WorldWideScience

Sample records for estimating air emissions

  1. Urban scale air quality modelling using detailed traffic emissions estimates

    Science.gov (United States)

    Borrego, C.; Amorim, J. H.; Tchepel, O.; Dias, D.; Rafael, S.; Sá, E.; Pimentel, C.; Fontes, T.; Fernandes, P.; Pereira, S. R.; Bandeira, J. M.; Coelho, M. C.

    2016-04-01

    The atmospheric dispersion of NOx and PM10 was simulated with a second generation Gaussian model over a medium-size south-European city. Microscopic traffic models calibrated with GPS data were used to derive typical driving cycles for each road link, while instantaneous emissions were estimated applying a combined Vehicle Specific Power/Co-operative Programme for Monitoring and Evaluation of the Long-range Transmission of Air Pollutants in Europe (VSP/EMEP) methodology. Site-specific background concentrations were estimated using time series analysis and a low-pass filter applied to local observations. Air quality modelling results are compared against measurements at two locations for a 1 week period. 78% of the results are within a factor of two of the observations for 1-h average concentrations, increasing to 94% for daily averages. Correlation significantly improves when background is added, with an average of 0.89 for the 24 h record. The results highlight the potential of detailed traffic and instantaneous exhaust emissions estimates, together with filtered urban background, to provide accurate input data to Gaussian models applied at the urban scale.

  2. Estimating air emissions from a remediation of a petroleum sump using direct measurement and modeling

    International Nuclear Information System (INIS)

    Schmidt, C.E.

    1991-01-01

    A technical approach was developed for the remediation of a petroleum sump near a residential neighborhood. The approach evolved around sludge handling/in-situ solidification and on-site disposal. As part of the development of the engineering approach, a field investigation and modeling program was conducted to predict air emissions from the proposed remediation. Field measurements using the EPA recommended surface isolation flux chamber were conducted to represent each major activity or air exposure involving waste at the site. Air emissions from freshly disturbed petroleum waste, along with engineering estimates were used to predict emissions from each phase of the engineering approach. This paper presents the remedial approach and the measurement/modeling technologies used to predict air toxic emissions from the remediation. Emphasis will be placed on the measurement approaches used in obtaining the emission rate data and the assumptions used in the modeling to estimate emissions from engineering scenarios

  3. A model for the estimation of energy consumption and air pollutant emissions from rail transport

    DEFF Research Database (Denmark)

    Lindgreen, Erik Bjørn Grønning; Sorenson, Spencer C

    2003-01-01

    A model is presented for the calculation of energy consumption and air pollutant emissions from rail transport. It is based on the estimation of energy consumption from a matirx describing the distribution of speeds and accelerations for operation. It is shown that calculations can be performed...

  4. Improved Rice Residue Burning Emissions Estimates: Accounting for Practice-Specific Emission Factors in Air Pollution Assessments of Vietnam

    Science.gov (United States)

    Lasko, Kristofer; Vadrevu, Krishna

    2018-01-01

    In Southeast Asia and Vietnam, rice residues are routinely burned after the harvest to prepare fields for the next season. Specific to Vietnam, the two prevalent burning practices include: a). piling the residues after hand harvesting; b). burning the residues without piling, after machine harvesting. In this study, we synthesized field and laboratory studies from the literature on rice residue burning emission factors for Particulate Matter less than 2.5 microns (PM2.5). We found significant differences in the resulting burning-practice specific emission factors, with 16.9 grams per square kilogram (plus or minus 6.9) for pile burning and 8.8 grams per square kilogram (plus or minus 3.5) for non-pile burning. We calculated burning practice specific emissions based on rice area data, region-specific fuel-loading factors, combined emission factors, and estimates of burning from the literature. Our results for year 2015 estimate 180 gigagrams of PM2.5 result from the pile burning method and 130 gigagrams result from non-pile burning method, with the most-likely current emission scenario of 150 gigagrams PM2.5 emissions for Vietnam. For comparison purposes, we calculated emissions using generalized agricultural emission factors employed in global biomass burning studies. These results estimate 80 gigagrams PM2.5, which is only 44 percent of the pile burning-based estimates, suggesting underestimation in previous studies. We compare our emissions to an existing all-combustion sources inventory, results show emissions account for 14-18 percent of Vietnam's total PM2.5 depending on burning practice. Within the highly-urbanized and cloud-covered Hanoi Capital region (HCR), we use rice area from Sentinel-1A to derive spatially-explicit emissions and indirectly estimate residue burning dates. Results from HYSPLIT (Hybrid Single-Particle Lagrangian Integrated Trajectory) back-trajectory analysis stratified by season show autumn has most emission trajectories originating in

  5. Radiation dose estimates due to air particulate emissions from selected phosphate industry operations

    International Nuclear Information System (INIS)

    Partridge, J.E.; Horton, T.R.; Sensintaffar, E.L.; Boysen, G.A.

    1978-06-01

    The EPA Office of Radiation Programs has conducted a series of studies to determine the radiological impact of the phosphate mining and milling industry. This report describes the efforts to estimate the radiation doses due to airborne emissions of particulates from selected phosphate milling operations in Florida. Two wet process phosphoric acid plants and one ore drying facility were selected for this study. The 1976 Annual Operations/Emissions Report, submitted by each facility to the Florida Department of Environmental Regulation, and a field survey trip by EPA personnel to each facility were used to develop data for dose calculations. The field survey trip included sampling for stack emissions and ambient air samples collected in the general vicinity of each plant. Population and individual radiation dose estimates are made based on these sources of data

  6. Modeling air pollutant emissions from Indian auto-rickshaws: Model development and implications for fleet emission rate estimates

    Science.gov (United States)

    Grieshop, Andrew P.; Boland, Daniel; Reynolds, Conor C. O.; Gouge, Brian; Apte, Joshua S.; Rogak, Steven N.; Kandlikar, Milind

    2012-04-01

    Chassis dynamometer tests were conducted on 40 Indian auto-rickshaws with 3 different fuel-engine combinations operating on the Indian Drive Cycle (IDC). Second-by-second (1 Hz) data were collected and used to develop velocity-acceleration look-up table models for fuel consumption and emissions of CO2, CO, total hydrocarbons (THC), oxides of nitrogen (NOx) and fine particulate matter (PM2.5) for each fuel-engine combination. Models were constructed based on group-average vehicle activity and emissions data in order to represent the performance of a 'typical' vehicle. The models accurately estimated full-cycle emissions for most species, though pollutants with more variable emission rates (e.g., PM2.5) were associated with larger errors. Vehicle emissions data showed large variability for single vehicles ('intra-vehicle variability') and within the test group ('inter-vehicle variability'), complicating the development of a single model to represent a vehicle population. To evaluate the impact of this variability, sensitivity analyses were conducted using vehicle activity data other than the IDC as model input. Inter-vehicle variability dominated the uncertainty in vehicle emission modeling. 'Leave-one-out' analyses indicated that the model outputs were relatively insensitive to the specific sample of vehicles and that the vehicle samples were likely a reasonable representation of the Delhi fleet. Intra-vehicle variability in emissions was also substantial, though had a relatively minor impact on model performance. The models were used to assess whether the IDC, used for emission factor development in India, accurately represents emissions from on-road driving. Modeling based on Global Positioning System (GPS) activity data from real-world auto-rickshaws suggests that, relative to on-road vehicles in Delhi, the IDC systematically under-estimates fuel use and emissions; real-word auto-rickshaws consume 15% more fuel and emit 49% more THC and 16% more PM2.5. The models

  7. Estimating criteria pollutant emissions using the California Regional Multisector Air Quality Emissions (CA-REMARQUE model v1.0

    Directory of Open Access Journals (Sweden)

    C. B. Zapata

    2018-04-01

    Full Text Available The California Regional Multisector Air Quality Emissions (CA-REMARQUE model is developed to predict changes to criteria pollutant emissions inventories in California in response to sophisticated emissions control programs implemented to achieve deep greenhouse gas (GHG emissions reductions. Two scenarios for the year 2050 act as the starting point for calculations: a business-as-usual (BAU scenario and an 80 % GHG reduction (GHG-Step scenario. Each of these scenarios was developed with an energy economic model to optimize costs across the entire California economy and so they include changes in activity, fuels, and technology across economic sectors. Separate algorithms are developed to estimate emissions of criteria pollutants (or their precursors that are consistent with the future GHG scenarios for the following economic sectors: (i on-road, (ii rail and off-road, (iii marine and aviation, (iv residential and commercial, (v electricity generation, and (vi biorefineries. Properly accounting for new technologies involving electrification, biofuels, and hydrogen plays a central role in these calculations. Critically, criteria pollutant emissions do not decrease uniformly across all sectors of the economy. Emissions of certain criteria pollutants (or their precursors increase in some sectors as part of the overall optimization within each of the scenarios. This produces nonuniform changes to criteria pollutant emissions in close proximity to heavily populated regions when viewed at 4 km spatial resolution with implications for exposure to air pollution for those populations. As a further complication, changing fuels and technology also modify the composition of reactive organic gas emissions and the size and composition of particulate matter emissions. This is most notably apparent through a comparison of emissions reductions for different size fractions of primary particulate matter. Primary PM2.5 emissions decrease by 4 % in the GHG

  8. Estimating criteria pollutant emissions using the California Regional Multisector Air Quality Emissions (CA-REMARQUE) model v1.0

    Science.gov (United States)

    Zapata, Christina B.; Yang, Chris; Yeh, Sonia; Ogden, Joan; Kleeman, Michael J.

    2018-04-01

    The California Regional Multisector Air Quality Emissions (CA-REMARQUE) model is developed to predict changes to criteria pollutant emissions inventories in California in response to sophisticated emissions control programs implemented to achieve deep greenhouse gas (GHG) emissions reductions. Two scenarios for the year 2050 act as the starting point for calculations: a business-as-usual (BAU) scenario and an 80 % GHG reduction (GHG-Step) scenario. Each of these scenarios was developed with an energy economic model to optimize costs across the entire California economy and so they include changes in activity, fuels, and technology across economic sectors. Separate algorithms are developed to estimate emissions of criteria pollutants (or their precursors) that are consistent with the future GHG scenarios for the following economic sectors: (i) on-road, (ii) rail and off-road, (iii) marine and aviation, (iv) residential and commercial, (v) electricity generation, and (vi) biorefineries. Properly accounting for new technologies involving electrification, biofuels, and hydrogen plays a central role in these calculations. Critically, criteria pollutant emissions do not decrease uniformly across all sectors of the economy. Emissions of certain criteria pollutants (or their precursors) increase in some sectors as part of the overall optimization within each of the scenarios. This produces nonuniform changes to criteria pollutant emissions in close proximity to heavily populated regions when viewed at 4 km spatial resolution with implications for exposure to air pollution for those populations. As a further complication, changing fuels and technology also modify the composition of reactive organic gas emissions and the size and composition of particulate matter emissions. This is most notably apparent through a comparison of emissions reductions for different size fractions of primary particulate matter. Primary PM2.5 emissions decrease by 4 % in the GHG-Step scenario vs

  9. Actual car fleet emissions estimated from urban air quality measurements and street pollution models

    International Nuclear Information System (INIS)

    Palmgren, F.; Berkowicz, R.; Hertel, O.; Ziv, A.

    1999-01-01

    A method to determine emissions from the actual car fleet under realistic driving conditions has been developed. The method is based on air quality measurements, traffic counts and inverse application of street air quality models. Many pollutants are of importance for assessing the adverse impact of the air pollution, e.g. NO 2 , CO, lead, VOCs and particulate matter. Aromatic VOCs are of special great concern due to their adverse health effects. Measurements of benzene, toluene and xylenes were carried out in central Copenhagen since 1994. Significant correlation was observed between VOCs and CO concentrations, indicating that the petrol engine vehicles are the major sources of VOC air pollution in central Copenhagen. Hourly mean concentrations of benzene were observed to reach values of up to 20 ppb, what is critically high according to the WHOs recommendations. Based on inverse model calculation of dispersion of pollutants in street canyons, an average emission factor of benzene for the fleet of petrol fuelled vehicles was estimated to be 0.38 g/km in 1994 and 0.11 in 1997. This decrease was caused by the reduction of benzene content in Danish petrol since summer 1995 and increasing percentage of cars equipped with three-way catalysts. The emission factors for benzene for diesel-fuelled vehicles were low

  10. International trade and air pollution: estimating the economic costs of air emissions from waterborne commerce vessels in the United States.

    Science.gov (United States)

    Gallagher, Kevin P

    2005-10-01

    Although there is a burgeoning literature on the effects of international trade on the environment, relatively little work has been done on where trade most directly effects the environment: the transportation sector. This article shows how international trade is affecting air pollution emissions in the United States' shipping sector. Recent work has shown that cargo ships have been long overlooked regarding their contribution to air pollution. Indeed, ship emissions have recently been deemed "the last unregulated source of traditional air pollutants". Air pollution from ships has a number of significant local, national, and global environmental effects. Building on past studies, we examine the economic costs of this increasing and unregulated form of environmental damage. We find that total emissions from ships are largely increasing due to the increase in foreign commerce (or international trade). The economic costs of SO2 pollution range from dollars 697 million to dollars 3.9 billion during the period examined, or dollars 77 to dollars 435 million on an annual basis. The bulk of the cost is from foreign commerce, where the annual costs average to dollars 42 to dollars 241 million. For NOx emissions the costs are dollars 3.7 billion over the entire period or dollars 412 million per year. Because foreign trade is driving the growth in US shipping, we also estimate the effect of the Uruguay Round on emissions. Separating out the effects of global trade agreements reveals that the trade agreement-led emissions amounted to dollars 96 to dollars 542 million for SO2 between 1993 and 2001, or dollars 10 to dollars 60 million per year. For NOx they were dollars 745 million for the whole period or dollars 82 million per year. Without adequate policy responses, we predict that these trends and costs will continue into the future.

  11. Emission Facilities - Air Emission Plants

    Data.gov (United States)

    NSGIC Education | GIS Inventory — Represents the Primary Facility type Air Emission Plant (AEP) point features. Air Emissions Plant is a DEP primary facility type related to the Air Quality Program....

  12. Uncertainties in emission estimates of greenhouse gases and air pollutants in China and India and their impacts on regional air quality

    Science.gov (United States)

    Saikawa, E.; Trail, M.; Young, C. L.; Zhong, M.; Avramov, A.; Kim, H.; Wu, Q.; Janssens-Maenhout, G. G. A.; Kurokawa, J. I.; Klimont, Z.; Wagner, F.; Naik, V.; Horowitz, L. W.; Zhao, Y.; Nagpure, A.; Gurjar, B.; Zhang, Q.

    2017-12-01

    Greenhouse gas and air pollutant precursor emissions have been increasing rapidly in both China and India, resulting in local to regional scale effects on air quality. Modelers use emission inventories to represent the temporal and spatial distribution of impacts of air pollutant emissions on regional and global air quality. However, large uncertainties exist in emission inventories. Quantification of uncertainties in emission estimates is essential to better understand the linkages among emissions, air quality, climate, and health. We use Monte Carlo methods to assess the uncertainties of the existing carbon dioxide (CO2), carbon monoxide (CO), sulfur dioxide (SO2), nitrogen oxides (NOx), and particulate matter (PM) emission estimates for both China and India. We focus on the period between 2000 and 2008. In addition to national totals, we also analyze emissions from four source sectors, including industry, transport, power, and residential. We also assess differences in the existing emission estimates within each of the subnational regions. We find large disagreements among the existing inventories at disaggregated levels. We further assess the impact of these differences in emissions on air quality using a chemical transport model. More efforts are needed to constrain emissions, especially in the Indo-Gangetic Plains and in the East and Central regions of China, where large differences across emission inventories result in concomitant large differences in the simulated concentrations of PM and ozone. Our study also highlights the importance of constraining SO2, NOx, and NH3 emissions for secondary PM concentrations over China and India.

  13. Determining the Uncertainties in Prescribed Burn Emissions Through Comparison of Satellite Estimates to Ground-based Estimates and Air Quality Model Evaluations in Southeastern US

    Science.gov (United States)

    Odman, M. T.; Hu, Y.; Russell, A. G.

    2016-12-01

    Prescribed burning is practiced throughout the US, and most widely in the Southeast, for the purpose of maintaining and improving the ecosystem, and reducing the wildfire risk. However, prescribed burn emissions contribute significantly to the of trace gas and particulate matter loads in the atmosphere. In places where air quality is already stressed by other anthropogenic emissions, prescribed burns can lead to major health and environmental problems. Air quality modeling efforts are under way to assess the impacts of prescribed burn emissions. Operational forecasts of the impacts are also emerging for use in dynamic management of air quality as well as the burns. Unfortunately, large uncertainties exist in the process of estimating prescribed burn emissions and these uncertainties limit the accuracy of the burn impact predictions. Prescribed burn emissions are estimated by using either ground-based information or satellite observations. When there is sufficient local information about the burn area, the types of fuels, their consumption amounts, and the progression of the fire, ground-based estimates are more accurate. In the absence of such information satellites remain as the only reliable source for emission estimation. To determine the level of uncertainty in prescribed burn emissions, we compared estimates derived from a burn permit database and other ground-based information to the estimates by the Biomass Burning Emissions Product derived from a constellation of NOAA and NASA satellites. Using these emissions estimates we conducted simulations with the Community Multiscale Air Quality (CMAQ) model and predicted trace gas and particulate matter concentrations throughout the Southeast for two consecutive burn seasons (2015 and 2016). In this presentation, we will compare model predicted concentrations to measurements at monitoring stations and evaluate if the differences are commensurate with our emission uncertainty estimates. We will also investigate if

  14. Air Emissions Guide for Air Force Mobile Sources: Methods for Estimating Emissions of Air Pollutants for Mobile Sources at U.S. Air Force Installations

    Science.gov (United States)

    2013-01-01

    dust, soot, smoke, and droplets formed from chemical reactions and incomplete burning of fuels.  The fine particles can get deep into the lung...Emissions” is undergoing revision to (1) increase consistency with the national inventory of GHG emissions and sinks , (2) incorporate state-level...turbine area, driving the movement of an output shaft that converts the energy to useful power. Typically, more than half of the shaft energy

  15. Estimation of emission adjustments from the application of four-dimensional data assimilation to photochemical air quality modeling

    International Nuclear Information System (INIS)

    Mendoza-Dominguez, A.; Russell, A.G.

    2001-01-01

    Four-dimensional data assimilation applied to photochemical air quality modeling is used to suggest adjustments to the emissions inventory of the Atlanta, Georgia metropolitan area. In this approach, a three-dimensional air quality model, coupled with direct sensitivity analysis, develops spatially and temporally varying concentration and sensitivity fields that account for chemical and physical processing, and receptor analysis is used to adjust source strengths. Proposed changes to domain-wide NO x , volatile organic compounds (VOCs) and CO emissions from anthropogenic sources and for VOC emissions from biogenic sources were estimated, as well as modifications to sources based on their spatial location (urban vs. rural areas). In general, domain-wide anthropogenic VOC emissions were increased approximately two times their base case level to best match observations, domain-wide anthropogenic NO x and biogenic VOC emissions (BEIS2 estimates) remained close to their base case value and domain-wide CO emissions were decreased. Adjustments for anthropogenic NO x emissions increased their level of uncertainty when adjustments were computed for mobile and area sources (or urban and rural sources) separately, due in part to the poor spatial resolution of the observation field of nitrogen-containing species. Estimated changes to CO emissions also suffer from poor spatial resolution of the measurements. Results suggest that rural anthropogenic VOC emissions appear to be severely underpredicted. The FDDA approach was also used to investigate the speciation profiles of VOC emissions, and results warrant revision of these profiles. In general, the results obtained here are consistent with what are viewed as the current deficiencies in emissions inventories as derived by other top-down techniques, such as tunnel studies and analysis of ambient measurements. (Author)

  16. Estimation of Air Pollutant Emissions in Flower Roundabouts and in Conventional Roundabouts

    Directory of Open Access Journals (Sweden)

    Corriere F.

    2013-06-01

    Full Text Available The road pollutant emissions, above all in urban context, are correlated to many infrastructural parameters and to traffic intensity and typology. The research work on road junction geometry, carried out in European research centres, has recently allowed to design new road intersection types which are of undoubted interest, especially in terms of traffic functionality and safety, like the flower roundabouts (in which right-turn manoeuvres do not conflict with the circulating flow. The main objective of this paper is to propose a model for the estimation the capacity, delay, levels of service and the pollutant emissions into flower roundabouts. A comparative analysis between conventional roundabout and flower roundabout has been carried out in terms of CO, CO2, CH4, NO, PM2,5 and PM10 vehicular emissions, evaluated by mean of COPERT Software which is developed as a European tool for the calculation of emissions from the road transport sector.

  17. Air Emission Inventory for the INEEL -- 1999 Emission Report

    Energy Technology Data Exchange (ETDEWEB)

    Zohner, Steven K

    2000-05-01

    This report presents the 1999 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradionuclide emissions estimates for stationary sources.

  18. Estimates of wildland fire emissions

    Science.gov (United States)

    Yongqiang Liu; John J. Qu; Wanting Wang; Xianjun Hao

    2013-01-01

    Wildland fire missions can significantly affect regional and global air quality, radiation, climate, and the carbon cycle. A fundamental and yet challenging prerequisite to understanding the environmental effects is to accurately estimate fire emissions. This chapter describes and analyzes fire emission calculations. Various techniques (field measurements, empirical...

  19. The Norwegian Emission Inventory 2010. Documentation of methodologies for estimating emissions of greenhouse gases and long-range transboundary air pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Sandmo, Trond (ed.)

    2010-06-15

    The Norwegian emission inventory is a joint undertaking between the Climate and Pollution Agency (Klif) and Statistics Norway. Statistics Norway is responsible for the collection and development of activity data, and emission figures are derived from models operated by Statistics Norway. The Climate and Pollution Agency is responsible for the emission factors, for providing data from specific industries and sources and for considering the quality, and assuring necessary updating, of emissions models like e.g. the road traffic model and calculation of methane emissions from landfills. Emission data are used for a range of national applications and for international reporting. The Climate and Pollution Agency is responsible for the Norwegian reporting to United Nations Framework Convention on Climate Change (UNFCCC) and to United Nations Economic Commission Europe (UN-ECE). This report documents the methodologies used in the Norwegian emission inventory of greenhouse gases (GHG), acidifying pollutants, heavy metals (HM) and persistent organic pollutants (POPs). The documentation will also serve as a part of the National Inventory Report submitted by Norway to the United Nations Framework Convention on Climate Change (UNFCCC), and as documentation of the reported emissions to UNECE for the pollutants restricted by CLRTAP (Convention on Long-Range Transboundary Air Pollution). LULUCF is not considered in this report, see the National Inventory Report (Climate and Pollution Agency 2010) for documentation on this topic. This report replaces the previous documentation of the emission model, (Sandmo 2009), and is the latest annually updated version of a report edited by Britta Hoem in 2005. The most important changes since last year's documentation are: Emissions of CH{sub 4} and N{sub 2}O from well testing of crude oil off shore have been included - these have previously not been estimated Emissions of CH{sub 4} from enteric fermentation have increased for the whole

  20. Estimation of health damage due to emission of air pollutants by cars: the canyon effect

    Energy Technology Data Exchange (ETDEWEB)

    Spadaro, J.V. [Ecole des Mines, Centre d' Energetique, Paris, 75 (France); Rabl, A.

    1999-07-01

    Since current epidemiological evidence suggests that air pollution has harmful effects even at typical ambient concentrations and the dispersion is significant over hundreds to thousands of km, the estimation of total health damage involves consideration of local and regional effects. In recent years, several estimates have been published of health damage due to air pollution from cars, in particular by Delucchi et al of UC Davis and by the ExternE Project of the European Commission. To capture the geographic extent of pollutant dispersion, local and regional models have been used in combination. The present paper addresses a potentially significant contribution of the total damage, not yet taken into account in these studies: the increased concentration of pollutants inside urban street canyons. This canyon effect is appreciable only for primary pollutants, the time constants for the formation of secondary pollutants being long compared to the residence time in the canyon. We assumed linearity of incremental health impact with incremental concentration, in view of the lack of epidemiological evidence for no-effect thresholds or significant deviations from linearity at typical ambient concentrations; therefore, only long term average concentrations matter. We use the FLUENT software to model the dispersion inside a street canyon for a wide range of rectangular geometries and wind velocities. Our results suggest that the canyon effect is of marginal significance for total damages, the contribution of the canyon effect being roughly 10 to 20% of the total. The relative importance of the canyon effect is, of course, highly variable with local conditions; it could be much smaller but it is unlikely to add more than 100% to the flat terrain estimate. (Author)

  1. EARTH, WIND AND FIRE: BUILDING METEOROLOGICALLY-SENSITIVE BIOGENIC AND WILDLAND FIRE EMISSION ESTIMATES FOR AIR QUALITY MODELS

    Science.gov (United States)

    Emission estimates are important for ensuring the accuracy of atmospheric chemical transport models. Estimates of biogenic and wildland fire emissions, because of their sensitivity to meteorological conditions, need to be carefully constructed and closely linked with a meteorolo...

  2. The Norwegian Emission Inventory 2012. Documentation of methodologies for estimating emissions of greenhouse gases and long-range transboundary air pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Sandmo, Trond (ed.)

    2012-07-01

    The Norwegian emission inventory is a joint undertaking between the Climate and Pollution Agency1 and Statistics Norway. Statistics Norway is responsible for the collection and development of activity data, and emission figures are derived from models operated by Statistics Norway. The Climate and Pollution Agency is responsible for the emission factors, for providing data from specific industries and sources and for considering the quality, and assuring necessary updating, of emission models like, e.g., the road traffic model and calculation of methane emissions from landfills. Emission data are used for a range of national applications and for international reporting. The Climate and Pollution Agency is responsible for the Norwegian reporting to United Nations Framework Convention on Climate Change (UNFCCC) and to United Nations Economic Commission Europe (UN-ECE). This report documents the methodologies used in the Norwegian emission inventory of greenhouse gases (GHG), acidifying pollutants, heavy metals (HM) and persistent organic pollutants (POPs). The documentation will also serve as a part of the National Inventory Report submitted by Norway to the United Nations Framework Convention on Climate Change (UNFCCC), and as documentation of the reported emissions to UNECE for the pollutants restricted by CLRTAP (Convention on Long-Range Transboundary Air Pollution). LULUCF (land use, land-use change and forestry) is not considered in this report, see the National Inventory Report (Climate and Pollution Agency 2012) for documentation on this topic.This report replaces the previous documentation of the emission model (Sandmo 2011), and is the latest annually updated version of a report edited by Britta Hoem in 2005. The most important changes since last year's documentation are: Minor NOx emissions from production of rock wool, which previously not have been estimated, have been included, Some factors for estimation of N2O from agriculture have been altered

  3. The Norwegian Emission Inventory 2012. Documentation of methodologies for estimating emissions of greenhouse gases and long-range transboundary air pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Sandmo, Trond [ed.

    2012-07-01

    The Norwegian emission inventory is a joint undertaking between the Climate and Pollution Agency1 and Statistics Norway. Statistics Norway is responsible for the collection and development of activity data, and emission figures are derived from models operated by Statistics Norway. The Climate and Pollution Agency is responsible for the emission factors, for providing data from specific industries and sources and for considering the quality, and assuring necessary updating, of emission models like, e.g., the road traffic model and calculation of methane emissions from landfills. Emission data are used for a range of national applications and for international reporting. The Climate and Pollution Agency is responsible for the Norwegian reporting to United Nations Framework Convention on Climate Change (UNFCCC) and to United Nations Economic Commission Europe (UN-ECE). This report documents the methodologies used in the Norwegian emission inventory of greenhouse gases (GHG), acidifying pollutants, heavy metals (HM) and persistent organic pollutants (POPs). The documentation will also serve as a part of the National Inventory Report submitted by Norway to the United Nations Framework Convention on Climate Change (UNFCCC), and as documentation of the reported emissions to UNECE for the pollutants restricted by CLRTAP (Convention on Long-Range Transboundary Air Pollution). LULUCF (land use, land-use change and forestry) is not considered in this report, see the National Inventory Report (Climate and Pollution Agency 2012) for documentation on this topic.This report replaces the previous documentation of the emission model (Sandmo 2011), and is the latest annually updated version of a report edited by Britta Hoem in 2005. The most important changes since last year's documentation are: Minor NOx emissions from production of rock wool, which previously not have been estimated, have been included, Some factors for estimation of N2O from agriculture have been altered, The

  4. Air Emissions Factors and Quantification

    Science.gov (United States)

    Emissions factors are used in developing air emissions inventories for air quality management decisions and in developing emissions control strategies. This area provides technical information on and support for the use of emissions factors.

  5. Model for traffic emissions estimation

    Science.gov (United States)

    Alexopoulos, A.; Assimacopoulos, D.; Mitsoulis, E.

    A model is developed for the spatial and temporal evaluation of traffic emissions in metropolitan areas based on sparse measurements. All traffic data available are fully employed and the pollutant emissions are determined with the highest precision possible. The main roads are regarded as line sources of constant traffic parameters in the time interval considered. The method is flexible and allows for the estimation of distributed small traffic sources (non-line/area sources). The emissions from the latter are assumed to be proportional to the local population density as well as to the traffic density leading to local main arteries. The contribution of moving vehicles to air pollution in the Greater Athens Area for the period 1986-1988 is analyzed using the proposed model. Emissions and other related parameters are evaluated. Emissions from area sources were found to have a noticeable share of the overall air pollution.

  6. Trading emissions improve air quality

    International Nuclear Information System (INIS)

    Lents, J.M.

    1993-01-01

    While admitting sharply contrasting views exist, James M. Lents of the South Coast Air Quality Management District in southern California sees emissions trading open-quotes as a lifesaver for our troubled planet.close quotes He explains: open-quotes If political support for the environment is to be maintained, we must seek the most economical and flexible means of pursuing cleanup. At present, market incentives and emissions trading represent our best hope.close quotes Lents is putting his money where his pen is. The air quality management district he heads plans to use market incentives, including emissions trading, to reduce air pollution in the notoriously dirty southern California area. When the system goes into operation in 1994, he estimates it will save southern California businesses more than $400 million a year in compliance costs, while also making major improvements in the region's air quality. If the idea works there, why won't it work elsewhere, even on a global scale, Lents asks? He believes it will. But open-quotes the ultimate success of emissions-trading programs, whether regional, national, or international in scope, lies in the proof that they're actually achieving reductions in harmful emissions,close quotes he emphasizes. open-quotes These reductions must be real and verifiable to satisfy the Clean Air Act and a skeptical public.close quotes

  7. Energetic balance and air pollutant emissions estimates in the Aburra Valley, 1999: A preliminary approximation

    International Nuclear Information System (INIS)

    Molina Perez; Francisco; Saavedra Duque, Marcela; Obregon Cardona Mauricio

    2003-01-01

    Based on the application of Material Fluxes Analysis, this paper presents the composition of the energetic basket in Valle de Aburra during 1999 and the atmospheric emissions caused by the consumption of those energetic materials. Basically, it was found that the daily energetic consumption of the system was 43,2 Tcal that generated 716 ton. by day of atmospheric contaminants as an output. The results show that the main energetic materials that participate in the global metabolism of the system, was those consumed in the transportation sector (gasoline and diesel). Therefore transportation sector contributes with the principal load of contaminants represented by carbon monoxide that overtake the 77,6% of the whole emissions

  8. Assessing concentrations and health impacts of air quality management strategies: Framework for Rapid Emissions Scenario and Health impact ESTimation (FRESH-EST).

    Science.gov (United States)

    Milando, Chad W; Martenies, Sheena E; Batterman, Stuart A

    2016-09-01

    In air quality management, reducing emissions from pollutant sources often forms the primary response to attaining air quality standards and guidelines. Despite the broad success of air quality management in the US, challenges remain. As examples: allocating emissions reductions among multiple sources is complex and can require many rounds of negotiation; health impacts associated with emissions, the ultimate driver for the standards, are not explicitly assessed; and long dispersion model run-times, which result from the increasing size and complexity of model inputs, limit the number of scenarios that can be evaluated, thus increasing the likelihood of missing an optimal strategy. A new modeling framework, called the "Framework for Rapid Emissions Scenario and Health impact ESTimation" (FRESH-EST), is presented to respond to these challenges. FRESH-EST estimates concentrations and health impacts of alternative emissions scenarios at the urban scale, providing efficient computations from emissions to health impacts at the Census block or other desired spatial scale. In addition, FRESH-EST can optimize emission reductions to meet specified environmental and health constraints, and a convenient user interface and graphical displays are provided to facilitate scenario evaluation. The new framework is demonstrated in an SO2 non-attainment area in southeast Michigan with two optimization strategies: the first minimizes emission reductions needed to achieve a target concentration; the second minimizes concentrations while holding constant the cumulative emissions across local sources (e.g., an emissions floor). The optimized strategies match outcomes in the proposed SO2 State Implementation Plan without the proposed stack parameter modifications or shutdowns. In addition, the lower health impacts estimated for these strategies suggest that FRESH-EST could be used to identify potentially more desirable pollution control alternatives in air quality management planning

  9. Estimation of biogenic emissions with satellite-derived land use and land cover data for air quality modeling of Houston-Galveston ozone nonattainment area.

    Science.gov (United States)

    Byun, Daewon W; Kim, Soontae; Czader, Beata; Nowak, David; Stetson, Stephen; Estes, Mark

    2005-06-01

    The Houston-Galveston Area (HGA) is one of the most severe ozone non-attainment regions in the US. To study the effectiveness of controlling anthropogenic emissions to mitigate regional ozone nonattainment problems, it is necessary to utilize adequate datasets describing the environmental conditions that influence the photochemical reactivity of the ambient atmosphere. Compared to the anthropogenic emissions from point and mobile sources, there are large uncertainties in the locations and amounts of biogenic emissions. For regional air quality modeling applications, biogenic emissions are not directly measured but are usually estimated with meteorological data such as photo-synthetically active solar radiation, surface temperature, land type, and vegetation database. In this paper, we characterize these meteorological input parameters and two different land use land cover datasets available for HGA: the conventional biogenic vegetation/land use data and satellite-derived high-resolution land cover data. We describe the procedures used for the estimation of biogenic emissions with the satellite derived land cover data and leaf mass density information. Air quality model simulations were performed using both the original and the new biogenic emissions estimates. The results showed that there were considerable uncertainties in biogenic emissions inputs. Subsequently, ozone predictions were affected up to 10 ppb, but the magnitudes and locations of peak ozone varied each day depending on the upwind or downwind positions of the biogenic emission sources relative to the anthropogenic NOx and VOC sources. Although the assessment had limitations such as heterogeneity in the spatial resolutions, the study highlighted the significance of biogenic emissions uncertainty on air quality predictions. However, the study did not allow extrapolation of the directional changes in air quality corresponding to the changes in LULC because the two datasets were based on vastly different

  10. Estimating emissions on vehicular traffic based on projected energy and transport demand on rural roads: Policies for reducing air pollutant emissions and energy consumption

    International Nuclear Information System (INIS)

    Ozan, Cenk; Haldenbilen, Soner; Ceylan, Halim

    2011-01-01

    This study deals with the estimation of emissions caused by vehicular traffic based on transport demand and energy consumption. Projected transport demand is calculated with Genetic Algorithm (GA) using population, gross domestic product per capita (GDPPC) and the number of vehicles. The energy consumption is modelled with the GA using the veh-km. The model age of the vehicles and their corresponding share for each year using the reference years is obtained. The pollutant emissions are calculated with estimated transport and energy demand. All the calculations are made in line to meet the European standards. For this purpose, two cases are composed. Case 1: Emissions based on energy consumption, and Case 2: Emissions based on transport demand. The both cases are compared. Three policies are proposed to control demand and the emissions. The policies provided the best results in terms of minimum emissions and the reasonable share of highway and railway mode as 70% and 30% usage for policy I, respectively. The emission calculation procedure presented in this study would provide an alternative way to make policies when there is no adequate data on emission measurement in developing countries. - Research highlights: → Emissions caused by vehicular traffic are modelled. → The pollutant emissions are calculated with estimated transport and energy demand. → All the calculations are made in line with to meet the European standards. → The calculation procedure will provide an alternative way to make policies. → The procedure will help planners to convince politicians to impose policies.

  11. Methodologies for estimating air emissions from three non-traditional source categories: Oil spills, petroleum vessel loading and unloading, and cooling towers. Final report, October 1991-March 1993

    International Nuclear Information System (INIS)

    Ramadan, W.; Sleva, S.; Dufner, K.; Snow, S.; Kersteter, S.L.

    1993-04-01

    The report discusses part of EPA's program to identify and characterize emissions sources not currently accounted for by either the existing Aerometric Information Retrieval System (AIRS) or State Implementation Plan (SIP) area source methodologies and to develop appropriate emissions estimation methodologies and emission factors for a group of these source categories. Based on the results of the identification and characterization portions of this research, three source categories were selected for methodology and emission factor development: oil spills, petroleum vessel loading and unloading, and cooling towers. The report describes the category selection process and presents emissions estimation methodologies and emission factor data for the selected source categories. The discussions for each category include general background information, emissions generation activities, pollutants emitted, sources of activity and pollutant data, emissions estimation methodologies and data issues. The information used in these discussions was derived from various sources including available literature, industrial and trade association publications and contracts, experts on the category and activity, and knowledgeable federal and state personnel

  12. The Norwegian Emission Inventory 2011. Documentation of methodologies for estimating emissions of greenhouse gases and long-range transboundary air pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Sandmo, Trond

    2012-07-01

    The Norwegian emission inventory is a joint undertaking between the Climate and Pollution Agency1 and Statistics Norway. Statistics Norway is responsible for the collection and development of activity data, and emission figures are derived from models operated by Statistics Norway. The Climate and Pollution Agency is responsible for the emission factors, for providing data from specific industries and sources and for considering the quality, and assuring necessary updating, of emission models like, e.g., the road traffic model and calculation of methane emissions from landfills. Emission data are used for a range of national applications and for international reporting. The Climate and Pollution Agency is responsible for the Norwegian reporting to United Nations Framework Convention on Climate Change (UNFCCC) and to United Nations Economic Commission Europe (UN-ECE). This report documents the methodologies used in the Norwegian emission inventory of greenhouse gases (GHG), acidifying pollutants, heavy metals (HM) and persistent organic pollutants (POPs). The documentation will also serve as a part of the National Inventory Report submitted by Norway to the United Nations Framework Convention on Climate Change (UNFCCC), and as documentation of the reported emissions to UNECE for the pollutants restricted by CLRTAP (Convention on Long-Range Transboundary Air Pollution). LULUCF is not considered in this report, see the National Inventory Report (Climate and Pollution Agency 2011b) for documentation on this topic. This report replaces the previous documentation of the emission model (Sandmo 2010), and is the latest annually updated version of a report edited by Britta Hoem in 2005. The most important changes since last year's documentation are: To define the different economic sectors in the Norwegian emission model, the standard industrial classification SIC2007 has replaced the previous SIC2002 (Appendix F) A new model for calculating emissions to air (HBEFA

  13. The Norwegian Emission Inventory 2011. Documentation of methodologies for estimating emissions of greenhouse gases and long-range transboundary air pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Sandmo, Trond

    2012-07-01

    The Norwegian emission inventory is a joint undertaking between the Climate and Pollution Agency1 and Statistics Norway. Statistics Norway is responsible for the collection and development of activity data, and emission figures are derived from models operated by Statistics Norway. The Climate and Pollution Agency is responsible for the emission factors, for providing data from specific industries and sources and for considering the quality, and assuring necessary updating, of emission models like, e.g., the road traffic model and calculation of methane emissions from landfills. Emission data are used for a range of national applications and for international reporting. The Climate and Pollution Agency is responsible for the Norwegian reporting to United Nations Framework Convention on Climate Change (UNFCCC) and to United Nations Economic Commission Europe (UN-ECE). This report documents the methodologies used in the Norwegian emission inventory of greenhouse gases (GHG), acidifying pollutants, heavy metals (HM) and persistent organic pollutants (POPs). The documentation will also serve as a part of the National Inventory Report submitted by Norway to the United Nations Framework Convention on Climate Change (UNFCCC), and as documentation of the reported emissions to UNECE for the pollutants restricted by CLRTAP (Convention on Long-Range Transboundary Air Pollution). LULUCF is not considered in this report, see the National Inventory Report (Climate and Pollution Agency 2011b) for documentation on this topic. This report replaces the previous documentation of the emission model (Sandmo 2010), and is the latest annually updated version of a report edited by Britta Hoem in 2005. The most important changes since last year's documentation are: To define the different economic sectors in the Norwegian emission model, the standard industrial classification SIC2007 has replaced the previous SIC2002 (Appendix F) A new model for calculating emissions to air (HBEFA) from

  14. Spatial estimation of air PM2.5 emissions using activity data, local emission factors and land cover derived from satellite imagery

    Science.gov (United States)

    Gibe, Hezron P.; Cayetano, Mylene G.

    2017-09-01

    Exposure to particulate matter (PM) is a serious environmental problem in many urban areas on Earth. In the Philippines, most existing studies and emission inventories have mainly focused on point and mobile sources, while research involving human exposures to particulate pollutants is rare. This paper presents a method for estimating the amount of fine particulate (PM2.5) emissions in a test study site in the city of Cabanatuan, Nueva Ecija, in the Philippines, by utilizing local emission factors, regionally procured data, and land cover/land use (activity data) interpreted from satellite imagery. Geographic information system (GIS) software was used to map the estimated emissions in the study area. The present results suggest that vehicular emissions from motorcycles and tricycles, as well as fuels used by households (charcoal) and burning of agricultural waste, largely contribute to PM2.5 emissions in Cabanatuan. Overall, the method used in this study can be applied in other small urbanizing cities, as long as on-site specific activity, emission factor, and satellite-imaged land cover data are available.

  15. Air emission inventory for the Idaho National Engineering Laboratory: 1994 emissions report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-07-01

    This report Presents the 1994 update of the Air Emission inventory for the Idaho National Engineering Laboratory (INEL). The INEL Air Emission Inventory documents sources and emissions of non-radionuclide pollutants from operations at the INEL. The report describes the emission inventory process and all of the sources at the INEL, and provides non-radionuclide emissions estimates for stationary sources.

  16. Air emission inventory for the Idaho National Engineering Laboratory: 1994 emissions report

    International Nuclear Information System (INIS)

    1995-07-01

    This report Presents the 1994 update of the Air Emission inventory for the Idaho National Engineering Laboratory (INEL). The INEL Air Emission Inventory documents sources and emissions of non-radionuclide pollutants from operations at the INEL. The report describes the emission inventory process and all of the sources at the INEL, and provides non-radionuclide emissions estimates for stationary sources

  17. Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory - Calendar Year 1999 Emission Report

    Energy Technology Data Exchange (ETDEWEB)

    Zohner, S.K.

    2000-05-30

    This report presents the 1999 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradionuclide emissions estimates for stationary sources.

  18. Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory - Calendar Year 1998 Emissions Report

    Energy Technology Data Exchange (ETDEWEB)

    S. K. Zohner

    1999-10-01

    This report presents the 1998 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradiological emissions estimates for stationary sources.

  19. Air emissions inventory for the Idaho National Engineering Laboratory -- 1995 emissions report

    International Nuclear Information System (INIS)

    1996-06-01

    This report presents the 1995 update of the Air Emission Inventory for the Idaho National Engineering Laboratory (INEL). The INEL Air Emission Inventory documents sources and emissions of non-radionuclide pollutants from operations at the INEL. The report describes the emission inventory process and all of the sources at the INEL, and provides non-radionuclide emissions estimates for stationary sources. The air contaminants reported include nitrogen oxides, sulfur oxides, carbon monoxide, volatile organic compounds, particulates, and hazardous air pollutants (HAPs)

  20. Air emissions inventory for the Idaho National Engineering Laboratory -- 1995 emissions report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-06-01

    This report presents the 1995 update of the Air Emission Inventory for the Idaho National Engineering Laboratory (INEL). The INEL Air Emission Inventory documents sources and emissions of non-radionuclide pollutants from operations at the INEL. The report describes the emission inventory process and all of the sources at the INEL, and provides non-radionuclide emissions estimates for stationary sources. The air contaminants reported include nitrogen oxides, sulfur oxides, carbon monoxide, volatile organic compounds, particulates, and hazardous air pollutants (HAPs).

  1. Estimating Emissions from Railway Traffic

    DEFF Research Database (Denmark)

    Jørgensen, Morten W.; Sorenson, Spencer C.

    1998-01-01

    Several parameters of importance for estimating emissions from railway traffic are discussed, and typical results presented. Typical emissions factors from diesel engines and electrical power generation are presented, and the effect of differences in national electrical generation sources...

  2. Analysis of motorcycle fleet in Hanoi for estimation of air pollution emission and climate mitigation co-benefit of technology implementation

    Science.gov (United States)

    Kim Oanh, Nguyen Thi; Thuy Phuong, Mai Thi; Permadi, Didin Agustian

    2012-11-01

    A fleet of over two million motorcycles (MC) in Hanoi is believed to contribute a substantial emission of air pollutants and climate forcers but has not been thoroughly characterized. This study conducted a survey of the MC technologies and activities in Hanoi using questionnaires, GPS monitoring, and video camera in 2008. The data were collected for three typical road types (highways, arterials, residential streets) in 3 zones of the city. Majority of MC in Hanoi were relatively new (3.6 years), had 4-stroke engine, but only 6% was equipped with catalyst exhaust control devices. About 35% of the fleet did not comply with any EURO standards. The MC daily driving was 20 km, mostly done on arterial streets. The main driving features in Hanoi arterials and residential streets were of low speeds with frequent starts/stops and idling. International Vehicle Emissions (IVE) model produced adjusted emission factors (EFs) that were compared with the limited available measurement data. The fleet emission was estimated for 2008 as a base case and for two “what-if” faster technology implementation scenarios: scenario 1 assumed that the entire fleet in 2008 conformed at least EURO2 and scenario 2 assumed 100% MC met the EURO3 standard. Total emissions from the fleet in 2008 of CO, VOC, NOx, SO2, PM10, and CH4 were 158, 51.5, 9.5, 0.17, 2.4 and 9.5 kt, respectively. Emissions of 1,3-butadiene, acetaldehydes, formaldehydes and benzene were 0.26, 1.2, 4.9 and 2.1 kt, respectively. Faster EURO3 technology intrusion in scenario 2 would significantly reduce the emission of pollutants (by 53-94%) and climate forcers in CO2-equivalent (53% for 20-year and 38% for 100-year horizon), which tripled the reductions obtained under scenario 1. Substantial co-benefits for air quality and climate forcer mitigation could be achieved by the faster technology implementation.

  3. Global and regional emissions estimates of 1,1-difluoroethane (HFC-152a, CH[subscript 3]CHF[subscript 2]) from in situ and air archive observations

    OpenAIRE

    Prinn, Ronald G.

    2015-01-01

    High frequency, in situ observations from 11 globally distributed sites for the period 1994–2014 and archived air measurements dating from 1978 onward have been used to determine the global growth rate of 1,1-difluoroethane (HFC-152a, CH[subscript 3]CHF[subscript 2]). These observations have been combined with a range of atmospheric transport models to derive global emission estimates in a top-down approach. HFC-152a is a greenhouse gas with a short atmospheric lifetime of about 1.5 years. Si...

  4. Radioactive air emissions 1992 summary

    International Nuclear Information System (INIS)

    Wahl, L.

    1993-10-01

    This report summarizes, by radionuclide or product and by emitting facility, the Laboratory's 1992 radioactive air emissions. In 1992, the total activity of radionuclides emitted into the air from Laboratory stacks was approximately 73,500 Ci. This was an increase over the activity of the total 1991 radioactive air emissions, which was approximately 62,400 Ci. Total 1992 Laboratory emissions of each radionuclide or product are summarized by tables and graphs in the first section of this report. Compared to 1991 radioactive air emissions, total tritium activity was decreased, total plutonium activity was decreased, total uranium activity was decreased, total mixed fission product activity was increased, total 41 Ar activity was decreased, total gaseous/mixed activation product (except 41 Ar) activity was increased, total particulate/vapor activation product activity was increased, and total 32 P activity was decreased. Radioactive emissions from specific facilities are detailed in this report. Each section provides 1992 data on a single radionuclide or product and is further divided by emitting facility. For each facility from which a particular radionuclide or product was emitted, a bar chart displays the air emissions of each radionuclide or product from each facility over the 12 reporting periods of 1992, a line chart shows the trend in total emissions of that radionuclide or product from that facility for the past three years, the greatest activity during the 1990--1992 period is discussed, and unexpected or unusual results are noted

  5. Global and regional emissions estimates of 1,1-difluoroethane (HFC-152a, CH3CHF2) from in situ and air archive observations

    Science.gov (United States)

    Simmonds, P. G.; Rigby, M.; Manning, A. J.; Lunt, M. F.; O'Doherty, S.; McCulloch, A.; Fraser, P. J.; Henne, S.; Vollmer, M. K.; Mühle, J.; Weiss, R. F.; Salameh, P. K.; Young, D.; Reimann, S.; Wenger, A.; Arnold, T.; Harth, C. M.; Krummel, P. B.; Steele, L. P.; Dunse, B. L.; Miller, B. R.; Lunder, C. R.; Hermansen, O.; Schmidbauer, N.; Saito, T.; Yokouchi, Y.; Park, S.; Li, S.; Yao, B.; Zhou, L. X.; Arduini, J.; Maione, M.; Wang, R. H. J.; Ivy, D.; Prinn, R. G.

    2016-01-01

    High frequency, in situ observations from 11 globally distributed sites for the period 1994-2014 and archived air measurements dating from 1978 onward have been used to determine the global growth rate of 1,1-difluoroethane (HFC-152a, CH3CHF2). These observations have been combined with a range of atmospheric transport models to derive global emission estimates in a top-down approach. HFC-152a is a greenhouse gas with a short atmospheric lifetime of about 1.5 years. Since it does not contain chlorine or bromine, HFC-152a makes no direct contribution to the destruction of stratospheric ozone and is therefore used as a substitute for the ozone depleting chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs). The concentration of HFC-152a has grown substantially since the first direct measurements in 1994, reaching a maximum annual global growth rate of 0.84 ± 0.05 ppt yr-1 in 2006, implying a substantial increase in emissions up to 2006. However, since 2007, the annual rate of growth has slowed to 0.38 ± 0.04 ppt yr-1 in 2010 with a further decline to an annual average rate of growth in 2013-2014 of -0.06 ± 0.05 ppt yr-1. The annual average Northern Hemisphere (NH) mole fraction in 1994 was 1.2 ppt rising to an annual average mole fraction of 10.1 ppt in 2014. Average annual mole fractions in the Southern Hemisphere (SH) in 1998 and 2014 were 0.84 and 4.5 ppt, respectively. We estimate global emissions of HFC-152a have risen from 7.3 ± 5.6 Gg yr-1 in 1994 to a maximum of 54.4 ± 17.1 Gg yr-1 in 2011, declining to 52.5 ± 20.1 Gg yr-1 in 2014 or 7.2 ± 2.8 Tg-CO2 eq yr-1. Analysis of mole fraction enhancements above regional background atmospheric levels suggests substantial emissions from North America, Asia, and Europe. Global HFC emissions (so called "bottom up" emissions) reported by the United Nations Framework Convention on Climate Change (UNFCCC) are based on cumulative national emission data reported to the UNFCCC, which in turn are based on

  6. Estimation of air quality by air pollution indices

    International Nuclear Information System (INIS)

    Liblik, Valdo; Kundel, Helmut

    1999-01-01

    A novel system for estimating the quality of atmospheric air in the over-ground air layer with the help of air pollution indices was developed. The method is based on a comparison of measured or calculated maximum short-term concentrations and average annual concentrations of pollutants with maximum permissible concentrations (with regard to human beings and vegetation). Special air quality estimation scales for residential areas and natural systems are presented. On the basis of the concentration of the substance under study zones of very high, high, rather high, moderate, low and very low air pollution were distinguished in the over-ground layer of the atmosphere. These are projected to land surface for landscape zonation. The application of the system of indices is demonstrated in the analysis of air quality for the towns of Kohtla-Jarve, Johvi and Kivioli (in 1997-1998). A comparative analysis of the air pollution zones distinguished on the basis of emissions and data from bio monitoring yielded satisfactory results. The system of air pollution indices developed enables to process the results of air monitoring in case of pollution fields of complicated composition so that the result for estimating the quality of ambient air in a residential area is easily understood by inhabitants and interpretable with the help of a special scale; analyse temporal changes in the quality of the air in towns, villages and other residential areas and use the results as basis for developing measures for reducing the pollution of ambient air; carry out zonation of large territories on the basis of air pollution levels (spatial air pollution zones are projected on the ground surface) and estimate air quality in places where air monitoring is lacking to forecast the possible effect of air pollution on natural systems (author)

  7. Federal Air Pollutant Emission Regulations and Preliminary Estimates of Potential-to-Emit from Biorefineries. Pathway #1: Dilute-Acid and Enzymatic Deconstruction of Biomass-to-Sugars and Biological Conversion of Sugars-to-Hydrocarbons

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yimin [National Renewable Energy Lab. (NREL), Golden, CO (United States); Bhatt, Arpit [National Renewable Energy Lab. (NREL), Golden, CO (United States); Heath, Garvin [National Renewable Energy Lab. (NREL), Golden, CO (United States); Thomas, Mae [Eastern Research Group, Lexington, MA (United States); Renzaglia, Jason [Eastern Research Group, Lexington, MA (United States)

    2016-02-01

    Biorefineries are subject to environmental laws, including complex air quality regulations that aim to protect and improve the quality of the air. These regulations govern the amount of certain types of air pollutants that can be emitted from different types of emission sources. To determine which federal air emission regulations potentially apply to the sugars-to-hydrocarbon (HC) biorefinery, we first identified the types of regulated air pollutants emitted to the ambient environment by the biorefinery or from specific equipment. Once the regulated air pollutants are identified, we review the applicability criteria of each federal air regulation to determine whether the sugars-to-HC biorefinery or specific equipment is subject to it. We then estimate the potential-to-emit of pollutants likely to be emitted from the sugars-to-HC biorefinery to understand the air permitting requirements.

  8. Federal Air Pollutant Emission Regulations and Preliminary Estimates of Potential-to-Emit from Biorefineries, Pathway #2: Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Fast Pyrolysis and Hydrotreating Bio-oil Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Bhatt, Arpit [National Renewable Energy Lab. (NREL), Golden, CO (United States). Strategic Energy Analysis Center. Technology Systems and Sustainability Analysis Group; Zhang, Yimin [National Renewable Energy Lab. (NREL), Golden, CO (United States). Strategic Energy Analysis Center. Technology Systems and Sustainability Analysis Group; Heath, Garvin [National Renewable Energy Lab. (NREL), Golden, CO (United States). Strategic Energy Analysis Center. Technology Systems and Sustainability Analysis Group; Thomas, Mae [Eastern Research Group, Research Triangle Park, NC (United States); Renzaglia, Jason [Eastern Research Group, Research Triangle Park, NC (United States)

    2017-01-01

    Biorefineries are subject to environmental laws, including complex air quality regulations that aim to protect and improve the quality of the air. These regulations govern the amount of certain types of air pollutants that can be emitted from different types of emission sources. To determine which federal air emission regulations potentially apply to the fast pyrolysis biorefinery, we first identified the types of regulated air pollutants emitted to the ambient environment by the biorefinery or from specific equipment. Once the regulated air pollutants are identified, we review the applicability criteria of each federal air regulation to determine whether the fast pyrolysis biorefinery or specific equipment is subject to it. We then estimate the potential-to-emit of pollutants likely to be emitted from the fast pyrolysis biorefinery to understand the air permitting requirements.

  9. Air Emission Inventory for the Idaho National Engineering Laboratory, 1993 emissions report

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-01

    This report presents the 1993 update of the Air Emission Inventory for the Idaho National Engineering Laboratory (INEL). The purpose of the Air Emission Inventory is to commence the preparation of the permit to operate application for the INEL, as required by the recently promulgated Title V regulations of the Clean Air Act. The report describes the emission inventory process and all of the sources at the INEL and provides emissions estimates for both mobile and stationary sources.

  10. Air Emission Inventory for the Idaho National Engineering Laboratory, 1993 emissions report

    International Nuclear Information System (INIS)

    1994-06-01

    This report presents the 1993 update of the Air Emission Inventory for the Idaho National Engineering Laboratory (INEL). The purpose of the Air Emission Inventory is to commence the preparation of the permit to operate application for the INEL, as required by the recently promulgated Title V regulations of the Clean Air Act. The report describes the emission inventory process and all of the sources at the INEL and provides emissions estimates for both mobile and stationary sources

  11. Estimating emissions from railway traffic

    Energy Technology Data Exchange (ETDEWEB)

    Joergensen, M.W.; Sorenson, C.

    1997-07-01

    The report discusses methods that can be used to estimate the emissions from various kinds of railway traffic. The methods are based on the estimation of the energy consumption of the train, so that comparisons can be made between electric and diesel driven trains. Typical values are given for the necessary traffic parameters, emission factors, and train loading. Detailed models for train energy consumption are presented, as well as empirically based methods using average train speed and distance between stop. (au)

  12. Modeling emissions and dispersion of contaminants from cleanup activities at a mixed waste site to estimate air impacts and risks

    International Nuclear Information System (INIS)

    Chang, Y.S.; Menlove, S.

    1993-09-01

    The transport and dispersion of contaminants via the air pathway is a major concern during cleanup of contaminated sites. Impacts to air quality and human health during cleanup were evaluated for the Weldon Spring site by using site-specific information for source areas, activities, and receptor locations. In order to ensure protection of human health and the environment, results are being used to focus on those cleanup activities for which release controls should be emphasized

  13. Air pollution from motor vehicle emissions

    International Nuclear Information System (INIS)

    Petrushevska, Ljubica

    1996-01-01

    This paper presents some aspects of air pollution from motor vehicle emissions as: characteristic primary and secondary pollutants, dependence of the motor vehicle emission from the engine type; the relationship of typical engine emission and performance to air-fuel ratio, transport of pollutants from mobile sources of emissions, as well as some world experiences in the control approaches for exhaust emissions. (author)

  14. Dioxin air emission inventory 1990-2004

    Energy Technology Data Exchange (ETDEWEB)

    Capral Henriksen, T; Illerup, J B; Nielsen, Ole-Kenneth [DMU, Dept. of Policy Analysis (Denmark)

    2006-12-15

    The present Danish dioxin air emission inventory shows that the emission has been reduced from 68.6 g I-TEQ in 1990 to 22.0 g I-TEQ in 2004, or about 68% over this period. Most of the significant reductions have been achieved in the industrial sector, where emissions have been reduced from 14.67 g I-TEQ in 1990 to 0.17 g I-TEQ in 2004; a reduction of almost 99%. Lower emissions from steel and aluminium reclamation industries form the major part of the reduction within industry. Emissions from waste incineration reduced from 32.5 g I-TEQ in 1990 to 2.1 g ITEQ in 2004; which is approx. 94%. This is due to installation of dioxin abatement equipment in incineration plants. The most important source of emission in 2004 is residential wood combustion, at 8.5 g I-TEQ, or around 40% of the total emission. In 2004, accidental fires, which are estimated to emit 6.1 g I-TEQ/year, are the second most important source, contributing with around 28% of the total emission. The present dioxin emission inventory for Denmark shows how emissions in 2004 come from sources other than waste incineration plants and industry, which were the largest sources in 1990. (au)

  15. Global and regional emissions estimates of 1,1-difluoroethane (HFC-152a, CH3CHF2 from in situ and air archive observations

    Directory of Open Access Journals (Sweden)

    P. G. Simmonds

    2016-01-01

    Full Text Available High frequency, in situ observations from 11 globally distributed sites for the period 1994–2014 and archived air measurements dating from 1978 onward have been used to determine the global growth rate of 1,1-difluoroethane (HFC-152a, CH3CHF2. These observations have been combined with a range of atmospheric transport models to derive global emission estimates in a top-down approach. HFC-152a is a greenhouse gas with a short atmospheric lifetime of about 1.5 years. Since it does not contain chlorine or bromine, HFC-152a makes no direct contribution to the destruction of stratospheric ozone and is therefore used as a substitute for the ozone depleting chlorofluorocarbons (CFCs and hydrochlorofluorocarbons (HCFCs. The concentration of HFC-152a has grown substantially since the first direct measurements in 1994, reaching a maximum annual global growth rate of 0.84 ± 0.05 ppt yr−1 in 2006, implying a substantial increase in emissions up to 2006. However, since 2007, the annual rate of growth has slowed to 0.38 ± 0.04 ppt yr−1 in 2010 with a further decline to an annual average rate of growth in 2013–2014 of −0.06 ± 0.05 ppt yr−1. The annual average Northern Hemisphere (NH mole fraction in 1994 was 1.2 ppt rising to an annual average mole fraction of 10.1 ppt in 2014. Average annual mole fractions in the Southern Hemisphere (SH in 1998 and 2014 were 0.84 and 4.5 ppt, respectively. We estimate global emissions of HFC-152a have risen from 7.3 ± 5.6 Gg yr−1 in 1994 to a maximum of 54.4 ± 17.1 Gg yr−1 in 2011, declining to 52.5 ± 20.1 Gg yr−1 in 2014 or 7.2 ± 2.8 Tg-CO2 eq yr−1. Analysis of mole fraction enhancements above regional background atmospheric levels suggests substantial emissions from North America, Asia, and Europe. Global HFC emissions (so called “bottom up” emissions reported by the United Nations Framework Convention on Climate Change (UNFCCC

  16. Air Emissions Sources, Charts and Maps

    Data.gov (United States)

    U.S. Environmental Protection Agency — Air Emissions provides (1) interactive charts supporting national, state, or county charts, (2) county maps of criteria air pollutant emissions for a state, and (3)...

  17. Air Contamination by Mercury, Emissions and Transformations-a Review.

    Science.gov (United States)

    Gworek, Barbara; Dmuchowski, Wojciech; Baczewska, Aneta H; Brągoszewska, Paulina; Bemowska-Kałabun, Olga; Wrzosek-Jakubowska, Justyna

    2017-01-01

    The present and future air contamination by mercury is and will continue to be a serious risk for human health. This publication presents a review of the literature dealing with the issues related to air contamination by mercury and its transformations as well as its natural and anthropogenic emissions. The assessment of mercury emissions into the air poses serious methodological problems. It is particularly difficult to distinguish between natural and anthropogenic emissions and re-emissions from lands and oceans, including past emissions. At present, the largest emission sources include fuel combustion, mainly that of coal, and "artisanal and small-scale gold mining" (ASGM). The distinctly highest emissions can be found in South and South-East Asia, accounting for 45% of the global emissions. The emissions of natural origin and re-emissions are estimated at 45-66% of the global emissions, with the largest part of emissions originating in the oceans. Forecasts on the future emission levels are not unambiguous; however, most forecasts do not provide for reductions in emissions. Ninety-five percent of mercury occurring in the air is Hg 0 -GEM, and its residence time in the air is estimated at 6 to 18 months. The residence times of its Hg II -GOM and that in Hg p -TPM are estimated at hours and days. The highest mercury concentrations in the air can be found in the areas of mercury mines and those of ASGM. Since 1980 when it reached its maximum, the global background mercury concentration in the air has remained at a relatively constant level.

  18. Bounding estimate of DWPF mercury emissions

    International Nuclear Information System (INIS)

    Jacobs, R.A.

    1993-01-01

    Two factors which have substantial impact on predicted Mercury emissions are the air flows in the Chemical Process Cell (CPC) and the exit temperature of the Formic Acid Vent Condenser (FAVC). The discovery in the IDMS (Integrated DWPF Melter System) of H 2 generation by noble metal catalyzed formic acid decomposition and the resultant required dilution air flow has increased the expected instantaneous CPC air flow by as much as a factor of four. In addition, IDMS has experienced higher than design (10 degrees C) FAVC exit temperatures during certain portions of the operating cycle. These temperatures were subsequently attributed to the exothermic reaction of NO to NO 2 . Moreover, evaluation of the DWPF FAVC indicated it was undersized and unless modified or replaced, routine exit temperatures would be in excess of design. Purges required for H 2 flammability control and verification of elevated FAVC exit temperatures due to NO x reactions have lead to significant changes in CPC operating conditions. Accordingly, mercury emissions estimates have been updated based upon the new operating requirements, IDMS experience, and development of an NO x /FAVC model which predicts FAVC exit temperatures. Using very conservative assumptions and maximum purge rates, the maximum calculated Hg emissions is approximately 130 lbs/yr. A range of 100 to 120 lbs/yr is conservatively predicted for other operating conditions. The peak emission rate calculated is 0.027 lbs/hr. The estimated DWPF Hg emissions for the construction permit are 175 lbs/yr (0.02 lbs/hr annual average)

  19. Air quality estimation by computational intelligence methodologies

    Directory of Open Access Journals (Sweden)

    Ćirić Ivan T.

    2012-01-01

    Full Text Available The subject of this study is to compare different computational intelligence methodologies based on artificial neural networks used for forecasting an air quality parameter - the emission of CO2, in the city of Niš. Firstly, inputs of the CO2 emission estimator are analyzed and their measurement is explained. It is known that the traffic is the single largest emitter of CO2 in Europe. Therefore, a proper treatment of this component of pollution is very important for precise estimation of emission levels. With this in mind, measurements of traffic frequency and CO2 concentration were carried out at critical intersections in the city, as well as the monitoring of a vehicle direction at the crossroad. Finally, based on experimental data, different soft computing estimators were developed, such as feed forward neural network, recurrent neural network, and hybrid neuro-fuzzy estimator of CO2 emission levels. Test data for some characteristic cases presented at the end of the paper shows good agreement of developed estimator outputs with experimental data. Presented results are a true indicator of the implemented method usability. [Projekat Ministarstva nauke Republike Srbije, br. III42008-2/2011: Evaluation of Energy Performances and br. TR35016/2011: Indoor Environment Quality of Educational Buildings in Serbia with Impact to Health and Research of MHD Flows around the Bodies, in the Tip Clearances and Channels and Application in the MHD Pumps Development

  20. 2006 LANL Radionuclide Air Emissions Report

    Energy Technology Data Exchange (ETDEWEB)

    David P. Fuehne

    2007-06-30

    This report describes the impacts from emissions of radionuclides at Los Alamos National Laboratory (LANL) for calendar year 2006. This report fulfills the requirements established by the Radionuclide National Emissions Standards for Hazardous Air Pollutants (Rad-NESHAP). This report is prepared by LANL's Rad-NESHAP compliance team, part of the Environmental Protection Division. The information in this report is required under the Clean Air Act and is being reported to the U.S. Environmental Protection Agency (EPA). The highest effective dose equivalent (EDE) to an off-site member of the public was calculated using procedures specified by the EPA and described in this report. LANL's EDE was 0.47 mrem for 2006. The annual limit established by the EPA is 10 mrem per year. During calendar year 2006, LANL continuously monitored radionuclide emissions at 28 release points, or stacks. The Laboratory estimates emissions from an additional 58 release points using radionuclide usage source terms. Also, LANL uses a network of air samplers around the Laboratory perimeter to monitor ambient airborne levels of radionuclides. To provide data for dispersion modeling and dose assessment, LANL maintains and operates meteorological monitoring systems. From these measurement systems, a comprehensive evaluation is conducted to calculate the EDE for the Laboratory. The EDE is evaluated as any member of the public at any off-site location where there is a residence, school, business, or office. In 2006, this location was the Los Alamos Airport Terminal. The majority of this dose is due to ambient air sampling of plutonium emitted from 2006 clean-up activities at an environmental restoration site (73-002-99; ash pile). Doses reported to the EPA for the past 10 years are shown in Table E1.

  1. The air emissions risk assessment model (AERAM)

    International Nuclear Information System (INIS)

    Gratt, L.B.

    1991-01-01

    AERAM is an environmental analysis and power generation station investment decision support tool. AERAM calculates the public health risk (in terms of the lifetime cancers) in the nearby population from pollutants released into the air. AERAM consists of four main subroutines: Emissions, Air, Exposure and Risk. The Emission subroutine uses power plant parameters to calculate the expected release of the pollutants. A coal-fired and oil-fired power plant are currently available. A gas-fired plant model is under preparation. The release of the pollutants into the air is followed by their dispersal in the environment. The dispersion in the Air Subroutine uses the Environmental Protection Agency's model, Industrial Source Complex-Long Term. Additional dispersion models (Industrial Source Complex - Short Term and Cooling Tower Drift) are being implemented for future AERAM versions. The Expose Subroutine uses the ambient concentrations to compute population exposures for the pollutants of concern. The exposures are used with corresponding dose-response model in the Risk Subroutine to estimate both the total population risk and individual risk. The risk for the dispersion receptor-population centroid for the maximum concentration is also calculated for regulatory-population purposes. In addition, automated interfaces with AirTox (an air risk decision model) have been implemented to extend AERAM's steady-state single solution to the decision-under-uncertainty domain. AERAM was used for public health risks, the investment decision for additional pollution control systems based on health risk reductions, and the economics of fuel vs. health risk tradeoffs. AERAM provides that state-of-the-art capability for evaluating the public health impact airborne toxic substances in response to regulations and public concern

  2. Radionuclide Air Emission Report for 2009

    Energy Technology Data Exchange (ETDEWEB)

    Wahl, Linnea

    2010-06-01

    Berkeley Lab operates facilities where radionuclides are handled and stored. These facilities are subject to the EPA radioactive air emission regulations in 40CFR61, Subpart H (EPA 1989). Radionuclides may be emitted from stacks or vents on buildings where radionuclide production or use is authorized or they may be emitted as diffuse sources. In 2009, all Berkeley Lab sources were minor sources of radionuclides (sources resulting in a potential dose of less than 0.1 mrem/yr [0.001 mSv/yr]). These minor sources included more than 100 stack sources and one source of diffuse emissions. There were no unplanned emissions from the Berkeley Lab site. Emissions from minor sources (stacks and diffuse emissions) either were measured by sampling or monitoring or were calculated based on quantities used, received for use, or produced during the year. Using measured and calculated emissions, and building-specific and common parameters, Laboratory personnel applied the EPA-approved computer code, CAP88-PC, to calculate the effective dose equivalent to the maximally exposed individual (MEI). The effective dose equivalent from all sources at Berkeley Lab in 2009 is 7.0 x 10{sup -3} mrem/yr (7.0 x 10{sup -5} mSv/yr) to the MEI, well below the 10 mrem/yr (0.1 mSv/yr) dose standard. The location of the MEI is at the University of California (UC) Lawrence Hall of Science, a public science museum about 1500 ft (460 m) east of Berkeley Lab's Building 56. The estimated collective effective dose equivalent to persons living within 50 mi (80 km) of Berkeley Lab is 1.5 x 10{sup -1} person-rem (1.5 x 10{sup -3} person-Sv) attributable to the Lab's airborne emissions in 2009.

  3. Electronic Reporting of Air Emissions

    Science.gov (United States)

    EPA regulations require affected sources to perform emissions source tests, conduct continuous emissions monitoring, and submit compliance and emissions reports. This site provides technical resources and access for providing such submissions.

  4. Fast Emission Estimates in China Constrained by Satellite Observations (Invited)

    Science.gov (United States)

    Mijling, B.; van der A, R.

    2013-12-01

    Emission inventories of air pollutants are crucial information for policy makers and form important input data for air quality models. Unfortunately, bottom-up emission inventories, compiled from large quantities of statistical data, are easily outdated for an emerging economy such as China, where rapid economic growth changes emissions accordingly. Alternatively, top-down emission estimates from satellite observations of air constituents have important advantages of being spatial consistent, having high temporal resolution, and enabling emission updates shortly after the satellite data become available. Constraining emissions from concentration measurements is, however, computationally challenging. Within the GlobEmission project of the European Space Agency (ESA) a new algorithm has been developed, specifically designed for fast daily emission estimates of short-lived atmospheric species on a mesoscopic scale (0.25 × 0.25 degree) from satellite observations of column concentrations. The algorithm needs only one forward model run from a chemical transport model to calculate the sensitivity of concentration to emission, using trajectory analysis to account for transport away from the source. By using a Kalman filter in the inverse step, optimal use of the a priori knowledge and the newly observed data is made. We apply the algorithm for NOx emission estimates in East China, using the CHIMERE model together with tropospheric NO2 column retrievals of the OMI and GOME-2 satellite instruments. The observations are used to construct a monthly emission time series, which reveal important emission trends such as the emission reduction measures during the Beijing Olympic Games, and the impact and recovery from the global economic crisis. The algorithm is also able to detect emerging sources (e.g. new power plants) and improve emission information for areas where proxy data are not or badly known (e.g. shipping emissions). The new emission estimates result in a better

  5. 2008 LANL radionuclide air emissions report

    Energy Technology Data Exchange (ETDEWEB)

    Fuehne, David P.

    2009-06-01

    The emissions of radionuclides from Department of Energy Facilities such as Los Alamos National Laboratory (LANL) are regulated by the Amendments to the Clean Air Act of 1990, National Emissions Standards for Hazardous Air Pollutants (40 CFR 61 Subpart H). These regulations established an annual dose limit of 10 mrem to the maximally exposed member of the public attributable to emissions of radionuclides. This document describes the emissions of radionuclides from LANL and the dose calculations resulting from these emissions for calendar year 2008. This report meets the reporting requirements established in the regulations.

  6. 2010 LANL radionuclide air emissions report /

    Energy Technology Data Exchange (ETDEWEB)

    Fuehne, David P.

    2011-06-01

    The emissions of radionuclides from Department of Energy Facilities such as Los Alamos National Laboratory (LANL) are regulated by the Amendments to the Clean Air Act of 1990, National Emissions Standards for Hazardous Air Pollutants (40 CFR 61 Subpart H). These regulations established an annual dose limit of 10 mrem to the maximally exposed member of the public attributable to emissions of radionuclides. This document describes the emissions of radionuclides from LANL and the dose calculations resulting from these emissions for calendar year 2010. This report meets the reporting requirements established in the regulations.

  7. Some Environmental and Economic Aspects of Energy Saving Measures in Houses. An estimation model for total energy consumption and emissions to air from the Norwegian dwelling stock, and a life cycle assessment method for energy saving measures in houses

    Energy Technology Data Exchange (ETDEWEB)

    Myhre, L

    1995-12-01

    Motivated by the need to reduce the total energy consumption and the environmental load from society, this doctoral thesis discusses energy conservation measures on existing houses. Alternative additional thermal insulation measures are assessed using an interdisciplinary life cycle approach. The first task is to develop an interdisciplinary assessment method for building improvement measures, taking account of energy consumption, resource consumption, emissions to air of environmentally harmful gases, and economic costs during the entire life cycle of the building. The second task is to develop an estimation model for the total energy consumption and emissions to air of environmentally harmful gases from the dwelling stock of Norway. Finally, the third task is to assess the total energy saving potential and the total environmental benefits of energy saving measures in houses on a national level, including only life cycle analyses of additional thermal insulation measures on single houses. Chap 2 describes the dwelling stock in Norway. Chaps 3 and 4 present an estimation model for total energy consumption and emissions to air from the dwelling stock, and calculations using the model. Chaps 5 and 6 propose and use a calculation method for the assessment of additional thermal insulation measures, using a ``cradle-to-grave`` approach. Since hydroelectric power is the main energy source in this sector in Norway, estimated payback periods for emissions to air are long. But hydroelectric power saved in this sector may be used to obtain reduction in fossil fuel use in other sectors as discussed in Chap 7. Some of the topics discussed are further elaborated on in appendices. 107 refs., 39 figs, 88 tabs.

  8. Measurement of air pollutant emissions from Lome, Cotonou and Accra

    Science.gov (United States)

    Lee, James; Vaughan, Adam; Nelson, Bethany; Young, Stuart; Evans, Mathew; Morris, Eleanor; Ladkin, Russel

    2017-04-01

    High concentrations of airborne pollutants (e.g. the oxides of nitrogen, sulphur dioxide and carbon monoxide) in existing and evolving cities along the Guinea Coast cause respiratory diseases with potentially large costs to human health and the economic capacity of the local workforce. It is important to understand the rate of emission of such pollutants in order to model current and future air quality and provide guidance to the potential outcomes of air pollution abatement strategies. Often dated technologies and poor emission control strategies lead to substantial uncertainties in emission estimates calculated from vehicle and population number density statistics. The unreliable electrical supply in cities in the area has led to an increased reliance on small-scale diesel powered generators and these potentially present a significant source of emissions. The uncontrolled open incineration of waste adds a further very poorly constrained emission source within the cities. The DACCIWA (Dynamics-Aerosol-Chemistry-Cloud Interactions in West Africa) project involved a field campaign which used highly instrumented aircraft capable of in situ measurements of a range of air pollutants. Seven flights using the UK British Antarctic Survey's Twin Otter aircraft specifically targeted air pollution emissions from cities in West Africa (4 x Accra, Ghana; 2 x Lome, Togo and 1 x Cotonou, Benin). Measurements of NO, NO2, SO2, CO, CH4 and CO2 were made at multiple altitudes upwind and downwind of the cities, with the mass balance technique used to calculate emission rates. These are then compared to the Emissions Database for Global Atmospheric Research (EDGAR) estimates. Ultimately the data will be used to inform on and potentially improve the emission estimates, which in turn should lead to better forecasting of air pollution in West African cities and help guide future air pollution abatement strategy.

  9. Comparative estimation of soil and plant pollution in the impact area of air emissions from an aluminium plant after technogenic load reduction.

    Science.gov (United States)

    Evdokimova, Galina A; Mozgova, Natalya P

    2015-01-01

    The work provides a comparative analysis of changes in soil properties in the last 10-13 years along the pollution gradient of air emissions from Kandalaksha aluminium plant in connection with the reduction of their volume. The content of the priority pollutant fluorine (F) in atmospheric precipitation and in the organic horizon of soil in the plant impact zone significantly decreased in 2011-2013 compared to 2001. The aluminium concentrations reduced only in immediate proximity to the plant (2 km). The fluorine, calcium (Ca) and magnesium (Mg) concentrations are higher in liquid phase compared to solid phase thus these elements can migrated to greater distances from the pollution source (up to 15-20 km). Silicon (Si), aluminium (Al), iron (Fe) and phosphorus (P) can be found only in solid phases and in fall-out within the 5 km. The acidity of soil litter reduced by 2 pH units in the proximity to the plot within the 2 km. The zone of maximum soil contamination decreased from 2.5 km to 1.5 km from the emission source, the zones of heavy and moderate pollution reduced by 5 km in connection with the reduction of pollutant emissions in the plant. A high correlation between the fluorine concentrations in vegetables and litter was found. Higher fluorine concentrations in the soil result in its accumulation in plants. Mosses accumulate fluorine most intensively.

  10. A practical approach to estimate emission rates of indoor air pollutants due to the use of personal combustible products based on small-chamber studies.

    Science.gov (United States)

    Szulejko, Jan E; Kim, Ki-Hyun

    2016-02-01

    As emission rates of airborne pollutants are commonly measured from combusting substances placed inside small chambers, those values need to be re-evaluated for the possible significance under practical conditions. Here, a simple numerical procedure is investigated to extrapolate the chamber-based emission rates of formaldehyde that can be released from various combustible sources including e-cigarettes, conventional cigarettes, or scented candles to their concentration levels in a small room with relatively poor ventilation. This simple procedure relies on a mass balance approach by considering the masses of pollutants emitted from source and lost through ventilation under the assumption that mixing occurs instantaneously in the room without chemical reactions or surface sorption. The results of our study provide valuable insights into re-evaluation procedure of chamber data to allow comparison between extrapolated and recommended values to judge the safe use of various combustible products in confined spaces. If two scented candles with a formaldehyde emission rate of 310 µg h(-1) each were lit for 4 h in a small 20 m(3) room with an air change rate of 0.5 h(-1), then the 4-h (candle lit) and 8-h (up to 8 h after candle lighting) TWA [FA] were determined to be 28.5 and 23.5 ppb, respectively. This is clearly above the 8-h NIOSH recommended exposure limit (REL) time weighted average of 16 ppb. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. HFC-152a and HFC-134a emission estimates and characterization of CFCs, CFC replacements, and other halogenated solvents measured during the 2008 ARCTAS campaign (CARB phase) over the South Coast Air Basin of California

    Science.gov (United States)

    Barletta, B.; Nissenson, P.; Meinardi, S.; Dabdub, D.; Sherwood Rowland, F.; Vancuren, R. A.; Pederson, J.; Diskin, G. S.; Blake, D. R.

    2011-03-01

    This work presents results from the NASA Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) study. Whole air samples were obtained on board research flights that flew over California during June 2008 and analyzed for selected volatile organic compounds, including several halogenated species. Samples collected over the South Coast Air Basin of California (SoCAB), which includes much of Los Angeles (LA) County, were compared with samples from inflow air masses over the Pacific Ocean. The levels of many halocarbon species were enhanced significantly over the SoCAB, including compounds regulated by the Montreal Protocol and subsequent amendments. Emissions estimates of HFC-152a (1,1-difluoroethane, CH3CHF2; 0.82 ± 0.11 Gg) and HFC-134a (1,1,1,2-tetrafluoroethane, CH2FCF3; 1.16 ± 0.22 Gg) in LA County for 2008 were obtained using the observed HFC:carbon monoxide (CO) enhancement ratio. Emission rates also were calculated for the SoCAB (1.60 ± 0.22 Gg yr-1 for HFC-152a and 2.12 ± 0.28 Gg yr-1 for HFC-134a) and then extrapolated to the United States (32 ± 4 Gg yr-1 for HFC-152a and 43 ± 6 Gg yr-1 for HFC-134a) using population data. In addition, emission rates of the two HFCs in LA County and SoCAB were calculated by a second method that utilizes air quality modeling. Emissions estimates obtained using both methods differ by less than 25% for the LA County and less than 45% for the SoCAB.

  12. HFC-152a and HFC-134a emission estimates and characterization of CFCs, CFC replacements, and other halogenated solvents measured during the 2008 ARCTAS campaign (CARB phase over the South Coast Air Basin of California

    Directory of Open Access Journals (Sweden)

    B. Barletta

    2011-03-01

    Full Text Available This work presents results from the NASA Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS study. Whole air samples were obtained on board research flights that flew over California during June 2008 and analyzed for selected volatile organic compounds, including several halogenated species. Samples collected over the South Coast Air Basin of California (SoCAB, which includes much of Los Angeles (LA County, were compared with samples from inflow air masses over the Pacific Ocean. The levels of many halocarbon species were enhanced significantly over the SoCAB, including compounds regulated by the Montreal Protocol and subsequent amendments. Emissions estimates of HFC-152a (1,1-difluoroethane, CH3CHF2; 0.82 ± 0.11 Gg and HFC-134a (1,1,1,2-tetrafluoroethane, CH2FCF3; 1.16 ± 0.22 Gg in LA County for 2008 were obtained using the observed HFC:carbon monoxide (CO enhancement ratio. Emission rates also were calculated for the SoCAB (1.60 ± 0.22 Gg yr−1 for HFC-152a and 2.12 ± 0.28 Gg yr−1 for HFC-134a and then extrapolated to the United States (32 ± 4 Gg yr−1 for HFC-152a and 43 ± 6 Gg yr−1 for HFC-134a using population data. In addition, emission rates of the two HFCs in LA County and SoCAB were calculated by a second method that utilizes air quality modeling. Emissions estimates obtained using both methods differ by less than 25% for the LA County and less than 45% for the SoCAB.

  13. AIR EMISSIONS FROM SCRAP TIRE COMBUSTION

    Science.gov (United States)

    The report discusses air emissions from two types of scrap tire combustion: uncontrolled and controlled. Uncontrolled sources are open tire fires, which produce many unhealthful products of incomplete combustion and release them directly into the atmosphere. Controlled combustion...

  14. The Impact of Uncertainties in African Biomass Burning Emission Estimates on Modeling Global Air Quality, Long Range Transport and Tropospheric Chemical Lifetimes

    Directory of Open Access Journals (Sweden)

    Guido R. van der Werf

    2012-02-01

    Full Text Available The chemical composition of the troposphere in the tropics and Southern Hemisphere (SH is significantly influenced by gaseous emissions released from African biomass burning (BB. Here we investigate how various emission estimates given in bottom-up BB inventories (GFEDv2, GFEDv3, AMMABB affect simulations of global tropospheric composition using the TM4 chemistry transport model. The application of various model parameterizations for introducing such emissions is also investigated. There are perturbations in near-surface ozone (O3 and carbon monoxide (CO of ~60–90% in the tropics and ~5–10% in the SH between different inventories. Increasing the update frequency of the temporal distribution to eight days generally results in decreases of between ~5 and 10% in near-surface mixing ratios throughout the tropics, which is larger than the influence of increasing the injection heights at which BB emissions are introduced. There are also associated differences in the long range transport of pollutants throughout the SH, where the composition of the free troposphere in the SH is sensitive to the chosen BB inventory. Analysis of the chemical budget terms reveals that the influence of increasing the tropospheric CO burden due to BB on oxidative capacity of the troposphere is mitigated by the associated increase in NOx emissions (and thus O3 with the variations in the CO/N ratio between inventories being low. For all inventories there is a decrease in the tropospheric chemical lifetime of methane of between 0.4 and 0.8% regardless of the CO emitted from African BB. This has implications for assessing the effect of inter-annual variability in BB on the annual growth rate of methane.

  15. Data structure for estimating emissions from non-road sources

    Energy Technology Data Exchange (ETDEWEB)

    Sorenson, S C; Kalivoda, M; Vacarro, R; Trozzi, C; Samaras, Z; Lewis, C A

    1997-03-01

    The work described in the following is a portion of the MEET project (Methodologies for Estimation Air Pollutant Emissions from Transport). The overall goal of the MEET project is to consolidate and present methodologies which can be used to estimate air pollutant emissions from various types of traffic sources. One of the goals of MEET is to provide methodologies to be used in the COMMUTE project also funded by DG VII. COMMUTE is developing computer software which can be used to provide emissions inventories on the European scale. Although COMMUTE is viewed as a prime user of the information generated in MEET, the MEET results are intended to be used in a broader area, and on both smaller and larger spatial scales. The methodologies and data presented will be useful for planners on a more local scale than a national or continental basis. While most attention in previous years has been concentrated on emissions from road transport, it has become increasingly apparent in later years that the so-called off road transportation contributes significantly to the emission of air pollutants. The three most common off-road traffic modes are Air Traffic, Rail Traffic, and Ship or Marine traffic. In the following, the basic structure of the methods for estimating the emissions from these sectors will be given and of the input and output data associated with these calculations. The structures will of necessity be different for the different types of traffic. The data structures in the following reflect these variations and uncertainties. In some instances alternative approaches to emissions estimation will be suggested. The user must evaluate the amount and reliability of available data for the application at hand, and select the method which would be expected to give the highest accuracy. In any event, a large amount of uncertainty is inherent in the estimation of emissions from the non-road traffic sources, particularly those involving rail and maritime transport. (EG)

  16. Estimation of automobile emissions and control strategies in India.

    Science.gov (United States)

    Nesamani, K S

    2010-03-15

    Rapid, but unplanned urban development and the consequent urban sprawl coupled with economic growth have aggravated auto dependency in India over the last two decades. This has resulted in congestion and pollution in cities. The central and state governments have taken many ameliorative measures to reduce vehicular emissions. However, evolution of scientific methods for emission inventory is crucial. Therefore, an attempt has been made to estimate the emissions (running and start) from on-road vehicles in Chennai using IVE model in this paper. GPS was used to collect driving patterns. The estimated emissions from motor vehicles in Chennai in 2005 were 431, 119, 46, 7, 4575, 29, and 0.41 tons/days respectively for CO, VOC, NO(x), PM, CO(2,) CH(4) and N(2)O. It is observed from the results that air quality in Chennai has degraded. The estimation revealed that two and three-wheelers emitted about 64% of the total CO emissions and heavy-duty vehicles accounted for more than 60% and 36% of the NO(x) and PM emissions respectively. About 19% of total emissions were that of start emissions. It is also estimated that on-road transport contributes about 6637 tons/day CO(2) equivalent in Chennai. This paper has further examined various mitigation options to reduce vehicular emissions. The study has concluded that advanced vehicular technology and augmentation of public transit would have significant impact on reducing vehicular emissions.

  17. Estimation of Turkish road transport emissions

    International Nuclear Information System (INIS)

    Soylu, Seref

    2007-01-01

    Using the COPERT III program, an inventory of Turkish road transport emissions was calculated and the contributions of road transport to global and local air pollutant emissions were examined for the year 2004. It was observed that passenger cars are the main source of CO, HC, and Pb emissions while heavy duty vehicles are mainly responsible for NO x , particulate matter (PM), and SO 2 emissions. Taking the emissions for the year 2004 as the baseline, a parametric study was conducted to determine the emission reduction potentials of different road transport strategies. The results indicated that the following road transport strategies; fleet renewal, promotion of public transportation, and faster urban traffic speed are very effective strategies for reducing regulated emissions and fuel consumption (FC) from a technical point of view. It was also noted that replacement of two-stroke motorcycles with four-stroke motorcycles is as effective as fleet renewal in reducing HC emissions

  18. Cordon Pricing Considering Air Pollutants Emission

    Directory of Open Access Journals (Sweden)

    Shahriar Afandizadeh

    2016-04-01

    Full Text Available This paper considers the issue of air pollutants emission for the optimal and sustainable determination of cordon location, toll level, and price of park and ride (P&R. Although air pollutants emission decreases within the cordon by the implementation of cordon pricing scheme, it may increase outside the cordon and the whole network. Hence, air pollutants emission may only transfer from inside of the cordon to its outside. Therefore, in this paper, a multi-objective bi-level optimization model is developed. A solution algorithm is also presented based on the second version of strength Pareto evolutionary algorithm (SPEA2. The results reveal that this multi-objective model can be a useful tool for the sustainable and optimal design of the cordon and P&R scheme. In addition, cordon pricing is a multi-objective problem. Therefore, it is necessary to consider air pollutants emission. By choosing another non-dominated result in the solution space, air pollutants emission outside the cordon and the whole network can be reduced without a significant reduction in social welfare.

  19. 77 FR 16508 - National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins...

    Science.gov (United States)

    2012-03-21

    ... National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins; Pesticide... Hazardous Air Pollutant Emissions: Group IV Polymers and Resins; National Emission Standards for Hazardous... proposed rule titled, National Emission Standards for Hazardous Air Pollutant Emissions: Group IV Polymers...

  20. Alberta air emissions : trends and projections

    International Nuclear Information System (INIS)

    2008-06-01

    This paper provided a summary of air emissions trends and projections for Alberta. Predicted regional distribution trends and industry sector emissions were presented. Historical and projected emissions included sulfur oxides (SO x ) nitrogen oxide (NO x ), volatile organic compounds (VOCs), and ammonia (NH 3 ). Results of the study indicated that carbon monoxide (CO) emissions were decreasing, while VOCs, NO x , SO x , PM 2.5 and NH 3 levels were increasing. Approximately 9 per cent of ammonia emissions were from point sources, while the majority of PM 2.5 emissions were attributed to unpaved roads and construction operations. Agricultural animal operations accounted for most of the VOC source emissions in the region. Increased development of the oil sands industry is contributing to increases in VOC emissions. Increases in NH 3 were attributed to growth in the agricultural sector and the increasing use of confined feeding operations in the region. Results of the study indicated that greenhouse gas (GHG) emissions in Alberta will keep increasing as a result of Alberta's growing economy. It was concluded that emissions from other industrial sectors are also expected to increase. In 2005, Alberta's total GHG emissions were 233 megatonnes of CO 2 equivalent, of which 168 megatonnes were attributed to industry. Results were presented in both graph and tabular formats. 3 tabs., 25 figs

  1. Estimation of fugitive dust emissions in opencast mines

    Energy Technology Data Exchange (ETDEWEB)

    Mukherjee, M. [MECON Ltd., Ranchi (India). Environmental Engineering Division

    2001-02-01

    Fugitive dusts being the most annoying air pollutant in opencast mines, estimation of the fugitive dust level at ongoing sites and also prediction of dust level for the future years is important. A rapid increase in the percentage of surface mining to support an optimistic industrial growth rate at core sector has raised alarms owing to the apprehension of phenomenal increase of dust level in mine air. Fairly accurate estimation of dust dispersion level is a prerequisite to designing adequacy and suitability of a dedusting system. Determination of emission factors suited to various geomining conditions is an important basic step towards this direction. In advanced countries research work has been carried out at the national level to evolve emission factors in mining and industry. Till now no concerted effort has been attempted in India for this. In the present paper the author has utilised limited data to discuss fugitive dust emission factors for various operations for mining. 9 refs., 2 tabs.

  2. 2014 LANL Radionuclide Air Emissions Report

    Energy Technology Data Exchange (ETDEWEB)

    Fuehne, David Patrick [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-07-21

    This report describes the emissions of airborne radionuclides from operations at Los Alamos National Laboratory (LANL) for calendar year 2014, and the resulting off-site dose from these emissions. This document fulfills the requirements established by the National Emissions Standards for Hazardous Air Pollutants in 40 CFR 61, Subpart H – Emissions of Radionuclides other than Radon from Department of Energy Facilities, commonly referred to as the Radionuclide NESHAP or Rad-NESHAP. Compliance with this regulation and preparation of this document is the responsibility of LANL’s RadNESHAP compliance program, which is part of the Environmental Protection Division. The information in this report is required under the Clean Air Act and is being submitted to the U.S. Environmental Protection Agency (EPA) Region 6.

  3. Characterization of particulate emissions from Australian open-cut coal mines: Toward improved emission estimates.

    Science.gov (United States)

    Richardson, Claire; Rutherford, Shannon; Agranovski, Igor

    2018-06-01

    Given the significance of mining as a source of particulates, accurate characterization of emissions is important for the development of appropriate emission estimation techniques for use in modeling predictions and to inform regulatory decisions. The currently available emission estimation methods for Australian open-cut coal mines relate primarily to total suspended particulates and PM 10 (particulate matter with an aerodynamic diameter available relating to the PM 2.5 (currently available emission estimation techniques, this paper presents results of sampling completed at three open-cut coal mines in Australia. The monitoring data demonstrate that the particulate size fraction varies for different mining activities, and that the region in which the mine is located influences the characteristics of the particulates emitted to the atmosphere. The proportion of fine particulates in the sample increased with distance from the source, with the coarse fraction being a more significant proportion of total suspended particulates close to the source of emissions. In terms of particulate composition, the results demonstrate that the particulate emissions are predominantly sourced from naturally occurring geological material, and coal comprises less than 13% of the overall emissions. The size fractionation exhibited by the sampling data sets is similar to that adopted in current Australian emission estimation methods but differs from the size fractionation presented in the U.S. Environmental Protection Agency methodology. Development of region-specific emission estimation techniques for PM 10 and PM 2.5 from open-cut coal mines is necessary to allow accurate prediction of particulate emissions to inform regulatory decisions and for use in modeling predictions. Development of region-specific emission estimation techniques for PM 10 and PM 2.5 from open-cut coal mines is necessary to allow accurate prediction of particulate emissions to inform regulatory decisions and for

  4. Biofuels, vehicle emissions, and urban air quality.

    Science.gov (United States)

    Wallington, Timothy J; Anderson, James E; Kurtz, Eric M; Tennison, Paul J

    2016-07-18

    Increased biofuel content in automotive fuels impacts vehicle tailpipe emissions via two mechanisms: fuel chemistry and engine calibration. Fuel chemistry effects are generally well recognized, while engine calibration effects are not. It is important that investigations of the impact of biofuels on vehicle emissions consider the impact of engine calibration effects and are conducted using vehicles designed to operate using such fuels. We report the results of emission measurements from a Ford F-350 fueled with either fossil diesel or a biodiesel surrogate (butyl nonanoate) and demonstrate the critical influence of engine calibration on NOx emissions. Using the production calibration the emissions of NOx were higher with the biodiesel fuel. Using an adjusted calibration (maintaining equivalent exhaust oxygen concentration to that of the fossil diesel at the same conditions by adjusting injected fuel quantities) the emissions of NOx were unchanged, or lower, with biodiesel fuel. For ethanol, a review of the literature data addressing the impact of ethanol blend levels (E0-E85) on emissions from gasoline light-duty vehicles in the U.S. is presented. The available data suggest that emissions of NOx, non-methane hydrocarbons, particulate matter (PM), and mobile source air toxics (compounds known, or suspected, to cause serious health impacts) from modern gasoline and diesel vehicles are not adversely affected by increased biofuel content over the range for which the vehicles are designed to operate. Future increases in biofuel content when accomplished in concert with changes in engine design and calibration for new vehicles should not result in problematic increases in emissions impacting urban air quality and may in fact facilitate future required emissions reductions. A systems perspective (fuel and vehicle) is needed to fully understand, and optimize, the benefits of biofuels when blended into gasoline and diesel.

  5. Air Quality Modelling and the National Emission Database

    DEFF Research Database (Denmark)

    Jensen, S. S.

    The project focuses on development of institutional strengthening to be able to carry out national air emission inventories based on the CORINAIR methodology. The present report describes the link between emission inventories and air quality modelling to ensure that the new national air emission...... inventory is able to take into account the data requirements of air quality models...

  6. Methods of valuing air pollution and estimated monetary values of air pollutants in various U.S. regions

    Energy Technology Data Exchange (ETDEWEB)

    Wang, M.Q.; Santini, D.J.; Warinner, S.A.

    1994-12-01

    Air pollutant emission values are used to determine the social costs of various technologies that cause air pollution and to estimate the benefits of emission control technologies. In this report, the authors present two methods of estimating air pollutant emission values--the damage value method and the control cost method--and review 15 recent studies in which these methods were employed to estimate emission values. The reviewed studies derived emission values for only a limited number of areas; emission value estimates are needed for other US regions. Using the emission values estimated in the reviewed studies, they establish regression relationships between emission values, air pollutant concentrations, and total population exposed, and apply the established relationships to 17 US metropolitan areas to estimate damage-based and control-cost-based emission values for reactive organic gases, nitrogen oxides, particulate matter measuring less than 10 microns, sulfur oxides, and carbon monoxide in these areas. Their estimates show significant variations in emission values across the 17 regions.

  7. Sequim Site Radionuclide Air Emissions Report for Calendar Year 2012

    Energy Technology Data Exchange (ETDEWEB)

    Snyder, Sandra F.; Barnett, J. Matthew; Gervais, Todd L.

    2013-04-01

    This report is prepared to document compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities and ashington Administrative Code (WAC) Chapter 246-247, Radiation Protection Air Emissions. This report meets the calendar year 2012 Sequim Site annual reporting requirement for its operations as a privately-owned facility as well as its federally-contracted status that began in October 2012. Compliance is indicated by comparing the estimated dose to the maximally exposed individual (MEI) with the 10 mrem/yr Environmental Protection Agency (EPA) standard. The MSL contains only sources classified as fugitive emissions. Despite the fact that the regulations are intended for application to point source emissions, fugitive emissions are included with regard to complying with the EPA standard. The dose to the Sequim Site MEI due to routine operations in 2012 was 9E-06 mrem (9E-08 mSv). No non-routine emissions occurred in 2012. The MSL is in compliance with the federal and state 10 mrem/yr standard.

  8. New Approaches for Estimating Motor Vehicle Emissions in Megacities

    Science.gov (United States)

    Marr, L. C.; Thornhill, D. A.; Herndon, S. C.; Onasch, T. B.; Wood, E. C.; Kolb, C. E.; Knighton, W. B.; Mazzoleni, C.; Zavala, M. A.; Molina, L. T.

    2007-12-01

    The rapid proliferation of megacities and their air quality problems is producing unprecedented air pollution health risks and management challenges. Quantifying motor vehicle emissions in the developing world's megacities, where vehicle ownership is skyrocketing, is critical for evaluating the cities' impacts on the atmosphere at urban, regional, and global scales. The main goal of this research is to quantify gasoline- and diesel-powered motor vehicle emissions within the Mexico City Metropolitan Area (MCMA). We apply positive matrix factorization to fast measurements of gaseous and particulate pollutants made by the Aerodyne Mobile Laboratory as it drove throughout the MCMA in 2006. We consider carbon dioxide; carbon monoxide; volatile organic compounds including benzene and formaldehyde; nitrogen oxides; ammonia; fine particulate matter; particulate polycyclic aromatic hydrocarbons; and black carbon. Analysis of the video record confirms the apportionment of emissions to different engine types. From the derived source profiles, we calculate fuel-based fleet-average emission factors and then estimate the total motor vehicle emission inventory. The advantages of this method are that it can capture a representative sample of vehicles in a variety of on-road driving conditions and can separate emissions from gasoline versus diesel engines. The results of this research can be used to help assess the accuracy of emission inventories and to guide the development of strategies for reducing vehicle emissions.

  9. Emission inventory estimation of an intercity bus terminal.

    Science.gov (United States)

    Qiu, Zhaowen; Li, Xiaoxia; Hao, Yanzhao; Deng, Shunxi; Gao, H Oliver

    2016-06-01

    Intercity bus terminals are hotspots of air pollution due to concentrated activities of diesel buses. In order to evaluate the bus terminals' impact on air quality, it is necessary to estimate the associated mobile emission inventories. Since the vehicles' operating condition at the bus terminal varies significantly, conventional calculation of the emissions based on average emission factors suffers the loss of accuracy. In this study, we examined a typical intercity bus terminal-the Southern City Bus Station of Xi'an, China-using a multi-scale emission model-(US EPA's MOVES model)-to quantity the vehicle emission inventory. A representative operating cycle for buses within the station is constructed. The emission inventory was then estimated using detailed inputs including vehicle ages, operating speeds, operating schedules, and operating mode distribution, as well as meteorological data (temperature and humidity). Five functional areas (bus yard, platforms, disembarking area, bus travel routes within the station, and bus entrance/exit routes) at the terminal were identified, and the bus operation cycle was established using the micro-trip cycle construction method. Results of our case study showed that switching to compressed natural gas (CNG) from diesel fuel could reduce PM2.5 and CO emissions by 85.64 and 6.21 %, respectively, in the microenvironment of the bus terminal. When CNG is used, tail pipe exhaust PM2.5 emission is significantly reduced, even less than brake wear PM2.5. The estimated bus operating cycles can also offer researchers and policy makers important information for emission evaluation in the planning and design of any typical intercity bus terminals of a similar scale.

  10. Estimation of vehicular emissions using dynamic emission factors: A case study of Delhi, India

    Science.gov (United States)

    Mishra, Dhirendra; Goyal, P.

    2014-12-01

    The estimation of vehicular emissions depends mainly on the values of emission factors, which are used for the development of a comprehensive emission inventory of vehicles. In this study the variations of emission factors as well as the emission rates have been studied in Delhi. The implementation of compressed natural gas (CNG), in the diesel and petrol, public vehicles in the year 2001 has changed the complete air quality scenario of Delhi. The dynamic emission factors of criteria pollutants viz. carbon monoxide (CO), nitrogen oxide (NOx) and particulate matter (PM10) for all types of vehicles have been developed after, which are based on the several factors such as regulated emission limits, number of vehicle deterioration, vehicle increment, vehicle age etc. These emission factors are found to be decreased continuously throughout the study years 2003-2012. The International Vehicle Emissions (IVE) model is used to estimate the emissions of criteria pollutants by utilizing a dataset available from field observations at different traffic intersections in Delhi. Thus the vehicular emissions, based on dynamic emission factors have been estimated for the years 2003-2012, which are found to be comparable with the monitored concentrations at different locations in Delhi. It is noticed that the total emissions of CO, NOx, and PM10 are increased by 45.63%, 68.88% and 17.92%, respectively up to the year 2012 and the emissions of NOx and PM10 are grown continuously with an annual average growth rate of 5.4% and 1.7% respectively.

  11. Using GIS to study the health impact of air emissions.

    Science.gov (United States)

    Dent, A L; Fowler, D A; Kaplan, B M; Zarus, G M; Henriques, W D

    2000-02-01

    Geographical Information Systems (GIS) is a fast-developing technology with an ever-increasing number of applications. Air dispersion modeling is a well-established discipline that can produce results in a spatial context. The marriage of these two applications is optimal because it leverages the predictive capacity of modeling with the data management, analysis, and display capabilities of GIS. In the public health arena, exposure estimation techniques are invaluable. The utilization of air emission data, such as U.S. EPA Toxic Release Inventory (TRI) data, and air dispersion modeling with GIS enable public health professionals to identify and define the potentially exposed population, estimate the health risk burden of that population, and determine correlations between point-based health outcome results with estimated health risk.

  12. Emissions and Air Quality Impacts of Freight Transportation

    Science.gov (United States)

    Bickford, Erica

    the photochemically modeled WIFE inventory against satellite retrievals of NO2 from OMI showed better spatial agreement between WIFE and OMI compared to another diesel inventory (LADCO), however with larger bias and error, especially in urban areas. This preliminary analysis illustrates the utility of satellite data in evaluating air quality model performance, and constraining surface emissions estimates.

  13. Estimation of shipping emissions in Candarli Gulf, Turkey.

    Science.gov (United States)

    Deniz, Cengiz; Kilic, Alper; Civkaroglu, Gökhan

    2010-12-01

    Ships are significant air pollution sources as their high powered main engines often use heavy fuels. The major atmospheric components emitted are nitrogen oxides, particulate matter (PM), sulfur oxide gases, carbon oxides, and toxic air pollutants. Shipping emissions cause severe impacts on health and environment. These effects of emissions are emerged especially in territorial waters, inland seas, canals, straits, bays, and port regions. Candarli Gulf is one of the major industrial regions on the Aegean side of Turkey. The marine environment of the region is affected by emissions from ships calling to ten different ports. In this study, NO( x ), SO(2), CO(2), hydrocarbons (HC), and PM emissions from 7,520 ships are estimated during the year of 2007. These emissions are classified regarding operation modes and types of ships. Annual shipping emissions are estimated as 631.2 t year(-1) for NO(x), 573.6 t year(-1) for SO(2), 33,848.9 t year(-1) for CO(2), 32.3 t year(-1) for HC, and 57.4 t year(-1) for PM.

  14. Review of maritime transportation air emission pollution and policy analysis

    Science.gov (United States)

    Wang, Haifeng; Liu, Dahai; Dai, Guilin

    2009-09-01

    The study of air emission in maritime transportation is new, and the recognition of its importance has been rising in the recent decade. The emissions of CO2, SO2, NO2 and particulate matters from maritime transportation have contributed to climate change and environmental degradation. Scientifically, analysts still have controversies regarding how to calculate the emissions and how to choose the baseline and methodologies. Three methods are generally used, namely the ‘bottom up’ approach, the ‘top down’ approach and the STEEM, which produce very different results, leading to various papers with great uncertainties. This, in turn, results in great difficulties to policy makers who attempt to regulate the emissions. A recent technique, the STEEM, is intended to combine the former two methods to reduce their drawbacks. However, the regulations based on its results may increase the costs of shipping companies and cause the competitiveness of the port states and coastal states. Quite a few papers have focused on this area and provided another fresh perspective for the air emission to be incorporated in maritime transportation regulations; these facts deserve more attention. This paper is to review the literature on the debates over air emission calculation, with particular attention given to the STEEM and the refined estimation methods. It also reviews related literature on the economic analysis of maritime transportation emission regulations, and provides an insight into such analysis. At the end of this paper, based on a review and analysis of previous literature, we conclude with the policy indications in the future and work that should be done. As the related regulations in maritime transportation emissions are still at their beginning stage in China, this paper provides specific suggestions on how China should regulate emissions in the maritime transportation sector.

  15. Estimating Vehicular Emission in Kathmandu Valley, Nepal

    Directory of Open Access Journals (Sweden)

    Krishna Prasad Ghimire

    2014-12-01

    Full Text Available The study estimate, the vehicular emission load for CO, CO2 , HCs, NOX, SO2, Dioxin/Furans, Particulate Matters (PM10, PM2.5, Black carbon and Organic Carbon by using emission factors and Global Warming Potentials (GWPs of the pollutants (CO2, NOX, BC and OC. For this purpose, data were collected through the video tape record (in 30 sites, questionnaire survey, field visit, and literatures review. The total estimated emission of Kathmandu Valley (KV was 7231053.12 ton/year. Of the total emission, CO2 emission was highest i.e., 91.01% followed by CO 5.03%, HC 0.96%, NOX 0.60%, PM10 0.18% and SO2 0.10%. Annually 529353.36 μg Toxic Equivalent (TEQ of Dioxin/Furan produced and directly disperse to the ambient environment. The total estimated PM2.5, BC and OC emission were 9649.40 ton/year, 1640.4 ton/year and 2894.82 ton/year. The total carbon equivalence of the combined emissions (CO2, NOX and BC for 100-years standard time horizon is 10579763.6 ton CO2-eq i.e., 2885390.07 ton carbon.CO2 alone will be responsible, for about 62% of the impacts for the next century from current emissions of CO2, NOX and BC. Of the total emission Heavy Duty Vehicles (HDV emits 50%, Light Duty Vehicles (LDV emits, 27%, 2-Wheelers emits 22% and 3-Wheeler (Tempo emits 1%. The total emission of all pollutants combined per vehicle together was estimated to be 5.46 ton/year which was estimated as 23.63, 10.35, 1.83 and 5.58 ton/year for HDV, LDV, 2-Wheelers and 3-Wheeler respectively. DOI: http://dx.doi.org/10.3126/ije.v3i4.11742      International Journal of EnvironmentVolume-3, Issue-4, Sep-Nov 2014Page: 133-146 

  16. Comparison of emissions inventories of anthropogenic air pollutants and greenhouse gases in China

    Science.gov (United States)

    Saikawa, Eri; Kim, Hankyul; Zhong, Min; Avramov, Alexander; Zhao, Yu; Janssens-Maenhout, Greet; Kurokawa, Jun-ichi; Klimont, Zbigniew; Wagner, Fabian; Naik, Vaishali; Horowitz, Larry W.; Zhang, Qiang

    2017-05-01

    Anthropogenic air pollutant emissions have been increasing rapidly in China, leading to worsening air quality. Modelers use emissions inventories to represent the temporal and spatial distribution of these emissions needed to estimate their impacts on regional and global air quality. However, large uncertainties exist in emissions estimates. Thus, assessing differences in these inventories is essential for the better understanding of air pollution over China. We compare five different emissions inventories estimating emissions of carbon dioxide (CO2), carbon monoxide (CO), nitrogen oxides (NOx), sulfur dioxide (SO2), and particulate matter with an aerodynamic diameter of 10 µm or less (PM10) from China. The emissions inventories analyzed in this paper include the Regional Emission inventory in ASia v2.1 (REAS), the Multi-resolution Emission Inventory for China (MEIC), the Emission Database for Global Atmospheric Research v4.2 (EDGAR), the inventory by Yu Zhao (ZHAO), and the Greenhouse Gas and Air Pollution Interactions and Synergies (GAINS). We focus on the period between 2000 and 2008, during which Chinese economic activities more than doubled. In addition to national totals, we also analyzed emissions from four source sectors (industry, transport, power, and residential) and within seven regions in China (East, North, Northeast, Central, Southwest, Northwest, and South) and found that large disagreements exist among the five inventories at disaggregated levels. These disagreements lead to differences of 67 µg m-3, 15 ppbv, and 470 ppbv for monthly mean PM10, O3, and CO, respectively, in modeled regional concentrations in China. We also find that all the inventory emissions estimates create a volatile organic compound (VOC)-limited environment and MEIC emissions lead to much lower O3 mixing ratio in East and Central China compared to the simulations using REAS and EDGAR estimates, due to their low VOC emissions. Our results illustrate that a better

  17. New global fire emission estimates and evaluation of volatile organic compounds

    Science.gov (United States)

    C. Wiedinmyer; L. K. Emmons; S. K. Akagi; R. J. Yokelson; J. J. Orlando; J. A. Al-Saadi; A. J. Soja

    2010-01-01

    A daily, high-resolution, global fire emissions model has been built to estimate emissions from open burning for air quality modeling applications: The Fire INventory from NCAR (FINN version 1). The model framework uses daily fire detections from the MODIS instruments and updated emission factors, specifically for speciated non-methane organic compounds (NMOC). Global...

  18. Ship emissions and air pollution in Denmark

    DEFF Research Database (Denmark)

    Olesen, Helge Rørdam; Winther, Morten; Ellermann, Thomas

    A project has been carried out to map the contribution from ship traffic to air pollution in Denmark. A main element in the project is the establishment of a new, improved inventory of ship emissions for the waters around Denmark. The inventory makes use of the so-called AIS system, which...... continuously keeps track of ship positions. The inventory provides basis for model calculations of air quality in Denmark for the years 2007, 2011 and 2020. The study has focus on identifying the contribution from ships, and on assessing the effect of international regulations of ship pollution. A minor...... component of the study concerns the contribution to local air pollution from ships at port....

  19. Different methodologies to quantify uncertainties of air emissions.

    Science.gov (United States)

    Romano, Daniela; Bernetti, Antonella; De Lauretis, Riccardo

    2004-10-01

    Characterization of the uncertainty associated with air emission estimates is of critical importance especially in the compilation of air emission inventories. In this paper, two different theories are discussed and applied to evaluate air emissions uncertainty. In addition to numerical analysis, which is also recommended in the framework of the United Nation Convention on Climate Change guidelines with reference to Monte Carlo and Bootstrap simulation models, fuzzy analysis is also proposed. The methodologies are discussed and applied to an Italian example case study. Air concentration values are measured from two electric power plants: a coal plant, consisting of two boilers and a fuel oil plant, of four boilers; the pollutants considered are sulphur dioxide (SO(2)), nitrogen oxides (NO(X)), carbon monoxide (CO) and particulate matter (PM). Monte Carlo, Bootstrap and fuzzy methods have been applied to estimate uncertainty of these data. Regarding Monte Carlo, the most accurate results apply to Gaussian distributions; a good approximation is also observed for other distributions with almost regular features either positive asymmetrical or negative asymmetrical. Bootstrap, on the other hand, gives a good uncertainty estimation for irregular and asymmetrical distributions. The logic of fuzzy analysis, where data are represented as vague and indefinite in opposition to the traditional conception of neatness, certain classification and exactness of the data, follows a different description. In addition to randomness (stochastic variability) only, fuzzy theory deals with imprecision (vagueness) of data. Fuzzy variance of the data set was calculated; the results cannot be directly compared with empirical data but the overall performance of the theory is analysed. Fuzzy theory may appear more suitable for qualitative reasoning than for a quantitative estimation of uncertainty, but it suits well when little information and few measurements are available and when

  20. Radioactive air emissions notice of construction portable temporary radioactive air emission units - August 1998; FINAL

    International Nuclear Information System (INIS)

    FRITZ, D.W.

    1999-01-01

    This notice of construction (NOC) requests a categorical approval for construction and operation of three types of portable/temporary radionuclide airborne emission units (PTRAEUs). These three types are portable ventilation-filter systems (Type I), mobile sample preparation facilities (Type II), and mobile sample screening and analysis facilities (Type 111). Approval of the NOC application is intended to allow construction and operation of the three types of PTRAEUs without prior project-specific approval. Environmental cleanup efforts on the Hanford Site often require the use of PTRAEUs. The PTRAEUs support site characterization activities, expedited response actions (ERAs), sampling and monitoring activities, and other routine activities. The PTRAEUs operate at various locations around the Hanford Site. Radiation Air Emissions Program, Washington Administrative Code (WAC) 246-247, requires that the Washington State Department of Health (WDOH) be notified before construction of any new emission that would release airborne radioactivity. The WDOH also must receive notification before any modification of an existing source. This includes changes in the source term or replacement of emission control equipment that might significantly contribute to the offsite maximum dose from a licensed facility. During site characterization activities, ERAs, sampling and monitoring activities, and other routine activities, the PTRAEUs might require startup immediately. The notification period hampers efforts to complete such activities in an effective and timely manner. Additionally, notification is to be submitted to the WDOH when the PTRAEUs are turned off. The U.S. Department of Energy, Richland Operations Office (DOE-RL) potentially could generate several notifications monthly. The WDOH would be required to review and provide approval on each NOC as well as review the notices of discontinued sources. The WDOH regulation also allows facilities the opportunity to request a

  1. Estimating the Biogenic Non-Methane Hydrocarbon Emissions over Greece

    Directory of Open Access Journals (Sweden)

    Ermioni Dimitropoulou

    2018-01-01

    Full Text Available Biogenic emissions affect the urban air quality as they are ozone and secondary organic aerosol (SOA precursors and should be taken into account when applying photochemical pollution models. The present study presents an estimation of the magnitude of non-methane volatile organic compounds (BNMVOCs emitted by vegetation over Greece. The methodology is based on computation developed with the aid of a Geographic Information System (GIS and theoretical equations in order to produce an emission inventory on a 6 × 6 km2 spatial resolution, in a temporal resolution of 1 h covering one year (2016. For this purpose, a variety of input data was used: updated satellite land-use data, land-use specific emission potentials, foliar biomass densities, temperature, and solar radiation data. Hourly, daily, and annual isoprene, monoterpenes, and other volatile organic compounds (OVOCs were estimated. In the area under study, the annual biogenic emissions were estimated up to 472 kt, consisting of 46.6% isoprene, 28% monoterpenes, and 25.4% OVOCs. Results delineate an annual cycle with increasing values from March to April, while maximum emissions were observed from May to September, followed by a decrease from October to January.

  2. CMS: CO2 Signals Estimated for Fossil Fuel Emissions and Biosphere Flux, California

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set provides estimated CO2 emission signals for 16 regions (air quality basins) in California, USA, during the individual months of November 2010 and May...

  3. EMISSIONS OF ORGANIC AIR TOXICS FROM OPEN ...

    Science.gov (United States)

    A detailed literature search was performed to collect and collate available data reporting emissions of toxic organic substances into the air from open burning sources. Availability of data varied according to the source and the class of air toxics of interest. Volatile organic compound (VOC) and polycyclic aromatic hydrocarbon (PAH) data were available for many of the sources. Data on semivolatile organic compounds (SVOCs) that are not PAHs were available for several sources. Carbonyl and polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofuran (PCDD/F) data were available for only a few sources. There were several sources for which no emissions data were available at all. Several observations were made including: 1) Biomass open burning sources typically emitted less VOCs than open burning sources with anthropogenic fuels on a mass emitted per mass burned basis, particularly those where polymers were concerned; 2) Biomass open burning sources typically emitted less SVOCs and PAHs than anthropogenic sources on a mass emitted per mass burned basis. Burning pools of crude oil and diesel fuel produced significant amounts of PAHs relative to other types of open burning. PAH emissions were highest when combustion of polymers was taking place; and 3) Based on very limited data, biomass open burning sources typically produced higher levels of carbonyls than anthropogenic sources on a mass emitted per mass burned basis, probably due to oxygenated structures r

  4. Bounding estimate of DWPF mercury emissions

    International Nuclear Information System (INIS)

    Jacobs, R.A.

    1992-01-01

    Purges required for H2 flammability control and verification of elevated Formic Acid Vent Condenser (FAVC) exit temperatures due to NO x reactions have lead to significant changes in Chemical Process Cell (CPC) operating conditions. Accordingly, mercury emissions estimates have been updated based upon the new operating requirements, IDMS (Integrated DWPF Melter System) experience, and development of an NO x /FAVC model which predicts FAVC exit temperatures. Using very conservative assumptions and maximum purge rates, the maximum calculated Hg emissions is approximately 130 lbs/yr. A range of 100 to 120 lbs/yr is conservatively predicted for other operating conditions. Defense Waste Processing Facility (DWPF) permitted Hg emissions are 175 lbs/yr (0.02 lbs/hr annual average)

  5. Radionuclide Air Emissions Report for 2012

    Energy Technology Data Exchange (ETDEWEB)

    Wahl, Linnea [Ernest Orlando Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

    2013-05-01

    Berkeley Lab operates facilities where radionuclides are produced, handled, store d, and potentially emitted . These facilities are subject to the EPA radioactive air emission regulations in 40 CFR 61, Subpart H (EPA 1989a). Radionuclides may be emitted from stacks or vents on buildings where radionuclide production or use is authorized or they may be emitted as diffuse sources. In 2012, all Berkeley Lab sources were minor sources of radionuclides (sources resulting in a potential dose of less than 0.1 mrem/yr [0.001 mSv/yr]) . These minor sources include d about 140 stack sources and no diffuse sources . T here were no unplanned airborne radionuclide emissions from Berkeley Lab operations . Emissions from minor sources were measured by sampling or monitoring or were calculated based on quantities used, received for use, or produced during the year. Using measured and calculated emissions, and building- specific and common parameters, Laboratory personnel applied the EPA -approved computer code s, CAP88-PC and COMPLY , to calculate doses to the maximally exposed individual (MEI) at any offsite point where there is a residence, school, business, or office. Because radionuclides are used at three noncontiguous locations (the main site, Berkeley West Bio center, and Joint BioEnergy Institute), three different MEIs were identified.

  6. High-global warming potential F-gas emissions in California: comparison of ambient-based versus inventory-based emission estimates, and implications of refined estimates.

    Science.gov (United States)

    Gallagher, Glenn; Zhan, Tao; Hsu, Ying-Kuang; Gupta, Pamela; Pederson, James; Croes, Bart; Blake, Donald R; Barletta, Barbara; Meinardi, Simone; Ashford, Paul; Vetter, Arnie; Saba, Sabine; Slim, Rayan; Palandre, Lionel; Clodic, Denis; Mathis, Pamela; Wagner, Mark; Forgie, Julia; Dwyer, Harry; Wolf, Katy

    2014-01-21

    To provide information for greenhouse gas reduction policies, the California Air Resources Board (CARB) inventories annual emissions of high-global-warming potential (GWP) fluorinated gases, the fastest growing sector of greenhouse gas (GHG) emissions globally. Baseline 2008 F-gas emissions estimates for selected chlorofluorocarbons (CFC-12), hydrochlorofluorocarbons (HCFC-22), and hydrofluorocarbons (HFC-134a) made with an inventory-based methodology were compared to emissions estimates made by ambient-based measurements. Significant discrepancies were found, with the inventory-based emissions methodology resulting in a systematic 42% under-estimation of CFC-12 emissions from older refrigeration equipment and older vehicles, and a systematic 114% overestimation of emissions for HFC-134a, a refrigerant substitute for phased-out CFCs. Initial, inventory-based estimates for all F-gas emissions had assumed that equipment is no longer in service once it reaches its average lifetime of use. Revised emission estimates using improved models for equipment age at end-of-life, inventories, and leak rates specific to California resulted in F-gas emissions estimates in closer agreement to ambient-based measurements. The discrepancies between inventory-based estimates and ambient-based measurements were reduced from -42% to -6% for CFC-12, and from +114% to +9% for HFC-134a.

  7. Air toxics emissions from an IGCC process

    Energy Technology Data Exchange (ETDEWEB)

    Mojtahedi, W.; Norrbacka, P. [Enviropower Inc., Espoo (Finland); Hinderson, A. [Vattenfall (Sweden); Rosenberg, R.; Zilliacus, R.; Kurkela, E.; Nieminen, M. [VTT Energy, Espoo (Finland); Hoffren, H. [IVO International Oy, Vantaa (Finland)

    1996-12-01

    The so-called simplified coal gasification combined cycle process, incorporating air gasification and hot gas cleanup, promises high power generation efficiency in an environmentally acceptable manner. Increasingly more stringent environmental regulations have focused attention on the emissions of not only SO{sub 2} and NO{sub x} but also on the so-called air toxics which include a number of toxic trace elements. As result of recent amendments to the United States Clean Air Act, IGCC emissions of eleven trace elements: antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, selenium - as well as the radionuclides uranium and thorium may be regulated. Similarly, air missions standards in Europe include a limit of 0.05 mg Nm{sup 3} for mercury and cadmium and 1.0 3/Nm{sup 3} for other class I trace elements. A suitable sampling/measuring system has been developed in this project (in cooperation with Imatran Voima Oy, Electric Power Research Institute (EPRI) and Radian Cooperation) which will be used in the pressurized gasification tests. This will enable an accurate measurement of the volatilized trace element species, at high temperature and pressure, which may be found in the vapour phase. Models are being developed that can be used to determine not only the chemical equilibrium composition of gaseous, liquid and solid phases, but also possible interactions of the gaseous species with aerosol particles and surfaces, These should be used to more accurately assess the impact of the toxic trace metals emitted from the simplified IGCC system

  8. Fast emission estimates in China and South Africa constrained by satellite observations

    Science.gov (United States)

    Mijling, Bas; van der A, Ronald

    2013-04-01

    Emission inventories of air pollutants are crucial information for policy makers and form important input data for air quality models. Unfortunately, bottom-up emission inventories, compiled from large quantities of statistical data, are easily outdated for emerging economies such as China and South Africa, where rapid economic growth change emissions accordingly. Alternatively, top-down emission estimates from satellite observations of air constituents have important advantages of being spatial consistent, having high temporal resolution, and enabling emission updates shortly after the satellite data become available. However, constraining emissions from observations of concentrations is computationally challenging. Within the GlobEmission project (part of the Data User Element programme of ESA) a new algorithm has been developed, specifically designed for fast daily emission estimates of short-lived atmospheric species on a mesoscopic scale (0.25 × 0.25 degree) from satellite observations of column concentrations. The algorithm needs only one forward model run from a chemical transport model to calculate the sensitivity of concentration to emission, using trajectory analysis to account for transport away from the source. By using a Kalman filter in the inverse step, optimal use of the a priori knowledge and the newly observed data is made. We apply the algorithm for NOx emission estimates in East China and South Africa, using the CHIMERE chemical transport model together with tropospheric NO2 column retrievals of the OMI and GOME-2 satellite instruments. The observations are used to construct a monthly emission time series, which reveal important emission trends such as the emission reduction measures during the Beijing Olympic Games, and the impact and recovery from the global economic crisis. The algorithm is also able to detect emerging sources (e.g. new power plants) and improve emission information for areas where proxy data are not or badly known (e

  9. Method to Locate Contaminant Source and Estimate Emission Strength

    Directory of Open Access Journals (Sweden)

    Qu Hongquan

    2013-01-01

    Full Text Available People greatly concern the issue of air quality in some confined spaces, such as spacecraft, aircraft, and submarine. With the increase of residence time in such confined space, contaminant pollution has become a main factor which endangers life. It is urgent to identify a contaminant source rapidly so that a prompt remedial action can be taken. A procedure of source identification should be able to locate the position and to estimate the emission strength of the contaminant source. In this paper, an identification method was developed to realize these two aims. This method was developed based on a discrete concentration stochastic model. With this model, a sensitivity analysis algorithm was induced to locate the source position, and a Kalman filter was used to further estimate the contaminant emission strength. This method could track and predict the source strength dynamically. Meanwhile, it can predict the distribution of contaminant concentration. Simulation results have shown the virtues of the method.

  10. 76 FR 13851 - National Emission Standards for Hazardous Air Pollutants: Mercury Emissions From Mercury Cell...

    Science.gov (United States)

    2011-03-14

    ... National Emission Standards for Hazardous Air Pollutants: Mercury Emissions From Mercury Cell Chlor-Alkali...-5] RIN 2060-AN99 National Emission Standards for Hazardous Air Pollutants: Mercury Emissions From Mercury Cell Chlor-Alkali Plants AGENCY: Environmental Protection Agency (EPA). ACTION: Supplemental...

  11. Modeling natural emissions in the Community Multiscale Air Quality (CMAQ Model–I: building an emissions data base

    Directory of Open Access Journals (Sweden)

    S. F. Mueller

    2010-05-01

    Full Text Available A natural emissions inventory for the continental United States and surrounding territories is needed in order to use the US Environmental Protection Agency Community Multiscale Air Quality (CMAQ Model for simulating natural air quality. The CMAQ air modeling system (including the Sparse Matrix Operator Kernel Emissions (SMOKE emissions processing system currently estimates non-methane volatile organic compound (NMVOC emissions from biogenic sources, nitrogen oxide (NOx emissions from soils, ammonia from animals, several types of particulate and reactive gas emissions from fires, as well as sea salt emissions. However, there are several emission categories that are not commonly treated by the standard CMAQ Model system. Most notable among these are nitrogen oxide emissions from lightning, reduced sulfur emissions from oceans, geothermal features and other continental sources, windblown dust particulate, and reactive chlorine gas emissions linked with sea salt chloride. A review of past emissions modeling work and existing global emissions data bases provides information and data necessary for preparing a more complete natural emissions data base for CMAQ applications. A model-ready natural emissions data base is developed to complement the anthropogenic emissions inventory used by the VISTAS Regional Planning Organization in its work analyzing regional haze based on the year 2002. This new data base covers a modeling domain that includes the continental United States plus large portions of Canada, Mexico and surrounding oceans. Comparing July 2002 source data reveals that natural emissions account for 16% of total gaseous sulfur (sulfur dioxide, dimethylsulfide and hydrogen sulfide, 44% of total NOx, 80% of reactive carbonaceous gases (NMVOCs and carbon monoxide, 28% of ammonia, 96% of total chlorine (hydrochloric acid, nitryl chloride and sea salt chloride, and 84% of fine particles (i.e., those smaller than 2.5 μm in size released into the

  12. Modeling natural emissions in the Community Multiscale Air Quality (CMAQ) Model-I: building an emissions data base

    Science.gov (United States)

    Smith, S. N.; Mueller, S. F.

    2010-05-01

    A natural emissions inventory for the continental United States and surrounding territories is needed in order to use the US Environmental Protection Agency Community Multiscale Air Quality (CMAQ) Model for simulating natural air quality. The CMAQ air modeling system (including the Sparse Matrix Operator Kernel Emissions (SMOKE) emissions processing system) currently estimates non-methane volatile organic compound (NMVOC) emissions from biogenic sources, nitrogen oxide (NOx) emissions from soils, ammonia from animals, several types of particulate and reactive gas emissions from fires, as well as sea salt emissions. However, there are several emission categories that are not commonly treated by the standard CMAQ Model system. Most notable among these are nitrogen oxide emissions from lightning, reduced sulfur emissions from oceans, geothermal features and other continental sources, windblown dust particulate, and reactive chlorine gas emissions linked with sea salt chloride. A review of past emissions modeling work and existing global emissions data bases provides information and data necessary for preparing a more complete natural emissions data base for CMAQ applications. A model-ready natural emissions data base is developed to complement the anthropogenic emissions inventory used by the VISTAS Regional Planning Organization in its work analyzing regional haze based on the year 2002. This new data base covers a modeling domain that includes the continental United States plus large portions of Canada, Mexico and surrounding oceans. Comparing July 2002 source data reveals that natural emissions account for 16% of total gaseous sulfur (sulfur dioxide, dimethylsulfide and hydrogen sulfide), 44% of total NOx, 80% of reactive carbonaceous gases (NMVOCs and carbon monoxide), 28% of ammonia, 96% of total chlorine (hydrochloric acid, nitryl chloride and sea salt chloride), and 84% of fine particles (i.e., those smaller than 2.5 μm in size) released into the atmosphere

  13. Modeling natural emissions in the Community Multiscale Air Quality (CMAQ) model - Part 1: Building an emissions data base

    Science.gov (United States)

    Smith, S. N.; Mueller, S. F.

    2010-01-01

    A natural emissions inventory for the continental United States and surrounding territories is needed in order to use the US Environmental Protection Agency Community Multiscale Air Quality (CMAQ) Model for simulating natural air quality. The CMAQ air modeling system (including the Sparse Matrix Operator Kernel Emissions (SMOKE) emissions processing system) currently estimates volatile organic compound (VOC) emissions from biogenic sources, nitrogen oxide (NOx) emissions from soils, ammonia from animals, several types of particulate and reactive gas emissions from fires, as well as windblown dust and sea salt emissions. However, there are several emission categories that are not commonly treated by the standard CMAQ Model system. Most notable among these are nitrogen oxide emissions from lightning, reduced sulfur emissions from oceans, geothermal features and other continental sources, and reactive chlorine gas emissions linked with sea salt chloride. A review of past emissions modeling work and existing global emissions data bases provides information and data necessary for preparing a more complete natural emissions data base for CMAQ applications. A model-ready natural emissions data base is developed to complement the anthropogenic emissions inventory used by the VISTAS Regional Planning Organization in its work analyzing regional haze based on the year 2002. This new data base covers a modeling domain that includes the continental United States plus large portions of Canada, Mexico and surrounding oceans. Comparing July 2002 source data reveals that natural emissions account for 16% of total gaseous sulfur (sulfur dioxide, dimethylsulfide and hydrogen sulfide), 44% of total NOx, 80% of reactive carbonaceous gases (VOCs and carbon monoxide), 28% of ammonia, 96% of total chlorine (hydrochloric acid, nitryl chloride and sea salt chloride), and 84% of fine particles (i.e., those smaller than 2.5 μm in size) released into the atmosphere. The seasonality and

  14. Scenarios for global emissions from air traffic. The development of regional and gridded (5 degrees x 5 degrees) emissions scenarios for aircraft and for surface sources, based on CPB scenarios and existing emission inventories for aircraft and surface sources

    NARCIS (Netherlands)

    Olivier JGJ; LAE

    1995-01-01

    An estimate was made of present global emissions from air traffic using statistical information on fuel consumption, aircraft types and applying emission factors for various compounds. To generate scenarios for future emissions from air traffic, assumptions were used regarding the development of the

  15. [Study on emission standard system of air pollutants].

    Science.gov (United States)

    Jiang, Mei; Zhang, Guo-Ning; Zhang, Ming-Hui; Zou, Lan; Wei, Yu-Xia; Ren, Chun

    2012-12-01

    Scientific and reasonable emission standard system of air pollutants helps to systematically control air pollution, enhance the protection of the atmospheric environment effect and improve the overall atmospheric environment quality. Based on the study of development, situation and characteristics of national air pollutants emission standard system, the deficiencies of system were pointed out, which were not supportive, harmonious and perfect, and the improvement measures of emission standard system were suggested.

  16. Secondary Aluminum Production: National Emission Standards for Hazardous Air Pollutants

    Science.gov (United States)

    National emission standards for hazardous air pollutants (NESHAP) for new and existing sources at secondary aluminum production facilities. Includes rule history, summary, federal register citations and implementation information.

  17. Methods for estimating on-site ambient air concentrations at disposal sites

    International Nuclear Information System (INIS)

    Hwang, S.T.

    1987-01-01

    Currently, Gaussian type dispersion modeling and point source approximation are combined to estimate the ambient air concentrations of pollutants dispersed downwind of an areawide emission source, using the approach of virtual point source approximation. This Gaussian dispersion modeling becomes less accurate as the receptor comes closer to the source, and becomes inapplicable for the estimation of on-site ambient air concentrations at disposal sites. Partial differential equations are solved with appropriate boundary conditions for use in estimating the on-site concentrations in the ambient air impacted by emissions from an area source such as land disposal sites. Two variations of solution techniques are presented, and their predictions are compared

  18. Product-related emissions of Mercury to Air in the European Union

    Energy Technology Data Exchange (ETDEWEB)

    Kindbom, Karin; Munthe, John

    2007-06-15

    Mercury emissions to air from the use of mercury in products have been estimated for the EU for the year 2005. The consumption of mercury in the EU in 2005 was amounted to 125 tonnes in technical products. Estimates of emissions of mercury from dental amalgam were derived from information on cremations in European countries and average contents of amalgam fillings. Annual emissions of mercury to air from product use in EU27 have been estimated to be in the range 10-18 tonnes (best estimate 14 tonnes) from technical products and to 2-5 tonnes from cremation, in total 12-23 tonnes. Of the mercury consumed in technical products, 11% was calculated to be emitted to air, 31% to end up in safe storage while 58% would still be accumulated in society or disposed of in landfills. From the share still accumulated in society, as well as from the already land filled amounts, further emissions of mercury to air may occur in the longer term. Emissions from technical products are calculated based on the consumption of mercury in 2005. Emissions occurring in the same year but caused by consumption in the previous 10 years were derived using the consumption in 2005 and assuming the same patterns of distribution and emissions. The latest available estimates of total anthropogenic emissions of mercury in EU27 refer to the year 2000 and are in the order of 140-190 tonnes, probably to have declined to 2005. Based on these figures the contribution to anthropogenic mercury emissions to air in EU from product use and cremation in 2005 is at least 6-16%. In a previous report product related air emissions of 72 tonnes were estimated for Europe in the mid 1990s, corresponding to 18% of the total air emissions. A significant decrease of emissions has thus occurred which is in line with a decreasing use of mercury in technical products, more efficient collection of remaining products and better emission control. However, the calculations show that the use of mercury in products still

  19. Air toxics emission from an IGCC process

    Energy Technology Data Exchange (ETDEWEB)

    Mojtahedi, W; Hovath, A [Carbona Inc, Helsinki (Finland); Hinderson, A [Vattenfall Utveckling (Sweden); Nykaenen, J; Hoffren, H [Imatran Voima Oy, Vantaa (Finland); Nieminen, M; Kurkela, E [VTT, Espoo (Finland)

    1997-10-01

    The emissions of 12 toxic trace element from a coal-fired IGCC plant were calculated based on thermodynamic equilibrium in the gas phase and some of the results published. The theoretical calculations were extended to include some other fuels as well as mixture of some of these fuels. The combustion of the product gas in the gas turbine is also considered. These simulations correspond to gasification of the fuel at 850-1050 deg C (depending on the fuel) and 1823 bar pressure. The gas composition was taken from the measured data as far as possible. In the absence of experimental data, a computer code developed for the U-Gas gasifier was used to determine the fuel gas composition. The gas was then cooled to 550 deg C in the gas cooler and filtered at this same temperature and burned in the gas turbine with an air ratio of 3.2. The results of these simulations are compared with the measured data of an experimental program designed to measure the emissions of a few selected trace elements from a 15 MW,h pressurized fluidized bed gasification pilot plant. The pilot plant was equipped with an advanced hot gas cleanup train which includes a two fluidized-bed reactor system for high-temperature, high-pressure external sulfur removal and a filtration unit housing porous, rigid ceramic candle filters. The trace element concentrations in the fuel, bottom ash, and filter ash are determined and the results compared with EPA regulatory levels

  20. Global and regional emission estimates for HCFC-22

    Directory of Open Access Journals (Sweden)

    E. Saikawa

    2012-11-01

    Full Text Available HCFC-22 (CHClF2, chlorodifluoromethane is an ozone-depleting substance (ODS as well as a significant greenhouse gas (GHG. HCFC-22 has been used widely as a refrigerant fluid in cooling and air-conditioning equipment since the 1960s, and it has also served as a traditional substitute for some chlorofluorocarbons (CFCs controlled under the Montreal Protocol. A low frequency record on tropospheric HCFC-22 since the late 1970s is available from measurements of the Southern Hemisphere Cape Grim Air Archive (CGAA and a few Northern Hemisphere air samples (mostly from Trinidad Head using the Advanced Global Atmospheric Gases Experiment (AGAGE instrumentation and calibrations. Since the 1990s high-frequency, high-precision, in situ HCFC-22 measurements have been collected at these AGAGE stations. Since 1992, the Global Monitoring Division of the National Oceanic and Atmospheric Administration/Earth System Research Laboratory (NOAA/ESRL has also collected flasks on a weekly basis from remote sites across the globe and analyzed them for a suite of halocarbons including HCFC-22. Additionally, since 2006 flasks have been collected approximately daily at a number of tower sites across the US and analyzed for halocarbons and other gases at NOAA. All results show an increase in the atmospheric mole fractions of HCFC-22, and recent data show a growth rate of approximately 4% per year, resulting in an increase in the background atmospheric mole fraction by a factor of 1.7 from 1995 to 2009. Using data on HCFC-22 consumption submitted to the United Nations Environment Programme (UNEP, as well as existing bottom-up emission estimates, we first create globally-gridded a priori HCFC-22 emissions over the 15 yr since 1995. We then use the three-dimensional chemical transport model, Model for Ozone and Related Chemical Tracers version 4 (MOZART v4, and a Bayesian inverse method to estimate global as well as regional annual emissions. Our inversion indicates

  1. NUMERICAL PREDICTION MODELS FOR AIR POLLUTION BY MOTOR VEHICLE EMISSIONS

    Directory of Open Access Journals (Sweden)

    M. M. Biliaiev

    2016-12-01

    Full Text Available Purpose. Scientific work involves: 1 development of 3D numerical models that allow calculating the process of air pollution by motor vehicles emissions; 2 creation of models which would allow predicting the air pollution level in urban areas. Methodology. To solve the problem upon assessing the level of air pollution by motor vehicles emissions fundamental equations of aerodynamics and mass transfer are used. For the solution of differential equations of aerodynamics and mass transfer finite-difference methods are used. For the numerical integration of the equation for the velocity potential the method of conditional approximations is applied. The equation for the velocity potential written in differential form, splits into two equations, where at each step of splitting an unknown value of the velocity potential is determined by an explicit scheme of running computation, while the difference scheme is implicit one. For the numerical integration of the emissions dispersion equation in the atmosphere applies the implicit alternating-triangular difference scheme of splitting. Emissions from the road are modeled by a series of point sources of given intensity. Developed numerical models form is the basis of the created software package. Findings. 3D numerical models were developed; they belong to the class of «diagnostic models». These models take into account main physical factors that influence the process of dispersion of harmful substances in the atmosphere when emissions from vehicles in the city occur. Based on the constructed numerical models the computational experiment was conducted to assess the level of air pollution in the street. Originality. Authors have developed numerical models that allow to calculate the 3D aerodynamics of the wind flow in urban areas and the process of mass transfer emissions from the highway. Calculations to determine the area of contamination, which is formed near the buildings, located along the highway were

  2. Trends in anthropogenic mercury emissions estimated for South Africa during 2000-2006

    Energy Technology Data Exchange (ETDEWEB)

    Masekoameng, K.E.; Leaner, J.; Dabrowski, J. [CSIR, Pretoria (South Africa)

    2010-08-15

    Recent studies suggest an increase in mercury (Hg) emissions to the global environment, particularly as a result of anthropogenic activities. This has prompted many countries to complete Hg emission inventories, based on country-specific Hg sources. In this study, information on annual coal consumption and Hg-containing commodities produced in South Africa, was used to estimate Hg emissions during 2000-2006. Based on the information, the UNEP toolkit was used to estimate the amount of Hg released to air and general waste from each activity; using South Africa specific and toolkit based emission factors. In both atmospheric and solid waste releases, coal-fired power plants were estimated to be the largest contributors of Hg emissions, viz. 27.1 to 38.9 tonnes y{sup -1} in air, and 5.8 to 7.4 tonnes y{sup -1} in waste. Cement production was estimated to be the second largest atmospheric Hg emission contributor (2.2-3.9 tonnes y{sup -1}), while coal gasification was estimated to be the second largest Hg contributor in terms of general waste releases (2.9-4.2 tonnes y{sup -1}). Overall, there was an increase in total atmospheric Hg emissions from all activities, estimated at ca. 34 tonnes in 2000, to 50 tonnes in 2006, with some fluctuations between the years. Similarly, the total Hg emissions released to general waste was estimated to be 9 tonnes in 2000, with an increase to 12 tonnes in 2006.

  3. Radionuclide air emissions report for the Hanford Site

    International Nuclear Information System (INIS)

    Rokkan, D.J.; Diediker, L.P.; Manley, C.L.

    1992-06-01

    This report documents the radionuclide air emissions from the Hanford Site in 1991 and the resulting effective dose equivalent to any member of the public. The report is submitted in compliance with reporting requirements in the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, ''National Emissions Standards for Hazardous Air Pollutants.''

  4. Air toxics and the 1990 Clean Air Act: Managing trace element emissions

    International Nuclear Information System (INIS)

    Chow, W.; Levin, L.; Miller, M.J.

    1992-01-01

    The US Environmental Protection Agency (EPA) has historically regulated air toxics (hazardous air pollutants) under Section 112 of the Clean Air Act. To date, EPA has established emission standards for 8 hazardous air pollutants (arsenic, asbestos, benzene, beryllium, mercury, radionuclides, coke oven emissions and vinyl chloride). The US electric utility industry was not determined to be a source category requiring regulation for any of the eight chemicals. Of the eight, radionuclides were the last species for which EPA established hazardous emissions standards. In this instance, EPA determined that the risks associated with electric utility fossil fuel power plant emissions were sufficiently low that they should not be regulated. However, the 1990 Clean Air Act Amendments require a new evaluation of the electric utility industry emissions of hazardous air pollutants. This paper summarizes the key features of the air toxics provisions of the Clean Air Act Amendments, describes EPRI's activities on the subject, and provides some preliminary insights from EPRI's research to date

  5. Megacity and country emissions from combustion sources-Buenos Aires-Argentina

    Science.gov (United States)

    Dawidowski, L.; Gomez, D.; Matranga, M.; D'Angiola, A.; Oreggioni, G.

    2010-12-01

    Historic time series (1970-2006) emissions of greenhouse gases and air pollutants arising from stationary and mobile combustion sources were estimated at national level for Argentina and at regional level for the metropolitan area of Buenos Aires (MABA). All emissions were estimated using a bottom-up approach following the IPCC good practice guidance. For mobile sources, national emissions include all transport categories. Regional emissions account thus far only for on-road. For national emissions, methodologies and guidance by the IPCC were employed, applying the highest possible tier and using: i)country-specific emission factors for carbon and sulphur and technology-based information for other species, ii)activity data from energy balance series (1970-2007), and iii)complementary information concerning the non-energy use of fuels. Regional emissions in 2006 were estimated in-depth using a technology-based approach for the city of Buenos Aires (CBA) and the 24 neighboring districts composing the MABA. A regional emissions factors database was developed to better characterize Latin American fleets and driving conditions employing COPERT III-IV algorithms and emission factors measured in dynamometers and circulating vehicles in Argentina, Brazil, Chile and Colombia. Past emissions were back estimated from 2005 to 1970 using the best available information, which differs greatly among categories, spatial disaggregation and time periods. The time series of stationary and mobile combustion sources at the national and regional level allowed the identification of distinct patterns. National greenhouse gas emissions in 2006 amounted to ~ 150 million ton CO2-equivalent, 70% of which were contributed by stationary sources. On-road transport was the major contributor within mobile sources (28.1 %). The increasing emissions trends are dominated by on-road transport, agriculture and residential categories while the variability is largely associated with energy industries

  6. Air Emission Inventory for the Idaho National Engineering Laboratory: 1992 emissions report

    International Nuclear Information System (INIS)

    Stirrup, T.S.

    1993-06-01

    This report presents the 1992 Air Emission Inventory for the Idaho National Engineering Laboratory. Originally, this report was in response to the Environmental Oversight and Monitoring Agreement in 1989 between the State of Idaho and the Department of Energy Idaho Field Office, and a request from the Idaho Air Quality Bureau. The current purpose of the Air Emission Inventory is to provide the basis for the preparation of the INEL Permit-to-Operate (PTO) an Air Emission Source Application, as required by the recently promulgated Title V regulations of the Clean Air Act. This report includes emissions calculations from 1989 to 1992. The Air Emission Inventory System, an ORACLE-based database system, maintains the emissions inventory

  7. Air Emission Inventory for the Idaho National Engineering Laboratory: 1992 emissions report

    Energy Technology Data Exchange (ETDEWEB)

    Stirrup, T.S.

    1993-06-01

    This report presents the 1992 Air Emission Inventory for the Idaho National Engineering Laboratory. Originally, this report was in response to the Environmental Oversight and Monitoring Agreement in 1989 between the State of Idaho and the Department of Energy Idaho Field Office, and a request from the Idaho Air Quality Bureau. The current purpose of the Air Emission Inventory is to provide the basis for the preparation of the INEL Permit-to-Operate (PTO) an Air Emission Source Application, as required by the recently promulgated Title V regulations of the Clean Air Act. This report includes emissions calculations from 1989 to 1992. The Air Emission Inventory System, an ORACLE-based database system, maintains the emissions inventory.

  8. Air pollution emissions and damages from energy production in the U.S.: 2002–2011

    International Nuclear Information System (INIS)

    Jaramillo, Paulina; Muller, Nicholas Z.

    2016-01-01

    This paper uses air pollution emissions data for the years 2002, 2005, 2008, and 2011 to estimate monetary damages due to air pollution exposure for PM 2.5 , SO 2 , NO x , NH 3 , and VOC from electric power generation, oil and gas extraction, coal mining, and oil refineries. In 2011, damages associated with emissions from these sectors totaled 131 billion dollars (in 2000$), with SO 2 emissions from power generation being the largest contributors to social damages. Further, damages have decreased significantly since 2002, even as energy production increased, suggesting that, among other factors, policies that have driven reductions in emissions have reduced damages. The results of this analysis highlight the spatial heterogeneity of the impacts associated with the emissions of a given pollutant. In the past, environmental regulations have assumed that the benefits of air emissions reductions are homogenous across source location. This analysis suggests that policy designs that account for spatial differences in the impacts of air emissions could result in more effective environmental regulation. Accounting for such spatial heterogeneity in the benefits of policies would be akin to accounting for differences in compliances costs across states, which the EPA did when establishing the state emissions standards for the Clean Power Plan rule. - Highlights: • Social costs of emissions from energy sector decreased between 2002 and 2011. • Emissions from power generation are the major contributors to social costs. • Policies to control SO 2 emissions may produce the largest social costs reductions.

  9. Inventory of conventional air pollutants emissions from road transportation for the state of Rio de Janeiro

    International Nuclear Information System (INIS)

    Souza, Cristiane Duarte Ribeiro de; Silva, Suellem Deodoro; Silva, Marcelino Aurélio Vieira da; D’Agosto, Márcio de Almeida; Barboza, Arthur Prado

    2013-01-01

    Road transportation has contributed to increased emissions of conventional air pollutants and, consequently, to the increase in problems associated with the environment and human health, depending on the type of pollutant and the concentration of it. To support the development of public policies aimed to decrease total tonnes of emissions, we used a bottom-up approach to estimate the amount of air pollutants, such as carbon monoxide (CO), total hydrocarbons (THC), nitrogen oxides (NO x ), particulate matter (PM), and aldehydes (RCHO), that are emitted by road transportation in the state of Rio de Janeiro (RJ) from 1980 to 2010. The results from 2010 show that cars are responsible for 55% of CO emissions, 61% of THC emissions, and 93% of RCHO emissions. Due to the use of hydrated ethanol and compressed natural gas (CNG) instead of petroleum based fuels during the period analyzed, 1,760,370 t of air pollutant emissions were avoided. Compared to Brazil, in 2010, RJ had a quantity of emissions per vehicle from 12% (CO) to 59% (PM) smaller than the national average. As strategies to reduce air pollutant emissions, we consider reducing the intensity of use, with a proportional reduction in emissions, and increased the use of biodiesel. - Highlights: ► We estimate road transportation emissions for Rio de Janeiro from 1980 to 2010. ► C gasoline was most responsible for CO (74%) and diesel for PM (91%). ► Emissions/vehicle for Rio de Janeiro are (12% to 59%) smaller than Brazilian. ► 1,760,370 t of emissions was avoided using non-petroleum-based fuels. ► Strategies to reduce the emissions of these air pollutants were proposed.

  10. Decomposing Air Pollutant Emissions in Asia: Determinants and Projections

    OpenAIRE

    Rafaj, P.; Amann, M.

    2018-01-01

    High levels of air pollution pose an urgent social and public health challenge in many Asian regions. This study evaluates the role of key factors that determined the changes in emission levels in China, India and Japan over the past 25 years. While emissions of air pollutants have been declining in Japan since the 1990s, China and India have experienced a rapid growth in pollution levels in recent years. Around 2005, control measures for sulfur emissions started to deliver expected reduction...

  11. Air quality and greenhouse gas emissions (Chapter 3)

    CSIR Research Space (South Africa)

    Winkler, H

    2016-01-01

    Full Text Available Shale gas development (SGD) presents opportunities and risks with regards to air pollution and greenhouse gas (GHG) emissions. There is a potential opportunity to reduce emissions, if shale gas replaces ‘dirtier’ (more emissions-intensive) fuels...

  12. National Emission Standards for Hazardous Air Pollutants Calendar Year 2005

    International Nuclear Information System (INIS)

    Bechtel Nevada

    2006-01-01

    The Nevada Test Site (NTS) is operated by the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office (NNSA/NSO). From 1951 through 1992, the NTS was operated as the nation's site for nuclear weapons testing. The release of man-made radionuclides from the NTS as a result of testing activities has been monitored since the first decade of atmospheric testing. After 1962, when nuclear tests were conducted only underground, the radiation exposure to the public surrounding the NTS was greatly reduced. After the 1992 moratorium on nuclear testing, radiation monitoring on the NTS focused on detecting airborne radionuclides that are resuspended into the air (e.g., by winds, dust-devils) along with historically-contaminated soils on the NTS. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (40 Code of Federal Regulations 61 Subpart H) limits the release of radioactivity from a U. S. Department of Energy (DOE) facility (e.g., the NTS) to 10 millirem per year (mrem/yr) effective dose equivalent (EDE) to any member of the public. This is the dose limit established for someone living off of the NTS for inhaling radioactive particles that may be carried by wind off of the NTS. This limit assumes that members of the public surrounding the NTS may also inhale 'background levels' or radioactive particles unrelated to NTS activities that come from naturally-occurring elements in the environment (e.g., radon gas from the earth or natural building materials) or from other man-made sources (e.g., cigarette smoke). The U. S. Environmental Protection Agency (EPA) requires DOE facilities (e.g., the NTS) to demonstrate compliance with the NESHAP dose limit by annually estimating the dose to a hypothetical member of the public, referred to as the maximally exposed individual (MEI), or the member of the public who resides within an 80-kilometer (50-mile) radius

  13. Letter to the Editor: Applications Air Q Model on Estimate Health Effects Exposure to Air Pollutants

    Directory of Open Access Journals (Sweden)

    Gholamreza Goudarzi

    2016-02-01

    Full Text Available Epidemiologic studies in worldwide have measured increases in mortality and morbidity associated with air pollution (1-3. Quantifying the effects of air pollution on the human health in urban area causes an increasingly critical component in policy discussion (4-6. Air Q model was proved to be a valid and reliable tool to predicts health effects related to criteria  pollutants (particulate matter (PM, ozone (O3, nitrogen dioxide (NO2, sulfur dioxide (SO2, and carbon monoxide (CO, determinate  the  potential short term effects of air pollution  and allows the examination of various scenarios in which emission rates of pollutants are varied (7,8. Air Q software provided by the WHO European Centre for Environment and Health (ECEH (9. Air Q model is based on cohort studies and used to estimates of both attributable average reductions in life-span and numbers of mortality and morbidity associated with exposure to air pollution (10,11. Applications

  14. Air pollutant and greenhouse gas emissions - 'Namea-Air' - February 2017

    International Nuclear Information System (INIS)

    Baude, Manuel

    2017-02-01

    For the first time, the SOeS (Monitoring and Statistics Directorate of France's Ministry of the Environment) is publishing air pollutant emissions accounts in the National Accounting Matrix Including Environmental Accounts (NAMEA) format for the years 1990, 1995, 2000, 2005, and 2008 to 2014. Namea-Air is an inventory format breaking down emissions of greenhouse gases (GHG) and air pollutants into 64 branches of economic activity and identifying a 'direct household emissions' category. (author)

  15. PestLCI 2.0: a second generation model for estimating emissions of pesticides from arable land in LCA

    DEFF Research Database (Denmark)

    Dijkman, Teunis Johannes; Birkved, Morten; Hauschild, Michael Zwicky

    2012-01-01

    The spatial dependency of pesticide emissions to air, surface water and groundwater is illustrated and quantified using PestLCI 2.0, an updated and expanded version of PestLCI 1.0.PestLCI is a model capable of estimating pesticide emissions to air, surface water and groundwater for use in life cy...

  16. Air toxic emissions from burning of biomass globally-preliminary results

    International Nuclear Information System (INIS)

    Ward, D.E.; Hao, W.M.

    1992-01-01

    Emissions of trace gases, particles, and air toxic substances in the smoke plumes from biomass fires are of importance to global climate change. The potential impact of the air toxic emissions on the human population of specific regions globally is another major concern. The toxic materials are produced in high concentrations in areas of heavy biomass burning, e.g., Amazon Basin and Central/southern Africa. We provide new estimates of air toxics based on the combustion efficiency (percent of total carbon released as CO 2 ) for fires burning in different ecosystems on a global basis. Estimates of total biomass consumed on a global basis range from 2 to 10 Pg (1 petagram = 10 15 g) per year. We apply emission factors for various air toxics (g of emission released per kg of fuel consumed) to the estimate of global biomass consumption of 6.4 Pg per year. The principal air toxics analyzed in this paper include: Total particulate matter, CO, formaldehyde, acetaldehyde, acrolein, benzene, toluene, o-xylene, m, p-xylene, benzo[a]pyrene, and polycyclic organic material. The total emissions calculated for these materials on a yearly global basis are: 75, 362, 4.9, 1.5, 1.5, 2.1, 2.1, 0.3, 0.6, 0.001, 0.026, Tg (1 teragram = 10 12 g) per year, respectively. Biomass burning in the United States contributes less than 3% to the total global emissions

  17. Savannah River Site radionuclide air emissions annual report for national emission standards for hazardous air pollutants

    International Nuclear Information System (INIS)

    Sullivan, I.K.

    1993-01-01

    The radiological air emission sources at the SRS have been divided into three categories, Point, Grouped and Non-Point, for this report. Point sources, analyzed individually, are listed with a listing of the control devices, and the control device efficiency. The sources listed have been grouped together either for security reasons or where individual samples are composited for analytical purposes. For grouped sources the listed control devices may not be on all sources within a group. Point sources that did not have continuous effluent monitoring/sampling in 1993 are noted. The emissions from these sources was determined from Health Protection smear data, facility radionuclide content or other calculational methods, including process knowledge, utilizing existing analytical data. This report also contain sections on facility descriptions, dose assessment, and supplemental information

  18. A fuel-based approach to estimating motor vehicle exhaust emissions

    Science.gov (United States)

    Singer, Brett Craig

    Motor vehicles contribute significantly to air pollution problems; accurate motor vehicle emission inventories are therefore essential to air quality planning. Current travel-based inventory models use emission factors measured from potentially biased vehicle samples and predict fleet-average emissions which are often inconsistent with on-road measurements. This thesis presents a fuel-based inventory approach which uses emission factors derived from remote sensing or tunnel-based measurements of on-road vehicles. Vehicle activity is quantified by statewide monthly fuel sales data resolved to the air basin level. Development of the fuel-based approach includes (1) a method for estimating cold start emission factors, (2) an analysis showing that fuel-normalized emission factors are consistent over a range of positive vehicle loads and that most fuel use occurs during loaded-mode driving, (3) scaling factors relating infrared hydrocarbon measurements to total exhaust volatile organic compound (VOC) concentrations, and (4) an analysis showing that economic factors should be considered when selecting on-road sampling sites. The fuel-based approach was applied to estimate carbon monoxide (CO) emissions from warmed-up vehicles in the Los Angeles area in 1991, and CO and VOC exhaust emissions for Los Angeles in 1997. The fuel-based CO estimate for 1991 was higher by a factor of 2.3 +/- 0.5 than emissions predicted by California's MVEI 7F model. Fuel-based inventory estimates for 1997 were higher than those of California's updated MVEI 7G model by factors of 2.4 +/- 0.2 for CO and 3.5 +/- 0.6 for VOC. Fuel-based estimates indicate a 20% decrease in the mass of CO emitted, despite an 8% increase in fuel use between 1991 and 1997; official inventory models predict a 50% decrease in CO mass emissions during the same period. Cold start CO and VOC emission factors derived from parking garage measurements were lower than those predicted by the MVEI 7G model. Current inventories

  19. National Emission Standards for Hazardous Air Pollutants

    International Nuclear Information System (INIS)

    Grossman, Robert F.

    2005-01-01

    The sources of radionuclides include current and previous activities conducted on the NTS. The NTS was the primary location for testing of nuclear explosives in the Continental U.S. between 1951 and 1992. Historical testing has included (1) atmospheric testing in the 1950s and early 1960s, (2) underground testing between 1951 and 1992, and (3) open-air nuclear reactor and rocket engine testing (DOE, 1996a). No nuclear tests have been conducted since September 23,1992 (DOE, 2000), however; radionuclides remaining on the soil surface in many NTS areas after several decades of radioactive decay are re-suspended into the atmosphere at concentrations that can be detected by air sampling. Limited non-nuclear testing includes spills of hazardous materials at the Non-Proliferation Test and Evaluation Complex (formerly called the Hazardous Materials Spill Center), private technology development, aerospace and demilitarization activities, and site remediating activities. Processing of radioactive materials is limited to laboratory analyses; handling, transport, storage, and assembly of nuclear explosive devices or radioactive targets for the Joint Actinide Shock Physics Experimental Research (JASPER) gas gun; and operation of radioactive waste management sites (RWMSs) for low-level radioactive and mixed waste (DOE, 1996a). Monitoring and evaluation of the various activities conducted onsite indicate that the potential sources of offsite radiation exposure in calendar year (CY) 2004 were releases from (1) evaporation of tritiated water (HTO) from containment ponds that receive drainage water from E Tunnel in Area 12 and water pumped from wells used to characterize the aquifers at the sites of past underground nuclear tests, (2) onsite radioanalytical laboratories, (3) the Area 3 and Area 5 RWMS facilities, and (4) diffuse sources of tritium (H 3 ) and re-suspension of plutonium ( 239+240 Pu) and americium ( 241 Am) at the sites of past nuclear tests. The following sections

  20. Assessing Potential Air Pollutant Emissions from Agricultural Feedstock Production using MOVES

    Energy Technology Data Exchange (ETDEWEB)

    Eberle, Annika [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Warner, Ethan [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Zhang, Yi Min [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Inman, Daniel J [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Carpenter Petri, Alberta C [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Heath, Garvin A [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Hettinger, Dylan J [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Bhatt, Arpit H [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2018-03-29

    Biomass feedstock production is expected to grow as demand for biofuels and bioenergy increases. The change in air pollutant emissions that may result from large-scale biomass supply has implications for local air quality and human health. We developed spatially explicit emissions inventories for corn grain and six cellulosic feedstocks through the extension of the National Renewable Energy Laboratory's Feedstock Production Emissions to Air Model (FPEAM). These inventories include emissions of seven pollutants (nitrogen oxides, ammonia, volatile organic compounds, particulate matter, sulfur oxides, and carbon monoxide) generated from biomass establishment, maintenance, harvest, transportation, and biofuel preprocessing activities. By integrating the EPA's MOtor Vehicle Emissions Simulator (MOVES) into FPEAM, we created a scalable framework to execute county-level runs of the MOVES-Onroad model for representative counties (i.e., those counties with the largest amount of cellulosic feedstock production in each state) on a national scale. We used these results to estimate emissions from the on-road transportation of biomass and combined them with county-level runs of the MOVES-Nonroad model to estimate emissions from agricultural equipment. We also incorporated documented emission factors to estimate emissions from chemical application and the operation of drying equipment for feedstock processing, and used methods developed by the EPA and the California Air Resources Board to estimate fugitive dust emissions. The model developed here could be applied to custom equipment budgets and is extensible to accommodate additional feedstocks and pollutants. Future work will also extend this model to analyze spatial boundaries beyond the county-scale (e.g., regional or sub-county levels).

  1. Estimation of biogenic volatile organic compounds emissions in subtropical island--Taiwan.

    Science.gov (United States)

    Chang, Ken-Hui; Chen, Tu-Fu; Huang, Ho-Chun

    2005-06-15

    Elevated tropospheric ozone is harmful to human health and plants. It is formed through the photochemical reactions involving volatile organic compounds (VOCs) and nitrogen oxides (NO(x)). The elevated ozone episodes occur mainly in summer months in the United States, while the high-ozone episodes frequently occur during the fall in Taiwan. The unique landscape of Taiwan produces tremendous amounts of biogenic VOCs in the mountain regions that are adjacent to concentrated urban areas. The urban areas, in turn, generate prodigious amounts of anthropogenic emissions. Biogenic VOC emissions have direct influence on tropospheric ozone formation. To explore the air quality problems in Taiwan, this study attempts to develop a biogenic VOC emission model suitable for air quality applications in Taiwan. The emission model is based on the Biogenic Emissions Inventory System Version 2 and coupled with a detailed Taiwan land use database. The 1999 total Taiwan biogenic VOC emissions were estimated at 214,000 metric tons. The emissions of isoprene, monoterpenes, and other VOCs were about 37.2%, 30.4%, and 32.4% of total biogenic VOC emissions, respectively. The annual total biogenic VOC emission per unit area was more than two times the value of that in any European country, implying that detailed emissions estimates in any size of region will benefit the global biogenic emission inventories.

  2. An intercomparison of biogenic emissions estimates from BEIS2 and BIOME: Reconciling the differences

    Energy Technology Data Exchange (ETDEWEB)

    Wilkinson, J.G. [Alpine Geophysics, Pittsburgh, PA (United States); Emigh, R.A. [Alpine Geophysics, Boulder, CO (United States); Pierce, T.E. [Atmospheric Characterization and Modeling Division/NOAA, Research Triangle Park, NC (United States)

    1996-12-31

    Biogenic emissions play a critical role in urban and regional air quality. For instance, biogenic emissions contribute upwards of 76% of the daily hydrocarbon emissions in the Atlanta, Georgia airshed. The Biogenic Emissions Inventory System-Version 2.0 (BEIS2) and the Biogenic Model for Emissions (BIOME) are two models that compute biogenic emissions estimates. BEIS2 is a FORTRAN-based system, and BIOME is an ARC/INFO{reg_sign} - and SAS{reg_sign}-based system. Although the technical formulations of the models are similar, the models produce different biogenic emissions estimates for what appear to be essentially the same inputs. The goals of our study are the following: (1) Determine why BIOME and BEIS2 produce different emissions estimates; (2) Attempt to understand the impacts that the differences have on the emissions estimates; (3) Reconcile the differences where possible; and (4) Present a framework for the use of BEIS2 and BIOME. In this study, we used the Coastal Oxidant Assessment for Southeast Texas (COAST) biogenics data which were supplied to us courtesy of the Texas Natural Resource Conservation Commission (TNRCC), and we extracted the BEIS2 data for the same domain. We compared the emissions estimates of the two models using their respective data sets BIOME Using TNRCC data and BEIS2 using BEIS2 data.

  3. Air pollution emission inventory along a major traffic route within ...

    African Journals Online (AJOL)

    Soyannwo, Olusola

    traffic emissions are the dominant source of gaseous ..... air concentrations, source profiles, and source apportionment of 71 ... heavy metals in Ibadan, Nigeria. Soil Sed. Contam. 10(6):577-591. Sjodin A, Persson K, Andreasson K, Arlander B, ...

  4. Assessment of the emissions and air quality impacts of biomass and biogas use in California.

    Science.gov (United States)

    Carreras-Sospedra, Marc; Williams, Robert; Dabdub, Donald

    2016-02-01

    It is estimated that there is sufficient in-state "technically" recoverable biomass to support nearly 4000 MW of bioelectricity generation capacity. This study assesses the emissions of greenhouse gases and air pollutants and resulting air quality impacts of new and existing bioenergy capacity throughout the state of California, focusing on feedstocks and advanced technologies utilizing biomass resources predominant in each region. The options for bioresources include the production of bioelectricity and renewable natural gas (NG). Emissions of criteria pollutants and greenhouse gases are quantified for a set of scenarios that span the emission factors for power generation and the use of renewable natural gas for vehicle fueling. Emissions are input to the Community Multiscale Air Quality (CMAQ) model to predict regional and statewide temporal air quality impacts from the biopower scenarios. With current technology and at the emission levels of current installations, maximum bioelectricity production could increase nitrogen oxide (NOx) emissions by 10% in 2020, which would cause increases in ozone and particulate matter concentrations in large areas of California. Technology upgrades would achieve the lowest criteria pollutant emissions. Conversion of biomass to compressed NG (CNG) for vehicles would achieve comparable emission reductions of criteria pollutants and minimize emissions of greenhouse gases (GHG). Air quality modeling of biomass scenarios suggest that applying technological changes and emission controls would minimize the air quality impacts of bioelectricity generation. And a shift from bioelectricity production to CNG production for vehicles would reduce air quality impacts further. From a co-benefits standpoint, CNG production for vehicles appears to provide the best benefits in terms of GHG emissions and air quality. This investigation provides a consistent analysis of air quality impacts and greenhouse gas emissions for scenarios examining

  5. Establishing credible emission reduction estimates: GERT's experience

    International Nuclear Information System (INIS)

    Loseth, H.

    2001-01-01

    To address the challenge of reducing the greenhouse gas emissions in Canada, the federal and provincial governments are developing strategies and policies to reach that goal. One of the proposed solutions is the establishment of an emission trading system, which it is believed would encourage investment in lower-cost reductions. The Greenhouse Gas Emission Reduction Trading (GERT) pilot was established in 1998 to examine emission trading. It represents the collaborative efforts of government, industry, and non-governmental organizations. It is possible to establish emission reduction trading outside of a regulated environment. Emission reduction is defined as being an action which reduces emissions when compared to what they would have been otherwise. The functioning of GERT was described from the initial application by a buyer/seller to the review process. The assessment of projects is based on mandatory criteria: reductions of emissions must be real, measurable, verifiable and surplus. A section of the presentation was devoted to landfill gas recovery project issues, while another dealt with fuel substitution project issues. Section 5 discussed emission reductions from an off-site source electricity project issues. figs

  6. VOCs and formaldehyde emissions from cleaning products and air fresheners

    OpenAIRE

    Solal , Cécilia; Rousselle , Christophe; Mandin , Corinne; Manel , Jacques; Maupetit , François

    2008-01-01

    International audience; Human indoor exposure to Volatile Organic Compounds (VOCs) may be associated with the use of household products. However little is known about their emissions and to what extent they contribute to indoor air pollution. The French Agency for Environmental and Occupational Health Safety (Afsset) conducted tests in order to characterize VOCs emissions from 32 consumer products: air fresheners, glass cleaners, furniture polishes, toilet products, carpet and floor cleaning ...

  7. Air Monitoring, Measuring, and Emissions Research

    Science.gov (United States)

    Measurement research is advancing the ability to determine the composition of sources of air pollution, conduct exposure assessments, improve monitoring capabilities and support public health research.

  8. Assessing emissions levels and costs associated with climate and air pollution policies in South Africa

    International Nuclear Information System (INIS)

    Henneman, Lucas R.F.; Rafaj, Peter; Annegarn, Harold J.; Klausbruckner, Carmen

    2016-01-01

    Affordable energy supply and reductions in emissions of local air pollution and greenhouse gases are each important aspects of South Africa's goals. Many traditional solutions, however, work in contradiction to one another. This work investigates effects on estimated emissions and costs of mitigation strategies using the Greenhouse Gas and Air Pollution Interaction Synergies (GAINS) model to identify policies that satisfy multiple goals. Eight scenarios that describe air pollution control options and mixes of energy production technologies are implemented in GAINS, which quantifies country-wide air pollution and greenhouse emissions and costs of controls. Emissions and costs trajectories are compared to the business as usual case, which projects CO_2 emissions to increase by 60% by 2050 compared to 2015. Results show that replacing all coal generation with renewables reduces CO_2 emissions in 2050 by 8% compared to 2015, and that aggressive policy targeting the whole energy sector reduces CO_2 emissions in 2050 by 40%. GAINS is used to show co-benefits and tradeoffs of each scenario, such as reductions in emissions control costs that accompany a switch to renewables. The approach provides supporting evidence for policies that exploit co-benefits and avoid contradictions by assessing multiple aspects of the energy sector within the integrated framework provided by the GAINS modeling platform.

  9. National Emission Standards for Hazardous Air Pollutants submittal - 1997

    International Nuclear Information System (INIS)

    Townsend, Y.E.; Black, S.C.

    1998-06-01

    Each potential source of Nevada Test Site (NTS) emissions was characterized by one of the following methods: (1) monitoring methods and procedures previously developed at the NTS; (2) a yearly radionuclide inventory of the source, assuming that volatile radionuclide are released to the environment; (3) the measurement of tritiated water (as HTO or T 2 O) concentration in liquid effluents discharged to containment ponds and assuming all the effluent evaporates over the course of the year to become an air emission; or (4) using a combination of environmental measurements and CAP88-PC to calculate emissions. The emissions for National Emission Standards for Hazardous Air Pollutants (NESHAPs) reporting are listed. They are very conservative and are used in Section 3 to calculate the EDE to the maximally exposed individual offsite. Offsite environmental surveillance data, where available, are used to confirm that calculated emissions are, indeed, conservative

  10. Greenhouse effect: A first estimation of the emissions in Italy

    International Nuclear Information System (INIS)

    Gaudioso, D.; Onufrio, G.

    1991-03-01

    The estimate of the anthropogenic emissions of greenhouse gases and the selection of the relevant emission factors represents a preliminary condition to define policies aiming at curbing these emissions. In the first part of this paper there is an analysis of C0 2 emission factors, referred to the various fuels and energy technologies. The values at issue take into account the physico-chemical composition of the different fossil fuels, as well as the overall efficiency of energy production cycles and end uses patterns. As concerns the other greenhouse gases, the available information is summarized at a much more integrate level. The second part presents some estimates of carbon dioxide emissions in Italy, by sector and by fuel; some characteristic levels of specific emissions are also identified. A comparative estimate for CH 4 , N 2 O, CO and CFC's is also made, in order to set up a first reference table of the emissions of greenhouse gases in our country. (author)

  11. Spatial distribution of emissions to air – the SPREAD model

    DEFF Research Database (Denmark)

    Plejdrup, Marlene Schmidt; Gyldenkærne, Steen

    The National Environmental Research Institute (NERI), Aarhus University, completes the annual national emission inventories for greenhouse gases and air pollutants according to Denmark’s obligations under international conventions, e.g. the climate convention, UNFCCC and the convention on long...... quality modelling in exposure studies. SPREAD includes emission distributions for each sector in the Danish inventory system; stationary combustion, mobile sources, fugitive emissions from fuels, industrial processes, solvents and other product use, agriculture and waste. This model enables generation...

  12. National Emission Standards for Hazardous Air Pollutants submittal -- 1994

    International Nuclear Information System (INIS)

    Townsend, Y.E.; Black, S.C.

    1995-06-01

    This report focuses on air quality at the Nevada Test Site (NTS) for 1994. A general description of the effluent sources are presented. Each potential source of NTS emissions was characterized by one of the following: (1) by monitoring methods and procedures previously developed at NTS; (2) by a yearly radionuclide inventory of the source, assuming that volatile radionuclides are released to the environment; (3) by the measurement of tritiated water concentration in liquid effluents discharged to containment ponds and assuming all the effluent evaporates over the course of the year to become an air emission; or (4) by using a combination of environmental measurements and CAP88-PC to calculate emissions. Appendices A through J describe the methods used to determine the emissions from the sources. These National Emission Standards for Hazardous Air Pollutants (NESHAP) emissions are very conservative, are used to calculate the effective dose equivalent to the Maximally Exposed Individual offsite, and exceed, in some cases, those reported in DOE's Effluent Information System (EIS). The NESHAP's worst-case emissions that exceed the EIS reported emissions are noted. Offsite environmental surveillance data are used to confirm that calculated emissions are, indeed, conservative

  13. California Air Resources board's mobil source emission reduction credit guidelines

    International Nuclear Information System (INIS)

    Dunwoody Lentz, C.; Werner, B.

    1993-01-01

    The California Air Resources Board has developed guidance for the generation and use of mobil source emission reduction credits. Mobil source credits can be used to improve air quality, or to mitigate increases in emissions associated with industrial and non-industrial sources. They are created by programs which reduce mobile source emission beyond the reductions required by federal, state, and local laws or air quality attainment plans. Significant amounts of credit can be generated by some types of programs which reduce mobile source emissions of oxides of nitrogen (NO x ) and reactive organic gases (ROG). Mobile source credit programs must be carefully structured to ensure that emission reductions are real, accurately quantified, enforceable, and have a defined life. Three potentially feasible programs for the creation of mobile source credits include accelerated retirement of older vehicles, purchase of low-emission buses, and purchase of zero-emission vehicles. These programs are evaluated for their ability to generate credit and to assess their cost effectiveness. Based on the examples presented, two methods of generating mobile source credits, the accelerated retirement of older vehicles and the purchase of low-emission buses, appear to be cost-effective when compared to other emission control measures

  14. Spatial distribution of emissions to air - the SPREAD model

    Energy Technology Data Exchange (ETDEWEB)

    Plejdrup, M S; Gyldenkaerne, S

    2011-04-15

    The National Environmental Research Institute (NERI), Aarhus University, completes the annual national emission inventories for greenhouse gases and air pollutants according to Denmark's obligations under international conventions, e.g. the climate convention, UNFCCC and the convention on long-range transboundary air pollution, CLRTAP. NERI has developed a model to distribute emissions from the national emission inventories on a 1x1 km grid covering the Danish land and sea territory. The new spatial high resolution distribution model for emissions to air (SPREAD) has been developed according to the requirements for reporting of gridded emissions to CLRTAP. Spatial emission data is e.g. used as input for air quality modelling, which again serves as input for assessment and evaluation of health effects. For these purposes distributions with higher spatial resolution have been requested. Previously, a distribution on the 17x17 km EMEP grid has been set up and used in research projects combined with detailed distributions for a few sectors or sub-sectors e.g. a distribution for emissions from road traffic on 1x1 km resolution. SPREAD is developed to generate improved spatial emission data for e.g. air quality modelling in exposure studies. SPREAD includes emission distributions for each sector in the Danish inventory system; stationary combustion, mobile sources, fugitive emissions from fuels, industrial processes, solvents and other product use, agriculture and waste. This model enables generation of distributions for single sectors and for a number of sub-sectors and single sources as well. This report documents the methodologies in this first version of SPREAD and presents selected results. Further, a number of potential improvements for later versions of SPREAD are addressed and discussed. (Author)

  15. Spatial distribution of emissions to air - the SPREAD model

    Energy Technology Data Exchange (ETDEWEB)

    Plejdrup, M.S.; Gyldenkaerne, S.

    2011-04-15

    The National Environmental Research Institute (NERI), Aarhus University, completes the annual national emission inventories for greenhouse gases and air pollutants according to Denmark's obligations under international conventions, e.g. the climate convention, UNFCCC and the convention on long-range transboundary air pollution, CLRTAP. NERI has developed a model to distribute emissions from the national emission inventories on a 1x1 km grid covering the Danish land and sea territory. The new spatial high resolution distribution model for emissions to air (SPREAD) has been developed according to the requirements for reporting of gridded emissions to CLRTAP. Spatial emission data is e.g. used as input for air quality modelling, which again serves as input for assessment and evaluation of health effects. For these purposes distributions with higher spatial resolution have been requested. Previously, a distribution on the 17x17 km EMEP grid has been set up and used in research projects combined with detailed distributions for a few sectors or sub-sectors e.g. a distribution for emissions from road traffic on 1x1 km resolution. SPREAD is developed to generate improved spatial emission data for e.g. air quality modelling in exposure studies. SPREAD includes emission distributions for each sector in the Danish inventory system; stationary combustion, mobile sources, fugitive emissions from fuels, industrial processes, solvents and other product use, agriculture and waste. This model enables generation of distributions for single sectors and for a number of sub-sectors and single sources as well. This report documents the methodologies in this first version of SPREAD and presents selected results. Further, a number of potential improvements for later versions of SPREAD are addressed and discussed. (Author)

  16. Radioactive air emissions notice of construction portable/temporary radioactive air emission units - August 1998

    International Nuclear Information System (INIS)

    FRITZ, D.W.

    1999-01-01

    This notice of construction (NOC) requests a categorical approval for construction and operation of three types of portable/temporary radionuclide airborne emission units (PTRAEUs). These three types are portable ventilation-filter systems (Type I), mobile sample preparation facilities (Type II), and mobile sample screening and analysis facilities (Type III). Approval of the NOC application is intended to allow construction and operation of the three types of PTRAEUs without prior project-specific approval. Environmental cleanup efforts on the Hanford Site often require the use of PTRAEUs. The PTRAEUs support site characterization activities, expedited response actions (ERAs), sampling and monitoring activities, and other routine activities. The PTRAEUs operate at various locations around the Hanford Site. Radiation Air Emissions Program, Washington Administrative Code (WAC) 246-247, requires that the Washington State Department of Health (WDOH) be notified before construction of any new emission that would release airborne radioactivity. The WDOH also must receive notification before any modification of an existing source. This includes changes in the source term or replacement of emission control equipment that might significantly contribute to the offsite maximum dose from a licensed facility. During site characterization activities, ERAs, sampling and monitoring activities, and other routine activities, the PTRAEUs might require startup immediately. The notification period hampers efforts to complete such activities in an effective and timely manner. Additionally, notification is to be submitted to the WDOH when the PTRAEUs are turned off. The U.S. Department of Energy, Richland Operations Office (DOE-RL) potentially could generate several notifications monthly. The WDOH would be required to review and provide approval on each NOC as well as review the notices of discontinued sources. The WDOH regulation also allows facilities the opportunity to request a

  17. Emissions of acidifying air pollutants in the North West region of England

    Energy Technology Data Exchange (ETDEWEB)

    Longhurst, J.W.S.; Lindley, S.J.; Conlan, D.E. [Manchester Metropolitan University, Manchester (United Kingdom). Dept. of Environmental and Geographical Sciences

    1995-12-01

    Most estimates of emission are concerned with the nation state level. This paper discusses methods utilised in the estimates of emissions to the atmosphere of sulphur dioxide, volatile organic compounds and oxides of nitrogen from a densely populated and heavily industrialised region of the United Kingdom. Data on power generation from coal, industrial plant, fuel usage, air, sea and road transportation, and human population statistics have been integrated into a method to provide regional emission estimates. The resulting emission patterns are described in terms of sources and emission density. Spatial and temporal patterns are identified and major sources of emissions discussed in terms of national control programmes. Transportation is the dominant source of oxides of nitrogen emissions whilst power generation is the dominant source of sulphur dioxide. The relative importance of the North West as an emission source within the UK is assessed. The change in the strengths of acidifying emissions between 1987 and 1992 is discussed and the rate of change in emission magnitudes between the North West region and the UK as a whole compared. 9 refs., 4 tabs.

  18. Emissions of acidifying air pollutants in the North West region of England

    International Nuclear Information System (INIS)

    Longhurst, J.W.S.; Lindley, S.J.; Conlan, D.E.

    1995-01-01

    Most estimates of emission are concerned with the nation state level. This paper discusses methods utilised in the estimates of emissions to the atmosphere of sulphur dioxide, volatile organic compounds and oxides of nitrogen from a densely populated and heavily industrialised region of the United Kingdom. Data on power generation from coal, industrial plant, fuel usage, air, sea and road transportation, and human population statistics have been integrated into a method to provide regional emission estimates. The resulting emission patterns are described in terms of sources and emission density. Spatial and temporal patterns are identified and major sources of emissions discussed in terms of national control programmes. Transportation is the dominant source of oxides of nitrogen emissions whilst power generation is the dominant source of sulphur dioxide. The relative importance of the North West as an emission source within the UK is assessed. The change in the strengths of acidifying emissions between 1987 and 1992 is discussed and the rate of change in emission magnitudes between the North West region and the UK as a whole compared. 9 refs., 4 tabs

  19. Impacts of Lowered Urban Air Temperatures on Precursor Emission and Ozone Air Quality.

    Science.gov (United States)

    Taha, Haider; Konopacki, Steven; Akbari, Hashem

    1998-09-01

    Meteorological, photochemical, building-energy, and power plant simulations were performed to assess the possible precursor emission and ozone air quality impacts of decreased air temperatures that could result from implementing the "cool communities" concept in California's South Coast Air Basin (SoCAB). Two pathways are considered. In the direct pathway, a reduction in cooling energy use translates into reduced demand for generation capacity and, thus, reduced precursor emissions from electric utility power plants. In the indirect pathway, reduced air temperatures can slow the atmospheric production of ozone as well as precursor emission from anthropogenic and biogenic sources. The simulations suggest small impacts on emissions following implementation of cool communities in the SoCAB. In summer, for example, there can be reductions of up to 3% in NO x emissions from in-basin power plants. The photochemical simulations suggest that the air quality impacts of these direct emission reductions are small. However, the indirect atmospheric effects of cool communities can be significant. For example, ozone peak concentrations can decrease by up to 11% in summer and population-weighted exceedance exposure to ozone above the California and National Ambient Air Quality Standards can decrease by up to 11 and 17%, respectively. The modeling suggests that if these strategies are combined with others, such as mobile-source emission control, the improvements in ozone air quality can be substantial.

  20. Working Toward Policy-Relevant Air Quality Emissions Scenarios

    Science.gov (United States)

    Holloway, T.

    2010-12-01

    Though much work has been done to develop accurate chemical emission inventories, few publicly available inventories are appropriate for realistic policy analysis. Emissions from the electricity and transportation sectors, in particular, respond in complex ways to policy, technology, and energy use change. Many widely used inventories, such as the EPA National Emissions Inventory, are well-suited for modeling current air quality, but do not have the specificity needed to address "what if?" questions. Changes in electricity demand, fuel prices, new power sources, and emission controls all influence the emissions from regional power production, requiring a plant-by-plant assessment to capture the spatially explicit impacts. Similarly, land use, freight distribution, or driving behavior will yield differentiated transportation emissions for urban areas, suburbs, and rural highways. We here present results from three recent research projects at the University of Wisconsin—Madison, where bottom-up emission inventories for electricity, freight transport, and urban vehicle use were constructed to support policy-relevant air quality research. These three studies include: 1) Using the MyPower electricity dispatch model to calculate emissions and air quality impacts of Renewable Portfolio Standards and other carbon-management strategies; 2) Using advanced vehicle and commodity flow data from the Federal Highway Administration to evaluate the potential to shift commodities from truck to rail (assuming expanded infrastructure), and assess a range of alternative fuel suggestions; and 3) Working with urban planners to connect urban density with vehicle use to evaluate the air quality impacts of smart-growth in major Midwest cities. Drawing on the results of these three studies, and on challenges overcome in their execution, we discuss the current state of policy-relevant emission dataset generation, as well as techniques and attributes that need to be further refined in order

  1. Atmospheric Inverse Estimates of Methane Emissions from Central California

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Chuanfeng; Andrews, Arlyn E.; Bianco, Laura; Eluszkiewicz, Janusz; Hirsch, Adam; MacDonald, Clinton; Nehrkorn, Thomas; Fischer, Marc L.

    2008-11-21

    Methane mixing ratios measured at a tall-tower are compared to model predictions to estimate surface emissions of CH{sub 4} in Central California for October-December 2007 using an inverse technique. Predicted CH{sub 4} mixing ratios are calculated based on spatially resolved a priori CH{sub 4} emissions and simulated atmospheric trajectories. The atmospheric trajectories, along with surface footprints, are computed using the Weather Research and Forecast (WRF) coupled to the Stochastic Time-Inverted Lagrangian Transport (STILT) model. An uncertainty analysis is performed to provide quantitative uncertainties in estimated CH{sub 4} emissions. Three inverse model estimates of CH{sub 4} emissions are reported. First, linear regressions of modeled and measured CH{sub 4} mixing ratios obtain slopes of 0.73 {+-} 0.11 and 1.09 {+-} 0.14 using California specific and Edgar 3.2 emission maps respectively, suggesting that actual CH{sub 4} emissions were about 37 {+-} 21% higher than California specific inventory estimates. Second, a Bayesian 'source' analysis suggests that livestock emissions are 63 {+-} 22% higher than the a priori estimates. Third, a Bayesian 'region' analysis is carried out for CH{sub 4} emissions from 13 sub-regions, which shows that inventory CH{sub 4} emissions from the Central Valley are underestimated and uncertainties in CH{sub 4} emissions are reduced for sub-regions near the tower site, yielding best estimates of flux from those regions consistent with 'source' analysis results. The uncertainty reductions for regions near the tower indicate that a regional network of measurements will be necessary to provide accurate estimates of surface CH{sub 4} emissions for multiple regions.

  2. The Impact of Future Emissions Changes on Air Pollution Concentrations and Related Human Health Effects

    Science.gov (United States)

    Mikolajczyk, U.; Suppan, P.; Williams, M.

    2015-12-01

    Quantification of potential health benefits of reductions in air pollution on the local scale is becoming increasingly important. The aim of this study is to conduct health impact assessment (HIA) by utilizing regionally and spatially specific data in order to assess the influence of future emission scenarios on human health. In the first stage of this investigation, a modeling study was carried out using the Weather Research and Forecasting (WRF) model coupled with Chemistry to estimate ambient concentrations of air pollutants for the baseline year 2009, and for the future emission scenarios in southern Germany. Anthropogenic emissions for the baseline year 2009 are derived from the emission inventory provided by the Netherlands Organization of Applied Scientific Research (TNO) (Denier van der Gon et al., 2010). For Germany, the TNO emissions were replaced by gridded emission data with a high spatial resolution of 1/64 x 1/64 degrees. Future air quality simulations are carried out under different emission scenarios, which reflect possible energy and climate measures in year 2030. The model set-up included a nesting approach, where three domains with horizontal resolution of 18 km, 6 km and 2 km were defined. The simulation results for the baseline year 2009 are used to quantify present-day health burdens. Concentration-response functions (CRFs) for PM2.5 and NO2 from the WHO Health risks of air Pollution in Europe (HRAPIE) project were applied to population-weighted mean concentrations to estimate relative risks and hence to determine numbers of attributable deaths and associated life-years lost. In the next step, future health impacts of projected concentrations were calculated taking into account different emissions scenarios. The health benefits that we assume with air pollution reductions can be used to provide options for future policy decisions to protect public health.

  3. Calculating emissions into the air. General methodological principles; Calcul des emissions dans l'air. Principes methodologiques generaux

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-05-01

    Knowing the quantities of certain substances discharged into the atmosphere is a necessary and fundamental stage in any environmental protection policy to tackle today's problems such as acid rain, the degradation of air quality, global warming and climate change, the depletion of the ozone layer, etc. This quantification, usually known as an 'emission inventory', is built on a set of specific rules which may vary from one inventory to another. This state of affairs presents the enormous disadvantage that the data available are not comparable. At the international level, an attempt at harmonization has been going on for some years between the various international bodies. This work is being pursued in parallel with the improvement of methodologies to estimate discharges from various types of source. To take account of changes in specifications and of improvements in our understanding of phenomena giving rise to atmospheric pollution, the results of inventories of emissions need to be regularly revised, even retrospectively, to maintain a consistent series. CITEPA, which acts as a National Reference Centre, has developed a system of inventories as part of the CORALIE programme with financial help from the French Ministry for Planning and the Environment. (author)

  4. Calculating emissions into the air. General methodological principles; Calcul des emissions dans l'air. Principes methodologiques generaux

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-05-01

    Knowing the quantities of certain substances discharged into the atmosphere is a necessary and fundamental stage in any environmental protection policy to tackle today's problems such as acid rain, the degradation of air quality, global warming and climate change, the depletion of the ozone layer, etc. This quantification, usually known as an 'emission inventory', is built on a set of specific rules which may vary from one inventory to another. This state of affairs presents the enormous disadvantage that the data available are not comparable. At the international level, an attempt at harmonization has been going on for some years between the various international bodies. This work is being pursued in parallel with the improvement of methodologies to estimate discharges from various types of source. To take account of changes in specifications and of improvements in our understanding of phenomena giving rise to atmospheric pollution, the results of inventories of emissions need to be regularly revised, even retrospectively, to maintain a consistent series. CITEPA, which acts as a National Reference Centre, has developed a system of inventories as part of the CORALIE programme with financial help from the French Ministry for Planning and the Environment. (author)

  5. Air pollutant emission rates for sources at the Davis Canyon Repository site

    International Nuclear Information System (INIS)

    1985-11-01

    This document summarizes the air-quality source terms used for the Davis Canyon, Utah environmental assessment report and explains their derivation. The engineering data supporting these source terms appear as appendixes to the report and include summary equipment lists for the repository (December, 1984) and detailed equipment lists for the exploratory shaft (June and July, 1985). Although substantial work has been performed in establishing the current repository design, a greater effort will be required for the final design. Consequently, the repository emission rates presented here should be considered as preliminary estimates. Another set of air pollutant emission rates will be calculated after design data are more firmly established. 19 refs., 18 tabs

  6. Air pollutant emission rates for sources at the Deaf Smith County repository site

    International Nuclear Information System (INIS)

    1985-11-01

    This document summarizes the air-quality source terms used for the Deaf Smith County, Texas environmental assessment report and explains their derivation. The engineering data supporting these source terms appear as appendixes to this report and include summary equipment lists for the repository and detailed equipment lists for the exploratory shaft. Although substantial work has been performed in establishing the current repository design, a greater effort will be required for the final design. Consequently, the repository emission rates presented here should be considered as preliminary estimates. Another set of air pollution emission rates will be calculated after design data are more firmly established. 18 refs., 15 tabs

  7. Update estimate emissions degassing inland tank vessels

    Energy Technology Data Exchange (ETDEWEB)

    De Buck, A.; Hoen, M. ' t; Den Boer, E.

    2013-11-15

    At the exchange of cargos of petroleum or chemical products, ships can be degassed, resulting in emissions of VOCs (volatile organic compounds). CE Delft investigated the current size of degassing in the Netherlands. Results can serve as a basis for feasible and effective policies.

  8. Estimating NOx emissions and surface concentrations at high spatial resolution using OMI

    Science.gov (United States)

    Goldberg, D. L.; Lamsal, L. N.; Loughner, C.; Swartz, W. H.; Saide, P. E.; Carmichael, G. R.; Henze, D. K.; Lu, Z.; Streets, D. G.

    2017-12-01

    In many instances, NOx emissions are not measured at the source. In these cases, remote sensing techniques are extremely useful in quantifying NOx emissions. Using an exponential modified Gaussian (EMG) fitting of oversampled Ozone Monitoring Instrument (OMI) NO2 data, we estimate NOx emissions and lifetimes in regions where these emissions are uncertain. This work also presents a new high-resolution OMI NO2 dataset derived from the NASA retrieval that can be used to estimate surface level concentrations in the eastern United States and South Korea. To better estimate vertical profile shape factors, we use high-resolution model simulations (Community Multi-scale Air Quality (CMAQ) and WRF-Chem) constrained by in situ aircraft observations to re-calculate tropospheric air mass factors and tropospheric NO2 vertical columns during summertime. The correlation between our satellite product and ground NO2 monitors in urban areas has improved dramatically: r2 = 0.60 in new product, r2 = 0.39 in operational product, signifying that this new product is a better indicator of surface concentrations than the operational product. Our work emphasizes the need to use both high-resolution and high-fidelity models in order to re-calculate vertical column data in areas with large spatial heterogeneities in NOx emissions. The methodologies developed in this work can be applied to other world regions and other satellite data sets to produce high-quality region-specific emissions estimates.

  9. 77 FR 3223 - National Emissions Standards for Hazardous Air Pollutants: Mineral Wool Production and Wool...

    Science.gov (United States)

    2012-01-23

    ... Emission Standards for Hazardous Air Pollutants: Mineral Wool Production Risk and Technology Review..., Administrative practice and procedure, Air pollution control, Hazardous substances, Intergovernmental relations... National Emissions Standards for Hazardous Air Pollutants: Mineral Wool Production and Wool Fiberglass...

  10. Estimating the burden of disease attributable to indoor air pollution ...

    African Journals Online (AJOL)

    Estimating the burden of disease attributable to indoor air pollution from household ... To estimate the burden of respiratory ill health in South African children and adults in ... Mortality and disability-adjusted life years (DALYs) from acute lower ...

  11. Development of a forecast model for global air traffic emissions

    Energy Technology Data Exchange (ETDEWEB)

    Schaefer, Martin

    2012-07-01

    The thesis describes the methodology and results of a simulation model that quantifies fuel consumption and emissions of civil air traffic. Besides covering historical emissions, the model aims at forecasting emissions in the medium-term future. For this purpose, simulation models of aircraft and engine types are used in combination with a database of global flight movements and assumptions about traffic growth, fleet rollover and operational aspects. Results from an application of the model include emissions of scheduled air traffic for the years 2000 to 2010 as well as forecasted emissions until the year 2030. In a baseline scenario of the forecast, input assumptions (e.g. traffic growth rates) are in line with predictions by the aircraft industry. Considering the effects of advanced technologies of the short-term and medium-term future, the forecast focusses on fuel consumption and emissions of nitric oxides. Calculations for historical air traffic additionally cover emissions of carbon monoxide, unburned hydrocarbons and soot. Results are validated against reference data including studies by the International Civil Aviation Organization (ICAO) and simulation results from international research projects. (orig.)

  12. Emissions from oil and gas operations in the United States and their air quality implications.

    Science.gov (United States)

    Allen, David T

    2016-06-01

    The energy supply infrastructure in the United States has been changing dramatically over the past decade. Increased production of oil and natural gas, particularly from shale resources using horizontal drilling and hydraulic fracturing, made the United States the world's largest producer of oil and natural gas in 2014. This review examines air quality impacts, specifically, changes in greenhouse gas, criteria air pollutant, and air toxics emissions from oil and gas production activities that are a result of these changes in energy supplies and use. National emission inventories indicate that volatile organic compound (VOC) and nitrogen oxide (NOx) emissions from oil and gas supply chains in the United States have been increasing significantly, whereas emission inventories for greenhouse gases have seen slight declines over the past decade. These emission inventories are based on counts of equipment and operational activities (activity factors), multiplied by average emission factors, and therefore are subject to uncertainties in these factors. Although uncertainties associated with activity data and missing emission source types can be significant, multiple recent measurement studies indicate that the greatest uncertainties are associated with emission factors. In many source categories, small groups of devices or sites, referred to as super-emitters, contribute a large fraction of emissions. When super-emitters are accounted for, multiple measurement approaches, at multiple scales, produce similar results for estimated emissions. Challenges moving forward include identifying super-emitters and reducing their emission magnitudes. Work done to date suggests that both equipment malfunction and operational practices can be important. Finally, although most of this review focuses on emissions from energy supply infrastructures, the regional air quality implications of some coupled energy production and use scenarios are examined. These case studies suggest that both

  13. Air Emissions Damages from Municipal Drinking Water Treatment Under Current and Proposed Regulatory Standards.

    Science.gov (United States)

    Gingerich, Daniel B; Mauter, Meagan S

    2017-09-19

    Water treatment processes present intersectoral and cross-media risk trade-offs that are not presently considered in Safe Drinking Water Act regulatory analyses. This paper develops a method for assessing the air emission implications of common municipal water treatment processes used to comply with recently promulgated and proposed regulatory standards, including concentration limits for, lead and copper, disinfection byproducts, chromium(VI), strontium, and PFOA/PFOS. Life-cycle models of electricity and chemical consumption for individual drinking water unit processes are used to estimate embedded NO x , SO 2 , PM 2.5 , and CO 2 emissions on a cubic meter basis. We estimate air emission damages from currently installed treatment processes at U.S. drinking water facilities to be on the order of $500 million USD annually. Fully complying with six promulgated and proposed rules would increase baseline air emission damages by approximately 50%, with three-quarters of these damages originating from chemical manufacturing. Despite the magnitude of these air emission damages, the net benefit of currently implemented rules remains positive. For some proposed rules, however, the promise of net benefits remains contingent on technology choice.

  14. Sampling for Air Chemical Emissions from the Life Sciences Laboratory II

    Energy Technology Data Exchange (ETDEWEB)

    Ballinger, Marcel Y. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lindberg, Michael J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2017-03-30

    Sampling for air chemical emissions from the Life Science Laboratory II (LSL-II) ventilation stack was performed in an effort to determine potential exposure of maintenance staff to laboratory exhaust on the building roof. The concern about worker exposure was raised in December 2015 and several activities were performed to assist in estimating exposure concentrations. Data quality objectives were developed to determine the need for and scope and parameters of a sampling campaign to measure chemical emissions from research and development activities to the outside air. The activities provided data on temporal variation of air chemical concentrations and a basis for evaluating calculated emissions. Sampling for air chemical emissions was performed in the LSL-II ventilation stack over the 6-week period from July 26 to September 1, 2016. A total of 12 sampling events were carried out using 16 sample media. Resulting analysis provided concentration data on 49 analytes. All results were below occupational exposure limits and most results were below detection limits. When compared to calculated emissions, only 5 of the 49 chemicals had measured concentrations greater than predicted. This sampling effort will inform other study components to develop a more complete picture of a worker’s potential exposure from LSL-II rooftop activities. Mixing studies were conducted to inform spatial variation in concentrations at other rooftop locations and can be used in conjunction with these results to provide temporal variations in concentrations for estimating the potential exposure to workers working in and around the LSL-II stack.

  15. Estimating Vehicle Fuel Consumption and Emissions Using GPS Big Data

    Directory of Open Access Journals (Sweden)

    Zihan Kan

    2018-03-01

    Full Text Available The energy consumption and emissions from vehicles adversely affect human health and urban sustainability. Analysis of GPS big data collected from vehicles can provide useful insights about the quantity and distribution of such energy consumption and emissions. Previous studies, which estimated fuel consumption/emissions from traffic based on GPS sampled data, have not sufficiently considered vehicle activities and may have led to erroneous estimations. By adopting the analytical construct of the space-time path in time geography, this study proposes methods that more accurately estimate and visualize vehicle energy consumption/emissions based on analysis of vehicles’ mobile activities (MA and stationary activities (SA. First, we build space-time paths of individual vehicles, extract moving parameters, and identify MA and SA from each space-time path segment (STPS. Then we present an N-Dimensional framework for estimating and visualizing fuel consumption/emissions. For each STPS, fuel consumption, hot emissions, and cold start emissions are estimated based on activity type, i.e., MA, SA with engine-on and SA with engine-off. In the case study, fuel consumption and emissions of a single vehicle and a road network are estimated and visualized with GPS data. The estimation accuracy of the proposed approach is 88.6%. We also analyze the types of activities that produced fuel consumption on each road segment to explore the patterns and mechanisms of fuel consumption in the study area. The results not only show the effectiveness of the proposed approaches in estimating fuel consumption/emissions but also indicate their advantages for uncovering the relationships between fuel consumption and vehicles’ activities in road networks.

  16. Estimating Vehicle Fuel Consumption and Emissions Using GPS Big Data.

    Science.gov (United States)

    Kan, Zihan; Tang, Luliang; Kwan, Mei-Po; Zhang, Xia

    2018-03-21

    The energy consumption and emissions from vehicles adversely affect human health and urban sustainability. Analysis of GPS big data collected from vehicles can provide useful insights about the quantity and distribution of such energy consumption and emissions. Previous studies, which estimated fuel consumption/emissions from traffic based on GPS sampled data, have not sufficiently considered vehicle activities and may have led to erroneous estimations. By adopting the analytical construct of the space-time path in time geography, this study proposes methods that more accurately estimate and visualize vehicle energy consumption/emissions based on analysis of vehicles' mobile activities ( MA ) and stationary activities ( SA ). First, we build space-time paths of individual vehicles, extract moving parameters, and identify MA and SA from each space-time path segment (STPS). Then we present an N-Dimensional framework for estimating and visualizing fuel consumption/emissions. For each STPS, fuel consumption, hot emissions, and cold start emissions are estimated based on activity type, i.e., MA , SA with engine-on and SA with engine-off. In the case study, fuel consumption and emissions of a single vehicle and a road network are estimated and visualized with GPS data. The estimation accuracy of the proposed approach is 88.6%. We also analyze the types of activities that produced fuel consumption on each road segment to explore the patterns and mechanisms of fuel consumption in the study area. The results not only show the effectiveness of the proposed approaches in estimating fuel consumption/emissions but also indicate their advantages for uncovering the relationships between fuel consumption and vehicles' activities in road networks.

  17. Transport and Environment Database System (TRENDS): Maritime Air Pollutant Emission Modelling

    DEFF Research Database (Denmark)

    Georgakaki, Aliki; Coffey, Robert; Lock, Grahm

    2005-01-01

    This paper reports the development of the maritime module within the framework of the Transport and Environment Database System (TRENDS) project. A detailed database has been constructed for the calculation of energy consumption and air pollutant emissions. Based on an in-house database...... changes from findings reported in Methodologies for Estimating air pollutant Emissions from Transport (MEET). The database operates on statistical data provided by Eurostat, which describe vessel and freight movements from and towards EU 15 major ports. Data are at port to Maritime Coastal Area (MCA...... with a view to this purpose, are mentioned. Examples of the results obtained by the database are presented. These include detailed air pollutant emission calculations for bulk carriers entering the port of Helsinki, as an example of the database operation, and aggregate results for different types...

  18. Radioactive air emissions from non-uranium mining operations

    International Nuclear Information System (INIS)

    Silhanek, J.S.; Andrews, V.E.

    1981-01-01

    Section 122 of the Clean Air Act Amendments of 1977, Public Law 9595, directed the Administrator of the Environmental Protection Agency to review all relevant information and determine whether emissions of radioactive pollutants into ambient air will cause or contribute to air pollution which may reasonably be anticipated to endanger public health. A section of this document presented a theoretical analysis of the radioactive airborne emissions from several non-uranium mines including iron, copper, zinc, clay, limestone, fluorspar, and phosphate. Since 1978 EPA's Las Vegas Laboratory has been gathering field data on actual radionuclide emissions from these mines to support the earlier theoretical analysis. The purpose of this paper is to present the results of those field measurements in comparison with the assumed values for the theoretical analysis

  19. Estimation of economic costs of particulate air pollution from road transport in China

    Science.gov (United States)

    Guo, X. R.; Cheng, S. Y.; Chen, D. S.; Zhou, Y.; Wang, H. Y.

    2010-09-01

    Valuation of health effects of air pollution is becoming a critical component of the performance of cost-benefit analysis of pollution control measures, which provides a basis for setting priorities for action. Beijing has focused on control of transport emission as vehicular emissions have recently become an important source of air pollution, particularly during Olympic games and Post-games. In this paper, we conducted an estimation of health effects and economic cost caused by road transport-related air pollution using an integrated assessment approach which utilizes air quality model, engineering, epidemiology, and economics. The results show that the total economic cost of health impacts due to air pollution contributed from transport in Beijing during 2004-2008 was 272, 297, 310, 323, 298 million US (mean value), respectively. The economic costs of road transport accounted for 0.52, 0.57, 0.60, 0.62, and 0.58% of annual Beijing GDP from 2004 to 2008. Average cost per vehicle and per ton of PM 10 emission from road transport can also be estimated as 106 US /number and 3584 US $ t -1, respectively. These findings illustrate that the impact of road transport contributed particulate air pollution on human health could be substantial in Beijing, whether in physical and economic terms. Therefore, some control measures to reduce transport emissions could lead to considerable economic benefit.

  20. Estimating the Impact of Urbanization on Air Quality in China Using Spatial Regression Models

    OpenAIRE

    Fang, Chuanglin; Liu, Haimeng; Li, Guangdong; Sun, Dongqi; Miao, Zhuang

    2015-01-01

    Urban air pollution is one of the most visible environmental problems to have accompanied China’s rapid urbanization. Based on emission inventory data from 2014, gathered from 289 cities, we used Global and Local Moran’s I to measure the spatial autorrelation of Air Quality Index (AQI) values at the city level, and employed Ordinary Least Squares (OLS), Spatial Lag Model (SAR), and Geographically Weighted Regression (GWR) to quantitatively estimate the comprehensive impact and spatial variati...

  1. Large Gain in Air Quality Compared to an Alternative Anthropogenic Emissions Scenario

    Science.gov (United States)

    Daskalakis, Nikos; Tsigaridis, Kostas; Myriokefalitakis, Stelios; Fanourgakis, George S.; Kanakidou, Maria

    2016-01-01

    During the last 30 years, significant effort has been made to improve air quality through legislation for emissions reduction. Global three-dimensional chemistrytransport simulations of atmospheric composition over the past 3 decades have been performed to estimate what the air quality levels would have been under a scenario of stagnation of anthropogenic emissions per capita as in 1980, accounting for the population increase (BA1980) or using the standard practice of neglecting it (AE1980), and how they compare to the historical changes in air quality levels. The simulations are based on assimilated meteorology to account for the yearto- year observed climate variability and on different scenarios of anthropogenic emissions of pollutants. The ACCMIP historical emissions dataset is used as the starting point. Our sensitivity simulations provide clear indications that air quality legislation and technology developments have limited the rapid increase of air pollutants. The achieved reductions in concentrations of nitrogen oxides, carbon monoxide, black carbon, and sulfate aerosols are found to be significant when comparing to both BA1980 and AE1980 simulations that neglect any measures applied for the protection of the environment. We also show the potentially large tropospheric air quality benefit from the development of cleaner technology used by the growing global population. These 30-year hindcast sensitivity simulations demonstrate that the actual benefit in air quality due to air pollution legislation and technological advances is higher than the gain calculated by a simple comparison against a constant anthropogenic emissions simulation, as is usually done. Our results also indicate that over China and India the beneficial technological advances for the air quality may have been masked by the explosive increase in local population and the disproportional increase in energy demand partially due to the globalization of the economy.

  2. Large gain in air quality compared to an alternative anthropogenic emissions scenario

    Directory of Open Access Journals (Sweden)

    N. Daskalakis

    2016-08-01

    Full Text Available During the last 30 years, significant effort has been made to improve air quality through legislation for emissions reduction. Global three-dimensional chemistry-transport simulations of atmospheric composition over the past 3 decades have been performed to estimate what the air quality levels would have been under a scenario of stagnation of anthropogenic emissions per capita as in 1980, accounting for the population increase (BA1980 or using the standard practice of neglecting it (AE1980, and how they compare to the historical changes in air quality levels. The simulations are based on assimilated meteorology to account for the year-to-year observed climate variability and on different scenarios of anthropogenic emissions of pollutants. The ACCMIP historical emissions dataset is used as the starting point. Our sensitivity simulations provide clear indications that air quality legislation and technology developments have limited the rapid increase of air pollutants. The achieved reductions in concentrations of nitrogen oxides, carbon monoxide, black carbon, and sulfate aerosols are found to be significant when comparing to both BA1980 and AE1980 simulations that neglect any measures applied for the protection of the environment. We also show the potentially large tropospheric air quality benefit from the development of cleaner technology used by the growing global population. These 30-year hindcast sensitivity simulations demonstrate that the actual benefit in air quality due to air pollution legislation and technological advances is higher than the gain calculated by a simple comparison against a constant anthropogenic emissions simulation, as is usually done. Our results also indicate that over China and India the beneficial technological advances for the air quality may have been masked by the explosive increase in local population and the disproportional increase in energy demand partially due to the globalization of the economy.

  3. Effect of low emission sources on air quality in Cracow

    Energy Technology Data Exchange (ETDEWEB)

    Nedoma, J. [EKOPOL Environmental Engineering Studies and Design Office, Co. Ltd., Cracow (Poland)

    1995-12-31

    The paper presents calculation of power engineering low emission and results of stimulation of the effect of this emission on air quality in Cracow, Poland. It has been stated that the segment of low emission in central areas of the town makes up ca. 40% of the observed concentration of sulfur dioxide. Furthermore it has been stated that the capital investment must be concentrated in the central part of the town in order to reach noticeable improvement of air quality in Cracow. Neither the output of a separate power source nor the emission level and its individual harmful effect, but the location of the source and especially packing density of the sources must decide the priority of upgrading actions.

  4. Estimating HAPs and radionuclide emissions from a laboratory complex at a nuclear processing site

    International Nuclear Information System (INIS)

    Paul, R.A.; Faugl, T.

    1993-01-01

    A unique methodology was developed for conducting an air emission inventory (AEI) at a DOE nuclear processing facility. This methodology involved the use of computer-assisted design (CAD) drawings to document emission points, computerized process drawings to document industrial processes leading to emissions, and a computerized data base of AEI forms to document emission estimates and related process data. A detailed air emissions inventory for operating years 1985--1991 was recently implemented for the entire site using this methodology. One industrial area at the DOE Site is comprised of laboratory facilities that provide direct support to the nuclear reactor and recovery operations, developmental studies to support reactor and separation operations, and developmental studies to support waste handling and storage. The majority of the functions are conducted in a single large building complex wherein bench scale and pilot scale experiments are carried out involving radionuclides, hazardous air pollutants (HAP), and other chemicals reportable under the Clean Air Act Amendments (CAAA) and Superfund Amendments and Re-authorization Act (SARA) Title 111. The results of the inventory showed that HAP and radionuclide emissions from the laboratory complex were relatively minor

  5. Air emissions assessment from offshore oil activities in Sonda de Campeche, Mexico.

    Science.gov (United States)

    Schifter, I; González-Macías, C; Miranda, A; López-Salinas, E

    2005-10-01

    Air emission data from offshore oil platforms, gas and oil processing installations and contribution of marine activities at the Sonda de Campeche, located at the Gulf of Mexico, were compiled and integrated to facilitate the study of long range transport of pollutants into the region. From this important region, roughly 76% of the total Mexican oil and gas production is obtained. It was estimated that the total air emissions of all contaminants are approximately 821,000 tons per year. Hydrocarbons are the largest pollutant emissions with 277,590 tons per year, generated during flaring activities, and SOx in second place with 185,907 tons per year. Marine and aviation activities contribute with less than 2% of total emissions. Mass of pollutants emitted per barrel of petroleum produced calculated in this work, are in the range reported by similar oil companies.

  6. Air pollution from industrial waste gas emissions is associated with cancer incidences in Shanghai, China.

    Science.gov (United States)

    Cong, Xiaowei

    2018-05-01

    Outdoor air pollution may be associated with cancer risk at different sites. This study sought to investigate outdoor air pollution from waste gas emission effects on multiple cancer incidences in a retrospective population-based study in Shanghai, China. Trends in cancer incidence for males and females and trends in waste gas emissions for the total waste gas, industrial waste gas, other waste gas, SO 2 , and soot were investigated between 1983 and 2010 in Shanghai, China. Regression models after adjusting for confounding variables were constructed to estimate associations between waste gas emissions and multiple cancer incidences in the whole group and stratified by sex, Engel coefficient, life expectancy, and number of doctors per 10,000 populations to further explore whether changes of waste gas emissions were associated with multiple cancer incidences. More than 550,000 new cancer patients were enrolled and reviewed. Upward trends in multiple cancer incidences for males and females and in waste gas emissions were observed from 1983 to 2010 in Shanghai, China. Waste gas emissions came mainly from industrial waste gas. Waste gas emissions was significantly positively associated with cancer incidence of salivary gland, small intestine, colorectal, anus, gallbladder, thoracic organs, connective and soft tissue, prostate, kidney, bladder, thyroid, non-Hodgkin's lymphoma, lymphatic leukemia, myeloid leukemia, and other unspecified sites (all p emissions and the esophagus cancer incidence was observed (p emissions was associated with multiple cancer incidences.

  7. Emission to air, water and ground: legislation in Norway

    International Nuclear Information System (INIS)

    Hansen, Dag Horsberg

    2001-01-01

    The article discusses Norwegian legislation on emission to air, water and ground. Pollution in the sense of the law is defined as ''the addition of solid matter, gas or liquid to air, water or ground''. The concept of pollution is, however, more far-reaching as even noise, light and radiation may be regarded as pollution although these are not discussed. Any pollution is prohibited. But there are two exceptions: commonly accepted pollutions such as arising from wood burning and agriculture, and emissions allowed by special permission from the National State Pollution Control Authority. The article also discusses liability issues

  8. U.S. DOE 2004 LANL Radionuclide Air Emissions

    International Nuclear Information System (INIS)

    K.W. Jacobson

    2005-01-01

    Amendments to the Clean Air Act, which added radionuclides to the National Emissions Standards for Hazardous Air Pollutants (NESHAP), went into effect in 1990. Specifically, a subpart (H) of 40 CFR 61 established an annual limit on the impact to the public attributable to emissions of radionuclides from U.S. Department of Energy facilities, such as the Los Alamos National Laboratory (LANL). As part of the new NESHAP regulations, LANL must submit an annual report to the U.S. Environmental Protection Agency headquarters and the regional office in Dallas by June 30. This report includes results of monitoring at LANL and the dose calculations for the calendar year 2004

  9. RADIONUCLIDE AIR EMISSIONS REPORT FOR THE HANFORD SITE CY2003

    International Nuclear Information System (INIS)

    ROKKAN, D.J.

    2004-01-01

    This report documents radionuclide air emissions from the US Department of Energy (DOE) Hanford Site in 2003 and the resulting effective dose equivalent (EDE) to the maximally exposed individual (MEI) member of the public. The report has been prepared in accordance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants, Subpart H, ''National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities''; Washington Administrative Code (WAC) Chapter 246-247, ''Radiation Protection-Air Emissions''; 10 CFR 830.120, Quality Assurance; DOE Order 414.1B, Quality Assurance; NQA-1, Quality Assurance Requirements for Nuclear Facility Application; EPA QA/R-2, EPA Requirements for Quality Management Plans; and EPA QA/R-5, Requirements for Quality Assurance Project Plans. The federal regulations in Subpart H of 40 CFR 61 require the measurement and reporting of radionuclides emitted from DOE facilities and the resulting public dose from those emissions. A standard of 10 mrem/yr EDE is not to be exceeded. The EDE to the MEI due to routine and nonroutine emissions in 2003 from Hanford Site point sources was 0.022 mrem (0.00022 mSv), or 0.22 percent of the federal standard. The portions of the Hanford Site MEI dose attributable to individual point sources as listed in Section 2.0 are appropriate for use in demonstrating the compliance of abated stack emissions with applicable terms of the Hanford Site Air Operating Permit and of Notices of Construction. The state has adopted the 40 CFR 61 standard of 10 mrem/yr EDE into their regulations, yet further requires that the EDE to the MEI be calculated not only from point source emissions but also from diffuse and fugitive sources of emissions. WAC 246-247 also requires the reporting of radionuclide emissions from all Hanford Site sources during routine as well as nonroutine operations. The EDE from

  10. Physical Sciences Facility Air Emission Control Equivalency Evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Brown, David M.; Belew, Shan T.

    2008-10-17

    This document presents the adequacy evaluation for the application of technology standards during design, fabrication, installation and testing of radioactive air exhaust systems at the Physical Sciences Facility (PSF), located on the Horn Rapids Triangle north of the Pacific Northwest National Laboratory (PNNL) complex. The analysis specifically covers the exhaust portion of the heating, ventilation and air conditioning (HVAC) systems associated with emission units EP-3410-01-S, EP-3420-01-S and EP 3430-01-S.

  11. Description of Latvian Metal Production and Processing Enterprises' Air Emissions

    OpenAIRE

    Pubule, J; Zahare, D; Blumberga, D

    2010-01-01

    The metal production and processing sector in Latvia has acquired a stable position in the national economy. Smelting of ferrous and nonferrous metals, production of metalware, galvanisation, etc. are developed in Latvia. The metal production and processing sector has an impact on air quality due to polluting substances which are released in the air from metal treatment processes. Therefore it is necessary to determine the total volume of emissions produced by the metal production and process...

  12. PestLCI - a model for estimating field emissions of pesticides in agricultural LCA

    DEFF Research Database (Denmark)

    Birkved, Morten; Hauschild, Michael Zwicky

    2006-01-01

    of a product or service is a specific element of LCA termed life cycle inventory (LCI). Estimation of chemical emissions in agricultural LCA is typically based on standard emission factors which at best are determined by a few physical-chemical substance properties and the use scenario of the chemical compound...... to the different environmental compartments. It estimates the fractions of the applied quantity which is emitted to the air, surface water, and groundwater compartment based on information which will normally be available to the model user about: type and time of application, crop species and development stage...... for other regions of the world. (c) 2006 Elsevier B.V. All rights reserved....

  13. Air pollution radiative forcing from specific emissions sectors at 2030

    Science.gov (United States)

    Unger, Nadine; Shindell, Drew T.; Koch, Dorothy M.; Streets, David G.

    2008-01-01

    Reduction of short-lived air pollutants can contribute to mitigate global warming in the near-term with ancillary benefits to human health. However, the radiative forcings of short-lived air pollutants depend on the location and source type of the precursor emissions. We apply the Goddard Institute for Space Studies atmospheric composition-climate model to quantify near-future (2030 A1B) global annual mean radiative forcing by ozone (O3) and sulfate from six emissions sectors in seven geographic regions. At 2030 the net forcings from O3, sulfate, black and organic carbon, and indirect CH4 effects for each emission sector are (in mWm-2) biomass burning, +95; domestic, +68; transportation, +67; industry, -131; and power, -224. Biomass burning emissions in East Asia and central and southern Africa, domestic biofuel emissions in East Asia, south Asia, and central and southern Africa, and transportation emissions in Europe and North America have large net positive forcings and are therefore attractive targets to counter global warming. Power and industry emissions from East Asia, south Asia, and north Africa and the Middle East have large net negative forcings. Therefore air quality control measures that affect these regional sectors require offsetting climate measures to avoid a warming impact. Linear relationships exist between O3 forcing and biomass burning and domestic biofuel CO precursor emissions independent of region with sensitivity of +0.2 mWm-2/TgCO. Similarly, linear relationships exist between sulfate forcing and SO2 precursor emissions that depend upon region but are independent of sector with sensitivities ranging from -3 to -12 mWm-2/TgS.

  14. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    Energy Technology Data Exchange (ETDEWEB)

    de la Rue du Can, Stephane; Wenzel, Tom; Price, Lynn

    2008-08-13

    Central to any study of climate change is the development of an emission inventory that identifies and quantifies the State's primary anthropogenic sources and sinks of greenhouse gas (GHG) emissions. CO2 emissions from fossil fuel combustion accounted for 80 percent of California GHG emissions (CARB, 2007a). Even though these CO2 emissions are well characterized in the existing state inventory, there still exist significant sources of uncertainties regarding their accuracy. This report evaluates the CO2 emissions accounting based on the California Energy Balance database (CALEB) developed by Lawrence Berkeley National Laboratory (LBNL), in terms of what improvements are needed and where uncertainties lie. The estimated uncertainty for total CO2 emissions ranges between -21 and +37 million metric tons (Mt), or -6percent and +11percent of total CO2 emissions. The report also identifies where improvements are needed for the upcoming updates of CALEB. However, it is worth noting that the California Air Resources Board (CARB) GHG inventory did not use CALEB data for all combustion estimates. Therefore the range in uncertainty estimated in this report does not apply to the CARB's GHG inventory. As much as possible, additional data sources used by CARB in the development of its GHG inventory are summarized in this report for consideration in future updates to CALEB.

  15. Past, Present, and Future Anthropogenic Emissions over Asia: a Regional Air Quality Modeling Perspective

    Science.gov (United States)

    Woo, Jung-Hun; Jung, Bujeon; Choi, Ki-Chul; Seo, Ji-Hyun; Kim, Tae Hyung; Park, Rokjin J.; Youn, Daeok; Jeong, Jaein; Moon, Byung-Kwon; Yeh, Sang-Wook

    2010-05-01

    Climate change will also affect future regional air quality which has potential human health, ecosystem, and economic implications. To analyze the impacts of climate change on Asian air quality, the NIER (National Institute of Environmental Research, Korea) integrated modeling framework was developed based on global-to-regional climate and atmospheric chemistry models. In this study, we developed emission inventories for the modeling framework for 1980~2100 with an emphasis on Asia emissions. Two emission processing systems which have functions of emission projection, spatial/temporal allocation, and chemical speciation have been also developed in support of atmospheric chemistry models including GEOS-Chem and Models-3/CMAQ. Asia-based emission estimates, projection factors, temporal allocation parameters were combined to improve regional modeling capability of past, present and future air quality over Asia. The global CO emissions show a 23% decrease from the years 1980 to 2000. For the future CO (from year 2000 to 2100), the A2 scenario shows a 95% increase due to the B40 (Residential-Biofuel) sector of Western Africa, Eastern Africa and East Asia and the F51 (Transport Road-Fossil fuel) sector of Middle East, USA and South Asia. The B1 scenario, however, shows a 79% decrease of emissions due to B40 and F51 sectors of East Asia, South Asia and USA for the same period. In many cases, Asian emissions play important roles for global emission increase or decrease depending on the IPCC scenarios considered. The regional ozone forming potential will be changed due to different VOC/NOx emission ratio changes in the future. More similarities and differences of Asian emission characteristics, in comparison with its global counterpart, are investigated.

  16. Seward CFB boilers will curb water pollution and air emissions

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-03-01

    When Reliant Energy Co's Seward station begins commercial operation in 2004, it will replace an 80-yr-old pulverized-coal plant with a circulating fluidized bed (CFB) facility that more than doubles the capacity while slashing total air emissions. The baseload facility, located in Indiana County, PA, will be fuelled by local low-grade waste coal. Added to the back end of the two 292-MW CFB boilers, selective noncatalytic reduction equipment will lower NOx emissions, and ALSTOM's flash dryer absorber (FDA) system will lower SO{sub 2} emissions whilst using less limestone. 3 photos.

  17. Unpaid ecological costs related to emissions in the air

    International Nuclear Information System (INIS)

    Moreau, Sylvain; Bottin, Anne; Nauroy, Frederic; Boitard, Corinne; Bird, Geoffrey; David, Michel; Greffet, Pierre; Mordant, Guillaume; Moreau, Sylvain; Nirascou, Francoise; Le Moullec, Aurelie; Berthier, Jean-Pierre; Hassan, Marie-Elizabeth; Curri-Lemaitre, Elen; Lagarenne, Christine; Devaux, Jeremy; Nicklaus, Doris; Puydarrieux, Philippe; Vanoli, Andre; Schucht, Simone

    2014-05-01

    This study proposes an analysis of unpaid ecological terms based on the use of new economic indicators related to sustainable development (going beyond the GDP, adjusted accounting aggregates, accounting unpaid ecological costs), an analysis of unpaid ecological costs related to climate change (context, used results and data, definitions of trajectories associated with greenhouse gas emissions, cost to be applied to emissions to get rid of, assessment of unpaid ecological costs), and an analysis of unpaid ecological costs related to air pollution (objectives, standard to be adopted, towards more ambitious emission reduction and re-assessed costs, unpaid ecological costs in 2010)

  18. Characterization of air freshener emission: the potential health effects.

    Science.gov (United States)

    Kim, Sanghwa; Hong, Seong-Ho; Bong, Choon-Keun; Cho, Myung-Haing

    2015-01-01

    Air freshener could be one of the multiple sources that release volatile organic compounds (VOCs) into the indoor environment. The use of these products may be associated with an increase in the measured level of terpene, such as xylene and other volatile air freshener components, including aldehydes, and esters. Air freshener is usually used indoors, and thus some compounds emitted from air freshener may have potentially harmful health impacts, including sensory irritation, respiratory symptoms, and dysfunction of the lungs. The constituents of air fresheners can react with ozone to produce secondary pollutants such as formaldehyde, secondary organic aerosol (SOA), oxidative product, and ultrafine particles. These pollutants then adversely affect human health, in many ways such as damage to the central nervous system, alteration of hormone levels, etc. In particular, the ultrafine particles may induce severe adverse effects on diverse organs, including the pulmonary and cardiovascular systems. Although the indoor use of air freshener is increasing, deleterious effects do not manifest for many years, making it difficult to identify air freshener-associated symptoms. In addition, risk assessment recognizes the association between air fresheners and adverse health effects, but the distinct causal relationship remains unclear. In this review, the emitted components of air freshener, including benzene, phthalate, and limonene, were described. Moreover, we focused on the health effects of these chemicals and secondary pollutants formed by the reaction with ozone. In conclusion, scientific guidelines on emission and exposure as well as risk characterization of air freshener need to be established.

  19. Estimation of regional air-quality damages from Marcellus Shale natural gas extraction in Pennsylvania

    International Nuclear Information System (INIS)

    Litovitz, Aviva; Abramzon, Shmuel; Curtright, Aimee; Samaras, Constantine; Burger, Nicholas

    2013-01-01

    This letter provides a first-order estimate of conventional air pollutant emissions, and the monetary value of the associated environmental and health damages, from the extraction of unconventional shale gas in Pennsylvania. Region-wide estimated damages ranged from $7.2 to $32 million dollars for 2011. The emissions from Pennsylvania shale gas extraction represented only a few per cent of total statewide emissions, and the resulting statewide damages were less than those estimated for each of the state’s largest coal-based power plants. On the other hand, in counties where activities are concentrated, NO x emissions from all shale gas activities were 20–40 times higher than allowable for a single minor source, despite the fact that individual new gas industry facilities generally fall below the major source threshold for NO x . Most emissions are related to ongoing activities, i.e., gas production and compression, which can be expected to persist beyond initial development and which are largely unrelated to the unconventional nature of the resource. Regulatory agencies and the shale gas industry, in developing regulations and best practices, should consider air emissions from these long-term activities, especially if development occurs in more populated areas of the state where per-ton emissions damages are significantly higher. (letter)

  20. Velocity Estimate Following Air Data System Failure

    National Research Council Canada - National Science Library

    McLaren, Scott A

    2008-01-01

    .... A velocity estimator (VEST) algorithm was developed to combine the inertial and wind velocities to provide an estimate of the aircraft's current true velocity to be used for command path gain scheduling and for display in the cockpit...

  1. Emission of toxic air pollutants from biomass combustion

    International Nuclear Information System (INIS)

    Houck, J.E.; Barnett, S.G.; Roholt, R.B.; Rock, M.E.

    1991-01-01

    Combustion of biomass for power generation, home heating, process steam generation, and waste disposal constitutes a major source of air pollutants nationwide. Emissions from hog-fueled boilers, demolition wood-fired power plants, municipal waste incinerators, woodstoves, fireplaces, pellet stoves, agricultural burning, and forestry burning have been characterized for a variety of purposes. These have included risk assessment, permitting, emission inventory development, source profiling for receptor modeling, and control technology evaluations. From the results of the source characterization studies a compilation of emission factors for criteria and non-criteria pollutants are presented here. Key among these pollutants are polycyclic aromatic hydrocarbons, priority pollutant metals, carbon monoxide, sulfur dioxide, nitrous oxides, and PM 10 particles. The emission factors from the biomass combustion processes are compared and contrasted with other pollutant sources. In addition, sampling and analysis procedures most appropriate for characterizing emissions from the biomass combustion sources are also discussed

  2. Methane Emission Estimates from Landfills Obtained with Dynamic Plume Measurements

    International Nuclear Information System (INIS)

    Hensen, A.; Scharff, H.

    2001-01-01

    Methane emissions from 3 different landfills in the Netherlands were estimated using a mobile Tuneable Diode Laser system (TDL). The methane concentration in the cross section of the plume is measured downwind of the source on a transect perpendicular to the wind direction. A gaussian plume model was used to simulate the concentration levels at the transect. The emission from the source is calculated from the measured and modelled concentration levels.Calibration of the plume dispersion model is done using a tracer (N 2 O) that is released from the landfill and measured simultaneously with the TDL system. The emission estimates for the different locations ranged from 3.6 to 16 m 3 ha -1 hr -1 for the different sites. The emission levels were compared to emission estimates based on the landfill gas production models. This comparison suggests oxidation rates that are up to 50% in spring and negligible in November. At one of the three sites measurements were performed in campaigns in 3 consecutive years. Comparison of the emission levels in the first and second year showed a reduction of the methane emission of about 50% due to implementation of a gas extraction system. From the second to the third year emissions increased by a factor of 4 due to new land filling. Furthermore measurements were performed in winter when oxidation efficiency was reduced. This paper describes the measurement technique used, and discusses the results of the experimental sessions that were performed

  3. How do emission patterns in megacities affect regional air pollution?

    Science.gov (United States)

    Heil, A.; Richter, C.; Schroeder, S.; Schultz, M. G.

    2010-12-01

    Megacities around the world show distinctly different emission patterns in terms of absolute amounts and emission ratios of individual chemical compounds due to varying socio-economic developments and technological standards. The emission patterns influence the chemical reactivity of the urban pollution plume, and hence determine air quality in and around megacity areas. In this study, which is part of the European project CITYZEN (megaCITY - Zoom for the ENvironment), the effects of emission changes in four selected megacity areas on air pollution were investigated: BeNeLux (BNL), Istanbul (IST), Pearl River Delta (PRD) and Sao Paulo (SAP). The study aims at answering the question: how would air pollution in megacity X change if it had the same urban emissions per capita as megacity Y? Model simulations with the global chemistry climate model ECHAM5-MOZ were carried out for the year 2001 using a resolution of about 2 degrees in the horizontal and of 31 levels (surface to 10 hPa) in the vertical. The model was driven by meteorological input data from the ECMWF ERA Interim reanalysis. Emissions were taken from the gridded global ACCMIP emission inventory recently established for use in chemistry-climate simulations in connection to the IPCC-AR5 assessments (Lamarque et al. 2010). We carried out sensitivity simulations where emission patterns from each of the megacity areas were replaced by those from all others. This was done on the basis of the per capita emissions for each species and sector averaged over the respective region. Total per capita CO and NMVOC emissions are highest in PRD and lowest in SAP while total per capita NOx emissions are highest in BNL and lowest in SAP. There are strong differences in the relative contribution of the urban sectors to total emissions of individual compounds. As a result, each of the four megacity areas exhibits a very characteristic NMVOC speciation profile which determines the NMVOC-related photochemical ozone (O_3

  4. Objective Measure of Nasal Air Emission Using Nasal Accelerometry

    Science.gov (United States)

    Cler, Meredith J.; Lien, Yu-An, S.; Braden, Maia N.; Mittleman, Talia; Downing, Kerri; Stepp, Cara, E.

    2016-01-01

    Purpose: This article describes the development and initial validation of an objective measure of nasal air emission (NAE) using nasal accelerometry. Method: Nasal acceleration and nasal airflow signals were simultaneously recorded while an expert speech language pathologist modeled NAEs at a variety of severity levels. In addition, microphone and…

  5. Impacts of Residential Biofuel Emissions on Air Quality and Climate

    Science.gov (United States)

    Huang, Y.; Unger, N.; Harper, K.; Storelvmo, T.

    2016-12-01

    The residential biofuel sector is defined as fuelwood, agricultural residues and dung used for household cooking and heating. Aerosol emissions from this human activity play an important role affecting local, regional and global air quality, climate and public health. However, there are only few studies available that evaluate the net impacts and large uncertainties persist. Here we use the Community Atmosphere Model version 5.3 (CAM v5.3) within the Community Earth System Model version 1.2.2, to quantify the impacts of cook-stove biofuel emissions on air quality and climate. The model incorporates a novel advanced treatment of black carbon (BC) effects on mixed-phase/ice clouds. We update the global anthropogenic emission inventory in CAM v5.3 to a state-of-the-art emission inventory from the Greenhouse Gas-Air Pollution Interactions and Synergies integrated assessment model. Global in-situ and aircraft campaign observations for BC and organic carbon are used to evaluate and validate the model performance. Sensitivity simulations are employed to assess the impacts of residential biofuel emissions on regional and global direct and indirect radiative forcings in the contemporary world. We focus the analyses on several key regions including India, China and Sub-Saharan Africa.

  6. Consequential life cycle air emissions externalities for plug-in electric vehicles in the PJM interconnection

    Science.gov (United States)

    Weis, Allison; Jaramillo, Paulina; Michalek, Jeremy

    2016-02-01

    We perform a consequential life cycle analysis of plug-in electric vehicles (PEVs), hybrid electric vehicles (HEVs), and conventional gasoline vehicles in the PJM interconnection using a detailed, normative optimization model of the PJM electricity grid that captures the change in power plant operations and related emissions due to vehicle charging. We estimate and monetize the resulting human health and environmental damages from life cycle air emissions for each vehicle technology. We model PJM using the most recent data available (2010) as well as projections of the PJM grid in 2018 and a hypothetical scenario with increased wind penetration. We assess a range of sensitivity cases to verify the robustness of our results. We find that PEVs have higher life cycle air emissions damages than gasoline HEVs in the recent grid scenario, which has a high percentage of coal generation on the margin. In particular, battery electric vehicles with large battery capacity can produce two to three times as much air emissions damage as gasoline HEVs, depending on charge timing. In our future 2018 grid scenarios that account for predicted coal plant retirements, PEVs would produce air emissions damages comparable to or slightly lower than HEVs.

  7. Consequential life cycle air emissions externalities for plug-in electric vehicles in the PJM interconnection

    International Nuclear Information System (INIS)

    Weis, Allison; Jaramillo, Paulina; Michalek, Jeremy

    2016-01-01

    We perform a consequential life cycle analysis of plug-in electric vehicles (PEVs), hybrid electric vehicles (HEVs), and conventional gasoline vehicles in the PJM interconnection using a detailed, normative optimization model of the PJM electricity grid that captures the change in power plant operations and related emissions due to vehicle charging. We estimate and monetize the resulting human health and environmental damages from life cycle air emissions for each vehicle technology. We model PJM using the most recent data available (2010) as well as projections of the PJM grid in 2018 and a hypothetical scenario with increased wind penetration. We assess a range of sensitivity cases to verify the robustness of our results. We find that PEVs have higher life cycle air emissions damages than gasoline HEVs in the recent grid scenario, which has a high percentage of coal generation on the margin. In particular, battery electric vehicles with large battery capacity can produce two to three times as much air emissions damage as gasoline HEVs, depending on charge timing. In our future 2018 grid scenarios that account for predicted coal plant retirements, PEVs would produce air emissions damages comparable to or slightly lower than HEVs. (letter)

  8. Anthropogenic Vanadium emissions to air and ambient air concentrations in North-West Europe

    Directory of Open Access Journals (Sweden)

    Visschedijk A. H. J.

    2013-04-01

    Full Text Available An inventory of Vanadium emissions for North-West Europe for the year 2005 was made based on an identification of the major sources. The inventory covers Belgium, Germany, Denmark, France, United Kingdom, Luxembourg, Netherlands and the OSPAR region of the North Sea. Vanadium emission were calculated bottom-up using energy use activity data and collected fuel and sector-specific emissions factors, taking into account various emission control measures. The NW European emissions were dominated by combustion of heavy fuel oil and petroleum cokes. Total emissions for 2005 amounted to 1569 tons/yr. The major sources are sea going ships (39%, petroleum refineries (35% and industry (19%. Emission is strongly concentrated at the densely populated cities with major sea ports. The location of sources at or near the major port cities was confirmed by observational data, as was the downward trend in emissions due to emission control, fuel switches in industry and fuel quality improvement. The results show the positive impact of lower sulphur fuels on other possible health relevant air pollutants such as particle bound Vanadium. The emission inventory can be expanded to the full European domain and can be used to for air quality modeling and particularly for the tracing of source contributions from certain types of fossil fuels (petroleum coke and residual fuel oil. Moreover, it will allow the monitoring of changes in fuel use over time.

  9. Estimating emissions from grout pouring operations

    International Nuclear Information System (INIS)

    Ballinger, M.Y.; Hendrickson, D.W.

    1993-08-01

    Grouting is a method for disposal of low-level radioactive waste in which a contaminated solution is mixed into a slurry, poured into a large storage vault, then dried, fixing the contaminants within a stable solid matrix. A model (RELEASE) has been developed to estimate the quantity of aeorsol created during the pouring process. Information and equations derived from spill experiments were used in the model to determine release fractions. This paper discusses the derivation of the release fraction equation used in the code and the model used to account for gravity settling of particles in the vault. The input and results for a base case application are shown

  10. Estimation of light duty vehicle emissions in Islamabad and climate co-benefits of improved emission standards implementation

    Science.gov (United States)

    Shah, Izhar Hussain; Zeeshan, Muhammad

    2016-02-01

    Light Duty Vehicles (LDVs) hold a major share in Islamabad's vehicle fleet and their contribution towards air pollution has not been analyzed previously. Emissions for the base year (2014) and two optimistic 'what-if' scenarios were estimated by using the International Vehicle Emissions (IVE) model. Considering the recent implementation of Euro II as emission standard in Pakistan, scenario 1 assumed entire LDV fleet meeting at least Euro II standards while scenario 2 assumed all LDVs meeting Euro IV standards except motorcycles which would be meeting Euro III emission standards. Higher average age for all vehicles and lower share of Euro compliant vehicles was found in the base case. Low engine stress mode (lower speeds with frequent decelerations) was observed for all vehicles especially on arterials and residential roads. Highest overall emissions (59%) were observed on arterials, followed by residential roads (24%) and highways (17%) with higher emissions observed during morning (8-10 am) and evening (4-6 pm) rush hours. Composite emission factors were also calculated. Results reveal that 1094, 147, 11.1, 0.2 and 0.4 kt of CO2, CO, NOx, SO2 and PM10 respectively were emitted in 2014 by LDVs. Compared with the base year, scenario 1 showed a reduction of 9%, 69%, 73%, 13% and 31%, while scenario 2 exhibited a reduction of 5%, 92%, 90%, 92% and 81% for CO2, CO, NOx, SO2 and PM10 respectively. As compared to the base year, a 20 year CO2-equivalent Global Warming Potential (GWP) reduced by 55% and 64% under scenario 1 and 2 respectively, while a 100 year GWP reduced by 40% and 44% under scenario 1 and 2 respectively. Our results demonstrated significant co-benefits that could be achieved in emission reduction and air quality improvement in the city by vehicle technology implementation.

  11. Air pollution response to changing weather and power plant emissions in the eastern United States

    Science.gov (United States)

    Bloomer, Bryan Jaye

    Air pollution in the eastern United States causes human sickness and death as well as damage to crops and materials. NOX emission reduction is observed to improve air quality. Effectively reducing pollution in the future requires understanding the connections between smog, precursor emissions, weather, and climate change. Numerical models predict global warming will exacerbate smog over the next 50 years. My analysis of 21 years of CASTNET observations quantifies a climate change penalty. I calculate, for data collected prior to 2002, a climate penalty factor of ˜3.3 ppb O3/°C across the power plant dominated receptor regions in the rural, eastern U.S. Recent reductions in NOX emissions decreased the climate penalty factor to ˜2.2 ppb O3/°C. Prior to 1995, power plant emissions of CO2, SO2, and NOX were estimated with fuel sampling and analysis methods. Currently, emissions are measured with continuous monitoring equipment (CEMS) installed directly in stacks. My comparison of the two methods show CO 2 and SO2 emissions are ˜5% lower when inferred from fuel sampling; greater differences are found for NOX emissions. CEMS are the method of choice for emission inventories and commodity trading and should be the standard against which other methods are evaluated for global greenhouse gas trading policies. I used CEMS data and applied chemistry transport modeling to evaluate improvements in air quality observed by aircraft during the North American electrical blackout of 2003. An air quality model produced substantial reductions in O3, but not as much as observed. The study highlights weaknesses in the model as commonly used for evaluating a single day event and suggests areas for further investigation. A new analysis and visualization method quantifies local-daily to hemispheric-seasonal scale relationships between weather and air pollution, confirming improved air quality despite increasing temperatures across the eastern U.S. Climate penalty factors indicate

  12. Directional Canopy Emissivity Estimation Based on Spectral Invariants

    Science.gov (United States)

    Guo, M.; Cao, B.; Ren, H.; Yongming, D.; Peng, J.; Fan, W.

    2017-12-01

    Land surface emissivity is a crucial parameter for estimating land surface temperature from remote sensing data and also plays an important role in the physical process of surface energy and water balance from local to global scales. To our knowledge, the emissivity varies with surface type and cover. As for the vegetation, its canopy emissivity is dependent on vegetation types, viewing zenith angle and structure that changes in different growing stages. Lots of previous studies have focused on the emissivity model, but few of them are analytic and suited to different canopy structures. In this paper, a new physical analytic model is proposed to estimate the directional emissivity of homogenous vegetation canopy based on spectral invariants. The initial model counts the directional absorption in six parts: the direct absorption of the canopy and the soil, the absorption of the canopy and soil after a single scattering and after multiple scattering within the canopy-soil system. In order to analytically estimate the emissivity, the pathways of photons absorbed in the canopy-soil system are traced using the re-collision probability in Fig.1. After sensitive analysis on the above six absorptions, the initial complicated model was further simplified as a fixed mathematic expression to estimate the directional emissivity for vegetation canopy. The model was compared with the 4SAIL model, FRA97 model, FRA02 model and DART model in Fig.2, and the results showed that the FRA02 model is significantly underestimated while the FRA97 model is a little underestimated, on basis of the new model. On the contrary, the emissivity difference between the new model with the 4SAIL model and DART model was found to be less than 0.002. In general, since the new model has the advantages of mathematic expression with accurate results and clear physical meaning, the model is promising to be extended to simulate the directional emissivity for the discrete canopy in further study.

  13. Fractional kalman filter to estimate the concentration of air pollution

    Science.gov (United States)

    Vita Oktaviana, Yessy; Apriliani, Erna; Khusnul Arif, Didik

    2018-04-01

    Air pollution problem gives important effect in quality environment and quality of human’s life. Air pollution can be caused by nature sources or human activities. Pollutant for example Ozone, a harmful gas formed by NOx and volatile organic compounds (VOCs) emitted from various sources. The air pollution problem can be modeled by TAPM-CTM (The Air Pollution Model with Chemical Transport Model). The model shows concentration of pollutant in the air. Therefore, it is important to estimate concentration of air pollutant. Estimation method can be used for forecast pollutant concentration in future and keep stability of air quality. In this research, an algorithm is developed, based on Fractional Kalman Filter to solve the model of air pollution’s problem. The model will be discretized first and then it will be estimated by the method. The result shows that estimation of Fractional Kalman Filter has better accuracy than estimation of Kalman Filter. The accuracy was tested by applying RMSE (Root Mean Square Error).

  14. Air Pollutant Emissions Projections for the Cement and Steel Industry in China and the Impact of Emissions Control Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Hasanbeigi, Ali [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Khanna, Nina [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Price, Lynn [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2017-03-01

    China’s cement and steel industry accounts for approximately half of the world’s total cement and steel production. These two industries are two of the most energy-intensive and highest carbon dioxide (CO2)-emitting industries and two of the key industrial contributors to air pollution in China. For example, the cement industry is the largest source of particulate matter (PM) emissions in China, accounting for 40 percent of its industrial PM emissions and 27 percent of its total national PM emissions. The Chinese steel industry contributed to approximately 20 percent of sulfur dioxide (SO2) emissions and 27 percent of PM emissions for all key manufacturing industries in China in 2013. In this study, we analyzed and projected the total PM and SO2 emissions from the Chinese cement and steel industry from 2010–2050 under three different scenarios: a Base Case scenario, an Advanced scenario, and an Advanced EOP (end-of-pipe) scenario. We used bottom-up emissions control technologies data and assumptions to project the emissions. In addition, we conducted an economic analysis to estimate the cost for PM emissions reductions in the Chinese cement industry using EOP control technologies, energy efficiency measures, and product change measures. The results of the emissions projection showed that there is not a substantial difference in PM emissions between the Base Case and Advanced scenarios, for both the cement and steel industries. This is mainly because PM emissions in the cement industry caused mainly by production process and not the fuel use. Since our forecast for the cement production in the Base Case and Advanced scenarios are not too different from each other, this results in only a slight difference in PM emissions forecast for these two scenarios. Also, we assumed a similar share and penetration rate of control technologies from 2010 up to 2050 for these two scenarios for the cement and steel industry. However, the Advanced EOP

  15. Computer Model to Estimate Reliability Engineering for Air Conditioning Systems

    International Nuclear Information System (INIS)

    Afrah Al-Bossly, A.; El-Berry, A.; El-Berry, A.

    2012-01-01

    Reliability engineering is used to predict the performance and optimize design and maintenance of air conditioning systems. Air conditioning systems are expose to a number of failures. The failures of an air conditioner such as turn on, loss of air conditioner cooling capacity, reduced air conditioning output temperatures, loss of cool air supply and loss of air flow entirely can be due to a variety of problems with one or more components of an air conditioner or air conditioning system. Forecasting for system failure rates are very important for maintenance. This paper focused on the reliability of the air conditioning systems. Statistical distributions that were commonly applied in reliability settings: the standard (2 parameter) Weibull and Gamma distributions. After distributions parameters had been estimated, reliability estimations and predictions were used for evaluations. To evaluate good operating condition in a building, the reliability of the air conditioning system that supplies conditioned air to the several The company's departments. This air conditioning system is divided into two, namely the main chilled water system and the ten air handling systems that serves the ten departments. In a chilled-water system the air conditioner cools water down to 40-45 degree F (4-7 degree C). The chilled water is distributed throughout the building in a piping system and connected to air condition cooling units wherever needed. Data analysis has been done with support a computer aided reliability software, this is due to the Weibull and Gamma distributions indicated that the reliability for the systems equal to 86.012% and 77.7% respectively. A comparison between the two important families of distribution functions, namely, the Weibull and Gamma families was studied. It was found that Weibull method performed for decision making.

  16. 1990 INEL national emission standards for hazardous air pollutants

    International Nuclear Information System (INIS)

    1990-05-01

    The Environmental Protection Agency issued on December 15, 1989 final rules governing air emissions of radionuclides. Requirements concerning radionuclide emissions from Department of Energy Facilities are addressed under Title 40, Code Federal Regulations (CFR) 61, Subpart H, ''National Emission Standards for Emissions of Radionuclides other Than Radon From Department of Energy Facilities.'' Section 61.94 of the regulations require that each DOE facility submit on an annual basis a report documenting compliance with the Subpart H requirements. This report addresses the section 61.94 reporting requirements for operations at the Idaho National Engineering Laboratory (INEL) for calendar year 1990. The Idaho Operations Office of the Department of Energy is the primary contact concerning NESHAPs compliance at the INEL

  17. Data Quality Objectives Supporting Radiological Air Emissions Monitoring for the PNNL Site

    Energy Technology Data Exchange (ETDEWEB)

    Barnett, J. Matthew; Meier, Kirsten M.; Snyder, Sandra F.; Fritz, Brad G.; Poston, Ted M.; Rhoads, Kathleen

    2010-05-25

    This document of Data Quality Objectives (DQOs) was prepared based on the U.S. Environmental Protection Agency (EPA) Guidance on Systematic Planning Using the Data Quality Objectives Process, EPA, QA/G4, 2/2006 (EPA 2006) as well as several other published DQOs. Pacific Northwest National Laboratory (PNNL) is in the process of developing a radiological air monitoring program for the PNNL Site that is distinct from that of the nearby Hanford Site. Radiological emissions at the PNNL Site result from Physical Sciences Facility (PSF) major emissions units. A team was established to determine how the PNNL Site would meet federal regulations and address guidelines developed to monitor and estimate offsite air emissions of radioactive materials. The result is a program that monitors the impact to the public from the PNNL Site.

  18. Energy use, emissions and air pollution reduction strategies in Asia

    International Nuclear Information System (INIS)

    Foell, W.; Green, C.; Amann, M.; Bhattacharya, S.; Carmichael, G.; Chadwick, M.; Cinderby, S.; Haugland, T.; Hettelingh, J.-P.; Hordijk, L.; Kuylenstierna, J.; Shah, J.; Shrestha, R.; Streets, D.; Zhao, D.

    1995-01-01

    In contrast to Europe and North America, air pollution in Asia is increasing rapidly, resulting in both local air quality problems and higher acidic depositions. In 1989, an east-west group of scientists initiated a multi-institutional research project on Acid Rain and Emissions Reduction in Asia, funded for the past two years by the World Bank and the Asian Development Bank. Phase I, covering 23 countries of Asia, focused on the development of PC-based software called the Regional Air Pollution Information and Simulation Model (RAINS-ASIA). A 94-region Regional Energy Scenario Generator was developed to create alternative energy/emission scenarios through the year 2020. A long-range atmospheric transport model was developed to calculate dispersion and deposition of sulfur, based upon emissions from area and large point sources, on a one-degree grid of Asia. The resulting impacts of acidic deposition on a variety of vegetation types were analyzed using the critical loads approach to test different emissions management strategies, including both energy conservation measures and sulfur abatement technologies. 14 refs., 7 figs

  19. Estimation of Methane Emissions from Municipal Solid Waste Landfills in China Based on Point Emission Sources

    Directory of Open Access Journals (Sweden)

    Cai Bo-Feng

    2014-01-01

    Citation: Cai, B.-F., Liu, J.-G., Gao, Q.-X., et al., 2014. Estimation of methane emissions from municipal solid waste landfills in China based on point emission sources. Adv. Clim. Change Res. 5(2, doi: 10.3724/SP.J.1248.2014.081.

  20. Innovations in projecting emissions for air quality modeling ...

    Science.gov (United States)

    Air quality modeling is used in setting air quality standards and in evaluating their costs and benefits. Historically, modeling applications have projected emissions and the resulting air quality only 5 to 10 years into the future. Recognition that the choice of air quality management strategy has climate change implications is encouraging longer modeling time horizons. However, for multi-decadal time horizons, many questions about future conditions arise. For example, will current population, economic, and land use trends continue, or will we see shifts that may alter the spatial and temporal pattern of emissions? Similarly, will technologies such as building-integrated solar photovoltaics, battery storage, electric vehicles, and CO2 capture emerge as disruptive technologies - shifting how we produce and use energy - or will these technologies achieve only niche markets and have little impact? These are some of the questions that are being evaluated by researchers within the U.S. EPA’s Office of Research and Development. In this presentation, Dr. Loughlin will describe a range of analytical approaches that are being explored. These include: (i) the development of alternative scenarios of the future that can be used to evaluate candidate management strategies over wide-ranging conditions, (ii) the application of energy system models to project emissions decades into the future and to assess the environmental implications of new technologies, (iii) and methodo

  1. Emissions of halocarbons from mobile vehicle air conditioning system in Hong Kong

    International Nuclear Information System (INIS)

    Yan, H.H.; Guo, H.; Ou, J.M.

    2014-01-01

    Highlights: • Halocarbon emissions from MVACS were characterized using bottom up approach. • Quantification of emission inventory was revealed using AUV Tools. • Potential emission reduction was estimated under 3 possible mitigation scenarios. • The results are useful for the policy makers to formulate and implement future phase-out schedule. - Abstract: During the implementation of Montreal Protocol, emission inventories of halocarbons in different sectors at regional scale are fundamental to the formulation of relevant management strategy and inspection of the implementation efficiency. This study investigated the emission profile of halocarbons used in the mobile vehicle air conditioning system, the leading sector of refrigeration industry in terms of the refrigerant bank, market and emission, in the Hong Kong Special Administrative Region, using a bottom-up approach developed by 2006 IPCC Good Practice Guidance. The results showed that emissions of CFC-12 peaked at 53 tons ODP (Ozone Depletion Potential) in 1992 and then gradually diminished, whereas HFC-134a presented an increasing emission trend since 1990s and the emissions of HFC-134a reached 65,000 tons CO 2 -equivelant (CO 2 -eq) by the end of 2011. Uncertainty analysis revealed relatively high levels of uncertainties for special-purpose vehicles and government vehicles. Moreover, greenhouse gas (GHG) abatements under different scenarios indicated that potential emission reduction of HFC-134a ranged from 4.1 to 8.4 × 10 5 tons CO 2 -eq. The findings in this study advance our knowledge of halocarbon emissions from mobile vehicle air conditioning system in Hong Kong

  2. Emissions of halocarbons from mobile vehicle air conditioning system in Hong Kong

    Energy Technology Data Exchange (ETDEWEB)

    Yan, H.H.; Guo, H., E-mail: ceguohai@polyu.edu.hk; Ou, J.M.

    2014-08-15

    Highlights: • Halocarbon emissions from MVACS were characterized using bottom up approach. • Quantification of emission inventory was revealed using AUV Tools. • Potential emission reduction was estimated under 3 possible mitigation scenarios. • The results are useful for the policy makers to formulate and implement future phase-out schedule. - Abstract: During the implementation of Montreal Protocol, emission inventories of halocarbons in different sectors at regional scale are fundamental to the formulation of relevant management strategy and inspection of the implementation efficiency. This study investigated the emission profile of halocarbons used in the mobile vehicle air conditioning system, the leading sector of refrigeration industry in terms of the refrigerant bank, market and emission, in the Hong Kong Special Administrative Region, using a bottom-up approach developed by 2006 IPCC Good Practice Guidance. The results showed that emissions of CFC-12 peaked at 53 tons ODP (Ozone Depletion Potential) in 1992 and then gradually diminished, whereas HFC-134a presented an increasing emission trend since 1990s and the emissions of HFC-134a reached 65,000 tons CO{sub 2}-equivelant (CO{sub 2}-eq) by the end of 2011. Uncertainty analysis revealed relatively high levels of uncertainties for special-purpose vehicles and government vehicles. Moreover, greenhouse gas (GHG) abatements under different scenarios indicated that potential emission reduction of HFC-134a ranged from 4.1 to 8.4 × 10{sup 5} tons CO{sub 2}-eq. The findings in this study advance our knowledge of halocarbon emissions from mobile vehicle air conditioning system in Hong Kong.

  3. Development of emissions inventories for the Auto/Oil Air Quality Improvement Research Program

    International Nuclear Information System (INIS)

    Pollack, A.K.; Fieber, J.L.; Lauer, G.; Dunker, A.M.; Noda, A.M.; Schleyer, C.H.; Chock, D.P.; Hertz, M.; Metcalfe, J.E.

    1992-01-01

    The air quality effects of different reformulated gasolines, various other alternative fuels, and developments in automotive technologies are being studied as part of a joint research project conducted by a consortium of three domestic auto companies and fourteen petroleum companies. As part of the air quality modeling effort, emission inventories are being developed in a near-term year (1995), and 21 fuels in a long-term year (2005 or 2010). A distinctive feature of this effort is that these inventories are the first used in an air quality study that treat light duty vehicle emissions by operating mode as well as by class, and base the speciation characteristics of each operating mode on actual vehicle test results. This incorporates an unusual amount of detail on the relative importance of each of the three vehicle exhaust, two evaporative, and running loss operating modes, both in terms of overall mass emission amounts and in terms of the hydrocarbon speciation and ozone reactivity. This study also allows a better estimate of the relative importance of each vehicle class and technology type to an overall emission inventory, and of the differences in the effects of alternative fuels between vehicle technologies and classes. In addition, the role of mobile source emissions relative to other sources of emissions for both short-term and long-term emission projections, and across a wide geographic range is being assessed. This paper first describes the techniques used in developing these emission inventories, and then examines regional, temporal, and fuel/vehicle effects on emissions

  4. Hazardous air emissions potential from a wood-fired furnace

    International Nuclear Information System (INIS)

    Hubbard, A.J.

    1995-01-01

    During the first week of April, 1991 the Wisconsin Department of Natural Resources (WDNR) conducted a series of air emissions tests of a small industrial wood-fired boiler in northern Wisconsin. The boiler was firing a virgin hogged wood/wood waste fuel with a moisture content of about 35 percent. The pollutants measured were particulates, nitrogen oxides (NOx), carbon monoxide (GO), total hydrocarbons (THC), benzene, formaldehyde (CHOH), polycyclic organic matter (POM, e.g. Benzo (a) pyrene), aldehydes, and trace metals (As, Ba, Cu, Pb, Mn, Ni, K, Se, Na, and Zn). For two and a half days continuous emissions data were recorded by laboratory-certified continuous emissions monitors for CO, NOx, 0-2, THC, and COq2 while the EPA reference method stack tests were being conducted for the other pollutants. In addition, a WDNR test team measured CO, 0-2, and flue gas temperature with a Rosemount portable combustion analyzer for several hours over the course of those two and a half days. The principal purpose behind the study was to evaluate the hazardous air emissions potential of a small industrial furnace firing a virgin wood fuel. To that end, it was hoped that a surrogate pollutant could be identified which would represent the levels of hazardous air emissions (e.g., benzene) present in the wood-fired furnace flue gases. If a readily monitorable pollutant could be identified, then a regulatory strategy of measuring one representative pollutant could be put in place to continually assess the hazardous emissions potential of virgin wood combustion. (UK)

  5. Uncertainty in estimating and mitigating industrial related GHG emissions

    International Nuclear Information System (INIS)

    El-Fadel, M.; Zeinati, M.; Ghaddar, N.; Mezher, T.

    2001-01-01

    Global climate change has been one of the challenging environmental concerns facing policy makers in the past decade. The characterization of the wide range of greenhouse gas emissions sources and sinks as well as their behavior in the atmosphere remains an on-going activity in many countries. Lebanon, being a signatory to the Framework Convention on Climate Change, is required to submit and regularly update a national inventory of greenhouse gas emissions sources and removals. Accordingly, an inventory of greenhouse gases from various sectors was conducted following the guidelines set by the United Nations Intergovernmental Panel on Climate Change (IPCC). The inventory indicated that the industrial sector contributes about 29% to the total greenhouse gas emissions divided between industrial processes and energy requirements at 12 and 17%, respectively. This paper describes major mitigation scenarios to reduce emissions from this sector based on associated technical, economic, environmental, and social characteristics. Economic ranking of these scenarios was conducted and uncertainty in emission factors used in the estimation process was emphasized. For this purpose, theoretical and experimental emission factors were used as alternatives to default factors recommended by the IPCC and the significance of resulting deviations in emission estimation is presented. (author)

  6. Modelling of radio emission from cosmic ray air showers

    Science.gov (United States)

    Ludwig, Marianne

    2011-06-01

    Cosmic rays entering the Earth's atmosphere induce extensive air showers consisting of up to billions of secondary particles. Among them, a multitude of electrons and positrons are generated. These get deflected in the Earth's magnetic field, creating time-varying transverse currents. Thereby, the air shower emits coherent radiation in the MHz frequency range measured by radio antenna arrays on the ground such as LOPES at the KIT. This detection method provides a possibility to study cosmic rays with energies above 1017 eV. At this time, the radio technique undergoes the change from prototype experiments to large scale application. Thus, a detailed understanding of the radio emission process is needed more than ever. Before starting this work, different models made conflicting predictions on the pulse shape and the amplitude of the radio signal. It turned out that a radiation component caused by the variation of the number of charged particles within the air shower was missed in several models. The Monte Carlo code REAS2 superposing the radiation of the individual air shower electrons and positrons was one of those. At this time, it was not known how to take the missing component into account. For REAS3, we developed and implemented the endpoint formalism, a universal approach, to calculate the radiation from each single particle. For the first time, we achieve a good agreement between REAS3 and MGMR, an independent and completely different simulation approach. In contrast to REAS3, MGMR is based on a macroscopic approach and on parametrisations of the air shower. We studied the differences in the underlying air shower models to explain the remaining deviations. For comparisons with LOPES data, we developed a new method which allows "top-down" simulations of air showers. From this, we developed an air shower selection criterion based on the number of muons measured with KASCADE to take shower-to-shower fluctuations for a single event analysis into account. With

  7. 76 FR 4155 - National Emission Standards for Hazardous Air Pollutants for Source Categories: Gasoline...

    Science.gov (United States)

    2011-01-24

    ... 63 National Emission Standards for Hazardous Air Pollutants for Source Categories: Gasoline Distribution Bulk Terminals, Bulk Plants, and Pipeline Facilities; and Gasoline Dispensing Facilities; Final...] RIN 2060-AP16 National Emission Standards for Hazardous Air Pollutants for Source Categories: Gasoline...

  8. 77 FR 33811 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

    Science.gov (United States)

    2012-06-07

    ... 63 National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines; New Source Performance Standards for Stationary Internal Combustion Engines; Proposed Rule #0;#0... Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines; New Source...

  9. Urban emissions hotspots: Quantifying vehicle congestion and air pollution using mobile phone GPS data

    International Nuclear Information System (INIS)

    Gately, Conor K.; Hutyra, Lucy R.; Peterson, Scott; Sue Wing, Ian

    2017-01-01

    On-road emissions vary widely on time scales as short as minutes and length scales as short as tens of meters. Detailed data on emissions at these scales are a prerequisite to accurately quantifying ambient pollution concentrations and identifying hotspots of human exposure within urban areas. We construct a highly resolved inventory of hourly fluxes of CO, NO 2 , NO x , PM 2.5 and CO 2 from road vehicles on 280,000 road segments in eastern Massachusetts for the year 2012. Our inventory integrates a large database of hourly vehicle speeds derived from mobile phone and vehicle GPS data with multiple regional datasets of vehicle flows, fleet characteristics, and local meteorology. We quantify the ‘excess’ emissions from traffic congestion, finding modest congestion enhancement (3–6%) at regional scales, but hundreds of local hotspots with highly elevated annual emissions (up to 75% for individual roadways in key corridors). Congestion-driven reductions in vehicle fuel economy necessitated ‘excess’ consumption of 113 million gallons of motor fuel, worth ∼ $415M, but this accounted for only 3.5% of the total fuel consumed in Massachusetts, as over 80% of vehicle travel occurs in uncongested conditions. Across our study domain, emissions are highly spatially concentrated, with 70% of pollution originating from only 10% of the roads. The 2011 EPA National Emissions Inventory (NEI) understates our aggregate emissions of NO x , PM 2.5 , and CO 2 by 46%, 38%, and 18%, respectively. However, CO emissions agree within 5% for the two inventories, suggesting that the large biases in NO x and PM 2.5 emissions arise from differences in estimates of diesel vehicle activity. By providing fine-scale information on local emission hotspots and regional emissions patterns, our inventory framework supports targeted traffic interventions, transparent benchmarking, and improvements in overall urban air quality. - Highlights: • A high resolution, bottom-up inventory of

  10. Air Emission Reduction Benefits of Biogas Electricity Generation at Municipal Wastewater Treatment Plants.

    Science.gov (United States)

    Gingerich, Daniel B; Mauter, Meagan S

    2018-02-06

    Conventional processes for municipal wastewater treatment facilities are energy and materially intensive. This work quantifies the air emission implications of energy consumption, chemical use, and direct pollutant release at municipal wastewater treatment facilities across the U.S. and assesses the potential to avoid these damages by generating electricity and heat from the combustion of biogas produced during anaerobic sludge digestion. We find that embedded and on-site air emissions from municipal wastewater treatment imposed human health, environmental, and climate (HEC) damages on the order of $1.63 billion USD in 2012, with 85% of these damages attributed to the estimated consumption of 19 500 GWh of electricity by treatment processes annually, or 0.53% of the US electricity demand. An additional 11.8 million tons of biogenic CO 2 are directly emitted by wastewater treatment and sludge digestion processes currently installed at plants. Retrofitting existing wastewater treatment facilities with anaerobic sludge digestion for biogas production and biogas-fueled heat and electricity generation has the potential to reduce HEC damages by up to 24.9% relative to baseline emissions. Retrofitting only large plants (>5 MGD), where biogas generation is more likely to be economically viable, would generate HEC benefits of $254 annually. These findings reinforce the importance of accounting for use-phase embedded air emissions and spatially resolved marginal damage estimates when designing sustainable infrastructure systems.

  11. Cosmic ray radio emission as air shower detection

    International Nuclear Information System (INIS)

    Curutiu, Alexandru; Rusu, Mircea; Isar, Gina; Zgura, Sorin

    2004-01-01

    The possibility of radio-detection of ultra-high energy cosmic rays (within the 10 to 100 MHz range) are discussed. Currently, air showers are detected by various methods, mainly based on particle detectors (KASCADE, Auger) or optical detection (Cerenkov radiation). Recently,to detect radio emission from cosmic ray air showers a method using electromagnetic radiation in low frequency domain (LOFAR) was proposed. We are investigating this possibility, using simulation codes created to investigate electromagnetic radiation of intricate antennae structure, for example fractal antennas. Some of the preliminary results will be communicated in this session. (authors)

  12. Characterization of process air emissions in automotive production plants.

    Science.gov (United States)

    D'Arcy, J B; Dasch, J M; Gundrum, A B; Rivera, J L; Johnson, J H; Carlson, D H; Sutherland, J W

    2016-01-01

    During manufacturing, particles produced from industrial processes become airborne. These airborne emissions represent a challenge from an industrial hygiene and environmental standpoint. A study was undertaken to characterize the particles associated with a variety of manufacturing processes found in the auto industry. Air particulates were collected in five automotive plants covering ten manufacturing processes in the areas of casting, machining, heat treatment and assembly. Collection procedures provided information on air concentration, size distribution, and chemical composition of the airborne particulate matter for each process and insight into the physical and chemical processes that created those particles.

  13. Estimation of air quality improvement at road and street intersections

    Energy Technology Data Exchange (ETDEWEB)

    Hoeglund, P.G. [Royal Inst. of Technology, Stockholm (Sweden). Traffic and Transport Planning

    1995-12-31

    There has always been a very great problem to quantify the detrimental exhaust air pollution related to the traffic flow, especially at road and street intersections. Until now model calculations have been developed mainly for the links between the intersections. In an attempt to remedy this situation the author has developed a method of estimating emissions on the micro level from motor vehicles at intersections as a help for infrastructural design related to improved environmental conditions. Very parsimonious knowledge exists regarding the deceleration and acceleration patterns at road- and street intersections. Not many surveys are done neither in Sweden nor within other countries. Evidently, the need for knowledge regarding deceleration and acceleration behaviour on the micro level has until now not been given priority. In traffic safety related research studies have been done describing the drivers` deceleration and acceleration behaviour and the vehicles` braking performance. Those results give deceleration data for extreme situations and are not useful for describing normal decelerations and accelerations at road- and street intersections. Environment related problems within the traffic flow analysis are now accentuating the need for the studying of special deceleration and acceleration behaviours in combination with an alternative design of the road and street infrastructure. There is a big difference in different vehicles` amount of emitted exhaust pollutions during the passing of intersections depending on the vehicles` speed levels related to their deceleration and acceleration levels. (author)

  14. Estimation of air quality improvement at road and street intersections

    Energy Technology Data Exchange (ETDEWEB)

    Hoeglund, P G [Royal Inst. of Technology, Stockholm (Sweden). Traffic and Transport Planning

    1996-12-31

    There has always been a very great problem to quantify the detrimental exhaust air pollution related to the traffic flow, especially at road and street intersections. Until now model calculations have been developed mainly for the links between the intersections. In an attempt to remedy this situation the author has developed a method of estimating emissions on the micro level from motor vehicles at intersections as a help for infrastructural design related to improved environmental conditions. Very parsimonious knowledge exists regarding the deceleration and acceleration patterns at road- and street intersections. Not many surveys are done neither in Sweden nor within other countries. Evidently, the need for knowledge regarding deceleration and acceleration behaviour on the micro level has until now not been given priority. In traffic safety related research studies have been done describing the drivers` deceleration and acceleration behaviour and the vehicles` braking performance. Those results give deceleration data for extreme situations and are not useful for describing normal decelerations and accelerations at road- and street intersections. Environment related problems within the traffic flow analysis are now accentuating the need for the studying of special deceleration and acceleration behaviours in combination with an alternative design of the road and street infrastructure. There is a big difference in different vehicles` amount of emitted exhaust pollutions during the passing of intersections depending on the vehicles` speed levels related to their deceleration and acceleration levels. (author)

  15. Feasibility of including fugitive PM-10 emissions estimates in the EPA emissions trends report

    International Nuclear Information System (INIS)

    Barnard, W.; Carlson, P.

    1990-09-01

    The report describes the results of Part 2 of a two part study. Part 2 was to evaluate the feasibility of developing regional emission trends for PM-10. Part 1 was to evaluate the feasibility of developing VOC emission trends, on a regional and temporal basis. These studies are part of the effort underway to improve the national emission trends. Part 1 is presented in a separate report. The categories evaluated for the feasibility of developing regional emissions estimates were: unpaved roads, paved roads, wind erosion, agricultural tilling, construction activities, feedlots, burning, landfills, mining and quarrying unpaved parking lots, unpaved airstrips and storage piles

  16. Sparse estimation of model-based diffuse thermal dust emission

    Science.gov (United States)

    Irfan, Melis O.; Bobin, Jérôme

    2018-03-01

    Component separation for the Planck High Frequency Instrument (HFI) data is primarily concerned with the estimation of thermal dust emission, which requires the separation of thermal dust from the cosmic infrared background (CIB). For that purpose, current estimation methods rely on filtering techniques to decouple thermal dust emission from CIB anisotropies, which tend to yield a smooth, low-resolution, estimation of the dust emission. In this paper, we present a new parameter estimation method, premise: Parameter Recovery Exploiting Model Informed Sparse Estimates. This method exploits the sparse nature of thermal dust emission to calculate all-sky maps of thermal dust temperature, spectral index, and optical depth at 353 GHz. premise is evaluated and validated on full-sky simulated data. We find the percentage difference between the premise results and the true values to be 2.8, 5.7, and 7.2 per cent at the 1σ level across the full sky for thermal dust temperature, spectral index, and optical depth at 353 GHz, respectively. A comparison between premise and a GNILC-like method over selected regions of our sky simulation reveals that both methods perform comparably within high signal-to-noise regions. However, outside of the Galactic plane, premise is seen to outperform the GNILC-like method with increasing success as the signal-to-noise ratio worsens.

  17. Vehicle emissions and effects on air quality: indoors and outdoors

    International Nuclear Information System (INIS)

    Perry, R.; Gee, I.L.

    1994-01-01

    Vehicle emissions of non-regulated volatile organic compounds (VOCs), such as benzene, can form a major contribution to pollution of the indoor as well as the outdoor environment. Several of these compounds are considered to be a health risk and are important factors in the production of photochemical smog. The introduction of unleaded and particularly 'super unleaded' fuels has significantly increased levels of aromatic compounds in petrol world-wide and has led to changes in fuel composition with respect to olefins and the use of oxygenates. Increased aromatics, olefins and other compounds in fuels used in vehicles not fitted with catalytic converters have shown to increase emissions of benzene, 1,4-budatiene and other VOCs as well as contributing to increases in photochemical smog precursors. Increases in VOC levels in ambient air clearly produce increased indoor air pollution, particularly in naturally ventilated buildings. (author) 6 figs., 5 tabs., 30 refs

  18. Electric discharges in air - Near infrared emission spectrum.

    Science.gov (United States)

    Benesch, W. M.; Saum, K. A.

    1972-01-01

    The emission from glow discharges in flowing air has been investigated in the 1- to 5-micron wavelength region with a vacuum spectrometer. Most of the spectral features observed in the pressure range of .5 to 10 torr are identified, including atomic lines of OI, NI, and HI and molecular bands of N2, NO, N2O, CO2, and CO. The spectra are presented as a function of pressure and a table compiled of the atomic lines. Of particular interest are the contrasts between the emission of the air discharge and that of the pure gases, nitrogen and oxygen. In addition, the results of studies of several discharge modes, employing steady voltages and pulsed, provide data on details of the energy flow within the plasma.

  19. Estimating national exhaust emissions from railway vehicles in Turkey

    International Nuclear Information System (INIS)

    Dincer, Faruk; Elbir, Tolga

    2007-01-01

    The estimated exhaust emissions from railway vehicles in Turkey were presented. The emissions of nitrogen oxides (NO x ), hydrocarbon compounds (HC), carbon monoxide (CO), particulate matter (PM), sulfur dioxide (SO 2 ) and carbon dioxide (CO 2 ) from the diesel locomotives and railcars were calculated using the railway traffic data recorded by Turkish State Railways (TSR) for the period of 2000-2005. EPA emission factors were used for different vehicle types and operation modes such as shunting and line-hauling. Total emissions from railway vehicles in Turkey were estimated as 384 t y - 1 for HC, 1016 t y - 1 for CO, 6799 t y - 1 for NO X , 256 t y - 1 for PM, 357 t y - 1 for SO 2 and 383 537 t y - 1 for CO 2 for the year 2005. The distribution of emissions with respect to type of railway vehicles shows that the mainline locomotives contribute ∝ 91% to the total emissions. The increases of 22%, 39% and 49% in the current numbers of mainline locomotives, shunting locomotives and diesel railcars, respectively corresponding to the full capacity of railway network in Turkey will increase the annual emissions to 431 t y - 1 for HC, 1121 t y - 1 for CO, 7399 t y - 1 for NO X , 342 t y - 1 for PM, 552 t y - 1 for SO 2 and 420 256 t y - 1 for CO 2 . Total railway emissions constitute 0.15%, 0.08% and 4.21% of total Turkish traffic emissions for HC, CO and NO X , respectively. (author)

  20. Emissions of air toxics from a simulated charcoal kiln. Final report, October 1997--September 1998

    International Nuclear Information System (INIS)

    Lemieux, P.M.

    1999-06-01

    The report gives results of experiments in a laboratory-scale charcoal kiln simulator to evaluate emissions of hazardous air pollutants from the production of charcoal in Missouri-type kilns. Fixed combustion gases were measured using continuous monitors. In addition, other pollutants, including methanol, volatile organic compounds, semivolatile organic compounds, and particle emission rates and size distributions were measured using various techniques. Emissions of all pollutants are reported in units of grams emitted per unit mass of initial wood converted to charcoal. Two burn conditions--slow and fast--were examined. High levels of methanol, benzene, and fine particulate were emitted in all tests. The estimated emissions from the fast burn conditions were significantly higher than those from the slow burn conditions

  1. 40 CFR 270.315 - What air emissions control information must I keep at my facility?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 26 2010-07-01 2010-07-01 false What air emissions control information... Facility § 270.315 What air emissions control information must I keep at my facility? If you have air emission control equipment subject to 40 CFR part 264, subpart CC, you must keep the following information...

  2. 76 FR 42052 - National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries

    Science.gov (United States)

    2011-07-18

    ...-AO55 National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries AGENCY... the National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries. EPA is now... signed a final rule amending the National Emission Standards for Hazardous Air Pollutants From Petroleum...

  3. Estimate of biogenic VOC emissions in Japan and their effects on photochemical formation of ambient ozone and secondary organic aerosol

    Science.gov (United States)

    Chatani, Satoru; Matsunaga, Sou N.; Nakatsuka, Seiji

    2015-11-01

    A new gridded database has been developed to estimate the amount of isoprene, monoterpene, and sesquiterpene emitted from all the broadleaf and coniferous trees in Japan with the Model of Emissions of Gases and Aerosols from Nature (MEGAN). This database reflects the vegetation specific to Japan more accurately than existing ones. It estimates much lower isoprene emitted from other vegetation than trees, and higher sesquiterpene emissions mainly emitted from Cryptomeria japonica, which is the most abundant plant type in Japan. Changes in biogenic emissions result in the decrease in ambient ozone and increase in organic aerosol simulated by the air quality simulation over the Tokyo Metropolitan Area in Japan. Although newly estimated biogenic emissions contribute to a better model performance on overestimated ozone and underestimated organic aerosol, they are not a single solution to solve problems associated with the air quality simulation.

  4. Air Toxics Emissions from Open Burning of Crop Residues in Southeast Asia

    Science.gov (United States)

    KIM Oanh, N. T.; Permadi, D. A.; Hopke, P. K.; Smith, K. R.; Nguyet, D. A.

    2016-12-01

    Agricultural crops production in Southeast Asia (SEA) increases annually to meet domestic consumption of growing population and also for export. Crop residue open burning (CROB) is commonly practiced by farmers to quickly dispose of huge amounts of the agricultural waste, such as rice straw, generated after each crop cycle. This CROB activity emits various toxic air pollutants as well as short-lived climate pollutants such as black carbon particles. Our study focused on quantifying the 2015 annual emissions of semi-volatile organic compounds including polycyclic aromatic hydrocarbons (PAHs), dioxins/furans (PCDD/PCDF), organochlorine pesticides (OCP), along with other conventional trace gases, particulate matter, and greenhouse gases from CROB in 10 major agricultural crop producing SEA countries. Crop production statistics and current field OB practices were gathered from our primary surveys and relevant secondary data sources. Emission factors for rice straw and maize residue burning were taken mainly from our measurements in Thailand while for other crops relevant published data were used. The best emission estimates of air toxics from CROB in SEA were 112 g-TEQ/yr of PCDD/PCDF, 33 t/yr of OCP, and 25 Gg/yr of total PAH of which the well-known carcinogenic benzo[a]pyrene was 0.3 Gg/yr. The CROB of rice production had the highest shares of emissions (33-95%) among considered 8 crop types. Indonesia was the top contributor to the total SEA emissions (30-45%) followed by Vietnam (16-26%), Thailand (6-22%) and Myanmar (5-18%). The spatial distributions of emissions, 0.1º x 0.1º, for each specie were prepared using MODIS land cover data. Temporally, higher emissions were observed in the harvesting months of the main rice crops. This emissions database can be used in regional air quality modeling studies to assess the impacts of CROB activity and to promote non-open burning alternatives.

  5. The Fire INventory from NCAR (FINN: a high resolution global model to estimate the emissions from open burning

    Directory of Open Access Journals (Sweden)

    C. Wiedinmyer

    2011-07-01

    Full Text Available The Fire INventory from NCAR version 1.0 (FINNv1 provides daily, 1 km resolution, global estimates of the trace gas and particle emissions from open burning of biomass, which includes wildfire, agricultural fires, and prescribed burning and does not include biofuel use and trash burning. Emission factors used in the calculations have been updated with recent data, particularly for the non-methane organic compounds (NMOC. The resulting global annual NMOC emission estimates are as much as a factor of 5 greater than some prior estimates. Chemical speciation profiles, necessary to allocate the total NMOC emission estimates to lumped species for use by chemical transport models, are provided for three widely used chemical mechanisms: SAPRC99, GEOS-CHEM, and MOZART-4. Using these profiles, FINNv1 also provides global estimates of key organic compounds, including formaldehyde and methanol. Uncertainties in the emissions estimates arise from several of the method steps. The use of fire hot spots, assumed area burned, land cover maps, biomass consumption estimates, and emission factors all introduce error into the model estimates. The uncertainty in the FINNv1 emission estimates are about a factor of two; but, the global estimates agree reasonably well with other global inventories of biomass burning emissions for CO, CO2, and other species with less variable emission factors. FINNv1 emission estimates have been developed specifically for modeling atmospheric chemistry and air quality in a consistent framework at scales from local to global. The product is unique because of the high temporal and spatial resolution, global coverage, and the number of species estimated. FINNv1 can be used for both hindcast and forecast or near-real time model applications and the results are being critically evaluated with models and observations whenever possible.

  6. Methyl halide emission estimates from domestic biomass burning in Africa

    Science.gov (United States)

    Mead, M. I.; Khan, M. A. H.; White, I. R.; Nickless, G.; Shallcross, D. E.

    Inventories of methyl halide emissions from domestic burning of biomass in Africa, from 1950 to the present day and projected to 2030, have been constructed. By combining emission factors from Andreae and Merlet [2001. Emission of trace gases and aerosols from biomass burning. Global Biogeochemical Cycles 15, 955-966], the biomass burning estimates from Yevich and Logan [2003. An assessment of biofuel use and burning of agricultural waste in the developing world. Global Biogeochemical Cycles 17(4), 1095, doi:10.1029/2002GB001952] and the population data from the UN population division, the emission of methyl halides from domestic biomass usage in Africa has been estimated. Data from this study suggest that methyl halide emissions from domestic biomass burning have increased by a factor of 4-5 from 1950 to 2005 and based on the expected population growth could double over the next 25 years. This estimated change has a non-negligible impact on the atmospheric budgets of methyl halides.

  7. REDD+ emissions estimation and reporting: dealing with uncertainty

    International Nuclear Information System (INIS)

    Pelletier, Johanne; Potvin, Catherine; Martin, Davy

    2013-01-01

    The United Nations Framework Convention on Climate Change (UNFCCC) defined the technical and financial modalities of policy approaches and incentives to reduce emissions from deforestation and forest degradation in developing countries (REDD+). Substantial technical challenges hinder precise and accurate estimation of forest-related emissions and removals, as well as the setting and assessment of reference levels. These challenges could limit country participation in REDD+, especially if REDD+ emission reductions were to meet quality standards required to serve as compliance grade offsets for developed countries’ emissions. Using Panama as a case study, we tested the matrix approach proposed by Bucki et al (2012 Environ. Res. Lett. 7 024005) to perform sensitivity and uncertainty analysis distinguishing between ‘modelling sources’ of uncertainty, which refers to model-specific parameters and assumptions, and ‘recurring sources’ of uncertainty, which refers to random and systematic errors in emission factors and activity data. The sensitivity analysis estimated differences in the resulting fluxes ranging from 4.2% to 262.2% of the reference emission level. The classification of fallows and the carbon stock increment or carbon accumulation of intact forest lands were the two key parameters showing the largest sensitivity. The highest error propagated using Monte Carlo simulations was caused by modelling sources of uncertainty, which calls for special attention to ensure consistency in REDD+ reporting which is essential for securing environmental integrity. Due to the role of these modelling sources of uncertainty, the adoption of strict rules for estimation and reporting would favour comparability of emission reductions between countries. We believe that a reduction of the bias in emission factors will arise, among other things, from a globally concerted effort to improve allometric equations for tropical forests. Public access to datasets and methodology

  8. REDD+ emissions estimation and reporting: dealing with uncertainty

    Science.gov (United States)

    Pelletier, Johanne; Martin, Davy; Potvin, Catherine

    2013-09-01

    The United Nations Framework Convention on Climate Change (UNFCCC) defined the technical and financial modalities of policy approaches and incentives to reduce emissions from deforestation and forest degradation in developing countries (REDD+). Substantial technical challenges hinder precise and accurate estimation of forest-related emissions and removals, as well as the setting and assessment of reference levels. These challenges could limit country participation in REDD+, especially if REDD+ emission reductions were to meet quality standards required to serve as compliance grade offsets for developed countries’ emissions. Using Panama as a case study, we tested the matrix approach proposed by Bucki et al (2012 Environ. Res. Lett. 7 024005) to perform sensitivity and uncertainty analysis distinguishing between ‘modelling sources’ of uncertainty, which refers to model-specific parameters and assumptions, and ‘recurring sources’ of uncertainty, which refers to random and systematic errors in emission factors and activity data. The sensitivity analysis estimated differences in the resulting fluxes ranging from 4.2% to 262.2% of the reference emission level. The classification of fallows and the carbon stock increment or carbon accumulation of intact forest lands were the two key parameters showing the largest sensitivity. The highest error propagated using Monte Carlo simulations was caused by modelling sources of uncertainty, which calls for special attention to ensure consistency in REDD+ reporting which is essential for securing environmental integrity. Due to the role of these modelling sources of uncertainty, the adoption of strict rules for estimation and reporting would favour comparability of emission reductions between countries. We believe that a reduction of the bias in emission factors will arise, among other things, from a globally concerted effort to improve allometric equations for tropical forests. Public access to datasets and methodology

  9. Estimated emission reductions from California's enhanced Smog Check program.

    Science.gov (United States)

    Singer, Brett C; Wenzel, Thomas P

    2003-06-01

    The U.S. Environmental Protection Agency requires that states evaluate the effectiveness of their vehicle emissions inspection and maintenance (I/M) programs. This study demonstrates an evaluation approach that estimates mass emission reductions over time and includes the effect of I/M on vehicle deterioration. It includes a quantitative assessment of benefits from pre-inspection maintenance and repairs and accounts for the selection bias effect that occurs when intermittent high emitters are tested. We report estimates of one-cycle emission benefits of California's Enhanced Smog Check program, ca. 1999. Program benefits equivalent to metric tons per day of prevented emissions were calculated with a "bottom-up" approach that combined average per vehicle reductions in mass emission rates (g/gal) with average per vehicle activity, resolved by model year. Accelerated simulation mode test data from the statewide vehicle information database (VID) and from roadside Smog Check testing were used to determine 2-yr emission profiles of vehicles passing through Smog Check and infer emission profiles that would occur without Smog Check. The number of vehicles participating in Smog Check was also determined from the VID. We estimate that in 1999 Smog Check reduced tailpipe emissions of HC, CO, and NO(x) by 97, 1690, and 81 t/d, respectively. These correspond to 26, 34, and 14% of the HC, CO, and NO(x) that would have been emitted by vehicles in the absence of Smog Check. These estimates are highly sensitive to assumptions about vehicle deterioration in the absence of Smog Check. Considering the estimated uncertainty in these assumptions yields a range for calculated benefits: 46-128 t/d of HC, 860-2200 t/d of CO, and 60-91 t/d of NO(x). Repair of vehicles that failed an initial, official Smog Check appears to be the most important mechanism of emission reductions, but pre-inspection maintenance and repair also contributed substantially. Benefits from removal of nonpassing

  10. Air pollution emission under control?; Luchtverontreinigende emissies onder controle?

    Energy Technology Data Exchange (ETDEWEB)

    Verbeek, R.; Smokers, R. [TNO Mobility / Sustainable Transport and Logistics, Delft (Netherlands)

    2011-10-15

    The air-polluting emissions of lorries and inland shipping needs to adhere to increasingly strict requirements. As a result, the emissions of new vehicles and vessels in 2020 will only be a fraction of the emissions of for example 1990. How does it work out in practice? Is it useful to switch to alternative fuels in the coming years, such as for example natural gas and biofuels? Or will all air-polluting emission problems have been solved in the near future, allowing for full focus on energy use and CO2 reduction?. [Dutch] De luchtverontreinigende emissies van vrachtauto's en binnenvaartschepen moeten aan steeds strengere eisen voldoen. Daardoor zullen de emissies van nieuwe voer- en vaartuigen in 2020 nog maar een fractie zijn in vergelijking tot bijvoorbeeld 1990. Werkt het allemaal goed in de praktijk? En heeft het de komende jaren nog zin om over te stappen naar alternatieve brandstoffen zoals aardgas en biobrandstoffen? Of zijn alle problemen rond de luchtverontreinigende emissies straks van de baan en kunnen we de focus geheel richten op energieverbruik en CO2-reductie?.

  11. Dioxin emission factors for automobiles from tunnel air sampling in Northern Taiwan.

    Science.gov (United States)

    Chang, Moo Been; Chang, Shu Hao; Chen, Yuan Wu; Hsu, Hsuan Chien

    2004-06-05

    This study measured PCDD/F concentrations in tunnel air and vehicle exhaust. The ambient air samples were collected with air samplers (Tisch PS-1) complying with USEPA TO-9A. The results indicate that the tunnel air had a PCDD/F TEQ concentration about two times as high as that of outside air (47.3 and 57.1 fg-I-TEQ/m3 for tunnel air vs. 37.1 fg-I-TEQ/m3 and 23.3 fg-I-TEQ/m3 for outside air, respectively). This provides the direct evidence that PCDD/F compounds are emitted from the combustion processes in gasoline- and diesel-fueled engines. According to the tunnel study, the emission factors ranged from 5.83 to 59.2 pg I-TEQ/km for gasoline vehicles and 23.32 to 236.65 pg I-TEQ/km of diesel vehicles. This indicates that the dioxin emission factor in Taiwan is lower than that measured in USA, Norway and Germany. When the speed of the diesel vehicle was set at 40 km/h, the dioxin concentration emitted from diesel vehicle was 278 pg/m3 (6.27 pg-I-TEQ/m3) from tailpipe testing. However, when the diesel vehicle was idled, the dioxin concentration increased greatly to 4078 pg/m3 (41.9 pg-I-TEQ/m3). From the results of tunnel air sampling, the PCDD/Fs emission from automobiles in Taiwan was estimated as 3.69 g I-TEQ per year. Copryright 2003 Elsevier B.V.

  12. Lidar method to estimate emission rates from extended sources

    Science.gov (United States)

    Currently, point measurements, often combined with models, are the primary means by which atmospheric emission rates are estimated from extended sources. However, these methods often fall short in their spatial and temporal resolution and accuracy. In recent years, lidar has emerged as a suitable to...

  13. Energy and air emission effects of water supply.

    Science.gov (United States)

    Stokes, Jennifer R; Horvath, Arpad

    2009-04-15

    Life-cycle air emission effects of supplying water are explored using a hybrid life-cycle assessment For the typically sized U.S. utility analyzed, recycled water is preferable to desalination and comparable to importation. Seawater desalination has an energy and air emission footprint that is 1.5-2.4 times larger than that of imported water. However, some desalination modes fare better; brackish groundwater is 53-66% as environmentally intensive as seawater desalination. The annual water needs (326 m3) of a typical Californian that is met with imported water requires 5.8 GJ of energy and creates 360 kg of CO2 equivalent emissions. With seawater desalination, energy use would increase to 14 GJ and 800 kg of CO2 equivalent emissions. Meeting the water demand of California with desalination would consume 52% of the state's electricity. Supply options were reassessed using alternative electricity mixes, including the average mix of the United States and several renewable sources. Desalination using solar thermal energy has lower greenhouse gas emissions than that of imported and recycled water (using California's electricity mix), but using the U.S. mix increases the environmental footprint by 1.5 times. A comparison with a more energy-intensive international scenario shows that CO2 equivalent emissions for desalination in Dubai are 1.6 times larger than in California. The methods, decision support tool (WEST), and results of this study should persuade decision makers to make informed water policy choices by including energy consumption and material use effects in the decision-making process.

  14. US Department of Energy report 1996 LANL radionuclide air emissions

    Energy Technology Data Exchange (ETDEWEB)

    Jacobson, K.W.

    1997-08-01

    Presented is the Laboratory-wide certified report regarding radioactive effluents released into the air by the Los Alamos National Laboratory (LANL) in 1996. This information is required under the Clean Air Act and is being reported to the U.S. Environmental Protection Agency (EPA). The effective dose equivalent (EDE) to a hypothetical maximum exposed individual (MEI) of the public was calculated, using procedures specified by the EPA and described in this report. That dose was 1.93 mrem for 1996. Emissions of {sup 11}C, {sup 13}N, and {sup 15}O from a 1-mA, 800 MeV proton accelerator contributed over 92% of the EDE to LANL`s MEI. Using CAP88, the EPA`s dose assessment model, more than 86% of the total dose received by the MEI was via the air immersion pathway.

  15. Biogenic nonmethane hydrocarbon emissions estimated from tethered balloon observations

    Science.gov (United States)

    Davis, K. J.; Lenschow, D. H.; Zimmerman, P. R.

    1994-01-01

    A new technique for estimating surface fluxes of trace gases, the mixed-layer gradient technique, is used to calculate isoprene and terpene emissions from forests. The technique is applied to tethered balloon measurements made over the Amazon forest and a pine-oak forest in Alabama at altitudes up to 300 m. The observations were made during the dry season Amazon Boundary Layer Experiment (ABLE 2A) and the Rural Oxidants in the Southern Environment 1990 experiment (ROSE I). Results from large eddy simulations of scalar transport in the clear convective boundary layer are used to infer fluxes from the balloon profiles. Profiles from the Amazon give a mean daytime emission of 3630 +/- 1400 micrograms isoprene sq m/h, where the uncertainty represents the standard deviation of the mean of eight flux estimates. Twenty profiles from Alabama give emissions of 4470 +/- 3300 micrograms isoprene sq m/h, 1740 +/- 1060 micrograms alpha-pinene sq m/h, and 790 +/- 560 micrograms beta-pinene sq m/h, respectively. These results are in agreement with emissions derived from chemical budgets. The emissions may be overestimated because of uncertainty about how to incorporate the effects of the canopy on the mixed-layer gradients. The large variability in these emission estimates is probably due to the relatively short sampling times of the balloon profiles, though spatially heterogeneous emissions may also play a role. Fluxes derived using this technique are representative of an upwind footprint of several kilometers and are independent of hydrocarbon oxidation rate and mean advection.

  16. Particulate emission rates from light-duty vehicles in the South Coast Air Quality Management District

    International Nuclear Information System (INIS)

    Durbin, T.D.; Norbeck, J.M.; Smith, M.R.; Truex, T.J.

    1999-01-01

    This paper presents the results of a particulate emission rate study conducted on 129 light-duty gasoline and 19 light-duty diesel vehicles for the Coordinating Research Council's (CRC's) Project E-24-2. Total particulate emission rates for newer gasoline vehicles were low with modest increases with vehicle age and older technology. Average FTP particulate emission rates as a function of model year for gasoline vehicles were found to be 2.5 mg/mi for 1991 and newer models, 14.4 mg/mi for 1986--1990 models, 49.0 mg/mi for 1981--1985 models, and 33.8 mg/mi for 1980 and older models. High gaseous emitters were found to have approximately 5--10 times the particulate emission rates of normal emitters. The diesel vehicles had an average particulate emission rate of 561 mg/mi. It should be noted that the light-duty diesel vehicles were predominantly older, pre-1985 vehicles; the 1985 and newer diesel vehicles had substantially lower particulate emissions, i.e., less than 100 mg/mi. Emission inventory estimates in the South Coast Air Basin based on the fleet emission rates were higher than those obtained using the default values in EMFAC7G, due primarily to the contribution of high emitters

  17. Development of a health effects based priority ranking system for air emissions reductions from oil refineries in Canada

    International Nuclear Information System (INIS)

    McColl, S.; Gower, S.; Hicks, J.; Shortreed, J.; Craig, L.

    2004-01-01

    This paper presents the concept and methodologies behind the development of a health effects priority ranking tool for the reduction of air emissions from oil refineries. The Health Effects Indicators Decision Index- Versions 2 (Heidi II) was designed to assist policy makers in prioritizing air emissions reductions on the basis of estimated risk to human health. Inputs include facility level rankings of potential health impacts associated with carcinogenic air toxics, non-carcinogenic air toxics and criteria air contaminants for each of the 20 refineries in Canada. Rankings of estimated health impacts are presented on predicted incidence of health effects. Heidi II considers site-specific annual pollutant emission data, ambient air concentrations associated with releases and concentration response functions for various types of health effects. Additional data includes location specific background air concentrations, site-specific population densities, and the baseline incidence of different health effects endpoints, such as cancer, non-cancer illnesses and cardiorespiratory illnesses and death. Air pollutants include the 29 air toxics reported annually in Environment Canada's National Pollutant Release Inventory. Three health impact ranking outputs are provided for each facility: ranking of pollutants based on predicted number of annual cases of health effects; ranking of pollutants based on simplified Disability Adjusted Life Years (DALYs); and ranking of pollutants based on more complex DALYs that consider types of cancer, systemic disease or types of cardiopulmonary health effects. Rankings rely on rough statistical estimates of predicted incidence rates for health endpoints. The models used to calculate rankings can provide useful guidance by comparing estimated health impacts. Heidi II has demonstrated that it is possible to develop a consistent and objective approach for ranking priority reductions of air emissions. Heidi II requires numerous types and

  18. Interactions between energy efficiency and emission trading under the 1990 Clean Air Act Amendments

    International Nuclear Information System (INIS)

    Hillsman, E.L.; Alvic, D.R.

    1994-08-01

    The 1990 Clean Air Act Amendments affect electric utilities in numerous ways. The feature that probably has received the greatest attention is the provision to let utilities trade emissions of sulfur dioxide (SO 2 ), while at the same time requiring them to reduce S0 2 emissions in 2000 by an aggregate 43%. The emission trading system was welcomed by many as a way of reducing the cost of reducing emissions, by providing greater flexibility than past approaches. This report examines some of the potential interactions between trading emissions and increasing end-use energy efficiency. The analysis focuses on emission trading in the second phase of the trading program, which begins in 2000. The aggregate effects, calculated by an emission compliance and trading model, turn out to be rather small. Aggressive improvement of end-use efficiency by all utilities might reduce allowance prices by $22/ton (1990 dollars), which is small compared to the reduction that has occurred in the estimates of future allowance prices and when compared to the roughly $400/ton price we estimate as a base case. However, the changes in the allowance market that result are large enough to affect some compliance decisions. If utilities in only a few states improve end-use efficiency aggressively, their actions may not have a large effect on the price of an allowance, but they could alter the demand for allowances and thereby the compliance decisions of utilities in other states. The analysis shows how improving electricity end-use efficiency in some states can cause smaller emission reductions in other states, relative to what would have happened without the improvements. Such a result, while not surprising given the theory behind the emission trading system, is upsetting to people who view emissions, environmental protection, and energy efficiency in moral rather than strictly economic terms

  19. Method to Estimate the Dissolved Air Content in Hydraulic Fluid

    Science.gov (United States)

    Hauser, Daniel M.

    2011-01-01

    In order to verify the air content in hydraulic fluid, an instrument was needed to measure the dissolved air content before the fluid was loaded into the system. The instrument also needed to measure the dissolved air content in situ and in real time during the de-aeration process. The current methods used to measure the dissolved air content require the fluid to be drawn from the hydraulic system, and additional offline laboratory processing time is involved. During laboratory processing, there is a potential for contamination to occur, especially when subsaturated fluid is to be analyzed. A new method measures the amount of dissolved air in hydraulic fluid through the use of a dissolved oxygen meter. The device measures the dissolved air content through an in situ, real-time process that requires no additional offline laboratory processing time. The method utilizes an instrument that measures the partial pressure of oxygen in the hydraulic fluid. By using a standardized calculation procedure that relates the oxygen partial pressure to the volume of dissolved air in solution, the dissolved air content is estimated. The technique employs luminescent quenching technology to determine the partial pressure of oxygen in the hydraulic fluid. An estimated Henry s law coefficient for oxygen and nitrogen in hydraulic fluid is calculated using a standard method to estimate the solubility of gases in lubricants. The amount of dissolved oxygen in the hydraulic fluid is estimated using the Henry s solubility coefficient and the measured partial pressure of oxygen in solution. The amount of dissolved nitrogen that is in solution is estimated by assuming that the ratio of dissolved nitrogen to dissolved oxygen is equal to the ratio of the gas solubility of nitrogen to oxygen at atmospheric pressure and temperature. The technique was performed at atmospheric pressure and room temperature. The technique could be theoretically carried out at higher pressures and elevated

  20. Ship emissions and air pollution in Denmark. Present situation and future scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Roerdam Olesen, H.; Winther, M.; Ellermann, T.; Christensen, Jesper; Plejdrup, M. (Aarhus Univ., National Environmental Research Institute, Aarhus (Denmark))

    2009-07-01

    order to evaluate the effect of the IMO regulations. The scenario calculations have been based on expected reductions in ship emissions and an estimate for land-based emissions in 2020. Finally, the contribution to local air pollution from ships at ports has been assessed in various ways, based on updates of previous studies.

  1. Emission estimates for some acidifying and greenhouse gases and options for their control in Finland

    Energy Technology Data Exchange (ETDEWEB)

    Pipatti, R. [VTT Energy, Espoo (Finland). Energy Systems

    1998-11-01

    This thesis presents estimates and options for control of anthropogenic ammonia (NH{sub 3}), methane (CH{sub 4}), nitrous oxide (N{sub 2}O) and some halocarbon emissions in Finland. Ammonia is an air pollutant which contributes to both acidification and nitrogen eutrophication of ecosystems. Its emissions are mainly caused by livestock manure. In Finland the anthropogenic emissions of NH{sub 3} have been estimated to be approximately 44 Gg in 1985 and 43 Gg in 1990. In the 1990`s the emissions have declined due to the reduced number of cattle and voluntary implementation of emission reducing measures. The impact of NH{sub 3} emissions on acidification is serious but in Finland it is less than the impact of the other acidifying gases sulphur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}). All three gases and their transformation products are transported by the atmosphere up to distances of hundreds or even more than a thousand kilometres. NH{sub 3} emissions can be reduced with relatively cost-effective measures and the measures can partly replace the implementation of more costly abatement measures on SO{sub 2} and NO{sub x} emissions needed to lower the acidifying deposition in Finland. The other gases studied in this thesis are greenhouse gases. Some of the gases also deplete stratospheric ozone. Finnish anthropogenic CH{sub 4} emissions have been estimated to be around 250 Gg per year during the 1990`s. The emissions come mainly from landfills and agricultural sources (enteric fermentation and manure). The significance of other CH{sub 4} sources in Finland is minor. The potential to reduce the Finnish CH{sub 4} emissions is estimated to be good. Landfill gas recovery offers an option to reduce the emissions significantly at negligible cost if the energy produced can be utilised in electricity and/or heat production. Measures directed at reducing the emissions from livestock manure management are more costly, and the achievable reduction in the emissions

  2. Temporal trends and spatial variation characteristics of primary air pollutants emissions from coal-fired industrial boilers in Beijing, China

    International Nuclear Information System (INIS)

    Xue, Yifeng; Tian, Hezhong; Yan, Jing; Zhou, Zhen; Wang, Junling; Nie, Lei; Pan, Tao; Zhou, Junrui; Hua, Shenbing; Wang, Yong; Wu, Xiaoqing

    2016-01-01

    Coal-fired combustion is recognized as a significant anthropogenic source of atmospheric compounds in Beijing, causing heavy air pollution events and associated deterioration in visibility. Obtaining an accurate understanding of the temporal trends and spatial variation characteristics of emissions from coal-fired industrial combustion is essential for predicting air quality changes and evaluating the effectiveness of current control measures. In this study, an integrated emission inventory of primary air pollutants emitted from coal-fired industrial boilers in Beijing is developed for the period of 2007–2013 using a technology-based approach. Future emission trends are projected through 2030 based on current energy-related and emission control policies. Our analysis shows that there is a general downward trend in primary air pollutants emissions because of the implementation of stricter local emission standards and the promotion by the Beijing municipal government of converting from coal-fired industrial boilers to gas-fired boilers. However, the ratio of coal consumed by industrial boilers to total coal consumption has been increasing, raising concerns about the further improvement of air quality in Beijing. Our estimates indicate that the total emissions of PM 10 , PM 2.5 , SO 2 , NO x , CO and VOCs from coal-fired industrial boilers in Beijing in 2013 are approximately 19,242 t, 13,345 t, 26,615 t, 22,965 t, 63,779 t and 1406 t, respectively. Under the current environmental policies and relevant energy savings and emission control plans, it may be possible to reduce NO x and other air pollutant emissions by 94% and 90% by 2030, respectively, if advanced flue gas purification technologies are implemented and coal is replaced with natural gas in the majority of existing boilers. - Highlights: • A unit-based emission inventory of coal-fired industrial boilers is developed. • Temporal trend of historical period 2007–2013 and the future till 2030 is

  3. Estimating marginal CO2 emissions rates for national electricity systems

    International Nuclear Information System (INIS)

    Hawkes, A.D.

    2010-01-01

    The carbon dioxide (CO 2 ) emissions reduction afforded by a demand-side intervention in the electricity system is typically assessed by means of an assumed grid emissions rate, which measures the CO 2 intensity of electricity not used as a result of the intervention. This emissions rate is called the 'marginal emissions factor' (MEF). Accurate estimation of MEFs is crucial for performance assessment because their application leads to decisions regarding the relative merits of CO 2 reduction strategies. This article contributes to formulating the principles by which MEFs are estimated, highlighting the strengths and weaknesses in existing approaches, and presenting an alternative based on the observed behaviour of power stations. The case of Great Britain is considered, demonstrating an MEF of 0.69 kgCO 2 /kW h for 2002-2009, with error bars at +/-10%. This value could reduce to 0.6 kgCO 2 /kW h over the next decade under planned changes to the underlying generation mix, and could further reduce to approximately 0.51 kgCO 2 /kW h before 2025 if all power stations commissioned pre-1970 are replaced by their modern counterparts. Given that these rates are higher than commonly applied system-average or assumed 'long term marginal' emissions rates, it is concluded that maintenance of an improved understanding of MEFs is valuable to better inform policy decisions.

  4. Estimates of future climate based on SRES emission scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Godal, Odd; Sygna, Linda; Fuglestvedt, Jan S.; Berntsen, Terje

    2000-02-14

    The preliminary emission scenarios in the Special Report on Emission Scenario (SRES) developed by the Intergovernmental Panel on Climate Change (IPCC), will eventually replace the old IS92 scenarios. By running these scenarios in a simple climate model (SCM) we estimate future temperature increase between 1.7 {sup o}C and 2.8 {sup o}C from 1990 to to 2100. The global sea level rise over the same period is between 0.33 m and 0.45 m. Compared to the previous IPCC scenarios (IS92) the SRES scenarios generally results in changes in both development over time and level of emissions, concentrations, radiative forcing, and finally temperature change and sea level rise. The most striking difference between the IS92 scenarios and the SRES scenarios is the lower level of SO{sub 2} emissions. The range in CO{sub 2} emissions is also expected to be narrower in the new scenarios. The SRES scenarios result in a narrower range both for temperature change and sea level rise from 1990 to 2100 compared to the range estimated for the IS92 scenarios. (author)

  5. Application of High Resolution Air-Borne Remote Sensing Observations for Monitoring NOx Emissions

    Science.gov (United States)

    Souri, A.; Choi, Y.; Pan, S.; Curci, G.; Janz, S. J.; Kowalewski, M. G.; Liu, J.; Herman, J. R.; Weinheimer, A. J.

    2017-12-01

    Nitrogen oxides (NOx=NO+NO2) are one of the air pollutants, responsible for the formation of tropospheric ozone, acid rain and particulate nitrate. The anthropogenic NOx emissions are commonly estimated based on bottom-up inventories which are complicated by many potential sources of error. One way to improve the emission inventories is to use relevant observations to constrain them. Fortunately, Nitrogen dioxide (NO2) is one of the most successful detected species from remote sensing. Although many studies have shown the capability of using space-borne remote sensing observations for monitoring emissions, the insufficient sample number and footprint of current measurements have introduced a burden to constrain emissions at fine scales. Promisingly, there are several air-borne sensors collected for NASA's campaigns providing high spatial resolution of NO2 columns. Here, we use the well-characterized NO2 columns from the Airborne Compact Atmospheric Mapper (ACAM) onboard NASA's B200 aircraft into a 1×1 km regional model to constrain anthropogenic NOx emissions in the Houston-Galveston-Brazoria area. Firstly, in order to incorporate the data, we convert the NO2 slant column densities to vertical ones using a joint of a radiative transfer model and the 1x1 km regional model constrained by P3-B aircraft measurements. After conducting an inverse modeling method using the Kalman filter, we find the ACAM observations are resourceful at mitigating the overprediction of model in reproducing NO2 on regular days. Moreover, the ACAM provides a unique opportunity to detect an anomaly in emissions leading to strong air quality degradation that is lacking in previous works. Our study provides convincing evidence that future geostationary satellites with high spatial and temporal resolutions will give us insights into uncertainties associated with the emissions at regional scales.

  6. On the validity of the incremental approach to estimate the impact of cities on air quality

    Science.gov (United States)

    Thunis, Philippe

    2018-01-01

    The question of how much cities are the sources of their own air pollution is not only theoretical as it is critical to the design of effective strategies for urban air quality planning. In this work, we assess the validity of the commonly used incremental approach to estimate the likely impact of cities on their air pollution. With the incremental approach, the city impact (i.e. the concentration change generated by the city emissions) is estimated as the concentration difference between a rural background and an urban background location, also known as the urban increment. We show that the city impact is in reality made up of the urban increment and two additional components and consequently two assumptions need to be fulfilled for the urban increment to be representative of the urban impact. The first assumption is that the rural background location is not influenced by emissions from within the city whereas the second requires that background concentration levels, obtained with zero city emissions, are equal at both locations. Because the urban impact is not measurable, the SHERPA modelling approach, based on a full air quality modelling system, is used in this work to assess the validity of these assumptions for some European cities. Results indicate that for PM2.5, these two assumptions are far from being fulfilled for many large or medium city sizes. For this type of cities, urban increments are largely underestimating city impacts. Although results are in better agreement for NO2, similar issues are met. In many situations the incremental approach is therefore not an adequate estimate of the urban impact on air pollution. This poses issues in terms of interpretation when these increments are used to define strategic options in terms of air quality planning. We finally illustrate the interest of comparing modelled and measured increments to improve our confidence in the model results.

  7. Estimation of greenhouse impacts of continuous regional emissions

    Energy Technology Data Exchange (ETDEWEB)

    Sinisalo, J. [VTT Energy, Espoo (Finland). Energy Systems

    1998-11-01

    In this thesis a method to calculate the greenhouse impact of continuous, time-dependent, non-global greenhouse gas emissions is used to estimate the impact of estimated anthropogenic pre-1990 and future (post 1990) emissions of CO{sub 2}, CH{sub 4} and N{sub 2}O from Finland and the Nordic countries. Estimates for the impact of Finnish CFCs and their substitutes and the significance of Finnish forests as carbon sink are also calculated. The method is also used to compare several different wood and peat energy production schemes with fossil fuel use, in terms of caused greenhouse impact. The uncertainty of the results is examined. The greenhouse impact is measured in this thesis as the global mean direct radiative forcing caused by the emissions. Radiative forcing is the driving force behind the climate change and as such it can be used to assess the ensuing climate change. The method is suitable for greenhouse agents that can be considered to be well mixed in the atmosphere (mainly CO{sub 2}, CH{sub 4}, N{sub 2}O and both CFCs and their substitutes). According to the results Finnish greenhouse impact due to anthropogenic CO{sub 2}, CH{sub 4} and N{sub 2}O emissions has increased eight-fold during this century, and will very likely remain higher than current level throughout the next century. The impact of the Nordic countries has followed the same general pattern as Finland. It is likely that the per capita radiative forcing of the Nordic countries will remain above the global average. The uncertainty of the absolute results is quite high due to uncertain knowledge at several stages of the calculation. When the results are used in comparisons (e.g. between emission scenarios, or emissions of different countries), the accuracy of the results increases considerably. (orig.) 54 refs.

  8. Urban emissions hotspots: Quantifying vehicle congestion and air pollution using mobile phone GPS data.

    Science.gov (United States)

    Gately, Conor K; Hutyra, Lucy R; Peterson, Scott; Sue Wing, Ian

    2017-10-01

    On-road emissions vary widely on time scales as short as minutes and length scales as short as tens of meters. Detailed data on emissions at these scales are a prerequisite to accurately quantifying ambient pollution concentrations and identifying hotspots of human exposure within urban areas. We construct a highly resolved inventory of hourly fluxes of CO, NO 2 , NO x , PM 2.5 and CO 2 from road vehicles on 280,000 road segments in eastern Massachusetts for the year 2012. Our inventory integrates a large database of hourly vehicle speeds derived from mobile phone and vehicle GPS data with multiple regional datasets of vehicle flows, fleet characteristics, and local meteorology. We quantify the 'excess' emissions from traffic congestion, finding modest congestion enhancement (3-6%) at regional scales, but hundreds of local hotspots with highly elevated annual emissions (up to 75% for individual roadways in key corridors). Congestion-driven reductions in vehicle fuel economy necessitated 'excess' consumption of 113 million gallons of motor fuel, worth ∼ $415M, but this accounted for only 3.5% of the total fuel consumed in Massachusetts, as over 80% of vehicle travel occurs in uncongested conditions. Across our study domain, emissions are highly spatially concentrated, with 70% of pollution originating from only 10% of the roads. The 2011 EPA National Emissions Inventory (NEI) understates our aggregate emissions of NO x , PM 2.5 , and CO 2 by 46%, 38%, and 18%, respectively. However, CO emissions agree within 5% for the two inventories, suggesting that the large biases in NO x and PM 2.5 emissions arise from differences in estimates of diesel vehicle activity. By providing fine-scale information on local emission hotspots and regional emissions patterns, our inventory framework supports targeted traffic interventions, transparent benchmarking, and improvements in overall urban air quality. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. An improved model for estimating pesticide emissions for agricultural LCA

    DEFF Research Database (Denmark)

    Dijkman, Teunis Johannes; Birkved, Morten; Hauschild, Michael Zwicky

    2011-01-01

    Credible quantification of chemical emissions in the inventory phase of Life Cycle Assessment (LCA) is crucial since chemicals are the dominating cause of the human and ecotoxicity-related environmental impacts in Life Cycle Impact Assessment (LCIA). When applying LCA for assessment of agricultural...... products, off-target pesticide emissions need to be quantified as accurately as possible because of the considerable toxicity effects associated with chemicals designed to have a high impact on biological organisms like for example insects or weed plants. PestLCI was developed to estimate the fractions...

  10. Life-cycle air emissions from PV power systems

    International Nuclear Information System (INIS)

    Watt, M.E.; Johnson, A.J.; Outhred, H.R.; Ellis, M.

    1998-01-01

    This paper addresses the air emission of grid supply versus grid-connected and off-grid photovoltaic power generation, using the framework of life-cycle assessment, in the contents of rural household energy supply in Australia. Emissions of carbon dioxide, sulphur dioxde and nitrous oxides are calculated for the three life-cycle stages of manufacture, use and disposal. Sensitivities to materials and data inputs, as well as to component efficiencies, lifetimes and sizing are discussed. For each supply option, demand management options, including insulation and appliance choice, and the substitution of solar heating or bottled gas for electricity are considered. The best option in all cases, in terms of life-cycle air emissions, is a grid-connected photovoltaic system used to supply an energy-efficient household with a mix of solar, gas and electric appliances. However, in financial terms, with current Australian energy prices, this option represents a high capital and life-cycle costs. Additionally, for the grid options, electricity costs do not significantly disadvantage the high demand scenarios. Both results provide a clear illustration of current Australian energy-pricing policies being in conflict with long-term environmental sustainability. (Author)

  11. Recent advances in prediction of emission of hazardous air pollutants from coal-fired power plants

    International Nuclear Information System (INIS)

    Senior, C.L.; Helble, J.J.; Sarofim, A.F.

    2000-01-01

    Coal-fired power plants are a primary source of mercury discharge into the atmosphere along with fine particulates containing arsenic, selenium, cadmium, and other hazardous air pollutants. Information regarding the speciation of these toxic metals is necessary to accurately predict their atmospheric transport and fate in the environment. New predictive tools have been developed to allow utilities to better estimate the emissions of toxic metals from coal-fired power plants. These prediction equations are based on fundamental physics and chemistry and can be applied to a wide variety of fuel types and combustion conditions. The models have significantly improved the ability to predict the emissions of air toxic metals in fine particulate and gas-phase mercury. In this study, the models were successfully tested using measured mercury speciation and mass balance information collected from coal-fired power plants

  12. Reconciling Top-Down and Bottom-Up Estimates of Oil and Gas Methane Emissions in the Barnett Shale

    Science.gov (United States)

    Hamburg, S.

    2015-12-01

    Top-down approaches that use aircraft, tower, or satellite-based measurements of well-mixed air to quantify regional methane emissions have typically estimated higher emissions from the natural gas supply chain when compared to bottom-up inventories. A coordinated research campaign in October 2013 used simultaneous top-down and bottom-up approaches to quantify total and fossil methane emissions in the Barnett Shale region of Texas. Research teams have published individual results including aircraft mass-balance estimates of regional emissions and a bottom-up, 25-county region spatially-resolved inventory. This work synthesizes data from the campaign to directly compare top-down and bottom-up estimates. A new analytical approach uses statistical estimators to integrate facility emission rate distributions from unbiased and targeted high emission site datasets, which more rigorously incorporates the fat-tail of skewed distributions to estimate regional emissions of well pads, compressor stations, and processing plants. The updated spatially-resolved inventory was used to estimate total and fossil methane emissions from spatial domains that match seven individual aircraft mass balance flights. Source apportionment of top-down emissions between fossil and biogenic methane was corroborated with two independent analyses of methane and ethane ratios. Reconciling top-down and bottom-up estimates of fossil methane emissions leads to more accurate assessment of natural gas supply chain emission rates and the relative contribution of high emission sites. These results increase our confidence in our understanding of the climate impacts of natural gas relative to more carbon-intensive fossil fuels and the potential effectiveness of mitigation strategies.

  13. Estimating the Impact of Urbanization on Air Quality in China Using Spatial Regression Models

    Directory of Open Access Journals (Sweden)

    Chuanglin Fang

    2015-11-01

    Full Text Available Urban air pollution is one of the most visible environmental problems to have accompanied China’s rapid urbanization. Based on emission inventory data from 2014, gathered from 289 cities, we used Global and Local Moran’s I to measure the spatial autorrelation of Air Quality Index (AQI values at the city level, and employed Ordinary Least Squares (OLS, Spatial Lag Model (SAR, and Geographically Weighted Regression (GWR to quantitatively estimate the comprehensive impact and spatial variations of China’s urbanization process on air quality. The results show that a significant spatial dependence and heterogeneity existed in AQI values. Regression models revealed urbanization has played an important negative role in determining air quality in Chinese cities. The population, urbanization rate, automobile density, and the proportion of secondary industry were all found to have had a significant influence over air quality. Per capita Gross Domestic Product (GDP and the scale of urban land use, however, failed the significance test at 10% level. The GWR model performed better than global models and the results of GWR modeling show that the relationship between urbanization and air quality was not constant in space. Further, the local parameter estimates suggest significant spatial variation in the impacts of various urbanization factors on air quality.

  14. Global fire emissions estimates during 1997–2016

    Directory of Open Access Journals (Sweden)

    G. R. van der Werf

    2017-09-01

    Full Text Available Climate, land use, and other anthropogenic and natural drivers have the potential to influence fire dynamics in many regions. To develop a mechanistic understanding of the changing role of these drivers and their impact on atmospheric composition, long-term fire records are needed that fuse information from different satellite and in situ data streams. Here we describe the fourth version of the Global Fire Emissions Database (GFED and quantify global fire emissions patterns during 1997–2016. The modeling system, based on the Carnegie–Ames–Stanford Approach (CASA biogeochemical model, has several modifications from the previous version and uses higher quality input datasets. Significant upgrades include (1 new burned area estimates with contributions from small fires, (2 a revised fuel consumption parameterization optimized using field observations, (3 modifications that improve the representation of fuel consumption in frequently burning landscapes, and (4 fire severity estimates that better represent continental differences in burning processes across boreal regions of North America and Eurasia. The new version has a higher spatial resolution (0.25° and uses a different set of emission factors that separately resolves trace gas and aerosol emissions from temperate and boreal forest ecosystems. Global mean carbon emissions using the burned area dataset with small fires (GFED4s were 2.2  ×  1015 grams of carbon per year (Pg C yr−1 during 1997–2016, with a maximum in 1997 (3.0 Pg C yr−1 and minimum in 2013 (1.8 Pg C yr−1. These estimates were 11 % higher than our previous estimates (GFED3 during 1997–2011, when the two datasets overlapped. This net increase was the result of a substantial increase in burned area (37 %, mostly due to the inclusion of small fires, and a modest decrease in mean fuel consumption (−19 % to better match estimates from field studies, primarily in savannas and

  15. Probabilistic estimation of residential air exchange rates for ...

    Science.gov (United States)

    Residential air exchange rates (AERs) are a key determinant in the infiltration of ambient air pollution indoors. Population-based human exposure models using probabilistic approaches to estimate personal exposure to air pollutants have relied on input distributions from AER measurements. An algorithm for probabilistically estimating AER was developed based on the Lawrence Berkley National Laboratory Infiltration model utilizing housing characteristics and meteorological data with adjustment for window opening behavior. The algorithm was evaluated by comparing modeled and measured AERs in four US cities (Los Angeles, CA; Detroit, MI; Elizabeth, NJ; and Houston, TX) inputting study-specific data. The impact on the modeled AER of using publically available housing data representative of the region for each city was also assessed. Finally, modeled AER based on region-specific inputs was compared with those estimated using literature-based distributions. While modeled AERs were similar in magnitude to the measured AER they were consistently lower for all cities except Houston. AERs estimated using region-specific inputs were lower than those using study-specific inputs due to differences in window opening probabilities. The algorithm produced more spatially and temporally variable AERs compared with literature-based distributions reflecting within- and between-city differences, helping reduce error in estimates of air pollutant exposure. Published in the Journal of

  16. A high-resolution air pollutants emission inventory in 2013 for the Beijing-Tianjin-Hebei region, China

    Science.gov (United States)

    Qi, Ji; Zheng, Bo; Li, Meng; Yu, Fang; Chen, Chuchu; Liu, Fei; Zhou, Xiafei; Yuan, Jing; Zhang, Qiang; He, Kebin

    2017-12-01

    We developed a high-resolution Beijing-Tianjin-Hebei (BTH) regional air pollutants emission inventory for the year 2013. The inventory was established using a bottom-up approach based on facility-level activity data obtained from multiple data sources. The estimates from the BTH 2013 emission inventory show that the total emissions of SO2, NOX, PM2.5, PM10, CO, NMVOC, NH3, BC, and OC were 2,305, 2,686, 1,090, 1,494, 20,567, 2,207, 623, 160, and 254 Gg, respectively. The industry sector is the largest emissions source for SO2, NOX, PM2.5, PM10, CO, and NMVOC in the BTH region, contributing 72.6%, 43.7%, 59.6%, 64.7%, 60.3%, and 70.4% of the total emissions, respectively. Power plants contributed 11.8% and 23.3% of the total SO2 and NOX emissions, respectively. The transportation sector contributed 28.9% of the total NOX emissions. Emissions from the residential sector accounted for 31.3%, 21.5%, 46.6% and 71.7% of the total PM2.5, NMVOC, BC and OC emissions, respectively. In addition, more than 90% of the total NH3 emissions originate from the agriculture sector, with 44.2% from fertilizer use and 47.7% from livestock. The spatial distribution results illustrate that air pollutant emissions are mainly distributed over the eastern and southern BTH regions. Beijing, Tianjin, Shijiazhuang, Tangshan and Handan are the major contributors of air pollutants. The major NMVOC species in the BTH region are ethylene, acetylene, ethane and toluene. Ethylene is the biggest contributor in Tianjin and Hebei. The largest contributor in Beijing is toluene. There is relatively low uncertainty in SO2 and NOX emission estimates, medium uncertainty in PM2.5, PM10 and CO emission estimates, and high uncertainties in VOC, NH3, BC and OC emission estimates. The proposed policy recommendations, based on the BTH 2013 emission inventory, would be helpful to develop strategies for air pollution control.

  17. Influence of benzene emission from motorcycle on Bangkok air quality

    Science.gov (United States)

    Leong, Shing Tet; Muttamara, S.; Laortanakul, Preecha

    This study investigated the influence of benzene concentration from motorcycle exhaust emissions on ambient air quality in Bangkok Metropolitan Region (BMR). Measurement of benzene concentration in exhaust emissions is performed on a standard test driving cycle through which each motorcycle to be tested is driven. The test result revealed that average benzene concentrations in exhaust emission for the test motorcycles ranged from 3.02 to 109.68 mg/m 3. The finding also indicated that two-stroke motorcycles emitted five times more benzene than that of four-stroke motorcycles. Four air monitoring sites were strategically established to determine the relationship between average benzene concentrations with different traffic configurations in each traffic zone of BMR during peak/non-peak hours, day/night times and weekday/weekend. The shape of the curve for benzene level usually shows two peaks corresponding to the morning and evening traffic rush or commuter rush hours. The finding shows that the mean concentrations for benzene in all monitoring stations in the ambient air for peak hours (07:00-09:00 and 16:00-18:00 h) ranged from 15.1 to 42.4 μg/m 3. For non-peak hour (11:30-15:00 h), benzene levels were found in the range 16.3-30.9 μg/m 3. It is observed that higher levels of benzene are found among roadside stations with slow moving traffic while lower levels are found among roadside stations with fast traffic movement. Additional factors such as temperature, wind speed, rainfall, etc. are also considered in this study to determine the relationship between traffic conditions and ambient benzene levels.

  18. Modelling Southern Africa Air Quality and Atmosphere: Importance and Interplay of Natural and Anthropogenic Emissions

    Science.gov (United States)

    Garland, R. M.; Naidoo, M.; Dedekind, Z.; Sibiya, B.; Piketh, S.; Engelbrecht, C. J.; Engelbrecht, F.

    2017-12-01

    Many parts of the southern hemisphere are linked in part due to the strong impact that emissions from natural sources, such as large biomass burning events and marine sources, as well as growing anthropogenic emission sources. Most of southern Africa has an arid to semi-arid climate that is strongly impacted by biomass burning, biogenic and dust emissions. In addition, there are areas of growing industrialization and urbanization that contributes to poor air quality. This air pollution can impact not only human health, but also agriculture, ecosystems, and the climate. This presentation will highlight on-going research to simulate the southern Africa atmosphere and impacts, with a focus on the interplay and relative importance of natural and anthropogenic emissions. The presentation will discuss the simulated sensitivity of the southern African climate to aerosol particles to highlight the importance of natural sources. These historical simulations (1979-2012) were performed with CCAM and are towards the development of the first Africa-led earth systems model. The analysis focused on the simulated sensitivity of the climate and clouds off the southwestern coast of Africa to aerosol particles. The interplay between natural and anthropogenic sources on air pollution will be highlighted using the Waterberg region of South Africa as a case study. CAMx was run at 2km resolution for 2013 using local emission inventories and meteorological output from CCAM to simulate the air quality of the region. These simulations estimate that, on average in the summer, up to 20% of ozone in and around a power plant plume is attributable to biogenic sources of VOCs, with ozone peaks of up to 120ppb; highlighting the importance of understanding the mix of pollutants in this area. In addition to presenting results from this study, the challenges in modelling will be highlighted. These challenges include very few or no measurements that are important to understand, and then accurately

  19. National emission standards for hazardous air pollutants submittal - 1996

    International Nuclear Information System (INIS)

    Townsend, Y.E.; Black, S.C.

    1997-06-01

    The Nevada Test Site (NTS) is operated by the US Department of Energy, Nevada Operations Office (DOE/NV) as the site for nuclear weapons testing. Monitoring and evaluation of the various activities conducted onsite indicate that the potential sources of offsite radiation exposure in 1996 were releases from the following: evaporation of tritiated water from containment ponds that receive drainage from E tunnel and from wells used for site characterization studies; onsite radioanalytical laboratories; the Area 5 RWMS facility; and diffuse sources of tritium and resuspension of plutonium. Section 1 describes these sources on the NTS. Section 2 tabulates the air emissions data for the NTS. These data are used to calculate the effective dose equivalents to offsite residents. Appendices describe the methods used to determine the emissions from the sources listed

  20. Top-down estimates of benzene and toluene emissions in the Pearl River Delta and Hong Kong, China

    Directory of Open Access Journals (Sweden)

    X. Fang

    2016-03-01

    Full Text Available Benzene (C6H6 and toluene (C7H8 are toxic to humans and the environment. They are also important precursors of ground-level ozone and secondary organic aerosols and contribute substantially to severe air pollution in urban areas in China. Discrepancies exist between different bottom-up inventories for benzene and toluene emissions in the Pearl River Delta (PRD and Hong Kong (HK, which are emission hot spots in China. This study provides top-down estimates of benzene and toluene emissions in the PRD and HK using atmospheric measurement data from a rural site in the area, Heshan, an atmospheric transport model, and an inverse modeling method. The model simulations captured the measured mixing ratios during most pollution episodes. For the PRD and HK, the benzene emissions estimated in this study for 2010 were 44 (12–75 and 5 (2–7 Gg yr−1 for the PRD and HK, respectively, and the toluene emissions were 131 (44–218 and 6 (2–9 Gg yr−1, respectively. Temporal and spatial differences between the inversion estimate and four different bottom-up emission estimates are discussed, and it is proposed that more observations at different sites are urgently needed to better constrain benzene and toluene (and other air pollutant emissions in the PRD and HK in the future.

  1. Top-down estimates of benzene and toluene emissions in the Pearl River Delta and Hong Kong, China

    Science.gov (United States)

    Fang, Xuekun; Shao, Min; Stohl, Andreas; Zhang, Qiang; Zheng, Junyu; Guo, Hai; Wang, Chen; Wang, Ming; Ou, Jiamin; Thompson, Rona L.; Prinn, Ronald G.

    2016-03-01

    Benzene (C6H6) and toluene (C7H8) are toxic to humans and the environment. They are also important precursors of ground-level ozone and secondary organic aerosols and contribute substantially to severe air pollution in urban areas in China. Discrepancies exist between different bottom-up inventories for benzene and toluene emissions in the Pearl River Delta (PRD) and Hong Kong (HK), which are emission hot spots in China. This study provides top-down estimates of benzene and toluene emissions in the PRD and HK using atmospheric measurement data from a rural site in the area, Heshan, an atmospheric transport model, and an inverse modeling method. The model simulations captured the measured mixing ratios during most pollution episodes. For the PRD and HK, the benzene emissions estimated in this study for 2010 were 44 (12-75) and 5 (2-7) Gg yr-1 for the PRD and HK, respectively, and the toluene emissions were 131 (44-218) and 6 (2-9) Gg yr-1, respectively. Temporal and spatial differences between the inversion estimate and four different bottom-up emission estimates are discussed, and it is proposed that more observations at different sites are urgently needed to better constrain benzene and toluene (and other air pollutant) emissions in the PRD and HK in the future.

  2. Methodology to estimate particulate matter emissions from certified commercial aircraft engines.

    Science.gov (United States)

    Wayson, Roger L; Fleming, Gregg G; Lovinelli, Ralph

    2009-01-01

    Today, about one-fourth of U.S. commercial service airports, including 41 of the busiest 50, are either in nonattainment or maintenance areas per the National Ambient Air Quality Standards. U.S. aviation activity is forecasted to triple by 2025, while at the same time, the U.S. Environmental Protection Agency (EPA) is evaluating stricter particulate matter (PM) standards on the basis of documented human health and welfare impacts. Stricter federal standards are expected to impede capacity and limit aviation growth if regulatory mandated emission reductions occur as for other non-aviation sources (i.e., automobiles, power plants, etc.). In addition, strong interest exists as to the role aviation emissions play in air quality and climate change issues. These reasons underpin the need to quantify and understand PM emissions from certified commercial aircraft engines, which has led to the need for a methodology to predict these emissions. Standardized sampling techniques to measure volatile and nonvolatile PM emissions from aircraft engines do not exist. As such, a first-order approximation (FOA) was derived to fill this need based on available information. FOA1.0 only allowed prediction of nonvolatile PM. FOA2.0 was a change to include volatile PM emissions on the basis of the ratio of nonvolatile to volatile emissions. Recent collaborative efforts by industry (manufacturers and airlines), research establishments, and regulators have begun to provide further insight into the estimation of the PM emissions. The resultant PM measurement datasets are being analyzed to refine sampling techniques and progress towards standardized PM measurements. These preliminary measurement datasets also support the continued refinement of the FOA methodology. FOA3.0 disaggregated the prediction techniques to allow for independent prediction of nonvolatile and volatile emissions on a more theoretical basis. The Committee for Aviation Environmental Protection of the International Civil

  3. Overview of Megacity Air Pollutant Emissions and Impacts

    Science.gov (United States)

    Kolb, C. E.

    2013-05-01

    The urban metabolism that characterizes major cities consumes very large qualities of humanly produced and/or processed food, fuel, water, electricity, construction materials and manufactured goods, as well as, naturally provided sunlight, precipitation and atmospheric oxygen. The resulting urban respiration exhalations add large quantities of trace gas and particulate matter pollutants to urban atmospheres. Key classes of urban primary air pollutants and their sources will be reviewed and important secondary pollutants identified. The impacts of these pollutants on urban and downwind regional inhabitants, ecosystems, and climate will be discussed. Challenges in quantifying the temporally and spatially resolved urban air pollutant emissions and secondary pollutant production rates will be identified and possible measurement strategies evaluated.

  4. Wind Energy and Air Emission Reduction Benefits: A Primer

    Energy Technology Data Exchange (ETDEWEB)

    Jacobson, D.; High, C.

    2008-02-01

    This document provides a summary of the impact of wind energy development on various air pollutants for a general audience. The core document addresses the key facts relating to the analysis of emission reductions from wind energy development. It is intended for use by a wide variety of parties with an interest in this issue, ranging from state environmental officials to renewable energy stakeholders. The appendices provide basic background information for the general reader, as well as detailed information for those seeking a more in-depth discussion of various topics.

  5. Methods for Measuring and Estimating Methane Emission from Ruminants

    Directory of Open Access Journals (Sweden)

    Jørgen Madsen

    2012-04-01

    Full Text Available This paper is a brief introduction to the different methods used to quantify the enteric methane emission from ruminants. A thorough knowledge of the advantages and disadvantages of these methods is very important in order to plan experiments, understand and interpret experimental results, and compare them with other studies. The aim of the paper is to describe the principles, advantages and disadvantages of different methods used to quantify the enteric methane emission from ruminants. The best-known methods: Chambers/respiration chambers, SF6 technique and in vitro gas production technique and the newer CO2 methods are described. Model estimations, which are used to calculate national budget and single cow enteric emission from intake and diet composition, are also discussed. Other methods under development such as the micrometeorological technique, combined feeder and CH4 analyzer and proxy methods are briefly mentioned. Methods of choice for estimating enteric methane emission depend on aim, equipment, knowledge, time and money available, but interpretation of results obtained with a given method can be improved if knowledge about the disadvantages and advantages are used in the planning of experiments.

  6. Estimates of clear night sky emissivity in the Negev Highlands, Israel

    International Nuclear Information System (INIS)

    Tang Runsheng; Etzion, Y.; Meir, I.A.

    2004-01-01

    A simple method was introduced to estimate the atmospheric emissivity of clear night skies based on the water temperature variation inside an open shallow pond. The method used the pond as an absorber of atmospheric radiation by measuring the water evaporation rate from the pond to ambient air and then calculating the heat loss inside the pond due to the radiative heat exchange between the pond and sky dome. An empirical correlation for the calculations of clear night sky emissivity in the Negev Highlands, Israel, was found. It showed that the emissivity of clear night sky in the Negev Highlands is slightly lower than that expected by Berdahl et al. and Clark's correlations under the climatic conditions during the period of measurements

  7. Using Multiple Regression in Estimating (semi) VOC Emissions and Concentrations at the European Scale

    DEFF Research Database (Denmark)

    Fauser, Patrik; Thomsen, Marianne; Pistocchi, Alberto

    2010-01-01

    chemicals available in the European Chemicals Bureau risk assessment reports (RARs). The method suggests a simple linear relationship between Henry's Law constant, octanol-water coefficient, use and production volumes, and emissions and PECs on a regional scale in the European Union. Emissions and PECs......This paper proposes a simple method for estimating emissions and predicted environmental concentrations (PECs) in water and air for organic chemicals that are used in household products and industrial processes. The method has been tested on existing data for 63 organic high-production volume...... are a result of a complex interaction between chemical properties, production and use patterns and geographical characteristics. A linear relationship cannot capture these complexities; however, it may be applied at a cost-efficient screening level for suggesting critical chemicals that are candidates...

  8. Measurement of Ozone Emission and Particle Removal Rates from Portable Air Purifiers

    Science.gov (United States)

    Mang, Stephen A.; Walser, Maggie L.; Nizkorodov, Sergey A.; Laux, John M.

    2009-01-01

    Portable air purifiers are popular consumer items, especially in areas with poor air quality. Unfortunately, most users of these air purifiers have minimal understanding of the factors affecting their efficiency in typical indoor settings. Emission of the air pollutant ozone (O[subscript 3]) by certain air purifiers is of particular concern. In an…

  9. Hazardous air pollutant emissions from gas-fired combustion sources: emissions and the effects of design and fuel type

    Energy Technology Data Exchange (ETDEWEB)

    England, G.C.; McGrath, T.P. [GE-Energy and Environmental Research Corp., Irvine, CA (United States); Gilmer, L. [Equilon Enterprises, Bellaire, TX (United States); Seebold, J.G. [Chevron Research and Technology Co., Richmond, CA (United States); Lev-On, M. [ARCO, Los Angeles, CA (United States); Hunt, T. [American Petroleum Institute, Washington, DC (United States)

    2001-07-01

    Air emissions from gas-fired combustion devices such as boilers, process heaters, gas turbines and stationary reciprocating engines contain hazardous air pollutants (HAPs) subjected to consideration under the federal clean air act (CAA). This work presents a recently completed major research project to develop an understanding of HAP emissions from gas-fired boilers and process heaters and new HAP emission factors based on field emission tests of gas-fired external combustion devices used in the petroleum industry. The effect of combustion system design and operating parameters on HAP emissions determined by both field and research tests are discussed. Data from field tests of gas-fired petroleum industry boilers and heaters generally show very low emission levels of organic HAPs. A comparison of the emission data for boilers and process heaters, including units with and without various forms of NO{sub x} emission controls, showed no significant difference in organic HAP emission characteristics due to process or burner design. This conclusion is also supported by the results of research tests with different burner designs. Based on field tests of units fired with natural gas and various petroleum industry process gases and research tests in which gas composition was intentionally varied, organic HAP emissions were not determined to be significantly affected by the gas composition. Research data indicate that elevated organic HAP emission levels are found only under extreme operating conditions (starved air or high excess air combustion) associated with poor combustion. (author)

  10. Hazardous air pollutant emissions from gas-fired combustion sources: emissions and the effects of design and fuel type

    International Nuclear Information System (INIS)

    England, G.C.; McGrath, T.P.; Gilmer, L.; Seebold, J.G.; Lev-On, M.; Hunt, T.

    2001-01-01

    Air emissions from gas-fired combustion devices such as boilers, process heaters, gas turbines and stationary reciprocating engines contain hazardous air pollutants (HAPs) subjected to consideration under the federal clean air act (CAA). This work presents a recently completed major research project to develop an understanding of HAP emissions from gas-fired boilers and process heaters and new HAP emission factors based on field emission tests of gas-fired external combustion devices used in the petroleum industry. The effect of combustion system design and operating parameters on HAP emissions determined by both field and research tests are discussed. Data from field tests of gas-fired petroleum industry boilers and heaters generally show very low emission levels of organic HAPs. A comparison of the emission data for boilers and process heaters, including units with and without various forms of NO x emission controls, showed no significant difference in organic HAP emission characteristics due to process or burner design. This conclusion is also supported by the results of research tests with different burner designs. Based on field tests of units fired with natural gas and various petroleum industry process gases and research tests in which gas composition was intentionally varied, organic HAP emissions were not determined to be significantly affected by the gas composition. Research data indicate that elevated organic HAP emission levels are found only under extreme operating conditions (starved air or high excess air combustion) associated with poor combustion. (author)

  11. Estimate of Possible CO2 Emission Reduction in Slovenia

    International Nuclear Information System (INIS)

    Plavcak, V.-P.; Jevsek, F.; Tirsek, A.

    1998-01-01

    The first estimation of possible CO 2 emission reduction, according to the obligations from Kyoto Protocol, is prepared. The results show that the required 8% reduction of greenhouses gases in Slovenia in the period from 2008 to 2012 with regard to year 1986 will require a through analytical treatment not only in electric power sector but also in transport and industry sectors, which are the main pollutants. (author)

  12. Marine vessel air emissions in the Lower Fraser Valley for the year 2000

    International Nuclear Information System (INIS)

    Quan, R.G.; Cheng, K.C.; Trask, T.C.; Meilleur, R.A.

    2002-01-01

    Emissions inventories are used by government agencies as a tool for policy development and air quality management. Marine vessels have been identified as a major source of anthropogenic pollution in British Columbia. This report presents estimates of emissions from marine vessels in coastal areas of British Columbia's Fraser Valley Regional District (FVRD) for the year 2000. The project includes an update of emission estimates for each marine vessel category and an update of emission estimates for pollutants of interest, including carbon monoxide (CO), nitrogen oxides (NOx), particulate matter (PM), sulphur oxides (SOx), volatile organic compounds (VOCs), as well as inhalable fine particulates (PM10 and PM2.5) and greenhouse gases such as carbon dioxide, methane, nitrous oxide and ammonia. This report presents both spatial and temporal allocation of emissions. Results indicate that ocean-going vessels are the major contributor to emissions of NOx, SOx, PM and greenhouse gases, accounting for 58, 95, 82, and 58 per cent of the total marine vessel emissions respectively. They also contribute 14 per cent to the marine totals for CO and VOCs. Harbour vessels contribute 28 and 27 per cent of NOx and greenhouse gases and 10 per cent or less to all other contaminant totals. Ferries contribute between 2 per cent and 13 per cent for to each contaminant, including 13 per cent of NOx, 12 per cent of greenhouse gases, and 6 per cent of CO. Fishing vessels contribute 1 per cent or less of all contaminants. Although recreational vessels are major contributors for CO and VOC, they contribute less than 10 per cent for all other contaminants. A comparison of 1993 and 2000 marine vessel inventory for British Columbia was presented and recommendations for improvements were presented. refs., tabs., figs

  13. Assessment of methane emission and oxidation at Air Hitam Landfill site cover soil in wet tropical climate.

    Science.gov (United States)

    Abushammala, Mohammed F M; Basri, Noor Ezlin Ahmad; Elfithri, Rahmah

    2013-12-01

    Methane (CH₄) emissions and oxidation were measured at the Air Hitam sanitary landfill in Malaysia and were modeled using the Intergovernmental Panel on Climate Change waste model to estimate the CH₄ generation rate constant, k. The emissions were measured at several locations using a fabricated static flux chamber. A combination of gas concentrations in soil profiles and surface CH₄ and carbon dioxide (CO₂) emissions at four monitoring locations were used to estimate the CH₄ oxidation capacity. The temporal variations in CH₄ and CO₂ emissions were also investigated in this study. Geospatial means using point kriging and inverse distance weight (IDW), as well as arithmetic and geometric means, were used to estimate total CH₄ emissions. The point kriging, IDW, and arithmetic means were almost identical and were two times higher than the geometric mean. The CH₄ emission geospatial means estimated using the kriging and IDW methods were 30.81 and 30.49 gm(−2) day(−1), respectively. The total CH₄ emissions from the studied area were 53.8 kg day(−1). The mean of the CH₄ oxidation capacity was 27.5 %. The estimated value of k is 0.138 year(−1). Special consideration must be given to the CH₄ oxidation in the wet tropical climate for enhancing CH₄ emission reduction.

  14. Estimation of bare soil surface temperature from air temperature and ...

    African Journals Online (AJOL)

    Soil surface temperature has critical influence on climate, agricultural and hydrological activities since it serves as a good indicator of the energy budget of the earth's surface. Two empirical models for estimating soil surface temperature from air temperature and soil depth temperature were developed. The coefficient of ...

  15. Estimating the burden of disease attributable to urban outdoor air ...

    African Journals Online (AJOL)

    Outdoor air pollution in urban areas in South Africa was estimated to cause 3.7% of the national mortality from cardiopulmonary disease and 5.1 % of mortality attributable to cancers of the trachea, bronchus and lung in adults aged 30 years and older, and 1.1 % of mortality from ARis in children under 5 years of age.

  16. Glass science tutorial: Lecture No. 4, commercial glass melting and associated air emission issues

    International Nuclear Information System (INIS)

    Kruger, A.A.

    1995-01-01

    This document serves as a manual for a workshop on commercial glass melting and associated air emission issues. Areas covered include: An overview of the glass industry; Furnace design and construction practices; Melting furnace operation; Energy input methods and controls; Air legislation and regulations; Soda lime emission mechanisms; and, Post furnace emission controls. Supporting papers are also included

  17. Glass science tutorial: Lecture No. 4, commercial glass melting and associated air emission issues

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, A.A.

    1995-01-01

    This document serves as a manual for a workshop on commercial glass melting and associated air emission issues. Areas covered include: An overview of the glass industry; Furnace design and construction practices; Melting furnace operation; Energy input methods and controls; Air legislation and regulations; Soda lime emission mechanisms; and, Post furnace emission controls. Supporting papers are also included.

  18. 76 FR 9409 - National Emission Standards for Hazardous Air Pollutants: Primary Lead Smelting

    Science.gov (United States)

    2011-02-17

    ... National Emission Standards for Hazardous Air Pollutants: Primary Lead Smelting; Proposed Rule #0;#0... Emission Standards for Hazardous Air Pollutants: Primary Lead Smelting AGENCY: Environmental Protection... standards for hazardous air pollutants (NESHAP) for Primary Lead Smelting to address the results of the...

  19. 'TEWI' concept for estimation of the global warming from the refrigerating and air conditioning systems

    International Nuclear Information System (INIS)

    Ciconkov, Risto

    2002-01-01

    The most applied CFC refrigerants and their HFC alternatives. values of ODP (Ozone Depletion Potential) and GWP (Global Warming Potential) of the most used refrigerants. natural working fluids and their properties. Montreal Protocol and Kyoto Protocol, illogical relations between them concerning to the HFC fluids. Confusion and polemics on the international level about the appliance of HFCs which, by the Kyoto Protocol, are liable to reduction. Introduction of the TEWI concept as a method for estimating the overall influence of refrigerating and air conditioning systems on the greenhouse effect: the direct emission (refrigerant leakage in the atmosphere) and indirect emission as a result of the electrical energy consumption. A demonstration of the TEWI concept on the concrete example in several variants. A discussion about the appliance of the TEWI concept. Meaning of the energy efficiency of the refrigerating systems (indirect CO 2 emission). One of the main measures: prevention of refrigerant leakage (direct CO 2 emission). A need of permanent education and training courses of the people who work on refrigerating and air conditioning systems. A necessity for constitution of an expert body in the country, preparation of a strategy to lay obligations on the new changes of the Kyoto Protocol and news on the world market. Introduction of country regulations, certification of the companies and people involved in refrigeration and air conditioning. (Author)

  20. Improving the accuracy of vehicle emissions profiles for urban transportation greenhouse gas and air pollution inventories.

    Science.gov (United States)

    Reyna, Janet L; Chester, Mikhail V; Ahn, Soyoung; Fraser, Andrew M

    2015-01-06

    Metropolitan greenhouse gas and air emissions inventories can better account for the variability in vehicle movement, fleet composition, and infrastructure that exists within and between regions, to develop more accurate information for environmental goals. With emerging access to high quality data, new methods are needed for informing transportation emissions assessment practitioners of the relevant vehicle and infrastructure characteristics that should be prioritized in modeling to improve the accuracy of inventories. The sensitivity of light and heavy-duty vehicle greenhouse gas (GHG) and conventional air pollutant (CAP) emissions to speed, weight, age, and roadway gradient are examined with second-by-second velocity profiles on freeway and arterial roads under free-flow and congestion scenarios. By creating upper and lower bounds for each factor, the potential variability which could exist in transportation emissions assessments is estimated. When comparing the effects of changes in these characteristics across U.S. cities against average characteristics of the U.S. fleet and infrastructure, significant variability in emissions is found to exist. GHGs from light-duty vehicles could vary by -2%-11% and CAP by -47%-228% when compared to the baseline. For heavy-duty vehicles, the variability is -21%-55% and -32%-174%, respectively. The results show that cities should more aggressively pursue the integration of emerging big data into regional transportation emissions modeling, and the integration of these data is likely to impact GHG and CAP inventories and how aggressively policies should be implemented to meet reductions. A web-tool is developed to aide cities in improving emissions uncertainty.

  1. Hazardous air pollutant (HAP) emission characterization of sewage treatment facilities in Korea.

    Science.gov (United States)

    Kang, Kyoung-Hee; Dong, Jong-In

    2010-04-01

    Until recently, nearly all sewage treatment-related regulations and researches have focused on the removal of the conventional and toxic pollutants from liquid effluents. The discharge of toxic compounds to the atmosphere has been implicitly regarded as a way of removal or destruction. During sewage treatment, the fate mechanism of volatilization/stripping, sorption and biotransformation primarily determines the fate of volatile HAPs. The objectives of this study are to investigate the emission characteristics of HAPs, which are generated from the liquid surface of sewage treatment facilities, by using an emission isolation flux chamber. HAP emissions increased at the inlet of the aerobic chamber during summer due to the relatively high atmospheric temperature. The percent ratio of flux for toluene reached its peak in winter, accounting for 33.6-34.2% of the total, but decreased to 25.1-28.6% in summer. In autumn, trichloroethene (TCE) was the highest, recording 17.6-18.1%, with chloroform and toluene showing similar levels. It seems that the ratio of chlorinated hydrocarbons increases in both summer and autumn because the chamber temperature during that time is higher than winter. This study is the initial study to investigate the emission characteristics of volatile HAPs emitted from domestic sewage treatment facilities to the air in Korea. Therefore, the isolation flux chamber will be used as an emission estimations tool to measure HAPs from sewage treatment facilities and may be applied to develop the emission factor and national source inventory of HAPs.

  2. Covariance specification and estimation to improve top-down Green House Gas emission estimates

    Science.gov (United States)

    Ghosh, S.; Lopez-Coto, I.; Prasad, K.; Whetstone, J. R.

    2015-12-01

    The National Institute of Standards and Technology (NIST) operates the North-East Corridor (NEC) project and the Indianapolis Flux Experiment (INFLUX) in order to develop measurement methods to quantify sources of Greenhouse Gas (GHG) emissions as well as their uncertainties in urban domains using a top down inversion method. Top down inversion updates prior knowledge using observations in a Bayesian way. One primary consideration in a Bayesian inversion framework is the covariance structure of (1) the emission prior residuals and (2) the observation residuals (i.e. the difference between observations and model predicted observations). These covariance matrices are respectively referred to as the prior covariance matrix and the model-data mismatch covariance matrix. It is known that the choice of these covariances can have large effect on estimates. The main objective of this work is to determine the impact of different covariance models on inversion estimates and their associated uncertainties in urban domains. We use a pseudo-data Bayesian inversion framework using footprints (i.e. sensitivities of tower measurements of GHGs to surface emissions) and emission priors (based on Hestia project to quantify fossil-fuel emissions) to estimate posterior emissions using different covariance schemes. The posterior emission estimates and uncertainties are compared to the hypothetical truth. We find that, if we correctly specify spatial variability and spatio-temporal variability in prior and model-data mismatch covariances respectively, then we can compute more accurate posterior estimates. We discuss few covariance models to introduce space-time interacting mismatches along with estimation of the involved parameters. We then compare several candidate prior spatial covariance models from the Matern covariance class and estimate their parameters with specified mismatches. We find that best-fitted prior covariances are not always best in recovering the truth. To achieve

  3. Top-down Estimates of Greenhouse Gas Intensities and Emissions for Individual Oil Sands Facilities in Alberta Canada

    Science.gov (United States)

    Liggio, J.; Li, S. M.; Staebler, R. M.; Hayden, K. L.; Mittermeier, R. L.; McLaren, R.; Baray, S.; Darlington, A.; Worthy, D.; O'Brien, J.

    2017-12-01

    The oil sands (OS) region of Alberta contributes approximately 10% to Canada's overall anthropogenic greenhouse gas (GHG) emissions. Such emissions have traditionally been estimated through "bottom-up" methods which seek to account for all individual sources of GHGs within a given facility. However, it is recognized that bottom-up approaches for complex industrial facilities can be subject to uncertainties associated with incomplete or inaccurate emission factor and/or activity data. In order to quantify air pollutant emissions from oil sands activities an aircraft-based measurement campaign was performed in the summer of 2013. The aircraft measurements could also be used to quantify GHG emissions for comparison to the bottom up emissions estimates. Utilizing specific flight patterns, together with an emissions estimation algorithm and measurements of CO2 and methane, a "top-down" estimate of GHG intensities for several large surface mining operations was obtained. The results demonstrate that there is a wide variation in emissions intensities (≈80 - 220 kg CO2/barrel oil) across OS facilities, which in some cases agree with calculated intensities, and in other cases are larger than that estimated using industry reported GHG emission and oil production data. When translated to annual GHG emissions, the "top-down" approach results in a CO2 emission of approximately 41 Mega Tonnes (MT) CO2/year for the 4 OS facilities investigated, in contrast to the ≈26 MT CO2/year reported by industry. The results presented here highlight the importance of using "top-down" approaches as a complimentary method in evaluating GHG emissions from large industrial sources.

  4. Emissions from the burning of vegetative debris in air curtain destructors.

    Science.gov (United States)

    Miller, C Andrew; Lemieux, Paul M

    2007-08-01

    Although air curtain destructors (ACDs) have been used for quite some time to dispose of vegetative debris, relatively little in-depth testing has been conducted to quantify emissions of pollutants other than CO and particulate matter. As part of an effort to prepare for possible use of ACDs to dispose of the enormous volumes of debris generated by Hurricanes Katrina and Rita, the literature on ACD emissions was reviewed to identify potential environmental issues associated with ACD disposal of construction and demolition (C&D) debris. Although no data have been published on emissions from C&D debris combustion in an ACD, a few studies provided information on emissions from the combustion of vegetative debris. These studies are reviewed, and the results compared with studies of open burning of biomass. Combustion of vegetative debris in ACD units results in significantly lower emissions of particulate matter and CO per unit of mass of debris compared with open pile burning. The available data are not sufficient to make general estimates regarding emissions of organic or metal compounds. The highly transient nature of the ACD combustion process, a minimal degree of operational control, and significant variability in debris properties make accurate prediction of ACD emissions impossible in general. Results of scoping tests conducted in preparation for possible in-depth emissions tests demonstrate the challenges associated with sampling ACD emissions and highlight the transient nature of the process. The environmental impacts of widespread use of ACDs for disposal of vegetative debris and their potential use to reduce the volume of C&D debris in future disaster response scenarios remain a considerable gap in understanding the risks associated with debris disposal options.

  5. Improved air ventilation rate estimation based on a statistical model

    International Nuclear Information System (INIS)

    Brabec, M.; Jilek, K.

    2004-01-01

    A new approach to air ventilation rate estimation from CO measurement data is presented. The approach is based on a state-space dynamic statistical model, allowing for quick and efficient estimation. Underlying computations are based on Kalman filtering, whose practical software implementation is rather easy. The key property is the flexibility of the model, allowing various artificial regimens of CO level manipulation to be treated. The model is semi-parametric in nature and can efficiently handle time-varying ventilation rate. This is a major advantage, compared to some of the methods which are currently in practical use. After a formal introduction of the statistical model, its performance is demonstrated on real data from routine measurements. It is shown how the approach can be utilized in a more complex situation of major practical relevance, when time-varying air ventilation rate and radon entry rate are to be estimated simultaneously from concurrent radon and CO measurements

  6. Biofuels that cause land-use change may have much larger non-GHG air quality emissions than fossil fuels.

    Science.gov (United States)

    Tsao, C-C; Campbell, J E; Mena-Carrasco, M; Spak, S N; Carmichael, G R; Chen, Y

    2012-10-02

    Although biofuels present an opportunity for renewable energy production, significant land-use change resulting from biofuels may contribute to negative environmental, economic, and social impacts. Here we examined non-GHG air pollution impacts from both indirect and direct land-use change caused by the anticipated expansion of Brazilian biofuels production. We synthesized information on fuel loading, combustion completeness, and emission factors, and developed a spatially explicit approach with uncertainty and sensitivity analyses to estimate air pollution emissions. The land-use change emissions, ranging from 6.7 to 26.4 Tg PM(2.5), were dominated by deforestation burning practices associated with indirect land-use change. We also found Brazilian sugar cane ethanol and soybean biodiesel including direct and indirect land-use change effects have much larger life-cycle emissions than conventional fossil fuels for six regulated air pollutants. The emissions magnitude and uncertainty decrease with longer life-cycle integration periods. Results are conditional to the single LUC scenario employed here. After LUC uncertainty, the largest source of uncertainty in LUC emissions stems from the combustion completeness during deforestation. While current biofuels cropland burning policies in Brazil seek to reduce life-cycle emissions, these policies do not address the large emissions caused by indirect land-use change.

  7. National Emission Standards for Hazardous Air Pollutants - Radionuclide Emissions, Calendar Year 2010

    International Nuclear Information System (INIS)

    2011-01-01

    The U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office operates the Nevada National Security Site (NNSS, formerly the Nevada Test Site) and North Las Vegas Facility (NLVF). From 1951 through 1992, the NNSS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NNSS activities has been monitored since the initiation of atmospheric testing. Limitation to underground detonations after 1962 greatly reduced radiation exposure to the public surrounding the NNSS. After nuclear testing ended in 1992, NNSS radiation monitoring focused on detecting airborne radionuclides from historically contaminated soils. These radionuclides are derived from re-suspension of soil (primarily by wind) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of tritium are also emitted to air at the NLVF, an NNSS support complex in North Las Vegas. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations (CFR) Part 61 Subpart H) (CFR, 2010a) limits the release of radioactivity from a U.S. Department of Energy (DOE) facility to that which would cause 10 millirem per year (mrem/yr) effective dose equivalent to any member of the public. This limit does not include radiation unrelated to NNSS activities. Unrelated doses could come from naturally occurring radioactive elements, from sources such as medically or commercially used radionuclides, or from sources outside of the United States, such as those from the damaged Fukushima nuclear power plant in Japan. Because this report is intended to discuss radioactive air emissions during calendar year 2010, data on radionuclides in air from the 2011 Fukushima nuclear power plant releases are not presented but will be included in the report for calendar year 2011. The NNSS demonstrates compliance with the NESHAP

  8. Impacts of air pollutants from fire and non-fire emissions on the regional air quality in Southeast Asia

    Directory of Open Access Journals (Sweden)

    H.-H. Lee

    2018-05-01

    Full Text Available Severe haze events in Southeast Asia caused by particulate pollution have become more intense and frequent in recent years. Widespread biomass burning occurrences and particulate pollutants from human activities other than biomass burning play important roles in degrading air quality in Southeast Asia. In this study, numerical simulations have been conducted using the Weather Research and Forecasting (WRF model coupled with a chemistry component (WRF-Chem to quantitatively examine the contributions of aerosols emitted from fire (i.e., biomass burning versus non-fire (including fossil fuel combustion, and road dust, etc. sources to the degradation of air quality and visibility over Southeast Asia. These simulations cover a time period from 2002 to 2008 and are driven by emissions from (a fossil fuel burning only, (b biomass burning only, and (c both fossil fuel and biomass burning. The model results reveal that 39 % of observed low-visibility days (LVDs can be explained by either fossil fuel burning or biomass burning emissions alone, a further 20 % by fossil fuel burning alone, a further 8 % by biomass burning alone, and a further 5 % by a combination of fossil fuel burning and biomass burning. Analysis of an 24 h PM2.5 air quality index (AQI indicates that the case with coexisting fire and non-fire PM2.5 can substantially increase the chance of AQI being in the moderate or unhealthy pollution level from 23 to 34 %. The premature mortality in major Southeast Asian cities due to degradation of air quality by particulate pollutants is estimated to increase from  ∼  4110 per year in 2002 to  ∼  6540 per year in 2008. In addition, we demonstrate the importance of certain missing non-fire anthropogenic aerosol sources including anthropogenic fugitive and industrial dusts in causing urban air quality degradation. An experiment of using machine learning algorithms to forecast the occurrence of haze events in Singapore is

  9. Impacts of air pollutants from fire and non-fire emissions on the regional air quality in Southeast Asia

    Science.gov (United States)

    Lee, Hsiang-He; Iraqui, Oussama; Gu, Yefu; Hung-Lam Yim, Steve; Chulakadabba, Apisada; Yiu-Ming Tonks, Adam; Yang, Zhengyu; Wang, Chien

    2018-05-01

    Severe haze events in Southeast Asia caused by particulate pollution have become more intense and frequent in recent years. Widespread biomass burning occurrences and particulate pollutants from human activities other than biomass burning play important roles in degrading air quality in Southeast Asia. In this study, numerical simulations have been conducted using the Weather Research and Forecasting (WRF) model coupled with a chemistry component (WRF-Chem) to quantitatively examine the contributions of aerosols emitted from fire (i.e., biomass burning) versus non-fire (including fossil fuel combustion, and road dust, etc.) sources to the degradation of air quality and visibility over Southeast Asia. These simulations cover a time period from 2002 to 2008 and are driven by emissions from (a) fossil fuel burning only, (b) biomass burning only, and (c) both fossil fuel and biomass burning. The model results reveal that 39 % of observed low-visibility days (LVDs) can be explained by either fossil fuel burning or biomass burning emissions alone, a further 20 % by fossil fuel burning alone, a further 8 % by biomass burning alone, and a further 5 % by a combination of fossil fuel burning and biomass burning. Analysis of an 24 h PM2.5 air quality index (AQI) indicates that the case with coexisting fire and non-fire PM2.5 can substantially increase the chance of AQI being in the moderate or unhealthy pollution level from 23 to 34 %. The premature mortality in major Southeast Asian cities due to degradation of air quality by particulate pollutants is estimated to increase from ˜ 4110 per year in 2002 to ˜ 6540 per year in 2008. In addition, we demonstrate the importance of certain missing non-fire anthropogenic aerosol sources including anthropogenic fugitive and industrial dusts in causing urban air quality degradation. An experiment of using machine learning algorithms to forecast the occurrence of haze events in Singapore is also explored in this study. All of these

  10. Air pollutant emissions from rice straw open field burning in India, Thailand and the Philippines

    International Nuclear Information System (INIS)

    Gadde, Butchaiah; Bonnet, Sebastien; Menke, Christoph; Garivait, Savitri

    2009-01-01

    Rice is a widely grown crop in Asia. China (30%) and India (21%) contribute to about half of the world's total rice production. In this study, three major rice-producing countries in Asia are considered, India, Thailand and the Philippines (the later two contributing 4% and 2% of the world's rice production). Rice straw is one of the main field based residues produced along with this commodity and its applications vary widely in the region. Although rice production practises vary from one country to another, open burning of straw is a common practice in these countries. In this study, an approach was followed aiming at (a) determining the quantity of rice straw being subject to open field burning in those countries, (b) congregating pollutant specific emissions factors for rice straw burning, and (c) quantifying the resulting air pollutant emissions. Uncertainties in the results obtained as compared to a global approach are also discussed. - This research work contributes to enhance scientific knowledge for estimating air pollutant emissions from open burning of crop residues and improve emission results accuracy.

  11. Intake fractions of industrial air pollutants in China. Estimation and application

    International Nuclear Information System (INIS)

    Wang, Shuxiao; Hao, Jiming; Li, Ji; Lu, Yongqi; Ho, Mun S.

    2006-01-01

    Intake fractions, an emissions-intake relationship for primary pollutants, are defined and are estimated in order to make simple estimates of health damages from air pollution. The sulfur dioxide (SO 2 ) and total suspended particles (TSP) intake fractions for five cities of China are estimated for the four main polluting industries-electric power generation, mineral (mostly cement) products industry, chemical process industry and metallurgical industry (mainly iron and steel smelting). The Industrial Source Complex Long Term (ISTLT3) model is used to simulate the spatial distribution of incremental ambient concentrations due to emissions from a large sample of site-specific sources. Detailed population distribution information is used for each city. The average intake fractions within 50 km of these sources are 4.4x10 -6 for TSP, and 4.2x10 -6 for SO 2 , with standard deviations of 8.15x10 -6 and 9.16x10 -6 , respectively. They vary over a wide range, from 10 -7 to 10 -5 . Although the electric power generation has been the focus of much of the air pollution research in China, our results show that it has the lowest average intake fraction for a local range among the four industries, which highlights the importance of pollutant emissions from other industrial sources. Sensitivity analyses show how the intake fractions are affected by the source and pollutant characteristics, the most important parameter being the size of the domain. However, the intake fraction estimates are robust enough to be useful for evaluating the local impacts on human health of primary SO 2 and TSP emissions. An application of intake fractions is given to demonstrate how this approach provides a rapid population risk estimate if the dose-response function is linear without threshold, and hence can help in prioritizing pollution control efforts. (author)

  12. Estimating the opportunity costs of reducing carbon dioxide emissions via avoided deforestation, using integrated assessment modelling

    NARCIS (Netherlands)

    Overmars, K.P.; Stehfest, E.; Tabeau, A.A.; Meijl, van J.C.M.; Beltran, A.M.; Kram, T.

    2014-01-01

    Estimates show that, in recent years, deforestation and forest degradation accounted for about 17% of global greenhouse gas emissions. The implementation of REDD (Reducing Emissions from Deforestation and Forest Degradation in Developing Countries) is suggested to provide substantial emission

  13. Multimodel estimates of premature human mortality due to intercontinental transport of air pollution

    Science.gov (United States)

    Liang, C.; Silva, R.; West, J. J.; Sudo, K.; Lund, M. T.; Emmons, L. K.; Takemura, T.; Bian, H.

    2015-12-01

    Numerous modeling studies indicate that emissions from one continent influence air quality over others. Reducing air pollutant emissions from one continent can therefore benefit air quality and health on multiple continents. Here, we estimate the impacts of the intercontinental transport of ozone (O3) and fine particulate matter (PM2.5) on premature human mortality by using an ensemble of global chemical transport models coordinated by the Task Force on Hemispheric Transport of Air Pollution (TF HTAP). We use simulations of 20% reductions of all anthropogenic emissions from 13 regions (North America, Central America, South America, Europe, Northern Africa, Sub-Saharan Africa, Former Soviet Union, Middle East, East Asia, South Asia, South East Asia, Central Asia, and Australia) to calculate their impact on premature mortality within each region and elsewhere in the world. To better understand the impact of potential control strategies, we also analyze premature mortality for global 20% perturbations from five sectors individually: power and industry, ground transport, forest and savannah fires, residential, and others (shipping, aviation, and agriculture). Following previous studies, premature human mortality resulting from each perturbation scenario is calculated using a health impact function based on a log-linear model for O3 and an integrated exposure response model for PM2.5 to estimate relative risk. The spatial distribution of the exposed population (adults aged 25 and over) is obtained from the LandScan 2011 Global Population Dataset. Baseline mortality rates for chronic respiratory disease, ischemic heart disease, cerebrovascular disease, chronic obstructive pulmonary disease, and lung cancer are estimated from the GBD 2010 country-level mortality dataset for the exposed population. Model results are regridded from each model's original grid to a common 0.5°x0.5° grid used to estimate mortality. We perform uncertainty analysis and evaluate the sensitivity

  14. Radioactive air emissions notice of construction 241-ER-311 catch tank

    International Nuclear Information System (INIS)

    HILL, J.S.

    1999-01-01

    The following description, attachments and references are provided to the Washington State Department of Health (WDOH), Division of Radiation Protection, Air Emissions and Defense Waste Section as a notice of construction (NOC) in accordance with the Washington Administrative Code (WAC) 246-247, Radiation Protection - Air Emissions. The WAC 246-247-060, ''Applications, registration and licensing,'' states ''This section describes the information requirements for approval to construct, modify, and operate an emission unit. Any NOC requires the submittal of the information listed in Appendix A,'' Appendix A (WAC 246-247-110) lists the requirements that must be addressed. Additionally, the following description, attachments and references are provided to the U.S. Environmental Protection Agency (EPA) as an NOC, in accordance with Title 40, Code of Federal Regulations (CFR), Part 6 1, ''National Emission Standards for Hazardous Air Pollutants.'' The information required for submittal to the EPA is specified in 40 CFR 61.07. The potential emissions from this activity are estimated to provide less than 0.1 millirem/year total effective dose equivalent (TEDE) to the hypothetical offsite maximally exposed individual (MEI), and commencement is needed within a short time frame. Therefore, this application is also intended to provide notification of the anticipated date of initial startup in accordance with the requirement listed in 40 CFR 61.09(a)(l), and it is requested that approval of this application will also constitute EPA acceptance of this 40 CFR 61.09(a)(l) notification. Written notification of the actual date of initial startup, in accordance with the requirement listed in 40 CFR 61.09(a)(2) will be provided later

  15. Radioactive air emissions notice of construction 241-SY-101 crust growth near term mitigation

    International Nuclear Information System (INIS)

    Homan, N.A.

    1999-01-01

    The following description and any attachments and references are provided to the Washington State Department of Health, Division of Radiation Protection, Air Emissions and Defense Waste Section as a notice of construction (NOC) in accordance with the Washington Administrative Code (WAC) 246-247, Radiation Protection - Air Emissions. The WAC 246-247-060, ''Applications, registration and licensing'', states ''This section describes the information requirements for approval to construct, modify, and operate an emission unit. Any NOC requires the submittal of the information listed in Appendix A.'' Appendix A (WAC 246-247-110), lists the requirements that must be addressed. Additionally, the following description, attachments and references are provided to the U.S. Environmental Protection Agency (EPA) as an NOC, in accordance with Title 40 Code of Federal Regulations (CFR), Part 61, ''National Emission Standards for Hazardous Air Pollutants.'' The information required for submittal to the EPA is specified in 40 CFR 61.07. The potential emissions from this activity are estimated to provide less than 0.1 mrem/year total effective dose equivalent to the hypothetical offsite maximally exposed individual, and commencement is needed within a short time frame. Therefore, this application is also intended to provide notification of the anticipated date of initial startup in accordance with the requirement listed in 40 CFR 61.09(a)(1), and it is requested that approval of this application will also constitute EPA acceptance of this 40 CFR 61.09(a)(1) notification. Written notification of the actual date of initial startup, in accordance with the requirement listed in 40 CFR 61.09(a)(2), will be provided at a later date

  16. Estimating greenhouse gas emissions using emission factors from the Sugarcane Development Company, Ahvaz, Iran

    Directory of Open Access Journals (Sweden)

    Amir Zahedi

    2018-05-01

    Full Text Available Background: Greenhouse gas (GHG emissions are increasing worldwide. They have harmful effects on human health, animals, and plants and play a major role in global warming and acid rain. Methods: This research investigated carbon dioxide (CO2 and CH4 emissions obtained from different parts of the Hakim Farabi, Dobal Khazaei, and Ramin factories which produce ethanol and yeast. Seasonal rates of CO2 at the soil surface at the studied sites were estimated from measurements made on location and at intervals with manual chambers. This study aimed to assess the production rate of GHG emissions (CH4, CO2 in the sugar production units of Hakim Farabi, Dobal Khazaei, and Ramin factories. Results: Mean concentrations of CO2 and CH4 emissions are respectively 279 500.207 and 3087.07 tons/ year from the Hakim Farabi agro-industry, 106 985.24 and 1.14 tons/year at the Dobal Khazaei ethanol producing factory, and 124 766.17 and 1.93 tons/year at the Ramin leavening producing factory. Conclusion: Sugar plant boilers and the burning of sugarcane contributed the most CO2 and CH4 emissions, respectively. Moreover, lime kilns and diesel generators showed the least carbon dioxide and methane emissions, respectively.

  17. Re-entrained road dust PM10 emission from selected streets of Krakow and its impact on air quality

    Directory of Open Access Journals (Sweden)

    Bogacki Marek

    2018-01-01

    Full Text Available Scientific research studies conducted in various parts of the world confirm that PM10 concentrations in urban air depend to a great extent on the resuspension processes of the dust deposited on the road surface. The paper presents the results of the study related to the determination of the re-entrained PM10 emissions from four selected streets of Krakow (Southern Poland together with the assessment of its impact on air quality. Examined streets are characterised by different traffic intensity (from 500 to over 20 000 vehicles per day and individual vehicle structure. Dust material sampling and estimation of the PM10 emission were conducted according to the U.S. EPA methodology (AP 42 Fifth Edition. Two variants of sample collection were applied: from the road surface including the area at the curb (4 streets and from the road surface alone (1 street. The estimates of resuspended road dust emission as well as the reference values derived from the U.S. EPA guidelines were used to assess the impact of this emission on the PM10 levels in the air at the location of one of the analysed streets. This assessment was conducted using the CALINE4 mathematical model. The study showed that the PM10 emissions from the re-entrained road dust can be responsible for up to 25 % in the winter and 50 % in the summer of the total PM10 concentrations in the air near the roads.

  18. Re-entrained road dust PM10 emission from selected streets of Krakow and its impact on air quality

    Science.gov (United States)

    Bogacki, Marek; Mazur, Marian; Oleniacz, Robert; Rzeszutek, Mateusz; Szulecka, Adriana

    2018-01-01

    Scientific research studies conducted in various parts of the world confirm that PM10 concentrations in urban air depend to a great extent on the resuspension processes of the dust deposited on the road surface. The paper presents the results of the study related to the determination of the re-entrained PM10 emissions from four selected streets of Krakow (Southern Poland) together with the assessment of its impact on air quality. Examined streets are characterised by different traffic intensity (from 500 to over 20 000 vehicles per day) and individual vehicle structure. Dust material sampling and estimation of the PM10 emission were conducted according to the U.S. EPA methodology (AP 42 Fifth Edition). Two variants of sample collection were applied: from the road surface including the area at the curb (4 streets) and from the road surface alone (1 street). The estimates of resuspended road dust emission as well as the reference values derived from the U.S. EPA guidelines were used to assess the impact of this emission on the PM10 levels in the air at the location of one of the analysed streets. This assessment was conducted using the CALINE4 mathematical model. The study showed that the PM10 emissions from the re-entrained road dust can be responsible for up to 25 % in the winter and 50 % in the summer of the total PM10 concentrations in the air near the roads.

  19. Incorrectly Interpreting the Carbon Mass Balance Technique Leads to Biased Emissions Estimates from Global Vegetation Fires

    Science.gov (United States)

    Surawski, N. C.; Sullivan, A. L.; Roxburgh, S. H.; Meyer, M.; Polglase, P. J.

    2016-12-01

    Vegetation fires are a complex phenomenon and have a range of global impacts including influences on climate. Even though fire is a necessary disturbance for the maintenance of some ecosystems, a range of anthropogenically deleterious consequences are associated with it, such as damage to assets and infrastructure, loss of life, as well as degradation to air quality leading to negative impacts on human health. Estimating carbon emissions from fire relies on a carbon mass balance technique which has evolved with two different interpretations in the fire emissions community. Databases reporting global fire emissions estimates use an approach based on `consumed biomass' which is an approximation to the biogeochemically correct `burnt carbon' approach. Disagreement between the two methods occurs because the `consumed biomass' accounting technique assumes that all burnt carbon is volatilized and emitted. By undertaking a global review of the fraction of burnt carbon emitted to the atmosphere, we show that the `consumed biomass' accounting approach overestimates global carbon emissions by 4.0%, or 100 Teragrams, annually. The required correction is significant and represents 9% of the net global forest carbon sink estimated annually. To correctly partition burnt carbon between that emitted to the atmosphere and that remaining as a post-fire residue requires the post-burn carbon content to be estimated, which is quite often not undertaken in atmospheric emissions studies. To broaden our understanding of ecosystem carbon fluxes, it is recommended that the change in carbon content associated with burnt residues be accounted for. Apart from correctly partitioning burnt carbon between the emitted and residue pools, it enables an accounting approach which can assess the efficacy of fire management operations targeted at sequestering carbon from fire. These findings are particularly relevant for the second commitment period for the Kyoto protocol, since improved landscape fire

  20. IMPROVING EMISSION INVENTORIES FOR EFFECTIVE AIR-QUALITY MANAGMENT ACROSS NORTH AMERICA - A NARSTO ASSESSMENT

    Science.gov (United States)

    The NARSTO Ozone and Particulate Matter Assessments emphasized that emission inventories are critical to the success of air quality management programs and that emissions inventories in Canada, Mexico, and the United States need improvement to meet expectations for quality, timel...

  1. Modeling to Evaluate Contribution of Oil and Gas Emissions to Air Pollution.

    Science.gov (United States)

    Thompson, Tammy M; Shepherd, Donald; Stacy, Andrea; Barna, Michael G; Schichtel, Bret A

    2017-04-01

    Oil and gas production in the Western United States has increased considerably over the past 10 years. While many of the still limited oil and gas impact assessments have focused on potential human health impacts, the typically remote locations of production in the Intermountain West suggests that the impacts of oil and gas production on national parks and wilderness areas (Class I and II areas) could also be important. To evaluate this, we utilize the Comprehensive Air quality Model with Extensions (CAMx) with a year-long modeling episode representing the best available representation of 2011 meteorology and emissions for the Western United States. The model inputs for the 2011 episodes were generated as part of the Three State Air Quality Study (3SAQS). The study includes a detailed assessment of oil and gas (O&G) emissions in Western States. The year-long modeling episode was run both with and without emissions from O&G production. The difference between these two runs provides an estimate of the contribution of the O&G production to air quality. These data were used to assess the contribution of O&G to the 8 hour average ozone concentrations, daily and annual fine particulate concentrations, annual nitrogen deposition totals and visibility in the modeling domain. We present the results for the Class I and II areas in the Western United States. Modeling results suggest that emissions from O&G activity are having a negative impact on air quality and ecosystem health in our National Parks and Class I areas. In this research, we use a modeling framework developed for oil and gas evaluation in the western United States to determine the modeled impacts of emissions associated with oil and gas production on air pollution metrics. We show that oil and gas production may have a significant negative impact on air quality and ecosystem health in some national parks and other Class I areas in the western United States. Our findings are of particular interest to federal

  2. Air quality and health effects of biogenic volatile organic compounds emissions from urban green spaces and the mitigation strategies

    International Nuclear Information System (INIS)

    Ren, Yuan; Qu, Zelong; Du, Yuanyuan; Xu, Ronghua; Ma, Danping; Yang, Guofu; Shi, Yan; Fan, Xing; Tani, Akira; Guo, Peipei; Ge, Ying; Chang, Jie

    2017-01-01

    Biogenic volatile organic compounds (BVOCs) emissions lead to fine particulate matter (PM 2.5 ) and ground-level ozone pollution, and are harmful to human health, especially in urban areas. However, most BVOCs estimations ignored the emissions from urban green spaces, causing inaccuracies in the understanding of regional BVOCs emissions and their environmental and health effects. In this study, we used the latest local vegetation datasets from our field survey and applied an estimation model to analyze the spatial-temporal patterns, air quality impacts, health damage and mitigating strategies of BVOCs emissions in the Greater Beijing Area. Results showed that: (1) the urban core was the hotspot of regional BVOCs emissions for the highest region-based emission intensity (3.0 g C m −2 yr −1 ) among the 11 sub-regions; (2) urban green spaces played much more important roles (account for 62% of total health damage) than rural forests in threating human health; (3) BVOCs emissions from green spaces will more than triple by 2050 due to urban area expansion, tree growth and environmental changes; and (4) adopting proactive management (e.g. adjusting tree species composition) can reduce 61% of the BVOCs emissions and 50% of the health damage related to BVOCs emissions by 2050. - Highlights: • Urban core is the hotspot of biogenic volatile organic compounds (BVOCs) emissions in the Greater Beijing Area. • Neglecting BVOCs emissions from urban green spaces leads to a 62% underestimation of the related health damage. • BVOCs contribute significantly to ozone pollution while make limited contribution to PM 2.5 pollution. • BVOCs emissions from urban green spaces will triple by 2050, and 61% of these emissions can be reduced through management. - Although BVOCs emissions from urban green spaces make limited contribution to regional emissions, their health impacts could be significant in urban areas.

  3. Evaluation of pollutant emissions in North China Plain using aircraft measurements from the Air Chemistry Research In Asia (ARIAs) campaign

    Science.gov (United States)

    He, H.; Ren, X.; Li, Z.; Dickerson, R. R.

    2017-12-01

    The North China Plain (NCP) is one of the most populated and polluted regions on Earth. With rapid economic development in past decades, air pollution including heavy atmospheric aerosol loadings became severe in this region, leading to environmental and climate problems. An aircraft campaign, Air Chemistry Research In Asia (ARIAs), was conducted in spring 2016 (in parallel to KORUS-AQ) to understand air quality in the NCP and transport of air pollutants from this area. Measurements of trace gases such as O3, CO, and SO2 and aerosol optical properties were analyzed to investigate the anthropogenic emissions in the NCP. Both high-efficiency combustion such as from automobiles and modern power plants as well as low-efficiency combustion such as from biomass burnings were identified. Transformations of primary pollutants and formation of secondary pollutants were simulated using the EPA CMAQ v5.2 model. The global HTAP-EDGAR v4.2 emission inventory of year 2010 was processed with SMOKE v4.5 to drive CMAQ. Modeling results were evaluated with aircraft observations to improve our knowledge of anthropogenic emissions and transport. We also used satellite observations including OMI SO2/NO2 and MODIS AOD to evaluate the model performance in the NCP. Through the comparison, we estimated the changes in emissions of major anthropogenic pollutants from 2010 to 2016. Sensitivity experiments with improved emission inventory were conducted to better investigate the air pollution in the NCP.

  4. Pesticide Active Ingredient Production Industry: National Emission Standards for Hazardous Air Pollutants (NESHAP)

    Science.gov (United States)

    This action promulgates national emission standards for hazardous air pollutants (NESHAP) for the pesticide active ingredient (PAI) production source category under section 112 of the Clean Air Act as amended (CAA or Act).

  5. 75 FR 37732 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

    Science.gov (United States)

    2010-06-30

    ... National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines... hazardous air pollutants for existing stationary compression ignition reciprocating internal combustion... combustion engines. 40 CFR 63.6590 was amended by revising paragraphs (b)(1) and (3). Inadvertently...

  6. 77 FR 37361 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

    Science.gov (United States)

    2012-06-21

    ... National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines; New Source Performance Standards for Stationary Internal Combustion Engines AGENCY: Environmental Protection... Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines; New Source Performance...

  7. Miscellaneous Coating Manufacturing: National Emission Standards for Hazardous Air Pollutants (NESHAP)

    Science.gov (United States)

    The national emission standards for hazardous air pollutants for miscellaneous coating manufacturing. Includes summary, rule history, compliance and implementation information, federal registry citations.

  8. Industrial Process Cooling Towers: National Emission Standards for Hazardous Air Pollutants

    Science.gov (United States)

    Standards limiting discharge of chromium compound air emissions from industrial process cooling towers (IPCT's). Includes rule history, Federal Registry citations, implementation information and additional resources.

  9. Reinforced Plastic Composites Production: National Emission Standards for Hazardous Air Pollutants

    Science.gov (United States)

    National emissions standards for hazardous air pollutants for reinforced plastic composites production facilities. Regulates production and ancillary processes used to manufacture products with thermoset resins and gel coats.

  10. Radionuclide air emissions report for the Hanford Site, calendar year 1992

    International Nuclear Information System (INIS)

    Diediker, L.P.; Johnson, A.R.; Rhoads, K.; Klages, D.L.; Soldat, J.K.; Rokkan, D.J.

    1993-06-01

    This report documents radionuclide air emissions from the Hanford Site in 1992 and the resulting effective dose equivalent to an member of the public. The report has been prepared and will be submitted in accordance with reporting requirements in the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, ''National Emissions Standards for Hazardous Air Pollutants,'' Subpart H, ''National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.''

  11. Effects of business-as-usual anthropogenic emissions on air quality

    Directory of Open Access Journals (Sweden)

    A. Pozzer

    2012-08-01

    Full Text Available The atmospheric chemistry general circulation model EMAC has been used to estimate the impact of anthropogenic emission changes on global and regional air quality in recent and future years (2005, 2010, 2025 and 2050. The emission scenario assumes that population and economic growth largely determine energy and food consumption and consequent pollution sources with the current technologies ("business as usual". This scenario is chosen to show the effects of not implementing legislation to prevent additional climate change and growing air pollution, other than what is in place for the base year 2005, representing a pessimistic (but plausible future.

    By comparing with recent observations, it is shown that the model reproduces the main features of regional air pollution distributions though with some imprecisions inherent to the coarse horizontal resolution (~100 km and simplified bottom-up emission input.

    To identify possible future hot spots of poor air quality, a multi pollutant index (MPI, suited for global model output, has been applied. It appears that East and South Asia and the Middle East represent such hotspots due to very high pollutant concentrations, while a general increase of MPIs is observed in all populated regions in the Northern Hemisphere. In East Asia a range of pollutant gases and fine particulate matter (PM2.5 is projected to reach very high levels from 2005 onward, while in South Asia air pollution, including ozone, will grow rapidly towards the middle of the century. Around the Persian Gulf, where natural PM2.5 concentrations are already high (desert dust, ozone levels are expected to increase strongly.

    The population weighted MPI (PW-MPI, which combines demographic and pollutant concentration projections, shows that a rapidly increasing number of people worldwide will experience reduced air quality during the first half of the 21st century. Following this business as usual

  12. Anisotropic effects of terahertz emission from laser sparks in air

    International Nuclear Information System (INIS)

    Zharova, N. A.; Mironov, V. A.; Fadeev, D. A.

    2010-01-01

    Strong terahertz (THz) radiation can be generated by intense femtosecond laser pulses propagating in air. The excitation of transient current induced in the wake just behind the laser pulse is studied in detail using numerical simulations on the basis of Maxwell's equations for THz-band fields and hydrodynamic model for the plasma motion. It is shown that the thermal effects, anisotropic in character in the case of linear polarized laser field, can explain observed quadrupole-type THz radiation pattern in the experiment performed by Akhmedzhanov et al. [Radiophys. Quantum Electron. 52, 482 (2009)]. Taking into account the transverse structure of the plasma filament, our numerical code enables us to calculate the spatial distribution and temporal evolution of terahertz electron current, its spectrum, and angular emission pattern. It is shown that an expansion of full fields in terms of azimuthal modes is a useful tool for research of THz generation in many situations of practical interest.

  13. Data Quality Objectives Supporting Radiological Air Emissions Monitoring for the PNNL Site

    Energy Technology Data Exchange (ETDEWEB)

    Barnett, J. Matthew; Meier, Kirsten M.; Snyder, Sandra F.; Fritz, Brad G.; Poston, Theodore M.; Antonio, Ernest J.

    2012-11-12

    Pacific Northwest National Laboratory (PNNL) is in the process of developing a radiological air monitoring program for the PNNL Site that is distinct from that of the nearby Hanford Site. The original DQO (PNNL-19427) considered radiological emissions at the PNNL Site from Physical Sciences Facility (PSF) major emissions units. This first revision considers PNNL Site changes subsequent to the implementation of the original DQO. A team was established to determine how the PNNL Site changes would continue to meet federal regulations and address guidelines developed to monitor air emissions and estimate offsite impacts of radioactive material operations. The result is an updated program to monitor the impact to the public from the PNNL Site. The team used the emission unit operation parameters and local meteorological data as well as information from the PSF Potential-to-Emit documentation and Notices of Construction submitted to the Washington State Department of Health (WDOH). The locations where environmental monitoring stations would most successfully characterize the maximum offsite impacts of PNNL Site emissions from the three PSF buildings with major emission units were determined from these data. Three monitoring station locations were determined during the original revision of this document. This first revision considers expanded Department of Energy operations south of the PNNL Site and relocation of the two offsite, northern monitoring stations to sites near the PNNL Site fenceline. Inclusion of the southern facilities resulted in the proposal for a fourth monitoring station in the southern region. The southern expansion added two minor emission unit facilities and one diffuse emission unit facility. Relocation of the two northern stations was possible due to the use of solar power, rather than the previous limitation of the need for access to AC power, at these more remote locations. Addendum A contains all the changes brought about by the revision 1

  14. Recent decreases in fossil-fuel emissions of ethane and methane derived from firn air.

    Science.gov (United States)

    Aydin, Murat; Verhulst, Kristal R; Saltzman, Eric S; Battle, Mark O; Montzka, Stephen A; Blake, Donald R; Tang, Qi; Prather, Michael J

    2011-08-10

    Methane and ethane are the most abundant hydrocarbons in the atmosphere and they affect both atmospheric chemistry and climate. Both gases are emitted from fossil fuels and biomass burning, whereas methane (CH(4)) alone has large sources from wetlands, agriculture, landfills and waste water. Here we use measurements in firn (perennial snowpack) air from Greenland and Antarctica to reconstruct the atmospheric variability of ethane (C(2)H(6)) during the twentieth century. Ethane levels rose from early in the century until the 1980s, when the trend reversed, with a period of decline over the next 20 years. We find that this variability was primarily driven by changes in ethane emissions from fossil fuels; these emissions peaked in the 1960s and 1970s at 14-16 teragrams per year (1 Tg = 10(12) g) and dropped to 8-10 Tg  yr(-1) by the turn of the century. The reduction in fossil-fuel sources is probably related to changes in light hydrocarbon emissions associated with petroleum production and use. The ethane-based fossil-fuel emission history is strikingly different from bottom-up estimates of methane emissions from fossil-fuel use, and implies that the fossil-fuel source of methane started to decline in the 1980s and probably caused the late twentieth century slow-down in the growth rate of atmospheric methane.

  15. Using Satellite Remote Sensing and Modelling for Insights into N02 Air Pollution and NO2 Emissions

    Science.gov (United States)

    Lamsal, L. N.; Martin, R. V.; Krotkov, N. A.; Bucsela, E. J.; Celarier, E. A.; vanDonkelaar, A.; Parrish, D.

    2012-01-01

    Nitrogen oxides (NO(x)) are key actors in air quality and climate change. Satellite remote sensing of tropospheric NO2 has developed rapidly with enhanced spatial and temporal resolution since initial observations in 1995. We have developed an improved algorithm and retrieved tropospheric NO2 columns from Ozone Monitoring Instrument. Column observations of tropospheric NO2 from the nadir-viewing satellite sensors contain large contributions from the boundary layer due to strong enhancement of NO2 in the boundary layer. We infer ground-level NO2 concentrations from the OMI satellite instrument which demonstrate significant agreement with in-situ surface measurements. We examine how NO2 columns measured by satellite, ground-level NO2 derived from satellite, and NO(x) emissions obtained from bottom-up inventories relate to world's urban population. We perform inverse modeling analysis of NO2 measurements from OMI to estimate "top-down" surface NO(x) emissions, which are used to evaluate and improve "bottom-up" emission inventories. We use NO2 column observations from OMI and the relationship between NO2 columns and NO(x) emissions from a GEOS-Chem model simulation to estimate the annual change in bottom-up NO(x) emissions. The emission updates offer an improved estimate of NO(x) that are critical to our understanding of air quality, acid deposition, and climate change.

  16. Uncertainty estimation and risk prediction in air quality

    International Nuclear Information System (INIS)

    Garaud, Damien

    2011-01-01

    This work is about uncertainty estimation and risk prediction in air quality. Firstly, we build a multi-model ensemble of air quality simulations which can take into account all uncertainty sources related to air quality modeling. Ensembles of photochemical simulations at continental and regional scales are automatically generated. Then, these ensemble are calibrated with a combinatorial optimization method. It selects a sub-ensemble which is representative of uncertainty or shows good resolution and reliability for probabilistic forecasting. This work shows that it is possible to estimate and forecast uncertainty fields related to ozone and nitrogen dioxide concentrations or to improve the reliability of threshold exceedance predictions. The approach is compared with Monte Carlo simulations, calibrated or not. The Monte Carlo approach appears to be less representative of the uncertainties than the multi-model approach. Finally, we quantify the observational error, the representativeness error and the modeling errors. The work is applied to the impact of thermal power plants, in order to quantify the uncertainty on the impact estimates. (author) [fr

  17. Energy and air emission implications of a decentralized wastewater system

    International Nuclear Information System (INIS)

    Shehabi, Arman; Stokes, Jennifer R; Horvath, Arpad

    2012-01-01

    Both centralized and decentralized wastewater systems have distinct engineering, financial and societal benefits. This paper presents a framework for analyzing the environmental effects of decentralized wastewater systems and an evaluation of the environmental impacts associated with two currently operating systems in California, one centralized and one decentralized. A comparison of energy use, greenhouse gas emissions and criteria air pollutants from the systems shows that the scale economies of the centralized plant help lower the environmental burden to less than a fifth of that of the decentralized utility for the same volume treated. The energy and emission burdens of the decentralized plant are reduced when accounting for high-yield wastewater reuse if it supplants an energy-intensive water supply like a desalination one. The centralized facility also reduces greenhouse gases by flaring methane generated during the treatment process, while methane is directly emitted from the decentralized system. The results are compelling enough to indicate that the life-cycle environmental impacts of decentralized designs should be carefully evaluated as part of the design process. (letter)

  18. Evaluation of Traffic Density Parameters as an Indicator of Vehicle Emission-Related Near-Road Air Pollution: A Case Study with NEXUS Measurement Data on Black Carbon

    Science.gov (United States)

    An important factor in evaluating health risk of near-road air pollution is to accurately estimate the traffic-related vehicle emission of air pollutants. Inclusion of traffic parameters such as road length/area, distance to roads, and traffic volume/intensity into models such as...

  19. Estimation of the emission polluting agents by Motorcycles in the Aburra Valley

    International Nuclear Information System (INIS)

    Giraldo Aristizabal, William Alonso; Toro Gomez, Maria Victoria

    2008-01-01

    The motorcycle is considered a generating movable polluting gas source like the volatile organic compounds and the carbon monoxide that are released to the atmosphere. In Colombia they have registered in the last years a high increase in the use of this type of vehicles having increased therefore the emissions, which has contributed with the deterioration of the quality of the air of the Valley of Aburra. In the other hand environmental regulation is recent and has not applied rigorously yet. Consequently and having like reference international Literature and the measurements in slow motion or minimum march, made by the Metropolitan Area, between January and March of 2006, factors of emission for carbon monoxide and hydrocarbons for the estimation of the impact in the city.

  20. A multitower measurement network estimate of California's methane emissions

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Seongeun [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division; Hsu, Ying-Kuang [California Air Resources Board, Sacramento, CA (United States); Andrews, Arlyn E. [National Oceanic and Atmospheric Administration (NOAA), Boulder, CO (United States). Earth System Research Lab.; Bianco, Laura [National Oceanic and Atmospheric Administration (NOAA), Boulder, CO (United States). Earth System Research Lab.; Univ. of Colorado, Boulder, CO (United States). Cooperative Inst. for Research in Environmental Sciences; Vaca, Patrick [California Air Resources Board, Sacramento, CA (United States); Wilczak, James M. [National Oceanic and Atmospheric Administration (NOAA), Boulder, CO (United States). Earth System Research Lab.; Fischer, Marc L. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division; California State Univ. (CalState East Bay), Hayward, CA (United States). Dept. of Anthropology, Geography and Environmental Studies

    2013-09-20

    In this paper, we present an analysis of methane (CH4) emissions using atmospheric observations from five sites in California's Central Valley across different seasons (September 2010 to June 2011). CH4 emissions for spatial regions and source sectors are estimated by comparing measured CH4 mixing ratios with transport model (Weather Research and Forecasting and Stochastic Time-Inverted Lagrangian Transport) predictions based on two 0.1° CH4 (seasonally varying “California-specific” (California Greenhouse Gas Emission Measurements, CALGEM) and a static global (Emission Database for Global Atmospheric Research, release version 42, EDGAR42)) prior emission models. Region-specific Bayesian analyses indicate that for California's Central Valley, the CALGEM- and EDGAR42-based inversions provide consistent annual total CH4 emissions (32.87 ± 2.09 versus 31.60 ± 2.17 Tg CO2eq yr-1; 68% confidence interval (CI), assuming uncorrelated errors between regions). Summing across all regions of California, optimized CH4 emissions are only marginally consistent between CALGEM- and EDGAR42-based inversions (48.35 ± 6.47 versus 64.97 ± 11.85 Tg CO2eq), because emissions from coastal urban regions (where landfill and natural gas emissions are much higher in EDGAR than CALGEM) are not strongly constrained by the measurements. Combining our results with those from a recent study of the South Coast Air Basin narrows the range of estimates to 43–57 Tg CO2eq yr-1 (1.3–1.8 times higher than the current state inventory). Finally, these results suggest that the combination of rural and urban measurements will be necessary to verify future changes in California's total CH4 emissions.

  1. Protocols of radiocontaminant air monitoring for inhalation exposure estimates

    International Nuclear Information System (INIS)

    Shinn, J.H.

    1995-09-01

    Monitoring the plutonium and americium particle emissions from soils contaminated during atmospheric nuclear testing or due to accidental releases is important for several reasons. First, it is important to quantify the extent of potential human exposure from inhalation of alpha-emitting particles, which is the major exposure pathway from transuranic radionuclides. Second, the information provided by resuspension monitoring is the basis of criteria that determine the target soil concentrations for management and cleanup of contaminated soil sites. There are other radioactive aerosols, such as the fission products (cesium and strontium) and neutron-activation products (europium isotopes), which may be resuspended and therefore necessary to monitor as well. This Standard Protocol (SP) provides the method used for radiocontaminant air monitoring by the Health and Ecological Assessment Division (formerly Environmental Sciences Division), Lawrence Livermore National Laboratory, as developed and tested at Nevada Test Site (NTS) and in the Marshall Islands. The objective of this SP is to document the applications and methods of monitoring of all the relevant variables. This protocol deals only with measuring air concentrations of radionuclides and total suspended particulates (TSP, or open-quotes dustclose quotes). A separate protocol presents the more difficult measurements required to determine transuranic aerosol emission rates, or open-quotes resuspension rateclose quotes

  2. National Emission Standards for Hazardous Air Pollutants - Radionuclide Emissions, Calendar Year 2011

    International Nuclear Information System (INIS)

    2012-01-01

    The U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office operates the Nevada National Security Site (NNSS) and North Las Vegas Facility (NLVF). From 1951 through 1992, the NNSS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NNSS activities has been monitored since the initiation of atmospheric testing. Limitation to underground detonations after 1962 greatly reduced radiation exposure to the public surrounding the NNSS. After nuclear testing ended in 1992, NNSS radiation monitoring focused on detecting airborne radionuclides from historically contaminated soils. These radionuclides are derived from re-suspension of soil (primarily by wind) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of legacy-related tritium are also emitted to air at the NLVF, an NNSS support complex in North Las Vegas. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations (CFR) Part 61 Subpart H) limits the release of radioactivity from a U.S. Department of Energy (DOE) facility to that which would cause 10 millirem per year (mrem/yr) effective dose equivalent to any member of the public. This limit does not include radiation unrelated to NNSS activities. Unrelated doses could come from naturally occurring radioactive elements, from sources such as medically or commercially used radionuclides, or from sources outside of the United States, such as the damaged Fukushima nuclear power plant in Japan. Radionuclides from the Fukushima nuclear power plant were detected at the NNSS in March 2011 and are discussed further in Section III. The NNSS demonstrates compliance with the NESHAP limit by using environmental measurements of radionuclide air concentrations at critical receptor locations. This method was approved by the EPA for use on the

  3. National Emission Standards for Hazardous Air Pollutants - Radionuclide Emissions Calendar Year 2012

    Energy Technology Data Exchange (ETDEWEB)

    Warren, R.

    2013-06-10

    The U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office (NNSA/NFO) operates the Nevada National Security Site (NNSS) and North Las Vegas Facility (NLVF). From 1951 through 1992, the NNSS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NNSS activities has been monitored since the initiation of atmospheric testing. Limitation to underground detonations after 1962 greatly reduced radiation exposure to the public surrounding the NNSS. After nuclear testing ended in 1992, NNSS radiation monitoring focused on detecting airborne radionuclides from historically contaminated soils. These radionuclides are derived from re-suspension of soil (primarily by wind) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of legacy-related tritium are also emitted to air at the NLVF, an NNSS support complex in North Las Vegas. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations [CFR] Part 61 Subpart H) (CFR 2010a) limits the release of radioactivity from a U.S. Department of Energy (DOE) facility to that which would cause 10 millirem per year (mrem/yr) effective dose equivalent to any member of the public. This limit does not include radiation unrelated to NNSS activities. Unrelated doses could come from naturally occurring radioactive elements, from sources such as medically or commercially used radionuclides, or from sources outside of the United States, such as the damaged Fukushima nuclear power plant in Japan in 2011. NNSA/NFO demonstrates compliance with the NESHAP limit by using environmental measurements of radionuclide air concentrations at critical receptor locations on the NNSS (U.S. Environmental Protection Agency [EPA] and DOE 1995). This method was approved by the EPA for use on the NNSS in 2001 (EPA 2001a) and has

  4. National Emission Standards for Hazardous Air Pollutants - Radionuclide Emissions Calendar Year 2013

    Energy Technology Data Exchange (ETDEWEB)

    Warren, R.

    2014-06-04

    The U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office (NNSA/NFO) operates the Nevada National Security Site (NNSS) and North Las Vegas Facility (NLVF). From 1951 through 1992, the NNSS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NNSS activities has been monitored since the initiation of atmospheric testing. Limitations to underground detonations after 1962 greatly reduced radiation exposure to the public surrounding the NNSS. After nuclear testing ended in 1992, NNSS radiation monitoring focused on detecting airborne radionuclides from historically contaminated soils. These radionuclides are derived from re-suspension of soil (primarily by wind) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of legacy-related tritium are also emitted to air at the NLVF, an NNSS support complex in North Las Vegas. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations [CFR] Part 61 Subpart H) (CFR 2010a) limits the release of radioactivity from a U.S. Department of Energy (DOE) facility to that which would cause 10 millirem per year (mrem/yr) effective dose equivalent to any member of the public. This limit does not include radiation unrelated to NNSS activities. Unrelated doses could come from naturally occurring radioactive elements, from sources such as medically or commercially used radionuclides, or from sources outside of the United States, such as the damaged Fukushima nuclear power plant in Japan in 2011. NNSA/NFO demonstrates compliance with the NESHAP limit by using environmental measurements of radionuclide air concentrations at critical receptor locations on the NNSS (U.S. Environmental Protection Agency [EPA] and DOE 1995). This method was approved by the EPA for use on the NNSS in 2001 (EPA 2001a) and has

  5. Air quality and health effects of biogenic volatile organic compounds emissions from urban green spaces and the mitigation strategies.

    Science.gov (United States)

    Ren, Yuan; Qu, Zelong; Du, Yuanyuan; Xu, Ronghua; Ma, Danping; Yang, Guofu; Shi, Yan; Fan, Xing; Tani, Akira; Guo, Peipei; Ge, Ying; Chang, Jie

    2017-11-01

    Biogenic volatile organic compounds (BVOCs) emissions lead to fine particulate matter (PM 2.5 ) and ground-level ozone pollution, and are harmful to human health, especially in urban areas. However, most BVOCs estimations ignored the emissions from urban green spaces, causing inaccuracies in the understanding of regional BVOCs emissions and their environmental and health effects. In this study, we used the latest local vegetation datasets from our field survey and applied an estimation model to analyze the spatial-temporal patterns, air quality impacts, health damage and mitigating strategies of BVOCs emissions in the Greater Beijing Area. Results showed that: (1) the urban core was the hotspot of regional BVOCs emissions for the highest region-based emission intensity (3.0 g C m -2 yr -1 ) among the 11 sub-regions; (2) urban green spaces played much more important roles (account for 62% of total health damage) than rural forests in threating human health; (3) BVOCs emissions from green spaces will more than triple by 2050 due to urban area expansion, tree growth and environmental changes; and (4) adopting proactive management (e.g. adjusting tree species composition) can reduce 61% of the BVOCs emissions and 50% of the health damage related to BVOCs emissions by 2050. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. Emission estimates of HCFCs and HFCs in California from the 2010 CalNex study

    Science.gov (United States)

    Barletta, Barbara; Carreras-Sospedra, Marc; Cohan, Alex; Nissenson, Paul; Dabdub, Donald; Meinardi, Simone; Atlas, Elliot; Lueb, Rich; Holloway, John S.; Ryerson, Thomas B.; Pederson, James; VanCuren, Richard A.; Blake, Donald R.

    2013-02-01

    The CalNex 2010 (California Research at the Nexus of Air Quality and Climate Change) study was designed to evaluate the chemical composition of air masses over key source regions in California. During May to June 2010, air samples were collected on board a National Oceanic and Atmospheric Administration (NOAA) WP-3D aircraft over the South Coast Air Basin of California (SoCAB) and the Central Valley (CV). This paper analyzes six effective greenhouse gases—chlorodifluoromethane (HCFC-22), 1,1-dichloro-1-fluoroethane (HCFC-141b), 1-chloro-1,1-difluoroethane (HCFC-142b), 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124), 1,1,1,2-tetrafluoroethane (HFC-134a), and 1,1-difluoroethane (HFC-152a)—providing the most comprehensive characterization of chlorofluorocarbon (CFC) replacement compound emissions in California. Concentrations of measured HCFCs and HFCs are enhanced greatly throughout the SoCAB and CV, with highest levels observed in the SoCAB: 310 ± 92 pptv for HCFC-22, 30.7 ± 18.6 pptv for HCFC-141b, 22.9 ± 2.0 pptv for HCFC-142b, 4.86 ± 2.56 pptv for HCFC-124, 109 ± 46.4 pptv for HFC-134a, and 91.2 ± 63.9 pptv for HFC-152a. Annual emission rates are estimated for all six compounds in the SoCAB using the measured halocarbon to carbon monoxide (CO) mixing ratios and CO emissions inventories. Emission rates of 3.05 ± 0.70 Gg for HCFC-22, 0.27 ± 0.07 Gg for HCFC-141b, 0.06 ± 0.01 Gg for HCFC-142b, 0.11 ± 0.03 Gg for HCFC-124, 1.89 ± 0.43 Gg for HFC-134a, and 1.94 ± 0.45 Gg for HFC-152b for the year 2010 are calculated for the SoCAB. These emissions are extrapolated from the SoCAB region to the state of California using population data. Results from this study provide a baseline emission rate that will help future studies determine if HCFC and HFC mitigation strategies are successful.

  7. Measurement error in mobile source air pollution exposure estimates due to residential mobility during pregnancy.

    Science.gov (United States)

    Pennington, Audrey Flak; Strickland, Matthew J; Klein, Mitchel; Zhai, Xinxin; Russell, Armistead G; Hansen, Craig; Darrow, Lyndsey A

    2017-09-01

    Prenatal air pollution exposure is frequently estimated using maternal residential location at the time of delivery as a proxy for residence during pregnancy. We describe residential mobility during pregnancy among 19,951 children from the Kaiser Air Pollution and Pediatric Asthma Study, quantify measurement error in spatially resolved estimates of prenatal exposure to mobile source fine particulate matter (PM 2.5 ) due to ignoring this mobility, and simulate the impact of this error on estimates of epidemiologic associations. Two exposure estimates were compared, one calculated using complete residential histories during pregnancy (weighted average based on time spent at each address) and the second calculated using only residence at birth. Estimates were computed using annual averages of primary PM 2.5 from traffic emissions modeled using a Research LINE-source dispersion model for near-surface releases (RLINE) at 250 m resolution. In this cohort, 18.6% of children were born to mothers who moved at least once during pregnancy. Mobile source PM 2.5 exposure estimates calculated using complete residential histories during pregnancy and only residence at birth were highly correlated (r S >0.9). Simulations indicated that ignoring residential mobility resulted in modest bias of epidemiologic associations toward the null, but varied by maternal characteristics and prenatal exposure windows of interest (ranging from -2% to -10% bias).

  8. Emissions of biogenic VOC from forest ecosystems in central Europe: Estimation and comparison with anthropogenic emission inventory

    International Nuclear Information System (INIS)

    Zemankova, Katerina; Brechler, Josef

    2010-01-01

    This paper describes a method of estimating emission fluxes of biogenic volatile organic compounds (BVOCs) based on the approach proposed by and the high-resolution Corine land-cover 2000 database (1 x 1 km resolution). The computed emission fluxes for the Czech Republic (selected for analysis as being representative of a heavily cultivated, central European country) are compared with anthropogenic emissions, both for the entire country and for individual administrative regions. In some regions, BVOC emissions are as high as anthropogenic emissions; however, in most regions the BVOC emissions are approximately 50% of the anthropogenic emissions. The yearly course of BVOC emissions (represented by monoterpenes and isoprene) is presented, along with the spatial distribution of annual mean values. Differences in emission distributions during winter (January) and summer (June) are also considered. - The amount of the biogenic VOCs emitted over the central Europe is comparable with the anthropogenic VOC emissions from this region.

  9. Air emission points for facilities in Iowa with operating permits for Title V of the Federal Clean Air Act_considered MAJOR permits

    Data.gov (United States)

    Iowa State University GIS Support and Research Facility — Air emission points for facilities in Iowa with operating permits for Title V of the Federal Clean Air Act, considered "major" permits. Also includes emission points...

  10. National Emission Standards for Hazardous Air Pollutants - Radionuclide Emissions Calendar Year 2009

    International Nuclear Information System (INIS)

    2010-01-01

    The U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office operates the Nevada Test Site (NTS) and North Las Vegas Facility (NLVF). From 1951 through 1992, the NTS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NTS activities has been monitored since the initiation of atmospheric testing. Limitation to underground detonations after 1962 greatly reduced radiation exposure to the public surrounding the NTS. After nuclear testing ended in 1992, NTS radiation monitoring focused on detecting airborne radionuclides from historically contaminated soils. These radionuclides are derived from re-suspension of soil (primarily by wind) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of tritium were also emitted to air at the NLVF, an NTS support complex in North Las Vegas. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations (CFR) Part 61 Subpart H) limits the release of radioactivity from a U.S. Department of Energy facility to 10 millirem per year (mrem/yr) effective dose equivalent to any member of the public. This limit does not include radiation not related to NTS activities. Unrelated doses could come from naturally occurring radioactive elements or from sources such as medically or commercially used radionuclides. The NTS demonstrates compliance with the NESHAP limit by using environmental measurements of radionuclide air concentrations at critical receptor locations. This method was approved by the U.S. Environmental Protection Agency for use on the NTS in 2001 and has been the sole method used since 2005. Six locations on the NTS have been established to act as critical receptor locations to demonstrate compliance with the NESHAP limit. These locations are actually pseudo-critical receptor stations, because no

  11. 75 FR 28227 - National Emission Standards for Hazardous Air Pollutants: Gold Mine Ore Processing and Production...

    Science.gov (United States)

    2010-05-20

    ...-AP48 National Emission Standards for Hazardous Air Pollutants: Gold Mine Ore Processing and Production... published a proposed rule for mercury emissions from the gold mine ore processing and production area source... Environmental protection, Air pollution control, Hazardous substances, Incorporations by reference, Reporting...

  12. HVAC SYSTEMS AS EMISSION SOURCES AFFECTING INDOOR AIR QUALITY: A CRITICAL REVIEW

    Science.gov (United States)

    The paper discusses results of an evaluation of literature on heating, ventilating, and air-conditioning (HVAC) systems as contaminant emission sources that affect indoor air quality (IAQ). The various literature sources and methods for characterizing HVAC emission sources are re...

  13. 76 FR 12863 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

    Science.gov (United States)

    2011-03-09

    ... National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines... combustion engines. The final rule was published on August 20, 2010. This direct final action amends certain... Emission Standards for Hazardous Air Pollutant for Stationary Reciprocating Internal Combustion Engines...

  14. Are changing emission patterns across the Northern Hemisphere influencing long-range transport contributions to background air pollution?

    Science.gov (United States)

    Mathur, R.; Kang, D.; Napelenok, S. L.; Xing, J.; Hogrefe, C.

    2017-12-01

    Air pollution reduction strategies for a region are complicated not only by the interplay of local emissions sources and several complex physical, chemical, dynamical processes in the atmosphere, but also hemispheric background levels of pollutants. Contrasting changes in emission patterns across the globe (e.g. declining emissions in North America and Western Europe in response to implementation of control measures and increasing emissions across Asia due to economic and population growth) are resulting in heterogeneous changes in the tropospheric chemical composition and are likely altering long-range transport impacts and consequently background pollution levels at receptor regions. To quantify these impacts, the WRF-CMAQ model is expanded to hemispheric scales and multi-decadal model simulations are performed for the period spanning 1990-2010 to examine changes in hemispheric air pollution resulting from changes in emissions over this period. Simulated trends in ozone and precursor species concentrations across the U.S. and the Northern Hemisphere over the past two decades are compared with those inferred from available measurements during this period. Additionally, the decoupled direct method (DDM) in CMAQ, a first- and higher-order sensitivity calculation technique, is used to estimate the sensitivity of O3 to emissions from different source regions across the Northern Hemisphere. The seasonal variations in source region contributions to background O3 are then estimated from these sensitivity calculations and will be discussed. These source region sensitivities estimated from DDM are then combined with the multi-decadal simulations of O3 distributions and emissions trends to characterize the changing contributions of different source regions to background O3 levels across North America. This characterization of changing long-range transport contributions is critical for the design and implementation of tighter national air quality standards

  15. Estimating the biogenic emissions of non-methane volatile organic compounds from the North Western Mediterranean vegetation of Catalonia, Spain

    International Nuclear Information System (INIS)

    Parra, R.; Gasso, S.; Baldasano, J.M.

    2004-01-01

    An estimation of the magnitude of non-methane volatile organic compounds (NMVOCs) emitted by vegetation in Catalonia (NE of the Iberian Peninsula, Spain), in addition to their superficial and temporal distribution, is presented for policy and scientific (photochemical modelling) purposes. It was developed for the year 2000, for different time resolutions (hourly, daily, monthly and annual) and using a high-resolution land-use map (1-km 2 squared cells). Several meteorological surface stations provided air temperature and solar radiation data. An adjusted mathematical emission model taking account of Catalonia's conditions was built into a geographic information system (GIS) software. This estimation uses the latest information, mainly relating to: (1) emission factors; (2) better knowledge of the composition of Catalonia's forest cover; and (3) better knowledge of the particular emission behaviour of some Mediterranean vegetal species. Results depict an annual cycle with increasing values in the March-April period with the highest emissions in July-August, followed by a decrease in October-November. Annual biogenic NMVOCs emissions reach 46.9 kt, with monoterpenes the most abundant species (24.7 kt), followed by other biogenic volatile organic compounds (e.g. alcohols, aldehydes and acetone) (16.3 kt), and isoprene (5.9 kt). These compounds signify 52%, 35% and 13%, respectively, of total emission estimates. Peak hourly total emission for a winter day could be less than 10% of the corresponding value for a summer day

  16. National inventories of air emissions in France: organisation and methodology - 8. edition - OMINEA, February 2011

    International Nuclear Information System (INIS)

    Fontelle, Jean-Pierre; Allemand, Nadine; Andre, Jean-Marc; Bastide, Aurelie; Chang, Jean-Pierre; Deflorenne, Emmanuel; Druart, Ariane; Gavel, Antoine; Gueguen, Celine; Jabot, Julien; Jacquier, Guillaume; Joya, Romain; Kessouar, Sabrina; Martinet, Yann; Mathias, Etienne; Nicco, Laetitia; Prouteau, Emilie; Serveau, Laetitia; Tuddenham, Mark; Vincent, Julien

    2011-01-01

    Usually, various methods are used to estimate emissions of atmospheric pollutants from anthropogenic or natural sources. These methods which are more or less specific, require large quantities of data to carry out what is commonly named 'emission inventories', 'cadastres' or 'registers' depending on characteristics of the collection in terms of spatial and sectoral resolution. The OMINEA report includes a description of the national inventory system of pollutant emissions into the atmosphere (SNIEPA) which deals with the following topics: organisation, break down of responsibilities and coverage. Technical operational arrangements are described and various elements relating to reference documents and definitions, control and quality assurance, estimation of uncertainties are provided. A description is given for each emitting source category and for several substances classified in the following topics: 'greenhouse gases', 'acidification and photochemical pollution', 'eutrophication', 'heavy metals', 'persistent organic pollutants', 'particulate matter', 'other'. The plan is based on the international reporting format defined by the United Nations within the framework of conventions on climate change and long range transboundary air pollution (sources categories listed in CRFI/NFR)

  17. National inventories of air emissions in France: organisation and methodology - 9. edition - OMINEA, February 2011

    International Nuclear Information System (INIS)

    Fontelle, Jean-Pierre; Andre, Jean-Marc; Bastide, Aurelie; Bort, Romain; Chang, Jean-Pierre; Deflorenne, Emmanuel; Druart, Ariane; Gavel, Antoine; Gueguen, Celine; Jabot, Julien; Jacquier, Guillaume; Jeannot, Coralie; Joya, Romain; Kessouar, Sabrina; Martinet, Yann; Mathias, Etienne; Nicco, Laetitia; Serveau, Laetitia; Tuddenham, Mark; Vasudeva, Divya; Vincent, Julien

    2012-01-01

    Usually, various methods are used to estimate emissions of atmospheric pollutants from anthropogenic or natural sources. These methods which are more or less specific, require large quantities of data to carry out what is commonly named 'emission inventories', 'cadastres' or 'registers' depending on characteristics of the collection in terms of spatial and sectoral resolution. The OMINEA report includes a description of the national inventory system of pollutant emissions into the atmosphere (SNIEPA) which deals with the following topics: organisation, break down of responsibilities and coverage. Technical operational arrangements are described and various elements relating to reference documents and definitions, control and quality assurance, estimation of uncertainties are provided. A description is given for each emitting source category and for several substances classified in the following topics: 'greenhouse gases', 'acidification and photochemical pollution', 'eutrophication', 'heavy metals', 'persistent organic pollutants', 'particulate matter', 'other'. The plan is based on the international reporting format defined by the United Nations within the framework of conventions on climate change and long range transboundary air pollution (sources categories listed in CRFI/NFR)

  18. Estimation of landfill emission lifespan using process oriented modeling

    International Nuclear Information System (INIS)

    Ustohalova, Veronika; Ricken, Tim; Widmann, Renatus

    2006-01-01

    Depending on the particular pollutants emitted, landfills may require service activities lasting from hundreds to thousands of years. Flexible tools allowing long-term predictions of emissions are of key importance to determine the nature and expected duration of maintenance and post-closure activities. A highly capable option represents predictions based on models and verified by experiments that are fast, flexible and allow for the comparison of various possible operation scenarios in order to find the most appropriate one. The intention of the presented work was to develop a experimentally verified multi-dimensional predictive model capable of quantifying and estimating processes taking place in landfill sites where coupled process description allows precise time and space resolution. This constitutive 2-dimensional model is based on the macromechanical theory of porous media (TPM) for a saturated thermo-elastic porous body. The model was used to simulate simultaneously occurring processes: organic phase transition, gas emissions, heat transport, and settlement behavior on a long time scale for municipal solid waste deposited in a landfill. The relationships between the properties (composition, pore structure) of a landfill and the conversion and multi-phase transport phenomena inside it were experimentally determined. In this paper, we present both the theoretical background of the model and the results of the simulations at one single point as well as in a vertical landfill cross section

  19. Quantification of emissions from domestic heating in residential areas of İzmir, Turkey and assessment of the impact on local/regional air-quality

    Energy Technology Data Exchange (ETDEWEB)

    Sari, Deniz, E-mail: deniz.sari@tubitak.gov.tr [TUBITAK Marmara Research Center, Environment and Cleaner Production Institute, 41470 Kocaeli (Turkey); Bayram, Abdurrahman [Department of Environmental Engineering, Faculty of Engineering, Dokuz Eylul University, Kaynaklar Campus, 35160 Buca, Izmir (Turkey)

    2014-08-01

    Air pollution in cities is a major environmental problem principally in the developing countries. The quantification of emissions is a basic requirement to assess the human influence to the atmosphere. The air quality generally shows decreases with the major contribution residential emissions and meteorology in the winter season in the big cities. Poor meteorological conditions especially inversion events for the efficient mixing of air pollutants occurred during the winter months in İzmir. With this work we quantify the amount of domestic heating emissions for particulate matter (PM10), sulfur dioxides (SO{sub 2}), nitrogen dioxides (NO{sub 2}), volatile organic compounds (VOC) and carbon monoxide (CO) together with greenhouse gases which are carbon dioxide (CO{sub 2}), nitrous oxide (N{sub 2}O) and methane (CH{sub 4}) in İzmir for 2008–2009 winter season. The results showed that the most affected residential areas were central districts in the city center from domestic heating emissions due to meteorological condition and demographic reasons. Air quality modeling is a great tool for assisting policy makers how to decrease emissions and improve air quality. At the second part of the study, calculated emissions were modeled by using CALMET/CALPUFF dispersion modeling system and plotted in the form of air pollution maps by using geographical information system to determine the locations and estimate the effects of the new residential areas that will be established in the future in İzmir. - Highlights: • The air pollution in cities especially shows raises with the opening of winter season. • Air pollution has become a problem due to rapid urbanization in İzmir, Turkey. • The air quality shows decreases with the residential emissions in İzmir's winter. • With this work we quantify the amount of domestic heating emissions for pollutants. • The impact of emissions on local air-quality is determined by using dispersion model.

  20. Quantification of emissions from domestic heating in residential areas of İzmir, Turkey and assessment of the impact on local/regional air-quality

    International Nuclear Information System (INIS)

    Sari, Deniz; Bayram, Abdurrahman

    2014-01-01

    Air pollution in cities is a major environmental problem principally in the developing countries. The quantification of emissions is a basic requirement to assess the human influence to the atmosphere. The air quality generally shows decreases with the major contribution residential emissions and meteorology in the winter season in the big cities. Poor meteorological conditions especially inversion events for the efficient mixing of air pollutants occurred during the winter months in İzmir. With this work we quantify the amount of domestic heating emissions for particulate matter (PM10), sulfur dioxides (SO 2 ), nitrogen dioxides (NO 2 ), volatile organic compounds (VOC) and carbon monoxide (CO) together with greenhouse gases which are carbon dioxide (CO 2 ), nitrous oxide (N 2 O) and methane (CH 4 ) in İzmir for 2008–2009 winter season. The results showed that the most affected residential areas were central districts in the city center from domestic heating emissions due to meteorological condition and demographic reasons. Air quality modeling is a great tool for assisting policy makers how to decrease emissions and improve air quality. At the second part of the study, calculated emissions were modeled by using CALMET/CALPUFF dispersion modeling system and plotted in the form of air pollution maps by using geographical information system to determine the locations and estimate the effects of the new residential areas that will be established in the future in İzmir. - Highlights: • The air pollution in cities especially shows raises with the opening of winter season. • Air pollution has become a problem due to rapid urbanization in İzmir, Turkey. • The air quality shows decreases with the residential emissions in İzmir's winter. • With this work we quantify the amount of domestic heating emissions for pollutants. • The impact of emissions on local air-quality is determined by using dispersion model

  1. Net radiative forcing and air quality responses to regional CO emission reductions

    Directory of Open Access Journals (Sweden)

    M. M. Fry

    2013-05-01

    Full Text Available Carbon monoxide (CO emissions influence global and regional air quality and global climate change by affecting atmospheric oxidants and secondary species. We simulate the influence of halving anthropogenic CO emissions globally and individually from 10 regions on surface and tropospheric ozone, methane, and aerosol concentrations using a global chemical transport model (MOZART-4 for the year 2005. Net radiative forcing (RF is then estimated using the GFDL (Geophysical Fluid Dynamics Laboratory standalone radiative transfer model. We estimate that halving global CO emissions decreases global annual average concentrations of surface ozone by 0.45 ppbv, tropospheric methane by 73 ppbv, and global annual net RF by 36.1 mW m−2, nearly equal to the sum of changes from the 10 regional reductions. Global annual net RF per unit change in emissions and the 100 yr global warming potential (GWP100 are estimated as −0.124 mW m−2 (Tg CO−1 and 1.34, respectively, for the global CO reduction, and ranging from −0.115 to −0.131 mW m−2 (Tg CO−1 and 1.26 to 1.44 across 10 regions, with the greatest sensitivities for regions in the tropics. The net RF distributions show widespread cooling corresponding to the O3 and CH4 decreases, and localized positive and negative net RFs due to changes in aerosols. The strongest annual net RF impacts occur within the tropics (28° S–28° N followed by the northern midlatitudes (28° N–60° N, independent of reduction region, while the greatest changes in surface CO and ozone concentrations occur within the reduction region. Some regional reductions strongly influence the air quality in other regions, such as East Asia, which has an impact on US surface ozone that is 93% of that from North America. Changes in the transport of CO and downwind ozone production clearly exceed the direct export of ozone from each reduction region. The small variation in CO GWPs among world regions suggests that future international

  2. Nevada Test Site National Emission Standards for Hazardous Air Pollutants - Radionuclide Emissions Calendar Year 2008

    International Nuclear Information System (INIS)

    Warren, Ronald; Grossman, Robert F.

    2009-01-01

    The Nevada Test Site (NTS) is operated by the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office. From 1951 through 1992, the NTS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NTS activities has been monitored since the initiation of atmospheric testing. Limitation to under-ground detonations after 1962 greatly reduced radiation exposure to the public surrounding the NTS. After nuclear testing ended in 1992, NTS radiation monitoring focused on detecting airborne radionuclides from historically contaminated soils. These radionuclides are derived from re-suspension of soil (primarily by winds) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of tritium were also emitted to air at the North Las Vegas Facility (NLVF), an NTS support complex in the city of North Las Vegas. To protect the public from harmful levels of man-made radiation, the Clean Air Act, National Emission Standards for Hazardous Air Pollutants (NESHAP) (Title 40 Code of Federal Regulations (CFR) Part 61 Subpart H) (CFR, 2008a) limits the release of radioactivity from a U.S. Department of Energy facility (e.g., the NTS) to 10 millirem per year (mrem/yr) effective dose equivalent to any member of the public. This limit does not include radiation not related to NTS activities. Unrelated doses could come from naturally occurring radioactive elements or from other man-made sources such as medical treatments. The NTS demonstrates compliance with the NESHAP limit by using environmental measurements of radionuclide air concentrations at critical receptor locations. This method was approved by the U.S. Environmental Protection Agency for use on the NTS in 2001 and has been the sole method used since 2005. Six locations on the NTS have been established to act as critical receptor locations to demonstrate compliance with the NESHAP limit. These locations are actually pseudo

  3. [Methodical approaches to evaluation of air pollution by emissions of motor vehicles in population areas].

    Science.gov (United States)

    Lyapkalo, A A; Dement'ev, A A; Tsurgan, A M

    2014-01-01

    There are results of comparative analysis of air pollution by emissions of motor vehicles in the residential districts of Ryazan via different methodical approaches. Emissions were calculated regarding analysis of the traffic intensity on the elements of the city traffic network. Relative emissions, equivalent relative emissions and relative coefficient of emission hazard were calculated for each district. Rating of the comparing districts was done according to the pollution level using the above-mentioned indices. Gorodskaya Roscha was detected as the most polluted district. The most informative approach was comparison of the residential districts according to the equivalent relative emissions and relative coefficient of emission hazard.

  4. Air Treatment Techniques for Abatement of Emissions from Intensive Livestock Production

    OpenAIRE

    Melse, R.W.; Ogink, N.W.M.; Rulkens, W.H.

    2009-01-01

    Intensive livestock production is connected with a number of environmental effects, including emissions of ammonia (NH3), greenhouse gases (CH4 and N2O), odour, and particulate matter (PM10 and PM2.5). Possible strategies for emission reduction include feed management, adaptation of housing design, and, in case of mechanically ventilated animal houses, the application of end-of-pipe air treatment, viz acid scrubbers and bioscrubbers. Air treatment techniques can achieve very high emission red...

  5. [Simulation of air pollution characteristics and estimates of environmental capacity in Zibo City].

    Science.gov (United States)

    Xue, Wen-Bo; Wang, Jin-Nan; Yang, Jin-Tian; Lei, Yu; Yan, Li; He, Jin-Yu; Han, Bao-Ping

    2013-04-01

    To develop a new pattern of air pollution control that is based on the integration of "concentration control, total amount control, and quality control", and in the context of developing national (2011-2015 air pollution control plan for key areas) and (Environmental protection plan of Zibo municipality for the "12th Five-Year Plan" period), a simulation of atmospheric dispersion of air pollutants in Zibo City and its peripheral areas is carried out by employing CALPUFF model, and the atmospheric environmental capacity of SO2, NO(x) and PM10 is estimated based on the results of model simulation and using multi-objective linear programming optimization. The results indicates that the air pollution in Zibo City is significantly related to the pollution sources outside of Zibo City, which contributes to the annual average concentration of SO2, NO2 and PM10 in Zibo City by 26.34%, 21.23%, and 14.58% respectively. There is a notable interaction between districts and counties of Zibo municipality, in which the contribution of SO2, NO(x) and PM10 emissions in surrounding counties and districts to the annual average concentrations of SO2, NO2 and PM10 in downtown area are 35.96%, 43.17%, and 17.69% respectively. There is a great variation in spatial sensitivity of air pollutant emission, and the environmental impact of unit pollutant emissions from Zhoucun, Huantai, Zhangdian and Zichuan is greater than that released from other districts/counties. To meet the requirement of (Ambient air quality standard) (GB 3095-2012), the environmental capacities of SO2, NO(x) and PM10 of Zibo City are only 8.03 x 10(4) t, 19.16 x 10(4) t and 3.21 x 10(4) t, respectively. Therefore, it is imperative to implement regional air pollution joint control in Shandong peninsula in order to ensure the achievement of air quality standard in Zibo City.

  6. Emissions of biogenic VOC from forest ecosystems in central Europe: estimation and comparison with anthropogenic emission inventory.

    Science.gov (United States)

    Zemankova, Katerina; Brechler, Josef

    2010-02-01

    This paper describes a method of estimating emission fluxes of biogenic volatile organic compounds (BVOCs) based on the approach proposed by Guenther et al. (1995) and the high-resolution Corine land-cover 2000 database (1x1km resolution). The computed emission fluxes for the Czech Republic (selected for analysis as being representative of a heavily cultivated, central European country) are compared with anthropogenic emissions, both for the entire country and for individual administrative regions. In some regions, BVOC emissions are as high as anthropogenic emissions; however, in most regions the BVOC emissions are approximately 50% of the anthropogenic emissions. The yearly course of BVOC emissions (represented by monoterpenes and isoprene) is presented, along with the spatial distribution of annual mean values. Differences in emission distributions during winter (January) and summer (June) are also considered. Copyright (c) 2009 Elsevier Ltd. All rights reserved.

  7. Top-down NOx and SO2 emissions simultaneously estimated from different OMI retrievals and inversion frameworks

    Science.gov (United States)

    Qu, Z.; Henze, D. K.; Wang, J.; Xu, X.; Wang, Y.

    2017-12-01

    Quantifying emissions trends of nitrogen oxides (NOx) and sulfur dioxide (SO2) is important for improving understanding of air pollution and the effectiveness of emission control strategies. We estimate long-term (2005-2016) global (2° x 2.5° resolution) and regional (North America and East Asia at 0.5° x 0.667° resolution) NOx emissions using a recently developed hybrid (mass-balance / 4D-Var) method with GEOS-Chem. NASA standard product and DOMINO retrievals of NO2 column are both used to constrain emissions; comparison of these results provides insight into regions where trends are most robust with respect to retrieval uncertainties, and highlights regions where seemingly significant trends are retrieval-specific. To incorporate chemical interactions among species, we extend our hybrid method to assimilate NO2 and SO2 observations and optimize NOx and SO2 emissions simultaneously. Due to chemical interactions, inclusion of SO2 observations leads to 30% grid-scale differences in posterior NOx emissions compared to those constrained only by NO2 observations. When assimilating and optimizing both species in pseudo observation tests, the sum of the normalized mean squared error (compared to the true emissions) of NOx and SO2 posterior emissions are 54-63% smaller than when observing/constraining a single species. NOx and SO2 emissions are also correlated through the amount of fuel combustion. To incorporate this correlation into the inversion, we optimize seven sector-specific emission scaling factors, including industry, energy, residential, aviation, transportation, shipping and agriculture. We compare posterior emissions from inversions optimizing only species' emissions, only sector-based emissions, and both species' and sector-based emissions. In situ measurements of NOx and SO2 are applied to evaluate the performance of these inversions. The impacts of the inversion on PM2.5 and O3 concentrations and premature deaths are also evaluated.

  8. Criteria and air-toxic emissions from in-use automobiles in the National Low-Emission Vehicle program.

    Science.gov (United States)

    Baldauf, Rich W; Gabele, Pete; Crews, William; Snow, Richard; Cook, J Rich

    2005-09-01

    The U.S. Environmental Protection Agency (EPA) implemented a program to identify tailpipe emissions of criteria and air-toxic contaminants from in-use, light-duty low-emission vehicles (LEVs). EPA recruited 25 LEVs in 2002 and measured emissions on a chassis dynamometer using the cold-start urban dynamometer driving schedule of the Federal Test Procedure. The emissions measured included regulated pollutants, particulate matter, speciated hydrocarbon compounds, and carbonyl compounds. The results provided a comparison of emissions from real-world LEVs with emission standards for criteria and air-toxic compounds. Emission measurements indicated that a portion of the in-use fleet tested exceeded standards for the criteria gases. Real-time regulated and speciated hydrocarbon measurements demonstrated that the majority of emissions occurred during the initial phases of the cold-start portion of the urban dynamometer driving schedule. Overall, the study provided updated emission factor data for real-world, in-use operation of LEVs for improved emissions modeling and mobile source inventory development.

  9. Air emissions perspective on energy efficiency: An empirical analysis of China’s coastal areas

    International Nuclear Information System (INIS)

    Qin, Quande; Li, Xin; Li, Li; Zhen, Wei; Wei, Yi-Ming

    2017-01-01

    Highlights: • We investigate the static and dynamic energy efficiency in China’s coastal areas. • Both environmental pollutants and greenhouse gas are considered. • Global benchmark technology is incorporated into the related DEA models. • China’s coastal areas have great potential of air emissions reduction. • Technological progress is main driven factor to improve energy efficiency. - Abstract: Improving energy efficiency has been recognized as the most effective way to reduce the greenhouse effect and achieve sustainable development. From the perspective of air emissions, this paper adopts data envelopment analysis approach to evaluate the energy efficiency in China’s coastal areas over the period of 2000–2012. Carbon dioxide, sulfur dioxide and nitrogen oxide are treated as undesirable outputs of energy consumptions. The proposed global Epsilon-based measure is used to estimate the static energy efficiency with an annual cross-section of data. The weights of the three undesirable outputs are determined according to their treatment costs. A global Malmquist-Luenberger productivity index based on directional distance function is employed to dynamically evaluate the energy efficiency. The results indicate the following in China’s coastal areas: (1) the level of economic development is positively related to energy efficiency scores; (2) energy efficiency scores decrease when considering undesirable outputs except Beijing and Hainan; (3) the Circum-Bohai Sea Economic Region greatly improves energy efficiency and has great potential of air emission; (4) the annual growth rate of Malmquist-Luenberger productivity index change is overestimated; (5) energy efficiency improvement is mainly driven by technological improvement, and scale efficiency and management level are the main obstacles.

  10. Development and Evaluation of a Comprehensive Atmospheric Emission Inventory for Air Quality Modeling in the Megacity of Bogotá

    Directory of Open Access Journals (Sweden)

    Jorge E. Pachón

    2018-02-01

    Full Text Available We built an emission inventory (EI for the megacity of Bogotá, Colombia for 2012, which for the first time augments traditional industrial and mobile sources by including commercial sources, biogenic sources, and resuspended dust. We characterized the methodologies for estimating each source annually, and allocated the sources to hourly and 1 km2 spatial resolution for use as inputs for air quality modeling purposes. A resuspended particulate matter (RPM emission estimate was developed using the first measurements of road dust loadings and silt content for the city. Results show that mobile sources dominate emissions of CO2 (80%, CO (99%, VOC (68%, NOx (95%, and SO2 (85%. However, the newly estimated RPM comprises 90% of total PM10 emissions, which are at least onefold larger than the PM10 emissions from combustion processes. The 2012 EI was implemented in a chemical transport model (CTM in order to understand the pollutants’ fate and transport. Model evaluation was conducted against observations from the city’s air quality monitoring network in two different periods. Modeling results for O3 concentrations showed a good agreement, with mean fractional bias (MFB of +11%, and a mean fractional error (MFE of +35% with observations, but simulated PM10 concentrations were strongly biased high (MFB +57%, MFE +68%, which was likely due to RPM emissions being overestimated. NOx, CO, and SO2 were also biased high by the model, which was probably due to emissions not reflecting current fleet conditions. Future work aims to revise emission factors for mobile sources, which are the main sources of pollutants to the atmosphere.

  11. Ship emission inventory and its impact on the PM2.5 air pollution in Qingdao Port, North China

    Science.gov (United States)

    Chen, Dongsheng; Wang, Xiaotong; Nelson, Peter; Li, Yue; Zhao, Na; Zhao, Yuehua; Lang, Jianlei; Zhou, Ying; Guo, Xiurui

    2017-10-01

    In this study, a first high temporal-spatial ship emission inventory in Qingdao Port and its adjacent waters has been developed using a ;bottom-up; method based on Automatic Identification System (AIS) data. The total estimated ship emissions for SO2, NOX, PM10, PM2.5, HC and CO in 2014 are 3.32 × 104, 4.29 × 104, 4.54 × 103, 4.18 × 103, 1.85 × 103 and 3.66 × 103 tonnes, respectively. Emissions of SO2 and NOX from ships account for 9% and 13% of the anthropogenic totals in Qingdao, respectively. The main contributors to the ship emissions are containers, followed by fishing ships, oil tankers and bulk carriers. The inter-monthly ship emissions varied significantly due to two reasons: stopping of the fishing ship activities during the fishing moratorium and the reduction of freight volume around the Chinese New Year Festival. Emissions from transport vessels concentrated basically along the shipping routes, while fishing ships contributed to massive irregular spatial emissions in the sea. The impact of ship emissions on the ambient air quality was further investigated using the Weather Research and Forecasting with Chemistry (WRF/Chem) model. The results reveal that the contribution of ship emissions to the PM2.5 concentrations in Qingdao is the highest in summer (13.1%) and the lowest in winter (1.5%). The impact was more evident over densely populated urban areas, where the contributions from ship emissions could be over 20% in July due to their close range to the docks. These results indicated that the management and control of the ship emissions are highly demanded considering their remarkable influence on the air quality and potential negative effects on human health.

  12. Emissions of organic hazardous air pollutants during Chinese coal combustion

    Energy Technology Data Exchange (ETDEWEB)

    Yan, R.; Zhu, H.J.; Zheng, C.G.; Xu, M.H. [Environmental Technology Institute, Singapore (Singapore). Innovative Center

    2002-05-01

    The emissions of organic hazardous air pollutants (HAPs) during the combustion of several typical Chinese coals were investigated. First, the distribution of four types of HAP, i.e., aliphatics, cyclic hydrocarbons, monoaromatic compounds and PAHs, in the CH{sub 2}C{sub l2} extracts of six Chinese coals were studied and the influences of the extractive times and coal varieties were also evaluated. Second, the partitioning of these HAPs in the flue gas during coal combustion in a small-scale reactor were investigated, depending on oven temperatures (500, 600, 700, 800, 900{sup o}C) and coal varieties. The behaviors of HAP in the combustion flue gas were compared with those in the CH{sub 2}, Cl{sub 2}, extracts. Finally, combustion was conducted at given conditions in two laboratory-scale reactors: a fluidized bed and a fixed bed. Two coals (Shengmu bituminous coal and Xunhuan anthracite coal) and one coke were considered. The HAP partitioning both in flue gases and in ashes were evaluated and compared between the two combustors.

  13. Estimation of unit risk for coke oven emissions

    International Nuclear Information System (INIS)

    Moolgavkar, S.H.; Luebeck, E.G.; Anderson, E.L.

    1998-01-01

    In 1984, based on epidemiological data on cohorts of coke oven workers, USEPA estimated a unit risk for lung cancer associated with continuous exposure from birth to 1 microg/m 3 of coke oven emissions, of 6.2 x 10 -4 . This risk assessment was based on information on the cohorts available through 1966. Follow-up of these cohorts has now been extended to 1982 and, moreover, individual job histories, which were not available in 1984, have been constructed. In this study, lung cancer mortality in these cohorts of coke oven workers with extended follow-up was analyzed using standard techniques of survival analysis and a new approach based on the two stage clonal expansion model of carcinogenesis. The latter approach allows the explicit consideration of detailed patterns of exposure of each individual in the cohort. The analyses used the extended follow-up data through 1982 and the detailed job histories now available. Based on these analyses, the best estimate of unit risk is 1.5 x 10 -4 with 95% confidence interval = 1.2 x 10 -4 --1.8 x 10 -4

  14. Effects of public health interventions on industrial emissions and ambient air in Cartagena, Spain.

    Science.gov (United States)

    Cirera, Lluís; Rodríguez, Miguel; Giménez, Joaquín; Jiménez, Enrique; Saez, Marc; Guillén, José-Jesús; Medrano, José; Martínez-Victoria, María-Aurelia; Ballester, Ferran; Moreno-Grau, Stella; Navarro, Carmen

    2009-03-01

    Ten years of public health interventions on industrial emissions to clean air were monitored for the Mediterranean city of Cartagena. During the 1960s, a number of large chemical and non-ferrous metallurgical factories were established that significantly deteriorated the city's air quality. By the 1970s, the average annual air concentration of sulfur dioxide (SO2) ranged from 200 to 300 microg/m3 (standard conditions units). In 1979, the Spanish government implemented an industrial intervention plan to improve the performance of factories and industrial air pollution surveillance. Unplanned urban development led to residential housing being located adjacent to three major factories. Factory A produced lead, factory B processed zinc from ore concentrates, and factory C produced sulfuric acid and phosphates. This, in combination with the particular abrupt topography and frequent atmospheric thermal inversions, resulted in the worsening of air quality and heightening concern for public health. In 1990, the City Council authorized the immediate intervention at these factories to reduce or shut down production if ambient levels of SO2 or total suspended particles (TSP) exceeded a time-emission threshold in pre-established meteorological contexts. The aim of this research was to assess the appropriateness and effectiveness of the intervention plan implemented from 1992 to 2001 to abate industrial air pollution. The maximum daily 1-h ambient air level of SO2, NO2, and TSP pollutants was selected from one of the three urban automatic stations, designed to monitor ambient air quality around industrial emissions sources. The day on which an intervention took place to reduce and/or interrupt industrial production by factory and pollutant was defined as a control day, and the day after an intervention as a post-control day. To assess the short-term intervention effect on air quality, an ecological time series design was applied, using regression analysis in generalized

  15. ESTIMATION OF NEAR SUBSURFACE COAL FIRE GAS EMISSIONS BASED ON GEOPHYSICAL INVESTIGATIONS

    Science.gov (United States)

    Chen-Brauchler, D.; Meyer, U.; Schlömer, S.; Kus, J.; Gundelach, V.; Wuttke, M.; Fischer, C.; Rueter, H.

    2009-12-01

    Spontaneous and industrially caused subsurface coal fires are worldwide disasters that destroy coal resources, cause air pollution and emit a large amount of green house gases. Especially in developing countries, such as China, India and Malaysia, this problem has intensified over the last 15 years. In China alone, 10 to 20 million tons of coal are believed to be lost in uncontrolled coal fires. The cooperation of developing countries and industrialized countries is needed to enforce internationally concerted approaches and political attention towards the problem. The Clean Development Mechanism (CDM) under the framework of the Kyoto Protocol may provide an international stage for financial investment needed to fight the disastrous situation. A Sino-German research project for coal fire exploration, monitoring and extinction applied several geophysical approaches in order to estimate the annual baseline especially of CO2 emissions from near subsurface coal fires. As a result of this project, we present verifiable methodologies that may be used in the CDM framework to estimate the amount of CO2 emissions from near subsurface coal fires. We developed three possibilities to approach the estimation based on (1) thermal energy release, (2) geological and geometrical determinations as well as (3) direct gas measurement. The studies involve the investigation of the physical property changes of the coal seam and bedrock during different burning stages of a underground coal fire. Various geophysical monitoring methods were applied from near surface to determine the coal volume, fire propagation, temperature anomalies, etc.

  16. On the estimation method of compressed air consumption during pneumatic caisson sinking

    OpenAIRE

    平川, 修治; ヒラカワ, シュウジ; Shuji, HIRAKAWA

    1990-01-01

    There are several methods in estimation of compressed air consumption during pneumatic caisson sinking. It is re uired in the estimation of compressed air consumption by the methods under the same conditions. In this paper, it is proposed the methods which is able to estimate accurately the compressed air consumption during pnbumatic caissons sinking at this moment.

  17. Estimating Western U.S. Oil & Gas Emissions with OMI NO2 Data

    Science.gov (United States)

    Clifton, O. E.; Holloway, T.; Oberman, J.

    2012-12-01

    In the last ten years, there has been a steep increase in the number natural gas and oil extraction facilities in the United States due to hydraulic fracturing ("fracking"). Each facility requires a large range of equipment, such as drilling rigs, compressor engines, heaters, and pneumatic devices. These activities can lead to elevated nitrogen dioxide (NO2) emissions in rural areas, often in regions without routine NO2 surface monitoring. Furthermore, permitting rules vary from state to state, and many new extraction facilities are unpermitted and exact emissions unknown. On April 18, 2012, the EPA announced air pollution standards for volatile organic compounds (VOCs) emissions from the oil and gas industry. Until 2015, when these standards must be in effect, NOx (NO2 + NO) will continue to react with VOCs to form unhealthy levels of tropospheric ozone in regions with heavy use of hydraulic fracturing. In order to identify areas of elevated NO2 emissions and constrain associated on-road and off-road sources in areas with prominent shale basins and known drilling, we employ remote sensing estimates of column NO2 from the Ozone Monitoring Instrument (OMI) aboard NASA's Aura satellite. OMI NO2 is sensitive to the planetary boundary layer and to surface air pollution and thus has high temporal and spatial variation. These Level-2 satellite data are processed with the Wisconsin Horizontal Interpolation Program for Satellites (WHIPS), developed at the University of Wisconsin-Madison. We interpolate the data to allow further ease in mapping change in NO2 associated with drilling, and the quantification of pollution trends attributable to hydraulic-fracturing in the Western U.S. from 2004 to the present.

  18. Impact of emissions from natural gas production facilities on ambient air quality in the Barnett Shale area: a pilot study.

    Science.gov (United States)

    Zielinska, Barbara; Campbell, Dave; Samburova, Vera

    2014-12-01

    Rapid and extensive development of shale gas resources in the Barnett Shale region of Texas in recent years has created concerns about potential environmental impacts on water and air quality. The purpose of this study was to provide a better understanding of the potential contributions of emissions from gas production operations to population exposure to air toxics in the Barnett Shale region. This goal was approached using a combination of chemical characterization of the volatile organic compound (VOC) emissions from active wells, saturation monitoring for gaseous and particulate pollutants in a residential community located near active gas/oil extraction and processing facilities, source apportionment of VOCs measured in the community using the Chemical Mass Balance (CMB) receptor model, and direct measurements of the pollutant gradient downwind of a gas well with high VOC emissions. Overall, the study results indicate that air quality impacts due to individual gas wells and compressor stations are not likely to be discernible beyond a distance of approximately 100 m in the downwind direction. However, source apportionment results indicate a significant contribution to regional VOCs from gas production sources, particularly for lower-molecular-weight alkanes (gas production. Implications: Rapid and extensive development of shale gas resources in recent years has created concerns about potential environmental impacts on water and air quality. This study focused on directly measuring the ambient air pollutant levels occurring at residential properties located near natural gas extraction and processing facilities, and estimating the relative contributions from gas production and motor vehicle emissions to ambient VOC concentrations. Although only a small-scale case study, the results may be useful for guidance in planning future ambient air quality studies and human exposure estimates in areas of intensive shale gas production.

  19. Examining air pollution in China using production- and consumption-based emissions accounting approaches.

    Science.gov (United States)

    Huo, Hong; Zhang, Qiang; Guan, Dabo; Su, Xin; Zhao, Hongyan; He, Kebin

    2014-12-16

    Two important reasons for China's air pollution are the high emission factors (emission per unit of product) of pollution sources and the high emission intensity (emissions per unit of GDP) of the industrial structure. Therefore, a wide variety of policy measures, including both emission abatement technologies and economic adjustment, must be implemented. To support such measures, this study used the production- and consumption-based emissions accounting approaches to simulate the SO2, NOx, PM2.5, and VOC emissions flows among producers and consumers. This study analyzed the emissions and GDP performance of 36 production sectors. The results showed that the equipment, machinery, and devices manufacturing and construction sectors contributed more than 50% of air pollutant emissions, and most of their products were used for capital formation and export. The service sector had the lowest emission intensities, and its output was mainly consumed by households and the government. In China, the emission intensities of production activities triggered by capital formation and export were approximately twice that of the service sector triggered by final consumption expenditure. This study suggests that China should control air pollution using the following strategies: applying end-of-pipe abatement technologies and using cleaner fuels to further decrease the emission factors associated with rural cooking, electricity generation, and the transportation sector; continuing to limit highly emission-intensive but low value-added exports; developing a plan to reduce construction activities; and increasing the proportion of service GDP in the national economy.

  20. Airborne measurements of western U.S. wildfire emissions: Comparison with prescribed burning and air quality implications: Western U.S. Wildfire Emissions

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xiaoxi [School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta Georgia USA; Now at Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder Colorado USA; Now at Department of Chemistry, University of Colorado Boulder, Boulder Colorado USA; Huey, L. Gregory [School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta Georgia USA; Yokelson, Robert J. [Department of Chemistry, University of Montana, Missoula Montana USA; Selimovic, Vanessa [Department of Chemistry, University of Montana, Missoula Montana USA; Simpson, Isobel J. [Department of Chemistry, University of California, Irvine California USA; Müller, Markus [Department of Chemistry, University of Montana, Missoula Montana USA; Institute for Ion Physics and Applied Physics, University of Innsbruck, Innsbruck Austria; Jimenez, Jose L. [Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder Colorado USA; Department of Chemistry, University of Colorado Boulder, Boulder Colorado USA; Campuzano-Jost, Pedro [Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder Colorado USA; Department of Chemistry, University of Colorado Boulder, Boulder Colorado USA; Beyersdorf, Andreas J. [NASA Langley Research Center, Hampton Virginia USA; Now at Department of Chemistry, California State University, San Bernardino California USA; Blake, Donald R. [Department of Chemistry, University of California, Irvine California USA; Butterfield, Zachary [Earth and Environmental Sciences Division, Los Alamos National Laboratory, Los Alamos New Mexico USA; Now at Department of Atmospheric, Oceanic, and Space Sciences, University of Michigan, Ann Arbor Michigan USA; Choi, Yonghoon [NASA Langley Research Center, Hampton Virginia USA; Science Systems and Applications, Inc., Hampton Virginia USA; Crounse, John D. [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena California USA; Day, Douglas A. [Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder Colorado USA; Department of Chemistry, University of Colorado Boulder, Boulder Colorado USA; Diskin, Glenn S. [NASA Langley Research Center, Hampton Virginia USA; Dubey, Manvendra K. [Earth and Environmental Sciences Division, Los Alamos National Laboratory, Los Alamos New Mexico USA; Fortner, Edward [Center for Aerosol and Cloud Chemistry, Aerodyne Research Inc., Billerica Massachusetts USA; Hanisco, Thomas F. [Atmospheric Chemistry and Dynamics Laboratory, NASA Goddard Space Flight Center, Greenbelt Maryland USA; Hu, Weiwei [Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder Colorado USA; Department of Chemistry, University of Colorado Boulder, Boulder Colorado USA; King, Laura E. [School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta Georgia USA; Kleinman, Lawrence [Environmental and Climate Sciences Department, Brookhaven National Laboratory, Upton New York USA; Meinardi, Simone [Department of Chemistry, University of California, Irvine California USA; Mikoviny, Tomas [Department of Chemistry, University of Oslo, Oslo Norway; Onasch, Timothy B. [Center for Aerosol and Cloud Chemistry, Aerodyne Research Inc., Billerica Massachusetts USA; Palm, Brett B. [Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder Colorado USA; Department of Chemistry, University of Colorado Boulder, Boulder Colorado USA; Peischl, Jeff [Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder Colorado USA; Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder Colorado USA; Pollack, Ilana B. [Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder Colorado USA; Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder Colorado USA; Now at Department of Atmospheric Science, Colorado State University, Fort Collins Colorado USA; Ryerson, Thomas B. [Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder Colorado USA; Sachse, Glen W. [NASA Langley Research Center, Hampton Virginia USA; Sedlacek, Arthur J. [Environmental and Climate Sciences Department, Brookhaven National Laboratory, Upton New York USA; Shilling, John E. [Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland Washington USA; Springston, Stephen [Environmental and Climate Sciences Department, Brookhaven National Laboratory, Upton New York USA; St. Clair, Jason M. [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena California USA; Now at Atmospheric Chemistry and Dynamics Laboratory, NASA Goddard Space Flight Center, Greenbelt Maryland USA; Now at Joint Center for Earth Systems Technology, University of Maryland, Baltimore County, Baltimore Maryland USA; Tanner, David J. [School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta Georgia USA; Teng, Alexander P. [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena California USA; Wennberg, Paul O. [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena California USA; Division of Engineering and Applied Science, California Institute of Technology, Pasadena California USA; Wisthaler, Armin [Institute for Ion Physics and Applied Physics, University of Innsbruck, Innsbruck Austria; Department of Chemistry, University of Oslo, Oslo Norway; Wolfe, Glenn M. [Atmospheric Chemistry and Dynamics Laboratory, NASA Goddard Space Flight Center, Greenbelt Maryland USA; Joint Center for Earth Systems Technology, University of Maryland, Baltimore County, Baltimore Maryland USA

    2017-06-14

    Wildfires emit significant amounts of pollutants that degrade air quality. Plumes from three wildfires in the western U.S. were measured from aircraft during the Studies of Emissions and Atmospheric Composition, Clouds, and Climate Coupling by Regional Surveys (SEAC4RS) and the Biomass Burning Observation Project (BBOP), both in summer 2013. This study reports an extensive set of emission factors (EFs) for over 80 gases and 5 components of submicron particulate matter (PM1) from these temperate wildfires. These include rarely, or never before, measured oxygenated volatile organic compounds and multifunctional organic nitrates. The observed EFs are compared with previous measurements of temperate wildfires, boreal forest fires, and temperate prescribed fires. The wildfires emitted high amounts of PM1 (with organic aerosol (OA) dominating the mass) with an average EF that is more than two times the EFs for prescribed fires. The measured EFs were used to estimate the annual wildfire emissions of carbon monoxide, nitrogen oxides, total nonmethane organic compounds, and PM1 from 11 western U.S. states. The estimated gas emissions are generally comparable with the 2011 National Emissions Inventory (NEI). However, our PM1 emission estimate (1530 ± 570 Gg yr-1) is over three times that of the NEI PM2.5 estimate and is also higher than the PM2.5 emitted from all other sources in these states in the NEI. This study indicates that the source of OA from BB in the western states is significantly underestimated. In addition, our results indicate prescribed burning may be an effective method to reduce fine particle emissions.

  1. Airborne measurements of western U.S. wildfire emissions: Comparison with prescribed burning and air quality implications: Western U.S. Wildfire Emissions

    International Nuclear Information System (INIS)

    Liu, Xiaoxi; University of Colorado, Boulder, CO; Huey, L. Gregory; Yokelson, Robert J.; Selimovic, Vanessa

    2017-01-01

    Wildfires emit significant amounts of pollutants that degrade air quality. Plumes from three wildfires in the western U.S. were measured from aircraft during the Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS) and the Biomass Burning Observation Project (BBOP), both in summer 2013. This study reports an extensive set of emission factors (EFs) for over 80 gases and 5 components of submicron particulate matter (PM 1 ) from these temperate wildfires. These include rarely, or never before, measured oxygenated volatile organic compounds and multifunctional organic nitrates. The observed EFs are compared with previous measurements of temperate wildfires, boreal forest fires, and temperate prescribed fires. Furthermore, the wildfires emitted high amounts of PM 1 (with organic aerosol (OA) dominating the mass) with an average EF that is more than 2 times the EFs for prescribed fires. The measured EFs were used to estimate the annual wildfire emissions of carbon monoxide, nitrogen oxides, total nonmethane organic compounds, and PM 1 from 11 western U.S. states. The estimated gas emissions are generally comparable with the 2011 National Emissions Inventory (NEI). However, our PM 1 emission estimate (1530 ± 570 Gg yr -1 ) is over 3 times that of the NEI PM2.5 estimate and is also higher than the PM2.5 emitted from all other sources in these states in the NEI. This study indicates that the source of OA from biomass burning in the western states is significantly underestimated. Additionally, our results indicate that prescribed burning may be an effective method to reduce fine particle emissions.

  2. A pilot study to determine medical laser generated air contaminant emission rates for a simulated surgical procedure.

    Science.gov (United States)

    Lippert, Julia F; Lacey, Steven E; Lopez, Ramon; Franke, John; Conroy, Lorraine; Breskey, John; Esmen, Nurtan; Liu, Li

    2014-01-01

    The U.S. Occupational Safety and Health Administration (OSHA) estimates that half a million health-care workers are exposed to laser surgical smoke each year. The purpose of this study was to establish a methodology to (1) estimate emission rates of laser-generated air contaminants (LGACs) using an emission chamber, and to (2) perform a screening study to differentiate the effects of three laser operational parameters. An emission chamber was designed, fabricated, and assessed for performance to estimate the emission rates of gases and particles associated with LGACs during a simulated surgical procedure. Two medical lasers (Holmium Yttrium Aluminum Garnet [Ho:YAG] and carbon dioxide [CO2]) were set to a range of plausible medical laser operational parameters in a simulated surgery to pyrolyze porcine skin generating plume in the emission chamber. Power, pulse repetition frequency (PRF), and beam diameter were evaluated to determine the effect of each operational parameter on emission rate using a fractional factorial design. The plume was sampled for particulate matter and seven gas phase combustion byproduct contaminants (benzene, ethylbenzene, toluene, formaldehyde, hydrogen cyanide, carbon dioxide, and carbon monoxide): the gas phase emission results are presented here. Most of the measured concentrations of gas phase contaminants were below their limit of detection (LOD), but detectable measurements enabled us to determine laser operation parameter influence on CO2 emissions. Confined to the experimental conditions of this screening study, results indicated that beam diameter was statistically significantly influential and power was marginally statistically significant to emission rates of CO2 when using the Ho:YAG laser but not with the carbon dioxide laser; PRF was not influential vis-a-vis emission rates of these gas phase contaminants.

  3. Estimating surface solar radiation from upper-air humidity

    Energy Technology Data Exchange (ETDEWEB)

    Kun Yang [Telecommunications Advancement Organization of Japan, Tokyo (Japan); Koike, Toshio [University of Tokyo (Japan). Dept. of Civil Engineering

    2002-07-01

    A numerical model is developed to estimate global solar irradiance from upper-air humidity. In this model, solar radiation under clear skies is calculated through a simple model with radiation-damping processes under consideration. A sky clearness indicator is parameterized from relative humidity profiles within three atmospheric sublayers, and the indicator is used to connect global solar radiation under clear skies and that under cloudy skies. Model inter-comparisons at 18 sites in Japan suggest (1) global solar radiation strongly depends on the sky clearness indicator, (2) the new model generally gives better estimation to hourly-mean solar irradiance than the other three methods used in numerical weather predictions, and (3) the new model may be applied to estimate long-term solar radiation. In addition, a study at one site in the Tibetan Plateau shows vigorous convective activities in the region may cause some uncertainties to radiation estimations due to the small-scale and short life of convective systems. (author)

  4. Transport and Environment Database System (TRENDS): Maritime Air Pollutant Emission Modelling

    DEFF Research Database (Denmark)

    Georgakaki, Aliki; Coffey, R. A.; Lock, G.

    2003-01-01

    This paper reports the development of the maritime module within the framework of the TRENDS project. A detailed database has been constructed, which includes all stages of the energy consumption and air pollutant emission calculations. The technical assumptions and factors incorporated in the da...... ¿ short sea or deep-sea shipping. Key Words: Air Pollution, Maritime Transport, Air Pollutant Emissions......This paper reports the development of the maritime module within the framework of the TRENDS project. A detailed database has been constructed, which includes all stages of the energy consumption and air pollutant emission calculations. The technical assumptions and factors incorporated...... encountered since the statistical data collection was not undertaken with a view to this purpose are mentioned. Examples of the results obtained by the database are presented. These include detailed air pollutant emission results per port and vessel type, to aggregate results for different types of movements...

  5. Modelling and analysis of ozone concentration by artificial intelligent techniques for estimating air quality

    Science.gov (United States)

    Taylan, Osman

    2017-02-01

    High ozone concentration is an important cause of air pollution mainly due to its role in the greenhouse gas emission. Ozone is produced by photochemical processes which contain nitrogen oxides and volatile organic compounds in the lower atmospheric level. Therefore, monitoring and controlling the quality of air in the urban environment is very important due to the public health care. However, air quality prediction is a highly complex and non-linear process; usually several attributes have to be considered. Artificial intelligent (AI) techniques can be employed to monitor and evaluate the ozone concentration level. The aim of this study is to develop an Adaptive Neuro-Fuzzy inference approach (ANFIS) to determine the influence of peripheral factors on air quality and pollution which is an arising problem due to ozone level in Jeddah city. The concentration of ozone level was considered as a factor to predict the Air Quality (AQ) under the atmospheric conditions. Using Air Quality Standards of Saudi Arabia, ozone concentration level was modelled by employing certain factors such as; nitrogen oxide (NOx), atmospheric pressure, temperature, and relative humidity. Hence, an ANFIS model was developed to observe the ozone concentration level and the model performance was assessed by testing data obtained from the monitoring stations established by the General Authority of Meteorology and Environment Protection of Kingdom of Saudi Arabia. The outcomes of ANFIS model were re-assessed by fuzzy quality charts using quality specification and control limits based on US-EPA air quality standards. The results of present study show that the ANFIS model is a comprehensive approach for the estimation and assessment of ozone level and is a reliable approach to produce more genuine outcomes.

  6. Energy-Efficiency and Air-Pollutant Emissions-Reduction Opportunities for the Ammonia Industry in China

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Ding [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Hasanbeigi, Ali [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chen, Wenying [Tsinghua Univ., Beijing (China)

    2015-06-01

    As one of the most energy-intensive and polluting industries, ammonia production is responsible for significant carbon dioxide (CO2) and air-pollutant emissions. Although many energy-efficiency measures have been proposed by the Chinese government to mitigate greenhouse gas emissions and improve air quality, lack of understanding of the cost-effectiveness of such improvements has been a barrier to implementing these measures. Assessing the costs, benefits, and cost-effectiveness of different energy-efficiency measures is essential to advancing this understanding. In this study, a bottom-up energy conservation supply curve model is developed to estimate the potential for energy savings and emissions reductions from 26 energy-efficiency measures that could be applied in China’s ammonia industry. Cost-effective implementation of these measures saves a potential 271.5 petajoules/year for fuel and 5,443 gigawatt-hours/year for electricity, equal to 14% of fuel and 14% of electricity consumed in China’s ammonia industry in 2012. These reductions could mitigate 26.7 million tonnes of CO2 emissions. This study also quantifies the co-benefits of reducing air-pollutant emissions and water use that would result from saving energy in China’s ammonia industry. This quantitative analysis advances our understanding of the cost-effectiveness of energy-efficiency measures and can be used to augment efforts to reduce energy use and environmental impacts.

  7. Impact of emissions from the Los Angeles port region on San Diego air quality during regional transport events.

    Science.gov (United States)

    Ault, Andrew P; Moore, Meagan J; Furutani, Hiroshi; Prather, Kimberly A

    2009-05-15

    Oceangoing ships emit an estimated 1.2-1.6 million metric tons (Tg) of PM10 per year and represent a significant source of air pollution to coastal communities. As shown herein, ship and other emissions near the Los Angeles and Long Beach Port region strongly influence air pollution levels in the San Diego area. During time periods with regional transport, atmospheric aerosol measurements in La Jolla, California show an increase in 0.5-1 microm sized single particles with unique signatures including soot, metals (i.e., vanadium, iron, and nickel), sulfate, and nitrate. These particles are attributed to primary emissions from residual oil sourcessuch as ships and refineries, as well as traffic in the port region, and secondary processing during transport. During regional transport events, particulate matter concentrations were 2-4 times higher than typical average concentrations from local sources, indicating the health, environmental, and climate impacts from these emission sources must be taken into consideration in the San Diego region. Unless significant regulations are imposed on shipping-related activities, these emission sources will become even more important to California air quality as cars and truck emissions undergo further regulations and residual oil sources such as shipping continue to expand.

  8. A multi-methodological approach to study the temporal and spatial distribution of air quality related to road transport emissions in Madrid, Spain

    Science.gov (United States)

    Perez, Pedro; Miranda, Regina

    2013-04-01

    The traffic-related atmospheric emissions, composition and transport of greenhouse gases (GHGs) and air toxic pollutants (ATPs), are an important environmental problem that affect climate change and air pollution in Madrid, Spain. Carbon dioxide (CO2) affects the regional weather and particularly fine particle matter (PM) translocate to the people resulting in local health problems. As the main source of emissions comes from road transport, and subsequent combustion of fossil fuels, air quality deterioration may be elevated during weekdays and peak hours. We postulate that traffic-related air quality (CO2, methane CH4, PM, volatile organic compounds VOCs, nitrogen oxides NOx and carbon monoxide CO contents) impairs epidemiology in part via effects on health and disease development, likely increasing the external costs of transport in terms of climate change and air pollution. First, the paper intends to estimate the local air quality related to the road transport emissions of weeks over a domain covering Madrid (used as a case study). The local air quality model (LAQM) is based on gridded and shaped emission fields. The European Environmental Agency (EEA) COPERT modeling system will provide GHGs and ATPs gridded and shaped emission data and mobile source parameters, available for Madrid from preliminary emission inventory records of the Municipality of Madrid and from disaggregated traffic counts of the Traffic Engineering Company and the Metropolitan Company of Metro (METRO-Madrid). The paper intends to obtain estimates of GHGs and ATPs concentrations commensurate with available ground measurements, 24-hour average values, from the Municipality of Madrid. The comparison between estimated concentrations and measurements must show small errors (e.g. fractional error, fractional bias and coefficient of determination). The paper's expected results must determine spatial and temporal patterns in Madrid. The estimates will be used to cross check the primary local

  9. Environmental challenges and opportunities of the evolving North American electricity market : Estimating future air pollution from new electric power generation

    International Nuclear Information System (INIS)

    Miller, P.; Patterson, Z.; Vaughan, S.

    2002-06-01

    A significant source of air pollutants and greenhouse gases in North America is a direct result of the generation of electricity from the combustion of fossil fuels. An attempt at estimating the future emissions of four key pollutants from the electricity generation sector in North America was made by the authors in this paper. They based their estimates on projections of future electricity generation capacity changes. They looked at new power plant projects in North America, as well as the expected changes in emissions as a result of these projects compared to the historical data originating from power plant emissions in the recent past. Both the local context and the national level were examined. Nitrogen oxides, sulfur dioxide, mercury, and carbon dioxide, all arising from the combustion of fossil fuels, were considered in this paper. Ground level ozone, or smog results from nitrogen oxides. Acidic deposition, also called acid rain, is caused in part by both nitrogen oxides and sulfur dioxide, as is fine particles in the atmosphere linked to lung damage and premature death. Fish consumption advisories were issued due to the levels of toxic mercury deposited in lakes and streams. Global climate change is caused in part to the greenhouse gas carbon dioxide. Air quality and climate change will both be impacted by the future evolution of the electricity generation sector in an integrated North American energy market. The authors attempted to provide a baseline of air emissions from that sector in North America for a common reference year, enabling the tracking of changes in emissions patterns in the future. A reference case inventory for the four pollutants was estimated, followed by the development of two boundary cases estimating future emissions in 2007. refs., 22 tabs

  10. Top-down estimates of benzene and toluene emissions in the Pearl River Delta and Hong Kong, China

    OpenAIRE

    Fang, Xuekun; Shao, Min; Stohl, Andreas; Zhang, Qiang; Zheng, Junyu; Guo, Hai; Wang, Chen; Wang, Ming; Ou, Jiamin; Thompson, Rona L.; Prinn, Ronald G.

    2016-01-01

    Benzene (C6H6) and toluene (C7H8) are toxic to humans and the environment. They are also important precursors of ground-level ozone and secondary organic aerosols and contribute substantially to severe air pollution in urban areas in China. Discrepancies exist between different bottom-up inventories for benzene and toluene emissions in the Pearl River Delta (PRD) and Hong Kong (HK), which are emission hot spots in China. This study provides top-down estimates of benzene and ...

  11. Top-down estimates of benzene and toluene emissions in Pearl River Delta and Hong Kong, China

    OpenAIRE

    X. Fang; M. Shao; A. Stohl; Q. Zhang; J. Zheng; H. Guo; C. Wang; M. Wang; J. Ou; R. L. Thompson; R. G. Prinn

    2015-01-01

    Benzene (C6H6) and toluene (C7H8) are toxic to humans and the environment. They are also important precursors of ground-level ozone and secondary organic aerosols and contribute substantially to severe air pollution in urban areas in China. Discrepancies exist between different bottom-up inventories for benzene and toluene emissions in Pearl River Delta (PRD) and Hong Kong (HK), which are emission hot spots in China. This study provides top-down estimates of benzene and tolu...

  12. Enhanced Representation of Soil NO Emissions in the Community Multiscale Air Quality (CMAQ) Model Version 5.0.2

    Science.gov (United States)

    Rasool, Quazi Z.; Zhang, Rui; Lash, Benjamin; Cohan, Daniel S.; Cooter, Ellen J.; Bash, Jesse O.; Lamsal, Lok N.

    2016-01-01

    Modeling of soil nitric oxide (NO) emissions is highly uncertain and may misrepresent its spatial and temporal distribution. This study builds upon a recently introduced parameterization to improve the timing and spatial distribution of soil NO emission estimates in the Community Multiscale Air Quality (CMAQ) model. The parameterization considers soil parameters, meteorology, land use, and mineral nitrogen (N) availability to estimate NO emissions. We incorporate daily year-specific fertilizer data from the Environmental Policy Integrated Climate (EPIC) agricultural model to replace the annual generic data of the initial parameterization, and use a 12km resolution soil biome map over the continental USA. CMAQ modeling for July 2011 shows slight differences in model performance in simulating fine particulate matter and ozone from Interagency Monitoring of Protected Visual Environments (IMPROVE) and Clean Air Status and Trends Network (CASTNET) sites and NO2 columns from Ozone Monitoring Instrument (OMI) satellite retrievals. We also simulate how the change in soil NO emissions scheme affects the expected O3 response to projected emissions reductions.

  13. Impacts of Energy Sector Emissions on PM2.5 Air Quality in Northern India

    Science.gov (United States)

    Karambelas, A. N.; Kiesewetter, G.; Heyes, C.; Holloway, T.

    2015-12-01

    India experiences high concentrations of fine particulate matter (PM2.5), and several Indian cities currently rank among the world's most polluted cities. With ongoing urbanization and a growing economy, emissions from different energy sectors remain major contributors to air pollution in India. Emission sectors impact ambient air quality differently due to spatial distribution (typical urban vs. typical rural sources) as well as source height characteristics (low-level vs. high stack sources). This study aims to assess the impacts of emissions from three distinct energy sectors—transportation, domestic, and electricity—on ambient PM2.5­­ in northern India using an advanced air quality analysis framework based on the U.S. EPA Community Multi-Scale Air Quality (CMAQ) model. Present air quality conditions are simulated using 2010 emissions from the Greenhouse Gas-Air Pollution Interaction and Synergies (GAINS) model. Modeled PM2.5 concentrations are compared with satellite observations of aerosol optical depth (AOD) from the Moderate Imaging Spectroradiometer (MODIS) for 2010. Energy sector emissions impacts on future (2030) PM2.5 are evaluated with three sensitivity simulations, assuming maximum feasible reduction technologies for either transportation, domestic, or electricity sectors. These simulations are compared with a business as usual 2030 simulation to assess relative sectoral impacts spatially and temporally. CMAQ is modeled at 12km by 12km and include biogenic emissions from the Community Land Model coupled with the Model of Emissions of Gases and Aerosols in Nature (CLM-MEGAN), biomass burning emissions from the Global Fires Emissions Database (GFED), and ERA-Interim meteorology generated with the Weather Research and Forecasting (WRF) model for 2010 to quantify the impact of modified anthropogenic emissions on ambient PM2.5 concentrations. Energy sector emissions analysis supports decision-making to improve future air quality and public health in

  14. Estimate of the emissions of methane in a dairy farm and a proposal of mitigation

    International Nuclear Information System (INIS)

    Schmidt, R; Alvarez, E; Gely, M; Pagano, A; Crozza, D

    2005-01-01

    The methane represents one of the most potent greenhouse gas and recent inventories express that the systems of handling of the manure of the livestock have influence in the global emissions of methane (Martinez et. al, 2003).This residue, during the periods of storage to open sky, suffers a natural anaerobic decomposition and gases like ammonium, hydrogen, sulfhydric, methane and dioxide of carbon; are generated and emitted to the atmosphere (EPA, 1999, Misselbrook et. al, 2001; Martinez et. al, 2003).In a report presented by the EPA (EPA, 1999) it was estimated that the methane emission originated in United States (1997) for the handling of the manure of the livestock ascended to 3.0 T g., what represents 10% of the total content of the methane emissions in that country.It is also expected that these emissions caused by the cattle residual grow above 25% from the 2000 to the 2020.In Argentina, and in particular in the region that includes the territorial space of the present study, in the Party of Olavarria located in the center of the Buenos Aires Province, it is considered that there are 8265 heads of bovine livestock, distributed under different forms of exploitation, dairy farms, cattle-breeding ranch and feedlots.These figures show the clearly incipient advance of the bovine livestock in this area, showing that the values of generated methane can influence thoroughly in the contribution of the greenhouse gas.The objective of the present study resides in carrying out an estimate of the equivalent quantity of CO 2 that is emitted to the atmosphere and how much it could decrease if the methodology of anaerobic digestion is applied, for the conversion of the bovine manure in biogas

  15. Historical and future emission of hazardous air pollutants (HAPs) from gas-fired combustion in Beijing, China.

    Science.gov (United States)

    Xue, Yifeng; Nie, Lei; Zhou, Zhen; Tian, Hezhong; Yan, Jing; Wu, Xiaoqing; Cheng, Linglong

    2017-07-01

    The consumption of natural gas in Beijing has increased in the past decade due to energy structure adjustments and air pollution abatement. In this study, an integrated emission inventory of hazardous air pollutants (HAPs) emitted from gas-fired combustion in Beijing was developed for the period from 2000 to 2014 using a technology-based approach. Future emission trends were projected through 2030 based on current energy-related and emission control policies. We found that emissions of primary HAPs exhibited an increasing trend with the rapid increase in natural gas consumption. Our estimates indicated that the total emissions of NO X , particulate matter (PM) 10 , PM 2.5 , CO, VOCs, SO 2 , black carbon, Pb, Cd, Hg, As, Cr, Cu, Ni, Zn, polychlorinated dibenzo-p-dioxins and dibenzofurans, and benzo[a]pyrene from gas-fired combustion in Beijing were approximately 22,422 t, 1042 t, 781 t, 19,097 t, 653 t, 82 t, 19 t, 0.6 kg, 0.1 kg, 43 kg, 52 kg, 0.3 kg, 0.03 kg, 4.3 kg, 0.6 kg, 216 μg, and 242 g, respectively, in 2014. To mitigate the associated air pollution and health risks caused by gas-fired combustion, stricter emission standards must be established. Additionally, combustion optimization and flue gas purification system could be used for lowering NO X emissions from gas-fired combustion, and gas-fired facilities should be continuously monitored based on emission limits. Graphical abstract Spatial distribution and typical live photos of gas-fired boiler in Beijing.

  16. Estimating historical landfill quantities to predict methane emissions

    NARCIS (Netherlands)

    Lyons, S.; Murphy, L.; Tol, R.S.J.

    2010-01-01

    There are no observations for methane emissions from landfill waste in Ireland. Methane emissions are imputed from waste data. There are intermittent data on waste sent to landfill. We compare two alternative ways to impute the missing waste " data" and evaluate the impact on methane emissions. We

  17. AIR PERMIT COMPLIANCE FOR WASTE RETRIEVAL OEPRATIONS INVOLVING MULTI-UNIT EMISSIONS

    International Nuclear Information System (INIS)

    SIMMONS FM

    2007-01-01

    Since 1970, approximately 38,000 suspect-transuranic and transuranic waste containers have been placed in retrievable storage on the Hanford Site in the 200 Areas burial grounds. Hanford's Waste Retrieval Project is retrieving these buried containers and processing them for safe storage and disposition. Container retrieval activities require an air emissions permit to account for potential emissions of radionuclides. The air permit covers the excavation activities as well as activities associated with assaying containers and installing filters in the retrieved transuranic containers lacking proper venting devices. Fluor Hanford, Inc. is required to track radioactive emissions resulting from the retrieval activities. Air, soil, and debris media contribute to the emissions and enabling assumptions allow for calculation of emissions. Each of these activities is limited to an allowed annual emission (per calendar year) and .contributes to the overall total emissions allowed for waste retrieval operations. Tracking these emissions is required to ensure a permit exceedance does not occur. A tracking tool was developed to calculate potential emissions in real time sense. Logic evaluations are established within the tracking system to compare real time data against license limits to ensure values are not exceeded for either an individual activity or the total limit. Data input are based on field survey and workplace air monitoring activities. This tracking tool is used monthly and quarterly to verify compliance to the license limits. Use of this tool has allowed Fluor Hanford, Inc. to successfully retrieve a significant number of containers in a safe manner without any exceedance of emission limits

  18. Estimating the Impact of US Agriculture Subsidies on Greenhouse Gas Emissions

    Science.gov (United States)

    Eshel, G.; Martin, P. A.

    2006-12-01

    It has been proposed in the popular media that US agricultural subsidies contribute deleteriously to both the American diet and environment. In this view, subsidies render mostly corn-based, animal products and sweeteners artificically cheap, leading to enhanced consumption. Problems accompanying this structure mentioned include enhanced meat, fat and sugar consumption and the associated enhancement of obesity, cardiovascular diseases, type II diabetes and possible various types of cancer, as well as air, soil and water pollution. Often overlooked in these discussions is the potential enhancement of greenhouse gas emissions accompanying this policy-based steering of food consumption toward certain products at the expense of others, possibly more nutritionally and environmentally benign. If such enhancements are in fact borne out by data, the policies that give rise to them will prove to constitute government-sponsored enhancement of greenhouse gas emissions, in contrast to any climate change mitigation efforts. If so, they represent low- hanging fruits in the national effort to reduce greenhouse gas emissions which may one day be launched. Agriculture subsidies impact the emissions of CO2 (by direct energy consumption), nitrous oxide (by land use alteration and manure management), and methane (by ruminant digestion and manure treatment). Quantifying the impacts of agricultural subsidies is complicated by many compounding and conflicting effects (many related to human behavior rather than the natural sciences) and the relatively short data timeseries. For example, subsidy policies change over time, certain subsidy types are introduced or eliminated, food preferences change as nutritional understanding (or propaganda) shift, etc. Despite the difficulties, such quantification is crucial to better estimate the overall effect and variability of dietary choices on greenhouse gas emissions, and ultimately minimize environmental impacts. In this study, we take preliminary

  19. Statistical estimate of mercury removal efficiencies for air pollution control devices of municipal solid waste incinerators.

    Science.gov (United States)

    Takahashi, Fumitake; Kida, Akiko; Shimaoka, Takayuki

    2010-10-15

    Although representative removal efficiencies of gaseous mercury for air pollution control devices (APCDs) are important to prepare more reliable atmospheric emission inventories of mercury, they have been still uncertain because they depend sensitively on many factors like the type of APCDs, gas temperature, and mercury speciation. In this study, representative removal efficiencies of gaseous mercury for several types of APCDs of municipal solid waste incineration (MSWI) were offered using a statistical method. 534 data of mercury removal efficiencies for APCDs used in MSWI were collected. APCDs were categorized as fixed-bed absorber (FA), wet scrubber (WS), electrostatic precipitator (ESP), and fabric filter (FF), and their hybrid systems. Data series of all APCD types had Gaussian log-normality. The average removal efficiency with a 95% confidence interval for each APCD was estimated. The FA, WS, and FF with carbon and/or dry sorbent injection systems had 75% to 82% average removal efficiencies. On the other hand, the ESP with/without dry sorbent injection had lower removal efficiencies of up to 22%. The type of dry sorbent injection in the FF system, dry or semi-dry, did not make more than 1% difference to the removal efficiency. The injection of activated carbon and carbon-containing fly ash in the FF system made less than 3% difference. Estimation errors of removal efficiency were especially high for the ESP. The national average of removal efficiency of APCDs in Japanese MSWI plants was estimated on the basis of incineration capacity. Owing to the replacement of old APCDs for dioxin control, the national average removal efficiency increased from 34.5% in 1991 to 92.5% in 2003. This resulted in an additional reduction of about 0.86Mg emission in 2003. Further study using the methodology in this study to other important emission sources like coal-fired power plants will contribute to better emission inventories. Copyright © 2010 Elsevier B.V. All rights

  20. National Emission Standards for Hazardous Air Pollutants—Calendar Year 2010 INL Report for Radionuclides (2011)

    Energy Technology Data Exchange (ETDEWEB)

    Mark Verdoorn; Tom Haney

    2011-06-01

    This report documents the calendar Year 2010 radionuclide air emissions and resulting effective dose equivalent to the maximally exposed individual member of the public from operations at the Department of Energy's Idaho National Laboratory Site. This report was prepared in accordance with the Code of Federal Regulations, Title 40, 'Protection of the Environment,' Part 61, 'National Emission Standards for Hazardous Air Pollutants,' Subpart H, 'National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.'

  1. Radionuclide air emission report for the Hanford Site Calendar Year 1993

    International Nuclear Information System (INIS)

    Diediker, L.P.; Curn, B.L.; Rhoads, K.; Damberg, E.G.; Soldat, J.K.; Jette, S.J.

    1994-01-01

    This report documents radionuclide air emissions from the Hanford Site in 1993 and the resulting effective dose equivalent to any member of the public. The report has been prepared and will be submitted in accordance with reporting requirements in the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, open-quotes National Emissions Standards for Hazardous Air Pollutants,close quotes Subpart H, open-quotes National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.close quotes

  2. Air emissions of small-scale (< 10 MW) biomass boilers. Review of three field tests

    International Nuclear Information System (INIS)

    Autret, E.

    2011-01-01

    Objectives of greenhouse gases emission reduction, which encourages bio-energy development for heat purposes, are compatible with air-quality policies if the concept of clean biomass combustion is applied. This paper presents actual emission levels of atmospheric pollutants of small-scale ( 2 , NO x , fine particulate matters, metallic compounds. Installation design (power, flue-gas cleaning techno logy) also has a major impact on organic pollutants and fine particulate matter emissions. A large majority of boilers have very low emission levels. Guidelines are finally stated to keep on promoting small-scale biomass boilers in order to be air-quality compatible and efficient to fight climate change. (author)

  3. Methane Emission Estimates in the Canadian Bakken Oil Fields from Mobile Lab Measurements

    Science.gov (United States)

    Staebler, R. M.; Li, S. M.; Liggio, J.; Worthy, D.; Lopez, M.; Narayan, J.; Darlington, A.

    2017-12-01

    Over the last few years, the progress in hydraulic fracturing methods to retrieve oil and gas from previously economically unviable sources has resulted in rapid expansion of the exploitation of fossil fuel containing shale plays across North America. These developments are associated with an increase in direct, local emissions of greenhouse gases (GHGs), including leakage from pipelines, wells and storage tanks. Several studies have been conducted, primarily in the US, to quantify these emissions both from the ground and from the air. In the fall of 2015, Environment and Climate Change Canada conducted a project with its mobile air quality lab CRUISER, instrumented with a suite of trace gas and aerosol instrumentation, in the southern Saskatchewan Bakken play, to investigate local emissions of GHGs. Measurement excursions were performed between 20/10/2015 and 17/11/2015 with a total driving time of 177 hours, for a total driving distance of 4897 km in the target area, potentially capturing 8822 wells and 480 tanks of the registered 28355 wells and 1666 tanks (31% and 29% respectively). Instrumentation relevant to this analysis included cavity ring-down and off-axis integrated cavity output spectrometers (Picarro Model G2201 and Los Gatos Research Model 9013 respectively), and ultrasonic anemometers mounted on the front and roof of CRUISER. Point source emission rates were estimated with two types of dispersion model, based on inputs of measured downwind concentration peaks above background and the measured wind speed and direction. Calibrated releases of N2O were conducted next to suspected CH4 sources in 228 cases to evaluate this approach. 50% of these cases reproduced the known N2O emission rate within a factor of 0.63 to 1.25. The associated CH4 emission rates were heavily skewed / nearly lognormal (25th, 50th and 75th percentiles: 1.2, 4.4 and 44 kg/h), confirming previously published findings that a few large emitters contribute the majority of the CH4

  4. Estimation of CO2 emissions from China’s cement production: Methodologies and uncertainties

    International Nuclear Information System (INIS)

    Ke, Jing; McNeil, Michael; Price, Lynn; Khanna, Nina Zheng; Zhou, Nan

    2013-01-01

    In 2010, China’s cement output was 1.9 Gt, which accounted for 56% of world cement production. Total carbon dioxide (CO 2 ) emissions from Chinese cement production could therefore exceed 1.2 Gt. The magnitude of emissions from this single industrial sector in one country underscores the need to understand the uncertainty of current estimates of cement emissions in China. This paper compares several methodologies for calculating CO 2 emissions from cement production, including the three main components of emissions: direct emissions from the calcination process for clinker production, direct emissions from fossil fuel combustion and indirect emissions from electricity consumption. This paper examines in detail the differences between common methodologies for each emission component, and considers their effect on total emissions. We then evaluate the overall level of uncertainty implied by the differences among methodologies according to recommendations of the Joint Committee for Guides in Metrology. We find a relative uncertainty in China’s cement-related emissions in the range of 10 to 18%. This result highlights the importance of understanding and refining methods of estimating emissions in this important industrial sector. - Highlights: ► CO 2 emission estimates are critical given China’s cement production scale. ► Methodological differences for emission components are compared. ► Results show relative uncertainty in China’s cement-related emissions of about 10%. ► IPCC Guidelines and CSI Cement CO 2 and Energy Protocol are recommended

  5. Future anthropogenic pollutant emissions in a Mediterranean port city with emphasis on the maritime sector emissions - Study of the impact on the city air quality

    Science.gov (United States)

    Liora, Natalia; Poupkou, Anastasia; Markakis, Konstantinos; Giannaros, Theodoros; Karagiannidis, Athanasios; Melas, Dimitrios

    2013-04-01

    The aim of this study is the estimation of the future emissions in the area of the large urban center of Thessaloniki (Greece) with emphasis on the emissions originated from the maritime sector within the port area of the city which are presented in detail. In addition, the contribution of the future anthropogenic emissions to atmospheric pollution levels in Thessaloniki focusing on PM levels is studied. A 2km spatial resolution anthropogenic gaseous and particulate matter emission inventory has been compiled for the port city of Thessaloniki for the year 2010 with the anthropogenic emission model MOSESS, developed by Laboratory of Atmospheric Physics of the Aristotle University of Thessaloniki. MOSESS was used for the estimation of emissions from several emission sources (road transport, central heating, industries, maritime sector etc) while the natural emission model NEMO was implemented for the calculation of dust, sea salt and biogenic emissions. Maritime emissions originated from the various processes inside the area of the port (harbor operations such as stockpiles, loading/unloading operations, machineries etc) as well as from the maritime transport sector including passenger ships, cargo shipping, inland waterways vessels (e.g. pleasure crafts) and fish catching ships. Ship emissions were estimated for the three operation modes; cruising, maneuvering and hotelling. For the calculation of maritime emissions, the activity data used were provided by local and national authorities (e.g.Thessaloniki Port Authority S.A.). Pollutant anthropogenic emissions were projected to the year 2020. The emissions from all the anthropogenic sources except for the maritime sector were projected using factors provided by the GAINS model. Future emissions from the maritime activities were estimated on the basis of the future activity data provided by the Port Authority and of the legislation for shipping in the future. Future maritime emissions are determined by the vessels

  6. Improving global fire carbon emissions estimates by combining moderate resolution burned area and active fire observations

    Science.gov (United States)

    Randerson, J. T.; Chen, Y.; Giglio, L.; Rogers, B. M.; van der Werf, G.

    2011-12-01

    In several important biomes, including croplands and tropical forests, many small fires exist that have sizes that are well below the detection limit for the current generation of burned area products derived from moderate resolution spectroradiometers. These fires likely have important effects on greenhouse gas and aerosol emissions and regional air quality. Here we developed an approach for combining 1km thermal anomalies (active fires; MOD14A2) and 500m burned area observations (MCD64A1) to estimate the prevalence of these fires and their likely contribution to burned area and carbon emissions. We first estimated active fires within and outside of 500m burn scars in 0.5 degree grid cells during 2001-2010 for which MCD64A1 burned area observations were available. For these two sets of active fires we then examined mean fire radiative power (FRP) and changes in enhanced vegetation index (EVI) derived from 16-day intervals immediately before and after each active fire observation. To estimate the burned area associated with sub-500m fires, we first applied burned area to active fire ratios derived solely from within burned area perimeters to active fires outside of burn perimeters. In a second step, we further modified our sub-500m burned area estimates using EVI changes from active fires outside and within of burned areas (after subtracting EVI changes derived from control regions). We found that in northern and southern Africa savanna regions and in Central and South America dry forest regions, the number of active fires outside of MCD64A1 burned areas increased considerably towards the end of the fire season. EVI changes for active fires outside of burn perimeters were, on average, considerably smaller than EVI changes associated with active fires inside burn scars, providing evidence for burn scars that were substantially smaller than the 25 ha area of a single 500m pixel. FRP estimates also were lower for active fires outside of burn perimeters. In our

  7. Autonomous mobile platform for monitoring air emissions from industrial and municipal wastewater ponds.

    Science.gov (United States)

    Fu, Long; Huda, Quamrul; Yang, Zheng; Zhang, Lucas; Hashisho, Zaher

    2017-11-01

    Significant amounts of volatile organic compounds and greenhouse gases are generated from wastewater lagoons and tailings ponds in Alberta, Canada. Accurate measurements of these air pollutants and greenhouse gases are needed to support management and regulatory decisions. A mobile platform was developed to measure air emissions from tailings pond in the oil sands region of Alberta. The mobile platform was tested in 2015 in a municipal wastewater treatment lagoon. With a flux chamber and a CO 2 /CH 4 sensor on board, the mobile platform was able to measure CO 2 and CH 4 emissions over two days at two different locations in the pond. Flux emission rates of CO 2 and CH 4 that were measured over the study period suggest the presence of aerobic and anaerobic zones in the wastewater treatment lagoon. The study demonstrated the capabilities of the mobile platform in measuring fugitive air emissions and identified the potential for the applications in air and water quality monitoring programs. The Mobile Platform demonstrated in this study has the ability to measure greenhouse gas (GHG) emissions from fugitive sources such as municipal wastewater lagoons. This technology can be used to measure emission fluxes from tailings ponds with better detection of spatial and temporal variations of fugitive emissions. Additional air and water sampling equipment could be added to the mobile platform for a broad range of air and water quality studies in the oil sands region of Alberta.

  8. The first 1-year-long estimate of the Paris region fossil fuel CO2 emissions based on atmospheric inversion

    Directory of Open Access Journals (Sweden)

    J. Staufer

    2016-11-01

    Full Text Available The ability of a Bayesian atmospheric inversion to quantify the Paris region's fossil fuel CO2 emissions on a monthly basis, based on a network of three surface stations operated for 1 year as part of the CO2-MEGAPARIS experiment (August 2010–July 2011, is analysed. Differences in hourly CO2 atmospheric mole fractions between the near-ground monitoring sites (CO2 gradients, located at the north-eastern and south-western edges of the urban area, are used to estimate the 6 h mean fossil fuel CO2 emission. The inversion relies on the CHIMERE transport model run at 2 km  ×  2 km horizontal resolution, on the spatial distribution of fossil fuel CO2 emissions in 2008 from a local inventory established at 1 km  ×  1 km horizontal resolution by the AIRPARIF air quality agency, and on the spatial distribution of the biogenic CO2 fluxes from the C-TESSEL land surface model. It corrects a prior estimate of the 6 h mean budgets of the fossil fuel CO2 emissions given by the AIRPARIF 2008 inventory. We found that a stringent selection of CO2 gradients is necessary for reliable inversion results, due to large modelling uncertainties. In particular, the most robust data selection analysed in this study uses only mid-afternoon gradients if wind speeds are larger than 3 m s−1 and if the modelled wind at the upwind site is within ±15° of the transect between downwind and upwind sites. This stringent data selection removes 92 % of the hourly observations. Even though this leaves few remaining data to constrain the emissions, the inversion system diagnoses that their assimilation significantly reduces the uncertainty in monthly emissions: by 9 % in November 2010 to 50 % in October 2010. The inverted monthly mean emissions correlate well with independent monthly mean air temperature. Furthermore, the inverted annual mean emission is consistent with the independent revision of the AIRPARIF inventory for the year

  9. Pacific Northwest National Laboratory Site Radionuclide Air Emissions Report for Calendar Year 2012

    Energy Technology Data Exchange (ETDEWEB)

    Snyder, Sandra F.; Barnett, J. Matthew; Bisping, Lynn E.

    2013-06-06

    This report documents radionuclide air emissions that result in the highest effective dose equivalent (EDE) to a member of the public, referred to as the maximally exposed individual (MEI). The report has been prepared in compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities and Washington Administrative Code (WAC) Chapter 246-247, Radiation Protection Air Emissions. The dose to the PNNL Site MEI due to routine major and minor point source emissions in 2012 from PNNL Site sources is 9E-06 mrem (9E-08 mSv) EDE. The dose from fugitive emissions (i.e., unmonitored sources) is 1E-7 mrem (1E-9 mSv) EDE. The dose from radon emissions is 2E-6 mrem (2E-08 mSv) EDE. No nonroutine emissions occurred in 2012. The total radiological dose for 2012 to the MEI from all PNNL Site radionuclide emissions, including fugitive emissions and radon, is 1E-5 mrem (1E-7 mSv) EDE, or 100,000 times smaller than the federal and state standard of 10 mrem/yr, to which the PNNL Site is in compliance.

  10. Pacific Northwest National Laboratory Campus Radionuclide Air Emissions Report for Calendar Year 2013

    Energy Technology Data Exchange (ETDEWEB)

    Snyder, Sandra F.; Barnett, J. Matthew; Bisping, Lynn E.

    2014-06-01

    This report documents radionuclide air emissions that result in the highest effective dose equivalent (EDE) to a member of the public, referred to as the maximally exposed individual (MEI). The report has been prepared in compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities and Washington Administrative Code (WAC) Chapter 246-247, Radiation Protection Air Emissions. The dose to the PNNL Site MEI due to routine major and minor point source emissions in 2013 from PNNL Site sources is 2E-05 mrem (2E-07 mSv) EDE. The dose from fugitive emissions (i.e., unmonitored sources) is 2E-6 mrem (2E-8 mSv) EDE. The dose from radon emissions is 1E-11 mrem (1E-13 mSv) EDE. No nonroutine emissions occurred in 2013. The total radiological dose for 2013 to the MEI from all PNNL Site radionuclide emissions, including fugitive emissions and radon, is 2E-5 mrem (2E-7 mSv) EDE, or 100,000 times smaller than the federal and state standard of 10 mrem/yr, to which the PNNL Site is in compliance

  11. Updated greenhouse gas and criteria air pollutant emission factors and their probability distribution functions for electricity generating units

    International Nuclear Information System (INIS)

    Cai, H.; Wang, M.; Elgowainy, A.; Han, J.

    2012-01-01

    Greenhouse gas (CO 2 , CH 4 and N 2 O, hereinafter GHG) and criteria air pollutant (CO, NO x , VOC, PM 10 , PM 2.5 and SO x , hereinafter CAP) emission factors for various types of power plants burning various fuels with different technologies are important upstream parameters for estimating life-cycle emissions associated with alternative vehicle/fuel systems in the transportation sector, especially electric vehicles. The emission factors are typically expressed in grams of GHG or CAP per kWh of electricity generated by a specific power generation technology. This document describes our approach for updating and expanding GHG and CAP emission factors in the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model developed at Argonne National Laboratory (see Wang 1999 and the GREET website at http://greet.es.anl.gov/main) for various power generation technologies. These GHG and CAP emissions are used to estimate the impact of electricity use by stationary and transportation applications on their fuel-cycle emissions. The electricity generation mixes and the fuel shares attributable to various combustion technologies at the national, regional and state levels are also updated in this document. The energy conversion efficiencies of electric generating units (EGUs) by fuel type and combustion technology are calculated on the basis of the lower heating values of each fuel, to be consistent with the basis used in GREET for transportation fuels. On the basis of the updated GHG and CAP emission factors and energy efficiencies of EGUs, the probability distribution functions (PDFs), which are functions that describe the relative likelihood for the emission factors and energy efficiencies as random variables to take on a given value by the integral of their own probability distributions, are updated using best-fit statistical curves to characterize the uncertainties associated with GHG and CAP emissions in life-cycle modeling with GREET.

  12. Updated greenhouse gas and criteria air pollutant emission factors and their probability distribution functions for electricity generating units

    Energy Technology Data Exchange (ETDEWEB)

    Cai, H.; Wang, M.; Elgowainy, A.; Han, J. (Energy Systems)

    2012-07-06

    Greenhouse gas (CO{sub 2}, CH{sub 4} and N{sub 2}O, hereinafter GHG) and criteria air pollutant (CO, NO{sub x}, VOC, PM{sub 10}, PM{sub 2.5} and SO{sub x}, hereinafter CAP) emission factors for various types of power plants burning various fuels with different technologies are important upstream parameters for estimating life-cycle emissions associated with alternative vehicle/fuel systems in the transportation sector, especially electric vehicles. The emission factors are typically expressed in grams of GHG or CAP per kWh of electricity generated by a specific power generation technology. This document describes our approach for updating and expanding GHG and CAP emission factors in the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model developed at Argonne National Laboratory (see Wang 1999 and the GREET website at http://greet.es.anl.gov/main) for various power generation technologies. These GHG and CAP emissions are used to estimate the impact of electricity use by stationary and transportation applications on their fuel-cycle emissions. The electricity generation mixes and the fuel shares attributable to various combustion technologies at the national, regional and state levels are also updated in this document. The energy conversion efficiencies of electric generating units (EGUs) by fuel type and combustion technology are calculated on the basis of the lower heating values of each fuel, to be consistent with the basis used in GREET for transportation fuels. On the basis of the updated GHG and CAP emission factors and energy efficiencies of EGUs, the probability distribution functions (PDFs), which are functions that describe the relative likelihood for the emission factors and energy efficiencies as random variables to take on a given value by the integral of their own probability distributions, are updated using best-fit statistical curves to characterize the uncertainties associated with GHG and CAP emissions in life

  13. Conflict resolution and alert zone estimation in air traffic management

    Science.gov (United States)

    Kuo, Vincent Hao-Hung

    The current air traffic control (ATC) system provides separations among all aircraft through pre-defined routes and flight procedures, and active controller participation. In particular, en route separations are achieved by choices of different flight routes, different flight levels, and speed control. During the final descent approach over an extended terminal area, aircraft separations are achieved by speed changes, altitude changes, and path stretching. Recently, a concept of free flight has been proposed for future air traffic management. In the proposed free flight environment, aircraft operators can change flight paths in real time, in order to achieve the best efficiency for the aircraft. Air traffic controllers are only supposed to intervene when situation warrants, to resolve potential conflicts among aircraft. In both cases, there is a region around each aircraft called alert zone. As soon as another aircraft touches the alert zone of own aircraft, either the own aircraft or both aircraft must initiate avoidance maneuvers to resolve a potential conflict. This thesis develops a systematic approach based on nonlinear optimal control theories to estimate alert zones in two aircraft conflict scenarios. Specifically, point-mass aircraft models are used to describe aircraft motions. Separate uses of heading, speed, and altitude control are first examined, and then the synergetic use of two control authorities are studied. Both cooperative maneuvers (in which both aircraft act) and non-cooperative maneuvers (in which the own aircraft acts alone) are considered. Optimal control problems are formulated to minimize the initial relative separation between the two aircraft for all possible initial conditions, subject to the requirement that inter-aircraft separation at any time satisfies the separation requirement. These nonlinear optimal control problems are solved numerically using a collation approach and the NPSOL software line for nonlinear programming. In

  14. Estimating State-Specific Contributions to PM2.5- and O3-Related Health Burden from Residential Combustion and Electricity Generating Unit Emissions in the United States.

    Science.gov (United States)

    Penn, Stefani L; Arunachalam, Saravanan; Woody, Matthew; Heiger-Bernays, Wendy; Tripodis, Yorghos; Levy, Jonathan I

    2017-03-01

    Residential combustion (RC) and electricity generating unit (EGU) emissions adversely impact air quality and human health by increasing ambient concentrations of fine particulate matter (PM 2.5 ) and ozone (O 3 ). Studies to date have not isolated contributing emissions by state of origin (source-state), which is necessary for policy makers to determine efficient strategies to decrease health impacts. In this study, we aimed to estimate health impacts (premature mortalities) attributable to PM 2.5 and O 3 from RC and EGU emissions by precursor species, source sector, and source-state in the continental United States for 2005. We used the Community Multiscale Air Quality model employing the decoupled direct method to quantify changes in air quality and epidemiological evidence to determine concentration-response functions to calculate associated health impacts. We estimated 21,000 premature mortalities per year from EGU emissions, driven by sulfur dioxide emissions forming PM 2.5 . More than half of EGU health impacts are attributable to emissions from eight states with significant coal combustion and large downwind populations. We estimate 10,000 premature mortalities per year from RC emissions, driven by primary PM 2.5 emissions. States with large populations and significant residential wood combustion dominate RC health impacts. Annual mortality risk per thousand tons of precursor emissions (health damage functions) varied significantly across source-states for both source sectors and all precursor pollutants. Our findings reinforce the importance of pollutant-specific, location-specific, and source-specific models of health impacts in design of health-risk minimizing emissions control policies. Citation: Penn SL, Arunachalam S, Woody M, Heiger-Bernays W, Tripodis Y, Levy JI. 2017. Estimating state-specific contributions to PM 2.5 - and O 3 -related health burden from residential combustion and electricity generating unit emissions in the United States. Environ

  15. Relative impact of on-road vehicular and point-source industrial emissions of air pollutants in a medium-sized Andean city

    Science.gov (United States)

    González, C. M.; Gómez, C. D.; Rojas, N. Y.; Acevedo, H.; Aristizábal, B. H.

    2017-03-01

    Cities in emerging countries are facing a fast growth and urbanization; however, the study of air pollutant emissions and its dynamics is scarce, making their populations vulnerable to potential effects of air pollution. This situation is critical in medium-sized urban areas built along the tropical Andean mountains. This work assesses the contribution of on-road vehicular and point-source industrial activities in the medium-sized Andean city of Manizales, Colombia. Annual fluxes of criteria pollutants, NMVOC, and greenhouse gases were estimated. Emissions were dominated by vehicular activity, with more than 90% of total estimated releases for the majority of air pollutants. On-road vehicular emissions for CO (43.4 Gg/yr) and NMVOC (9.6 Gg/yr) were mainly associated with the use of motorcycles (50% and 81% of total CO and NMVOC emissions respectively). Public transit buses were the main source of PM10 (47%) and NOx (48%). The per-capita emission index was significantly higher in Manizales than in other medium-sized cities, especially for NMVOC, CO, NOx and CO2. The unique mountainous terrain of Andean cities suggest that a methodology based on VSP model could give more realistic emission estimates, with additional model components that include slope and acceleration. Food and beverage facilities were the main contributors of point-source industrial emissions for PM10 (63%), SOx (55%) and NOx (45%), whereas scrap metal recycling had high emissions of CO (73%) and NMVOC (47%). Results provide the baseline for ongoing research in atmospheric modeling and urban air quality, in order to improve the understanding of air pollutant fluxes, transport and transformation in the atmosphere. In addition, this emission inventory could be used as a tool to identify areas of public health exposure and provide information for future decision makers.

  16. Simulating smoke transport from wildland fires with a regional-scale air quality model: sensitivity to spatiotemporal allocation of fire emissions.

    Science.gov (United States)

    Garcia-Menendez, Fernando; Hu, Yongtao; Odman, Mehmet T

    2014-09-15

    Air quality forecasts generated with chemical transport models can provide valuable information about the potential impacts of fires on pollutant levels. However, significant uncertainties are associated with fire-related emission estimates as well as their distribution on gridded modeling domains. In this study, we explore the sensitivity of fine particulate matter concentrations predicted by a regional-scale air quality model to the spatial and temporal allocation of fire emissions. The assessment was completed by simulating a fire-related smoke episode in which air quality throughout the Atlanta metropolitan area was affected on February 28, 2007. Sensitivity analyses were carried out to evaluate the significance of emission distribution among the model's vertical layers, along the horizontal plane, and into hourly inputs. Predicted PM2.5 concentrations were highly sensitive to emission injection altitude relative to planetary boundary layer height. Simulations were also responsive to the horizontal allocation of fire emissions and their distribution into single or multiple grid cells. Additionally, modeled concentrations were greatly sensitive to the temporal distribution of fire-related emissions. The analyses demonstrate that, in addition to adequate estimates of emitted mass, successfully modeling the impacts of fires on air quality depends on an accurate spatiotemporal allocation of emissions. Copyright © 2014 Elsevier B.V. All rights reserved.

  17. Emissions databases for polycyclic aromatic compounds in the Canadian Athabasca oil sands region - development using current knowledge and evaluation with passive sampling and air dispersion modelling data

    Science.gov (United States)

    Qiu, Xin; Cheng, Irene; Yang, Fuquan; Horb, Erin; Zhang, Leiming; Harner, Tom

    2018-03-01

    Two speciated and spatially resolved emissions databases for polycyclic aromatic compounds (PACs) in the Athabasca oil sands region (AOSR) were developed. The first database was derived from volatile organic compound (VOC) emissions data provided by the Cumulative Environmental Management Association (CEMA) and the second database was derived from additional data collected within the Joint Canada-Alberta Oil Sands Monitoring (JOSM) program. CALPUFF modelling results for atmospheric polycyclic aromatic hydrocarbons (PAHs), alkylated PAHs, and dibenzothiophenes (DBTs), obtained using each of the emissions databases, are presented and compared with measurements from a passive air monitoring network. The JOSM-derived emissions resulted in better model-measurement agreement in the total PAH concentrations and for most PAH species concentrations compared to results using CEMA-derived emissions. At local sites near oil sands mines, the percent error of the model compared to observations decreased from 30 % using the CEMA-derived emissions to 17 % using the JOSM-derived emissions. The improvement at local sites was likely attributed to the inclusion of updated tailings pond emissions estimated from JOSM activities. In either the CEMA-derived or JOSM-derived emissions scenario, the model underestimated PAH concentrations by a factor of 3 at remote locations. Potential reasons for the disagreement include forest fire emissions, re-emissions of previously deposited PAHs, and long-range transport not considered in the model. Alkylated PAH and DBT concentrations were also significantly underestimated. The CALPUFF model is expected to predict higher concentrations because of the limited chemistry and deposition modelling. Thus the model underestimation of PACs is likely due to gaps in the emissions database for these compounds and uncertainties in the methodology for estimating the emissions. Future work is required that focuses on improving the PAC emissions estimation and

  18. Emissions databases for polycyclic aromatic compounds in the Canadian Athabasca oil sands region – development using current knowledge and evaluation with passive sampling and air dispersion modelling data

    Directory of Open Access Journals (Sweden)

    X. Qiu

    2018-03-01

    Full Text Available Two speciated and spatially resolved emissions databases for polycyclic aromatic compounds (PACs in the Athabasca oil sands region (AOSR were developed. The first database was derived from volatile organic compound (VOC emissions data provided by the Cumulative Environmental Management Association (CEMA and the second database was derived from additional data collected within the Joint Canada–Alberta Oil Sands Monitoring (JOSM program. CALPUFF modelling results for atmospheric polycyclic aromatic hydrocarbons (PAHs, alkylated PAHs, and dibenzothiophenes (DBTs, obtained using each of the emissions databases, are presented and compared with measurements from a passive air monitoring network. The JOSM-derived emissions resulted in better model–measurement agreement in the total PAH concentrations and for most PAH species concentrations compared to results using CEMA-derived emissions. At local sites near oil sands mines, the percent error of the model compared to observations decreased from 30 % using the CEMA-derived emissions to 17 % using the JOSM-derived emissions. The improvement at local sites was likely attributed to the inclusion of updated tailings pond emissions estimated from JOSM activities. In either the CEMA-derived or JOSM-derived emissions scenario, the model underestimated PAH concentrations by a factor of 3 at remote locations. Potential reasons for the disagreement include forest fire emissions, re-emissions of previously deposited PAHs, and long-range transport not considered in the model. Alkylated PAH and DBT concentrations were also significantly underestimated. The CALPUFF model is expected to predict higher concentrations because of the limited chemistry and deposition modelling. Thus the model underestimation of PACs is likely due to gaps in the emissions database for these compounds and uncertainties in the methodology for estimating the emissions. Future work is required that focuses on improving the PAC

  19. Air treatment techniques for abatement of emissions from intensive livestock production

    NARCIS (Netherlands)

    Melse, R.W.

    2009-01-01

    Keywords: Air treatment; Scrubber; Bioscrubber; Biofilter; Biotrickling filter; Ammonia; NH3; Odour; Livestock production; Animal husbandry; Pig; Poultry.

    Intensive livestock production is connected with a number of environmental effects, including emissions of ammonia (NH3), greenhouse

  20. Photoionization capable, extreme and vacuum ultraviolet emission in developing low temperature plasmas in air

    NARCIS (Netherlands)

    Stephens, J.; Fierro, A.; Beeson, S.; Laity, G.; Trienekens, D.; Joshi, R.P.; Dickens, J.; Neuber, A.

    2016-01-01

    Experimental observation of photoionization capable extreme ultraviolet and vacuum ultraviolet emission from nanosecond timescale, developing low temperature plasmas (i.e. streamer discharges) in atmospheric air is presented. Applying short high voltage pulses enabled the observation of the onset of

  1. CAPSULE REPORT: SOURCES AND AIR EMISSION CONTROL TECHNOLOGIES AT WASTE MANAGEMENT FACILITIES

    Science.gov (United States)

    The chemicals processed during waste management operations can volatilize into the atmosphere and cause carcinogenic or other toxic effects or contribute to ozone formation. Regulations have been developed to control air emissions from these operations. The EPA has promulgated st...

  2. Final Rule to Reduce Hazardous Air Emissions from Newly Built Stationary Combustion Turbines: Fact Sheet

    Science.gov (United States)

    This page contains an August 2003 fact sheet with information regarding the National Emissions Standards for Hazardous Air Pollutants (NESHAP) for Stationary Combustion Turbines. This document provides a summary of the information for this NESHAP.

  3. The indicative effects of inefficient urban traffic flow on fuel cost and exhaust air pollutant emissions

    CSIR Research Space (South Africa)

    Moselakgomo, M

    2015-07-01

    Full Text Available Poor urban traffic management such as poor intersection controls, congestions, illegal roadway blockages and construction works causes “stop-go” driving conditions with excessive idling resulting in wasted fuel and increased air pollutant emissions...

  4. 75 FR 75937 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

    Science.gov (United States)

    2010-12-07

    ... National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines... internal combustion engines. Subsequently, the Administrator received two petitions for reconsideration... Any industry using a stationary 2211 Electric power reciprocating internal generation, combustion...

  5. 76 FR 12923 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

    Science.gov (United States)

    2011-03-09

    ... National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines... pollutants for existing stationary spark ignition reciprocating internal combustion engines. The final rule... reciprocating internal combustion generation, engine. transmission, or distribution. 622110 Medical and surgical...

  6. 77 FR 60341 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

    Science.gov (United States)

    2012-10-03

    ... National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines; New Source Performance Standards for Stationary Internal Combustion Engines AGENCY: Environmental Protection... Pollutants for Stationary Reciprocating Internal Combustion Engines to solicit comment on specific issues...

  7. Cellulose Products Manufacturing: National Emission Standards for Hazardous Air Pollutants (NESHAP)

    Science.gov (United States)

    Read the National Emission Standards for Hazardous Air Pollutants (NESHAP) for Cellulose Products Manufacturing, see the rule history for this Maximum Achievable Control Technology (MACT), and find Compliance help for this source.

  8. Air emissions from sour-gas processing plants and dairy-cattle reproduction in Alberta, Canada.

    Science.gov (United States)

    Scott, H M; Soskolne, C L; Martin, S W; Shoukri, M M; Lissemore, K D; Coppock, R W; Guidotti, T L

    2003-02-15

    The dispersion of air pollutants from all 231 licensed sour-gas processing plants in Alberta, Canada, was modeled on a monthly basis over a 10-year period (1985-1994). Exposure estimates for sulfur dioxide (SO(2)-used as a surrogate for exposure to combusted emissions) then were assigned to 1382 provincial dairy farms using a geographical-information system. Individual average and peak exposure for periods prior to each of 15 months of age and conception (four exposure-averaging periods for each of two dispersion models) were estimated for 163,988 primiparous female dairy-cattle between 1986 and 1994. Monthly or annual average farm-site exposure estimates likewise were assigned to associated herd-level data sets for the biologically relevant period of interest for each of three additional reproductive outcomes: monthly herd-average calving interval, stillbirth risk, and twinning risk. In one of the main-effects models, the maximum (i.e., peak) monthly sour-gas exposure experienced by individual-animals from birth to conception was associated with an increased time to first-calving in the very-highest exposure category (hazard ratio=0.86, 95% CI=0.80, 0.92). This equates to a decreased hazard (lambda) of calving (in each month subsequent to 22 months of age) for the highest-exposure animals (lambda=0.170) versus the zero-exposure animals (lambda=0.198) in a model with referent values for agro-ecological region and season of birth. The dose-response was not consistent across the full range of exposure categories. There was significant (P=0.003) interaction of emissions with agro-ecological region. After accounting for the interaction, a more-consistent dose-response was evident for some (but not all) agro-ecological regions. This suggests that any effect of emissions on dairy-heifer reproduction is subject to modification by features of soil type, vegetative cover, and/or climate. The increase in monthly herd-average calving interval on farms exposed to the very

  9. Air quality enhancement by reducing emissions from electric power industry

    International Nuclear Information System (INIS)

    Hamzeh, Ali

    2006-01-01

    designed for one power station (Banias station) only. For other stations it is to design similar programs considering the actual situation of the station in concern. The program consists of the three projects: a capacity building training. Efficiency Management System (EMS) and Maintenance Management System (MMS). They are expected to improve the efficiency by about 13% and the production availability by 12%. Besides, the emission of pollutants (CO2 and SO2) would be reduced by 13%. The economic evaluation of the proposed action program has given promising results. While the projects are estimated to require USD 27.058 million, they are expected to save about USD 93.258 million over 8 years (which has a present value of USD 48.652 million). The projects have been developed in such details that thy can be easily applied. The developed environmental management program (EMP) for any power system in general and the developed action program of a power station as well, from the significance of my presentation. Both environmental programs can be applied to the real systems.(Author)

  10. SAFARI 2000 1-Degree Estimates of Burned Biomass, Area, and Emissions, 2000

    Data.gov (United States)

    National Aeronautics and Space Administration — A new method is used to generate spatial estimates of monthly averaged biomass burned area and spatial and temporal estimates of trace gas and aerosol emissions from...

  11. Application of the emission inventory model TEAM: Uncertainties in dioxin emission estimates for central Europe

    NARCIS (Netherlands)

    Pulles, M.P.J.; Kok, H.; Quass, U.

    2006-01-01

    This study uses an improved emission inventory model to assess the uncertainties in emissions of dioxins and furans associated with both knowledge on the exact technologies and processes used, and with the uncertainties of both activity data and emission factors. The annual total emissions for the

  12. Estimating PM2.5-associated mortality increase in California due to the Volkswagen emission control defeat device

    Science.gov (United States)

    Wang, Tianyang; Jerrett, Michael; Sinsheimer, Peter; Zhu, Yifang

    2016-11-01

    The Volkswagen Group of America (VW) was found by the US Environmental Protection Agency (EPA) and the California Air Resources Board (CARB) to have installed "defeat devices" and emit more oxides of nitrogen (NOx) than permitted under current EPA standards. In this paper, we quantify the hidden NOx emissions from this so-called VW scandal and the resulting public health impacts in California. The NOx emissions are calculated based on VW road test data and the CARB Emission Factors (EMFAC) model. Cumulative hidden NOx emissions from 2009 to 2015 were estimated to be over 3500 tons. Adult mortality changes were estimated based on ambient fine particulate matter (PM2.5) change due to secondary nitrate formation and the related concentration-response functions. We estimated that hidden NOx emissions from 2009 to 2015 have resulted in a total of 12 PM2.5-associated adult mortality increases in California. Most of the mortality increase happened in metropolitan areas, due to their high population and vehicle density.

  13. Multi-annual changes of NOx emissions in megacity regions: nonlinear trend analysis of satellite measurement based estimates

    Directory of Open Access Journals (Sweden)

    J. P. Burrows

    2010-09-01

    Full Text Available Hazardous impact of air pollutant emissions from megacities on atmospheric composition on regional and global scales is currently an important issue in atmospheric research. However, the quantification of emissions and related effects is frequently a difficult task, especially in the case of developing countries, due to the lack of reliable data and information. This study examines possibilities to retrieve multi-annual NOx emissions changes in megacity regions from satellite measurements of nitrogen dioxide and to quantify them in terms of linear and nonlinear trends. By combining the retrievals of the GOME and SCIAMACHY satellite instrument data with simulations performed by the CHIMERE chemistry transport model, we obtain the time series of NOx emission estimates for the 12 largest urban agglomerations in Europe and the Middle East in the period from 1996 to 2008. We employ then a novel method allowing estimation of a nonlinear trend in a noisy time series of an observed variable. The method is based on the probabilistic approach and the use of artificial neural networks; it does not involve any quantitative a priori assumptions. As a result, statistically significant nonlinearities in the estimated NOx emission trends are detected in 5 megacities (Bagdad, Madrid, Milan, Moscow and Paris. Statistically significant upward linear trends are detected in Istanbul and Tehran, while downward linear trends are revealed in Berlin, London and the Ruhr agglomeration. The presence of nonlinearities in NOx emission changes in Milan, Paris and Madrid is confirmed by comparison of simulated NOx concentrations with independent air quality monitoring data. A good quantitative agreement between the linear trends in the simulated and measured near surface NOx concentrations is found in London.

  14. Estimating radionuclide air concentrations near buildings: a screening approach

    International Nuclear Information System (INIS)

    Miller, C.W.; Yildiran, M.

    1984-01-01

    For some facilities that routinely release small amounts of radionuclides to the atmosphere, such as hospitals, research laboratories, contaminated clothing laundries, and others, it is necessary to estimate the dose to persons very near the buildings from which the releases occur. Such facilities need simple screening procedures which provide reasonable assurance that as long as the calculated dose is less than some fraction of a relevant dose limit no individual will receive a dose in excess of that limit. Screening procedures have been proposed for persons living within hundreds of meters to a few kilometers from a source of radioactive effluent. This paper examines a screening technique for estimating long-term average radionuclide air concentrations within approximately 100 m of a building from which the release occurs. The technique is based on a modified gaussion plume model (HB model) which considers the influence of the tallest building within 100 m and is independant of atmospheric stability and downwind distance. 4 references, 2 tables

  15. Methane Emissions from Bangladesh: Bridging the Gap Between Ground-based and Space-borne Estimates

    Science.gov (United States)

    Peters, C.; Bennartz, R.; Hornberger, G. M.

    2015-12-01

    Gaining an understanding of methane (CH4) emission sources and atmospheric dispersion is an essential part of climate change research. Large-scale and global studies often rely on satellite observations of column CH4 mixing ratio whereas high-spatial resolution estimates rely on ground-based measurements. Extrapolation of ground-based measurements on, for example, rice paddies to broad region scales is highly uncertain because of spatio-temporal variability. We explore the use of ground-based river stage measurements and independent satellite observations of flooded area along with satellite measurements of CH4 mixing ratio to estimate the extent of methane emissions. Bangladesh, which comprises most of the Ganges Brahmaputra Meghna (GBM) delta, is a region of particular interest for studying spatio-temporal variation of methane emissions due to (1) broadscale rice cultivation and (2) seasonal flooding and atmospheric convection during the monsoon. Bangladesh and its deltaic landscape exhibit a broad range of environmental, economic, and social circumstances that are relevant to many nations in South and Southeast Asia. We explore the seasonal enhancement of CH4 in Bangladesh using passive remote sensing spectrometer CH4 products from the SCanning Imaging Absorption SpectroMeter for Atmospheric CHartographY (SCIAMACHY) and the Atmospheric Infrared Sounder (AIRS). The seasonal variation of CH4 is compared to independent estimates of seasonal flooding from water gauge stations and space-based passive microwave water-to-land fractions from the Tropical Rainfall Measuring Mission Microwave Imager (TRMM-TMI). Annual cycles in inundation (natural and anthropogenic) and atmospheric CH4 concentrations show highly correlated seasonal signals. NOAA's HYSPLIT model is used to determine atmospheric residence time of ground CH4 fluxes. Using the satellite observations, we can narrow the large uncertainty in extrapolation of ground-based CH4 emission estimates from rice paddies

  16. Pacific Northwest National Laboratory Campus Radionuclide Air Emissions Report for Calendar Year 2014

    Energy Technology Data Exchange (ETDEWEB)

    Snyder, Sandra F. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Barnett, J. Matthew [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Bisping, Lynn E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-06-01

    This report documents radionuclide air emissions that result in the 2014 highest effective dose equivalent (EDE) to an offsite member of the public, referred to as the maximally exposed individual (MEI). The report has been prepared in compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, “National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities” and Washington Administrative Code (WAC) Chapter 246-247, “Radiation Protection–Air Emissions.” The dose to the PNNL Campus MEI due to routine major and minor point source emissions in 2014 from PNNL Campus sources is 2E 05 mrem (2E-07 mSv) EDE. The dose from all fugitive sources is 3E-6 mrem (3E-8 mSv) EDE. The dose from radon emissions is 1E-6 mrem (1E-8 mSv) EDE. No nonroutine emissions occurred in 2014. The total radiological dose for 2014 to the MEI from all PNNL Campus radionuclide emissions, including fugitive emissions and radon, is 3E-5 mrem (3E-7 mSv) EDE, or more than 100,000 times smaller than the federal and state standard of 10 mrem/yr, to which the PNNL Campus is in compliance.

  17. Pacific Northwest National Laboratory Campus Radionuclide Air Emissions Report for Calendar Year 2015

    Energy Technology Data Exchange (ETDEWEB)

    Snyder, Sandra F. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Barnett, J. Matthew [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Bisping, Lynn E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2016-06-01

    This report documents radionuclide air emissions that result in the 2015 highest effective dose equivalent (EDE) to an offsite member of the public, referred to as the maximally exposed individual (MEI). The report has been prepared in compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, “National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities” and Washington Administrative Code (WAC) Chapter 246-247, “Radiation Protection–Air Emissions.” The dose to the PNNL Campus MEI from routine major and minor point source emissions in 2015 from PNNL Campus sources is 2.6E-4 mrem (2.6E-6 mSv) EDE. The dose from all fugitive sources is 1.8E-6 mrem (1.8E-8 mSv) EDE. The dose from radon emissions is 4.4E-8 mrem (4.4E-10 mSv) EDE. No nonroutine emissions occurred in 2015. The total radiological dose to the MEI from all PNNL Campus radionuclide emissions, including fugitive emissions and radon, is 2.6E-4 mrem (2.6E-6 mSv) EDE, or more than 10,000 times less than the federal and state standard of 10 mrem/yr, with which the PNNL Campus is in compliance.

  18. Urban air chemistry and diesel vehicles emissions: Quantifying small and big hydrocarbons by CIMS to improve emission inventories

    Science.gov (United States)

    Jobson, B. T.; Derstroff, B.; Edtbauer, A.; VanderSchelden, G. S.; Williams, J.

    2017-10-01

    Emissions from vehicles are a major source of volatile organic compounds (VOCs) in urban environments. Photochemical oxidation of VOCs emitted from vehicle exhaust contributes to O3 and PM2.5 formation, harmful pollutants that major urban areas struggle to control. How will a shift to a diesel engine fleet impact urban air chemistry? Diesel vehicles are a growing fraction of the passenger vehicle fleet in Europe as a result of a deliberate policy to reduce energy consumption and CO2 emissions from the transportation sector (Sullivan et al., 2004). In countries such as France the diesel passenger fleet was already ∼50% of the total in 2009, up from 20% in 1995. Dunmore et al. (2015) have recently inferred that in London, HO radical loss rates to organic compounds is dominated by diesel engine emissions. In the US, increasingly more stringent vehicles emission standards and requirement for improved energy efficiency means spark ignition passenger vehicle emissions have declined significantly over the last 20 years, resulting in the urban diesel fleet traffic (freight trucks) having a growing importance as a source of vehicle pollution (McDonald et al., 2013). The recent scandal involving a major car manufacturer rigging emission controls for diesel passenger cars is a reminder that real world emissions of VOCs from diesel engines are not well understood nor thoroughly accounted for in air quality modeling.

  19. Marine vessel air emissions in B.C. and Washington State outside the GVRD and FVRD for the year 2000

    International Nuclear Information System (INIS)

    Quan, R.G.; Trask, T.C.; Cheng, K.C.

    2002-01-01

    Emissions inventories are used by government agencies as a tool for policy development and air quality management. Marine vessels have been identified as a major source of anthropogenic pollution in British Columbia. This report presents estimates of emissions from marine vessels in coastal areas in British Columbia outside of the Greater Vancouver Regional District (GVRD), the Fraser Valley Regional District (FVRD), and in Washington State for the year 2000. The project includes an update of emission estimates for each marine vessel category and an update of emission estimates for pollutants of interest, including carbon monoxide (CO), nitrogen oxides (NOx), particulate matter (PM), sulphur oxides (SOx), volatile organic compounds (VOCs), as well as inhalable fine particulates (PM10 and PM2.5) and greenhouse gases such as carbon dioxide, methane, nitrous oxide and ammonia. This report presented emissions results for both the Canadian and U.S. portions. It also includes both spatial and temporal allocation of emissions. Results indicate that ocean-going vessels are the major contributor to emissions of NOx, SOx, PM and greenhouse gases, accounting for 56, 93, 83, and 51 per cent of the total marine vessel emissions respectively. They also contribute 30 and 33 per cent to the marine totals for CO and VOCs. Harbour vessels contribute 22 and 24 per cent of NOx and greenhouse gases and 17 per cent of both CO and VOCs. Ferries contribute between 15 per cent and 23 per cent for CO, VOC, NOx and GHGs, but less than 9 per cent for SOx and PM. Fishing vessels contribute 1 per cent or less of all contaminants. Although recreational vessels are major contributors for CO and VOC, they contribute less than 2 per cent for all other contaminants. A comparison of 1995 and 2000 marine vessel inventory for British Columbia was presented and recommendations for improvements were presented. refs., tabs., figs.

  20. Airborne measurements of western U.S. wildfire emissions: Comparison with prescribed burning and air quality implications

    Science.gov (United States)

    Liu, Xiaoxi; Huey, L. Gregory; Yokelson, Robert J.; Selimovic, Vanessa; Simpson, Isobel J.; Müller, Markus; Jimenez, Jose L.; Campuzano-Jost, Pedro; Beyersdorf, Andreas J.; Blake, Donald R.; Butterfield, Zachary; Choi, Yonghoon; Crounse, John D.; Day, Douglas A.; Diskin, Glenn S.; Dubey, Manvendra K.; Fortner, Edward; Hanisco, Thomas F.; Hu, Weiwei; King, Laura E.; Kleinman, Lawrence; Meinardi, Simone; Mikoviny, Tomas; Onasch, Timothy B.; Palm, Brett B.; Peischl, Jeff; Pollack, Ilana B.; Ryerson, Thomas B.; Sachse, Glen W.; Sedlacek, Arthur J.; Shilling, John E.; Springston, Stephen; St. Clair, Jason M.; Tanner, David J.; Teng, Alexander P.; Wennberg, Paul O.; Wisthaler, Armin; Wolfe, Glenn M.

    2017-06-01

    Wildfires emit significant amounts of pollutants that degrade air quality. Plumes from three wildfires in the western U.S. were measured from aircraft during the Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS) and the Biomass Burning Observation Project (BBOP), both in summer 2013. This study reports an extensive set of emission factors (EFs) for over 80 gases and 5 components of submicron particulate matter (PM1) from these temperate wildfires. These include rarely, or never before, measured oxygenated volatile organic compounds and multifunctional organic nitrates. The observed EFs are compared with previous measurements of temperate wildfires, boreal forest fires, and temperate prescribed fires. The wildfires emitted high amounts of PM1 (with organic aerosol (OA) dominating the mass) with an average EF that is more than 2 times the EFs for prescribed fires. The measured EFs were used to estimate the annual wildfire emissions of carbon monoxide, nitrogen oxides, total nonmethane organic compounds, and PM1 from 11 western U.S. states. The estimated gas emissions are generally comparable with the 2011 National Emissions Inventory (NEI). However, our PM1 emission estimate (1530 ± 570 Gg yr-1) is over 3 times that of the NEI PM2.5 estimate and is also higher than the PM2.5 emitted from all other sources in these states in the NEI. This study indicates that the source of OA from biomass burning in the western states is significantly underestimated. In addition, our results indicate that prescribed burning may be an effective method to reduce fine particle emissions.

  1. Heritability estimates for methane emission in Holstein cows using breath measurements

    DEFF Research Database (Denmark)

    Lassen, Jan; Madsen, Jørgen; Løvendahl, Peter

    2012-01-01

    Enteric methane emission from ruminants contributes substantially to the greenhouse effect. Few studies have focused on the genetic variation in enteric methane emission from dairy cattle. The objective of this study was to estimate the heritability for enteric methane emission from Danish Holste...... to ketosis....

  2. Estimation of N2O emission factors for soils depending on environmental conditions and crop management

    NARCIS (Netherlands)

    Lesschen, J.P.; Velthof, G.L.

    2009-01-01

    Nitrous oxide (N2O) contributes 8% to anthropogenic global warming, of which about one third are direct emissions of agricultural soils. These N2O emissions are often estimated using the default IPCC 2006 emission factor of 1% of the amount of N applied for mineral fertilizer, manure and crop

  3. Contribution of milk production to global greenhouse gas emissions. An estimation based on typical farms.

    Science.gov (United States)

    Hagemann, Martin; Ndambi, Asaah; Hemme, Torsten; Latacz-Lohmann, Uwe

    2012-02-01

    Studies on the contribution of milk production to global greenhouse gas (GHG) emissions are rare (FAO 2010) and often based on crude data which do not appropriately reflect the heterogeneity of farming systems. This article estimates GHG emissions from milk production in different dairy regions of the world based on a harmonised farm data and assesses the contribution of milk production to global GHG emissions. The methodology comprises three elements: (1) the International Farm Comparison Network (IFCN) concept of typical farms and the related globally standardised dairy model farms representing 45 dairy regions in 38 countries; (2) a partial life cycle assessment model for estimating GHG emissions of the typical dairy farms; and (3) standard regression analysis to estimate GHG emissions from milk production in countries for which no typical farms are available in the IFCN database. Across the 117 typical farms in the 38 countries analysed, the average emission rate is 1.50 kg CO(2) equivalents (CO(2)-eq.)/kg milk. The contribution of milk production to the global anthropogenic emissions is estimated at 1.3 Gt CO(2)-eq./year, accounting for 2.65% of total global anthropogenic emissions (49 Gt; IPCC, Synthesis Report for Policy Maker, Valencia, Spain, 2007). We emphasise that our estimates of the contribution of milk production to global GHG emissions are subject to uncertainty. Part of the uncertainty stems from the choice of the appropriate methods for estimating emissions at the level of the individual animal.

  4. Future emissions and atmospheric fate of HFC-1234yf from mobile air conditioners in Europe.

    Science.gov (United States)

    Henne, Stephan; Shallcross, Dudley E; Reimann, Stefan; Xiao, Ping; Brunner, Dominik; O'Doherty, Simon; Buchmann, Brigitte

    2012-02-07

    HFC-1234yf (2,3,3,3-tetrafluoropropene) is under discussion for replacing HFC-134a (1,1,1,2-tetrafluoroethane) as a cooling agent in mobile air conditioners (MACs) in the European vehicle fleet. Some HFC-1234yf will be released into the atmosphere, where it is almost completely transformed to the persistent trifluoroacetic acid (TFA). Future emissions of HFC-1234yf after a complete conversion of the European vehicle fleet were assessed. Taking current day leakage rates and predicted vehicle numbers for the year 2020 into account, European total HFC-1234yf emissions from MACs were predicted to range between 11.0 and 19.2 Gg yr(-1). Resulting TFA deposition rates and rainwater concentrations over Europe were assessed with two Lagrangian chemistry transport models. Mean European summer-time TFA mixing ratios of about 0.15 ppt (high emission scenario) will surpass previously measured levels in background air in Germany and Switzerland by more than a factor of 10. Mean deposition rates (wet + dry) of TFA were estimated to be 0.65-0.76 kg km(-2) yr(-1), with a maxium of ∼2.0 kg km(-2) yr(-1) occurring in Northern Italy. About 30-40% of the European HFC-1234yf emissions were deposited as TFA within Europe, while the remaining fraction was exported toward the Atlantic Ocean, Central Asia, Northern, and Tropical Africa. Largest annual mean TFA concentrations in rainwater were simulated over the Mediterranean and Northern Africa, reaching up to 2500 ng L(-1), while maxima over the continent of about 2000 ng L(-1) occurred in the Czech Republic and Southern Germany. These highest annual mean concentrations are at least 60 t