WorldWideScience

Sample records for enhanced modified faraday

  1. Modified Faraday cup

    Science.gov (United States)

    Elmer, John W.; Teruya, Alan T.; O'Brien, Dennis W.

    1996-01-01

    A tomographic technique for measuring the current density distribution in electron beams using electron beam profile data acquired from a modified Faraday cup to create an image of the current density in high and low power beams. The modified Faraday cup includes a narrow slit and is rotated by a stepper motor and can be moved in the x, y and z directions. The beam is swept across the slit perpendicular thereto and controlled by deflection coils, and the slit rotated such that waveforms are taken every few degrees form 0.degree. to 360.degree. and the waveforms are recorded by a digitizing storage oscilloscope. Two-din-tensional and three-dimensional images of the current density distribution in the beam can be reconstructed by computer tomography from this information, providing quantitative information about the beam focus and alignment.

  2. Fabry-Perot enhanced Faraday rotation in graphene.

    Science.gov (United States)

    Ubrig, Nicolas; Crassee, Iris; Levallois, Julien; Nedoliuk, Ievgeniia O; Fromm, Felix; Kaiser, Michl; Seyller, Thomas; Kuzmenko, Alexey B

    2013-10-21

    We demonstrate that giant Faraday rotation in graphene in the terahertz range due to the cyclotron resonance is further increased by constructive Fabry-Perot interference in the supporting substrate. Simultaneously, an enhanced total transmission is achieved, making this effect doubly advantageous for graphene-based magneto-optical applications. As an example, we present far-infrared spectra of epitaxial multilayer graphene grown on the C-face of 6H-SiC, where the interference fringes are spectrally resolved and a Faraday rotation up to 0.15 radians (9°) is attained. Further, we discuss and compare other ways to increase the Faraday rotation using the principle of an optical cavity.

  3. Enhancement of Faraday rotation at photonic-band-gap edge in garnet-based magnetophotonic crystals

    International Nuclear Information System (INIS)

    Zhdanov, A.G.; Fedyanin, A.A.; Aktsipetrov, O.A.; Kobayashi, D.; Uchida, H.; Inoue, M.

    2006-01-01

    Spectral dependences of Faraday rotation angle in one-dimensional garnet-based magnetophotonic crystals are considered. The enhancement of Faraday angle is demonstrated at the photonic band gap (PBG) edge both theoretically and experimentally. It is shown to be associated with the optical field localization in the magnetic layers of the structure. The advantages of magnetophotonic crystals in comparison with traditional magnetic microcavities are discussed. The specially designed microcavity structures optimized for the Faraday effect enhancement at the PBG edge are suggested

  4. Surfactants non-monotonically modify the onset of Faraday waves

    Science.gov (United States)

    Strickland, Stephen; Shearer, Michael; Daniels, Karen

    2017-11-01

    When a water-filled container is vertically vibrated, subharmonic Faraday waves emerge once the driving from the vibrations exceeds viscous dissipation. In the presence of an insoluble surfactant, a viscous boundary layer forms at the contaminated surface to balance the Marangoni and Boussinesq stresses. For linear gravity-capillary waves in an undriven fluid, the surfactant-induced boundary layer increases the amount of viscous dissipation. In our analysis and experiments, we consider whether similar effects occur for nonlinear Faraday (gravity-capillary) waves. Assuming a finite-depth, infinite-breadth, low-viscosity fluid, we derive an analytic expression for the onset acceleration up to second order in ɛ =√{ 1 / Re } . This expression allows us to include fluid depth and driving frequency as parameters, in addition to the Marangoni and Boussinesq numbers. For millimetric fluid depths and driving frequencies of 30 to 120 Hz, our analysis recovers prior numerical results and agrees with our measurements of NBD-PC surfactant on DI water. In both case, the onset acceleration increases non-monotonically as a function of Marangoni and Boussinesq numbers. For shallower systems, our model predicts that surfactants could decrease the onset acceleration. DMS-0968258.

  5. Nonreciprocal plasmonics enables giant enhancement of thin-film Faraday rotation.

    Science.gov (United States)

    Chin, Jessie Yao; Steinle, Tobias; Wehlus, Thomas; Dregely, Daniel; Weiss, Thomas; Belotelov, Vladimir I; Stritzker, Bernd; Giessen, Harald

    2013-01-01

    Light propagation is usually reciprocal. However, a static magnetic field along the propagation direction can break the time-reversal symmetry in the presence of magneto-optical materials. The Faraday effect in magneto-optical materials rotates the polarization plane of light, and when light travels backward the polarization is further rotated. This is applied in optical isolators, which are of crucial importance in optical systems. Faraday isolators are typically bulky due to the weak Faraday effect of available magneto-optical materials. The growing research endeavour in integrated optics demands thin-film Faraday rotators and enhancement of the Faraday effect. Here, we report significant enhancement of Faraday rotation by hybridizing plasmonics with magneto-optics. By fabricating plasmonic nanostructures on laser-deposited magneto-optical thin films, Faraday rotation is enhanced by one order of magnitude in our experiment, while high transparency is maintained. We elucidate the enhanced Faraday effect by the interplay between plasmons and different photonic waveguide modes in our system.

  6. Enhanced Faraday rotation in one dimensional magneto-plasmonic structure due to Fano resonance

    Science.gov (United States)

    Sadeghi, S.; Hamidi, S. M.

    2018-04-01

    Enhanced Faraday rotation in a new type of magneto-plasmonic structure with the capability of Fano resonance, has been reported theoretically. A magneto-plasmonic structure composed of a gold corrugated layer deposited on a magneto-optically active layer was studied by means of Lumerical software based on finite-difference time-domain. In our proposed structure, plasmonic Fano resonance and localized surface plasmon have induced enhancement in magneto-optical Faraday rotation. It is shown that the influence of geometrical parameters in gold layer offers a desirable platform for engineering spectral position of Fano resonance and enhancement of Faraday rotation.

  7. Faraday rotation enhancement of gold coated Fe2O3 nanoparticles: comparison of experiment and theory.

    Science.gov (United States)

    Dani, Raj Kumar; Wang, Hongwang; Bossmann, Stefan H; Wysin, Gary; Chikan, Viktor

    2011-12-14

    Understanding plasmonic enhancement of nanoscale magnetic materials is important to evaluate their potential for application. In this study, the Faraday rotation (FR) enhancement of gold coated Fe(2)O(3) nanoparticles (NP) is investigated experimentally and theoretically. The experiment shows that the Faraday rotation of a Fe(2)O(3) NP solution changes from approximately 3 rad/Tm to 10 rad/Tm as 5 nm gold shell is coated on a 9.7 nm Fe(2)O(3) core at 632 nm. The results also show how the volume fraction normalized Faraday rotation varies with the gold shell thickness. From the comparison of experiment and calculated Faraday rotation based on the Maxwell-Garnett theory, it is concluded that the enhancement and shell dependence of Faraday rotation of Fe(2)O(3) NPs is a result of the shifting plasmon resonance of the composite NP. In addition, the clustering of the NPs induces a different phase lag on the Faraday signal, which suggests that the collective response of the magnetic NP aggregates needs to be considered even in solution. From the Faraday phase lag, the estimated time of the full alignment of the magnetic spins of bare (cluster size 160 nm) and gold coated NPs (cluster size 90 nm) are found to be 0.65 and 0.17 μs. The calculation includes a simple theoretical approach based on the Bruggeman theory to account for the aggregation and its effect on the Faraday rotation. The Bruggeman model provides a qualitatively better agreement with the experimentally observed Faraday rotation and points out the importance of making a connection between component properties and the average "effective" optical behavior of the Faraday medium containing magnetic nanoparticles. © 2011 American Institute of Physics

  8. Cavity-enhanced Faraday rotation measurement with auto-balanced photodetection.

    Science.gov (United States)

    Chang, Chia-Yu; Shy, Jow-Tsong

    2015-10-01

    Optical cavity enhancement for a tiny Faraday rotation is demonstrated with auto-balanced photodetection. This configuration is analyzed using the Jones matrix formalism. The resonant rotation signal is amplified, and thus, the angular sensitivity is improved. In the experiment, the air Faraday rotation is measured with an auto-balanced photoreceiver in single-pass and cavity geometries. The result shows that the measured Faraday rotation in the single-pass geometry is enhanced by a factor of 85 in the cavity geometry, and the sensitivity is improved to 7.54×10(-10)  rad Hz(-1/2), which agrees well with the Jones matrix analysis. With this verification, we propose an AC magnetic sensor whose magnetic sensitivity is expected to achieve 10  pT Hz(-1/2).

  9. Anomalous effects on radiation detectors and capacitance measurements inside a modified Faraday cage

    Energy Technology Data Exchange (ETDEWEB)

    Milián-Sánchez, V., E-mail: vicmisan@iqn.upv.es [Institute for Industrial, Radiophysical and Environmental Safety, Universitat Politècnica de València, Camino de Vera, s/n, Valencia (Spain); Mocholí-Salcedo, A., E-mail: amocholi@eln.upv.es [Traffic Control Systems Group, ITACA Institute, Universitat Politécnica de, Camino de Vera, s/n, Valencia (Spain); Milián, C., E-mail: carles.milian@cpht.polytechnique.fr [Centre de Physique Théorique, CNRS, École Polytechnique, F-91128 Palaiseau (France); Kolombet, V.A., E-mail: kolombet@iteb.ru [Institute of Theoretical and Experimental Biophysics, Russian Academy of Science, Moscow Region, Pushchino 142290 (Russian Federation); Verdú, G., E-mail: gverdu@iqn.upv.es [Institute for Industrial, Radiophysical and Environmental Safety, Universitat Politècnica de València, Camino de Vera, s/n, Valencia (Spain); Chemical and Nuclear Engineering Department, Universitat Politécnica de Valencia, Camino de Vera, s/n, Valencia (Spain)

    2016-08-21

    We present experimental results showing certain anomalies in the measurements performed inside a modified Faraday cage of decay rates of Ra-226, Tl-204 and Sr-90/I-90, of the gamma spectrum of a Cs-137 preparation, and of the capacitance of both a class-I multilayer ceramic capacitor and of the interconnection cable between the radiation detector and the scaler. Decay rates fluctuate significantly up to 5% around the initial value and differently depending on the type of nuclide, and the spectrum photopeak increases in 4.4%. In the case of the capacitor, direct capacitance measurements at 100 Hz, 10 kHz and 100 kHz show variations up to 0.7%, the most significant taking place at 100 Hz. In the case of the interconnection cable, the capacitance varies up to 1%. Dispersion also tends to increase inside the enclosure. However, the measured capacitance variations do not explain the variations observed in decay rates. - Highlights: • Background counts and decay rates changes of different nuclides are described. • Those changes are observed inside a multilayer modified Faraday cage. • Noise in a multichannel analyzer increases inside the multilayer enclosure. • Capacitance of a class-I multilayer ceramic capacitor varies inside the enclosure. • Capacitance changes depend on the used frequency.

  10. Anomalous effects on radiation detectors and capacitance measurements inside a modified Faraday cage

    International Nuclear Information System (INIS)

    Milián-Sánchez, V.; Mocholí-Salcedo, A.; Milián, C.; Kolombet, V.A.; Verdú, G.

    2016-01-01

    We present experimental results showing certain anomalies in the measurements performed inside a modified Faraday cage of decay rates of Ra-226, Tl-204 and Sr-90/I-90, of the gamma spectrum of a Cs-137 preparation, and of the capacitance of both a class-I multilayer ceramic capacitor and of the interconnection cable between the radiation detector and the scaler. Decay rates fluctuate significantly up to 5% around the initial value and differently depending on the type of nuclide, and the spectrum photopeak increases in 4.4%. In the case of the capacitor, direct capacitance measurements at 100 Hz, 10 kHz and 100 kHz show variations up to 0.7%, the most significant taking place at 100 Hz. In the case of the interconnection cable, the capacitance varies up to 1%. Dispersion also tends to increase inside the enclosure. However, the measured capacitance variations do not explain the variations observed in decay rates. - Highlights: • Background counts and decay rates changes of different nuclides are described. • Those changes are observed inside a multilayer modified Faraday cage. • Noise in a multichannel analyzer increases inside the multilayer enclosure. • Capacitance of a class-I multilayer ceramic capacitor varies inside the enclosure. • Capacitance changes depend on the used frequency.

  11. Shot-noise-limited optical Faraday polarimetry with enhanced laser noise cancelling

    International Nuclear Information System (INIS)

    Li, Jiaming; Luo, Le; Carvell, Jeff; Cheng, Ruihua; Lai, Tianshu; Wang, Zixin

    2014-01-01

    We present a shot-noise-limited measurement of optical Faraday rotations with sub-ten-nanoradian angular sensitivity. This extremely high sensitivity is achieved by using electronic laser noise cancelling and phase sensitive detection. Specially, an electronic laser noise canceller with a common mode rejection ratio of over 100 dB was designed and built for enhanced laser noise cancelling. By measuring the Faraday rotation of ambient air, we demonstrate an angular sensitivity of up to 9.0×10 −9  rad/√(Hz), which is limited only by the shot-noise of the photocurrent of the detector. To date, this is the highest angular sensitivity ever reported for Faraday polarimeters in the absence of cavity enhancement. The measured Verdet constant of ambient air, 1.93(3)×10 −9 rad/(G cm) at 633 nm wavelength, agrees extremely well with the earlier experiments using high finesse optical cavities. Further, we demonstrate the applications of this sensitive technique in materials science by measuring the Faraday effect of an ultrathin iron film

  12. Anomalous effects on radiation detectors and capacitance measurements inside a modified Faraday cage

    Science.gov (United States)

    Milián-Sánchez, V.; Mocholí-Salcedo, A.; Milián, C.; Kolombet, V. A.; Verdú, G.

    2016-08-01

    We present experimental results showing certain anomalies in the measurements performed inside a modified Faraday cage of decay rates of Ra-226, Tl-204 and Sr-90/I-90, of the gamma spectrum of a Cs-137 preparation, and of the capacitance of both a class-I multilayer ceramic capacitor and of the interconnection cable between the radiation detector and the scaler. Decay rates fluctuate significantly up to 5% around the initial value and differently depending on the type of nuclide, and the spectrum photopeak increases in 4.4%. In the case of the capacitor, direct capacitance measurements at 100 Hz, 10 kHz and 100 kHz show variations up to 0.7%, the most significant taking place at 100 Hz. In the case of the interconnection cable, the capacitance varies up to 1%. Dispersion also tends to increase inside the enclosure. However, the measured capacitance variations do not explain the variations observed in decay rates.

  13. Anomalous effects of radioactive decay rates and capacitance values measured inside a modified Faraday cage: Correlations with space weather

    Science.gov (United States)

    Scholkmann, F.; Milián-Sánchez, V.; Mocholí-Salcedo, A.; Milián, C.; Kolombet, V. A.; Verdú, G.

    2017-03-01

    Recently we reported (Milián-Sánchez V. et al., Nucl. Instrum. Methods A, 828 (2016) 210) our experimental results involving 226Ra decay rate and capacitance measurements inside a modified Faraday cage. Our measurements exhibited anomalous effects of unknown origin. In this letter we report new results regarding our investigation into the origins of the observed effects. We report preliminary findings of a correlation analysis between the radioactive decay rates and capacitance time series and space weather related variables (geomagnetic field disturbances and cosmic-ray neutron counts). A significant correlation was observed for specific data sets. The results are presented and possible implications for future work discussed.

  14. Large enhancement of Faraday rotation by localized surface plasmon resonance in Au nanoparticles embedded in Bi:YIG film

    International Nuclear Information System (INIS)

    Uchida, H.; Masuda, Y.; Fujikawa, R.; Baryshev, A.V.; Inoue, M.

    2009-01-01

    A large enhancement of the Faraday rotation, which is associated with localized surface plasmon resonance (LSPR), was obtained in a sample with Au nanoparticles embedded in a Bi-substituted yttrium iron garnet (Bi:YIG) film. On a quartz substrate, Au nanoparticles were formed by heating an Au thin film, and a Bi:YIG film was then deposited on them. A sample containing the Au nanoparticles produced by 1000 deg. C heating showed a resonant attenuation with narrower bandwidth in the transmission spectrum than nanoparticles of other samples formed by low-temperature heating. The sharp resonant Faraday rotation angle was 4.4 times larger than the estimated intrinsic Bi:YIG film at the LSPR wavelength; the angular difference was 0.14 deg. A discrepancy in the bandwidth between the transmission attenuation and the resonant Faraday rotation is discussed

  15. Slit disk for modified faraday cup diagnostic for determining power density of electron and ion beams

    Science.gov (United States)

    Teruya, Alan T [Livermore, CA; Elmer,; John, W [Danville, CA; Palmer, Todd A [State College, PA

    2011-03-08

    A diagnostic system for characterization of an electron beam or an ion beam includes an electrical conducting disk of refractory material having a circumference, a center, and a Faraday cup assembly positioned to receive the electron beam or ion beam. At least one slit in the disk provides diagnostic characterization of the electron beam or ion beam. The at least one slit is located between the circumference and the center of the disk and includes a radial portion that is in radial alignment with the center and a portion that deviates from radial alignment with the center. The electron beam or ion beam is directed onto the disk and translated to the at least one slit wherein the electron beam or ion beam enters the at least one slit for providing diagnostic characterization of the electron beam or ion beam.

  16. Highlights from Faraday Discussion FDSERS17: Surface Enhanced Raman Scattering - SERS, Glasgow, UK, 30th August-1st September 2017.

    Science.gov (United States)

    Di Martino, G; Fleming, H; Kamp, M; Lussier, F

    2017-11-28

    The 2017 Faraday Discussion on Surface Enhanced Raman Scattering (SERS) attracted more than a hundred delegates from a broad spectrum of backgrounds and experience levels, bringing together leading scientists involved in the long living field of SERS. The meeting gave an overview of the liveliness of the topic, characterised by open questions and fascinating science still to discover. In the following, we discuss the topics covered during this meeting and briefly highlight the content of each presentation.

  17. Novel configuration for an enhanced and compact all-fiber Faraday rotator with matched birefringence.

    Science.gov (United States)

    Asraf, Sagie; Sintov, Yoav; Zalevsky, Zeev

    2017-08-07

    We propose a novel configuration for an improved and compact all fiber Faraday rotator based on phase matching between the Faraday rotation and bend-induced birefringence. The device utilizes a coiled fiber within two electro-magnetic toroids, such that the fiber length required for getting the beat length is quite long and several rounds of fiber are needed. Analysis of the capabilities of the proposed device and its sensitivity to different parameters is presented. Faraday rotation of 13° was experimentally measured in six meters of single mode silica fiber, with a magnetic field of about 0.06T at a wavelength of 1064nm. We show that phase matching between the two phenomena significantly improves the polarization rotation by a factor of 4-10. In addition, we demonstrate the ability to achieve higher rotation by using Fabry Perot resonator in low terbium doped glass.

  18. Enhancement of magneto-optical Faraday effects and extraordinary optical transmission in a tri-layer structure with rectangular annular arrays.

    Science.gov (United States)

    Lei, Chengxin; Chen, Leyi; Tang, Zhixiong; Li, Daoyong; Cheng, Zhenzhi; Tang, Shaolong; Du, Youwei

    2016-02-15

    The properties of optics and magneto-optical Faraday effects in a metal-dielectric tri-layer structure with subwavelength rectangular annular arrays are investigated. It is noteworthy that we obtained the strongly enhanced Faraday rotation of the desired sign along with high transmittance by optimizing the parameters of the nanostructure in the visible spectral ranges. In this system, we obtained two extraordinary optical transmission (EOT) resonant peaks with enhanced Faraday rotations, whose signs are opposite, which may provide the possibility of designing multi-channel magneto-optical devices. Study results show that the maximum of the figure of merit (FOM) of the structure can be obtained between two EOT resonant peaks accompanied by an enhanced Faraday rotation. The positions of the maximum value of the FOM and resonant peaks of transmission along with a large Faraday rotation can be tailored by simply adjusting the geometric parameters of our models. These research findings are of great importance for future applications of magneto-optical devices.

  19. Enhancement of Faraday effect in one-dimensional magneto-optical photonic crystal including a magnetic layer with wavelength dependent off-diagonal elements of dielectric constant tensor

    International Nuclear Information System (INIS)

    Inui, Chie; Ozaki, Shinsuke; Kura, Hiroaki; Sato, Tetsuya

    2011-01-01

    Optical and magneto-optical properties of one-dimensional magneto-optical photonic crystal (1-D MPC) prepared by the sol-gel dip-coating method, including a magnetic defect layer composed of mixture of CoFe 2 O 4 and SiO 2 , are investigated from both the experimental and theoretical standpoints. The resonant transmission of light was observed around 570 nm in the photonic band gap. The Faraday rotation angle θ F showed two maxima at 490 and 640 nm, and the wavelength dependence of θ F above 760 nm was similar to that of the CoFe 2 O 4 +SiO 2 single-layer film. The two maxima of θ F are attributed to the enhanced Faraday rotation of nonmagnetic TiO 2 layers in the cavity structure and that in magnetic CoFe 2 O 4 +SiO 2 layer through the light localization in MPC. The maximum value of θ F due to the magnetic CoFe 2 O 4 +SiO 2 layer in the MPC was 22-times larger than that in the single-layer film. The simulation study of MPC with CoFe 2 O 4 +SiO 2 magnetic defect layer, based on the matrix approach method, showed that the resonant light transmission was accompanied by the localization of electric field, and large enhancement of θ F appeared at different wavelengths so as to agree with the experimental features. This can be explained in terms of the wavelength dependent off-diagonal components of the dielectric constant tensor in addition to the large extinction coefficient in the CoFe 2 O 4 +SiO 2 magnetic defect layer. - Highlights: → 1-D magnetic photonic crystal (MPC) prepared by sol-gel method. → Enhancement of Faraday rotation due to the magnetic defect layer of CoFe 2 O 4 . → Shift of wavelength of Faraday rotation maximum from resonant light transmission.

  20. Inverse Faraday Effect Revisited

    Science.gov (United States)

    Mendonça, J. T.; Ali, S.; Davies, J. R.

    2010-11-01

    The inverse Faraday effect is usually associated with circularly polarized laser beams. However, it was recently shown that it can also occur for linearly polarized radiation [1]. The quasi-static axial magnetic field by a laser beam propagating in plasma can be calculated by considering both the spin and the orbital angular momenta of the laser pulse. A net spin is present when the radiation is circularly polarized and a net orbital angular momentum is present if there is any deviation from perfect rotational symmetry. This orbital angular momentum has recently been discussed in the plasma context [2], and can give an additional contribution to the axial magnetic field, thus enhancing or reducing the inverse Faraday effect. As a result, this effect that is usually attributed to circular polarization can also be excited by linearly polarized radiation, if the incident laser propagates in a Laguerre-Gauss mode carrying a finite amount of orbital angular momentum.[4pt] [1] S. ALi, J.R. Davies and J.T. Mendonca, Phys. Rev. Lett., 105, 035001 (2010).[0pt] [2] J. T. Mendonca, B. Thidé, and H. Then, Phys. Rev. Lett. 102, 185005 (2009).

  1. Faraday instability on patterned surfaces

    Science.gov (United States)

    Feng, Jie; Rubinstein, Gregory; Jacobi, Ian; Stone, Howard

    2013-11-01

    We show how micro-scale surface patterning can be used to control the onset of the Faraday instability in thin liquid films. It is well known that when a liquid film on a planar substrate is subject to sufficient vibrational accelerations, the free surface destabilizes, exhibiting a family of non-linear standing waves. This instability remains a canonical problem in the study of spontaneous pattern formation, but also has practical uses. For example, the surface waves induced by the Faraday instability have been studied as a means of enhanced damping for mechanical vibrations (Genevaux et al. 2009). Also the streaming within the unstable layer has been used as a method for distributing heterogeneous cell cultures on growth medium (Takagi et al. 2002). In each of these applications, the roughness of the substrate significantly affects the unstable flow field. We consider the effect of patterned substrates on the onset and behavior of the Faraday instability over a range of pattern geometries and feature heights where the liquid layer is thicker than the pattern height. Also, we describe a physical model for the influence of patterned roughness on the destabilization of a liquid layer in order to improve the design of practical systems which exploit the Faraday instability.

  2. Michael Faraday's Bicentenary.

    Science.gov (United States)

    Williams, L. Pearce; And Others

    1991-01-01

    Six articles discuss the work of Michael Faraday, a chemist whose work revolutionized physics and led directly to both classical field and relativity theory. The scientist as a young man, the electromagnetic experiments of Faraday, his search for the gravelectric effect, his work on optical glass, his laboratory notebooks, and his creative use of…

  3. Broadband Faraday isolator.

    Science.gov (United States)

    Berent, Michał; Rangelov, Andon A; Vitanov, Nikolay V

    2013-01-01

    Driving on an analogy with the technique of composite pulses in quantum physics, we theoretically propose a broadband Faraday rotator and thus a broadband optical isolator, which is composed of sequences of ordinary Faraday rotators and achromatic quarter-wave plates rotated at the predetermined angles.

  4. Faraday effect and solar neutrino problem

    International Nuclear Information System (INIS)

    Nawaz, S.

    2001-01-01

    We have studied the Faraday effect and solar neutrino problem. Our main emphasis was on the Faraday rotation of neutrino de Broglie wave of electron-neutrino producing in the nuclear reactions in the sun and converting into any other flavor of neutrino while passing through matter and/or magnetic field of the sun. We have shown that specific Faraday angle can minimize the number of free parameters occurring in the neutrino oscillation. We have also shown that the resonant Faraday angle corresponding to the resonance of MSW effect can be obtained the knowledge of the oscillation parameter delta m/sup 2/ and the neutrino energy. Using neutrino-Faraday angle approach, we have shown that the matter enhanced neutrino oscillations is dominating over the resonant spin flavor precession (RSFP) even in the favorable region of the spin flavor procession. Using the latest solar neutrino data, we have shown that Faraday angle is almost 10/sup -3/ times smaller. This can be interpreted as the interaction of magnetic moment of neutrino with the solar magnetic field is negligibly small as compare to the effect of matter field on the neutrino oscillation. (author)

  5. Real time Faraday spectrometer

    Science.gov (United States)

    Smith, Jr., Tommy E.; Struve, Kenneth W.; Colella, Nicholas J.

    1991-01-01

    This invention uses a dipole magnet to bend the path of a charged particle beam. As the deflected particles exit the magnet, they are spatially dispersed in the bend-plane of the magnet according to their respective momenta and pass to a plurality of chambers having Faraday probes positioned therein. Both the current and energy distribution of the particles is then determined by the non-intersecting Faraday probes located along the chambers. The Faraday probes are magnetically isolated from each other by thin metal walls of the chambers, effectively providing real time current-versus-energy particle measurements.

  6. Real time Faraday spectrometer

    International Nuclear Information System (INIS)

    Smith, T.E.; Struve, K.W.; Colella, N.J.

    1991-01-01

    This patent describes an invention which uses a dipole magnet to bend the path of a charged particle beam. As the deflected particles exit the magnet, they are spatially dispersed in the bend-plane of the magnet according to their respective momenta and pass to a plurality of chambers having Faraday probes positioned therein. Both the current and energy distribution of the particles is then determined by the non-intersecting Faraday probes located along the chambers. The Faraday probes are magnetically isolated from each other by thin metal walls of the chambers, effectively providing real time current-versus-energy particle measurements

  7. The Flexible Faraday Cage

    Science.gov (United States)

    Gluck, Paul

    2004-03-01

    The Faraday ice-pail experiment is performed when studying the distribution of charges in conductors: Inside a hollow conductor the net charge is zero, and any excess charge resides on the outside surface.

  8. Michael Faraday, media man.

    Science.gov (United States)

    Fara, Patricia

    2006-03-01

    Michael Faraday was an enthusiastic portrait collector, and he welcomed the invention of photography not only as a possible means of recording observations accurately, but also as a method for advertising science and its practitioners. This article (which is part of the Science in the Industrial Revolution series) shows that like many eminent scientists, Faraday took advantage of the burgeoning Victorian media industry by posing in various roles.

  9. Optical isolation by Faraday rotator

    International Nuclear Information System (INIS)

    Kasai, Takeshi; Matsushima, Isao; Nemoto, Fusashi; Yano, Masaaki

    1984-01-01

    Three Faraday rotators designed as optical isolators in a high power glass laser system are described. The spatial fluctuation of applied magnetic field is less than 1% throughout the Faraday glass rod. The Faraday rotators transmit more than 80% of the forward-going laser light and reject more than 96% of the backward-going light. (author)

  10. The Faraday effect revisited

    DEFF Research Database (Denmark)

    Cornean, Horia; Nenciu, Gheorghe

    2009-01-01

    This paper is the second in a series revisiting the (effect of) Faraday rotation. We formulate and prove the thermodynamic limit for the transverse electric conductivity of Bloch electrons, as well as for the Verdet constant. The main mathematical tool is a regularized magnetic and geometric...

  11. Following Michael Faraday's Footprints

    Science.gov (United States)

    Galeano, Javier

    2011-01-01

    Last fall I had the good fortune of receiving financial support to shoot a documentary about Michael Faraday. I took the opportunity to learn more about this great experimentalist and to visit the highlights of places in his life. In this paper, I would like to share a list and description of some of the most remarkable places in London suitable…

  12. SMAP Faraday Rotation

    Science.gov (United States)

    Le Vine, David

    2016-01-01

    Faraday rotation is a change in the polarization as signal propagates through the ionosphere. At L-band it is necessary to correct for this change and measurements are made on the spacecraft of the rotation angle. These figures show that there is good agreement between the SMAP measurements (blue) and predictions based on models (red).

  13. Fluorescence enhancement of modified silver nanoparticles.

    Science.gov (United States)

    Liu, Meicen; Zhang, Zhenglong; Liu, Gaining; Dong, Jun; Sun, Yu; Zheng, Hairong; Li, Guian

    2011-11-01

    Surface enhanced fluorescence (SEF) effect of acridine orange fluorophore in the proximity of silver nanoparticles (NPs) has been investigated experimentally in the aqueous solution system. It was found that the SEF effect could be influenced by the distribution of the NPs and the separation between the fluorophore molecule and metal surface. The fluorescence enhancement was improved significantly when Ag NPs was capped with 4-Aminothiophenol (PATP) that was acted as an isolating layer between the metal surface and fluorophore molecules. The results suggest that a proper distribution of metallic NPs and proper separation between fluorophore molecule and the particle surface are important for obtaining an optimal SEF effect.

  14. Modified MIMO Cube for Enhanced Channel Capacity

    Directory of Open Access Journals (Sweden)

    Lajos Nagy

    2012-01-01

    Full Text Available This paper deals with the optimization of MIMO antenna elements' position in modified MIMO cube for getting maximal channel capacity in indoor environment. The dependence of the channel capacity on the antenna orientation was analyzed by simulations. We have also examined the effect of the frequency dependence of the antenna system (in case of conjugate matching and nonconjugate matching for the channel capacity. Based on the simulation results in the created and measured antenna system, the antennas were at a right angle to each other. At the two chosen different structures, we measured the antenna parameters and the channel capacity. In this paper, we present the results of the measurements which clearly confirm our simulations. We will point out the differences between the two antenna structures.

  15. Faraday effect in hybrid magneto-plasmonic photonic crystals.

    Science.gov (United States)

    Caballero, B; García-Martín, A; Cuevas, J C

    2015-08-24

    We present a theoretical study of the Faraday effect in hybrid magneto-plasmonic crystals that consist of Au-Co-Au perforated membranes with a periodic array of sub-wavelength holes. We show that in these hybrid systems the interplay between the extraordinary optical transmission and the magneto-optical activity leads to a resonant enhancement of the Faraday rotation, as compared to purely ferromagnetic membranes. In particular, we determine the geometrical parameters for which this enhancement is optimized and show that the inclusion of a noble metal like Au dramatically increases the Faraday rotation over a broad bandwidth. Moreover, we show that the analysis of the Faraday rotation in these periodically perforated membranes provides a further insight into the origin of the extraordinary optical transmission.

  16. Mobile Phone Faraday Cage

    OpenAIRE

    French, M M J

    2011-01-01

    A Faraday cage is an interesting physics phenomena where an electromagnetic wave can be excluded from a volume of space by enclosure with an electrically conducting material. The practical application of this in the classroom is to block the signal to a mobile phone by enclosing it in a metal can! The background of the physics behind this is described in some detail followed by a explanation of some demonstrations and experiments which I have used.

  17. Michael Faraday vs. the Spiritualists

    Science.gov (United States)

    Hirshfeld, Alan

    2006-12-01

    In the 1850s, renowned physicist Michael Faraday launched a public campaign against pseudoscience and spiritualism, which were rampant in England at the time. Faraday objected especially to claims that electrical or magnetic forces were responsible for paranormal phenomena, such as table-spinning and communication with the dead. Using scientific methods, Faraday unmasked the deceptions of spiritualists, clairvoyants and mediums and also laid bare the credulity of a public ill-educated in science. Despite his efforts, Victorian society's fascination with the paranormal swelled. Faraday's debacle anticipates current controversies about public science education and the interface between science and religion. This episode is one of many described in the new biography, The Electric Life of Michael Faraday (Walker & Co.), which chronicles Faraday's discoveries and his unlikely rise from poverty to the pinnacle of the English science establishment.

  18. Faraday instability and Faraday patterns in a superfluid Fermi gas

    International Nuclear Information System (INIS)

    Tang Rongan; Xue Jukui; Li Haocai

    2011-01-01

    With the consideration of the coupling between the transverse width and the longitudinal density, the parametric excitations related to Faraday waves in a cigar-shaped superfluid Fermi gas are studied. A Mathieu equation is obtained, and it is demonstrated firstly that the excited actual 3D Faraday pattern is the combination of the longitudinal Faraday density wave and the corresponding transverse width fluctuation in the longitudinal direction. The Faraday instability growth index and the kinematic equations of the Faraday density wave and the width fluctuation along the Bose-Einstein condensate (BEC)-Bardeen-Cooper-Schrieffer (BCS) crossover are also given for the first time. It is found that the 3D Faraday pattern presents quite different behaviours (such as the excitations and the motions) when the system crosses from the BEC side to the BCS side. The coupling not only plays an important role in the parametric excitation, but also determines the dominant wavelength of the spatial structure. Along the crossover, the coupling effects are more significant in the BCS side. The final numerical investigation verifies these results and gives a detailed study of the parametric excitations (i.e. Faraday instability) and the 3D pattern formation.

  19. Inverse Faraday effect with plasmon beams

    International Nuclear Information System (INIS)

    Ali, S; Mendonca, J T

    2011-01-01

    The angular momentum conservation equation is considered for an electron gas, in the presence of Laguerre-Gaussian (LG) plasmons propagating along the z-axis. The LG plasmons carry a finite orbital angular momentum despite longitudinal nature, which can be partly transfered to the electrons. For short timescales, such that ion motion can be neglected, plasmons primarily interact with the electrons, creating an azimuthal electric field and generating an axial magnetic field. This effect can be called an inverse Faraday effect due to plasmons. Numerically, it is found that the magnitude of the magnetic field enhances with the plasmon density or with the energy of the electron plasma waves. A comparison of the magnitudes of the axial magnetic field is made for the inverse Faraday effect excited by both plasmons and transverse photons.

  20. Faraday imaging at high temperatures

    Science.gov (United States)

    Hackel, Lloyd A.; Reichert, Patrick

    1997-01-01

    A Faraday filter rejects background light from self-luminous thermal objects, but transmits laser light at the passband wavelength, thus providing an ultra-narrow optical bandpass filter. The filter preserves images so a camera looking through a Faraday filter at a hot target illuminated by a laser will not see the thermal radiation but will see the laser radiation. Faraday filters are useful for monitoring or inspecting the uranium separator chamber in an atomic vapor laser isotope separation process. Other uses include viewing welds, furnaces, plasma jets, combustion chambers, and other high temperature objects. These filters are can be produced at many discrete wavelengths. A Faraday filter consists of a pair of crossed polarizers on either side of a heated vapor cell mounted inside a solenoid.

  1. SPARSE FARADAY ROTATION MEASURE SYNTHESIS

    International Nuclear Information System (INIS)

    Andrecut, M.; Stil, J. M.; Taylor, A. R.

    2012-01-01

    Faraday rotation measure synthesis is a method for analyzing multichannel polarized radio emissions, and it has emerged as an important tool in the study of Galactic and extragalactic magnetic fields. The method requires the recovery of the Faraday dispersion function from measurements restricted to limited wavelength ranges, which is an ill-conditioned deconvolution problem. Here, we discuss a recovery method that assumes a sparse approximation of the Faraday dispersion function in an overcomplete dictionary of functions. We discuss the general case when both thin and thick components are included in the model, and we present the implementation of a greedy deconvolution algorithm. We illustrate the method with several numerical simulations that emphasize the effect of the covered range and sampling resolution in the Faraday depth space, and the effect of noise on the observed data.

  2. Faraday anomalous dispersion optical tuners

    Science.gov (United States)

    Wanninger, P.; Valdez, E. C.; Shay, T. M.

    1992-01-01

    Common methods for frequency stabilizing diode lasers systems employ gratings, etalons, optical electric double feedback, atomic resonance, and a Faraday cell with low magnetic field. Our method, the Faraday Anomalous Dispersion Optical Transmitter (FADOT) laser locking, is much simpler than other schemes. The FADOT uses commercial laser diodes with no antireflection coatings, an atomic Faraday cell with a single polarizer, and an output coupler to form a compound cavity. This method is vibration insensitive, thermal expansion effects are minimal, and the system has a frequency pull in range of 443.2 GHz (9A). Our technique is based on the Faraday anomalous dispersion optical filter. This method has potential applications in optical communication, remote sensing, and pumping laser excited optical filters. We present the first theoretical model for the FADOT and compare the calculations to our experimental results.

  3. Faraday imaging at high temperatures

    International Nuclear Information System (INIS)

    Hackel, L.A.; Reichert, P.

    1997-01-01

    A Faraday filter rejects background light from self-luminous thermal objects, but transmits laser light at the passband wavelength, thus providing an ultra-narrow optical bandpass filter. The filter preserves images so a camera looking through a Faraday filter at a hot target illuminated by a laser will not see the thermal radiation but will see the laser radiation. Faraday filters are useful for monitoring or inspecting the uranium separator chamber in an atomic vapor laser isotope separation process. Other uses include viewing welds, furnaces, plasma jets, combustion chambers, and other high temperature objects. These filters are can be produced at many discrete wavelengths. A Faraday filter consists of a pair of crossed polarizers on either side of a heated vapor cell mounted inside a solenoid. 3 figs

  4. The correspondance of Michael Faraday

    CERN Document Server

    1991-01-01

    The initial volume of the correspondence of Micahel Faraday (1791-1867), published in the year of the bicentenary of his birth, covers his early years up to his discovery of electromagnetic induction in 1831. Other scientific and technical topics covered include Faraday's discovery of electromagnetic rotations (in 1821), the liquefaction of gases (in 1823) and the long series of experiments in the latter part of the 1820s to improve optical glass.

  5. Faraday rotation measurements at Ootacamund

    Science.gov (United States)

    Sethia, G.; Chandra, H.; Deshpande, M. R.; Rastogi, R. G.

    1978-01-01

    The results of Faraday rotation measurements made at Ootacamund during ATS-6 phase II are presented. For summer and equinoctial months, even though no clear noon bite-out is observed in the variation of Faraday a decrease is observed in the rate of increase of rotation around 0900-1000 hours LT. This is attributed to the 'fountain effect' which is responsible for the noontime bite-out in F2-region peak electron density.

  6. Active Faraday optical frequency standard.

    Science.gov (United States)

    Zhuang, Wei; Chen, Jingbiao

    2014-11-01

    We propose the mechanism of an active Faraday optical clock, and experimentally demonstrate an active Faraday optical frequency standard based on narrow bandwidth Faraday atomic filter by the method of velocity-selective optical pumping of cesium vapor. The center frequency of the active Faraday optical frequency standard is determined by the cesium 6 (2)S(1/2) F=4 to 6 (2)P(3/2) F'=4 and 5 crossover transition line. The optical heterodyne beat between two similar independent setups shows that the frequency linewidth reaches 281(23) Hz, which is 1.9×10(4) times smaller than the natural linewidth of the cesium 852-nm transition line. The maximum emitted light power reaches 75 μW. The active Faraday optical frequency standard reported here has advantages of narrow linewidth and reduced cavity pulling, which can readily be extended to other atomic transition lines of alkali and alkaline-earth metal atoms trapped in optical lattices at magic wavelengths, making it useful for new generation of optical atomic clocks.

  7. Faraday effect in semimagnetic semiconductors

    International Nuclear Information System (INIS)

    Nikitin, P.I.; Savchuk, A.I.

    1990-01-01

    Experimental and theoretical studies of the Faraday effect in a new class of materials -semimagnetic semiconductors (SS) have been received. Mechanisms of the giant Faraday effect in SS based on s, p-d exchange interaction of excitons, electrons and holes with magnetic ions have been discussed. Faraday rotation as a function of a radiation wavelength, magnetic component concentration, temperature, magnetic field intensity for crystals A 2 B 6 (Mn)A 2 x -1Mn xB 6 : and other SS (GaAs(Mn), CdP 2 (Mn),Pb 1-X2 )Mn x J 2 have been considered. We have attended to use FR for the study of a paramagnetic-spin glass transmission for determining the role of the relaxation effects with a participation of magnetic Mn 2+ ions, exitons, polarons in the direct and inverse Faraday effects. In addition the features of FR in thin films of SS and in spin superlattices have been discussed. Finally, we have analysed possibilities of applying the SS Faraday effect for developing magnetooptic devices (optical isolators and fibre optic sensors of magnetic fields)

  8. Neutrino oscillations and a new Faraday effect

    International Nuclear Information System (INIS)

    Anwar Mughal, M.; Ahmed, K.

    1992-07-01

    By analogy with the classical Faraday effect for the electromagnetic waves, a Faraday effect for massive neutrinos is found to be a somewhat generic description of neutrino oscillations when the neutrinos traverse a dense medium with or without a magnetic field. We further plot the Faraday angle for the solar neutrino problem as an illustration of the fact that the Faraday effect may yield a conceptually convenient parametrization of various neutrino oscillation scenarios. (author). 8 refs, 3 figs

  9. Enhanced fluoride adsorption using Al (III) modified calcium hydroxyapatite

    International Nuclear Information System (INIS)

    Nie, Yulun; Hu, Chun; Kong, Chuipeng

    2012-01-01

    Highlights: ► Al modified hydroxyapatite possessed a higher defluoridation capacity of 32.57 mg/g. ► Hydroxyl groups on the surface of Al-HAP was the adsorption sites for F − removal. ► Enhanced F − removal over Al-HAP was attributed to the modification with aluminum. - Abstract: Aluminum-modified hydroxyapatite (Al-HAP) was prepared and characterized using XRD and BET analyses. Al-HAP possessed higher defluoridation capacity (DC) of 32.57 mgF − /g than unmodified hydroxyapatite (HAP) which showed a DC of 16.38 mgF − /g. The effect of Al/Ca atomic ratio in Al-HAP, solution pH and co-existing anions was further studied. The results indicated that the adsorption data could be well described by the Langmuir isotherm model and the adsorption kinetic followed the pseudo-second-order model. The pH changes during the adsorption process suggested that the -OH on the surface of Al-HAP was the adsorption sites. The more adsorption sites were formed on Al modified HAP, which possessed abundant surface hydroxyl groups, resulting in higher efficiency of F − removal. Thermodynamic parameters such as ΔG°, ΔH° and ΔS° were calculated in order to understand the nature of adsorption process. The results revealed that the adsorption reaction was a spontaneous and endothermic process.

  10. Faraday's first dynamo: A retrospective

    Science.gov (United States)

    Smith, Glenn S.

    2013-12-01

    In the early 1830s, Michael Faraday performed his seminal experimental research on electromagnetic induction, in which he created the first electric dynamo—a machine for continuously converting rotational mechanical energy into electrical energy. His machine was a conducting disc, rotating between the poles of a permanent magnet, with the voltage/current obtained from brushes contacting the disc. In his first dynamo, the magnetic field was asymmetric with respect to the axis of the disc. This is to be contrasted with some of his later symmetric designs, which are the ones almost invariably discussed in textbooks on electromagnetism. In this paper, a theoretical analysis is developed for Faraday's first dynamo. From this analysis, the eddy currents in the disc and the open-circuit voltage for arbitrary positioning of the brushes are determined. The approximate analysis is verified by comparing theoretical results with measurements made on an experimental recreation of the dynamo. Quantitative results from the analysis are used to elucidate Faraday's qualitative observations, from which he learned so much about electromagnetic induction. For the asymmetric design, the eddy currents in the disc dissipate energy that makes the dynamo inefficient, prohibiting its use as a practical generator of electric power. Faraday's experiments with his first dynamo provided valuable insight into electromagnetic induction, and this insight was quickly used by others to design practical generators.

  11. Faraday's Law and Seawater Motion

    Science.gov (United States)

    De Luca, R.

    2010-01-01

    Using Faraday's law, one can illustrate how an electromotive force generator, directly utilizing seawater motion, works. The conceptual device proposed is rather simple in its components and can be built in any high school or college laboratory. The description of the way in which the device generates an electromotive force can be instructive not…

  12. Faraday Cage Protects Against Lightning

    Science.gov (United States)

    Jafferis, W.; Hasbrouck, R. T.; Johnson, J. P.

    1992-01-01

    Faraday cage protects electronic and electronically actuated equipment from lightning. Follows standard lightning-protection principles. Whether lightning strikes cage or cables running to equipment, current canceled or minimized in equipment and discharged into ground. Applicable to protection of scientific instruments, computers, radio transmitters and receivers, and power-switching equipment.

  13. Synchrotron Radiation and Faraday Rotation

    NARCIS (Netherlands)

    Heald, George

    2015-01-01

    Synchrotron radiation and its degree of linear polarization are powerful tracers of magnetic fields that are illuminated by cosmic ray electrons. Faraday rotation of the linearly polarized radiation is induced by intervening line-of-sight magnetic fields that are embedded in ionized plasmas. For

  14. A Mobile Phone Faraday Cage

    Science.gov (United States)

    French, M. M. J.

    2011-01-01

    A Faraday cage is an interesting physical phenomenon where an electromagnetic wave can be excluded from a volume of space by enclosure with an electrically conducting material. The practical application of this in the classroom is to block the signal to a mobile phone by enclosing it in a metal can. The background of the physics behind this is…

  15. Various Paths to Faraday's Law

    Science.gov (United States)

    Redzic, Dragan V.

    2008-01-01

    In a recent note, the author presented a derivation of Faraday's law of electromagnetic induction for a closed filamentary circuit C(t) which is moving at relativistic velocities and also changing its shape as it moves via the magnetic vector potential. Recently, Kholmetskii et al, while correcting an error in an equation, showed that it can be…

  16. Building a better Faraday cage

    Science.gov (United States)

    MartinAlfven; Wright, David; skocpol; Rounce, Graham; Richfield, Jon; W, Nick; wheelsonfire

    2015-11-01

    In reply to the physicsworld.com news article “Are Faraday cages less effective than previously thought?” (15 September, http://ow.ly/SfklO), about a study that indicated, based on mathematical modelling, that conducting wire-mesh cages may not be as good at excluding electromagnetic radiation as is commonly assumed.

  17. An enhanced Brinson model with modified kinetics for martensite transformation

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Young-Jin; Lee, Jung Ju [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of); Jeong, Ju-Won [Korea Aerospace Research Institute, Daejeon (Korea, Republic of); Lim, Jae Hyuk [Chonbuk National University, Jeonju (Korea, Republic of)

    2017-03-15

    We propose an enhanced Brinson model with modified kinetics for martensite transformation. Two additional material constants are considered to follow the stress-temperature diagram above austenite start temperature (As) along with treatment to keep the continuity of the martensite volume fraction and the path dependency of the phase transformation. To demonstrate the performance of the proposed model, we implement this algorithm into ABAQUS user subroutine, then conduct several numerical simulations and compare their results with SMA wire experiments as well as those of three-dimensional SMA constitutive models. From the results, it turns out that the proposed model is as accurate as the three-dimensional models and shows better accuracy over original Brinson model in terms of recovery stress.

  18. Electrical control of Faraday rotation at a liquid-liquid interface.

    Science.gov (United States)

    Marinescu, Monica; Kornyshev, Alexei A; Flatté, Michael E

    2015-01-01

    A theory is developed for the Faraday rotation of light from a monolayer of charged magnetic nanoparticles at an electrified liquid-liquid interface. The polarization fields of neighboring nanoparticles enhance the Faraday rotation. At such interfaces, and for realistic sizes and charges of nanoparticles, their adsorption-desorption can be controlled with a voltage variationFaraday rotation. A calculation based on the Maxwell-Garnett theory predicts that the corresponding redistribution of 40 nm nanoparticles of yttrium iron garnet can switch a cavity with a quality factor larger than 10(4) for light of wavelength 500 nm at normal incidence.

  19. Enhanced Stormwater Contaminant Removal Using Tree Filters And Modified Sorbents

    Science.gov (United States)

    Schifman, L. A.; Kasaraneni, V. K.; Boving, T. B.; Oyanedel-Craver, V.

    2012-12-01

    Stormwater runoff, particularly in urban areas, contains several groups of contaminants that negatively impact surface- and groundwater quality if left untreated. Contaminants in runoff are often addressed by structural best management practices (BMP) that capture and treat runoff before discharging it. Many BMPs, such as tree filters, act as primary filtration devices that attenuate total suspended solids, nutrients, and heavy metals from runoff; but typically these BMPs are not designed to treat bacteria and have only minor petroleum hydrocarbon (PH) treatment capabilities. To address this shortcoming, three materials (red cedar wood chips, expanded shale, and crushed concrete) were modified with either Quaternary Ammonium Silane (QAS) or Silver Nanoparticles (AgNPs) to provide antimicrobial properties to the matrix and/or exploit their affinity to sorb PH, particularly polycyclic aromatic hydrocarbons (PAH). Results show that of the three materials investigated, wood chips exhibit the highest sorption capacity for QAS, making this material favorable for treating bacteria, while at the same time attenuating PAHs by sorption processes. In case of AgNP amendments to wood, less uptake and more desorption from the wood matrix was observed. Relative to wood, expanded shale and crushed concrete exhibited less affinity for QAS (results for AgNPs are pending). Currently, batch isotherm and unsaturated flow column studies are under way to determine the performance of the amended materials with regard to removal of bacteria, nutrients, heavy metals, and PAH from artificially contaminated runoff. In this presentation, the contaminant removal efficiency of all modified and unmodified materials will be discussed on the background of how these materials may find use in enhanced treatment of stormwater in tree filter BMPs.

  20. Faraday anomalous dispersion optical filters

    Science.gov (United States)

    Shay, T. M.; Yin, B.; Alvarez, L. S.

    1993-01-01

    The effect of Faraday anomalous dispersion optical filters on infrared and blue transitions of some alkali atoms is calculated. A composite system is designed to further increase the background noise rejection. The measured results of the solar background rejection and image quality through the filter are presented. The results show that the filter may provide high transmission and high background noise rejection with excellent image quality.

  1. Reconfigurable antennas radiations using plasma Faraday cage

    OpenAIRE

    Barro , Oumar Alassane; Himdi , Mohamed; Lafond , Olivier

    2015-01-01

    International audience; This letter presents a new reconfigurable plasma antenna associated with a Faraday cage. The Faraday cage is realized using a fluorescent lamp. A patch antenna with a broadside radiation pattern or a monopole antenna with an end-fire radiation pattern , operating at 2.45 GHz, is placed inside Faraday cage. The performance of the reconfigurable system is observed in terms of input reflection coefficient, gain and radiation pattern via simulation and measurement. It is s...

  2. Incomplete Faraday cage effect of helicopters used in platform live-line maintenance

    Energy Technology Data Exchange (ETDEWEB)

    Cameron, G.W.; Bodger, P.S.; Woudberg, J.J. [University of Canterbury, Christchurch (New Zealand). Dept. of Electrical and Electronic Engineering

    1998-03-01

    The use of helicopters for maintenance on live overhead transmission lines has become a realistic option. The helicopter blades, body and working platform can be seen as creating an incomplete Faraday cage which may be an enhancement to live-line worker safety. This paper simulates the condition using a Faraday cage which can be dismantled in a controlled laboratory environment, to ascertain the effectiveness of apparatus. (author)

  3. Intracavity Faraday modulation spectroscopy (INFAMOS): A tool for radical detection

    Science.gov (United States)

    Gianella, Michele; Pinto, Tomas H. P.; Wu, Xia; Ritchie, Grant A. D.

    2017-08-01

    We present the intra-cavity Faraday modulation spectroscopy technique, whereby optical feedback cavity-enhanced spectroscopy is coupled with Faraday modulation spectroscopy to greatly enhance the interaction path length of a laser beam with a paramagnetic sample in a magnetic field. We describe a first prototype based upon a cw quantum cascade laser targeting a selection of fundamental rovibrational R-branch transitions of nitric oxide (1890 cm-1), consisting of a linear cavity (finesse F =6300 ) and a water-cooled solenoid. We demonstrate a minimum detectable Verdet constant of Vmin=4.7 ×10-14 rad cm-1 G-1 H z-1/2 (at SNR = 1), corresponding to a single-pass rotation angle of 1.6 ×10-10 rad Hz-1/2 and a limit of detection of 0.21 ppbv Hz-1/2 NO.

  4. Intracavity Faraday modulation spectroscopy (INFAMOS): A tool for radical detection.

    Science.gov (United States)

    Gianella, Michele; Pinto, Tomas H P; Wu, Xia; Ritchie, Grant A D

    2017-08-07

    We present the intra-cavity Faraday modulation spectroscopy technique, whereby optical feedback cavity-enhanced spectroscopy is coupled with Faraday modulation spectroscopy to greatly enhance the interaction path length of a laser beam with a paramagnetic sample in a magnetic field. We describe a first prototype based upon a cw quantum cascade laser targeting a selection of fundamental rovibrational R-branch transitions of nitric oxide (1890 cm -1 ), consisting of a linear cavity (finesse F=6300) and a water-cooled solenoid. We demonstrate a minimum detectable Verdet constant of V min =4.7×10 -14  rad cm -1  G -1  Hz -1/2 (at SNR = 1), corresponding to a single-pass rotation angle of 1.6×10 -10  rad Hz -1/2 and a limit of detection of 0.21 ppbv Hz -1/2 NO.

  5. Faraday rotation in jets of AGN: the case of 3C 120

    International Nuclear Information System (INIS)

    Gómez, José L; Roca-Sogorb, Mar; Agudo, Iván; Marscher, Alan P; Jorstad, Svetlana G

    2012-01-01

    The source of Faraday rotation in the jet of the radio galaxy 3C 120 is analyzed through Very Long Baseline Array observations carried out between 1999 and 2007 at 15, 22 and 43 GHz. Uncorrelated changes in the linear polarization of the underlying jet emission and the Faraday rotation screen indicate that the emitting jet and the source of Faraday rotation are not closely connected physically and have different configurations for the magnetic field and/or kinematical properties. Furthermore, the existence of a region of enhanced rotation measure whose properties remain constant over three years requires a localized source of Faraday rotation, favoring a model in which a significant fraction of the rotation measure originates in foreground clouds.

  6. Faraday screen sputtering on TPX

    International Nuclear Information System (INIS)

    Ehst, D.A.

    1994-12-01

    The TPX design stipulates that the ion-cyclotron resonance frequency (ICRF) antenna must have a Faraday screen (FS). The author considers here possible low Z coatings for the screen, as well as sputtering behavior of the Ni and Ti substrates. The theory of rf-induced sputtering has been developed, and he follows those theoretical approaches. The author's emphasis will be on both impurity generation as a possible source of increased Z eff , and also on actual erosion-lifetime of the materials under worst case conditions

  7. A Note on Faraday Paradoxes

    CERN Document Server

    Auchmann, Bernhard; Russenschuck, Stephan

    2014-01-01

    The validity of the flux rule to determine the electromotive force in a cycle, epsilon = -d Phi/dt, has been the subject of a large amount of controversy since the beginning of electrical technology. Although most authors reach correct conclusions for a class of problems called Faraday paradoxes, the arguments that are used vary and often rely on ad-hoc physical reasoning. A didactic and insightful treatment should be based solely on Maxwell's equations, the constitutive laws, and a detailed study of the mathematics involved.

  8. Gyromagnetic Faraday effect in transparent magnetic crystals

    International Nuclear Information System (INIS)

    Krinchik, G.S.; Koptsik, S.V.; Gan'shina, E.A.

    1982-01-01

    Faraday effect in the transparent paramagnetic Gd 3 Ga 5 O 12 at 4.2 K in magnetic fields up to 50 kE within 1-2.5 μm range is studied. The gyromagnetic Faraday effect caused by precession of magnetization vector under the effect of the magnetic field of wave light is shown to be the determinimg one in the infrared range. Hyromagnetic and gyroelectric contributions to Faraday effect in Gd 3 Fe 5 O 12 and Y 3 Fe 5 O 12 are determined. It is shown that field dependence of Faraday effect in non-colinear ferrimagnetic Yb 3 Fe 5 O 12 qualitatively proves the existence of gyromagnetic Faraday effect

  9. Faraday instability in deformable domains

    International Nuclear Information System (INIS)

    Pucci, G.

    2013-01-01

    Hydrodynamical instabilities are usually studied either in bounded regions or free to grow in space. In this article we review the experimental results of an intermediate situation, in which an instability develops in deformable domains. The Faraday instability, which consists in the formation of surface waves on a liquid experiencing a vertical forcing, is triggered in floating liquid lenses playing the role of deformable domains. Faraday waves deform the lenses from the initial circular shape and the mutual adaptation of instability patterns with the lens boundary is observed. Two archetypes of behaviour have been found. In the first archetype a stable elongated shape is reached, the wave vector being parallel to the direction of elongation. In the second archetype the waves exceed the response of the lens border and no equilibrium shape is reached. The lens stretches and eventually breaks into fragments that have a complex dynamics. The difference between the two archetypes is explained by the competition between the radiation pressure the waves exert on the lens border and its response due to surface tension.

  10. Modified silica sol coatings for surface enhancement of leather.

    Science.gov (United States)

    Mahltig, Boris; Vossebein, Lutz; Ehrmann, Andrea; Cheval, Nicolas; Fahmi, Amir

    2012-06-01

    The presented study reports on differently modified silica sols for coating applications on leather. Silica sols are prepared by acidic hydrolysis of tetraethoxysilane and modified by silane compounds with fluorinated and non-fluorinated alkylgroups. In contrast to many earlier investigations regarding sol-gel applications on leather, no acrylic resin is used together with the silica sols when applying on leather. The modified silica particles are supposed to aggregate after application, forming thus a modified silica coating on the leather substrate. Scanning electron microscopy investigation shows that the applied silica coatings do not fill up or close the pores of the leather substrate. However, even if the pores of the leather are not sealed by this sol-gel coating, an improvement of the water repellent and oil repellent properties of the leather substrates are observed. These improved properties of leather by application of modified silica sols can provide the opportunity to develop sol-gel products for leather materials present in daily life.

  11. Linear theory on temporal instability of megahertz faraday waves for monodisperse microdroplet ejection.

    Science.gov (United States)

    Tsai, Shirley C; Tsai, Chen S

    2013-08-01

    A linear theory on temporal instability of megahertz Faraday waves for monodisperse microdroplet ejection based on mass conservation and linearized Navier-Stokes equations is presented using the most recently observed micrometer- sized droplet ejection from a millimeter-sized spherical water ball as a specific example. The theory is verified in the experiments utilizing silicon-based multiple-Fourier horn ultrasonic nozzles at megahertz frequency to facilitate temporal instability of the Faraday waves. Specifically, the linear theory not only correctly predicted the Faraday wave frequency and onset threshold of Faraday instability, the effect of viscosity, the dynamics of droplet ejection, but also established the first theoretical formula for the size of the ejected droplets, namely, the droplet diameter equals four-tenths of the Faraday wavelength involved. The high rate of increase in Faraday wave amplitude at megahertz drive frequency subsequent to onset threshold, together with enhanced excitation displacement on the nozzle end face, facilitated by the megahertz multiple Fourier horns in resonance, led to high-rate ejection of micrometer- sized monodisperse droplets (>10(7) droplets/s) at low electrical drive power (<;1 W) with short initiation time (<;0.05 s). This is in stark contrast to the Rayleigh-Plateau instability of a liquid jet, which ejects one droplet at a time. The measured diameters of the droplets ranging from 2.2 to 4.6 μm at 2 to 1 MHz drive frequency fall within the optimum particle size range for pulmonary drug delivery.

  12. Construction of the Faraday Cup based on fluorescent screen as an electron beam sensor

    International Nuclear Information System (INIS)

    Sutadi; Rany Saptaaji; Suhartono; Sukaryono

    2016-01-01

    The Faraday Cup based on fluorescent screen as an electron beam profile sensor at electron accelerator has been conducted. In the principle, the electron beam which obtained from the electron source and accelerated in the accelerator tube will obtain the light which can be observed visually when it interact with fluorescent material (phosphorescent). This Faraday Cup for electron beam sensor was made from the modified TV tube. The main component of this Faraday Cup construction includes: 17 inch TV tube, SS reducer flange and the vacuum adhesive. There are two kind of test has been conducted, that is the vacuum level test and the electron beam sensor test. The vacuum level test was conducted by measuring the final vacuum level that can be reach, while the electron beam sensor test was conducted by monitoring of the electron beam profile that was trapped by Faraday Cup visually. The test result shows that TV tube can be modified as the Faraday Cup to sensor electron beam in the electron accelerator. (author)

  13. Faraday diamagnetism under slowly oscillating magnetic fields

    Science.gov (United States)

    Kimura, Tsunehisa; Kimura, Fumiko; Kimura, Yosuke

    2018-04-01

    Diamagnetism is a universal phenomenon of materials arising from the orbital motion of electrons bound to atoms, which is commonly known as Langevin diamagnetism. The orbital motion also occurs according to the Faraday's law of induction when the applied magnetic field is oscillating. However, the influence of this dynamic effect on the magnetism of materials has seldom been studied. Here, we propose a new type diamagnetism coined Faraday diamagnetism. The magnitude of this diamagnetism evaluated by an atomic electric circuit model was as large as that of Langevin diamagnetism. The predicted scale of Faraday diamagnetism was supported by experiments.

  14. Faraday wave lattice as an elastic metamaterial.

    Science.gov (United States)

    Domino, L; Tarpin, M; Patinet, S; Eddi, A

    2016-05-01

    Metamaterials enable the emergence of novel physical properties due to the existence of an underlying subwavelength structure. Here, we use the Faraday instability to shape the fluid-air interface with a regular pattern. This pattern undergoes an oscillating secondary instability and exhibits spontaneous vibrations that are analogous to transverse elastic waves. By locally forcing these waves, we fully characterize their dispersion relation and show that a Faraday pattern presents an effective shear elasticity. We propose a physical mechanism combining surface tension with the Faraday structured interface that quantitatively predicts the elastic wave phase speed, revealing that the liquid interface behaves as an elastic metamaterial.

  15. ICRF antenna Faraday shield plasma sheath model

    International Nuclear Information System (INIS)

    Whealton, J.H.; Ryan, P.M.; Raridon, R.J.

    1990-01-01

    A two-dimensional nonlinear formulation that explicitly considers the plasma edge near a Faraday shield in a self-consistent manner is used in the modeling of the ion motion for a Faraday shield concept and model suggested by Perkins. Two models are considered that may provide significant insight into the generation of impurities for ion cyclotron resonance heating (ICRH) antennas. In one of these models a significant sheath periodically forms next to the Faraday screen, with ion acoustic waves heating the ions in the plasma. (orig.)

  16. Theory of nanotube faraday cage

    Science.gov (United States)

    Roxana Margine, Elena; Nisoli, Cristiano; Kolmogorov, Aleksey; Crespi, Vincent H.

    2003-03-01

    Charge transfer between dopants and double-wall carbon nanotubes is examined theoretically. We model the system as a triple cylindrical capacitor with the dopants forming a shell around the outer wall of the nanotube. The total energy of the system contains three terms: the band structure energies of the inner and outer tube, calculated in a tight-binding model with rigid bands, and the electrostatic energy of the tri-layer distribution. Even for metallic inner and outer tube walls, wherein the diameter dependence of the bandgap does not favor the outer wall, nearly all of the dopant charge resides on the outer layer, a nanometer-scale Faraday cage. The calculated charge distribution is in agreement with recent experimental measurements.

  17. Porous surface modified bioactive bone cement for enhanced bone bonding.

    Directory of Open Access Journals (Sweden)

    Qiang He

    Full Text Available Polymethylmethacrylate bone cement cannot provide an adhesive chemical bonding to form a stable cement-bone interface. Bioactive bone cements show bone bonding ability, but their clinical application is limited because bone resorption is observed after implantation. Porous polymethylmethacrylate can be achieved with the addition of carboxymethylcellulose, alginate and gelatin microparticles to promote bone ingrowth, but the mechanical properties are too low to be used in orthopedic applications. Bone ingrowth into cement could decrease the possibility of bone resorption and promote the formation of a stable interface. However, scarce literature is reported on bioactive bone cements that allow bone ingrowth. In this paper, we reported a porous surface modified bioactive bone cement with desired mechanical properties, which could allow for bone ingrowth.The porous surface modified bioactive bone cement was evaluated to determine its handling characteristics, mechanical properties and behavior in a simulated body fluid. The in vitro cellular responses of the samples were also investigated in terms of cell attachment, proliferation, and osteoblastic differentiation. Furthermore, bone ingrowth was examined in a rabbit femoral condyle defect model by using micro-CT imaging and histological analysis. The strength of the implant-bone interface was also investigated by push-out tests.The modified bone cement with a low content of bioactive fillers resulted in proper handling characteristics and adequate mechanical properties, but slightly affected its bioactivity. Moreover, the degree of attachment, proliferation and osteogenic differentiation of preosteoblast cells was also increased. The results of the push-out test revealed that higher interfacial bonding strength was achieved with the modified bone cement because of the formation of the apatite layer and the osseointegration after implantation in the bony defect.Our findings suggested a new bioactive

  18. Faraday Rotation Measurement with the SMAP Radiometer

    Science.gov (United States)

    Le Vine, D. M.; Abraham, S.

    2016-01-01

    Faraday rotation is an issue that needs to be taken into account in remote sensing of parameters such as soil moisture and ocean salinity at L-band. This is especially important for SMAP because Faraday rotation varies with azimuth around the conical scan. SMAP retrieves Faraday rotation in situ using the ratio of the third and second Stokes parameters, a procedure that was demonstrated successfully by Aquarius. This manuscript reports the performance of this algorithm on SMAP. Over ocean the process works reasonably well and results compare favorably with expected values. But over land, the inhomogeneous nature of the scene results in much noisier, and in some cases unreliable estimates of Faraday rotation.

  19. The Faraday rotation experiment. [solar corona

    Science.gov (United States)

    Volland, H.; Levy, G. S.; Bird, M. K.; Stelzried, C. T.; Seidel, B. L.

    1984-01-01

    The magnetized plasma of the solar corona was remotely sounded using the Faraday rotation effect. The solar magnetic field together with the electrons of the coronal plasma cause a measurable Faraday rotation effect, since the radio waves of Helios are linearly polarized. The measurement is performed at the ground stations. Alfven waves traveling from the Sun's surface through the corona into interplanetary space are observed. Helios 2 signals penetrating through a region where coronal mass is ejected show wavelike structures.

  20. Heating profiles on ICRF antenna Faraday shields

    International Nuclear Information System (INIS)

    Taylor, D.J.; Baity, F.W.; Hahs, C.L. Riemer, B.W.; Ryan, D.M.; Williamson, D.E.

    1992-01-01

    Poor definition of the heating profiles that occur during normal operation of Faraday shields for ion cyclotron resonant frequency (ICRF) antennas has complicated the mechanical design of ICRF system components. This paper reports that at Oak Ridge National Laboratory (ORNL), Faraday shield analysis is being used in defining rf heating profiles. In recent numerical analyses of proposed hardware for the Burning Plasma Experiment (BPX) and DIII-D, rf magnetic fields at Faraday shield surfaces were calculated, providing realistic predictions of the induced skin currents flowing on the shield elements and the resulting dissipated power profile. Detailed measurements on mock-ups of the Faraday shields for DIII-D and the Tokamak Fusion Test Reactor (TFTR) confirmed the predicted magnetic field distributions. A conceptual design for an uncooled Faraday shield for the BPX ion cyclotron resonance heating (ICRH) antenna, which should withstand the proposed long-pulse operation, has been completed. The analytical effort is described in detail, with emphasis on the design work for the BPX ICRH antenna conceptual design and for the replacement Faraday shield for the DIII-D FWCD antenna. Results of analyses are shown, and configuration issues involved in component modeling are discussed

  1. Innovative technologies for Faraday shield cooling

    International Nuclear Information System (INIS)

    Rosenfeld, J.H.; Lindemuth, J.E.; North, M.T.; Goulding, R.H.

    1995-01-01

    Alternative advanced technologies are being evaluated for use in cooling the Faraday shields used for protection of ion cyclotron range of frequencies (ICR) antennae in Tokamaks. Two approaches currently under evaluation include heat pipe cooling and gas cooling. A Monel/water heat pipe cooled Faraday shield has been successfully demonstrated. Heat pipe cooling offers the advantage of reducing the amount of water discharged into the Tokamak in the event of a tube weld failure. The device was recently tested on an antenna at Oak Ridge National Laboratory. The heat pipe design uses inclined water heat pipes with warm water condensers located outside of the plasma chamber. This approach can passively remove absorbed heat fluxes in excess of 200 W/cm 2 ;. Helium-cooled Faraday shields are also being evaluated. This approach offers the advantage of no liquid discharge into the Tokamak in the event of a tube failure. Innovative internal cooling structures based on porous metal cooling are being used to develop a helium-cooled Faraday shield structure. This approach can dissipate the high heat fluxes typical of Faraday shield applications while minimizing the required helium blower power. Preliminary analysis shows that nominal helium flow and pressure drop can sufficiently cool a Faraday shield in typical applications. Plans are in progress to fabricate and test prototype hardware based on this approach

  2. Speech Enhancement by Modified Convex Combination of Fractional Adaptive Filtering

    Directory of Open Access Journals (Sweden)

    M. Geravanchizadeh

    2014-12-01

    Full Text Available This paper presents new adaptive filtering techniques used in speech enhancement system. Adaptive filtering schemes are subjected to different trade-offs regarding their steady-state misadjustment, speed of convergence, and tracking performance. Fractional Least-Mean-Square (FLMS is a new adaptive algorithm which has better performance than the conventional LMS algorithm. Normalization of LMS leads to better performance of adaptive filter. Furthermore, convex combination of two adaptive filters improves its performance. In this paper, new convex combinational adaptive filtering methods in the framework of speech enhancement system are proposed. The proposed methods utilize the idea of normalization and fractional derivative, both in the design of different convex mixing strategies and their related component filters. To assess our proposed methods, simulation results of different LMS-based algorithms based on their convergence behavior (i.e., MSE plots and different objective and subjective criteria are compared. The objective and subjective evaluations include examining the results of SNR improvement, PESQ test, and listening tests for dual-channel speech enhancement. The powerful aspects of proposed methods are their low complexity, as expected with all LMS-based methods, along with a high convergence rate.

  3. Enhanced linear-array photoacoustic beamforming using modified coherence factor.

    Science.gov (United States)

    Mozaffarzadeh, Moein; Yan, Yan; Mehrmohammadi, Mohammad; Makkiabadi, Bahador

    2018-02-01

    Photoacoustic imaging (PAI) is a promising medical imaging modality providing the spatial resolution of ultrasound imaging and the contrast of optical imaging. For linear-array PAI, a beamformer can be used as the reconstruction algorithm. Delay-and-sum (DAS) is the most prevalent beamforming algorithm in PAI. However, using DAS beamformer leads to low-resolution images as well as high sidelobes due to nondesired contribution of off-axis signals. Coherence factor (CF) is a weighting method in which each pixel of the reconstructed image is weighted, based on the spatial spectrum of the aperture, to mainly improve the contrast. We demonstrate that the numerator of the formula of CF contains a DAS algebra and propose the use of a delay-multiply-and-sum beamformer instead of the available DAS on the numerator. The proposed weighting technique, modified CF (MCF), has been evaluated numerically and experimentally compared to CF. It was shown that MCF leads to lower sidelobes and better detectable targets. The quantitative results of the experiment (using wire targets) show that MCF leads to for about 45% and 40% improvement, in comparison with CF, in the terms of signal-to-noise ratio and full-width-half-maximum, respectively. (2018) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE).

  4. Enhanced linear-array photoacoustic beamforming using modified coherence factor

    Science.gov (United States)

    Mozaffarzadeh, Moein; Yan, Yan; Mehrmohammadi, Mohammad; Makkiabadi, Bahador

    2018-02-01

    Photoacoustic imaging (PAI) is a promising medical imaging modality providing the spatial resolution of ultrasound imaging and the contrast of optical imaging. For linear-array PAI, a beamformer can be used as the reconstruction algorithm. Delay-and-sum (DAS) is the most prevalent beamforming algorithm in PAI. However, using DAS beamformer leads to low-resolution images as well as high sidelobes due to nondesired contribution of off-axis signals. Coherence factor (CF) is a weighting method in which each pixel of the reconstructed image is weighted, based on the spatial spectrum of the aperture, to mainly improve the contrast. We demonstrate that the numerator of the formula of CF contains a DAS algebra and propose the use of a delay-multiply-and-sum beamformer instead of the available DAS on the numerator. The proposed weighting technique, modified CF (MCF), has been evaluated numerically and experimentally compared to CF. It was shown that MCF leads to lower sidelobes and better detectable targets. The quantitative results of the experiment (using wire targets) show that MCF leads to for about 45% and 40% improvement, in comparison with CF, in the terms of signal-to-noise ratio and full-width-half-maximum, respectively.

  5. Nanowire modified carbon fibers for enhanced electrical energy storage

    Science.gov (United States)

    Shuvo, Mohammad Arif Ishtiaque; (Bill) Tseng, Tzu-Liang; Ashiqur Rahaman Khan, Md.; Karim, Hasanul; Morton, Philip; Delfin, Diego; Lin, Yirong

    2013-09-01

    The study of electrochemical super-capacitors has become one of the most attractive topics in both academia and industry as energy storage devices because of their high power density, long life cycles, and high charge/discharge efficiency. Recently, there has been increasing interest in the development of multifunctional structural energy storage devices such as structural super-capacitors for applications in aerospace, automobiles, and portable electronics. These multifunctional structural super-capacitors provide structures combining energy storage and load bearing functionalities, leading to material systems with reduced volume and/or weight. Due to their superior materials properties, carbon fiber composites have been widely used in structural applications for aerospace and automotive industries. Besides, carbon fiber has good electrical conductivity which will provide lower equivalent series resistance; therefore, it can be an excellent candidate for structural energy storage applications. Hence, this paper is focused on performing a pilot study for using nanowire/carbon fiber hybrids as building materials for structural energy storage materials; aiming at enhancing the charge/discharge rate and energy density. This hybrid material combines the high specific surface area of carbon fiber and pseudo-capacitive effect of metal oxide nanowires, which were grown hydrothermally in an aligned fashion on carbon fibers. The aligned nanowire array could provide a higher specific surface area that leads to high electrode-electrolyte contact area thus fast ion diffusion rates. Scanning Electron Microscopy and X-Ray Diffraction measurements are used for the initial characterization of this nanowire/carbon fiber hybrid material system. Electrochemical testing is performed using a potentio-galvanostat. The results show that gold sputtered nanowire carbon fiber hybrid provides 65.9% higher energy density than bare carbon fiber cloth as super-capacitor.

  6. Temperature dependence of the Faraday rotation for CdMnCoTe films

    International Nuclear Information System (INIS)

    Ahn, J. Y.; Tanaka, M.; Imamura, M.

    2001-01-01

    The temperature dependence of magneto-optical property in the visible wavelength region has been studied on four-element semimagnetic semiconductor CdMnCoTe films deposited on quartz glass substrates by using MBE equipment. A large dispersion of Faraday rotation was observed, and the peak of the Faraday rotation was shifted to the higher photon energies with increasing Mn concentration at low temperatures. At 180 K, the value of the Faraday rotation observed for the Cd 0.647 Mn 0.34 Co 0.013 Te film on quartz glass was -0.36 deg/cmG at 630 nm. It is equivalent to the value of -0.36 deg/cmG observed at 77 K for the Cd 0.52 Mn 0.48 Te film on quartz glass. At 77 K, the Faraday rotation observed for the Cd 0.647 Mn 0.34 Co 0.013 Te film on quartz glass was -0.49 deg/cmG at 610 nm. The value is approximately two times larger than that of the Cd 0.52 Mn 0.48 Te film deposited on the same quartz glass substrate. The origin of the enhancement of Faraday rotation in CdMnCoTe films has been discussed in terms of the magnetic susceptibility χ. [copyright] 2001 American Institute of Physics

  7. The gravitational analog of Faraday's induction law

    Science.gov (United States)

    Zile, Daniel; Overduin, James

    2015-04-01

    Michael Faraday, the discoverer of electromagnetic induction, was convinced that there must also be a gravitational analog of this law, and he carried out drop-tower experiments in 1849 to look for the electric current induced in a coil by changes in gravitational flux through the coil. This work, now little remembered, was in some ways the first investigation of what we would now call a unified-field theory. We revisit Faraday's experiments in the light of current knowledge and ask what might be learned if they were to be performed today. We then review the gravitational analog for Faraday's law that arises within the vector (or gravito-electromagnetic) approximation to Einstein's theory of general relativity in the weak-field, low-velocity limit. This law relates spinning masses and induced ``mass currents'' rather than spinning charges and electric currents, but is otherwise remarkably similar to its electromagnetic counterpart. The predicted effects are completely unobservable in everyday settings like those envisioned by Faraday, but are thought to be relevant in astrophysical contexts like the accretion disks around collapsed stars, thus bearing out Faraday's remarkable intuition. Undergraduate student.

  8. Tensor B mode and stochastic Faraday mixing

    CERN Document Server

    Giovannini, Massimo

    2014-01-01

    This paper investigates the Faraday effect as a different source of B mode polarization. The E mode polarization is Faraday rotated provided a stochastic large-scale magnetic field is present prior to photon decoupling. In the first part of the paper we discuss the case where the tensor modes of the geometry are absent and we argue that the B mode recently detected by the Bicep2 collaboration cannot be explained by a large-scale magnetic field rotating, through the Faraday effect, the well established E mode polarization. In this case, the observed temperature autocorrelations would be excessively distorted by the magnetic field. In the second part of the paper the formation of Faraday rotation is treated as a stationary, random and Markovian process with the aim of generalizing a set of scaling laws originally derived in the absence of the tensor modes of the geometry. We show that the scalar, vector and tensor modes of the brightness perturbations can all be Faraday rotated even if the vector and tensor par...

  9. Faraday rotation measurement method and apparatus

    Science.gov (United States)

    Brockman, M. H. (Inventor)

    1981-01-01

    A method and device for measuring Faraday rotation of a received RF signal is described. A simultaneous orthogonal polarization receiver compensates for a 3 db loss due to splitting of a received signal into left circular and right circular polarization channels. The compensation is achieved by RF and modulation arraying utilizing a specific receiver array which also detects and measures Faraday rotation in the presence or absence of spin stabilization effects on a linear polarization vector. Either up-link or down-link measurement of Faraday rotation is possible. Specifically, the Faraday measurement apparatus utilized in conjunction with the specific receiver array provides a means for comparing the phase of a reference signal in the receiver array to the phase of a tracking loop signal related to the incoming signal, and comparing the phase of the reference signal to the phase of the tracking signal shifted in phase by 90 degrees. The averaged and unaveraged signals, are compared, the phase changes between the two signals being related to Faraday rotation.

  10. Soft X-Ray Magneto-optical Faraday Effect around Ni M2,3 Edges

    International Nuclear Information System (INIS)

    Kai, Chen; Ming-Qi, Cui; Fen, Yan; Li-Juan, Sun; Lei, Zheng; Chen-Yan, Ma; Shi-Bo, Xi; Yi-Dong, Zhao; Jia, Zhao

    2008-01-01

    We present magneto-optical (MO) Faraday spectra measured around the M 2,3 edges (60–70eV) of Ni films at the Beijing Synchrotron Radiation Facility (BSRF). A polarization analysis of the final state of the transmitted radiation from the Ni film is employed to determine the Faraday rotation at the edges. The MO effect becomes resonantly enhanced at the M 2,3 edges, and accordingly large values for the rotation angle β of 1.85 ± 0.19° for this ferromagnetic Ni film with thickness of 31 nm are measured. Without the magnetic field, the azimuthal angles do not shift; with parallel and antiparallel magnetic field the rotation angles shift in the opposite way and they are symmetrical. The uncertainty of Faraday rotation angles mainly comes from the data fitting and the state change of the beamline when the angles are measured

  11. Faraday polarization fluctuations of satellite beacon signals

    Science.gov (United States)

    Lee, M. C.; Klobuchar, J. A.

    1988-01-01

    The anisotropic effects of random density irregularities in causing Faraday polarization fluctuations of VHF radio signals are examined, taking both rod-like and sheet-like irregularities into consideration. It is found that the variance of Faraday polarization fluctuations depends on the ratio of perpendicular to parallel correlation lengths. The anisotropic effect of rod-like ionospheric irregularities are shown to be most appreciable for longitudinal propagation. The anisotropic effect of sheet-like ionospheric irregularities, however, is not strongly dependent on the radio propagation angle. During transionospheric propagation at large angles with respect to the geomagnetic field, sheet-like irregularities may cause greater Faraday polarization fluctuations than rod-like irregularities.

  12. Mode-locking via dissipative Faraday instability.

    Science.gov (United States)

    Tarasov, Nikita; Perego, Auro M; Churkin, Dmitry V; Staliunas, Kestutis; Turitsyn, Sergei K

    2016-08-09

    Emergence of coherent structures and patterns at the nonlinear stage of modulation instability of a uniform state is an inherent feature of many biological, physical and engineering systems. There are several well-studied classical modulation instabilities, such as Benjamin-Feir, Turing and Faraday instability, which play a critical role in the self-organization of energy and matter in non-equilibrium physical, chemical and biological systems. Here we experimentally demonstrate the dissipative Faraday instability induced by spatially periodic zig-zag modulation of a dissipative parameter of the system-spectrally dependent losses-achieving generation of temporal patterns and high-harmonic mode-locking in a fibre laser. We demonstrate features of this instability that distinguish it from both the Benjamin-Feir and the purely dispersive Faraday instability. Our results open the possibilities for new designs of mode-locked lasers and can be extended to other fields of physics and engineering.

  13. Faraday waves under time-reversed excitation.

    Science.gov (United States)

    Pietschmann, Dirk; Stannarius, Ralf; Wagner, Christian; John, Thomas

    2013-03-01

    Do parametrically driven systems distinguish periodic excitations that are time mirrors of each other? Faraday waves in a Newtonian fluid are studied under excitation with superimposed harmonic wave forms. We demonstrate that the threshold parameters for the stability of the ground state are insensitive to a time inversion of the driving function. This is a peculiarity of some dynamic systems. The Faraday system shares this property with standard electroconvection in nematic liquid crystals [J. Heuer et al., Phys. Rev. E 78, 036218 (2008)]. In general, time inversion of the excitation affects the asymptotic stability of a parametrically driven system, even when it is described by linear ordinary differential equations. Obviously, the observed symmetry has to be attributed to the particular structure of the underlying differential equation system. The pattern selection of the Faraday waves above threshold, on the other hand, discriminates between time-mirrored excitation functions.

  14. Faraday scaling and the Bicep2 observations

    CERN Document Server

    Giovannini, Massimo

    2014-01-01

    As repeatedly speculated in the past, the linear polarization of the Cosmic Microwave Background can be rotated via the Faraday effect. An economic explanation of the recent Bicep2 observations, not relying on long-wavelength tensor modes of the geometry, would stipulate that the detected B mode comes exclusively from a Faraday rotated E mode polarization. We show hereunder that this interpretation is ruled out by the existing upper limits on the B mode polarization obtained by independent experiments at observational frequencies much lower than the operating frequency of the Bicep2 experiment. We then derive the fraction of the observed B mode polarization ascribable to the Faraday effect and suggest a dedicated experimental strategy for its detection.

  15. Heating profiles on ICRF antenna Faraday shields

    International Nuclear Information System (INIS)

    Taylor, D.J.; Baity, F.W.; Hahs, C.L.; Riemer, B.W.; Ryan, P.M.; Williamson, D.E.

    1991-01-01

    A conceptual design for an uncooled Faraday shield for the BPX ion cyclotron resonance heating (ICRH) antenna, which should withstand the proposed long-pulse operation, has been completed. A high-heat-flux, uncooled Faraday shield has also been designed for the fast-wave current drive (FWCD) antenna on D3-D. For both components, the improved understanding of the heating profiles made it possible to design for heat fluxes that would otherwise have been too close to mechanically established limits. The analytical effort is described in detail, with emphasis on the design work for the BPX ICRH antenna conceptual design and for the replacement Faraday shield for the D3-D FWCD antenna. Results of analyses are shown, and configuration issues involved in component modeling are discussed. 3 refs., 6 figs., 2 tabs

  16. The hyperfine Paschen–Back Faraday effect

    International Nuclear Information System (INIS)

    Zentile, Mark A; Andrews, Rebecca; Weller, Lee; Adams, Charles S; Hughes, Ifan G; Knappe, Svenja

    2014-01-01

    We investigate experimentally and theoretically the Faraday effect in an atomic medium in the hyperfine Paschen–Back regime, where the Zeeman interaction is larger than the hyperfine splitting. We use a small permanent magnet and a micro-fabricated vapour cell, giving magnetic fields of the order of a tesla. We show that for low absorption and small rotation angles, the refractive index is well approximated by the Faraday rotation signal, giving a simple way to measure the atomic refractive index. Fitting to the atomic spectra, we achieve magnetic field sensitivity at the 10 −4 level. Finally we note that the Faraday signal shows zero crossings which can be used as temperature insensitive error signals for laser frequency stabilization at large detuning. The theoretical sensitivity for 87 Rb is found to be ∼40 kHz °C −1 . (paper)

  17. Rapid determination of Faraday rotation in optical glasses by means of secondary Faraday modulator.

    Science.gov (United States)

    Sofronie, M; Elisa, M; Sava, B A; Boroica, L; Valeanu, M; Kuncser, V

    2015-05-01

    A rapid high sensitive method for determining the Faraday rotation of optical glasses is proposed. Starting from an experimental setup based on a Faraday rod coupled to a lock-in amplifier in the detection chain, two methodologies were developed for providing reliable results on samples presenting low and large Faraday rotations. The proposed methodologies were critically discussed and compared, via results obtained in transmission geometry, on a new series of aluminophosphate glasses with or without rare-earth doping ions. An example on how the method can be used for a rapid examination of the optical homogeneity of the sample with respect to magneto-optical effects is also provided.

  18. Faraday effect in hollow quantum cylinder of finite thickness

    International Nuclear Information System (INIS)

    Ismailov, T.G.; Jabrailova, G.G.

    2009-01-01

    The interband Faraday rotation in hollow quantum cylinder of finite thickness is theoretically investigated. Faraday rotation in the dependence on incident light energy for different values of cylinder thickness. It is seen that the resonance peaks appear on Faraday rotation curve. The roles of selection are obtained

  19. Enhancement of turbulent flow heat transfer in a tube with modified twisted tapes

    Energy Technology Data Exchange (ETDEWEB)

    Lei, Y.G.; Zhao, C.H.; Song, C.F. [College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan (China)

    2012-12-15

    Numerical simulations were performed to study the fluid flow and heat transfer in a tube with staggered twisted tapes with central holes. In the range of Reynolds numbers between 6000 and 28 000, the modified twisted tapes increased the Nusselt number by 76.2 {proportional_to} 149.7 % and the friction factor by 380.2 {proportional_to} 443.8 % compared to the smooth tube. Compared to the typical twisted tapes, the modified twisted tapes produced an acceleration flow through the triangle regions leading to the enhancement of heat transfer, and the holes in the modified tapes reduced the severe pressure loss. It was found that the modified twisted tapes decreased the friction factor by 8.0 {proportional_to} 16.1 % and enhanced the heat transfer by 34.1 {proportional_to} 46.8 % in comparison with the typical tapes. These results indicated that the performance ratio values of the tube with modified twisted tapes were higher than 1.0 in the range of Reynolds numbers studied. The computed performance ratios of the tube with modified twisted tapes were much higher than those of the tube with typical twisted tapes. This means that the integrated performance of the tube with staggered twisted tapes with central holes is superior to that of the tube with typical twisted tapes. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  20. Exotic species and genetically modified organisms in aquaculture and enhanced fisheries: ICLARM's position

    OpenAIRE

    Pullin, R.S.V.

    1994-01-01

    This article contains a discussion paper on the use of exotic species and genetically modified organisms in aquaculture and enhanced fisheries, together with a summary of ICLARM's (International Center for Living Aquatic Resources Management, Philippines) current position on this important topic.

  1. The Faraday effect revisited: General theory

    DEFF Research Database (Denmark)

    Cornean, Horia Decebal; Nenciu, Gheorghe; Pedersen, Thomas Garm

    2006-01-01

    This paper is the first in a series revisiting the Faraday effect, or more generally, the theory of electronic quantum transport/optical response in bulk media in the presence of a constant magnetic field. The independent electron approximation is assumed. At zero temperature and zero frequency...

  2. Faraday Rotation and L Band Oceanographic Measurements

    DEFF Research Database (Denmark)

    Skou, Niels

    2003-01-01

    Spaceborne radiometric measurements of the L band brightness temperature over the oceans make it possible to estimate sea surface salinity. However, Faraday rotation in the ionosphere disturbs the signals and must be corrected. Two different ways of assessing the disturbance directly from...

  3. ionFR: Ionospheric Faraday rotation [Dataset

    NARCIS (Netherlands)

    Sotomayor-Beltran, C.; et al., [Unknown; Hessels, J.W.T.; van Leeuwen, J.; Markoff, S.; Wijers, R.A.M.J.

    2013-01-01

    IonFR calculates the amount of ionospheric Faraday rotation for a specific epoch, geographic location, and line-of-sight. The code uses a number of publicly available, GPS-derived total electron content maps and the most recent release of the International Geomagnetic Reference Field. ionFR can be

  4. The Minus Sign in Faraday's Law Revisited

    Science.gov (United States)

    O'Sullivan, Colm; Hurley, Donal

    2013-01-01

    By introducing the mathematical concept of orientation, the significance of the minus sign in Faraday's law may be made clear to students with some knowledge of vector calculus. For many students, however, the traditional approach of treating the law as a relationship between positive scalars and of relying on Lenz's law to provide the information…

  5. Fast Faraday Cup With High Bandwidth

    Science.gov (United States)

    Deibele, Craig E [Knoxville, TN

    2006-03-14

    A circuit card stripline Fast Faraday cup quantitatively measures the picosecond time structure of a charged particle beam. The stripline configuration maintains signal integrity, and stitching of the stripline increases the bandwidth. A calibration procedure ensures the measurement of the absolute charge and time structure of the charged particle beam.

  6. The Faraday effect revisited: General theory

    DEFF Research Database (Denmark)

    Cornean, Horia Decebal; Nenciu, Gheorghe; Pedersen, Thomas Garm

    This paper is the first in a series revisiting the Faraday effect, or more generally, the theory of electronic quantum transport/optical response in bulk media in the presence of a constant magnetic field. The independent electron approximation is assumed. For free electrons, the transverse...

  7. Nonlinear pattern formation of Faraday waves

    NARCIS (Netherlands)

    Binks, D.J.; Water, van de W.

    1997-01-01

    A cascade of surface wave patterns with increasing rotational symmetry ranging from simple square to tenfold quasiperiodic is observed for Faraday waves. The experiment concerns the excitation of subharmonic standing surface waves by oscillating vertical acceleration. Our observation agrees with the

  8. Nonlinear Faraday rotation in samarium vapor

    International Nuclear Information System (INIS)

    Barkov, L.M.; Melik-Pashaev, D.A.; Zolotorev, M.S.

    1988-01-01

    Experiments on nonlinear magnetic optical (Faraday) rotation on resonance transitions of atomic samarium are described. Measurements were carried out on transitions with different angular momenta of upper and lower states: 1→0, 0→1 and 1→1. Qualitative explanations of observed phenomena are given

  9. Reflections of a Faraday Challenge Day Leader

    Science.gov (United States)

    Sewell, Keira

    2014-01-01

    Keira Sewell has just finished her second year as a Challenge Leader for the Faraday Challenge, a STEM-based scheme run by the Institution of Engineering and Technology. Aimed at 12-13 year-old students, its purpose is to engage students in future careers in engineering. Each year, a new challenge is held in over sixty schools and universities…

  10. [Enhancing effect of Ulex europaeus agglutinin I modified liposomes on oral insulin absorption in mice].

    Science.gov (United States)

    Zhang, Na; Ping, Qi-neng; Xu, Wen-fang

    2004-12-01

    To investigate the enhancing effect on insulin absorption through GI. tract in mice by using the Ulex europaeus agglutinin I (UEA1) modified liposomes as the carrier. UEA1 modified phosphatidylethanolamine (PE) was prepared by conjugating method of 1-ethyl-3-(3'-dimethylaminopropyl) carbodiimide (EDC), then the modified compound (PE-UEA1) was incorporated into the conventional liposomes of insulin to obtain UEA1 modified liposomes. The agglutination test was performed to examine the UEA1 biological activities after synthesis and modification. When liposomes were applied to healthy mice or diabetic mice at insulin dose of 350 u x kg(-1) orally, the hypoglycemic effect was investigated according to the blood glucose level determination. The blood glucose levels of the healthy mice reduced by UEA1 modified liposomes were (84 +/- 15)% at 4 h, (78 +/- 11)% at 8 h and (90 +/- 12)% at 12 h after oral administration. The conventional liposomes and saline showed no effect. The blood glucose levels of the diabetic mice reduced by UEA1 modified liposomes were (73 +/- 7)% at 4 h, (74 +/- 9)% at 8 h, (86 +/- 9)% at 12 h after oral administration. The UEA1 modified liposomes promote the oral absorption of insulin due to the specific-site combination on M cell membrane.

  11. Design and modeling of Faraday cages for substrate noise isolation

    Science.gov (United States)

    Wu, Joyce H.; del Alamo, Jesús A.

    2013-07-01

    A Faraday cage structure using through-substrate vias is an effective strategy to suppress substrate crosstalk, particularly at high frequencies. Faraday cages can reduce substrate noise by 32 dB at 10 GHz, and 26 dB at 50 GHz. We have developed lumped-element, equivalent circuit models of the Faraday cages and test structures to better understand the performance of the Faraday cages. These models compare well to measured results and show that the vias of the Faraday cage act as an RLC shunt to ground that draws substrate current. Designing a Faraday cage to achieve optimum isolation requires low via impedance and mitigation of via sidewall capacitance. The Faraday cage inductance is correlated to the number of vias and via spacing of the cage and can be optimized for the frequency of operation.

  12. Continuous Faraday measurement of spin precession without light shifts

    Science.gov (United States)

    Jasperse, M.; Kewming, M. Â. J.; Fischer, S. Â. N.; Pakkiam, P.; Anderson, R. Â. P.; Turner, L. Â. D.

    2017-12-01

    We describe a dispersive Faraday optical probe of atomic spin which performs a weak measurement of spin projection of a quantum gas continuously for more than one second. To date, focusing bright far-off-resonance probes onto quantum gases has proved invasive due to strong scalar and vector light shifts exerting dipole and Stern-Gerlach forces. We show that tuning the probe near the magic-zero wavelength at 790 nm between the fine-structure doublet of 87Rb cancels the scalar light shift, and careful control of polarization eliminates the vector light shift. Faraday rotations due to each fine-structure line reinforce at this wavelength, enhancing the signal-to-noise ratio for a fixed rate of probe-induced decoherence. Using this minimally invasive spin probe, we perform microscale atomic magnetometry at high temporal resolution. Spectrogram analysis of the Larmor precession signal of a single spinor Bose-Einstein condensate measures a time-varying magnetic field strength with 1 μ G accuracy every 5 ms; or, equivalently, makes more than 200 successive measurements each at 10 pT /√{Hz } sensitivity.

  13. Enhanced photoelectrochemical and photocatalytic activity of WO3-surface modified TiO2 thin film

    Science.gov (United States)

    Qamar, Mohammad; Drmosh, Qasem; Ahmed, Muhammad I.; Qamaruddin, Muhammad; Yamani, Zain H.

    2015-02-01

    Development of nanostructured photocatalysts for harnessing solar energy in energy-efficient and environmentally benign way remains an important area of research. Pure and WO3-surface modified thin films of TiO2 were prepared by magnetron sputtering on indium tin oxide glass, and photoelectrochemical and photocatalytic activities of these films were studied. TiO2 particles were <50 nm, while deposited WO3 particles were <20 nm in size. An enhancement in the photocurrent was observed when the TiO2 surface was modified WO3 nanoparticles. Effect of potential, WO3 amount, and radiations of different wavelengths on the photoelectrochemical activity of TiO2 electrodes was investigated. Photocatalytic activity of TiO2 and WO3-modified TiO2 for the decolorization of methyl orange was tested.

  14. Gene Therapy Vectors with Enhanced Transfection Based on Hydrogels Modified with Affinity Peptides

    Science.gov (United States)

    Shepard, Jaclyn A.; Wesson, Paul J.; Wang, Christine E.; Stevans, Alyson C.; Holland, Samantha J.; Shikanov, Ariella; Grzybowski, Bartosz A.; Shea, Lonnie D.

    2011-01-01

    Regenerative strategies for damaged tissue aim to present biochemical cues that recruit and direct progenitor cell migration and differentiation. Hydrogels capable of localized gene delivery are being developed to provide a support for tissue growth, and as a versatile method to induce the expression of inductive proteins; however, the duration, level, and localization of expression isoften insufficient for regeneration. We thus investigated the modification of hydrogels with affinity peptides to enhance vector retention and increase transfection within the matrix. PEG hydrogels were modified with lysine-based repeats (K4, K8), which retained approximately 25% more vector than control peptides. Transfection increased 5- to 15-fold with K8 and K4 respectively, over the RDG control peptide. K8- and K4-modified hydrogels bound similar quantities of vector, yet the vector dissociation rate was reduced for K8, suggesting excessive binding that limited transfection. These hydrogels were subsequently applied to an in vitro co-culture model to induce NGF expression and promote neurite outgrowth. K4-modified hydrogels promoted maximal neurite outgrowth, likely due to retention of both the vector and the NGF. Thus, hydrogels modified with affinity peptides enhanced vector retention and increased gene delivery, and these hydrogels may provide a versatile scaffold for numerous regenerative medicine applications. PMID:21514659

  15. Nonresonant Faraday rotation in glassy semiconductors

    Science.gov (United States)

    van den Keybus, P.; Grevendonk, W.

    1986-06-01

    Nonresonant interband Faraday rotation in amorphous semiconductors, as a function of photon energy, may be described by an equation derived for direct transitions in crystalline semiconductors. In this paper it is shown how this equation may be obtained for the former case also, assuming a parabolic density of states function N(E) and a correlation between valence- and conduction-band states. The analysis of experiments on chalcogenide glasses reveals a Faraday-rotation energy gap EFRg that is significantly larger than the optical gap Eoptg. The effect is attributed to transitions between extended states, so that it is meaningful to compare EFRg with the mobility gap Eμg. For oxide glasses both gaps are comparable but for chalcogenide glasses EFRg is too large by a few tenths of 1 eV.

  16. Biology's built-in Faraday cages

    Science.gov (United States)

    Klee, Maurice M.

    2014-05-01

    Biological fluids are water-based, ionic conductors. As such, they have both high relative dielectric constants and substantial conductivities, meaning they are lossy dielectrics. These fluids contain charged molecules (free charges), whose movements play roles in essentially all cellular processes from metabolism to communication with other cells. Using the problem of a point source in air above a biological fluid of semi-infinite extent, the bound charges in the fluid are shown to perform the function of a fast-acting Faraday cage, which protects the interior of the fluid from external electric fields. Free charges replace bound charges in accordance with the fluid's relaxation time, thereby providing a smooth transition between the initial protection provided by the bound charges and the steady state protection provided by the free charges. The electric fields within the biological fluid are thus small for all times just as they would be inside a classical Faraday cage.

  17. La electricidad antes de Faraday. Parte 2

    Directory of Open Access Journals (Sweden)

    Gabriel Poveda Ramos

    2004-01-01

    Full Text Available Esta es la segunda y última parte de este artículo, cuya primera parte fue publicada en el número anterior de esta revista. Esta parte cubre el período de la Edad Moderna posterior al Renacimiento, hasta llegar a Faraday. Presenta los descubrimientos y los inventos que en este tramo de historia se hicieron en la teoría y en la experimentación en el campo de la electricidad, los cuales forman parte muy importante de esa ciencia, con el nombre de electrostática. Esta parte final (y el artículo completo llegan hasta Faraday porque este gran científico reunió en un solo cuerpo de conocimientos la electricidad y el magnetismo.

  18. Theory of Kerr and Faraday rotations and linear dichroism in Topological Weyl Semimetals.

    Science.gov (United States)

    Kargarian, Mehdi; Randeria, Mohit; Trivedi, Nandini

    2015-08-03

    We consider the electromagnetic response of a topological Weyl semimetal (TWS) with a pair of Weyl nodes in the bulk and corresponding Fermi arcs in the surface Brillouin zone. We compute the frequency-dependent complex conductivities σαβ(ω) and also take into account the modification of Maxwell equations by the topological θ-term to obtain the Kerr and Faraday rotations in a variety of geometries. For TWS films thinner than the wavelength, the Kerr and Faraday rotations, determined by the separation between Weyl nodes, are significantly larger than in topological insulators. In thicker films, the Kerr and Faraday angles can be enhanced by choice of film thickness and substrate refractive index. We show that, for radiation incident on a surface with Fermi arcs, there is no Kerr or Faraday rotation but the electric field develops a longitudinal component inside the TWS, and there is linear dichroism signal. Our results have implications for probing the TWS phase in various experimental systems.

  19. Environmentally responsive surface-modified silica nanoparticles for enhanced oil recovery

    International Nuclear Information System (INIS)

    Behzadi, Abed; Mohammadi, Aliasghar

    2016-01-01

    Environmentally responsive surface-modified nanoparticles are colloidal nanoparticles coated with, at least, two physicochemically distinct surface groups. Recent advances in the synthesis and production of nanoparticles have enabled the production of environmentally responsive surface-modified nanoparticles with both hydrophilic and hydrophobic surface groups. These nanoparticles act like colloidal surfactants. In this paper, environmentally responsive surface-modified silica nanoparticles are synthesized and used for enhancement of oil recovery. For this purpose, silica nanoparticles are coated with polyethylene glycol chains as hydrophilic agent and propyl chains as hydrophobic agent at various quantities, and their ability to modulate oil–water interface properties and oil recovery is examined. Oil–water interfacial tension and water surface tension are decreased by 50 % in the presence of silica nanoparticles coated with both agents. Measuring oil-drop contact angle on oil-wetted glass slides and carbonate rock sections, after aging in various surface-modified silica nanofluids, indicates that the wettability of various oil-wetted surfaces is modified from strongly oil-wet to water-wet. Flooding nanofluids to glass micro-models and pore-level investigations demonstrate that surface modification of silica nanoparticles, specially, with both hydrophilic and hydrophobic agents improves considerably their performance in increasing oil recovery and wettability alteration.

  20. Environmentally responsive surface-modified silica nanoparticles for enhanced oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Behzadi, Abed; Mohammadi, Aliasghar, E-mail: amohammadi@sharif.edu [Sharif University of Technology, Department of Chemical and Petroleum Engineering (Iran, Islamic Republic of)

    2016-09-15

    Environmentally responsive surface-modified nanoparticles are colloidal nanoparticles coated with, at least, two physicochemically distinct surface groups. Recent advances in the synthesis and production of nanoparticles have enabled the production of environmentally responsive surface-modified nanoparticles with both hydrophilic and hydrophobic surface groups. These nanoparticles act like colloidal surfactants. In this paper, environmentally responsive surface-modified silica nanoparticles are synthesized and used for enhancement of oil recovery. For this purpose, silica nanoparticles are coated with polyethylene glycol chains as hydrophilic agent and propyl chains as hydrophobic agent at various quantities, and their ability to modulate oil–water interface properties and oil recovery is examined. Oil–water interfacial tension and water surface tension are decreased by 50 % in the presence of silica nanoparticles coated with both agents. Measuring oil-drop contact angle on oil-wetted glass slides and carbonate rock sections, after aging in various surface-modified silica nanofluids, indicates that the wettability of various oil-wetted surfaces is modified from strongly oil-wet to water-wet. Flooding nanofluids to glass micro-models and pore-level investigations demonstrate that surface modification of silica nanoparticles, specially, with both hydrophilic and hydrophobic agents improves considerably their performance in increasing oil recovery and wettability alteration.

  1. Platelet Lysate-Modified Porous Silicon Microparticles for Enhanced Cell Proliferation in Wound Healing Applications.

    Science.gov (United States)

    Fontana, Flavia; Mori, Michela; Riva, Federica; Mäkilä, Ermei; Liu, Dongfei; Salonen, Jarno; Nicoletti, Giovanni; Hirvonen, Jouni; Caramella, Carla; Santos, Hélder A

    2016-01-13

    The new frontier in the treatment of chronic nonhealing wounds is the use of micro- and nanoparticles to deliver drugs or growth factors into the wound. Here, we used platelet lysate (PL), a hemoderivative of platelets, consisting of a multifactorial cocktail of growth factors, to modify porous silicon (PSi) microparticles and assessed both in vitro and ex vivo the properties of the developed microsystem. PL-modified PSi was assessed for its potential to induce proliferation of fibroblasts. The wound closure-promoting properties of the microsystem were then assessed in an in vitro wound healing assay. Finally, the PL-modified PSi microparticles were evaluated in an ex vivo experiment over human skin. It was shown that PL-modified PSi microparticles were cytocompatible and enhanced the cell proliferation in different experimental settings. In addition, this microsystem promoted the closure of the gap between the fibroblast cells in the wound healing assay, in periods of time comparable with the positive control, and induced a proliferation and regeneration process onto the human skin in an ex vivo experiment. Overall, our results show that PL-modified PSi microparticles are suitable microsystems for further development toward applications in the treatment of chronic nonhealing wounds.

  2. C-60 as a Faraday cage

    OpenAIRE

    Delaney, Paul; Greer, J.C.

    2004-01-01

    Endohedral fullerenes have been proposed for a number of technological uses, for example, as a nanoscale switch, memory bit and as qubits for quantum computation. For these technology applications, it is important to know the ease with which the endohedral atom can be manipulated using an applied electric field. We find that the Buckminsterfullerene (C-60) acts effectively as a small Faraday cage, with only 25% of the field penetrating the interior of the molecule. Thus influencing the atom i...

  3. La electricidad antes de Faraday. Parte 1

    Directory of Open Access Journals (Sweden)

    Gabriel Poveda Ramos

    2003-01-01

    Full Text Available Este documento es una monografía sobre el surgimiento y el desarrollo de la ciencia de la electricidad desde la remota antigüedad hasta la época de Michael Faraday, a comienzos del siglo XIX. Está escrito con el propósito de reunirlo con otro que el autor ya escribió sobre la historia del magnetismo durante el mismo período.

  4. MUSIC for Faraday rotation measure synthesis

    Science.gov (United States)

    Andrecut, M.

    2013-03-01

    Faraday rotation measure (RM) synthesis requires the recovery of the Faraday dispersion function (FDF) from measurements restricted to limited wavelength ranges, which is an ill-conditioned deconvolution problem. Here, we propose a novel deconvolution method based on an extension of the MUltiple SIgnal Classification (MUSIC) algorithm. The complexity and speed of the method is determined by the eigen-decomposition of the covariance matrix of the observed polarizations. We show numerically that for high to moderate signal-to-noise ratio (S/N) cases the RM-MUSIC method is able to recover the Faraday depth values of closely spaced pairs of thin RM components, even in situations where the peak response of the FDF is outside of the RM range between the two input RM components. This result is particularly important because the standard deconvolution approach based on RM-CLEAN fails systematically in such situations, due to its greedy mechanism used to extract the RM components. For low S/N situations, both the RM-MUSIC and RM-CLEAN methods provide similar results.

  5. Midplane Faraday Rotation: A densitometer for BPX

    International Nuclear Information System (INIS)

    Jobes, F.C.; Mansfield, D.K.

    1992-02-01

    The density in a high field, high density tokamak such as BPX can be determined by measuring the Faraday rotation of a 10.6 μm laser directed tangent to the toroidal field. If there is a horizontal array of such beams, then n e (R) can be readily obtained with a simple Abel version about the center line of the tokamak. For BPX operated at full field and density, the rotation angle would be quite large -- about 75 degrees per pass. A layout in which a single laser beam is fanned out in the horizontal midplane of the tokamak, with a set of retroreflectors on the far side of the vacuum vessel, would provide good spatial resolution, depending only upon the number of reflectors. With this proposed layout, only one window would be needed. Because the rotation angle is never more than 1 ''fringe,'' the data is always good, and it is also a continuous measurement in time. Faraday rotation is dependent only upon the plasma itself, and thus is not sensitive to vibration of the optical components. Simulations of the expected results show that BPX would be well served even at low densities by a Midplane Faraday Rotation densitometer of ∼64 channels. Both TFTR and PBX-M would be suitable test beds for the BPX system

  6. Cloud point enhancement profile of libraries of modified Poly(N-isopropylmethacrylamide)

    International Nuclear Information System (INIS)

    Tavares, Alexandre Guilherme Silva; Silveira, Kelly Cristine da; Lucas, Elizabete Fernandes

    2016-01-01

    Full text: Poly(N-isopropyl methacrylamide) (PNIPMAM) based polymers are commercially available. These polymers present low cloud point, which may result in precipitation problems when applying for petroleum exploration [1]. Production of oil and gas has high temperature points, which can induce loss of activity for kinetic hydrate inhibitors (KHI), causing blockages by hydrates in pipes, fittings or valves. Hydrophobic groups can be added to modify PNIPMAM based polymers for hydrate inhibition during petroleum production. The cloud point enhancement profile of series of modified polymers was studied in this work. We synthesized poly(N-isopropyl methacrylamide-co-acrylic acid), P(NIPMAM-co-AA), by standard polymerization using AIBN as initiator. Series of modified polymers using two different groups (terc-butil and cyclopentyl) were studied. The characterization was made by nuclear magnetic resonance (NMR) to confirm the chemical structure; titration was used to determine the acrylic acid content for all synthesized polymers; Gel Permeation Chromatography (GPC) was applied to determine molar mass and polydispersity. A carbodiimide mediated coupling reaction (CMC) [2] was used to post synthetically modify the base polymer P(NIPMAM-co-AA) with N-(3-dimethylaminopropyl)-N’- ethylcarbodiimide hydrochloride (EDC) and N-hydroxysuccinimide (NHS) as activation agents. The cloud point experiment was carried out with deionized water and brine water where small vials with polymer solution were heated at 12 deg C/min rate. The temperature when the solution became turbid was monitored. The modified PNIPMAM based polymers presented a significant enhancement on cloud point temperature, up to 80 deg C, in comparison to unmodified polymer, P(NIPMAM-co- AA). References: [1] Mady, M. F.; Kelland, M.A. Energy and Fuels,28, 5714 (2014) [2] Silveira, K.C.; Sheng, Q.; Tian, W.; Lucas, E.F.; Wood, C.D. J. Appl. Poly. Sci.,132, 42797 (2015). (author)

  7. Rethinking Faraday's law for teaching motional electromotive force

    International Nuclear Information System (INIS)

    Zuza, Kristina; Guisasola, Jenaro; Michelini, Marisa; Santi, Lorenzo

    2012-01-01

    This study shows physicists' discussions on the meaning of Faraday's law where situations involving extended conductors or moving contact points are particularly troublesome. We raise questions to test students' difficulties in applying Faraday's law in motional electromotive force phenomena. We suggest the benefit of analysing these phenomena when teaching Faraday's law in introductory physics courses at university. We are not implying that Faraday's law should be revised, but we do want to set the stage for careful rethinking regarding the meaning and application of each term of the law as it appears in traditional introductory courses. (paper)

  8. Competing Turing and Faraday Instabilities in Longitudinally Modulated Passive Resonators.

    Science.gov (United States)

    Copie, François; Conforti, Matteo; Kudlinski, Alexandre; Mussot, Arnaud; Trillo, Stefano

    2016-04-08

    We experimentally investigate the interplay of Turing (modulational) and Faraday (parametric) instabilities in a bistable passive nonlinear resonator. The Faraday branch is induced via parametric resonance owing to a periodic modulation of the resonator dispersion. We show that the bistable switching dynamics is dramatically affected by the competition between the two instability mechanisms, which dictates two completely novel scenarios. At low detunings from resonance, switching occurs between the stable stationary lower branch and the Faraday-unstable upper branch, whereas at high detunings we observe the crossover between the Turing and Faraday periodic structures. The results are well explained in terms of the universal Lugiato-Lefever model.

  9. Generalized Faraday law derived from classical forces in a rotating frame

    OpenAIRE

    Choi, Taeseung

    2009-01-01

    We show the additional spin dependent classical force due to the rotation of an electron spin's rest frame is essential to derive a spin-Faraday law by using an analogy with the usual Faraday law. The contribution of the additional spin dependent force to the spin-Faraday law is the same as that of the spin geometric phase. With this observations, Faraday law is generalized to include both the usual Faraday and the spin-Faraday laws in a unified manner.

  10. ON THE SOURCE OF FARADAY ROTATION IN THE JET OF THE RADIO GALAXY 3C 120

    International Nuclear Information System (INIS)

    Gomez, Jose L.; Roca-Sogorb, Mar; Agudo, Ivan; Marscher, Alan P.; Jorstad, Svetlana G.

    2011-01-01

    The source of Faraday rotation in the jet of the radio galaxy 3C 120 is analyzed through Very Long Baseline Array observations carried out between 1999 and 2007 at 86, 43, 22, 15, 12, 8, 5, 2, and 1.7 GHz. Comparison of observations from 1999 to 2001 reveals uncorrelated changes in the linear polarization of the underlying jet emission and the Faraday rotation screen: while the rotation measure (RM) remains constant between approximately 2 and 5 mas from the core, the RM-corrected electric vector position angles (EVPAs) of two superluminal components are rotated by almost 90 0 when compared to other components moving through similar jet locations. On the other hand, the innermost 2 mas experiences a significant change in RM-including a sign reversal-but without variations in the RM-corrected EVPAs. Similarly, observations in 2007 reveal a double sign reversal in RM along the jet, while the RM-corrected EVPAs remain perpendicular to the jet axis. Although the observed coherent structure and gradient of the RM along the jet support the idea that the Faraday rotation is produced by a sheath of thermal electrons that surrounds the emitting jet, the uncorrelated changes in the RM and RM-corrected EVPAs indicate that the emitting jet and the source of Faraday rotation are not closely connected physically and have different configurations for the magnetic field and/or kinematical properties. Furthermore, the existence of a region of enhanced RM whose properties remain constant over three years requires a localized source of Faraday rotation, favoring a model in which a significant fraction of the RM originates in foreground clouds.

  11. Extracts of human atherosclerotic lesions modify LDL inducing enhanced macrophage uptake

    International Nuclear Information System (INIS)

    Hoff, H.F.; O'Neill, J.

    1986-01-01

    Both an LDL-like fraction isolated from human aortic plaques and LDL incubated with cultured aortic endothelial or smooth muscle cells have been shown to be internalized by macrophages in vitro in an unregulated fashion leading to foam cell formation. Lipid peroxidation induced by free radicals released from cells was shown to be responsible for cell-modified LDL. The authors incubated LDL with a supernatant fraction of leached, i.e. non-homogenized, extracts of aortic plaques for one hour at 37 0 C, to determine whether extracellular components present in arteries were also capable of modifying LDL. Extract-treated LDL showed the following changes relative to untreated LDL: 1) increased electrophretic mobility, 2) altered pattern of B-100 on SDS-PAGE, i.e. presence of a doublet with higher M/sub r/ than B-100, and 3) enhanced uptake by cultured mouse peritoneal macrophages as measured by increased degradation of 125 I-LDL, and increased stimulation of cholesterol esterification using 14 C-oleate. Extracts from homogenized plaques and grossly normal intima induced similar changes. The modification was tissue specific in that extracts of arteries but not of liver, muscle or skin modified LDL. Protease degradation of LDL during incubation was probably not responsible since inhibitors did not prevent modification. It is possible that products of lipid peroxidation present in extracellular lipid of arteries may propagate free radicals or be incorporated into LDL, leading to modifications similar to those found in cell-modified LDL

  12. Enhanced osteoblast responses to poly ether ether ketone surface modified by water plasma immersion ion implantation.

    Science.gov (United States)

    Wang, Heying; Lu, Tao; Meng, Fanhao; Zhu, Hongqin; Liu, Xuanyong

    2014-05-01

    Poly ether ether ketone (PEEK) offers a set of characteristics superior for human implants; however, its application is limited by the bio-inert surface property. In this work, PEEK surface was modified using single step plasma immersion ion implantation (PIII) treatment with a gas mixture of water vapor as a plasma resource and argon as an ionization assistant. Field emission scanning electron microscopy, atomic force microscopy and X-ray photoelectron spectroscopy were used to investigate the microstructure and composition of the modified PEEK surface. The water contact angle and zeta-potential of the surfaces were also measured. Osteoblast precursor cells MC3T3-E1 and rat bone mesenchymal stem cells were cultured on the PEEK samples to evaluate their cytocompatibility. The obtained results show that the hydroxyl groups as well as a "ravined structure" are constructed on water PIII modified PEEK. Compared with pristine PEEK, the water PIII treated PEEK is more favorable for osteoblast adhesion, spreading and proliferation, besides, early osteogenic differentiation indicated by the alkaline phosphatase activity is also up-regulated. Our study illustrates enhanced osteoblast responses to the PEEK surface modified by water PIII, which gives positive information in terms of future biomedical applications. Copyright © 2014 Elsevier B.V. All rights reserved.

  13. Interaction between Faraday rotation and Cotton-Mouton effects in polarimetry modeling for NSTX

    International Nuclear Information System (INIS)

    Zhang, J.; Crocker, N. A.; Carter, T. A.; Kubota, S.; Peebles, W. A.

    2010-01-01

    The evolution of electromagnetic wave polarization is modeled for propagation in the major radial direction in the National Spherical Torus Experiment with retroreflection from the center stack of the vacuum vessel. This modeling illustrates that the Cotton-Mouton effect-elliptization due to the magnetic field perpendicular to the propagation direction-is shown to be strongly weighted to the high-field region of the plasma. An interaction between the Faraday rotation and Cotton-Mouton effects is also clearly identified. Elliptization occurs when the wave polarization direction is neither parallel nor perpendicular to the local transverse magnetic field. Since Faraday rotation modifies the polarization direction during propagation, it must also affect the resultant elliptization. The Cotton-Mouton effect also intrinsically results in rotation of the polarization direction, but this effect is less significant in the plasma conditions modeled. The interaction increases at longer wavelength and complicates interpretation of polarimetry measurements.

  14. Image quality enhancement in low-light-level ghost imaging using modified compressive sensing method

    Science.gov (United States)

    Shi, Xiaohui; Huang, Xianwei; Nan, Suqin; Li, Hengxing; Bai, Yanfeng; Fu, Xiquan

    2018-04-01

    Detector noise has a significantly negative impact on ghost imaging at low light levels, especially for existing recovery algorithm. Based on the characteristics of the additive detector noise, a method named modified compressive sensing ghost imaging is proposed to reduce the background imposed by the randomly distributed detector noise at signal path. Experimental results show that, with an appropriate choice of threshold value, modified compressive sensing ghost imaging algorithm can dramatically enhance the contrast-to-noise ratio of the object reconstruction significantly compared with traditional ghost imaging and compressive sensing ghost imaging methods. The relationship between the contrast-to-noise ratio of the reconstruction image and the intensity ratio (namely, the average signal intensity to average noise intensity ratio) for the three reconstruction algorithms are also discussed. This noise suppression imaging technique will have great applications in remote-sensing and security areas.

  15. Cell penetrating peptide-modified poly(lactic-co-glycolic acid) nanoparticles with enhanced cell internalization.

    Science.gov (United States)

    Steinbach, Jill M; Seo, Young-Eun; Saltzman, W Mark

    2016-01-01

    The surface modification of nanoparticles (NPs) can enhance the intracellular delivery of drugs, proteins, and genetic agents. Here we studied the effect of different surface ligands, including cell penetrating peptides (CPPs), on the cell binding and internalization of poly(lactic-co-glycolic) (PLGA) NPs. Relative to unmodified NPs, we observed that surface-modified NPs greatly enhanced cell internalization. Using one CPP, MPG (unabbreviated notation), that achieved the highest degree of internalization at both low and high surface modification densities, we evaluated the effect of two different NP surface chemistries on cell internalization. After 2h, avidin-MPG NPs enhanced cellular internalization by 5 to 26-fold relative to DSPE-MPG NP formulations. Yet, despite a 5-fold increase in MPG density on DSPE compared to Avidin NPs, both formulations resulted in similar internalization levels (48 and 64-fold, respectively) after 24h. Regardless of surface modification, all NPs were internalized through an energy-dependent, clathrin-mediated process, and became dispersed throughout the cell. Overall both Avidin- and DSPE-CPP modified NPs significantly increased internalization and offer promising delivery options for applications in which internalization presents challenges to efficacious delivery. Copyright © 2015 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

  16. Voltage splay modes and enhanced phase locking in a modified linear Josephson array

    Science.gov (United States)

    Harris, E. B.; Garland, J. C.

    1997-02-01

    We analyze a modified linear Josephson-junction array in which additional unbiased junctions are used to greatly enhance phase locking. This geometry exhibits strong correlated behavior, with an external magnetic field tuning the voltage splay angle between adjacent Josephson oscillators. The array displays a coherent in-phase mode for f=, where f is the magnetic frustration, while for 0tolerant of critical current disorder approaching 100%. The stability of the array has also been studied by computing Floquet exponents. These exponents are found to be negative for all array lengths, with a 1/N2 dependence, N being the number of series-connected junctions.

  17. Rethinking Faraday's Law for Teaching Motional Electromotive Force

    Science.gov (United States)

    Zuza, Kristina; Guisasola, Jenaro; Michelini, Marisa; Santi, Lorenzo

    2012-01-01

    This study shows physicists' discussions on the meaning of Faraday's law where situations involving extended conductors or moving contact points are particularly troublesome. We raise questions to test students' difficulties in applying Faraday's law in motional electromotive force phenomena. We suggest the benefit of analysing these phenomena…

  18. Self-Induced Faraday Instability Laser

    Science.gov (United States)

    Perego, A. M.; Smirnov, S. V.; Staliunas, K.; Churkin, D. V.; Wabnitz, S.

    2018-05-01

    We predict the onset of self-induced parametric or Faraday instabilities in a laser, spontaneously caused by the presence of pump depletion, which leads to a periodic gain landscape for light propagating in the cavity. As a result of the instability, continuous wave oscillation becomes unstable even in the normal dispersion regime of the cavity, and a periodic train of pulses with ultrahigh repetition rate is generated. Application to the case of Raman fiber lasers is described, in good quantitative agreement between our conceptual analysis and numerical modeling.

  19. C60 as a Faraday cage

    Science.gov (United States)

    Delaney, P.; Greer, J. C.

    2004-01-01

    Endohedral fullerenes have been proposed for a number of technological uses, for example, as a nanoscale switch, memory bit and as qubits for quantum computation. For these technology applications, it is important to know the ease with which the endohedral atom can be manipulated using an applied electric field. We find that the Buckminsterfullerene (C60) acts effectively as a small Faraday cage, with only 25% of the field penetrating the interior of the molecule. Thus influencing the atom is difficult, but as a qubit the endohedral atom should be well shielded from environmental electrical noise. We also predict how the field penetration should increase with the fullerene radius.

  20. Homogenized boundary conditions and resonance effects in Faraday cages

    Science.gov (United States)

    Hewitt, I. J.

    2016-01-01

    We present a mathematical study of two-dimensional electrostatic and electromagnetic shielding by a cage of conducting wires (the so-called ‘Faraday cage effect’). Taking the limit as the number of wires in the cage tends to infinity, we use the asymptotic method of multiple scales to derive continuum models for the shielding, involving homogenized boundary conditions on an effective cage boundary. We show how the resulting models depend on key cage parameters such as the size and shape of the wires, and, in the electromagnetic case, on the frequency and polarization of the incident field. In the electromagnetic case, there are resonance effects, whereby at frequencies close to the natural frequencies of the equivalent solid shell, the presence of the cage actually amplifies the incident field, rather than shielding it. By appropriately modifying the continuum model, we calculate the modified resonant frequencies, and their associated peak amplitudes. We discuss applications to radiation containment in microwave ovens and acoustic scattering by perforated shells. PMID:27279775

  1. Homogenized boundary conditions and resonance effects in Faraday cages

    Science.gov (United States)

    Hewett, D. P.; Hewitt, I. J.

    2016-05-01

    We present a mathematical study of two-dimensional electrostatic and electromagnetic shielding by a cage of conducting wires (the so-called `Faraday cage effect'). Taking the limit as the number of wires in the cage tends to infinity, we use the asymptotic method of multiple scales to derive continuum models for the shielding, involving homogenized boundary conditions on an effective cage boundary. We show how the resulting models depend on key cage parameters such as the size and shape of the wires, and, in the electromagnetic case, on the frequency and polarization of the incident field. In the electromagnetic case, there are resonance effects, whereby at frequencies close to the natural frequencies of the equivalent solid shell, the presence of the cage actually amplifies the incident field, rather than shielding it. By appropriately modifying the continuum model, we calculate the modified resonant frequencies, and their associated peak amplitudes. We discuss applications to radiation containment in microwave ovens and acoustic scattering by perforated shells.

  2. Faraday instability of crystallization waves in 4He

    International Nuclear Information System (INIS)

    Abe, H; Ueda, T; Morikawa, M; Saitoh, Y; Nomura, R; Okuda, Y

    2007-01-01

    Periodic modulation of the gravity acceleration makes a flat surface of a fluid unstable and standing waves are parametrically excited on the surface. This phenomenon is called Faraday instability. Since a crystal-superfluid interface of 4 He at low temperatures is very mobile and behaves like a fluid surface, Saarloos and Weeks predicted that Faraday instability of the crystallization waves exists in 4 He and that the threshold excitation for the instability depends on the crystal growth coefficient. We successfully observed the Faraday instability of the crystal-liquid interface at 160 mK. Faraday waves were parametrically generated at one half of the driving frequency 90 Hz. Amplitude of the Faraday wave becomes smaller at higher temperature due to decrease of the crystal growth coefficient and disappears above 200 mK

  3. Enhanced performance of dye-sensitized solar cells using gold nanoparticles modified fluorine tin oxide electrodes

    International Nuclear Information System (INIS)

    Zhang Dingwen; Shen Jie; Huang Sumei; Wang Milton; Brolo, Alexandre G; Li Xiaodong

    2013-01-01

    We have investigated plasmon-assisted energy conversion in dye-sensitized solar cells (DSCs) applying gold nanoparticles (NPs) modified fluorine tin oxide (FTO) electrodes. A series of Au NPs with different sizes (15-80 nm) were synthesized and immobilized onto FTO glass slides. Photoanodes were prepared on these Au modified FTO substrates using P25 TiO 2 powders and by the screen-printing method. The size effects of Au NPs on the photovoltaic performance of the formed DSCs were investigated systematically. Structural and photoelectrochemical properties of the formed photoanodes were examined by field emission scanning electron microscopy and electrochemical impedance spectroscopy. It was found that the energy conversion efficiency of the DSC was highly dependent on the Au particle size. When the particle size was not greater than 60 nm, the DSC based on the Au NP-FTO composite electrode showed a higher short-circuit current density and better photovoltaic (PV) performance than the cell based on the bare FTO. The best cell was achieved using 25 nm sized Au NPs modified FTO. It exhibited a conversion efficiency of 6.69%, which was 15% higher than that of DSCs without Au NPs. The related PV performance enhancement mechanisms, photoelectrochemical processes and surface-plasmon resonances in DSCs with Au nanostructures are analysed and discussed.

  4. DNA-modified electrodes fabricated using copper-free click chemistry for enhanced protein detection.

    Science.gov (United States)

    Furst, Ariel L; Hill, Michael G; Barton, Jacqueline K

    2013-12-31

    A method of DNA monolayer formation has been developed using copper-free click chemistry that yields enhanced surface homogeneity and enables variation in the amount of DNA assembled; extremely low-density DNA monolayers, with as little as 5% of the monolayer being DNA, have been formed. These DNA-modified electrodes (DMEs) were characterized visually, with AFM, and electrochemically, and were found to facilitate DNA-mediated reduction of a distally bound redox probe. These low-density monolayers were found to be more homogeneous than traditional thiol-modified DNA monolayers, with greater helix accessibility through an increased surface area-to-volume ratio. Protein binding efficiency of the transcriptional activator TATA-binding protein (TBP) was also investigated on these surfaces and compared to that on DNA monolayers formed with standard thiol-modified DNA. Our low-density monolayers were found to be extremely sensitive to TBP binding, with a signal decrease in excess of 75% for 150 nM protein. This protein was detectable at 4 nM, on the order of its dissociation constant, with our low-density monolayers. The improved DNA helix accessibility and sensitivity of our low-density DNA monolayers to TBP binding reflects the general utility of this method of DNA monolayer formation for DNA-based electrochemical sensor development.

  5. Thermal enhancement cartridge heater modified (TECH Mod) tritium hydride bed development, Part 1 - Design and fabrication

    Energy Technology Data Exchange (ETDEWEB)

    Klein, J.E.; Estochen, E.G. [Savannah River National Laboratory, Aiken, SC (United States)

    2015-03-15

    The Savannah River Site (SRS) tritium facilities have used first generation (Gen1) LaNi{sub 4.25}Al{sub 0.75} (LANA0.75) metal hydride storage beds for tritium absorption, storage, and desorption. The Gen1 design utilizes hot and cold nitrogen supplies to thermally cycle these beds. Second and third generation (Gen2 and Gen3) storage bed designs include heat conducting foam and divider plates to spatially fix the hydride within the bed. For thermal cycling, the Gen2 and Gen3 beds utilize internal electric heaters and glovebox atmosphere flow over the bed inside the bed external jacket for cooling. The currently installed Gen1 beds require replacement due to tritium aging effects on the LANA0.75 material, and cannot be replaced with Gen2 or Gen3 beds due to different designs of these beds. At the end of service life, Gen1 bed desorption efficiencies are limited by the upper temperature of hot nitrogen supply. To increase end-of-life desorption efficiency, the Gen1 bed design was modified, and a Thermal Enhancement Cartridge Heater Modified (TECH Mod) bed was developed. Internal electric cartridge heaters in the new design to improve end-of-life desorption, and also permit in-bed tritium accountability (IBA) calibration measurements to be made without the use of process tritium. Additional enhancements implemented into the TECH Mod design are also discussed. (authors)

  6. Chitosan-modified porous silicon microparticles for enhanced permeability of insulin across intestinal cell monolayers.

    Science.gov (United States)

    Shrestha, Neha; Shahbazi, Mohammad-Ali; Araújo, Francisca; Zhang, Hongbo; Mäkilä, Ermei M; Kauppila, Jussi; Sarmento, Bruno; Salonen, Jarno J; Hirvonen, Jouni T; Santos, Hélder A

    2014-08-01

    Porous silicon (PSi) based particulate systems are emerging as an important drug delivery system due to its advantageous properties such as biocompatibility, biodegradability and ability to tailor the particles' physicochemical properties. Here, annealed thermally hydrocarbonized PSi (AnnTHCPSi) and undecylenic acid modified AnnTHCPSi (AnnUnTHCPSi) microparticles were developed as a PSi-based platform for oral delivery of insulin. Chitosan (CS) was used to modify the AnnUnTHCPSi microparticles to enhance the intestinal permeation of insulin. Surface modification with CS led to significant increase in the interaction of PSi microparticles with Caco-2/HT-29 cell co-culture monolayers. Compared to pure insulin, the CS-conjugated microparticles significantly improved the permeation of insulin across the Caco-2/HT-29 cell monolayers, with ca. 20-fold increase in the amount of insulin permeated and ca. 7-fold increase in the apparent permeability (P(app)) value. Moreover, among all the investigated particles, the CS-conjugated microparticles also showed the highest amount of insulin associated with the mucus layer and the intestinal Caco-2 cells and mucus secreting HT-29 cells. Our results demonstrate that CS-conjugated AnnUnTHCPSi microparticles can efficiently enhance the insulin absorption across intestinal cells, and thus, they are promising microsystems for the oral delivery of proteins and peptides across the intestinal cell membrane. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. Ultrafast time-resolved faraday rotation in EuO thin films.

    Science.gov (United States)

    Liu, F; Makino, T; Yamasaki, T; Ueno, K; Tsukazaki, A; Fukumura, T; Kong, Y; Kawasaki, M

    2012-06-22

    We have investigated the ultrafast spin dynamics in EuO thin films by time-resolved Faraday rotation spectroscopy. The photoinduced magnetization is found to be increased in a transient manner, accompanied with subsequent demagnetization. The dynamical magnetization enhancement showed a maximum slightly below the Curie temperature with prolonged tails toward both lower and higher temperatures and dominates the demagnetization counterpart at 55 K. The magnetization enhancement component decays in ~1 ns. The realization of the transient collective ordering is attributable to the enhancement of the f-d exchange interaction.

  8. Preinjector for Linac 1, Faraday cage

    CERN Multimedia

    1974-01-01

    The 50 MeV Linac 1 started up in 1958 as injector to the 26 GeV PS, with a 520 kV Cockcroft-Walton generator as its preinjector, housed in a vast Faraday cage, visible here. When the Cockcroft-Walton broke down in 1973, it was replaced by a much smaller SAMES generator, of the kind used for electrostatic separators. From 1980 on, Linac 2 took over as injector for the 800 MeV Booster, and Linac 1 continued as injector for LEAR. In 1984, the electrostatic preinjector (i.e. the Faraday cage with its contents, SAMES generator and all) was replaced by a 520 keV RFQ. At the lower left corner we see the HV connectors to the SAMES generator, at the right edge part of the opened electronics-platform. Jean-Luc Vallet sees to it that all parts are properly grounded. See also 7403073X, 7403074X, 7403081X, 7403083X.

  9. Nuclear spin optical rotation and Faraday effect in gaseous and liquid water.

    Science.gov (United States)

    Pennanen, Teemu S; Ikäläinen, Suvi; Lantto, Perttu; Vaara, Juha

    2012-05-14

    Nuclear spin optical rotation (NSOR) of linearly polarized light, due to the nuclear spins through the Faraday effect, provides a novel probe of molecular structure and could pave the way to optical detection of nuclear magnetization. We determine computationally the effects of the liquid medium on NSOR and the Verdet constant of Faraday rotation (arising from an external magnetic field) in water, using the recently developed theory applied on a first-principles molecular dynamics trajectory. The gas-to-liquid shifts of the relevant antisymmetric polarizability and, hence, NSOR magnitude are found to be -14% and -29% for (1)H and (17)O nuclei, respectively. On the other hand, medium effects both enhance the local electric field in water and, via bulk magnetization, the local magnetic field. Together these two effects partially cancel the solvation influence on the single-molecular property. We find a good agreement for the hydrogen NSOR with a recent pioneering experiment on H(2)O(l).

  10. Enhanced oxidation and detection of toxic ractopamine using carbon nanotube film-modified electrode

    International Nuclear Information System (INIS)

    Liu Zhuan; Zhou Yikai; Wang Yanying; Cheng Qin; Wu Kangbing

    2012-01-01

    Highlights: ► The enhanced oxidation of ractopamine on MWCNT film surface was firstly studied. ► The oxidation occurred at phenolic hydroxyl groups and transferred two electrons. ► A sensitive and effective electrochemical sensor was developed for ractopamine. ► It was used to detect ractopamine in animal tissues, the recovery was satisfactory. - Abstract: Insoluble multi-walled carbon nanotube (MWCNT) was readily dispersed into water in the presence of dihexadecyl hydrogen phosphate, and then used to modify the surface of glassy carbon electrode (GCE) by means of solvent evaporation. Scanning electron microscopy test indicated that the GCE surface was coated with uniform MWCNT film. The resulting MWCNT film-modified GCE greatly enhanced the oxidation signal of ractopamine. The oxidation mechanism was studied, and it was found that the oxidation of ractopamine occurred at two phenolic hydroxyl groups, involving two protons and two electrons. Moreover, the influences of pH value, amount of MWCNT, accumulation potential and time were investigated on the oxidation signal of ractopamine. Based on the strong enhancement effect of MWCNT, a sensitive, rapid and simple electrochemical method was developed for the detection of ractopamine. The linear range was from 50 μg L −1 to 2 mg L −1 , and the detection limit was 20 μg L −1 . Finally, this method was successfully used to detect the content of ractopamine in pork and liver samples, and the recovery was in the range from 93.1% to 107.2%.

  11. Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition

    Energy Technology Data Exchange (ETDEWEB)

    Carugno, Sofía [INQUIMAE – DQIAQF, Facultad de Ciencias, Exactas y Naturales, Universidad de Buenos Aires, Consejo Nacional de Investigaciones Científicas y Técnicas, 1428 Buenos Aires (Argentina); Chassaing, Elisabeth [IRDEP (UMR7174), EDF R and D, 6 Quai Watier, 78401 Chatou (France); Rosso, Michel [LPMC (UMR7643), CNRS, Ecole Polytechnique, F91128 Palaiseau Cedex (France); González, Graciela A., E-mail: graciela@qi.fcen.uba.ar [INQUIMAE – DQIAQF, Facultad de Ciencias, Exactas y Naturales, Universidad de Buenos Aires, Consejo Nacional de Investigaciones Científicas y Técnicas, 1428 Buenos Aires (Argentina)

    2014-02-14

    In this paper, we report a study of electrocatalytic oxidation of methanol on copper electrodes subjected to different surface treatments, either electrocorrosion or electrodeposition in the absence of strong hydrogen co-deposition. The surface morphology of treated electrodes was examined by Field Emission Scanning Electron Microscopy (FE-SEM). The effect of different treatment conditions and the methanol concentration dependence were evaluated by cyclic voltammetric technique. The results indicate that the oxidation of methanol can be enhanced by a suitable micro and nano structure generated by these treatments. This enhanced electrode activity is related to an increase of the effective surface area and/or to an increase of the surface concentration of electroactive molecules or intermediates. - Highlights: • We presented simple treatments to increase the response of copper electrodes. • Copper electrodes were modified by electrocorrosion and electrodeposition. • Scanning Electron Microscopy images reveal the effects of the different treatments. • The response is enhanced by an area increase and/or intermediates concentration. • For each treatment the concentration range of the diffusion control is analyzed.

  12. Development of Faraday rotators for high power glass laser systems

    International Nuclear Information System (INIS)

    Yoshida, Kunio; Kato, Yoshiaki; Yamanaka, Chiyoe.

    1980-01-01

    As a new approach to nuclear fusion, laser-induced fusion has been recently highlighted. It is no exaggeration to say that the future success of this technique depends on the development of high power laser as the energy driver. Faraday rotators are used as photo-diodes to prevent amplifiers and oscillator assemblies from the possibility to be broken by reversely transmitting light. The authors were able to increase the isolation ratio by about 10 times as compared with conventional one by employing the large performance index, disc type Faraday glass, FR-5. In this paper, first, Faraday glasses which are the composing element of Faraday rotators and the optical characteristics of dielectric thin-film polarizers are described, and next, the design of a magnetic coil and its resulting coil characteristics are reported. Then the dominant causes limiting the isolation ratio of Faraday rotators are investigated, and it is clarified that the residual strain in Faraday glasses and the non-uniformity of magnetic field affect predominantly. The measured results are as follows: The magnetic flux densities required to rotate by 45 deg the polarizing plane of the light transmitted through the Faraday rotators A and B are both 27 kG; and the isolation ratios over the whole effective plane are 36 and 32 dB, respectively. (Wakatsuki, Y.)

  13. Performance enhancement of optical code-division multiple-access systems using transposed modified Walsh code

    Science.gov (United States)

    Sikder, Somali; Ghosh, Shila

    2018-02-01

    This paper presents the construction of unipolar transposed modified Walsh code (TMWC) and analysis of its performance in optical code-division multiple-access (OCDMA) systems. Specifically, the signal-to-noise ratio, bit error rate (BER), cardinality, and spectral efficiency were investigated. The theoretical analysis demonstrated that the wavelength-hopping time-spreading system using TMWC was robust against multiple-access interference and more spectrally efficient than systems using other existing OCDMA codes. In particular, the spectral efficiency was calculated to be 1.0370 when TMWC of weight 3 was employed. The BER and eye pattern for the designed TMWC were also successfully obtained using OptiSystem simulation software. The results indicate that the proposed code design is promising for enhancing network capacity.

  14. Facile synthesis of polyaniline-modified CuS with enhanced adsorbtion and photocatalytic activity

    Science.gov (United States)

    Wang, Xiufang; Chen, Shaohua; Shuai, Ying

    2016-10-01

    Novel hierarchical polyaniline-modified CuS (PANI-CuS) has been synthesized by simple assembling PANI on the surface of flower-like CuS spheres. The PANI modification enhances the adsorption properties of flower-like CuS. The prepared PANI-CuS composites exhibit higher visible-light-driven photocatalytic activities in degradation of rhodamine B (RhB) than that of neat CuS. The unusual photocatalytic activity could be attributed to the great adsorptivity of dyes, the extended photoresponse range, and the high migration efficiency of photoinduced electrons, which may effectively suppress the charge recombination. This work not only provides a simple strategy for fabricating highly efficient and stable CuS-based composites, but also proves that these unique structures are excellent platforms for significantly improving their visible- light-driven photoactivities, holding great promise for their applications in the field of purifying polluted water resources.

  15. Voltage splay modes and enhanced phase locking in a modified linear Josephson array

    International Nuclear Information System (INIS)

    Harris, E.B.; Garland, J.C.

    1997-01-01

    We analyze a modified linear Josephson-junction array in which additional unbiased junctions are used to greatly enhance phase locking. This geometry exhibits strong correlated behavior, with an external magnetic field tuning the voltage splay angle between adjacent Josephson oscillators. The array displays a coherent in-phase mode for f=(1)/(2), where f is the magnetic frustration, while for 0 p (f)=2aV dc /Φ 0 (1-2f). The locked splay modes are found to be tolerant of critical current disorder approaching 100%. The stability of the array has also been studied by computing Floquet exponents. These exponents are found to be negative for all array lengths, with a 1/N 2 dependence, N being the number of series-connected junctions. copyright 1996 The American Physical Society

  16. Modifying Memory: Selectively Enhancing and Updating Personal Memories for a Museum Tour by Reactivating Them

    Science.gov (United States)

    St. Jacques, Peggy L.; Schacter, Daniel L.

    2013-01-01

    Memory can be modified when reactivated, but little is known about how the properties and extent of reactivation can selectively affect subsequent memory. We developed a novel museum paradigm to directly investigate reactivation-induced plasticity for personal memories. Participants reactivated memories triggered by photos taken from a camera they wore during a museum tour and made relatedness judgments on novel photos taken from a different tour of the same museum. Subsequent recognition memory for events at the museum was better for memories that were highly reactivated (i.e., the retrieval cues during reactivation matched the encoding experience) than for memories that were reactivated at a lower level (i.e., the retrieval cues during reactivation mismatched the encoding experience), but reactivation also increased false recognition of photographs depicting stops that were not experienced during the museum tour. Reactivation thus enables memories to be selectively enhanced and distorted via updating, thereby supporting the dynamic and flexible nature of memory. PMID:23406611

  17. Modified enhanced recovery after surgery (ERAS) protocols for patients with obstructive colorectal cancer.

    Science.gov (United States)

    Shida, Dai; Tagawa, Kyoko; Inada, Kentaro; Nasu, Keiichi; Seyama, Yasuji; Maeshiro, Tsuyoshi; Miyamoto, Sachio; Inoue, Satoru; Umekita, Nobutaka

    2017-02-16

    Enhanced recovery after surgery (ERAS) protocols are now well-known to be useful for elective colorectal surgery, as they result in shorter hospital stays without adversely affecting morbidity. However, the efficacy and safety of ERAS protocols for patients with obstructive colorectal cancer have yet to be clarified. We evaluated 122 consecutive resections for obstructive colorectal cancer performed between July 2008 and November 2012 at Tokyo Metropolitan Bokutoh Hospital. Patients with rupture or impending rupture and those who received simple colostomy were excluded. The first set of 42 patients was treated based on traditional protocols, and the latter 80 according to modified ERAS protocols. The main endpoints were length of postoperative hospital stay, postoperative short-term morbidity, rate of readmission within 30 days, and mortality. Differences in modified ERAS protocols relative to traditional care include intensive preoperative counseling (by both surgeons and anesthesiologists), perioperative fluid management (avoidance of sodium/fluid overload), shortening of postoperative fasting period and early provision of oral nutrition, intraoperative warm air body heating, enforced postoperative mobilization, stimulation of gut motility, early removal of urinary catheter, and a multidisciplinary team approach to care. Median (interquartile range) postoperative hospital stay was 10 (10-14.25) days in the traditional group, and seven (7-8.75) days in the ERAS group, showing a 3-day reduction in hospital stay (p < 0.01). According to the Clavien-Dindo classification, overall incidences of grade 2 or higher postoperative complications for the traditional and ERAS groups were 15 and 10% (p = 0.48), and 30-day readmission rates were 0 and 1.3% (p = 1.00), respectively. As for mortality, one patient in the traditional group died and none in the ERAS group (p = 0.34). Modified ERAS protocols for obstructive colorectal cancer reduced hospital stay

  18. Bio-active molecules modified surfaces enhanced mesenchymal stem cell adhesion and proliferation

    International Nuclear Information System (INIS)

    Mobasseri, Rezvan; Tian, Lingling; Soleimani, Masoud; Ramakrishna, Seeram; Naderi-Manesh, Hossein

    2017-01-01

    Surface modification of the substrate as a component of in vitro cell culture and tissue engineering, using bio-active molecules including extracellular matrix (ECM) proteins or peptides derived ECM proteins can modulate the surface properties and thereby induce the desired signaling pathways in cells. The aim of this study was to evaluate the behavior of human bone marrow mesenchymal stem cells (hBM-MSCs) on glass substrates modified with fibronectin (Fn), collagen (Coll), RGD peptides (RGD) and designed peptide (R-pept) as bio-active molecules. The glass coverslips were coated with fibronectin, collagen, RGD peptide and R-peptide. Bone marrow mesenchymal stem cells were cultured on different substrates and the adhesion behavior in early incubation times was investigated using scanning electron microscopy (SEM) and confocal microscopy. The MTT assay was performed to evaluate the effect of different bio-active molecules on MSCs proliferation rate during 24 and 72 h. Formation of filopodia and focal adhesion (FA) complexes, two steps of cell adhesion process, were observed in MSCs cultured on bio-active molecules modified coverslips, specifically in Fn coated and R-pept coated groups. SEM image showed well adhesion pattern for MSCs cultured on Fn and R-pept after 2 h incubation, while the shape of cells cultured on Coll and RGD substrates indicated that they might experience stress condition in early hours of culture. Investigation of adhesion behavior, as well as proliferation pattern, suggests R-peptide as a promising bio-active molecule to be used for surface modification of substrate in supporting and inducing cell adhesion and proliferation. - Highlights: • Bioactive molecules modified surface is a strategy to design biomimicry scaffold. • Bi-functional Tat-derived peptide (R-pept) enhanced MSCs adhesion and proliferation. • R-pept showed similar influences to fibronectin on FA formation and attachment.

  19. Enhanced Stormwater Contaminant Removal and Improved Runoff Quality Using Modified Sorbents in Tree Filters

    Science.gov (United States)

    Schifman, L. A.; Kasaraneni, V.; Boving, T. B.; Oyanedel-Craver, V.

    2013-12-01

    Stormwater runoff, particularly in urban areas, contains high concentrations of pathogens that are often cited as one of the main reasons for beach closings and other water quality issues in coastal areas. Commonly found contaminants in runoff are often addressed by structural best management practices (BMP) that capture and treat the runoff before discharging it. Many BMP, such as tree filters, act as primary filtration devices that attenuate total suspended solids, nutrients, and heavy metals from runoff, but typically these BMPs are not designed to treat bacteria and have only minor petroleum hydrocarbon (PH) treatment capabilities. To address this shortcoming, the contaminant retention of an alternative sorption material was compared to expanded shale that is usually used in tree filters. Red cedar wood chips were modified with either Quaternary Ammonium Silane (QAS) or Silver Nanoparticles (AgNPs) to provide antimicrobial properties to the matrix and/or exploit their affinity to sorb PH, particularly polycyclic aromatic hydrocarbons (PAH). Results show that the wood chips exhibit the highest sorption capacity for QAS, making this material favorable for treating bacteria, while at the same time attenuating PAH by sorption processes. In the case of AgNP amendment to wood, less AgNP uptake and more desorption from the wood matrix was observed, making this amendment less favorable for bacteria deactivation. Batch experiments show that wood chips modified with QAS can remove up to 3 orders of magnitude of bacteria and retain up to 0.1 mg/g of PAH compared to shale, which has very limited bacteria deactivation (less than one order of magnitude) a PAH retention capacity of 0.04 mg/g. In this talk, the contaminant removal efficiency of the modified and unmodified materials will be discussed on the background of how these materials may find use in enhanced treatment of stormwater in tree filter BMPs.

  20. Enhanced electrocatalytic oxidation of isoniazid at electrochemically modified rhodium electrode for biological and pharmaceutical analysis.

    Science.gov (United States)

    Cheemalapati, Srikanth; Chen, Shen-Ming; Ali, M Ajmal; Al-Hemaid, Fahad M A

    2014-09-01

    A simple and sensitive electrochemical method has been proposed for the determination of isoniazid (INZ). For the first time, rhodium (Rh) modified glassy carbon electrode (GCE) has been employed for the determination of INZ by linear sweep voltammetry technique (LSV). Compared with the unmodified electrode, the proposed Rh modified electrode provides strong electrocatalytic activity toward INZ with significant enhancement in the anodic peak current. Scanning electron microscopy (SEM) and field emission scanning electron microscopy (FESEM) results reveal the morphology of Rh particles. With the advantages of wide linearity (70-1300μM), good sensitivity (0.139μAμM(-1)cm(-2)) and low detection limit (13μM), this proposed sensor holds great potential for the determination of INZ in real samples. The practicality of the proposed electrode for the detection of INZ in human urine and blood plasma samples has been successfully demonstrated using LSV technique. Through the determination of INZ in commercially available pharmaceutical tablets, the practical applicability of the proposed method has been validated. The recovery results are found to be in good agreement with the labeled amounts of INZ in tablets, thus showing its great potential for use in clinical and pharmaceutical analysis. Copyright © 2014 Elsevier B.V. All rights reserved.

  1. Synthesis and characterization of modified κ-carrageenan for enhanced proton conductivity as polymer electrolyte membrane.

    Directory of Open Access Journals (Sweden)

    Joy Wei Yi Liew

    Full Text Available Polymer electrolyte membranes based on the natural polymer κ-carrageenan were modified and characterized for application in electrochemical devices. In general, pure κ-carrageenan membranes show a low ionic conductivity. New membranes were developed by chemically modifying κ-carrageenan via phosphorylation to produce O-methylene phosphonic κ-carrageenan (OMPC, which showed enhanced membrane conductivity. The membranes were prepared by a solution casting method. The chemical structure of OMPC samples were characterized using Fourier transform infrared spectroscopy (FTIR, 1H nuclear magnetic resonance (1H NMR spectroscopy and 31P nuclear magnetic resonance (31P NMR spectroscopy. The conductivity properties of the membranes were investigated by electrochemical impedance spectroscopy (EIS. The characterization demonstrated that the membranes had been successfully produced. The ionic conductivity of κ-carrageenan and OMPC were 2.79 × 10-6 S cm-1 and 1.54 × 10-5 S cm-1, respectively. The hydrated membranes showed a two orders of magnitude higher ionic conductivity than the dried membranes.

  2. Simulation of modified hybrid noise reduction algorithm to enhance the speech quality

    International Nuclear Information System (INIS)

    Waqas, A.; Muhammad, T.; Jamal, H.

    2013-01-01

    Speech is the most essential method of correspondence of humankind. Cell telephony, portable hearing assistants and, hands free are specific provisions in this respect. The performance of these communication devices could be affected because of distortions which might augment them. There are two essential sorts of distortions that might be recognized, specifically: convolutive and additive noises. These mutilations contaminate the clean speech and make it unsatisfactory to human audiences i.e. perceptual value and intelligibility of speech signal diminishes. The objective of speech upgrade systems is to enhance the quality and understandability of speech to make it more satisfactory to audiences. This paper recommends a modified hybrid approach for single channel devices to process the noisy signals considering only the effect of background noises. It is a mixture of pre-processing relative spectral amplitude (RASTA) filter, which is approximated by a straight forward 4th order band-pass filter, and conventional minimum mean square error short time spectral amplitude (MMSE STSA85) estimator. To analyze the performance of the algorithm an objective parameter called Perceptual estimation of speech quality (PESQ) is measured. The results show that the modified algorithm performs well to remove the background noises. SIMULINK implementation is also performed and its profile report has been generated to observe the execution time. (author)

  3. Surface-modified polymeric pads for enhanced performance during chemical mechanical planarization

    International Nuclear Information System (INIS)

    Deshpande, S.; Dakshinamurthy, S.; Kuiry, S.C.; Vaidyanathan, R.; Obeng, Y.S.; Seal, S.

    2005-01-01

    The chemical mechanical planarization (CMP) process occurs at an atomic level at the slurry/wafer interface and hence slurries and polishing pads play a critical role in their successful implementation. Polyurethane is a commonly used polymer in the manufacturing of CMP pads. These pads are incompatible with some chemicals present in the CMP slurries, such as hydrogen peroxide. To overcome these problems, Psiloquest has developed new Application Specific Pads (ASP). Surface of such pads has been modified by depositing a thin film of tetraethyl orthosilicate using plasma-enhanced chemical vapor deposition (PECVD) process. In the present study, mechanical properties of such coated pads have been investigated using nanoindentation. The surface morphology and the chemistry of the ASP were studied using scanning electron microcopy, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy techniques. It was observed that mechanical and chemical properties of the pad top surface are a function of the PECVD coating time. Such PECVD-treated pads are found to be hydrophilic and do not require storage in aqueous media during the not-in-use period. The metal removal rate using such surface-modified polishing pads was found to increase linearly with the PECVD coating time

  4. Growth, Faraday and inverse Faraday characteristics of Tb2Ti2O7 crystal.

    Science.gov (United States)

    Guo, Feiyun; Sun, Yilin; Yang, Xiongsheng; Chen, Xin; Zhao, Bin; Zhuang, Naifeng; Chen, Jianzhong

    2016-03-21

    Tb2Ti2O7 (TTO) single crystal with dimensions of 20 × 20 × 16 mm3 was grown by the Czochralski method. Rietveld structure refinement of X-ray diffraction (XRD) data confirms that the compound crystallizes in the cubic system with pyrochlore structure. Transmission spectra, Magnetic circular dichroism (MCD) spectra, Faraday and inverse Faraday characteristics of TTO crystal have been measured and analyzed in detail. The results demonstrate that TTO crystal has high transmittance at 700-1400 nm waveband and a larger Verdat constant than that of TGG reported. Magnetic circular dichroism (MCD) spectra showed that the 4f→4f transitions of Tb3+ have significant contributions to the magneto-optical activity (MOA). In the time-resolved pump-probe spectroscopy, the rotation signals of the probe beam based on the inverse Faraday effect in magneto-optical crystal were observed at zero time delay, the full width at half maximum of the rotation and ellipticity signals can be as fast as ~500 fs, which indicates that TTO crystal can be a promising material for ultrafast all-optical magnetic switching.

  5. The RSC Faraday prize lecture of 1989 on platinum.

    Science.gov (United States)

    Thomas, John Meurig

    2017-08-25

    In 1861, Michael Faraday gave one of his last Friday Evening Discourses at the Royal Institution of Great Britain, London, on platinum, which he described as "this beautiful, magnificent and valuable metal". More than a hundred and twenty years later (in 1989), the author re-enacted, at the Royal Institution, many of the demonstrations that Faraday carried out in his memorable Discourse. This article outlines many of Faraday's views on, and experiments with, platinum. It also describes the continuing importance and utilization of platinum, both as perceived in 1989 and from present perspectives.

  6. Giant Faraday Rotation in Metal-Fluoride Nanogranular Films.

    Science.gov (United States)

    Kobayashi, N; Ikeda, K; Gu, Bo; Takahashi, S; Masumoto, H; Maekawa, S

    2018-03-21

    Magneto-optical Faraday effect is widely applied in optical devices and is indispensable for optical communications and advanced information technology. However, the bismuth garnet Bi-YIG is only the Faraday material since 1972. Here we introduce (Fe, FeCo)-(Al-,Y-fluoride) nanogranular films exhibiting giant Faraday effect, 40 times larger than Bi-YIG. These films have a nanocomposite structure, in which nanometer-sized Fe, FeCo ferromagnetic granules are dispersed in a Al,Y-fluoride matrix.

  7. Theory of the inverse Faraday effect in metals

    International Nuclear Information System (INIS)

    Hertel, Riccardo

    2006-01-01

    An analytic expression is given for the inverse Faraday effect, i.e., for the magnetization occurring in a transparent medium exposed to a circularly polarized high-frequency electromagnetic wave. Using a microscopic approach based on the Drude approximation of a free-electron gas, the magnetization of the medium due to the inverse Faraday effect is identified as the result of microscopic solenoidal currents generated by the electromagnetic wave. In contrast to the better known phenomenological derivation, this microscopic treatment provides important information on the frequency dependence of the inverse Faraday effect

  8. Measurement of plasma conductivity using faraday rotation of submillimeter waves

    International Nuclear Information System (INIS)

    Kuzmenko, P.J.; Self, S.A.

    1983-01-01

    This paper examines the application of Faraday rotation to the measurement of electron combustion MHD plasmas. Details on the design of a working system are given, including the selection of operating wavelength. A theoretical comparison between the Faraday rotation technique and two-path interferometry shows Faraday rotation in its simplest form to be somewhat less sensitive to changes in electron concentration. This deficit can be balanced against greater immunity to vibration and thermal drift. Improved techniques of measuring the rotation angle promise greater sensitivity. A preliminary experiment has verified the technique

  9. Faraday waves in Bose-Einstein condensates

    International Nuclear Information System (INIS)

    Nicolin, Alexandru I.; Carretero-Gonzalez, R.; Kevrekidis, P. G.

    2007-01-01

    Motivated by recent experiments on Faraday waves in Bose-Einstein condensates we investigate both analytically and numerically the dynamics of cigar-shaped Bose-condensed gases subject to periodic modulation of the strength of the transverse confinement. We offer a fully analytical explanation of the observed parametric resonance, based on a Mathieu-type analysis of the non-polynomial Schroedinger equation. The theoretical prediction for the pattern periodicity versus the driving frequency is directly compared to the experimental data, yielding good qualitative and quantitative agreement between the two. These results are corroborated by direct numerical simulations of both the one-dimensional non-polynomial Schroedinger equation and of the fully three-dimensional Gross-Pitaevskii equation

  10. The Faraday effect revisited General theory

    CERN Document Server

    Cornean, H D; Pedersen, T G

    2005-01-01

    This paper is the first in a series revisiting the Faraday effect, or more generally, the theory of electronic quantum transport/optical response in bulk media in the presence of a constant magnetic field. The independent electron approximation is assumed. For free electrons, the transverse conductivity can be explicitly computed and coincides with the classical result. In the general case, using magnetic perturbation theory, the conductivity tensor is expanded in powers of the strength of the magnetic field $B$. Then the linear term in $B$ of this expansion is written down in terms of the zero magnetic field Green function and the zero field current operator. In the periodic case, the linear term in $B$ of the conductivity tensor is expressed in terms of zero magnetic field Bloch functions and energies. No derivatives with respect to the quasimomentum appear and thereby all ambiguities are removed, in contrast to earlier work.

  11. Faraday Discussions meeting Catalysis for Fuels.

    Science.gov (United States)

    Fischer, Nico; Kondrat, Simon A; Shozi, Mzamo

    2017-05-02

    Welcome to Africa was the motto when after more than 100 years the flag ship conference series of the Royal Society of Chemistry, the Faraday Discussions was hosted for the first time on the African Continent. Under the fitting topic 'Catalysis for Fuels' over 120 delegates followed the invitation by the conference chair Prof. Graham Hutchings FRS (Cardiff Catalysis Institute), his organizing committee and the co-organizing DST-NRF Centre of Excellence in Catalysis c*change (). In the presentations of 21 invited speakers and 59 posters, cutting edge research in the field of catalysis for fuels, designing new catalysts for synthetic fuels, hydrocarbon conversion in the production of synthetic fuels and novel photocatalysis was presented over the two-day meeting. The scene was set by the opening lecture of Prof. Enrique Iglesias (UC Berkeley) and wrapped-up with the concluding remarks by Philip Gibson (SASOL).

  12. Optical frequency comb Faraday rotation spectroscopy

    Science.gov (United States)

    Johansson, Alexandra C.; Westberg, Jonas; Wysocki, Gerard; Foltynowicz, Aleksandra

    2018-05-01

    We demonstrate optical frequency comb Faraday rotation spectroscopy (OFC-FRS) for broadband interference-free detection of paramagnetic species. The system is based on a femtosecond doubly resonant optical parametric oscillator and a fast-scanning Fourier transform spectrometer (FTS). The sample is placed in a DC magnetic field parallel to the light propagation. Efficient background suppression is implemented via switching the direction of the field on consecutive FTS scans and subtracting the consecutive spectra, which enables long-term averaging. In this first demonstration, we measure the entire Q- and R-branches of the fundamental band of nitric oxide in the 5.2-5.4 µm range and achieve good agreement with a theoretical model.

  13. The Inverse Faraday Effect In Plasma

    International Nuclear Information System (INIS)

    Eliezer, S.; Paiss, Y.; Horovitz, Y.; Henis, Z.

    1999-01-01

    The existence of axial magnetic field 1-3 induced by the interaction of circularly polarized laser light with plasma is reported. Axial magnetic fields from 500 Gauss up to 2.17 MegaGauss were measured using a Nd:YAG laser with a pulse duration of 7 ns for irradiance from 10 9 to 10 14 W/cm'2 accordingly. Up to 5 - 10 13 W/cm 2 , the results are in agreement with a nonlinear model of the inverse Faraday effect dominated by the ponderomotive force. Two diagnostic methods were used to measure the axial magnetic field. At low irradiance (10 9 - 10 1 '1 W/cm 2 ) the axial magnetic field induced by the circularly polarized laser light (CPLL) in a ferrite target was measured from the voltage signal induced by the magnetic field in an output coil. At higher irradiance the axial magnetic field was measured using the Faraday rotation diagnostic. The scaling law of the measured axial magnetic field B from the experiments performed with CPLL, in the intensities range of 10 9 - 10 13 W/cm 2 , is B ∼ I / 1/2 . At higher intensities of the order of 3 . 10 1 '4 W/cm 2 a sudden increase of the axial magnetic field beyond the above scaling law is observed in the experiments performed with CPLL. This study might have interesting implications in creating a mini tokamak configuration in laser produced plasmas, with intermediate plasma densities (10 22 cm 3 ) and confinement times (100 ns). Such an approach to fusion circumvents many of the complexities of inertial confinement fusion where very symmetric implosions using many laser beams are required. Intermediate fusion density may also overcome severe requirements of tokamak fusion

  14. Periodic reversal of magneto-optic Faraday rotation on uniaxial birefringence crystal with ultrathin magnetic films

    Directory of Open Access Journals (Sweden)

    C. W. Su

    2013-07-01

    Full Text Available An experimental approach of inclined incidence magneto-optic Faraday effect observed in the polar plane is applied. Three samples containing ferromagnetic cobalt ultrathin films on a semiconductor zinc oxide (0001 single crystal substrate with in-plane and out-of-plane anisotropy are evaluated. Through the fine adjustment of crossed polarizers in the magneto-optic effect measurement completely recorded the detail optical and magneto-optical responses from the birefringent crystal substrate and the magnetic film, especially for the signal induced from the substrate with uniaxial optical axis. The angle dependency of interference phenomena periodically from the optical and magneto-optical responses is attributed to the birefringence even in the absence of a magnetic field. The new type of observation finds that the transmission Faraday intensity in the oblique incidence includes a combination of polarization rotations, which results from optical compensation from the substrate and magneto-optical Faraday effects from the film. The samples grown at different rates and examined by this method exhibit magnetic structure discriminations. This result can be applied in the advanced polarized-light technologies to enhance the spatial resolution of magnetic surfaces with microstructural information under various magnetic field direction.

  15. Thiourea-Modified TiO2 Nanorods with Enhanced Photocatalytic Activity

    Directory of Open Access Journals (Sweden)

    Xiaofeng Wu

    2016-02-01

    Full Text Available Semiconductor TiO2 photocatalysis has attracted much attention due to its potential application in solving the problems of environmental pollution. In this paper, thiourea (CH4N2S modified anatase TiO2 nanorods were fabricated by calcination of the mixture of TiO2 nanorods and thiourea at 600 °C for 2 h. It was found that only N element was doped into the lattice of TiO2 nanorods. With increasing the weight ratio of thiourea to TiO2 (R from 0 to 8, the light-harvesting ability of the photocatalyst steady increases. Both the crystallization and photocatalytic activity of TiO2 nanorods increase first and then decrease with increase in R value, and R2 sample showed the highest crystallization and photocatalytic activity in degradation of Brilliant Red X3B (X3B and Rhodamine B (RhB dyes under visible light irradiation (λ > 420 nm. The increased visible-light photocatalytic activity of the prepared N-doped TiO2 nanorods is due to the synergistic effects of the enhanced crystallization, improved light-harvesting ability and reduced recombination rate of photo-generated electron-hole pairs. Note that the enhanced visible photocatalytic activity of N-doped nanorods is not based on the scarification of their UV photocatalytic activity.

  16. Enhanced antimicrobial properties, cytocompatibility, and corrosion resistance of plasma-modified biodegradable magnesium alloys.

    Science.gov (United States)

    Zhao, Ying; Jamesh, Mohammed Ibrahim; Li, Wing Kan; Wu, Guosong; Wang, Chenxi; Zheng, Yufeng; Yeung, Kelvin W K; Chu, Paul K

    2014-01-01

    Magnesium alloys are potential biodegradable materials and have received increasing attention due to their outstanding biological performance and mechanical properties. However, rapid degradation in the physiological environment and potential toxicity limit clinical applications. Recently, special magnesium-calcium (Mg-Ca) and magnesium-strontium (Mg-Sr) alloys with biocompatible chemical compositions have been reported, but the rapid degradation still does not meet clinical requirements. In order to improve the corrosion resistance, a rough, hydrophobic and ZrO(2)-containing surface film is fabricated on Mg-Ca and Mg-Sr alloys by dual zirconium and oxygen ion implantation. Weight loss measurements and electrochemical corrosion tests show that the corrosion rate of the Mg-Ca and Mg-Sr alloys is reduced appreciably after surface treatment. A systematic investigation of the in vitro cellular response and antibacterial capability of the modified binary magnesium alloys is performed. The amounts of adherent bacteria on the Zr-O-implanted and Zr-implanted samples diminish remarkably compared to the unimplanted control. In addition, significantly enhanced cell adhesion and proliferation are observed from the Zr-O-implanted sample. The results suggest that dual zirconium and oxygen ion implantation, which effectively enhances the corrosion resistance, in vitro biocompatibility and antimicrobial properties of Mg-Ca and Mg-Sr alloys, provides a simple and practical means to expedite clinical acceptance of biodegradable magnesium alloys. Copyright © 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

  17. Transferrin-Modified Nanoparticles for Photodynamic Therapy Enhance the Antitumor Efficacy of Hypocrellin A

    Directory of Open Access Journals (Sweden)

    Xi Lin

    2017-11-01

    Full Text Available Photodynamic therapy (PDT has emerged as a potent novel therapeutic modality that induces cell death through light-induced activation of photosensitizer. But some photosensitizers have characteristics of poor water-solubility and non-specific tissue distribution. These characteristics become main obstacles of PDT. In this paper, we synthesized a targeting drug delivery system (TDDS to improve the water-solubility of photosensitizer and enhance the ability of targeted TFR positive tumor cells. TDDS is a transferrin-modified Poly(D,L-Lactide-co-glycolide (PLGA and carboxymethyl chitosan (CMC nanoparticle loaded with a photosensitizer hypocrellin A (HA, named TF-HA-CMC-PLGA NPs. Morphology, size distribution, Fourier transform infrared (FT-IR spectra, encapsulation efficiency, and loading capacity of TF-HA-CMC-PLGA NPs were characterized. In vitro TF-HA-CMC-PLGA NPs presented weak dark cytotoxicity and significant photo-cytotoxicity with strong reactive oxygen species (ROS generation and apoptotic cancer cell death. In vivo photodynamic antitumor efficacy of TF-HA-CMC-PLGA NPs was investigated with an A549 (TFR positive tumor-bearing model in male athymic nude mice. TF-HA-CMC-PLGA NPs caused tumor delay with a remarkable tumor inhibition rate of 63% for 15 days. Extensive cell apoptosis in tumor tissue and slight side effects in normal organs were observed. The results indicated that TDDS has great potential to enhance PDT therapeutic efficacy.

  18. Enhanced Synaptic Transmission at the Squid Giant Synapse by Artificial Seawater Based on Physically Modified Saline

    Directory of Open Access Journals (Sweden)

    Soonwook eChoi

    2014-02-01

    Full Text Available Superfusion of the squid giant synapse with artificial seawater (ASW based on isotonic saline containing oxygen nanobubbles (RNS60 ASW generates an enhancement of synaptic transmission. This was determined by examining the postsynaptic response to single and repetitive presynaptic spike activation, spontaneous transmitter release, and presynaptic voltage clamp studies. In the presence of RNS60 ASW single presynaptic stimulation elicited larger postsynaptic potentials (PSP and more robust recovery from high frequency stimulation than in control ASW. Analysis of postsynaptic noise revealed an increase in spontaneous transmitter release with modified noise kinetics in RNS60 ASW. Presynaptic voltage clamp demonstrated an increased EPSP, without an increase in presynaptic ICa⁺⁺ amplitude during RNS60 ASW superfusion. Synaptic release enhancement reached stable maxima within 5 to 10 minutes of RNS60 ASW superfusion and was maintained for the entire recording time, up to one hour. Electronmicroscopic morphometry indicated a decrease in synaptic vesicle density and the number at active zones with an increase in the number of clathrin-coated vesicles and large endosome-like vesicles near junctional sites. Block of mitochondrial ATP synthesis by presynaptic injection of oligomycin reduced spontaneous release and prevented the synaptic noise increase seen in RNS60 ASW. After ATP block the number of vesicles at the active zone and clathrin-coated vesicles was reduced, with an increase in large vesicles. The possibility that RNS60 ASW acts by increasing mitochondrial ATP synthesis was tested by direct determination of ATP levels in both presynaptic and postsynaptic structures. This was implemented using luciferin/luciferase photon emission, which demonstrated a marked increase in ATP synthesis following RNS60 administration. It is concluded that RNS60 positively modulates synaptic transmission by up-regulating ATP synthesis, thus leading to synaptic

  19. Enhanced synaptic transmission at the squid giant synapse by artificial seawater based on physically modified saline

    Science.gov (United States)

    Choi, Soonwook; Yu, Eunah; Rabello, Guilherme; Merlo, Suelen; Zemmar, Ajmal; Walton, Kerry D.; Moreno, Herman; Moreira, Jorge E.; Sugimori, Mutsuyuki; Llinás, Rodolfo R.

    2014-01-01

    Superfusion of the squid giant synapse with artificial seawater (ASW) based on isotonic saline containing oxygen nanobubbles (RNS60 ASW) generates an enhancement of synaptic transmission. This was determined by examining the postsynaptic response to single and repetitive presynaptic spike activation, spontaneous transmitter release, and presynaptic voltage clamp studies. In the presence of RNS60 ASW single presynaptic stimulation elicited larger postsynaptic potentials (PSP) and more robust recovery from high frequency stimulation than in control ASW. Analysis of postsynaptic noise revealed an increase in spontaneous transmitter release with modified noise kinetics in RNS60 ASW. Presynaptic voltage clamp demonstrated an increased EPSP, without an increase in presynaptic ICa++ amplitude during RNS60 ASW superfusion. Synaptic release enhancement reached stable maxima within 5–10 min of RNS60 ASW superfusion and was maintained for the entire recording time, up to 1 h. Electronmicroscopic morphometry indicated a decrease in synaptic vesicle density and the number at active zones with an increase in the number of clathrin-coated vesicles (CCV) and large endosome-like vesicles near junctional sites. Block of mitochondrial ATP synthesis by presynaptic injection of oligomycin reduced spontaneous release and prevented the synaptic noise increase seen in RNS60 ASW. After ATP block the number of vesicles at the active zone and CCV was reduced, with an increase in large vesicles. The possibility that RNS60 ASW acts by increasing mitochondrial ATP synthesis was tested by direct determination of ATP levels in both presynaptic and postsynaptic structures. This was implemented using luciferin/luciferase photon emission, which demonstrated a marked increase in ATP synthesis following RNS60 administration. It is concluded that RNS60 positively modulates synaptic transmission by up-regulating ATP synthesis, thus leading to synaptic transmission enhancement. PMID:24575037

  20. Non-reciprocity of Faraday rotation in gyrotropic crystals

    OpenAIRE

    Vlokh R.; Adamenko D.

    2008-01-01

    It is shown that, under the conditions of coexisting natural optical activity and non-zero linear optical birefringence, reversal of the light wave vector sign can result in changing angle of Faraday rotation.

  1. The Faraday effect of natural and artificial ferritins.

    Science.gov (United States)

    Koralewski, M; Kłos, J W; Baranowski, M; Mitróová, Z; Kopčanský, P; Melníková, L; Okuda, M; Schwarzacher, W

    2012-09-07

    Measurements of the Faraday rotation at room temperature over the light wavelength range of 300-680 nm for horse spleen ferritin (HSF), magnetoferritin with different loading factors (LFs) and nanoscale magnetite and Fe(2)O(3) suspensions are reported. The Faraday rotation and the magnetization of the materials studied present similar magnetic field dependences and are characteristic of a superparamagnetic system. The dependence of the Faraday rotation on the magnetic field is described, excluding HSF and Fe(2)O(3), by a Langevin function with a log-normal distribution of the particle size allowing the core diameters of the substances studied to be calculated. It was found that the specific Verdet constant depends linearly on the LF. Differences in the Faraday rotation spectra and their magnetic field dependences allow discrimination between magnetoferritin with maghemite and magnetite cores which can be very useful in biomedicine.

  2. Faraday rotation measures in 20 AGN jets at parsec scale

    Directory of Open Access Journals (Sweden)

    Kravchenko Evgeniya V.

    2013-12-01

    Full Text Available We present multi wavelength parsec-scale Faraday rotation measure properties of twenty active galactic nuclei, observed with the Very Long Baseline Array simultaneously at 1.4, 1.6, 2.2, 2.4, 4.6, 5.0, 8.1, 8.4 and 15.4 GHz in the full polarization mode. For the observed sources we construct Faraday rotation measure and Faraday-corrected linear polarization maps. Direction of electrical field in the optically thick core regions confirms bimodal distribution. No significant changes of a Faraday rotation measure transverse to the jet direction are found in any of the observed sources. We propose a new magnetic field spatial geometry reconstruction method based on core shift measurements. This technique is applied to the quasar 1004+141. Results indicate an existence of a large scale poloidal magnetic field in the jet of 1004+141.

  3. The Faraday effect of natural and artificial ferritins

    International Nuclear Information System (INIS)

    Koralewski, M; Kłos, J W; Baranowski, M; Mitróová, Z; Kopčanský, P; Melníková, L; Okuda, M; Schwarzacher, W

    2012-01-01

    Measurements of the Faraday rotation at room temperature over the light wavelength range of 300–680 nm for horse spleen ferritin (HSF), magnetoferritin with different loading factors (LFs) and nanoscale magnetite and Fe 2 O 3 suspensions are reported. The Faraday rotation and the magnetization of the materials studied present similar magnetic field dependences and are characteristic of a superparamagnetic system. The dependence of the Faraday rotation on the magnetic field is described, excluding HSF and Fe 2 O 3 , by a Langevin function with a log-normal distribution of the particle size allowing the core diameters of the substances studied to be calculated. It was found that the specific Verdet constant depends linearly on the LF. Differences in the Faraday rotation spectra and their magnetic field dependences allow discrimination between magnetoferritin with maghemite and magnetite cores which can be very useful in biomedicine. (paper)

  4. One-Piece Faraday Generator: A Paradoxical Experiment from 1851

    Science.gov (United States)

    Crooks, M. J.; And Others

    1978-01-01

    Describes an experiment based on Faraday's one-piece generator, where the rotating disk is replaced by a cylindrical permanent magnet. Explains the apparent paradox that an observer in an inertial frame could measure his absolute velocity. (GA)

  5. Diagnose of large area electron beam with faraday cup

    International Nuclear Information System (INIS)

    Tang Ying; Qian Hang; Yi Aiping; Huang Xin; Yu Li; Liu Jingru; Su Jiancang; Ding Zhenjie; Ding Yongzhong; Yu Jianguo

    2008-01-01

    In the experiment of gas laser pumped by electron beam, large area uniform electron beam is important to generate high efficiency laser output. This paper introduces Faraday cup is used in the diagnose experiment on the uniformity of large area e-beam generated by SPG-200 pulsed power generator. Construction of Faraday cup and the results of calibration are presented in detail. The uniformity of velvet emission is given, and the results of experiment are analyzed. (authors)

  6. Reconfigurable Patch Antenna Radiations Using Plasma Faraday Shield Effect

    OpenAIRE

    Barro , Oumar Alassane; Himdi , Mohamed; Lafond , Olivier

    2016-01-01

    International audience; This letter presents a new reconfigurable antenna associated with a plasma Faraday shield effect. The Faraday shield effect is realized by using a fluorescent lamp. A patch antenna operating at 2.45 GHz is placed inside the lamp. The performance of the reconfigurable system is observed in terms of S11, gain and radiation patterns by simulation and measurement. It is shown that by switching ON the fluorescent lamp, the gain of the antenna decreases and the antenna syste...

  7. Faraday cup for analyzing multi-ion plasma

    International Nuclear Information System (INIS)

    Fujita, Takao

    1987-01-01

    A compact and convenient ion analyzer (a kind of a Faraday cup) is developed in order to analyze weakly ionized multi-ion plasmas. This Faraday cup consists of three mesh electrodes and a movable ion collector. With a negative gate pulse superimposed on the ion retarding bias, ions are analyzed by means of time-of-flight. The identification of ion species and measurements of ion density and ion temperature are studied. (author)

  8. Galactic foreground science: Faraday Tomography at low frequencies

    Science.gov (United States)

    Haverkorn, Marijke

    2018-05-01

    This contribution describes how low-frequency radio-spectropolarimetric imaging as done for Epoch of Reionization detection is used to investigate the nearby Galactic interstellar medium. The method of Faraday Tomography allows disentangling of every line of sight into various components in Faraday depth, which is a proxy for density-weighted magnetic field. I discuss instrumental biases and side effects of this method, and early results it has yielded.

  9. Polychaete richness and abundance enhanced in anthropogenically modified estuaries despite high concentrations of toxic contaminants.

    Directory of Open Access Journals (Sweden)

    Katherine A Dafforn

    Full Text Available Ecological communities are increasingly exposed to multiple chemical and physical stressors, but distinguishing anthropogenic impacts from other environmental drivers remains challenging. Rarely are multiple stressors investigated in replicated studies over large spatial scales (>1000 kms or supported with manipulations that are necessary to interpret ecological patterns. We measured the composition of sediment infaunal communities in relation to anthropogenic and natural stressors at multiple sites within seven estuaries. We observed increases in the richness and abundance of polychaete worms in heavily modified estuaries with severe metal contamination, but no changes in the diversity or abundance of other taxa. Estuaries in which toxic contaminants were elevated also showed evidence of organic enrichment. We hypothesised that the observed response of polychaetes was not a 'positive' response to toxic contamination or a reduction in biotic competition, but due to high levels of nutrients in heavily modified estuaries driving productivity in the water column and enriching the sediment over large spatial scales. We deployed defaunated field-collected sediments from the surveyed estuaries in a small scale experiment, but observed no effects of sediment characteristics (toxic or enriching. Furthermore, invertebrate recruitment instead reflected the low diversity and abundance observed during field surveys of this relatively 'pristine' estuary. This suggests that differences observed in the survey are not a direct consequence of sediment characteristics (even severe metal contamination but are related to parameters that covary with estuary modification such as enhanced productivity from nutrient inputs and the diversity of the local species pool. This has implications for the interpretation of diversity measures in large-scale monitoring studies in which the observed patterns may be strongly influenced by many factors that covary with anthropogenic

  10. Faraday rotation due to excitation of magnetoplasmons in graphene microribbons.

    Science.gov (United States)

    Tymchenko, Mykhailo; Nikitin, Alexey Yu; Martín-Moreno, Luis

    2013-11-26

    A single graphene sheet, when subjected to a perpendicular static magnetic field, provides a Faraday rotation that, per atomic layer, greatly surpasses that of any other known material. In continuous graphene, Faraday rotation originates from the cyclotron resonance of massless carriers, which allows dynamical tuning through either external electrostatic or magneto-static setting. Furthermore, the rotation direction can be controlled by changing the sign of the carriers in graphene, which can be done by means of an external electric field. However, despite these tuning possibilities, the requirement of large magnetic fields hinders the application of the Faraday effect in real devices, especially for frequencies higher than a few terahertz. In this work we demonstrate that large Faraday rotation can be achieved in arrays of graphene microribbons, through the excitation of the magnetoplasmons of individual ribbons, at larger frequencies than those dictated by the cyclotron resonance. In this way, for a given magnetic field and chemical potential, structuring graphene periodically can produce large Faraday rotation at larger frequencies than what would occur in a continuous graphene sheet. Alternatively, at a given frequency, graphene ribbons produce large Faraday rotation at much smaller magnetic fields than in continuous graphene.

  11. B polarization of the CMB from Faraday rotation

    International Nuclear Information System (INIS)

    Scoccola, Claudia; Harari, Diego; Mollerach, Silvia

    2004-01-01

    We study the effect of Faraday rotation due to a uniform magnetic field on the polarization of the cosmic microwave background. Scalar fluctuations give rise only to parity-even E-type polarization of the cosmic microwave background. However in the presence of a magnetic field, a nonvanishing parity-odd B-type polarization component is produced through Faraday rotation. We derive the exact solution for the E and B modes generated by scalar perturbations including the Faraday rotation effect of a uniform magnetic field, and evaluate their cross correlations with temperature anisotropies. We compute the angular autocorrelation function of the B-modes in the limit that the Faraday rotation is small. We find that uniform primordial magnetic fields of present strength around B 0 =10 -9 G rotate E-modes into B-modes with amplitude comparable to those due to the weak gravitational lensing effect at frequencies around ν=30 GHz. The strength of B-modes produced by Faraday rotation scales as B 0 /ν 2 . We evaluate also the depolarizing effect of Faraday rotation upon the cross correlation between temperature anisotropy and E-type polarization

  12. Enhanced attachment and growth of periodontal cells on glycine-arginine-glycine-aspartic modified chitosan membranes

    Directory of Open Access Journals (Sweden)

    Hsiao-Pei Tu

    2016-01-01

    Full Text Available Background: Chitosan, a polymeric carbohydrate derived from the exoskeleton of arthropod, has been suggested to be an excellent biomaterial for improving wound healing, especially for bones. To improve the periodontal cell attachment and growth, the cell adhesive peptide glycine-arginine-glycine-aspartic acid (Gly-Arg-Gly-Asp, GRGD grafted chitosan membrane was introduced in this study. Materials and Methods: Two types of commercial chitosan, three types of primary cultured cells, and two established cell lines were used. Human gingival and periodontal fibroblasts (hGF and hPDL, human root derived cell (hRDC, and rat calvaria bone cell (rCalB were cultured on the GRGD-fixed by ultraviolet light photochemical method on the chitosan membrane. With (3-[4,5-dimethylthiazol-2-yl]-5-[3-carboxymethoxyphenyl]-2-[4-sulfophenyl]-2H-tetrazolium assay and propidium iodine (PI staining, the cell adhesion and growth on GRGD-grafted chitosan were examined. Basal mRNA expressions of the receptors for GRGD, integrin αv (ITG αv and ITG β3, in the human gingival fibroblast cell line and mouse osteoblast cell line (MC3T3-E1 were examined with real-time polymerase chain reaction. Results: Because the cell adhesion/growth patterns on two chitosan membranes were similar, the GRGD modification was performed on one membrane (Primex only. For periodontal cells (hGFs, hPDLs, and hRDCs, the number of attached cells were increased on the membrane with the high concentration of GRGD than those on the membrane unmodified or modified with low concentration GRGD. For rCalBs cells, a different pattern was noted: GRGD modification did not enhance the calvaria cells attachment or growth. Moreover, mRNA expressions of ITG αv and β3 in AG09319 cells were significantly higher than those in MC3T3-E1 cells. Conclusions: With the limitation of this study, we suggested that GRGD-modified chitosan, especially at high concentration, could enhance the growth of various periodontal

  13. PROBING THE ROSETTE NEBULA STELLAR BUBBLE WITH FARADAY ROTATION

    Energy Technology Data Exchange (ETDEWEB)

    Savage, Allison H.; Spangler, Steven R.; Fischer, Patrick D. [Department of Physics and Astronomy, University of Iowa, Iowa City, IA 52242 (United States)

    2013-03-01

    We report the results of Faraday rotation measurements of 23 background radio sources whose lines of sight pass through or close to the Rosette Nebula. We made linear polarization measurements with the Karl G. Jansky Very Large Array (VLA) at frequencies of 4.4 GHz, 4.9 GHz, and 7.6 GHz. We find the background Galactic contribution to the rotation measure in this part of the sky to be +147 rad m{sup -2}. Sources whose lines of sight pass through the nebula have an excess rotation measure of 50-750 rad m{sup -2}, which we attribute to the plasma shell of the Rosette Nebula. We consider two simple plasma shell models and how they reproduce the magnitude and sign of the rotation measure, and its dependence on distance from the center of the nebula. These two models represent different modes of interaction of the Rosette Nebula star cluster with the surrounding interstellar medium. Both can reproduce the magnitude and spatial extent of the rotation measure enhancement, given plausible free parameters. We contend that the model based on a stellar bubble more closely reproduces the observed dependence of rotation measure on distance from the center of the nebula.

  14. Photoswitchable Faraday effect in EuS-Au nanosystems

    Energy Technology Data Exchange (ETDEWEB)

    Kawashima, Akira; Nakanishi, Takayuki; Kitagawa, Yuichi; Fushimi, Koji; Hasegawa, Yasuchika [Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, North-13 West-8, Kita-ku, 060-8628, Sapporo (Japan)

    2016-01-15

    Effective photoswitchable europium sulfide nanocrystals with gold nanoparticles using dithiol (DDT: 1,10-decanedithiol) joint molecules, EuS-Au nanosystems, are demonstrated. The TEM image indicates the formation of EuS-Au nanosystems composed of cube-shaped EuS nanocrystals and spherical Au nanoparticles. Under visible-light irradiation, a drastic change of absorption band of EuS-Au nanosystems at around 600 nm was observed. The Faraday effects of EuS-Au nanosystems were estimated using magnetic circular dichroism (MCD) measurements. The effective change of the MCD spectra of EuS-Au nanosystems under visible-light irradiation was successfully observed at around 670 nm for the first time. The effective reversible changes in MCD spectra with the alternative irradiation cycles of visible light (>440 nm) and dark are also presented. The decrease rate of rotation angle at 670 nm of EuS-Au nanosystems is larger than that of absorbance. These results indicate that the effective change of MCD spectra of EuS-Au nanosystems would be dominated not only by a drastic change of absorption band related to enhanced LSPR of Au nanoparticles but also by specific interaction between EuS and Au in nanosystem under irradiation. Illustration of photoswitch and TEM image of EuS-Au nanosystems. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  15. Faraday rotation echo spectroscopy and detection of quantum fluctuations.

    Science.gov (United States)

    Chen, Shao-Wen; Liu, Ren-Bao

    2014-04-15

    Central spin decoherence is useful for detecting many-body physics in environments and moreover, the spin echo control can remove the effects of static thermal fluctuations so that the quantum fluctuations are revealed. The central spin decoherence approach, however, is feasible only in some special configurations and often requires uniform coupling between the central spin and individual spins in the baths, which are very challenging in experiments. Here, by making analogue between central spin decoherence and depolarization of photons, we propose a scheme of Faraday rotation echo spectroscopy (FRES) for studying quantum fluctuations in interacting spin systems. The echo control of the photon polarization is realized by flipping the polarization with a birefringence crystal. The FRES, similar to spin echo in magnetic resonance spectroscopy, can suppress the effects of the static magnetic fluctuations and therefore reveal dynamical magnetic fluctuations. We apply the scheme to a rare-earth compound LiHoF4 and calculate the echo signal, which is related to the quantum fluctuations of the system. We observe enhanced signals at the phase boundary. The FRES should be useful for studying quantum fluctuations in a broad range of spin systems, including cold atoms, quantum dots, solid-state impurities, and transparent magnetic materials.

  16. Cognitive enhancers (Nootropics). Part 3: drugs interacting with targets other than receptors or enzymes. Disease-modifying drugs. Update 2014.

    Science.gov (United States)

    Froestl, Wolfgang; Pfeifer, Andrea; Muhs, Andreas

    2014-01-01

    Scientists working in the field of Alzheimer's disease and, in particular, cognitive enhancers, are very productive. The review "Drugs interacting with Targets other than Receptors or Enzymes. Disease-modifying Drugs" was accepted in October 2012. In the last 20 months, new targets for the potential treatment of Alzheimer's disease were identified. Enormous progress was realized in the pharmacological characterization of natural products with cognitive enhancing properties. This review covers the evolution of research in this field through May 2014.

  17. Enhanced transdermal bioavailability of testosterone propionate via surfactant-modified ethosomes

    Directory of Open Access Journals (Sweden)

    Meng S

    2013-08-01

    Full Text Available Shu Meng,1 Zaixing Chen,2 Liqun Yang,1 Wei Zhang,1 Danhua Liu,1 Jing Guo,1 Yanmin Guan,1 Jianxin Li11Liaoning Research Institute of Family Planning, Shenyang, Liaoning Province, People's Republic of China; 2School of Pharmacy, China Medical University, Shenyang, Liaoning Province, People's Republic of ChinaAbstract: The current investigation aimed to evaluate the transdermal potential of novel testosterone propionate (TP ethosomes and liposomes prepared by surfactant modification. The effect of hexadecyl trimethyl ammonium bromide and cremophor EL-35 on the particle size and zeta potential of the prepared vesicles was investigated. The entrapment efficiency and stability, as well as in vitro and in vivo skin permeation, were studied with the various techniques, such as differential scanning calorimetry, confocal laser scanning microscopy, transmission electron microscopy, dynamic light scattering, and so on. The results indicated that the ethosomes were defined as spherical, unilamellar structures with low polydispersity (0.100 ± 0.015 and nanometric size (156.5 ± 3.5 nm. The entrapment efficiency of TP in ethosomal and liposomal carriers was 92.7% ± 3.7% and 64.7% ± 2.1%, respectively. The stability profile of the prepared TP ethosomal system assessed for 120 days revealed very low aggregation and very low growth in vesicular size. TP ethosomes also provided an enhanced transdermal flux of 37.85 ± 2.8 µg/cm2/hour and a decreased lag time of 0.18 hours across mouse skin. The skin permeation efficiency of the TP ethosomes as further assessed by confocal laser scanning microscopy revealed enhanced permeation of rhodamine red-loaded formulations to the deeper layers of the skin (260 µm than that of the liposomal formation (120 µm.Keywords: testosterone propionate, surfactant-modified ethosomes, liposomes, confocal laser scanning microscopy

  18. Immunotherapy with Dendritic Cells Modified with Tumor-Associated Antigen Gene Demonstrates Enhanced Antitumor Effect Against Lung Cancer

    Directory of Open Access Journals (Sweden)

    Tao Jiang

    2017-04-01

    Full Text Available BACKGROUND: Immunotherapy using dendritic cell (DC vaccine has the potential to overcome the bottleneck of cancer therapy. METHODS: We engineered Lewis lung cancer cells (LLCs and bone marrow–derived DCs to express tumor-associated antigen (TAA ovalbumin (OVA via lentiviral vector plasmid encoding OVA gene. We then tested the antitumor effect of modified DCs both in vitro and in vivo. RESULTS: The results demonstrated that in vitro modified DCs could dramatically enhance T-cell proliferation (P < .01 and killing of LLCs than control groups (P < .05. Moreover, modified DCs could reduce tumor size and prolong the survival of LLC tumor-bearing mice than control groups (P < .01 and P < .01, respectively. Mechanistically, modified DCs demonstrated enhanced homing to T-cell–rich compartments and triggered more naive T cells to become cytotoxic T lymphocytes, which exhibited significant infiltration into the tumors. Interestingly, modified DCs also markedly reduced tumor cells harboring stem cell markers in mice (P < .05, suggesting the potential role on cancer stem-like cells. CONCLUSION: These findings suggested that DCs bioengineered with TAA could enhance antitumor effect and therefore represent a novel anticancer strategy that is worth further exploration.

  19. Enhanced forward osmosis from chemically modified polybenzimidazole (PBI) nanofiltration hollow fiber membranes with a thin wall

    KAUST Repository

    Wang, Kai Yu; Yang, Qian; Chung, Tai-Shung; Rajagopalan, Raj

    2009-01-01

    To develop high-flux and high-rejection forward osmosis (FO) membranes for water reuses and seawater desalination, we have fabricated polybenzimidazole (PBI) nanofiltration (NF) hollow fiber membranes with a thin wall and a desired pore size via non-solvent induced phase inversion and chemically cross-linking modification. The cross-linking by p-xylylene dichloride can finely tune the mean pore size and enhance the salt selectivity. High water permeation flux and improved salt selectivity for water reuses were achieved by using the 2-h modified PBI NF membrane which has a narrow pore size distribution. Cross-linking at a longer time produces even a lower salt permeation flux potentially suitable for desalination but at the expense of permeation flux due to tightened pore sizes. It is found that draw solution concentration and membrane orientations are main factors determining the water permeation flux. In addition, effects of membrane morphology and operation conditions on water and salt transport through membrane have been investigated. © 2008 Elsevier Ltd. All rights reserved.

  20. The Enhanced Photo-Electrochemical Detection of Uric Acid on Au Nanoparticles Modified Glassy Carbon Electrode

    Science.gov (United States)

    Shi, Yuting; Wang, Jin; Li, Shumin; Yan, Bo; Xu, Hui; Zhang, Ke; Du, Yukou

    2017-07-01

    In this work, a sensitive and novel method for determining uric acid (UA) has been developed, in which the glassy carbon electrode (GCE) was modified with electrodeposition Au nanoparticles and used to monitor the concentration of UA with the assistant of visible light illumination. The morphology of the Au nanoparticles deposited on GCE surface were characterized by scanning electron microscope (SEM) and the nanoparticles were found to be well-dispersed spheres with the average diameter approaching 26.1 nm. A series of cyclic voltammetry (CV) and differential pulse voltammetry (DPV) measurements have revealed that the introduction of visible light can greatly enhance both the strength and stability of response current due to the surface plasmon resonance (SPR). Specifically, the DPV showed a linear relationship between peak current and UA concentration in the range of 2.8 to 57.5 μM with the equation of I pa (μA) = 0.0121 c UA (μM) + 0.3122 ( R 2 = 0.9987). Herein, the visible light illuminated Au/GCE possesses a potential to be a sensitive electrochemical sensor in the future.

  1. Enhanced transduction and replication of RGD-fiber modified adenovirus in primary T cells.

    Directory of Open Access Journals (Sweden)

    Sadhak Sengupta

    2011-03-01

    Full Text Available Adenoviruses are often used as vehicles to mediate gene delivery for therapeutic purposes, but their research scope in hematological cells remains limited due to a narrow choice of host cells that express the adenoviral receptor (CAR. T cells, which are attractive targets for gene therapy of numerous diseases, remain resistant to adenoviral infection because of the absence of CAR expression. Here, we demonstrate that this resistance can be overcome when murine or human T cells are transduced with an adenovirus incorporating the RGD-fiber modification (Ad-RGD.A luciferase-expressing replication-deficient Ad-RGD infected 3-fold higher number of activated primary T cells than an adenovirus lacking the RGD-fiber modification in vitro. Infection with replication-competent Ad-RGD virus also caused increased cell cycling, higher E1A copy number and enriched hexon antigen expression in both human and murine T cells. Transduction with oncolytic Ad-RGD also resulted in higher titers of progeny virus and enhanced the killing of T cells. In vivo, 35-45% of splenic T cells were transduced by Ad-RGD.Collectively, our results prove that a fiber modified Ad-RGD successfully transduces and replicates in primary T cells of both murine and human origin.

  2. Oxygen-plasma-modified biomimetic nanofibrous scaffolds for enhanced compatibility of cardiovascular implants

    Directory of Open Access Journals (Sweden)

    Anna Maria Pappa

    2015-01-01

    Full Text Available Electrospun nanofibrous scaffolds have been extensively used in several biomedical applications for tissue engineering due to their morphological resemblance to the extracellular matrix (ECM. Especially, there is a need for the cardiovascular implants to exhibit a nanostructured surface that mimics the native endothelium in order to promote endothelialization and to reduce the complications of thrombosis and implant failure. Thus, we herein fabricated poly-ε-caprolactone (PCL electrospun nanofibrous scaffolds, to serve as coatings for cardiovascular implants and guide tissue regeneration. Oxygen plasma treatment was applied in order to modify the surface chemistry of the scaffold and its effect on cell attachment and growth was evaluated. The conditions of the surface modification were properly adjusted in order to define those conditions of the treatment that result in surfaces favorable for cell growth, while maintaining morphological integrity and mechanical behavior. Goniometry (contact angle measurements, scanning electron microscopy (SEM, atomic force microscopy (AFM, and X-ray photoelectron spectroscopy (XPS measurements were used to evaluate the morphological and chemical changes induced by the plasma treatment. Moreover, depth-sensing nanoindentation was performed to study the resistance of the plasma-treated scaffolds to plastic deformation. Lastly, the cell studies indicated that all scaffolds were cytocompatible, with the plasma-treated ones expressing a more pronounced cell viability and adhesion. All the above findings demonstrate the great potential of these biomimetic tissue-engineering constructs as efficient coatings for enhanced compatibility of cardiovascular implants.

  3. Quercetin-Based Modified Porous Silicon Nanoparticles for Enhanced Inhibition of Doxorubicin-Resistant Cancer Cells.

    Science.gov (United States)

    Liu, Zehua; Balasubramanian, Vimalkumar; Bhat, Chinmay; Vahermo, Mikko; Mäkilä, Ermei; Kemell, Marianna; Fontana, Flavia; Janoniene, Agne; Petrikaite, Vilma; Salonen, Jarno; Yli-Kauhaluoma, Jari; Hirvonen, Jouni; Zhang, Hongbo; Santos, Hélder A

    2017-02-01

    One of the most challenging obstacles in nanoparticle's surface modification is to achieve the concept that one ligand can accomplish multiple purposes. Upon such consideration, 3-aminopropoxy-linked quercetin (AmQu), a derivative of a natural flavonoid inspired by the structure of dopamine, is designed and subsequently used to modify the surface of thermally hydrocarbonized porous silicon (PSi) nanoparticles. This nanosystem inherits several advanced properties in a single carrier, including promoted anticancer efficiency, multiple drug resistance (MDR) reversing, stimuli-responsive drug release, drug release monitoring, and enhanced particle-cell interactions. The anticancer drug doxorubicin (DOX) is efficiently loaded into this nanosystem and released in a pH-dependent manner. AmQu also effectively quenches the fluorescence of the loaded DOX, thereby allowing the use of the nanosystem for monitoring the intracellular drug release. Furthermore, a synergistic effect with the presence of AmQu is observed in both normal MCF-7 and DOX-resistant MCF-7 breast cancer cells. Due to the similar structure as dopamine, AmQu may facilitate both the interaction and internalization of PSi into the cells. Overall, this PSi-based platform exhibits remarkable superiority in both multifunctionality and anticancer efficiency, making this nanovector a promising system for anti-MDR cancer treatment. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Enhanced forward osmosis from chemically modified polybenzimidazole (PBI) nanofiltration hollow fiber membranes with a thin wall

    KAUST Repository

    Wang, Kai Yu

    2009-04-01

    To develop high-flux and high-rejection forward osmosis (FO) membranes for water reuses and seawater desalination, we have fabricated polybenzimidazole (PBI) nanofiltration (NF) hollow fiber membranes with a thin wall and a desired pore size via non-solvent induced phase inversion and chemically cross-linking modification. The cross-linking by p-xylylene dichloride can finely tune the mean pore size and enhance the salt selectivity. High water permeation flux and improved salt selectivity for water reuses were achieved by using the 2-h modified PBI NF membrane which has a narrow pore size distribution. Cross-linking at a longer time produces even a lower salt permeation flux potentially suitable for desalination but at the expense of permeation flux due to tightened pore sizes. It is found that draw solution concentration and membrane orientations are main factors determining the water permeation flux. In addition, effects of membrane morphology and operation conditions on water and salt transport through membrane have been investigated. © 2008 Elsevier Ltd. All rights reserved.

  5. Melamine modified P25 with heating method and enhanced the photocatalytic activity on degradation of ciprofloxacin

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Huiqin [School of Materials Science & Engineering, Jiangsu University, Zhenjiang 212013 (China); Li, Jinze; Ma, Changchang [School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China); Guan, Qingfeng [School of Materials Science & Engineering, Jiangsu University, Zhenjiang 212013 (China); Lu, Ziyang [School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China); Huo, Pengwei, E-mail: huopw1@163.com [School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China); Yan, Yongsheng [School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China)

    2015-02-28

    Highlights: • We demonstrated the as-prepared photocatalyst of g-C{sub 3}N{sub 4}-TiO{sub 2} with the commercial TiO{sub 2} (P25) composited melamine under ball milling and calcined. • The enhanced photocatalytic performance could be mainly attributed to the suitable band gap structure with heterojunction of CN-P25. • The possible photocatalytic mechanism of g-C{sub 3}N{sub 4}/P25 under visible light irradiation is proposed. - Abstract: The graphitic carbon nitride (g-C{sub 3}N{sub 4}), as one photocatalyst which possess the suitable band gap, is better for modified TiO{sub 2} and enhanced photocatalytic degradation of organic pollutants. In this work, the g-C{sub 3}N{sub 4}/TiO{sub 2} were successfully prepared via directly calcined the mixture of melamine and P25. The as-prepared g-C{sub 3}N{sub 4}/TiO{sub 2} photocatalysts were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM) and high resolution electron microscopy (HRTEM), Raman and Fourier transform-infrared spectroscopy (FT-IR). The photocatalytic performances of g-C{sub 3}N{sub 4}/TiO{sub 2} composites were investigated by degradation of ciprofloxacin. The results showed that the g-C{sub 3}N{sub 4} and P25 were successfully composited, and the bond of C–N was well formed, the calcined temperature for as-prepared photocatalysts and the ratio of melamine and P25 were important to the degradation rate of ciprofloxacin. When the mixture of melamine and P25 with 1:2, and calcined temperature at 600 °C, the degradation rate of ciprofloxacin could reach 95% in 60 min. The enhanced photocatalytic performances could be mainly attributed to the suitable band gap structure with heterojunction of CN-P25. Finally, the possible transferred processes of photoelectrons and photoholes were proposed.

  6. Polyethylene Glycol Modified, Cross-Linked Starch Coated Iron Oxide Nanoparticles for Enhanced Magnetic Tumor Targeting

    Science.gov (United States)

    Cole, Adam J.; David, Allan E.; Wang, Jianxin; Galbán, Craig J.; Hill, Hannah L.; Yang, Victor C.

    2010-01-01

    While successful magnetic tumor targeting of iron oxide nanoparticles has been achieved in a number of models, the rapid blood clearance of magnetically suitable particles by the reticuloendothelial system (RES) limits their availability for targeting. This work aimed to develop a long-circulating magnetic iron oxide nanoparticle (MNP) platform capable of sustained tumor exposure via the circulation and, thus, enhanced magnetic tumor targeting. Aminated, cross-linked starch (DN) and aminosilane (A) coated MNPs were successfully modified with 5 kDa (A5, D5) or 20 kDa (A20, D20) polyethylene glycol (PEG) chains using simple N-Hydroxysuccinimide (NHS) chemistry and characterized. Identical PEG-weight analogues between platforms (A5 & D5, A20 & D20) were similar in size (140–190 nm) and relative PEG labeling (1.5% of surface amines – A5/D5, 0.4% – A20/D20), with all PEG-MNPs possessing magnetization properties suitable for magnetic targeting. Candidate PEG-MNPs were studied in RES simulations in vitro to predict long-circulating character. D5 and D20 performed best showing sustained size stability in cell culture medium at 37°C and 7 (D20) to 10 (D5) fold less uptake in RAW264.7 macrophages when compared to previously targeted, unmodified starch MNPs (D). Observations in vitro were validated in vivo, with D5 (7.29 hr) and D20 (11.75 hr) showing much longer half-lives than D (0.12 hr). Improved plasma stability enhanced tumor MNP exposure 100 (D5) to 150 (D20) fold as measured by plasma AUC0-∞ Sustained tumor exposure over 24 hours was visually confirmed in a 9L-glioma rat model (12 mg Fe/kg) using magnetic resonance imaging (MRI). Findings indicate that both D5 and D20 are promising MNP platforms for enhanced magnetic tumor targeting, warranting further study in tumor models. PMID:21176955

  7. FARADAY ROTATION: EFFECT OF MAGNETIC FIELD REVERSALS

    International Nuclear Information System (INIS)

    Melrose, D. B.

    2010-01-01

    The standard formula for the rotation measure (RM), which determines the position angle, ψ = RMλ 2 , due to Faraday rotation, includes contributions only from the portions of the ray path where the natural modes of the plasma are circularly polarized. In small regions of the ray path where the projection of the magnetic field on the ray path reverses sign (called QT regions) the modes are nearly linearly polarized. The neglect of QT regions in estimating RM is not well justified at frequencies below a transition frequency where mode coupling changes from strong to weak. By integrating the polarization transfer equation across a QT region in the latter limit, I estimate the additional contribution Δψ needed to correct this omission. In contrast with a result proposed by Broderick and Blandford, Δψ is small and probably unobservable. I identify a new source of circular polarization, due to mode coupling in an asymmetric QT region. I also identify a new circular-polarization-dependent correction to the dispersion measure at low frequencies.

  8. FARADAY ROTATION: EFFECT OF MAGNETIC FIELD REVERSALS

    Energy Technology Data Exchange (ETDEWEB)

    Melrose, D B [SIfA, School of Physics, University of Sydney, NSW 2006 (Australia)

    2010-12-20

    The standard formula for the rotation measure (RM), which determines the position angle, {psi} = RM{lambda}{sup 2}, due to Faraday rotation, includes contributions only from the portions of the ray path where the natural modes of the plasma are circularly polarized. In small regions of the ray path where the projection of the magnetic field on the ray path reverses sign (called QT regions) the modes are nearly linearly polarized. The neglect of QT regions in estimating RM is not well justified at frequencies below a transition frequency where mode coupling changes from strong to weak. By integrating the polarization transfer equation across a QT region in the latter limit, I estimate the additional contribution {Delta}{psi} needed to correct this omission. In contrast with a result proposed by Broderick and Blandford, {Delta}{psi} is small and probably unobservable. I identify a new source of circular polarization, due to mode coupling in an asymmetric QT region. I also identify a new circular-polarization-dependent correction to the dispersion measure at low frequencies.

  9. Ultrafast terahertz Faraday rotation in graphene

    Energy Technology Data Exchange (ETDEWEB)

    Heyman, J. N.; Foo Kune, R. F.; Alebachew, B. A.; Nguyen, M. D. [Macalester College, Saint Paul, Minnesota 55105 (United States); Robinson, J. T. [Naval Research Laboratory, Washington, DC 20375 (United States)

    2014-12-07

    Terahertz (THz) Faraday rotation measurements were performed to investigate carrier dynamics in p-type Chemical vapor deposition (CVD) graphene. We used static and time-resolved polarization-sensitive THz transmission measurements in a magnetic field to probe free carriers in GaAs, InP, and Graphene. Static measurements probe the equilibrium carrier density and momentum scattering rate. Time-resolved (optical pump/THz probe) measurements probe the change in these quantities following photoexcitation. In a typical CVD graphene sample, we found that 0.5 ps following photoexcitation with 1 × 10{sup 13} photons/cm{sup 2} pulses at 800 nm the effective hole scattering time decreased from 37 fs to 34.5 fs, while the carrier concentration increased from 2.0 × 10{sup 12} cm{sup −2} to 2.04 × 10{sup 12} cm{sup −2}, leading to a transient decrease in the conductivity of the film.

  10. 1/f Noise Inside a Faraday Cage

    Science.gov (United States)

    Handel, Peter H.; George, Thomas F.

    2009-04-01

    We show that quantum 1/f noise does not have a lower frequency limit given by the lowest free electromagnetic field mode in a Faraday cage, even in an ideal cage. Indeed, quantum 1/f noise comes from the infrared-divergent coupling of the field with the charges, in their joint nonlinear system, where the charges cause the field that reacts back on the charges, and so on. This low-frequency limitation is thus not applicable for the nonlinear system of matter and field in interaction. Indeed, this nonlinear system is governed by Newton's laws, Maxwell's equations, in general also by the diffusion equations for particles and heat, or reaction kinetics given by quantum matrix elements. Nevertheless, all the other quantities can be eliminated in principle, resulting in highly nonlinear integro-differential equations for the electromagnetic field only, which no longer yield a fundamental frequency. Alternatively, we may describe this through the presence of an infinite system of subharmonics. We show how this was proven early in the classical and quantum domains, adding new insight.

  11. 1/f Noise Inside a Faraday Cage

    International Nuclear Information System (INIS)

    Handel, Peter H.; George, Thomas F.

    2009-01-01

    We show that quantum 1/f noise does not have a lower frequency limit given by the lowest free electromagnetic field mode in a Faraday cage, even in an ideal cage. Indeed, quantum 1/f noise comes from the infrared-divergent coupling of the field with the charges, in their joint nonlinear system, where the charges cause the field that reacts back on the charges, and so on. This low-frequency limitation is thus not applicable for the nonlinear system of matter and field in interaction. Indeed, this nonlinear system is governed by Newton's laws, Maxwell's equations, in general also by the diffusion equations for particles and heat, or reaction kinetics given by quantum matrix elements. Nevertheless, all the other quantities can be eliminated in principle, resulting in highly nonlinear integro-differential equations for the electromagnetic field only, which no longer yield a fundamental frequency. Alternatively, we may describe this through the presence of an infinite system of subharmonics. We show how this was proven early in the classical and quantum domains, adding new insight.

  12. Performance enhancement of modified solar still using water sprinkler: An experimental approach

    OpenAIRE

    Gupta, Bhupendra; Sharma, Raghvendra; Shankar, Prem; Baredar, Prashant

    2016-01-01

    In this communication, existing design of single slope solar still has been modified, developed and tested. The modifications in conventional single slope solar still include (i) inside walls painted with white colour and (ii) attachment of water sprinkler with constant water flow rate of 0.0001 kg/s on the glass cover. The performance of modified single slope solar still has been evaluated and compared with conventional solar still. Experiments have been carried out on both modified and conv...

  13. Chemically modified carbon nanotubes as material enhanced laser desorption ionisation (MELDI) material in protein profiling

    International Nuclear Information System (INIS)

    Najam-ul-Haq, M.; Rainer, M.; Schwarzenauer, T.; Huck, C.W.; Bonn, G.K.

    2006-01-01

    Biomarkers play a potential role in the early detection and diagnosis of a disease. Our aim is to derivatize carbon nanotubes for exploration of the differences in human body fluids e.g. serum, through matrix assisted laser desorption ionisation/time of flight mass spectrometry (MALDI/TOF-MS) that can be related to disease and subsequently to be employed in the biomarker discovery process. This application we termed as the material enhanced laser desorption ionisation (MELDI). The versatility of this technology is meant to increase the amount of information from biological samples on the protein level, which will have a major impact to serve the cause of diagnostic markers. Serum peptides and proteins are immobilized on derivatized carbon nanotubes, which function as binding material. Protein-loaded suspension is placed on a stainless steel target or buckypaper on aluminum target for direct analysis with MALDI-MS. The elution method to wash the bound proteins from carbon nanotubes was employed to compare with the direct analysis procedure. Elution is carried out by MALDI matrix solution to get them out of the entangled nanotubes, which are difficult to desorb by laser due to the complex nanotube structures. The advantage of these optimized methods compared to the conventional screening methods is the improved sensitivity, selectivity and the short analysis time without prior albumin and immunoglobulin depletion. The comparison of similarly modified diamond and carbon nanotubes exhibit differences in their nature to bind the proteins out of serum due to the differences in their physical characteristics. Infrared (IR) spectroscopy provided hint for the presence of tertiary amine peak at the crucial chemical step of iminodiacetic acid addition to acid chloride functionality on carbon nanotubes. Atomic absorption spectroscopy (AAS) was utilized to quantitatively measure the copper capacity of these derivatized carbon nanotubes which is a direct measure of capacity of

  14. Palladium nanoparticles decorated on activated fullerene modified screen printed carbon electrode for enhanced electrochemical sensing of dopamine.

    Science.gov (United States)

    Palanisamy, Selvakumar; Thirumalraj, Balamurugan; Chen, Shen-Ming; Ali, M Ajmal; Al-Hemaid, Fahad M A

    2015-06-15

    In the present work, an enhanced electrochemical sensor for dopamine (DA) was developed based on palladium nanoparticles decorated activated fullerene-C60 (AC60/PdNPs) composite modified screen printed carbon electrode (SPCE). The scanning electron microscopy and elemental analysis confirmed the formation of PdNPs on AC60. The fabricated AC60/PdNPs composite modified electrode exhibited an enhanced electrochemical response to DA with a lower oxidation potential than that of SPCE modified with PdNPs and C60, indicating the excellent electrooxidation behavior of the AC60/PdNPs composite modified electrode. The electrochemical studies confirmed that the electrooxidation of DA at the composite electrode is a diffusion controlled electrochemical process. The differential pulse voltammetry was employed for the determination of DA; under optimum conditions, the electrochemical oxidation signal of DA increased linearly at the AC60/PdNPs composite from 0.35 to 133.35 μM. The limit of detection was found as 0.056 μM with a sensitivity of 4.23 μA μM(-1) cm(-2). The good recovery of DA in the DA injection samples further revealed the good practicality of AC60/PdNPs modified electrode. Copyright © 2015 Elsevier Inc. All rights reserved.

  15. Enhancement of light absorption by blood to Nd:YAG laser using PEG-modified gold nanorods.

    Science.gov (United States)

    Xing, Linzhuang; Li, Dong; Chen, Bin; Dai, Yuze; Wu, Wenjuan; Wang, Guoxiang

    2016-10-01

    On the basis of the principle of selective photothermolysis, laser therapy has been the most effective treatment strategy for Port-wine stains (PWSs) caused by the expansion of dermal capillaries. Neodymium:Yttrium Aluminum Garnet (Nd:YAG) laser at 1064 nm wavelength has great potential for deeply buried PWS, although its application is limited because of its weak absorption by blood. The purpose of this study is to investigate the effect of PEG-modified gold nanorods (NRs) on the blood absorption enhancement for Nd:YAG laser. PEG-modified gold nanorods (NRs) were synthesized via the seeded growth method. Then, the effect of PEG-modified gold NRs on blood light absorbance was investigated through adding different concentration of PEG-modified gold NRs to 1 ml of blood at room temperature. Finally, the optical properties of whole mice blood with or without PEG-modified gold NRs under slow heating were investigated. The average length and width of PEG-modified gold NRs are 79.5 ± 10.5 and 13.5 ± 0.9 nm, respectively, with the aspect ratio of 5.89, and a strong absorption peak exists at ∼1050 nm in the near-infrared range. A linear correlation between the blood absorbance at 1064 nm and the amount of PEG-modified gold NRs was obtained. The absorbance at 1064 nm increased 17.6, 33.0, 48.3, and 65.4 times when 0.4, 0.8, 1.2, and 1.6 mg of PEG-modified gold NRs was added to 1 ml of blood at room temperature, respectively. After adding 0.8 mg of PEG-modified gold NRs to 1 ml of blood, blood absorbance at 1064 nm at different temperatures increased by an average of 24.0 times. After intravenously injecting PEG-modified gold NRs (0.87 mg/ml) into Sprague-Dawley mice, the blood absorbance at 1064 nm increased from 0.014 to 0.5. Our findings suggest that PEG-modified gold NRs injection is an efficient way to enhance light absorption by blood to Nd:YAG laser. Lasers Surg. Med. 48:790-803, 2016. © 2016 Wiley Periodicals, Inc. © 2016 Wiley

  16. Improving the lean muscle color of dark-cutting beef by aging, antioxidant-enhancement, and modified atmospheric packaging.

    Science.gov (United States)

    Wills, K M; Mitacek, R M; Mafi, G G; VanOverbeke, D L; Jaroni, D; Jadeja, R; Ramanathan, R

    2017-12-01

    The objective was to evaluate the effects of wet-aging, rosemary-enhancement, and modified atmospheric packaging on the color of dark-cutting beef during simulated retail display. No-roll dark-cutting strip loins ( = 12; pH > 6.0) were selected from a commercial packing plant within 3 d postharvest. Using a balanced incomplete block design, dark-cutting loins were sectioned in half, and assigned to 1 of 3 aging periods: 7, 14, or 21 d. After respective aging, each aged section was divided into 3 equal parts, and randomly assigned to 1 of 3 enhancement treatments: nonenhanced dark-cutting, dark-cutter enhanced with 0.1% rosemary, and dark-cutter enhanced with 0.2% rosemary. Following enhancement, steaks were randomly assigned to 1 of 3 packaging treatments: high-oxygen modified atmospheric packaging (HiOx-MAP; 80% O and 20% CO), carbon monoxide modified atmospheric packaging (CO-MAP; 0.4% CO, 69.6% N, and 30% CO), and polyvinyl chloride overwrap (PVC; 20% O). Instrumental and visual color measurements were recorded during 5 d simulated retail display. Lipid oxidation was determined utilizing the thiobarbituric acid reactive substances (TBARS) method. There was a significant packaging × enhancement × display time interaction for values and chroma ( 0.001). On d 0 of display, dark-cutting steaks enhanced with 0.1% and 0.2% rosemary and packaged in HiOx-MAP had greater ( 0.001) values and chroma than other dark-cutting packaging/enhancement treatments. A significant packaging × enhancement × display time interaction resulted for values ( 0.001). Dark-cutting steaks enhanced with 0.2% rosemary and packaged in HiOx-MAP was lighter ( 0.001; greater values) than other dark-cutting treatments on d 5 of display. There were no differences ( 0.34) in discoloration scores on d 5 among different dark-cutting treatments when steaks were packaged in HiOx- and CO-MAP. There was an aging period × enhancement × packaging interaction ( cutting steaks enhanced with 0.2% rosemary

  17. Faraday instability in a near-critical fluid under weightlessness.

    Science.gov (United States)

    Gandikota, G; Chatain, D; Amiroudine, S; Lyubimova, T; Beysens, D

    2014-01-01

    Experiments on near-critical hydrogen have been conducted under magnetic compensation of gravity to investigate the Faraday instability that arises at the liquid-vapor interface under zero-gravity conditions. We investigated such instability in the absence of stabilizing gravity. Under such conditions, vibration orients the interface and can destabilize it. The experiments confirm the existence of Faraday waves and demonstrate a transition from a square to a line pattern close to the critical point. They also show a transition very close to the critical point from Faraday to periodic layering of the vapor-liquid interface perpendicular to vibration. It was seen that the Faraday wave instability is favored when the liquid-vapor density difference is large enough (fluid far from the critical point), whereas periodic layering predominates for small difference in the liquid and vapor densities (close to the critical point). It was observed for the Faraday wave instability that the wavelength of the instability decreases as one approaches the critical point. The experimental results demonstrate good agreement to the dispersion relation for zero gravity except for temperatures very close to the critical point where a transition from a square pattern to a line pattern is detected, similarly to what is observed under 1g conditions.

  18. Accomplishing equilibrium in ALSEP: demonstrations of modified process chemistry on 3-D printed enhanced annular centrifugal contactors

    Energy Technology Data Exchange (ETDEWEB)

    Brown, M.A.; Wardle, K.E.; Gelis, A.V. [Nuclear Engineering Division, Argonne National Laboratory, Lemont, IL, 60439 (United States); Lumetta, G. [Paccific Northwest National Laboratory, Richland, WA (United States)

    2016-07-01

    The ALSEP (Actinide Lanthanide Separation Process) was developed to treat a PUREX raffinate stream by liquid-liquid extraction with the intent of separating trivalent minor actinides (Am/Cm; An) from trivalent fission-product lanthanides (Ln) and selected transition metals. The major components of the modified ALSEP process have been demonstrated on a modified 2-cm annular centrifugal contactor with an enhanced mixing zone using stable fission products and radiotracers. The results show that by decreasing the pH of the minor actinide stripping solution, using HEDTA instead of DTPA, and increasing contact time, the process is very effective in separating americium from the lanthanides and the fission products.

  19. Enhanced antifouling behaviours of polyvinylidene fluoride membrane modified through blending with nano-TiO2/polyethylene glycol mixture

    International Nuclear Information System (INIS)

    Zhang, Jie; Wang, Zhiwei; Zhang, Xingran; Zheng, Xiang; Wu, Zhichao

    2015-01-01

    Graphical abstract: - Highlights: • Nano-TiO 2 /polyethylene glycol (PEG) mixture was used to modify PVDF membranes. • The steric hindrance effects of PEG enabled the dispersion of nanoparticles. • The energy barrier between SMP and modified membranes was increased. • The modification by nano-TiO 2 /PEG well improved the anti-fouling ability. - Abstract: Titanium dioxide (TiO 2 ) nanoparticles/polyethylene glycol (PEG) mixture was used to modify polyvinylidene fluoride (PVDF) membranes aiming to improve their antifouling ability. The use of PEG could improve the dispersion of nanoparticles thanks to steric hindrance effects. Test results showed that compared to the original PVDF membrane, the modified membranes had higher hydrophilicity and lower negative Zeta potential, facilitating membrane fouling control. The extended Derjaguin-Landau-Verwey-Overbeek (XDLVO) analysis indicated that the addition of TiO 2 nanoparticles improved their electron donor monopolarity, i.e., enhanced electron-donating ability. The interaction energy barrier between soluble microbial products (SMP) and membrane surfaces was also improved, indicating that anti-fouling ability of the modified membrane was elevated. The optimal dosage of nano-TiO 2 was found to be 0.15%, and further increase of dosage resulted in the aggregation of nanoparticles which consequently impaired the modification efficiency. Quartz crystal microbalance with dissipation (QCM-D) monitoring and SMP filtration tests confirmed the antifouling ability of the modified membrane

  20. Enhanced antifouling behaviours of polyvinylidene fluoride membrane modified through blending with nano-TiO{sub 2}/polyethylene glycol mixture

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Jie [State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai, 200092 (China); Wang, Zhiwei, E-mail: zwwang@tongji.edu.cn [State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai, 200092 (China); Zhang, Xingran [State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai, 200092 (China); Zheng, Xiang, E-mail: zhengxiang7825@163.com [School of Environment and Natural Resources, Renmin University of China, Beijing, 100872 (China); Wu, Zhichao [State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai, 200092 (China)

    2015-08-01

    Graphical abstract: - Highlights: • Nano-TiO{sub 2}/polyethylene glycol (PEG) mixture was used to modify PVDF membranes. • The steric hindrance effects of PEG enabled the dispersion of nanoparticles. • The energy barrier between SMP and modified membranes was increased. • The modification by nano-TiO{sub 2}/PEG well improved the anti-fouling ability. - Abstract: Titanium dioxide (TiO{sub 2}) nanoparticles/polyethylene glycol (PEG) mixture was used to modify polyvinylidene fluoride (PVDF) membranes aiming to improve their antifouling ability. The use of PEG could improve the dispersion of nanoparticles thanks to steric hindrance effects. Test results showed that compared to the original PVDF membrane, the modified membranes had higher hydrophilicity and lower negative Zeta potential, facilitating membrane fouling control. The extended Derjaguin-Landau-Verwey-Overbeek (XDLVO) analysis indicated that the addition of TiO{sub 2} nanoparticles improved their electron donor monopolarity, i.e., enhanced electron-donating ability. The interaction energy barrier between soluble microbial products (SMP) and membrane surfaces was also improved, indicating that anti-fouling ability of the modified membrane was elevated. The optimal dosage of nano-TiO{sub 2} was found to be 0.15%, and further increase of dosage resulted in the aggregation of nanoparticles which consequently impaired the modification efficiency. Quartz crystal microbalance with dissipation (QCM-D) monitoring and SMP filtration tests confirmed the antifouling ability of the modified membrane.

  1. Enhancing On-Task Behavior in Fourth-Grade Students Using a Modified Color Wheel System

    Science.gov (United States)

    Blondin, Carolyn; Skinner, Christopher; Parkhurst, John; Wood, Allison; Snyder, Jamie

    2012-01-01

    The authors used a withdrawal design to evaluate the effects of a modified Color Wheel System (M-CWS) on the on-task behavior of 7 students enrolled in the 4th grade. Standard CWS procedures were modified to include a 4th set of rules designed to set behavioral expectation for cooperative learning activities. Mean data showed that immediately…

  2. On Faraday's law in the presence of extended conductors

    Science.gov (United States)

    Bilbao, Luis

    2018-06-01

    The use of Faraday's Law of induction for calculating the induced currents in an extended conducting body is discussed. In a general case with arbitrary geometry, the solution to the problem of a moving metal object in the presence of a magnetic field is difficult and implies solving Maxwell's equations in a time-dependent situation. In many cases, including cases with good conductors (but not superconductors) Ampère's Law can be neglected and a simpler solution based solely in Faraday's law can be obtained. The integral form of Faraday's Law along any loop in the conducting body is equivalent to a Kirkhhoff's voltage law of a circuit. Therefore, a numerical solution can be obtained by solving a linear system of equations corresponding to a discrete number of loops in the body.

  3. Faraday rotation near charged black holes and other electrovacuum geometries

    International Nuclear Information System (INIS)

    Gerlach, U.H.

    1975-01-01

    In space permeated by a steady background electromagnetic field a gravitational wave and an electromagnetic wave not only undergo beat frequency oscillations, but the linear polarizations of these waves undergo Faraday rotations as well. The beating and the Faraday rotations are inextricably related. The classification of these phenomena requires three parameters, the three Euler parameters of SU(2). They specify in a more general sense the ''polarization'' of an electrograviton mode. The evolution of the beat frequency oscillations and the Faraday rotations along a propagating wave front is described as a moving point in SU(2). Consequently, a charged black hole serves not only as a catalyst for converting suitably directed electromagnetic radiation into gravitational radiation, but also as an agent that randomized the linear polarizations of radiation emerging from it. An assessment of these phenomena in relation to the origin of Weber's signals is given

  4. Evaluation of ion collection area in Faraday probes.

    Science.gov (United States)

    Brown, Daniel L; Gallimore, Alec D

    2010-06-01

    A Faraday probe with three concentric rings was designed and fabricated to assess the effect of gap width and collector diameter in a systematic study of the diagnostic ion collection area. The nested Faraday probe consisted of two concentric collector rings and an outer guard ring, which enabled simultaneous current density measurements on the inner and outer collectors. Two versions of the outer collector were fabricated to create gaps of 0.5 and 1.5 mm between the rings. Distribution of current density in the plume of a low-power Hall thruster ion source was measured in azimuthal sweeps at constant radius from 8 to 20 thruster diameters downstream of the exit plane with variation in facility background pressure. A new analytical technique is proposed to account for ions collected in the gap between the Faraday probe collector and guard ring. This method is shown to exhibit excellent agreement between all nested Faraday probe configurations, and to reduce the magnitude of integrated ion beam current to levels consistent with Hall thruster performance analyses. The technique is further studied by varying the guard ring bias potential with a fixed collector bias potential, thereby controlling ion collection in the gap. Results are in agreement with predictions based on the proposed analytical technique. The method is applied to a past study comparing the measured ion current density profiles of two Faraday probe designs. These findings provide new insight into the nature of ion collection in Faraday probe diagnostics, and lead to improved accuracy with a significant reduction in measurement uncertainty.

  5. An assessment of the lifetime of Faraday shield elements

    International Nuclear Information System (INIS)

    Caughman, J.B.O. II; Ruzic, D.N.; Hoffman, D.J.; Langley, R.A.; Lewis, M.B.; Ryan, P.M.

    1989-01-01

    The interaction of plasma with rf fields from an ion cyclotron range of frequencies (ICRF) antenna has been studied to estimate the amount of Faraday shield erosion expected in normal ICRF heating (ICRH) operation. Plasma parameters and ion energies have been measured in the near field of an antenna and used in a model to estimate the erosion rate of the Faraday shield surface. Experiments were conducted on the RF Test Facility (RFTF), a magnetic mirror device at Oak Ridge National Laboratory (ORNL), using a single-strap resonant loop antenna with a two-tier Faraday shield. The outer tier, facing the plasma, was layered with graphite tiles. The antenna was operated at currents and voltages (∼500 A, ∼20 kV at 25 kW) within 50% of those expected in tokamaks. The time varying floating potential was measured with a capacitively coupled probe, and the time-averaged floating potential, electron temperature, and electron density were measured with a Langmuir probe. Both probes were scanned in front of the antenna. Ion energies were measured with a gridded energy analyzer located below the antenna, and samples of silicon were placed on the Faraday shield surface to estimate the incident ion energy. The capacitive probe measurements show that the rf floating potential follows the magnetic field pattern of the antenna, indicating that the electromagnetic fields are responsible for the potential formation. Plasma parameters and ion energies have been correlated with the antenna current and used in s computational model of the plasma sheath to predict the amount of erosion expected from the Faraday shield elements exposed to plasma. Predictions of light ion sputtering of candidate Faraday shield materials are presented. 19 refs., 6 figs., 1 tab

  6. An assessment of the lifetime of Faraday shield elements

    International Nuclear Information System (INIS)

    Caughman, J.B.O. II; Ruzic, D.N.; Hoffman, D.J.; Langley, R.A.; Lewis, M.B.; Ryan, P.M.

    1990-01-01

    The interaction of plasma with rf fields from an ion cyclotron range of frequencies (ICRF) antenna has been studied to estimate the amount of Faraday shield erosion expected in normal ICRF heating operation. Plasma parameters and ion energies have been measured in the near field of an antenna and used in a model to estimate the erosion rate of the Faraday shield surface. Experiments were conducted on the RF Test Facility, a magnetic mirror device at Oak Ridge National Laboratory, using a single-strap resonant loop antenna with a two-tier Faraday shield. The outer tier, facing the plasma, was layered with graphite tiles. The antenna was operated at currents and voltages within 50% of those expected in tokamaks. The time-varying floating potential was measured with a capacitively coupled probe, and the time-averaged floating potential, electron temperature, and electron density were measured with a Langmuir probe. Ion energies were measured with a gridded energy analyser located below the antenna, and samples of silicon were placed on the Faraday shield surface to estimate the incident ion energy. The capacitive probe measurements show that the rf floating potential follows the magnetic field pattern of the antenna, indicating that the electromagnetic fields are responsible for the potential formation. Plasma parameters and ion energies have been correlated with the antenna current and used in a computational model of the plasma sheath to predict the amount of erosion expected from the Faraday shield elements exposed to plasma. Predictions of light ion sputtering of candidate Faraday shield materials are presented

  7. Evaluation of ion collection area in Faraday probes

    International Nuclear Information System (INIS)

    Brown, Daniel L.; Gallimore, Alec D.

    2010-01-01

    A Faraday probe with three concentric rings was designed and fabricated to assess the effect of gap width and collector diameter in a systematic study of the diagnostic ion collection area. The nested Faraday probe consisted of two concentric collector rings and an outer guard ring, which enabled simultaneous current density measurements on the inner and outer collectors. Two versions of the outer collector were fabricated to create gaps of 0.5 and 1.5 mm between the rings. Distribution of current density in the plume of a low-power Hall thruster ion source was measured in azimuthal sweeps at constant radius from 8 to 20 thruster diameters downstream of the exit plane with variation in facility background pressure. A new analytical technique is proposed to account for ions collected in the gap between the Faraday probe collector and guard ring. This method is shown to exhibit excellent agreement between all nested Faraday probe configurations, and to reduce the magnitude of integrated ion beam current to levels consistent with Hall thruster performance analyses. The technique is further studied by varying the guard ring bias potential with a fixed collector bias potential, thereby controlling ion collection in the gap. Results are in agreement with predictions based on the proposed analytical technique. The method is applied to a past study comparing the measured ion current density profiles of two Faraday probe designs. These findings provide new insight into the nature of ion collection in Faraday probe diagnostics, and lead to improved accuracy with a significant reduction in measurement uncertainty.

  8. Modified natural diatomite and its enhanced immobilization of lead, copper and cadmium in simulated contaminated soils

    International Nuclear Information System (INIS)

    Ye, Xinxin; Kang, Shenghong; Wang, Huimin; Li, Hongying; Zhang, Yunxia; Wang, Guozhong; Zhao, Huijun

    2015-01-01

    Highlights: • We modify natural diatomite using the facile acid treatment and ultrasonication. • Modification add pore volume, surface area and electronegativity of natural diatomite. • Modified diatomite is superior to natural diatomite in soil heavy metal remediation. • Modified diatomite can be promising for in-situ immobilization of heavy metal in soil. - Abstract: Natural diatomite was modified through facile acid treatment and ultrasonication, which increased its electronegativity, and the pore volume and surface area achieved to 0.211 cm 3 g −1 and 76.9 m 2 g −1 , respectively. Modified diatomite was investigated to immobilize the potential toxic elements (PTEs) of Pb, Cu and Cd in simulated contaminated soil comparing to natural diatomite. When incubated with contaminated soils at rates of 2.5% and 5.0% by weight for 90 days, modified diatomite was more effective in immobilizing Pb, Cu and Cd than natural diatomite. After treated with 5.0% modified diatomite for 90 days, the contaminated soils showed 69.7%, 49.7% and 23.7% reductions in Pb, Cu and Cd concentrations after 0.01 M CaCl 2 extraction, respectively. The concentrations of Pb, Cu and Cd were reduced by 66.7%, 47.2% and 33.1% in the leaching procedure, respectively. The surface complexation played an important role in the immobilization of PTEs in soils. The decreased extractable metal content of soil was accompanied by improved microbial activity which significantly increased (P < 0.05) in 5.0% modified diatomite-amended soils. These results suggested that modified diatomite with micro/nanostructured characteristics increased the immobilization of PTEs in contaminated soil and had great potential as green and low-cost amendments

  9. Modified natural diatomite and its enhanced immobilization of lead, copper and cadmium in simulated contaminated soils

    Energy Technology Data Exchange (ETDEWEB)

    Ye, Xinxin, E-mail: xxye@issp.ac.cn [Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Kang, Shenghong; Wang, Huimin [Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Li, Hongying [Institute of Soil and Fertilizer, Anhui Academy of Agricultural Sciences, Hefei 230031 (China); Zhang, Yunxia [Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Wang, Guozhong, E-mail: gzhwang@issp.ac.cn [Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Zhao, Huijun [Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Centre for Clean Environment and Energy, Gold Coast Campus, Griffith University, Queensland 4222 (Australia)

    2015-05-30

    Highlights: • We modify natural diatomite using the facile acid treatment and ultrasonication. • Modification add pore volume, surface area and electronegativity of natural diatomite. • Modified diatomite is superior to natural diatomite in soil heavy metal remediation. • Modified diatomite can be promising for in-situ immobilization of heavy metal in soil. - Abstract: Natural diatomite was modified through facile acid treatment and ultrasonication, which increased its electronegativity, and the pore volume and surface area achieved to 0.211 cm{sup 3} g{sup −1} and 76.9 m{sup 2} g{sup −1}, respectively. Modified diatomite was investigated to immobilize the potential toxic elements (PTEs) of Pb, Cu and Cd in simulated contaminated soil comparing to natural diatomite. When incubated with contaminated soils at rates of 2.5% and 5.0% by weight for 90 days, modified diatomite was more effective in immobilizing Pb, Cu and Cd than natural diatomite. After treated with 5.0% modified diatomite for 90 days, the contaminated soils showed 69.7%, 49.7% and 23.7% reductions in Pb, Cu and Cd concentrations after 0.01 M CaCl{sub 2} extraction, respectively. The concentrations of Pb, Cu and Cd were reduced by 66.7%, 47.2% and 33.1% in the leaching procedure, respectively. The surface complexation played an important role in the immobilization of PTEs in soils. The decreased extractable metal content of soil was accompanied by improved microbial activity which significantly increased (P < 0.05) in 5.0% modified diatomite-amended soils. These results suggested that modified diatomite with micro/nanostructured characteristics increased the immobilization of PTEs in contaminated soil and had great potential as green and low-cost amendments.

  10. Modified starch enhances absorption and accelerates recovery in experimental diarrhea in rats.

    Science.gov (United States)

    Wingertzahn, M A; Teichberg, S; Wapnir, R A

    1999-03-01

    Rice gruels have been used as home remedies to treat dehydration associated with diarrheal illness in developing countries. These preparations have produced conflicting results, most likely due to the heterogeneity of starch used. We investigated whether the modified tapioca starch, Textra (TX), at 5.0 or 10.0 g/L added to a 90 mmol/L Na+-111 mmol glucose oral rehydration solution (ORS) enhanced water and electrolyte absorption in two models of diarrhea. To induce a secretory state (model A), the jejunum of juvenile rats was perfused with 10 mmol/L theophylline (THEO) under anesthesia and then perfused with the solutions indicated above. To produce chronic osmotic-secretory diarrhea (model B), rats had a magnesium citrate-phenolphthalein solution as the sole fluid source for 1 wk, and then were perfused as the THEO-treated rats. Water, electrolyte, and glucose absorption were measured during both perfusions. As an extension of the perfusion studies, we compared how fast rats recovered from chronic osmotic diarrhea by offering them either water, ORS, or ORS containing 5.0 g/L TX along with solid food. Recovery rate markers were measured after 24 h and included weight gain, food and fluid intake, and stool output. In model A, addition of 5.0 g/L TX to ORS reversed Na+ secretion and improved net water as well as K+ and glucose absorption, compared with THEO-treated rats perfused with ORS without TX. In model B, addition of TX to ORS increased water, Na+, K+, and glucose absorption, compared with rats perfused without TX. Increasing TX from 5.0 to 10.0 g/L had no additional benefit. In recovery experiments, animals with free access to ORS with TX had significantly greater weight gain and decreased stool output compared with animals recovering with water or ORS without TX. Our experiments suggest that TX may be a useful additive to standard ORS to promote fluid and electrolyte absorption and may provide additional energy without increasing ORS osmotic load.

  11. Enhanced sorption of radiocobalt from water by Bi(III) modified montmorillonite: A novel adsorbent

    International Nuclear Information System (INIS)

    Guo Zhiqiang; Li Yuan; Zhang Shouwei; Niu Haihong; Chen Zhesheng; Xu Jinzhang

    2011-01-01

    Highlights: → Bi-Mt has higher surface area than Ca-Mt. → The sorption of Co(II) on Bi-Mt is dependent on ionic strength and pH. → The sorption of Co(II) on Bi-Mt is an spontaneous and endothermic process. → Bi-Mt has good practical application potential in wastewater disposal. - Abstract: In this study, Ca-montmorillonite (Ca-Mt) modified with Bi 3+ was used as a novel adsorbent for the sorption of Co(II) from aqueous solutions. The sorption of Co(II) on Bi-montmorillonite (Bi-Mt) was investigated as a function of contact time, pH, ionic strength, adsorbent content, Co(II) concentrations, fulvic acid (FA) and temperature. Compared to Ca-Mt, Bi-Mt showed a higher affinity to bind Co(II) ions. The sorption percentage of Co(II) on Bi-Mt increased with increasing pH at pH 3.0-8.5, and then maintained the high level at pH 8.5-12. The sorption of Co(II) on Bi-Mt was dependent on ionic strength at low pH, and independent of ionic strength at high pH. The presence of FA enhanced Co(II) sorption at low pH, but suppressed Co(II) sorption at high pH. The thermodynamic data derived from temperature dependent sorption isotherms suggested that the sorption of Co(II) on Bi-Mt was spontaneous and endothermic process. Outer-sphere surface complexation and/or ion exchange were the main mechanisms of Co(II) sorption on Bi-Mt at low pH, whereas inner-sphere surface complexation was the main sorption mechanism at high pH. From the experimental results, it is possible to conclude that Bi-Mt is suitable for application of Co(II) removal from aqueous solutions.

  12. Improving surface-enhanced Raman scattering effect using gold-coated hierarchical polystyrene bead substrates modified with postgrowth microwave treatment.

    Science.gov (United States)

    Yuen, Clement; Zheng, Wei; Huang, Zhiwei

    2008-01-01

    We report a novel postgrowth microwave heating implementation by selectively modifying hierarchical polystyrene (PS) bead substrates coated with gold (Au) films to effectively improve the surface-enhanced Raman scattering (SERS) effect on the analytes. The SERS signal of probe molecule rhodamine 6G (Rh 6G) on the microwave-treated Au-PS substrates can be improved by 10-fold, while the detection limit of Rh 6G in concentration can be enhanced by two orders of magnitude compared to the as-growth substrates. The high-quality SERS spectrum of saliva can also be acquired using the modified substrates, demonstrating the potential for the realization of the high-performance SERS substrates for biomedical applications.

  13. Faraday tarotion: new parameter for electromagnetic pulse propagation in magnetoplasma

    International Nuclear Information System (INIS)

    Bloch, S.C.; Lyons, P.W.

    1976-01-01

    Extreme distortion and time-dependent Faraday rotation occur for propagation of short electromagnetic pulses in magnetoplasma, for some ranges of plasma parameters. In order to relate pulse and monochromatic waves for propagation-path diagnostic purposes, a new parameter is introduced for the transmitted pulse train which has properties that correspond very accurately to results that would be expected for Faraday rotation of a continuous wave having the central frequency of the incident pulse spectrum. Results for 5-ns pulses (10 GHz) are presented for varying propagating length, static magnetic field, electron density, and collisional absorption

  14. The contributions of Faraday and Maxwell to electrical science

    CERN Document Server

    Tricker, R A R

    1966-01-01

    The Contributions of Faraday and Maxwell to Electrical Science deals with the development of electromagnetic theory following the establishment of the basis for the first law of circulation relating to the magnetic fields generated by steady currents. This book is organized into two parts encompassing nine chapters that specifically treat the provision of the basis for the second law of circulation, the law that deals with the induction of currents, which was predominantly the work of British physicists, Michael Faraday and James Clerk Maxwell. Part I highlights their life, career, and contri

  15. Concluding remarks: Faraday Discussion on chemistry in the urban atmosphere.

    Science.gov (United States)

    Jimenez, Jose L

    2016-07-18

    This article summarises the Concluding remarks from the Faraday Discussion on Chemistry in the Urban Atmosphere. The following themes are addressed: (a) new results that inform our understanding of the evolving sources and composition of the urban atmosphere ("News"); (b) results that identify gaps in our understanding that necessitate further work ("Gaps"); (c) the emerging instrumentation revolution and some of the challenges that it brings; (d) the structural issues of insufficient support for the analysis of field campaigns; and (e) some important areas that were missing from this Faraday Discussion and that should receive an increasing focus in the future.

  16. Fast Faraday fading of long range satellite signals.

    Science.gov (United States)

    Heron, M. L.

    1972-01-01

    20 MHz radio signals have been received during the day from satellite Beacon-B when it was below the optical horizon by using a bank of narrow filters to improve the signal to noise ratio. The Faraday fading rate becomes constant, under these conditions, at a level determined by the plasma frequency just below the F-layer peak. Variations in the Faraday fading rate reveal fluctuations in the electron density near the peak, while the rate of attaining the constant level depends on the shape of the electron density profile.

  17. Compensation of thermally induced polarisation distortions in Faraday isolators

    International Nuclear Information System (INIS)

    Khazanov, E A

    1999-01-01

    Two new Faraday isolator designs are proposed. They make it possible to compensate partly for the depolarisation of radiation which occurs in magneto-optical elements because of the photoelastic effect caused by heating associated with the absorption of laser radiation. Analytic and numerical comparisons of the new and traditional designs demonstrate a significant (by orders of magnitude) increase in the isolation ratio of the new isolators. The results obtained indicate that it should be possible to construct a Faraday isolator with the isolation ratio of 30 dB for laser radiation with an average power of several kilowatts. (laser applications and other topics in quantum electronics)

  18. Ligand-Modified Human Serum Albumin Nanoparticles for Enhanced Gene Delivery.

    Science.gov (United States)

    Look, Jennifer; Wilhelm, Nadine; von Briesen, Hagen; Noske, Nadja; Günther, Christine; Langer, Klaus; Gorjup, Erwin

    2015-09-08

    The development of nonviral gene delivery systems is a great challenge to enable safe gene therapy. In this study, ligand-modified nanoparticles based on human serum albumin (HSA) were developed and optimized for an efficient gene therapy. Different glutaraldehyde cross-linking degrees were investigated to optimize the HSA nanoparticles for gene delivery. The peptide sequence arginine-glycine-aspartate (RGD) and the HIV-1 transactivator of transduction sequence (Tat) are well-known as promising targeting ligands. Plasmid DNA loaded HSA nanoparticles were covalently modified on their surface with these different ligands. The transfection potential of the obtained plasmid DNA loaded RGD- and Tat-modified nanoparticles was investigated in vitro, and optimal incubation conditions for these preparations were studied. It turned out that Tat-modified HSA nanoparticles with the lowest cross-linking degree of 20% showed the highest transfection potential. Taken together, ligand-functionalized HSA nanoparticles represent promising tools for efficient and safe gene therapy.

  19. Enhanced performance of microbial fuel cells by using MnO_2/Halloysite nanotubes to modify carbon cloth anodes

    International Nuclear Information System (INIS)

    Chen, Yingwen; Chen, Liuliu; Li, Peiwen; Xu, Yuan; Fan, Mengjie; Zhu, Shemin; Shen, Shubao

    2016-01-01

    The modification of anode materials is important to enhance the power generation of MFCs (microbial fuel cells). A novel and cost-effective modified anode that is fabricated by dispersing manganese dioxide (MnO_2) and HNTs (Halloysite nanotubes) on carbon cloth to improve the MFCs' power production was reported. The results show that the MnO_2/HNT anodes acquire more bacteria and provide greater kinetic activity and power density compared to the unmodified anode. Among all modified anodes, 75 wt% MnO_2/HNT exhibits the highest electrochemical performance. The maximum power density is 767.3 mWm"−"2, which 21.6 higher than the unmodified anode (631 mW/m"2). Besides, CE (Coulombic efficiency) was improved 20.7, indicating that more chemical energy transformed to electricity. XRD (X-Ray powder diffraction) and FTIR (Fourier transform infrared spectroscopy) are used to characterize the structure and functional groups of the anode. CV (cyclic voltammetry) scans and SEM (scanning electron microscope) images demonstrate that the measured power density is associated with the attachment of bacteria, the microorganism morphology differed between the modified and the original anode. These findings demonstrate that MnO_2/HNT nanocomposites can alter the characteristics of carbon cloth anodes to effectively modify the anode for practical MFC applications. - Highlights: • Different contents of MnO_2/HNT composites were prepared and used to modify anodes in MFCs. • The performance of MFCs was improved by the anode modification. • 75% wt MnO_2/HNT modified anode showed the better capacity on power density. • Water contact angle, CV, SEM were determined to figure out the effect of modification on MFCs. • MnO_2/HNT modified anode in MFCs was first studied to push MFCs technology forward.

  20. Electromagnetic analysis of the Faraday shield of the EAST ICRF antenna

    International Nuclear Information System (INIS)

    Yang Qingxi; Song Yuntao; Wu Songtao; Zhao Yanping

    2011-01-01

    Faraday shield is one of the important components of ICRF antenna for EAST. In view of the structural safety of the Faraday shield, the electromagnetic and structural analyses for the Faraday shield have been carried out by applying the finite element method and the formulas under the cases of plasma disruption and vertical displacement event (VDE). Results of the electromagnetic forces, the stresses distribution as well as the deformation in the Faraday shield have been obtained under the two cases. They meet the design requirements and provide the theoretical basis for the structural safety evaluation of the Faraday shield. (authors)

  1. Modified natural diatomite and its enhanced immobilization of lead, copper and cadmium in simulated contaminated soils.

    Science.gov (United States)

    Ye, Xinxin; Kang, Shenghong; Wang, Huimin; Li, Hongying; Zhang, Yunxia; Wang, Guozhong; Zhao, Huijun

    2015-05-30

    Natural diatomite was modified through facile acid treatment and ultrasonication, which increased its electronegativity, and the pore volume and surface area achieved to 0.211 cm(3) g(-1) and 76.9 m(2) g(-1), respectively. Modified diatomite was investigated to immobilize the potential toxic elements (PTEs) of Pb, Cu and Cd in simulated contaminated soil comparing to natural diatomite. When incubated with contaminated soils at rates of 2.5% and 5.0% by weight for 90 days, modified diatomite was more effective in immobilizing Pb, Cu and Cd than natural diatomite. After treated with 5.0% modified diatomite for 90 days, the contaminated soils showed 69.7%, 49.7% and 23.7% reductions in Pb, Cu and Cd concentrations after 0.01 M CaCl2 extraction, respectively. The concentrations of Pb, Cu and Cd were reduced by 66.7%, 47.2% and 33.1% in the leaching procedure, respectively. The surface complexation played an important role in the immobilization of PTEs in soils. The decreased extractable metal content of soil was accompanied by improved microbial activity which significantly increased (Psoils. These results suggested that modified diatomite with micro/nanostructured characteristics increased the immobilization of PTEs in contaminated soil and had great potential as green and low-cost amendments. Copyright © 2015 Elsevier B.V. All rights reserved.

  2. Multilayer Choline Phosphate Molecule Modified Surface with Enhanced Cell Adhesion but Resistance to Protein Adsorption.

    Science.gov (United States)

    Chen, Xingyu; Yang, Ming; Liu, Botao; Li, Zhiqiang; Tan, Hong; Li, Jianshu

    2017-08-22

    Choline phosphate (CP), which is a new zwitterionic molecule, and has the reverse order of phosphate choline (PC) and could bind to the cell membrane though the unique CP-PC interaction. Here we modified a glass surface with multilayer CP molecules using surface-initiated atom-transfer radical polymerization (SI-ATRP) and the ring-opening method. Polymeric brushes of (dimethylamino)ethyl methacrylate (DMAEMA) were synthesized by SI-ATRP from the glass surface. Then the grafted PDMAEMA brushes were used to introduce CP groups to fabricate the multilayer CP molecule modified surface. The protein adsorption experiment and cell culture test were used to evaluate the biocompatibility of the modified surfaces by using human umbilical veinendothelial cells (HUVECs). The protein adsorption results demonstrated that the multilayer CP molecule decorated surface could prevent the adsorption of fibrinogen and serum protein. The adhesion and proliferation of cells were improved significantly on the multilayer CP molecule modified surface. Therefore, the biocompatibility of the material surface could be improved by the modified multilayer CP molecule, which exhibits great potential for biomedical applications, e.g., scaffolds in tissue engineering.

  3. Enhanced biofouling resistance of polyethersulfone membrane surface modified with capsaicin derivative and itaconic acid

    International Nuclear Information System (INIS)

    Wang, Jian; Gao, Xueli; Wang, Qun; Sun, Haijing; Wang, Xiaojuan; Gao, Congjie

    2015-01-01

    Graphical abstract: - Highlights: • PES membrane was modified with a capsaicin derivative. • UV-assisted graft polymerization was carried out on membrane surface. • The capsaicin derivative modified membrane shows better antibiofouling property. - Abstract: The culprit of biofouling is the reproduction of viable microorganisms on the membrane surface. Recently, functionalization of membrane surface with natural antibacterial agents has drawn great attention. This work presents the fabrication of antibiofouling polyethersulfone (PES) ultrafiltration (UF) membranes by UV-assisted photo grafting of capsaicin derivative (N-(4-hydroxy-3-methoxy-benzyl)-acrylamide, HMBA) and itaconic acid (IA) on the surface of PES membrane. Results of FTIR-ATR, water static contact angle (WSCA) and atomic force microscopy (AFM) analysis confirmed the successful grafting of HMBA and IA on the membrane surface. We investigated the antifouling and antibacterial properties of these membranes using BSA and Escherichia coli as the test model, respectively. During a 150-min test, the modified membranes show much lower flux decline (42.7% for PES-g-1H0I, 22.2% for PES-g-1H1I and 7.7% for PES-g-1H5I) when compared with the pristine membrane (flux declined by 77%). The modified membranes exhibit excellent antibacterial activity (nearly 100%) when UV irradiation time was 6 min. The morphological study suggested that the E. coli on the pristine membrane showed a regular and smooth surface while that on the modified membrane was disrupted, which validated the antibacterial activity of the modified membranes.

  4. Enhanced biofouling resistance of polyethersulfone membrane surface modified with capsaicin derivative and itaconic acid

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jian [Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100 (China); College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100 (China); Gao, Xueli, E-mail: gxl_ouc@126.com [Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100 (China); College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100 (China); Wang, Qun; Sun, Haijing; Wang, Xiaojuan [Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100 (China); College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100 (China); Gao, Congjie, E-mail: gaocjie@ouc.edu.cn [Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100 (China); College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100 (China)

    2015-11-30

    Graphical abstract: - Highlights: • PES membrane was modified with a capsaicin derivative. • UV-assisted graft polymerization was carried out on membrane surface. • The capsaicin derivative modified membrane shows better antibiofouling property. - Abstract: The culprit of biofouling is the reproduction of viable microorganisms on the membrane surface. Recently, functionalization of membrane surface with natural antibacterial agents has drawn great attention. This work presents the fabrication of antibiofouling polyethersulfone (PES) ultrafiltration (UF) membranes by UV-assisted photo grafting of capsaicin derivative (N-(4-hydroxy-3-methoxy-benzyl)-acrylamide, HMBA) and itaconic acid (IA) on the surface of PES membrane. Results of FTIR-ATR, water static contact angle (WSCA) and atomic force microscopy (AFM) analysis confirmed the successful grafting of HMBA and IA on the membrane surface. We investigated the antifouling and antibacterial properties of these membranes using BSA and Escherichia coli as the test model, respectively. During a 150-min test, the modified membranes show much lower flux decline (42.7% for PES-g-1H0I, 22.2% for PES-g-1H1I and 7.7% for PES-g-1H5I) when compared with the pristine membrane (flux declined by 77%). The modified membranes exhibit excellent antibacterial activity (nearly 100%) when UV irradiation time was 6 min. The morphological study suggested that the E. coli on the pristine membrane showed a regular and smooth surface while that on the modified membrane was disrupted, which validated the antibacterial activity of the modified membranes.

  5. Surface-Modified Quantum Dots Enhanced Luminescence Polymer Nanocomposites Light Emitting Diode

    National Research Council Canada - National Science Library

    Wei, Kung-Hwa

    2006-01-01

    .... Both the photoluminescence and electroluminescence efficiencies of the polymer nanocomposites are dramatically enhanced--sometimes by more than double--relative to the values of the pure polymer...

  6. ICRF Faraday shield plasma sheath physics: The Perkins paradigm

    International Nuclear Information System (INIS)

    Whealton, J.H.; Ryan, P.M.; Raridon, R.J.

    1989-01-01

    Using a 2-D nonlinear formulation which considers the plasma edge near a Faraday shield in a self consistent manner, progress is indicated in the modeling of the ion motion for a Perkins embodiment. Ambiguities in the formulation are also indicated, the resolution of which will provide significant insight into the impurities generation for ICRH antennas. 6 refs., 3 figs

  7. Recent VLA Measurements of CME-Induced Faraday Rotation

    Science.gov (United States)

    Kooi, Jason; Thomas, Najma; Guy, Michael; Spangler, Steven R.

    2018-01-01

    Observations of Faraday rotation, the change in polarization position angle of linearly polarized radiation as it propagates through a magnetized plasma, have been used for decades to determine the strength and structure of the coronal magnetic field and plasma density. Similarly, observations of Faraday rotation through a coronal mass ejection (CME) have the potential to improve our understanding of the CME’s plasma structure. We report recent results from simultaneous white-light coronagraph and radio observations made of a CME in July 2015. We made radio observations using the Karl G. Jansky Very Large Array (VLA) at 1 - 2 GHz frequencies of a set of cosmic radio sources through the solar corona at heliocentric distances that ranged between 8 - 23 solar radii. A unique aspect of these observations is that the CME occulted several of these radio sources and, therefore, our Faraday rotation measurements provide information on the plasma structure in different regions of the CME. We successfully measured CME-induced Faraday rotation along multiple lines of sight because we made special arrangements with the staff at the National Radio Astronomy Observatory to trigger VLA observations when a candidate CME appeared low in the corona in near real-time images from the Large Angle and Spectrometric Coronagraph (LASCO) C2 instrument.

  8. The Journey from Maxwell to Faraday (From Fields to Strings)

    Indian Academy of Sciences (India)

    2010-07-02

    Jul 2, 2010 ... markets!). Signature of its robustness and versatility. Basically it is tailor-made for describing systems with infinitely many interacting degrees of freedom. ... QED is a successful theory of quantum fields. Faraday's picture is not quantitatively useful. What are the equations governing the diffuse lines of flux?

  9. Assessment of the Usability of the Workbench Faraday Cage Method

    OpenAIRE

    Sørensen, Morten; Franek, Ondrej; Christensen, Søren K.; Pedersen, Gert Frølund; Ebert, Hans

    2011-01-01

    The workbench Faraday Cage method (WBFC) is a time efficient module pre-compliance test regarding radiated emission. This work investigates the method’s usability and credibility and concludes that for this particular case the WBFC perform a tolerable compliance test for frequencies below 360 MHz while it is essentially useless for higher frequencies.

  10. Assessment of the Usability of the Workbench Faraday Cage Method

    DEFF Research Database (Denmark)

    Sørensen, Morten; Franek, Ondrej; Christensen, Søren K.

    2011-01-01

    The workbench Faraday Cage method (WBFC) is a time efficient module pre-compliance test regarding radiated emission. This work investigates the method’s usability and credibility and concludes that for this particular case the WBFC perform a tolerable compliance test for frequencies below 360 MHz...

  11. Faraday's Investigation of Electromagnetic Induction. Experiment No. 21.

    Science.gov (United States)

    Devons, Samuel

    This paper focuses on Michael Faraday's experimental research in electricity in the 1830's. Historical notes related to his work are included as well as experiments, his objectives, and illustrations of equipment for the experiments. Examples from his diary are given so that students can attempt to emulate his honest and systematic manner of…

  12. Non-destructive Faraday imaging of dynamically controlled ultracold atoms

    DEFF Research Database (Denmark)

    Gajdacz, Miroslav; Pedersen, Poul Lindholm; Mørch, Troels

    2013-01-01

    We describe an easily implementable method for non-destructive measurements of ultracold atomic clouds based on dark field imaging of spatially resolved Faraday rotation. The signal-to-noise ratio is analyzed theoretically and, in the absence of experimental imperfections, the sensitivity limit...

  13. Quantum noise for Faraday light–matter interfaces

    DEFF Research Database (Denmark)

    Vasliyev, D.V.; Hammerer, K.; Korolev, N.

    2012-01-01

    In light–matter interfaces based on the Faraday effect, quite a number of quantum information protocols have been successfully demonstrated. In order to further increase the performance and fidelities achieved in these protocols, a deeper understanding of the relevant noise and decoherence...

  14. Faraday effect on stimulated Raman scattering in the linear region

    Science.gov (United States)

    Liu, Z. J.; Li, B.; Xiang, J.; Cao, L. H.; Zheng, C. Y.; Hao, L.

    2018-04-01

    The paper presents the effect of Faraday rotation on stimulated Raman scattering (SRS). When light propagates along the magnetic field upon plasma, Faraday rotation occurs. The rotation angle can be expressed as {{d}}θ /{{d}}{s}=2.93× {10}-4B\\tfrac{{n}e/{n}c}{\\sqrt{1-{n}e/{n}c}} {cm}}-1 approximately, where θ is the rotation angle and s is distance, n e is the electron density, n c is the critical density and B is magnetic field in unit of Gauss. Both the incident light and Raman light have Faraday effects. The angle between the polarization directions of incident light and Raman light changes with position. The driven force of electron plasma wave also reduces, and then SRS scattering level is reduced. Faraday rotation effect can increase the laser intensity threshold of Raman scattering, even if the magnetic field strength is small. The circularly polarized light incident case is also compared with that of the linearly polarized light incident. The Raman scattering level of linearly polarized light is much smaller than that of circularly polarized light in the magnetized plasma. The difference between linearly and circularly polarized lights is also discussed.

  15. Coarsening of Faraday Heaps: Experiment, Simulation, and Theory

    NARCIS (Netherlands)

    Gerner, van H.J.; Robledo, Caballero G.A.; Meer, van der D.; Weele, van der J.P.; Hoef, van der M.A.

    2009-01-01

    When a layer of granular material is vertically shaken, the surface spontaneously breaks up in a landscape of small Faraday heaps that merge into larger ones on an ever increasing time scale. This coarsening process is studied in a linear setup, for which the average life span of the transient state

  16. Correspondence of Michael Faraday, v.5 1855-1860

    CERN Document Server

    Faraday, Michael

    2008-01-01

    This volume includes 70% of previously unpublished letters of Michael Farday spanning half of the 1850s and most of 1860. Topics include Faraday's work on regelation, the transmission of light through gold and his appointment by Emperor Napoleon III to be a Commander of the Legion of Honour.

  17. Faraday, Dickens and Science Education in Victorian Britain

    Science.gov (United States)

    Melville, Wayne; Allingham, Philip V.

    2011-01-01

    The achievements of Michael Faraday in the fields of electricity and electrochemistry have led some to describe him as the greatest experimental scientist in history. Charles Dickens was the creative genius behind some of the most memorable characters in literature. In this article, we share an historical account of how the collaboration of these…

  18. Faraday effect revisited: sum rules and convergence issues

    DEFF Research Database (Denmark)

    Cornean, Horia; Nenciu, Gheorghe

    2010-01-01

    This is the third paper of a series revisiting the Faraday effect. The question of the absolute convergence of the sums over the band indices entering the Verdet constant is considered. In general, sum rules and traces per unit volume play an important role in solid-state physics, and they give...

  19. Faraday rotation applied to the hot plasmas diagnosis

    International Nuclear Information System (INIS)

    Cojocaru, E.

    1980-01-01

    In many circumstances it is of theoretical or practical interest to know the electric and magnetic fields in the hot plasmas. A method for the determination of the magnetic field in the hot plasmas is the Faraday rotation measurement. The aim of this paper is to point out the principle and application of this rarely used optical method. (author)

  20. Cerium-modified Aurivillius-type sodium lanthanum bismuth titanate with enhanced piezoactivities

    International Nuclear Information System (INIS)

    Wang Chunming; Zhao Liang; Wang Jinfeng; Zheng Limei; Du Juan; Zhao Minglei; Wang Chunlei

    2009-01-01

    The electrical, piezoelectric and dielectric properties of cerium-modified Aurivillius-type sodium lanthanum bismuth titanate (Na 0.5 La 0.5 Bi 4 Ti 4 O 15 , NLBT) ceramics were investigated. It was found the piezoelectric activities of NLBT ceramics were significantly improved by cerium modification. The piezoelectric coefficient d 33 and Curie temperature T c for the 0.50 wt.% cerium-modified NLBT were found to be 29 pC/N and 573 deg. C, respectively. The reasons for piezoelectric activities improvement by cerium modification were given. A small dielectric abnormity was observed in NLBT ceramics, which can be suppressed by cerium modification.

  1. Using modified soy protein to enhance foaming of egg white protein.

    Science.gov (United States)

    Wang, Guang; Troendle, Molly; Reitmeier, Cheryll A; Wang, Tong

    2012-08-15

    It is well known that the foaming properties of egg white protein are significantly reduced when a small amount of yolk is mixed in the white. To improve foaming properties of yolk-contaminated egg white protein, soy protein isolate (SPI) and egg proteins were modified to make basic proteins, and effects of these modified proteins on egg white foaming were evaluated in a model and an angel cake system. SPI and egg yolk proteins were modified to have an isoelectric point of 10, and sonication was used to increase protein dispersibility after the ethyl esterification reaction. However, only the addition of sonicated and modified SPI (SMSPI) showed improvement of foaming in the 5% egg protein model system with 0.4% yolk addition. SMSPI was then used in making angel food cake to examine whether the cake performance reduction due to yolk contamination of the white would be restored by such alkaline protein. Cake performance was improved when cream of tartar was used together with SMSPI. Basic soy protein can be made and used to improve egg white foaming properties and cake performance. Copyright © 2012 Society of Chemical Industry.

  2. Enhancing the crumb rubber modified asphalt’s storage stability through the control of its internal network structure

    Directory of Open Access Journals (Sweden)

    Mohyeldin Ragab

    2018-01-01

    Full Text Available The current research investigated the effect of the internal network structure developed in the crumb rubber modified asphalt (CRMA on its storage stability. The authors investigated the influence of asphalt-crumb rubber modifier (CRM interaction parameters (interaction time, interaction speed, and interaction temperature on the development of the internal network structure in CRMA. The authors found that the existence of three dimensional (3D network structures in the CRMA enhanced its storage stability. Fourier Transform Infrared (FTIR Spectroscopy was utilized to determine the nature of CRM components responsible for the development of 3D network structure in the liquid phase of CRMA. This was achieved by monitoring the changes of the IR distinctive peaks in the CRMA liquid phase. Dissolution tests and thermo gravimetric analysis (TGA were carried out on the extracted CRM after interaction with asphalt to determine the role of CRM dissolved amounts and released components on the development of 3D network structure in CRMA. The asphalt-CRM interaction parameters were found to be essential to induce the formation of the 3D network structure within the liquid phase of the CRMA through controlling the swelling, dissolution and release of CRM components into the asphalt liquid phase. The existence of 3D network structure in the CRMA had determinant impact on the enhancement of its storage stability. Keywords: Storage stability, Three dimensional (3D network, Crumb rubber modified asphalt

  3. An assessment of the lifetime of Faraday shield elements

    International Nuclear Information System (INIS)

    Caughman, J.B.O. II; Ruzic, D.N.; Hoffman, D.J.; Langley, R.A.; Lewis, M.B.; Ryan, P.M.

    1989-01-01

    The interaction of plasma with rf fields from an ion cyclotron range of frequencies (ICRF) antenna has been studied to estimate the amount of Faraday shield erosion expected in normal ICRF heating operation. Plasma parameters and ion energies have been measured in the near field of an antenna and used in a model to estimate the erosion rate of the Faraday shield surface. Experiments were conducted on the RF Test Facility, a magnetic mirror device at Oak Ridge National Laboratory, using a single-strap resonant loop antenna with a two-tier Faraday shield. The outer tier, facing the plasma, was layered with graphite tiles. The antenna was operated at currents and voltages within 50% of those expected in tokamaks. The time-varying floating potential was measured with a capacitively coupled probe, and the time-averaged floating potential, electron temperature, and electron density were measured with Langmuir probe. Both probes were scanned in front of the antenna. Ion energies were measured with a gridded energy analyzer located below the antenna, and samples of silicon were placed on the Faraday shield surface to estimate the incident ion energy. The capacitive probe measurement show that the rf floating potential follows the magnetic field pattern of the antenna, indicating that the electromagnetic fields are responsible for the potential formation. Electron temperatures increase with rf power and can reach values ≥60 eV for an rf power of ∼25 kW. Incident ion energies ≥300 eV have been measured for the same power level. Predictions of light ion sputtering of candidate Faraday shield materials are presented. 19 refs., 6 figs., 1 tab

  4. Structure, spectra and thermal, mechanical, Faraday rotation properties of novel diamagnetic SeO2-PbO-Bi2O3-B2O3 glasses

    Science.gov (United States)

    Chen, Qiuling; Su, Kai; Li, Yantao; Zhao, Zhiwei

    2018-06-01

    Faraday rotation diamagnetic glass has attracted research attentions in photonics, sensing and magneto optical devices due to their high refractive index, wide transmittance in UV and Fourier transform infrared (FT-IR) range and temperature independent Faraday rotation. Selenite modified heavy metal oxides glasses with composition of xSeO2-(10-x) B2O3-45PbO-45Bi2O3 (x = 0, 1, 5 and 10mol%) and 15%SeO2-40%PbO-45%Bi2O3 have been fabricated by melt-quenching method in present study. The influence of SeO2 on glass forming ability, thermal, mechanical properties and Faraday rotation were evaluated through X-ray Diffraction (XRD), Fourier transforms infrared spectra (FT-IR), Raman, X-ray photoelectron spectroscopy (XPS), differential scanning calorimetry (DSC), Vicker's hardness and Verdet constant measurements. XRD spectra reveal that the good vitrification was achieved for glass with SeO2 amounts ≤10% even without B2O3. FT-IR, Raman and XPS spectra ascertain the existence of characteristic vibration of SeO4, SeO3, PbO4, BiO3 and BO3 units. The incorporation of SeO2 increases the connectivity of glassy network by increasing the Tg, thermal stability and mechanical hardness. The small band gap, high polarizable Se4+ ions and isolated SeO3 units contribute to Faraday rotation improvement.

  5. Characterization of magnetic field profiles at RFX-mod by Faraday rotation measurements

    Science.gov (United States)

    Auriemma, Fulvio; Brombin, Matteo; Canton, Alessandra; Giudicotti, Leonardo; Innocente, Paolo; Zilli, Enrico

    2009-11-01

    A multichannel far-infrared (FIR, λ=118.8 μm) polarimeter has been recently upgraded and re-installed on RFX-mod to measure the Faraday rotation angle along five vertical chords. Polarimetric data, associated with electron density profile, allow the reconstruction of the poloidal magnetic field profile. In this work the setup of the diagnostic is presented and the first Faraday rotation measurements are analyzed. The measurements have been performed at plasma current above 1.2 MA and electron density between 2 and 6x10^19 m-3. The actual S/N ratio is slightly lower than the expected one, due to electromagnetic coupling of the detectors with the saddle coils close to the polarimeter position. Due to this limit, only average information in the flat-top phase of the discharge could be so far obtained. The experimental data have been compared with the result of the μ&p equilibrium model [1], showing a good agreement between experiment and model, whereas the main differences are in the external region of the plasma. A different parameterization of the μ=μ0 J.B/B^2 profile has been proposed to enhance the agreement between model and experiment. [0pt] [1] Ortolani and Snack, World Scientific (1993) Singapore

  6. Representing the Electromagnetic Field: How Maxwell's Mathematics Empowered Faraday's Field Theory

    Science.gov (United States)

    Tweney, Ryan D.

    2011-07-01

    James Clerk Maxwell `translated' Michael Faraday's experimentally-based field theory into the mathematical representation now known as `Maxwell's Equations.' Working with a variety of mathematical representations and physical models Maxwell extended the reach of Faraday's theory and brought it into consistency with other results in the physics of electricity and magnetism. Examination of Maxwell's procedures opens many issues about the role of mathematical representation in physics and the learning background required for its success. Specifically, Maxwell's training in `Cambridge University' mathematical physics emphasized the use of analogous equations across fields of physics and the repeated solving of extremely difficult problems in physics. Such training develops an array of overlearned mathematical representations supported by highly sophisticated cognitive mechanisms for the retrieval of relevant information from long term memory. For Maxwell, mathematics constituted a new form of representation in physics, enhancing the formal derivational and calculational role of mathematics and opening a cognitive means for the conduct of `experiments in the mind' and for sophisticated representations of theory.

  7. Enhancement of methylbenzene adsorption capacity through cetyl trimethyl ammonium bromide-modified activated carbon derived from Astragalus residue

    Science.gov (United States)

    Feng, Ningchuan; Zhang, Yumei; Fan, Wei; Zhu, Meilin

    2018-02-01

    Activated carbon was prepared from astragalus residue by KOH and then treated with cetyl trimethyl ammonium bromide (CTAB) and used for the removal of methylbenzene from aqueous solution. The samples were characterized by FTIR, XRD, SEM and Boehm titration. The results showed that CTAB changed the physicochemical properties of activated carbon significantly. The isotherm adsorption studies of methylbenzene onto the astragalus residue activated carbon (ASC) and CTAB-modified astragalus residue activated carbon (ASCCTAB) were examined by using batch techniques and agreed well with the Langmuir model. The maximum adsorption capacity of ASC and ASC-CTAB for methylbenzene determined from the Langmuir model was183.56 mg/g and 235.18 mg/g, respectively. The results indicated that using CTAB as a modifier for ASC modification could markedly enhance the methylbenzene removal from water.

  8. Assembling gold nanorods on a poly-cysteine modified glassy carbon electrode strongly enhance the electrochemical response to tetrabromobisphenol A

    International Nuclear Information System (INIS)

    Wang, Yanying; Liu, Guishen; Hou, Xiaodong; Huang, Yina; Li, Chunya; Wu, Kangbing

    2016-01-01

    Cysteine (Cys) was electrochemically deposited on a glassy carbon electrode (GCE) by cyclic voltammetry. The poly-Cys modified electrode was placed in a solution of gold nanorods (GNRs) to induced self-assembly of the GNRs. The GNRs/poly-Cys/GCEs were characterized by scanning electron microscopy and electrochemical impedance spectroscopy. A voltammetric study on tetrabromobisphenol A (TBBPA) with this GCE showed the current response to be enhanced by a factor of 11 compared to a non-modified GCE. Based on these findings, a square wave voltammetric assay was worked out. Under optimized conditions, a linear relationship between the oxidation peak current and TBBPA is found for the 10 nM to 10 μM concentration range. The detection limit is 3.2 nM (at an S/N ratio of 3). The electrode was successfully applied to the determination of TBBPA in spiked tap water and lake water samples. (author)

  9. Adaptive Multiscale Noise Control Enhanced Stochastic Resonance Method Based on Modified EEMD with Its Application in Bearing Fault Diagnosis

    Directory of Open Access Journals (Sweden)

    Jimeng Li

    2016-01-01

    Full Text Available The structure of mechanical equipment becomes increasingly complex, and tough environments under which it works often make bearings and gears subject to failure. However, effective extraction of useful feature information submerged in strong noise that is indicative of structural defects has remained a major challenge. Therefore, an adaptive multiscale noise control enhanced stochastic resonance (SR method based on modified ensemble empirical mode decomposition (EEMD for mechanical fault diagnosis is proposed in the paper. According to the oscillation characteristics of signal itself, the algorithm of modified EEMD can adaptively decompose the fault signals into different scales and it reduces the decomposition levels to improve calculation efficiency of the proposed method. Through filter processing with the constructed filters, the orthogonality of adjacent intrinsic mode functions (IMFs can be improved, which is conducive to enhancing the extraction of weak features from strong noise. The constructed signal obtained by using IMFs is inputted into the SR system, and the noise control parameter of different scales is optimized and selected with the help of the genetic algorithm, thus achieving the enhancement extraction of weak features. Finally, simulation experiments and engineering application of bearing fault diagnosis demonstrate the effectiveness and feasibility of the proposed method.

  10. Enhanced specific capacitance of modified needle cokes by controlling oxidation treatment

    International Nuclear Information System (INIS)

    Yang, Sunhye; Kim, Ick-Jun; Choi, In-Sik; Soo Kim, Hyun; Tack Kim, Yu

    2010-01-01

    The electric double-layer performance of needle cokes can be affected by the morphology of structures. Hence, we introduce modified needle cokes by using simple oxidation treatment. The degree of graphitization with high specific capacitance is controlled by acid and heat treatment. The active sites of cokes are increased with increasing oxidation time. Dilute nitric acid (HNO 3 ) and sodium chlorate (NaClO 3 ) are used for the activation of cokes. In this case, the interlayer distance is dramatically increased from 3.5 to 8.9 A. The specific capacitances are 33 F g -1 and 30 F ml -1 , respectively, on a two-electrode system with a potential range of 0-2.5 V. The behaviors of double-layer capacitance are demonstrated by the charge-discharge process and the morphologies of modified needle cokes are analyzed by XRD, FE-SEM, BET and elemental analysis.

  11. Preparation of Phosphonic Acid Functionalized Graphene Oxide-modified Aluminum Powder with Enhanced Anticorrosive Properties

    Science.gov (United States)

    He, Lihua; Zhao, Yan; Xing, Liying; Liu, Pinggui; Wang, Zhiyong; Zhang, Youwei; Liu, Xiaofang

    2017-07-01

    To improve the anticorrosive performance of aluminum powder, a common functional filler in polymer coatings, we report a novel method to prepare graphene oxide modified aluminum powder (GO-Al) using 3-aminoproplyphosphoic acid as "link" agent. The GO nanosheets were firstly functionalized with 3-aminoproplyphosphoic acid (APSA) by the reaction of amine groups of APSA and the epoxy groups of GO. Subsequently, a layer of GO nanosheets uniformly and tightly covered the surface of flaky aluminum particle though the strong linking strength between -PO(OH)2 functional groups of the modified GO and aluminum. The hydrogen evolution experiment suggests that the GO attached on the aluminum powder could effectively improve the anticorrosive performance of the pigments.

  12. Effect of imperfect Faraday mirrors on the security of a Faraday–Michelson quantum cryptography system

    International Nuclear Information System (INIS)

    Wang, Wei-Long; Gao, Ming; Ma, Zhi

    2013-01-01

    The one-way Faraday–Michelson system is a very useful practical quantum cryptography system where Faraday mirrors (FMs) play an important role. In this paper we analyze the security of this system against imperfect FMs. We consider the security loophole caused by imperfect FMs in Alice’s and Bob’s security zones. Then we implement a passive FM attack in this system. By changing the values of the imperfection parameters of Alice’s FMs, we calculate the quantum bit error rate between Alice and Bob induced by Eve and the probability that Eve obtains outcomes successfully. It is shown that the imperfection of one of Alice’s two FMs makes the system sensitive to an attack. Finally we give a modified key rate as a function of the FM imperfections. The security analysis indicates that both Alice’s and Bob’s imperfect FMs can compromise the secure key. (paper)

  13. Mimicking Faraday rotation to sort the orbital angular momentum of light.

    Science.gov (United States)

    Zhang, Wuhong; Qi, Qianqian; Zhou, Jie; Chen, Lixiang

    2014-04-18

    The efficient separation of the orbital angular momentum (OAM) is essential to both the classical and quantum applications with twisted photons. Here we devise and demonstrate experimentally an efficient method of mimicking the Faraday rotation to sort the OAM based on the OAM-to-polarization coupling effect induced by a modified Mach-Zehnder interferometer. Our device is capable of sorting the OAM of positive and negative numbers, as well as their mixtures. Furthermore, we report the first experimental demonstration to sort optical vortices of noninteger charges. The possibility of working at the photon-count level is also shown using an electron-multiplying CCD camera. Our scheme holds promise for quantum information applications with single-photon entanglement and for high-capacity communication systems with polarization and OAM multiplexing.

  14. Highly selective and sensitive detection of Cu2+ with lysine enhancing bovine serum albumin modified-carbon dots fluorescent probe.

    Science.gov (United States)

    Liu, Jia-Ming; Lin, Li-ping; Wang, Xin-Xing; Lin, Shao-Qin; Cai, Wen-Lian; Zhang, Li-Hong; Zheng, Zhi-Yong

    2012-06-07

    Based on the ability of lysine (Lys) to enhance the fluorescence intensity of bovine serum albumin modified-carbon dots (CDs-BSA) to decrease surface defects and quench fluorescence of the CDs-BSA-Lys system in the presence of Cu(2+) under conditions of phosphate buffer (PBS, pH = 5.0) at 45 °C for 10 min, a sensitive Lys enhancing CDs-BSA fluorescent probe was designed. The environment-friendly, simple, rapid, selective and sensitive fluorescent probe has been utilized to detect Cu(2+) in hair and tap water samples and it achieved consistent results with those obtained by inductively coupled plasma mass spectroscopy (ICP-MS). The mechanism of the proposed assay for the detection of Cu(2+) is discussed.

  15. Aflatoxin Toxicity Reduction in Feed by Enhanced Binding to Surface-Modified Clay Additives

    Science.gov (United States)

    Jaynes, William F.; Zartman, Richard E.

    2011-01-01

    Animal feeding studies have demonstrated that clay additives, such as bentonites, can bind aflatoxins in ingested feed and reduce or eliminate the toxicity. Bentonite deposits are found throughout the world and mostly consist of expandable smectite minerals, such as montmorillonite. The surfaces of smectite minerals can be treated with organic compounds to create surface-modified clays that more readily bind some contaminants than the untreated clay. Montmorillonites treated with organic cations, such as hexadecyltrimethylammonium (HDTMA) and phenyltrimethylammonium (PTMA), more effectively remove organic contaminants, such as benzene and toluene, from water than untreated clay. Similarly, montmorillonite treated with PTMA (Kd = 24,100) retained more aflatoxin B1 (AfB1) from aqueous corn flour than untreated montmorillonite (Kd = 944). Feed additives that reduced aflatoxin toxicity in animal feeding studies adsorbed more AfB1 from aqueous corn flour than feed additives that were less effective. The organic cations HDTMA and PTMA are considered toxic and would not be suitable for clay additives used in feed or food, but other non-toxic or nutrient compounds can be used to prepare surface-modified clays. Montmorillonite (SWy) treated with choline (Kd = 13,800) and carnitine (Kd = 3960) adsorbed much more AfB1 from aqueous corn flour than the untreated clay (Kd = 944). A choline-treated clay prepared from a reduced-charge, high-charge montmorillonite (Kd = 20,100) adsorbed more AfB1 than the choline-treated high-charge montmorillonite (Kd = 1340) or the untreated montmorillonite (Kd = 293). Surface-modified clay additives prepared using low-charge smectites and nutrient or non-toxic organic compounds might be used to more effectively bind aflatoxins in contaminated feed or food and prevent toxicity. PMID:22069725

  16. Depth of focus enhancement of a modified imaging quasi-fractal zone plate.

    Science.gov (United States)

    Zhang, Qinqin; Wang, Jingang; Wang, Mingwei; Bu, Jing; Zhu, Siwei; Gao, Bruce Z; Yuan, Xiaocong

    2012-10-01

    We propose a new parameter w for optimization of foci distribution of conventional fractal zone plates (FZPs) with a greater depth of focus (DOF) in imaging. Numerical simulations of DOF distribution on axis directions indicate that the values of DOF can be extended by a factor of 1.5 or more by a modified quasi-FZP. In experiments, we employ a simple object-lens-image-plane arrangement to pick up images at various positions within the DOF of a conventional FZP and a quasi-FZP, respectively. Experimental results show that the parameter w improves foci distribution of FZPs in good agreement with theoretical predictions.

  17. Combined use of vancomycin-modified Ag-coated magnetic nanoparticles and secondary enhanced nanoparticles for rapid surface-enhanced Raman scattering detection of bacteria.

    Science.gov (United States)

    Wang, Chongwen; Gu, Bing; Liu, Qiqi; Pang, Yuanfeng; Xiao, Rui; Wang, Shengqi

    2018-01-01

    Pathogenic bacteria have always been a significant threat to human health. The detection of pathogens needs to be rapid, accurate, and convenient. We present a sensitive surface-enhanced Raman scattering (SERS) biosensor based on the combination of vancomycin-modified Ag-coated magnetic nanoparticles (Fe 3 O 4 @Ag-Van MNPs) and Au@Ag nanoparticles (NPs) that can effectively capture and discriminate bacterial pathogens from solution. The high-performance Fe 3 O 4 @Ag MNPs were modified with vancomycin and used as bacteria capturer for magnetic separation and enrichment. The modified MNPS were found to exhibit strong affinity with a broad range of Gram-positive and Gram-negative bacteria. After separating and rinsing bacteria, Fe 3 O 4 @Ag-Van MNPs and Au@Ag NPs were synergistically used to construct a very large number of hot spots on bacteria cells, leading to ultrasensitive SERS detection. The dominant merits of our dual enhanced strategy included high bacterial-capture efficiency (>65%) within a wide pH range (pH 3.0-11.0), a short assay time (<30 min), and a low detection limit (5×10 2 cells/mL). Moreover, the spiked tests show that this method is still valid in milk and blood samples. Owing to these capabilities, the combined system enabled the sensitive and specific discrimination of different pathogens in complex solution, as verified by its detection of Gram-positive bacterium Escherichia coli , Gram-positive bacterium Staphylococcus aureus , and methicillin-resistant S. aureus . This method has great potential for field applications in food safety, environmental monitoring, and infectious disease diagnosis.

  18. When Does Testing Enhance Retention? A Distribution-Based Interpretation of Retrieval as a Memory Modifier

    Science.gov (United States)

    Halamish, Vered; Bjork, Robert A.

    2011-01-01

    Tests, as learning events, can enhance subsequent recall more than do additional study opportunities, even without feedback. Such advantages of testing tend to appear, however, only at long retention intervals and/or when criterion tests stress recall, rather than recognition, processes. We propose that the interaction of the benefits of testing…

  19. Performance enhancement in organic photovoltaic solar cells using iridium (Ir) ultra-thin surface modifier (USM)

    Science.gov (United States)

    Pandey, Rina; Lim, Ju Won; Kim, Jung Hyuk; Angadi, Basavaraj; Choi, Ji Won; Choi, Won Kook

    2018-06-01

    In this study, Iridium (Ir) metallic layer as an ultra-thin surface modifier (USM) was deposited on ITO coated glass substrate using radio frequency magnetron sputtering for improving the photo-conversion efficiency of organic photovoltaic cells. Ultra-thin Ir acts as a surface modifier replacing the conventional hole transport layer (HTL) PEDOT:PSS in organic photovoltaic (OPV) cells with two different active layers P3HT:PC60BM and PTB7:PC70BM. The Ir USM (1.0 nm) coated on ITO glass substrate showed transmittance of 84.1% and work function of >5.0 eV, which is higher than that of ITO (4.5-4.7 eV). The OPV cells with Ir USM (1.0 nm) exhibits increased power conversion efficiency of 3.70% (for P3HT:PC60BM active layer) and 7.28% (for PTB7:PC70BM active layer) under 100 mW/cm2 illumination (AM 1.5G) which are higher than those of 3.26% and 6.95% for the same OPV cells but with PEDOT:PSS as HTL instead of Ir USM. The results reveal that the chemically stable Ir USM layer could be used as an alternative material for PEDOT:PSS in organic photovoltaic cells.

  20. Enhanced Thermal Conductivity of Polyimide Composites Filled with Modified h-BN and Nanodiamond Hybrid Filler.

    Science.gov (United States)

    Yang, Xi; Yu, Xiaoyan; Naito, Kimiyoshi; Ding, Huili; Qu, Xiongwei; Zhang, Qingxin

    2018-05-01

    A new thermally conductive and electrically insulative polyimide were prepared by filling different amounts of hexagonal boron nitride (h-BN) particles, and the thermal conductivity of Polyimide (PI) composites were improved with the increasing h-BN content. Based on this, two methods were applied to improve thermal conductivity furtherly at limited filler loading in this paper. One is modifying the h-BN to improve interface interaction, another is fabricating a nano-micro hybrid filler with 2-D h-BN and 0-D nano-scale nanodiamond (ND) to build more effective conductive network. Both surface modification and hybrid system have a positive effect on thermal conductivity. The composites introducing 40 wt% hybrid filler (the weight ratio of ND/modified BN was 1/10) showed the highest thermal conductivity, being up to 0.98 W/(m K) (5.2 times that of PI). In addition, the composites exhibits excellent electrical insulation, thermal stability properties etc.

  1. Enhancing adsorption capacity of toxic malachite green dye through chemically modified breadnut peel: equilibrium, thermodynamics, kinetics and regeneration studies.

    Science.gov (United States)

    Chieng, Hei Ing; Lim, Linda B L; Priyantha, Namal

    2015-01-01

    Breadnut skin, in both its unmodified (KS) and base-modified (BM-KS) forms, was investigated for its potential use as a low-cost adsorbent for the removal of toxic dye, malachite green (MG). Characterization of the adsorbents was carried out using scanning electron microscope, X-ray fluorescence and Fourier transform infra-red spectroscopy. Batch adsorption experiments, carried out under optimized conditions, for the adsorption of MG were fitted using five isotherm models (Langmuir, Freundlich, Dubinin-Radushkevich, Temkin and Sips) and six error functions to determine the best-fit model. The adsorption capacity was greatly enhanced when breadnut skin was chemically modified with NaOH, leading to an adsorption capacity of 353.0 mg g(-1), that was far superior to most reported adsorbents for the removal of MG. Thermodynamics studies indicated that the adsorption of MG was spontaneous on KS and BM-KS, and the reactions were endothermic and exothermic, respectively. Kinetics studies showed that both followed the pseudo-second order. Regeneration experiments on BM-KS indicated that its adsorption capacity was still maintained at>90% even after five cycles. It can be concluded that NaOH-modified breadfruit skin has great potential to be utilized in real-life application as a low-cost adsorbent for the removal of MG in wastewater treatment.

  2. Enhancing the Detection of Dysmorphic Red Blood Cells and Renal Tubular Epithelial Cells with a Modified Urinalysis Protocol.

    Science.gov (United States)

    Chu-Su, Yu; Shukuya, Kenichi; Yokoyama, Takashi; Lin, Wei-Chou; Chiang, Chih-Kang; Lin, Chii-Wann

    2017-01-11

    Urinary sediment is used to evaluate patients with possible urinary tract diseases. Currently, numerous protocols are applied to detect dysmorphic red blood cells (RBCs) and renal tubular epithelial cells (RTECs) in urinary sediment. However, distinct protocols are used by nephrologists and medical technologists for specimen concentration and observation, which leads to major discrepancies in the differential counts of formed elements such as dysmorphic RBCs and RTECs and might interfere with an accurate clinical diagnosis. To resolve these problems, we first tested a modified urinalysis protocol with an increased relative centrifuge force and concentration factor in 20 biopsy-confirmed glomerulonephritis patients with haematuria. We successfully improved the recovery ratio of dysmorphic RBCs in clinical specimens from 34.7% to 42.0% (P dysmorphic RBCs were detected using a bright field microscope, with results comparable to those using a standard phase contrast microscope. Finally, we applied Sternheimer stain to enhance the contrast of RTECs in the urinary sediments. We concluded that this modified urinalysis protocol significantly enhanced the quality of urinalysis.

  3. Plasma polarimetry for large Cotton--Mouton and Faraday effects

    International Nuclear Information System (INIS)

    Segre, S.E.

    1995-01-01

    A formalism is presented for treating plasma polarimetry when both the Cotton--Mouton and the Faraday effects are large. For this general case it is shown that, for each measuring chord, up to nine parameters related to the plasma can be determined, instead of the usual single Faraday rotation. These parameters can be measured by a convenient modulation of the polarization state of the input radiation, and they can be used in the reconstruction of the magnetohydrodynamic equilibrium. Thus, the potential of the polarimetric diagnostic can be significantly increased, and the range of plasma conditions where the latter can be used, is extended. The importance of refraction is discussed. copyright 1995 American Institute of Physics

  4. CRADA Final Report, 2011S003, Faraday Technologies

    International Nuclear Information System (INIS)

    Faraday Technologies

    2012-01-01

    This Phase I SBIR program addressed the need for an improved manufacturing process for electropolishing niobium RF superconducting cavities for the International Linear Collider (ILC). The ILC is a proposed particle accelerator that will be used to gain a deeper understanding of the forces of energy and matter by colliding beams of electrons and positrons at nearly the speed of light. The energy required for this to happen will be achieved through the use of advanced superconducting technology, specifically ∼16,000 RF superconducting cavities operating at near absolute zero. The RF superconductor cavities will be fabricated from highly pure Nb, which has an extremely low surface resistance at 2 Kelvin when compared to other materials. To take full advantage of the superconducting properties of the Nb cavities, the inner surface must be a) polished to a microscale roughness < 0.1 µm with removal of at least 100 µm of material, and b) cleaned to be free of impurities that would degrade performance of the ILC. State-of-the-art polishing uses either chemical polishing or electropolishing, both of which require hydrofluoric acid to achieve breakdown of the strong passive film on the surface. In this Phase I program, Faraday worked with its collaborators at the Thomas Jefferson National Accelerator Facility (JLab) to demonstrate the feasibility of an electropolishing process for pure niobium, utilizing an environmentally benign alternative to chemical or electrochemical polishing electrolytes containing hydrofluoric acid. Faraday utilized a 31 wt% aqueous sulfuric acid solution (devoid of hydrofluoric acid) in conjunction with the FARADAYICSM Process, which uses pulse/pulse reverse fields for electropolishing, to demonstrate the ability to electropolish niobium to the desired surface finish. The anticipated benefits of the FARADAYICSM Electropolishing process will be a simpler, safer, and less expensive method capable of surface finishing high purity niobium cavities

  5. Faraday rotation measurements in maghemite-silica aerogels

    International Nuclear Information System (INIS)

    Taboada, E.; Real, R.P. del; Gich, M.; Roig, A.; Molins, E.

    2006-01-01

    Faraday rotation measurements have been performed on γ-Fe 2 O 3 /SiO 2 nanocomposite aerogels which are light, porous and transparent magnetic materials. The materials have been prepared by sol-gel polymerization of a silicon alkoxide, impregnation of the intermediate silica gel with a ferrous salt and supercritical drying of the gels. During supercritical evacuation of the solvent, spherical nanoparticles of iron oxide, with a mean particle diameter of 8.1±2.0 nm, are formed and are found to be homogenously distributed within the silica matrix. The specific Faraday rotation of the composite was measured at 0.6 T using polarized light of 810 nm, being 29.6 deg./cm. The changes in the plane of polarization of the transmitted light and the magnetization of the material present similar magnetic field dependencies and are characteristic of a superparamagnetic system

  6. An optimized Faraday cage design for electron beam current measurements

    International Nuclear Information System (INIS)

    Turner, J.N.; Hausner, G.G.; Parsons, D.F.

    1975-01-01

    A Faraday cage detector is described for measuring electron beam intensity for use with energies up to 1.2 Mev, with the present data taken at 100 keV. The design features a readily changeable limiting aperture and detector cup geometry, and a secondary electron suppression grid. The detection efficiency of the cage is shown to be limited only by primary backscatter through the detector solid angle of escape, which is optimized with respect to primary backscattered electrons and secondary electron escape. The geometry and stopping material of the detection cup are varied, and the results show that for maximum detection efficiency with carbon as the stopping mateiral, the solid angle of escape must be equal to or less than 0.05πsr. The experimental results are consistent within the +-2% accuracy of the detection electronics, and are not limited by the Faraday cage detection efficiency. (author)

  7. Non-destructive Faraday imaging of dynamically controlled ultracold atoms

    Science.gov (United States)

    Gajdacz, Miroslav; Pedersen, Poul; Mørch, Troels; Hilliard, Andrew; Arlt, Jan; Sherson, Jacob

    2013-05-01

    We investigate non-destructive measurements of ultra-cold atomic clouds based on dark field imaging of spatially resolved Faraday rotation. In particular, we pursue applications to dynamically controlled ultracold atoms. The dependence of the Faraday signal on laser detuning, atomic density and temperature is characterized in a detailed comparison with theory. In particular the destructivity per measurement is extremely low and we illustrate this by imaging the same cloud up to 2000 times. The technique is applied to avoid the effect of shot-to-shot fluctuations in atom number calibration. Adding dynamic changes to system parameters, we demonstrate single-run vector magnetic field imaging and single-run spatial imaging of the system's dynamic behavior. The method can be implemented particularly easily in standard imaging systems by the insertion of an extra polarizing beam splitter. These results are steps towards quantum state engineering using feedback control of ultracold atoms.

  8. Faraday waves in a Hele-Shaw cell

    Science.gov (United States)

    Li, Jing; Li, Xiaochen; Chen, Kaijie; Xie, Bin; Liao, Shijun

    2018-04-01

    We investigate Faraday waves in a Hele-Shaw cell via experimental, numerical, and theoretical studies. Inspired by the Kelvin-Helmholtz-Darcy theory, we develop the gap-averaged Navier-Stokes equations and end up with the stable standing waves with half frequency of the external forced vibration. To overcome the dependency of a numerical model on the experimental parameter of wave length, we take two-phase flow into consideration and a novel dispersion relation is derived. The numerical results compare well with our experimental data, which effectively validates our proposed mathematical model. Therefore, this model can produce robust solutions of Faraday wave patterns and resolve related physical phenomena, which demonstrates the practical importance of the present study.

  9. Resonant microsphere gyroscope based on a double Faraday rotator system.

    Science.gov (United States)

    Xie, Chengfeng; Tang, Jun; Cui, Danfeng; Wu, Dajin; Zhang, Chengfei; Li, Chunming; Zhen, Yongqiu; Xue, Chenyang; Liu, Jun

    2016-10-15

    The resonant microsphere gyroscope is proposed based on a double Faraday rotator system for the resonant microsphere gyroscope (RMSG) that is characterized by low insertion losses and does not destroy the reciprocity of the gyroscope system. Use of the echo suppression structure and the orthogonal polarization method can effectively inhibit both the backscattering noise and the polarization error, and reduce them below the system sensitivity limit. The resonance asymmetry rate dropped from 34.2% to 2.9% after optimization of the backscattering noise and the polarization noise, which greatly improved the bias stability and the scale factor linearity of the proposed system. Additionally, based on the optimum parameters for the double Faraday rotator system, a bias stability of 0.04°/s has been established for an integration time of 10 s in 1000 s in a resonator microsphere gyroscope using a microsphere resonator with a diameter of 1 mm and a Q of 7.2×106.

  10. A variable suppressed aperture and Faraday cup system

    International Nuclear Information System (INIS)

    Price, H.G.; Charlesworth, T.R.

    1979-02-01

    The injection system of the NSF accelerator within the high voltage enclosure is illustrated. The optics calls for a waist close to the entrance of the 500 kV accelerator tube. This waist will be the initial diagnostic point on the injection path for determining ion source performance and transmission through the later system. This will be made by determining the beam current after a preliminary mass analysis by the 30 0 magnet. To provide this diagnostic and to enable a waist to be formed at this point, a variable aperture and Faraday cup system is required. The Faraday cup will measure the beam transmitted by the aperture. Maximisation of this beam by adjustment of the preceding optical elements will ensure the waist in the beam at that point. (author)

  11. A Faraday effect position sensor for interventional magnetic resonance imaging.

    Science.gov (United States)

    Bock, M; Umathum, R; Sikora, J; Brenner, S; Aguor, E N; Semmler, W

    2006-02-21

    An optical sensor is presented which determines the position and one degree of orientation within a magnetic resonance tomograph. The sensor utilizes the Faraday effect to measure the local magnetic field, which is modulated by switching additional linear magnetic fields, the gradients. Existing methods for instrument localization during an interventional MR procedure often use electrically conducting structures at the instruments that can heat up excessively during MRI and are thus a significant danger for the patient. The proposed optical Faraday effect position sensor consists of non-magnetic and electrically non-conducting components only so that heating is avoided and the sensor could be applied safely even within the human body. With a non-magnetic prototype set-up, experiments were performed to demonstrate the possibility of measuring both the localization and the orientation in a magnetic resonance tomograph. In a 30 mT m(-1) gradient field, a localization uncertainty of 1.5 cm could be achieved.

  12. Faraday Rotator 5 kV Capacitor Bank

    International Nuclear Information System (INIS)

    Fetterman, C.C.

    1975-01-01

    A Faraday rotator 5 kV capacitor bank is a pulsed output power supply used to energize Faraday rotators for optical isolation in the ''LLL kJ Glass Laser System.'' Each supply contains either one, two or three parallel 240 μF storage capacitors depending on the size of the isolator used. Generally, the ''A*''(216 μH) isolator is energized with one capacitor, the ''A''(116 μH) isolator uses two capacitors and the ''B''(87 μH) isolator requires three capacitors. All models of isolators have been tested with four capacitors under maximum voltage and 25 feet of RG-217 cable with no hazardous effects. Except for the number of capacitors in each unit, the supplies are otherwise physically identical

  13. Comparison of transient severe motion in gadoxetate disodium and gadopentetate dimeglumine-enhanced MRI. Effect of modified breath-holding method

    International Nuclear Information System (INIS)

    Song, Ji Soo; Choi, Eun Jung; Park, Eun Hae; Lee, Ju-Hyung

    2018-01-01

    To compare the occurrence of transient severe motion (TSM) between gadoxetate disodium- and gadopentetate dimeglumine-enhanced MRI and between gadoxetate disodium-enhanced MRI scans obtained with and without the application of a modified breath-holding technique. We reviewed 80 patients who underwent two magnetic resonance examinations (gadoxetate disodium-enhanced MRI and gadopentetate dimeglumine-enhanced MRI) with the application of a modified breath-holding technique (dual group). This group was compared with 100 patients who underwent gadoxetate disodium-enhanced MRI without the application of the modified breath-holding technique (single group). Patient risk factors and motion scores (1 [none] to 5 [non-diagnostic]) for each dynamic-phase imaging were analysed. In the dual group, mean motion scores did not differ significantly between gadoxetate disodium- and gadopentetate dimeglumine-enhanced MRI (p=0.096-0.807) in any phase. However, in all phases except the late dynamic phase, mean motion scores of the dual group were significantly lower than those in the single group. TSM incidence did not differ significantly between gadoxetate disodium- and gadopentetate dimeglumine-enhanced MRI in the dual group (3.8% vs. 1.3%, p=0.620). With proper application of the modified breath-holding technique, TSM occurrence with gadoxetate disodium-enhanced MRI was comparable to that associated with gadopentetate dimeglumine-enhanced MRI. (orig.)

  14. Comparison of transient severe motion in gadoxetate disodium and gadopentetate dimeglumine-enhanced MRI. Effect of modified breath-holding method

    Energy Technology Data Exchange (ETDEWEB)

    Song, Ji Soo; Choi, Eun Jung; Park, Eun Hae [Chonbuk National University Medical School and Hospital, Department of Radiology, Jeonju (Korea, Republic of); Research Institute of Clinical Medicine of Chonbuk National University, Jeonju (Korea, Republic of); Biomedical Research Institute of Chonbuk National University Hospital, Jeonju (Korea, Republic of); Lee, Ju-Hyung [Chonbuk National University Medical School, Department of Preventive Medicine, Jeonju (Korea, Republic of)

    2018-03-15

    To compare the occurrence of transient severe motion (TSM) between gadoxetate disodium- and gadopentetate dimeglumine-enhanced MRI and between gadoxetate disodium-enhanced MRI scans obtained with and without the application of a modified breath-holding technique. We reviewed 80 patients who underwent two magnetic resonance examinations (gadoxetate disodium-enhanced MRI and gadopentetate dimeglumine-enhanced MRI) with the application of a modified breath-holding technique (dual group). This group was compared with 100 patients who underwent gadoxetate disodium-enhanced MRI without the application of the modified breath-holding technique (single group). Patient risk factors and motion scores (1 [none] to 5 [non-diagnostic]) for each dynamic-phase imaging were analysed. In the dual group, mean motion scores did not differ significantly between gadoxetate disodium- and gadopentetate dimeglumine-enhanced MRI (p=0.096-0.807) in any phase. However, in all phases except the late dynamic phase, mean motion scores of the dual group were significantly lower than those in the single group. TSM incidence did not differ significantly between gadoxetate disodium- and gadopentetate dimeglumine-enhanced MRI in the dual group (3.8% vs. 1.3%, p=0.620). With proper application of the modified breath-holding technique, TSM occurrence with gadoxetate disodium-enhanced MRI was comparable to that associated with gadopentetate dimeglumine-enhanced MRI. (orig.)

  15. Polymer as permeability modifier in porous media for enhanced oil recovery

    Science.gov (United States)

    Parsa, Shima; Weitz, David

    2017-11-01

    We use confocal microscopy to directly visualize the changes in morphology and mobilization of trapped oil ganglia within a 3D micromodel of porous media upon polymer flooding. Enhanced oil recovery is achieved in polymer flooding with large molecular weight at concentrations close or higher than a critical concentration of polymer. We also measure the fluctuations of the velocity of the displacing fluid and show that the velocities change upon polymer flooding in the whole medium. The changes in the fluid velocities are heterogeneous and vary in different pores, hence only providing enough pressure gradient across a few of the trapped oil ganglia and mobilize them. Our measurements show that polymer flooding is an effective method for enhancing oil recovery due to retention of polymer on the solid surfaces and changing the resistances of the available paths to water.

  16. Anomalous Faraday effect of a system with extraordinary optical transmittance.

    Science.gov (United States)

    Khanikaev, Alexander B; Baryshev, Alexander V; Fedyanin, Andrey A; Granovsky, Alexander B; Inoue, Mitsuteru

    2007-05-28

    It is shown theoretically that the Faraday rotation becomes anomalously large and exhibits extraordinary behavior near the frequencies of the extraordinary optical transmittance through optically thick perforated metal film with holes filled with a magneto-optically active material. This phenomenon is explained as result of strong confinement of the evanescent electromagnetic field within magnetic material, which occurs due to excitation of the coupled plasmon-polaritons on the opposite surfaces of the film.

  17. Sodium and potassium vapor Faraday filters revisited: theory and applications

    International Nuclear Information System (INIS)

    Harrell, S. D.; She, C.-Y.; Yuan Tao; Krueger, David A.; Chen, H.; Chen, S. S.; Hu, Z. L.

    2009-01-01

    A complete theory describing the transmission of atomic vapor Faraday filters is developed. The dependence of the filter transmission on atomic density and external magnetic field strength, as well as the frequency dependence of transmission, are explained in physical terms. As examples, applications of the computed results to ongoing research to suppress sky background, thus allowing Na lidar operation under sunlit conditions, and to enable measurement of the density of mesospheric oxygen atoms are briefly discussed

  18. Homogenized boundary conditions and resonance effects in Faraday cages

    OpenAIRE

    Hewett, DP; Hewitt, IJ

    2016-01-01

    We present a mathematical study of two-dimensional electrostatic and electromagnetic shielding by a cage of conducting wires (the so-called `Faraday cage e ect'). Taking the limit as the number of wires in the cage tends to in nity we use the asymptotic method of multiple scales to derive continuum models for the shielding, involving homogenized boundary conditions on an e ective cage boundary. We show how the resulting models depend on key cage parameters such as the...

  19. Faraday cage angled-etching of nanostructures in bulk dielectrics

    OpenAIRE

    Latawiec, Pawel; Burek, Michael J.; Sohn, Young-Ik; Lončar, Marko

    2016-01-01

    For many emerging optoelectronic materials, heteroepitaxial growth techniques do not offer the same high material quality afforded by bulk, single-crystal growth. However, the need for optical, electrical, or mechanical isolation at the nanoscale level often necessitates the use of a dissimilar substrate, upon which the active device layer stands. Faraday cage angled-etching (FCAE) obviates the need for these planar, thin-film technologies by enabling in-situ device release and isolation thro...

  20. A flat spectral Faraday filter for sodium lidar.

    Science.gov (United States)

    Yang, Yong; Cheng, Xuewu; Li, Faquan; Hu, Xiong; Lin, Xin; Gong, Shunsheng

    2011-04-01

    We report a flat spectral Faraday anomalous dispersion optical filter (FS-FADOF) for sodium lidar. The physical and technical considerations for obtaining a FS-FADOF with a 3.5 GHz flat spectral transmission function are presented. It was found that the effective transmission of this filter was much higher (>94%) and more uniform than that of the ultranarrowband FADOF, and therefore were less sensitive to laser-frequency drift. Thus, the FS-FADOF can improve lidar efficiency and precision.

  1. Oscillon dynamics and rogue wave generation in Faraday surface ripples.

    Science.gov (United States)

    Xia, H; Maimbourg, T; Punzmann, H; Shats, M

    2012-09-14

    We report new experimental results which suggest that the generation of extreme wave events in the Faraday surface ripples is related to the increase in the horizontal mobility of oscillating solitons (oscillons). The analysis of the oscillon trajectories in a horizontal plane shows that at higher vertical acceleration, oscillons move chaotically, merge and form enclosed areas on the water surface. The probability of the formation of such craters, which precede large wave events, increases with the increase in horizontal mobility.

  2. Titania nanotube arrays surface-modified with ZnO for enhanced photocatalytic applications

    Energy Technology Data Exchange (ETDEWEB)

    Nageri, Manoj; Kalarivalappil, Vijila; Vijayan, Baiju K.; Kumar, Viswanathan, E-mail: vkumar10@yahoo.co.in

    2016-05-15

    Highlights: • Heterostructures of TNA/ZnO synthesised through potentiostatic anodisation followed by hydrothermal method. • Evaluation of morphological features of the heterostructure with hydrothermal processing time. • Correlation of photocatalytic activity of the hetrostructure with its morphology and surface texture. - Abstract: Well ordered titanium dioxide nanotube arrays (TNA) of average diameter 129 nm and wall thickness of 25 nm were fabricated through potentiostatic anodisation of titanium (Ti) metal substrates. Such TNA were subsequently surface-modified with various amounts of zinc oxide (ZnO) nanopowders using hydrothermal technique to obtain heterogeneous TNA/ZnO nanostructures. The crystalline phase and surface microstructure of the heterostructures were determined by X-ray diffraction, Raman spectroscopy and scanning electron microscopy respectively. The morphology of the heterostructures strongly depended on the hydrothermal conditions employed. The photocatalytic activity of the heterostructures have also been investigated and correlated with their surface morphology and texture.

  3. Interfacial enhancement of polypropylene composites modified with sorbitol derivatives and siloxane-silsesquioxane resin

    Science.gov (United States)

    Dobrzyńska-Mizera, Monika; Dutkiewicz, Michał; Sterzyński, Tomasz; Di Lorenzo, Maria Laura

    2015-12-01

    Composites based on polypropylene (iPP) modified with a sorbitol derivative (NX8000) and siloxane-silsesquioxane resin (SiOPh) containing maleated polypropylene (MAPP) as compatibilizer were prepared by melt extrusion. Calorimetric investigations were carried out using differential scanning calorimetry (DSC), whereas the morphological and mechanical properties were investigated by scanning electron microscopy (SEM) and static tensile tests. DSC measurements revealed no influence of SiOPh and a slight effect of MAPP addition on the crystallization kinetics of polypropylene. Additionally, the introduction of MAPP into the iPP+NX8000+SiOPh composites increased plastic properties of the samples. All the above was attributed to the compatibilizing effect of MAPP which improved interfacial adhesion between iPP, NX8000 and SiOPh. This phenomenon was also confirmed by the SEM images illustrating more homogenous distribution of the filler in the compatibilized samples.

  4. Joule loss on a Faraday shield of JT-60 ICRF test antenna

    International Nuclear Information System (INIS)

    Fujii, Tsuneyuki; Saigusa, Mikio; Ikeda, Yoshitaka; Kimura, Haruyuki; Hirashima, Teruhisa; Uehara, Munenori.

    1988-01-01

    Joule loss on a Faraday shield of JT-60 ICRF test antenna with a conductive casing is investigated at the frequency range of 120 MHz. The magnetic field radiated from the antenna is measured by three-dimensionally scanning an rf probe both inside and outside the antenna casing. The magnetic field perpendicular to the Faraday shield, B x , is found to be the largest component near the Faraday shield. It consequently gives the major part of the joule loss on the Faraday shield. The temperature distribution of the Faraday shield due to joule loss is measured directly with a thermocamera. It is confirmed that the area of the high temperature rise is consistent with the peak positions of the B x field. Faraday shield resistance which is estimated from power measurements agrees with the theoretical value. (author)

  5. Faraday rotation dispersion microscopy imaging of diamagnetic and chiral liquids with pulsed magnetic field.

    Science.gov (United States)

    Suwa, Masayori; Nakano, Yusuke; Tsukahara, Satoshi; Watarai, Hitoshi

    2013-05-21

    We have constructed an experimental setup for Faraday rotation dispersion imaging and demonstrated the performance of a novel imaging principle. By using a pulsed magnetic field and a polarized light synchronized to the magnetic field, quantitative Faraday rotation images of diamagnetic organic liquids in glass capillaries were observed. Nonaromatic hydrocarbons, benzene derivatives, and naphthalene derivatives were clearly distinguished by the Faraday rotation images due to the difference in Verdet constants. From the wavelength dispersion of the Faraday rotation images in the visible region, it was found that the resonance wavelength in the UV region, which was estimated based on the Faraday B-term, could be used as characteristic parameters for the imaging of the liquids. Furthermore, simultaneous acquisition of Faraday rotation image and natural optical rotation image was demonstrated for chiral organic liquids.

  6. Simple theory of the inverse Faraday effect with relationship to optical constants N and K

    International Nuclear Information System (INIS)

    Yoshino, Toshihiko

    2011-01-01

    The inverse Faraday effect in general materials is theoretically investigated based on the classical motion of an electron. It is shown that the inverse Faraday effect is simply and explicitly expressed in terms of optical constants N and K, i.e., the real and imaginary parts of complex refractive index of materials. The derived new formula provides a good physical perspective for the inverse Faraday effect and enables its easy quantitative evaluation from familiar optical constants. - Highlights: → The theory of the inverse Faraday effect in general materials is presented based on the classical motion model of electron. → The simple relationship between optical constants of materials and the inverse Faraday effect is given. → The given new formula enables easy quantitative evaluation of the inverse Faraday effect from known optical constants.

  7. Effects of Faraday Rotation Observed in Filter Magnetograph Data

    Science.gov (United States)

    Hagyard, Mona J.; Adams, Mitzi L.; Smith, J. E.; West, Edward A.

    1999-01-01

    In this paper we analyze the effects of Faraday rotation on the azimuth of the transverse magnetic field from observations taken with the Marshall Space Flight Center's vector magnetograph for a simple sunspot observed on June 9, 1985. Vector magnetograms were obtained over the wavelength interval of 170 mA redward of line center of the Fe I 5250.22 A spectral line to 170 mA to the blue, in steps of 10 mA. These data were analyzed to produce the variation of the azimuth as a function of wavelength at each pixel over the field of vi ew of the sunspot. At selected locations in the sunspot, curves of the observed variation of azimuth with wavelength were compared with model calculations for the amount of Faraday rotation of the azimuth. From these comparisons we derived the amount of rotation as functions of bo th the magnitude and inclination of the sunspot's field and deduced the ranges of these field values for which Faraday rotation presents a significant problem in observations taken near the center of a spectral line.

  8. Development of an external Faraday cup for beam current measurements

    International Nuclear Information System (INIS)

    Kim, Kye-Ryung; Jung, Myung-Hwan; Ra, Se-Jin; Lee, Seok-Ki

    2010-01-01

    In general, beam current measurements are very important for many kinds of experiments using highly energetic particle beams at accelerators, such as cyclotrons, linacs, etc. The Faraday cup is known to be one of the most popular beam current measurement tools. We developed an external Faraday cup to measure the beam current at a dedicated beam line for low-flux experiments installed at the MC-50 cyclotron of Korea Institute of Radiological and Medical Sciences (KIRAMS). It was designed for external beam current measurements and is composed of a vacuum chamber, an entrance window, a collimator, a electrostatic suppressor ring, and a cup. The window is made of 75-um-thick Kapton film, and the diameter of the collimator is 10 mm or 20 mm. The ring and the cup has 5-cm inner diameters, and the thickness of the bottom of the cup is 2 cm, which is enough to absorb the total proton energy up to 45 MeV. Using this external Faraday cup, we measured the beam current from the cyclotron, and we compared measured flux to the results from film dosimetry using GAF films.

  9. Wave-particle interaction in the Faraday waves.

    Science.gov (United States)

    Francois, N; Xia, H; Punzmann, H; Shats, M

    2015-10-01

    Wave motion in disordered Faraday waves is analysed in terms of oscillons or quasi-particles. The motion of these oscillons is measured using particle tracking tools and it is compared with the motion of fluid particles on the water surface. Both the real floating particles and the oscillons, representing the collective fluid motion, show Brownian-type dispersion exhibiting ballistic and diffusive mean squared displacement at short and long times, respectively. While the floating particles motion has been previously explained in the context of two-dimensional turbulence driven by Faraday waves, no theoretical description exists for the random walk type motion of oscillons. It is found that the r.m.s velocity ⟨μ̃(osc)⟩(rms) of oscillons is directly related to the turbulent r.m.s. velocity ⟨μ̃⟩(rms) of the fluid particles in a broad range of vertical accelerations. The measured ⟨μ̃(osc)⟩(rms) accurately explains the broadening of the frequency spectra of the surface elevation observed in disordered Faraday waves. These results suggest that 2D turbulence is the driving force behind both the randomization of the oscillons motion and the resulting broadening of the wave frequency spectra. The coupling between wave motion and hydrodynamic turbulence demonstrated here offers new perspectives for predicting complex fluid transport from the knowledge of wave field spectra and vice versa.

  10. Development and first experimental tests of Faraday cup array.

    Science.gov (United States)

    Prokůpek, J; Kaufman, J; Margarone, D; Krůs, M; Velyhan, A; Krása, J; Burris-Mog, T; Busold, S; Deppert, O; Cowan, T E; Korn, G

    2014-01-01

    A new type of Faraday cup, capable of detecting high energy charged particles produced in a high intensity laser-matter interaction environment, has recently been developed and demonstrated as a real-time detector based on the time-of-flight technique. An array of these Faraday cups was designed and constructed to cover different observation angles with respect to the target normal direction. Thus, it allows reconstruction of the spatial distribution of ion current density in the subcritical plasma region and the ability to visualise its time evolution through time-of-flight measurements, which cannot be achieved with standard laser optical interferometry. This is a unique method for two-dimensional visualisation of ion currents from laser-generated plasmas. A technical description of the new type of Faraday cup is introduced along with an ad hoc data analysis procedure. Experimental results obtained during campaigns at the Petawatt High-Energy Laser for Heavy Ion Experiments (GSI, Darmstadt) and at the Prague Asterix Laser System (AS CR) are presented. Advantages and limitations of the used diagnostic system are discussed.

  11. Effects of interband transitions on Faraday rotation in metallic nanoparticles.

    Science.gov (United States)

    Wysin, G M; Chikan, Viktor; Young, Nathan; Dani, Raj Kumar

    2013-08-14

    The Faraday rotation in metallic nanoparticles is considered based on a quantum model for the dielectric function ϵ(ω) in the presence of a DC magnetic field B. We focus on effects in ϵ(ω) due to interband transitions (IBTs), which are important in the blue and ultraviolet for noble metals used in plasmonics. The dielectric function is found using the perturbation of the electron density matrix due to the optical field of the incident electromagnetic radiation. The calculation is applied to transitions between two bands (d and p, for example) separated by a gap, as one finds in gold at the L-point of the Fermi surface. The result of the DC magnetic field is a shift in the effective optical frequency causing IBTs by ±μBB/ħ, where opposite signs are associated with left/right circular polarizations. The Faraday rotation for a dilute solution of 17 nm diameter gold nanoparticles is measured and compared with both the IBT theory and a simpler Drude model for the bound electron response. Effects of the plasmon resonance mode on Faraday rotation in nanoparticles are also discussed.

  12. Midplane Faraday rotation: A densitometer for large tokamaks

    International Nuclear Information System (INIS)

    Jobes, F.C.; Mansfield, D.K.

    1992-01-01

    The density in a large tokamak such as International Thermonuclear Experimental Reactor (ITER), or any of the proposed future US machines, can be determined by measuring the Faraday rotation of a 10.6 μm laser directed tangent to the toroidal field. If there is a horizontal array of such beams, then n e (R) can be readily obtained with a simple Abel inversion about the center line of the tokamak. For a large machine, operated at a full field of 30 T m and a density of 2x10 20 /m 3 , the rotation angle would be quite large-about 60 degree for two passes. A layout in which a single laser beam is fanned out in the horizontal midplane of the tokamak, with a set of retroreflectors on the far side of the vacuum vessel, would provide good spatial resolution, depending only upon the number of reflectors. With this proposed layout, only one window would be needed. Because the rotation angle is never more than 1 ''fringe,'' the data is always good, and it is also a continuous measurement in time. Faraday rotation is dependent only upon the plasma itself, and thus is not sensitive to vibration of the optical components. Simulations of the expected results show that ITER, or any large tokamak, existing or proposed, would be well served even at low densities by a midplane Faraday rotation densitometer of ∼64 channels

  13. Application of a modified flux-coupling type superconducting fault current limiter to transient performance enhancement of micro-grid

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Lei, E-mail: stclchen1982@163.com [School of Electrical Engineering, Wuhan University, Wuhan 430072 (China); Zheng, Feng; Deng, Changhong; Li, Shichun; Li, Miao; Liu, Hui [School of Electrical Engineering, Wuhan University, Wuhan 430072 (China); Zhu, Lin [Department of Electrical Engineering and Computer Science, University of Tennessee, Knoxville 37996 (United States); Guo, Fang [Department of Substation, Guang Dong Electric Power Design Institute, Guangzhou 510663 (China)

    2015-11-15

    Highlights: • A modified flux-coupling type SFCL is suggested to enhance the transient performance of a micro-grid. • The SFCL’s main contribution is to improve the micro-grid’s fault ride-through capability. • The SFCL also can make the micro-grid carry out a smooth transition between its grid-connected and islanded modes. • The simulations show that the SFCL can availably strengthen the micro-grid’s voltage and frequency stability. - Abstract: Concerning the application and development of a micro-grid system which is designed to accommodate high penetration of intermittent renewable resources, one of the main issues is related to an increase in the fault-current level. It is crucial to ensure the micro-grid’s operational stability and service reliability when a fault occurs in the main network. In this paper, our research group suggests a modified flux-coupling type superconducting fault current limiter (SFCL) to enhance the transient performance of a typical micro-grid system. The SFCL is installed at the point of common coupling (PCC) between the main network and the micro-grid, and it is expected to actively improve the micro-grid’s fault ride-through capability. And for some specific faults, the micro-grid should disconnect from the main network, and the SFCL’s contribution is to make the micro-grid carry out a smooth transition between its grid-connected and islanded modes. Related theory derivation, technical discussion and simulation analysis are performed. From the demonstrated results, applying the SFCL can effectively limit the fault current, maintain the power balance, and enhance the voltage and frequency stability of the micro-grid.

  14. Application of a modified flux-coupling type superconducting fault current limiter to transient performance enhancement of micro-grid

    International Nuclear Information System (INIS)

    Chen, Lei; Zheng, Feng; Deng, Changhong; Li, Shichun; Li, Miao; Liu, Hui; Zhu, Lin; Guo, Fang

    2015-01-01

    Highlights: • A modified flux-coupling type SFCL is suggested to enhance the transient performance of a micro-grid. • The SFCL’s main contribution is to improve the micro-grid’s fault ride-through capability. • The SFCL also can make the micro-grid carry out a smooth transition between its grid-connected and islanded modes. • The simulations show that the SFCL can availably strengthen the micro-grid’s voltage and frequency stability. - Abstract: Concerning the application and development of a micro-grid system which is designed to accommodate high penetration of intermittent renewable resources, one of the main issues is related to an increase in the fault-current level. It is crucial to ensure the micro-grid’s operational stability and service reliability when a fault occurs in the main network. In this paper, our research group suggests a modified flux-coupling type superconducting fault current limiter (SFCL) to enhance the transient performance of a typical micro-grid system. The SFCL is installed at the point of common coupling (PCC) between the main network and the micro-grid, and it is expected to actively improve the micro-grid’s fault ride-through capability. And for some specific faults, the micro-grid should disconnect from the main network, and the SFCL’s contribution is to make the micro-grid carry out a smooth transition between its grid-connected and islanded modes. Related theory derivation, technical discussion and simulation analysis are performed. From the demonstrated results, applying the SFCL can effectively limit the fault current, maintain the power balance, and enhance the voltage and frequency stability of the micro-grid.

  15. Study of the Vertical Magnetic Field in Face-on Galaxies Using Faraday Tomography

    Science.gov (United States)

    Ideguchi, Shinsuke; Tashiro, Yuichi; Akahori, Takuya; Takahashi, Keitaro; Ryu, Dongsu

    2017-07-01

    Faraday tomography allows astronomers to probe the distribution of the magnetic field along the line of sight (LOS), but that can be achieved only after the Faraday spectrum is interpreted. However, the interpretation is not straightforward, mainly because the Faraday spectrum is complicated due to a turbulent magnetic field; it ruins the one-to-one relation between the Faraday depth and the physical depth, and appears as many small-scale features in the Faraday spectrum. In this paper, by employing “simple toy models” for the magnetic field, we describe numerically as well as analytically the characteristic properties of the Faraday spectrum. We show that the Faraday spectrum along “multiple LOSs” can be used to extract the global properties of the magnetic field. Specifically, considering face-on spiral galaxies and modeling turbulent magnetic field as a random field with a single coherence length, we numerically calculate the Faraday spectrum along a number of LOSs and its shape-characterizing parameters, that is, the moments. When multiple LOSs cover a region of ≳(10 coherence length)2, the shape of the Faraday spectrum becomes smooth and the shape-characterizing parameters are well specified. With the Faraday spectrum constructed as a sum of Gaussian functions with different means and variances, we analytically show that the parameters are expressed in terms of the regular and turbulent components of the LOS magnetic field and the coherence length. We also consider the turbulent magnetic field modeled with a power-law spectrum, and study how the magnetic field is revealed in the Faraday spectrum. Our work suggests a way to obtain information on the magnetic field from a Faraday tomography study.

  16. The Faraday effect in two-dimensional magneto-photonic crystals

    International Nuclear Information System (INIS)

    Merzlikin, A.M.; Vinogradov, A.P.; Inoue, M.; Khanikaev, A.B.; Granovsky, A.B.

    2006-01-01

    The necessary conditions for the observation of the Faraday effect in 2D magneto-photonic crystals are discussed. It is found. that the Faraday effect may be observed in the directions where any couple of the wave vectors of the harmonics consisting the Bloch waves of TE and TM solutions in zero magnetic field are identical. This direction corresponds neither to Faraday nor to Voigt geometry

  17. The Faraday effect in two-dimensional magneto-photonic crystals

    Energy Technology Data Exchange (ETDEWEB)

    Merzlikin, A.M. [Institute for Theoretical and Applied Electromagnetism, OIVT, Russian Academy of Sciences, Izhorskay 13/19, Moscow 125412 (Russian Federation)]. E-mail: merzlikin_a@mail.ru; Vinogradov, A.P. [Institute for Theoretical and Applied Electromagnetism, OIVT, Russian Academy of Sciences, Izhorskay 13/19, Moscow 125412 (Russian Federation); Inoue, M. [Department of Electrical and Electronic Engineering, Toyohashi University of Technology, 1-1, Hibari-Ga-Oka, Tempaku, Toyohashi 441-8580 (Japan); Khanikaev, A.B. [Department of Electrical and Electronic Engineering, Toyohashi University of Technology, 1-1, Hibari-Ga-Oka, Tempaku, Toyohashi 441-8580 (Japan); Granovsky, A.B. [Faculty of Physics, Lomonosov Moscow State University, Leninski Gory, Moscow 119992 (Russian Federation)

    2006-05-15

    The necessary conditions for the observation of the Faraday effect in 2D magneto-photonic crystals are discussed. It is found. that the Faraday effect may be observed in the directions where any couple of the wave vectors of the harmonics consisting the Bloch waves of TE and TM solutions in zero magnetic field are identical. This direction corresponds neither to Faraday nor to Voigt geometry.

  18. Thin Film Magnetless Faraday Rotators for Compact Heterogeneous Integrated Optical Isolators (Postprint)

    Science.gov (United States)

    2017-06-15

    AFRL-RX-WP-JA-2017-0348 THIN-FILM MAGNETLESS FARADAY ROTATORS FOR COMPACT HETEROGENEOUS INTEGRATED OPTICAL ISOLATORS (POSTPRINT) Dolendra Karki...Interim 9 May 2016 – 1 December 2016 4. TITLE AND SUBTITLE THIN-FILM MAGNETLESS FARADAY ROTATORS FOR COMPACT HETEROGENEOUS INTEGRATED OPTICAL...transfer of ultra-compact thin-film magnetless Faraday rotators to silicon photonic substrates. Thin films of magnetization latching bismuth

  19. Observation of two-dimensional Faraday waves in extremely shallow depth.

    Science.gov (United States)

    Li, Xiaochen; Yu, Zhengyue; Liao, Shijun

    2015-09-01

    A family of two-dimensional Faraday waves in extremely shallow depth (1 mm to 2 mm) of absolute ethanol are observed experimentally using a Hele-Shaw cell that vibrates vertically. The same phenomena are not observed by means of water, ethanol solution, and silicone oil. These Faraday waves are quite different from the traditional ones. These phenomena are helpful to deepen and enrich our understandings about Faraday waves, and besides provide a challenging problem for computational fluid dynamics.

  20. Study of the Vertical Magnetic Field in Face-on Galaxies Using Faraday Tomography

    International Nuclear Information System (INIS)

    Ideguchi, Shinsuke; Ryu, Dongsu; Tashiro, Yuichi; Takahashi, Keitaro; Akahori, Takuya

    2017-01-01

    Faraday tomography allows astronomers to probe the distribution of the magnetic field along the line of sight (LOS), but that can be achieved only after the Faraday spectrum is interpreted. However, the interpretation is not straightforward, mainly because the Faraday spectrum is complicated due to a turbulent magnetic field; it ruins the one-to-one relation between the Faraday depth and the physical depth, and appears as many small-scale features in the Faraday spectrum. In this paper, by employing “simple toy models” for the magnetic field, we describe numerically as well as analytically the characteristic properties of the Faraday spectrum. We show that the Faraday spectrum along “multiple LOSs” can be used to extract the global properties of the magnetic field. Specifically, considering face-on spiral galaxies and modeling turbulent magnetic field as a random field with a single coherence length, we numerically calculate the Faraday spectrum along a number of LOSs and its shape-characterizing parameters, that is, the moments. When multiple LOSs cover a region of ≳(10 coherence length) 2 , the shape of the Faraday spectrum becomes smooth and the shape-characterizing parameters are well specified. With the Faraday spectrum constructed as a sum of Gaussian functions with different means and variances, we analytically show that the parameters are expressed in terms of the regular and turbulent components of the LOS magnetic field and the coherence length. We also consider the turbulent magnetic field modeled with a power-law spectrum, and study how the magnetic field is revealed in the Faraday spectrum. Our work suggests a way to obtain information on the magnetic field from a Faraday tomography study.

  1. First measurement of poloidal-field-induced Faraday rotation in a tokamak plasma

    International Nuclear Information System (INIS)

    Kunz, W.; Association Euratom-CEA sur la Fusion, Centre d'Etudes Nucleaires de Fontenay-aux-Roses, 92

    1978-01-01

    Faraday rotation measurements using a ferrite modulation technique were performed on one channel of the 337 μm-interferometer on TFR. The experiment is intended as a preparatory step towards poloidal-field determination on the basis of the Faraday effect in a multi-channel configuration. The technical feasibility of precise Faraday rotation measurements under machine conditions is demonstrated. The measured rotation is unambiguously due to the poloidal magnetic field and agrees fairly with what can be estimated. (author)

  2. Nongenetically modified Lactococcus lactis-adjuvanted vaccination enhanced innate immunity against Helicobacter pylori.

    Science.gov (United States)

    Liu, Wei; Tan, Zhoulin; Liu, Hai; Zeng, Zhiqin; Luo, Shuanghui; Yang, Huimin; Zheng, Lufeng; Xi, Tao; Xing, Yingying

    2017-10-01

    Gram-positive enhancer matrix particles (GEM) produced by Lactococcus lactis can enhance vaccine-induced immune response. However, the mechanism under which this adjuvant mounts the efficacy of orally administered vaccines remains unexplored. We used a prophylactic mice model to investigate the mechanism of GEM-adjuvanted vaccination. Helicobacter pylori urease-specific antibody response was monitored and detected in murine serum by ELISA. Urease-specific splenic cytokine profile was examined. Gastric inflammatory responses were measured on day 43 or 71 by quantitative real-time PCR, flow cytometry and histology. We found that GEM enhanced the efficiency of oral H. pylori vaccine by promoting innate immunity. The vaccine CUE-GEM composed of GEM particles and recombinant antigen CTB-UE provided protection of immunized mice against H. pylori insult. The protective response was associated with induction of postimmunization gastritis and local Th1/Th17 cell-medicated immune response. We showed that innate inflammatory responses including neutrophil chemokines CXCL1-2, neutrophils, and antimicrobial proteins S100A8 and MUC1 were significantly elevated. Within all infected mice, S100A8 and MUC1 levels were negatively correlated with H. pylori burden. Strikingly, mice receiving GEM also show reduction of colonization, possibly through natural host response pathways to recruit CD4 + T cells and promote S100A8 expression. These findings suggest that GEM-based vaccine may impact Th1/Th17 immunity to orchestrate innate immune response against H. pylori infection. © 2017 John Wiley & Sons Ltd.

  3. Modified MIS-structure based on nanoporous silicon with enhanced sensitivity to the hydrogen containing gases

    Energy Technology Data Exchange (ETDEWEB)

    Gorbanyuk, T.; Evtukh, A.; Litovchenko, V.; Solntsev, V. [Institute of Semiconductor Physics, Kiev (Ukraine)

    2008-07-01

    The gas sensitivity of metal-insulator-semiconductor (MIS)-structures based on nanoporous silicon with active electrodes from palladium/tungsten oxide composite has been studied. It was found that the using of palladium/tungsten oxide composite (instead of thin palladium film) leads to enhanced sensitivity of MIS structures to hydrogen sulphide in air. The mechanism of this phenomenon has been established. The enhanced H{sub 2}S sensitivity is explained in the following way. The microparticles of tungsten trioxide inside palladium matrix stimulate the dissociation of hydrogen sulphide molecules, and hydrogen atoms and/or protons flow down to palladium surface, are absorbed by palladium volume, diffuse to palladium/oxidized nanoporous silicon interface. Hydrogen atoms adsorbed at the interface are polarized and give rise to a dipole layer. As a result, the voltage shift of the capacity-voltage (C-V) curve proportional to the measured gas concentration is observed. The surface microstructure of Pd/WO{sub 3} composite was studied by AFM microscopy. The chemical content of the composite film has been investigated by SIMS. It was found that the composite film on nanoporous silicon surface poses the holes with the size about 0.05 {mu}m, the mean separation between tungsten oxide microparticles is 1-2 {mu}m. It also was found that the using of the additional double layer polymer film (polymer film (phthalocyanine zinc)/semicon-ductor film (cadmium sulphide)) on composite film surface leads to the additional enhancement of the gas sensitivity to hydrogen sulphide. (copyright 2008 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  4. Modified field enhancement and extinction by plasmonic nanowire dimers due to nonlocal response

    DEFF Research Database (Denmark)

    Toscano, Giuseppe; Raza, Søren; Jauho, Antti-Pekka

    2012-01-01

    We study the effect of nonlocal optical response on the optical properties of metallic nanowires, by numerically implementing the hydrodynamical Drude model for arbitrary nanowire geometries. We first demonstrate the accuracy of our frequency-domain finite-element implementation by benchmarking...... it in a wide frequency range against analytical results for the extinction cross section of a cylindrical plasmonic nanowire. Our main results concern more complex geometries, namely cylindrical and bow-tie nanowire dimers that can strongly enhance optical fields. For both types of dimers we find that nonlocal...

  5. A novel Cs-(129)Xe atomic spin gyroscope with closed-loop Faraday modulation.

    Science.gov (United States)

    Fang, Jiancheng; Wan, Shuangai; Qin, Jie; Zhang, Chen; Quan, Wei; Yuan, Heng; Dong, Haifeng

    2013-08-01

    We report a novel Cs-(129)Xe atomic spin gyroscope (ASG) with closed-loop Faraday modulation method. This ASG requires approximately 30 min to start-up and 110 °C to operate. A closed-loop Faraday modulation method for measurement of the optical rotation was used in this ASG. This method uses an additional Faraday modulator to suppress the laser intensity fluctuation and Faraday modulator thermal induced fluctuation. We theoretically and experimentally validate this method in the Cs-(129)Xe ASG and achieved a bias stability of approximately 3.25 °∕h.

  6. Ultrafast magnetic vortex core switching driven by the topological inverse Faraday effect.

    Science.gov (United States)

    Taguchi, Katsuhisa; Ohe, Jun-ichiro; Tatara, Gen

    2012-09-21

    We present a theoretical discovery of an unconventional mechanism of inverse Faraday effect which acts selectively on topological magnetic structures. The effect, topological inverse Faraday effect, is induced by the spin Berry's phase of the magnetic structure when a circularly polarized light is applied. Thus a spin-orbit interaction is not necessary unlike that in the conventional inverse Faraday effect. We demonstrate by numerical simulation that topological inverse Faraday effect realizes ultrafast switching of a magnetic vortex within a switching time of 150 ps without magnetic field.

  7. Generalized Faraday law derived from classical forces in a rotating frame

    International Nuclear Information System (INIS)

    Choi, Taeseung

    2010-01-01

    We show that an additional spin-dependent classical force due to the rotation of an electron spin's rest frame is essential to derive a spin-Faraday law that has the same form as the usual Faraday law. We show that the contribution of the additional spin-dependent force to the spin-Faraday law is the same as the time derivative of the spin geometric phase. With this observations, the spin-Faraday law is generalized to include both an Aharonov-Casher (AC) effect and a scalar AC effect in a unified manner.

  8. Comparison of algorithms for determination of rotation measure and Faraday structure. I. 1100–1400 MHz

    International Nuclear Information System (INIS)

    Sun, X. H.; Akahori, Takuya; Anderson, C. S.; Farnes, J. S.; O’Sullivan, S. P.; Rudnick, L.; O’Brien, T.; Bell, M. R.; Bray, J. D.; Scaife, A. M. M.; Ideguchi, S.; Kumazaki, K.; Stepanov, R.; Stil, J.; Wolleben, M.; Takahashi, K.; Weeren, R. J. van

    2015-01-01

    Faraday rotation measures (RMs) and more general Faraday structures are key parameters for studying cosmic magnetism and are also sensitive probes of faint ionized thermal gas. A definition of which derived quantities are required for various scientific studies is needed, as well as addressing the challenges in determining Faraday structures. A wide variety of algorithms has been proposed to reconstruct these structures. In preparation for the Polarization Sky Survey of the Universe's Magnetism (POSSUM) to be conducted with the Australian Square Kilometre Array Pathfinder and the ongoing Galactic Arecibo L-band Feeds Array Continuum Transit Survey (GALFACTS), we run a Faraday structure determination data challenge to benchmark the currently available algorithms, including Faraday synthesis (previously called RM synthesis in the literature), wavelet, compressive sampling, and QU-fitting. The input models include sources with one Faraday thin component, two Faraday thin components, and one Faraday thick component. The frequency set is similar to POSSUM/GALFACTS with a 300 MHz bandwidth from 1.1 to 1.4 GHz. We define three figures of merit motivated by the underlying science: (1) an average RM weighted by polarized intensity, RM wtd , (2) the separation Δϕ of two Faraday components, and (3) the reduced chi-squared χ r 2 . Based on the current test data with a signal-to-noise ratio of about 32, we find the following. (1) When only one Faraday thin component is present, most methods perform as expected, with occasional failures where two components are incorrectly found. (2) For two Faraday thin components, QU-fitting routines perform the best, with errors close to the theoretical ones for RM wtd but with significantly higher errors for Δϕ. All other methods, including standard Faraday synthesis, frequently identify only one component when Δϕ is below or near the width of the Faraday point-spread function. (3) No methods as currently implemented work well

  9. NOx Direct Decomposition: Potentially Enhanced Thermodynamics and Kinetics on Chemically Modified Ferroelectric Surfaces

    Science.gov (United States)

    Kakekhani, Arvin; Ismail-Beigi, Sohrab

    2014-03-01

    NOx are regulated pollutants produced during automotive combustion. As part of an effort to design catalysts for NOx decomposition that operate in oxygen rich environment and permit greater fuel efficiency, we study chemistry of NOx on (001) ferroelectric surfaces. Changing the polarization at such surfaces modifies electronic properties and leads to switchable surface chemistry. Using first principles theory, our previous work has shown that addition of catalytic RuO2 monolayer on ferroelectric PbTiO3 surface makes direct decomposition of NO thermodynamically favorable for one polarization. Furthermore, the usual problem of blockage of catalytic sites by strong oxygen binding is overcome by flipping polarization that helps desorb the oxygen. We describe a thermodynamic cycle for direct NO decomposition followed by desorption of N2 and O2. We provide energy barriers and transition states for key steps of the cycle as well as describing their dependence on polarization direction. We end by pointing out how a switchable order parameter of substrate,in this case ferroelectric polarization, allows us to break away from some standard compromises for catalyst design(e.g. the Sabatier principle). This enlarges the set of potentially catalytic metals. Primary support from Toyota Motor Engineering and Manufacturing, North America, Inc.

  10. Enhancement of Capacitive Performance in Titania Nanotubes Modified by an Electrochemical Reduction Method

    Directory of Open Access Journals (Sweden)

    Nurul Asma Samsudin

    2018-01-01

    Full Text Available Highly ordered titania nanotubes (TNTs were synthesised by an electrochemical anodization method for supercapacitor applications. However, the capacitive performance of the TNTs was relatively low and comparable to the conventional capacitor. Therefore, in order to improve the capacitive performance of the TNTs, a fast and facile electrochemical reduction method was applied to modify the TNTs (R-TNTs by introducing oxygen vacancies into the lattice. X-ray photoelectron spectroscopy (XPS data confirmed the presence of oxygen vacancies in the R-TNTs lattice upon the reduction of Ti4+ to Ti3+. Electrochemical reduction parameters such as applied voltage and reduction time were varied to optimize the best conditions for the modification process. The electrochemical performance of the samples was analyzed in a three-electrode configuration cell. The cyclic voltammogram recorded at 200 mV s−1 showed a perfect square-shaped voltammogram indicating the excellent electrochemical performance of R-TNTs prepared at 5 V for 30 s. The total area of the R-TNTs voltammogram was 3 times larger than the unmodified TNTs. A specific capacitance of 11.12 mF cm−2 at a current density of 20 μA cm−2 was obtained from constant current charge-discharge measurements, which was approximately 57 times higher than that of unmodified TNTs. R-TNTs also displayed outstanding cycle stability with 99% capacity retention after 1000 cycles.

  11. Modified chemically defined medium for enhanced respiratory growth of Lactobacillus casei and Lactobacillus plantarum groups.

    Science.gov (United States)

    Ricciardi, A; Ianniello, R G; Parente, E; Zotta, T

    2015-09-01

    Members of the Lactobacillus casei and Lactobacillus plantarum groups are capable of aerobic and respiratory growth. However, they grow poorly in aerobiosis in the currently available chemically defined media, suggesting that aerobic and respiratory growth require further supplementation. The effect of Tween 80, L-alanine, L-asparagine, L-aspartate, L-proline and L-serine on anaerobic and respiratory growth of Lact. casei N87 was investigated using a 2(5) factorial design. The effectiveness of modified CDM (mCDM) was validated on 21 strains of Lact. casei and Lact. plantarum groups. Tween 80 supplementation did not affect anaerobic growth, but improved respiratory growth. L-asparagine, L-proline and L-serine were stimulatory for respiring cells, while the presence of L-aspartate, generally, impaired biomass production. mCDM promoted the growth of Lact. casei and Lact. plantarum, with best results for strains showing a respiratory phenotype. The nutritional requirements of anaerobic and respiratory cultures of members of the Lact. casei and Lact. plantarum groups differ. Tween 80 and selected amino acids derived from pathways related to TCA cycle, pyruvate conversion and NADH recycling are required for respiration. The availability of mCDM will facilitate the study of aerobic metabolism of lactobacilli under controlled conditions. © 2015 The Society for Applied Microbiology.

  12. Enhanced luminol electrochemiluminescence triggered by an electrode functionalized with dendrimers modified with titanate nanotubes

    International Nuclear Information System (INIS)

    Lin, Yanyu; Yang, Yusheng; Dai, Hong; Xu, Guifang; Yang, Ting; Tong, Yuejin; Yang, Caiping; Chen, Guonan

    2013-01-01

    We have constructed a novel electro chemiluminescence (ECL) platform by functionalizing a poly(amidoamine) dendrimer (PAAD) with titanate nanotubes (TiNTs). The PAAD has an open spherical structure that possesses a high density of active groups and thus favors mass transport, while the TiNTs possess excellent electronic conductivity and thus can promote electron transfer on the surface of a glassy carbon electrode (GCE). A study on the intensity and stability of the ECL of luminol on the modified GCE revealed a substantial improvement compared to that of a bare GCE. The effects of the concentration of TiNTs, the pH value of the solution, and of electrochemical parameters on the intensity of the ECL of luminol were studied and resulted in a sensitive ECL sensor for hydrogen peroxide (H 2 O 2 ) that works in the concentration range of 1 nM to 0.9 μM. The scavenging effect of superoxide dismutase (SOD) on the H 2 O 2 electrode ECL was then exploited to design a biosensor for the determination of SOD in concentrations between 50 and 500 nM. (author)

  13. Enhanced gene ranking approaches using modified trace ratio algorithm for gene expression data

    Directory of Open Access Journals (Sweden)

    Shruti Mishra

    Full Text Available Microarray technology enables the understanding and investigation of gene expression levels by analyzing high dimensional datasets that contain few samples. Over time, microarray expression data have been collected for studying the underlying biological mechanisms of disease. One such application for understanding the mechanism is by constructing a gene regulatory network (GRN. One of the foremost key criteria for GRN discovery is gene selection. Choosing a generous set of genes for the structure of the network is highly desirable. For this role, two suitable methods were proposed for selection of appropriate genes. The first approach comprises a gene selection method called Information gain, where the dataset is reformed and fused with another distinct algorithm called Trace Ratio (TR. Our second method is the implementation of our projected modified TR algorithm, where the scoring base for finding weight matrices has been re-designed. Both the methods' efficiency was shown with different classifiers that include variants of the Artificial Neural Network classifier, such as Resilient Propagation, Quick Propagation, Back Propagation, Manhattan Propagation and Radial Basis Function Neural Network and also the Support Vector Machine (SVM classifier. In the study, it was confirmed that both of the proposed methods worked well and offered high accuracy with a lesser number of iterations as compared to the original Trace Ratio algorithm. Keywords: Gene regulatory network, Gene selection, Information gain, Trace ratio, Canonical correlation analysis, Classification

  14. A critical evaluation of the enhancement of mechanical properties of epoxy modified using CNTs

    Science.gov (United States)

    Bedsole, Robert W.; Park, Cheol; Bogert, Philip B.; Tippur, Hareesh V.

    2015-09-01

    Carbon nanotubes (CNTs) have been widely shown in the literature to improve mechanical properties of epoxy, such as tensile strength, elastic modulus, strain to failure, and fracture toughness. These improvements in nanocomposite properties have been attributed to the extraordinary properties of the nanotubes, as well as the quality of their dispersion within and adhesion to the epoxy matrix. However, many authors have also struggled to show significant mechanical improvements using similar methodologies and despite, in some cases, showing qualitative improvements in dispersion with optical microscopy. These authors have frequently resorted to other methods for improving the mechanical properties of CNT/epoxy, such as electrically aligning CNTs, using different types of CNTs, or modifying the stoichiometry. The current work examines many different dispersion techniques, types of CNTs, types of epoxies, curing cycles, and other variables in an attempt to improve the mechanical properties of neat epoxy with CNTs. Despite seeing significant changes in the microscopy, no significant improvements in tensile or fracture properties have been attributed to CNTs in this work.

  15. Modified double contrast-enhanced examination of the stomach of adipose patients after vertical gastroplasty

    International Nuclear Information System (INIS)

    Raissaki, M.T.; Prassopoulos, P.; Hatjidakis, A.A.; Christodoulakis, M.; Melissas, J.; Gourtsoyiannis, N.C.

    1995-01-01

    The study reported covers 28 patients who were examined once by radiology before surgery, and twice after surgery. The first post-surgery examination was done on days 5-7, the second during the 4th until 6th month after surgery. For the first examination, water-soluble contrast agent was initially applied, then barium containing contrast agent. The second examination was done by modified double contrast technique. The most frequent, pre-surgery findings revealed gastro-esophageal reflux in 13 patients. The first post-surgery control detected a somastenosis in 2 patients, while the second control examination detected complications of various nature in 11 patients and gastro-esophageal reflux in 5 patients. In 6 patients, discrepancy between clinical and radiological findings was stated. The pouch size did not correlate with the frequency of complications, or with the body-to-mass index decrease. The examination method proposed in this article yields pre-surgery information on the anatomy of the stomach, more accurate dewscription of post-surgery complications, and better evaluation of the antireflux effect of the vertical gastroplasty. (orig.) [de

  16. Thermal enhancement cartridge heater modified tritium hydride bed development, Part 2 - Experimental validation of key conceptual design features

    Energy Technology Data Exchange (ETDEWEB)

    Heroux, K.J.; Morgan, G.A. [Savannah River Laboratory, Aiken, SC (United States)

    2015-03-15

    The Thermal Enhancement Cartridge Heater Modified (TECH Mod) tritium hydride bed is an interim replacement for the first generation (Gen1) process hydride beds currently in service in the Savannah River Site (SRS) Tritium Facilities. 3 new features are implemented in the TECH Mod hydride bed prototype: internal electric cartridge heaters, porous divider plates, and copper foam discs. These modifications will enhance bed performance and reduce costs by improving bed activation and installation processes, in-bed accountability measurements, end-of-life bed removal, and He-3 recovery. A full-scale hydride bed test station was constructed at the Savannah River National Laboratory (SRNL) in order to evaluate the performance of the prototype TECH Mod hydride bed. Controlled hydrogen (H{sub 2}) absorption/ desorption experiments were conducted to validate that the conceptual design changes have no adverse effects on the gas transfer kinetics or H{sub 2} storage/release properties compared to those of the Gen1 bed. Inert gas expansions before, during, and after H{sub 2} flow tests were used to monitor changes in gas transfer rates with repeated hydriding/de-hydriding of the hydride material. The gas flow rates significantly decreased after initial hydriding of the material; however, minimal changes were observed after repeated cycling. The data presented herein confirm that the TECH Mod hydride bed would be a suitable replacement for the Gen1 bed with the added enhancements expected from the advanced design features. (authors)

  17. Depth-enhanced three-dimensional-two-dimensional convertible display based on modified integral imaging.

    Science.gov (United States)

    Park, Jae-Hyeung; Kim, Hak-Rin; Kim, Yunhee; Kim, Joohwan; Hong, Jisoo; Lee, Sin-Doo; Lee, Byoungho

    2004-12-01

    A depth-enhanced three-dimensional-two-dimensional convertible display that uses a polymer-dispersed liquid crystal based on the principle of integral imaging is proposed. In the proposed method, a lens array is located behind a transmission-type display panel to form an array of point-light sources, and a polymer-dispersed liquid crystal is electrically controlled to pass or to scatter light coming from these point-light sources. Therefore, three-dimensional-two-dimensional conversion is accomplished electrically without any mechanical movement. Moreover, the nonimaging structure of the proposed method increases the expressible depth range considerably. We explain the method of operation and present experimental results.

  18. Solution deposited and modified iron oxide for enhanced solar water splitting

    Science.gov (United States)

    Abel, Anthony J.

    Growing worldwide energy demand coupled with an increasing awareness of anthropogenic climate change has driven research into carbon-neutral and solar-derived energy sources. One attractive strategy is the storage of solar energy in the bonds of H2 formed by photoelectrochemical (PEC) water splitting. Hematite, an iron oxide, has been widely investigated as a candidate material for PEC water splitting due to its stability, non-toxicity, earth abundance and consequent low cost, and a theoretical 15% solar-to-hydrogen conversion efficiency. However, poor electrical properties and slow rates of the water oxidation reaction have limited its potential as an economical water splitting catalyst. Additionally, the most efficient hematite-based devices are fabricated via expensive, vacuum-phase techniques, limiting scalability to broad integration into the energy supply. In this thesis, I develop a new, solution-based deposition method for high quality, planar hematite thin films using successive ionic layer adsorption and reaction (SILAR). The constant geometry and tight control over layer thickness possible with SILAR makes these films ideal model systems to understand the two key steps of PEC water oxidation: charge separation and interfacial hole transfer. In Chapter 3, I report on facile annealing treatments to dope hematite with Ti and Sn, and I show that these impurity atoms at the hematite/electrolyte interface increase hole transfer efficiency from nearly 0 to above 60%. However, charge separation remains below 15% with these dopants incorporated via solid state diffusion, mainly due to low hole mobility. To overcome this associated small transport length, extremely thin hematite coatings were deposited on Sb:SnO2 monolayer inverse opal scaffolds. With this modified substrate, photocurrent increased proportionately to the surface area of the scaffold. While Chapter 3 discusses incorporation of dopants via solid state diffusion, Chapter 4 examines methods to

  19. RGD-modified poly(D,L-lactic acid nanoparticles enhance tumor targeting of oridonin

    Directory of Open Access Journals (Sweden)

    Xu J

    2012-01-01

    Full Text Available Jie Xu, Ji-Hui Zhao, Ying Liu, Nian-Ping Feng, Yong-Tai ZhangSchool of Pharmacy, Shanghai University of Traditional Chinese Medicine, Shanghai, People's Republic of ChinaObjective: The purpose of this study was to develop an active targeting strategy to improve the therapeutic antitumor efficacy of oridonin (ORI, the main active ingredient in the medicinal herb Rabdosia rubescens.Methods: A modified spontaneous emulsification solvent diffusion method was used to prepare the ORI-loaded atactic poly(D,L-lactic acid nanoparticles (ORI-PLA-NPs. Surface cross-linking with the peptide Arg-Gly-Asp (RGD further modified the ORI-PLA-NPs, generating ORI-PLA-RGD-NPs. The NPs were characterized and release experiments were performed in vitro. The pharmacokinetics, tissue distribution, and antitumor activity of the NPs were studied in mice bearing hepatocarcinoma 22 (H22-derived tumors.Results: The ORI-PLA-NPs and ORI-PLA-RGD-NPs were smooth, sphere-like, and relatively uniform in size. The RGD surface modification slightly increased the mean particle size (95.8 nm for ORI-PLA-NPs versus 105.2 nm for ORI-PLA-RGD-NPs and considerably altered the surface electrical property (-10.19 mV for ORI-PLA-NPs versus -21.95 mV for ORI-PLA-RGD-NPs, but it had no obvious influence on ORI loading (8.23% ± 0.35% for ORI-PLA-NPs versus 8.02% ± 0.38% for ORI-PLA-RGD-NPs, entrapment efficiency (28.86% ± 0.93% for ORI-PLA-NPs versus 28.24% ± 0.81% for ORI-PLA-RGD-NPs, or the release of ORI. The pharmacokinetic properties of free ORI were improved by encapsulation in NPs, as shown by increased area under the concentration-time curve (11.89 ± 0.35 µg·mL-1 · h for ORI solution versus 22.03 ± 0.01 µg · mL-1 · h for ORI-PLA-RGD-NPs and prolonged mean retention time (2.03 ± 0.09 hours for ORI solution versus 8.68 ± 0.66 hours for ORI-PLA-RGD-NPs. In the tissue distribution study, more ORI targeted tumor tissue in the mice treated with ORI-PLA-RGD-NPs than with ORI

  20. Enhancement of Inverted Polymer Solar Cells Performances Using Cetyltrimethylammonium-Bromide Modified ZnO

    Directory of Open Access Journals (Sweden)

    Chung-Kai Wu

    2018-03-01

    Full Text Available In this study, the performance and stability of inverted bulk heterojunction (BHJ polymer solar cells (PSCs is enhanced by doping zinc oxide (ZnO with 0–6 wt % cetyltrimethylammonium bromide (CTAB in the sol-gel ZnO precursor solution. The power conversion efficiency (PCE of the optimized 3 wt % CTAB-doped ZnO PSCs was increased by 9.07%, compared to a PCE of 7.31% for the pristine ZnO device. The 0–6 wt % CTAB-doped ZnO surface roughness was reduced from 2.6 to 1 nm and the number of surface defects decreased. The X-ray photoelectron spectroscopy binding energies of Zn 2p3/2 (1021.92 eV and 2p1/2 (1044.99 eV shifted to 1022.83 and 1045.88 eV, respectively, which is related to strong chemical bonding via bromide ions (Br− that occupy oxygen vacancies in the ZnO lattice, improving the PCE of PSCs. The concentration of CTAB in ZnO significantly affected the work function of PSC devices; however, excessive CTAB increased the work function of the ZnO layer, resulting from the aggregation of CTAB molecules. In addition, after a 120-hour stability test in the atmosphere with 40% relative humidity, the inverted device based on CTAB-doped ZnO retained 92% of its original PCE and that based on pristine ZnO retained 68% of its original PCE. The obtained results demonstrate that the addition of CTAB into ZnO can dramatically influence the optical, electrical, and morphological properties of ZnO, enhancing the performance and stability of BHJ PSCs.

  1. Using modified information delivery to enhance the traditional pharmacy OSCE program at TMU - a pilot study.

    Science.gov (United States)

    Lin, Che-Wei; Chang, Elizabeth H; Clinciu, Daniel L; Peng, Yun-Ting; Huang, Wen-Chen; Wu, Chien-Chih; Wu, Jen-Chieh; Li, Yu-Chuan

    2018-05-01

    Objective Structured Clinical Examination (OSCE) has been used in many areas of healthcare training over the years. However, it constantly needs to be upgraded and enhanced due to technological and teaching changes. We aim at implementing an integrative OSCE method which employs informatics via the virtual patient within the pharmacy education curriculum at Taipei Medical University to enhance the pharmacy students' competence for using and disseminating information and to also improve critical thinking and clinical reasoning. We propose an integrated pharmacy OSCE which uses standardized patients and virtual patients (DxR Clinician). To evaluate this method, we designed four simulated stations and pilot tested with 19 students in the first year of the Master in Clinical Pharmacy program. Three stations were simulated as the inpatient pharmacy: 1) History and lab data collection; 2) Prescription review; 3) Calling physician to discuss potential prescription problems. The fourth was simulated as the patient ward station to provide patient education. A satisfaction questionnaire was administered at the end of the study. Students rated their ability of 2.84, 2.37, 2.37, and 3.63 of 5 for each of the four stations, with the second and third being the most difficult stations. The method obtained an average rating of 4.32 of 5 for relevance, 4.16 for improving clinical ability, 4.32 for practicality in future healthcare work, and 4.28 for willing to have another similar learning experience. The integration of Virtual Patient in this study reveals that this assessment method is efficient and practical in many aspects. Most importantly, it provides the test taker with a much closer real-life clinical encounter. Although it is in many ways more difficult, it also provides for better "learning from mistakes" opportunities for test-takers. Copyright © 2017. Published by Elsevier B.V.

  2. Enhancing sensitivity of SERRS nanoprobes by modifying heptamethine cyanine-based reporter molecules

    Directory of Open Access Journals (Sweden)

    Yunfei Zhang

    2016-07-01

    Full Text Available Surface enhanced resonance Raman scattering (SERRS is a physical phenomenon that occurs when the energy of incident light is close to that of electronic excitation of reporter molecules (RMs attached on substrates. SERRS has showed great promise in healthcare applications such as tumor diagnosis, image-guided tumor surgery and real-time evaluation of therapeutic response due to its ultra-sensitivity, manipulating convenience and easy accessibility. As the most widely used organic near-infrared (NIR fluorophore, heptamethine cyanines possess the electronic excitation energy that is close to the plasmon absorption energy of the gold nano-scaffolds, which results in the extraordinary enhancement of the SERRS signal. However, the effect of heptamethine cyanine structure and the gold nanoparticle morphology to the SERRS intensity are barely investigated. This work developed a series of SERRS nanoprobes in which two heptamethine cyanine derivatives (IR783 and IR780 were used as the RM and three gold nanoparticles (nanorod, nanosphere and nanostar were used as the substrates. Interestingly, even though IR780 and IR783 possess very similar chemical structure, SERRS signal produced by IR780 was determined as 14 times higher than that of IR783 when the RM concentration was 6.5 × 10−6M. In contrast, less than 4.0 fold SERRS signal intensity increase was measured by changing the substrate morphologies. Above experimental results indicate that finely tuning the chemical structure of the heptamethine cyanine could be a feasible way to develop robust SERRS probes to visualize tumor or guide tumor resection with high sensitivity and target to background ratio.

  3. Enhancement in thermal property and mechanical property of phase change microcapsule with modified carbon nanotube

    International Nuclear Information System (INIS)

    Li, Min; Chen, Meirong; Wu, Zhishen

    2014-01-01

    Highlights: • Carbon nanotubes was grafted and used to enhance the thermal conductivities of the microcapsules. • The average particle size of the prepared MicroPCMs/CNTs-SA is 0.1 μm. • The thermal conductivity of MicroPCMs/CNTs-SA with 4% of CNTs increased by 79.2% compared with MicroPCMs. • MicroPCMs/CNTs-SA has better durability and thermal stability compared to the original MicroPCMs. - Abstract: Carbon nanotubes grafted with stearyl alcohol (CNTs-SA) was used in synthesizing phase change microcapsules (MicroPCMs) in order to enhance the thermal conductivities of the microcapsules. Urea–formaldehyde resin (UFR) was used as wall material. Scanning Electron Microscope (SEM), laser particle size analyzer, Fourier Transform Infrared Spectroscopy (FTIR), Differential Scanning Calorimeter (DSC) are employed to characterize the prepared MicroPCMs containing the grafted CNTs (MicroPCMs/CNTs-SA). The results indicated that CNTs improved the performance of microcapsules. The average particle diameter of MicroPCMs/CNTs-SA is much smaller than that of MicroPCMs. There was no chemical reaction among paraffin, CNTs and UFR. The phase change temperature and latent heat of MicroPCMs/CNTs-SA was 26.2 °C and 47.7 J/g, respectively. The thermal conductivity of MicroPCMs/CNTs-SA with 4% of CNTs increased by 79.2% compared with MicroPCMs. The initial decomposition temperature of MicroPCMs/CNTs-SA is 38 °C higher than that of MicroPCMs. After 100 heating and cooling cycles, MicroPCMs/CNTs-SA still has good durability and thermal stability

  4. Enhancing human performance in ship operations by modifying global design factors at the design stage

    International Nuclear Information System (INIS)

    Montewka, Jakub; Goerlandt, Floris; Innes-Jones, Gemma; Owen, Douglas; Hifi, Yasmine; Puisa, Romanas

    2017-01-01

    Usually the improvements of human performance in the course of ship design process is carried out by modifying local ergonomics, like electronic visualisation and information display systems on the bridge or in the engine control room, stair or hatch covers design. However, the effect of global design factors (GDFs), such as ship motion, whole body vibration and noise, on human performance has not been given attention before. Such knowledge would allow the improvements of human performance by effective design modification on very early stage of ship design process. Therefore, in this paper we introduce probabilistic models linking the effect of GDFs with the human performance suitable for ship design process. As a theoretical basis for modelling human performance the concept of Attention Management is utilized, which combines the theories described by Dynamic Adaptability Model, Cognitive Control Model and Malleable Attentional Resources Theory. Since the analysed field is characterised by a high degree of uncertainty, we adopt a specific modelling technique along with a validation framework that allows uncertainty treatment and helps the potential end-users to gain confidence in the models and the results that they yield. The proposed models are developed with the use Bayesian Belief Networks, which allows systematic translation of the available background knowledge into a coherent network and the uncertainty assessment and treatment. The obtained results are promising as the models are responsive to changes in the GDF nodes as expected. The models may be used as intended by naval architects and vessel designers, to facilitate risk-based ship design. - Highlights: • Models linking the effect of GDFs with the human performance are established. • Three global design factors (GDFs) are considered: ship motion, body vibration, noise. • Attention Management concept as theoretical base is modelled with Bayesian Networks. • Two models are developed that can be

  5. Enhanced adherence of mouse fibroblast and vascular cells to plasma modified polyethylene

    Energy Technology Data Exchange (ETDEWEB)

    Reznickova, Alena, E-mail: alena.reznickova@vscht.cz [Department of Solid State Engineering, Institute of Chemical Technology Prague, 166 28 Prague 6 (Czech Republic); Novotna, Zdenka, E-mail: zdenka1.novotna@vscht.cz [Department of Solid State Engineering, Institute of Chemical Technology Prague, 166 28 Prague 6 (Czech Republic); Kolska, Zdenka [Faculty of Science, J.E. Purkyně University, 400 96 Usti nad Labem (Czech Republic); Kasalkova, Nikola Slepickova [Department of Solid State Engineering, Institute of Chemical Technology Prague, 166 28 Prague 6 (Czech Republic); Rimpelova, Silvie [Department of Biochemistry and Microbiology, Institute of Chemical Technology Prague, 166 28 Prague 6 (Czech Republic); Svorcik, Vaclav [Department of Solid State Engineering, Institute of Chemical Technology Prague, 166 28 Prague 6 (Czech Republic)

    2015-07-01

    Since the last decade, tissue engineering has shown a sensational promise in providing more viable alternatives to surgical procedures for harvested tissues, implants and prostheses. Biomedical polymers, such as low-density polyethylene (LDPE), high-density polyethylene (HDPE) and ultra-high molecular weight polyethylene (UHMWPE), were activated by Ar plasma discharge. Degradation of polymer chains was examined by determination of the thickness of ablated layer. The amount of an ablated polymer layer was measured by gravimetry. Contact angle, measured by goniometry, was studied as a function of plasma exposure and post-exposure aging times. Chemical structure of modified polymers was characterized by angle resolved X-ray photoelectron spectroscopy. Surface chemistry and polarity of the samples were investigated by electrokinetic analysis. Changes in surface morphology were followed using atomic force microscopy. Cytocompatibility of plasma activated polyethylene foils was studied using two distinct model cell lines; VSMCs (vascular smooth muscle cells) as a model for vascular graft testing and connective tissue cells L929 (mouse fibroblasts) approved for standardized material cytotoxicity testing. Specifically, the cell number, morphology, and metabolic activity of the adhered and proliferated cells on the polyethylene matrices were studied in vitro. It was found that the plasma treatment caused ablation of the polymers, resulting in dramatic changes in their surface morphology and roughness. ARXPS and electrokinetic measurements revealed oxidation of the polymer surface. It was found that plasma activation has a positive effect on the adhesion and proliferation of VSMCs and L929 cells. - Highlights: • Plasma activation of LDPE, HDPE and UHMWPE • Study of surface properties by several techniques: ARXPS, AFM, zeta-potential, and goniometry • Investigation of adhesion and spreading of vascular smooth muscle cells (VSMCs) and mouse fibroblasts (L929)

  6. Enhanced bioremediation of oil contaminated soil by graded modified Fenton oxidation.

    Science.gov (United States)

    Xu, Jinlan; Xin, Lei; Huang, Tinglin; Chang, Kun

    2011-01-01

    Graded modified Fenton's (MF) oxidation is a strategy in which H2O2 is added intermittently to prevent a sharp temperature increase and undesired soil sterilization at soil circumneutral pH versus adding the same amount of H2O2 continuously. The primary objective of the present study was to investigate whether a mild MF pre-oxidation such as a stepwise addition of H2O2 can prevent sterilization and achieve a maximum degradation of tank oil in soil. Optimization experiments of graded MF oxidation were conducted using citric acid, oxalic acid and SOLV-X as iron chelators under different frequencies of H2O2 addition. The results indicated that the activity order of iron chelates decreased as: citric acid (51%) > SOLV-X (44%) > oxalic acid (9%), and citric acid was found to be an optimized iron chelating agent of graded MF oxidation. Three-time addition of H2O2 was found to be favorable and economical due to decreasing total petroleum hydrocarbon removal from three time addition (51%) to five time addition (59%). Biological experiments were conducted after graded MF oxidation of tank oil completed under optimum conditions mentioned above. After graded oxidation, substantially higher increase (31%) in microbial activity was observed with excessive H2O2 (1470 mmol/L, the mol ratio of H2O2:Fe2+ was 210:1) than that of non-oxidized soil. Removal efficiency of tank oil was up to 93% after four weeks. Especially, the oil fraction (C10-C40) became more biodagradable after graded MF oxidation than its absence. Therefore, graded MF oxidation is a mild pretreatment to achieve an effective bioremediation of oil contaminated soil.

  7. Novel levocetirizine HCl tablets with enhanced palatability: synergistic effect of combining taste modifiers and effervescence technique

    Directory of Open Access Journals (Sweden)

    Labib GS

    2015-09-01

    Full Text Available Gihan S Labib1,2 1Department of Pharmaceutics and Industrial Pharmacy, Faculty of Pharmacy, King Abdulaziz University, Jeddah, Saudi Arabia; 2Department of Pharmaceutics, Faculty of Pharmacy, Alexandria University, Alexandria, Egypt Objectives: Levocetirizine HCl, a second-generation piperazine derivative and H1-selective antihistaminic agent, possesses few side effects. The first objective of the study was to compare and evaluate the taste-masking effect of different ratios of 2-hydroxypropyl-β-cyclodextrin and mannitol on levocetirizine HCl using an inclusion complex and solid dispersion, respectively. The second objective was to study the possibility of preparing and evaluating effervescent tablets from the best-chosen taste-masked blends for the purpose of their use either as orodispersible tablets or as water-soluble effervescent tablets, according to patients’ will.Materials and methods: Prepared taste-masked blends were prepared and subjected to palatability, Fourier-transform infrared spectroscopy, and differential scanning calorimetry studies. Tablets containing different percentages of effervescent mixtures were prepared by direct compression on the selected taste-modified blends. Evaluation tests were conducted, including flowability and compressibility on the precompressed blends and hardness, friability, wetting time, effervescent time, in vitro, in vivo disintegration time, and in vitro dissolution study on the compressed tablets. Formulated tablets were evaluated and compared to marketed orodispersible tablets for mouth feel and palatability.Results: All prepared tablets showed convenient physical and palatability properties compared to the selected brand. The in vitro drug-release study revealed fast release of levocetirizine HCl within 5 minutes from all prepared tablets.Conclusion: Levocetirizine HCl effervescent tablets are likely to increase patient compliance with drug administration. Moreover, the use of these

  8. Novel levocetirizine HCl tablets with enhanced palatability: synergistic effect of combining taste modifiers and effervescence technique

    Science.gov (United States)

    Labib, Gihan S

    2015-01-01

    Objectives Levocetirizine HCl, a second-generation piperazine derivative and H1-selective antihistaminic agent, possesses few side effects. The first objective of the study was to compare and evaluate the taste-masking effect of different ratios of 2-hydroxypropyl-β-cyclodextrin and mannitol on levocetirizine HCl using an inclusion complex and solid dispersion, respectively. The second objective was to study the possibility of preparing and evaluating effervescent tablets from the best-chosen taste-masked blends for the purpose of their use either as orodispersible tablets or as water-soluble effervescent tablets, according to patients’ will. Materials and methods Prepared taste-masked blends were prepared and subjected to palatability, Fourier-transform infrared spectroscopy, and differential scanning calorimetry studies. Tablets containing different percentages of effervescent mixtures were prepared by direct compression on the selected taste-modified blends. Evaluation tests were conducted, including flowability and compressibility on the precompressed blends and hardness, friability, wetting time, effervescent time, in vitro, in vivo disintegration time, and in vitro dissolution study on the compressed tablets. Formulated tablets were evaluated and compared to marketed orodispersible tablets for mouth feel and palatability. Results All prepared tablets showed convenient physical and palatability properties compared to the selected brand. The in vitro drug-release study revealed fast release of levocetirizine HCl within 5 minutes from all prepared tablets. Conclusion Levocetirizine HCl effervescent tablets are likely to increase patient compliance with drug administration. Moreover, the use of these effervescent tablets in an orodispersible dosage form can improve oral drug bioavailability and act as an attractive pediatric dosage form. PMID:26379426

  9. Synergistic Effect of Cu2O and Urea as Modifiers of TiO2 for Enhanced Visible Light Activity

    Directory of Open Access Journals (Sweden)

    Marcin Janczarek

    2018-06-01

    Full Text Available Low cost compounds, i.e., Cu2O and urea, were used as TiO2 modifiers to introduce visible light activity. Simple and cheap methods were applied to synthesize an efficient and stable nanocomposite photocatalytic material. First, the core-shell structure TiO2–polytriazine derivatives were prepared. Thereafter, Cu2O was added as the second semiconductor to form a dual heterojunction system. Enhanced visible light activity was found for the above-mentioned nanocomposite, confirming a synergistic effect of Cu2O and urea (via polytriazine derivatives on titania surface. Two possible mechanisms of visible light activity of the considered material were proposed regarding the type II heterojunction and Z-scheme through the essential improvement of the charge separation effect.

  10. Robust and thermal-enhanced melamine formaldehyde–modified glassfiber composite separator for high-performance lithium batteries

    International Nuclear Information System (INIS)

    Wang, Qingfu

    2015-01-01

    The composite separator of melamine formaldehyde resin coated glass microfiber membrane was prepared for high performance lithium ion battery. It was demonstrated that this composite membranes possessed a significantly enhanced tensile strength and a modified porous structure, compared with that of pristine glass microfiber membrane. Impressive improvements in thermo-stability, with no shrinkage at an elevated temperature of 150 °C. Meanwhile, such composite membrane presented a favorable wettability and remarkable electrochemical stability in commercial liquid electrolyte. In addition, the battery test results of LiCoO 2 /graphite cells proved the composite membrane was a promising separator with an improved cycling performance and rate capability. The cycle performance of LiFePO 4 /Li cells at the elevated temperature of 120 °C demonstrated their excellent safety characteristic as separator in LIB, indicating the composite membrane was a potential separator candidate for high power battery.

  11. Generalized optical code construction for enhanced and Modified Double Weight like codes without mapping for SAC-OCDMA systems

    Science.gov (United States)

    Kumawat, Soma; Ravi Kumar, M.

    2016-07-01

    Double Weight (DW) code family is one of the coding schemes proposed for Spectral Amplitude Coding-Optical Code Division Multiple Access (SAC-OCDMA) systems. Modified Double Weight (MDW) code for even weights and Enhanced Double Weight (EDW) code for odd weights are two algorithms extending the use of DW code for SAC-OCDMA systems. The above mentioned codes use mapping technique to provide codes for higher number of users. A new generalized algorithm to construct EDW and MDW like codes without mapping for any weight greater than 2 is proposed. A single code construction algorithm gives same length increment, Bit Error Rate (BER) calculation and other properties for all weights greater than 2. Algorithm first constructs a generalized basic matrix which is repeated in a different way to produce the codes for all users (different from mapping). The generalized code is analysed for BER using balanced detection and direct detection techniques.

  12. Enhanced NO2 abatement by alkaline-earth modified g-C3N4 nanocomposites for efficient air purification

    Science.gov (United States)

    Papailias, Ilias; Todorova, Nadia; Giannakopoulou, Tatiana; Karapati, Sofia; Boukos, Nikos; Dimotikali, Dimitra; Trapalis, Christos

    2018-02-01

    The emission of nitrogen dioxide (NO2) is a major problem encountered in photocatalytic NOx removal for air purification. Although the oxidation of nitric oxide (NO) has been extensively studied, the elimination of NO2 byproduct is still in preliminary stage. In this work, alkaline-earth modified graphitic carbon nitride (g-C3N4) is proposed for efficient NOx removal by minimizing the emission of NO2 during the NO oxidation process. The novel photocatalysts were synthesized by annealing mixtures of melamine and various alkaline-earth acetates (magnesium, calcium and barium acetate) at 550 °C for 3 h. The specific surface area of the photocatalysts varied between 4.65 and 11.81 m2/g. The formation of MgO, CaCO3 and BaCO3 was demonstrated by XPS and FT-IR analyses. The initial concentration of each alkaline-earth precursor was 5 and 10 wt%, while the final metal concentration in the nanocomposites was in the range of 7.19-22.39 wt%. The modified photocatalysts showed slightly reduced NO oxidation ability. However, the overall air quality was significantly improved by restraining the NO2 emission. The results were related to the basic character of the nanocomposites due to the presence of alkaline-earths and their enhanced NO2 adsorption capability.

  13. Enhanced NO2 sensing characteristics of Au modified porous silicon/thorn-sphere-like tungsten oxide composites

    Science.gov (United States)

    Yuan, Lin; Hu, Ming; Wei, Yulong; Ma, Wenfeng

    2016-12-01

    The thorn-sphere-like tungsten oxide (WO3) made up by 1D nanorods has been successfully synthesized through hydrothermal method on the Au-modified porous silicon (PS) substrates with seed-layer induction. By using XRD, EDS, FESEM and TEM techniques, we tested and verified that the crystal structure and morphology evolution of WO3 hierarchical nanostructure on the Au-modified PS strongly depend on the Au-sputtering time and hydrothermal reaction time. In addition, by comparing the NO2-sensing properties of the prepared products, we found that the 10 s-Au decorated PS/WO3-3 h (sputtering Au for 10 s and hydrothermal reaction for 3 h) composites sensor behaving as a typical p-type semiconductor and operating at room temperature (RT) exhibits high sensitivity and response characteristics even to ppb-level NO2, which makes this kind of sensor a competitive candidate for NO2-sensing applications. Moreover, the enhanced response may not only due to the high specific surface area but the Au nanoparticles acting as promoters for the spillover effect and forming metal-semiconductor heterojunctions with the PS and WO3. The transmission of electrons and holes in the heterogeneous interface generated among PS, WO3 and Au is proposed to illustrate the p-type response mechanism.

  14. Chitosan surface modified electrospun poly(ε-caprolactone)/carbon nanotube composite fibers with enhanced mechanical, cell proliferation and antibacterial properties.

    Science.gov (United States)

    Wang, Siyu; Li, Yumei; Zhao, Rui; Jin, Toufeng; Zhang, Li; Li, Xiang

    2017-11-01

    The surface modification is one of the most effective methods to improve the bioactivity and cell affinity effect of electrospun poly(ε-caprolactone) (PCL) fibers. In the present study, chitosan (CS), a cationic polysaccharide, was used to modify the surface of electrospun PCL fibers. To obtain strong interaction between CS and PCL fibers, negatively charged PCL fibers were prepared by the incorporation of acid-treated carbon nanotubes (CNTs) into the fibers. In this way, the positively charged chitosan could be immobilized onto the surface of PCL fibers tightly by the electrostatic attraction. Besides, the incorporation of CNTs could significantly improve the mechanical strength of electrospun PCL fibers even after the CS modification, which guaranteed their usability in practical applications. The CS modification could effectively improve the wettability and bioactivity of electrospun PCL fibers. Cultivation of L929 fibroblast cells on the obtained fibers and the antibacterial activity were both evaluated to discuss the influence of chitosan modification. The results indicated that this modification could enhance the cell proliferation and antibacterial ability in comparison to the non-modified groups. Copyright © 2017 Elsevier B.V. All rights reserved.

  15. Mechanism insights into enhanced trichloroethylene removal using xanthan gum-modified microscale zero-valent iron particles.

    Science.gov (United States)

    Xin, Jia; Han, Jun; Zheng, Xilai; Shao, Haibing; Kolditz, Olaf

    2015-03-01

    This report focuses on the enhancement in trichloroethylene (TCE) removal from contaminated groundwater using xanthan gum (XG)-modified, microscale, zero-valent iron (mZVI). Compared with bare mZVI, XG-coated mZVI increased the TCE removal efficiency by 30.37% over a 480-h experimental period. Because the TCE removal is attributed to both sorption and reduction processes, the contributions from sorption and reduction were separately investigated to determine the mechanism of XG on TCE removal using mZVI. The results showed that the TCE sorption capacity of mZVI was lower in the presence of XG, whereas the TCE reduction capacity was significantly increased. The FTIR spectra confirmed that XG, which is rich in hydrophilic functional groups, was adsorbed onto the iron surface through intermolecular hydrogen bonds, which competitively repelled the sorption and mass transfer of TCE toward reactive sites. The variations in the pH, Eh, and Fe(2+) concentration as functions of the reaction time were recorded and indicated that XG buffered the solution pH, inhibited surface passivation, and promoted TCE reduction by mZVI. Overall, the XG-modified mZVI was considered to be potentially effective for the in-situ remediation of TCE contaminated groundwater due to its high stability and dechlorination reactivity. Copyright © 2014 Elsevier Ltd. All rights reserved.

  16. Increased half-life and enhanced potency of Fc-modified human PCSK9 monoclonal antibodies in primates.

    Directory of Open Access Journals (Sweden)

    Yijun Shen

    Full Text Available Blocking proprotein convertase subtilisin kexin type 9 (PCSK9 binding to low-density lipoprotein receptor (LDLR can profoundly lower plasma LDL levels. Two anti-PCKS9 monoclonal antibodies (mAbs, alirocumab and evolocumab, were approved by the FDA in 2015. The recommended dose is 75 mg to 150 mg every two weeks for alirocumab and 140mg every two weeks or 420 mg once a month for evolocumab. This study attempted to improve the pharmacokinetic properties of F0016A, an IgG1 anti-PCKS9 mAb, to generate biologically superior molecules. We engineered several variants with two or three amino acid substitutions in the Fc fragment based on prior knowledge. The Fc-modified mAbs exhibited increased binding to FcRn, resulting in prolonged serum half-life and enhanced efficacy in vivo. These results demonstrate that Fc-modified anti-PCKS9 antibodies may enable less frequent or lower dosing of antibodies by improved recycling into the blood.

  17. Facile formation of dendrimer-stabilized gold nanoparticles modified with diatrizoic acid for enhanced computed tomography imaging applications.

    Science.gov (United States)

    Peng, Chen; Li, Kangan; Cao, Xueyan; Xiao, Tingting; Hou, Wenxiu; Zheng, Linfeng; Guo, Rui; Shen, Mingwu; Zhang, Guixiang; Shi, Xiangyang

    2012-11-07

    We report a facile approach to forming dendrimer-stabilized gold nanoparticles (Au DSNPs) through the use of amine-terminated fifth-generation poly(amidoamine) (PAMAM) dendrimers modified by diatrizoic acid (G5.NH(2)-DTA) as stabilizers for enhanced computed tomography (CT) imaging applications. In this study, by simply mixing G5.NH(2)-DTA dendrimers with gold salt in aqueous solution at room temperature, dendrimer-entrapped gold nanoparticles (Au DENPs) with a mean core size of 2.5 nm were able to be spontaneously formed. Followed by an acetylation reaction to neutralize the dendrimer remaining terminal amines, Au DSNPs with a mean size of 6 nm were formed. The formed DTA-containing [(Au(0))(50)-G5.NHAc-DTA] DSNPs were characterized via different techniques. We show that the Au DSNPs are colloid stable in aqueous solution under different pH and temperature conditions. In vitro hemolytic assay, cytotoxicity assay, flow cytometry analysis, and cell morphology observation reveal that the formed Au DSNPs have good hemocompatibility and are non-cytotoxic at a concentration up to 3.0 μM. X-ray absorption coefficient measurements show that the DTA-containing Au DSNPs have enhanced attenuation intensity, much higher than that of [(Au(0))(50)-G5.NHAc] DENPs without DTA or Omnipaque at the same molar concentration of the active element (Au or iodine). The formed DTA-containing Au DSNPs can be used for CT imaging of cancer cells in vitro as well as for blood pool CT imaging of mice in vivo with significantly improved signal enhancement. With the two radiodense elements of Au and iodine incorporated within one particle, the formed DTA-containing Au DSNPs may be applicable for CT imaging of various biological systems with enhanced X-ray attenuation property and detection sensitivity.

  18. A combined approach for the enhancement and segmentation of mammograms using modified fuzzy C-means method in wavelet domain.

    Science.gov (United States)

    Srivastava, Subodh; Sharma, Neeraj; Singh, S K; Srivastava, R

    2014-07-01

    In this paper, a combined approach for enhancement and segmentation of mammograms is proposed. In preprocessing stage, a contrast limited adaptive histogram equalization (CLAHE) method is applied to obtain the better contrast mammograms. After this, the proposed combined methods are applied. In the first step of the proposed approach, a two dimensional (2D) discrete wavelet transform (DWT) is applied to all the input images. In the second step, a proposed nonlinear complex diffusion based unsharp masking and crispening method is applied on the approximation coefficients of the wavelet transformed images to further highlight the abnormalities such as micro-calcifications, tumours, etc., to reduce the false positives (FPs). Thirdly, a modified fuzzy c-means (FCM) segmentation method is applied on the output of the second step. In the modified FCM method, the mutual information is proposed as a similarity measure in place of conventional Euclidian distance based dissimilarity measure for FCM segmentation. Finally, the inverse 2D-DWT is applied. The efficacy of the proposed unsharp masking and crispening method for image enhancement is evaluated in terms of signal-to-noise ratio (SNR) and that of the proposed segmentation method is evaluated in terms of random index (RI), global consistency error (GCE), and variation of information (VoI). The performance of the proposed segmentation approach is compared with the other commonly used segmentation approaches such as Otsu's thresholding, texture based, k-means, and FCM clustering as well as thresholding. From the obtained results, it is observed that the proposed segmentation approach performs better and takes lesser processing time in comparison to the standard FCM and other segmentation methods in consideration.

  19. Transgenerational inheritance of modified DNA methylation patterns and enhanced tolerance induced by heavy metal stress in rice (Oryza sativa L.).

    Science.gov (United States)

    Ou, Xiufang; Zhang, Yunhong; Xu, Chunming; Lin, Xiuyun; Zang, Qi; Zhuang, Tingting; Jiang, Lili; von Wettstein, Diter; Liu, Bao

    2012-01-01

    DNA methylation is sensitive and responsive to stressful environmental conditions. Nonetheless, the extent to which condition-induced somatic methylation modifications can impose transgenerational effects remains to be fully understood. Even less is known about the biological relevance of the induced epigenetic changes for potentially altered well-being of the organismal progenies regarding adaptation to the specific condition their progenitors experienced. We analyzed DNA methylation pattern by gel-blotting at genomic loci representing transposable elements and protein-coding genes in leaf-tissue of heavy metal-treated rice (Oryza sativa) plants (S0), and its three successive organismal generations. We assessed expression of putative genes involved in establishing and/or maintaining DNA methylation patterns by reverse transcription (RT)-PCR. We measured growth of the stressed plants and their unstressed progenies vs. the control plants. We found (1) relative to control, DNA methylation patterns were modified in leaf-tissue of the immediately treated plants, and the modifications were exclusively confined to CHG hypomethylation; (2) the CHG-demethylated states were heritable via both maternal and paternal germline, albeit often accompanying further hypomethylation; (3) altered expression of genes encoding for DNA methyltransferases, DNA glycosylase and SWI/SNF chromatin remodeling factor (DDM1) were induced by the stress; (4) progenies of the stressed plants exhibited enhanced tolerance to the same stress their progenitor experienced, and this transgenerational inheritance of the effect of condition accompanying heritability of modified methylation patterns. Our findings suggest that stressful environmental condition can produce transgenerational epigenetic modifications. Progenies of stressed plants may develop enhanced adaptability to the condition, and this acquired trait is inheritable and accord with transmission of the epigenetic modifications. We suggest

  20. BisGMA/TEGDMA dental nanocomposites containing glyoxylic acid modified high-aspect ratio hydroxyapatite nanofibers with enhanced dispersion

    Science.gov (United States)

    Chen, Liang; Xu, Changqi; Wang, Yong; Shi, Jian; Yu, Qingsong

    2012-01-01

    The purpose of this research was to investigate the influence of the glyoxylic acid (GA) modification of hydroxyapatite (HAP) nanofibers on their dispersion in bisphenol A glycidyl methacrylate (BisGMA)/triethylene glycol dimethacrylate (TEGDMA) dental composites and also investigate the mechanical properties, water absorption, and water solubility of the resulting dental resins and composites. Scanning/Transmission electron microscopy (STEM) images showed that microsized HAP nanofiber bundles could be effectively broken down to individual HAP nanofibers with an average length of ~15 μm after the surface modification process. Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and thermal gravimetric analysis (TGA) characterization confirmed glyoxylic acid was chemically grafted on the HAP nanofiber surface, hypothetically by reacting with the amine group on HAP nanofiber surface. The enhanced dispersion of HAP nanofibers in dental matrix led to increased biaxial flexural strength (BFS) compared with the corresponding dental resins and composites filled with untreated HAP nanofibers. In addition, impregnation of small mass fractions of the glyoxylic acid modified HAP nanofibers into the BisGMA/TEGDMA dental resins (5wt%, 10wt%) or composites (2wt%, 3wt%) could also substantially improve the BFS in comparison with the controls(pure resins or dental composites filled with silica particles alone). Larger mass fractions could not further increase the mechanical property or even degrade the BFS values. Water behavior testing results indicated that the addition of glyoxylic acid modified HAP nanofibers resulted in higher water absorption and water solubility values which is not preferred for clinical application. In summary, well dispersed HAP nanofibers and their dental composites with enhanced mechanical property have been successfully fabricated but the water absorption and water solubility of such dental composites need to be

  1. BisGMA/TEGDMA dental nanocomposites containing glyoxylic acid-modified high-aspect ratio hydroxyapatite nanofibers with enhanced dispersion

    International Nuclear Information System (INIS)

    Chen Liang; Yu Qingsong; Li Hao; Xu Changqi; Wang Yong; Shi Jian

    2012-01-01

    The purpose of this research was to investigate the influence of the glyoxylic acid (GA) modification of hydroxyapatite (HAP) nanofibers on their dispersion in bisphenol A glycidyl methacrylate (BisGMA)/triethylene glycol dimethacrylate (TEGDMA) dental composites and also to investigate the mechanical properties, water absorption and water solubility of the resulting dental resins and composites. Scanning/transmission electron microscopy images showed that microsized HAP nanofiber bundles could be effectively broken down into individual HAP nanofibers with an average length of ∼15 µm after the surface modification process. Fourier transform infrared spectroscopy, x-ray photoelectron spectroscopy and thermal gravimetric analysis characterization confirmed that GA was chemically grafted on the HAP nanofiber surface, hypothetically by reacting with the amine group on the HAP nanofiber surface. The enhanced dispersion of HAP nanofibers in the dental matrix led to increased biaxial flexural strength (BFS) compared with the corresponding dental resins and composites filled with untreated HAP nanofibers. In addition, impregnation of small mass fractions of the GA-modified HAP nanofibers into the BisGMA/TEGDMA dental resins (5 wt%, 10 wt%) or composites (2 wt%, 3 wt%) could also substantially improve the BFS in comparison with the controls (pure resins or dental composites filled with silica particles alone). Larger mass fractions could not increase the mechanical property further or even degraded the BFS values. Water behavior testing results indicated that the addition of the GA-modified HAP nanofibers resulted in higher water absorption and water solubility values, which are not preferred for clinical application. In summary, well-dispersed HAP nanofibers and their dental composites with enhanced mechanical properties have been successfully fabricated, but the water absorption and water solubility of such dental composites need to be further improved. (paper)

  2. Enhancement of Osteoblastic-Like Cell Activity by Glow Discharge Plasma Surface Modified Hydroxyapatite/β-Tricalcium Phosphate Bone Substitute

    Directory of Open Access Journals (Sweden)

    Eisner Salamanca

    2017-11-01

    Full Text Available Glow discharge plasma (GDP treatments of biomaterials, such as hydroxyapatite/β-tricalcium phosphate (HA/β-TCP composites, produce surfaces with fewer contaminants and may facilitate cell attachment and enhance bone regeneration. Thus, in this study we used argon glow discharge plasma (Ar-GDP treatments to modify HA/β-TCP particle surfaces and investigated the physical and chemical properties of the resulting particles (HA/β-TCP + Ar-GDP. The HA/β-TCP particles were treated with GDP for 15 min in argon gas at room temperature under the following conditions: power: 80 W; frequency: 13.56 MHz; pressure: 100 mTorr. Scanning electron microscope (SEM observations showed similar rough surfaces of HA/β-TCP + Ar-GDP HA/β-TCP particles, and energy dispersive spectrometry analyses showed that HA/β-TCP surfaces had more contaminants than HA/β-TCP + Ar-GDP surfaces. Ca/P mole ratios in HA/β-TCP and HA/β-TCP + Ar-GDP were 1.34 and 1.58, respectively. Both biomaterials presented maximal intensities of X-ray diffraction patterns at 27° with 600 a.u. At 25° and 40°, HA/β-TCP + Ar-GDP and HA/β-TCP particles had peaks of 200 a.u., which are similar to XRD intensities of human bone. In subsequent comparisons, MG-63 cell viability and differentiation into osteoblast-like cells were assessed on HA/β-TCP and HA/β-TCP + Ar-GDP surfaces, and Ar-GDP treatments led to improved cell growth and alkaline phosphatase activities. The present data indicate that GDP surface treatment modified HA/β-TCP surfaces by eliminating contaminants, and the resulting graft material enhanced bone regeneration.

  3. Enhancement of visible-light photocatalytic activity of silver and mesoporous carbon co-modified Bi2WO6

    International Nuclear Information System (INIS)

    Zhao, Qian; Gong, Ming; Liu, Wangping; Mao, Yulin; Le, Shukun; Ju, Shang; Long, Fei; Liu, Xiufang; Liu, Kai; Jiang, Tingshun

    2015-01-01

    Graphical abstract: - Highlights: • Silver and mesoporous carbon co-modified Bi 2 WO 6 (Ag/Bi 2 WO 6 /CMK-3) composite was prepared. • Photocatalytic activity of Bi 2 WO 6 was remarkably enhanced by co-modification of silver and mesoporous carbon. • The degradation rate of MB can reach ca. 95.1% under visible light irradiation. • The Ag/Bi 2 WO 6 /CMK-3 composite has good stability and potential application prospects. - Abstract: Ordered mesoporous carbon CMK-3 was prepared by hard template method using SBA-15 as template, sucrose as carbon source. Flower/sphere-like Bi 2 WO 6 and CMK-3/Bi 2 WO 6 photocatalysts were synthesized by hydrothermal method, and then Ag/Bi 2 WO 6 and Ag/Bi 2 WO 6 /CMK-3 composite photocatalysts were prepared via a photoreduction process. The samples were characterized by XRD, UV–vis, TEM (HR-TEM), SEM, N 2 physical adsorption and PL and their photocatalytic activities were evaluated by the photocatalytic degradation of methylene blue (MB) under visible light irradiation. The results show that both incorporating of CMK-3 and Ag loading greatly improved the photocatalytic activity of Bi 2 WO 6 , and the content of CMK-3 and silver have an impact on the photocatalytic activity of Bi 2 WO 6 . The photocatalytic activity of Ag/Bi 2 WO 6 /CMK-3 photocatalyst is superior to the activities of CMK-3/Bi 2 WO 6 and Ag/Bi 2 WO 6 under comparable conditions, and Ag/Bi 2 WO 6 /CMK-3 photocatalyst has high stability and is easy to be recycled. Also, the mechanism for the enhancement of the photocatalytic activity of CMK-3 and Ag co-modified Bi 2 WO 6 was also investigated

  4. Enhancement of modified solar still integrated with external condenser using nanofluids: An experimental approach

    International Nuclear Information System (INIS)

    Kabeel, A.E.; Omara, Z.M.; Essa, F.A.

    2014-01-01

    Highlights: • The effect of using nanofluids on the solar still performance is investigated. • The solar still with external condenser increases the productivity by about 53.2%. • Using nanofluids improves the solar still water productivity by about 116%. - Abstract: The distilled water productivity of the single basin solar still is very limited. In this context, the design modification of a single basin solar still has been investigated to improve the solar still performance through increasing the productivity of distilled water. The experimental attempts are made to enhance the solar still productivity by using nanofluids and also by integrating the still basin with external condenser. The used nanofluid is the suspended nanosized solid particles of aluminum-oxide in water. Nanofluids change the transport properties, heat transfer characteristics and evaporative properties of the water. Nanofluids are expected to exhibit superior evaporation rate compared with conventional water. The effect of adding external condenser to the still basin is to decrease the heat loss by convection from water to glass as the condenser acts as an additional and effective heat and mass sink. So, the effect of drawn vapor at different speeds was investigated. The results show that integrating the solar still with external condenser increases the distillate water yield by about 53.2%. And using nanofluids improves the solar still water productivity by about 116%, when the still integrated with the external condenser

  5. Enhanced dielectric and ferroelectric characteristics in Ca-modified BaTiO3 ceramics

    Directory of Open Access Journals (Sweden)

    Xiao Na Zhu

    2013-08-01

    Full Text Available Synergic modification of BaTiO3 ceramics was investigated by Ca-substitution, and the superior dielectric and ferroelectric properties were determined together with the structure evolution. X-ray diffraction (XRD analysis demonstrated a large solubility limit above x = 0.25 in Ba1−xCaxTiO3 solid solution where the fine grain structure was observed with increasing x. Room temperature dielectric constant as high as 1655 was achieved in the present ceramics together with the significantly reduced dielectric loss of 0.013 (x = 0.20 at 100 kHz, where the Curie temperature kept almost a constant while other two transition temperatures decreased continuously with increasing x. More importantly, the remanent polarization Pr and dielectric strength Eb were significantly enhanced by Ca-substitution, and the best Pr (11.34 μC/cm2 and the highest dielectric strength Eb (75 kV/cm were acquired at x = 0.25. The present ceramics should be very desirable for the applications such as high density energy storage devices.

  6. Two fold modified chitosan for enhanced adsorption of hexavalent chromium from simulated wastewater and industrial effluents.

    Science.gov (United States)

    Kahu, S S; Shekhawat, A; Saravanan, D; Jugade, R M

    2016-08-01

    Ionic solid (Ethylhexadecyldimethylammoniumbromide) impregnated phosphated chitosan (ISPC) was synthesized and applied for enhanced adsorption of hexavalent chromium from industrial effluent. The compound obtained was extensively characterized using instrumental techniques like FT-IR, TGA-DTA, XRD, SEM, BET and EDX. ISPC showed high adsorption capacity of 266.67mg/g in accordance with Langmuir isotherm model at pH 3.0 due to the presence of multiple sites which contribute for ion pair and electrostatic interactions with Cr(VI) species. The sorption kinetics and thermodynamic studies revealed that adsorption of Cr(VI) followed pseudo-second-order kinetics with exothermic and spontaneous behaviour. Applicability of ISPC for higher sample volumes was discerned through column studies. The real chrome plating industry effluent was effectively treated with total chromium recovery of 94%. The used ISPC was regenerated simply by dilute ammonium hydroxide treatment and tested for ten adsorption-desorption cycles with marginal decrease in adsorption efficiency. Copyright © 2016 Elsevier Ltd. All rights reserved.

  7. Enhanced Deformation of Azobenzene-Modified Liquid Crystal Polymers under Dual Wavelength Exposure: A Photophysical Model

    Science.gov (United States)

    Liu, Ling; Onck, Patrick R.

    2017-08-01

    Azobenzene-embedded liquid crystal polymers can undergo mechanical deformation in response to ultraviolet (UV) light. The natural rodlike trans state azobenzene absorbs UV light and isomerizes to a bentlike cis state, which disturbs the order of the polymer network, leading to an anisotropic deformation. The current consensus is that the magnitude of the photoinduced deformation is related to the statistical building up of molecules in the cis state. However, a recent experimental study [Liu and Broer, Nat. Commun. 6 8334 (2015)., 10.1038/ncomms9334] shows that a drastic (fourfold) increase of the photoinduced deformation can be generated by exposing the samples simultaneously to 365 nm (UV) and 455 nm (visible) light. To elucidate the physical mechanism that drives this increase, we develop a two-light attenuation model and an optomechanical constitutive relation that not only accounts for the statistical accumulation of cis azobenzenes, but also for the dynamic trans-cis-trans oscillatory isomerization process. Our experimentally calibrated model predicts that the optimal single-wavelength exposure is 395 nm light, a pronounced shift towards the visible spectrum. In addition, we identify a range of optimal combinations of two-wavelength lights that generate a favorable response for a given amount of injected energy. Our model provides mechanistic insight into the different (multi)wavelength exposures used in experiments and, at the same time, opens new avenues towards enhanced, multiwavelength optomechanical behavior.

  8. Pt-modified carbon nanotube networked layers for enhanced gas microsensors

    International Nuclear Information System (INIS)

    Penza, M.; Rossi, R.; Alvisi, M.; Suriano, D.; Serra, E.

    2011-01-01

    Carbon nanotubes (CNTs) networked films have been grown by chemical vapor deposition (CVD) technology onto miniaturized low-cost alumina substrates, coated by nanosized Co-catalyst for growing CNTs, to perform chemical detection of toxic gasses (NO 2 and NH 3 ), greenhouse gasses (CO 2 and CH 4 ) and domestic safety gasses (CO and C 2 H 5 OH) at an operating sensor temperature of 120 °C. The morphology and structure of the CNTs networks have been characterized by scanning electron microscopy (SEM). A dense network of bundles of multiple tubes consisting of multi-walled carbon nanostructures appears with a maximum length of 1–5 μm and single-tube diameter varying in the range of 5–40 nm. Surface modifications of the CNTs networks with sputtered Platinum (Pt) nanoclusters, at tuned loading of 8, 15 and 30 nm, provide higher sensitivity for significantly enhanced gas detection compared to un-decorated CNTs. This could be caused by a spillover of the targeted gas molecules onto Pt-catalyst surface with a chemical gating into CNTs layers. The measured electrical conductance of the functionalized CNTs upon exposures of a given oxidizing and reducing gas is modulated by a charge transfer model with p-type semiconducting characteristics. The effect of activated carbons as chemical filters to reduce the influence of the domestic interfering alcohols on CO gas detection has been studied. Functionalized CNT gas sensors exhibited better performances compared to unmodified CNTs, making them highly promising candidates for functional applications of gas control and alarms.

  9. Enhanced compatibility of chemically modified titanium surface with periodontal ligament cells

    International Nuclear Information System (INIS)

    Kado, T.; Hidaka, T.; Aita, H.; Endo, K.; Furuichi, Y.

    2012-01-01

    Highlights: ► Cell-adhesive molecules were covalently immobilized on a Ti surface. ► Immobilized cell-adhesive molecules maintained native function on the Ti surface. ► Immobilized collagen enhanced adhesion of periodontal ligament cells to the Ti. - Abstract: A simple chemical modification method was developed to immobilize cell-adhesive molecules on a titanium surface to improve its compatibility with human periodontal ligament cells (HPDLCs).The polished titanium disk was immersed in 1% (v/v) p-vinylbenzoic acid solution for 2 h to introduce carboxyl groups onto the surface. After rinsing with distilled deionized water, the titanium disk was dipped into 1.47% 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide solution containing 0.1 mg/ml Gly-Arg-Gly-Asp-Ser (GRGDS), human plasma fibronectin (pFN), or type I collagen from calf skin (Col) to covalently immobilize the cell-adhesive molecules on the titanium surface via formation of peptide bonds. X-ray photoelectron spectroscopy analyses revealed that cell-adhesive molecules were successfully immobilized on the titanium surfaces. The Col-immobilized titanium surface revealed higher values regarding nano rough characteristics than the as-polished titanium surface under scanning probe microscopy. The number of HPDLCs attached to both the pFN- and Col-immobilized titanium surfaces was twice that attached to the as-polished titanium surfaces. The cells were larger with the cellular processes that stretched to a greater extent on the pFN- and Col-immobilized titanium surfaces than on the as-polished titanium surface (p < 0.05). HPDLCs on the Col-immobilized titanium surfaces showed more extensive expression of vinculin at the tips of cell projections and more contiguously along the cell outline than on the as-polished, GRGDS-immobilized and pFN-immobilized titanium surfaces. It was concluded that cell-adhesive molecules successfully immobilized on the titanium surface and improved the compatibility of the surface

  10. Cognitive enhancers (nootropics). Part 3: drugs interacting with targets other than receptors or enzymes. disease-modifying drugs.

    Science.gov (United States)

    Froestl, Wolfgang; Pfeifer, Andrea; Muhs, Andreas

    2013-01-01

    Cognitive enhancers (nootropics) are drugs to treat cognition deficits in patients suffering from Alzheimer's disease, schizophrenia, stroke, attention deficit hyperactivity disorder, or aging. Cognition refers to a capacity for information processing, applying knowledge, and changing preferences. It involves memory, attention, executive functions, perception, language, and psychomotor functions. The term nootropics was coined in 1972 when memory enhancing properties of piracetam were observed in clinical trials. In the meantime, hundreds of drugs have been evaluated in clinical trials or in preclinical experiments. To classify the compounds, a concept is proposed assigning drugs to 19 categories according to their mechanism(s) of action, in particular drugs interacting with receptors, enzymes, ion channels, nerve growth factors, re-uptake transporters, antioxidants, metal chelators, and disease modifying drugs, meaning small molecules, vaccines, and monoclonal antibodies interacting with amyloid-β and tau. For drugs, whose mechanism of action is not known, they are either classified according to structure, e.g., peptides, or their origin, e.g., natural products. The review covers the evolution of research in this field over the last 25 years.

  11. Interface control: A modified rooting technique for enhancing field emission from multiwall carbon nanotube based bulk emitters

    Energy Technology Data Exchange (ETDEWEB)

    Lahiri, Indranil [Nanomaterials and Device Lab, Department of Mechanical and Materials Engineering, Florida International University, 10555 West Flagler Street, Miami, FL 33174 (United States); Choi, Wonbong, E-mail: choiw@fiu.edu [Nanomaterials and Device Lab, Department of Mechanical and Materials Engineering, Florida International University, 10555 West Flagler Street, Miami, FL 33174 (United States)

    2011-08-15

    The unique properties of carbon nanotubes (CNTs) have raised hopes that these materials might find wide application as cold cathodes in various electron sources. The excellent field emission properties shown by CNT-based field emitters has further stimulated this expectation. However, efficient performance of a practical field emitter, which comprises a large number of randomly or regularly oriented CNTs, is restricted primarily due to poor junctions formed between CNTs and substrates. This study is aimed at enhancing the junction performance by way of a modified 'rooting' technique-interface control. In this process, the interface between CNTs and substrate has been tailored with different metals in an attempt to improve the CNT-substrate junction performance. Multiwall carbon nanotubes (MWCNTs) were synthesized on different interface-controlled substrates, i.e. Cu, Al, W, Si and low-temperature co-fired ceramic. All the samples produced mat-type, randomly oriented MWCNT structures. Among the four different substrates studied, MWCNT-based field emitters on Cu substrate demonstrated the best field emission response, in terms of low turn-on field, high emission current, good field enhancement factor and excellent stability in long-term operation. Emitter structures and their field emission behavior were correlated and it was shown that interface control, as an advanced 'rooting' process, plays an important role in determining the emission response from a bulk field emitter.

  12. Enhanced photovoltaic performance of QDSSCs via modifying ZnO photoanode with a 3-PPA self-assembled monolayer

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Lili, E-mail: jhyang1@jlnu.edu.cn [Department of Physics, Jilin Normal University, Siping 136000 (China); Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Siping 136000, Jilin (China); Chen, Gang; Sun, Yunfei [Department of Physics, Jilin Normal University, Siping 136000 (China); Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Siping 136000, Jilin (China); Han, Donglai; Yang, Shuo [State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Gao, Ming; Wang, Zhe; Zou, Ping; Luan, Hongmei; Kong, Xiangwang; Yang, Jinghai [Department of Physics, Jilin Normal University, Siping 136000 (China); Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Siping 136000, Jilin (China)

    2015-02-15

    Graphical abstract: - Highlights: • The CdS/3-PPA/ZnO QDSSCs were construct in our experiment. • The power conversion efficiency was strongly enhanced after depositing 3-PPA layer. • The 3-PPA layer serves as a recombination barrier and passivates surface defects. - Abstract: A SAMs layer of 3-PPA with a phosphonic acid headgroup and carboxylic acid tailgroups has been used to modify the surface of ZnO nanorods photoanode in CdS quantum dots sensitized solar cells. Its effects on the photovoltic performance have been investigated in detail by adjusting the concentration and deposition time of 3-PPA. Especially, we utilize ultraviolet photoelectron spectroscopy to characterize the variation of band alignment after introducing 3-PPA layer in the solar cells. The results reveal that the 3-PPA not only suppress the electron-hole recombination process due to its passivation on the surface defects, but forms an energy barrier to efficiently retard the back transfer of electrons, which finally results in the enhancement of conversion efficiency of solar cells.

  13. Enhanced photovoltaic performance of QDSSCs via modifying ZnO photoanode with a 3-PPA self-assembled monolayer

    International Nuclear Information System (INIS)

    Yang, Lili; Chen, Gang; Sun, Yunfei; Han, Donglai; Yang, Shuo; Gao, Ming; Wang, Zhe; Zou, Ping; Luan, Hongmei; Kong, Xiangwang; Yang, Jinghai

    2015-01-01

    Graphical abstract: - Highlights: • The CdS/3-PPA/ZnO QDSSCs were construct in our experiment. • The power conversion efficiency was strongly enhanced after depositing 3-PPA layer. • The 3-PPA layer serves as a recombination barrier and passivates surface defects. - Abstract: A SAMs layer of 3-PPA with a phosphonic acid headgroup and carboxylic acid tailgroups has been used to modify the surface of ZnO nanorods photoanode in CdS quantum dots sensitized solar cells. Its effects on the photovoltic performance have been investigated in detail by adjusting the concentration and deposition time of 3-PPA. Especially, we utilize ultraviolet photoelectron spectroscopy to characterize the variation of band alignment after introducing 3-PPA layer in the solar cells. The results reveal that the 3-PPA not only suppress the electron-hole recombination process due to its passivation on the surface defects, but forms an energy barrier to efficiently retard the back transfer of electrons, which finally results in the enhancement of conversion efficiency of solar cells

  14. Interface control: A modified rooting technique for enhancing field emission from multiwall carbon nanotube based bulk emitters

    International Nuclear Information System (INIS)

    Lahiri, Indranil; Choi, Wonbong

    2011-01-01

    The unique properties of carbon nanotubes (CNTs) have raised hopes that these materials might find wide application as cold cathodes in various electron sources. The excellent field emission properties shown by CNT-based field emitters has further stimulated this expectation. However, efficient performance of a practical field emitter, which comprises a large number of randomly or regularly oriented CNTs, is restricted primarily due to poor junctions formed between CNTs and substrates. This study is aimed at enhancing the junction performance by way of a modified 'rooting' technique-interface control. In this process, the interface between CNTs and substrate has been tailored with different metals in an attempt to improve the CNT-substrate junction performance. Multiwall carbon nanotubes (MWCNTs) were synthesized on different interface-controlled substrates, i.e. Cu, Al, W, Si and low-temperature co-fired ceramic. All the samples produced mat-type, randomly oriented MWCNT structures. Among the four different substrates studied, MWCNT-based field emitters on Cu substrate demonstrated the best field emission response, in terms of low turn-on field, high emission current, good field enhancement factor and excellent stability in long-term operation. Emitter structures and their field emission behavior were correlated and it was shown that interface control, as an advanced 'rooting' process, plays an important role in determining the emission response from a bulk field emitter.

  15. Enhanced Photocatalytic Degradation of Methyl Orange Dye under the Daylight Irradiation over CN-TiO₂ Modified with OMS-2.

    Science.gov (United States)

    Hassan, Mohamed Elfatih; Chen, Jing; Liu, Guanglong; Zhu, Duanwei; Cai, Jianbo

    2014-12-12

    In this study, CN-TiO₂ was modified with cryptomelane octahedral molecular sieves (OMS-2) by the sol-gel method based on the self-assembly technique to enhance its photocatalytic activity under the daylight irradiation. The synthesized samples were characterized by X-ray diffraction (XRD), UV-vis spectroscopy, Fourier transform infrared spectroscopy (FT-IR) and porosimeter analysis. The results showed that the addition of OMS-2 in the sol lead to higher Brunauer-Emmett-Teller (BET) surface area, pore volume, porosity of particle after heat treatment and the specific surface area, porosity, crystallite size and pore size distribution could be controlled by adjusting the calcination temperature. Compared to the CN-TiO₂-400 sample, CN-TiO₂/OMS-2-400 exhibited greater red shift in absorption edge of samples in visible region due to the OMS-2 coated. The enhancement of photocatalytic activity of CN-TiO₂/OMS-2 composite photocatalyst was subsequently evaluated for the degradation of the methyl orange dye under the daylight irradiation in water. The results showed that the methyl orange dye degradation rate reach to 37.8% for the CN-TiO₂/OMS-2-400 sample under the daylight irradiation for 5 h, which was higher than that of reference sample. The enhancement in daylight photocatalytic activities of the CN-TiO₂/OMS samples could be attributed to the synergistic effects of OMS-2 coated, larger surface area and red shift in adsorption edge of the prepared sample.

  16. A 3D Faraday Shield for Interdigitated Dielectrometry Sensors and Its Effect on Capacitance

    Directory of Open Access Journals (Sweden)

    Alex Risos

    2016-12-01

    Full Text Available Interdigitated dielectrometry sensors (IDS are capacitive sensors investigated to precisely measure the relative permittivity ( ϵ r of insulating liquids. Such liquids used in the power industry exhibit a change in ϵ r as they degrade. The IDS ability to measure ϵ r in-situ can potentially reduce maintenance, increase grid stability and improve safety. Noise from external electric field sources is a prominent issue with IDS. This paper investigates the novelty of applying a Faraday cage onto an IDS as a 3D shield to reduce this noise. This alters the spatially distributed electric field of an IDS affecting its sensing properties. Therefore, dependency of the sensor’s signal with the distance to a shield above the IDS electrodes has been investigated experimentally and theoretically via a Green’s function calculation and FEM. A criteria of the shield’s distance s = s 0 has been defined as the distance which gives a capacitance for the IDS equal to 1 − e − 2 = 86.5 % of its unshielded value. Theoretical calculations using a simplified geometry gave a constant value for s 0 / λ = 1.65, where λ is the IDS wavelength. In the experiment, values for s 0 were found to be lower than predicted as from theory and the ratio s 0 / λ variable. This was analyzed in detail and it was found to be resulting from the specific spatial structure of the IDS. A subsequent measurement of a common insulating liquid with a nearby noise source demonstrates a considerable reduction in the standard deviation of the relative permittivity from σ unshielded = ± 9.5% to σ shielded = ± 0.6%. The presented findings enhance our understanding of IDS in respect to the influence of a Faraday shield on the capacitance, parasitic capacitances of the IDS and external noise impact on the measurement of ϵ r .

  17. A 3D Faraday Shield for Interdigitated Dielectrometry Sensors and Its Effect on Capacitance.

    Science.gov (United States)

    Risos, Alex; Long, Nicholas; Hunze, Arvid; Gouws, Gideon

    2016-12-31

    Interdigitated dielectrometry sensors (IDS) are capacitive sensors investigated to precisely measure the relative permittivity ( ϵ r ) of insulating liquids. Such liquids used in the power industry exhibit a change in ϵ r as they degrade. The IDS ability to measure ϵ r in-situ can potentially reduce maintenance, increase grid stability and improve safety. Noise from external electric field sources is a prominent issue with IDS. This paper investigates the novelty of applying a Faraday cage onto an IDS as a 3D shield to reduce this noise. This alters the spatially distributed electric field of an IDS affecting its sensing properties. Therefore, dependency of the sensor's signal with the distance to a shield above the IDS electrodes has been investigated experimentally and theoretically via a Green's function calculation and FEM. A criteria of the shield's distance s = s 0 has been defined as the distance which gives a capacitance for the IDS equal to 1 - e - 2 = 86.5 % of its unshielded value. Theoretical calculations using a simplified geometry gave a constant value for s 0 / λ = 1.65, where λ is the IDS wavelength. In the experiment, values for s 0 were found to be lower than predicted as from theory and the ratio s 0 / λ variable. This was analyzed in detail and it was found to be resulting from the specific spatial structure of the IDS. A subsequent measurement of a common insulating liquid with a nearby noise source demonstrates a considerable reduction in the standard deviation of the relative permittivity from σ unshielded = ± 9.5% to σ shielded = ± 0.6%. The presented findings enhance our understanding of IDS in respect to the influence of a Faraday shield on the capacitance, parasitic capacitances of the IDS and external noise impact on the measurement of ϵ r .

  18. A Left-Hand Rule for Faraday's Law

    Science.gov (United States)

    Salu, Yehuda

    2014-01-01

    A left-hand rule for Faraday's law is presented here. This rule provides a simple and quick way of finding directional relationships between variables of Faraday's law without using Lenz's rule.

  19. High-field Faraday rotation in II-VI-based semimagnetic semiconductors

    NARCIS (Netherlands)

    Savchuk, AI; Fediv, [No Value; Nikitin, PI; Perrone, A; Tatzenko, OM; Platonov, VV

    The effects of d-d exchange interaction have been studied by measuring high-field Faraday rotation in II-VI-based semimagnetic semiconductors. For Cd1-xMnxTe crystals with x = 0.43 and at room temperature a saturation in magnetic field dependence of the Faraday rotation has been observed. In the

  20. Magneto-optically modulated CH/sub 3/OH laser For faraday rotation measurements in tokamaks

    International Nuclear Information System (INIS)

    Mansfield, D.K.; Johnson, L.C.

    1981-01-01

    Distortion-free intracavity polarization modulation of an optically pumped CH/sub 3/OH laser is shown to be viable. The possible use of this modulation technique to make a multichannel Faraday rotation measurement on a Tokamak device is discussed. In addition, the CdTe Faraday modulator employed in this study is shown to have an anomalously large Verdet constant. 12 refs

  1. A magneto-optically modulated CH3OH laser for Faraday rotation measurements in tokamaks

    International Nuclear Information System (INIS)

    Mansfield, D.K.; Johnson, L.C.

    1981-01-01

    Distortion-free intracavity polarization modulation of an optically pumped CH3OH laser is shown to be viable. The possible use of this modulation technique to make a multichannel Faraday rotation measurement on a tokamak device is discussed. In addition, the CdTe Faraday modulator employed in this study is shown to have an anomalously large Verdet constant

  2. Faraday cup with nanosecond response and adjustable impedance for fast electron beam characterization

    International Nuclear Information System (INIS)

    Hu Jing; Rovey, Joshua L.

    2011-01-01

    A movable Faraday cup design with simple structure and adjustable impedance is described in this work. This Faraday cup has external adjustable shunt resistance for self-biased measurement setup and 50 Ω characteristic impedance to match with 50 Ω standard BNC coaxial cable and vacuum feedthroughs for nanosecond-level pulse signal measurements. Adjustable shunt resistance allows self-biased measurements to be quickly acquired to determine the electron energy distribution function. The performance of the Faraday cup is validated by tests of response time and amplitude of output signal. When compared with a reference source, the percent difference of the Faraday cup signal fall time is less than 10% for fall times greater than 10 ns. The percent difference of the Faraday cup signal pulse width is below 6.7% for pulse widths greater than 10 ns. A pseudospark-generated electron beam is used to compare the amplitude of the Faraday cup signal with a calibrated F-70 commercial current transformer. The error of the Faraday cup output amplitude is below 10% for the 4-14 kV tested pseudospark voltages. The main benefit of this Faraday cup is demonstrated by adjusting the external shunt resistance and performing the self-biased method for obtaining the electron energy distribution function. Results from a 4 kV pseudospark discharge indicate a ''double-humped'' energy distribution.

  3. Representing the Electromagnetic Field: How Maxwell's Mathematics Empowered Faraday's Field Theory

    Science.gov (United States)

    Tweney, Ryan D.

    2011-01-01

    James Clerk Maxwell "translated" Michael Faraday's experimentally-based field theory into the mathematical representation now known as "Maxwell's Equations." Working with a variety of mathematical representations and physical models Maxwell extended the reach of Faraday's theory and brought it into consistency with other…

  4. Faraday cup with nanosecond response and adjustable impedance for fast electron beam characterization.

    Science.gov (United States)

    Hu, Jing; Rovey, Joshua L

    2011-07-01

    A movable Faraday cup design with simple structure and adjustable impedance is described in this work. This Faraday cup has external adjustable shunt resistance for self-biased measurement setup and 50 Ω characteristic impedance to match with 50 Ω standard BNC coaxial cable and vacuum feedthroughs for nanosecond-level pulse signal measurements. Adjustable shunt resistance allows self-biased measurements to be quickly acquired to determine the electron energy distribution function. The performance of the Faraday cup is validated by tests of response time and amplitude of output signal. When compared with a reference source, the percent difference of the Faraday cup signal fall time is less than 10% for fall times greater than 10 ns. The percent difference of the Faraday cup signal pulse width is below 6.7% for pulse widths greater than 10 ns. A pseudospark-generated electron beam is used to compare the amplitude of the Faraday cup signal with a calibrated F-70 commercial current transformer. The error of the Faraday cup output amplitude is below 10% for the 4-14 kV tested pseudospark voltages. The main benefit of this Faraday cup is demonstrated by adjusting the external shunt resistance and performing the self-biased method for obtaining the electron energy distribution function. Results from a 4 kV pseudospark discharge indicate a "double-humped" energy distribution.

  5. ICRF Faraday shield plasma sheath models: Low and high conductivity limits

    International Nuclear Information System (INIS)

    Whealton, J.H.; Ryan, P.M.; Raridon, R.J.

    1989-01-01

    Using a 2-D nonlinear formulation which explicitly considers the plasma edge near a Faraday shield in a self consistent manner, progress is indicated in the modeling of the ion motion for a Faraday shield concept and model suggested by Perkins. Several models are considered which may provide significant insight into the impurities generation for ICRH antennas. 6 refs., 8 figs

  6. Application of Faraday cup array detector in measurement of electron-beam distribution homogeneity

    International Nuclear Information System (INIS)

    Xu Zhiguo; Wang Jinchuan; Xiao Guoqing; Guo Zhongyan; Wu Lijie; Mao Ruishi; Zhang Li

    2005-01-01

    It is described that a kind of Faraday cup array detector, which consists of Faraday cup, suppressor electrode insulation PCB board, Base etc. The homogeneity of electron-beam distribution is measured and the absorbed dose for the irradiated sample is calculated. The results above provide the important parameters for the irradiation experiment and the improvement for the quality of electron beam. (authors)

  7. Absorption lines, Faraday rotation, and magnetic field estimates for QSO absorption-line clouds

    International Nuclear Information System (INIS)

    Kronberg, P.P.; Perry, J.J.

    1982-01-01

    We have estimated the extragalactic component of Faraday rotation for a sample of 37 QSOs for which there is good absorption line data, which we have also analyzed. Statistical evidence is presented which suggests that we have isolated a component of Faraday rotation which is occurring in the absorption clouds of some QSOs

  8. Electric potential behaviour in segmented Faraday-type MHD generators

    International Nuclear Information System (INIS)

    James, M.I.; Mittal, M.L.; Gupta, G.P.; Rohatgi, V.K.

    1985-01-01

    The potential distribution in the transverse cross-section of a segmented Faraday-type MHD generator is studied. The governing elliptic equation, derived with allowance for the finite electrode segmentation effect and nonuniformity of the gas in the channel, is solved numerically using the Alternating Direction Implicit method in the finite difference scheme, instead of the successive over-relaxation method. The computed potential distribution and the potential drops are found to compare well with experimental results. The potential drops at the electrodes are found to increase with increasing current density. (author)

  9. Faraday-rotation measurements in ISX-B

    International Nuclear Information System (INIS)

    Hutchinson, D.P.; Ma, C.H.; Staats, P.A.; Vander Sluis, K.L.

    1982-01-01

    A submillimeter-wave, phase-modulated polarimeter/interferometer is used for simultaneous time-dependent measurement of line-averaged electron density and poloidal field-induced Faraday rotation along chords of the plasma column in ISX-B tokamak. Heterodyne detection and hollow dielectric waveguide are utilized to achieve the high sensitivity required for the multichord experiment. A data analysis code has been developed to reconstruct the asymmetric distributions of plasma density. The validity of the code is examined, and the result shows good agreement with density profiles measured by Thomson scattering

  10. The Correspondence of Michael Faraday Pt 6 1860-1867

    CERN Document Server

    Frank, James

    2012-01-01

    Michael Faraday (1791-1867) was one of the most important men of science in nineteenth century Britain. His discoveries of electro-magnetic rotations (1821) and electro-magnetic induction (1831) laid the foundations of the modern electrical industry. His discovery of the magneto-optical effect and diamagnetism (1845) led him to formulate the field theory of electro-magnetism, which forms one of the cornerstones of modern physics.These and a whole host of other fundamental discoveries in physics and chemistry, together with his lecturing at the Royal Institution, his work for the state (includi

  11. FARADAY ROTATION IN a-As2Se3

    OpenAIRE

    Vanhuyse , B.; Van Den Keybus , P.; Grevendonk , W.

    1981-01-01

    Measurements of Faraday Rotation (FR) in amorphous As2Se3, as a function of photon energy are reported. In the bulk material the temperature dependence of the FR and the derived energy gap EFRg is investigated in the range 3-300 K. For EFRg a temperature coefficient of 2.4 x 10-4 eV/K is found. In amorphous films the FR could be measured through the energy range where the sign of the FR-angle is reversed. The photon energy corresponding to zero FR is in agreement with the gap value calculated...

  12. Observation of Faraday Waves in a Bose-Einstein Condensate

    International Nuclear Information System (INIS)

    Engels, P.; Atherton, C.; Hoefer, M. A.

    2007-01-01

    Faraday waves in a cigar-shaped Bose-Einstein condensate are created. It is shown that periodically modulating the transverse confinement, and thus the nonlinear interactions in the BEC, excites small amplitude longitudinal oscillations through a parametric resonance. It is also demonstrated that even without the presence of a continuous drive, an initial transverse breathing mode excitation of the condensate leads to spontaneous pattern formation in the longitudinal direction. Finally, the effects of strongly driving the transverse breathing mode with large amplitude are investigated. In this case, impact-oscillator behavior and intriguing nonlinear dynamics, including the gradual emergence of multiple longitudinal modes, are observed

  13. Faraday cup: absolute dosimetry for ELIMED beam line

    International Nuclear Information System (INIS)

    Leanza, R.; Romano, F.; Scuderi, V.; Amico, A.G.; Cuttone, G.; Larosa, G.; Milluzzo, G.; Petringa, G.; Pipek, J.; Cirrone, G.A.P.; Margarone, D.; Schillaci, F.

    2017-01-01

    The scientific community has shown a growing interest towards multidisciplinary applications of laser-driven beams. In this framework, the ELIMED (ELI-Beamlines MEDical and multidisciplinary applications) beamline will be the first transport beamline dedicated to the medical and multidisciplinary studies with laser-accelerated ion beams. Detectors for dosimetry represent one of key-element of the ELIMED beamline, allowing a dose delivering with good result as required in the clinical applications. In this contribution, a Faraday Cup for absolute dosimetry, designed and realized at INFN-LNS, is described.

  14. Preinjector for Linac 1, inside the Faraday cage

    CERN Multimedia

    1974-01-01

    For a description of the Linac 1 preinjector, please see first 7403070X. Here, the view is towards the upper level of the Faraday cage. Far to the right, a technician is peering through the service door. The huge box-shaped cubicle is the electronics platform, at 520 kV potential during operation. The "bull eye" at the left back sits at the top end of the accelerating column (see 7403081X) and houses the ion source with its electronics (see 7403083X). The SAMES generator, providing the 520 kV HV (7403074) sits on the floor and is not visible here.

  15. Localized instability on the route to disorder in Faraday waves.

    Science.gov (United States)

    Shani, Itamar; Cohen, Gil; Fineberg, Jay

    2010-05-07

    We experimentally investigate how disorder comes about in parametrically excited waves on a fluid surface (Faraday waves). We find that the transition from an ordered pattern to disorder corresponding to "defect-mediated turbulence" is mediated by a spatially incoherent oscillatory phase. This phase consists of highly damped waves that propagate through the effectively elastic lattice defined by the pattern. They have a well-defined frequency, velocity, and transverse polarization. As these waves decay within a few lattice spaces, they are spatially and temporally uncorrelated at larger scales.

  16. Anisotropy of the Faraday effect in the weak ferromagnet YFeO3

    International Nuclear Information System (INIS)

    Zenkov, A.V.; Krichevtsov, B.B.; Moskvin, A.S.; Mukimov, K.M.; Pisarev, R.V.; Ruvinshtein, M.M.

    1989-01-01

    An experimental investigation was made of the magnetic-field dependence of the Faraday effect in a weak ferromagnet YFeO 3 at the wavelength λ = 0.63 μm. Measurements were made for different orientations of the direction of light propagation k and of the magnetic field H. Changes in the Faraday effect in the k parallel c, H parallel a case were not proportional to changes in the component of the magnetic moment m z . A phenomenological description of the Faraday effect in YFeO 3 was used to separate the ferromagnetic, antiferromagnetic, and diamagnetic contributions to the effect. The antiferromagnetic contribution dominating the Faraday effect was strongly anisotropic. A theoretical analysis was made of the microscopic Faraday effect mechanisms in YFeO 3 using the example of a dipole-allowed transition 6 A 1g → 6 T 1u

  17. Enhancement of uranium(VI) biosorption by chemically modified marine-derived mangrove endophytic fungus Fusarium sp. ZZF51

    International Nuclear Information System (INIS)

    Chen, F.; Tan, N.; Long, W.; Yang, S.K.; She, Z.G.; Lin, Y.C.

    2014-01-01

    Fusarium sp. ZZF51, mangrove endophytic fungus originated from South China Sea coast, was chemically modified by formaldehyde, methanol and acetic acid to enhance its affinity of uranium(VI) from waste water. The influencing factors about uranium(VI) adsorption such as contact time, solution pH, the ratio of solid/liquid (S/L) and initial uranium(VI) concentration were investigated, and the suitable adsorption isotherm and kinetic models were determined. In addition, the biosorption mechanism was also discussed by FTIR analysis. Experimental results show that the maximum biosorption capacity of formaldehyde-treated biomass for uranium(VI) at the optimized condition of pH 6.0, S/L 0.6 and equilibrium time 90 min is 318.04 mg g -1 , and those of methanol-treated and HAc-treated biomass are 311.95 and 351.67 mg g -1 at the same pH and S/L values but different equilibrium time of 60 and 90 min, respectively. Thus the maximum biosorption capacity of the three kind of modified biomass have greatly surpassed that of the raw biomass (21.42 mg g -1 ). The study of kinetic exhibits a high level of compliance with the Lagergren's pseudo-second-order kinetic models. Langumir and Freundlich models have proved to be well able to explain the sorption equilibrium with the satisfactory correlation coefficients higher than 0.96. FTIR analysis reveals that the carboxyl, amino and hydroxyl groups on the cell wall of Fusarium sp. ZZF51 play an important role in uranium(VI) biosorption process. (author)

  18. Preparation and Faraday rotation of Bi-YIG/PMMA nanocomposite

    Science.gov (United States)

    Fu, H. P.; Hong, R. Y.; Wu, Y. J.; Di, G. Q.; Xu, B.; Zheng, Y.; Wei, D. G.

    Bismuth-substituted yttrium iron garnet (Bi-YIG) nanoparticles (NPs) were prepared by coprecipitation and subsequent heating treatment. Thermal gravity-differential thermal analysis was performed to investigate the thermal behavior of the Bi-YIG precursors and to decide the best annealing temperature. Phase formation of garnet NPs was investigated by X-ray powder diffraction. The size of Bi-YIG NPs was investigated by transmission electron microscopy, and the magnetic properties of Bi-YIG NPs were measured using a vibrating sample magnetometer. The results show that the temperature needed for the transformation of Bi-YIG from the amorphous phase to the garnet phase decreases with increasing Bi content, and Bi-YIG NPs with sizes of 28-78 nm are obtained after heating treatment at 650-1000 °C. The saturation magnetization of Bi-YIG NPs increases as the Bi content increases. Moreover, the Faraday rotation of polymethyl methacrylate (PMMA) slices doped with Bi-YIG NPs was investigated. The results indicate that the angle of Faraday rotation increases with increasing Bi content in PMMA composites, and the maximum value of the figure of merit is 1.46°, which is comparable to the value of a sputtered film. The Bi-YIG NPs-doped PMMA slices are new promising materials for magneto-optical devices.

  19. Faraday Rotation Measure Study of Cluster Magnetic Fields

    Science.gov (United States)

    Frankel, M. M.; Clarke, T. E.

    2001-12-01

    Magnetic fields are thought to play an important role in galaxy cluster evolution. To this end in this study, we looked at polarized radio sources viewed at small impact parameters to the cores of non-cooling flow clusters. By looking at non-cooling flow clusters we hoped to establish what magnetic fields of clusters look like in the absence of the compressed central magnetic fields of the cooling-flow cores. Clarke, Kronberg and Boehringer (2001) examined Faraday rotation measures of radio probes at relatively large impact parameters to the cores of galaxy clusters. The current study is an extension of the Clarke et al. analysis to probe the magnetic fields in the cores of galaxy clusters. We looked at the Faraday rotation of electromagnetic waves from background or imbedded radio galaxies, which were observed with the VLA in A&B arrays. Our results are consistent with previous findings and exhibit a trend towards higher rotation measures and in turn higher magnetic fields at small impact parameters to cluster cores. This research was made possible through funding from the National Science Foundation.

  20. Microreactors for Gold Nanoparticles Synthesis: From Faraday to Flow

    Directory of Open Access Journals (Sweden)

    Md. Taifur Rahman

    2014-06-01

    Full Text Available The seminal work of Michael Faraday in 1850s transmuted the “Alchemy of gold” into a fascinating scientific endeavor over the millennia, particularly in the past half century. Gold nanoparticles (GNPs arguably hold the central position of nanosciences due to their intriguing size-and-shape dependent physicochemical properties, non-toxicity, and ease of functionalization and potential for wide range of applications. The core chemistry involved in the syntheses is essentially not very different from what Michael Faraday resorted to: transforming ions into metallic gold using mild reducing agents. However, the process of such reduction and outcome (shapes and sizes are intricately dependent on basic operational parameters such as sequence of addition and efficiency of mixing of the reagents. Hence, irreproducibility in synthesis and maintaining batch-to-batch quality are major obstacles in this seemingly straightforward process, which poses challenges in scaling-up. Microreactors, by the virtue of excellent control over reagent mixing in space and time within narrow channel networks, opened a new horizon of possibilities to tackle such problems to produce GNPs in more reliable, reproducible and scalable ways. In this review, we will delineate the state-of-the-art of GNPs synthesis using microreactors and will discuss in length how such “flask-to-chip” paradigm shift may revolutionize the very concept of nanosyntheses.

  1. Michael Faraday and the concept of atomic structure

    International Nuclear Information System (INIS)

    Pocock, R.F.

    1991-01-01

    Written to commemorate the bicentenary of Faraday's birth, this article surveys his influence on atomic theory during the 19th and early 20th centuries. It identifies which developments were derived from projects which he had started; it shows that his ideas and methods determined the direction of researches which he had not himself initiated. The account is in the form of a chronological narrative. This is based entirely on published sources, and the treatment is non-mathematical. In consequence it contains no new factual data. The presentation of Faraday's work in this particular context is, however, original. Although not covering studies of the nucleus - which were mostly later than the period considered -this article describes the origins of modern theories of atomic structure reasonably completely. It is a useful overview for engineers unfamiliar with details of the history of physics. In addition, it is a case-study of the persistence of scientific ideas in researches occupying a century or more. (author)

  2. Surface-enhanced Raman difference between bombesin and its modified analogues on the colloidal and electrochemically roughen silver surfaces.

    Science.gov (United States)

    Podstawka, Edyta; Ozaki, Yukihiro

    2008-10-01

    In this article, surface-enhanced Raman scattering (SERS) spectra of bombesin (BN) and its six modified analogues ([D-Phe(12)]BN, [Tyr(4)]BN, [Tyr(4),D-Phe(12)]BN, [D-Phe(12),Leu(14)]BN, [Leu(13)-(R)-Leu(14)]BN, and [Lys(3)]BN) on a colloidal silver surface are reported and compared with SERS spectra of these species immobilized onto an ellectrochemically roughen silver electrode. Changes in enhancement and wavenumber of proper bands upon adsorption on different silver surfaces are consistent with BN and its analogues adsorption primarily through Trp(8). Slightly different adsorption states of these molecules are observed depending upon natural amino acids substitution. For example, the indole ring in all the peptides interacts with silver nanoparticles in a edge-on orientation. It is additionally coordinated to the silver through the N(1)--H bond for all the peptides, except [Phe(12)]BN. This is in contrary to the results obtained for the silver roughen electrode that show direct but not strong N(1)--H/Ag interaction for all peptides except [D-Phe(12),Leu(14)]BN and [Leu(13)-(R)-Leu(14)]BN. For BN only C==O is not involved in the chemical coordination with the colloidal surface. [Lys(3)]BN and BN also adsorb with the C--N bond of NH(2) group normal and horizontal, respectively, to the colloidal surface, whereas C--NH(2) in other peptides is tilted to this surface. Also, the Trp(8) --CH(2)-- moiety of only [Tyr(4)]BN, [Lys(3)]BN, and [Tyr(4),D-Phe(12)]BN coordinates to Ag, whereas the Phe(12) ring of [Phe(12)]BN, [Tyr(4),D-Phe(12)]BN, and [D-Phe(12),Leu(14)]BN assists in the peptides binding only on the colloidal silver. (c) 2008 Wiley Periodicals, Inc.

  3. One pot synthesis of Ag nanoparticle modified ZnO microspheres in ethylene glycol medium and their enhanced photocatalytic performance

    International Nuclear Information System (INIS)

    Tian Chungui; Li Wei; Pan Kai; Zhang Qi; Tian Guohui; Zhou Wei; Fu Honggang

    2010-01-01

    Ag nanoparticles (NPs) modified ZnO microspheres (Ag/ZnO microspheres) were prepared by a facile one pot strategy in ethylene glycol (EG) medium. The EG played two important roles in the synthesis: it could act as a reaction media for the formation of ZnO and reduce Ag + to Ag 0 . A series of the characterizations indicated the successful combination of Ag NPs with ZnO microspheres. It was shown that Ag modification could greatly enhance the photocatalytic efficiency of ZnO microspheres by taking the photodegradation of Rhodamine B as a model reaction. With appropriate ratio of Ag and ZnO, Ag/ZnO microspheres showed the better photocatalytic performance than commercial Degussa P-25 TiO 2 . Photoluminescence and surface photovoltage spectra demonstrated that Ag modification could effectively inhibit the recombination of the photoinduced electron and holes of ZnO. This is responsible for the higher photocatalytic activity of Ag/ZnO composites. -- Graphical abstract: A 'one-pot' strategy was developed for preparing the Ag/ZnO microspheres in ethylene glycol. The composites exhibited superior photocatalytic performance for photodegradation of Rhodamine B dye in water. Display Omitted

  4. Performance-Enhanced Activated Carbon Electrodes for Supercapacitors Combining Both Graphene-Modified Current Collectors and Graphene Conductive Additive.

    Science.gov (United States)

    Wang, Rubing; Qian, Yuting; Li, Weiwei; Zhu, Shoupu; Liu, Fengkui; Guo, Yufen; Chen, Mingliang; Li, Qi; Liu, Liwei

    2018-05-15

    Graphene has been widely used in the active material, conductive agent, binder or current collector for supercapacitors, due to its large specific surface area, high conductivity, and electron mobility. However, works simultaneously employing graphene as conductive agent and current collector were rarely reported. Here, we report improved activated carbon (AC) electrodes (AC@G@NiF/G) simultaneously combining chemical vapor deposition (CVD) graphene-modified nickel foams (NiF/Gs) current collectors and high quality few-layer graphene conductive additive instead of carbon black (CB). The synergistic effect of NiF/Gs and graphene additive makes the performances of AC@G@NiF/G electrodes superior to those of electrodes with CB or with nickel foam current collectors. The performances of AC@G@NiF/G electrodes show that for the few-layer graphene addition exists an optimum value around 5 wt %, rather than a larger addition of graphene, works out better. A symmetric supercapacitor assembled by AC@G@NiF/G electrodes exhibits excellent cycling stability. We attribute improved performances to graphene-enhanced conductivity of electrode materials and NiF/Gs with 3D graphene conductive network and lower oxidation, largely improving the electrical contact between active materials and current collectors.

  5. Performance-Enhanced Activated Carbon Electrodes for Supercapacitors Combining Both Graphene-Modified Current Collectors and Graphene Conductive Additive

    Science.gov (United States)

    Wang, Rubing; Qian, Yuting; Li, Weiwei; Zhu, Shoupu; Liu, Fengkui; Guo, Yufen; Chen, Mingliang; Li, Qi; Liu, Liwei

    2018-01-01

    Graphene has been widely used in the active material, conductive agent, binder or current collector for supercapacitors, due to its large specific surface area, high conductivity, and electron mobility. However, works simultaneously employing graphene as conductive agent and current collector were rarely reported. Here, we report improved activated carbon (AC) electrodes (AC@G@NiF/G) simultaneously combining chemical vapor deposition (CVD) graphene-modified nickel foams (NiF/Gs) current collectors and high quality few-layer graphene conductive additive instead of carbon black (CB). The synergistic effect of NiF/Gs and graphene additive makes the performances of AC@G@NiF/G electrodes superior to those of electrodes with CB or with nickel foam current collectors. The performances of AC@G@NiF/G electrodes show that for the few-layer graphene addition exists an optimum value around 5 wt %, rather than a larger addition of graphene, works out better. A symmetric supercapacitor assembled by AC@G@NiF/G electrodes exhibits excellent cycling stability. We attribute improved performances to graphene-enhanced conductivity of electrode materials and NiF/Gs with 3D graphene conductive network and lower oxidation, largely improving the electrical contact between active materials and current collectors. PMID:29762528

  6. A rapid method for detection of genetically modified organisms based on magnetic separation and surface-enhanced Raman scattering.

    Science.gov (United States)

    Guven, Burcu; Boyacı, İsmail Hakkı; Tamer, Ugur; Çalık, Pınar

    2012-01-07

    In this study, a new method combining magnetic separation (MS) and surface-enhanced Raman scattering (SERS) was developed to detect genetically modified organisms (GMOs). An oligonucleotide probe which is specific for 35 S DNA target was immobilized onto gold coated magnetic nanospheres to form oligonucleotide-coated nanoparticles. A self assembled monolayer was formed on gold nanorods using 5,5'-dithiobis (2-nitrobenzoic acid) (DTNB) and the second probe of the 35 S DNA target was immobilized on the activated nanorod surfaces. Probes on the nanoparticles were hybridized with the target oligonucleotide. Optimization parameters for hybridization were investigated by high performance liquid chromatography. Optimum hybridization parameters were determined as: 4 μM probe concentration, 20 min immobilization time, 30 min hybridization time, 55 °C hybridization temperature, 750 mM buffer salt concentration and pH: 7.4. Quantification of the target concentration was performed via SERS spectra of DTNB on the nanorods. The correlation between the target concentration and the SERS signal was found to be linear within the range of 25-100 nM. The analyses were performed with only one hybridization step in 40 min. Real sample analysis was conducted using Bt-176 maize sample. The results showed that the developed MS-SERS assay is capable of detecting GMOs in a rapid and selective manner. This journal is © The Royal Society of Chemistry 2012

  7. Facile preparation of C, N co-modified Nb2O5 nanoneedles with enhanced visible light photocatalytic activity

    KAUST Repository

    Xue, Jiao

    2016-09-28

    C, N co-modified niobium pentoxide (Nb2O5) nanoneedles have been successfully synthesized via a facile hydrothermal method with Niobium Chloride (NbCl5) as a precursor and triethylamine as both the carbon and nitrogen source. The formation process of Nb2O5 nanoneedles has been presented in detail by investigating the effect of the crystallization temperature, the amount of triethylamine and the calcination temperature. The as-prepared Nb2O5 nanoneedles exhibit more efficient photocatalytic activity than commercial Degussa P25 and commercial Nb2O5 towards photodegradation of Rhodamine B (RhB) at a concentration of 10 mg L−1 under visible light. Special chemical species, such as carbonate species and NOX species, that exist on the surface of the as-prepared catalyst could extend the absorption into the visible region and thus enhance the photocatalytic activity of the Nb2O5 nanoneedles. At the same time, the obtained Nb2O5 nanoneedles exhibit excellent stability even after three successive cycles. A possible photodegradation mechanism was proposed and the corresponding photodecomposition process of RhB over the Nb2O5 nanoneedles was elucidated by a reactive species trapping experiment, suggesting that h+ and O2˙− play a major role in the photodegradation of RhB in aqueous solution.

  8. Quantitative estimation of renal function with dynamic contrast-enhanced MRI using a modified two-compartment model.

    Directory of Open Access Journals (Sweden)

    Bin Chen

    Full Text Available To establish a simple two-compartment model for glomerular filtration rate (GFR and renal plasma flow (RPF estimations by dynamic contrast-enhanced magnetic resonance imaging (DCE-MRI.A total of eight New Zealand white rabbits were included in DCE-MRI. The two-compartment model was modified with the impulse residue function in this study. First, the reliability of GFR measurement of the proposed model was compared with other published models in Monte Carlo simulation at different noise levels. Then, functional parameters were estimated in six healthy rabbits to test the feasibility of the new model. Moreover, in order to investigate its validity of GFR estimation, two rabbits underwent acute ischemia surgical procedure in unilateral kidney before DCE-MRI, and pixel-wise measurements were implemented to detect the cortical GFR alterations between normal and abnormal kidneys.The lowest variability of GFR and RPF measurements were found in the proposed model in the comparison. Mean GFR was 3.03±1.1 ml/min and mean RPF was 2.64±0.5 ml/g/min in normal animals, which were in good agreement with the published values. Moreover, large GFR decline was found in dysfunction kidneys comparing to the contralateral control group.Results in our study demonstrate that measurement of renal kinetic parameters based on the proposed model is feasible and it has the ability to discriminate GFR changes in healthy and diseased kidneys.

  9. Fabrication of Faraday Cup Array for the Measurement of 2-Dimensional Proton Beam Profile

    International Nuclear Information System (INIS)

    Jung, Myunghwan; Kim, Bom Sok; Kim, Kyeryung

    2014-01-01

    It has an advantage of easy-to-use and possible to visually check, immediately; on the other hand, the measurement range is very limited. Another method is using the CCD camera-scintillator device such as p43 phosphor screen or chromox. A variety of faraday cup detectors have been recently introduced. The faraday cup is one of the powerful and popular tools for the measurement of beam current. By using several faraday cups in array geometry, it is possible to observe current distribution. In this study, we developed an external faraday cup array for the measure the beam current and profile at a KOMAC (Korea Multi-purpose Accelerator Complex) beam utilization facility. To measure the beam profile, before fabrication of faraday cup array, we use gafchromic film. By making the faraday cup array we were able to reduce the consumption of Gafchromic film and a more accurate diagnosis of the proton beam is possible. The use of faraday cup array, experiment using the proton beam is more reliable and confident

  10. Ramsey-CPT spectrum with the Faraday effect and its application to atomic clocks

    International Nuclear Information System (INIS)

    Tian Yuan; Gu Si-Hong; Tan Bo-Zhong; Yang Jing; Zhang Yi

    2015-01-01

    A method that obtains the Ramsey-coherent population trapping (CPT) spectrum with the Faraday effect is investigated. An experiment is implemented to detect the light polarization components generated from the Faraday effect. The experimental results agree with the theoretical calculations based on the Liouville equation. By comparing with the method without using the Faraday effect, the potential of this method for a CPT-based atomic clock is assessed. The results indicate that this method should improve the short-term frequency stability by several times. (paper)

  11. Faraday effect in Hg1-xMnxTe semimagnetic semiconductors

    International Nuclear Information System (INIS)

    Savchuk, A.I.; Frasunyak, V.M.; Fediv, V.I.

    1995-01-01

    Results on studies of spectral and temperature dependencies of the Faraday rotation in the Hg 1-x Mn x Te semiconductors are presented. It is shown that the Faraday rotation spectral dependence in the Hg 1-x Mn x Te crystals corresponds to model of the Faraday giant effect in other A 1-x 2 Mn x B 6 semimagnetic semiconductors, caused by strong exchange interaction between Mn d-electrons and s,p - zone carriers. The phase transition into the glass spin state is observed in the Hg 1-x Mn x Te crystals with Mn high content. 5 refs.; 2 figs

  12. Inverse energy cascade and emergence of large coherent vortices in turbulence driven by Faraday waves.

    Science.gov (United States)

    Francois, N; Xia, H; Punzmann, H; Shats, M

    2013-05-10

    We report the generation of large coherent vortices via inverse energy cascade in Faraday wave driven turbulence. The motion of floaters in the Faraday waves is three dimensional, but its horizontal velocity fluctuations show unexpected similarity with two-dimensional turbulence. The inverse cascade is detected by measuring frequency spectra of the Lagrangian velocity, and it is confirmed by computing the third moment of the horizontal velocity fluctuations. This is observed in deep water in a broad range of wavelengths and vertical accelerations. The results broaden the scope of recent findings on Faraday waves in thin layers [A. von Kameke et al., Phys. Rev. Lett. 107, 074502 (2011)].

  13. A two-in-one Faraday rotator mirror exempt of active optical alignment.

    Science.gov (United States)

    Wan, Qiong; Wan, Zhujun; Liu, Hai; Liu, Deming

    2014-02-10

    A two-in-one Faraday rotator mirror was presented, which functions as two independent Faraday rotation mirrors with a single device. With the introduction of a reflection lens as substitution of the mirror in traditional structure, this device is characterized by exemption of active optical alignment for the designers and manufacturers of Faraday rotator mirrors. A sample was fabricated by passive mechanical assembly. The insertion loss was measured as 0.46 dB/0.50 dB for the two independent ports, respectively.

  14. Nondestructive measurement of the mobility in semiconductors by means of the microwave Faraday effect

    International Nuclear Information System (INIS)

    Musil, F.; Zacek, F.; Buerger, A.; Karlovsky, J.

    1976-01-01

    The measurement is described of electron mobility in semiconducting plates placed between two cylindrical antennas with diameter d approximately equal to 0.75lambda 0 by means of the microwave Faraday effect. This system makes it possible (i) to measure the Faraday rotation in semiconductina plates of arbitrary transverse dimensions, greater or at least equal to the diameter of dielectric antennas, (ii) to evaluate the unknown value of the charge carrier mobility from the measured rotation in an unbounded solid state plasma slab approximation. The measurement of Faraday rotation in n-type Ge plates is reported. The comparison of the experimental data with the theory shows good agreement. (author)

  15. Faraday cup for electron flux measurements on the microtron MT 25

    International Nuclear Information System (INIS)

    Vognar, M.; Simane, C.; Chvatil, D.

    2001-01-01

    The basic design criteria for construction of an evacuated Faraday cup for precise measurement of 5-25 MeV electron beam currents in air from a microtron are characterized. The homemade Faraday cup is described along with the electronic chain and its incorporation into the measuring beam line. The provisions applied to reduce backward electron escape are outlined. The current range was 10 -5 to 10 -10 A. The diameter of the Al entrance window of the Faraday cup was 1.8 cm, its area was 2.54 cm 2 and thickness 0.1 mm

  16. Differential detection for measurements of Faraday rotation by means of ac magnetic fields

    International Nuclear Information System (INIS)

    Valev, V K; Wouters, J; Verbiest, T

    2008-01-01

    We demonstrate that by using a combination of a Wollaston prism and two photodiodes the accuracy in the measurements of Faraday rotation with ac magnetic fields can be greatly improved. Our experiments were performed on microscope cover glass plates with thicknesses between 0.13 and 0.16 mm. We show that our setup is capable of distinguishing between the Faraday rotation signals of glass plates having a difference in thickness of a few micrometers, corresponding to Faraday rotations of hundreds of microdegrees per Tesla only

  17. New technologies to enhance quality and safety of table eggs: ultra-violet treatment and modified atmosphere packaging

    Directory of Open Access Journals (Sweden)

    Frédérique Pasquali

    2014-12-01

    Full Text Available In the present study the effect of ultra-violet (UV treatment alone and in combination with 100% CO2 modified atmosphere packaging (MAP was evaluated both on the survival of naturally occurring bacteria, as well as on quality parameters of table eggs during 28 days of storage at 21°C. Table eggs were collected from the conveyor belt after the UV module, and placed on carton trays. A representative number of carton trays were packed in a high barrier multilayer pouch filled with 100% CO2. All eggs were stored at 21°C and analysed at 0, 1, 7, 14, 21 and 28 days of storage. Eggs not treated with UV and not packed were also included. On the eggshells total colony count, total coliforms and faecal coliforms counts, as well as the detection of Salmonella spp. were investigated. Moreover, chemical-functional parameters such as weight loss, albumen pH and Haugh Unit (HU were evaluated. The total colony count on UV treated table eggs was approximately 1 log10 CFU/g lower than untreated eggs (2.27 vs 3.29 log10 CFU/g. During storage, CO2 packed eggs maintained the initial values of HU, whereas the albumen pH decreased up to 1.5-2 points in comparison to unpacked eggs. The UV treatment was effective in reducing the total colony count on the surface of table eggs. MAP showed a great potential in maintaining/enhance the technological properties of egg constituents (higher foam stability of the albumen for meringue preparation without significantly impacting on the microbial load of table eggs.

  18. Study on the enhanced adsorption properties of lysozyme on polyacrylic acid modified TiO2 nano-adsorbents

    Science.gov (United States)

    Liu, Yufeng; Jin, Zu; Meng, Hao; Zhang, Xia

    2018-01-01

    The adsorption and immobilization of enzymes onto solid carriers has been focused on due to their many advantages, such as improved stability against a thermal or organic solvent and a good cycle usability. TiO2 nanoparticles is one of excellent nano-adsorbents owing to its excellent biocompatibility, non-inflammatory, and abundant surface hydroxyl groups, which are convenient to be combined with various functional groups. In this paper polyacrylic acid (PAA) modified TiO2 nanoparticles were synthesized through an in situ light-induced polymerization of acrylic acid on the surface of TiO2 nanoparticles. The structure and surface physicochemical properties of the PAA/TiO2 nanoparticles were characterized by TEM, XRD, FT-IR, Zeta potential measurements and TG-DSC. The experimental results showed that the isoelectric point of PAA/TiO2 significantly reduced to 1.82 compared with that of pure TiO2 nanoparticles (6.08). In the adsorption tests of lysozyme (Lyz), the PAA/TiO2 nanoparticles displayed enhanced adsorption activity compared with pristine TiO2. The maximum adsorption capacity of PAA/TiO2 for Lyz was 225.9 mg g-1 under the optimum conditions where the initial concentration of Lyz was 300 mg ml-1, the addition amount of PAA/TiO2 was 6.4 mg, the adsorption time was 30 min and the pH value was 7.0. The sodium dodecyl sulfate (SDS, 0.5%) presented the best efficiency (76.86%) in the removal of adsorbed Lyz, and the PAA/TiO2 nanoparticles showed excellent adsorption stability based on five cyclic adsorption-desorption tests. The fitting calculation results of the adsorption isotherm and the thermodynamics indicated the adsorption was an exothermic, entropy increasing, spontaneous and monomolecular layer adsorption process.

  19. Faraday cup dosimetry in a proton therapy beam without collimation

    International Nuclear Information System (INIS)

    Grusell, Erik; Isacsson, Ulf; Montelius, Anders; Medin, Joakim

    1995-01-01

    A Faraday cup in a proton beam can give an accurate measurement of the number of protons collected by the cup. It is shown that the collection efficiency with a proper design can be close to unity. To be able to calibrate an ionization chamber from such a measurement, as is recommended in some dosimetry protocols, the energy spectrum of the proton beam must be accurately known. This is normally not the case when the lateral beam extension is defined by collimators. Therefore a method for relating an ionization chamber measurement in an uncollimated beam to the total number of protons in the beam has been developed and is described together with experimental results from calibrating an ionization chamber using this method in the therapeutic beam in Uppsala. This method is applicable to ionization chambers of any shape and the accuracy is estimated to be 1.6% (1 SD). (Author)

  20. Electrostatic capacitance and Faraday cage behavior of carbon nanotube forests

    Energy Technology Data Exchange (ETDEWEB)

    Ya' akobovitz, A. [Mechanosynthesis Group, Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States); Department of Mechanical Engineering, Faculty of Engineering Sciences, Ben-Gurion University, Beer-Sheva (Israel); Bedewy, M. [Mechanosynthesis Group, Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States); Hart, A. J. [Mechanosynthesis Group, Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States); Department of Mechanical Engineering and Laboratory for Manufacturing and Productivity, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

    2015-02-02

    Understanding of the electrostatic properties of carbon nanotube (CNT) forests is essential to enable their integration in microelectronic and micromechanical devices. In this study, we sought to understand how the hierarchical geometry and morphology of CNT forests determines their capacitance. First, we find that at small gaps, solid micropillars have greater capacitance, yet at larger gaps the capacitance of the CNT forests is greater. The surface area of the CNT forest accessible to the electrostatic field was extracted by analysis of the measured capacitance, and, by relating the capacitance to the average density of CNTs in the forest, we find that the penetration depth of the electrostatic field is on the order of several microns. Therefore, CNT forests can behave as a miniature Faraday cage. The unique electrostatic properties of CNT forests could therefore enable their use as long-range proximity sensors and as shielding elements for miniature electronic devices.

  1. Virtual resistive network and conductivity reconstruction with Faraday's law

    International Nuclear Information System (INIS)

    Lee, Min Gi; Ko, Min-Su; Kim, Yong-Jung

    2014-01-01

    A network-based conductivity reconstruction method is introduced using the third Maxwell equation, or Faraday's law, for a static case. The usual choice in electrical impedance tomography is the divergence-free equation for the electrical current density. However, if the electrical current density is given, the curl-free equation for the electrical field gives a direct relation between the current and the conductivity and this relation is used in this paper. Mimetic discretization is applied to the equation, which gives the virtual resistive network system. Properties of the numerical schemes introduced are investigated and their advantages over other conductivity reconstruction methods are discussed. Numerically simulated results, with an analysis of noise propagation, are presented. (paper)

  2. Current measurements by Faraday rotation in single mode optical fibers

    International Nuclear Information System (INIS)

    Chandler, G.I.; Jahoda, F.C.

    1984-01-01

    Development of techniques for measuring magnetic fields and currents by Faraday rotation in single-mode optical fibers has continued. We summarize the results of attempts to measure the toroidal plasma current in the ZT-40 Reversed-Field-Pinch using multi-turn fiber coils. The fiber response is reproducible and in accord with theory, but the amount and distribution of the stress-induced birefringence in this case are such that prediction of the sensor response at low currents is difficult if not impossible. The low-current difficulty can be overcome by twisting the fiber to induce a circular birefringence bias. We report the results of auxiliary experiments with a fiber that has been twisted with 15 turns per meter and then re-coated to lock the twist in place

  3. Electrostatic capacitance and Faraday cage behavior of carbon nanotube forests

    International Nuclear Information System (INIS)

    Ya'akobovitz, A.; Bedewy, M.; Hart, A. J.

    2015-01-01

    Understanding of the electrostatic properties of carbon nanotube (CNT) forests is essential to enable their integration in microelectronic and micromechanical devices. In this study, we sought to understand how the hierarchical geometry and morphology of CNT forests determines their capacitance. First, we find that at small gaps, solid micropillars have greater capacitance, yet at larger gaps the capacitance of the CNT forests is greater. The surface area of the CNT forest accessible to the electrostatic field was extracted by analysis of the measured capacitance, and, by relating the capacitance to the average density of CNTs in the forest, we find that the penetration depth of the electrostatic field is on the order of several microns. Therefore, CNT forests can behave as a miniature Faraday cage. The unique electrostatic properties of CNT forests could therefore enable their use as long-range proximity sensors and as shielding elements for miniature electronic devices

  4. Electrostatic capacitance and Faraday cage behavior of carbon nanotube forests

    Science.gov (United States)

    Ya'akobovitz, A.; Bedewy, M.; Hart, A. J.

    2015-02-01

    Understanding of the electrostatic properties of carbon nanotube (CNT) forests is essential to enable their integration in microelectronic and micromechanical devices. In this study, we sought to understand how the hierarchical geometry and morphology of CNT forests determines their capacitance. First, we find that at small gaps, solid micropillars have greater capacitance, yet at larger gaps the capacitance of the CNT forests is greater. The surface area of the CNT forest accessible to the electrostatic field was extracted by analysis of the measured capacitance, and, by relating the capacitance to the average density of CNTs in the forest, we find that the penetration depth of the electrostatic field is on the order of several microns. Therefore, CNT forests can behave as a miniature Faraday cage. The unique electrostatic properties of CNT forests could therefore enable their use as long-range proximity sensors and as shielding elements for miniature electronic devices.

  5. Compensating Faraday Depolarization by Magnetic Helicity in the Solar Corona

    Energy Technology Data Exchange (ETDEWEB)

    Brandenburg, Axel; Ashurova, Mohira B. [Laboratory for Atmospheric and Space Physics, University of Colorado, Boulder, CO 80303 (United States); Jabbari, Sarah, E-mail: brandenb@nordita.org [School of Mathematical Sciences and Monash Centre for Astrophysics, Monash University, Clayton, VIC 3800 (Australia)

    2017-08-20

    A turbulent dynamo in spherical geometry with an outer corona is simulated to study the sign of magnetic helicity in the outer parts. In agreement with earlier studies, the sign in the outer corona is found to be opposite to that inside the dynamo. Line-of-sight observations of polarized emission are synthesized to explore the feasibility of using the local reduction of Faraday depolarization to infer the sign of helicity of magnetic fields in the solar corona. This approach was previously identified as an observational diagnostic in the context of galactic magnetic fields. Based on our simulations, we show that this method can be successful in the solar context if sufficient statistics are gathered by using averages over ring segments in the corona separately for the regions north and south of the solar equator.

  6. Faraday rotation calculations for a FIR polarimeter on ITER

    International Nuclear Information System (INIS)

    Nieswand, C.

    1997-01-01

    The measurement of the safety factor profile has been considered as an essential diagnostics for ITER. Without the presence of a neutral beam, the only reliable diagnostics which can fulfill the requirements for the q-profile determination is at present the polarimetry. This paper presents the results of calculations of the Faraday rotation and the Cotton-Mouton effect for various plasma configurations (considered as typical) and various beam geometries which can eventually be realized in spite of the restricted access. The calculations should help to find a decision for the wavelength and the number and the position of the observation chords of a possible polarimeter system on ITER. The paper does not deal with technical questions concerning the implementation of such a system on ITER. The potential use of internal retro-reflectors or waveguides for the beams is not discussed. (author) 4 figs., 3 refs

  7. Analytic expressions for polarimetry in plasma with large Cotton endash Mouton or Faraday effects

    International Nuclear Information System (INIS)

    Segre, S.E.

    1996-01-01

    Analytic expressions for plasma polarimetry are derived for the case when either the Cotton endash Mouton effect or the Faraday effect is large while the other effect is small. copyright 1996 American Institute of Physics

  8. New conceptual antenna with spiral structure and back Faraday shield for FWCD (fast wave current drive)

    International Nuclear Information System (INIS)

    Saigusa, M.; Moriyama, S.; Fujii, T.; Kimura, H.

    1994-01-01

    A new conceptual antenna, which we call as a spiral antenna, is proposed as a traveling wave antenna for fast wave current drive in tokamaks. The features of the spiral antenna are a sharp N z spectrum, easy impedance matching, N z controllable and good coupling. A back Faraday shield is proposed for improving the cooling design of Faraday shield and better antenna-plasma coupling. A helical support which is a compact and wide band support is proposed as a kind of quarter wave length stub supports. The RF properties of the spiral antenna and the back Faraday shield have been investigated by using mock-up antennas. The VSWR of spiral antenna is low at the wide frequency band from 15 MHz to 201 MHz. The back Faraday shield is effective for suppressing the RF toroidal electric field between adjacent currents straps. (author)

  9. Temperature Dependence of Faraday Effect-Induced Bias Error in a Fiber Optic Gyroscope.

    Science.gov (United States)

    Li, Xuyou; Liu, Pan; Guang, Xingxing; Xu, Zhenlong; Guan, Lianwu; Li, Guangchun

    2017-09-07

    Improving the performance of interferometric fiber optic gyroscope (IFOG) in harsh environments, such as magnetic field and temperature field variation, is necessary for its practical applications. This paper presents an investigation of Faraday effect-induced bias error of IFOG under varying temperature. Jones matrix method is utilized to formulize the temperature dependence of Faraday effect-induced bias error. Theoretical results show that the Faraday effect-induced bias error changes with the temperature in the non-skeleton polarization maintaining (PM) fiber coil. This phenomenon is caused by the temperature dependence of linear birefringence and Verdet constant of PM fiber. Particularly, Faraday effect-induced bias errors of two polarizations always have opposite signs that can be compensated optically regardless of the changes of the temperature. Two experiments with a 1000 m non-skeleton PM fiber coil are performed, and the experimental results support these theoretical predictions. This study is promising for improving the bias stability of IFOG.

  10. The Faraday effect of an antiferromagnetic photonic crystal with a defect layer

    International Nuclear Information System (INIS)

    Wang Xuanzhang

    2005-01-01

    A theoretical calculation of the Faraday optical rotation effect of an antiferromagnetic (AF) photonic crystal is presented. This crystal is composed of AF and dielectric (D) layers and contains an AF defect layer. From the theoretical results for the FeF 2 -SiO 2 crystal, we see a defect mode with high transmission and a high Faraday rotation angle in the optical stop band for ω/2πc -1 . The Faraday rotation of the mode is about 28 deg. mm -1 and 15 times that of the single AF film. Another more striking property is that the rotation in the vicinity of the zero-field AF resonance frequency is even larger than that of the defect mode: about 250 times. The Faraday rotation can be tuned by changing the strength of the external static magnetic field

  11. HIE-ISOLDE Faraday cups tested with ion beams at TRIUMF

    CERN Document Server

    Cantero, E D

    2014-01-01

    The future HIE-ISOLDE Faraday cups for both the intercryomodule regions and the HEBTs have been tested using 34S+7, 4He+, 23Na+6 and 20Ne+5 beams from the ISAC-II accelerator at TRIUMF. Their performance has been characterized together with the Faraday cups from REX-ISOLDE and those from ISAC-II. The measurements were done at E/A = 1.5, 2.85 and 5.5 MeV/u, with beam intensities in the range of 100 pA to 4 nA. The performance of these Faraday cups has been compared under the same beam conditions for different bias voltages up to -350 V. Within the experimental uncertainties, most of them coming from fluctuations in beam intensity, all devices showed similar results. Biasing the Faraday cup repeller ring to voltages of at least -60 V, the escape of secondary electrons was suppressed.

  12. Transparent Flexible Active Faraday Cage Enables In Vivo Capacitance Measurement in Assembled Microsensor.

    Science.gov (United States)

    Ahmadi, Mahdi; Rajamani, Rajesh; Sezen, Serdar

    2017-10-01

    Capacitive micro-sensors such as accelerometers, gyroscopes and pressure sensors are increasingly used in the modern electronic world. However, the in vivo use of capacitive sensing for measurement of pressure or other variables inside a human body suffers from significant errors due to stray capacitance. This paper proposes a solution consisting of a transparent thin flexible Faraday cage that surrounds the sensor. By supplying the active sensing voltage simultaneously to the deformable electrode of the capacitive sensor and to the Faraday cage, the stray capacitance during in vivo measurements can be largely eliminated. Due to the transparency of the Faraday cage, the top and bottom portions of a capacitive sensor can be accurately aligned and assembled together. Experimental results presented in the paper show that stray capacitance is reduced by a factor of 10 by the Faraday cage, when the sensor is subjected to a full immersion in water.

  13. Novel Faraday cup for the simultaneous observation and measurement of ion-beam currents

    International Nuclear Information System (INIS)

    Wei, C.; Seidman, D.N.

    1977-01-01

    A novel Faraday cup is described which allows the simultaneous observation and measurement of ion-beam currents. The Faraday cup is constructed around a Galileo channel electron multiplier array (CEMA), which serves as the basis of an internal image intensification system (a gain of >10 4 ) for the observation of the ion beam; the CEMA also acts as a collector for the ion current which is measured by a Keithley 602 electrometer. The ion current is integrated by a simple and inexpensive dosimeter; the electronic circuit for the dosimeter is described. The application of the Faraday cup to the observation and measurement of a 30-keV Ar + ion beam is presented as an illustrative example. We have also employed this Faraday cup to observe and measure 30-keV Cr + , Mo + , or W + , and 18-keV Au + ion beams employed for the in situ irradiation of field-ion microscope specimens

  14. Enhanced photocatalytic, electrochemical and photoelectrochemical properties of TiO2 nanotubes arrays modified with Cu, AgCu and Bi nanoparticles obtained via radiolytic reduction

    International Nuclear Information System (INIS)

    Nischk, Michał; Mazierski, Paweł; Wei, Zhishun; Siuzdak, Katarzyna; Kouame, Natalie Amoin; Kowalska, Ewa; Remita, Hynd; Zaleska-Medynska, Adriana

    2016-01-01

    Highlights: • TiO 2 nanotubes were modified with Cu, AgCu, Bi nanoparticles via gamma radiolysis. • Excessive amount of deposited metal decreased photocatalytic activity. • AgCu-modified samples were more active than Cu-modified (with the same Cu content). • AgCu nanoparticles exist in a core (Ag) -shell (Cu) form. • Examined photocatalysts were resistant towards photocorrosion processes. - Abstract: TiO 2 nanotubes arrays (NTs), obtained via electrochemical anodization of Ti foil, were modified with monometallic (Cu, Bi) and bimetallic (AgCu) nanoparticles. Different amounts of metals’ precursors were deposited on the surface of NTs by the spin-coating technique, and the reduction of metals was performed via gamma radiolysis. Surface modification of titania was studied by EDS and XPS analysis. The results show that AgCu nanoparticles exist in a Ag core -Cu shell form. Photocatalytic activity was examined under UV irradiation and phenol was used as a model pollutant of water. Over 95% of phenol degradation was achieved after 60 min of irradiation for almost all examined samples, but only slight difference in degradation efficiency (about 3%) between modified and bare NTs was observed. However, the initial phenol degradation rate and TOC removal efficiency was significantly enhanced for the samples modified with 0.31 and 0.63 mol% of Bi as well as for all the samples modified with Cu and AgCu nanoparticles in comparison with bare titania nanotubes. The saturated photocurrent, under the influence of simulated solar light irradiation, for the most active Bi- and AgCu-modified samples, was over two times higher than for pristine NTs. All the examined materials were resistant towards photocorrosion processes that enables their application for long term processes induced by light.

  15. Enhanced photocatalytic, electrochemical and photoelectrochemical properties of TiO{sub 2} nanotubes arrays modified with Cu, AgCu and Bi nanoparticles obtained via radiolytic reduction

    Energy Technology Data Exchange (ETDEWEB)

    Nischk, Michał [Department of Chemical Technology, Faculty of Chemistry, Gdansk University of Technology, 11/12 G. Narutowicza 11/12 St., 80-233 Gdansk (Poland); Department of Environmental Technology, Faculty of Chemistry, University of Gdansk, 63 Wita Stwosza St., 80-308 Gdansk (Poland); Mazierski, Paweł [Department of Environmental Technology, Faculty of Chemistry, University of Gdansk, 63 Wita Stwosza St., 80-308 Gdansk (Poland); Wei, Zhishun [Institute for Catalysis, Hokkaido University, N21, W10, 001-0021, Sapporo (Japan); Siuzdak, Katarzyna [Centre for Plasma and Laser Engineering, The Szewalski Institute of Fluid-Flow Machinery, Polish Academy of Sciences, 14 Fiszera St., 80-231 Gdansk (Poland); Kouame, Natalie Amoin [Laboratoire de Chimie Physique, CNRS—UMR 8000,Université Paris-Sud, Université Paris-Saclay, Bâtiment 349, 91405 Orsay (France); Kowalska, Ewa [Institute for Catalysis, Hokkaido University, N21, W10, 001-0021, Sapporo (Japan); Remita, Hynd [Laboratoire de Chimie Physique, CNRS—UMR 8000,Université Paris-Sud, Université Paris-Saclay, Bâtiment 349, 91405 Orsay (France); Zaleska-Medynska, Adriana, E-mail: adriana.zaleska@ug.edu.pl [Department of Environmental Technology, Faculty of Chemistry, University of Gdansk, 63 Wita Stwosza St., 80-308 Gdansk (Poland)

    2016-11-30

    Highlights: • TiO{sub 2} nanotubes were modified with Cu, AgCu, Bi nanoparticles via gamma radiolysis. • Excessive amount of deposited metal decreased photocatalytic activity. • AgCu-modified samples were more active than Cu-modified (with the same Cu content). • AgCu nanoparticles exist in a core{sub (Ag)}-shell{sub (Cu)} form. • Examined photocatalysts were resistant towards photocorrosion processes. - Abstract: TiO{sub 2} nanotubes arrays (NTs), obtained via electrochemical anodization of Ti foil, were modified with monometallic (Cu, Bi) and bimetallic (AgCu) nanoparticles. Different amounts of metals’ precursors were deposited on the surface of NTs by the spin-coating technique, and the reduction of metals was performed via gamma radiolysis. Surface modification of titania was studied by EDS and XPS analysis. The results show that AgCu nanoparticles exist in a Ag{sub core}-Cu{sub shell} form. Photocatalytic activity was examined under UV irradiation and phenol was used as a model pollutant of water. Over 95% of phenol degradation was achieved after 60 min of irradiation for almost all examined samples, but only slight difference in degradation efficiency (about 3%) between modified and bare NTs was observed. However, the initial phenol degradation rate and TOC removal efficiency was significantly enhanced for the samples modified with 0.31 and 0.63 mol% of Bi as well as for all the samples modified with Cu and AgCu nanoparticles in comparison with bare titania nanotubes. The saturated photocurrent, under the influence of simulated solar light irradiation, for the most active Bi- and AgCu-modified samples, was over two times higher than for pristine NTs. All the examined materials were resistant towards photocorrosion processes that enables their application for long term processes induced by light.

  16. Study of Charge Distribution in a Dust Beam using a Faraday Cup Assembly

    International Nuclear Information System (INIS)

    Kausik, S.S.; Dutta, P.; Chakraborty, M.; Kakati, M.; Saikia, B.K.

    2005-01-01

    A Faraday cup assembly is employed to study the charge distribution in a dust beam. The Faraday Cup scans the dust beam across its diameter and the dust particle current is noted in an Electrometer. The variation of the pico ampere current, carried by the charged dust particles in the beam, is studied with change in the gas pressure. The observations provide an insight into the variation of the charge to mass ratio in a dust beam

  17. BROADBAND RADIO POLARIMETRY AND FARADAY ROTATION OF 563 EXTRAGALACTIC RADIO SOURCES

    International Nuclear Information System (INIS)

    Anderson, C. S.; Gaensler, B. M.; Feain, I. J.; Franzen, T. M. O.

    2015-01-01

    We present a broadband spectropolarimetric survey of 563 discrete, mostly unresolved radio sources between 1.3 and 2.0 GHz using data taken with the Australia Telescope Compact Array. We have used rotation-measure synthesis to identify Faraday-complex polarized sources, those objects whose frequency-dependent polarization behavior indicates the presence of material possessing complicated magnetoionic structure along the line of sight (LOS). For sources classified as Faraday-complex, we have analyzed a number of their radio and multiwavelength properties to determine whether they differ from Faraday-simple polarized sources (sources for which LOS magnetoionic structures are comparatively simple) in these properties. We use this information to constrain the physical nature of the magnetoionic structures responsible for generating the observed complexity. We detect Faraday complexity in 12% of polarized sources at ∼1′ resolution, but we demonstrate that underlying signal-to-noise limitations mean the true percentage is likely to be significantly higher in the polarized radio source population. We find that the properties of Faraday-complex objects are diverse, but that complexity is most often associated with depolarization of extended radio sources possessing a relatively steep total intensity spectrum. We find an association between Faraday complexity and LOS structure in the Galactic interstellar medium (ISM) and claim that a significant proportion of the Faraday complexity we observe may be generated at interfaces of the ISM associated with ionization fronts near neutral hydrogen structures. Galaxy cluster environments and internally generated Faraday complexity provide possible alternative explanations in some cases

  18. A 2D semi-analytical model for Faraday shield in ICP source

    International Nuclear Information System (INIS)

    Zhang, L.G.; Chen, D.Z.; Li, D.; Liu, K.F.; Li, X.F.; Pan, R.M.; Fan, M.W.

    2016-01-01

    Highlights: • In this paper, a 2D model of ICP with faraday shield is proposed considering the complex structure of the Faraday shield. • Analytical solution is found to evaluate the electromagnetic field in the ICP source with Faraday shield. • The collision-free motion of electrons in the source is investigated and the results show that the electrons will oscillate along the radial direction, which brings insight into how the RF power couple to the plasma. - Abstract: Faraday shield is a thin copper structure with a large number of slits which is usually used in inductive coupled plasma (ICP) sources. RF power is coupled into the plasma through these slits, therefore Faraday shield plays an important role in ICP discharge. However, due to the complex structure of the Faraday shield, the resulted electromagnetic field is quite hard to evaluate. In this paper, a 2D model is proposed on the assumption that the Faraday shield is sufficiently long and the RF coil is uniformly distributed, and the copper is considered as ideal conductor. Under these conditions, the magnetic field inside the source is uniform with only the axial component, while the electric field can be decomposed into a vortex field generated by changing magnetic field together with a gradient field generated by electric charge accumulated on the Faraday shield surface, which can be easily found by solving Laplace's equation. The motion of the electrons in the electromagnetic field is investigated and the results show that the electrons will oscillate along the radial direction when taking no account of collision. This interesting result brings insight into how the RF power couples into the plasma.

  19. Faraday waves in quasi-one-dimensional superfluid Fermi-Bose mixtures

    DEFF Research Database (Denmark)

    Abdullaev, F. Kh.; Ögren, Magnus; Sørensen, Mads Peter

    2013-01-01

    The generation of Faraday waves in superfluid Fermi-Bose mixtures in elongated traps is investigated. The generation of waves is achieved by periodically changing a parameter of the system in time. Two types of modulations of parameters are considered: a variation of the fermion-boson scattering...... length and the boson-boson scattering length. We predict the properties of the generated Faraday patterns and study the parameter regions where they can be excited....

  20. Faraday rotation in an electron-positron plasma containing a fraction of ions

    International Nuclear Information System (INIS)

    Hall, J.O.; Shukla, P.K.

    2005-01-01

    The Faraday rotation in a magnetized electron-positron plasma containing a fraction of ions is investigated by using a multifluid description. It is shown that the Faraday rotation for circularly polarized electromagnetic waves with frequencies much larger than the electron/positron plasma and electron gyrofrequencies is proportional to the ion number density and the magnitude of the ambient magnetic-field strength. The results are relevant for astrophysical observations and diagnostics of laboratory electron-positron-ion magnetoplasmas

  1. Mini biased collimated faraday cups for measurement of intense pulsed ion beams

    International Nuclear Information System (INIS)

    He Xiaoping; Shi Lei; Zhang Jiasheng; Qiu Aici

    2000-01-01

    An analysis of principle of a biased Faraday cup for measuring ion beams density and the main reasons related to the measuring accuracy were presented. An array of mini biased collimated Faraday cups was manufactured for the measurement of ion beam density of a compact 200 keV high power ion beam source. In the experiments the maximum density of ion beam was in the center of the beam, and it was about 170 A/cm 2

  2. Anisotropy of the Faraday effect in the weak ferromagnetic YFeO3

    International Nuclear Information System (INIS)

    Zenkov, A.V.; Krichevtsov, B.B.; Moskvin, A.S.; Mukimov, K.M.; Pisarev, R.V.; Ruvinshtejn, M.M.

    1989-01-01

    The field strength dependence of the Faraday effect in the weak ferromagnetic YFeO 3 at the wavelength λ=0.63 μm are investigated experimentally for various directions of propagation of the light k-vector and magnetic field H-vector. It is shown that the variation of the Faraday effect for k-vector parallel c-vector and H-vector parallel a-vector is not proportional to the change of the magnetic moment component m z . The ferro-, antiferro- and diamagnetic contributions to the Faraday effect are separated on the basis of a phenomenological description of the Faraday effect in YFeO 3 . It is found that the antiferromagnetic contribution which determines the Faraday effect is strongly anisotropic. The microscopic mechanisms of the Faraday effect in YFeO 3 are considered theoretically for the case of the dipole-allowed 6 A 1g → 6 T 1u transition. It is shown that the mechanisms proposed earlier cannot explain the strong anisotropy of the antiferromagnetic contribution. In order to explain the anisotropy the spin-foreign orbit exchange-relativistic interaction should be taken into account

  3. Material and electromagnetic properties of Faraday shields for ion cyclotron heating antennas

    International Nuclear Information System (INIS)

    Hoffman, D.J.; Baity, F.W.; Becraft, W.R.; Caughman, J.B.O.; Tsai, C.C.

    1985-01-01

    The Faraday shields for ion cyclotron antennas must transmit magnetic waves and absorb little RF power. To investigate these properties, we have constructed 27 Faraday shields in many configurations, including chevrons, tubes, straps, concentric rings, various layered shields, conventionally leafed straps, and replicas of the Faraday shields for ASDEX, the Joint European Torus (JET), TEXTOR, and Alcator-C. We have measured the magnetic flux and observed loading at various operating resistances by using dielectric sheets or magnetic-coupled loads. Each Faraday shield effects a net change in the characteristic inductance of the antenna, resulting in a reduction of wave coupling. However, the load experienced by the antenna is not always reduced because the Faraday shield itself acts as a load. We differentiate between these effects experimentally. The net result of the study is that the Faraday shields now in use cost up to a factor of 50% of coupling. This, of course, reduces the power handling capability by 50% as well. However, configurations exist that are easily cooled and result in a reduction of less than 5% in loading

  4. Material and electromagnetic properties of Faraday shields for ion cyclotron heating antennas

    International Nuclear Information System (INIS)

    Hoffman, D.J.; Becraft, W.R.; Baity, F.W.; Caughman, J.B.O.; Tsai, C.C.

    1985-01-01

    The Faraday shields for ion cyclotron antennas must transmit magnetic waves and adsorb little rf power. To investigate these properties, we have constructed 27 Faraday shields in many configurations, including chevrons, tubes, straps, concentric rings, various layered shields, conventionally leafed straps, and replicas of the Faraday shields for ASDEX, the Joint European Torus (JET), TEXTOR, and Alcator-C. We have measured the magnetic flux and observed loading at various operating resistances by using dielectric sheets or magnetic-coupled loads. Each Faraday shield effects a net change in the characteristic inductance of the antenna, resulting in a reduction of wave coupling. However, the load experienced by the antenna is not always reduced because the Faraday shield itself acts as a load. We differentiate between these effects experimentally. The net result of the study is that the Faraday shields now in use cost up to a factor of 50% of coupling. This, of course, reduces the power handling capability by 50% as well. However, configurations exist that are easily cooled and result in a reduction of less than 5% in loading

  5. Polysulfone hemodiafiltration membranes with enhanced anti-fouling and hemocompatibility modified by poly(vinyl pyrrolidone) via in situ cross-linked polymerization

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Lijing, E-mail: zhulijing@nimte.ac.cn; Song, Haiming; Wang, Jiarong; Xue, Lixin, E-mail: xuelx@nimte.ac.cn

    2017-05-01

    Poly(vinyl pyrrolidone) (PVP) and its copolymers have been widely employed for the modification of hemodiafiltration membranes due to their excellent hydrophilicity, antifouling and hemocompatibility. However, challenges still remain to simplify the modification procedure and to improve the utilization efficiency. In this paper, antifouling and hemocompatibility polysulfone (PSf) hemodiafiltration membranes were fabricated via in situ cross-linked polymerization of vinyl pyrrolidone (VP) and vinyltriethoxysilane (VTEOS) in PSf solutions and non-solvent induced phase separation (NIPS) technique. The prepared membranes were characterized by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM), which suggested that VP and VTEOS have been cross-linked copolymerized in PSf membranes. The modified PSf membranes with high polymer content showed improved hydrophilicity, ultrafiltration and protein antifouling ability. In addition, the modified PSf membranes showed lower protein adsorption, inhibited platelet adhesion and deformation, prolonged the activated partial thromboplastin time (APTT), prothrombin time (PT), and decreased the content of fibrinogen (FIB) transferring to fibrin, indicating enhanced hemocompatibility. In a word, the present work provides a simple and effective one-step modification method to construct PSf membranes with improved hydrophilicity, antifouling and hemocompatibility. - Highlights: • PSf membranes were modified by in situ cross-linked polymerization. • The modified PSf membranes showed enhanced hydrophilicity. • The anti-fouling and hemocompatibility of PSf membranes were improved.

  6. Polysulfone hemodiafiltration membranes with enhanced anti-fouling and hemocompatibility modified by poly(vinyl pyrrolidone) via in situ cross-linked polymerization

    International Nuclear Information System (INIS)

    Zhu, Lijing; Song, Haiming; Wang, Jiarong; Xue, Lixin

    2017-01-01

    Poly(vinyl pyrrolidone) (PVP) and its copolymers have been widely employed for the modification of hemodiafiltration membranes due to their excellent hydrophilicity, antifouling and hemocompatibility. However, challenges still remain to simplify the modification procedure and to improve the utilization efficiency. In this paper, antifouling and hemocompatibility polysulfone (PSf) hemodiafiltration membranes were fabricated via in situ cross-linked polymerization of vinyl pyrrolidone (VP) and vinyltriethoxysilane (VTEOS) in PSf solutions and non-solvent induced phase separation (NIPS) technique. The prepared membranes were characterized by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM), which suggested that VP and VTEOS have been cross-linked copolymerized in PSf membranes. The modified PSf membranes with high polymer content showed improved hydrophilicity, ultrafiltration and protein antifouling ability. In addition, the modified PSf membranes showed lower protein adsorption, inhibited platelet adhesion and deformation, prolonged the activated partial thromboplastin time (APTT), prothrombin time (PT), and decreased the content of fibrinogen (FIB) transferring to fibrin, indicating enhanced hemocompatibility. In a word, the present work provides a simple and effective one-step modification method to construct PSf membranes with improved hydrophilicity, antifouling and hemocompatibility. - Highlights: • PSf membranes were modified by in situ cross-linked polymerization. • The modified PSf membranes showed enhanced hydrophilicity. • The anti-fouling and hemocompatibility of PSf membranes were improved.

  7. Enhanced photoelectrochemical and photocatalytic behaviors of MFe2O4 (M = Ni, Co, Zn and Sr) modified TiO2 nanorod arrays

    Science.gov (United States)

    Gao, Xin; Liu, Xiangxuan; Zhu, Zuoming; Wang, Xuanjun; Xie, Zheng

    2016-07-01

    Modified TiO2 nanomaterials are considered to be promising in energy conversion and ferrites modification may be one of the most efficient modifications. In this research, various ferrites, incorporated with various cations (MFe2O4, M = Ni, Co, Zn, and Sr), are utilized to modify the well aligned TiO2 nanorod arrays (NRAs), which is synthesized by hydrothermal method. It is found that all MFe2O4/TiO2 NRAs show obvious red shift into the visible light region compared with the TiO2 NRAs. In particular, NiFe2O4 modification is demonstrated to be the best way to enhance the photoelectrochemical and photocatalytic activity of TiO2 NRAs. Furthermore, the separation and transfer of charge carriers after MFe2O4 modification are clarified by electrochemical impedance spectroscopy measurements. Finally, the underlying mechanism accounting for the enhanced photocatalytic activity of MFe2O4/TiO2 NRAs is proposed. Through comparison among different transition metals modified TiO2 with the same synthesis process and under the same evaluating condition, this work may provide new insight in designing modified TiO2 nanomaterials as visible light active photocatalysts.

  8. Enhanced photocatalytic reduction of Hg(II) in aqueous medium by 2-aminothiazole-modified TiO2 particles

    OpenAIRE

    Cristante,Valtair M.; Araujo,Adriana B.; Jorge,Sônia M. A.; Florentino,Ariovaldo O.; Valente,José P. S.; Padilha,Pedro M.

    2006-01-01

    This work describes the synthesis and characterization of 2-aminothiazole-modified titania and its application on Hg (II) photoreduction in aqueous medium. Infrared spectroscopy confirmed the chemical modification of the titania matrix. The number of 2-aminothiazole groups attached to the titania was determined by Kjeldahl's method. The photocatalytic experiments were carried out in a cylindrical photoreactor thermostatted at 298 K. The resulting modified photocatalyst 2-aminothiazole titania...

  9. Synthesis of NaOH-Modified TiOF2 and Its Enhanced Visible Light Photocatalytic Performance on RhB

    Directory of Open Access Journals (Sweden)

    Chentao Hou

    2017-08-01

    Full Text Available NaOH-modified TiOF2 was successfully prepared using a modified low-temperature hydrothermal method. Scanning electron microscopy shows that NaOH-modified TiOF2 displayed a complex network shape with network units of about 100 nm. The structures of NaOH-modified TiOF2 have not been reported elsewhere. The network shape permits the NaOH-modified TiOF2 a SBET of 36 m2∙g−1 and a pore diameter around 49 nm. X-ray diffraction characterization shows that TiOF2 and NaOH-modified TiOF2 are crystallized with a pure changed cubic phase which accords with the SEM results. Fourier transform infrared spectroscopy characterization shows that NaOH-modified TiOF2 has more O–H groups to supply more lone electron pairs to transfer from O of O–H to Ti and O of TiOF2. UV–vis diffuse reflectance spectroscopy (DRS shows that the NaOH-modified TiOF2 sample has an adsorption plateau rising from 400 to 600 nm in comparison with TiOF2, and its band gap is 2.62 eV, lower than that of TiOF2. Due to the lower band gap, more O–H groups adsorption, network morphologies with larger surface area, and sensitization progress, the NaOH-modified TiOF2 exhibited much higher photocatalytic activity for Rhodamine B (RhB degradation. In addition, considering the sensitization progress, O–H groups on TiOF2 not only accelerated the degradation rate of RhB, but also changed its degradation path. As a result, the NaOH-modified TiOF2 exhibited much higher photocatalytic activity for RhB degradation than the TiOF2 in references under visible light. This finding provides a new idea to enhance the photocatalytic performance by NaOH modification of the surface of TiOF2.

  10. Full coverage of perovskite layer onto ZnO nanorods via a modified sequential two-step deposition method for efficiency enhancement in perovskite solar cells

    Science.gov (United States)

    Ruankham, Pipat; Wongratanaphisan, Duangmanee; Gardchareon, Atcharawon; Phadungdhitidhada, Surachet; Choopun, Supab; Sagawa, Takashi

    2017-07-01

    Full coverage of perovskite layer onto ZnO nanorod substrates with less pinholes is crucial for achieving high-efficiency perovskite solar cells. In this work, a two-step sequential deposition method is modified to achieve an appropriate property of perovskite (MAPbI3) film. Surface treatment of perovskite layer and its precursor have been systematically performed and their morphologies have been investigated. By pre-wetting of lead iodide (PbI2) and letting it dry before reacting with methylammonium iodide (MAI) provide better coverage of perovskite film onto ZnO nanorod substrate than one without any treatment. An additional MAI deposition followed with toluene drop-casting technique on the perovskite film is also found to increase the coverage and enhance the transformation of PbI2 to MAPbI3. These lead to longer charge carrier lifetime, resulting in an enhanced power conversion efficiency (PCE) from 1.21% to 3.05%. The modified method could been applied to a complex ZnO nanorods/TiO2 nanoparticles substrate. The enhancement in PCE to 3.41% is observed. These imply that our introduced method provides a simple way to obtain the full coverage and better transformation to MAPbI3 phase for enhancement in performances of perovskite solar cells.

  11. Faraday rotation, stochastic magnetic fields and CMB maps

    CERN Document Server

    Giovannini, Massimo

    2008-01-01

    The high- and low-frequency descriptions of the pre-decoupling plasma are deduced from the Vlasov-Landau treatment generalized to curved space-times and in the presence of the relativistic fluctuations of the geometry. It is demonstrated that the interplay between one-fluid and two-fluid treatments is mandatory for a complete and reliable calculation of the polarization observables. The Einstein-Boltzmann hierarchy is generalized to handle the dispersive propagation of the electromagnetic disturbances in the pre-decoupling plasma. Given the improved physical and numerical framework, the polarization observables are computed within the magnetized $\\Lambda$CDM paradigm (m$\\Lambda$CDM). In particular, the Faraday-induced B-mode is consistently estimated by taking into account the effects of the magnetic fields on the initial conditions of the Boltzmann hierarchy, on the dynamical equations and on the dispersion relations. The complete calculations of the angular power spectra constitutes the first step for the d...

  12. Evolution of pulsarmagnetism by virtue of a Faraday dynamo mechanism

    International Nuclear Information System (INIS)

    Heintzmann, H.; Novello, M.

    1983-01-01

    The evidence that radio-pulsars are slowed-down and Roentgen - pulsars accelerated predominantly by magnetic torques is now very strong. Angular momentum is transferred away from the neutron star to the velocity-of-light cylinder or from the Alfven - cylinder down to the neutron star by means of a magnetic spring the physical origin of which is an appropriate current flowing along the magnetic field lines. As this current must be closed at the neutron star's surface and no Hall-Field can be built-up a Faraday dynamo mechanism is set up. It is pointed out that this mechanism could switch -off a radio pulsar or turn-on a Roentgen pulsar. Many disconcerting pulsar observations could thus be explained, if radio pulsars can be reactivated in the galactic plane by means of accretion of matter in dense clouds and if Roentgenpulsars must first create a sufficiently strong magnetic field to function as a regularly pulsed emitter. (Author) [pt

  13. Faraday and Kerr Effects Diagnostics for Underwater Exploding Wires

    Science.gov (United States)

    Sarkisov, G. S.; Fedotov-Gefen, A. V.; Krasik, Ya. E.

    2012-10-01

    Two-channel laser polarimeter was used to measure magnetic and electric fields in vicinity of underwater exploding wire. Nd:YAG Q-switch laser with 532nm wavelength, 100mJ energy and 5ns pulse width was used for probing. Single wire, parallel wires and X and V- shaped wires was used in experiments. Electric and magnetic field induced birefringes in the water results in changing of polarization stage of probing beam after propagation through this anisotropic medium. Magnetic field results in circular anisotropy of the water, while electric field creates linear anisotropy. Magnetic field results in rotation of polarization plan of linear-polarized probing beam. Electric field effect is more complicated- polarization plan of the laser beam subjected to pulsation and changing of ellipticity. Effect of electric field depends on initial probing geometry- angle between electrical field vector E and polarization plane of probing wave. In our exploding wire experiments we found influence of both Faraday and Kerr effects. It was demonstrated existence of Kerr effect inside bubbles at high voltage electrode. Effect of magnetic fields interaction for multi-wire loads was observed.

  14. Faraday rotation signatures of fluctuation dynamos in young galaxies

    Science.gov (United States)

    Sur, Sharanya; Bhat, Pallavi; Subramanian, Kandaswamy

    2018-03-01

    Observations of Faraday rotation through high-redshift galaxies have revealed that they host coherent magnetic fields that are of comparable strengths to those observed in nearby galaxies. These fields could be generated by fluctuation dynamos. We use idealized numerical simulations of such dynamos in forced compressible turbulence up to rms Mach number of 2.4 to probe the resulting rotation measure (RM) and the degree of coherence of the magnetic field. We obtain rms values of RM at dynamo saturation of the order of 45-55 per cent of the value expected in a model where fields are assumed to be coherent on the forcing scale of turbulence. We show that the dominant contribution to the RM in subsonic and transonic cases comes from the general sea of volume filling fields, rather than from the rarer structures. However, in the supersonic case, strong field regions as well as moderately overdense regions contribute significantly. Our results can account for the observed RMs in young galaxies.

  15. Determination of kojic acid based on the interface enhancement effects of carbon nanotube/alizarin red S modified electrode.

    Science.gov (United States)

    Liu, Jieshu; Zhou, Dazhai; Liu, Xiaopeng; Wu, Kangbing; Wan, Chidan

    2009-04-01

    Based on non-covalent interactions such as pi-pi stacking, van der Waals interactions and strong adsorption, alizarin red S (ARS) interacts with multi-walled carbon nanotubes (MWNT), improving the solubility of MWNT in water and resulting in a stable MWNT/ARS solution. By successive cyclic sweeps between 0.0 and 2.2V in the MWNT/ARS solution, a MWNT/ARS composite film was fabricated on an electrode surface. The electrochemical behaviors of kojic acid at the bare electrode, the ARS film-modified electrode and the MWNT/ARS film-modified electrode were investigated. It was found that the oxidation signal of kojic acid significantly increased at the MWNT/ARS film-modified electrode, which was attributed to the unique properties of MWNT such as large surface area, strong adsorptive ability and subtle electronic character. The effects of pH and cyclic number of electropolymerization were examined. A rapid, sensitive and simple electrochemical method was then developed for the determination of kojic acid. This method exhibits good linearity over the range from 4.0 x 10(-7) to 6.0 x 10(-5)mol L(-1), and the limit of detection is as low as 1.0 x 10(-7)mol L(-1). In order to validate feasibility, the MWNT/ARS film-modified electrode was used for quantitative analysis of kojic acid in food samples.

  16. The use of maleic anhydride-modified polypropylene for performance enhancement in continuous glass fiber-reinforced polypropylene composites

    NARCIS (Netherlands)

    Rijsdijk, H.A.; Contant, M.; Peijs, A.A.J.M.; Miravete, A.

    1993-01-01

    The influence of maleic anhydride-modified polypropylene (m-PP) on static mech. properties of continuous glass fiber-reinforced polypropylene (PP) composites was studied. M-PP was added to the PP homopolymer to improve the adhesion between the matrix and the glass fiber. Three-point bending tests

  17. Engineering of Porphyrin Molecules for Use as Effective Cathode Interfacial Modifiers in Organic Solar Cells of Enhanced Efficiency and Stability.

    Science.gov (United States)

    Tountas, Marinos; Verykios, Apostolis; Polydorou, Ermioni; Kaltzoglou, Andreas; Soultati, Anastasia; Balis, Nikolaos; Angaridis, Panagiotis A; Papadakis, Michael; Nikolaou, Vasilis; Auras, Florian; Palilis, Leonidas C; Tsikritzis, Dimitris; Evangelou, Evangelos K; Gardelis, Spyros; Koutsoureli, Matroni; Papaioannou, George; Petsalakis, Ioannis D; Kennou, Stella; Davazoglou, Dimitris; Argitis, Panagiotis; Falaras, Polycarpos; Coutsolelos, Athanassios G; Vasilopoulou, Maria

    2018-06-06

    In the present work, we effectively modify the TiO 2 electron transport layer of organic solar cells with an inverted architecture using appropriately engineered porphyrin molecules. The results show that the optimized porphyrin modifier bearing two carboxylic acids as the anchoring groups and a triazine electron-withdrawing spacer significantly reduces the work function of TiO 2 , thereby reducing the electron extraction barrier. Moreover, the lower surface energy of the porphyrin-modified substrate results in better physical compatibility between the latter and the photoactive blend. Upon employing porphyrin-modified TiO 2 electron transport layers in PTB7:PC 71 BM-based organic solar cells we obtained an improved average power conversion efficiency up to 8.73%. Importantly, porphyrin modification significantly increased the lifetime of the devices, which retained 80% of their initial efficiency after 500 h of storage in the dark. Because of its simplicity and efficacy, this approach should give tantalizing glimpses and generate an impact into the potential of porphyrins to facilitate electron transfer in organic solar cells and related devices.

  18. Well-defined copolymers synthesized by RAFT polymerization as effective modifiers to enhance the photocatalytic performance of TiO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Vasilaki, E., E-mail: euavasilakh@gmail.com [Department of Chemistry, University of Crete, 710 03, Heraklion, Crete (Greece); Center of Materials Technology and Photonics, School of Applied Technology, Technological Educational Institute of Crete, 710 04 Heraklion, Crete (Greece); Kaliva, M. [Institute of Electronic Structure and Laser, Foundation for Research & Technology-Hellas, P.O. Box 1385, Vassilika Vouton, 711 10 Heraklion, Crete (Greece); Department of Materials Science and Technology, University of Crete, 710 03, Heraklion, Crete (Greece); Katsarakis, N. [Center of Materials Technology and Photonics, School of Applied Technology, Technological Educational Institute of Crete, 710 04 Heraklion, Crete (Greece); Institute of Electronic Structure and Laser, Foundation for Research & Technology-Hellas, P.O. Box 1385, Vassilika Vouton, 711 10 Heraklion, Crete (Greece); Vamvakaki, M. [Institute of Electronic Structure and Laser, Foundation for Research & Technology-Hellas, P.O. Box 1385, Vassilika Vouton, 711 10 Heraklion, Crete (Greece); Department of Materials Science and Technology, University of Crete, 710 03, Heraklion, Crete (Greece)

    2017-03-31

    Highlights: • Well-defined, random functional copolymers were synthesized by RAFT polymerization. • Novel TiO{sub 2} particles in-situ modified with copolymers were synthesized. • The hybrid catalysts exhibited reduced aggregation and particle size. • The photocatalytic removal of methylene blue was higher for the hybrid catalysts. - Αbstract: The enhancement of the photocatalytic performance of anatase TiO{sub 2} nanoparticles is demonstrated by a facile route, involving their in-situ surface modification with preformed polymer chains. Random copolymers of poly(ethylene glycol) methyl ether acrylate-co-methacrylic acid (PEGA-co-MAA) or poly(ethylene glycol) methyl ether acrylate-co-dopamine methacrylamide (PEGA-co-DMA) were synthesized by reversible addition−fragmentation chain-transfer (RAFT) polymerization and were bound onto the surface of anatase titania nanoparticles via the “grafting to” method. The hybrid nanocatalysts were characterized by fourier transform infrared spectroscopy, zeta-potential measurements, X-ray powder diffraction, thermogravimetric analysis and transmission electron microscopy. Their photocatalytic performance was evaluated by the decoloration of methylene blue (MB) dye in aqueous media under UV–vis light irradiation. The enhanced photoactivity and reusability of the polymer modified photocatalysts compared to that of bare TiO{sub 2} nanoparticles was attributed to their improved dispersability and colloidal stability, the smaller particle size that leads to a larger surface area and the increased adsorption capacity of the dye onto the polymer modified nanoparticles.

  19. Well-defined copolymers synthesized by RAFT polymerization as effective modifiers to enhance the photocatalytic performance of TiO_2

    International Nuclear Information System (INIS)

    Vasilaki, E.; Kaliva, M.; Katsarakis, N.; Vamvakaki, M.

    2017-01-01

    Highlights: • Well-defined, random functional copolymers were synthesized by RAFT polymerization. • Novel TiO_2 particles in-situ modified with copolymers were synthesized. • The hybrid catalysts exhibited reduced aggregation and particle size. • The photocatalytic removal of methylene blue was higher for the hybrid catalysts. - Αbstract: The enhancement of the photocatalytic performance of anatase TiO_2 nanoparticles is demonstrated by a facile route, involving their in-situ surface modification with preformed polymer chains. Random copolymers of poly(ethylene glycol) methyl ether acrylate-co-methacrylic acid (PEGA-co-MAA) or poly(ethylene glycol) methyl ether acrylate-co-dopamine methacrylamide (PEGA-co-DMA) were synthesized by reversible addition−fragmentation chain-transfer (RAFT) polymerization and were bound onto the surface of anatase titania nanoparticles via the “grafting to” method. The hybrid nanocatalysts were characterized by fourier transform infrared spectroscopy, zeta-potential measurements, X-ray powder diffraction, thermogravimetric analysis and transmission electron microscopy. Their photocatalytic performance was evaluated by the decoloration of methylene blue (MB) dye in aqueous media under UV–vis light irradiation. The enhanced photoactivity and reusability of the polymer modified photocatalysts compared to that of bare TiO_2 nanoparticles was attributed to their improved dispersability and colloidal stability, the smaller particle size that leads to a larger surface area and the increased adsorption capacity of the dye onto the polymer modified nanoparticles.

  20. Laser-Modified Surface Enhances Osseointegration and Biomechanical Anchorage of Commercially Pure Titanium Implants for Bone-Anchored Hearing Systems

    Science.gov (United States)

    Omar, Omar; Simonsson, Hanna; Palmquist, Anders; Thomsen, Peter

    2016-01-01

    Osseointegrated implants inserted in the temporal bone are a vital component of bone-anchored hearing systems (BAHS). Despite low implant failure levels, early loading protocols and simplified procedures necessitate the application of implants which promote bone formation, bone bonding and biomechanical stability. Here, screw-shaped, commercially pure titanium implants were selectively laser ablated within the thread valley using an Nd:YAG laser to produce a microtopography with a superimposed nanotexture and a thickened surface oxide layer. State-of-the-art machined implants served as controls. After eight weeks’ implantation in rabbit tibiae, resonance frequency analysis (RFA) values increased from insertion to retrieval for both implant types, while removal torque (RTQ) measurements showed 153% higher biomechanical anchorage of the laser-modified implants. Comparably high bone area (BA) and bone-implant contact (BIC) were recorded for both implant types but with distinctly different failure patterns following biomechanical testing. Fracture lines appeared within the bone ~30–50 μm from the laser-modified surface, while separation occurred at the bone-implant interface for the machined surface. Strong correlations were found between RTQ and BIC and between RFA at retrieval and BA. In the endosteal threads, where all the bone had formed de novo, the extracellular matrix composition, the mineralised bone area and osteocyte densities were comparable for the two types of implant. Using resin cast etching, osteocyte canaliculi were observed directly approaching the laser-modified implant surface. Transmission electron microscopy showed canaliculi in close proximity to the laser-modified surface, in addition to a highly ordered arrangement of collagen fibrils aligned parallel to the implant surface contour. It is concluded that the physico-chemical surface properties of laser-modified surfaces (thicker oxide, micro- and nanoscale texture) promote bone bonding

  1. Time-Resolved Tandem Faraday Cup Development for High Energy TNSA Particles

    Science.gov (United States)

    Padalino, S.; Simone, A.; Turner, E.; Ginnane, M. K.; Glisic, M.; Kousar, B.; Smith, A.; Sangster, C.; Regan, S.

    2015-11-01

    MTW and OMEGA EP Lasers at LLE utilize ultra-intense laser light to produce high-energy ion pulses through Target Normal Sheath Acceleration (TNSA). A Time Resolved Tandem Faraday Cup (TRTF) was designed and built to collect and differentiate protons from heavy ions (HI) produced during TNSA. The TRTF includes a replaceable thickness absorber capable of stopping a range of user-selectable HI emitted from TNSA plasma. HI stop within the primary cup, while less massive particles continue through and deposit their remaining charge in the secondary cup, releasing secondary electrons in the process. The time-resolved beam current generated in each cup will be measured on a fast storage scope in multiple channels. A charge-exchange foil at the TRTF entrance modifies the charge state distribution of HI to a known distribution. Using this distribution and the time of flight of the HI, the total HI current can be determined. Initial tests of the TRTF have been made using a proton beam produced by SUNY Geneseo's 1.7 MV Pelletron accelerator. A substantial reduction in secondary electron production, from 70% of the proton beam current at 2MeV down to 0.7%, was achieved by installing a pair of dipole magnet deflectors which successfully returned the electrons to the cups in the TRTF. Ultimately the TRTF will be used to normalize a variety of nuclear physics cross sections and stopping power measurements. Based in part upon work supported by a DOE NNSA Award#DE-NA0001944.

  2. Atomic nitrogen encapsulated in fullerenes: realization of a chemical Faraday cage

    International Nuclear Information System (INIS)

    Lips, K.

    2000-01-01

    Fullerenes, C 60 and C 70 , are ideal containers for atomic nitrogen. We will show by electron paramagnetic resonance (EPR) experiments that nitrogen in C 60 keeps its atomic ground state configuration and resides in the center of the cage. This is the first time that atomic nitrogen is stabilized at ambient conditions. The inert shell of the fullerene protects the highly reactive nitrogen from undergoing chemical reactions with the surroundings. The fullerene cage is the chemical analogue of the Faraday cage in case of electrical fields, i.e. it shields off the chemical reactivity. As for the free nitrogen atom, the spins of the three p-electrons of nitrogen in C 60 are parallel (S = 3/2) and the atom has spherical symmetry. Due to the center position of nitrogen in C 60 , extremely sharp EPR lines are observed. This reflects the absence of a strong host-guest interaction and shows that the individuality of nitrogen in the fullerenes is preserved. Further evidence for the almost interaction-free suspension of nitrogen in the fullerene cages is provided by g-factor measurements. These investigations show that magnetic shielding of the host molecules can account for the observed differences between N rate at C 60 and N rate at C 70 . The fullerene cage can be chemically modified without destroying the endohedral complex. The chemical modifications change the symmetry of the molecule which is observed through an additional fine structure in the EPR spectrum. Influences of the modifications on the stability of N rate at C 60 will be discussed. (orig.)

  3. Measurement of the effects of Faraday shields on ICRH antenna coupling

    International Nuclear Information System (INIS)

    Kwon, M.; Thomas, C.E. Jr.; Rettig, C.L.

    1990-01-01

    Compact loop antennas are being applied to several fusion experiments. Although individual configurations vary, all of these antennas generally comprise a current strap in a recessed box and a Faraday shield. The effect of the cross-sectional shape of the current strap on voltage and current levels was measured. In this work the coupling characteristics of cavity antennas that have current straps with the previously evaluated cross-sectional shapes re tested with several Faraday shields. Impedances and relative fields are measured for various combinations of the current strap and Faraday shield. The experiments show that the fractional reduction in the magnetic flux linkage to the plasma resulting from the addition of any particular Faraday shield i virtually independent of the shape of the current strap. This is true in spite of the fact that the same mechanism which is responsible for the reduction in flux is also responsible for a significant redistribution of the antenna current on the current strap. Thus the process of optimizing antennas is reduced to that of separately optimizing the current strap and Faraday shield

  4. Position control of desiccation cracks by memory effect and Faraday waves.

    Science.gov (United States)

    Nakayama, Hiroshi; Matsuo, Yousuke; Takeshi, Ooshida; Nakahara, Akio

    2013-01-01

    Pattern formation of desiccation cracks on a layer of a calcium carbonate paste is studied experimentally. This paste is known to exhibit a memory effect, which means that a short-time application of horizontal vibration to the fresh paste predetermines the direction of the cracks that are formed after the paste is dried. While the position of the cracks (as opposed to their direction) is still stochastic in the case of horizontal vibration, the present work reports that their positioning is also controllable, at least to some extent, by applying vertical vibration to the paste and imprinting the pattern of Faraday waves, thus breaking the translational symmetry of the system. The experiments show that the cracks tend to appear in the node zones of the Faraday waves: in the case of stripe-patterned Faraday waves, the cracks are formed twice more frequently in the node zones than in the anti-node zones, presumably due to the localized horizontal motion. As a result of this preference of the cracks to the node zones, the memory of the square lattice pattern of Faraday waves makes the cracks run in the oblique direction differing by 45 degrees from the intuitive lattice direction of the Faraday waves.

  5. A Faraday laser lasing on Rb 1529 nm transition.

    Science.gov (United States)

    Chang, Pengyuan; Peng, Huanfa; Zhang, Shengnan; Chen, Zhangyuan; Luo, Bin; Chen, Jingbiao; Guo, Hong

    2017-08-21

    We present the design and performance characterization of a Faraday laser directly lasing on the Rb 1529 nm transition (Rb, 5P 3/2  - 4D 5/2 ) with high stability, narrow spectral linewidth and low cost. This system does not need an additional frequency-stabilized pump laser as a prerequisite to preparing Rb atom from 5S to 5P excited state. Just by using a performance-improved electrodeless discharge lamp-based excited-state Faraday anomalous dispersion optical filter (LESFADOF), we realized a heterogeneously Faraday laser with the frequency corresponding to atomic transition, working stably over a range of laser diode (LD) current from 85 mA to 171 mA and the LD temperature from 11 °C to 32 °C, as well as the 24-hour long-term frequency fluctuation range of no more than 600 MHz. Both the laser linewidth and relative intensity noisy (RIN) are measured. The Faraday laser lasing on Rb 1529 nm transition (telecom C-band) can be applied to further research on metrology, microwave photonics and optical communication systems. Besides, since the transitions correspongding to the populated excited-states of alkali atoms within lamp are extraordinarily rich, this scheme can increase the flexibility for choosing proper wavelengths for Faraday laser and greatly expand the coverage of wavelength corresponding to atomic transmission for laser frequency stabilization.

  6. Diagnostics of the solar corona from comparison between Faraday rotation measurements and magnetohydrodynamic simulations

    International Nuclear Information System (INIS)

    Le Chat, G.; Cohen, O.; Kasper, J. C.; Spangler, S. R.

    2014-01-01

    Polarized natural radio sources passing behind the Sun experience Faraday rotation as a consequence of the electron density and magnetic field strength in coronal plasma. Since Faraday rotation is proportional to the product of the density and the component of the magnetic field along the line of sight of the observer, a model is required to interpret the observations and infer coronal structures. Faraday rotation observations have been compared with relatively ad hoc models of the corona. Here for the first time we compare these observations with magnetohydrodynamic (MHD) models of the solar corona driven by measurements of the photospheric magnetic field. We use observations made with the NRAO Very Large Array of 34 polarized radio sources occulted by the solar corona between 5 and 14 solar radii. The measurements were made during 1997 May, and 2005 March and April. We compare the observed Faraday rotation values with values extracted from MHD steady-state simulations of the solar corona. We find that (1) using a synoptic map of the solar magnetic field just one Carrington rotation off produces poorer agreements, meaning that the outer corona changes in the course of one month, even in solar minimum; (2) global MHD models of the solar corona driven by photospheric magnetic field measurements are generally able to reproduce Faraday rotation observations; and (3) some sources show significant disagreement between the model and the observations, which appears to be a function of the proximity of the line of sight to the large-scale heliospheric current sheet.

  7. A modified abstraction of Sierpiński fractals towards enhanced sensitivity of a cross-coupled bow-tie nanostructure

    Science.gov (United States)

    Hasan, Dihan; Lee, Chengkuo

    2018-06-01

    We experimentally demonstrate a modified abstraction of a fractal geometry (up to order M = 2), namely the Sierpiński fractal, with intrinsic self-similarity for a multitude of infrared sensing applications. The modification particularly strengthens the dipolar resonance and enables optical magnetism at longer wavelengths on a relatively miniaturized footprint. In contrast to the conventional resonant sensing, we harness the broadband electric field enhancement of the modified fractal patterns originating from the lightning rod effect in the non-resonant regime. We demonstrate strong enhancement of molecular absorption at mid-IR by the fractal patterns in the non-resonant regime even under extreme thermal broadening. Finally, we extend the work towards the functional study of the molecular fingerprint of ultra-thin film (∼5 nm) on a non-complementary metamaterial platform in the non-resonant regime. With the help of the solid state chemical dewetting of the monolayer, we also successfully demonstrate a new type of cross-coupling mediated sensitivity of the multispectral and mutually coupled fractal patterns. The research clearly indicates the usefulness of broadband electric field enhancement by the second order fractal pattern for on chip, complete profiling of mid-IR fingerprints of biological elements, i.e. cell, and protein monolayer on a limited footprint and under versatile morphological states.

  8. 2'-OMe-phosphorodithioate-modified siRNAs show increased loading into the RISC complex and enhanced anti-tumour activity.

    Science.gov (United States)

    Wu, Sherry Y; Yang, Xianbin; Gharpure, Kshipra M; Hatakeyama, Hiroto; Egli, Martin; McGuire, Michael H; Nagaraja, Archana S; Miyake, Takahito M; Rupaimoole, Rajesha; Pecot, Chad V; Taylor, Morgan; Pradeep, Sunila; Sierant, Malgorzata; Rodriguez-Aguayo, Cristian; Choi, Hyun J; Previs, Rebecca A; Armaiz-Pena, Guillermo N; Huang, Li; Martinez, Carlos; Hassell, Tom; Ivan, Cristina; Sehgal, Vasudha; Singhania, Richa; Han, Hee-Dong; Su, Chang; Kim, Ji Hoon; Dalton, Heather J; Kovvali, Chandra; Keyomarsi, Khandan; McMillan, Nigel A J; Overwijk, Willem W; Liu, Jinsong; Lee, Ju-Seog; Baggerly, Keith A; Lopez-Berestein, Gabriel; Ram, Prahlad T; Nawrot, Barbara; Sood, Anil K

    2014-03-12

    Improving small interfering RNA (siRNA) efficacy in target cell populations remains a challenge to its clinical implementation. Here, we report a chemical modification, consisting of phosphorodithioate (PS2) and 2'-O-Methyl (2'-OMe) MePS2 on one nucleotide that significantly enhances potency and resistance to degradation for various siRNAs. We find enhanced potency stems from an unforeseen increase in siRNA loading to the RNA-induced silencing complex, likely due to the unique interaction mediated by 2'-OMe and PS2. We demonstrate the therapeutic utility of MePS2 siRNAs in chemoresistant ovarian cancer mouse models via targeting GRAM domain containing 1B (GRAMD1B), a protein involved in chemoresistance. GRAMD1B silencing is achieved in tumours following MePS2-modified siRNA treatment, leading to a synergistic anti-tumour effect in combination with paclitaxel. Given the previously limited success in enhancing siRNA potency with chemically modified siRNAs, our findings represent an important advance in siRNA design with the potential for application in numerous cancer types.

  9. 2’f-OMe-phosphorodithioate modified siRNAs show increased loading into the RISC complex and enhanced anti-tumour activity

    Science.gov (United States)

    Wu, Sherry Y.; Yang, Xianbin; Gharpure, Kshipra M.; Hatakeyama, Hiroto; Egli, Martin; McGuire, Michael H.; Nagaraja, Archana S.; Miyake, Takahito M.; Rupaimoole, Rajesha; Pecot, Chad V.; Taylor, Morgan; Pradeep, Sunila; Sierant, Malgorzata; Rodriguez-Aguayo, Cristian; Choi, Hyun J.; Previs, Rebecca A.; Armaiz-Pena, Guillermo N.; Huang, Li; Martinez, Carlos; Hassell, Tom; Ivan, Cristina; Sehgal, Vasudha; Singhania, Richa; Han, Hee-Dong; Su, Chang; Kim, Ji Hoon; Dalton, Heather J.; Kowali, Chandra; Keyomarsi, Khandan; McMillan, Nigel A.J.; Overwijk, Willem W.; Liu, Jinsong; Lee, Ju-Seog; Baggerly, Keith A.; Lopez-Berestein, Gabriel; Ram, Prahlad T.; Nawrot, Barbara; Sood, Anil K.

    2014-01-01

    Improving small interfering RNA (siRNA) efficacy in target cell populations remains a challenge to its clinical implementation. Here, we report a chemical modification, consisting of phosphorodithioate (PS2) and 2’-O-Methyl (2’-OMe) MePS2 on one nucleotide that significantly enhances potency and resistance to degradation for various siRNAs. We find enhanced potency stems from an unforeseen increase in siRNA loading to the RNA-induced silencing complex, likely due to the unique interaction mediated by 2’-OMe and PS2. We demonstrate the therapeutic utility of MePS2 siRNAs in chemoresistant ovarian cancer mouse models via targeting GRAM Domain Containing 1B (GRAMD1B), a protein involved in chemoresistance. GRAMD1B silencing is achieved in tumors following MePS2-modified siRNA treatment, leading to a synergistic anti-tumor effect in combination with paclitaxel. Given the previously limited success in enhancing siRNA potency with chemically modified siRNAs, our findings represent an important advance in siRNA design with the potential for application in numerous cancer types. PMID:24619206

  10. Enhanced piezoelectric properties and excellent thermal stabilities of cobalt-modified Aurivillius-type calcium bismuth titanate (CaBi_4Ti_4O_1_5)

    International Nuclear Information System (INIS)

    Zhao, Tian-Long; Wang, Chun-Ming; Wang, Chun-Lei; Wang, Yi-Ming; Dong, Shuxiang

    2015-01-01

    Highlights: • Cobalt oxide modified CBT-based ceramics were prepared and investigated in detail. • XRPD analysis revealed Co ions enter into B-site of CBT-based ceramics. • CBT-Co4 ceramics show the enhanced d_3_3 of 14 pC/N and T_c of 782 °C. • CBT-Co4 ceramics present the improved high-temperature resistivity. • Thermal depoling behavior indicates CBT-Co4 ceramics exhibit good thermal stability. - Abstract: Bismuth layer-structured ferroelectric (BLSF) calcium bismuth titanate (CaBi_4Ti_4O_1_5, CBT) piezoelectric ceramics with 0.0–1.0 wt.% cobalt oxide (Co_2O_3) have been prepared via a conventional solid-state reaction method. Microstructural morphology and electrical properties of cobalt oxide-modified CBT ceramics were investigated in detail. X-ray powder diffraction (XRPD) analysis revealed that the cobalt oxide-modified CBT ceramics have a pure four-layer Aurivillius-type structure. The piezoelectric properties of CBT ceramics were significantly enhanced by cobalt oxide modifications. The piezoelectric coefficient d_3_3 and Curie temperature T_c of 0.2 wt.% cobalt oxide-modified CBT ceramics (CBT-Co4) are 14 pC/N and 782 °C, respectively. The DC resistivity and thermal depoling behavior at elevated temperature indicated that the CBT-Co4 ceramics exhibit good thermal stability, demonstrating that the CBT-Co4 ceramics are potential materials for high temperature piezoelectric applications.

  11. Synthesis of Ru nanoparticles confined in magnesium oxide-modified mesoporous alumina and their enhanced catalytic performance during ammonia decomposition

    KAUST Repository

    Tan, Hua

    2012-09-01

    In this work, Ru nanoparticles confined in the channels of ordered mesoporous alumina (MA) and magnesium oxide-modified ordered MA are prepared for the first time via a two-solvent technique, combined with the amorphous citrate route. Structural characterizations reveal that uniform 2-3 nm Ru nanoparticles are highly dispersed in the blockage-free channels of mesoporous supports. The Ru nanoparticles confined in MA modified with 20% molar ratio magnesium oxide exhibited a high catalytic activity and stability during ammonia decomposition due to the optimized particle size, basic support, lack of chlorine, and confined space provided by the channels of the mesoporous supports. © 2012 Elsevier B.V. All rights reserved.

  12. Synthesis of Ru nanoparticles confined in magnesium oxide-modified mesoporous alumina and their enhanced catalytic performance during ammonia decomposition

    KAUST Repository

    Tan, Hua; Li, Kun; Sioud, Salim; Cha, Dong Kyu; Amad, Maan H.; Hedhili, Mohamed N.; Al-Talla, Zeyad

    2012-01-01

    In this work, Ru nanoparticles confined in the channels of ordered mesoporous alumina (MA) and magnesium oxide-modified ordered MA are prepared for the first time via a two-solvent technique, combined with the amorphous citrate route. Structural characterizations reveal that uniform 2-3 nm Ru nanoparticles are highly dispersed in the blockage-free channels of mesoporous supports. The Ru nanoparticles confined in MA modified with 20% molar ratio magnesium oxide exhibited a high catalytic activity and stability during ammonia decomposition due to the optimized particle size, basic support, lack of chlorine, and confined space provided by the channels of the mesoporous supports. © 2012 Elsevier B.V. All rights reserved.

  13. Cellobiose Dehydrogenase Aryl Diazonium Modified Single Walled Carbon Nanotubes: Enhanced Direct Electron Transfer through a Positively Charged Surface

    Science.gov (United States)

    2011-01-01

    One of the challenges in the field of biosensors and biofuel cells is to establish a highly efficient electron transfer rate between the active site of redox enzymes and electrodes to fully access the catalytic potential of the biocatalyst and achieve high current densities. We report on very efficient direct electron transfer (DET) between cellobiose dehydrogenase (CDH) from Phanerochaete sordida (PsCDH) and surface modified single walled carbon nanotubes (SWCNT). Sonicated SWCNTs were adsorbed on the top of glassy carbon electrodes and modified with aryl diazonium salts generated in situ from p-aminobenzoic acid and p-phenylenediamine, thus featuring at acidic pH (3.5 and 4.5) negative or positive surface charges. After adsorption of PsCDH, both electrode types showed excellent long-term stability and very efficient DET. The modified electrode presenting p-aminophenyl groups produced a DET current density of 500 μA cm−2 at 200 mV vs normal hydrogen reference electrode (NHE) in a 5 mM lactose solution buffered at pH 3.5. This is the highest reported DET value so far using a CDH modified electrode and comes close to electrodes using mediated electron transfer. Moreover, the onset of the electrocatalytic current for lactose oxidation started at 70 mV vs NHE, a potential which is 50 mV lower compared to when unmodified SWCNTs were used. This effect potentially reduces the interference by oxidizable matrix components in biosensors and increases the open circuit potential in biofuel cells. The stability of the electrode was greatly increased compared with unmodified but cross-linked SWCNTs electrodes and lost only 15% of the initial current after 50 h of constant potential scanning. PMID:21417322

  14. Characterization of potassium hydroxide (KOH) modified hydrochars from different feedstocks for enhanced removal of heavy metals from water.

    Science.gov (United States)

    Sun, Kejing; Tang, Jingchun; Gong, Yanyan; Zhang, Hairong

    2015-11-01

    Hydrochars produced from different feedstocks (sawdust, wheat straw, and corn stalk) via hydrothermal carbonization (HTC) and KOH modification were used as alternative adsorbents for aqueous heavy metals remediation. The chemical and physical properties of the hydrochars and KOH-treated hydrochars were characterized, and the ability of hydrochars for removal of heavy metals from aqueous solutions as a function of reaction time, pH, and initial contaminant concentration was tested. The results showed that KOH modification of hydrochars might have increased the aromatic and oxygen-containing functional groups, such as carboxyl groups, resulting in about 2-3 times increase of cadmium sorption capacity (30.40-40.78 mg/g) compared to that of unmodified hydrochars (13.92-14.52 mg/g). The sorption ability among different feedstocks after modification was as the following: sawdust > wheat straw > corn stack. Cadmium sorption kinetics on modified hydrochars could be interpreted with a pseudo-second order, and sorption isotherm was simulated with Langmuir adsorption model. High cadmium uptake on modified hydrochars was observed over the pH range of 4.0-8.0, while for other heavy metals (Pb(2+), Cu(2+), and Zn(2+)) the range was 4.0-6.0. In a multi-metal system, the sorption capacity of heavy metals by modified hydrochars was also higher than that by unmodified ones and followed the order of Pb(II) > Cu(II) > Cd(II) > Zn(II). The results suggest that KOH-modified hydrochars can be used as a low cost, environmental-friendly, and effective adsorbent for heavy metal removal from aqueous solutions.

  15. Habitat structure modified by an invasive grass enhances inundation withstanding in a salt-marsh wolf spider

    OpenAIRE

    Pétillon, J.; Lambeets, K.; Montaigne, W.; Maelfait, J.-P.; Bonte, D.

    2010-01-01

    Vegetation and underground structures are known to influence flood avoidance and flood resistance in invertebrates. In bimonthly-flooded European salt marshes, recent invasions by the nitrophilous grass Elymus athericus strongly modified usual habitat structure, notably by the production of a deep litter layer. Consequently, invaded habitats provide more interstitial spaces that may act as a refuge during flood events. By using both controlled and field designs, we tested whether invaded habi...

  16. Mesoporous fluorocarbon-modified silica aerogel membranes enabling long-term continuous CO2 capture with large absorption flux enhancements.

    Science.gov (United States)

    Lin, Yi-Feng; Chen, Chien-Hua; Tung, Kuo-Lun; Wei, Te-Yu; Lu, Shih-Yuan; Chang, Kai-Shiun

    2013-03-01

    The use of a membrane contactor combined with a hydrophobic porous membrane and an amine absorbent has attracted considerable attention for the capture of CO2 because of its extensive use, low operational costs, and low energy consumption. The hydrophobic porous membrane interface prevents the passage of the amine absorbent but allows the penetration of CO2 molecules that are captured by the amine absorbent. Herein, highly porous SiO2 aerogels modified with hydrophobic fluorocarbon functional groups (CF3 ) were successfully coated onto a macroporous Al2 O3 membrane; their performance in a membrane contactor for CO2 absorption is discussed. The SiO2 aerogel membrane modified with CF3 functional groups exhibits the highest CO2 absorption flux and can be continuously operated for CO2 absorption for extended periods of time. This study suggests that a SiO2 aerogel membrane modified with CF3 functional groups could potentially be used in a membrane contactor for CO2 absorption. Also, the resulting hydrophobic SiO2 aerogel membrane contactor is a promising technology for large-scale CO2 absorption during the post-combustion process in power plants. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Bromine-doped DWNTs: A Molecular Faraday Cage

    Science.gov (United States)

    Chen, Gugang; Margine, Roxana; Gupta, Rajeev; Crespi, Vincent; Eklund, Peter; Sumanasekera, Gamini; Bandow, Shunji; Iijima, S.

    2003-03-01

    Raman scattering is used to probe the charge transfer distribution in Bromine-doped double-walled carbon nanotubes (DWNT). Using 1064 nm and 514.5 nm laser excitation we are able to study the charge-transfer sensitive phonons in the inner ( (5,5)) and outer ( (10,10)) tubes of the double-walled pair. The experimental results are compared to our tight binding band structure calculations that include a self-consistent electrostatic term sensitive to the average net charge density on each tube. Upon doping, the nanotube tangential and radial Raman bands from the outer (primary) tubes were observed to shift dramatically to higher frequencies, consistent with a C-C bond contraction driven by the acceptor-doping. The peak intensities of these bands significantly decreased with increasing doping exposure, and they eventually vanished, consistent with a deep depression in the Fermi energy that extinguishes the resonant Raman effect. Interestingly, at the same time, we observed little or no change for the tangential and radial Raman features identified with the inner (secondary) tubes during the bromine doping. Our electronic structure calculations show that the charge distribution between the outer and inner tubes depends on doping level and also, to some extent, on specific tube chirality combinations. In general, in agreement with experiment, the calculations find a very small net charge on the inner tube, consistent with a "Molecular Faraday Effect", e.g., a DWNT of (10, 10)/ (5, 5) configuration that exhibits 0.5 holes/Å total charge transfer, has only 0.04 holes/Å on the inner (secondary) tube.

  18. Surfactant-promoted Prussian Blue-modified carbon electrodes: enhancement of electro-deposition step, stabilization, electrochemical properties and application to lactate microbiosensors for the neurosciences.

    Science.gov (United States)

    Salazar, P; Martín, M; O'Neill, R D; Roche, R; González-Mora, J L

    2012-04-01

    We report here for the first time a comparison of the beneficial effects of different cationic surfactants - cetyl trimethyl ammonium bromide (CTAB), benzethonium chloride (BZT) and cetylpyridinium chloride (CPC) - for the electrochemical synthesis of Prussian Blue (PB) films, using cyclic voltammetry (CV), on screen-printed carbon electrodes (SPCEs). Their electrochemical properties were investigated, paying special attention to parameters such as the amount of PB deposited, film thickness, charge transfer rate, permeability, reversibility, stability and sensitivity to hydrogen peroxide detection. All surfactant-enhanced PB-modified SPCEs displayed a significant improvement in their electrochemical properties compared with PB-modified SPCEs formed in the absence of surfactants. Surfactant-modified electrodes displayed a consistently higher PB surface concentration value of 2.1±0.4×10(-8) mol cm(-2) (mean±SD, n=3) indicating that PB deposition efficiency was improved 2-3 fold. K(+) and Na(+) permeability properties of the films were also studied, as were kinetic parameters, such as the surface electron transfer rate constant (k(s)) and the transfer coefficient (α). The hydrogen peroxide sensitivity of surfactant-modified PB films generated by 10 electro-deposition CV cycles gave values of 0.63 A M(-1) cm(-2), which is higher than those reported previously for SPCEs by other authors. Finally, the first lactate microbiosensor described in the literature based on BZT-modified PB-coated carbon fiber electrodes is presented. Its very small cross-section (~10 μm diameter) makes it particularly suitable for neuroscience studies in vivo. Copyright © 2011 Elsevier B.V. All rights reserved.

  19. Design for coordinated measurements of Faraday rotation and line-of-sight electron density using heterodyne techniques

    International Nuclear Information System (INIS)

    Jacobson, A.R.

    1977-07-01

    This report proposes a device which can overcome certain of the compromises of conventional Faraday rotation methods and at the same time measure the optical phase as well as the polarization. This would be useful for unfolding the Faraday rotation signal using the line-of-sight density along exactly the same path. Preliminary design parameters using a CO 2 laser are presented

  20. Novel Faraday cup for the simultaneous observation and measurement of ion-beam currents

    International Nuclear Information System (INIS)

    Wei, C.Y.; Seidman, D.N.

    1977-07-01

    The Faraday cup is constructed around a Galileo channel electron multiplier array (CEMA) which serves as the basis of an internal image intensification system (a gain of greater than 10 4 ) for the observation of the ion beam; the CEMA also acts as a collector for the ion cured by a Keithley 602 electrometer. The ion current is integrated by a simple and inexpensive dosimeter; the electronic circuit for the dosimeter is described. The application of the Faraday cup to the observation and measurement of a 30 keV Ar + ion beam is presented as an illustrative example. This Faraday cup was also employed to observe and measure 30 keV Cr + , Mo + or W + and 18 keV Au + ion beams employed for the in-situ irradiation of field-ion microscope specimens

  1. NMT - A new individual ion counting method: Comparison to a Faraday cup

    Science.gov (United States)

    Burton, Michael; Gorbunov, Boris

    2018-03-01

    Two sample detectors used to analyze the emission from Gas Chromatography (GC) columns are the Flame Ionization Detector (FID) and the Electron Capture Detector (ECD). Both of these detectors involve ionization of the sample molecules and then measuring electric current in the gas using a Faraday cup. In this paper a newly discovered method of ion counting, Nanotechnology Molecular Tagging (NMT) is tested as a replacement to the Faraday cup in GCs. In this method the effective physical volume of individual molecules is enlarged up to 1 billion times enabling them to be detected by an optical particle counter. It was found that the sensitivity of NMT was considerably greater than the Faraday cup. The background in the NMT was circa 200 ions per cm3, corresponding to an extremely low electric current ∼10-17 A.

  2. Faraday rotation influence factors in tellurite-based glass and fibers

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Qiuling; Wang, Qingwei [Henan University of Technology, School of Materials Science and Engineering, Zhengzhou, Henan (China); Wang, Hui; Chen, Qiuping [Politecnico di Torino, Department of Applied Science and Technology, Turin (Italy)

    2015-09-15

    The Faraday rotation influence factors in tellurite-based glass and fibers were studied by experiments and simulations. TeO{sub 2}-ZnO-Na{sub 2}O-BaO glass family was fabricated and characterized in terms of the thermal and magneto-optical properties. Two core-cladding pairs for two fibers were selected from fabricated glasses. The Verdet constants of the glasses and fibers were measured at different wavelengths using a homemade optical bench, and the Verdet constant of fiber was close to that of the bulk glass. The influence from external factors (wavelength, laser power and magnetic field) and internal factors (thermal expansion coefficient difference, refractive index and Verdet constant of core and cladding) on Faraday rotation in fibers was investigated and discussed, and the purpose of this study is to improve the Faraday rotation in tellurite fibers for MO device applications both from internal material property match and external parameter configuration in measurement. (orig.)

  3. Magneto-optical Faraday rotation of semiconductor nanoparticles embedded in dielectric matrices.

    Science.gov (United States)

    Savchuk, Andriy I; Stolyarchuk, Ihor D; Makoviy, Vitaliy V; Savchuk, Oleksandr A

    2014-04-01

    Faraday rotation has been studied for CdS, CdTe, and CdS:Mn semiconductor nanoparticles synthesized by colloidal chemistry methods. Additionally these materials were prepared in a form of semiconductor nanoparticles embedded in polyvinyl alcohol films. Transmission electron microscopy and atomic force microscopy analyses served as confirmation of nanocrystallinity and estimation of the average size of the nanoparticles. Spectral dependence of the Faraday rotation for the studied nanocrystals and nanocomposites is correlated with a blueshift of the absorption edge due to the confinement effect in zero-dimensional structures. Faraday rotation spectra and their temperature behavior in Mn-doped nanocrystals demonstrates peculiarities, which are associated with s, p-d exchange interaction between Mn²⁺ ions and band carriers in diluted magnetic semiconductor nanostructures.

  4. Polycrystalline (TbXY1-X)2O3 Faraday rotator.

    Science.gov (United States)

    Ikesue, Akio; Aung, Yan Lin; Makikawa, Shinji; Yahagi, Akira

    2017-11-01

    We have succeeded for the first time in synthesizing an optical grade (Tb X Y 1-X ) 2 O 3 (X=0.5-1.0) ceramic Faraday rotator, which greatly exceeds the basic characteristics of the commercial terbium gallium garnet (TGG) (Tb 3 Ga 5 O 12 ) crystal. The Faraday rotation angle increased as the Tb concentration increased, and the Verdet constant increased from 2.1 (82  rad T -1  m -1 at X=0.5) to 3.8 times (154  rad T -1  m -1 at X=1.0) than the TGG single crystal, which is regarded as highest class. Therefore, it is possible to minimize the Faraday rotator length and the magnet in building an optical isolator. It was also confirmed that its optical quality was very comparable to the commercial TGG crystal.

  5. Faraday-Shielded dc Stark-Shift-Free Optical Lattice Clock

    Science.gov (United States)

    Beloy, K.; Zhang, X.; McGrew, W. F.; Hinkley, N.; Yoon, T. H.; Nicolodi, D.; Fasano, R. J.; Schäffer, S. A.; Brown, R. C.; Ludlow, A. D.

    2018-05-01

    We demonstrate the absence of a dc Stark shift in an ytterbium optical lattice clock. Stray electric fields are suppressed through the introduction of an in-vacuum Faraday shield. Still, the effectiveness of the shielding must be experimentally assessed. Such diagnostics are accomplished by applying high voltage to six electrodes, which are grounded in normal operation to form part of the Faraday shield. Our measurements place a constraint on the dc Stark shift at the 10-20 level, in units of the clock frequency. Moreover, we discuss a potential source of error in strategies to precisely measure or cancel nonzero dc Stark shifts, attributed to field gradients coupled with the finite spatial extent of the lattice-trapped atoms. With this consideration, we find that Faraday shielding, complemented with experimental validation, provides both a practically appealing and effective solution to the problem of dc Stark shifts in optical lattice clocks.

  6. Faraday rotation in multiple quantum wells of GaAs/AlGaAs

    International Nuclear Information System (INIS)

    Dudziak, E.; Bozym, J.; Prochnik, D.; Wasilewski, Z.R.

    1996-01-01

    We report on the results of first measurements on the Faraday rotation of modulated n-doped multiple quantum wells of GaAs/Al x Ga 1-x As (x = 0.312). The measurements have been performed in the magnetic fields up to 13 T at the temperature of 2 K, in the spectral region of interband transitions. A rich structure of magneto-excitons has been found in the measured spectra. Faraday rotation (phase) measurements are proposed as an alternative method to the photoluminescence excitation for investigations of magneto-excitons in quantum wells. The dependence of measured Faraday rotation on magnetic field and hypothetical connections with quantum Hall effect are also discussed. (author)

  7. Faraday-effect polarimeter diagnostic for internal magnetic field fluctuation measurements in DIII-D.

    Science.gov (United States)

    Chen, J; Ding, W X; Brower, D L; Finkenthal, D; Muscatello, C; Taussig, D; Boivin, R

    2016-11-01

    Motivated by the need to measure fast equilibrium temporal dynamics, non-axisymmetric structures, and core magnetic fluctuations (coherent and broadband), a three-chord Faraday-effect polarimeter-interferometer system with fast time response and high phase resolution has recently been installed on the DIII-D tokamak. A novel detection scheme utilizing two probe beams and two detectors for each chord results in reduced phase noise and increased time response [δb ∼ 1G with up to 3 MHz bandwidth]. First measurement results were obtained during the recent DIII-D experimental campaign. Simultaneous Faraday and density measurements have been successfully demonstrated and high-frequency, up to 100 kHz, Faraday-effect perturbations have been observed. Preliminary comparisons with EFIT are used to validate diagnostic performance. Principle of the diagnostic and first experimental results is presented.

  8. Faraday-effect polarimeter diagnostic for internal magnetic field fluctuation measurements in DIII-D

    International Nuclear Information System (INIS)

    Chen, J.; Ding, W. X.; Brower, D. L.; Finkenthal, D.; Muscatello, C.; Taussig, D.; Boivin, R.

    2016-01-01

    Motivated by the need to measure fast equilibrium temporal dynamics, non-axisymmetric structures, and core magnetic fluctuations (coherent and broadband), a three-chord Faraday-effect polarimeter-interferometer system with fast time response and high phase resolution has recently been installed on the DIII-D tokamak. A novel detection scheme utilizing two probe beams and two detectors for each chord results in reduced phase noise and increased time response [δb ∼ 1G with up to 3 MHz bandwidth]. First measurement results were obtained during the recent DIII-D experimental campaign. Simultaneous Faraday and density measurements have been successfully demonstrated and high-frequency, up to 100 kHz, Faraday-effect perturbations have been observed. Preliminary comparisons with EFIT are used to validate diagnostic performance. Principle of the diagnostic and first experimental results is presented.

  9. Giant Faraday Rotation of High-Order Plasmonic Modes in Graphene-Covered Nanowires.

    Science.gov (United States)

    Kuzmin, Dmitry A; Bychkov, Igor V; Shavrov, Vladimir G; Temnov, Vasily V

    2016-07-13

    Plasmonic Faraday rotation in nanowires manifests itself in the rotation of the spatial intensity distribution of high-order surface plasmon polariton (SPP) modes around the nanowire axis. Here we predict theoretically the giant Faraday rotation for SPPs propagating on graphene-coated magneto-optically active nanowires. Upon the reversal of the external magnetic field pointing along the nanowire axis some high-order plasmonic modes may be rotated by up to ∼100° on the length scale of about 500 nm at mid-infrared frequencies. Tuning the carrier concentration in graphene by chemical doping or gate voltage allows for controlling SPP-properties and notably the rotation angle of high-order azimuthal modes. Our results open the door to novel plasmonic applications ranging from nanowire-based Faraday isolators to the magnetic control in quantum-optical applications.

  10. Faraday rotation influence factors in tellurite-based glass and fibers

    International Nuclear Information System (INIS)

    Chen, Qiuling; Wang, Qingwei; Wang, Hui; Chen, Qiuping

    2015-01-01

    The Faraday rotation influence factors in tellurite-based glass and fibers were studied by experiments and simulations. TeO 2 -ZnO-Na 2 O-BaO glass family was fabricated and characterized in terms of the thermal and magneto-optical properties. Two core-cladding pairs for two fibers were selected from fabricated glasses. The Verdet constants of the glasses and fibers were measured at different wavelengths using a homemade optical bench, and the Verdet constant of fiber was close to that of the bulk glass. The influence from external factors (wavelength, laser power and magnetic field) and internal factors (thermal expansion coefficient difference, refractive index and Verdet constant of core and cladding) on Faraday rotation in fibers was investigated and discussed, and the purpose of this study is to improve the Faraday rotation in tellurite fibers for MO device applications both from internal material property match and external parameter configuration in measurement. (orig.)

  11. Faraday effect in Cd1-xMnxTe semimagnetic semiconductor

    International Nuclear Information System (INIS)

    Vatamanyuk, P.P.; Savitskij, A.V.; Savchuk, A.I.; Ul'yanitskij, K.S.

    1988-01-01

    The Faraday effect is investigated in the semimagnetic semiconductor Cd 1-x Mn x Te (0≥x≤0.3) in the spectral range from 0.6 to 1.8 eV at temperatures between 4.2 and 350 K and in magnetic fields up to 250 kOe. Some peculiarities in the dispersion of the Faraday rotation (FR) are observed which are connected with a change in the direction of rotation depending on the composition and temperature. The results are analyzed by assuming the FR to consist of three components: an interband, exciton and intracentral contribution. The deviation of FR from saturation in strong magnetic fields is interpreted within the framework of antiferromagnetic exchange interaction between the Mn 2+ ions. On the basis of an analysis of the FR temperature dependence it is suggested that the spontaneous Faraday effect is characteristic of semimagnetic semiconductors in spin glass phase

  12. Haploinsufficiency of the insulin-like growth factor-1 receptor enhances endothelial repair and favorably modifies angiogenic progenitor cell phenotype.

    Science.gov (United States)

    Yuldasheva, Nadira Y; Rashid, Sheikh Tawqeer; Haywood, Natalie J; Cordell, Paul; Mughal, Romana; Viswambharan, Hema; Imrie, Helen; Sukumar, Piruthivi; Cubbon, Richard M; Aziz, Amir; Gage, Matthew; Mbonye, Kamatamu Amanda; Smith, Jessica; Galloway, Stacey; Skromna, Anna; Scott, D Julian A; Kearney, Mark T; Wheatcroft, Stephen B

    2014-09-01

    Defective endothelial regeneration predisposes to adverse arterial remodeling and is thought to contribute to cardiovascular disease in type 2 diabetes mellitus. We recently demonstrated that the type 1 insulin-like growth factor receptor (IGF1R) is a negative regulator of insulin sensitivity and nitric oxide bioavailability. In this report, we examined partial deletion of the IGF1R as a potential strategy to enhance endothelial repair. We assessed endothelial regeneration after wire injury in mice and abundance and function of angiogenic progenitor cells in mice with haploinsufficiency of the IGF1R (IGF1R(+/-)). Endothelial regeneration after arterial injury was accelerated in IGF1R(+/-) mice. Although the yield of angiogenic progenitor cells was lower in IGF1R(+/-) mice, these angiogenic progenitor cells displayed enhanced adhesion, increased secretion of insulin-like growth factor-1, and enhanced angiogenic capacity. To examine the relevance of IGF1R manipulation to cell-based therapy, we transfused IGF1R(+/-) bone marrow-derived CD117(+) cells into wild-type mice. IGF1R(+/-) cells accelerated endothelial regeneration after arterial injury compared with wild-type cells and did not alter atherosclerotic lesion formation. Haploinsufficiency of the IGF1R is associated with accelerated endothelial regeneration in vivo and enhanced tube forming and adhesive potential of angiogenic progenitor cells in vitro. Partial deletion of IGF1R in transfused bone marrow-derived CD117(+) cells enhanced their capacity to promote endothelial regeneration without altering atherosclerosis. Our data suggest that manipulation of the IGF1R could be exploited as novel therapeutic approach to enhance repair of the arterial wall after injury. © 2014 American Heart Association, Inc.

  13. Enhancement of fluorescence quenching and exciplex formation in DNA major groove by double incorporation of modified fluorescent deoxyuridines.

    Science.gov (United States)

    Tanaka, Makiko; Oguma, Kazuhiro; Saito, Yoshio; Saito, Isao

    2012-06-15

    5-(1-Naphthalenylethynyl)-2'-deoxyuridine ((N)U) and 5-[(4-cyano-1-naphthalenyl)ethynyl]-2'-deoxyuridine ((CN)U) were synthesized and incorporated into oligodeoxynucleotides. Fluorescence emissions of modified duplexes containing double (N)U were efficiently quenched depending upon the sequence pattern of the naphthalenes in DNA major groove, as compared to the duplex possessing single (N)U. When one of the naphthalene moieties has a cyano substituent, the exciplex emission from the chromophores in DNA major groove was observed at longer wavelength. Copyright © 2012 Elsevier Ltd. All rights reserved.

  14. Electrodeless-discharge-vapor-lamp-based Faraday anomalous-dispersion optical filter.

    Science.gov (United States)

    Sun, Qinqing; Zhuang, Wei; Liu, Zhiwen; Chen, Jingbiao

    2011-12-01

    We report an excited-state Faraday anomalous-dispersion optical filter operating on the rubidium 5P(3/2)-5D(5/2) transition (775.9 nm in vacuum) without the use of a pump laser. An electrodeless discharge vapor lamp is employed to replace the Rb vapor cell in a traditional Faraday anomalous-dispersion optical filter system. Atoms can be excited by power rather than a complex frequency-locked pump laser. A proof-of-concept experimental demonstration with a maximum transmission of 1.9% and a filter bandwidth of 650 MHz is presented. © 2011 Optical Society of America

  15. Graphite-ceramic rf Faraday-thermal shield and plasma limiter

    Science.gov (United States)

    Hwang, D.L.Q.; Hosea, J.C.

    1983-05-05

    The present invention is directed to a brazing procedure for joining a ceramic or glass material (e.g., Al/sub 2/O/sub 3/ or Macor) to graphite. In particular, the present invention is directed to a novel brazing procedure for the production of a brazed ceramic graphite product useful as a Faraday shield. The brazed ceramic graphite Faraday shield of the present invention may be used in Magnetic Fusion Devices (e.g., Princeton Large Torus Tokamak) or other high temperature resistant apparatus.

  16. Measurement of the current in water discharge using magneto-optical Faraday effect

    International Nuclear Information System (INIS)

    Sarkisov, G.S.; Woodworth, J.R.

    2006-01-01

    The observation of magnetooptical Faraday effects in water in experiments with electrical breakdown is presented. After high-voltage breakdown, the ionized channel with ∼4 kA current was generated. The magnetic field from the current channel induces a circular birefringence which results in rotation of the polarization plane of a probing laser (200 ps, 532 nm). In spite of fast opposite radius drop of the magnetic field in radial direction, the Faraday rotation effect drops very slowly. The rotation of the polarization plane was ∼0.65 deg. ±5%. The optical measurements are in good agreement within ∼7% with the electrical measurements of the current

  17. Orthotropic conductivity reconstruction with virtual-resistive network and Faraday's law

    KAUST Repository

    Lee, Min-Gi

    2015-06-01

    We obtain the existence and the uniqueness at the same time in the reconstruction of orthotropic conductivity in two-space dimensions by using two sets of internal current densities and boundary conductivity. The curl-free equation of Faraday\\'s law is taken instead of the elliptic equation in a divergence form that is typically used in electrical impedance tomography. A reconstruction method based on layered bricks-type virtual-resistive network is developed to reconstruct orthotropic conductivity with up to 40% multiplicative noise.

  18. El concepto de estado electro-tónico en Faraday

    OpenAIRE

    Romo Feito, José

    1991-01-01

    Sabemos la centralidad que la noción de estado electro-tónico tuvo en la primera formulación de las ecuaciones de Maxwell. El concepto, sin embargo, proviene de Faraday, que lo introdujo a raíz de su descubrimiento de la inducción electromagnética en 1831, y recurrió a él intermitentemente en los años siguientes. La tesis pretende trazar la evolución del concepto en la obra de Faraday.El capitulo 1 se ocupa, en primer lugar, de proporcionar algunos elementos para comprender la situación de la...

  19. Interaction of vortex lattice with ultrasound and the acoustic Faraday effect

    International Nuclear Information System (INIS)

    Dominguez, D.; Bulaevskii, L.; Ivlev, B.; Maley, M.; Bishop, A.R.

    1995-01-01

    The interaction of sound with the vortex lattice is considered for high-T c superconductors, taking into account pinning and electrodynamic forces between vortices and crystal displacements. At low temperatures the Magnus force results in the acoustic Faraday effect; the velocity of sound propagating along the magnetic field depends on the polarization. This effect is linear in the Magnus force and magnetic field in crystals with equivalent a and b axes for a field parallel to the c axis. In the thermally activated flux flow regime, the Faraday effect is caused by electric and magnetic fields induced by vortices and acting on ions

  20. Simultaneous measurement of line electron density and Faraday rotation in the ISX-B tokamak

    International Nuclear Information System (INIS)

    Hutchinson, D.P.; Ma, C.H.; Staats, P.A.; Vander Sluis, K.L.

    1981-01-01

    A new diagnostic system utilizing a submillimetre-wave, phase-modulated polarimeter/interferometer has been used to simultaneously measure the time evolution of the line-averaged electron density and poloidal field-induced Faraday rotation in the ISX-B tokamak. The measurements, performed along four chords of the plasma column, have been correlated with poloidal field changes associated with a ramp in the Ohmic-heating current and by neutral-beam injection. These are the first simultaneous measurements of line electron density and Faraday rotation to be made along a chord of submillimetre laser beam in a tokamak plasma. (author)