooperation in the Baltic region: the untapped potential

Directory of Open Access Journals (Sweden)

Romanova T. A.

2014-03-01

Full Text Available A stereotypical understanding of EU-Russia energy relations is often reduced to trade in oil and natural gas, which downplays the importance of energy efficiency cooperation. Such cooperation is promoted within the Energy Charter and its Treaty, Partnership and Cooperation Agreement, Energy Dialogue, Common Economic Space, Partnership for Modernisation. However, it lacks practical development, which relates to the instability of the legal environment in Russia, insufficient mechanisms of financial support for energy conservation projects and poor political support. Nevertheless, energy efficiency cooperation is capable of changing Russia-EU energy cooperation qualitatively: it offers a cheaper way to meet the needs of the EU, redefines interdependence between the parties, and introduces new elements of equality between them. Energy efficiency cooperation also transforms the patterns of the EU-Russia legal harmonization, creates new conditions for the convergence of regulations and the development of the middle class in Russia. Due to its specific features, cooperation in the Baltic Sea region becomes a locomotive of the Russia-EU energy efficiency cooperation, and, as a result, is capable of changing the quality of relations between the partners.

Photoluminescence varied by selective excitation in BiGdWO6:Eu3+ phosphor

Science.gov (United States)

Pavani, K.; Graça, M. P. F.; Kumar, J. Suresh; Neves, A. J.

2017-12-01

Eu3+ doped bismuth gadolinium tungstate (BGW), a simplest member of Aurivillius family of layered perovskites, was synthesized by solid-state reaction method. Structural characterisation has been performed by X-Ray diffraction (XRD), Raman spectroscopy, Fourier Transform Infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). Band gap of the host matrix has been calculated using reflectance and absorption spectra. Three different mechanisms were found to explain the excitation of Eu3+ ions and are described in detail. Photoluminescence (PL) spectra of the BGW phosphor doped with Eu3+ ions consist of major emission lines associated with 5D0 → 7FJ (J = 0, 1, 2, 3 and 4) of Eu3+ ion. Site selective PL excitation and emission indicates that Eu3+ ions doped in BiGdWO6 are sensitive to the excitation wavelength without change in the structure. Change in emission spectra were observed when the excitation wavelength was changed. Judd-Ofelt (J-O) parameters were determined from the indirect method to interpret the interactions between the host and dopant ions along with detailed analysis of lifetime measurements.

Trade in Value Added (TiVA in EU New Member States (EU NMS

Directory of Open Access Journals (Sweden)

Ines Kersan-Škabić

2017-01-01

Full Text Available Contemporary trade analysis indicates the necessity of calculating trade in value added (TiVA which is created through global value chains (GVCs. This paper aims to determine the characteristics and importance of GVC trade in the EU new member states (EU NMS with special emphasis placed on the industry level. The results demonstrate different levels of GVC participation of the EU NMS, where Hungary is the most integrated country and Croatia the least integrated. Regional GVCs exist because a huge part of value added (VA comes from EU member states, as in gross export as well as in final demand (Europe as a hub. The most important source countries are Germany and Italy and there is also evidence of geographical and historical relations between the countries. The domination of backward participation has been found in the analysis made on the industrial level, i.e. the EU NMS are highly dependent on the import of intermediates for the production and export of final products. Strong interconnections between imports of intermediate products and exports of final products have been found in the manufacture of computers, electronics and optical products; manufacture of wood, paper, printing and reproduction. This research has contributed to the scarce literature concerning GVC (TiVA in EU NMS and has opened up new possibilities for further research and analysis.

Present developmental conditions petroleum substituting energies in the EU; Sekiyu daitai energy kaihatsu no genjo (EU)

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-03-01

This report outlines the policy of development and introduction of petroleum substituting energies, and its diffusion situation in the EU. On the policy, development, introduction and diffusion of petroleum substituting energies in the EU, based on the new EU energy white paper issued in fiscal 1996, the policy of energy and environment in every EU country is first outlined. The policy of and practical approach to petroleum substituting energies in every EU country are next described. In particular, since ALTENER which has been continuously promoted by the EU for 3 years as main control measures against CO2 is newly moving toward the second plan, the trend of ALTENER and the new SAVE2 plan are presented. The content of JOULE-THERMIE is also precisely presented which is the new energy program of the 4th framework R & D program. In relation to the developmental trend of alternative energies to oil in the EU until 2020, its prediction result is presented on the basis of the latest study promoted by EC committee in the ALTENER plan. 10 tabs.

Growing Significance of EU Institutions in Promotion of Inter-regional policies

Directory of Open Access Journals (Sweden)

Ella V. Ermakova

2014-01-01

Full Text Available The article explores the variety of tools and vehicles applied within the EU to expand the prerogative of the regions of the EU member states. The author uses as an example the inter-regional policies in Belgium in respect of the Flemish Region and the Walloon Region. The author analyzes the mechanisms of promotion of external regional relations in Belgium as a means of addressing different problems both on national and all-European level, supporting the arguments and conclusions by examples of relevant EU initiatives. The article details the activities of the EU Regional Committee (RC, the EU advisory body with the powers of political initiative, upholding the principle ofsubsidarity in the implementation of the EU member states' regional policies. The involvement of the Flemish Region and the Walloon Region in the activities of EU RC is described and summarized. As a case study, the article deals with Belgium's rotating six months presidency in the EUin 2010 when the country, which was going through a severe political crisis with no federal government in place, was represented by the two regions. The special focus of the article is on the strategic EU program "Europe2020" and its implementation by the regions of Belgium. There is an account of the initiatives undertaken by the Flemish Region and the Walloon Region within the framework of this program outlining the interaction of the two regions. The author provides a comprehensive analysis of the involvement of the Flemish Region and the Walloon Region with various EU institutions describing how each party achieves the promotion of its regional interests. Within this context, it is a noteworthy development that the Flemish Region is participating in the international program "Pact 2020" on energy all by its own. The article features quotations by Flemish and Walloon political figures which serve as an illustration of the prevailing attitudes in the Belgian society to the process of

EU-US economic relations: the TTIP negotiations and its implications

Directory of Open Access Journals (Sweden)

Javier Arregui Moreno

2015-09-01

Full Text Available This article analyses some of the most important arguments for creating a free trade area between the EU and the United States. It also identifies the most conflictive issues in the Transatlantic Trade and Investment Partnership (TTIP and the possible agreements according to the mechanisms and strategies used. The article shows that the TTIP negotiation has sufficient potential to link issues together so that both the EU and the US can exchange positions on various subjects via the logrolling mechanism. Given that the TTIP presents significant potential advantages to both sides and that in this type of negotiation absolute profits tend to prevail, it is feasible that a final agreement will be reached that is accepted by both parties. It would be a new turn of the screw in the process of globalisation, with the aim of preserving the West’s central role on the international stage.

A new promising phosphor, Na3La2(BO3)3:Ln (Ln=Eu, Tb)

International Nuclear Information System (INIS)

Li Zhihua; Zeng Jinghui; Zhang Guochun; Li Yadong

2005-01-01

We present an efficient way to search a host for ultraviolet (UV) phosphor from UV nonlinear optical (NLO) materials. With the guidance, Na 3 La 2 (BO 3 ) 3 (NLBO), as a promising NLO material with a broad transparency range and high damage threshold, was adopted as a host material for the first time. The lanthanide ions (Tb 3+ and Eu 3+ )-doped NLBO phosphors have been synthesized by solid-state reaction. Luminescent properties of the Ln-doped (Ln=Tb 3+ , Eu 3+ ) sodium lanthanum borate were investigated under UV ray excitation. The emission spectrum was employed to probe the local environments of Eu 3+ ions in NLBO crystal. For red phosphor, NLBO:Eu, the measured dominating emission peak was at 613 nm, which is attributed to 5 D - 7 F 2 transition of Eu 3+ . The luminescence indicates that the local symmetry of Eu 3+ in NLBO crystal lattice has no inversion center. Optimum Eu 3+ concentration of NLBO:Eu 3+ under UV excitation with 395 nm wavelength is about 30 mol%. The green phosphor, NLBO:Tb, showed bright green emission at 543 with 252 nm excited light. The measured concentration quenching curve demonstrated that the maximum concentration of Tb 3+ in NLBO was about 20%. The luminescence mechanism of Ln-doped NLBO (Tb 3+ and Eu 3+ ) was analyzed. The relative high quenching concentration was also discussed

Quadrupole splitting and Eu partial lattice dynamics in europium orthophosphate EuPO {sub 4}

Energy Technology Data Exchange (ETDEWEB)

Klobes, B., E-mail: b.klobes@fz-juelich.de [JARA-FIT - Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science JCNS and Peter Grünberg Institute PGI (Germany); Arinicheva, Y., E-mail: y.arinicheva@fz-juelich.de; Neumeier, S., E-mail: s.neumeier@fz-juelich.de [Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research (IEK-6) Nuclear Waste Management and Reactor Safety (Germany); Simon, R. E., E-mail: r.simon@fz-juelich.de; Jafari, A., E-mail: a.jafari@fz-juelich.de [JARA-FIT - Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science JCNS and Peter Grünberg Institute PGI (Germany); Bosbach, D., E-mail: d.bosbach@fz-juelich.de [Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research (IEK-6) Nuclear Waste Management and Reactor Safety (Germany); Hermann, R. P., E-mail: hermannrp@ornl.gov [JARA-FIT - Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science JCNS and Peter Grünberg Institute PGI (Germany)

2016-12-15

Hyperfine interactions in europium orthophosphate EuPO{sub 4} were investigated using {sup 151}Eu Mössbauer spectroscopy from 6 to 300 K. The value of the quadrupole splitting and the asymmetry parameter were refined and further substantiated by nuclear forward scattering data obtained at room temperature. The temperature dependence of the relative absorption was modeled with an Eu specific Debye temperature of 221(1) K. Eu partial lattice dynamics were probed by means of nuclear inelastic scattering and the mean force constant, the Lamb-Mössbauer factor, the internal energy, the vibrational entropy, the average phonon group velocity were calculated using the extracted density of phonon states. In general, Eu specific vibrations are characterized by rather small phonon energies and contribute strongly to the total entropy of the system. Although there is no classical Debye like behavior at low vibrational energies, the average phonon group velocity can be reasonably approximated using a linear fit.

Properties–structure relationship research on LiCaPO4:Eu2+ as blue phosphor for NUV LED application

International Nuclear Information System (INIS)

Zhang, Xinguo; Mo, Fuwang; Zhou, Liya; Gong, Menglian

2013-01-01

Graphical abstract: The graphical abstract shows the excitation and emission spectrum of LiCaPO 4 :Eu 2+ , and the CIE coordinates of LiCaPO 4 :Eu 2+ . The inset shows the photo of blue LED prepared by LiCaPO 4 :Eu 2+ and NUV chip. It indicates that this phosphor can be excited by UV light and emit strong greenish-blue light. Highlights: •Pure phase blue phosphors of LiCaPO 4 :Eu 2+ with a hexagonal structure were first prepared via solid-state method. •The crystallographic site of Eu 2+ ion in the LiCaPO 4 lattice was identified as 8-fold Ca 2+ site. •The phosphor exhibits excellent thermal stability and the corresponding mechanism was thermal assisted ionization. •Bright and high color purity blue LED prototype based on LiCaPO 4 :Eu 2+ phosphor was fabricated. -- Abstract: Blue-emitting phosphors of Eu 2+ -activated LiCaPO 4 with a hexagonal structure were prepared via a conventional solid-state method. The XRD, PL spectra and thermal quenching were applied to characterize the phosphors. The crystallographic site of Eu 2+ ion in the LiCaPO 4 lattice was identified and discussed. The optimized LiCaPO 4 :0.03Eu 2+ exhibits the bright greenish-blue emission with CIE coordinates of (0.119, 0.155) and a quantum efficiency of 52%. The critical energy-transfer distance was confirmed as ∼18 Å by both calculated crystal structure method and experimental spectral method. The thermal stability of LiCaPO 4 :Eu 2+ was evaluated by temperature-dependent PL spectra, and the thermal quenching mechanism was found to be thermal assisted ionization. Prototype blue LEDs with high color purity and good current stability were fabricated

EU Trade Governance and Policy: A Critical Perspective

Directory of Open Access Journals (Sweden)

Lucy Ford

2013-10-01

Full Text Available This article offers a critical analysis of EU trade policy. It does so by highlighting the political and economic enclosures within which EU trade policy is embedded and that continue to hamper more holistic and interdisciplinary analyses that are argued to be necessary in order to comprehend the obstacles to and avenues towards a more sustainable and socially just world. The article critically analyses economic and political hegemony by drawing on two strands of critical international thought, namely neo-Gramscian analysis and global political ecology, employing a critical realist approach. The article identifies the perceived twin short-comings of conventional analyses: firstly, the neglect of understandings of power relations and social justice, and secondly the lack of attention to criteria of sustainability. Within critical debates about European governance, including the governance of trade and trade policy, neo-Gramscian perspectives highlight the power relations within EU governance, exposing the mechanisms of hegemony as well as identifying potential counter-hegemonic forces. While this offers important insights, the article argues that a critical perspective cannot be complete without attention to sustainability. Political ecology makes a vital contribution to critical perspectives by highlighting the natural limits within which by necessity all human activity takes place. Using illustrations from trade policy debates, the article argues that current EU trade policy and governance is not best placed to meet the challenges of sustainability and social justice and it points to the need for more holistic systems thinking to challenge orthodoxy.

Overlever EU?

DEFF Research Database (Denmark)

Østergaard, Uffe

2015-01-01

Det bliver stadig tydeligere at EU i kraft af den styrkede nationalisme i øst, vest og nord og kombineret med de nye regionale krav om national selvstændighed vil bevæge sig i retning af et mellemstatsligt samarbejde, støttet af en retsorden beskyttet af en domstol, bliver stadig tydeligere. Det ...... mindre sikkert, om den nationale egoisme vil ende med at opløse samarbejdet. EU vil sandsynligvis overleve, men det bliver snarere ligesom det Tysk-Romerske Rige, hvis institutioner overlevede helt til 1804....

Synthesis and effect of Ce and Mn co-doping on photoluminescence characteristics of Ca6AlP5O20:Eu novel phosphors.

Science.gov (United States)

Shinde, K N; Dhoble, S J

2013-01-01

A series of Ca6AlP5O20 doped with rare earths (Eu and Ce) and co-doped (Eu, Ce and Eu,Mn) were prepared by combustion synthesis. Under Hg-free excitation, Ca6AlP5O20:Eu exhibited Eu(2+) (486 nm) emission in the blue region of the spectrum and under near Hg excitation (245 nm), Ca6AlP5O20:Ce phosphor exhibited Ce(3+) emission (357 nm) in the UV range. Photoluminescence (PL) peak intensity increased in Ca6AlP5O20:Eu,Ce and Ca6AlP5O20:Eu, Mn phosphors due to co-activators of Ce(3+) and Mn(2+) ions. As a result, these ions played an important role in PL emission in the present matrix. Ca6AlP5O20:Eu, Ce and Ca6AlP5O20:Eu, Mn phosphors provided energy transfer mechanisms via Ce(3+) → Eu(2+) and Eu(2+) → Mn(2+), respectively. Eu ions acted as activators and Ce ions acted as sensitizers. Ce emission energy was well matched with Eu excitation energy in the case of Ca6AlP5O20:Eu, Ce and Eu ions acted as activators and Mn ions acted as sensitizers in Ca6AlP5O20:Eu, Mn. This study included synthesis of new and efficient phosphate phosphors. The impact of doping and co-doping on photoluminescence properties and energy transfer mechanisms were investigated and we propose a feasible interpretation. Copyright © 2012 John Wiley & Sons, Ltd.

EU Think Tank Fora as Transaction Cost Reducers: A Study of Informal Interest Intermediation in the EU

Directory of Open Access Journals (Sweden)

Marybel Perez

2014-05-01

Full Text Available By examining the organisational structure of EU think tank fora (seminars, workshops and conferences, this article proposes that fora can play the role of transaction cost reducers in EU policymaking. I argue that certain aspects of EU policymaking, including i controlled processes of consultation, ii diminishing costs of management, and iii the risk of state capture, incentivise EU institutions to outsource part of the consultation activity to policy actors that can help EU institutions fulfil their informational and legitimacy needs. I argue that think tanks are able to play this role because they i reduce information asymmetries by connecting a wide variety of policy actors and ii act as intermediaries that mitigate opportunistic behaviour. The empirical assessment reveals that the dimensions characterising transactions are present in EU think tank fora. It shows that policy actors that do not usually participate in formal consultation processes frequently attend fora where they meet representatives of EU institutions, particularly Parliament and Commission representatives.

Essentials of EU law

CERN Document Server

Reinisch, August

2012-01-01

This book explores the history and institutions of the EU, examines the interplay of its main bodies in its legislative process and illustrates the role played by the EU Courts and the importance of fundamental rights. The student is also introduced to the key principles of the internal market, in particular the free movement of goods and the free movement of workers. In addition a number of other EU policies, such as the Common Agricultural Policy, Environmental Protection and Social Policy are outlined, while a more detailed inquiry is made into European competition law.

Development of EU Environmental Regulation

DEFF Research Database (Denmark)

Klemmensen, Børge

2007-01-01

En tematiseret gennemgang af udviklingstrinene i EU's miljøpolitik fra de allerførste skirdt i 1970-72, der måtte basere sig på EU-traktatens generalklausul i Artikel 235, over declarationen på EU-topmødet i Paris i 1972, der kædede økonomisk udvikling sammen med et krav om hensyntagen til miljøet...

Luminescence properties and dynamical processes of energy transfer in BiPO{sub 4}: Tb{sup 3+},Eu{sup 3+} phosphor

Energy Technology Data Exchange (ETDEWEB)

Zhong, Jianming; Zhao, Weiren, E-mail: zwren123@126.com; Song, Enhai; Deng, Yongqiang

2014-10-15

A series of new emission-tunable phosphors Bi{sub 0.95−y}PO{sub 4}:0.05Tb{sup 3+},yEu{sup 3+} were synthesized by a facile hydrothermal method with surfactant-free environment. XRD results indicated that phosphors possess the standard BiPO{sub 4} monoclinic structure. From the luminescence spectra and decay curves, the energy transfer from Tb{sup 3+} to Eu{sup 3+} was confirmed. The efficient Tb{sup 3+} to Eu{sup 3+} energy transfer can be used to tune the emission color from green, yellow to orange by simply changing the concentration of europium, making the materials have potential applications in three-color-based displays and white light illumination. Finally, the energy transfer mechanism between Tb{sup 3+} and Eu{sup 3+} was demonstrated to be the electric quadrupole–quadrupole interaction based on Dexter's energy transfer formula and the Inokuti–Hirayama model. - Highlights: • BiPO{sub 4}: Tb{sup 3+}, Eu{sup 3+} phosphor was synthesized by a facile hydrothermal method. • Energy transfer from Tb{sup 3+} to Eu{sup 3+} in BiPO{sub 4} was firstly studied. • The Q–Q interaction is the main mechanism for energy transfer from Tb{sup 3+} to Eu{sup 3+}. • BiPO{sub 4}: Tb{sup 3+}, Eu{sup 3+} has potential applications in white LEDs and display devices.

Multichannel Luminescence Properties of Mixed-Valent Eu2+/Eu3+ Coactivated SrAl3BO7 Nanocrystalline Phosphors for Near-UV LEDs.

Science.gov (United States)

Liu, Xiaoming; Xie, Weijie; Lü, Ying; Feng, Jingchun; Tang, Xinghua; Lin, Jun; Dai, Yuhua; Xie, Yu; Yan, Liushui

2017-11-20

Up to now, orchestrating the coexistence of Eu 2+ and Eu 3+ activators in a single host lattice has been an extremely difficult task, especially for the appearance of the characteristic emission of Eu 2+ and Eu 3+ in order to generate white light. Nevertheless, here we demonstrate a new Eu 2+ /Eu 3+ coactivated SrAl 3 BO 7 nanocrystalline phosphor with abundant and excellent multichannel luminescence properties. A series of Eu 2+ /Eu 3+ coactivated SrAl 3 BO 7 nanocrystalline phosphors were prepared through a Pechini-type sol-gel method followed by a reduction process. With excitation of UV/NUV light, the prepared SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphors show not only the characteristic f-f transitions of Eu 3+ ion ( 5 D J → 7 F J,J' , J, J' = 0-3), but also the 5d → 4f transitions of Eu 2+ ion with comparable intensity from 400 to 700 nm in the whole visible spectral region. The luminescence color of the SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphor can be tuned from blue, blue-green, white, and orange to orange-red by changing the excitation wavelength, the overall doping concentration of europium ions (Eu 2+ , Eu 3+ ), and the relative ratio of Eu 2+ to Eu 3+ ions to some extent. A single-phase white-light emission has been realized in SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphor. The obtained SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphor has potential application in the area of NUV white-light-emitting diodes.

The Impact of the Explosion of EU News on Voter Choice in the 2014 EU Elections

Directory of Open Access Journals (Sweden)

Jan Kleinnijenhuis

2016-02-01

Full Text Available The European elections in 2014 were the first to be held after a long period in which EU-related news was prominent in the media. They were held after years of daily news about the euro crisis and after months of news about the popular uprising in the Ukraine against president Yanukovych, who had refused to sign the association agreement with the EU. This could have invited political parties to overcome the usual problem of low salience of EU issues by strongly profiling themselves on EU issues. Turnout at the 2014 EU elections, however, remained low, hinting that parties were unable to convert the attention for European issues into enthusiasm for their party at the European elections. This paper asks how vote choice was influenced by party campaigning on EU related issues. A news effects analysis based on a content analysis of Dutch newspapers and television, and on a panel survey among Dutch voters revealed that EU issues functioned as wedge issues: the more strongly parties were associated in the news with the euro crisis and the Ukraine, the less they succeeded in mobilizing voters.

Carbon pricing in the EU: Evaluation of different EU ETS reform options

International Nuclear Information System (INIS)

Brink, Corjan; Vollebergh, Herman R.J.; Werf, Edwin van der

2016-01-01

This paper studies various options to support allowance prices in the EU Emissions Trading System (ETS), such as adjusting the cap, an auction reserve price, and fixed and variable carbon taxes in addition to the EU ETS. We use a dynamic computable general equilibrium model that explicitly allows for allowance banking and for a detailed cost-effectiveness analysis at the EU Member State level. We find that tightening the cap provides an ad hoc solution to the fundamental issue of the robustness of the effective carbon price, while introducing a price component to the ETS brings structural carbon price support in times of negative demand shocks for emission allowances. These price-based policies still benefit from the intertemporal flexibility through the banking provision in the EU ETS by re-allocating emissions over time with stronger emission reductions in early years and emission increases in later years. A higher emission price has a larger negative impact on the new Member States' economies than on other Member States. Furthermore, introducing a carbon tax in addition to the EU ETS decreases the price of allowances, resulting in welfare gains for net buyers of allowances while net sellers are worse off. - Highlights: • We analyse reform options for European Union Emission Trading System (EU ETS) with a CGE model. • Variable carbon tax and auction reserve price support carbon price at least cost. • Price-based reforms decrease early emissions but increase later emissions through banking. • New Member States' economies are affected more than others by higher CO_2 prices. • Lower allowance prices due to a carbon tax are unfavourable to net sellers of allowances.

EU Energy Policy in a Supply-constrained World

International Nuclear Information System (INIS)

De Jong, J.; Van der Linde, C.

2008-10-01

Energy is quickly becoming an issue of integration and disintegration of the EU and will perhaps turn out to be the ultimate litmus test of political and economic unity in the EU, as energy issues are increasingly intertwined with wider security issues on the continent. Very often, economic issues are elevated to the political-strategic level, serving a different agenda than merely contributing to the energy policy agenda of the EU. The challenges to the EU and its member states in the energy sector are many: some issues are part of the wider geopolitical and geo-economic agenda, but some are also the product of the new EU that emerged after the fall of the Berlin Wall. The enlargement with member states that are asymmetrically dependent on oil and gas supplies mainly from Russia has further emphasised the growth of structural energy import dependency. Moreover, the new member states did not have the benefit of introducing the energy 'acquis', i.e. liberalisation, in a period of ample supply and relatively low prices. From 2004 onwards, energy has become tighter and more politicised. It was these developments that also uncovered the calculated risk of the old member states to embark on liberalisation without putting a crisis management policy into place. With the increasing worries about the security of supply and the asymmetric exposure of Eastern Europe to a single supplier, energy security issues also began to dominate the internal policy debates both in energy and in external relations. The new developments require the EU member states to consider how and to what extent their external energy policies should also be merged into a more EU-wide approach, if they can agree on the common risks that need to be averted and the common benefits gained, and if and how a crisis mechanism for fuels other than oil is needed to manage the perceived increased security of supply risks. Moreover, they should also consider the internal market design they set out to implement and

Synthesis and characterization of a liquid Eu precursor (EuCp{sup pm}{sub 2}) allowing for valence control of Eu ions doped into GaN by organometallic vapor phase epitaxy

Energy Technology Data Exchange (ETDEWEB)

Mitchell, Brandon, E-mail: bmitchell@wcupa.edu [Department of Physics, West Chester University, West Chester, PA, 19383 (United States); Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871 (Japan); Koizumi, Atsushi; Nunokawa, Takumi; Wakamatsu, Ryuta; Lee, Dong-gun; Saitoh, Yasuhisa; Timmerman, Dolf [Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871 (Japan); Kuboshima, Yoshinori; Mogi, Takayuki; Higashi, Shintaro; Kikukawa, Kaoru [Kojundo Chemical Laboratory Co., Ltd., 5-1-28 Chiyoda, Sakado, Saitama, 350-0284 (Japan); Ofuchi, Hironori; Honma, Tetsuo [Japan Synchrotron Radiation Research Institute (JASRI/SPring-8), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo, 679-5198 (Japan); Fujiwara, Yasufumi, E-mail: fujiwara@mat.eng.osaka-u.ac.jp [Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871 (Japan)

2017-06-01

A liquid Eu precursor, bis(normal-propyl-tetramethylcyclopentadienyl)europium has been synthesized. This precursor exists as a liquid at temperatures higher than 49 °C, has a moderately high vapor pressure, contains no oxygen in its molecular structure, and can be distilled to high purity. These properties make it ideal for doping using a chemical vapor or atomic layer deposition method, and provide a degree of control previously unavailable. As a precursor the Eu exists in the divalent valance state, however, once doped into GaN by organometallic vapor phase epitaxy, the room-temperature photoluminescence of the Eu-doped GaN exhibited the typical red emission due to the intra-4f shell transition of trivalent Eu. After variation of the growth temperature, it was found that divalent Eu could be stabilized in the GaN matrix. By tuning the Fermi level through donor doping, the ratio of Eu{sup 2+} to Eu{sup 3+} could be controlled. The change in valence state of the Eu ions was confirmed using X-ray absorption near-edge structure. - Highlights: • A liquid Eu precursor was synthesized and its properties were characterized. • Precursor has a low melting point and a moderately high vapor pressure. • Does not contain oxygen in its molecular structure. • Eu can changed its valance state when incorporated into GaN. • Valence state of Eu in GaN can be controlled by donor doping.

The EU's cybercrime and cyber-security rulemaking: mapping the internal and external dimensions of EU security

NARCIS (Netherlands)

Fahey, E.

2014-01-01

By taking the EU Cyber Strategy as a case in point, this contribution examines how the distinction between external and internal security in contemporary EU law manifests itself in large-scale risk regulation and in particular, how the EU relies upon external norms to regulate risk. This article

Electrochemical reduction of Eu (III) in propionic media

International Nuclear Information System (INIS)

Brotto, M.E.; Rabockai, T.

1988-01-01

Some chronopotentiometric studies of Eu (III) electro-reducion in propionic media that suggests the presence of two parallel rections: Eu (III) → Eu (II) and Eu (III) → Eu (II) → Y are presented. Some experimental data, such Eu (III) reducion, electrolysis of solutions and ionic power of the system are discussed. (M.J.C.) [pt

Advances in Metal Supported Cells in the METSOFC EU Consortium

DEFF Research Database (Denmark)

McKenna, Brandon J.; Christiansen, Niels; Schauperl, Richard

2012-01-01

Employing a mechanically robust metal support as the structural element in SOFC has been the objective of various development efforts. The EU-sponsored project “METSOFC”, completed at the end of 2011, resulted in a number of advancements towards implementing this strategy. These include robust me...... outcomes of the METSOFC consortium are covered, along with associated work supported by the Danish National Advanced Technology Foundation.......Employing a mechanically robust metal support as the structural element in SOFC has been the objective of various development efforts. The EU-sponsored project “METSOFC”, completed at the end of 2011, resulted in a number of advancements towards implementing this strategy. These include robust...... metal supported cells (MSCs) having low ASR at low temperature, incorporation into small stacks of powers approaching ½kW, and stack tolerance to various operation cycles. DTU Energy Conversion's (formerly Risø DTU) research into planar MSCs has produced an advanced cell design with high performance...

Dependence of photoluminescence (PL) emission intensity on Eu3+ and ZnO concentrations in Y2O3:Eu3+ and ZnO·Y2O3:Eu3+ nanophosphors

CSIR Research Space (South Africa)

Mhlongo, GH

2011-08-01

Full Text Available Y2O3:Eu3+ and ZnO·Y2O3:Eu3+ nanophosphor powders with different concentrations of Eu3+ ions were synthesized by a sol–gel method and their luminescence properties were investigated. The red photoluminescence (PL) from Eu3+ ions with the main...

Enforcement Alert: Hazardous Waste Management Practices at Mineral Processing Facilities Under Scrutiny by U.S. EPA; EPA Clarifies 'Bevill Exclusion' Wastes and Establishes Disposal Standards

Science.gov (United States)

This is the enforcement alert for Hazardous Waste Management Practices at Mineral Processing Facilities Under Scrutiny by U.S. EPA; EPA Clarifies 'Bevill Exclusion' Wastes and Establishes Disposal Standards

Reform of the EU's climate policy. Small step or big hit?

International Nuclear Information System (INIS)

Janssen, Matthias; Peichert, Patrick; Perner, Jens; Riechmann, Christoph

2015-01-01

Emissions trading listed as a flexible mechanism under the Kyoto Protocol is regarded as a market economy way in climate protection. Since 2005 the European Emissions Trading System (EU ETS) is the central climate policy instrument for reducing the emissions of greenhouse gases, in particular for carbon dioxide (CO 2 ). For years, however, the CO 2 price is too low to direct the politically and socially targeted technical innovations in the electricity sector and the industry. The article analyses the temporary and structural causes of this problem, highlights the EU's reform efforts and points to areas of activity, the basis of which the EU ETS may act in the future as a central instrument for climate protection in the European Union. [de

Consequences of EU air quality directives for spatial development plans in various EU countries

International Nuclear Information System (INIS)

Koelemeijer, R.B.A.; Blom, W.F.; Bouwman, A.A.; Hammingh, P.; Backes, C.W.

2005-01-01

Over the past few years, the highest Dutch court of justice has rejected many building plans for new homes, roads and businesses because of reasons related to EU air quality limit values. This has made it clear that detailed impact assessments are necessary to having plans approved for permits, and that failure to achieve limit values can be a reason to reject a plan. An investigation to see whether such issues have also played a role in other EU countries has proven the contrary. Only a few similar court cases have taken place in other countries, while air quality limit values are breached in other EU countries as well. The reason is that the Netherlands has implemented the first EU Daughter Directive in a relatively strict manner in comparison to other countries, in particular: Adopting a strict legal coupling of air quality and spatial planning policies, with many types of plans being subject to an air quality impact assessment; Perceiving limit values as absolute limit values, whereas in many other countries a need to meet a limit value is weighted with other interests in granting permits; Applying limit values to the whole country. Although this application is, in principle, valid for all EU member states, some member states apply limit values only to locations where people can be exposed; Since air quality assessment is detailed in the Netherlands, many locations are appointed where air quality limit values are breached. Clearly, the role of limit values in granting permits for plans differs considerably among the EU countries, while the underlying EU legislation is the same, and while limit values are breached in other countries as well [nl

An electric mandate. The EU procedure for harmonising cross-border network codes for electricity

Energy Technology Data Exchange (ETDEWEB)

Jevnaker, Torbjoerg

2012-07-01

The research question addressed in this report is why the EU procedure for developing network codes for electricity was enacted in its particular form. Passed by the EU in 2009, European organisations partly outside of the formal EU structure were given a mandate to make rules that would apply across the EU. This was puzzling given the observed resistance on part of the member states to let go of national control over energy issues. Drawing on institutionalist perspectives, the analysis shows that the procedure would not have been passed without support from and compromise among the Commission, European Parliament and the member states in Council; that parts of the procedure imitated existing practices within related policy areas; that horizontal and vertical specialization within the nation-states along with a Commission actively promoting transnational cooperation changed the feedback mechanisms, which changed the direction of European energy market regulation; and finally, that the new actors played an active role vis-a-vis EU bodies as the latter were legislating on the procedure. (Author)

Luminescence and energy transfer mechanism in Eu{sup 3+}/Tb{sup 3+}-co-doped ZrO{sub 2} nanocrystal rods

Energy Technology Data Exchange (ETDEWEB)

Ahemen, I., E-mail: ahemior@gmail.com; Dejene, F. B. [University of the Free State-QwaQwa Campus, Department of Physics (South Africa)

2017-01-15

Nanocrystal rods of Eu{sup 3+}/Tb{sup 3+}-co-doped ZrO{sub 2} were synthesized using a simple chemical precipitation technique. Both ions were successfully doped into the Zr{sup 4+} ion site in a mixed structure containing both monoclinic and tetragonal phases. The Eu{sup 3+} or Tb{sup 3+} singly doped zirconia produced red and green luminescence which are characteristics of Eu{sup 3+} and Tb{sup 3+} ions, respectively. The co-doped zirconia samples produced blue emission from defect states transitions in the host ZrO{sub 2}, red and green luminescence from dopant ions giving cool to warm white light emissions. The phosphors were efficiently excited by ultraviolet and near-ultraviolet/blue radiations giving white and red light, respectively. The decay lifetime was found to increase with increasing donor ion concentration contrary to conventional observations reported by previous researchers. Weak quadrupole–quatdrupole multipolar process was responsible for energy transfer from Tb{sup 3+} (donor) ion to Eu{sup 3+} ion. No energy back-transfer from Eu{sup 3+} to Tb{sup 3+} ion was observed from the excitation spectra. Temperature-dependent photoluminescence shows the presence of defects at low temperature, but these defects vanished at room temperature and beyond. The Eu{sup 3+}/Tb{sup 3+}-co-doped ZrO{sub 2} nanocrystal rod is a potential phosphor for white light application using UV as an excitation source. Thermoluminescence measurements show that the inclusion of Tb{sup 3+} ion increases trap depths in the host zirconia.

Luminescent properties of BaCl2-Eu microcrystals embedded in a CsI matrix

International Nuclear Information System (INIS)

Pushak, A.; Vistovskyy, V.; Voloshinovskii, A.; Savchyn, P.; Antonyak, O.; Demkiv, T.; Dacyuk, Yu.; Myagkota, S.; Gektin, A.

2013-01-01

The spectral-luminescent properties of CsI-BaCl 2 (1 mol%)-Eu(0.02 mol%) crystalline system are studied. Europium ion doped BaCl 2 microcrystals embedded in a CsI matrix are revealed on CsI-BaCl 2 (1 mol%)-Eu(0.02 mol%) freshly cleaved surface by the scanning electron microscopy. The size of microcrystals is shown to be within 0.5–5 microns. The luminescent parameters of the BaCl 2 -Eu 2+ microcrystals are shown to be similar to ones of a single crystal analogue. The 4f → 5d absorption transitions in europium ions and the reabsorption of the intrinsic emission of the CsI host are the main excitation mechanisms of europium luminescence in the BaCl 2 microcrystals. -- Highlights: ► The formation of chloride BaCl 2 :Eu microcrystals in the case of BaCl 2 doped CsI crystal has been revealed. ► The observed size of microcrystals at BaCl 2 concentration of 1% is about 0.5–5 μm. ► Majority of Eu 2+ ions in CsI-BaCl 2 -EuCl 3 crystalline system enters into BaCl 2 microcrystals. ► The luminescent parameters of the BaCl 2 :Eu 2+ microcrystals and its bulk analogue are similar

Triple energy transfer and color tuning in Tb3+ and Eu3+-coactivated apatite-type gadolinium-containing phosphors

Science.gov (United States)

Guo, Ning; Liang, Qimeng; Li, Shuo; Ouyang, Ruizhuo; Lü, Wei

2017-11-01

A family of apatite-type fluorophosphate phosphors with general formula Sr3Gd(1-m-n)Na(PO4)3F:mTb3+,nEu3+ (SGN:mTb3+,nEu3+) have been synthesized via the high-temperature solid-state reaction method. Triple energy transfer processes from Gd3+ in the host to both Tb3+ and Eu3+, as well as from Tb3+ to Eu3+ have been verified by the photoluminescence spectra. Under the excitation of UV light, both green line from the transitions of Tb3+ and red line origin from the transitions of Eu3+ have been simultaneously observed in a single phase phosphor, which makes a promise for tunable color emissions from yellowish-green through yellow and ultimately to reddish-orange by simply adjusting the Eu3+ content (n) in SGN:0.20Tb3+,nEu3+ phosphors. Additionally, the energy transfer from the Tb3+ to the Eu3+ ions has been demonstrated to be a resonant type via a quadrupole-quadrupole mechanism based on the Dexter's theoretical model, and the energy transfer efficiency increases with an increase in Eu3+ concentration.

Reforming the EU Budget

DEFF Research Database (Denmark)

Citi, Manuele

The marginal involvement of the EU in redistributive policies and its limited fiscal resources have led to a lack of attention to the EU budget and its determinants. In this paper I analyse an original dataset containing yearly data on the main macrocategories of expenditure and how they have...

EU Labour Law

DEFF Research Database (Denmark)

Nielsen, Ruth

The focus in this book is upon EU labour law and its interaction with national and international labour law. The book provides an analysis of the framework and sources of European labour law. It covers a number of substantive topics, notably collective labour law, individual employment contracts......, discrimination on grounds of sex and on other grounds, free movement of persons, restructuring of enterprises, working environment and enforcement of rights derived from EU labour law....

Varying Eu2+ magnetic order by chemical pressure in EuFe2(As1-xPx)2

Science.gov (United States)

Zapf, S.; Wu, D.; Bogani, L.; Jeevan, H. S.; Gegenwart, P.; Dressel, M.

2011-10-01

Based on low-field magnetization measurements on a series of single crystals, we present a scheme of the Eu2+ spin alignment in EuFe2(As1-xPx)2. We explain observations of the Eu2+ ordering previously reported, reconciling different existing phase diagrams. The magnetic moments of the Eu2+ ions are slightly canted, yielding a ferromagnetic contribution along the c direction that becomes stronger with pressure, until superconductivity sets in. The spin-density wave as well as the superconducting phase coexist with an antiferromagnetic interlayer coupling of the canted spins. Reducing the interlayer distance finally leads to a ferromagnetic Eu2+ interlayer coupling and to the suppression of superconductivity.

Key challenges in the combat of human trafficking : Evaluating the EU trafficking strategy and EU trafficking directive

NARCIS (Netherlands)

Bosma, Alice; Rijken, Conny

2016-01-01

The problem of trafficking in human beings (THB) is still omnipresent in Europe, despite the numerous preventive and retributive actions taken. This article evaluates the two most important EU-instruments to combat trafficking: the EU Directive and the EU Strategy. Based on secondary analysis of

TRLIFS study of Eu(III) spectroscopic properties to obtain structural and thermodynamic informations on lanthanide-malonamide complexes in the Eu(III)/NaNO3/tetraethylmalonamide system

International Nuclear Information System (INIS)

Couston, L.; Charbonnel, M.C.; Flandin, J.L.; Rancier, F.; Moulin, C.

2004-01-01

Improvement of the nuclear fuel reprocessing involves separating the minor actinides (Am(III) and Cm(III)) from the fission products. In the French strategy, the first step consists in the separation of the trivalent actinides and lanthanides from high-level liquid waste, for which malonamides RR'NCO(CHR '' )CONRR' are promising ligands. These molecules have been optimized for reprocessing but still require basic chemical studies to describe the complexation mechanisms at a molecular scale. This paper discusses a thermodynamic and structural study of a Ln(III)-malonamide complex formed with the hydrosoluble tetraethylmalonamide ligand (TEMA = (C 2 H 5 ) 2 NCOCH 2 CON(C 2 H 5 ) 2 ) dissolved in a nitrate medium. Despite the simplified chemical system obtained with TEMA, its weak chemical affinity and its physical properties pushed the analytical techniques to their limits. The sensitivity of time-resolved laser-induced fluorescence spectroscopy (TRLIFS) combined with the major luminescent spectroscopic properties of Eu(III) (hypersensitive band and fluorescence lifetime) were successfully used to determine the equilibrium constant and hydration number in the Eu(III), TEMA, and NO 3 - system. Fluorescence lifetimes, connected with the first coordination sphere of the solvated metal, clearly show the inner-sphere location of nitrate in the Eu(NO 3 ) 2+ complex, the outer-sphere location of TEMA in the Eu(TEMA) 3+ complex, and the outer-sphere location of both ligands in the Eu(NO 3 )(TEMA) 2+ complex. (orig.)

EU's hær skal tale tyrkisk

DEFF Research Database (Denmark)

Adler-Nissen, Rebecca

2009-01-01

For at kunne udleve sine accelererende forsvarsambitioner har EU brug for at låne Tyrkiets 600.000 soldater. Hvis Tyrkiet ikke kan blive EU-medlem, må svaret være at give tyrkerne 'associeret medlemskab' af EU's sikkerhedspolitik. Sker det, vil Tyrkiet med ét være bedre integreret i EU-forsvaret ...

Are EU Banks Safe?

NARCIS (Netherlands)

R.J. Theissen (Roel)

2013-01-01

markdownabstract__Abstract__ What exactly are the rules banks are subject to, and are they fit for purpose? These are the two questions addressed in this book ‘Are EU banks safe?’ and its descriptive companion book ‘EU banking supervision’. The full rulebook on banks is difficult to find

Stormy weather. Echoes of Columbia/HCA heard as Tenet overhauls management amid scrutiny of outliner payments and investor protests.

Science.gov (United States)

Galloro, Vince

2002-11-11

What began as a small shower of questions quickly transformed into a storm of investor protest last week as Tenet Healthcare Corp. underwent a management overhaul and analysts asked questions about its fiscal future. Tenet's business strategy came under scrutiny because a large proportion of its Medicare revenue was generated by so-called outlier payments. Chairman and CEO Jeffrey Barbakow (left) says that's not how he wants to do business.

EU agricultural reform fails on biodiversity

NARCIS (Netherlands)

Pe'er, G.; Dicks, L.V.; Visconti, A.; Arlettaz, R.; Baldi, A.; Kleijn, D.; Scott, A.V.

2014-01-01

In December 2013, the European Union (EU) enacted the reformed Common Agricultural Policy (CAP) for 2014–2020, allocating almost 40% of the EU's budget and influencing management of half of its terrestrial area. Many EU politicians are announcing the new CAP as “greener,” but the new environmental

The New European and/or EU Studies Curriculum

OpenAIRE

Brie, Mircea; Dolghi, Dorin; Pantea, Dana

2011-01-01

In this part we will present turn by turn the evolution of the curriculum in four domains which are developing in the area of European and/or EU Studies: EU Intercultural Dialogue Studies, EU International Relations and Diplomacy Studies, EU Communication and Information Studies, EU and Comparative Regionalism, from several points of view. First, we will take into consideration the perspective that each curriculum from the four domains has in the ensemble of European and/or EU Studies, t...

Den brede, folkelige debat om EU

DEFF Research Database (Denmark)

Dosenrode, Søren

2005-01-01

I Danmark er EUropa noget fjernt på trods af, at EU er rammen om dansk politik, både udenrigs og indenrigs. Danmark er medlem af en de facto føderation, men de brede folkelige debater om hvordan EU skal gestaltes har manglet.......I Danmark er EUropa noget fjernt på trods af, at EU er rammen om dansk politik, både udenrigs og indenrigs. Danmark er medlem af en de facto føderation, men de brede folkelige debater om hvordan EU skal gestaltes har manglet....

Negative pressure driven valence instability of Eu in cubic Eu{sub 0.4}La{sub 0.6}Pd{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Pandey, Abhishek [S N Bose National Centre for Basic Sciences, Block-JD, Sector-III, Salt Lake, Kolkata-700098 (India); Mazumdar, Chandan; Ranganathan, R [Experimental Condensed Matter Physics Division, Saha Institute of Nuclear Physics, 1/AF, Bidhannagar, Kolkata-700064 (India)], E-mail: abhishek.phy@gmail.com, E-mail: chandan.mazumar@saha.ac.in

2009-05-27

We report the change in the valency of Eu-ions in the binary intermetallic cubic compound EuPd{sub 3} induced by La doping at rare-earth sites. Doping of La generates negative chemical pressure in the lattice, resulting in a significant increase of the lattice parameter without altering the simple-cubic structure of the compound. Results of dc-magnetic measurements suggest that this increase in the lattice parameter is associated with the valence transition of Eu-ions from Eu{sup 3+} to a mixed-valent state. As Eu{sup 2+}-ions possess a large magnetic moment, this valence transition significantly modifies the magnetic behavior of the compound. In contrast to introducing boron at the vacant body center site of the unit cell to change the valency of Eu-ions, as in the case of EuPd{sub 3}B, our results suggest it can also be altered by doping a rare-earth ion of larger size at the lattice site of Eu in EuPd{sub 3}.

Eu3+-doped Y2O3 hexagonal prisms: Shape-controlled synthesis and tailored luminescence properties

International Nuclear Information System (INIS)

Yang, Errui; Li, Guangshe; Fu, Chaochao; Zheng, Jing; Huang, Xinsong; Xu, Wen; Li, Liping

2015-01-01

In this work, Eu 3+ doped Y 2 O 3 hexagonal prisms were synthesized by a novel two-phase approach, which involves water at the bottom as aqueous phase and oleylamine in the above as oil phase. With this unique reaction system, precursors of hexagonal prisms Y 4 O(OH) 9 (NO 3 ) were first obtained by simply varying the volume ratio of water to oleylamine. Time-dependent experiments were systematically performed to reveal the growth mechanism of the precursor. After subsequent heat treatment, these precursors transformed to Y 2 O 3 hexagonal prisms with controlled diameters and aspect ratios varying from 4 to 19. Such a transformation is preceded via a topotactic process, as indicated by TG-DTA and mass spectra. Eventually, all Eu 3+ doped Y 2 O 3 hexagonal prisms were found to exhibit an intensive red emission at 611 nm, which corresponds to 5 D 0 → 7 F 2 transition of Eu 3+ . With varying the aspect ratio of hexagonal prisms and increasing Eu 3+ concentration in Y 2 O 3 , an optimum external quantum efficiency was achieved. - Graphical abstract: In this work, Eu 3+ doped Y 2 O 3 hexagonal prisms with controlled aspect ratio from 4.4 to 19.3 were synthesized by transformation of the precursor Y 4 O(OH) 9 (NO 3 ) hexagonal prisms from a novel two-phase reaction system. The growth mechanism of the precursor has been systematically investigated, and a topotactic phase transformation from precursors to cubic Y 2 O 3 is for the first time put forward. By the size controlling and aspect ratio adjusting, the luminescence emission intensity as well as external quantum efficiency of Eu 3+ doped Y 2 O 3 hexagonal prisms is further tailored to show an optimum. - Highlights: • Eu 3+ doped Y 2 O 3 hexagonal prisms were synthesized by a novel two-phase approach. • Inheriting mechanism of prisms morphology from Y 4 O(OH) 9 (NO 3 ) to Y 2 O 3 was discussed. • Aspect ratio of prisms was tailored by the volume ratio of water to oleylamine. • Luminescence properties were

Persistent detwinning of EuFe{sub 2}As{sub 2} by small magnetic fields

Energy Technology Data Exchange (ETDEWEB)

Maiwald, Jannis; Stingl, Christian; Bach, Nora; Jeevan, H.S.; Gegenwart, Philipp [Experimentalphysik VI, Universitaet Augsburg (Germany); Zapf, Sina; Jiang, Shuai; Neubauer, David; Loehle, Anja; Clauss, Conrad; Dressel, Martin [1. Physikalisches Institut, Universitaet Stuttgart (Germany); Post, Kirk; Basov, Dimitri [Department of Physics, UC San Diego (United States)

2015-07-01

The formation of twin domains in the orthorhombic phase of high-temperature superconductors is impeding the investigation of the in-plane anisotropy of these materials. Recently, we have shown how the brief application of a small magnetic field of ∝ 1 Tesla in the EuFe{sub 2}As{sub 2} iron pnictide leads to a substantial detwinning of the system, which is persistent up to the structural transition at ∝ 190 K even after the magnetic field has been switched off. This offers researchers the opportunity to investigate the detwinned iron arsenide without the application of any external symmetry breaking force, like the pressure of a mechanical clamp, or a magnetic field present during measurement. We will present angular dependent magnetoresistance, magnetostriction, thermal expansion and thermoelectric power measurements on the EuFe{sub 2}As{sub 2} parent compound as well as on various doped variants in order to shed further light on the mechanism behind the field induced detwinning, i.e. the interplay of the involved magnetic moments stemming form the Eu and Fe atoms in these compounds.

Why use experiments in EU Studies?

DEFF Research Database (Denmark)

Nielsen, Julie Hassing

2014-01-01

two things. First, by summarising the use of experiments in EU research, it provides an overview of the evolution of the use of experiments within EU studies. This includes a content exploration of the pioneering sub-areas within EU studies where experimentation is frequently used. Particular focus......The past decades have witnessed an explosion in the use of experiments. Though experiments have been increasingly applied, their recognition as useful methodological tools to investigate EU-related research questions has lagged behind the rest of the political science community. This article does...... is paid on election, framing and deliberation studies. Second, the article argues for the promising potentials experimentation provides for EU studies, overcoming problems of causal estimation as well as endogeneity concerns. The article concludes by addressing some of the critiques often made against...

Self-aggregation of magnetic semiconductor EuS nanocrystals

International Nuclear Information System (INIS)

Tanaka, Atsushi; Hasegawa, Yasuchika; Kamikubo, Hironari; Kataoka, Mikio; Kawai, Tsuyoshi

2009-01-01

Controlled formation of aggregates having organized structure of cube-shaped EuS nanocrystals is reported. The EuS aggregates in liquid media (methanol) were obtained by means of van der Waals interaction between EuS nanocrystals. The packing structure of the EuS aggregates is characterized with transmission electron microscopy (TEM) and small angle X-ray scattering measurements (SAXS). TEM image indicates the EuS nanocrystals form self-aggregated 2D orthogonal lattice structure. The diffraction peak of (111) of SAXS profile shows that the cube-shaped EuS form 3D cubic superlattice. We successfully demonstrated that the aggregates of cube-shaped EuS nanocrystals formed cubic stacking structure.

ENHANCING EU-TAIWAN ECONOMIC COOPERATION AGREEMENT

Directory of Open Access Journals (Sweden)

Chung-hung Cho

2018-01-01

Full Text Available The EU’s 2015 new trade strategy: Trade for all: toward a more responsible trade and investment policy, highlights its key role in keeping markets open worldwide and lists the Asia-Pacific region as the priority party for signing Regional Trade Arrangements (RTAs with the EU. The new strategy allows the EU and its member states to initiate talks on economic cooperation agreement (ECA with Taiwan. This article takes the EU-Asia interregional cooperation as a case study while exploring the role of Taiwan in the region. The first section describes the shift in EU’s trade policies and the special features of the types of interregionalism between the EU and Asia. The second section explores the bilateral trade relations. The third section evaluates the opportunities and the internal and external challenges and limitations of an EU-Taiwan ECA, emphasizing the factor of mainland China. The final section provides conclusions on the influence of an EU-Taiwan ECA on the relations of EUTaiwan considering economic and non-economic factor

The exploration and characterization of an orange emitting long persistent luminescence phosphor LiSr4(BO3)3:Eu2+

International Nuclear Information System (INIS)

Jin, Yahong; Hu, Yihua; Wu, Haoyi; Chen, Li; Wang, Xiaojuan

2016-01-01

An orange emitting long persistent phosphor LiSr 4 (BO 3 ) 3 :Eu 2+ was prepared successfully using a conventional solid state reaction method. The luminescent and persistent luminescence properties were studied using fluorescence spectra, decay curves, persistent luminescence spectra and thermoluminescence (TL) glow curves. The effects on the fluorescence and persistent luminescence properties by the dosage of Li 2 CO 3 were explored. The relationship between the Eu 2+ contents and persistent luminescence properties were studied. The optimal doping concentration of Eu 2+ was experimentally to be 1 mol%. The detailed processes and a possible mechanism were also discussed. - Highlights: • Li 2 CO 3 plays a critical role in producing persistent luminescence. • 40 % excess of Li 2 CO 3 makes the largest enhancement on persistent luminescence. • The optimal doping concentration of Eu 2+ was experimentally to be 1mol %. • Possible mechanism for persistent luminescence was discussed.

Legitimate Governance of Risk at the EU level? The Case of GMOs

DEFF Research Database (Denmark)

Borras, Susana

2006-01-01

In the past few years, the EU has been establishing a new regulatory framework for GMOs, a central issue in the governance of risk that came under fierce attack in the mid-1990s. The primary question addressed in this article is whether this new framework will be able to solve the legitimacy...... problem of GMO governance at the EU level. Focusing on theories concerning input–output legitimacy and democracy and the role of expertise, this article examines the level of involvement of stakeholders in the process leading to the new rules; the predominant mechanisms of representation that have been...

The N2HDM under theoretical and experimental scrutiny

Energy Technology Data Exchange (ETDEWEB)

Mühlleitner, Margarete [Institute for Theoretical Physics, Karlsruhe Institute of Technology, 76128 Karlsruhe (Germany); Sampaio, Marco O.P. [Departamento de Física, Universidade de Aveiro and CIDMA, Campus de Santiago, 3810-183 Aveiro (Portugal); Santos, Rui [ISEL - Instituto Superior de Engenharia de Lisboa, Instituto Politécnico de Lisboa, 1959-007 Lisboa (Portugal); Centro de Física Teórica e Computacional, Faculdade de Ciências, Universidade de Lisboa, Campo Grande, Edifício C8, 1749-016 Lisboa (Portugal); Wittbrodt, Jonas [Institute for Theoretical Physics, Karlsruhe Institute of Technology, 76128 Karlsruhe (Germany); Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, D-22607 Hamburg (Germany)

2017-03-17

The N2HDM is based on the CP-conserving 2HDM extended by a real scalar singlet field. Its enlarged parameter space and its fewer symmetry conditions as compared to supersymmetric models allow for an interesting phenomenology compatible with current experimental constraints, while adding to the 2HDM sector the possibility of Higgs-to-Higgs decays with three different Higgs bosons. In this paper the N2HDM is subjected to detailed scrutiny. Regarding the theoretical constraints we implement tests of tree-level perturbativity and vacuum stability. Moreover, we present, for the first time, a thorough analysis of the global minimum of the N2HDM. The model and the theoretical constraints have been implemented in ScannerS, and we provide N2HDECAY, a code based on HDECAY, for the computation of the N2HDM branching ratios and total widths including the state-of-the-art higher order QCD corrections and off-shell decays. We then perform an extensive parameter scan in the N2HDM parameter space, with all theoretical and experimental constraints applied, and analyse its allowed regions. We find that large singlet admixtures are still compatible with the Higgs data and investigate which observables will allow to restrict the singlet nature most effectively in the next runs of the LHC. Similarly to the 2HDM, the N2HDM exhibits a wrong-sign parameter regime, which will be constrained by future Higgs precision measurements.

The N2HDM under theoretical and experimental scrutiny

International Nuclear Information System (INIS)

Mühlleitner, Margarete; Sampaio, Marco O.P.; Santos, Rui; Wittbrodt, Jonas

2017-01-01

The N2HDM is based on the CP-conserving 2HDM extended by a real scalar singlet field. Its enlarged parameter space and its fewer symmetry conditions as compared to supersymmetric models allow for an interesting phenomenology compatible with current experimental constraints, while adding to the 2HDM sector the possibility of Higgs-to-Higgs decays with three different Higgs bosons. In this paper the N2HDM is subjected to detailed scrutiny. Regarding the theoretical constraints we implement tests of tree-level perturbativity and vacuum stability. Moreover, we present, for the first time, a thorough analysis of the global minimum of the N2HDM. The model and the theoretical constraints have been implemented in ScannerS, and we provide N2HDECAY, a code based on HDECAY, for the computation of the N2HDM branching ratios and total widths including the state-of-the-art higher order QCD corrections and off-shell decays. We then perform an extensive parameter scan in the N2HDM parameter space, with all theoretical and experimental constraints applied, and analyse its allowed regions. We find that large singlet admixtures are still compatible with the Higgs data and investigate which observables will allow to restrict the singlet nature most effectively in the next runs of the LHC. Similarly to the 2HDM, the N2HDM exhibits a wrong-sign parameter regime, which will be constrained by future Higgs precision measurements.

Fermi Surface Properties of Eu-Divalent and Eu-Trivalent Electronic States with the AuCu3-type Cubic Structure

International Nuclear Information System (INIS)

Nakamura, Ai; Takeuchi, Tetsuya; Tatetsu, Yasutomi; Maehira, Takahiro; Hedo, Masato; Nakama, Takao; Ōnuki, Yoshichika; Harima, Hisatomo

2015-01-01

The electronic states in EuBi 3 and EuPd 3 are known to be Eu-divalent and Eu- trivalent, respectively, from the previous studies using polycrystal samples. In the present study, we succeeded in growing high-quality single crystals, and carried out the de Haas-van Alphen (dHvA) measurements and energy band calculations to clarify the Fermi surface properties

Moessbauer spectroscopy of 151Eu and 153Eu. Applications to structural chemistry and electronic properties of rare-earth compounds

International Nuclear Information System (INIS)

Meyer, Marc.

1975-01-01

The decrease of the 151 Eu isomer shift on hydrogenation of a dilute EuPd alloy (2.5at% Eu) is discussed in term of the volume effect on the charge density at the nucleus. It is shown from 153 Eu Moessbauer spectroscopy in rare earth titanates that a vibrational anisotropy lead to the observation of a Goldanskii-Karyagin effect [fr

The europium(II) oxide halides Eu{sub 2}OBr{sub 2} and Eu{sub 2}OI{sub 2}; Die Europium(II)-Oxidhalogenide Eu{sub 2}OBr{sub 2} und Eu{sub 2}OI{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Rudolph, Daniel; Schleid, Thomas [Stuttgart Univ. (Germany). Inst. fuer Anorganische Chemie

2017-07-01

The syntheses and crystal structures of the two isotypic europium(II) oxide halides Eu{sub 2}OBr{sub 2} and Eu{sub 2}OI{sub 2} are reported. They crystallize orthorhombically in the space group Ibam (Z=4; Eu{sub 2}OBr{sub 2}: a=709.86(5), b=1200.34(9), c=628.71(4) pm; Eu{sub 2}OI{sub 2}: a=739.78(5), b=1295.13(9), c=644.82(4) pm). The unit cell parameters presented here, and thus the interatomic distances of Eu{sub 2}OI{sub 2}, are significantly smaller than the ones reported in the literature, which is explained by the substitution of europium with larger barium cations due to the synthesis route described in the early study. Central building blocks of both crystal structures are trans-edge-connected [OEu{sub 4}]{sup 6+} tetrahedra forming straight {sup 1}{sub ∞}{[OEu"e_4_/_2]"2"+} chains running parallel to the [001] direction. Bundled like a hexagonal rod packing, their interaction is achieved by Br{sup -} or I{sup -} anions for charge compensation.

EU ligger i Danmark!

DEFF Research Database (Denmark)

Adler-Nissen, Rebecca

2007-01-01

EU må ikke reduceres til et spørgsmål om folkeafstemninger. Den virkelige udfordring handler om, hvordan EU-beslutninger om alt fra dyretransporter til terrorbekæmpelse kan kontrolleres på en demokratisk måde. De beslutninger, der bliver truffet i Bruxelles er i højeste grad en del af den nationa...

Multicolor light emitters based on energy exchange between Tb and Eu ions co-doped into ultrasmall β-NaYF 4 nanocrystals

KAUST Repository

Podhorodecki, Artur P.

2012-01-01

Multicolor emission is reported from ultrasmall (<10 nm) β-NaYF4:Eu,Tb nanocrystals depending on the excitation wavelengths or emission detection delay time. Detailed optical investigations of three samples (NaYF4:Eu, NaYF4:Tb and NaYF4:Eu,Tb) obtained by a co-thermolysis method have been carried out. Photoluminescence, photoluminescence excitation and emission decay time obtained at different excitation wavelengths have been measured. Excitation mechanisms of Eu and Tb ions have been explained based on the experimental results and calculations using Judd-Ofelt theory. It has been shown that efficient energy transfer from Tb to Eu ions accounts for the efficient red emission of NaYF4:Tb,Eu nanocrystals. © The Royal Society of Chemistry 2012.

Development of the EU Ecolabel Criteria and Revision of the EU Green Public Procurement Criteria for Cleaning Services

OpenAIRE

DE ALMEIDA FERREIRA NETO BELMIRA; WOLF Oliver; FIELD Bethany; JENKIN Nicola; TAM Max; BENJAMIN Oscar

2016-01-01

The objective of this project is to develop a new EU Ecolabel and revise the existing EU Green Public Procurement (GPP) criteria for professional cleaning services (hereafter referred to as cleaning services). This preliminary report investigates the market, operational and sustainability aspects of cleaning services, with a goal to develop a robust evidence base and prioritise key environmental and social issues to support the development of EU Ecolabel criteria and the revision of the EU GP...

EU agricultural domestic support in GTAP

DEFF Research Database (Denmark)

Boulanger, Pierre; Philippidis, George; Jensen, Hans Grinsted

The engagement of JRC IPTS in the GTAP contributing team to the EU domestic support has opened up the opportunity to use the CATS database when compiling EU domestic support payments by member state, which are subsequently calibrated into the GTAP database. To maintain consistency, the GTAP version...... 9 includes EU domestic support which follows the approach adopted in the previous releases (Jensen, 2009, 2010). The difference is for pillar 1 support for which the CATS data are used (in previous GTAP database releases, pillar 1 support was based on EAGF financial reports). All together EU...

The expanding EU

DEFF Research Database (Denmark)

Zank, Wolfgang

In this paper I try to explore whether the EU can go on expanding and thereby become culturally ever more diversified, and at the same retain its stability. The answer is, in principle, affirmative. Europe has always been much diversified, and therefore it is not possible to define a European...... identity in terms of particular cultural traditions. However, in spite of their diversity, the EU-member countries are united by their adherence to the principles of democracy, rule by law and human rights. Countries which do not share this basic consensus would not be accepted as members, nor is it likely...... that they would apply for it. An essential part is the willingness of member states to accept a reduction of national sovereignty on some important policy fields. The EU project is basically about lifting the principles of democracy and rule by law on the international level, most and foremost among the member...

EU enlargement and new member countries' involvement in the exchange rates system

Directory of Open Access Journals (Sweden)

Vlatka Bilas

2005-08-01

Full Text Available For each country, joining the union is a unique process, considering advantages and disadvantages which a country can thus obtain. In order to fulfill conditions for the EU accession, transition countries must achieve different convergence criteria. Expansion of the EU brings along many challenges including coordination of policies and conducting a common monetary policy. After joining the EU new members are expected to have a minimum of two years of participation in the Exchange Rate Mechanism 2 before accepting euro. ERM2 can be a flexible and efficient framework for the determination of a appropriate level of irrevocable exchange rate fixing according to euro, as well as for achieving macroeconomic stability. Even though, considering demands for complete abolition of capital controls and high capital mobility, fixed exchange rate with fluctuation margins of ±15% is to become sensitive to the capital movements and speculative attacks.

Banking and Fiscal Unions in the EU: What is More Relevant?

Directory of Open Access Journals (Sweden)

Anna N. Tsibulina

2014-01-01

Full Text Available The article deals with financial system structures in the eurozone member states, linkages between banking sectors and fiscal solvency of states and EU initiatives towards improving frameworks to prevent and if necessary to deal with crises in the future. The global economic and financial crisis has revealed a close interrelation between banks problems and sovereigns in the EU. The instruments which were used by national governments in order to save systemically important banks forced the EU to revise approaches to bank supervision and establish new mechanisms for banks' restructuring. At the same time sovereign debt crises in a number of member-states, on the one hand, showed lack of an effective EU-wide system of control over a fiscal discipline and, on the other hand raised questions about lack of any system of fiscal transfers to countries hit by a negative shock. The New Banking and Fiscal unions have been designed to withshand those challenges. The author analyses problems which might be solved with the help of the new instruments established within theabove mentioned unions. At the same time far from all initiatives aimed at achieving greater fiscal consolidation might turn out to be effective when dealing with systemic problems in times of a crisis.

Structural and spectroscopic diagnosis of Eu:ZnO and Eu:Yb:ZnO glass and ceramics.

Science.gov (United States)

Bahadur, A; Dwivedi, Y; Rai, S B

2012-06-01

Eu and Eu:Yb codoped ZnO nanocrystals embedded in B(2)O(3) glass matrix were synthesized and their structural, optical properties were discussed. On excitation with 532 nm laser radiation intense orange/red emissions from Eu(3+) ions were observed. The fluorescence intensity was found to enhance on annealing. Frequency upconversion emissions from Eu(3+) ions were observed in presence of Yb(3+) ions on excitation with NIR (976 nm) laser. The enhancement in emission intensity was explained and the photo-physics involved is linked with the unique structural properties of the crystallites formed. Ion interactions and the different energy transfer parameters were also calculated. Copyright © 2012 Elsevier B.V. All rights reserved.

Concentration depolarization of luminescence of Eu3+-doped glasses

International Nuclear Information System (INIS)

Bodunov, E.N.; Lebedev, V.P.; Malyshev, V.A.; Przheuskij, A.K.

1989-01-01

Experimental study of concentrational depolarization luminescence (CDL) of phosphate and germanate glasses, containing Eu 3+ ions, has been carried out. On the basis of three-body self-consistent approximation the theory of CDL is conceived, which takes into account Eu-Eu interaction of higher multipolarities. By comparing the theory with the experiment energy transfer radii for Eu-Eu dipole-dipole, dipole-quadrupole and quadrupole-quadrupole interactions are determined. The attempt to discriminate Eu-Eu interaction types in the studied range of Eu 3+ ion concentration change has failed owing to law accuracy of luminescence emittance anisotropy measurement

Governing EU employment policy

DEFF Research Database (Denmark)

Sørensen, Eva; Triantafillou, Peter; Damgaard, Bodil

2015-01-01

In the European Union (EU), employment policy is a prerogative of the member states. Therefore the EU's ability to govern in this area depends on its capability to involve national governments and relevant stakeholders in a collaborative effort to formulate and implement shared policy objectives....... of collaboration, the implementation phase mainly consists in the less demanding forms of cooperation and coordination....

Tunable luminescence properties and efficient energy transfer in Eu2+, Tb3+ co-doped NaBaPO4

Directory of Open Access Journals (Sweden)

Qiuhong Zhang

2014-01-01

Full Text Available Eu2 + and Tb3+ singly doped and co-doped NaBaPO4 phosphors were synthesized by solid state reaction. The structure character, photoluminescence properties and the lifetime were investigated. The emission spectra of NaBaPO4:Eu2+, Tb3+, Na+ phosphor show both broad blue emission band and sharp green emission peaks. The energy transfer mechanism from Eu2+ to Tb3+ in NaBaPO4 host was discussed. The excitation spectra of NaBaPO4: Eu2+, Tb3+, Na+ phosphor show broad excitation band in the 250–400 nm range, which was in agreement with the near-ultraviolet (n-UV chip. The hue of the NaBaPO4: Eu2+, Tb3+, Na+ phosphors could be appropriately tuned by adjusting the contents of activators.

Financial Integration into EU: The Romanian Case

Directory of Open Access Journals (Sweden)

Ibrahim Bozkurt

2016-05-01

Full Text Available The aim of this study is to investigate the determinants of integration between stock market of Romania and other stock markets of European Union (EU countries. Correlations between the stock returns represent the level of integration between the stock markets. Empirical analysis are performed with daily stock returns of 24 EU members including Romania for 2002-2012 period using panel data gravity models and correlations are investigated. Findings reveal that the following factors have significant and robust effects on the financial integration process of Romania with other 23 EU members; (i EU membership, (ii bilateral trade, (iii GDP per capita, (iv 2012 sovereign debt crisis and (v East European location. The results emphasize that intensifying economic relations with EU members can contribute the integration of Romanian stock market with other EU members. designed & hoste

Valence behavior of Eu-ions in intermetallic compound Ce{sub 0.5}Eu{sub 0.5}Pd{sub 3}B{sub 0.5}

Energy Technology Data Exchange (ETDEWEB)

Pandey, Abhishek, E-mail: apandey@ameslab.gov [Experimental Condensed Matter Physics Division, Saha Institute of Nuclear Physics, 1/AF, Bidhannagar, Kolkata 700064 (India); S.N. Bose National Centre for Basic Sciences, Block-JD, Sector-III, Salt Lake, Kolkata 700098 (India); Mazumdar, Chandan, E-mail: chandan.mazumdar@saha.ac.in [S.N. Bose National Centre for Basic Sciences, Block-JD, Sector-III, Salt Lake, Kolkata 700098 (India); Ranganathan, R. [S.N. Bose National Centre for Basic Sciences, Block-JD, Sector-III, Salt Lake, Kolkata 700098 (India); Raghavendra Reddy, V.; Gupta, Ajay [UGC-DAE Consortium for Scientific Research, University Campus, Khandawa Road, Indore (India)

2011-12-15

We have studied the valence behavior of rare-earth ions, in particular Eu-ions, in a cubic intermetallic compound Ce{sub 0.5}Eu{sub 0.5}Pd{sub 3}B{sub 0.5} which is a homogeneous solid solution of two mixed-valent compounds CePd{sub 3} and EuPd{sub 3}B. Results of {sup 151}Eu Moessbauer spectroscopic measurements show that two different valence states, i.e., divalent- and trivalent-like states of Eu-ions exist in the compound. The possible reason for the observed heterogeneous valency vis-a-vis the variation in the chemical environment and the number of nearest-neighbor B atoms surrounding the Eu-ions has been discussed. Our results demonstrate that B incorporation in such Eu-based cubic intermetallic compounds leads to a situation where heterogeneous-valence state of Eu-ions is an energetically favorable ground state. - Highlights: > Intermetallic compound Ce{sub 0.5}Eu{sub 0.5}Pd{sub 3}B{sub 0.5} crystallizes in a single phase. > Eu-ions in Ce{sub 0.5}Eu{sub 0.5}Pd{sub 3}B{sub 0.5} are charge-ordered compared to +2.3 valency in Ce{sub 0.5}Eu{sub 0.5}Pd{sub 3}. > B incorporation makes charge-ordered state of Eu-ions energetically more favorable. > Nearest-neighbor chemical environment affects the Eu valency.

EuAuGe type indides RAgIn (R = Ca, Sr, La, Eu)

Energy Technology Data Exchange (ETDEWEB)

Stein, Sebastian; Schmolke, Kai Heinz; Block, Theresa; Heletta, Lukas; Hoffmann, Rolf-Dieter; Poettgen, Rainer [Institut fuer Anorganische und Analytische Chemie, Universitaet Muenster (Germany)

2017-08-03

The equiatomic intermetallic phases CaAgIn [a = 482.75(7), b = 750.0(1), c = 835.5(1) pm], SrAgIn [a = 495.86(5), b = 794.71(9), c = 851.89(9) pm], LaAgIn [a = 489.99(5), b = 767.93(9), c = 837.53(9) pm], and EuAgIn [a = 493.02(7), b = 781.6(1), c = 844.2(1) pm] were synthesized from the elements in sealed niobium containers. They crystallize with the EuAuGe type structure, space group Imm2. The four structures were refined from single-crystal X-ray data. The silver and indium atoms build up orthorhombically distorted, puckered Ag{sub 3}In{sub 3} hexagons, which are stacked in AA' sequence, leading to direct Ag-Ag and In-In interlayer bonding (e.g. 303 and 304 pm in CaAgIn). Temperature dependent magnetic susceptibility measurements show a magnetic moment of 7.40(1) μ{sub B} per europium atom. EuAgIn orders antiferromagnetically at 5.7(5) K. The divalent nature of europium is also evident from {sup 151}Eu Moessbauer spectra: δ = -10.50(1) mm.s{sup -1} at 78 K. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Correlation Theory Applied to the Static and Dynamic Properties of EuO and EuS

DEFF Research Database (Denmark)

Lindgård, Per-Anker

1982-01-01

was used previously in the correlation theory2) primarily to calculate static properties. Self‐consistent dynamic and static calculations have here been performed for EuO, which is an ideal Heisenberg magnet with significant second‐nearest‐neighbor interaction (J2 = J1/5). The two‐pole approximation...... a cutoff of the spectrum at high frequencies, which cannot be seen experimentally, but which significantly influences the frequency moments. It was found that the finite J2 has significant importance for a comparison between theory and experiment. It is concluded that the calculation for a simple cubic n.......n. magnet by Hubbard3) does not describe the EuO data accurately, neither with respect to line shape nor frequency scale. Significant differences are to be expected between EuO and EuS having opposite sign for J2....

Assessing EU perception in Kazakhstan's mass media

Directory of Open Access Journals (Sweden)

Bakyt Ospanova

2017-01-01

Our main findings suggest that Kazakhstan's mass media positively perceives the role of the EU in the region. Moreover, they tend to portray the EU mainly as an economic powerhouse. Our findings support some suggestions by similar studies of the EU's external perception.

Low temperature magnetic characterization of EuO1-x

Science.gov (United States)

Rimal, Gaurab; Tang, Jinke

EuO is a widely studied magnetic semiconductor. It is an ideal case of a Heisenberg ferromagnet as well as a model magnetic polaron system. The interesting aspect of this material is the existance of magnetic polarons in the low temperature region. We study the properties of oxygen deficient EuO prepared by pulsed laser deposition. Besides normal ferromagnetic transitions near 70K and 140K, we observe a different transition at 16K. We also observe a shift in the coercivity for field cooling versus zero field cooling. Possible mechanisms driving these behaviors will be discussed. This work was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering (DEFG02-10ER46728) and by the School of Energy Resources of the University of Wyoming.

EU, Eastern Europe and Values Imperialism

Directory of Open Access Journals (Sweden)

Stephen White

2014-01-01

Full Text Available This paper proposes an idea of'values imperialism'as a helpful way of conceptualising the relationship between the EU and the states that came within its sphere of influence after the end of the Cold War, particularly its 'neighbours' in Eastern Europe. Values imperialism places its emphasis on the 'superstructure', including norms, laws and social practices. EU larger objective was that the assumptions about government and ownership that were favoured by the dominant powers (EU and the West in the broad term should be absorbed and recapitulated by those countries that were subordinate. The broad framework ofsubordination was established by the Partnership and Cooperation Agreements that began to be concluded from 1994 onwards. Patterns of'values imperialism'could also be discovered in the EU Common Strategies on Russia and Ukraine that were adopted in 1999. Article also points out several cases when the EU intervened directly in the domestic affairs of the Eastern Europe countries in a manner that was not always compatible with the provisions on state sovereignty: a 'European Instrument for Democracy and Human Rights', launched in 2006, interventions ofEU representatives in the work of local courts and organisation of exit polls, which could be used to discredit the official election results and in this way to undermine the position of local governments. Finally, the author concludes that the EU used 'values imperialism'practices in order to extend its influence, particularly in the Eastern Europe.

Electronic Structure of Eu6C60

Institute of Scientific and Technical Information of China (English)

WANG Xiao-Xiong; LI Hong-Nian; XU Ya-Bo; WANG Peng; ZHANG Wen-Hua; XU Fa-Qiang

2009-01-01

We study the valence band of Eu-intercalated C60 by synchrotron radiation photoelectron spectroscopy to un-derstand the ferromagnetism (FM) and the giant magnetoresistance (GMR) of Eu6C60. The results reveal the semiconducting property and the remarkable 5d6s-π hybridization. Eu-C60 bonding has both ionic and covalent contributions. No more than half the 5d6s electrons transfer from Eu to the LUMO derived band of C60, and the LUMO+1 derived band is not filled. The remaining valence electrons of Eu, together with some π (LUMO, HOMO and HOMO-1) electrons, constitute the covalent bond. The electronic structure implies that the magnetic coupling in Eu6C60 should be through the intra-atomic f-sd exchange and the medium of the π electrons. The possibility of the GMR being tunnelling magnetoresistance is ruled out.

Mixed valence and metamagnetism in a metal flux grown compound Eu2Pt3Si5

International Nuclear Information System (INIS)

Sarkar, Sumanta; Subbarao, Udumula; Joseph, Boby; Peter, Sebastian C.

2015-01-01

A new compound Eu 2 Pt 3 Si 5 with plate shaped morphology has been grown from excess In flux. The compound crystallizes in the orthorhombic U 2 Co 3 Si 5 structure type, Ibam space group and the lattice parameters are a=10.007(2) Å, b=11.666(2) Å and c=6.0011(12) Å. The crystal structure of this compound can be conceived as inter-twinned chains of [Pt 2 Si 2 ] and [PtSi 3 ] tetrahedra connected along [100] direction to give rise to a complex three dimensional [Pt 3 Si 5 ] network. Temperature dependent magnetic susceptibility data suggests that Eu 2 Pt 3 Si 5 undergoes a strong antiferromagnetic ordering (T N =19 K) followed by a weak ferromagnetic transition (T C =5.5 K). The effective magnetic moment/Eu obtained from susceptibility data is 6.78 μ B accounts mixed valent Eu with almost 85% divalent Eu, which is supported by X-ray absorption near edge spectroscopy. The compound undergoes a metamagnetic transition under applied magnetic field through a probable spin flop mechanism. - Graphical abstract: Eu 2 Pt 3 Si 5 , a new member in the U 2 Co 3 Si 5 (Ibam) family undergoes metamagnetic transition at high magnetic field and Eu is in mixed valence state. - Highlights: • A new compound Eu 2 Pt 3 Si 5 has been synthesized using indium as an inactive metal flux. • The compound undergoes metamagnetic transition at higher field. • Eu in this compound resides in a mixed valence state

Europium(II)heptaphosphide EuP/sub 7/

Energy Technology Data Exchange (ETDEWEB)

von Schnering, H G; Wittmann, M

1980-07-01

The novel polyphosphide, EuP/sub 7/, was prepared under controlled conditions by reaction of the elements in salt melts at 750-800 K. EuP/sub 7/ forms black prismatic crystals not attacked by dilute mineral acids and bases. The thermal decomposition yields EuP/sub 3/ at 700 K and in further steps EuP/sub 2/, Eu/sub 3/P/sub 4/ and EuP, respectively. According to the crystal structure as well as the electrical, optical and magnetic properties, EuP/sub 7/ is a semiconductor (Esub(G) = 0.9 eV; Esub(G) (vert) = 1.1 eV) with divalent europium (..mu.. = 7.55 B.M.). The compound crystallizes in the monoclinic space group P 2/sub 1//n with a = 1148.8(7) pm, b = 570.0(3) pm, c = 1061.0(6) pm, and ..beta.. = 106.08/sup 0/(5); (X-ray diffraction data; 1479 hkl; R = 0.031). The P-atoms are connected ((P-P) = 218.0-223.5 pm) to a 2-dimensional infinite polyanionic structure 2sub(infinity)(P/sub 7//sup 2 -/) with homonuclear 3-bonded and 2-bonded P-atoms in the ratio 5 : 2. The polyanionic network contains P/sub 6/-rings (chair conformation) as well as P/sub 8/-rings and P/sub 10/-rings. The Eu-atoms are bonded to 9 P-atoms (1,4,4-polyhedra) with bond distances ranging from 306.6 to 326.6 pm. The Eu-atoms complete the tetrahedral environment of the P-atoms.

MTU engines for locomotives satisfying the EU stage IIIB emission standard; MTU-Lokomotivantriebe fuer die Emissionsstufe EU IIIB

Energy Technology Data Exchange (ETDEWEB)

Wintruff, Ingo; Reich, Christian; Geiselmann, Wolfgang; Gottschalch, Harald; Jansen, Eddy [MTU Friedrichshafen GmbH, Friedrichshafen (Germany)

2011-07-01

The emission limits for diesel locomotives inside the European Union are included within the scope of Directive 97/68/EC, which is sometimes referred to as the ''non-road directive''. The pollutants limited by it are NO{sub x}, particulates, CO and HCs. The aim, through the directive, is to reduce railway emissions by a factor of ten by the year 2020. The EU stage IIIB standard is due to take effect on 1 January 2012. This envisages a further drastic reduction in limit values compared with EU stage IIIA, which is applicable today. For diesel locomotives, EU stage IIIA only came into force as recently as 2009. The manufacturers of engines and locomotives are thus having to face up to the huge challenge of getting the technologies needed for EU stage IIIB ready for the production line within a period of only three years. MTU has succeeded in developing engines for diesel locomotives that comply with the EU stage IIIB emission standard, which appreciably lower emissions compared with engines satisfying EU stage IIIA, thanks to the incorporation of the most modern technologies available, and has even gone as far as preparing them for the EU stage IV, the next one to come into force. (orig.)

Photoswitchable Faraday effect in EuS-Au nanosystems

Energy Technology Data Exchange (ETDEWEB)

Kawashima, Akira; Nakanishi, Takayuki; Kitagawa, Yuichi; Fushimi, Koji; Hasegawa, Yasuchika [Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, North-13 West-8, Kita-ku, 060-8628, Sapporo (Japan)

2016-01-15

Effective photoswitchable europium sulfide nanocrystals with gold nanoparticles using dithiol (DDT: 1,10-decanedithiol) joint molecules, EuS-Au nanosystems, are demonstrated. The TEM image indicates the formation of EuS-Au nanosystems composed of cube-shaped EuS nanocrystals and spherical Au nanoparticles. Under visible-light irradiation, a drastic change of absorption band of EuS-Au nanosystems at around 600 nm was observed. The Faraday effects of EuS-Au nanosystems were estimated using magnetic circular dichroism (MCD) measurements. The effective change of the MCD spectra of EuS-Au nanosystems under visible-light irradiation was successfully observed at around 670 nm for the first time. The effective reversible changes in MCD spectra with the alternative irradiation cycles of visible light (>440 nm) and dark are also presented. The decrease rate of rotation angle at 670 nm of EuS-Au nanosystems is larger than that of absorbance. These results indicate that the effective change of MCD spectra of EuS-Au nanosystems would be dominated not only by a drastic change of absorption band related to enhanced LSPR of Au nanoparticles but also by specific interaction between EuS and Au in nanosystem under irradiation. Illustration of photoswitch and TEM image of EuS-Au nanosystems. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

The 'primacy' and 'direct effect' of EU international agreements

DEFF Research Database (Denmark)

Gáspár-Szilágyi, Szilárd

2015-01-01

The rules on invoking EU norms before the Court of Justice and Member State courts are at the core of EU constitutional law. International agreements binding on the EU form an integral part of EU law and have primacy over inconsistent secondary EU legislation. Moreover, they also have primacy over...

A long walk to obedience: Missiology and mission under scrutiny (1910-2010

Directory of Open Access Journals (Sweden)

Johannes J. Knoetze

2017-05-01

Full Text Available This article describes the discipline of missiology and mission over the last century since Edinburgh 1910 followed by two world wars to Edinburgh 2010, as a long walk to obedience – a walk in discerning God’s will. Even in biblical times, mission as spreading the gospel to those who do not yet believe in the Trinitarian God, was under scrutiny from within and outside the church (cf. Ac 10-11, 15 and Galatians. Throughout history until today it was never different. This article looks at the development of mission over the last 100 years from a Western (mainline missionary churches – MMCs perspective. The development of missiology as a subject and theological discipline will be described along the lines of some of the mission conferences. Attention will be given to the following questions: What does it mean to b eobedient to the mission calling in a broken and traumatised world? Is there a credible way of redeeming mission and missiology from its own past?

Adsorption of Sr(II) and Eu(III) on Na-rectorite. Effect of pH, ionic strength, concentration and modelling

Energy Technology Data Exchange (ETDEWEB)

Hu, J.; Wang, X.K. [School of Nuclear Science and Engineering, North China Electric Power Univ., BJ (China); Key Lab. of Novel Thin Film Solar Cells, Inst. of Plasma Physics, Chinese Academy of Sciences, Hefei (China); Chen, C.L.; Sheng, G.D.; Li, J.X. [Key Lab. of Novel Thin Film Solar Cells, Inst. of Plasma Physics, Chinese Academy of Sciences, Hefei (China); Chen, Y.X. [School of Nuclear Science and Engineering, North China Electric Power Univ., BJ (China)

2010-07-01

The surface charge characteristics of Na-rectorite (NaAl{sub 4}[Si,Al]{sub 8}O{sub 20}(OH){sub 4}.nH{sub 2}O;) were studied by potentiometric acid-base titrations. Sr(II) and Eu(III) adsorptions on Na-rectorite as a function of pH, ionic strength, and Sr(II)/Eu(III) concentrations were carried out to investigate the surface interactions between Sr(II)/Eu(III) with Na-rectorite. The results indicated that the adsorptions of Sr(II) and Eu(III) on Na-rectorite increased with increasing pH and decreased with increasing ionic strength and initial Sr(II)/Eu(III) concentrations, and that the affinity of Na-rectorite for Eu(III) was much higher than for Sr(II). The experimental data of Sr(II)/Eu(III) adsorption were simulated by the diffuse-layer model (DLM) well with the aid of FITEQL 3.2. Simultaneous adsorptions of Sr(II) and Eu(III) on Na-rectorite were also modeled using the DLM. The adsorption mechanisms of Sr(II) and Eu(III) on Na-rectorite may be dominated by ion exchange interaction at low pH or moderate pH, and by surface complexation interaction at high pH. (orig.)

BA DEMO R and D, activities on advanced tritium breeders in EU

Energy Technology Data Exchange (ETDEWEB)

Knitter, Regina; Kolb, Matthias H.H.; Leys, Oliver H.J.B. [Karlsruhe Institute of Technology (KIT), Eggenstein-Leopoldshafen (Germany). Inst. for Applied Materials (IAM-WPT)

2013-07-01

Within the Broader Approach (BA) activities on DEMO R and D, EU and Japan have launched a collaborative project on scalable and reliable production routes for advanced tritium breeders. Besides the development of the fabrication process, the reprocessing as well as the long-term stability of advanced breeder is to be investigated. In the EU, a modified melt-based process for the fabrication of lithium orthosilicate pebbles have been developed. Besides the optimization of process parameters, the chemical composition of the pebbles was altered by additions of titania in order to increase the mechanical properties by the formation of lithium metatitanate as a secondary, strengthening phase. (orig.)

A novel fluorescent probe (dtpa-bis(cytosine)) for detection of Eu(III) in rare earth metal ions

Science.gov (United States)

Yang, Fan; Ren, Peipei; Liu, Guanhong; Song, Youtao; Bu, Naishun; Wang, Jun

2018-03-01

In this paper, a novel fluorescent probe, dtpa-bis(cytosine), was designed and synthesized for detecting europium (Eu3 +) ion. Upon addition of Eu3 + ions into the dtpa-bis(cytosine) solution, the fluorescence intensity can strongly be enhanced. Conversely, adding other rare earth metal ions, such as Y3 +, Ce3 +, Pr3 +, Nd3 +, Sm3 +, Gd3 +, Tb3 +, Dy3 +, Ho3 +, Er3 +, Yb3 + and Lu3 +, into dtpa-bis(cytosine) solution, the fluorescence intensity is decreased slightly. Some parameters affecting the fluorescence intensity of dtpa-bis(cytosine) solution in the presence of Eu3 + ions were investigated, including solution pH value, Eu3 + ion concentration and interfering substances. The detection mechanism of Eu3 + ion using dtpa-bis(cytosine) as fluorescent probe was proposed. Under optimum conditions, the fluorescence emission intensities of EuIII-dtpa-bis(cytosine) at 375 nm in the concentration range of 0.50 × 10- 5 mol • L- 1-5.00 × 10- 5 mol • L- 1 of Eu3 + ion display a better linear relationship. The limit of detection (LOD) was determined as 8.65 × 10- 7 mol • L- 1 and the corresponding correlation coefficient (R2) of the linear equation is 0.9807. It is wished that the proposed method could be applied for sensitively and selectively detecting Eu3 + ion.

Linking project-based mechanisms with domestic greenhouse gas emissions trading schemes

International Nuclear Information System (INIS)

Bygrave, S.; Bosi, M.

2004-01-01

Although there are a number of possible links between emission trading and project-based mechanisms, the focus of this paper is on linking domestic GHG emission trading schemes with: (1) domestic; and, (2) international (JI and CDM) GHG reduction project activities. The objective is to examine some of the challenges in linking DETs and project-based mechanisms, as well as some possible solutions to address these challenges. The link between JI / CDM and intergovernmental international emissions trading (i.e. Article 17 of the Kyoto Protocol) is defined by the Kyoto Protocol, and therefore is not covered in this paper. The paper is written in the context of: (a) countries adhering to the Kyoto Protocol and elaborating their strategies to meet their GHG emission commitments, including through the use of the emissions trading and project-based mechanisms. For example, the European Union (EU) will be commencing a GHG Emissions Trading Scheme in January 2005, and recently, the Council of ministers and the European Parliament agreed on a text for an EU Linking Directive allowing the use of JI and CDM emission units in the EU Emission Trading Scheme (EU-ETS); and (b) all countries (and/or regions within countries) with GHG emission obligations that may choose to use domestic emissions trading and project-based mechanisms to meet their GHG commitments. The paper includes the following elements: (1) an overview of the different flexibility mechanisms (i.e. GHG emissions trading and PBMs), including a brief description and comparisons between the mechanisms (Section 3); (2) an exploration of the issues that emerge when project-based mechanisms link with domestic emissions trading schemes, as well as possible solutions to address some of the challenges raised (Section 4); (3) a case study examining the EU-ETS and the EU Linking Directive on project-based mechanisms, in particular on how the EU is addressing in a practical context relevant linking issues (Section 5); (4) a

A study of Eu incorporated ZnO thin films: An application of Al/ZnO:Eu/p-Si heterojunction diode

Energy Technology Data Exchange (ETDEWEB)

Turgut, G. [Department of Basic Sciences, Faculty of Science, Erzurum Technical University, Erzurum, 25240 (Turkey); Duman, S., E-mail: sduman@atauni.edu.tr [Department of Physics, Faculty of Science, Ataturk University, Erzurum, 25240 (Turkey); Sonmez, E. [Department of Physics, Faculty of K.K. Education, Ataturk University, Erzurum, 25240 (Turkey); Ozcelik, F.S. [Department of Physics, Faculty of Science, Ataturk University, Erzurum, 25240 (Turkey)

2016-04-15

Highlights: • Eu incorporated ZnO thin films were grown by sol–gel spin coating. • The influence of Eu contribution on features of ZnO was investigated. • Al/ZnO:Eu/p-Si heterojunction diodes were also fabricated. • The diode parameters were calculated from I–V measurements. - Abstract: In present work, the pure and europium (Eu) incorporated zinc oxide (ZnO) thin films were deposited with sol-gel spin coating by using zinc acetate dehydrate and Eu (III) chloride salts. The coated films were examined by means of XRD, AFM and UV/VIS spectrophotometer. The ZnO hexagonal wurtzite nanoparticles with (002) preferential direction were observed for all films. The values of crystallite size, micro-strain and surface roughness continuously increased from 21 nm, 1.10 × 10{sup −3} and 2.43 nm to the values of 35.56 nm, 1.98 × 10{sup −3} and 28.99 nm with Eu doping, respectively. The optical band gap value of the pure ZnO initially increased from 3.296 eV to 3.328 eV with Eu doping up to 2 at.% doping level, then it started to decrease with more Eu content. The electrical features of Al/n-ZnO:Eu/p-Si heterojunction diodes were inquired by current-voltage (I–V) measurements at the room temperature.

Ex-ante evaluation of EU ETS during 2013–2030: EU-internal abatement

International Nuclear Information System (INIS)

Hu, Jing; Crijns-Graus, Wina; Lam, Long; Gilbert, Alyssa

2015-01-01

This study investigates CO 2 emission reduction within the EU resulting from the Emissions Trading Scheme (ETS) up to 2030. This is performed by constructing a baseline scenario without the ETS and assessing the impacts of the ETS, as currently designed. The results indicate that the ETS will start to impact emissions primarily after 2025 due to the prevalence of a sizable allowance surplus. The impact of approved (i.e. back-loading and 2.2% linear reduction factor (LRF)) and proposed (i.e. market stability reserve (MSR)) policy interventions and the inclusion of aviation, could accelerate the exhaustion of surplus and increase emission reductions during the investigated period. However, these measures would be insufficient to restore the scarcity of allowances and the corresponding carbon price before the start of ETS Phase IV, and the effectiveness of EU-internal abatement cannot be guaranteed until 2023. The effectiveness could be further reduced in the case of the economic shocks or the exclusion of international aviation. To restore the scarcity of allowances, other reform options are necessary. This paper extends the reasoning for the early removal of the back-loaded 900 Mtonne allowances by 2020 and broadening the scope of ETS to other sectors with potential high demand for allowances. - Highlights: • Quantification of CO 2 emission abatement in the EU resulting from the ETS up to 2030. • The impact of policy interventions and the inclusion of aviation is quantified. • The effectiveness of EU ETS in EU-internal abatement is limited until 2023

EU trade in the time of financial crisis

Directory of Open Access Journals (Sweden)

Fojtíková, L.

2010-12-01

Full Text Available The paper is focused on the European Union (EU trade and trade policy in the time of global financial and economic crisis. The analysis of the EU exports and imports points out that the financial crisis has had a negative impact on the intra as well as on the extra-EU trade in the period 2007-2009, but differences among the EU member states have existed. Although the EU tries to support trade development in the world and remove barriers to trade, some protectionist tendencies were recorded in the time of the economic crisis. The last part of the paper gives emphasis to the EU trade policy and some trade measures which have been taken in the EU and its member states to support trade development or vice versa, to protect domestic industries. The results of the analysis show that, although some protectionist tendencies have been recorded both in extra and intra-EU trade, trade relations which are provided among member states are of significant importance all the time.

EU import restrictions on genetically modified feeds: impacts on Spanish, EU and global livestock sectors

Energy Technology Data Exchange (ETDEWEB)

Philippidis, G.

2010-07-01

Over the last decade, much controversy has surrounded the usage of genetically modified organism (GMO) technology in commercial agriculture. More specifically, it is feared that GMOs may introduce new allergens into the food chain or contribute to antibiotic resistance. At the current time, the European Union (EU) adopts a zero tolerance policy toward non-approved GMO imports, whilst the approval process has not kept pace with the proliferation of new GMO varieties. In the EU livestock sectors, this apparent mis-match threatens to interrupt supplies of high protein feed inputs (e.g., soy meal) from countries with more relaxed regulations regarding GMOs. Employing a well known multi-region computable general equilibrium framework, this study quantitatively assesses the impact of a hypothetical EU import ban on unapproved GMO varieties of soybean and maize imports on livestock, meat and dairy sectors. The model code is heavily modified to improve the characterisation of the agricultural sectors and land usage, whilst a realistic baseline is employed to update the global database to 2008, the year the hypothetical ban is implemented. In the worst case scenario, there are significant competitive losses in EU livestock, meat and dairy sectors. In Spain, the negative impacts are particularly pronounced given the importance of pig production in agriculture. In contrast, all non-EU regions trade balances improve, with notable trade gains in the USA and Brazil. To conclude, the EU must urgently find a long term strategy for GMOs if it is to reconcile political expediency with pragmatic economic concerns. (Author) 21 refs.

EU's tiltræden til EMRK - et sisyfosarbejde?

DEFF Research Database (Denmark)

Bang Fuglsang Madsen Sørensen, Henning

2015-01-01

EU-Domstolen afviste med opinion 2/13 den 18. december 2014 at lade EU tiltræde EMRK på grundlag af et udkast til en tiltrædelsesaftale. I artiklen behandles baggrunden for og det konkrete indhold i EU-Domstolens afvisning, hvorefter det undersøges, i hvilket omfang EMD fremover kan forventes...... at respektere EU-rettens forrang og dermed undlade at holde medlemsstaterne ansvarlige for påståede krænkelser som følge af medlemsstaternes forpligtelser efter EU-retten....

GENERAL OVERWIEV ON EU ECONOMY

Directory of Open Access Journals (Sweden)

NICOLETA GEORGETA PANAIT

2013-05-01

Full Text Available The impact of the international economic crisis on new EU member states has proven to be more severe than the first estimates of the economic analysts. The situation is different for each Member State, the nature and the dimension of the challenges faced are not identical, and the pace of reform is not the same. The economic crisis has prompted intense and sustained action by the EU's national governments, the European Central Bank and the Commission. All have been working closely together to support growth and employment, ensure financial stability, and put in place a better governance system for the future. Sustainable development in the future is the common responsibility of all Member States and EU institutions, because our economies are closely interlinked, and the EU economic governance now reconfigured to provide more effective responses at the policy level, to give a good reaction to the present and the future challenges.

EuCARD final project report

CERN Document Server

Koutchouk, J P

2014-01-01

After four years of activity, EuCARD has most of its objectives fulfilled, with some new objectives added and a few others on excellent tracks while requiring additional time. The management has been active in reinforcing the collaborative links between partners and projects, contributing to the preparation of FP7-EuCARD2, initiating FP7-HiLumi-LHC Design Study, to favour sustained collaborations beyond EuCARD. An out-of-contract network has been successfully launched on laser plasma acceleration, to combine forces between accelerator, laser and plasma communities. Communication and dissemination activities have led to two highlights: Accelerating News, an accelerator R&D newsletter initiated by EuCARD and now common to all FP7 accelerator projects (over 1000 subscribers) and a series of monographs on accelerator sciences that is progressively finding its public. The scientific networks have more than fulfilled their initial objectives: roadmaps are defined for neutrino facilities, submitted to the Europe...

EU Nuclear vs. Fukushima

International Nuclear Information System (INIS)

Poncelet, Jean-Pol

2011-01-01

Conclusions: • The Fukushima-Daiichi accident represents an opportunity for the nuclear industry to demonstrate its ability to learn from experience through “a continuous improvement strategy”; • Inside the EU: which legal framework for nuclear safety - harmonisation of licensing procedures - EU-level reactor design clearance?; • No way forward without public support: how to address, explain, convince?; • Greater cooperation between industry and international organizations: FORATOM available to contribute

The EU's Normative Power in Changing World Politics

DEFF Research Database (Denmark)

Manners, Ian

2009-01-01

global order: 1) what is the concept of normative power in world politics?; 2) what is an effective EU toolbox for tackling new challenges?; 3) how does the EU go beyond self-perception and rhetoric?; 4) what is the raison d'etre of the EU?; and 5) how might normative power in EU external policies lead...

Calling the EU's bluff. Who are the real champions of biodiversity and traditional knowledge in the EU-Central American and EU-Community of Andean Nations Association Agreements?

International Nuclear Information System (INIS)

Hall, R.

2009-12-01

Global Europe and the EU's Raw Materials Initiative are designed to bolster the EU's economic position - whatever the cost - in the face of fierce global competition for both markets and resources, especially from emerging economies such as China and India. The EU also fears losing trade to the US, which has already secured trade and investment concessions from countries in the Western hemisphere, through the Dominican Republic-Central American Free Trade Agreement (DR-CAFTA) and other bilateral trade agreements.

Defect analysis of BaSrFBr:Eu irradiated by X-ray

International Nuclear Information System (INIS)

Lee, C. Y.; Jeong, J. M.; Kim, J. H.

2010-01-01

The mechanical property of the BaSrFBr:Eu phosphor layer of X-ray image plates was investigated by using image quality (IQ), resolution (LP/mm), and coincidence Doppler broadening (CDB) positron annihilation. The screen samples of BaSrFBr:Eu phosphors were irradiated with hospital X-rays in the course of diagnostic radiography at an average rate of 20,000 times per year and were used for various periods of time. The LP/mm values of the irradiated BaSrFBr:Eu image plates varied between 2.4 and 2.0 for three years while the IQ values varied between 35 and 11 over the same period. CDB positron annihilation spectroscopy was used to analyze the defect structures in the phosphor layer. The S parameter values increased in correlation with increased exposure time, which indicated that more defects were generated. There was a positive relationship between the IQ and S parameters. Measurements of the defects indicate that most of the defects were likely to have been generated by the X-ray radiation.

Effect of Eu magnetism on the electronic properties of the candidate Dirac material EuMnBi2

Science.gov (United States)

May, Andrew F.; McGuire, Michael A.; Sales, Brian C.

2014-08-01

The crystal structure and physical properties of the layered material EuMnBi2 have been characterized by measurements on single crystals. EuMnBi2 is isostructural with the Dirac material SrMnBi2 based on single-crystal x-ray diffraction, crystallizing in the I4/mmm space group (No. 139). Magnetic susceptibility measurements suggest antiferromagnetic (AFM) ordering of moments on divalent Eu ions near TN=22 K. For low fields, the ordered Eu moments are aligned along the c axis, and a spin flop is observed near 5.4 T at 5 K. The moment is not saturated in an applied field of 13 T at 5 K, which is uncommon for compounds containing Eu2+. The magnetic behavior suggests an anisotropy enhancement via interaction between Eu and the Mn moments that appear to be ordered antiferromagnetically below ≈310 K. A large increase in the magnetoresistance is observed across the spin flop, with absolute magnetoresistance reaching ≈650% at 5 K and 12 T. Hall effect measurements reveal a decrease in the carrier density below TN, which implies a manipulation of the Fermi surface by magnetism on the sites surrounding the Bi square nets that lead to Dirac cones in this family of materials.

Synchrotron radiation studies on luminescence of Eu2+-doped LaCl3 microcrystals embedded in a NaCl matrix

International Nuclear Information System (INIS)

Savchyn, P.V.; Vistovskyy, V.V.; Pushak, A.S.; Voloshinovskii, A.S.; Gektin, A.V.; Pankratov, V.; Popov, A.I.

2012-01-01

LaCl 3 :Eu 2+ microcrystals dispersed in the NaCl matrix have been obtained in the NaCl–LaCl 3 (1 mol.%)–EuCl 3 (0.1 mol.%) crystalline system. The low-temperature luminescent properties of these microcrystals have been studied upon the VUV and UV excitation by the synchrotron radiation. The spectroscopic parameters as well as decay time constants of Eu 2+ -doped LaCl 3 host have been established. The excitation mechanism of divalent europium centers through energy transfer and reabsorption is discussed.

Enhanced flexibility in the EU's 2030 effort sharing agreement: issues and options - Final report

International Nuclear Information System (INIS)

Sartor, Oliver; Bart, Istvan; Cochran, Ian; Tuerk, Andreas

2015-04-01

The sectors which are not covered by the European carbon market account for around 60% of the EU's GHG emissions. The European Council has set a target to reduce emissions in these sectors by -30% vs. 2005 levels by 2030. Given the way this target is allocated, there is a risk that EU Member States may fail to achieve their national goals by reducing abatement domestically, while others will undertake too little abatement and avoid needing to begin a low-carbon transition in these sectors. This paper therefore proposes a new design for a European financing mechanism to catalyse action in low-income Member States while ensuring that all Member States comply with the EU targets. (authors)

Blue emission in photoluminescence spectra of the red phosphor CaAlSiN3:Eu2+ at low Eu2+ concentration

Science.gov (United States)

Suda, Yoriko; Kamigaki, Yoshiaki; Yamamoto, Hajime

2018-04-01

In red phosphor CaAlSiN3:Eu2+, unintentional blue emission occurs with increasing intensity at low Eu2+ concentrations and also at low measurement temperatures. Time-resolved photoluminescence measurements were used to confirm the decrease in red emission and increase in blue emission with the decreasing Eu2+ concentration. The peak timing of blue emission occurred faster than that of red emission, and long lasting luminescence of red emission was observed as well as that of blue emission. The Eu2+ concentration dependences of the red and blue emissions were similar to those of the g values 4.75 (Eu2+) and 2.0025 (nitrogen vacancies), respectively, which were observed from electron spin resonance (ESR) measurements. The origin of the blue emission is proposed to be nitrogen vacancy defects, which had about the same ESR signal intensity as that of Eu2+ ions in CaAlSiN3:Eu2+ containing 0.01 at. % Eu2+. The possibility of red emission also arising from excited electron tunneling or thermal pathways via nitrogen vacancies is discussed. Long lasting red emission was observed, which is proposed to involve trapped electrons remaining at nitrogen vacancies, yielding blue emission and inducing red emission from Eu2+ ions.

Fighting windmills? EU industrial interest and global climate negotiations

International Nuclear Information System (INIS)

Steiner Brand, U.; Tinggaard Svendsen, G.

2003-01-01

Why has the EU been so eager to continue the climate negotiations? Can it be solely attributed to the EU feeling morally obliged to be the main initiator of continued progress on the climate change negotiations, or can industrial interests in the EU, at least partly, explain the behaviour of the EU? We suggest that the EU has a rational economic interest in forcing the technological development of renewable energy sources to get a fast-mover advantage, which will only pay if a sufficient number of countries implement sufficiently stringent GHG reductions. The Kyoto Protocol, which imposes binding reductions on 38 OECD countries, implies that, as a first-mover, the EU will be to sell the necessary new renewable technologies, most prominently wind mills, to other countries, when they ratify and implement the Kyoto target levels. In the latest EU proposal made in Johannesburg, the EU pushed for setting a target of 15% of all energy to come from sources such as windmills, solar panels and waves by 2015. Such a target would further the EU's interests globally, and could explain, in economic terms, why the EU eagerly promotes GHG trade at a global level whereas the US has left the Kyoto agreement to save the import costs of buying the EU's renewable systems. (au)

The EU and Climate Change Policy: Law, Politics and Prominence at Different Levels

Directory of Open Access Journals (Sweden)

Chad David Damro

2008-11-01

Full Text Available The European Union (EU is a prominent player in the politics of climate change, operating as an authoritative regional actor that influences policy-making at the national and international levels. The EU’s climate change policies are thus subjected to multiple pressures that arise from the domestic politics of its twenty-seven individual member states and the international politics of non-EU states with which it negotiates. Facing these multiple pressures, how and why could such a non-traditional actor develop into a prominent player at different levels of climate change policy-making? This article argues that the EU’s rise to prominence can be understood by tracking a number of historical-legal institutional developments at the domestic and international levels. The article also provides a preliminary investigation of the EU emissions trading scheme, a new institutional mechanism that illustrates the policy pressures arising from different levels.

Contract theory and EU Contract Law

OpenAIRE

Hesselink, M.W.; Twigg-Flesner, C.

2016-01-01

This paper explores the relationship between contract theory and European contract law. In particular, it confronts the leading contract law theories with the main characteristics of EU contract law. The conclusion is that the two do not match well. In particular, monist normative contract theories are largely irreconcilable with the contract law of the EU. The paper further addresses the main implications of this mismatch, both for contract theory and for EU contract law. It suggests that in...

AU-EU “Strategic Partnership”

DEFF Research Database (Denmark)

Rodt, Annemarie Peen; Okeke, Jide

2013-01-01

This article appraises strategic partnership between the African Union (AU) and European Union (EU). It examines the context and nature of AU and EU security relations and explores the conditions under which partnership has a positive impact in this regard. This includes an evaluation...... of convergence between the two organizations and its effect or lack thereof on African security. The article concludes that events leading up to and initiatives following the 2007 Joint Africa–European Union Strategy have produced a degree of AU and EU convergence, which has had limited impact on the efficacy...... of the African security regime, the level of which remains mediocre at best....

Budgetary cash flows in the EU and their impact on national budget liquidity: the case of Slovenia

Directory of Open Access Journals (Sweden)

Tanja Markovič Hribernik

2005-12-01

Full Text Available On May 1, 2004 ten new states joined the EU. At the same time, budgetary cash flow mechanisms between the EU budget (as the central subject and national budgets were established. Despite the fact that all the rules are clear and known in advance - stipulated by the EU directives and regulations - there are some uncertainties, which may have an important effect on the liquidity as well as on the budgetary cash flows in new member states. The greatest problem for the liquidity of new member states’ budgets is posed by the time lags between inflows and outflows of EU funds. These lags are mainly because of delayed payments from the EU budget and problems with some member state’s absorption capacity. This article deals with the dynamics and the scale of budgetary cash flows between the Slovenian budget and the EU budget until 2006. A couple of likely scenarios are presented, which could happen in case of delayed payments of European funds. Consequently, both an unexpected state budget liquidity deficit and an additional burden arising from interest on delayed payments to the Brussels are possible for Slovenia.

EU

DEFF Research Database (Denmark)

Abrahamson, Peter; Borchorst, Anette

2002-01-01

Der er et komplekst forhold mellem EU og den danske velfærdsstat. Den sociale dimension i det europæiske samarbejde er splittet mellem et pres mod harmonisering og pres for at fastholde national suverænitet. Negativ integration har været den foretrukne interventionsform. Drivkræfterne har især...

Modelling Eu(III) speciation in a Eu(III)/PAHA/α-Al2O3 ternary system

International Nuclear Information System (INIS)

Janot, Noemie; Reiller, Pascal E.; Benedetti, Marc F.

2013-01-01

In this work, modelling of Eu(III) speciation in a ternary system, i.e., in presence of purified Aldrich humic acid (PAHA) and α-Al 2 O 3 , is presented. First, the mineral surface charge is measured by potentiometric titrations and then described using the CD-MUSIC model. This model is also used to describe Eu(III) binding to the α-Al 2 O 3 surface at different pH values, ionic strength and mineral concentrations. Time resolved luminescence spectroscopy (TRLS) is then used to study the binding of Eu(III) to PAHA at pH 4 with different humic acid concentrations. The spectra are used to calculate a spectroscopic 'titration curve', used to determine Eu(III)/PAHA binding parameters in the NICA-Donnan model. Following a previous study (Janot et al., Water Res. 46, 731-740), modelling of the ternary system is based upon the definition of two PAHA pools where one fraction remains in solution and the other is adsorbed onto the mineral surface, with each possessing different proton and metal binding parameters. The modification of protonation behaviour for both fractions is examined using spectrophotometric titrations of the non adsorbed PAHA fraction at different organic/mineral ratios. These data are then used to describe Eu(III) interactions in the ternary system: Eu(III) re-partitioning in the ternary system is calculated for different pH, ionic strength and PAHA concentrations, and results are compared to experimental observations. The model is in good agreement with experimental data, except at high PAHA fractionation rates. Results show that organic complexation dominates over a large pH range, with the predominant species existing as the surface-bound fraction. Above pH 8, Eu(III) seems to be mostly complexed to the mineral surface, which is in agreement with previous spectroscopic observations (Janot et al., Environ. Sci. Technol. 45, 3224-3230). (authors)

EU Agro Biogas Project

OpenAIRE

Amon, T.; Mayr, H.; Eder, M.; Hobbs, P.; Rao Ravella, S.; Roth, U.; Niebaum, A.; Doehler, H.; Weiland, P.; Abdoun, E.; Moser, A.; Lyson, M.; Heiermann, M.; Plöchl, M.; Budde, J.

2009-01-01

EU-AGRO-BIOGAS is a European Biogas initiative to improve the yield of agricultural biogas plants in Europe, to optimise biogas technology and processes and to improve the efficiency in all parts of the production chain from feedstock to biogas utilisation. Leading European research institutions and universities are cooperating with key industry partners in order to work towards sustainable biogas production in Europe. Fourteen partners from eight European countries are involved in the EU-AGR...

Succession of States in the EU

Directory of Open Access Journals (Sweden)

Mario Martini

2014-09-01

Full Text Available A specter is haunting Europe – the specter of separatism. Scotland, Catalonia, Flanders, South Tyrol – all these regions have separatist movements pursuing independence from their current National State. The breakup of an EU Member State no longer seems impossible. To date, it is unclear what impact this would have on the EU membership of the new entities (with consequences for the character of citizenship, voting rights in the council, number of MEPs etc. that emerge from the old States. The common rules of Public International Law governing the succession of States are insufficient in the case of a succession of States in the EU. Although the Treaties do not provide for such a situation and the past 60 years of European history offer only a few and not really persuasive precedents, the nature of the EU as a joint association of sovereign States (“Staatenverbund” demands a special approach: A separated State will neither be automatically excluded from the EU nor will it automatically become a new Member State.

Europe, the EU and its 2050 Energy Storylines

International Nuclear Information System (INIS)

De Jong, J.; Weeda, E.

2007-12-01

This paper seeks to explore some of the conditions under which energy policy could be formulated in and by the European Union (EU) over the next 40 years. The development of energy policy at the EU level is addressed from a wider historical perspective, taking into account a number of factors that influence both the EU project and its energy supply security. These factors include the EU's international orientation and cooperation; the EU 'economic community of law' paradigm; the EU's (failing?) external leadership role; the impact of the fall of the Berlin Wall; and Europe's talents for creativity and improvisation. These factors are discussed in somewhat greater depth in the context of the formulation of an all-EU energy policy. The global energy policy environment is briefly discussed, indicating that energy resources for the world are less at stake than their access. On this basis, a closer look is taken at the theoretical and practical aspects of using scenarios as a tool for energy policy-making. A few examples are presented, and it is argued that scenarios should basically be addressed on the basis of storylines. Storylines do require a set of specific parameters, and in this case the choice was made to use the various roles played by stakeholders for intervening in markets and in the world order. This choice is argued on the basis of the global interrelations that are currently influencing resource policies in general and energy in particular. Market efficiency, climate change, poverty issues, geopolitics and global coordination mechanisms are considered, leading to the two policy dimensions of 'nationalism' versus 'globalism' and 'heavy' versus 'light' government as the axes for the scenarios and storylines. This paper develops four storylines that are conceivable and inherently consistent. They are labelled with names that refer not only to their content, but also to the political and societal climate prevailing in the region. The first, 'l'Europe des

The EU electricity production structure requires a differentiated energy policy; Die Stromerzeugungsstruktur der EU erfordert eine differenzierte Energiepolitik

Energy Technology Data Exchange (ETDEWEB)

Anon.

2016-04-15

For the electricity production of the EU there are differentiated structures which are based on different natural conditions, political decisions and investments of past decades. It has long been struggled committed to the ''one and correct'' energy policy. But precisely because of the differences in the individual countries, a unified energy and climate policy for the EU is not the right way. Diversity is a strength, which quite the EU Commission considered. Increased understanding of the specifics in other countries should just apply the German politics and the public that all too often judges from their own perspective. [German] Bei der Stromerzeugung in der EU bestehen differenzierte Strukturen, die auf unterschiedlichen natuerlichen Gegebenheiten, politischen Entscheidungen und Investitionen vergangener Jahrzehnte beruhen. Seit langem wird engagiert um die ''eine und richtige'' Energiepolitik gerungen. Doch gerade wegen der Unterschiede in den einzelnen Laendern kann eine vereinheitlichte Energie- und Klimapolitik fuer die EU nicht der richtige Weg sein. Vielfalt ist eine Staerke, was die EU-Kommission durchaus beruecksichtigt. Mehr Verstaendnis fuer die Spezifika in anderen Laendern sollte daher gerade die deutsche Politik und Oeffentlichkeit aufbringen, die allzu oft aus eigener Perspektive heraus urteilt.

The evolution of emissions trading in the EU. Tensions between national trading schemes and the proposed EU directive

International Nuclear Information System (INIS)

Boemare, Catherine; Quirion, Philippe; Sorrell, Steve

2003-12-01

The EU is pioneering the development of greenhouse gas emissions trading, but there is a tension between the 'top-down' and 'bottom-up' evolution of trading schemes. While the Commission is introducing a European emissions trading scheme (EU ETS) in 2005, several member states have already introduced negotiated agreements that include trading arrangements. Typically, these national schemes have a wider scope than the proposed EU directive and allow firms to use relative rather than absolute targets. The coexistence of 'top-down' and 'bottom-up' trading schemes may create some complex problems of policy interaction. This paper explores the potential interactions between the EU ETS and the negotiated agreements in France and UK and uses these to illustrate some important generic issues. The paper first describes the proposed EU directive, outlines the UK and French policies and compares their main features to the EU ETS. It then discusses how the national and European policies may interact in practice. Four issues are highlighted, namely, double regulation, double counting of emission reductions, equivalence of effort and linking trading schemes. The paper concludes with some recommendations for the future development of UK and French climate policy

EU Law Autonomy Versus European Fundamental Rights Protection

DEFF Research Database (Denmark)

Storgaard, Louise Halleskov

2015-01-01

In the recently issued Opinion 2/13, the EU Court of Justice ruled that EU accession to the European Convention on Human Rights on the basis of the current Draft Accession Agreement would be incompatible with the EU Treaties. This article examines the impact of Opinion 2/13 on European fundamental...... rights protection. It argues that the concerns for EU law autonomy expressed in the Opinion for the most part are unwarranted and that the Court, through the use of classic constitutionalist language, seeks to position EU law as the superior European fundamental rights regime. The article furthermore...

Understanding the DNA of EU's GDPR

OpenAIRE

Editorial Team, IndraStra Global

2018-01-01

On May 25, 2018, a new data protection regulation touted as General Data Protection Regulation (GDPR), Regulation (European Union - EU) 2016/689, will come into force in the European Union (EU) and its 28 Member States. It will replace the 1995 EU Data Protection Directive 95/46/EC. The GDPR will have a significant impact in protecting the data and digital footprint of users of apps and another digital platform. It will provide significant new data privacy protections for individuals res...

Electronic transport through EuO spin-filter tunnel junctions

KAUST Repository

Jutong, Nuttachai

2012-11-12

Epitaxial spin-filter tunnel junctions based on the ferromagnetic semiconductor europium monoxide (EuO) are investigated by means of density functional theory. In particular, we focus on the spin transport properties of Cu(100)/EuO(100)/Cu(100) junctions. The dependence of the transmission coefficient and the current-voltage curves on the interface spacing and EuO thickness is explained in terms of the EuO density of states and the complex band structure. Furthermore, we also discuss the relation between the spin transport properties and the Cu-EuO interface geometry. The level alignment of the junction is sensitively affected by the interface spacing, since this determines the charge transfer between EuO and the Cu electrodes. Our calculations indicate that EuO epitaxially grown on Cu can act as a perfect spin filter, with a spin polarization of the current close to 100%, and with both the Eu-5d conduction-band and the Eu-4f valence-band states contributing to the coherent transport. For epitaxial EuO on Cu, a symmetry filtering is observed, with the Δ1 states dominating the transmission. This leads to a transport gap larger than the fundamental EuO band gap. Importantly, the high spin polarization of the current is preserved up to large bias voltages.

PSEUDO-SCIENTIFIC ECONOMIC POLICIES OF MOLDOVA ASSOCIATION TO THE EU: METHODOLOGY, PROBLEMS, SOLUTIONS

Directory of Open Access Journals (Sweden)

Gheorghe RUSU

2016-01-01

reliable data on economic processes’ trends as well as macroeconomic prognoses for designing a set of development scenarios. Results were reflected in elaboration of a system of actions which includes EU as a monitoring mechanism for preventing and anticipating the disequilibrium that may occur during the association process. Stimulation of consumption, of the research and technological progress and targeting foreign investments in the innovation development priorities are some of other actions that are recommended in the article.

A Novel Orange-Red Emitting ZnB4O7:Eu3+ Phosphor with Urchin-Like Nanostructure

Directory of Open Access Journals (Sweden)

Hom Nath Luitel

2015-01-01

Full Text Available A novel phosphor, ZnB4O7:Eu3+, with urchin-like structure consisting of radially arranged high density nanorods was successfully synthesized by hydrothermal process at 150°C for 24 h. The nanorods were measured from 200 to 400 nm in diameter and several µm in length. The urchins were few µm to 40 µm in diameter. The ZnB4O7:Eu3+ phosphors were efficiently excited by ultraviolet (UV ~ 254 nm to visible light of ~ 220 to 450 nm and exhibited intense orange-red emission consisting of main peaks at 590, 615, and 695 nm due to the charge transfer in the host and f→f transitions (5D0 to 7F1,2,4 of the Eu3+ ions. Effect of the Eu3+ ions concentration on the photoluminescence (PL emission intensity was investigated and it was found that 5 at% Eu3+ is the optimum concentration. Meanwhile, the concentration quenching mechanism was discussed. The key parameters, such as temperature dependent PL and CIE values of ZnB4O7:Eu3+ phosphors, were studied. The ZnB4O7:Eu3+ phosphor exhibited good thermal stability and better absorption cross section compared to the commercial Y2O2S:Eu3+ phosphor. All these characteristics indicate that the phosphor will be a potential candidate for the UV based white LEDs.

Correlation theory applied to the static and dynamic properties of EuO and EuS

International Nuclear Information System (INIS)

Lindgard, P.A.

1981-10-01

The paramagnetic scattering was recently measured for EuO. It was found that spin-wave-like excitations develop for wave vectors approaching the zone boundary. The spectrum was found to be well described by damped harmonic oscillators (also called the two-pole-approximation). This approximation was used previously in the correlation theory primarily to calculate static properties. Selfconsistent dynamic and static calculations have been performed for EuO, which is an ideal Heisenberg magnet with significant second nearest neighbor interaction (J 2 = J/sub 1/5). The two-pole approximation describes accurately the correlation range, the static susceptibility and the qualitative behavior of the dynamic properties (i.e., the wave vector at which peaks appear in the spectrum as a function of temperature). However, in order to also obtain the correct frequency scale it is necessary to use a cut-off of the spectrum at high frequencies, which cannot be seen experimentally, but which significantly influences the frequency moments. It was found that the finite J 2 has significant importance for a comparison between theory and experiment. It is concluded that the calculation for a simple cubic n.n. magnet by Hubbard does not describe the EuO data accurately, neither with respect to lineshape nor frequency scale. Significant differences are to be expected between EuO and EuS having opposite sign for J 2

Facile synthesis of Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts mat with the enhanced fluorescence and mechanical performance

Energy Technology Data Exchange (ETDEWEB)

Zhao, Hailei; Cui, Bo [State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620 (China); Wang, Hongzhi, E-mail: wanghz@dhu.edu.cn [State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620 (China); Zhang, Qinghong [Engineering Research Center of Advanced Glasses Manufacturing Technology, MOE, College of Materials Science and Engineering, Donghua University, Shanghai 201620 (China); Li, Yaogang, E-mail: yaogang_li@dhu.edu.cn [Engineering Research Center of Advanced Glasses Manufacturing Technology, MOE, College of Materials Science and Engineering, Donghua University, Shanghai 201620 (China)

2016-01-15

Yellow-emitting phosphor mat consisting of Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts was prepared by electrospinning and subsequent nitridation. The as-prepared fiber precursor is smooth and uniform with diameter of 800 to 900 nm. After removing organic templates and nitridation, the morphology of the fiber is well retained and thus a smooth microbelts phosphor mat was obtained. X-ray diffraction and the photoluminescence (PL) spectra reveals that a relatively pure Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16} phase and the highest spectral intensity could be obtained at a relatively low temperature of 1500 °C and Eu{sup 2+} doping molar concentration of 0.1. The excitation spectra exhibits a broad band, ranging from 300 to 550 nm, which could be excited by blue LED chip at room temperature. The emission spectra of all exhibits a single broad band in the 400 to 700 nm region, with the maximum intensity always being at 580 nm. The Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts phosphor mat has the bending strength about 4.5 MPa with a photoluminescence quantum yield as high as 65%. By employing it as yellow phosphor, a high-performance warm white LED could be fabricated with low correlated color temperature (2985 K), high-color-rendering index (Ra=86) and luminous efficacy of 129.5 lm W{sup −1}. Different color temperatures also could be tuned by employing microbelts phosphor mats with different thicknesses. - Graphical abstract: Yellow-emitting phosphor mat consisting of Ca{sub 0.68}Si{sub 9}Al{sub 3}(ON){sub 16}:Eu{sup 2+} microbelts fibers were prepared by electrospinning the fiber precursor and subsequent nitridation. Because the good mechanical strength it could be utilized to realize LEDs remote packaging. By employing it as yellow phosphor, a high-performance warm white LED could be fabricated. Different color temperatures also could be tuned by employing microbelts phosphor mats with different thicknesses

Doorkeepers and Gatecrashers: EU Enlargement and Negotiation Strategies

DEFF Research Database (Denmark)

Brücker, Herbert; Schröder, Philipp; Weise, Christian

2004-01-01

This paper discusses the eastward enlargement process of the EU in the framework of a simple war of attrition bargaining game. Both players -- the existing EU members and the applicants -- benefit from enlargement, yet for the applicants, reform to the acquis is costly, while the EU prefers subst...... the benefits for new members are all effective negotiation strategies for the EU that have been applied in the process....

Eu3+/Tb3+-doped La2O2CO3/La2O3 nano/microcrystals with multiform morphologies: facile synthesis, growth mechanism, and luminescence properties.

Science.gov (United States)

Li, Guogang; Peng, Chong; Zhang, Cuimiao; Xu, Zhenhe; Shang, Mengmeng; Yang, Dongmei; Kang, Xiaojiao; Wang, Wenxin; Li, Chunxia; Cheng, Ziyong; Lin, Jun

2010-11-15

LaCO(3)OH nano/microcrystals with a variety of morphologies/sizes including nanoflakes, microflowers, nano/microrhombuses, two-double microhexagrams sandwichlike microspindles, and peach-nucleus-shaped microcrystals have been synthesized via a facile homogeneous precipitation route under mild conditions. A series of controlled experiments indicate that the pH values in the initial reaction systems, carbon sources, and simple ions (NH(4)(+) and Na(+)) were responsible for the shape determination of the LaCO(3)OH products. A possible formation mechanism for these products with diverse architectures has been presented. After annealing at suitable temperatures, LaCO(3)OH was easily converted to La(2)O(2)CO(3) and La(2)O(3) with the initial morphologies. A systematic study on the photoluminescence and cathodoluminescence properties of Eu(3+)- or Tb(3+)-doped La(2)O(2)CO(3)/La(2)O(3) samples has been performed in detail. The excitation and site-selective emission spectra were recorded to investigate the microstructure, site symmetry, and difference in the (5)D(0) → (7)F(2) transition of Eu(3+) ions in La(2)O(2)CO(3) and La(2)O(3) host lattices. In addition, the dependence of the luminescent intensity on the morphology for the as-prepared La(2)O(2)CO(3)/La(2)O(3):Ln(3+) (Ln = Eu, Tb) samples has been investigated. The ability of generating diverse morphologies and multiemitting colors for different rare-earth activator ion (Ln = Eu, Tb) doped La(2)O(2)CO(3)/La(2)O(3) nano/microstructures provides a great opportunity for the systematic evaluation of morphology-dependent luminescence properties, as well as the full exploration of their application in many types of color display fields.

Rethinking EU Citizenship: Towards the Postmodern Ethics of Citizenship

Directory of Open Access Journals (Sweden)

Sanja IVIC

2009-11-01

Full Text Available The concept of EU citizenship reflects EU politics of (fixed identity, which guarantees rights only to the homogenous groups (and individuals as representatives of these groups. Hence, it leaves room for marginalizing, othering, excluding and other forms of discrimination, by creating binary oppositions: we/they, citizen/alien, EU/non-EU and so forth. EU citizenship is based on the modernist ethics of priority of right over the good. It is created to promote European idea, so it has only instrumental value. On the other hand, the politics of affinity leads to the substantive EU citizenship founded on multiple identities. The politics of affinity requires a new ethics which will lead to transformation of the main concepts of EU legal discourse.

Exporting EU Liberalism Eastwards

Directory of Open Access Journals (Sweden)

Lynn M. Tesser

2009-07-01

Full Text Available There is much more to liberalism in the post communist context than has been acknowledged. A sizeable effort has indeed emerged to transplant a relatively coherent liberal ideology to the region, one exported not merely through the conditionality of international financial institutions, but also through the conditionality and socialization of organizations like the NATO, OSCE, EU, and the Council of Europe. ‘EU liberalism’ includes the ‘standard’ liberal emphasis on individual rights, the rule of law, constitutional democracy, freedom, and market economics as well as support for minority rights, and a seemingly schizophrenic emphasis on economic integration that involves, first bringing down borders for the free movement of people, goods, capital, and services between member states, and second, market regulation to diminish the social downsides of capitalism. This paper outlines EU liberalism’s emergence and its application to Central and East European countries.

The EU and China

DEFF Research Database (Denmark)

Zank, Wolfgang

In September 2004 David Shambaugh, of George Washington University, published a small article under the heading: “China and Europe: The Emerging Axis.” In his view, one “of the most important, yet least appreciated developments … has been the dramatic growth in ties between China and Europe......” (Shambaugh 2004, 243). He pointed, firstly, at the strong growth in trade relations; the EU also became the largest foreign supplier of technology and equipment, in the form of direct investment, but also through a number of joint technology projects. The EU-China Framework Program became the world’s largest...... common research project. As to political cooperation, numerous meetings have been institutionalised, among them, at the top level an annual EU-China Summit. The contacts have resulted in a number of agreements, for instance on group tourism. According to estimates 100,000 Chinese Students went...

Towards a Practice Turn in EU Studies

DEFF Research Database (Denmark)

Adler-Nissen, Rebecca

2016-01-01

This article explores how practice theory can be recruited for the study of European integration. New generations of EU researchers are fascinated by the prospect of leaving the armchair and studying the people and artefacts that make the EU on an everyday level. This article surveys key practice......-oriented, anthropological and micro-sociological studies of the EU and European integration and shows how their findings challenge more traditional understandings of the dynamics of European integration. Moving beyond a stock-taking, the article distinguishes between ‘order- ing’ and ‘disordering’ practices and explores...... the potential of a practice turn in EU studies for both theory (overcoming dualism, replacing substantialism with processualism and rethinking power) and methods (including unstructured interviews, fieldwork and participant observation). A practice turn will force us to rethink core assumptions about the EU...

The EU's Convergence Dilemma

Directory of Open Access Journals (Sweden)

Notermans Ton

2015-02-01

Full Text Available As economic stagnation continues to mark the EU in the fifth year of the euro zone crisis, political support for integration is waning. The European Parliament elections of 2014 returned a hitherto unparalleled number of Eurosceptic MEPs, with EU-critical parties becoming the largest ones in several Member States. Much of this Euroscepticism is driven by economic polarisation between core and peripheral countries. While an increasing number of voters in the northwestern creditor countries resent having to foot the bill for what they consider economic mismanagement in the periphery, voters in peripheral countries increasingly rebel against what they deem to be an economically catastrophic Diktat from Germany and its allies. Continued political support for European integration will hinge on successful income convergence in the EU but the current dilemma is that such policies might not be politically feasible. Periods of rapid convergence would seem to suggest that success depends on two main policy strategies. First, a monetary policy that promotes credit for productive purposes, leaves inflation control to other instruments, and employs selective credit rationing to prevent asset booms. Second, a vertical industrial policy prioritising selected industrial sectors. The first policy conflicts with the present framework of euro zone monetary policy, but that framework was only installed in the first place because many peripheral countries were desperately in search of an external constraint on domestic distributional conflict. Industrial policies, in turn, require a sufficient degree of state autonomy from business elites in order to be effective, but it is highly questionable whether most states in the EU possess such autonomy. Though there are, as yet hesitant, signs of a reorientation of both monetary and cohesion policy in the EU, the question of the institutional and political preconditions for their successful implementation has been largely

Refugee Quota Trading within the Context of EU-ENP Cooperation: Rational, Bounded Rational and Ethical Critiques

Directory of Open Access Journals (Sweden)

Mollie Gerver

2013-02-01

Full Text Available In 1997 Peter Schuck proposed a ‘refugee quota trading’ mechanism, whereby countries voluntarily form a union, each country accepting a quota of refugees and able to buy and sell the quota to other states within and even outside of the union. Today, the EU arguably has a de facto cash transfer mechanism both within the EU and between the EU and European Neighbourhood Policy countries. This article explores the question of refugee quota trading, explaining why current EU policy fails to increase refugee protection. Throughout the critique, states are treated either as rational actors or actors with present-preference bias, the latter largely ignored in current discussions on international refugee ‘burden sharing’. In addition, the ethics of refugee quota trading is presented using arguments distinct from that of Anker et al. (1998 who argue that refugee quota trading creates a ‘commodification’ of refugees. One could argue that refugees’ protection is being commodified, not refugees themselves. However, when states are provided funds not to deport refugees, this can be a type of reward for not taking an action that states ought to follow regardless of the reward. Just as there are non-utilitarian reasons not to rely on rewards alone for lowering the crime rates for heinous crimes within states, there may be non-utilitarian arguments against refugee quota trading.

Absolute measurement of 152Eu

International Nuclear Information System (INIS)

Baba, Hiroshi; Baba, Sumiko; Ichikawa, Shinichi; Sekine, Toshiaki; Ishikawa, Isamu

1981-08-01

A new method of the absolute measurement for 152 Eu was established based on the 4πβ-γ spectroscopic anti-coincidence method. It is a coincidence counting method consisting of a 4πβ-counter and a Ge(Li) γ-ray detector, in which the effective counting efficiencies of the 4πβ-counter for β-rays, conversion electrons, and Auger electrons were obtained by taking the intensity ratios for certain γ-rays between the single spectrum and the spectrum coincident with the pulses from the 4πβ-counter. First, in order to verify the method, three different methods of the absolute measurement were performed with a prepared 60 Co source to find excellent agreement among the results deduced by them. Next, the 4πβ-γ spectroscopic coincidence measurement was applied to 152 Eu sources prepared by irradiating an enriched 151 Eu target in a reactor. The result was compared with that obtained by the γ-ray spectrometry using a 152 Eu standard source supplied by LMRI. They agreed with each other within the error of 2%. (author)

Photoluminescence properties and thermal stability of blue-emitting Ba5-xCl(PO4)3:xEu2+ (0.004≤x≤0.016) phosphors.

Science.gov (United States)

Liu, Jie; Zhang, Zhi-Ming; Wu, Zhan-Chao; Wang, Fang-Fang; Li, Zhen-Jiang; Kuang, Shao-Ping; Wu, Ming-Mei

2017-01-15

A series of blue-emitting Ba 5-x Cl(PO 4 ) 3 :xEu 2+ (0.004≤x≤0.016) phosphors were synthesized by conventional high-temperature solid state reaction. The structure and photoluminescence (PL) properties of the phosphors were investigated. The as-prepared phosphors exhibit broad excitation band ranging from 250 to 420nm, and strong asymmetric blue emission band peaking at 436nm. The optimum concentration of Eu 2+ in the Ba 5 Cl(PO 4 ) 3 :Eu 2+ phosphor is x=0.01, and the concentration quenching mechanism is verified to be the combined actions of dipole-dipole interaction and radiation re-absorption mechanism. The thermal stability of Ba 5 Cl(PO 4 ) 3 :Eu 2+ was evaluated by temperature-dependent PL spectra. Compared with that of commercial BaMgAl 10 O 17 :Eu 2+ (BAM) phosphor, the Ba 5-x Cl(PO 4 ) 3 :xEu 2+ phosphors exhibit similarly excellent thermal quenching property. In addition, the CIE chromaticity coordinates of Ba 5-x Cl(PO 4 ) 3 :xEu 2+ (0.004≤x≤0.016) were calculated to evaluate the color quality. All the results indicate that Ba 5 Cl(PO 4 ) 3 :Eu 2+ is a promising candidate phosphor for near-ultraviolet (n-UV) pumped LED. Copyright © 2016 Elsevier B.V. All rights reserved.

Coordinating the Uncoordinated: The EU Forest Strategy

Directory of Open Access Journals (Sweden)

Filip Aggestam

2018-03-01

Full Text Available The second European Union (EU Forest Strategy responds to new challenges facing both forests and the forest-based sector which highlights the EU’s need for a policy framework ensuring coordination and coherence of forest-related policies. The objective of the present article is to analyse whether the new Strategy contributes towards horizontal policy coherence of EU forest-related policies, given its shared and exclusive competences. This is achieved by comparing European Commission and forest industry policy priorities as articulated in the Strategy and through research carried out for the recent Cumulative Cost Assessment (CCA of forest-based industries. Results from the comparative analysis demonstrate that the Strategy does not address many EU policies and policy instruments that affect the whole forest value chain and that it clearly omits existing EU policy instrument objectives that entail significant costs for the forest-based industry. It is therefore argued that without coordinating collective EU goals and gathering strong political support, it is at best extremely difficult or at worst impossible, to achieve coherence for EU forest-related policies across the whole forest value chain. Improving coherence of Union forest-related policies will require the Strategy to address more policy areas and instruments, including clearly defined parameters of what constitutes an EU forest-related policy. These pressing needs reach beyond what the Strategy presently sets out to achieve.

IMPACTS OF CLIMATE CHANGE ON EU AGRICULTURE

Directory of Open Access Journals (Sweden)

Shailesh Shrestha

2013-09-01

Full Text Available The current paper investigates the medium term economic impact of climate changes on the EU agriculture. The yield change data under climate change scenarios are taken from the BIOMA (Biophysical Models Application simulation environment. We employ CAPRI modelling framework to identify the EU aggregate economic effects as well as regional impacts. We take into account supply and market price adjustments of the EU agricultural sector as well as technical adaptation of crops to climate change. Overall results indicate an increase in yields and production level in the EU agricultural sector due to the climate change. In general, there are relatively small effects at the EU aggregate. For example, the value of land use and welfare change by approximately between -2% and 0.2%. However, there is a stronger impact at regional level with some stronger effects prevailing particularly in the Central and Northern EU and smaller impacts are observed in Southern Europe. Regional impacts of climate change vary by a factor higher up to 10 relative to the aggregate EU impacts. The price adjustments reduce the response of agricultural sector to climate change in particular with respect to production and income changes. The technical adaption of crops to climate change may result in a change production and land use by a factor between 1.4 and 6 relative to no-adaptation situation.

The Limits of Conditionality: Turkey – EU Taxation Negotiations

Directory of Open Access Journals (Sweden)

Hakan Cavlak

2015-10-01

Full Text Available Conditionality is mostly defined as the EU policy engendered for candidate countries. However, the mere use of conditionality by the EU does not essentially explain transferring of policies and EU rules towards the candidate countries. EU conditionality may be considered as a comprising approach but in certain policy areas or countries it might not be as successful as it was on other ones. The EU conditionality basically defined as a bargaining policy of affecting through reward, under which the EU provides inducements to candidate or neighbor countries to aligning with the conditions of the EU. In this study the explanatory power of conditionality would be questioned; so the main question will be “to what extent does the EU have influence on policy convergence in a candidate country that does not have a clear membership perspective? Taxation chapter in accession negotiations between Turkey and the EU has been chosen as the case of this research as providing to have an answer on this question. The main objective of this paper is ‘analyzing the extent of EU conditionality on Turkish taxation policy.’ Furthermore, it is argued in this study that “without a concrete incentive, European Union’s impact on a candidate country would be limited.”  

EU-reporting of policy measures to mitigate climate change within the administrative sector of the Ministry of the Environment; Ilmastonmuutoksen hillintaeaen taehtaeaevien politiikkatoimenpiteiden raportointi EU:lle ympaeristoeministerioen hallinnonalalta

Energy Technology Data Exchange (ETDEWEB)

Hilden, M.; Mattinen, M.; Maeenpaeae, I.

2013-04-15

The UN's climate agreement and EU's legislation that is linked to the agreement, necessitate evaluation and reporting of the policy sectors, the implementation of policy measures, and the achievement of the set goals. A report according to EU's monitoring mechanism, Decision (280/2004/EC) and (2005/166/EU) was submitted in 2011. This report describes in detail how the data was collected in the administrative sector of the Ministry of Environment, and how the reporting was organized in practice. As a result of the experiences, measures were identified that could simplify future reporting. Some measures concern development of contentual matters, such as an improvement of economic assessments, other measures concern data management. Especially, a web-based reporting system and its realization alternatives and possibilities have been outlined. It is recommended to develop light reporting system for the environmental administration, that makes it possible to save and process data related to policies and measures, so that the different reporting needs can be met by changing the output format. (orig.)

Tipping the scale? Social media’s influences on EU attitudes and vote choice in the Danish 2015 EU referendum

DEFF Research Database (Denmark)

Ohme, Jakob

Citizens’ media use can be an important predictor of attitudes towards the European Union; those attitudes, in turn, can affect EU-related vote decisions. Elementary changes in the media environment and the increasing pressure on the EU in recent referendums may therefore be connected (e.g. Denmark...... in a referendum. Using a two-wave survey design (n=675), the study investigates if political social media use reinforces existing attitudes towards the EU. Subsequently, positive and negative polarization tendencies are connected to the ‘yes or no’ vote of Danish citizens in the 2015 EU referendum. The study...

Final report on COOMET.RI(II)-S2.Eu-152 (319/RU/04): Comparison measurements of radionuclide volume sources (Eu-152)

International Nuclear Information System (INIS)

Korostin, S.; Hernandez, T.; Oropesa, P.; Arnold, D.; Evseev, V.; Ivanukovich, A.; Milevskiy, V.; Svec, A.; Lapenas, A.; Andonova, V.; Steiner, V.

2010-01-01

Measurements of the Eu-152 specific activity in artificial volume sample of water density were performed in nine laboratories with the HPGe spectrometry technique. Analysis of the gamma radiation absorption in the sample material confirmed the Compton scattering as the main mechanism of interaction of photons with energy between 300 - 600 keV and 779 - 1408 keV in the most important for environmental monitoring substances (food, water, biological materials, soils). A list of CMCs supported by the comparison is suggested. (authors)

Final report on COOMET.RI(II)-S2.Eu-152 (319/RU/04): Comparison measurements of radionuclide volume sources (Eu-152)

Energy Technology Data Exchange (ETDEWEB)

Korostin, S. [All Russian Research Institute for Physical-Technical and Radio-Technical Measurements (VNIIFTRI), Mendeleevo (Russian Federation); Hernandez, T.; Oropesa, P. [Center of Isotopes - Radionuclide Metrology Department (CENTIS-DMR), Habana (Cuba); Arnold, D. [Physikalisch-Technische Bundesanstalt (PTB), Braunschweig (Germany); Evseev, V. [National Scientific Centre ' Institute of Metrology' (NSC IM), Kharkov (Ukraine); Ivanukovich, A.; Milevskiy, V. [Belarusian State Institute of Metrology (BelGIM), Minsk (Belarus); Svec, A. [Slovak Institute of Metrology (SMU), Bratislava (Slovakia); Lapenas, A. [Latvian National Metrology Centre Ltd, Radiation Metrology and Testing Centre (RMTC), Salaspils (Latvia); Andonova, V. [Bulgarian Institute of Metrology - National Centre of Metrology (BIM-NCM), Sofia (Bulgaria); Steiner, V. [Ministry of the Environment - Radiation and Noise Division (ISR-MoE), Jerusalem (Israel)

2010-04-15

Measurements of the Eu-152 specific activity in artificial volume sample of water density were performed in nine laboratories with the HPGe spectrometry technique. Analysis of the gamma radiation absorption in the sample material confirmed the Compton scattering as the main mechanism of interaction of photons with energy between 300 - 600 keV and 779 - 1408 keV in the most important for environmental monitoring substances (food, water, biological materials, soils). A list of CMCs supported by the comparison is suggested. (authors)

Luminescence and thermal stability tuning in (Ba,Mn)3(Gd,Y)Na(PO4)5F:Eu2+ phosphors via cation-substitution

Science.gov (United States)

Mei, Juan; Lv, Lemin; Gao, Junsong; Wei, Yi; Feng, Yuxin; Yan, Chunjie; Li, Guogang

2018-04-01

In this work, [Y3+-Gd3+] and [Mn2+-Ba2+] substitutions were designed in Ba3GdNa(PO4)5F:Eu2+ system, which were marked as BG1-xYxNPF:Eu2+ and B1-yMyGNPF:Eu2+, respectively. It is found that their luminescence properties and thermal stability could be obviously tuned. For BG1-xYxNPF:Eu2+ series, under 365 nm UV light, the emission spectra exhibited a continuous red-shift from 458 nm (x = 0) to 485 nm (x = 1) with the corresponding luminescence varying from blue light to cyan light. For B1-yMyGNPF:Eu2+ series, it was observed the coexistence of blue-green and enhanced red emission of Eu2+ and the appearance of Eu3+ emission when Mn2+ partly substituted Ba2+, resulting in a final white emission. In addition, the thermal stabilities of B1-yMyGNPF:Eu2+ were obviously improved with Mn2+ doping. The corresponding luminescence and thermal stability tuning mechanisms were investigated.

Crossrelaxations and non-radiative energy transfer from (4G5/2) Sm3+ → (5D0) Eu3+: B2O3–ZnO glasses

International Nuclear Information System (INIS)

Naresh, V.; Rudramadevi, B.H.; Buddhudu, S.

2015-01-01

Graphical abstract: The energy transfer process occurring from Sm 3+ to Eu 3+ in B 2 O 3 –ZnO (BZn) glasses is analyzed. Based on the Foster–Dexter theory, the possibility of energy transfer between Sm 3+ and Eu 3+ has been demonstrated from the spectral overlap of Eu 3+ absorption and Sm 3+ emission, photoluminescence spectra, energy level diagram and lifetime measurements. The energy transfer mechanism in (Sm 3+ + Eu 3+ ) co-doped glass is governed by dipole–dipole interaction. - Highlights: • Spectroscopic properties of individually doped Sm 3+ , Eu 3+ & co-doped (Sm 3+ + Eu 3+ ) in BZn glasses were studied separately. • The effect of Eu 3+ concentration on luminescence properties is explained from cross-relaxations. • Energy transfer from Sm 3+ ( 4 G 5/2 ) to Eu 3+ ( 5 D 0 ) has been explained from Foster–Dexter theory. • Dipole–dipole mechanism governs the energy transfer from Sm 3+ to Eu 3+ . - Abstract: The present paper reports on the results concerning to photoluminescence features of Eu 3+ , Sm 3+ ions and energy transfer process occurring from Sm 3+ to Eu 3+ doped in 45 B 2 O 3 –55 ZnO (BZn) glasses prepared by melt quenching technique. Luminescence quenching as a function of Eu 3+ concentration in BZn glasses has been discussed. Among the studied concentrations, 0.5 mol% of Eu 3+ is optimized because it has exhibited red emission transition 5 D 0 → 7 F 2 . With regard to Sm 3+ glasses, orange emission at 602 nm ( 4 G 5/2 → 6 H 7/2 ) has been noticed on exciting with λ exci = 403 nm. Based on the Foster–Dexter theory, the possibility of energy transfer between Sm 3+ and Eu 3+ has been explained from the spectral overlap of Eu 3+ absorption and Sm 3+ emission. The optimized concentration 0.5 mol% of Eu 3+ is co-doped with Sm 3+ in various concentrations ranging from 0.1 to 1.5 mol% inorder to study the sensitization effect of Sm 3+ on Eu 3+ luminescence. The results have revealed that with the addition of Sm 3+ to Eu 3+ : BZn

En 'dansk' immigrationspakke til EU - uden Danmark

DEFF Research Database (Denmark)

Adler-Nissen, Rebecca

2008-01-01

og den franske immigrationspagt i Danmark, skyldes, som så ofte før, at vi her i landet har en Europadebat, der er vendt på hovedet i forhold til den, der føres i de andre EU-lande. Mens danske politikere hen over sensommeren har diskuteret, hvordan man kan minimere EU's indflydelse på dansk......I dag præsenterer Kommissionen en ambitiøs pakke om lovlig og ulovlig indvandring og integration. Målet er, at den skal vedtages sammen med det franske formandskabs immigrationspagt af EU's stats- og regeringschefer den 15.-16. oktober 2008. At der ikke har været mere debat om Kommissionens pakke...... indvandringspolitik og særligt familiesammenføringsreglerne, har resten af EU diskuteret, hvordan man fortsat kan styrke EU's rolle i indvandrings- og immigrationspolitikken og skabe en højere grad af solidaritet mellem medlemslandene. Udgivelsesdato: 8. oktober...

EU Energy Law and Policy Issues. Volume 3

Energy Technology Data Exchange (ETDEWEB)

Delvaux, B.; Hunt, M.; Talus, K. (eds.)

2011-12-15

This third volume of EU Energy Law and Policy Issues presents an overview of some of the most recent developments taking place in the EU energy sector at a time when the Third Energy Package is likely to be or has been implemented in the EU Member States. In this respect, the reader will find a number of contributions which offer detailed and critical views on some of the main issues tackled by the Third Energy Package. Aside from this, the relationship between sector specific regulation and the rules of general competition law is examined in the second section of the book. This part also contains particular contributions on access regimes in gas and electricity markets as well as an innovating analysis on the methods for allocating allowances under the EU Emissions trading scheme and the interaction of such methods with EU state aid rules. Just like the previous volumes of the book, section III offers a deep insight into the external aspects of EU energy policy. Accordingly, the role of the Lisbon Treaty in promoting EU energy policy in the international arena is scrutinized in addition to the most recent evolutions on the topical issue of the Energy Charter Treaty. This section is completed with a daring contribution about the need to adopt a comprehensive theory of legal harmonization between the EU and third partners, which is presented using the specific case of the EU-Russia Energy Dialogue. Last but not least, some fundamental issues regarding the environmental aspects of EU Energy policy undergo an in-depth study in the final section of the book. Not only is the legal regime of energy efficiency in energy-related products examined, but also the issue of carbon constraining policies under WTO law. Finally, the electricity's industry viewpoint on the 2020 targets rounds off this third volume of EU Energy Law and Policy Issues with judicious comments.

EU Energy Law and Policy Issues. Volume 3

International Nuclear Information System (INIS)

Delvaux, B.; Hunt, M.; Talus, K.

2011-12-01

This third volume of EU Energy Law and Policy Issues presents an overview of some of the most recent developments taking place in the EU energy sector at a time when the Third Energy Package is likely to be or has been implemented in the EU Member States. In this respect, the reader will find a number of contributions which offer detailed and critical views on some of the main issues tackled by the Third Energy Package. Aside from this, the relationship between sector specific regulation and the rules of general competition law is examined in the second section of the book. This part also contains particular contributions on access regimes in gas and electricity markets as well as an innovating analysis on the methods for allocating allowances under the EU Emissions trading scheme and the interaction of such methods with EU state aid rules. Just like the previous volumes of the book, section III offers a deep insight into the external aspects of EU energy policy. Accordingly, the role of the Lisbon Treaty in promoting EU energy policy in the international arena is scrutinized in addition to the most recent evolutions on the topical issue of the Energy Charter Treaty. This section is completed with a daring contribution about the need to adopt a comprehensive theory of legal harmonization between the EU and third partners, which is presented using the specific case of the EU-Russia Energy Dialogue. Last but not least, some fundamental issues regarding the environmental aspects of EU Energy policy undergo an in-depth study in the final section of the book. Not only is the legal regime of energy efficiency in energy-related products examined, but also the issue of carbon constraining policies under WTO law. Finally, the electricity's industry viewpoint on the 2020 targets rounds off this third volume of EU Energy Law and Policy Issues with judicious comments.

Luminescence of Eu:Y3Al5O12, Eu:Lu3Al5O12, and Eu:GdAlO3 Nanocrystals Synthesized by Solution Combustion

Science.gov (United States)

Vilejshikova, E. V.; Khort, A. A.; Podbolotov, K. B.; Loiko, P. A.; Shimanski, V. I.; Shashkov, S. N.; Yumashev, K. V.

2017-11-01

Nanocrystals of rare-earth garnets Y3Al5O12 and Lu3Al5O12 and perovskite GdAlO3 highly doped (10-20 at%) with Eu3+ are synthesized by the solution combustion technique and subsequent annealing in air at 800 and 1300oC. Their structure, morphology, and phase composition are studied. These materials exhibit intense red luminescence under UV excitation. Eu:GdAlO3 luminescence has CIE 1931 color coordinates (0.632, 0.368); dominant wavelength, 599.6 nm; and color purity, >99%. Judd-Ofelt parameters, luminescence branching ratios, and lifetimes of the Eu3+ 5D0 state are determined. The luminescence quantum yield for Eu:GdAlO3 (10 at%) reaches 74% with a lifetime of 1.4 ms for the 5D0 state. The synthesized materials are promising for red ceramic phosphors.

EU emissions trading: Distinctive behavior of small companies

OpenAIRE

Naegele, Helene; Zaklan, Aleksandar

2016-01-01

The EU Emissions Trading System (EU ETS) is the cornerstone of the European Union's climate policy and covers just under half of the EU's greenhouse gas emissions. More than ten years since the EU ETS was first introduced, there continues to be substantial research interest regarding its functioning and the behavior of participating companies. DIW Berlin conducted three econometric studies based on microdata at company and/or installation level. The findings suggest that, overall, there are o...

EU-policy and smart materials; EU-beleid en smart materials

Energy Technology Data Exchange (ETDEWEB)

Pieters, D.; Van der Beek, M.

2012-09-15

Netherlands will focus on large-scale production of smart materials. Several examples from Dutch universities show that the Netherlands is very active in this sector. Nanotechnology and the development of advanced materials are considered as 'key technologies'. To realize these applications EU funding will be made available both for research projects and to support market introduction [Dutch] Nederland zet in de toekomst in op grootschalige productie van smart materials. Verschillende voorbeelden van Nederlandse universiteiten laten zien dat Nederland tot op heden zeer actief is in deze veelzijdige sector. Nanotechnologie en de ontwikkeling van geavanceerde materialen worden in dit licht beschouwd als zogenoemde 'sleuteltechnologieen'. Om deze toepassingen te realiseren komt zowel EU-geld beschikbaar voor onderzoeksprojecten als ter ondersteuning van marktintroductie.

The new fluorescence enhancement system Eu3+-ARADE-HMTM-AI3+ and its analytical application

International Nuclear Information System (INIS)

Wenwu Quin; Weisheng Liu; Tianlin Yang

2004-01-01

A new bis-Schiff base ligand, N,N -bis-(4-N-aminothiourea-2-amylidene)-4,4 -diaminodiphenyl ether (ARADE), was synthesized. Its complex with Eu 3+ in DMF emits the intrinsic fluorescence of Eu 3+ . The fluorescence intensity of the Eu 3+ -ARADE system was enhanced about 60-fold by the addition of hexamethylene tetramine (NMTM) and potash alum. This is a new fluorescence enhancement phenomenon. The excitation and emission wavelengths are 375 nm and 615 nm, respectively. Under optimal conditions, the fluorescence intensities vary linearly with the concentration of Eu 3+ in the range of 7.8x10 -9 -1.75x10 -5 mol L -1 with a detection limit of 5.2x10 -9 mol L -1 , or with the concentration of Al 3+ in the range of 3.1x10 -7 -9.7x10 -5 mol-L -1 with a detection limit of 2.7x10 -7 mol L -1 . The interferences of some rare earth metals and other inorganic ions were described. This method was applied to the determination of Eu 3+ in high purity yttrium oxide and the analysis of AI 3+ in alloy steel standard samples. The mechanism of fluorescence enhancement was also studied. (author)

Point Climat no. 16 'Applying MiFID to the EU ETS: what are the implications?'

International Nuclear Information System (INIS)

Patay, Magali; Alberola, Emilie

2012-01-01

Among the publications of CDC Climat Research, 'Climate Briefs' presents, in a few pages, hot topics in climate change policy. This issue addresses the following points: The European Union is moving ahead with a proposal to regulate trading in carbon assets under the revised Markets in Financial Instruments Directive (MiFID). This would mean that all trading in such assets, from the European Union Emissions Trading System (EU ETS) to international carbon credits from Kyoto project-based mechanisms eligible for the EU ETS would be covered by the existing EU regulatory framework for financial markets. Allowance spot and derivative markets are set to be supervised by a single oversight authority, and the MiFID and Market Abuse Directive will apply. While this will bring benefits in terms of improved security, transparency and protections for market participants in the carbon market, future challenges for the EU ETS will involve the proper coordination of MiFID with the Auctioning Regulation, and ensuring that the ad hoc treatment of emission allowances is maintained within the MiFID legislation

Highlight report: Launch of a large integrated European in vitro toxicology project: EU-ToxRisk.

Science.gov (United States)

Daneshian, Mardas; Kamp, Hennicke; Hengstler, Jan; Leist, Marcel; van de Water, Bob

2016-05-01

The integrated European project, EU-ToxRisk, proudly sees itself as "flagship" exploring new alternative-to-animal approaches to chemical safety evaluation. It promotes mechanism-based toxicity testing and risk assessment according to the principles laid down for toxicology for the twenty-first century. The project was officially launched in January 2016 with a kickoff meeting in Egmond aan Zee, the Netherlands. Over 100 scientists representing academia and industry as well as regulatory authorities attended the inaugural meeting. The project will integrate advances in in vitro and in silico toxicology, read-across methods, and adverse outcome pathways. EU-ToxRisk will continue to make use of the case study strategy deployed in SEURAT-1, a FP7 initiative ended in December 2015. Even though the development of new non-animal methods is one target of EU-ToxRisk, the project puts special emphasis on their acceptance and implementation in regulatory contexts. This €30 million Horizon 2020 project involves 38 European partners and one from the USA. EU-ToxRisk aims at the "development of a new way of risk assessment."

Antiferromagnetism in EuPdGe{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Albedah, Mohammed A. [Department of Physics, University of Ottawa, Ottawa, Ontario K1N 6N5 (Canada); Al-Qadi, Khalid [Department of Physics, University of Ottawa, Ottawa, Ontario K1N 6N5 (Canada); Department of Mathematics, Statistics and Physics, Qatar University, P.O. Box 2713, Doha (Qatar); Stadnik, Zbigniew M., E-mail: stadnik@uottawa.ca [Department of Physics, University of Ottawa, Ottawa, Ontario K1N 6N5 (Canada); Przewoźnik, Janusz [Solid State Physics Department, Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, 30-059 Kraków (Poland)

2014-11-15

Highlights: • We show that EuPdGe{sub 3} crystallizes in the BaNiSn{sub 3}-type structure with the lattice constants a = 4.4457(1) Å and c = 10.1703(2). • We demonstrate that EuPdGe{sub 3} is an antiferromagnet with the Néel temperature T{sub N} = 12.16(1) K. • The temperature dependence of the hyperfine magnetic field follows a S = 7/2 Brillouin function. • We find that the Debye temperature of the studied compound is 199(2) K. - Abstract: The results of X-ray diffraction, magnetic susceptibility and magnetization, and {sup 151}Eu Mössbauer spectroscopy measurements of polycrystalline EuPdGe{sub 3} are reported. EuPdGe{sub 3} crystallizes in the BaNiSn{sub 3}-type tetragonal structure (space group I4mm) with the lattice constants a=4.4457(1)Å and c=10.1703(2)Å. The results are consistent with EuPdGe{sub 3} being an antiferromagnet with the Néel temperature T{sub N}=12.16(1)K and with the Eu spins S=7/2 in the ab plane. The temperature dependence of the magnetic susceptibility above T{sub N} follows the modified Curie-Weiss law with the effective magnetic moment of 7.82(1) μ{sub B} per Eu atom and the paramagnetic Curie temperature of -5.3(1)K indicative of dominant antiferromagnetic interactions. The M(H) isotherms for temperatures approaching T{sub N} from above are indicative of dynamical short-range antiferromagnetic ordering in the sample. The temperature dependence of the hyperfine magnetic field follows a S=7/2 Brillouin function. The principal component of the electric field gradient tensor is shown to increase with decreasing temperature and is well described by a T{sup 3/2} power-law relation. The Debye temperature of EuPdGe{sub 3} determined from the Mössbauer data is 199(2) K.

25 years of European Union (EU) quality schemes for agricultural products and foodstuffs across EU Member States.

Science.gov (United States)

Albuquerque, Tânia G; Oliveira, M Beatriz Pp; Costa, Helena S

2018-05-01

Consumers are increasingly turning their attention to the quality and origin of products that they consume. European Union (EU) quality schemes are associated with a label, which was introduced to allow consumers to perform an informed choice and to protect producers from unfair practices. This present study provides an overview of the last 25 years of EU quality schemes [Protected Designations of Origin (PDO), Protected Geographical Indications (PGI) and Traditional Specialities Guaranteed (TSG)] on agricultural products and foodstuffs across the 28 EU Member States. According to the results, it was possible to conclude that Southern European countries have the highest number of registered products. The most used EU quality scheme is PGI, followed by PDO. Concerning the analysis of the evolution in the last 25 years, the number of registered products among EU Member States has increased significantly. The fruit, vegetables and cereals (fresh or processed) category is the one that accounts for the highest percentage (26.8%) of registered products, followed by cheeses and meat products (cooked, salted, smoked) categories, with 17.2% and 13.5%, respectively. Further investigations should address consumer preferences, knowledge and attitudes, especially Northern European countries with a lower number of registered products. Moreover, the investigation and registration of products should be encouraged among all EU Member States to allow the maintenance of important elements of the history, culture and heritage of the local areas, regions and countries. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

Search for linking transitions in {sup 143}Eu

Energy Technology Data Exchange (ETDEWEB)

Lerma, F.; LaFosse, D.R.; Devlin, M. [Washington Univ., Saint Louis, MO (United States)] [and others

1996-12-31

Six SD bands were populated in {sup 143}Eu and {sup 144}Eu, two of which had not been previously observed. Sum spectra were generated to search for two step links from the yrast SD band in {sup 143}Eu. However, no two step links were found. A single link from the SD band in {sup 143}Eu was found at 3364 keV. The level where it feeds into has not been identified. Alpha-particle energy (E{sub {alpha}}) spectra leading to the SD band and to normal states in {sup 143}Eu were measured and a correlation was found between E{sub {alpha}} and the level spin of the residual nucleus.

Extraction behaviour of Am(III) and Eu(III) from nitric acid medium in TEHDGA-HDEHP impregnated resins

Energy Technology Data Exchange (ETDEWEB)

Saipriya, G.; Kumar, T. [Bhabha Atomic Research Centre Facilities, Kalpakkam (India). Kalpakkam Reprocessing Plant; Kumaresan, R.; Nayak, P.K.; Venkatesan, K.A.; Antony, M.P. [Indira Gandhi Center for Atomic Research, Kalpakkam (India). Fuel Chemistry Div.

2016-07-01

The extraction behaviour of Am(III) and Eu(III) from nitric acid medium was studied in the solvent impregnated resins containing extractants such as tetra-bis(2-ethylhexyl)diglycolamide (TEHDGA) or bis-(2-ethylhexyl)phosphoric acid (HDEHP) or mixture of TEHDGA+HDEHP. The rate of extraction of Am(III) and Eu(III) from 1 M nitric acid and the effect of various parameters, such as the concentration of nitric acid in aqueous phase and concentration of TEHDGA and HDEHP in resin phase, on the distribution coefficient of Am(III) and Eu(III) was studied. The distribution coefficient of Am(III) and Eu(III) in HDEHP-impregnated resin decreased and that in TEHDGA-impregnated resin increased, with increase in the concentration of nitric acid. However, in (TEHDGA+HDEHP) - impregnated resin, synergic extraction was observed at lower nitric acid concentration and antagonism at higher nitric acid concentration. The mechanism of Am(III) and Eu(III) extraction in the combined resin was investigated by slope analysis method. The extraction of various metal ions present in the fast reactor simulated high-level liquid waste was studied. The separation factor of Am(III) over Eu(III) was studied using citrate-buffered diethylenetriaminepentaacetic acid (DTPA) solution.

Guardians of EU law? Analysing roles and behaviour of Dutch legislative drafters involved in EU compliance

NARCIS (Netherlands)

Mastenbroek, E.

2017-01-01

By drafting statutes and delegated acts, national legislative drafters play a crucial role in European Union (EU) compliance. Given their extensive legal training, they can be expected to operate as ‘guardians of EU law’ and thus correct national non-compliant tendencies. Yet, they also have a role

Guardians of EU law? Analysing roles and behaviour of Dutch legislative drafters involved in EU compliance

NARCIS (Netherlands)

Mastenbroek, E.; Thomann, E.; Sager, F.

2018-01-01

By drafting statutes and delegated acts, national legislative drafters play a crucial role in European Union (EU) compliance. Given their extensive legal training, they can be expected to operate as ‘guardians of EU law’ and thus correct national non-compliant tendencies. Yet, they also have a role

COMPARATIVE PERSPECTIVES IN ECONOMIC CRISES GEOGRAPHY. ECONOMIC STRATEGIES IN EU COUNTRIES

Directory of Open Access Journals (Sweden)

Roxana Maria Grecu

2011-06-01

Full Text Available The strategies for structural-systemic crisis management have generated, to a geographical level, a number of differences between EU countries. These cleavages are the result of differentialmacroeconomic policies. In this context, this article has the aim of achieving a comparative approach between countries of the south, west and east of the EU space. Also our approach is focused on observing the nature of macroeconomic policies and also on identifying a "pattern" associated with a common ideal -type of "rational choice" in the efficient and effective management of systemic crises. This article aims to identify areas of growth and economic stability of a particular model of public policy and political-economic ideology, to set up a mechanism for "economic engineering”. From the methodological point of view, this article uses a quantitativemethodology, derived from mathematical analysis, statistics and stochastic, in order to explain, understand and predict the possible evolution of the systemic crises in the EU countries. The interest lies in the possibility of giving a model of macroeconomic policy for the adjustment of inflationist imbalances, labor market and pricepolicy, and also in regulating the equation of production-consumption.

EU enlargement and the Common Agricultural Policy: The case of Slovenia

Directory of Open Access Journals (Sweden)

S. KAVCIC

2008-12-01

Full Text Available The paper aims at assessing the economic effects of Slovenia ’s accession to the EU.For this purpose, a sector model of Slovenian agriculture APAS-PAM has been constructed.The methodological framework allows for assessment of market, income and competitiveness effects for ten key agricultural products with consideration of two accession scenarios (optimistic EUe and pessimistic EUpthat describe the whole range of possible accession effects.Slovenia ’s accession to the EU will not increase agricultural production significantly.Accession under the scenario of complete acceptance of the CAP mechanisms and quasi equal treatment by the EU (EUewill not bring significant changes to aggregate production and income levels with moderate changes on commodity basis. Discrimination of the candidate countries in the field of direct payments and non-competitive down-stream sector assumed by the EUp– subscenario will significantly deteriorate the income situation of domestic producers. This holds especially for cereal and beef production. For many commodities,the competitiveness of the food processing industry assuming different price levels for raw materials could have much greater impact on the economic situation of agricultural production than agricultural policy environment itself.;

Study of formation of deep trapping mechanism by UV, beta and gamma irradiated Eu(3+) activated SrY2O4 and Y4Al2O9 phosphors.

Science.gov (United States)

Dubey, Vikas; Kaur, Jagjeet; Parganiha, Yogita; Suryanarayana, N S; Murthy, K V R

2016-04-01

This paper reports the thermoluminescence properties of Eu(3+) doped different host matrix phosphors (SrY2O4 and Y4Al2O9). The phosphor is prepared by high temperature solid state reaction method. The method is suitable for large scale production and fixed concentration of boric acid using as a flux. The prepared samples were characterized by X-ray diffraction technique and the crystallite size calculated by Scherer's formula. The prepared phosphor characterized by Scanning Electron Microscopic (SEM), Fourier Transform Infrared (FTIR), Energy Dispersive X-ray analysis (EDX), thermoluminescence (TL) and Transmission Electron Microscopic (TEM) techniques. The prepared phosphors for different concentration of Eu(3+) ions were examined by TL glow curve for UV, beta and gamma irradiation. The UV 254nm source used for UV irradiation, Sr(90) source was used for beta irradiation and Co(60) source used for gamma irradiation. SrY2O4:Eu(3+)and Y4Al2O9:Eu(3+) phosphors which shows both higher temperature peaks and lower temperature peaks for UV, beta and gamma irradiation. Here UV irradiated sample shows the formation of shallow trap (surface trapping) and the gamma irradiated sample shows the formation of deep trapping. The estimation of trap formation was evaluated by knowledge of trapping parameters. The trapping parameters such as activation energy, order of kinetics and frequency factor were calculated by peak shape method. Here most of the peak shows second order of kinetics. The effect of gamma, beta and UV exposure on TL studies was also examined and it shows linear response with dose which indicate that the samples may be useful for TL dosimetry. Formation of deep trapping mechanism by UV, beta and gamma irradiated Eu(3+) activated SrY2O4 and Y4Al2O9 phosphors is discussed in this paper. Copyright © 2015 Elsevier Ltd. All rights reserved.

Synthesis and tunable luminescence properties of Eu2+ and Tb3+-activated Na2Ca4(PO4)3F phosphors based on energy transfer

International Nuclear Information System (INIS)

Zhou, Jun; Xia, Zhiguo; You, Hongpeng; Shen, Kai; Yang, Mengxia; Liao, Libing

2013-01-01

A series of color-tunable blue–green emitting Na 2 Ca 4 (PO 4 ) 3 F:Eu 2+ ,Tb 3+ phosphors were prepared by a high temperature solid-state reaction. Their luminescence properties reveal that there is an efficient energy transfer from Eu 2+ to Tb 3+ ions via a dipole–quadrupole mechanism where Eu 2+ ions exhibit a strong excitation band in near ultraviolet (UV) region, matching well with the dominant emission band of near UV (350–420 nm) LED chips, and Eu 2+ and Tb 3+ ions can give characteristic blue and green emission light. The varied color of the phosphors from blue to green can be achieved by properly tuning the relative ratio of Eu 2+ to Tb 3+ dopant through the energy transfer from Eu 2+ to Tb 3+ ions. Thermal quenching luminescence results reveal that Na 2 Ca 4 (PO 4 ) 3 F:Eu 2+ ,Tb 3+ exhibits good thermal stability. These results demonstrate that Tb 3+ ion with low 4f–4f absorption efficiency in near UV region can play the role of an activator in narrow green-emitting phosphor through efficient energy feeding by allowing 4f–5d absorption of Eu 2+ with high oscillator strength. The present Eu 2+ –Tb 3+ codoped Na 2 Ca 4 (PO 4 ) 3 F phosphor will have potential application for the near UV white LEDs. - Highlights: ► Color-tunable blue–green Na 2 Ca 4 (PO 4 ) 3 F:Eu 2+ ,Tb 3+ phosphors were prepared. ► Eu 2+ –Tb 3+ energy transfer process and mechanism discussed. ► Thermal quenching properties of blue and green phosphors were studied.

Enhanced luminescence in Eu-doped ZnO nanocrystalline films

Energy Technology Data Exchange (ETDEWEB)

Suzuki, Keigo, E-mail: ksuzuki@murata.com; Murayama, Koji; Tanaka, Nobuhiko [Murata Manufacturing Co., Ltd., 10-1, Higashikotari 1-chome, Nagaokakyo, Kyoto 617-8555 (Japan)

2015-07-20

We found an enhancement of Eu{sup 3+} emissions in Eu-doped ZnO nanocrystalline films fabricated by microemulsion method. The Eu{sup 3+} emission intensities were increased by reducing annealing temperatures from 633 K to 533 K. One possible explanation for this phenomenon is that the size reduction enhances the energy transfer from ZnO nanoparticles to Eu{sup 3+} ions. Also, the shift of the charge-transfer band into the low-energy side of the absorption edge is found to be crucial, which seems to expedite the energy transfer from O atoms to Eu{sup 3+} ions. These findings will be useful for the material design of Eu-doped ZnO phosphors.

Implementation of integrated homecare in EU

DEFF Research Database (Denmark)

Larsen, Torben

://www.integratedhomecare.eu/ ) aims to develop a strategy for better clinical continuity in EU. Data and Method A systematic literature review on integrated care forms the base for design of an HTA of integrated home care (IHC) for chronic conditions in such a state of disablement that patient schools are not enough. The EUnet...... approach with the adaption to local conditions in a decentralized approach. This means that a regional level with direct cooperation between the administrative/financial and the clinical/specialist levels is focused. This meso- level is addressed by an international network of national specialist groups......  Implementation of Integrated Home Care in EU Objective WHO put the fragmented delivery of health and social services for large groups of chronic conditions on the research agenda in 2002 as implemented in the call EU-FP7-HEALTH-2007-3.1.6. This granted project ( http...

Renewable energies in the EU-Accession States

International Nuclear Information System (INIS)

Reiche, Danyel

2006-01-01

The aim of this article is to discuss obstacles and success conditions for renewable energy sources in the EU-Accession States and to compare them with the framework in the EU-15. Besides the ten states which will join the EU in 2004, Bulgaria and Romania which will probably join in 2007 as well as Turkey are analysed. Most of these countries have had a century-long tradition in the utilisation of RES, primarily in biomass and hydropower. However, the communist regimes were convinced of the superiority of large-scale systems and converted the energy sectors into centralised units. Due to this dominating belief system more decentralised applications such as installations using renewable energies had to close. One crucial driving force for future renewable energy development in the Accession States comes from the stipulations set by the EU. The EU-Directive on the promotion of electricity produced from RES gives the new EU-members targets for their RES-development until 2010. Due to the Directive many Accession States have already begun to pay more attention to the topic and to introduce more systematic policies. Six of the Accession States have introduced minimum tariffs which were one of the main success conditions (besides a stable and sound investment programme as well as favourable background conditions) in the leading wind energy countries Germany and Spain. Beside the external pressure by the EU and other international obligations other driving forces such as the path dependencies in the national energy policies (degree of coal, oil and gas exploitation, nuclear power use, import dependency), the political support schemes for renewable energies, possibilities of obtaining external financial support and the cognitive environment are discussed. Finally similarities and differences between EU-15 and Accession States are worked out

Synthesis and optical properties of red/blue-emitting Sr2MgSi2O7:Eu3+/Eu2+ phosphors for white LED

Directory of Open Access Journals (Sweden)

Tong Thi Hao Tam

2016-06-01

Full Text Available Phosphor-converted white light emitting diodes (white LEDs have received great attention in recent years since they have several excellent features such as high lumen output, low power consumption, long lifetime and environmentally friendly. In this work, we report the co-precipitation synthesis of red/blue Sr2MgSi2O7:Eu3+/Eu2+ phosphors with various Eu doping concentration. The results show that the obtained Sr2MgSi2O7:Eu3+/Eu2+ phosphors have good crystallinity and emit strong red (Sr2MgSi2O7:Eu3+ and blue (Sr2MgSi2O7:Eu2+ emissions under near UV light excitation. The sharp emission peaks at 577, 590, 612, 653, and 701 nm corresponded to the typical 5D0 → 7Fj (j = 0,1,2,3,4 transitions of Eu3+, and the blue emission peaking at 460 nm is attributed to the typical 4f65d1-4f7 transition of Eu2+ in the same Sr2MgSi2O7 host lattice. Both phosphors can be well excited in the wavelength range of 260–400 nm where the near UV-LED is well matched. The above results suggest that the Sr2MgSi2O7:Eu3+/Eu2+ phosphors are promising red/blue-emitting phosphors for the application in near UV pumped phosphor-converted white LEDs.

Constructing post-carbon institutions: Assessing EU carbon reduction efforts through an institutional risk governance approach

International Nuclear Information System (INIS)

LaBelle, Michael

2012-01-01

This paper examines three different governance approaches the European Union (EU) and Member States (MS) are relying on to reach a low carbon economy by 2050. Current governance literature explains the operational methods of the EU's new governance approach to reduce carbon emissions. However, the literature neglects to account for the perceived risks that inhibit the roll-out of new low carbon technology. This article, through a novel approach, uses a grounded theoretical framework to reframe traditional risk literature and provides a connection to governance literature in order to assess the ability of EU governance mechanisms to reduce carbon emissions. The empirical research is based on responses from European energy stakeholders who participated in a Delphi method discussion and in semi-structured interviews; these identified three essential requirements for carbon emissions to be reduced to near zero by 2050: (1) an integrated European energy network, (2) carbon pricing and (3) demand reduction. These features correspond to institutionalized responses by the EU and MS: the Agency for the Cooperation of Energy Regulators (ACER); European Union Emission Trading Scheme (EU ETS) and energy efficiency directives and policies integrated into existing MS institutions. The theoretical and empirical findings suggest that governance by facilitation (energy efficiency) fails to induce significant investment and new policy approaches and cannot be relied on to achieve requisite reductions in demand. Governance by negotiation (ACER) and governance by hierarchy (EU ETS) do reduce risks and may encourage the necessary technological uptake. The term ‘risk governance’ is used to explain the important role governance plays in reducing risks and advancing new technology and thereby lowering carbon emissions in the energy sector. - Highlights: ► This article assesses the role of EU institutions in reducing carbon emissions by 2050. ► Empirical research is based on Delphi

Economic Impacts of the 1997 EU Energy Tax: Simulations with Three EU-Wide Models

International Nuclear Information System (INIS)

Jansen, H.; Klaassen, G.

2000-01-01

In March 1997 the European Commission adopted a proposal that increases existing minimum levels of taxation on mineral oils by around 10 to 25% and introduces excises for other energy products. This paper analyses the macroeconomic impacts of the proposal. It employs three models: HERMES, GEM-E3, and E3ME. All models confirm that the proposal will have positive macroeconomic impacts when the tax revenues are used to reduce social security contributions paid by employers. For the EU as a whole, both GDP and employment are expected to be higher and CO2 emissions are 0.9 to 1.6 percent lower. The positive EU-wide effects can be observed in practically all member states. The sector impacts are modest, with the energy sector expected to face the most negative impacts. Differences between model results are due to the model type (general equilibrium or macro-econometric), the EU countries covered and the way tax exemptions were handled. Crucial assumptions to obtain the 'double dividend' are the modelling of the labour market and the impacts on EU external trade. The sensitivity of the results for the use of tax revenues, tax exemptions and tax rate increases is assessed. 21 refs

EU ENLARGEMENT AT A CROSSROADS

Directory of Open Access Journals (Sweden)

Andreea Cătălina Paul

2012-06-01

Full Text Available The present article aims to explore the general theme of the EU enlargement strategy in the new 2012 European context. Until now, the EU’s enlargement strategy has yielded impressive results. It succeeded in transforming ten central and eastern European countries from post-communism confusion into open-market, mature and effective systems of democratic governments, and even on the economic front, they have also made astonishing progress. It is no doubt that people in the new EU countries live better then before. In this context, the EU must continue the enlargement process to help stabilize the Balkan region that lie beyond its expanded eastern border. No one can deny that major issues concerning western Balkan countries’ accession are still on the table, and they even exert a geopolitical influence of sorts. This makes it all the more important to see stability and regional co-operation there are strategically vital. An all-out effort must now be made to complete the enlargement process and ensure there is no strategic vacuum. This article provides the framework of analyses for the EU problems and the challenges for the Balkans governments as for Brussels.

EU

DEFF Research Database (Denmark)

Nissen, Mogens Rostgaard

2008-01-01

politiske sigte er, at det tværnationale samarbejde skal øge den politiske og kulturelle samhørighed landene imellem. I det dansk-tyske grænseområde har EU gennem mange år forsøgt at medvirke til øge samarbejdet over grænsen. Der er ydet økonomisk og politisk støtte til forskellige projekter, der kan styrke...

Material Deprivation in Selected EU Countries According to EU-SILC Income Statistics

Directory of Open Access Journals (Sweden)

Stávková Jana

2012-06-01

Full Text Available The article deals with issues of households at risk of poverty in relative conception. Income poverty means a situation when the threshold of 0.6 of median income is not achieved. The analysis of a broader definition of poverty is based on identification and assessment of material deprivation factors, including: financial stress, housing conditions, availability of consumer durables and basic needs. Data sources are based EU-SILC dataset. Presented analysis is focused on selected EU countries, namely Czech Republic, Finland, France, Spain and United Kingdom. The result identifies the problem areas that cause deprivation symptoms.

Re-dispersible Li+ and Eu3+ co-doped CdS nanoparticles ...

Indian Academy of Sciences (India)

Also, it can be used as sensor for drug delivery in our body [12,13]. In the present work, we prepare re-dispersible CdS, Li+- and Eu3+-doped CdS nanoparticles in organic solvent by urea hydrolysis at 170◦C and their lumines- cence properties are studied. We propose the mechanism of re-dispersion of CdS nanoparticles ...

Optical measurements on iron pnictides containing Eu

Energy Technology Data Exchange (ETDEWEB)

Neubauer, David; Baumgartner, Andreas; Merz, Johannes; Zapf, Sina; Dressel, Martin [1. Physikalisches Institut, Universitaet Stuttgart (Germany); Aswartham, Saicharan [University of Kentucky, Lexington (United States); Wurmehl, Sabine [IFW, Dresden (Germany); Jiao, Wen-He; Cao, Guang-Han [Zhejiang University, Hangzhou (China)

2015-07-01

The interplay of magnetism with superconductivity is a fascinating, highly debated field of research and many questions still remain unsolved. Members of the EuFe{sub 2}As{sub 2} family are a perfectly suited playground for investigations concerning this topic, due to the peculiarity of strong local magnetism of the europium (T{sub N}∼ 20K), which is a unique feature among the 122 iron pnictides. Optical studies of the parent compound have already revealed that the spin density wave formation deviates from the other 122 pnictides. To get more insight into the superconducting properties of the EuFe{sub 2}As{sub 2} family we carried out an optical study on differently doped samples. We compare Eu(Fe{sub 1-x}Ir{sub x}){sub 2}As{sub 2} where electron doping takes place directly in the conducting iron layer, with EuFe{sub 2}(As{sub 1-x}P{sub x}){sub 2} which corresponds to isovalent substitution at atomic positions out of the Fe-plane. The influence of the Eu is furthermore investigated by placing data we obtained on Ba{sub 0.6}Eu{sub 0.4}(Fe{sub 1-x}Co{sub x}){sub 2}As{sub 2} in juxtaposition to the already highly investigated pure Ba analogue.

Luminescent properties and energy transfer of Gd{sup 3+}/Eu{sup 3+} co-doped cubic CaCO{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Sun, Yidi; Zou, Haifeng; Zhang, Bowen; Zhou, Xiuqing; Song, Yanhua; Zheng, Keyan [College of Chemistry, Jilin University, Changchun 130012 (China); Shi, Zhan [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Sheng, Ye, E-mail: shengye@jlu.edu.cn [College of Chemistry, Jilin University, Changchun 130012 (China)

2016-10-15

Gd{sup 3+} and Eu{sup 3+} ions co-doped CaCO{sub 3} nanoparticles have been successfully synthesized via carbonization method. The emission spectra of co-doped CaCO{sub 3} phosphors in the range of VUV–vis spectral were studied. The results reveal that the co-doped CaCO{sub 3} phosphors show intense red emission in the VUV range because of the Gd{sup 3+} ions as sensitizers. The energy transfer process from Gd{sup 3+} to Eu{sup 3+} in CaCO{sub 3}:Gd{sup 3+}/Eu{sup 3+} phosphors was investigated and discussed in terms of the luminescence spectra and the decay curves, which demonstrated that the energy transfer of Gd{sup 3+}→Eu{sup 3+} is efficient. The mechanism of energy transfer from Gd{sup 3+} to Eu{sup 3+} is a resonant transfer, in which electric dipole–dipole interaction plays a leading role. Furthermore, the effect of doping concentration of Eu{sup 3+} ions on the energy transfer efficiency was also investigated. From the photoluminescence (PL) spectra, it was also found that the incorporation of Na{sup +} ions into CaCO{sub 3}:Gd{sup 3+}/Eu{sup 3+} could lead to a remarkable increase of luminescent intensity due to the charge compensation.

Europe, the EU and its 2050 Energy Storylines

Energy Technology Data Exchange (ETDEWEB)

De Jong, J.; Weeda, E.

2007-12-15

This paper seeks to explore some of the conditions under which energy policy could be formulated in and by the European Union (EU) over the next 40 years. The development of energy policy at the EU level is addressed from a wider historical perspective, taking into account a number of factors that influence both the EU project and its energy supply security. These factors include the EU's international orientation and cooperation; the EU 'economic community of law' paradigm; the EU's (failing?) external leadership role; the impact of the fall of the Berlin Wall; and Europe's talents for creativity and improvisation. These factors are discussed in somewhat greater depth in the context of the formulation of an all-EU energy policy. The global energy policy environment is briefly discussed, indicating that energy resources for the world are less at stake than their access. On this basis, a closer look is taken at the theoretical and practical aspects of using scenarios as a tool for energy policy-making. A few examples are presented, and it is argued that scenarios should basically be addressed on the basis of storylines. Storylines do require a set of specific parameters, and in this case the choice was made to use the various roles played by stakeholders for intervening in markets and in the world order. This choice is argued on the basis of the global interrelations that are currently influencing resource policies in general and energy in particular. Market efficiency, climate change, poverty issues, geopolitics and global coordination mechanisms are considered, leading to the two policy dimensions of 'nationalism' versus 'globalism' and 'heavy' versus 'light' government as the axes for the scenarios and storylines. This paper develops four storylines that are conceivable and inherently consistent. They are labelled with names that refer not only to their content, but also to the political and

Pesticide authorization in the EU-environment unprotected?

Science.gov (United States)

Stehle, Sebastian; Schulz, Ralf

2015-12-01

Pesticides constitute an integral part of high-intensity European agriculture. Prior to their authorization, a highly elaborated environmental risk assessment is mandatory according to EU pesticide legislation, i.e., Regulation (EC) No. 1107/2009. However, no field data-based evaluation of the risk assessment outcome, i.e., the regulatory acceptable concentrations (RACs), and therefore of the overall protectiveness of EU pesticide regulations exists. We conducted here a comprehensive meta-analysis using peer-reviewed literature on agricultural insecticide concentrations in EU surface waters and evaluated associated risks using the RACs derived from official European pesticide registration documents. As a result, 44.7 % of the 1566 cases of measured insecticide concentrations (MICs) in EU surface waters exceeded their respective RACs. It follows that current EU pesticide regulations do not protect the aquatic environment and that insecticides threaten aquatic biodiversity. RAC exceedances were significantly higher for insecticides authorized using conservative tier-I RACs and for more recently developed insecticide classes, i.e., pyrethroids. In addition, we identified higher risks, e.g., for smaller surface waters that are specifically considered in the regulatory risk assessment schemes. We illustrate the shortcomings of the EU regulatory risk assessment using two case studies that contextualize the respective risk assessment outcomes to field exposure. Overall, our meta-analysis challenges the field relevance and protectiveness of the regulatory environmental risk assessment conducted for pesticide authorization in the EU and indicates that critical revisions of related pesticide regulations and effective mitigation measures are urgently needed to substantially reduce the environmental risks arising from agricultural insecticide use.

Luminescence of BaCl2:Eu2+ particles dispersed in the NaCl host excited by synchrotron radiation

International Nuclear Information System (INIS)

Pushak, A.S.; Savchyn, P.V.; Vistovskyy, V.V.; Demkiv, T.M.; Dacyuk, J.R.; Myagkota, S.V.; Voloshinovskii, A.S.

2013-01-01

BaCl 2 :Eu 2+ microcrystals embedded in the NaCl host have been obtained in the NaCl–BaCl 2 (1 mol%)–EuCl 3 (0.02 mol%) crystalline system. The influence of the annealing conditions on the formation of such particles has been studied. In particular, long-term annealing (at 200 °S during 100 h) promotes the microcrystals formation in the NaCl–BaCl 2 –Eu crystalline system. The subsequent heat treatment (annealed at 600 °S during 72 h and quenched to room temperature) is shown to lead to the destruction of the majority of these particles. The luminescent-kinetic properties of BaCl 2 :Eu 2+ microcrystals have been studied upon the ultra-violet excitation by the synchrotron radiation. The X-ray excited luminescence has been measured in order to estimate the distribution of europium ions between microcrystals and the NaCl host. The excitation mechanisms of Eu 2+ ions in the NaCl–BaCl 2 –Eu crystalline system are discussed. - Highlights: ► The formation of BaCl 2 :Eu 2+ microcrystals of 1–100 μm size embedded in the NaCl host is revealed. ► Annealing at 600 °C leads to the destruction of significant number of embedded microcrystals. ► The luminescent parameters of microcrystals is similar to ones of single crystal analogs.

Multi-level lobbying in the EU: The case of the Renewables Directive and the German energy industry

Energy Technology Data Exchange (ETDEWEB)

Ydersbond, Inga Margrete

2012-11-01

This study examines the lobbying strategies employed by the interest organizations of Germany's energy industries in the process leading up to the EU's Renewable Energy Directive. How did they lobby, and what does this reveal about their perceptions of power relations in the EU? This report focuses on the most controversial part of the Directive: legal prescriptions for support mechanisms to increase the production of renewable energy in Europe. The utilities and the renewables industries disagreed deeply, with the utilities industry favouring an EU-wide green certificate scheme, while the renewables industry pressed for national feed-in tariffs. Nine interest organizations representing these sectors, five German and four at the EU level, serve as cases in this study. Expectations as to lobbying behaviour based on the two theories/theory perspectives of liberal intergovernmentalism (LI) and multi-level governance (MLG) are formulated and tested in a most-likely case design. Result: observations are better described by the MLG perspective than by LI.(auth)

Multi-level lobbying in the EU: The case of the Renewables Directive and the German energy industry

Energy Technology Data Exchange (ETDEWEB)

Ydersbond, Inga Margrete

2012-11-01

This study examines the lobbying strategies employed by the interest organizations of Germany's energy industries in the process leading up to the EU's Renewable Energy Directive. How did they lobby, and what does this reveal about their perceptions of power relations in the EU? This report focuses on the most controversial part of the Directive: legal prescriptions for support mechanisms to increase the production of renewable energy in Europe. The utilities and the renewables industries disagreed deeply, with the utilities industry favouring an EU-wide green certificate scheme, while the renewables industry pressed for national feed-in tariffs. Nine interest organizations representing these sectors, five German and four at the EU level, serve as cases in this study. Expectations as to lobbying behaviour based on the two theories/theory perspectives of liberal intergovernmentalism (LI) and multi-level governance (MLG) are formulated and tested in a most-likely case design. Result: observations are better described by the MLG perspective than by LI.(auth)

Sharing Lessons Learned Between Industries in EU

International Nuclear Information System (INIS)

Muehleisen, A.; Strucic, M.

2012-01-01

Recent events in nuclear industry remind us on importance of continuous sharing of the knowledge and experience gained through evaluations of incidents and accidents. We frequently use experience from our daily life activities to improve our performance and avoid some mistakes or unwanted events. In the similar way we can use other industries experience. These experiences can be applied to improve nuclear safety. For example, Safety Culture, which has a great influence on the level of nuclear power plants safety, is similarly presented in other industries. Mechanisms which led to accidents from weak safety culture in one branch of other industry could be comparable to those in nuclear industry. Some other industries have many more cumulative years of experience than nuclear industry. Aviation and Oil industries are typical representatives. Part of their experience can be used in nuclear industry too. Number of reports from nuclear power plants showed us that not only specific equipment related causes lay behind accidents; there are also other causes and contributors which are more common for all industries. Hence lessons learned in other industry should be assessed and used in nuclear industry too. In the European Union, a regional initiative has been set up in 2008 in support of EU Member State nuclear safety authorities, but also EU technical support organizations, international organizations and the broader nuclear community, to enhance nuclear safety through improvement of the use of lessons learned from operational experience of nuclear power plants (NPPs). The initiative, called ''the EU Clearinghouse on Operational Experience Feedback for NPP'', is organized as a network operated by a centralized office located at the Joint Research Centre of the European Commission. The reduction of occurrence and significance of events in NPPs and their safe operation is its ultimate goal. Among others EU Clearinghouse provides services such as technical and scientific

EU Studies in Denmark and Sweden

DEFF Research Database (Denmark)

Garski, Salla; Jørgensen, Knud Erik; Manners, Ian

2012-01-01

In this brief chapter we take stock of Danish and Swedish scholarship on the European Union (EU). We intend to analyze and evaluate Danish and Swedish scholarship on EU issues, using a mixed methodology integrated into the analysis of this chapter. The method integrates a secondary analysis...

EU criminal law and fundamental rights

NARCIS (Netherlands)

de Hert, Paul; Mitsilegas, V.; Bergström, M.; Konstadinides, Th.

2016-01-01

The chapter first offers a background analysis to EU fundamental rights law, recalling the historical affirmation of the protection of fundamental rights as a EU concern, and the important innovation brought about by the Lisbon Treaty (section 2) and the multiplicity of actors involved in the system

The robustness of EU financial crimes legislation: A critical review of the EU and UK anti-fraud and money laundering scheme

OpenAIRE

Herlin-Karnell, E.; Ryder, N.

2017-01-01

In this paper we set out to chart the European Union’s (EU) genesis of fighting crime as partly one of establishing the EU as an “Area of Freedom, Security and Justice” (AFSJ) and partly one of facilitating the EU internal market creation and the establishment of a global market place. We provide an overview of the current complexities facing the EU in its current struggles for a reformation and against statist approaches by focusing on the law on financial crimes and its contemporary challan...

Ukraine, Russia and the EU: linked by gas

International Nuclear Information System (INIS)

Furfari, Samuele

2014-01-01

The Ukrainian crisis serves as a reminder just how much Ukraine plays a determining role for the European Union in energy matters, being the funnel through which most of Russian gas has to pass to reach Western Europe. One inevitable conclusion is already obvious: Russia and the EU are intimately linked and Moscow is as dependent on the EU for foreign exchange as is the EU on Russia for its gas. Nevertheless, the absence of stability in Ukraine constitutes a permanent threat to supplies to member states of the EU, especially Germany. (author)

EU-PIL

DEFF Research Database (Denmark)

Lookofsky, Joseph; Hertz, Ketilbjørn

Now in a Second Edition comprising the Brussels I Regulation “recast”, as well as other key EU legislation and case law, this book brings together principles of juridical jurisdiction, choice of law, recognition of judgments and commercial arbitration. It shows the interrelationship of the rules...

Electrochemical behaviour of the Eu3+/Eu2+ system in propionic media studied by cyclic chrono potentiometry

International Nuclear Information System (INIS)

Brotto, M.E.

1989-01-01

The electrochemical behaviour of the Eu 3 + / Eu 2 + system in propionic media was studied by means of current reversal chrono potentiometry and cyclic chrono potentiometry. Sodium perchlorate was employed as supporting electrolyte. The experiments were carried out at (25.0 ± 0.1) 0 C. The studied variables were the concentration of the electro active species, the composition of the solution and the current density. The cyclic chrono potentiometry results reveal that the charge transfer reaction is followed by the (H 3 O) + ion assisted irreversible catalytic reaction in which the Eu 3 + species is regenerated. (author)

Multi-level governance in EU climate law

NARCIS (Netherlands)

Vedder, Hans; Woerdman, Edwin; Roggenkamp, Martha; Holwerda, Marijn

2015-01-01

This chapter analyses the multi-level governance in EU climate law; it connects the international arena, with EU and national decision-making and relates climate change considerations to competitiveness concerns.

X-ray or UV-ray imaging sensor utilizing optically stimulated luminescence phenomenon in Eu-doped KCl phosphors

International Nuclear Information System (INIS)

Nanto, Hidehito; Murayama, Kazuhiko; Hirai, Yoshiaki; Taniguchi, Shin-ichi; Makamura, Shouichi; Takeuchi, Nozomu.

1993-01-01

An intense OSL with a peak at about 420 [nm] has been observed by stimulating an X-ray or UV-ray irradiated KCl: Eu crystal with F-band light whose wavelength is about 560 [um]. A possible excitation and emission mechanisms for the 420 [um] OSL peak X-ray or UV-ray irradiated sample is proposed. It is found that the OSL intensity is proportional to the X-ray absorbed dose or UV-ray irradiation dose. It is also found that X-ray or UV-ray irradiated KCl; Eu exhibited excellent fading characteristics. These results strongly suggest that the KCl: Eu is one of the most attractive candidates for two-dimensional X-ray or UV-ray imaging sensor utilizing the OSL phenomenon. (J.P.N.)

Influence of fluorescence of Eu(dbm)3phen doped films by gold nanorods

International Nuclear Information System (INIS)

Wang, Qingru; Shi, Qiang; Li, Shuhong; Zhang, Dong; Wang, Wenjun

2016-01-01

The gold nanorods (AuNRs) were precipitated on Eu(dbm) 3 phen doped films by different spin rates. The plasmonic enhancement and quenching effects of gold nanorods on the fluorescence of Eu(dbm) 3 phen were both demonstrated. The enhancement on the fluorescence is sensitive to the distribution of the AuNRs. Both fluorescence enhancement mechanisms, i.e. increase of the intense absorption of ligands and increase of quantum efficiency, promote the 20 fold enhancement, at which the excitation wavelength red-shifts from 362 nm to 372 nm. Higher absorption of ligands in the complex due to the AuNRs caused the bathochromic shift of excitation peak. The quenching factor at 612 nm reached to 0.47.

The Impact of EU Financial Crisis and the EU Member States Measures taken to Leave Recession

Directory of Open Access Journals (Sweden)

Simona Moagăr-Poladian

2009-10-01

Full Text Available This paper is focussed on the financial packages and fiscal stimuli measures taken by EU as a group and by each EU country for supporting hard-hit sectors like automotive industry, tourism and construction. The economic crisis from 2008-2009 has led to a sharp decrease of investment climate and a massive contraction of economic activity. This means a sharp decrease of capacity utilisation that had led in time to an excessive unemployment especially in the most hit sectors. The financial rescue measures of EU are comprised in European Economic Recovery Plan (EERP. Measures approved are different from country to country, depending by the political support and the strategy chosen by the government. The EU's response to support the real economy during the economic crisis has been taken very fast and well-organized in certain countries and industries. By contrary, some Member States' recovery measures has been approved late and the rescue strategy wasn’t enough achieved. This has led to a deepening of financial instability and unemployment.

EU Policy. A Debate on EU Energy Policy

International Nuclear Information System (INIS)

Cohen, R.; Kjoelbye, L.; Aaslund, A.; Zwitserloot, R.

2008-01-01

Views from four experts in the field of energy on the EU's energy policy, as laid down in the Third Package, are presented. Kjoelbye and Cohen argue about the pros and cons of unbundling, Aaslund defends the policy of reciprocity towards Gazprom, and Zwitserloot warns that Europe's anti-Gazprom policy endangers security of supply

Epistemic Dependence and the EU Seal Ban Debate

Directory of Open Access Journals (Sweden)

Lars Christian Blichner

2015-03-01

Full Text Available On September 2009 the European Union (EU adopted a regulation banning the import of seal products into the EU or placing seal products on the EU market. The European Parliament was the main driving force behind the regulation and the EU has been criticised by affected countries outside the EU for not basing this decision on the available expert knowledge. The questions asked are how, given epistemic dependence, non-experts may challenge an expert based policy proposal. Can non-experts hold experts accountable, and if so in what way? Three main tests and ten subtests of expert knowledge are proposed and these tests are then used to assess whether the European Parliament did in fact argue in a way consistent with available expert knowledge in amending the Commission proposal for a regulation.

Eu Enlargement and Migration: Scenarios of Croatian Accession

Directory of Open Access Journals (Sweden)

Wadim Strielkowski

2013-09-01

Full Text Available This paper analyzes possible incidence of pending Croatian EU accession that is to take place on the 1st of July 2013, on the labour migration from Croatia to the European Union. We apply panel data estimators using the data on emigration from 18 EU countries into Germany (which is the EU country with the largest share of ex-Yugoslav and Croatian migrants in order to construct possible scenarios of Croatian migration to the EU.Three scenarios of migration - pessimistic, realistic and optimistic - are drawn and the sensitivity of estimated coefficients on migration from Croatia into Germany during next 25 years is further discussed in detail. We conclude that, similarly to hypothetical Turkish accession, Croatian EU accession is not going to cause massive migration inflows.

Tunable photoluminescence and magnetic properties of Dy(3+) and Eu(3+) doped GdVO4 multifunctional phosphors.

Science.gov (United States)

Liu, Yanxia; Liu, Guixia; Dong, Xiangting; Wang, Jinxian; Yu, Wensheng

2015-10-28

A series of Dy(3+) or/and Eu(3+) doped GdVO4 phosphors were successfully prepared by a simple hydrothermal method and characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectrometry (EDS), photoluminescence (PL) spectroscopy and vibrating sample magnetometry (VSM). The results indicate that the as-prepared samples are pure tetragonal phase GdVO4, taking on nanoparticles with an average size of 45 nm. Under ultraviolet (UV) light excitation, the individual Dy(3+) or Eu(3+) ion activated GdVO4 phosphors exhibit excellent emission properties in their respective regions. The mechanism of energy transfer from the VO4(3-) group and the charge transfer band (CTB) to Dy(3+) and Eu(3+) ions is proposed. Color-tunable emissions in GdVO4:Dy(3+),Eu(3+) phosphors are realized through adopting different excitation wavelengths or adjusting the appropriate concentration of Dy(3+) and Eu(3+) when excited by a single excitation wavelength. In addition, the as-prepared samples show paramagnetic properties at room temperature. This kind of multifunctional color-tunable phosphor has great potential applications in the fields of photoelectronic devices and biomedical sciences.

EU policy objectives and energy investment decisions

OpenAIRE

Alario, Juan

2007-01-01

EU energy policies have changed focus in the last few years with a view to substantially reducing energy import dependency and greenhouse gas emissions. The EU Commission has played a leading role in defining the new orientations. The implementation of the EU policy objectives approved by the Council of March 2007 will require a substantial expansion of energy investments. However, the degree of uncertainty affecting investment decisions remains high, notably in relation to the pricing of CO2...

Incentives for energy efficiency in the EU emission trading scheme

Energy Technology Data Exchange (ETDEWEB)

Schleich, Joachim [Fraunhofer-Institut fuer Systemtechnik und Innovationsforschung (ISI), Karlsruhe (Germany); Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States); Rogge, Karoline [Fraunhofer-Institut fuer Systemtechnik und Innovationsforschung (ISI), Karlsruhe (Germany); ETH Zurich (Switzerland). Group for Sustainability and Technology; Betz, Regina [New South Wales Univ. (Australia). Centre for Energy and Environmental Markets

2008-07-01

This paper explores the incentives for energy efficiency induced by the European Union Emissions Trading Scheme (EU ETS) for installations in the energy and industry sectors. Our analysis of the National Allocation Plans for 27 EU Member States for phase 2 of the EU ETS (2008-2012) suggests that the price and cost effects for improvements in carbon and energy efficiency in the energy and industry sectors will be stronger than in phase 1 (2005-2007), but only because the European Commission has substantially reduced the number of allowances to be allocated by the Member States. To the extent that companies from these sectors (notably power producers) pass through the extra costs for carbon, higher prices for allowances translate into stronger incentives for demand- side energy efficiency. With the cuts in allocation to energy and industry sectors these will be forced to greater reductions, thus the non-ET sectors like household, tertiary and transport will have to reduce less, which is more in line with the cost-efficient share of emission reductions. The findings also imply that domestic efficiency improvements in the energy and industry sectors may remain limited since companies can make substantial use of credits from the Kyoto mechanisms. The analysis of the rules for existing installations, new projects and closures suggests that incentives for energy efficiency are higher in phase 2 than in phase 1 because of the increased application of benchmarking to new and existing installations and because a lower share of allowances will be allocated for free. Nevertheless, there is still ample scope to further improve the EU ETS so that the full potential for energy efficiency can be realized. (orig.)

Energy transfer and color tunable emission in Tb3+,Eu3+ co-doped Sr3LaNa(PO4)3F phosphors.

Science.gov (United States)

Li, Shuo; Guo, Ning; Liang, Qimeng; Ding, Yu; Zhou, Huitao; Ouyang, Ruizhuo; Lü, Wei

2018-02-05

A group of color tunable Sr 3 LaNa(PO 4 ) 3 F:Tb 3+ ,Eu 3+ phosphors were prepared by conventional high temperature solid state method. The phase structures, luminescence properties, fluorescence lifetimes and energy transfer were investigated in detail. Under 369nm excitation, owing to efficient energy transfer of Tb 3+ →Eu 3+ , the emission spectra both have green emission of Tb 3+ and red emission of Eu 3+ . An efficient energy transfer occur in Tb 3+ , Eu 3+ co-doped Sr 3 LaNa(PO 4 ) 3 F phosphors. The most possible mechanism of energy transfer is dipole-dipole interaction by Dexter's theoretical model. The energy transfer of Tb 3+ and Eu 3+ was confirmed by the variations of emission and excitation spectra and Tb 3+ /Eu 3+ decay lifetimes in Sr 3 LaNa(PO 4 ) 3 F:Tb 3+ ,Eu 3+ . The color tone can tuned from yellowish-green through yellow and eventually to reddish-orange with fixed Tb 3+ content by changing Eu 3+ concentrations. The results show that the prepared Tb 3+ , Eu 3+ co-doped color tunable Sr 3 LaNa(PO 4 ) 3 F phosphor can be used for white LED. Copyright © 2017 Elsevier B.V. All rights reserved.

Energy transfer and color tunable emission in Tb3 +,Eu3 + co-doped Sr3LaNa(PO4)3F phosphors

Science.gov (United States)

Li, Shuo; Guo, Ning; Liang, Qimeng; Ding, Yu; Zhou, Huitao; Ouyang, Ruizhuo; Lü, Wei

2018-02-01

A group of color tunable Sr3LaNa(PO4)3F:Tb3 +,Eu3 + phosphors were prepared by conventional high temperature solid state method. The phase structures, luminescence properties, fluorescence lifetimes and energy transfer were investigated in detail. Under 369 nm excitation, owing to efficient energy transfer of Tb3 + → Eu3 +, the emission spectra both have green emission of Tb3 + and red emission of Eu3 +. An efficient energy transfer occur in Tb3 +, Eu3 + co-doped Sr3LaNa(PO4)3F phosphors. The most possible mechanism of energy transfer is dipole-dipole interaction by Dexter's theoretical model. The energy transfer of Tb3 + and Eu3 + was confirmed by the variations of emission and excitation spectra and Tb3 +/Eu3 + decay lifetimes in Sr3LaNa(PO4)3F:Tb3 +,Eu3 +. The color tone can tuned from yellowish-green through yellow and eventually to reddish-orange with fixed Tb3 + content by changing Eu3 + concentrations. The results show that the prepared Tb3 +, Eu3 + co-doped color tunable Sr3LaNa(PO4)3F phosphor can be used for white LED.

The EU Dimension to Soil Science in Schools

Science.gov (United States)

Johnson, Sue

2012-01-01

The EU as a context for science lessons may be given scant attention but EU decision-making is a vital factor in everyday life. Lessons on the emergence of soil science with Charles Darwin's simple scientific experiments can be linked with competence through action, inclusion and argumentations in science lessons. Decisions about an EU Soil…

Key indicators for tracking 2030 strategies towards decarbonization in the EU: which indicators, why and what process for using them?

International Nuclear Information System (INIS)

Sartor, Oliver

2016-09-01

Decarbonizing national economies will require significant structural transformations of national energy systems and a number of emissions intensive sectors. Policy makers will therefore need to identify a comprehensive and coherent set of goals for each key aspect of the transition and monitor progress towards achieving these goals using indicators. But which specific goals and indicators should they focus on? And how can we be sure that the approach is consistent with achieving deep transformation change? This paper attempts to answer this question. This question is particularly relevant for current policy debate in Europe, where EU Member States have agreed to develop a set of 'key indicators' to track progress towards decarbonization as part of the new Energy Union governance mechanism. The EU is currently in the process of developing a 'new governance mechanism' to ensure the effective implementation of the EU's Energy Union project and the achievement of the EU's targets under the 2030 Climate and Energy Framework. The new governance mechanism will have far- reaching consequences for the way that the EU and its Member States plan, monitor and coordinate on energy and climate policy post-2020. Key indicators will have a crucial role to play in this mechanism. The purpose of indicators for climate and energy policy is to monitor progress towards EU climate and energy goals. However, since the bulk of policy action towards these goals generally takes place at the Member State level, these goals must also be adopted at Member State level for the indicators to track the success of policy implementation. For this, the goals that indicators track need to be included in national climate and energy plans. The EU has proposed to make this the case for some EU goals contained in the Energy Union project, but not for other ones. A closer integration of European indictors and national plans and targets set by Member States is needed. A singular use of indicators only to

EU emission trading. Requirement of adaptation of the Cap as a consequence of external shocks and unexpected developments?; EU-Emissionshandel. Anpassungsbedarf des Caps als Reaktion auf externe Schocks und unerwartete Entwicklungen?

Energy Technology Data Exchange (ETDEWEB)

Diekmann, Jochen [DIW, Berlin (Germany)

2012-11-15

The effectivity of the European emission trading system (EU-ETS) with respect to the reduction of greenhouse gas emissions based essentially on the quantity of the emission caps. The regional, sectorial and temporal boundaries of this system as well as the regulations covering international flexible mechanisms and banking have to be considered in the evaluation of the effectivity of the EU-ETS. Under this aspect, the authors of the contribution under consideration discuss the advantages and disadvantages of the different variants of adjustment. First of all, the criteria for an identification of a possible justified needs of adaptation are investigated. Furthermore, the authors discuss the question about suitable points in time for an intervention.

EU-retten 1

DEFF Research Database (Denmark)

Sørensen, Karsten Engsig; Nielsen, Poul Runge

Udover en introduktion til EU-retten, herunder dens institutioner og retskilderne, indeholder bogen en grundig analyse af EF-traktatens regler om fri bevægelighed for varer, personer, tjenesteydelser og kapital....

Process of radiation damage in BaFX:Eu2+ (X=Br, I) photo-stimulable phosphor for imaging plate (IP)

International Nuclear Information System (INIS)

Kato, Munetaka; Takahashi, Kenji

2005-01-01

Imaging Plate (IP) is a 2-dimensional radiation detector utilizing photo-stimulable phosphors. Photo-stimulated luminescence (PSL) is a kind of process in radiation-induced reactions and IP can be repeatedly performed. The mechanism of PSL is reviewed and the radiation damage, which is a phenomenon that the luminescence goes down under X-ray irradiation, is also referred to. The relation between the composition of BaFX: Eu 2+ (X=Br, I), which is widely used in IPs, and the degree of radiation damage is investigated. The degree of radiation damage is smaller in the mixed crystal system of Br and I such as BaFBr 0.85 I 0.15 :Eu 2+ than in BaFBr: Eu 2+ and BaFI: Eu 2+ . This is explained by the characteristics of luminescence centers and F centers under X-ray irradiation. (author)

Business interest of Gazprom in the EU-27 in 2007

International Nuclear Information System (INIS)

Meijknecht, J.

2008-04-01

Gazprom is an important supplier of gas to the EU. Liberalisation of the EU gas market has also influenced the gas relations with Russia and the way the Russian Gas company Gazprom is securing its interest in this internal EU market. From a relationship of bilateral gas contracts with EU member states and their companies before gas market liberalisation, a new approach to secure its market share is beginning to evolve. The positioning of Gazprom in the EU market has raised concerns of EU policy makers. There is some trepidation that the investment strategy of Gazprom in the EU gas market will lead to a position of market dominance in an increasingly import dependent EU market. The discussion on Gazprom's market strategy needs to be fed with factual information on its activities and it is exactly what this new report is providing because information on the activities of Gazprom in the various member states' gas sector was incomplete. In this factual report in Dutch, the author presents a comprehensive oversight and characterisation of Gazprom's downstream assets in the EU-27. Through four layers - long-term contracts, company stakes, asset swaps and political support - a detailed insight is given in Gazprom's downstream activities in the EU-27. [nl

The new Zintl phases Eu{sub 21}Cd{sub 4}Sb{sub 18} and Eu{sub 21}Mn{sub 4}Sb{sub 18}

Energy Technology Data Exchange (ETDEWEB)

Wang, Yi; Darone, Gregory M.; Bobev, Svilen, E-mail: bobev@udel.edu

2016-06-15

Crystals of two new Zintl compounds, Eu{sub 21}Mn{sub 4}Sb{sub 18} and Eu{sub 21}Cd{sub 4}Sb{sub 18} have been synthesized using the molten metal flux method, and their structures have been established by single-crystal X-ray diffraction. Both compounds are isotypic and crystallize in the monoclinic space group C2/m (No. 12, Z=4). The structures are based on edge- and corner-shared MnSb{sub 4} or CdSb{sub 4} tetrahedra, which make octameric [Mn{sub 8}Sb{sub 22}] or [Cd{sub 8}Sb{sub 22}] polyanions. Homoatomic Sb–Sb bonds are present in both structures. The Eu atoms take the role of Eu{sup 2+}cations with seven unpaired 4f electrons, as suggested by the temperature-dependent magnetization measurements. The magnetic susceptibilities of Eu{sub 21}Mn{sub 4}Sb{sub 18} and Eu{sub 21}Cd{sub 4}Sb{sub 18} indicate that both phases order anti-ferromagnetically with Néel temperatures of ca. 7 K and ca. 10 K, respectively. The unpaired 3d electrons of the Mn atoms in Eu{sub 21}Mn{sub 4}Sb{sub 18} do contribute to the magnetic response, however, the bulk magnetization measurements do not provide evidence for long-range ordering of the Mn spins down to 5 K. Electrical resistivity measurements suggest that both compounds are narrow band gap semiconductors. - Graphical abstract: Eu{sub 21}Mn{sub 4}Sb{sub 18} and Eu{sub 21}Cd{sub 4}Sb{sub 18} have complex monoclinic structures, based on MnSb{sub 4} and CdSb{sub 4} tetrahedra, both edge- and corner-shared. A perspective of the crystal structure is shown, as viewed along the b axis. Display Omitted - Highlights: • Eu{sub 21}Mn{sub 4}Sb{sub 18} and Eu{sub 21}Cd{sub 4}Sb{sub 18} are novel compounds in the respective ternary phase diagrams. • For both structures, the Zintl-Klemm rules are followed, and both are small gap semiconductors. • Eu{sub 21}Mn{sub 4}Sb{sub 18} and Eu{sub 21}Cd{sub 4}Sb{sub 18} are air-stable Zintl phases and could be new thermoelectric materials.

The synthesis and luminescence properties of a novel red-emitting phosphor: Eu3+-doped Ca9La(PO4)7

Science.gov (United States)

Liang, Zehui; Mu, Zhongfei; Wang, Qiang; Zhu, Daoyun; Wu, Fugen

2017-10-01

A series of novel red-emitting phosphors Ca9La1- x (PO4)7: xEu3+ were synthesized by high-temperature solid state reactions. The photoluminescence excitation and photoluminescence spectra of these phosphors were investigated in detail. O2--Eu3+ charge transfer band peaking at about 261 nm is dominant in the PLE spectra of Eu3+-doped Ca9La(PO4)7, indicating that the phosphors are suitable for tricolor fluorescent lamps. The phosphors also show a good absorption in near ultraviolet (around 395 nm) and blue (around 465 nm) spectral region, which indicates that it can be pumped with NUV and blue chips for white light-emitting diodes. The transition of 5D0 → 7F2 of Eu3+ in this lattice can emit bright red light. Ca9La(PO4)7 could accommodate a large amount of Eu3+ with an optimal concentration of 60 mol%. The dipole-dipole interaction between Eu3+ is the dominant mechanism for concentration quenching of Eu3+. The calculated color coordinates lie in red region ( x = 0.64, y = 0.36), which is close to Y2O3: 0.05Eu3+ ( x = 0.65, y = 0.34). The integral emission intensity of Ca9La0.4(PO4)7: 0.6Eu3+ is 1.9 times stronger than that of widely used commercial red phosphor Y2O3: 0.05Eu3+. All these results indicate that Eu3+-doped Ca9La(PO4)7 is a promising red-emitting phosphor which can be used in tricolor fluorescent lamps and white light-emitting diodes.

Dramatic improvement in photostability of luminescent Eu(III) complexes with tetraphenylimidodiphosphinate ligand

International Nuclear Information System (INIS)

Zheng, Wei; Li, Shu-Jing; Li, Cheng-Hui; Zheng, You-Xuan; You, Xiao-Zeng

2014-01-01

In this paper, we synthesized and characterized a new Eu(III) tetraphenylimidodiphosphinate complex with dimethyl sulfoxide (DMSO) as co-ligand. Moreover, we compared the photostability of a series of Eu(III) complexes containing tetraphenylimidodiphosphinate ligands, Eu(tpip) 3 , Eu(tpip) 3 Phen, Eu(tpip) 3 DMSO, with their analogs of 1,3-dibenzoylmethanate, Eu(dbm) 3 ∙2H 2 O, Eu(dbm) 3 Phen, Eu(dbm) 3 (DMSO) 2 . We found that the photostability of the luminescent Eu(III) complexes was significantly improved upon substitution of the 1,3-diketones with tetraphenylimidodiphosphinate ligands. -- Highlights: • We synthesized and characterized a new Eu(III) tetraphenylimidodiphosphinate complexes with dimethyl sulfoxide. • We compared the photostability of Eu(III) complex with tetraphenylimidodiphosphinate and 1,3-dibenzoylmethanate ligands. • The photostability is significantly improved in Eu(III) complexes with tetraphenylimidodiphosphinate ligands

Luminescent characteristic of the CsBr phosphor activated with Eu{sup 2+} and Mn{sup 2+} ions

Energy Technology Data Exchange (ETDEWEB)

Téllez-Flores, E., E-mail: bluedays8i@hotmail.com [Programa de Posgrado en Ciencias (Física), Departamento de Investigación en Física, Universidad de Sonora, Rosales y Blvd. Transversal S/N, 83000 Hermosillo, Son., México (Mexico); Aceves, R., E-mail: raceves@cifus.uson.mx [Centro de Investigación en Física, Universidad de Sonora, Apartado Postal 5-88, 83190 Hermosillo, Son., México (Mexico); Pérez-Salas, R., E-mail: rperez@cifus.uson.mx [Centro de Investigación en Física, Universidad de Sonora, Apartado Postal 5-88, 83190 Hermosillo, Son., México (Mexico); Camarillo, I., E-mail: as99@xanum.uam.mx [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, Col. Vicentina, Delegación Iztapalapa, C.P. 09340 México D.F. (Mexico); Caldiño, U., E-mail: cald@xanum.uam.mx [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, Col. Vicentina, Delegación Iztapalapa, C.P. 09340 México D.F. (Mexico)

2013-12-15

Spectra of excitation and emission were measured at RT and 15 K in crystals quenched (Q) of CsBr:Eu{sup 2+}, CsBr:Mn{sup 2+} and CsBr:Eu{sup 2+},Mn{sup 2+}. Emission bands at 444, 480, 520 and 570 nm with different relative intensities are generated in the samples after UV excitation. The blue band at 444 nm was ascribed with unknown clusters or aggregated centers (AC) of dipoles type Eu{sup 2+}–V{sub C}{sup −} and insulated dipole centers (IDC) like Eu{sup 2+}–O{sup 2−}. The bands at 480, 520 and 570 nm were assigned to Cs{sub 4}EuBr{sub 6} nanocrystals; AC containing MnBr{sub 4}{sup 2−} units in tetrahedral symmetry and another yet unidentified AC defect, respectively. In crystals of CsBr:Eu{sup 2+},Mn{sup 2+} the excitation and emission spectra taken at 15 K show no clear evidence of an energy transfer mechanism. Instead, the results suggest that the emission is produced by direct excitation of the ions of Eu{sup 2+} and Mn{sup 2+}. Accordingly, single- or double-doped CsBr crystals may contain the same type of defects, either AC and/or IDC. -- Highlights: • The PL consists of several overlapping bands in the entire visible region. • The emission bands were ascribed to dipoles, aggregated and nanocrystals of different nature. • No clear evidence of energy transfer, meaning Eu and Mn pairs are not formed. • The material shows potential characteristics for its use as LED to white emission.

Achieving Economic Growth in the EU Through Lobbyism

DEFF Research Database (Denmark)

Svendsen, Gert Tinggaard; Brandt, Urs Steiner

2009-01-01

EU budget. Here, the two main redistribution policies, (1) Common Agricultural Policy (CAP) and (2) the Structural Funds, consume more than four fifths of the total annual EU budget. Thus, if the EU is to achieve its strategic goal, a strong cure is needed to reduce redistribution and encourage more......At Lisbon in 2000, the European Union (EU) set itself a new strategic goal, namely to become the world's leading economy and to enhance social cohesion across the union, all within a decade. It is argued in this article that one fundamental barrier to the fulfilment of this dream is the fact...

Definition of an intramolecular Eu-to-Eu energy transfer within a discrete [Eu2L] complex in solution.

Science.gov (United States)

Nonat, Aline; Regueiro-Figueroa, Martín; Esteban-Gómez, David; de Blas, Andrés; Rodríguez-Blas, Teresa; Platas-Iglesias, Carlos; Charbonnière, Loïc J

2012-06-25

Ligand L, based on two do3a moieties linked by the methylene groups of 6,6'-dimethyl-2,2'-bipyridine, was synthesized and characterized. The addition of Ln salts to an aqueous solution of L (0.01 M Tris-HCl, pH 7.4) led to the successive formation of [LnL] and [Ln(2)L] complexes, as evidenced by UV/Vis and fluorescence titration experiments. Homodinuclear [Ln(2)L] complexes (Ln = Eu, Gd, Tb, Yb, and Lu) were prepared and characterized. The (1)H and (13)C NMR spectra of the Lu and Yb complexes in D(2)O solution (pD = 7.0) showed C(1) symmetry of these species in solution, pointing to two different chemical environments for the two lanthanide cations. The analysis of the chemical shifts of the Yb complex indicated that the two coordination sites present square antiprismatic (SAP) coordination environments around the metal ions. The spectroscopic properties of the [Tb(2)L] complex upon ligand excitation revealed conventional behavior with τ(H2O) = 2.05(1) ms and ϕ(H2O) = 51%, except for the calculation of the hydration number obtained from the luminescent lifetimes in H(2)O and D(2)O, which pointed to a non-integer value of 0.6 water molecules per Tb(III) ion. In contrast, the Eu complex revealed surprising features such as: 1) the presence of two and up to five components in the (5)D(0)→(7)F(0) and (5)D(0)→(7)F(1) emission bands, respectively; 2) marked differences between the normalized spectra obtained in H(2)O and D(2)O solutions; and 3) unconventional temporal evolution of the luminescence intensity at certain wavelengths, the intensity profile first displaying a rising step before the occurrence of the expected decay. Additional spectroscopic experiments performed on [Gd(2-x)Eu(x)L] complexes (x = 0.1 and 1.9) confirmed the presence of two distinct Eu sites with hydration numbers of 0 (site I) and 2 (site II), and showed that the unconventional temporal evolution of the emission intensity is the result of an unprecedented intramolecular Eu-to-Eu

The Eastern Partnership and the EU-Turkey Energy Relations

Directory of Open Access Journals (Sweden)

Demiryol Tolga

2014-10-01

Full Text Available This article discusses the prospects and challenges of energy cooperation between the European Union (EU and Turkey within the context of the Eastern Partnership (EaP. Part of the EaP agenda is to advance energy cooperation between the EU and the partner states, particularly regarding the diversification of import routes. As an energy corridor between the EU and the hydrocarbon-rich Caspian states, Turkey is a strategic asset for European energy security. Turkey also has economic ties and political capital in the Caspian region that can help the EU reach out to its eastern partners. Despite robust incentives for cooperation, however, the EU-Turkey energy partnership has so far failed to meet mutual expectations. This article argues that this is primarily due to the inability of the two actors to credibly commit to regional energy cooperation. Commitment problem stems from two factors. First, the predominance of national energy interests over communal ones undermines credible commitment. The variation in energy needs of Member States prevents the EU from acting in unison in external energy policy. Similarly, Turkey also prioritizes its own energy security, particularly in its relations with suppliers, which undermines cooperation with the EU. Second, the EU and Turkey hold divergent perspectives on the potential political payoffs of energy cooperation. Turkish decision makers are convinced that energy cooperation warrants palpable progress in Turkey’s accession while most EU actors appear hesitant to establish a direct connection between energy and accession.

The Eu as a strategic global policy actor

DEFF Research Database (Denmark)

Chatzopoulou, Sevasti; Ansell, Christopher

that shapes and is being shaped by the EU strategic choices. This process is facilitated by the existing EU institutions and structures, the administrative and technical expertise capacity when it responds to the internal and external challenges (environment, sustainable development climate and circular......This article aims to complement the existing literature on the EU as a global actor and demonstrates that the EU’s entrepreneurship on policy, ideas and knowledge production contributes to the evolution of the EU as a strategic global policy actor. While the number of significant studies on the EU...... as a global actor proliferated the last decades, these studies concentrate on the EU’s role in a fragmented manner, focusing either on specific normative or more economic and trade issues, and thus often competing between themselves. This article acknowledges these contributions and aims to take them further...

Cross-Border Litigation and ADR Mechanisms in Disputes Concerning Mobile Computing in the EU

DEFF Research Database (Denmark)

Savin, Andrej

2011-01-01

The aim of this paper is to discuss briefly how the EU rules on jurisdiction, choice of law and alternative dispute resolution in civil and commercial matters operate in the context of mobile computing. The article first looks at rules on jurisdiction in commercial disputes, both between businesses...... and between businesses and consumers. It then discusses the choice-of-law issues applicable to mobile computing. Finally, there is an examination of alternative dispute resolution as an alternative to regular courts in transactions involving mobile computing....

Performing the EU Referendum

DEFF Research Database (Denmark)

Moeran, Brian

2016-01-01

This editorial makes use of the EU Referendum to discuss the presence of magic in contemporary societies. It analysis magic in terms of magicians, magical representations, and magical rites – as originally expounded by Malinowski and Mauss – and argues that magic is to be found not only in politi......This editorial makes use of the EU Referendum to discuss the presence of magic in contemporary societies. It analysis magic in terms of magicians, magical representations, and magical rites – as originally expounded by Malinowski and Mauss – and argues that magic is to be found not only...

Further development of the EU Emissions Trading Scheme in Germany and the European Union under consideration of experiences in other EU Member States; Weiterentwicklung des Emissionshandels - national und auf EU-Ebene

Energy Technology Data Exchange (ETDEWEB)

Wartmann, S; Klaus, S; Scharte, M; Harnisch, J [Ecofys GmbH, Nuernberg (Germany); Heilmann, S; Bertenrath, R [FiFo Koeln (Germany)

2008-02-15

The study analyses options for further development of the EU Emissions Trading Scheme (EU-ETS) after 2012. The first analysis focuses on the effects of the EU-ETS on companies, power prices, competitiveness and employment. It is followed by an analysis of overlaps or lacking coverage regarding the climate policies EU-ETS, Eco-Tax (Oekosteuer) resp. Energy Tax, the Renewable Energy Sources Act and the Combined Heat and Powert Act. These instruments are analysed with regards to their coherence. As a next step, the national allocation plans of France, The Netherlands, the United Kingdom and Poland are evaluated and recommendations are developed. Best practice recommendations for further developing the EU-ETS after 2012 both at the European and the national level are developed from the comparison of these European national allocation plans. Finally, design features of certificate systems relevant for international linking of such systems are addressed. In the analysis such design features are identified and approaches for problems potentially arising when certificate systems are linked, are developed. (orig.)

Migration from New EU Member Countries

DEFF Research Database (Denmark)

Pytlikova, Mariola

2007-01-01

The main purpose of the paper is to give predictions of the migration potential from the 7 new EU member countries to the EEA/EU-13 countries. Being able to analyze 'real' migration behavior from these particular countries over the period 1990-2000 helps me to avoid problems related to (double) o...

Advanced Stirling Radioisotope Generator EU2 Anomaly Investigation

Science.gov (United States)

Lewandowski, Edward J.; Dobbs, Michael W.; Oriti, Salvatore M.

2016-01-01

The Advanced Stirling Radioisotope Generator (ASRG) Engineering Unit 2 (EU2) is the highest fidelity electrically-heated Stirling radioisotope generator built to date. NASA Glenn Research Center (GRC) completed the assembly of the ASRG EU2 in September, 2014 using hardware from the now cancelled ASRG flight development project. The ASRG EU2 integrated the first pair of Sunpower's ASC-E3 Stirling convertors (ASC-E3 #1 and #2) in an aluminum generator housing with Lockheed Martin's Engineering Development Unit (EDU) 4 controller. After just 179 hours of EU2 generator operation, the first power fluctuation occurred on ASC-E3 #1. The first power fluctuation occurred 175 hours later on ASC-E3 #2. Over time, the power fluctuations became more frequent on both convertors and larger in magnitude. Eventually the EU2 was shut down in January, 2015. An anomaly investigation was chartered to determine root cause of the power fluctuations and other anomalous observations. A team with members from GRC, Sunpower, and Lockheed Martin conducted a thorough investigation of the EU2 anomalies. Findings from the EU2 disassembly identified proximate causes of the anomalous observations. Discussion of the team's assessment of the primary possible failure theories, root cause, and conclusions is provided. Recommendations are made for future Stirling generator development to address the findings from the anomaly investigation. Additional findings from the investigation are also discussed.

Antidumping duties, undertakings and foreign direct investment in the EU

NARCIS (Netherlands)

Belderbos, R.A.; Vandenbussche, H.; Veugelers, R.

2004-01-01

We study the effects of EU antidumping policy when foreign firms can ‘jump’ antidumping duties through foreign direct investment (FDI) in the EU. We show that duty jumping or duty pre-empting FDI occurs if the EU administration has broader objectives than protecting EU industry's profitability and

Composition dependence of the optical and structural properties of Eu-doped oxyfluoride glasses

DEFF Research Database (Denmark)

Zhu, C.F.; Wu, D.Q.; Zhang, Y.F.

2015-01-01

Europium doped oxyfluoride glasses were prepared by the melt quenching method for the light emitting diodes applications. The optical and structural properties of these glasses were studied by means of photoluminescence spectra, Commission Internationale de L'Eclairage chromaticity coordinates, X...... compositions. Finally, we propose a mechanism to explain how the glass structure affects the reduction of Eu ions as well as optical properties of the glasses.......Europium doped oxyfluoride glasses were prepared by the melt quenching method for the light emitting diodes applications. The optical and structural properties of these glasses were studied by means of photoluminescence spectra, Commission Internationale de L'Eclairage chromaticity coordinates, X...... on the base glass compositions. For certain base glass compositions, CaF2 crystals can form during the melt cooling process, and thereby enhance the conversion from Eu3+ to Eu2+. The formation of CaF2 crystals can be suppressed by adding CaO, Al2O3 and B2O3, but enhanced by adding Na2O and K2O in glass...

Potential tunable white-emitting phosphor LiSr4(BO3)3:Ce3+, Eu2+ for ultraviolet light-emitting diodes

International Nuclear Information System (INIS)

Wang Qian; Deng Degang; Hua Youjie; Huang Lihui; Wang Huanping; Zhao Shilong; Jia Guohua; Li Chenxia; Xu Shiqing

2012-01-01

A novel Ce 3+ /Eu 2+ co-activated LiSr 4 (BO 3 ) 3 phosphor has been synthesized by traditional solid-state reaction. The samples could display varied color emission from blue towards white and ultimately to yellow under the excitation of ultraviolet (UV) light with the appropriate adjustment of the relative proportion of Ce 3+ /Eu 2+ . The resonance-type energy transfer mechanism from Ce 3+ to Eu 2+ in LiSr 4 (BO 3 ) 3 :Ce 3+ , Eu 2+ phosphors is dominant by electric dipole–dipole interaction, and the critical distance is calculated to be about 29.14 Å by the spectra overlap method. White light was observed from LiSr 4 (BO 3 ) 3 :mCe 3+ , nEu 2+ phosphors with chromaticity coordinates (0.34, 0.30) upon 350 nm excitation. The LiSr 4 (BO 3 ) 3 :Ce 3+ , Eu 2+ phosphor has potential applications as an UV radiation-converting phosphor for white light-emitting diodes. - Highlights: ► White light was observed from the novel phosphor with chromaticity coordinate (0.34, 0.30). ► Resonant energy transfer between Ce 3+ and Eu 2+ occurs in the novel phosphor. ► This novel phosphor has potential applications as a UV-driven light-emitting phosphor.

Comparison of Eu(NO3)3 and Eu(acac)3 precursors for doping luminescent silica nanoparticles

International Nuclear Information System (INIS)

Enrichi, F.; Ricco, R.; Scopece, P.; Parma, A.; Mazaheri, A. R.; Riello, P.; Benedetti, A.

2010-01-01

In this study, we report the comparison between Eu 3+ -doped silica nanoparticles synthesized by Stoeber method using Eu(NO 3 ) 3 or Eu(acac) 3 as precursors. The impact of different europium species on the properties of the final silica nanospheres is investigated in details in terms of size, morphology, reachable doping amount, and luminescence efficiency. Moreover, the results obtained for different thermal treatments are presented and discussed. It is shown that the organic complex modify the silica growing process, leading to bigger and irregular nanoparticles (500-800 nm) with respect to the perfectly spherical ones (400 nm) obtained by the nitrate salt, but their luminescence intensity and lifetime is significantly higher when 800-900 o C annealing is performed.

Sol–gel synthesis of long-lasting phosphors CdSiO3: Mn2+, RE3+ (RE = Tb, Eu, Nd) and luminescence mechanism research

International Nuclear Information System (INIS)

Qu, Xiaofei; Cao, Lixin; Liu, Wei; Su, Ge; Wang, Pingping; Schultz, Isabel

2012-01-01

Highlights: ► New long-lasting CdSiO 3 : Mn 2+ , RE 3+ (RE = Tb, Eu, Nd) phosphors were synthesized by a sol–gel method. ► The afterglow performance of the CdSiO 3 : Mn 2+ , Eu 3+ phosphor was the best. ► The role of RE 3+ co-doped into the CdSiO 3 : Mn 2+ matrix was discussed in this paper. -- Abstract: Mn 2+ and RE 3+ (RE = Tb, Eu, Nd) co-doped CdSiO 3 orange phosphors were prepared at 1050 °C by a sol–gel method. The phase and crystallinity of the synthesized materials were investigated by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The luminescence characteristics were analyzed using photoluminescence (PL) spectra, afterglow decay curves, long-lasting phosphorescence spectra, and thermoluminescence (TL) spectra. Due to the difference in co-doped rare earth ionic radii, it varied greatly in trap density and trap depth caused by the different defects deriving from RE 3+ ions co-doping into the CdSiO 3 : Mn 2+ host. The afterglow intensity and time for these samples increased as follows: CdSiO 3 : Mn 2+ 0.2%, Nd 3+ 0.8% 3 : Mn 2+ 0.4%, Tb 3+ 0.8% 3 : Mn 2+ 0.4%, Eu 3+ 0.3%. CdSiO 3 : Mn 2+ 0.4%, Eu 3+ 0.3% had the best afterglow properties, which could be due to the proper traps formed by Eu 3+ ions co-doping into the host. The role of RE 3+ co-doped into the CdSiO 3 : Mn 2+ matrix and the possible long-lasting phosphorescence process was also discussed in this paper.

Implementing SDG 15.3 on Land Degradation Neutrality in the EU and EU Member States

Science.gov (United States)

Wunder, Stephanie; Starke, Sue Martina; Frelih-Larsen, Ana; Kaphengst, Timo

2017-04-01

The continuing degradation of land and soils is a severe threat to the provision of ecosystem services and economic development. Sustainable use of land and soils are therefore an integral part of the "Agenda 2030" with its 17 Sustainable Development Goals (SDGs) and 169 targets adopted by the UNGeneral Assembly in September 2015. The SDGs provide new opportunities for an ambitious and integrated environmental policy worldwide and in the EU. Among the many relevant targets that directly or indirectly address soils (such as goals on zero hunger, well being, clean energy, climate change, water and sustainable cities), target 15.3 that aims to achieve "a land degradation-neutral world" by 2030 is the most relevant. The concept of "Land Degradation Neutrality" (LDN) is not only about halting the loss of healthy and fertile land, but also actively reversing degradation by restoring land in order to counterbal-ance losses that cannot be avoided. It is a very ambitious target but due to a lack of balancing mechanisms for degradation and restoration in most countries also a new concept. Land Degra-dation Neutrality therefore both needs a scientific conceptual framework as well as a political debate about its implementation and development of instruments. In the EU and its Member States, this debate can also serve as a catalyst to revive the discussion on a common soil policy in Europe after the withdrawal of the proposal for a soil framework directive in 2014. To analyze options for the implementation of target 15.3 in Germany and Europe the research project "Implementing the Sustainable Development Goals on Soils in Germany" (http://ecologic.eu/12876) is currently carried out by the Ecologic Institute on behalf of the Ger-man Environment Agency (UBA) and the German Federal Environment Ministry (BMUB). The project will run until spring 2017 and the session "European Environmental Policies and Sustainability" at the EGU will be an ideal opportunity to present the final

Eu{sup 3+}-doped Y{sub 2}O{sub 3} hexagonal prisms: Shape-controlled synthesis and tailored luminescence properties

Energy Technology Data Exchange (ETDEWEB)

Yang, Errui [Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Li, Guangshe [Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Fu, Chaochao; Zheng, Jing [Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Huang, Xinsong [Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Xu, Wen [State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012 (China); Li, Liping, E-mail: lipingli@fjirsm.ac.cn [Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)

2015-10-25

In this work, Eu{sup 3+} doped Y{sub 2}O{sub 3} hexagonal prisms were synthesized by a novel two-phase approach, which involves water at the bottom as aqueous phase and oleylamine in the above as oil phase. With this unique reaction system, precursors of hexagonal prisms Y{sub 4}O(OH){sub 9}(NO{sub 3}) were first obtained by simply varying the volume ratio of water to oleylamine. Time-dependent experiments were systematically performed to reveal the growth mechanism of the precursor. After subsequent heat treatment, these precursors transformed to Y{sub 2}O{sub 3} hexagonal prisms with controlled diameters and aspect ratios varying from 4 to 19. Such a transformation is preceded via a topotactic process, as indicated by TG-DTA and mass spectra. Eventually, all Eu{sup 3+} doped Y{sub 2}O{sub 3} hexagonal prisms were found to exhibit an intensive red emission at 611 nm, which corresponds to {sup 5}D{sub 0}→{sup 7}F{sub 2} transition of Eu{sup 3+}. With varying the aspect ratio of hexagonal prisms and increasing Eu{sup 3+} concentration in Y{sub 2}O{sub 3}, an optimum external quantum efficiency was achieved. - Graphical abstract: In this work, Eu{sup 3+} doped Y{sub 2}O{sub 3} hexagonal prisms with controlled aspect ratio from 4.4 to 19.3 were synthesized by transformation of the precursor Y{sub 4}O(OH){sub 9}(NO{sub 3}) hexagonal prisms from a novel two-phase reaction system. The growth mechanism of the precursor has been systematically investigated, and a topotactic phase transformation from precursors to cubic Y{sub 2}O{sub 3} is for the first time put forward. By the size controlling and aspect ratio adjusting, the luminescence emission intensity as well as external quantum efficiency of Eu{sup 3+} doped Y{sub 2}O{sub 3} hexagonal prisms is further tailored to show an optimum. - Highlights: • Eu{sup 3+} doped Y{sub 2}O{sub 3} hexagonal prisms were synthesized by a novel two-phase approach. • Inheriting mechanism of prisms morphology from Y{sub 4}O(OH){sub 9

EU-UN partnership in military conflict management: Whither the ...

African Journals Online (AJOL)

UN) and the European Union (EU) in African conflict management. Constructing the EU as a security actor, including its validation through the UN, is not a process solely based on the normative claims inherent in the EU as a sui generis actor, ...

The harmonization of banking legislation in the EU

Directory of Open Access Journals (Sweden)

Shkëlqesa Çitaku

2016-03-01

Full Text Available This paper attempts to assess the current legislation of banking in the European Union. The process of unification in Europe is also followed by efforts to harmonize and unify the laws of the member states. In the field of banking industry the precondition for harmonization of laws is the integration of internal market with the free movement of capital. The regulation and supervision of banks in EU still remains fragmented. European member states still have diverse regulations concerning the role of the state. The European Commission has the important function of proposing EU legislation on financial services including banks and ensuring that EU law is properly applied throughout the EU. Banks are considered as a key industry enabling all the economic activities via depositing, crediting and arranging of payments. A number of secondary legislation has been adopted by the EU institutions to harmonize the national banking law of Member States. The principles and objectives set by the European Commission Treaty depend on four EU freedoms with the aim of effective and open market including banks. Therefore it was a continuous process of harmonization of national banking regulation via secondary law since the 70’s.

Luminescence and Tb3+-Ce3+-Eu3+ ion energy transfer in single-crystalline films of Tb3Al5O12:Ce,Eu garnet

International Nuclear Information System (INIS)

Zorenko, Y.; Gorbenko, V.; Voznyak, T.; Batentschuk, M.; Osvet, A.; Winnacker, A.

2008-01-01

The paper is devoted to investigation of the processes of excitation energy transfer between the host cations (Tb 3+ ions) and the activators (Ce 3+ and Eu 3+ ions) in single-crystalline films of Tb 3 Al 5 O 12 :Ce,Eu (TbAG:Ce,Eu) garnet which is considered as a promising luminescent material for the conversion of LED's radiation. The cascade process of excitation energy transfer is shown to be realized in TbAG:Ce,Eu: (i) from Tb 3+ ions to Ce 3+ and Eu 3+ ions; (ii) from Ce 3+ ions to Eu 3+ ions by means of dipole-dipole interaction and through Tb 3+ ion sublattice

EU GHG Emission Targets: 'Mind the gap'

International Nuclear Information System (INIS)

Lojodice, Ilaria

2012-06-01

In Durban, the European Union has been able to overcome the traditional dividing lines between developed and developing countries, setting a 'road-map' for a post-Kyoto framework. This would see countries conclude an 'agreed outcome with legal force' on emissions targets by 2015. Was this a key goal or a partial success for EU climate diplomacy? The main concerns are that the second commitment period would only come into force by 2021, and that necessary carbon cuts are not be increased before 2020. The direct by-product for the EU victory has been the awakening of the debate about raising emissions reductions to 30%. In fact, as stated in the Low Carbon Road-map, the EU has adopted a target of cutting emissions by 20% to by 2020, and of moving to a 30% reduction target if the conditions are right. Is this finally the time for Europe to improve its performance, even if it means going it alone? The EU has always been a strong defender of the Kyoto Protocol under certain constraints, such as developing and emerging countries entering into the deal. But does the EU have all the right assets to fight for this? Where is Europe in achieving its 2020 goal? In essence, this paper provides an estimate of what EU emissions could be in 2020, and how they stand compared to Kyoto and 20% objective of the 2020 strategy. (author)

Coping with EU environmental legislation

DEFF Research Database (Denmark)

Anker, Helle Tegner; de Graaf, Kars; Purdy, Ray

2015-01-01

A ‘burden reducing’ agenda has spurred an increased interest in how EU environmental legislation is transposed into national legislation—most prominently reflected in the principle of ‘no gold-plating’. Yet, an important question is to what extent transposition principles and practices may ensure...... on coherence and accessibility with respect to environmental legislation and that such issues deserve more attention in the transposition process.......A ‘burden reducing’ agenda has spurred an increased interest in how EU environmental legislation is transposed into national legislation—most prominently reflected in the principle of ‘no gold-plating’. Yet, an important question is to what extent transposition principles and practices may ensure...... a coherent and accessible body of environmental legislation, while at the same time ensuring adequate transposition of EU environmental legislation. This article analyses the existence, or emergence, of transposition principles and practices in three Member States—the United Kingdom, the Netherlands...

Review of EU Conflict Management in DRC

DEFF Research Database (Denmark)

Mandrup, Thomas

2016-01-01

The report present the backdrop on EU's involvement in the DRC conflict, its history, the nature of the conflict......The report present the backdrop on EU's involvement in the DRC conflict, its history, the nature of the conflict...

High-pressure luminescence spectroscopy of EuAl2O4 phosphor

International Nuclear Information System (INIS)

Zorenko, Yu.; Gorbenko, V.; Grinberg, M.; Turos-Matysiak, R.; Kuklinski, B.

2007-01-01

EuAl 2 O 4 powder phosphor was prepared by solid-state reaction of EuO and Al 2 O 3 oxides in vacuum. The influence of conditions of preparation on spectral lineshape of Eu 2+ emission was analyzed. It was found that the fluorescence spectra of vacuum-prepared EuAl 2 O 4 samples at 300 K present the superposition of three bands peaked at 430, 500 and 528 nm, corresponding to the 4f 6 5d 1 →4f 7 ( 8 S 7/2 ) transition of Eu 2+ ions in the different sites of EuAl 2 O 4 lattice. The luminescence of Eu 2+ centers in EuAl 2 O 4 host was also studied using the high-pressure spectroscopy up to 67 kbar. It was found that the bright green-yellow fluorescence of EuAl 2 O 4 at 300 K in the band peaked at 520-530nm range can be presented by superposition of two Gaussian sub-bands. The different pressure shifts -23 and -27cm -1 /kbar for two sub-bands were found. Such a structure of the emission spectrum was attributed to the existence of two different Eu 2+ centers in the Eu II 2+ sites of EuAl 2 O 4 lattice with higher coordination number

Who wants full membership? Characteristics of Turkish public support for EU membership

OpenAIRE

Çarkoğlu, Ali; Carkoglu, Ali

2003-01-01

Examines the basis of support and resistance to European Union (EU) membership among voters in Turkey. Issues concerning Turkey's candidacy for EU membership; Description of EU support across different constituencies of public opinion; Implications of EU membership support for EU-Turkey relations; Factors that influenced the expressed support for EU membership.

EU and Tourism Development: Bark or Bite?

DEFF Research Database (Denmark)

Halkier, Henrik

2010-01-01

In the absence of major programmes to strengthen the quality and competitiveness of European destinations, the role of the EU in tourism development has often been seen as fairly limited. Despite this, spill-overs or side effects from adjoining policy areas with extensive European regulation...... or intervention can be equally important, and the paper examines key aspects of the EU's role in tourism development in order to discuss to what extent the traditional interpretation of a passive actor of little consequence should be modified or even discarded. Drawing upon European and Nordic documentary sources...... as well as existing specialist literature, the text first examines the development of an EU policy statement on tourism, and then two areas of EU policy - competition policy and regional development - are analysed with a view to establishing side-effects in European and Nordic destinations...

EU Enlargement between Economic and Political Criteria

Directory of Open Access Journals (Sweden)

Romeo-Victor Ionescu

2013-05-01

Full Text Available The paper answers at two important questions: Is the EU able to support new adhering processes? and Is the Euro area able to enlarge in 2014? The comparative analysis in the paper covers four economic competitors: EU, USA, China and Japan, and is based on GDP growth rate, unemployment and inflation rates. The second part of the paper deals with an economic forecast during 2015-2016, focused on EU27, Euro area, Croatia and Latvia, in order to discuss the effects of the adhering to EU and Euro area. The results of the two-level analysis are supported by pertinent diagrams and annexes. The analysis uses a neutral statistical database – Eurostat – and dedicated forecast software. The main conclusion of the paper is that the adhering processes from 2013 and 2014 are based on economic and political criteria.

State and legal regulation of refugees’ and asylum seekers’ migration in EU as institutional basis of management of international migrations

Directory of Open Access Journals (Sweden)

V.V. Ievdokymov

2017-12-01

Full Text Available According to the analysis of World Bank data on the dynamics of migration indicators in Europe and Fragile State Index data the authors determine the groups of EU countries in geo-economic risk, which forms the pushing factors in the refugee flow formation. The geographic structure of refugees’ migratory flows to the EU is analyzed and the migration corridor dynamics is determined, in particular, it is found out that the overwhelming majority of refugees arrive to the EU through the Central and Eastern Mediterranean channels. In addition, It is determined that strengthening military and political instability in Africa and the Middle East, the tight policies and institutional mechanisms for crossing the EU's borders cause the increased flows of illegal migrants entering the EU in dangerous ways, in particular through the Mediterranean Sea, where a significant number of such persons, especially women and children, die. In addition, EU countries are structured by their migration policies (views on immigration, using of quantitative restrictions on immigration including highly skilled workers. As a result of the legal document study, the authors establish the system of documents identifying the institutional frameworks for the refugees’ and asylum seekers’ migratory flow management.

Complexation of Cucurbit(7)uril with Eu(III)

International Nuclear Information System (INIS)

Kar, Aishwarya; Rawat, Neetika; Rao, Ankita; Tomar, B.S.; Nayak, S.K.; Ray, Alok

2014-01-01

Cucurbiturils (CBs) CB(n)s are macrocyclic molecules with carbonyl groups at the portals, which bind cations through ion dipole interactions and the cavity which stabilize hydrophobic moieties. The size of the portal and the volume of the interior cavities of CB(n)s are dependent on the number of glycoluril units present in CBs. CBs are widely used as supramolecular host systems in applications, such as formation of supramolecular hydrogels, drug delivery systems. Though the binding of CBs with organic guest molecules have been studied extensively where as metal complexation studies are very few. In the present work, complexation studies of Cucurbit(7)uril (with seven glycouril units, CB7) with Eu(III) were carried out using fluorescence, UV-vis spectrophotometry. The stability constant for 1:1 complex CB7-Eu(III) complex determined by monitoring the change in CB7 UV- vis absorption spectra on addition of Eu(III) was found to be 2.99 ± 0.08. The fluorescence spectra of increasing ligand to metal ratio exhibited the increase in the intensity ratio of peak at 616 and 592 which is the measure of complexation of Eu(III) with CB7 and was used to deduce the stability constant and the value (2.82 ± 0.07) obtained was in good agreement with that obtained from UV vis spectroscopy. Further, the life time of Eu(III) ion, which increased with CB7 to Eu(III) ratio, was used to deduce number of water molecules around Eu(III) metal ion which were found to decrease from 9 to 3 thereby suggesting inner sphere complexation. The stability constant of CB7 with Eu(III) is one order of magnitude less than CB5, derived in separate study by authors. The smaller cavity of CB5 (2.4 A 0 ) favors its interactions with Eu(III) ion of comparable diameter (2.16 A 0 ) leading to higher stability constant compared to CB7 (5.4 A 0 ) having larger cavity

The Preparation and Optical Properties of Novel LiLa(MoO42:Sm3+,Eu3+ Red Phosphor

Directory of Open Access Journals (Sweden)

Jiaxi Wang

2018-02-01

Full Text Available Novel LiLa1−x−y(MoO42:xSm3+,yEu3+ (in short: LL1−x−yM:xSm3+,yEu3+ double molybdate red phosphors were synthesized by a solid-state reaction at as low temperature as 610 °C. The optimal doping concentration of Sm3+ in LiLa1−x(MoO42:xSm3+ (LL1−xM:xSm3+ phosphor is x = 0.05 and higher concentrations lead to emission quenching by the electric dipole—electric dipole mechanism. In the samples co-doped with Eu3+ ions, the absorption spectrum in the near ultraviolet and blue regions became broader and stronger than these of the Sm3+ single-doped samples. The efficient energy transfer from Sm3+ to Eu3+ was found and the energy transfer efficiency was calculated. Under the excitation at 403 nm, the chromaticity coordinates of LL0.95−yM:0.05Sm3+,yEu3+ approach to the NTSC standard values (0.670, 0.330 continuously with increasing Eu3+ doping concentration. The phosphor exhibits high luminous efficiency under near UV or blue light excitation and remarkable thermal stability. At 150 °C, the integrated emission intensity of the Eu3+ remained 85% of the initial intensity at room temperature and the activation energy is calculated to be 0.254 eV. The addition of the LL0.83M:0.05Sm3+,0.12Eu3+ red phosphors can improve the color purity and reduce the correlated color temperature of WLED lamps. Hence, LL1−x−yM:xSm3+,yEu3+ is a promising WLED red phosphor.

Tunable blue-green color emitting phosphors Sr{sub 3}YNa(PO{sub 4}){sub 3}F:Eu{sup 2+}, Tb{sup 3+} based on energy transfer for near-UV white LEDs

Energy Technology Data Exchange (ETDEWEB)

Jin, Yahong, E-mail: yhjin@gdut.edu.cn; Lv, Yang; Hu, Yihua, E-mail: huyh@gdut.edu.cn; Chen, Li; Ju, Guifang; Mu, Zhongfei

2017-05-15

A series of Eu{sup 2+} and Tb{sup 3+} doped Sr{sub 3}YNa(PO{sub 4}){sub 3}F phosphors have been synthesized via a high temperature solid state reaction method. Eu{sup 2+} activated Sr{sub 3}YNa(PO{sub 4}){sub 3}F phosphors can be efficiently excited by light in the range of 220–420 nm, which matches well with the commercial n-UV LEDs, and show intense blue emission centered at 456 nm. The optimal doping concentration of Eu{sup 2+} is determined to be 1 mol%. The concentration quenching mechanism of Eu{sup 2+} in SYNPF host is mainly attributed to the dipole-dipole interaction. Energy transfer from Eu{sup 2+} to Tb{sup 3+} is observed when Eu{sup 2+} and Tb{sup 3+} are co-doped into Sr{sub 3}YNa(PO{sub 4}){sub 3}F host. Under excitation of 380 nm, the emission color can be varied from blue to green along with the increase of Tb{sup 3+} doping concentration. Based on decay curves, the energy transfer from the Eu{sup 2+} to Tb{sup 3+} ions is demonstrated to be a dipole–dipole mechanism. According to thermal quenching study by yoyo experiments of heating-cooling, Sr{sub 3}YNa(PO{sub 4}){sub 3}F:Eu{sup 2+}, Tb{sup 3+} shows good thermal stability. The thermal quenching mechanism is also discussed. The results indicate that as-prepared samples might be of potential application in w-LEDs.

EU COMPARISON OF VAT

Directory of Open Access Journals (Sweden)

MARIA ZENOVIA GRIGORE

2012-05-01

Full Text Available VAT is one of the newest tools of the global economy and is widely adopted in most of the countries. For EU Member States is required not only the existence of VAT, but also that its main characteristics to be uniformly implemented. This should facilitate intra-Community transactions, but in practice does not as there are many local variations which can lead to costly errors and penalties. The objective of this paper is to collate data about the main characteristics of VAT in EU Member States and to highlight the key differences between them. This survey shows that there continue to be opportunities and risks for businesses trading cross border, as a result of differences in application of Community legislation on VAT. This led to the necessity of VAT reform. On this basis, the Commission adopted on the end of the last year a Communication on the future of VAT. This sets out the fundamental characteristics that must underlie the new VAT regime, and priority actions needed to create a simpler, more efficient and more robust VAT system in the EU.

Pressure-induced valence change and moderate heavy fermion state in Eu-compounds

Science.gov (United States)

Honda, Fuminori; Okauchi, Keigo; Sato, Yoshiki; Nakamura, Ai; Akamine, Hiromu; Ashitomi, Yosuke; Hedo, Masato; Nakama, Takao; Takeuchi, Tetsuya; Valenta, Jaroslav; Prchal, Jiri; Sechovský, Vladimir; Aoki, Dai; Ōnuki, Yoshichika

2018-05-01

A pressure-induced valence transition has attracted much attention in Eu-compounds. Among them, EuRh2Si2, EuNi2Ge2, and EuCo2Ge2 reveal the valence transition around 1, 2, and 3 GPa, respectively. We have succeeded in growing single crystals of EuT2X2 (T: transition metal, X: Si, Ge) and studied electronic properties under pressure. EuRh2Si2 indicates a first-order valence transition between 1 and 2 GPa, with a large and prominent hysteresis in the electrical resistivity. At higher pressures, the first-order valence transition changes to a cross-over regime with an intermediate valence state. Tuning of the valence state with pressure is reflected in a drastic change of the temperature dependence of the electrical resistivity in EuRh2Si2 single crystals. Effect of pressure on the valence states on EuRh2Si2, EuIr2Si2, EuNi2Ge2, and EuCo2Ge2, as well as an isostructural related compound EuGa4, are reviewed.

Photoluminescence properties of a novel red phosphor Sr{sub 3}Ga{sub 2}O{sub 5}Cl{sub 2}:Eu{sup 3+}

Energy Technology Data Exchange (ETDEWEB)

Wang, Zhonghua; Hu, Yihua; Zhang, Shaoan; Lin, Jun [Guangdong University of Technology, School of Physics and Optoelectronic Engineering, Guangzhou (China)

2016-02-15

Eu{sup 3+}-doped Sr{sub 3}Ga{sub 2}O{sub 5}Cl{sub 2} phosphors were synthesized successfully via a two-step solid-state reaction method. Phase purity and morphology of the phosphor were confirmed by XRD and SEM techniques. In the excitation spectra of Sr{sub 3}Ga{sub 2}O{sub 5}Cl{sub 2}:Eu{sup 3+} phosphor, the broad excitation band centering at 310 nm is due to the combination of charge transfer from Eu{sup 3+}→O{sup 2-} and host absorption. And it matches well the emission wavelength from UV LEDs. Sr{sub 3}Ga{sub 2}O{sub 5}Cl{sub 2}:Eu{sup 3+} phosphors show a bright orange-red luminescence under excitation with 301 nm. However, concentration quenching of Eu{sup 3+} in Sr{sub 3}Ga{sub 2}O{sub 5}Cl{sub 2}:Eu{sup 3+} occurs at a low content of 0.07 in this work. The quenching mechanism of Sr{sub 3}Ga{sub 2}O{sub 5}Cl{sub 2}:Eu{sup 3+} was discussed in detail on the basis of the experimental results. (orig.)

Facile one-step hydrothermal synthesis and luminescence properties of Eu{sup 3+}-doped NaGd(WO{sub 4}){sub 2} nanophosphors

Energy Technology Data Exchange (ETDEWEB)

Jiang, Zehan; Cai, Peiqing; Chen, Cuili; Pu, Xipeng; Kim, Sun Il, E-mail: sikim@pknu.ac.kr; Jin Seo, Hyo, E-mail: hjseo@pknu.ac.kr

2017-06-01

Eu{sup 3+}-doped NaGd(WO{sub 4}){sub 2} nanophosphors were synthesized via a facile one-step hydrothermal method without any surfactants or a further heat treatment. X-ray powder diffraction (XRD), scanning electron microscope (SEM), fourier transform infrared spectroscopy (FT-IR), the photoluminescence (PL) excitation and emission spectra, and decay curves were used to characterize NaGd(WO{sub 4}){sub 2}:Eu{sup 3+} phosphors. The results show that the Eu{sup 3+}-concentration has little influence on the structure and morphology of the as-synthesized samples. However, pH value plays a vital role on the structure and morphology of NaGd(WO{sub 4}){sub 2}. The well-crystallized sheet-like NaGd(WO{sub 4}){sub 2} phosphors can be obtained only at pH = 5–7. On the basis of the time-dependent synthesis, a possible growth mechanism of sheet-like architectures is proposed. The luminescence properties of NaGd{sub 1-x}Eu{sub x}(WO{sub 4}){sub 2} (0 ≤ x ≤ 1) are investigated. It is found that the charge transfer band of Eu{sup 3+} shifts to lower energy and broadens with increasing the Eu{sup 3+}-concentration. - Highlights: • NaGd(WO{sub 4}){sub 2}:Eu{sup 3+} nanosheets were synthesized by facile one-step hydrothermal method. • Luminescence properties of NaGd(WO{sub 4}){sub 2}:Eu{sup 3+} phosphor were firstly reported. • The CT band of Eu{sup 3+} depends strongly on Eu{sup 3+}-concentrations.

Capacity mechanisms and cross-border participation: the EU wide approach in question

International Nuclear Information System (INIS)

Finon, Dominique

2014-07-01

A capacity remuneration mechanism (CRM) which excludes cross border participants is considered to have serious distortive effects on long term competition, compared to explicit cross border participation (CBP), on the grounds that it doesn't capture the advantages of multi-system competition. This paper examines the reality of these advantages by distinguishing situations with and without congestion between systems during critical periods because congestion separates markets and their collective goods of reliability and adequacy for each system, and suppresses any economic and physical relevance of a capacity commitment from a new external participant to a CRM. From the limited perspective of any single system, there are two potential advantages of explicit CBP: the first is the supplement of the set of committed capacities to a CRM; the second is the lower cost of the adequacy policy of the system, thanks to enlarged competition, but it is illusory because the clearing price of capacity is the same with and without explicit CBP. Moreover concretization of such benefits for the system is not possible when there is congestion. From the EU wide perspective, we identify some potential gains of social efficiency from explicit CBP at the multi-system level, when we have systems with a long standing situation of over-capacity beside systems with tight situations during their critical periods; or when there exists projects of hydro equipment (pumping storage, etc... But again, congestion removes any sense to any additional revenue to them. In any case erratic revenues certainly do not steer new investment towards either system. Furthermore exchanges of capacity rights between systems equipped with different CRMs introduce a supplement of distortions compared to the same situation with implicit CPB and no trade of capacity rights. It is problematic in the case of congestion; this delays the price signal of capacity scarcity in the system with the least attractive CRM in

Ukraine, EU and Russia: soft power versus Realpolitik?

Directory of Open Access Journals (Sweden)

Pedro Barata

2014-05-01

Full Text Available The relationship between the European Union (EU and Ukraine began in 1998 with the signature of the Partnership and Cooperation Agreement. Afterwards, in 2003 Ukraine joined the European Neighbourhood Policy and in 2004 EU was already the major trade partner with Ukraine, bigger than Russia. Anticipating the approach of former soviet republics towards Euro Atlantic structures and the foreseen loss of influence in its near abroad, Putin’s Russia launched in 2011 the Eurasian Economic Union, an economic bloc formed by some of the Russia’s former satellite States - Belarus and Kazakhstan – and through a carrot and stick policy tried to attract also Ukraine and Kyrgyzstan, in order to thwart the Chinese economic development and to impose itself in the regional and global markets. In November 2013, during the 3rd EU’s Eastern Partnership Summit, in Vilnius, Lithuania, Ukraine’s President, Viktor Yanukovych surprised the world refusing to sign the Commercial Agreement with EU, turning back to a EU possible integration. On the other hand, Russia offered to reduce the natural gas rates plus a fifteen billion dollars loan, throwing Ukraine in a quasi civil war, and leaving EU and Russia on opposite sides. Considering this situation what to expect from Ukraine? To continue being a Russian satellite or head towards the Euro Atlantic geopolitical space? This paper intents to analyse the actual situation in Ukraine following Barry Buzan’s approach of multidimensional security, focusing on the different postures assumed by each one of the actors - EU and Russia - which have been between complementarity and division. The scope of the analysis is to contribute to the academic debate about security dynamics between EU, Russia and Ukraine during the post-USSR period, arguing that in the geopolitical dispute for the post-soviet space where Ukraine is integrated, the Russian Realpolitik prevails the EU soft power.

A study of luminescence from Eu"3"+, Ce"3"+, Tb"3"+ and Ce"3"+/Tb"3"+ in new potassium gadolinium phosphate K_3Gd_5(PO_4)_6

International Nuclear Information System (INIS)

Meng, Fangui; Zhang, Hongzhi; Chen, Cuili; Kim, Sun Il; Seo, Hyo Jin; Zhang, Xinmin

2016-01-01

New potassium gadolinium phosphate [K_3Gd_5(PO_4)_6] doped with Eu"3"+, Ce"3"+, Tb"3"+ and co-doped with Ce"3"+ and Tb"3"+ phosphors were prepared by high temperature solid state synthesis. Phase purity of the powders was checked by X-ray powder diffraction. Luminescence and excitation spectra of samples were reported. In particular, the interaction mechanism between Eu"3"+ ions was investigated in terms of the Inokuti–Hirayama model; it was found that the interactions between Eu"3"+ can be assigned to dipole–dipole interaction. K_3Gd_5(PO_4)_6:Eu"3"+ could act as a candidate for solid state lighting due to its strong absorption band in the near-UV region (350–400 nm). The energy transfer from Ce"3"+ to Tb"3"+ was confirmed and the mechanism was studied using Dexter's theory; it is concluded that electric dipole–dipole interaction predominates in the energy transfer process from Ce"3"+ to Tb"3"+ in the K_3Gd_5(PO_4)_6 host. The energy transfer efficiency and critical distance were also investigated. - Highlights: • Optical properties of K_3Gd_5(PO_4)_6:RE"3"+ are investigated for the first time. • The interaction mechanism between Eu"3"+ ions is attributed to dipole–dipole type. • K_3Eu_5(PO_4)_6 is a candidate phosphor for application to solid state lighting. • There exists an efficient energy transfer from Ce"3"+ to Tb"3"+ (η is up to 95%). • The mechanism of energy transfer process is electric dipole–dipole interaction.

Post-Enlargement Intra-EU Labour Mobility Under Stress Test

DEFF Research Database (Denmark)

Galgóczi, Béla; Leschke, Janine

2014-01-01

Freedom of movement for persons and workers is undoubtedly one of the core values and main building blocks of the EU. This paper examines a number of its aspects that have important political and institutional relevance for the EU and its future.......Freedom of movement for persons and workers is undoubtedly one of the core values and main building blocks of the EU. This paper examines a number of its aspects that have important political and institutional relevance for the EU and its future....

Insight into Eu redox and Pr

NARCIS (Netherlands)

Zhou, Rongfu; Lin, Litian; Liu, Chunmeng; Dorenbos, P.; Tao, Ye; Huang, Yan; Liang, Hongbin

2018-01-01

A series of Ln-doped KSrPO₄ (Ln = Ce³⁺, Eu³⁺, Eu²⁺, Pr³⁺) phosphors are prepared through a high-temperature solid-state method. The KSrPO₄ compound is confirmed to possess a β-K₂SO₄ structure with the Pnma

Tunable Yellow-Red Photoluminescence and Persistent Afterglow in Phosphors Ca4LaO(BO3)3:Eu3+ and Ca4EuO(BO3)3.

Science.gov (United States)

Chen, Zhen; Pan, Yuexiao; Xi, Luqing; Pang, Ran; Huang, Shaoming; Liu, Guokui

2016-11-07

In most Eu 3+ activated phosphors, only red luminescence from the 5 D 0 is obtainable, and efficiency is limited by concentration quenching. Herein we report a new phosphor of Ca 4 LaO(BO 3 ) 3 :Eu 3+ (CLBO:Eu) with advanced photoluminescence properties. The yellow luminescence emitted from the 5 D 1,2 states is not thermally quenched at room temperature. The relative intensities of the yellow and red emission bands depend strongly on the Eu 3+ doping concentration. More importantly, concentration quenching of Eu 3+ photoluminescence is absent in this phosphor, and the stoichiometric compound of Ca 4 EuO(BO 3 ) 3 emits stronger luminescence than the Eu 3+ doped compounds of CLBO:Eu; it is three times stronger than that of a commercial red phosphor of Y 2 O 3 :Eu 3+ . Another beneficial phenomenon is that ligand-to-metal charge transfer (CT) transitions occur in the long UV region with the lowest charge transfer band (CTB) stretched down to about 3.67 eV (∼330 nm). The CT transitions significantly enhance Eu 3+ excitation, and thus result in stronger photoluminescence and promote trapping of excitons for persistent afterglow emission. Along with structure characterization, optical spectra and luminescence dynamics measured under various conditions as a function of Eu 3+ doping, temperature, and excitation wavelength are analyzed for a fundamental understanding of electronic interactions and for potential applications.

Correlation between electronic structure and energy band in Eu-doped CuInTe2 semiconductor compound with chalcopyrite structure

Institute of Scientific and Technical Information of China (English)

Tai Wang; Yong-Quan Guo; Shuai Li

2017-01-01

The Eu-doped Cu(In,Eu)Te2 semiconductors with chalcopyrite structures are promising materials for their applications in the absorption layer for thin-film solar cells due to their wider band-gaps and better optical properties than those of CulnTe2.In this paper,the Eu-doped CulnTe2 (Culn1-xEuxTe2,x =0,0.1,0.2,0.3) are studied systemically based on the empirical electron theory (EET).The studies cover crystal structures,bonding regularities,cohesive energies,energy levels,and valence electron structures.The theoretical values fit the experimental results very well.The physical mechanism of a broadened band-gap induced by Eu doping into CuInTe2 is the transitions between different hybridization energy levels induced by electron hopping between s and d orbitals and the transformations from the lattice electrons to valence electrons for Cu and In ions.The research results reveal that the photovoltaic effect induces the increase of lattice electrons of In and causes the electric resistivity to decrease.The Eu doping into CuInTe2 mainly influences the transition between different hybridization energy levels for Cu atoms,which shows that the 3d electron numbers of Cu atoms change before and after Eu doping.In single phase CuIn1-xEuxTe2,the number of valence electrons changes regularly with increasing Eu content,and the calculated band gap Eg also increases,which implies that the optical properties of Eu-doped CuIn1-xEuxTe2 are improved.

Sr(1.7)Zn(0.3)CeO4: Eu3+ novel red-emitting phosphors: synthesis and photoluminescence properties.

Science.gov (United States)

Li, Haifeng; Zhao, Ran; Jia, Yonglei; Sun, Wenzhi; Fu, Jipeng; Jiang, Lihong; Zhang, Su; Pang, Ran; Li, Chengyu

2014-03-12

A series of novel red-emitting Sr1.7Zn0.3CeO4:Eu(3+) phosphors were synthesized through conventional solid-state reactions. The powder X-ray diffraction patterns and Rietveld refinement verified the similar phase of Sr1.7Zn0.3CeO4:Eu(3+) to that of Sr2CeO4. The photoluminescence spectrum exhibits that peak located at 614 nm ((5)D0-(7)F2) dominates the emission of Sr1.7Zn0.3CeO4:Eu(3+) phosphors. Because there are two regions in the excitation spectrum originating from the overlap of the Ce(4+)-O(2-) and Eu(3+)-O(2-) charge-transfer state band from 200 to 440 nm, and from the intra-4f transitions at 395 and 467 nm, the Sr1.7Zn0.3CeO4:Eu(3+) phosphors can be well excited by the near-UV light. The investigation of the concentration quenching behavior, luminescence decay curves, and lifetime implies that the dominant mechanism type leading to concentration quenching is the energy transfer among the nearest neighbor or next nearest neighbor activators. The discussion about the dependence of photoluminescence spectra on temperature shows the better thermal quenching properties of Sr1.7Zn0.3CeO4:0.3Eu(3+) than that of Sr2CeO4:Eu(3+). The experimental data indicates that Sr1.7Zn0.3CeO4:Eu(3+) phosphors have the potential as red phosphors for white light-emitting diodes.

Energy transfer in M₅(PO₄)₃  F:Eu²⁺,Ce³⁺ (M = Ca and Ba) phosphors.

Science.gov (United States)

Shinde, K N; Dhoble, S J

2014-08-01

M5(PO4)3F:Eu(2+) (M = Ca and Ba) co-doped with Ce(3+) phosphors were successfully prepared by the combustion synthesis method. The introduction of co-dopant (Ce(3+)) into the host enhanced the luminescent intensity of the M5(PO4)3F:Eu(2+) (M = Ca and Ba) efficiently. Previously, we have reported the synthesis and photoluminescence properties of same phosphors. The aim of this article is to report energy transfer mechanism between Ce(3+) ➔Eu(2+) ions in M5(PO4)3F:Eu(2+) (M = Ca and Ba) phosphors, where Ce(3+) ions act as sensitizers and Eu(2+) ions act as activators. The M5(PO4)3F:Eu(2+) (M = Ca and Ba) co-doped with Ce(3+) phosphor exhibits great potential for use in white ultraviolet (UV) light-emitting diode applications to serve as a single-phased phosphor that can be pumped with near-UV or UV light-emitting diodes. Copyright © 2013 John Wiley & Sons, Ltd.

Impact of Transposition of the Directive 2013/34/EU into the National Laws of EU Member States Emphatically V4

Directory of Open Access Journals (Sweden)

Jana Gláserová

2017-01-01

Full Text Available The European Union has published the Directive 2013/34/EU of the European Parliament and of the Council of 26 June 2013 on the annual financial statements, consolidated financial statements and related reports of certain types of undertakings for reasons of increasing of the competitive advantage and productivity of small and medium‑sized enterprises. The EU Member States have to incorporate the rules of the Directive with their national law by 20 July 2015 at the latest during the year 2016. The intention of this paper is to determine and to evaluate the impacts of transposition of the Directive into the Czech Accounting Law and into the national accounting laws of EU Member States chosen. There is an identification of main differences of Czech Accounting Law and of amended Czech Accounting Law issued 1st of January 2016. There is an impact of implementation of the Directive 2013/34/EU on financial statements and at the same time on requirements of audit for individual categories of Czech accounting entities. In this paper, there is also an analysis of impact of the Directive 2013/34/EU on national accounting laws V4 States and on several further EU Member States. On the basis of comparison of differences recognized, there is an deduction of findings for companies falling into the same group.

Yb3+,Er3+,Eu3+-codoped YVO4 material for bioimaging with dual mode excitation

International Nuclear Information System (INIS)

Thao, Chu Thi Bich; Huy, Bui The; Sharipov, Mirkomil; Kim, Jin-Ik.; Dao, Van-Duong; Moon, Ja-Young; Lee, Yong-Ill

2017-01-01

We propose an efficient bioimaging strategy using Yb 3+ ,Er 3+ ,Eu 3+ -triplet doped YVO 4 nanoparticles which were synthesized with polymer as a template. The obtained particles possess nanoscale, uniform, and flexible excitation. The effect of Eu 3+ ions on the luminescence properties of YVO 4 :Yb 3+ ,Er 3+ ,Eu 3+ was investigated. The upconversion mechanism of the prepared material was also discussed. The structure and optical properties of the prepared material were characterized by using X-ray diffraction (XRD), Fourier-transform IR spectroscopy (FTIR), scanning electron microscopy (SEM), Transmission electron microscopy (TEM) upconversion and photoluminescence spectra. The Commission International de I′Eclairage (CIE) chromaticity coordinates was investigated to confirm the performance of color luminescent emission. The prepared YVO 4 :Yb 3+ ,Er 3+ ,Eu 3+ nanoparticles could be easily dispersed in water by surface modification with cysteine (Cys) and glutathione (GSH). The aqueous dispersion of the modified YVO 4 :Yb 3+ ,Er 3+ ,Eu 3+ exhibits bright upconversion and downconversion luminescence and has been applied for bioimaging of HeLa cells. Our developed material with dual excitation offers a promising advance in bioimaging. - Highlights: • Prepared particles possess nanoscale size, uniform, and larger scale. • The material exhibits strong emission under dual mode excitations. • The surface material has been applied for bioimaging of HeLa cell. • Low cytotoxicity, no auto-fluorescence

Selective separation of Eu3+ using polymer-enhanced ultrafiltration

International Nuclear Information System (INIS)

Norton, M.V.

1994-03-01

A process to selectively remove 241 Am from liquid radioactive waste was investigated as an actinide separation method applicable to Hanford and other waste sites. The experimental procedures involved removal of Eu, a nonradioactive surrogate for Am, from aqueous solutions at pH 5 using organic polymers in conjunction with ultrafiltration. Commercially available polyacrylic acid (60,000 MW) and Pacific Northwest Laboratory's (PNL) synthesized E3 copolymer (∼10,000 MW) were tested. Test solutions containing 10 μg/mL of Eu were dosed vath each polymer at various concentrations in order to bind Eu (i.e., by complexation and/or cation exchange) for subsequent rejection by an ultrafiltration coupon. Test solutions were filtered with and without polymer to determine if enhanced Eu separation could be achieved from polymer treatment. Both polymers significantly increased Eu removal. Optimum concentrations were 20 μg/mL of polyacrylic acid and 100 μg/mL of E3 for 100% Eu rejection by the Amicon PM10 membrane at 55 psi. In addition to enhancement of removal, the polymers selectively bound Eu over Na, suggesting that selective separation of Eu was possible. This suggests that polymer-enhanced ultrafiltration is a potential process for separation of 241 Am from Hanford tank waste, further investigation of binding agents and membranes effective under very alkaline and high ionic strength is warranted. This process also has potential applications for selective separation of toxic metals from industrial process streams

Solar Energy: Incentives to Promote PV in EU27

Directory of Open Access Journals (Sweden)

María del P. Pablo-Romero

2013-11-01

Full Text Available The growth in the use of renewable energies in the EU has been remarkable. Among these energies is PV. The average annual growth rate for the EU-27 countries in installed PV capacity in the period 2005-2012 was 41.2%. While the installed capacity of PV has reached almost 82 % of National Renewable Energy Action Plan (NREAP targets for the EU-27 countries for 2020, it is still far from being used at its full potential. Over recent years, several measures have been adopted in the EU to enhance and promote PV. This paper undertakes a complete review of the state of PV power in Europe and the measures taken to date to promote it in EU-27. 25 countries have adopted measures to promote PV. The most widespread measure to promote PV use is Feed- in Tariffs. Tariffs are normally adjusted, in a decreasing manner, annually. Nevertheless, currently, seven countries have decided to accelerate this decrease rate in view of cost reduction of the installations and of higher efficiencies. The second instrument used to promote PV in the EU-27 countries is the concession of subsidies. Nevertheless, subsidies have the disadvantage of being closely linked to budgetary resources and therefore to budgetary constraints. In most EU countries, subsidies for renewable energy for PV are being lowered. Twelve EU-27 countries adopted tax measures. Low-interest loans and green certificate systems were only sparingly used.

Google and the search for a theory of harm

DEFF Research Database (Denmark)

Bergqvist, Christian

2018-01-01

The Commission has published its June 2017 Google decision, thus exposing it to scrutiny. While the work undertaken by the EU Commission is impressive and bold, much of the legal dimension of the decision bears discussion. Moreover, the case has been redacted significantly, thus leaving open...

The "New Politics" of EU's Eastern Enlargement

DEFF Research Database (Denmark)

Zank, Wolfgang

The paper gives an overview of EU's eastern enlargement and draws some theoretical conclusions. In particular, it stresses the point that the EU member states in the process of enlargement have entered a phase of "new politics", characterised by multilateralism, conditionality, help and binding...

Copper tolerance in Frankia sp. strain EuI1c involves surface binding and copper transport.

Science.gov (United States)

Rehan, Medhat; Furnholm, Teal; Finethy, Ryan H; Chu, Feixia; El-Fadly, Gomaah; Tisa, Louis S

2014-09-01

Several Frankia strains have been shown to be copper-tolerant. The mechanism of their copper tolerance was investigated for Frankia sp. strain EuI1c. Copper binding was shown by binding studies. Unusual globular structures were observed on the surface of the bacterium. These globular structures were composed of aggregates containing many relatively smaller "leaf-like" structures. Scanning electron microscopy with energy-dispersive X-ray (SEM-EDAX) analysis of these structures indicated elevated copper and phosphate levels compared to the control cells. Fourier transform infrared spectroscopy (FTIR) analysis indicated an increase in extracellular phosphate on the cell surface of copper-stressed cells. Bioinformatics' analysis of the Frankia sp. strain EuI1c genome revealed five potential cop genes: copA, copZ, copC, copCD, and copD. Experiments with Frankia sp. strain EuI1c using qRT-PCR indicated an increase in messenger RNA (mRNA) levels of the five cop genes upon Cu(2+) stress. After 5 days of Cu(2+) stress, the copA, copZ, copC, copCD, and copD mRNA levels increased 25-, 8-, 18-, 18-, and 25-fold, respectively. The protein profile of Cu(2+)-stressed Frankia sp. strain EuI1c cells revealed the upregulation of a 36.7 kDa protein that was identified as FraEuI1c_1092 (sulfate-binding periplasmic transport protein). Homologues of this gene were only present in the genomes of the Cu(2+)-resistant Frankia strains (EuI1c, DC12, and CN3). These data indicate that copper tolerance by Frankia sp. strain EuI1c involved the binding of copper to the cell surface and transport proteins.

THE CRUCIAL THEMES OF EU ENLARGEMENT

Directory of Open Access Journals (Sweden)

Jacques Pelkmans

2001-12-01

Full Text Available This article provides a critical review of the “terms” of the ongoing EU enlargement, in the light of the European public interest. The European public interest ought to include the prospective (Central European members, within a perspective of an enlarged Union in 2010, or so. The following forms a personalised summary of a major report published (in Dutch in September 2001 by the WRR in The Hague (a think-tank, formally under the Dutch Prime Minister, but by statute fully independent. The author was one of the lead-writers of this report. The present article merely focuses on the policy recommendations of the report. It is hoped that these kinds of critical analyses will help to stimulate solid policy debate on the EU in Romania, on the road to EU membership. The article discusses why the notion of a “core-acquis” would improve the enlargement strategy; the application of the core acquis to the internal market, environment and justice and home affairs; judicial and administrative capacity; accession to “euro-land”; the rapid reform of the CAP; a reform of “cohesion” approaches; and a note on the EU budgetary implications.

EU ecodesign regulation. More as only a light bulb ban; EU-Oekodesign-Richtlinie. Mehr als ein Gluehbirnenverbot

Energy Technology Data Exchange (ETDEWEB)

Fischer, Corinna [Oeko-Institut e.V., Freiburg (Germany)

2011-10-15

Within a broader public, the EU Ecodesign Directive (Directive 2009/125/EC) was known and notoriously as a 'light bulb ban'. This resulted in strong emotions. But it has shown an impact in many other areas - usually unnoticed and often for the financial and practical benefits of the consumers. Now, the EU Commission wants to go one step further.

The EU sustainable energy policy indicators framework.

Science.gov (United States)

Streimikiene, Dalia; Sivickas, Gintautas

2008-11-01

The article deals with indicators framework to monitor implementation of the main EU (European Union) directives and other policy documents targeting sustainable energy development. The main EU directives which have impact on sustainable energy development are directives promoting energy efficiency and use of renewable energy sources, directives implementing greenhouse gas mitigation and atmospheric pollution reduction policies and other policy documents and strategies targeting energy sector. Promotion of use of renewable energy sources and energy efficiency improvements are among priorities of EU energy policy because the use of renewable energy sources and energy efficiency improvements has positive impact on energy security and climate change mitigation. The framework of indicators can be developed to establish the main targets set by EU energy and environmental policies allowing to connect indicators via chain of mutual impacts and to define policies and measures necessary to achieve established targets based on assessment of their impact on the targeted indicators representing sustainable energy development aims. The article discusses the application of indicators framework for EU sustainable energy policy analysis and presents the case study of this policy tool application for Baltic States. The article also discusses the use of biomass in Baltic States and future considerations in this field.

INTEGRATION OF ROMANIAN INSURANCES MARKET IN EU

Directory of Open Access Journals (Sweden)

Gheorghe MOROŞAN

2015-08-01

Full Text Available One of the most important phenomena of the last decade has been the convergence of the financial services industry, especially the capital and insurance markets. The convergence in the insurance industry was determined by the increased frequency and the severity of catastrophic risks, market inefficiency in the past, and the new technologies in IT and communications. These globally developments can be observed much better at EU level, one of the most integrated areas of the world, which aimed the convergence of financial market, including an important component such as insurance market. As part of the EU, Romania also aims to financial market convergence with the EU countries. The article offers an overview and an analysis of the insurance market in the EU and Romania. Through a wide series of indicators such as: the amount of insurance premiums, degree of penetration, number of employees or number of insurance companies, it will analyze the evolution of this market convergence, as per all EU countries and Romania. It will identify the stage in which the insurance market in Romania is, regarding the requirements of full integration. Finally, there will be identified factors encouraging and particularly those who are impediments to insurance market convergence in Romania.

Lattice dynamic studies from {sup 151}Eu-Moessbauer spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Katada, Motomi [Tokyo Metropolitan Univ., Hachioji (Japan). Faculty of Science

1997-03-01

New complexes {l_brace}(Eu(napy){sub 2}(H{sub 2}O){sub 3})(Fe(CN){sub 6})4H{sub 2}O{r_brace}{sub x}, bpy({l_brace}(Eu(bpy)(H{sub 2}O){sub 4})(Fe(CN){sub 6})1.5bpy4H{sub 2}O{r_brace}{sub x}) and ({l_brace}(Eu(phen){sub 2}(H{sub 2}O){sub 2})(Fe(CN){sub 6})2phen{r_brace}{sub x}) etc were synthesized using phenanthroline and bipyridine. Lattice dynamic behaviors of Eu and Fe atom in the complexes were investigated by Moessbauer spectroscopy. By {sup 151}Eu-Moessbauer spectrum and parameters of new complexes, bpy complex showed the largest quadrupole splitting value, indicating bad symmetry of Eu ligand in the environment. Molecular structure of napy, bpy and phen complex were shown. These complexes are consisted of Eu atom coordinated with ligand and water molecule, of which (Fe(CN){sub 6}){sup 3-} ion formed one dimentional polymer chain and naphthyridines formed stacking structure. New complexes were observed by {sup 57}Fe-Moessbauer spectroscopy, too. The quadrupole splitting values were very different each other, indicating change of symmetry of Fe atom in the environment and three valence low spin state of Fe in the complex. (S.Y.)

Removing EU milk quotas, soft landing versus hard landing

NARCIS (Netherlands)

Bouamra-Mechemache, Z.; Jongeneel, R.; Réquillart, V.

2008-01-01

This paper analyses EU dairy policy reforms and mainly focus on EU milk quota removal scenarios. The model used to evaluate the scenario is a spatial equilibrium model of the dairy sector. It integrates the main competitor of the EU on world markets, Oceania, as well as the main importing regions in

Site and local structure of activator Eu{sup 2+} in phosphor Ca{sub 10−x}(PO{sub 4}){sub 6}Cl{sub 2}:xEu{sup 2+}

Energy Technology Data Exchange (ETDEWEB)

Wang, Chun-Hai, E-mail: chwang81@gmail.com [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, Mianyang 621900 (China); Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); School of Physics, Peking University, Beijing 100871 (China); Gui, Dong-Yun; Qin, Rui [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, Mianyang 621900 (China); Yang, Feng-Li [Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Jing, Xi-Ping, E-mail: xpjing@pku.edu.cn [Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Tian, Guang-Shan [School of Physics, Peking University, Beijing 100871 (China); Zhu, Wenjun [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, Mianyang 621900 (China)

2013-10-15

The site and local structure of activator Eu{sup 2+} in phosphor Ca{sub 10−x}(PO{sub 4}){sub 6}Cl{sub 2}:xEu{sup 2+} is investigated by experiment measurements, first-principle calculations and XAFS simulations. From first-principle calculations, the “local” structure [bond length L(M–O)≤R(M{sup 2+})+R(O{sup 2−})] of host shows a significant deformation (expansion) when Ca{sup 2+} is substituted by Eu{sup 2+}, and Eu{sup 2+} should prefer 6h site to 4f site in the host. The d→f emission of Eu{sup 2+} at 4f site should show a longer wavelength than that of Eu{sup 2+} at 6h site. The XAFS measurement and simulations suggest that the Eu{sup 2+} in our Ca{sub 9.9}(PO{sub 4}){sub 6}Cl{sub 2}:0.1Eu{sup 2+} sample mainly locates at 6h site. In the emission spectrum, two emission profiles of Ca{sub 9.9}(PO{sub 4}){sub 6}Cl{sub 2}:0.1Eu{sup 2+} sample are obtained and assigned. The major one (2.71 eV≈456 nm) should be the emission of Eu{sup 2+} at 6h site. The minor one (2.61 eV≈465 nm) should be that of Eu{sup 2+} at 4f site. - Graphical abstract: The d→f emission of Eu{sup 2+} in Ca{sub 9.9}(PO{sub 4}){sub 6}Cl{sub 2}:0.1Eu{sup 2+} can be assigned as: emission profile at 2.71 eV and 2.61 eV are Eu{sup 2+} at 6h and 4f site, respectively. Display Omitted - Highlights: • Eu{sup 2+} in Ca{sub 10−x}(PO{sub 4}){sub 6}Cl{sub 2}:xEu{sup 2+} causes deformation to “local” structure. • Eu{sup 2+} should prefer 6h site to 4f site in the host from energy aspect. • Emission at 2.71 eV and 2.61 eV should be Eu{sup 2+} at 6h and 4f site.