WorldWideScience

Sample records for energy transfer rates

  1. Geometry effect on energy transfer rate in a coupled-quantum-well structure: nonlinear regime

    International Nuclear Information System (INIS)

    Salavati-fard, T; Vazifehshenas, T

    2014-01-01

    We study theoretically the effect of geometry on the energy transfer rate at nonlinear regime in a coupled-quantum-well system using the balance equation approach. To investigate comparatively the effect of both symmetric and asymmetric geometry, different structures are considered. The random phase approximation dynamic dielectric function is employed to include the contributions from both quasiparticle and plasmon excitations. Also, the short-range exchange interaction is taken into account through the Hubbard approximation. Our numerical results show that the energy transfer rate increases by increasing the well thicknesses in symmetric structures. Furthermore, by increasing spatial asymmetry, the energy transfer rate decreases for the electron temperature range of interest. From numerical calculations, it is obtained that the nonlinear energy transfer rate is proportional to the square of electron drift velocity in all structures and also, found that the influence of Hubbard local field correction on the energy transfer rate gets weaker by increasing the strength of applied electric field. (paper)

  2. Spontaneous Emission and Energy Transfer Rates Near a Coated Metallic Cylinder

    OpenAIRE

    BRADLEY, LOUISE

    2014-01-01

    PUBLISHED The spontaneous emission and energy transfer rates of quantum systems in proximity to a dielectrically coated metallic cylinder are investigated using a Green's tensor formalism. The excitation of surface plasmon modes can significantly modify these rates. The spontaneous emission and energy transfer rates are investigated as a function of the material and dimensions of the core and coating, as well as the emission wavelength of the donor. For the material of the core we consider...

  3. Energy transfer rates in inhomogeneous van der Waals clusters

    International Nuclear Information System (INIS)

    Desfrancois, C.; Schermann, J.P.

    1991-01-01

    The internal energy exchange inside an inhomogeneous van der Waals cluster are investigated by means of molecular dynamic calculations. The very long time scales for relaxation of the high frequency degrees of freedom are examined within the framework of Nekhoroshev's theorem. (orig.)

  4. On the Statistical Properties of Turbulent Energy Transfer Rate in the Inner Heliosphere

    Science.gov (United States)

    Sorriso-Valvo, Luca; Carbone, Francesco; Perri, Silvia; Greco, Antonella; Marino, Raffaele; Bruno, Roberto

    2018-01-01

    The transfer of energy from large to small scales in solar wind turbulence is an important ingredient of the long-standing question of the mechanism of the interplanetary plasma heating. Previous studies have shown that magnetohydrodynamic (MHD) turbulence is statistically compatible with the observed solar wind heating as it expands in the heliosphere. However, in order to understand which processes contribute to the plasma heating, it is necessary to have a local description of the energy flux across scales. To this aim, it is customary to use indicators such as the magnetic field partial variance of increments (PVI), which is associated with the local, relative, scale-dependent magnetic energy. A more complete evaluation of the energy transfer should also include other terms, related to velocity and cross-helicity. This is achieved here by introducing a proxy for the local, scale-dependent turbulent energy transfer rate ɛ_{Δ t}(t), based on the third-order moment scaling law for MHD turbulence. Data from Helios 2 are used to determine the statistical properties of such a proxy in comparison with the magnetic and velocity fields PVI, and the correlation with local solar wind heating is computed. PVI and ɛ_{Δ t}(t) are generally well correlated; however, ɛ_{Δ t}(t) is a very sensitive proxy that can exhibit large amplitude values, both positive and negative, even for low amplitude peaks in the PVI. Furthermore, ɛ_{Δ t}(t) is very well correlated with local increases of the temperature when large amplitude bursts of energy transfer are localized, thus suggesting an important role played by this proxy in the study of plasma energy dissipation.

  5. Anomalous resonance-radiation energy-transfer rate in a scattering dispersive medium

    International Nuclear Information System (INIS)

    Shekhtman, V.L.

    1992-01-01

    This paper describes a generalization of the concept of group velocity as an energy-transfer rate in a dispersive medium with complex refractive index when the polaritons, which are energy carriers, undergo scattering, in contrast to the classical concept of the group velocity of free polaritons (i.e., without scattering in the medium). The concept of delay time from quantum multichannel-scattering, theory is used as the fundamental concept. Based on Maxwell's equations and the new mathematical Φ-function method, a consistent conceptual definition of group velocity in terms of the ratio of the coherent-energy flux density to the coherent-energy density is obtained for the first time, and a critical analysis of the earlier (Brillouin) understanding of energy-transfer rate is given in the light of radiation-trapping theory and the quantum theory of resonance scattering. The role of generalized group velocity is examined for the interpretation of the phenomenon of multiple resonance scattering, or radiation diffusion. The question of causality for the given problem is touched upon; a new relationship is obtained, called the microcausality condition, which limits the anomalous values of group velocity by way of the indeterminacy principle and the relativistic causality principle for macroscopic time intervals directly measurable in experiment, whereby attention is focused on the connection of the given microcausality condition and the well-known Wigner inequality for the time delay of spherical waves. 22 refs

  6. Free energy correlation of rate constants for electron transfer between organic systems in aqueous solutions

    Energy Technology Data Exchange (ETDEWEB)

    Meisel, D

    1975-07-15

    Recent experimental data concerning the rate constants for electron transfer reactions of organic systems in aqueous solutions and their equilibrium constants is examined for possible correlation. The data is correlated quite well by the Marcus theory, if a reorganization parameter, lambda, of 18 kcal/mole is used. Assuming that the only contribution to lambda is the free energy of rearrangement of the water molecules, an effective radius of 5 A for the reacting entities is estimated. For the zero free energy change reaction, i.e., electron exchange between a radical ion and its parent molecule, a rate constant of about 5 X 10/sup 7/ M/sup -1/ s/sup -1/ is predicted. (auth)

  7. Rate for energy transfer from excited cyclohexane to nitrous oxide in the liquid phase

    International Nuclear Information System (INIS)

    Wada, T.; Hatano, Y.

    1975-01-01

    Pure liquid cyclohexane and cyclohexane solutions of nitrous oxide have been photolyzed at 163 nm. The quantum yield of the product hydrogen in the photolysis of pure cyclohexane is found to be 1.0. The addition of nitrous oxide results in the reduction in the yield of hydrogen and in the formation of nitrogen. The decrement of the hydrogen yield is approximately equal to the increment of the nitrogen yield. About 40 percent of the hydrogen yield in pure cyclohexane is found to be produced through a path which is not affected by the addition of nitrous oxide. The effect of the addition of nitrous oxide is attributed to energy transfer from excited cyclohexane to nitrous oxide with the rate constant of k = 1.0 x 10 11 M -1 sec -1 (at 15 0 C). This value is about a factor of 10 larger than that expected as for diffusion-controlled rate. A contribution of the energy transfer process to the formation of nitrogen in the radiolysis of cyclohexane solutions of nitrous oxide has also been discussed. (auth)

  8. Reaction Coordinate, Free Energy, and Rate of Intramolecular Proton Transfer in Human Carbonic Anhydrase II.

    Science.gov (United States)

    Paul, Sanjib; Paul, Tanmoy Kumar; Taraphder, Srabani

    2018-03-22

    The role of structure and dynamics of an enzyme has been investigated at three different stages of its function including the chemical event it catalyzes. A one-pot computational method has been designed for each of these stages on the basis of classical and/or quantum mechanical-molecular mechanical molecular dynamics and transition path sampling simulations. For a pair of initial and final states A and B separated by a high free-energy barrier, using a two-stage selection process, several collective variables (CVs) are identified that can delineate A and B. However, these CVs are found to exhibit strong cross-coupling over the transition paths. A set of mutually orthogonal order parameters is then derived from these CVs and an optimal reaction coordinate, r, determined applying half-trajectory likelihood maximization along with a Bayesian information criterion. The transition paths are also used to project the multidimensional free energy surface and barrier crossing dynamics along r. The proposed scheme has been applied to the rate-determining intramolecular proton transfer reaction of the well-known enzyme human carbonic anhydrase II. The potential of mean force, F( r), in the absence of the chemical step is found to reproduce earlier results on the equilibrium population of two side-chain orientations of key residue His-64. Estimation of rate constants, k, from mean first passage times for the three different stages of catalysis shows that the rate-determining step of intramolecular proton transfer occurs with k ≃ 1.0 × 10 6 s -1 , in close agreement with known experimental results.

  9. Vibrational energy transfer in selectively excited diatomic molecules. [Relaxation rates, self-relaxation, upper limits

    Energy Technology Data Exchange (ETDEWEB)

    Dasch, C.J.

    1978-09-01

    Single rovibrational states of HCl(v=2), HBr(v=2), DCl(v=2), and CO(v=2) were excited with a pulsed optical parametric oscillator (OPO). Total vibrational relaxation rates near - resonance quenchers were measured at 295/sup 0/K using time resolved infrared fluorescence. These rates are attributed primarily to V - V energy transfer, and they generally conform to a simple energy gap law. A small deviation was found for the CO(v) + DCl(v') relaxation rates. Upper limits for the self relaxation by V - R,T of HCl(v=2) and HBr(v=2) and for the two quantum exchange between HCl and HBr were determined. The HF dimer was detected at 295/sup 0/K and 30 torr HF pressure with an optoacoustic spectrometer using the OPO. Pulsed and chopped, resonant and non-resonant spectrophones are analyzed in detail. From experiments and first order perturbation theory, these V - V exchange rates appear to behave as a first order perturbation in the vibrational coordinates. The rotational dynamics are known to be complicated however, and the coupled rotational - vibrational dynamics were investigated theoreticaly in infinite order by the Dillon and Stephenson and the first Magnus approximations. Large ..delta..J transitions appear to be important, but these calculations differ by orders of magnitude on specific rovibrational transition rates. Integration of the time dependent semiclassical equations by a modified Gordon method and a rotationally distorted wave approximation are discussed as methods which would treat the rotational motion more accurately. 225 references.

  10. Dexter energy transfer pathways.

    Science.gov (United States)

    Skourtis, Spiros S; Liu, Chaoren; Antoniou, Panayiotis; Virshup, Aaron M; Beratan, David N

    2016-07-19

    Energy transfer with an associated spin change of the donor and acceptor, Dexter energy transfer, is critically important in solar energy harvesting assemblies, damage protection schemes of photobiology, and organometallic opto-electronic materials. Dexter transfer between chemically linked donors and acceptors is bridge mediated, presenting an enticing analogy with bridge-mediated electron and hole transfer. However, Dexter coupling pathways must convey both an electron and a hole from donor to acceptor, and this adds considerable richness to the mediation process. We dissect the bridge-mediated Dexter coupling mechanisms and formulate a theory for triplet energy transfer coupling pathways. Virtual donor-acceptor charge-transfer exciton intermediates dominate at shorter distances or higher tunneling energy gaps, whereas virtual intermediates with an electron and a hole both on the bridge (virtual bridge excitons) dominate for longer distances or lower energy gaps. The effects of virtual bridge excitons were neglected in earlier treatments. The two-particle pathway framework developed here shows how Dexter energy-transfer rates depend on donor, bridge, and acceptor energetics, as well as on orbital symmetry and quantum interference among pathways.

  11. Theoretical and computational study of the energy dependence of the muon transfer rate from hydrogen to higher-Z gases

    Energy Technology Data Exchange (ETDEWEB)

    Bakalov, Dimitar, E-mail: dbakalov@inrne.bas.bg [Institute for Nuclear Research and Nuclear Energy, Bulgarian Academy of Sciences, Tsarigradsko chaussée 72, Sofia 1784 (Bulgaria); Adamczak, Andrzej [Institute of Nuclear Physics, Polish Academy of Sciences, ul. Radzikowskiego 152, 31-342 Krakow (Poland); Stoilov, Mihail [Institute for Nuclear Research and Nuclear Energy, Bulgarian Academy of Sciences, Tsarigradsko chaussée 72, Sofia 1784 (Bulgaria); Vacchi, Andrea [Istituto Nazionale di Fisica Nucleare, Sezione di Trieste, Via A. Valerio 2, 34127 Trieste (Italy)

    2015-01-23

    The recent PSI Lamb shift experiment and the controversy about proton size revived the interest in measuring the hyperfine splitting in muonic hydrogen as an alternative possibility for comparing ordinary and muonic hydrogen spectroscopy data on proton electromagnetic structure. This measurement critically depends on the energy dependence of the muon transfer rate to heavier gases in the epithermal range. The available data provide only qualitative information, and the theoretical predictions have not been verified. We propose a new method by measurements of the transfer rate in thermalized target at different temperatures, estimate its accuracy and investigate the optimal experimental conditions. - Highlights: • Method for measuring the energy dependence of muon transfer rate to higher-Z gases. • Thermalization and depolarization of muonic hydrogen studied by Monte Carlo method. • Optimal experimental conditions determined by Monte Carlo simulations. • Mathematical model and for estimating the uncertainty of the experimental results.

  12. Time averaging procedure for calculating the mass and energy transfer rates in adiabatic two phase flow

    International Nuclear Information System (INIS)

    Boccaccini, L.V.

    1986-07-01

    To take advantages of the semi-implicit computer models - to solve the two phase flow differential system - a proper averaging procedure is also needed for the source terms. In fact, in some cases, the correlations normally used for the source terms - not time averaged - fail using the theoretical time step that arises from the linear stability analysis used on the right handside. Such a time averaging procedure is developed with reference to the bubbly flow regime. Moreover, the concept of mass that must be exchanged to reach equilibrium from a non-equilibrium state is introduced to limit the mass transfer during a time step. Finally some practical calculations are performed to compare the different correlations for the average mass transfer rate developed in this work. (orig.) [de

  13. Electron transfer rates and energy releases during denitrification of municipal wastewater

    DEFF Research Database (Denmark)

    Abdul-Talib, S.; Ujang, Z; Vollertsen, J.

    2004-01-01

    could be simplified by a two-stage process. In the first stage, nitrate was utilised with significant accumulation of nitrite. In the second stage nitrite was utilised when nitrate depleted. Denitrification rates during the two stages were expressed in terms of electron equivalents (e-eq.) in order...... to compare the process when differennt electron acceptors namlely, nitrate and nitrite were utilised. The energy release rates during the two stages were calculated and compared....

  14. Pump--probe measurements of state-to-state rotational energy transfer rates in N2 (v=1)

    International Nuclear Information System (INIS)

    Sitz, G.O.; Farrow, R.L.

    1990-01-01

    We report direct measurements of the state-to-state rotational energy transfer rates for N 2 (υ=1) at 298 K. Stimulated Raman pumping of Q-branch (υ=1 left-arrow 0) transitions is used to prepare a selected rotational state of N 2 in the υ=1 state. After allowing an appropriate time interval for collisions to occur, 2+2 resonance-enhanced multiphoton ionization is used (through the a 1 Π g left-arrow X 1 Σ + g transition) to detect the relative population of the pumped level and other levels to which rotational energy transfer has occurred. We have performed a series of measurements in which a single even rotational level (J i =0--14) is excited and the time-dependent level populations are recorded at three or more delay times. This data set is then globally fit to determine the best set of state-to-state rate constants. The fitting procedure does not place any constraints (such as an exponential gap law) on the J or energy dependence of the rates. We compare our measurements and best-fit rates with results predicted from phenomenological rate models and from a semiclassical scattering calculation of Koszykowski et al. [J. Phys. Chem. 91, 41 (1987)]. Excellent agreement is obtained with two of the models and with the scattering calculation. We also test the validity of the energy-corrected sudden (ECS) scaling theory for N 2 by using our experimental transfer rates as basis rates (J=L→0), finding that the ECS scaling expressions accurately predict the remaining rates

  15. Influence of radiant energy exchange on the determination of convective heat transfer rates to Orbiter leeside surfaces during entry

    Science.gov (United States)

    Throckmorton, D. A.

    1982-01-01

    Temperatures measured at the aerodynamic surface of the Orbiter's thermal protection system (TPS), and calorimeter measurements, are used to determine heating rates to the TPS surface during atmospheric entry. On the Orbiter leeside, where convective heating rates are low, it is possible that a significant portion of the total energy input may result from solar radiation, and for the wing, cross radiation from the hot (relatively) Orbiter fuselage. In order to account for the potential impact of these sources, values of solar- and cross-radiation heat transfer are computed, based upon vehicle trajectory and attitude information and measured surface temperatures. Leeside heat-transfer data from the STS-2 mission are presented, and the significance of solar radiation and fuselage-to-wing cross-radiation contributions to total energy input to Orbiter leeside surfaces is assessed.

  16. Rapid vibrational and rotational energy-transfer rates in heated carbon dioxide collisions by double-resonance laser spectroscopy

    International Nuclear Information System (INIS)

    Thomason, M.D.

    1982-07-01

    Rates for resonant vibrational and rotational energy transfer from the 001 state by CO 2 + CO 2 collisions have been measured. All data were obtained by double resonance spectroscopy with CO 2 lasers in a 2.5 meter absorption cell at 700 0 K. Results for rotation transfer include pumped-level relaxation and the response of other 001 levels with ΔJ up to 18. These data are compared to four relevant collision models via a 35-level rate equation analysis. Sequence-band (002 → 101) and hot-band (011 → 110) lasting have been used to observe resonant nu 3 -transfer relaxation involving 001 + 001 reversible 002 + 000, 001 + 100 reversible 101 + 000, and 001 + 010 reversible 011 + 000. A multilevel rate analysis has been utilized to determine the rate coefficients for 001 going to the 002, the 101, and the 011 levels. Part of the hot-band data has been interpreted as due to 110 + 000 reversible 100 + 010, and the associated rate constant has been estimated. The results of the study are compared to the theory and to other experiments

  17. Forster resonance energy transfer rate in any dielectric nanophotonic medium with weak dispersion

    DEFF Research Database (Denmark)

    Wubs, Martijn; Vos, Willem L.

    2016-01-01

    frequency dependent in nanophotonic media. Therefore, the position-dependent FRET rate and the LDOS at the donor transition frequency are completely uncorrelated for any nondispersive medium. Secondly, we derive an exact expression for the FRET rate as a frequency integral of the imaginary part of the Green...

  18. Laser induced energy transfer

    International Nuclear Information System (INIS)

    Falcone, R.W.

    1979-01-01

    Two related methods of rapidly transferring stored energy from one excited chemical species to another are described. The first of these, called a laser induced collision, involves a reaction in which the energy balance is met by photons from an intense laser beam. A collision cross section of ca 10 - 17 cm 2 was induced in an experiment which demonstrated the predicted dependence of the cross section on wavelength and power density of the applied laser. A second type of laser induced energy transfer involves the inelastic scattering of laser radiation from energetically excited atoms, and subsequent absorption of the scattered light by a second species. The technique of producing the light, ''anti-Stokes Raman'' scattering of visible and infrared wavelength laser photons, is shown to be an efficient source of narrow bandwidth, high brightness, tunable radiation at vacuum ultraviolet wavelengths by using it to excite a rare gas transition at 583.7 A. In addition, this light source was used to make the first measurement of the isotopic shift of the helium metastable level at 601 A. Applications in laser controlled chemistry and spectroscopy, and proposals for new types of lasers using these two energy transfer methods are discussed

  19. Energy transfer properties and mechanisms

    International Nuclear Information System (INIS)

    1991-01-01

    This report discusses the energy transfer mechanisms in azulene, benzene, toluene, and isotopomers. Also discussed is the coupled energy reservoirs model, quantum effects in energy transfer, NO 2 energy transfer, densities of states, the reactant states model, and O 3 excited electronic states

  20. Energy transfer in plasmonic systems

    International Nuclear Information System (INIS)

    Pustovit, Vitaliy N; Urbas, Augustine M; Shahbazyan, Tigran V

    2014-01-01

    We present our results on energy transfer between donor and acceptor molecules or quantum dots near a plasmonic nanoparticle. In such systems, the Förster resonance energy transfer is strongly modified due to plasmon-mediated coupling between donors and acceptors. The transfer efficiency is determined by a competition between transfer, radiation and dissipation that depends sensitively on system parameters. When donor and accepror spectral bands overlap with dipole surface plasmon resonance, the dominant transfer mechanism is through plasmon-enhanced radiative coupling. When transfer takes place from an ensemble of donors to an acceptor, a cooperative amplification of energy transfer takes place in a wide range of system parameters. (paper)

  1. Intramolecular Energy Transfer, Charge Transfer & Hydrogen Bond

    Indian Academy of Sciences (India)

    Ultrafast Dynamics of Chemical Reactions in Condensed Phase: Intramolecular Energy Transfer, Charge Transfer & Hydrogen Bond · PowerPoint Presentation · Slide 3 · Slide 4 · Slide 5 · Slide 6 · Slide 7 · Slide 8 · Slide 9 · Slide 10 · Slide 11 · Slide 12 · Slide 13 · Slide 14 · Slide 15 · Slide 16 · Slide 17 · Slide 18 · Slide 19.

  2. Plasmonic energy transfer in periodically doped graphene

    International Nuclear Information System (INIS)

    Silveiro, I; Manjavacas, A; Thongrattanasiri, S; García de Abajo, F J

    2013-01-01

    We predict unprecedentedly large values of the energy-transfer rate between an optical emitter and a layer of periodically doped graphene. The transfer exhibits divergences at photon frequencies corresponding to the Van Hove singularities of the plasmonic band structure of the graphene. In particular, we find flat bands associated with regions of vanishing doping charge, which appear in graphene when it is patterned through gates of spatially alternating signs, giving rise to intense transfer rate singularities. Graphene is thus shown to provide a unique platform for fast control of optical energy transfer via fast electrostatic inhomogeneous doping. (paper)

  3. Energy transfer properties and mechanisms

    International Nuclear Information System (INIS)

    Barker, J.R.

    1993-01-01

    Since no single experimental technique is the best method for energy transfer experiments, we have used both time-dependent infrared fluorescence (IRF) and time-dependent thermal lensing (TDTL) to study energy transfer in various systems. We are investigating pump-probe techniques employing resonance enhanced multiphoton ionization (REMPI). IRF was used to study benzene, azulene, and toluene. TDTL was used to study CS 2 and SO 2 (data not given for latter). Large molecule energy transfer mechanisms are discussed. 10 figs

  4. Resonance energy transfer: Dye to metal nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Wari, M. N.; Pujar, G. H.; Inamdar, S. R., E-mail: him-lax3@yahoo.com [Laser Spectroscopy Programme, Department of Physics, Karnatak University, Dharwad-580003 (India)

    2015-06-24

    In the present study, surface energy transfer (SET) from Coumarin 540A (C540 A) to Gold nanoparticle (Au) is demonstrated. The observed results show pronounced effect on the photoluminescence intensity and shortening of the lifetime of Coumarin 540A upon interaction with the spherical gold nanoparticle, also there are measured effects on radiative rate of the dye. Experimental results are analyzed with fluorescence resonance energy transfer (FRET) and SET theories. The results obtained from distance-dependent quenching provide experimental evidence that the efficiency curve slope and distance of quenching is best modeled by surface energy transfer process.

  5. Effects of energy, distance and orientation on electron transfer rates studied by pulse radiolysis in organic media

    International Nuclear Information System (INIS)

    Miller, J.R.

    1987-01-01

    In the past few years the methods of radiation chemistry in organic media have made an enormous change in how we view electron transfer processes, as these media have proved the most useful for studying long distance electron transfer between molecules. This paper briefly summarizes a few of the aspects of this area and discusses some of the attributes and limitations of radiation tehniques, particularly pulse radiolysis, in organic solvents. 14 refs., 2 figs

  6. Energy Transfer Kinetics and Dynamics of Relevance to Iodine Lasers

    National Research Council Canada - National Science Library

    Heaven, Michael C

    2001-01-01

    ...). Energy transfer between I(2 P(1/2)) and 02(X) has been studied in detail. Rate constants for electronic energy transfer and nuclear spin relaxation were measured over the temperature range from 150-300K...

  7. Stray energy transfer during endoscopy.

    Science.gov (United States)

    Jones, Edward L; Madani, Amin; Overbey, Douglas M; Kiourti, Asimina; Bojja-Venkatakrishnan, Satheesh; Mikami, Dean J; Hazey, Jeffrey W; Arcomano, Todd R; Robinson, Thomas N

    2017-10-01

    Endoscopy is the standard tool for the evaluation and treatment of gastrointestinal disorders. While the risk of complication is low, the use of energy devices can increase complications by 100-fold. The mechanism of increased injury and presence of stray energy is unknown. The purpose of the study was to determine if stray energy transfer occurs during endoscopy and if so, to define strategies to minimize the risk of energy complications. A gastroscope was introduced into the stomach of an anesthetized pig. A monopolar generator delivered energy for 5 s to a snare without contacting tissue or the endoscope itself. The endoscope tip orientation, energy device type, power level, energy mode, and generator type were varied to mimic in vivo use. The primary outcome (stray current) was quantified as the change in tissue temperature (°C) from baseline at the tissue closest to the tip of the endoscope. Data were reported as mean ± standard deviation. Using the 60 W coag mode while changing the orientation of the endoscope tip, tissue temperature increased by 12.1 ± 3.5 °C nearest the camera lens (p energy transfer (p = 0.04 and p = 0.002, respectively) as did utilizing the low-voltage cut mode (6.6 ± 0.5 °C, p energy transfer compared to a standard generator (1.5 ± 3.5 °C vs. 9.5 ± 0.8 °C, p energy is transferred within the endoscope during the activation of common energy devices. This could result in post-polypectomy syndrome, bleeding, or perforation outside of the endoscopist's view. Decreasing the power, utilizing low-voltage modes and/or an impedance-monitoring generator can decrease the risk of complication.

  8. Pumped energy transfer stations (STEP)

    International Nuclear Information System (INIS)

    Tournery, Jean-Francois

    2015-12-01

    As objectives of development are high for renewable energies (they are supposed to cover 50 per cent of new energy needs by 2035), pumped energy transfer stations are to play an important role in this respect. The author first discusses the consequences of the development of renewable energies on the exploitation of electric grids: issue of intermittency for some of them, envisaged solutions. Then, he addresses one of the solutions: the storage of electric power. He notices that increasing the potential energy of a volume of water is presently the most mature solution to face massive needs of the power system. Dams and pumped energy transfer stations represent now almost the whole installed storage power in the world. The author then presents these pumped energy transfer stations: principle, brief history (the first appeared in Italy and Switzerland at the end of the 1890's). He indicates the various parameters of assessment of such stations: maximum stored energy, installed power in pumping mode and turbine mode, time constant, efficiency, level of flexibility. He discusses economic issues. He describes and comments the operation of turbine-pump groups: ternary groups, reversible binary groups. He discusses barriers to be overcome and technical advances to be made for varying speed groups and for marine stations. He finally gives an overview (table with number of stations belonging to different power ranges, remarkable installations) of existing stations in China, USA, Japan, Germany, Austria, Spain, Portugal, Italy, Switzerland, France and UK, and indicate predictions regarding storage needs at the world level. Some data are finally indicated for the six existing French installations

  9. Effects of the Distributions of Energy or Charge Transfer Rates on Spectral Hole Burning in Pigment-Protein Complexes at Low Temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Herascu, N.; Ahmouda, S.; Picorel, R.; Seibert, M.; Jankowiak, R.; Zazubovich, V.

    2011-12-22

    Effects of the distributions of excitation energy transfer (EET) rates (homogeneous line widths) on the nonphotochemical (resonant) spectral hole burning (SHB) processes in photosynthetic chlorophyll-protein complexes (reaction center [RC] and CP43 antenna of Photosystem II from spinach) are considered. It is demonstrated that inclusion of such a distribution results in somewhat more dispersive hole burning kinetics. More importantly, however, inclusion of the EET rate distributions strongly affects the dependence of the hole width on the fractional hole depth. Different types of line width distributions have been explored, including those resulting from Foerster type EET between weakly interacting pigments as well as Gaussian ones, which may be a reasonable approximation for those resulting, for instance, from so-called extended Foerster models. For Gaussian line width distributions, it is possible to determine the parameters of both line width and tunneling parameter distributions from SHB data without a priori knowledge of any of them. Concerning more realistic asymmetric distributions, we demonstrate, using the simple example of CP43 antenna, that one can use SHB modeling to estimate electrostatic couplings between pigments and support or exclude assignment of certain pigment(s) to a particular state.

  10. On the use of analytical approximate expressions for the transfer rate in excitation transfer kinetics

    International Nuclear Information System (INIS)

    Kusba, J.; Sipp, B.

    1985-01-01

    We present a discussion about the range of validity of the usual approximate transfer rate expressions used in the description of the kinetics of diffusion-modulated excitation transfer, for a reactive interaction of exponential functional form. We simulate the features of energy transfer by a numerical inversion of the exact Laplace transform of the transfer rate. It is shown that for high diffusion coefficients of the order of 10 -5 cm 2 s -1 , the kinetics may be well reproduced, even at short times, by the asymptotic form of the transfer rate. For slow molecular displacements, the short time static regime is brought to direct observation, but the transfer rate approaches is asymptotic value at a much later time

  11. Multistate cohort models with proportional transfer rates

    DEFF Research Database (Denmark)

    Schoen, Robert; Canudas-Romo, Vladimir

    2006-01-01

    of transfer rates. The two living state case and hierarchical multistate models with any number of living states are analyzed in detail. Applying our approach to 1997 U.S. fertility data, we find that observed rates of parity progression are roughly proportional over age. Our proportional transfer rate...... approach provides trajectories by parity state and facilitates analyses of the implications of changes in parity rate levels and patterns. More women complete childbearing at parity 2 than at any other parity, and parity 2 would be the modal parity in models with total fertility rates (TFRs) of 1.40 to 2......We present a new, broadly applicable approach to summarizing the behavior of a cohort as it moves through a variety of statuses (or states). The approach is based on the assumption that all rates of transfer maintain a constant ratio to one another over age. We present closed-form expressions...

  12. Intergenerational transfers and the social discount rate

    International Nuclear Information System (INIS)

    Howarth, R.B.; Norgaard, R.B.

    1992-08-01

    This paper investigates the relationship between intergenerational asset transfers and the choice of the discount rate for use in cost-benefit analysis in a model of a competitive overlapping generations economy constrained by a socially managed exhaustible resource. Provided that there are no distortions in capital markets and that all agents hold perfect foresight, cost-benefit techniques will result in a Pareto efficient resource allocation if the discount rate is set equal to the market rate of interest. But since the path of the interest rate depends on the level of intergenerational transfers, cost-benefit techniques do not ensure a socially desirable distribution of welfare between generations; a social optimum will result only if intergenerational transfers are properly chosen and enforced. Decentralized private altruism may result in intergenerational transfers that both present and future individuals would agree are too small if members of the present generation attach positive weight to the general welfare of future generations, not simply their personal descendants. In a world where intergenerational transfers are non-optimal, second-best policy-making may imply a constrained optimum that is inefficient. Together, these findings suggest that cost-benefit analysis is at best a partial criterion to policy formulation that should be used only in conjunction with ethical principles that define the proper distribution of welfare between present and future generations

  13. Risk transfer via energy-savings insurance

    International Nuclear Information System (INIS)

    Mills, Evan

    2003-01-01

    Among the key barriers to investment in energy efficiency are uncertainties about attaining projected energy savings and potential disputes over stipulated savings. The fields of energy management and risk management are thus intertwined. While many technical methods have emerged to manage performance risks (e.g. building diagnostics and commissioning), financial methods are less developed in the energy management arena than in other segments of the economy. Energy-savings insurance (ESI) - formal insurance of predicted energy savings - transfers and spreads both types of risk over a larger pool of energy efficiency projects and reduces barriers to market entry of smaller energy service firms who lack sufficiently strong balance sheets to self-insure the savings. ESI encourages those implementing energy-saving projects to go beyond standard measures and thereby achieve more significant levels of energy savings. Insurance providers are proponents of improved savings measurement and verification techniques, as well as maintenance, thereby contributing to national energy-saving objectives. If properly applied, ESI can potentially reduce the net cost of energy-saving projects by reducing the interest rates charged by lenders, and by increasing the level of savings through quality control. Governmental agencies have been pioneers in the use of ESI and could continue to play a role

  14. Integrated light in direct excitation and energy transfer luminescence

    OpenAIRE

    Chimczak, Eugeniusz

    2007-01-01

    Integrated light in direct excitation and energy transfer luminescence has been investigated. In the investigations reported here, monomolecular centers were taken into account. It was found that the integrated light is equal to the product of generation rate and time of duration of excitation pulse for both direct excitation and energy transfer luminescence.

  15. Mode-to-mode energy transfers in convective patterns

    Indian Academy of Sciences (India)

    Abstract. We investigate the energy transfer between various Fourier modes in a low- dimensional model for thermal convection. We have used the formalism of mode-to-mode energy transfer rate in our calculation. The evolution equations derived using this scheme is the same as those derived using the hydrodynamical ...

  16. Energy transfer and kinetics in mechanochemistry.

    Science.gov (United States)

    Chen, Zhiliang; Lu, Shengyong; Mao, Qiongjing; Buekens, Alfons; Wang, Yuting; Yan, Jianhua

    2017-11-01

    Mechanochemistry (MC) exerts extraordinary degradation and decomposition effects on many chlorinated, brominated, and even fluorinated persistent organic pollutants (POPs). However, its application is still limited by inadequate study of its reaction kinetic aspects. In the present work, the ball motion and energy transfer in planetary ball mill are investigated in some detail. Almost all milling parameters are summarised in a single factor-total effective impact energy. Furthermore, the MC kinetic between calcium oxide/Al and hexachlorobenzene is well established and modelled. The results indicate that total effective impact energy and reagent ratio are the two factors sufficient for describing the MC degradation degree of POPs. The reaction rate constant only depends on the chemical properties of reactants, so it could be used as an important index to appraise the quality of MC additives. This model successfully predicts the reaction rate for different operating conditions, indicating that it could be suitably applied for conducting MC reactions in other reactors.

  17. Risk transfer via energy savings insurance

    Energy Technology Data Exchange (ETDEWEB)

    Mills, Evan

    2001-10-01

    Among the key barriers to investment in energy efficiency improvements are uncertainties about attaining projected energy savings and apprehension about potential disputes over these savings. The fields of energy management and risk management are thus intertwined. While many technical methods have emerged to manage performance risks (e.g. building commissioning), financial risk transfer techniques are less developed in the energy management arena than in other more mature segments of the economy. Energy Savings Insurance (ESI) - formal insurance of predicted energy savings - is one method of transferring financial risks away from the facility owner or energy services contractor. ESI offers a number of significant advantages over other forms of financial risk transfer, e.g. savings guarantees or performance bonds. ESI providers manage risk via pre-construction design review as well as post-construction commissioning and measurement and verification of savings. We found that the two mos t common criticisms of ESI - excessive pricing and onerous exclusions - are not born out in practice. In fact, if properly applied, ESI can potentially reduce the net cost of energy savings projects by reducing the interest rates charged by lenders, and by increasing the level of savings through quality control. Debt service can also be ensured by matching loan payments to projected energy savings while designing the insurance mechanism so that payments are made by the insurer in the event of a savings shortfall. We estimate the U.S. ESI market potential of $875 million/year in premium income. From an energy-policy perspective, ESI offers a number of potential benefits: ESI transfers performance risk from the balance sheet of the entity implementing the energy savings project, thereby freeing up capital otherwise needed to ''self-insure'' the savings. ESI reduces barriers to market entry of smaller energy services firms who do not have sufficiently strong balance

  18. Risk transfer via energy savings insurance; TOPICAL

    International Nuclear Information System (INIS)

    Mills, Evan

    2001-01-01

    Among the key barriers to investment in energy efficiency improvements are uncertainties about attaining projected energy savings and apprehension about potential disputes over these savings. The fields of energy management and risk management are thus intertwined. While many technical methods have emerged to manage performance risks (e.g. building commissioning), financial risk transfer techniques are less developed in the energy management arena than in other more mature segments of the economy. Energy Savings Insurance (ESI) - formal insurance of predicted energy savings - is one method of transferring financial risks away from the facility owner or energy services contractor. ESI offers a number of significant advantages over other forms of financial risk transfer, e.g. savings guarantees or performance bonds. ESI providers manage risk via pre-construction design review as well as post-construction commissioning and measurement and verification of savings. We found that the two mos t common criticisms of ESI - excessive pricing and onerous exclusions - are not born out in practice. In fact, if properly applied, ESI can potentially reduce the net cost of energy savings projects by reducing the interest rates charged by lenders, and by increasing the level of savings through quality control. Debt service can also be ensured by matching loan payments to projected energy savings while designing the insurance mechanism so that payments are made by the insurer in the event of a savings shortfall. We estimate the U.S. ESI market potential of$875 million/year in premium income. From an energy-policy perspective, ESI offers a number of potential benefits: ESI transfers performance risk from the balance sheet of the entity implementing the energy savings project, thereby freeing up capital otherwise needed to ''self-insure'' the savings. ESI reduces barriers to market entry of smaller energy services firms who do not have sufficiently strong balance sheets to self

  19. Electromechanical capacitor for energy transfer

    International Nuclear Information System (INIS)

    Carroll, T.A.; Chowdhuri, P.; Marshall, J.

    1983-01-01

    Inductive energy transfer between two magnets can be achieved with almost 100% efficiency with a transfer capacitor. However, the bulk and cost will be high, and reliability low if conventional capacitors are used. A homopolar machine, used as a capacitor, will be compact and economical. A homopolar machine was designed with counter-rotating copper disks completely immersed in a liquid metal (NaK-78) to work as a pulse capacitor. Absence of solid-brush collectors minimized wear and frictional losses. Wetting of the copper disks throughout the periphery by the liquid metal minimized the resistive losses at the collector interface. A liquid-metal collector would, however, introduce hydrodynamic and magnetohydrodynamic losses. The selected liquid metal, e.g., NaK-78 will produce the lowest of such losses among the available liquid metals. An electromechanical capacitor of this design was tested at various dc magnetic fields. Its measured capacitance was about 100 farads at a dc magnetic field of 1.15 tesla

  20. Comparison of the rate constants for energy transfer in the light-harvesting protein, C-phycocyanin, calculated from Foerster`s theory and experimentally measured by time-resolved fluorescence spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Debreczeny, Martin Paul [Univ. of California, Berkeley, CA (United States)

    1994-05-01

    We have measured and assigned rate constants for energy transfer between chromophores in the light-harvesting protein C-phycocyanin (PC), in the monomeric and trimeric aggregation states, isolated from Synechococcus sp. PCC 7002. In order to compare the measured rate constants with those predicted by Fdrster`s theory of inductive resonance in the weak coupling limit, we have experimentally resolved several properties of the three chromophore types ({beta}{sub 155} {alpha}{sub 84}, {beta}{sub 84}) found in PC monomers, including absorption and fluorescence spectra, extinction coefficients, fluorescence quantum yields, and fluorescence lifetimes. The cpcB/C155S mutant, whose PC is missing the {beta}{sub 155} chromophore, was, useful in effecting the resolution of the chromophore properties and in assigning the experimentally observed rate constants for energy transfer to specific pathways.

  1. Standard Test Method for Measuring Extreme Heat-Transfer Rates from High-Energy Environments Using a Transient, Null-Point Calorimeter

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2008-01-01

    1.1 This test method covers the measurement of the heat-transfer rate or the heat flux to the surface of a solid body (test sample) using the measured transient temperature rise of a thermocouple located at the null point of a calorimeter that is installed in the body and is configured to simulate a semi-infinite solid. By definition the null point is a unique position on the axial centerline of a disturbed body which experiences the same transient temperature history as that on the surface of a solid body in the absence of the physical disturbance (hole) for the same heat-flux input. 1.2 Null-point calorimeters have been used to measure high convective or radiant heat-transfer rates to bodies immersed in both flowing and static environments of air, nitrogen, carbon dioxide, helium, hydrogen, and mixtures of these and other gases. Flow velocities have ranged from zero (static) through subsonic to hypersonic, total flow enthalpies from 1.16 to greater than 4.65 × 101 MJ/kg (5 × 102 to greater than 2 × 104 ...

  2. Transfer of energy in an atom

    International Nuclear Information System (INIS)

    Chemin, J.F.

    2001-01-01

    In most cases the nucleus does not interact with the electron cloud because its energy range is far higher, but in some rare cases electrons from the electron cloud and the nucleus may exchange energy: an electron may de-excite by transferring a part of its energy to the nucleus that becomes itself excited (nuclear excitation by electronic transfer or NEET), conversely electrons can receive energy from the nucleus (bound internal conversion or BIC). For the first time both energy transfers have been observed: a BIC process on a tellurium-125 atom by a French team and a NEET process on a gold-197 atom by a Japanese team. (A.C.)

  3. Energy transfer mechanism between manganese and neodymium

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, R [Department of Physics, Government Raza Post-Graduate College, Rampur 244901, U.P., India

    1977-01-01

    The mechanism of energy transfer between Mn/sup 2 +/ ..-->.. Nd/sup 3 +/ in barium borate glass has been investigated. The change in emission intensities and lifetimes of Mn/sup 2 +/ (donor) due to the presence of Nd/sup 3 +/ (acceptor) are observed. It has been concluded that the mechanism of energy transfer involves a nonradiative resonance process. The electrostatic multiple interaction responsible for the transfer is dipole-dipole in nature.

  4. Interactive Joint Transfer of Energy and Information

    DEFF Research Database (Denmark)

    Popovski, Petar; Fouladgar, A. M.; Simeone, Osvaldo

    2013-01-01

    In some communication networks, such as passive RFID systems, the energy used to transfer information between a sender and a recipient can be reused for successive communication tasks. In fact, from known results in physics, any system that exchanges information via the transfer of given physical...... key design insights. Index Terms— Two-way channel, interactive communication, energy transfer, energy harvesting....... resources, such as radio waves, particles and qubits, can conceivably reuse, at least part, of the received resources. This paper aims at illustrating some of the new challenges that arise in the design of communication networks in which the signals exchanged by the nodes carry both information and energy...

  5. Energy-transfer properties and mechanisms:

    International Nuclear Information System (INIS)

    Barker, J.R.

    1988-02-01

    This project continues the research on vibrational energy transfer involving large molecules. The motivation of the research is to advance knowledge concerning molecular energy in the electronic ground state so that meaningful predictions can be made. The experimental program will use several techniques on several different molecules with the aim of eliminating experimental artifacts and gaining more insight into energy transfer processes. The theoretical effort will be directed toward assessing the validity of the Biased Random Walk theory and toward developing simpler models that adequately describe the energy transfer process. 6 figs

  6. Energy transfer during the hydroentanglement of fibres

    CSIR Research Space (South Africa)

    Moyo, D

    2012-10-01

    Full Text Available .kashan.co.za] ABSTRACT The hydroentanglement of fibres is achieved by the energy of the high-velocity waterjets. This method is highly energy intensive and costly, hence the attempt to study the energy transfer during the process. Generally, the amount of energy used... in the nonwoven fabric strength were studied. In the study, the energies of the waterjets transferred to every fabric sample as a function of the waterjet pressure, machine speed, machine efficiency and the web area weight were quantified, and the resultant...

  7. Targeting Low-Energy Ballistic Lunar Transfers

    Science.gov (United States)

    Parker, Jeffrey S.

    2010-01-01

    Numerous low-energy ballistic transfers exist between the Earth and Moon that require less fuel than conventional transfers, but require three or more months of transfer time. An entirely ballistic lunar transfer departs the Earth from a particular declination at some time in order to arrive at the Moon at a given time along a desirable approach. Maneuvers may be added to the trajectory in order to adjust the Earth departure to meet mission requirements. In this paper, we characterize the (Delta)V cost required to adjust a low-energy ballistic lunar transfer such that a spacecraft may depart the Earth at a desirable declination, e.g., 28.5(white bullet), on a designated date. This study identifies the optimal locations to place one or two maneuvers along a transfer to minimize the (Delta)V cost of the transfer. One practical application of this study is to characterize the launch period for a mission that aims to launch from a particular launch site, such as Cape Canaveral, Florida, and arrive at a particular orbit at the Moon on a given date using a three-month low-energy transfer.

  8. Risk transfer via energy savings insurance

    OpenAIRE

    Mills, Evan

    2001-01-01

    Among the key barriers to investment in energy efficiency improvements are uncertainties about attaining projected energy savings and apprehension about potential disputes over these savings. The fields of energy management and risk management are thus intertwined. While many technical methods have emerged to manage performance risks (e.g. building commissioning), financial risk transfer techniques are less developed in the energy management arena than in other more mature segments of t...

  9. Wireless energy transfer between anisotropic metamaterials shells

    Energy Technology Data Exchange (ETDEWEB)

    Díaz-Rubio, Ana; Carbonell, Jorge; Sánchez-Dehesa, José, E-mail: jsdehesa@upv.es

    2014-06-15

    The behavior of strongly coupled Radial Photonic Crystals shells is investigated as a potential alternative to transfer electromagnetic energy wirelessly. These sub-wavelength resonant microstructures, which are based on anisotropic metamaterials, can produce efficient coupling phenomena due to their high quality factor. A configuration of selected constitutive parameters (permittivity and permeability) is analyzed in terms of its resonant characteristics. The coupling to loss ratio between two coupled resonators is calculated as a function of distance, the maximum (in excess of 300) is obtained when the shells are separated by three times their radius. Under practical conditions an 83% of maximum power transfer has been also estimated. -- Highlights: •Anisotropic metamaterial shells exhibit high quality factors and sub-wavelength size. •Exchange of electromagnetic energy between shells with high efficiency is analyzed. •Strong coupling is supported with high wireless transfer efficiency. •End-to-end energy transfer efficiencies higher than 83% can be predicted.

  10. Wireless energy transfer between anisotropic metamaterials shells

    International Nuclear Information System (INIS)

    Díaz-Rubio, Ana; Carbonell, Jorge; Sánchez-Dehesa, José

    2014-01-01

    The behavior of strongly coupled Radial Photonic Crystals shells is investigated as a potential alternative to transfer electromagnetic energy wirelessly. These sub-wavelength resonant microstructures, which are based on anisotropic metamaterials, can produce efficient coupling phenomena due to their high quality factor. A configuration of selected constitutive parameters (permittivity and permeability) is analyzed in terms of its resonant characteristics. The coupling to loss ratio between two coupled resonators is calculated as a function of distance, the maximum (in excess of 300) is obtained when the shells are separated by three times their radius. Under practical conditions an 83% of maximum power transfer has been also estimated. -- Highlights: •Anisotropic metamaterial shells exhibit high quality factors and sub-wavelength size. •Exchange of electromagnetic energy between shells with high efficiency is analyzed. •Strong coupling is supported with high wireless transfer efficiency. •End-to-end energy transfer efficiencies higher than 83% can be predicted

  11. Quantum electrodynamics of resonant energy transfer in condensed matter

    International Nuclear Information System (INIS)

    Juzeliunas, G.; Andrews, D.L.

    1994-01-01

    A microscopic many-body QED theory for dipole-dipole resonance energy transfer has been developed from first principles. A distinctive feature of the theory is full incorporation of the dielectric effects of the supporting medium. The approach employs the concept of bath polaritons mediating the energy transfer. The transfer rate is derived in terms of the Green's operator corresponding to the polariton matrix Hamiltonian. In contrast to the more common lossless polariton models, the present theory accommodates an arbitrary number of energy levels for each molecule of the medium. This includes, a case of special interest, where the excitation energy spectrum of the bath molecules is sufficiently dense that it can be treated as a quasicontinuum in the energy region in question, as in the condensed phase normally results from homogeneous and inhomogeneous line broadening. In such a situation, the photon ''dressed'' by the medium polarization (the polariton) acquires a finite lifetime, the role of the dissipative subsystem being played by bath molecules. It is this which leads to the appearance of the exponential decay factor in the microscopically derived pair transfer rates. Accordingly, the problem associated with potentially infinite total ensemble rates, due to the divergent R -2 contribution, is solved from first principles. In addition, the medium modifies the distance dependence of the energy transfer function A(R) and also produces extra modifications due to screening contributions and local field effects. The formalism addresses cases where the surrounding medium is either absorbing or lossless over the range of energies transferred. In the latter case the exponential factor does not appear and the dielectric medium effect in the near zone reduces to that which is familiar from the theory of radiationless (Foerster) energy transfer

  12. Energy transfer in turbulence under rotation

    Science.gov (United States)

    Buzzicotti, Michele; Aluie, Hussein; Biferale, Luca; Linkmann, Moritz

    2018-03-01

    It is known that rapidly rotating turbulent flows are characterized by the emergence of simultaneous upscale and downscale energy transfer. Indeed, both numerics and experiments show the formation of large-scale anisotropic vortices together with the development of small-scale dissipative structures. However the organization of interactions leading to this complex dynamics remains unclear. Two different mechanisms are known to be able to transfer energy upscale in a turbulent flow. The first is characterized by two-dimensional interactions among triads lying on the two-dimensional, three-component (2D3C)/slow manifold, namely on the Fourier plane perpendicular to the rotation axis. The second mechanism is three-dimensional and consists of interactions between triads with the same sign of helicity (homochiral). Here, we present a detailed numerical study of rotating flows using a suite of high-Reynolds-number direct numerical simulations (DNS) within different parameter regimes to analyze both upscale and downscale cascade ranges. We find that the upscale cascade at wave numbers close to the forcing scale is generated by increasingly dominant homochiral interactions which couple the three-dimensional bulk and the 2D3C plane. This coupling produces an accumulation of energy in the 2D3C plane, which then transfers energy to smaller wave numbers thanks to the two-dimensional mechanism. In the forward cascade range, we find that the energy transfer is dominated by heterochiral triads and is dominated primarily by interaction within the fast manifold where kz≠0 . We further analyze the energy transfer in different regions in the real-space domain. In particular, we distinguish high-strain from high-vorticity regions and we uncover that while the mean transfer is produced inside regions of strain, the rare but extreme events of energy transfer occur primarily inside the large-scale column vortices.

  13. Energy reviews: the expense rate

    International Nuclear Information System (INIS)

    Chavanne, X.; Frangi, J.P.

    2008-01-01

    The threats against energy supplies push the prices of energy increasingly and lasting/ higher. Therefore it is important to establish the energy balance of an energy industry, which is more accurate than a too global financial balance. Life Cycle Analyses could be finely tuned using a method and tool suggested here: the T expense rate, the ratio between dissipated or spent energies, and extracted energy. T is a profitability indicator based on thermodynamics principles with 1 or 100 % as a theoretical limit. T is convenient too, because it can be broken down between the various steps or processes, and their D expenses. T also allows for a finely tuned analysis, to identify physical and technical parameters impacting the balance sheet. Uncertainties and arbitrary assumptions are explained, after having been boiled down to a minimum amount. A comparison between industries is thus possible for a given use (transportation, electrical production) depending on the form of energy extracted and the processes used. The energy balance is supplemented by the resource availability balance, different from the first one, even though availability may depend on it. (authors)

  14. Optical Energy Transfer and Conversion System

    Science.gov (United States)

    Hogan, Bartholomew P. (Inventor); Stone, William C. (Inventor)

    2018-01-01

    An optical energy transfer and conversion system comprising a fiber spooler and an electrical power extraction subsystem connected to the spooler with an optical waveguide. Optical energy is generated at and transferred from a base station through fiber wrapped around the spooler, and ultimately to the power extraction system at a remote mobility platform for conversion to another form of energy. The fiber spooler may reside on the remote mobility platform which may be a vehicle, or apparatus that is either self-propelled or is carried by a secondary mobility platform either on land, under the sea, in the air or in space.

  15. Production and transfer of energy and information in Hamiltonian systems.

    Directory of Open Access Journals (Sweden)

    Chris G Antonopoulos

    Full Text Available We present novel results that relate energy and information transfer with sensitivity to initial conditions in chaotic multi-dimensional Hamiltonian systems. We show the relation among Kolmogorov-Sinai entropy, Lyapunov exponents, and upper bounds for the Mutual Information Rate calculated in the Hamiltonian phase space and on bi-dimensional subspaces. Our main result is that the net amount of transfer from kinetic to potential energy per unit of time is a power-law of the upper bound for the Mutual Information Rate between kinetic and potential energies, and also a power-law of the Kolmogorov-Sinai entropy. Therefore, transfer of energy is related with both transfer and production of information. However, the power-law nature of this relation means that a small increment of energy transferred leads to a relatively much larger increase of the information exchanged. Then, we propose an "experimental" implementation of a 1-dimensional communication channel based on a Hamiltonian system, and calculate the actual rate with which information is exchanged between the first and last particle of the channel. Finally, a relation between our results and important quantities of thermodynamics is presented.

  16. Energy technology transfer to developing countries

    International Nuclear Information System (INIS)

    Goldemberg, J.

    1991-01-01

    This paper gives some examples of how technology transfer can successfully be given to third world countries to allow them to benefit in their quest for economic growth and better standards of living through reduced energy consumption and environmental pollution. It also suggests methods by which obstacles such as high investment costs, lack of information, market demand, etc., can be overcome in order to motivate technological transfer by industrialized countries

  17. Nuclear energy technology transfer: the security barriers

    International Nuclear Information System (INIS)

    Rinne, R.L.

    1975-08-01

    The problems presented by security considerations to the transfer of nuclear energy technology are examined. In the case of fusion, the national security barrier associated with the laser and E-beam approaches is discussed; for fission, the international security requirements, due to the possibility of the theft or diversion of special nuclear materials or sabotage of nuclear facilities, are highlighted. The paper outlines the nuclear fuel cycle and terrorist threat, examples of security barriers, and the current approaches to transferring technology. (auth)

  18. Power law scaling for rotational energy transfer

    International Nuclear Information System (INIS)

    Pritchard, D.E.; Smith, N.; Driver, R.D.; Brunner, T.A.

    1979-01-01

    We have applied a new scaling law to several sets of rotational energy transfer cross sections. The new law asserts that the square of the T-matrix depends on the amount of energy transferred as a power law. Two different kinds of angular momentum statistics are assumed, one corresponding to m/sub j/ being conserved and the other corresponding to m/sub j/ being completely randomized. Numerical fits are presented which demonstrate that the data follow the power law better than the widely used exponential gap law

  19. Theory of coherent resonance energy transfer

    International Nuclear Information System (INIS)

    Jang, Seogjoo; Cheng, Y.-C.; Reichman, David R.; Eaves, Joel D.

    2008-01-01

    A theory of coherent resonance energy transfer is developed combining the polaron transformation and a time-local quantum master equation formulation, which is valid for arbitrary spectral densities including common modes. The theory contains inhomogeneous terms accounting for nonequilibrium initial preparation effects and elucidates how quantum coherence and nonequilibrium effects manifest themselves in the coherent energy transfer dynamics beyond the weak resonance coupling limit of the Foerster and Dexter (FD) theory. Numerical tests show that quantum coherence can cause significant changes in steady state donor/acceptor populations from those predicted by the FD theory and illustrate delicate cooperation of nonequilibrium and quantum coherence effects on the transient population dynamics.

  20. Energy transfer in a mechanically trapped exciplex.

    Science.gov (United States)

    Klosterman, Jeremy K; Iwamura, Munetaka; Tahara, Tahei; Fujita, Makoto

    2009-07-15

    Host-guest complexes involving M(6)L(4) coordination cages can display unusual photoreactivity, and enclathration of the very large fluorophore bisanthracene resulted in an emissive, mechanically trapped intramolecular exciplex. Mechanically linked intramolecular exciplexes are important for understanding the dependence of energy transfer on donor-acceptor distance, orientation, and electronic coupling but are relatively unexplored. Steady-state and picosecond time-resolved fluorescence measurements have revealed that selective excitation of the encapsulated guest fluorophore results in efficient energy transfer from the excited guest to an emissive host-guest exciplex state.

  1. Resonant vibrational energy transfer in ice Ih

    Energy Technology Data Exchange (ETDEWEB)

    Shi, L.; Li, F.; Skinner, J. L. [Theoretical Chemistry Institute and Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706 (United States)

    2014-06-28

    Fascinating anisotropy decay experiments have recently been performed on H{sub 2}O ice Ih by Timmer and Bakker [R. L. A. Timmer, and H. J. Bakker, J. Phys. Chem. A 114, 4148 (2010)]. The very fast decay (on the order of 100 fs) is indicative of resonant energy transfer between OH stretches on different molecules. Isotope dilution experiments with deuterium show a dramatic dependence on the hydrogen mole fraction, which confirms the energy transfer picture. Timmer and Bakker have interpreted the experiments with a Förster incoherent hopping model, finding that energy transfer within the first solvation shell dominates the relaxation process. We have developed a microscopic theory of vibrational spectroscopy of water and ice, and herein we use this theory to calculate the anisotropy decay in ice as a function of hydrogen mole fraction. We obtain very good agreement with experiment. Interpretation of our results shows that four nearest-neighbor acceptors dominate the energy transfer, and that while the incoherent hopping picture is qualitatively correct, vibrational energy transport is partially coherent on the relevant timescale.

  2. Excitation energy transfer from dye molecules to doped graphene

    Indian Academy of Sciences (India)

    Recently, we have reported theoretical studies on the rate of energy transfer ... Dirac cone approximation and hence our conclusions are of qualitative nature. 2. .... make another change of variable to r given by r = ki q/2 to get. G1 (q) = Aq2.

  3. Effects of the charge-transfer reorganization energy on the open-circuit voltage in small-molecular bilayer organic photovoltaic devices: comparison of the influence of deposition rates of the donor.

    Science.gov (United States)

    Lee, Chih-Chien; Su, Wei-Cheng; Chang, Wen-Chang

    2016-05-14

    The theoretical maximum of open-circuit voltage (VOC) of organic photovoltaic (OPV) devices has yet to be determined, and its origin remains debated. Here, we demonstrate that VOC of small-molecule OPV devices can be improved by controlling the deposition rate of a donor without changing the interfacial energy gap at the donor/acceptor interface. The measurement of external quantum efficiency and electroluminescence spectra facilitates the observation of the existence of charge transfer (CT) states. A simplified approach by reusing the reciprocity relationship for obtaining the properties of the CT states is proposed without introducing complex techniques. We compare experimental and fitting results and propose that reorganization energy is the primary factor in determining VOC instead of either the CT energy or electronic coupling term in bilayer OPV devices. Atomic force microscopy images indicate a weak molecular aggregation when a higher deposition rate is used. The results of temperature-dependent measurements suggest the importance of molecular stacking for the CT properties.

  4. Energy transfer in scattering by rotating potentials

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    Quantum mechanical scattering theory is studied for time-dependent. Schrödinger ... the energy transferred to a particle by collision with a rotating blade. Keywords. ..... terms of the unitary group for some time-independent generator. This will ...

  5. Photophysical properties and energy transfer mechanism of PFO/Fluorol 7GA hybrid thin films

    Energy Technology Data Exchange (ETDEWEB)

    Al-Asbahi, Bandar Ali, E-mail: alasbahibandar@gmail.com [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia (UKM), 43600 Bangi, Selangor (Malaysia); Department of Physics, Faculty of Science, Sana' a University (Yemen); Jumali, Mohammad Hafizuddin Haji, E-mail: hafizhj@ukm.my [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia (UKM), 43600 Bangi, Selangor (Malaysia); Yap, Chi Chin; Flaifel, Moayad Husein [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia (UKM), 43600 Bangi, Selangor (Malaysia); Salleh, Muhamad Mat [Institute of Microengineering and Nanoelectronics (IMEN), Universiti Kebangsaan Malaysia (UKM), 43600 Bangi, Selangor (Malaysia)

    2013-10-15

    Photophysical properties of poly (9,9′-di-n-octylfluorenyl-2.7-diyl) (PFO)/2-butyl-6- (butylamino)benzo [de] isoquinoline-1,3-dione (Fluorol 7GA) and energy transfer between them have been investigated. In this work, both PFO and Fluorol 7GA act as donor and acceptor, respectively. Based on the absorption and luminescence measurements, the photophysical and energy transfer properties such as fluorescence quantum yield (Φ{sub f}), fluorescence lifetime (τ), radiative rate constant (k{sub r}), non-radiative rate constant (k{sub nr}), quenching rate constant (k{sub SV}), energy transfer rate constant (k{sub ET}), energy transfer probability (P{sub DA}), energy transfer efficiency (η), critical concentration of acceptor (C{sub o}), energy transfer time (τ{sub ET}) and critical distance of energy transfer (R{sub o}) were calculated. Large values of k{sub SV}, k{sub ET} and R{sub o} suggested that Förster-type energy transfer was the dominant mechanism for the energy transfer between the excited donor and ground state acceptor molecules. It was observed that the Förster energy transfer together with the trapping process are crucial for performance improvement in ITO/(PFO/Fluorol7GA)/Al device. -- Highlights: • The efficient of energy transfer from PFO to Fluorol 7GA was evidenced. • The resonance energy transfer (Förster type) is the dominant mechanism. • Hsu et al. model was used to calculate Φ{sub f}, τ, k{sub r} and k{sub nr} of PFO thin film. • Several of the photophysical and energy transfer properties were calculated. • Trapping process and Förster energy transfer led to improve the device performance.

  6. Far-field RF energy transfer and harvesting

    NARCIS (Netherlands)

    Visser, H.J.; Vullers, R.; Briand, D.; Yeatman, E.; Roundy, S.

    2015-01-01

    This chapter deals with radio frequency (RF) energy transfer over a distance. After explaining the differences between nonradiative and radiative RF energy transfer, the chapter gives definitions for transfer and harvesting. Nonradiative RF energy transfer is mostly employed in inductive systems,

  7. Electron transfer in organic glass. Distance and energy dependence

    International Nuclear Information System (INIS)

    Krongauz, V.V.

    1992-01-01

    The authors have investigated the distance and energy dependence of electron transfer in rigid organic glasses containing randomly dispersed electron donor and electron acceptor molecules. Pulsed radiolysis by an electron beam from a linear accelerator was used for ionization resulting in charge deposition on donor molecules. The disappearance kinetics of donor radical anions due to electron transfer to acceptor was monitored spectroscopically by the change in optical density at the wavelength corresponding to that of donor radical anion absorbance. It was found that the rate of the electron transfer observed experimentally was higher than that computed using the Marcus-Levich theory assuming that the electron-transfer activation barrier is equal to the binding energy of electron on the donor molecule. This discrepancy between the experimental and computed results suggests that the open-quotes inertclose quotes media in which electron-transfer reaction takes place may be participating in the process, resulting in experimentally observed higher electron-transfer rates. 32 refs., 3 figs., 2 tabs

  8. Stochastic Modelling of Wireless Energy Transfer

    Science.gov (United States)

    Veilleux, Shaun; Almaghasilah, Ahmed; Abedi, Ali; Wilkerson, DeLisa

    2017-01-01

    This study investigates the efficiency of a new method of powering remote sensors by the means of wireless energy transfer. The increased use of sensors for data collection comes with the inherent cost of supplying power from sources such as power cables or batteries. Wireless energy transfer technology eliminates the need for power cables or periodic battery replacement. The time and cost of setting up or expanding a sensor network will be reduced while allowing sensors to be placed in areas where running power cables or battery replacement is not feasible. This paper models wireless channels for power and data separately. Smart scheduling for the data channel is proposed to avoid transmitting data on a noisy channel where the probability of data loss is high to improve power efficiency. Analytical models have been developed and verified using simulations.

  9. Energy relaxation and transfer in excitonic trimer

    International Nuclear Information System (INIS)

    Herman, Pavel; Barvik, Ivan; Urbanec, Martin

    2004-01-01

    Two models describing exciton relaxation and transfer (the Redfield model in the secular approximation and Capek's model) are compared for a simple example - a symmetric trimer coupled to a phonon bath. Energy transfer within the trimer occurs via resonance interactions and coupling between the trimer and the bath occurs via modulation of the monomer energies by phonons. Two initial conditions are adopted: (1) one of higher eigenstates of the trimer is initially occupied and (2) one local site of the trimer is initially occupied. The diagonal exciton density matrix elements in the representation of eigenstates are found to be the same for both models, but this is not so for the off-diagonal density matrix elements. Only if the off-diagonal density matrix elements vanish initially (initial condition (1)), they then vanish at arbitrary times in both models. If the initial excitation is local, the off-diagonal matrix elements essentially differ

  10. Wireless Energy Transfer Through Magnetic Reluctance Coupling

    International Nuclear Information System (INIS)

    Pillatsch, P

    2014-01-01

    Energy harvesting from human motion for body worn or implanted devices faces the problem of the wearer being still, e.g. while asleep. Especially for medical devices this can become an issue if a patient is bed-bound for prolonged periods of time and the internal battery of a harvesting system is not recharged. This article introduces a mechanism for wireless energy transfer based on a previously presented energy harvesting device. The internal rotor of the energy harvester is made of mild steel and can be actuated through a magnetic reluctance coupling to an external motor. The internal piezoelectric transducer is consequently actuated and generates electricity. This paper successfully demonstrates energy transfer over a distance of 16 mm in air and an achieved power output of 85 μW at 25 Hz. The device functional volume is 1.85 cm 3 . Furthermore, it was demonstrated that increasing the driving frequency beyond 25 Hz did not yield a further increase in power output. Future research will focus on improving the reluctance coupling, e.g. by investigating the use of multiple or stronger magnets, in order to increase transmission distance

  11. Resonance Energy Transfer Molecular Imaging Application in Biomedicine

    Directory of Open Access Journals (Sweden)

    NIE Da-hong1,2;TANG Gang-hua1,3

    2016-11-01

    Full Text Available Resonance energy transfer molecular imaging (RETI can markedly improve signal intensity and tissue penetrating capacity of optical imaging, and have huge potential application in the deep-tissue optical imaging in vivo. Resonance energy transfer (RET is an energy transition from the donor to an acceptor that is in close proximity, including non-radiative resonance energy transfer and radiative resonance energy transfer. RETI is an optical imaging technology that is based on RET. RETI mainly contains fluorescence resonance energy transfer imaging (FRETI, bioluminescence resonance energy transfer imaging (BRETI, chemiluminescence resonance energy transfer imaging (CRETI, and radiative resonance energy transfer imaging (RRETI. RETI is the hot field of molecular imaging research and has been widely used in the fields of biology and medicine. This review mainly focuses on RETI principle and application in biomedicine.

  12. Local shell-to-shell energy transfer via nonlocal interactions in fluid ...

    Indian Academy of Sciences (India)

    However, the shell-to-shell energy transfer rate is found to be local and forward. .... interaction was strong, but the energy exchange occurred predominantly between ..... The wave-number range considered is in the inverse cascade regime.

  13. Coherent or hopping like energy transfer in the chlorosome ?

    Science.gov (United States)

    Nalbach, Peter

    2014-08-01

    Chlorosomes, as part of the light-harvesting system of green bacteria, are the largest and most efficient antennae systems in nature. We have studied energy transfer dynamics in the chlorosome in a simplified toy model employing a master equation. Dephasing and relaxation due to environmental fluctuations are included by Lindblad dephasing and Redfield thermalization rates. We find at room temperature three separate time scales, i.e. 25 fs, 250 fs and 2.5 ps and determine the according energy pathways through the hierarchical structure in the chlorosome. Quantum coherence lives up to 150 fs at which time the energy is spread over roughly 12 pigments in our model.

  14. Regulation control and energy management scheme for wireless power transfer

    Science.gov (United States)

    Miller, John M.

    2015-12-29

    Power transfer rate at a charging facility can be maximized by employing a feedback scheme. The state of charge (SOC) and temperature of the regenerative energy storage system (RESS) pack of a vehicle is monitored to determine the load due to the RESS pack. An optimal frequency that cancels the imaginary component of the input impedance for the output signal from a grid converter is calculated from the load of the RESS pack, and a frequency offset f* is made to the nominal frequency f.sub.0 of the grid converter output based on the resonance frequency of a magnetically coupled circuit. The optimal frequency can maximize the efficiency of the power transfer. Further, an optimal grid converter duty ratio d* can be derived from the charge rate of the RESS pack. The grid converter duty ratio d* regulates wireless power transfer (WPT) power level.

  15. Energy distribution and transfer in flowing hydrogen microwave plasmas

    International Nuclear Information System (INIS)

    Chapman, R.A.

    1987-01-01

    This thesis is an experimental investigation of the physical and chemical properties of a hydrogen discharge in a flowing microwave plasma system. The plasma system is the mechanisms utilized in an electrothermal propulsion concept to convert electromagnetic energy into the kinetic energy of flowing hydrogen gas. The plasmas are generated inside a 20-cm ID resonant cavity at a driving frequency of 2.45 GHz. The flowing gas is contained in a coaxially positioned 22-mm ID quartz discharge tube. The physical and chemical properties are examined for absorbed powers of 20-100 W, pressures of 0.5-10 torr, and flow rates of 0-10,000 μ-moles/sec. A calorimetry system enclosing the plasma system to accurately measure the energy inputs and outputs has been developed. The rate of energy that is transferred to the hydrogen gas as it flows through the plasma system is determined as a function of absorbed power, pressure, and flow rate to +/-1.8 W from an energy balance around the system. The percentage of power that is transferred to the gas is found to increase with increasing flow rate, decrease with increasing pressure, and to be independent of absorbed power

  16. Using Carbon Nanotubes for Nanometer-Scale Energy Transfer Microscopy

    Science.gov (United States)

    Johnston, Jessica; Shafran, Eyal; Mangum, Ben; Mu, Chun; Gerton, Jordan

    2009-10-01

    We investigate optical energy transfer between fluorophores and carbon nanotubes (CNTs). CNTs are grown on Si-oxide wafers by chemical vapor deposition (CVD), lifted off substrates by atomic force microscope (AFM) tips via Van der Waals forces, then shortened by electrical pulses. The tip-attached CNTs are scanned over fluorescent CdSe-ZnS quantum dots (QDs) with sub-nm precision while recording the fluorescence rate. A novel photon counting technique enables us to produce 3D maps of the QD-CNT coupling, revealing nanoscale lateral and vertical features. All CNTs tested (>50) strongly quenched the QD fluorescence, apparently independent of chirality. In some data, a delay in the recovery of QD fluorescence following CNT-QD contact was observed, suggesting possible charge transfer in this system. In the future, we will perform time-resolved studies to quantify the rate of energy and charge transfer processes and study the possible differences in fluorescence quenching and nanotube-QD energy transfer when comparing single-walled (SW) versus multi-walled (MW) CNTs, attempting to grow substrates consisting primarily of SW or MWCNTs and characterizing the structure of tip-attached CNTs using optical spectroscopy.

  17. Pregnancy Rates After Compulsatory One and Conditional Two Embriyo Transfer

    Directory of Open Access Journals (Sweden)

    Seyhan Gümüşlü

    2013-06-01

    Full Text Available Objective: To predict our pregnancy rates after compulsatory one and conditional two embriyo transfer (ET number. Design: Retrospective Analysis Materiyal and Methods: One or two embryo transferred 362 patient were analyzed between March 2010 and September 2011. Results: Our clinical pregnancy rate was 31% and implantation rate was 25%. Our pregnancy rates after one or two ET were 30 and 32 % respectively ( P>0.05. We transferred embryos at second, third day or blastocyst stage. Pregnancy rates were 19, 30 and 48 % respectively (p< 0.001, implantation rates were 14.5, 23.5 and 42.4 % respectively ( P< 0.001. Our freezing rate was 39.5 %. Not to have freezing quality embrios or to have increased the the pregnancy rate from 21% to %45 significantly. When one embriyo transfered 95 % single and 5 % twins observed. When two embryos were transfered 81% single,17% twin and 2 % triplets observed. Conclusion: Pregnancy rates for one or two ET were statistically similar. If embryo quality allows us to culture up to blastocyt stage pregnancy rates were statistically increased. New Turkish ET policy resulted 95 % to 81 % single gestational sacs according to 1 or 2 ET at Gazi University IVF center.

  18. Electromagnetic Energy Absorption due to Wireless Energy Transfer: A Brief Review

    Directory of Open Access Journals (Sweden)

    Syafiq A.

    2016-01-01

    Full Text Available This paper reviews an implementation of evaluating compliance of wireless power transfer systems with respect to human electromagnetic exposure limits. Methods for both numerical analysis and measurements are discussed. The objective is to evaluate the rate of which energy is absorbed by the human body when exposed to a wireless energy transfer, although it can be referred to the absorption of other forms of energy by tissue. An exposure assessment of a representative wireless power transfer system, under a limited set of operating conditions, is provided in order to estimate the maximum SAR levels. The aim of this review is to conclude the possible side effect to the human body when utilizing wireless charging in daily life so that an early severe action can be taken when using wireless transfer.

  19. Distributed Wireless Power Transfer With Energy Feedback

    Science.gov (United States)

    Lee, Seunghyun; Zhang, Rui

    2017-04-01

    Energy beamforming (EB) is a key technique for achieving efficient radio-frequency (RF) transmission enabled wireless energy transfer (WET). By optimally designing the waveforms from multiple energy transmitters (ETs) over the wireless channels, they can be constructively combined at the energy receiver (ER) to achieve an EB gain that scales with the number of ETs. However, the optimal design of EB waveforms requires accurate channel state information (CSI) at the ETs, which is challenging to obtain practically, especially in a distributed system with ETs at separate locations. In this paper, we study practical and efficient channel training methods to achieve optimal EB in a distributed WET system. We propose two protocols with and without centralized coordination, respectively, where distributed ETs either sequentially or in parallel adapt their transmit phases based on a low-complexity energy feedback from the ER. The energy feedback only depends on the received power level at the ER, where each feedback indicates one particular transmit phase that results in the maximum harvested power over a set of previously used phases. Simulation results show that the two proposed training protocols converge very fast in practical WET systems even with a large number of distributed ETs, while the protocol with sequential ET phase adaptation is also analytically shown to converge to the optimal EB design with perfect CSI by increasing the training time. Numerical results are also provided to evaluate the performance of the proposed distributed EB and training designs as compared to other benchmark schemes.

  20. Wireless energy transfer through non-resonant magnetic coupling

    DEFF Research Database (Denmark)

    Peng, Liang; Breinbjerg, Olav; Mortensen, Asger

    2010-01-01

    could be properly designed to minimize undesired energy dissipation in the source coil when the power receiver is out of the range. Our basic observation paves the way for more flexible design and fabrication of non-resonant mid-range wireless energy transfer systems, thus potentially impacting......We demonstrate by theoretical analysis and experimental verification that mid-range wireless energy transfer systems may take advantage of de-tuned coupling devices, without jeopardizing the energy transfer efficiency. Allowing for a modest de-tuning of the source coil, energy transfer systems...... practical implementations of wireless energy transfer....

  1. Efficient near-field wireless energy transfer using adiabatic system variations

    Energy Technology Data Exchange (ETDEWEB)

    Hamam, Rafif E.; Karalis, Aristeidis; Joannopoulos, John D.; Soljacic, Marin

    2017-11-28

    Disclosed is a method for transferring energy wirelessly including transferring energy wirelessly from a first resonator structure to an intermediate resonator structure, wherein the coupling rate between the first resonator structure and the intermediate resonator structure is .kappa..sub.1B, transferring energy wirelessly from the intermediate resonator structure to a second resonator structure, wherein the coupling rate between the intermediate resonator structure and the second resonator structure is .kappa..sub.B2, and during the wireless energy transfers, adjusting at least one of the coupling rates .kappa..sub.1B and .kappa..sub.B2 to reduce energy accumulation in the intermediate resonator structure and improve wireless energy transfer from the first resonator structure to the second resonator structure through the intermediate resonator structure.

  2. Energy transfer in contact binary systems

    International Nuclear Information System (INIS)

    Robertson, J.A.

    1980-01-01

    A simple model for the transfer of energy by steady circulation within the envelope of a contact binary system is presented. The model describes the fully compressible, two-dimensional flow of a perfect gas within a rectangular region in a uniform gravitational field. The region is heated non-uniformly from below. Coriolis forces are neglected but the interaction of the circulation with convection is discussed briefly. Numerical solutions of the linearized equations of the problem are discussed in detail, and the results of some non-linear calculations are also presented. The influence of alternative boundary conditions is examined. (author)

  3. Nanophotonics: Energy Transfer towards Enhanced Luminescent Chemosensing

    Science.gov (United States)

    Aad, Roy; Couteau, Christophe; Lérondel, Gilles

    2015-01-01

    We discuss a recently proposed novel photonic approach for enhancing the fluorescence of extremely thin chemosensing polymer layers. We present theoretical and experimental results demonstrating the concept of gain-assisted waveguided energy transfer (G-WET) on a very thin polymer nanolayer spincoated on an active ZnO thin film. The G-WET approach is shown to result in an 8-fold increase in polymer fluorescence. We then extend the G-WET concept to nanostructured media. The benefits of using active nanostructured substrates on the sensitivity and fluorescence of chemosensing polymers are discussed. Preliminary theoretical results on enlarged sensing surface and photonic band-gap are presented. PMID:28788025

  4. Low-Energy Ballistic Transfers to Lunar Halo Orbits

    Science.gov (United States)

    Parker, Jeffrey S.

    2009-01-01

    Recent lunar missions have begun to take advantage of the benefits of low-energy ballistic transfers between the Earth and the Moon rather than implementing conventional Hohmann-like lunar transfers. Both Artemis and GRAIL plan to implement low-energy lunar transfers in the next few years. This paper explores the characteristics and potential applications of many different families of low-energy ballistic lunar transfers. The transfers presented here begin from a wide variety of different orbits at the Earth and follow several different distinct pathways to the Moon. This paper characterizes these pathways to identify desirable low-energy lunar transfers for future lunar missions.

  5. Transfer and breakup reactions at intermediate energies

    International Nuclear Information System (INIS)

    Stokstad, R.G.

    1986-04-01

    The origin of the quasi-elastic peak in peripheral heavy-ion reactions is discussed in terms of inelastic scattering and transfer reactions to unbound states of the primary projectile-like fragment. The situation is analogous to the use of reverse kinematics in fusion reactions, a technique in which the object of study is moving with nearly the beam velocity. It appears that several important features of the quasi-elastic peak may be explained by this approach. Projectile-breakup reactions have attractive features for the study of nuclear structure. They may also be used to determine the partition of excitation energy in peripheral reactions. At intermediate energies, neutron-pickup reactions leading to four-body final states become important. Examples of experiments are presented that illustrate these points. 15 refs., 14 figs

  6. Energy transfer mechanisms in layered 2D perovskites.

    Science.gov (United States)

    Williams, Olivia F; Guo, Zhenkun; Hu, Jun; Yan, Liang; You, Wei; Moran, Andrew M

    2018-04-07

    Two-dimensional (2D) perovskite quantum wells are generating broad scientific interest because of their potential for use in optoelectronic devices. Recently, it has been shown that layers of 2D perovskites can be grown in which the average thicknesses of the quantum wells increase from the back to the front of the film. This geometry carries implications for light harvesting applications because the bandgap of a quantum well decreases as its thickness increases. The general structural formula for the 2D perovskite systems under investigation in this work is (PEA) 2 (MA) n-1 [Pb n I 3n+1 ] (PEA = phenethyl ammonium, MA = methyl ammonium). Here, we examine two layered 2D perovskites with different distributions of quantum well thicknesses. Spectroscopic measurements and model calculations suggest that both systems funnel electronic excitations from the back to the front of the film through energy transfer mechanisms on the time scales of 100's of ps (i.e., energy transfer from thinner to thicker quantum wells). In addition, the model calculations demonstrate that the transient absorption spectra are composed of a progression of single exciton and biexciton resonances associated with the individual quantum wells. We find that exciton dissociation and/or charge transport dynamics make only minor contributions to the transient absorption spectra within the first 1 ns after photo-excitation. An analysis of the energy transfer kinetics indicates that the transitions occur primarily between quantum wells with values of n that differ by 1 because of the spectral overlap factor that governs the energy transfer rate. Two-dimensional transient absorption spectra reveal a pattern of resonances consistent with the dominance of sequential energy transfer dynamics.

  7. Energy transfer mechanisms in layered 2D perovskites

    Science.gov (United States)

    Williams, Olivia F.; Guo, Zhenkun; Hu, Jun; Yan, Liang; You, Wei; Moran, Andrew M.

    2018-04-01

    Two-dimensional (2D) perovskite quantum wells are generating broad scientific interest because of their potential for use in optoelectronic devices. Recently, it has been shown that layers of 2D perovskites can be grown in which the average thicknesses of the quantum wells increase from the back to the front of the film. This geometry carries implications for light harvesting applications because the bandgap of a quantum well decreases as its thickness increases. The general structural formula for the 2D perovskite systems under investigation in this work is (PEA)2(MA)n-1[PbnI3n+1] (PEA = phenethyl ammonium, MA = methyl ammonium). Here, we examine two layered 2D perovskites with different distributions of quantum well thicknesses. Spectroscopic measurements and model calculations suggest that both systems funnel electronic excitations from the back to the front of the film through energy transfer mechanisms on the time scales of 100's of ps (i.e., energy transfer from thinner to thicker quantum wells). In addition, the model calculations demonstrate that the transient absorption spectra are composed of a progression of single exciton and biexciton resonances associated with the individual quantum wells. We find that exciton dissociation and/or charge transport dynamics make only minor contributions to the transient absorption spectra within the first 1 ns after photo-excitation. An analysis of the energy transfer kinetics indicates that the transitions occur primarily between quantum wells with values of n that differ by 1 because of the spectral overlap factor that governs the energy transfer rate. Two-dimensional transient absorption spectra reveal a pattern of resonances consistent with the dominance of sequential energy transfer dynamics.

  8. Higher order energy transfer. Quantum electrodynamical calculations and graphical representation

    International Nuclear Information System (INIS)

    Jenkins, R.D.

    2000-01-01

    In Chapter 1, a novel method of calculating quantum electrodynamic amplitudes is formulated using combinatorial theory. This technique is used throughout instead of conventional time-ordered methods. A variety of hyperspaces are discussed to highlight isomorphism between a number of A generalisation of Pascal's triangle is shown to be beneficial in determining the form of hyperspace graphs. Chapter 2 describes laser assisted resonance energy transfer (LARET), a higher order perturbative contribution to the well-known process resonance energy transfer, accommodating an off resonance auxiliary laser field to stimulate the migration. Interest focuses on energy exchanges between two uncorrelated molecular species, as in a system where molecules are randomly oriented. Both phase-weighted and standard isotropic averaging are required for the calculations. Results are discussed in terms of a laser intensity-dependent mechanism. Identifying the applied field regime where LARET should prove experimentally significant, transfer rate increases of up to 30% are predicted. General results for three-center energy transfer are elucidated in chapter 3. Cooperative and accretive mechanistic pathways are identified with theory formulated to elicit their role in a variety of energy transfer phenomena and their relative dominance. In multichromophoric the interplay of such factors is analysed with regard to molecular architectures. The alignments and magnitudes of donor and acceptor transition moments and polarisabilities prove to have profound effects on achievable pooling efficiency for linear configurations. Also optimum configurations are offered. In ionic lattices, although both mechanisms play significant roles in pooling and cutting processes, only the accretive is responsible for sensitisation. The local, microscopic level results are used to gauge the lattice response, encompassing concentration and structural effects. (author)

  9. Energy Transfer in Scattering by Rotating Potentials

    Indian Academy of Sciences (India)

    Quantum mechanical scattering theory is studied for time-dependent Schrödinger operators, in particular for particles in a rotating potential. Under various assumptions about the decay rate at infinity we show uniform boundedness in time for the kinetic energy of scattering states, existence and completeness of wave ...

  10. Energy-donor phosphorescence quenching study of triplet–triplet energy transfer between UV absorbers

    International Nuclear Information System (INIS)

    Kikuchi, Azusa; Nakabai, Yuya; Oguchi-Fujiyama, Nozomi; Miyazawa, Kazuyuki; Yagi, Mikio

    2015-01-01

    The intermolecular triplet–triplet energy transfer from a photounstable UV-A absorber, 4-tert-butyl-4′-methoxydibenzoylmethane (BMDBM), to UV-B absorbers, 2-ethylhexyl 4-methoxycinnamate (octyl methoxycinnamate, OMC), octocrylene (OCR) and dioctyl 4-methoxybenzylidenemalonate (DOMBM) has been observed using a 355 nm laser excitation in rigid solutions at 77 K. The decay curves of the energy-donor phosphorescence in the presence of the UV-B absorbers deviate from the exponential decay at the initial stage of the decay. The Stern–Volmer formulation is not valid in rigid solutions because molecular diffusion is impossible. The experimental results indicate that the rate constant of triplet–triplet energy transfer from BMDBM to the UV-B absorbers, k T–T , decreases in the following order: k T–T (BMDBM–DOMBM)>k T–T (BMDBM–OMC)≥k T–T (BMDBM–OCR). The presence of DOMBM enhances the photostability of the widely used combination of UV-A and UV-B absorbers, BMDBM and OCR. The effects of the triplet–triplet energy transfer on the photostability of BMDBM are discussed. - Highlights: • The intermolecular triplet–triplet energy transfer between UV absorbers was observed. • The phosphorescence decay deviates from exponential at the initial stage of decay. • The effects of triplet–triplet energy transfer on the photostability are discussed

  11. Enhancing radiative energy transfer through thermal extraction

    Science.gov (United States)

    Tan, Yixuan; Liu, Baoan; Shen, Sheng; Yu, Zongfu

    2016-06-01

    Thermal radiation plays an increasingly important role in many emerging energy technologies, such as thermophotovoltaics, passive radiative cooling and wearable cooling clothes [1]. One of the fundamental constraints in thermal radiation is the Stefan-Boltzmann law, which limits the maximum power of far-field radiation to P0 = σT4S, where σ is the Boltzmann constant, S and T are the area and the temperature of the emitter, respectively (Fig. 1a). In order to overcome this limit, it has been shown that near-field radiations could have an energy density that is orders of magnitude greater than the Stefan-Boltzmann law [2-7]. Unfortunately, such near-field radiation transfer is spatially confined and cannot carry radiative heat to the far field. Recently, a new concept of thermal extraction was proposed [8] to enhance far-field thermal emission, which, conceptually, operates on a principle similar to oil immersion lenses and light extraction in light-emitting diodes using solid immersion lens to increase light output [62].Thermal extraction allows a blackbody to radiate more energy to the far field than the apparent limit of the Stefan-Boltzmann law without breaking the second law of thermodynamics. Thermal extraction works by using a specially designed thermal extractor to convert and guide the near-field energy to the far field, as shown in Fig. 1b. The same blackbody as shown in Fig. 1a is placed closely below the thermal extractor with a spacing smaller than the thermal wavelength. The near-field coupling transfers radiative energy with a density greater than σT4. The thermal extractor, made from transparent and high-index or structured materials, does not emit or absorb any radiation. It transforms the near-field energy and sends it toward the far field. As a result, the total amount of far-field radiative heat dissipated by the same blackbody is greatly enhanced above SσT4, where S is the area of the emitter. This paper will review the progress in thermal

  12. Ultrasound acoustic wave energy transfer and harvesting

    Science.gov (United States)

    Shahab, Shima; Leadenham, Stephen; Guillot, François; Sabra, Karim; Erturk, Alper

    2014-04-01

    This paper investigates low-power electricity generation from ultrasound acoustic wave energy transfer combined with piezoelectric energy harvesting for wireless applications ranging from medical implants to naval sensor systems. The focus is placed on an underwater system that consists of a pulsating source for spherical wave generation and a harvester connected to an external resistive load for quantifying the electrical power output. An analytical electro-acoustic model is developed to relate the source strength to the electrical power output of the harvester located at a specific distance from the source. The model couples the energy harvester dynamics (piezoelectric device and electrical load) with the source strength through the acoustic-structure interaction at the harvester-fluid interface. Case studies are given for a detailed understanding of the coupled system dynamics under various conditions. Specifically the relationship between the electrical power output and system parameters, such as the distance of the harvester from the source, dimensions of the harvester, level of source strength, and electrical load resistance are explored. Sensitivity of the electrical power output to the excitation frequency in the neighborhood of the harvester's underwater resonance frequency is also reported.

  13. Enhancing radiative energy transfer through thermal extraction

    Directory of Open Access Journals (Sweden)

    Tan Yixuan

    2016-06-01

    Full Text Available Thermal radiation plays an increasingly important role in many emerging energy technologies, such as thermophotovoltaics, passive radiative cooling and wearable cooling clothes [1]. One of the fundamental constraints in thermal radiation is the Stefan-Boltzmann law, which limits the maximum power of far-field radiation to P0 = σT4S, where σ is the Boltzmann constant, S and T are the area and the temperature of the emitter, respectively (Fig. 1a. In order to overcome this limit, it has been shown that near-field radiations could have an energy density that is orders of magnitude greater than the Stefan-Boltzmann law [2-7]. Unfortunately, such near-field radiation transfer is spatially confined and cannot carry radiative heat to the far field. Recently, a new concept of thermal extraction was proposed [8] to enhance far-field thermal emission, which, conceptually, operates on a principle similar to oil immersion lenses and light extraction in light-emitting diodes using solid immersion lens to increase light output [62].Thermal extraction allows a blackbody to radiate more energy to the far field than the apparent limit of the Stefan-Boltzmann law without breaking the second law of thermodynamics.

  14. Energy Transfer Using Gradient Index Metamaterial

    Directory of Open Access Journals (Sweden)

    Boopalan Ganapathy

    2018-01-01

    Full Text Available The gradient refractive index structure in this paper is used to increase the quantum of energy transfer. This is done by improving the directive gain of the pyramidal horn antenna at a frequency of 10 GHz. A three-dimensional array of closed square rings is placed in front of the horn antenna aperture to form a gradient refractive index structure. This structure increases the directive gain by 1.6 dB as compared to that of the conventional horn antenna. The structure nearly doubles the wireless power transfer quantum between the transmitter and the receiver when placed at both ends. The increase in the directivity is achieved by converting the spherical wave emanating from the horn to a plane wave once it passes through the structure. This transformation is realized by the gradient refractive index structure being placed perpendicular to the direction of propagation. The gradient refractive index is constructed by changing the dimensions of a closed square ring placed in the unit cell of the array. The change in the refractive index gives rise to an improvement of the half power beam width and side lobe level compared to that of the normal horn. The design and simulation were done using CST Studio software.

  15. Fluorescence energy transfer on erythrocyte membranes

    International Nuclear Information System (INIS)

    Fuchs, H.M.; Hof, M.; Lawaczeck, R.

    1995-08-01

    Stationary and time-dependent fluorescence have been measured for a donor/acceptor (DA) pair bound to membrane proteins of bovine erythrocyte ghosts. The donor N-(p-(2-benzoxazolyl)phenyl)-maleimid (BMI) and the acceptor fluram bind to SH- and NH 2 -residues, respectively. The fluorescence spectra and the time-dependent emission are consistent with a radiationless fluorescence energy transfer (RET). The density of RET-effective acceptor binding sites c=0.072 nm -2 was calculated on the basis of the two-dimensional Foerster-kinetic. Band3 protein is the only membrane spanning protein with accessible SH-groups, and therefore only effective binding sites on the band3 protein are counted for the RET measurements performed. (author). 23 refs, 4 figs, 2 tabs

  16. Nanophotonics: Energy Transfer towards Enhanced Luminescent Chemosensing

    Directory of Open Access Journals (Sweden)

    Roy Aad

    2015-04-01

    Full Text Available We discuss a recently proposed novel photonic approach for enhancing the fluorescence of extremely thin chemosensing polymer layers. We present theoretical and experimental results demonstrating the concept of gain-assisted waveguided energy transfer (G-WET on a very thin polymer nanolayer spincoated on an active ZnO thin film. The G-WET approach is shown to result in an 8-fold increase in polymer fluorescence. We then extend the G-WET concept to nanostructured media. The benefits of using active nanostructured substrates on the sensitivity and fluorescence of chemosensing polymers are discussed. Preliminary theoretical results on enlarged sensing surface and photonic band-gap are presented.

  17. Energy transfer in structured and unstructured environments

    DEFF Research Database (Denmark)

    Iles-Smith, Jake; Dijkstra, Arend G.; Lambert, Neill

    2016-01-01

    of motion over a wide range of parameters. Furthermore, we show that the Zusman equations, which may be obtained in a semiclassical limit of the reaction coordinate model, are often incapable of describing the correct dynamical behaviour. This demonstrates the necessity of properly accounting for quantum......We explore excitonic energy transfer dynamics in a molecular dimer system coupled to both structured and unstructured oscillator environments. By extending the reaction coordinate master equation technique developed by Iles-Smith et al. [Phys. Rev. A 90, 032114 (2014)], we go beyond the commonly...... correlations generated between the system and its environment when the Born-Markov approximations no longer hold. Finally, we apply the reaction coordinate formalism to the case of a structured environment comprising of both underdamped (i.e., sharply peaked) and overdamped (broad) components simultaneously...

  18. Intermolecular energy transfer in binary systems of dye polymers

    Science.gov (United States)

    Liu, Lin-I.; Barashkov, Nikolay N.; Palsule, Chintamani P.; Gangopadhyay, Shubhra; Borst, Walter L.

    2000-10-01

    We present results and physical interpretations for the energy transfer mechanisms in two-component dye polymer systems. The data consist of fluorescence emission spectra and decays. Two dyes were embedded in an epoxypolymer base, and only they participated in the energy transfer. Following pulsed laser excitation of the donor dye, energy transfer took place to the accept dye. The possible transfer paths considered here were nonradiative and radiative transfer. The latter involves two steps, emission and absorption of a photon, and therefore is relatively slow, while nonradiative transfer is a fast single step resulting from direct Coulomb interactions. A predominantly nonradiative transfer is desirable for applications, for instance in wavelength shifters in high energy particle detection. We studied the concentration effects of the dyes on the energy transfer and obtained the relative quantum efficiencies of various wavelength shifters from the fluorescence emission spectra. For low acceptor concentrations, radiative transfer was found to dominate, while nonradiative transfer became dominant at increasing dye concentrations. The fluorescence decays were analyzed with a sum-of-exponentials method and with Förster kinetics. The sum of exponential model yielded mean decay times of the dye polymers useful for a general classification. The decay times decreased as desired with increasing acceptor concentration. The samples, in which nonradiative energy transfer dominated, were analyzed with Förster kinetics. As a result, the natural decay times of the donor and acceptor dyes and the critical radii for nonradiative energy transfer were obtained from a global best fit.

  19. Definition and determination of the triplet-triplet energy transfer reaction coordinate.

    Science.gov (United States)

    Zapata, Felipe; Marazzi, Marco; Castaño, Obis; Acuña, A Ulises; Frutos, Luis Manuel

    2014-01-21

    A definition of the triplet-triplet energy transfer reaction coordinate within the very weak electronic coupling limit is proposed, and a novel theoretical formalism is developed for its quantitative determination in terms of internal coordinates The present formalism permits (i) the separation of donor and acceptor contributions to the reaction coordinate, (ii) the identification of the intrinsic role of donor and acceptor in the triplet energy transfer process, and (iii) the quantification of the effect of every internal coordinate on the transfer process. This formalism is general and can be applied to classical as well as to nonvertical triplet energy transfer processes. The utility of the novel formalism is demonstrated here by its application to the paradigm of nonvertical triplet-triplet energy transfer involving cis-stilbene as acceptor molecule. In this way the effect of each internal molecular coordinate in promoting the transfer rate, from triplet donors in the low and high-energy limit, could be analyzed in detail.

  20. Energy transfer of excitons between quantum wells separated by a wide barrier

    International Nuclear Information System (INIS)

    Lyo, S. K.

    2000-01-01

    We present a microscopic theory of the excitonic Stokes and anti-Stokes energy-transfer mechanisms between two widely separated unequal quantum wells with a large energy mismatch (Δ) at low temperatures (T). Several important intrinsic energy-transfer mechanisms have been examined, including dipolar coupling, real and virtual photon-exchange coupling, and over-barrier ionization of the excitons via exciton-exciton Auger processes. The transfer rate is calculated as a function of T and the center-to-center distance d between the wells. The rates depend sensitively on T for plane-wave excitons. For localized excitons, the rates depend on T only through the T dependence of the exciton localization radius. For Stokes energy transfer, the dominant energy transfer occurs through a photon-exchange interaction, which enables the excitons from the higher-energy wells to decay into free electrons and holes in the lower-energy wells. The rate has a slow dependence on d, yielding reasonable agreement with recent data from GaAs/Al x Ga 1-x As quantum wells. The dipolar rate is about an order of magnitude smaller for large d (e.g., d=175Aa) with a stronger range dependence proportional to d -4 . However, the latter can be comparable to the radiative rate for small d (e.g., d≤80Aa). For anti-Stokes transfer through exchange-type (e.g., dipolar and photon-exchange) interactions, we show that thermal activation proportional to exp(-Δ/k B T) is essential for the transfer, contradicting a recent nonactivated result based on the Fo''rster-Dexter's spectral-overlap theory. Phonon-assisted transfer yields a negligibly small rate. On the other hand, energy transfer through over-barrier ionization of excitons via Auger processes yields a significantly larger nonactivated rate which is independent of d. The result is compared with recent data

  1. Organic solar cells: understanding the role of Förster resonance energy transfer.

    Science.gov (United States)

    Feron, Krishna; Belcher, Warwick J; Fell, Christopher J; Dastoor, Paul C

    2012-12-12

    Organic solar cells have the potential to become a low-cost sustainable energy source. Understanding the photoconversion mechanism is key to the design of efficient organic solar cells. In this review, we discuss the processes involved in the photo-electron conversion mechanism, which may be subdivided into exciton harvesting, exciton transport, exciton dissociation, charge transport and extraction stages. In particular, we focus on the role of energy transfer as described by F¨orster resonance energy transfer (FRET) theory in the photoconversion mechanism. FRET plays a major role in exciton transport, harvesting and dissociation. The spectral absorption range of organic solar cells may be extended using sensitizers that efficiently transfer absorbed energy to the photoactive materials. The limitations of F¨orster theory to accurately calculate energy transfer rates are discussed. Energy transfer is the first step of an efficient two-step exciton dissociation process and may also be used to preferentially transport excitons to the heterointerface, where efficient exciton dissociation may occur. However, FRET also competes with charge transfer at the heterointerface turning it in a potential loss mechanism. An energy cascade comprising both energy transfer and charge transfer may aid in separating charges and is briefly discussed. Considering the extent to which the photo-electron conversion efficiency is governed by energy transfer, optimisation of this process offers the prospect of improved organic photovoltaic performance and thus aids in realising the potential of organic solar cells.

  2. Organic Solar Cells: Understanding the Role of Förster Resonance Energy Transfer

    Directory of Open Access Journals (Sweden)

    Paul C. Dastoor

    2012-12-01

    Full Text Available Organic solar cells have the potential to become a low-cost sustainable energy source. Understanding the photoconversion mechanism is key to the design of efficient organic solar cells. In this review, we discuss the processes involved in the photo-electron conversion mechanism, which may be subdivided into exciton harvesting, exciton transport, exciton dissociation, charge transport and extraction stages. In particular, we focus on the role of energy transfer as described by F¨orster resonance energy transfer (FRET theory in the photoconversion mechanism. FRET plays a major role in exciton transport, harvesting and dissociation. The spectral absorption range of organic solar cells may be extended using sensitizers that efficiently transfer absorbed energy to the photoactive materials. The limitations of F¨orster theory to accurately calculate energy transfer rates are discussed. Energy transfer is the first step of an efficient two-step exciton dissociation process and may also be used to preferentially transport excitons to the heterointerface, where efficient exciton dissociation may occur. However, FRET also competes with charge transfer at the heterointerface turning it in a potential loss mechanism. An energy cascade comprising both energy transfer and charge transfer may aid in separating charges and is briefly discussed. Considering the extent to which the photo-electron conversion efficiency is governed by energy transfer, optimisation of this process offers the prospect of improved organic photovoltaic performance and thus aids in realising the potential of organic solar cells.

  3. Influence of donor-donor transport on excitation energy transfer

    Energy Technology Data Exchange (ETDEWEB)

    Pandey, K K; Joshi, H C; Pant, T C [Kumaun University, Nainital (India). Department of Physics

    1989-01-01

    Energy migration and transfer from acriflavine to rhodamine B and malachite green in poly (methylmethacrylate) have been investigated using the decay function analysis. It is found that the influence of energy migration in energy transfer can be described quite convincingly by making use of the theories of Loring, Andersen and Fayer (LAF) and Huber. At high acceptor concentration direct donor-acceptor transfer occurs through Forster mechanism. (author). 17 refs., 5 figs.

  4. The security energy encryption in wireless power transfer

    Science.gov (United States)

    Sadzali, M. N.; Ali, A.; Azizan, M. M.; Albreem, M. A. M.

    2017-09-01

    This paper presents a concept of security in wireless power transfer (WPT) by applying chaos theory. Chaos theory is applied as a security system in order to safeguard the transfer of energy from a transmitter to the intended receiver. The energy encryption of the wireless power transfer utilizes chaos theory to generate the possibility of a logistic map for the chaotic security key. The simulation for energy encryption wireless power transfer system was conducted by using MATLAB and Simulink. By employing chaos theory, the chaotic key ensures the transmission of energy from transmitter to its intended receiver.

  5. Integrated analysis of energy transfers in elastic-wave turbulence.

    Science.gov (United States)

    Yokoyama, Naoto; Takaoka, Masanori

    2017-08-01

    In elastic-wave turbulence, strong turbulence appears in small wave numbers while weak turbulence does in large wave numbers. Energy transfers in the coexistence of these turbulent states are numerically investigated in both the Fourier space and the real space. An analytical expression of a detailed energy balance reveals from which mode to which mode energy is transferred in the triad interaction. Stretching energy excited by external force is transferred nonlocally and intermittently to large wave numbers as the kinetic energy in the strong turbulence. In the weak turbulence, the resonant interactions according to the weak turbulence theory produce cascading net energy transfer to large wave numbers. Because the system's nonlinearity shows strong temporal intermittency, the energy transfers are investigated at active and moderate phases separately. The nonlocal interactions in the Fourier space are characterized by the intermittent bundles of fibrous structures in the real space.

  6. Nanophotonic Control of the Förster Resonance Energy Transfer Efficiency

    DEFF Research Database (Denmark)

    Blum, Christian; Zijlstra, Niels; Lagendijk, Ad

    2012-01-01

    We have studied the influence of the local density of optical states (LDOS) on the rate and efficiency of Forster resonance energy transfer (FRET) from a donor to an acceptor. The donors and acceptors are dye molecules that are separated by a short strand of double-stranded DNA. The LDOS...... is controlled by carefully positioning the FRET pairs near a mirror. We find that the energy transfer efficiency changes with LDOS, and that, in agreement with theory, the energy transfer rate is independent of the LDOS, which allows one to quantitatively control FRET systems in a new way. Our results imply...

  7. Vibrational energy transfer in hydrogen liquid and its isotopes

    International Nuclear Information System (INIS)

    Gale, G.M.; Delalande, C.

    1978-01-01

    The transfer of vibrational energy (V-V) from H 2 to isotopic impurities (HD or D 2 ) has been studied in the liquid state, between 15 and 30 K. The subsequent ralaxation (V-T) of the excited impurity by the H 2 liquid host has also been measured and contrasted with the vibrational relaxation behaviour of pure H 2 and D 2 liquids. The isothermal density dependence of both V-V and V-T transfer has been investigated in the fluid state at 30 K. High density relaxation rates are also compared to the data in the pure gases and to other available gas phase results. Measurements in the solid, near the triple-point temperature, are equally reported for each process studied. (Auth.)

  8. Elementary Energy Transfer Pathways in Allochromatium vinosum Photosynthetic Membranes

    Energy Technology Data Exchange (ETDEWEB)

    Lüer, Larry; Carey, Anne-Marie; Henry, Sarah; Maiuri, Margherita; Hacking, Kirsty; Polli, Dario; Cerullo, Giulio; Cogdell, Richard J.

    2015-11-01

    Allochromatium vinosum (formerly Chromatium vinosum) purple bacteria are known to adapt their light-harvesting strategy during growth according to environmental factors such as temperature and average light intensity. Under low light illumination or low ambient temperature conditions, most of the LH2 complexes in the photosynthetic membranes form a B820 exciton with reduced spectral overlap with LH1. To elucidate the reason for this light and temperature adaptation of the LH2 electronic structure, we performed broadband femtosecond transient absorption spectroscopy as a function of excitation wavelength in A. vinosum membranes. A target analysis of the acquired data yielded individual rate constants for all relevant elementary energy transfer (ET) processes. We found that the ET dynamics in high-light-grown membranes was well described by a homogeneous model, with forward and backward rate constants independent of the pump wavelength. Thus, the overall B800→B850→B890→ Reaction Center ET cascade is well described by simple triexponential kinetics. In the low-light-grown membranes, we found that the elementary backward transfer rate constant from B890 to B820 was strongly reduced compared with the corresponding constant from B890 to B850 in high-light-grown samples. The ET dynamics of low-light-grown membranes was strongly dependent on the pump wavelength, clearly showing that the excitation memory is not lost throughout the exciton lifetime. The observed pump energy dependence of the forward and backward ET rate constants suggests exciton diffusion via B850→ B850 transfer steps, making the overall ET dynamics nonexponential. Our results show that disorder plays a crucial role in our understanding of low-light adaptation in A. vinosum.

  9. Elementary Energy Transfer Pathways in Allochromatium vinosum Photosynthetic Membranes.

    Science.gov (United States)

    Lüer, Larry; Carey, Anne-Marie; Henry, Sarah; Maiuri, Margherita; Hacking, Kirsty; Polli, Dario; Cerullo, Giulio; Cogdell, Richard J

    2015-11-03

    Allochromatium vinosum (formerly Chromatium vinosum) purple bacteria are known to adapt their light-harvesting strategy during growth according to environmental factors such as temperature and average light intensity. Under low light illumination or low ambient temperature conditions, most of the LH2 complexes in the photosynthetic membranes form a B820 exciton with reduced spectral overlap with LH1. To elucidate the reason for this light and temperature adaptation of the LH2 electronic structure, we performed broadband femtosecond transient absorption spectroscopy as a function of excitation wavelength in A. vinosum membranes. A target analysis of the acquired data yielded individual rate constants for all relevant elementary energy transfer (ET) processes. We found that the ET dynamics in high-light-grown membranes was well described by a homogeneous model, with forward and backward rate constants independent of the pump wavelength. Thus, the overall B800→B850→B890→ Reaction Center ET cascade is well described by simple triexponential kinetics. In the low-light-grown membranes, we found that the elementary backward transfer rate constant from B890 to B820 was strongly reduced compared with the corresponding constant from B890 to B850 in high-light-grown samples. The ET dynamics of low-light-grown membranes was strongly dependent on the pump wavelength, clearly showing that the excitation memory is not lost throughout the exciton lifetime. The observed pump energy dependence of the forward and backward ET rate constants suggests exciton diffusion via B850→ B850 transfer steps, making the overall ET dynamics nonexponential. Our results show that disorder plays a crucial role in our understanding of low-light adaptation in A. vinosum. Copyright © 2015 Biophysical Society. Published by Elsevier Inc. All rights reserved.

  10. Electron transfer by excited benzoquinone anions: slow rates for two-electron transitions.

    Science.gov (United States)

    Zamadar, Matibur; Cook, Andrew R; Lewandowska-Andralojc, Anna; Holroyd, Richard; Jiang, Yan; Bikalis, Jin; Miller, John R

    2013-09-05

    Electron transfer (ET) rate constants from the lowest excited state of the radical anion of benzoquinone, BQ(-•)*, were measured in THF solution. Rate constants for bimolecular electron transfer reactions typically reach the diffusion-controlled limit when the free-energy change, ΔG°, reaches -0.3 eV. The rate constants for ET from BQ(-•)* are one-to-two decades smaller at this energy and do not reach the diffusion-controlled limit until -ΔG° is 1.5-2.0 eV. The rates are so slow probably because a second electron must also undergo a transition to make use of the energy of the excited state. Similarly, ET, from solvated electrons to neutral BQ to form the lowest excited state, is slow, while fast ET is observed at a higher excited state, which can be populated in a transition involving only one electron. A simple picture based on perturbation theory can roughly account for the control of electron transfer by the need for transition of a second electron. The picture also explains how extra driving force (-ΔG°) can restore fast rates of electron transfer.

  11. Modeling the efficiency of Förster resonant energy transfer from energy relay dyes in dye-sensitized solar cells

    KAUST Repository

    Hoke, Eric T.

    2010-02-11

    Förster resonant energy transfer can improve the spectral breadth, absorption and energy conversion efficiency of dye sensitized solar cells. In this design, unattached relay dyes absorb the high energy photons and transfer the excitation to sensitizing dye molecules by Förster resonant energy transfer. We use an analytic theory to calculate the excitation transfer efficiency from the relay dye to the sensitizing dye accounting for dynamic quenching and relay dye diffusion. We present calculations for pores of cylindrical and spherical geometry and examine the effects of the Förster radius, the pore size, sensitizing dye surface concentration, collisional quenching rate, and relay dye lifetime. We find that the excitation transfer efficiency can easily exceed 90% for appropriately chosen dyes and propose two different strategies for selecting dyes to achieve record power conversion efficiencies. © 2010 Optical Society of America.

  12. Resonant electronic excitation energy transfer by Dexter mechanism in the quantum dot system

    Science.gov (United States)

    Samosvat, D. M.; Chikalova-Luzina, O. P.; Vyatkin, V. M.; Zegrya, G. G.

    2016-11-01

    In present work the energy transfer between quantum dots by the exchange (Dexter) mechanism is analysed. The interdot Coulomb interaction is taken into consideration. It is assumed that the quantum dot-donor and the quantum dot-acceptor are made from the same compound A3B5 and embedded in the matrix of other material creating potential barriers for electron and holes. The dependences of the energy transfer rate on the quantum-dot system parameters are found using the Kane model that provides the most adequate description spectra of semiconductors A3B5. Numerical calculations show that the rate of the energy transfer by Dexter mechanism is comparable to the rate of the energy transfer by electrostatic mechanism at the distances approaching to the contact ones.

  13. Resonant electronic excitation energy transfer by Dexter mechanism in the quantum dot system

    International Nuclear Information System (INIS)

    Samosvat, D M; Chikalova-Luzina, O P; Zegrya, G G; Vyatkin, V M

    2016-01-01

    In present work the energy transfer between quantum dots by the exchange (Dexter) mechanism is analysed. The interdot Coulomb interaction is taken into consideration. It is assumed that the quantum dot-donor and the quantum dot-acceptor are made from the same compound A3B5 and embedded in the matrix of other material creating potential barriers for electron and holes. The dependences of the energy transfer rate on the quantum-dot system parameters are found using the Kane model that provides the most adequate description spectra of semiconductors A3B5. Numerical calculations show that the rate of the energy transfer by Dexter mechanism is comparable to the rate of the energy transfer by electrostatic mechanism at the distances approaching to the contact ones. (paper)

  14. Mechanism and models for collisional energy transfer in highly excited large polyatomic molecules

    International Nuclear Information System (INIS)

    Gilbert, R. G.

    1995-01-01

    Collisional energy transfer in highly excited molecules (say, 200-500 kJ mol -1 above the zero-point energy of reactant, or of product, for a recombination reaction) is reviewed. An understanding of this energy transfer is important in predicting and interpreting the pressure dependence of gas-phase rate coefficients for unimolecular and recombination reactions. For many years it was thought that this pressure dependence could be calculated from a single energy-transfer quantity, such as the average energy transferred per collision. However, the discovery of 'super collisions' (a small but significant fraction of collisions which transfer abnormally large amounts of energy) means that this simplistic approach needs some revision. The 'ordinary' (non-super) component of the distribution function for collisional energy transfer can be quantified either by empirical models (e.g., an exponential-down functional form) or by models with a physical basis, such as biased random walk (applicable to monatomic or diatomic collision partners) or ergodic (for polyatomic collision partners) treatments. The latter two models enable approximate expressions for the average energy transfer to be estimated from readily available molecular parameters. Rotational energy transfer, important for finding the pressure dependence for recombination reactions, can for these purposes usually be taken as transferring sufficient energy so that the explicit functional form is not required to predict the pressure dependence. The mechanism of 'ordinary' energy transfer seems to be dominated by low-frequency modes of the substrate, whereby there is sufficient time during a vibrational period for significant energy flow between the collision partners. Super collisions may involve sudden energy flow as an outer atom of the substrate is squashed between the substrate and the bath gas, and then is moved away from the interaction by large-amplitude motion such as a ring vibration or a rotation; improved

  15. Ultrafast Energy Transfer in an Artificial Photosynthetic Antenna

    Directory of Open Access Journals (Sweden)

    van Grondelle R.

    2013-03-01

    Full Text Available We temporally resolved energy transfer kinetics in an artificial light-harvesting dyad composed of a phthalocyanine covalently linked to a carotenoid. Upon carotenoid photo-excitation, energy transfers within ≈100fs (≈52% efficiency to the phthalocyanine.

  16. Fluorescence Resonance Energy Transfer in Polydiacetylene Liposomes

    Science.gov (United States)

    Li, Xuelian; Matthews, Shelton; Kohli, Punit

    2009-01-01

    Conjugated polydiacetylene (PDA) possessing stimuli-responsive properties has been intensively investigated for developing efficient sensors. We report here fluorescence resonance energy transfer (FRET) in liposomes synthesized using different molar ratios of dansyl-tagged diacetylene and diacetylene–carboxylic acid monomers. Photopolymerization of diacetylene resulted in cross-linked PDA liposomes. We used steady-state electronic absorption, emission, and fluorescence anisotropy (FA) analysis to characterize the thermal-induced FRET between dansyl fluorophores (donor) and PDA (acceptor). We found that the monomer ratio of acceptor to donor (Rad) and length of linkers (functional part that connects dansyl fluorophores to the diacetylene group in the monomer) strongly affected FRET. For Rad = 10 000, the acceptor emission intensity was amplified by more than 18 times when the liposome solution was heated from 298 to 338 K. A decrease in Rad resulted in diminished acceptor emission amplification. This was primarily attributed to lower FRET efficiency between donors and acceptors and a higher background signal. We also found that the FRET amplification of PDA emissions after heating the solution was much higher when dansyl was linked to diacetylene through longer and flexible linkers than through shorter linkers. We attributed this to insertion of dansyl in the bilayer of the liposomes, which led to an increased dansyl quantum yield and a higher interaction of multiple acceptors with limited available donors. This was not the case for shorter and more rigid linkers where PDA amplification was much smaller. The present studies aim at enhancing our understanding of FRET between fluorophores and PDA-based conjugated liposomes. Furthermore, receptor tagged onto PDA liposomes can interact with ligands present on proteins, enzymes, and cells, which will produce emission sensing signal. Therefore, using the present approach, there exist opportunities for designing FRET

  17. The Unimolecular Reactions of CF3CHF2 Studied by Chemical Activation: Assignment of Rate Constants and Threshold Energies to the 1,2-H Atom Transfer, 1,1-HF and 1,2-HF Elimination Reactions, and the Dependence of Threshold Energies on the Number of F-Atom Substituents in the Fluoroethane Molecules.

    Science.gov (United States)

    Smith, Caleb A; Gillespie, Blanton R; Heard, George L; Setser, D W; Holmes, Bert E

    2017-11-22

    The recombination of CF 3 and CHF 2 radicals in a room-temperature bath gas was used to prepare vibrationally excited CF 3 CHF 2 * molecules with 101 kcal mol -1 of vibrational energy. The subsequent 1,2-H atom transfer and 1,1-HF and 1,2-HF elimination reactions were observed as a function of bath gas pressure by following the CHF 3 , CF 3 (F)C: and C 2 F 4 product concentrations by gas chromatography using a mass spectrometer as the detector. The singlet CF 3 (F)C: concentration was measured by trapping the carbene with trans-2-butene. The experimental rate constants are 3.6 × 10 4 , 4.7 × 10 4 , and 1.1 × 10 4 s -1 for the 1,2-H atom transfer and 1,1-HF and 1,2-HF elimination reactions, respectively. These experimental rate constants were matched to statistical RRKM calculated rate constants to assign threshold energies (E 0 ) of 88 ± 2, 88 ± 2, and 87 ± 2 kcal mol -1 to the three reactions. Pentafluoroethane is the only fluoroethane that has a competitive H atom transfer decomposition reaction, and it is the only example with 1,1-HF elimination being more important than 1,2-HF elimination. The trend of increasing threshold energies for both 1,1-HF and 1,2-HF processes with the number of F atoms in the fluoroethane molecule is summarized and investigated with electronic-structure calculations. Examination of the intrinsic reaction coordinate associated with the 1,1-HF elimination reaction found an adduct between CF 3 (F)C: and HF in the exit channel with a dissociation energy of ∼5 kcal mol -1 . Hydrogen-bonded complexes between HF and the H atom migration transition state of CH 3 (F)C: and the F atom migration transition state of CF 3 (F)C: also were found by the calculations. The role that these carbene-HF complexes could play in 1,1-HF elimination reactions is discussed.

  18. Single blastocyst transfer: The key to reduce multiple pregnancy rates without compromising the live birth rate

    Directory of Open Access Journals (Sweden)

    Uma M Sundhararaj

    2017-01-01

    Full Text Available Background: Historically, to achieve higher pregnancy rates, multiple embryos were transferred after an in-vitro fertilisation (IVF. However, this practice is being reassessed, because it leads to multiple pregnancies that is known to cause adverse maternal and fetal outcomes. Aim: To compare the pregnancy outcomes in fresh IVF or intracytoplasmic sperm injection (ICSI cycles among women undergoing elective single blastocyst transfer (eSBT vs. those undergoing double blastocyst transfer (DBT. Settings and Design: It is a retrospective data analysis of 582 patients undergoing fresh IVF/ICSI cycles performed from January 2012 to June 2015. Materials and Methods: Patients, who underwent IVF/ICSI and developed more than one blastocyst, were included in the study. Donor cycles were excluded from the study. All the embryos were cultured to blastocyst stage in sequential media followed by transfer of two blastocysts (DBT or eSBT and cryopreservation of the remaining. Statistical Analysis: Statistical analysis was performed using chi square test. Results: Out of 582 patients, in 149 patients one blastocyst was transferred and in 433 patients two blastocysts were transferred. There was no statistical difference in the biochemical pregnancy rate, clinical pregnancy rate and live birth rate in both the groups. Statistics demonstrated a significant drop in miscarriage rate in eSBT group. There was no incidence of twins in eSBT group, whereas twin birth rate per clinical pregnancy was 29.02% in DBT group. Conclusion: Single blastocyst transfer is an effective method to reduce the risk of multiple births without compromising the pregnancy outcomes. Given the promising potential of vitrification; the remaining blastocyst can be cryopreserved.

  19. Transfer of spontaneously hatching or hatched blastocyst yields better pregnancy rates than expanded blastocyst transfer

    Directory of Open Access Journals (Sweden)

    Natachandra M Chimote

    2013-01-01

    Full Text Available Context: Blastocyst stage embryo transfer (ET has become routine practice in recent years. However, probably due to limitations of assisted hatching techniques, expanded blastocyst transfer (EBT is still the preferred mode. Inexplicably, not much consideration has been given to spontaneously hatching/hatched blastocyst transfer (SHBT. Aim: This study aimed to investigate developmental potential of spontaneously hatching/hatched blastocyst against EBT in in vitro fertilization (IVF cycles. Settings and Design: Prospective study of 146 women undergoing their first IVF- ET cycle. SUBJECTS AND Methods: On the basis of blastocyst status, women were classified into SHBT and EBT groups. Intracytoplasmic sperm injection cycles were excluded to remove male factor bias. Implantation rate (IR, clinical pregnancy rate, and live birth rate were the main outcome measures. Statistical Analysis: Graph-pad Prism 5 statistical package. Results: SHBT group showed significantly higher blastocyst formation rate (53.3 ± 17.5 vs. 43.1 ± 14.5%, P = 0.0098, top-quality blastocysts (71.8 vs. 53.7%, P = 0.0436, IR (43.6 vs. 27.9%, P = 0.0408, pregnancy rate (59.4 vs. 45.1%, P = 0.0173, and live birth rate (36.8 vs. 22.8%, P = 0.003 compared to EBT group. Multiple pregnancy rates remained comparable between the two groups. Implantation correlated strongly with top-quality blastocysts (Pearson, r = 0.4441 in SHBT group, while the correlation was nonsignificant in EBT group. Conclusion: Extending culture of expanded blastocysts by a few hours to allow transfer of spontaneously hatching/hatched blastocysts gives higher implantation and pregnancy rates with no added risk of multiple gestations. Spontaneously hatching/hatched blastocysts have a better potential to implant and develop into a positive pregnancy.

  20. Energy technology transfer to developing countries

    International Nuclear Information System (INIS)

    Butera, F.; Farinelli, U.

    1992-01-01

    With the use of critical analyses of some examples of technology transfer by industrialized to third world countries, this paper illustrates the importance, in technology transfer, of giving due consideration to the specific social and marketing contexts of the targeted developing country and its physical and financial capability to acquire all the technology necessary to make the total realization of a desired industrial scheme feasible from the economic, technical and social points of view. It also indicates that the most effective transfers are those in which efforts are made to optimize local work force learning levels, process scheme efficiency and cost through the careful integration of innovative with conventional technologies

  1. Theoretical study of electronic transfer current rate at dye-sensitized solar cells

    Science.gov (United States)

    AL-Agealy, Hadi J. M.; AlMaadhede, Taif Saad; Hassooni, Mohsin A.; Sadoon, Abbas K.; Ashweik, Ahmed M.; Mahdi, Hind Abdlmajeed; Ghadhban, Rawnaq Qays

    2018-05-01

    In this research, we present a theoretical study of electronic transfer kinetics rate in N719/TiO2 and N719/ZnO dye-sensitized solar cells (DSSC) systems using a simple model depending on the postulate of quantum mechanics theory. The evaluation of the electronic transition current rate in DSSC systems are function of many parameters such that; the reorientation transition energies ΛSe m D y e , the transition coupling parameter ℂT(0), potential exponential effect e-(E/C-EF ) kBT , unit cell volume VSem, and temperature T. Furthermore, the analysis of electronic transfer current rate in N719/TiO2 and N719/ZnO systems show that the rate upon dye-sensitization solar cell increases with increases of transition coupling parameter, decreasing potential that building at interface a results of different material in this devices and increasing with reorientation transition energy. On the other hand, we can find the electronic transfer behavior is dependent of the dye absorption spectrum and mainly depending on the reorientation of transition energy. The replacement of the solvents in both DSSC system caused increasing of current rates dramatically depending on polarity of solvent in subset devices. This change in current rate of electron transfer were attributed to much more available of recombination sites introduced by the solvents medium. The electronic transfer current dynamics are shown to occurs in N719/TiO2 system faster many time compare to ocuures at N719/ZnO system, this indicate that TiO2 a is a good and active material compare with ZnO to using in dye sensitized solar cell devices. In contrast, the large current rate in N719/TiO2 comparing to ZnO of N719/ZnO systems indicate that using TiO2 with N719 dye lead to increasing the efficiency of DSSC.

  2. Market penetration rates of new energy technologies

    International Nuclear Information System (INIS)

    Lund, Peter

    2006-01-01

    The market penetration rates of 11 different new energy technologies were studied covering energy production and end-use technologies. The penetration rates were determined by fitting observed market data to an epidemical diffusion model. The analyses show that the exponential penetration rates of new energy technologies may vary from 4 up to over 40%/yr. The corresponding take-over times from a 1% to 50% share of the estimated market potential may vary from less than 10 to 70 years. The lower rate is often associated with larger energy impacts. Short take-over times less than 25 years seem to be mainly associated with end-use technologies. Public policies and subsides have an important effect on the penetration. Some technologies penetrate fast without major support explained by technology maturity and competitive prices, e.g. compact fluorescent lamps show a 24.2%/yr growth rate globally. The penetration rates determined exhibit some uncertainty as penetration has not always proceeded close to saturation. The study indicates a decreasing penetration rate with increasing time or market share. If the market history is short, a temporally decreasing functional form for the penetration rate coefficient could be used to anticipate the probable behavior

  3. Energy transfer from triplet aromatic hydrocarbons to Tb3+ and Eu3+ in aqueous micellar solutions

    International Nuclear Information System (INIS)

    Almgren, M.; Grieser, F.; Thomas, J.K.

    1979-01-01

    The sensitization of Tb 3+ and Eu 3+ luminescence by energy transfer from aromatic triplet donors like naphthalene, bromonaphthalene, biphenyl, and phenanthrene in micellar sodium lauryl sulfate solution has been studied. Formal second-order rate constants for the energy transfer process in the micellar solutions were determined as 5 x 10 5 and 1.8 x 10 5 M -1 S -1 for transfer from biphenyl to Tb 3+ . The method of converting these rate constants to second-order constants pertaining to the micellar microenvironment is discussed; it is estimated that the transfer process at the micelles is charaterized by rate constants about one order of magnitude smaller than the formal ones. The transfer process is thus extremely slow. 7 figures

  4. Visual prosthesis wireless energy transfer system optimal modeling.

    Science.gov (United States)

    Li, Xueping; Yang, Yuan; Gao, Yong

    2014-01-16

    Wireless energy transfer system is an effective way to solve the visual prosthesis energy supply problems, theoretical modeling of the system is the prerequisite to do optimal energy transfer system design. On the basis of the ideal model of the wireless energy transfer system, according to visual prosthesis application condition, the system modeling is optimized. During the optimal modeling, taking planar spiral coils as the coupling devices between energy transmitter and receiver, the effect of the parasitic capacitance of the transfer coil is considered, and especially the concept of biological capacitance is proposed to consider the influence of biological tissue on the energy transfer efficiency, resulting in the optimal modeling's more accuracy for the actual application. The simulation data of the optimal model in this paper is compared with that of the previous ideal model, the results show that under high frequency condition, the parasitic capacitance of inductance and biological capacitance considered in the optimal model could have great impact on the wireless energy transfer system. The further comparison with the experimental data verifies the validity and accuracy of the optimal model proposed in this paper. The optimal model proposed in this paper has a higher theoretical guiding significance for the wireless energy transfer system's further research, and provide a more precise model reference for solving the power supply problem in visual prosthesis clinical application.

  5. Ultrafast excitation energy transfer from encapsulated quaterrylene to single-walled carbon nanotube

    Energy Technology Data Exchange (ETDEWEB)

    Koyama, Takeshi, E-mail: koyama@nuap.nagoya-u.ac.jp [Department of Applied Physics, Nagoya University, Chikusa, Nagoya 464-8603 (Japan); Tsunekawa, Takuya [Department of Applied Physics, Nagoya University, Chikusa, Nagoya 464-8603 (Japan); Saito, Takeshi [Research Center for Advanced Carbon Materials, AIST, Tsukuba, Ibaraki 305-8565 (Japan); Asaka, Koji; Saito, Yahachi [Department of Quantum Engineering, Nagoya University, Chikusa, Nagoya 464-8603 (Japan); Kishida, Hideo [Department of Applied Physics, Nagoya University, Chikusa, Nagoya 464-8603 (Japan); Nakamura, Arao [Department of Applied Physics, Nagoya University, Chikusa, Nagoya 464-8603 (Japan); Toyota Physical and Chemical Research Institute, Nagakute, Aichi 480-1192 (Japan)

    2016-01-15

    We investigate excitation energy transfer from an encapsulated quaterrylene molecule to a single-walled carbon nanotube by means of femtosecond pump-probe spectroscopy. The time constant of energy transfer becomes shorter with increasing average diameter of nanotube: 1.4±0.2 ps for 1.0 nm, 1.1±0.2 ps for 1.4 nm, and 0.4±0.1 ps for 1.8 nm. The observed behavior is discussed considering the distance of less than 1 nm between the molecule and the nanotube wall. - Highlights: • Dynamical properties of excited states in quaterrylene/SWNT composites were studied. • Excitation energy transfer occurs in the time range of 0.4-1.4 ps. • The transfer rate depends on the nanotube diameter, i.e. molecule-nanotube wall distance. • This dependence indicates the feature of excitation energy transfer on the nanoscale.

  6. The Grover energy transfer algorithm for relativistic speeds

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Escartin, Juan Carlos; Chamorro-Posada, Pedro, E-mail: juagar@yllera.tel.uva.e [Dpto. de TeorIa de la Senal y Comunicaciones e Ingenieria Telematica, Universidad de Valladolid, ETSI de Telecomunicacion, Campus Miguel Delibes, Paseo Belen 15, 47011 Valladolid (Spain)

    2010-11-12

    Grover's algorithm for quantum search can also be applied to classical energy transfer. The procedure takes a system in which the total energy is equally distributed among N subsystems and transfers most of it to one marked subsystem. We show that in a relativistic setting the efficiency of this procedure can be improved. We will consider the transfer of relativistic kinetic energy in a series of elastic collisions. In this case, the number of steps of the energy transfer procedure approaches 1 as the initial velocities of the objects become closer to the speed of light. This is a consequence of introducing nonlinearities in the procedure. However, the maximum attainable transfer will depend on the particular combination of speed and number of objects. In the procedure, we will use N elements, as in the classical non-relativistic case, instead of the log{sub 2}(N) states of the quantum algorithm.

  7. The Grover energy transfer algorithm for relativistic speeds

    International Nuclear Information System (INIS)

    Garcia-Escartin, Juan Carlos; Chamorro-Posada, Pedro

    2010-01-01

    Grover's algorithm for quantum search can also be applied to classical energy transfer. The procedure takes a system in which the total energy is equally distributed among N subsystems and transfers most of it to one marked subsystem. We show that in a relativistic setting the efficiency of this procedure can be improved. We will consider the transfer of relativistic kinetic energy in a series of elastic collisions. In this case, the number of steps of the energy transfer procedure approaches 1 as the initial velocities of the objects become closer to the speed of light. This is a consequence of introducing nonlinearities in the procedure. However, the maximum attainable transfer will depend on the particular combination of speed and number of objects. In the procedure, we will use N elements, as in the classical non-relativistic case, instead of the log 2 (N) states of the quantum algorithm.

  8. Calculation of energy transfer by fission fragments from plane uranium layer to thin wire

    International Nuclear Information System (INIS)

    Pikulev, A.A.

    2006-01-01

    Energy transfer from a flat fissile uranium slab to a fine wire via fission fragments is calculated. The rate of energy transfer versus the thicknesses of the slab and protecting aluminum film, as well as the wire-slab gap, is found. An expression for the absorption coefficient of the wire is derived, and the effect the thickness of the wire has on the energy transfer process is studied. The amount of the edge effect for a finite-size uranium slab is demonstrated with calculations for vacuum conditions and for argon under a pressure of 0.25 atm [ru

  9. Pair transfer processes probed at deep sub barrier energies

    International Nuclear Information System (INIS)

    Corradi, L.; Mason, P.; Fioretto, E.; Michelagnoli, C.; Stefanini, A.M.; Valiente-Dobon, J.J.; Szinler, S.; Jelavic-Malenica, D.; Soic, N.; Pollarolo, G.; Farnea, E.; Montagnoli, G.; Montanari, D.; Scarlassara, F.; Ur, C.A.; Gadea, A.; Haas, F.; Marginean, N.

    2011-01-01

    Multinucleon transfer cross sections in the system 40 Ca+ 96 Zr have been measured at bombarding energies ranging from the Coulomb barrier to ∼ 25% below. Target-like (lighter) recoils in inverse kinematics have been completely identified in A,Z and Q-value with the large solid angle magnetic spectrometer PRISMA. The experimental slopes of the neutron transfer probabilities at large internuclear separation are consistent with the values derived from the binding energies. A phenomenological interpretation of the transfer probabilities indicates the presence of enhanced values for the even number of neutron transfers. (authors)

  10. Energy transfers and magnetic energy growth in small-scale dynamo

    KAUST Repository

    Kumar, Rohit Raj; Verma, Mahendra K.; Samtaney, Ravi

    2013-01-01

    In this letter we investigate the dynamics of magnetic energy growth in small-scale dynamo by studying energy transfers, mainly energy fluxes and shell-to-shell energy transfers. We perform dynamo simulations for the magnetic Prandtl number Pm = 20

  11. A planning framework for transferring building energy technologies

    Energy Technology Data Exchange (ETDEWEB)

    Farhar, B C; Brown, M A; Mohler, B L; Wilde, M; Abel, F H

    1990-07-01

    Accelerating the adoption of new and existing cost-effective technologies has significant potential to reduce the energy consumed in US buildings. This report presents key results of an interlaboratory technology transfer planning effort in support of the US Department of Energy's Office of Building Technologies (OBT). A guiding assumption for planning was that OBT's R D program should forge linkages with existing programs whose goals involved enhancing energy efficiency in buildings. An ad hoc Technology Transfer Advisory Group reviewed the existing analysis and technology transfer program, brainstormed technology transfer approaches, interviewed DOE program managers, identified applicable research results, and developed a framework that management could use in deciding on the best investments of technology transfer resources. Representatives of 22 organizations were interviewed on their views of the potential for transferring energy efficiency technologies through active linking with OBT. The report describes these programs and interview results; outlines OBT tools, technologies, and practices to be transferred; defines OBT audiences; identifies technology transfer functions and presents a framework devised using functions and audiences; presents some 60 example technology transfer activities; and documents the Advisory Group's recommendations. 37 refs., 3 figs., 12 tabs.

  12. Ultrafast Single and Multiexciton Energy Transfer in Semiconductor Nanoplatelets

    Science.gov (United States)

    Schaller, Richard

    Photophysical processes such as fluorescence resonance energy transfer (FRET) enable optical antennas, wavelength down-conversion in light-emitting diodes (LEDs), and optical bio-sensing schemes. The rate and efficiency of this donor to acceptor transfer of excitation between chromophores dictates the utility of FRET and can unlock new device operation motifs including quantum-funnel solar cells and reduced gain thresholds. However, the fastest reported FRET time constants involving spherical quantum dots (QDs) (0.12-1 ns), do not outpace biexciton Auger recombination (0.01-0.1 ns), which impedes multiexciton-driven applications including electrically-pumped lasers and carrier-multiplication-enhanced photovoltaics. Precisely controlled, few-monolayer thick semiconductor nano-platelets with tens-of-nanometer diameters exhibit intense optical transitions and hundreds-of-picosecond Auger recombination, but heretofore lack FRET characterizations. We examine binary CdSe NPL solids and show that inter-plate FRET (~6-23 ps, presumably for co-facial arrangements) can occur 15-50 times faster than Auger recombination and demonstrate multiexcitonic FRET, making such materials ideal candidates for advanced technologies. This work was performed at the Center for Nanoscale Materials, a U.S. Department of Energy Office of Science User Facility under Contract No. DE-AC02-06CH11357.

  13. Energy transfers in dynamos with small magnetic Prandtl numbers

    KAUST Repository

    Kumar, Rohit; Verma, Mahendra K.; Samtaney, Ravi

    2015-01-01

    We perform numerical simulation of dynamo with magnetic Prandtl number Pm = 0.2 on 10243 grid, and compute the energy fluxes and the shell-to-shell energy transfers. These computations indicate that the magnetic energy growth takes place mainly due

  14. Energy transfer dynamics in Light-Harvesting Dendrimers

    Science.gov (United States)

    Melinger, Joseph S.; McMorrow, Dale; Kleiman, Valeria D.

    2002-03-01

    We explore energy transfer dynamics in light-harvesting phenylacetylene symmetric and asymmetric dendrimers. Femtosecond pump-probe spectroscopy is used to probe the ultrafast dynamics of electronic excitations in these dendrimers. The backbone of the macromolecule consists of branches of increasing conjugation length, creating an energy gradient, which funnels energy to an accepting perylene trap. In the case of the symmetric dendrimer (nanostar), the energy transfer efficiency is known to approach nearly unity, although the nature and timescale of the energy transfer process is still unknown. For the asymmetric dendrimers, energy transfer efficiencies are very high, with the possibility of more complex transfer processes. We experimentally monitor the transport of excitons through the light-harvesting dendrimer. The transients show a number of components, with timescales ranging from <300fs to several tens of picoseconds, revealing the complex photophysics taking place in these macromolecules. We interpret our results in terms of the Förster mechanism in which energy transfer occurs through dipole-dipole interactions.

  15. A simplified approach for the coupling of excitation energy transfer

    Energy Technology Data Exchange (ETDEWEB)

    Shi Bo [Hefei National Laboratory for Physical Science at Microscale, University of Science and Technology of China, Hefei 230026 (China); Department of Chemical Physics, University of Science and Technology of China, Hefei 230026 (China); Gao Fang, E-mail: gaofang@iim.ac.cn [Institute of Intelligent Machines, Chinese Academy of Sciences, Hefei 230031 (China); State Key Laboratory of Robotics, Shenyang Institute of Automation, Chinese Academy of Sciences, Shenyang 110016 (China); Liang Wanzhen [Hefei National Laboratory for Physical Science at Microscale, University of Science and Technology of China, Hefei 230026 (China); Department of Chemical Physics, University of Science and Technology of China, Hefei 230026 (China)

    2012-02-06

    Highlights: Black-Right-Pointing-Pointer We propose a simple method to calculate the coupling of singlet-to-singlet and triplet-to-triplet energy transfer. Black-Right-Pointing-Pointer Coulomb term are the major contribution to the coupling of singlet-to-singlet energy transfer. Black-Right-Pointing-Pointer Effect from the intermolecular charge-transfer states dorminates in triplet-to-triplet energy transfer. Black-Right-Pointing-Pointer This method can be expanded by including correlated wavefunctions. - Abstract: A simplified approach for computing the electronic coupling of nonradiative excitation-energy transfer is proposed by following Scholes et al.'s construction on the initial and final states [G.D. Scholes, R.D. Harcourt, K.P. Ghiggino, J. Chem. Phys. 102 (1995) 9574]. The simplification is realized through defining a set of orthogonalized localized MOs, which include the polarization effect of the charge densities. The method allows calculating the coupling of both the singlet-to-singlet and triplet-to-triplet energy transfer. Numerical tests are performed for a few of dimers with different intermolecular orientations, and the results demonstrate that Coulomb term are the major contribution to the coupling of singlet-to-singlet energy transfer whereas in the case of triplet-to-triplet energy transfer, the dominant effect is arisen from the intermolecular charge-transfer states. The present application is on the Hartree-Fock level. However, the correlated wavefunctions which are normally expanded in terms of the determinant wavefunctions can be employed in the similar way.

  16. Muon transfer rates in collisions of hydrogen isotope mesic atoms on 'bare' nuclei. Multichannel adiabatic approach

    International Nuclear Information System (INIS)

    Korobov, V.I.; Melezhik, V.S.; Ponomarev, L.I.

    1992-01-01

    A numerical scheme for solving the problem of slow collisions in the three-body adiabatic approach is applied for calculation of muon transfer rates in collisions of hydrogen isotope atoms on bare nuclei. It is demonstrated that the multichannel adiabatic approach allows one to reach high accuracy results (∼3%) estimating the cross sections of charge transfer processes which are the best ones up to date. The method is appliable in a wide range of energies (0.001-50 eV) which is of interest for analysis of muon catalysed fusion experiments. 20 refs.; 3 figs.; 5 tabs

  17. Modelling excitonic energy transfer in the photosynthetic unit of purple bacteria

    International Nuclear Information System (INIS)

    Linnanto, J.M.; Korppi-Tommola, J.E.I.

    2009-01-01

    Molecular mechanics and quantum chemical configuration interaction calculations in combination with exciton theory were used to predict vibronic energies and eigenstates of light harvesting antennae and the reaction centre and to evaluate excitation energy transfer rates in the photosynthetic unit of purple bacteria. Excitation energy transfer rates were calculated by using the transition matrix formalism and exciton basis sets of the interacting antenna systems. Energy transfer rates of 600-800 fs from B800 ring to B850 ring in the LH2 antenna, 3-10 ps from LH2 to LH2 antenna, 2-8 ps from LH2 to LH1 antenna and finally 30-70 ps from LH1 to the reaction centre were obtained. Dependencies of energy transfer rates on lateral and vertical inter-complex distances were determined. The results indicate that a fair amount of spatial heterogeneity of antenna complexes in the photosynthetic membrane is tolerated without much loss in excitation energy transfer efficiency

  18. Modelling excitonic energy transfer in the photosynthetic unit of purple bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Linnanto, J.M. [Department of Chemistry, P.O. Box 35, FIN-40014 University of Jyvaeskylae, Jyvaeskylae (Finland)], E-mail: juha.m.linnanto@jyu.fi; Korppi-Tommola, J.E.I. [Department of Chemistry, P.O. Box 35, FIN-40014 University of Jyvaeskylae, Jyvaeskylae (Finland)

    2009-02-23

    Molecular mechanics and quantum chemical configuration interaction calculations in combination with exciton theory were used to predict vibronic energies and eigenstates of light harvesting antennae and the reaction centre and to evaluate excitation energy transfer rates in the photosynthetic unit of purple bacteria. Excitation energy transfer rates were calculated by using the transition matrix formalism and exciton basis sets of the interacting antenna systems. Energy transfer rates of 600-800 fs from B800 ring to B850 ring in the LH2 antenna, 3-10 ps from LH2 to LH2 antenna, 2-8 ps from LH2 to LH1 antenna and finally 30-70 ps from LH1 to the reaction centre were obtained. Dependencies of energy transfer rates on lateral and vertical inter-complex distances were determined. The results indicate that a fair amount of spatial heterogeneity of antenna complexes in the photosynthetic membrane is tolerated without much loss in excitation energy transfer efficiency.

  19. Rotational energy transfer of the A{sup 2}{Sigma}`({nu}`=1) state of OH

    Energy Technology Data Exchange (ETDEWEB)

    Beaud, P; Radi, P; Frey, H B; Mischler, B; Tzannis, A P; Gerber, T [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    Spectrally and temporally resolved laser excited fluorescence of OH is investigated in the picosecond time domain. The total rotational energy transfer (RET) rate from the excited state is determined from the experimental data. Simulated spectra obtained by modelling RET with the energy corrected sudden approximation agree well with the measured spectra. (author) 1 fig., 1 tab., 5 refs.

  20. Ultrafast energy transfer in dansylated POPAM--eosin complexes

    Science.gov (United States)

    Aumanen, Jukka; Lehtovuori, Viivi; Werner, Nicole; Richardt, Gabriele; van Heyst, Jeroen; Vögtle, Fritz; Korppi-Tommola, Jouko

    2006-12-01

    Excitation energy transfer (EET) in dendritic host-guest complexes has been studied. Three generations G2, G3 and G4 of dansyl substituted poly(propyleneamine) dendrimers (POPAM) were complexed with a fluorescent dye eosin in chloroform solution. Arrival of excitation from dansyls to eosin was monitored by femtosecond transient absorption spectroscopy. EET rates from the dansyls to eosin(s) are characterised by two time constants 1 ps and 6 ps independent of dendrimer generation. Relaxation processes in eosin were clearly faster when complexed with dendrimer than in solution. As several eosins are bound to G3 and G4 dendrimers, besides host-guest interaction, also eosin-eosin interactions may contribute to the faster relaxation observed in these complexes.

  1. Vibrational energy transfer in selectively excited diatomic molecules

    International Nuclear Information System (INIS)

    Dasch, C.J.

    1978-09-01

    Single rovibrational states of HCl(v=2), HBr(v=2), DCl(v=2), and CO(v=2) were excited with a pulsed optical parametric oscillator (OPO). Total vibrational relaxation rates near - resonance quenchers were measured at 295 0 K using time resolved infrared fluorescence. These rates are attributed primarily to V - V energy transfer, and they generally conform to a simple energy gap law. A small deviation was found for the CO(v) + DCl(v') relaxation rates. Upper limits for the self relaxation by V - R,T of HCl(v=2) and HBr(v=2) and for the two quantum exchange between HCl and HBr were determined. The HF dimer was detected at 295 0 K and 30 torr HF pressure with an optoacoustic spectrometer using the OPO. Pulsed and chopped, resonant and non-resonant spectrophones are analyzed in detail. From experiments and first order perturbation theory, these V - V exchange rates appear to behave as a first order perturbation in the vibrational coordinates. The rotational dynamics are known to be complicated however, and the coupled rotational - vibrational dynamics were investigated theoreticaly in infinite order by the Dillon and Stephenson and the first Magnus approximations. Large ΔJ transitions appear to be important, but these calculations differ by orders of magnitude on specific rovibrational transition rates. Integration of the time dependent semiclassical equations by a modified Gordon method and a rotationally distorted wave approximation are discussed as methods which would treat the rotational motion more accurately. 225 references

  2. A chopper circuit for energy transfer between superconducting magnets

    International Nuclear Information System (INIS)

    Onishi, Toshitada; Tateishi, Hiroshi; Takeda, Masatoshi; Matsuura, Toshiaki; Nakatani, Toshio.

    1986-01-01

    It has been suggested that superconducting magnets could provide a medium for storing energy and supplying the large energy pulses needed by experimental nuclear-fusion equipment and similar loads. Based on this concept, tests on energy transfer between superconducting magnets are currently being conducted at the Agency of Industrial Science and Technology's Electrotechnical Laboratory. Mitsubishi Electric has pioneered the world's first chopper circuit for this application. The circuit has the advantages of being simple and permitting high-speed, bipolar energy transfer. The article describes this circuit and its testing. (author)

  3. Energy transfers and magnetic energy growth in small-scale dynamo

    KAUST Repository

    Kumar, Rohit Raj

    2013-12-01

    In this letter we investigate the dynamics of magnetic energy growth in small-scale dynamo by studying energy transfers, mainly energy fluxes and shell-to-shell energy transfers. We perform dynamo simulations for the magnetic Prandtl number Pm = 20 on 10243 grid using the pseudospectral method. We demonstrate that the magnetic energy growth is caused by nonlocal energy transfers from the large-scale or forcing-scale velocity field to small-scale magnetic field. The peak of these energy transfers moves towards lower wave numbers as dynamo evolves, which is the reason why the integral scale of the magnetic field increases with time. The energy transfers U2U (velocity to velocity) and B2B (magnetic to magnetic) are forward and local. Copyright © EPLA, 2013.

  4. Foerster resonance energy transfer in inhomogeneous non-dispersive nanophotonic environments

    DEFF Research Database (Denmark)

    Wubs, Martijn; Vos, Willem L.

    A nondispersive inhomogeneous dielectric environment of a donor-acceptor pair of quantum emitters affects their Foerster resonance energy transfer (FRET) rate. We find that this rate does not depend on the emission frequency and hence not on the local optical density of states (LDOS) at that freq...

  5. Energy transfer in porous anodic alumina/rhodamine 110 nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Elhouichet, H., E-mail: habib.elhouichet@fst.rnu.tn [Laboratoire de Physico-Chimie des Materiaux Mineraux et leurs Applications, Centre National de Recherches en Sciences des Materiaux, B.P. 95, Hammam-Lif 2050 (Tunisia); Departement de Physique, Faculte des Sciences de Tunis, University of Tunis Elmanar 2092 Tunis (Tunisia); Harima, N.; Koyama, H. [Hyogo University of Teacher Education, Kato, Hyogo 673-1494 (Japan); Gaponenko, N.V. [Belarusian State University of Informatics and Radioelectronics, P. Browki St. 6, 220013 Minsk (Belarus)

    2012-09-15

    We have used porous anodic alumina (PAA) films as templates for embedding rhodamine 110 (Rh110) molecules and examined their photoluminescence (PL) properties in detail. The analysis of the polarization memory (PM) of PL strongly suggests that there is a significant energy transfer from PAA to Rh110 molecules. The effect of annealing the PAA layer on the PL properties of the nanocomposite has been studied. The results show that the energy transfer becomes more efficient in annealed PAA. - Highlights: Black-Right-Pointing-Pointer Porous anodic alumina-rhodamine 110 nanocomposites are elaborated. Black-Right-Pointing-Pointer Efficient energy transfer from the host to Rh110 molecules is evidenced from measurements of photoluminescence and degree of polarization memory spectra. Black-Right-Pointing-Pointer Thermal annealing of porous anodic alumina can improve the process of excitation transfer.

  6. Vectorial photoinduced energy transfer between boron-dipyrromethene (Bodipy) chromophores across a fluorene bridge.

    Science.gov (United States)

    Puntoriero, Fausto; Nastasi, Francesco; Campagna, Sebastiano; Bura, Thomas; Ziessel, Raymond

    2010-08-02

    A series of novel multichromophoric, luminescent compounds has been prepared, and their absorption spectra, luminescence properties (both at 77 K in rigid matrix and at 298 K in fluid solution), and photoinduced intercomponent energy-transfer processes have been studied. The series contains two new multichromophoric systems 1 and 2, each one containing two different boron-dipyrromethene (Bodipy) subunits and one bridging fluorene species, and two fluorene-Bodipy bichromophoric species, 6 and 7. Three monochromophoric compounds, 3, 4, and 5, used as precursors in the synthetic process, were also fully characterized. The absorption spectra of the multichromophoric compounds are roughly the summation of the absorption spectra of their individual components, thus demonstrating the supramolecular nature of the assemblies. Luminescence studies show that quantitative energy transfer occurs in 6 and 7 from the fluorene chromophore to the Bodipy dyes. Luminescence studies, complemented by transient-absorption spectroscopy studies, also indicate that efficient inter-Bodipy energy transfer across the rigid fluorene spacer takes place in 1 and 2, with rate constants, evaluated by several experimental methods, between 2.0 and 7.0 x 10(9) s(-1). Such an inter-Bodipy energy transfer appears to be governed by the Förster mechanism. By taking advantage of the presence of various protonable sites in the substituents of the lower-energy Bodipy subunit of 1 and 2, the effect of protonation on the energy-transfer rates has also been investigated. The results suggest that control of energy-transfer rate and efficiency of inter-Bodipy energy transfer in this type of systems can be achieved by an external, reversible input.

  7. Complexity, rate of energy exchanges and stochasticity

    International Nuclear Information System (INIS)

    Casartelli, M.; Sello, S.

    1987-01-01

    The complexity of trajectories in the phase of anharmonic crystal (mostly a Lennard-Jones chain) is analysed by the variance of microcanonical density and by new parameters P and chi defined, respectively, as the mean value of the time averages and the relative variance of the absolute exchange rate of energies among the normal modes. Evidence is given to the trapping action of residual invariant surfaces in low stochastic regime of motion. The parameter chi, moreover, proves efficient in exploring the border of stochasticity. A simple power law for P vs. the specific energy is obtained and proved to be independent of stochasticity and of the type of anharmonic potential

  8. Energy storage and transfer with homopolar machine for a linear theta-pinch hybrid reactor

    International Nuclear Information System (INIS)

    Vogel, H.F.; Brennan, M.; Dase, W.G.; Tolk, K.M.; Weldon, W.F.

    1976-01-01

    The energy storage and transfer system for the compression coils of a linear theta-pinch hybrid reactor (LTPHR) are described. High efficiency and low cost are the principal requirements for the energy storage and transfer of 25MJ/m or 25GJ for a 1-km LTPHR. The circuit efficiency must be approximately 90%, and the cost for the circuit 5-6c/J. Scaling laws and simple relationships between circuit efficiency and cost-per-unit energy as a function of the half cycle time are presented. An important consideration concerns the pulse repetition rate of 2.25 pulses per second, 70x10 6 shots/yr, or 1.7x10 9 shots over the 25-yr plant life. Current interruption to initiate energy transfer is not feasible at this rate. Therefore, a simple ringing circuit with contactors to make and break at the periodically occurring zero-current instances, is considered

  9. Energy transfers in dynamos with small magnetic Prandtl numbers

    KAUST Repository

    Kumar, Rohit

    2015-06-25

    We perform numerical simulation of dynamo with magnetic Prandtl number Pm = 0.2 on 10243 grid, and compute the energy fluxes and the shell-to-shell energy transfers. These computations indicate that the magnetic energy growth takes place mainly due to the energy transfers from large-scale velocity field to large-scale magnetic field and that the magnetic energy flux is forward. The steady-state magnetic energy is much smaller than the kinetic energy, rather than equipartition; this is because the magnetic Reynolds number is near the dynamo transition regime. We also contrast our results with those for dynamo with Pm = 20 and decaying dynamo. © 2015 Taylor & Francis.

  10. Linear motor with contactless energy transfer

    NARCIS (Netherlands)

    2014-01-01

    An integrated electromagnetic energy conversions device is provided that includes a synchronous or brushless linear (SoBL) motor, and a transformer, where the transformer is integrated electromagnetically and topologically with the SoBL motor, where an electromagnetic field orientation of the

  11. Luminescence and energy transfer in Garnet Scintillators

    NARCIS (Netherlands)

    Ogiegło, J.M.

    2012-01-01

    The thesis is focused on development and fundamental understanding of scintillators that play a central role in the field of medical imaging. These materials convert high energy, gamma or X-ray, radiation into visible light that is then used to create a detailed image of the patient’s body. The

  12. Optical absorption and energy transfer processes in dendrimers

    International Nuclear Information System (INIS)

    Reineker, P.; Engelmann, A.; Yudson, V.I.

    2004-01-01

    For dendrimers of various sizes the energy transfer and the optical absorption is investigated theoretically. The molecular subunits of a dendrimer are modeled as two-level systems. The electronic interaction between them is described via transfer integrals and the influence of vibrational degrees of freedom is taken into account in a first approach using a stochastic model. We discuss the time dependence of the energy transport and show that rim states of the dendrimer dominate the absorption spectra, that in general the electronic excitation energy is concentrated on peripheric molecules, and that the energetically lowest absorption peak is redshifted with increasing dendrimer size due to delocalization of the electronic excitation

  13. Nuclear response functions at large energy and momentum transfer

    International Nuclear Information System (INIS)

    Bertozzi, W.; Moniz, E.J.; Lourie, R.W.

    1991-01-01

    Quasifree nucleon processes are expected to dominate the nuclear electromagnetic response function for large energy and momentum transfers, i.e., for energy transfers large compared with nuclear single particle energies and momentum transfers large compared with typical nuclear momenta. Despite the evident success of the quasifree picture in providing the basic frame work for discussing and understanding the large energy, large momentum nuclear response, the limits of this picture have also become quite clear. In this article a selected set of inclusive and coincidence data are presented in order to define the limits of the quasifree picture more quantitatively. Specific dynamical mechanisms thought to be important in going beyond the quasifree picture are discussed as well. 75 refs, 37 figs

  14. Heat transfer in intermediate heat exchanger under low flow rate conditions

    International Nuclear Information System (INIS)

    Mochizuki, H.

    2008-01-01

    The present paper describes the heat transfer in intermediate heat exchangers (IHXs) of liquid metal cooled fast reactors when flow rate is low such as a natural circulation condition. Although empirical correlations of heat transfer coefficients for IHX were derived using test data at the fast reactor 'Monju' and 'Joyo' and also at the 50 MW steam generator facility, the heat transfer coefficient was very low compared to the well known correlation for liquid metals proposed by Seban-Shimazaki. The heat conduction in IHX was discussed as a possible cause of the low Nusselt number. As a result, the heat conduction is not significant under the natural circulation condition, and the heat conduction term in the energy equation can be neglected in the one-dimensional plant dynamics calculation. (authors)

  15. Energy transfer from a superconducting magnet to an inductive load

    International Nuclear Information System (INIS)

    Onishi, Toshitada; Miura, Akinori.

    1977-01-01

    Experiments on energy transfer between two superconducting magnets have been carried out using an inductive energy transfer system similar to the flying capacitor system developed at the Karlsruhe Institute. In the present system the capacitor is grounded and diodes are used instead of thyristors, and a fraction of stored energy is transferred to the capacitor only when the relay connected in parallel to the magnet is switched off. The capacitor is expected to have no constraint in size, while in the flying capacitor system the capacitor is required to exceed a threshold size. Consequently it is possible to shorten the transfer time to some extent in comparison with the one in the flying capacitor system. Transfer experiments have been carried out using a storage magnet with inductance of 1.2H and a load of 0.41H. The capacitance is 200μF. It is possible to transfer 80.1% of the stored energy of 221 J into the load in less than about 0.35 seconds. (auth.)

  16. Luminescence and energy transfer in Garnet Scintillators

    OpenAIRE

    Ogiegło, J.M.

    2012-01-01

    The thesis is focused on development and fundamental understanding of scintillators that play a central role in the field of medical imaging. These materials convert high energy, gamma or X-ray, radiation into visible light that is then used to create a detailed image of the patient’s body. The power of such imaging techniques as diagnostic medical tools is hard to overestimate.

  17. Exploiting energy transfer in hybrid metal and semiconductor nanoparticle systems for biosensing and energy harvesting

    Energy Technology Data Exchange (ETDEWEB)

    Mayilo, Sergiy

    2009-06-19

    In this work, gold and semiconductor nanoparticles are used as building blocks for nanostructures, in which energy transfer is investigated. Fluorescence quenching by gold nanoparticles is investigated and used to develop novel immunoassays for medically relevant molecules. The influence of gold nanoparticles on radiative and non-radiative rates of Cy3 and Cy3B dyes is studied here. A competitive, homogeneous immunoassay for digoxigenin and digoxin, a drug used to cure heart diseases, is developed. The assay has a limit of detection of 0.5 nM in buffer and 50 nM in serum. Time resolved spectroscopy reveals that the quenching is due to energy transfer with an efficiency of 70%. A homogeneous sandwich immunoassay for cardiac troponin T, an indicator of damage to the heart muscle, is developed. Gold nanoparticles and fluorophores are functionalized with anti-troponin T antibodies. In the presence of troponin T the nanoparticles and fluorophores form a sandwich structure, in which the dye fluorescence is quenched by a gold nanoparticle. The limit of detection of the immunoassay in buffer is 0.02 nM and 0.11 nM in serum. Energy transfer is demonstrated in clusters of CdTe nanocrystals assembled using three methods. In the first method, clusters of differently-sized water soluble CdTe nanocrystals capped by negatively charged mercaptoacid stabilizers are produced through electrostatic interactions with positively charged Ca{sup 2+} cations. The two other methods employ covalent binding through dithiols and thiolated DNA as linkers between nanocrystals. Energy transfer from smaller nanocrystals to larger nanocrystals in aggregates is demonstrated by means of steady-state and time-resolved photoluminescence spectroscopy, paving the way for nanocrystal-based light harvesting structures in solution. Multi-shell onion-like CdSe/ZnS/CdSe/ZnS nanocrystals are presented. The shade of the white light can be controlled by annealing the particles. Evidence for intra

  18. VLAD for epithermal neutron scattering experiments at large energy transfers

    International Nuclear Information System (INIS)

    Tardocchi, M; Gorini, G; Perelli-Cippo, E; Andreani, C; Imberti, S; Pietropaolo, A; Senesi, R; Rhodes, N R; Schooneveld, E M

    2006-01-01

    The Very Low Angle Detector (VLAD) bank will extend the kinematical region covered by today's epithermal neutron scattering experiments to low momentum transfer ( -1 ) together with large energy transfer 0 -4 0 . In this paper the design of VLAD is presented together with Montecarlo simulations of the detector performances. The results of tests made with prototype VLAD detectors are also presented, confirming the usefulness of the Resonance Detector for measurements at very low scattering angles

  19. Energy from Biomass Research and Technology Transfer Program

    Energy Technology Data Exchange (ETDEWEB)

    Schumacher, Dorin

    2015-12-31

    The purpose of CPBR is to foster and facilitate research that will lead to commercial applications. The goals of CPBR’s Energy from Biomass Research and Technology Transfer Program are to bring together industry, academe, and federal resources to conduct research in plant biotechnology and other bio-based technologies and to facilitate the commercialization of the research results to: (1) improve the utilization of plants as energy sources; (2) reduce the cost of renewable energy production; (3) facilitate the replacement of petroleum by plant-based materials; (4) create an energy supply that is safer in its effect on the environment, and (5) contribute to U.S. energy independence.

  20. Plasmon-enhanced energy transfer for improved upconversion of infrared radiation in doped-lanthanide nanocrystals

    Science.gov (United States)

    Sun, Qi; Mundoor, Haridas; Ribot, Josep; Singh, Vivek; Smalyukh, Ivan; Nagpal, Prashant

    2014-03-01

    Upconversion of infrared radiation into visible light has been investigated for applications in biological imaging and photovoltaics. However, low conversion efficiency due to small absorption cross-section for infrared light (Yb3+) , and slow rate of energy transfer (to Er3+ states) has prevented application of upconversion photoluminescence (UPL) for diffuse sunlight or imaging tissue samples. Here, we utilize resonant surface plasmon polaritons (SPP) waves to enhance UPL in doped-lanthanide nanocrystals. Our analysis indicates that SPP waves not only enhance the electromagnetic field, and hence weak Purcell effect, but also increases the rate of resonant energy transfer from Yb3+ to Er3+ ions by 6 fold. While we do observe strong metal mediated quenching (14 fold) of green fluorescence on flat metal surfaces, the nanostructured metal is resonant in the infrared, and hence enhances the nanocrystal UPL. This strong columbic effect on energy transfer can have important implications for other fluorescent and excitonic systems too.

  1. Plasmon-enhanced energy transfer for improved upconversion of infrared radiation in doped-lanthanide nanocrystals.

    Science.gov (United States)

    Sun, Qi-C; Mundoor, Haridas; Ribot, Josep C; Singh, Vivek; Smalyukh, Ivan I; Nagpal, Prashant

    2014-01-08

    Upconversion of infrared radiation into visible light has been investigated for applications in photovoltaics and biological imaging. However, low conversion efficiency due to small absorption cross-section for infrared light (Yb(3+)), and slow rate of energy transfer (to Er(3+) states) has prevented application of upconversion photoluminescence (UPL) for diffuse sunlight or imaging tissue samples. Here, we utilize resonant surface plasmon polaritons (SPP) waves to enhance UPL in doped-lanthanide nanocrystals. Our analysis indicates that SPP waves not only enhance the electromagnetic field, and hence weak Purcell effect, but also increase the rate of resonant energy transfer from Yb(3+) to Er(3+) ions by 6 fold. While we do observe strong metal mediated quenching (14-fold) of green fluorescence on flat metal surfaces, the nanostructured metal is resonant in the infrared and hence enhances the nanocrystal UPL. This strong Coulombic effect on energy transfer can have important implications for other fluorescent and excitonic systems too.

  2. A new energy transfer model for turbulent free shear flow

    Science.gov (United States)

    Liou, William W.-W.

    1992-01-01

    A new model for the energy transfer mechanism in the large-scale turbulent kinetic energy equation is proposed. An estimate of the characteristic length scale of the energy containing large structures is obtained from the wavelength associated with the structures predicted by a weakly nonlinear analysis for turbulent free shear flows. With the inclusion of the proposed energy transfer model, the weakly nonlinear wave models for the turbulent large-scale structures are self-contained and are likely to be independent flow geometries. The model is tested against a plane mixing layer. Reasonably good agreement is achieved. Finally, it is shown by using the Liapunov function method, the balance between the production and the drainage of the kinetic energy of the turbulent large-scale structures is asymptotically stable as their amplitude saturates. The saturation of the wave amplitude provides an alternative indicator for flow self-similarity.

  3. Solar wind energy transfer through the magnetopause of an open magnetosphere

    International Nuclear Information System (INIS)

    Lee, L.C.; Roederer, J.G.

    1982-01-01

    An expression for the total power P/sub T/ transferred from the solar wind to an ''open'' magnetopause with a nonzero normal component of the magnetic field, which is identified as a rotational discontinuity. The total power P/sub T/ consists of (1) the power P/sub EM/ representing the electromagnetic energy transfer and (2) the power P/sub KE/ representing the rate of kinetic energy carried by particles penetrating into the magnetosphere. It is found that P/sub EM/approx. =V/sub SW/ B/sub SW/psi, P/sub KE/approx. =(1/2 M/sub A/-1) P/sub EM/ and P/sub T/approx. =1/2M/sub A/P/sub EM/, where V/sub SW/, B/sub SW/, and M/sub A/ are the velocity, magnetic field, and the Alfven--Mach number in the solar wind, respectively, and Psi is the open magnetic flux in the magnetosphere. The Alfven--Mach number of flow at the magnetopause determines the nature of the local energy transfer; the power per unit area transferred from the solar wind to the magnetosphere consists mainly of kinetic energy. The electromagnetic energy rate P/sub EM/ controls the near-earth magnetospheric activity, whereas the kinetic energy rate P/sub KE/(approx. =3--4 P/sub EM/) should dominate the dynamics of the distant magnetotail

  4. Advances in energy-transfer technology

    International Nuclear Information System (INIS)

    Terpstra, L.

    1992-01-01

    This paper discusses the technology of drying and curing inks, coatings and adhesives which is changing rapidly as converters and manufacturers strive to comply with regulations governing airborne emissions as well as discharge of liquid and solid wastes. Compliance with these regulations will become more difficult in the coming decade as the Clean Air Act's increasingly stringent limitations on emissions of volatile organic compounds are implemented to support the intentions of the Montreal protocol. Many of the customary solvents are being eliminated, and the volume of production for many others will be severely reduced. For some companies, the switch to the new materials means updating or replacing antiquated hot-air drying systems with high-velocity impingement ovens with higher temperature capabilities. Probably the least-expansive alternative to replacing the entire oven is to retrofit the installation with infrared (IR) energy in the form of separate predryers or postheaters or, in some cases, to install auxiliary IR heaters between the hot-air nozzles within the oven

  5. Intramolecular energy transfer and mode-specific effects in unimolecular reactions of 1,2-difluoroethane

    Science.gov (United States)

    Raff, Lionel M.

    1989-06-01

    The unimolecular decomposition reactions of 1,2-difluoroethane upon mode-specific excitation to a total internal energy of 7.5 eV are investigated using classical trajectory methods and a previously formulated empirical potential-energy surface. The decomposition channels for 1,2-difluoroethane are, in order of importance, four-center HF elimination, C-C bond rupture, and hydrogen-atom dissociation. This order is found to be independent of the particular vibrational mode excited. Neither fluorine-atom nor F2 elimination reactions are ever observed even though these dissociation channels are energetically open. For four-center HF elimination, the average fraction of the total energy partitioned into internal HF motion varies between 0.115-0.181 depending upon the particular vibrational mode initially excited. The internal energy of the fluoroethylene product lies in the range 0.716-0.776. Comparison of the present results with those previously obtained for a random distribution of the initial 1,2-difluoroethane internal energy [J. Phys. Chem. 92, 5111 (1988)], shows that numerous mode-specific effects are present in these reactions in spite of the fact that intramolecular energy transfer rates for this system are 5.88-25.5 times faster than any of the unimolecular reaction rates. Mode-specific excitation always leads to a total decomposition rate significantly larger than that obtained for a random distribution of the internal energy. Excitation of different 1,2-difluoroethane vibrational modes is found to produce as much as a 51% change in the total decomposition rate. Mode-specific effects are also seen in the product energy partitioning. The rate coefficients for decomposition into the various channels are very sensitive to the particular mode excited. A comparison of the calculated mode-specific effects with the previously determined mode-to-mode energy transfer rate coefficients [J. Chem. Phys. 89, 5680 (1988)] shows that, to some extent, the presence of mode

  6. Energy transfer processes in Er-doped crystals

    International Nuclear Information System (INIS)

    Georgescu, Serban; Toma, Octavian

    2005-01-01

    In this paper, the microparameters characteristic to various energy-transfer processes in erbium doped crystals are estimated using the Dexter theory. For all the investigated processes, electric dipole-dipole interaction between donor and acceptor ions is assumed. The spectra appearing in Dexter's expression of the microparameter are simulated as a superposition of Lorentzian lines, knowing the positions of both initial and final Stark levels, and calibrated using the Judd-Ofelt model. This approach can give an estimation of the importance of the energy-transfer processes. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  7. An estimate of spherical impactor energy transfer for mechanical frequency up-conversion energy harvester

    Directory of Open Access Journals (Sweden)

    L. R. Corr

    2016-08-01

    Full Text Available Vibration energy harvesters, which use the impact mechanical frequency up-conversion technique, utilize an impactor, which gains kinetic energy from low frequency ambient environmental vibrations, to excite high frequency systems that efficiently convert mechanical energy to electrical energy. To take full advantage of the impact mechanical frequency up-conversion technique, it is prudent to understand the energy transfer from the low frequency excitations, to the impactor, and finally to the high frequency systems. In this work, the energy transfer from a spherical impactor to a multi degree of freedom spring / mass system, due to Hertzian impact, is investigated to gain insight on how best to design impact mechanical frequency up-conversion energy harvesters. Through this academic work, it is shown that the properties of the contact (or impact area, i.e., radius of curvature and material properties, only play a minor role in energy transfer and that the equivalent mass of the target system (i.e., the spring / mass system dictates the total amount of energy transferred during the impact. The novel approach of utilizing the well-known Hertzian impact methodology to gain an understanding of impact mechanical frequency up-conversion energy harvesters has made it clear that the impactor and the high frequency energy generating systems must be designed together as one system to ensure maximum energy transfer, leading to efficient ambient vibration energy harvesters.

  8. Can nanophotonics control the Förster resonance energy transfer efficiency?

    DEFF Research Database (Denmark)

    Blum, C.; Zijlstra, N.; Lagendijk, A.

    2013-01-01

    from photovoltaics and lighting, to probing molecular distances and interactions.It is an intriguing open question whether the FRET rate γFRET and the energy transfer efficiency ηFRET can also be controlled by the nanoscale optical environment, characterized by the local density of optical states (LDOS...... precisely-defined, isolated, and efficient donor-acceptor pairs. The FRET pairs are dye molecules that covalently bound to the opposite ends of a 15 basepair long double-stranded with a precisely defined distance of 6.8 nm. Control over the LDOS is realized by positioning the FRET systems at well...... of the energy donor by the LDOS, the energy transfer efficiency can be enhanced or reduced. If a donor with unit quantum efficiency is placed in a 3D photonic bandgap, the energy transfer efficiency will approach 100 %, independent of the acceptor, and of the distances and orientations between the FRET partners....

  9. Ion-ion interaction and energy transfer of 4+ transuranium ions in cerium tetrafluoride

    International Nuclear Information System (INIS)

    Liu, G.K.; Beitz, J.V.

    1990-01-01

    Dynamics of excited 5f electron states of the transuranium ions Cm 4+ and Bk 4+ in CeF 4 are compared. Based on time- and wavelength-resolved laser-induced fluorescence, excitation energy transfer processes have been probed. Depending on concentration and electronic energy level structure of the studied 4+ transuranium ion, the dominant energy transfer mechanisms were identified as cross relaxation, exciton-exciton annihilation, and trapping. Energy transfer rates derived from the fitting of the observed fluorescence decays to theoretical models, based on electric multipolar ion-ion interactions, are contrasted with prior studies of 4f states of 3+ lanthanide and 3d states of transition metal ions. 16 refs., 1 tab

  10. Spectral Gap Energy Transfer in Atmospheric Boundary Layer

    Science.gov (United States)

    Bhushan, S.; Walters, K.; Barros, A. P.; Nogueira, M.

    2012-12-01

    Experimental measurements of atmospheric turbulence energy spectra show E(k) ~ k-3 slopes at synoptic scales (~ 600 km - 2000 km) and k-5/3 slopes at the mesoscales (theory, it is expected that a strong backward energy cascade would develop at the synoptic scale, and that circulation would grow infinitely. To limit this backward transfer, energy arrest at macroscales must be introduced. The most commonly used turbulence models developed to mimic the above energy transfer include the energy backscatter model for 2D turbulence in the horizontal plane via Large Eddy Simulation (LES) models, dissipative URANS models in the vertical plane, and Ekman friction for the energy arrest. One of the controversial issues surrounding the atmospheric turbulence spectra is the explanation of the generation of the 2D and 3D spectra and transition between them, for energy injection at the synoptic scales. Lilly (1989) proposed that the existence of 2D and 3D spectra can only be explained by the presence of an additional energy injection in the meso-scale region. A second issue is related to the observations of dual peak spectra with small variance in meso-scale, suggesting that the energy transfer occurs across a spectral gap (Van Der Hoven, 1957). Several studies have confirmed the spectral gap for the meso-scale circulations, and have suggested that they are enhanced by smaller scale vertical convection rather than by the synoptic scales. Further, the widely accepted energy arrest mechanism by boundary layer friction is closely related to the spectral gap transfer. This study proposes an energy transfer mechanism for atmospheric turbulence with synoptic scale injection, wherein the generation of 2D and 3D spectra is explained using spectral gap energy transfer. The existence of the spectral gap energy transfer is validated by performing LES for the interaction of large scale circulation with a wall, and studying the evolution of the energy spectra both near to and far from the wall

  11. Heat transfer rate within non-spherical thick grains

    Directory of Open Access Journals (Sweden)

    Huchet Florian

    2017-01-01

    Full Text Available The prediction of the internal heat conduction into non-spherical thick grains constitutes a significant issue for physical modeling of a large variety of application involving convective exchanges between fluid and grains. In that context, the present paper deals with heat rate measurements of various sizes of particles, the thermal sensors being located at the interface fluid/grain and into the granular materials. Their shape is designed as cuboid in order to control the surface exchanges. In enclosed coneshaped apparatus, a sharp temperature gradient is ensured from a hot source releasing the air stream temperature equal to about 400°C. Two orientations of grain related to the air stream are considered: diagonally and straight arrangements. The thermal diffusivity of the grains and the Biot numbers are estimated from an analytical solution established for slab. The thermal kinetics evolution is correlated to the sample granular mass and its orientation dependency is demonstrated. Consequently, a generalized scaling law is proposed which is funded from the effective area of the heat transfer at the grain-scale, the dimensionless time being defined from the calculated diffusional coefficients.

  12. Heat transfer rate within non-spherical thick grains

    Science.gov (United States)

    Huchet, Florian; Richard, Patrick; Joniot, Jules; Le Guen, Laurédan

    2017-06-01

    The prediction of the internal heat conduction into non-spherical thick grains constitutes a significant issue for physical modeling of a large variety of application involving convective exchanges between fluid and grains. In that context, the present paper deals with heat rate measurements of various sizes of particles, the thermal sensors being located at the interface fluid/grain and into the granular materials. Their shape is designed as cuboid in order to control the surface exchanges. In enclosed coneshaped apparatus, a sharp temperature gradient is ensured from a hot source releasing the air stream temperature equal to about 400°C. Two orientations of grain related to the air stream are considered: diagonally and straight arrangements. The thermal diffusivity of the grains and the Biot numbers are estimated from an analytical solution established for slab. The thermal kinetics evolution is correlated to the sample granular mass and its orientation dependency is demonstrated. Consequently, a generalized scaling law is proposed which is funded from the effective area of the heat transfer at the grain-scale, the dimensionless time being defined from the calculated diffusional coefficients.

  13. Modeling the efficiency of Förster resonant energy transfer from energy relay dyes in dye-sensitized solar cells

    KAUST Repository

    Hoke, Eric T.; Hardin, Brian E.; McGehee, Michael D.

    2010-01-01

    Förster resonant energy transfer can improve the spectral breadth, absorption and energy conversion efficiency of dye sensitized solar cells. In this design, unattached relay dyes absorb the high energy photons and transfer the excitation

  14. Electro-mechanical energy conversion system having a permanent magnet machine with stator, resonant transfer link and energy converter controls

    Science.gov (United States)

    Skeist, S. Merrill; Baker, Richard H.

    2006-01-10

    An electro-mechanical energy conversion system coupled between an energy source and an energy load comprising an energy converter device including a permanent magnet induction machine coupled between the energy source and the energy load to convert the energy from the energy source and to transfer the converted energy to the energy load and an energy transfer multiplexer to control the flow of power or energy through the permanent magnetic induction machine.

  15. A theoretical analysis on vibrational-energy transfers in gases

    International Nuclear Information System (INIS)

    Mastrocinque, G.

    1981-01-01

    In order to investigate the relationships between three-dimensional and colinear molecular-collision models with particular emphasis on the role of repulsive and attractive forces in vibrational-energy transfers in gases, a theoretical analysis is developed in this paper. A few known results - mainly the Cottrell and Ream equation, the Takayanagi and the Shin expressions of the transfer probability - relevant to repulsive-force-dominated processes are obtained and/or discussed in the proposed frame. Light is also given on long-range, attractive-forces-dominated processes. The main result of this investigation is that, when a suitable hypothesis is done on the transfer probability, centrifugal effects on the intermolecular trajectories due to standard potentials are negligible in the low-temperature range. A quasi-colinear collision model, which is found to be correlated to the Cottrell and Ream expression for the transfer probability, is regained from a three-dimensional geometry in these conditions. (author)

  16. A Design Study Of A Wireless Power Transfer System For Use To Transfer Energy From A Vibration Energy Harvester

    Science.gov (United States)

    Grabham, N. J.; Harden, C.; Vincent, D.; Beeby, S. P.

    2016-11-01

    A wirelessly powered remote sensor node is presented along with its design process. The purpose of the node is the further expansion of the sensing capabilities of the commercial Perpetuum system used for condition monitoring on trains and rolling stock which operates using vibration energy harvesting. Surplus harvested vibration energy is transferred wirelessly to a remote satellite sensor to allow measurements over a wider area to be made. This additional data is to be used for long term condition monitoring. Performance measurements made on the prototype remote sensor node are reported and advantages and disadvantages of using the same RF frequency for power and data transfer are identified.

  17. Direct observation of coherent energy transfer in nonlinear micromechanical oscillators.

    Science.gov (United States)

    Chen, Changyao; Zanette, Damián H; Czaplewski, David A; Shaw, Steven; López, Daniel

    2017-05-26

    Energy dissipation is an unavoidable phenomenon of physical systems that are directly coupled to an external environmental bath. In an oscillatory system, it leads to the decay of the oscillation amplitude. In situations where stable oscillations are required, the energy dissipated by the vibrations is usually compensated by replenishment from external energy sources. Consequently, if the external energy supply is removed, the amplitude of oscillations start to decay immediately, since there is no means to restitute the energy dissipated. Here, we demonstrate a novel dissipation engineering strategy that can support stable oscillations without supplying external energy to compensate losses. The fundamental intrinsic mechanism of resonant mode coupling is used to redistribute and store mechanical energy among vibrational modes and coherently transfer it back to the principal mode when the external excitation is off. To experimentally demonstrate this phenomenon, we exploit the nonlinear dynamic response of microelectromechanical oscillators to couple two different vibrational modes through an internal resonance.

  18. Computational study of energy transfer in two-dimensional J-aggregates

    International Nuclear Information System (INIS)

    Gallos, Lazaros K.; Argyrakis, Panos; Lobanov, A.; Vitukhnovsky, A.

    2004-01-01

    We perform a computational analysis of the intra- and interband energy transfer in two-dimensional J-aggregates. Each aggregate is represented as a two-dimensional array (LB-film or self-assembled film) of two kinds of cyanine dyes. We consider the J-aggregate whose J-band is located at a shorter wavelength to be a donor and an aggregate or a small impurity with longer wavelength to be an acceptor. Light absorption in the blue wing of the donor aggregate gives rise to the population of its excitonic states. The depopulation of these states is possible by (a) radiative transfer to the ground state (b) intraband energy transfer, and (c) interband energy transfer to the acceptor. We study the dependence of energy transfer on properties such as the energy gap, the diagonal disorder, and the exciton-phonon interaction strength. Experimentally observable parameters, such as the position and form of luminescence spectrum, and results of the kinetic spectroscopy measurements strongly depend upon the density of states in excitonic bands, rates of energy exchange between states and oscillator strengths for luminescent transitions originating from these states

  19. The charge transfer structure and effective energy transfer in multiplayer assembly film

    International Nuclear Information System (INIS)

    Li Mingqiang; Jian Xigao

    2005-01-01

    Charge transfer multiplayer films have been prepared by layer-by-layer self-assembly technique. The films incorporate the rare-earth-containing polyoxometalate K 11 [Eu{PW 11 O 39 } 2 ].nH 2 O and the rich electron polyelectrolyte poly(3-viny-1-methyl-pyridine) quaternary ammonium and display a linear increase in the absorption and film thickness with the number of deposition cycles. Ultraviolet and visible absorption spectra, atomic force micrographs, small-angle X-ray reflectivity measurements, and photoluminescence spectra were used to determine the structure of films. Linear and regular multilayer growth was observed. We can observe the formation of charge transfer complex compound in multiplayer by layer-by-layer assembly method. Most importantly, the luminescence spectra show the charge transfer band in assembly films, which suggest that energy could be effectively transferred to rare earth ions in assembly multiplayer films

  20. Factors affecting conception rates in cattle following embryo transfer ...

    African Journals Online (AJOL)

    Embryo Transfer Technology (ETT) plays an important role in improving productivity of dairy cattle (Bos indicus). Embryo Transfer Technology allows top quality female livestock to improve a herd or flock in much the same way that artificial insemination has allowed greater use of superior sires. The technology hastens ...

  1. Novel DNA sequence detection method based on fluorescence energy transfer

    International Nuclear Information System (INIS)

    Kobayashi, S.; Tamiya, E.; Karube, I.

    1987-01-01

    Recently the detection of specific DNA sequence, DNA analysis, has been becoming more important for diagnosis of viral genomes causing infections disease and human sequences related to inherited disorders. These methods typically involve electrophoresis, the immobilization of DNA on a solid support, hybridization to a complementary probe, the detection using labeled with /sup 32/P or nonisotopically with a biotin-avidin-enzyme system, and so on. These techniques are highly effective, but they are very time-consuming and expensive. A principle of fluorescene energy transfer is that the light energy from an excited donor (fluorophore) is transferred to an acceptor (fluorophore), if the acceptor exists in the vicinity of the donor and the excitation spectrum of donor overlaps the emission spectrum of acceptor. In this study, the fluorescence energy transfer was applied to the detection of specific DNA sequence using the hybridization method. The analyte, single-stranded DNA labeled with the donor fluorophore is hybridized to a probe DNA labeled with the acceptor. Because of the complementary DNA duplex formation, two fluorophores became to be closed to each other, and the fluorescence energy transfer was occurred

  2. Accurate magnetic field calculations for contactless energy transfer coils

    NARCIS (Netherlands)

    Sonntag, C.L.W.; Spree, M.; Lomonova, E.A.; Duarte, J.L.; Vandenput, A.J.A.

    2007-01-01

    In this paper, a method for estimating the magnetic field intensity from hexagon spiral windings commonly found in contactless energy transfer applications is presented. The hexagonal structures are modeled in a magneto-static environment using Biot-Savart current stick vectors. The accuracy of the

  3. Metaphors Describing Energy Transfer through Ecosystems: Helpful or Misleading?

    Science.gov (United States)

    Wernecke, Ulrike; Schwanewedel, Julia; Harms, Ute

    2018-01-01

    Energy transfer in ecosystems is an abstract and challenging topic for learners. Metaphors are widely used in scientific and educational discourse to communicate ideas about abstract phenomena. However, although considered valuable teaching tools, metaphors are ambiguous and can be misleading when used in educational contexts. Educational…

  4. Reversible Energy Transfer and Fluorescence Decay in Solid Solutions

    Science.gov (United States)

    Shealy, David L.; Hoover, Richard B.; Gabardi, David R.

    1988-07-01

    The article deals with the influence of reversible excitation energy transfer on the fluorescence decay in systems with random distribution of molecules. On the basis of a hopping model, we have obtained an expression for the Laplace transform of the decay function and an expression for the average decay time. The case of dipole-dipole interaction is discussed in detail.

  5. Femtosecond carotenoid to retinal energy transfer in xanthorhodopsin

    Czech Academy of Sciences Publication Activity Database

    Polívka, Tomáš; Balashov, S.P.; Chábera, P.; Imasheva, E.S.; Yartsev, A.; Sundström, V.; Lanyi, J.K.

    2009-01-01

    Roč. 96, č. 6 (2009), s. 2268-2277 ISSN 0006-3495 R&D Projects: GA AV ČR IAA608170604 Institutional research plan: CEZ:AV0Z50510513 Keywords : energy transfer * carotenoids * femtosecond spectroscopy Subject RIV: BO - Biophysics Impact factor: 4.390, year: 2009

  6. Ultrafast electron and energy transfer in dye-sensitized iron oxide and oxyhydroxide nanoparticles

    DEFF Research Database (Denmark)

    Gilbert, Benjamin; Katz, Jordan E.; Huse, Nils

    2013-01-01

    photo-initiated interfacial electron transfer. This approach enables time-resolved study of the fate and mobility of electrons within the solid phase. However, complete analysis of the ultrafast processes following dye photoexcitation of the sensitized iron(iii) oxide nanoparticles has not been reported....... We addressed this topic by performing femtosecond transient absorption (TA) measurements of aqueous suspensions of uncoated and DCF-sensitized iron oxide and oxyhydroxide nanoparticles, and an aqueous iron(iii)–dye complex. Following light absorption, excited state relaxation times of the dye of 115...... a four-state model of the dye-sensitized system, finding electron and energy transfer to occur on the same ultrafast timescale. The interfacial electron transfer rates for iron oxides are very close to those previously reported for DCF-sensitized titanium dioxide (for which dye–oxide energy transfer...

  7. Wireless energy transfer: Dielectric lens antennas for beam shaping in wireless power-transfer applications

    Science.gov (United States)

    Gonçalves, Ricardo; Carvalho, Nuno B.; Pinho, Pedro

    2017-02-01

    In the current contest of wireless systems, the last frontier remains the cut of the power cord. In that sense, the interest over wireless energy transfer technologies in the past years has grown exponentially. However, there are still many challenges to be overcome in order to enable wireless energy transfer full potential. One of the focus in the development of such systems is the design of very-high-gain, highly efficient, antennas that can compensate for the propagation loss of radio signals over the air. In this paper, we explore the design and manufacturing process of dielectric lenses, fabricated using a professional-grade desktop 3D printer. Lens antennas are used in order to increase beam efficiency and therefore maximize the efficiency of a wireless power-transfer system operating at microwave frequencies in the Ku band. Measurements of two fabricated prototypes showcase a large directivity, as predicted with simulations. xml:lang="fr"

  8. Energy transfer in diatom/diatom molecular collisions

    International Nuclear Information System (INIS)

    Sohlberg, K.W.

    1992-01-01

    In a collision of two molecules, the translational energy of the collision may be redistributed into internal energy of rotation, vibration, or electron motion, in one or both of the colliding partners. In addition, internal energy in one or more of these modes may be open-quotes quenchedclose quotes into translation, leading to a superelastic collision. Such energy transfer may take place by a number of mechanisms. This energy transfer is of fundamental importance in understanding chemical reaction dynamics. Nearly all chemical reactions take place through a bimolecular collision process (or multiple bimolecular collisions) and the quantum state specificity of the reaction can have a major role in determining the kinetics of the reaction, In particular, the author has investigated vibrational energy transfer in collisions between two diatomic molecules. In addition to serving as models for all molecular collision process, gas phase collisions of these species are ubiquitous in atmospheric phenomena which are of critical importance in answering the current questions about the human induced degradation of the earth's atmospheric. Classical trajectory methods have been used to explore the excitation of vibrations in gas-phase collisions of the nitrogen molecular ion with its parent molecule. The near symmetry of the reactants is shown to result in a high probability that the two molecules are excited by an equal amount of energy. This provides a possible explanation of the molecular beam measurements which show that the total number of vibrational energy quanta excited in the collision is, with a high probability that the two molecules are excited by an equal amount of energy. This provides a possible explanation of the molecular beam measurements which show that the total number of vibrational energy quanta excited in the collision is, with a high probability, even

  9. Electron transfer and energy transfer reactions in photoexcited a-nonathiophene/C60 films and solutions

    NARCIS (Netherlands)

    Janssen, R.A.J.; Moses, D.; Sariciftci, N.S.; Heeger, A.J.

    1994-01-01

    Photoexcitation of a nonathiophene in film or solution across the p-p* energy gap produces a metastable triplet state. In the presence of C60, on the other hand, an ultra fast electron transfer from the photoexcited nonathiophene onto C60 is observed in films, whereas in solution C60 is involved in

  10. RF Power Transfer, Energy Harvesting, and Power Management Strategies

    Science.gov (United States)

    Abouzied, Mohamed Ali Mohamed

    Energy harvesting is the way to capture green energy. This can be thought of as a recycling process where energy is converted from one form (here, non-electrical) to another (here, electrical). This is done on the large energy scale as well as low energy scale. The former can enable sustainable operation of facilities, while the latter can have a significant impact on the problems of energy constrained portable applications. Different energy sources can be complementary to one another and combining multiple-source is of great importance. In particular, RF energy harvesting is a natural choice for the portable applications. There are many advantages, such as cordless operation and light-weight. Moreover, the needed infra-structure can possibly be incorporated with wearable and portable devices. RF energy harvesting is an enabling key player for Internet of Things technology. The RF energy harvesting systems consist of external antennas, LC matching networks, RF rectifiers for ac to dc conversion, and sometimes power management. Moreover, combining different energy harvesting sources is essential for robustness and sustainability. Wireless power transfer has recently been applied for battery charging of portable devices. This charging process impacts the daily experience of every human who uses electronic applications. Instead of having many types of cumbersome cords and many different standards while the users are responsible to connect periodically to ac outlets, the new approach is to have the transmitters ready in the near region and can transfer power wirelessly to the devices whenever needed. Wireless power transfer consists of a dc to ac conversion transmitter, coupled inductors between transmitter and receiver, and an ac to dc conversion receiver. Alternative far field operation is still tested for health issues. So, the focus in this study is on near field. The goals of this study are to investigate the possibilities of RF energy harvesting from various

  11. Energy density and rate limitations in structural composite supercapacitors

    Science.gov (United States)

    Snyder, J. F.; Gienger, E.; Wetzel, E. D.; Xu, K.

    2012-06-01

    The weight and volume of conventional energy storage technologies greatly limits their performance in mobile platforms. Traditional research efforts target improvements in energy density to reduce device size and mass. Enabling a device to perform additional functions, such as bearing mechanical load, is an alternative approach as long as the total mass efficiency exceeds that of the individual materials it replaces. Our research focuses on structural composites that function as batteries and supercapacitors. These multifunctional devices could be used to replace conventional structural components, such as vehicle frame elements, to provide significant system-level weight reductions and extend mission times. Our approach is to design structural properties directly into the electrolyte and electrode materials. Solid polymer electrolyte materials bind the system and transfer load to the fibers while conducting ions between the electrodes. Carbon fiber electrodes provide a route towards optimizing both energy storage and load-bearing capabilities, and may also obviate the need for a separate current collector. The components are being integrated using scalable, cost-effective composite processing techniques that are amenable to complex part shapes. Practical considerations of energy density and rate behavior are described here as they relate to materials used. Our results highlight the viability as well as the challenges of this multifunctional approach towards energy storage.

  12. Energy Efficient Beam Transfer Channels for High Energy Particle Accelerators

    CERN Document Server

    Gardlowski, Philipp; Ondreka, David

    2016-01-01

    conducting (NC) magnets or high current pulsed (HCP) magnets are an economic solution. For high repetition rates above 1.0 Hz, superconducting Cos(N) (SC) magnets or superferric (SF) magnets are more attractive; at least if they are operated in DC mode and if no dynamic losses occur in the cryogenic system. Unfortunately, a range between these values exist, in which no...

  13. The surface-forming energy release rate versus the local energy release rate

    OpenAIRE

    Xiao, Si; Wang, He-ling; Landis, Chad M; Hwang, Keh-Chih; Liu, Bin

    2016-01-01

    This paper identifies two ways to extract the energy (or power) flowing into a crack tip during propagation based on the power balance of areas enclosed by a stationary contour and a comoving contour. It is very interesting to find a contradiction that two corresponding energy release rates (ERRs), a surface-forming ERR and a local ERR, are different when stress singularity exists at a crack tip. Besides a rigorous mathematical interpretation, we deduce that the stress singularity leads to an...

  14. The transfer of technologies for biomass energy utilization

    Energy Technology Data Exchange (ETDEWEB)

    Schneiders, H H [German Agency for Technical Cooperation (GTZ), Eschborn (Germany)

    1995-12-01

    The first part of the paper presents the common perception of technology transfer as a trade relationship rather than a systematic approach to establish a complex technological capacity in a given field. It aims to correct this misperception by introducing some other ideas: (a) the need to support the people, adjust the relevant organizations and establish the capacities to provide the products and services; (b) the typical life cycles of technologies from the initial concept to the final stages of transfer and sustainable dissemination; (c) the needs and expectations of the groups targeted by the technologies for biomass energy utilization. The second part of the paper discusses one example of successful technology transfer: the use of large biomass-burning stoves for food preparation in public institutions and private restaurants in East Africa. The third part of the paper highlights two non-technological barriers to the transfer of biomass energy technologies: (a) weak market forces and business interests and a large number of State activities and projects and (b) conflicting interests of end-users, craftsmen, private and public project partners, which can threaten the success of the attempted technology transfer, even after local adaptation. Finally, suggestions are made for overcoming some of these problems. (author)

  15. The transfer of technologies for biomass energy utilization

    International Nuclear Information System (INIS)

    Schneiders, H.H.

    1995-01-01

    The first part of the paper presents the common perception of technology transfer as a trade relationship rather than a systematic approach to establish a complex technological capacity in a given field. It aims to correct this misperception by introducing some other ideas: (a) the need to support the people, adjust the relevant organizations and establish the capacities to provide the products and services; (b) the typical life cycles of technologies from the initial concept to the final stages of transfer and sustainable dissemination; (c) the needs and expectations of the groups targeted by the technologies for biomass energy utilization. The second part of the paper discusses one example of successful technology transfer: the use of large biomass-burning stoves for food preparation in public institutions and private restaurants in East Africa. The third part of the paper highlights two non-technological barriers to the transfer of biomass energy technologies: (a) weak market forces and business interests and a large number of State activities and projects and (b) conflicting interests of end-users, craftsmen, private and public project partners, which can threaten the success of the attempted technology transfer, even after local adaptation. Finally, suggestions are made for overcoming some of these problems. (author)

  16. Wireless energy transfer platform for medical sensors and implantable devices.

    Science.gov (United States)

    Zhang, Fei; Hackworth, Steven A; Liu, Xiaoyu; Chen, Haiyan; Sclabassi, Robert J; Sun, Mingui

    2009-01-01

    Witricity is a newly developed technique for wireless energy transfer. This paper presents a frequency adjustable witricity system to power medical sensors and implantable devices. New witricity resonators are designed for both energy transmission and reception. A prototype platform is described, including an RF power source, two resonators with new structures, and inductively coupled input and output stages. In vitro experiments, both in open air and using a human head phantom consisting of simulated tissues, are employed to verify the feasibility of this platform. An animal model is utilized to evaluate in vivo energy transfer within the body of a laboratory pig. Our experiments indicate that witricity is an effective new tool for providing a variety of medical sensors and devices with power.

  17. Long range energy transfer in graphene hybrid structures

    International Nuclear Information System (INIS)

    Gonçalves, Hugo; Bernardo, César; Moura, Cacilda; Belsley, Michael; Schellenberg, Peter; Ferreira, R A S; André, P S; Stauber, Tobias

    2016-01-01

    In this work we quantify the distance dependence for the extraction of energy from excited chromophores by a single layer graphene flake over a large separation range. To this end hybrid structures were prepared, consisting of a thin (2 nm) layer of a polymer matrix doped with a well chosen strongly fluorescent organic molecule, followed by an un-doped spacer layer of well-defined thicknesses made of the same polymer material and an underlying single layer of pristine, undoped graphene. The coupling strength is assessed through the variation of the fluorescence decay kinetics as a function of distance between the graphene and the excited chromophore molecules. Non-radiative energy transfer to the graphene was observed at distances of up to 60 nm; a range much greater than typical energy transfer distances observed in molecular systems. (paper)

  18. Direct observation of triplet energy transfer from semiconductor nanocrystals.

    Science.gov (United States)

    Mongin, Cédric; Garakyaraghi, Sofia; Razgoniaeva, Natalia; Zamkov, Mikhail; Castellano, Felix N

    2016-01-22

    Triplet excitons are pervasive in both organic and inorganic semiconductors but generally remain confined to the material in which they originate. We demonstrated by transient absorption spectroscopy that cadmium selenide semiconductor nanoparticles, selectively excited by green light, engage in interfacial Dexter-like triplet-triplet energy transfer with surface-anchored polyaromatic carboxylic acid acceptors, extending the excited-state lifetime by six orders of magnitude. Net triplet energy transfer also occurs from surface acceptors to freely diffusing molecular solutes, further extending the lifetime while sensitizing singlet oxygen in an aerated solution. The successful translation of triplet excitons from semiconductor nanoparticles to the bulk solution implies that such materials are generally effective surrogates for molecular triplets. The nanoparticles could thereby potentially sensitize a range of chemical transformations that are relevant for fields as diverse as optoelectronics, solar energy conversion, and photobiology. Copyright © 2016, American Association for the Advancement of Science.

  19. State-of-the-Art Developments of Acoustic Energy Transfer

    Directory of Open Access Journals (Sweden)

    Md Rabiul Awal

    2016-01-01

    Full Text Available Acoustic energy transfer (AET technology has drawn significant industrial attention recently. This paper presents the reviews of the existing AETs sequentially, preferably, from the early stage. From the review, it is evident that, among all the classes of wireless energy transfer, AET is the safest technology to adopt. Thus, it is highly recommended for sensitive area and devices, especially implantable devices. Though, the efficiency for relatively long distances (i.e., >30 mm is less than that of inductive or capacitive power transfer; however, the trade-off between safety considerations and performances is highly suitable and better than others. From the presented statistics, it is evident that AET is capable of transmitting 1.068 kW and 5.4 W of energy through wall and in-body medium (implants, respectively. Progressively, the AET efficiency can reach up to 88% in extension to 8.6 m separation distance which is even superior to that of inductive and capacitive power transfer.

  20. Photon-exchange energy transfer of an electron–hole plasma between quasi-two-dimensional semiconductor layers

    International Nuclear Information System (INIS)

    Lyo, S.K.

    2012-01-01

    Photon-mediated energy transfer is shown to play an important role for transfer of an electron–hole plasma between two quasi-two-dimensional quantum wells separated by a wide barrier. The magnitude and the dependence of the transfer rate of an electron–hole plasma on the temperature, the well-to-well distance, and the plasma density are compared with those of the standard Förster (i.e., dipolar) rate and also with the exciton transfer rate. The plasma transfer rate through the photon-exchange mechanism decays very slowly as a function of the well-to-well distance and is larger than the dipolar rate except for short distances. The transfer rate of plasmas saturates at high densities and decays rapidly with the temperature. - Highlights: ► We study energy transfer (ET) between two two-dimensional semiconductor quantum wells. ► We compare the ET rates of an electron–hole plasma (at a high density) and Mott excitons. ► We show that the proposed photon-exchange rate is practically dominant over the Förster rate. ► We examine the dependences of the ET rate on the temperature, density, and well-to-well distance.

  1. TRANSFER

    African Journals Online (AJOL)

    This paper reports on further studies on long range energy transfer between curcumine as donor and another thiazine dye, thionine, which is closely related to methylene blue as energy harvester (Figure 1). Since thionine is known to have a higher quantum yield of singlet oxygen sensitization than methylene blue [8], it is ...

  2. Liability aspects of home energy-rating systems

    Energy Technology Data Exchange (ETDEWEB)

    Hendrickson, P.L.

    1983-10-01

    Liability aspects of home energy rating systems are discussed. An introduction to the rating system concept, including types of rating systems, implementation efforts to date, and possible groups to conduct ratings, is also included. The home energy rating system concept involves the periodic rating of the energy efficiency of residential buildings. The rating can provide a relative indication of a home's energy efficiency and also a quantitative estimate of consumption, fuel cost, or both. Primary attention is given to liability issues associated with developing and performing ratings. Secondary attention is given to possible liability associated with misuse of a rating once it has been performed.

  3. Graphene-based chemiluminescence resonance energy transfer for homogeneous immunoassay.

    Science.gov (United States)

    Lee, Joon Seok; Joung, Hyou-Arm; Kim, Min-Gon; Park, Chan Beum

    2012-04-24

    We report on chemiluminescence resonance energy transfer (CRET) between graphene nanosheets and chemiluminescent donors. In contrast to fluorescence resonance energy transfer, CRET occurs via nonradiative dipole-dipole transfer of energy from a chemiluminescent donor to a suitable acceptor molecule without an external excitation source. We designed a graphene-based CRET platform for homogeneous immunoassay of C-reactive protein (CRP), a key marker for human inflammation and cardiovascular diseases, using a luminol/hydrogen peroxide chemiluminescence (CL) reaction catalyzed by horseradish peroxidase. According to our results, anti-CRP antibody conjugated to graphene nanosheets enabled the capture of CRP at the concentration above 1.6 ng mL(-1). In the CRET platform, graphene played a key role as an energy acceptor, which was more efficient than graphene oxide, while luminol served as a donor to graphene, triggering the CRET phenomenon between luminol and graphene. The graphene-based CRET platform was successfully applied to the detection of CRP in human serum samples in the range observed during acute inflammatory stress.

  4. 2013 MOLECULAR ENERGY TRANSFER GORDON RESEARCH CONFERENCE (JANUARY 13-18, 2013 - VENTURA BEACH MARRIOTT, VENTURA CA

    Energy Technology Data Exchange (ETDEWEB)

    Reid, Scott A. [Marquette University

    2012-10-18

    Sessions covered all areas of molecular energy transfer, with 10 sessions of talks and poster sessions covering the areas of :  Energy Transfer in Inelastic and Reactive Scattering  Energy Transfer in Photoinitiated and Unimolecular Reactions  Non-adiabatic Effects in Energy TransferEnergy Transfer at Surfaces and Interfaces  Energy Transfer in Clusters, Droplets, and Aerosols  Energy Transfer in Solution and Solid  Energy Transfer in Complex Systems  Energy Transfer: New vistas and horizons  Molecular Energy Transfer: Where Have We Been and Where are We Going?

  5. Oxygen transfer rate identifies priming compounds in parsley cells.

    Science.gov (United States)

    Schilling, Jana Viola; Schillheim, Britta; Mahr, Stefan; Reufer, Yannik; Sanjoyo, Sandi; Conrath, Uwe; Büchs, Jochen

    2015-11-25

    In modern agriculture, the call for an alternative crop protection strategy increases because of the desired reduction of fungicide and pesticide use and the continuously evolving resistance of pathogens and pests to agrochemicals. The direct activation of the plant immune system does not provide a promising plant protection measure because of high fitness costs. However, upon treatment with certain natural or synthetic compounds, plant cells can promote to a fitness cost-saving, primed state of enhanced defense. In the primed state, plants respond to biotic and abiotic stress with faster and stronger activation of defense, and this is often associated with immunity and abiotic stress tolerance. Until now, the identification of chemical compounds with priming-inducing activity (so-called plant activators) relied on tedious and invasive approaches, or required the late detection of secreted furanocoumarin phytoalexins in parsley cell cultures. Thus, simple, fast, straightforward, and noninvasive techniques for identifying priming-inducing compounds for plant protection are very welcome. This report demonstrates that a respiration activity-monitoring system (RAMOS) can identify compounds with defense priming-inducing activity in parsley cell suspension in culture. RAMOS relies on the quasi-continuous, noninvasive online determination of the oxygen transfer rate (OTR). Treatment of parsley culture cells with the known plant activator salicylic acid (SA), a natural plant defense signal, resulted in an OTR increase. Addition of the defense elicitor Pep13, a cell wall peptide of Phythophthora sojae, induced two distinctive OTR peaks that were higher in SA-primed cells than in unprimed cells upon Pep13 challenge. Both, the OTR increase after priming with SA and the Pep13 challenge were dose-dependent. Furthermore, there was a close correlation of a compound's activity to enhance the oxygen consumption in parsley cells and its capacity to prime Pep13-induced furanocoumarin

  6. Morphing continuum analysis of energy transfer in compressible turbulence

    Science.gov (United States)

    Cheikh, Mohamad Ibrahim; Wonnell, Louis B.; Chen, James

    2018-02-01

    A shock-preserving finite volume solver with the generalized Lax-Friedrichs splitting flux for morphing continuum theory (MCT) is presented and verified. The numerical MCT solver is showcased in a supersonic turbulent flow with Mach 2.93 over an 8∘ compression ramp. The simulation results validated MCT with experiments as an alternative for modeling compressible turbulence. The required size of the smallest mesh cell for the MCT simulation is shown to be almost an order larger than that in a similar direct numerical simulation study. The comparison shows MCT is a much more computationally friendly theory than the classical Navier-Stokes equations. The dynamics of energy cascade at the length scale of individual eddies is illuminated through the subscale rotation introduced by MCT. In this regard, MCT provides a statistical averaging procedure for capturing energy transfer in compressible turbulence, not found in classical fluid theories. Analysis of the MCT results show the existence of a statistical coupling of the internal and translational kinetic energy fluctuations with the corresponding eddy rotational energy fluctuations, indicating a multiscale transfer of energy. In conclusion, MCT gives a new characterization of the energy cascade within compressible turbulence without the use of excessive computational resources.

  7. Excitonic energy transfer in light-harvesting complexes in purple bacteria

    International Nuclear Information System (INIS)

    Ye Jun; Sun Kewei; Zhao Yang; Lee, Chee Kong; Yu Yunjin; Cao Jianshu

    2012-01-01

    Two distinct approaches, the Frenkel-Dirac time-dependent variation and the Haken-Strobl model, are adopted to study energy transfer dynamics in single-ring and double-ring light-harvesting (LH) systems in purple bacteria. It is found that the inclusion of long-range dipolar interactions in the two methods results in significant increase in intra- or inter-ring exciton transfer efficiency. The dependence of exciton transfer efficiency on trapping positions on single rings of LH2 (B850) and LH1 is similar to that in toy models with nearest-neighbor coupling only. However, owing to the symmetry breaking caused by the dimerization of BChls and dipolar couplings, such dependence has been largely suppressed. In the studies of coupled-ring systems, both methods reveal an interesting role of dipolar interactions in increasing energy transfer efficiency by introducing multiple intra/inter-ring transfer paths. Importantly, the time scale (4 ps) of inter-ring exciton transfer obtained from polaron dynamics is in good agreement with previous studies. In a double-ring LH2 system, non-nearest neighbor interactions can induce symmetry breaking, which leads to global and local minima of the average trapping time in the presence of a non-zero dephasing rate, suggesting that environment dephasing helps preserve quantum coherent energy transfer when the perfect circular symmetry in the hypothetic system is broken. This study reveals that dipolar coupling between chromophores may play an important role in the high energy transfer efficiency in the LH systems of purple bacteria and many other natural photosynthetic systems.

  8. Excitonic energy transfer in light-harvesting complexes in purple bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Ye Jun; Sun Kewei; Zhao Yang; Lee, Chee Kong [School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Yu Yunjin [School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 (Singapore); College of Physics Science and Technology, Shenzhen University, Guangdong 518060 (China); Cao Jianshu [Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

    2012-06-28

    Two distinct approaches, the Frenkel-Dirac time-dependent variation and the Haken-Strobl model, are adopted to study energy transfer dynamics in single-ring and double-ring light-harvesting (LH) systems in purple bacteria. It is found that the inclusion of long-range dipolar interactions in the two methods results in significant increase in intra- or inter-ring exciton transfer efficiency. The dependence of exciton transfer efficiency on trapping positions on single rings of LH2 (B850) and LH1 is similar to that in toy models with nearest-neighbor coupling only. However, owing to the symmetry breaking caused by the dimerization of BChls and dipolar couplings, such dependence has been largely suppressed. In the studies of coupled-ring systems, both methods reveal an interesting role of dipolar interactions in increasing energy transfer efficiency by introducing multiple intra/inter-ring transfer paths. Importantly, the time scale (4 ps) of inter-ring exciton transfer obtained from polaron dynamics is in good agreement with previous studies. In a double-ring LH2 system, non-nearest neighbor interactions can induce symmetry breaking, which leads to global and local minima of the average trapping time in the presence of a non-zero dephasing rate, suggesting that environment dephasing helps preserve quantum coherent energy transfer when the perfect circular symmetry in the hypothetic system is broken. This study reveals that dipolar coupling between chromophores may play an important role in the high energy transfer efficiency in the LH systems of purple bacteria and many other natural photosynthetic systems.

  9. Quantum dot-dye hybrid systems for energy transfer applications

    International Nuclear Information System (INIS)

    Ren, Ting

    2010-01-01

    In this thesis, we focus on the preparation of energy transfer-based quantum dot (QD)-dye hybrid systems. Two kinds of QD-dye hybrid systems have been successfully synthesized: QD-silica-dye and QD-dye hybrid systems. In the QD-silica-dye hybrid system, multishell CdSe/CdS/ZnS QDs were adsorbed onto monodisperse Stoeber silica particles with an outer silica shell of thickness 2-24 nm containing organic dye molecules (Texas Red). The thickness of this dye layer has a strong effect on the total sensitized acceptor emission, which is explained by the increase in the number of dye molecules homogeneously distributed within the silica shell, in combination with an enhanced surface adsorption of QDs with increasing dye amount. Our conclusions were underlined by comparison of the experimental results with Monte-Carlo simulations, and by control experiments confirming attractive interactions between QDs and Texas Red freely dissolved in solution. New QD-dye hybrid system consisting of multishell QDs and organic perylene dyes have been synthesized. We developed a versatile approach to assemble extraordinarily stable QD-dye hybrids, which uses dicarboxylate anchors to bind rylene dyes to QD. This system yields a good basis to study the energy transfer between QD and dye because of its simple and compact design: there is no third kind of molecule linking QD and dye; no spacer; and the affinity of the functional group to the QD surface is strong. The FRET signal was measured for these complexes as a function of both dye to QD ratio and center-to-center distance between QD and dye by controlling number of covered ZnS layers. Data showed that fluorescence resonance energy transfer (FRET) was the dominant mechanism of the energy transfer in our QD-dye hybrid system. FRET efficiency can be controlled by not only adjusting the number of dyes on the QD surface or the QD to dye distance, but also properly choosing different dye and QD components. Due to the strong stability, our QD

  10. Quantum dot-dye hybrid systems for energy transfer applications

    Energy Technology Data Exchange (ETDEWEB)

    Ren, Ting

    2010-07-01

    In this thesis, we focus on the preparation of energy transfer-based quantum dot (QD)-dye hybrid systems. Two kinds of QD-dye hybrid systems have been successfully synthesized: QD-silica-dye and QD-dye hybrid systems. In the QD-silica-dye hybrid system, multishell CdSe/CdS/ZnS QDs were adsorbed onto monodisperse Stoeber silica particles with an outer silica shell of thickness 2-24 nm containing organic dye molecules (Texas Red). The thickness of this dye layer has a strong effect on the total sensitized acceptor emission, which is explained by the increase in the number of dye molecules homogeneously distributed within the silica shell, in combination with an enhanced surface adsorption of QDs with increasing dye amount. Our conclusions were underlined by comparison of the experimental results with Monte-Carlo simulations, and by control experiments confirming attractive interactions between QDs and Texas Red freely dissolved in solution. New QD-dye hybrid system consisting of multishell QDs and organic perylene dyes have been synthesized. We developed a versatile approach to assemble extraordinarily stable QD-dye hybrids, which uses dicarboxylate anchors to bind rylene dyes to QD. This system yields a good basis to study the energy transfer between QD and dye because of its simple and compact design: there is no third kind of molecule linking QD and dye; no spacer; and the affinity of the functional group to the QD surface is strong. The FRET signal was measured for these complexes as a function of both dye to QD ratio and center-to-center distance between QD and dye by controlling number of covered ZnS layers. Data showed that fluorescence resonance energy transfer (FRET) was the dominant mechanism of the energy transfer in our QD-dye hybrid system. FRET efficiency can be controlled by not only adjusting the number of dyes on the QD surface or the QD to dye distance, but also properly choosing different dye and QD components. Due to the strong stability, our QD

  11. Energy Transfer and Dual Cascade in Kinetic Magnetized Plasma Turbulence

    International Nuclear Information System (INIS)

    Plunk, G. G.; Tatsuno, T.

    2011-01-01

    The question of how nonlinear interactions redistribute the energy of fluctuations across available degrees of freedom is of fundamental importance in the study of turbulence and transport in magnetized weakly collisional plasmas, ranging from space settings to fusion devices. In this Letter, we present a theory for the dual cascade found in such plasmas, which predicts a range of new behavior that distinguishes this cascade from that of neutral fluid turbulence. These phenomena are explained in terms of the constrained nature of spectral transfer in nonlinear gyrokinetics. Accompanying this theory are the first observations of these phenomena, obtained via direct numerical simulations using the gyrokinetic code AstroGK. The basic mechanisms that are found provide a framework for understanding the turbulent energy transfer that couples scales both locally and nonlocally.

  12. Energy Transfer and Dual Cascade in Kinetic Magnetized Plasma Turbulence

    Science.gov (United States)

    Plunk, G. G.; Tatsuno, T.

    2011-04-01

    The question of how nonlinear interactions redistribute the energy of fluctuations across available degrees of freedom is of fundamental importance in the study of turbulence and transport in magnetized weakly collisional plasmas, ranging from space settings to fusion devices. In this Letter, we present a theory for the dual cascade found in such plasmas, which predicts a range of new behavior that distinguishes this cascade from that of neutral fluid turbulence. These phenomena are explained in terms of the constrained nature of spectral transfer in nonlinear gyrokinetics. Accompanying this theory are the first observations of these phenomena, obtained via direct numerical simulations using the gyrokinetic code AstroGK. The basic mechanisms that are found provide a framework for understanding the turbulent energy transfer that couples scales both locally and nonlocally.

  13. Homopolar machine for reversible energy storage and transfer systems

    International Nuclear Information System (INIS)

    Stillwagon, R.E.

    1978-01-01

    A homopolar machine designed to operate as a generator and motor in reversibly storing and transferring energy between the machine and a magnetic load coil for a thermonuclear reactor is described. The machine rotor comprises hollow thin-walled cylinders or sleeves which form the basis of the system by utilizing substantially all of the rotor mass as a conductor thus making it possible to transfer substantially all the rotor kinetic energy electrically to the load coil in a highly economical and efficient manner. The rotor is divided into multiple separate cylinders or sleeves of modular design, connected in series and arranged to rotate in opposite directions but maintain the supply of current in a single direction to the machine terminals

  14. Photosynthetic Energy Transfer at the Quantum/Classical Border.

    Science.gov (United States)

    Keren, Nir; Paltiel, Yossi

    2018-06-01

    Quantum mechanics diverges from the classical description of our world when very small scales or very fast processes are involved. Unlike classical mechanics, quantum effects cannot be easily related to our everyday experience and are often counterintuitive to us. Nevertheless, the dimensions and time scales of the photosynthetic energy transfer processes puts them close to the quantum/classical border, bringing them into the range of measurable quantum effects. Here we review recent advances in the field and suggest that photosynthetic processes can take advantage of the sensitivity of quantum effects to the environmental 'noise' as means of tuning exciton energy transfer efficiency. If true, this design principle could be a base for 'nontrivial' coherent wave property nano-devices. Copyright © 2018 Elsevier Ltd. All rights reserved.

  15. Energy transfer in purple bacterial photosynthetic units from cells grown in various light intensities.

    Science.gov (United States)

    Niedzwiedzki, Dariusz M; Gardiner, Alastair T; Blankenship, Robert E; Cogdell, Richard J

    2018-05-03

    Three photosynthetic membranes, called intra-cytoplasmic membranes (ICMs), from wild-type and the ∆pucBA abce mutant of the purple phototrophic bacterium Rps. palustris were investigated using optical spectroscopy. The ICMs contain identical light-harvesting complex 1-reaction centers (LH1-RC) but have various spectral forms of light-harvesting complex 2 (LH2). Spectroscopic studies involving steady-state absorption, fluorescence, and femtosecond time-resolved absorption at room temperature and at 77 K focused on inter-protein excitation energy transfer. The studies investigated how energy transfer is affected by altered spectral features of the LH2 complexes as those develop under growth at different light conditions. The study shows that LH1 → LH2 excitation energy transfer is strongly affected if the LH2 complex alters its spectroscopic signature. The LH1 → LH2 excitation energy transfer rate modeled with the Förster mechanism and kinetic simulations of transient absorption of the ICMs demonstrated that the transfer rate will be 2-3 times larger for ICMs accumulating LH2 complexes with the classical B800-850 spectral signature (grown in high light) compared to the ICMs from the same strain grown in low light. For the ICMs from the ∆pucBA abce mutant, in which the B850 band of the LH2 complex is blue-shifted and almost degenerate with the B800 band, the LH1 → LH2 excitation energy transfer was not observed nor predicted by calculations.

  16. Intramolecular singlet-singlet energy transfer in antenna-substituted azoalkanes.

    Science.gov (United States)

    Pischel, Uwe; Huang, Fang; Nau, Werner M

    2004-03-01

    Two novel azoalkane bichromophores and related model compounds have been synthesised and photophysically characterised. Dimethylphenylsiloxy (DPSO) or dimethylnaphthylsiloxy (DNSO) serve as aromatic donor groups (antenna) and the azoalkane 2,3-diazabicyclo[2.2.2]oct-2-ene (DBO) as the acceptor. The UV spectral window of DBO (250-300 nm) allows selective excitation of the donor. Intramolecular singlet-singlet energy transfer to DBO is highly efficient and proceeds with quantum yields of 0.76 with DPSO and 0.99 with DNSO. The photophysical and spectral properties of the bichromophoric systems suggest that energy transfer occurs through diffusional approach of the donor and acceptor within a van der Waals contact at which the exchange mechanism is presumed to dominate. Furthermore, akin to the behaviour of electron-transfer systems in the Marcus inverted region, a rate of energy transfer 2.5 times slower was observed for the system with the more favourable energetics, i.e. singlet-singlet energy transfer from DPSO proceeded slower than from DNSO, although the process is more exergonic for DPSO (-142 kJ mol(-1) for DPSO versus-67 kJ mol(-1) for DNSO).

  17. Optically nonlinear energy transfer in light-harvesting dendrimers

    Science.gov (United States)

    Andrews, David L.; Bradshaw, David S.

    2004-08-01

    Dendrimeric polymers are the subject of intense research activity geared towards their implementation in nanodevice applications such as energy harvesting systems, organic light-emitting diodes, photosensitizers, low-threshold lasers, and quantum logic elements, etc. A recent development in this area has been the construction of dendrimers specifically designed to exhibit novel forms of optical nonlinearity, exploiting the unique properties of these materials at high levels of photon flux. Starting from a thorough treatment of the underlying theory based on the principles of molecular quantum electrodynamics, it is possible to identify and characterize several optically nonlinear mechanisms for directed energy transfer and energy pooling in multichromophore dendrimers. Such mechanisms fall into two classes: first, those where two-photon absorption by individual donors is followed by transfer of the net energy to an acceptor; second, those where the excitation of two electronically distinct but neighboring donor groups is followed by a collective migration of their energy to a suitable acceptor. Each transfer process is subject to minor dissipative losses. In this paper we describe in detail the balance of factors and the constraints that determines the favored mechanism, which include the excitation statistics, structure of the energy levels, laser coherence factors, chromophore selection rules and architecture, possibilities for the formation of delocalized excitons, spectral overlap, and the overall distribution of donors and acceptors. Furthermore, it transpires that quantum interference between different mechanisms can play an important role. Thus, as the relative importance of each mechanism determines the relevant nanophotonic characteristics, the results reported here afford the means for optimizing highly efficient light-harvesting dendrimer devices.

  18. Accurate magnetic field calculations for contactless energy transfer coils

    OpenAIRE

    Sonntag, C.L.W.; Spree, M.; Lomonova, E.A.; Duarte, J.L.; Vandenput, A.J.A.

    2007-01-01

    In this paper, a method for estimating the magnetic field intensity from hexagon spiral windings commonly found in contactless energy transfer applications is presented. The hexagonal structures are modeled in a magneto-static environment using Biot-Savart current stick vectors. The accuracy of the models are evaluated by mapping the current sticks and the hexagon spiral winding tracks to a local twodimensional plane, and comparing their two-dimensional magnetic field intensities. The accurac...

  19. Energy Transfer in Microhydrated Uracil, 5-Fluorouracil, and 5-Bromouracil

    Czech Academy of Sciences Publication Activity Database

    Poštulka, J.; Slavíček, P.; Fedor, Juraj; Fárník, Michal; Kočišek, Jaroslav

    2017-01-01

    Roč. 121, č. 38 (2017), s. 8965-8974 ISSN 1520-6106 R&D Projects: GA ČR GJ16-10995Y; GA ČR(CZ) GA17-04068S Institutional support: RVO:61388955 Keywords : Aromatic compounds * Electrons * Energy transfer Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 3.177, year: 2016

  20. Spatial propagation of excitonic coherence enables ratcheted energy transfer

    OpenAIRE

    Hoyer, Stephan; Ishizaki, Akihito; Whaley, K. Birgitta

    2011-01-01

    Experimental evidence shows that a variety of photosynthetic systems can preserve quantum beats in the process of electronic energy transfer, even at room temperature. However, whether this quantum coherence arises in vivo and whether it has any biological function have remained unclear. Here we present a theoretical model that suggests that the creation and recreation of coherence under natural conditions is ubiquitous. Our model allows us to theoretically demonstrate a mechanism for a ratch...

  1. Gravity influence on heat transfer rate in flow boiling

    NARCIS (Netherlands)

    Baltis, C.H.M.; Celata, G.P.; Cumo, M.; Saraceno, L.; Zummo, G.

    2012-01-01

    The aim of the present paper is to describe the results of flow boiling heat transfer at low gravity and compare them with those obtained at earth gravity, evaluating possible differences. The experimental campaigns at low gravity have been performed with parabolic flights. The paper will show the

  2. Investigation of sensitizer ions tunable-distribution in fluoride nanoparticles for efficient accretive three-center energy transfer

    International Nuclear Information System (INIS)

    Guo, Hui; Yu, Hua; Lao, Aiqing; Chang, Lifen; Gao, Shaohua; Zhang, Haoxiong; Zhou, Taojie; Zhao, Lijuan

    2014-01-01

    Cooperative upconversion luminescence of Yb 3+ -Yb 3+ couples and three-center energy transfer mechanisms have been deeply investigated in Yb 3+ doped and Yb 3+ -Tb 3+ co-doped β-PbF 2 nanoparticles. As sensitizer ions, the distribution of Yb 3+ ions, which is a key factor that affects the cooperative upconversion luminescence and three-center energy transfer processes, can be tuned by the structure of nanoparticles. Based on the three-center distributions in tetragonal PbYb x Tb 1−x F 5 nanoparticles, two different energy transfer models, Cooperative Energy Transfer (CET) and Accretive Energy Transfer (AET) mechanisms were established. Especially, AET model is observed and verified in this work for the first time. Experimental results obtained from photoluminescence spectroscopy study are in agreement with the theoretical calculations by applying rate equations in these models, strongly supporting the proposed three-center energy transfer mechanisms. The sensitization between Yb 3+ ions only existing in AET process can greatly improve the energy transfer rates, further to enhance the quantum efficiency. The results that the calculated luminescence quantum efficiency in AET quantum cutting process is much higher than that in CET process (134% and 104%, respectively), can benefit for further increasing the conversion efficiency of c-Si solar cells.

  3. Coherence and relaxation in energy transfer processes in condensed phases

    International Nuclear Information System (INIS)

    Shelby, R.M.

    1978-03-01

    Investigations of electronic triplet and vibrational energy transfer dynamics and relaxation processes are presented. Emphasis is placed on understanding the role of coherence and interactions which tend to destroy the coherence. In the case of triplet excitons at low temperatures, the importance of coherence in energy migration can be established, and the average coherence parameters can be experimentally determined. In the case of vibrational excitations, both picosecond spectroscopic studies of vibrational relaxation and spontaneous Raman spectroscopy are used to characterize the dynamics and give increased insight into the nature of the mechanisms responsible for vibrational dephasing. The design and operation of the picosecond apparatus used in these experiments is also described

  4. Isotope separation process by transfer of vibrational energy

    International Nuclear Information System (INIS)

    Angelie, C.; Cauchetier, M.; Paris, J.

    1983-01-01

    This process consists in exciting A molecules by absorption of a pulsed light beam, then in exciting until their dissociation X molecules, present in several isotopic forms, by a vibrational transfer between the A molecules and the X molecules, the A molecules having a dissociation energy greater than that of the X molecules, the duration and energy of the light pulses being such that the absorption time by the A molecules is less than the excitation time of the X molecules and the temperature conditions such that the thermal width of the vibration rays is at the most near the isotopic difference between the resonance rays of the two isotopic varieties [fr

  5. State-to-state dynamics of molecular energy transfer

    Energy Technology Data Exchange (ETDEWEB)

    Gentry, W.R.; Giese, C.F. [Univ. of Minnesota, Minneapolis (United States)

    1993-12-01

    The goal of this research program is to elucidate the elementary dynamical mechanisms of vibrational and rotational energy transfer between molecules, at a quantum-state resolved level of detail. Molecular beam techniques are used to isolate individual molecular collisions, and to control the kinetic energy of collision. Lasers are used both to prepare specific quantum states prior to collision by stimulated-emission pumping (SEP), and to measure the distribution of quantum states in the collision products by laser-induced fluorescence (LIF). The results are interpreted in terms of dynamical models, which may be cast in a classical, semiclassical or quantum mechanical framework, as appropriate.

  6. Collisional energy transfer in Na(4p--3d)--He,H2 collisions

    International Nuclear Information System (INIS)

    Kleiber, P.D.; Wong, T.H.; Bililign, S.

    1993-01-01

    We have investigated the direct collisional energy transfer process Na*(4p)+M→Na*(3d)+M, where M=He,H 2 under gas cell conditions. We have measured the temporal profiles of the Na(3d--3p) sensitized fluorescence as a function of quenching gas pressure and fit the profiles to a two-state rate equation model to obtain the quenching rate coefficients from the Na*(4p) state. The total energy transfer rate coefficient out of the 4p state for He is small [(0.5±0.2)x10 -10 cm 3 /s]. The total quenching rate coefficient out of the 4p state is much larger for H 2 [(3.9±0.5)x10 -10 cm 3 /s]. Evidence suggests that the energy transfer rate coefficient for the 4p--3d process is ∼2.0x10 -10 cm 3 /s with the remainder of the 4p quenching being predominantly reactive. We also compare the far-red wing absorption line shapes for the NaHe and NaH 2 systems

  7. Homopolar machine for reversible energy storage and transfer systems

    Science.gov (United States)

    Stillwagon, Roy E.

    1978-01-01

    A homopolar machine designed to operate as a generator and motor in reversibly storing and transferring energy between the machine and a magnetic load coil for a thermo-nuclear reactor. The machine rotor comprises hollow thin-walled cylinders or sleeves which form the basis of the system by utilizing substantially all of the rotor mass as a conductor thus making it possible to transfer substantially all the rotor kinetic energy electrically to the load coil in a highly economical and efficient manner. The rotor is divided into multiple separate cylinders or sleeves of modular design, connected in series and arranged to rotate in opposite directions but maintain the supply of current in a single direction to the machine terminals. A stator concentrically disposed around the sleeves consists of a hollow cylinder having a number of excitation coils each located radially outward from the ends of adjacent sleeves. Current collected at an end of each sleeve by sleeve slip rings and brushes is transferred through terminals to the magnetic load coil. Thereafter, electrical energy returned from the coil then flows through the machine which causes the sleeves to motor up to the desired speed in preparation for repetition of the cycle. To eliminate drag on the rotor between current pulses, the brush rigging is designed to lift brushes from all slip rings in the machine.

  8. Homopolar machine for reversible energy storage and transfer systems

    International Nuclear Information System (INIS)

    Stillwagon, R.E.

    1981-01-01

    A homopolar machine designed to operate as a generator and motor in reversibly storing and transferring energy between the machine and a magnetic load coil for a thermo-nuclear reactor. The machine rotor comprises hollow thin-walled cylinders or sleeves which form the basis of the system by utilizing substantially all of the rotor mass as a conductor thus making it possible to transfer substantially all the rotor kinetic energy electrically to the load coil in a highly economical and efficient manner. The rotor is divided into multiple separate cylinders or sleeves of modular design, connected in series and arranged to rotate in opposite directions but maintain the supply of current in a single direction to the machine terminals. A stator concentrically disposed around the sleeves consists of a hollow cylinder having a number of excitation coils each located radially outward from the ends of adjacent sleeves. Current collected at an end of each sleeve by sleeve slip rings and brushes is transferred through terminals to the magnetic load coil. Thereafter, electrical energy returned from the coil then flows through the machine which causes the sleeves to motor up to the desired speed in preparation for repetition of the cycle. To eliminate drag on the rotor between current pulses, the brush rigging is designed to lift brushes from all slip rings in the machine

  9. Solar wind energy transfer regions inside the dayside magnetopause

    International Nuclear Information System (INIS)

    Lundin, R.; Dubinin, E.

    1984-01-01

    PROGNOZ-7 high temporal resolution measurements of the ion composition and hot plasma distribution in the dayside high latitude boundary layer near noon have revealed that magnetosheath plasma may penetrate the dayside magnetopause and form high density, high β, magnetosheath-like regions inside the magnetopause. From these measurements it is demonstrated that the magnetosheath injection regions most probably play an important role in transferring solar wind energy into the magnetosphere. The transfer regions are characterized by a strong perpendicular flow towards dawn or dusk (depending on local time) but are also observed to expand rapidly along the boundary field lines. This increased flow component transverse to the local magnetic field corresponds to a predominantly radial electric field of up to several mV m -1 , which indicates that the injected magnetosheath plasma causes an enhanced polarization of the boundary layer. Polarization of the boundary layer can therefore be considered a result of a local MHD-process where magnetosheath plasma excess momentum is converted into electromagnetic energy (electric field), i.e. there is an MHD-generator. It was observed that the boundary layer is charged up to tens of kilovolts, a potential which may be highly variable on e.g. the presence of a momentum exchange by the energy transfer regions. (author)

  10. Energy and charge transfer in ionized argon coated water clusters

    International Nuclear Information System (INIS)

    Kočišek, J.; Lengyel, J.; Fárník, M.; Slavíček, P.

    2013-01-01

    We investigate the electron ionization of clusters generated in mixed Ar-water expansions. The electron energy dependent ion yields reveal the neutral cluster composition and structure: water clusters fully covered with the Ar solvation shell are formed under certain expansion conditions. The argon atoms shield the embedded (H 2 O) n clusters resulting in the ionization threshold above ≈15 eV for all fragments. The argon atoms also mediate more complex reactions in the clusters: e.g., the charge transfer between Ar + and water occurs above the threshold; at higher electron energies above ∼28 eV, an excitonic transfer process between Ar + * and water opens leading to new products Ar n H + and (H 2 O) n H + . On the other hand, the excitonic transfer from the neutral Ar* state at lower energies is not observed although this resonant process was demonstrated previously in a photoionization experiment. Doubly charged fragments (H 2 O) n H 2 2+ and (H 2 O) n 2+ ions are observed and Intermolecular Coulomb decay (ICD) processes are invoked to explain their thresholds. The Coulomb explosion of the doubly charged cluster formed within the ICD process is prevented by the stabilization effect of the argon solvent

  11. Neutron scattering investigation of magnetic excitations at high energy transfers

    International Nuclear Information System (INIS)

    Loong, C.K.

    1984-01-01

    With the advance of pulsed spallation neutron sources, neutron scattering investigation of elementary excitations in magnetic materials can now be extended to energies up to several hundreds of MeV. We have measured, using chopper spectrometers and time-of-flight techniques, the magnetic response functions of a series of d and f transition metals and compounds over a wide range of energy and momentum transfer. In PrO 2 , UO 2 , BaPrO 3 and CeB 6 we observed crystal-field transitions between the magnetic ground state and the excited levels in the energy range from 40 to 260 MeV. In materials exhibiting spin-fluctuation or mixed-valent character such as Ce 74 Th 26 , on the other hand, no sharp crystal-field lines but a broadened quasielastic magnetic peak was observed. The line width of the quasielastic component is thought to be connected to the spin-fluctuation energy of the 4f electrons. The significance of the neutron scattering results in relation to the ground state level structure of the magnetic ions and the spin-dynamics of the f electrons is discussed. Recently, in a study of the spin-wave excitations in itinerant magnetic systems, we have extended the spin-wave measurements in ferromagnetic iron up to about 160 MeV. Neutron scattering data at high energy transfers are of particular interest because they provide direct comparison with recent theories of itinerant magnetism. 26 references, 7 figures

  12. Luminescence and energy transfer processes in rare earth compounds

    International Nuclear Information System (INIS)

    Vliet, J.P.M. van.

    1989-01-01

    In this thesis some studies are presented of the luminescence and energy transfer in compounds containing Eu 3+ , Pr 3+ and Gd 3+ ions. Ch. 2 deals with the energy migration in the system Gd 1 - xEu x(IO 3) 3. In ch 3 the luminescence properties of the Pr 3+ ion in the system La 1 - xPr xMgAl 1 10 1 9 are reported. Ch. 4 discusses the luminescence properties of alkali europium double tungstates and molybdates AEuW 20 8 and AEuMo 20 * (A + = alkali metal atom). The luminiscence and energy migration characteristics of the isostructural system LiGd 1 - xEu xF 4 and Gd 1 - xEu xNbO 4 are reported in ch. 5. In ch. 6 the mechanism of energy migration in (La,Gd)AlO 3 and (Gd,Eu)AlO 3 is discussed. Ch. 7 deals with the system Na 5(Gd,Eu) (WO 4) 4. In ch. 8 the luminescence and energy transfer properties of two europium tellurite anti-glass phases are reported. The two phases are Eu 1 . 7 9TeO x, which has a pseudotetragonal structure, and Eu 1 . 0 6TeO x, which has a monoclinic, ordered structure. (author). 201 refs.; 39 figs.; 8 tabs

  13. Molding resonant energy transfer by colloidal crystal: Dexter transfer and electroluminescence

    Science.gov (United States)

    González-Urbina, Luis; Kolaric, Branko; Libaers, Wim; Clays, Koen

    2010-05-01

    Building photonic crystals by combination of colloidal ordering and metal sputtering we were able to construct a system sensitive to an electrical field. In corresponding crystals we embedded the Dexter pair (Ir(ppy3) and BAlq) and investigated the influence of the band gap on the resonant energy transfer when the system is excited by light and by an electric field respectively. Our investigations extend applications of photonic crystals into the field of electroluminescence and LED technologies.

  14. Targeted Energy Transfer Phenomena in Vibro-Impact Oscillators

    International Nuclear Information System (INIS)

    Lee, Young S.; McFarland, D. Michael; Bergman, Lawrence A.; Nucera, Francesco; Vakakis, Alexander F.

    2008-01-01

    We study targeted energy transfer (TET) in a coupled oscillator, consisting of a single-degree-of-freedom primary linear oscillator coupled to a vibro-impact nonlinear energy sink (VI NES). For this purpose, we first compute the VI periodic orbits of the underlying hamiltonian VI system, and construct the corresponding frequency-energy plot (FEP). Then, considering inelastic impacts and viscous dissipation, we examine VI damped transitions on the FEP to identify a TET phenomenon by exciting a VI impulsive orbit, which is the most efficient mechanism for TET. Not only can the VI TET involve passive absorption and local dissipation of significant portions of the energy from the primary systems, but it occurs at sufficiently fast time scales. This renders VI NESs suitable for applications, like seismic mitigation, where shock elimination in the early, highly energetic regime of the motion is a critical requirement

  15. Transfer Rate Edited experiment for the selective detection of Chemical Exchange via Saturation Transfer (TRE-CEST)

    Science.gov (United States)

    Friedman, Joshua I.; Xia, Ding; Regatte, Ravinder R.; Jerschow, Alexej

    2015-07-01

    Chemical Exchange Saturation Transfer (CEST) magnetic resonance experiments have become valuable tools in magnetic resonance for the detection of low concentration solutes with far greater sensitivity than direct detection methods. Accurate measures of rates of chemical exchange provided by CEST are of particular interest to biomedical imaging communities where variations in chemical exchange can be related to subtle variations in biomarker concentration, temperature and pH within tissues using MRI. Despite their name, however, traditional CEST methods are not truly selective for chemical exchange and instead detect all forms of magnetization transfer including through-space NOE. This ambiguity crowds CEST spectra and greatly complicates subsequent data analysis. We have developed a Transfer Rate Edited CEST experiment (TRE-CEST) that uses two different types of solute labeling in order to selectively amplify signals of rapidly exchanging proton species while simultaneously suppressing 'slower' NOE-dominated magnetization transfer processes. This approach is demonstrated in the context of both NMR and MRI, where it is used to detect the labile amide protons of proteins undergoing chemical exchange (at rates ⩾ 30 s-1) while simultaneously eliminating signals originating from slower (∼5 s-1) NOE-mediated magnetization transfer processes. TRE-CEST greatly expands the utility of CEST experiments in complex systems, and in-vivo, in particular, where it is expected to improve the quantification of chemical exchange and magnetization transfer rates while enabling new forms of imaging contrast.

  16. Tracing of backward energy transfer from LH1 to LH2 in photosynthetic membranes grown under high and low irradiation.

    Directory of Open Access Journals (Sweden)

    Lanzani G.

    2013-03-01

    Full Text Available By introducing derivative transient absorption spectroscopy, we obtain rate constants for backward and forward energy transfer between LH1 and LH2 complexes in purple bacterial membranes. We find that backward energy transfer is strongly reduced in membranes grown under low irradiation conditions, compared to high light grown ones. We conclude that backward energy transfer is managed actively by the bacteria to avoid LH1 exciton deactivation under high irradiation conditions. The analytical method is generally applicable to excitonically coupled systems.

  17. Determination of Erosion/Corrosion Rates in Hanford Tank Farms Radioactive Waste Transfer System Pipelines

    International Nuclear Information System (INIS)

    Washenfelder, D. J.; Girardot, C. L.; Wilson, E. R.; Page, J. A.; Engeman, J. K.; Gunter, J. R.; Johnson, J. M.; Baide, D. G.; Cooke, G. A.; Larson, J. D.; Castleberry, J. L.; Boomer, K. D.

    2015-01-01

    The twenty-eight double-shell underground radioactive waste storage tanks at the U. S. Department of Energy's Hanford Site near Richland, WA are interconnected by the Waste Transfer System network of buried steel encased pipelines and pipe jumpers in below-grade pits. The pipeline material is stainless steel or carbon steel in 51 mm to 152 mm (2 in. to 6 in.) sizes. The pipelines carry slurries ranging up to 20 volume percent solids and supernatants with less than one volume percent solids at velocities necessary to prevent settling. The pipelines, installed between 1976 and 2011, were originally intended to last until the 2028 completion of the double-shell tank storage mission. The mission has been subsequently extended. In 2010 the Tank Operating Contractor began a systematic evaluation of the Waste Transfer System pipeline conditions applying guidelines from API 579-1/ASME FFS-1 (2007), Fitness-For-Service. Between 2010 and 2014 Fitness-for-Service examinations of the Waste Transfer System pipeline materials, sizes, and components were completed. In parallel, waste throughput histories were prepared allowing side-by-side pipeline wall thinning rate comparisons between carbon and stainless steel, slurries and supernatants and throughput volumes. The work showed that for transfer volumes up to 6.1E+05 m"3 (161 million gallons), the highest throughput of any pipeline segment examined, there has been no detectable wall thinning in either stainless or carbon steel pipeline material regardless of waste fluid characteristics or throughput. The paper describes the field and laboratory evaluation methods used for the Fitness-for-Service examinations, the results of the examinations, and the data reduction methodologies used to support Hanford Waste Transfer System pipeline wall thinning conclusions.

  18. Heat transfer and flow in solar energy and bioenergy systems

    Science.gov (United States)

    Xu, Ben

    The demand for clean and environmentally benign energy resources has been a great concern in the last two decades. To alleviate the associated environmental problems, reduction of the use of fossil fuels by developing more cost-effective renewable energy technologies becomes more and more significant. Among various types of renewable energy sources, solar energy and bioenergy take a great proportion. This dissertation focuses on the heat transfer and flow in solar energy and bioenergy systems, specifically for Thermal Energy Storage (TES) systems in Concentrated Solar Power (CSP) plants and open-channel algal culture raceways for biofuel production. The first part of this dissertation is the discussion about mathematical modeling, numerical simulation and experimental investigation of solar TES system. First of all, in order to accurately and efficiently simulate the conjugate heat transfer between Heat Transfer Fluid (HTF) and filler material in four different solid-fluid TES configurations, formulas of an e?ective heat transfer coe?cient were theoretically developed and presented by extending the validity of Lumped Capacitance Method (LCM) to large Biot number, as well as verifications/validations to this simplified model. Secondly, to provide design guidelines for TES system in CSP plant using Phase Change Materials (PCM), a general storage tank volume sizing strategy and an energy storage startup strategy were proposed using the enthalpy-based 1D transient model. Then experimental investigations were conducted to explore a novel thermal storage material. The thermal storage performances were also compared between this novel storage material and concrete at a temperature range from 400 °C to 500 °C. It is recommended to apply this novel thermal storage material to replace concrete at high operating temperatures in sensible heat TES systems. The second part of this dissertation mainly focuses on the numerical and experimental study of an open-channel algae

  19. Electronic energy transfer through non-adiabatic vibrational-electronic resonance. I. Theory for a dimer

    Science.gov (United States)

    Tiwari, Vivek; Peters, William K.; Jonas, David M.

    2017-10-01

    Non-adiabatic vibrational-electronic resonance in the excited electronic states of natural photosynthetic antennas drastically alters the adiabatic framework, in which electronic energy transfer has been conventionally studied, and suggests the possibility of exploiting non-adiabatic dynamics for directed energy transfer. Here, a generalized dimer model incorporates asymmetries between pigments, coupling to the environment, and the doubly excited state relevant for nonlinear spectroscopy. For this generalized dimer model, the vibrational tuning vector that drives energy transfer is derived and connected to decoherence between singly excited states. A correlation vector is connected to decoherence between the ground state and the doubly excited state. Optical decoherence between the ground and singly excited states involves linear combinations of the correlation and tuning vectors. Excitonic coupling modifies the tuning vector. The correlation and tuning vectors are not always orthogonal, and both can be asymmetric under pigment exchange, which affects energy transfer. For equal pigment vibrational frequencies, the nonadiabatic tuning vector becomes an anti-correlated delocalized linear combination of intramolecular vibrations of the two pigments, and the nonadiabatic energy transfer dynamics become separable. With exchange symmetry, the correlation and tuning vectors become delocalized intramolecular vibrations that are symmetric and antisymmetric under pigment exchange. Diabatic criteria for vibrational-excitonic resonance demonstrate that anti-correlated vibrations increase the range and speed of vibronically resonant energy transfer (the Golden Rule rate is a factor of 2 faster). A partial trace analysis shows that vibronic decoherence for a vibrational-excitonic resonance between two excitons is slower than their purely excitonic decoherence.

  20. Energy efficiency rating of districts, case Finland

    International Nuclear Information System (INIS)

    Hedman, Åsa; Sepponen, Mari; Virtanen, Mikko

    2014-01-01

    There is an increasing political pressure on the city planning to create more energy efficient city plans. Not only do the city plans have to enable and promote energy efficient solutions, but it also needs to be clearly assessed how energy efficient the plans are. City planners often have no or poor know how about energy efficiency and building technologies which makes it difficult for them to answer to this need without new guidelines and tools. An easy to use tool for the assessment of the energy efficiency of detailed city plans was developed. The aim of the tool is for city planners to easily be able to assess the energy efficiency of the proposed detailed city plan and to be able to compare the impacts of changes in the plan. The tool is designed to be used with no in-depth knowledge about energy or building technology. With a wide use of the tool many missed opportunities for improving energy efficiency can be avoided. It will provide better opportunities for sustainable solutions leading to less harmful environmental impact and reduced emissions. - Highlights: • We have created a tool for assessing energy efficiency of detailed city plans. • The energy source is the most important factor for efficiency of districts in Finland. • Five case districts in Finland were analyzed. • In this paper one residential district has in-depth sensitivity analyses done

  1. New theory of radiative energy transfer in free electromagnetic fields

    International Nuclear Information System (INIS)

    Wolf, E.

    1976-01-01

    A new theory of radiative energy transfer in free, statistically stationary electromagnetic fields is presented. It provides a model for energy transport that is rigorous both within the framework of the stochastic theory of the classical field as well as within the framework of the theory of the quantized field. Unlike the usual phenomenological model of radiative energy transfer that centers around a single scalar quantity (the specific intensity of radiation), our theory brings into evidence the need for characterizing the energy transport by means of two (related) quantities: a scalar and a vector that may be identified, in a well-defined sense, with ''angular components'' of the average electromagnetic energy density and of the average Poynting vector, respectively. Both of them are defined in terms of invariants of certain new electromagnetic correlation tensors. In the special case when the field is statistically homogeneous, our model reduces to the usual one and our angular component of the average electromagnetic energy density, when multiplied by the vacuum speed of light, then acquires all the properties of the specific intensity of radiation. When the field is not statistically homogeneous our model approximates to the usual phenomenological one, provided that the angular correlations between plane wave modes of the field extend over a sufficiently small solid angle of directions about the direction of propagation of each mode. It is tentatively suggested that, when suitably normalized, our angular component of the average electromagnetic energy density may be interpreted as a quasi-probability (general quantum-mechancial phase-space distribution function, such as Wigner's) for the position and the momentum of a photon

  2. Membranes: A Variety of Energy Landscapes for Many Transfer Opportunities.

    Science.gov (United States)

    Bacchin, Patrice

    2018-02-22

    A membrane can be represented by an energy landscape that solutes or colloids must cross. A model accounting for the momentum and the mass balances in the membrane energy landscape establishes a new way of writing for the Darcy law. The counter-pressure in the Darcy law is no longer written as the result of an osmotic pressure difference but rather as a function of colloid-membrane interactions. The ability of the model to describe the physics of the filtration is discussed in detail. This model is solved in a simplified energy landscape to derive analytical relationships that describe the selectivity and the counter-pressure from ab initio operating conditions. The model shows that the stiffness of the energy landscape has an impact on the process efficiency: a gradual increase in interactions (such as with hourglass pore shape) can reduce the separation energetic cost. It allows the introduction of a new paradigm to increase membrane efficiency: the accumulation that is inherent to the separation must be distributed across the membrane. Asymmetric interactions thus lead to direction-dependent transfer properties and the membrane exhibits diode behavior. These new transfer opportunities are discussed.

  3. Transfer Rate Edited experiment for the selective detection of Chemical Exchange via Saturation Transfer (TRE-CEST).

    Science.gov (United States)

    Friedman, Joshua I; Xia, Ding; Regatte, Ravinder R; Jerschow, Alexej

    2015-07-01

    Chemical Exchange Saturation Transfer (CEST) magnetic resonance experiments have become valuable tools in magnetic resonance for the detection of low concentration solutes with far greater sensitivity than direct detection methods. Accurate measures of rates of chemical exchange provided by CEST are of particular interest to biomedical imaging communities where variations in chemical exchange can be related to subtle variations in biomarker concentration, temperature and pH within tissues using MRI. Despite their name, however, traditional CEST methods are not truly selective for chemical exchange and instead detect all forms of magnetization transfer including through-space NOE. This ambiguity crowds CEST spectra and greatly complicates subsequent data analysis. We have developed a Transfer Rate Edited CEST experiment (TRE-CEST) that uses two different types of solute labeling in order to selectively amplify signals of rapidly exchanging proton species while simultaneously suppressing 'slower' NOE-dominated magnetization transfer processes. This approach is demonstrated in the context of both NMR and MRI, where it is used to detect the labile amide protons of proteins undergoing chemical exchange (at rates⩾30s(-1)) while simultaneously eliminating signals originating from slower (∼5s(-1)) NOE-mediated magnetization transfer processes. TRE-CEST greatly expands the utility of CEST experiments in complex systems, and in-vivo, in particular, where it is expected to improve the quantification of chemical exchange and magnetization transfer rates while enabling new forms of imaging contrast. Copyright © 2015 Elsevier Inc. All rights reserved.

  4. Long-range electron transfer in porphyrin-containing [2]-rotaxanes: tuning the rate by metal cation coordination.

    Science.gov (United States)

    Andersson, Mikael; Linke, Myriam; Chambron, Jean-Claude; Davidsson, Jan; Heitz, Valérie; Hammarström, Leif; Sauvage, Jean-Pierre

    2002-04-24

    A series of [2]-rotaxanes has been synthesized in which two Zn(II)-porphyrins (ZnP) electron donors were attached as stoppers on the rod. A macrocycle attached to a Au(III)-porphyrin (AuP+) acceptor was threaded on the rod. By selective excitation of either porphyrin, we could induce an electron transfer from the ZnP to the AuP+ unit that generated the same ZnP*+-AuP* charge-transfer state irrespective of which porphyrin was excited. Although the reactants were linked only by mechanical or coordination bonds, electron-transfer rate constants up to 1.2x10(10) x s(-1) were obtained over a 15-17 A edge-to-edge distance between the porphyrins. The resulting charge-transfer state had a relatively long lifetime of 10-40 ns and was formed in high yield (>80%) in most cases. By a simple variation of the link between the reactants, viz. a coordination of the phenanthroline units on the rotaxane rod and ring by either Ag+ or Cu+, we could enhance the electron-transfer rate from the ZnP to the excited 3AuP+. We interpret our data in terms of an enhanced superexchange mechanism with Ag+ and a change to a stepwise hopping mechanism with Cu+, involving the oxidized Cu(phen)22+ unit as a real intermediate. When the ZnP unit was excited instead, electron transfer from the excited 1ZnP to AuP+ was not affected, or even slowed, by Ag+ or Cu+. We discuss this asymmetry in terms of the different orbitals involved in mediating the reaction in an electron- and a hole-transfer mechanism. Our results show the possibility to tune the rates of electron transfer between noncovalently linked reactants by a convenient modification of the link. The different effect of Ag+ and Cu+ on the rate with ZnP and AuP+ excitation shows an additional possibility to control the electron-transfer reactions by selective excitation. We also found that coordination of the Cu+ introduced an energy-transfer reaction from 1ZnP to Cu(phen)2+ (k = 5.1x10(9) x s(-1)) that proceeded in competition with electron

  5. Rate of Iron Transfer Through the Horse Spleen Ferritin Shell Determined by the Rate of Formation of Prussian Blue and Fe-desferrioxamine Within the Ferritin Cavity

    Science.gov (United States)

    Zhang, Bo; Watt, Richard K.; Galvez, Natividad; Dominquez-Vera, Jose M.; Watt, Gerald D.

    2005-01-01

    Iron (2+ and 3+) is believed to transfer through the three-fold channels in the ferritin shell during iron deposition and release in animal ferritins. However, the rate of iron transit in and out through these channels has not been reported. The recent synthesis of [Fe(CN)(sub 6)](3-), Prussian Blue (PB) and desferrioxamine (DES) all trapped within the horse spleen ferritin (HoSF) interior makes these measurements feasible. We report the rate of Fe(2+) penetrating into the ferritin interior by adding external Fe(2+) to [Fe(CN)(sub 6)](3-) encapsulated in the HoSF interior and measuring the rate of formation of the resulting encapsulated PB. The rate at which Fe(2+) reacts with [Fe(CN)(sub 6)](3-) in the HoSF interior is much slower than the formation of free PB in solution and is proceeded by a lag period. We assume this lag period and the difference in rate represent the transfer of Fe(2+) through the HoSF protein shell. The calculated diffusion coefficient, D approx. 5.8 x 10(exp -20) square meters per second corresponds to the measured lag time of 10-20 s before PB forms within the HoSF interior. The activation energy for Fe(2+) transfer from the outside solution through the protein shell was determined to be 52.9 kJ/mol by conducting the reactions at 10 to approximately 40 C. The reaction of Fe(3+) with encapsulated [Fe(CN)6](4-) also readily forms PB in the HoSF interior, but the rate is faster than the corresponding Fe(2+) reaction. The rate for Fe(3+) transfer through the ferritin shell was confirmed by measuring the rate of the formation of Fe-DES inside HoSF and an activation energy of 58.4 kJ/mol was determined. An attempt was made to determine the rate of iron (2+ and 3+) transit out from the ferritin interior by adding excess bipyridine or DES to PB trapped within the HoSF interior. However, the reactions are slow and occur at almost identical rates for free and HoSF-encapsulated PB, indicating that the transfer of iron from the interior through the

  6. Energy transfer in compressible magnetohydrodynamic turbulence for isothermal self-gravitating fluids

    Science.gov (United States)

    Banerjee, Supratik; Kritsuk, Alexei G.

    2018-02-01

    Three-dimensional, compressible, magnetohydrodynamic turbulence of an isothermal, self-gravitating fluid is analyzed using two-point statistics in the asymptotic limit of large Reynolds numbers (both kinetic and magnetic). Following an alternative formulation proposed by Banerjee and Galtier [Phys. Rev. E 93, 033120 (2016), 10.1103/PhysRevE.93.033120; J. Phys. A: Math. Theor. 50, 015501 (2017), 10.1088/1751-8113/50/1/015501], an exact relation has been derived for the total energy transfer. This approach results in a simpler relation expressed entirely in terms of mixed second-order structure functions. The kinetic, thermodynamic, magnetic, and gravitational contributions to the energy transfer rate can be easily separated in the present form. By construction, the new formalism includes such additional effects as global rotation, the Hall term in the induction equation, etc. The analysis shows that solid-body rotation cannot alter the energy flux rate of compressible turbulence. However, the contribution of a uniform background magnetic field to the flux is shown to be nontrivial unlike in the incompressible case. Finally, the compressible, turbulent energy flux rate does not vanish completely due to simple alignments, which leads to a zero turbulent energy flux rate in the incompressible case.

  7. Development of a methodology for life cycle building energy ratings

    International Nuclear Information System (INIS)

    Hernandez, Patxi; Kenny, Paul

    2011-01-01

    Traditionally the majority of building energy use has been linked to its operation (heating, cooling, lighting, etc.), and much attention has been directed to reduce this energy use through technical innovation, regulatory control and assessed through a wide range of rating methods. However buildings generally employ an increasing amount of materials and systems to reduce the energy use in operation, and energy embodied in these can constitute an important part of the building's life cycle energy use. For buildings with 'zero-energy' use in operation the embodied energy is indeed the only life cycle energy use. This is not addressed by current building energy assessment and rating methods. This paper proposes a methodology to extend building energy assessment and rating methods accounting for embodied energy of building components and systems. The methodology is applied to the EU Building Energy Rating method and, as an illustration, as implemented in Irish domestic buildings. A case study dwelling is used to illustrate the importance of embodied energy on life cycle energy performance, particularly relevant when energy use in operation tends to zero. The use of the Net Energy Ratio as an indicator to select appropriate building improvement measures is also presented and discussed. - Highlights: → The definitions for 'zero energy buildings' and current building energy ratings are examined. → There is a need to integrate a life cycle perspective within building energy ratings. → A life cycle building energy rating method (LC-BER), including embodied energy is presented. → Net Energy Ratio is proposed as an indicator to select building energy improvement options.

  8. Comparison of vibrational conductivity and radiative energy transfer methods

    Science.gov (United States)

    Le Bot, A.

    2005-05-01

    This paper is concerned with the comparison of two methods well suited for the prediction of the wideband response of built-up structures subjected to high-frequency vibrational excitation. The first method is sometimes called the vibrational conductivity method and the second one is rather known as the radiosity method in the field of acoustics, or the radiative energy transfer method. Both are based on quite similar physical assumptions i.e. uncorrelated sources, mean response and high-frequency excitation. Both are based on analogies with some equations encountered in the field of heat transfer. However these models do not lead to similar results. This paper compares the two methods. Some numerical simulations on a pair of plates joined along one edge are provided to illustrate the discussion.

  9. Impact of the lipid bilayer on energy transfer kinetics in the photosynthetic protein LH2.

    Science.gov (United States)

    Ogren, John I; Tong, Ashley L; Gordon, Samuel C; Chenu, Aurélia; Lu, Yue; Blankenship, Robert E; Cao, Jianshu; Schlau-Cohen, Gabriela S

    2018-03-28

    Photosynthetic purple bacteria convert solar energy to chemical energy with near unity quantum efficiency. The light-harvesting process begins with absorption of solar energy by an antenna protein called Light-Harvesting Complex 2 (LH2). Energy is subsequently transferred within LH2 and then through a network of additional light-harvesting proteins to a central location, termed the reaction center, where charge separation occurs. The energy transfer dynamics of LH2 are highly sensitive to intermolecular distances and relative organizations. As a result, minor structural perturbations can cause significant changes in these dynamics. Previous experiments have primarily been performed in two ways. One uses non-native samples where LH2 is solubilized in detergent, which can alter protein structure. The other uses complex membranes that contain multiple proteins within a large lipid area, which make it difficult to identify and distinguish perturbations caused by protein-protein interactions and lipid-protein interactions. Here, we introduce the use of the biochemical platform of model membrane discs to study the energy transfer dynamics of photosynthetic light-harvesting complexes in a near-native environment. We incorporate a single LH2 from Rhodobacter sphaeroides into membrane discs that provide a spectroscopically amenable sample in an environment more physiological than detergent but less complex than traditional membranes. This provides a simplified system to understand an individual protein and how the lipid-protein interaction affects energy transfer dynamics. We compare the energy transfer rates of detergent-solubilized LH2 with those of LH2 in membrane discs using transient absorption spectroscopy and transient absorption anisotropy. For one key energy transfer step in LH2, we observe a 30% enhancement of the rate for LH2 in membrane discs compared to that in detergent. Based on experimental results and theoretical modeling, we attribute this difference to

  10. Supporting the Energy Transition: the Role of Low Interest Rates

    International Nuclear Information System (INIS)

    Monnin, Pierre

    2015-01-01

    Low interest rates tend to favor 'green technologies' competitiveness while also increasing their cost volatility. Our analysis of the impact of interest rates on green energy technologies costs points to three key conclusions: - A low interest rate environment makes green energy technologies more competitive. Hydroelectric power is less expensive than any other technology across the entire spectrum of interest rate levels that we analyzed in this paper. Wind on-shore is competitive with all other technologies up until interest rates of about 8%. - Green energy technologies' LCOEs react more significantly to a change in interest rates than the LCOEs of brown energy technologies, implying a greater volatility for green energy technologies' costs in response to interest rate volatility. A higher volatility is damaging because it brings more uncertainty in investment decisions. As a result, stable interest rates are more beneficial for green energy investments than for brown energy investments. - In order to increase the ratio of green to brown energy investments, we can consider a discount on the interest rates for the former or a premium on interest rates for the latter. Our estimations indicate that, because interest rate changes have a greater impact on the costs of green energy technologies, a discount on green investments' interest rates would be more efficient than a premium on brown investments' interest rates. (author)

  11. Controlling resonance energy transfer in nanostructure emitters by positioning near a mirror

    Science.gov (United States)

    Weeraddana, Dilusha; Premaratne, Malin; Gunapala, Sarath D.; Andrews, David L.

    2017-08-01

    The ability to control light-matter interactions in quantum objects opens up many avenues for new applications. We look at this issue within a fully quantized framework using a fundamental theory to describe mirror-assisted resonance energy transfer (RET) in nanostructures. The process of RET communicates electronic excitation between suitably disposed donor and acceptor particles in close proximity, activated by the initial excitation of the donor. Here, we demonstrate that the energy transfer rate can be significantly controlled by careful positioning of the RET emitters near a mirror. The results deliver equations that elicit new insights into the associated modification of virtual photon behavior, based on the quantum nature of light. In particular, our results indicate that energy transfer efficiency in nanostructures can be explicitly expedited or suppressed by a suitably positioned neighboring mirror, depending on the relative spacing and the dimensionality of the nanostructure. Interestingly, the resonance energy transfer between emitters is observed to "switch off" abruptly under suitable conditions of the RET system. This allows one to quantitatively control RET systems in a new way.

  12. Intramolecular energy transfer at donor-acceptor interactions in model and biological membranes

    International Nuclear Information System (INIS)

    Umarova, Fatima T.

    2011-01-01

    Intramolecular triplet-triplet energy transfer between molecules of sensibilisator and photochrome for registration of protein interactions in the membrane preparation of Na,K-ATPase was investigated. Erythrosinithiocyanate (ERITC) was used as the triplet label of sensibilisator, and 4-acetoamido-4 -isothiocyanatostilbene-2,2 disullfonic acid (SITS) was used as the photochrome label. Na,K-ATPase preparations were covalently bound with ERITC in active centre of enzyme, and SITS molecules were covalently bound by NH2-groups. In model system, in chymotrypsinogene molecule, SITS and ERITC labels were used also. The cis-trans-isomerization of SITS was initiated by triplet-triplet energy transfer from light excited ERITC molecule to photochrome. The kinetics of isomerization was recorded by the SITS fluorescence measurements. The constant of rate of triplet-triplet energy transfer from ERITC to cis-isomers of SITS in Na,K-ATPase was determined as (3-7)x10 3 M -1 s -1 , and in model system it equals 1x 10 7 M 1 s -1 . The value of energy transfer between loos molecules of erythrosine and SITS in buffer solution equaled to 7x10 7 M -1 s -1 . This drop of R m y in the membrane preparation of Na,K-ATPase at 10 4 reflected the decrease in the frequency of label collisions caused by the increase in the media viscosity and steric hindrances. (author)

  13. Transfer of mechanical energy during the shot put

    Directory of Open Access Journals (Sweden)

    Błażkiewicz Michalina

    2016-09-01

    Full Text Available The aim of this study was to analyse transfer of mechanical energy between body segments during the glide shot put. A group of eight elite throwers from the Polish National Team was analysed in the study. Motion analysis of each throw was recorded using an optoelectronic Vicon system composed of nine infrared camcorders and Kistler force plates. The power and energy were computed for the phase of final acceleration of the glide shot put. The data were normalized with respect to time using the algorithm of the fifth order spline and their values were interpolated with respect to the percentage of total time, assuming that the time of the final weight acceleration movement was different for each putter. Statistically significant transfer was found in the study group between the following segments: Right Knee – Right Hip (p = 0.0035, Left Hip - Torso (p = 0.0201, Torso – Right Shoulder (p = 0.0122 and Right Elbow – Right Wrist (p = 0.0001. Furthermore, the results of cluster analysis showed that the kinetic chain used during the final shot acceleration movement had two different models. Differences between the groups were revealed mainly in the energy generated by the hips and trunk.

  14. Surprisal analysis and probability matrices for rotational energy transfer

    International Nuclear Information System (INIS)

    Levine, R.D.; Bernstein, R.B.; Kahana, P.; Procaccia, I.; Upchurch, E.T.

    1976-01-01

    The information-theoretic approach is applied to the analysis of state-to-state rotational energy transfer cross sections. The rotational surprisal is evaluated in the usual way, in terms of the deviance of the cross sections from their reference (''prior'') values. The surprisal is found to be an essentially linear function of the energy transferred. This behavior accounts for the experimentally observed exponential gap law for the hydrogen halide systems. The data base here analyzed (taken from the literature) is largely computational in origin: quantal calculations for the hydrogenic systems H 2 +H, He, Li + ; HD+He; D 2 +H and for the N 2 +Ar system; and classical trajectory results for H 2 +Li + ; D 2 +Li + and N 2 +Ar. The surprisal analysis not only serves to compact a large body of data but also aids in the interpretation of the results. A single surprisal parameter theta/subR/ suffices to account for the (relative) magnitude of all state-to-state inelastic cross sections at a given energy

  15. Excitation decay due to incoherent energy transfer : A comparative study by means of an exact density expansion

    NARCIS (Netherlands)

    Knoester, J.; Himbergen, J.E. Van

    1984-01-01

    In this paper we consider a system of identical, randomly distributed donors, between which incoherent energy transfer takes place, described by coupled rate equations. It is proved, that the well-known diagrammatic series expansion of Gochanour, Andersen, and Fayer for the self-energy, while not an

  16. Energy transfer dynamics in an RC-LH1-PufX tubular photosynthetic membrane

    Energy Technology Data Exchange (ETDEWEB)

    Hsin, J; Sener, M; Schulten, K [Department of Physics and Beckman Institute, University of Illinois at Urbana-Champaign, Urbana (United States); Struempfer, J [Center for Biophysics and Computational Biology and Beckman Institute, University of Illinois at Urbana-Champaign, Urbana (United States); Qian, P; Hunter, C N, E-mail: kschulte@ks.uiuc.ed [Department of Molecular Biology and Biotechnology, University of Sheffield, Sheffield S10 2TN (United Kingdom)

    2010-08-15

    Light absorption and the subsequent transfer of excitation energy are the first two steps in the photosynthetic process, carried out by protein-bound pigments, mainly bacteriochlorophylls (BChls), in photosynthetic bacteria. BChls are anchored in light-harvesting (LH) complexes, such as light-harvesting complex I (LH1), which directly associates with the reaction center (RC), forming the RC-LH1 core complex. In Rhodobacter sphaeroides, RC-LH1 core complexes contain an additional protein, PufX, and assemble into dimeric RC-LH1-PufX core complexes. In the absence of LH complex II (LH2), the former complexes can aggregate into a helically ordered tubular photosynthetic membrane. We have examined the excitation transfer dynamics in a single RC-LH1-PufX core complex dimer using the hierarchical equations of motion for dissipative quantum dynamics that accurately, yet in a computationally costly manner, treat the coupling between BChls and their protein environment. A widely employed description, the generalized Foerster (GF) theory, was also used to calculate the transfer rates of the same excitonic system in order to verify the accuracy of this computationally cheap method. Additionally, in light of the structural uncertainties in the Rba. sphaeroides RC-LH1-PufX core complex, geometrical alterations were introduced into the BChl organization. It is shown that the energy transfer dynamics are not affected by the considered changes in the BChl organization and that the GF theory provides accurate transfer rates. An all-atom model for a tubular photosynthetic membrane is then constructed on the basis of electron microscopy data, and the overall energy transfer properties of this membrane are computed.

  17. Energy transfer dynamics in an RC-LH1-PufX tubular photosynthetic membrane

    International Nuclear Information System (INIS)

    Hsin, J; Sener, M; Schulten, K; Struempfer, J; Qian, P; Hunter, C N

    2010-01-01

    Light absorption and the subsequent transfer of excitation energy are the first two steps in the photosynthetic process, carried out by protein-bound pigments, mainly bacteriochlorophylls (BChls), in photosynthetic bacteria. BChls are anchored in light-harvesting (LH) complexes, such as light-harvesting complex I (LH1), which directly associates with the reaction center (RC), forming the RC-LH1 core complex. In Rhodobacter sphaeroides, RC-LH1 core complexes contain an additional protein, PufX, and assemble into dimeric RC-LH1-PufX core complexes. In the absence of LH complex II (LH2), the former complexes can aggregate into a helically ordered tubular photosynthetic membrane. We have examined the excitation transfer dynamics in a single RC-LH1-PufX core complex dimer using the hierarchical equations of motion for dissipative quantum dynamics that accurately, yet in a computationally costly manner, treat the coupling between BChls and their protein environment. A widely employed description, the generalized Foerster (GF) theory, was also used to calculate the transfer rates of the same excitonic system in order to verify the accuracy of this computationally cheap method. Additionally, in light of the structural uncertainties in the Rba. sphaeroides RC-LH1-PufX core complex, geometrical alterations were introduced into the BChl organization. It is shown that the energy transfer dynamics are not affected by the considered changes in the BChl organization and that the GF theory provides accurate transfer rates. An all-atom model for a tubular photosynthetic membrane is then constructed on the basis of electron microscopy data, and the overall energy transfer properties of this membrane are computed.

  18. Manipulation of Energy Transfer Processes in Nano channels

    International Nuclear Information System (INIS)

    Devaux, A.; Calzaferri, G.

    2010-01-01

    The realisation of molecular assemblies featuring specific macroscopic properties is a prime example for the versatility of supramolecular organisation. Microporous materials such as zeolite L are well suited for the preparation of host-guest composites containing dyes, complexes, or clusters. This short tutorial focuses on the possibilities offered by zeolite L to study and influence Forster resonance energy transfer inside of its nano channels. The highly organised host-guest materials can in turn be structured on a larger scale to form macroscopic patterns, making it possible to create large-scale structures from small, highly organised building blocks for novel optical applications.

  19. Nanoparticles for heat transfer and thermal energy storage

    Science.gov (United States)

    Singh, Dileep; Cingarapu, Sreeram; Timofeeva, Elena V.; Moravek, Michael

    2015-07-14

    An article of manufacture and method of preparation thereof. The article of manufacture and method of making the article includes an eutectic salt solution suspensions and a plurality of nanocrystalline phase change material particles having a coating disposed thereon and the particles capable of undergoing the phase change which provides increase in thermal energy storage. In addition, other articles of manufacture can include a nanofluid additive comprised of nanometer-sized particles consisting of copper decorated graphene particles that provide advanced thermal conductivity to heat transfer fluids.

  20. Single particle tracking and single molecule energy transfer

    CERN Document Server

    Bräuchle, Christoph; Michaelis, Jens

    2009-01-01

    Closing a gap in the literature, this handbook gathers all the information on single particle tracking and single molecule energy transfer. It covers all aspects of this hot and modern topic, from detecting virus entry to membrane diffusion, and from protein folding using spFRET to coupled dye systems, as well recent achievements in the field. Throughout, the first-class editors and top international authors present content of the highest quality, making this a must-have for physical chemists, spectroscopists, molecular physicists and biochemists.

  1. Energy transfer to xanthene dyes in dansylated POPAM dendrimers

    Science.gov (United States)

    Aumanen, Jukka; Korppi-Tommola, Jouko

    2011-12-01

    Excitation energy transfer (EET) in host-guest complexes of dansylated POPAM dendrimers and xanthene dyes have been studied by transient absorption spectroscopy. EET from dansyl periphery to guests: rose bengal, eosin, or fluorescein, showed non-exponential behaviour as a result of distribution of donor-acceptor distances. Time constants range from 100 fs to 8 ps, independent of the dye and the dendrimer generation. Experiments suggested that in dendrimers binding more than one guest, EET among the guests becomes effective. Guest-host and guest-guest interactions induce non-radiative relaxation channels making excitation decays of the guests clearly faster in complexes than in solution.

  2. Energy transfer from an alkene triplet state during pulse radiolysis

    International Nuclear Information System (INIS)

    Barwise, A.J.G.; Gorman, A.A.; Rodgers, M.A.J.

    1976-01-01

    Pulse radiolysis of a benzene solution of norbornene containing low concentrations of anthracene results in delayed formation of anthracene triplet: this is the result of diffusion-controlled energy transfer from the alkene triplet state which has a natural lifetime in benzene of 250 ns. The use of various hydrocarbon acceptors has indicated that Esub(T)=20 000+-500 cm -1 for the relaxed T 1 state of the alkene, at least 5000 cm -1 below that of the spectroscopic state. (Auth.)

  3. Energy-dependent applications of the transfer matrix method

    International Nuclear Information System (INIS)

    Oeztunali, O.I.; Aronson, R.

    1975-01-01

    The transfer matrix method is applied to energy-dependent neutron transport problems for multiplying and nonmultiplying media in one-dimensional plane geometry. Experimental cross sections are used for total, elastic, and inelastic scattering and fission. Numerical solutions are presented for the problem of a unit point isotropic source in an infinite medium of water and for the problem of the critical 235 U slab with finite water reflectors. No iterations were necessary in this method. Numerical results obtained are consistent with physical considerations and compare favorably with the moments method results for the problem of the unit point isotropic source in an infinite water medium. (U.S.)

  4. Energy transfer efficiency measurements in a theta-pinch

    International Nuclear Information System (INIS)

    Cavalcanti, G.H.; Luna, F.R.T.; Trigueiros, A.G.

    1993-01-01

    An increase in energy transfer efficiency of the capacitor bank to the plasma was obtained when the electrical system of a theta-pinch was changed so that the ratio of total inductance to coil inductance was switched of 1/6 to 1/2. A further increase about 20% was obtained for 16/1 ratio. The measurements were made through the current discharge decay, and the spectral analysis of the emitted light from theta-pinch shows a correspondent efficiency increase. (author)

  5. Study of energy transfer to solvent in radiation graft polymerization of styrene onto polyethylene

    International Nuclear Information System (INIS)

    Rabie, A.; Odian, G.

    1977-01-01

    The radiation-initiated graft polymerization of styrene onto polyethylene was studied to determine whether energy transfer to diluent was responsible for the previously observed high orders of dependence of the grafting rate on monomer concentration. n-Octane was used as the diluent instead of benzene. If energy transfer from excited polyethylene to benzene were present, it should not be with n-octane. The percent swelling of polyethylene by various n-octane--styrene mixtures was determined. The compositions of various n-octane--styrene mixtures absorbed inside polyethylene were determined by ultraviolet and refractive index measurements and found to be richer in styrene than the corresponding mixtures in which the polyethylene had been placed. The graft polymerization rates were determined at 0.000761, 0.0371, and 0.213 Mrad/hr and plotted against the inside styrene concentrations on a log-log scale to yield the kinetic orders of dependence of rate on monomer as 2, 3, and 3, respectively. It was concluded that energy transfer to diluent was not responsible for the high-order dependence observed

  6. The influence of molecular rotation on vibration--translation energy transfer

    International Nuclear Information System (INIS)

    McKenzie, R.L.

    1977-01-01

    The role of molecular rotations in the exchange of vibrational and translational energy is investigated for collisions between anharmonic diatomic molecules and structureless atoms. A three-dimensional, semiclassical, impact parameter description is applied with emphasis directed towards the influence of rotational coupling on the net rate of vibrational energy transfer summed over all final rotational states. These results are then related to the predictions of an equivalent collinear collision model, and their comparison allows an evaluation of the collinear approximation. The mechanisms of vibrational energy transfer including rotational transitions are shown to be separable into three classes, with the molecules belonging to each class identified first and foremost by their ratio of fundamental vibrational and rotational frequencies, ω/sub e//B/sub e/, and second by the proximity of their initial state to a near-resonant vibration--rotation transition with a small change in angular momentum. While the dynamics of molecules with ω/sub e//B/sub e/ ratios that are comparable to the range of angular momentum transitions having strong coupling are found to require a complete three-dimensional description, the rates of vibrational energy transfer in molecules with large ω/sub e//B/sub e/ ratios appear to be well approximated by a collinear collision model

  7. Identification of energy storage rate components. Theoretical and experimental approach

    International Nuclear Information System (INIS)

    Oliferuk, W; Maj, M

    2010-01-01

    The subject of the present paper is decomposition of energy storage rate into terms related to different mode of deformation. The stored energy is the change in internal energy due to plastic deformation after specimen unloading. Hence, this energy describes the state of the cold-worked material. Whereas, the ratio of the stored energy increment to the appropriate increment of plastic work is the measure of energy conversion process. This ratio is called the energy storage rate. Experimental results show that the energy storage rate is dependent on plastic strain. This dependence is influenced by different microscopic deformation mechanisms. It has been shown that the energy storage rate can be presented as a sum of particular components. Each of them is related to the separate internal microscopic mechanism. Two of the components are identified. One of them is the storage rate of statistically stored dislocation energy related to uniform deformation. Another one is connected with non-uniform deformation at the grain level. It is the storage rate of the long range stresses energy and geometrically necessary dislocation energy. The maximum of energy storage rate, that appeared at initial stage of plastic deformation is discussed in terms of internal micro-stresses.

  8. Incorporating the Delphi Technique to investigate renewable energy technology transfer in Saudi Arabia

    Science.gov (United States)

    Al-Otaibi, Nasir K.

    Saudi Arabia is a major oil-producing nation facing a rapidly-growing population, high unemployment, climate change, and the depletion of its natural resources, potentially including its oil supply. Technology transfer is regarded as a means to diversify countries' economies beyond their natural resources. This dissertation examined the opportunities and barriers to utilizing technology transfer successfully to build renewable energy resources in Saudi Arabia to diversify the economy beyond oil production. Examples of other developing countries that have successfully used technology transfer to transform their economies are explored, including Japan, Malayasia, and the United Arab Emirates. Brazil is presented as a detailed case study to illustrate its transition to an economy based to a much greater degree than before on renewable energy. Following a pilot study, the Delphi Method was used in this research to gather the opinions of a panel of technology transfer experts consisting of 10 heterogeneous members of different institutions in the Kingdom of Saudi Arabia, including aviation, telecommunication, oil industry, education, health systems, and military and governmental organizations. In three rounds of questioning, the experts identified Education, Dependence on Oil, and Manpower as the 3 most significant factors influencing the potential for success of renewable energy technology transfer for Saudi Arabia. Political factors were also rated toward the "Very Important" end of a Likert scale and were discussed as they impact Education, Oil Dependence, and Manpower. The experts' opinions are presented and interpreted. They form the basis for recommended future research and discussion of how in light of its political system and its dependence on oil, Saudi Arabia can realistically move forward on renewable energy technology transfer and secure its economic future.

  9. Charge and energy transfer interplay in hybrid sensitized solar cells mediated by graphene quantum dots

    International Nuclear Information System (INIS)

    Mihalache, Iuliana; Radoi, Antonio; Mihaila, Mihai; Munteanu, Cornel; Marin, Alexandru; Danila, Mihai; Kusko, Mihaela; Kusko, Cristian

    2015-01-01

    Highlights: • We report a one pot synthesis metod of GQD with controlled size and optoelectronic properties. • An improvement of common N3-DSSC characteristics is achieved when GQDs are used as co-sensitiser. • The role of GQD as cosensitisers in hybrid DSSC was investigated and the interplay between charge and energy transfer phenomena mediated by GQDs was demonstrated. • The GQDs presence determines an inhibition of the recombination processes at the TiO 2 /electrolyte interface. - Abstract: We explored the role of graphene quantum dots (GQDs) as co-sensitizers in hybrid dye sensitized solar cell (DSSC) architectures, focusing on various concurring mechanisms, such as: charge transfer, energy transfer and recombination rate, towards light harvesting improvement. GQDs were prepared by the hydrothermal method that allows the tuning of electronic levels and optical properties by employing appropriate precursors and synthesis conditions. The aim was to realize a type II alignment for TiO 2 /GQD/dye hybrid configuration, using standard N3 Ru-dye in order to improve charge transfer. When GQDs were used as co-sensitizers together with N3 Ru-dye, an improvement in power conversion efficiency was achieved, as shown by electrical measurements. The experimental analysis indicates that this improvement arises from the interplay of various mechanisms mediated by GQDs: (i) enhancement of charge separation and collection due to the cascaded alignment of the energy levels; (ii) energy transfer from GQDs to N3 Ru-dye due to the overlap between GQD photoluminescence and N3 Ru-dye absorption spectra; and (iii) reduction of the electron recombination to the redox couple due to the inhibition of the back electron transfer to the electrolyte by the GQDs

  10. Pregnancy and Multiple Births rate after Transferring 2 or 3 Embryos

    Directory of Open Access Journals (Sweden)

    F Mostajeran

    2006-05-01

    Full Text Available Background: In vitro fertilization (IVF is a progressing common reproduction method and if the number of transferred embryo increases, the pregnancy rate and multiple pregnancies will increase which may lead to higher medical costs and human suffering. We compared pregnancy and multiple pregnancies rate after two or three transferred embryo via IVF. Methods: From April 2003 to June 2004, 301 referred infertile women to Isfahan infertility center underwent IVF with transferring two or three good quality embryos. Results: From 298 patients, 2 and 3 embryos were transferred in 155 patients and in 143 patients, respectively. Pregnancy rate was 19.4% versus 24.5% in 2 and 3 embryos transferred patients, respectively. Twin gestations were found in 5(3.2% of 2 embryos transferred patients and in 11(7.7% of 3 embryos transferred patients. Discussion: Transferring two or three embryos with good quality increase the rate of twin gestations in young women, without significant improve in the chance of singleton conception. Key words: In Vitro Fertilization, Multiple gestations, Embryo transfer

  11. Power Loss Analysis and Comparison of Segmented and Unsegmented Energy Coupling Coils for Wireless Energy Transfer.

    Science.gov (United States)

    Tang, Sai Chun; McDannold, Nathan J

    2015-03-01

    This paper investigated the power losses of unsegmented and segmented energy coupling coils for wireless energy transfer. Four 30-cm energy coupling coils with different winding separations, conductor cross-sectional areas, and number of turns were developed. The four coils were tested in both unsegmented and segmented configurations. The winding conduction and intrawinding dielectric losses of the coils were evaluated individually based on a well-established lumped circuit model. We found that the intrawinding dielectric loss can be as much as seven times higher than the winding conduction loss at 6.78 MHz when the unsegmented coil is tightly wound. The dielectric loss of an unsegmented coil can be reduced by increasing the winding separation or reducing the number of turns, but the power transfer capability is reduced because of the reduced magnetomotive force. Coil segmentation using resonant capacitors has recently been proposed to significantly reduce the operating voltage of a coil to a safe level in wireless energy transfer for medical implants. Here, we found that it can naturally eliminate the dielectric loss. The coil segmentation method and the power loss analysis used in this paper could be applied to the transmitting, receiving, and resonant coils in two- and four-coil energy transfer systems.

  12. Vibronic coupling explains the ultrafast carotenoid-to-bacteriochlorophyll energy transfer in natural and artificial light harvesters

    Energy Technology Data Exchange (ETDEWEB)

    Perlík, Václav; Seibt, Joachim; Šanda, František; Mančal, Tomáš [Institute of Physics, Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 5, Prague 121 16 (Czech Republic); Cranston, Laura J.; Cogdell, Richard J. [Institute of Molecular Cell and System Biology, College of Medical, Veterinary and Life Sciences, University of Glasgow, Glasgow Biomedical Research Centre, 120 University Place, Glasgow G12 8TA, Scotland (United Kingdom); Lincoln, Craig N.; Hauer, Jürgen, E-mail: juergen.hauer@tuwien.ac.at [Photonics Institute, Vienna University of Technology, Gusshausstrasse 27, 1040 Vienna (Austria); Savolainen, Janne [Department of Physical Chemistry II, Ruhr-University Bochum, 44780 Bochum (Germany)

    2015-06-07

    The initial energy transfer steps in photosynthesis occur on ultrafast timescales. We analyze the carotenoid to bacteriochlorophyll energy transfer in LH2 Marichromatium purpuratum as well as in an artificial light-harvesting dyad system by using transient grating and two-dimensional electronic spectroscopy with 10 fs time resolution. We find that Förster-type models reproduce the experimentally observed 60 fs transfer times, but overestimate coupling constants, which lead to a disagreement with both linear absorption and electronic 2D-spectra. We show that a vibronic model, which treats carotenoid vibrations on both electronic ground and excited states as part of the system’s Hamiltonian, reproduces all measured quantities. Importantly, the vibronic model presented here can explain the fast energy transfer rates with only moderate coupling constants, which are in agreement with structure based calculations. Counterintuitively, the vibrational levels on the carotenoid electronic ground state play the central role in the excited state population transfer to bacteriochlorophyll; resonance between the donor-acceptor energy gap and the vibrational ground state energies is the physical basis of the ultrafast energy transfer rates in these systems.

  13. Vibronic coupling explains the ultrafast carotenoid-to-bacteriochlorophyll energy transfer in natural and artificial light harvesters

    International Nuclear Information System (INIS)

    Perlík, Václav; Seibt, Joachim; Šanda, František; Mančal, Tomáš; Cranston, Laura J.; Cogdell, Richard J.; Lincoln, Craig N.; Hauer, Jürgen; Savolainen, Janne

    2015-01-01

    The initial energy transfer steps in photosynthesis occur on ultrafast timescales. We analyze the carotenoid to bacteriochlorophyll energy transfer in LH2 Marichromatium purpuratum as well as in an artificial light-harvesting dyad system by using transient grating and two-dimensional electronic spectroscopy with 10 fs time resolution. We find that Förster-type models reproduce the experimentally observed 60 fs transfer times, but overestimate coupling constants, which lead to a disagreement with both linear absorption and electronic 2D-spectra. We show that a vibronic model, which treats carotenoid vibrations on both electronic ground and excited states as part of the system’s Hamiltonian, reproduces all measured quantities. Importantly, the vibronic model presented here can explain the fast energy transfer rates with only moderate coupling constants, which are in agreement with structure based calculations. Counterintuitively, the vibrational levels on the carotenoid electronic ground state play the central role in the excited state population transfer to bacteriochlorophyll; resonance between the donor-acceptor energy gap and the vibrational ground state energies is the physical basis of the ultrafast energy transfer rates in these systems

  14. Effect of high linear energy transfer radiation on biological membranes

    International Nuclear Information System (INIS)

    Choudhary, D.; Srivastava, M.; Kale, R.K.; Sarma, A.

    1998-01-01

    Cellular membranes are vital elements, and their integrity is extremely essential for the viability of the cells. We studied the effects of high linear energy transfer (LET) radiation on the membranes. Rabbit erythrocytes (1 x 10 7 cells/ml) and microsomes (0.6 mg protein/ml) prepared from liver of rats were irradiated with 7 Li ions of energy 6.42 MeV/u and 16 O ions of energy 4.25 MeV/u having maximum LET values of 354 keV/μm and 1130 keV/μm, respectively. 7 Li- and 16 O-induced microsomal lipid peroxidation was found to increase with fluence. The 16 O ions were more effective than 7 Li ions, which could be due to the denser energy distribution in the track and the yield of free radicals. These findings suggested that the biological membranes could be peroxidized on exposure to high-LET radiation. Inhibition of the lipid peroxidation was observed in the presence of a membrane-active drug, chlorpromazine (CPZ), which could be due to scavenging of free radicals (mainly HO. and ROO.), electron donation, and hydrogen transfer reactions. The 7 Li and 16 O ions also induced hemolysis in erythrocytes. The extent of hemolysis was found to be a function of time and fluence, and showed a characteristic sigmoidal pattern. The 16 O ions were more effective in the lower fluence range than 7 Li ions. These results were compared with lipid peroxidation and hemolysis induced by gamma-radiation. (orig.)

  15. Heat transfer and energy efficiency in infrared paper dryers

    Energy Technology Data Exchange (ETDEWEB)

    Pettersson, Magnus

    1999-11-01

    Infrared (IR) dryers are widely used in the paper industry, mainly in the production of coated paper grades. The thesis deals with various aspects of heat transfer and energy use in infrared heaters and dryers as employed in the paper industry. Both gas-fired and electric IR dryers are considered and compared. The thesis also provides an introduction to infrared heaters and infrared drying, including a review of recent literature in the field. The transport of thermal radiation inside a paper sheet was investigated and different IR dryers were compared in terms of their ability to transfer energy to the internal parts of a paper sheet. Although there were evident differences in the absorption of radiation between gas-fired and electric IR dryers, the distinction was found not to be as important as has generally been believed. The main differences appeared to be due to the choice of a one- or a two-sided dryer solution, rather than the spectral distributions emitted by the dryers. A method for evaluating the radiation efficiency of IR heaters was proposed. An electric IR heater was evaluated in the laboratory. The radiation efficiency of the heater was shown to be strongly dependent on the power level. The maximum efficiency, found at high power level, was close to 60 %. A procedure for evaluation of the total energy transfer efficiency of an infrared paper dryer was proposed and used in the evaluation of an electric IR dryer operating in an industrial coating machine. The efficiency of the dryer was roughly 40 %. A model for an electric IR heater was developed. The model includes non-grey radiative heat transfer between the different parts of the heater, as well as conduction in reflector material and convective cooling of the surfaces. Using IR module voltage as the only input, model predictions of temperatures and heat flux were found to agree well with experimental data both at steady state and under transient conditions. The model was also extended to include

  16. Heat transfer enhancement in energy storage in spherical capsules filled with paraffin wax and metal beads

    International Nuclear Information System (INIS)

    Ettouney, Hisham; Alatiqi, Imad; Al-Sahali, Mohammad; Al-Hajirie, Khalida

    2006-01-01

    Energy storage is an attractive option to conserve limited energy resources, where more than 50% of the generated industrial energy is discarded in cooling water and stack gases. This study focuses on the evaluation of heat transfer enhancement in phase change energy storage units. The experiments are performed using spherical capsules filled with paraffin wax and metal beads. The experiments are conducted by inserting a single spherical capsule filled with wax and metal beads in a stream of hot/cold air. Experimental measurements include the temperature field within the spherical capsule and in the air stream. To determine the enhancement effects of the metal beads, the measured data is correlated against those for a spherical capsule filled with pure wax. Data analysis shows a reduction of 15% in the melting and solidification times upon increasing the number and diameter of the metal beads. This reduction is caused by a similar decrease in the thermal load of the sphere due to replacement of the wax by metal beads. The small size of the spherical capsule limits the enhancement effects; this is evident upon comparison of the heat transfer in a larger size, double pipe energy storage unit, where 2% of the wax volume is replaced with metal inserts, result in a three fold reduction in the melting/solidification time and a similar enhancement in the heat transfer rate

  17. Light harvesting via energy transfer in the dye solar cell

    Energy Technology Data Exchange (ETDEWEB)

    Siegers, Conrad

    2007-11-09

    The PhD-thesis ''Light Harvesting via Energy Transfer in the Dye Solar Cell'' (University of Freiburg, July 2007) describes the conceptual design, synthesis and testing of energy donor acceptor sensitizers for the dye solar cell (DSC). Under monochromatic illumination solar cells sensitized with the novel donor acceptor systems revealed a higher power conversion efficiency than cells containing exclusively the acceptor component. The following approach led to this conclusion: (i) the choice of suitable chromophores as energy donor and acceptor moieties according to the Foerster-theory, (ii) the synthesis of different donor acceptor systems, (iii) the development of a methodology allowing the quantification of energy transfer within dye solar cells, and (iv) the evaluation of characteristics of DSCs that were sensitized with the different donor acceptor systems. The acceptor chromophores used in this work were derived from [Ru(dcbpy)2acac]Cl (dcbpy = 4,4'-dicarboxy-2,2'-bipyridin, acac = acetylacetonato). This complex offered the opportunity to introduce substituents at the acac-ligand's terminal CH3 groups without significantly affecting its excellent photoelectrochemical properties. Alkylated 4-amino-1,8-naphthalimides (termed Fluorols in the following) were used as energy donor chromophores. This class of compounds fulfils the requirements for efficient energy transfer to [Ru(dcbpy)2acac]Cl. Covalently linking donor and acceptor chromophores to one another was achieved by two different concepts. A dyad comprising one donor and one acceptor chromophore was synthesized by subsequent hydrosilylation steps of an olefin-bearing donor and an acceptor precursor to the dihydrosilane HSiMe2-CH2CH2-SiMe2H. A series of polymers comprising multiple donor and acceptor units was made by the addition of alkyne-bearing chromophores to hyperbranched polyglycerol azide (''Click-chemistry''). In this series the donor acceptor

  18. Interregional technology transfer on advanced materials and renewable energy systems

    International Nuclear Information System (INIS)

    Agrianidis, P.; David, C.; Anthymidis, K.; Ekhrawat, M.

    2008-01-01

    Advanced materials are used in most industrial sectors and human activities and all developing and developed countries as well as international organizations eg. United Nations have established work groups, which survey the national and global state and developments in the area of advanced materials trying to establish strategies on that crucial technology sector. These strategies are focused on research and technology activities including education and vocation training, as well as stimulus for the starting up of new industrial applications. To introduce such a concept in Greece and especially in Northern Greece, the Technological Education Institute of Serres has initiated an Interregional technology transfer project in this scientific field. This project includes mod topics of advanced materials technology with emphasison specific industrial applications (renewable energy systems). The project demonstrates the development of a prototype photovoltaic thermal system in terms of a new industrial product. The product development procedure consists of steps such as initial product design, materials selection and processing, prototype design and manufacturing, quality control, performance optimization, but also control of materials ecocompatibility according to the national trends of life cycle design and recycling techniques. Keywords: Interregional technology transfer, materials, renewable energy systems

  19. Interregional technology transfer on advanced materials and renewable energy systems

    Energy Technology Data Exchange (ETDEWEB)

    Agrianidis, P.; David, C.; Anthymidis, K.; Ekhrawat, M. [Department of Mechanical Engineering, Technological Educational Institute of Serres, Serres (Greece)

    2008-07-01

    Advanced materials are used in most industrial sectors and human activities and all developing and developed countries as well as international organizations eg. United Nations have established work groups, which survey the national and global state and developments in the area of advanced materials trying to establish strategies on that crucial technology sector. These strategies are focused on research and technology activities including education and vocation training, as well as stimulus for the starting up of new industrial applications. To introduce such a concept in Greece and especially in Northern Greece, the Technological Education Institute of Serres has initiated an Interregional technology transfer project in this scientific field. This project includes mod topics of advanced materials technology with emphasison specific industrial applications (renewable energy systems). The project demonstrates the development of a prototype photovoltaic thermal system in terms of a new industrial product. The product development procedure consists of steps such as initial product design, materials selection and processing, prototype design and manufacturing, quality control, performance optimization, but also control of materials ecocompatibility according to the national trends of life cycle design and recycling techniques. Keywords: Interregional technology transfer, materials, renewable energy systems.

  20. Energy transfer mechanism in CsI:Eu crystal

    International Nuclear Information System (INIS)

    Yakovlev, V.; Trefilova, L.; Karnaukhova, A.; Ovcharenko, N.

    2014-01-01

    This paper studies the scintillation process in CsI:Eu crystal exposed to the pulse electron irradiation (E=0.25 MeV, t 1/2 =15 ns and W=0.003 J/cm 2 ). It has been proved that the energy transfer from the lattice to Eu 2+ ions in CsI:Eu occurs through the re-absorption of STE emission. The proposed model rests on the following experimental facts: (1) the activator emission at 2.68 eV rises gradually after the decay of the excitation pulse even at temperature lower than 90 K when V k centers are immobile; (2) the rise time of 2.68 eV emission and the decay time of STE emission have the same temperature dependences at T=78–300 K; (3) the excitation spectrum of 2.68 eV emission overlaps the emission spectrum of STE. -- Highlights: • The scintillation process in CsI:Eu was studied under pulsed electron irradiation. • A model of the energy transfer from the lattice to Eu 2+ ions in CsI:Eu was proposed. • Eu 2+ ions in CsI:Eu reabsorb the π-emission of self-trapped excitons

  1. Fluorescence resonance energy transfer sensors for quantitative monitoring of pentose and disaccharide accumulation in bacteria

    Directory of Open Access Journals (Sweden)

    Looger Loren L

    2008-06-01

    Full Text Available Abstract Background Engineering microorganisms to improve metabolite flux requires detailed knowledge of the concentrations and flux rates of metabolites and metabolic intermediates in vivo. Fluorescence resonance energy transfer sensors represent a promising technology for measuring metabolite levels and corresponding rate changes in live cells. These sensors have been applied successfully in mammalian and plant cells but potentially could also be used to monitor steady-state levels of metabolites in microorganisms using fluorimetric assays. Sensors for hexose and pentose carbohydrates could help in the development of fermentative microorganisms, for example, for biofuels applications. Arabinose is one of the carbohydrates to be monitored during biofuels production from lignocellulose, while maltose is an important degradation product of starch that is relevant for starch-derived biofuels production. Results An Escherichia coli expression vector compatible with phage λ recombination technology was constructed to facilitate sensor construction and was used to generate a novel fluorescence resonance energy transfer sensor for arabinose. In parallel, a strategy for improving the sensor signal was applied to construct an improved maltose sensor. Both sensors were expressed in the cytosol of E. coli and sugar accumulation was monitored using a simple fluorimetric assay of E. coli cultures in microtiter plates. In the case of both nanosensors, the addition of the respective ligand led to concentration-dependent fluorescence resonance energy transfer responses allowing quantitative analysis of the intracellular sugar levels at given extracellular supply levels as well as accumulation rates. Conclusion The nanosensor destination vector combined with the optimization strategy for sensor responses should help to accelerate the development of metabolite sensors. The new carbohydrate fluorescence resonance energy transfer sensors can be used for in vivo

  2. Inverse problem of estimating transient heat transfer rate on external wall of forced convection pipe

    International Nuclear Information System (INIS)

    Chen, W.-L.; Yang, Y.-C.; Chang, W.-J.; Lee, H.-L.

    2008-01-01

    In this study, a conjugate gradient method based inverse algorithm is applied to estimate the unknown space and time dependent heat transfer rate on the external wall of a pipe system using temperature measurements. It is assumed that no prior information is available on the functional form of the unknown heat transfer rate; hence, the procedure is classified as function estimation in the inverse calculation. The accuracy of the inverse analysis is examined by using simulated exact and inexact temperature measurements. Results show that an excellent estimation of the space and time dependent heat transfer rate can be obtained for the test case considered in this study

  3. Core-debris quenching-heat-transfer rates under top- and bottom-reflood conditions

    International Nuclear Information System (INIS)

    Ginsberg, T.; Tutu, N.; Klages, J.; Schwarz, C.E.; Sanborn, Y.

    1983-02-01

    This paper presents recent experimental data for the quench-heat-transfer characteristics of superheated packed beds of spheres which were cooled, in separate experiments, by top- and bottom-flooding modes. Experiments were carried out with beds of 3-mm steel spheres of 330-mm height. The initial bed temperature was 810 K. The observed heat-transfer rates are strongly dependent on the mode of water injection. The results suggest that top-flood bed quench heat transfer is limited by the rate at which water can penetrate the bed under two-phase countercurrent-flow conditions. With bottom-reflood the heat-transfer rate is an order-of-magnitude greater than under top-flood conditions and appears to be limited by particle-to-fluid film boiling heat transfer

  4. Instrumented home energy rating and commissioning

    Energy Technology Data Exchange (ETDEWEB)

    Wray, Craig P.; Walker, Iain S.; Sherman, Max H.

    2003-05-01

    Currently, houses do not perform optimally or even as many codes and forecasts predict, largely because they are field assembled and there is no consistent process to identify deficiencies or to correct them. Solving this problem requires field performance evaluations using appropriate and agreed upon procedures in the form of a new process called residential commissioning. The purpose of this project is to develop and document these procedures and to demonstrate the value that applying them could provide in both new and existing California houses. This project has four specific objectives: to develop metrics and diagnostics for assessing house performance, to provide information on the potential benefits of commissioning using a whole-house approach, to develop programmatic guidelines for commissioning, and to conduct outreach efforts to transfer project results to industry stakeholders. The primary outcomes from this project are the development of residential commissioning guidelines and the analytical confirmation that there are significant potential benefits associated with commissioning California houses, particularly existing ones. In addition, we have made substantial advances in understanding the accuracy and usability of diagnostics for commissioning houses. In some cases, we have been able to work with equipment manufacturers to improve these aspects of their diagnostic tools. These outcomes provide a solid foundation on which to build a residential commissioning program in California. We expect that a concerted effort will be necessary to integrate such a program with existing building industry efforts and to demonstrate its use in the field.

  5. Live birth rate and number of blastomeres on day 2 transfer

    DEFF Research Database (Denmark)

    Azzarello, Antonino; Hoest, Thomas; Hay-Schmidt, Anders

    2016-01-01

    -lapse assessment, ACDs and/or recalculated fragmentation >25 % was recognized in 106/578 (18.3 %) of transferred embryos. None of them resulted in a live birth. After exclusion of these embryos, the number of blastomeres on the day of transfer did not have any impact on life birth rate. Conclusion Conventional...

  6. Epidemiology of distal radius fractures in polytrauma patients and the influence of high traumatic energy transfer.

    Science.gov (United States)

    Ferree, Steven; van der Vliet, Quirine M J; Nawijn, Femke; Bhashyam, Abhiram R; Houwert, Roderick M; Leenen, Luke P H; Hietbrink, Falco

    2018-03-01

    For several extremity fractures differences in morphology, incidence rate and functional outcome were found when polytrauma patients were compared to patients with an isolated injury. This is not proven for distal radius fractures (DRF). Therefore, this study aimed to analyse fracture morphology in relation to energy transfer in both poly- and mono-trauma patients with a DRF. This was a retrospective cohort study. All patients aged 16 years and older with a DRF were included. Patients with an Injury Severity Score of 16 or higher were classified as polytrauma patients. Injuries were defined as high or low energy. All DRFs were classified using the AO/OTA fracture classification system. A total of 830 patients with a DRF were included, 12% were polytrauma. The incidence rate of DRF in polytrauma patients was 3.5%. Ipsilateral upper extremity injury was found in >30% of polytrauma and high-energy monotrauma patients, compared to 5% in low-energy monotrauma patients. More type C DRF were found in polytrauma and high-energy monotrauma patients versus low-energy monotrauma patients. Operative intervention rates for all types of DRF were similar for polytrauma and high-energy monotrauma patients. Non-union rates were higher in polytrauma patients. Higher energy mechanisms of injury, in polytrauma and high-energy monotrauma patients, were associated with more severe complex articular distal radius fractures and more ipsilateral upper extremity injuries. Polytrauma and high-energy monotrauma patient have a similar fracture morphology. However, polytrauma patients have in addition to more injured body regions also more non-union related interventions than high-energy monotrauma patients. Copyright © 2018 Elsevier Ltd. All rights reserved.

  7. Photovoltaic module energy rating methodology development

    Energy Technology Data Exchange (ETDEWEB)

    Kroposki, B.; Myers, D.; Emery, K.; Mrig, L. [National Renewable Energy Lab., Golden, CO (United States); Whitaker, C.; Newmiller, J. [Endecon Engineering, San Ramon, CA (United States)

    1996-05-01

    A consensus-based methodology to calculate the energy output of a PV module will be described in this paper. The methodology develops a simple measure of PV module performance that provides for a realistic estimate of how a module will perform in specific applications. The approach makes use of the weather data profiles that describe conditions throughout the United States and emphasizes performance differences between various module types. An industry-representative Technical Review Committee has been assembled to provide feedback and guidance on the strawman and final approach used in developing the methodology.

  8. Transfer rates of 19 typical pesticides and the relationship with their physicochemical property.

    Science.gov (United States)

    Chen, Hongping; Pan, Meiling; Pan, Rong; Zhang, Minglu; Liu, Xin; Lu, Chengyin

    2015-01-21

    Determining the transfer rate of pesticides during tea brewing is important to identify the potential exposure risks from pesticide residues in tea. In this study, the transfer rates of 19 typical pesticides from tea to brewing were investigated using gas chromatography tandem mass and ultraperformance liquid chromatography tandem mass. The leaching rates of five pesticides (isocarbophos, triazophos, fenvalerate, buprofezin, and pyridaben) during tea brewing were first reported. The pesticides exhibited different transfer rates; however, this result was not related to residual concentrations and tea types. Pesticides with low octanol-water partition coefficients (Logkow) and high water solubility demonstrated high transfer rates. The transfer rates of pesticides with water solubility > 29 mg L(-1) (or 25% (or 2.48) were >65% (or <35%). This result indicates that water solubility at approximately 20 mg L(-1) and LogKow at approximately 2.0 could be the demarcation lines of transfer rate. The results of this study can be used as a guide in the application of pesticides to tea trees and establishment of maximum residue limits of pesticides in tea to reduce pesticide exposure in humans.

  9. Energy transfer modelling of active thermoacoustic engines via Lagrangian thermoacoustic dynamics

    International Nuclear Information System (INIS)

    Hong, Boe-Shong; Chou, Chia-Yu

    2014-01-01

    Highlights: • Resonant control on thermoacoustic engines to amplify power rating. • Least-action principle of thermoacoustic dynamics to shape engine chamber. • Spatiotemporal transfer function into feedback systems. • Conservation law of thermoacoustic storage to figure out engine cycles. • Robin boundary condition to identify flow leakage. - Abstract: This paper develops energy-transfer modelling of active thermoacoustic engines resonantly controlled on boundary for amplification of power rating toward satisfaction of renewable industry. Therein the wave equation of thermoacoustic dynamics in resonators with non-uniform media and boundary actuations is derived and then turned into a least-action principle. With this least-action principle, we obtain the governing equation of longitudinal resonators with spatially variant cross-section areas to investigate how to shape the resonator for boosting piston stroke and power-transmission efficiency. It is followed by spatiotemporal transfer-function modelling that functionally represents the dynamics and interprets the boundary actuations into internal inputs. This helps formulate the overall dynamics into feedback-interconnection between the thermoacoustic dynamics in the resonator and the mechatronic dynamics of the alternative current generator, so that synthesis of feedback systems can be applied to design the entire engine. Transfer-function modelling following least-action principle leads to the conservation law of thermoacoustic storage, which figures out engine cycles, the most fundamental principle in designing active thermoacoustic engines. Based on such feedback realization, digital signal processing is programmed to numerically assess power ratings of active designs

  10. Modeling the cooperative energy transfer dynamics of quantum cutting for solar cells

    NARCIS (Netherlands)

    Rabouw, Freddy T.; Meijerink, Andries

    2015-01-01

    Cooperative energy transfer (ET) is a quantum cutting (or downconversion) process where a luminescent center splits its excited state energy in two by simultaneous transfer to two nearby acceptor centers, thus yielding two low-energy photons for each high-energy photon absorbed. It has the potential

  11. The Clean Energy Transfer : preliminary assesment of the potential for a clean energy transfer between Manitoba and Ontario

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-09-01

    Ontario may have an electrical power shortfall of as much as 25,000 MW by 2020, due to phase-out of coal fired plants, a general increase in demand and existing plants reaching the end of their design lives. Manitoba has approximately 5,000 MW of new hydroelectric power potential which could help to reduce this shortfall. This document reports on a study between the Manitoba government, the Ontario government, Manitoba Hydro, Hydro One, and the Ontario Independent Electricity Market Operator to provide an incremental transfer capability of 1,500 MW between the provinces. This is known as the Clean Energy Transfer Initiative (CETI). The current east-west transmission grid is limited to about 200 MW and is thus not sufficient for this project. Three transmission options have been studied. The report claims that CETI would be the largest single project in terms of greenhouse gas reductions. It is also claimed to potentially benefit Aboriginal groups by increasing employment and business opportunities. Also, tax revenues would be substantial. The most likely alternative energy supply is considered to be the combined cycle gas turbine which, according to the study, would cost about the same amount per MWh, excluding environmental credits. 4 tabs., 11 figs.

  12. The Clean Energy Transfer : preliminary assesment of the potential for a clean energy transfer between Manitoba and Ontario

    International Nuclear Information System (INIS)

    2004-09-01

    Ontario may have an electrical power shortfall of as much as 25,000 MW by 2020, due to phase-out of coal fired plants, a general increase in demand and existing plants reaching the end of their design lives. Manitoba has approximately 5,000 MW of new hydroelectric power potential which could help to reduce this shortfall. This document reports on a study between the Manitoba government, the Ontario government, Manitoba Hydro, Hydro One, and the Ontario Independent Electricity Market Operator to provide an incremental transfer capability of 1,500 MW between the provinces. This is known as the Clean Energy Transfer Initiative (CETI). The current east-west transmission grid is limited to about 200 MW and is thus not sufficient for this project. Three transmission options have been studied. The report claims that CETI would be the largest single project in terms of greenhouse gas reductions. It is also claimed to potentially benefit Aboriginal groups by increasing employment and business opportunities. Also, tax revenues would be substantial. The most likely alternative energy supply is considered to be the combined cycle gas turbine which, according to the study, would cost about the same amount per MWh, excluding environmental credits. 4 tabs., 11 figs

  13. Reducing twin pregnancy rates after IVF--elective single embryo transfer (eSET).

    LENUS (Irish Health Repository)

    Milne, P

    2010-01-01

    Multiple pregnancy is a major complication of IVF and is associated with increased maternal, fetal and neonatal morbidity. Elective single embryo transfer (eSET) during IVF, rather than the more standard transfer of two embryos (double embryo transfer or DET), has been shown to significantly reduce the multiple pregnancy rate associated with IVF, while maintaining acceptable pregnancy rates. Couples undergoing IVF in 2008 who met good prognostic criteria had eSET performed. Pregnancy and twinning rates were compared with those for similar couples in 2007 who had DET. Couples unsuccessful with a fresh cycle of treatment had subsequent frozen embryo transfer cycles with DET. The cumulative pregnancy rate was similar for each group. However there were no multiple pregnancies in the eSET group, compared to 4 twins of 5 pregnancies in the DET group. 96% of eligible couples agreed to eSET. ESET is successful in and acceptable to good prognosis Irish couples undergoing IVF.

  14. An analytical solution for modeling thermal energy transfer in a confined aquifer system

    Science.gov (United States)

    Shaw-Yang, Yang; Hund-der, Yeh

    2008-12-01

    A mathematical model is developed for simulating the thermal energy transfer in a confined aquifer with different geological properties in the underlying and overlying rocks. The solutions for temperature distributions in the aquifer, underlying rock, and overlying rock are derived by the Laplace transforms and their corresponding time-domain solutions are evaluated by the modified Crump method. Field data adopted from the literature are used as examples to demonstrate the applicability of the solutions in modeling the heat transfer in an aquifer thermal energy storage (ATES) system. The results show that the aquifer temperature increases with time, injection flow rate, and water temperature. However, the temperature decreases with increasing radial and vertical distances. The heat transfer in the rocks is slow and has an effect on the aquifer temperature only after a long period of injection time. The influence distance depends on the aquifer physical and thermal properties, injection flow rate, and injected water temperature. A larger value of thermal diffusivity or injection flow rate will result in a longer influence distance. The present solution can be used as a tool for designing the heat injection facilities for an ATES system.

  15. Förster resonance energy transfer between acridinediones and selected fluorophores—Medium dependence

    Energy Technology Data Exchange (ETDEWEB)

    Krishnaveni, R. [National Centre for Ultrafast Processes, University of Madras, Taramani Campus, Chennai-600113 (India); Ramamurthy, P., E-mail: prm60@hotmail.com [National Centre for Ultrafast Processes, University of Madras, Taramani Campus, Chennai-600113 (India)

    2013-06-15

    We report highly efficient Förster resonance energy transfer process between acridinedione dyes and basic fluorophores. FRET between free and β-cyclodextrin modified acridinediones as donors and fluorophoric dyes like safranine as acceptor were investigated in an alcoholic medium, polymer solution and a polymeric film. Efficiency of the processes were experimentally found by steady-state and time-resolved experiments for different donor and acceptor combinations. The associated spectral parameters viz., R{sup 0}, J(λ) were calculated, the Stern–Volmer relations based on fluorescence intensity and lifetime were constructed and the rates of energy transfer were calculated. The results indicated that the dominant mechanism responsible for the excitation energy transfer is that of resonance transfer due to long range dipole–dipole interaction and the process was found to be highly efficient when the medium was a constrained one as in the case of a polymeric film. A multifold enhancement in efficiency of energy transfer was also observed when the donor was a modified acridinedione when compared to a free acridinedione. The reason is attributed to the effective binding of the acceptor into the cavity of β-cyclodextrin. Highlights: ► FRET between acridinediones and fluorophoric acceptors were investigated. ► FRET analysis was carried out in methanol, a 5% PVA solution and in PVA matrix. ► FRET efficiency was maximum when the medium was PVA matrix. ► FRET efficiency was also more when β-CD modified ADR is used as the donor. ► Efficiency enhancement is due to the inclusion of acceptor into the cavity of β-CD.

  16. Energy transfer and reaction dynamics of matrix-isolated 1,2-difluoroethane-d4

    Science.gov (United States)

    Raff, Lionel M.

    1990-09-01

    The molecular dynamics of vibrationally excited 1,2-difluoroethane-d4 isolated in Ar, Kr, and Xe matrices at 12 K are investigated using trajectory methods. The matrix model is an fcc crystal containing 125 unit cells with 666 atoms in a cubic (5×5×5) arrangement. It is assumed that 1,2-difluoroethane-d4 is held interstitially within the volume bounded by the innermost unit cell of the crystal. The transport effects of the bulk are simulated using the velocity reset method introduced by Riley, Coltrin, and Diestler [J. Chem. Phys. 88, 5934 (1988)]. The system potential is written as the separable sum of a lattice potential, a lattice-molecule interaction and a gas-phase potential for 1,2-difluoroethane. The first two of these are assumed to have pairwise form while the molecular potential is a modified form of the global potential previously developed for 1,2-difluoroethane [J. Phys. Chem. 91, 3266 (1987)]. Calculated sublimation energies for the pure crystals are in good accord with the experimental data. The distribution of metastable-state energies for matrix-isolated 1,2-difluoroethane-d4 is Gaussian in form. In krypton, the full width at half maximum for the distribution is 0.37 eV. For a total excitation energy of 6.314 eV, the observed dynamic processes are vibrational relaxation, orientational exchange, and four-center DF elimination reactions. The first of these processes is characterized by a near linear, first-order decay curve with rate coefficients in the range 1.30-1.48×1011 s-1. The average rates in krypton and xenon are nearly equal. The process is slightly slower in argon. The decay curves exhibit characteristic high-frequency oscillations that are generally seen in energy transfer studies. It is demonstrated that these oscillations are associated with the frequencies for intramolecular energy transfer so that the entire frequency spectrum for such transfer processes can be obtained from the Fourier transform of the decay curve. Orientational

  17. Embryo transfer simulation improves pregnancy rates and decreases time to proficiency in Reproductive Endocrinology and Infertility fellow embryo transfers.

    Science.gov (United States)

    Heitmann, Ryan J; Hill, Micah J; Csokmay, John M; Pilgrim, Justin; DeCherney, Alan H; Deering, Shad

    2017-05-01

    To design and evaluate an ET simulator to train Reproductive Endocrinology and Infertility (REI) fellows' techniques of ET. Simulation model development and retrospective cohort analysis. Not applicable. Patients undergoing IVF. Simulation model evaluation and implementation of ET simulation training. Pregnancy rates. The REI fellow and faculty evaluation responses (n = 19/21 [90%]) of the model demonstrated realistic characteristics, with evaluators concluding the model was suitable for training in almost all evaluated areas. A total of 12 REI fellows who performed ET were analyzed: 6 before ET trainer and 6 after ET trainer. Pregnancy rates were 31% in the initial 10 ETs per fellow before simulator vs. 46% after simulator. One of six pre-ET trainer fellows (17%) had pregnancy rates ≥40% in their first 10 ETs; whereas four of six post-ET trainer fellows had pregnancy rates ≥40% in their first 10 ETs. The average number of ETs to obtain >40% pregnancy efficiency was 27 ETs before trainer vs. 15 ETs after trainer. Pregnancy rates were similar in the two groups after 20 ETs, and collective terminal pregnancy rates were >50% after 40 ETs. Embryo transfer simulation improved REI fellow pregnancy rates in their first 10 transfers and led to a more rapid ET proficiency. These data suggest potential value in adopting ET simulation, even in programs with a robust history of live ET in fellowship training. Published by Elsevier Inc.

  18. Energy rating procedure for PV-modules; Energy rating procedure voor PV-modules

    Energy Technology Data Exchange (ETDEWEB)

    Van der Borg, N.J.C.M.; Jansen, M.J. [ECN Zon, Petten (Netherlands)

    2005-10-15

    The performance of PV-modules is usually characterized by the nominal power at standard test conditions. However more relevant for the end-user is the energy production. To arrive at a so-called energy rating procedure the P(G{sub i},T{sub m}) matrix is defined, which makes it possible to calculate the expected annual energy production of a PV-module at any given location with known frequency distribution of horizontal irradiation and ambient temperature. In order to make the de P(G{sub i},T{sub m}) independent of the time and location of the tests the effective irradiation (G{sub i}) is measured with a device with the same characteristics as the module under test. Such a device can be a suitable reference cell or, even better, the module under test itself. The latter, however, is only possible in case the module under test is stable in time. Measurements were performed to test the applicability of the so-called self-reference for a-Si modules. Furthermore the difference between the effective irradiance and the real irradiance (measured with a pyranometer) was quantified for the test location Petten, the Netherlands. The conclusions are: Self-reference is not applicable for a-Si modules because of the time instability, even after 1 full year of degradation; Self-reference signals (the short circuit current of the module under test) can be calibrated outdoor by comparison with a pyranometer at irradiance levels above 800 W/m{sup 2}. The uncertainty of such a calibration is within 3%; The difference between the effective irradiance and the real irradiance on annual basis at Petten is virtually zero for x-Si modules and about 1% for a-Si modules. [Dutch] Het is gebruikelijk om de prestatie van PV-modules te karakteriseren met het nominale vermogen onder standaard testcondities (STC). Echter dit nominaal vermogen geeft geen directe indicatie voor de energieopbrengst. Om tot een karakteristiek voor de energie-opbrengst (energy rating) te komen wordt de prestatie van de

  19. Activation energy of etching for CR-39 as a function of linear energy transfer of the incident particles

    CERN Document Server

    Awad, E M

    1999-01-01

    In this work, we have studied the effect of the radiation damage caused by the incident particles on the activation energy of etching for CR-39 samples. The damage produced by the incident particle is expressed in terms of the linear energy transfer (LET). CR-39 samples from American Acrylic were irradiated to three different LET particles. These are N (LET sub 2 sub 0 sub 0 = 20 KeV/mu m) as a light particle, Fe (LET sub 2 sub 0 sub 0 = 110 KeV/mu m) as a medium particle and fission fragments (ff) from a sup 2 sup 5 sup 2 Cf source as heavy particles. In general the bulk etch rate was calculated using the weight difference method and the track etch rate was determined using the track geometry at various temperatures (50-90 deg. C) and concentrations (4-9 N) of the NaOH etchant. The average activation energy E sub b related to the bulk etch rate v sub b was calculated from 1n v sub b vs. 1/T. The average activation energy E sub t related to the track etch rate v sub t was estimated from 1n v sub t vs. 1/T. It...

  20. Resonance energy transfer: The unified theory via vector spherical harmonics

    Energy Technology Data Exchange (ETDEWEB)

    Grinter, Roger, E-mail: r.grinter@uea.ac.uk; Jones, Garth A., E-mail: garth.jones@uea.ac.uk [School of Chemistry, University of East Anglia, Norwich NR4 7TJ (United Kingdom)

    2016-08-21

    In this work, we derive the well-established expression for the quantum amplitude associated with the resonance energy transfer (RET) process between a pair of molecules that are beyond wavefunction overlap. The novelty of this work is that the field of the mediating photon is described in terms of a spherical wave rather than a plane wave. The angular components of the field are constructed in terms of vector spherical harmonics while Hankel functions are used to define the radial component. This approach alleviates the problem of having to select physically correct solution from non-physical solutions, which seems to be inherent in plane wave derivations. The spherical coordinate system allows one to easily decompose the photon’s fields into longitudinal and transverse components and offers a natural way to analyse near-, intermediate-, and far-zone RET within the context of the relative orientation of the transition dipole moments for the two molecules.

  1. Proxy studies of energy transfer to the magnetosphere

    International Nuclear Information System (INIS)

    Scurry, L.; Russell, C.T.

    1991-01-01

    The transfer of energy into the magnetosphere is studied using as proxy the Am geomagnetic index and multilinear regressions and correlations with solar wind data. In particular, the response of Am to the reconnection mechanism is examined in relation to the orientation of the interplanetary magnetic field as well as the upstream plasma parameters. A functional dependence of Am on clock angle, the orientation of the IMF in the plane perpendicular to the flow, is derived after first correcting the index for nonreconnection effects due to dynamic pressure and velocity. An examination of the effect of upstream magnetosonic Mach number shows the reconnection mechanism to become less efficient at high Mach numbers. The reconnection mechanism is shown to be slightly enhanced by higher dynamic pressures

  2. Unravelling radiative energy transfer in solid-state lighting

    Science.gov (United States)

    Melikov, Rustamzhon; Press, Daniel Aaron; Ganesh Kumar, Baskaran; Sadeghi, Sadra; Nizamoglu, Sedat

    2018-01-01

    Today, a wide variety of organic and inorganic luminescent materials (e.g., phosphors, quantum dots, etc.) are being used for lighting and new materials (e.g., graphene, perovskite, etc.) are currently under investigation. However, the understanding of radiative energy transfer is limited, even though it is critical to understand and improve the performance levels of solid-state lighting devices. In this study, we derived a matrix approach that includes absorption, reabsorption, inter-absorption and their iterative and combinatorial interactions for one and multiple types of fluorophores, which is simplified to an analytical matrix. This mathematical approach gives results that agree well with the measured spectral and efficiency characteristics of color-conversion light-emitting diodes. Moreover, it also provides a deep physical insight by uncovering the entire radiative interactions and their contribution to the output optical spectrum. The model is universal and applicable for all kinds of fluorophores.

  3. Control of particle precipitation by energy transfer from solar wind

    Science.gov (United States)

    Bremer, J.; Gernandt, H.

    1985-12-01

    The energy transfer function (epsilon), introduced by Perreault and Akasofu (1978), appears to be well suited for the description of the long-term control of the particle precipitation by interplanetary parameters. An investigation was conducted with the objective to test this control in more detail. This investigation included the calculation of hourly epsilon values on the basis of satellite-measured solar wind and IMF (interplanetary magnetic field) data. The results were compared with corresponding geomagnetic and ionospheric data. The ionospheric data had been obtained by three GDR (German Democratic Republic) teams during the 21st, 22nd, and 23rd Soviet Antarctic Expeditions in the time period from 1976 to 1979. It was found that, in high latitudes, the properties of the solar wind exercise a pronounced degree of control on the precipitation of energetic particles into the atmosphere, taking into account a time delay of about one hour due to the occurrence of magnetospheric storage processes.

  4. Basal Metabolic Rate and Energy Expenditure of Rural Farmers in ...

    African Journals Online (AJOL)

    Measurement of basal metabolic rate (BMR) provides an important baseline for the determination of an individual's total energy requirement. The study sought to establish human energy expenditure of rural farmers in Magubike village in Tanzania, through determination of BMR, physical activity level (PAL) and total energy ...

  5. Solar-pumped electronic-to-vibrational energy transfer lasers

    Science.gov (United States)

    Harries, W. L.; Wilson, J. W.

    1981-01-01

    The possibility of using solar-pumped lasers as solar energy converters is examined. The absorbing media considered are halogens or halogen compounds, which are dissociated to yield excited atoms, which then hand over energy to a molecular lasing medium. Estimates of the temperature effects for a Br2-CO2-He system with He as the cooling gas are given. High temperatures can cause the lower energy levels of the CO2 laser transition to be filled. The inverted populations are calculated and lasing should be possible. However, the efficiency is less than 0.001. Examination of other halogen-molecular lasant combinations (where the rate coefficients are known) indicate efficiencies in all cases of less than 0.005.

  6. Study on reasonable curtailment rate of large scale renewable energy

    Science.gov (United States)

    Li, Nan; Yuan, Bo; Zhang, Fuqiang

    2018-02-01

    Energy curtailment rate of renewable energy generation is an important indicator to measure renewable energy consumption, it is also an important parameters to determine the other power sources and grids arrangement in the planning stage. In general, to consume the spike power of the renewable energy which is just a small proportion, it is necessary to dispatch a large number of peaking resources, which will reduce the safety and stability of the system. In planning aspect, if it is allowed to give up a certain amount of renewable energy, overall peaking demand of the system will be reduced, the peak power supply construction can be put off to avoid the expensive cost of marginal absorption. In this paper, we introduce the reasonable energy curtailment rate into the power system planning, and use the GESP power planning software, conclude that the reasonable energy curtailment rate of the regional grids in China is 3% -10% in 2020.

  7. Wave energy: technology transfer and generic R and D recommendations

    Energy Technology Data Exchange (ETDEWEB)

    Scarr, D.; Kollek, R.; Collier, D.

    2001-07-01

    Arup have reviewed the status of the industry by way of individual interviews with all teams currently active in the UK as well as by research of international activities in the area. A preliminary technology workshop was organised to identify and discuss key issues with the teams and other industries. The following technology areas were discussed: (1) Regulatory Environment, HSE, Design Codes and Verification; (2) Construction Methods and Project Cost Estimation; (3) Marine Operations; (4) Mooring Systems; (5) Operations and Maintenance; (6) Materials; (7) Hydraulic Systems; (8) Pneumatic Systems; (9) Subsea Cables and Connectors; (10) Control Systems; (11) Power Quality and Grid Connection. The recommendations were made bearing in mind the proposed programme of Wave Energy Converter (WEC) prototype and power station development and the perceived need for further cost reductions. The major conclusions of the study were: The Wave Energy Industry is poorly co-ordinated. At present, all teams are working independently and commercial considerations force them to keep their ideas secret. There remains a lack of investor confidence and hence industrial support for the industry. Teams tend to be relatively small working out of University Departments or SMEs with some industrial backing. No major technological barriers to the development of Wave Energy Prototypes have been identified. All the issues raised under design, construction, deployment and operation can be addressed by transfer of technology from other industries, especially the offshore industry. However, costs, risks and approvals will need to be addressed. However, some technology gaps have been identified, notably in the areas of mooring and cable connections detailing, hydraulic machines and grid connection and energy storage. (author)

  8. Heat transfer in a counterflow heat exchanger at low flow rates

    International Nuclear Information System (INIS)

    Hashimoto, A.; Hattori, N.; Naruke, K.

    1995-01-01

    A study was made of heat transfer in a double-tube heat exchanger at low flow rates of water. The temperatures of fluid and tube walls in the axial direction of tube were measured precisely at flow rate ratios of annulus to inner tube (or flow rate ratios of inner tube to annulus W i /W a , Re i approx. = 80 - 4000), W a /W i =0.1 - 1.1. In parallel with experiment, numerical calculation for forced-convection heat transfer was also carried out for laminar flows in the same tube configuration as experiment. Average over-all coefficients of heat transfer, obtained by experiments, indicate the same characteristics as numerical calculation in the examined range of flow rate ratio. Their experimental values, however, are somewhat larger than those of calculation at small values of flow rate ratio. (author)

  9. Reaction rate and energy-loss rate for photopair production by relativistic nuclei

    Science.gov (United States)

    Chodorowski, Michal J.; Zdziarski, Andrzej A.; Sikora, Marek

    1992-01-01

    The process of e(+/-) pair production by relativistic nuclei on ambient photons is considered. The process is important for cosmic-ray nuclei in interstellar and intergalactic space as well as in galactic and extragalactic compact objects. The rate of this process is given by an integral of the cross section over the photon angular and energy distribution. In the case of isotropic photons, the angular integration is performed to provide an expression for the rate at given photon energy in the nucleus rest frame. The total rate then becomes a single integral of that rate over the photon energy distribution. Formulas are also given for the fractional energy loss of a relativistic nucleus colliding with a photon of a given energy in the rest frame. The nucleus energy-loss rate is integrated over the photon angular distribution in the case of isotropic photons, and simple fits are provided.

  10. Window Energy Rating System and Calculation of Energy Performance of Windows

    DEFF Research Database (Denmark)

    Laustsen, Jacob Birck; Svendsen, Svend

    The goal of reducing the energy consumption in buildings is the background for the introduction of an energy rating system of fenestration products in Denmark. The energy rating system requires that producers declare, among other things, the heat loss coefficient, U, and the total solar energy...... development, e.g. when the resulting effects of a reduced frame area are evaluated....

  11. Energy transfer in reactive and non-reactive H2 + OH collisions

    International Nuclear Information System (INIS)

    Rashed, O.; Brown, N.J.

    1985-04-01

    We have used the methods of quasi-classical dynamics to compute energy transfer properties of non-reactive and reactive H 2 + OH collisions. Energy transfer has been investigated as function of translational temperature, reagent rotational energy, and reagent vibrational energy. The energy transfer mechanism is complex with ten types of energy transfer possible, and evidence was found for all types. There is much more exchange between the translational degree of freedom and the H 2 vibrational degree of freedom than there is between translation and OH vibration. Translational energy is transferred to the rotational degrees of freedom of each molecule. There is a greater propensity for the transfer of translation to OH rotation than H 2 rotation. In reactive collisions, increases in reagent translational temperature predominantly appear as vibrational energy in the water molecule. Energy transfer in non-reactive and reactive collisions does not depend strongly on the initial angular momentum in either molecule. In non-reactive collisions, vibrational energy is transferred to translation, to the rotational degree of freedom of the same molecule, and to the rotational and vibrational degrees of freedom of the other molecule. In reactive collisions, the major effect of increasing the vibrational energy in reagent molecules is that, on the average, the vibrational energy of the reagents appears as product vibrational energy. 18 refs., 16 figs., 6 tabs

  12. Syntrophic growth with direct interspecies electron transfer as the primary mechanism for energy exchange

    DEFF Research Database (Denmark)

    Shrestha, Pravin Malla; Rotaru, Amelia-Elena; Aklujkar, Muktak

    2013-01-01

    Direct interspecies electron transfer (DIET) through biological electrical connections is an alternative to interspecies H2 transfer as a mechanism for electron exchange in syntrophic cultures. However, it has not previously been determined whether electrons received via DIET yield energy...... dehydrogenase, the pilus-associated c-type cytochrome OmcS and pili consistent with electron transfer via DIET. These results suggest that electrons transferred via DIET can serve as the sole energy source to support anaerobic respiration....

  13. Near-field thermal upconversion and energy transfer through a Kerr medium.

    Science.gov (United States)

    Khandekar, Chinmay; Rodriguez, Alejandro W

    2017-09-18

    We present an approach for achieving large Kerr χ (3) -mediated thermal energy transfer at the nanoscale that exploits a general coupled-mode description of triply resonant, four-wave mixing processes. We analyze the efficiency of thermal upconversion and energy transfer from mid- to near-infrared wavelengths in planar geometries involving two slabs supporting far-apart surface plasmon polaritons and separated by a nonlinear χ (3) medium that is irradiated by externally incident light. We study multiple geometric and material configurations and different classes of intervening mediums-either bulk or nanostructured lattices of nanoparticles embedded in nonlinear materials-designed to resonantly enhance the interaction of the incident light with thermal slab resonances. We find that even when the entire system is in thermodynamic equilibrium (at room temperature) and under typical drive intensities ~ W/μm 2 , the resulting upconversion rates can approach and even exceed thermal flux rates achieved in typical symmetric and non-equilibrium configurations of vacuum-separated slabs. The proposed nonlinear scheme could potentially be exploited to achieve thermal cooling and refrigeration at the nanoscale, and to actively control heat transfer between materials with dramatically different resonant responses.

  14. Energy transfers between N_2(A"3Σ) nitrogen metastable molecules and oxygen atoms and molecules

    International Nuclear Information System (INIS)

    De Souza, Antonio Rogerio

    1985-01-01

    This research thesis aims at determining reaction coefficients for energy transfers between nitrogen in its metastable status and oxygen atoms and molecules, the variation of these coefficients with respect to temperature (mainly in the 200-400 K range), products formed and more particularly branching rates of O("1S) oxygen and of NO_2. Reaction coefficients are experimentally determined by using the technique of post-discharge in flow. The experimental set-up is described and the study of the best operating conditions is reported. In the next part, the author reports the study of the energy transfer between nitrogen in its metastable status N_2(A) and oxygen molecules. Reaction coefficients are determined for the first three vibrational levels. The author then reports the study of the transfer of N_2(A) molecules on oxygen atoms in their fundamental status. Reactions coefficients and their variations are determined for the three first vibrational levels. The author describes the dissociation method and the method of detection of atomic oxygen. A kinetic model is proposed for the analysis of formed products during a post-discharge in flow, and the branching rate for the formation of O("1S) oxygen between 190 and 365 K is determined. The author finally discusses publications on the role of these reactions in the interpretation of some atmospheric phenomena

  15. Proton Linear Energy Transfer measurement using Emulsion Cloud Chamber

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Jae-ik [Proton Therapy Center, National Cancer Center (Korea, Republic of); Division of Heavy Ion Clinical Research, Korea Institute of Radiological & Medical Sciences (KIRAMS), Seoul (Korea, Republic of); Park, Seyjoon [Department of Radiation Oncology, Samsung Medical Center, Sungkyunkwan University, School of Medicine, Seoul (Korea, Republic of); Kim, Haksoo; Kim, Meyoung [Proton Therapy Center, National Cancer Center (Korea, Republic of); Jeong, Chiyoung [Department of Radiation Oncology, Asan Medical Center, University of Ulsan College of Medicine, Seoul (Korea, Republic of); Cho, Sungkoo [Department of Radiation Oncology, Samsung Medical Center, Sungkyunkwan University, School of Medicine, Seoul (Korea, Republic of); Lim, Young Kyung; Shin, Dongho [Proton Therapy Center, National Cancer Center (Korea, Republic of); Lee, Se Byeong, E-mail: sblee@ncc.re.kr [Proton Therapy Center, National Cancer Center (Korea, Republic of); Morishima, Kunihiro; Naganawa, Naotaka; Sato, Osamu [Department of Physics, Nagoya University, Nagoya (Japan); Kwak, Jungwon [Department of Radiation Oncology, Asan Medical Center, University of Ulsan College of Medicine, Seoul (Korea, Republic of); Kim, Sung Hyun [Center for Underground Physics, Institute for Basic Science (IBS), Daejeon (Korea, Republic of); Cho, Jung Sook [Department of refinement education, Dongseo University, Busan (Korea, Republic of); Ahn, Jung Keun [Department of Physics, Korea University, Seoul (Korea, Republic of); Kim, Ji Hyun; Yoon, Chun Sil [Gyeongsang National University, Jinju (Korea, Republic of); Incerti, Sebastien [CNRS, IN2P3, CENBG, UMR 5797, F-33170 Gradignan (France); Université Bordeaux 1, CENBG, UMR 5797, F-33170 Gradignan (France)

    2015-04-15

    This study proposes to determine the correlation between the Volume Pulse Height (VPH) measured by nuclear emulsion and Linear Energy Transfer (LET) calculated by Monte Carlo simulation based on Geant4. The nuclear emulsion was irradiated at the National Cancer Center (NCC) with a therapeutic proton beam and was installed at 5.2 m distance from the beam nozzle structure with various thicknesses of water-equivalent material (PMMA) blocks to position with specific positions along the Bragg curve. After the beam exposure and development of the emulsion films, the films were scanned by S-UTS developed in Nagoya University. The proton tracks in the scanned films were reconstructed using the ‘NETSCAN’ method. Through this procedure, the VPH can be derived from each reconstructed proton track at each position along the Bragg curve. The VPH value indicates the magnitude of energy loss in proton track. By comparison with the simulation results obtained using Geant4, we found the correlation between the LET calculated by Monte Carlo simulation and the VPH measured by the nuclear emulsion.

  16. Internal high linear energy transfer (LET) targeted radiotherapy for cancer

    International Nuclear Information System (INIS)

    Allen, Barry J

    2006-01-01

    High linear energy transfer (LET) radiation for internal targeted therapy has been a long time coming on to the medical therapy scene. While fundamental principles were established many decades ago, the clinical implementation has been slow. Localized neutron capture therapy, and more recently systemic targeted alpha therapy, are at the clinical trial stage. What are the attributes of these therapies that have led a band of scientists and clinicians to dedicate so much of their careers? High LET means high energy density, causing double strand breaks in DNA, and short-range radiation, sparing adjacent normal tissues. This targeted approach complements conventional radiotherapy and chemotherapy. Such therapies fail on several fronts. Foremost is the complete lack of progress for the control of primary GBM, the holy grail for cancer therapies. Next is the inability to regress metastatic cancer on a systemic basis. This has been the task of chemotherapy, but palliation is the major application. Finally, there is the inability to inhibit the development of lethal metastatic cancer after successful treatment of the primary cancer. This review charts, from an Australian perspective, the developing role of local and systemic high LET, internal radiation therapy. (review)

  17. Proton Linear Energy Transfer measurement using Emulsion Cloud Chamber

    International Nuclear Information System (INIS)

    Shin, Jae-ik; Park, Seyjoon; Kim, Haksoo; Kim, Meyoung; Jeong, Chiyoung; Cho, Sungkoo; Lim, Young Kyung; Shin, Dongho; Lee, Se Byeong; Morishima, Kunihiro; Naganawa, Naotaka; Sato, Osamu; Kwak, Jungwon; Kim, Sung Hyun; Cho, Jung Sook; Ahn, Jung Keun; Kim, Ji Hyun; Yoon, Chun Sil; Incerti, Sebastien

    2015-01-01

    This study proposes to determine the correlation between the Volume Pulse Height (VPH) measured by nuclear emulsion and Linear Energy Transfer (LET) calculated by Monte Carlo simulation based on Geant4. The nuclear emulsion was irradiated at the National Cancer Center (NCC) with a therapeutic proton beam and was installed at 5.2 m distance from the beam nozzle structure with various thicknesses of water-equivalent material (PMMA) blocks to position with specific positions along the Bragg curve. After the beam exposure and development of the emulsion films, the films were scanned by S-UTS developed in Nagoya University. The proton tracks in the scanned films were reconstructed using the ‘NETSCAN’ method. Through this procedure, the VPH can be derived from each reconstructed proton track at each position along the Bragg curve. The VPH value indicates the magnitude of energy loss in proton track. By comparison with the simulation results obtained using Geant4, we found the correlation between the LET calculated by Monte Carlo simulation and the VPH measured by the nuclear emulsion

  18. Proton Linear Energy Transfer measurement using Emulsion Cloud Chamber

    Science.gov (United States)

    Shin, Jae-ik; Park, Seyjoon; Kim, Haksoo; Kim, Meyoung; Jeong, Chiyoung; Cho, Sungkoo; Lim, Young Kyung; Shin, Dongho; Lee, Se Byeong; Morishima, Kunihiro; Naganawa, Naotaka; Sato, Osamu; Kwak, Jungwon; Kim, Sung Hyun; Cho, Jung Sook; Ahn, Jung Keun; Kim, Ji Hyun; Yoon, Chun Sil; Incerti, Sebastien

    2015-04-01

    This study proposes to determine the correlation between the Volume Pulse Height (VPH) measured by nuclear emulsion and Linear Energy Transfer (LET) calculated by Monte Carlo simulation based on Geant4. The nuclear emulsion was irradiated at the National Cancer Center (NCC) with a therapeutic proton beam and was installed at 5.2 m distance from the beam nozzle structure with various thicknesses of water-equivalent material (PMMA) blocks to position with specific positions along the Bragg curve. After the beam exposure and development of the emulsion films, the films were scanned by S-UTS developed in Nagoya University. The proton tracks in the scanned films were reconstructed using the 'NETSCAN' method. Through this procedure, the VPH can be derived from each reconstructed proton track at each position along the Bragg curve. The VPH value indicates the magnitude of energy loss in proton track. By comparison with the simulation results obtained using Geant4, we found the correlation between the LET calculated by Monte Carlo simulation and the VPH measured by the nuclear emulsion.

  19. Energy transfer in structured and unstructured environments: Master equations beyond the Born-Markov approximations

    Energy Technology Data Exchange (ETDEWEB)

    Iles-Smith, Jake, E-mail: Jakeilessmith@gmail.com [Controlled Quantum Dynamics Theory, Imperial College London, London SW7 2PG (United Kingdom); Photon Science Institute and School of Physics and Astronomy, The University of Manchester, Oxford Road, Manchester M13 9PL (United Kingdom); Department of Photonics Engineering, DTU Fotonik, Ørsteds Plads, 2800 Kongens Lyngby (Denmark); Dijkstra, Arend G. [Max Planck Institute for the Structure and Dynamics of Matter, Luruper Chaussee 149, 22761 Hamburg (Germany); Lambert, Neill [CEMS, RIKEN, Saitama 351-0198 (Japan); Nazir, Ahsan, E-mail: ahsan.nazir@manchester.ac.uk [Photon Science Institute and School of Physics and Astronomy, The University of Manchester, Oxford Road, Manchester M13 9PL (United Kingdom)

    2016-01-28

    We explore excitonic energy transfer dynamics in a molecular dimer system coupled to both structured and unstructured oscillator environments. By extending the reaction coordinate master equation technique developed by Iles-Smith et al. [Phys. Rev. A 90, 032114 (2014)], we go beyond the commonly used Born-Markov approximations to incorporate system-environment correlations and the resultant non-Markovian dynamical effects. We obtain energy transfer dynamics for both underdamped and overdamped oscillator environments that are in perfect agreement with the numerical hierarchical equations of motion over a wide range of parameters. Furthermore, we show that the Zusman equations, which may be obtained in a semiclassical limit of the reaction coordinate model, are often incapable of describing the correct dynamical behaviour. This demonstrates the necessity of properly accounting for quantum correlations generated between the system and its environment when the Born-Markov approximations no longer hold. Finally, we apply the reaction coordinate formalism to the case of a structured environment comprising of both underdamped (i.e., sharply peaked) and overdamped (broad) components simultaneously. We find that though an enhancement of the dimer energy transfer rate can be obtained when compared to an unstructured environment, its magnitude is rather sensitive to both the dimer-peak resonance conditions and the relative strengths of the underdamped and overdamped contributions.

  20. Phosphorus-31 NMR magnetization transfer measurements of metabolic reaction rates in the rat heart and kidney in vivo

    International Nuclear Information System (INIS)

    Koretsky, A.P.

    1984-01-01

    31 P NMR is a unique tool to study bioenergetics in living cells. The application of magnetization transfer techniques to the measurement of steady-state enzyme reaction rates provides a new approach to understanding the regulation of high energy phosphate metabolism. This dissertation is concerned with the measurement of the rates of ATP synthesis in the rat kidney and of the creatine kinase catalyzed reaction in the rat heart in situ. The theoretical considerations of applying magnetization transfer techniques to intact organs are discussed with emphasis on the problems associated with multiple exchange reactions and compartmentation of reactants. Experimental measurements of the ATP synthesis rate were compared to whole kidney oxygen consumption and Na + reabsorption rates to derive ATP/O values. The problems associated with ATP synthesis rate measurements in kidney, e.g. the heterogeneity of the inorganic phosphate resonance, are discussed and experiments to overcome these problems proposed. In heart, the forward rate through creatine kinase was measured to be larger than the reverse rate. To account for the difference in forward and reverse rates a model is proposed based on the compartmentation of a small pool of ATP

  1. Estimating Survival Rates in Engineering for Community College Transfer Students Using Grades in Calculus and Physics

    Science.gov (United States)

    Laugerman, Marcia; Shelley, Mack; Rover, Diane; Mickelson, Steve

    2015-01-01

    This study uses a unique synthesized set of data for community college students transferring to engineering by combining several cohorts of longitudinal data along with transcript-level data, from both the Community College and the University, to measure success rates in engineering. The success rates are calculated by developing Kaplan-Meier…

  2. Role of methylene spacer in the excitation energy transfer in europium 1- and 2- naphthylcarboxylates

    Energy Technology Data Exchange (ETDEWEB)

    Zhuravlev, K. [V.A. Kotelnikov Institute of Radioengineering and Electronics of RAS, 1 Vvedenskii sq., Fryazino Moscow reg. 141190 (Russian Federation); Tsaryuk, V., E-mail: vit225@ire216.msk.s [V.A. Kotelnikov Institute of Radioengineering and Electronics of RAS, 1 Vvedenskii sq., Fryazino Moscow reg. 141190 (Russian Federation); Kudryashova, V.; Pekareva, I. [V.A. Kotelnikov Institute of Radioengineering and Electronics of RAS, 1 Vvedenskii sq., Fryazino Moscow reg. 141190 (Russian Federation); Sokolnicki, J. [Faculty of Chemistry, University of WrocLaw, 14 F. Joliot-Curie str., WrocLaw 50-383 (Poland); Yakovlev, Yu. [V.A. Kotelnikov Institute of Radioengineering and Electronics of RAS, 1 Vvedenskii sq., Fryazino Moscow reg. 141190 (Russian Federation)

    2010-08-15

    A series of compounds Ln(RCOO){sub 3}.Phen (Ln=Eu, Gd, Tb; RCOO{sup -}-1- and 2-naphthoate, 1- and 2-naphthylacetate, 1- and 2-naphthoxyacetate anions, Phen-1,10-phenanthroline) was investigated by methods of optical spectroscopy. Compounds of composition Ln(RCOO){sub 3}.nH{sub 2}O with the same carboxylate ligands are also considered. Results of studies of the effects of methylene spacer decoupling the {pi}-{pi}- or p-{pi}-conjugation in the naphthylcarboxylate ligand on the structure of Eu{sup 3+} coordination centre, on the lifetime of {sup 5}D{sub 0} (Eu{sup 3+}) state, and on processes of the excitation energy transfer to Eu{sup 3+} or Tb{sup 3+} ions are presented. Introduction of the methylene bridge in the ligand weakens the influence of the steric hindrances in forming of a crystal lattice and results in lowering the distortion of the Eu{sup 3+} luminescence centre, and in elongation of the observed {sup 5}D{sub 0} lifetime {tau}{sub obs}. The latter is caused by decrease in contribution of the radiative processes rate 1/{tau}{sub r}. This is confirmed by the correlation between the lifetimes {tau}{sub obs} and the quantities '{tau}{sub r}.const' inversely proportional to the total integral intensities of Eu(RCOO){sub 3}.Phen luminescence spectra. The methylene spacer performs a role of regulator of sensitization of the Ln{sup 3+} luminescence efficiency by means of an influence on mutual location of lowest triplet states of the ligands, the ligand-metal charge transfer (LMCT) states, and the emitting states of Ln{sup 3+} ions. The lowest triplet state in lanthanide naphthylcarboxylate adducts with Phen is related to carboxylate anion. A presence of the methylene spacer in naphthylcarboxylate ligand increases the triplet state energy. At the same time, the energy of 'carboxylic group-Eu{sup 3+} ion' charge transfer states falls, which can promote the degradation of excitation energy. In naphthylcarboxylates investigated a range of the

  3. Excitation and charge transfer in low-energy hydrogen atom collisions with neutral iron

    Science.gov (United States)

    Barklem, P. S.

    2018-05-01

    Data for inelastic processes due to hydrogen atom collisions with iron are needed for accurate modelling of the iron spectrum in late-type stars. Excitation and charge transfer in low-energy Fe+H collisions is studied theoretically using a previously presented method based on an asymptotic two-electron linear combination of atomic orbitals model of ionic-covalent interactions in the neutral atom-hydrogen-atom system, together with the multi-channel Landau-Zener model. An extensive calculation including 166 covalent states and 25 ionic states is presented and rate coefficients are calculated for temperatures in the range 1000-20 000 K. The largest rates are found for charge transfer processes to and from two clusters of states around 6.3 and 6.6 eV excitation, corresponding in both cases to active 4d and 5p electrons undergoing transfer. Excitation and de-excitation processes among these two sets of states are also significant. Full Tables and rate coefficient data are only available at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/612/A90

  4. Spatially Mapping Energy Transfer from Single Plasmonic Particles to Semiconductor Substrates via STEM/EELS.

    Science.gov (United States)

    Li, Guoliang; Cherqui, Charles; Bigelow, Nicholas W; Duscher, Gerd; Straney, Patrick J; Millstone, Jill E; Masiello, David J; Camden, Jon P

    2015-05-13

    Energy transfer from plasmonic nanoparticles to semiconductors can expand the available spectrum of solar energy-harvesting devices. Here, we spatially and spectrally resolve the interaction between single Ag nanocubes with insulating and semiconducting substrates using electron energy-loss spectroscopy, electrodynamics simulations, and extended plasmon hybridization theory. Our results illustrate a new way to characterize plasmon-semiconductor energy transfer at the nanoscale and bear impact upon the design of next-generation solar energy-harvesting devices.

  5. Simple analytical approximation for rotationally inelastic rate constants based on the energy corrected sudden scaling law

    International Nuclear Information System (INIS)

    Smith, N.; Pritchard, D.E.

    1981-01-01

    We have recently demonstrated that the energy corrected sudden (ECS) scaling law of De Pristo et al. when conbined with the power law assumption for the basis rates k/sub l/→0proportional[l(l+1)]/sup -g/ can accurately fit a wide body of rotational energy transfer data. We develop a simple and accurate approximation to this fitting law, and in addition mathematically show the connection between it and our earlier proposed energy based law which also has been successful in describing both theoretical and experimental data on rotationally inelastic collisions

  6. Effect of phase change material on the heat transfer rate of different building materials

    Science.gov (United States)

    Hasan, Mushfiq; Alam, Shahnur; Ahmed, Dewan Hasan

    2017-12-01

    Phase change material (PCM) is widely known as latent heat storage. A comprehensive study is carried out to investigate the effect of PCM on heat transfer rate of building materials. Paraffin is used as PCM along with different conventional building materials to investigate the heat transfer rate from the heated region to the cold region. PCM is placed along with the three different types of building materials like plaster which is well know building material in urban areas and wood and straw which are commonly used in rural areas for roofing as well as wall panel material and investigated the heat transfer rate. An experimental setup was constructed with number of rectangular shape aluminum detachable casing (as cavity) and placed side by side. Series of rectangular cavity filled with convent ional building materials and PCM and these were placed in between two chambers filled with water at different temperature. Building materials and PCM were placed in different cavities with different combinations and investigated the heat transfer rate. The results show that using the PCM along with other building materials can be used to maintain lower temperature at the inner wall and chamber of the cold region. Moreover, the placement or orientation of the building materials and PCM make significant contribution to heat transfer rate from the heated zone to the cold zone.

  7. Vibrational relaxation and energy transfer of matrix isolated HCl and DCl

    Energy Technology Data Exchange (ETDEWEB)

    Wiesenfeld, J.M.

    1977-12-01

    Vibrational kinetic and spectroscopic studies have been performed on matrix-isolated HCl and DCl between 9 and 20 K. Vibrational relaxation rates for v = 2 and v = 1 were measured by a tunable infrared laser-induced, time-resolved fluorescence technique. In an Ar matrix, vibrational decay times are faster than radiative and it is found that HCl relaxes about 35 times more rapidly than CCl, in spite of the fact that HCl must transfer more energy to the lattice than DCl. This result is explained by postulating that the rate-determining step for vibrational relaxation produces a highly rotationally excited guest in a V yield R step; rotational relaxation into lattice phonons follows rapidly. HCl v = 1, but not v = 2, excitation rapidly diffuses through the sample by a resonant dipole-dipole vibrational energy transfer process. Molecular complexes, and in particular the HCl dimer, relax too rapidly for direct observation, less than or approximately 1 ..mu..s, and act as energy sinks in the energy diffusion process. The temperature dependence for all these processes is weak--less than a factor of two between 9 and 20 K. Vibrational relaxation of HCl in N/sub 2/ and O/sub 2/ matrices is unobservable, presumably due to rapid V yield V transfer to the host. A V yield R binary collision model for relaxation in solids is successful in explaining the HCl(DCl)/Ar results as well as results of other experimenters. The model considers relaxation to be the result of ''collisions'' due to molecular motion in quantized lattice normal modes--gas phase potential parameters can fit the matrix kinetic data.

  8. Vibrational relaxation and energy transfer of matrix isolated HCl and DCl

    International Nuclear Information System (INIS)

    Wiesenfeld, J.M.

    1977-12-01

    Vibrational kinetic and spectroscopic studies have been performed on matrix-isolated HCl and DCl between 9 and 20 K. Vibrational relaxation rates for v = 2 and v = 1 were measured by a tunable infrared laser-induced, time-resolved fluorescence technique. In an Ar matrix, vibrational decay times are faster than radiative and it is found that HCl relaxes about 35 times more rapidly than CCl, in spite of the fact that HCl must transfer more energy to the lattice than DCl. This result is explained by postulating that the rate-determining step for vibrational relaxation produces a highly rotationally excited guest in a V yield R step; rotational relaxation into lattice phonons follows rapidly. HCl v = 1, but not v = 2, excitation rapidly diffuses through the sample by a resonant dipole-dipole vibrational energy transfer process. Molecular complexes, and in particular the HCl dimer, relax too rapidly for direct observation, less than or approximately 1 μs, and act as energy sinks in the energy diffusion process. The temperature dependence for all these processes is weak--less than a factor of two between 9 and 20 K. Vibrational relaxation of HCl in N 2 and O 2 matrices is unobservable, presumably due to rapid V yield V transfer to the host. A V yield R binary collision model for relaxation in solids is successful in explaining the HCl(DCl)/Ar results as well as results of other experimenters. The model considers relaxation to be the result of ''collisions'' due to molecular motion in quantized lattice normal modes--gas phase potential parameters can fit the matrix kinetic data

  9. Local Measurement of Fuel Energy Deposition and Heat Transfer Environment During Fuel Lifetime Using Controlled Calorimetry

    International Nuclear Information System (INIS)

    Don W. Miller; Andrew Kauffmann; Eric Kreidler; Dongxu Li; Hanying Liu; Daniel Mills; Thomas D. Radcliff; Joseph Talnagi

    2001-01-01

    A comprehensive description of the accomplishments of the DOE grant titled, ''Local Measurement of Fuel Energy Deposition and Heat Transfer Environment During Fuel Lifetime using Controlled Calorimetry''

  10. Two-Dimensional Free Energy Surfaces for Electron Transfer Reactions in Solution

    Directory of Open Access Journals (Sweden)

    Shigeo Murata

    2008-01-01

    Full Text Available Change in intermolecular distance between electron donor (D and acceptor (A can induce intermolecular electron transfer (ET even in nonpolar solvent, where solvent orientational polarization is absent. This was shown by making simple calculations of the energies of the initial and final states of ET. In the case of polar solvent, the free energies are functions of both D-A distance and solvent orientational polarization. On the basis of 2-dimensional free energy surfaces, the relation of Marcus ET and exciplex formation is discussed. The transient effect in fluorescence quenching was measured for several D-A pairs in a nonpolar solvent. The results were analyzed by assuming a distance dependence of the ET rate that is consistent with the above model.

  11. A unified picture of energy and electron transfer in primary photosynthesis

    International Nuclear Information System (INIS)

    Barter, Laura M.C.; Klug, David R.

    2005-01-01

    A quantitative structure-function relationship for an enzyme should relate the coordinates of atoms in a protein structure to the rates, equilibria and activation energies of the catalysed reaction. In effect, the calculational tools used for determining a structure-function relationship in an enzyme are linking two sets of experimental data, one data set being the coordinates of the enzymes constituent atoms and the other being measurements of its chemical activity. The ability to compare structure and function in this quantitative manner is an important stage in the ultimate development of engineering design rules for biological catalysts. This paper discusses the determination of parameters, in particular the state energies and the free energy surfaces that control the structure-function relationship, and thus the catalytic function of a photosynthetic enzyme. We discuss two different microscopic descriptions, one using conventional non-adiabatic electron transfer theory and the other a supermolecular description of the system (the Multimer Model), which takes into account the electron-phonon coupling in the system in a consistent manner. We demonstrate that although conventional non-adiabatic theory can be employed to reproduce the rates of electron transfer it cannot be employed to provide a consistent and unified description of all the spectroscopic data available in the literature from studies of this enzyme

  12. A unified picture of energy and electron transfer in primary photosynthesis

    Energy Technology Data Exchange (ETDEWEB)

    Barter, Laura M.C. [Molecular Dynamics Group, Room 266, Department of Chemistry, South Kensington Campus, Exhibition Road, Imperial College London, SW7 2AZ (United Kingdom)], E-mail: l.barter@ic.ac.uk; Klug, David R. [Molecular Dynamics Group, Room 266, Department of Chemistry, South Kensington Campus, Exhibition Road, Imperial College London, SW7 2AZ (United Kingdom)

    2005-12-07

    A quantitative structure-function relationship for an enzyme should relate the coordinates of atoms in a protein structure to the rates, equilibria and activation energies of the catalysed reaction. In effect, the calculational tools used for determining a structure-function relationship in an enzyme are linking two sets of experimental data, one data set being the coordinates of the enzymes constituent atoms and the other being measurements of its chemical activity. The ability to compare structure and function in this quantitative manner is an important stage in the ultimate development of engineering design rules for biological catalysts. This paper discusses the determination of parameters, in particular the state energies and the free energy surfaces that control the structure-function relationship, and thus the catalytic function of a photosynthetic enzyme. We discuss two different microscopic descriptions, one using conventional non-adiabatic electron transfer theory and the other a supermolecular description of the system (the Multimer Model), which takes into account the electron-phonon coupling in the system in a consistent manner. We demonstrate that although conventional non-adiabatic theory can be employed to reproduce the rates of electron transfer it cannot be employed to provide a consistent and unified description of all the spectroscopic data available in the literature from studies of this enzyme.

  13. Interaction mechanism for energy transfer from Ce to Tb ions in silica

    International Nuclear Information System (INIS)

    Seed Ahmed, H.A.A.; Chae, W.S.; Ntwaeaborwa, O.M.; Kroon, R.E.

    2016-01-01

    Energy transfer phenomena can play an important role in the development of luminescent materials. In this study, numerical simulations based on theoretical models of non-radiative energy transfer are compared to experimental results for Ce, Tb co-doped silica. Energy transfer from the donor (Ce) to the acceptor (Tb) resulted in a decrease in the Ce luminescence intensity and lifetime. The decrease in intensity corresponded best with the energy transfer models based on the exchange interaction and the dipole-dipole interaction. The critical transfer distance obtained from the fitting using both these models is around 2 nm. Since the exchange interaction requires a distance shorter than 1 nm to occur, the mechanism most likely to account for the energy transfer is concluded to be the dipole–dipole interaction. This is supported by an analysis of the lifetime data.

  14. Controlling energy transfer between multiple dopants within a single nanoparticle

    Science.gov (United States)

    DiMaio, Jeffrey R.; Sabatier, Clément; Kokuoz, Baris; Ballato, John

    2008-01-01

    Complex core-shell architectures are implemented within LaF3 nanoparticles to allow for a tailored degree of energy transfer (ET) between different rare earth dopants. By constraining specific dopants to individual shells, their relative distance to one another can be carefully controlled. Core-shell LaF3 nanoparticles doped with Tb3+ and Eu3+ and consisting of up to four layers were synthesized with an outer diameter of ≈10 nm. It is found that by varying the thicknesses of an undoped layer between a Tb3+-doped layer and a Eu3+-doped layer, the degree of ET can be engineered to allow for zero, partial, or total ET from a donor ion to an acceptor ion. More specifically, the ratio of the intensities of the 541-nm Tb3+ and 590 nm Eu3+ peaks was tailored from core-shell configuration that restricts ET is used. Beyond simply controlling ET, which can be limiting when designing materials for optical applications, this approach can be used to obtain truly engineered spectral features from nanoparticles and composites made from them. Further, it allows for a single excitation source to yield multiple discrete emissions from numerous lanthanide dopants that heretofore would have been quenched in a more conventional active optical material. PMID:18250307

  15. Heavy ion mutagenesis: linear energy transfer effects and genetic linkage

    Science.gov (United States)

    Kronenberg, A.; Gauny, S.; Criddle, K.; Vannais, D.; Ueno, A.; Kraemer, S.; Waldren, C. A.; Chatterjee, A. (Principal Investigator)

    1995-01-01

    We have characterized a series of 69 independent mutants at the endogenous hprt locus of human TK6 lymphoblasts and over 200 independent S1-deficient mutants of the human x hamster hybrid cell line AL arising spontaneously or following low-fluence exposures to densely ionizing Fe ions (600 MeV/amu, linear energy transfer = 190 keV/microns). We find that large deletions are common. The entire hprt gene (> 44 kb) was missing in 19/39 Fe-induced mutants, while only 2/30 spontaneous mutants lost the entire hprt coding sequence. When the gene of interest (S1 locus = M1C1 gene) is located on a nonessential human chromosome 11, multilocus deletions of several million base pairs are observed frequently. The S1 mutation frequency is more than 50-fold greater than the frequency of hprt mutants in the same cells. Taken together, these results suggest that low-fluence exposures to Fe ions are often cytotoxic due to their ability to create multilocus deletions that may often include the loss of essential genes. In addition, the tumorigenic potential of these HZE heavy ions may be due to the high potential for loss of tumor suppressor genes. The relative insensitivity of the hprt locus to mutation is likely due to tight linkage to a gene that is required for viability.

  16. Study of primary energy transfer process in ultrafast plastic scintillators

    International Nuclear Information System (INIS)

    Bengtson, B.; Moszynski, M.

    1978-01-01

    The study of the light-pulse shape, the initial delay of light pulses and the light yield of plastics prepared by a modification of the NE111 scintillator were performed. The NE111 scintillator doped with several quench agents, the plastics prepared as a solution of butyl PBD in PVT of different concentration and PVT alone were studied. The study confirmed that the light pulse shape from fast binary plastics is well described analytically by the convolution of the clipped Gaussian and exponential functions. The investigation of the PVT-butyl PBD plastics shows that even more than three times larger concentration of butyl PBD compared to that of PBD in the NE111 solution does not improve the rise of the light pulse. Thus the rise time seems to be not controlled by the intermolecular energy transfer process. Finally, the observed rise time of the light pulse from the PVT sample was also approximated well by the Gaussian function. Altogether it brought a strong support for the earlier hypothesis that the initial slow rise of light pulses from plastic scintillators may come from the deexcitation of several higher levels of the solvent molecules excited by nuclear particles. (Auth.)

  17. Low-energy charge transfer excitations in NiO

    International Nuclear Information System (INIS)

    Sokolov, V I; Yermakov, A Ye; Uimin, M A; Gruzdev, N B; Pustovarov, V A; Churmanov, V N; Ivanov, V Yu; Sokolov, P S; Baranov, A N; Moskvin, A S

    2012-01-01

    Comparative analysis of photoluminescence (PL) and photoluminescence excitation (PLE) spectra of NiO poly- and nanocrystals in the spectral range 2-5.5 eV reveals two PLE bands peaked near 3.7 and 4.6 eV with a dramatic rise in the low-temperature PLE spectral weight of the 3.7 eV PLE band in the nanocrystalline NiO as compared with its polycrystalline counterpart. In frames of a cluster model approach we assign the 3.7 eV PLE band to the low-energy bulk-forbidden p-d (t 1g (π)-e g ) charge transfer (CT) transition which becomes the allowed one in the nanocrystalline state while the 4.6 eV PLE band is related to a bulk allowed d-d (e g -e g ) CT transition scarcely susceptible to the nanocrystallization. The PLE spectroscopy of the nanocrystalline materials appears to be a novel informative technique for inspection of different CT transitions.

  18. Oxygen transfer rate estimation in oxidation ditches from clean water measurements.

    Science.gov (United States)

    Abusam, A; Keesman, K J; Meinema, K; Van Straten, G

    2001-06-01

    Standard methods for the determination of oxygen transfer rate are based on assumptions that are not valid for oxidation ditches. This paper presents a realistic and simple new method to be used in the estimation of oxygen transfer rate in oxidation ditches from clean water measurements. The new method uses a loop-of-CSTRs model, which can be easily incorporated within control algorithms, for modelling oxidation ditches. Further, this method assumes zero oxygen transfer rates (KLa) in the unaerated CSTRs. Application of a formal estimation procedure to real data revealed that the aeration constant (k = KLaVA, where VA is the volume of the aerated CSTR) can be determined significantly more accurately than KLa and VA. Therefore, the new method estimates k instead of KLa. From application to real data, this method proved to be more accurate than the commonly used Dutch standard method (STORA, 1980).

  19. Increasing vaginal progesterone gel supplementation after frozen-thawed embryo transfer significantly increases the delivery rate

    DEFF Research Database (Denmark)

    Alsbjerg, Birgit; Polyzos, Nikolaos P; Elbaek, Helle Olesen

    2013-01-01

    The aim of this study was to evaluate the reproductive outcome in patients receiving frozen-thawed embryo transfer before and after doubling of the vaginal progesterone gel supplementation. The study was a retrospective study performed in The Fertility Clinic, Skive Regional Hospital, Denmark....... A total of 346 infertility patients with oligoamenorrhoea undergoing frozen-thawed embryo transfer after priming with oestradiol and vaginal progesterone gel were included. The vaginal progesterone dose was changed from 90mg (Crinone) once a day to twice a day and the reproductive outcome during the two...... rate (8.7% versus 20.5%, respectively; P=0.002). Doubling of the vaginal progesterone gel supplementation during frozen-thawed embryo transfer cycles decreased the early pregnancy loss rate, resulting in a significantly higher delivery rate. This study evaluated the reproductive outcome of 346 women...

  20. The log mean heat transfer rate method of heat exchanger considering the influence of heat radiation

    International Nuclear Information System (INIS)

    Wong, K.-L.; Ke, M.-T.; Ku, S.-S.

    2009-01-01

    The log mean temperature difference (LMTD) method is conventionally used to calculate the total heat transfer rate of heat exchangers. Because the heat radiation equation contains the 4th order exponential of temperature which is very complicate in calculations, thus LMTD method neglects the influence of heat radiation. From the recent investigation of a circular duct in some practical situations, it is found that even in the situation of the temperature difference between outer duct surface and surrounding is low to 1 deg. C, the heat radiation effect can not be ignored in the situations of lower ambient convective heat coefficient and greater surface emissivities. In this investigation, the log mean heat transfer rate (LMHTR) method which considering the influence of heat radiation, is developed to calculate the total heat transfer rate of heat exchangers.

  1. Radiative transport and collisional transfer of excitation energy in Cs vapors mixed with Ar or He

    International Nuclear Information System (INIS)

    Vadla, Cedomil; Horvatic, Vlasta; Niemax, Kay

    2003-01-01

    This paper is a review (with a few original additions) on the radiative transport and collisional transfer of energy in laser-excited cesium vapors in the presence of argon or helium. Narrow-band excitation of lines with Lorentz, Doppler and Voigt profiles is studied in order to calculate effective rates for pumping of spectral lines with profiles comprising inhomogeneous broadening components. The radiative transport of excitation energy is considered, and a new, simple and robust, but accurate theoretical method for quantitative treatment of radiation trapping in relatively optically thin media is presented. Furthermore, comprehensive lists of experimental values for the excitation energy transfer cross-sections related to thermal collisions in Cs-Ar and Cs-He mixtures are given. Within the collected cross-section data sets, specific regularities with respect to the energy defect, as well as the temperature, are discerned. A particular emphasis is put on the radiative and collisional processes important for the optimization of resonance-fluorescence imaging atomic filters based on Cs-noble gas systems

  2. Experimental Analysis of File Transfer Rates over Wide-Area Dedicated Connections

    Energy Technology Data Exchange (ETDEWEB)

    Rao, Nageswara S. [ORNL; Liu, Qiang [ORNL; Sen, Satyabrata [ORNL; Hinkel, Gregory Carl [ORNL; Imam, Neena [ORNL; Foster, Ian [University of Chicago; Kettimuthu, R. [Argonne National Laboratory (ANL); Settlemyer, Bradley [Los Alamos National Laboratory (LANL); Wu, Qishi [University of Memphis; Yun, Daqing [Harrisburg University

    2016-12-01

    File transfers over dedicated connections, supported by large parallel file systems, have become increasingly important in high-performance computing and big data workflows. It remains a challenge to achieve peak rates for such transfers due to the complexities of file I/O, host, and network transport subsystems, and equally importantly, their interactions. We present extensive measurements of disk-to-disk file transfers using Lustre and XFS file systems mounted on multi-core servers over a suite of 10 Gbps emulated connections with 0-366 ms round trip times. Our results indicate that large buffer sizes and many parallel flows do not always guarantee high transfer rates. Furthermore, large variations in the measured rates necessitate repeated measurements to ensure confidence in inferences based on them. We propose a new method to efficiently identify the optimal joint file I/O and network transport parameters using a small number of measurements. We show that for XFS and Lustre with direct I/O, this method identifies configurations achieving 97% of the peak transfer rate while probing only 12% of the parameter space.

  3. Boosting biomethane yield and production rate with graphene: The potential of direct interspecies electron transfer in anaerobic digestion.

    Science.gov (United States)

    Lin, Richen; Cheng, Jun; Zhang, Jiabei; Zhou, Junhu; Cen, Kefa; Murphy, Jerry D

    2017-09-01

    Interspecies electron transfer between bacteria and archaea plays a vital role in enhancing energy efficiency of anaerobic digestion (AD). Conductive carbon materials (i.e. graphene nanomaterial and activated charcoal) were assessed to enhance AD of ethanol (a key intermediate product after acidogenesis of algae). The addition of graphene (1.0g/L) resulted in the highest biomethane yield (695.0±9.1mL/g) and production rate (95.7±7.6mL/g/d), corresponding to an enhancement of 25.0% in biomethane yield and 19.5% in production rate. The ethanol degradation constant was accordingly improved by 29.1% in the presence of graphene. Microbial analyses revealed that electrogenic bacteria of Geobacter and Pseudomonas along with archaea Methanobacterium and Methanospirillum might participate in direct interspecies electron transfer (DIET). Theoretical calculations provided evidence that graphene-based DIET can sustained a much higher electron transfer flux than conventional hydrogen transfer. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Comparison of pregnancy rate between fresh embryo transfers and frozen-thawed embryo transfers following ICSI treatment

    Directory of Open Access Journals (Sweden)

    Zahra Basirat

    2016-01-01

    Full Text Available Background: The use of assisted reproductive technology (ART is increasing in the world. The rate, efficacy and safety of ART are very different among countries. There is an increase in the use of intra cytoplasmic sperm injection (ICSI, single fresh embryo transfer (ET and frozen-thawed embryo transfer (FET. Objective: The objective of this study was to compare pregnancy rate in fresh ET and FET. Materials and Methods: In this retrospective cross-sectional study 1014 ICSI-ET cycles (426 fresh ET and 588 FET from 753 women undergoing ICSI treatment referred to Fatemezahra Infertility and Reproductive Health Research Center in Babol, Iran from 2008 to 2013 were reviewed. Results: There were no significant differences between biochemical pregnancy rate (23% versus 18.8%, OR 1.301; 95% CI .95-1.774, gestational sac (95.6% versus 100% in FET, OR 0.60; 95% CI 0.54-0.67, and fetal heart activity (87.2% versus 93.6% OR .46; 95% CI .16-1.32 in fresh ET and FET cycles, respectively. P< 0.05 was considered statistically significant for all measures. Conclusion: Although, the result showed no significantly difference between the fresh ET and the FET cycles, however the embryos are able to be stored for subsequent ART. Therefore, we recommend FET cycles as an option alongside the fresh ET.

  5. Charge Transfer Processes in Collisions of Si4+ Ions with He Atoms at Intermediate Energies

    Science.gov (United States)

    Suzuki, R.; Watanabe, A.; Sato, H.; Gu, J. P.; Hirsch, G.; Buenker, R. J.; Kimura, M.; Stancil, P. C.

    Charge transfer in collisions of Si4+ ions with He atoms below 100 keV/u is studied by using a molecular orbital representation within both the semiclassical and quantal representations. Single transfer reaction Si4++He →Si3++He+ has been studied by a number of theoretical investigations. In addition to the reaction (1), the first semiclassical MOCC calculations are performed for the double transfer channel Si4++HE→Si2++He2+ Nine molecular states that connect both with single and double electron transfer processes are considered in the present model. Electronic states and corresponding couplings are determined by the multireference single- and double- excitation configuration interaction method. The present cross sections tie well with the earlier calculations of Stancil et al., Phys. Rev. A 55, 1064 (1997) at lower energies, but show a rather different magnitude from those of Bacchus-Montabonel and Ceyzeriat, Phys. Rev. A 58, 1162 (1998). The present rate constant is found to be significantly different from the experimental finding of Fang and Kwong, Phys. Rev. A 59, 342 (1996) at 4,600 K, and hence does not support the experiment.

  6. Enhanced non-radiative energy transfer in hybrid III-nitride structures

    International Nuclear Information System (INIS)

    Smith, R. M.; Athanasiou, M.; Bai, J.; Liu, B.; Wang, T.

    2015-01-01

    The effect of surface states has been investigated in hybrid organic/inorganic white light emitting structures that employ high efficiency, nearfield non-radiative energy transfer (NRET) coupling. The structures utilize blue emitting InGaN/GaN multiple quantum well (MQW) nanorod arrays to minimize the separation with a yellow emitting F8BT coating. Surface states due to the exposed III-nitride surfaces of the nanostructures are found to reduce the NRET coupling rate. The surface states are passivated by deposition of a silicon nitride layer on the III-nitride nanorod surface leading to reduced surface recombination. A low thickness surface passivation is shown to increase the NRET coupling rate by 4 times compared to an un-passivated hybrid structure. A model is proposed to explain the increased NRET rate for the passivated hybrid structures based on the reduction in surface electron depletion of the passivated InGaN/GaN MQW nanorods surfaces

  7. Transfer of human frozen-thawed embryos with further cleavage during culture increases pregnancy rates

    Directory of Open Access Journals (Sweden)

    Bharat V Joshi

    2010-01-01

    Full Text Available Aim: To compare the pregnancy rate following transfer of frozen-thawed embryos with or without overnight culture after thawing. Settings and Design: This is a retrospective analysis of frozen-thawed embryo transfer (FET cycles performed between January 2006 and December 2008. Materials and Methods: Out of 518 thaw cycles, 504 resulted in embryo transfers (ETs. Of the total FET cycles, 415 were performed after an overnight culture of embryos (group A; and in 89 cycles, ET was performed within 2 hours of embryo thawing (group B. Statistical Analysis: The data were statistically analyzed using chi-square test. Results: We observed that with FET, women ≤30 years of age had a significantly higher (P=0.003 pregnancy rate (PR=28.9% as compared to women >30 years of age (17.5%. A significantly higher (P<0.001FNx08 pregnancy rate was also observed in women receiving 3 frozen-thawed embryos (29% as compared to those who received less than 3 embryos (10.7%. The difference in PR between group A (PR=24.3% and group B (PR=20.3% was not statistically significant. However, within group A, ET with cleaved embryos showed significantly ( P≤0.01 higher pregnancy rate compared to the uncleaved embryos, depending on the number of cleaved embryos transferred. Conclusion: No significant difference was noticed between FETs made with transfer of embryos with overnight culture and those without culture. However, within the cultured group, transfer of embryos cleaved during overnight culture gave significantly higher PR than transfers without any cleavage.

  8. Energy and Information Transfer Via Coherent Exciton Wave Packets

    Science.gov (United States)

    Zang, Xiaoning

    associated excitations were dubbed twisted excitons. Twisted exciton packets can be manipulated as they travel down molecular chains, and this has applications in quantum information science as well. In each setting considered, exciton dynamics were initially studied using a simple tight-binding formalism. This misses the actual many-body interactions and multiple energy levels associated real systems. To remedy this, I adapted an existing time-domain Density Functional Theory code and applied it to study the dynamics of exciton wave packets on quasi-one-dimensional systems. This required the use of high-performance computing and the construction of a number of key auxiliary codes. Establishing the requisite methodology constituted a substantial part of the entire thesis. Surprisingly, this effort uncovered a computational issue associated with Rabi oscillations that had been incorrectly characterized in the literature. My research elucidated the actual problem and a solution was found. This new methodology was an integral part of the overall computational analysis. The thesis then takes up the a detailed consideration of the prospect for creating systems that support a strong measure of transport coherence. While physical implementations include molecular assemblies, solid-state superlattices, and even optical lattices, I decided to focus on assemblies of nanometer-sized silicon quantum dots. First principles computational analysis was used to quantify reorganization within individual dots and excitonic coupling between dots. Quantum dot functionalizations were identified that make it plausible to maintain a measure of excitonic coherence even at room temperatures. Attention was then turned to the use of covalently bonded bridge material to join quantum dots in a way that facilitates efficient exciton transfer. Both carbon and silicon structures were considered by considering the way in which subunits might be best brought together. This resulted in a set of design criteria

  9. International Energy Prices(Exchange Rate and PPP)

    Energy Technology Data Exchange (ETDEWEB)

    Jo, Sung Han; Yoo, Dong Heon [Korea Energy Economics Institute, Euiwang (Korea)

    2000-11-01

    Energy is to be specially important to the Korean economy. In the past the major purpose of Korea's energy policies was to ensure that the energy was supplied at the low cost to encourage and sustain economic development and growth. Therefore, energy prices are distorted by government intervention. And this was the cause of inefficiency in usage of energy. In order to improve the energy efficiency and reduce the environmental impact of energy consumption, new energy pricing should be needed to the energy industry and the Korean economy. It is necessary to compare the domestic energy prices with other countries to improve the energy pricing system including tax, the relative structure of energy price, etc. In order to compare the domestic energy prices to those of other countries, the exchange rate, purchasing power parity and Big Mac index are used for calculation of common currency. We select 12 countries, which are Belgium, France, Germany, Greece, Ireland, Italy, Portugal, Spain, Switzerland, Taiwan, Mexico and England. The oil products(gasoline, diesel, heavy fuel oil and light fuel oil), natural gas and electricity are selected to compare the price. (author). 12 refs., 13 tabs.

  10. Commercial Building Energy Asset Rating Program -- Market Research

    Energy Technology Data Exchange (ETDEWEB)

    McCabe, Molly J.; Wang, Na

    2012-04-19

    Under contract to Pacific Northwest National Laboratory, HaydenTanner, LLC conducted an in-depth analysis of the potential market value of a commercial building energy asset rating program for the U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy. The market research objectives were to: (1) Evaluate market interest and need for a program and tool to offer asset rating and rapidly identify potential energy efficiency measures for the commercial building sector. (2) Identify key input variables and asset rating outputs that would facilitate increased investment in energy efficiency. (3) Assess best practices and lessons learned from existing national and international energy rating programs. (4) Identify core messaging to motivate owners, investors, financiers, and others in the real estate sector to adopt a voluntary asset rating program and, as a consequence, deploy high-performance strategies and technologies across new and existing buildings. (5) Identify leverage factors and incentives that facilitate increased investment in these buildings. To meet these objectives, work consisted of a review of the relevant literature, examination of existing and emergent asset and operational rating systems, interviews with industry stakeholders, and an evaluation of the value implication of an asset label on asset valuation. This report documents the analysis methodology and findings, conclusion, and recommendations. Its intent is to support and inform the DOE Office of Energy Efficiency and Renewable Energy on the market need and potential value impacts of an asset labeling and diagnostic tool to encourage high-performance new buildings and building efficiency retrofit projects.

  11. Investigations of effect of phase change mass transfer rate on cavitation process with homogeneous relaxation model

    Energy Technology Data Exchange (ETDEWEB)

    He, Zhixia; Zhang, Liang; Saha, Kaushik; Som, Sibendu; Duan, Lian; Wang, Qian

    2017-12-01

    The super high fuel injection pressure and micro size of nozzle orifice has been an important development trend for the fuel injection system. Accordingly, cavitation transient process, fuel compressibility, amount of noncondensable gas in the fuel and cavitation erosion have attracted more attention. Based on the fact of cavitation in itself is a kind of thermodynamic phase change process, this paper takes the perspective of the cavitation phase change mass transfer process to analyze above mentioned phenomenon. The two-phase cavitating turbulent flow simulations with VOF approach coupled with HRM cavitation model and U-RANS of standard k-ε turbulence model were performed for investigations of cavitation phase change mass transfer process. It is concluded the mass transfer time scale coefficient in the Homogenous Relaxation Model (HRM) representing mass transfer rate should tend to be as small as possible in a condition that ensured the solver stable. At very fast mass transfer rate, the phase change occurs at very thin interface between liquid and vapor phase and condensation occurs more focused and then will contribute predictably to a more serious cavitation erosion. Both the initial non-condensable gas in fuel and the fuel compressibility can accelerate the cavitation mass transfer process.

  12. System modelling to support accelerated fuel transfer rate at EBR-II

    International Nuclear Information System (INIS)

    Imel, G.R.; Houshyar, A.; Planchon, H.P.; Cutforth, D.C.

    1995-01-01

    The Experimental Breeder Reactor-II (EBR-II) ia a 62.5 MW(th) liquid metal reactor operated by Argonne National Laboratory for The United States Department of Energy. The reactor is located near Idaho Falls, Idaho at the Argonne-West site (ANL-W). Full power operation was achieved in 1964,- the reactor operated continuously since that time until October 1994 in a variety of configurations depending on the programmatic mission. A three year program was initiated in October, 1993 to replace the 330 depleted uranium blanket subassemblies (S/As) with stainless steel reflectors. It was intended to operate the reactor during the three year blanket unloading program, followed by about a half year of driver fuel unloading. However, in the summer of 1994, Congress dictacted that EBR-II be shut down October 1, and complete defueling without operation. To assist in the planning for resources needed for this defueling campaign, a mathematical model of the fuel handling sequence was developed utilizing the appropriate reliability factors and inherent mm constraints of each stage of the process. The model allows predictions of transfer rates under different scenarios. Additionally, it has facilitated planning of maintenance activities, as well as optimization of resources regarding manpower and modification effort. The model and its application is described in this paper

  13. Rate Optimization of Two-Way Relaying with Wireless Information and Power Transfer

    Directory of Open Access Journals (Sweden)

    Thinh Phu Do

    2017-11-01

    Full Text Available We consider the simultaneous wireless information and power transfer in two-phase decode-and-forward two-way relaying networks, where a relay harvests the energy from the signal to be relayed through either power splitting or time splitting. Here, we formulate the resource allocation problems optimizing the time-phase and signal splitting ratios to maximize the sum rate of the two communicating devices. The joint optimization problems are shown to be convex for both the power splitting and time splitting approaches after some transformation if required to be solvable with an existing solver. To lower the computational complexity, we also present the suboptimal methods optimizing the splitting ratio for the fixed time-phase and derive a closed-form solution for the suboptimal method based on the power splitting. The results demonstrate that the power splitting approaches outperform their time splitting counterparts and the suboptimal power splitting approach provides a performance close to the optimal one while reducing the complexity significantly.

  14. Förster resonance energy transfer, absorption and emission spectra in multichromophoric systems. III. Exact stochastic path integral evaluation.

    Science.gov (United States)

    Moix, Jeremy M; Ma, Jian; Cao, Jianshu

    2015-03-07

    A numerically exact path integral treatment of the absorption and emission spectra of open quantum systems is presented that requires only the straightforward solution of a stochastic differential equation. The approach converges rapidly enabling the calculation of spectra of large excitonic systems across the complete range of system parameters and for arbitrary bath spectral densities. With the numerically exact absorption and emission operators, one can also immediately compute energy transfer rates using the multi-chromophoric Förster resonant energy transfer formalism. Benchmark calculations on the emission spectra of two level systems are presented demonstrating the efficacy of the stochastic approach. This is followed by calculations of the energy transfer rates between two weakly coupled dimer systems as a function of temperature and system-bath coupling strength. It is shown that the recently developed hybrid cumulant expansion (see Paper II) is the only perturbative method capable of generating uniformly reliable energy transfer rates and emission spectra across a broad range of system parameters.

  15. High Yolk Testosterone Transfer Is Associated with an Increased Female Metabolic Rate.

    Science.gov (United States)

    Tschirren, Barbara; Ziegler, Ann-Kathrin; Canale, Cindy I; Okuliarová, Monika; Zeman, Michal; Giraudeau, Mathieu

    2016-01-01

    Yolk androgens of maternal origin are important mediators of prenatal maternal effects. Although in many species short-term benefits of exposure to high yolk androgen concentrations for the offspring have been observed, females differ substantially in the amount of androgens they transfer to their eggs. It suggests that costs for the offspring or the mother constrain the evolution of maternal hormone transfer. However, to date, the nature of these costs remains poorly understood. Unlike most previous work that focused on potential costs for the offspring, we here investigated whether high yolk testosterone transfer is associated with metabolic costs (i.e., a higher metabolic rate) for the mother. We show that Japanese quail (Coturnix japonica) females that deposit higher testosterone concentrations into their eggs have a higher resting metabolic rate. Because a higher metabolic rate is often associated with a shorter life span, this relationship may explain the negative association between yolk testosterone transfer and female longevity observed in the wild. Our results suggest that metabolic costs for the mother can balance the short-term benefits of yolk testosterone exposure for the offspring, thereby contributing to the maintenance of variation in maternal yolk hormone transfer in natural populations.

  16. The empirical relationship between energy futures prices and exchange rates

    International Nuclear Information System (INIS)

    Sadorsky, P.

    2000-01-01

    This paper investigates the interaction between energy futures prices and exchange rates. Results are presented to show that futures prices for crude oil, heating oil and unleaded gasoline are co-integrated with a trade-weighted index of exchange rates. This is important because it means that there exists a long-run equilibrium relationship between these four variables. Granger causality results for both the long- and short-run are presented. Evidence is also presented that suggests exchange rates transmit exogenous shocks to energy futures prices. 22 refs

  17. Imaging and Manipulating Energy Transfer Among Quantum Dots at Individual Dot Resolution.

    Science.gov (United States)

    Nguyen, Duc; Nguyen, Huy A; Lyding, Joseph W; Gruebele, Martin

    2017-06-27

    Many processes of interest in quantum dots involve charge or energy transfer from one dot to another. Energy transfer in films of quantum dots as well as between linked quantum dots has been demonstrated by luminescence shift, and the ultrafast time-dependence of energy transfer processes has been resolved. Bandgap variation among dots (energy disorder) and dot separation are known to play an important role in how energy diffuses. Thus, it would be very useful if energy transfer could be visualized directly on a dot-by-dot basis among small clusters or within films of quantum dots. To that effect, we report single molecule optical absorption detected by scanning tunneling microscopy (SMA-STM) to image energy pooling from donor into acceptor dots on a dot-by-dot basis. We show that we can manipulate groups of quantum dots by pruning away the dominant acceptor dot, and switching the energy transfer path to a different acceptor dot. Our experimental data agrees well with a simple Monte Carlo lattice model of energy transfer, similar to models in the literature, in which excitation energy is transferred preferentially from dots with a larger bandgap to dots with a smaller bandgap.

  18. Blinking fluorescence of single donor-acceptor pairs: important role of "dark'' states in resonance energy transfer via singlet levels.

    Science.gov (United States)

    Osad'ko, I S; Shchukina, A L

    2012-06-01

    The influence of triplet levels on Förster resonance energy transfer via singlet levels in donor-acceptor (D-A) pairs is studied. Four types of D-A pair are considered: (i) two-level donor and two-level acceptor, (ii) three-level donor and two-level acceptor, (iii) two-level donor and three-level acceptor, and (iv) three-level donor and three-level acceptor. If singlet-triplet transitions in a three-level acceptor molecule are ineffective, the energy transfer efficiency E=I_{A}/(I_{A}+I_{D}), where I_{D} and I_{A} are the average intensities of donor and acceptor fluorescence, can be described by the simple theoretical equation E(F)=FT_{D}/(1+FT_{D}). Here F is the rate of energy transfer, and T_{D} is the donor fluorescence lifetime. In accordance with the last equation, 100% of the donor electronic energy can be transferred to an acceptor molecule at FT_{D}≫1. However, if singlet-triplet transitions in a three-level acceptor molecule are effective, the energy transfer efficiency is described by another theoretical equation, E(F)=F[over ¯](F)T_{D}/[1+F[over ¯](F)T_{D}]. Here F[over ¯](F) is a function of F depending on singlet-triplet transitions in both donor and acceptor molecules. Expressions for the functions F[over ¯](F) are derived. In this case the energy transfer efficiency will be far from 100% even at FT_{D}≫1. The character of the intensity fluctuations of donor and acceptor fluorescence indicates which of the two equations for E(F) should be used to find the value of the rate F. Therefore, random time instants of photon emission in both donor and acceptor fluorescence are calculated by the Monte Carlo method for all four types of D-A pair. Theoretical expressions for start-stop correlators (waiting time distributions) in donor and acceptor fluorescence are derived. The probabilities w_{N}^{D}(t) and w_{N}^{A}(t) of finding N photons of donor and acceptor fluorescence in the time interval t are calculated for various values of the energy

  19. The 2H(e, e' p)n reaction at large energy transfers

    NARCIS (Netherlands)

    Willering, Hendrik Willem

    2003-01-01

    At the ELSA accelerator facillity in Bonn, Germany, we have measured the deutron "breakup" reaction 2H(e,e' p)n at four-momentum transfers around Q2 = -0 .20(GeV/c)2 with an electron beam energy of E0 = 1.6 GeV. The cross section has been determined for energy transfers extending from the

  20. Insights into the energy transfer mechanism in Ce3+-Yb3+ codoped YAG phosphors

    NARCIS (Netherlands)

    Yu, D. C.; Rabouw, F. T.|info:eu-repo/dai/nl/413318036; Boon, W. Q.; Kieboom, T.; Ye, S.; Zhang, Q. Y.; Meijerink, A.|info:eu-repo/dai/nl/075044986

    2014-01-01

    Two distinct energy transfer (ET) mechanisms have been proposed for the conversion of blue to near-infrared (NIR) photons in YAG:Ce3+,Yb3+. The first mechanism involves downconversion by cooperative energy transfer, which would yield two NIR photons for each blue photon excitation. The second

  1. Hybrid Systems Based on Layered Silicate and Organic Dyes for Cascade Energy Transfer

    Czech Academy of Sciences Publication Activity Database

    Belušáková, S.; Lang, Kamil; Bujdák, J.

    2015-01-01

    Roč. 119, č. 38 (2015), s. 21784-21794 ISSN 1932-7447 Institutional support: RVO:61388980 Keywords : Cascade energy transfers * Multicomponent films * Resonance energy transfer * Spectral properties * Steady state fluorescence * Time-resolved fluorescence spectroscopy Subject RIV: CA - Inorganic Chemistry Impact factor: 4.509, year: 2015

  2. Forster resonance energy transfer in the system of human serum albumin-xanthene dyes

    Science.gov (United States)

    Kochubey, V. I.; Pravdin, A. B.; Melnikov, A. G.; Konstantinova, I.; Alonova, I. V.

    2016-04-01

    The processes of interaction of fluorescent probes: eosin and erythrosine with human serum albumin (HSA) were studied by the methods of absorption and fluorescence spectroscopy. Extinction coefficients of probes were determined. Critical transfer radius and the energy transfer efficiency were defined by fluorescence quenching of HSA. Analysis of the excitation spectra of HSA revealed that the energy transfer process is carried out mainly between tryptophanyl and probes.

  3. Multi-step intramolecular excitation energy transfer in dendritic pyrene-phosphorus(V)porphyrin heptads

    International Nuclear Information System (INIS)

    Hirakawa, Kazutaka; Segawa, Hiroshi

    2016-01-01

    Dendritic heptad molecules in which four pyrenyl groups are connected at the central phosphorus atom of the edge-porphyrins of the center-to-edge type porphyrin trimers were synthesized to investigate a multi-step excitation energy transfer. As the central energy acceptor, two types porphyrins which one was phosphorus(V)tetraphenylporphyrin (H2) and another was its derivative substituted by butoxy groups at four para-position of meso-phenyl groups (H1) were used. In the photoexcited state of the pyrene units, the excitation energy transfer to the central-porphyrin unit was observed in toluene. The excitation energy transfer is considered to be through two pathways; one is a stepwise pathway through the edge-porphyrin unit and another is a direct excitation energy transfer to the central porphyrin. The direct excitation energy transfer from pyrenes to the edge-porphyrin and central-porphyrin were observed in the case for H1. From the excited state of the edge-porphyrins, the excitation energy transfer to the central-porphyrin occurs in the H1 case. In the H2 case, the excitation energy of central-porphyrin is higher than that of H1, and the electron transfer from edge-porphyrin to the central-porphyrin become predominant process. - Highlights: • Dendritic pyrene-porphyrin heptads were synthesized. • Excitation energy transfer occurs from the pyrenyl moiety to the phosphorus(V)porphyrin. • The stepwise and direct energy transfer pathways were observed. • The quantum yields of these energy transfer pathways could be determined.

  4. Multi-step intramolecular excitation energy transfer in dendritic pyrene-phosphorus(V)porphyrin heptads

    Energy Technology Data Exchange (ETDEWEB)

    Hirakawa, Kazutaka, E-mail: hirakawa.kazutaka@shizuoka.ac.jp [Applied Chemistry and Biochemical Engineering Course, Department of Engineering, Graduate School of Integrated Science and Technology, Shizuoka University, Johoku 3-5-1, Naka-ku, Hamamatsu, Shizuoka 432-8561 (Japan); Department of Optoelectronics and Nanostructure Science, Graduate School of Science and Technology, Shizuoka University, Johoku 3-5-1, Naka-ku, Hamamatsu, Shizuoka 432-8561 (Japan); Segawa, Hiroshi [Department of Multi-Disciplinary Science - General Systems Studies, Graduate School of Arts and Sciences, The University of Tokyo, Komaba 3-8-1, Meguro-ku, Tokyo 153-8904 (Japan); Research Center for Advanced Science and Technology, The University of Tokyo, Komaba 4-6-1, Meguro-ku, Tokyo 153-8904 (Japan)

    2016-11-15

    Dendritic heptad molecules in which four pyrenyl groups are connected at the central phosphorus atom of the edge-porphyrins of the center-to-edge type porphyrin trimers were synthesized to investigate a multi-step excitation energy transfer. As the central energy acceptor, two types porphyrins which one was phosphorus(V)tetraphenylporphyrin (H2) and another was its derivative substituted by butoxy groups at four para-position of meso-phenyl groups (H1) were used. In the photoexcited state of the pyrene units, the excitation energy transfer to the central-porphyrin unit was observed in toluene. The excitation energy transfer is considered to be through two pathways; one is a stepwise pathway through the edge-porphyrin unit and another is a direct excitation energy transfer to the central porphyrin. The direct excitation energy transfer from pyrenes to the edge-porphyrin and central-porphyrin were observed in the case for H1. From the excited state of the edge-porphyrins, the excitation energy transfer to the central-porphyrin occurs in the H1 case. In the H2 case, the excitation energy of central-porphyrin is higher than that of H1, and the electron transfer from edge-porphyrin to the central-porphyrin become predominant process. - Highlights: • Dendritic pyrene-porphyrin heptads were synthesized. • Excitation energy transfer occurs from the pyrenyl moiety to the phosphorus(V)porphyrin. • The stepwise and direct energy transfer pathways were observed. • The quantum yields of these energy transfer pathways could be determined.

  5. Energy and charge transfer cascade in methylammonium lead bromide perovskite nanoparticle aggregates.

    Science.gov (United States)

    Bouduban, Marine E F; Burgos-Caminal, Andrés; Ossola, Rachele; Teuscher, Joël; Moser, Jacques-E

    2017-06-01

    Highly photoluminescent hybrid lead halide perovskite nanoparticles have recently attracted wide interest in the context of high-stake applications, such as light emitting diodes (LEDs), light emitting transistors and lasers. In addition, they constitute ideal model systems to explore energy and charge transport phenomena occurring at the boundaries of nanocrystalline grains forming thin films in high-efficiency perovskite solar cells (PSCs). Here we report a complete photophysical study of CH 3 NH 3 PbBr 3 perovskite nanoparticles suspended in chlorobenzene and highlight some important interaction properties. Colloidal suspensions under study were constituted of dispersed aggregates of quasi-2D platelets of a range of thicknesses, decorated with 3D-like spherical nanoparticles. These types of nanostructures possess different optical properties that afford a handle for probing them individually. The photophysics of the colloidal particles was studied by femtosecond pump-probe spectroscopy and time-correlated single-photon counting. We show here that a cascade of energy and exciton-mediated charge transfer occurs between nanostructures: upon photoexcitation, localized excitons within one nanostructure can either recombine on a ps timescale, yielding a short-lived emission, or form charge-transfer states (CTSs) across adjacent domains, resulting in longer-lived photoluminescence in the millisecond timescale. Furthermore, CTSs exhibit a clear signature in the form of a strong photoinduced electroabsorption evidenced in femtosecond transient absorption measurements. Charge transfer dynamics at the surface of the nanoparticles have been studied with various quenchers in solution. Efficient hole transfer to N , N , N ', N '-tetrakis(4-methoxyphenyl)benzidine (MeO-TPD) and 1,4-bis(diphenyl-amino)benzene (BDB) donors was attested by the quenching of the nanoparticles emission. The charge transfer rate was limited by the organic layer used to stabilize the nanoparticles

  6. Travelling energy systems: knowledge transfer for energy efficiency and conservation from European to Australian building projects

    Energy Technology Data Exchange (ETDEWEB)

    Glad, Wiktoria (Tema Technology and Social Change, Linkoeping Univ. (Sweden); Inst. for Sustainable Futures, Univ. of Technology, Sydney (Australia))

    2009-07-01

    Energy efficiency and conservation in the Australian built environment have not yet been implemented to any great extent. Despite favourable prerequisites, such as vast windswept unpopulated areas suitable for wind power and many hours of direct sunlight in most populated areas, electricity is mainly generated by burning brown coal and buildings are poorly equipped for hot summers and cool winters. Australia urgently needs to convert to alternative energy sources and implement energy efficiency measures, since its carbon dioxide emissions per capita are among the highest in the world. In a recent major redevelopment in Sydney, the Carlton and United Brewery (CUB) site knowledge of energy efficiency and conservation measures used in European buildings was transferred and implemented in local designs and infrastructure. This knowledge came mainly from urban planning and developments in London, but also from high-profile architectural firms based in Paris and Germany. The arrival of this knowledge in Australia led to phases when the knowledge was translated and enacted in local spaces and the constituent ideas were transformed into action. The present research is based on ten months of ethnographic fieldwork in which the planning and design of the CUB site was observed. The results of the study identify barriers to and opportunities for energy system knowledge transfer between different cultures and local spaces. Substantial time must be spent overcoming cultural barriers, so the involved parties can start talking the same language. This is not only true for stakeholders operating in different continents, but for stakeholders operating in different local arenas in the same country.

  7. Energy Efficiency Maximization for WSNs with Simultaneous Wireless Information and Power Transfer.

    Science.gov (United States)

    Yu, Hongyan; Zhang, Yongqiang; Guo, Songtao; Yang, Yuanyuan; Ji, Luyue

    2017-08-18

    Recently, the simultaneous wireless information and power transfer (SWIPT) technique has been regarded as a promising approach to enhance performance of wireless sensor networks with limited energy supply. However, from a green communication perspective, energy efficiency optimization for SWIPT system design has not been investigated in Wireless Rechargeable Sensor Networks (WRSNs). In this paper, we consider the tradeoffs between energy efficiency and three factors including spectral efficiency, the transmit power and outage target rate for two different modes, i.e., power splitting (PS) and time switching modes (TS), at the receiver. Moreover, we formulate the energy efficiency maximization problem subject to the constraints of minimum Quality of Service (QoS), minimum harvested energy and maximum transmission power as non-convex optimization problem. In particular, we focus on optimizing power control and power allocation policy in PS and TS modes to maximize energy efficiency of data transmission. For PS and TS modes, we propose the corresponding algorithm to characterize a non-convex optimization problem that takes into account the circuit power consumption and the harvested energy. By exploiting nonlinear fractional programming and Lagrangian dual decomposition, we propose suboptimal iterative algorithms to obtain the solutions of non-convex optimization problems. Furthermore, we derive the outage probability and effective throughput from the scenarios that the transmitter does not or partially know the channel state information (CSI) of the receiver. Simulation results illustrate that the proposed optimal iterative algorithm can achieve optimal solutions within a small number of iterations and various tradeoffs between energy efficiency and spectral efficiency, transmit power and outage target rate, respectively.

  8. Energy Efficiency Maximization for WSNs with Simultaneous Wireless Information and Power Transfer

    Science.gov (United States)

    Yu, Hongyan; Zhang, Yongqiang; Yang, Yuanyuan; Ji, Luyue

    2017-01-01

    Recently, the simultaneous wireless information and power transfer (SWIPT) technique has been regarded as a promising approach to enhance performance of wireless sensor networks with limited energy supply. However, from a green communication perspective, energy efficiency optimization for SWIPT system design has not been investigated in Wireless Rechargeable Sensor Networks (WRSNs). In this paper, we consider the tradeoffs between energy efficiency and three factors including spectral efficiency, the transmit power and outage target rate for two different modes, i.e., power splitting (PS) and time switching modes (TS), at the receiver. Moreover, we formulate the energy efficiency maximization problem subject to the constraints of minimum Quality of Service (QoS), minimum harvested energy and maximum transmission power as non-convex optimization problem. In particular, we focus on optimizing power control and power allocation policy in PS and TS modes to maximize energy efficiency of data transmission. For PS and TS modes, we propose the corresponding algorithm to characterize a non-convex optimization problem that takes into account the circuit power consumption and the harvested energy. By exploiting nonlinear fractional programming and Lagrangian dual decomposition, we propose suboptimal iterative algorithms to obtain the solutions of non-convex optimization problems. Furthermore, we derive the outage probability and effective throughput from the scenarios that the transmitter does not or partially know the channel state information (CSI) of the receiver. Simulation results illustrate that the proposed optimal iterative algorithm can achieve optimal solutions within a small number of iterations and various tradeoffs between energy efficiency and spectral efficiency, transmit power and outage target rate, respectively. PMID:28820496

  9. Photoprotection and triplet energy transfer in higher plants: the role of electronic and nuclear fluctuations.

    Science.gov (United States)

    Cupellini, Lorenzo; Jurinovich, Sandro; Prandi, Ingrid G; Caprasecca, Stefano; Mennucci, Benedetta

    2016-04-28

    Photosynthetic organisms employ several photoprotection strategies to avoid damage due to the excess energy in high light conditions. Among these, quenching of triplet chlorophylls by neighboring carotenoids (Cars) is fundamental in preventing the formation of singlet oxygen. Cars are able to accept the triplets from chlorophylls by triplet energy transfer (TET). We have here studied TET rates in CP29, a minor light-harvesting complex (LHC) of the Photosystem II in plants. A fully atomistic strategy combining classical molecular dynamics of the LHC in its natural environment with a hybrid time-dependent density functional theory/polarizable MM description of the TET is used. We find that the structural fluctuations of the pigment-protein complex can largely enhance the transfer rates with respect to those predicted using the crystal structure, reducing the triplet quenching times in the subnanosecond scale. These findings add a new perspective for the interpretation of the photoprotection function and its relation with structural motions of the LHC.

  10. Luminescence and energy transfer properties of Eu3+ and Gd3+ in ZrO2

    International Nuclear Information System (INIS)

    Villabona-Leal, E.G.; Diaz-Torres, L.A.; Desirena, H.; Rodríguez-López, J.L.; Pérez, Elías; Meza, Octavio

    2014-01-01

    Red luminescence emission in ZrO2:Gd 3+ –Eu 3+ nanocrystal under 250 nm radiation excitation is achieved. These materials exhibit a tetragonal phase that is retained by the presence of lanthanide ions. Thus, a study of the optical properties as a function of the dopant concentration was been carried out without the deleterious effects of having segregation of other crystalline phases. We analyze the emission and lifetime curves as a function of dopant concentration through a rate equation simulation, finding an excellent fitting. As results, the nonradiative and radiative relaxation constants, as well as a quantitative estimation of the energy transfer processes among Eu 3+ , Gd 3+ and O 2− ions are reported for the first time. The proposed model can be extended (or applicable) to explain the fluorescence dynamics in other nanomaterials doped with Eu 3+ and Gd 3+ under UV excitation. -- Highlights: • ZrO 2 nanocrystal exhibits a tetragonal phase in the presence of Eu and Gd dopants. • Emission and lifetimes as a function of dopant concentration were analyzed by rate equation model. • Quantitative estimation of the energy transfer processes among Eu 3+ , Gd 3+ and O 2− ions are reported

  11. Multinucleon effects in muon capture on 3He at high energy transfer

    International Nuclear Information System (INIS)

    Kuhn, S.E.; Cummings, W.J.; Dodge, G.E.; Hanna, S.S.; King, B.H.; Shin, Y.M.; Congleton, J.G.; Helmer, R.; Schubank, R.B.; Stevenson, N.R.; Wienands, U.; Lee, Y.K.; Mason, G.R.; King, B.E.; Chung, K.S.; Lee, J.M.; Rosenzweig, D.P.

    1994-01-01

    Energy spectra of both protons and deuterons emitted following the capture of negative muons by 3 He nuclei have been measured for energies above 15 MeV. A limited number of proton-neutron pairs emitted in coincidence were also observed. A simple plane wave impulse approximation (PWIA) model calculation yields fair agreement with the measured proton energy spectra, but underpredicts the measured rate of deuteron production above our energy threshold by a large factor. A more sophisticated PWIA calculation for the two-body breakup channel, based on a realistic three-body wave function for the initial state, is closer to the deuteron data at moderate energies, but still is significantly lower near the kinematic end point. The proton-neutron coincidence data also point to the presence of significant strength involving more than one nucleon in the capture process at high energy transfer. These results indicate that additional terms in the capture matrix element beyond the impulse approximation contribution may be required to explain the experimental data. Specifically, the inclusion of nucleon-nucleon correlations in the initial or final state and meson exchange current contributions could bring calculations into better agreement with our data. A fully microscopic calculation would thus open the possibility for a quantitative test of multinucleon effects in the weak interaction

  12. On the rate of triplet excitation transfer in the diffuse limit

    International Nuclear Information System (INIS)

    Davidovich, M.A.; Knox, R.S.

    1979-11-01

    The usefulness of spectral data in estimating intermolecular triplet excitation transfer rates in found to be rather limited and to depend explicitly on the mechaisms which allow the optical transitions. Necessary conditions for the validity of such use of spectra are given, and the otherwise required correction factors are discussed and estimated. (Author) [pt

  13. Nanofluid heat transfer under mixed convection flow in a tube for solar thermal energy applications.

    Science.gov (United States)

    Sekhar, Y Raja; Sharma, K V; Kamal, Subhash

    2016-05-01

    The solar flat plate collector operating under different convective modes has low efficiency for energy conversion. The energy absorbed by the working fluid in the collector system and its heat transfer characteristics vary with solar insolation and mass flow rate. The performance of the system is improved by reducing the losses from the collector. Various passive methods have been devised to aid energy absorption by the working fluid. Also, working fluids are modified using nanoparticles to improve the thermal properties of the fluid. In the present work, simulation and experimental studies are undertaken for pipe flow at constant heat flux boundary condition in the mixed convection mode. The working fluid at low Reynolds number in the mixed laminar flow range is undertaken with water in thermosyphon mode for different inclination angles of the tube. Local and average coefficients are determined experimentally and compared with theoretical values for water-based Al2O3 nanofluids. The results show an enhancement in heat transfer in the experimental range with Rayleigh number at higher inclinations of the collector tube for water and nanofluids.

  14. Localized surface plasmon mediated energy transfer in the vicinity of core-shell nanoparticle

    Energy Technology Data Exchange (ETDEWEB)

    Shishodia, Manmohan Singh, E-mail: manmohan@gbu.ac.in; Juneja, Soniya [Department of Applied Physics, School of Vocational Studies and Applied Sciences, Gautam Buddha University, Greater Noida 201308 (India)

    2016-05-28

    Multipole spectral expansion based theory of energy transfer interactions between a donor and an acceptor molecule in the vicinity of a core-shell (nanoshell or core@shell) based plasmonic nanostructure is developed. In view of the diverse applications and rich plasmonic features such as tuning capability of surface plasmon (SP) frequencies, greater sensitivity to the change of dielectric environment, controllable redirection of electromagnetic radiation, closed form expressions for Energy Transfer Rate Enhancement Factor (ETREF) near core-shell particle are reported. The dependence of ETREF on different parameters is established through fitting equations, perceived to be of key importance for developing appropriate designs. The theoretical approach developed in the present work is capable of treating higher order multipoles, which, in turn, are also shown to play a crucial role in the present context. Moreover, closed form expressions derived in the present work can directly be used as formula, e.g., for designing SP based biosensors and estimating energy exchange between proteins and excitonic interactions in quantum dots.

  15. Lumley's energy cascade dissipation rate model for boundary-free turbulent shear flows

    Science.gov (United States)

    Duncan, B. S.

    1992-01-01

    True dissipation occurs mainly at the highest wavenumbers where the eddy sizes are comparatively small. These high wavenumbers receive their energy through the spectral cascade of energy starting with the largest eddies spilling energy into the smaller eddies, passing through each wavenumber until it is dissipated at the microscopic scale. However, a small percentage of the energy does not spill continuously through the cascade but is instantly passed to the higher wavenumbers. Consequently, the smallest eddies receive a certain amount of energy almost immediately. As the spectral energy cascade continues, the highest wavenumber needs a certain time to receive all the energy which has been transferred from the largest eddies. As such, there is a time delay, of the order of tau, between the generation of energy by the largest eddies and the eventual dissipation of this energy. For equilibrium turbulence at high Reynolds numbers, there is a wide range where energy is neither produced by the large eddies nor dissipated by viscosity, but is conserved and passed from wavenumber to higher wavenumbers. The rate at which energy cascades from one wavenumber to another is proportional to the energy contained within that wavenumber. This rate is constant and has been used in the past as a dissipation rate of turbulent kinetic energy. However, this is true only in steady, equilibrium turbulence. Most dissipation models contend that the production of dissipation is proportional to the production of energy and that the destruction of dissipation is proportional to the destruction of energy. In essence, these models state that the change in the dissipation rate is proportional to the change in the kinetic energy. This assumption is obviously incorrect for the case where there is no production of turbulent energy, yet energy continues to cascade from large to small eddies. If the time lag between the onset on the energy cascade to the destruction of energy at the microscale can be

  16. Energy optimization for upstream data transfer in 802.15.4 beacon-enabled star formulation

    Science.gov (United States)

    Liu, Hua; Krishnamachari, Bhaskar

    2008-08-01

    Energy saving is one of the major concerns for low rate personal area networks. This paper models energy consumption for beacon-enabled time-slotted media accessing control cooperated with sleeping scheduling in a star network formulation for IEEE 802.15.4 standard. We investigate two different upstream (data transfer from devices to a network coordinator) strategies: a) tracking strategy: the devices wake up and check status (track the beacon) in each time slot; b) non-tracking strategy: nodes only wake-up upon data arriving and stay awake till data transmitted to the coordinator. We consider the tradeoff between energy cost and average data transmission delay for both strategies. Both scenarios are formulated as optimization problems and the optimal solutions are discussed. Our results show that different data arrival rate and system parameters (such as contention access period interval, upstream speed etc.) result in different strategies in terms of energy optimization with maximum delay constraints. Hence, according to different applications and system settings, different strategies might be chosen by each node to achieve energy optimization for both self-interested view and system view. We give the relation among the tunable parameters by formulas and plots to illustrate which strategy is better under corresponding parameters. There are two main points emphasized in our results with delay constraints: on one hand, when the system setting is fixed by coordinator, nodes in the network can intelligently change their strategies according to corresponding application data arrival rate; on the other hand, when the nodes' applications are known by the coordinator, the coordinator can tune the system parameters to achieve optimal system energy consumption.

  17. Fracture patterns and the energy release rate of phosphorene.

    Science.gov (United States)

    Liu, Ning; Hong, Jiawang; Pidaparti, Ramana; Wang, Xianqiao

    2016-03-14

    Phosphorene, also known as monolayer black phosphorus, has been enjoying popularity in electronic devices due to its superior electrical properties. However, it's relatively low Young's modulus, low fracture strength and susceptibility to structural failure have limited its application in mechanical devices. Therefore, in order to design more mechanically reliable devices that utilize phosphorene, it is necessary to explore the fracture patterns and energy release rate of phosphorene. In this study, molecular dynamics simulations are performed to investigate phosphorene's fracture mechanism. The results indicate that fracture under uniaxial tension along the armchair direction is attributed to a break in the interlayer bond angles, while failure in the zigzag direction is triggered by the break in both intra-layer angles and bonds. Furthermore, we developed a modified Griffith criterion to analyze the energy release rate of phosphorene and its dependence on the strain rates and orientations of cracks. Simulation results indicate that phosphorene's energy release rate remains almost unchanged in the armchair direction while it fluctuates intensively in the zigzag direction. Additionally, the strain rate was found to play a negligible role in the energy release rate. The geometrical factor α in the Griffith's criterion is almost constant when the crack orientation is smaller than 45 degree, regardless of the crack orientation and loading direction. Overall, these findings provide helpful insights into the mechanical properties and failure behavior of phosphorene.

  18. Effects of variable specific heat on energy transfer in a high-temperature supersonic channel flow

    Science.gov (United States)

    Chen, Xiaoping; Li, Xiaopeng; Dou, Hua-Shu; Zhu, Zuchao

    2018-05-01

    An energy transfer mechanism in high-temperature supersonic turbulent flow for variable specific heat (VSH) condition through turbulent kinetic energy (TKE), mean kinetic energy (MKE), turbulent internal energy (TIE) and mean internal energy (MIE) is proposed. The similarities of energy budgets between VSH and constant specific heat (CSH) conditions are investigated by introducing a vibrational energy excited degree and considering the effects of fluctuating specific heat. Direct numerical simulation (DNS) of temporally evolving high-temperature supersonic turbulent channel flow is conducted at Mach number 3.0 and Reynolds number 4800 combined with a constant dimensional wall temperature 1192.60 K for VSH and CSH conditions to validate the proposed energy transfer mechanism. The differences between the terms in the two kinetic energy budgets for VSH and CSH conditions are small; however, the magnitude of molecular diffusion term for VSH condition is significantly smaller than that for CSH condition. The non-negligible energy transfer is obtained after neglecting several small terms of diffusion, dissipation and compressibility related. The non-negligible energy transfer involving TIE includes three processes, in which energy can be gained from TKE and MIE and lost to MIE. The same non-negligible energy transfer through TKE, MKE and MIE is observed for both the conditions.

  19. Subwavelength dielectric nanorod chains for energy transfer in the visible range.

    Science.gov (United States)

    Li, Dongdong; Zhang, Jingjing; Yan, Changchun; Xu, Zhengji; Zhang, Dao Hua

    2017-10-15

    We report a new type of energy transfer device, formed by a dielectric nanorod array embedded in a silver slab. Such dielectric chain structures allow surface plasmon wave guiding with large propagation length and highly suppressed crosstalk between adjacent transmission channels. The simulation results show that our proposed design can be used to enhance the energy transfer along the waveguide-like dielectric nanorod chains via coupled plasmons, where the energy spreading is effectively suppressed, and superior imaging properties in terms of resolution and energy transfer distance can be achieved.

  20. Liquid metal heat transfer in heat exchangers under low flow rate conditions

    International Nuclear Information System (INIS)

    Mochizuki, Hiroyasu

    2015-01-01

    The present paper describes the liquid metal heat transfer in heat exchangers under low flow rate conditions. Measured data from some experiments indicate that heat transfer coefficients of liquid metals at very low Péclet number are much lower than what are predicted by the well-known empirical relations. The cause of this phenomenon was not fully understood for many years. In the present study, one countercurrent-type heat exchanger is analyzed using three, separated countercurrent heat exchanger models: one is a heat exchanger model in the tube bank region, while the upper and lower plena are modeled as two heat exchangers with a single heat transfer tube. In all three heat exchangers, the same empirical correlation is used in the heat transfer calculation on the tube and the shell sides. The Nusselt number, as a function of the Péclet number, calculated from measured temperature and flow rate data in a 50 MW experimental facility was correctly reproduced by the calculation result, when the calculated result is processed in the same way as the experiment. Finally, it is clarified that the deviation is a superficial phenomenon which is caused by the heat transfer in the plena of the heat exchanger. (author)

  1. Excitation and charge transfer in low-energy hydrogen atom collisions with neutral oxygen

    Science.gov (United States)

    Barklem, P. S.

    2018-02-01

    Excitation and charge transfer in low-energy O+H collisions is studied; it is a problem of importance for modelling stellar spectra and obtaining accurate oxygen abundances in late-type stars including the Sun. The collisions have been studied theoretically using a previously presented method based on an asymptotic two-electron linear combination of atomic orbitals (LCAO) model of ionic-covalent interactions in the neutral atom-hydrogen-atom system, together with the multichannel Landau-Zener model. The method has been extended to include configurations involving excited states of hydrogen using an estimate for the two-electron transition coupling, but this extension was found to not lead to any remarkably high rates. Rate coefficients are calculated for temperatures in the range 1000-20 000 K, and charge transfer and (de)excitation processes involving the first excited S-states, 4s.5So and 4s.3So, are found to have the highest rates. Data are available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/vizbin/qcat?J/A+A/610/A57. The data are also available at http://https://github.com/barklem/public-data

  2. Magnetospheric storm dynamics in terms of energy output rate

    International Nuclear Information System (INIS)

    Prigancova, A.; Feldstein, Ya.I.

    1992-01-01

    Using hourly values of both the global magnetospheric disturbance characteristic DR, and AE index of auroral ionospheric currents during magnetic storm intervals, the energy output rate dynamics is evaluated for a magnetic storm main/recovery phase and a whole storm interval. The magnetospheric response to the solar wind energy input rate under varying interplanetary and magnetospheric conditions is considered from the temporal variability point of view. The peculiarities of the response are traced separately. As far as quantitative characteristics of energy output rate are concerned, the time dependence pattern of the ring current decay parameter is emphasized to be fairly important. It is pointed out that more insight into the plasma processes, especially at L = 3 - 5, is needed for adequate evidence of the dependence. (Author)

  3. Efficient energy transfer and increase of energy density of magnetically charged flywheels

    International Nuclear Information System (INIS)

    Hinterdorfer, T.

    2014-01-01

    Flywheel Energy Storage Systems represent an ecologically and economically sustainable technology for decentralized energy storage. Compared to other storage technologies such as e.g. chemical accumulators, they offer longer life cycles without performance degradation over time and usage and need almost no systematic maintenance. Further, they are made of environmentally friendly materials. By means of the driving torque of an electric motor, the flywheel is accelerated and thus electrical energy is transformed to kinetic energy. The stored energy can be transfered back by the load torque of a generator when needed. Modern flywheel energy storage applications use magnetic bearings to minimize selfdischarge. To avoid bearing forces due to rotor eccentricity an unbalance control strategy is used. However, this leads to an off-centered run of the electric machines rotor which in turn generates undesirable forces. A force-compensating operation of the electric machine will minimize the influence on the magnetic bearings in the planned control scheme, thus increasing their efficiency. Different concepts will be developed and compared to each other by means of simulations. Validation of the simulation models is carried out on a specially constructed test setup under defined conditions. In addition, the electrical machine will be integrated into the concept of redundancy of the flywheel. A bearingless operation increases the reliability and enables a safe shutdown of the application in case of malfunction of the magnetic bearings. High strength composite materials are used to achieve high speeds. Based on existing results from past research activities, a disc-shaped rotor is optimized first. To increase material utilization and to maximize energy density a topology optimization is performed. Evolutionary and gradient based optimization algorithms are used. Thereby the unused strength potential of the material is exploited in order to increase the economic efficiency of

  4. Energy transfers in large-scale and small-scale dynamos

    Science.gov (United States)

    Samtaney, Ravi; Kumar, Rohit; Verma, Mahendra

    2015-11-01

    We present the energy transfers, mainly energy fluxes and shell-to-shell energy transfers in small-scale dynamo (SSD) and large-scale dynamo (LSD) using numerical simulations of MHD turbulence for Pm = 20 (SSD) and for Pm = 0.2 on 10243 grid. For SSD, we demonstrate that the magnetic energy growth is caused by nonlocal energy transfers from the large-scale or forcing-scale velocity field to small-scale magnetic field. The peak of these energy transfers move towards lower wavenumbers as dynamo evolves, which is the reason for the growth of the magnetic fields at the large scales. The energy transfers U2U (velocity to velocity) and B2B (magnetic to magnetic) are forward and local. For LSD, we show that the magnetic energy growth takes place via energy transfers from large-scale velocity field to large-scale magnetic field. We observe forward U2U and B2B energy flux, similar to SSD.

  5. Fundamental studies of energy-and hole/electron- transfer in hydroporphyrin architectures

    Energy Technology Data Exchange (ETDEWEB)

    Bocian, David F. [University of California, Riverside, CA (United States)

    2014-08-20

    The long-term objective of the Bocian/Holten/Lindsey research program is to design, synthesize, and characterize tetrapyrrole-based molecular architectures that absorb sunlight, funnel energy, and separate charge with high efficiency and in a manner compatible with current and future solar-energy conversion schemes. The synthetic tetrapyrroles include porphyrins and hydroporphyrins; the latter classes of molecules encompass analogues of the naturally occurring chlorophylls and bacteriochlorophylls (e.g., chlorins, bacteriochlorins, and their derivatives). The attainment of the goals of the research program requires the close interplay of molecular design and synthesis (Lindsey group), static and time-resolved optical spectroscopic measurements (Holten group), and electrochemical, electron paramagnetic resonance, and resonance Raman studies, as well as density functional theory calculations (Bocian Group). The proposed research encompasses four interrelated themes: (1) Determination of the rates of ground-state hole/electron transfer between (hydro)porphyrins in multipigment arrays as a function of array size, distance between components, linker type, site of linker connection, and frontier molecular orbital composition. (2) Examination of excited-state energy transfer among hydroporphyrins in multipigment arrrays, including both pairwise and non-adjacent transfer, with a chief aim to identify the relative contributions of through-space (Förster) and through-bond (Dexter) mechanisms of energy transfer, including the roles of site of linker connection and frontier molecular orbital composition. (3) Elucidation of the role of substituents in tuning the spectral and electronic properties of bacteriochlorins, with a primary aim of learning how to shift the long-wavelength absorption band deeper into the near-infrared region. (4) Continued development of the software package PhotochemCAD for spectral manipulations and calculations through the compilation of a database

  6. Effect of crack-microcracks interaction on energy release rates

    Science.gov (United States)

    Chudnovsky, A.; Wu, Shaofu

    1990-01-01

    The energy release rates associated with the main crack advancing into its surrounding damage zone, and the damage zone translation relative to the main crack, as well as the energy of interaction between the crack and the damage zone are analyzed. The displacement and stress fields for this crack-damage interaction problem are reconstructed by employing a semi-empirical stress analysis which involves experimental evaluation of the average microcrack density in the damage zone.

  7. Energy transfer dynamics from individual semiconductor nanoantennae to dye molecules with implication to light-harvesting nanosystems

    Science.gov (United States)

    Shan, Guangcun; Hu, Mingjun; Yan, Ze; Li, Xin; Huang, Wei

    2018-03-01

    Semiconductor nanocrystals can be used as nanoscale optical antennae to photoexcite individual dye molecules in an ensemble via energy transfer mechanism. The theoretical framework developed by Förster and others describes how electronic excitation migrates in the photosynthetic apparatus of plants, algae, and bacteria from light absorbing pigments to reaction centers where light energy is utilized for the eventual conversion into chemical energy. Herein we investigate the effect of the average donor-acceptor spacing on the time-resolved fluorescence intensity and dynamics of single donor-acceptor pairs with the dye acceptor concentration decreasing by using quantum Monte-Carlo simulation of FRET dynamics. Our results validated that the spatial disorder controlling the microscopic energy transfer rates accounts for the scatter in donor fluorescence lifetimes and intensities, which provides a new design guideline for artificial light-harvesting nanosystems.

  8. Design of triads for probing the direct through space energy transfers in closely spaced assemblies.

    Science.gov (United States)

    Camus, Jean-Michel; Aly, Shawkat M; Fortin, Daniel; Guilard, Roger; Harvey, Pierre D

    2013-08-05

    Using a selective stepwise Suzuki cross-coupling reaction, two trimers built on three different chromophores were prepared. These trimers exhibit a D(^)A1-A2 structure where the donor D (octa-β-alkyl zinc(II)porphyrin either as diethylhexamethyl, 10a, or tetraethyltetramethyl, 10b, derivatives) through space transfers the S1 energy to two different acceptors, di(4-ethylbenzene) zinc(II)porphyrin (A1; acceptor 1) placed cofacial with D, and the corresponding free base (A2; acceptor 2), which is meso-meso-linked with A1. This structure design allows for the possibility of comparing two series of assemblies, 9a,b (D(^)A1) with 10a,b (D(^)Â1-A2), for the evaluation of the S1 energy transfer for the global process D*→A2 in the trimers. From the comparison of the decays of the fluorescence of D, the rates for through space energy transfer, kET for 10a,b (kET ≈ 6.4 × 10(9) (10a), 5.9 × 10(9) s(-1) (10b)), and those for the corresponding cofacial D(^)A1 systems, 9a,b, (kET ≈ 5.0 × 10(9) (9a), 4.7 × 10(9) s(-1) (9b)), provide an estimate for kET for the direct through space D*→A2 process (i.e., kET(D(^)A1-A2) - kET(D(^)A1) = kET(D*→A2) ∼ 1 × 10(9) s(-1)). This channel of relaxation represents ∼15% of kET for D*→A1.

  9. Design of a variable-phase contactless energy transfer platform using air-cored planar inductor technology

    NARCIS (Netherlands)

    Sonntag, C.L.W.

    2010-01-01

    Contactless Energy Transfer (CET) describes the process in which electrical energy is transferred among two or more galvanically isolated electrical circuits or devices by means of magnetic induction (magnetic energy). The potential applications can range from the transfer of energy between low

  10. Linear energy transfer incorporated intensity modulated proton therapy optimization

    Science.gov (United States)

    Cao, Wenhua; Khabazian, Azin; Yepes, Pablo P.; Lim, Gino; Poenisch, Falk; Grosshans, David R.; Mohan, Radhe

    2018-01-01

    The purpose of this study was to investigate the feasibility of incorporating linear energy transfer (LET) into the optimization of intensity modulated proton therapy (IMPT) plans. Because increased LET correlates with increased biological effectiveness of protons, high LETs in target volumes and low LETs in critical structures and normal tissues are preferred in an IMPT plan. However, if not explicitly incorporated into the optimization criteria, different IMPT plans may yield similar physical dose distributions but greatly different LET, specifically dose-averaged LET, distributions. Conventionally, the IMPT optimization criteria (or cost function) only includes dose-based objectives in which the relative biological effectiveness (RBE) is assumed to have a constant value of 1.1. In this study, we added LET-based objectives for maximizing LET in target volumes and minimizing LET in critical structures and normal tissues. Due to the fractional programming nature of the resulting model, we used a variable reformulation approach so that the optimization process is computationally equivalent to conventional IMPT optimization. In this study, five brain tumor patients who had been treated with proton therapy at our institution were selected. Two plans were created for each patient based on the proposed LET-incorporated optimization (LETOpt) and the conventional dose-based optimization (DoseOpt). The optimized plans were compared in terms of both dose (assuming a constant RBE of 1.1 as adopted in clinical practice) and LET. Both optimization approaches were able to generate comparable dose distributions. The LET-incorporated optimization achieved not only pronounced reduction of LET values in critical organs, such as brainstem and optic chiasm, but also increased LET in target volumes, compared to the conventional dose-based optimization. However, on occasion, there was a need to tradeoff the acceptability of dose and LET distributions. Our conclusion is that the

  11. Energy transfer moments in thermalization; Les moments dei transfert d'energie en thermalisation

    Energy Technology Data Exchange (ETDEWEB)

    Soule, J L; Pillard, D [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    For all moderators of the 'incoherent gaussian' type, it is possible to calculate, at any temperature, the energy transfer moments as a function of the incident energy without having to use the differential sections. Integral formulae are derived for the integral cross-section, the first and the second moment, which make it possible to tabulate directly these three functions in a few minutes calculation on IBM 7094, for the most part models proposed in the literature for the common moderators. (authors) [French] Pour tous les moderateurs de type 'incoherent gaussien' on peut calculer, a n'importe quelle temperature, les moments de transfert d'energie en fonction de l'energie incidente, sans passer par l'intermediaire des sections differentielles. On developpe des formules integrales pour la section efficace integrale, le premier et le second moment, qui permettent de tabuler directement ces trois fonctions en quelques minutes de calcul sur IBM 7094, pour la plupart des modeles proposes dans la litterature pour les moderateurs usuels. (auteurs)

  12. Numerical analysis of the effects of radiation heat transfer and ionization energy loss on the cavitation Bubble's dynamics

    International Nuclear Information System (INIS)

    Mahdi, M.; Ebrahimi, R.; Shams, M.

    2011-01-01

    A numerical scheme for simulating the acoustic and hydrodynamic cavitation was developed. Bubble instantaneous radius was obtained using Gilmore equation which considered the compressibility of the liquid. A uniform temperature was assumed for the inside gas during the collapse. Radiation heat transfer inside the bubble and the heat conduction to the bubble was considered. The numerical code was validated with the experimental data and a good correspondence was observed. The dynamics of hydrofoil cavitation bubble were also investigated. It was concluded that the thermal radiation heat transfer rate strongly depended on the cavitation number, initial bubble radius and hydrofoil angle of attack. -- Highlights: → Heat transfer and ionization energy losses were analyzed in the cavitation bubble. → Radiation of hydrodynamic bubble was approximately equal to the black body. → Radiation heat transfer did not affect the bubble dynamic. → Conduction decreased the bubble pressure and increased the bubble temperature. → Ionization decreased the temperature and increased the pressure in the bubble.

  13. Energy Dissipation Rate in an Agitated Crucible Containing Molten Metal

    Science.gov (United States)

    Li, Tao; Shimasaki, Shin-ichi; Narita, Shunsuke; Taniguchi, Shoji

    2017-10-01

    The energy dissipation rate (EDR) is an important parameter for characterizing the behavior of inclusion coagulation in agitated molten metal. To clarify the inclusion coagulation mechanism, we review previous water model studies by particularly focusing on the relation between the impeller torque and the EDR of the fluid, which indicates the ratio of energy dissipated in the viscous medium to the energy inputted by the rotating impeller. In the present study, simulations coupled with experiments were performed to determine the relation between the torque and the effective EDR for water and liquid Al in crucibles with and without baffles.

  14. Photoinduced energy and electron transfer in rubrene-benzoquinone and rubrene-porphyrin systems

    KAUST Repository

    Khan, Jafar Iqbal

    2014-11-01

    Excited-state electron and energy transfer from singlet excited rubrene (Ru) to benzoquinone (BQ) and tetra-(4-aminophenyl) porphyrin (TAPP) were investigated by steady-state absorption and emission, time-resolved transient absorption, and femtosecond (fs)-nanosecond (ns) fluorescence spectroscopy. The low reduction potential of BQ provides the high probability of electron transfer from the excited Ru to BQ. Steady-state and time-resolved results confirm such an excited electron transfer scenario. On the other hand, strong spectral overlap between the emission of Ru and absorption of TAPP suggests that energy transfer is a possible deactivation pathway of the Ru excited state.

  15. Predicting Hydride Donor Strength via Quantum Chemical Calculations of Hydride Transfer Activation Free Energy.

    Science.gov (United States)

    Alherz, Abdulaziz; Lim, Chern-Hooi; Hynes, James T; Musgrave, Charles B

    2018-01-25

    We propose a method to approximate the kinetic properties of hydride donor species by relating the nucleophilicity (N) of a hydride to the activation free energy ΔG ⧧ of its corresponding hydride transfer reaction. N is a kinetic parameter related to the hydride transfer rate constant that quantifies a nucleophilic hydridic species' tendency to donate. Our method estimates N using quantum chemical calculations to compute ΔG ⧧ for hydride transfers from hydride donors to CO 2 in solution. A linear correlation for each class of hydrides is then established between experimentally determined N values and the computationally predicted ΔG ⧧ ; this relationship can then be used to predict nucleophilicity for different hydride donors within each class. This approach is employed to determine N for four different classes of hydride donors: two organic (carbon-based and benzimidazole-based) and two inorganic (boron and silicon) hydride classes. We argue that silicon and boron hydrides are driven by the formation of the more stable Si-O or B-O bond. In contrast, the carbon-based hydrides considered herein are driven by the stability acquired upon rearomatization, a feature making these species of particular interest, because they both exhibit catalytic behavior and can be recycled.

  16. Effective transfer entropy approach to information flow between exchange rates and stock markets

    International Nuclear Information System (INIS)

    Sensoy, Ahmet; Sobaci, Cihat; Sensoy, Sadri; Alali, Fatih

    2014-01-01

    We investigate the strength and direction of information flow between exchange rates and stock prices in several emerging countries by the novel concept of effective transfer entropy (an alternative non-linear causality measure) with symbolic encoding methodology. Analysis shows that before the 2008 crisis, only low level interaction exists between these two variables and exchange rates dominate stock prices in general. During crisis, strong bidirectional interaction arises. In the post-crisis period, the strong interaction continues to exist and in general stock prices dominate exchange rates

  17. Cross-beam energy transfer: On the accuracy of linear stationary models in the linear kinetic regime

    Science.gov (United States)

    Debayle, A.; Masson-Laborde, P.-E.; Ruyer, C.; Casanova, M.; Loiseau, P.

    2018-05-01

    We present an extensive numerical study by means of particle-in-cell simulations of the energy transfer that occurs during the crossing of two laser beams. In the linear regime, when ions are not trapped in the potential well induced by the laser interference pattern, a very good agreement is obtained with a simple linear stationary model, provided the laser intensity is sufficiently smooth. These comparisons include different plasma compositions to cover the strong and weak Landau damping regimes as well as the multispecies case. The correct evaluation of the linear Landau damping at the phase velocity imposed by the laser interference pattern is essential to estimate the energy transfer rate between the laser beams, once the stationary regime is reached. The transient evolution obtained in kinetic simulations is also analysed by means of a full analytical formula that includes 3D beam energy exchange coupled with the ion acoustic wave response. Specific attention is paid to the energy transfer when the laser presents small-scale inhomogeneities. In particular, the energy transfer is reduced when the laser inhomogeneities are comparable with the Landau damping characteristic length of the ion acoustic wave.

  18. Coherent excitation-energy transfer and quantum entanglement in a dimer

    International Nuclear Information System (INIS)

    Liao Jieqiao; Sun, C. P.; Huang Jinfeng; Kuang Leman

    2010-01-01

    We study coherent energy transfer of a single excitation and quantum entanglement in a dimer, which consists of a donor and an acceptor modeled by two two-level systems. Between the donor and the acceptor, there exists a dipole-dipole interaction, which provides the physical mechanism for coherent energy transfer and entanglement generation. The donor and the acceptor couple to two independent heat baths with diagonal couplings that do not dissipate the energy of the noncoupling dimer. Special attention is paid to the effect on single-excitation energy transfer and entanglement generation of the energy detuning between the donor and the acceptor and the temperatures of the two heat baths. It is found that, the probability for single-excitation energy transfer largely depends on the energy detuning in the low temperature limit. Concretely, the positive and negative energy detunings can increase and decrease the probability at steady state, respectively. In the high temperature limit, however, the effect of the energy detuning on the probability is negligibly small. We also find that the probability is negligibly dependent on the bath temperature difference of the two heat baths. In addition, it is found that quantum entanglement can be generated in the process of coherent energy transfer. As the bath temperature increases, the generated steady-state entanglement decreases. For a given bath temperature, the steady-state entanglement decreases with the increase of the absolute value of the energy detuning.

  19. Heat transfer

    International Nuclear Information System (INIS)

    Saad, M.A.

    1985-01-01

    Heat transfer takes place between material systems as a result of a temperature difference. The transmission process involves energy conversions governed by the first and second laws of thermodynamics. The heat transfer proceeds from a high-temperature region to a low-temperature region, and because of the finite thermal potential, there is an increase in entropy. Thermodynamics, however, is concerned with equilibrium states, which includes thermal equilibrium, irrespective of the time necessary to attain these equilibrium states. But heat transfer is a result of thermal nonequilibrium conditions, therefore, the laws of thermodynamics alone cannot describe completely the heat transfer process. In practice, most engineering problems are concerned with the rate of heat transfer rather than the quantity of heat being transferred. Resort then is directed to the particular laws governing the transfer of heat. There are three distinct modes of heat transfer: conduction, convection, and radiation. Although these modes are discussed separately, all three types may occur simultaneously

  20. Quantum transfer energy in the framework of time-dependent dipole-dipole interaction

    Science.gov (United States)

    El-Shishtawy, Reda M.; Haddon, Robert C.; Al-Heniti, Saleh H.; Raffah, Bahaaudin M.; Berrada, K.; Abdel-Khalek, S.; Al-Hadeethi, Yas F.

    2018-03-01

    In this work, we examine the process of the quantum transfer of energy considering time-dependent dipole-dipole interaction in a dimer system characterized by two-level atom systems. By taking into account the effect of the acceleration and speed of the atoms in the dimer coupling, we demonstrate that the improvement of the probability for a single-excitation transfer energy extremely benefits from the incorporation of atomic motion effectiveness and the energy detuning. We explore the relevance between the population and entanglement during the time-evolution and show that this kind of nonlocal correlation may be generated during the process of the transfer of energy. Our work may provide optimal conditions to implement realistic experimental scenario in the transfer of the quantum energy.

  1. Chirality and energy transfer amplified circularly polarized luminescence in composite nanohelix

    Science.gov (United States)

    Yang, Dong; Duan, Pengfei; Zhang, Li; Liu, Minghua

    2017-01-01

    Transfer of both chirality and energy information plays an important role in biological systems. Here we show a chiral donor π-gelator and assembled it with an achiral π-acceptor to see how chirality and energy can be transferred in a composite donor–acceptor system. It is found that the individual chiral gelator can self-assemble into nanohelix. In the presence of the achiral acceptor, the self-assembly can also proceed and lead to the formation of the composite nanohelix. In the composite nanohelix, an energy transfer is realized. Interestingly, in the composite nanohelix, the achiral acceptor can both capture the supramolecular chirality and collect the circularly polarized energy from the chiral donor, showing both supramolecular chirality and energy transfer amplified circularly polarized luminescence (ETACPL). PMID:28585538

  2. Ring current energy injection rate and solar wind-magnetosphere energy coupling

    International Nuclear Information System (INIS)

    Lee, L.C.; Kan, J.R.; Akasofu, S.-I.

    1982-01-01

    The purpose of this paper is to (i) formulate the ring current injection rate Usub(R) in terms of phisub(CT) (cross-tail potential drop) by assuming that the ring current formation is a direct consequence of an enhanced convection, (ii) examine the relationship between the injection rate Usub(R) and the power transferred from the solar wind to the magnetosphere and (iii) demonstrate that an enhanced convection indeed leads to the formation of the ring current. (author)

  3. Treatment of complex biological mixtures with pulsed electric fields An energy transfer characterization

    International Nuclear Information System (INIS)

    Schrive, Luc

    2004-01-01

    Sewage sludge from waste water treatment plants is a complex biological mixture and a problematic by-product because of valorisation restrictions. In order to limit its production, pulsed electric fields (PEF) were studied because of their biological effects and their potentially physico-chemical action. This work demonstrated a paradoxical phenomenon: cell lysis triggered a respirometric activation followed by a delayed lethality. This phenomenon was related to the leakage of internal compounds which were immediately bio-assimilated. At high energy expense, the plasmic membrane permeabilization led to cell death. Practically, with the technical configuration of the equipment, no hydrolysis was detected. This limitation decreases the interest for excess sludge reduction, but for the same reason, PEF cold sterilization technique can be assessed as a promising process. The representation of the electric energy transfer from electrodes to cell was exchanged by the study of mass transfer from the biological cell to the surrounding media under an electromotive force. Thus, the survival rate was modelled by a Sherwood number taking account of electrical, biological and hydraulic parameters. (author) [fr

  4. Generic mechanism of optimal energy transfer efficiency: a scaling theory of the mean first-passage time in exciton systems.

    Science.gov (United States)

    Wu, Jianlan; Silbey, Robert J; Cao, Jianshu

    2013-05-17

    An asymptotic scaling theory is presented using the conceptual basis of trapping-free subspace (i.e., orthogonal subspace) to establish the generic mechanism of optimal efficiency of excitation energy transfer in light-harvesting systems. A quantum state orthogonal to the trap will exhibit noise-assisted transfer, clarifying the significance of initial preparation. For such an initial state, the efficiency is enhanced in the weak damping limit (⟨t⟩ ∼ 1/Γ), and suppressed in the strong damping limit (⟨t⟩ ∼ Γ), analogous to Kramers turnover in classical rate theory. An interpolating expression ⟨t⟩ = A/Γ + B + CΓ quantitatively describes the trapping time over the entire range of the dissipation strength, and predicts the optimal efficiency at Γ(opt) ∼ J for homogenous systems. In the presence of static disorder, the scaling law of transfer time with respect to dephasing rate changes from linear to square root, suggesting a weaker dependence on the environment. The prediction of the scaling theory is verified in a symmetric dendrimer system by numerically exact quantum calculations. Though formulated in the context of excitation energy transfer, the analysis and conclusions apply in general to open quantum processes, including electron transfer, fluorescence emission, and heat conduction.

  5. Resonance Energy Transfer in Hybrid Devices in the Presence of a Surface

    DEFF Research Database (Denmark)

    Kopylov, Oleksii; Huck, Alexander; Kadkhodazadeh, Shima

    2014-01-01

    to approximately 10 nm was observed. By comparing the carrier dynamics of the quantum wells and the nanocrystals, we found that nonradiative recombination via surface states, generated during dry etching of the wafer, counteracts the nonradiative energy-transfer process to the nanocrystals and therefore decreases......We have studied room-temperature, nonradiative resonant energy transfer from InGaN/GaN quantum wells to CdSe/ZnS nanocrystals separated by aluminum oxide layers of different thicknesses. Nonradiative energy transfer from the quantum wells to the nanocrystals at separation distances of up...

  6. Spectroscopic evidence of resonance energy transfer mechanism from PbS QDs to bulk silicon

    Directory of Open Access Journals (Sweden)

    Bernechea M.

    2013-06-01

    Full Text Available In this work, we study the efficiency of the resonance energy transfer from PbS quantum dots to bulk silicon. We present spectroscopic evidence that resonance energy transfer from PbS quantum dots to bulk silicon can be an efficient process for separation distances below 12 nm. Temperature measurements are also presented for PbS quantum dots deposited on glass and silicon with 5 nm and 20nm spacer thicknesses substrates. Our findings show that the resonance energy transfer efficiency remains constant over the 50K to 300K temperature range.

  7. Charge transfer and ionization in collisions of Si3+ with H from low to high energy

    Science.gov (United States)

    Wang, J. G.; He, B.; Ning, Y.; Liu, C. L.; Yan, J.; Stancil, P. C.; Schultz, D. R.

    2006-11-01

    Charge transfer processes due to collisions of ground state Si3+(3sS1) ions with atomic hydrogen are investigated using the quantum-mechanical molecular-orbital close-coupling (MOCC) and classical-trajectory Monte Carlo (CTMC) methods. The MOCC calculations utilize ab initio adiabatic potentials and nonadiabatic radial coupling matrix elements obtained from Herrero [J. Phys. B 29, 5583 (1996)] which were calculated with a full configuration-interaction method. Total and state-selective single-electron capture cross sections are obtained for collision energies from 0.01eV/u to 1MeV/u . Total and state-selective rate coefficients are also presented for temperatures from 2×103K to 107K . Comparison with existing data reveals that the total CTMC cross sections are in good agreement with the experimental measurements at the higher considered energies and that previous Landau-Zener calculations underestimate the total rate coefficients by a factor of up to two. The CTMC calculations of target ionization are presented for high energies.

  8. Charge transfer and ionization in collisions of Si3+ with H from low to high energy

    International Nuclear Information System (INIS)

    Wang, J. G.; He, B.; Ning, Y.; Liu, C. L.; Yan, J.; Stancil, P. C.; Schultz, D. R.

    2006-01-01

    Charge transfer processes due to collisions of ground state Si 3+ (3s 1 S) ions with atomic hydrogen are investigated using the quantum-mechanical molecular-orbital close-coupling (MOCC) and classical-trajectory Monte Carlo (CTMC) methods. The MOCC calculations utilize ab initio adiabatic potentials and nonadiabatic radial coupling matrix elements obtained from Herrero et al. [J. Phys. B 29, 5583 (1996)] which were calculated with a full configuration-interaction method. Total and state-selective single-electron capture cross sections are obtained for collision energies from 0.01 eV/u to 1 MeV/u. Total and state-selective rate coefficients are also presented for temperatures from 2x10 3 K to 10 7 K. Comparison with existing data reveals that the total CTMC cross sections are in good agreement with the experimental measurements at the higher considered energies and that previous Landau-Zener calculations underestimate the total rate coefficients by a factor of up to two. The CTMC calculations of target ionization are presented for high energies

  9. The impact of fiscal transfer on energy efficiency in Indonesia

    NARCIS (Netherlands)

    Syaifudin, N.; Sutrisno, A.; Setiawan, A.D.

    2015-01-01

    Conference and Exhibition Indonesia - New, Renewable Energy and Energy Conservation (The 3rd Indo-EBTKE ConEx 2014) IRSA-Indonesia 5, a bottom-up CGE model, was employed to analyze the impacts of fiscal support to the sub-national region to implement energy efficiency policy. By implementing several

  10. Active transfer of poloidal magnetic energy during plasma disruptions in J-TEXT

    International Nuclear Information System (INIS)

    Zhang, Ming; Zhang, Jun; Rao, Bo; Chen, Zhongyong; Li, Xiaolong; Xu, Wendi; Pan, Yuan; Yu, Kexun

    2016-01-01

    Highlights: • An alternative plasma disruption mitigation method by transferring partial poloidal magnetic energy out of the vacuum vessel has been presented in this paper. • This method can reduced the magnetic energy dissipated inside the vacuum vessel during disruption and mitigated the disruption damage. • This method has been experimentally verified in J-TEXT with an experiment system set up. • According to the experimental results, the magnetic energy dissipated inside the vacuum vessel during disruption can be reduced by 20% or more and the loop voltage can be reduced by 58%. - Abstract: The magnitude of the damaging effects of plasma disruptions on vacuum vessel (VV) components increases with the thermal energy and poloidal magnetic energy dissipated inside the VV. This study focuses on an alternative method, by which partial poloidal magnetic energy is transferred out of the VV. The quantity of the poloidal magnetic energy dissipated inside the VV (W_d_i_s) can be reduced with this method, and the damaging effects can be mitigated. Partial magnetic energy is transferred based on magnetic coupling by a group of energy transfer coils (ETCs) that are coupled with the plasma current. This method, which is called magnetic energy transfer (MET), has been experimentally verified in J-TEXT. W_d_i_s can be reduced by approximately 20%, and the loop voltage can be reduced by 58%. MET is established as a novel, promising, and effective plasma disruption mitigation method.

  11. Quasiclassical trajectory study of the energy transfer in CO2--rare gas systems

    International Nuclear Information System (INIS)

    Suzukawa, H.H. Jr.; Wolfsberg, M.; Thompson, D.L.

    1978-01-01

    Computational methods are presented for the study of collisions between a linear, symmetric triatomic molecule and an atom by three-dimensional quasiclassical trajectory calculations. Application is made to the investigation of translational to rotational and translational to vibrational energy transfer in the systems CO 2 --Kr, CO 2 --Ar, and CO 2 --Ne. Potential-energy surfaces based on spectroscopic and molecular beam scattering data are used. In most of the calculations, the CO 2 molecule is initially in the quantum mechanical zero-point vibrational state and in a rotational state picked from a Boltzmann distribution at 300 0 K. The energy transfer processes are investigated for translational energies ranging from 0.1 to 10 eV. Translational to rotational energy transfer is found to be the major process for CO 2 --rare gas collisions at these energies. Below 1 eV there is very little translational to vibrational energy transfer. The effects of changes in the internal energy of the molecule, in the masses of the collidants, and in the potential-energy parameters are studied in an attempt to gain understanding of the energy transfer processes

  12. Is free knowledge transfer history in the energy sector?

    International Nuclear Information System (INIS)

    Zewald, H.

    2000-01-01

    The European power industry is gradually changing from a government-controlled sector of monopolists to an internationally privatized free sector. Companies that used to cooperate are now competing with one another. The question is: can the international knowledge transfer institutes escape from this competitive climate or will they fall victim to it?

  13. High-data-transfer-rate read heads composed of spin-torque oscillators

    International Nuclear Information System (INIS)

    Mizushima, K; Kudo, K; Nagasawa, T; Sato, R

    2011-01-01

    The signal-to-noise ratios (SNRs) of the high-data-transfer-rate read heads beyond 3 Gbits/s composed of spin-torque oscillators (STOs) are calculated under the thermal magnetization fluctuations by using the recent nonlinear theories. The STO head senses the media field as a modulation in the oscillation frequency, enabling high signal transfer rates beyond the limit of ferromagnetic relaxation. The output (digital) signal is obtained by FM (frequency modulation) detection, which is commonly used in communication technologies. As the problem of rapid phase diffusion in STOs caused by the thermal fluctuations is overcome by employing a delay detection method, the sufficiently large SNRs are obtained even in nonlinear STOs less than 30 x 30 nm 2 in size.

  14. Energy transfer and thermal studies of Pr 3+ doped cerium oxalate ...

    Indian Academy of Sciences (India)

    The analysis of energy level diagrams of cerium and praseodymium ions indicates that the energy gap between the sensitizer and the activator ions varies in a small range suggesting a possible energy transfer from the Ce3+ to Pr3+. The emission and absorption spectra of these crystals were recorded. The overlapping of ...

  15. Operational and Strategic Implementation of Dynamic Line Rating for Optimized Wind Energy Generation Integration

    International Nuclear Information System (INIS)

    Gentle, Jake Paul

    2016-01-01

    One primary goal of rendering today's transmission grid 'smarter' is to optimize and better manage its power transfer capacity in real time. Power transfer capacity is affected by three main elements: stability, voltage limits, and thermal ratings. All three are critical, but thermal ratings represent the greatest opportunity to quickly, reliably and economically utilize the grid's true capacity. With the 'Smarter Grid', new solutions have been sought to give operators a better grasp on real time conditions, allowing them to manage and extend the usefulness of existing transmission infrastructure in a safe and reliable manner. The objective of the INL Wind Program is to provide industry a Dynamic Line Rating (DLR) solution that is state of the art as measured by cost, accuracy and dependability, to enable human operators to make informed decisions and take appropriate actions without human or system overloading and impacting the reliability of the grid. In addition to mitigating transmission line congestion to better integrate wind, DLR also offers the opportunity to improve the grid with optimized utilization of transmission lines to relieve congestion in general. As wind-generated energy has become a bigger part of the nation's energy portfolio, researchers have learned that wind not only turns turbine blades to generate electricity, but can cool transmission lines and increase transfer capabilities significantly, sometimes up to 60 percent. INL's DLR development supports EERE and The Wind Energy Technology Office's goals by informing system planners and grid operators of available transmission capacity, beyond typical Static Line Ratings (SLR). SLRs are based on a fixed set of conservative environmental conditions to establish a limit on the amount of current lines can safely carry without overheating. Using commercially available weather monitors mounted on industry informed custom brackets developed by INL in combination with Computational Fluid Dynamics (CFD

  16. Standard Test Method for Measuring Heat Transfer Rate Using a Thin-Skin Calorimeter

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2005-01-01

    1.1 This test method covers the design and use of a thin metallic calorimeter for measuring heat transfer rate (also called heat flux). Thermocouples are attached to the unexposed surface of the calorimeter. A one-dimensional heat flow analysis is used for calculating the heat transfer rate from the temperature measurements. Applications include aerodynamic heating, laser and radiation power measurements, and fire safety testing. 1.2 Advantages 1.2.1 Simplicity of ConstructionThe calorimeter may be constructed from a number of materials. The size and shape can often be made to match the actual application. Thermocouples may be attached to the metal by spot, electron beam, or laser welding. 1.2.2 Heat transfer rate distributions may be obtained if metals with low thermal conductivity, such as some stainless steels, are used. 1.2.3 The calorimeters can be fabricated with smooth surfaces, without insulators or plugs and the attendant temperature discontinuities, to provide more realistic flow conditions for ...

  17. Tungsten Trioxide/Zinc Tungstate Bilayers: Electrochromic Behaviors, Energy Storage and Electron Transfer

    International Nuclear Information System (INIS)

    Wei, Huige; Ding, Daowei; Yan, Xingru; Guo, Jiang; Shao, Lu; Chen, Haoran; Sun, Luyi; Colorado, Henry A.; Wei, Suying; Guo, Zhanhu

    2014-01-01

    Highlights: • Tungsten oxide and zinc tungstate bilayers have been prepared via a facile sol-gel method for integrated applications of electrochromic behaviors and energy storage;. • Electron transfer behaviors between the semiconductor bilayer films have been found dependent on the bilayer assembly sequence;. • Methylene blue (MB) has been employed for the first time as an indicator to study the electron transfer phenomenon in the bilayer films. - Abstract: Pair-sequentially spin-coated tungsten trioxide (WO 3 ) and zinc tungstate (ZnWO 4 ) bilayer films onto indium tin oxide (ITO) coated glass slides have been prepared via sol-gel methods followed by annealing. The bilayers (ZnWO 4 /WO 3 denoting the bilayer film with the inner layer of ZnWO 4 and the outer layer of WO 3 on the ITO while WO 3 /ZnWO 4 standing for the bilayer film with the inner layer of WO 3 and the outer layer of ZnWO 4 on the ITO) exhibit integrated functions of electrochromic and energy storage behaviors as indicated by the in situ spectroelectrochemistry and cyclic voltammetry (CV) results. Accordingly, blue color was observed for the bilayer films at -1 V in 0.5 M H 2 SO 4 solution. An areal capacitance of 140 and 230 μF/cm 2 was obtained for the ZnWO 4 /WO 3 , and WO 3 /ZnWO 4 film, respectively, at a scan rate of 0.05 V/s in the CV measurements. The CV results also unveiled the electron transfer behavior between the semiconductor films in the oxidation process, suggesting a sequence-dependent electrochemical response in the bilayer films. Meanwhile, methylene blue (MB) was used as an indicator to study the electron transfer phenomenon during the reduction process at negative potentials of -0.4 and -0.8 V, in 0.5 M Na 2 SO 4 . The results indicated that the electrons transfer across the bilayers was enhanced at more negative potentials

  18. Quantifying the Interactions between Maternal and Fetal Heart Rates by Transfer Entropy.

    Directory of Open Access Journals (Sweden)

    Faezeh Marzbanrad

    Full Text Available Evidence of the short term relationship between maternal and fetal heart rates has been found in previous studies. However there is still limited knowledge about underlying mechanisms and patterns of the coupling throughout gestation. In this study, Transfer Entropy (TE was used to quantify directed interactions between maternal and fetal heart rates at various time delays and gestational ages. Experimental results using maternal and fetal electrocardiograms showed significant coupling for 63 out of 65 fetuses, by statistically validating against surrogate pairs. Analysis of TE showed a decrease in transfer of information from fetus to the mother with gestational age, alongside the maturation of the fetus. On the other hand, maternal to fetal TE was significantly greater in mid (26-31 weeks and late (32-41 weeks gestation compared to early (16-25 weeks gestation (Mann Whitney Wilcoxon (MWW p<0.05. TE further increased from mid to late, for the fetuses with RMSSD of fetal heart rate being larger than 4 msec in the late gestation. This difference was not observed for the fetuses with smaller RMSSD, which could be associated with the quiet sleep state. Delay in the information transfer from mother to fetus significantly decreased (p = 0.03 from mid to late gestation, implying a decrease in fetal response time. These changes occur concomitant with the maturation of the fetal sensory and autonomic nervous systems with advancing gestational age. The effect of maternal respiratory rate derived from maternal ECG was also investigated and no significant relationship was found between breathing rate and TE at any lag. In conclusion, the application of TE with delays revealed detailed information on the fetal-maternal heart rate coupling strength and latency throughout gestation, which could provide novel clinical markers of fetal development and well-being.

  19. ENERGY RELEASE AND TRANSFER IN SOLAR FLARES: SIMULATIONS OF THREE-DIMENSIONAL RECONNECTION

    International Nuclear Information System (INIS)

    Birn, J.; Fletcher, L.; Hesse, M.; Neukirch, T.

    2009-01-01

    Using three-dimensional magnetohydrodynamic simulations we investigate energy release and transfer in a three-dimensional extension of the standard two-ribbon flare picture. In this scenario, reconnection is initiated in a thin current sheet (suggested to form below a departing coronal mass ejection) above a bipolar magnetic field. Two cases are contrasted: an initially force-free current sheet (low beta) and a finite-pressure current sheet (high beta), where beta represents the ratio between gas (plasma) and magnetic pressure. The energy conversion process from reconnection consists of incoming Poynting flux turned into up- and downgoing Poynting flux, enthalpy flux, and bulk kinetic energy flux. In the low-beta case, the outgoing Poynting flux is the dominant contribution, whereas the outgoing enthalpy flux dominates in the high-beta case. The bulk kinetic energy flux is only a minor contribution in the downward direction. The dominance of the downgoing Poynting flux in the low-beta case is consistent with an alternative to the thick target electron beam model for solar flare energy transport, suggested recently by Fletcher and Hudson, whereas the enthalpy flux may act as an alternative transport mechanism. For plausible characteristic parameters of the reconnecting field configuration, we obtain energy release timescales and energy output rates that compare favorably with those inferred from observations for the impulsive phase of flares. Significant enthalpy flux and heating are found even in the initially force-free case with very small background beta, resulting mostly from adiabatic compression rather than Ohmic dissipation. The energy conversion mechanism is most easily understood as a two-step process (although the two steps may occur essentially simultaneously): the first step is the acceleration of the plasma by Lorentz forces in layers akin to the slow shocks in the Petschek reconnection model, involving the conversion of magnetic energy to bulk kinetic

  20. Thermodynamic chemical energy transfer mechanisms of non-equilibrium, quasi-equilibrium, and equilibrium chemical reactions

    International Nuclear Information System (INIS)

    Roh, Heui-Seol

    2015-01-01

    Chemical energy transfer mechanisms at finite temperature are explored by a chemical energy transfer theory which is capable of investigating various chemical mechanisms of non-equilibrium, quasi-equilibrium, and equilibrium. Gibbs energy fluxes are obtained as a function of chemical potential, time, and displacement. Diffusion, convection, internal convection, and internal equilibrium chemical energy fluxes are demonstrated. The theory reveals that there are chemical energy flux gaps and broken discrete symmetries at the activation chemical potential, time, and displacement. The statistical, thermodynamic theory is the unification of diffusion and internal convection chemical reactions which reduces to the non-equilibrium generalization beyond the quasi-equilibrium theories of migration and diffusion processes. The relationship between kinetic theories of chemical and electrochemical reactions is also explored. The theory is applied to explore non-equilibrium chemical reactions as an illustration. Three variable separation constants indicate particle number constants and play key roles in describing the distinct chemical reaction mechanisms. The kinetics of chemical energy transfer accounts for the four control mechanisms of chemical reactions such as activation, concentration, transition, and film chemical reactions. - Highlights: • Chemical energy transfer theory is proposed for non-, quasi-, and equilibrium. • Gibbs energy fluxes are expressed by chemical potential, time, and displacement. • Relationship between chemical and electrochemical reactions is discussed. • Theory is applied to explore nonequilibrium energy transfer in chemical reactions. • Kinetics of non-equilibrium chemical reactions shows the four control mechanisms

  1. Visible Light Photocatalysis of [2+2] Styrene Cycloadditions via Energy Transfer

    Science.gov (United States)

    Lu, Zhan; Yoon, Tehshik P.

    2012-01-01

    Hip to be square: Styrenes participate in [2+2] cycloadditions upon irradiation with visible light in the presence of an iridium(III) polypyridyl complex. In contrast to previous reports of visible light photoredox catalysis, the mechanism of this process involves photosensitization by energy transfer and not electron transfer. PMID:22965321

  2. Morphological Change and Decreasing Transfer Rate of Biofilm-Featured Listeria monocytogenes EGDe.

    Science.gov (United States)

    Lee, Yuejia; Wang, Chinling

    2017-03-01

    Listeria monocytogenes , a lethal foodborne pathogen, has the ability to resist the hostile food processing environment and thus frequently contaminates ready-to-eat foods during processing. It is commonly accepted that the tendency of L. monocytogenes ' to generate biofilms on various surfaces enhances its resistance to the harshness of the food processing environment. However, the role of biofilm formation in the transferability of L. monocytogenes EGDe remains controversial. We examined the growth of Listeria biofilms on stainless steel surfaces and their effect on the transferability of L. monocytogenes EGDe. The experiments were a factorial 2 × 2 design with at least three biological replicates. Through scanning electron microscopy, a mature biofilm with intensive aggregates of cells was observed on the surface of stainless steel after 3 or 5 days of incubation, depending on the initial level of inoculation. During biofilm development, L. monocytogenes EGDe carried out binary fission vigorously before a mature biofilm was formed and subsequently changed its cellular morphology from rod shaped to sphere shaped. Furthermore, static biofilm, which was formed after 3 days of incubation at 25°C, significantly inhibited the transfer rate of L. monocytogenes EGDe from stainless steel blades to 15 bologna slices. During 7 days of storage at 4°C, however, bacterial growth rate was not significantly impacted by whether bacteria were transferred from biofilm and the initial concentrations of transferred bacteria on the slice. In conclusion, this study is the first to report a distinct change in morphology of L. monocytogenes EGDe at the late stage of biofilm formation. More importantly, once food is contaminated by L. monocytogenes EGDe, contamination proceeds independently of biofilm development and the initial level of contamination when food is stored at 4°C, even if contamination with L. monocytogenes EGDe was initially undetectable before storage.

  3. Transfer Rates of Enteric Microorganisms in Recycled Water during Machine Clothes Washing▿

    Science.gov (United States)

    O'Toole, Joanne; Sinclair, Martha; Leder, Karin

    2009-01-01

    Approximately 15% of overall Australian household water usage is in the laundry; hence, a significant reduction in household drinking water demand could be achieved if potable-quality water used for clothes washing is replaced with recycled water. To investigate the microbiological safety of using recycled water in washing machines, bacteriophages MS-2 and PRD-1, Escherichia coli, and Cryptosporidium parvum oocysts were used in a series of experiments to investigate the transfer efficiency of enteric microorganisms from washing machine water to objects including hands, environmental surfaces, air, and fabric swatches. By determining the transference efficiency, it is possible to estimate the numbers of microorganisms that the user will be exposed to if recycled water with various levels of residual microorganisms is used in washing machines. Results, expressed as transfer rates to a given surface area per object, showed that the mean transfer efficiency of E. coli, bacteriophages MS-2 and PRD-1, and C. parvum oocysts from seeded water to fabric swatches ranged from 0.001% to 0.090%. Greatest exposure to microorganisms occurred through direct contact of hands with seeded water and via hand contact with contaminated fabric swatches. No microorganisms were detected in the air samples during the washing machine spin cycle, and transfer rates of bacteriophages from water to environmental surfaces were 100-fold less than from water directly to hands. Findings from this study provide relevant information that can be used to refine regulations governing recycled water and to allay public concerns about the use of recycled water. PMID:19124592

  4. Evaporation rates and surface profiles on heterogeneous surfaces with mass transfer and surface reaction

    Energy Technology Data Exchange (ETDEWEB)

    Flytzani-Stephanopoulos, M; Schmidt, L D

    1979-01-01

    Simple models incorporating surface reaction and diffusion of volatile products through a boundary layer are developed to calculate effective rates of evaporation and local surface profiles on surfaces having active and inactive regions. The coupling between surface heterogeneities with respect to a particular reaction and external mass transfer may provide a mechanism for the surface rearrangement and metal loss encountered in several catalytic systems of practical interest. Calculated transport rates for the volatilization of platinum in oxidizing environments and the rearrangement of this metal during the ammonia oxidation reaction agree well with published experimental data.

  5. Information transfer with rate-modulated Poisson processes: a simple model for nonstationary stochastic resonance.

    Science.gov (United States)

    Goychuk, I

    2001-08-01

    Stochastic resonance in a simple model of information transfer is studied for sensory neurons and ensembles of ion channels. An exact expression for the information gain is obtained for the Poisson process with the signal-modulated spiking rate. This result allows one to generalize the conventional stochastic resonance (SR) problem (with periodic input signal) to the arbitrary signals of finite duration (nonstationary SR). Moreover, in the case of a periodic signal, the rate of information gain is compared with the conventional signal-to-noise ratio. The paper establishes the general nonequivalence between both measures notwithstanding their apparent similarity in the limit of weak signals.

  6. SCEPTIC, Pressure Drop, Flow Rate, Heat Transfer, Temperature in Reactor Heat Exchanger

    International Nuclear Information System (INIS)

    Kattchee, N.; Reynolds, W.C.

    1975-01-01

    1 - Nature of physical problem solved: SCEPTIC is a program for calculating pressure drop, flow rates, heat transfer rates, and temperature in heat exchangers such as fuel elements of typical gas or liquid cooled nuclear reactors. The effects of turbulent and heat interchange between flow passages are considered. 2 - Method of solution: The computation procedure amounts to a nodal of lumped parameter type of calculation. The axial mesh size is automatically selected to assure that a prescribed accuracy of results is obtained. 3 - Restrictions on the complexity of the problem: Maximum number of subchannels is 25, maximum number of heated surfaces is 46

  7. Dose rate constant and energy spectrum of interstitial brachytherapy sources

    International Nuclear Information System (INIS)

    Chen Zhe; Nath, Ravinder

    2001-01-01

    In the past two years, several new manufacturers have begun to market low-energy interstitial brachytherapy seeds containing 125 I and 103 Pd. Parallel to this development, the National Institute of Standards and Technology (NIST) has implemented a modification to the air-kerma strength (S K ) standard for 125 I seeds and has also established an S K standard for 103 Pd seeds. These events have generated a considerable number of investigations on the determination of the dose rate constants (Λ) of interstitial brachytherapy seeds. The aim of this work is to study the general properties underlying the determination of Λ and to develop a simple method for a quick and accurate estimation of Λ. As the dose rate constant of clinical seeds is defined at a fixed reference point, we postulated that Λ may be calculated by treating the seed as an effective point source when the seed's source strength is specified in S K and its source characteristics are specified by the photon energy spectrum measured in air at the reference point. Using a semi-analytic approach, an analytic expression for Λ was derived for point sources with known photon energy spectra. This approach enabled a systematic study of Λ as a function of energy. Using the measured energy spectra, the calculated Λ for 125 I model 6711 and 6702 seeds and for 192 Ir seed agreed with the AAPM recommended values within ±1%. For the 103 Pd model 200 seed, the agreement was 5% with a recently measured value (within the ±7% experimental uncertainty) and was within 1% with the Monte Carlo simulations. The analytic expression for Λ proposed here can be evaluated using a programmable calculator or a simple spreadsheet and it provides an efficient method for checking the measured dose rate constant for any interstitial brachytherapy seed once the energy spectrum of the seed is known

  8. Microbial catabolic activities are naturally selected by metabolic energy harvest rate.

    Science.gov (United States)

    González-Cabaleiro, Rebeca; Ofiţeru, Irina D; Lema, Juan M; Rodríguez, Jorge

    2015-12-01

    The fundamental trade-off between yield and rate of energy harvest per unit of substrate has been largely discussed as a main characteristic for microbial established cooperation or competition. In this study, this point is addressed by developing a generalized model that simulates competition between existing and not experimentally reported microbial catabolic activities defined only based on well-known biochemical pathways. No specific microbial physiological adaptations are considered, growth yield is calculated coupled to catabolism energetics and a common maximum biomass-specific catabolism rate (expressed as electron transfer rate) is assumed for all microbial groups. Under this approach, successful microbial metabolisms are predicted in line with experimental observations under the hypothesis of maximum energy harvest rate. Two microbial ecosystems, typically found in wastewater treatment plants, are simulated, namely: (i) the anaerobic fermentation of glucose and (ii) the oxidation and reduction of nitrogen under aerobic autotrophic (nitrification) and anoxic heterotrophic and autotrophic (denitrification) conditions. The experimentally observed cross feeding in glucose fermentation, through multiple intermediate fermentation pathways, towards ultimately methane and carbon dioxide is predicted. Analogously, two-stage nitrification (by ammonium and nitrite oxidizers) is predicted as prevailing over nitrification in one stage. Conversely, denitrification is predicted in one stage (by denitrifiers) as well as anammox (anaerobic ammonium oxidation). The model results suggest that these observations are a direct consequence of the different energy yields per electron transferred at the different steps of the pathways. Overall, our results theoretically support the hypothesis that successful microbial catabolic activities are selected by an overall maximum energy harvest rate.

  9. Energy transfer in the major intrinsic light-harvesting complex from Amphidinium carterae

    Czech Academy of Sciences Publication Activity Database

    Polívka, Tomáš; van Stokkum, I.H.M.; Zigmantas, D.; van Grondelle, R.; Sundström, V.; Hiller, R.G.

    2006-01-01

    Roč. 45, - (2006), s. 8516-8526 ISSN 0006-2960 Institutional research plan: CEZ:AV0Z50510513 Keywords : Energy transfer * Amphidinium carterae Subject RIV: CE - Biochemistry Impact factor: 3.633, year: 2006

  10. Energy transfer in the major intrinsic light-harvesting complex from Amphidinium carterae

    Czech Academy of Sciences Publication Activity Database

    Polívka, Tomáš; van Stokkum, I.H.M.; Zigmantas, D.; van Grondelle, R.; Sundström, V.; Hiller, R.G.

    2006-01-01

    Roč. 45, č. 28 (2006), s. 8516-8526 ISSN 0006-2960 Institutional research plan: CEZ:AV0Z50510513 Keywords : carotenoids * Energy transfer Subject RIV: CE - Biochemistry Impact factor: 3.633, year: 2006

  11. Energy transfer in isolated LHC II studied by femtosecond pump-probe technique

    CERN Document Server

    Yang Yi; Liu Yuan; Liu Wei Min; Zhu Rong Yi; Qian Shi Xiong; Xu Chun He

    2003-01-01

    Excitation energy transfer in the isolated light-harvesting chlorophyll (Chl)-a/b protein complex of photosystem II (LHC II) was studied by the one-colour pump-probe technique with femtosecond time resolution. After exciting Chl-b by 638nm beam, the dynamic behaviour shows that the ultrafast energy transfer from Chl-b at positions of B2, B3, and B5 to the corresponding Chl-a molecules in monomeric subunit of LHC II is in the time scale of 230fs. While with the excitation of Chl-a at 678nm, the energy transfer between excitons of Chl-a molecules has the lifetime of about 370 fs, and two other slow decay components are due to the energy transfer between different Chl-a molecules in a monomeric subunit of LHC II or in different subunits, or due to change of molecular conformation. (20 refs).

  12. Ultrafast Dynamics of Dansylated POPAM Dendrimers and Energy Transfer in their Dye Complexes

    Science.gov (United States)

    Aumanen, J.; Kesti, T.; Sundström, V.; Vögtle, F.; Korppi-Tommola, J.

    We have studied internal dynamics of dansylated poly(propyleneamine) dendrimers of different generations in solution and excitation energy transfer from dansyl chromophores to xanthene dyes that form van der Waals complexes with the dendrimers

  13. Optogalvanic monitoring of collisional transfer of laser excitation energy in a neon RF plasma

    International Nuclear Information System (INIS)

    Armstrong, T.D.

    1994-01-01

    The optogalvanic signals produced by pulsed laser excitation of 1s5--2p8 and 1s5-2p9 (Paschen notation) transition by a ∼29 MHz radiofrequency (rf) discharge at ∼5 torr have been investigated. The optogalvanic signal produced by 1s5-2p9 excitations indicates that there is transfer of energy from the 2p9 state to some other state. The state to which this energy is transferred is believed to be mainly the 2p8 state because of the very small energy gap between the 2p9 and 2p8 states. To verify this transfer, the 1s5-2p8 transition was investigated. The similarity of the temporal profiles of the optogalvanic signals in both excitations confirms the collisional transfer of laser excitation energy from 2p9 to 2p8

  14. Inhibition of crossed-beam energy transfer induced by expansion-velocity fluctuations

    Science.gov (United States)

    Neuville, C.; Glize, K.; Loiseau, P.; Masson-Laborde, P.-E.; Debayle, A.; Casanova, M.; Baccou, C.; Labaune, C.; Depierreux, S.

    2018-04-01

    Crossed-beam energy transfer between three laser beams has been experimentally investigated in a flowing plasma. Time-evolution measurements of the amplification of a first beam by a second beam highlighted the inhibition of energy transfer by hydrodynamic modifications of the plasma in the crossing volume due to the propagation of a third beam. According to 3D simulations and an analytical model, it appears that the long-wavelength expansion-velocity fluctuations produced by the propagation of the third beam in the crossing volume are responsible for this mitigation of energy transfer. This effect could be a cause of the over-estimation of the amount of the transferred energy in indirect-drive inertial confinement fusion experiments. Besides, tuning such long-wavelength fluctuations could be a way to completely inhibit CBET at the laser entrance holes of hohlraums.

  15. Review of existing residential energy efficiency certification and rating programs

    Energy Technology Data Exchange (ETDEWEB)

    Hendrickson, P.L.

    1986-11-01

    This report was prepared for the Office of Buildings and Community Systems, US Department of Energy (DOE). The principal objective of the report is to present information on existing Home Energy Rating Systems (HERS) and their features. Much of the information in this report updates a 1982 report (PNL-4359), also prepared by the Pacific Northwest Laboratory (PNL) for DOE. Secondary objectives of the report are to qualitatively examine the benefits and costs of HERS programs, review survey results on the attitudes of various user groups toward the programs, and discuss selected design and implementation issues.

  16. [Fluorescence Resonance Energy Transfer Detection of Cobalt Ions by Silver Triangular Nanoplates and Rhodamine 6G].

    Science.gov (United States)

    Zhang, Xiu-qing; Peng, Jun; Ling, Jian; Liu, Chao-juan; Cao, Qiu-e; Ding, Zhong-tao

    2015-04-01

    In the present paper, the authors studied fluorescence resonance energy transfer (FRET) phenomenon between silver triangular nanoplates and bovine serum albumin (BSA)/Rhodamine 6G fluorescence complex, and established a fluorescence method for the detection of cobalt ions. We found that when increasing the silver triangular nanoplates added to certain concentrations of fluorescent bovine serum albumin (BSA)/Rhodamine 6G complex, the fluorescence of Rhodamine 6G would be quenched up to 80% due to the FRET between the quencher and donor. However, in the presence of cobalt ions, the disassociation of the fluorescent complex from silver triangular nanoplates occurred and the fluorescence of the Rhodamine 6G recovered. The recovery of fluorescence intensity rate (I/I0) has a good relationship with the cobalt ion concentration (cCO2+) added. Thus, the authors developed a fluorescence method for the detection of cobalt ions based on the FRET of silver triangular nanoplates and Rhodamine 6G.

  17. Ab initio study of charge transfer in B2+ low-energy collisions with atomic hydrogen

    Science.gov (United States)

    Turner, A. R.; Cooper, D. L.; Wang, J. G.; Stancil, P. C.

    2003-07-01

    Charge transfer processes due to collisions of ground state B2+(2s 2S) ions with atomic hydrogen are investigated using the quantum-mechanical molecular-orbital close-coupling (MOCC) method. The MOCC calculations utilize ab initio adiabatic potentials and nonadiabatic radial and rotational coupling matrix elements obtained with the spin-coupled valence-bond approach. Total and state-selective cross sections and rate coefficients are presented. Comparison with the existing experiments shows our results to be in good agreement. When EMOCC cross sections with and without rotational coupling are small (400 eV/u, inclusion of rotational coupling increases the total cross section by 50% 80%, improving the agreement between the current calculations and experiments. For state-selective cross sections, rotational coupling induces mixing between different symmetries; however, its effect, especially at low collision energies, is not as important as had been suggested in previous work.

  18. Ab initio study of charge transfer in B2+ low-energy collisions with atomic hydrogen

    International Nuclear Information System (INIS)

    Turner, A.R.; Cooper, D.L.; Wang, J.G.; Stancil, P.C.

    2003-01-01

    Charge transfer processes due to collisions of ground state B 2+ (2s 2 S) ions with atomic hydrogen are investigated using the quantum-mechanical molecular-orbital close-coupling (MOCC) method. The MOCC calculations utilize ab initio adiabatic potentials and nonadiabatic radial and rotational coupling matrix elements obtained with the spin-coupled valence-bond approach. Total and state-selective cross sections and rate coefficients are presented. Comparison with the existing experiments shows our results to be in good agreement. When E 400 eV/u, inclusion of rotational coupling increases the total cross section by 50%-80%, improving the agreement between the current calculations and experiments. For state-selective cross sections, rotational coupling induces mixing between different symmetries; however, its effect, especially at low collision energies, is not as important as had been suggested in previous work

  19. Determination of pesticide residue transfer rates (percent) from dried tea leaves to brewed tea.

    Science.gov (United States)

    Wang, Jian; Cheung, Wendy; Leung, Daniel

    2014-01-29

    This paper presents a study on pesticide residue transfer rates (%) from dried tea leaves to brewed tea. In the study, a brewing procedure simulated the preparation of a hot tea drink as in routine. After brewing, pesticide residues were extracted from brewed tea using a method known as QuEChERS (quick, easy, cheap, effective, rugged, and safe). An UHPLC/ESI-MS/MS method was developed and validated to identify and quantify up to 172 pesticides in both tea leaves and brewed tea samples. Quantification was achieved using matrix-matched standard calibration curves with isotopically labeled standards or a chemical analogue as internal standards, and the calibration curves consisted of six points (0.4, 2.0, 8.0, 16.0, 24.0, and 40.0 μg/L equivalent in sample). The method was validated at four concentration levels (4.0, 12, 20.0, and 32.0 μg/L equivalent in sample) using five different brewed tea matrices on two separate days per matrix. Method performance parameters included overall recovery, intermediate precision, and measurement uncertainty, which were evaluated according to a nested experimental design. Approximately, 95% of the pesticides studied had recoveries between 81 and 110%, intermediate precision ≤20%, and measurement uncertainty ≤40%. From a pilot study of 44 incurred tea samples, pesticide residues were examined for their ability to transfer from dried tea leaves to brewed tea. Each sample, both tea leaves and brewed tea, was analyzed in duplicate. Pesticides were found to have different transfer rates (%). For example, imidacloprid, methomyl, and carbendazim had transfer rates of 84.9, 83.4, and 92.4%, respectively.

  20. Charge transfer through single molecule contacts: How reliable are rate descriptions?

    Directory of Open Access Journals (Sweden)

    Denis Kast

    2011-08-01

    Full Text Available Background: The trend for the fabrication of electrical circuits with nanoscale dimensions has led to impressive progress in the field of molecular electronics in the last decade. However, a theoretical description of molecular contacts as the building blocks of future devices is challenging, as it has to combine the properties of Fermi liquids in the leads with charge and phonon degrees of freedom on the molecule. Outside of ab initio schemes for specific set-ups, generic models reveal the characteristics of transport processes. Particularly appealing are descriptions based on transfer rates successfully used in other contexts such as mesoscopic physics and intramolecular electron transfer. However, a detailed analysis of this scheme in comparison with numerically exact solutions is still elusive.Results: We show that a formulation in terms of transfer rates provides a quantitatively accurate description even in domains of parameter space where strictly it is expected to fail, e.g., at lower temperatures. Typically, intramolecular phonons are distributed according to a voltage driven steady state that can only roughly be captured by a thermal distribution with an effective elevated temperature (heating. An extension of a master equation for the charge–phonon complex, to effectively include the impact of off-diagonal elements of the reduced density matrix, provides very accurate solutions even for stronger electron–phonon coupling.Conclusion: Rate descriptions and master equations offer a versatile model to describe and understand charge transfer processes through molecular junctions. Such methods are computationally orders of magnitude less expensive than elaborate numerical simulations that, however, provide exact solutions as benchmarks. Adjustable parameters obtained, e.g., from ab initio calculations allow for the treatment of various realizations. Even though not as rigorously formulated as, e.g., nonequilibrium Green’s function

  1. Quantifying the Interactions between Maternal and Fetal Heart Rates by Transfer Entropy

    Science.gov (United States)

    Marzbanrad, Faezeh; Kimura, Yoshitaka; Palaniswami, Marimuthu; Khandoker, Ahsan H.

    2015-01-01

    Evidence of the short term relationship between maternal and fetal heart rates has been found in previous studies. However there is still limited knowledge about underlying mechanisms and patterns of the coupling throughout gestation. In this study, Transfer Entropy (TE) was used to quantify directed interactions between maternal and fetal heart rates at various time delays and gestational ages. Experimental results using maternal and fetal electrocardiograms showed significant coupling for 63 out of 65 fetuses, by statistically validating against surrogate pairs. Analysis of TE showed a decrease in transfer of information from fetus to the mother with gestational age, alongside the maturation of the fetus. On the other hand, maternal to fetal TE was significantly greater in mid (26–31 weeks) and late (32–41 weeks) gestation compared to early (16–25 weeks) gestation (Mann Whitney Wilcoxon (MWW) pgestation. This difference was not observed for the fetuses with smaller RMSSD, which could be associated with the quiet sleep state. Delay in the information transfer from mother to fetus significantly decreased (p = 0.03) from mid to late gestation, implying a decrease in fetal response time. These changes occur concomitant with the maturation of the fetal sensory and autonomic nervous systems with advancing gestational age. The effect of maternal respiratory rate derived from maternal ECG was also investigated and no significant relationship was found between breathing rate and TE at any lag. In conclusion, the application of TE with delays revealed detailed information on the fetal-maternal heart rate coupling strength and latency throughout gestation, which could provide novel clinical markers of fetal development and well-being. PMID:26701122

  2. Argonne National Laboratory energy storage and transfer experimental program

    International Nuclear Information System (INIS)

    Kustom, R.L.; Wehrle, R.B.; Smith, R.P.; Fuja, R.E.

    1978-01-01

    Magnetic fusion reactor, equilibrium field, and ohmic heating (OH) coils require the coil energy to be cycled in relatively short periods of time. For large fusion reactor systems, the energy can be in the thousands of MJ range. These large amounts of energy cannot be removed from or returned to the power grid without having an adverse effect on the grid. Several schemes have been proposed which can minimize the amount of energy required from the power grid over a fusion-reactor cycle. They include the flying capacitor, the inductor-convertor bridge, the homopolar generator, and the motor-generator flywheel (MGF). The MGF is best understood and has been in use for this purpose for many years. It requires the least amount of development. The other schemes have not been applied to the energy buffering problem and require considerable development. Of the three remaining schemes, the homopolar generator and the inductor-convertor bridge seem to be the most desirable

  3. Energy Link Optimization in a Wireless Power Transfer Grid under Energy Autonomy Based on the Improved Genetic Algorithm

    Directory of Open Access Journals (Sweden)

    Zhihao Zhao

    2016-08-01

    Full Text Available In this paper, an optimization method is proposed for the energy link in a wireless power transfer grid, which is a regional smart microgrid comprised of distributed devices equipped with wireless power transfer technology in a certain area. The relevant optimization model of the energy link is established by considering the wireless power transfer characteristics and the grid characteristics brought in by the device repeaters. Then, a concentration adaptive genetic algorithm (CAGA is proposed to optimize the energy link. The algorithm avoided the unification trend by introducing the concentration mechanism and a new crossover method named forward order crossover, as well as the adaptive parameter mechanism, which are utilized together to keep the diversity of the optimization solution groups. The results show that CAGA is feasible and competitive for the energy link optimization in different situations. This proposed algorithm performs better than its counterparts in the global convergence ability and the algorithm robustness.

  4. Nonradiative inter- and intramolecular energy transfer from the aromatic donor anisole to a synthesized photoswitchable acceptor system.

    Science.gov (United States)

    Bardhan, Munmun; Bhattacharya, Sudeshna; Misra, Tapas; Mukhopadhyay, Rupa; De, Asish; Chowdhury, Joydeep; Ganguly, Tapan

    2010-02-01

    We report steady state and time resolved fluorescence measurements on acetonitrile (ACN) solutions of the model compounds, energy donor anisole (A) and a photoswitchable acceptor N,N'-1,2-phenylene di-p-tosylamide (B) and the multichromophore (M) where A and B are connected by a spacer containing both rigid triple (acetylenic) and flexible methylene bonds. Both steady state and time correlated single photon counting measurements demonstrate that though intermolecular energy transfer, of Forster type, between the donor and acceptor moieties occurs with rate 10(8)s(-1) but when these two reacting components are linked by a spacer (multichromophore, M) the observed transfer rate ( approximately 10(11)s(-1)) enhances. This seemingly indicates that the imposition of the spacer by inserting a triple bond may facilitate in the propagation of electronic excitation energy through bond. The time resolved fluorescence measurements along with the theoretical predictions using Configuration interaction singles (CIS) method by using 6-31G (d,p) basis set, implemented in the Gaussian package indicate the formations of the two excited conformers of B. The experimental findings made from the steady state and time resolved fluorescence measurements demonstrate that, though two different isomeric species of the acceptor B are formed in the excited singlet states, the prevailing singlet-singlet nonradiative energy transfer route was found from the donor A to the relatively longer-lived isomeric species of B. Copyright (c) 2009 Elsevier B.V. All rights reserved.

  5. Modeling of MeV alpha particle energy transfer to lower hybrid waves

    International Nuclear Information System (INIS)

    Schivell, J.; Monticello, D.A.; Fisch, N.; Rax, J.M.

    1993-10-01

    The interaction between a lower hybrid wave and a fusion alpha particle displaces the alpha particle simultaneously in space and energy. This results in coupled diffusion. Diffusion of alphas down the density gradient could lead to their transferring energy to the wave. This could, in turn, put energy into current drive. An initial analytic study was done by Fisch and Rax. Here the authors calculate numerical solutions for the alpha energy transfer and study a range of conditions that are favorable for wave amplification from alpha energy. They find that it is possible for fusion alpha particles to transfer a large fraction of their energy to the lower hybrid wave. The numerical calculation shows that the net energy transfer is not sensitive to the value of the diffusion coefficient over a wide range of practical values. An extension of this idea, the use of a lossy boundary to enhance the energy transfer, is investigated. This technique is shown to offer a large potential benefit

  6. Energy transfer between a nanosystem and its host fluid: A multiscale factorization approach

    Science.gov (United States)

    Sereda, Yuriy V.; Espinosa-Duran, John M.; Ortoleva, Peter J.

    2014-02-01

    Energy transfer between a macromolecule or supramolecular assembly and a host medium is considered from the perspective of Newton's equations and Lie-Trotter factorization. The development starts by demonstrating that the energy of the molecule evolves slowly relative to the time scale of atomic collisions-vibrations. The energy is envisioned to be a coarse-grained variable that coevolves with the rapidly fluctuating atomistic degrees of freedom. Lie-Trotter factorization is shown to be a natural framework for expressing this coevolution. A mathematical formalism and workflow for efficient multiscale simulation of energy transfer is presented. Lactoferrin and human papilloma virus capsid-like structure are used for validation.

  7. Energy transfer between a nanosystem and its host fluid: A multiscale factorization approach

    International Nuclear Information System (INIS)

    Sereda, Yuriy V.; Espinosa-Duran, John M.; Ortoleva, Peter J.

    2014-01-01

    Energy transfer between a macromolecule or supramolecular assembly and a host medium is considered from the perspective of Newton's equations and Lie-Trotter factorization. The development starts by demonstrating that the energy of the molecule evolves slowly relative to the time scale of atomic collisions-vibrations. The energy is envisioned to be a coarse-grained variable that coevolves with the rapidly fluctuating atomistic degrees of freedom. Lie-Trotter factorization is shown to be a natural framework for expressing this coevolution. A mathematical formalism and workflow for efficient multiscale simulation of energy transfer is presented. Lactoferrin and human papilloma virus capsid-like structure are used for validation

  8. HVDC interrupter experiments for large Magnetic Energy Transfer and Storage (METS) systems

    International Nuclear Information System (INIS)

    Swannack, C.E.; Haarman, R.A.; Lindsay, J.D.G.; Weldon, D.M.

    1975-01-01

    Proposed fusion-test reactors will require energy storage systems of hundreds of megajoules with transfer times of the order of one millisecond. The size of the energy storage submodule (and hence, the overall system cost and complexity) is directly determined by the voltage and current limits of the switch used for the energy transfer. Experiments are being conducted on high voltage dc circuit breakers as a major part of the energy storage, pulsed power program. DC circuit interruption characteristics of a commercially available ac power vacuum interrupter are discussed. Preliminary data of interruption characteristics are reported for an interrupter developed specifically to match a present METS circuit requirement

  9. Neutrino energy loss rate in a stellar plasma

    International Nuclear Information System (INIS)

    Esposito, S.; Mangano, G.; Miele, G.; Picardi, I.; Pisanti, O.

    2003-01-01

    We review the purely leptonic neutrino emission processes, contributing to the energy loss rate of the stellar plasma. We perform a complete analysis up to the first order in the electromagnetic coupling constant. In particular the radiative electromagnetic corrections, at order α, to the process e + e - →νν-bar at finite density and temperature have been computed. This process gives one of the main contributions to the cooling of stellar interior in the late stages of star evolution. As a result of the analysis we find that the corrections affect the energy loss rate, computed at tree level, by a factor (-4-1)% in the temperature and density region where the pair annihilation is the most efficient cooling mechanism

  10. Fault on-off versus strain rate and earthquakes energy

    Directory of Open Access Journals (Sweden)

    C. Doglioni

    2015-03-01

    Full Text Available We propose that the brittle-ductile transition (BDT controls the seismic cycle. In particular, the movements detected by space geodesy record the steady state deformation in the ductile lower crust, whereas the stick-slip behavior of the brittle upper crust is constrained by its larger friction. GPS data allow analyzing the strain rate along active plate boundaries. In all tectonic settings, we propose that earthquakes primarily occur along active fault segments characterized by relative minima of strain rate, segments which are locked or slowly creeping. We discuss regional examples where large earthquakes happened in areas of relative low strain rate. Regardless the tectonic style, the interseismic stress and strain pattern inverts during the coseismic stage. Where a dilated band formed during the interseismic stage, this will be shortened at the coseismic stage, and vice-versa what was previously shortened, it will be dilated. The interseismic energy accumulation and the coseismic expenditure rather depend on the tectonic setting (extensional, contractional, or strike-slip. The gravitational potential energy dominates along normal faults, whereas the elastic energy prevails for thrust earthquakes and performs work against the gravity force. The energy budget in strike-slip tectonic setting is also primarily due elastic energy. Therefore, precursors may be different as a function of the tectonic setting. In this model, with a given displacement, the magnitude of an earthquake results from the coseismic slip of the deformed volume above the BDT rather than only on the fault length, and it also depends on the fault kinematics.

  11. Growth rate in the dynamical dark energy models

    International Nuclear Information System (INIS)

    Avsajanishvili, Olga; Arkhipova, Natalia A.; Samushia, Lado; Kahniashvili, Tina

    2014-01-01

    Dark energy models with a slowly rolling cosmological scalar field provide a popular alternative to the standard, time-independent cosmological constant model. We study the simultaneous evolution of background expansion and growth in the scalar field model with the Ratra-Peebles self-interaction potential. We use recent measurements of the linear growth rate and the baryon acoustic oscillation peak positions to constrain the model parameter α that describes the steepness of the scalar field potential. (orig.)

  12. Growth rate in the dynamical dark energy models.

    Science.gov (United States)

    Avsajanishvili, Olga; Arkhipova, Natalia A; Samushia, Lado; Kahniashvili, Tina

    Dark energy models with a slowly rolling cosmological scalar field provide a popular alternative to the standard, time-independent cosmological constant model. We study the simultaneous evolution of background expansion and growth in the scalar field model with the Ratra-Peebles self-interaction potential. We use recent measurements of the linear growth rate and the baryon acoustic oscillation peak positions to constrain the model parameter [Formula: see text] that describes the steepness of the scalar field potential.

  13. Influence of mass transfer resistance on overall nitrate removal rate in upflow sludge bed reactors.

    Science.gov (United States)

    Ting, Wen-Huei; Huang, Ju-Sheng

    2006-09-01

    A kinetic model with intrinsic reaction kinetics and a simplified model with apparent reaction kinetics for denitrification in upflow sludge bed (USB) reactors were proposed. USB-reactor performance data with and without sludge wasting were also obtained for model verification. An independent batch study showed that the apparent kinetic constants k' did not differ from the intrinsic k but the apparent Ks' was significantly larger than the intrinsic Ks suggesting that the intra-granule mass transfer resistance can be modeled by changes in Ks. Calculations of the overall effectiveness factor, Thiele modulus, and Biot number combined with parametric sensitivity analysis showed that the influence of internal mass transfer resistance on the overall nitrate removal rate in USB reactors is more significant than the external mass transfer resistance. The simulated residual nitrate concentrations using the simplified model were in good agreement with the experimental data; the simulated results using the simplified model were also close to those using the kinetic model. Accordingly, the simplified model adequately described the overall nitrate removal rate and can be used for process design.

  14. The effect of air bubble position after blastocyst transfer on pregnancy rates in IVF cycles.

    Science.gov (United States)

    Friedman, Brooke E; Lathi, Ruth B; Henne, Melinda B; Fisher, Stephanie L; Milki, Amin A

    2011-03-01

    To investigate the relationship between air bubble position after blastocyst transfer (BT) and pregnancy rates (PRs). Retrospective cohort study. University-based infertility center. Three hundred fifteen consecutive nondonor BTs by a single provider. Catheters were loaded with 25 μL of culture media, 20 μL of air, 25 μL of media containing the blastocysts, 20 μL of air, and a small amount of additional media. The distance from the air bubble to the fundus, as seen on abdominal ultrasound examination, was measured at the time of transfer. Air bubble location was categorized as 20 mm from the fundus. Clinical pregnancy rate. After controlling for age, parity, FSH and frozen transfers, and accounting for repeated cycles per patient, the PRs for both the >20-mm (38.3%) and the 10-20-mm (42.0%) from the fundus group were significantly reduced compared with the group in which the bubble was Reproductive Medicine. Published by Elsevier Inc. All rights reserved.

  15. New aspects of high energy heavy-ion transfer reactions

    International Nuclear Information System (INIS)

    Scott, D.K.

    1975-03-01

    New aspects of heavy ion reactions at incident energies in the region of 10 MeV/nucleon are discussed with an emphasis on the peripheral nature of the collisions, which leads to simplicities in the differential cross sections. The distortion of the peripheral distribution through the interference of direct and multistep processes is used to illustrate aspects of high energy reactions unique to heavy ions. The simplicities of the distributions for reactions on lighter nuclei are exploited to give new information about nuclear structure from direct and compound reactions at high energy. (16 figures, 32 references) (U.S.)

  16. Proton-proton reaction rates at extreme energies

    International Nuclear Information System (INIS)

    Nagano, Motohiko

    1993-01-01

    Results on proton-antiproton reaction rates (total cross-section) at collision energies of 1.8 TeV from experiments at Fermilab have suggested a lower rate of increase with energy compared to the extrapolation based on results previously obtained at CERN's proton-antiproton collider (CERN Courier, October 1991). Now an independent estimate of the values for the proton-proton total cross-section for collision energies from 5 to 30 TeV has been provided by the analysis of cosmic ray shower data collected over ten years at the Akeno Observatory operated by the Institute for Cosmic Ray Research of University of Tokyo. These results are based on the inelastic cross-section for collisions of cosmic ray protons with air nuclei at energies in the range10 16-18 eV. A new extensive air shower experiment was started at Akeno, 150 km west of Tokyo, in 1979 with a large array of detectors, both on the ground and under a 1-metre concrete absorber. This measured the total numbers of electrons and muons of energies above 1GeV for individual showers with much better accuracy than before. Data collection was almost continuous for ten years without any change in the triggering criteria for showers above10 16 eV. The mean free path for proton-air nuclei collisions has been determined from the zenith angle of the observed frequency of air showers which have the same effective path length for development in the atmosphere and the same primary energy

  17. General theory of excitation energy transfer in donor-mediator-acceptor systems.

    Science.gov (United States)

    Kimura, Akihiro

    2009-04-21

    General theory of the excitation energy transfer (EET) in the case of donor-mediator-acceptor system was constructed by using generalized master equation (GME). In this theory, we consider the direct and indirect transitions in the EET consistently. Hence, our theory includes the quantum mechanical interference between the direct and indirect transitions automatically. Memory functions in the GME were expressed by the overlap integrals among the time-dependent emission spectrum of the donor, the absorption spectrum of the mediator, the time-dependent emission spectrum of the mediator, and the absorption spectrum of the acceptor. In the Markov limit of the memory functions, we obtained the rate of EET which consists of three terms due to the direct transition, the indirect transition, and the interference between them. We found that the interference works effectively in the limit of slow thermalization at the intermediate state. The formula of EET rate in this limit was expressed by the convolution of the EET interaction and optical spectra. The interference effect strongly depends on the width of the absorption spectrum of mediator molecule and the energy gap between the donor and the mediator molecules.

  18. Dynamic bounds for power and efficiency of non-ideal energy converters under nonlinear transfer laws

    International Nuclear Information System (INIS)

    Sieniutycz, Stanislaw

    2009-01-01

    We present a thermodynamic approach to simulation and modeling of nonlinear energy converters, in particular radiation engines. Novel results are obtained especially for dynamical engines when the temperature of the propelling medium decreases in time due to a continual decrease of the medium's internal energy caused by the power production. Basic thermodynamic principles determine the converter's efficiency and work limits in terms of the entropy production. The real work is a cumulative effect obtained in a system of a resource fluid, a sequence of engines, and an infinite bath. Nonlinear modeling involves dynamic optimization in which the classical expression for efficiency at maximum power is generalized to endoirreversible machines and nonlinear transfer laws. The primary result is a finite-rate generalization of the classical, reversible work potential (exergy). The generalized work function depends on thermal coordinates and a dissipation index, h, i.e. a Hamiltonian of the minimum entropy production problem. This generalized work function implies stronger bounds on work delivered or supplied than the reversible work potential. The role of the nonlinear analyses and dynamic optimization is shown especially for radiation engines. As an example of the kinetic work limit, generalized exergy of radiation fluid is estimated in terms of finite rates, quantified by the Hamiltonian h

  19. Numerical simulations of energy transfer in two collisionless interpenetrating plasmas

    Directory of Open Access Journals (Sweden)

    Davis S.

    2013-11-01

    Full Text Available Ion stream instabilities are essential for collisionless shock formation as seen in astrophysics. Weakly relativistic shocks are considered as candidates for sources of high energy cosmic rays. Laboratory experiments may provide a better understanding of this phenomenon. High intensity short pulse laser systems are opening possibilities for efficient ion acceleration to high energies. Their collision with a secondary target could be used for collisionless shock formation. In this paper, using particle-in-cell simulations we are studying interaction of a sub-relativistic, laser created proton beam with a secondary gas target. We show that the ion bunch initiates strong electron heating accompanied by the Weibel-like filamentation and ion energy losses. The energy repartition between ions, electrons and magnetic fields are investigated. This yields insight on the processes occurring in the interstellar medium (ISM and gamma-ray burst afterglows.

  20. Heat transfer efficient thermal energy storage for steam generation

    International Nuclear Information System (INIS)

    Adinberg, R.; Zvegilsky, D.; Epstein, M.

    2010-01-01

    A novel reflux heat transfer storage (RHTS) concept for producing high-temperature superheated steam in the temperature range 350-400 deg. C was developed and tested. The thermal storage medium is a metallic substance, Zinc-Tin alloy, which serves as the phase change material (PCM). A high-temperature heat transfer fluid (HTF) is added to the storage medium in order to enhance heat exchange within the storage system, which comprises PCM units and the associated heat exchangers serving for charging and discharging the storage. The applied heat transfer mechanism is based on the HTF reflux created by a combined evaporation-condensation process. It was shown that a PCM with a fraction of 70 wt.% Zn in the alloy (Zn70Sn30) is optimal to attain a storage temperature of 370 deg. C, provided the heat source such as solar-produced steam or solar-heated synthetic oil has a temperature of about 400 deg. C (typical for the parabolic troughs technology). This PCM melts gradually between temperatures 200 and 370 deg. C preserving the latent heat of fusion, mainly of the Zn-component, that later, at the stage of heat discharge, will be available for producing steam. The thermal storage concept was experimentally studied using a lab scale apparatus that enabled investigating of storage materials (the PCM-HTF system) simultaneously with carrying out thermal performance measurements and observing heat transfer effects occurring in the system. The tests produced satisfactory results in terms of thermal stability and compatibility of the utilized storage materials, alloy Zn70Sn30 and the eutectic mixture of biphenyl and diphenyl oxide, up to a working temperature of 400 deg. C. Optional schemes for integrating the developed thermal storage into a solar thermal electric plant are discussed and evaluated considering a pilot scale solar plant with thermal power output of 12 MW. The storage should enable uninterrupted operation of solar thermal electric systems during additional hours

  1. Experimental Study of RF Energy Transfer System in Indoor Environment

    International Nuclear Information System (INIS)

    Adami, S-E; Proynov, P P; Stark, B H; Hilton, G S; Craddock, I J

    2014-01-01

    This paper presents a multi-transmitter, 2.43 GHz Radio-Frequency (RF) wireless power transfer (WPT) system for powering on-body devices. It is shown that under typical indoor conditions, the received power range spans several orders of magnitude from microwatts to milliwatts. A body-worn dual-polarised rectenna (rectifying antenna) is presented, designed for situations where the dominant polarization is unpredictable, as is the case for the on-body sensors. Power management circuitry is demonstrated that optimally loads the rectenna even under highly intermittent conditions, and boosts the voltage to charge an on-board storage capacitor

  2. Experimental Study of RF Energy Transfer System in Indoor Environment

    Science.gov (United States)

    Adami, S.-E.; Proynov, P. P.; Stark, B. H.; Hilton, G. S.; Craddock, I. J.

    2014-11-01

    This paper presents a multi-transmitter, 2.43 GHz Radio-Frequency (RF) wireless power transfer (WPT) system for powering on-body devices. It is shown that under typical indoor conditions, the received power range spans several orders of magnitude from microwatts to milliwatts. A body-worn dual-polarised rectenna (rectifying antenna) is presented, designed for situations where the dominant polarization is unpredictable, as is the case for the on-body sensors. Power management circuitry is demonstrated that optimally loads the rectenna even under highly intermittent conditions, and boosts the voltage to charge an on-board storage capacitor.

  3. Statistical error of spin transfer to hyperon at RHIC energy

    International Nuclear Information System (INIS)

    Han Ran; Mao Yajun

    2009-01-01

    From the RHIC/PHENIX experiment data, it is found that the statistical error of spin transfer is few times larger than the statistical error of the single spin asymmetry. In order to verify the difference between σDLL and σAL, the linear least squares method was used to check it first, and then a simple Monte-Carlo simulation to test this factor again. The simulation is consistent with the calculation result which indicates that the few times difference is reasonable. (authors)

  4. The role of the concentration scale in the definition of transfer free energies.

    Science.gov (United States)

    Moeser, Beate; Horinek, Dominik

    2015-01-01

    The Gibbs free energy of transferring a solute at infinite dilution between two solvents quantifies differences in solute-solvent interactions - if the transfer takes place at constant molarity of the solute. Yet, many calculation formulae and measuring instructions that are commonly used to quantify solute-solvent interactions correspond to transfer processes in which not the molarity of the solute but its concentration measured in another concentration scale is constant. Here, we demonstrate that in this case, not only the change in solute-solvent interactions is quantified but also the entropic effect of a volume change during the transfer. Consequently, the "phenomenon" which is known as "concentration-scale dependence" of transfer free energies is simply explained by a volume-entropy effect. Our explanations are of high importance for the study of cosolvent effects on protein stability. Copyright © 2014 Elsevier B.V. All rights reserved.

  5. Observation of the one- to six-neutron transfer reactions at sub-barrier energies

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, C.L.; Rehm, K.E.; Gehring, J. [and others

    1995-08-01

    It was suggested many years ago that when two heavy nuclei are in contact during a grazing collision, the transfer of several correlated neutron-pairs could occur. Despite considerable experimental effort, however, so far only cross sections for up to four-neutron transfers have been uniquely identified. The main difficulties in the study of multi-neutron transfer reactions are the small cross sections encountered at incident energies close to the barrier, and various experimental uncertainties which can complicate the analysis of these reactions. We have for the first time found evidence for multi-neutron transfer reactions covering the full sequence from one- to six-neutron transfer reactions at sub-barrier energies in the system {sup 58}Ni + {sup 100}Mo.

  6. Evaluation of the effect of indomethacin and piroxicam administration before embryo transfer on pregnancy rate.

    Science.gov (United States)

    Kumbasar, Serkan; Gül, Özer; Şık, Aytek

    2017-03-01

    The aim of this study was to evaluate the effect of non-steroidal anti-inflammatory drug (NSAID) administration before embryo transfer (ET) on pregnancy rates in women undergoing in vitro fertilization/intracytoplasmic sperm injection ET. Our study included 255 patients diagnosed with primary or secondary infertility caused by a male or tubal-related factor, endometriosis or unexplained factors. The patients were divided randomly into three groups. Two groups were administered oral piroxicam (10 mg capsules) or 100 mg indomethacin (rectal suppository), respectively, 1-2 h before ET. As a control, the third group did not receive any form of treatment before ET. Basal levels of follicle-stimulating hormone, luteinizing hormone, and level 17β-estradiol on the day of human chorionic gonadotropin administration, the collected and transferred number of embryos, and the number of grade A embryos obtained were determined in all patients. The implantation, clinical pregnancy, and miscarriage rates of the groups were compared. The clinical pregnancy rate per ET and the implantation rate were 35.2% and 12.15% in the piroxicam group, 31.7% and 10.9% in the indomethacin group, and 32.9% and 12.5% in the control, respectively. The miscarriage rates of groups 1, 2 and 3 were 12%, 11.7% and 11.7%, respectively (P = 0.964). The differences in clinical pregnancy rates among the groups were not statistically significant (P = 0.887). There were also no significant differences in the implantation rates (P = 0.842). These results suggest that NSAID administration before ET has no additional effect on pregnancy outcome in patients undergoing in vitro fertilization. © 2017 Japan Society of Obstetrics and Gynecology.

  7. Observations of turbulent energy dissipation rate in the upper ocean of the central South China Sea

    Science.gov (United States)

    Chen, G.

    2016-02-01

    Measurements of turbulent energy dissipation rate, velocity, temperature, and salinity were obtained in the upper ocean of the central South China Sea (14.5˚N, 117.0˚E) during an experimental campaign from May 11th to 13th 2010. Dissipation rate was elevated ( 10-7 Wkg-1) at night by convection mixing and was weakened ( 10-9 Wkg-1) in daytime due to the warming stratification. Thermocline dissipation rate varied with time ( 10-9 Wkg-1 to 10-8 Wkg-1) under the influence of internal waves. Energy was transferred from the diurnal internal tides to high frequency internal waves through nonlinear wave-wave interactions. This energy cascade process was accompanied by elevated shear and enhanced dissipation, which played an important role in the turbulent mixing in thermocline. Compare with the thermocline dissipation, dissipation below the thermocline was more stable and weak ( 10-10 Wkg-1). The observed dissipation rate during the measurement was well parameterized by the MacKinnon-Gregg parameterization (a model based on a reinterpretation of wave-wave interaction theory), whereas the Gregg-Henyey parameterization was not in good agreement with the observed dissipation rate.

  8. Fluorescence resonance energy transfer between conjugated molecules infiltrated in three-dimensional opal photonic crystals

    International Nuclear Information System (INIS)

    Zou, Lu; Sui, Ning; Wang, Ying-Hui; Qian, Cheng; Ma, Yu-Guang; Zhang, Han-Zhuang

    2015-01-01

    Fluorescence resonance energy transfer (FRET) from Coumarin 6 (C-6) to Sulforhodamine B (S-B) infiltrated into opal PMMA (poly-methyl-methacrylate) photonic crystals (PCs) has been studied in detail. The intrinsic mesh micro-porous structure of opal PCs could increase the luminescent efficiency through inhibiting the intermolecular interaction. Meanwhile, its structure of periodically varying refractive indices could also modify the FRET through affecting the luminescence characteristics of energy donor or energy acceptor. The results demonstrate that the FRET efficiency between conjugated dyes was easily modified by opal PCs. - Highlights: • We investigate the fluorescence resonance energy transfer between two kinds of dyes. • These two kinds of dyes are infiltrated in PMMA opal photonic crystals. • The structure of opal PCs could improve the luminescent characteristics. • The structure of opal PCs could improve the energy transfer characteristics

  9. A general real-time formulation for multi-rate mass transfer problems

    Directory of Open Access Journals (Sweden)

    O. Silva

    2009-08-01

    Full Text Available Many flow and transport phenomena, ranging from delayed storage in pumping tests to tailing in river or aquifer tracer breakthrough curves or slow kinetics in reactive transport, display non-equilibrium (NE behavior. These phenomena are usually modeled by non-local in time formulations, such as multi-porosity, multiple processes non equilibrium, continuous time random walk, memory functions, integro-differential equations, fractional derivatives or multi-rate mass transfer (MRMT, among others. We present a MRMT formulation that can be used to represent all these models of non equilibrium. The formulation can be extended to non-linear phenomena. Here, we develop an algorithm for linear mass transfer, which is accurate, computationally inexpensive and easy to implement in existing groundwater or river flow and transport codes. We illustrate this approach by application to published data involving NE groundwater flow and solute transport in rivers and aquifers.

  10. Determination of Erosion/Corrosion Rates in Hanford Tank Farms Radioactive Waste Transfer System Pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Washenfelder, D. J.; Girardot, C. L.; Wilson, E. R.; Page, J. A.; Engeman, J. K.; Gunter, J. R.; Johnson, J. M.; Baide, D. G.; Cooke, G. A.; Larson, J. D.; Castleberry, J. L.; Boomer, K. D.

    2015-11-05

    The twenty-eight double-shell underground radioactive waste storage tanks at the U. S. Department of Energy’s Hanford Site near Richland, WA are interconnected by the Waste Transfer System network of buried steel encased pipelines and pipe jumpers in below-grade pits. The pipeline material is stainless steel or carbon steel in 51 mm to 152 mm (2 in. to 6 in.) sizes. The pipelines carry slurries ranging up to 20 volume percent solids and supernatants with less than one volume percent solids at velocities necessary to prevent settling. The pipelines, installed between 1976 and 2011, were originally intended to last until the 2028 completion of the double-shell tank storage mission. The mission has been subsequently extended. In 2010 the Tank Operating Contractor began a systematic evaluation of the Waste Transfer System pipeline conditions applying guidelines from API 579-1/ASME FFS-1 (2007), Fitness-For-Service. Between 2010 and 2014 Fitness-for-Service examinations of the Waste Transfer System pipeline materials, sizes, and components were completed. In parallel, waste throughput histories were prepared allowing side-by-side pipeline wall thinning rate comparisons between carbon and stainless steel, slurries and supernatants and throughput volumes. The work showed that for transfer volumes up to 6.1E+05 m3 (161 million gallons), the highest throughput of any pipeline segment examined, there has been no detectable wall thinning in either stainless or carbon steel pipeline material regardless of waste fluid characteristics or throughput. The paper describes the field and laboratory evaluation methods used for the Fitness-for-Service examinations, the results of the examinations, and the data reduction methodologies used to support Hanford Waste Transfer System pipeline wall thinning conclusions.

  11. [Specific growth rate and the rate of energy metabolism in the ontogenesis of axolotl, Ambystoma mexicanum (Amphibia: Ambystomatidae)].

    Science.gov (United States)

    Vladimirova, I G; Kleĭmenov, S Iu; Alekseeva, T A; Radzinskaia, L I

    2003-01-01

    Concordant changes in the rate of energy metabolism and specific growth rate of axolotls have been revealed. Several periods of ontogeny are distinguished, which differ in the ratio of energy metabolism to body weight and, therefore, are described by different allometric equations. It is suggested that the specific growth rate of an animal determines the type of dependence of energy metabolism on body weight.

  12. Mid-range adiabatic wireless energy transfer via a mediator coil

    International Nuclear Information System (INIS)

    Rangelov, A.A.; Vitanov, N.V.

    2012-01-01

    A technique for efficient mid-range wireless energy transfer between two coils via a mediator coil is proposed. By varying the coil frequencies, three resonances are created: emitter–mediator (EM), mediator–receiver (MR) and emitter–receiver (ER). If the frequency sweeps are adiabatic and such that the EM resonance precedes the MR resonance, the energy flows sequentially along the chain emitter–mediator–receiver. If the MR resonance precedes the EM resonance, then the energy flows directly from the emitter to the receiver via the ER resonance; then the losses from the mediator are suppressed. This technique is robust against noise, resonant constraints and external interferences. - Highlights: ► Efficient and robust mid-range wireless energy transfer via a mediator coil. ► The adiabatic energy transfer is analogous to adiabatic passage in quantum optics. ► Wireless energy transfer is insensitive to any resonant constraints. ► Wireless energy transfer is insensitive to noise in the neighborhood of the coils.

  13. Collisions involving energy transfer between atoms with large angular moments

    International Nuclear Information System (INIS)

    Vdovin, Yu.A.; Galitskij, V.M.

    1975-01-01

    Study is made of the collisions of excited and nonexcited atoms with a small resonance defect, assuming that the excited and ground states of each atom are bound via an allowed dipole transition and that intrinsic moments of states are great. In such an approximation the atomic interaction is defined by a dipole-dipole interaction operator. Equations for amplitudes are derived for two cases: (1) the first atom is in an excited state while the second is in the ground state and (2) the first atom is in the ground state while the second is in an excited state. The problem is solved in the approximation that the moments of the excited and ground states of each atom are equal. An expression for the excitation transfer cross section is written down. Analysis of this expression shows that the excitation transfer cross section at first increases with removal from the exact resonance and reaches resonance at lambda approximately 0.1 (lambda is a dimensionless parameter which is equal to the ratio of the resonance defect Δ to the interaction at spacings of the order of the Weisskopf radius). Only at lambda >0.16 does the cross section become smaller than the resonance one. This effect is due to the interaction Hamiltonian approximation adopted in the present study

  14. The rate of second electron transfer to QB(-) in bacterial reaction center of impaired proton delivery shows hydrogen-isotope effect.

    Science.gov (United States)

    Maróti, Ágnes; Wraight, Colin A; Maróti, Péter

    2015-02-01

    The 2nd electron transfer in reaction center of photosynthetic bacterium Rhodobacter sphaeroides is a two step process in which protonation of QB(-) precedes interquinone electron transfer. The thermal activation and pH dependence of the overall rate constants of different RC variants were measured and compared in solvents of water (H2O) and heavy water (D2O). The electron transfer variants where the electron transfer is rate limiting (wild type and M17DN, L210DN and H173EQ mutants) do not show solvent isotope effect and the significant decrease of the rate constant of the second electron transfer in these mutants is due to lowering the operational pKa of QB(-)/QBH: 4.5 (native), 3.9 (L210DN), 3.7 (M17DN) and 3.1 (H173EQ) at pH7. On the other hand, the proton transfer variants where the proton transfer is rate limiting demonstrate solvent isotope effect of pH-independent moderate magnitude (2.11±0.26 (WT+Ni(2+)), 2.16±0.35 (WT+Cd(2+)) and 2.34±0.44 (L210DN/M17DN)) or pH-dependent large magnitude (5.7 at pH4 (L213DN)). Upon deuteration, the free energy and the enthalpy of activation increase in all proton transfer variants by about 1 kcal/mol and the entropy of activation becomes negligible in L210DN/M17DN mutant. The results are interpreted as manifestation of equilibrium and kinetic solvent isotope effects and the structural, energetic and kinetic possibility of alternate proton delivery pathways are discussed. Copyright © 2014 Elsevier B.V. All rights reserved.

  15. Crossed-beam energy transfer: polarization effects and evidence of saturation

    Science.gov (United States)

    Turnbull, D.; Colaïtis, A.; Follett, R. K.; Palastro, J. P.; Froula, D. H.; Michel, P.; Goyon, C.; Chapman, T.; Divol, L.; Kemp, G. E.; Mariscal, D.; Patankar, S.; Pollock, B. B.; Ross, J. S.; Moody, J. D.; Tubman, E. R.; Woolsey, N. C.

    2018-05-01

    Recent results on crossed-beam energy transfer are presented. Wavelength tuning was used to vary the amount of energy transfer between two beams in a quasi-stationary plasma with carefully controlled conditions. The amount of transfer agreed well with calculations assuming linear ion acoustic waves (IAWs) with amplitudes up to δ n/n≈ 0.015. Increasing the initial probe intensity to access larger IAW amplitudes for otherwise fixed conditions yields evidence of saturation. The ability to manipulate a beam's polarization, which results from the anisotropic nature of the interaction, is revisited; an example is provided to demonstrate how polarization effects in a multibeam situation can dramatically enhance the expected amount of energy transfer.

  16. Risk Factors Influencing Conception Rate in Holstein Heifers before Artificial Insemination or Embryo Transfer

    Directory of Open Access Journals (Sweden)

    M. Yusuf

    2016-12-01

    Full Text Available The objective of this study was to show the risk factors affecting the conception rate in Holstein heifers after synchronization of estrus. A total of 275 Holstein heifers housed in a free barn were used for the experiment. The herd was visited regularly at four week intervals for synchronization of estrus using Heatsynch and CIDR-Heatsynch protocols. A group of four to 14 animals, depending on the availability, were referred to the experiment at each visit. Estrus induction rates in the two protocols were 93.9% and 94.9%, respectively. There was no difference in the conception rate between the two protocols. Conception rate after artificial insemination (AI or embryo transfer (ET were 46.3% and 51.4%, respectively. The risk factors affecting conception rate in heifers were daily weight gain (odds ratio [OR]= 4.673; P= 0.036 and body condition score (BCS (OR= 3.642; P= 0.018. Furthermore, estrus synchronization protocol (OR= 1.774; P= 0.083 and the absence of corpus luteum (CL at the initiation of treatment (OR= 0.512; P= 0.061 had a tendency to affect the conception rate, while age (OR= 0.715; P= 0.008 was a protective factor to conception rate.  In conclusion, positive daily weight gain before AI or ET, higher BCS, younger age, and the presence of CL at the initiation of estrus synchronization in dairy heifers increased the likelihood to conceive.

  17. Förster-type energy transfer as a probe for changes in local fluctuations of the protein matrix.

    Science.gov (United States)

    Somogyi, B; Matkó, J; Papp, S; Hevessy, J; Welch, G R; Damjanovich, S

    1984-07-17

    Much evidence, on both theoretical and experimental sides, indicates the importance of local fluctuations (in energy levels, conformational substates, etc.) of the macromolecular matrix in the biological activity of proteins. We describe here a novel application of the Förster-type energy-transfer process capable of monitoring changes both in local fluctuations and in conformational states of macromolecules. A new energy-transfer parameter, f, is defined as an average transfer efficiency, [E], normalized by the actual average quantum efficiency of the donor fluorescence, [phi D]. A simple oscillator model (for a one donor-one acceptor system) is presented to show the sensitivity of this parameter to changes in amplitudes of local fluctuations. The different modes of averaging (static, dynamic, and intermediate cases) occurring for a given value of the average transfer rate, [kt], and the experimental requirements as well as limitations of the method are also discussed. The experimental tests were performed on the ribonuclease T1-pyridoxamine 5'-phosphate conjugate (a one donor-one acceptor system) by studying the change of the f parameter with temperature, an environmental parameter expectedly perturbing local fluctuations of proteins. The parameter f increased with increasing temperature as expected on the basis of the oscillator model, suggesting that it really reflects changes of fluctuation amplitudes (significant changes in the orientation factor, k2, as well as in the spectral properties of the fluorophores can be excluded by anisotropy measurements and spectral investigations). Possibilities of the general applicability of the method are also discussed.

  18. Transfer

    DEFF Research Database (Denmark)

    Wahlgren, Bjarne; Aarkrog, Vibe

    Bogen er den første samlede indføring i transfer på dansk. Transfer kan anvendes som praksis-filosofikum. Den giver en systematisk indsigt til den studerende, der spørger: Hvordan kan teoretisk viden bruges til at reflektere over handlinger i situationer, der passer til min fremtidige arbejdsplads?...

  19. Free energy landscapes of electron transfer system in dipolar environment below and above the rotational freezing temperature

    International Nuclear Information System (INIS)

    Suzuki, Yohichi; Tanimura, Yoshitaka

    2007-01-01

    Electron transfer reaction in a polar solvent is modeled by a solute dipole surrounded by dipolar molecules with simple rotational dynamics posted on the three-dimensional distorted lattice sites. The interaction energy between the solute and solvent dipoles as a reaction coordinate is adopted and free energy landscapes are calculated by generating all possible states for a 26 dipolar system and by employing Wang-Landau sampling algorithm for a 92 dipolar system. For temperatures higher than the energy scale of dipole-dipole interactions, the free energy landscapes for the small reaction coordinate region have quadratic shape as predicted by Marcus [Rev. Mod. Phys. 65, 599 (1993)] whereas for the large reaction coordinate region, the landscapes exhibit a nonquadratic shape. When the temperature drops, small notched structures appear on the free energy profiles because of the frustrated interactions among dipoles. The formation of notched structure is analyzed with statistical approach and it is shown that the amplitude of notched structure depend upon the segment size of the reaction coordinate and is characterized by the interaction energy among the dipoles. Using simulated free energy landscapes, the authors calculate the reaction rates as a function of the energy gap for various temperatures. At high temperature, the reactions rates follow a bell shaped (inverted parabolic) energy gap law in the small energy gap regions, while it becomes steeper than the parabolic shape in a large energy gap regions due to the nonquadratic shape of the free energy landscape. The peak position of parabola also changes as the function of temperature. At low temperature, the profile of the reaction rates is no longer smooth because of the many local minima of the free energy landscape

  20. Fluorescence resonance energy transfer (FRET) in chemistry and ...

    Indian Academy of Sciences (India)

    Förster distance dependence of the FRET rate. SANGEETA SAINI,1 HARJINDER SINGH2 and BIMAN BAGCHI1,*. 1Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012. 2Permanent address: Department of ...

  1. The effect of rumen content transfer on rate of bacteria and protozoa growth

    International Nuclear Information System (INIS)

    Suharyono; M Winugroho; Y Widiati; S Marijati

    1998-01-01

    The aims the experiment wants to know the benefit of rate of microbial protein in rumen content and to complete the information that isolates is useful for ruminant animals feed. The result indicated that buffaloes from East Nusa Tenggara is the best when they are used as donor rumen transfer making isolate. When rumen of ongole cattle generation was mixed in rumen content of buffaloes from East Nusa Tenggara and incubated 48 h, the rate of bacteria cell growth is better than rate of protozoa cell growth comparing to the other animals. The values are 30.99 mg/h/100 ml and 24.92 mg.h/100 ml respectively. The results of isolate selection in 48 h incubation indicated that treatment F is the best. The results rates of bacteria cell growth and rate of protozoa's cell growth are 26.96 mg/h/100 ml and 2.53 mg/h/100 respectively. The result of in vitro study indicated that pH and ammonia concentration support the rate of bacteria cell growth and do not cause the toxicity of microbes and animal . The rate of bacteria cell growth on D treatment is significant to A,B, and C treatments. The values are 21.44 mg/h/100 ml. 7.99; 13.13; and 13.38 mg/h/100 ml respectively. The result rates of protozoa's cell growth tends lower than rates of bacteria cell. The overall conclusion is a lower or a higher rate of microorganism cell growth depends on the environment condition. (author)

  2. 77 FR 31756 - Energy Conservation Program: Alternative Efficiency Determination Methods and Alternative Rating...

    Science.gov (United States)

    2012-05-30

    ...-AC46 Energy Conservation Program: Alternative Efficiency Determination Methods and Alternative Rating... regulations authorizing the use of alternative methods of determining energy efficiency or energy consumption... alternative methods of determining energy efficiency or energy consumption of various consumer products and...

  3. Energy levels and radiative rates for transitions in Ti VI

    International Nuclear Information System (INIS)

    Aggarwal, K M; Keenan, F P; Msezane, A Z

    2013-01-01

    We report on calculations of energy levels, radiative rates, oscillator strengths and line strengths for transitions among the lowest 253 levels of the (1s 2 2s 2 2p 6 ) 3s 2 3p 5 , 3s3p 6 , 3s 2 3p 4 3d, 3s3p 5 3d, 3s 2 3p 3 3d 2 , 3s 2 3p 4 4s, 3s 2 3p 4 4p and 3s 2 3p 4 4d configurations of Ti VI. The general-purpose relativistic atomic structure package and flexible atomic code are adopted for the calculations. Radiative rates, oscillator strengths and line strengths are reported for all electric dipole (E1), magnetic dipole (M1), electric quadrupole (E2) and magnetic quadrupole (M2) transitions among the 253 levels, although calculations have been performed for a much larger number of levels. Comparisons are made with existing available results and the accuracy of the data is assessed. Additionally, lifetimes for all 253 levels are listed, although comparisons with other theoretical results are limited to only 88 levels. Our energy levels are estimated to be accurate to better than 1% (within 0.03 Ryd), whereas results for other parameters are probably accurate to better than 20%. A reassessment of the energy level data on the National Institute of Standards and Technology website for Ti VI is suggested. (paper)

  4. Renewable Energy Centre: design, realisation and exploitation transfer

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-31

    The Renewable Energy Centre (REC), which was completed in October 2003, has become one of the very few, maybe the only, commercial office project in the world to attempt to achieve net zero carbon dioxide emissions. This achievement results from a highly integrated, interactive use of four different renewable energy sources. These sources include a 225kW wind turbine, a 170m{sup 2} solar array (both thermal and photovoltaic), biomass fuel for heating and borehole water for cooling. The building itself is a converted 1930s farm building, sensitively restored to reflect its historical importance using, as far as possible, sustainable construction methods and materials with low embodied energy and designed to have a low energy requirement by means of good insulation and extensive passive solar measures. This document is a final report on the operation of the Centre as part of the IPID programme. The work carried out on this contract has been extremely successful in terms of its principal objectives. A vast amount of useful data has been collected, analysed and openly disseminated by a variety of means. Much of the data is summarized in this final report and new data continues to be collected and displayed on the Beaufort Court website.

  5. The Ontario-Manitoba clean energy transfer initiative

    International Nuclear Information System (INIS)

    Clarkson, J.

    2006-01-01

    Manitoba currently generates 5500 MW of electricity, and has the potential to add another 5000 MW of clean energy. Nearly 2000 MW of Manitoba's electricity is currently being sold to the United States. New transmission sites will ensure both grid reliability and energy security for Ontario, and power exchanges are expected to reduce costs. This presentation provided details of a memorandum of understanding (MOU) between Ontario and Manitoba concerning energy sales across existing and future transmission infrastructure. Peak energy sales were expected to reach 1000 MW in the near future. Options for the interconnection included direct high voltage direct current (HVDC) lines to Sudbury as well as lines through Thunder Bay and Winnipeg. Manitoba's existing hydro sites were outlined, and potential sites were reviewed. In addition to presenting new supply options, this presentation described generation and transmission approval processes, as well as construction schedules for new sites and interconnection points. It was concluded that while there is currently a provincial focus on electricity supply and demand, new generation technologies will make interprovincial electricity agreements economically viable. tabs., figs

  6. Wireless Energy Transfer Using Zero Bias Schottky Diodes Rectenna Structures

    International Nuclear Information System (INIS)

    Marian, V.; Adami, S.E.; Vollaire, Ch.; Allard, B.; Verdier, J.

    2011-01-01

    This paper presents several RF-to-DC converter topologies and compares their performances based on measurements made on fabricated prototypes. A medium range wireless low power transmission experiment is presented. A low power DC-DC boost converter designed rectenna-generated energy conditioning is also discussed. (author)

  7. Instruction transfer and storage exploration for low energy embedded VLIWs

    NARCIS (Netherlands)

    Aa, van der T.

    2005-01-01

    Portable consumer electronics to play multimedia have to be high performant and flexible. Energy consumption has to be kept as low as possible to ensure a long battery lifetime. To be flexible, these systems often contain an instruction set processor. Very Long Instruction Word (VLIW) processors

  8. Direct determination of resonance energy transfer in photolyase: structural alignment for the functional state.

    Science.gov (United States)

    Tan, Chuang; Guo, Lijun; Ai, Yuejie; Li, Jiang; Wang, Lijuan; Sancar, Aziz; Luo, Yi; Zhong, Dongping

    2014-11-13

    Photoantenna is essential to energy transduction in photoinduced biological machinery. A photoenzyme, photolyase, has a light-harvesting pigment of methenyltetrahydrofolate (MTHF) that transfers its excitation energy to the catalytic flavin cofactor FADH¯ to enhance DNA-repair efficiency. Here we report our systematic characterization and direct determination of the ultrafast dynamics of resonance energy transfer from excited MTHF to three flavin redox states in E. coli photolyase by capturing the intermediates formed through the energy transfer and thus excluding the electron-transfer quenching pathway. We observed 170 ps for excitation energy transferring to the fully reduced hydroquinone FADH¯, 20 ps to the fully oxidized FAD, and 18 ps to the neutral semiquinone FADH(•), and the corresponding orientation factors (κ(2)) were determined to be 2.84, 1.53 and 1.26, respectively, perfectly matching with our calculated theoretical values. Thus, under physiological conditions and over the course of evolution, photolyase has adopted the optimized orientation of its photopigment to efficiently convert solar energy for repair of damaged DNA.

  9. Negative transfer of heart rate control following biofeedback training: a partial replication.

    Science.gov (United States)

    Steptoe, A; Macready, D

    1985-09-01

    Ability to raise and lower heart rate (HR) on instruction was tested before and after unidirectional biofeedback training in two groups of 10 male volunteers. Instructional control was assessed in 2-min trials before training, and after 5 and 10 biofeedback trials of increasing (Group I) and decreasing (Group D) HR. The magnitude of HR elevations produced by Group D diminished following training, while modifications in Group I were unchanged. This negative transfer effect is discussed in relation to whether voluntary speeding and slowing HR reflect distinct capacities.

  10. Hand-to-hand coupling and strategies to minimize unintentional energy transfer during laparoscopic surgery.

    Science.gov (United States)

    Overbey, Douglas M; Hilton, Sarah A; Chapman, Brandon C; Townsend, Nicole T; Barnett, Carlton C; Robinson, Thomas N; Jones, Edward L

    2017-11-01

    Energy-based devices are used in nearly every laparoscopic operation. Radiofrequency energy can transfer to nearby instruments via antenna and capacitive coupling without direct contact. Previous studies have described inadvertent energy transfer through bundled cords and nonelectrically active wires. The purpose of this study was to describe a new mechanism of stray energy transfer from the monopolar instrument through the operating surgeon to the laparoscopic telescope and propose practical measures to decrease the risk of injury. Radiofrequency energy was delivered to a laparoscopic L-hook (monopolar "bovie"), an advanced bipolar device, and an ultrasonic device in a laparoscopic simulator. The tip of a 10-mm telescope was placed adjacent but not touching bovine liver in a standard four-port laparoscopic cholecystectomy setup. Temperature increase was measured as tissue temperature from baseline nearest the tip of the telescope which was never in contact with the energy-based device after a 5-s open-air activation. The monopolar L-hook increased tissue temperature adjacent to the camera/telescope tip by 47 ± 8°C from baseline (P energy devices significantly reduced temperature change in comparison to the monopolar instrument (47 ± 8°C) for both the advanced bipolar (1.2 ± 0.5°C; P energy transfers from the monopolar "bovie" instrument through the operating surgeon to standard electrically inactive laparoscopic instruments. Hand-to-hand coupling describes a new form of capacitive coupling where the surgeon's body acts as an electrical conductor to transmit energy. Strategies to reduce stray energy transfer include avoiding the same surgeon holding the active electrode and laparoscopic camera or using alternative energy devices. Copyright © 2017 Elsevier Inc. All rights reserved.

  11. A Conceptual Change Model for Teaching Heat Energy, Heat Transfer and Insulation

    Science.gov (United States)

    Lee, C. K.

    2014-01-01

    This study examines the existing knowledge that pre-service elementary teachers (PSETs) have regarding heat energy, heat transfer and insulation. The PSETs' knowledge of heat energy was initially assessed by using an activity: determining which container would be best to keep hot water warm for the longest period of time. Results showed that PSETs…

  12. Experimental studies and computer simulation of the control of energy transfer using inductor-converter bridges

    International Nuclear Information System (INIS)

    Hirano, M.; Kustom, R.L.

    1984-03-01

    An inductor-converter bridge (ICB) is a solid state DC-AC-DC power converter system for bidirectional, controllable, energy transfer between two coils. The ICB is suitable for supplying large pulsed power to such magnets as the superconducting equilibrium field coil of the proposed tokamak power reactors from another superconducting energy storage coil

  13. Designed azurins show lower reorganization free energies for intraprotein electron transfer

    DEFF Research Database (Denmark)

    Farver, Ole; Marshall, Nicholas M; Wherland, Scot

    2013-01-01

    Low reorganization free energies are necessary for fast electron transfer (ET) reactions. Hence, rational design of redox proteins with lower reorganization free energies has been a long-standing challenge, promising to yield a deeper understanding of the underlying principles of ET reactivity...

  14. Generating Excitement: Build Your Own Generator to Study the Transfer of Energy

    Science.gov (United States)

    Fletcher, Kurt; Rommel-Esham, Katie; Farthing, Dori; Sheldon, Amy

    2011-01-01

    The transfer of energy from one form to another can be difficult to understand. The electrical energy that turns on a lamp may come from the burning of coal, water falling at a hydroelectric plant, nuclear reactions, or gusts of wind caused by the uneven heating of the Earth. The authors have developed and tested an exciting hands-on activity to…

  15. Analysis of energy transfer process based emission spectra of erbium doped germanate glasses for mid-infrared laser materials

    Energy Technology Data Exchange (ETDEWEB)

    Cai, Muzhi; Wei, Tao; Zhou, Beier; Tian, Ying; Zhou, Jiajia; Xu, Shiqing, E-mail: shiqingxu@cjlu.edu.cn; Zhang, Junjie, E-mail: jjzhang@cjlu.edu.cn

    2015-03-25

    Highlights: • Er{sup 3+} doped germanate glass with good thermal stability were prepared. • Ionic boding nature was proved by bonding parameter calculation. • Mid-infrared fluorescent behaviors and energy transfer were investigated. • Rate equation and Dexter’s theory were utilized to elucidate 2.7 μm emission. - Abstract: Er{sup 3+} activated germanate glass with good thermal stability was prepared. Bonding parameters have been calculated and the nature of ionic bonding of the germanate glass has been determined. Mid-infrared fluorescence was observed and corresponding radiative properties were investigated. For Er{sup 3+}:{sup 4}I{sub 11/2}→{sup 4}I{sub 13/2} transition, high spontaneous radiative transition probability (30.09 s{sup −1}), large emission cross section ((14.84 ± 0.10) × 10{sup −21} cm{sup 2}) and superior gain performance were obtained from the prepared glass. Besides, energy transfer processes concerning the 2.7 μm emission were also discussed in detail. According to simplified rate equation and Dexter’s theory, energy transfer microscopic parameters were computed to elucidate observed 2.7 μm emissions. Results demonstrate that the prepared germanate glass possessing excellent spectroscopic properties might be an attractive candidate for mid-infrared laser or amplifier.

  16. Analysis of energy transfer process based emission spectra of erbium doped germanate glasses for mid-infrared laser materials

    International Nuclear Information System (INIS)

    Cai, Muzhi; Wei, Tao; Zhou, Beier; Tian, Ying; Zhou, Jiajia; Xu, Shiqing; Zhang, Junjie

    2015-01-01

    Highlights: • Er 3+ doped germanate glass with good thermal stability were prepared. • Ionic boding nature was proved by bonding parameter calculation. • Mid-infrared fluorescent behaviors and energy transfer were investigated. • Rate equation and Dexter’s theory were utilized to elucidate 2.7 μm emission. - Abstract: Er 3+ activated germanate glass with good thermal stability was prepared. Bonding parameters have been calculated and the nature of ionic bonding of the germanate glass has been determined. Mid-infrared fluorescence was observed and corresponding radiative properties were investigated. For Er 3+ : 4 I 11/2 → 4 I 13/2 transition, high spontaneous radiative transition probability (30.09 s −1 ), large emission cross section ((14.84 ± 0.10) × 10 −21 cm 2 ) and superior gain performance were obtained from the prepared glass. Besides, energy transfer processes concerning the 2.7 μm emission were also discussed in detail. According to simplified rate equation and Dexter’s theory, energy transfer microscopic parameters were computed to elucidate observed 2.7 μm emissions. Results demonstrate that the prepared germanate glass possessing excellent spectroscopic properties might be an attractive candidate for mid-infrared laser or amplifier

  17. A generalized window energy rating system for typical office buildings

    Energy Technology Data Exchange (ETDEWEB)

    Tian, Cheng; Chen, Tingyao; Yang, Hongxing; Chung, Tse-ming [Research Center for Building Environmental Engineering, Department of Building Services Engineering, The Hong Kong Polytechnic University, Hong Kong (China)

    2010-07-15

    Detailed computer simulation programs require lengthy inputs, and cannot directly provide an insight to relationship between the window energy performance and the key window design parameters. Hence, several window energy rating systems (WERS) for residential houses and small buildings have been developed in different countries. Many studies showed that utilization of daylight through elaborate design and operation of windows leads to significant energy savings in both cooling and lighting in office buildings. However, the current WERSs do not consider daylighting effect, while most of daylighting analyses do not take into account the influence of convective and infiltration heat gains. Therefore, a generalized WERS for typical office buildings has been presented, which takes all primary influence factors into account. The model includes embodied and operation energy uses and savings by a window to fully reflect interactions among the influence parameters. Reference locations selected for artificial lighting and glare control in the current common simulation practice may cause uncompromised conflicts, which could result in over- or under-estimated energy performance. Widely used computer programs, DOE2 and ADELINE, for hourly daylighting and cooling simulations have their own weaknesses, which may result in unrealistic or inaccurate results. An approach is also presented for taking the advantages of the both programs and avoiding their weaknesses. The model and approach have been applied to a typical office building of Hong Kong as an example to demonstrate how a WERS in a particular location can be established and how well the model can work. The energy effect of window properties, window-to-wall ratio (WWR), building orientation and lighting control strategies have been analyzed, and can be indicated by the localized WERS. An application example also demonstrates that the algebraic WERS derived from simulation results can be easily used for the optimal design of

  18. Low-energy plasma immersion ion implantation to induce DNA transfer into bacterial E. coli

    Energy Technology Data Exchange (ETDEWEB)

    Sangwijit, K. [Biotechnology Unit, University of Phayao, Muang, Phayao 56000 (Thailand); Yu, L.D., E-mail: yuld@thep-center.org [Plasma and Beam Physics Research Facility, Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Thailand Center of Excellence in Physics, Commission on Higher Education, 328 Si Ayutthaya Road, Bangkok 10400 (Thailand); Sarapirom, S. [Plasma and Beam Physics Research Facility, Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Faculty of Science, Maejo University, Bang Khen, Chiang Mai 50290 (Thailand); Pitakrattananukool, S. [School of Science, University of Phayao, Muang, Phayao 56000 (Thailand); Anuntalabhochai, S. [Biotechnology Unit, University of Phayao, Muang, Phayao 56000 (Thailand)

    2015-12-15

    Plasma immersion ion implantation (PIII) at low energy was for the first time applied as a novel biotechnology to induce DNA transfer into bacterial cells. Argon or nitrogen PIII at low bias voltages of 2.5, 5 and 10 kV and fluences ranging from 1 × 10{sup 12} to 1 × 10{sup 17} ions/cm{sup 2} treated cells of Escherichia coli (E. coli). Subsequently, DNA transfer was operated by mixing the PIII-treated cells with DNA. Successes in PIII-induced DNA transfer were demonstrated by marker gene expressions. The induction of DNA transfer was ion-energy, fluence and DNA-size dependent. The DNA transferred in the cells was confirmed functioning. Mechanisms of the PIII-induced DNA transfer were investigated and discussed in terms of the E. coli cell envelope anatomy. Compared with conventional ion-beam-induced DNA transfer, PIII-induced DNA transfer was simpler with lower cost but higher efficiency.

  19. Reduction of momentum transfer rates by parallel electric fields: A two-fluid demonstration

    International Nuclear Information System (INIS)

    Delamere, P.A.; Stenbaek-Nielsen, H.C.; Otto, A.

    2002-01-01

    Momentum transfer between an ionized gas cloud moving relative to an ambient magnetized plasma is a general problem in space plasma physics. Obvious examples include the Io-Jupiter interaction, comets, and coronal mass ejections. Active plasma experiments have demonstrated that momentum transfer rates associated with Alfven wave propagation are poorly understood. Barium injection experiments from the Combined Release and Radiation Effects Satellite (CRRES) have shown that dense ionized clouds are capable of ExB drifting over large distances perpendicular to the magnetic field. The CRRES 'skidding' distances were much larger than predicted by magnetohydrodynamic theory and it has been proposed that parallel electric fields were a key component in the skidding phenomenon. A two-fluid code was used to demonstrate the role of parallel electric fields in reducing momentum transfer between two distinct plasma populations. In this study, a dense plasma was initialized moving relative to an ambient plasma and perpendicular to B. Parallel electric fields were introduced via a friction term in the electron momentum equation and the collision frequency was scaled in proportion to the field-aligned current density. The simulation results showed that parallel electric fields decreased the decelerating magnetic tension force on the plasma cloud through a magnetic diffusion/reconnection process

  20. Analysis of optical near-field energy transfer by stochastic model unifying architectural dependencies

    Energy Technology Data Exchange (ETDEWEB)

    Naruse, Makoto, E-mail: naruse@nict.go.jp [Photonic Network Research Institute, National Institute of Information and Communications Technology, 4-2-1 Nukui-kita, Koganei, Tokyo 184-8795 (Japan); Nanophotonics Research Center, Graduate School of Engineering, The University of Tokyo, 2-11-16 Yayoi, Bunkyo-ku, Tokyo 113-8656 (Japan); Akahane, Kouichi; Yamamoto, Naokatsu [Photonic Network Research Institute, National Institute of Information and Communications Technology, 4-2-1 Nukui-kita, Koganei, Tokyo 184-8795 (Japan); Holmström, Petter [Laboratory of Photonics and Microwave Engineering, Royal Institute of Technology (KTH), SE-164 40 Kista (Sweden); Thylén, Lars [Laboratory of Photonics and Microwave Engineering, Royal Institute of Technology (KTH), SE-164 40 Kista (Sweden); Hewlett-Packard Laboratories, Palo Alto, California 94304 (United States); Huant, Serge [Institut Néel, CNRS and Université Joseph Fourier, 25 rue des Martyrs BP 166, 38042 Grenoble Cedex 9 (France); Ohtsu, Motoichi [Nanophotonics Research Center, Graduate School of Engineering, The University of Tokyo, 2-11-16 Yayoi, Bunkyo-ku, Tokyo 113-8656 (Japan); Department of Electrical Engineering and Information Systems, Graduate School of Engineering, The University of Tokyo, 2-11-16 Yayoi, Bunkyo-ku, Tokyo 113-8656 (Japan)

    2014-04-21

    We theoretically and experimentally demonstrate energy transfer mediated by optical near-field interactions in a multi-layer InAs quantum dot (QD) structure composed of a single layer of larger dots and N layers of smaller ones. We construct a stochastic model in which optical near-field interactions that follow a Yukawa potential, QD size fluctuations, and temperature-dependent energy level broadening are unified, enabling us to examine device-architecture-dependent energy transfer efficiencies. The model results are consistent with the experiments. This study provides an insight into optical energy transfer involving inherent disorders in materials and paves the way to systematic design principles of nanophotonic devices that will allow optimized performance and the realization of designated functions.