WorldWideScience

Sample records for enriched injection gas

  1. Laser and gas centrifuge enrichment

    Science.gov (United States)

    Heinonen, Olli

    2014-05-01

    Principles of uranium isotope enrichment using various laser and gas centrifuge techniques are briefly discussed. Examples on production of high enriched uranium are given. Concerns regarding the possibility of using low end technologies to produce weapons grade uranium are explained. Based on current assessments commercial enrichment services are able to cover the global needs of enriched uranium in the foreseeable future.

  2. Effect of Hydrogen and Hydrogen Enriched Compressed Natural Gas Induction on the Performance of Rubber Seed Oil Methy Ester Fuelled Common Rail Direct Injection (CRDi Dual Fuel Engines

    Directory of Open Access Journals (Sweden)

    Mallikarjun Bhovi

    2017-06-01

    Full Text Available Renewable fuels are in biodegradable nature and they tender good energy security and foreign exchange savings. In addition they address environmental concerns and socio-economic issues. The present work presents the experimental investigations carried out on the utilization of such renewable fuel combinations for diesel engine applications. For this a single-cylinder four-stroke water cooled direct injection (DI compression ignition (CI engine provided with CMFIS (Conventional Mechanical Fuel Injection System was rightfully converted to operate with CRDi injection systems enabling high pressure injection of Rubber seed oil methyl ester (RuOME in the dual fuel mode with induction of varied gas flow rates of hydrogen and hydrogen enriched CNG (HCNG gas combinations. Experimental investigations showed a considerable improvement in dual fuel engine performance with acceptable brake thermal efficiency and reduced emissions of smoke, hydrocarbon (HC, carbon monoxide (CO and slightly increased nitric oxide (NOx emission levels for increased hydrogen and HCNG flow rates. Further CRDi facilitated dual fuel engine showed improved engine performance compared to CMFIS as the former enabled high pressure (900 bar injection of the RuOME and closer to TDC (Top Dead Centre as well. Combustion parameters such as ignition delay, combustion duration, pressure-crank angle and heat release rates were analyzed and compared with baseline data generated. Combustion analysis showed that the rapid rate of burning of hydrogen and HCNG along with air mixtures increased due to presence of hydrogen in total and in partial combination with CNG which further resulted into higher cylinder pressures and energy release rates. However, sustained research that can provide feasible engine technology operating on such fuels in dual fuel operation can pave the way for continued fossil fuel usage.

  3. Uranium enrichment by gas centrifuge

    International Nuclear Information System (INIS)

    Heriot, I.D.

    1988-01-01

    After recalling the physical principles and the techniques of centrifuge enrichment the report describes the centrifuge enrichment programmes of the various countries concerned and compares this technology with other enrichment technologies like gaseous diffusion, laser, aerodynamic devices and chemical processes. The centrifuge enrichment process is said to be able to replace with advantage the existing enrichment facilities in the short and medium term. Future prospects of the process are also described, like recycled uranium enrichment and economic improvements; research and development needs to achieve the economic prospects are also indicated. Finally the report takes note of the positive aspect of centrifuge enrichment as far as safeguards and nuclear safety are concerned. 27 figs, 113 refs

  4. A pulsed injection parahydrogen generator and techniques for quantifying enrichment

    Science.gov (United States)

    Feng, Bibo; Coffey, Aaron M.; Colon, Raul D.; Chekmenev, Eduard Y.; Waddell, Kevin W.

    2012-01-01

    A device is presented for efficiently enriching parahydrogen by pulsed injection of ambient hydrogen gas. Hydrogen input to the generator is pulsed at high pressure to a catalyst chamber making thermal contact with the cold head of a closed-cycle cryocooler maintained between 15 and 20 K. The system enables fast production (0.9 standard liters per minute) and allows for a wide range of production targets. Production rates can be systematically adjusted by varying the actuation sequence of high-pressure solenoid valves, which are controlled via an open source microcontroller to sample all combinations between fast and thorough enrichment by varying duration of hydrogen contact in the catalyst chamber. The entire enrichment cycle from optimization to quantification and storage kinetics are also described. Conversion of the para spin-isomer to orthohydrogen in borosilicate tubes was measured at 8 min intervals over a period of 64 h with a 12 T NMR spectrometer. These relaxation curves were then used to extract initial enrichment by exploiting the known equilibrium (relaxed) distribution of spin isomers with linear least squares fitting to a single exponential decay curve with an estimated error less than or equal to 1%. This procedure is time-consuming, but requires only one sample pressurized to atmosphere. Given that tedious matching to external references are unnecessary with this procedure, we find it to be useful for periodic inspection of generator performance. The equipment and procedures offer a variation in generator design that eliminate the need to meter flow while enabling access to increased rates of production. These tools for enriching and quantifying parahydrogen have been in steady use for 3 years and should be helpful as a template or as reference material for building and operating a parahydrogen production facility.

  5. Gas-phase UF6 enrichment monitor for enrichment plant safeguards

    International Nuclear Information System (INIS)

    Strittmatter, R.B.; Tape, J.W.

    1980-03-01

    An in-line enrichment monitor is being developed to provide real-time enrichment data for the gas-phase UF 6 feed stream of an enrichment plant. The nondestructive gamma-ray assay method can be used to determine the enrichment of natural UF 6 with a relative precision of better than 1% for a wide range of pressures

  6. Performance of CO2 enrich CNG in direct injection engine

    Science.gov (United States)

    Firmansyah, W. B.; Ayandotun, E. Z.; Zainal, A.; Aziz, A. R. A.; Heika, M. R.

    2015-12-01

    This paper investigates the potential of utilizing the undeveloped natural gas fields in Malaysia with high carbon dioxide (CO2) content ranging from 28% to 87%. For this experiment, various CO2 proportions by volume were added to pure natural gas as a way of simulating raw natural gas compositions in these fields. The experimental tests were carried out using a 4-stroke single cylinder spark ignition (SI) direct injection (DI) compressed natural gas (CNG) engine. The tests were carried out at 180° and 300° before top dead centre (BTDC) injection timing at 3000 rpm, to establish the effects on the engine performance. The results show that CO2 is suppressing the combustion of CNG while on the other hand CNG combustion is causing CO2 dissociation shown by decreasing CO2 emission with the increase in CO2 content. Results for 180° BTDC injection timing shows higher performance compared to 300° BTDC because of two possible reasons, higher volumetric efficiency and higher stratification level. The results also showed the possibility of increasing the CO2 content by injection strategy.

  7. Solid Organic Deposition During Gas Injection Studies

    DEFF Research Database (Denmark)

    Dandekar, Abhijit Y.; Andersen, Simon Ivar; Stenby, Erling Halfdan

    2000-01-01

    was also evident as oil fractions expelled from the top to bottom of the PVT cell were observed to vary in density, molecular weight, as well as darkness of color. The change in stability of the oil samples before and after the contact with gas was analyzed using flocculation threshold titration......Recently a series of first contact miscibility (swelling) experiments have been performed on undersaturated light and heavy oils using LPG rich and methane rich injection gases, in which solid organic deposition was observed. A compositional gradient in the oils during the gas injection process...... during the gas injection process in comparison with the standard asphaltenes in order to understand the mechanisms involved in asphaltene deposition....

  8. Performance and exhaust emission characteristics of direct-injection diesel engine fueled with enriched biodiesel

    International Nuclear Information System (INIS)

    Altaie, Mohamad A. Hasan; Janius, Rimfiel B.; Rashid, Umer; Taufiq-Yap, Yun Hin; Yunus, Robiah; Zakaria, Rabitah; Adam, Nor Mariah

    2015-01-01

    Highlights: • Enrichment of PME by MO addition leads to slightly improved BTE. • The enrichment leads to a remarkable reduction in BSFC. • The enrichment did not improve exhaust emissions relative to neat PME. • Cetane number shows to be the key properties that determined the emissions. - Abstract: Biodiesel is a renewable alternative diesel fuel derived from different feedstocks that may have significantly different fatty acid profiles and physiochemical properties. This study aimed to gain further insight into the use of biodiesel in a single-cylinder direct-injection diesel engine. The influences of the properties and compound structure of neat and enriched components of biodiesel on engine performance and exhaust emissions were compared with that of petrodiesel under full load conditions. The enriched blends for testing were prepared by adding methyl oleate (MO) to palm oil methyl ester (PME) at specified volumetric ratios (vol/vol%): PME80:MO20, PME70:MO30, PME60:MO40, and PME50:MO50. Furthermore, various physiochemical properties of neat and enriched blends were evaluated against the ASTM D6751 standard. The impact of key fuel properties of neat and enriched blends associated with the performance of engine and exhaust emissions was discussed. The experimental results exhibited that enriched blends yielded a lower brake torque with higher brake specific fuel consumption (BSFC) than the petroleum diesel because of lower calorific value. Intrinsic reductions in the carbon monoxide (CO) and hydrocarbon (HC) emissions, and exhaust gas temperature (EGT) were also observed, as well as a slight increase in nitrogen oxide (NOx) emission. In addition, enriched blends showed a noticeable improvement in BSFC, with a slight increase in CO emission, HC emission, EGT, and NOx emission over individual PME as a result of lower ignition quality and lower oxygen content. Consequently, biodiesel that possesses more saturated components, and higher oxygen content yields

  9. Gas injection in PLT: experimental overview

    Energy Technology Data Exchange (ETDEWEB)

    Schmidt, G. L.; Bretz, N. I.; Hawryluk, R. J.; Hosea, J. C.; Johnson, D. W.

    1977-01-01

    Cold gas injection serves both the obvious role of a particle source at the surface of the plasma and a more subtle role as one element in the process by which the relative impurity concentration and the MHD activity of a discharge are determined. Evidence offered by PLT experiments in support of these two widely recognized roles is considered.

  10. Gas injection pilot in the Hochleiten field

    Energy Technology Data Exchange (ETDEWEB)

    Potsch, K.; Ramberger, R.; Glantschnig, J.; Baumgarthuber, S.; Goessnitzer, F. [OMV AG, Wien (Austria)

    2004-07-01

    The Hochleiten field, located in the north of Vienna, is small in extension and highly compartmentalized. The main reservoir horizons are at a depth of approximately 1000 m. The oil quality shows high density and viscosity. Waterflood was initiated, but worked only in a part of the reservoir. Compartmentalization and lateral facies changes result in poor comunication and big pressure differences across the field. Some of the oil in place is not reached by primary or secondary recovery processes, and a solution was sought for accessing the bypassed oil. The screening process suggested gas injection as the most promising method. This contribution presents the first results of a field pilot project. Information will be given on the geology, additional lab work, and the realization in the field. The injection and production profiles of this pilot are presented. CO{sub 2} improved the inflow capacity of the injector, but the oil rates of the effected wells increased only slightly. In order to match the actual response of the reservoir, we had to adjust our reservoir model. Meanwhile N{sub 2} was injected as a tracer in one of the wells, to find out the preferred communication paths, before we proceeded with further gas injection. (orig.)

  11. Evolved gas composition monitoring by repetitive injection gas chromatography.

    Science.gov (United States)

    White, Robert L

    2015-11-20

    Performance characteristics and applications of a small volume gas chromatograph oven are described. Heating and cooling properties of the apparatus are evaluated and examples are given illustrating the advantages of greatly reducing the air bath volume surrounding fused silica columns. Fast heating and cooling of the oven permit it to be employed for repetitive injection analyses. By using fast gas chromatography separations to achieve short assay cycle times, the apparatus can be employed for on-line species-specific gas stream composition monitoring when volatile species concentrations vary on time scales of a few minutes or longer. This capability facilitates repeated sampling and fast gas chromatographic separations of volatile product mixtures produced during thermal analyses. Applications of repetitive injection gas chromatography-mass spectrometry evolved gas analyses to monitoring purge gas effluent streams containing volatile acid catalyzed polymer cracking products are described. The influence of thermal analysis and chromatographic experimental parameters on effluent sampling frequency are delineated. Copyright © 2015 Elsevier B.V. All rights reserved.

  12. Steam-injected gas turbine analysis: steam rates

    Science.gov (United States)

    Rice, I. G.

    1995-04-01

    This paper presents an analysis of steam rates in steam-injected gas turbines (simple and reheat). In considering a gas turbine of this type, the steam-injection flow is separated from the main gas stream for analysis. Dalton's and Avogadro's laws of partial pressure and gas mixtures are applied. Results obtained provide for the accurate determination of heat input, gas expansion based on partial pressures, and heat-rejection steam-enthalpy points.

  13. Injection molded pinched flow fractionation device for enrichment of somatic cells in cow milk

    DEFF Research Database (Denmark)

    Jensen, Marie Pødenphant; Marie, Rodolphe; Olesen, Tom

    2014-01-01

    . The enrichment was performed using an all-polymer pinched flow fractionation device fabricated by injection molding. The polymer chips were bonded to a 500 lm polymer foil using UV assisted thermal bonding. The quality of the final devices was reproducible and the injection molding process combined with the use...

  14. Mathematical analysis of intermittent gas injection model in oil production

    Science.gov (United States)

    Tasmi, Silvya, D. R.; Pudjo, S.; Leksono, M.; Edy, S.

    2016-02-01

    Intermittent gas injection is a method to help oil production process. Gas is injected through choke in surface and then gas into tubing. Gas forms three areas in tubing: gas column area, film area and slug area. Gas column is used to propel slug area until surface. A mathematical model of intermittent gas injection is developed in gas column area, film area and slug area. Model is expanding based on mass and momentum conservation. Using assume film thickness constant in tubing, model has been developed by Tasmi et. al. [14]. Model consists of 10 ordinary differential equations. In this paper, assumption of pressure in gas column is uniform. Model consist of 9 ordinary differential equations. Connection of several variables can be obtained from this model. Therefore, dynamics of all variables that affect to intermittent gas lift process can be seen from four equations. To study the behavior of variables can be analyzed numerically and mathematically. In this paper, simple mathematically analysis approach is used to study behavior of the variables. Variables that affect to intermittent gas injection are pressure in upstream valve and in gas column. Pressure in upstream valve will decrease when gas mass in valve greater than gas mass in choke. Dynamic of the pressure in the gas column will decrease and increase depending on pressure in upstream valve.

  15. Optimization of refrigeration system with gas-injected scroll compressor

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Baolong; Shi, Wenxing; Han, Linjun; Li, Xianting [Department of Building Science, Tsinghua University, Beijing 100084 (China)

    2009-11-15

    Gas refrigerant injection has been proven as an effective method to improve the performance of the scroll compressor and its refrigeration system under high compression ratio working conditions. Much research on the injected scroll compressor and its system has been conducted, but the universal control and design method is still lacking. A model of the refrigeration system with a gas-injected scroll compressor is developed in this paper. With this model, the effects of gas injection on the system and component parameters are investigated. Based on the identified evaporator characteristics and thermodynamic analysis, a set of general principles for the design and operation of the refrigeration or heat pump system with a gas-injected scroll compressor is proposed. (author)

  16. Defining the needs for gas centrifuge enrichment plants advanced safeguards

    Energy Technology Data Exchange (ETDEWEB)

    Boyer, Brian David [Los Alamos National Laboratory; Erpenbeck, Heather H [Los Alamos National Laboratory; Miller, Karen A [Los Alamos National Laboratory; Swinhoe, Martyn T [Los Alamos National Laboratory; Ianakiev, Kiril [Los Alamos National Laboratory; Marlow, Johnna B [Los Alamos National Laboratory

    2010-04-05

    Current safeguards approaches used by the International Atomic Energy Agency (IAEA) at gas centrifuge enrichment plants (GCEPs) need enhancement in order to verify declared low-enriched (LEU) production, detect undeclared LEU production and detect highly enriched uranium (HEU) production with adequate detection probability using nondestructive assay (NDA) techniques. At present inspectors use attended systems, systems needing the presence of an inspector for operation, during inspections to verify the mass and {sup 235}U enrichment of declared UF{sub 6} containers used in the process of enrichment at GCEPs. In verifying declared LEU production, the inspectors also take samples for off-site destructive assay (DA) which provide accurate data, with 0.1% to 0.5% measurement uncertainty, on the enrichment of the UF{sub 6} feed, tails, and product. However, taking samples of UF{sub 6} for off-site analysis is a much more labor and resource intensive exercise for the operator and inspector. Furthermore, the operator must ship the samples off-site to the IAEA laboratory which delays the timeliness of results and interruptions to the continuity of knowledge (CofK) of the samples during their storage and transit. This paper contains an analysis of possible improvements in unattended and attended NDA systems such as process monitoring and possible on-site analysis of DA samples that could reduce the uncertainty of the inspector's measurements and provide more effective and efficient IAEA GCEPs safeguards. We also introduce examples advanced safeguards systems that could be assembled for unattended operation.

  17. Increasing injectivity and productivity indexes of a gas well

    Energy Technology Data Exchange (ETDEWEB)

    Kirk, W.B.

    1972-05-09

    The injectivity and productivity indexes of a well in fluid commuication with a subterranean hydrocarbon reservoir used for the storage of hydrocarbon is enhanced by injecting 1 to 500 gal of a micellar dispersion per vertical foot of reservoir and then displacing the micellar dispersion out ito the reservoir. Preferably 0.1 to 50 volumes of water per volume of micellar dispersion is injected after the micellar dispersion and preferably gas is injected behind the water to displace substantially all of the water out into the reservoir and to re-establish a gas phase in the immediate vicinity of the well bore. (16 claims)

  18. Construction and characterization of valve for fast gas injection

    International Nuclear Information System (INIS)

    Ueda, M.; Rossi, J.O.; Aso, Y.; Mangueira, L.S.; Pereira, C.A.

    1989-01-01

    An electromagnetic valve for fast gas injection was built and characterized. This type of gas injection valve has been routinely applied to various plasma experiments: in magnetic confinement devices as TOKAMAK, RFP and Compact Toroids as well as intense ion beam and neutral particle generators. The valve is capable of injecting gas pulses with up to 80 m Torr peak pressure, rising time < 400 μs and duration time of 40 ms, in the present experimental set-up. It is easy to build and its components can be totally acquired in the country. (author)

  19. CENTAR gas centrifuge enrichment project: economics and engineering considerations

    International Nuclear Information System (INIS)

    Fishman, A.M.

    1977-01-01

    Description of some economic and engineering considerations of the CENTAR Associates' 3000000 SWU/yr gas centrifuge uranium enrichment plant project. The need for uranium enrichment facilities is discussed, and the advantages of using the centrifuge process rather than the presently used gaseous diffusion process are reviewed. A description of the CENTAR plant is given, highlighting the major features of the facility. Since the centiruges to be used in the plant account for approximately 50% of the capital cost of the project, the philosophy of their manufacture and procurement is discussed. Various design considerations which bear upon process economics are presented to give the reader an appreciation of the subtleties of the technology and the flexibility possible in plant design. Special attention is given to meeting the needs of the utility customer at the lowest possible cost

  20. Prediction of Gas Injection Performance for Heterogeneous Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Blunt, Martin J.; Orr, Jr., Franklin M.

    1999-12-20

    This report describes research carried out in the Department of Petroleum Engineering at Stanford University from September 1998 - September 1998 under the third year of a three-year Department of Energy (DOE) grant on the ''Prediction of Gas Injection Performance for Heterogeneous Reservoirs''. The research effort is an integrated study of the factors affecting gas injection, from the pore scale to the field scale, and involves theoretical analysis, laboratory experiments and numerical simulation. The research is divided into four main areas: (1) Pore scale modeling of three-phase flow in porous media; (2) Laboratory experiments and analysis of factors influencing gas injection performance at the core scale with an emphasis on the fundamentals of three-phase flow; (3) Benchmark simulations of gas injection at the field scale; and (4) Development of streamline-based reservoir simulator.

  1. Designing and analysis study of uranium enrichment with gas centrifuge

    International Nuclear Information System (INIS)

    Tsunetoshi Kai

    2006-01-01

    This note concerns a designing and analysis study of uranium enrichment with a gas centrifuge. At first, one dimensional model is presented and a conventional analytical method is applied to grasp the general idea of a centrifuge performance. Secondly, two-dimensional numerical method is adopted to describe the diffusion phenomena with assumption of simple flow patterns. Parametric surveys are made on the dimension of a centrifuge rotor, the gas feed, withdrawal and circulation system, and operation variables such as feed flow rate, cut and so on. Thirdly, full numerical solutions are obtained for the flow and diffusion equations in static state, using a modified version of the Newton method without neglect of any non-linear term. The numerical results are compared with the experimental data made by Beams et al. and Zippe, and found to be in good agreement. Further, the theoretical pressure and separative power are compared respectively with experimental ones on a comparatively recent centrifuge. The results reveal that the characteristics of separation performance of a centrifuge can be fully described by the present method. Some of inevitable problems are tackled regarding UF 6 gas isotope separation by centrifugation. To examine the influence of the extraneous light gas, the diffusion equations for ternary mixture are solved and also the flow field of binary mixture with large mass difference is obtained to simultaneously solve the Navier-Stokes equations and the diffusion equation.for binary case. Since the gas in the interior region of the rotor is so rarefied that the Navier-Stokes equations cease to be valid, the Burnett equations are solved.for gas flow in a rotating cylinder. Considering that the uranium recovered at a reprocessing plant includes 236 U besides 235 U and 238 U, the concentration distributions of the ternary gas isotopes are determined and a value function is defined for the evaluation of separative work for the multi-component mixture

  2. Large-volume on-column injections for gas chromatography.

    NARCIS (Netherlands)

    Ramalho, S.; Hankemeier, T.; de Jong, M.; Brinkman, U.A.T.; Vreuls, J.J.

    1996-01-01

    Large‐volume injection is an attractive means to improve detection limits when analyzing dilute sample extracts. There is now no need to achieve enrichment by means of solvent evaporation, which makes the total analytical procedure less reliable and less robust due to loss of volatile compounds. In

  3. Thermodynamic analysis of steam-injected advanced gas turbine cycles

    Science.gov (United States)

    Pandey, Devendra; Bade, Mukund H.

    2017-12-01

    This paper deals with thermodynamic analysis of steam-injected gas turbine (STIGT) cycle. To analyse the thermodynamic performance of steam-injected gas turbine (STIGT) cycles, a methodology based on pinch analysis is proposed. This graphical methodology is a systematic approach proposed for a selection of gas turbine with steam injection. The developed graphs are useful for selection of steam-injected gas turbine (STIGT) for optimal operation of it and helps designer to take appropriate decision. The selection of steam-injected gas turbine (STIGT) cycle can be done either at minimum steam ratio (ratio of mass flow rate of steam to air) with maximum efficiency or at maximum steam ratio with maximum net work conditions based on the objective of plants designer. Operating the steam injection based advanced gas turbine plant at minimum steam ratio improves efficiency, resulting in reduction of pollution caused by the emission of flue gases. On the other hand, operating plant at maximum steam ratio can result in maximum work output and hence higher available power.

  4. Systems approach used in the Gas Centrifuge Enrichment Plant

    International Nuclear Information System (INIS)

    Rooks, W.A. Jr.

    1982-01-01

    A requirement exists for effective and efficient transfer of technical knowledge from the design engineering team to the production work force. Performance-Based Training (PBT) is a systematic approach to the design, development, and implementation of technical training. This approach has been successfully used by the US Armed Forces, industry, and other organizations. The advantages of the PBT approach are: cost-effectiveness (lowest life-cycle training cost), learning effectiveness, reduced implementation time, and ease of administration. The PBT process comprises five distinctive and rigorous phases: Analysis of Job Performance, Design of Instructional Strategy, Development of Training Materials and Instructional Media, Validation of Materials and Media, and Implementation of the Instructional Program. Examples from the Gas Centrifuge Enrichment Plant (GCEP) are used to illustrate the application of PBT

  5. Solid Organic Deposition During Gas Injection Studies

    DEFF Research Database (Denmark)

    Dandekar, Abhijit Y.; Andersen, Simon Ivar; Stenby, Erling Halfdan

    2000-01-01

    was also evident as oil fractions expelled from the top to bottom of the PVT cell were observed to vary in density, molecular weight, as well as darkness of color. The change in stability of the oil samples before and after the contact with gas was analyzed using flocculation threshold titration....... The asphaltene content of the different oil samples were determined by the TP 143 method. The standard asphaltenes and the solid organic deposit recovered from the swelling tests were analyzed using FTIR, HPLC-SEC and H-1 NMR. The aim of these analyses is to reveal the molecular nature of the deposits formed...

  6. PREDICTION OF GAS INJECTION PERFORMANCE FOR HETEROGENEOUS RESERVOIRS

    Energy Technology Data Exchange (ETDEWEB)

    Martin J. Blunt; Franklin M. Orr Jr

    2000-06-01

    This final report describes research carried out in the Department of Petroleum Engineering at Stanford University from September 1996--May 2000 under a three-year grant from the Department of Energy on the ''Prediction of Gas Injection Performance for Heterogeneous Reservoirs''. The advances from the research include: new tools for streamline-based simulation including the effects of gravity, changing well conditions, and compositional displacements; analytical solutions to 1D compositional displacements which can speed-up gas injection simulation still further; and modeling and experiments that delineate the physics that is unique to three-phase flow.

  7. Prediction of Gas Injection Performance for Heterogeneous Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Franklin M. Orr, Jr; Martin J. Blunt

    1998-03-31

    This project performs research in four main areas: laboratory experiments to measure three-phase relative permeability; network modeling to predict three-phase relative perme- ability; benchmark simulations of gas injection and waterfl ooding at the field scale; and the development of fast streamline techniques to study field-scale oil. The aim of the work is to achieve a comprehensive description of gas injection processes from the pore to the core to the reservoir scale. In this report we provide a detailed description of our measurements of three-phase relative permeability.

  8. Numerical analysis of a microwave torch with axial gas injection

    Energy Technology Data Exchange (ETDEWEB)

    Gritsinin, S. I.; Davydov, A. M.; Kossyi, I. A., E-mail: kossyi@fpl.gpi.ru [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation); Kulumbaev, E. B. [National Research University Belgorod State University (Russian Federation); Lelevkin, V. M. [Kyrgyz-Russian Slavic University (Kyrgyzstan)

    2013-07-15

    The characteristics of a microwave discharge in an argon jet injected axially into a coaxial channel with a shortened inner electrode are numerically analyzed using a self-consistent equilibrium gas-dynamic model. The specific features of the excitation and maintenance of the microwave discharge are determined, and the dependences of the discharge characteristics on the supplied electromagnetic power and gas flow rate are obtained. The calculated results are compared with experimental data.

  9. Prediction of Gas Injection Performance for Heterogeneous Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Blunt, Michael J.; Orr, Franklin M.

    1999-05-26

    This report describes research carried out in the Department of Petroleum Engineering at Stanford University from September 1996 - September 1997 under the first year of a three-year Department of Energy grant on the Prediction of Gas Injection Performance for Heterogeneous Reservoirs. The research effort is an integrated study of the factors affecting gas injection, from the pore scale to the field scale, and involves theoretical analysis, laboratory experiments and numerical simulation. The original proposal described research in four main areas; (1) Pore scale modeling of three phase flow in porous media; (2) Laboratory experiments and analysis of factors influencing gas injection performance at the core scale with an emphasis on the fundamentals of three phase flow; (3) Benchmark simulations of gas injection at the field scale; and (4) Development of streamline-based reservoir simulator. Each stage of the research is planned to provide input and insight into the next stage, such that at the end we should have an integrated understanding of the key factors affecting field scale displacements.

  10. Prediction of Gas Injection Performance for Heterogeneous Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Blunt, M.J.; Orr, F.M. Jr.

    2001-03-26

    This report was an integrated study of the physics and chemistry affecting gas injection, from the pore scale to the field scale, and involved theoretical analysis, laboratory experiments and numerical simulation. Specifically, advances were made on streamline-based simulation, analytical solutions to 1D compositional displacements, and modeling and experimental measures of three-phase flow.

  11. Prediction of Gas Injection Performance for Heterogeneous Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Blunt, Martin J.; Orr, Franklin M.

    1999-05-17

    This report describes research carried out in the Department of Petroleum Engineering at Stanford University from September 1997 - September 1998 under the second year of a three-year grant from the Department of Energy on the "Prediction of Gas Injection Performance for Heterogeneous Reservoirs." The research effort is an integrated study of the factors affecting gas injection, from the pore scale to the field scale, and involves theoretical analysis, laboratory experiments, and numerical simulation. The original proposal described research in four areas: (1) Pore scale modeling of three phase flow in porous media; (2) Laboratory experiments and analysis of factors influencing gas injection performance at the core scale with an emphasis on the fundamentals of three phase flow; (3) Benchmark simulations of gas injection at the field scale; and (4) Development of streamline-based reservoir simulator. Each state of the research is planned to provide input and insight into the next stage, such that at the end we should have an integrated understanding of the key factors affecting field scale displacements.

  12. Theory of Gas Injection: Interaction of Phase Behavior and Flow

    Science.gov (United States)

    Dindoruk, B.

    2015-12-01

    The theory of gas injection processes is a central element required to understand how components move and partition in the reservoir as one fluid is displacing another (i.e., gas is displacing oil). There is significant amount of work done in the area of interaction of phase-behavior and flow in multiphase flow conditions. We would like to present how the theory of gas injection is used in the industry to understand/design reservoir processes in various ways. The tools that are developed for the theory of gas injection originates from the fractional flow theory, as the first solution proposed by Buckley-Leveret in 1940's, for water displacing oil in porous media. After 1960's more and more complex/coupled equations were solved using the initial concept(s) developed by Buckley-Leverett, and then Welge et al. and others. However, the systematic use of the fractional flow theory for coupled set of equations that involves phase relationships (EOS) and phase appearance and disappearance was mainly due to the theory developed by Helfferich in early 80's (in petroleum literature) using method of characteristics primarily for gas injection process and later on by the systematic work done by Orr and his co-researchers during the last two decades. In this talk, we will present various cases that use and extend the theory developed by Helfferich and others (Orr et al., Lake et al. etc.). The review of various injection systems reveals that displacement in porous media has commonalities that can be represented with a unified theory for a class of problems originating from the theory of gas injection (which is in a way generalized Buckley-Leverett problem). The outcome of these solutions can be used for (and are not limited to): 1) Benchmark solutions for reservoir simulators (to quantify numerical dispersion, test numerical algorithms) 2) Streamline simulators 3) Design of laboratory experiments and their use (to invert the results) 4) Conceptual learning and to investigate

  13. Monitoring of density in tokamaks: pumping and gas injection

    International Nuclear Information System (INIS)

    Dejarnac, R.

    2002-11-01

    In thermonuclear fusion devices, controlling the Deuterium-Tritium fuel density and exhausting the Helium ashes is a crucial point. This is achieved by fuelling the discharges by different methods (gas puffing and pellet injection are the most commonly used) and by implementing pumping devices at the plasma periphery. These two issues are treated in this work, both from an experimental and a modelling point of view, using the neutral transport code EIRENE as main tool for our studies. As far as pumping is concerned, we have modelled the outboard pump limiter of the Tore Supra tokamak with the EIRENE code to which we coupled a plasma module specially developed to simulate the neutrals and the plasma in a coherent way. This allowed to validate the code against experimental data. As far as plasma fuelling is concerned, we present here an original method: the supersonic pulsed gas injection (SPGI). This intermediate method between conventional gas puff (GP) and pellet injection was designed and tested at Tore Supra. It consists of injecting very dense and short gas puffs at high speed into the plasma. Experimentally, SPGI was found to have a better fuelling efficiency than GP and to lead to a strong plasma cooling. The mechanisms responsible for this improved efficiency are analysed by modelling, using the EIRENE code to determine the ionisation source and a 1 D transport model to reproduce the plasma density response. At last, an extrapolation of the present injector is presented, discussing the possibility to obtain a radial drift of the injected matter as observed in the case of high field side pellet injection. (author)

  14. Hydrogen Gas as a Fuel in Direct Injection Diesel Engine

    Science.gov (United States)

    Dhanasekaran, Chinnathambi; Mohankumar, Gabriael

    2016-04-01

    Hydrogen is expected to be one of the most important fuels in the near future for solving the problem caused by the greenhouse gases, for protecting environment and saving conventional fuels. In this study, a dual fuel engine of hydrogen and diesel was investigated. Hydrogen was conceded through the intake port, and simultaneously air and diesel was pervaded into the cylinder. Using electronic gas injector and electronic control unit, the injection timing and duration varied. In this investigation, a single cylinder, KIRLOSKAR AV1, DI Diesel engine was used. Hydrogen injection timing was fixed at TDC and injection duration was timed for 30°, 60°, and 90° crank angles. The injection timing of diesel was fixed at 23° BTDC. When hydrogen is mixed with inlet air, emanation of HC, CO and CO2 decreased without any emission (exhaustion) of smoke while increasing the brake thermal efficiency.

  15. Nuclear material safeguards for enrichments plants: Part 4, Gas Centrifuge Enrichment Plant: Diversion scenarios and IAEA safeguards activities: Safeguards training course

    Energy Technology Data Exchange (ETDEWEB)

    1988-10-01

    This publication is Part 4 of a safeguards training course in Nuclear Material Safeguards for enrichment plants. This part of the course deals with diversion scenarios and safeguards activities at gas centrifuge enrichment plants.

  16. Safeguards approaches for conversion and gas centrifuge enrichment plants

    International Nuclear Information System (INIS)

    Stanuch, C.; Whitaker, M.; Lockwood, D.; Boyer, B.

    2013-01-01

    This paper describes recent studies and investigations of new safeguards measures and inspection tools to strengthen international safeguards at GCEPs (Gas Centrifuge Enrichment Plants) and conversion plants. The IAEA has indicated that continuous, unattended process monitoring should play a central role in future safeguards approaches for conversion plants and GCEPs. Monitoring safeguards relevant information from accountancy scales, process load cells, and unit header pipes can make existing safeguards approaches more efficient by replacing repetitive, routine, labor-intensive inspection activities with automated systems. These systems can make the safeguards approach more effective by addressing more completely the safeguards objectives at these facilities. Automated collection and analysis of the data can further enable the IAEA to move towards a fully-information driven inspection regime with randomized (from the operator's perspective), short-notice inspections. The reduction in repetitive on-site inspection activities would also be beneficial to plant operators, but only if sensitive and proprietary information can be protected and the new systems prove to be reliable. New facilities that incorporate Safeguards by Design into the earliest design stages can facilitate the effective DIV (Design Information Verification) of the plant to allow the inspectors to analyze the capacity of the plant, to project maximum production from the plant, and to provide a focus on the areas in the plant where credible diversion scenarios could be attempted. Facilitating efficient nuclear material accountancy by simplifying process pipework and making flow measurement points more accessible can allow for easier estimation of plant holdup and a potential reduction in the number of person-days of inspection. Lastly, a universal monitoring standard that tracks the location, movement, and use of UF 6 cylinders may enhance the efficiency of operations at industry sites and would

  17. Simulation of performance and nitrogen oxide formation of a hydrogen-enriched diesel engine with the steam injection method

    Directory of Open Access Journals (Sweden)

    Gonca Guven

    2015-01-01

    Full Text Available In the present study, steam injection method (SIM is implemented to a hydrogen-enriched diesel engine in order to improve the levels of performance and NO emissions. As hydrogen enrichment method increases effective efficiency, NO emissions could be increased. However, the SIM is used to control NO emissions and improve the engine performance. Due to these positive effects, hydrogen enrichment and the SIMare applied into a diesel engine by using a two-zone combustion model for30% hydrogen enrichment of the fuel volume and 20% steam ratio of the fuel mass at full load conditions. The results obtained are compared with conventional diesel engine (D, steam injected diesel engine (D+S20, hydrogen-enriched diesel engine (D+H30 and hydrogen-enriched diesel engine with steam injection (D+H30+S20 in terms of performance and NO emissions. In the results, the effective efficiency and effective power improve up to 22.8% and %3.1, as NO emissions decrease up to 22.1%. Hence, the hydrogen enrichment with steam injection method is more environmentally friendly with better performance.

  18. Compressive properties of aluminum foams by gas injection method

    OpenAIRE

    Zhang Huiming; Chen Xiang; Fan Xueliu

    2012-01-01

    The compressive properties of aluminum foams by gas injection method are investigated under both quasi-static and dynamic compressive loads in this paper. The experimental results indicate that the deformation of the aluminum foams goes through three stages: elastic deforming, plastic deforming and densification stage, during both the quasi-static and dynamic compressions. The aluminum foams with small average cell size or low porosity have high yield strength. An increase in strain rate can ...

  19. Flue gas injection into gas hydrate reservoirs for methane recovery and carbon dioxide sequestration

    International Nuclear Information System (INIS)

    Yang, Jinhai; Okwananke, Anthony; Tohidi, Bahman; Chuvilin, Evgeny; Maerle, Kirill; Istomin, Vladimir; Bukhanov, Boris; Cheremisin, Alexey

    2017-01-01

    Highlights: • Flue gas was injected for both methane recovery and carbon dioxide sequestration. • Kinetics of methane recovery and carbon dioxide sequestration was investigated. • Methane-rich gas mixtures can be produced inside methane hydrate stability zones. • Up to 70 mol% of carbon dioxide in the flue gas was sequestered as hydrates. - Abstract: Flue gas injection into methane hydrate-bearing sediments was experimentally investigated to explore the potential both for methane recovery from gas hydrate reservoirs and for direct capture and sequestration of carbon dioxide from flue gas as carbon dioxide hydrate. A simulated flue gas from coal-fired power plants composed of 14.6 mol% carbon dioxide and 85.4 mol% nitrogen was injected into a silica sand pack containing different saturations of methane hydrate. The experiments were conducted at typical gas hydrate reservoir conditions from 273.3 to 284.2 K and from 4.2 to 13.8 MPa. Results of the experiments show that injection of the flue gas leads to significant dissociation of the methane hydrate by shifting the methane hydrate stability zone, resulting in around 50 mol% methane in the vapour phase at the experimental conditions. Further depressurisation of the system to pressures well above the methane hydrate dissociation pressure generated methane-rich gas mixtures with up to 80 mol% methane. Meanwhile, carbon dioxide hydrate and carbon dioxide-mixed hydrates were formed while the methane hydrate was dissociating. Up to 70% of the carbon dioxide in the flue gas was converted into hydrates and retained in the silica sand pack.

  20. Technical and economic feasibility study of flue gas injection in an Iranian oil field

    Directory of Open Access Journals (Sweden)

    Mohammad Ali Ahmadi

    2015-09-01

    The main aim of this research is to investigate various gas injection methods (N2, CO2, produced reservoir gas, and flue gas in one of the northern Persian gulf oil fields by a numerical simulation method. Moreover, for each scenario of gas injection technical and economical considerations are took into account. Finally, an economic analysis is implemented to compare the net present value (NPV of the different gas injection scenarios in the aforementioned oil field.

  1. Measurement of the enrichment of uranium in the pipework of a gas centrifuge enrichment plant

    International Nuclear Information System (INIS)

    Packer, T.W.; Lees, E.W.; Close, D.; Nixon, K.V.; Pratt, J.C.; Strittmatter, R.

    1985-01-01

    The US and UK have been separately working on the development of a NDA instrument to determine the enrichment of gaseous UF 6 at low pressures in cascade header pipework in line with the conclusions of the Hexapartite Safeguards Project viz. the instrument is capable of making a ''go/no go'' decision of whether the enrichment is less than/greater than 20%. Recently, there has been a series of very useful technical exchanges of ideas and information between the two countries. This has led to a technical formulation for such an instrumentation based on γ-ray spectrometry which, although plant-specific in certain features, nevertheless is based on the same physical principles. Experimental results from commercially operating enrichment plants are very encouraging and indicate that a complete measurement including set up time on the pipe should be attainable in about 30 minutes when measuring pipes of diameter around 110 mm. 5 refs., 4 figs

  2. Measurement of the enrichment of uranium-hexafluoride gas in product pipes in the centrifuge enrichment plant at Almelo

    International Nuclear Information System (INIS)

    Packer, T.W.; Lees, E.W.; Aaldijk, J.K.; Harry, R.J.S.

    1987-09-01

    One of the objectives of safeguarding centrifuge enrichment plants is to apply non-destructive measurements inside the cascade area to confirm that the enrichment level is in the low enriched uranium range. Research in the UK and USA has developed a NDA instrument which can confirm the presence of low enriched uranium on a rapid go/no go basis in cascade header pipework of their centrifuge enrichment plants. The instrument is based on a gamma spectroscopic measurement coupled with an X-ray fluorescence analysis. This report gives the results of measurements carried out at Almelo by the UKAEA Harwell, ECN Petten and KFA Juelich to determine if these techniques could be employed at Almelo and Gronau. The energy dispersive X-ray fluorescence analysis has been applied to determine the total mass of uranium in the gas phase, and the deposit correction technique and the two geometry technique have been applied at Almelo to correct the measured gamma intensities for those emitted by the deposit. After an executive summary the report discusses the principles of the two correction methods. A short description of the equipment precedes the presentation of the results of the measurements and the discussion. After the conclusions the report contains two appendices which contain the derivation of the formulae for the deposit correction technique and a discussion of the systematic errors of this technique. 8 figs.; 11 refs.; 6 tables

  3. Maximize Liquid Oil Production from Shale Oil and Gas Condensate Reservoirs by Cyclic Gas Injection

    Energy Technology Data Exchange (ETDEWEB)

    Sheng, James

    2017-11-17

    The current technology to produce shale oil reservoirs is the primary depletion using fractured wells (generally horizontal wells). The oil recovery is less than 10%. The prize to enhance oil recovery (EOR) is big. Based on our earlier simulation study, huff-n-puff gas injection has the highest EOR potential. This project was to explore the potential extensively and from broader aspects. The huff-n-puff gas injection was compared with gas flooding, water huff-n-puff and waterflooding. The potential to mitigate liquid blockage was also studied and the gas huff-n-puff method was compared with other solvent methods. Field pilot tests were initiated but terminated owing to the low oil price and the operator’s budget cut. To meet the original project objectives, efforts were made to review existing and relevant field projects in shale and tight reservoirs. The fundamental flow in nanopores was also studied.

  4. Enrichment study of hot intra-cluster gas through X-ray spectroscopy

    NARCIS (Netherlands)

    Plaa, J. de

    2007-01-01

    Enrichment study of hot intra-cluster gas through X-ray spectroscopy Clouds of hot X-ray emitting gas associated with clusters of galaxies are the biggest aggregates of baryons that we know, except for the cosmic web. A typical cloud contains the nuclear-fusion products of billions of supernovae.

  5. Intravitreal gas injection for the treatment of diabetic macular edema

    Directory of Open Access Journals (Sweden)

    McHugh D

    2011-10-01

    Full Text Available Dominic McHugh, Bhaskar Gupta, Manzar Saeed King's College Hospital, Denmark Hill, London, England, UK Purpose: This study investigates the efficacy of an intravitreal gas injection in inducing a posterior vitreous detachment (PVD in patients with clinically significant diabetic macular edema refractory to laser therapy. Methods: A local ethics committee-approved technique of an intravitreal injection of pure perfluoropropane gas (C3F8 was performed for all participants. After a period of prone positioning, the patients underwent regular and detailed clinical review. Main outcome measures: The induction of a PVD, change in macular thickness, change in visual acuity. Results: A PVD was induced in all five eyes with subsequent signs of reduction in macular thickness and resolution of exudates. Mean visual improvement was 11 ETDRS (Early Treatment Diabetic Retinopathy Study letters (range 4–21. Apart from a transient vitreous hemorrhage in one eye, there were no significant treatment-related complications. Conclusion: The induction of a PVD by pneumatic retinopexy appears to have a significant influence on diabetic macular edema in eyes which have not successfully responded to macular laser therapy. A randomized clinical trial is justified on the basis of the initial promising data. Keywords: optical coherence tomography, OCT, posterior vitreous detachment, perfluoropropane

  6. Effect of oxygen enrichment in air on acid gas combustion under Claus conditions

    KAUST Repository

    Ibrahim, Salisu

    2013-09-01

    Results are presented to examine the combustion of acid gas (H2S and CO2) in hydrogen-fueled flames using a mixture of oxygen and nitrogen under Claus conditions (Φ = 3). Specifically the effect of oxygen enrichment in the above flames is examined. The compositions of acid gas examined are100% H2S and 50% H2S/50% CO2 with different percentages of oxygen enrichment (0%, 19.3% and 69.3%) in the oxygen/nitrogen mixtures. The results revealed that combustion of acid gas formed SO2 wherein the mole fraction of SO2 increased to an asymptotic value at all the oxygen concentrations examined. In addition, increase in oxygen enrichment of the air resulted in increased amounts of SO2 rather than the formation of more desirable elemental sulfur. In case of 50% H2S/50% CO2 acid gas, carbon monoxide mole fraction increased with oxygen enrichment which is an indicator to the availability of additional amounts of oxygen into the reaction pool. This gas mixture resulted in the formation of other sulfurous–carbonaceous compounds (COS and CS2) due to the presence of carbon monoxide. The results showed that the rate of COS formation increased with oxygen enrichment due to the availability of higher amounts of CO while that of CS2 reduced. The global reactions responsible for this observed phenomenon are presented.

  7. Study on atmospheric hydrogen enrichment by cryopump method and isotope separation by gas chromatography

    International Nuclear Information System (INIS)

    Taniyama, Yuki; Momoshima, Noriyuki

    2001-01-01

    To obtain the information of source of atmospheric hydrogen tritium an analysis of tritium isotopes is thought to be effective. So an atmospheric hydrogen enrichment apparatus and a cryogenic gas chromatographic column were made. Experiments were carried out to study the performance of cryopump to enrich atmospheric hydrogen and the column to separate hydrogen isotopes that obtained by cryopump method. The cryopump was able to process about 1000 1 atmosphere and the column was able to separate hydrogen isotopes with good resolution. (author)

  8. Fast, Approximate Solutions for 1D Multicomponent Gas Injection Problems

    DEFF Research Database (Denmark)

    Jessen, Kristian; Wang, Yun; Ermakov, Pavel

    2001-01-01

    by the geometry of key tie lines. It has previously been proven that for systems with an arbitrary number of components, the key tie lines can be approximated quite accurately by a sequence of intersecting tie lines. As a result, analytical solutions can be constructed efficiently for problems with constant......This paper presents a new approach for constructing approximate analytical solutions for ID, multicomponent gas displacement problems. The solution to mass conservation equations governing ID dispersion-free flow in which components partition between two equilibrium phases is controlled...... initial and injection compositions (Riemann problems). For fully self-sharpening systems, in which all key tie lines are connected by shocks, the analytical solutions obtained are rigorously accurate, while for systems in which some key tie lines are connected by spreading waves, the analytical solutions...

  9. Compressive properties of aluminum foams by gas injection method

    Directory of Open Access Journals (Sweden)

    Zhang Huiming

    2012-08-01

    Full Text Available The compressive properties of aluminum foams by gas injection method are investigated under both quasi-static and dynamic compressive loads in this paper. The experimental results indicate that the deformation of the aluminum foams goes through three stages: elastic deforming, plastic deforming and densification stage, during both the quasi-static and dynamic compressions. The aluminum foams with small average cell size or low porosity have high yield strength. An increase in strain rate can lead to an increase of yield strength. The yield strength of the aluminum foams under the dynamic loading condition is much greater than that under the quasi-static loading condition. Dynamic compressive tests show that a higher strain rate can give rise to a higher energy absorption capacity, which demonstrates that the aluminum foams have remarkable strain rate sensitivity on the loading rate.

  10. Numerical Simulation of Electric Controlled Injection Device Equipped on Gas Fuel Engine

    OpenAIRE

    Wenqing Ge; Yanjun Zhao; Bo Li; Binbin Sun

    2014-01-01

    Since there exist the problems of engine temping and combustion instability on the heavy-duty gas fuel engine based on single-point injection system, an electronically controlled multi-point injection system utilizing moving-coil electromagnetic linear actuator and mushrooms type valve structure was developed. The influence mechanism to gas fuel intake and mixing process caused by injection pulse width and installation site of the injection device was determined by the established CFD numeric...

  11. Modeling of noble gas injection into tokamak plasmas

    International Nuclear Information System (INIS)

    Morozov, D.Kh.; Yurchenko, E.I.; Lukash, V.E.; Baronova, E.O.; Rozhansky, V.A.; Senichenkov, I.Yu.; Veselova, I.Yu.; Schneider, R.

    2005-01-01

    Noble gas injection for mitigation of the disruption in DIII-D is simulated. The simulation of the first two stages is performed: of the neutral gas jet penetration through the background plasmas, and of the thermal quench. In order to simulate the first stage the 1.5-dimensional numerical code LLP with improved radiation model for noble gas is used. It is demonstrated that the jet remains mainly neutral and thus is able to penetrate to the central region of the tokamak in accordance with experimental observations. Plasma cooling at this stage is provided by the energy exchange with the jet. The radiation is relatively small, and the plasma thermal energy is spent mainly on the jet expansion. The magnetic surfaces in contact with the jet are cooled significantly. The cooling front propagates towards the plasma center. The simulations of the plasma column dynamics in the presence of moving jet is performed by means of the free boundary transport modeling DINA code. It has been shown that the cooling front is accompanied by strongly localized 'shark fin-like' perturbation in toroidal current density profile. After few milliseconds the jet (together with the current perturbation) achieves the region where safety factor is slightly higher than unity and a new type of the non-local kink mode develops. The unstable kink perturbation is non-resonant for any magnetic surface, both inside the plasma column, and in the vacuum space. The mode disturbs mainly the core region. The growth time of the 'shark fin-like' mode is higher than the Alfven time by a factor of 100 for DIII-D parameters. Hence, the simulation describes the DIII-D experimental results, at least, qualitatively. (author)

  12. Transient effects caused by pulsed gas and liquid injections into low pressure plasmas

    International Nuclear Information System (INIS)

    Ogawa, D; Goeckner, M; Overzet, L; Chung, C W

    2010-01-01

    The fast injection of liquid droplets into a glow discharge causes significant time variations in the pressure, the chemical composition of the gas and the phases present (liquid and/or solid along with gas). While the variations can be large and important, very few studies, especially kinetic studies, have been published. In this paper we examine the changes brought about in argon plasma by injecting Ar (gas), N 2 (gas) hexane (gas) and hexane (liquid droplets). The changes in the RF capacitively coupled power (forward and reflected), electron and ion density (n e , n i ), electron temperature (T e ) and optical emissions were monitored during the injections. It was found that the Ar injection (pressure change only) caused expected variations. The electron temperature reduced, the plasma density increased and the optical emission intensity remained nearly constant. The N 2 and hexane gas injections (chemical composition and pressure changes) also followed expected trends. The plasma densities increased and electron temperature decreased while the optical emissions changed from argon to the injected gas. These all serve to highlight the fact that the injection of evaporating hexane droplets in the plasma caused very little change. This is because the number of injected droplets is too small to noticeably affect the plasma, even though the shift in the chemical composition of the gas caused by evaporation from those same droplets can be very significant. The net conclusion is that using liquid droplets to inject precursors for low pressure plasmas is both feasible and controllable.

  13. Development of lab scale fast gas injection system for SST-1 Tokamak

    International Nuclear Information System (INIS)

    Pathan, F.S.; Banaudha, Moni; Khristi, Yohan; Khan, M.S.; Khan, Ziauddin; Raval, D.C.; Khirwadkar, Samir

    2017-01-01

    The plasma density control plays an important role in Tokamak operation. The factors that influence plasma density in a Tokamak device are working gas injection, pumping, ionization rate and the recycle coefficient representing the wall conditions. Among these factors, gas injection is relatively convenient to be controlled. Hence, the most frequently adopted method to control the plasma density is to control the fast gas injection. This paper describes the design and experimental work carried out towards the development of Fast Gas Injection System for SST-1 Tokamak. Laboratory based test setup was successfully established for Fast Gas Injection System that can feed predefined quantity of gas in a controlled manner into vacuum chamber. Further, this FGIS system will be implemented in SST-1 Tokamak environment with online density feedback signal

  14. Socioeconomic effects of the DOE Gas Centrifuge Enrichment Plant. Volume 1: methodology and analysis

    International Nuclear Information System (INIS)

    1979-01-01

    The socioeconomic effects of the Gas Centrifuge Enrichment Plant being built in Portsmouth, Ohio were studied. Chapters are devoted to labor force, housing, population changes, economic impact, method for analysis of services, analysis of service impacts, schools, and local government finance

  15. Direct injection of high pressure gas : scaling properties of pulsed turbulent jets

    NARCIS (Netherlands)

    Baert, R.S.G.; Klaassen, A.; Doosje, E.

    2010-01-01

    Existing gasoline DI injection equipment has been modified to generate single hole pulsed gas jets. Injection experiments have been performed at combinations of 3 different pressure ratios (2 of which supercritical) respectively 3 different hole geometries (i.e. length to diameter ratios). Injection

  16. Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions

    Science.gov (United States)

    Biruduganti, Munidhar S.; Gupta, Sreenath Borra; Sekar, R. Raj; McConnell, Steven S.

    2008-11-25

    A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

  17. Oil, Gas, and Injection Wells in Louisiana, Geographic NAD83, LDNR (2007) [oil_gas_wells_LDNR_2007

    Data.gov (United States)

    Louisiana Geographic Information Center — This is a point dataset containing the location of over 230,000 oil and gas and injection wells in the state of Louisiana. It was developed from the DNR Office of...

  18. Effect of administration of water enriched in O2 by injection or electrolysis on transcutaneous oxygen pressure in anesthetized pigs

    Science.gov (United States)

    Charton, Antoine; Péronnet, François; Doutreleau, Stephane; Lonsdorfer, Evelyne; Klein, Alexis; Jimenez, Liliana; Geny, Bernard; Diemunsch, Pierre; Richard, Ruddy

    2014-01-01

    Background Oral administration of oxygenated water has been shown to improve blood oxygenation and could be an alternate way for oxygen (O2) supply. In this experiment, tissue oxygenation was compared in anesthetized pigs receiving a placebo or water enriched in O2 by injection or a new electrolytic process. Methods Forty-two pigs randomized in three groups received either mineral water as placebo or water enriched in O2 by injection or the electrolytic process (10 mL/kg in the stomach). Hemodynamic parameters, partial pressure of oxygen in the arterial blood (PaO2), skin blood flow, and tissue oxygenation (transcutaneous oxygen pressure, or TcPO2) were monitored during 90 minutes of general anesthesia. Absorption and tissue distribution of the three waters administered were assessed using dilution of deuterium oxide. Results Mean arterial pressure, heart rate, PaO2, arteriovenous oxygen difference, and water absorption from the gut were not significantly different among the three groups. The deuterium to protium ratio was also similar in the plasma, skin, and muscle at the end of the protocol. Skin blood flow decreased in the three groups. TcPO2 slowly decreased over the last 60 minutes of the experiment in the three groups, but when compared to the control group, the values remained significantly higher in animals that received the water enriched in O2 by electrolysis. Conclusions In this protocol, water enriched in O2 by electrolysis lessened the decline of peripheral tissue oxygenation. This observation is compatible with the claim that the electrolytic process generates water clathrates which trap O2 and facilitate O2 diffusion along pressure gradients. Potential applications of O2-enriched water include an alternate method of oxygen supply. PMID:25210438

  19. Disruption mitigation with high-pressure helium gas injection on EAST tokamak

    Science.gov (United States)

    Chen, D. L.; Shen, B.; Granetz, R. S.; Qian, J. P.; Zhuang, H. D.; Zeng, L.; Duan, Y.; Shi, T.; Wang, H.; Sun, Y.; Xiao, B. J.

    2018-03-01

    High pressure noble gas injection is a promising technique to mitigate the effect of disruptions in tokamaks. In this paper, results of mitigation experiments with low-Z massive gas injection (helium) on the EAST tokamak are reported. A fast valve has been developed and successfully implemented on EAST, with valve response time  ⩽150 μs, capable of injecting up to 7 × 1022 particles, corresponding to 300 times the plasma inventory. Different amounts of helium gas were injected into stable plasmas in the preliminary experiments. It is seen that a small amount of helium gas (N_He≃ N_plasma ) can not terminate a discharge, but can trigger MHD activity. Injection of 40 times the plasma inventory impurity (N_He≃ 40× N_plasma ) can effectively radiate away part of the thermal energy and make the electron density increase rapidly. The mitigation result is that the current quench time and vertical displacement can both be reduced significantly, without resulting in significantly higher loop voltage. This also reduces the risk of runaway electron generation. As the amount of injected impurity gas increases, the gas penetration time decreases slowly and asymptotes to (˜7 ms). In addition, the impurity gas jet has also been injected into VDEs, which are more challenging to mitigate that stable plasmas.

  20. Safeguards considerations for uranium enrichment facilities, as applied to gas centrifuge and gaseous diffusion facilities

    International Nuclear Information System (INIS)

    1979-03-01

    The goals and objectives of IAEA safeguards as they are understood by the authors based on published documents are reviewed. These goals are then used to derive safeguards concerns, diversion strategies, and potential safeguards measures for four base cases, the production of highly enriched uranium (HEU) at a diffusion plant, the diversion of low enriched uranium (LEU) at a diffusion plant, the diversion of HEU at a gas centrifuge plant, and the diversion of LEU at a gas centrifuge plant. Tables of estimated capabilities are given for each case, under the assumption that the inspector would have access: to the cascade perimeter at or after the start of operations, to the cascade perimeter throughout construction and operation, to the cascade perimeter during operation plus a one-time access to the cascade itself, to the cascade during construction but only its perimeter during operation, or to the cascade itself during construction and operation

  1. Japan-IAEA sefeguards demonstration programme in the gas centrifuge uranium enrichment facility

    International Nuclear Information System (INIS)

    Akiba, Mitsunori; Iwamoto, Tomonori; Omae, Masayoshi

    1985-01-01

    The Hexa-partite Safequard Project was started for the purpose of examining the effective techniques of safeguards for gas centrifuge uranium enrichment facilities. By the proposal of respective participating countries, it was decided to carry out the verifying test of various safeguard techniques at the actual plants. Japan carried out the verifying test of safeguard techniques at the Ningyotoge uranium enrichment pilot plant in June, 1982, and from November, 1983, to August, 1984. The contents of this test is reported. In Japan, this verifying test was positioned as a part of JASPAS (Japanese project of supporting IAEA safeguards). The verifying test of realtime and in-operation inventories, the verifying test of IAEA load cell type weighing machines for UF 6 cylinders, the verifying test of the measurement of the degree of enrichment in UF 6 cylinders by nondestructive test, the verifying test of confinement/watch system, and the verifying test of IAEA gas phase uranium enrichment monitors were carried out. The results were presented as the data for examination in the HSP, and evaluated as useful, informative and well compiled. It is necessary to pursue more cost-effective approaches. (Kako, I.)

  2. Comparative Exergoeconomic Analyses of Gas Turbine Steam Injection Cycles with and without Fogging Inlet Cooling

    Directory of Open Access Journals (Sweden)

    Hassan Athari

    2015-09-01

    Full Text Available The results are reported of exergoeconomic analyses of a simple gas turbine cycle without a fogging system (SGT, a simple steam injection gas turbine cycle (STIG, and a steam injection gas turbine cycle with inlet fogging cooler (FSTIG. The results show that (1 a gas-turbine cycle with steam injection and simultaneous cooling has a higher power output than the other considered cycle; (2 at maximum energy efficiency conditions the gas turbine has the highest exergy efficiency of the cycle components and the lowest value of exergy efficiency is calculated for the fog cooler, where the mixing of air and water at greatly different temperatures causes the high exergy destruction; and (3 utilization of the fogging cooler in the steam injection cycle increases the exergy destruction in the combustion chamber. Furthermore, the simple gas turbine cycle is found to be more economic as its relative cost difference, total unit product cost, and exergoeconomic factors are less than those for the two other configurations. However, its efficiency and net power output are notably lower than for the gas turbine with steam injection and/or fog cooling. The total unit product cost is highest for the simple gas turbine with steam injection.

  3. Gas centrifuge enrichment plants inspection frequency and remote monitoring issues for advanced safeguards implementation

    Energy Technology Data Exchange (ETDEWEB)

    Boyer, Brian David [Los Alamos National Laboratory; Erpenbeck, Heather H [Los Alamos National Laboratory; Miller, Karen A [Los Alamos National Laboratory; Ianakiev, Kiril D [Los Alamos National Laboratory; Reimold, Benjamin A [Los Alamos National Laboratory; Ward, Steven L [Los Alamos National Laboratory; Howell, John [GLASGOW UNIV.

    2010-09-13

    Current safeguards approaches used by the IAEA at gas centrifuge enrichment plants (GCEPs) need enhancement in order to verify declared low enriched uranium (LEU) production, detect undeclared LEU production and detect high enriched uranium (BEU) production with adequate probability using non destructive assay (NDA) techniques. At present inspectors use attended systems, systems needing the presence of an inspector for operation, during inspections to verify the mass and {sup 235}U enrichment of declared cylinders of uranium hexafluoride that are used in the process of enrichment at GCEPs. This paper contains an analysis of how possible improvements in unattended and attended NDA systems including process monitoring and possible on-site destructive analysis (DA) of samples could reduce the uncertainty of the inspector's measurements providing more effective and efficient IAEA GCEPs safeguards. We have also studied a few advanced safeguards systems that could be assembled for unattended operation and the level of performance needed from these systems to provide more effective safeguards. The analysis also considers how short notice random inspections, unannounced inspections (UIs), and the concept of information-driven inspections can affect probability of detection of the diversion of nuclear material when coupled to new GCEPs safeguards regimes augmented with unattended systems. We also explore the effects of system failures and operator tampering on meeting safeguards goals for quantity and timeliness and the measures needed to recover from such failures and anomalies.

  4. EXTERNAL PHOTOEVAPORATION OF THE SOLAR NEBULA: JUPITER's NOBLE GAS ENRICHMENTS

    International Nuclear Information System (INIS)

    Monga, Nikhil; Desch, Steven

    2015-01-01

    We present a model explaining the elemental enrichments in Jupiter's atmosphere, particularly the noble gases Ar, Kr, and Xe. While He, Ne, and O are depleted, seven other elements show similar enrichments (∼3 times solar, relative to H). Being volatile, Ar is difficult to fractionate from H 2 . We argue that external photoevaporation by far-ultraviolet (FUV) radiation from nearby massive stars removed H 2 , He, and Ne from the solar nebula, but Ar and other species were retained because photoevaporation occurred at large heliocentric distances where temperatures were cold enough (≲ 30 K) to trap them in amorphous water ice. As the solar nebula lost H, it became relatively and uniformly enriched in other species. Our model improves on the similar model of Guillot and Hueso. We recognize that cold temperatures alone do not trap volatiles; continuous water vapor production is also necessary. We demonstrate that FUV fluxes that photoevaporated the disk generated sufficient water vapor in regions ≲ 30 K to trap gas-phase species in amorphous water ice in solar proportions. We find more efficient chemical fractionation in the outer disk: whereas the model of Guillot and Hueso predicts a factor of three enrichment when only <2% of the disk mass remains, we find the same enrichments when 30% of the disk mass remains. Finally, we predict the presence of ∼0.1 M ⊕ of water vapor in the outer solar nebula and protoplanetary disks in H II regions

  5. Effectiveness of oxygen enriched hydrogen-HHO gas addition on DI diesel engine performance, emission and combustion characteristics

    Directory of Open Access Journals (Sweden)

    Premkartikkumar S.R.

    2014-01-01

    Full Text Available Nowadays, more researches focus on protecting the environment. Present investigation concern with the effectiveness of Oxygen Enriched hydrogen- HHO gas addition on performance, emission and combustion characteristics of a DI diesel engine. Here the Oxygen Enriched hydrogen-HHO gas was produced by the process of water electrolysis. When potential difference is applied across the anode and cathode electrodes of the electrolyzer, water is transmuted into Oxygen Enriched hydrogen-HHO gas. The produced gas was aspirated into the cylinder along with intake air at the flow rates of 1 lpm and 3.3 lpm. The results show that when Oxygen Enriched hydrogen-HHO gas was inducted, the brake thermal efficiency of the engine increased by 11.06%, Carbon monoxide decreased by 15.38%, Unburned hydrocarbon decreased by 18.18%, Carbon dioxide increased by 6.06%, however, the NOX emission increased by 11.19%.

  6. Laboratory gas injection tests on compacted bentonite buffer material for TRU waste disposal

    International Nuclear Information System (INIS)

    Namiki, Kazuto; Asano, Hidekazu; Takahashi, Shinichi; Shimura, Tomoyuki; Hirota, Ken

    2012-01-01

    Document available in extended abstract form only. In order to evaluate the gas transport mechanism through the TRU waste disposal facility, it is important to understand the gas migration phenomena based on the previous results of relevant research. The conventional large scale gas migration tests were mainly carried out for the purpose of grasp of a phenomenon, under realistic site environment. On the other hand, the acquisition and expansion of fundamental data to the bentonite buffer material that is assumed for use in Japan are important. The Radioactive Waste Management Funding and Research Center is carrying out a series of laboratory gas injection tests with a view to acquiring the data on gas migration properties under the assumed disposal conditions/materials, in view of the fact that there are few examples of previously conducted gas injections, either in Japan or other countries. Two sizes of bentonite columns were taken with heights of 50 mm and 25 mm. Both types of columns had a diameter of 60 mm and a dry density of 1.36 Mg/m 3 . The test apparatus consists of a lower loading platform, a bentonite column mold, and a top loading platform. The bentonite columns were fully saturated and then gas was injected from the lower part of the bentonite column. A load cell was installed in the lower loading platform, and the swelling pressure of the sample was measured. The bentonite columns which have 90% of initial saturation were selected to reduce the duration for saturation. Moreover, the stepwise pressurization (0.05 MPa/day) approach was adopted for gas injection test. Gas/water permeability in saturated bentonite In the typical gas injection test, the water outflow from the outer section started to increase rapidly after the gas injection pressure reached 1.7 MPa, and then the gas breakthrough occurred at the injection pressure of 1.8 MPa. Once the gas breakthrough occurred, the amount of gas outflow from outer section increased uniformly until the

  7. Modeling and designing a new gas injection diffusion system for metalorganic chemical vapor deposition

    Science.gov (United States)

    Liao, C. C.; Hsiau, S. S.; Chuang, T. C.

    2018-01-01

    Metalorganic chemical vapor deposition (MOCVD) is a critical process and is widely used for the epitaxial growth of light-emitting diode (LED) wafers. The key component, a gas injection system, delivers the gas into the reactor by using a nozzle or showerhead. In this paper, the numerical simulation method was applied to investigate the thermal fluid field and to design a new gas injection system for MOCVD. In this study, we developed a new gas injection system with inlet barriers. The inlet barriers can separate the various reactive gases, reduce the prereaction, and prevent adducted particles from forming and blocking the inlet gas system. The barrier geometry, including the barrier length, the barrier inclination angle, and the V/III precursor ratio was systematically studied to determine the optimal design conditions. Higher growth rate and improved uniformity were demonstrated using the new optimal gas inlet barrier design.

  8. Simulation bidimensional of water and gas alternative injection; Simulacao bidimensional de injecao alternada de agua e gas

    Energy Technology Data Exchange (ETDEWEB)

    Santana, Ana Paula Silva C. de

    1999-07-01

    This dissertation presents a study of the unidimensional of water and gas alternate injection (WAG) using the stream line theory. It is considered incompressible fluid., unit mobility ratio, negligible capillary and gravitational effects, homogeneous and isotropic reservoir, isothermal flow two phases, oil and water, and three components, oil, water and gas. In the stream line theory, the following injection schemes are considered: staggered line five-spot, direct line and seven-spot. It is also considered that there is no flow among the streams. In the WAG calculations it is used the fractional flow theory and the method of characteristics, which consists of shock waves and rarefactions. The composition of these waves is said compatible if it satisfies the entropy condition. The solution goes through a certain path from the left to the right side constrained by the initial and boundary conditions. The gas injection is at a high pressure to ensure miscible displacement. It is considered first injection of a water bank and then, injection of a gas bank. We concluded that the gas injection at a high pressure recoveries all residual oil and the water saturation remains is greater than initial saturation. (author)

  9. Spin injection into a two-dimensional electron gas using inter-digital-ferromagnetic contacts

    DEFF Research Database (Denmark)

    Hu, C.M.; Nitta, J.; Jensen, Ane

    2002-01-01

    We present a model that describes the spin injection across a single interface with two electrodes. The spin-injection rate across a typical hybrid junction made of ferromagnet (FM) and a two-dimensional electron gas (2DEG) is found at the percentage level. We perforin spin-injection-detection ex......-injection-detection experiment on devices with two ferromagnetic contacts on a 2DEG confined in an InAs quantum well. A spin-injection rate of 4.5% is estimated from the measured magnetoresistance....

  10. Assessment of steam-injected gas turbine systems and their potential application

    Science.gov (United States)

    Stochl, R. J.

    1982-01-01

    Results were arrived at by utilizing and expanding on information presented in the literature. The results were analyzed and compared with those for simple gas turbine and combined cycles for both utility power generation and industrial cogeneration applications. The efficiency and specific power of simple gas turbine cycles can be increased as much as 30 and 50 percent, respectively, by the injection of steam into the combustor. Steam-injected gas turbines appear to be economically competitive with both simple gas turbine and combined cycles for small, clean-fuel-fired utility power generation and industrial cogeneration applications. For large powerplants with integrated coal gasifiers, the economic advantages appear to be marginal.

  11. Natural gas extraction and artificial gas injection experiments in Opalinus Clay, Mont Terri rock laboratory (Switzerland)

    Energy Technology Data Exchange (ETDEWEB)

    Vinsot, A.; Lundy, M. [Agence Nationale pour la Gestion des Déchets Radioactifs ANDRA, Meuse Haute-Marne Center, Bure (France); Appelo, C.A.J. [Dr C.A.J. Appelo, Hydrochemical Consultant, Amsterdam (Netherlands); and others

    2017-04-15

    Two experiments have been installed at Mont Terri in 2004 and 2009 that allowed gas circulation within a borehole at a pressure between 1 and 2 bar. These experiments made it possible to observe the natural gases that were initially dissolved in pore-water degassing into the borehole and to monitor their content evolution in the borehole over several years. They also allowed for inert (He, Ne) and reactive (H{sub 2}) gases to be injected into the borehole with the aim either to determine their diffusion properties into the rock pore-water or to evaluate their removal reaction kinetics. The natural gases identified were CO{sub 2}, light alkanes, He, and more importantly N{sub 2}. The natural concentration of four gases in Opalinus Clay pore-water was evaluated at the experiment location: N{sub 2} 2.2 mmol/L ± 25%, CH{sub 4} 0.30 mmol/L ± 25%, C{sub 2}H{sub 6} 0.023 mmol/L ± 25%, C{sub 3}H{sub 8} 0.012 mmol/L ± 25%. Retention properties of methane, ethane, and propane were estimated. Ne injection tests helped to characterize rock diffusion properties regarding the dissolved inert gases. These experimental results are highly relevant towards evaluating how the fluid composition could possibly evolve in the drifts of a radioactive waste disposal facility. (authors)

  12. The Effect of Injection Timings on Performance and Emissions of Compressed Natural-Gas Direct Injection Engine

    Directory of Open Access Journals (Sweden)

    Saad Aljamali

    2016-01-01

    Full Text Available This experimental part investigates the effect of injection timing on performance and emissions of homogenous mixture compressed natural-gas direct injection. The engine of 1.6 L capacity, 4 cylinders, spark ignition, and compression ratio of 14 was used. Performance and emission were recorded under wide-open throttle using an engine control system (Rotronics and the portable exhaust gas analyser (Kane. The engine was tested at speed ranging from 1500 revolutions per minute (RPM to 4000 RPM with 500 RPM increments. The engine control unit (ECU was modified using Motec 800. The injection timings investigated were at the end of injection (EOI 120 bTDC, 180 bTDC, 300 bTDC, and 360 bTDC. Results show high brake power, torque, and BMEP with 120 as compared with the other injection timings. At 4000 RPM the power, torque, and BMEP with 120 were 5% compared to that with 180. Furthermore, it shows low BSFC and high fuel conversion efficiency with 120. With 360, the engine produced less CO and CO2 at higher speeds.

  13. NACOWA experiments on LMFBR cover gas aerosols, heat transfer, and fission product enrichment

    International Nuclear Information System (INIS)

    Minges, J.; Schuetz, W.

    1993-12-01

    Fifteen different NACOWA test series were carried out. The following items were investigated: sodium mass concentration in the cover gas, sodium aerosol particle size, radiative heat transfer across the cover gas, total heat transfer across the cover gas, sodium deposition on the cover plate, temperature profiles across the cover gas, phenomena if the argon cover gas is replaced by helium, enrichment of cesium, iodine, and zinc in the aerosol and in the deposits. The conditions were mainly related to the design parameters of the EFR. According to the first consistent design, a pool temperature of 545 C and a roof temperature of only 120 C were foreseen at a cover gas height of 85 cm. The experiments were carried out in a stainless steel test vessel of 0.6 m diameter and 1.14 m height. Pool temperature (up to 545 C), cover gas height (12.5 cm, 33 cm, and others), and roof temperature (from 110 C to 450 C) were the main parameters. (orig./HP) [de

  14. Geochemical evaluation of CO2 injection and containment in a depleted gas field

    NARCIS (Netherlands)

    Tambach, T.J.; Koenen, M.; Wasch, L.J.; Bergen, F. van

    2015-01-01

    The short- and long-term geochemical impact of CO2 injection into a depleted gas reservoir (DGR) is investigated using reservoir/geochemical modeling with TOUGH2/TOUGHREACT and 1D kinetic diffusion modeling with PHREEQC (caprock/well-cement). Simulations of CO2 injection into the reservoir predict

  15. RADIO FREQUENCY IDENTIFICATION DEVICES: EFFECTIVENESS IN IMPROVING SAFEGUARDS AT GAS-CENTRIFUGE URANIUM-ENRICHMENT PLANTS

    International Nuclear Information System (INIS)

    JOE, J.

    2007-01-01

    Recent advances in radio frequency identification devices (RFIDs) have engendered a growing interest among international safeguards experts. Potentially, RFIDs could reduce inspection work, viz. the number of inspections, number of samples, and duration of the visits, and thus improve the efficiency and effectiveness of international safeguards. This study systematically examined the applications of RFIDs for IAEA safeguards at large gas-centrifuge enrichment plants (GCEPs). These analyses are expected to help identify the requirements and desirable properties for RFIDs, to provide insights into which vulnerabilities matter most, and help formulate the required assurance tests. This work, specifically assesses the application of RFIDs for the ''Option 4'' safeguards approach, proposed by Bruce Moran, U. S. Nuclear Regulatory Commission (NRC), for large gas-centrifuge uranium-enrichment plants. The features of ''Option 4'' safeguards include placing RFIDs on all feed, product and tails (F/P/T) cylinders, along with WID readers in all FP/T stations and accountability scales. Other features of Moran's ''Option 4'' are Mailbox declarations, monitoring of load-cell-based weighing systems at the F/P/T stations and accountability scales, and continuous enrichment monitors. Relevant diversion paths were explored to evaluate how RFIDs improve the efficiency and effectiveness of safeguards. Additionally, the analysis addresses the use of RFIDs in conjunction with video monitoring and neutron detectors in a perimeter-monitoring approach to show that RFIDs can help to detect unidentified cylinders

  16. Performance of an Otto cycle motor with natural gas direct injection; Desempenho de um motor ciclo Otto com injecao direta de gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Barbosa, Cleiton Rubens Formiga

    1997-07-01

    A Otto cycle engine with natural gas direct injection, during the inlet stroke, was submitted to runs with full power in a Foucaut dynamometer. The results obtained show a increase in the volumetric efficiency of the engine with natural gas direct injection when compared with natural gas injection applied in the inlet manifold, upstream of the throttle butterfly. In the conversion to natural gas direct injection, the technical characteristics were not changed. A kit for natural gas direct injection, with electronic management was located on the cylinder head of the test engine. Maintaining the pressure constant in the natural gas fuel line, using a reduction valve, the mass of fuel injected into the cylinder was regulated, varying the opening time of the solenoid valve fuel injector. Engine performance data is compared, emphasizing the factors that contribute to this increase in relative volumetric efficiency. Modifications are made to maximize the power of the engine with natural gas direct injection. (author)

  17. Novel preconcentration technique for on-line coupling to high-speed narrow-bore capillary gas chromatography: sample enrichment by equilibrium (ab)sorption. II. Coupling to a portable micro gas chromatograph.

    Science.gov (United States)

    Tuan, H P; Janssen, H G; Cramers, C A; Mussche, P; Lips, J; Wilson, N; Handley, A

    1997-12-12

    The technique of equilibrium (ab)sorption has been proven to be a powerful method for preconcentration of gaseous samples for high-speed narrow-bore capillary gas chromatography (GC) in general and field-portable GC instruments, often referred as micro GCs, in particular. Using a simple experimental set-up equipped with an open-tubular enrichment column it is possible to produce a homogeneously enriched sample plug, allowing reproducible injections of an enriched sample into the micro GC. Using a non-polar trapping column enrichment factors found for n-alkanes in the range of C7 to C10 ranged from 15 to 150 and agree well with calculated values. Using a highly retentive Thermocap column, the enrichment factor observed for heptane was above 500. As the use of this new preconcentration method requires only minimum modification of the micro GC, the chromatographic performance of the instrument was not compromised by direct coupling to the preconcentration device. Examples of on-line enrichment with portable micro GC analysis of VOCs from air are shown. These examples clearly demonstrate the potentials of the new method in field analysis.

  18. In situ water and gas injection experiments performed in the Hades Underground Research Facility

    International Nuclear Information System (INIS)

    Volckaert, G.; Ortiz, L.; Put, M.

    1995-01-01

    The movement of water and gas through plastic clay is an important subject in the research at SCK-CEN on the possible disposal of high level radioactive waste in the Boom clay layer at Mol. Since the construction of the Hades underground research facility in 1983, SCK-CEN has developed and installed numerous piezometers for the geohydrologic characterization and for in situ radionuclide migration experiments. In situ gas and water injection experiments have been performed at two different locations in the underground laboratory. The first location is a multi filter piezometer installed vertically at the bottom of the shaft in 1986. The second location is a three dimensional configuration of four horizontal multi piezometers installed from the gallery. This piezometer configuration was designed for the MEGAS (Modelling and Experiments on GAS migration through argillaceous rocks) project and installed in 1992. It contains 29 filters at distances between 10 m and 15 m from the gallery in the clay. Gas injection experiments show that gas breakthrough occurs at a gas overpressure of about 0.6 MPa. The breakthrough occurs by the creation of gas pathways along the direction of lowest resistance i.e. the zone of low effective stress resulting from the drilling of the borehole. The water injections performed in a filter -- not used for gas injection -- show that the flow of water is also influenced by the mechanical stress conditions. Low effective stress leads to higher hydraulic conductivity. However, water overpressures up to 1.3 MPa did not cause hydrofracturing. Water injections performed in a filter previously used for gas injections, show that the occluded gas hinders the water flow and reduces the hydraulic conductivity by a factor two

  19. Simulation study to determine the feasibility of injecting hydrogen sulfide, carbon dioxide and nitrogen gas injection to improve gas and oil recovery oil-rim reservoir

    Science.gov (United States)

    Eid, Mohamed El Gohary

    This study is combining two important and complicated processes; Enhanced Oil Recovery, EOR, from the oil rim and Enhanced Gas Recovery, EGR from the gas cap using nonhydrocarbon injection gases. EOR is proven technology that is continuously evolving to meet increased demand and oil production and desire to augment oil reserves. On the other hand, the rapid growth of the industrial and urban development has generated an unprecedented power demand, particularly during summer months. The required gas supplies to meet this demand are being stretched. To free up gas supply, alternative injectants to hydrocarbon gas are being reviewed to support reservoir pressure and maximize oil and gas recovery in oil rim reservoirs. In this study, a multi layered heterogeneous gas reservoir with an oil rim was selected to identify the most optimized development plan for maximum oil and gas recovery. The integrated reservoir characterization model and the pertinent transformed reservoir simulation history matched model were quality assured and quality checked. The development scheme is identified, in which the pattern and completion of the wells are optimized to best adapt to the heterogeneity of the reservoir. Lateral and maximum block contact holes will be investigated. The non-hydrocarbon gases considered for this study are hydrogen sulphide, carbon dioxide and nitrogen, utilized to investigate miscible and immiscible EOR processes. In November 2010, re-vaporization study, was completed successfully, the first in the UAE, with an ultimate objective is to examine the gas and condensate production in gas reservoir using non hydrocarbon gases. Field development options and proces schemes as well as reservoir management and long term business plans including phases of implementation will be identified and assured. The development option that maximizes the ultimate recovery factor will be evaluated and selected. The study achieved satisfactory results in integrating gas and oil

  20. Determination of uranium (IV) in cloride solutions of enrichment columns by spectrometry with flow injection

    International Nuclear Information System (INIS)

    Bastos, M.B.R.

    1988-01-01

    The utilization of Flow Injection Analysis for the U (IV) spectrophotometric determination in chloride solutions is described. The method has been shown reproducible in the range of concentrations and conditions employed with a standard deviation of about 0,3. (C.G.C.) [pt

  1. Effect of CO2 injection on brine flow and salt precipitation after gas field production

    NARCIS (Netherlands)

    Tambach, T.J.; Loeve, D.; Hofstee, C.; Plug, W.J.; Maas, J.G.

    2014-01-01

    This paper reports modeling of gas field production and CO2 injection in a theoretical reservoir based on characteristics of the P18 gas field in the Dutch offshore, which consists of four geological deposits with different petrophysical properties. We especially focus on the brine flow during and

  2. Radiation asymmetries during the thermal quench of massive gas injection disruptions in JET

    Czech Academy of Sciences Publication Activity Database

    Lehnen, M.; Gerasimov, S.N.; Jachmich, S.; Koslowski, H.R.; Kruezi, U.; Matthews, G.F.; Mlynář, Jan; Reux, C.; de Vries, P.C.

    2015-01-01

    Roč. 55, č. 12 (2015), s. 123027-123027 ISSN 0029-5515 Institutional support: RVO:61389021 Keywords : disruptions * disruption mitigation * heat loads * massive gas injection * radiation asymmetry Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 4.040, year: 2015

  3. Intrathecal injection of CD133-positive enriched bone marrow progenitor cells in children with cerebral palsy: feasibility and safety.

    Science.gov (United States)

    Zali, Alireza; Arab, Leila; Ashrafi, Farzad; Mardpour, Soura; Niknejhadi, Maryam; Hedayati-Asl, Amir Abbas; Halimi-Asl, Aliasghar; Ommi, Davood; Hosseini, Seyyedeh-Esmat; Baharvand, Hossein; Aghdami, Nasser

    2015-02-01

    Recent studies have proposed that cellular transplantation may have some regenerative and functional efficacy in the treatment of cerebral palsy (CP); however, much remains to be understood regarding its safety, feasibility and efficacy. This study was initiated to evaluate the safety of autologous bone marrow-derived CD133(+) cell intrathecal injection. Children (n = 12), aged 4 to 12 years, who were diagnosed with different types of CP underwent BM aspiration. CD133(+) cells were enriched from the BM samples and intrathecally injected. The Gross Motor Function Measure (GMFM-66), Gross Motor Function Classification System (GMFCS), UK FIM+FAM, Functional Independence Measure (FIM) and Functional Assessment Measure (FAM) were assessed at baseline and 6 months after the procedure. Patients' ability to balance was measured by the Berg Balance Scale (BBS), and severity of spasticity was evaluated by the Modified Ashworth Scale. Magnetic resonance imaging was done at baseline and 6 months after therapy. This study was registered in ClinicalTrials.gov (NCT01404663). There were no adverse events detected by clinical and laboratory tests or imaging studies, with the exception of a seizure in 1 patient. A significant improvement was observed 6 months after cell transplantation versus baseline according to GMFM, GMFCS, FIM+FAM, Ashworth Scale, and BBS outcomes. Subarachnoid injection of CD133-positive enriched bone marrow progenitor cells in children with CP is a safe approach. The results suggest a possible short-term improvement in neurological function. Copyright © 2015 International Society for Cellular Therapy. Published by Elsevier Inc. All rights reserved.

  4. Rapid quantitative detection of glucose content in glucose injection by reaction headspace gas chromatography.

    Science.gov (United States)

    Xie, Wei-Qi; Gong, Yi-Xian; Yu, Kong-Xian

    2017-10-20

    This work investigates an automated technique for rapid detecting the glucose content in glucose injection by reaction headspace gas chromatography (HS-GC). This method is based on the oxidation reaction of glucose in glucose injection with potassium dichromate. The carbon dioxide (CO 2 ) formed from the oxidation reaction can be quantitatively detected by GC. The results show that the relative standard deviation (RSD) of the present method was within 2.91%, and the measured glucose contents in glucose injection closely match those quantified by the reference method (relative differences glucose content in glucose injection related applications. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. Experiments with electron beam injection in ionosphere plasma and rare gas

    International Nuclear Information System (INIS)

    Bykovskij, V.F.; Meshkov, I.N.; Seleznev, I.A.; Syresin, E.M.

    2003-01-01

    The active experiment 'Electron' is intended for the electron beam injection from a meteorological rocket in the ionosphere plasma. The beam is injected in the ionosphere plasma at a current of 0.5 A and an energy of 6.5 - 8 keV. The energy spectra are given for the plasma electrons and ions. The radio-wave spectrum is measured in a RF frequency range of 100-500 MHz. The radio wave traversing through the electron beam injection region is discussed. The laboratory experiments are performed with the electron beam injection in a rare gas to model the active outer-space experiments

  6. The effect of hydrogen enrichment towards the flammability limits of natural gas in conventional combustion

    International Nuclear Information System (INIS)

    Izirwan Izhab; Nur Syuhada Mohd Shokri; Nurul Saadah Sulaiman; Mohd Zulkifli Mohamad Noor; Siti Zubaidah Sulaiman; Rosmawati Naim; Norida Ridzuan, Mohd Masri Razak; Abdul Halim Abdul Razik; Zulkafli Hassan

    2010-01-01

    The use of hydrogenated fuels shows a considerable promise for the applications in gas turbines and internal combustion engines. The aims of this study are to determine the flammability limits of natural gas/ air mixtures and to investigate the effect of hydrogen enrichment on the flammability limits of natural gas/ air mixtures up to 60 vol % of hydrogen/fuel volume ratio at atmospheric pressure and ambient temperature. The experiments were performed in a 20 L closed explosion vessel where the mixtures were ignited by using a spark permanent wire that was placed at the centre of the vessel. The pressure-time variations during explosions of natural gas/ air mixtures in an explosion vessel were recorded. Moreover, the explosion pressure data is used to determine the flammability limits that flame propagation is considered to occur if explosion pressure is greater than 0.1 bar. Therefore, in this study, the results show that the range of flammability limits are from 6 vol % to 15 vol % and by the addition of hydrogen in natural gas proved to extend the initial lower flammability limit of 6 vol % to 2 vol % of methane. (author)

  7. Particle transport and gas feed during gun injection

    International Nuclear Information System (INIS)

    Fowler, T K.

    1999-01-01

    It is shown that ion and neutral transport during gun injection tends to equalize the density in the spheromak to that in the open-line current channel. Since a gun operating at or near the ion saturation current requires a minimum density, because of transport these gun requirements also determine a minimum density in the spheromak that increases as the field increases. Hence attaining high fields by gun injection sets lower limits on the density, which in turn limits the temperature of the plasma and increases its ohmic resistance. Estimates of these effects are given using 0-D models calibrated to CTX, as guidance to 2-D UEDGE calculations in progress. For gun power levels in SSPX and the Pulsed Spheromak reactor, we find that buildup persists to the highest field levels of interest

  8. Piezoelectric valve for massive gas injection in ASDEX upgrade

    Energy Technology Data Exchange (ETDEWEB)

    Dibon, Mathias; Neu, Rudolf [Max-Planck-Institute for Plasmaphysics, Boltzmannstr. 2, 85748 Garching (Germany); Technical University Munich, Boltzmannstr. 15, 85748 Garching (Germany); Herrmann, Albrecht; Mank, Klaus; Mertens, Vitus; Pautasso, Gabriella; Ploeckl, Bernhard [Max-Planck-Institute for Plasmaphysics, Boltzmannstr. 2, 85748 Garching (Germany)

    2016-07-01

    A sudden loss of plasma temperature can cause a disruption, which poses a significant problem for current Tokamaks and future fusion devices. Hence, mitigating forces and thermal loads during disruptions is important for the integrity of the vessel and first wall components. Therefore, high speed gas valves are used to deliver a pulse of noble gas onto the plasma, which irradiates the thermal energy quickly, avoiding localized heat loads and mechanical stress due to induced currents. A new design for such a valve is currently under development. The valve plate is driven by two piezoelectric stack actuators. The stroke of the actuators (0.07 mm) is amplified by a monolithic titanium frame and reaches 2 mm. The frame also serves as spring to pre-load the actuators. In the idle state, it also presses the conical valve plate into the seal, closing the gas chamber (42 cm{sup 3}). The actuators accelerate the stem and the valve plate until it is fully opened after 2 ms. The orifice of the valve has a diameter of 14 mm. This allows a peak mass flow rate of the gas up to 8 . 10{sup 4} (Pa.m)/(s) after 1.8 ms and an average mass flow rate of 2 . 10{sup 4} (Pa.m)/(s) over the evacuation time of 10 ms. Therefore, one valve would be sufficient to deliver the required amount of gas to mitigate disruptions at ASDEX Upgrade.

  9. Measuring deuterium enrichment of glucose hydrogen atoms by gas chromatography/mass spectrometry.

    Science.gov (United States)

    Antoniewicz, Maciek R; Kelleher, Joanne K; Stephanopoulos, Gregory

    2011-04-15

    We developed a simple and accurate method for determining deuterium enrichment of glucose hydrogen atoms by electron impact gas chromatography mass spectrometry (GC/MS). First, we prepared 18 derivatives of glucose and screened over 200 glucose fragments to evaluate the accuracy and precision of mass isotopomer data for each fragment. We identified three glucose derivatives that gave six analytically useful ions: (1) glucose aldonitrile pentapropionate (m/z 173 derived from C4-C5 bond cleavage; m/z 259 from C3-C4 cleavage; m/z 284 from C4-C5 cleavage; and m/z 370 from C5-C6 cleavage); (2) glucose 1,2,5,6-di-isopropylidene propionate (m/z 301, no cleavage of glucose carbon atoms); and (3) glucose methyloxime pentapropionate (m/z 145 from C2-C3 cleavage). Deuterium enrichment at each carbon position of glucose was determined by least-squares regression of mass isotopomer distributions. The validity of the approach was tested using labeled glucose standards and carefully prepared mixtures of standards. Our method determines deuterium enrichment of glucose hydrogen atoms with an accuracy of 0.3 mol %, or better, without the use of any calibration curves or correction factors. The analysis requires only 20 μL of plasma, which makes the method applicable for studying gluconeogenesis using deuterated water in cell culture and animal experiments. © 2011 American Chemical Society

  10. Injection, flow, and mixing of CO2 in porous media with residual gas.

    Energy Technology Data Exchange (ETDEWEB)

    Oldenburg, C.M.; Doughty, C.A.

    2010-09-01

    Geologic structures associated with depleted natural gas reservoirs are desirable targets for geologic carbon sequestration (GCS) as evidenced by numerous pilot and industrial-scale GCS projects in these environments world-wide. One feature of these GCS targets that may affect injection is the presence of residual CH{sub 4}. It is well known that CH{sub 4} drastically alters supercritical CO{sub 2} density and viscosity. Furthermore, residual gas of any kind affects the relative permeability of the liquid and gas phases, with relative permeability of the gas phase strongly dependent on the time-history of imbibition or drainage, i.e., dependent on hysteretic relative permeability. In this study, the effects of residual CH{sub 4} on supercritical CO{sub 2} injection were investigated by numerical simulation in an idealized one-dimensional system under three scenarios: (1) with no residual gas; (2) with residual supercritical CO{sub 2}; and (3) with residual CH{sub 4}. We further compare results of simulations that use non-hysteretic and hysteretic relative permeability functions. The primary effect of residual gas is to decrease injectivity by decreasing liquid-phase relative permeability. Secondary effects arise from injected gas effectively incorporating residual gas and thereby extending the mobile gas plume relative to cases with no residual gas. Third-order effects arise from gas mixing and associated compositional effects on density that effectively create a larger plume per unit mass. Non-hysteretic models of relative permeability can be used to approximate some parts of the behavior of the system, but fully hysteretic formulations are needed to accurately model the entire system.

  11. The U.S. Gas Flooding Experience: CO2 Injection Strategies and Impact on Ultimate Recovery

    Energy Technology Data Exchange (ETDEWEB)

    Nunez-Lopez, Vanessa [The University of Texas at Austin; Hosseini, Seyyed; Gil-Egui, Ramon

    2017-09-29

    The Permian Basin in West Texas and southwestern New Mexico has seen 45 years of oil reserve growth through CO2 enhanced oil recovery (CO2 EOR). More than 60 CO2 EOR projects are currently active in the region’s limestone, sandstone and dolomite reservoirs. Water alternating gas (WAG) has been the development strategy of choice in the Permian for several technical and economic reasons. More recently, the technology started to get implemented in the much more porous and permeable clastic depositional systems of the onshore U.S. Gulf Coast. Continued CO2 injection (CGI), as opposed to WAG, was selected as the injection strategy to develop Gulf Coast oil fields, where CO2 injection volumes are significantly larger (up to 6 times larger) than those of the Permian. We conducted a compositional simulation based study with the objective of comparing the CO2 utilization ratios (volume of CO2 injected to produce a barrel of oil) of 4 conventional and novel CO2 injection strategies: (1) continuous gas injection (CGI), (2) water alternating gas (WAG), (3) water curtain injection (WCI), and (4) WAG and WCI combination. These injection scenarios were simulated using the GEM module from the Computer Modeling Group (CMG). GEM is an advanced general equation-of-state compositional simulator, which includes equation of state, CO2 miscible flood, CO2/brine interactions, and complex phase behavior. The simulator is set up to model three fluid phases including water, oil, and gas. Our study demonstrates how the selected field development strategy has a significant impact on the ultimate recovery of CO2-EOR projects, with GCI injection providing maximum oil recovery in absolute volume terms, but with WAG offering a more balanced technical-economical approach.

  12. Experiments and numerical analysis of a control method for natural circulation through helium gas injection

    Energy Technology Data Exchange (ETDEWEB)

    Takeda, Tetsuaki, E-mail: ttakeda@yamanashi.ac.jp; Hatori, Hirofumi; Funatani, Shumpei

    2016-09-15

    This study investigated a control method for natural circulation of air by helium gas injection. A depressurization accident is a design-basis accident of a very high temperature reactor. When a primary pipe rupture accident occurs, air is expected to enter the reactor pressure vessel from the breach. Thus, in-core graphite structures are oxidized. In order to predict and analyze the phenomena of air ingress during a depressurization accident, numerical analysis was carried out using a one-dimensional (1D) analysis code and three-dimensional computational fluid dynamics (3D CFD). An experiment was carried out regarding natural circulation using a circular pipe consisting of a reverse U-shaped channel. The channel consisted of two vertical heated and cooled pipes. The temperature difference between the vertical pipes was maintained at 40–80 K, and a small amount of helium gas was injected into the channel. The injected volume of helium was about 3.1–12.5% of the total channel volume. After injecting helium gas, each component gas moved through molecular diffusion and very weak natural circulation. After approximately 1180 s, ordinary natural circulation of air was suddenly produced. The numerical results of the 3D CFD code were in good agreement with the experimental results. The numerical results also showed that the natural circulation of air can be controlled by helium gas injection.

  13. Flash Atomization: A New Concept to Control Combustion Instability in Water-Injected Gas Turbines

    Directory of Open Access Journals (Sweden)

    Vishwas Iyengar

    2012-01-01

    Full Text Available The objective of this work is to explore methods to reduce combustor rumble in a water-injected gas turbine. Attempts to use water injection as a means to reduce NOX emissions in gas turbines have been largely unsuccessful because of increased combustion instability levels. This pulsation causes chronic fretting, wear, and fatigue that damages combustor components. Of greater concern is that liberated fragments could cause extensive damage to the turbine section. Combustion instability can be tied to the insufficient atomization of injected water; large water droplets evaporate non-uniformly that lead to energy absorption in chaotic pulses. Added pulsation is amplified by the combustion process and acoustic resonance. Effervescent atomization, where gas bubbles are injected, is beneficial by producing finely atomized droplets; the gas bubbles burst as they exit the nozzles creating additional energy to disperse the liquid. A new concept for effervescent atomization dubbed “flash atomization” is presented where water is heated to just below its boiling point in the supply line so that some of it will flash to steam as it leaves the nozzle. An advantage of flash atomization is that available heat energy can be used rather than mechanical energy to compress injection gas for conventional effervescent atomization.

  14. HIGH RESOLUTION PREDICTION OF GAS INJECTION PROCESS PERFORMANCE FOR HETEROGENEOUS RESERVOIRS

    Energy Technology Data Exchange (ETDEWEB)

    Franklin M. Orr, Jr.

    2003-06-30

    This report presents a detailed analysis of the development of miscibility during gas cycling in condensates and the formation of condensate banks at the leading edge of the displacement front. Dispersion-free, semi-analytical one-dimensional (1D) calculations are presented for enhanced condensate recovery by gas injection. The semi-analytical approach allows investigation of the possible formation of condensate banks (often at saturations that exceed the residual liquid saturation) and also allows fast screening of optimal injection gas compositions. We describe construction of the semi-analytical solutions, a process which differs in some ways from related displacements for oil systems. We use an analysis of key equilibrium tie lines that are part of the displacement composition path to demonstrate that the mechanism controlling the development of miscibility in gas condensates may vary from first-contact miscible drives to pure vaporizing and combined vaporizing/condensing drives. Depending on the compositions of the condensate and the injected gas, multicontact miscibility can develop at the dew point pressure, or below the dew point pressure of the reservoir fluid mixture. Finally, we discuss the possible impact on performance prediction of the formation of a mobile condensate bank at the displacement front in near-miscible gas cycling/injection schemes.

  15. Hydrogen enrichment and separation from synthesis gas by the use of a membrane reactor

    International Nuclear Information System (INIS)

    Sanchez, J.M.; Barreiro, M.M.; Marono, M.

    2011-01-01

    One of the objectives of the CHRISGAS project was to study innovative gas separation and gas upgrading systems that have not been developed sufficiently yet to be tested at a demonstration scale within the time frame of the project, but which show some attractive merits and features for further development. In this framework CIEMAT studied, at bench scale, hydrogen enrichment and separation from syngas by the use of membranes and membrane catalytic reactors. In this paper results about hydrogen separation from synthesis gas by means of selective membranes are presented. Studies dealt with the evaluation of permeation and selectivity to hydrogen of prepared and pre-commercial Pd-based membranes. Whereas prepared membranes turned out to be non-selective, due to discontinuities of the palladium layer, studies conducted with the pre-commercial membrane showed that by means of a membrane reactor it is possible to completely separate hydrogen from the other gas components and produce pure hydrogen as a permeate stream, even in the case of complex reaction system (H 2 /CO/CO 2 /H 2 O) under WGS conditions gas mixtures. The advantages of using a water-gas shift membrane reactor (MR) over a traditional fixed bed reactor (TR) have also been studied. The experimental device included the pre-commercial Pd-based membrane and a commercial high temperature Fe-Cr-based, WGS catalyst, which was packed in the annulus between the membrane and the reactor outer shell. Results show that in the MR concept, removal of H 2 from the reaction side has a positive effect on WGS reaction, reaching higher CO conversion than in a traditional packed bed reactor at a given temperature. On increasing pressure on the reaction side permeation is enhanced and hence carbon monoxide conversion increases. -- Highlights: → H 2 enrichment and separation using a bench-scale membrane reactor MR is studied. → Permeation and selectivity to H 2 of Pd-based membranes was determined. → Complete separation

  16. Intradiscal injection of oxygen-ozone gas mixture for the treatment of cervical disc herniations.

    Science.gov (United States)

    Alexandre, A; Corò, L; Azuelos, A; Buric, J; Salgado, H; Murga, M; Marin, F; Giocoli, H

    2005-01-01

    For disc herniations the use of open surgical approaches is reduced since new percutaneous methods allowing shrinkage of the disc and improvement of the radicular function are gaining interest. Studies on the spontaneous disappearance of disc fragments have demonstrated autoimmune responses with a chronic inflammatory reaction. Also radicular pain has been shown to be mostly due to biochemical mechanisms. Researchers in different fields surprisingly noticed that a brief, calculated, oxidative stress by ozone administration may correct a persistent imbalance due to excessive, chronic oxidative injury. Oxygen-ozone gas injection in painful patients has a dramatic effect on clinical symptoms. On these bases the intradiscal injection of oxygen-ozone gas has been conceived. We report the treatment on a series of patients affected by cervical disc pathology, treated by intradiscal injection of oxygen-ozone gas mixture. The effects both on pain and on radicular dysfunction are impressive. The morphological effect of the treatment was also evaluated by pathological examination.

  17. Prototype demonstration of dual sorbent injection for acid gas control on municipal solid waste combustion units

    Energy Technology Data Exchange (ETDEWEB)

    None

    1994-05-01

    This report gathered and evaluated emissions and operations data associated with furnace injection of dry hydrated lime and duct injection of dry sodium bicarbonate at a commercial, 1500 ton per day, waste-to-energy facility. The information compiled during the project sheds light on these sorbents to affect acid gas emissions from municipal solid waste combustors. The information assesses the capability of these systems to meet the 1990 Clean Air Act and 1991 EPA Emission Guidelines.

  18. The extent of chemically enriched gas around star-forming dwarf galaxies

    Science.gov (United States)

    Johnson, Sean

    2018-01-01

    Supernovae driven winds are often invoked to remove chemically enriched gas from galaxies to match the low metallicities of dwarf galaxies. In such shallow potential wells, outflows may produce massive amounts of enriched halo gas (circum-galactic medium or CGM) and pollute the intergalactic medium (IGM). I will present a survey of the CGM and IGM around 18 star-forming field dwarf galaxies with stellar masses of log M*/M⊙ ≈ 8 ‑ 9 at z ≈ 0.2. Eight of these have CGM probed by quasar absorption spectra at projected distances, d, less than the host virial radius, Rh. Ten are probed at d/Rh = 1 ‑ 3 to study the surrounding IGM. The absorption measurements include neutral hydrogen (H I), the dominant silicon ions for diffuse cool gas (T ∼ 104 K; Si II, Si III, and Si IV), more highly ionized carbon (C IV), and highly ionized oxygen (O VI). The metal absorption from the CGM of the dwarf galaxies is less common and ≈ 4× weaker compared to massive star-forming galaxies though O VI absorption is still common. None of the dwarfs probed at d/Rh = 1 ‑ 3 have definitive metal-line detections. Combining the available silicon ions, we estimate that the cool CGM accounts for only 2 ‑ 6% of the expected silicon budget. CGM absorption from O VI can account for ≈ 8% of the expected oxygen budget. As O VI traces an ion with expected equilibrium ion fractions of 0.2, this highly ionized phase of the CGM may represent a significant metal reservoir even for dwarf galaxies not expected to maintain gravitationally shock heated hot halos.

  19. Gas injection may have triggered earthquakes in the Cogdell oil field, Texas.

    Science.gov (United States)

    Gan, Wei; Frohlich, Cliff

    2013-11-19

    Between 1957 and 1982, water flooding was conducted to improve petroleum production in the Cogdell oil field north of Snyder, TX, and a contemporary analysis concluded this induced earthquakes that occurred between 1975 and 1982. The National Earthquake Information Center detected no further activity between 1983 and 2005, but between 2006 and 2011 reported 18 earthquakes having magnitudes 3 and greater. To investigate these earthquakes, we analyzed data recorded by six temporary seismograph stations deployed by the USArray program, and identified 93 well-recorded earthquakes occurring between March 2009 and December 2010. Relocation with a double-difference method shows that most earthquakes occurred within several northeast-southwest-trending linear clusters, with trends corresponding to nodal planes of regional focal mechanisms, possibly indicating the presence of previously unidentified faults. We have evaluated data concerning injection and extraction of oil, water, and gas in the Cogdell field. Water injection cannot explain the 2006-2011 earthquakes, especially as net volumes (injection minus extraction) are significantly less than in the 1957-1982 period. However, since 2004 significant volumes of gases including supercritical CO2 have been injected into the Cogdell field. The timing of gas injection suggests it may have contributed to triggering the recent seismic activity. If so, this represents an instance where gas injection has triggered earthquakes having magnitudes 3 and larger. Further modeling studies may help evaluate recent assertions suggesting significant risks accompany large-scale carbon capture and storage as a strategy for managing climate change.

  20. Health risk assessment linked with purified biogas injection in a natural gas distribution system

    International Nuclear Information System (INIS)

    Leroux, Carole; Modelon, Hugues; Rousselle, Christophe; Zdanevitch, Isabelle; Evanno, Sebastien

    2009-06-01

    This document provides for the opinion of the French Agency for Environmental and Occupational Health and Safety (Afsset) expressed after the collective expertise carried out for the evaluation of the health risk linked with biogas injection in the natural gas distribution system. Following the recommendations issued by the Afsset, works have been started in order to collect the sludge-derived biogas and to analyse its composition. These data will be used to assess accidental risks (resulting from biogas valorisation, pipeline transport, industrial and domestic energy valorisation) as well as health risks for users (resulting from the injection in the natural gas distribution system)

  1. Turbulent heat transfer on a permeable surface in the range of supercritical gas injections

    International Nuclear Information System (INIS)

    Kichatov, B.V.; Polyaev, V.M.

    1997-01-01

    Gas injection in a permeable surface is used as one of the most perspective ways of thermal protection. Forcing back of the boundary layer from the surface takes place by injection, whereby the friction coefficients and heat exchange are decreased. By certain injection parameter, which is called critical, there takes place the complete forcing back of the boundary layer from the surface. However the process of friction and heat exchange degeneration proceeds nonuniformly. This article is devoted to explanation of the above notice. Analysis of the problem is based on the limiting relative law of heat exchange and friction for a turbulent boundary layer

  2. Influence of gas injection on viscous and viscoelastic properties of Xanthan gum.

    Science.gov (United States)

    Bobade, Veena; Cheetham, Madalyn; Hashim, Jamal; Eshtiaghi, Nicky

    2018-05-01

    Xanthan gum is widely used as a model fluid for sludge to mimic the rheological behaviour under various conditions including impact of gas injection in sludge. However, there is no study to show the influence of gas injection on rheological properties of xanthan gum specifically at the concentrations at which it is used as a model fluid for sludge with solids concentration above 2%. In this paper, the rheological properties of aqueous xanthan gum solutions at different concentrations were measured over a range of gas injection flow rates. The effect of gas injection on both the flow and viscoelastic behaviour of Xanthan gum (using two different methods - a creep test and a time sweep test) was evaluated. The viscosity curve of different solid concentrations of digested sludge and waste activated sludge were compared with different solid concentrations of Xanthan gum and the results showed that Xanthan gum can mimic the flow behaviour of sludge in flow regime. The results in linear viscoelastic regime showed that increasing gas flow rate increases storage modulus (G'), indicating an increase in the intermolecular associations within the material structure leading to an increase in material strength and solid behaviour. Similarly, in creep test an increase in the gas flow rate decreased strain%, signifying that the material has become more resistant to flow. Both observed behaviour is opposite to what occurs in sludge under similar conditions. The results of both the creep test and the time sweep test indicated that choosing Xanthan gum aqueous solution as a transparent model fluid for sludge in viscoelastic regime under similar conditions involving gas injection in a concentration range studied is not feasible. However Xanthan gum can be used as a model material for sludge in flow regime; because it shows a similar behaviour to sludge. Copyright © 2018 Elsevier Ltd. All rights reserved.

  3. Evaluation of a subsurface oxygenation technique using colloidal gas aphron injections into packed column reactors

    International Nuclear Information System (INIS)

    Wills, R.A.; Coles, P.

    1991-11-01

    Bioremediation may be a remedial technology capable of decontaminating subsurface environments. The objective of this research was to evaluate the use of colloidal gas aphron (CGA) injection, which is the injection of micrometer-size air bubbles in an aqueous surfactant solution, as a subsurface oxygenation technique to create optimal growth conditions for aerobic bacteria. Along with this, the capability of CGAs to act as a soil-washing agent and free organic components from a coal tar-contaminated matrix was examined. Injection of CGAs may be useful for remediation of underground coal gasification (UCG) sites. Because of this, bacteria and solid material from a UCG site located in northeastern Wyoming were used in this research. Colloidal gas aphrons were generated and pumped through packed column reactors (PCRS) containing post-burn core materials. For comparison, PCRs containing sand were also studied. Bacteria from this site were tested for their capability to degrade phenol, a major contaminant at the UCG site, and were also used to bioaugment the PCR systems. In this study we examined: (1) the effect of CGA injection on dissolved oxygen concentrations in the PCR effluents, (2) the effect of CGA, H 2 O 2 , and phenol injections on bacterial populations, (3) the stability and transport of CGAs over distance, and (4) CGA injection versus H 2 O 2 injection as an oxygenation technique

  4. Performance and Economics of Catalytic Glow Plugs and Shields in Direct Injection Natural Gas Engines for the Next Generation Natural Gas Vehicle Program: Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Mello, J. P.; Bezaire, D.; Sriramulu, S.; Weber, R.

    2003-08-01

    Subcontractor report details work done by TIAX and Westport to test and perform cost analysis for catalytic glow plugs and shields for direct-injection natural gas engines for the Next Generation Natural Gas Vehicle Program.

  5. The response of the Tore Supra edge plasma to supersonic pulsed gas injection

    Czech Academy of Sciences Publication Activity Database

    Pánek, Radomír; Gunn, J. P.; Bucalossi, J.; Ďuran, Ivan; Geraud, A.; Hron, Martin; Loarer, T.; Pégourié, B.; Stöckel, Jan; Tsitrone, E.

    337-339, č. 16 (2005), s. 530-534 ISSN 0022-3115. [Plasma Surface Interactions /16./. Portland, 24.5.2005-28.5.2005] R&D Projects: GA ČR(CZ) GP202/03/P062 Institutional research plan: CEZ:AV0Z20430508 Keywords : Edge plasma * Gas injection and fuelling * probes * Plasma flow * Tore Supra Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.414, year: 2005

  6. Maximization of ICRF power by SOL density tailoring with local gas injection

    Czech Academy of Sciences Publication Activity Database

    Jacquet, P.; Goniche, M.; Bobkov, V.; Lerche, E.; Pinsker, R.I.; Pitts, R.A.; Zhang, W.; Colas, L.; Hosea, J.; Moriyama, S.; Wang, S.-J.; Wukitch, S.; Zhang, X.; Bilato, R.; Bufferand, H.; Guimarais, L.; Faugel, H.; Hanson, G.R.; Kocan, M.; Monakhov, I.; Noterdaeme, J.-M.; Petržílka, Václav; Shaw, A.; Stepanov, I.; Sips, A.C.C.; Van Eester, D.; Wauters, T.

    2016-01-01

    Roč. 56, č. 4 (2016), s. 046001 ISSN 0029-5515 EU Projects: European Commission(XE) 633053 - EUROfusion Institutional support: RVO:61389021 Keywords : ICRF power * antenna loading * gas injection * SOL density Subject RIV: BL - Plasma and Gas Discharge Physics OBOR OECD: Fluids and plasma physics (including surface physics) Impact factor: 3.307, year: 2016 http://iopscience.iop.org/article/10.1088/0029-5515/56/4/046001

  7. From the Lab to the real world : sources of error in UF {sub 6} gas enrichment monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Lombardi, Marcie L.

    2012-03-01

    Safeguarding uranium enrichment facilities is a serious concern for the International Atomic Energy Agency (IAEA). Safeguards methods have changed over the years, most recently switching to an improved safeguards model that calls for new technologies to help keep up with the increasing size and complexity of today’s gas centrifuge enrichment plants (GCEPs). One of the primary goals of the IAEA is to detect the production of uranium at levels greater than those an enrichment facility may have declared. In order to accomplish this goal, new enrichment monitors need to be as accurate as possible. This dissertation will look at the Advanced Enrichment Monitor (AEM), a new enrichment monitor designed at Los Alamos National Laboratory. Specifically explored are various factors that could potentially contribute to errors in a final enrichment determination delivered by the AEM. There are many factors that can cause errors in the determination of uranium hexafluoride (UF{sub 6}) gas enrichment, especially during the period when the enrichment is being measured in an operating GCEP. To measure enrichment using the AEM, a passive 186-keV (kiloelectronvolt) measurement is used to determine the {sup 235}U content in the gas, and a transmission measurement or a gas pressure reading is used to determine the total uranium content. A transmission spectrum is generated using an x-ray tube and a “notch” filter. In this dissertation, changes that could occur in the detection efficiency and the transmission errors that could result from variations in pipe-wall thickness will be explored. Additional factors that could contribute to errors in enrichment measurement will also be examined, including changes in the gas pressure, ambient and UF{sub 6} temperature, instrumental errors, and the effects of uranium deposits on the inside of the pipe walls will be considered. The sensitivity of the enrichment calculation to these various parameters will then be evaluated. Previously, UF

  8. Modelling the effect of gas injections on the stability of asphaltene-containing crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, X.; Moorwood, T. [Infochem, Munich (Germany); Merino Garcia, D.; Pena Diez, J.L. [Repsol YPF, Madrid (Spain)

    2008-07-01

    In oil fields where asphaltene deposits occur, they present major remediation problems and can halt production due to flow blockage. Crude oils which precipitate asphaltenes generally contain both asphaltene molecules and lighter resin molecules. Resins are thought to solvate the asphaltene molecules, thus stabilizing the solution, while light gases have the opposite effect. In order to model asphaltene phase behaviour, it is important to understand the impact of adding gas to asphaltene-containing crudes. This study presented several experimental investigations of gas injection into asphaltene-containing crudes. The trends of asphaltene destabilization were discussed. The injection gases ranged from pure gases to a gas condensate. The data were modelled using a conventional equation of state together with an extra term that considered the association between asphaltene molecules and their solvation by resins. Since the model could simultaneously described the gas, oil and asphaltene phases, it was possible to calculate phase stability and phase equilibria. However, a different model had to be used to obtain the gas-oil equilibrium because the use of solubility parameters only allows the stability of the asphaltene phase to be calculated. The model correctly predicted that the gases will promote asphaltene precipitation. In its original form, the model tended to over-predict the trend. The optimal parameter values needed to represent all the available experimental data were determined. The extent to which the effect of gas injection on asphaltenes can be predicted was then discussed.

  9. Reduction of gaseous pollutant emissions from gas turbine combustors using hydrogen-enriched jet fuel

    Science.gov (United States)

    Clayton, R. M.

    1976-01-01

    Recent progress in an evaluation of the applicability of the hydrogen enrichment concept to achieve ultralow gaseous pollutant emission from gas turbine combustion systems is described. The target emission indexes for the program are 1.0 for oxides of nitrogen and carbon monoxide, and 0.5 for unburned hydrocarbons. The basic concept utilizes premixed molecular hydrogen, conventional jet fuel, and air to depress the lean flammability limit of the mixed fuel. This is shown to permit very lean combustion with its low NOx production while simulataneously providing an increased flame stability margin with which to maintain low CO and HC emission. Experimental emission characteristics and selected analytical results are presented for a cylindrical research combustor designed for operation with inlet-air state conditions typical for a 30:1 compression ratio, high bypass ratio, turbofan commercial engine.

  10. Approach to IAEA material-balance verification at the Portsmouth Gas Centrifuge Enrichment Plant

    International Nuclear Information System (INIS)

    Gordon, D.M.; Sanborn, J.B.; Younkin, J.M.; DeVito, V.J.

    1983-01-01

    This paper describes a potential approach by which the International Atomic Energy Agency (IAEA) might verify the nuclear-material balance at the Portsmouth Gas Centrifuge Enrichment Plant (GCEP). The strategy makes use of the attributes and variables measurement verification approach, whereby the IAEA would perform independent measurements on a randomly selected subset of the items comprising the U-235 flows and inventories at the plant. In addition, the MUF-D statistic is used as the test statistic for the detection of diversion. The paper includes descriptions of the potential verification activities, as well as calculations of: (1) attributes and variables sample sizes for the various strata, (2) standard deviations of the relevant test statistics, and (3) the detection sensitivity which the IAEA might achieve by this verification strategy at GCEP

  11. HIGH RESOLUTION PREDICTION OF GAS INJECTION PROCESS PERFORMANCE FOR HETEROGENEOUS RESERVOIRS

    Energy Technology Data Exchange (ETDEWEB)

    Franklin M. Orr, Jr.

    2004-05-01

    This final technical report describes and summarizes results of a research effort to investigate physical mechanisms that control the performance of gas injection processes in heterogeneous reservoirs and to represent those physical effects in an efficient way in simulations of gas injection processes. The research effort included four main lines of research: (1) Efficient compositional streamline methods for 3D flow; (2) Analytical methods for one-dimensional displacements; (3) Physics of multiphase flow; and (4) Limitations of streamline methods. In the first area, results are reported that show how the streamline simulation approach can be applied to simulation of gas injection processes that include significant effects of transfer of components between phases. In the second area, the one-dimensional theory of multicomponent gas injection processes is extended to include the effects of volume change as components change phase. In addition an automatic algorithm for solving such problems is described. In the third area, results on an extensive experimental investigation of three-phase flow are reported. The experimental results demonstrate the impact on displacement performance of the low interfacial tensions between the gas and oil phases that can arise in multicontact miscible or near-miscible displacement processes. In the fourth area, the limitations of the streamline approach were explored. Results of an experimental investigation of the scaling of the interplay of viscous, capillary, and gravity forces are described. In addition results of a computational investigation of the limitations of the streamline approach are reported. The results presented in this report establish that it is possible to use the compositional streamline approach in many reservoir settings to predict performance of gas injection processes. When that approach can be used, it requires substantially less (often orders of magnitude) computation time than conventional finite difference

  12. Dynamics of CO 2 transport and injection strategies in a depleted gas field

    NARCIS (Netherlands)

    Veltin, J.; Belfroid, S.P.C.

    2012-01-01

    As Carbon Capture and Storage slowly gets accepted and integrated as a mean for cleaner utilization of fossil fuels, accurate knowledge of the transport of CO2 through pipelines and into wells becomes crucial. A representative North Sea transport and injection scenario into a depleted gas field is

  13. Technique for locating injected gas in oil bearing formations behind casing

    International Nuclear Information System (INIS)

    Wallace, J.P.

    1987-01-01

    A method is described for determining the location of injected gas in an oil well comprising the steps of: obtaining data representing a near count rate from a compensated neutron logging tool; obtaining data representing a far count rate from a compensated neutron logging tool; scaling the near count rate and the far count rate; plotting the scaled near count rate and the scaled far rate; comparing the scaled near count rate plot and the scaled far count rate plot and; determining the location of injected gas whenever the plot of the scaled near count rate and the plot of the scaled far count rate differ by a predetermined factor; obtaining data representing a second near count rate for a compensated neutron logging tool at a second time; obtaining data representing a second far count rate from a compensated neutron logging tool at the second time; scaling the second near count rate and the second far count rate; plotting the scaled second near count rate and the scaled second far count rate; comparing the scaled second near count rate plot and the scaled second far count rate plot; determining a second location of injected gas whenever the plot of the scaled second near count rate and the plot of the scaled second far count rate differ by a predetermined factor; and determining the migration of the injected gas by comparing the location with the second location

  14. Consequences of thermal fracture developments due to injection cold CO2 into depleted gas fields

    NARCIS (Netherlands)

    Peters, E.; Pizzocolo, F.; Loeve, D.; Fokker, P.A.; Hofstee, C.; Orlic, B.; Maas, J.G.

    2013-01-01

    CO2 storage is planned in a depleted gas field called P18, which is located offshore in the vicinity of the Dutch coast. This project is also known as the ROAD project, which is the Rotterdam capture and storage demonstration project. In the P18-4 compartment, cold CO2 will be injected into a

  15. Effect of advanced injection timing on the performance of natural gas ...

    Indian Academy of Sciences (India)

    Abstract. Concern over the environment and/or the increasing demand for conventional fossil fuel has promoted interest in the development of alternative sources of fuel energy for internal combustion (IC) engines. The effect of advanced injection timing on the performance of natural gas used as primary fuel in dual-fuel ...

  16. Suppression of Tritium Retention in Remote Areas of ITER by Nonperturbative Reactive Gas Injection

    NARCIS (Netherlands)

    Tabares, F. L.; Ferreira, J. A.; Ramos, A.; van Rooij, G. J.; Westerhout, J.; Al, R.; Rapp, J.; Drenik, A.; Mozetic, M.

    2010-01-01

    A technique based on reactive gas injection in the afterglow region of the divertor plasma is proposed for the suppression of tritium-carbon codeposits in remote areas of ITER when operated with carbon-based divertor targets. Experiments in a divertor simulator plasma device indicate that a 4 nm/min

  17. Injection halos of hydrocarbons above oil-gas fields with super-high pressures

    Energy Technology Data Exchange (ETDEWEB)

    Bakhtin, V.V.

    1979-09-01

    We studied the origin of injection halos of hydrocarbons above oil-gas fields with anomalously high formation pressures (AHFP). Using fields in Azerbaydzhan and Chechen-Ingushetiya as an example, we demonstrate the effect of certain factors (in particular, faults and zones of increased macro- and micro-jointing) on the morpholoy of the halos. The intensity of micro-jointing (jointing permeability, three-dimensional density of micro-jointing) is directly connected with vertical dimensions of the halos. We measured halos based on transverse profiles across the Khayan-Kort field and studied the distribution of bitumen saturation within the injection halo. Discovery of injection halos during drilling has enabled us to improve the technology of wiring deep-seated exploratory wells for oil and gas in regions with development of AHFP.

  18. Disruption mitigation using high-pressure noble gas injection on DIII-D

    International Nuclear Information System (INIS)

    Whyte, D.G.

    2002-01-01

    High-pressure gas jet injection of neon and argon is shown to be a simple and robust method to mitigate the deleterious effects of disruptions on the DIII-D tokamak. The gas jet penetrates to the central plasma at its sonic velocity. The deposited species dissipates ∼100% of the plasma thermal energy by radiation and substantially reduces mechanical stresses on the vessel caused by poloidal halo currents. The gas jet species charge distribution can include >50% fraction neutral species which inhibits runaway electrons. The favorable scaling of this technique to burning fusion plasmas is discussed. (author)

  19. THE STUDY OF GAS MIGRATION IN CRYSTALLINE ROCK USING INJECTION TESTS

    Directory of Open Access Journals (Sweden)

    Jiří Svoboda

    2012-07-01

    Full Text Available The study of gas migration in crystalline rock using injection tests is being carried out in the frame of the FORGE (Fate of Repository Gases project. The Czech Technical University in Prague (CTU, Centre of Experimental Geotechnics (CEG is participating in WP4 which is focused on disturbed host rock formations with respect to radioactive waste deep repositories. A series of in-situ tests is being conducted at the Josef Underground Laboratory. The aim of the testing is to simulate and study phenomena that might lead to gas-driven radionuclide transport in fractured crystalline rock. The in-situ tests combine migration and large-scale gas injection measurements; gas injection tests are being employed for the study of gas transport. For the purposes of comparison of the behaviour of the rock mass with regard to air and water a series of water pressure tests are also being carried out. The quality of the rock mass is assessed using rock mass classification systems.

  20. HIGH RESOLUTION PREDICTION OF GAS INJECTION PROCESS PERFORMANCE FOR HETEROGENEOUS RESERVOIRS

    Energy Technology Data Exchange (ETDEWEB)

    Franklin M. Orr, Jr.

    2001-12-31

    This report outlines progress in the first quarter of the second year of the DOE project ''High Resolution Prediction of Gas Injection Process Performance for Heterogeneous Reservoirs''. The application of the analytical theory for gas injection processes, including the effects of volume change on mixing, has up to now been limited to fully self-sharpening systems, systems where all solution segments that connect the key tie lines present in the displacement are shock fronts. In the following report, we describe the extension of the analytical theory to include systems with rarefactions (continuous composition and saturation variations) between key tie lines. With the completion of this analysis, a completely general procedure has been developed for finding solutions for problems in which a multicomponent gas displaces a multicomponent oil.

  1. Influence of heat exchange of reservoir with rocks on hot gas injection via a single well

    Science.gov (United States)

    Nikolaev, Vladimir E.; Ivanov, Gavril I.

    2017-11-01

    In the computational experiment the influence of heat exchange through top and bottom of the gas-bearing reservoir on the dynamics of temperature and pressure fields during hot gas injection via a single well is investigated. The experiment was carried out within the framework of modified mathematical model of non-isothermal real gas filtration, obtained from the energy and mass conservation laws and the Darcy law. The physical and caloric equations of state together with the Newton-Riemann law of heat exchange of gas reservoir with surrounding rocks, are used as closing relations. It is shown that the influence of the heat exchange with environment on temperature field of the gas-bearing reservoir is localized in a narrow zone near its top and bottom, though the size of this zone is increased with time.

  2. Bubble Formation at a Submerged Orifice for Aluminum Foams Produced by Gas Injection Method

    Science.gov (United States)

    Fan, Xueliu; Chen, Xiang; Liu, Xingnan; Zhang, Huiming; Li, Yanxiang

    2013-02-01

    The bubble formation at a submerged orifice in the process of aluminum foams produced by gas injection method is investigated. The experimental results show that the increase of the gas flow rate and the orifice diameter can lead to increasing of the bubble size. The large orifice can make the frequency of bubble formation decrease by slowing down the increase of the gas chamber pressure when the gas flow rate increases. The effect of the gas chamber volume on the bubble size can be ignored in the experiment when it expands from 1 to 125 cm3. A theoretical model of bubble formation, expansion, and detachment under constant flow conditions is established to predict the bubble size. The theoretical predictions for air-aluminum melt systems are consistent with the experimental results.

  3. Determination of glycerol concentrations and glycerol isotopic enrichments in human plasma by gas chromatography/mass spectrometry

    NARCIS (Netherlands)

    Ackermans, M. T.; Ruiter, A. F.; Endert, E.

    1998-01-01

    An analytical method is presented to determine glycerol concentrations and stable isotope tracer enrichments in human plasma after intravenous tracer infusion in a single analytical run, using gas chromatography coupled to mass spectrometry. The method uses an internal standard, which is also a

  4. Radiation loads on the ITER first wall during massive gas injection

    Energy Technology Data Exchange (ETDEWEB)

    Landman, I., E-mail: igor.landman@kit.edu [Karlsruhe Institute of Technology, IHM, P.O. Box 3640, 76021 Karlsruhe (Germany); Bazylev, B. [Karlsruhe Institute of Technology, IHM, P.O. Box 3640, 76021 Karlsruhe (Germany); Pitts, R.A. [ITER Organization, Route de Vinon sur Verdon, 13115 Saint Paul Lez Durance (France); Saibene, G. [Fusion for Energy Joint Undertaking, Josep Pla no. 2 – Torres Diagonal Litoral Edificio B3 7/03, Barselona 08019 (Spain); Pestchanyi, S. [Karlsruhe Institute of Technology, IHM, P.O. Box 3640, 76021 Karlsruhe (Germany); Putvinski, S.; Sugihara, M. [ITER Organization, Route de Vinon sur Verdon, 13115 Saint Paul Lez Durance (France)

    2013-10-15

    Highlights: • The massive gas injection (neon) is simulated with the two-dimensional tokamak code TOKES assuming the toroidal symmetry. • The neon injection, assimilation and transport of impurities through the entire plasma volume are modelled. • The output of TOKES is used by the melt motion code MEMOS to assess beryllium wall temperature and the regime with melting. • Complete plasma cooling occurs in minimum time of 5.7 ms with avoiding Be melting at any point on the first wall. -- Abstract: Unmitigated disruptions in ITER can produce strong localized surface damage on the first wall (FW). Massive gas injection (MGI) systems are being designed to dissipate a large fraction of the plasma stored energy at the disruption thermal quench (TQ) and hence reduce the consequences for FW components. The stored energies can be high enough, however, for there to be potential for the photon flash at the MGI TQ to drive local melting of beryllium FW components. To estimate the poloidal distribution of FW surface temperatures, the MGI process is being simulated using the 2D code TOKES, assuming toroidal symmetry. High pressure neon injection, assimilation and transport of injected impurities through the entire plasma volume are modelled. The output of these simulations is used by the melt motion code MEMOS to assess the resulting maximum surface temperature and the regimes with melting on the FW surface.

  5. Analysis of Precooling Injection Transient of Steam Generator for High Temperature Gas Cooled Reactor

    Directory of Open Access Journals (Sweden)

    Yan Wang

    2017-01-01

    Full Text Available After a postulated design basis accident leads high temperature gas cooled reactor to emergency shutdown, steam generator still remains with high temperature level and needs to be cooled down by a precooling before reactor restarts with clearing of fault. For the large difference of coolant temperature between inlet and outlet of steam generator in normal operation, the temperature distribution on the components of steam generator is very complicated. Therefore, the temperature descending rate of the components in steam generator needs to be limited to avoid the potential damage during the precooling stage. In this paper, a pebble-bed high temperature gas cooled reactor is modeled by thermal-hydraulic system analysis code and several postulated precooling injection transients are simulated and compared to evaluate their effects, which will provide support for the precooling design. The analysis results show that enough precooling injection is necessary to satisfy the precooling requirements, and larger mass flow rate of precooling water injection will accelerate the precooling process. The temperature decrease of steam generator is related to the precooling injection scenarios, and the maximal mass flow rate of the precooling injection should be limited to avoid the excessively quick temperature change of the structures in steam generator.

  6. On-Line Enrichment Monitor (OLEM) Phase II Final Report Techniques and Equipment for Safeguards at Gas Centrifuge Enrichment Plants

    Energy Technology Data Exchange (ETDEWEB)

    Younkin, James R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Garner, James R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2017-04-01

    Over the last five years, OLEM has been a collaborative development effort involving the IAEA, LANL, ORNL, URENCO, and the NNSA. The collective team has completed the following: design and modelling, software development, hardware integration, testing with the ORNL UF6 Flow Loop, a field trial at the Urenco facility in Almelo, the Netherlands, and a Demonstration at the Urenco USA facility in Eunice, New Mexico. This combined effort culminated in the deployment of several OLEM collection nodes in Iran. These OLEM units are one unattended monitoring system component of the Joint Comprehensive Plan of Action allowing the International Atomic Energy Agency to verify Iran’s compliance with the enrichment production aspects of the agreement.

  7. Permeability in Rotliegend gas sandstones to gas and brine as predicted from NMR, mercury injection and image analysis

    DEFF Research Database (Denmark)

    Rosenbrand, Esther; Fabricius, Ida Lykke; Fisher, Quentin

    2015-01-01

    Permeability characterisation of low permeability, clay-rich gas sandstones is part of production forecasting and reservoir management. The physically based Kozeny (1927) equation linking permeability with porosity and pore size is derived for a porous medium with a homogeneous pore size, whereas...... the pore sizes in tight sandstones can range from nm to μm. Nuclear magnetic resonance (NMR) transverse relaxation was used to estimate a pore size distribution for 63 samples of Rotliegend sandstone. The surface relaxation parameter required to relate NMR to pore size is estimated by combination of NMR...... and mercury injection data. To estimate which pores control permeability to gas, gas permeability was calculated for each pore size increment by using the Kozeny equation. Permeability to brine is modelled by assuming a bound water layer on the mineral pore interface. The measured brine permeabilities...

  8. Performance and environment as objectives in multi-criterion optimization of steam injected gas turbine cycles

    International Nuclear Information System (INIS)

    Kayadelen, Hasan Kayhan; Ust, Yasin

    2014-01-01

    Rapidly growing demand for gas turbines promotes research on their performance improvement and reducing their exhaust pollutants. Even small increments in net power or thermal efficiency and small changes in pollutant emissions have become significant concerns for both new designs and cycle modifications. To fulfill these requirements an accurate performance evaluation method which enables to see the effects on the exhaust gas composition is an important necessity. To fill this gap, a thermo-ecologic performance evaluation approach for gas turbine cycles with chemical equilibrium approximation which enables performance and environmental aspects to be considered simultaneously, is presented in this work. Steam injection is an effective modification to boost power and limit NO x emissions for gas turbine systems. Steam injection also increases thermal efficiency so less fuel is burnt to maintain the same power output. Because of its performance related and environmental advantages, presented approach is applied on the steam injected gas turbine cycle and a precise multi-criterion optimization is carried out for varying steam injection, as well as equivalence and pressure ratios. Irreversibilities and pressure losses are also considered. Effects of each parameter on the net work and thermal efficiency as well as non-equilibrium NO x and CO emissions are demonstrated. Precision improvement of the presented thermo-ecological model is shown and two main concerns; constant turbine inlet condition for higher net work output and constant net work output condition for lower fuel consumption are compared. - Highlights: • A thermodynamically precise performance estimation tool for GT cycles is presented. • STIG application is provided to show its flexibility for any GT cycle and diluents. • Constant TIT and net work output conditions have been compared and discussed. • The model provides results to evaluate economic and environmental aspects together. • It provides a

  9. Apparent Km of mitochondria for oxygen computed from Vmax measured in permeabilized muscle fibers is lower in water enriched in oxygen by electrolysis than injection

    Science.gov (United States)

    Zoll, Joffrey; Bouitbir, Jamal; Sirvent, Pascal; Klein, Alexis; Charton, Antoine; Jimenez, Liliana; Péronnet, François R; Geny, Bernard; Richard, Ruddy

    2015-01-01

    Background It has been suggested that oxygen (O2) diffusion could be favored in water enriched in O2 by a new electrolytic process because of O2 trapping in water superstructures (clathrates), which could reduce the local pressure/content relationships for O2 and facilitate O2 diffusion along PO2 gradients. Materials and methods Mitochondrial respiration was compared in situ in saponin-skinned fibers isolated from the soleus muscles of Wistar rats, in solution enriched in O2 by injection or the electrolytic process 1) at an O2 concentration decreasing from 240 µmol/L to 10 µmol/L (132 mmHg to 5 mmHg), with glutamate–malate or N, N, N′, N′-tetramethyl-p-phenylenediamine dihydrochloride (TMPD)–ascorbate (with antimycin A) as substrates; and 2) at increasing adenosine diphosphate (ADP) concentration with glutamate–malate as substrate. Results As expected, maximal respiration decreased with O2 concentration and, when compared to glutamate–malate, the apparent Km O2 of mitochondria for O2 was significantly lower with TMPD–ascorbate with both waters. However, when compared to the water enriched in O2 by injection, the Km O2 was significantly lower with both electron donors in water enriched in O2 by electrolysis. This was not associated with any increase in the sensitivity of mitochondria to ADP; no significant difference was observed for the Km ADP between the two waters. Conclusion In this experiment, a higher affinity of the mitochondria for O2 was observed in water enriched in O2 by electrolysis than by injection. This observation is consistent with the hypothesis that O2 diffusion can be facilitated in water enriched in O2 by the electrolytic process. PMID:26203225

  10. Re-injection feasibility study of fracturing flow-back fluid in shale gas mining

    Science.gov (United States)

    Kang, Dingyu; Xue, Chen; Chen, Xinjian; Du, Jiajia; Shi, Shengwei; Qu, Chengtun; Yu, Tao

    2018-02-01

    Fracturing flow-back fluid in shale gas mining is usually treated by re-injecting into formation. After treatment, the fracturing flow-back fluid is injected back into the formation. In order to ensure that it will not cause too much damage to the bottom layer, feasibility evaluations of re-injection of two kinds of fracturing fluid with different salinity were researched. The experimental research of the compatibility of mixed water samples based on the static simulation method was conducted. Through the analysis of ion concentration, the amount of scale buildup and clay swelling rate, the feasibility of re-injection of different fracturing fluid were studied. The result shows that the swelling of the clay expansion rate of treated fracturing fluid is lower than the mixed water of treated fracturing fluid and the distilled water, indicating that in terms of clay expansion rate, the treated fracturing flow-back fluid is better than that of water injection after re-injection. In the compatibility test, the maximum amount of fouling in the Yangzhou oilfield is 12mg/L, and the maximum value of calcium loss rate is 1.47%, indicating that the compatibility is good. For the fracturing fluid with high salinity in the Yanchang oilfield, the maximum amount of scaling is 72mg/L, and the maximum calcium loss rate is 3.50%, indicating that the compatibility is better.

  11. Numerical investigation of natural gas direct injection properties and mixture formation in a spark ignition engine

    Directory of Open Access Journals (Sweden)

    Yadollahi Bijan

    2014-01-01

    Full Text Available In this study, a numerical model has been developed in AVL FIRE software to perform investigation of Direct Natural Gas Injection into the cylinder of Spark Ignition Internal Combustion Engines. In this regard two main parts have been taken into consideration, aiming to convert an MPFI gasoline engine to direct injection NG engine. In the first part of study multi-dimensional numerical simulation of transient injection process, mixing and flow field have been performed via three different validation cases in order to assure the numerical model validity of results. Adaption of such a modeling was found to be a challenging task because of required computational effort and numerical instabilities. In all cases present results were found to have excellent agreement with experimental and numerical results from literature. In the second part, using the moving mesh capability the validated model has been applied to methane Injection into the cylinder of a Direct Injection engine. Five different piston head shapes along with two injector types have been taken into consideration in investigations. A centrally mounted injector location has been adapted to all cases. The effects of injection parameters, combustion chamber geometry, injector type and engine RPM have been studied on mixing of air-fuel inside cylinder. Based on the results, suitable geometrical configuration for a NG DI Engine has been discussed.

  12. Enchancing the use of coal by gas reburning and sorben injection

    International Nuclear Information System (INIS)

    Keen, R.T.; Hong, C.C.; Opatrny, J.C.; Sommer, T.M.; Folsom, B.A.; Payne, R.; Ritz, H.J.; Pratapas, J.M.; May, T.J.; Krueger, M.S.

    1993-01-01

    The Gas Reburning-Sorbent Injection (GR-SI) Process was demonstrated on a 71 MWe net tangentially fired boiler at Hennepin, Illinois, and is being demonstrated on a 33 MWe net cyclone-fired boiler at Springfield, Illinois as a Clean Coal Technology Round I demonstration project. The Hennepin demonstration was completed after more than 2,000 hours of successful operation. In long-term demonstration testing at a Ca/S molar ratio of 1.75 an 19 percent gas heat input, 53 percent SO 2 reduction and 67 percent NO x reduction were achieved without any adverse impacts on boiler performance or electrostatic precipitator performance with flue gas humidification. These achievements exceeded the project goals of 50 and 60 percent, respectively. The CO 2 reduction due to the use of 18 percent natural gas was 8 percent

  13. Impairment from gas narcosis when breathing air and enriched air nitrox underwater.

    Science.gov (United States)

    Hobbs, Malcolm B

    2014-11-01

    Nitrogen (N2) in air causes cognitive impairment from gas narcosis when breathed at increased ambient pressures. This impairment might be reduced by using enriched air nitrox (EANx) mixtures, which have a higher oxygen and lower N2 content compared to air. This study aimed to investigate if divers differed in memory ability and self-assessment when breathing air and EANx30. The effect of depth (shallow vs. deep) and breathing gas (air vs. EANx30) on memory ability and subjective ratings of impairment was compared in 20 divers. Memory performance was significantly worse in deep water (Air: M = 22.1%, SD = 21.7%; EANx30: M = 22.1%, SD = 17.2%) compared to shallow water (Air: M = 29.2%, SD = 18.3%; EANx30: M = 33.3%, SD = 18.2%), but this impairment did not differ significantly between air and EANx30. Subjective ratings of impairment increased significantly from shallow water (Air: M = 5.2, SD = 5.9; EANx30: M = 3.0, SD = 4.4) to deep water (Air: M = 36.8, SD = 25.3; EANx30: M = 24.8, SD = 16.1) when breathing both air and EANx30. However, ratings were significantly lower when breathing EANx30 compared to air when in the deep water. It was concluded EANx30 does not reduce narcotic impairment over air. Additionally, divers were able to make a correct global self-assessment they were impaired by narcosis, but were unable to make a finer assessment, leading them to erroneously believe that EANx30 was less narcotic than air.

  14. Large scale gas injection test (Lasgit) performed at the Aespoe Hard Rock Laboratory. Summary report 2008

    International Nuclear Information System (INIS)

    Cuss, R.J.; Harrington, J.F.; Noy, D.J.

    2010-02-01

    This report describes the set-up, operation and observations from the first 1,385 days (3.8 years) of the large scale gas injection test (Lasgit) experiment conducted at the Aespoe Hard Rock Laboratory. During this time the bentonite buffer has been artificially hydrated and has given new insight into the evolution of the buffer. After 2 years (849 days) of artificial hydration a canister filter was identified to perform a series of hydraulic and gas tests, a period that lasted 268 days. The results from the gas test showed that the full-scale bentonite buffer behaved in a similar way to previous laboratory experiments. This confirms the up-scaling of laboratory observations with the addition of considerable information on the stress responses throughout the deposition hole. During the gas testing stage, the buffer was continued to artificially hydrate. Hydraulic results, from controlled and uncontrolled events, show that the buffer continues to mature and has yet to reach full maturation. Lasgit has yielded high quality data relating to the hydration of the bentonite and the evolution in hydrogeological properties adjacent to the deposition hole. The initial hydraulic and gas injection tests confirm the correct working of all control and data acquisition systems. Lasgit has been in successful operation for in excess of 1,385 days

  15. Large scale gas injection test (Lasgit) performed at the Aespoe Hard Rock Laboratory. Summary report 2008

    Energy Technology Data Exchange (ETDEWEB)

    Cuss, R.J.; Harrington, J.F.; Noy, D.J. (British Geological Survey (United Kingdom))

    2010-02-15

    This report describes the set-up, operation and observations from the first 1,385 days (3.8 years) of the large scale gas injection test (Lasgit) experiment conducted at the Aespoe Hard Rock Laboratory. During this time the bentonite buffer has been artificially hydrated and has given new insight into the evolution of the buffer. After 2 years (849 days) of artificial hydration a canister filter was identified to perform a series of hydraulic and gas tests, a period that lasted 268 days. The results from the gas test showed that the full-scale bentonite buffer behaved in a similar way to previous laboratory experiments. This confirms the up-scaling of laboratory observations with the addition of considerable information on the stress responses throughout the deposition hole. During the gas testing stage, the buffer was continued to artificially hydrate. Hydraulic results, from controlled and uncontrolled events, show that the buffer continues to mature and has yet to reach full maturation. Lasgit has yielded high quality data relating to the hydration of the bentonite and the evolution in hydrogeological properties adjacent to the deposition hole. The initial hydraulic and gas injection tests confirm the correct working of all control and data acquisition systems. Lasgit has been in successful operation for in excess of 1,385 days

  16. In-Born Radio Frequency Identification Devices for Safeguards Use at Gas-Centrifuge Enrichment Plants

    International Nuclear Information System (INIS)

    Ward, R.; Rosenthal, M.

    2009-01-01

    Global expansion of nuclear power has made the need for improved safeguards measures at Gas Centrifuge Enrichment Plants (GCEPs) imperative. One technology under consideration for safeguards applications is Radio Frequency Identification Devices (RFIDs). RFIDs have the potential to increase IAEA inspector's efficiency and effectiveness either by reducing the number of inspection visits necessary or by reducing inspection effort at those visits. This study assesses the use of RFIDs as an integral component of the 'Option 4' safeguards approach developed by Bruce Moran, U.S. Nuclear Regulatory Commission (NRC), for a model GCEP [1]. A previous analysis of RFIDs was conducted by Jae Jo, Brookhaven National Laboratory (BNL), which evaluated the effectiveness of an RFID tag applied by the facility operator [2]. This paper presents a similar evaluation carried out in the framework of Jo's paper, but it is predicated on the assumption that the RFID tag is applied by the manufacturer at the birth of the cylinder, rather than by the operator. Relevant diversion scenarios are examined to determine if RFIDs increase the effectiveness and/ or efficiency of safeguards in these scenarios. Conclusions on the benefits offered to inspectors by using in-born RFID tagging are presented.

  17. Hydrogen enriched compressed natural gas (HCNG: A futuristic fuel for internal combustion engines

    Directory of Open Access Journals (Sweden)

    Nanthagopal Kasianantham

    2011-01-01

    Full Text Available Air pollution is fast becoming a serious global problem with increasing population and its subsequent demands. This has resulted in increased usage of hydrogen as fuel for internal combustion engines. Hydrogen resources are vast and it is considered as one of the most promising fuel for automotive sector. As the required hydrogen infrastructure and refueling stations are not meeting the demand, widespread introduction of hydrogen vehicles is not possible in the near future. One of the solutions for this hurdle is to blend hydrogen with methane. Such types of blends take benefit of the unique combustion properties of hydrogen and at the same time reduce the demand for pure hydrogen. Enriching natural gas with hydrogen could be a potential alternative to common hydrocarbon fuels for internal combustion engine applications. Many researchers are working on this for the last few years and work is now focused on how to use this kind of fuel to its maximum extent. This technical note is an assessment of HCNG usage in case of internal combustion engines. Several examples and their salient features have been discussed. Finally, overall effects of hydrogen addition on an engine fueled with HCNG under various conditions are illustrated. In addition, the scope and challenges being faced in this area of research are clearly described.

  18. Neural control systems for alternatively fuelled vehicles and natural gas fuel injection for DACIA NOVA

    Energy Technology Data Exchange (ETDEWEB)

    Sulatisky, M. [Saskatchewan Research Council, Saskatoon, SK (Canada); Ghelesel, A. [BC Gas International, Vancouver, BC (Canada)

    1999-07-01

    The elements of natural gas vehicle conversion technology are described as background to a discussion of the development of bi-fuel injection system for the Rumanian-manufactured DACIA-NOVA automobile. The bi-fuel injection system mirrors the fueling system installed by the original equipment manufacturer; it can also be easily installed on Ford, General Motors and DaimlerChrysler vehicles as well as on most imports.To meet emission standards after 2000, it is envisaged to install on the DACIA NOVA a neural control system (NCS) and a completely adaptive linear control system (ACLS). Details of natural gas vehicles development and the development of NCS and ACLS are discussed, including short-term and long-term objectives.

  19. Numerical analysis of experiments with gas injection into liquid metal coolant

    International Nuclear Information System (INIS)

    Usov, E V; Lobanov, P D; Pribaturin, N A; Mosunova, N A; Chuhno, V I; Kutlimetov, A E

    2016-01-01

    Presented paper contains results of a numerical analysis of experiments with gas injection in water and liquid metal which have been performed at the Institute of Thermophysics Russian Academy of Science (IT RAS). Obtained experimental data are very important to predict processes that take place in the BREST-type reactor during the hypothetical accident with damage of the steam generator tubes, and may be used as a benchmark to validate thermo-hydraulic codes. Detailed description of models to simulate transport of gas phase in a vertical liquid column is presented in a current paper. Two-fluid model with closing relation for wall friction and interface friction coefficients was used to simulate processes which take place in a liquid during injection of gaseous phase. It has being shown that proposed models allow obtaining a good agreement between experimental data and calculation results. (paper)

  20. A description of the ITER's gas injection systems and current R and D activities

    International Nuclear Information System (INIS)

    Li, W.; Li, B.; Maruyama, S.; Jiang, T.; Yang, Y.; Xia, Z.W.; Zhang, Y.X.; Lu, J.

    2012-01-01

    The gas injection system (GIS) is an indispensable part of ITER fueling system. It deliveries the necessary gas species from tritium plant to vacuum vessel, pellet injection system or neutral beam for plasma operation and fusion power shutdown. In this paper, the current design status of GIS, including the previous design changes, is briefly described. As the GIS design justification and support, the experimental study on GIS response time is illustrated. The factors delayed the GIS response time are identified, and two kinds of control mode are proved to be effective for improving the GIS response time. The exploration on magnetic shield design shows the discrepancy of shielding performance occurs in the case of the paralleling external magnetic field to the sample cylinder. These R and D works prove the design feasibility in some ways, and support possible solutions for design challenges as alternative design options.

  1. High-pressure liquid chromatography with direct injection of gas sample.

    Science.gov (United States)

    Astanin, Anton I; Baram, Grigory I

    2017-06-09

    The conventional method of using liquid chromatography to determine the composition of a gaseous mixture entails dissolving vapors in a suitable solvent, then obtaining a chromatograph of the resulting solution. We studied the direct introduction of a gaseous sample into a C18 reversed-phase column, followed by separation of the components by HPLC with UV detection. Since the chromatography was performed at high pressure, vapors readily dissolved in the eluent and the substances separated in the column as effectively as in liquid samples. Samples were injected into the column in two ways: a) through the valve without a flow stop; b) after stopping the flow and relieving all pressure. We showed that an injectable gas volume could reach 70% of column dead volume. When an injected gaseous sample volume was less than 10% of the column dead volume, the resulting peaks were symmetrical and the column efficiency was high. Copyright © 2017 Elsevier B.V. All rights reserved.

  2. Performance analysis of a small regenerative gas turbine system adopting steam injection and side-wall in finned tube evaporator

    International Nuclear Information System (INIS)

    Kang, Soo Young; Lee, Jong Jun; Kim, Tong Seop

    2009-01-01

    Small gas turbines in power range of several MWs are quite suitable for application in distributed generation as well as Community Energy Systems (CES). Humidification is an effective way to improve gas turbine performance, and steam injection is the most general and practically feasible method. This study intended to examine the effect of steam injection on the performance of several MW class gas turbines. A primary concern is given to the regenerative cycle gas turbine. The steam injection effect on the performance of a system without the regenerator (i.e. a simple cycle) is also examined. In addition, the influence of bypass of some of the exhaust gas on the performance of the gas turbine, especially the regenerative cycle gas turbine, is evaluated.

  3. Synthesis of diamond-like carbon via PECD using a streaming neutral gas injection hollow cathode

    International Nuclear Information System (INIS)

    Pacho, A.; Pares, E.; Ramos, H.; Mendenilla, A.; Malapit, G.

    2009-01-01

    A streaming neutral gas injection hollow cathode system was used to deposit diamond-like carbon films via plasma enhanced chemical vapor deposition on silicon and nickel-coated silicon substrates with acetylene and hydrogen as reactant gases. Samples were characterized using SEM and Raman spectroscopy. The work presented here aims to demonstrate the capability of the system to synthesize carbonaceous films and is starting point towards work on formation of carbon nanostructures. (author)

  4. Preliminary Failure Modes and Effects Analysis of the US Massive Gas Injection Disruption Mitigation System Design

    Energy Technology Data Exchange (ETDEWEB)

    Cadwallader, Lee C. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2013-10-01

    This report presents the results of a preliminary failure modes and effects analysis (FMEA) of a candidate design for the ITER Disruption Mitigation System. This candidate is the Massive Gas Injection System that provides machine protection in a plasma disruption event. The FMEA was quantified with “generic” component failure rate data as well as some data calculated from operating facilities, and the failure events were ranked for their criticality to system operation.

  5. Effect of intake manifold water injection on a natural gas spark ignition engine: an experimental study

    Science.gov (United States)

    Arruga, H.; Scholl, F.; Kettner, M.; Amad, O. I.; Klaissle, M.; Giménez, B.

    2017-10-01

    Design and development of gas CHP (combined heat and power) engines are strongly influenced by the progressively more severe European NOx emissions normative. Water injection represents a promising approach to reduce these emissions while attaining high engine efficiency. In this work, the effect of intake manifold water injection on combustion parameters and performance of a single-cylinder naturally aspirated natural gas spark ignition engine is presented. First, the most appropriate injector was selected, using a spray test bed. Subsequently, engine experiments at constant indicated mean effective pressure (IMEP) and engine speed were conducted with water-fuel ratios of 0.1 to 0.3. IMEP was kept constant at about 6.3 bar by adjusting both air-fuel ratio and spark timing. A NOx reduction of 0.2 g/kWhi (15 %) for a constant ISFC of about 204 g/kWhi was achieved. In the low NOx regime, water injection allows for an improvement of the NOx-ISFC trade-off, while leading to poor fuel consumption at same NOx in the high efficiency regime. Furthermore, water injection implies a reduction of intake mixture temperature, lengthened burning delay and combustion duration and a moderate increase of combustion instability.

  6. Quantification of Stable Isotope Traces Close to Natural Enrichment in Human Plasma Metabolites Using Gas Chromatography-Mass Spectrometry

    Directory of Open Access Journals (Sweden)

    Lisa Krämer

    2018-02-01

    Full Text Available Currently, changes in metabolic fluxes following consumption of stable isotope-enriched foods are usually limited to the analysis of postprandial kinetics of glucose. Kinetic information on a larger diversity of metabolites is often lacking, mainly due to the marginal percentage of fully isotopically enriched plant material in the administered food product, and hence, an even weaker 13C enrichment in downstream plasma metabolites. Therefore, we developed an analytical workflow to determine weak 13C enrichments of diverse plasma metabolites with conventional gas chromatography-mass spectrometry (GC-MS. The limit of quantification was increased by optimizing (1 the metabolite extraction from plasma, (2 the GC-MS measurement, and (3 most importantly, the computational data processing. We applied our workflow to study the catabolic dynamics of 13C-enriched wheat bread in three human subjects. For that purpose, we collected time-resolved human plasma samples at 16 timepoints after the consumption of 13C-labeled bread and quantified 13C enrichment of 12 metabolites (glucose, lactate, alanine, glycine, serine, citrate, glutamate, glutamine, valine, isoleucine, tyrosine, and threonine. Based on isotopomer specific analysis, we were able to distinguish catabolic profiles of starch and protein hydrolysis. More generally, our study highlights that conventional GC-MS equipment is sufficient to detect isotope traces below 1% if an appropriate data processing is integrated.

  7. Quantification of Stable Isotope Traces Close to Natural Enrichment in Human Plasma Metabolites Using Gas Chromatography-Mass Spectrometry.

    Science.gov (United States)

    Krämer, Lisa; Jäger, Christian; Trezzi, Jean-Pierre; Jacobs, Doris M; Hiller, Karsten

    2018-02-14

    Currently, changes in metabolic fluxes following consumption of stable isotope-enriched foods are usually limited to the analysis of postprandial kinetics of glucose. Kinetic information on a larger diversity of metabolites is often lacking, mainly due to the marginal percentage of fully isotopically enriched plant material in the administered food product, and hence, an even weaker 13 C enrichment in downstream plasma metabolites. Therefore, we developed an analytical workflow to determine weak 13 C enrichments of diverse plasma metabolites with conventional gas chromatography-mass spectrometry (GC-MS). The limit of quantification was increased by optimizing (1) the metabolite extraction from plasma, (2) the GC-MS measurement, and (3) most importantly, the computational data processing. We applied our workflow to study the catabolic dynamics of 13 C-enriched wheat bread in three human subjects. For that purpose, we collected time-resolved human plasma samples at 16 timepoints after the consumption of 13 C-labeled bread and quantified 13 C enrichment of 12 metabolites (glucose, lactate, alanine, glycine, serine, citrate, glutamate, glutamine, valine, isoleucine, tyrosine, and threonine). Based on isotopomer specific analysis, we were able to distinguish catabolic profiles of starch and protein hydrolysis. More generally, our study highlights that conventional GC-MS equipment is sufficient to detect isotope traces below 1% if an appropriate data processing is integrated.

  8. Tokamak experiments on JIPP T-II with pulsed gas injection

    International Nuclear Information System (INIS)

    Toi, K.; Itoh, S.; Fujita, J.; Kadota, K.; Kawahata, K.

    1978-02-01

    The confinement of tokamak plasma has been investigated in the wide range of electron density average n sub(e) from 1 x 10 13 to 5 x 10 13 cm -3 by using the pulsed gas injection. The gross energy confinement time increases with increase of electron density and reaches 14 msec. The averaged effective ionic charge derived from plasma conductivity = is about 1 to 2 in the regime of small streaming parameter ( = 0.01 -- 0.08). The ratio of ion temperature to electron one is in the range greater than 0.5. This fact means that the ion energy confinement time is greater than the electron-ion energy relaxation time. Excessive injection of cold neutral gas excites m = 2 MHD oscillations. Much more gas injection leads to the remarkable cooling of plasma periphery and disruptive instabilities. These MHD oscillations and disruptive instabilities have been suppressed by the heating of plasma periphery with the second rapid rise of plasma current. (auth.)

  9. Study of H2S increasing in gas production of vapor continuous injection

    Energy Technology Data Exchange (ETDEWEB)

    Centeno, J. [PDVSA INTEVEP (Venezuela)

    2011-07-01

    In the heavy oil industry, thermal recovery methods are often used to enhance oil recovery, continuous vapor injection is one of them. In this method, water vapor is injected into the reservoir at high temperatures, affecting the geochemical system of the fluid reservoir. It has been noticed that the use of the continuous vapor injection method results in increased concentrations of H2S in gas production. Previous studies proved that H2S diffusion is affected by the H2S/CO2 ratio and this paper aimed at determining the influence of such ratios on the diffusion properties of acid gases. Experiments were conducted with three different H2S/CO2 ratios and heavy oil samples from Orinoco oil elt. Results showed that acid gas diffusion decreases when the H2S/CO2 ratio increases and that the diffusion of H2S is better with a high percentage of water. This study successfully assessed the variation of acid gas diffusion with different values of H2S/CO2 ratios and water percentages.

  10. Opportunities and challenges in green house gases reduction using high pressure direct injection of natural gas

    International Nuclear Information System (INIS)

    Ouellette, P.

    2001-01-01

    In an effort to reduce Greenhouse Gases, Westport Innovations is developing a high pressure direct injection (HPDI) technology for gaseous fuels. This technology adapts the diesel cycle for gaseous fuels, since the diesel cycle provides high efficiency, high low-speed torque, fast transient capabilities and reliability. Because of their high efficiency, diesels are very favorable from a Greenhouse Gas (GHG) point of view, however they remain challenged by high nitrogen oxides (NOx) and particulate matter (PM) emissions. When directly injecting natural gas, NOx and PM emissions can be reduced by approximately 50% while maintaining the performance of the diesel engine. This allows the use of abundant and historically cheaper natural gas. Because of its lower carbon content per unit energy, natural gas also offers further GHG reduction over the diesel if the efficiency is preserved and if methane emissions are low. This paper discusses development efforts at Westport for several applications including on-highway trucks, light-duty delivery trucks and power generation

  11. Effect of Injection Location and Multi-Hole Nozzle on Mixing Performance in a CNG-Fuelled Engine with Port Gas Injection, Using CFD Analyses

    Directory of Open Access Journals (Sweden)

    Wang Tianbo

    2017-01-01

    Full Text Available A compressed natural gas injection device with moving-coil electromagnetic linear actuator and mushroom type poppet valve was designed to supply a large-bore intake port injection type engine with sufficient fuel timely. The transient engine CFD model combined with the poppet valve's motion was established to research the effect of injection conditions on the mixing homogeneity in the intake port and cylinder. Computed penetration distances of impinging jet with different k-ε models and different wall functions are compared with measured results in the literature to validate the model. It was observed that the gas injection location and number of nozzle holes have a significant effect on mixing performance both in the intake port and cylinder.

  12. Prediction of the Gas Injection Effect on the Asphaltene Phase Envelope

    Directory of Open Access Journals (Sweden)

    Bahrami Peyman

    2015-11-01

    Full Text Available Asphaltene instability may occur when pressure, temperature and compositional variations affect the reservoir oil. Permeability reduction, wettability alteration, and plugging of wells and flow lines are the consequences of this phenomenon. Therefore, it is crucial to investigate the asphaltene behavior in different thermodynamic conditions by knowing the Asphaltene Precipitation Envelope (APE in a preventive way rather than the costly clean-up procedures. The selected reservoir oil has faced a remarkable decline in production due to several years of extraction, and Enhanced Oil Recovery (EOR has been considered as a solution. Therefore, in this paper, a comprehensive study was carried out to predict the effects of different injected gases on asphaltene onset and to prevent future asphaltene precipitation based on the laboratory data. The Advanced Redlich-Kwong-Soave (RKSA equation of state was considered to develop APE using Multiflash (Infochem Co.. For the selected reservoir oil, with temperature reduction at low temperatures, asphaltene precipitation weakened and made the onset pressure decrease, so this behavior is different from the results obtained in other published reports. On the basis of this model, several sensitivity analyses were performed with different gases (i.e., methane, CO2, N2 and associated gases to compare the risk of each gas for future EOR strategies. APE tend to expand as the amount of injected gases increases, except for CO2 gas injection, that showed another unconventional behavior for this crude oil. It was observed that for CO2 gas injection below a certain temperature, asphaltene stability increased, which can be considered as a good inhibitor of asphaltene precipitation.

  13. Hot surface assisted compression ignition in a direct injection natural gas engine

    Energy Technology Data Exchange (ETDEWEB)

    Aesoey, Vilmar

    1996-12-31

    This study investigates the problem of ignition in a direct injection natural gas engine. Due to poor auto-ignition properties of natural gas compared to regular diesel engine fuels, a special arrangement to assist and secure ignition is required. The objective was to investigate the feasibility of using a hot surface as ignition assistance, primarily for application in medium and large size engines, and further study the main mechanisms involved in the ignition process. A constant volume combustion bomb and a test engine are used for experiments, supported by theoretical analysis and numerical simulations. Variable composition of natural gas depending on the gas source and over time, is a important problem causing significant variation in ignition properties. It is shown that even small quantities of non-methane components, which are normally present in natural gases, strongly influence ignition. Actions to handle the ignition problem caused by variable natural composition, are also discussed. In order to estimate the ignition properties of natural gas, a simple correlation to gas composition is proposed, showing good correlation to the experimental data. Mathematical models for simulation of the processes are developed based on fundamental physical relations and experimental results. They are mainly used in this study to support and analyze the physical experiments, but can also be useful in future design and optimization processes. 71 refs., 80 figs., 6 tabs.

  14. GreenGasGrids. A vision for biomethane in France for 2030. Injection of purified gas into the natural gas network

    International Nuclear Information System (INIS)

    2014-10-01

    This publication proposes a presentation of the activity of a work group on the injection of biomethane into natural gas networks, presents some key data and definitions regarding the production of biogas and its valorisation (co-generation and biomethane), some results and a brief presentation of scenarios and their hypotheses about the development of resources and biogas-based energy production. Results are presented for a trend-based scenario and a pro-active scenario. The last part presents the European GreenGasGrids project which aimed at stimulating the biomethane European market

  15. Gas exchange and growth responses to nutrient enrichment in invasive Glyceria maxima and native New Zealand Carex species

    DEFF Research Database (Denmark)

    Sorrell, Brian Keith; Brix, Hans; Fitridge, Isla

    2012-01-01

    , but that its success under nutrient enrichment is a consequence of greater physiological responsiveness and growth plasticity, and stronger integration between gas exchange and growth, coupled with indifference to resource wastage (i.e. low WUE and NUE) at high nutrient supply. The poorer performance of G......We compared photosynthetic gas exchange, the photosynthesis-leaf nitrogen (N) relationship, and growth response to nutrient enrichment in the invasive wetland grass Glyceria maxima (Hartman) Holmburg with two native New Zealand Carex sedges (C. virgata Boott and C. secta Boott), to explore...... the ecophysiological traits contributing to invasive behaviour. The photosynthesis-nitrogen relationship was uniform across all three species, and the maximum light-saturated rate of photosynthesis expressed on a leaf area basis (Amaxa) did not differ significantly between species. However, specific leaf area (SLA...

  16. Impact of gas injection on the apparent viscosity and viscoelastic property of waste activated sewage sludge.

    Science.gov (United States)

    Bobade, Veena; Baudez, Jean Christophe; Evans, Geoffery; Eshtiaghi, Nicky

    2017-05-01

    Gas injection is known to play a major role on the particle size of the sludge, the oxygen transfer rate, as well as the mixing efficiency of membrane bioreactors and aeration basins in the waste water treatment plants. The rheological characteristics of sludge are closely related to the particle size of the sludge floc. However, particle size of sludge floc depends partly on the shear induced in the sludge and partly on physico-chemical nature of the sludge. The objective of this work is to determine the impact of gas injection on both the apparent viscosity and viscoelastic property of sludge. The apparent viscosity of sludge was investigated by two methods: in-situ and after sparging. Viscosity curves obtained by in-situ measurement showed that the apparent viscosity decreases significantly from 4000 Pa s to 10 Pa s at low shear rate range (below 10 s -1 ) with an increase in gas flow rate (0.5LPM to 3LPM); however the after sparging flow curve analysis showed that the reduction in apparent viscosity throughout the shear rate range is negligible to be displayed. Torque and displacement data at low shear rate range revealed that the obtained lower apparent viscosity in the in-situ method is not the material characteristics, but the slippage effect due to a preferred location of the bubbles close to the bob, causing an inconsistent decrease of torque and increase of displacement at low shear rate range. In linear viscoelastic regime, the elastic and viscous modulus of sludge was reduced by 33% & 25%, respectively, due to gas injection because of induced shear. The amount of induced shear measured through two different tests (creep and time sweep) were the same. The impact of this induced shear on sludge structure was also verified by microscopic images. Copyright © 2017 Elsevier Ltd. All rights reserved.

  17. Gas diffusion-flow injection determination of total inorganic carbon in water using tungsten oxide electrode.

    Science.gov (United States)

    Monser, L; Adhoum, N; Sadok, S

    2004-02-06

    A novel gas diffusion-flow injection method has been developed for the rapid and sensitive determination of total inorganic carbon (TIC) in water. The method is based on the diffusion of CO(2) across gas permeable membrane from a donor stream containing 0.1M HCl to an acceptor stream of sodium acetate (10(-5)moll(-1) and pH 10). The CO(2) trapped in the acceptor stream passes through an electrochemical flow cell contains a tungsten oxide wire and a silver/silver chloride electrode, where it was sensitively detected. The parameters affecting the sensitivity of the electrode such as buffer concentration, pH, flow rate and injected volume were studied in detail. The electrode response was linear in the concentration range from 5 to 100mugml(-1) CO(3)(2-) with a correlation coefficient (R(2)) of 0.998. Precision (R.S.D.) was 1.42% for 20mugml(-1) standard solution of CO(3)(2-) (n=10). The detection limit was 0.20mugml(-1) CO(3)(2-). The method was evaluated by the injection of real natural water samples and an average recovery of 100.1% was obtained. The sampling rate was 30 samplesh(-1). The method is simple, feasible with satisfactory accuracy and precision and thus could be used for monitoring TIC in water.

  18. Exhaust gas heat recovery through secondary expansion cylinder and water injection in an internal combustion engine

    Directory of Open Access Journals (Sweden)

    Nassiri Toosi Ali

    2017-01-01

    Full Text Available To enhance thermal efficiency and increase performance of an internal combustion engine, a novel concept of coupling a conventional engine with a secondary 4-stroke cylinder and direct water injection process is proposed. The burned gases after working in a traditional 4-stroke combustion cylinder are transferred to a secondary cylinder and expanded even more. After re-compression of the exhaust gases, pre-heated water is injected at top dead center. The evaporation of injected water not only recovers heat from exhaust gases, but also increases the mass of working gas inside the cylinder, therefore improves the overall thermal efficiency. A 0-D/1-D model is used to numerically simulate the idea. The simulations outputs showed that the bottoming cycle will be more efficient at higher engines speeds, specifically in a supercharged/turbocharged engine, which have higher exhaust gas pressure that can reproduce more positive work. In the modeled supercharged engine, results showed that brake thermal efficiency can be improved by about 17%, and brake power by about 17.4%.

  19. Parametric performance analysis of steam-injected gas turbine with a thermionic-energy-converter-lined combustor

    Science.gov (United States)

    Choo, Y. K.; Burns, R. K.

    1982-01-01

    The performance of steam-injected gas turbines having combustors lined with thermionic energy converters (STIG/TEC systems) was analyzed and compared with that of two baseline systems; a steam-injected gas turbine (without a TEC-lined combustor) and a conventional combined gas turbine/steam turbine cycle. Common gas turbine parameters were assumed for all of the systems. Two configurations of the STIG/TEC system were investigated. In both cases, steam produced in an exhaust-heat-recovery boiler cools the TEC collectors. It is then injected into the gas combustion stream and expanded through the gas turbine. The STIG/TEC system combines the advantage of gas turbine steam injection with the conversion of high-temperature combustion heat by TEC's. The addition of TEC's to the baseline steam-injected gas turbine improves both its efficiency and specific power. Depending on system configuration and design parameters, the STIG/TEC system can also achieve higher efficiency and specific power than the baseline combined cycle.

  20. Gas Injection And Fast Pressure-Rise Measurements For The Linac4 H− Source

    CERN Document Server

    Mahner, E; Lettry, J; Mattei, S; O'Neil, M; Neupert, H; Pasquino, C; Schmitzer, C

    2013-01-01

    In the era of the Large Hadron Collider, the CERN injector complex comprising the 34 years old Linac2 with its primary proton source, is presently upgraded with a new linear accelerator for H− (Linac4). The design, construction, and test of volume production and cesiated RF-driven H− ion sources is presently ongoing with the final goal of producing an H− beam with 80 mA beam current, 45 keV beam energy, 500 s pulse length, and a repetition rate of 2 Hz. In order to have quantitative information of the hydrogen gas density at the moment of plasma ignition the dynamic vacuum properties of the plasma generator were studied experimentally. We describe the experimental setup and present fast pressure-rise measurements for different parameters of the gas injection system, such as gas species (H2, He, N2, Ar), piezo valve voltage pulse length (200 - 500 s), and injection pressure (400 - 2800 mbar). The obtained data are compared with a conductance model of the plasma generator.

  1. The injection of inert gas ions into solids: their trapping and escape

    International Nuclear Information System (INIS)

    Carter, G.; Armour, D.G.; Donnelly, S.E.; Ingram, D.C.; Webb, R.P.

    1980-01-01

    The first part of this contribution will review experimental studies of the trapping probabilities of ions injected into solids as a function of ion energy and indicate how the data can be modelled theoretically. It will be demonstrated that trapping is a two stage process, the first involving penetration into the solid and the second requiring atom dissolution and experimental evidence will be cited to show how the latter process may be dominant for light ions which create little radiation damage. For low ion fluences, injected atoms are generally trapped in isolation but as fluence increases gas-defect complexes are formed and it will be shown how post bombardment thermal evaluation studies can provide evidence for the growth of these complexes. Concomitant with trapping however, dissolved gas may be evolved from the solid by some form of sputtering process, sometimes by mechanisms much more efficient than congruent sputtering of the solid together with the trapped species. Measurements of the trapped atom concentration-ion fluence behaviour and of the evolution of one initially trapped species by bombardment with a second species provide information on the physical processes involved in trapped atom sputtering and upon the mechanism of gas incorporation saturation and experimental studies in this area, together with some first approximation theoretical investigations will be discussed. It will be shown that an important mechanism in dictating incorporation saturation, in addition to sputtering, is the atomic saturation of the solid by the implant. (author)

  2. CO2 Capture by Injection of Flue Gas or CO2-N2 Mixtures into Hydrate Reservoirs: Dependence of CO2 Capture Efficiency on Gas Hydrate Reservoir Conditions.

    Science.gov (United States)

    Hassanpouryouzband, Aliakbar; Yang, Jinhai; Tohidi, Bahman; Chuvilin, Evgeny; Istomin, Vladimir; Bukhanov, Boris; Cheremisin, Alexey

    2018-04-03

    Injection of flue gas or CO 2 -N 2 mixtures into gas hydrate reservoirs has been considered as a promising option for geological storage of CO 2 . However, the thermodynamic process in which the CO 2 present in flue gas or a CO 2 -N 2 mixture is captured as hydrate has not been well understood. In this work, a series of experiments were conducted to investigate the dependence of CO 2 capture efficiency on reservoir conditions. The CO 2 capture efficiency was investigated at different injection pressures from 2.6 to 23.8 MPa and hydrate reservoir temperatures from 273.2 to 283.2 K in the presence of two different saturations of methane hydrate. The results showed that more than 60% of the CO 2 in the flue gas was captured and stored as CO 2 hydrate or CO 2 -mixed hydrates, while methane-rich gas was produced. The efficiency of CO 2 capture depends on the reservoir conditions including temperature, pressure, and hydrate saturation. For a certain reservoir temperature, there is an optimum reservoir pressure at which the maximum amount of CO 2 can be captured from the injected flue gas or CO 2 -N 2 mixtures. This finding suggests that it is essential to control the injection pressure to enhance CO 2 capture efficiency by flue gas or CO 2 -N 2 mixtures injection.

  3. Elements and gas enrichment laws of sweet spots in shale gas reservoir: A case study of the Longmaxi Fm in Changning block, Sichuan Basin

    Directory of Open Access Journals (Sweden)

    Renfang Pan

    2016-05-01

    Full Text Available Identification of sweet spot is of great significance in confirming shale gas prospects to realize large-scale economic shale gas development. In this paper, geological characteristics of shale gas reservoirs were compared and analyzed based on abundant data of domestic and foreign shale gas reservoirs. Key elements of sweet spots were illustrated, including net thickness of gas shale, total organic carbon (TOC content, types and maturity (Ro of organic matters, rock matrix and its physical properties (porosity and permeability, and development characteristics of natural fractures. After the data in Changning and Weiyuan blocks, the Sichuan Basin, were analyzed, the geologic laws of shale gas enrichment were summarized based on the economic exploitation characteristics of shale gas and the correlation between the elements. The elements of favorable “sweet spots” of marine shale gas reservoirs in the Changning block and their distribution characteristics were confirmed. Firstly, the quality of gas source rocks is ensured with the continuous thickness of effective gas shale larger than 30 m, TOC > 2.0% and Ro = 2.4–3.5%. Secondly, the quality of reservoir is ensured with the brittle minerals content being 30–69%, the clay mineral content lower than 30% and a single lamination thickness being 0.1–1.0 m. And thirdly, the porosity is higher than 2.0%, the permeability is larger than 50 nD, gas content is higher than 1.45 m3/t, and formation is under normal pressure–overpressure system, which ensures the production modes and capacities. Finally, the primary and secondary elements that control the “sweet spots” of shale gas reservoirs were further analyzed and their restrictive relationships with each other were also discussed.

  4. Electrical resistance tomography during gas injection at the Savannah River Site

    International Nuclear Information System (INIS)

    Ramirez, A.L.; Daily, W.D.

    1993-05-01

    Electrical resistance tomography (ERT) is used to monitor some of the in situ remediation processes being evaluated for removal of volatile organic compounds from subsurface water and soil at the Integrated Demonstration for VOC's in Soils and Groundwater at Non Arid Sites, the Savannah River Site, near Aiken, South Carolina. Air was injected in the saturated zone and the intrained air was tomographically imaged by its effects on the formation electrical resistivity. The authors found that the flow paths are confined to a complex three dimensional network of channels, some of which extend as far as 30 m from the injection well. They conclude, based on these results, that the shape and extent of the air plume are controlled by spatial variations in the local gas permeability. These channels are somewhat unstable over a period of months and new channels appear to form with time

  5. Fault features and enrichment laws of narrow-channel distal tight sandstone gas reservoirs: A case study of the Jurassic Shaximiao Fm gas reservoir in the Zhongjiang Gas Field, Sichuan Basin

    Directory of Open Access Journals (Sweden)

    Zhongping Li

    2016-11-01

    Full Text Available The Jurassic Shaximiao Fm gas reservoir in the Zhongjiang Gas Field, Sichuan Basin, is the main base of Sinopec Southwest Oil & Gas Company for gas reserves and production increase during the 12th Five-Year Plan. However, its natural gas exploration and development process was restricted severely, since the exploration wells cannot be deployed effectively in this area based on the previous gas accumulation and enrichment pattern of “hydrocarbon source fault + channel sand body + local structure”. In this paper, the regional fault features and the gas accumulation and enrichment laws were discussed by analyzing the factors like fault evolution, fault elements, fault-sand body configuration (the configuration relationship between hydrocarbon source faults and channel sand bodies, trap types, and reservoir anatomy. It is concluded that the accumulation and enrichment of the Shaximiao Fm gas reservoir in this area is controlled by three factors, i.e., hydrocarbon source, sedimentary facies and structural position. It follows the accumulation laws of source controlling region, facies controlling zone and position controlling reservoir, which means deep source and shallow accumulation, fault-sand body conductivity, multiphase channel, differential accumulation, adjusted enrichment and gas enrichment at sweet spots. A good configuration relationship between hydrocarbon source faults and channel sand bodies is the basic condition for the formation of gas reservoirs. Natural gas accumulated preferentially in the structures or positions with good fault-sand body configuration. Gas reservoirs can also be formed in the monoclinal structures which were formed after the late structural adjustment. In the zones supported by multiple faults or near the crush zones, no gas accumulation occurs, but water is dominantly produced. The gas-bearing potential is low in the area with undeveloped faults or being 30 km away from the hydrocarbon source faults. So

  6. Analyses of Injection-Coupled Combustion Instability from J-2X Gas Generator Development

    Science.gov (United States)

    Hulka, James R.; Kenny, R. Jeremy; Protz, Chris; Casiano, Matthew

    2011-01-01

    During development of the gas generator for the liquid oxygen/liquid hydrogen propellant J-2X rocket engine, combustion instabilities were observed near the frequency of the first longitudinal acoustic mode of the hot gas combustion chamber duct. These instabilities were similar to intermediate-frequency or buzz-type instabilities as described in historical programs, except for several aspects: 1) the frequencies were low, in the realm of chug; 2) at times the instability oscillation amplitudes were quite large, with peak-to-peak amplitudes exceeding 50% of the mean chamber pressure along with the appearance of harmonics; 3) the chamber excitation was related to but not exactly at the first longitudinal combustion chamber acoustic mode; and 4) the injector provided mass flow rate oscillations induced by capacitance and inertance effects in the injector rather than by organ pipe resonances of the coaxial oxidizer posts. This type of combustion instability is referred to as "injection coupling" because one critical driving source of the instability is mass flow rate oscillations from the injector. However, the type of injection coupling observed here is different than observed in previous instances of buzz instability with coaxial injectors, because of the lower frequencies and lack of influence from the oxidizer post organ pipe resonances. Test data and preliminary analyses of the initial combustion instabilities were presented in several papers at the 5th Liquid Propulsion Subcommittee meeting. Since that time, additional hot-fire tests with several new hardware configurations have been conducted, and additional analyses have been completed. The analytical models described in previous papers have been updated to include the influences of new geometrical configurations, including a different oxidizer injector manifold configuration and a branch pipe in the hot gas duct that supplies gaseous helium during the start transient to pre-spin the turbine. In addition, the

  7. Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas

    Energy Technology Data Exchange (ETDEWEB)

    Carl Richardson; Katherine Dombrowski; Douglas Orr

    2006-12-31

    This project Final Report is submitted to the U.S. Department of Energy (DOE) as part of Cooperative Agreement DE-FC26-03NT41987, 'Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas.' Sorbent injection technology is targeted as the primary mercury control process on plants burning low/medium sulfur bituminous coals equipped with ESP and ESP/FGD systems. About 70% of the ESPs used in the utility industry have SCAs less than 300 ft2/1000 acfm. Prior to this test program, previous sorbent injection tests had focused on large-SCA ESPs. This DOE-NETL program was designed to generate data to evaluate the performance and economic feasibility of sorbent injection for mercury control at power plants that fire bituminous coal and are configured with small-sized electrostatic precipitators and/or an ESP-flue gas desulfurization (FGD) configuration. EPRI and Southern Company were co-funders for the test program. Southern Company and Reliant Energy provided host sites for testing and technical input to the project. URS Group was the prime contractor to NETL. ADA-ES and Apogee Scientific Inc. were sub-contractors to URS and was responsible for all aspects of the sorbent injection systems design, installation and operation at the different host sites. Full-scale sorbent injection for mercury control was evaluated at three sites: Georgia Power's Plant Yates Units 1 and 2 [Georgia Power is a subsidiary of the Southern Company] and Reliant Energy's Shawville Unit 3. Georgia Power's Plant Yates Unit 1 has an existing small-SCA cold-side ESP followed by a Chiyoda CT-121 wet scrubber. Yates Unit 2 is also equipped with a small-SCA ESP and a dual flue gas conditioning system. Unit 2 has no SO2 control system. Shawville Unit 3 is equipped with two small-SCA cold-side ESPs operated in series. All ESP systems tested in this program had SCAs less than 250 ft2/1000 acfm. Short-term parametric tests were conducted on Yates

  8. Quantitative risk management in gas injection project: a case study from Oman oil and gas industry

    Science.gov (United States)

    Khadem, Mohammad Miftaur Rahman Khan; Piya, Sujan; Shamsuzzoha, Ahm

    2017-09-01

    The purpose of this research was to study the recognition, application and quantification of the risks associated in managing projects. In this research, the management of risks in an oil and gas project is studied and implemented within a case company in Oman. In this study, at first, the qualitative data related to risks in the project were identified through field visits and extensive interviews. These data were then translated into numerical values based on the expert's opinion. Further, the numerical data were used as an input to Monte Carlo simulation. RiskyProject Professional™ software was used to simulate the system based on the identified risks. The simulation result predicted a delay of about 2 years as a worse case with no chance of meeting the project's on stream date. Also, it has predicted 8% chance of exceeding the total estimated budget. The result of numerical analysis from the proposed model is validated by comparing it with the result of qualitative analysis, which was obtained through discussion with various project managers of company.

  9. Deep microbial life in the Altmark natural gas reservoir: baseline characterization prior CO2 injection

    Science.gov (United States)

    Morozova, Daria; Shaheed, Mina; Vieth, Andrea; Krüger, Martin; Kock, Dagmar; Würdemann, Hilke

    2010-05-01

    Within the framework of the CLEAN project (CO2 Largescale Enhanced gas recovery in the Altmark Natural gas field) technical basics with special emphasis on process monitoring are explored by injecting CO2 into a gas reservoir. Our study focuses on the investigation of the in-situ microbial community of the Rotliegend natural gas reservoir in the Altmark, located south of the city Salzwedel, Germany. In order to characterize the microbial life in the extreme habitat we aim to localize and identify microbes including their metabolism influencing the creation and dissolution of minerals. The ability of microorganisms to speed up dissolution and formation of minerals might result in changes of the local permeability and the long-term safety of CO2 storage. However, geology, structure and chemistry of the reservoir rock and the cap rock as well as interaction with saline formation water and natural gases and the injected CO2 affect the microbial community composition and activity. The reservoir located at the depth of about 3500m, is characterised by high salinity fluid and temperatures up to 127° C. It represents an extreme environment for microbial life and therefore the main focus is on hyperthermophilic, halophilic anaerobic microorganisms. In consequence of the injection of large amounts of CO2 in the course of a commercial EGR (Enhanced Gas Recovery) the environmental conditions (e.g. pH, temperature, pressure and solubility of minerals) for the autochthonous microorganisms will change. Genetic profiling of amplified 16S rRNA genes are applied for detecting structural changes in the community by using PCR- SSCP (PCR-Single-Strand-Conformation Polymorphism) and DGGE (Denaturing Gradient Gel Electrophoresis). First results of the baseline survey indicate the presence of microorganisms similar to representatives from other saline, hot, anoxic, deep environments. However, due to the hypersaline and hyperthermophilic reservoir conditions, cell numbers are low, so that

  10. Monitoring of density in tokamaks: pumping and gas injection; Controle de la densite dans les tokamaks: pompage et injection de matiere

    Energy Technology Data Exchange (ETDEWEB)

    Dejarnac, R

    2002-11-01

    In thermonuclear fusion devices, controlling the Deuterium-Tritium fuel density and exhausting the Helium ashes is a crucial point. This is achieved by fuelling the discharges by different methods (gas puffing and pellet injection are the most commonly used) and by implementing pumping devices at the plasma periphery. These two issues are treated in this work, both from an experimental and a modelling point of view, using the neutral transport code EIRENE as main tool for our studies. As far as pumping is concerned, we have modelled the outboard pump limiter of the Tore Supra tokamak with the EIRENE code to which we coupled a plasma module specially developed to simulate the neutrals and the plasma in a coherent way. This allowed to validate the code against experimental data. As far as plasma fuelling is concerned, we present here an original method: the supersonic pulsed gas injection (SPGI). This intermediate method between conventional gas puff (GP) and pellet injection was designed and tested at Tore Supra. It consists of injecting very dense and short gas puffs at high speed into the plasma. Experimentally, SPGI was found to have a better fuelling efficiency than GP and to lead to a strong plasma cooling. The mechanisms responsible for this improved efficiency are analysed by modelling, using the EIRENE code to determine the ionisation source and a 1 D transport model to reproduce the plasma density response. At last, an extrapolation of the present injector is presented, discussing the possibility to obtain a radial drift of the injected matter as observed in the case of high field side pellet injection. (author)

  11. Effect of gas injection during LH wave coupling at ITER-relevant plasma–wall distances in JET

    Czech Academy of Sciences Publication Activity Database

    Ekedahl, A.; Rantamäki, K.; Goniche, M.; Mailloux, J.; Petržílka, Václav; Alper, B.; Baranov, Y.; Basiuk, V.; Beaumont, P.; Corrigan, G.; Delpech, L.; Erents, K.; Granucci, G.; Hawkes, N.; Hobirk, J.; Imbeaux, F.; Joffrin, E.; Kirov, K.; Loarer, T.; McDonald, D.; Nave, M.F.F.; Nunes, I.; Ongena, J.; Parail, V.; Piccolo, F.; Rachlew, E.; Silva, C.; Sirinelli, A.; Stamp, M.; Zastrow, K.D.; JET EFDA, Contributors.

    2009-01-01

    Roč. 51, č. 4 (2009), 044001-17 ISSN 0741-3335 R&D Projects: GA MŠk LA08048; GA ČR GA202/07/0044 Institutional research plan: CEZ:AV0Z20430508 Keywords : gas injection * LH wave * plasma Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.409, year: 2009

  12. Improved enrichment culture technique for methane-oxidizing bacteria from marine ecosystems: the effect of adhesion material and gas composition.

    Science.gov (United States)

    Vekeman, Bram; Dumolin, Charles; De Vos, Paul; Heylen, Kim

    2017-02-01

    Cultivation of microbial representatives of specific functional guilds from environmental samples depends largely on the suitability of the applied growth conditions. Especially the cultivation of marine methanotrophs has received little attention, resulting in only a limited number of ex situ cultures available. In this study we investigated the effect of adhesion material and headspace composition on the methane oxidation activity in methanotrophic enrichments obtained from marine sediment. Addition of sterilized natural sediment or alternatively the addition of acid-washed silicon dioxide significantly increased methane oxidation. This positive effect was attributed to bacterial adhesion on the particles via extracellular compounds, with a minimum amount of particles required for effect. As a result, the particles were immobilized, thus creating a stratified environment in which a limited diffusive gas gradients could build up and various microniches were formed. Such diffusive gas gradient might necessitate high headspace concentrations of CH 4 and CO 2 for sufficient concentrations to reach the methane-oxidizing bacteria in the enrichment culture technique. Therefore, high concentrations of methane and carbon dioxide, in addition to the addition of adhesion material, were tested and indeed further stimulated methane oxidation. Use of adhesion material in combination with high concentrations of methane and carbon dioxide might thus facilitate the cultivation and subsequent enrichment of environmentally important members of this functional guild. The exact mechanism of the observed positive effects on methane oxidation and the differential effect on methanotrophic diversity still needs to be explored.

  13. X-ray phase contrast with injected gas for tumor microangiography

    International Nuclear Information System (INIS)

    Lundström, U; Larsson, D H; Burvall, A; Hertz, H M; Westermark, U K; Henriksson, M Arsenian

    2014-01-01

    We show that the microvasculature of mouse tumors can be visualized using propagation-based phase-contrast x-ray imaging with gas as the contrast agent. The large density difference over the gas–tissue interface provides high contrast, allowing the imaging of small-diameter blood vessels with relatively short exposure times and low dose using a compact liquid-metal-jet x-ray source. The method investigated is applied to tumors (E1A/Ras-transformed mouse embryonic fibroblasts) grown in mouse ears, demonstrating sub-15-µm-diameter imaging of their blood vessels. The exposure time for a 2D projection image is a few seconds and a full tomographic 3D map takes some minutes. The method relies on the strength of the vasculature to withstand the gas pressure. Given that tumor vessels are known to be more fragile than normal vessels, we investigate the tolerance of the vasculature of 12 tumors to gas injection and find that a majority withstand 200 mbar pressures, enough to fill 12-µm-diameter vessels with gas. A comparison of the elasticity of tumorous and non-tumorous vessels supports the assumption of tumor vessels being more fragile. Finally, we conclude that the method has the potential to be extended to the imaging of 15 µm vessels in thick tissue, including mouse imaging, making it of interest for, e.g., angiogenesis research. (paper)

  14. Analyte enrichment and matrix removal in flow injection analysis-inductively coupled plasma-atomic emission spectrometry: determination of phosphorus in steels

    Science.gov (United States)

    McLeod, C. W.; Cook, I. G.; Worsfold, P. J.; Davies, J. E.; Queay, J.

    A flow injection analysis (FIA) system incorporating a microcolumn of activated alumina has been devised for performing rapid analyte enrichment/matrix removal in inductively coupled plasma-atomic emission spectrometry (ICP-AES). The activated alumina has a high affinity for phosphate ions and the FIA system was tested for the determination of trace P in synthetic aqueous solutions utilizing the PI 213.62 nm line. Phosphate deposition and elution were dependent on sample acidity, column length and the nature and concentration of eluent. Linear calibration was established over the range 0-50 μgP ml -1 and the relative standard deviation was 1.6% at 20 μgP ml -1. The limit of detection was 0.6 μgP ml -1 without analyte enrichment. Application to the analysis of a standard steel (BCS 408) was demonstrated.

  15. Metal enrichment of the neutral gas of blue compact dwarf galaxies: the compelling case of Pox 36

    Science.gov (United States)

    Lebouteiller, V.; Kunth, D.; Thuan, T. X.; Désert, J. M.

    2009-02-01

    implies that most of the metals released by consecutive star-formation episodes mixes with the H i gas. The volume extent of the enrichment is so large that the metallicity of the neutral gas increases only slightly. The star-forming regions could be enriched only by a small fraction (~1%), but it would greatly enhance its metallicity. Our results are compared to those of other BCDs. We confirm the overall underabundance of metals in their neutral gas, with perhaps only the lowest metallicity BCDs showing no discontinuity.

  16. Nuclear material safeguards for enrichment plants: Part 4, Gas Centrifuge Enrichment Plant: Diversion scenarios and IAEA safeguards activities: Safeguards training course

    International Nuclear Information System (INIS)

    1987-10-01

    This 5-day training course on nuclear material safeguards for uranium enrichment plants has been developed to train IAEA professionals who are responsible for safeguarding uranium enrichment facilties on the safeguards relevant principles of enrichment technology, particularly as related to centrifuge enrichment plants. This volume contains discussions of diversions of declared material at a centrifuge plant, centrifuge facility material balance verification activities, enriching beyond declared levels in a centrifuge facility, safeguards inspection techniques that may be used inside cascade areas, and demonstration of the enrichment verification measurement technique for cascade header pipes

  17. Characterization of Swirl-Venturi Lean Direct Injection Designs for Aviation Gas-Turbine Combustion

    Science.gov (United States)

    Heath, Christopher M.

    2013-01-01

    Injector geometry, physical mixing, chemical processes, and engine cycle conditions together govern performance, operability and emission characteristics of aviation gas-turbine combustion systems. The present investigation explores swirl-venturi lean direct injection combustor fundamentals, characterizing the influence of key geometric injector parameters on reacting flow physics and emission production trends. In this computational study, a design space exploration was performed using a parameterized swirl-venturi lean direct injector model. From the parametric geometry, 20 three-element lean direct injection combustor sectors were produced and simulated using steady-state, Reynolds-averaged Navier-Stokes reacting computations. Species concentrations were solved directly using a reduced 18-step reaction mechanism for Jet-A. Turbulence closure was obtained using a nonlinear ?-e model. Results demonstrate sensitivities of the geometric perturbations on axially averaged flow field responses. Output variables include axial velocity, turbulent kinetic energy, static temperature, fuel patternation and minor species mass fractions. Significant trends have been reduced to surrogate model approximations, intended to guide future injector design trade studies and advance aviation gas-turbine combustion research.

  18. Enhancing the use of coals by gas reburning-sorbent injection

    Energy Technology Data Exchange (ETDEWEB)

    1989-09-27

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device.

  19. [Heterochromia of the Iris after t-PA and Gas Injection of Sulfur Fluoride].

    Science.gov (United States)

    Hoffmann, Esther M; Schwenn, Oliver

    2004-01-01

    Are changes in iris colour and retinal pigment epithelium after t-PA and gas injection and subsequent vitreous haemorrhage caused by blood cells, or is this a toxic effect? A 81-year old female presented for vitrectomy with a persistent vitreous haemorrhage two months after t-PA and gas injection because of subretinal macular haemorrhage. Sonographic control revealed attached retina. The examination disclosed a new heterochromia of the iris with a change from blue to green-brown. A discrete anterior chamber flare and blood cells were found. Subsequent vitrectomy revealed a thick, rubber-like haemorrhage in the vitreous with suspect pigmentation. A change in retinal pigmentation was also evident. The cause for the heterochromia and the change in pigmentation of the retinal pigment epithelium remained unclear. It may have been a consequence of the persistent bleeding with iron apposition on the iris. A toxic effect of t-PA has to be discussed which led to the alteration in pigmentation.

  20. Mineral storage of CO2/H2S gas mixture injection in basaltic rocks

    Science.gov (United States)

    Clark, D. E.; Gunnarsson, I.; Aradottir, E. S.; Oelkers, E. H.; Sigfússon, B.; Snæbjörnsdottír, S. Ó.; Matter, J. M.; Stute, M.; Júlíusson, B. M.; Gíslason, S. R.

    2017-12-01

    Carbon capture and storage is one solution to reducing CO2 emissions in the atmosphere. The long-term geological storage of buoyant supercritical CO2 requires high integrity cap rock. Some of the risk associated with CO2 buoyancy can be overcome by dissolving CO2 into water during its injection, thus eliminating its buoyancy. This enables injection into fractured rocks, such as basaltic rocks along oceanic ridges and on continents. Basaltic rocks are rich in divalent cations, Ca2+, Mg2+ and Fe2+, which react with CO2 dissolved in water to form stable carbonate minerals. This possibility has been successfully tested as a part of the CarbFix CO2storage pilot project at the Hellisheiði geothermal power plant in Iceland, where they have shown mineralization occurs in less than two years [1, 2]. Reykjavik Energy and the CarbFix group has been injecting a mixture of CO2 and H2S at 750 m depth and 240-250°C since June 2014; by 1 January 2016, 6290 tons of CO2 and 3530 tons of H2S had been injected. Once in the geothermal reservoir, the heat exchange and sufficient dissolution of the host rock neutralizes the gas-charged water and saturates the formation water respecting carbonate and sulfur minerals. A thermally stable inert tracer was also mixed into the stream to monitor the subsurface transport and to assess the degree of subsurface carbonation and sulfide precipitation [3]. Water and gas samples have been continuously collected from three monitoring wells and geochemically analyzed. Based on the results, mineral saturation stages have been defined. These results and tracer mass balance calculations are used to evaluate the rate and magnitude of CO2 and H2S mineralization in the subsurface, with indications that mineralization of carbon and sulfur occurs within months. [1] Gunnsarsson, I., et al. (2017). Rapid and cost-effective capture and subsurface mineral storage of carbon and sulfur. Manuscript submitted for publication. [2] Matter, J., et al. (2016). Rapid

  1. Self-sealing experiments and gas injection tests in a backfilled micro-tunnel of the Mont Terri URL

    International Nuclear Information System (INIS)

    Lanyon, Bill; Marschall, Paul; Trick, Thomas; Vaissiere, Remi de La; Shao, Hua; Leung, Helen

    2012-01-01

    Document available in extended abstract form only. The investigation of damage zones around excavations such as seal sections in tunnels or shafts and their impact on gas migration are key issues in the field of underground waste disposal. The experiment ('Gas path through host rock and along seal sections / HG-A') was designed as a long-term gas experiment in a backfilled micro-tunnel, to investigate both leak-off rates and gas release paths from a sealed tunnel section in an ultra-low permeability host rock (Opalinus Clay). The aims of the HG-A experiment are to: - Provide evidence for barrier function of the Opalinus Clay on the tunnel scale (scale effects in rock permeability); - Investigate self-sealing of the EDZ after tunnel closure (mechanical self-sealing in response to packer inflation and pore pressure changes); - Provide evidence for gas transport capacity of Opalinus Clay (intact host rock and EDZ). The HG-A experiment is located in the southern part of the Mont Terri Rock Laboratory off Gallery 04. A 13 m long, 1 m diameter micro-tunnel was excavated in February 2005. Hydraulic and mechanical response to excavation was monitored in an array of boreholes HG-A2 to HG-A7. This was subsequently extended with additional piezometers and remote sensing boreholes (HG-A8-14, HGA24, A25). In summer 2006 a Mega-packer was emplaced to create a tunnel seal isolating the test section (see Figure 1). The test and seal sections were instrumented with piezometers, strain gauges, total pressure cells and Time Domain Reflectometers (TDRs). The response to excavation of the micro-tunnel and the associated creation and development of the Excavation Damage Zone (EDZ) is discussed in Marschall et al. (2006, 2008). The test section saturation and hydraulic testing prior to gas injection is presented in Lanyon et al. (2009). This paper presents the results of gas leak-off testing, subsequent post-gas hydraulic testing together with an overview of the rock's response to

  2. Response of potato gas exchange and productivity to phosphorus deficiency and CO2 enrichment

    Science.gov (United States)

    The degree to which crops respond to atmospheric carbon dioxide enrichment (CO2) may be influenced by their nutrition level. While the majority of CO2 and plant nutrition studies focus on nitrogen, phosphorus (P) is also required in relatively high amounts for important crops such as potato. To de...

  3. Integration of biohydrogen fermentation and gas separation processes to recover and enrich hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Belafi-Bako, K.; Bucsu, D. [Research Institute of Chemical and Process Engineering, University of Veszprem, Egyetem u. 2., 8200 Veszprem (Hungary); Pientka, Z. [Institute of Macromolecular Chemistry, Czech Academy of Sciences, Heyrovsky sq. 2., Prague (Czech Republic); Balint, B.; Herbel, Z.; Kovacs, K.L. [Department of Biotechnology and Institute of Biophysics, Biological Research Center, Hungarian Academy of Sciences, University of Szeged, Temesvari krt. 62., 6726 Szeged (Hungary); Wessling, M. [Membrane Technology Group, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)

    2006-09-15

    An integrated system for biohydrogen production and separation was designed, constructed and operated where biohydrogen was fermented by Thermococcus litoralis, a heterotrophic archaebacterium, and a two-step gas separation process was coupled to recover and concentrate hydrogen. A special liquid seal system was built to deliver, compress and collect the laboratory scale, low volume gas mixtures consisting of hydrogen, nitrogen and carbon dioxide. As a result, gas mixture with 73% high hydrogen content was produced by a combination of a porous and a non-porous gas separation membrane. (author)

  4. Mechanisms of disruptions caused by noble gas injection into tokamak plasmas

    International Nuclear Information System (INIS)

    Morozov, D.Kh.; Yurchenko, E.I.; Lukash, V.E.; Baronova, E.O.; Pozdnyakov, Yu.I.; Rozhansky, V.A.; Senichenkov, I.Yu.; Veselova, I.Yu.; Schneider, R.

    2005-01-01

    Noble gas injection for disruption mitigation in DIII-D is simulated. The simulation of the first two stages of the disruption is performed: the first one is the neutral gas jet penetration through the background plasmas, and the second one is the instability growth. In order to simulate the first stage, the MHD pellet code LLP with improved radiation model for noble gas is used. Plasma cooling at this stage is provided by the energy exchange with the jet. The opacity effects in radiation losses are found to be important in the energy balance calculations. The magnetic surfaces in contact with the jet are cooled significantly; however, the temperature as well as the electric conductivity, remains high. The cooling front propagates towards the plasma centre. It has been shown that the cooling front is accompanied by strongly localized 'shark fin-like' perturbation in toroidal current density profile. The simplified cylindrical model shows that the cooling front is able to produce the internal kink-like mode with growth rate significantly higher than the tearing mode. The unstable kink perturbation obtained is non-resonant for any magnetic surface, both inside the plasma column, and in the vacuum space outside the separatrix. The mode disturbs mainly the core region. The growth time of the 'shark fin-like' mode is higher than the Alfven time by a factor of 10-100 for DIII-D parameters

  5. THE COMPLEXITY THAT THE FIRST STARS BROUGHT TO THE UNIVERSE: FRAGILITY OF METAL-ENRICHED GAS IN A RADIATION FIELD

    International Nuclear Information System (INIS)

    Aykutalp, A.; Spaans, M.

    2011-01-01

    The initial mass function (IMF) of the first (Population III) stars and Population II (Pop II) stars is poorly known due to a lack of observations of the period between recombination and reionization. In simulations of the formation of the first stars, it has been shown that, due to the limited ability of metal-free primordial gas to cool, the IMF of the first stars is a few orders of magnitude more massive than the current IMF. The transition from a high-mass IMF of the first stars to a lower-mass current IMF is thus important to understand. To study the underlying physics of this transition, we performed several simulations using the cosmological hydrodynamic adaptive mesh refinement code Enzo for metallicities of 10 -4 , 10 -3 , 10 -2 , and 10 -1 Z sun . In our simulations, we include a star formation prescription that is derived from a metallicity-dependent multi-phase interstellar medium (ISM) structure, an external UV radiation field, and a mechanical feedback algorithm. We also implement cosmic ray heating, photoelectric heating, and gas-dust heating/cooling, and follow the metal enrichment of the ISM. It is found that the interplay between metallicity and UV radiation leads to the coexistence of Pop III and Pop II star formation in non-zero-metallicity (Z/Z sun ≥ 10 -2 ) gas. A cold (T 10 -22 g cm -3 ) gas phase is fragile to ambient UV radiation. In a metal-poor (Z/Z sun ≤ 10 -3 ) gas, the cold and dense gas phase does not form in the presence of a radiation field of F 0 ∼ 10 -5 -10 -4 erg cm -2 s -1 . Therefore, metallicity by itself is not a good indicator of the Pop III-Pop II transition. Metal-rich (Z/Z sun ≥ 10 -2 ) gas dynamically evolves two to three orders of magnitude faster than metal-poor gas (Z/Z sun ≤ 10 -3 ). The simulations including supernova explosions show that pre-enrichment of the halo does not affect the mixing of metals.

  6. Dual-fuelling of a direct-injection automotive diesel engine by diesel and compressed natural gas

    International Nuclear Information System (INIS)

    Pirouzpanah, V.; Mohammadi Kosha, A.; Mosseibi, A.; Moshirabadi, J.; Gangi, A.; Moghadaspour, M.

    2000-01-01

    Application of Compressed Natural Gas in diesel engines has always been important, especially in the field of automotive engineering. This is due to easy accessibility, better mixing quality and good combustion characteristics of the Compressed Natural Gas fuel. In this study the application of Compressed Natural Gas fuel along with diesel oil in a heavy duty direct-injection automotive diesel engine is experimentally investigated. In order to convert a diesel engine into a diesel-gas one, the so called m ixed diesel-gas a pproach has been used and for this purpose a carbureted Compressed Natural Gas fuel system has been designed and manufactured. For controlling quantity of Compressed Natural Gas, the gas valve is linked to the diesel fuel injection system by means of a set of rods. Then, the dual-fuel system is adjusted so that, at full load conditions, the quantity of diesel fuel is reduced to 20% and 80% of its equivalent energy is substituted by Compressed Natural Gas fuel. Also injection pressure of pilot jet is increased by 11.4%. Performance and emission tests are conducted under variation of load and speed on both diesel and diesel-gas engines. Results show that, with equal power and torque, the diesel-gas engine has the potential to improve overall engine performance and emission. For example, at rated power and speed, fuel economy increases by 5.48%, the amount of smoke decreases by 78%, amount of CO decreases by 64.3% and mean exhaust gas temperature decreases by 6.4%

  7. Enriched-uranium feed costs for the High-Temperature Gas-Cooled reactor: trends and comparison with other reactor concepts

    International Nuclear Information System (INIS)

    Thomas, W.E.

    1976-04-01

    This report discusses each of the components that affect the unit cost for enriched uranium; that is, ore costs, U 3 O 8 to UF 6 conversion cost, costs for enriching services, and changes in transaction tails assay. Historical trends and announced changes are included. Unit costs for highly enriched uranium (93.15 percent 235 U) and for low-enrichment uranium (3.0, 3.2, and 3.5 percent 235 U) are displayed as a function of changes in the above components and compared. It is demonstrated that the trends in these cost components will probably result in significantly less cost increase for highly enriched uranium than for low-enrichment uranium--hence favoring the High-Temperature Gas-Cooled Reactor

  8. Prediction of Gas Injection Effect on Asphaltene Precipitation Onset Using the Cubic and Cubic-Plus-Association Equations of State

    DEFF Research Database (Denmark)

    Arya, Alay; Liang, Xiaodong; von Solms, Nicolas

    2017-01-01

    Gas injection is a proven enhanced oil recovery technique. The gas injection changes the reservoir oil composition, temperature, and pressure conditions, which may result in asphaltene precipitation. In this work, we have used a modeling approach from the literature in order to predict asphaltene...... precipitation onset condition during gas injection. The modeling approach is used with the Soave Redlich Kwong, Soave Redlich Kwong-Plus-Huron Vidal mixing rule and cubic-plus-association (CPA) equations of state (EoS). Six different reservoir fluids are studied with respect to asphaltene onset precipitation...... on asphaltene onset conditions. The CPA EoS is more reliable than the other two models, which are sensitive to asphaltene molecular weight and sometimes predict highly nonlinear behavior outside the experimental temperature range used for fitting the model parameters....

  9. Explosive injection of gas-particle dispersions into a non-fluidized granular host: volcanological implications

    Science.gov (United States)

    Ross, P.; White, J. D.; Zimanowski, B.; Buettner, R.

    2006-12-01

    Discrete explosive bursts, or explosions, are known from many volcanic eruptions. In maar-diatreme eruptions, they have occurred in debris-filled volcanic vents when magma interacted with groundwater, implying that material mobilized by such explosions passed through the overlying and enclosing debris to reach the surface. Although other studies have addressed the form and characteristics of craters formed by discrete explosions in unconsolidated material, no details are available regarding the structure of the disturbed debris between the explosion site and the crater floor. Field studies of diatreme deposits reveal cross-cutting, steep- sided zones of non-bedded volcaniclastic material that have been inferred to result from "debris jets" driven by explosions. In order to determine the general processes and deposit geometry resulting from discrete, explosive injections of entrained particles through a particulate host, we ran a series of analog experiments in which specific volumes of compressed (5-20 MPa) air were released in bursts that drove gas-particle dispersions through a particulate host. The air expanded into and entrained red particles in a small crucible before moving upward into the white beads used for the host. Injected particles and the overlying host material were glass beads of identical size, shape and density. The experiments revealed that each burst drove into the host an expanding cavity containing air and colored particles, which rapidly collapsed as the driving gas escaped through the permeable roof. Total duration of each run, recorded with high-speed video, was approximately 0.5-1 second. As gas slowed and escaped the cavity the colored beads sedimented into the transient cavity, which was also closing laterally because of inward-directed granular flow of the host. This same behavior was observed even in runs where there was no explosive breaching of the surface, and no colored beads ejected. A columnar body of colored beads was left that

  10. HIGH RESOLUTION PREDICTION OF GAS INJECTION PROCESS PERFORMANCE FOR HETEROGENEOUS RESERVOIRS

    Energy Technology Data Exchange (ETDEWEB)

    Franklin M. Orr, Jr.

    2002-06-30

    This report outlines progress in the third quarter of the second year of the DOE project ''High Resolution Prediction of Gas Injection Process Performance for Heterogeneous Reservoirs''. High order finite difference schemes for one-dimensional, two-phase, multicomponent displacements are investigated. Numerical tests are run using a three component fluid description for a case when the interaction between phase behavior and flow is strong. Some currently used total variation diminishing (TVD) methods produce unstable results. A third order essentially non-oscillatory (ENO) method captures the effects of phase behavior for this test case. Possible modifications to ensure stability are discussed along with plans to incorporate higher order schemes into the 3DSL streamline simulator.

  11. Morphological Investigation of Foamed Aluminum Parts Produced by Melt Gas Injection

    Directory of Open Access Journals (Sweden)

    R. Surace

    2009-01-01

    Full Text Available Porous metal materials are a new class of materials with low densities, large specific surface, and novel physical and mechanical properties. Their applications are extremely varied: for light weight structural components, for filters and electrodes, and for shock or sound absorbing products. Recently, interesting foaming technology developments have proposed metallic foams as a valid commercial chance; foam manufacturing techniques include solid, liquid, or vapor state methods. The foams presented in this study are produced by Melt Gas Injection (MGI process starting from melt aluminum. The aim of this investigation is to obtain complex foamed aluminum parts in order to make the MGI more flexible. This new method, called MGI-mould process, makes possible to produce 3D-shaped parts with complicated shape or configuration using some moulds obtained by traditional investment casting process.

  12. Staged fuel and air injection in combustion systems of gas turbines

    Energy Technology Data Exchange (ETDEWEB)

    Hughes, Michael John; Berry, Jonathan Dwight

    2018-04-10

    A gas turbine including a working fluid flowpath extending aftward from a forward injector in a combustor. The combustor may include an inner radial wall, an outer radial wall, and, therebetween, a flow annulus, and a third radial wall formed about the outer radial wall that forms an outer flow annulus. A staged injector may intersect the flow annulus so to attain an injection point within the working fluid flowpath by which aftward and forward annulus sections are defined. Air directing structure may include an aftward intake section corresponding to the aftward annulus section and a forward intake section corresponding to the forward annulus section. The air directing structure may include a switchback coolant flowpath to direct air from the compressor discharge cavity to the staged injector. The switchback coolant flowpath may include an upstream section through the flow annulus, and a downstream section through the outer flow annulus.

  13. Effect of diesel pre-injection timing on combustion and emission characteristics of compression ignited natural gas engine

    International Nuclear Information System (INIS)

    Xu, Min; Cheng, Wei; Zhang, Hongfei; An, Tao; Zhang, Shaohua

    2016-01-01

    Highlights: • Pre-injection timing on combustion and emission of CING engine are studied. • Closely pre-injection operations leads to increase of combustion intensity. • Early pre-injection operations leads to lower combustion intensity. • Early pre-injection modes provide better NO x emission. - Abstract: Pre-injection strategy is considered to be one of the most important ways to improve diesel engine performance, emission and combustion. It is the same important factor in pilot diesel compression ignition natural gas (CING) engine. In this study, effects of pre-injection timing on combustion and emission performances were experimentally studied in a CING engine which was modified from a turbocharged six-cylinder diesel engine. The experiments were conducted at constant speed of 1400 rpm and different engine loads with a constant fuel injection pressure of 1100 bar. Main injection timing was fixed at 10 °CA BTDC in the advance process of pre-injection timing. The cylinder pressure, heart release rate (HRR), pressure rise rate (PRR), start of combustion (SOC) and coefficient of variation (COV IMEP ), as well as NO x , HC and CO emissions were analyzed. The results indicated that closely pre-injection operations lead to the advance of SOC which intensified combustion of in-cylinder mixture, thereby resulting in higher cylinder pressure, HRR and PRR, as well higher NO x emissions and lower HC and CO emissions. However, early pre-injection operations lead to lower cylinder pressure, HRR and PRR due to decreasing in combustion intensity. Pre-injection timing of 70 °CA BTDC is a conversion point in which influence of pre-injection fuel on ignition and combustion of natural gas nearly disappeared and lowest NO x emission could be obtained. Compared with single injection ignition mode, NO x emissions at the conversion point were reduced by 33%, 38% and 7% at engine load of 38%, 60% and 80% respectively. This is important for the conditions that ignition fuel

  14. Low Emission Hydrogen Combustors for Gas Turbines Using Lean Direct Injection

    Science.gov (United States)

    Marek, C. John; Smith, Timothy D.; Kundu, Krishna

    2005-01-01

    One of the key technology challenges for the use of hydrogen in gas turbine engines is the performance of the combustion system, in particular the fuel injectors. To investigate the combustion performance of gaseous hydrogen fuel injectors flame tube combustor experiments were performed. Tests were conducted to measure the nitrogen oxide (NOx) emissions and combustion performance at inlet conditions of 600 to 1000 deg F, 60 to 200 pounds per square inch absolute (psia), and equivalence ratios up to 0.48. All the injectors were based on Lean Direct Injection (LDI) technology with multiple injection points and quick mixing. One challenge to hydrogen based premixing combustion systems is flashback since hydrogen has a reaction rate over seven times that of Jet-A. To reduce the risk, design mixing times were kept short and velocities high to minimize flashback. Five fuel injector designs were tested in 2.5 and 3.5-in. diameter flame tubes with non-vitiated heated air and gaseous hydrogen. Data is presented on measurements of NOx emissions and combustion efficiency for the hydrogen injectors at 1.0, 3.125, and 5.375 in. from the injector face. Results show that for some configurations, NOx emissions are comparable to that of state of the art Jet-A LDI combustor concepts.

  15. Low-Emission Hydrogen Combustors for Gas Turbines Using Lean Direct Injection

    Science.gov (United States)

    Marek, C. John; Smith, Timothy D.; Kundu, Krishna

    2007-01-01

    One of the key technology challenges for the use of hydrogen in gas turbine engines is the performance of the combustion system, in particular the fuel injectors. To investigate the combustion performance of gaseous hydrogen fuel injectors flame tube combustor experiments were performed. Tests were conducted to measure the nitrogen oxide (NO(x)) emissions and combustion performance at inlet conditions of 588 to 811 K, 0.4 to 1.4 MPa, and equivalence ratios up to 0.48. All the injectors were based on Lean Direct Injection (LDI) technology with multiple injection points and quick mixing. One challenge to hydrogen-based premixing combustion systems is flashback since hydrogen has a reaction rate over 7 times that of Jet-A. To reduce the risk, design mixing times were kept short and velocities high to minimize flashback. Five fuel injector designs were tested in 6.35- and 8.9-cm-diameter flame tubes with non-vitiated heated air and gaseous hydrogen. Data is presented on measurements of NO(x) emissions and combustion efficiency for the hydrogen injectors at 2.540, 7.937, and 13.652 cm from the injector face. Results show that for some configurations, NO(x) emissions are comparable to that of state of the art Jet-A LDI combustor concepts.

  16. Experimental Combustion Dynamics Behavior of a Multi-Element Lean Direct Injection (LDI) Gas Turbine Combustor

    Science.gov (United States)

    Acosta, Waldo A.; Chang, Clarence T.

    2016-01-01

    An experimental investigation of the combustion dynamic characteristics of a research multi-element lean direct injection (LDI) combustor under simulated gas turbine conditions was conducted. The objective was to gain a better understanding of the physical phenomena inside a pressurized flametube combustion chamber under acoustically isolated conditions. A nine-point swirl venturi lean direct injection (SV-LDI) geometry was evaluated at inlet pressures up to 2,413 kPa and non-vitiated air temperatures up to 867 K. The equivalence ratio was varied to obtain adiabatic flame temperatures between 1388 K and 1905 K. Dynamic pressure measurements were taken upstream of the SV-LDI, in the combustion zone and downstream of the exit nozzle. The measurements showed that combustion dynamics were fairly small when the fuel was distributed uniformly and mostly due to fluid dynamics effects. Dynamic pressure fluctuations larger than 40 kPa at low frequencies were measured at 653 K inlet temperature and 1117 kPa inlet pressure when fuel was shifted and the pilot fuel injector equivalence ratio was increased to 0.72.

  17. Radiative response on massive noble gas injection for Runaway suppression in disruptive plasmas

    International Nuclear Information System (INIS)

    Reiter, Bernhard

    2010-01-01

    The most direct way to avoid the formation of a relativistic electron beam under the influence of an electric field in a highly conducting plasma, is to increase the electron density to a value, where the retarding collisional force balances the accelerating one. In a disruptive tokamak plasma, rapid cooling induces a high electric field, which could easily violate the force balance and push electrons into the relativistic regime. Such relativistic electrons, the so-called runaways, accumulate many MeV's and can cause substantial damage when they hit the wall. This thesis is based on the principle of rapidly fueling the plasma for holding the force balance even under the influence of high electric fields typical for disruptions. The method of injecting high amounts of noble gas particles into the plasma from a close distance is put into practice in the ASDEX Upgrade fusion test facility. In the framework of this thesis, a multi-channel photometer system based on 144 AXUV detectors in a toroidal stereo measurement setup was built. It kept its promise to provide new insights into the transport mechanisms in a disruptive plasma under the influence of strong radiative interaction dynamics between injected matter and the hot plasma.

  18. plasma modes behaviors and electron injection influence in an audio-ultrasonic air gas discharge

    International Nuclear Information System (INIS)

    Ragheb, M.S.; Haleem, N.A.

    2010-01-01

    the main purpose of this study is to investigate the favorable conditions for the production of plasma particle acceleration in an audio-ultrasonic air gas discharge of 20 cm long and 34 mm diameter.it is found that according to the applied conditions the formed plasma changes its behavior and overtakes diverse modes of different characteristics. the pressure, the voltage, and the frequency applied to the plasma determine its proper state. both experimental data collection and optical observations are introduced to clarify and to put in evidence the present plasma facts. the distribution of the electrons density along the plasma tube draws in average the electric field distribution of the ionization waves. in addition, the plasma is studied with and without electrons injection in order to investigate its influence . it is found that the electron injection decreases the plasma intensity and the plasma temperature, while it increases the discharge current. in turn, the decrease of the plasma temperature decreases the plasma oscillations and enhances the plasma instability. on the other hand,the enhancement of the plasma instability performs good conditions for electron acceleration. as a result, the qualified mode for particles acceleration is attained and its conditions are retrieved and defined for that purpose.

  19. Assessment of Factors Influencing Effective CO2 Storage Capacity and Injectivity in Eastern Gas Shales

    Energy Technology Data Exchange (ETDEWEB)

    Godec, Michael [Advanced Resources International, Inc., Arlington, VA (United States)

    2013-06-30

    Building upon advances in technology, production of natural gas from organic-rich shales is rapidly developing as a major hydrocarbon supply option in North America and around the world. The same technology advances that have facilitated this revolution - dense well spacing, horizontal drilling, and hydraulic fracturing - may help to facilitate enhanced gas recovery (EGR) and carbon dioxide (CO2) storage in these formations. The potential storage of CO2 in shales is attracting increasing interest, especially in Appalachian Basin states that have extensive shale deposits, but limited CO2 storage capacity in conventional reservoirs. The goal of this cooperative research project was to build upon previous and on-going work to assess key factors that could influence effective EGR, CO2 storage capacity, and injectivity in selected Eastern gas shales, including the Devonian Marcellus Shale, the Devonian Ohio Shale, the Ordovician Utica and Point Pleasant shale and equivalent formations, and the late Devonian-age Antrim Shale. The project had the following objectives: (1) Analyze and synthesize geologic information and reservoir data through collaboration with selected State geological surveys, universities, and oil and gas operators; (2) improve reservoir models to perform reservoir simulations to better understand the shale characteristics that impact EGR, storage capacity and CO2 injectivity in the targeted shales; (3) Analyze results of a targeted, highly monitored, small-scale CO2 injection test and incorporate into ongoing characterization and simulation work; (4) Test and model a smart particle early warning concept that can potentially be used to inject water with uniquely labeled particles before the start of CO2 injection; (5) Identify and evaluate potential constraints to economic CO2 storage in gas shales, and propose development approaches that overcome these constraints

  20. Apparent Km of mitochondria for oxygen computed from Vmax measured in permeabilized muscle fibers is lower in water enriched in oxygen by electrolysis than injection

    Directory of Open Access Journals (Sweden)

    Zoll J

    2015-07-01

    Full Text Available Joffrey Zoll,1 Jamal Bouitbir,1 Pascal Sirvent,2 Alexis Klein,3 Antoine Charton,1,4 Liliana Jimenez,3 François R Péronnet,5 Bernard Geny,1 Ruddy Richard61Physiology Department, Faculty of Medicine and EA3072, Université de Strasbourg, Strasbourg, 2Clermont Université, Université Blaise Pascal, EA 3533, Laboratoire des Adaptations Métaboliques à l’Exercice en Conditions Physiologiques et Pathologiques, Clermont-Ferrand, 3Danone Research, Centre Daniel Carasso, Palaiseau, 4Department of Anesthesia and Critical Care and EA3072, Hôpital de Hautepierre, Université de Strasbourg, France; 5Kinesiology Department, Université de Montréal, Montréal, QC, Canada; 6Department of Sport Medicine and Functional Explorations and INRA UMR 1019, Faculty of Medicine, Université d’Auvergne, Clermont-Ferrand, FranceBackground: It has been suggested that oxygen (O2 diffusion could be favored in water enriched in O2 by a new electrolytic process because of O2 trapping in water superstructures (clathrates, which could reduce the local pressure/content relationships for O2 and facilitate O2 diffusion along PO2 gradients.Materials and methods: Mitochondrial respiration was compared in situ in saponin-skinned fibers isolated from the soleus muscles of Wistar rats, in solution enriched in O2 by injection or the electrolytic process 1 at an O2 concentration decreasing from 240 µmol/L to 10 µmol/L (132 mmHg to 5 mmHg, with glutamate–malate or N, N, N', N'-tetramethyl-p-phenylenediamine dihydrochloride (TMPD–ascorbate (with antimycin A as substrates; and 2 at increasing adenosine diphosphate (ADP concentration with glutamate–malate as substrate.Results: As expected, maximal respiration decreased with O2 concentration and, when compared to glutamate–malate, the apparent Km O2 of mitochondria for O2 was significantly lower with TMPD–ascorbate with both waters. However, when compared to the water enriched in O2 by injection, the Km O2 was

  1. The effects of gas-fluid-rock interactions on CO2 injection and storage: Insights from reactive transport modeling

    Energy Technology Data Exchange (ETDEWEB)

    Xiao, Y.; Xu, T.; Pruess, K.

    2008-10-15

    Possible means of reducing atmospheric CO{sub 2} emissions include injecting CO{sub 2} in petroleum reservoirs for Enhanced Oil Recovery or storing CO{sub 2} in deep saline aquifers. Large-scale injection of CO{sub 2} into subsurface reservoirs would induce a complex interplay of multiphase flow, capillary trapping, dissolution, diffusion, convection, and chemical reactions that may have significant impacts on both short-term injection performance and long-term fate of CO{sub 2} storage. Reactive Transport Modeling is a promising approach that can be used to predict the spatial and temporal evolution of injected CO{sub 2} and associated gas-fluid-rock interactions. This presentation will summarize recent advances in reactive transport modeling of CO{sub 2} storage and review key technical issues on (1) the short- and long-term behavior of injected CO{sub 2} in geological formations; (2) the role of reservoir mineral heterogeneity on injection performance and storage security; (3) the effect of gas mixtures (e.g., H{sub 2}S and SO{sub 2}) on CO{sub 2} storage; and (4) the physical and chemical processes during potential leakage of CO{sub 2} from the primary storage reservoir. Simulation results suggest that CO{sub 2} trapping capacity, rate, and impact on reservoir rocks depend on primary mineral composition and injecting gas mixtures. For example, models predict that the injection of CO{sub 2} alone or co-injection with H{sub 2}S in both sandstone and carbonate reservoirs lead to acidified zones and mineral dissolution adjacent to the injection well, and carbonate precipitation and mineral trapping away from the well. Co-injection of CO{sub 2} with H{sub 2}S and in particular with SO{sub 2} causes greater formation alteration and complex sulfur mineral (alunite, anhydrite, and pyrite) trapping, sometimes at a much faster rate than previously thought. The results from Reactive Transport Modeling provide valuable insights for analyzing and assessing the dynamic

  2. A Model To Estimate Carbon Dioxide Injectivity and Storage Capacity for Geological Sequestration in Shale Gas Wells.

    Science.gov (United States)

    Edwards, Ryan W J; Celia, Michael A; Bandilla, Karl W; Doster, Florian; Kanno, Cynthia M

    2015-08-04

    Recent studies suggest the possibility of CO2 sequestration in depleted shale gas formations, motivated by large storage capacity estimates in these formations. Questions remain regarding the dynamic response and practicality of injection of large amounts of CO2 into shale gas wells. A two-component (CO2 and CH4) model of gas flow in a shale gas formation including adsorption effects provides the basis to investigate the dynamics of CO2 injection. History-matching of gas production data allows for formation parameter estimation. Application to three shale gas-producing regions shows that CO2 can only be injected at low rates into individual wells and that individual well capacity is relatively small, despite significant capacity variation between shale plays. The estimated total capacity of an average Marcellus Shale well in Pennsylvania is 0.5 million metric tonnes (Mt) of CO2, compared with 0.15 Mt in an average Barnett Shale well. Applying the individual well estimates to the total number of existing and permitted planned wells (as of March, 2015) in each play yields a current estimated capacity of 7200-9600 Mt in the Marcellus Shale in Pennsylvania and 2100-3100 Mt in the Barnett Shale.

  3. Performance and stability analysis of gas-injection enhanced natural circulation in heavy-liquid-metal-cooled systems

    Science.gov (United States)

    Yoo, Yeon-Jong

    The purpose of this study is to investigate the performance and stability of the gas-injection enhanced natural circulation in heavy-liquid-metal-cooled systems. The target system is STAR-LM, which is a 400-MWt-class advanced lead-cooled fast reactor under development by Argonne National Laboratory and Oregon State University. The primary loop of STAR-LM relies on natural circulation to eliminate main circulation pumps for enhancement of passive safety. To significantly increase the natural circulation flow rate for the incorporation of potential future power uprates, the injection of noncondensable gas into the coolant above the core is envisioned ("gas lift pump"). Reliance upon gas-injection enhanced natural circulation raises the concern of flow instability due to the relatively high temperature change in the reactor core and the two-phase flow condition in the riser. For this study, the one-dimensional flow field equations were applied to each flow section and the mixture models of two-phase flow, i.e., both the homogeneous and drift-flux equilibrium models were used in the two-phase region of the riser. For the stability analysis, the linear perturbation technique based on the frequency-domain approach was used by employing the Nyquist stability criterion and a numerical root search method. It has been shown that the thermal power of the STAR-LM natural circulation system could be increased from 400 up to 1152 MW with gas injection under the limiting void fraction of 0.30 and limiting coolant velocity of 2.0 m/s from the steady-state performance analysis. As the result of the linear stability analysis, it has turned out that the STAR-LM natural circulation system would be stable even with gas injection. In addition, through the parametric study, it has been found that the thermal inertia effects of solid structures such as fuel rod and heat exchanger tube should be considered in the stability analysis model. The results of this study will be a part of the

  4. Integration of biohydrogen fermentation and gas separation processes to recover and enrich hydrogen

    Czech Academy of Sciences Publication Activity Database

    Bélafi-Bakó, K.; Búcsú, D.; Pientka, Zbyněk; Bálint, B.; Herbel, Z.; Kovács, K. L.; Wessling, M.

    2006-01-01

    Roč. 31, č. 11 (2006), s. 1490-1495 ISSN 0360-3199 R&D Projects: GA ČR GA203/06/1207 Institutional research plan: CEZ:AV0Z40500505 Keywords : integrated system * gas separation * polymer membranes Subject RIV: CD - Macromolecular Chemistry Impact factor: 2.612, year: 2006

  5. Integration of biohydrogen fermentation and gas separation processes to recover and enrich hydrogen

    NARCIS (Netherlands)

    Bélafi-Bakó, K.; Búcsú, D.; Pientka, Z.; Bálint, B.; Herbel, Z.; Kovács, K.I.; Wessling, Matthias

    2006-01-01

    An integrated system for biohydrogen production and separation was designed, constructed and operated where biohydrogen was fermented by Thermococcus litoralis, a heterotrophic archaebacterium, and a two-step gas separation process was coupled to recover and concentrate hydrogen. A special liquid

  6. Interfacial Tension and Contact Angle Determination in Water-sandstone Systems with Injection of Flue Gas and CO2

    NARCIS (Netherlands)

    Shojaikaveh, N.; Rudolph, E.S.J.; Rossen, W.R.; Van Hemert, P.; Wolf, K.H.A.A.

    2013-01-01

    Carbon capture and storage (CCS) has the potential for reducing CO2 emissions to the atmosphere. This option includes storage strategies such as CO2 injection into deep saline aquifers, depleted oil and gas reservoirs, and unmineable coal seams. This process is largely controlled by the interactions

  7. Prediction of Gas Injection Effect on Asphaltene Precipitation Onset Using the Cubic and Cubic-Plus-Association Equations of State

    DEFF Research Database (Denmark)

    Arya, Alay; Liang, Xiaodong; von Solms, Nicolas

    2017-01-01

    precipitation onset condition during gas injection. The modeling approach is used with the Soave Redlich Kwong, Soave Redlich Kwong-Plus-Huron Vidal mixing rule and cubic-plus-association (CPA) equations of state (EoS). Six different reservoir fluids are studied with respect to asphaltene onset precipitation...

  8. Investigation of the Gas Injection Effect on Asphaltene Onset Precipitation Using the Cubic-Plus-Association Equation of State

    DEFF Research Database (Denmark)

    Arya, Alay; von Solms, Nicolas; Kontogeorgis, Georgios M.

    2016-01-01

    problem. Therefore, it is imperative to investigate beforehand the effect of gas injection into the reservoir from the modeling results. The cubic-plus-association (CPA) equation of state (EoS) has previously been applied to model the asphaltene onset precipitation condition. In this work, we adopt...

  9. Estimate for interstage water injection in air compressor incorporated into gas-turbine cycles and combined power plants cycles

    Science.gov (United States)

    Kler, A. M.; Zakharov, Yu. B.; Potanina, Yu. M.

    2017-05-01

    The objects of study are the gas turbine (GT) plant and combined cycle power plant (CCPP) with opportunity for injection between the stages of air compressor. The objective of this paper is technical and economy optimization calculations for these classes of plants with water interstage injection. The integrated development environment "System of machine building program" was a tool for creating the mathematic models for these classes of power plants. Optimization calculations with the criterion of minimum for specific capital investment as a function of the unit efficiency have been carried out. For a gas-turbine plant, the economic gain from water injection exists for entire range of power efficiency. For the combined cycle plant, the economic benefit was observed only for a certain range of plant's power efficiency.

  10. Study of the influence of gas flow on PECVD diamond growth: influence of the separate injection of gases

    Science.gov (United States)

    Mesbahi, A.; Silva, F.

    2017-11-01

    This study is a follow-up to previously published modeling work examining a bell jar microwave plasma CVD reactor operating at high pressure (Mesbahi et al 2013 J. Phys. D: Appl. Phys. 46 385502). In this paper, we present the influence of gas injection mode on flow structure, on the production and coupled transport of diamond growth key species, and on the resulting diamond growth. Several gas injection configurations have been tested and experimental results in terms of growth rate and thickness uniformity will be compared with numerical simulations. In this study, we found that direct injection of methane closer to the discharge allowed one to significantly increase the diamond growth rate. These results will be discussed using a non-dimensional analysis of the transport phenomena (mass, energy and momentum by convection and diffusion) and production of the CH3 radical in the reactor.

  11. Experimental Investigation of Gas Hydrate Production at Injection of Liquid Nitrogen into Water with Bubbles of Freon 134A

    Directory of Open Access Journals (Sweden)

    Meleshkin Anton V.

    2016-01-01

    Full Text Available The hydrodynamic processes during the injection of the cryogenic liquid into the volume of water with bubbles of gas freon 134a are studding experimentally. A processes during the explosive boiling of liquid nitrogen in the volume of water are registered. Video recording of identified gas hydrate flakes formed during this process is carried out by high speed camera. These results may be useful for the study of the new method of producing gas hydrates, based on the shock-wave method.

  12. Pressure-assisted electrokinetic injection for on-line enrichment in capillary electrophoresis-mass spectrometry: a sensitive method for measurement of ten haloacetic acids in drinking water.

    Science.gov (United States)

    Zhang, Huijuan; Zhu, Jiping; Aranda-Rodriguez, Rocio; Feng, Yong-Lai

    2011-11-07

    Haloacetic acids (HAAs) are by-products of the chlorination of drinking water containing natural organic matter and bromide. A simple and sensitive method has been developed for determination of ten HAAs in drinking water. The pressure-assisted electrokinetic injection (PAEKI), an on-line enrichment technique, was employed to introduce the sample into a capillary electrophoresis (CE)-electrospray ionization-tandem mass spectrometry system (ESI-MS/MS). HAAs were monitored in selected reaction monitoring mode. With 3 min of PAEKI time, the ten major HAAs (HAA10) in drinking water were enriched up to 20,000-fold into the capillary without compromising resolution. A simple solid phase clean-up method has been developed to eliminate the influence of ionic matrices from drinking water on PAEKI. Under conditions optimized for mass spectrometry, PAEKI and capillary electrophoresis, detection limits defined as three times ratio of signal to noise have been achieved in a range of 0.013-0.12 μg L(-1) for ten HAAs in water sample. The overall recoveries for all ten HAAs in drinking water samples were between 76 and 125%. Six HAAs including monochloro- (MCAA), dichloro- (DCAA), trichloro- (TCAA), monobromo- (MBAA), bromochloro- (BCAA), and bromodichloroacetic acids (BDCAA) were found in tap water samples collected. Crown Copyright © 2011. Published by Elsevier B.V. All rights reserved.

  13. Simultaneous quantification of polar and non-polar volatile organic compounds in water samples by direct aqueous injection-gas chromatography/mass spectrometry.

    Science.gov (United States)

    Aeppli, Christoph; Berg, Michael; Hofstetter, Thomas B; Kipfer, Rolf; Schwarzenbach, René P

    2008-02-15

    A direct aqueous injection-gas chromatography/mass spectrometry (DAI-GC/MS) method for trace analysis of 24 volatile organic compounds (VOCs) in water samples is presented. The method allows for the simultaneous quantification of benzene, toluene, ethyl benzene, and xylenes (BTEX), methyl tert-butyl ether (MTBE), tert-butyl alcohol (TBA), as well as a variety of chlorinated methanes, ethanes, propane, enthenes and benzenes. Applying a liquid film polyethylene glycol or a porous layer open tubular (PLOT) divinylbenzene GC capillary column to separate the water from the VOCs, volumes of 1-10 microL aqueous sample are directly injected into the GC. No enrichment or pretreatment steps are required and sample volumes as low as 100 microL are sufficient for accurate quantification. Method detection limits determined in natural groundwater samples were between 0.07 and 2.8 microg/L and instrument detection limits of VOCs. DAI-GC/MS offers both good accuracy and precision (relative standard deviations VOC concentration measurements in a polluted aquifer. The wide range of detectable compounds and the lack of labor-intensive sample preparation illustrate that the DAI method is robust and easily applicable for the quantification of important organic groundwater contaminants.

  14. Characterization of gas reburning-sorbent injection technology by-products

    International Nuclear Information System (INIS)

    Mattigod, S.V.; Rai, D.

    1992-01-01

    This paper reports that three samples of fly ashes from pilot-scale tests of gas reburning and sorbent injection (GR-SI) technology were characterized physically, chemically, and mineralogically. Texturally, the samples consist of approximately 97% of the total mass of the sample on average. Approximately 3% of the sample mass consisted of the elements Cl, Mg, P, K, Na, and Ti, and ).4% consisted of trace elements. Major crystalline compounds found in these samples were lime (CaO), anhydrite (CaSO 4 ), and calcium carbonate (CaCO 3 ). The morphology and chemistry of particles in GR-SI samples were similar to those of particles in conventional coal fly ashes. Most of the particles were calcerous. Silicate and alumino-silicate particles were fewer in number, and iron-rich particles were rare. The EP test indicated that extract concentrations of Ag, As, Ba, Cd, Cr, Pb, and Se were sell below the EPA regulatory levels. Predictions of leachate compositions from these types of fly ashes, if disposed of as a landfill at a midwestern U.S. site indicate, that during the first ten years the concentrations of Ca, SO 4 , Na, b, and OH would remain high. The concentrations of minor constituents (As, Ba, Cd, Cd, cu, Cr, Fe, Ni, and Se) in the leachate are predicted to be at trace levels

  15. Amperometric Determination of Sulfite by Gas Diffusion- Sequential Injection with Boron-Doped Diamond Electrode

    Directory of Open Access Journals (Sweden)

    Orawon Chailapakul

    2008-03-01

    Full Text Available A gas diffusion sequential injection system with amperometric detection using aboron-doped diamond electrode was developed for the determination of sulfite. A gasdiffusion unit (GDU was used to prevent interference from sample matrices for theelectrochemical measurement. The sample was mixed with an acid solution to generategaseous sulfur dioxide prior to its passage through the donor channel of the GDU. Thesulfur dioxide diffused through the PTFE hydrophobic membrane into a carrier solution of 0.1 M phosphate buffer (pH 8/0.1% sodium dodecyl sulfate in the acceptor channel of theGDU and turned to sulfite. Then the sulfite was carried to the electrochemical flow cell anddetected directly by amperometry using the boron-doped diamond electrode at 0.95 V(versus Ag/AgCl. Sodium dodecyl sulfate was added to the carrier solution to preventelectrode fouling. This method was applicable in the concentration range of 0.2-20 mgSO32−/L and a detection limit (S/N = 3 of 0.05 mg SO32−/L was achieved. This method wassuccessfully applied to the determination of sulfite in wines and the analytical resultsagreed well with those obtained by iodimetric titration. The relative standard deviations forthe analysis of sulfite in wines were in the range of 1.0-4.1 %. The sampling frequency was65 h−1.

  16. Industrial Compositional Streamline Simulation for Efficient and Accurate Prediction of Gas Injection and WAG Processes

    Energy Technology Data Exchange (ETDEWEB)

    Margot Gerritsen

    2008-10-31

    Gas-injection processes are widely and increasingly used for enhanced oil recovery (EOR). In the United States, for example, EOR production by gas injection accounts for approximately 45% of total EOR production and has tripled since 1986. The understanding of the multiphase, multicomponent flow taking place in any displacement process is essential for successful design of gas-injection projects. Due to complex reservoir geometry, reservoir fluid properties and phase behavior, the design of accurate and efficient numerical simulations for the multiphase, multicomponent flow governing these processes is nontrivial. In this work, we developed, implemented and tested a streamline based solver for gas injection processes that is computationally very attractive: as compared to traditional Eulerian solvers in use by industry it computes solutions with a computational speed orders of magnitude higher and a comparable accuracy provided that cross-flow effects do not dominate. We contributed to the development of compositional streamline solvers in three significant ways: improvement of the overall framework allowing improved streamline coverage and partial streamline tracing, amongst others; parallelization of the streamline code, which significantly improves wall clock time; and development of new compositional solvers that can be implemented along streamlines as well as in existing Eulerian codes used by industry. We designed several novel ideas in the streamline framework. First, we developed an adaptive streamline coverage algorithm. Adding streamlines locally can reduce computational costs by concentrating computational efforts where needed, and reduce mapping errors. Adapting streamline coverage effectively controls mass balance errors that mostly result from the mapping from streamlines to pressure grid. We also introduced the concept of partial streamlines: streamlines that do not necessarily start and/or end at wells. This allows more efficient coverage and avoids

  17. Effect of 13C enrichment and sugar type on analysis of sugars by gas chromatography/combustion/isotope ratio mass spectrometry.

    Science.gov (United States)

    Baumann, Karen; Dignac, Marie-France; Bardoux, Gérard; Rumpel, Cornelia

    2012-09-15

    The objective of this investigation was to test gas-chromatographic compound-specific analysis for studies on the isotopic composition of (13)C-enriched sugar molecules. The effects of (13)C enrichment and type of sugar (C5, C6) will provide valuable information on isotopic correction for future studies employing (13)C-enriched sugars. Five sugar solutions of xylose, mannose and glucose with (13)C enrichments ranging between 1.1 and 1.5 atom-% were prepared. The (13)C enrichments of the initial sugars were measured by elemental analyser/isotope ratio mass spectrometry (EA/IRMS); (13)C enrichments for derivatised sugars were obtained by gas chromatography/combustion/IRMS (GC/C/IRMS). The linear relationships between the (13)C enrichments of the initial sugars and the values for the derivatised sugars were sugar-type dependent. Corrections for GC/C/IRMS values took into account the kinetic isotope effect (KIE) of the derivatising agent associated with the coefficient (K(d)) and a newly introduced second coefficient (K(c)) associated with the KIE of the sugar. While K(d) was constant, K(c) varied with sugar type. During derivatisation acetate groups with (12)C and sugars with more (13)C reacted faster. Coefficients for the specific ranges of (13)C enrichments under study have to be assessed and the reactions of different sugar types have to be taken into account to avoid underestimation of (13)C enrichment of up to 9% (C5) or overestimation of up to 4% (C6). Copyright © 2012 John Wiley & Sons, Ltd.

  18. Optimizations of packed sorbent and inlet temperature for large volume-direct aqueous injection-gas chromatography to determine high boiling volatile organic compounds in water.

    Science.gov (United States)

    Yu, Bofan; Song, Yonghui; Han, Lu; Yu, Huibin; Liu, Yang; Liu, Hongliang

    2014-08-22

    For the expanded application area, fast trace analysis of certain high boiling point (i.e., 150-250 °C) volatile organic compounds (HVOCs) in water, a large volume-direct aqueous injection-gas chromatography (LV-DAI-GC) method was optimized for the following parameters: packed sorbent for sample on-line pretreatment, inlet temperature and detectors configuration. Using the composite packed sorbent self-prepared with lithium chloride and a type of diatomite, the method enabled safe injection of an approximately 50-100 μL sample at an inlet temperature of 150 °C in the splitless mode and separated HVOCs from water matrix in 2 min. Coupled with a flame ionization detector (FID), an electron capture detector (ECD) and a flame photometric detector (FPD), the method could simultaneously quantify 27 HVOCs that belong to seven subclasses (i.e., halogenated aliphatic hydrocarbons, chlorobenzenes, nitrobenzenes, anilines, phenols, polycyclic aromatic hydrocarbons and organic sulfides) in 26 min. Injecting a 50 μL sample without any enrichment step, such as cryotrap focusing, the limits of quantification (LOQs) for the 27 HVOCs was 0.01-3 μg/L. Replicate analyses of the 27 HVOCs spiked source and river water samples exhibited good precision (relative standard deviations ≤ 11.3%) and accuracy (relative errors ≤ 17.6%). The optimized LV-DAI-GC was robust and applicable for fast determination and automated continuous monitoring of HVOCs in surface water. Copyright © 2014 Elsevier B.V. All rights reserved.

  19. Design of Electrical System for Inhibitor Injection Pump’s Motor PAQ 01/02/03 RSG-GAS

    International Nuclear Information System (INIS)

    Taufiq, M.; Teguh Sulistyo; Kiswanto; Santosa Pujiarta

    2008-01-01

    In order to control the water quality related to the growth of scale, corrosion and micro-organism in the PA01 BR01 and PA02 BR 02 piping system of secondary cooling system of RSG-GAS, electrical systems for motor of inhibitor injection pump PAQ 01/02/03, including motor control system circuit for inhibitor injection pump PAQ02 AP01, motor control system circuit for NaOCl injection pump PAQ01 AP01, motor control system circuit for inhibitor injection pump PAQ02 AP02 and control system circuit for stir pump RW02 have been designed. Motor control system circuit for pump PAQ02 AP01 which attached at the inhibitor tank will operate when conductivity control CQ01 indicates blow down condition and pump motor PAQ02 AP02 is not operate when level control CL02 indicates minimum level. This design is expected that, NaOCl injection pump PAQ01 AP 01 will operate continuously and inhibitor injection pump PAQ02 AP02 will operate automatically. (author)

  20. Foaming morphology control of microcellular injection molded parts with gas counter pressure and dynamic mold temperature control

    Science.gov (United States)

    Shiu, Tai-Yi; Huang, Chao-Tsai; Chang, Rong-Yu; Hwang, Shyh-Shin

    2014-05-01

    Microcellular injection molding process is a promising solution for products with special requirements such as weight reduction, extra thin wall, high dimensional stability, clamping force reduction, etc. Despite microcellular foaming application used in reciprocating screw injection molding machine was built more than a decade, some limitations, such as poor surface quality or poor foaming control, confine the usage of this technology. Earlier CAE simulation tool for microcellular injection molding was not successful due to insufficient physical and computational considerations, limited by complicated bubble growth mechanism; so that, an economic and efficient tool for examining foaming quality of injection foaming product was lack. In this study, a recent developed three-dimensional simulation tool is used to predict injection foaming process. Predictions are carried out with commodity polypropylene and polystyrene with nitrogen and carbon dioxide supercritical fluids (SCFs). Comparisons of simulations between microcellular injection molding with and without counter pressure are discussed to provide insights into the correlation of surface quality and cell size distribution near the surface of product. Furthermore, comparisons between simulation predictions and experimental results of molding process, which is featured with dynamic mold temperature and gas counter pressure, are given for understanding quality improvement by controlling foaming morphology, and benefit of industrial application.

  1. Flow injection gas chromatography with sulfur chemiluminescence detection for the analysis of total sulfur in complex hydrocarbon matrixes.

    Science.gov (United States)

    Hua, Yujuan; Hawryluk, Myron; Gras, Ronda; Shearer, Randall; Luong, Jim

    2018-01-01

    A fast and reliable analytical technique for the determination of total sulfur levels in complex hydrocarbon matrices is introduced. The method employed flow injection technique using a gas chromatograph as a sample introduction device and a gas phase dual-plasma sulfur chemiluminescence detector for sulfur quantification. Using the technique described, total sulfur measurement in challenging hydrocarbon matrices can be achieved in less than 10 s with sample-to-sample time ideal for fast analysis or trace sulfur analysis. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Pre-injection Comparison of Methods for Sampling Formation Water and Associated Gas from a Monitoring Well at a Carbon Dioxide Injection Site, Citronelle Oil Field, Alabama

    Science.gov (United States)

    Conaway, C.; Thordsen, J. J.; Manning, M. A.; Cook, P. J.; Abedini, A. A.; Trautz, R. C.; Thomas, B.; Kharaka, Y. K.

    2012-12-01

    The chemical composition of formation water and associated gases from the lower Cretaceous Paluxy Formation was determined using four different sampling methods at a well in the Citronelle Oil Field, Alabama, a site that will be used for a carbon dioxide injection experiment. Prior to each of the two sampling periods, the well was cleaned from the drilling fluids and KCl solutions by producing at least three pore volumes of formation water. Accurate measurements of the chemical composition of groundwater or formation water, including dissolved gasses, and gas samples is essential in understanding subsurface geochemical processes occurring as a result of geologic carbon dioxide injection, which is used for enhanced oil recovery (EOR) and has been proposed as a means of carbon sequestration. In this study, formation water and gas samples for geochemical analyses were obtained from well D-9-8 #2 at Citronelle using nitrogen lift, submersible pump, U-Tube, and a downhole (Kuster) sampler. Field chemical analyses included electrical conductivity, hydrogen sulfide, alkalinity, and pH, and laboratory analyses included major, minor and trace elements by mass spectrometry and ion chromatography, dissolved carbon, organic acid anions, free and dissolved gas species. The formation water obtained from this well is a Na-Ca-Cl brine with a salinity of 160,000 and 200,000 mg/L total dissolved solids (TDS). Differences were evident between sampling methodologies, particularly in pH, Fe and alkalinity measurements. The results of the comparison demonstrate the difficulty and importance of preserving volatile analytes in samples, with the downhole sampler and U-Tube system performing most favorably in this aspect.

  3. Accumulation conditions and enrichment patterns of natural gas in the Lower Cambrian Longwangmiao Fm reservoirs of the Leshan-Longnǚsi Palaeohigh, Sichuan Basin

    Directory of Open Access Journals (Sweden)

    Xu Chunchun

    2014-10-01

    Full Text Available As several major new gas discoveries have been made recently in the Lower Cambrian Longwangmiao Fm reservoirs in the Leshan-Longnǚsi Palaeohigh of the Sichuan Basin, a super-huge gas reservoir group with multiple gas pay zones vertically and cluster reservoirs laterally is unfolding in the east segment of the palaeohigh. Study shows that the large-scale enrichment and accumulation of natural gas benefits from the good reservoir-forming conditions, including: (1 multiple sets of source rocks vertically, among which, the high-quality Lower Paleozoic source rocks are widespread, and have a hydrocarbon kitchen at the structural high of the Palaeohigh, providing favorable conditions for gas accumulation near the source; (2 three sets of good-quality reservoirs, namely, the porous-vuggy dolomite reservoirs of mound-shoal facies in the 2nd and 4th members of the Sinian Dengying Fm as well as the porous dolomite reservoirs of arene-shoal facies in the Lower Cambrian Longwangmiao Fm, are thick and wide in distribution; (3 structural, lithological and compound traps developed in the setting of large nose-like uplift provide favorable space for hydrocarbon accumulation. It is concluded that the inheritance development of the Palaeohigh and its favorable timing configuration with source rock evolution are critical factors for the extensive enrichment of gas in the Lower Cambrian Longwangmiao Fm reservoirs. The structural high of the Palaeohigh is the favorable area for gas accumulation. The inherited structural, stratigraphic and lithological traps are the favorable sites for gas enrichment. The areas where present structures and ancient structures overlap are the sweet-spots of gas accumulation.

  4. Impact of localized gas injection on ICRF coupling and SOL parameters in JET-ILW H-mode plasmas

    Czech Academy of Sciences Publication Activity Database

    Lerche, E.; Goniche, M.; Jacquet, P.; Van Eester, D.; Bobkov, V.; Colas, L.; Czarnecka, A.; Brezinsek, S.; Brix, M.; Crombe, K.; Graham, M.; Groth, M.; Monakhov, I.; Mathurin, T.; Matthews, G.; Meneses, L.; Noble, C.; Petržílka, Václav; Rimini, F.; Shaw, A.

    2015-01-01

    Roč. 463, August (2015), s. 634-639 ISSN 0022-3115. [PLASMA-SURFACE INTERACTIONS 21: International Conference on Plasma-Surface Interactions in Controlled Fusion Devices. Kanazawa, 26.05.2014-30.05.2014] Institutional support: RVO:61389021 Keywords : Ion cyclotron * gas injection Subject RIV: JF - Nuclear Energetics OBOR OECD: Nuclear related engineering Impact factor: 2.199, year: 2015 http://dx.doi.org/10.1016/j.jnucmat.2014.10.074

  5. Greenhouse Gas Fluxes from Salt Marshes Exposed to Chronic Nutrient Enrichment.

    Directory of Open Access Journals (Sweden)

    Gail L Chmura

    Full Text Available We assessed the impact of nutrient additions on greenhouse gas fluxes using dark static chambers in a microtidal and a macrotidal marsh along the coast of New Brunswick, Canada approximately monthly over a year. Both were experimentally fertilized for six years with varying levels of N and P. For unfertilized, N and NPK treatments, average yearly CO2 emissions (which represent only respiration at the microtidal marsh (13, 19, and 28 mmoles CO2 m(-2 hr(-1, respectively were higher than at the macrotidal marsh (12, 15, and 19 mmoles m(-2 hr(-1, respectively, with a flux under the additional high N/low P treatment of 21 mmoles m(-2 hr(-1. Response of CH4 to fertilization was more variable. At the macrotidal marsh average yearly fluxes were 1.29, 1.26, and 0.77 μmol CH4 m(-2 hr(-1 with control, N, and NPK treatments, respectively and 1.21 μmol m(-2 hr(-1 under high N/low P treatment. At the microtidal marsh CH4 fluxes were 0.23, 0.16, and -0.24 μmol CH4 m(-2 hr(-1 in control, N, and NPK and treatments, respectively. Fertilization changed soils from sinks to sources of N2O. Average yearly N2O fluxes at the macrotidal marsh were -0.07, 0.08, and 1.70, μmol N2O m(-2 hr(-1 in control, N, NPK and treatments, respectively and 0.35 μmol m(-2 hr(-1 under high N/low P treatment. For the control, N, and NPK treatments at the microtidal marsh N2O fluxes were -0.05, 0.30, and 0.52 μmol N2O m(-2 hr(-1, respectively. Our results indicate that N2O fluxes are likely to vary with the source of pollutant nutrients but emissions will be lower if N is not accompanied by an adequate supply of P (e.g., atmospheric deposition vs sewage or agricultural runoff. With chronic fertilization the global warming potential of the increased N2O emissions may be enough to offset the global cooling potential of the C sequestered by salt marshes.

  6. Greenhouse gas fluxes from salt marshes exposed to chronic nutrient enrichment

    Science.gov (United States)

    Chmura, Gail L.; Kellman, Lisa; van Ardenne, Lee; Guntenspergen, Glenn R.

    2016-01-01

    We assessed the impact of nutrient additions on greenhouse gas fluxes using dark static chambers in a microtidal and a macrotidal marsh along the coast of New Brunswick, Canada approximately monthly over a year. Both were experimentally fertilized for six years with varying levels of N and P. For unfertilized, N and NPK treatments, average yearly CO2 emissions (which represent only respiration) at the microtidal marsh (13, 19, and 28 mmoles CO2 m-2 hr-1, respectively) were higher than at the macrotidal marsh (12, 15, and 19 mmoles m-2 hr-1, respectively, with a flux under the additional high N/low P treatment of 21 mmoles m-2 hr-1). Response of CH4 to fertilization was more variable. At the macrotidal marsh average yearly fluxes were 1.29, 1.26, and 0.77 μmol CH4 m-2 hr-1 with control, N, and NPK treatments, respectively and 1.21 μmol m-2 hr-1 under high N/low P treatment. At the microtidal marsh CH4fluxes were 0.23, 0.16, and -0.24 μmol CH4 m-2 hr-1 in control, N, and NPK and treatments, respectively. Fertilization changed soils from sinks to sources of N2O. Average yearly N2O fluxes at the macrotidal marsh were -0.07, 0.08, and 1.70, μmol N2O m-2 hr-1 in control, N, NPK and treatments, respectively and 0.35 μmol m-2 hr-1 under high N/low P treatment. For the control, N, and NPK treatments at the microtidal marsh N2O fluxes were -0.05, 0.30, and 0.52 μmol N2O m-2 hr-1, respectively. Our results indicate that N2O fluxes are likely to vary with the source of pollutant nutrients but emissions will be lower if N is not accompanied by an adequate supply of P (e.g., atmospheric deposition vs sewage or agricultural runoff). With chronic fertilization the global warming potential of the increased N2O emissions may be enough to offset the global cooling potential of the C sequestered by salt marshes.

  7. Full evaporation dynamic headspace and gas chromatography-mass spectrometry for uniform enrichment of odor compounds in aqueous samples.

    Science.gov (United States)

    Ochiai, Nobuo; Sasamoto, Kikuo; Hoffmann, Andreas; Okanoya, Kazunori

    2012-06-01

    A method for analysis of a wide range of odor compounds in aqueous samples at sub-ng mL⁻¹ to μg mL⁻¹ levels was developed by full evaporation dynamic headspace (FEDHS) and gas chromatography-mass spectrometry (GC-MS). Compared to conventional DHS and headspace solid phase microextraction (HS-SPME), FEDHS provides more uniform enrichment over the entire polarity range for odor compounds in aqueous samples. FEDHS at 80°C using 3 L of purge gas allows complete vaporization of 100 μL of an aqueous sample, and trapping and drying it in an adsorbent packed tube, while providing high recoveries (85-103%) of the 18 model odor compounds (water solubility at 25°C: log0.54-5.65 mg L⁻¹, vapor pressure at 25°C: 0.011-3.2 mm Hg) and leaving most of the low volatile matrix behind. The FEDHS-GC-MS method showed good linearity (r²>0.9909) and high sensitivity (limit of detection: 0.21-5.2 ng mL⁻¹) for the model compounds even with the scan mode in the conventional MS. The feasibility and benefit of the method was demonstrated with analyses of key odor compounds including hydrophilic and less volatile characteristics in beverages (whiskey and green tea). In a single malt whiskey sample, phenolic compounds including vanillin could be determined in the range of 0.92-5.1 μg mL⁻¹ (RSDfuraneol, indole, maltol, and pyrazine congeners) were determined in the range of 0.21-110 ng mL⁻¹ (RSD<10%, n=6). Copyright © 2012 Elsevier B.V. All rights reserved.

  8. Influence of Injector Location on Part-Load Performance Characteristics of Natural Gas Direct-Injection in a Spark Ignition Engine

    Energy Technology Data Exchange (ETDEWEB)

    Sevik, James [Argonne National Lab. (ANL), Argonne, IL (United States); Pamminger, Michael [Argonne National Lab. (ANL), Argonne, IL (United States); Wallner, Thomas [Argonne National Lab. (ANL), Argonne, IL (United States); Scarcelli, Riccardo [Argonne National Lab. (ANL), Argonne, IL (United States); Boyer, Brad [Ford Motor Co., Detroit, MI (United States); Wooldridge, Steven [Ford Motor Co., Detroit, MI (United States); Hall, Carrie [Illinois Inst. of Technology, Chicago, IL (United States); Miers, Scott [Michigan Technological Univ., Houghton, MI (United States)

    2016-04-05

    Interest in natural gas as an alternative fuel source to petroleum fuels for light-duty vehicle applications has increased due to its domestic availability and stable price compared to gasoline. With its higher hydrogen-to-carbon ratio, natural gas has the potential to reduce engine out carbon dioxide emissions, which has shown to be a strong greenhouse gas contributor. For part-load conditions, the lower flame speeds of natural gas can lead to an increased duration in the inflammation process with traditional port-injection. Direct-injection of natural gas can increase in-cylinder turbulence and has the potential to reduce problems typically associated with port-injection of natural gas, such as lower flame speeds and poor dilution tolerance. A study was designed and executed to investigate the effects of direct-injection of natural gas at part-load conditions. Steady-state tests were performed on a single-cylinder research engine representative of current gasoline direct-injection engines. Tests were performed with direct-injection in the central and side location. The start of injection was varied under stoichiometric conditions in order to study the effects on the mixture formation process. In addition, exhaust gas recirculation was introduced at select conditions in order to investigate the dilution tolerance. Relevant combustion metrics were then analyzed for each scenario. Experimental results suggest that regardless of the injector location, varying the start of injection has a strong impact on the mixture formation process. Delaying the start of injection from 300 to 120°CA BTDC can reduce the early flame development process by nearly 15°CA. While injecting into the cylinder after the intake valves have closed has shown to produce the fastest combustion process, this does not necessarily lead to the highest efficiency, due to increases in pumping and wall heat losses. When comparing the two injection configurations, the side location shows the best

  9. Determination of Parabens by Injection-Port Derivatization Coupled With Gas-Chromatography-Mass Spectrometry and Matrix Solid Phase Dispersion

    Science.gov (United States)

    Djatmika, Rosalina; Ding, Wang-Hsien; Sulistyarti, Hermin

    2018-01-01

    A rapid determination of four parabens preservatives (methyl paraben, ethyl paraben, propyl paraben, and butyl paraben) in marketed seafood is presented. Analytes were extracted and purified using matrix solid-phase dispersion (MSPD) method, followed by Injection port acylation gas chromatography-mass spectrometry (GC-MS) with acetic anhydride reagent. In this method, acylation of parabens was performed by acetic anhydride at GC injection-port generating reduction of the time-consuming sample-processing steps, and the amount of toxic reagents and solvents. The parameters affecting this method such as injection port temperature, purge-off time and acylation (acetic anhydride) volume were studied. In addition, the MSPD influence factors (including the amount of dispersant and clean-up co-sorbent, as well as the volume of elution solvent) were also investigated. After MSPD method and Injection port acylation applied, good linearity of analytes was achieved. The limits of quantitation (LOQs) were 0.2 to 1.0 ng/g (dry weight). Compared with offline derivatization commonly performed, injection port acylation employs a rapid, simple, low-cost and environmental-friendly derivatization process. The optimized method has been successfully applied for the analysis of parabens in four kind of marketed seafood. Preliminary results showed that the total concentrations of four selected parabens ranged from 16.7 to 44.7 ng/g (dry weight).

  10. Calf Spleen Extractive Injection (CSEI, a small peptides enriched extraction, induces human hepatocellular carcinoma cell apoptosis via ROS/MAPKs dependent mitochondrial pathway

    Directory of Open Access Journals (Sweden)

    Dongxu Jia

    2016-10-01

    Full Text Available Calf Spleen Extractive Injection (CSEI, a small peptides enriched extraction, performs immunomodulatory activity on cancer patients suffering from radiotherapy or chemotherapy. The present study aims to investigate the anti-hepatocellular carcinoma effects of CSEI in cells and tumor-xenografted mouse models. In HepG2 and SMMC-7721 cells, CSEI reduced cell viability, enhanced apoptosis rate, caused reactive oxygen species (ROS accumulation, inhibited migration ability, and induced caspases cascade and mitochondrial membrane potential dissipation. CSEI significantly inhibited HepG2-xenografted tumor growth in nude mice. In cell and animal experiments, CSEI increased the activations of pro-apoptotic proteins including caspase 8, caspase 9 and caspase 3; meanwhile, it suppressed the expressions of anti-apoptotic protein B-cell lymphoma 2 (Bcl-2 and anti-oxidation proteins, such as nuclear factor-erythroid 2 related factor 2 (Nrf2 and catalase (CAT. The enhanced phosphorylation of P38 and c-JunN-terminalkinase (JNK, and decreased phosphorylation of extra cellular signal-regulated protein kinase (ERKs were observed in CSEI-treated cells and tumor tissues. CSEI-induced cell viability reduction was significantly attenuated by N-Acetyl-l-cysteine (a ROS inhibitor pretreatment. All data demonstrated that the upregulated oxidative stress status and the altered mitogen-activated protein kinases (MAPKs phosphorylation contributed to CSEI-driven mitochondrial dysfunction. Taken together, CSEI exactly induced apoptosis in human hepatocellular carcinoma cells via ROS/MAPKs dependent mitochondrial pathway.

  11. Recent ORNL experience in site performance prediction: the Gas Centrifuge Enrichment Plant and the Oak Ridge Central Waste Disposal Facility

    International Nuclear Information System (INIS)

    Pin, F.G.

    1985-01-01

    The suitability of the Portsmouth Gas Centrifuge Enrichment Plant Landfill and the Oak Ridge, Tennessee, Central Waste Disposal Facility for disposal of low-level radioactive waste was evaluated using pathways analyses. For these evaluations, a conservative approach was selected; that is, conservatism was built into the analyses when assumptions concerning future events had to be made or when uncertainties concerning site or waste characteristics existed. Data from comprehensive laboratory and field investigations were used in developing the conceptual and numerical models that served as the basis for the numerical simulations of the long-term transport of contamination to man. However, the analyses relied on conservative scenarios to describe the generation and migration of contamination and the potential human exposure to the waste. Maximum potential doses to man were calculated and compared to the appropriate standards. Even under this conservative framework, the sites were found to provide adequate buffer to persons outside the DOE reservations and conclusions concerning site capacity and site acceptability were drawn. Our experience through these studies has shown that in reaching conclusions in such studies, some consideration must be given to the uncertainties and conservatisms involved in the analyses. Analytical methods to quantitatively assess the probability of future events to occur and to quantitatively determine the sensitivity of the results to data uncertainty may prove useful in relaxing some of the conservatism built into the analyses. The applicability of such methods to pathways analyses is briefly discussed

  12. Wintertime Air-Sea Gas Transfer Rates and Air Injection Fluxes at Station Papa in the NE Pacific

    Science.gov (United States)

    McNeil, C.; Steiner, N.; Vagle, S.

    2008-12-01

    In recent studies of air-sea fluxes of N2 and O2 in hurricanes, McNeil and D'Asaro (2007) used a simplified model formulation of air-sea gas flux to estimate simultaneous values of gas transfer rate, KT, and air injection flux, VT. The model assumes air-sea gas fluxes at high to extreme wind speeds can be explained by a combination of two processes: 1) air injection, by complete dissolution of small bubbles drawn down into the ocean boundary layer by turbulent currents, and 2) near-surface equilibration processes, such as occurs within whitecaps. This analysis technique relies on air-sea gas flux estimates for two gases, N2 and O2, to solve for the two model parameters, KT and VT. We present preliminary results of similar analysis of time series data collected during winter storms at Station Papa in the NE Pacific during 2003/2004. The data show a clear increase in KT and VT with increasing NCEP derived wind speeds and acoustically measured bubble penetration depth.

  13. Enhancing the use of coals by gas reburning-sorbent injection: Volume 4 -- Gas reburning-sorbent injection at Lakeside Unit 7, City Water, Light and Power, Springfield, Illinois. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    A demonstration of Gas Reburning-Sorbent Injection (GR-SI) has been completed at a cyclone-fired utility boiler. The Energy and Environmental Research Corporation (EER) has designed, retrofitted and tested a GR-SI system at City Water Light and Power`s 33 MWe Lakeside Station Unit 7. The program goals of 60% NO{sub x} emissions reduction and 50% SO{sub 2} emissions reduction were exceeded over the long-term testing period; the NO{sub x} reduction averaged 63% and the SO{sub 2} reduction averaged 58%. These were achieved with an average gas heat input of 22% and a calcium (sorbent) to sulfur (coal) molar ratio of 1.8. GR-SI resulted in a reduction in thermal efficiency of approximately 1% at full load due to firing natural gas which forms more moisture in flue gas than coal and also results in a slight increase in air heater exit gas temperature. Minor impacts on other areas of unit performance were measured and are detailed in this report. The project at Lakeside was carried out in three phases, in which EER designed the GR-SI system (Phase 1), completed construction and start-up activities (Phase 2), and evaluated its performance with both short parametric tests and a long-term demonstration (Phase 3). This report contains design and technical performance data; the economics data for all sites are presented in Volume 5.

  14. Off-design analysis of a gas turbine powerplant augmented by steam injection using various fuels

    Science.gov (United States)

    Stochl, R. J.

    1980-01-01

    Results are compared using coal derived low and intermediate heating valve fuel gases and a conventional distillate. The results indicate that steam injection provides substantial increases in both power and efficiency within the available compressor surge margin. The results also indicate that these performance gains are relatively insensitive as to the type of fuel. Also, in a cogeneration application, steam injection could provide some degree of flexibility by varying the split between power and process steam.

  15. Data for generation of all Tables and Figures for AIMS-ES publication in 2016 pertaining to dry sorbent injection of trona for acid gas control

    Data.gov (United States)

    U.S. Environmental Protection Agency — emissions data and removal efficiencies for coal combustion utilizing PM control devices and dry sorbent injection of trona specifically for acid gas control. This...

  16. Modeling of fault activation and seismicity by injection directly into a fault zone associated with hydraulic fracturing of shale-gas reservoirs

    Science.gov (United States)

    LBNL, in consultation with the EPA, expanded upon a previous study by injecting directly into a 3D representation of a hypothetical fault zone located in the geologic units between the shale-gas reservoir and the drinking water aquifer.

  17. The mechanism study between 3D Space-time deformation and injection or extraction of gas pressure change, the Hutubi Underground gas storage

    Science.gov (United States)

    Xiaoqiang, W.; Li, J.; Daiqing, L.; Li, C.

    2017-12-01

    The surface deformation of underground gas reservoir with the change of injection pressure is an excellent opportunity to study the load response under the action of tectonic movement and controlled load. This paper mainly focuses on the elastic deformation of underground structure caused by the change of the pressure state of reservoir rock under the condition of the irregular change of pressure in the underground gas storage of Hutubi, the largest underground gas storage in Xinjiang, at the same time, it makes a fine study on the fault activities of reservoir and induced earthquakes along with the equilibrium instability caused by the reservoir. Based on the 34 deformation integrated observation points and 3 GPS continuous observation stations constructed in the underground gas storage area of Hutubi, using modern measurement techniques such as GPS observation, precise leveling survey, flow gravity observation and so on, combined with remote sensing technology such as InSAR, the 3d space-time sequence images of the surface of reservoir area under pressure change were obtained. Combined with gas well pressure, physical parameters and regional seismic geology and geophysical data, the numerical simulation and analysis of internal changes of reservoir were carried out by using elastic and viscoelastic model, the deformation mechanical relationship of reservoir was determined and the storage layer under controlled load was basically determined. This research is financially supported by National Natural Science Foundation of China (Grant No.41474016, 41474051, 41474097)

  18. Injection of natural gas in the blast furnace tuyeres three of the Usiminas, Ipatinga Plant; Injecao de gas natural nas ventaneiras do alto-forno 3 da Usiminas, Usina de Ipatinga

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Murilo Alves Tito de; Rosa, Ericson Rimen Ribeiro; Oliveira, Claudiney Freitas de; Hostt, Helton [USIMINAS, Ipatinga, MG (Brazil). Gerencia Geral de Reducao

    2011-12-21

    The reduction in production costs is a major strategic objectives of Usiminas and the use of natural gas in the Blast Furnace 3 (BF 3) contribute to achieve this goal. The use of natural gas as fuel in the BF 3 to reduce the use of metallurgical coke (main fuel) and reduces production losses during periods of maintenance in the pulverized coal injection system and improving operational control of the Blast Furnace. The work presents the deployment of the natural gas injection and the performance obtained by the BF 3 from the start of injection, with a focus on reducing consumption of metallurgical coke and stable operation of blast furnace (author)

  19. Economic feasibility of hydrogen enrichment for reducing NOx emissions from landfill gas power generation alternatives: A comparison of the levelized cost of electricity with present strategies

    International Nuclear Information System (INIS)

    Kornbluth, Kurt; Greenwood, Jason; Jordan, Eddie; McCaffrey, Zach; Erickson, Paul A.

    2012-01-01

    Based on recent research showing that hydrogen enrichment can lower NO x emissions from landfill gas combustion below future NO x emission control standards imposed by both federal and California state regulations, an investigation was performed to compare the levelized cost of electricity of this technology with other options. In this cost study, a lean-burn reciprocating engine with no after-treatment was the baseline case to compare six other landfill gas-to-energy projects. These cases include a lean burn engine with selective catalytic reduction after treatment, a lean-burn microturbine, and four variations on an ultra-lean-burn engine utilizing hydrogen enrichment with each case using a different method of hydrogen production. Only hydrogen enrichment with an in-stream autothermal fuel reformer was shown to be potentially cost-competitive with current strategies for reaching the NO x reduction target in IC engines. - Highlights: ► Levelized cost of electricity for hydrogen enriched combustion was compared. ► Various ultra-lean-burn engines and microturbines with hydrogen were analyzed. ► Combustion with an autothermal fuel reformer was potentially cost-competitive.

  20. An experimental study of tracers for labelling of injection gas in oil reservoirs

    International Nuclear Information System (INIS)

    Dugstad, Oe.

    1992-01-01

    This work demonstrates the feasibility of the PMCP and PMCH as tracers in field experiments. These compounds have properties which make them as well suited for well to well studies as the more common tracers CH 3 T and 85 Kr. In an injection project carried out at the Gullfaks field in the North Sea the two PFCs verified communication between wells. This implies communication between different geological layers in the reservoir and also communication across faults within the same layers. Laboratory studies carried out have focused on the retention of the tracers in dynamic flooding experiments under conditions comparable with those in the petroleum reservoirs. Simultaneous injection of a variety of tracers has shown individual variations in tracer retention which are caused by important reservoir parameters as fluid saturation and rock properties. By proper design of field injection programs the tracers response may therefore be used to estimate fluid saturation if actual rock properties are known. 45 refs., 20 figs., 13 tabs

  1. Characterization of shale gas enrichment in the Wufeng Formation–Longmaxi Formation in the Sichuan Basin of China and evaluation of its geological construction–transformation evolution sequence

    Directory of Open Access Journals (Sweden)

    Zhiliang He

    2017-02-01

    Full Text Available Shale gas in Upper Ordovician Wufeng Formation–Lower Silurian Longmaxi Formation in the Sichuan Basin is one of the key strata being explored and developed in China, where shale gas reservoirs have been found in Fuling, Weiyuan, Changning and Zhaotong. Characteristics of shale gas enrichment in the formation shown by detailed profiling and analysis are summarized as “high, handsome and rich”. “High” mainly refers to the high quality of original materials for the formation of shale with excellent key parameters, including the good type and high abundance of organic matters, high content of brittle minerals and moderate thermal evolution. “Handsome” means late and weak deformation, favorable deformation mode and structure, and appropriate uplift and current burial depth. “Rich” includes high gas content, high formation pressure coefficient, good reservoir property, favorable reservoir scale transformation and high initial and final output, with relative ease of development and obvious economic benefit. For shale gas enrichment and high yield, it is important that the combination of shale was deposited and formed in excellent conditions (geological construction, and then underwent appropriate tectonic deformation, uplift, and erosion (geological transformation. Evaluation based on geological construction (evolution sequence from formation to the reservoir includes sequence stratigraphy and sediment, hydrocarbon generation and formation of reservoir pores. Based on geological transformation (evolution sequence from the reservoir to preservation, the strata should be evaluated for structural deformation, the formation of reservoir fracture and preservation of shale gas. The evaluation of the “construction - transformation” sequence is to cover the whole process of shale gas formation and preservation. This way, both positive and negative effects of the formation-transformation sequence on shale gas are assessed. The evaluation

  2. Thermo-economic analysis of a solid oxide fuel cell and steam injected gas turbine plant integrated with woodchips gasification

    DEFF Research Database (Denmark)

    Mazzucco, Andrea; Rokni, Masoud

    2014-01-01

    cost on the generation cost is also presented. In order to discuss the investment cost, an economic analysis has been carried out and main parameters such as Net Present Value (NPV), internal rate of return (IRR) and Time of Return of Investment (TIR) are calculated and discussed.......This paper presents a thermo-economic analysis of an integrated biogas-fueled solid oxide fuel cell (SOFC) system for electric power generation. Basic plant layout consists of a gasification plant (GP), an SOFC and a retrofitted steam-injected gas turbine (STIG). Different system configurations...... and simulations are presented and investigated. A parallel analysis for simpler power plants, combining GP, SOFC, and hybrid gas turbine (GT) is carried out to obtain a reference point for thermodynamic results. Thermodynamic analysis shows energetic and exergetic efficiencies for optimized plant above 53% and 43...

  3. Emission Characteristics for a Homogeneous Charged Compression Ignition Diesel Engine with Exhaust Gas Recirculation Using Split Injection Methodology

    Directory of Open Access Journals (Sweden)

    Changhee Lee

    2017-12-01

    Full Text Available Due to the serious issues caused by air pollution and global warming, emission regulations are becoming stricter. New technologies that reduce NOx and PM emissions are needed. To cope with these social exhaust gas regulation demands, many advanced countries are striving to develop eco-friendly vehicles in order to respond to stricter emissions regulations. The homogeneous charged compression ignition engine (HCCI incorporates a multi-stage combustion engine with multiple combustion modes, catalyst, direct fuel injection and partial mixing combustion. In this study, the HCCI combustion was applied to analyze and review the results of engines applying HCCI combustion without altering the conventional engine specifications. The optimization of exhaust gas recirculation (EGR and compression ratio changes provides an optimal fuel economy. In this study, potential for optimum economy within the range of IMEP 0.8 MPa has been evaluated.

  4. Effect of advanced injection timing on the performence of natural gas ...

    Indian Academy of Sciences (India)

    Advanced injection timing; brake specific fuel consumption; brake thermal efficiency; exhaust temperatures; hydrocarbon emissions. Abstract. Concern over the environment and/or the increasing demand for conventional fossil fuel has promoted interest in the development of alternative sources of fuel energy for internal ...

  5. Capillary gas chromatographic analysis of nerve agents using large volume injections

    NARCIS (Netherlands)

    Degenhardt, C.E.A.M.; Kientz, C.E.

    1996-01-01

    The use of large volume injections has been studied for the verification of intact organophosphorus chemical warfare agents in water samples. As the use of ethyl acetate caused severe detection problems new potential solvents were evaluated. With the developed procedure, the nerve agents sarin,

  6. Diesel Engine with Different Kind of Injection Systems Exhaust Gas Analysis

    OpenAIRE

    Mantas Smolnikovas; Gintas Viselga; Greta Viselgaitė; Algirdas Jasinskas

    2016-01-01

    The article presents an overview of structural evolution of diesel engines’ injection systems, air pollution caused by diesel engines and permissible emission rates. An analytical research on air pollution was also performed. Experimental studies evaluated air pollution during the emission of particulate matter according to diesel engine exploitation time and different constructions emissions.

  7. Diesel Engine with Different Kind of Injection Systems Exhaust Gas Analysis

    Directory of Open Access Journals (Sweden)

    Mantas Smolnikovas

    2016-02-01

    Full Text Available The article presents an overview of structural evolution of diesel engines’ injection systems, air pollution caused by diesel engines and permissible emission rates. An analytical research on air pollution was also performed. Experimental studies evaluated air pollution during the emission of particulate matter according to diesel engine exploitation time and different constructions emissions.

  8. Development of a direct-injected natural gas engine system for heavy-duty vehicles: Final report phase 2

    Energy Technology Data Exchange (ETDEWEB)

    Cox, G.B.; DelVecchio, K.A.; Hays, W.J.; Hiltner, J.D.; Nagaraj, R.; Emmer, C.

    2000-03-02

    This report summarizes the results of Phase 2 of this contract. The authors completed four tasks under this phase of the subcontract. (1) They developed a computational fluid dynamics (CFD) model of a 3500 direct injected natural gas (DING) engine gas injection/combustion system and used it to identify DING ignition/combustion system improvements. The results were a 20% improvement in efficiency compared to Phase 1 testing. (2) The authors designed and procured the components for a 3126 DING engine (300 hp) and finished assembling it. During preliminary testing, the engine ran successfully at low loads for approximately 2 hours before injector tip and check failures terminated the test. The problems are solvable; however, this phase of the program was terminated. (3) They developed a Decision & Risk Analysis model to compare DING engine technology with various other engine technologies in a number of commercial applications. The model shows the most likely commercial applications for DING technology and can also be used to identify the sensitivity of variables that impact commercial viability. (4) MVE, Inc., completed a preliminary design concept study that examines the major design issues involved in making a reliable and durable 3,000 psi LNG pump. A primary concern is the life of pump seals and piston rings. Plans for the next phase of this program (Phase 3) have been put on indefinite hold. Caterpillar has decided not to fund further DING work at this time due to limited current market potential for the DING engine. However, based on results from this program, the authors believe that DI natural gas technology is viable for allowing a natural gas-fueled engine to achieve diesel power density and thermal efficiency for both the near and long terms.

  9. Parametric Simulation on Enhancement of the Regenerative Gas Turbine Performance by Effect of Inlet Air Cooling System and Steam Injection

    Directory of Open Access Journals (Sweden)

    Aadel A. Alkumait

    2016-02-01

    Full Text Available Aadel Abdulrazzaq Alkumait/Tikrit Journal of Engineering Sciences 22(1 (201538-44Iraq being one of the developing countries of the world considers energy efficiency and the impact of its generation on the environment an imperative process in improvement of its power generation policies. Iraq bearing high temperatures all year long results in reduction of air density, therefore, Inlet air Cooling and Steam Injection Gas Turbines are a striking addition to the regenerative gas turbines. Regenerating Gas turbines tend to have a high back work ratio and a high exhaust temperature, thus, it leads to a low efficiency in power generation in hotter climate. Moreover, STIG and IAC through fog cooling have known to be the best retrofitting methods available in the industry which improve the efficiency of generation from 30.5 to 43% and increase the power output from 22MW to 33.5MW as the outcomes of computer simulations reveal. Additionally, this happens without bringing about much extensive change to original features of the power generation cycle. Furthermore, STIG and spray coolers have also resulted in power boosting and exceeding generation efficiency of gas turbine power plant.

  10. In-Situ Measurements of Low Enrichment Uranium Holdup Process Gas Piping at K-25 - Paper for Waste Management Symposia 2010 East Tennessee Technology Park Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    Rasmussen, B.

    2010-01-01

    This document is the final version of a paper submitted to the Waste Management Symposia, Phoenix, 2010, abstract BJC/OR-3280. The primary document from which this paper was condensed is In-Situ Measurement of Low Enrichment Uranium Holdup in Process Gas Piping at K-25 Using NaI/HMS4 Gamma Detection Systems, BJC/OR-3355. This work explores the sufficiency and limitations of the Holdup Measurement System 4 (HJVIS4) software algorithms applied to measurements of low enriched uranium holdup in gaseous diffusion process gas piping. HMS4 has been used extensively during the decommissioning and demolition project of the K-25 building for U-235 holdup quantification. The HMS4 software is an integral part of one of the primary nondestructive assay (NDA) systems which was successfully tested and qualified for holdup deposit quantification in the process gas piping of the K-25 building. The initial qualification focused on the measurement of highly enriched UO 2 F 2 deposits. The purpose of this work was to determine if that qualification could be extended to include the quantification of holdup in UO 2 F 2 deposits of lower enrichment. Sample field data are presented to provide evidence in support of the theoretical foundation. The HMS4 algorithms were investigated in detail and found to sufficiently compensate for UO 2 F 2 source self-attenuation effects, over the range of expected enrichment (4-40%), in the North and East Wings of the K-25 building. The limitations of the HMS4 algorithms were explored for a described set of conditions with respect to area source measurements of low enriched UO 2 F 2 deposits when used in conjunction with a 1 inch by 1/2 inch sodium iodide (NaI) scintillation detector. The theoretical limitations of HMS4, based on the expected conditions in the process gas system of the K-25 building, are related back to the required data quality objectives (DQO) for the NBA measurement system established for the K-25 demolition project. The combined

  11. In-Situ Measurements of Low Enrichment Uranium Holdup Process Gas Piping at K-25 - Paper for Waste Management Symposia 2010 East Tennessee Technology Park Oak Ridge, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    Rasmussen B.

    2010-01-01

    This document is the final version of a paper submitted to the Waste Management Symposia, Phoenix, 2010, abstract BJC/OR-3280. The primary document from which this paper was condensed is In-Situ Measurement of Low Enrichment Uranium Holdup in Process Gas Piping at K-25 Using NaI/HMS4 Gamma Detection Systems, BJC/OR-3355. This work explores the sufficiency and limitations of the Holdup Measurement System 4 (HJVIS4) software algorithms applied to measurements of low enriched uranium holdup in gaseous diffusion process gas piping. HMS4 has been used extensively during the decommissioning and demolition project of the K-25 building for U-235 holdup quantification. The HMS4 software is an integral part of one of the primary nondestructive assay (NDA) systems which was successfully tested and qualified for holdup deposit quantification in the process gas piping of the K-25 building. The initial qualification focused on the measurement of highly enriched UO{sub 2}F{sub 2} deposits. The purpose of this work was to determine if that qualification could be extended to include the quantification of holdup in UO{sub 2}F{sub 2} deposits of lower enrichment. Sample field data are presented to provide evidence in support of the theoretical foundation. The HMS4 algorithms were investigated in detail and found to sufficiently compensate for UO{sub 2}F{sub 2} source self-attenuation effects, over the range of expected enrichment (4-40%), in the North and East Wings of the K-25 building. The limitations of the HMS4 algorithms were explored for a described set of conditions with respect to area source measurements of low enriched UO{sub 2}F{sub 2} deposits when used in conjunction with a 1 inch by 1/2 inch sodium iodide (NaI) scintillation detector. The theoretical limitations of HMS4, based on the expected conditions in the process gas system of the K-25 building, are related back to the required data quality objectives (DQO) for the NBA measurement system established for the K-25

  12. The injection of inert gas ions into solids: their trapping and escape

    International Nuclear Information System (INIS)

    Carter, G.; Armour, D.G.; Donnelly, S.E.; Ingram, D.C.; Webb, R.P.

    1980-01-01

    Basic information is required to understand fission gas generation and its consequence for swelling and embrittlement in fission reactors, for understanding and controlling first wall problems in fusion reactors and for attempting to design storage for active gas waste. In all of these areas the rare gas atoms are generated with kinetic energy and may thus interact differently, during their slowing down, with the solid than if they had been introduced more gently (e.g. via diffusion) into the solid. An important method of simulating the behaviour of such energetic rare gas atoms in solids is via external irradiation of the solid with rare gas ions of appropriate species and energies and it is the purpose of this review to evaluate studies of this nature. The review is divided into three parts. The first describes experimental techniques, discusses the results of measurements of how ions penetrate into and may be retained in a solid, and outlines theoretical interpretations of the data. The mechanisms of gas atom dissolution and thermal transport in solids are of profound importance and so, in the second part of this review, attention is devoted to how the technique of post-implantation thermal evolution spectrometry can be employed to attempt to understand some of these processes. Particular attention is paid to the difficulties of unique interpretation of evolution spectra. In the final section, consideration will be given to the processes which lead to the inevitable saturation of solids undergoing continued irradiation with rare gas ions and experimental measurements and their probable interpretation will be discussed. Since many materials are of importance in the context of this symposium, reference will be made to as broad a range of studies as possible. (author)

  13. Hot gas injection as an artificial lift system through a concentric tubing completion in a heavy oil well, Pilon field, Faja Petrolifera del Orinoco

    Energy Technology Data Exchange (ETDEWEB)

    Marfissi, S.; Lujan, A. [PDVSA EandP (Venezuela)

    2011-07-01

    The Pilon Field in the Morichal District, Venezuela is producing heavy oil with numerous gas lift wells. Some of these wells are now inactive due to casing damage. The purpose of this paper is to assess the benefits of using hot gas injection as an artificial lift system through a concentric tubing completion in such wells. A pilot test was conducted on a well presenting a low water cut and 12 degree API, an indirect fire heater was installed near the wells. Results showed that heat losses were minimized thanks to the concentric pipe completion. In addition hot gas injection resulted in an oil production increase of 57%. The hot gas injection method used with a concentric tubing completion was proved to be a good alternative to the use of diluent but an economic analysis is nevertheless recommended to determine the costs of installing heating equipment.

  14. Thermal conductivity of gas by pulse injection techniques using specific thermal conductivity detector (TCD)

    OpenAIRE

    Cataluña, Renato; Silva, Rosângela da; Menezes, Eliana W.; Samios, Dimitrios

    2004-01-01

    This paper presents a procedure to determine the thermal conductivity of gases by pulse injection, using a thermal conductivity detector (TCD). The measurements are taken at 323K and atmospheric pressure with a 160 omega tungsten filament sensor. Under well defined approximations the original nonlinear second order equation, which describes the sensors output, as a function of thermal conductivity and constant volume specific heat was transformed into a linear first order equation. According ...

  15. On-line liquid chromatography-gas chromatography: A novel approach for the analysis of phytosterol oxidation products in enriched foods.

    Science.gov (United States)

    Scholz, Birgit; Wocheslander, Stefan; Lander, Vera; Engel, Karl-Heinz

    2015-05-29

    A novel methodology for the automated qualitative and quantitative determination of phytosterol oxidation products in enriched foods via on-line liquid chromatography-gas chromatography (LC-GC) was established. The approach is based on the LC pre-separation of acetylated phytosterols and their corresponding oxides using silica as stationary phase and a mixture of n-hexane/methyl tert-butyl ether/isopropanol as eluent. Two LC-fractions containing (i) 5,6-epoxy- and 7-hydroxyphytosterols, and (ii) 7-ketophytosterols are transferred on-line to the GC for the analysis of their individual compositions on a medium polar trifluoropropylmethyl polysiloxane capillary column. Thus, conventionally employed laborious off-line purification and enrichment steps can be avoided. Validation data, including recovery, repeatability, and reproducibility of the method, were elaborated using an enriched margarine as example. The margarine was subjected to a heating procedure in order to exemplarily monitor the formation of phytosterol oxidation products. Quantification was performed using on-line LC-GC-FID, identification of the analytes was based on on-line LC-GC-MS. The developed approach offers a new possibility for the reliable and fast analysis of phytosterol oxidation products in enriched foods. Copyright © 2015 Elsevier B.V. All rights reserved.

  16. A Numerical Study of Gas Injection and Caprock Leakage from Yort-e-Shah Aquifer in Iran

    Directory of Open Access Journals (Sweden)

    H. S. Rad

    2017-08-01

    Full Text Available In order to mitigate the adverse effects of global warming due to anthropogenic CO2 emission into the atmosphere, geological sequestration of CO2 into subsurface formations has been investigated by many studies over the last decade. However, selection of formations and sites for any field application is still open to debate. The most important properties of a formation suitable for carbon sequestration are those which impact the fluid flow processes. The injection or extraction of gas can change the pore pressure within the reservoir, which in turn results in redistribution of the stress field. These events may cause considerably leakage of the fluid into the surrounding geological formations or ground surface. The main objective of this paper is to evaluate the potential of Yort-e-Shah aquifer for CO2 storage, through a series of analyses with a simplified numerical model. The numerical results suggest that the optimum injection pressure in Yort-e-Shah aquifer is about 15.51 MPa with a safety factor of about 1.7. The results of the fluid pressure and gas plume expansion are presented. Also, an analysis was carried out for a case with leak through cap rock. When there is no leak, the pressure within the aquifer is stable, while on the other hand, the pressure in case of leakage is slightly smaller. In case of leakage, the pressure is lowest in the middle of the reservoir, mainly because the nodes at the middle of the aquifer are influenced by all the leakage points, while around the wellbore or near the end of gas plume, are affected less due to their longer distance to leakage points.

  17. METHANE EMISSIONS FROM THE NATURAL GAS INDUSTRY VOLUME 13: CHEMICAL INJECTION PUMPS

    Science.gov (United States)

    The 15-volume report summarizes the results of a comprehensive program to quantify methane (CH4) emissions from the U.S. natural gas industry for the base year. The objective was to determine CH4 emissions from the wellhead and ending downstream at the customer's meter. The accur...

  18. Tomographic Imaging of Water Injection and Withdrawal in PEMFC Gas Diffusion Layers

    Energy Technology Data Exchange (ETDEWEB)

    McGill U; Gostick, J. T.; Gunterman, H. P.; Weber, A. Z.; Newman, J. S.; Kienitz, B. L.; MacDowell, A. A.

    2010-06-25

    X-ray computed tomography was used to visualize the water configurations inside gas diffusion layers for various applied capillary pressures, corresponding to both water invasion and withdrawal. A specialized sample holder was developed to allow capillary pressure control on the small-scale samples required. Tests were performed on GDL specimens with and without hydrophobic treatments.

  19. Cross-field diffusion quenching by neutral gas injection in a magnetized plasma

    International Nuclear Information System (INIS)

    Fasoli, A.; Skiff, F.; Good, T.N.; Paris, P.J.

    1991-12-01

    Cross-field transport of test ions is investigated in a linear Q-machine plasma. Test particles are created and followed in their motion by an optical tagging diagnostic scheme. Direct information on ion diffusivity is obtained from a comparison between the actual tag signal and a simple theoretical simulation. Diffusion is demonstrated to be supported by classical mechanisms. When different noble buffer gases are injected, the plasma reacts in such a way that the diffusivity remains classical but its magnitude is considerably reduced. (author) 9 figs., 15 refs

  20. Design and operation of a fast electromagnetic inductive massive gas injection valve for NSTX-U

    Science.gov (United States)

    Raman, R.; Jarboe, T. R.; Nelson, B. A.; Gerhardt, S. P.; Lay, W.-S.; Plunkett, G. J.

    2014-11-01

    Results from the operation of an electromagnetic valve, that does not incorporate ferromagnetic materials, are presented. Image currents induced on a conducting disc placed near a pancake solenoid cause it to move away from the solenoid and open the vacuum seal. A new and important design feature is the use of Lip Seals for the sliding piston. The pressure rise in the test chamber is measured directly using a fast time response Baratron gauge. The valve injects over 200 Torr l of nitrogen in less than 3 ms, which remains unchanged at moderate magnetic fields.

  1. Integrated gasification combined cycle and steam injection gas turbine powered by biomass joint-venture evaluation

    International Nuclear Information System (INIS)

    Sterzinger, G.J.

    1994-05-01

    This report analyzes the economic and environmental potential of biomass integrated gasifier/gas turbine technology including its market applications. The mature technology promises to produce electricity at $55--60/MWh and to be competitive for market applications conservatively estimated at 2000 MW. The report reviews the competitiveness of the technology of a stand-alone, mature basis and finds it to be substantial and recognized by DOE, EPRI, and the World Bank Global Environmental Facility

  2. Effect of Orifice Diameter on Bubble Generation Process in Melt Gas Injection to Prepare Aluminum Foams

    Science.gov (United States)

    Yuan, Jianyu; Li, Yanxiang; Wang, Ningzhen; Cheng, Ying; Chen, Xiang

    2016-06-01

    The bubble generation process in conditioned A356 alloy melt through submerged spiry orifices with a wide diameter range (from 0.07 to 1.0 mm) is investigated in order to prepare aluminum foams with fine pores. The gas flow rate and chamber pressure relationship for each orifice is first determined when blowing gas in atmospheric environment. The effects of chamber pressure ( P c) and orifice diameter ( D o) on bubble size are then analyzed separately when blowing gas in melt. A three-dimensional fitting curve is obtained illustrating both the influences of orifice diameter and chamber pressure on bubble size based on the experimental data. It is found that the bubble size has a V-shaped relationship with orifice diameter and chamber pressure neighboring the optimized parameter ( D o = 0.25 mm, P c = 0.4 MPa). The bubble generation mechanism is proposed based on the Rayleigh-Plesset equation. It is found that the bubbles will not be generated until a threshold pressure difference is reached. The threshold pressure difference is dependent on the orifice diameter, which determines the time span of pre-formation stage and bubble growth stage.

  3. Comparative study of the influence of the gas injection system on the Nd:yttrium-aluminum-garnet laser cutting of advanced oxide ceramics

    International Nuclear Information System (INIS)

    Quintero, F.; Pou, J.; Lusquinos, F.; Boutinguiza, M.; Soto, R.; Perez-Amor, M.

    2003-01-01

    Cutting of advanced oxide ceramics is still a difficult task. In this work, the possibility to effectively cut them using a Nd:YAG laser guided by an optical fiber is demonstrated. The key points are the aerodynamic interactions of the assist gas jet in the fusion laser cutting of ceramics. A comprehensive study of the influence of these aerodynamic interactions on the laser cutting of advanced oxide ceramics has been carried out. The characteristics of the heat affected zone (HAZ) were studied related to the efficiency of the assist gas to eject the molten material. It has been demonstrated that the HAZ can be avoided with a suitable design of the gas injection system combined with an appropriate selection of the values of the processing parameters. With the aim of improving the efficiency of the assist gas injection system, a new cutting head with an off-axis supersonic nozzle was developed. Furthermore, a comparison between the utilization of a conventional coaxial conical nozzle to inject the assist gas and the new system is presented. The results obtained give clear proof that the use of the new gas injection system leads to a great improvement on the cut quality by means of a more efficient removing of the molten material out of the cutting front. This result is of special interest in the laser fusion cutting of thick ceramic plates at high processing rates

  4. Bioanalysis of the enantiomers of (+/-)-sarin using automated thermal cold-trap injection combined with two-dimensional gas chromatography.

    Science.gov (United States)

    Spruit, H E; Trap, H C; Langenberg, J P; Benschop, H P

    2001-01-01

    A fully automated multidimensional gas chromatographic system with thermal desorption injection and alkali flame detection was developed for analysis of the enantiomers of the nerve agent (+/-)-sarin. The chiral stationary phase was CP Cyclodex B on which the sarin enantiomers were completely resolved. The absolute detection limit was 2.5 pg per enantiomer. The method is intended to be used for the analysis of the sarin enantiomers in biological samples. For this purpose, sarin was isolated from guinea pig blood via solid-phase extraction. Deuterated sarin was used as internal standard. Stabilization of sarin in the blood sample by acidification and addition of an excess of a competitive organophosphorus compound (neopentyl sarin) appeared to be essential. The absolute recovery of the extraction procedure was 60%, whereas the recovery relative to the internal standard was 100%.

  5. Heat transfer characteristics around a single heated rod immersed in sodium pool with gas jet injection

    International Nuclear Information System (INIS)

    Hideto Niikura; Kazuo Soga; Ken-ichiro Sugiyama; Akira Yamaguchi

    2005-01-01

    In a steam generator using liquid sodium, water intensely reacts with sodium when it leaks out from a heat transfer tube. It is important to evaluate the influence of sodium-water reaction to surrounding tubes and the shell. Hence, it has been desired to develop the simulation code for the evaluation of sodium-water reaction. From this viewpoint, the Japan Nuclear Cycle is now developing the SERAPHIM code. We reported a preliminary study to establish an experimental method for a single heated rod immersed in sodium pool with steam jet impingement planned in the near future as well as to obtain a preliminary data to verify the adequacy of SERAPHIM code. We first measured local and mean heat transfer coefficients around a horizontal single heated rod immersed in a water pool and a sodium pool with a limited volume in the experimental apparatus. It was confirmed that the mean heat transfer coefficients fairly agreed with the existing data for natural convection in water and sodium. Secondary we measured local and mean heat transfer coefficients around a horizontal single heated rod with Ar gas jet impingement immersed in the limited water pool and in the limited sodium pool. It was clearly observed that the local heat transfer coefficients in the sodium pool keep almost the same values in every angle regardless of increase in Ar gas jet velocity varied from about 8.7m/s to about 78m/s. On the other hand, it was confirmed in the water pool that local heat transfer coefficients on the forward stagnation side exposed in the Ar gas jet impingement increase with increasing the jet velocity while the local heat transfer coefficients on the opposite surface keep almost same values regardless of increase in the velocity. (authors)

  6. Fast gas chromatographic residue analysis in animal feed using split injection and atmospheric pressure chemical ionisation tandem mass spectrometry.

    Science.gov (United States)

    Tienstra, M; Portolés, T; Hernández, F; Mol, J G J

    2015-11-27

    Significant speed improvement for instrumental runtime would make GC–MS much more attractive for determination of pesticides and contaminants and as complementary technique to LC–MS. This was the trigger to develop a fast method (time between injections less than 10 min) for the determination of pesticides and PCBs that are not (or less) amenable to LC–MS. A key factor in achieving shorter analysis time was the use of split injection (1:10) which allowed the use of a much higher initial GC oven temperature. A shorter column (15 m), higher temperature ramp, and higher carrier gas flow rate (6 mL/min) further contributed to analysis-time reduction. Chromatographic resolution was slightly compromised but still well fit-for-purpose. Due to the high sensitivity of the technique used (GC–APCI-triple quadrupole MS/MS), quantification and identification were still possible down to the 10 μg/kg level, which was demonstrated by successful validation of the method for complex feed matrices according to EU guidelines. Other advantages of the method included a better compatibility of acetonitrile extracts (e.g. QuEChERS) with GC, and a reduced transfer of co-extractants into the GC column and mass spectrometer.

  7. Gas-Assisted Heating Technology for High Aspect Ratio Microstructure Injection Molding

    Directory of Open Access Journals (Sweden)

    Shia-Chung Chen

    2013-01-01

    Full Text Available A hot gas is used for heating the cavity surface of a mold. Different mold gap sizes were designed. The mold surface temperature was heated to above the glass transition temperature of the plastic material, and the mold then closed for melt filling. The cavity surface can be heated to 130°C to assist the melt filling of the microfeatures. Results show that hot gas heating can improve the filling process and achieve 91% of the high aspect ratio microgrooves (about 640.38 μm of the maximum of 700 μm. The mold gap size strongly affects the heating speed and heating uniformity. Without surface preheating, the center rib is the highest. When the heating target temperature is 90°C or 100°C, the three microribs have a good uniformity of height. However, when the target temperature exceeds 100°C, the left side rib is higher than the other ribs.

  8. 10 CFR Appendix B to Part 110 - Illustrative List of Gas Centrifuge Enrichment Plant Components Under NRC's Export Licensing...

    Science.gov (United States)

    2010-01-01

    ... the centrifuges or to control the plant. Normally UF6 is evaporated from the solid using heated... disc-shaped baffle(s) and a stationary tube arrangement for feeding and extracting UF6 gas and... main separation chamber and, in some cases, to assist the UF6 gas circulation within the main...

  9. Large volume cold on-column injection for gas chromatography-negative chemical ionization-mass spectrometry analysis of selected pesticides in air samples.

    Science.gov (United States)

    Bailey, Renata; Belzer, Wayne

    2007-02-21

    A new gas chromatographic method is described for the analysis of fungicides captan, captafol, and folpet from organic extracts of air samples using large volume injection (LVI) via a cold on-column (COC) inlet coupled with gas chromatography-negative chemical ionization-mass spectrometry (GC-NCI-MS). Although standard split/splitless injection due to high injection port temperatures (>225 degrees C) have been shown to degrade these thermally labile fungicides, COC injection minimizes degradation. Insecticides such as chlorpyrifos and diazinon were also examined to show added selectivity. By using a solvent vapor exit with the COC inlet, injection volumes of 10-100 microL can be made to lower detection levels. GC-NCI-MS was compared to GC-electron impact ionization-mass spectrometry for each pesticide using LVI-COC injections and was found to be 2-80 times more sensitive, depending on the pesticide. Method detection limit (MDL) values with 100 microL injections were 2.5 microg L-1 for captan, folpet, and diazinon, 5.0 microg L-1 captafol, and 1.0 microg L-1 for chlorpyrifos, with the normal working range examined for sample analysis from MDL to 100 microg L-1. Detection of all pesticides except captafol, used only in the United States but not Canada, was demonstrated from air samples taken from Abbotsford, British Columbia, Canada.

  10. Oxygen enrichment incineration

    International Nuclear Information System (INIS)

    Kim, Jeong Guk; Yang, Hee Chul; Park, Geun Il; Kim, Joon Hyung

    2000-10-01

    Oxygen enriched combustion technology has recently been used in waste incineration. To apply the oxygen enrichment on alpha-bearing waste incineration, which is being developed, a state-of-an-art review has been performed. The use of oxygen or oxygen-enriched air instead of air in incineration would result in increase of combustion efficiency and capacity, and reduction of off-gas product. Especially, the off-gas could be reduced below a quarter, which might reduce off-gas treatment facilities, and also increase an efficiency of off-gas treatment. However, the use of oxygen might also lead to local overheating and high nitrogen oxides (NOx) formation. To overcome these problems, an application of low NOx oxy-fuel burner and recycling of a part of off-gas to combustion chamber have been suggested

  11. Oxygen enrichment incineration

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jeong Guk; Yang, Hee Chul; Park, Geun Il; Kim, Joon Hyung

    2000-10-01

    Oxygen enriched combustion technology has recently been used in waste incineration. To apply the oxygen enrichment on alpha-bearing waste incineration, which is being developed, a state-of-an-art review has been performed. The use of oxygen or oxygen-enriched air instead of air in incineration would result in increase of combustion efficiency and capacity, and reduction of off-gas product. Especially, the off-gas could be reduced below a quarter, which might reduce off-gas treatment facilities, and also increase an efficiency of off-gas treatment. However, the use of oxygen might also lead to local overheating and high nitrogen oxides (NOx) formation. To overcome these problems, an application of low NOx oxy-fuel burner and recycling of a part of off-gas to combustion chamber have been suggested.

  12. Catalytic combustion of the retentate gas from a CO2/H2 separation membrane reactor for further CO2 enrichment and energy recovery

    International Nuclear Information System (INIS)

    Hwang, Kyung-Ran; Park, Jin-Woo; Lee, Sung-Wook; Hong, Sungkook; Lee, Chun-Boo; Oh, Duck-Kyu; Jin, Min-Ho; Lee, Dong-Wook; Park, Jong-Soo

    2015-01-01

    The CCR (catalytic combustion reaction) of the retentate gas, consisting of 90% CO 2 and 10% H 2 obtained from a CO 2 /H 2 separation membrane reactor, was investigated using a porous Ni metal catalyst in order to recover energy and further enrich CO 2 . A disc-shaped porous Ni metal catalyst, namely Al[0.1]/Ni, was prepared by a simple method and a compact MCR (micro-channel reactor) equipped with a catalyst plate was designed for the CCR. CO 2 and H 2 concentrations of 98.68% and 0.46%, respectively, were achieved at an operating temperature of 400 °C, GHSV (gas-hourly space velocity) of 50,000 h −1 and a H 2 /O 2 ratio (R/O) of 2 in the unit module. In the case of the MCR, a sheet of the Ni metal catalyst was easily installed along with the other metal plates and the concentration of CO 2 in the retentate gas increased up to 96.7%. The differences in temperatures measured before and after the CCR were 31 °C at the product outlet and 19 °C at the N 2 outlet in the MCR. The disc-shaped porous metal catalyst and MCR configuration used in this study exhibit potential advantages, such as high thermal transfer resulting in improved energy recovery rate, simple catalyst preparation, and easy installation of the catalyst in the MCR. - Highlights: • The catalytic combustion of a retentate gas obtained from the H 2 /CO 2 separation membrane. • A disc-shaped porous nickel metal catalyst and a micro-channel reactor for catalytic hydrogen combustion. • CO 2 enrichment up to 98.68% at 400 °C, 50,000 h −1 and H 2 /O 2 ratio of 2.

  13. Experimental study of unsteady heat release in an unstable single element Lean Direct Injection (LDI) gas turbine combustor

    Science.gov (United States)

    Lakshmanan, Varun S.

    In an effort to curb emissions from gas turbine engines, many low emission engine concepts have been developed. Among the most promising of these is the LDI (Lean Direct Injection). These systems operate at relatively low equivalence ratios close to blowout and are prone to instabilities. Combustion instabilities can reduce the life of the combustor by causing large pressure fluctuations and enhanced heat release to the walls of the combustor and reduce the efficiency of the engines. The understanding of combustion instabilities is vital to the implementation of such systems. Combustion instabilities are studied in an self-excited single element gas turbine combustor that uses an LDI element for fuel injection at elevetaed chamber pressures. The LDI combustor uses a swirler to ensure mixing of the air and the fuel and expansion of the swirl through a pressure swirl venturi to create a swirl stabilized flame. This project aims to study the heat release modes that occur in the combustor through measurement of light emissions from the flame using photodiodes that are sensitive to wavelengths of light produced by the flame. These are used along with high frequency pressure transducers. The focus is on the flame behavior in the diverging section of the venturi where the swirl is expanded and the flame starts since optic access cannot be obtained in this section. The use of photodiodes also facilitates the study of hydrodynamic modes that occur in the combustor alongside the thermoacoustics. A section which could accommodate the photodiodes was designed and installed on the LDI test rig in the Gas Turbine Cell at Maurice J Zucrow Propulsion Labs at Purdue University. The combustor was tested with this section and dynamic data was obtained from the pressure transducers and the photodiodes for a range of inlet air temperatures and range of equivalence ratios for each inlet air temperature. The dominant instability modes in both sets of data were analyzed and are presented

  14. Enrichment of radon and carbon dioxide in the open atmosphere of an Australian coal seam gas field.

    Science.gov (United States)

    Tait, Douglas R; Santos, Isaac R; Maher, Damien T; Cyronak, Tyler J; Davis, Rachael J

    2013-04-02

    Atmospheric radon ((222)Rn) and carbon dioxide (CO2) concentrations were used to gain insight into fugitive emissions in an Australian coal seam gas (CSG) field (Surat Basin, Tara region, Queensland). (222)Rn and CO2 concentrations were observed for 24 h within and outside the gas field. Both (222)Rn and CO2 concentrations followed a diurnal cycle with night time concentrations higher than day time concentrations. Average CO2 concentrations over the 24-h period ranged from ~390 ppm at the control site to ~467 ppm near the center of the gas field. A ~3 fold increase in maximum (222)Rn concentration was observed inside the gas field compared to outside of it. There was a significant relationship between maximum and average (222)Rn concentrations and the number of gas wells within a 3 km radius of the sampling sites (n = 5 stations; p gas field related to both point (well heads, pipelines, etc.) and diffuse soil sources. Radon may be useful in monitoring enhanced soil gas fluxes to the atmosphere due to changes in the geological structure associated with wells and hydraulic fracturing in CSG fields.

  15. Effect of Exhaust Gas Recirculation (EGR on the Performance Characteristics of a Direct Injection Multi Cylinders Diesel Engine

    Directory of Open Access Journals (Sweden)

    Khalil Ibrahim Abaas

    2016-07-01

    Full Text Available Owing  to  the  energy  crisis  and  pollution  problems  of  today  investigations  have  concentrated  on decreasing  fuel  consumption  and  on  lowering  the  concentration  of  toxic  components  in  combustion products by using exhaust gas after treatments methods like PM filters and EGR for NOx reduction. In this study, the combustion characteristics of diesel fuel were compared with that pr oduced from adding EGR at several percentages to air manifold. The tests were performed in a four-cylinder direct injection (DI diesel engine at constant engine speed (1500 rpm and variable loads (from no load to 86 kN/m2, the tests were repeated with constant load (77 kN/m2 and variable engine speeds (from 1250 to 3000 rpm.The experimental results showed that adding EGR to diesel engine provided significant reductions in brake power (bp, brake thermal efficiency and exhaust gas temperatures, while high increments in brake specific  fuel  consumption  (bsfc.  High  EGR  percentage  (as  30%  in  this  article  caused  an  11.7% reduction  in  brake  thermal  efficiency,  26.38%  reduction  in  exhaust  gas  temperatures  and  12.28%  in volumetric efficiency at full load conditions.

  16. Generating usable and safe CO{sub 2} for enrichment of greenhouses from the exhaust gas of a biomass heating system

    Energy Technology Data Exchange (ETDEWEB)

    Dion, L.M.; Lefsrud, M. [McGill Univ., Macdonald Campus, Ste-Anne-deBellevue, PQ (Canada). Dept. of Bioresource Engineering

    2010-07-01

    This study demonstrated the use of biomass as a renewable fuel to enrich a greenhouse with carbon dioxide (CO{sub 2}). CO{sub 2} enrichment of greenhouses has been shown to improve crop production whether it occurs from liquid CO{sub 2} or combustion of fossil fuels. Biomass, in the form of wood chips or pellets, has received much interest as a sustainable and economically viable alternative to heat greenhouses. As such, the opportunity exists to convert exhaust gases from a greenhouse wood heating system into a useful resource. CO{sub 2} can be extracted from flue gas via membrane separation instead of electrostatic precipitators. This technique has shown potential for large industries trying to reduce and isolate CO{sub 2} emissions for sequestration and may be applicable to the greenhouse industry. Some research has also been done with wet scrubbers using catalysts to obtain plant fertilizers. Sulphur dioxide (SO{sub 2}) and nitrogen (NO) emissions can be stripped from flue gas to form ammonium sulphate as a valuable byproduct for fertilizer markets. This study will review the potential of these techniques in the summer of 2010 when experiments will be conducted at the Macdonald Campus of McGill University.

  17. Enhancement of Leaf Gas Exchange and Primary Metabolites under Carbon Dioxide Enrichment Up-Regulates the Production of Secondary Metabolites in Labisia pumila Seedlings

    Directory of Open Access Journals (Sweden)

    Mohd Hafiz Ibrahim

    2011-05-01

    Full Text Available A split plot 3 by 3 experiment was designed to investigate and distinguish the relationships among production of primary metabolites (soluble sugar and starch, secondary metabolites (total phenolics, TP; total flavonoids, TF and leaf gas exchange of three varieties of the Malaysian medicinal herb Labisia pumila Blume, namely the varieties alata, pumila and lanceolata, under three levels of CO2 enrichment (400, 800 and 1,200 µmol mol−1 for 15 weeks. The treatment effects were solely contributed by CO2 enrichment levels; no varietal differences were observed. As CO2 levels increased from 400 to 1,200 µmol mol−1, the production of carbohydrates also increased steadily, especially for starch more than soluble sugar (sucrose. TF and TP content, simultaneously, reached their peaks under 1,200 µmol exposure, followed by 800 and 400 µmol mol−1. Net photosynthesis (A and quantum efficiency of photosystem II (fv/fm were also enhanced as CO2 increased from 400 to 1,200 µmol mol−1. Leaf gas exchange characteristics displayed a significant positive relationship with the production of secondary metabolites and carbohydrate contents. The increase in production of TP and TFs were manifested by high C/N ratio and low protein content in L. pumila seedlings, and accompanied by reduction in cholorophyll content that exhibited very significant negative relationships with total soluble sugar, starch and total non structural carbohydrate.

  18. Lean burn versus stoichiometric operation with EGR and 3-way catalyst of an engine fueled with natural gas and hydrogen enriched natural gas

    OpenAIRE

    Saanum, Inge; Bysveen, Marie; Tunestål, Per; Johansson, Bengt

    2007-01-01

    Engine tests have been performed on a 9.6 liter spark-ignited engine fueled by natural gas and a mixture of 25/75 hydrogen/natural gas by volume. The scope of the work was to test two strategies for low emissions of harmful gases; lean burn operation and stoichiometric operation with EGR and a three-way catalyst. Most gas engines today, used in city buses, utilize the lean burn approach to achieve low NOx formation and high thermal efficiency. However, the lean burn appro...

  19. Layered storage of biogenic methane-enriched gas bubbles in peat: A lumped capacitance model controlled by soil structure

    Science.gov (United States)

    Chen, X.; Comas, X.; Binley, A. M.; Slater, L. D.

    2017-12-01

    Methane can accumulate in the gaseous phase in peats, and enter the atmosphere as gas bubbles with a mass flux higher than that via diffusion and plant-mediated pathways. A complete understanding of the mechanisms regulating bubble storage in peats remains incomplete. We developed a layered model to quantify the storage of gas bubbles over a peat column based on a general lumped capacitance model. This conceptual model was applied to explain the effects of peat structure on bubble storage at different depths observed in a laboratory experiment. A peat monolith was collected from the Everglades, a subtropical wetland located in Florida (USA), and kept submerged in a cuboid chamber over 102 days until gas bubble saturation was achieved. Time-lapse ground-penetrating radar (GPR) was used to estimate changes in gas content of each layer and the corresponding average dimensions of stored gas bubbles. The results highlight a hotspot layer of bubble accumulation at depths between 5 and 10 cm below the monolith surface. Bubbles in this shallow hotspot layer were larger relative to those in deeper layers, whilst the degree of decomposition of the upper layers was generally smaller than that of the lower layers based on von Post humification tests. X-ray Computer tomography (CT) was applied to resin-impregnated peat sections from different depths and the results showed that a higher porosity promotes bubbles storage. The stored gas bubbles were released by changing water levels and the air CH4 concentrations above the peat monolith were measured using a flow-through chamber system to confirm the high CH4 concentration in the stored bubbles. Our findings suggest that bubble capacitance is related to the difference in size between gas bubbles and peat pores. This work has implications for better understanding how changes in water table elevation associated with climate change and sea level rise (particularly for freshwater wetlands near coastal areas like the Everglades) may

  20. Understanding the interaction of injected CO2 and reservoir fluids in the Cranfield enhanced oil recovery (EOR) field (MS, USA) by non-radiogenic noble gas isotopes

    Science.gov (United States)

    Gyore, Domokos; Stuart, Finlay; Gilfillan, Stuart

    2016-04-01

    Identifying the mechanism by which the injected CO2 is stored in underground reservoirs is a key challenge for carbon sequestration. Developing tracing tools that are universally deployable will increase confidence that CO2 remains safely stored. CO2 has been injected into the Cranfield enhanced oil recovery (EOR) field (MS, USA) since 2008 and significant amount of CO2 has remained (stored) in the reservoir. Noble gases (He, Ne, Ar, Kr, Xe) are present as minor natural components in the injected CO2. He, Ne and Ar previously have been shown to be powerful tracers of the CO2 injected in the field (Györe et al., 2015). It also has been implied that interaction with the formation water might have been responsible for the observed CO2 loss. Here we will present work, which examines the role of reservoir fluids as a CO2 sink by examining non-radiogenic noble gas isotopes (20Ne, 36Ar, 84Kr, 132Xe). Gas samples from injection and production wells were taken 18 and 45 months after the start of injection. We will show that the fractionation of noble gases relative to Ar is consistent with the different degrees of CO2 - fluid interaction in the individual samples. The early injection samples indicate that the CO2 injected is in contact with the formation water. The spatial distribution of the data reveal significant heterogeneity in the reservoir with some wells exhibiting a relatively free flow path, where little formation water is contacted. Significantly, in the samples, where CO2 loss has been previously identified show active and ongoing contact. Data from the later stage of the injection shows that the CO2 - oil interaction has became more important than the CO2 - formation water interaction in controlling the noble gas fingerprint. This potentially provides a means to estimate the oil displacement efficiency. This dataset is a demonstration that noble gases can resolve CO2 storage mechanisms and its interaction with the reservoir fluids with high resolution

  1. Evaluation of enrichment by centrifugal separation: the future of the centrifugal-separation method

    International Nuclear Information System (INIS)

    Kanagawa, A.

    A gas centrifuge plant for uranium enrichment is considered from the point of view of economic competition with other methods. Characteristics of the method are presented including: energy efficiency, the cascade, the separation coefficient, the equilibrium separation process, and capability as centrifugal pump. The structure of an individual gas centrifuge separator is described including the rotating cylinder, mechanisms for gas injection and extraction, mechanisms for counter-streaming of gas, the axle holder mechanism, the gas sealing mechanism, and the driving mechanism. (U.S.)

  2. Effect of Gas- and Liquid-injection Methods on Formation of Bubble and Liquid Slug at Merging Micro T-junction

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jun Kyoung [Kyungnam Univ., Changwon (Korea, Republic of); Lee, Chi Young [Pukyong Nat’l Univ., Busan (Korea, Republic of)

    2016-04-15

    In the present experimental study, the effect of gas- and liquid-injected methods on the formation of bubble and liquid slug at the merging micro T-junction of a square microchannel with dimensions 600 μm × 600 μm was investigated. Nitrogen and water were used as test fluids. The superficial velocities of the liquid and gas were in the range of 0.05 - 1 m/s, and 0.1 - 1 m/s, respectively, where the Taylor flow was observed. The bubble length, liquid slug length, bubble velocity, and bubble generation frequency were measured by analyzing the images captured using a high-speed camera. Under similar inlet superficial velocity conditions, in the case of gas injection to the main channel at the merging T-junction (T{sub g}as-liquid), the lengths of the bubble and liquid slug were longer, and the bubble generation frequency was lower than in the case of liquid injection to the main channel at the merging T-junction (T{sub l}iquid-gas). On the other hand, in both cases, the bubble velocity was almost the same. The previous correlation proposed using experimental data for T{sub l}iquid-gas had predicted the present experimental data of bubble length, bubble velocity, liquid slug length, and bubble generation frequency for T{sub g}as-liquid to be ~24%, ~9%, ~39%, ~55%, respectively.

  3. Health risk assessment based on injection of upgraded biogas in natural gas grid; Evaluation des risques sanitaires et accidentels lies a l'injection de biogaz epure dans un reseau de gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Leroux, C.; Modelon, H.; Rousselle, C. [AFSSET, 94 - Maisons Alfort (France); Zdanevitch, I.; Evanno, S. [INERIS, 60 - Verneuil en Halatte (France)

    2010-07-01

    This document presents the opinion of the French Agency for Environmental and Occupational Health Safety (AFSSET). Results are based on a collective expertise conducted to assess health risks associated with the injection of biogas in the natural gas grid. The complete assessment is published and available on the web site of the Agency; only the major results are presented in this document. Following recommendations issued by AFSSET in 2008, a new study has been initiated to collect and analyze data on the composition of biogas from sewage sludge. The French National Institute for Industrial Environment and Risks (INERIS) is in charge of this project. The data will be used to assess the accidental risks (resulting from the upgrading of biogas, transport by pipeline and utilization for energy purposes) and health risks for users (resulting from the injection in the natural gas grid). (authors)

  4. Life cycle assessment of biogas production by monofermentation of energy crops and injection into the natural gas grid

    International Nuclear Information System (INIS)

    Jury, Colin; Benetto, Enrico; Koster, Daniel; Schmitt, Bianca; Welfring, Joelle

    2010-01-01

    The use of renewable energy is a possible solution to reduce the contribution to climate change of human activities. Nevertheless, there is much controversy about the non-climate related environmental impacts of renewable energy as compared to fossil energy. The aim of this study is to assess a new technology of biomethane production by monofermentation of cultivated crops. Based on the results of an attributional Life Cycle Assessment (LCA), the contribution to climate change of biomethane production and injection into the grid is 30-40% (500a time horizon) or 10-20% (100a) lower than the contribution of natural gas importation. The reduction depends mainly on the biogas yield, the amount of readily available nitrogen in the digestate and the type of agricultural practices. Nevertheless, the natural gas definitively generates far lower ecosystem quality and human health damages than the biomethane production. Farming activities have the most important contribution to the damages mainly because of land occupation and the use of fertilizer. The main improvement opportunities highlighted are: the increase of biogas yield, the choice of good agricultural practices and the cultivation of winter or summer crops exclusively. Future research should include the emission and sequestration of CO 2 from soil. The ripple effects related to the total increase of farming area and the consequences of farming activities on the food production chain should be addressed as well. To this aim, the switch to consequential LCA is a critical challenge, from both the methodological and application point of view, to support decision-making. (author)

  5. Health risks associated with biogas. Assessment of health risks related to the injection of biogas into the natural gas network. Affset opinion. Collective expertise report. Final version

    International Nuclear Information System (INIS)

    JAEG, Jean-Philippe; Bajeat, Philippe; Wenisch, Sandrine; Bellenfant, Gael; Godon, Jean-Jacques; Keck, Gerard; Lattes, Armand; Moletta-Denat, Marina; Naja, Ghinwa; Ramalho, Olivier; Zdanevitch, Isabelle; ALARY, Rene; RAMEL, Martine

    2008-10-01

    This publication reports a study which aimed at acquiring and analysing available bibliographical data regarding risks associated with the exposure to toxic compounds in relationship with the injection of biogas into the natural gas network, at characterising biogas composition and notably their content in potentially toxic compounds with respect to the currently distributed natural gas, at assessing health risks related to the exposure to toxic agents before and after combustion, also with respect to the currently distributed natural gas, and, based on this risk assessment, at determining biogas composition characteristics. Thus, after a presentation of the context, scope and modalities of this study, the report proposes an overview of various contextual aspects related to biogas (interest, production means, purification processes, valorisation, injection processes), the report discusses chemical risks related to biogas: bibliographical study, biogas chemical composition, chemical composition of biogas combustion residues. It also discusses microbiological risks. Several appendices are provided

  6. Evaluation of volatile compounds in different types of ghee using direct injection with gas chromatography-mass spectrometry.

    Science.gov (United States)

    Wadodkar, Uday R; Punjrath, Jagjit S; Shah, Amrish C

    2002-02-01

    Desi ghee (DG) was prepared from fermented cream followed by heat clarification (desi method) in the laboratory and butter oil (BO) was prepared from fresh butter by melting and centrifugation. Fresh samples of three brands of industrial ghee (IG-1, IG-2, IG-3) were collected from the local market. Volatile compounds of desi and industrial ghee and butter oil were isolated and concentrated using direct injection and cryofocussing techniques; separation and identification was by Gas Chromatography Mass Spectrometry (GCMS). A maximum of 36 compounds were detected in desi ghee whereas compounds detected in three industrial ghee samples varied from 22-29. The lowest number of compounds (16) was detected in butter oil. Of the identified compounds, maltol, 5-hydroxymethyl furfuraldehyde, dihydrodihydroxypyranone, 1,3-butanediol and 1-octanol were identified only in desi ghee volatiles. The concentration of acetic acid was found to be remarkably higher in desi ghee volatiles than in industrial ghee. Also the levels of identified fatty acids, methyl ketones, aldehydes, lactones and alcohols were high in desi ghee volatiles compared with industrial ghee and butter oil. In total, 62 compounds were detected, which included 6 aldehydes, 12 ketones, 8 each of fatty acids, alcohols and lactones, 4 each of esters and hydrocarbons or other compounds, and 12 compounds remained unidentified.

  7. Spectrophotometric flow-injection determination of sulphite in white wines involving gas diffusion through a concentric tubular membrane

    Directory of Open Access Journals (Sweden)

    Melo Denise

    2003-01-01

    Full Text Available A flow-injection system is proposed for the spectrophotometric determination of sulphite in white wines. The method involves analyte conversion to SO2, gas diffusion through a Teflon® semi-permeable membrane, collection into an alkaline stream (pH 8, reaction with Malachite green (MG and monitoring at 620 nm. With a concentric tubular membrane, the system design was simplified. Influence of reagent concentrations, pH of donor and acceptor streams, temperature, timing, surfactant addition and presence of potential interfering species of the wine matrix were investigated. A pronounced (ca. 100% enhancement in sensitivity was noted by adding cetylpyridinium chloride (CPC. The proposed system is robust and baseline drift is not observed during 4 h operating periods. Only 400 muL of sample and 0.32 mg MG are required per determination. The system handles 30 samples per hour, yielding precise results (r.s.d. < 0.015 for 1.0 - 20.0 mg L-1 SO2 in agreement with those obtained by an alternative procedure.

  8. Uranium enrichment in the United States

    International Nuclear Information System (INIS)

    Hill, J.H.; Parks, J.W.

    1975-01-01

    History, improvement programs, status of electrical power availability, demands for uranium enrichment, operating plan for the U. S. enriching facilities, working inventory of enriched uranium, possible factors affecting deviations in the operating plan, status of gaseous diffusion technology, status of U. S. gas centrifuge advances, transfer of enrichment technology, gaseous diffusion--gas centrifuge comparison, new enrichment capacity, U. S. separative work pricing, and investment in nuclear energy are discussed. (LK)

  9. Power plant including an exhaust gas recirculation system for injecting recirculated exhaust gases in the fuel and compressed air of a gas turbine engine

    Science.gov (United States)

    Anand, Ashok Kumar; Nagarjuna Reddy, Thirumala Reddy; Shaffer, Jason Brian; York, William David

    2014-05-13

    A power plant is provided and includes a gas turbine engine having a combustor in which compressed gas and fuel are mixed and combusted, first and second supply lines respectively coupled to the combustor and respectively configured to supply the compressed gas and the fuel to the combustor and an exhaust gas recirculation (EGR) system to re-circulate exhaust gas produced by the gas turbine engine toward the combustor. The EGR system is coupled to the first and second supply lines and configured to combine first and second portions of the re-circulated exhaust gas with the compressed gas and the fuel at the first and second supply lines, respectively.

  10. Determination of plant stanols and plant sterols in phytosterol enriched foods with a gas chromatographic-flame ionization detection method: NMKL collaborative study.

    Science.gov (United States)

    Laakso, Päivi H

    2014-01-01

    This collaborative study with nine participating laboratories was conducted to determine the total plant sterol and/or plant stanol contents in phytosterol fortified foods with a gas chromatographic method. Four practice and 12 test samples representing mainly commercially available foodstuffs were analyzed as known replicates. Twelve samples were enriched with phytosterols, whereas four samples contained only natural contents of phytosterols. The analytical procedure consisted of two alternative approaches: hot saponification method, and acid hydrolysis treatment prior to hot saponification. As a result, sterol/stanol compositions and contents in the samples were measured. The amounts of total plant sterols and total plant stanols varying from 0.005 to 8.04 g/100 g product were statistically evaluated after outliers were eliminated. The repeatability RSD (RSDr) varied from 1.34 to 17.13%. The reproducibility RSD (RSDR) ranged from 3.03 to 17.70%, with HorRat values ranging from 0.8 to 2.1. When only phytosterol enriched food test samples are considered, the RSDr ranged from 1.48 to 6.13%, the RSD, ranged from 3.03 to 7.74%, and HorRat values ranged from 0.8 to 2.1. Based on the results of this collaborative study, the study coordinator concludes the method is fit for its purpose.

  11. DIRECT FORMATION OF SUPERMASSIVE BLACK HOLES IN METAL-ENRICHED GAS AT THE HEART OF HIGH-REDSHIFT GALAXY MERGERS

    Energy Technology Data Exchange (ETDEWEB)

    Mayer, Lucio; Fiacconi, Davide [Center for Theoretical Astrophysics and Cosmology, Institute for Computational Science, University of Zurich, Winterthurerstrasse 190, CH-8057 Zürich (Switzerland); Bonoli, Silvia [Centro de Estudios de Fisica del Cosmos de Aragon, Plaza San Juan 1, Planta-2, E-44001, Teruel (Spain); Quinn, Thomas [Astronomy Department, University of Washington, Box 351580, Seattle, WA 98195-1580 (United States); Roškar, Rok [Scientific IT Services, ETH Zürich, Weinbergstrasse 11, CH-8092 Zürich (Switzerland); Shen, Sijing [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom); Wadsley, James, E-mail: lmayer@physik.uzh.ch [Department of Physics and Astronomy, McMaster University, Hamilton, Ontario L8S 4M1 (Canada)

    2015-09-01

    We present novel 3D multi-scale smoothed particle hydrodynamics (SPH) simulations of gas-rich galaxy mergers between the most massive galaxies at z ∼ 8–10, designed to scrutinize the direct collapse formation scenario for massive black hole seeds proposed in Mayer et al. The simulations achieve a resolution of 0.1 pc, and include both metallicity-dependent optically thin cooling and a model for thermal balance at high optical depth. We consider different formulations of the SPH hydrodynamical equations, including thermal and metal diffusion. When the two merging galaxy cores collide, gas infall produces a compact, optically thick nuclear disk with densities exceeding 10{sup −10} g cm{sup 3}. The disk rapidly accretes higher angular momentum gas from its surroundings reaching ∼5 pc and a mass of ≳10{sup 9} M{sub ⊙} in only a few 10{sup 4} years. Outside ≳2 pc it fragments into massive clumps. Instead, supersonic turbulence prevents fragmentation in the inner parsec region, which remains warm (∼3000–6000 K) and develops strong non-axisymmetric modes that cause prominent radial gas inflows (>10{sup 4} M{sub ⊙} yr{sup −1}), forming an ultra-dense massive disky core. Angular momentum transport by non-axisymmetric modes should continue below our spatial resolution limit, quickly turning the disky core into a supermassive protostar which can collapse directly into a massive black hole of mass 10{sup 8}–10{sup 9} M{sub ⊙} via the relativistic radial instability. Such a “cold direct collapse” explains naturally the early emergence of high-z QSOs. Its telltale signature would be a burst of gravitational waves in the frequency range of 10{sup −4}–10{sup −1} Hz, possibly detectable by the planned eLISA interferometer.

  12. Biomass Steam Gasification with In-Situ CO2 Capture for Enriched Hydrogen Gas Production: A Reaction Kinetics Modelling Approach

    Directory of Open Access Journals (Sweden)

    Mohamed Ibrahim Abdul Mutalib

    2010-08-01

    Full Text Available Due to energy and environmental issues, hydrogen has become a more attractive clean fuel. Furthermore, there is high interest in producing hydrogen from biomass with a view to sustainability. The thermochemical process for hydrogen production, i.e. gasification, is the focus of this work. This paper discusses the mathematical modeling of hydrogen production process via biomass steam gasification with calcium oxide as sorbent in a gasifier. A modelling framework consisting of kinetics models for char gasification, methanation, Boudouard, methane reforming, water gas shift and carbonation reactions to represent the gasification and CO2 adsorption in the gasifier, is developed and implemented in MATLAB. The scope of the work includes an investigation of the influence of the temperature, steam/biomass ratio and sorbent/biomass ratio on the amount of hydrogen produced, product gas compositions and carbon conversion. The importance of different reactions involved in the process is also discussed. It is observed that hydrogen production and carbon conversion increase with increasing temperature and steam/biomass ratio. The model predicts a maximum hydrogen mole fraction in the product gas of 0.81 occurring at 950 K, steam/biomass ratio of 3.0 and sorbent/biomass ratio of 1.0. In addition, at sorbent/biomass ratio of 1.52, purity of H2 can be increased to 0.98 mole fraction with all CO2 present in the system adsorbed.

  13. Effects of GC temperature and carrier gas flow rate on on-line oxygen isotope measurement as studied by on-column CO injection.

    Science.gov (United States)

    Chen, Zhi-Gang; Yin, Xi-Jie; Zhou, Youping

    2015-08-01

    Although deemed important to δ 18 O measurement by on-line high-temperature conversion techniques, how the GC conditions affect δ 18 O measurement is rarely examined adequately. We therefore directly injected different volumes of CO or CO-N 2 mix onto the GC column by a six-port valve and examined the CO yield, CO peak shape, CO-N 2 separation, and δ 18 O value under different GC temperatures and carrier gas flow rates. The results show the CO peak area decreases when the carrier gas flow rate increases. The GC temperature has no effect on peak area. The peak width increases with the increase of CO injection volume but decreases with the increase of GC temperature and carrier gas flow rate. The peak intensity increases with the increase of GC temperature and CO injection volume but decreases with the increase of carrier gas flow rate. The peak separation time between N 2 and CO decreases with an increase of GC temperature and carrier gas flow rate. δ 18 O value decreases with the increase of CO injection volume (when half m/z 28 intensity is rate. On average, the δ 18 O value of the injected CO is about 1‰ higher than that of identical reference CO. The δ 18 O distribution pattern of the injected CO is probably a combined result of ion source nonlinearity and preferential loss of C 16 O or oxygen isotopic exchange between zeolite and CO. For practical application, a lower carrier gas flow rate is therefore recommended as it has the combined advantages of higher CO yield, better N 2 -CO separation, lower He consumption, and insignificant effect on δ 18 O value, while a higher-than-60 °C GC temperature and a larger-than-100 µl CO volume is also recommended. When no N 2 peak is expected, a higher GC temperature is recommended, and vice versa. Copyright © 2015 John Wiley & Sons, Ltd. Copyright © 2015 John Wiley & Sons, Ltd.

  14. Wettability determination by contact angle measurements: hvbB coal-water system with injection of synthetic flue gas and CO2.

    Science.gov (United States)

    Shojai Kaveh, Narjes; Rudolph, E Susanne J; Wolf, Karl-Heinz A A; Ashrafizadeh, Seyed Nezameddin

    2011-12-01

    Geological sequestration of pure carbon dioxide (CO(2)) in coal is one of the methods to sequester CO(2). In addition, injection of CO(2) or flue gas into coal enhances coal bed methane production (ECBM). The success of this combined process depends strongly on the wetting behavior of the coal, which is function of coal rank, ash content, heterogeneity of the coal surface, pressure, temperature and composition of the gas. The wetting behavior can be evaluated from the contact angle of a gas bubble, CO(2) or flue gas, on a coal surface. In this study, contact angles of a synthetic flue gas, i.e. a 80/20 (mol%) N(2)/CO(2) mixture, and pure CO(2) on a Warndt Luisenthal (WL) coal have been determined using a modified pendant drop cell in a pressure range from atmospheric to 16 MPa and a constant temperature of 318 K. It was found that the contact angles of flue gas on WL coal were generally smaller than those of CO(2). The contact angle of CO(2) changes from water-wet to gas-wet by increasing pressure above 8.5 MPa while the one for the flue gas changes from water-wet to intermediate-wet by increasing pressure above 10 MPa. Copyright © 2011 Elsevier Inc. All rights reserved.

  15. Effects of a reduced dose of injected iron on health, iron status and growth of suckling piglets with access to iron enriched soil.

    Science.gov (United States)

    Thanner, S; Gutzwiller, A

    2018-02-01

    The effects of the recommended dose of 200 mg iron and of half that dose injected on the first day of life on health, iron status and performance during the 4 week suckling period were studied in 2'123 piglets. All piglets received creep feed and soil which was supplemented with 14 g iron per kg. Neither mortality nor the prevalence of arthritis, meningitis and foot abscess (each disease affecting about 1% of the piglets) differed between the two groups. The low dose of 100 mg iron decreased blood haemoglobin concentration at weaning (110 ± 19 vs.120 ± 15 g/l), but did not affect growth rate.

  16. Effects of CO[sub 2] enrichment and nitrogen fertilization on leaf gas exchange and yield of field-grown sweet potatoes

    Energy Technology Data Exchange (ETDEWEB)

    Hileman, D.R.; Strachan, R.; Alemayehu, M.; Huluka, G.; Moore, J.; Biswas, P.K. (Tuskegee Univ., AL (United States))

    1993-06-01

    Sweet potatoes (Ipomoea batatas L.) were grown in the field in open-top chambers at two levels of CO[sub 2] (ambient and 300 [mu]L L[sup [minus]1] above ambient) and two levels of nitrogen fertilization. Leaf gas exchange rates were determined during midday hours under sunny conditions. CO[sub 2] enrichment led to an increase of 48% in net photosynthetic rates and to decreases of 15% and 29% in leaf transpiration and stomatal conductance. The nitrogen treatment had no significant effects on leaf gas exchange, The number of storage roots and total storage root fresh weight increased 33% and 38%, respectively, at elevated CO[sub 2]. There was a non-significant trend towards larger storage roots at high nitrogen levels. The lack of significant effects due to the nitrogen treatment (except for a positive effect on leaf size) may indicate that nitrogen was not limiting, Elemental analysis of plant and soil samples, currently in progress, will help clarify this situation.

  17. Enriched Air Nitrox Breathing Reduces Venous Gas Bubbles after Simulated SCUBA Diving: A Double-Blind Cross-Over Randomized Trial.

    Directory of Open Access Journals (Sweden)

    Vincent Souday

    Full Text Available To test the hypothesis whether enriched air nitrox (EAN breathing during simulated diving reduces decompression stress when compared to compressed air breathing as assessed by intravascular bubble formation after decompression.Human volunteers underwent a first simulated dive breathing compressed air to include subjects prone to post-decompression venous gas bubbling. Twelve subjects prone to bubbling underwent a double-blind, randomized, cross-over trial including one simulated dive breathing compressed air, and one dive breathing EAN (36% O2 in a hyperbaric chamber, with identical diving profiles (28 msw for 55 minutes. Intravascular bubble formation was assessed after decompression using pulmonary artery pulsed Doppler.Twelve subjects showing high bubble production were included for the cross-over trial, and all completed the experimental protocol. In the randomized protocol, EAN significantly reduced the bubble score at all time points (cumulative bubble scores: 1 [0-3.5] vs. 8 [4.5-10]; P < 0.001. Three decompression incidents, all presenting as cutaneous itching, occurred in the air versus zero in the EAN group (P = 0.217. Weak correlations were observed between bubble scores and age or body mass index, respectively.EAN breathing markedly reduces venous gas bubble emboli after decompression in volunteers selected for susceptibility for intravascular bubble formation. When using similar diving profiles and avoiding oxygen toxicity limits, EAN increases safety of diving as compared to compressed air breathing.ISRCTN 31681480.

  18. Efficient carbon dioxide utilization and simultaneous hydrogen enrichment from off-gas of acetone-butanol-ethanol fermentation by succinic acid producing Escherichia coli.

    Science.gov (United States)

    He, Aiyong; Kong, Xiangping; Wang, Chao; Wu, Hao; Jiang, Min; Ma, Jiangfeng; Ouyang, Pingkai

    2016-08-01

    The off-gas from acetone-butanol-ethanol (ABE) fermentation was firstly used to be CO2 source (co-substrate) for succinic acid production. The optimum ratio of H2/CO2 indicated higher CO2 partial pressures with presence of H2 could enhance C4 pathway flux and reductive product productivity. Moreover, when an inner recycling bioreactor was used for CO2 recycling at a high total pressure (0.2Mpa), a maximum succinic acid concentration of 65.7g·L(-1) was obtained, and a productivity of 0.76g·L(-1)·h(-1) and a high yield of 0.86g·g(-1) glucose were achieved. Furthermore, the hydrogen content was simultaneously enriched to 92.7%. These results showed one successful attempt to reuse the off-gas of ABE fermentation which can be an attractive CO2 source for succinic acid production. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Development and Validation of 3D-CFD Injection and Combustion Models for Dual Fuel Combustion in Diesel Ignited Large Gas Engines

    Directory of Open Access Journals (Sweden)

    Lucas Eder

    2018-03-01

    Full Text Available This paper focuses on improving the 3D-Computational Fluid Dynamics (CFD modeling of diesel ignited gas engines, with an emphasis on injection and combustion modeling. The challenges of modeling are stated and possible solutions are provided. A specific approach for modeling injection is proposed that improves the modeling of the ballistic region of the needle lift. Experimental results from an inert spray chamber are used for model validation. Two-stage ignition methods are described along with improvements in ignition delay modeling of the diesel ignited gas engine. The improved models are used in the Extended Coherent Flame Model with the 3 Zones approach (ECFM-3Z. The predictive capability of the models is investigated using data from single cylinder engine (SCE tests conducted at the Large Engines Competence Center (LEC. The results are discussed and further steps for development are identified.

  20. Gas-Phase Enrichment of Multiply Charged Peptide Ions by Differential Ion Mobility Extend the Comprehensiveness of SUMO Proteome Analyses.

    Science.gov (United States)

    Pfammatter, Sibylle; Bonneil, Eric; McManus, Francis P; Thibault, Pierre

    2018-04-05

    The small ubiquitin-like modifier (SUMO) is a member of the family of ubiquitin-like modifiers (UBLs) and is involved in important cellular processes, including DNA damage response, meiosis and cellular trafficking. The large-scale identification of SUMO peptides in a site-specific manner is challenging not only because of the low abundance and dynamic nature of this modification, but also due to the branched structure of the corresponding peptides that further complicate their identification using conventional search engines. Here, we exploited the unusual structure of SUMO peptides to facilitate their separation by high-field asymmetric waveform ion mobility spectrometry (FAIMS) and increase the coverage of SUMO proteome analysis. Upon trypsin digestion, branched peptides contain a SUMO remnant side chain and predominantly form triply protonated ions that facilitate their gas-phase separation using FAIMS. We evaluated the mobility characteristics of synthetic SUMO peptides and further demonstrated the application of FAIMS to profile the changes in protein SUMOylation of HEK293 cells following heat shock, a condition known to affect this modification. FAIMS typically provided a 10-fold improvement of detection limit of SUMO peptides, and enabled a 36% increase in SUMO proteome coverage compared to the same LC-MS/MS analyses performed without FAIMS. Graphical Abstract ᅟ.

  1. Gas exchange and growth responses to nutrient enrichment in invasive Glyceria maxima and native New Zealand Carex species

    DEFF Research Database (Denmark)

    Sorrell, Brian Keith; Brix, Hans; Fitridge, Isla

    2012-01-01

    the sedges, but correlations between leaf N, gas exchange parameters (Amaxa, Amaxm, Rd and gs) and RGR were all highly significant in G. maxima, whereas they were weak or absent in the sedges. Allocation of biomass (root:shoot ratio, leaf mass ratio, root mass ratio), plant N and P content, and allocation......) in G. maxima (17 ± 6 m2 kg-1) was 1.3 times that of the sedges, leading to 1.4 times higher maximum rates of photosynthesis (350 – 400 nmol CO2 g-1 dry mass s-1) expressed on a leaf mass basis (Amaxm) when N supply was unlimited, compared to the sedges (mass s-1). Analysis......, the sedges had 2.4 times higher intrinsic water use efficiency (A/gs: range 20-70 c.f. 8-30 µmol CO2 mol-1 H2O) and 1.6 times higher nitrogen use efficiency (NUE: 25 – 30 c.f. 20 – 23 g dry mass g-1 N) under excess N supply. Relative growth rates (RGR) were not significantly higher in G. maxima than...

  2. Multiscale Characterization and Quantification of Arsenic Mobilization and Attenuation During Injection of Treated Coal Seam Gas Coproduced Water into Deep Aquifers

    Science.gov (United States)

    Rathi, Bhasker; Siade, Adam J.; Donn, Michael J.; Helm, Lauren; Morris, Ryan; Davis, James A.; Berg, Michael; Prommer, Henning

    2017-12-01

    Coal seam gas production involves generation and management of large amounts of co-produced water. One of the most suitable methods of management is injection into deep aquifers. Field injection trials may be used to support the predictions of anticipated hydrological and geochemical impacts of injection. The present work employs reactive transport modeling (RTM) for a comprehensive analysis of data collected from a trial where arsenic mobilization was observed. Arsenic sorption behavior was studied through laboratory experiments, accompanied by the development of a surface complexation model (SCM). A field-scale RTM that incorporated the laboratory-derived SCM was used to simulate the data collected during the field injection trial and then to predict the long-term fate of arsenic. We propose a new practical procedure which integrates laboratory and field-scale models using a Monte Carlo type uncertainty analysis and alleviates a significant proportion of the computational effort required for predictive uncertainty quantification. The results illustrate that both arsenic desorption under alkaline conditions and pyrite oxidation have likely contributed to the arsenic mobilization that was observed during the field trial. The predictive simulations show that arsenic concentrations would likely remain very low if the potential for pyrite oxidation is minimized through complete deoxygenation of the injectant. The proposed modeling and predictive uncertainty quantification method can be implemented for a wide range of groundwater studies that investigate the risks of metal(loid) or radionuclide contamination.

  3. Injection characteristics study of high-pressure direct injector for Compressed Natural Gas (CNG) using experimental and analytical method

    Science.gov (United States)

    Taha, Z.; Rahim, MF Abdul; Mamat, R.

    2017-10-01

    The injection characteristics of direct injector affect the mixture formation and combustion processes. In addition, the injector is converted from gasoline operation for CNG application. Thus measurement of CNG direct injector mass flow rate was done by independently tested a single injector on a test bench. The first case investigated the effect of CNG injection pressure and the second case evaluate the effect of pulse-width of injection duration. An analytical model was also developed to predict the mass flow rate of the injector. The injector was operated in a choked condition in both the experiments and simulation studies. In case 1, it was shown that mass flow rate through the injector is affected by injection pressure linearly. Based on the tested injection pressure of 20 bar to 60 bar, the resultant mass flow rate are in the range of 0.4 g/s to 1.2 g/s which are met with theoretical flow rate required by the engine. However, in Case 2, it was demonstrated that the average mass flow rate at short injection durations is lower than recorded in Case 1. At injection pressure of 50 bar, the average mass flow rate for Case 2 and Case 1 are 0.7 g/s and 1.1 g/s respectively. Also, the measured mass flow rate at short injection duration showing a fluctuating data in the range of 0.2 g/s - 1.3 g/s without any noticeable trends. The injector model able to predict the trend of the mass flow rate at different injection pressure but unable to track the fluctuating trend at short injection duration.

  4. Combustion characteristics of a 4-stroke CI engine operated on Honge oil, Neem and Rice Bran oils when directly injected and dual fuelled with producer gas induction

    Energy Technology Data Exchange (ETDEWEB)

    Banapurmath, N.R.; Tewari, P.G. [Department of Mechanical Engineering, B.V.B. College of Engineering and Technology, Hubli 580031, Karnataka (India); Yaliwal, V.S. [Department of Mechanical Engineering, SDM College of Engineering and Technology, Dharwad Karnataka (India); Kambalimath, Satish [Wipro Technologies (India); Basavarajappa, Y.H. [K.L.E. Society' s Polytechnic, Hubli (India)

    2009-07-15

    Energy is an essential requirement for economic and social development of any country. Sky rocketing of petroleum fuel costs in present day has led to growing interest in alternative fuels like vegetable oils, alcoholic fuels, CNG, LPG, Producer gas, biogas in order to provide a suitable substitute to diesel for a compression ignition (CI) engine. The vegetable oils present a very promising alternative fuel to diesel oil since they are renewable, biodegradable and clean burning fuel having similar properties as that of diesel. They offer almost same power output with slightly lower thermal efficiency due to their lower energy content compared to diesel. Utilization of producer gas in CI engine on dual fuel mode provides an effective approach towards conservation of diesel fuel. Gasification involves conversion of solid biomass into combustible gases which completes combustion in a CI engines. Hence the producer gas can act as promising alternative fuel and it has high octane number (100-105) and calorific value (5-6 MJ/Nm{sup 3}). Because of its simpler structure with low carbon content results in substantial reduction of exhaust emission. Downdraft moving bed gasifier coupled with compression ignition engine are a good choice for moderate quantities of available mass up to 500 kW of electrical power. Hence bio-derived gas and vegetable liquids appear more attractive in view of their friendly environmental nature. Experiments have been conducted on a single cylinder, four-stroke, direct injection, water-cooled CI engine operated in single fuel mode using Honge, Neem and Rice Bran oils. In dual fuel mode combinations of Producer gas and three oils were used at different injection timings and injection pressures. Dual fuel mode of operation resulted in poor performance at all the loads when compared with single fuel mode at all injection timings tested. However, the brake thermal efficiency is improved marginally when the injection timing was advanced. Decreased

  5. Enrichment of Ly6Chi monocytes by multiple GM-CSF injections with HBV vaccine contributes to viral clearance in a HBV mouse model.

    Science.gov (United States)

    Zhao, Weidong; Zhou, Xian; Zhao, Gan; Lin, Qing; Wang, Xianzheng; Yu, Xueping; Wang, Bin

    2017-12-02

    Adjuvants are considered a necessary component for HBV therapeutic vaccines but few are licensed in clinical practice due to concerns about safety or efficiency. In our recent study, we established that a combination protocol of 3-day pretreatments with GM-CSF before a vaccination (3 × GM-CSF+VACCINE) into the same injection site could break immune tolerance and cause over 90% reduction of HBsAg level in the HBsAg transgenic mouse model. Herein, we further investigated the therapeutic potential of the combination in AAV8-1.3HBV-infected mice. After 4 vaccinations, both serum HBeAg and HBsAg were cleared and there was a 95% reduction of HBV-positive hepatocytes, in addition to the presence of large number of infiltrating CD8 + T cells in the livers. Mechanistically, the HBV-specific T-cell responses were elicited via a 3 × GM-CSF+VACCINE-induced conversion of CCR2-dependent CD11b + Ly6C hi monocytes into CD11b + CD11c + DCs. Experimental depletion of Ly6C hi monocytes resulted in a defective HBV-specific immune response thereby abrogating HBV eradication. This vaccination strategy could lead to development of an effective therapeutic protocol against chronic HBV in infected patients.

  6. Comparison of headspace-oxylipin-volatilomes of some Eastern Himalayan mosses extracted by sample enrichment probe and analysed by gas chromatography-mass spectrometry.

    Science.gov (United States)

    Mitra, Souvik; Burger, Barend V; Poddar-Sarkar, Mousumi

    2017-03-01

    Mosses have an inherent adaptability against different biotic and abiotic stresses. Oxylipins, the volatile metabolites derived from polyunsaturated fatty acids (PUFAs), play a key role in the chemical defence strategy of mosses. In the present study, a comparative survey of these compounds, including an investigation into their precursor fatty acids (FAs), was carried out for the first time on the mosses Brachymenium capitulatum (Mitt.) Paris, Hydrogonium consanguineum (Thwaites & Mitt.) Hilp., Barbula hastata Mitt., and Octoblepharum albidum Hedw. collected from the Eastern Himalayan Biodiversity hotspot. Their headspace volatiles were sampled using a high-efficiency sample enrichment probe (SEP) and were characterized by gas chromatography-mass spectrometric analysis. FAs from neutral lipid (NL) and phospholipid (PL) fractions were also evaluated. Analysis of the oxylipin volatilome revealed the generation of diverse metabolites from C 5 to C 18 , dominated by alkanes, alkenes, saturated and unsaturated alcohols, aldehydes, ketones and cyclic compounds, with pronounced structural variations. The C 6 and C 8 compounds dominated the total volatilome of all the samples. Analyses of FAs from membrane PL and storage NL highlighted the involvement of C 18 and C 20 PUFAs in oxylipin generation. The volatilome of each moss is characterized by a 'signature oxylipin mixture'. Quantitative differences in the C 6 and C 8 metabolites indicate their phylogenetic significance.

  7. Enriched Air Nitrox Breathing Reduces Venous Gas Bubbles after Simulated SCUBA Diving: A Double-Blind Cross-Over Randomized Trial.

    Science.gov (United States)

    Souday, Vincent; Koning, Nick J; Perez, Bruno; Grelon, Fabien; Mercat, Alain; Boer, Christa; Seegers, Valérie; Radermacher, Peter; Asfar, Pierre

    2016-01-01

    To test the hypothesis whether enriched air nitrox (EAN) breathing during simulated diving reduces decompression stress when compared to compressed air breathing as assessed by intravascular bubble formation after decompression. Human volunteers underwent a first simulated dive breathing compressed air to include subjects prone to post-decompression venous gas bubbling. Twelve subjects prone to bubbling underwent a double-blind, randomized, cross-over trial including one simulated dive breathing compressed air, and one dive breathing EAN (36% O2) in a hyperbaric chamber, with identical diving profiles (28 msw for 55 minutes). Intravascular bubble formation was assessed after decompression using pulmonary artery pulsed Doppler. Twelve subjects showing high bubble production were included for the cross-over trial, and all completed the experimental protocol. In the randomized protocol, EAN significantly reduced the bubble score at all time points (cumulative bubble scores: 1 [0-3.5] vs. 8 [4.5-10]; P diving profiles and avoiding oxygen toxicity limits, EAN increases safety of diving as compared to compressed air breathing. ISRCTN 31681480.

  8. Application of pathways analyses for site performance prediction for the Gas Centrifuge Enrichment Plant and Oak Ridge Central Waste Disposal Facility

    International Nuclear Information System (INIS)

    Pin, F.G.; Oblow, E.M.

    1984-01-01

    The suitability of the Gas Centrifuge Enrichment Plant and the Oak Ridge Central Waste Disposal Facility for shallow-land burial of low-level radioactive waste is evaluated using pathways analyses. The analyses rely on conservative scenarios to describe the generation and migration of contamination and the potential human exposure to the waste. Conceptual and numerical models are developed using data from comprehensive laboratory and field investigations and are used to simulate the long-term transport of contamination to man. Conservatism is built into the analyses when assumptions concerning future events have to be made or when uncertainties concerning site or waste characteristics exist. Maximum potential doses to man are calculated and compared to the appropriate standards. The sites are found to provide adequate buffer to persons outside the DOE reservations. Conclusions concerning site capacity and site acceptability are drawn. In reaching these conclusions, some consideration is given to the uncertainties and conservatisms involved in the analyses. Analytical methods to quantitatively assess the probability of future events to occur and the sensitivity of the results to data uncertainty may prove useful in relaxing some of the conservatism built into the analyses. The applicability of such methods to pathways analyses is briefly discussed. 18 refs., 9 figs

  9. Investigation of plasma behavior during noble gas injection in the end-cell of GAMMA 10/PDX by using the multi-fluid code ‘LINDA’

    Science.gov (United States)

    Islam, M. S.; Nakashima, Y.; Hatayama, A.

    2017-12-01

    The linear divertor analysis with fluid model (LINDA) code has been developed in order to simulate plasma behavior in the end-cell of linear fusion device GAMMA 10/PDX. This paper presents the basic structure and simulated results of the LINDA code. The atomic processes of hydrogen and impurities have been included in the present model in order to investigate energy loss processes and mechanism of plasma detachment. A comparison among Ar, Kr and Xe shows that Xe is the most effective gas on the reduction of electron and ion temperature. Xe injection leads to strong reduction in the temperature of electron and ion. The energy loss terms for both the electron and the ion are enhanced significantly during Xe injection. It is shown that the major energy loss channels for ion and electron are charge-exchange loss and radiative power loss of the radiator gas, respectively. These outcomes indicate that Xe injection in the plasma edge region is effective for reducing plasma energy and generating detached plasma in linear device GAMMA 10/PDX.

  10. Application of dynamic liquid-phase microextraction and injection port derivatization combined with gas chromatography-mass spectrometry to the determination of acidic pharmaceutically active compounds in water samples.

    Science.gov (United States)

    Zhang, Jie; Lee, Hian Kee

    2009-10-30

    A method has been established for the determination of four pharmaceutically active compounds (ibuprofen, ketoprofen, naproxen and clofibric acid) in water samples using dynamic hollow fiber liquid-phase microextraction (HF/LPME) followed by gas chromatography (GC) injection port derivatization and GC-mass spectrometric (MS) determination. Dynamic HF/LPME is a novel approach to microextraction that involves the use of a programmable syringe pump to move the liquid phases participating in the extraction so as to facilitate the process. Trimethylanilinium hydroxide (TMAH) was used as derivatization reagent for the analytes to increase their volatility and improve chromatographic separation. Parameters that affect extraction efficiency (selection of organic solvent, volume of organic solvent, agitation in the donor phase, plunger movement and extraction time) were investigated. Under optimal conditions, the proposed method provided good enrichment factors up to 251, reproducibility ranging from 3.26% to 10.61%, and good linearity from 0.2 to 50 microg/L. The limits of detection ranged between 0.01 and 0.05 microg/L (S/N=3) using selective ion monitoring. This method was applied to the determination of the four pharmaceutically active compounds in tap water and wastewater collected from a drain in the vicinity of a hospital.

  11. Uranium enrichment

    International Nuclear Information System (INIS)

    1989-01-01

    GAO was asked to address several questions concerning a number of proposed uranium enrichment bills introduced during the 100th Congress. The bill would have restructured the Department of Energy's uranium enrichment program as a government corporation to allow it to compete more effectively in the domestic and international markets. Some of GAO's findings discussed are: uranium market experts believe and existing market models show that the proposed DOE purchase of a $750 million of uranium from domestic producers may not significantly increase production because of large producer-held inventories; excess uranium enrichment production capacity exists throughout the world; therefore, foreign producers are expected to compete heavily in the United States throughout the 1990s as utilities' contracts with DOE expire; and according to a 1988 agreement between DOE's Offices of Nuclear Energy and Defense Programs, enrichment decommissioning costs, estimated to total $3.6 billion for planning purposes, will be shared by the commercial enrichment program and the government

  12. Integrated biogas upgrading and hydrogen utilization in an anaerobic reactor containing enriched hydrogenotrophic methanogenic culture.

    Science.gov (United States)

    Luo, Gang; Angelidaki, Irini

    2012-11-01

    Biogas produced by anaerobic digestion, is mainly used in a gas motor for heat and electricity production. However, after removal of CO(2) , biogas can be upgraded to natural gas quality, giving more utilization possibilities, such as utilization as autogas, or distant utilization by using the existing natural gas grid. The current study presents a new biological method for biogas upgrading in a separate biogas reactor, containing enriched hydrogenotrophic methanogens and fed with biogas and hydrogen. Both mesophilic- and thermophilic anaerobic cultures were enriched to convert CO(2) to CH(4) by addition of H(2) . Enrichment at thermophilic temperature (55°C) resulted in CO(2) and H(2) bioconversion rate of 320 mL CH(4) /(gVSS h), which was more than 60% higher than that under mesophilic temperature (37°C). Different dominant species were found at mesophilic- and thermophilic-enriched cultures, as revealed by PCR-DGGE. Nonetheless, they all belonged to the order Methanobacteriales, which can mediate hydrogenotrophic methanogenesis. Biogas upgrading was then tested in a thermophilic anaerobic reactor under various operation conditions. By continuous addition of hydrogen in the biogas reactor, high degree of biogas upgrading was achieved. The produced biogas had a CH(4) content, around 95% at steady-state, at gas (mixture of biogas and hydrogen) injection rate of 6 L/(L day). The increase of gas injection rate to 12 L/(L day) resulted in the decrease of CH(4) content to around 90%. Further study showed that by decreasing the gas-liquid mass transfer by increasing the stirring speed of the mixture the CH(4) content was increased to around 95%. Finally, the CH(4) content around 90% was achieved in this study with the gas injection rate as high as 24 L/(L day). Copyright © 2012 Wiley Periodicals, Inc.

  13. When does decentralized production of biogas and centralized upgrading and injection into the natural gas grid make sense?

    NARCIS (Netherlands)

    Hengeveld, E. J.; van Gernert, W. J. T.; Bekkering, J.; Broekhuis, A. A.

    The production of biogas through anaerobic digestion is one of the technological solutions to convert biomass into a readily usable fuel. Biogas can replace natural gas, if the biogas is upgraded to green gas. To contribute to the EU-target to reduce Green House Gases emissions, the installed biogas

  14. Uranium enrichment

    International Nuclear Information System (INIS)

    Rae, H.K.; Melvin, J.G.

    1988-06-01

    Canada is the world's largest producer and exporter of uranium, most of which is enriched elsewhere for use as fuel in LWRs. The feasibility of a Canadian uranium-enrichment enterprise is therefore a perennial question. Recent developments in uranium-enrichment technology, and their likely impacts on separative work supply and demand, suggest an opportunity window for Canadian entry into this international market. The Canadian opportunity results from three particular impacts of the new technologies: 1) the bulk of the world's uranium-enrichment capacity is in gaseous diffusion plants which, because of their large requirements for electricity (more than 2000 kW·h per SWU), are vulnerable to competition from the new processes; 2) the decline in enrichment costs increases the economic incentive for the use of slightly-enriched uranium (SEU) fuel in CANDU reactors, thus creating a potential Canadian market; and 3) the new processes allow economic operation on a much smaller scale, which drastically reduces the investment required for market entry and is comparable with the potential Canadian SEU requirement. The opportunity is not open-ended. By the end of the century the enrichment supply industry will have adapted to the new processes and long-term customer/supplier relationships will have been established. In order to seize the opportunity, Canada must become a credible supplier during this century

  15. A Practical Approach for Formation Damage Control in Both Miscible and Immiscible CO2 Gas Flooding in Asphaltenic Crude Systems Using Water Slugs and Injection Parameters

    Science.gov (United States)

    David, Sergio Z.

    CO2 flooding has proven to be an effective technique for enhanced oil recovery. However, the application of CO2 flooding in the recovery process of asphaltenic crude systems is often avoided, as high asphaltene precipitation rates may occur. While the effects of asphaltene concetration and CO2 injection pressure on asphaltene precipitation rate have been the focus of many studies, asphaltene precipitation rate is not a reliable factor to predict the magnitude of asphaltene-induced formation damage. Wettability alteration is only caused by the immobile asphaltene deposits on the rock surface. The enternmaint of flocs may occur at high fluid velocity. Morover, the effective permeability reduction is only caused by the flocs, which have become large enough to block the pore throats. The dissociation of the flocs may occur under certain flow conditions. In this study, a compositional reservoir simulation was conducted using Eclipse 300 to investigate the injection practice, which avoids asphaltene-induced formation damage during both immiscible and miscible CO2 flooding in asphaltenic crude system. Without injection, at pressure above bubble point, slight precipitation occurred in the zone of the lowest pressure near the producing well. As pressure approached the bubble point, precipitation increased due to the change in the hydrocarbon composition, which suggested that the potential of asphaltene-induced formation damage is determined by the overall fluid composition. At very low pressure, precipitation decreased due to the increase in the density. As CO2 was injected below the minimum miscibility pressure, a slight precipitation occurred in the transition zone at the gas-oil interface due to the microscopic diffusion of the volatile hydrocarbon components caused by the local concentration gradients. The increase in CO2 injection rate did not significantly increase the precipitation rate. As CO2 was injected at pressure above the minimum miscibility pressure

  16. On-line solid-phase enrichment coupled to packed reactor flow injection analysis in a green analytical procedure to determine low levels of folic acid using fluorescence detection

    Directory of Open Access Journals (Sweden)

    Emara Samy

    2012-12-01

    Full Text Available Abstract Background Analysis of folic acid (FA is not an easy task because of its presence in lower concentrations, its lower stability under acidic conditions, and its sensitiveness against light and high temperature. The present study is concerned with the development and validation of an automated environmentally friendly pre-column derivatization combined by solid-phase enrichment (SPEn to determine low levels of FA. Results Cerium (IV trihydroxyhydroperoxide (CTH as a packed oxidant reactor has been used for oxidative cleavage of FA into highly fluorescent product, 2-amino-4-hydroxypteridine-6-carboxylic acid. FA was injected into a carrier stream of 0.04 M phosphate buffer, pH 3.4 at a flow-rate of 0.25 mL/min. The sample zone containing the analyte was passed through the CTH reactor thermostated at 40°C, and the fluorescent product was trapped and enriched on a head of small ODS column (10 mm x 4.6 mm i.d., 5 μm particle size. The enriched product was then back-flush eluted by column-switching from the small ODS column to the detector with a greener mobile phase consisting of ethanol and phosphate buffer (0.04M, pH 3.4 in the ratio of 5:95 (v/v. The eluent was monitored fluorimetrically at emission and excitation wavelengths of 463 and 367 nm, respectively. The calibration graph was linear over concentrations of FA in the range of 1.25-50 ng/mL, with a detection limit of 0.49 ng/mL. Conclusion A new simple and sensitive green analytical procedure including on-line pre-column derivatization combined by SPEn has been developed for the routine quality control and dosage form assay of FA at very low concentration level. The method was a powerful analytical technique that had excellent sensitivity, sufficient accuracy and required relatively simple and inexpensive instrumentation.

  17. Experimental investigation of the impulse gas injection into liquid and the use of experimental data for verification of the HYDRA-IBRAE/LM thermohydraulic code

    Science.gov (United States)

    Lobanov, P. D.; Usov, E. V.; Butov, A. A.; Pribaturin, N. A.; Mosunova, N. A.; Strizhov, V. F.; Chukhno, V. I.; Kutlimetov, A. E.

    2017-10-01

    Experiments with impulse gas injection into model coolants, such as water or the Rose alloy, performed at the Novosibirsk Branch of the Nuclear Safety Institute, Russian Academy of Sciences, are described. The test facility and the experimental conditions are presented in details. The dependence of coolant pressure on the injected gas flow and the time of injection was determined. The purpose of these experiments was to verify the physical models of thermohydraulic codes for calculation of the processes that could occur during the rupture of tubes of a steam generator with heavy liquid metal coolant or during fuel rod failure in water-cooled reactors. The experimental results were used for verification of the HYDRA-IBRAE/LM system thermohydraulic code developed at the Nuclear Safety Institute, Russian Academy of Sciences. The models of gas bubble transportation in a vertical channel that are used in the code are described in detail. A two-phase flow pattern diagram and correlations for prediction of friction of bubbles and slugs as they float up in a vertical channel and of two-phase flow friction factor are presented. Based on the results of simulation of these experiments using the HYDRA-IBRAE/LM code, the arithmetic mean error in predicted pressures was calculated, and the predictions were analyzed considering the uncertainty in the input data, geometry of the test facility, and the error of the empirical correlation. The analysis revealed major factors having a considerable effect on the predictions. The recommendations are given on updating of the experimental results and improvement of the models used in the thermohydraulic code.

  18. Thermo-mechanical Analysis of Cold Helium Injection into Gas Storage Tanks made of Carbon Steel Following Resistive Transition of the LHC Magnets

    CERN Document Server

    Chorowski, M

    1998-01-01

    A resistive transition (quench) of the LHC sector magnets will be followed by cold helium venting to a quench buffer volume of 2000 m3 at ambient temperature. The volume will be composed of eight medi um-pressure (2 MPa) gas storage tanks made of carbon steel, which constrains the temperature of the wall to be higher than -50oC (223 K). The aim of the analysis is the assessment of a possible spot c ooling intensity and thermo-mechanical stresses in the tank wall following helium injection.

  19. Information contained within the large scale gas injection test (Lasgit) dataset exposed using a bespoke data analysis tool-kit

    International Nuclear Information System (INIS)

    Bennett, D.P.; Thomas, H.R.; Cuss, R.J.; Harrington, J.F.; Vardon, P.J.

    2012-01-01

    Document available in extended abstract form only. The Large Scale Gas Injection Test (Lasgit) is a field scale experiment run by the British Geological Survey (BGS) and is located approximately 420 m underground at SKB's Aespoe Hard Rock Laboratory (HRL) in Sweden. It has been designed to study the impact on safety of gas build up within a KBS-3V concept high level radioactive waste repository. Lasgit has been in almost continuous operation for approximately seven years and is still underway. An analysis of the dataset arising from the Lasgit experiment with particular attention to the smaller scale features and phenomenon recorded has been undertaken in parallel to the macro scale analysis performed by the BGS. Lasgit is a highly instrumented, frequently sampled and long-lived experiment leading to a substantial dataset containing in excess of 14.7 million datum points. The data is anticipated to include a wealth of information, including information regarding overall processes as well as smaller scale or 'second order' features. Due to the size of the dataset coupled with the detailed analysis of the dataset required and the reduction in subjectivity associated with measurement compared to observation, computational analysis is essential. Moreover, due to the length of operation and complexity of experimental activity, the Lasgit dataset is not typically suited to 'out of the box' time series analysis algorithms. In particular, the features that are not suited to standard algorithms include non-uniformities due to (deliberate) changes in sample rate at various points in the experimental history and missing data due to hardware malfunction/failure causing interruption of logging cycles. To address these features a computational tool-kit capable of performing an Exploratory Data Analysis (EDA) on long-term, large-scale datasets with non-uniformities has been developed. Particular tool-kit abilities include: the parameterization of signal variation in the dataset

  20. High potential recovery -- Gas repressurization

    Energy Technology Data Exchange (ETDEWEB)

    Madden, M.P.

    1998-05-01

    The objective of this project was to demonstrate that small independent oil producers can use existing gas injection technologies, scaled to their operations, to repressurize petroleum reservoirs and increase their economic oil production. This report gives background information for gas repressurization technologies, the results of workshops held to inform small independent producers about gas repressurization, and the results of four gas repressurization field demonstration projects. Much of the material in this report is based on annual reports (BDM-Oklahoma 1995, BDM-Oklahoma 1996, BDM-Oklahoma 1997), a report describing the results of the workshops (Olsen 1995), and the four final reports for the field demonstration projects which are reproduced in the Appendix. This project was designed to demonstrate that repressurization of reservoirs with gas (natural gas, enriched gas, nitrogen, flue gas, or air) can be used by small independent operators in selected reservoirs to increase production and/or decrease premature abandonment of the resource. The project excluded carbon dioxide because of other DOE-sponsored projects that address carbon dioxide processes directly. Two of the demonstration projects, one using flue gas and the other involving natural gas from a deeper coal zone, were both technical and economic successes. The two major lessons learned from the projects are the importance of (1) adequate infrastructure (piping, wells, compressors, etc.) and (2) adequate planning including testing compatibility between injected gases and fluids, and reservoir gases, fluids, and rocks.

  1. Fast gas chromatographic residue analysis in animal feed using split injection and atmospheric pressure chemical ionisation tandem mass spectrometry

    NARCIS (Netherlands)

    Tienstra, M.; Portolés, T.; Hernandez, F.; Mol, J.G.J.

    2015-01-01

    Significant speed improvement for instrumental runtime would make GC–MS much more attractive for determination of pesticides and contaminants and as complementary technique to LC–MS. This was the trigger to develop a fast method (time between injections less than 10 min) for the determination of

  2. A gas-tracer injection for evaluating the fate of methane in a coastal plain stream: Degassing versus in-stream oxidation

    Science.gov (United States)

    Heilweil, Victor M.; Solomon, D. Kip; Darrah, Thomas H.; Gilmore, Troy E.; Genereux, David P.

    2016-01-01

    Methane emissions from streams and rivers have recently been recognized as an important component of global greenhouse budgets. Stream methane is lost as evasion to the atmosphere or in-stream methane oxidation. Previous studies have quantified evasion and oxidation with point-scale measurements. In this study, dissolved gases (methane, krypton) were injected into a coastal plain stream in North Carolina to quantify stream CH4 losses at the watershed scale. Stream-reach modeling yielded gas transfer and oxidation rate constants of 3.2 ± 0.5 and 0.5 ± 1.5 d–1, respectively, indicating a ratio of about 6:1. The resulting evasion and oxidation rates of 2.9 mmol m–2 d–1 and 1,140 nmol L–1 d–1, respectively, lie within ranges of published values. Similarly, the gas transfer velocity (K600) of 2.1 m d–1 is consistent with other gas tracer studies. This study illustrates the utility of dissolved-gas tracers for evaluating stream methane fluxes. In contrast to point measurements, this approach provides a larger watershed-scale perspective. Further work is needed to quantify the magnitude of these fluxes under varying conditions (e.g., stream temperature, nutrient load, gradient, flow rate) at regional and global scales before reliable bottom-up estimates of methane evasion can be determined at global scales.

  3. Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report no. 8-A, June 1--August 31, 1989

    Energy Technology Data Exchange (ETDEWEB)

    1989-09-27

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device.

  4. AN APPLICATION OF FLOW INJECTION ANALYSIS WITH GAS DIFFUSION AND SPECTROPHOTOMETRIC DETECTION FOR THE MONITORING OF DISSOLVED SULPHIDE CONCENTRATION IN ENVIRONMENTAL SAMPLES

    Directory of Open Access Journals (Sweden)

    Malwina Cykowska

    2014-10-01

    Full Text Available The monitoring of the concentration of sulphide is very important from the environment point of view because of high toxicity of hydrogen sulphide. What is more hydrogen sulphide is an important pollution indicator. In many cases the determination of sulphide is very difficult due to complicated matrix of some environmental samples, which causes that most analytical methods cannot be used. Flow injection analysis allows to avoid matrix problem what makes it suitable for a wide range of applications in analytical laboratories. In this paper determination of dissolved sulphide in environmental samples by gas-diffusion flow injection analysis with spectrophotometric detection was presented. Used gas-diffusion separation ensures the elimination of interferences caused by sample matrix and gives the ability of determination of sulphides in coloured and turbid samples. Studies to optimize the measurement conditions and to determine the value of the validation parameters (e.g. limit of detection, limit of quantification, precision, accuracy were carried out. Obtained results confirm the usefulness of the method for monitoring the concentration of dissolved sulphides in water and waste water. Full automation and work in a closed system greatly reduces time of analysis, minimizes consumption of sample and reagents and increases safety of analyst’s work.

  5. Determination of low-molecular-weight dicarboxylic acids in atmospheric aerosols by injection-port derivatization and gas chromatography-mass spectrometry.

    Science.gov (United States)

    Hsu, Ching-Lin; Ding, Wang-Hsien

    2009-12-15

    A rapid and environmental-friendly injection-port derivatization with gas chromatography-mass spectrometry (GC-MS) method was developed to determine selected low-molecular weight (LMW) dicarboxylic acids (from C2 to C10) in atmospheric aerosol samples. The parameters related to the derivatization process (i.e., type of ion-pair reagent, injection-port temperature and concentration of ion-pair reagent) were optimized. Tetrabutylammonium hydroxide (TBA-OH) 20 mM in methanol gave excellent yield for di-butyl ester dicarboxylate derivatives at injection-port temperature at 300 degrees C. Solid-phase extraction (SPE) method instead of rotary evaporation was used to concentrate analytes from filter extracts. The recovery from filter extracts ranged from 78 to 95% with relative standard deviation (RSD) less than 12%. Limits of quantitation (LOQs) ranged from 25 to 250 pg/m(3). The concentrations of di-carboxylated C2-C5 and total C6-C10 in particles of atmospheric aerosols ranged from 91.9 to 240, 11.3 to 56.7, 9.2 to 49.2, 8.7 to 35.3 and n.d. to 37.8 ng/m(3), respectively. Oxalic acid (C2) was the dominant LMW-dicarboxylic acids detected in aerosol samples. The quantitative results were comparable to the results obtained by the off-line derivatization.

  6. Isotope enrichment

    International Nuclear Information System (INIS)

    Garbuny, M.

    1979-01-01

    The invention discloses a method for deriving, from a starting material including an element having a plurality of isotopes, derived material enriched in one isotope of the element. The starting material is deposited on a substrate at less than a critical submonatomic surface density, typically less than 10 16 atoms per square centimeter. The deposit is then selectively irradiated by a laser (maser or electronic oscillator) beam with monochromatic coherent radiation resonant with the one isotope causing the material including the one istope to escape from the substrate. The escaping enriched material is then collected. Where the element has two isotopes, one of which is to be collected, the deposit may be irradiated with radiation resonant with the other isotope and the residual material enriched in the one isotope may be evaporated from the substrate and collected

  7. A model of reaction field in gas-injected arc-in-water method to synthesize single-walled carbon nanohorns: Influence of water temperature

    International Nuclear Information System (INIS)

    Poonjarernsilp, Chantamanee; Sano, Noriaki; Tamon, Hajime; Charinpanitkul, Tawatchai

    2009-01-01

    The method to synthesize single-walled carbon nanohorns (SWCNHs) using gas-injected arc in water (GI-AIW) has been experimentally studied. GI-AIW is known as one of the cost-effective methods to obtain SWCNHs. It was revealed that the yield of SWCNHs significantly decreases with the increase in water temperature although the purity of SWCNHs is not dependent on the temperature change. Then the model of relevant reactions in the GI-AIW system was proposed by accounting the emission of carbon vapor, formation of SWCNHs, and diffusion of water vapor in three zones inside the cathode hole (arc plasma zone, quenching zone, and downstream zone). The side reaction between H 2 O and C produces H 2 gas and consumes a certain amount of carbon vapor, resulting in the hindered SWCNH formation. Moreover the observation of the optical spectra emitting from the arc plasma zone strongly supported that the H 2 generating reaction does not occur at arc plasma zone since N 2 flow can purge H 2 O out. The model proposed in this study can precisely explain the correlation between H 2 gas production and water temperature.

  8. Full scale calcium bromide injection with subsequent mercury oxidation and removal within wet flue gas desulphurization system: Experience at a 700 MW coal-fired power facility

    Science.gov (United States)

    Berry, Mark Simpson

    The Environmental Protection Agency promulgated the Mercury and Air Toxics Standards rule, which requires that existing power plants reduce mercury emissions to meet an emission rate of 1.2 lb/TBtu on a 30-day rolling average and that new plants meet a 0.0002 lb/GWHr emission rate. This translates to mercury removals greater than 90% for existing units and greater than 99% for new units. Current state-of-the-art technology for the control of mercury emissions uses activated carbon injected upstream of a fabric filter, a costly proposition. For example, a fabric filter, if not already available, would require a 200M capital investment for a 700 MW size unit. A lower-cost option involves the injection of activated carbon into an existing cold-side electrostatic precipitator. Both options would incur the cost of activated carbon, upwards of 3M per year. The combination of selective catalytic reduction (SCR) reactors and wet flue gas desulphurization (wet FGD) systems have demonstrated the ability to substantially reduce mercury emissions, especially at units that burn coals containing sufficient halogens. Halogens are necessary for transforming elemental mercury to oxidized mercury, which is water-soluble. Plants burning halogen-deficient coals such as Power River Basin (PRB) coals currently have no alternative but to install activated carbon-based approaches to control mercury emissions. This research consisted of investigating calcium bromide addition onto PRB coal as a method of increasing flue gas halogen concentration. The treated coal was combusted in a 700 MW boiler and the subsequent treated flue gas was introduced into a wet FGD. Short-term parametric and an 83-day longer-term tests were completed to determine the ability of calcium bromine to oxidize mercury and to study the removal of the mercury in a wet FGD. The research goal was to show that calcium bromine addition to PRB coal was a viable approach for meeting the Mercury and Air Toxics Standards rule

  9. Gas

    International Nuclear Information System (INIS)

    1996-01-01

    The French government has decided to modify the conditions of extension of local natural gas authorities to neighbouring districts. The European Union is studying the conditions of internal gas market with the objective of more open markets although considering public service requirements

  10. Experimental investigations of a four-stroke single cylinder direct injection diesel engine operated on dual fuel mode with producer gas as inducted fuel and Honge oil and its methyl ester (HOME) as injected fuels

    Energy Technology Data Exchange (ETDEWEB)

    Banapurmath, N.R.; Tewari, P.G. [Department of Mechanical Engineering, B.V.B. College of Engineering and Technology, Hubli 580031, Karnataka (India); Hosmath, R.S. [Department of Mechanical Engineering, K.L.E Society' s College of Engineering and Technology, Belgaum, Karnataka (India)

    2008-09-15

    In order to meet the energy requirements, there has been growing interest in alternative fuels like biodiesels, methyl alcohol, ethyl alcohol, biogas, hydrogen and producer gas to provide a suitable diesel oil substitute for internal combustion engines. Vegetable oils present a very promising alternative to diesel oil since they are renewable and have similar properties. Vegetable oils offer almost the same power output with slightly lower thermal efficiency when used in diesel engine [Srivastava A, Prasad R. Triglycerides-based diesel fuels. Renew Sustain Energy Rev 2000;4:111-33.; Vellguth G. Performance of vegetable oils and their monoesters as fuels for diesel engines. SAE 831358, 1983.; Demirbas A. Biodiesel production from vegetable oils via catalytic and non-catalytic supercritical methanol transesterification methods. Int J Prog Energy Combust Sci 2005;31:466-87.; Jajoo BN, Keoti RS. Evaluation of vegetable oils as supplementary fuels for diesel engines. In: Proceedings of the XV national conference on IC engines and combustion, Anna University Chennai, 1997.; Altin R, Cetinkaya S, Yucesu HS. The potential of using vegetable oil fuels as fuel for diesel engines. Int J Energy Convers Manage 2000;42:529-38, 248.; Gajendra Babu MK, Chandan Kumar Das LM. Experimental investigations on a Karanja oil methyl ester fuelled DI diesel engine. SAE 2006-01-0238, 2006.; Agarwal D, Kumar Agarwal A. Performance and emission characteristics of a Jatropha oil (preheated and blends) in a direct injection compression ignition engine. Int J Appl Therm Eng 2007;27:2314-23. ]. Research in this direction with edible oils have yielded encouraging results, but their use as fuel for diesel engine has limited applications due to higher domestic requirement [Scholl Kyle W, Sorenson Spencer C. Combustion Analysis of soyabean oil methyl ester in a direct injection diesel engine. SAE 930934, 1993.; Nwafor OMI. Effect of advanced injection timing on the performance of rapeseed oil in

  11. Validation of a method for simultaneous determination of menthol and methyl salicylate in pharmaceuticals by capillary gas chromatography with cool on-column injection.

    Science.gov (United States)

    Krzek, Jan; Czekaj, Janusz Sławomir; Rzeszutko, Włodzimierz

    2003-01-01

    The conditions for the identification and quantitative determination of menthol and methyl salicylate in ointment Balsamum Mentholi Compositum on a hydrocarbon-ester base (vaseline-lanolin), have been established by using capillary gas chromatography with cool on-column injection and flame ionization detection (FID). The good separation of menthol (tR = 7.2 min), methyl salicylate (tR = 8.7 min) and thymol (tR = 12.3 min) and camphor (tR = 6.0 min), used as alternative internal standards, beside vehiculum constituents (peak of tR = 15.8 min) was obtained. The method features a high sensitivity - detection limit for menthol and methyl salicylate was 0.1 ng and 5.0 ng, respectively, high accuracy, precision and recovery for active substances: 100.0% +/- 2.2%, when camphor was used as an internal standard.

  12. Measurement of runaway electron energy distribution function during high-Z gas injection into runaway electron plateaus in DIII-Da)

    Energy Technology Data Exchange (ETDEWEB)

    Hollmann, E. M. [University of California—San Diego, 9500 Gilman Dr., La Jolla, California 92093, USA; Parks, P. B. [General Atomics, PO Box 85608, San Diego, California 92186, USA; Commaux, N. [Oak Ridge National Laboratory, PO Box 2008, Oak Ridge, Tennessee 37831, USA; Eidietis, N. W. [General Atomics, PO Box 85608, San Diego, California 92186, USA; Moyer, R. A. [University of California—San Diego, 9500 Gilman Dr., La Jolla, California 92093, USA; Shiraki, D. [Oak Ridge National Laboratory, PO Box 2008, Oak Ridge, Tennessee 37831, USA; Austin, M. E. [Institute for Fusion Studies, University of Texas—Austin, 2100 San Jacinto Blvd, Austin, Texas 78712, USA; Lasnier, C. J. [Lawrence Livermore National Laboratory, 7000 East Ave, Livermore, California 94550, USA; Paz-Soldan, C. [General Atomics, PO Box 85608, San Diego, California 92186, USA; Rudakov, D. L. [University of California—San Diego, 9500 Gilman Dr., La Jolla, California 92093, USA

    2015-05-01

    The evolution of the runaway electron (RE) energy distribution function fεfε during massive gas injection into centered post-disruption runaway electron plateaus has been reconstructed. Overall, fεfε is found to be much more skewed toward low energy than predicted by avalanche theory. The reconstructions also indicate that the RE pitch angle θ is not uniform, but tends to be large at low energies and small θ ~0.1–0.2 at high energies. Overall power loss from the RE plateau appears to be dominated by collisions with background free and bound electrons, leading to line radiation. However, the drag on the plasma current appears to be dominated by collisions with impurity ions in most cases. Synchrotron emission appears not to be significant for overall RE energy dissipation but may be important for limiting the peak RE energy.

  13. Quantitative analysis of fragrance in selectable one dimensional or two dimensional gas chromatography-mass spectrometry with simultaneous detection of multiple detectors in single injection.

    Science.gov (United States)

    Tan, Hui Peng; Wan, Tow Shi; Min, Christina Liew Shu; Osborne, Murray; Ng, Khim Hui

    2014-03-14

    A selectable one-dimensional ((1)D) or two-dimensional ((2)D) gas chromatography-mass spectrometry (GC-MS) system coupled with flame ionization detector (FID) and olfactory detection port (ODP) was employed in this study to analyze perfume oil and fragrance in shower gel. A split/splitless (SSL) injector and a programmable temperature vaporization (PTV) injector are connected via a 2-way splitter of capillary flow technology (CFT) in this selectable (1)D/(2)D GC-MS/FID/ODP system to facilitate liquid sample injections and thermal desorption (TD) for stir bar sorptive extraction (SBSE) technique, respectively. The dual-linked injectors set-up enable the use of two different injector ports (one at a time) in single sequence run without having to relocate the (1)D capillary column from one inlet to another. Target analytes were separated in (1)D GC-MS/FID/ODP and followed by further separation of co-elution mixture from (1)D in (2)D GC-MS/FID/ODP in single injection without any instrumental reconfiguration. A (1)D/(2)D quantitative analysis method was developed and validated for its repeatability - tR; calculated linear retention indices (LRI); response ratio in both MS and FID signal, limit of detection (LOD), limit of quantitation (LOQ), as well as linearity over a concentration range. The method was successfully applied in quantitative analysis of perfume solution at different concentration level (RSD≤0.01%, n=5) and shower gel spiked with perfume at different dosages (RSD≤0.04%, n=5) with good recovery (96-103% for SSL injection; 94-107% for stir bar sorptive extraction-thermal desorption (SBSE-TD). Copyright © 2014 Elsevier B.V. All rights reserved.

  14. AEC determines uranium enrichment policy

    International Nuclear Information System (INIS)

    Anon.

    1992-01-01

    The Advisory Committee on Uranium Enrichment of the Atomic Energy Commission (AEC) has submitted a report to AEC chairman concerning the promotion of the introduction of advanced material, high performance centrifuges to replace conventional metallic drum centrifuges, and the development of next generation advanced centrifuges. The report also called for the postponement until around 1997 of the decision whether the development should be continued or not on atomic vapor laser isotope separation (AVLIS) and molecular laser isotope separation (MLIS) processes, as well as the virtual freezing of the construction of a chemical process demonstration plant. The report was approved by the AEC chairman in August. The uranium enrichment service market in the world will continue to be characterized by oversupply. The domestic situation of uranium enrichment supply-demand trend, progress of the expansion of Rokkasho enrichment plant, the trend in the development of gas centrifuge process and the basic philosophy of commercializing domestic uranium enrichment are reported. (K.I.)

  15. Prediction of major pollutants emission in direct injection dual-fuel diesel and natural-gas engines

    International Nuclear Information System (INIS)

    Pirouzpanah, V.; Kashani, B.O.

    2000-01-01

    The dual-fuel diesel engine is a conventional diesel engine in which much of the energy released, hence power, comes from the combustion of gaseous fuel such as natural gas. The exhaust emission characteristics of the dual-fuel diesel engine needs further refinements, particularly in terms of reduction of Unburnt Hydrocarbons and Carbon Monoxide (CO) emission, because the concentration of these pollutants are higher than that of the baseline diesel engine. Furthermore, the combustion process in a typical dual-fuel diesel engine tends to be complex, showing combination of the problems encountered both in diesel and spark ignition engines. In this work, a computer code has been modified for simulation of dual-fuel diesel engine combustion process. This model simulates dual-fuel diesel engine combustion by using a Multi-Zone Combustion Model for diesel pilot jet combustion and a conventional spark ignition combustion model for modelling of combustion of premixed gas/air charge. Also, in this model, there are four submodels for prediction of major emission pollutants such as: Unburnt Hydrocarbons, No, Co and soot which are emitted from dual-fuel diesel engine. For prediction of formation and oxidation rates of pollutants, relevant s conventional kinetically-controlled mechanisms and mass balances are used. the model has been verified by experimental data obtained from a heavy-duty truck and bus diesel engines. The comparison shows that, there exist good agreements between the experimental and predicted results from the dual-fuel diesel engine

  16. EVALUATIONS OF RADIONUCLIDES OF URANIUM, THORIUM, AND RADIUM ASSOCIATED WITH PRODUCED FLUIDS, PRECIPITATES, AND SLUDGES FROM OIL, GAS, AND OILFIELD BRINE INJECTION WELLS IN MISSISSIPPI

    Energy Technology Data Exchange (ETDEWEB)

    Charles Swann; John Matthews; Rick Ericksen; Joel Kuszmaul

    2004-03-01

    Naturally occurring radioactive materials (NORM) are known to be produced as a byproduct of hydrocarbon production in Mississippi. The presence of NORM has resulted in financial losses to the industry and continues to be a liability as the NORM-enriched scales and scale encrusted equipment is typically stored rather than disposed of. Although the NORM problem is well known, there is little publically available data characterizing the hazard. This investigation has produced base line data to fill this informational gap. A total of 329 NORM-related samples were collected with 275 of these samples consisting of brine samples. The samples were derived from 37 oil and gas reservoirs from all major producing areas of the state. The analyses of these data indicate that two isotopes of radium ({sup 226}Ra and {sup 228}Ra) are the ultimate source of the radiation. The radium contained in these co-produced brines is low and so the radiation hazard posed by the brines is also low. Existing regulations dictate the manner in which these salt-enriched brines may be disposed of and proper implementation of the rules will also protect the environment from the brine radiation hazard. Geostatistical analyses of the brine components suggest relationships between the concentrations of {sup 226}Ra and {sup 228}Ra, between the Cl concentration and {sup 226}Ra content, and relationships exist between total dissolved solids, BaSO{sub 4} saturation and concentration of the Cl ion. Principal component analysis points to geological controls on brine chemistry, but the nature of the geologic controls could not be determined. The NORM-enriched barite (BaSO{sub 4}) scales are significantly more radioactive than the brines. Leaching studies suggest that the barite scales, which were thought to be nearly insoluble in the natural environment, can be acted on by soil microorganisms and the enclosed radium can become bioavailable. This result suggests that the landspreading means of scale disposal

  17. Combustion Noise and Pollutants Prediction for Injection Pattern and Exhaust Gas Recirculation Tuning in an Automotive Common-Rail Diesel Engine

    Directory of Open Access Journals (Sweden)

    Arsie Ivan

    2015-01-01

    Full Text Available In the last years, emissions standards for internal combustion engines are becoming more and more restrictive, particularly for NOx and soot emissions from Diesel engines. In order to comply with these requirements, OEMs have to face with innovative combustion concepts and/or sophisticate after-treatment devices. In both cases, the role of the Engine Management System (EMS is increasingly essential, following the large number of actuators and sensors introduced and the need to meet customer expectations on performance and comfort. On the other hand, the large number of control variables to be tuned imposes a massive recourse to the experimental testing which is poorly sustainable in terms of time and money. In order to reduce the experimental effort and the time to market, the application of simulation models for EMS calibration has become fundamental. Predictive models, validated against a limited amount of experimental data, allow performing detailed analysis on the influence of engine control variables on pollutants, comfort and performance. In this paper, a simulation analysis on the impact of injection pattern and Exhaust Gas Recirculation (EGR rate on fuel consumption, combustion noise, NO and soot emissions is presented for an automotive Common-Rail Diesel engine. Simulations are accomplished by means of a quasi-dimensional multi-zone model of in-cylinder processes. Furthermore a methodology for in-cylinder pressure processing is presented to estimate combustion noise contribution to radiated noise. Model validation is carried out by comparing simulated in-cylinder pressure traces and exhaust emissions with experimental data measured at the test bench in steady-state conditions. Effects of control variables on engine performance, noise and pollutants are analyzed by imposing significant deviation of EGR rate and injection pattern (i.e. rail pressure, start-of-injection, number of injections. The results evidence that quasi-dimensional in

  18. The injection of biomethane produced from sludge from sewage stations into the French natural gas distribution network. Scientific and technical support report. Scientific and technical support related to the problem of injection of biomethane produced from sludges from sewage stations into the French natural gas distribution network

    International Nuclear Information System (INIS)

    Zdanevitch, Isabelle; Jaeg, Jean-Philippe; Leroux, Carole; Pernelet-Joly, Valerie; Solal, Cecilia; Saddoki, Sophia

    2013-04-01

    This report aimed at producing an assessment of health risks (for consumers as well as for professionals) related to the injection of biogas produced from water treatment stations into the natural gas transport and distribution network. Data on the chemical composition of raw bio-gases produced by sewage stations and of biomethane produced from sludge from these stations have been obtained from different sources and measurements. After a recall of works performed in answer to a first expertise mission which comprised an approach to the assessment of microbiological risks, this report presents the various data and their sources. It discusses the characterisation (i.e. the various components) of raw bio-gases and of biomethane produced from sludge from sewage stations, and of natural gas. The last part proposes an identification of risks through a qualitative approach

  19. Local gas injection as a scrape-off layer diagnostic on the Alcator C-Mod tokamak

    International Nuclear Information System (INIS)

    Jablonski, D.F.

    1996-05-01

    A capillary puffing array has been installed on Alcator C-Mod which allows localized introduction of gaseous species in the scrape-off layer. This system has been utilized in experiments to elucidate both global and local properties of edge transport. Deuterium fueling and recycling impurity screening are observed to be characterized by non-dimensional screening efficiencies which are independent of the location of introduction. In contrast, the behavior of non-recycling impurities is seen to be characterized by a screening time which is dependent on puff location. The work of this thesis has focused on the use of the capillary array with a camera system which can view impurity line emission plumes formed in the region of an injection location. The ionic plumes observed extend along the magnetic field line with a comet-like asymmetry, indicative of background plasma ion flow. The flow is observed to be towards the nearest strike-point, independent of x-point location, magnetic field direction, and other plasma parameters. While the axes of the plumes are generally along the field line, deviations are seen which indicate cross-field ion drifts. A quasi-two dimensional fluid model has been constructed to use the plume shapes of the first charge state impurity ions to extract information about the local background plasma, specifically the temperature, parallel flow velocity, and radial electric field. Through comparisons of model results with those of a three dimensional Monte Carlo code, and comparisons of plume extracted parameters with scanning probe measurements, the efficacy of the model is demonstrated. Plume analysis not only leads to understandings of local edge impurity transport, but also presents a novel diagnostic technique

  20. Local gas injection as a scrape-off layer diagnostic on the Alcator C-Mod tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Jablonski, David F. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

    1996-05-01

    A capillary puffing array has been installed on Alcator C-Mod which allows localized introduction of gaseous species in the scrape-off layer. This system has been utilized in experiments to elucidate both global and local properties of edge transport. Deuterium fueling and recycling impurity screening are observed to be characterized by non-dimensional screening efficiencies which are independent of the location of introduction. In contrast, the behavior of non-recycling impurities is seen to be characterized by a screening time which is dependent on puff location. The work of this thesis has focused on the use of the capillary array with a camera system which can view impurity line emission plumes formed in the region of an injection location. The ionic plumes observed extend along the magnetic field line with a comet-like asymmetry, indicative of background plasma ion flow. The flow is observed to be towards the nearest strike-point, independent of x-point location, magnetic field direction, and other plasma parameters. While the axes of the plumes are generally along the field line, deviations are seen which indicate cross-field ion drifts. A quasi-two dimensional fluid model has been constructed to use the plume shapes of the first charge state impurity ions to extract information about the local background plasma, specifically the temperature, parallel flow velocity, and radial electric field. Through comparisons of model results with those of a three dimensional Monte Carlo code, and comparisons of plume extracted parameters with scanning probe measurements, the efficacy of the model is demonstrated. Plume analysis not only leads to understandings of local edge impurity transport, but also presents a novel diagnostic technique.

  1. An experimental investigation on engine performance and emissions of a single cylinder diesel engine using hydrogen as inducted fuel and diesel as injected fuel with exhaust gas recirculation

    Energy Technology Data Exchange (ETDEWEB)

    Bose, Probir Kumar; Maji, Dines [Department of Mechanical Engineering, Jadavpur University, Heat Power Laboratory, Kolkata 32, West Bengal (India)

    2009-06-15

    Fast depletion of fossil fuels is demanding an urgent need to carry out research work to find out the viable alternative fuels for meeting sustainable energy demand with minimum environmental impact. In the future, our energy systems will need to be renewable and sustainable, efficient and cost-effective, convenient and safe. The technology for producing hydrogen from a variety of resources, including renewable, is evolving and that will make hydrogen energy system as cost-effective. Hydrogen safety concerns are not the cause for fear but they simply are different than those we are accustomed to with gasoline, diesel and other fossil fuels. For the time being full substitution of diesel with hydrogen is not convenient but use of hydrogen in a diesel engine in dual fuel mode is possible. So Hydrogen has been proposed as the perfect fuel for this future energy system. The experiment is conducted using diesel-hydrogen blend. A timed manifold induction system which is electronically controlled has been developed to deliver hydrogen on to the intake manifold. The solenoid valve is activated by the new technique of taking signal from the rocker arm of the engine instead of cam actuation mechanism. In the present investigation hydrogen-enriched air has been used in a diesel engine with hydrogen flow rate at 0.15 kg/h. As diesel is substituted and hydrogen is inducted, the NO{sub x} emission is increased. In order to reduce NO{sub x} emission an EGR system has been developed. In the EGR system a lightweight EGR cooler has been used instead of bulky heat exchanger. In this experiment performance parameters such as brake thermal efficiency, volumetric efficiency, BSEC are determined and emissions such as oxides of nitrogen, carbon dioxide, carbon monoxide, hydrocarbon, smoke and exhaust gas temperature are measured. Dual fuel operation with hydrogen induction coupled with exhaust gas recirculation results in lowered emission level and improved performance level compared to

  2. Effects on hemodynamics and gas exchange of omega-3 fatty acid-enriched lipid emulsion in acute respiratory distress syndrome (ARDS: a prospective, randomized, double-blind, parallel group study

    Directory of Open Access Journals (Sweden)

    Sacanell Judit

    2008-10-01

    Full Text Available Abstract Introduction We investigated the effects on hemodynamics and gas exchange of a lipid emulsion enriched with omega-3 fatty acids in patients with ARDS. Methods The design was a prospective, randomized, double-blind, parallel group study in our Intensive Medicine Department of Vall d'Hebron University Hospital (Barcelona-Spain. We studied 16 consecutive patients with ARDS and intolerance to enteral nutrition (14 men and 2 women; mean age: 58 ± 13 years; APACHE II score: 17.8 ± 2.3; Lung Injury Score: 3.1 ± 0.5; baseline PaO2/FiO2 ratio: 149 ± 40. Patients were randomized into 2 groups: Group A (n = 8 received the study emulsion Lipoplus® 20%, B.Braun Medical (50% MCT, 40% LCT, 10% ω-3; Group B (n = 8 received the control emulsion Intralipid® Fresenius Kabi (100% LCT. Lipid emulsions were administered during 12 h at a dose of 0.12 g/kg/h. Measurements of the main hemodynamic and gas exchange parameters were made at baseline (immediately before administration of the lipid emulsions, every hour during the lipid infusion, at the end of administration, and six hours after the end of administration lipid infusion. Results No statistically significant changes were observed in the different hemodynamic values analyzed. Likewise, the gas exchange parameters did not show statistically significant differences during the study. No adverse effect attributable to the lipid emulsions was seen in the patients analyzed. Conclusion The lipid emulsion enriched with omega-3 fatty acids was safe and well tolerated in short-term administration to patients with ARDS. It did not cause any significant changes in hemodynamic and gas exchange parameters. Trial registration ISRCTN63673813

  3. Culturable prokaryotic diversity of deep, gas hydrate sediments: first use of a continuous high-pressure, anaerobic, enrichment and isolation system for subseafloor sediments (DeepIsoBUG)

    OpenAIRE

    Parkes, R John; Sellek, Gerard; Webster, Gordon; Martin, Derek; Anders, Erik; Weightman, Andrew J; Sass, Henrik

    2009-01-01

    Deep subseafloor sediments may contain depressurization-sensitive, anaerobic, piezophilic prokaryotes. To test this we developed the DeepIsoBUG system, which when coupled with the HYACINTH pressure-retaining drilling and core storage system and the PRESS core cutting and processing system, enables deep sediments to be handled without depressurization (up to 25 MPa) and anaerobic prokaryotic enrichments and isolation to be conducted up to 100 MPa. Here, we describe the system and its first use...

  4. Determination of low-molecular-weight dicarboxylic acids in atmospheric aerosols by injection-port derivatization and gas chromatography-mass spectrometry

    Science.gov (United States)

    Ding, W.; Hsu, C.

    2008-12-01

    Currently, the investigations on aerosol water-soluble organic compounds (WSOCs) formed by burning biomass have become increasingly concerned with the role of these compounds in atmospheric chemistry and their effect on climate, because they have great potential to influence cloud formation, precipitation, and climate on both global and regional scales. Of these compounds, low-molecular weight (LMW) dicarboxylic acids (from C2 to C10) have attracted the most interest because of their properties as specific tracers for the burning of biomass. In this study, a modified injection-port derivatization and gas chromatography - mass spectrometry method was developed and evaluated for rapid determination of LMW dicarboxylic acids in atmospheric aerosol samples. The parameters related to the derivatization process (i.e., type of ion-pair reagent, injection-port temperature and concentration of ion-pair reagent) were optimized. Tetrabutylammonium hydroxide (TBA-OH) dissolved in methanol used as the ion-pair solution gave excellent yield for di-butyl ester low-molecular weight derivatives. Solid-phase extraction method instead of rotary evaporation was used to concentrate analytes from filter extracts. The recovery from filter extracts ranged from 67 to 86% with relative standard deviation (RSD) less than 13%. The concentrations of dicarboxylated C2, C3, C4, C5 and C6-C10 in atmospheric aerosols ranged from 91-240 ng/m3, 11-56 ng/m3, 12-49 ng/m3, 8-35 ng/m3 and n.d. to 17 ng/m3, respectively. Oxalic (C2) acid was the dominant dicarboxylic acids detected in aerosol samples. The total concentrations of the LMW dicarboxylic acids (from C2 to C10) correspond to 2.2 to 2.6% of the total aerosol mass.

  5. Testosterone Injection

    Science.gov (United States)

    ... typical male characteristics. Testosterone injection works by supplying synthetic testosterone to replace the testosterone that is normally ... as a pellet to be injected under the skin.Testosterone injection may control your symptoms but will ...

  6. Method and apparatus for enrichment or upgrading heavy water

    International Nuclear Information System (INIS)

    Butler, J.P.; Hammerli, M.

    1979-01-01

    A method and apparatus for upgrading and final enrichment of heavy water are described, comprising means for contacting partially enriched heavy water feed in a catalyst column with hydrogen gas (essentially D 2 ) originating in an electrolysis cell so as to enrich the feed water with deuterium extracted from the electrolytic hydrogen gas and means for passing the deuterium enriched water to the electrolysis cell. (author)

  7. Characterization of sp3bond content of carbon films deposited by high power gas injection magnetron sputtering method by UV and VIS Raman spectroscopy.

    Science.gov (United States)

    Zdunek, Krzysztof; Chodun, Rafał; Wicher, Bartosz; Nowakowska-Langier, Katarzyna; Okrasa, Sebastian

    2018-04-05

    This paper presents the results of investigations of carbon films deposited by a modified version of the magnetron sputtering method - HiPGIMS (High Power Gas Injection Magnetron Sputtering). In this experiment, the magnetron system with inversely polarized electrodes (sputtered cathode at ground potential and positively biased, spatially separated anode) was used. This arrangement allowed us to conduct the experiment using voltages ranging from 1 to 2kV and a power supply system equipped with 25/50μF capacitor battery. Carbon films were investigated by VIS/UV Raman spectroscopy. Sp 3 /sp 2 bonding ratio was evaluated basing the elementary components of registered spectra. Our investigation showed that sp 3 bond content increases with discharge power but up to specific value only. In extreme conditions of generating plasma impulses, we detected a reversed relation of the sp 3 /sp 2 ratio. In our opinion, a energy of plasma pulse favors nucleation of a sp 3 phase because of a relatively higher ionization state but in extreme cases the influence of energy is reversed. Copyright © 2018 Elsevier B.V. All rights reserved.

  8. Comparison of Airway Responses Induced in a Mouse Model by the Gas and Particulate Fractions of Gasoline Direct Injection Engine Exhaust

    Directory of Open Access Journals (Sweden)

    Caitlin L. Maikawa

    2018-03-01

    Full Text Available Diesel exhaust has been associated with asthma, but its response to other engine emissions is not clear. The increasing prevalence of vehicles with gasoline direct injection (GDI engines motivated this study, and the objective was to evaluate pulmonary responses induced by acute exposure to GDI engine exhaust in an allergic asthma murine model. Mice were sensitized with an allergen to induce airway hyperresponsiveness or treated with saline (non-allergic group. Animals were challenged for 2-h to exhaust from a laboratory GDI engine operated at conditions equivalent to a highway cruise. Exhaust was filtered to assess responses induced by the particulate and gas fractions. Short-term exposure to particulate matter from GDI engine exhaust induced upregulation of genes related to polycyclic aromatic hydrocarbon (PAH metabolism (Cyp1b1 and inflammation (TNFα in the lungs of non-allergic mice. High molecular weight PAHs dominated the particulate fraction of the exhaust, and this response was therefore likely attributable to the presence of these PAHs. The particle fraction of GDI engine exhaust further contributed to enhanced methacholine responsiveness in the central and peripheral tissues in animals with airway hyperresponsiveness. As GDI engines gain prevalence in the vehicle fleet, understanding the health impacts of their emissions becomes increasingly important.

  9. Comparison of Airway Responses Induced in a Mouse Model by the Gas and Particulate Fractions of Gasoline Direct Injection Engine Exhaust.

    Science.gov (United States)

    Maikawa, Caitlin L; Zimmerman, Naomi; Ramos, Manuel; Shah, Mittal; Wallace, James S; Pollitt, Krystal J Godri

    2018-03-01

    Diesel exhaust has been associated with asthma, but its response to other engine emissions is not clear. The increasing prevalence of vehicles with gasoline direct injection (GDI) engines motivated this study, and the objective was to evaluate pulmonary responses induced by acute exposure to GDI engine exhaust in an allergic asthma murine model. Mice were sensitized with an allergen to induce airway hyperresponsiveness or treated with saline (non-allergic group). Animals were challenged for 2-h to exhaust from a laboratory GDI engine operated at conditions equivalent to a highway cruise. Exhaust was filtered to assess responses induced by the particulate and gas fractions. Short-term exposure to particulate matter from GDI engine exhaust induced upregulation of genes related to polycyclic aromatic hydrocarbon (PAH) metabolism ( Cyp1b1 ) and inflammation ( TNFα ) in the lungs of non-allergic mice. High molecular weight PAHs dominated the particulate fraction of the exhaust, and this response was therefore likely attributable to the presence of these PAHs. The particle fraction of GDI engine exhaust further contributed to enhanced methacholine responsiveness in the central and peripheral tissues in animals with airway hyperresponsiveness. As GDI engines gain prevalence in the vehicle fleet, understanding the health impacts of their emissions becomes increasingly important.

  10. Development of a bar adsorptive micro-extraction-large-volume injection-gas chromatography-mass spectrometric method for pharmaceuticals and personal care products in environmental water matrices.

    Science.gov (United States)

    Neng, N R; Nogueira, J M F

    2012-01-01

    The combination of bar adsorptive micro-extraction using activated carbon (AC) and polystyrene-divinylbenzene copolymer (PS-DVB) sorbent phases, followed by liquid desorption and large-volume injection gas chromatography coupled to mass spectrometry, under selected ion monitoring mode acquisition, was developed for the first time to monitor pharmaceutical and personal care products (PPCPs) in environmental water matrices. Assays performed on 25 mL water samples spiked (100 ng L(-1)) with caffeine, gemfibrozil, triclosan, propranolol, carbamazepine and diazepam, selected as model compounds, yielded recoveries ranging from 74% to 99% under optimised experimental conditions (equilibrium time, 16 h (1,000 rpm); matrix characteristics: pH 5, 5% NaCl for AC phase; LD: methanol/acetonitrile (1:1), 45 min). The analytical performance showed good precision (RSD 0.99), where the PS-DVB sorbent phase showed a much better efficiency. By using the standard addition methodology, the application of the present analytical approach on tap, ground, sea, estuary and wastewater samples allowed very good performance at the trace level. The proposed method proved to be a suitable sorption-based micro-extraction alternative for the analysis of priority pollutants with medium-polar to polar characteristics, showing to be easy to implement, reliable, sensitive and requiring a low sample volume to monitor PPCPs in water matrices.

  11. Characterization of sp3 bond content of carbon films deposited by high power gas injection magnetron sputtering method by UV and VIS Raman spectroscopy

    Science.gov (United States)

    Zdunek, Krzysztof; Chodun, Rafał; Wicher, Bartosz; Nowakowska-Langier, Katarzyna; Okrasa, Sebastian

    2018-04-01

    This paper presents the results of investigations of carbon films deposited by a modified version of the magnetron sputtering method - HiPGIMS (High Power Gas Injection Magnetron Sputtering). In this experiment, the magnetron system with inversely polarized electrodes (sputtered cathode at ground potential and positively biased, spatially separated anode) was used. This arrangement allowed us to conduct the experiment using voltages ranging from 1 to 2 kV and a power supply system equipped with 25/50 μF capacitor battery. Carbon films were investigated by VIS/UV Raman spectroscopy. Sp3/sp2 bonding ratio was evaluated basing the elementary components of registered spectra. Our investigation showed that sp3 bond content increases with discharge power but up to specific value only. In extreme conditions of generating plasma impulses, we detected a reversed relation of the sp3/sp2 ratio. In our opinion, a energy of plasma pulse favors nucleation of a sp3 phase because of a relatively higher ionization state but in extreme cases the influence of energy is reversed.

  12. Enrichment of boron 10

    International Nuclear Information System (INIS)

    Coutinho, C.M.M.; Rodrigues Filho, J.S.R.; Umeda, K.; Echternacht, M.V.

    1990-01-01

    A isotopic separation pilot plant with five ion exchange columns interconnected in series were designed and built in the IEN. The columns are charged with a strong anionic resin in its alkaline form. The boric acid solution is introduced in the separation columns until it reaches a absorbing zone length which is sufficient to obtain the desired boron-10 isotopic concentration. The boric acid absorbing zone movement is provided by the injection of a diluted hydrochloric acid solution, which replace the boric acid throughout the columns. The absorbing zone equilibrium length is proportional to its total length. The enriched boron-10 and the depleted boron are located in the final boundary and in the initial position of the absorbing zones, respectively. (author)

  13. Gas threshold pressure test performed at the Mont Terri Rock Laboratory (Switzerland): experimental data and data analysis; Essais d'injection de gaz dans les argiles a opalinus du Laboratoire souterrain du Mont Terre (Suisse): donnees et interpretation

    Energy Technology Data Exchange (ETDEWEB)

    Croise, J.; Mayer, G. [Colenco Power Engineering AG, Groundwater Protection and Waste Disposal, Baden (Switzerland); Marschall, P. [NAGRA, National Cooperative for the Disposal of Radioactive Waste, Wettingen (Switzerland); Matray, J.M. [Institut de Radioprotection et de Surete Nucleaire (IRSN), 92 - Fontenay-aux-Roses (France); Tanaka, T. [Obayashi Corporation, Tokyo (Japan); Vogel, P. [Bundesanstalt fuer Geowissenschaften und Rohstoffe, Hannover (Germany)

    2006-09-15

    Migration of gases in argillaceous formations increasingly attracts the attention of various geo-scientific disciplines for purposes like CO{sub 2} sequestration, gas storage in geological formations and disposal of hazardous wastes. Quantitative assessment of gas transport in such ultra-low permeability formations requires information on gas transport properties of the argillaceous formation. A series of hydro- and gas tests in boreholes was performed at the Mont Terri Rock Laboratory in Switzerland to investigate gas transport in the Opalinus Clay, an indurated clay formation of Jurassic age. This paper presents the results of a comprehensive test campaign in the shaly facies of the Opalinus Clay, comprising a 'classical' hydro-test with water injections followed by pressure recovery sequences and an extended gas threshold pressure test. A detailed interpretation of both the hydraulic and gas test sequences was conducted using numerical simulations for the data analysis (software TOUGH2/iTOUGH2). In contrast to former test analyses, the sequential interpretation of the hydro- and gas test sequences provided a consistent set of single-phase hydraulic parameters and two-phase flow parameters. The use of independent information from laboratory testing (porosity, capillary pressure curves) constrained distinctly the inverse problem of parameter fitting. Discrimination between different parametric models of the relative permeability was impaired by inherent limitations of the field data due to non-ideal test conditions. Nevertheless, a classical two-phase flow type capillary pressure - relative permeability relationship based on the Van Genuchten - Mualem approach was found to be valid. A supplementary design study was conducted to optimise the test procedures to better distinguish between relative permeability models. It is shown that long term (> 1 year) injection tests are more adequate to constrain the models. This finding is important for the design of

  14. Uranium enrichment. 1980 annual report

    International Nuclear Information System (INIS)

    1981-05-01

    This report contains data and related information on the production of enriched uranium at the gaseous diffusion plants and an update on the construction and project control center for the gas centrifuge plant. Power usage at the gaseous diffusion plants is illustrated. The report contains several glossy color pictures of the plants and processes described. In addition to gaseous diffusion and the centrifuge process, three advanced isotope separation process are now being developed. The business operation of the enrichment plants is described; charts on revenue, balance sheets, and income statements are included

  15. Intraperitoneal pressure and volume of gas injected as effective parameters of the correct position of the Veress needle during creation of pneumoperitoneum.

    Science.gov (United States)

    Azevedo, João L M C; Azevedo, Otavio C; Sorbello, Albino A; Becker, Otavio M; Hypolito, Otavio; Freire, Dalmer; Miyahira, Susana; Guedes, Afonso; Azevedo, Glicia C

    2009-12-01

    The aim of this work was to establish reliable parameters of the correct position of the Veress needle in the peritoneal cavity during creation of pneumoperitoneum. The Veress needle was inserted into the peritoneal cavity of 100 selected patients, and a carbon-dioxide flow rate of 1.2 L/min and a maximum pressure of 12 mm Hg were established. Intraperitoneal pressure (IP) and the volume of gas injected (VG) were recorded at the beginning of insufflation and at every 20 seconds. Correlations were established for pressure and volume in function of time. Values of IP and VG were predicted at 1, 2, 3, and 4 minutes of insufflation, by applying the following formulas: IP = 2.3083 + 0.0266 x time +8.3 x 10(-5) x time(2) - 2.44 x 10(-7) x time(3); and VG = 0.813 + 0.0157 x time. A strong correlation was observed between IP and preestablished time points during creation of the pneumoperitoneum, as well as between VG and preestablished time points during creation of the pneumoperitoneum, with a coefficient of determination of 0.8011 for IP and of 0.9604 for VG. The predicted values were as follows: 1 minute = 4.15; 2 minutes = 6.27; 3 minutes = 8.36; and 4 minutes = 10.10 for IP (mm Hg); and 1 minute = 1.12; 2 minutes = 2.07; 3 minutes = 3.01; and 4 minutes = 3.95 for VG (L). Values of IP and VG at given time points during insufflation for creation of the pneumoperitoneum, using the Veress needle, can be effective parameters to determine whether the needle is correctly positioned in the peritoneal cavity.

  16. Flow injection analysis of ethyl xanthate by gas diffusion and UV detection as CS2 for process monitoring of sulfide ore flotation.

    Science.gov (United States)

    Cordeiro, Thiago G; Hidalgo, Pilar; Gutz, Ivano G R; Pedrotti, Jairo J

    2010-07-15

    A sensitive and robust analytical method for spectrophotometric determination of ethyl xanthate, CH(3)CH(2)OCS(2)(-) at trace concentrations in pulp solutions from froth flotation process is proposed. The analytical method is based on the decomposition of ethyl xanthate, EtX(-), with 2.0 mol L(-1) HCl generating ethanol and carbon disulfide, CS(2). A gas diffusion cell assures that only the volatile compounds diffuse through a PTFE membrane towards an acceptor stream of deionized water, thus avoiding the interferences of non-volatile compounds and suspended particles. The CS(2) is selectively detected by UV absorbance at 206 nm (epsilon=65,000 L mol(-1) cm(-1)). The measured absorbance is directly proportional to EtX(-) concentration present in the sample solutions. The Beer's law is obeyed in a 1x10(-6) to 2x10(-4) mol L(-1) concentration range of ethyl xanthate in the pulp with an excellent correlation coefficient (r=0.999) and a detection limit of 3.1x10(-7) mol L(-1), corresponding to 38 microg L(-1). At flow rates of 200 microL min(-1) of the donor stream and 100 microL min(-1) of the acceptor channel a sampling rate of 15 injections per hour could be achieved with RSDapplications demonstrate the versatility of the FIA method: (i) evaluation the free EtX(-) concentration during a laboratory study of the EtX(-) adsorption capacity on pulverized sulfide ore (pyrite) and (ii) monitoring of EtX(-) at different stages (from starting load to washing effluents) of a flotation pilot plant processing a Cu-Zn sulfide ore. Copyright 2010 Elsevier B.V. All rights reserved.

  17. The gas chromatographic determination of volatile fatty acids in wastewater samples: evaluation of experimental biases in direct injection method against thermal desorption method.

    Science.gov (United States)

    Ullah, Md Ahsan; Kim, Ki-Hyun; Szulejko, Jan E; Cho, Jinwoo

    2014-04-11

    The production of short-chained volatile fatty acids (VFAs) by the anaerobic bacterial digestion of sewage (wastewater) affords an excellent opportunity to alternative greener viable bio-energy fuels (i.e., microbial fuel cell). VFAs in wastewater (sewage) samples are commonly quantified through direct injection (DI) into a gas chromatograph with a flame ionization detector (GC-FID). In this study, the reliability of VFA analysis by the DI-GC method has been examined against a thermal desorption (TD-GC) method. The results indicate that the VFA concentrations determined from an aliquot from each wastewater sample by the DI-GC method were generally underestimated, e.g., reductions of 7% (acetic acid) to 93.4% (hexanoic acid) relative to the TD-GC method. The observed differences between the two methods suggest the possibly important role of the matrix effect to give rise to the negative biases in DI-GC analysis. To further explore this possibility, an ancillary experiment was performed to examine bias patterns of three DI-GC approaches. For instance, the results of the standard addition (SA) method confirm the definite role of matrix effect when analyzing wastewater samples by DI-GC. More importantly, their biases tend to increase systematically with increasing molecular weight and decreasing VFA concentrations. As such, the use of DI-GC method, if applied for the analysis of samples with a complicated matrix, needs a thorough validation to improve the reliability in data acquisition. Copyright © 2014 Elsevier B.V. All rights reserved.

  18. Computed Tomography Demonstration of the Production and Distribution of Oxygen Gas Following Intratumoral Injection of a New Radiosensitizer (KORTUC) for Patients with Breast Cancer-Is Intratumoral Injection Not an Ideal Approach to Solve the Major Problem of Tumor Hypoxia in Radiotherapy?

    Science.gov (United States)

    Hayashi, Naoya; Ogawa, Yasuhiro; Kubota, Kei; Okino, Kazuhiro; Akima, Ryo; Morita-Tokuhiro, Shiho; Tsuzuki, Akira; Yaogawa, Shin; Nishioka, Akihito; Miyamura, Mitsuhiko

    2016-04-01

    We previously developed a new enzyme-targeting radiosensitization treatment named Kochi Oxydol-Radiation Therapy for Unresectable Carcinomas, Type II (KORTUC II), which contains hydrogen peroxide and sodium hyaluronate for injection into various types of tumors. For breast cancer treatment, the radiosensitization agent was injected into the tumor tissue twice a week under ultrasonographic guidance, immediately prior to each administration of radiation therapy. At approximately three hours after the second or third injection, computed tomography (CT) was performed to confirm the production and distribution of oxygen gas generated from the KORTUC radiosensitization agent by catalysis of peroxidases contained mainly in tumor tissue. The purpose of this study was to demonstrate that tumor hypoxia could be overcome by such a procedure and to evaluate the method of intratumoral injection in terms of confirming oxygen distribution in the target tumor tissue and around the tumor to be visualized on dedicated CT imaging. Three-dimensional reconstructed maximum intensity projection imaging of contrast-enhanced breast magnetic resonance imaging was used to compare the position of the tumor and that of the generated oxygen. Distributed oxygen gas was confirmed in the tumor tissue and around it in all 10 patients examined in the study. A region of oxygen gas was measured as an average value of -457.2 Hounsfield units (HU) as a region of interest. A slightly increased HU value compared to the density of air or oxygen was considered due to the presence of tumor tissue in the low-density area on 5-mm-thick reconstructed CT imaging. The results of this study showed that intratumoral oxygen was successfully produced by intratumoral KORTUC injection under ultrasonographic guidance, and that tumor hypoxia, which is considered a main cause of radioresistance in currently used Linac (linear accelerator) radiation therapy for malignant neoplasms, could be resolved by this method.

  19. Cefoxitin Injection

    Science.gov (United States)

    ... injection is used to treat infections caused by bacteria including pneumonia and other lower respiratory tract (lung) infections; and urinary tract, abdominal (stomach area), female reproductive organs, blood, ... by killing bacteria.Antibiotics such as cefoxitin injection will not work ...

  20. Golimumab Injection

    Science.gov (United States)

    ... damaged, and do not use an auto-injection device if the security seal is broken. Look through the viewing window on the prefilled syringe or auto-injection device. The liquid inside should be clear and colorless ...

  1. Doxycycline Injection

    Science.gov (United States)

    ... may have been exposed to anthrax in the air. Doxycycline injection is in a class of medications ... decrease the effectiveness of hormonal contraceptives (birth control pills, patches, rings, or injections). Talk to your doctor ...

  2. Abaloparatide Injection

    Science.gov (United States)

    ... injection may cause osteosarcoma (bone cancer) in laboratory rats. It is not known whether abaloparatide injection increases ... too have too much calcium in the blood, hyperparathyroidism (condition in which the body produces too much ...

  3. Paliperidone Injection

    Science.gov (United States)

    Paliperidone extended-release injections (Invega Sustenna, Invega Trinza) are used to treat schizophrenia (a mental illness that ... interest in life, and strong or inappropriate emotions). Paliperidone extended-release injection (Invega Sustenna) is also used ...

  4. Doripenem Injection

    Science.gov (United States)

    ... injection is in a class of medications called carbapenem antibiotics. It works by killing bacteria.Antibiotics such ... if you are allergic to doripenem injection; other carbapenem antibiotics such as imipenem/cilastatin (Primaxin) or meropenem ( ...

  5. Ceftriaxone Injection

    Science.gov (United States)

    Ceftriaxone injection is used to treat certain infections caused by bacteria such as gonorrhea (a sexually transmitted ... skin, urinary tract, blood, bones, joints, and abdomen. Ceftriaxone injection is also sometimes given before certain types ...

  6. Nalbuphine Injection

    Science.gov (United States)

    ... injection is in a class of medications called opioid agonist-antagonists. It works by changing the way ... suddenly stop using nalbuphine injection, you may experience withdrawal symptoms including restlessness; teary eyes; runny nose; yawning; ...

  7. Naltrexone Injection

    Science.gov (United States)

    ... Videos & Tools Español You Are Here: Home → Drugs, Herbs and Supplements → Naltrexone Injection URL of this page: ... become depressed and sometimes try to harm or kill themselves. Receiving naltrexone injection does not decrease the ...

  8. Production of gas from coal seams in the Upper Silesian Coal Basin in Poland in the post-injection period of an ECBM pilot site

    NARCIS (Netherlands)

    Bergen, F. van; Krzystolik, P.; Wageningen, N. van; Pagnier, H.; Jura, B.; Skiba, J.; Winthaegen, P.; Kobiela, Z.

    2009-01-01

    A pilot site for CO2 storage in coal seams was set-up in the Upper Silesian Coal Basin in Poland in the scope of the RECOPOL project, funded by the European Commission. About 760 tons CO2 were injected into the reservoir from August 2004 to June 2005. Breakthrough of the injected CO2 was

  9. Synthesis of chemically-modified single-walled carbon nanotubes by counter-current ammonia gas injection into the induction thermal plasma process

    Science.gov (United States)

    Shahverdi, Ali

    Pristine single-walled carbon nanotubes (SWCNTs) are poorly dispersible and insoluble in many solvents and need to be chemically modified prior to their use in many applications. This work is focused on the investigation of the synthesis of chemically modified SWCNTs material through an in situ approach. The main objectives of the presented research are: 1) to explore the in situ chemical process during the synthesis of SWCNT and 2) to closely examine the effect of a reactive environment on SWCNTs. Effects of the catalyst type and content on the SWCNTs final product, synthesized by induction thermal plasma (ITP), were studied to replace toxic cobalt (Co) in the feedstock. In this regard, three different catalyst mixtures (i.e. Ni-Y2O3, Ni-Co-Y2O3, and Ni-Mo-Y2O3) were used. Experimental results showed that the catalyst type affects the quality of the SWCNT final product. Similar quality SWCNTs can be produced when the same amount of Co was replaced by Ni. Moreover, the results observed in this experimental work were further explained by thermodynamic calculation results. Thermogravimetry (TG) was used throughout the work to characterize the SWCNTs product. TG was firstly standardized by studying the effects of three main instrumental parameters (temperature ramp, TR, initial mass of the sample, IM, and gas flow rate, FR) on the Tonset and full-width half maximum (FWHM) obtained from TG and derivative TG graphs of carbon black, respectively. Therefore, a two-level factorial statistical design was performed. The statistical analysis showed that the effect of TR, IM, and to a lower extent, FR, is significant on FWHM and insignificant on Tonset. A methodology was then developed based upon the SWCNTs synthesis using the ITP system, through an in situ chemistry approach. Ammonia (NH3) was selected and counter-currently injected into the ITP reactor at three different flow rates and by four different nozzle designs. Numerical simulation indicated a better mixing of NH3 in

  10. Influence of the technique for injection of flue gas and the configuration of the swirl burner throat on combustion of gaseous fuel and formation of nitrogen oxides in the flame

    Science.gov (United States)

    Dvoinishnikov, V. A.; Khokhlov, D. A.; Knyaz'kov, V. P.; Ershov, A. Yu.

    2017-05-01

    How the points at which the flue gas was injected into the swirl burner and the design of the burner outlet influence the formation and development of the flame in the submerged space, as well as the formation of nitrogen oxides in the combustion products, have been studied. The object under numerical investigation is the flame of the GMVI combined (oil/gas) burner swirl burner fitted with a convergent, biconical, cylindrical, or divergent throat at the burner outlet with individual supply of the air and injection of the gaseous fuel through tubing. The burners of two designs were investigated; they differ by the absence or presence of an inlet for individual injection of the flue gas. A technique for numerical simulation of the flame based on the CFD methods widely used in research of this kind underlies the study. Based on the summarized results of the numerical simulation of the processes that occur in jet flows, the specific features of the aerodynamic pattern of the flame have been established. It is shown that the flame can be conventionally divided into several sections over its length in all investigations. The lengths of each of the sections, as well as the form of the fields of axial velocity, temperatures, concentrations of the fuel, oxygen, and carbon and nitrogen oxides, are different and determined by the design features of the burner, the flow rates of the agent, and the compositions of the latter in the burner ducts as well as the configuration of the burner throat and the temperature of the environment. To what degree the burner throat configuration and the techniques for injection of the flue gas at different ambient temperatures influence the formation of nitrogen oxides has been established. It is shown that the supply of the recirculation of flue gas into the fuel injection zone enables a considerable reduction in the formation of nitrogen oxides in the flame combustion products. It has been established that the locations of the zones of

  11. Other enrichment related contracts

    International Nuclear Information System (INIS)

    Hall, J.C.

    1978-01-01

    In addition to long-term enrichment contracts, DOE has other types of contracts: (1) short-term, fixed-commitment enrichment contract; (2) emergency sales agreement for enriched uranium; (3) feed material lease agreement; (4) enriched uranium storage agreement; and (5) feed material usage agreement

  12. Gas chromatography-flame ionization determination of benzaldehyde in non-steroidal anti-inflammatory drug injectable formulations using new ultrasound-assisted dispersive liquid-liquid micro extraction

    International Nuclear Information System (INIS)

    Mashayekhi, H.A.; Pourshamsian, K.

    2012-01-01

    Summary: In this study, simple and efficient ultrasound-assisted dispersive liquid-liquid micro extraction combined with gas chromatography (GC) was developed for the preconcentration and determination of benzaldehyde in injectable formulations of the non-steroidal anti-inflammatory drugs, diclofenac, Vitamin B-complex and Voltaren injection solutions. Fourteen microliters of toluene was injected slowly into 10 mL home-designed centrifuge glass vial containing an aqueous sample without salt addition that was located inside the ultrasonic water bath. The formed emulsion was centrifuged and 2 macro L of separated toluene was injected into a gas chromatographic system equipped with a flame ionization detector (GC-FID) for analysis. Several factors influencing the extraction efficiency as the nature and volume of organic solvent, extraction temperature, ionic strength and centrifugation time were investigated and optimized. Using optimum extraction conditions a detection limit of 0.3 macro g L/sup -1/ and a good linearity in a calibration range of 2.0-1000 macro g L/sup -1/ were achieved for analyte. This proposed method was successfully applied to the analysis of benzaldehyde in three injection formulations and relative standard deviation (RSD) of analysis (n=3), before spiking with standard benzaldehyde were 3.3, 2.0 and 1.3% for Na-diclofenac, vitamin B-complex and voltaren, respectively and after spiking of standard benzaldehyde (0.3 mg L/sup -1/), the RSD were 6.5, 3.6 and 2.8% for Na-diclofenac, vitamin B-complex and voltaren, respectively. (author)

  13. Premixed direct injection disk

    Science.gov (United States)

    York, William David; Ziminsky, Willy Steve; Johnson, Thomas Edward; Lacy, Benjamin; Zuo, Baifang; Uhm, Jong Ho

    2013-04-23

    A fuel/air mixing disk for use in a fuel/air mixing combustor assembly is provided. The disk includes a first face, a second face, and at least one fuel plenum disposed therebetween. A plurality of fuel/air mixing tubes extend through the pre-mixing disk, each mixing tube including an outer tube wall extending axially along a tube axis and in fluid communication with the at least one fuel plenum. At least a portion of the plurality of fuel/air mixing tubes further includes at least one fuel injection hole have a fuel injection hole diameter extending through said outer tube wall, the fuel injection hole having an injection angle relative to the tube axis. The invention provides good fuel air mixing with low combustion generated NOx and low flow pressure loss translating to a high gas turbine efficiency, that is durable, and resistant to flame holding and flash back.

  14. The enriched chromium neutrino source for GALLEX

    International Nuclear Information System (INIS)

    Hartmann, F.X.; Hahn, R.L.

    1991-01-01

    The preparation and study of an intense source of neutrinos in the form of neutron irradiated materials which are enriched in Cr-50 for use in the GALLEX solar neutrino experiment are discussed. Chromyl fluoride gas is enriched in the Cr-50 isotope by gas centrifugation and subsequently converted to a very stable form of chromium oxide. The results of neutron activation analyses of such chromium samples indicate low levels of any long-lived activities, but show that short-lived activities, in particular Na-24, may be of concern. These results show that irradiating chromium oxide enriched in Cr-50 is preferable to irradiating either natural chromium or argon gas as a means of producing a neutrino source to calibrate the GALLEX detector. These results of the impurity level analysis of the enriched chromyl fluoride gas and its conversion to the oxide are also of interest to work in progress by other members of the Collaboration investigating an alternative conversion of the enriched gas to chromium metal. 35 refs., 12 figs., 5 tabs

  15. Flavonoid and leaf gas exchange responses of Centella asiatica to acute gamma irradiation and carbon dioxide enrichment under controlled environment conditions.

    Science.gov (United States)

    Moghaddam, Sina Siavash; Jaafar, Hawa Binti; Aziz, Maheran Abdul; Ibrahim, Rusli; Rahmat, Asmah Bt; Philip, Elizabeth

    2011-10-25

    The study was couducted to investigate the effects of gamma irradiation and CO₂ on flavonoid content and leaf gas exchange in C.asiatica. For flavonoid determination, the design was a split split plot based on Randomized Complete Block Design (RCBD). For other parameters, the designs were split plots. Statistical tests revealed significant differences in flavonoid contents of Centella asiatica leaves between different growth stages and various CO₂ treatments. CO₂ 400, G20 (400 = ambient CO₂; G20 = Plants exposed to 20 Gy) showed 82.90% higher total flavonoid content (TFC) in the 5th week than CO₂ 400 as control at its best harvest time (4th week). Increasing the concentration of CO₂ from 400 to 800 μmol/mol had significant effects on TFC and harvesting time. In fact, 800 μmol/mol resulted in 171.1% and 66.62% increases in TFC for control and irradiated plants, respectively. Moreover, increasing CO₂ concentration reduced the harvesting time to three and four weeks for control and irradiated plants, respectively. Enhancing CO₂ to 800 µmol/mol resulted in a 193.30% (CO₂ 800) increase in leaf biomass compared to 400 µmol/mol and 226.34% enhancement in irradiated plants (CO₂ 800, G20) [800 = Ambient CO₂; G20 = Plants exposed to 20 Gy] than CO₂ 400, G20. In addition, the CO₂ 800, G20 had the highest amount of flavonoid*biomass in the 4th week. The results of this study indicated that all elevated CO₂ treatments had higher PN than the ambient ones. The findings showed that when CO₂ level increased from 400 to 800 µmol/mol, stomatal conductance, leaf intercellular CO₂ and transpiration rate had the tendency to decrease. However, water use efficiency increased in response to elevated CO₂ concentration. Returning to the findings of this study, it is now possible to state that the proposed method (combined CO₂ and gamma irradiation) has the potential to increase the product value by reducing the time to harvest, increasing the yield

  16. Flavonoid and Leaf Gas Exchange Responses of Centella asiatica to Acute Gamma Irradiation and Carbon Dioxide Enrichment under Controlled Environment Conditions

    Directory of Open Access Journals (Sweden)

    Hawa Binti Jaafar

    2011-10-01

    Full Text Available The study was couducted to investigate the effects of gamma irradiation and CO2 on flavonoid content and leaf gas exchange in C.asiatica. For flavonoid determination, the design was a split split plot based on Randomized Complete Block Design (RCBD. For other parameters, the designs were split plots. Statistical tests revealed significant differences in flavonoid contents of Centella asiatica leaves between different growth stages and various CO2 treatments. CO2 400, G20 (400 = ambient CO2; G20 = Plants exposed to 20 Gy showed 82.90% higher total flavonoid content (TFC in the 5th week than CO2 400 as control at its best harvest time (4th week. Increasing the concentration of CO2 from 400 to 800 μmol/mol had significant effects on TFC and harvesting time. In fact, 800 μmol/mol resulted in 171.1% and 66.62% increases in TFC for control and irradiated plants, respectively. Moreover, increasing CO2 concentration reduced the harvesting time to three and four weeks for control and irradiated plants, respectively. Enhancing CO2 to 800 µmol/mol resulted in a 193.30% (CO2 800 increase in leaf biomass compared to 400 µmol/mol and 226.34% enhancement in irradiated plants (CO2 800, G20 [800 = Ambient CO2; G20 = Plants exposed to 20 Gy] than CO2 400, G20. In addition, the CO2 800, G20 had the highest amount of flavonoid*biomass in the 4th week. The results of this study indicated that all elevated CO2 treatments had higher PN than the ambient ones. The findings showed that when CO2 level increased from 400 to 800 µmol/mol, stomatal conductance, leaf intercellular CO2 and transpiration rate had the tendency to decrease. However, water use efficiency increased in response to elevated CO2 concentration. Returning to the findings of this study, it is now possible to state that the proposed method (combined CO2 and gamma irradiation has the potential to increase the product value by reducing the time to harvest, increasing the yield per unit area via

  17. Controlling effect of fractures on gas accumulation and production within the tight sandstone: A case study on the Jurassic Dibei gas reservoir in the eastern part of the Kuqa foreland basin, China

    Directory of Open Access Journals (Sweden)

    Hui Lu

    2016-02-01

    Full Text Available Using Dibei tight sandstone gas reservoir in the eastern part of the Kuqa foreland basin as an example, this paper discusses tight sandstone reservoir fractures characterization, its effect on storage space and gas flow capacity, and its contribution to gas accumulation, enrichment and production in tight sandstone reservoir by using laser scanning confocal microscope (LSCM observation, mercury intrusion capillary pressure (MICP testing, and gas-water two-phase relative permeability testing. The statistics of laser scanning confocal microscopy observation showed that the microstructural fractures width in the Dibei gas reservoir was mainly 8–25 μm, and the associated micro-fractures width was mainly 4–10 μm. Additionally, the throat radius was mainly 1–4 μm. The fractures width was significantly wider than the throat radius that served as the main channel of in gas flow. In addition, it illustrated that the samples with developed fractures became easier for gas to flow under equal porosity condition, because of lower expulsion pressure, higher mercury injection saturation, and increased gas relative permeability based on the physical simulation experiment of gas charging into core samples with saturated water, mercury injection and gas-water two-phase permeability experiments. Furthermore, it had been concluded that the fractures control tight gas in the following aspects: (1 Fractures play a significant role in reservoir property improvement. The isolated pores were linked by the fractures to form connective reservoir spaces, and dissolution is prone to occur along the fractures forming new pores. The fractures with bigger width are reservoir space as well. (2 Fractures increased fluid flow capacity because it decreased the starting pressure gradient, and it increased gas effective permeability. Thus, fractures improved the gas injection efficiency as well as gas production. (3 Fractures that developed in different time and spatial

  18. Advances in uranium enrichment processes

    International Nuclear Information System (INIS)

    Rae, H.K.; Melvin, J.G.; Slater, J.B.

    1986-05-01

    Advances in gas centrifuges and development of the atomic vapour laser isotope separation process promise substantial reductions in the cost of enriched uranium. The resulting reduction in LWR fuel costs could seriously erode the economic advantage of CANDU, and in combination with LWR design improvements, shortened construction times and increased operational reliability could allow the LWR to overtake CANDU. CANDU's traditional advantages of neutron economy and high reliability may no longer be sufficient - this is the challenge. The responses include: combining neutron economy and dollar economy by optimizing CANDU for slightly enriched uranium fuel; developing cost-reducing improvements in design, manufacture and construction; and reducing the cost of heavy water. Technology is a renewable resource which must be continually applied to a product for it to remain competitive in the decades to come. Such innovation is a prerequisite to Canada increasing her share of the international market for nuclear power stations. The higher burn-up achievable with enriched fuel in CANDU can reduce the fuel cycle costs by 20 to 40 percent for a likely range of costs for yellowcake and separative work. Alternatively, some of the benefits of a higher fissile content can take the form of a cheaper reactor core containing fewer fuel channels and less heavy water, and needing only a single fuelling machine. An opportunity that is linked to this need to introduce an enriched uranium fuel cycle into CANDU is to build an enrichment business in Canada. This could offer greater value added to our uranium exports, security of supply for enriched CANDUs, technological growth in Canada and new employment opportunities. AECL has a study in progress to define this opportunity

  19. Principles and techniques of uranium enrichment

    International Nuclear Information System (INIS)

    Frejacques, Claude; Mezin, Michel

    1975-01-01

    The main separation processes already used industrially or likely to be used before the end of century (gas diffusion, ultracentrifugation, laser, the nozzle process, a process developed in South Africa) are presented. Some data on the costs of the enrichment are clarified. The main characteristics of the enrichment market in which the Eurodif plant is called upon, on the expiration of five years, to take a foremost place are reported [fr

  20. Applicability of Gas Chromatography (GC) Coupled to Triple-Quadrupole (QqQ) Tandem Mass Spectrometry (MS/MS) for Polybrominated Diphenyl Ether (PBDE) and Emerging Brominated Flame Retardant (BFR) Determinations in Functional Foods Enriched in Omega-3.

    Science.gov (United States)

    García-Bermejo, Ángel; Mohr, Susana; Herrero, Laura; González, María-José; Gómara, Belén

    2016-09-28

    This paper reports on the optimization, characterization, and applicability of gas chromatography coupled to triple-quadrupole tandem mass spectrometry (GC-QqQ(MS/MS)) for the determination of 14 polybrominated diphenylethers (PBDEs) and 2 emerging brominated flame retardants, 1,2-bis(2,4,6-tribromophenoxy)ethane (BTBPE) and decabromodiphenylethane (DBDPE), in functional food samples. The method showed satisfactory precision and linearity with instrumental limits of detection (iLODs) ranging from 0.12 to 7.1 pg, for tri- to octa-BDEs and BTBPE, and equal to 51 and 20 pg for BDE-209 and DBDPE, respectively. The highest ΣBFR concentrations were found in fish oil supplements (924 pg/g fresh weight, fw), followed by biscuits (90 pg/g fw), vegetable oil supplements (46 pg/g fw), chicken eggs (45 pg/g fw), cow's milk (7.7 pg/g fw), and soy products (1.6 pg/g fw). BDE-47, BDE-99, and DBDPE were the most abundant compounds. Foodstuffs enriched with omega-3 presented concentrations similar to or even lower than those of conventional foods commercialized in Spain since 2000.

  1. Étude des équilibres thermodynamiques des réactions de gazéification en vue de l'optimisation du rapport vapeur/comburant injecté dans un gazogène souterrain Study of Thermodynamic Equilibria in Gasification Reactions So As to Optimise the Steam/Oxidizer Ratio Injected Into an Underground Gas Generator

    Directory of Open Access Journals (Sweden)

    Pirard J. P.

    2006-11-01

    Full Text Available Le but de cette étude est de déterminer sur la base des équilibres thermodynamiques des réactions de gazéification le rapport vapeur/comburant à injecter dans un gazogène fonctionnant sous pression pour optimaliser les compositions, les pouvoirs calorifiques, les rendements de gazéification et la consommation d'agent gazéifiant. The aim of this study is to determine, on the basis of the thermodynamic equilibria of gazification reactions, the steam/oxidizer ratio to be injected into a gas generator operating under pressure so as to optimize the compositions, the heating values, the gasification efficiencies and the consumption of gasifying agent.

  2. Uranium enrichment plans

    International Nuclear Information System (INIS)

    Thomas, D.C.; Gagne, R.W.

    1978-01-01

    The following topics are covered: the status of the Government's existing uranium enrichment services contracts, natural uranium requirements based on the latest contract information, uncertainty in predicting natural uranium requirements based on uranium enrichment contracts, and domestic and foreign demand assumed in enrichment planning

  3. Extraction of Dissolved Gaseous Hydrocarbons from Brine at an Engineered CO2 Injection, Cranfield, Mississippi

    Science.gov (United States)

    Romanak, K.; Zhang, T.; Yang, C.; Gilbert, K.; Bennett, P.; Hovorka, S.

    2010-12-01

    Injection of anthropogenic CO2 into oil and gas reservoirs is being considered as a method for concurrently extracting fossil fuels through enhanced oil recovery and attaining long-term geological carbon storage. Inherent in this process is interaction of injected CO2, brine, rock and dissolved gases in brine which contain light hydrocarbons. Controlled laboratory experiments are underway to simulate the changes in gas concentrations observed during an engineered CO2 injection at the Cranfield oilfield as part of the Department of Energy Southeast Regional Carbon Partnership study. Laboratory simulations are also being used to validate a gas mixing model devised to separate the effects of physical mixing from chemical extraction processes in the reservoir. During the injection period from December 2009 to May 2010, approximately 100,000 tonnes of CO2 were injected into an oil and gas reservoir below the oil water contact. Gas samples were collected from 2 observation wells (~3000m depth) using a pressure loop UTube sampler and analyzed by gas chromatography. The target oil and gas reservoir has brines that contain dissolved hydrocarbons (77% CH4, 3.2% CO2, 1.8% C2H6, 0.2% C3H6, 0.05% He), while the injectate gas is similarly complex, (95% CO2, 2.3% CH4, 0.2% C2H6, 0.07% C3H8, 0.005% He). Both C2 and C3 are enriched in the gas phase during CO2 transport over 60m. CO2 and CH4 versus He ratios show an initial increase then decrease after supercritical CO2 arrives at the monitoring wells. This change in concentrations suggests an initial partitioning of CH4 into CO2, then depletion of CH4 over time. Also, C2/C3 and C3/C4 ratios decrease dramatically. High pressure-temperature experiments are being designed to understand what chemical factors might account for the variability in extraction of CH4 and other light hydrocarbons from brines observed during CO2 injection at Cranfield.

  4. Profile of World Uranium Enrichment Programs - 2007

    Energy Technology Data Exchange (ETDEWEB)

    Laughter, Mark D [ORNL

    2007-11-01

    It is generally agreed that the most difficult step in building a nuclear weapon is acquiring weapons grade fissile material, either plutonium or highly enriched uranium (HEU). Plutonium is produced in a nuclear reactor, while HEU is produced using a uranium enrichment process. Enrichment is also an important step in the civil nuclear fuel cycle, in producing low enriched uranium (LEU) for use in fuel for nuclear reactors. However, the same equipment used to produce LEU for nuclear fuel can also be used to produce HEU for weapons. Safeguards at an enrichment plant are the array of assurances and verification techniques that ensure uranium is only enriched to LEU, no undeclared LEU is produced, and no uranium is enriched to HEU or secretly diverted. There are several techniques for enriching uranium. The two most prevalent are gaseous diffusion, which uses older technology and requires a lot of energy, and gas centrifuge separation, which uses more advanced technology and is more energy efficient. Gaseous diffusion plants (GDPs) provide about 40% of current world enrichment capacity, but are being phased out as newer gas centrifuge enrichment plants (GCEPs) are constructed. Estimates of current and future enrichment capacity are always approximate, due to the constant upgrades, expansions, and shutdowns occurring at enrichment plants, largely determined by economic interests. Currently, the world enrichment capacity is approximately 53 million kg-separative work units (SWU) per year, with 22 million in gaseous diffusion and 31 million in gas centrifuge plants. Another 23 million SWU/year of capacity are under construction or planned for the near future, almost entirely using gas centrifuge separation. Other less-efficient techniques have also been used in the past, including electromagnetic and aerodynamic separations, but these are considered obsolete, at least from a commercial perspective. Laser isotope separation shows promise as a possible enrichment technique

  5. Experimental and simulation determination of minimum miscibility pressure for a Bakken tight oil and different injection gases

    Directory of Open Access Journals (Sweden)

    Sheng Li

    2017-03-01

    Full Text Available The effective development of unconventional tight oil formations, such as Bakken, could include CO2 enhanced oil recovery (EOR technologies with associated benefits of capturing and storing large quantities of CO2. It is important to conduct the gas injection at miscible condition so as to reach maximum recovery efficiency. Therefore, determination of the minimum miscibility pressure (MMP of reservoir live oil–injection gas system is critical in a miscible gas flooding project design. In this work, five candidate injection gases, namely CO2, CO2-enriched flue gas, natural gas, nitrogen, and CO2-enriched natural gas, were selected and their MMPs with a Bakken live oil were determined experimentally and numerically. At first, phase behaviour tests were conducted for the reconstituted Bakken live oil and the gases. CO2 outperformed other gases in terms of viscosity reduction and oil swelling. Rising bubble apparatus (RBA determined live oil–CO2 MMP as 11.9 MPa and all other gases higher than 30 MPa. The measured phase behaviour data were used to build and tune an equation-of-state (EOS model, which calculated the MMPs for different live oil-gas systems. The EOS-based calculations indicated that CO2 had the lowest MMP with live oil among the five gases in the study. At last, the commonly-accepted Alston et al. equation was used to calculate live oil–pure CO2 MMP and effect of impurities in the gas phase on MMP change. The Bakken oil–CO2 had a calculated MMP of 10.3 MPa from the Alston equation, and sensitivity analysis showed that slight addition of volatile impurities, particularly N2, can increase MMP significantly.

  6. Injectivity errors in simulation of foam EOR

    NARCIS (Netherlands)

    Leeftink, T.N.; Latooij, C.A.; Rossen, W.R.

    2014-01-01

    Injectivity is a key factor in the economics of foam enhanced oil recovery (EOR) processes. Poor injectivity of low-mobility foam slows the production of oil and allows more time for gravity segregation of injected gas. The conventional Peaceman equation (1978), when applied in a large grid block,

  7. Uranium Enrichment, an overview

    International Nuclear Information System (INIS)

    Coates, J.H.

    1994-01-01

    This general presentation on uranium enrichment will be followed by lectures on more specific topics including descriptions of enrichment processes and assessments of the prevailing commercial and industrial situations. I shall therefore avoid as much as possible duplications with these other lectures, and rather dwell on: some theoretical aspects of enrichment in general, underlying the differences between statistical and selective processes, a review and comparison between enrichment processes, remarks of general order regarding applications, the proliferation potential of enrichment. It is noteworthy that enrichment: may occur twice in the LWR fuel cycle: first by enriching natural uranium, second by reenriching uranium recovered from reprocessing, must meet LWR requirements, and in particular higher assays required by high burn up fuel elements, bears on the structure of the entire front part of the fuel cycle, namely in the conversion/reconversion steps only involving UF 6 for the moment. (author). tabs., figs., 4 refs

  8. Magnesium Removal from an Aluminum A-332 Molten Alloy Using Enriched Zeolite with Nanoparticles of SiO2

    Directory of Open Access Journals (Sweden)

    R. Muñoz-Arroyo

    2014-01-01

    Full Text Available In order to improve the Mg removal from an A-380 molten alloy, mixtures of zeolite and SiO2 nanoparticles (SiO2(NPs were tested. Zeolite was enriched with 2.5, 5, 7.5, 10, or 12.5 wt-% of amorphous SiO2(NPs. The SiO2(NPs and zeolite were mixed for 30 min in ethanol for each experiment and then dried in a furnace at 80°C for 12 h. The enriched zeolites were analyzed by scanning electron microscopy, transmission electron microscopy, and N2 gas adsorption analysis. The Mg removal was carried out injecting each mixture into the molten aluminum alloy at 750°C using argon. The Mg content of the molten alloy was measured after different periods of the injection time. Zeolites enriched with 2.5 and 5 wt-% of SiO2(NPs were demonstrated to be the better mixtures, removing Mg from an initial content of 1.6 to a final content of 0.0002 and 0.0101 wt-%, respectively, in 45 min of injection.

  9. Cefazolin Injection

    Science.gov (United States)

    ... is used to treat certain infections caused by bacteria including skin, bone, joint, genital, blood, heart valve, respiratory tract (including pneumonia), biliary tract, and urinary tract infections. Cefazolin injection ...

  10. Atezolizumab Injection

    Science.gov (United States)

    ... is in a class of medications called monoclonal antibodies. It works by blocking the action of a ... infection breath that smells fruity slowed, fast or irregular heartbeat Atezolizumab injection may cause other side effects. ...

  11. Cidofovir Injection

    Science.gov (United States)

    Cidofovir injection is used along with another medication (probenecid) to treat cytomegaloviral retinitis (CMV retinitis) in people ... body's response to the medication.You must take probenecid tablets by mouth with each dose of cidofovir. ...

  12. Acyclovir Injection

    Science.gov (United States)

    ... It is also used to treat first-time genital herpes outbreaks (a herpes virus infection that causes sores ... in the body. Acyclovir injection will not cure genital herpes and may not stop the spread of genital ...

  13. Alirocumab Injection

    Science.gov (United States)

    ... further decrease the amount of low-density lipoprotein (LDL) cholesterol ('bad cholesterol') in the blood. Alirocumab injection is ... antibodies. It works by blocking the production of LDL cholesterol in the body to decrease the amount of ...

  14. Pegloticase Injection

    Science.gov (United States)

    ... doctor if you have glucose-6-phosphate dehydrogenase (G6PD) deficiency (an inherited blood disease). Your doctor may test you for G6PD deficiency before you start to receive pegloticase injection. If ...

  15. Risperidone Injection

    Science.gov (United States)

    ... of interest in life, and strong or inappropriate emotions). Risperidone extended-release injection is used alone or ... during your treatment: extreme thirst, frequent urination, extreme hunger, blurred vision, or weakness. It is very important ...

  16. Olanzapine Injection

    Science.gov (United States)

    ... of interest in life, and strong or inappropriate emotions). Olanzapine injection is used to treat episodes of ... during your treatment: extreme thirst, frequent urination, extreme hunger, blurred vision, or weakness. It is very important ...

  17. Tacrolimus Injection

    Science.gov (United States)

    ... in people who have received kidney, liver, or heart transplants. Tacrolimus injection should only be used by people ... or nurse will watch you closely during the first 30 minutes of your treatment and then will ...

  18. Omalizumab Injection

    Science.gov (United States)

    ... injection is used to decrease the number of asthma attacks (sudden episodes of wheezing, shortness of breath, and ... about how to treat symptoms of a sudden asthma attack. If your asthma symptoms get worse or if ...

  19. Daclizumab Injection

    Science.gov (United States)

    ... neck, armpits, or groin; diarrhea; bloody stools; stomach pain; or any new, unexplained symptom affecting any part of your body.Because of the risks with this medication, daclizumab injection is available only through a special ...

  20. Temozolomide Injection

    Science.gov (United States)

    ... balance or coordination fainting dizziness hair loss insomnia memory problems pain, itching, swelling, or redness in the place where the medication was injected changes in vision Some side effects can be serious. If you ...

  1. Moxifloxacin Injection

    Science.gov (United States)

    ... tendon area, or inability to move or to bear weight on an affected area.Using moxifloxacin injection ... muscle weakness) and cause severe difficulty breathing or death. Tell your doctor if you have myasthenia gravis. ...

  2. Delafloxacin Injection

    Science.gov (United States)

    ... a tendon area, or inability to move or bear weight on an affected area.Using delafloxacin injection ... muscle weakness) and cause severe difficulty breathing or death. Tell your doctor if you have myasthenia gravis. ...

  3. Levofloxacin Injection

    Science.gov (United States)

    ... tendon area, or inability to move or to bear weight on an affected area.Using levofloxacin injection ... muscle weakness) and cause severe difficulty breathing or death. Tell your doctor if you have myasthenia gravis. ...

  4. Ciprofloxacin Injection

    Science.gov (United States)

    ... a tendon area, or inability to move or bear weight on an affected area.Using ciprofloxacin injection ... muscle weakness) and cause severe difficulty breathing or death. Tell your doctor if you have myasthenia gravis. ...

  5. Butorphanol Injection

    Science.gov (United States)

    ... Butorphanol is in a class of medications called opioid agonist-antagonists. It works by changing the way ... suddenly stop using butorphanol injection, you may experience withdrawal symptoms such as nervousness, agitation, shakiness, diarrhea, chills, ...

  6. Haloperidol Injection

    Science.gov (United States)

    ... of interest in life, and strong or inappropriate emotions). Haloperidol injection is also used to control motor ... and the laboratory. Your doctor may order certain lab tests to check your body's response to haloperidol ...

  7. Ketorolac Injection

    Science.gov (United States)

    ... of ketorolac by intravenous (into a vein) or intramuscular (into a muscle) injection in a hospital or ... You can also visit the Food and Drug Administration (FDA) website (http://www.fda.gov/Drugs/DrugSafety/ ...

  8. Burnable gas concentration control device

    International Nuclear Information System (INIS)

    Goto, Hiroshi; Sanada, Takahiro; Kuboniwa, Takao.

    1980-01-01

    Purpose: To provide connecting ports by doubling nitrogen gas injection pipes thereby to secure lengthiness of the device only by providing one nitrogen gas generator. Constitution: Nitrogen gas injection pipes are provided in two lines separately, and attachable and detachable connecting ports for feeding nitrogen gas connectable to a movable type nitrogen gas supply installation for the purpose of backing up the nitrogen gas generator. (Yoshihara, H.)

  9. A Theoretical and Experimental Analysis of Post-Compression Water Injection in a Rolls-Royce M250 Gas Turbine Engine

    Science.gov (United States)

    2015-05-18

    Brian Ray 5d. PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) 8. PERFORMING...for his continued help and support throughout the last four years as both his student and advisee. Additionally, I would like to thank Mr. Charles ...Daggett, David L., Silvio Ortanderl, David Eames , Jeffrey J. Berton, and Christopher A. Snyder. Revisiting Water Injection for Commercial Aircraft

  10. Optimal set of selected uranium enrichments that minimizes blending consequences

    International Nuclear Information System (INIS)

    Nachlas, J.A.; Kurstedt, H.A. Jr.; Lobber, J.S. Jr.

    1977-01-01

    Identities, quantities, and costs associated with producing a set of selected enrichments and blending them to provide fuel for existing reactors are investigated using an optimization model constructed with appropriate constraints. Selected enrichments are required for either nuclear reactor fuel standardization or potential uranium enrichment alternatives such as the gas centrifuge. Using a mixed-integer linear program, the model minimizes present worth costs for a 39-product-enrichment reference case. For four ingredients, the marginal blending cost is only 0.18% of the total direct production cost. Natural uranium is not an optimal blending ingredient. Optimal values reappear in most sets of ingredient enrichments

  11. Recovery enhancement at the later stage of supercritical condensate gas reservoir development via CO2 injection: A case study on Lian 4 fault block in the Fushan sag, Beibuwan Basin

    Directory of Open Access Journals (Sweden)

    Wenyan Feng

    2016-11-01

    Full Text Available Lian 4 fault block is located in the northwest of Fushan sag, Beibuwan Basin. It is a high-saturated condensate gas reservoir with rich condensate oil held by three faults. In order to seek an enhanced condensate oil recovery technology that is suitable for this condensate gas reservoir at its later development stage, it is necessary to analyze its reserve producing degree and remaining development potential after depletion production, depending on the supercritical fluid phase behavior and depletion production performance characteristics. The supercritical fluid theories and multiple reservoir engineering dynamic analysis methods were adopted comprehensively, such as dynamic reserves, production decline, liquid-carrying capacity of a production well, and remaining development potential analysis. It is shown that, at its early development stage, the condensate in Lian 4 fault block presented the features of supercritical fluid, and the reservoir pressure was lower than the dew point pressure, so retrograde condensate loss was significant. Owing to the retrograde condensate effect and the fast release of elastic energy, the reserve producing degree of depletion production is low in Lian 4 fault block, and 80% of condensate oil still remains in the reservoir. So, the remaining development potential is great. The supercritical condensate in Lian 4 fault block is of high density. Based on the optimization design by numerical simulation of compositional model, it is proposed to inject CO2 at the top and build up pressure by alternating production and injection, so that the secondary gas cap is formed while the gravity-stable miscible displacement is realized. In this way, the recovery factor of condensate reservoirs can be improved by means of the secondary development technology.

  12. Advanced enrichment techniques

    International Nuclear Information System (INIS)

    Johnson, A.

    1988-01-01

    BNFL is in a unique position in that it has commercial experience of diffusion enrichment, and of centrifuge enrichment through its associate company Urenco. In addition BNFL is developing laser enrichment techniques as part of a UK development programme in this area. The paper describes the development programme which led to the introduction of competitive centrifuge enrichment technology by Urenco and discusses the areas where improvements have and will continue to be made in the centrifuge process. It also describes the laser development programme currently being undertaken in the UK. The paper concludes by discussing the relative merits of the various methods of uranium enrichment, with particular reference to the enrichment market likely to obtain over the rest of the century

  13. Adjustable hybrid gas bearing – Influence of piezoelectrically adjusted injection on damping factors and natural frequencies of a flexible rotor operating under critical speeds

    DEFF Research Database (Denmark)

    Pierart, Fabián G.; Santos, Ilmar F.

    2016-01-01

    Damping factors and natural frequencies of a flexible rotor supported by a gas bearing with piezoelectrically adjusted flow, are theoretically determined using a rotor finite element model coupled with the modified Reynolds equation. An extra term is added to the standard formulation of Reynolds...

  14. Effect of Biodiesel Fuel Injection Timing and Venture for Gaseous Fuel Induction on the Performance, Emissions and Combustion Characteristics of Dual Fuel Engine

    Directory of Open Access Journals (Sweden)

    Mallikarjun Bhovi

    2018-02-01

    Full Text Available Advancing or retarding pilot fuel injection timing in a diesel engine provided with either conventional mechanical fuel injection (CMFIS or high pressure injection as in common rail fuel injection (CRDI systems can significantly affect its performance and tail pipe emissions. Performance of diesel engine when fueled with various biofuels as well as gaseous fuels tends to vary with subsequent changes in pilot fuel injection timings. Biodiesel derived from rubber seed oil called Rubber Seed Oil Methyl Ester (RuOME and hydrogen (H2 and hydrogen enriched compressed natural gas called (HCNG both being renewable fuels when used in diesel engines modified to operate in dual fuel mode can provide complete replacement for fossil diesel. In the present study, effect of injection timings and venture design for gas mixing on the performance, combustion and emission characteristics of dual fuel engine fitted with both CMFIS and CRDI injection systems and operated on RuOME and HCNG/hydrogen has been investigated. Results showed that high pressure CRDI assisted injection of RuOME with optimized mixing chamber (carburetor for hydrogen induction in dual fuel engine performed improved compared to that with CMFIS. In addition, for the same fuel combinations, CRDI resulted in lower biodiesel consumption, lower carbon monoxide (BSCO and hydrocarbon (BSHC emissions and increased NOx emissions than CMFIS operation.

  15. Uranium enrichment: an overview

    Energy Technology Data Exchange (ETDEWEB)

    Cazalet, J.

    1995-12-31

    This paper is a general presentation of uranium enrichment processes and assessments of the prevailing commercial and industrial situations. It gives first some theoretical aspects of enrichment in general and explains the differences between statistical and selective processes in particular. Then a review of the different processes is made with a comparison between them. Finally, some general remarks concerning applications are given and the risks of proliferation related to enrichment are mentioned. (J.S.). 4 refs., 5 figs., 8 tabs.

  16. Uranium enrichment: an overview

    International Nuclear Information System (INIS)

    Cazalet, J.

    1995-01-01

    This paper is a general presentation of uranium enrichment processes and assessments of the prevailing commercial and industrial situations. It gives first some theoretical aspects of enrichment in general and explains the differences between statistical and selective processes in particular. Then a review of the different processes is made with a comparison between them. Finally, some general remarks concerning applications are given and the risks of proliferation related to enrichment are mentioned. (J.S.). 4 refs., 5 figs., 8 tabs

  17. Assessment of multi-phase movements in a gas-gathering pipeline and the relevance to on-line, real-time corrosion monitoring and inhibitor injection

    Energy Technology Data Exchange (ETDEWEB)

    Baker, M.A.; Asperger, R.G.

    1988-01-01

    A study was conducted to determine the time required for aqueous fluid to travel 100 miles (160 km) from an offshore platform in the Gulf of Mexico to landfill. If this time is short, the corrosivity of the water at landfall may be used as the basis for setting the offshore corrosion inhibitor injection rates. But, for this particular system, the traveling time was found to be long, greater than 65 days. Therefore, the corrosivity as measured on-shore can not be used for online, real-time adjustments of the offshore, corrosion inhibitor chemical pumps.

  18. Effect of Injection Flow Rate on Product Gas Quality in Underground Coal Gasification (UCG Based on Laboratory Scale Experiment: Development of Co-Axial UCG System

    Directory of Open Access Journals (Sweden)

    Akihiro Hamanaka

    2017-02-01

    Full Text Available Underground coal gasification (UCG is a technique to recover coal energy without mining by converting coal into a valuable gas. Model UCG experiments on a laboratory scale were carried out under a low flow rate (6~12 L/min and a high flow rate (15~30 L/min with a constant oxygen concentration. During the experiments, the coal temperature was higher and the fracturing events were more active under the high flow rate. Additionally, the gasification efficiency, which means the conversion efficiency of the gasified coal to the product gas, was 71.22% in the low flow rate and 82.42% in the high flow rate. These results suggest that the energy recovery rate with the UCG process can be improved by the increase of the reaction temperature and the promotion of the gasification area.

  19. Effect of Diesel Engine Converted to Sequential Port Injection Compressed Natural Gas Engine on the Cylinder Pressure vs Crank Angle in Variation Engine Speeds

    OpenAIRE

    Semin; Abdul R. Ismail; Rosli A. Bakar

    2009-01-01

    The diesel engine converted to compressed natural gas (CNG) engine effect is lower in performance. Problem statement: The hypothesis is that the lower performance of CNG engine is caused by the effect of lower in engine cylinder pressure. Are the CNG engine is lower cylinder pressure than diesel engine? This research is conducted to investigate the cylinder pressure of CNG engine as a new engine compared to diesel engine as a baseline engine. Approach: The research approach in this study is b...

  20. Ceftazidime Injection

    Science.gov (United States)

    ... is used to treat certain infections caused by bacteria including pneumonia and other lower respiratory tract (lung) infections; meningitis (infection of the membranes that surround the brain and spinal cord) and ... killing bacteria.Antibiotics such as ceftazidime injection will not work ...

  1. Teduglutide Injection

    Science.gov (United States)

    ... who need additional nutrition or fluids from intravenous (IV) therapy. Teduglutide injection is in a class of medications ... of the ingredients.tell your doctor and pharmacist what other prescription and nonprescription medications, vitamins, nutritional supplements, and herbal products you are taking ...

  2. Dexrazoxane Injection

    Science.gov (United States)

    ... are used to treat or prevent certain side effects that may be caused by chemotherapy medications. Dexrazoxane injection (Zinecard) is used to prevent or decrease heart damage caused by doxorubicin in women who are taking the medication to treat breast cancer that has spread to other parts of the ...

  3. Dulaglutide Injection

    Science.gov (United States)

    ... thyroid carcinoma (MTC; a type of thyroid cancer). Laboratory animals who were given dulaglutide developed tumors, but it ... your doctor will probably tell you not to use dulaglutide injection. If you ... doctor and the laboratory. Your doctor may order certain tests to check ...

  4. Albiglutide Injection

    Science.gov (United States)

    ... thyroid carcinoma (MTC; a type of thyroid cancer). Laboratory animals who were given medications similar to albiglutide developed ... your doctor will probably tell you not to use albiglutide injection. If you ... doctor and the laboratory. Your doctor may order certain tests to check ...

  5. Semaglutide Injection

    Science.gov (United States)

    ... thyroid carcinoma (MTC; a type of thyroid cancer). Laboratory animals who were given semaglutide developed tumors, but it ... your doctor will probably tell you not to use semaglutide injection. If you ... doctor and the laboratory. Your doctor may order certain tests to check ...

  6. Liraglutide Injection

    Science.gov (United States)

    ... thyroid carcinoma (MTC; a type of thyroid cancer). Laboratory animals who were given liraglutide developed tumors, but it ... your doctor will probably tell you not to use liraglutide injection. If you ... doctor and the laboratory. Your doctor may order certain tests to check ...

  7. Exenatide Injection

    Science.gov (United States)

    ... thyroid carcinoma (MTC; a type of thyroid cancer). Laboratory animals who were given exenatide developed tumors, but it ... your doctor will probably tell you not to use exenatide injection. If you ... doctor and the laboratory. Your doctor may order certain tests to check ...

  8. Etoposide Injection

    Science.gov (United States)

    ... used in combination with other medications to treat cancer of the testicles that has not improved or that has worsened after treatment with other medications or radiation therapy. Etoposide injection ... type of lung cancer (small cell lung cancer; SCLC). Etoposide is in ...

  9. Cefepime Injection

    Science.gov (United States)

    ... infection because they have a low number of white blood cells. Cefepime injection is in a class ... In case of overdose, call the poison control helpline at 1-800-222-1222. Information is also available online at https://www.poisonhelp.org/help. If the victim has ...

  10. Triptorelin Injection

    Science.gov (United States)

    ... puberty too soon, resulting in faster than normal bone growth and development of sexual characteristics) in children 2 years and older. Triptorelin injection is in a class of medications called gonadotropin-releasing hormone (GnRH) agonists. It works by decreasing the amount ...

  11. Uranium enrichment plans

    International Nuclear Information System (INIS)

    Gagne, R.W.; Thomas, D.C.

    1977-01-01

    The status of existing uranium enrichment contracts in the US is reviewed and expected natural uranium requirements for existing domestic uranium enrichment contracts are evaluated. Uncertainty in natural uranium requirements associated with requirements-type and fixed-commitment type contracts is discussed along with implementation of variable tails assay

  12. Uranium enrichment plans and policies

    International Nuclear Information System (INIS)

    Schwennesen, J.L.

    1981-01-01

    Significant progress has been made in US efforts to expand its enrichment capacity. The Cascade Improvement Program (CIP) and Cascade Upgrading Program (CUP) are now complete at Oak Ridge and Paducah and almost complete at Portsmouth. Considerable progress has also been made in constructing the Gas Centrifuge Enrichment Plant (GCEP), and physical construction of the first process building is well under way. Current plans are to have two process buildings on-line by 1989 with the remaining six buildings to be added sequentially as needed to meet demand. The status of DOE enrichment services contracts is essentially unchanged from that reported at last year's seminar. The OUEA latest forecast of nuclear power growth, however, is considerably lower than reported last year, although a leveling trend is becoming apparent. The Variable Tails Assay Option (VTAO) of the AFC contract was made available for the third time for FY 1983. The DOE inventories of natural uranium still remain high. The Department of Energy will dispose of this material by using it for Government programs and for enrichment plant operations. It appears that Government inventories of uranium are adequate through at least the mid-1990s. It remains DOE policy not to dispose of its natural uranium stocks through direct sales in the marketplace, except for very small quantities or if an emergency situation would exist and all reasonable attempts had been made, without success, to obtain natural uranium from commercial sources. Finally, with regard to DOE plans on future transaction tails assays, it still appears likely that the current 0.20 percent uranium-235 reference tails assay will be maintained until well into the 1990s, at which time it might be increased up to 0.25 percent uranium-235

  13. Expansion of U. S. uranium enrichment capacity. Final environmental statement

    Energy Technology Data Exchange (ETDEWEB)

    1976-04-01

    Reasonably foreseeable environmental, social, economic, and technological costs and benefits of postulated expansion of U. S. enrichment capacity through the year 2000 and reasonably available alternatives to such expansion are described. Both the gas centrifuge and gaseous diffusion methods for the enrichment of uranium are considered in this impact assessment. (JGB)

  14. Injection-induced earthquakes.

    Science.gov (United States)

    Ellsworth, William L

    2013-07-12

    Earthquakes in unusual locations have become an important topic of discussion in both North America and Europe, owing to the concern that industrial activity could cause damaging earthquakes. It has long been understood that earthquakes can be induced by impoundment of reservoirs, surface and underground mining, withdrawal of fluids and gas from the subsurface, and injection of fluids into underground formations. Injection-induced earthquakes have, in particular, become a focus of discussion as the application of hydraulic fracturing to tight shale formations is enabling the production of oil and gas from previously unproductive formations. Earthquakes can be induced as part of the process to stimulate the production from tight shale formations, or by disposal of wastewater associated with stimulation and production. Here, I review recent seismic activity that may be associated with industrial activity, with a focus on the disposal of wastewater by injection in deep wells; assess the scientific understanding of induced earthquakes; and discuss the key scientific challenges to be met for assessing this hazard.

  15. Optimization of a microwave-assisted extraction large-volume injection and gas chromatography-ion trap mass spectrometry procedure for the determination of polybrominated diphenyl ethers, polybrominated biphenyls and polychlorinated naphthalenes in sediments

    Energy Technology Data Exchange (ETDEWEB)

    Yusa, V. [Analytical Chemistry Department, University of Valencia, Edifici Jeroni Munoz, 50th Dr. Moliner, 46100 Burjassot, Valencia (Spain); Pardo, O. [Analytical Chemistry Department, University of Valencia, Edifici Jeroni Munoz, 50th Dr. Moliner, 46100 Burjassot, Valencia (Spain); Pastor, A. [Analytical Chemistry Department, University of Valencia, Edifici Jeroni Munoz, 50th Dr. Moliner, 46100 Burjassot, Valencia (Spain)]. E-mail: Agustin.Pastor@uv.es; Guardia, M. de la [Analytical Chemistry Department, University of Valencia, Edifici Jeroni Munoz, 50th Dr. Moliner, 46100 Burjassot, Valencia (Spain)

    2006-01-31

    A sensitive and rapid method for the determination of polybrominated diphenyl ethers (PBDEs), polybrominated biphenyls (PBBs) and polychlorinated naphthalenes (PCNs) in sediment samples is proposed. The method involving microwave-assisted extraction (MAE) and large-volume injection (LVI) gas chromatography (GC)-ion trap mass spectrometry (ITMS), and the experimental conditions were optimized using the statistical design of experiments (DOE). A Plackett-Burman (P-B) design was chosen to estimate the influence of five factors, such as resonance excitation voltage (EV), isolation time (IT), excitation time (ET), ion source temperature (IST) and electron energy (EE) on the analytical response in the ITMS determination. In order to increase the analytical response, 70 {mu}L of the final extract were injected into the GC-tandem mass spectrometry (MS-MS) using a programmable temperature vaporizer (PTV). The factor settings involving injection temperature, vaporization temperature, vaporization time and flow during the evaporation step were previously optimized using a central composite design (CCD). The MAE was carried out using the hexane-acetone (1:1, v/v) mixture and the extraction conditions were optimized with a CCD. The highest response was obtained with a volume of 48 mL, a temperature of 152 deg. C and an extraction time of 24 min. The optimized method gives recoveries between 75 and 95% with relative standard deviations (R.S.D.) that ranged from 4 to 13%. The limit of detection (LOD) ranged between 4 and 20 pg g{sup -1} dry weight (dw) when 5 g of sediment were analyzed. The MAE method was applied to the analyses of polyhalogenated compounds in sediments collected in the harbour of Valencia (Spain). The proposed method may serve as an alternative for GC-negative chemical ionization (NCI)-MS and can be used in government testing programmes.

  16. The efficacy of preventive parasternal single injection of bupivacaine on intubation time, blood gas parameters, narcotic requirement, and pain relief after open heart surgery: A randomized clinical trial study

    Directory of Open Access Journals (Sweden)

    Mahmoud Saeidi

    2011-01-01

    Full Text Available Background: Postsurgical pain usually results in some complications in the patients. This study has tried to investigate the effects of parasternal single injection of bupivacaine on postoperative pulmonary and pain consequences in patients after open heart surgery. Methods: : In a prospective double blind clinical study, 100 consenting patients undergoing elective open heart surgery were randomized into two groups. In case group, bupivacaine was injected at both sides of sternum, immediately before sternal closure. In the control group, no intervention was performed. Then, the patients were investigated regarding intubation period, length of ICU stay, arterial blood gas (ABG parameters, morphine requirement, and their severity of postoperative pain using a visual analogue scale (VAS device. Results: No differences were found between the two groups regarding to age, sex, pump time, operation time, and body mass index and preoperative cardiac ejection fraction. Mean intubation length in case group was much shorter than that in control group. Mean PaO 2 in case group was lower in different checking times in postoperative period. The patients in the case group needed less morphine compared to those in the control group during the 24-hour observation period in the ICU. Finally, mean VAS scores of pain in case group were significantly lower than those in control group at 6, 12, and 24 hours postoperatively. Conclusions: Patients′ pain relief by parasternal single injection of bupivacaine in early postoperative period can facilitate earlier ventilator weaning and tracheal extubation after open heart surgery as well as achieving lower pain scores and narcotic requirements.

  17. How is uranium supply affecting enrichment?

    International Nuclear Information System (INIS)

    Steve Kidd

    2007-01-01

    As a result of the enlivened uranium market, momentum has in turn picked up in the enrichment sector. What are the consequences of higher uranium prices? There is, of course, a link between uranium and enrichment supply to the extent that they are at least partial substitutes. On the enrichment supply side, the most obvious feature is the gradual replacement of the old gas diffusion facilities of Usec in the USA and EURODIF in France with more modern and economical centrifuge plants. Assuming Usec can overcome the financing and technical issues surrounding its plans, the last gas diffusion capacity should disappear around 2015 and the entire enrichment market should then be using centrifuges. On the commercial side, the key anticipated developments are mostly in Russia. Although there should still continue to be substantial quantities of surplus Russian HEU available for down blending in the period beyond 2013, it is now reasonable to expect that it will be mostly consumed by internal needs, to fuel Russian-origin reactors both at home and in export markets such as China and India. Finally, as a key sensitive area for the non-proliferation of nuclear weapons, the enrichment sector is likely to be a central point of the new international arrangements which must be developed to support a buoyant nuclear sector throughout this century.

  18. Injection of Deuterium Pellets

    DEFF Research Database (Denmark)

    Sørensen, H.; Andersen, P.; Andersen, S. A.

    1984-01-01

    A pellet injection system made for the TFR tokamak at Fontenay-aux-Roses, Paris is described. 0.12-mg pellets are injected with velocities of around 600-700 m/s through a 5-m long guide tube. Some details of a new light gas gun are given; with this gun, hydrogen pellets are accelerated...... to velocities above 1400 m/s, deuterium pellets to velocities above 1300 m/s and neon pellets to velocities above 500 m/s. Finally, a new acceleration method where a pellet should be accelerated by means of a magnetically stabilised electrical discharge is discussed, and a set up for measuring of the pellet...

  19. Mixture formation of direct gasoline injection engine. In cylinder gas sampling using fast response ionization detector; Tonai funsha gasoline engine no kongoki keisei. Kosoku FID ni yoru tonai gas sampling

    Energy Technology Data Exchange (ETDEWEB)

    Yamashita, H.; Marubara, M.; Ota, N.; Kudo, H.; Yamamoto, H. [Mazda Motor Corp., Hiroshima (Japan)

    1997-10-01

    Local mixture concentration near the spark plug of a direct gasoline injection engine was observed by a fast flame ionization detector. To ensure combustion stability and good fuel economy in DISC operation, the swirl ratio and the piston configuration were optimized. Swirl is needed to retain well-vaporized and stable mixture near the spark plug especially in light load. And adequate volume in piston cavity is required for trapping curved fuel spray in it. With these specifications, the fuel economy improvement of 13 to 30 % was realized. 2 refs., 13 figs., 1 tab.

  20. TRIGA low enrichment fuel

    International Nuclear Information System (INIS)

    Gietzen, A.

    1993-01-01

    Sixty TRIGA reactors have been sold and the earliest of these are now passing twenty years of operation. All of these reactors use the uranium-zirconium hydride fuel (UZrH) which provides certain unique advantages arising out of its large prompt negative temperature coefficient, very low fission product release, and high temperature capability. Eleven of these Sixty reactors are conversions from plate fuel to TRIGA fuel which were made as a result of these advantages. With only a few exceptions, TRIGA reactors have always used low-enriched-uranium (LEU) fuel with an enrichment of 19.9%. The exceptions have either been converted from the standard low-enriched fuel to the 70% enriched FLIP fuel in order to achieve extended lifetime, or are higher powered reactors which were designed for long life using 93%-enriched uranium during the time when the use and export of highly enriched uranium (HEU) was not restricted. The advent of international policies focusing attention on nonproliferation and safeguards made the HEU fuels obsolete. General Atomic immediately undertook a development effort (nearly two years ago) in order to be in a position to comply with these policies for all future export sales and also to provide a low-enriched alternative to fully enriched plate-type fuels. This important work was subsequently partially supported by the U.S. Department of Energy. The laboratory and production tests have shown that higher uranium densities can be achieved to compensate for reducing the enrichment to 20%, and that the fuels maintain the characteristics of the very thoroughly proven standard TRIGA fuels. In May of 1978, General Atomic announced that these fuels were available for TRIGA reactors and for plate-type reactors with power levels up to 15 MW with GA's standard commercial warranty

  1. Quantitation of fluoride ion released sarin in red blood cell samples by gas chromatography-chemical ionization mass spectrometry using isotope dilution and large-volume injection.

    Science.gov (United States)

    Jakubowski, E M; McGuire, J M; Evans, R A; Edwards, J L; Hulet, S W; Benton, B J; Forster, J S; Burnett, D C; Muse, W T; Matson, K; Crouse, C L; Mioduszewski, R J; Thomson, S A

    2004-01-01

    A new method for measuring fluoride ion released isopropyl methylphosphonofluoridate (sarin, GB) in the red blood cell fraction was developed that utilizes an autoinjector, a large-volume injector port (LVI), positive ion ammonia chemical ionization detection in the SIM mode, and a deuterated stable isotope internal standard. This method was applied to red blood cell (RBC) and plasma ethyl acetate extracts from spiked human and animal whole blood samples and from whole blood of minipigs, guinea pigs, and rats exposed by whole-body sarin inhalation. Evidence of nerve agent exposure was detected in plasma and red blood cells at low levels of exposure. The linear method range of quantitation was 10-1000 pg on-column with a detection limit of approximately 2-pg on-column. In the course of method development, several conditions were optimized for the LVI, including type of injector insert, injection volume, initial temperature, pressure, and flow rate. RBC fractions had advantages over the plasma with respect to assessing nerve agent exposure using the fluoride ion method especially in samples with low serum butyrylcholinesterase activity.

  2. Uranium enrichment: heading for the abyss

    International Nuclear Information System (INIS)

    Norman, C.

    1983-01-01

    This article discusses the federal government's $2.3 billion a year business enriching uranium for nuclear power plants which is heading toward a major crisis. Due to miscalculations by the Department of Energy, it is caught with billions of dollars of construction in progress just as projected demand for enriched uranium is decreasing. At the center of the controversy is the Gas Centrifuge Plant at Portsmouth, Ohio - estimated to cost $10 billion dollars. A review of how DOE got into this situation and how they plan to solve it is presented

  3. Sensitivity improvement of ammonia determination based on flow-injection indophenol spectrophotometry with manganese(II) ion as a catalyst and analysis of exhaust gas of thermal power plant.

    Science.gov (United States)

    Tsuboi, Tomonori; Hirano, Yoshio; Shibata, Yoshinori; Motomizu, Shoji

    2002-10-01

    The sensitivity improvement of a flow-injection spectrophotometric method for the determination of ammonia was examined based on an indophenol blue coloration reaction with salicylate and hypochlorite in the presence of manganese(II) as a reaction promotion catalyst. The optimal conditions for achieving higher sensitivity of ammonia determination were examined using a three-line flow system. The limit of detection corresponding to a signal-to-noise ratio (S/N) of 3 was 0.005 mg l(-1) (approximately equal to 5 ppb) of NH4+. A calibration graph was linear in the range from 5 ppb to 1,000 ppb of ammonium ion. The relative standard deviations (n = 9) for 50 ppb and 100 ppb of ammonium ion were 6.4% and 2.2%, respectively. The proposed method was applied to the determination of ammonia in the exhaust gas of a thermal power plant. Prior to the FIA determination, ammonia in the exhaust gas was absorbed into a boric acid solution; the absorption solution was then analyzed by the proposed FIA.

  4. Supercritical fuel injection system

    Science.gov (United States)

    Marek, C. J.; Cooper, L. P. (Inventor)

    1980-01-01

    a fuel injection system for gas turbines is described including a pair of high pressure pumps. The pumps provide fuel and a carrier fluid such as air at pressures above the critical pressure of the fuel. A supercritical mixing chamber mixes the fuel and carrier fluid and the mixture is sprayed into a combustion chamber. The use of fuel and a carrier fluid at supercritical pressures promotes rapid mixing of the fuel in the combustion chamber so as to reduce the formation of pollutants and promote cleaner burning.

  5. Injectable foams for regenerative medicine.

    Science.gov (United States)

    Prieto, Edna M; Page, Jonathan M; Harmata, Andrew J; Guelcher, Scott A

    2014-01-01

    The design of injectable biomaterials has attracted considerable attention in recent years. Many injectable biomaterials, such as hydrogels and calcium phosphate cements (CPCs), have nanoscale pores that limit the rate of cellular migration and proliferation. While introduction of macroporosity has been suggested to increase cellular infiltration and tissue healing, many conventional methods for generating macropores often require harsh processing conditions that preclude their use in injectable foams. In recent years, processes such as porogen leaching, gas foaming, and emulsion-templating have been adapted to generate macroporosity in injectable CPCs, hydrogels, and hydrophobic polymers. While some of the more mature injectable foam technologies have been evaluated in clinical trials, there are challenges remaining to be addressed, such as the biocompatibility and ultimate fate of the sacrificial phase used to generate pores within the foam after it sets in situ. Furthermore, while implantable scaffolds can be washed extensively to remove undesirable impurities, all of the components required to synthesize injectable foams must be injected into the defect. Thus, every compound in the foam must be biocompatible and noncytotoxic at the concentrations utilized. As future research addresses these critical challenges, injectable macroporous foams are anticipated to have an increasingly significant impact on improving patient outcomes for a number of clinical procedures. © 2013 Wiley Periodicals, Inc.

  6. Enriched School Libraries

    Directory of Open Access Journals (Sweden)

    Thijs M. J. Nielen

    2015-12-01

    Full Text Available We compared students from schools with an enriched school library—that is, one with a larger and more up-to-date book collection—with students from schools with a typical school library. We tested effects of an enriched school library on reading motivation, reading frequency, and academic skills. Fourth- and fifth-grade students of 14 schools with an enriched library (n = 272 were compared to fourth and fifth graders from 10 control schools (n = 411. Assignment to the experimental group was external and not determined by participants within schools. Students from schools with enriched libraries scored on average half a standard deviation higher on a standardized reading comprehension test than students from control schools. Mediation analysis revealed that for girls, this effect may have been obtained as a result of an increase in reading motivation and reading frequency. For boys, only reading frequency was a significant mediator.

  7. Performance Analysis of Compositional and Modified Black-Oil Models For a Gas Lift Process Analyse des performances de modèles black-oil pour le procédé d’extraction par injection de gaz

    Directory of Open Access Journals (Sweden)

    Mahmudi M.

    2013-03-01

    Full Text Available Artificial gas lift is frequently used to boost production rate of mature oil fields. An integrated mathematical model was developed in order to track the spatial and temporal changes in various components of the continuous gas lift process. The computational demand for solving the comprehensive gas lift model highly depends on the thermodynamic treatment of the hydrocarbon fluids involved. A full compositional treatment using an equation of state provides the most accurate results but at a high computational cost. The results of this article showed that the computational cost can be halved without sacrificing accuracy by using reduced parameter stability and flash calculation procedures. It was also demonstrated that a Modified Black-Oil treatment of the fluids can provide reasonable accuracy at a much-reduced computational cost. The Modified Black-Oil treatment provides a valuable tool when the model has to be solved many hundreds of times to find the optimal combination of the gas lift parameters. Les procédés artificiels d’extraction par injection de gaz sont utilisés pour améliorer le taux de récupération des champs pétroliers matures. Un modèle mathématique intégré a été développé pour détecter de faibles changements temporels et spatiaux dans plusieurs composants des procédés continus d’extraction par injection de gaz. La solution numérique utilisée pour résoudre le modèle du procédé d’extraction dépend fortement du comportement thermodynamique des hydrocarbures impliqués. Un traitement complet de la composition utilisant une équation d’état offre les résultats les plus précis, mais à un coût de calcul très élevé. Les résultats de nos travaux de recherche montrent que l’implication des paramètres de stabilité et des procédures de calcul flash, peut diviser par deux le coût du calcul tout en gardant la précision attendue. Ces travaux montrent que la précision admissible peut être

  8. Uranium enrichment: investment options for the long term

    International Nuclear Information System (INIS)

    Anon.

    1983-01-01

    The US government supplies a major portion of the enriched uranium used to fuel most of the nuclear power plants that furnish electricity in the free world. As manager of the US uranium enrichment concern, the Department of Energy (DOE) is investigating a number of technological choices to improve enrichment service and remain a significant world supplier. The Congress will ultimately select a strategy for federal investment in the uranium enrichment enterprise. A fundamental policy choice between possible future roles - that of the free world's main supplier of enrichment services, and that of a mainly domestic supplier - will underlie any investment decision the Congress makes. The technological choices are gaseous diffusion, gas centrifuge, and atomic vapor laser isotope separation (AVLIS). A base plan and four alternatives were examined by DOE and the Congressional Budget Office. In terms of total enterprise costs, Option IV, ultimately relying on advanced gas centrifuges for enrichment services, would offer the most economic approach, with costs over the full projection period totaling $123.5 billion. Option III, ultimately relying on AVLIS without gas centrifuge enrichment or gaseous diffusion, falls next in the sequence, with costs of $128.2 billion. Options I and II, involving combinations of the gas centrifuge and AVLIS technologies, follow closely with costs of $128.7 and $129.6 billion. The base plan has costs of $136.8 billion over the projection period. 1 figure, 22 tables

  9. Early Metal Enrichment of the Intergalactic Medium by Pregalactic Outflows

    Science.gov (United States)

    Madau, Piero; Ferrara, Andrea; Rees, Martin J.

    2001-07-01

    We assess supernova-driven pregalactic outflows as a mechanism for distributing the product of stellar nucleosynthesis over large cosmological volumes prior to the reionization epoch. Supernova (SN) ejecta will escape the grasp of halos with virial temperatures Tvir>~104.3 K (corresponding to masses M>~108 h-1 Msolar at redshift z=9 when they collapse from 2 σ fluctuations) if rapid cooling can take place, and a significant fraction of their baryonic mass is converted into stars over a dynamical timescale. We study the evolution of SN-driven bubbles as they blow out from subgalactic halos and propagate into the intergalactic medium (IGM), and we show that to lift the halo gas out of the potential well, the energy injection must continue at least until blowaway occurs. If the fraction of ionizing photons that escape the dense sites of star formation into intergalactic space is greater than a few percent, pregalactic outflows will propagate into an IGM that has been prephotoionized by the same massive stars that later explode as SNe, and the expansion of the metal-enriched bubbles will be halted by the combined action of external pressure, gravity, and radiative losses. The collective explosive output of about 10,000 SNe per M>~108 h-1 Msolar halo at these early epochs could pollute vast regions of intergalactic space to a mean metallicity =ΩZ/Ωb>~0.003 (comparable to the levels observed in the Lyα forest at z~3) without hydrodynamically perturbing the IGM much, i.e., producing large variations of the baryons relative to the dark matter. Rayleigh-Taylor instabilities between the dense shell that contains pristine swept-up material and the hot, metal-enriched, low-density bubble may contribute to the mixing and diffusion of heavy elements. The volume filling factor of the ejecta is higher than 20% if the star formation efficiency is on the order of 10%. Larger filling factors (not required by current observations) may be obtained for larger efficiencies

  10. Transformations of highly enriched uranium into metal or oxide

    International Nuclear Information System (INIS)

    Nollet, P.; Sarrat, P.

    1964-01-01

    The enriched uranium workshops in Cadarache have a double purpose on the one hand to convert uranium hexafluoride into metal or oxide, and on the other hand to recover the uranium contained in scrap materials produced in the different metallurgical transformations. The principles that have been adopted for the design and safety of these workshops are reported. The nuclear safety is based on the geometrical limitations of the processing vessels. To establish the processes and the technology of these workshops, many studies have been made since 1960, some of which have led to original achievements. The uranium hexafluoride of high isotopic enrichment is converted either by injection of the gas into ammonia or by an original process of direct hydrogen reduction to uranium tetrafluoride. The uranium contained m uranium-zirconium metal scrap can be recovered by combustion with hydrogen chloride followed treatment of the uranium chloride by fluorine in order to obtain the uranium in the hexafluoride state. Recovery of the uranium contained m various scrap materials is obtained by a conventional refining process combustion of metallic scrap, nitric acid dissolution of the oxide, solvent purification by tributyl phosphate, ammonium diuranate precipitation, calcining, reduction and hydro fluorination into uranium tetrafluoride, bomb reduction by calcium and slag treatment. Two separate workshops operate along these lines one takes care of the uranium with an isotopic enrichment of up to 3 p. 100, the other handles the high enrichments. The handling of each step of this process, bearing in mind the necessity for nuclear safety, has raised some special technological problems and has led to the conception of new apparatus, in particular the roasting furnace for metal turnings, the nitric acid dissolution unit, the continuous precipitator and ever safe filter and dryer for ammonium diuranate, the reduction and hydro fluorination furnace and the slag recovery apparatus These are

  11. Method of deuterium isotope separation and enrichment

    International Nuclear Information System (INIS)

    Benson, S.W.

    1980-01-01

    A method of deuterium isotope separation and enrichment using infrared laser technology in combination with chemical processes for treating and recycling the unreacted and deuterium-depleted starting materials is described. Organic molecules of the formula RX (where R is an ethyl, isopropyl, t-butyl, or cyclopentenyl group and X is F, Cl, Br or OH) containing a normal abundance of hydrogen and deuterium are exposed to intense laser infrared radiation. An olefin containing deuterium (olefin D) will be formed, along with HX. The enriched olefin D can be stripped from the depleted stream of RX and HX, and can be burned to form enriched water or pyrolyzed to produce hydrogen gas with elevated deuterium content. The depleted RX is decomposed to olefins and RX, catalytically exchanged with normal water to restore the deuterium content to natural levels, and recombined to form RX which can be recycled. (LL)

  12. Method of deuterium isotope separation and enrichment

    International Nuclear Information System (INIS)

    Benson, S.W.

    1978-01-01

    A method of separating deuterium, i.e., heavy hydrogen, from certain naturally occurring sources using tuned infrared lasers to selectively decompose specified classes of organic molecules (i.e., RX) into enriched molecular products containing deuterium atoms is described. The deuterium containing molecules are easily separated from the starting material by absorption, distillation or other simple chemical separation techniques and methods. After evaporation such deuterium containing molecules can be burned to form water with an enriched deuterium content or pyrolyzed to form hydrogen gas with an enriched deuterium content. The undecomposed molecules and the other reaction products which are depleted of their deuterium containing species can be catalytically treated, preferably using normal water, to restore the natural abundance of deuterium and such restored molecules can then be recycled

  13. Gas chromatography/isotope ratio mass spectrometry: analysis of methanol, ethanol and acetic acid by direct injection of aqueous alcoholic and acetic acid samples.

    Science.gov (United States)

    Ai, Guomin; Sun, Tong; Dong, Xiuzhu

    2014-08-15

    Methanol, ethanol, and acetic acid are not easily extracted from aqueous samples and are susceptible to isotope fractionation in gas chromatography/isotope ratio mass spectrometry (GC/IRMS) analysis. Developing a direct dilution GC/IRMS method for aqueous samples, by adjusting the sample concentrations in common solvents to be similar to each other and using a fixed GC split ratio, is very convenient and important because any linearity effects caused by amount-dependent isotope fractionation can be avoided. The suitability of acetonitrile and acetone solvents for the GC/IRMS analysis of pure methanol, ethanol and acetic acid, and commercial liquor and vinegar samples was evaluated using n-hexane and water as control solvents. All the solvents including water were separated from the analyte on a HP-INNOWAX column and were diverted away from the combustion interface. The influence of liquor matrix on the ethanol GC/IRMS analyses was evaluated by adding pure ethanol to liquor samples. Acetonitrile and acetone gave similar δ(13) C values for pure ethanol and pure acetic acid to those obtained in water and n-hexane, and also gave similar δ(13) C values of ethanol in liquor and acetic acid in white vinegar to that obtained in water. For methanol analysis, acetonitrile and refined acetone gave similar δ(13) C values to that obtained in water, but n-hexane was not a suitable solvent. In addition, isotopic fractionation caused by solvent and solute interactions was observed. We recommend using acetonitrile for the GC/IRMS analysis of aqueous alcoholic samples, and acetone for the analysis of aqueous acetic acid samples. This direct dilution method can provide high accurate and precise GC/IRMS analysis of the relative changes in δ(13) C values of methanol, ethanol, and acetic acid. Copyright © 2014 John Wiley & Sons, Ltd.

  14. X-ray angiography perfusion imaging with an intra-arterial injection: comparative study with 15O-gas/water positron emission tomography.

    Science.gov (United States)

    Asai, Katsunori; Nakamura, Hajime; Watabe, Tadashi; Nishida, Takeo; Sakaguchi, Manabu; Hatazawa, Jun; Yoshimine, Toshiki; Kishima, Haruhiko

    2017-12-04

    X-ray angiography perfusion (XAP) is a perfusion imaging technique based on conventional DSA. In this study, we aimed to validate parameters derived from XAP by comparing them with 15 O-gas/water positron emission tomography (PET), using data from patients with chronic ischemic cerebrovascular disease. 18 consecutive patients were included. XAP was performed with intra-arterial infusion of contrast media, and a time-density curve was constructed for each cerebral hemisphere. From the curves, the relative values of mean transit time (rMTT) and wash-in rate (rWiR) were obtained by dividing the values of the right hemisphere by those of the left hemisphere. These were then compared with the relative values of cerebral blood flow (rCBF) and rMTT calculated from the PET data. XAP rWiR correlated strongly with PET rCBF (r=0.86, P<0.0001). rMTT measurements from the two modalities were also strongly correlated (r=0.85, P<0.0001). Bland-Altman analysis revealed a bias of 0.14±0.18 (95% limits of agreement -0.22 to 0.51) for PET rCBF versus XAP rWiR, and 0.016±0.093 (95% limits of agreement -0.17 to 0.20) for rMTT between the two modalities. The relative values obtained from XAP were validated across a population of patients with chronic ischemic cerebrovascular disease. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2017. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

  15. Profile of World Uranium Enrichment Programs-2009

    Energy Technology Data Exchange (ETDEWEB)

    Laughter, Mark D [ORNL

    2009-04-01

    It is generally agreed that the most difficult step in building a nuclear weapon is acquiring fissile material, either plutonium or highly enriched uranium (HEU). Plutonium is produced in a nuclear reactor, whereas HEU is produced using a uranium enrichment process. Enrichment is also an important step in the civil nuclear fuel cycle, in producing low enriched uranium (LEU) for use as fuel for nuclear reactors to generate electricity. However, the same equipment used to produce LEU for nuclear reactor fuel can also be used to produce HEU for weapons. Safeguards at an enrichment plant are the array of assurances and verification techniques that ensure uranium is not diverted or enriched to HEU. There are several techniques for enriching uranium. The two most prevalent are gaseous diffusion, which uses older technology and requires a lot of energy, and gas centrifuge separation, which uses more advanced technology and is more energy efficient. Gaseous diffusion plants (GDPs) provide about 40% of current world enrichment capacity but are being phased out as newer gas centrifuge enrichment plants (GCEPs) are constructed. Estimates of current and future enrichment capacity are always approximate, due to the constant upgrades, expansions, and shutdowns occurring at enrichment plants, largely determined by economic interests. Currently, the world enrichment capacity is approximately 56 million kilogram separative work units (SWU) per year, with 22.5 million in gaseous diffusion and more than 33 million in gas centrifuge plants. Another 34 million SWU/year of capacity is under construction or planned for the near future, almost entirely using gas centrifuge separation. Other less-efficient techniques have also been used in the past, including electromagnetic and aerodynamic separations, but these are considered obsolete, at least from a commercial perspective. Laser isotope separation shows promise as a possible enrichment technique of the future but has yet to be

  16. Detection of uranium enrichment activities using environmental monitoring techniques

    International Nuclear Information System (INIS)

    Belew, W.L.; Carter, J.A.; Smith, D.H.; Walker, R.L.

    1993-01-01

    Uranium enrichment processes have the capability of producing weapons-grade material in the form of highly enriched uranium. Thus, detection of undeclared uranium enrichment activities is an international safeguards concern. The uranium separation technologies currently in use employ UF 6 gas as a separation medium, and trace quantities of enriched uranium are inevitably released to the environment from these facilities. The isotopic content of uranium in the vegetation, soil, and water near the plant site will be altered by these releases and can provide a signature for detecting the presence of enriched uranium activities. This paper discusses environmental sampling and analytical procedures that have been used for the detection of uranium enrichment facilities and possible safeguards applications of these techniques

  17. Detection of uranium enrichment activities using environmental monitoring techniques

    Energy Technology Data Exchange (ETDEWEB)

    Belew, W.L.; Carter, J.A.; Smith, D.H.; Walker, R.L.

    1993-03-30

    Uranium enrichment processes have the capability of producing weapons-grade material in the form of highly enriched uranium. Thus, detection of undeclared uranium enrichment activities is an international safeguards concern. The uranium separation technologies currently in use employ UF{sub 6} gas as a separation medium, and trace quantities of enriched uranium are inevitably released to the environment from these facilities. The isotopic content of uranium in the vegetation, soil, and water near the plant site will be altered by these releases and can provide a signature for detecting the presence of enriched uranium activities. This paper discusses environmental sampling and analytical procedures that have been used for the detection of uranium enrichment facilities and possible safeguards applications of these techniques.

  18. Experimental study of the vaporization of a droplets injection in a fluidized gas-solid media; Etude experimentale de la vaporisation d'un jet de goutelettes au contact d'un milieu gaz-solide fluidise

    Energy Technology Data Exchange (ETDEWEB)

    Leclere, K.

    2002-09-01

    The quality of feedstock injection in the Fluid Catalytic Process (FCC) is essential to ensure a good vaporization. The vaporization should be fast so that the cracking reaction in the gaseous phase can happen within the short residence time in the riser (a few seconds). Vaporization is helped by a uniform injection of droplets as small as possible as well as a good mixing with the catalyst particles that represent the main heat source. Several models were developed to predict the droplet vaporization in a gas-solid media. However, no experimental validation exists for these models, whose predictions vary (from 1 to several hundreds of milliseconds). The objective of this study was to get a better understanding of the physical phenomena taking place during droplet vaporization. This was done in two steps. First, operating limits had to be defined to ensure an optimal vaporization and to avoid local saturation and agglomerate formation. These limits were precisely determined under laboratory conditions to validate a model that showed that agglomeration does not occur under industrial conditions. Then, a kinematic study of vaporization under operating conditions without agglomerate formation was performed. An original measurement technique was developed to get samples at very short times (tens of milliseconds). Experiments showed that heat transfer was not limiting and that mass transfer was the limiting process during vaporization. The developed model was thus based on mass transfer through a boundary layer. The validation of this model in a dense fluidized bed justified its application to operating conditions were the bed voidance is higher. A detailed study of operating parameters will help determine how to improve vaporization. (author)

  19. Noble Gas signatures of Enhanced Oil Recovery

    Science.gov (United States)

    Barry, P. H.; Kulongoski, J. T.; Tyne, R. L.; Hillegonds, D.; Byrne, D. J.; Landon, M. K.; Ballentine, C. J.

    2017-12-01

    Noble gases are powerful tracers of fluids from various oil and gas production activities in hydrocarbon reservoirs and nearby groundwater. Non-radiogenic noble gases are introduced into undisturbed oil and natural gas reservoirs through exchange with formation waters [1-3]. Reservoirs with extensive hydraulic fracturing, injection for enhanced oil recovery (EOR), and/or waste disposal also show evidence for a component of noble gases introduced from air [4]. Isotopic and elemental ratios of noble gases can be used to 1) assess the migration history of the injected and formation fluids, and 2) determine the extent of exchange between multiphase fluids in different reservoirs. We present noble gas isotope and abundance data from casing, separator and injectate gases of the Lost Hills and Fruitvale oil fields in the San Joaquin basin, California. Samples were collected as part of the California State Water Resource Control Board's Oil and Gas Regional Groundwater Monitoring Program. Lost Hills (n=7) and Fruitvale (n=2) gases are geochemically distinct and duplicate samples are highly reproducible. Lost Hills casing gas samples were collected from areas where EOR and hydraulic fracturing has occurred in the past several years, and from areas where EOR is absent. The Fruitvale samples were collected from a re-injection port. All samples are radiogenic in their He isotopes, typical of a crustal environment, and show enrichments in heavy noble gases, resulting from preferential adsorption on sediments. Fruitvale samples reflect air-like surface conditions, with higher air-derived noble gas concentrations. Lost Hills gases show a gradation from pristine crustal signatures - indicative of closed-system exchange with formation fluids - to strongly air-contaminated signatures in the EOR region. Pristine samples can be used to determine the extent of hydrocarbon exchange with fluids, whereas samples with excess air can be used to quantify the extent of EOR. Determining noble

  20. Uranium Conversion & Enrichment

    Energy Technology Data Exchange (ETDEWEB)

    Karpius, Peter Joseph [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-02-06

    The isotopes of uranium that are found in nature, and hence in ‘fresh’ Yellowcake’, are not in relative proportions that are suitable for power or weapons applications. The goal of conversion then is to transform the U3O8 yellowcake into UF6. Conversion and enrichment of uranium is usually required to obtain material with enough 235U to be usable as fuel in a reactor or weapon. The cost, size, and complexity of practical conversion and enrichment facilities aid in nonproliferation by design.

  1. Advanced uranium enrichment processes

    International Nuclear Information System (INIS)

    Clerc, M.; Plurien, P.

    1986-01-01

    Three advanced Uranium enrichment processes are dealt with in the report: AVLIS (Atomic Vapour LASER Isotope Separation), MLIS (Molecular LASER Isotope Separation) and PSP (Plasma Separation Process). The description of the physical and technical features of the processes constitutes a major part of the report. If further presents comparisons with existing industrially used enrichment technologies, gives information on actual development programmes and budgets and ends with a chapter on perspectives and conclusions. An extensive bibliography of the relevant open literature is added to the different subjects discussed. The report was drawn up by the nuclear research Centre (CEA) Saclay on behalf of the Commission of the European Communities

  2. A dynamic leaf gas-exchange strategy is conserved in woody plants under changing ambient CO2: evidence from carbon isotope discrimination in paleo and CO2 enrichment studies

    Science.gov (United States)

    Rising atmospheric [CO2], ca, is expected to affect stomatal regulation of leaf gas-exchange of woody plants, thus influencing energy fluxes as well as carbon (C), water and nutrient cycling of forests. Researchers have reported that stomata regulate leaf gas-exchange around “set...

  3. A dynamic leaf gas-exchange strategy is conserved in woody plants under changing ambient CO2 : evidence from carbon isotope discrimination in paleo and CO2 enrichment studies

    Science.gov (United States)

    Steven L. Voelker; J. Renee Brooks; Frederick C. Meinzer; Rebecca Anderson; Martin K.-F. Bader; Giovanna Battipaglia; Katie M. Becklin; David Beerling; Didier Bert; Julio L. Betancourt; Todd E. Dawson; Jean-Christophe Domec; Richard P. Guyette; Christian K??rner; Steven W. Leavitt; Sune Linder; John D. Marshall; Manuel Mildner; Jerome Ogee; Irina Panyushkina; Heather J. Plumpton; Kurt S. Pregitzer; Matthias Saurer; Andrew R. Smith; Rolf T. W. Siegwolf; Michael C. Stambaugh; Alan F. Talhelm; Jacques C. Tardif; Peter K. Van de Water; Joy K. Ward; Lisa. Wingate

    2016-01-01

    Rising atmospheric [CO2], ca, is expected to affect stomatal regulation of leaf gas-exchange of woody plants, thus influencing energy fluxes as well as carbon (C), water, and nutrient cycling of forests. Researchers have proposed various strategies for stomatal regulation of leaf gas-exchange that include maintaining a constant leaf internal [CO...

  4. Stir-bar-sorptive extraction and liquid desorption combined with large-volume injection gas chromatography-mass spectrometry for ultra-trace analysis of musk compounds in environmental water matrices.

    Science.gov (United States)

    Silva, Ana Rita M; Nogueira, J M F

    2010-03-01

    Stir-bar-sorptive extraction with liquid desorption followed by large-volume injection and capillary gas chromatography coupled to mass spectrometry in selected ion monitoring acquisition mode (SBSE-LD/LVI-GC-MS(SIM)) has been developed to monitor ultra-traces of four musks (celestolide (ADBI), galaxolide (HHCB), tonalide (AHTN) and musk ketone (MK)) in environmental water matrices. Instrumental calibration (LVI-GC-MS(SIM)) and experimental conditions that could affect the SBSE-LD efficiency are discussed. Assays performed on 30-mL water samples spiked at 200 ng L(-1) under optimized experimental conditions yielded recoveries ranging from 83.7 ± 8.1% (MK) to 107.6 ± 10.8% (HHCB). Furthermore, the experimental data were in very good agreement with predicted theoretical equilibria described by octanol-water partition coefficients (K (PDMS/W) ≈ K (O/W)). The methodology also showed excellent linear dynamic ranges for the four musks studied, with correlation coefficients higher than 0.9961, limits of detection and quantification between 12 and 19 ng L(-1) and between 41 and 62 ng L(-1), respectively, and suitable precision (ultra-trace level, overcoming several disadvantages presented by other sample-preparation techniques.

  5. Simple method for the simultaneous quantification of medium-chain fatty acids and ethyl hexanoate in alcoholic beverages by gas chromatography-flame ionization detector: development of a direct injection method.

    Science.gov (United States)

    Takahashi, Kei; Goto-Yamamoto, Nami

    2011-10-28

    Free medium-chain fatty acids (MCFAs) can negatively influence the fermentation process and taste quality in alcoholic beverages. Ethyl hexanoate is important in providing a fruit-like flavour to drinks, particularly in Japanese sake. In this study, we developed a direct injection method for a gas chromatography-flame ionization detector following the semi-purification of chemical components, such as esters, alcohols and MCFAs in alcoholic beverages. Evaluation of MCFAs by this method gave a limit of detection on the order of sub-ppm and relative standard deviations less than 10% in standard solution. Good repeatability and recovery rates against MCFAs and ethyl hexanoate were also obtained in non-distilled real alcoholic beverages. Because this method enabled us to simultaneously quantify the concentrations of MCFAs and ethyl hexanoate, the proportion of ester against MCFAs was proposed as a quality control index. This method could be suitable for routine analysis in the alcohol beverage industry. Copyright © 2011 Elsevier B.V. All rights reserved.

  6. Unattended safeguards instrumentation at centrifuge enrichment plants

    International Nuclear Information System (INIS)

    Smith, L. Eric; Lebrun, Alain R.; Labella, Rocco

    2014-01-01

    As global uranium enrichment capacity under international safeguards expands, the International Atomic Energy Agency (IAEA) is challenged to develop effective safeguards approaches at gaseous centrifuge enrichment plants, particularly high‑capacity plants, while working within budgetary constraints. New safeguards approaches should meet the high‑level verification objectives for such facilities (i.e., timely detection of: diversion of declared material, excess production beyond declared amounts, and production of enrichment levels higher than declared), but should also strive for efficiency advantages in implementation, for both the IAEA and operators. Under the Agency’s State- level approach to safeguards implementation, the Agency needs a flexible toolbox of technologies, allowing tailoring of safeguards measures for each individual enrichment facility. In this paper, the potential roles and development status for three different types of unattended measurement instrumentation are discussed. On‑Line Enrichment Monitors (OLEM) could provide continuous enrichment measurement for 100% of the declared gas flowing through unit header pipes. Unattended Cylinder Verification Stations (UCVS) could provide unattended verification of the declared uranium mass and enrichment of 100% of the cylinders moving through the plant, but also apply and verify an ‘NDA Fingerprint’ to preserve verification knowledge on the contents of each cylinder throughout its life in the facility. Sharing of the operator’s load cell signals from feed and withdrawal stations could count all cylinders introduced to the process and provide periodic monitoring of the uranium mass balance for in‑process material. The integration of load cell, OLEM and UCVS data streams offers the possibility for 100% verification of declared cylinder flow, and enables the periodic verification of the declared 235 U mass balance in the plant. These new capabilities would enhance the IAEA

  7. Availability of enrichment services

    International Nuclear Information System (INIS)

    Svenke, E.

    1977-01-01

    The report summarizes major uncertainties which are likely to influence future demands for uranium isotopic enrichment. Since for the next decade the development of nuclear power will be largely concerned with the increment in demand the timely need for enrichment capacity will be particularly sensitive to assumptions about growth rates. Existing worldwide capacity together with capacities under construction will be sufficient well into the 1980's. However, long decision and construction leadtime, uncertainty as to future demand as well as other factors, specifically high capital need, all of which entail financial risks, create hindrances to a timely development of increment. The adequacy of current technology is well demonstrated in plant operation and new technology is under way. Technology is, however, not freely available on a purely commercial basis. Commercial willingness, which anticipates a limited degree of financial risk, is requesting both long term back-up from the utilities that would parallel their firm decisions on the acquisition of nuclear power units, and a protective government umbrella. This situation depends on the symbiotic relationship that exists between the nuclear power generating organizations, the enrichment undertakings and the governments involved. The report accordingly stresses the need for a more cooperative approach and this, moreover, at the multinational level. There is otherwise a risk that proper resources and financing means will not be allocated to the enrichment sector. Export limitations that request the highest degree of industrial processing of nuclear fuel, i.e. the compulsory enrichment of natural uranium, do not serve the interests of overall industrial efficiency

  8. An Investigation on Gas Lift Performance Curve in an Oil-Producing Well

    OpenAIRE

    Saepudin, Deni; Soewono, Edy; Sidarto, Kuntjoro Adji; Gunawan, Agus Yodi; Siregar, Septoratno; Sukarno, Pudjo

    2007-01-01

    The main objective in oil production system using gas lift technique is to obtain the optimum gas injection rate which yields the maximum oil production rate. Relationship between gas injection rate and oil production rate is described by a continuous gas lift performance curve (GLPC). Obtaining the optimum gas injection rate is important because excessive gas injection will reduce production rate, and also increase the operation cost. In this paper, we discuss a mathematical model for gas li...

  9. Promotion of uranium enrichment business

    International Nuclear Information System (INIS)

    Kurushima, Morihiro

    1981-01-01

    The Committee on Nuclear Power has studied on the basic nuclear power policy, establishing its five subcommittees, entrusted by the Ministry of Nternational Trade and Industry. The results of examination by the subcommittee on uranium enrichment business are given along with a report in this connection by the Committee. In order to establish the nuclear fuel cycle, the aspect of uranium enrichment is essential. The uranium enrichment by centrifugal process has proceeded steadily in Power Reactor and Nuclear Fuel Development Corporation. The following matters are described: the need for domestic uranium enrichment, the outlook for overseas enrichment services and the schedule for establishing domestic enrichment business, the current state of technology development, the position of the prototype enrichment plant, the course to be taken to establish enrichment business the main organization operating the prototype and commercial plants, the system of supplying centrifuges, the domestic conversion of natural uranium the subsidies for uranium enrichment business. (J.P.N.)

  10. Pressure Build-up and Decay in Acid Gas Injection Operations in Reefs in the Zama Field, Canada, and Implications for CO2 Storage Variations de pression au cours de l’injection de gaz acides dans le réservoir récifal duchamp de Zama, Canada. Implications pour le stockage géologique de CO2

    Directory of Open Access Journals (Sweden)

    Pooladi-Darvish M.

    2011-03-01

    Full Text Available The objective of this paper is to examinereasons for pressure rise in the Zama X2X pool in northwestern Alberta, Canada, that was used foracid gas disposal, and whether subsequent pressure decay was a result of pressure dissipation into a larger aquifer. The Zama X2X pool, approximately 1 km2 in size, is connected to four other nearby poolsthrough a common underlying aquifer. Pressure analysis for all the pools indicates that they are in goodhydraulic communication. Initial pressure in the Zama X2X pool was approximately 15 MPa. Pressuredeclined first during oil production, stabilizing at around 10 MPa in the early 1970s, after which started toincrease such that it reached 26 MPa in 1986. Subsequently, pressure declined reaching 22 MPa by 1995just prior to starting injection of acid gas (80% CO2 and 20% H2S. The operator injected acid gas at lowerrates and wellhead pressures than those licensed by the regulatory agency. Despite significant production ofwater and hydrocarbons, the pressure in the Zama X2X pool continued to be higher than the initial reservoirpressure by more than 5 MPa, such that disposal operations were suspended in late 1998. Oil productioncontinued all this time until 2002. Numerical simulations using CMG-IMEXTM and corresponding sensitivity studies reported in this papershow that disposal of more than 1 million m3 of water between 1970 and 1988 and again in 1992-1993 inthe adjacent Zama YY pool, which is in good hydrodynamic communication with the Zama X2X poolthrough the aquifer below the oil column, is the main reason for the high pressures observed in the ZamaX2X pool. Sensitivity studies indicate that pressure decay in the X2X pool was due to fluid production.The study indicates that while pressure rise has been caused by hydraulic communication between theX2X and YY pools through the common aquifer, the aquifer was not of large volume to allow dissipationof the pressure. In addition to the case study, the implications of

  11. Uranium enrichment by centrifuge in Japan

    International Nuclear Information System (INIS)

    Watanabe, T.; Murase, T.

    1977-01-01

    The demand for enriched uranium is on the increase with nuclear power capacity in which the LWR predominates and is estimated to exceed the supply from the present facilities in the world in less than ten years. Therefore, the basic strategy for enriched uranium is investigated on the following three-point long-range program in Japan: 1. To continue negotiations to extend the current allocation by the long-term contract; 2. To seek active participation in international enrichment projects; and 3. To make efforts to develop uranium enrichment technology and to construct inland facilities. On this basis, a vigorous development program of gas centrigue process for industrialization was launched out in 1972 as a national project. Ever since substantial progress in this field has been made and development works have been increased year after year. At present, a concrete plan of a pilot plant is taking shape. Up to now, several types of centrifuges were developed, of which some were completed as prototype models, and subjected to life tests and also to extensive earthquake-resistivity tests for the characteristics of Japanese geological condition. An enrichment plant is composed of so many centrifuges that the installation and piping system of centrifuges is an important factor which has an effect on plant economy and reliability. Two types of the experimental cascade were constructed in Japan. One has been in operation since 1973, and the other since 1975. Valuable empirical data have been accumulated on cascade characteristics, maintenance scheme and so on. It will be important for the coming plants to have a flexibility to escalation of labor and energy cost, or to variation of the separative work requirement and further. An economic prospect of centrifuge enrichment process is presented

  12. Gas supply device

    International Nuclear Information System (INIS)

    Yamamoto, Tokihiro.

    1986-01-01

    Purpose: When injecting gas during plasma discharge, to prevent erronous operation of the piezoelectric valves due to vibrations and to inject gas into the vacuum vessel by accurately controlling gas flow. Constitution: The piezoelectric valve designed to control the flow of gas when charging vacuum vessels is installed between the vacuum vessel and the gas cylinder and a pulse voltage generator to control the valve (open/close) and the reverse voltage generator to apply a reverse current to the valve element are also provided. When a voltage is applied to the piezoelectric element, the piezoelectric element bends. However, when the polarity is changed, the direction of the bend is also reversed. The seat portion is pressed in proportion to the degree of bending. When gas is injected while plasma is being discharged, the gap created, due to vibrations, between the piezoelectric element and the sealing material is prevented by the application of a reverse current. This allows precise control of the gas injection volume as well as the injection interval. This assures maintenance of precise test conditions when testing thermonuclear devices. (Horiuchi, T.)

  13. Development of enrichment techniques

    International Nuclear Information System (INIS)

    Mohrhauer, H.; Krey, M.

    1993-01-01

    The experience accumulated in operating the older uranium enrichment plants in Almelo and Capenhurst was the basis for the construction of the Gronau centrifuge plant commissioned in August 1985 after three and a half years of construction. The total capacity of the three Urenco plants as of late 1992 is 2750 t SWU/a. The goal set at the beginning of centrifuge development, i.e. to achive troublefree operation of the centrifuges for more than ten years, has been attained. Enrichment by centrifuges on the whole consumes less than one permil of the electric power generated. Economic calculations show that a laser plant is hardly able to underrun the costs of separative work of a centrifuge plant. (orig.) [de

  14. South Australia, uranium enrichment

    International Nuclear Information System (INIS)

    1976-02-01

    The Report sets out the salient data relating to the establishment of a uranium processing centre at Redcliff in South Australia. It is conceived as a major development project for the Commonwealth, the South Australian Government and Australian Industry comprising the refining and enrichment of uranium produced from Australian mines. Using the data currently available in respect of markets, demand, technology and possible financial return from overseas sales, the project could be initiated immediately with hexafluoride production, followed rapidly in stages by enrichment production using the centrifuge process. A conceptual development plan is presented, involving a growth pattern that would be closely synchronised with the mining and production of yellowcake. The proposed development is presented in the form of an eight-and-half-year programme. Costs in this Report are based on 1975 values, unless otherwise stated. (Author)

  15. Safe injection procedures, injection practices, and needlestick ...

    African Journals Online (AJOL)

    Safe injection procedures, injection practices, and needlestick injuries among health care workers in operating rooms. Nermine Mohamed Tawfik Foda, Noha Selim Mohamed Elshaer, Yasmine Hussein Mohamed Sultan ...

  16. Measurements and Application of Partition Coefficients of Compounds Suitable for Tracing Gas Injected Into Oil Reservoirs Mesures et applications des coefficients de partage de composants utilisables comme gaz traceurs injectés dans des réservoirs de pétrole

    Directory of Open Access Journals (Sweden)

    Dugstad O.

    2006-11-01

    Full Text Available Tracing of injection gas in oil reservoirs is a technique used to improve the description of permeability distributions in situ. Results from dynamic laboratory experiments of gas tracers are reported. Gas tracers are delayed when flooding through a reservoir by the partitioning into the oil phase. A knowledge of this effect is important to optimize the interpretation of field tracer tests. The partition is quantified by the partition coefficient K. Two chemical tracers perfluoromethylcyclopentane (PMCP and perfluoromethylcyclohexane (PMCH and the radioactive 14C labelled ethane have been studied here. The two chemical compounds are new as reservoir tracers and no field results with these tracers are reported in the open literature. Our group has, however, recently applied these compound successfully as tracers in a North Sea reservoir. Les traceurs représentent un outil précieux pour améliorer la description des gisements. On les a utilisés pour obtenir des renseignements sur la configuration de l'écoulement des fluides injectés et sur leur vitesse, sur l'instant de percé des venues d'eau et sur leur origine précise, sur les traitements d'amélioration du balayage, sur les hétérogénéités importantes telles que fractures, barrières d'écoulement et stratifications de la perméabilité. Dans les gisements importants comportant plusieurs puits de production et plusieurs puits d'injection, il est donc souhaitable de disposer de plusieurs traceurs afin de pouvoir injecter différents traceurs ou mélanges de traceurs dans les différents puits. L'article présenté ici est une contribution a l'effort fait pour étendre le nombre de gaz traceurs fiables applicables aux gisements. L'article présente les résultats d'essais dynamiques en laboratoires dans lesquels on injecte des traceurs à travers un milieu poreux. Lorsqu'ils traversent un réservoir, les gaz traceurs sont retardés du fait de leur ségrégation dans la phase huile. La

  17. Development and start up of a co-injection system of coal tar/natural gas in blast furnace no. 4; Desarrollo y puesta en operacion de un sistema de co-inyeccion de alquitran/gas natural en el alto horno no. 4

    Energy Technology Data Exchange (ETDEWEB)

    Falcon Rodriguez, Manuel I.; Mata Esparza, Hector Rolando; Arevalo Ballesteros, Gerardo [Altos Hornos de Mexico S. A., Coahuila (Mexico)

    1993-12-31

    The crisis has attracted the world`s attention on the need for energy conservation and the development in a greater extent the utilization of carbon base fuels and other energy sources (nuclear energy). Being a blast furnace, not only an energy consumer but also an energy producer, the greatest contribution to the pig iron cost is the energy needed to melt and reduce to metallic state the iron ores, this energy is mainly derived from coke. The dependence on coal via the coking plant to produce first fusion iron is incremented day after day as a result of the high levels of production. Altos Hornos de Mexico (AHMSA), contemplated within its strategic plan, the reduction in the production of its coking plants derived from the natural aging of its furnaces, consequently the shortage of coke for productions higher than 2.6 MMT of pig iron is pending. The injection of fuels into a blast furnace through its nozzles is a technology used for the diminishing the coke consumption of coke, its use implies a change in the philosophy of the blast furnace operation, and is currently employed in most of the blast furnaces of the world. AHMSA taking advantage of coal tar production (approx. 130 tons/day) in its coking plants decided the design and put into operation a co-injection system of coal tar and natural gas. The activities tending to carry out this project were initiated on April 1993, performing all of them with its own resources, completing them on July 18, 1993, day on which the injection of coal tar/natural gas in blast furnace No. 4 in a stable form. To date (October 1993), the coal tar injection has been increased up to 36 kg/ton of pig iron. During the injection periods, the presence of operational, mechanical and instrumentation problems have not been an obstacle for the evolution on the injection, fulfilling its function of substituting coke in a replacing relationship of 1:1, i.e. 1 kg of coal tar per each kg of coke, without affecting the product quality

  18. Safe injection procedures, injection practices, and needlestick ...

    African Journals Online (AJOL)

    Nermine Mohamed Tawfik Foda

    2017-01-10

    Jan 10, 2017 ... tionnaire was administered to HCWs (n = 318) at the Alexandria Main University Hospital. Results: Safe injection procedures regarding final waste disposal were sufficiently adopted, while mea- sures regarding disposable injection equipment, waste containers, hand hygiene, as well as injection practices ...

  19. Synthesis of fertilizers nitrogen and 15N-enriched. Pt. I. Production of enriched 15N-anhydrous ammonia

    International Nuclear Information System (INIS)

    Bendassolli, J.A.; Mortatti, J.; Trivelin, P.C.O.; Victoria, R.L.

    1988-01-01

    The results of 15 N-anhydrous ammonia production through reaction between 15 N-enriched ammonium sulphate and sodium hidroxide are reported. Influence of the reaction temperature, carrier gas flow, reaction time and mass of ammonium sulphate on the production of anhydrous ammonia were studied. Analyses for the cost of production of 5% atoms in 15 N-enriched anhydrous ammonia were made. (M.A.C.) [pt

  20. Criticality analysis in uranium enrichment plant

    International Nuclear Information System (INIS)

    Okamoto, Tsuyoshi; Kiyose, Ryohei

    1977-01-01

    In a large scale uranium enrichment plant, uranium inventory in cascade rooms is not very large in quantity, but the facilities dealing with the largest quantity of uranium in that process are the UF 6 gas supply system and the blending system for controlling the product concentration. When UF 6 spills out of these systems, the enriched uranium is accumulated, and the danger of criticality accident is feared. If a NaF trap is placed at the forestage of waste gas treatment system, plenty of UF 6 and HF are adsorbed together in the NaF trap. Thus, here is the necessity of checking the safety against criticality. Various assumptions were made to perform the computation surveying the criticality of the system composed of UF 6 and HF adsorbed on NaF traps with WIMS code (transport analysis). The minimum critical radius resulted in about 53 cm in case of 3.5% enriched fuel for light water reactors. The optimum volume ratio of fissile material in the double salt UF 6 .2NaF and NaF.HF is about 40 vol. %. While, criticality survey computation was also made for the annular NaF trap having the central cooling tube, and it was found that the effect of cooling tube radius did not decrease the multiplication factor up to the cooling tube radius of about 5 cm. (Wakatsuki, Y.)

  1. Penicillin G Procaine Injection

    Science.gov (United States)

    Penicillin G procaine injection is used to treat certain infections caused by bacteria. Penicillin G procaine injection should not be used to treat ... in the treatment of certain serious infections. Penicillin G procaine injection is in a class of medications ...

  2. Experimental study of biomass gasification with oxygen-enriched air in fluidized bed gasifier.

    Science.gov (United States)

    Liu, Lingqin; Huang, Yaji; Cao, Jianhua; Liu, Changqi; Dong, Lu; Xu, Ligang; Zha, Jianrui

    2018-06-01

    Considering the universality, renewability and cleanness of biomass, an experimental research is carried out using rice straw in a two-stage fluidized bed. The experimental analysis identified the relevant parameters in the operation of the two-stage fluidized bed to investigate the properties of biomass enriched air gasification. Results show that higher gasification temperature is conducive to enhance the gasification performance. An increasing ER is shown to go against adding gas heat value. When oxygen concentration increases from 21% to 45%, the gas heating value increases from 4.00MJ/kg to 5.24MJ/kg and the gasification efficiency increases from 29.60% to 33.59%, which shows higher oxygen concentration is conducive to higher quality gas and higher gasification efficiency. A secondary oxygen injection leads to reduction of tar concentration from 15.78g/Nm 3 to 10.24g/Nm 3 . The optimal secondary oxygen ratio is about 33.00%. When the secondary oxygen ratio increased to 46.86%, monocyclic aromatics reduced from 28.17% to 19.65% and PAHs increased from 34.97% to 44.05%, leading to the increase aromatization of tar. Copyright © 2018 Elsevier B.V. All rights reserved.

  3. New Prototype Safeguards Technology Offers Improved Confidence and Automation for Uranium Enrichment Facilities

    Energy Technology Data Exchange (ETDEWEB)

    Brim, Cornelia P.

    2013-04-01

    An important requirement for the international safeguards community is the ability to determine the enrichment level of uranium in gas centrifuge enrichment plants and nuclear fuel fabrication facilities. This is essential to ensure that countries with nuclear nonproliferation commitments, such as States Party to the Nuclear Nonproliferation Treaty, are adhering to their obligations. However, current technologies to verify the uranium enrichment level in gas centrifuge enrichment plants or nuclear fuel fabrication facilities are technically challenging and resource-intensive. NNSA’s Office of Nonproliferation and International Security (NIS) supports the development, testing, and evaluation of future systems that will strengthen and sustain U.S. safeguards and security capabilities—in this case, by automating the monitoring of uranium enrichment in the entire inventory of a fuel fabrication facility. One such system is HEVA—hybrid enrichment verification array. This prototype was developed to provide an automated, nondestructive assay verification technology for uranium hexafluoride (UF6) cylinders at enrichment plants.

  4. Integrated vacuum absorption steam cycle gas separation

    Science.gov (United States)

    Chen, Shiaguo [Champaign, IL; Lu, Yonggi [Urbana, IL; Rostam-Abadi, Massoud [Champaign, IL

    2011-11-22

    Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

  5. Optimization of gas lift system in Varg field

    OpenAIRE

    Ibrahim, Abu Taher Md.

    2007-01-01

    Master's thesis in Petroleum engineering The objective of this thesis work is to obtain the optimum gas injection rate which yields the maximum oil production. Obtaining the optimum gas injection rate is important because excessive gas injection rate reduces oil production rate and increases operation cost. To obtain the optimum gas injection rate for achieving the maximum oil production, all wells had been modelled by Prosper program and network solver calculation had been performed by...

  6. ISOLDE Off-line Gas Leak Upgrade

    CERN Document Server

    Nielsen, Kristoffer Bested

    2017-01-01

    This study investigates gas injection system of the ISOLDE Off-line separator. A quadrupole mass spectrometer is used to analysis the composition of the gas. Based on these measurements a contamination of the injected gas is found and a system upgrade is purposed. Furthermore a calibration of the leak rate of the leak valve is made.

  7. Determination of low isotopic enrichment of L-[1-C-13]valine by gas chromatography combustion isotope ratio mass spectrometry : a robust method for measuring protein fractional synthetic rates in vivo

    NARCIS (Netherlands)

    Reijngoud, DJ; Hellstern, G; Elzinga, H; de Sain-van der Velden, MG; Okken, A; Stellaard, F

    A method was developed for measuring protein fractional synthetic rates using the N-methoxycarbonylmethyl ester (MCM) derivative of L-[1-C-13]valine and on-line gas chromatography/combustion/isotope ratio mass spectrometry (GC/C/IRMS). The derivatization procedure can be performed rapidly and GC

  8. High permeability heavy oil reservoir nitrogen injection EOR research

    Science.gov (United States)

    Wu, Xiaodong; Wang, Yining; Wang, Ruihe; Han, Guoqing; An, Yongsheng

    2014-05-01

    Nitrogen chemically very unreactive under normal showed great inertia. It is difficult to burn , dry, non-explosive , non-toxic , non-corrosive , and thus the use of safe and reliable. Coefficient of variation of nitrogen increases with increasing pressure , less affected by temperature . Under the same conditions, the ratio of the nitrogen gas formation volume factor carbon dioxide gas is high, about three times the carbon dioxide , the greater the elastic expansion of nitrogen play a beneficial role in flooding . EOR project trends increase the number of oil and gas injection gas injection from the calendar view, carbon dioxide miscible flooding gas injection EOR is the focus of the flue gas project currently has less to carry , nitrogen flooding is still subject to considerable attention. Note the nitrogen requirements of the basic conditions for enhanced oil recovery from major tectonic conditions , reservoir properties of crude nature of the gas injection timing and other aspects to consider , for different reservoir injected in different ways. Oilfield against a thick , high permeability and other characteristics, to improve oil recovery by injecting nitrogen indoor experiments conducted nitrogen injection process factors and supporting technical studies ; and introduced the field of nitrogen injection EOR field test conditions .

  9. Review of Membrane Oxygen Enrichment for Efficient Combustion

    Science.gov (United States)

    Ariono, Danu; Kusuma Wardani, Anita

    2017-07-01

    Oxygen enrichment from air is a simple way of increasing the efficiency of combustion process, as in oxy-combustion. Oxy-combustion has become one of the most attracting combustion technologies because of its potential to address both pollutant reduction and CO2 capture. In oxy-combustion, the fuel and recycled flue gas are combusted with oxygen enriched air (OEA). By using OEA, many benefits can be obtained, such as increasing available heat, improving ignition characteristics, flue gas reduction, increasing productivity, energy efficiency, turndown ratio, and flame stability. Membrane-based gas separation for OEA production becomes an attractive technology over the conventional technology due to the some advantages, including low capital cost, low energy consumption, compact size, and modularity. A single pass through membrane usually can enrich O2 concentration in the air up to 35% and a 50% concentration can be achieved with a double pass of membrane. The use of OEA in the combustion process eliminates the presence of nitrogen in the flue gas. Hence, the flue gas is mainly composed of CO2 and condensable water that can be easily separated. This paper gives an overview of oxy-combustion with membrane technology for oxygen enrichment process. Special attention is given to OEA production and the effect of OEA to the efficiency of combustion.

  10. The world enrichment market

    International Nuclear Information System (INIS)

    Gunter, L.; McCants, C.; Rutkowski, E.

    1991-01-01

    The enrichment market can be divided into two periods: the near-term market (1991 to 1995) and the long-term market (1995 and beyond). The near-term market is characterized by limited unfilled requirements of 4% per year, to be supplied by national stockpiles and excess inventories. This low-cost material will be drawn down by about 1993, causing a subsequent price rise. As the price rises, primary supplier activity is expected to increase. In the near-term, two contracting activities are apparent: spot; and intermediate-term. The current spot market is expected to last until available low cost inventories are drawn down. Recently, in attempts to gain market share, suppliers have offered attractively priced intermediate-term (3 year) contracts for 1996 to 1998. While a small spot market will continue after 1995, it is anticipated that utilities will prefer a mix of medium- and long-term (5 to 10 year) contracts from primary suppliers for most of their enrichment requirements. As national stockpiles and utility inventories are consumed, low-cost supply available to the spot market is expected to diminish. Consequently, with little low-cost supply available, the only apparent source of material will be from primary suppliers, and the resulting competition over market share is expected to be intense. (author)

  11. Injection related anxiety in insulin-treated diabetes.

    Science.gov (United States)

    Zambanini, A; Newson, R B; Maisey, M; Feher, M D

    1999-12-01

    The presence of injection related anxiety and phobia may influence compliance, glycaemic control and quality of life in patients with insulin-treated diabetes. Unselected consecutive, insulin-treated patients attending a diabetes clinic for follow-up, completed a standardised questionnaire providing an injection anxiety score (IAS) and general anxiety score (GAS). A total of 115 insulin-treated (80 Type 1 and 35 Type 2) diabetic patients completed the questionnaire. Injections had been avoided secondary to anxiety in 14% of cases and 42% expressed concern at having to inject more frequently. An IAS > or = 3 was seen in 28% of patients and of these, 66% injected insulin one to two times/day, 45% had avoided injections, and 70% would be bothered by more frequent injections. A significant correlation between IAS and GAS was seen (Kendall's tau-a 0.30, 95% CI 0.19-0.41, P < 0.001). GAS was significantly associated with both previous injection avoidance and expressed concern at increased injection frequency. No significant correlation was seen with HbA1c and injection or general anxiety scores. Symptoms relating to insulin injection anxiety and phobia have a high prevalence in an unselected group of diabetic patients requiring insulin injections and are associated with higher levels of general anxiety.

  12. Isotope mixture enrichment and equipment therefor

    International Nuclear Information System (INIS)

    Inchauspe, N.; Bearn, A. de.

    1973-01-01

    A mixture of isotopes of an element belonging to the third group-first subgroup, or the fourth group-first subgroup, or the sixth group-second subgroup, or the rare gases group of the periodic system in the gaseous phase is introduced into a chamber filled with a sorption medium showing fixation properties and with a damping gas, inert to the isotope mixture as well as to the sorption medium. The fraction enriched by the least adsorbed isotope may be trapped at the chamber output. (B.S.)

  13. The Sheppard Oxygen Mask: Efficient oxygen enrichment in the ...

    African Journals Online (AJOL)

    Adele

    63 Patients were studied in the post-anaesthesia care unit (PACU) and divided into three groups. Group-V received-oxygen enriched air via standard venturi masks at 8L/min fresh gas flow (FGF);. Groups S4 and S8 breathed via SOM's at FGF of 4 and 8L/min. Inspired (Fi) and expired (FE) gases, as well as blood gas ten-.

  14. Renewable gas French panorama 2016

    International Nuclear Information System (INIS)

    De Singly, Bertrand; Pinel, Julie; Garret, Mathilde; Schmit, Julien; Apolit, Robin; Bock, Roger; Pisani, Olivier; Marron, Didier

    2017-01-01

    This publication first describes how biomethane is a gaseous renewable source of energy, by outlining how biogas production and biomethane injection into the network represent a solution for the reduction of greenhouse gas emissions, and by describing the different types of biomethane injection sites and the different types of inputs used to supply these sites. Then, after a presentation and a brief discussion of some key data regarding production and consumption, this publication presents the economic context, the regulatory framework, and a map of biomethane injection in Europe. The third part presents the fleet of biomethane injection installations in France, the characteristics of the connected sites, the regional distribution of the biomethane injection sector, and the production of biomethane injection installations. The fourth part discusses the growth perspectives of this sector by proposing an overview of planned injection projects, by assessing the potential production of methanization, and by addressing prospective issues on other ways of production of renewable gas

  15. Thermal breeder fuel enrichment zoning

    Science.gov (United States)

    Capossela, Harry J.; Dwyer, Joseph R.; Luce, Robert G.; McCoy, Daniel F.; Merriman, Floyd C.

    1992-01-01

    A method and apparatus for improving the performance of a thermal breeder reactor having regions of higher than average moderator concentration are disclosed. The fuel modules of the reactor core contain at least two different types of fuel elements, a high enrichment fuel element and a low enrichment fuel element. The two types of fuel elements are arranged in the fuel module with the low enrichment fuel elements located between the high moderator regions and the high enrichment fuel elements. Preferably, shim rods made of a fertile material are provided in selective regions for controlling the reactivity of the reactor by movement of the shim rods into and out of the reactor core. The moderation of neutrons adjacent the high enrichment fuel elements is preferably minimized as by reducing the spacing of the high enrichment fuel elements and/or using a moderator having a reduced moderating effect.

  16. Radial lean direct injection burner

    Science.gov (United States)

    Khan, Abdul Rafey; Kraemer, Gilbert Otto; Stevenson, Christian Xavier

    2012-09-04

    A burner for use in a gas turbine engine includes a burner tube having an inlet end and an outlet end; a plurality of air passages extending axially in the burner tube configured to convey air flows from the inlet end to the outlet end; a plurality of fuel passages extending axially along the burner tube and spaced around the plurality of air passage configured to convey fuel from the inlet end to the outlet end; and a radial air swirler provided at the outlet end configured to direct the air flows radially toward the outlet end and impart swirl to the air flows. The radial air swirler includes a plurality of vanes to direct and swirl the air flows and an end plate. The end plate includes a plurality of fuel injection holes to inject the fuel radially into the swirling air flows. A method of mixing air and fuel in a burner of a gas turbine is also provided. The burner includes a burner tube including an inlet end, an outlet end, a plurality of axial air passages, and a plurality of axial fuel passages. The method includes introducing an air flow into the air passages at the inlet end; introducing a fuel into fuel passages; swirling the air flow at the outlet end; and radially injecting the fuel into the swirling air flow.

  17. Alkaline sorbent injection for mercury control

    Science.gov (United States)

    Madden, Deborah A.; Holmes, Michael J.

    2002-01-01

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  18. Common rail fuel injection system for improvement of engine performance and reduction of exhaust emission on heavy duty diesel engine; Common rail system ni yoru seino haishutsu gas no kaizen

    Energy Technology Data Exchange (ETDEWEB)

    Kato, T.; Koyama, T.; Sasaki, K.; Mori, K.; Mori, K. [Mitsubishi Motor Corp., Tokyo (Japan)

    1997-10-01

    With the objective of improvement of engine performance and reduction of exhaust emissions, influence of control method to decrease initial injection rate and effect of injector types on fuel leakage of common rail fuel injection system (Common Rail System) were investigated. As a results, it became clear that injector with 2-way valve brings improvement of engine performance and reduction of exhaust emissions as compared with injector with 3-way valve because injector with 2-way valve has lower fuel leakage and is able to use higher injection pressure than injector with 3-way valve. 5 refs., 13 figs., 1 tab.

  19. Gas and Gas Pains

    Science.gov (United States)

    ... to produce gas. Often, relatively simple changes in eating habits can lessen bothersome gas. Certain digestive system disorders, ... such as soda and beer, increase stomach gas. Eating habits, such as eating too quickly, drinking through a ...

  20. Improved verification methods for safeguards verifications at enrichment plants

    International Nuclear Information System (INIS)

    Lebrun, A.; Kane, S. C.; Bourva, L.; Poirier, S.; Loghin, N. E.; Langlands, D.

    2009-01-01

    The International Atomic Energy Agency (IAEA) has initiated a coordinated research and development programme to improve its verification methods and equipment applicable to enrichment plants. The programme entails several individual projects to meet the objectives of the IAEA Safeguards Model Approach for Gas Centrifuge Enrichment Plants updated in 2006. Upgrades of verification methods to confirm the absence of HEU (highly enriched uranium) production have been initiated and, in particular, the Cascade Header Enrichment Monitor (CHEM) has been redesigned to reduce its weight and incorporate an electrically cooled germanium detector. Such detectors are also introduced to improve the attended verification of UF 6 cylinders for the verification of the material balance. Data sharing of authenticated operator weighing systems such as accountancy scales and process load cells is also investigated as a cost efficient and an effective safeguards measure combined with unannounced inspections, surveillance and non-destructive assay (NDA) measurement. (authors)