Anti-Ferroelectric Ceramics for High Energy Density Capacitors

Directory of Open Access Journals (Sweden)

Aditya Chauhan

2015-11-01

Full Text Available With an ever increasing dependence on electrical energy for powering modern equipment and electronics, research is focused on the development of efficient methods for the generation, storage and distribution of electrical power. In this regard, the development of suitable dielectric based solid-state capacitors will play a key role in revolutionizing modern day electronic and electrical devices. Among the popular dielectric materials, anti-ferroelectrics (AFE display evidence of being a strong contender for future ceramic capacitors. AFE materials possess low dielectric loss, low coercive field, low remnant polarization, high energy density, high material efficiency, and fast discharge rates; all of these characteristics makes AFE materials a lucrative research direction. However, despite the evident advantages, there have only been limited attempts to develop this area. This article attempts to provide a focus to this area by presenting a timely review on the topic, on the relevant scientific advancements that have been made with respect to utilization and development of anti-ferroelectric materials for electric energy storage applications. The article begins with a general introduction discussing the need for high energy density capacitors, the present solutions being used to address this problem, and a brief discussion of various advantages of anti-ferroelectric materials for high energy storage applications. This is followed by a general description of anti-ferroelectricity and important anti-ferroelectric materials. The remainder of the paper is divided into two subsections, the first of which presents various physical routes for enhancing the energy storage density while the latter section describes chemical routes for enhanced storage density. This is followed by conclusions and future prospects and challenges which need to be addressed in this particular field.

Charge storage mechanism in nanoporous carbons and its consequence for electrical double layer capacitors

Energy Technology Data Exchange (ETDEWEB)

Simon, P.; Gogotsi, Y.

2010-06-21

Electrochemical capacitors, also known as supercapacitors, are energy storage devices that fill the gap between batteries and dielectric capacitors. Thanks to their unique features, they have a key role to play in energy storage and harvesting, acting as a complement to or even a replacement of batteries which has already been achieved in various applications. One of the challenges in the supercapacitor area is to increase their energy density. Some recent discoveries regarding ion adsorption in microporous carbon exhibiting pores in the nanometre range can help in designing the next generation of high-energy-density supercapacitors.

High to ultra-high power electrical energy storage.

Science.gov (United States)

Sherrill, Stefanie A; Banerjee, Parag; Rubloff, Gary W; Lee, Sang Bok

2011-12-14

High power electrical energy storage systems are becoming critical devices for advanced energy storage technology. This is true in part due to their high rate capabilities and moderate energy densities which allow them to capture power efficiently from evanescent, renewable energy sources. High power systems include both electrochemical capacitors and electrostatic capacitors. These devices have fast charging and discharging rates, supplying energy within seconds or less. Recent research has focused on increasing power and energy density of the devices using advanced materials and novel architectural design. An increase in understanding of structure-property relationships in nanomaterials and interfaces and the ability to control nanostructures precisely has led to an immense improvement in the performance characteristics of these devices. In this review, we discuss the recent advances for both electrochemical and electrostatic capacitors as high power electrical energy storage systems, and propose directions and challenges for the future. We asses the opportunities in nanostructure-based high power electrical energy storage devices and include electrochemical and electrostatic capacitors for their potential to open the door to a new regime of power energy.

Testing and evaluation of different energy storage devices for piezoelectric energy harvesting under road conditions

Science.gov (United States)

Gopalakrishnan, Pratheek

The increasing needs in green technology have propelled the rapid development in energy conversion and the advancement of electric energy storage systems. A viable storage technology is needed to store intermittent electrical energy in different electronic applications. In this thesis, recent progress on the chemistry and design of batteries is summarized with their challenges and improvements. Along with that, electrolytic capacitors are also reviewed with their types, advantages and disadvantages of each in short. Super capacitors having higher surface area and thinner dielectrics than conventional capacitors along with hybrid capacitors, are discussed in detail. The potential of a hybrid capacitor, Ni(OH)2/ Active Carbon, compared with Ni-Cd batteries and electrolytic capacitors in the application of energy storage for high way energy harvesting has been explored in this work. Both the battery and the hybrid capacitor has been tested under various experimental conditions and their properties in relation to their chemical compositions are compared. The results obtained from the experiments have been analyzed and the most suitable energy storage devices have been selected with their application potential evaluated before drawing conclusion reported in this thesis.

Analysis of stationary fuel cell dynamic ramping capabilities and ultra capacitor energy storage using high resolution demand data

Science.gov (United States)

Meacham, James R.; Jabbari, Faryar; Brouwer, Jacob; Mauzey, Josh L.; Samuelsen, G. Scott

Current high temperature fuel cell (HTFC) systems used for stationary power applications (in the 200-300 kW size range) have very limited dynamic load following capability or are simply base load devices. Considering the economics of existing electric utility rate structures, there is little incentive to increase HTFC ramping capability beyond 1 kWs -1 (0.4% s -1). However, in order to ease concerns about grid instabilities from utility companies and increase market adoption, HTFC systems will have to increase their ramping abilities, and will likely have to incorporate electrical energy storage (EES). Because batteries have low power densities and limited lifetimes in highly cyclic applications, ultra capacitors may be the EES medium of choice. The current analyses show that, because ultra capacitors have a very low energy storage density, their integration with HTFC systems may not be feasible unless the fuel cell has a ramp rate approaching 10 kWs -1 (4% s -1) when using a worst-case design analysis. This requirement for fast dynamic load response characteristics can be reduced to 1 kWs -1 by utilizing high resolution demand data to properly size ultra capacitor systems and through demand management techniques that reduce load volatility.

Energy Efficient Graphene Based High Performance Capacitors.

Science.gov (United States)

Bae, Joonwon; Kwon, Oh Seok; Lee, Chang-Soo

2017-07-10

Graphene (GRP) is an interesting class of nano-structured electronic materials for various cutting-edge applications. To date, extensive research activities have been performed on the investigation of diverse properties of GRP. The incorporation of this elegant material can be very lucrative in terms of practical applications in energy storage/conversion systems. Among various those systems, high performance electrochemical capacitors (ECs) have become popular due to the recent need for energy efficient and portable devices. Therefore, in this article, the application of GRP for capacitors is described succinctly. In particular, a concise summary on the previous research activities regarding GRP based capacitors is also covered extensively. It was revealed that a lot of secondary materials such as polymers and metal oxides have been introduced to improve the performance. Also, diverse devices have been combined with capacitors for better use. More importantly, recent patents related to the preparation and application of GRP based capacitors are also introduced briefly. This article can provide essential information for future study. Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.org.

Multifunctional composites for energy storage

Science.gov (United States)

Shuvo, Mohammad Arif I.; Karim, Hasanul; Rajib, Md; Delfin, Diego; Lin, Yirong

2014-03-01

Electrochemical super-capacitors have become one of the most important topics in both academia and industry as novel energy storage devices because of their high power density, long life cycles, and high charge/discharge efficiency. Recently, there has been an increasing interest in the development of multifunctional structural energy storage devices such as structural super-capacitors for applications in aerospace, automobiles and portable electronics. These multifunctional structural super-capacitors provide lighter structures combining energy storage and load bearing functionalities. Due to their superior materials properties, carbon fiber composites have been widely used in structural applications for aerospace and automotive industries. Besides, carbon fiber has good electrical conductivity which will provide lower equivalent series resistance; therefore, it can be an excellent candidate for structural energy storage applications. Hence, this paper is focused on performing a pilot study for using nanowire/carbon fiber hybrids as building materials for structural energy storage materials; aiming at enhancing the charge/discharge rate and energy density. This hybrid material combines the high specific surface area of carbon fiber and pseudo-capacitive effect of metal oxide nanowires which were grown hydrothermally in an aligned fashion on carbon fibers. The aligned nanowire array could provide a higher specific surface area that leads to high electrode-electrolyte contact area and fast ion diffusion rates. Scanning Electron Microscopy (SEM) and XRay Diffraction (XRD) measurements were used for the initial characterization of this nanowire/carbon fiber hybrid material system. Electrochemical testing has been performed using a potentio-galvanostat. The results show that gold sputtered nanowire hybrid carbon fiber provides 65.9% better performance than bare carbon fiber cloth as super-capacitor.

Development of energy storage system for DC electric rolling stock applying electric double layer capacitor

Energy Technology Data Exchange (ETDEWEB)

Sekijima, Y.; Kudo, Y.; Inui, M. [Central Japan Railway Co., Aichi (Japan); Monden, Y.; Toda, S.; Aoyama, I. [Toshiba Corp., Tokyo (Japan)

2006-07-01

This paper provided details of an energy storage system designed for use with DC electric rolling stock through the application of an electric double layer capacitor (EDLC). The EDLC was selected due to its long life-span and its low operational costs. Testing was conducted to assess the system's basic control function, acceleration using stored energy, and behaviour during regenerative brake failure. A control circuit chip was used in the DC electric rolling stock on an inverter of the energy storage system. Tests confirmed that the control method was effective for actual rolling stocks. A full-scale energy storage system for installation on series 313 locomotives was then constructed. Braking energy was generated only from a regenerative brake. In case of brake failure, braking energy was generated from an air brake was well as an electric brake. Data from a field test conducted at the Tokaido and Chuo railway lines showed a capacity of 0.6 kWh. The EDLC was used to reduce peak air brake energy. It was concluded that storing 0.28 kW of brake energy in the EDLC can reduce peaks of air brake energy in high speed ranges. Experimental equipment was used to confirm use of the system with 0.56 kWh of EDLC, the average energy of air brake used in regenerative energy failure. 1 tab., 10 figs.

Mechanical confinement for improved energy storage density in BNT-BT-KNN lead-free ceramic capacitors

Directory of Open Access Journals (Sweden)

Aditya Chauhan

2014-08-01

Full Text Available With the advent of modern power electronics, embedded circuits and non-conventional energy harvesting, the need for high performance capacitors is bound to become indispensible. The current state-of-art employs ferroelectric ceramics and linear dielectrics for solid state capacitance. However, lead-free ferroelectric ceramics propose to offer significant improvement in the field of electrical energy storage owing to their high discharge efficiency and energy storage density. In this regards, the authors have investigated the effects of compressive stress as a means of improving the energy storage density of lead-free ferroelectric ceramics. The energy storage density of 0.91(Bi0.5Na0.5TiO3-0.07BaTiO3-0.02(K0.5Na0.5NbO3 ferroelectric bulk ceramic was analyzed as a function of varying levels of compressive stress and operational temperature .It was observed that a peak energy density of 387 mJ.cm-3 was obtained at 100 MPa applied stress (25oC. While a maximum energy density of 568 mJ.cm-3 was obtained for the same stress at 80oC. These values are indicative of a significant, 25% and 84%, improvement in the value of stored energy compared to an unloaded material. Additionally, material's discharge efficiency has also been discussed as a function of operational parameters. The observed phenomenon has been explained on the basis of field induced structural transition and competitive domain switching theory.

Energy storage, compression, and switching. Vol. 2

International Nuclear Information System (INIS)

Nardi, V.; Bostick, W.H.; Sahlin, H.

1983-01-01

This book is a compilation of papers presented at the Second International Conference on Energy Storage, Compression, and Switching, which was held in order to assemble active researchers with a major interest in plasma physics, electron beams, electric and magnetic energy storage systems, high voltage and high current switches, free-electron lasers, and pellet implosion plasma focus. Topics covered include: Slow systems: 50-60 Hz machinery, homopolar generators, slow capacitors, inductors, and solid state switches; Intermediate systems: fast capacitor banks; superconducting storage and switching; gas, vacuum, and dielectric switching; nonlinear (magnetic) switching; imploding liners capacitors; explosive generators; and fuses; and Fast systems: Marx, Blumlein, oil, water, and pressurized water dielectrics; switches; magnetic insulation; electron beams; and plasmas

Electrochemical Energy Storage Technical Team Roadmap

Energy Technology Data Exchange (ETDEWEB)

None

2013-06-01

This U.S. DRIVE electrochemical energy storage roadmap describes ongoing and planned efforts to develop electrochemical energy storage technologies for plug-in electric vehicles (PEVs). The Energy Storage activity comprises a number of research areas (including advanced materials research, cell level research, battery development, and enabling R&D which includes analysis, testing and other activities) for advanced energy storage technologies (batteries and ultra-capacitors).

Newly discovered failure mode in high energy density, energy storage capacitors

International Nuclear Information System (INIS)

Boicourt, G.P.; Kemp, E.L.

1978-07-01

High energy density pulse capacitors, typified by the 10-kV, 170-μF unit, have become widely used in recent years. These units primarily were designed for lower cost and higher energy per unit volume. The life characteristics of these units have never been determined fully, but they have already been shown capable of lives much longer than originally expected. The Los Alamos Scientific Laboratory is now conducting an extended program to determine the long-term capabilities of these capacitors. This program is aimed not only at finding the statistical parameters of the failure distribution but also at determining the physical failure modes characteristic of such units. Recently, a new failure mode was found. This failure mode has prevented test samples of polypropylene-paper-dioctyl phthalate units from actually reaching the true potential life of the insulation. In this report, the new failure mechanism is examined and suggestions are made that could eliminate the failure mode

Mechanical confinement for improved energy storage density in BNT-BT-KNN lead-free ceramic capacitors

Energy Technology Data Exchange (ETDEWEB)

Chauhan, Aditya; Patel, Satyanarayan; Vaish, Rahul, E-mail: rahul@iitmandi.ac.in [School of Engineering, Indian Institute of Technology Mandi, 175 001 (India)

2014-08-15

With the advent of modern power electronics, embedded circuits and non-conventional energy harvesting, the need for high performance capacitors is bound to become indispensible. The current state-of-art employs ferroelectric ceramics and linear dielectrics for solid state capacitance. However, lead-free ferroelectric ceramics propose to offer significant improvement in the field of electrical energy storage owing to their high discharge efficiency and energy storage density. In this regards, the authors have investigated the effects of compressive stress as a means of improving the energy storage density of lead-free ferroelectric ceramics. The energy storage density of 0.91(Bi{sub 0.5}Na{sub 0.5})TiO{sub 3}-0.07BaTiO{sub 3}-0.02(K{sub 0.5}Na{sub 0.5})NbO{sub 3} ferroelectric bulk ceramic was analyzed as a function of varying levels of compressive stress and operational temperature .It was observed that a peak energy density of 387 mJ.cm{sup -3} was obtained at 100 MPa applied stress (25{sup o}C). While a maximum energy density of 568 mJ.cm{sup -3} was obtained for the same stress at 80{sup o}C. These values are indicative of a significant, 25% and 84%, improvement in the value of stored energy compared to an unloaded material. Additionally, material's discharge efficiency has also been discussed as a function of operational parameters. The observed phenomenon has been explained on the basis of field induced structural transition and competitive domain switching theory.

A compact seven switches topology and reduced DC-link capacitor size for single-phase stand-alone PV system with hybrid energy storages

DEFF Research Database (Denmark)

Liu, Xiong; Wang, Peng; Loh, Poh Chiang

2011-01-01

Single-phase stand-alone PV system is suitable for household applications in remote area. Hybrid battery/ultra-capacitor energy storage can reduce charge and discharge cycles and avoid deep discharges of battery. This paper proposes a compact seven switches structure for stand-alone PV system......, which otherwise needs nine switches configuration, inclusive of one switch for boost converter, four switches for single-phase inverter and four switches for two DC/DC converters of battery and ultra-capacitor. It is well-known that a bulky DC-link capacitor is always required to absorb second......-order harmonic current caused by single-phase inverter. In the proposed compact topology, a small size DC-link capacitor can achieve the same function through charging/discharging control of ultra-capacitor to mitigate second-order ripple current. Simulation results are provided to validate the effectiveness...

Large energy storage efficiency of the dielectric layer of graphene nanocapacitors

Science.gov (United States)

Bezryadin, A.; Belkin, A.; Ilin, E.; Pak, M.; Colla, Eugene V.; Hubler, A.

2017-12-01

Electric capacitors are commonly used in electronic circuits for the short-term storage of small amounts of energy. It is desirable however to use capacitors to store much larger energy amounts to replace rechargeable batteries. Unfortunately existing capacitors cannot store sufficient energy to be able to replace common electrochemical energy storage systems. Here we examine the energy storage capabilities of graphene nanocapacitors, which are tri-layer devices involving an Al film, Al2O3 dielectric layer, and a single layer of carbon atoms, i.e., graphene. This is a purely electronic capacitor and therefore it can function in a wide temperature interval. The capacitor shows a high dielectric breakdown electric field strength, of the order of 1000 kV mm-1 (i.e., 1 GV m-1), which is much larger than the table value of the Al2O3 dielectric strength. The corresponding energy density is 10-100 times larger than the energy density of a common electrolytic capacitor. Moreover, we discover that the amount of charge stored in the dielectric layer can be equal or can even exceed the amount of charge stored on the capacitor plates. The dielectric discharge current follows a power-law time dependence. We suggest a model to explain this behavior.

Large energy storage efficiency of the dielectric layer of graphene nanocapacitors.

Science.gov (United States)

Bezryadin, A; Belkin, A; Ilin, E; Pak, M; Colla, Eugene V; Hubler, A

2017-12-08

Electric capacitors are commonly used in electronic circuits for the short-term storage of small amounts of energy. It is desirable however to use capacitors to store much larger energy amounts to replace rechargeable batteries. Unfortunately existing capacitors cannot store sufficient energy to be able to replace common electrochemical energy storage systems. Here we examine the energy storage capabilities of graphene nanocapacitors, which are tri-layer devices involving an Al film, Al 2 O 3 dielectric layer, and a single layer of carbon atoms, i.e., graphene. This is a purely electronic capacitor and therefore it can function in a wide temperature interval. The capacitor shows a high dielectric breakdown electric field strength, of the order of 1000 kV mm -1 (i.e., 1 GV m -1 ), which is much larger than the table value of the Al 2 O 3 dielectric strength. The corresponding energy density is 10-100 times larger than the energy density of a common electrolytic capacitor. Moreover, we discover that the amount of charge stored in the dielectric layer can be equal or can even exceed the amount of charge stored on the capacitor plates. The dielectric discharge current follows a power-law time dependence. We suggest a model to explain this behavior.

Materials for electrochemical capacitors

Science.gov (United States)

Simon, Patrice; Gogotsi, Yury

2008-11-01

Electrochemical capacitors, also called supercapacitors, store energy using either ion adsorption (electrochemical double layer capacitors) or fast surface redox reactions (pseudo-capacitors). They can complement or replace batteries in electrical energy storage and harvesting applications, when high power delivery or uptake is needed. A notable improvement in performance has been achieved through recent advances in understanding charge storage mechanisms and the development of advanced nanostructured materials. The discovery that ion desolvation occurs in pores smaller than the solvated ions has led to higher capacitance for electrochemical double layer capacitors using carbon electrodes with subnanometre pores, and opened the door to designing high-energy density devices using a variety of electrolytes. Combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries. The use of carbon nanotubes has further advanced micro-electrochemical capacitors, enabling flexible and adaptable devices to be made. Mathematical modelling and simulation will be the key to success in designing tomorrow's high-energy and high-power devices.

Homogeneous/Inhomogeneous-Structured Dielectrics and their Energy-Storage Performances.

Science.gov (United States)

Yao, Zhonghua; Song, Zhe; Hao, Hua; Yu, Zhiyong; Cao, Minghe; Zhang, Shujun; Lanagan, Michael T; Liu, Hanxing

2017-05-01

The demand for dielectric capacitors with higher energy-storage capability is increasing for power electronic devices due to the rapid development of electronic industry. Existing dielectrics for high-energy-storage capacitors and potential new capacitor technologies are reviewed toward realizing these goals. Various dielectric materials with desirable permittivity and dielectric breakdown strength potentially meeting the device requirements are discussed. However, some significant limitations for current dielectrics can be ascribed to their low permittivity, low breakdown strength, and high hysteresis loss, which will decrease their energy density and efficiency. Thus, the implementation of dielectric materials for high-energy-density applications requires the comprehensive understanding of both the materials design and processing. The optimization of high-energy-storage dielectrics will have far-reaching impacts on the sustainable energy and will be an important research topic in the near future. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Inductive line energy storage generator

Energy Technology Data Exchange (ETDEWEB)

Choi, P [Ecole Polytechnique, Palaiseau (France). Laboratoire de Physique des Milieux Ionises

1997-12-31

The inductive energy storage (IES) generator has long been considered to be the most efficient system for energy usage in large pulsed power system at the MA level. A number of parameters govern the efficiency of energy transfer between the storage capacitors and the load, and the level of current deliverable to the load. For high power system, the energy storage capacitors are arranged as a Marx generator. The primary constraints are the inductances in the various parts of the circuit, in particular, the upstream inductance between the Marx and the POS, and the downstream inductance between the POS and the load. This paper deals with the effect of replacing part of the upstream inductance with a transmission line and introduces the new concept of an inductive line for energy storage (ILES). Extensive parametric scans were carried out on circuit simulations to investigate the effect of this upstream transmission line. A model was developed to explain the operation of the ILES design based on the data obtained. Comparison with an existing IES generator shows that the ILES design offers a significant improvement in the maximum current and hence energy delivered to an inductive load. (author). 5 figs., 1 ref.

Electrically tuned super-capacitors

OpenAIRE

Chowdhury, Tazima S.; Grebel, Haim

2015-01-01

Fast charging and discharging of large amounts of electrical energy make super-capacitors ideal for short-term energy storage [1-5]. In its simplest form, the super-capacitor is an electrolytic capacitor made of an anode and a cathode immersed in an electrolyte. As for an ordinary capacitor, minimizing the charge separation distance and increasing the electrode area increase capacitance. In super-capacitors, charge separation is of nano-meter scale at each of the electrode interface (the Helm...

EPR ohmic heating energy storage

International Nuclear Information System (INIS)

Heck, F.M.; Stillwagon, R.E.; King, E.I.

1977-01-01

The Ohmic Heating (OH) Systems for all the Experimental Power Reactor (EPR) designs to date have all used temporary energy storage to assist in providing the OH current charge required to build up the plasma current. The energies involved (0.8 x 10 9 J to 1.9 x 10 9 J) are so large as to make capacitor storage impractical. Two alternative approaches are homopolar dc generators and ac generators. Either of these can be designed for pulse duty and can be made to function in a manner similar to a capacitor in the OH circuit and are therefore potential temporary energy storage devices for OH systems for large tokamaks. This study compared total OH system costs using homopolar and ac generators to determine their relative merits. The total system costs were not significantly different for either type of machine. The added flexibility and the lower maintenance of the ac machine system make it the more attractive approach

Progress in electrical energy storage system:A critical review

Institute of Scientific and Technical Information of China (English)

Haisheng Chen; Thang Ngoc Cong; Wei Yang; Chunqing Tan; Yongliang Li; Yulong Ding

2009-01-01

Electrical energy storage technologies for stationary applications are reviewed.Particular attention is paid to pumped hydroelectric storage,compressed air energy storage,battery,flow battery,fuel cell,solar fuel,superconducting magnetic energy storage, flywheel, capacitor/supercapacitor,and thermal energy torage.Comparison is made among these technologies in terms of technical characteris-tics,applications and deployment status.

Wide Temperature Range Hybrid Energy Storage Device, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — This proposal concerns the fabrication of a hybrid battery capacitor (HBC) using Eltron's knowledge gained in battery and capacitor research. Energy storage systems...

PLZT Film Capacitors for Power Electronics and Energy Storage Applications

Energy Technology Data Exchange (ETDEWEB)

Ma, Beihai; Hu, Zhongqiang; Koritala, Rachel E.; Lee, Tae H.; Dorris, Stephen E.; Balachandran, Uthamalingam

2015-12-01

Ceramic film capacitors with high dielectric constant and high breakdown strength hold special promise for applications demanding high power density. By means of chemical solution deposition, we deposited ≈2-μm-thick films of lanthanum-doped lead zirconate titanate (PLZT) on LaNiO3-buffered Ni (LNO/Ni) foils and platinized silicon (PtSi) substrates. The dielectric properties and energy storage performance of the resulting samples were determined under a high level of applied electric field. X-ray diffraction stress analysis revealed that PLZT on LNO/Ni bears a compressive stress of ≈370 MPa while PLZT on PtSi endures a tensile stress of ≈250 MPa. Compressive stress was found to lead to heightened polarization, improved tunability, increased irreversible domain wall motion, and enhanced breakdown strength for PLZT deposited on the LNO/Ni as compared with the PtSi substrate. We observed a tunability of ≈55 and ≈40 % at room temperature under 100 kV/cm applied field, remanent polarization of ≈23.5 and ≈7.4 µC/cm^2, coercive electric field of ≈25.6 and ≈21.1 kV/cm, and dielectric breakdown strength of ≈2.6 and ≈1.5 MV/cm for PLZT deposited on LNO/Ni foils and PtSi substrates, respectively. A high recoverable energy density of ≈85 J/cm^3 and energy conversion efficiency of ≈65 % were measured on the PLZT film grown on LNO/Ni.

A hybrid electrochemical device based on a synergetic inner combination of Li ion battery and Li ion capacitor for energy storage.

Science.gov (United States)

Zheng, Jun-Sheng; Zhang, Lei; Shellikeri, Annadanesh; Cao, Wanjun; Wu, Qiang; Zheng, Jim P

2017-02-07

Li ion battery (LIB) and electrochemical capacitor (EC) are considered as the most widely used energy storage systems (ESSs) because they can produce a high energy density or a high power density, but it is a huge challenge to achieve both the demands of a high energy density as well as a high power density on their own. A new hybrid Li ion capacitor (HyLIC), which combines the advantages of LIB and Li ion capacitor (LIC), is proposed. This device can successfully realize a potential match between LIB and LIC and can avoid the excessive depletion of electrolyte during the charge process. The galvanostatic charge-discharge cycling tests reveal that at low current, the HyLIC exhibits a high energy density, while at high current, it demonstrates a high power density. Ragone plot confirms that this device can make a synergetic balance between energy and power and achieve a highest energy density in the power density range of 80 to 300 W kg -1 . The cycle life test proves that HyLIC exhibits a good cycle life and an excellent coulombic efficiency. The present study shows that HyLIC, which is capable of achieving a high energy density, a long cycle life and an excellent power density, has the potential to achieve the winning combination of a high energy and power density.

On the Suitability of Interleaved Switched Capacitor Converter as an Interface for Electric Vehicle Dual Energy Storage Systems

Energy Technology Data Exchange (ETDEWEB)

Amjadi, Zahra; Williamson, Sheldon

2010-09-15

This paper presents the analysis and novel hybrid controller design for an interleaved 2-quadrant switched capacitor (SC) bidirectional DC/DC converter for a hybrid electric vehicle (HEV) dual energy storage system. The designed novel control strategy enables simpler dynamics compared to a standard buck converter with input filter, good regulation capability, low EMI, lower source current ripple, ease of control, and continuous input current waveform in both buck as well as boost modes of operation.

Ten questions to Jean Dhers on the storage of electric energy

International Nuclear Information System (INIS)

2006-01-01

The authors proposes a comprehensive set of technical and economical data and information on electricity storage: the reasons to store energy (autonomous, stationary and network applications), the different types and advantages of energy storages with reversible power, the means to massively store electricity to exploit in on the network (description, uses and comparison of pumping energy transfer station, energy storage under the form of compressed air), the inertial storage (storage of kinetic energy accumulated in a flywheel, and its applications), the importance of storage with electrochemical batteries (reversible storage, evolution of batteries in ground transports, main economic sectors for batteries), fuel cells, the role of energy storage by power capacitors, the perspectives of super capacitors in a near future (comparison of their performance with those of batteries, possible applications), the use of electromagnetic storage of electricity (description, advantages, drawbacks and applications of superconducting magnet energy storage or SMES), and how the research on electric power storage is organised

Nanowire modified carbon fibers for enhanced electrical energy storage

Science.gov (United States)

Shuvo, Mohammad Arif Ishtiaque; (Bill) Tseng, Tzu-Liang; Ashiqur Rahaman Khan, Md.; Karim, Hasanul; Morton, Philip; Delfin, Diego; Lin, Yirong

2013-09-01

The study of electrochemical super-capacitors has become one of the most attractive topics in both academia and industry as energy storage devices because of their high power density, long life cycles, and high charge/discharge efficiency. Recently, there has been increasing interest in the development of multifunctional structural energy storage devices such as structural super-capacitors for applications in aerospace, automobiles, and portable electronics. These multifunctional structural super-capacitors provide structures combining energy storage and load bearing functionalities, leading to material systems with reduced volume and/or weight. Due to their superior materials properties, carbon fiber composites have been widely used in structural applications for aerospace and automotive industries. Besides, carbon fiber has good electrical conductivity which will provide lower equivalent series resistance; therefore, it can be an excellent candidate for structural energy storage applications. Hence, this paper is focused on performing a pilot study for using nanowire/carbon fiber hybrids as building materials for structural energy storage materials; aiming at enhancing the charge/discharge rate and energy density. This hybrid material combines the high specific surface area of carbon fiber and pseudo-capacitive effect of metal oxide nanowires, which were grown hydrothermally in an aligned fashion on carbon fibers. The aligned nanowire array could provide a higher specific surface area that leads to high electrode-electrolyte contact area thus fast ion diffusion rates. Scanning Electron Microscopy and X-Ray Diffraction measurements are used for the initial characterization of this nanowire/carbon fiber hybrid material system. Electrochemical testing is performed using a potentio-galvanostat. The results show that gold sputtered nanowire carbon fiber hybrid provides 65.9% higher energy density than bare carbon fiber cloth as super-capacitor.

Pseudocapacitive Sodium Storage in Mesoporous Single-Crystal-like TiO2-Graphene Nanocomposite Enables High-Performance Sodium-Ion Capacitors.

Science.gov (United States)

Le, Zaiyuan; Liu, Fang; Nie, Ping; Li, Xinru; Liu, Xiaoyan; Bian, Zhenfeng; Chen, Gen; Wu, Hao Bin; Lu, Yunfeng

2017-03-28

Sodium-ion capacitors can potentially combine the virtues of high power capability of conventional electrochemical capacitors and high energy density of batteries. However, the lack of high-performance electrode materials has been the major challenge of sodium-based energy storage devices. In this work, we report a microwave-assisted synthesis of single-crystal-like anatase TiO 2 mesocages anchored on graphene as a sodium storage material. The architecture of the nanocomposite results in pseudocapacitive charge storage behavior with fast kinetics, high reversibility, and negligible degradation to the micro/nanostructure. The nanocomposite delivers a high capacity of 268 mAh g -1 at 0.2 C, which remains 126 mAh g -1 at 10 C for over 18 000 cycles. Coupling with a carbon-based cathode, a full cell of sodium-ion capacitor successfully demonstrates a high energy density of 64.2 Wh kg -1 at 56.3 W kg -1 and 25.8 Wh kg -1 at 1357 W kg -1 , as well as an ultralong lifespan of 10 000 cycles with over 90% of capacity retention.

Low-inductance switch and capacitor energy storage modules made of packages of industrial condensers IK50-3

International Nuclear Information System (INIS)

Bykov, Yu A; Krastelev, E G; Sedin, A A; Feduschak, V F

2017-01-01

A low-inductance module of a high-current capacitive energy storage with an operating voltage of 40 kV is developed. The design of the module is based on the application of capacitive sections of the industrial condenser IK50-3. The module includes two capacitors of 0.35 μF each, one common low-jitter triggered gas switch and 2 groups of output cables of 4 from each capacitor. A bus bars topology developed for the switch and cables connections provides a small total inductance of the discharge circuit, for the module with the output cables KVIM of 0.5 m long, it is lower than 40 nH. The set of 10 modules is now used for driving the 20 stages linear transformer for a fast charging of the pulse forming line of the high-current nanosecond accelerator. A design of the module and the results of tests of a single module and a set of 10 are presented. (paper)

A High Power Density Single-Phase PWM Rectifier With Active Ripple Energy Storage

Energy Technology Data Exchange (ETDEWEB)

Wang, Ruxi [Virginia Polytechnic Institute and State University (Virginia Tech); Wang, Fei [ORNL; Boroyevich, Dushan [Virginia Polytechnic Institute and State University (Virginia Tech); Burgos, Rolando [ABB; Lai, Rixin [General Electric; Ning, Puqi [ORNL; Rajashekara, Kaushik [Rolls Royce

2011-01-01

It is well known that single-phase pulse width modulation rectifiers have second-order harmonic currents and corresponding ripple voltages on the dc bus. The low-frequency harmonic current is normally filtered using a bulk capacitor in the bus, which results in low power density. However, pursuing high power density in converter design is a very important goal in the aerospace applications. This paper studies methods for reducing the energy storage capacitor for single-phase rectifiers. The minimum ripple energy storage requirement is derived independently of a specific topology. Based on theminimum ripple energy requirement, the feasibility of the active capacitor s reduction schemes is verified. Then, we propose a bidirectional buck boost converter as the ripple energy storage circuit, which can effectively reduce the energy storage capacitance. The analysis and design are validated by simulation and experimental results.

Optimal Scheduling for Energy Harvesting Transmitters with Hybrid Energy Storage

OpenAIRE

Ozel, Omur; Shahzad, Khurram; Ulukus, Sennur

2013-01-01

We consider data transmission with an energy harvesting transmitter which has a hybrid energy storage unit composed of a perfectly efficient super-capacitor (SC) and an inefficient battery. The SC has finite space for energy storage while the battery has unlimited space. The transmitter can choose to store the harvested energy in the SC or in the battery. The energy is drained from the SC and the battery simultaneously. In this setting, we consider the offline throughput maximization problem ...

Multiple Interfacial Fe3O4@BaTiO3/P(VDF-HFP) Core-Shell-Matrix Films with Internal Barrier Layer Capacitor (IBLC) Effects and High Energy Storage Density.

Science.gov (United States)

Zhou, Ling; Fu, Qiuyun; Xue, Fei; Tang, Xiahui; Zhou, Dongxiang; Tian, Yahui; Wang, Geng; Wang, Chaohong; Gou, Haibo; Xu, Lei

2017-11-22

Flexible nanocomposites composed of high dielectric constant fillers and polymer matrix have shown great potential for electrostatic capacitors and energy storage applications. To obtain the composited material with high dielectric constant and high breakdown strength, multi-interfacial composited particles, which composed of conductive cores and insulating shells and possessed the internal barrier layer capacitor (IBLC) effect, were adopted as fillers. Thus, Fe 3 O 4 @BaTiO 3 core-shell particles were prepared and loaded into the poly(vinylidene fluoride-co-hexafluoropropylene) (P(VDF-HFP)) polymer matrix. As the mass fraction of core-shell fillers increased from 2.5 wt % to 30 wt %, the dielectric constant of the films increased, while the loss tangent remained at a low level (capacitor model was also adopted to interpret the efficiency of IBLC effects on the suppressed loss tangent and the superior breakdown strength. This work explored an effective approach to prepare dielectric nanocomposites for energy storage applications experimentally and theoretically.

Electric energy storage - Overview of technologies

International Nuclear Information System (INIS)

Boye, Henri

2013-01-01

Energy storage is a challenging and costly process, as electricity can only be stored by conversion into other forms of energy (e.g. potential, thermal, chemical or magnetic energy). The grids must be precisely balanced in real time and it must be made sure that the cost of electricity is the lowest possible. Storage of electricity has many advantages, in centralized mass storages used for the management of the transmission network, or in decentralized storages of smaller dimensions. This article presents an overview of the storage technologies: mechanical storage in hydroelectric and pumped storage power stations, compressed air energy storage (CAES), flywheels accumulating kinetic energy, electrochemical batteries with various technologies, traditional lead acid batteries, lithium ion, sodium sulfur (NaS) and others, including vehicle to grid, sensible heat thermal storage, superconducting magnetic energy storage (SMES), super-capacitors, conversion into hydrogen... The different technologies are compared in terms of cost and level of maturity. The development of intermittent renewable energies will result in a growing need for mechanisms to regulate energy flow and innovative energy storage solutions seem well positioned to develop. (author)

Double-layer capacitors with a higher energy density; Doppelschichtkondensatoren mit hoeherem Energieinhalt

Energy Technology Data Exchange (ETDEWEB)

Presser, Volker [Leibniz-Institut fuer Neue Materialien (INM) gGmbH, Saarbruecken (Germany). Juniorforschungs-Gruppe Energie-Materialien; Universitaet des Saarlandes, Saarbruecken (Germany)

2013-05-15

Electrical double-layer capacitors, also known as supercapacitors (SC) are devices for electrical energy storage used for fast acceleration of hybrid cars or for the energy recovery during breaking operations. In contrast, lithium-ion batteries (LIB) are used as energy storage devices to provide an extended travel distance for plug-in hybrid cars and electric vehicles. Current research aims to overcome the major limitations of both technologies (SC: low energy density/LIB: slow recharge and limited service life) and hybrid cells are considered a promising solution. The goal is to improve the performance and energy density of storage devices which can be achieved, as shown by the Leibniz-Institute for New Materials (INM), with the use of nanotechnology. (orig.)

Lithium-ion storage capacitors achieved by CVD graphene/TaC/Ta-wires and carbon hollow spheres

International Nuclear Information System (INIS)

Zhao, Liwei; Li, Hongji; Li, Mingji; Xu, Sheng; Li, Cuiping; Qu, Changqing; Zhang, Lijun; Yang, Baohe

2016-01-01

Highlights: • Graphene/TaC/Ta wire electrode was prepared by CVD. • Carbon hollow spheres as a solid electrolyte were prepared by hydrothermal. • Specific capacitance of assembled capacitor reached 593 F g −1 at 10 A g −1 . • The capacitor provided high energy and power densities (132 W h kg −1 /3.17 kW kg −1 ). • The hybrid capacitor also exhibited a high stability during long endurance tests. - Abstract: Lithium-ion storage capacitors were assembled using graphene/tantalum carbide/tantalum wire electrodes and carbon hollow spheres as electrolyte. The graphene/tantalum carbide layers were prepared by electron-assisted hot filament chemical vapor deposition; the carbon hollow spheres were synthesized by hydrothermal reaction and pyrolysis treatment. The specific capacitance of the capacitor was 593 F g −1 at a current density of 10 A g −1 . The capacitor showed excellent cycling stability, retaining 91.2% of its initial capacitance after 8000 cycles. Moreover, the capacitor provided a high specific energy density of 132 W h kg −1 at a high power density of 3.17 kW kg −1 . The high energy density is attributed to the widened operation window ranging from 0 to 3.0 V. The graphene layer of the electrode and carbon hollow spheres in electrolyte synergistic affect influence on the electrochemical performance of the capacitor are discussed. In addition, the use of a low-cost lithium salt, lithium chloride, is also featured in this paper.

Designing and Testing Composite Energy Storage Systems for Regulating the Outputs of Linear Wave Energy Converters

Directory of Open Access Journals (Sweden)

Zanxiang Nie

2017-01-01

Full Text Available Linear wave energy converters generate intrinsically intermittent power with variable frequency and amplitude. A composite energy storage system consisting of batteries and super capacitors has been developed and controlled by buck-boost converters. The purpose of the composite energy storage system is to handle the fluctuations and intermittent characteristics of the renewable source, and hence provide a steady output power. Linear wave energy converters working in conjunction with a system composed of various energy storage devices, is considered as a microsystem, which can function in a stand-alone or a grid connected mode. Simulation results have shown that by applying a boost H-bridge and a composite energy storage system more power could be extracted from linear wave energy converters. Simulation results have shown that the super capacitors charge and discharge often to handle the frequent power fluctuations, and the batteries charge and discharge slowly for handling the intermittent power of wave energy converters. Hardware systems have been constructed to control the linear wave energy converter and the composite energy storage system. The performance of the composite energy storage system has been verified in experiments by using electronics-based wave energy emulators.

A combined theoretical and experimental approach of a new ternary metal oxide in molybdate composite for hybrid energy storage capacitors

Science.gov (United States)

Minakshi, M.; Watcharatharapong, T.; Chakraborty, S.; Ahuja, R.

2018-04-01

Sustainable energy sources require an efficient energy storage system possessing excellent electrochemical properties. The better understanding of possible crystal configurations and the development of a new ternary metal oxide in molybdate composite as an electrode for hybrid capacitors can lead to an efficient energy storage system. Here, we reported a new ternary metal oxide in molybdate composite [(Mn1/3Co1/3Ni1/3)MoO4] prepared by simple combustion synthesis with an extended voltage window (1.8 V vs. Carbon) resulting in excellent specific capacity 35 C g-1 (58 F g-1) and energy density (50 Wh kg-1 at 500 W kg-1) for a two electrode system in an aqueous NaOH electrolyte. The binding energies measured for Mn, Co, and Ni 2p are consistent with the literature, and with the metal ions being present as M(II), implying that the oxidation states of the transition metals are unchanged. The experimental findings are correlated well through density functional theory based electronic structure calculations. Our reported work on the ternary metal oxide studies (Mn1/3Co1/3Ni1/3)MoO4 suggests that will be an added value to the materials for energy storage.

Energy storage and transfer with homopolar machine for a linear theta-pinch hybrid reactor

International Nuclear Information System (INIS)

Vogel, H.F.; Brennan, M.; Dase, W.G.; Tolk, K.M.; Weldon, W.F.

1975-12-01

This report describes the energy storage and transfer system for the compression coil system of a linear theta-pinch hybrid reactor (LTPHR). High efficiency and low cost are the principal requirements for the energy storage and transfer of 25 MJ/m or 25 GJ for a 1-km LTPHR. The circuit efficiency must be approximately 90 percent, and the cost for the circuit 5 to 6 cents/J. Scaling laws and simple relationships between circuit efficiency and cost per unit energy as a function of the half cycle time are presented. Capacitors and homopolor machines are considered as energy storage elements with both functioning basically as capacitors. The advantage of the homopolar machine in this application is its relatively low cost, whereas that of capacitors is better efficiency

ARRA-Multi-Level Energy Storage and Controls for Large-Scale Wind Energy Integration

Energy Technology Data Exchange (ETDEWEB)

David Wenzhong Gao

2012-09-30

The Project Objective is to design innovative energy storage architecture and associated controls for high wind penetration to increase reliability and market acceptance of wind power. The project goals are to facilitate wind energy integration at different levels by design and control of suitable energy storage systems. The three levels of wind power system are: Balancing Control Center level, Wind Power Plant level, and Wind Power Generator level. Our scopes are to smooth the wind power fluctuation and also ensure adequate battery life. In the new hybrid energy storage system (HESS) design for wind power generation application, the boundary levels of the state of charge of the battery and that of the supercapacitor are used in the control strategy. In the controller, some logic gates are also used to control the operating time durations of the battery. The sizing method is based on the average fluctuation of wind profiles of a specific wind station. The calculated battery size is dependent on the size of the supercapacitor, state of charge of the supercapacitor and battery wear. To accommodate the wind power fluctuation, a hybrid energy storage system (HESS) consisting of battery energy system (BESS) and super-capacitor is adopted in this project. A probability-based power capacity specification approach for the BESS and super-capacitors is proposed. Through this method the capacities of BESS and super-capacitor are properly designed to combine the characteristics of high energy density of BESS and the characteristics of high power density of super-capacitor. It turns out that the super-capacitor within HESS deals with the high power fluctuations, which contributes to the extension of BESS lifetime, and the super-capacitor can handle the peaks in wind power fluctuations without the severe penalty of round trip losses associated with a BESS. The proposed approach has been verified based on the real wind data from an existing wind power plant in Iowa. An

Energy Storage Systems

Science.gov (United States)

Elliott, David

2017-07-01

As renewable energy use expands there will be a need to develop ways to balance its variability. Storage is one of the options. Presently the main emphasis is for systems storing electrical power in advanced batteries (many of them derivatives of parallel developments in the electric vehicle field), as well as via liquid air storage, compressed air storage, super-capacitors and flywheels, and, the leader so far, pumped hydro reservoirs. In addition, new systems are emerging for hydrogen generation and storage, feeding fuel cell power production. Heat (and cold) is also a storage medium and some systems exploit thermal effects as part of wider energy management activity. Some of the more exotic ones even try to use gravity on a large scale. This short book looks at all the options, their potentials and their limits. There are no clear winners, with some being suited to short-term balancing and others to longer-term storage. The eventual mix adopted will be shaped by the pattern of development of other balancing measures, including smart-grid demand management and super-grid imports and exports.

Can ionophobic nanopores enhance the energy storage capacity of electric-double-layer capacitors containing nonaqueous electrolytes?

International Nuclear Information System (INIS)

Lian, Cheng; University of California, Riverside, CA; Liu, Honglai; Henderson, Douglas; Wu, Jianzhong

2016-01-01

The ionophobicity effect of nanoporous electrodes on the capacitance and the energy storage capacity of nonaqueous-electrolyte supercapacitors is studied by means of the classical density functional theory (DFT). It has been hypothesized that ionophobic nanopores may create obstacles in charging, but they store energy much more efficiently than ionophilic pores. In this paper, we find that, for both ionic liquids and organic electrolytes, an ionophobic pore exhibits a charging behavior different from that of an ionophilic pore, and that the capacitance–voltage curve changes from a bell shape to a two-hump camel shape when the pore ionophobicity increases. For electric-double-layer capacitors containing organic electrolytes, an increase in the ionophobicity of the nanopores leads to a higher capacity for energy storage. Without taking into account the effects of background screening, the DFT predicts that an ionophobic pore containing an ionic liquid does not enhance the supercapacitor performance within the practical voltage ranges. However, by using an effective dielectric constant to account for ion polarizability, the DFT predicts that, like an organic electrolyte, an ionophobic pore with an ionic liquid is also able to increase the energy stored when the electrode voltage is beyond a certain value. We find that the critical voltage for an enhanced capacitance in an ionic liquid is larger than that in an organic electrolyte. Finally, our theoretical predictions provide further understanding of how chemical modification of porous electrodes affects the performance of supercapacitors.

Electricity storage - A challenge for energy transition

International Nuclear Information System (INIS)

Bart, Jean-Baptiste; Nekrasov, Andre; Pastor, Emmanuel; Benefice, Emmanuel; Brincourt, Thierry; Cagnac, Albannie; Brisse, Annabelle; Jeandel, Elodie; Lefebvre, Thierry; Penneau, Jean-Francois; Radvanyi, Etienne; Delille, Gautier; Hinchliffe, Timothee; Lancel, Gilles; Loevenbruck, Philippe; Soler, Robert; Stevens, Philippe; Torcheux, Laurent

2017-01-01

After a presentation of the energetic context and of its issues, this collective publication proposes presentations of various electricity storage technologies with a distinction between direct storage, thermal storage and hydrogen storage. As far as direct storage is concerned, the following options are described: pumped energy transfer stations or PETS, compressed air energy storage or CAES, flywheels, various types of electrochemical batteries (lead, alkaline, sodium, lithium), metal air batteries, redox flow batteries, and super-capacitors. Thermal storage comprises power-to-heat and heat-to-power technologies. Hydrogen can be stored under different forms (compressed gas, liquid), in saline underground cavities, or by using water electrolysis and fuel cells. The authors propose an overview of the different services provided by energy storage to the electricity system, and discuss the main perspectives and challenges for tomorrow's storage (electric mobility, integration of renewable energies, electrification of isolated areas, scenarios of development)

Pseudocapacitive Oxides and Sulfides for High-Performance Electrochemical Energy Storage

KAUST Repository

Xia, Chuan

2018-01-01

The intermittent nature of several sustainable energy sources such as solar and wind energy has ignited the demand of electrochemical energy storage devices in the form of batteries and electrochemical capacitors. The future generation

Long vs. short-term energy storage:sensitivity analysis.

Energy Technology Data Exchange (ETDEWEB)

Schoenung, Susan M. (Longitude 122 West, Inc., Menlo Park, CA); Hassenzahl, William V. (,Advanced Energy Analysis, Piedmont, CA)

2007-07-01

This report extends earlier work to characterize long-duration and short-duration energy storage technologies, primarily on the basis of life-cycle cost, and to investigate sensitivities to various input assumptions. Another technology--asymmetric lead-carbon capacitors--has also been added. Energy storage technologies are examined for three application categories--bulk energy storage, distributed generation, and power quality--with significant variations in discharge time and storage capacity. Sensitivity analyses include cost of electricity and natural gas, and system life, which impacts replacement costs and capital carrying charges. Results are presented in terms of annual cost, $/kW-yr. A major variable affecting system cost is hours of storage available for discharge.

Storage and Dissipation Limits in Resonant Switched-Capacitor Converters

Directory of Open Access Journals (Sweden)

Jonathan C. Mayo-Maldonado

2018-01-01

Full Text Available The purpose of this manuscript is twofold, first we introduce an energy-based modeling framework for the analysis of resonant switched-capacitor (SC converters and second we demonstrate that energy storage and dissipation in resonant SC with ideal switches are bounded by a fundamental physical limit that, up until now, has been only associated with the special case of pure SC topologies. For instance, we show that the maximum energy stored in the small size inductors in resonant SC converters is equal to the energy that would be dissipated by their purely SC counterpart. The presented analysis permits the computation of resonant inductances in terms of maximum current peak values, which is experimentally validated. Furthermore, we introduce a relative loss factor that permits determining the efficiency of a design for a general case in the presence of parasitic resistances. These results corroborate that migrating to resonant SC technologies is one of the most compelling alternatives to overcome well-known disadvantages in pure SC topologies.

Pseudo-capacitor device for aqueous electrolytes

Science.gov (United States)

Prakash, Jai; Thackeray, Michael M.; Dees, Dennis W.; Vissers, Donald R.; Myles, Kevin M.

1998-01-01

A pseudo-capacitor having a high energy storage capacity develops a double layer capacitance as well as a Faradaic or battery-like redox reaction, also referred to as pseudo-capacitance. The Faradaic reaction gives rise to a capacitance much greater than that of the typical ruthenate oxide ultracapacitor which develops only charge separation-based double layer capacitance. The capacitor employs a lead and/or bismuth/ruthenate and/or iridium system having the formula A.sub.2 ›B.sub.2-x Pb.sub.x !O.sub.7-y, where A=Pb, Bi, and B=Ru, Ir, and Ocapacitor. The amount of expensive ruthenate and iridium can be substantially reduced in the pseudo-capacitor by increasing the lead content while improving energy storage capacity.

Graphene Based Ultra-Capacitors for Safer, More Efficient Energy Storage

Science.gov (United States)

Roberson, Luke B.; Mackey, Paul J.; Zide, Carson J.

2016-01-01

Current power storage methods must be continuously improved in order to keep up with the increasingly competitive electronics industry. This technological advancement is also essential for the continuation of deep space exploration. Today's energy storage industry relies heavily on the use of dangerous and corrosive chemicals such as lithium and phosphoric acid. These chemicals can prove hazardous to the user if the device is ruptured. Similarly they can damage the environment if they are disposed of improperly. A safer, more efficient alternative is needed across a wide range of NASA missions. One solution would a solid-state carbon based energy storage device. Carbon is a safer, less environmentally hazardous alternative to current energy storage materials. Using the amorphous carbon nanostructure, graphene, this idea of a safer portable energy is possible. Graphene was electrochemically produced in the lab and several coin cell devices were built this summer to create a working prototype of a solid-state graphene battery.

Ultra-capacitors in power conversion systems analysis, modeling and design in theory and practice

CERN Document Server

Grbovic, Petar J

2014-01-01

Divided into five parts, this book is focused on ultra-capacitors and their applications in power conversion systems. It discusses ultra-capacitor analysis, modelling and module design from a macroscopic (application) perspective. It also describes power conversion applications, interface dc-dc converter design and entire conversion system design. Part One covers the background of energy storage technologies, with particular attention on state-of-the-art ultra-capacitor energy storage technologies. In Chapter four of this part, power conversion systems with integrated energy storage is discus

The stationary storage of energy. Available technologies and CEA researches

International Nuclear Information System (INIS)

2012-01-01

After a discussion of the main challenges related to the stationary storage of energy, this publication proposes an overview of the different available technologies: plant for transfer of energy by pumping, compressed air, energy flywheels, hydrogen, lithium-ion battery, redox-flow battery, thermal storage by sensitive heat, thermal-chemical storage coupled to a thermal solar system, thermal storage by phase change, superconductive inductance storage, super-capacitors. It discusses the criteria of choice of storage technology, either for electric energy storage or for heat storage. It proposes an overview of researches performed within the CEA on storage systems: electrochemical, thermal, and hydrogen-based storages. The final chapter addresses current fundamental researches on storage in the field of lithium-ion batteries, hydrogen as a fuel, and thermoelectricity

Multifunctional Carbon Nanostructures for Advanced Energy Storage Applications

Directory of Open Access Journals (Sweden)

Yiran Wang

2015-05-01

Full Text Available Carbon nanostructures—including graphene, fullerenes, etc.—have found applications in a number of areas synergistically with a number of other materials. These multifunctional carbon nanostructures have recently attracted tremendous interest for energy storage applications due to their large aspect ratios, specific surface areas, and electrical conductivity. This succinct review aims to report on the recent advances in energy storage applications involving these multifunctional carbon nanostructures. The advanced design and testing of multifunctional carbon nanostructures for energy storage applications—specifically, electrochemical capacitors, lithium ion batteries, and fuel cells—are emphasized with comprehensive examples.

High energy density capacitors fabricated by thin film technology

International Nuclear Information System (INIS)

Barbee, T W; Johnson, G W; Wagner, A V.

1999-01-01

Low energy density in conventional capacitors severely limits efforts to miniaturize power electronics and imposes design limitations on electronics in general. We have successfully applied physical vapor deposition technology to greatly increase capacitor energy density. The high dielectric breakdown strength we have achieved in alumina thin films allows high energy density to be achieved with this moderately low dielectric constant material. The small temperature dependence of the dielectric constant, and the high reliability, high resistivity, and low dielectric loss of Al 2 O 3 , make it even more appealing. We have constructed single dielectric layer thin film capacitors and shown that they can be stacked to form multilayered structures with no loss in yield for a given capacitance. Control of film growth morphology is critical for achieving the smooth, high quality interfaces between metal and dielectric necessary for device operation at high electric fields. Most importantly, high rate deposition with extremely low particle generation is essential for achieving high energy storage at a reasonable cost. This has been achieved by reactive magnetron sputtering in which the reaction to form the dielectric oxide has been confined to the deposition surface. By this technique we have achieved a yield of over 50% for 1 cm 2 devices with an energy density of 14 J per cubic centimeter of Al 2 O 3 dielectric material in 1.2 kV, 4 nF devices. By further reducing defect density and increasing the dielectric constant of the material, we will be able to increase capacitance and construct high energy density devices to meet the requirements of applications in power electronics

Possible Lead Free Nanocomposite Dielectrics for High Energy Storage Applications

Directory of Open Access Journals (Sweden)

Srinivas Kurpati

2017-03-01

Full Text Available There is an increasing demand to improve the energy density of dielectric capacitors for satisfying the next generation material systems. One effective approach is to embed high dielectric constant inclusions such as lead zirconia titanate in polymer matrix. However, with the increasing concerns on environmental safety and biocompatibility, the need to expel lead (Pb from modern electronics has been receiving more attention. Using high aspect ratio dielectric inclusions such as nanowires could lead to further enhancement of energy density. Therefore, the present brief review work focuses on the feasibility of development of a lead-free nanowire reinforced polymer matrix capacitor for energy storage application. It is expected that Lead-free sodium Niobate nanowires (NaNbO3 and Boron nitride will be a future candidate to be synthesized using simple hydrothermal method, followed by mixing them with polyvinylidene fluoride (PVDF/ divinyl tetramethyl disiloxanebis (benzocyclobutene matrix using a solution-casting method for Nanocomposites fabrication. The energy density of NaNbO3 and BN based composites are also be compared with that of lead-containing (PbTiO3/PVDF Nano composites to show the feasibility of replacing lead-containing materials from high-energy density dielectric capacitors. Further, this paper explores the feasibility of these materials for space applications because of high energy storage capacity, more flexibility and high operating temperatures. This paper is very much useful researchers who would like to work on polymer nanocomposites for high energy storage applications.

Pulsed power inductive energy storage in the microsecond range

International Nuclear Information System (INIS)

Rix, W.; Miller, A.R.; Thompson, J.; Waisman, E.; Wilkinson, M.; Wilson, A.

1993-01-01

During the past five years Maxwell has developed a series of inductive energy storage (IES) pulsed power generators; ACE 1, ACE 2, ACE 3, and ACE 4, to drive electron-beam loads. They are all based on a plasma opening switch (POS) contained in a single vacuum envelope operating at conduction times of around one microsecond. They all employ fast capacitor bank technology to match this conduction time without intermediate power conditioning. Oil or air filled transmission lines transfer capacitor bank energy to a vacuum section where the final pulse compression is accomplished. Development of the ACE series is described, emphasizing capacitor bank and the opening switch technology for delivering high voltage, multimegampere pulses to electron beam loads

Status of electrical energy storage systems

Energy Technology Data Exchange (ETDEWEB)

NONE

2004-07-01

This report presents an overview of the status of electrical storage systems in the light of the growing use of renewable energy sources and distributed generation (DG) in meeting emission targets and in the interest of the UK electricity supply industry. Examples of storage technologies, their applications and current status are examined along with technical issues and possible activities by UK industries. Details are given of development opportunities in the fields of flow cells, advanced batteries - lithium batteries, high temperature batteries, flywheels, and capacitors. Power conversion systems and system integration, the all-electric ship project, and compressed air energy storage are discussed. Opportunities for development and deployment, small scale systems, demonstration programmes, and research and development issues are considered. An outline of the US Department of Energy Storage programme is given in the Annex to the report.

High Tc superconducting energy storage systems

Energy Technology Data Exchange (ETDEWEB)

Werfel, Frank [Adelwitz Technologiezentrum GmbH (ATZ), Arzberg-Adelwitz (Germany)

2012-07-01

Electric energy is basic to heat and light our homes, to power our businesses and to transport people and goods. Powerful storage techniques like SMES, Flywheel, Super Capacitor, and Redox - Flow batteries are needed to increase the overall efficiency, stability and quality of electrical grids. High-Tc superconductors (HTS) possess superior physical and technical properties and can contribute in reducing the dissipation and losses in electric machines as motors and generators, in electric grids and transportation. The renewable energy sources as solar, wind energy and biomass will require energy storage systems even more as a key technology. We survey the physics and the technology status of superconducting flywheel energy storage (FESS) and magnetic energy storage systems (SMES) for their potential of large-scale commercialization. We report about a 10 kWh / 250 kW flywheel with magnetic stabilization of the rotor. The progress of HTS conductor science and technological engineering are basic for larger SMES developments. The performance of superconducting storage systems is reviewed and compared. We conclude that a broad range of intensive research and development in energy storage is urgently needed to produce technological options that can allow both climate stabilization and economic development.

High Energy Density Aqueous Electrochemical Capacitors with a KI-KOH Electrolyte.

Science.gov (United States)

Wang, Xingfeng; Chandrabose, Raghu S; Chun, Sang-Eun; Zhang, Tianqi; Evanko, Brian; Jian, Zelang; Boettcher, Shannon W; Stucky, Galen D; Ji, Xiulei

2015-09-16

We report a new electrochemical capacitor with an aqueous KI-KOH electrolyte that exhibits a higher specific energy and power than the state-of-the-art nonaqueous electrochemical capacitors. In addition to electrical double layer capacitance, redox reactions in this device contribute to charge storage at both positive and negative electrodes via a catholyte of IOx-/I- couple and a redox couple of H2O/Had, respectively. Here, we, for the first time, report utilizing IOx-/I- redox couple for the positive electrode, which pins the positive electrode potential to be 0.4-0.5 V vs Ag/AgCl. With the positive electrode potential pinned, we can polarize the cell to 1.6 V without breaking down the aqueous electrolyte so that the negative electrode potential could reach -1.1 V vs Ag/AgCl in the basic electrolyte, greatly enhancing energy storage. Both mass spectroscopy and Raman spectrometry confirm the formation of IO3- ions (+5) from I- (-1) after charging. Based on the total mass of electrodes and electrolyte in a practically relevant cell configuration, the device exhibits a maximum specific energy of 7.1 Wh/kg, operates between -20 and 50 °C, provides a maximum specific power of 6222 W/kg, and has a stable cycling life with 93% retention of the peak specific energy after 14,000 cycles.

Multidimensional materials and device architectures for future hybrid energy storage

Science.gov (United States)

Lukatskaya, Maria R.; Dunn, Bruce; Gogotsi, Yury

2016-09-01

Electrical energy storage plays a vital role in daily life due to our dependence on numerous portable electronic devices. Moreover, with the continued miniaturization of electronics, integration of wireless devices into our homes and clothes and the widely anticipated `Internet of Things', there are intensive efforts to develop miniature yet powerful electrical energy storage devices. This review addresses the cutting edge of electrical energy storage technology, outlining approaches to overcome current limitations and providing future research directions towards the next generation of electrical energy storage devices whose characteristics represent a true hybridization of batteries and electrochemical capacitors.

An Improved Genetic Algorithm for Optimal Stationary Energy Storage System Locating and Sizing

OpenAIRE

Bin Wang; Zhongping Yang; Fei Lin; Wei Zhao

2014-01-01

The application of a stationary ultra-capacitor energy storage system (ESS) in urban rail transit allows for the recuperation of vehicle braking energy for increasing energy savings as well as for a better vehicle voltage profile. This paper aims to obtain the best energy savings and voltage profile by optimizing the location and size of ultra-capacitors. This paper firstly raises the optimization objective functions from the perspectives of energy savings, regenerative braking cancellation a...

Flywheel energy storage; Schwungmassenspeicher

Energy Technology Data Exchange (ETDEWEB)

Bornemann, H.J. [Forschungszentrum Karlsruhe GmbH Technik und Umwelt (Germany)

1996-12-31

Energy storages may be chemical systems such as batteries, thermal systems such as hot-water tanks, electromagnetic systems such as capacitors and coils, or mechanical systems such as pumped storage power systems or flywheel energy storages. In flywheel energy storages the energy is stored in the centrifugal mass in the form of kinetic energy. This energy can be converted to electricity via a motor/generator unit and made available to the consumer. The introduction of magnetic bearings has greatly enhanced the potential of flywheel energy storages. As there is no contact between the moving parts of magnetic bearings, this technology provides a means of circumventing the engineering and operational problems involved in the we of conventional bearings (ball, roller, plain, and gas bearings). The advantages of modern flywheel energy storages over conventional accumulators are an at least thousandfold longer service life, low losses during long-time storage, greater power output in the case of short-time storage, and commendable environmental benignity. (orig./HW) [Deutsch] Als Enegiespeicher kommen chemische Systeme, z.B. Batterien, thermische Systeme, z.B. Warmwassertanks, elektromagnetische Systeme, z.B. Kondensatoren und Spulen, sowie mechanische Systeme, z.B. Pumpspeicherwerke und Schwungmassenspeicher in Frage. In einem Schwungmassenspeicher wird Energie in Form von kinetischer Energie in der Schwungmasse gespeichert. Ueber eine Moter/Generator Einheit wird diese Energie in elektrischen Strom umgewandelt und dem Verbraucher zugefuehrt. Mit der Einfuehrung von magnetischen Lagern konnte die Leistungsfaehigkeit von Schwungmassenspeichern erheblich gesteigert werden. Da in einem Magnetlager keine Beruehrung zwischen sich bewegenden Teilen besteht, wird ein Grossteil der mit dem Einsatz konventioneller Lager (Kugel- und Rollenlager, Gleitlager und Gaslager) verbundenen ingenieurtechnischen und betriebstechnischen Probleme vermieden. Die Vorteile von modernen

Li-Ion, Ultra-capacitor Based Hybrid Energy Module

National Research Council Canada - National Science Library

Daboussi, Zaher; Paryani, Anil; Khalil, Gus; Catherino, Henry; Gargies, Sonya

2007-01-01

.... To determine the optimum utilization of ultra-capacitors in applications where high power density and high energy density are required, an optimized Li-Ion/Ultra-capacitor Hybrid Energy Module (HEM...

Energy Conversion and Storage Requirements for Hybrid Electric Aircraft

Science.gov (United States)

Misra, Ajay

2016-01-01

Among various options for reducing greenhouse gases in future large commercial aircraft, hybrid electric option holds significant promise. In the hybrid electric aircraft concept, gas turbine engine is used in combination with an energy storage system to drive the fan that propels the aircraft, with gas turbine engine being used for certain segments of the flight cycle and energy storage system being used for other segments. The paper will provide an overview of various energy conversion and storage options for hybrid electric aircraft. Such options may include fuel cells, batteries, super capacitors, multifunctional structures with energy storage capability, thermoelectric, thermionic or a combination of any of these options. The energy conversion and storage requirements for hybrid electric aircraft will be presented. The role of materials in energy conversion and storage systems for hybrid electric aircraft will be discussed.

Electromechanical capacitor for energy transfer

International Nuclear Information System (INIS)

Carroll, T.A.; Chowdhuri, P.; Marshall, J.

1983-01-01

Inductive energy transfer between two magnets can be achieved with almost 100% efficiency with a transfer capacitor. However, the bulk and cost will be high, and reliability low if conventional capacitors are used. A homopolar machine, used as a capacitor, will be compact and economical. A homopolar machine was designed with counter-rotating copper disks completely immersed in a liquid metal (NaK-78) to work as a pulse capacitor. Absence of solid-brush collectors minimized wear and frictional losses. Wetting of the copper disks throughout the periphery by the liquid metal minimized the resistive losses at the collector interface. A liquid-metal collector would, however, introduce hydrodynamic and magnetohydrodynamic losses. The selected liquid metal, e.g., NaK-78 will produce the lowest of such losses among the available liquid metals. An electromechanical capacitor of this design was tested at various dc magnetic fields. Its measured capacitance was about 100 farads at a dc magnetic field of 1.15 tesla

Energy Storage of Polyarylene Ether Nitriles at High Temperature

Science.gov (United States)

Tang, Xiaohe; You, Yong; Mao, Hua; Li, Kui; Wei, Renbo; Liu, Xiaobo

2018-03-01

Polyarylene ether nitrile (PEN) was synthesized and used as film capacitors for energy storage at high temperature. Scanning electron microscopy observation indicated that the films of PEN have pinholes at nanoscales which restricted the energy storage properties of the material. The pinhole shadowing effect through which the energy storage properties of PEN were effectively improved to be 2.3 J/cm3 was observed by using the overlapped film of PEN. The high glass transition temperature (T g) of PEN was as high as 216 °C and PEN film showed stable dielectric constant, breakdown strength and energy storage density before the T g. The PEN films will be a potential candidate as high performance electronic storage materials used at high temperature.

New energy storage systems for photovoltaic supplied consumer products

International Nuclear Information System (INIS)

Burges, K.; Blok, K.

1993-12-01

In a previous study attention was paid to the possibility of reducing battery wastes in the Netherlands by means of integration of photovoltaic (PV) cells in small, electric consumer products. The result of that study was that only two environment-friendly applications could be used: capacitors in calculators or watches. However, new types of energy storage systems have been developed and commercialized, so that the above-mentioned study is updated. First, the technical, economic and environmental parameters of several energy storage systems are compared. Next, a number of products, in which PV-cells can be integrated, has been selected and the economic and environmental effects are calculated and analyzed. The energy storage systems discussed are primary alkaline batteries, NiCd batteries, Ni-Metal-Hydride (NiMH) batteries, Li-Solid-State (LiSS) batteries, and capacitors. It is estimated that by means of the proposed integration of PV-cells in specific consumer products the amount of battery wastes can be reduced by 50%. 33 tabs., 1 appendix, 50 refs

An Improved Genetic Algorithm for Optimal Stationary Energy Storage System Locating and Sizing

Directory of Open Access Journals (Sweden)

Bin Wang

2014-10-01

Full Text Available The application of a stationary ultra-capacitor energy storage system (ESS in urban rail transit allows for the recuperation of vehicle braking energy for increasing energy savings as well as for a better vehicle voltage profile. This paper aims to obtain the best energy savings and voltage profile by optimizing the location and size of ultra-capacitors. This paper firstly raises the optimization objective functions from the perspectives of energy savings, regenerative braking cancellation and installation cost, respectively. Then, proper mathematical models of the DC (direct current traction power supply system are established to simulate the electrical load-flow of the traction supply network, and the optimization objections are evaluated in the example of a Chinese metro line. Ultimately, a methodology for optimal ultra-capacitor energy storage system locating and sizing is put forward based on the improved genetic algorithm. The optimized result shows that certain preferable and compromised schemes of ESSs’ location and size can be obtained, acting as a compromise between satisfying better energy savings, voltage profile and lower installation cost.

Process Optimization of P(VDF-TrFE)-BaTiO3 Nanocomposites for Storage Capacitor Applications

KAUST Repository

Almadhoun, Mahmoud N.

2011-07-11

Increasing demands for efficient energy storage in microelectronics has pushed the scientific community towards finding suitable materials that can effectively deliver high pulse power in miniaturized systems. Polymer-ceramic composites are considered to be one possible solution towards the fabrication of high energy density capacitors, whether as embedded capacitors or gate insulators in organic field effect transistors (OFETs). Selecting high permittivity ceramics mixed with polymers with high breakdown field strengths would be the wisest approach towards enhancing energy storage. As such, novel ferroelectric polymers such as P(VDF-TrFE-CTFE) are being developed and researched, all displaying record dielectric values (K > 50) as promising candidates for high energy density composite capacitors (> 25 J/cm3). However, much work is still needed to understand the interaction mechanisms between the phases. We aim to seek an understanding of the processing challenges, especially in terms of fabricating thin film ferroelectric polymers and their application in nanocomposite capacitors while effectively maintaining optimized performance when embedded in flexible electronics. A process for synthesizing high performance P(VDF-TrFE) thin films is developed realizing the importance of controlling several process parameters to achieve high quality devices. Electrical and physicochemical characterization demonstrate how the performance of the polymer films improves with prolonged annealing periods by allowing sufficient time for solvent evaporation, crystallization and preferential-orientation of the crystallites. The polymer P(VDF-TrFE) is then used as a host material with barium titanate (BTO) nanoparticles below 100 nm (K = 150) as a ceramic filler in nanocomposite films. Facile surface modification by hydroxylation proved to be essential in the performance of the devices in terms of leakage current. A decrease of approximately 2 orders of magnitude in current leakage is

A Two-terminal Active Capacitor

DEFF Research Database (Denmark)

Wang, Haoran; Wang, Huai

2017-01-01

This letter proposes a concept of two-terminal active capacitor implemented by power semiconductor switches and passive elements. The active capacitor has the same level of convenience as a passive one with two power terminals only. It is application independent and can be specified by rated...... voltage, ripple current, equivalent series resistance, and operational frequency range. The concept, control method, self-power scheme, and impedance characteristics of the active capacitor are presented. A case study of the proposed active capacitor for a capacitive DC-link application is discussed....... The results reveal a significantly lower overall energy storage of passive elements and a reduced cost to fulfill a specific reliability target, compared to a passive capacitor solution. Proof-of-concept experimental results are given to verify the functionality of the proposed capacitor....

Flowable Conducting Particle Networks in Redox-Active Electrolytes for Grid Energy Storage

Energy Technology Data Exchange (ETDEWEB)

Hatzell, K. B.; Boota, M.; Kumbur, E. C.; Gogotsi, Y.

2015-01-01

This study reports a new hybrid approach toward achieving high volumetric energy and power densities in an electrochemical flow capacitor for grid energy storage. The electrochemical flow capacitor suffers from high self-discharge and low energy density because charge storage is limited to the available surface area (electric double layer charge storage). Here, we examine two carbon materials as conducting particles in a flow battery electrolyte containing the VO2+/VO2+ redox couple. Highly porous activated carbon spheres (CSs) and multi-walled carbon nanotubes (MWCNTs) are investigated as conducting particle networks that facilitate both faradaic and electric double layer charge storage. Charge storage contributions (electric double layer and faradaic) are distinguished for flow-electrodes composed of MWCNTs and activated CSs. A MWCNT flow-electrode based in a redox-active electrolyte containing the VO2+/VO2+ redox couple demonstrates 18% less self-discharge, 10 X more energy density, and 20 X greater power densities (at 20 mV s-1) than one based on a non-redox active electrolyte. Furthermore, a MWCNT redox-active flow electrode demonstrates 80% capacitance retention, and >95% coulombic efficiency over 100 cycles, indicating the feasibility of utilizing conducting networks with redox chemistries for grid energy storage.

Feasibility Study to Evaluate Candidate Materials of Nanofilled Block Copolymers for Use in Ultra High Density Pulsed Power Capacitors

Science.gov (United States)

2015-10-26

capacitor films showing the first-ever application of self-assembling BCPs as the nanostructured dielectric media in electrostatic capacitors . Using... dielectric media in electrostatic capacitors . Using controlled ordering of lamellae- forming BCPs via our cold zone annealing soft-shear (CZA-SS...fast energy storage and discharge capabilities. However, the energy storage density of these capacitors is limited by the dielectric properties of

Energy storage

International Nuclear Information System (INIS)

Odru, P.

2010-01-01

This book proposes a broad overview of the technologies developed in the domains of on-board electricity storage (batteries, super-capacitors, flywheels), stationary storage (hydraulic dams, compressed air, batteries and hydrogen), and heat storage (sensible, latent and sorption) together with their relative efficiency, their expected developments and what advantages they can offer. Eminent specialists of this domain have participated to the redaction of this book, all being members of the Tuck's Foundation 'IDees' think tank. (J.S.)

Barium titanate nanocomposite capacitor FY09 year end report.

Energy Technology Data Exchange (ETDEWEB)

Stevens, Tyler E.; DiAntonio, Christopher Brian; Yang, Pin; Chavez, Tom P.; Winter, Michael R.; Monson, Todd C.; Roesler, Alexander William; Fellows, Benjamin D.

2009-11-01

This late start RTBF project started the development of barium titanate (BTO)/glass nanocomposite capacitors for future and emerging energy storage applications. The long term goal of this work is to decrease the size, weight, and cost of ceramic capacitors while increasing their reliability. Ceramic-based nanocomposites have the potential to yield materials with enhanced permittivity, breakdown strength (BDS), and reduced strain, which can increase the energy density of capacitors and increase their shot life. Composites of BTO in glass will limit grain growth during device fabrication (preserving nanoparticle grain size and enhanced properties), resulting in devices with improved density, permittivity, BDS, and shot life. BTO will eliminate the issues associated with Pb toxicity and volatility as well as the variation in energy storage vs. temperature of PZT based devices. During the last six months of FY09 this work focused on developing syntheses for BTO nanoparticles and firing profiles for sintering BTO/glass composite capacitors.

Modeling of capacitor charging dynamics in an energy harvesting system considering accurate electromechanical coupling effects

Science.gov (United States)

Bagheri, Shahriar; Wu, Nan; Filizadeh, Shaahin

2018-06-01

This paper presents an iterative numerical method that accurately models an energy harvesting system charging a capacitor with piezoelectric patches. The constitutive relations of piezoelectric materials connected with an external charging circuit with a diode bridge and capacitors lead to the electromechanical coupling effect and the difficulty of deriving accurate transient mechanical response, as well as the charging progress. The proposed model is built upon the Euler-Bernoulli beam theory and takes into account the electromechanical coupling effects as well as the dynamic process of charging an external storage capacitor. The model is validated through experimental tests on a cantilever beam coated with piezoelectric patches. Several parametric studies are performed and the functionality of the model is verified. The efficiency of power harvesting system can be predicted and tuned considering variations in different design parameters. Such a model can be utilized to design robust and optimal energy harvesting system.

A Novel Degradation Estimation Method for a Hybrid Energy Storage System Consisting of Battery and Double-Layer Capacitor

Directory of Open Access Journals (Sweden)

Yuanbin Yu

2016-01-01

Full Text Available This paper presents a new method for battery degradation estimation using a power-energy (PE function in a battery/ultracapacitor hybrid energy storage system (HESS, and the integrated optimization which concerns both parameters matching and control for HESS has been done as well. A semiactive topology of HESS with double-layer capacitor (EDLC coupled directly with DC-link is adopted for a hybrid electric city bus (HECB. In the purpose of presenting the quantitative relationship between system parameters and battery serving life, the data during a 37-minute driving cycle has been collected and decomposed into discharging/charging fragments firstly, and then the optimal control strategy which is supposed to maximally use the available EDLC energy is presented to decompose the power between battery and EDLC. Furthermore, based on a battery degradation model, the conversion of power demand by PE function and PE matrix is applied to evaluate the relationship between the available energy stored in HESS and the serving life of battery pack. Therefore, according to the approach which could decouple parameters matching and optimal control of the HESS, the process of battery degradation and its serving life estimation for HESS has been summed up.

The role of nanomaterials in redox-based supercapacitors for next generation energy storage devices

Science.gov (United States)

Zhao, Xin; Sánchez, Beatriz Mendoza; Dobson, Peter J.; Grant, Patrick S.

2011-03-01

The development of more efficient electrical storage is a pressing requirement to meet future societal and environmental needs. This demand for more sustainable, efficient energy storage has provoked a renewed scientific and commercial interest in advanced capacitor designs in which the suite of experimental techniques and ideas that comprise nanotechnology are playing a critical role. Capacitors can be charged and discharged quickly and are one of the primary building blocks of many types of electrical circuit, from microprocessors to large-sale power supplies, but usually have relatively low energy storage capability when compared with batteries. The application of nanostructured materials with bespoke morphologies and properties to electrochemical supercapacitors is being intensively studied in order to provide enhanced energy density without comprising their inherent high power density and excellent cyclability. In particular, electrode materials that exploit physical adsorption or redox reactions of electrolyte ions are foreseen to bridge the performance disparity between batteries with high energy density and capacitors with high power density. In this review, we present some of the novel nanomaterial systems applied for electrochemical supercapacitors and show how material morphology, chemistry and physical properties are being tailored to provide enhanced electrochemical supercapacitor performance.

Performance Evaluation of Lower-Energy Energy Storage Alternatives for Full-Hybrid Vehicles; NREL (National Renewable Energy Laboratory)

Energy Technology Data Exchange (ETDEWEB)

Gonder, J.; Cosgrove, J.; Pesaran, A.

2014-02-11

Automakers have been mass producing hybrid electric vehicles (HEVs) for well over a decade, and the technology has proven to be very effective at reducing per-vehicle fuel use. However, the incremental cost of HEVs such as the Toyota Prius or Ford Fusion Hybrid remains several thousand dollars higher than the cost of comparable conventional vehicles, which has limited HEV market penetration. The b b b b battery energy storage device is typically the component with the greatest contribution toward this cost increment, so significant cost reductions/performance improvements to the energy storage system (ESS) can correspondingly improve the vehicle-level cost/benefit relationship. Such an improvement would in turn lead to larger HEV market penetration and greater aggregate fuel savings. The United States Advanced Battery Consortium (USABC) and the U.S. Department of Energy (DOE) Energy Storage Program managers asked the National Renewable Energy Laboratory (NREL) to collaborate with a USABC Workgroup and analyze the trade-offs between vehicle fuel economy and reducing the decade-old minimum energy requirement for power-assist HEVs. NREL’s analysis showed that significant fuel savings could still be delivered from an ESS with much lower energy storage than the previous targets, which prompted USABC to issue a new set of lower-energy ESS (LEESS) targets that could be satisfied by a variety of technologies. With support from DOE, NREL has developed an HEV test platform for in-vehicle performance and fuel economy validation testing of the hybrid system using such LEESS devices. This presentation describes development of the vehicle test platform, and laboratory as well as in-vehicle evaluation results with alternate energy storage configurations as compared to the production battery system. The alternate energy storage technologies considered include lithium-ion capacitors -- i.e., asymmetric electrochemical energy storage devices possessing one electrode with battery

Cascaded H-Bridge with Bidirectional Boost Converters for Energy Storage

DEFF Research Database (Denmark)

Trintis, Ionut; Munk-Nielsen, Stig; Teodorescu, Remus

2011-01-01

This paper presents the design and control of a cascaded H-bridge converter for energy storage with bidirectional boost converter as charge/discharge unit. The disadvantage of the second harmonic on the main energy storage unit as well as its voltage variation with the state of charge is solved...... by this structure. The independent phase grid control is proposed for this topology. This strategy is able to control the average dc-link voltage for each phase independently and to balance the cells capacitors voltages. The balance of the energy storage units is achieved by controlling independently each cell...

Supercapacitors: Ferroelectric Polymer-Ceramic Nanoparticle Composite Films for Use in the Capacitive Storage of Electrical Energy

Science.gov (United States)

Parsons, Dana; Pierce, Andrew; Porter, Tim; Dillingham, Randy; Cornelison, David

2010-03-01

Most new alternative energy solutions including wind and solar power, will require short term energy storage for widespread implementation. One means of storage would be the use of capacitors owing to their rapid delivery of power and longevity compared to chemical batteries. Capacitor materials exhibiting high dielectric permittivity and breakdown strength, as well as light weight and environmental safety are most desirable. Recently, new classes of capacitor dielectric materials, consisting of ferroelectric polymer matrices containing ceramic nanoparticles have attracted renewed interest due to their high potential energy storage, charge and discharge properties and lightweight. In this study, polyvinylidene flouride (PVDF) thin films containing nanoparticles of the ceramic titanium dioxide created using a physical vapor deposition process, are analyzed for use as dielectrics for a supercapacitor. Measured results of the film parameters including dielectric properties and breakdown voltages will be presented. These parameters will be analyzed with respect to film characteristics such as, dispersion of the ceramic particles, thickness of the films and composition ratios.

Integrated solar capacitors for energy conversion and storage

Institute of Scientific and Technical Information of China (English)

Ruiyuan Liu; Yuqiang Liu; Haiyang Zou; Tao Song; Baoquan Sun

2017-01-01

Solar energy is one of the most popular clean energy sources and is a promising alternative to fulfill the increasing energy demands of modern society.Solar cells have long been under intensive research attention for harvesting energy from sunlight with a high power-conversion efficiency and low cost.However,the power outputs of photovoltaic devices suffer from fluctuations due to the intermittent instinct of the solar radiation.Integrating solar cells and energystorage devices as self-powering systems may solve this problem through the simultaneous storage of the electricity and manipulation of the energy output.This review summarizes the research progress in the integration of new-generation solar cells with supercapacitors,with emphasis on the structures,materials,performance,and new design features.The current challenges and future prospects are discussed with the aim of expanding research and development in this field.

Fundamentally Addressing Bromine Storage through Reversible Solid-State Confinement in Porous Carbon Electrodes: Design of a High-Performance Dual-Redox Electrochemical Capacitor.

Science.gov (United States)

Yoo, Seung Joon; Evanko, Brian; Wang, Xingfeng; Romelczyk, Monica; Taylor, Aidan; Ji, Xiulei; Boettcher, Shannon W; Stucky, Galen D

2017-07-26

Research in electric double-layer capacitors (EDLCs) and rechargeable batteries is converging to target systems that have battery-level energy density and capacitor-level cycling stability and power density. This research direction has been facilitated by the use of redox-active electrolytes that add faradaic charge storage to increase energy density of the EDLCs. Aqueous redox-enhanced electrochemical capacitors (redox ECs) have, however, performed poorly due to cross-diffusion of soluble redox couples, reduced cycle life, and low operating voltages. In this manuscript, we propose that these challenges can be simultaneously met by mechanistically designing a liquid-to-solid phase transition of oxidized catholyte (or reduced anolyte) with confinement in the pores of electrodes. Here we demonstrate the realization of this approach with the use of bromide catholyte and tetrabutylammonium cation that induces reversible solid-state complexation of Br 2 /Br 3 - . This mechanism solves the inherent cross-diffusion issue of redox ECs and has the added benefit of greatly stabilizing the reactive bromine generated during charging. Based on this new mechanistic insight on the utilization of solid-state bromine storage in redox ECs, we developed a dual-redox EC consisting of a bromide catholyte and an ethyl viologen anolyte with the addition of tetrabutylammonium bromide. In comparison to aqueous and organic electric double-layer capacitors, this system enhances energy by factors of ca. 11 and 3.5, respectively, with a specific energy of ∼64 W·h/kg at 1 A/g, a maximum power density >3 kW/kg, and cycling stability over 7000 cycles.

Electrode/Dielectric Strip For High-Energy-Density Capacitor

Science.gov (United States)

Yen, Shiao-Ping S.

1994-01-01

Improved unitary electrode/dielectric strip serves as winding in high-energy-density capacitor in pulsed power supply. Offers combination of qualities essential for high energy density: high permittivity of dielectric layers, thinness, and high resistance to breakdown of dielectric at high electric fields. Capacitors with strip material not impregnated with liquid.

Low-Cost and High-Productivity Three-Dimensional Nanocapacitors Based on Stand-Up ZnO Nanowires for Energy Storage.

Science.gov (United States)

Wei, Lei; Liu, Qi-Xuan; Zhu, Bao; Liu, Wen-Jun; Ding, Shi-Jin; Lu, Hong-Liang; Jiang, Anquan; Zhang, David Wei

2016-12-01

Highly powered electrostatic capacitors based on nanostructures with a high aspect ratio are becoming critical for advanced energy storage technology because of their high burst power and energy storage capability. We report the fabrication process and the electrical characteristics of high capacitance density capacitors with three-dimensional solid-state nanocapacitors based on a ZnO nanowire template. Stand-up ZnO nanowires are grown face down on p-type Si substrates coated with a ZnO seed layer using a hydrothermal method. Stacks of AlZnO/Al2O3/AlZnO are then deposited sequentially on the ZnO nanowires using atomic layer deposition. The fabricated capacitor has a high capacitance density up to 92 fF/μm(2) at 1 kHz (around ten times that of the planar capacitor without nanowires) and an extremely low leakage current density of 3.4 × 10(-8) A/cm(2) at 2 V for a 5-nm Al2O3 dielectric. Additionally, the charge-discharge characteristics of the capacitor were investigated, indicating that the resistance-capacitance time constants were 550 ns for both the charging and discharging processes and the time constant was not dependent on the voltage. This reflects good power characteristics of the fabricated capacitors. Therefore, the current work provides an exciting strategy to fabricate low-cost and easily processable, high capacitance density capacitors for energy storage.

Nonlinear dielectric thin films for high-power electric storage with energy density comparable with electrochemical supercapacitors.

Science.gov (United States)

Yao, Kui; Chen, Shuting; Rahimabady, Mojtaba; Mirshekarloo, Meysam Sharifzadeh; Yu, Shuhui; Tay, Francis Eng Hock; Sritharan, Thirumany; Lu, Li

2011-09-01

Although batteries possess high energy storage density, their output power is limited by the slow movement of charge carriers, and thus capacitors are often required to deliver high power output. Dielectric capacitors have high power density with fast discharge rate, but their energy density is typically much lower than electrochemical supercapacitors. Increasing the energy density of dielectric materials is highly desired to extend their applications in many emerging power system applications. In this paper, we review the mechanisms and major characteristics of electric energy storage with electrochemical supercapacitors and dielectric capacitors. Three types of in-house-produced ferroic nonlinear dielectric thin film materials with high energy density are described, including (Pb(0.97)La(0.02))(Zr(0.90)Sn(0.05)Ti(0.05))O(3) (PLZST) antiferroelectric ceramic thin films, Pb(Zn(1/3)Nb(2/3))O(3-)Pb(Mg(1/3)Nb(2/3))O(3-)PbTiO(3) (PZN-PMN-PT) relaxor ferroelectric ceramic thin films, and poly(vinylidene fluoride) (PVDF)-based polymer blend thin films. The results showed that these thin film materials are promising for electric storage with outstandingly high power density and fairly high energy density, comparable with electrochemical supercapacitors.

Recent Advances in Porous Carbon Materials for Electrochemical Energy Storage.

Science.gov (United States)

Wang, Libin; Hu, Xianluo

2018-06-18

Climate change and the energy crisis have promoted the rapid development of electrochemical energy-storage devices. Owing to many intriguing physicochemical properties, such as excellent chemical stability, high electronic conductivity, and a large specific surface area, porous carbon materials have always been considering as a promising candidate for electrochemical energy storage. To date, a wide variety of porous carbon materials based upon molecular design, pore control, and compositional tailoring have been proposed for energy-storage applications. This focus review summarizes recent advances in the synthesis of various porous carbon materials from the view of energy storage, particularly in the past three years. Their applications in representative electrochemical energy-storage devices, such as lithium-ion batteries, supercapacitors, and lithium-ion hybrid capacitors, are discussed in this review, with a look forward to offer some inspiration and guidelines for the exploitation of advanced carbon-based energy-storage materials. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Peapod-like Li3 VO4 /N-Doped Carbon Nanowires with Pseudocapacitive Properties as Advanced Materials for High-Energy Lithium-Ion Capacitors.

Science.gov (United States)

Shen, Laifa; Lv, Haifeng; Chen, Shuangqiang; Kopold, Peter; van Aken, Peter A; Wu, Xiaojun; Maier, Joachim; Yu, Yan

2017-07-01

Lithium ion capacitors are new energy storage devices combining the complementary features of both electric double-layer capacitors and lithium ion batteries. A key limitation to this technology is the kinetic imbalance between the Faradaic insertion electrode and capacitive electrode. Here, we demonstrate that the Li 3 VO 4 with low Li-ion insertion voltage and fast kinetics can be favorably used for lithium ion capacitors. N-doped carbon-encapsulated Li 3 VO 4 nanowires are synthesized through a morphology-inheritance route, displaying a low insertion voltage between 0.2 and 1.0 V, a high reversible capacity of ≈400 mAh g -1 at 0.1 A g -1 , excellent rate capability, and long-term cycling stability. Benefiting from the small nanoparticles, low energy diffusion barrier and highly localized charge-transfer, the Li 3 VO 4 /N-doped carbon nanowires exhibit a high-rate pseudocapacitive behavior. A lithium ion capacitor device based on these Li 3 VO 4 /N-doped carbon nanowires delivers a high energy density of 136.4 Wh kg -1 at a power density of 532 W kg -1 , revealing the potential for application in high-performance and long life energy storage devices. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Charging Graphene for Energy Storage

Energy Technology Data Exchange (ETDEWEB)

Liu, Jun

2014-10-06

Since 2004, graphene, including single atomic layer graphite sheet, and chemically derived graphene sheets, has captured the imagination of researchers for energy storage because of the extremely high surface area (2630 m2/g) compared to traditional activated carbon (typically below 1500 m2/g), excellent electrical conductivity, high mechanical strength, and potential for low cost manufacturing. These properties are very desirable for achieving high activity, high capacity and energy density, and fast charge and discharge. Chemically derived graphene sheets are prepared by oxidation and reduction of graphite1 and are more suitable for energy storage because they can be made in large quantities. They still contain multiply stacked graphene sheets, structural defects such as vacancies, and oxygen containing functional groups. In the literature they are also called reduced graphene oxide, or functionalized graphene sheets, but in this article they are all referred to as graphene for easy of discussion. Two important applications, batteries and electrochemical capacitors, have been widely investigated. In a battery material, the redox reaction occurs at a constant potential (voltage) and the energy is stored in the bulk. Therefore, the energy density is high (more than 100 Wh/kg), but it is difficult to rapidly charge or discharge (low power, less than 1 kW/kg)2. In an electrochemical capacitor (also called supercapacitors or ultracapacitor in the literature), the energy is stored as absorbed ionic species at the interface between the high surface area carbon and the electrolyte, and the potential is a continuous function of the state-of-charge. The charge and discharge can happen rapidly (high power, up to 10 kW/kg) but the energy density is low, less than 10 Wh/kg2. A device that can have both high energy and high power would be ideal.

Reliability-oriented Design of a Cost-effective Active Capacitor

DEFF Research Database (Denmark)

Wang, Haoran; Wang, Huai

2017-01-01

This paper presents the reliability-oriented design of a two-terminal active capacitor proposed recently. The two-terminal active capacitor has the same level of convenience as a passive capacitor with reduced requirement of overall energy storage. In order to fully explore the potential...... of the proposed concept, a comprehensive design procedure is necessary to optimally sizing the key components of the active capacitor in terms of cost and reliability. Moreover, the inherent condition monitoring capability of the active capacitor is discussed by utilizing the existing feedback signals. A 500 W...

Research on laser detonation pulse circuit with low-power based on super capacitor

Science.gov (United States)

Wang, Hao-yu; Hong, Jin; He, Aifeng; Jing, Bo; Cao, Chun-qiang; Ma, Yue; Chu, En-yi; Hu, Ya-dong

2018-03-01

According to the demand of laser initiating device miniaturization and low power consumption of weapon system, research on the low power pulse laser detonation circuit with super capacitor. Established a dynamic model of laser output based on super capacitance storage capacity, discharge voltage and programmable output pulse width. The output performance of the super capacitor under different energy storage capacity and discharge voltage is obtained by simulation. The experimental test system was set up, and the laser diode of low power pulsed laser detonation circuit was tested and the laser output waveform of laser diode in different energy storage capacity and discharge voltage was collected. Experiments show that low power pulse laser detonation based on super capacitor energy storage circuit discharge with high efficiency, good transient performance, for a low power consumption requirement, for laser detonation system and low power consumption and provide reference light miniaturization of engineering practice.

Capacitor voltage ripple reduction and arm energy balancing in MMC-HVDC

DEFF Research Database (Denmark)

Parikh, Harsh; Martin-Loeches, Ruben Sánches; Tsolaridis, Georgios

2016-01-01

Modular Multilevel Converters are emerging and widely used in HVDC applications. However, the submodule capacitors are still large and the energy balancing under unbalanced conditions is a challenge. In this paper, an analytical model focusing on the energy stored in the capacitors and voltage...... variations is utilized in order to achieve better performance. By injecting a second order harmonic component into the circulating current, the energy variation and consequently the capacitor voltage ripple is reduced allowing for a capacitor size reduction. At the same time, an arm energy balancing...

Design of arc power supply for neutral beam injection system based on super capacitor energy storage

International Nuclear Information System (INIS)

Yang Puqiong; Xuan Weimin; Cao Jianyong; Li Qing; Liu Xiaolong

2015-01-01

The arc power supply is one of the most important equipment for neutral beam injection system. The stability of arc discharge and the quality of ion beam extraction were determined by its performance. For improving stability of the arc discharge, reducing the power network capacity and decreasing impulse on power network, the topology of the arc power supply applied the structure of DC/DC converter based on technology of super capacitor energy storage and switching power supply. Several IGBT power modules are operated in parallel, and it can improve the arc power supply's operating frequency and dynamic response. A filter circuit and a current fast transferring circuit were designed based on a detailed analysis on working process of the arc power sup- ply. According to the requirements and parameters of the arc power supply, and the current response of RL first order circuit, the minimum filter inductances were accurately calculated. Finally, using the model and Matlab, the performance of the arc power supply was simulated and verified, and it meets the design requirement. (authors)

Can ionophobic nanopores enhance the energy storage capacity of electric-double-layer capacitors containing nonaqueous electrolytes?

Science.gov (United States)

Lian, Cheng; Liu, Honglai; Henderson, Douglas; Wu, Jianzhong

2016-10-01

The ionophobicity effect of nanoporous electrodes on the capacitance and the energy storage capacity of nonaqueous-electrolyte supercapacitors is studied by means of the classical density functional theory (DFT). It has been hypothesized that ionophobic nanopores may create obstacles in charging, but they store energy much more efficiently than ionophilic pores. In this study, we find that, for both ionic liquids and organic electrolytes, an ionophobic pore exhibits a charging behavior different from that of an ionophilic pore, and that the capacitance-voltage curve changes from a bell shape to a two-hump camel shape when the pore ionophobicity increases. For electric-double-layer capacitors containing organic electrolytes, an increase in the ionophobicity of the nanopores leads to a higher capacity for energy storage. Without taking into account the effects of background screening, the DFT predicts that an ionophobic pore containing an ionic liquid does not enhance the supercapacitor performance within the practical voltage ranges. However, by using an effective dielectric constant to account for ion polarizability, the DFT predicts that, like an organic electrolyte, an ionophobic pore with an ionic liquid is also able to increase the energy stored when the electrode voltage is beyond a certain value. We find that the critical voltage for an enhanced capacitance in an ionic liquid is larger than that in an organic electrolyte. Our theoretical predictions provide further understanding of how chemical modification of porous electrodes affects the performance of supercapacitors. The authors are saddened by the passing of George Stell but are pleased to contribute this article in his memory. Some years ago, DH gave a talk at a Gordon Conference that contained an approximation that George had demonstrated previously to be in error in one of his publications. Rather than making this point loudly in the discussion, George politely, quietly, and privately pointed this out

Problems of increasing specific characteristics of pulse capacitors and cables

International Nuclear Information System (INIS)

Kuchinskij, G.S.; Monastyrskij, A.E.; Shilin, O.V.

1984-01-01

Requirements for high specific energy are practically related to all types of pulse capacitors of energy storage. At present the specific energy for most types of home and foreign pulse capacitors is about 0.1 MJ/m 3 at operating electric field intensity 70-100 kV/mm. It is shown that the basic means for increasing the specific energy and working intensity is the application of new polymeric film materials. Application of paper-film and film insulation permits to develop the specific types of capacitors designed for a limited service life in an aperiodic discharge mode with lower reliabiliy and the specific energy upto 0.5 MJ/m 3 . Characteristics of separate types of pulse capacitors and cables are given, and reliability criterion is considered. Measures of increasing reliability and service life for pulse capacitors and cables, used as tokamak power supplies are enumerated

Effect of capacitor loss on discharging characteristics of xenon flash lamp

International Nuclear Information System (INIS)

Zhang Chu; Lin Dejiang; Xu Chunmei; Shen Hongbin; Chen Xiaohan

2012-01-01

The effect of storage capacitor's loss on the discharging characteristics of the xenon flash lamp was studied, and the xenon flash lamp discharging circuit was analyzed and improved. The capacitor can be equivalent to a series of an ideal capacitor and loss resistance. The improved formula of the xenon lamp discharging characteristics was given when actual capacitance loss is not zero, and the xenon lamp discharging current and discharging power are calculated and analyzed in detail with the increase of the capacitor loss. The results show that the increase of loss will lead to the decrease of xenon lamp discharging current and peak power and the xenon lamp flash time, and influence laser pumping efficiency. The loss will also lead to the capacitor inverse charging in LC discharging circuit; this will influence normal working of the capacitor and decrease the lift of the xenon lamp. The actual energy storage capacitor charging and discharging experiments show that the increase of capacitor loss will lead to the decrease of xenon lamp light-emitting waveform peak, shortening of the flash time and increase of the electrode sputter, thus verity, the reasonableness of theoretical analysis. In addition, the experiments show that environmental factors have very significant impact on the increase of the storage capacitor loss. (authors)

Lower-Energy Energy Storage System (LEESS) Component Evaluation

Energy Technology Data Exchange (ETDEWEB)

Gonder, J.; Cosgrove, J.; Shi, Y.; Saxon, A.; Pesaran, A.

2014-10-01

Alternate hybrid electric vehicle (HEV) energy storage systems (ESS) such as lithium-ion capacitors (LICs) and electrochemical double-layer capacitor (EDLC) modules have the potential for improved life, superior cold temperature performance, and lower long-term cost projections relative to traditional battery storage systems. If such lower-energy ESS (LEESS) devices can also be shown to maintain high HEV fuel savings, future HEVs designed with these devices could have an increased value proposition relative to conventional vehicles. NREL's vehicle test platform is helping validate the in-vehicle performance capability of alternative LEESS devices and identify unforeseen issues. NREL created the Ford Fusion Hybrid test platform for in-vehicle evaluation of such alternative LEESS devices, bench testing of the initial LIC pack, integration and testing of the LIC pack in the test vehicle, and bench testing and installation of an EDLC module pack. EDLC pack testing will continue in FY15. The in-vehicle LIC testing results suggest technical viability of LEESS devices to support HEV operation. Several LIC configurations tested demonstrated equivalent fuel economy and acceleration performance as the production nickel-metal-hydride ESS configuration across all tests conducted. The lowest energy LIC scenario demonstrated equivalent performance over several tests, although slightly higher fuel consumption on the US06 cycle and slightly slower acceleration performance. More extensive vehicle-level calibration may be able to reduce or eliminate these performance differences. The overall results indicate that as long as critical attributes such as engine start under worst case conditions can be retained, considerable ESS downsizing may minimally impact HEV fuel savings.

Inventory of future power and heat production technologies. Partial report Energy storage; Inventering av framtidens el- och vaermeproduktionstekniker. Delrapport Energilagring

Energy Technology Data Exchange (ETDEWEB)

Messing, Lars; Lindahl, Sture [Gothia Power AB, Goeteborg (Sweden)

2008-12-15

In this report a survey of different techniques for storage of electrical energy. The following alternatives are described regarding method, characteristics, potential and economy. Batteries; Capacitors; Flywheels; Pump storage hydro power plants; Hydrogen gas generation; Air compression. Regarding evaluation of methods for storage of electrical energy. Battery storage: The development of Lithium-ion batteries are of great interest. In the present situation it is however difficult of classify battery storage as a good alternation in applications with frequent re-charging cycles and re-charging of large energy volumes. The batteries have limited life length compared to other alternatives. Also the power is limited at charging and discharging. Energy storage in capacitors: 'Super-capacitors' having large power capacity is considered to be of interest in applications where fast control of power is necessary. The ongoing development of based on carbon-nanotubes will increase the energy storage capacity compared with the today existing super-capacitors. This can in the future be an alternative to battery storage. Of further interest is also the idea to combine battery and capacitor based storage to achieve longer life-time of the batteries and faster power control. Flywheel energy storage: The energy storage capacity is relatively limited but power control can be fast. This system can be an alternative to capacitor based energy storage. Pump-storage hydro power plant: This type of energy storage is well suited and proven for time frame up to some days. In the Swedish power system there is today not any large demand of energy storage in this time frame as there is a large capacity in conventional hydro power plants with storage capacity. Pump-storage can however be of interest in the southern part of Sweden. In some operation stages the grid is loaded up to its limit due to large power transmission from the north. The pump-storage can reduce this power transfer during

Inventory of future power and heat production technologies. Partial report Energy storage; Inventering av framtidens el- och vaermeproduktionstekniker. Delrapport Energilagring

Energy Technology Data Exchange (ETDEWEB)

Messing, Lars; Lindahl, Sture (Gothia Power AB, Goeteborg (Sweden))

2008-12-15

In this report a survey of different techniques for storage of electrical energy. The following alternatives are described regarding method, characteristics, potential and economy. Batteries; Capacitors; Flywheels; Pump storage hydro power plants; Hydrogen gas generation; Air compression. Regarding evaluation of methods for storage of electrical energy. Battery storage: The development of Lithium-ion batteries are of great interest. In the present situation it is however difficult of classify battery storage as a good alternation in applications with frequent re-charging cycles and re-charging of large energy volumes. The batteries have limited life length compared to other alternatives. Also the power is limited at charging and discharging. Energy storage in capacitors: 'Super-capacitors' having large power capacity is considered to be of interest in applications where fast control of power is necessary. The ongoing development of based on carbon-nanotubes will increase the energy storage capacity compared with the today existing super-capacitors. This can in the future be an alternative to battery storage. Of further interest is also the idea to combine battery and capacitor based storage to achieve longer life-time of the batteries and faster power control. Flywheel energy storage: The energy storage capacity is relatively limited but power control can be fast. This system can be an alternative to capacitor based energy storage. Pump-storage hydro power plant: This type of energy storage is well suited and proven for time frame up to some days. In the Swedish power system there is today not any large demand of energy storage in this time frame as there is a large capacity in conventional hydro power plants with storage capacity. Pump-storage can however be of interest in the southern part of Sweden. In some operation stages the grid is loaded up to its limit due to large power transmission from the north. The pump-storage can reduce this power transfer

Achieving High-Energy-High-Power Density in a Flexible Quasi-Solid-State Sodium Ion Capacitor.

Science.gov (United States)

Li, Hongsen; Peng, Lele; Zhu, Yue; Zhang, Xiaogang; Yu, Guihua

2016-09-14

Simultaneous integration of high-energy output with high-power delivery is a major challenge for electrochemical energy storage systems, limiting dual fine attributes on a device. We introduce a quasi-solid-state sodium ion capacitor (NIC) based on a battery type urchin-like Na2Ti3O7 anode and a capacitor type peanut shell derived carbon cathode, using a sodium ion conducting gel polymer as electrolyte, achieving high-energy-high-power characteristics in solid state. Energy densities can reach 111.2 Wh kg(-1) at power density of 800 W kg(-1), and 33.2 Wh kg(-1) at power density of 11200 W kg(-1), which are among the best reported state-of-the-art NICs. The designed device also exhibits long-term cycling stability over 3000 cycles with capacity retention ∼86%. Furthermore, we demonstrate the assembly of a highly flexible quasi-solid-state NIC and it shows no obvious capacity loss under different bending conditions.

Energy recovery storage systems in electrical vehicles with batteries; Tecnicas de armazenamiento de energia em veiculos electricos a baterias

Energy Technology Data Exchange (ETDEWEB)

Chaves, M.; Maia, J.; Foito, D.

2004-07-01

In this paper are presented three energy recovery storage systems that can be used in electrical vehicles with batteries. The first storage system uses ultra capacitors that is electrical energy storage, the second system is based on superconductivity magnetic storage, and the third system uses on kinetic energy stored in flywheels. It is also presented the power electronics needed to perform the energy systems. (Author)

Energy storage device including a redox-enhanced electrolyte

Science.gov (United States)

Stucky, Galen; Evanko, Brian; Parker, Nicholas; Vonlanthen, David; Auston, David; Boettcher, Shannon; Chun, Sang-Eun; Ji, Xiulei; Wang, Bao; Wang, Xingfeng; Chandrabose, Raghu Subash

2017-08-08

An electrical double layer capacitor (EDLC) energy storage device is provided that includes at least two electrodes and a redox-enhanced electrolyte including two redox couples such that there is a different one of the redox couples for each of the electrodes. When charged, the charge is stored in Faradaic reactions with the at least two redox couples in the electrolyte and in a double-layer capacitance of a porous carbon material that comprises at least one of the electrodes, and a self-discharge of the energy storage device is mitigated by at least one of electrostatic attraction, adsorption, physisorption, and chemisorption of a redox couple onto the porous carbon material.

Capacitor requirements for controlled thermonuclear experiments and reactors

International Nuclear Information System (INIS)

Boicourt, G.P.; Hoffman, P.S.

1975-01-01

Future controlled thermonuclear experiments as well as controlled thermonuclear reactors will require substantial numbers of capacitors. The demands on these units are likely to be quite severe and quite different from the normal demands placed on either present energy storage capacitors or present power factor correction capacitors. It is unlikely that these two types will suffice for all necessary Controlled Thermonuclear Research (CTR) applications. The types of capacitors required for the various CTR operating conditions are enumerated. Factors that influence the life, cost and operating abilities of these types of capacitors are discussed. The problems of capacitors in a radiation environment are considered. Areas are defined where future research is needed. Some directions that this research should take are suggested. (U.S.)

Capacitor requirements for controlled thermonuclear experiments and reactors

International Nuclear Information System (INIS)

Boicourt, G.P.; Hoffman, P.S.

1975-01-01

Future controlled thermonuclear experiments as well as controlled thermonuclear reactors will require substantial numbers of capacitors. The demands on these units are likely to be quite severe and quite different from the normal demands placed on either present energy storage capacitors or present power factor correction capacitors. It is unlikely that these two types will suffice for all necessary Controlled Thermonuclear Research (CTR) applications. The types of capacitors required for the various CTR operating conditions are enumerated. Factors that influence the life, cost and operating abilities of these types of capacitors are discussed. The problems of capacitors in a radiation environment are considered. Areas are defined where future research is needed. Some directions that this research should take are suggested

An Electrochemical Capacitor with Applicable Energy Density of 7.4 Wh/kg at Average Power Density of 3000 W/kg.

Science.gov (United States)

Zhai, Teng; Lu, Xihong; Wang, Hanyu; Wang, Gongming; Mathis, Tyler; Liu, Tianyu; Li, Cheng; Tong, Yexiang; Li, Yat

2015-05-13

Electrochemical capacitors represent a new class of charge storage devices that can simultaneously achieve high energy density and high power density. Previous reports have been primarily focused on the development of high performance capacitor electrodes. Although these electrodes have achieved excellent specific capacitance based on per unit mass of active materials, the gravimetric energy densities calculated based on the weight of entire capacitor device were fairly small. This is mainly due to the large mass ratio between current collector and active material. We aimed to address this issue by a 2-fold approach of minimizing the mass of current collector and increasing the electrode performance. Here we report an electrochemical capacitor using 3D graphene hollow structure as current collector, vanadium sulfide and manganese oxide as anode and cathode materials, respectively. 3D graphene hollow structure provides a lightweight and highly conductive scaffold for deposition of pseudocapacitive materials. The device achieves an excellent active material ratio of 24%. Significantly, it delivers a remarkable energy density of 7.4 Wh/kg (based on the weight of entire device) at the average power density of 3000 W/kg. This is the highest gravimetric energy density reported for asymmetric electrochemical capacitors at such a high power density.

Hot Thermal Storage in a Variable Power, Renewable Energy System

Science.gov (United States)

2014-06-01

where cost effective, increase the utilization of distributed electric power generation through wind, solar, geothermal , and biomass renewable...characteristics and may not necessarily be available in all cases. Types of direct heat energy systems include solar thermal, waste heat, and geothermal ...of super capacitor energy storage system in microgrid,” in International Conference on Sustainable Power Generation and Supply, Janjing, China

Synthesis of graphene nanomaterials and their application in electrochemical energy storage

Science.gov (United States)

Xiong, Guoping

The need to store and use energy on diverse scales in a modern technological society necessitates the design of large and small energy systems, among which electrical energy storage systems such as batteries and capacitors have attracted much interest in the past several decades. Supercapacitors, also known as ultracapacitors, or electrochemical capacitors, with fast power delivery and long cycle life are complementing or even replacing batteries in many applications. The rapid development of miniaturized electronic devices has led to a growing need for rechargeable micro-power sources with high performance. Among different sources, electrochemical micro-capacitors or micro-supercapacitors provide higher power density than their counterparts and are gaining increased interest from the research and engineering communities. Rechargeable Li ion batteries with high energy and power density, long cycling life, high charge-discharge rate (1C - 3C) and safe operation are in high demand as power sources and power backup for hybrid electric vehicles and other applications. In the present work, graphene-based graphene materials have been designed and synthesized for electrochemical energy storage applications, e.g., conventional supercapacitors (macro-supercapacitors), microsupercapacitors and lithium ion batteries. Factors influencing the formation and structure of graphitic petals grown by microwave plasma-enhanced chemical vapor deposition on oxidized silicon substrates were investigated through process variation and materials analysis. Insights gained into the growth mechanism of these graphitic petals suggest a simple scribing method can be used to control both the location and formation of petals on flat Si substrates. Transitional metal oxides and conducting polymers have been coated on the graphitic petal-based electrodes by facile chemical methods for multifunctional energy storage applications. Detailed electrochemical characterization (e.g., cyclic voltammetry and

Improving energy conversion efficiency for triboelectric nanogenerator with capacitor structure by maximizing surface charge density.

Science.gov (United States)

He, Xianming; Guo, Hengyu; Yue, Xule; Gao, Jun; Xi, Yi; Hu, Chenguo

2015-02-07

Nanogenerators with capacitor structures based on piezoelectricity, pyroelectricity, triboelectricity and electrostatic induction have been extensively investigated. Although the electron flow on electrodes is well understood, the maximum efficiency-dependent structure design is not clearly known. In this paper, a clear understanding of triboelectric generators with capacitor structures is presented by the investigation of polydimethylsiloxane-based composite film nanogenerators, indicating that the generator, in fact, acts as both an energy storage and output device. Maximum energy storage and output depend on the maximum charge density on the dielectric polymer surface, which is determined by the capacitance of the device. The effective thickness of polydimethylsiloxane can be greatly reduced by mixing a suitable amount of conductive nanoparticles into the polymer, through which the charge density on the polymer surface can be greatly increased. This finding can be applied to all the triboelectric nanogenerators with capacitor structures, and it provides an important guide to the structural design for nanogenerators. It is demonstrated that graphite particles with sizes of 20-40 nm and 3.0% mass mixed into the polydimethylsiloxane can reduce 34.68% of the effective thickness of the dielectric film and increase the surface charges by 111.27% on the dielectric film. The output power density of the triboelectric nanogenerator with the composite polydimethylsiloxane film is 3.7 W m(-2), which is 2.6 times as much as that of the pure polydimethylsiloxane film.

Optimal Energy Management, Location and Size for Stationary Energy Storage System in a Metro Line Based on Genetic Algorithm

Directory of Open Access Journals (Sweden)

Huan Xia

2015-10-01

Full Text Available The installation of stationary super-capacitor energy storage system (ESS in metro systems can recycle the vehicle braking energy and improve the pantograph voltage profile. This paper aims to optimize the energy management, location, and size of stationary super-capacitor ESSes simultaneously and obtain the best economic efficiency and voltage profile of metro systems. Firstly, the simulation platform of an urban rail power supply system, which includes trains and super-capacitor energy storage systems, is established. Then, two evaluation functions from the perspectives of economic efficiency and voltage drop compensation are put forward. Ultimately, a novel optimization method that combines genetic algorithms and a simulation platform of urban rail power supply system is proposed, which can obtain the best energy management strategy, location, and size for ESSes simultaneously. With actual parameters of a Chinese metro line applied in the simulation comparison, certain optimal scheme of ESSes’ energy management strategy, location, and size obtained by a novel optimization method can achieve much better performance of metro systems from the perspectives of two evaluation functions. The simulation result shows that with the increase of weight coefficient, the optimal energy management strategy, locations and size of ESSes appear certain regularities, and the best compromise between economic efficiency and voltage drop compensation can be obtained by a novel optimization method, which can provide a valuable reference to subway company.

Contribution to dimensioning a pack of super-capacitors for 12/42 V application

Energy Technology Data Exchange (ETDEWEB)

Rafik, F.; Karmous, M. [Ecole d' Ingenieurs de l' Arc Jurassien, CH (Switzerland); Gualous, H.; Berthon, A. [Universite de Franche-Comte, Lab. en Electronique, Electrotechnique et Systemes (L2ES), UTBM, 90 - Belfort (France); Gallay, R. [Maxwell Technologies, CH (Switzerland)

2004-07-01

Increase power demands on automotive are making current 12/14 V electrical systems inadequate. The total power demand will triple in some cars from 800 W today to an average of 2500 W and into kW range for peak demand in the future. Super-capacitor can be used for energy storage and for peak power requirement in order to increase the efficiency and the life cycle of the system. However, the sizing of energy storage with super-capacitors is very important for embedded applications, because of the weight and the volume of the system. This paper presents a sizing method of a pack of super-capacitors. The proposed method is based on the power and energy demand. In order to validate this method, a model of the Maxwell cell BCAP0010 of super-capacitors is presented and implemented in the SIMPLORER software. (authors)

A compact 100 kV high voltage glycol capacitor.

Science.gov (United States)

Wang, Langning; Liu, Jinliang; Feng, Jiahuai

2015-01-01

A high voltage capacitor is described in this paper. The capacitor uses glycerol as energy storage medium, has a large capacitance close to 1 nF, can hold off voltages of up to 100 kV for μs charging time. Allowing for low inductance, the capacitor electrode is designed as coaxial structure, which is different from the common structure of the ceramic capacitor. With a steady capacitance at different frequencies and a high hold-off voltage of up to 100 kV, the glycol capacitor design provides a potential substitute for the ceramic capacitors in pulse-forming network modulator to generate high voltage pulses with a width longer than 100 ns.

Energy storage, to make the wager to believe

International Nuclear Information System (INIS)

Signoret, Stephane; Guilhem, Jean; De Santis, Audrey; Kim, Caroline; Petitot, Pauline; Mary, Olivier

2016-01-01

After having evoked some examples and studies (an assessment of the costs of energy storage, an industrial perspective for sodium-ion batteries, the development of an energy recovery system for road transport), a first article discusses the importance of a right definition of energy storage, of its functions and development framework (how to store, where to store, at which price, in which context). A second article evokes the installation of Forsee Power (a leader in battery assembly) in France. A third article discusses how to couple renewable energies and local energy storage. While evoking the example of the LMP battery by Bollore, a fourth article outline the common benefits of high capacity batteries used in electric vehicles as well as in domestic applications or renewable energy supply schemes. The fifth article proposes an overview of researches for the improvement of energy storage solutions (study of battery ageing, use of super-capacitors, thermal storage in industry, a hybrid storage of renewable energy in overseas districts, use of nano-silicon to improve anodes, improvement of oxygen supply in fuel cells, development of very porous silicon layers for anodes). The sixth article discusses the development of a process by Babcok and the Cnim Group for a massive storage of energy by thermal accumulation for electric or thermal energy producers. The seventh and last article notices that the IRENA (International renewable energy Agency) outlined the role of energy storage for the development of rural areas and of islands which are disconnected from the grid

High Energy Density Polymer Film Capacitors

National Research Council Canada - National Science Library

Boufelfel, Ali

2006-01-01

High-energy-density capacitors that are compact and light-weight are extremely valuable in a number of critical DoD systems that include portable field equipment, pulsed lasers, detection equipment...

Low Temperature Double-layer Capacitors with Improved Energy Density: An Overview of Recent Development Efforts

Science.gov (United States)

Brandon, Erik J.; West, William C.; Smart, Marshall C.; Yushin, Gleb; Korenblit, Yair; Kajdos, Adam; Kvit, Alexander; Jagiello, Jacek

2012-01-01

Electrochemical double-layer capacitors are finding increased use in a wide range of energy storage applications, particularly where high pulse power capabilities are required. Double-layer capacitors store charge at a liquid/solid interface, making them ideal for low temperature power applications, due to the facile kinetic processes associated with the rearrangement of the electrochemical double-layer at these temperatures. Potential low temperature applications include hybrid and electric vehicles, operations in polar regions, high altitude aircraft and aerospace avionics, and distributed environmental and structural health monitoring. State-of-the-art capacitors can typically operate to -40 C, with a subsequent degradation in power performance below room temperature. However, recent efforts focused on advanced electrolyte and electrode systems can enable operation to temperatures as low as -70 C, with capacities similar to room temperature values accompanied by reasonably low equivalent series resistances. This presentation will provide an overview of recent development efforts to extend and improve the wide temperature performance of these devices.

Infant-mortality testing of high-energy-density capacitors used on Nova

International Nuclear Information System (INIS)

Merritt, B.T.; Whitham, K.

1983-01-01

Nova is a solid-state large laser for inertial-confinement fusion research. Its flashlamps are driven by a 60-MJ capacitor bank. Part of this bank is being built with high-energy-density capacitors, 52-μF, 22 kV, 12.5 kJ. A total of 2645 of these capacitors have been purchased from two manufacturers. Each capacitor was infant-mortality tested. The first test consisted of a high-potential test, bushing-to-case, since these capacitors have dual bushings. Then the capacitors were discharged 500 times with circuit conditions approximating the capacitors normal flashlamp load. Failure of either of these tests or if the capacitor was leaking was cause for rejection

Designing lead-free antiferroelectrics for energy storage

Science.gov (United States)

Xu, Bin; Íñiguez, Jorge; Bellaiche, L.

2017-01-01

Dielectric capacitors, although presenting faster charging/discharging rates and better stability compared with supercapacitors or batteries, are limited in applications due to their low energy density. Antiferroelectric (AFE) compounds, however, show great promise due to their atypical polarization-versus-electric field curves. Here we report our first-principles-based theoretical predictions that Bi1−xRxFeO3 systems (R being a lanthanide, Nd in this work) can potentially allow high energy densities (100–150 J cm−3) and efficiencies (80–88%) for electric fields that may be within the range of feasibility upon experimental advances (2–3 MV cm−1). In addition, a simple model is derived to describe the energy density and efficiency of a general AFE material, providing a framework to assess the effect on the storage properties of variations in doping, electric field magnitude and direction, epitaxial strain, temperature and so on, which can facilitate future search of AFE materials for energy storage. PMID:28555655

Powering microbial electrolysis cells by capacitor circuits charged using microbial fuel cell

KAUST Repository

Hatzell, Marta C.

2013-05-01

A microbial electrolysis cell (MEC) was powered by a capacitor based energy storage circuit using energy from a microbial fuel cell (MFC) to increase MEC hydrogen production rates compared to that possible by the MFC alone. To prevent voltage reversal, MFCs charged the capacitors in a parallel configuration, and then the capacitors were discharged in series to boost the voltage that was used to power the MECs. The optimal capacitance for charging was found to be ∼0.01 F for each MFC. The use of the capacitor charging system increased energy recoveries from 9 to 13%, and hydrogen production rates increased from 0.31 to 0.72 m3 m-3-day-1, compared to coupled systems without capacitors. The circuit efficiency (the ratio of the energy that was discharged to the MEC to the energy provided to the capacitor from the MFCs) was ∼90%. These results provide an improved method for linking MFCs to MECs for renewable hydrogen gas production. © 2012 Elsevier B.V. All rights reserved.

Advanced Energy Storage Devices: Basic Principles, Analytical Methods, and Rational Materials Design

Science.gov (United States)

Liu, Jilei; Wang, Jin; Xu, Chaohe; Li, Chunzhong; Lin, Jianyi

2017-01-01

Abstract Tremendous efforts have been dedicated into the development of high‐performance energy storage devices with nanoscale design and hybrid approaches. The boundary between the electrochemical capacitors and batteries becomes less distinctive. The same material may display capacitive or battery‐like behavior depending on the electrode design and the charge storage guest ions. Therefore, the underlying mechanisms and the electrochemical processes occurring upon charge storage may be confusing for researchers who are new to the field as well as some of the chemists and material scientists already in the field. This review provides fundamentals of the similarities and differences between electrochemical capacitors and batteries from kinetic and material point of view. Basic techniques and analysis methods to distinguish the capacitive and battery‐like behavior are discussed. Furthermore, guidelines for material selection, the state‐of‐the‐art materials, and the electrode design rules to advanced electrode are proposed. PMID:29375964

Fabrication of wound capacitors using flexible alkali-free glass

International Nuclear Information System (INIS)

Wilke, Rudeger H. T.; Baker, Amanda; Brown-Shaklee, Harlan; Johnson-Wilke, Raegan; Hettler, Chad

2016-01-01

Here, alkali-free glasses, which exhibit high energy storage densities (~35 J/cc), present a unique opportunity to couple high temperature stability with high breakdown strength, and thus provide an avenue for capacitor applications with stringent temperature and power requirements. Realizing the potential of these materials in kilovolt class capacitors with >1 J/cc recoverable energy density requires novel packaging strategies that incorporate these extremely fragile dielectrics. In this paper, we demonstrate the feasibility of fabricating wound capacitors using 50-μm-thick glass. Two capacitors were fabricated from 2.8-m-long ribbons of thin (50 μm) glass wound into 125-140-mm-diameter spools. The capacitors exhibit a capacitance of 70-75 nF with loss tangents below 1%. The wound capacitors can operate up to 1 kV and show excellent temperature stability to 150 °C. By improving the end terminations, the self-resonance can be shifted to above 1 MHz, indicating that these materials may be useful for pulsed power applications with microsecond discharge times.

Sol-gel Technology and Advanced Electrochemical Energy Storage Materials

Science.gov (United States)

Chu, Chung-tse; Zheng, Haixing

1996-01-01

Advanced materials play an important role in the development of electrochemical energy devices such as batteries, fuel cells, and electrochemical capacitors. The sol-gel process is a versatile solution for use in the fabrication of ceramic materials with tailored stoichiometry, microstructure, and properties. This processing technique is particularly useful in producing porous materials with high surface area and low density, two of the most desirable characteristics for electrode materials. In addition,the porous surface of gels can be modified chemically to create tailored surface properties, and inorganic/organic micro-composites can be prepared for improved material performance device fabrication. Applications of several sol-gel derived electrode materials in different energy storage devices are illustrated in this paper. V2O5 gels are shown to be a promising cathode material for solid state lithium batteries. Carbon aerogels, amorphous RuO2 gels and sol-gel derived hafnium compounds have been studied as electrode materials for high energy density and high power density electrochemical capacitors.

Review—Two-Dimensional Layered Materials for Energy Storage Applications

KAUST Repository

Kumar, Pushpendra

2016-07-02

Rechargeable batteries are most important energy storage devices in modern society with the rapid development and increasing demand for handy electronic devices and electric vehicles. The higher surface-to-volume ratio two-dimensional (2D) materials, especially transition metal dichalcogenides (TMDCs) and transition metal carbide/nitrite generally referred as MXene, have attracted intensive research activities due to their fascinating physical/chemical properties with extensive applications. One of the growing applications is to use these 2D materials as potential electrodes for rechargeable batteries and electrochemical capacitors. This review is an attempt to summarize the research and development of TMDCs, MXenes and their hybrid structures in energy storage systems. (C) The Author(s) 2016. Published by ECS. All rights reserved.

Review—Two-Dimensional Layered Materials for Energy Storage Applications

KAUST Repository

Kumar, Pushpendra; Abuhimd, Hatem; Wahyudi, Wandi; Li, Mengliu; Ming, Jun; Li, Lain-Jong

2016-01-01

Rechargeable batteries are most important energy storage devices in modern society with the rapid development and increasing demand for handy electronic devices and electric vehicles. The higher surface-to-volume ratio two-dimensional (2D) materials, especially transition metal dichalcogenides (TMDCs) and transition metal carbide/nitrite generally referred as MXene, have attracted intensive research activities due to their fascinating physical/chemical properties with extensive applications. One of the growing applications is to use these 2D materials as potential electrodes for rechargeable batteries and electrochemical capacitors. This review is an attempt to summarize the research and development of TMDCs, MXenes and their hybrid structures in energy storage systems. (C) The Author(s) 2016. Published by ECS. All rights reserved.

Inductive energy storage commutator

International Nuclear Information System (INIS)

Gavrilov, I.M.

1987-01-01

An inductive energy storage commutator is described. The value of commutated current is up to 800 A, the voltage amplitude in the load is up to 50 kV, the working frequency is equal to 1-50 Hz, the commutated power is up to 40 MW. The commutating device comprises of the first stage commutator having two in-series connected modules of the BTSV - 800/235 high-voltage thyristor unit, the second stage commutator containing three GMI-43A parallel connected powerful pulsed triodes, a commutating capacitor, an induction coil, two supplementary high-voltage thyristor keys (20 in-series connected thyristors T2-300 (13 class)), load, control pulse shapers, thyristor keys, power supply

Electric converters of electromagnetic strike machine with capacitor supply

Science.gov (United States)

Usanov, K. M.; Volgin, A. V.; Kargin, V. A.; Moiseev, A. P.; Chetverikov, E. A.

2018-03-01

The application of pulse linear electromagnetic engines in small power strike machines (energy impact is 0.01...1.0 kJ), where the characteristic mode of rare beats (pulse seismic vibrator, the arch crash device bins bulk materials), is quite effective. At the same time, the technical and economic performance of such machines is largely determined by the ability of the power source to provide a large instantaneous power of the supply pulses in the winding of the linear electromagnetic motor. The use of intermediate energy storage devices in power systems of rare-shock LEME makes it possible to obtain easily large instantaneous powers, forced energy conversion, and increase the performance of the machine. A capacitor power supply of a pulsed source of seismic waves is proposed for the exploration of shallow depths. The sections of the capacitor storage (CS) are connected to the winding of the linear electromagnetic motor by thyristor dischargers, the sequence of activation of which is determined by the control device. The charge of the capacitors to the required voltage is made directly from the battery source, or through the converter from a battery source with a smaller number of batteries.

Nanohybrid capacitor: the next generation electrochemical capacitors

Energy Technology Data Exchange (ETDEWEB)

Naoi, K. [Institute of Symbiotic Science and Technology, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8558 (Japan)

2010-10-15

Conventional electric double layer capacitors (EDLC) designed with two symmetrical activated carbon electrodes can deliver substantially more power than similar size Li-ion batteries. There is presently a major effort to increase the energy density of EDLC s up to a target value in the vicinity of 20-30 Wh kg{sup -1}.The present review article deals with the recent contributions to get this high energy density and new approaches that have been made to increase the withstanding voltage of the EDLCs. Important alternative approach to meet this goal that is under serious investigation is to develop an asymmetric (hybrid) capacitors. Hybrid capacitor systems are the promising approach to meet the goal to effectively increase the energy density. The investigation is to develop hybrid capacitors has been initiated by Li-ion capacitors. And, now Nanohybrid capacitor certainly achieves as high energy density as Li-ion capacitors with higher stability, higher safety and higher productivity. This is the new lithium-ion based hybrid capacitor using the lithium titanate (Li{sub 4}Ti{sub 5}O{sub 12}) negative intercalation electrode that can operate at unusually high current densities. The high-rate Li{sub 4}Ti{sub 5}O{sub 12} negative electrode has a unique nano-structure consisting of unusually small nano-crystalline Li{sub 4}Ti{sub 5}O{sub 12} nucleated and grafted onto carbon nano-fiber anchors (nc-Li{sub 4}Ti{sub 5}O{sub 12}/CNF). (Abstract Copyright [2010], Wiley Periodicals, Inc.)

Infant mortality testing of high energy-density capacitors used on Nova

International Nuclear Information System (INIS)

Merritt, B.T.; Whitham, K.

1983-01-01

Nova is a solid state large laser for inertial confinement fusion research. Its flashlamps are driven by a 60 MJ capacitor bank. Part of this bank is being built with high energy-density capacitors, 52 μF, 22 KV, 12.5 KJ. A total of 2,645 of these capacitors have been purchased from two manufacturers. Each capacitor was infant mortality tested. The first test consisted of a high-potential test, bushing-to-case, since these capacitors have dual bushings. Then the capacitors were discharged 500 times with circuit conditions approximating the capacitors normal flashlamp load. Failure of either of these tests or if the capacitor was leaking was cause for rejection. The test results were remarkably good. Less than 0.5 percent failed the pulse-discharge test and less than 2.5 percent were rejected overall

High-energy power capacitors, their applied technology and the trends

International Nuclear Information System (INIS)

2012-01-01

High-voltage and high-energy-density power capacitors called high-power ones such as film or electrolytic capacitors, have been used in large quantities for the pulse power technology such as an impulse current or voltage generator and a laser power supply, and for the power electronics one with progress of the power semiconductor device and the inverter technology. Recently, electric double layer capacitors (EDLC) with remarkable technical progress have been applied for the equipments of electric power and industrial field for the purpose of energy saving or electric power quality improvement, which have come to link to the electric power system. Thus, using a lot of high-power capacitors near our life would require to know the structure, the principle and the characteristic of capacitors, and also to consider suitable directions for use, maintenance and safety and so on, when carrying out a system and a facility design. In the technical report, while describing the dielectric and the feature of some high-power capacitors, and introducing the application examples to the laser-fusion power supply and some systems with EDLC, the trend of standardization of EDLC and the directivity of the examination about installation and maintenance of the applied equipments are described. (author)

Optimal energy management of HEVs with hybrid storage system

International Nuclear Information System (INIS)

Vinot, E.; Trigui, R.

2013-01-01

Highlights: • A battery and ultra-capacitor system for parallel hybrid vehicle is considered. • Optimal management using Pontryagin’s minimum principle is developed. • Battery stress limitation is taken into account by means of RMS current. • Rule based management approaching the optimal control is proposed. • Comparison between rule based and optimal management are proposed using Pareto front. - Abstract: Energy storage systems are a key point in the design and development of electric and hybrid vehicles. In order to reduce the battery size and its current stress, a hybrid storage system, where a battery is coupled with an electrical double-layer capacitor (EDLC) is considered in this paper. The energy management of such a configuration is not obvious and the optimal operation concerning the energy consumption and battery RMS current has to be identified. Most of the past work on the optimal energy management of HEVs only considered one additional power source. In this paper, the control of a hybrid vehicle with a hybrid storage system (HSS), where two additional power sources are used, is presented. Applying the Pontryagin’s minimum principle, an optimal energy management strategy is found and compared to a rule-based parameterized control strategy. Simulation results are shown and discussed. Applied on a small compact car, optimal and ruled-based methods show that gains of fuel consumption and/or a battery RMS current higher than 15% may be obtained. The paper also proves that a well tuned rule-based algorithm presents rather good performances when compared to the optimal strategy and remains relevant for different driving cycles. This rule-based algorithm may easily be implemented in a vehicle prototype or in an HIL test bench

Capacitor blocks for linear transformer driver stages.

Science.gov (United States)

Kovalchuk, B M; Kharlov, A V; Kumpyak, E V; Smorudov, G V; Zherlitsyn, A A

2014-01-01

In the Linear Transformer Driver (LTD) technology, the low inductance energy storage components and switches are directly incorporated into the individual cavities (named stages) to generate a fast output voltage pulse, which is added along a vacuum coaxial line like in an inductive voltage adder. LTD stages with air insulation were recently developed, where air is used both as insulation in a primary side of the stages and as working gas in the LTD spark gap switches. A custom designed unit, referred to as a capacitor block, was developed for use as a main structural element of the transformer stages. The capacitor block incorporates two capacitors GA 35426 (40 nF, 100 kV) and multichannel multigap gas switch. Several modifications of the capacitor blocks were developed and tested on the life time and self breakdown probability. Blocks were tested both as separate units and in an assembly of capacitive module, consisting of five capacitor blocks. This paper presents detailed design of capacitor blocks, description of operation regimes, numerical simulation of electric field in the switches, and test results.

Some properties of castor oil affecting its performance as a capacitor impregnant and their significance to future impregnant research

International Nuclear Information System (INIS)

Boicourt, G.P.

1975-01-01

For a considerable time castor oil and polychlorinated biphenyl (PCB) have been the principal impregnants used in energy-storage capacitors. Castor oil has proven to be better than PCB for pulsed applications. PCB's have come under attack as an environmental hazard, while castor oil is a vegetable product and its supply and quality are subject to fluctuation. These two facts make the development of new impregnants desirable. The properties of PCB as a capacitor impregnant are well known. This paper first compares a number of properties of castor oil and PCB's. A comparison is made between the lives of castor oil capacitors and comparable PCB energy-storage capacitors. Some of the physical and chemical properties of castor oil which make it a good pulse capacitor impregnant are examined. These properties can be used as a guide for future research on new pulse capacitor impregnants

Pseudocapacitive Oxides and Sulfides for High-Performance Electrochemical Energy Storage

KAUST Repository

Xia, Chuan

2018-03-22

The intermittent nature of several sustainable energy sources such as solar and wind energy has ignited the demand of electrochemical energy storage devices in the form of batteries and electrochemical capacitors. The future generation of electrochemical capacitors will in large part depend on the use of pseudocapacitive materials in one or both electrodes. Developing pseudocapacitors to have both high energy and power density is crucial for future energy storage systems. This dissertation evaluates two different material systems to achieve high energy density pseudocapacitive energy storage. This research presents the successful preparation and application of ternary NiCo2S4, which is based on the surface redox mechanism, in the area of pseudocapacitive energy storage. Attention has been paid to understanding its basic physical properties which can impact its electrochemical behavior. Well-defined single- and double-shell NiCo2S4 hollow spheres were fabricated for pseudocapacitor applications, showing much improved electrochemical storage performance with good energy and power densities, as well as excellent cycling stability. To overcome the complexity of the preparation methods of NiCo2S4 nanostructures, a one-step approach was developed for the first time. Asymmetric pseudocapacitors using NiCo2S4 as cathode and graphene as anode were also fabricated to extend the operation voltage in aqueous electrolyte, and thus enhance the overall capacity of the cells. Furthermore, high-performance on-chip pseudocapacitive energy storage was demonstrated using NiCo2S4 as electrochemically active materials. This dissertation also involves another material system, intercalation pseudocapacitive VO2 (B), that displays a different charge storage mechanism from NiCo2S4. By constructing high-quality, atomically-thin two-dimensional (2D) VO2 (B) sheets using a general monomer-assisted approach, we demonstrate that a rational design of atomically thin, 2D nanostructures of

Comparison of modified driver circuit and capacitor-transfer circuit in longitudinally excited N2 laser.

Science.gov (United States)

Uno, Kazuyuki; Akitsu, Tetsuya; Nakamura, Kenshi; Jitsuno, Takahisa

2013-04-01

We developed a modified driver circuit composed of a capacitance and a spark gap, called a direct-drive circuit, for a longitudinally excited gas laser. The direct-drive circuit uses a large discharge impedance caused by a long discharge length of the longitudinal excitation scheme and eliminates the buffer capacitance used in the traditional capacitor-transfer circuit. We compared the direct-drive circuit and the capacitor-transfer circuit in a longitudinally excited N2 laser (wavelength: 337 nm). Producing high output energy with the capacitor-transfer circuit requires a large storage capacitance and a discharge tube with optimum dimensions (an inner diameter of 4 mm and a length of 10 cm in this work); in contrast, the direct-drive circuit requires a high breakdown voltage, achieved with a small storage capacitance and a large discharge tube. Additionally, for the same input energy of 792 mJ, the maximum output energy of the capacitor-transfer circuit was 174.2 μJ, and that of the direct-drive circuit was 344.7 μJ.

Low Li+ Insertion Barrier Carbon for High Energy Efficient Lithium-Ion Capacitor.

Science.gov (United States)

Lee, Wee Siang Vincent; Huang, Xiaolei; Tan, Teck Leong; Xue, Jun Min

2018-01-17

Lithium-ion capacitor (LIC) is an attractive energy-storage device (ESD) that promises high energy density at moderate power density. However, the key challenge in its design is the low energy efficient negative electrode, which barred the realization of such research system in fulfilling the current ESD technological inadequacy due to its poor overall energy efficiency. Large voltage hysteresis is the main issue behind high energy density alloying/conversion-type materials, which reduces the electrode energy efficiency. Insertion-type material though averted in most research due to the low capacity remains to be highly favorable in commercial application due to its lower voltage hysteresis. To further reduce voltage hysteresis and increase capacity, amorphous carbon with wider interlayer spacing has been demonstrated in the simulation result to significantly reduce Li + insertion barrier. Hence, by employing such amorphous carbon, together with disordered carbon positive electrode, a high energy efficient LIC with round-trip energy efficiency of 84.3% with a maximum energy density of 133 Wh kg -1 at low power density of 210 W kg -1 can be achieved.

Energy storage technologies and hybrid architectures for specific diesel-driven rail duty cycles: Design and system integration aspects

International Nuclear Information System (INIS)

Meinert, M.; Prenleloup, P.; Schmid, S.; Palacin, R.

2015-01-01

Highlights: • We assessed integration of energy storage systems into hybrid system architectures. • We considered mechanical and electrical energy storage systems. • Potential of different combinations has been analyzed by standardized duty cycles. • Most promising are diesel-driven suburban, regional and shunting operations. • Double-layer capacitors and Lithium-ion batteries have the highest potential. - Abstract: The use of diesel-driven traction is an intrinsic part of the functioning of railway systems and it is expected to continue being so for the foreseeable future. The recent introduction of more restrictive greenhouse gas emission levels and other legislation aiming at the improvement of the environmental performance of railway systems has led to the need of exploring alternatives for cleaner diesel rolling stock. This paper focuses on assessing energy storage systems and the design of hybrid system architectures to determine their potential use in specific diesel-driven rail duty cycles. Hydrostatic accumulators, flywheels, Lithium-ion batteries and double-layer capacitors have been assessed and used to design hybrid system architectures. The potential of the different technology combinations has been analyzed using standardized duty cycles enhanced with gradient profiles related to suburban, regional and shunting operations. The results show that double-layer capacitors and Lithium-ion batteries have the highest potential to be successfully integrated into the system architecture of diesel-driven rail vehicles. Furthermore, the results also suggest that combining these two energy storage technologies into a single hybridisation package is a highly promising design that draws on their strengthens without any significant drawbacks.

Charge and Energy Stored in a Capacitor

Science.gov (United States)

Kraftmakher, Yaakov

2012-01-01

Using a data-acquisition system, the charge and energy stored in a capacitor are measured and displayed during the charging/discharging process. The experiment is usable as a laboratory work and/or a lecture demonstration. (Contains 3 figures.)

Energy-Storing Structures: Composite Capacitors and Batteries

Science.gov (United States)

2012-07-30

circuit board (PCB) prepreg C electrode dielectric Autoclave-processed structural capacitor • Objective: High energy density, scalable...Continued scaling (lab safety limit  100 J) – Beyond commercial FR4 prepreg  high dielectric additives, super- clean prepregging

Stabilization of Wind Energy Conversion System with Hydrogen Generator by Using EDLC Energy Storage System

Science.gov (United States)

Shishido, Seiji; Takahashi, Rion; Murata, Toshiaki; Tamura, Junji; Sugimasa, Masatoshi; Komura, Akiyoshi; Futami, Motoo; Ichinose, Masaya; Ide, Kazumasa

The spread of wind power generation is progressed hugely in recent years from a viewpoint of environmental problems including global warming. Though wind power is considered as a very prospective energy source, wind power fluctuation due to the random fluctuation of wind speed has still created some problems. Therefore, research has been performed how to smooth the wind power fluctuation. This paper proposes Energy Capacitor System (ECS) for the smoothing of wind power which consists of Electric Double-Layer Capacitor (EDLC) and power electronics devices and works as an electric power storage system. Moreover, hydrogen has received much attention in recent years from a viewpoint of exhaustion problem of fossil fuel. Therefore it is also proposed that a hydrogen generator is installed at the wind farm to generate hydrogen. In this paper, the effectiveness of the proposed system is verified by the simulation analyses using PSCAD/EMTDC.

Viabilidade econômica da implantação de um banco de capacitores em unidade armazenadora de grãos = Economic feasibility of the installation of capacitor banks in a grain storage

Directory of Open Access Journals (Sweden)

Gustavo Veloso

2017-07-01

Full Text Available As unidades de armazenagem de grãos apresentam elevado consumo de energia elétrica e o aumento do seu preço tem aumentado o custo operacional delas. Esses gastos podem ser diminuídos pela correção do fator de potência através da instalação de bancos de capacitores. Este trabalho analisou a viabilidade econômica da implantação desse tipo de equipamento em uma unidade armazenadora de grãos sediada no município de Brasília, Distrito Federal. O custo da implantação do banco de capacitores foi comparado com a economia advinda da redução dos valores mensais com o consumo reativo de energia. Os cálculos consideram financiamento bancário do valor total a uma taxa de juros de 8,5% ao ano. A taxa mínima de atratividade é 4,46% ao semestre [a.s.]. Os indicadores econômicos utilizados foram: Valor Presente Líquido [VPL], Taxa Interna de Retorno [TIR] e Payback. O investimento considerado foi de R$ 26.772,03. O projeto tem VPL de R$ 7.228,63, TIR de 9,34% a.s. e Payback de três anos e quatro meses. Com base nesses resultados o investimento é atrativo e economicamente viável. = Grain storage complexes require a high consumption of electric energy and the increase in the price of electricity has generated a large impact on their operating costs. One alternative is the correction of the power factor through the installation of capacitor banks. This work aimed to evaluate the economic feasibility of a capacitor installation in a grain storage located in Brasília, Distrito Federal. The cost of deploying the capacitor bank was compared to the values saved in the monthly payments with the reactive energy consumption. To purchase the capacitor bank, financing was simulated with an interest rate of 8.5% per year. The minimum attractive rate of return [MARR] was fixed on 4.46% per semester [p.s.]. Economic indicators estimated were Net Present Value [NPV], Internal Rate of Return [IRR] and simple Payback. The total project cost was R$ 26

A Comparison of Electrolytic Capacitors and Supercapacitors for Piezo-Based Energy Harvesting

Science.gov (United States)

2013-07-01

A Comparison of Electrolytic Capacitors and Supercapacitors for Piezo-Based Energy Harvesting by Matthew H. Ervin, Carlos M. Pereira, John R...Capacitors and Supercapacitors for Piezo-Based Energy Harvesting Matthew H. Ervin Sensors and Electronic Devices Directorate, ARL Carlos M. Pereira... Supercapacitors for Piezo-Based Energy Harvesting 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Matthew H

A new power supply for superconductive magnetic energy storage system

International Nuclear Information System (INIS)

Karady, G.G.; Han, B.M.

1992-01-01

In this paper a new power supply for a superconductive magnetic energy storage system, which permits a fast independent regulation of the active and reactive power, is presented. The power supply is built with several units connected in parallel. Each unit consists of a 24-pulse bridge converter, thyristor-switched tap-changing transformer, and thyristor-switched capacitor bank. Its system operation is analyzed by computer simulation and a feasible system realization is shown. A superconductive magnetic energy storage system with the proposed power supply has the capability of leveling the load variation, damping the low-frequency oscillation, and improving the transient stability in the power system. This power supply can be built with commercially available components using well-proven technologies

Carbons, ionic liquids and quinones for electrochemical capacitors

Directory of Open Access Journals (Sweden)

Raul eDiaz

2016-04-01

Full Text Available Carbons are the main electrode materials used in electrochemical capacitors, which are electrochemical energy storage devices with high power densities and long cycling lifetimes. However, increasing their energy density will improve their potential for commercial implementation. In this regard, the use of high surface area carbons and high voltage electrolytes are well known strategies to increase the attainable energy density, and lately ionic liquids have been explored as promising alternatives to current state of the art acetonitrile-based electrolytes. Also, in terms of safety and sustainability ionic liquids are attractive electrolyte materials for electrochemical capacitors. In addition, it has been shown that the matching of the carbon pore size with the electrolyte ion size further increases the attainable electric double layer (EDL capacitance and energy density.The use of pseudocapacitive reactions can significantly increase the attainable energy density, and quinonic-based materials offer a potentially sustainable and cost effective research avenue for both the electrode and the electrolyte. This perspective will provide an overview of the current state of the art research on electrochemical capacitors based on combinations of carbons, ionic liquids and quinonic compounds, highlighting performances and challenges and discussing possible future research avenues. In this regard, current interest is mainly focused on strategies which may ultimately lead to commercially competitive sustainable high performance electrochemical capacitors for different applications including those requiring mechanical flexibility and biocompatibility.

An Active Capacitor with Self-Power and Internal Feedback Control Signals

DEFF Research Database (Denmark)

Wang, Haoran; Wang, Huai

2017-01-01

This paper proposes a concept of two-terminal active capacitor implemented by power semiconductor switches and passive elements. The active capacitor has the same level of convenience as a passive one with two power terminals only. A control strategy that does not require any external feedback...... signal is proposed and a self-power scheme for gate drivers and the controller is applied to achieve the two-terminal active capacitor. The concept, control method, self-power scheme, efficiency, and impedance characteristics of the active capacitor are presented. A case study of the proposed active...... capacitor for a capacitive DC-link application is discussed. The results reveal a significantly lower overall energy storage of passive elements and a reduced cost to fulfill a specific reliability target, compared to a passive capacitor solution. Proof-of-concept experimental results are given to verify...

Analysis of switching surges generated by current interruption in an energy-storage coil

International Nuclear Information System (INIS)

Chowdhuri, P.

1981-01-01

The paper presents an analysis of the transient voltages which are generated when the current in a large magnetic energy storage coil is interrupted by a dc vacuum circuit breaker. The effect of the various parameters in the circuit on the transient voltage is discussed. The self inductance of the dump resistor must be minimized to control the generated transient. Contrary to general belief, a capacitor across the coil is not an effective surge suppressor. In fact, the capacitor may excite oscillations of higher magnitude. However, a capacitor, in addition to a surge suppressor, may be used to modify the frequency components of the transient voltage so that these frequency components are not coincident with the natural frequencies of the coil. Otherwise, resonant oscillations inside the coil may attain damaging magnitudes. The capacitor would also reduce the steepness of the wavefront of the transient across the coil, thus reducing the nonlinear voltage distribution inside the coil

Metal-free aqueous redox capacitor via proton rocking-chair system in an organic-based couple

Science.gov (United States)

Tomai, Takaaki; Mitani, Satoshi; Komatsu, Daiki; Kawaguchi, Yuji; Honma, Itaru

2014-01-01

Safe and inexpensive energy storage devices with long cycle lifetimes and high power and energy densities are mandatory for the development of electrical power grids that connect with renewable energy sources. In this study, we demonstrated metal-free aqueous redox capacitors using couples comprising low-molecular-weight organic compounds. In addition to the electric double layer formation, proton insertion/extraction reactions between a couple consisting of inexpensive quinones/hydroquinones contributed to the energy storage. This energy storage mechanism, in which protons are shuttled back and forth between two electrodes upon charge and discharge, can be regarded as a proton rocking-chair system. The fabricated capacitor showed a large capacity (>20 Wh/kg), even in the applied potential range between 0–1 V, and high power capability (>5 A/g). The support of the organic compounds in nanoporous carbon facilitated the efficient use of the organic compounds with a lifetime of thousands of cycles. PMID:24395117

Applications of CCTO supercapacitor in energy storage and electronics

Directory of Open Access Journals (Sweden)

R. K. Pandey

2013-06-01

Full Text Available Since the discovery of colossal dielectric constant in CCTO supercapacitor in 2000, development of its practical application to energy storage has been of great interest. In spite of intensive efforts, there has been thus far, no report of proven application. The object of this research is to understand the reason for this lack of success and to find ways to overcome this limitation. Reported herein is the synthesis of our research in ceramic processing of this material and its characterization, particularly with the objective of identifying potential applications. Experimental results have shown that CCTO's permittivity and loss tangent, the two most essential dielectric parameters of fundamental importance for the efficiency of a capacitor device, are intrinsically coupled. They increase or decrease in tandem. Therefore, efforts to simultaneously retain the high permittivity while minimizing the loss tangent of CCTO might not succeed unless an entirely non-typical approach is taken for processing this material. Based on the experimental results and their analysis, it has been identified that it is possible to produce CCTO bulk ceramics with conventional processes having properties that can be exploited for fabricating an efficient energy storage device (EDS. We have additionally identified that CCTO can be used for the development of efficient solid state capacitors of Class II type comparable to the widely used barium titanate (BT capacitors. Based on high temperature studies of the resistivity and the Seebeck coefficient it is found that CCTO is a wide bandgap n-type semiconductor material which could be used for high temperature electronics. The temperature dependence of the linear thermal expansion of CCTO shows the presence of possible phase changes at 220 and 770 °C the origin of which remains unexplained.

Applications of CCTO supercapacitor in energy storage and electronics

Science.gov (United States)

Pandey, R. K.; Stapleton, W. A.; Tate, J.; Bandyopadhyay, A. K.; Sutanto, I.; Sprissler, S.; Lin, S.

2013-06-01

Since the discovery of colossal dielectric constant in CCTO supercapacitor in 2000, development of its practical application to energy storage has been of great interest. In spite of intensive efforts, there has been thus far, no report of proven application. The object of this research is to understand the reason for this lack of success and to find ways to overcome this limitation. Reported herein is the synthesis of our research in ceramic processing of this material and its characterization, particularly with the objective of identifying potential applications. Experimental results have shown that CCTO's permittivity and loss tangent, the two most essential dielectric parameters of fundamental importance for the efficiency of a capacitor device, are intrinsically coupled. They increase or decrease in tandem. Therefore, efforts to simultaneously retain the high permittivity while minimizing the loss tangent of CCTO might not succeed unless an entirely non-typical approach is taken for processing this material. Based on the experimental results and their analysis, it has been identified that it is possible to produce CCTO bulk ceramics with conventional processes having properties that can be exploited for fabricating an efficient energy storage device (EDS). We have additionally identified that CCTO can be used for the development of efficient solid state capacitors of Class II type comparable to the widely used barium titanate (BT) capacitors. Based on high temperature studies of the resistivity and the Seebeck coefficient it is found that CCTO is a wide bandgap n-type semiconductor material which could be used for high temperature electronics. The temperature dependence of the linear thermal expansion of CCTO shows the presence of possible phase changes at 220 and 770 °C the origin of which remains unexplained.

Energy storage

International Nuclear Information System (INIS)

Anon.

1992-01-01

This chapter discusses the role that energy storage may have on the energy future of the US. The topics discussed in the chapter include historical aspects of energy storage, thermal energy storage including sensible heat storage, latent heat storage, thermochemical heat storage, and seasonal heat storage, electricity storage including batteries, pumped hydroelectric storage, compressed air energy storage, and superconducting magnetic energy storage, and production and combustion of hydrogen as an energy storage option

In Situ High-Level Nitrogen Doping into Carbon Nanospheres and Boosting of Capacitive Charge Storage in Both Anode and Cathode for a High-Energy 4.5 V Full-Carbon Lithium-Ion Capacitor.

Science.gov (United States)

Sun, Fei; Liu, Xiaoyan; Wu, Hao Bin; Wang, Lijie; Gao, Jihui; Li, Hexing; Lu, Yunfeng

2018-05-02

To circumvent the imbalances of electrochemical kinetics and capacity between Li + storage anodes and capacitive cathodes for lithium-ion capacitors (LICs), we herein demonstrate an efficient solution by boosting the capacitive charge-storage contributions of carbon electrodes to construct a high-performance LIC. Such a strategy is achieved by the in situ and high-level doping of nitrogen atoms into carbon nanospheres (ANCS), which increases the carbon defects and active sites, inducing more rapidly capacitive charge-storage contributions for both Li + storage anodes and PF 6 - storage cathodes. High-level nitrogen-doping-induced capacitive enhancement is successfully evidenced by the construction of a symmetric supercapacitor using commercial organic electrolytes. Coupling a pre-lithiated ANCS anode with a fresh ANCS cathode enables a full-carbon LIC with a high operating voltage of 4.5 V and high energy and power densities thereof. The assembled LIC device delivers high energy densities of 206.7 and 115.4 Wh kg -1 at power densities of 0.225 and 22.5 kW kg -1 , respectively, as well as an unprecedented high-power cycling stability with only 0.0013% capacitance decay per cycle within 10 000 cycles at a high power output of 9 kW kg -1 .

Process Optimization of P(VDF-TrFE)-BaTiO3 Nanocomposites for Storage Capacitor Applications

KAUST Repository

Almadhoun, Mahmoud N.

2011-01-01

are considered to be one possible solution towards the fabrication of high energy density capacitors, whether as embedded capacitors or gate insulators in organic field effect transistors (OFETs). Selecting high permittivity ceramics mixed with polymers with high

Extracting renewable energy from a salinity difference using a capacitor.

Science.gov (United States)

Brogioli, Doriano

2009-07-31

Completely renewable energy can be produced by using water solutions of different salinity, like river water and sea water. Many different methods are already known, but development is still at prototype stage. Here I report a novel method, based on electric double-layer capacitor technology. Two porous electrodes, immersed in the salt solution, constitute a capacitor. It is first charged, then the salt solution is brought into contact with fresh water. The electrostatic energy increases as the salt concentration of the solution is reduced due to diffusion. This device can be used to turn sources of salinity difference into completely renewable sources of energy. An experimental demonstration is given, and performances and possible improvements are discussed.

Pulse Power Capability Of High Energy Density Capacitors Based on a New Dielectric Material

Science.gov (United States)

Winsor, Paul; Scholz, Tim; Hudis, Martin; Slenes, Kirk M.

1999-01-01

A new dielectric composite consisting of a polymer coated onto a high-density metallized Kraft has been developed for application in high energy density pulse power capacitors. The polymer coating is custom formulated for high dielectric constant and strength with minimum dielectric losses. The composite can be wound and processed using conventional wound film capacitor manufacturing equipment. This new system has the potential to achieve 2 to 3 J/cu cm whole capacitor energy density at voltage levels above 3.0 kV, and can maintain its mechanical properties to temperatures above 150 C. The technical and manufacturing development of the composite material and fabrication into capacitors are summarized in this paper. Energy discharge testing, including capacitance and charge-discharge efficiency at normal and elevated temperatures, as well as DC life testing were performed on capacitors manufactured using this material. TPL (Albuquerque, NM) has developed the material and Aerovox (New Bedford, MA) has used the material to build and test actual capacitors. The results of the testing will focus on pulse power applications specifically those found in electro-magnetic armor and guns, high power microwave sources and defibrillators.

Silicon-doped hafnium oxide anti-ferroelectric thin films for energy storage

Science.gov (United States)

Ali, Faizan; Liu, Xiaohua; Zhou, Dayu; Yang, Xirui; Xu, Jin; Schenk, Tony; Müller, Johannes; Schroeder, Uwe; Cao, Fei; Dong, Xianlin

2017-10-01

Motivated by the development of ultracompact electronic devices as miniaturized energy autonomous systems, great research efforts have been expended in recent years to develop various types of nano-structural energy storage components. The electrostatic capacitors characterized by high power density are competitive; however, their implementation in practical devices is limited by the low intrinsic energy storage density (ESD) of linear dielectrics like Al2O3. In this work, a detailed experimental investigation of energy storage properties is presented for 10 nm thick silicon-doped hafnium oxide anti-ferroelectric thin films. Owing to high field induced polarization and slim double hysteresis, an extremely large ESD value of 61.2 J/cm3 is achieved at 4.5 MV/cm with a high efficiency of ˜65%. In addition, the ESD and the efficiency exhibit robust thermal stability in 210-400 K temperature range and an excellent endurance up to 109 times of charge/discharge cycling at a very high electric field of 4.0 MV/cm. The superior energy storage performance together with mature technology of integration into 3-D arrays suggests great promise for this recently discovered anti-ferroelectric material to replace the currently adopted Al2O3 in fabrication of nano-structural supercapacitors.

Enhanced electric polarization and breakdown strength in the all-organic sandwich-structured poly(vinylidene fluoride-based dielectric film for high energy density capacitor

Directory of Open Access Journals (Sweden)

Yue Zhang

2017-07-01

Full Text Available It is essential to develop the dielectric energy storage capacitor for the modern electrical and electronic equipment. Here, the all-organic sandwich-structured composite with superior breakdown strength and delayed saturation polarization is presented. Furthermore, the energy storage characteristics of the composite are enhanced by the poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene fiber and the redistribution of local electric field. The dielectric permittivity of composite increases to ∼16, and the discharged energy density is high to ∼8.7 J/cm3 at 360 kV/mm, and the breakdown strength is up to ∼408 kV/mm. The excellent performance of the composite broadens the application in the field of power electronics industry.

25-MJ energy storage system delivers 3.5 MA in 1 ms

International Nuclear Information System (INIS)

Whitham, K.

1978-01-01

A 25-MJ, 20-kV capacitive energy storage and delivery system has been built and tested for Shiva. LLL laser fusion program's giant, multiarmed fusion research laser. This system supplies more than 3.5 MA in less than 1 ms to 2400 xenon flashlamps for optical pumping of laser amplifiers. The peak powder requirements of this energy need exceed the capacity of the public utility power grid. Thus, to achieve this peak power, we developed a large capacitor bank as the intermediate storage and power conditioner. Because personnel safety was a prime consideration, we implemented a grounding and fault scheme that minimizes the possibilities of faults extending outside the prescribed areas. Also, the cost and construction period were well within the original plan

Energy Storage.

Science.gov (United States)

Eaton, William W.

Described are technological considerations affecting storage of energy, particularly electrical energy. The background and present status of energy storage by batteries, water storage, compressed air storage, flywheels, magnetic storage, hydrogen storage, and thermal storage are discussed followed by a review of development trends. Included are…

Iso-Oriented NaTi2(PO4)3 Mesocrystals as Anode Material for High-Energy and Long-Durability Sodium-Ion Capacitor.

Science.gov (United States)

Wei, Tongye; Yang, Gongzheng; Wang, Chengxin

2017-09-20

Sodium-ion capacitors (SIC) combine the merits of both high-energy batteries and high-power electrochemical capacitors as well as the low cost and high safety. However, they are also known to suffer from the severe deficiency of suitable electrode materials with high initial Coulombic efficiency (ICE) and kinetic balance between both electrodes. Herein, we report a facile solvothermal synthesis of NaTi 2 (PO 4 ) 3 nanocages constructed by iso-oriented tiny nanocrystals with a mesoporous architecture. It is notable that the NaTi 2 (PO 4 ) 3 mesocrystals exhibit a large ICE of 94%, outstanding rate capability (98 mA h g -1 at 10 C), and long cycling life (over 77% capacity retention after 10 000 cycles) in half cells, all of which are in favor to be utilized into a full cell. When assembled with commercial activated carbon to an SIC, the system delivers an energy density of 56 Wh kg -1 at a power density of 39 W kg -1 . Even at a high current rate of 5 A g -1 (corresponds to finish a full charge/discharge process in 2 min), the SIC still works well after 20 000 cycles without obvious capacity degradation. With the merits of impressive energy/power densities and longevity, the obtained hybrid capacitor should be a promising device for highly efficient energy storage systems.

Phase shift PWM with double two-switch bridge for high power capacitor charging

International Nuclear Information System (INIS)

Karandikar, U.S.; Singh, Yashpal; Thakurta, A.C.

2013-01-01

Pulse power supply systems working at higher voltage and high repetition rate demands for higher power from capacitor chargers. Capacitor charging requirement become more challenging in such cases. In pulse power circuits, energy storage capacitor should be charged to its desired voltage before the next switching occurs. It is discharged within a small time, delivering large pulse power. A capacitor charger has to work with wide load variation repeatedly. Many schemes are used for this purpose. The proposed scheme aims at reducing stresses on switches by reducing peak current and their evils. A high voltage power supply is designed for capacitor charging. The proposed scheme is based on a Phase-Shifted PWM without using any extra component to achieve soft switching. Indirect constant average current capacitor charging is achieved with a simple control scheme. A double two-switch bridge is proposed to enhance reliability. Power supply has been developed to charge a capacitor of 50 μF to 2.5 kV at 25 Hz. (author)

Study made of dielectric properties of promising materials for cryogenic capacitors

Science.gov (United States)

Mathes, K. N.; Minnich, S. H.

1967-01-01

Experimental investigations were conducted to determine dielectric properties of promising materials for cryogenic capacitors to be used in energy storage and pulse applications. The three classes of materials investigated were inorganic bonded ferroelectric materials, anodic coatings on metal foils, and polar low temperature liquids.

The impact of hybrid energy storage on power quality, when high power pulsed DC loads are operated on a microgrid testbed

Science.gov (United States)

Kelley, Jay Paul

As the Navy's demands for high power transient loads evolves, so too does the need for alternative energy sources to back-up the more traditional power generation. Such applications in need of support include electrical grid backup and directed energy weapon systems such as electromagnetic launchers, laser systems, and high power microwave generators, among others. Among the alternative generation sources receiving considerable attention are energy storage devices such as rechargeable electrochemical batteries and capacitors. In such applications as those mentioned above, these energy storage devices offer the ability to serve a dual role as both a power source to the various loads as well high power loads themselves to the continual generation when the high power transient loads are in periods of downtime. With the recent developments in electrochemical energy storage, lithium-ion batteries (LIBs) seem like the obvious choice, but previous research has shown that the elevated rates of charging can be detrimental to both the cycle life and the operational life span of the device. In order to preserve the batteries, their charge rate must be limited. One proposed method to accomplish the dual role task mentioned above, while preserving the life of the batteries, is by combining high energy density LIBs with high power density electric double layer capacitors (EDLCs) or lithium-ion capacitors (LICs) using controllable power electronics to adjust the flow of power to and from each device. Such a configuration is typically referred to as hybrid energy storage module (HESM). While shipboard generators start up, the combined high energy density and high power density of the HESM provides the capability to source critical loads for an extended period of time at the high rates they demand. Once the generator is operationally efficient, the HESM can act as a high energy reservoir to harvest the energy from the generator while the loads are in short periods of inactivity

Chemical modification of graphene aerogels for electrochemical capacitor applications.

Science.gov (United States)

Hong, Jin-Yong; Wie, Jeong Jae; Xu, Yu; Park, Ho Seok

2015-12-14

Graphene aerogel is a relatively new type of aerogel that is ideal for energy storage applications because of its large surface area, high electrical conductivity and good chemical stability. Also, three dimensional interconnected macropores offer many advantages such as low density, fast ion and mass transfer, and easy access to storage sites. Such features allow graphene aerogels to be intensively applied for electrochemical capacitor applications. Despite the growing interest in graphene aerogel-based electrochemical capacitors, however, the graphene aerogels still suffer from their low capacitive performances and high fragility. Both relatively low capacitance and brittleness of physically crosslinked graphene aerogels remain a critical challenge. Until now, a number of alternative attempts have been devoted to overcome these shortcomings. In this perspective, we summarize the recent research progress towards the development of advanced graphene aerogel-based electrochemical capacitors according to the different approaches (e.g. porosity, composition and structure controls). Then, the recently proposed chemical strategies to improve the capacitive performances and mechanical durability of graphene aerogels for practical applications are highlighted. Finally, the current challenges and perspectives in this emerging material are also discussed.

Tube-Super Dielectric Materials: Electrostatic Capacitors with Energy Density Greater than 200 J·cm-3.

Science.gov (United States)

Cortes, Francisco Javier Quintero; Phillips, Jonathan

2015-09-17

The construction and performance of a second generation of super dielectric material based electrostatic capacitors (EC), with energy density greater than 200 J·cm - ³, which rival the best reported energy density of electric double layer capacitors (EDLC), also known as supercapacitors, are reported. The first generation super dielectric materials (SDM) are multi-material mixtures with dielectric constants greater than 1.0 × 10⁵, composed of a porous, electrically insulating powder filled with a polarizable, ion-containing liquid. Second-generation SDMs (TSDM), introduced here, are anodic titania nanotube arrays filled with concentrated aqueous salt solutions. Capacitors using TiO₂ based TSDM were found to have dielectric constants at ~0 Hz greater than 10⁷ in all cases, a maximum operating voltage of greater than 2 volts and remarkable energy density that surpasses the highest previously reported for EC capacitors by approximately one order of magnitude. A simple model based on the classic ponderable media model was shown to be largely consistent with data from nine EC type capacitors employing TSDM.

Tube-Super Dielectric Materials: Electrostatic Capacitors with Energy Density Greater than 200 J·cm−3

Directory of Open Access Journals (Sweden)

Francisco Javier Quintero Cortes

2015-09-01

Full Text Available The construction and performance of a second generation of super dielectric material based electrostatic capacitors (EC, with energy density greater than 200 J·cm−3, which rival the best reported energy density of electric double layer capacitors (EDLC, also known as supercapacitors, are reported. The first generation super dielectric materials (SDM are multi-material mixtures with dielectric constants greater than 1.0 × 105, composed of a porous, electrically insulating powder filled with a polarizable, ion-containing liquid. Second-generation SDMs (TSDM, introduced here, are anodic titania nanotube arrays filled with concentrated aqueous salt solutions. Capacitors using TiO2 based TSDM were found to have dielectric constants at ~0 Hz greater than 107 in all cases, a maximum operating voltage of greater than 2 volts and remarkable energy density that surpasses the highest previously reported for EC capacitors by approximately one order of magnitude. A simple model based on the classic ponderable media model was shown to be largely consistent with data from nine EC type capacitors employing TSDM.

Lower-Energy Energy Storage System (LEESS) Evaluation in a Full-Hybrid Electric Vehicle (HEV) (Presentation)

Energy Technology Data Exchange (ETDEWEB)

Cosgrove, J.; Gonder, J.; Pesaran, A.

2013-11-01

The cost of hybrid electric vehicles (HEVs) (e.g., Toyota Prius or Ford Fusion Hybrid) remains several thousand dollars higher than the cost of comparable conventional vehicles, which has limited HEV market penetration. The battery energy storage device is typically the component with the greatest contribution toward this cost increment, so significant cost reductions/performance improvements to the energy storage system (ESS) can improve the vehicle-level cost-benefit relationship, which would in turn lead to larger HEV market penetration and greater aggregate fuel savings. The National Renewable Energy Laboratory (NREL) collaborated with a United States Advanced Battery Consortium (USABC) Workgroup to analyze trade-offs between vehicle fuel economy and reducing the minimum energy requirement for power-assist HEVs. NREL's analysis showed that significant fuel savings could still be delivered from an ESS with much lower energy storage than previous targets, which prompted the United States Advanced Battery Consortium (USABC) to issue a new set of lower-energy ESS (LEESS) targets that could be satisfied by a variety of technologies, including high-power batteries or ultracapacitors. NREL has developed an HEV test platform for in-vehicle performance and fuel economy validation testing of the hybrid system using such LEESS devices. This presentation describes development of the vehicle test platform and in-vehicle evaluation results using a lithium-ion capacitor ESS-an asymmetric electrochemical energy storage device possessing one electrode with battery-type characteristics (lithiated graphite) and one with ultracapacitor-type characteristics (carbon). Further efforts include testing other ultracapacitor technologies in the HEV test platform.

Peculiar Li-storage mechanism at graphene edges in turbostratic carbon black and their application in high energy Li-ion capacitor

Science.gov (United States)

Anothumakkool, Bihag; Dupré, Nicolas; Moreau, Philippe; Guyomard, Dominique; Brousse, Thierry; Gaubicher, Joel

2018-02-01

We report experimental evidence for the specific Li-storage at turbostratic graphene edges of a well-known and cheap Super P® carbon black (Csp) material, which is usually used as a conductive additive in composite electrodes. Indeed, operando XRD and HR-TEM consistently demonstrate Li insertion occurs with zero expansion of graphene layer up to a composition of Li0.4C6 (150 mA h/g) that is reached at 0.01 V vs. Li+/Li. 7Li NMR substantiates these results and suggests that the weak electronic transfer from the carbon host to the intercalant could help local reorganization of the layer order as suggested by the unexpected reversible changes of the (002) Bragg peak intensity during the charge-discharge process. Our observations also indicate this insertion mechanism is kinetically favored resulting in remarkable cycling stability over 1000 cycles and power capability allowing to sustain 110 mA h/g at 8 A/g (21 C) in half cell. The capability of Csp as an efficient anode is ultimately demonstrated in a lithium hybrid capacitor against a positive electrode of activated carbon. The full cell delivers a maximum energy of 120 Wh/kg (4.3-2 V) and remarkable capacity retention over 1800 cycles.

Thin and flexible Ni-P based current collectors developed by electroless deposition for energy storage devices

International Nuclear Information System (INIS)

Wu, Haoran; Susanto, Amelia; Lian, Keryn

2017-01-01

Highlights: • A PET metallized by electroless nickel was developed as flexible current collector. • The Ni-PET current collector showed good conductivity and chemical stability. • The flexible nanocarbon electrodes with Ni-PET exhibited capacitive behavior. • The Ni-PET enabled electrodes performed nicely in liquid and solid supercapacitors. - Abstract: A PET film metalized by electroless nickel deposition was demonstrated as thin and flexible current collector for energy storage devices. The resultant nickel-on-PET film (Ni-PET) can be used both as current collector for electrochemical capacitors and as electrode for thin film batteries. The composition of Ni-PET was characterized by EDX and XPS. The electrochemical performance of the Ni-PET current collector was similar to Ni foil but with less hydrogen evolution at low potential. The Ni-PET film exhibited better flexibility than a metallic Ni foil. Carbon nanotubes were coated on a Ni-PET substrate to form an electrochemical capacitor electrode which exhibited high chemical stability in both liquid and solid electrolytes, showing strong promise for solid energy storage devices.

Thin and flexible Ni-P based current collectors developed by electroless deposition for energy storage devices

Energy Technology Data Exchange (ETDEWEB)

Wu, Haoran, E-mail: haoran.wu@mail.utoronto.ca; Susanto, Amelia; Lian, Keryn

2017-02-01

Highlights: • A PET metallized by electroless nickel was developed as flexible current collector. • The Ni-PET current collector showed good conductivity and chemical stability. • The flexible nanocarbon electrodes with Ni-PET exhibited capacitive behavior. • The Ni-PET enabled electrodes performed nicely in liquid and solid supercapacitors. - Abstract: A PET film metalized by electroless nickel deposition was demonstrated as thin and flexible current collector for energy storage devices. The resultant nickel-on-PET film (Ni-PET) can be used both as current collector for electrochemical capacitors and as electrode for thin film batteries. The composition of Ni-PET was characterized by EDX and XPS. The electrochemical performance of the Ni-PET current collector was similar to Ni foil but with less hydrogen evolution at low potential. The Ni-PET film exhibited better flexibility than a metallic Ni foil. Carbon nanotubes were coated on a Ni-PET substrate to form an electrochemical capacitor electrode which exhibited high chemical stability in both liquid and solid electrolytes, showing strong promise for solid energy storage devices.

Faraday Rotator 5 kV Capacitor Bank

International Nuclear Information System (INIS)

Fetterman, C.C.

1975-01-01

A Faraday rotator 5 kV capacitor bank is a pulsed output power supply used to energize Faraday rotators for optical isolation in the ''LLL kJ Glass Laser System.'' Each supply contains either one, two or three parallel 240 μF storage capacitors depending on the size of the isolator used. Generally, the ''A*''(216 μH) isolator is energized with one capacitor, the ''A''(116 μH) isolator uses two capacitors and the ''B''(87 μH) isolator requires three capacitors. All models of isolators have been tested with four capacitors under maximum voltage and 25 feet of RG-217 cable with no hazardous effects. Except for the number of capacitors in each unit, the supplies are otherwise physically identical

Capacitance of carbon-based electrical double-layer capacitors.

Science.gov (United States)

Ji, Hengxing; Zhao, Xin; Qiao, Zhenhua; Jung, Jeil; Zhu, Yanwu; Lu, Yalin; Zhang, Li Li; MacDonald, Allan H; Ruoff, Rodney S

2014-01-01

Experimental electrical double-layer capacitances of porous carbon electrodes fall below ideal values, thus limiting the practical energy densities of carbon-based electrical double-layer capacitors. Here we investigate the origin of this behaviour by measuring the electrical double-layer capacitance in one to five-layer graphene. We find that the capacitances are suppressed near neutrality, and are anomalously enhanced for thicknesses below a few layers. We attribute the first effect to quantum capacitance effects near the point of zero charge, and the second to correlations between electrons in the graphene sheet and ions in the electrolyte. The large capacitance values imply gravimetric energy storage densities in the single-layer graphene limit that are comparable to those of batteries. We anticipate that these results shed light on developing new theoretical models in understanding the electrical double-layer capacitance of carbon electrodes, and on opening up new strategies for improving the energy density of carbon-based capacitors.

Electrochemical capacitor based on materials with pseudocapacitive properties

OpenAIRE

Olivia Moreno, David

2011-01-01

This thesis is divided into two chapters. Chapter 1 is about energy storage device such as the electrochemical capacitor (EC) and the electrode materials used for its construction. The basic principle of supercapacitor performance, double-layer capacitance and pseudocapacitance phenomena are described in the introduction. Activated carbons, nanotubes, conducting polymers and metal oxides as well as their composites were considered as electrode materials. Symmetric and asymmetric configurat...

Energy storage

Science.gov (United States)

Kaier, U.

1981-04-01

Developments in the area of energy storage are characterized, with respect to theory and laboratory, by an emergence of novel concepts and technologies for storing electric energy and heat. However, there are no new commercial devices on the market. New storage batteries as basis for a wider introduction of electric cars, and latent heat storage devices, as an aid for solar technology applications, with satisfactory performance standards are not yet commercially available. Devices for the intermediate storage of electric energy for solar electric-energy systems, and for satisfying peak-load current demands in the case of public utility companies are considered. In spite of many promising novel developments, there is yet no practical alternative to the lead-acid storage battery. Attention is given to central heat storage for systems transporting heat energy, small-scale heat storage installations, and large-scale technical energy-storage systems.

The Most Energy Efficient Way to Charge the Capacitor in an RC Circuit

Science.gov (United States)

Wang, Dake

2017-01-01

The voltage waveform that minimizes the energy loss in the resistance when charging the capacitor in a resistor-capacitor circuit is investigated using the calculus of variation. A linear voltage ramp gives the best efficiency, which means a constant current source should be used for charging. Comparison between constant current source and…

Nanoarchitectured graphene-based supercapacitors for next-generation energy-storage applications.

Science.gov (United States)

Salunkhe, Rahul R; Lee, Ying-Hui; Chang, Kuo-Hsin; Li, Jing-Mei; Simon, Patrice; Tang, Jing; Torad, Nagy L; Hu, Chi-Chang; Yamauchi, Yusuke

2014-10-20

Tremendous development in the field of portable electronics and hybrid electric vehicles has led to urgent and increasing demand in the field of high-energy storage devices. In recent years, many research efforts have been made for the development of more efficient energy-storage devices such as supercapacitors, batteries, and fuel cells. In particular, supercapacitors have great potential to meet the demands of both high energy density and power density in many advanced technologies. For the last half decade, graphene has attracted intense research interest for electrical double-layer capacitor (EDLC) applications. The unique electronic, thermal, mechanical, and chemical characteristics of graphene, along with the intrinsic benefits of a carbon material, make it a promising candidate for supercapacitor applications. This Review focuses on recent research developments in graphene-based supercapacitors, including doped graphene, activated graphene, graphene/metal oxide composites, graphene/polymer composites, and graphene-based asymmetric supercapacitors. The challenges and prospects of graphene-based supercapacitors are also discussed. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Nonmedical application of computed tomography to power capacitor quality assesment

International Nuclear Information System (INIS)

Kruger, R.P.

1981-01-01

Present research and development efforts at Los Alamos Scientific Laboratory require the design and use of high-efficiency rapid-discharge energy storage capacitors for laser isotope separation and plasma physics programs. In these applications, capacitors are subjected to electrical, mechanical, thermal, and other environmental stresses. These stresses cause the dielectric constant to change due to gasification from arcing at nonsoldering connections, which produce a chemical reduction of the dielectric material. This effectively limits the lifetime of the capacitor. The programs mentioned above require capacitors with a multikilohertz frequency response at a current of tens of kiloamperes and a voltage of at least 100 kV. The lifetime of such capacitors should exceed 10 10 charge/discharge cycles. Such capacitors do not presently exist. The exploration of new capacitor designs will require the use of both electrical functional tests and tests that show the changes in internal physical structure as the capacitor is repeatedly stressed by the charge/discharge cycle. The integration of electrical and structural tests throughout the life cycle of a candidate capacitor makes it imperative that the structural integrity tests be nondestructive. Computed tomography (CT) makes this integration possible. The work reported here is the result of a pilot project designed to show the potential use of CT for this application. This work includes visualization of material defects using both a layered sequence of conventional tomographic slices and orthogonal multiangular pseudoradiographs generated from these slices

Testing Low-Energy, High-Power Energy Storage Alternatives in a Full-Hybrid Vehicle (Presentation)

Energy Technology Data Exchange (ETDEWEB)

Cosgrove, J.; Gonger, J.

2014-01-01

Automakers have been mass producing hybrid electric vehicles (HEVs) for well over a decade, and the technology has proven to be very effective at reducing per-vehicle gasoline use. However, the battery cost in HEVs contribute to higher incremental cost of HEVs (a few thousand dollars) than the cost of comparable conventional vehicles, which has limited HEV market penetration. Significant cost reductions/performance improvements to the energy storage system (ESS) can improve the vehicle-level cost vs. benefit relationship for HEVs. Such an improvement could lead to larger HEV market penetration and greater aggregate gasoline savings. After significant analysis by the National Renewable Energy Laboratory (NREL), the United States Advanced Battery Consortium (USABC) and Department of Energy (DOE) Energy Storage program suggested a new set of requirements for ESS for power-assist HEVs for cost reduction without impacting performance and fuel economy significantly. With support from DOE, NREL has developed an HEV test platform for in-vehicle performance and fuel economy validation testing of the hybrid system using such LEESS devices. This poster will describe development of the LEESS HEV test platform, and LEESS laboratory as well as in-vehicle evaluation results. The first LEESS technology tested was lithium-ion capacitors (LICs) - i.e., asymmetric electrochemical energy storage devices possessing one electrode with battery-type characteristics (lithiated graphite) and one with ultracapacitor-type characteristics (carbon). We will discuss the performance and fuel saving results with LIC with comparison with original NiMH battery.

Low-dimensional carbon and MXene-based electrochemical capacitor electrodes.

Science.gov (United States)

Yoon, Yeoheung; Lee, Keunsik; Lee, Hyoyoung

2016-04-29

Due to their unique structure and outstanding intrinsic physical properties such as extraordinarily high electrical conductivity, large surface area, and various chemical functionalities, low-dimension-based materials exhibit great potential for application in electrochemical capacitors (ECs). The electrical properties of electrochemical capacitors are determined by the electrode materials. Because energy charge storage is a surface process, the surface properties of the electrode materials greatly influence the electrochemical performance of the cell. Recently, graphene, a single layer of sp(2)-bonded carbon atoms arrayed into two-dimensional carbon nanomaterial, has attracted wide interest as an electrode material for electrochemical capacitor applications due to its unique properties, including a high electrical conductivity and large surface area. Several low-dimensional materials with large surface areas and high conductivity such as onion-like carbons (OLCs), carbide-derived carbons (CDCs), carbon nanotubes (CNTs), graphene, metal hydroxide, transition metal dichalcogenides (TMDs), and most recently MXene, have been developed for electrochemical capacitors. Therefore, it is useful to understand the current issues of low-dimensional materials and their device applications.

Low-dimensional carbon and MXene-based electrochemical capacitor electrodes

International Nuclear Information System (INIS)

Yoon, Yeoheung; Lee, Hyoyoung; Lee, Keunsik

2016-01-01

Due to their unique structure and outstanding intrinsic physical properties such as extraordinarily high electrical conductivity, large surface area, and various chemical functionalities, low-dimension-based materials exhibit great potential for application in electrochemical capacitors (ECs). The electrical properties of electrochemical capacitors are determined by the electrode materials. Because energy charge storage is a surface process, the surface properties of the electrode materials greatly influence the electrochemical performance of the cell. Recently, graphene, a single layer of sp 2 -bonded carbon atoms arrayed into two-dimensional carbon nanomaterial, has attracted wide interest as an electrode material for electrochemical capacitor applications due to its unique properties, including a high electrical conductivity and large surface area. Several low-dimensional materials with large surface areas and high conductivity such as onion-like carbons (OLCs), carbide-derived carbons (CDCs), carbon nanotubes (CNTs), graphene, metal hydroxide, transition metal dichalcogenides (TMDs), and most recently MXene, have been developed for electrochemical capacitors. Therefore, it is useful to understand the current issues of low-dimensional materials and their device applications. (topical review)

The CUNY Energy Institute Electrical Energy Storage Development for Grid Applications

Energy Technology Data Exchange (ETDEWEB)

Banerjee, Sanjoy

2013-03-31

1. Project Objectives The objectives of the project are to elucidate science issues intrinsic to high energy density electricity storage (battery) systems for smart-grid applications, research improvements in such systems to enable scale-up to grid-scale and demonstrate a large 200 kWh battery to facilitate transfer of the technology to industry. 2. Background Complex and difficult to control interfacial phenomena are intrinsic to high energy density electrical energy storage systems, since they are typically operated far from equilibrium. One example of such phenomena is the formation of dendrites. Such dendrites occur on battery electrodes as they cycle, and can lead to internal short circuits, reducing cycle life. An improved understanding of the formation of dendrites and their control can improve the cycle life and safety of many energy storage systems, including rechargeable lithium and zinc batteries. Another area where improved understanding is desirable is the application of ionic liquids as electrolytes in energy storage systems. An ionic liquid is typically thought of as a material that is fully ionized (consisting only of anions and cations) and is fluid at or near room temperature. Some features of ionic liquids include a generally high thermal stability (up to 450 °C), a high electrochemical window (up to 6 V) and relatively high intrinsic conductivities. Such features make them attractive as battery or capacitor electrolytes, and may enable batteries which are safer (due to the good thermal stability) and of much higher energy density (due to the higher voltage electrode materials which may be employed) than state of the art secondary (rechargeable) batteries. Of particular interest is the use of such liquids as electrolytes in metal air batteries, where energy densities on the order of 1-2,000 Wh / kg are possible; this is 5-10 times that of existing state of the art lithium battery technology. The Energy Institute has been engaged in the

Development of compact rapid charging power supply for capacitive energy storage in pulsed power drivers.

Science.gov (United States)

Sharma, Surender Kumar; Shyam, Anurag

2015-02-01

High energy capacitor bank is used for primary electrical energy storage in pulsed power drivers. The capacitors used in these pulsed power drivers have low inductance, low internal resistance, and less dc life, so it has to be charged rapidly and immediately discharged into the load. A series resonant converter based 45 kV compact power supply is designed and developed for rapid charging of the capacitor bank with constant charging current up to 150 mA. It is short circuit proof, and zero current switching technique is used to commute the semiconductor switch. A high frequency resonant inverter switching at 10 kHz makes the overall size small and reduces the switching losses. The output current of the power supply is limited by constant on-time and variable frequency switching control technique. The power supply is tested by charging the 45 kV/1.67 μF and 15 kV/356 μF capacitor banks. It has charged the capacitor bank up to rated voltage with maximum charging current of 150 mA and the average charging rate of 3.4 kJ/s. The output current of the power supply is limited by reducing the switching frequency at 5 kHz, 3.3 kHz, and 1.7 kHz and tested with 45 kV/1.67 μF capacitor bank. The protection circuit is included in the power supply for over current, under voltage, and over temperature. The design details and the experimental testing results of the power supply for resonant current, output current, and voltage traces of the power supply with capacitive, resistive, and short circuited load are presented and discussed.

Thermal Vapor Deposition and Characterization of Polymer-Ceramic Nanoparticle Thin Films and Capacitors

Science.gov (United States)

Iwagoshi, Joel A.

Research on alternative energies has become an area of increased interest due to economic and environmental concerns. Green energy sources, such as ocean, wind, and solar power, are subject to predictable and unpredictable generation intermittencies which cause instability in the electrical grid. This problem could be solved through the use of short term energy storage devices. Capacitors made from composite polymer:nanoparticle thin films have been shown to be an economically viable option. Through thermal vapor deposition, we fabricated dielectric thin films composed of the polymer polyvinylidine fluoride (PVDF) and the ceramic nanoparticle titanium dioxide (TiO2). Fully understanding the deposition process required an investigation of electrode and dielectric film deposition. Film composition can be controlled by the mass ratio of PVDF:TiO2 prior to deposition. An analysis of the relationship between the ratio of PVDF:TiO2 before and after deposition will improve our understanding of this novel deposition method. X-ray photoelectron spectroscopy and energy dispersive x-ray spectroscopy were used to analyze film atomic concentrations. The results indicate a broad distribution of deposited TiO2 concentrations with the highest deposited amount at an initial mass concentration of 17% TiO2. The nanoparticle dispersion throughout the film is analyzed through atomic force microscopy and energy dispersive x-ray spectroscopy. Images from these two techniques confirm uniform TiO2 dispersion with cluster size less than 300 nm. These results, combined with spectroscopic analysis, verify control over the deposition process. Capacitors were fabricated using gold parallel plates with PVDF:TiO 2 dielectrics. These capacitors were analyzed using the atomic force microscope and a capacohmeter. Atomic force microscope images confirm that our gold films are acceptably smooth. Preliminary capacohmeter measurements indicate capacitance values of 6 nF and break down voltages of 2.4 V

Graphene double-layer capacitor with ac line-filtering performance.

Science.gov (United States)

Miller, John R; Outlaw, R A; Holloway, B C

2010-09-24

Electric double-layer capacitors (DLCs) can have high storage capacity, but their porous electrodes cause them to perform like resistors in filter circuits that remove ripple from rectified direct current. We have demonstrated efficient filtering of 120-hertz current with DLCs with electrodes made from vertically oriented graphene nanosheets grown directly on metal current collectors. This design minimized electronic and ionic resistances and produced capacitors with RC time constants of less than 200 microseconds, in contrast with ~1 second for typical DLCs. Graphene nanosheets have a preponderance of exposed edge planes that greatly increases charge storage as compared with that of designs that rely on basal plane surfaces. Capacitors constructed with these electrodes could be smaller than the low-voltage aluminum electrolyte capacitors that are typically used in electronic devices.

Graphene Double-Layer Capacitor with ac Line-Filtering Performance

Science.gov (United States)

Miller, John R.; Outlaw, R. A.; Holloway, B. C.

2010-09-01

Electric double-layer capacitors (DLCs) can have high storage capacity, but their porous electrodes cause them to perform like resistors in filter circuits that remove ripple from rectified direct current. We have demonstrated efficient filtering of 120-hertz current with DLCs with electrodes made from vertically oriented graphene nanosheets grown directly on metal current collectors. This design minimized electronic and ionic resistances and produced capacitors with RC time constants of less than 200 microseconds, in contrast with ~1 second for typical DLCs. Graphene nanosheets have a preponderance of exposed edge planes that greatly increases charge storage as compared with that of designs that rely on basal plane surfaces. Capacitors constructed with these electrodes could be smaller than the low-voltage aluminum electrolyte capacitors that are typically used in electronic devices.

Evaluation of lead/carbon devices for utility applications : a study for the DOE Energy Storage Program.

Energy Technology Data Exchange (ETDEWEB)

Walmet, Paula S. (MeadWestvaco Corporation,North Charleston, SC)

2009-06-01

This report describes the results of a three-phase project that evaluated lead-based energy storage technologies for utility-scale applications and developed carbon materials to improve the performance of lead-based energy storage technologies. In Phase I, lead/carbon asymmetric capacitors were compared to other technologies that used the same or similar materials. At the end of Phase I (in 2005) it was found that lead/carbon asymmetric capacitors were not yet fully developed and optimized (cost/performance) to be a viable option for utility-scale applications. It was, however, determined that adding carbon to the negative electrode of a standard lead-acid battery showed promise for performance improvements that could be beneficial for use in utility-scale applications. In Phase II various carbon types were developed and evaluated in lead-acid batteries. Overall it was found that mesoporous activated carbon at low loadings and graphite at high loadings gave the best cycle performance in shallow PSoC cycling. Phase III studied cost/performance benefits for a specific utility application (frequency regulation) and the full details of this analysis are included as an appendix to this report.

A high energy and power sodium-ion hybrid capacitor based on nitrogen-doped hollow carbon nanowires anode

Science.gov (United States)

Li, Dongdong; Ye, Chao; Chen, Xinzhi; Wang, Suqing; Wang, Haihui

2018-04-01

The sodium ion hybrid capacitor (SHC) has been attracting much attention. However, the SHC's power density is significantly confined to a low level due to the sluggish ion diffusion in the anode. Herein, we propose to use an electrode with a high double layer capacitance as the anode in the SHC instead of insertion anodes. To this aim, nitrogen doped hollow carbon nanowires (N-HCNWs) with a high specific surface area are prepared, and the high capacitive contribution during the sodium ion storage process is confirmed by a series of electrochemical measurements. A new SHC consisting of a N-HCNW anode and a commercial active carbon (AC) cathode is fabricated for the first time. Due to the hybrid charge storage mechanism combining ion insertion and capacitive process, the as-fabricated SHC strikes a balance between the energy density and power density, a energy density of 108 Wh kg-1 and a power density of 9 kW kg-1 can be achieved, which overwhelms the electrochemical performances of most reported AC-based SHCs.

Development of a hybrid energy storage sizing algorithm associated with the evaluation of power management in different driving cycles

International Nuclear Information System (INIS)

Masoud, Masih Tehrani; Mohammad Reza, Ha'iri Yazdi; Esfahanian, Vahid; Sagha, Hossein

2012-01-01

In this paper, a hybrid energy storage sizing algorithm for electric vehicles is developed to achieve a semi optimum cost effective design. Using the developed algorithm, a driving cycle is divided into its micro-trips and the power and energy demands in each micro trip are determined. The battery size is estimated because the battery fulfills the power demands. Moreover, the ultra capacitor (UC) energy (or the number of UC modules) is assessed because the UC delivers the maximum energy demands of the different micro trips of a driving cycle. Finally, a design factor, which shows the power of the hybrid energy storage control strategy, is utilized to evaluate the newly designed control strategies. Using the developed algorithm, energy saving loss, driver satisfaction criteria, and battery life criteria are calculated using a feed forward dynamic modeling software program and are utilized for comparison among different energy storage candidates. This procedure is applied to the hybrid energy storage sizing of a series hybrid electric city bus in Manhattan and to the Tehran driving cycle. Results show that a higher aggressive driving cycle (Manhattan) requires more expensive energy storage system and more sophisticated energy management strategy

A review on electrochemical double-layer capacitors

International Nuclear Information System (INIS)

Sharma, Pawan; Bhatti, T.S.

2010-01-01

Various energy storage technologies have been developed in the market for various applications. Batteries flywheels, fuel cells are a few which are much common, those are being used in several countries and also research is also carrying on these technologies to make much better them. The electrochemical double-layer capacitor (EDLC) is an emerging technology, which really plays a key part in fulfilling the demands of electronic devices and systems, for present and future. This paper presents the historical background, classification, construction, modeling, testing, and voltage balancing of the EDLC technology. The applications of EDLC in electrical vehicles, power quality, and others are also discussed and their advantages over other storages technologies are also discussed.

Design definition of a mechanical capacitor

Science.gov (United States)

Michaelis, T. D.; Schlieban, E. W.; Scott, R. D.

1977-01-01

A design study and analyses of a 10 kW-hr, 15 kW mechanical capacitor system was studied. It was determined that magnetically supported wheels constructed of advanced composites have the potential for high energy density and high power density. Structural concepts are analyzed that yield the highest energy density of any structural design yet reported. Particular attention was paid to the problem of 'friction' caused by magnetic and I to the second power R losses in the suspension and motor-generator subsystems, and low design friction levels have been achieved. The potentially long shelf life of this system, and the absence of wearing parts, provide superior performance over conventional flywheels supported with mechanical bearings. Costs and economies of energy storage wheels were reviewed briefly.

A review of molecular modelling of electric double layer capacitors.

Science.gov (United States)

Burt, Ryan; Birkett, Greg; Zhao, X S

2014-04-14

Electric double-layer capacitors are a family of electrochemical energy storage devices that offer a number of advantages, such as high power density and long cyclability. In recent years, research and development of electric double-layer capacitor technology has been growing rapidly, in response to the increasing demand for energy storage devices from emerging industries, such as hybrid and electric vehicles, renewable energy, and smart grid management. The past few years have witnessed a number of significant research breakthroughs in terms of novel electrodes, new electrolytes, and fabrication of devices, thanks to the discovery of innovative materials (e.g. graphene, carbide-derived carbon, and templated carbon) and the availability of advanced experimental and computational tools. However, some experimental observations could not be clearly understood and interpreted due to limitations of traditional theories, some of which were developed more than one hundred years ago. This has led to significant research efforts in computational simulation and modelling, aimed at developing new theories, or improving the existing ones to help interpret experimental results. This review article provides a summary of research progress in molecular modelling of the physical phenomena taking place in electric double-layer capacitors. An introduction to electric double-layer capacitors and their applications, alongside a brief description of electric double layer theories, is presented first. Second, molecular modelling of ion behaviours of various electrolytes interacting with electrodes under different conditions is reviewed. Finally, key conclusions and outlooks are given. Simulations on comparing electric double-layer structure at planar and porous electrode surfaces under equilibrium conditions have revealed significant structural differences between the two electrode types, and porous electrodes have been shown to store charge more efficiently. Accurate electrolyte and

Energy storage technology for electric and hybrid vehicles. Matching technology to design requirements

Energy Technology Data Exchange (ETDEWEB)

Wahlstroem, J. [Sycon Energikonsult AB, Malmoe (Sweden)

1999-12-01

A central issue when dealing with electrical vehicles has always been how to store energy in sufficient quantities. On April 27 through 28 1999 a workshop was held on this matter at University of California Davis (UC Davis). Organizer and host was Dr. Andrew Burke and the Institute of Transportation Studies (ITS) at UC Davis. The workshop included battery technology, ultra capacitors and fly wheels, but did not include fuel cell technology. In this paper the conference is reviewed with the emphasis on battery development. A section on ultra capacitors and flywheels is also included. The overall observation made at the conference is that most of the effort on energy storage in electric and hybrid vehicles are put into batteries. There is some development on ultra capacitors but almost none on flywheels. The battery also seems to be the choice of the car industry at this point, especially the pulse battery for engine dominant hybrid vehicles, like the Toyota Prius. The battery manufacturers seem to focus more on technology development than cost reduction at this point. An important technological issue as of now is to improve thermal management in order to increase life of the batteries. But when the technological goals are met focus must shift to cost minimization and marketing if the battery electric vehicle shall make a market break through.

Thermal energy storage devices, systems, and thermal energy storage device monitoring methods

Science.gov (United States)

Tugurlan, Maria; Tuffner, Francis K; Chassin, David P.

2016-09-13

Thermal energy storage devices, systems, and thermal energy storage device monitoring methods are described. According to one aspect, a thermal energy storage device includes a reservoir configured to hold a thermal energy storage medium, a temperature control system configured to adjust a temperature of the thermal energy storage medium, and a state observation system configured to provide information regarding an energy state of the thermal energy storage device at a plurality of different moments in time.

Carbon nanotube based composites for electricity storage in supercapacitors

OpenAIRE

Zhang, Shengwen

2010-01-01

In the context of fossil-fuel shortage and climate change, the production, conversion, storage and distribution of energy have become the focus of today's world. Supercapacitors, with their unique energy and power density specifications, cover the application gap between batteries and conventional capacitors and hence making valuable contributions in energy storage and distribution. Caron nanotubes (CNTs), with their unique aspect ratio and other distinctive physical, electrochemical and...

Energy storage

CERN Document Server

Brunet, Yves

2013-01-01

Energy storage examines different applications such as electric power generation, transmission and distribution systems, pulsed systems, transportation, buildings and mobile applications. For each of these applications, proper energy storage technologies are foreseen, with their advantages, disadvantages and limits. As electricity cannot be stored cheaply in large quantities, energy has to be stored in another form (chemical, thermal, electromagnetic, mechanical) and then converted back into electric power and/or energy using conversion systems. Most of the storage technologies are examined: b

Process for the generation of high capacity pulses from an inductive energy storage device

International Nuclear Information System (INIS)

Maier, F.; Maier, S.

1984-01-01

An inductive storage circuit for generating high voltage pulses includes a quenching circuit and a discharge circuit each connected in parallel with a storage inductor. One branch of the quenching circuit includes a quenching capacitor and one branch of the discharge circuit includes a resistor and a diode in series. These two branches have a common junction, to which is connected a quenching thyristor that forms the second branch of each of the quenching and discharge circuits. Thus, the quenching thyristor is in series with each of the quenching capacitor and the discharge resistor

Thermal energy storage apparatus, controllers and thermal energy storage control methods

Science.gov (United States)

Hammerstrom, Donald J.

2016-05-03

Thermal energy storage apparatus, controllers and thermal energy storage control methods are described. According to one aspect, a thermal energy storage apparatus controller includes processing circuitry configured to access first information which is indicative of surpluses and deficiencies of electrical energy upon an electrical power system at a plurality of moments in time, access second information which is indicative of temperature of a thermal energy storage medium at a plurality of moments in time, and use the first and second information to control an amount of electrical energy which is utilized by a heating element to heat the thermal energy storage medium at a plurality of moments in time.

The Effects of Self-Discharge on the Performance of Symmetric Electric Double-Layer Capacitors and Active Electrolyte-Enhanced Supercapacitors: Insights from Modeling and Simulation

Science.gov (United States)

Ike, Innocent S.; Sigalas, Iakovos; Iyuke, Sunny E.

2017-02-01

The effects of self-discharge on the performance of symmetric electric double-layer capacitors (EDLCs) and active electrolyte-enhanced supercapacitors were examined by incorporating self-discharge into electrochemical capacitor models during charging and discharging. The sources of self-discharge in capacitors were side reactions or redox reactions and several impurities and electric double-layer (EDL) instability. The effects of self-discharge during capacitor storage was negligible since it took a fully charged capacitor a minimum of 14.0 days to be entirely discharged by self-discharge in all conditions studied, hence self-discharge in storage condition can be ignored. The first and second charge-discharge cycle energy efficiencies η_{{{{E}}1}} and η_{{{{E}}2}} of a capacitor of electrode effective conductivity α1 = 0.05 S/cm with only EDL instability self-discharge with current density J_{{VR}} = 1.25 × 10-3 A/cm2 were 72.33% and 72.34%, respectively. Also, energy efficiencies η_{{{{E}}1}} and η_{{{{E}}2}} of a similar capacitor with both side reactions and redox reactions and EDL instability self-discharges with current densities J_{{VR}} = 0.00125 A/cm2 and J_{{{{VR}}1}} = 0.0032 A/cm2 were 38.13% and 38.14% respectively, compared with 84.24% and 84.25% in a similar capacitor without self-discharge. A capacitor with only EDL instability self-discharge and that with both side reactions and redox reactions and EDL instability self-discharge lost 9.73 Wh and 28.38 Wh of energy, respectively, through self-discharge during charging and discharging. Hence, EDLCs charging and discharging time is significantly dependent on the self-discharge rate which are too large to be ignored.

Low-cost capacitor voltage inverter for outstanding performance in piezoelectric energy harvesting.

Science.gov (United States)

Lallart, Mickaël; Garbuio, Lauric; Richard, Claude; Guyomar, Daniel

2010-01-01

The purpose of this paper is to propose a new scheme for piezoelectric energy harvesting optimization. The proposed enhancement relies on a new topology for inverting the voltage across a single capacitor with reduced losses. The increase of the inversion quality allows a much more effective energy harvesting process using the so-called synchronized switch harvesting on inductor (SSHI) nonlinear technique. It is shown that the proposed architecture, based on a 2-step inversion, increases the harvested power by a theoretical factor up to square root of 2 (i.e., 40% gain) compared with classical SSHI, allowing an increase of the harvested power by a factor greater than 1000% compared with the standard energy harvesting technique for realistic values of inversion components. The proposed circuit, using only 4 digital switches and an intermediate capacitor, is also ultra-low power, because the inversion circuit does not require any external energy and the command signals are very simple.

A fast fault protection based on direction of bus-side capacitor discharge current for a high-surety power supply

DEFF Research Database (Denmark)

Li, Haijin; Chen, Min; Yang, Boping

2017-01-01

A short-circuit fault protection strategy based on the direction of bus-side capacitor discharge current for a high-surety power supply, known as Super Uninterruptable Power Supply (Super UPS), is studied in this paper. It consists of multiple energy sources and storage components. All energy...... strategy is necessary to keep the uninterruptable power for the critical load. In this paper, the characteristics of the short-circuit fault are analyzed first. Then, a fast short-circuit fault locating and isolating strategy based on the direction of the discharge current of the busside capacitors...

Capacitive Energy Storage from - 50o to 100o Using an Ionic Liquid Electrolyte

Energy Technology Data Exchange (ETDEWEB)

Lin, Rongying [Universite Paul Sabatier, Toulouse Cedex, France.; Taberna, Pierre-Louis [Universite Paul Sabatier, Toulouse Cedex, France.; Santini, Sebastien [SOLVIONIC Company, Toulouse, France; Presser, Volker [ORNL; Perez, Carlos R. [Drexel University; Malbosc, Francois [SOLVIONIC Company, Toulouse, France; Rupesinghe, Nalin L. [AIXTRON, Cambridge, UK; Teo, Kenneth B. K. [AIXTRON, Cambridge, UK; Gogotsi, Yury G. [Drexel University; Simon, Patrice [Universite Paul Sabatier, Toulouse Cedex, France.

2011-01-01

Relying on redox reactions, most batteries are limited in their ability to operate at very low or very high temperatures. While performance of electrochemical capacitors is less dependent on the temperature, present-day devices still cannot cover the entire range needed for automotive and electronics applications under a variety of environmental conditions. We show that the right combination of the exohedral nanostructured carbon (nanotubes and onions) electrode and a eutectic mixture of ionic liquids can dramatically extend the temperature range of electrical energy storage, thus defying the conventional wisdom that ionic liquids can only be used as electrolytes above room temperature. We demonstrate electrical double layer capacitors able to operate from 50 to 100 C over a wide voltage window (up to 3.7 V) and at very high charge/discharge rates of up to 20 V/s.

Energy storage

Energy Technology Data Exchange (ETDEWEB)

1962-07-01

The papers on energy storage problems, given to the United Nations Conference on New Sources of Energy, Rome, 1961, are reviewed. Many aspects of the subject are discussed: comparisons between the costs of storing energy in batteries and in fuel cells; the use, efficiency and expected improvement of fuel cells; the principles involved in the chemical conversion of solar energy to chemical energy; the use of metal hydride fuel cells; the chemical conversion and storage of concentrated solar energy for which the solar furnace is used for photochemical reactions. Finally, the general costs of storing energy in any form and delivering it are analyzed with particular reference to storage batteries and fuel cells.

Capacitor discharge engineering

CERN Document Server

Früngel, Frank B A

1976-01-01

High Speed Pulse Technology, Volume III: Capacitor Discharge Engineering covers the production and practical application of capacitor dischargers for the generation and utilization of high speed pulsed of energy in different forms. This nine-chapter volume discusses the principles of electric current, voltage, X-rays, gamma rays, heat, beams of electrons, neutrons and ions, magnetic fields, sound, and shock waves in gases and liquids. Considerable chapters consider the applications of capacitor discharges, such as impulse hardening of steel, ultrapulse welding of precision parts, X-ray flash t

Charging System Optimization of Triboelectric Nanogenerator for Water Wave Energy Harvesting and Storage.

Science.gov (United States)

Yao, Yanyan; Jiang, Tao; Zhang, Limin; Chen, Xiangyu; Gao, Zhenliang; Wang, Zhong Lin

2016-08-24

Ocean waves are one of the most promising renewable energy sources for large-scope applications due to the abundant water resources on the earth. Triboelectric nanogenerator (TENG) technology could provide a new strategy for water wave energy harvesting. In this work, we investigated the charging characteristics of utilizing a wavy-structured TENG to charge a capacitor under direct water wave impact and under enclosed ball collision, by combination of theoretical calculations and experimental studies. The analytical equations of the charging characteristics were theoretically derived for the two cases, and they were calculated for various load capacitances, cycle numbers, and structural parameters such as compression deformation depth and ball size or mass. Under the direct water wave impact, the stored energy and maximum energy storage efficiency were found to be controlled by deformation depth, while the stored energy and maximum efficiency can be optimized by the ball size under the enclosed ball collision. Finally, the theoretical results were well verified by the experimental tests. The present work could provide strategies for improving the charging performance of TENGs toward effective water wave energy harvesting and storage.

How to Transform, with a Capacitor, Thermal Energy into Usable Work

Science.gov (United States)

Miranda, E. N.

2010-01-01

The temperature dependence of the dielectric permittivity is taken into account to study the energy change in a capacitor that follows a cycle between a cold and a hot thermal reservoir. There is a net energy gain in the process that, in principle, can be transformed into usable work. The paper is simple enough as to be used with keen…

Carbon-Based Materials for Lithium-Ion Batteries, Electrochemical Capacitors, and Their Hybrid Devices.

Science.gov (United States)

Yao, Fei; Pham, Duy Tho; Lee, Young Hee

2015-07-20

A rapidly developing market for portable electronic devices and hybrid electrical vehicles requires an urgent supply of mature energy-storage systems. As a result, lithium-ion batteries and electrochemical capacitors have lately attracted broad attention. Nevertheless, it is well known that both devices have their own drawbacks. With the fast development of nanoscience and nanotechnology, various structures and materials have been proposed to overcome the deficiencies of both devices to improve their electrochemical performance further. In this Review, electrochemical storage mechanisms based on carbon materials for both lithium-ion batteries and electrochemical capacitors are introduced. Non-faradic processes (electric double-layer capacitance) and faradic reactions (pseudocapacitance and intercalation) are generally explained. Electrochemical performance based on different types of electrolytes is briefly reviewed. Furthermore, impedance behavior based on Nyquist plots is discussed. We demonstrate the influence of cell conductivity, electrode/electrolyte interface, and ion diffusion on impedance performance. We illustrate that relaxation time, which is closely related to ion diffusion, can be extracted from Nyquist plots and compared between lithium-ion batteries and electrochemical capacitors. Finally, recent progress in the design of anodes for lithium-ion batteries, electrochemical capacitors, and their hybrid devices based on carbonaceous materials are reviewed. Challenges and future perspectives are further discussed. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Evaluation of Polymer Hermetically Sealed Tantalum Capacitors

Science.gov (United States)

Teverovsky, Alexander A.

2014-01-01

Polymer cathode tantalum capacitors have lower ESR (equivalent series resistance) compared to other types of tantalum capacitors and for this reason have gained popularity in the electronics design community. Their use allows improved performance of power supply systems along with substantial reduction of size and weight of the components used. However, these parts have poor thermal stability and can degrade in humid environments. Polymer hermetically sealed (PHS) capacitors avoid problems related to environmental degradation of molded case parts and can potentially replace current wet and solid hermetically sealed capacitors. In this work, PHS capacitors manufactured per DLA LAM DWG#13030 are evaluated for space applications. Several lots of capacitors manufactured over period from 2010 to 2014 were tested for the consistency of performance, electrical and thermal characteristics, highly accelerated life testing, and robustness under reverse bias and random vibration conditions. Special attention was given to analysis of leakage currents and the effect of long-term high temperature storage on capacitors in as is condition and after hermeticity loss. The results show that PHS capacitors might be especially effective for low-temperature applications or for system requiring a cold start-up. Additional screening and qualification testing have been recommended to assure the necessary quality of capacitors for space projects.

High Energy Storage Density and Impedance Response of PLZT2/95/5 Antiferroelectric Ceramics.

Science.gov (United States)

Li, Bi; Liu, Qiuxiang; Tang, Xingui; Zhang, Tianfu; Jiang, Yanping; Li, Wenhua; Luo, Jie

2017-02-08

(Pb 0.97 La 0.02 )(Zr 0.95 Ti 0.05 )O₃ (PLZT2/95/5) ceramics were successfully prepared via a solid-state reaction route. The dielectric properties were investigated in the temperature region of 26-650 °C. The dielectric diffuse anomaly in the dielectric relaxation was found in the high temperature region of 600-650 °C with increasing the measuring frequency, which was related to the dynamic thermal process of ionized oxygen vacancies generated in the high temperature. Two phase transition points were detected during heating, which were found to coexist from 150 to 200 °C. Electric field induced ferroelectric to antiferroelectric phase transition behavior of the (Pb 0.97 La 0.02 )(Zr 0.95 Ti 0.05 )O₃ ceramics was investigated in this work with an emphasis on energy storage properties. A recoverable energy-storage density of 0.83 J/cm³ and efficiency of 70% was obtained in (Pb 0.97 La 0.02 )(Zr 0.95 Ti 0.05 )O₃ ceramics at 55 kV/cm. Based on these results, (Pb 0.97 La 0.02 )(Zr 0.95 Ti 0.05 )O₃ ceramics with a large recoverable energy-storage density could be a potential candidate for the applications in high energy-storage density ceramic capacitors.

High Energy Storage Density and Impedance Response of PLZT2/95/5 Antiferroelectric Ceramics

Directory of Open Access Journals (Sweden)

Bi Li

2017-02-01

Full Text Available (Pb0.97La0.02(Zr0.95Ti0.05O3 (PLZT2/95/5 ceramics were successfully prepared via a solid-state reaction route. The dielectric properties were investigated in the temperature region of 26–650 °C. The dielectric diffuse anomaly in the dielectric relaxation was found in the high temperature region of 600–650 °C with increasing the measuring frequency, which was related to the dynamic thermal process of ionized oxygen vacancies generated in the high temperature. Two phase transition points were detected during heating, which were found to coexist from 150 to 200 °C. Electric field induced ferroelectric to antiferroelectric phase transition behavior of the (Pb0.97La0.02(Zr0.95Ti0.05O3 ceramics was investigated in this work with an emphasis on energy storage properties. A recoverable energy-storage density of 0.83 J/cm3 and efficiency of 70% was obtained in (Pb0.97La0.02(Zr0.95Ti0.05O3 ceramics at 55 kV/cm. Based on these results, (Pb0.97La0.02(Zr0.95Ti0.05O3 ceramics with a large recoverable energy-storage density could be a potential candidate for the applications in high energy-storage density ceramic capacitors.

Design, control and power management of a battery/ultra-capacitor hybrid system for small electric vehicles

DEFF Research Database (Denmark)

Li, Zhihao; Onar, Omer; Khaligh, Alireza

2009-01-01

This paper introduces design, control, and power management of a battery/ultra-capacitor hybrid system, utilized for small electric vehicles (EV). The batteries are designed and controlled to work as the main energy storage source of the vehicle, supplying average power to the load; and the ultra...

Toward Superior Capacitive Energy Storage: Recent Advances in Pore Engineering for Dense Electrodes.

Science.gov (United States)

Liu, Congcong; Yan, Xiaojun; Hu, Fei; Gao, Guohua; Wu, Guangming; Yang, Xiaowei

2018-04-01

With the rapid development of mobile electronics and electric vehicles, future electrochemical capacitors (ECs) need to store as much energy as possible in a rather limited space. As the core component of ECs, dense electrodes that have a high volumetric energy density and superior rate capability are the key to achieving improved energy storage. Here, the significance of and recent progress in the high volumetric performance of dense electrodes are presented. Furthermore, dense yet porous electrodes, as the critical precondition for realizing superior electrochemical capacitive energy, have become a scientific challenge and an attractive research focus. From a pore-engineering perspective, insight into the guidelines of engineering the pore size, connectivity, and wettability is provided to design dense electrodes with different porous architectures toward high-performance capacitive energy storage. The current challenges and future opportunities toward dense electrodes are discussed and include the construction of an orderly porous structure with an appropriate gradient, the coupling of pore sizes with the solvated cations and anions, and the design of coupled pores with diverse electrolyte ions. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Centrifugal Spinning and Its Energy Storage Applications

Science.gov (United States)

Yao, Lu

Lithium-ion batteries (LIBs) and supercapacitors are important electrochemical energy storage systems. LIBs have high specific energy density, long cycle life, good thermal stability, low self-discharge, and no memory effect. However, the low abundance of Li in the Earth's crust and the rising cost of LIBs urge the attempts to develop alternative energy storage systems. Recently, sodium-ion batteries (SIBs) have become an attractive alternative to LIBs due to the high abundance and low cost of Na. Although the specific capacity and energy density of SIBs are not as high as LIBs, SIBs can still be promising power sources for certain applications such as large-scale, stationary grids. Supercapacitors are another important class of energy storage devices. Electric double-layer capacitors (EDLCs) are one important type of supercapacitors and they exhibit high power density, long cycle life, excellent rate capability and environmental friendliness. The potential applications of supercapacitors include memory protection in electronic circuitry, consumer portable electronic devices, and electrical hybrid vehicles. The electrochemical performance of SIBs and EDLCs is largely dependent on the electrode materials. Therefore, development of superior electrodes is the key to achieve highperformance alternative energy storage systems. Recently, one-dimensional nano-/micro-fiber based electrodes have become promising candidates in energy storage because they possess a variety of desirable properties including large specific surface area, well-guided ionic/electronic transport, and good electrode-electrolyte contact, which contribute to enhanced electrochemical performance. Currently, most nano-/micro-fiber based electrodes are prepared via electrospinning method. However, the low production rate of this approach hinders its practical application in the production of fibrous electrodes. Thus, it is significantly important to employ a rapid, low-cost and scalable nano

Synthesis and characterization of nanostructured transition metal oxides for energy storage devices

Science.gov (United States)

Kim, Jong Woung

Finding a promising material and constructing a new method to have both high energy and power are key issues for future energy storage systems. This dissertation addresses three different materials systems to resolve those issues. Pseudocapacitive materials such as RuO2 and MnO2 display high capacitance but Nb2O5, displays a different charge storage mechanism, one highly dependent on its crystal phase rather than its surface area. Various sol-gel techniques were used to synthesize the different phases of Nb2O5 and electrochemical testing was used to study their charge storage with some phases displaying comparable charge storage to MnO2. To overcome the electrical limitations of using an insulating material, the core-shell structure (Nb2O 5/C) was also examined and the method could be generalized to improve other pseudocapacitors. Besides electronic conductivity, the diffusion of the electrolyte ions through the shell material is a critical factor for fast charging/discharging in the core-shell structure. This dissertation also involves another topic, a reconfigurable electrode, that displays both high energy and power density. By constructing a reconfigurable electrode which has different electrical properties (metallic or insulating state) depending on the amount of intercalated `guest' ions into `host' material, it can be used as a battery or electrochemical capacitor material in the insulating or metallic state respectively. Metal oxide bronzes having metal-insulator transition were investigated in this study.

Nanostructured core-shell electrode materials for electrochemical capacitors

Science.gov (United States)

Jiang, Long-bo; Yuan, Xing-zhong; Liang, Jie; Zhang, Jin; Wang, Hou; Zeng, Guang-ming

2016-11-01

Core-shell nanostructure represents a unique system for applications in electrochemical energy storage devices. Owing to the unique characteristics featuring high power delivery and long-term cycling stability, electrochemical capacitors (ECs) have emerged as one of the most attractive electrochemical storage systems since they can complement or even replace batteries in the energy storage field, especially when high power delivery or uptake is needed. This review aims to summarize recent progress on core-shell nanostructures for advanced supercapacitor applications in view of their hierarchical architecture which not only create the desired hierarchical porous channels, but also possess higher electrical conductivity and better structural mechanical stability. The core-shell nanostructures include carbon/carbon, carbon/metal oxide, carbon/conducting polymer, metal oxide/metal oxide, metal oxide/conducting polymer, conducting polymer/conducting polymer, and even more complex ternary core-shell nanoparticles. The preparation strategies, electrochemical performances, and structural stabilities of core-shell materials for ECs are summarized. The relationship between core-shell nanostructure and electrochemical performance is discussed in detail. In addition, the challenges and new trends in core-shell nanomaterials development have also been proposed.

A High-Performance Lithium-Ion Capacitor Based on 2D Nanosheet Materials.

Science.gov (United States)

Li, Shaohui; Chen, Jingwei; Cui, Mengqi; Cai, Guofa; Wang, Jiangxin; Cui, Peng; Gong, Xuefei; Lee, Pooi See

2017-02-01

Lithium-ion capacitors (LICs) are promising electrical energy storage systems for mid-to-large-scale applications due to the high energy and large power output without sacrificing long cycle stability. However, due to the different energy storage mechanisms between anode and cathode, the energy densities of LICs often degrade noticeably at high power density, because of the sluggish kinetics limitation at the battery-type anode side. Herein, a high-performance LIC by well-defined ZnMn 2 O 4 -graphene hybrid nanosheets anode and N-doped carbon nanosheets cathode is presented. The 2D nanomaterials offer high specific surface areas in favor of a fast ion transport and storage with shortened ion diffusion length, enabling fast charge and discharge. The fabricated LIC delivers a high specific energy of 202.8 Wh kg -1 at specific power of 180 W kg -1 , and the specific energy remains 98 Wh kg -1 even when the specific power achieves as high as 21 kW kg -1 . © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Design of an hybrid source with fuel cell and super-capacitors; Conception d'une source hybride utilisant une pile a combustible et des supercondensateurs

Energy Technology Data Exchange (ETDEWEB)

Thounthong, Ph

2005-12-15

The design and testing of a purely super-capacitor energy storage device as auxiliary power source in electrical vehicle applications having a PEM fuel cell as main source are presented. The two control strategies are explained. The control algorithms are that fuel cell is simply operating in almost steady state conditions in order to lessen the mechanical stresses of fuel cell and to ensure a good synchronization between fuel flow and fuel cell current. Super-capacitors are functioning during absence of energy from fuel cell, transient energy delivery or transient energy recovery. The system utilizes two modules of SAFT super-capacitive storage device. This device is connected to a 42 V DC bus by a 2-quadrant dc/dc converter, and fuel cell is connected to the dc bus by a boost converter. The system structure is realized by analogical current loops and digital control (dSPACE) for voltage loops and estimation algorithms. Experimental results with a 500 W PEM fuel cell point out the slow dynamics naturally of fuel cell because of thermodynamic and mechanical operation, and also substantiate that the super-capacitors can improve dynamics and power conditioning for automotive electrical system. (author)

Energy Storage and Smart Energy Systems

DEFF Research Database (Denmark)

Lund, Henrik; Østergaard, Poul Alberg; Connolly, David

2016-01-01

It is often highlighted how the transition to renewable energy supply calls for significant electricity storage. However, one has to move beyond the electricity-only focus and take a holistic energy system view to identify optimal solutions for integrating renewable energy. In this paper......, an integrated cross-sector approach is used to determine the most efficient and least-cost storage options for the entire renewable energy system concluding that the best storage solutions cannot be found through analyses focusing on the individual sub-sectors. Electricity storage is not the optimum solution...... to integrate large inflows of fluctuating renewable energy, since more efficient and cheaper options can be found by integrating the electricity sector with other parts of the energy system and by this creating a Smart Energy System. Nevertheless, this does not imply that electricity storage should...

Novel electric double-layer capacitor with a coaxial fiber structure.

Science.gov (United States)

Chen, Xuli; Qiu, Longbin; Ren, Jing; Guan, Guozhen; Lin, Huijuan; Zhang, Zhitao; Chen, Peining; Wang, Yonggang; Peng, Huisheng

2013-11-26

A coaxial electric double-layer capacitor fiber is developed from the aligned carbon nanotube fiber and sheet, which functions as two electrodes with a polymer gel sandwiched between them. The unique coaxial structure enables a rapid transportation of ions between the two electrodes with a high electrochemical performance. These energy storage fibers are also flexible and stretchable, and can be woven into and widely used for electronic textiles. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Capacitor charging FET switcher with controller to adjust pulse width

Science.gov (United States)

Mihalka, Alex M.

1986-01-01

A switching power supply includes an FET full bridge, a controller to drive the FETs, a programmable controller to dynamically control final output current by adjusting pulse width, and a variety of protective systems, including an overcurrent latch for current control. Power MOSFETS are switched at a variable frequency from 20-50 kHz to charge a capacitor load from 0 to 6 kV. A ferrite transformer steps up the DC input. The transformer primary is a full bridge configuration with the FET switches and the secondary is fed into a high voltage full wave rectifier whose output is connected directly to the energy storage capacitor. The peak current is held constant by varying the pulse width using predetermined timing resistors and counting pulses. The pulse width is increased as the capacitor charges to maintain peak current. A digital ripple counter counts pulses, and after the desired number is reached, an up-counter is clocked. The up-counter output is decoded to choose among different resistors used to discharge a timing capacitor, thereby determining the pulse width. A current latch shuts down the supply on overcurrent due to either excessive pulse width causing transformer saturation or a major bridge fault, i.e., FET or transformer failure, or failure of the drive circuitry.

Hybrid lithium-ion capacitor with LiFePO4/AC composite cathode - Long term cycle life study, rate effect and charge sharing analysis

Science.gov (United States)

Shellikeri, A.; Yturriaga, S.; Zheng, J. S.; Cao, W.; Hagen, M.; Read, J. A.; Jow, T. R.; Zheng, J. P.

2018-07-01

Energy storage devices, which can combine the advantages of lithium-ion battery with that of electric double layer capacitor, are of prime interest. Recently, composite cathodes, which combine a battery material with capacitor material, have shown promise in enhancing life cycle and energy/power performances. Lithium-ion capacitor (LIC), with unique charge storage mechanism of combining a pre-lithiated battery anode with a capacitor cathode, is one such device which has the potential to synergistically incorporate the composite cathode to enhance capacity and cycle life. We report here a hybrid LIC consisting of a lithium iron phosphate (LiFePO4-LFP)/Activated Carbon composite cathode in combination with a hard carbon anode, by integrating the cycle life and capacity enhancing strategies of a dry method of electrode fabrication, anode pre-lithiation and a 3:1 anode to cathode capacity ratio, demonstrating a long cycle life, while elaborating on the charge sharing between the faradaic and non-faradaic mechanism in the battery and capacitor materials, respectively in the composite cathode. An excellent cell capacity retention of 94% (1000 cycles at 1C) and 92% (100,000 cycles at 60C) were demonstrated, while retaining 78% (over 6000 cycles at 2.7C) and 67% (over 70,000 cycles at 43C) of the LFP capacity in the composite cathode.

Thin Film Energy Storage Device with Spray‐Coated Sliver Paste Current Collector

Directory of Open Access Journals (Sweden)

Seong Man Yoon

2017-12-01

Full Text Available This paper challenges the fabrication of a thin film energy storage device on a flexible polymer substrate specifically by replacing most commonly used metal foil current collectors with coated current collectors. Mass‐manufacturable spray‐coating technology enables the fabrication of two different half‐cell electric double layer capacitors (EDLC with a spray‐coated silver paste current collector and a Ni foil current collector. The larger specific capacitances of the half‐cell EDLC with the spray‐coated silver current collector are obtained as 103.86 F/g and 76.8 F/g for scan rates of 10 mV/s and 500 mV/s, respectively. Further, even though the half‐cell EDLC with the spray‐coated current collector is heavier than that with the Ni foil current collector, smaller Warburg impedance and contact resistance are characterized from Nyquist plots. For the applied voltages ranging from −0.5 V to 0.5 V, the spray‐coated thin film energy storage device exhibits a better performance.

MgO-templated carbon as a negative electrode material for Na-ion capacitors

Science.gov (United States)

Kado, Yuya; Soneda, Yasushi

2016-12-01

In this study, MgO-templated carbon with different pore structures was investigated as a negative electrode material for Na-ion capacitors. With increasing the Brunauer-Emmett-Teller surface area, the irreversible capacity increased, and the coulombic efficiency of the 1st cycle decreased because of the formation of solid electrolyte interface layers. MgO-templated carbon annealed at 1000 °C exhibited the highest capacity and best rate performance, suggesting that an appropriate balance between surface area and crystallinity is imperative for fast Na-ion storage, attributed to the storage mechanism: combination of non-faradaic electric double-layer capacitance and faradaic Na intercalation in the carbon layers. Finally, a Na-ion capacitor cell using MgO-templated carbon and activated carbon as the negative and positive electrodes, respectively, exhibited an energy density at high power density significantly greater than that exhibited by the cell using a commercial hard carbon negative electrode.

Letter of professional groups. Energies and fuel cells; La lettre des Groupe Professionnels, energies et piles a combustible

Energy Technology Data Exchange (ETDEWEB)

Meunier, M. [Supelec, 91 - Gif sur Yvette (France); Serre Combe, P. [CEA Grenoble, 38 (France); Sartorelli, G. [Maxwell Technologie, San Diego, CA (United States); Lafont, G. [PILLER France S.A., 92 - Nanterre (France); Green, A. [SAFT, 93170 Bagnolet (France); Perrin, M. [CEA Cadarache, 13 - Saint Paul lez Durance (France); Fregere, J.P.

2004-07-01

These proceedings of the 'Arts et Metiers' professional groups treats of energy storage solutions for delocalized power generation units. Four types of energy storage systems are presented with their operation principle, advantages and drawbacks: fuel cells and hydrogen, super-capacitors, flywheels, conventional batteries (lithium-ion, lead, redox, nickel-cadmium, zinc-air), and comparison between the different energy storage solutions including compressed air. (J.S.)

High Performance Lithium-Ion Hybrid Capacitors Employing Fe3O4-Graphene Composite Anode and Activated Carbon Cathode.

Science.gov (United States)

Zhang, Shijia; Li, Chen; Zhang, Xiong; Sun, Xianzhong; Wang, Kai; Ma, Yanwei

2017-05-24

Lithium-ion capacitors (LICs) are considered as promising energy storage devices to realize excellent electrochemical performance, with high energy-power output. In this work, we employed a simple method to synthesize a composite electrode material consisting of Fe 3 O 4 nanocrystallites mechanically anchored among the layers of three-dimensional arrays of graphene (Fe 3 O 4 -G), which exhibits several advantages compared with other traditional electrode materials, such as high Li storage capacity (820 mAh g -1 at 0.1 A g -1 ), high electrical conductivity, and improved electrochemical stability. Furthermore, on the basis of the appropriated charge balance between cathode and anode, we successfully fabricated Fe 3 O 4 -G//activated carbon (AC) soft-packaging LICs with a high energy density of 120.0 Wh kg -1 , an outstanding power density of 45.4 kW kg -1 (achieved at 60.5 Wh kg -1 ), and an excellent capacity retention of up to 94.1% after 1000 cycles and 81.4% after 10 000 cycles. The energy density of the Fe 3 O 4 -G//AC hybrid device is comparable with Ni-metal hydride batteries, and its capacitive power capability and cycle life is on par with supercapacitors (SCs). Therefore, this lithium-ion hybrid capacitor is expected to bridge the gap between Li-ion battery and SCs and gain bright prospects in next-generation energy storage fields.

Design of an hybrid source with fuel cell and super-capacitors; Conception d'une source hybride utilisant une pile a combustible et des supercondensateurs

Energy Technology Data Exchange (ETDEWEB)

Thounthong, Ph.

2005-12-15

The design and testing of a purely super-capacitor energy storage device as auxiliary power source in electrical vehicle applications having a PEM fuel cell as main source are presented. The two control strategies are explained. The control algorithms are that fuel cell is simply operating in almost steady state conditions in order to lessen the mechanical stresses of fuel cell and to ensure a good synchronization between fuel flow and fuel cell current. Super-capacitors are functioning during absence of energy from fuel cell, transient energy delivery or transient energy recovery. The system utilizes two modules of SAFT super-capacitive storage device. This device is connected to a 42 V DC bus by a 2-quadrant dc/dc converter, and fuel cell is connected to the dc bus by a boost converter. The system structure is realized by analogical current loops and digital control (dSPACE) for voltage loops and estimation algorithms. Experimental results with a 500 W PEM fuel cell point out the slow dynamics naturally of fuel cell because of thermodynamic and mechanical operation, and also substantiate that the super-capacitors can improve dynamics and power conditioning for automotive electrical system. (author)

Energy Storage and Smart Energy Systems

Directory of Open Access Journals (Sweden)

Poul Alberg Østergaard

2016-12-01

Full Text Available It is often highlighted how the transition to renewable energy supply calls for significant electricity storage. However, one has to move beyond the electricity-only focus and take a holistic energy system view to identify optimal solutions for integrating renewable energy. In this paper, an integrated cross-sector approach is used to determine the most efficient and least-cost storage options for the entire renewable energy system concluding that the best storage solutions cannot be found through analyses focusing on the individual sub-sectors. Electricity storage is not the optimum solution to integrate large inflows of fluctuating renewable energy, since more efficient and cheaper options can be found by integrating the electricity sector with other parts of the energy system and by this creating a Smart Energy System. Nevertheless, this does not imply that electricity storage should be disregarded but that it will be needed for other purposes in the future.

A SVPWM based on fluctuate capacitor voltage in 3L-NPC back-to-back converter applied to wind energy

DEFF Research Database (Denmark)

Chen, Quan; Wang, Qunjing; Chen, Zhe

2014-01-01

Three-level Neutral-point-clamped (3L-NPC) converters are becoming a realistic alternative to the conventional converters in high-power wind-energy applications. But the unbalance in the supported capacitors' voltage of back-to-back 3L-NPC converters, including the dynamics of the capacitors...... between the fluctuate voltage of upper and lower capacitors is extracted. Based on this error factor the duty-time of every active voltage vector is calculated. In order to validate the model and the control strategy proposed in this paper, a 2MW 3L-NPC converter used in wind energy has been simulated....

Some wind-energy storage options

Energy Technology Data Exchange (ETDEWEB)

Eldridge, F R; Ljungstroem, O [ed.

1976-01-01

Systems capable of storing energy generated from the wind can be categorized in terms of electrochemical energy storage systems, thermal energy storage systems, kinetic energy systems, and potential energy systems. Recent surveys of energy storage systems have evaluated some of these available storage technologies in terms of the minimum economic sizes for utility applications, estimated capital costs of these units, expected life, dispersed storage capabilities, and estimated turn-around efficiencies of the units. These are summarized for various types of energy storage options.

Natural sisal fibers derived hierarchical porous activated carbon as capacitive material in lithium ion capacitor

Science.gov (United States)

Yang, Zhewei; Guo, Huajun; Li, Xinhai; Wang, Zhixing; Yan, Zhiliang; Wang, Yansen

2016-10-01

Lithium-ion capacitor (LIC) is a novel advanced electrochemical energy storage (EES) system bridging gap between lithium ion battery (LIB) and electrochemical capacitor (ECC). In this work, we report that sisal fiber activated carbon (SFAC) was synthesized by hydrothermal treatment followed by KOH activation and served as capacitive material in LIC for the first time. Different particle structure, morphology, specific surface area and heteroatoms affected the electrochemical performance of as-prepared materials and corresponding LICs. When the mass ratio of KOH to char precursor was 2, hierarchical porous structured SFAC-2 was prepared and exhibited moderate specific capacitance (103 F g-1 at 0.1 A g-1), superior rate capability and cyclic stability (88% capacity retention after 5000 cycles at 1 A g-1). The corresponding assembled LIC (LIC-SC2) with optimal comprehensive electrochemical performance, displayed the energy density of 83 Wh kg-1, the power density of 5718 W kg-1 and superior cyclic stability (92% energy density retention after 1000 cycles at 0.5 A g-1). It is worthwhile that the source for activated carbon is a natural and renewable one and the synthesis method is eco-friendly, which facilitate that hierarchical porous activated carbon has potential applications in the field of LIC and other energy storage systems.

A mini review of designed mesoporous materials for energy-storage applications: from electric double-layer capacitors to hybrid supercapacitors

Science.gov (United States)

Lim, Eunho; Jo, Changshin; Lee, Jinwoo

2016-04-01

In recent years, porous materials have attracted significant attention in various research fields because of their structural merits. In particular, well-designed mesoporous structures with two- or three-dimensionally interconnected pores have been recognized as electrode materials of particular interest for achieving high-performance electrochemical capacitors (ECs). In this mini review, recent progress in the design of mesoporous electrode materials for ECs, from electric double-layer capacitors (EDLCs) and pseudocapacitors (PCs) to hybrid supercapacitors (HSCs), and research challenges for the development of new mesoporous electrode materials has been discussed.

Thermally tunable VO2-SiO2 nanocomposite thin-film capacitors

Science.gov (United States)

Sun, Yifei; Narayanachari, K. V. L. V.; Wan, Chenghao; Sun, Xing; Wang, Haiyan; Cooley, Kayla A.; Mohney, Suzanne E.; White, Doug; Duwel, Amy; Kats, Mikhail A.; Ramanathan, Shriram

2018-03-01

We present a study of co-sputtered VO2-SiO2 nanocomposite dielectric thin-film media possessing continuous temperature tunability of the dielectric constant. The smooth thermal tunability is a result of the insulator-metal transition in the VO2 inclusions dispersed within an insulating matrix. We present a detailed comparison of the dielectric characteristics of this nanocomposite with those of a VO2 control layer and of VO2/SiO2 laminate multilayers of comparable overall thickness. We demonstrated a nanocomposite capacitor that has a thermal capacitance tunability of ˜60% between 25 °C and 100 °C at 1 MHz, with low leakage current. Such thermally tunable capacitors could find potential use in applications such as sensing, thermal cloaks, and phase-change energy storage devices.

Advanced materials for energy storage.

Science.gov (United States)

Liu, Chang; Li, Feng; Ma, Lai-Peng; Cheng, Hui-Ming

2010-02-23

Popularization of portable electronics and electric vehicles worldwide stimulates the development of energy storage devices, such as batteries and supercapacitors, toward higher power density and energy density, which significantly depends upon the advancement of new materials used in these devices. Moreover, energy storage materials play a key role in efficient, clean, and versatile use of energy, and are crucial for the exploitation of renewable energy. Therefore, energy storage materials cover a wide range of materials and have been receiving intensive attention from research and development to industrialization. In this Review, firstly a general introduction is given to several typical energy storage systems, including thermal, mechanical, electromagnetic, hydrogen, and electrochemical energy storage. Then the current status of high-performance hydrogen storage materials for on-board applications and electrochemical energy storage materials for lithium-ion batteries and supercapacitors is introduced in detail. The strategies for developing these advanced energy storage materials, including nanostructuring, nano-/microcombination, hybridization, pore-structure control, configuration design, surface modification, and composition optimization, are discussed. Finally, the future trends and prospects in the development of advanced energy storage materials are highlighted.

Silicon-Based Lithium-Ion Capacitor for High Energy and High Power Application

Science.gov (United States)

Wu, James J.; Demattia, Brianne; Loyselle, Patricia; Reid, Concha; Kohout, Lisa

2017-01-01

Si-based Li-ion capacitor has been developed and demonstrated. The results show it is feasible to improve both power density and energy density in this configuration. The applied current density impacts the power and energy density: low current favors energy density while high current favors power density. Active carbon has a better rate capability than Si. Next StepsFuture Directions. Si electrode needs to be further studied and improved. Further optimization of SiAC ratio and evaluation of its impact on energy density and power density.

Contemporary energy storage sources. Energy saving

International Nuclear Information System (INIS)

Manev, Veselin

2011-01-01

The development of renewable energy system for electricity production is impede because of needs to be stabilized with nearly equivalent installed power of energy storage devices. The development of more electrical energy storage facilities will be extremely important for electricity generation in the future. Using hydro pumping, combined with a long life and fast charge/discharge rate, highly efficient contemporary power energy storage as Altairnano lithium ion battery, currently is seems to be the best solution for fast penetration rate of wind and solar energy systems

Sol-gel derived polymer composites for energy storage and conversion

Science.gov (United States)

Han, Kuo

Sol-gel process is a simple chemistry to convert the small precursor molecules into an inorganic polymer, which could be applied to synthesize inorganic materials, modify the interface of materials, bridge the organic and inorganic materials, etc. In this dissertation, novel sol-gel derived composites have been developed for high dielectric breakdown capacitors, low high frequency loss capacitors and flexible piezoelectrics. Numerous efforts have been made in the past decades to improve the energy storage capability of composite materials by incorporating nanometer scale ceramic addictives with high dielectric permittivity into dielectric polymers with high breakdown strength. However, most composites suffer from the low breakdown strength and make the potential gain in energy density small. Here, a new chemical strategy is proposed that, through sol-gel reactions between ceramic precursors and functional groups at the end of the functionalized Poly(vinylidene fluoride -co-chlorotrifluoroethylene) chains, amorphous low permittivity ceramics was in-situ generated in the polymer matrix and cross-linked the polymer chains simultaneously. By carefully tuning precursors, the polymer/precursors feeding ratios, a series of nanocomposites were systematically designed. All the samples are comprehensively characterized and the structure-property correlations are well investigated. The optimal samples exhibit higher breakdown strength than the pristine polymer. The enhanced breakdown strength ascribed to low contrast in permittivity, great dispersion and improved electrical and mechanical properties. This newly developed approach has shown great promise for new composite capacitors. The percolative polymer composites have recently exhibited great potential in energy storage due to their high dielectric permittivities at the neighborhood of the percolation threshold. Yet high energy dissipation and poor voltage endurance of the percolative composites resulted from electrical

Nanostructured oxides for energy storage applications in batteries and supercapacitors

International Nuclear Information System (INIS)

Chandra, A.; Roberts, A. J.; Yee, E. L. H.; Slade, R. C. T.

2009-01-01

Nanostructured materials are extensively investigated for application in energy storage and power generation devices. This paper deals with the synthesis and characterization of nanomaterials based on oxides of vanadium and with their application as electrode materials for energy storage systems viz. supercapacitors. These nano-oxides have been synthesized using a hydrothermal route in the presence of templates: 1-hexadecylamine, Tweens and Brij types. Using templates during synthesis enables tailoring of the particle morphology and physical characteristics of synthesized powders. Broad X-ray diffraction peaks show the formation of nanoparticles, confirmed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) investigations. SEM studies show that a large range of nanostructures such as needles, fibers, particles, etc. can be synthesized. These particles have varying surface areas and electrical conductivity. Enhancement of surface area as much as seven times relative to surface areas of starting parent materials has been observed. These properties make such materials ideal candidates for application as electrode materials in super capacitors. Assembly and characterization of supercapacitors based on electrodes containing these active nano-oxides are discussed. Specific capacitance of >100 F g -1 has been observed. The specific capacitance decreases with cycling: causes of this phenomenon are presented. (authors)

Hierarchically porous Li3VO4/C nanocomposite as an advanced anode material for high-performance lithium-ion capacitors

Science.gov (United States)

Xu, Xuena; Niu, Feier; Zhang, Dapeng; Chu, Chenxiao; Wang, Chunsheng; Yang, Jian; Qian, Yitai

2018-04-01

Lithium-ion capacitors, as a hybrid electrochemical energy storage device, realize high specific energy and power density within one device, thus attracting extensive attention. Here, hierarchically porous Li3VO4/C nanocomposite is prepared by a solvo-thermal reaction, followed with a post-annealing process. This composite has macropores at the center and mesopores in the wall, thus effectively promoting electrolyte penetration and structure stability upon cycling simultaneously. Compared to mesoporous Li3VO4, the enhanced rate capability and specific capacity of hierarchically porous Li3VO4/C indicate the synergistic effect of mesopores and macropores. Inspired by these results, this composite is coupled with mesoporous carbon (CMK-3) for lithium-ion capacitors, generating a specific energy density of 105 Wh kg-1 at a power density of 188 W kg-1. Even if the power density increases to 9.3 kW kg-1, the energy density still remains 62 Wh kg-1. All these results demonstrate the promising potential of hierarchically porous Li3VO4 in lithium ion capacitors.

A 66pW Discontinuous Switch-Capacitor Energy Harvester for Self-Sustaining Sensor Applications.

Science.gov (United States)

Wu, Xiao; Shi, Yao; Jeloka, Supreet; Yang, Kaiyuan; Lee, Inhee; Sylvester, Dennis; Blaauw, David

2016-06-01

We present a discontinuous harvesting approach for switch capacitor DC-DC converters that enables ultra-low power energy harvesting. By slowly accumulating charge on an input capacitor and then transferring it to a battery in burst-mode, switching and leakage losses in the DC-DC converter can be optimally traded-off with the loss due to non-ideal MPPT operation. The harvester uses a 15pW mode controller, an automatic conversion ratio modulator, and a moving sum charge pump for low startup energy upon a mode switch. In 180nm CMOS, the harvester achieves >40% end-to-end efficiency from 113pW to 1.5μW with 66pW minimum input power, marking a >10× improvement over prior ultra-low power harvesters.

Advanced materials for energy storage

Energy Technology Data Exchange (ETDEWEB)

Liu, Chang; Li, Feng; Ma, Lai-Peng; Cheng, Hui-Ming [Shenyang National Laboratory for Materials Science Institute of Metal Research, Chinese Academy of Sciences 72 Wenhua Road, Shenyang 110016 (China)

2010-02-23

Popularization of portable electronics and electric vehicles worldwide stimulates the development of energy storage devices, such as batteries and supercapacitors, toward higher power density and energy density, which significantly depends upon the advancement of new materials used in these devices. Moreover, energy storage materials play a key role in efficient, clean, and versatile use of energy, and are crucial for the exploitation of renewable energy. Therefore, energy storage materials cover a wide range of materials and have been receiving intensive attention from research and development to industrialization. In this review, firstly a general introduction is given to several typical energy storage systems, including thermal, mechanical, electromagnetic, hydrogen, and electrochemical energy storage. Then the current status of high-performance hydrogen storage materials for on-board applications and electrochemical energy storage materials for lithium-ion batteries and supercapacitors is introduced in detail. The strategies for developing these advanced energy storage materials, including nanostructuring, nano-/microcombination, hybridization, pore-structure control, configuration design, surface modification, and composition optimization, are discussed. Finally, the future trends and prospects in the development of advanced energy storage materials are highlighted. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

The SERI solar energy storage program

Science.gov (United States)

Copeland, R. J.; Wright, J. D.; Wyman, C. E.

1980-01-01

In support of the DOE thermal and chemical energy storage program, the solar energy storage program (SERI) provides research on advanced technologies, systems analyses, and assessments of thermal energy storage for solar applications in support of the Thermal and Chemical Energy Storage Program of the DOE Division of Energy Storage Systems. Currently, research is in progress on direct contact latent heat storage and thermochemical energy storage and transport. Systems analyses are being performed of thermal energy storage for solar thermal applications, and surveys and assessments are being prepared of thermal energy storage in solar applications. A ranking methodology for comparing thermal storage systems (performance and cost) is presented. Research in latent heat storage and thermochemical storage and transport is reported.

Mixed bi-material electrodes based on LiMn2O4 and activated carbon for hybrid electrochemical energy storage devices

International Nuclear Information System (INIS)

Cericola, Dario; Novak, Petr; Wokaun, Alexander; Koetz, Ruediger

2011-01-01

Highlights: → Bi-material electrodes for electrochemical hybrid devices were characterized. → Bi-material electrodes have higher specific charge than capacitor electrodes. → Bi-material electrodes have better rate capability than battery electrodes. → Bi-material systems outperform batteries and capacitors in pulsed applications. - Abstract: The performance of mixed bi-material electrodes composed of the battery material, LiMn 2 O 4 , and the electrochemical capacitor material, activated carbon, for hybrid electrochemical energy storage devices is investigated by galvanostatic charge/discharge and pulsed discharge experiments. Both, a high and a low conductivity lithium-containing electrolyte are used. The specific charge of the bi-material electrode is the linear combination of the specific charges of LiMn 2 O 4 and activated carbon according to the electrode composition at low discharge rates. Thus, the specific charge of the bi-material electrode falls between the specific charge of the activated carbon electrode and the LiMn 2 O 4 battery electrode. The bi-material electrodes have better rate capability than the LiMn 2 O 4 battery electrode. For high current pulsed applications the bi-material electrodes typically outperform both the battery and the capacitor electrode.

Floating body cell a novel capacitor-less DRAM cell

CERN Document Server

Ohsawa, Takashi

2011-01-01

DRAM together with NAND Flash is driving semiconductor technologies with wide spectrum of usage ranging from PC, mobile phone and digital home appliances to solid-state disk (SSD). However, the DRAM cell which consists of a data storage capacitor (1C) and a switching transistor (1T) is facing serious difficulty in shrinking the size of the capacitor whose capacitance needs to be kept almost constant (20~30fF) throughout generations. The availability of a new DRAM cell which does not rely on an explicit capacitor for storing its data is more than ever awaited for further increasing the bit dens

Dielectric and Energy Storage Properties of Ba0.65Sr0.35TiO3 Ceramics Modified by BiNbO4

Science.gov (United States)

Zheng, Yi; Zhang, Jihua; Wei, Meng; Dong, Xiangxiang; Huang, Jiapeng; Wu, Kaituo; Chen, Hongwei

2018-02-01

(1 - x) (Ba0.65Sr0.35TiO3)-xBiNbO4 (x = 0.0-0.15) ceramic were prepared by solid-state reaction method. The phase composition, microstructure, dielectric properties, polarization-electric field, breakdown strength and energy storage behaviors for the BiNbO4-modified Ba0.65Sr0.35TiO3 ceramics were investigated. With the addition of BiNbO4, the remnant polarization and saturation polarization decreased and the nonlinearity was suppressed. When x = 0.07, the maximum recoverable energy storage achieved was 0.5 J/cm3, 1.5 times that of un-doped Ba0.65Sr0.35TiO3 ceramics, with an efficiency of 96.89% and a breakdown electric field reaching 15.3 kV/mm. Therefore, BiNbO4 doping could improve the energy storage properties of Ba0.65Sr0.35TiO3 for high-energy pulse capacitor application.

An overview of carbon materials for flexible electrochemical capacitors.

Science.gov (United States)

He, Yongmin; Chen, Wanjun; Gao, Caitian; Zhou, Jinyuan; Li, Xiaodong; Xie, Erqing

2013-10-07

Under the background of the quick development of lightweight, flexible, and wearable electronic devices in our society, a flexible and highly efficient energy management strategy is needed for their counterpart energy-storage systems. Among them, flexible electrochemical capacitors (ECs) have been considered as one of the most promising candidates because of their significant advantages in power and energy densities, and unique properties of being flexible, lightweight, low-cost, and environmentally friendly compared with current energy storage devices. In a common EC, carbon materials play an irreplaceable and principal role in its energy-storage performance. Up till now, most progress towards flexible ECs technologies has mostly benefited from the continuous development of carbon materials. As a result, in view of the dual remarkable highlights of ECs and carbon materials, a summary of recent research progress on carbon-based flexible EC electrode materials is presented in this review, including carbon fiber (CF, consisting of carbon microfiber-CMF and carbon nanofiber-CNF) networks, carbon nanotube (CNT) and graphene coatings, CNT and/or graphene papers (or films), and freestanding three-dimensional (3D) flexible carbon-based macroscopic architectures. Furthermore, some promising carbon materials for great potential applications in flexible ECs are introduced. Finally, the trends and challenges in the development of carbon-based electrode materials for flexible ECs and their smart applications are analyzed.

The two-capacitor problem revisited: a mechanical harmonic oscillator model approach

International Nuclear Information System (INIS)

Lee, Keeyung

2009-01-01

The well-known two-capacitor problem, in which exactly half the stored energy disappears when a charged capacitor is connected to an identical capacitor, is discussed based on the mechanical harmonic oscillator model approach. In the mechanical harmonic oscillator model, it is shown first that exactly half the work done by a constant applied force is dissipated irrespective of the form of dissipation mechanism when the system comes to a new equilibrium after a constant force is abruptly applied. This model is then applied to the energy loss mechanism in the capacitor charging problem or the two-capacitor problem. This approach allows a simple explanation of the energy dissipation mechanism in these problems and shows that the dissipated energy should always be exactly half the supplied energy whether that is caused by the Joule heat or by the radiation. This paper, which provides a simple treatment of the energy dissipation mechanism in the two-capacitor problem, is suitable for all undergraduate levels

High Energy Density Capacitors, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — Capacitor size and reliability are often limiting factors in pulse power, high speed switching, and power management and distribution (PMAD) systems. T/J...

Treated Carbon Nanofibers for Storing Energy in Aqueous KOH

Science.gov (United States)

Firsich, David W.

2004-01-01

A surface treatment has been found to enhance the performances of carbon nanofibers as electrode materials for electrochemical capacitors in which aqueous solutions of potassium hydroxide are used as the electrolytes. In the treatment, sulfonic acid groups are attached to edge plane sites on carbon atoms. The treatment is applicable to a variety of carbon nanofibers, including fibrils and both single- and multiple-wall nanotubes. The reason for choosing nanofibers over powders and other forms of carbon is that nanofibers offer greater power features. In previous research, it was found that the surface treatment of carbon nanofibers increased energy-storage densities in the presence of acid electrolytes. Now, it has been found that the same treatment increases energy-storage densities of carbon nanofibers in the presence of alkaline electrolytes when the carbon is paired with a NiOOH electrode. This beneficial effect varies depending on the variety of carbon substrate to which it is applied. It has been conjectured that the sulfonic acid groups, which exist in a deprotonated state in aqueous KOH solutions, undergo reversible electro-chemical reactions that are responsible for the observed increases in energystorage capacities. The increases can be considerable: For example, in one case, nanofibers exhibited a specific capacitance of 34 Farads per gram before treatment and 172 Farads per gram (an increase of about 400 percent) after treatment. The most promising application of this development appears to lie in hybrid capacitors, which are devices designed primarily for storing energy. These devices are designed to be capable of (1) discharge at rates greater than those of batteries and (2) storing energy at densities approaching those of batteries. A hybrid capacitor includes one electrode like that of a battery and one electrode like that of an electrochemical capacitor. For example, a hybrid capacitor could contain a potassium hydroxide solution as the electrolyte

ERDA's Chemical Energy Storage Program

Science.gov (United States)

Swisher, J. H.; Kelley, J. H.

1977-01-01

The Chemical Energy Storage Program is described with emphasis on hydrogen storage. Storage techniques considered include pressurized hydrogen gas storage, cryogenic liquid hydrogen storage, storage in hydride compounds, and aromatic-alicyclic hydrogen storage. Some uses of energy storage are suggested. Information on hydrogen production and hydrogen use is also presented. Applications of hydrogen energy systems include storage of hydrogen for utilities load leveling, industrial marketing of hydrogen both as a chemical and as a fuel, natural gas supplementation, vehicular applications, and direct substitution for natural gas.

Elaboration of a microstructured inkjet-printed carbon electrochemical capacitor

Energy Technology Data Exchange (ETDEWEB)

Pech, David; Brunet, Magali; Fabre, Norbert; Mesnilgrente, Fabien; Conedera, Veronique; Durou, Hugo [LAAS-CNRS, Universite de Toulouse, 7 av. du Colonel Roche, F-31077 Toulouse (France); Taberna, Pierre-Louis; Simon, Patrice [CIRIMAT-CNRS, Universite de Toulouse, 118 route de Narbonne, F-31062 Toulouse (France)

2010-02-15

Carbon-based micro-supercapacitors dedicated to energy storage in self-powered modules were fabricated with inkjet printing technology on silicon substrate. An ink was first prepared by mixing an activated carbon powder with a PTFE polymer binder in ethylene glycol stabilized with a surfactant then deposited by inkjet on patterned gold current collectors with the substrate heated at 140 C in order to assure a good homogeneity. Electrochemical micro-capacitors with electrodes in an interdigital configuration were fabricated, and characterized using electrochemical techniques in 1 M Et{sub 4}NBF{sub 4} propylene carbonate electrolyte. These micro-devices show an excellent capacitive behavior over a wide potential range of 2.5 V for a cell capacitance of 2.1 mF cm{sup -2}. The newly developed technology will allow the integration of the storage device as close as possible to the MEMS-based energy harvesting device, minimizing power losses through connections. (author)

Marker Pen Lithography for Flexible and Curvilinear On-Chip Energy Storage

KAUST Repository

Jiang, Qiu

2015-07-14

On-chip energy storage using microsupercapacitors can serve the dual role of supplementing batteries for pulse power delivery, and replacement of bulky electrolytic capacitors in ac-line filtering applications. Despite complexity and processing costs, microfabrication techniques are being employed in fabricating a great variety of microsupercapacitor devices. Here, a simple, cost-effective, and versatile strategy is proposed to fabricate flexible and curvilinear microsupercapacitors (MSCs). The protocol involves writing sacrificial ink patterns using commercial marker pens on rigid, flexible, and curvilinear substrates. It is shown that this process can be used in both lift-off and etching modes, and the possibility of multistack design of active materials using simple pen lithography is demonstrated. As a prototype, this method is used to produce conducting polymer MSCs involving both poly(3,4-ethylenedioxythiophene), polyaniline, and metal oxide (MnO2) electrode materials. Typical values of energy density in the range of 5-11 mWh cm-3 at power densities of 1-6 W cm-3 are achieved, which is comparable to thin film batteries and superior to the carbon and metal oxide based microsupercapacitors reported in the literature. The simplicity and broad scope of this innovative strategy can open up new avenues for easy and scalable fabrication of a wide variety of on-chip energy storage devices. © 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.

Marker Pen Lithography for Flexible and Curvilinear On-Chip Energy Storage

KAUST Repository

Jiang, Qiu; Kurra, Narendra; Alshareef, Husam N.

2015-01-01

On-chip energy storage using microsupercapacitors can serve the dual role of supplementing batteries for pulse power delivery, and replacement of bulky electrolytic capacitors in ac-line filtering applications. Despite complexity and processing costs, microfabrication techniques are being employed in fabricating a great variety of microsupercapacitor devices. Here, a simple, cost-effective, and versatile strategy is proposed to fabricate flexible and curvilinear microsupercapacitors (MSCs). The protocol involves writing sacrificial ink patterns using commercial marker pens on rigid, flexible, and curvilinear substrates. It is shown that this process can be used in both lift-off and etching modes, and the possibility of multistack design of active materials using simple pen lithography is demonstrated. As a prototype, this method is used to produce conducting polymer MSCs involving both poly(3,4-ethylenedioxythiophene), polyaniline, and metal oxide (MnO2) electrode materials. Typical values of energy density in the range of 5-11 mWh cm-3 at power densities of 1-6 W cm-3 are achieved, which is comparable to thin film batteries and superior to the carbon and metal oxide based microsupercapacitors reported in the literature. The simplicity and broad scope of this innovative strategy can open up new avenues for easy and scalable fabrication of a wide variety of on-chip energy storage devices. © 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.

Technology Roadmap: Energy Storage

Energy Technology Data Exchange (ETDEWEB)

NONE

2014-03-01

Energy storage technologies are valuable components in most energy systems and could be an important tool in achieving a low-carbon future. These technologies allow for the decoupling of energy supply and demand, in essence providing a valuable resource to system operators. There are many cases where energy storage deployment is competitive or near-competitive in today's energy system. However, regulatory and market conditions are frequently ill-equipped to compensate storage for the suite of services that it can provide. Furthermore, some technologies are still too expensive relative to other competing technologies (e.g. flexible generation and new transmission lines in electricity systems). One of the key goals of this new roadmap is to understand and communicate the value of energy storage to energy system stakeholders. This will include concepts that address the current status of deployment and predicted evolution in the context of current and future energy system needs by using a ''systems perspective'' rather than looking at storage technologies in isolation.

Negative capacitance in a ferroelectric capacitor.

Science.gov (United States)

Khan, Asif Islam; Chatterjee, Korok; Wang, Brian; Drapcho, Steven; You, Long; Serrao, Claudy; Bakaul, Saidur Rahman; Ramesh, Ramamoorthy; Salahuddin, Sayeef

2015-02-01

The Boltzmann distribution of electrons poses a fundamental barrier to lowering energy dissipation in conventional electronics, often termed as Boltzmann Tyranny. Negative capacitance in ferroelectric materials, which stems from the stored energy of a phase transition, could provide a solution, but a direct measurement of negative capacitance has so far been elusive. Here, we report the observation of negative capacitance in a thin, epitaxial ferroelectric film. When a voltage pulse is applied, the voltage across the ferroelectric capacitor is found to be decreasing with time--in exactly the opposite direction to which voltage for a regular capacitor should change. Analysis of this 'inductance'-like behaviour from a capacitor presents an unprecedented insight into the intrinsic energy profile of the ferroelectric material and could pave the way for completely new applications.

Static and Dynamic Stability Analysis of Distributed Energy Resources Components with Storage Devices and Loads for Smart Grids

DEFF Research Database (Denmark)

Mihet-Popa, Lucian; Groza, V.

2011-01-01

of the Smart Grids (SGs). A SG can operate interconnected to the main distribution grid or in islanded mode. This paper presents experimental tests for static and dynamic stability analysis carried out in a dedicated laboratory for research in distributed control and smart grid with a high share of renewable......The distributed energy resources (DER) contains several technologies, such as diesel engines, small wind turbines, photovoltaic inverters, etc. The control of DER components with storage devices and (controllable) loads, such as batteries, capacitors, dump loads, are central to the concept...... energy production. Moreover to point out, on a laboratory scale, the coupling between DR and storage and to effectively compensate wind fluctuations a number of tests have been done. In order to find out the parameters of various types of DER components for dynamic simulation models a number of tests...

A Quasi-Solid-State Sodium-Ion Capacitor with High Energy Density.

Science.gov (United States)

Wang, Faxing; Wang, Xiaowei; Chang, Zheng; Wu, Xiongwei; Liu, Xiang; Fu, Lijun; Zhu, Yusong; Wu, Yuping; Huang, Wei

2015-11-18

A quasi-solid-state sodium-ion capacitor is demonstrated with nanoporous disordered carbon and macroporous graphene as the negative and positive electrodes, respectively, using a sodium-ion-conducting gel polymer electrolyte. It can operate at a cell voltage as high as 4.2 V with an energy density of record high 168 W h kg(-1). © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

The flywheel as an energy storage device in railway and tram networks; Schwungrad als Energiespeicher in Bahnnetzen. Erfahrungen aus einem Versuchsprojekt in der Stadt Zuerich

Energy Technology Data Exchange (ETDEWEB)

Bischof, M. [EWZ, Zuerich (Switzerland)

2010-07-01

This article reviews experience made with a flywheel-based energy storage system that was tested on part of Zurich's tram network. The aim of the six weeks of tests was to determine how much energy that is generated by the recuperation of braking energy can be temporarily stored to provide power for accelerating trams on the network. The article discusses the valuable knowledge gained during the tests. The basic ideas behind the tests and the goals aimed for are discussed, both concerning energy balances as well as other factors such as noise and electromagnetic emissions. The part of the tram line used for the tests is described and the results are discussed. Other power storage systems using flywheels and capacitors are reviewed.

Energy transfer from a superconducting magnet to an inductive load

International Nuclear Information System (INIS)

Onishi, Toshitada; Miura, Akinori.

1977-01-01

Experiments on energy transfer between two superconducting magnets have been carried out using an inductive energy transfer system similar to the flying capacitor system developed at the Karlsruhe Institute. In the present system the capacitor is grounded and diodes are used instead of thyristors, and a fraction of stored energy is transferred to the capacitor only when the relay connected in parallel to the magnet is switched off. The capacitor is expected to have no constraint in size, while in the flying capacitor system the capacitor is required to exceed a threshold size. Consequently it is possible to shorten the transfer time to some extent in comparison with the one in the flying capacitor system. Transfer experiments have been carried out using a storage magnet with inductance of 1.2H and a load of 0.41H. The capacitance is 200μF. It is possible to transfer 80.1% of the stored energy of 221 J into the load in less than about 0.35 seconds. (auth.)

Capacitors.

Science.gov (United States)

Trotter, Donald M., Jr.

1988-01-01

Presents a historical backdrop for a discussion of capacitor design and function. Discusses the production, importance, and function of two types of miniature capacitors; electrolytic and multilayer ceramic capacitors. Describes the function of these miniature capacitors in comparison to the Leyden jar, a basic demonstration of capacitance. (CW)

Superconducting magnetic energy storage

International Nuclear Information System (INIS)

Rogers, J.D.; Boenig, H.J.

1978-01-01

Superconducting inductors provide a compact and efficient means of storing electrical energy without an intermediate conversion process. Energy storage inductors are under development for diurnal load leveling and transmission line stabilization in electric utility systems and for driving magnetic confinement and plasma heating coils in fusion energy systems. Fluctuating electric power demands force the electric utility industry to have more installed generating capacity than the average load requires. Energy storage can increase the utilization of base-load fossil and nuclear power plants for electric utilities. Superconducting magnetic energy storage (SMES) systems, which will store and deliver electrical energy for load leveling, peak shaving, and the stabilization of electric utility networks are being developed. In the fusion area, inductive energy transfer and storage is also being developed by LASL. Both 1-ms fast-discharge theta-pinch and 1-to-2-s slow tokamak energy transfer systems have been demonstrated. The major components and the method of operation of an SMES unit are described, and potential applications of different size SMES systems in electric power grids are presented. Results are given for a 1-GWh reference design load-leveling unit, for a 30-MJ coil proposed stabilization unit, and for tests with a small-scale, 100-kJ magnetic energy storage system. The results of the fusion energy storage and transfer tests are also presented. The common technology base for the systems is discussed

Energy storage. A challenge for energy transition

International Nuclear Information System (INIS)

Bart, Jean-Baptiste; Nekrasov, Andre; Pastor, Emmanuel; Benefice, Emmanuel; Brincourt, Thierry; Brisse, Annabelle; Cagnac, Albannie; Delille, Gauthier; Hinchliffe, Timothee; Lancel, Gilles; Jeandel, Elodie; Lefebvre, Thierry; Loevenbruck, Philippe; Penneau, Jean-Francois; Soler, Robert; Stevens, Philippe; Radvanyi, Etienne; Torcheux, Laurent

2017-06-01

Written by several EDF R and D engineers, this book aims at presenting an overview of knowledge and know-how of EDF R and D in the field of energy storage, and at presenting the different technologies and their application to electric power systems. After a description of the context related to a necessary energy transition, the authors present the numerous storage technologies. They distinguish direct storage of power (pumped storage water stations, compressed air energy storage, flywheels, the various electrochemical batteries, metal-air batteries, redox flow batteries, superconductors), thermal storage (power to heat, heat to power) and hydrogen storage (storage under different forms), and propose an overview of the situation of standardisation of storage technologies. In the next part, they give an overview of the main services provided by storage to the electric power system: production optimisation, frequency adjustment, grid constraint resolution, local smoothing of PV and wind production, supply continuity. The last part discusses perspectives regarding the role of tomorrow's storage in the field of electrical mobility, for emerging markets, and with respect to different scenarios

A high energy density relaxor antiferroelectric pulsed capacitor dielectric

Energy Technology Data Exchange (ETDEWEB)

Jo, Hwan Ryul; Lynch, Christopher S. [Department of Mechanical and Aerospace Engineering, University of California, Los Angeles (UCLA), Los Angeles, California 90095 (United States)

2016-01-14

Pulsed capacitors require high energy density and low loss, properties that can be realized through selection of composition. Ceramic (Pb{sub 0.88}La{sub 0.08})(Zr{sub 0.91}Ti{sub 0.09})O{sub 3} was found to be an ideal candidate. La{sup 3+} doping and excess PbO were used to produce relaxor antiferroelectric behavior with slim and slanted hysteresis loops to reduce the dielectric hysteresis loss, to increase the dielectric strength, and to increase the discharge energy density. The discharge energy density of this composition was found to be 3.04 J/cm{sup 3} with applied electric field of 170 kV/cm, and the energy efficiency, defined as the ratio of the discharge energy density to the charging energy density, was 0.920. This high efficiency reduces the heat generated under cyclic loading and improves the reliability. The properties were observed to degrade some with temperature increase above 80 °C. Repeated electric field cycles up to 10 000 cycles were applied to the specimen with no observed performance degradation.

The Use of Energy Storage Systems for Supporting the Voltage Needs of Urban and Suburban Railway Contact Lines

Directory of Open Access Journals (Sweden)

Enrico Pagano

2013-03-01

Full Text Available The paper aims to contribute to the use of electric double layer capacitor (EDLC sets for boosting voltages of contact lines in urban and suburban railway traction systems. Different electrical configurations of contact lines are considered and investigated. For each of them, proper mathematical models are suggested to evaluate the electrical performances of the contact lines. They give rise, also, to sample design procedures for the sizing of the most appropriate energy storage systems, to be distributed along the lines, for boosting line voltages and avoiding undesired voltage drops. A numerical example based on the “Cumana” suburban Naples railway network is presented to give an idea of the weights and sizes of electric double layer capacitors needed to boost the voltage of a sample contact line. In particular, three different EDLC systems, for a overall installed energy of 9.6 kWh, have been placed nearby the stations presenting the highest voltage drops during the most representative situation of trains’ service. The new voltage drop is equal to 32% of that obtained in absence of EDLCs.

The Use of Energy Storage Systems for Supporting the Voltage Needs of Urban and Suburban Railway Contact Lines

Energy Technology Data Exchange (ETDEWEB)

Iannuzzi, Diago [University of Federico II, Naples (Italy). Electrical Engineering Department; Pagano, Enrico [University of Federico II, Naples (Italy). Electrical Engineering Department; Tricoli, Pietro [University of Birmingham (United Kingdom). School of Electronic, Electrical and Computer Engineering

2013-04-15

The paper aims to contribute to the use of electric double layer capacitor (EDLC) sets for boosting voltages of contact lines in urban and suburban railway traction systems. Different electrical configurations of contact lines are considered and investigated. For each of them, proper mathematical models are suggested to evaluate the electrical performances of the contact lines. They give rise, also, to sample design procedures for the sizing of the most appropriate energy storage systems, to be distributed along the lines, for boosting line voltages and avoiding undesired voltage drops. A numerical example based on the “Cumana” suburban Naples railway network is presented to give an idea of the weights and sizes of electric double layer capacitors needed to boost the voltage of a sample contact line. In particular, three different EDLC systems, for a overall installed energy of 9.6 kWh, have been placed nearby the stations presenting the highest voltage drops during the most representative situation of trains’ service. The new voltage drop is equal to 32% of that obtained in absence of EDLCs.

Copper vanadate nanowires-based MIS capacitors: Synthesis, characterization, and their electrical charge storage applications

KAUST Repository

Shahid, Muhammad

2013-07-14

Copper vanadate (CVO) nanowires were grown on Si/SiO2 substrates by thermal annealing technique. A thin film of a CVO precursor at 550 C under an ambient atmosphere could also be prepared. The electrical properties of the nanowires embedded in the dielectrical layer were examined by capacitance-voltage (C-V) measurements. The C-V curves for Au/CVO nanowires embedded in an hafnium oxide layer/SiO2/p-Si capacitor at 298 K showed a clockwise hysteresis loop when the gate bias was swept cyclically. The hysteresis characteristics were studied further at different frequencies, which clearly indicated that the traps in the nanowires have a large charging-discharging time and thus the as-synthesized nanowires can be utilized for electrical charge storage devices. © 2013 Springer Science+Business Media Dordrecht.

Copper vanadate nanowires-based MIS capacitors: synthesis, characterization, and their electrical charge storage applications

Energy Technology Data Exchange (ETDEWEB)

Shahid, Muhammad, E-mail: shahid@skku.edu [King Abdullah University of Science and Technology, Material Science and Engineering (Saudi Arabia); Nafady, Ayman [King Saud University, Department of Chemistry, College of Science (Saudi Arabia); Shakir, Imran; Rana, Usman Ali; Sarfraz, Mansoor [King Saud University, Sustainable Energy Technologies (SET) Center, College of Engineering (Saudi Arabia); Warsi, Muhammad Farooq [The Islamia University of Bahawalpur, Department of Chemistry (Pakistan); Hussain, Rafaqat [Universiti Teknologi Malaysia, Ibnu Sina Institute for Fundamental Science Studies (Malaysia); Ashiq, Muhammad Naeem [Bahauddin Zakaryia University, Institute of Chemical Sciences (Pakistan)

2013-08-15

Copper vanadate (CVO) nanowires were grown on Si/SiO{sub 2} substrates by thermal annealing technique. A thin film of a CVO precursor at 550 Degree-Sign C under an ambient atmosphere could also be prepared. The electrical properties of the nanowires embedded in the dielectrical layer were examined by capacitance-voltage (C-V) measurements. The C-V curves for Au/CVO nanowires embedded in an hafnium oxide layer/SiO{sub 2}/p-Si capacitor at 298 K showed a clockwise hysteresis loop when the gate bias was swept cyclically. The hysteresis characteristics were studied further at different frequencies, which clearly indicated that the traps in the nanowires have a large charging-discharging time and thus the as-synthesized nanowires can be utilized for electrical charge storage devices.

Copper vanadate nanowires-based MIS capacitors: Synthesis, characterization, and their electrical charge storage applications

KAUST Repository

Shahid, Muhammad; Nafady, Ayman; Shakir, Imran; Rana, Usman Ali; Sarfraz, Mansoor M.; Warsi, Muhammad Farooq; Hussain, Rafaqat; Ashiq, Muhammad Naeem

2013-01-01

Copper vanadate (CVO) nanowires were grown on Si/SiO2 substrates by thermal annealing technique. A thin film of a CVO precursor at 550 C under an ambient atmosphere could also be prepared. The electrical properties of the nanowires embedded in the dielectrical layer were examined by capacitance-voltage (C-V) measurements. The C-V curves for Au/CVO nanowires embedded in an hafnium oxide layer/SiO2/p-Si capacitor at 298 K showed a clockwise hysteresis loop when the gate bias was swept cyclically. The hysteresis characteristics were studied further at different frequencies, which clearly indicated that the traps in the nanowires have a large charging-discharging time and thus the as-synthesized nanowires can be utilized for electrical charge storage devices. © 2013 Springer Science+Business Media Dordrecht.

Energy storage systems cost update : a study for the DOE Energy Storage Systems Program.

Energy Technology Data Exchange (ETDEWEB)

Schoenung, Susan M. (Longitude 122 West, Menlo Park, CA)

2011-04-01

This paper reports the methodology for calculating present worth of system and operating costs for a number of energy storage technologies for representative electric utility applications. The values are an update from earlier reports, categorized by application use parameters. This work presents an update of energy storage system costs assessed previously and separately by the U.S. Department of Energy (DOE) Energy Storage Systems Program. The primary objective of the series of studies has been to express electricity storage benefits and costs using consistent assumptions, so that helpful benefit/cost comparisons can be made. Costs of energy storage systems depend not only on the type of technology, but also on the planned operation and especially the hours of storage needed. Calculating the present worth of life-cycle costs makes it possible to compare benefit values estimated on the same basis.

A Switched-Capacitor Based High Conversion Ratio Converter for Renewable Energy Applications

DEFF Research Database (Denmark)

Li, Kerui; Yin, Zhijian; Yang, Yongheng

2017-01-01

A high step-up switched-capacitor based converter is proposed in this paper. The proposed converter features high conversion ratio, low voltage stress and continuous input current, which makes it very suitable for renewable energy applications like photovoltaic systems. More importantly...... voltage gain, low voltage stress on the switches, continuous input current, and relatively high efficiency....

Nanostructured Electrode Materials for Electrochemical Capacitor Applications.

Science.gov (United States)

Choi, Hojin; Yoon, Hyeonseok

2015-06-02

The advent of novel organic and inorganic nanomaterials in recent years, particularly nanostructured carbons, conducting polymers, and metal oxides, has enabled the fabrication of various energy devices with enhanced performance. In this paper, we review in detail different nanomaterials used in the fabrication of electrochemical capacitor electrodes and also give a brief overview of electric double-layer capacitors, pseudocapacitors, and hybrid capacitors. From a materials point of view, the latest trends in electrochemical capacitor research are also discussed through extensive analysis of the literature and by highlighting notable research examples (published mostly since 2013). Finally, a perspective on next-generation capacitor technology is also given, including the challenges that lie ahead.

Comparison of three topologies and controls of a hybrid energy storage system for microgrids

International Nuclear Information System (INIS)

Etxeberria, A.; Vechiu, I.; Camblong, H.; Vinassa, J.-M.

2012-01-01

Highlight: ► A microgrid with high penetration of renewable sources is analysed. ► A storage system formed by a supercapacitor and a vanadium redox battery is used. ► Three topologies to connect the storage devices and manage the microgrid are compared. ► Effect of renewable sources and grid disconnection are simulated. ► The feasibility, power losses and THD of each topology are compared. - Abstract: A high penetration rate of the Renewable Energy Sources (RES) can create stability, reliability and power quality problems in the main electrical grid. The microgrid should be a feasible alternative to solve these issues. As it is a weak electrical grid, the microgrid is very sensitive to any variation and consequently an Energy Storage System (ESS) is necessary to reduce their effect. A microgrid needs an ESS with high energy and power densities, but none of the currently available storage technologies satisfies both requirements at the same time. Consequently, it is necessary to associate more than one storage technology creating a Hybrid Energy Storage System (HESS). The objective of this work is to compare by means of simulations three different topologies that are used to control a HESS formed by a SuperCapacitor (SC) bank and a Vanadium Redox Battery (VRB). The compared topologies are the parallel active topology, the floating topology and the Three-Level Neutral Point Clamped (3LNPC) converter topology. The analysed microgrid is formed by the mentioned HESS and different renewable energy sources. This microgrid is interconnected to a weak grid based on a Diesel Generator (DG). Two case studies have been analysed: the effect of the RES while the microgrid is connected to the weak grid and the effect of the disconnection of the microgrid from the weak grid. The different topologies are compared analysing their capability of facing the mentioned variations, their power losses and their Total Harmonic Distortion (THD). The Matlab/Simulink software and the

Direct Mismatch Characterization of femto-Farad Capacitors

KAUST Repository

Omran, Hesham

2015-08-17

Reducing the capacitance of programmable capacitor arrays, commonly used in analog integrated circuits, is necessary for low-energy applications. However, limited mismatch data is available for small capacitors. We report mismatch measurement for a 2fF poly-insulator-poly (PIP) capacitor, which is the smallest reported PIP capacitor to the best of the authors’ knowledge. Instead of using complicated custom onchip circuitry, direct mismatch measurement is demonstrated and verified using Monte Carlo Simulations and experimental measurements. Capacitive test structures composed of 9 bit programmable capacitor arrays (PCAs) are implemented in a low-cost 0:35m CMOS process. Measured data is compared to mismatch of large PIP capacitors, theoretical models, and recently published data. Measurement results indicate an estimated average relative standard deviation of 0.43% for the 2fF unit capacitor, which is better than the reported mismatch of metal-oxide-metal (MOM) fringing capacitors implemented in an advanced 32nm CMOS process.

Direct Mismatch Characterization of femto-Farad Capacitors

KAUST Repository

Omran, Hesham; Elafandy, Rami T.; Arsalan, Muhammad; Salama, Khaled N.

2015-01-01

Reducing the capacitance of programmable capacitor arrays, commonly used in analog integrated circuits, is necessary for low-energy applications. However, limited mismatch data is available for small capacitors. We report mismatch measurement for a 2fF poly-insulator-poly (PIP) capacitor, which is the smallest reported PIP capacitor to the best of the authors’ knowledge. Instead of using complicated custom onchip circuitry, direct mismatch measurement is demonstrated and verified using Monte Carlo Simulations and experimental measurements. Capacitive test structures composed of 9 􀀀 bit programmable capacitor arrays (PCAs) are implemented in a low-cost 0:35m CMOS process. Measured data is compared to mismatch of large PIP capacitors, theoretical models, and recently published data. Measurement results indicate an estimated average relative standard deviation of 0.43% for the 2fF unit capacitor, which is better than the reported mismatch of metal-oxide-metal (MOM) fringing capacitors implemented in an advanced 32nm CMOS process.

Energy storage connection system

Science.gov (United States)

Benedict, Eric L.; Borland, Nicholas P.; Dale, Magdelena; Freeman, Belvin; Kite, Kim A.; Petter, Jeffrey K.; Taylor, Brendan F.

2012-07-03

A power system for connecting a variable voltage power source, such as a power controller, with a plurality of energy storage devices, at least two of which have a different initial voltage than the output voltage of the variable voltage power source. The power system includes a controller that increases the output voltage of the variable voltage power source. When such output voltage is substantially equal to the initial voltage of a first one of the energy storage devices, the controller sends a signal that causes a switch to connect the variable voltage power source with the first one of the energy storage devices. The controller then causes the output voltage of the variable voltage power source to continue increasing. When the output voltage is substantially equal to the initial voltage of a second one of the energy storage devices, the controller sends a signal that causes a switch to connect the variable voltage power source with the second one of the energy storage devices.

Comparing energy storage options for renewable energy integration

DEFF Research Database (Denmark)

Østergaard, Poul Alberg

-inclusive 100% renewable energy scenario developed for the Danish city Aalborg based on wind power, bio-resources and low-temperature geothermal heat. The paper investigates the system impact of different types of energy storage systems including district heating storage, biogas storage and electricity storage......Increasing penetrations of fluctuating energy sources for electricity generation, heating, cooling and transportation increase the need for flexibility of the energy system to accommodate the fluctuations of these energy sources. Controlling production, controlling demand and utilizing storage...... options are the three general categories of measures that may be applied for ensuring balance between production and demand, however with fluctuating energy sources, options are limited, and flexible demand has also demonstrated limited perspective. This paper takes its point of departure in an all...

Large-area printed supercapacitor technology for low-cost domestic green energy storage

International Nuclear Information System (INIS)

Tehrani, Z.; Thomas, D.J.; Korochkina, T.; Phillips, C.O.; Lupo, D.; Lehtimäki, S.; O'Mahony, J.; Gethin, D.T.

2017-01-01

In this research we demonstrate that a flexible ultra-thin supercapacitor can be fabricated using high volume screen printing process. This has enabled the sequential deposition of current collector, electrode, electrolyte materials and adhesive onto a Polyethylene terephthalate (PET) substrate in order to form flexible electrodes for reliable energy storage applications. The electrodes were based on an activated carbon ink and gel electrolyte each of which were formulated for this application. Supercapacitors that have surface areas from 100 to 1600 mm"2 and an assembled device thickness of 375 μm were demonstrated. The capacitance ranged from 50 to 400 mF. Capacitance of printed carbon electrodes is rarely reported in literature and no references were found. The chemistry developed during this study displayed long-term cycling potential and demonstrated the stability of the capacitor for continued usage. The gel electrolyte developed within this work showed comparable performance to that of a liquid counterpart. This improvement resulted in the reduction in gel resistance from 90Ω to 0.5Ω. Significant reduction was observed for all resistances. The solid-state supercapacitors with the gel electrolyte showed comparable performance to the supercapacitors that used a liquid electrolyte. This large area printed device can be used in future houses for reliable green energy storage. - Highlights: • It has been demonstrated that a flexible supercapacitors with large area storage has been developed. • The simplified architecture has the potential to lead to a new class of printable, thin storage devices. • The specific capacitance of 21 F/g was measured.

Solar applications analysis for energy storage

Science.gov (United States)

Blanchard, T.

1980-01-01

The role of energy storage as it relates to solar energy systems is considered. Storage technologies to support solar energy applications, the status of storage technologies, requirements and specifications for storage technologies, and the adequacy of the current storage research and development program to meet these requirements are among the factors discussed. Emphasis is placed on identification of where the greatest potential exists for energy storage in support of those solar energy systems which could have a significant impact on the U.S. energy mix.

Frequency Dispersion of the Impedance of Capacitor Structures with Asymmetrically Connected Electrodes

Science.gov (United States)

Emel'yanov, O. A.; Ivanov, I. O.

2018-01-01

A method to estimate the frequency dispersion of the impedance of capacitance structures with asymmetric opposite connection of electrodes is considered. The proposed equations are used to derive exact solutions for spatially nonuniform distributions of potential and current. The solutions are in agreement with the results of the 3D simulation using the COMSOL Multiphysics software. The frequency dispersion of the impedance must be taken into account in the development of modern capacitors needed for construction of efficient energy storages.

Hybrid nanostructured materials for high-performance electrochemical capacitors

KAUST Repository

Yu, Guihua

2013-03-01

The exciting development of advanced nanostructured materials has driven the rapid growth of research in the field of electrochemical energy storage (EES) systems which are critical to a variety of applications ranging from portable consumer electronics, hybrid electric vehicles, to large industrial scale power and energy management. Owing to their capability to deliver high power performance and extremely long cycle life, electrochemical capacitors (ECs), one of the key EES systems, have attracted increasing attention in the recent years since they can complement or even replace batteries in the energy storage field, especially when high power delivery or uptake is needed. This review article describes the most recent progress in the development of nanostructured electrode materials for EC technology, with a particular focus on hybrid nanostructured materials that combine carbon based materials with pseudocapacitive metal oxides or conducting polymers for achieving high-performance ECs. This review starts with an overview of EES technologies and the comparison between various EES systems, followed by a brief description of energy storage mechanisms for different types of EC materials. This review emphasizes the exciting development of both hybrid nanomaterials and novel support structures for effective electrochemical utilization and high mass loading of active electrode materials, both of which have brought the energy density of ECs closer to that of batteries while still maintaining their characteristic high power density. Last, future research directions and the remaining challenges toward the rational design and synthesis of hybrid nanostructured electrode materials for next-generation ECs are discussed. © 2012 Elsevier Ltd.

Research progress about chemical energy storage of solar energy

Science.gov (United States)

Wu, Haifeng; Xie, Gengxin; Jie, Zheng; Hui, Xiong; Yang, Duan; Du, Chaojun

2018-01-01

In recent years, the application of solar energy has been shown obvious advantages. Solar energy is being discontinuity and inhomogeneity, so energy storage technology becomes the key to the popularization and utilization of solar energy. Chemical storage is the most efficient way to store and transport solar energy. In the first and the second section of this paper, we discuss two aspects about the solar energy collector / reactor, and solar energy storage technology by hydrogen production, respectively. The third section describes the basic application of solar energy storage system, and proposes an association system by combining solar energy storage and power equipment. The fourth section briefly describes several research directions which need to be strengthened.

Application of PFN capacitors in high power systems

International Nuclear Information System (INIS)

Parker, R.D.

1979-01-01

The application of lightweight reliable capacitors in a mobile energy store is discussed. The relationship of system design parameters to capacitor size and life is displayed. Electric fields and weights of a 21 J/lb and a 77 J/lb pulse discharge capacitor design are given. Estimates of future near-tern development are made

Mutual capacitor and its applications

Directory of Open Access Journals (Sweden)

Chun Li

2014-06-01

Full Text Available This study presents a new ac circuit element – the mutual capacitor, being a dual of the mutual inductor, which is also a new ac transformer. This element is characteristic of the mutual-capacitance coupling of a multi-capacitance system. A unity-coupled mutual capacitor works as an ideal current or voltage transformer, and incidentally acts as waveform separating when inductor employed or waveform converting from square-wave to quasi-sine or waveform filtering, between ports. As a transformer, the mutual capacitor is easy to design, easy for heat cooling, more accurate for current or voltage transformation, dissipating less energy as well as saving materials, suitable for high-power and high-voltage applications. Experiments to demonstrate performances of unity-coupled mutual capacitors are also given.

Nanostructured Electrode Materials for Electrochemical Capacitor Applications

Directory of Open Access Journals (Sweden)

Hojin Choi

2015-06-01

Full Text Available The advent of novel organic and inorganic nanomaterials in recent years, particularly nanostructured carbons, conducting polymers, and metal oxides, has enabled the fabrication of various energy devices with enhanced performance. In this paper, we review in detail different nanomaterials used in the fabrication of electrochemical capacitor electrodes and also give a brief overview of electric double-layer capacitors, pseudocapacitors, and hybrid capacitors. From a materials point of view, the latest trends in electrochemical capacitor research are also discussed through extensive analysis of the literature and by highlighting notable research examples (published mostly since 2013. Finally, a perspective on next-generation capacitor technology is also given, including the challenges that lie ahead.

DTU international energy report 2013. Energy storage options for future sustainable energy systems

Energy Technology Data Exchange (ETDEWEB)

Hvidtfeldt Larsen, H.; Soenderberg Petersen, L. (eds.)

2013-11-01

One of the great challenges in the transition to a non-fossil energy system with a high share of fluctuating renewable energy sources such as solar and wind is to align consumption and production in an economically satisfactory manner. Energy storage could provide the necessary balancing power to make this possible. This energy report addresses energy storage from a broad perspective: It analyses smaller stores that can be used locally in for example heat storage in the individual home or vehicle, such as electric cars or hydrogen cars. The report also addresses decentralized storage as flywheels and batteries linked to decentralized energy systems. In addition it addresses large central storages as pumped hydro storage and compressed air energy storage and analyse this in connection with international transmission and trading over long distances. The report addresses electrical storage, thermal storage and other forms of energy storage, for example conversion of biomass to liquid fuel and conversion of solar energy directly into hydrogen, as well as storage in transmission, grid storage etc. Finally, the report covers research, innovation and the future prospects and addresses the societal challenges and benefits of the use of energy storage. (Author)

Capacitor energy needed to induce transitions from the superconducting to the normal state

International Nuclear Information System (INIS)

Eberhard, P.H.; Ross, R.R.

1985-08-01

The purpose of this paper is to describe a technique to turn a long length of superconducting wire normal by dumping a charged capacitor into it and justify some formulae needed in the design. The physical phenomenon is described. A formula for the energy to be stored in the capacitor is given. There are circumstances where the dc in an electrical circuit containing superconducting elements has to be turned off quickly and where the most convenient way to switch the current off is to turn a large portion or all of the superconducting wire normal. Such was the case of the Time Projection Chamber (TPC) superconducting magnet as soon as a quench was detected. The technique used was the discharge of a capacitor into the coil center tap. It turned the magnet winding normal in ten milliseconds or so and provided an adequate quench protection. The technique of discharging a capacitor into a superconducting wire should have many other applications whenever a substantial resistance in a superconducting circuit has to be generated in that kind of time scale. The process involves generating a pulse of large currents in some part of the circuit and heating the wire up by ac losses until the value of the wire critical current is smaller than the dc current. Use of low inductance connections to the circuit is necessary. Then the dc gets turned off due to the resistance of the wire as in a magnet quench

A local energy management of a hybrid PV-storage based distributed generation for microgrids

International Nuclear Information System (INIS)

Choudar, Adel; Boukhetala, Djamel; Barkat, Said; Brucker, Jean-Michel

2015-01-01

Highlights: • The proposed system is based on photovoltaic system, batteries and ultra-capacitors. • Batteries are used as an energy source, ultra-capacitors are used as a fast power regulator. • An energy management strategy, to operate a grid connected active PV system (APS). • Different levels of the control system are studied and organized in a hierarchical control structure. • Different operating modes are explained (island, limited PV power, normal, fast recovering). - Abstract: The presented work focuses on energy management strategy, to operate a grid connected active PV system (APS) in a microgrid. A microgrid is a smart grid in a small scale which can be stand-alone or grid-tied. The proposed system is based on photovoltaic system, batteries and ultra-capacitors. Three converters are used to interface the elements of the APS to a common DC-link capacitor. The presented control strategy manages the power flow between the converters and the grid through the DC-link in order to maintain the grid power demand coming from the grid operator. Batteries are used as an energy source, to stabilize and permit the APS units to run at a constant and stable output power, damping peak surges in electricity demand and to store the excess of energy from the PV array. Ultra-capacitors are used as a fast power regulator to: limit the battery’s current, regulate the DC-link voltage when the disconnection mode occurs and to deliver a smooth power to the grid, despite primary source and load fluctuations. Several operating modes are presented to manage locally the power flows between the various sources, taking into account the state of charge of batteries (SOC), the energy level of ultra-capacitors (Lev), the available PV power and the power demand from the grid operator

Multilayer capacitors, method for making multilayer capacitors

Science.gov (United States)

Ma, Beihai; Balachandran, Uthamalingam

2018-03-06

The invention provides a stacked capacitor configuration comprising subunits each with a thickness of as low as 20 microns. Also provided is combination capacitor and printed wire board wherein the capacitor is encapsulated by the wire board. The invented capacitors are applicable in micro-electronic applications and high power applications, whether it is AC to DC or DC to AC, or DC to DC.

Electron Charged Graphite-based Hydrogen Storage Material

Energy Technology Data Exchange (ETDEWEB)

Dr. Chinbay Q. Fan; D Manager

2012-03-14

The electron-charge effects have been demonstrated to enhance hydrogen storage capacity using materials which have inherent hydrogen storage capacities. A charge control agent (CCA) or a charge transfer agent (CTA) was applied to the hydrogen storage material to reduce internal discharge between particles in a Sievert volumetric test device. GTI has tested the device under (1) electrostatic charge mode; (2) ultra-capacitor mode; and (3) metal-hydride mode. GTI has also analyzed the charge distribution on storage materials. The charge control agent and charge transfer agent are needed to prevent internal charge leaks so that the hydrogen atoms can stay on the storage material. GTI has analyzed the hydrogen fueling tank structure, which contains an air or liquid heat exchange framework. The cooling structure is needed for hydrogen fueling/releasing. We found that the cooling structure could be used as electron-charged electrodes, which will exhibit a very uniform charge distribution (because the cooling system needs to remove heat uniformly). Therefore, the electron-charge concept does not have any burden of cost and weight for the hydrogen storage tank system. The energy consumption for the electron-charge enhancement method is quite low or omitted for electrostatic mode and ultra-capacitor mode in comparison of other hydrogen storage methods; however, it could be high for the battery mode.

Super-capacitors fuel-cell hybrid electric vehicle optimization and control strategy development

International Nuclear Information System (INIS)

Paladini, Vanessa; Donateo, Teresa; De Risi, Arturo; Laforgia, Domenico

2007-01-01

In the last decades, due to emissions reduction policies, research focused on alternative powertrains among which hybrid electric vehicles (HEVs) powered by fuel cells are becoming an attractive solution. One of the main issues of these vehicles is the energy management in order to improve the overall fuel economy. The present investigation aims at identifying the best hybrid vehicle configuration and control strategy to reduce fuel consumption. The study focuses on a car powered by a fuel cell and equipped with two secondary energy storage devices: batteries and super-capacitors. To model the powertrain behavior an on purpose simulation program called ECoS has been developed in Matlab/Simulink environment. The fuel cell model is based on the Amphlett theory. The battery and the super-capacitor models account for charge/discharge efficiency. The analyzed powertrain is also equipped with an energy regeneration system to recover braking energy. The numerical optimization of vehicle configuration and control strategy of the hybrid electric vehicle has been carried out with a multi objective genetic algorithm. The goal of the optimization is the reduction of hydrogen consumption while sustaining the battery state of charge. By applying the algorithm to different driving cycles, several optimized configurations have been identified and discussed

Capacitor with a composite carbon foam electrode

Science.gov (United States)

Mayer, Steven T.; Pekala, Richard W.; Kaschmitter, James L.

1999-01-01

Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid partides being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy.

Capacitor Discharge - A Capacitor Tutorial [video

OpenAIRE

Naval Postgraduate School Physics

2014-01-01

NPS Physics Physics Demonstrations Here's a capacitor discharge demonstrated by physicist Dr. Dernardo. Dr. D gives a nice capacitor lesson along with some fireworks. Charging and Discharging a Capacitor is dangerous. Do not try this at home. Dr. Bruce Denardo uses eleven 9V batteries, connected in series for a total of 99 creating a pretty large spark.

Performance analysis of an integrated energy storage and energy upgrade thermochemical solid–gas sorption system for seasonal storage of solar thermal energy

International Nuclear Information System (INIS)

Li, Tingxian; Wang, Ruzhu; Kiplagat, Jeremiah K.; Kang, YongTae

2013-01-01

An innovative dual-mode thermochemical sorption energy storage method is proposed for seasonal storage of solar thermal energy with little heat losses. During the charging phase in summer, solar thermal energy is stored in form of chemical bonds resulting from thermochemical decomposition process, which enables the stored energy to be kept several months at ambient temperature. During the discharging phase in winter, the stored thermal energy is released in the form of chemical reaction heat resulting from thermochemical synthesis process. Thermodynamic analysis showed that the advanced dual-mode thermochemical sorption energy storage is an effective method for the long-term seasonal storage of solar energy. A coefficient of performance (COP h ) of 0.6 and energy density higher than 1000 kJ/kg of salt can be attained from the proposed system. During the discharging phase at low ambient temperatures, the stored thermal energy can be upgraded by use of a solid–gas thermochemical sorption heat transformer cycle. The proposed thermochemical sorption energy storage has distinct advantages over the conventional sensible heat and latent heat storage, such as higher energy storage density, little heat losses, integrated energy storage and energy upgrade, and thus it can contribute to improve the seasonal utilization of solar thermal energy. - Highlights: ► A dual-mode solid thermochemical sorption is proposed for seasonal solar thermal energy storage. ► Energy upgrade techniques into the energy storage system are integrated. ► Performance of the proposed seasonal energy storage system is evaluated. ► Energy density and COP h from the proposed system are as high as 1043 kJ/kg of salt and 0.60, respectively

Distributed energy systems with wind power and energy storage

Energy Technology Data Exchange (ETDEWEB)

Korpaas, Magnus

2004-07-01

The topic of this thesis is the study of energy storage systems operating with wind power plants. The motivation for applying energy storage in this context is that wind power generation is intermittent and generally difficult to predict, and that good wind energy resources are often found in areas with limited grid capacity. Moreover, energy storage in the form of hydrogen makes it possible to provide clean fuel for transportation. The aim of this work has been to evaluate how local energy storage systems should be designed and operated in order to increase the penetration and value of wind power in the power system. Optimization models and sequential and probabilistic simulation models have been developed for this purpose. Chapter 3 presents a sequential simulation model of a general wind hydrogen energy system. Electrolytic hydrogen is used either as a fuel for transportation or for power generation in a stationary fuel cell. The model is useful for evaluating how hydrogen storage can increase the penetration of wind power in areas with limited or no transmission capacity to the main grid. The simulation model is combined with a cost model in order to study how component sizing and choice of operation strategy influence the performance and economics of the wind-hydrogen system. If the stored hydrogen is not used as a separate product, but merely as electrical energy storage, it should be evaluated against other and more energy efficient storage options such as pumped hydro and redox flow cells. A probabilistic model of a grid-connected wind power plant with a general energy storage unit is presented in chapter 4. The energy storage unit is applied for smoothing wind power fluctuations by providing a firm power output to the grid over a specific period. The method described in the chapter is based on the statistical properties of the wind speed and a general representation of the wind energy conversion system and the energy storage unit. This method allows us to

Use of Super-Capacitor to Enhance Charging Performance of Stand-Alone Solar PV System

KAUST Repository

Huang, B. J.

2011-01-01

Introduction: The battery charging performance in a stand-alone solar PV system affects the PV system efficiency and the load operating time. The New Energy Center of National Taiwan University has been devoted to the development of a PWM charging technique to continue charging the lead-acid battery after the overcharge point to increase the battery storage capacity by more than 10%. The present study intends to use the super-capacitor to further increase the charge capacity before the overcharge point of the battery. The super-capacitor is connected in parallel to the lead-acid battery. This will reduce the overall charging impedance during the charge and increase the charging current, especially in sunny weather. A system dynamics model of the lead-acid battery and super-capacitor was derived and the control system simulation was carried out to predict the charging performance for various weathers. It shows that the overall battery impedance decreases and charging power increases with increasing solar radiation. An outdoor comparative test for two identical PV systems with and without supercapacitor was carried out. The use of super-capacitor is shown to be able to increase the lead-acid charging capacity by more than 25% at sunny weather and 10% in cloudy weather. © Springer-Verlag Berlin Heidelberg 2011.

Cellulose Triacetate Dielectric Films For Capacitors

Science.gov (United States)

Yen, Shiao-Ping S.; Jow, T. Richard

1994-01-01

Cellulose triacetate investigated for use as dielectric material in high-energy-density capacitors for pulsed-electrical-power systems. Films of cellulose triacetate metalized on one or both sides for use as substrates for electrodes and/or as dielectrics between electrodes in capacitors. Used without metalization as simple dielectric films. Advantages include high breakdown strength and self-healing capability.

Capacitance-voltage characteristics of MOS capacitors with Ge nanocrystals embedded in ZrO2 gate material

International Nuclear Information System (INIS)

Lee, Hye-Ryoung; Choi, Samjong; Cho, Kyoungah; Kim, Sangsig

2007-01-01

Capacitance versus voltage (C-V) curves of Ge-nanocrystals (NCs)-embedded metal-oxide-semiconductor (MOS) capacitors are characterized in this work. Ge NCs were formed in 20-nm thick ZrO 2 gate layers by ion implantation and subsequent annealing procedures. The formation of the Ge NCs in the ZrO 2 gate layers was confirmed by high-resolution transmission electron microscopy and energy dispersive spectroscopy. The C-V curves obtained from a representative MOS capacitor embedded with the Ge NCs exhibit a 3 V memory window as bias voltage varied from 9 to - 9 V and then back to the initial positive voltage, whereas MOS capacitors without Ge NCs show negligible memory windows at the same voltage range. This indicates the presence of charge storages in the Ge NCs. The counterclockwise hysteresis observed from the C-V curves implies that electrons are trapped in Ge NCs presented inside the ZrO 2 gate layer. And our experimental results obtained from capacitance versus time measurements show good retention characteristics of Ge-NCs-embedded MOS capacitors with ZrO 2 gate material for the application of NFGM

Applying Vertically Aligned Carbon Nanotubes in Energy Harvesting and Energy Storage

Science.gov (United States)

Oguntoye, Moses

This work has been a scientific inquisition into the potential of carbon nanotubes, fabricated in a vertically aligned configuration, for their application to solving pressing energy problems. This dissertation is introduced by providing a background to energy storage and generation as well as the various major equipment and techniques used throughout the scientific inquisition. The generic method of vertically aligned carbon nanotubes (VACNT) growth is then presented. By using a combination of recipes previously described in literature, an easy to replicate method of growing carbon nanotubes is developed with demonstrated success on different substates. The different conditions required to facilitate efficiency in the VACNT growth are highlighted. The properties of the as-grown VACNT forest are also studied and presented. Based on the recipe used, the VACNT are categorized as multiwalled and the number of walls is confirmed to be about 15 walls using transmission electron microscopy (TEM). Their graphitic nature is confirmed using thermogravimetric analysis (TGA). The surface area characterization is done using the Brunauer-Emmett-Teller (BET) method and weight-gain method. The first part of this dissertation deals with the application of the VACNT electrodes fabricated for the harvesting of mechanical energy using the triboelectric nanogenerator (TENG) technology. Here, energy is harvested from mechanical systems using both polytetrafluoroethylene (PTFE) and polyethylene (PET) counter electrodes to confirm the applicability of VACNT electrodes for this purpose. A mechanism for the electron motion is proposed based on the already identified dielectric-metal TENG pairing. Furthermore, the usefulness of this technology is demonstrated further by charging a 0.47microF capacitor to 4.5V in one minute using the VACNT-PTFE TENG. The second part of this dissertation deals with the application of VACNT electrodes in energy storage using supercapacitors. Firstly, the

Electrochemical energy storage

CERN Document Server

Tarascon, Jean-Marie

2015-01-01

The electrochemical storage of energy has become essential in assisting the development of electrical transport and use of renewable energies. French researchers have played a key role in this domain but Asia is currently the market leader. Not wanting to see history repeat itself, France created the research network on electrochemical energy storage (RS2E) in 2011. This book discusses the launch of RS2E, its stakeholders, objectives, and integrated structure that assures a continuum between basic research, technological research and industries. Here, the authors will cover the technological

Powder based superdielectric materials for novel Capacitor design

Science.gov (United States)

2017-06-01

found in cars, smartphones and other devices have adequate energy densities but lack optimal electric power delivery performance [4]. Stated differently... physical damage to the electrodes [5]. Conversely, capacitors store energy electrostatically by releasing excited state electrons collected on a...overview of capacitor theory is presented as a means of highlighting key physics principles applicable to this research. First, the concept of

2KJ/S 1KV, 25HZ PRR capacitor charging power supply with twin phase shifted primary windings to achieve high charge transfer rate and stability

International Nuclear Information System (INIS)

Kelkar, Y.; Singh, Y.P.; Thakurta, A.C.

2013-01-01

The capacitor charging power supply (CCPS) was developed to charge bank of 150uF energy storage capacitor (15uf , 10 nos in parallel) upto 1kV in 35 ms exhibiting a peak charging power of 2 kJ/s at a repetition rate of 25 pps. A CCPS observes a large change in load variations at the output. Initially the capacitor will act as a short circuit so the topology must be such that it should withstand short circuit condition repetitively. The High Voltage capacitor charging power supply consist of two identical full bridge resonant converters feeding to two primary windings of a transformer with rectified secondary connected to capacitor load. Topology selection is based on the fact that the series resonant converter with switching frequency f s , below 50% of the resonant frequency f r (f s ≤ 0.5 f r ) act as a current source. (author)

All 2D materials as electrodes for high power hybrid energy storage applications

Science.gov (United States)

Kato, Keiko; Sayed, Farheen N.; Babu, Ganguli; Ajayan, Pulickel M.

2018-04-01

Achieving both high energy and power densities from energy storage devices is a core strategy to meet the increasing demands of high performance portable electronics and electric transportation systems. Li-ion capacitor is a promising hybrid technology that strategically exploits high energy density from a Li-ion battery electrode and high power density from a supercapacitor electrode. However, the performance and safety of hybrid devices are still major concerns due to the use of graphite anodes which form passivation layers with organic electrolytes at lower potentials. Here, we explore 2D nanosheets as both anode and cathode electrodes to build a high power system without compromising energy density. Owing to the high electrical conductivity and multivalent redox activity at higher potentials, the Li-ion intercalation electrode is capable of maintaining large energy density at higher current rates with less safety risk than conventional systems. Hybrid devices consisting of all in all 2D electrodes deliver energy density as high as 121 Wh g-1 (at 240 W kg-1) and retains 29 Wh g-1 at high power density of 3600 W kg-1.

Advanced Fibre Based Energy Storage

Science.gov (United States)

Reid, Daniel Oliver

New energy storage devices are required to enable future technologies. With the rise of wearable consumer and medical devices, a suitable flexible and wearable means of storing electrical energy is required. Fibre-based devices present a possible method of achieving this aim. Fibres are inherently more flexible than their bulk counterparts, and as such can be employed to form the electrodes of flexible batteries and capacitors. They also present a facile possibility for incorporation into many fabrics and clothes, further boosting their potential for use in wearable devices. Electrically conducting fibres were produced from a dispersion of carbon nanomaterials in a room temperature ionic liquid. Coagulation of this dispersion was achieved through manual injection into aqueous solutions of xanthan gum. The limitations of this method are highlighted by very low ultimate tensile strengths of these fibres, in the order of 3 MPa, with high variation within all of the fibres. Fibres were also produced via scrolling of bi-component films containing poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) and poly(vinyl alcohol) (PVA). Chemical treatments were employed to impart water compatibility to these fibres, and their electrochemical, physical and electrical properties were analysed. Fibres were wet spun from two PEDOT:PSS sources, in several fibre diameters. The effect of chemical treatments on the fibres were investigated and compared. Short 5 min treatment times with dimethyl sulfoxide (DMSO) on 20 mum fibres produced from Clevios PH1000 were found to produce the best overall treatment. Up to a six-fold increase in electrical conductivity resulted, reaching 800 S cm-1, with up to 40 % increase in specific capacitance and no loss of mechanical strength (55 F g-1 and 150 MPa recorded). A wet spinning system to produce PEDOT:PSS fibres containing functionalised graphenes and carbon nanotubes, as well as birnessite nanotubes was subsequently developed

Space-Filling Supercapacitor Carpets: Highly scalable fractal architecture for energy storage

Science.gov (United States)

Tiliakos, Athanasios; Trefilov, Alexandra M. I.; Tanasǎ, Eugenia; Balan, Adriana; Stamatin, Ioan

2018-04-01

Revamping ground-breaking ideas from fractal geometry, we propose an alternative micro-supercapacitor configuration realized by laser-induced graphene (LIG) foams produced via laser pyrolysis of inexpensive commercial polymers. The Space-Filling Supercapacitor Carpet (SFSC) architecture introduces the concept of nested electrodes based on the pre-fractal Peano space-filling curve, arranged in a symmetrical equilateral setup that incorporates multiple parallel capacitor cells sharing common electrodes for maximum efficiency and optimal length-to-area distribution. We elucidate on the theoretical foundations of the SFSC architecture, and we introduce innovations (high-resolution vector-mode printing) in the LIG method that allow for the realization of flexible and scalable devices based on low iterations of the Peano algorithm. SFSCs exhibit distributed capacitance properties, leading to capacitance, energy, and power ratings proportional to the number of nested electrodes (up to 4.3 mF, 0.4 μWh, and 0.2 mW for the largest tested model of low iteration using aqueous electrolytes), with competitively high energy and power densities. This can pave the road for full scalability in energy storage, reaching beyond the scale of micro-supercapacitors for incorporating into larger and more demanding applications.

Electrical Properties of Thin-Film Capacitors Fabricated Using High Temperature Sputtered Modified Barium Titanate

Directory of Open Access Journals (Sweden)

Robert Mamazza

2012-04-01

Full Text Available Simple thin-film capacitor stacks were fabricated from sputter-deposited doped barium titanate dielectric films with sputtered Pt and/or Ni electrodes and characterized electrically. Here, we report small signal, low frequency capacitance and parallel resistance data measured as a function of applied DC bias, polarization versus applied electric field strength and DC load/unload experiments. These capacitors exhibited significant leakage (in the range 8–210 μA/cm2 and dielectric loss. Measured breakdown strength for the sputtered doped barium titanate films was in the range 200 kV/cm −2 MV/cm. For all devices tested, we observed clear evidence for dielectric saturation at applied electric field strengths above 100 kV/cm: saturated polarization was in the range 8–15 μC/cm2. When cycled under DC conditions, the maximum energy density measured for any of the capacitors tested here was ~4.7 × 10−2 W-h/liter based on the volume of the dielectric material only. This corresponds to a specific energy of ~8 × 10−3 W-h/kg, again calculated on a dielectric-only basis. These results are compared to those reported by other authors and a simple theoretical treatment provided that quantifies the maximum energy that can be stored in these and similar devices as a function of dielectric strength and saturation polarization. Finally, a predictive model is developed to provide guidance on how to tailor the relative permittivities of high-k dielectrics in order to optimize their energy storage capacities.

Physics of failure based analysis of aluminium electrolytic capacitor

International Nuclear Information System (INIS)

Sahoo, Satya Ranjan; Behera, S.K.; Kumar, Sachin; Varde, P.V.; Ravi Kumar, G.

2016-01-01

Electrolytic capacitors are one of the important devices in various power electronic systems, such as motor drives, uninterruptible power supply, electric vehicles and dc power supply. Electrolytic capacitors are also the integral part of many other electronic devices. One of the primary function of electrolytic capacitors is the smoothing of voltage ripple and storing electrical energy. However, the electrolytic capacitor has the shortest lifespan of components in power electronics. Past experiences show that electrolytic capacitor tends to degrade and fail faster under high electrical or thermal stress conditions during operations. The primary failure mechanism of an electrolytic capacitor is the evaporation of the electrolyte due to electrical or thermal overstress. This leads to the drift in the values of two important parameters-capacitance and equivalent series resistance (ESR) of the electrolytic capacitor. An attempt has been made to age the electrolytic capacitor and validate the results. The overall goal is to derive the accurate degradation model of the electrolytic capacitor. (author)

Molecular solar thermal energy storage in photoswitch oligomers increases energy densities and storage times.

Science.gov (United States)

Mansø, Mads; Petersen, Anne Ugleholdt; Wang, Zhihang; Erhart, Paul; Nielsen, Mogens Brøndsted; Moth-Poulsen, Kasper

2018-05-16

Molecular photoswitches can be used for solar thermal energy storage by photoisomerization into high-energy, meta-stable isomers; we present a molecular design strategy leading to photoswitches with high energy densities and long storage times. High measured energy densities of up to 559 kJ kg -1 (155 Wh kg -1 ), long storage lifetimes up to 48.5 days, and high quantum yields of conversion of up to 94% per subunit are demonstrated in norbornadiene/quadricyclane (NBD/QC) photo-/thermoswitch couples incorporated into dimeric and trimeric structures. By changing the linker unit between the NBD units, we can at the same time fine-tune light-harvesting and energy densities of the dimers and trimers so that they exceed those of their monomeric analogs. These new oligomers thereby meet several of the criteria to be met for an optimum molecule to ultimately enter actual devices being able to undergo closed cycles of solar light-harvesting, energy storage, and heat release.

Fe3O4/carbon hybrid nanoparticle electrodes for high-capacity electrochemical capacitors.

Science.gov (United States)

Lee, Jun Seop; Shin, Dong Hoon; Jun, Jaemoon; Lee, Choonghyeon; Jang, Jyongsik

2014-06-01

Fe3O4/carbon hybrid nanoparticles (FeCHNPs) were fabricated using dual-nozzle electrospraying, vapor deposition polymerization (VDP), and carbonization. FeOOH nanoneedles decorated with polypyrrole (PPy) nanoparticles (FePNPs) were fabricated by electrospraying pristine PPy mixed with FeCl3 solution, followed by heating stirring reaction. A PPy coating was then formed on the FeOOH nanoneedles through a VDP process. FeCHNPs were produced through carbonization of PPy and FeOOH phase transitions. These hybrid carbon nanoparticles (NPs) were used to build electrodes of electrochemical capacitors. The specific capacitance of the FeCHNPs was 455 F g(-1), which is larger than that of pristine PPy NPs (105 F g(-1)) or other hybrid PPy NPs. Furthermore, the FeCHNP-based capacitors exhibited better cycle stability during charge-discharge cycling than other hybrid NP capacitors. This is because the carbon layer on the Fe3 O4 surface formed a protective coating, preventing damage to the electrode materials during the charge-discharge processes. This fabrication technique is an effective approach for forming stable carbon/metal oxide nanostructures for energy storage applications. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

A Review of Energy Storage Technologies

DEFF Research Database (Denmark)

Connolly, David

2010-01-01

A brief examination into the energy storage techniques currently available for the integration of fluctuating renewable energy was carried out. These included Pumped Hydroelectric Energy Storage (PHES), Underground Pumped Hydroelectric Energy Storage (UPHES), Compressed Air Energy Storage (CAES...... than PHES depending on the availability of suitable sites. FBES could also be utilised in the future for the integration of wind, but it may not have the scale required to exist along with electric vehicles. The remaining technologies will most likely be used for their current applications...

Battery energy storage market feasibility study

Energy Technology Data Exchange (ETDEWEB)

Kraft, S. [Frost and Sullivan, Mountain View, CA (United States); Akhil, A. [Sandia National Labs., Albuquerque, NM (United States). Energy Storage Systems Analysis and Development Dept.

1997-07-01

Under the sponsorship of the Department of Energy`s Office of Utility Technologies, the Energy Storage Systems Analysis and Development Department at Sandia National Laboratories (SNL) contracted Frost and Sullivan to conduct a market feasibility study of energy storage systems. The study was designed specifically to quantify the energy storage market for utility applications. This study was based on the SNL Opportunities Analysis performed earlier. Many of the groups surveyed, which included electricity providers, battery energy storage vendors, regulators, consultants, and technology advocates, viewed energy storage as an important enabling technology to enable increased use of renewable energy and as a means to solve power quality and asset utilization issues. There are two versions of the document available, an expanded version (approximately 200 pages, SAND97-1275/2) and a short version (approximately 25 pages, SAND97-1275/1).

Iodine encapsulation in CNTs and its application for electrochemical capacitor

International Nuclear Information System (INIS)

Taniguchi, Y.; Ishii, Y.; Al-zubaidi, A.; Kawasaki, S.; Rashid, M.; Syakirin, A.

2016-01-01

We report the experimental results for new type electrochemical capacitor using iodine redox reaction in single-walled carbon nanotubes (SWCNTs). It was found that the energy density of the present redox capacitor using SWCNTs is almost three times larger than that of the normal electric double layer capacitor.

Iodine encapsulation in CNTs and its application for electrochemical capacitor

Energy Technology Data Exchange (ETDEWEB)

Taniguchi, Y.; Ishii, Y.; Al-zubaidi, A.; Kawasaki, S., E-mail: kawasaki.shinji@nitech.ac.jp [Nagoya Institute of Technology, Gokiso, Showa, Nagoya, Aichi (Japan); Rashid, M.; Syakirin, A. [Universiti Teknologi MARA (UiTM), 40450 Shah Alam, Selangor (Malaysia)

2016-07-06

We report the experimental results for new type electrochemical capacitor using iodine redox reaction in single-walled carbon nanotubes (SWCNTs). It was found that the energy density of the present redox capacitor using SWCNTs is almost three times larger than that of the normal electric double layer capacitor.

Wind-energy storage

Science.gov (United States)

Gordon, L. H.

1980-01-01

Program SIMWEST can model wind energy storage system using any combination of five types of storage: pumped hydro, battery, thermal, flywheel, and pneumatic. Program is tool to aid design of optional system for given application with realistic simulation for further evaluation and verification.

Energy storage in Canada - Embassy report

International Nuclear Information System (INIS)

Quennehen, Sylvain

2014-09-01

After having outlined what is at stake in energy storage in the world (brief presentation of storage methods, overview of world electricity production and its storage challenges), and given an overview of the Canadian energy sector, this report gives an overview of the Canadian key and particularly innovating actors: main organisations, scientific research (in the fields of advanced batteries, of fuel cells, and of thermal storage), industrial sector (leaders in electricity production, in the electric or hybrid automotive sector and in the field of portable electronic devices, in the Li-ion battery sector, and in the hydrogen fuel cell sector, innovating actors in other energy storage methods). The author then discusses the innovation momentum in Canada: examples of energy storage projects by public organisations (CNRC, RNC), industrial projects in energy projects, investment dynamics

Analysis and Design of a Bidirectional Isolated DC-DC Converter for Fuel Cell and Super-Capacitor Hybrid System

DEFF Research Database (Denmark)

Zhang, Zhe; Ouyang, Ziwei; Thomsen, Ole Cornelius

2012-01-01

Electrical power system in future uninterruptible power supply (UPS) or electrical vehicle (EV) may employ hybrid energy sources, such as fuel cells and super-capacitors. It will be necessary to efficiently draw the energy from these two sources as well as recharge the energy storage elements...... by the DC bus. In this paper, a bidirectional isolated DC-DC converter controlled by phase-shift and duty cycle for the fuel cell hybrid energy system is analyzed and designed. The proposed topology minimizes the number of switches and their associated gate driver components by using two high frequency...

Scalable fabrication of high-power graphene micro-supercapacitors for flexible and on-chip energy storage

Science.gov (United States)

El-Kady, Maher F.; Kaner, Richard B.

2013-02-01

The rapid development of miniaturized electronic devices has increased the demand for compact on-chip energy storage. Microscale supercapacitors have great potential to complement or replace batteries and electrolytic capacitors in a variety of applications. However, conventional micro-fabrication techniques have proven to be cumbersome in building cost-effective micro-devices, thus limiting their widespread application. Here we demonstrate a scalable fabrication of graphene micro-supercapacitors over large areas by direct laser writing on graphite oxide films using a standard LightScribe DVD burner. More than 100 micro-supercapacitors can be produced on a single disc in 30 min or less. The devices are built on flexible substrates for flexible electronics and on-chip uses that can be integrated with MEMS or CMOS in a single chip. Remarkably, miniaturizing the devices to the microscale results in enhanced charge-storage capacity and rate capability. These micro-supercapacitors demonstrate a power density of ~200 W cm-3, which is among the highest values achieved for any supercapacitor.

High Energy Density and High Temperature Multilayer Capacitor Films for Electric Vehicle Applications

Science.gov (United States)

Treufeld, Imre; Song, Michelle; Zhu, Lei; Baer, Eric; Snyder, Joe; Langhe, Deepak

2015-03-01

Multilayer films (MLFs) with high energy density and high temperature capability (>120 °C) have been developed at Case Western Reserve University. Such films offer a potential solution for electric car DC-link capacitors, where high ripple currents and high temperature tolerance are required. The current state-of-the-art capacitors used in electric cars for converting DC to AC use biaxially oriented polypropylene (BOPP), which can only operate at temperatures up to 85 °C requiring an external cooling system. The polycarbonate (PC)/poly(vinylidene fluoride) (PVDF) MLFs have a higher permittivity compared to that of BOPP (2.3), leading to higher energy density. They have good mechanical stability and reasonably low dielectric losses at 120 °C. Nonetheless, our preliminary dielectric measurements show that the MLFs exhibit appreciable dielectric losses (20%) at 120 °C, which would, despite all the other advantages, make them not suitable for practical applications. Our preliminary data showed that dielectric losses of the MLFs at 120 °C up to 400 MV/m and 1000 Hz originate mostly from impurity ionic conduction. This work is supported by the NSF PFI/BIC Program (IIP-1237708).

Ionic liquids and their solid-state analogues as materials for energy generation and storage

Science.gov (United States)

Macfarlane, Douglas R.; Forsyth, Maria; Howlett, Patrick C.; Kar, Mega; Passerini, Stefano; Pringle, Jennifer M.; Ohno, Hiroyuki; Watanabe, Masayoshi; Yan, Feng; Zheng, Wenjun; Zhang, Shiguo; Zhang, Jie

2016-02-01

Salts that are liquid at room temperature, now commonly called ionic liquids, have been known for more than 100 years; however, their unique properties have only come to light in the past two decades. In this Review, we examine recent work in which the properties of ionic liquids have enabled important advances to be made in sustainable energy generation and storage. We discuss the use of ionic liquids as media for synthesis of electromaterials, for example, in the preparation of doped carbons, conducting polymers and intercalation electrode materials. Focusing on their intrinsic ionic conductivity, we examine recent reports of ionic liquids used as electrolytes in emerging high-energy-density and low-cost batteries, including Li-ion, Li-O2, Li-S, Na-ion and Al-ion batteries. Similar developments in electrolyte applications in dye-sensitized solar cells, thermo-electrochemical cells, double-layer capacitors and CO2 reduction are also discussed.

Fundamental characteristics of new electric power storage equipment celled `ECS`; Atarashii denryoku chozo sochi `ECS` no kisoteki tokusei

Energy Technology Data Exchange (ETDEWEB)

Okamura, T.; Yamagishi, M.

1997-01-30

This paper introduces new electric power storage equipment called an energy capacitor system. A special electrically double-layered capacitor with its energy density raised in sacrifice of internal resistance has the current so adjusted that loss will not increase by using a switching converter (consisting of a charger and a current pump). The capacitor is charged and discharged at high efficiency. Upper limits of the charge voltage for each capacitor are connected with parallel monitor circuits so that maximum charge voltage of each capacitor will be aligned at one level, wherein charge and discharge are performed with that voltage used as the starting point. A drawback in a capacitor is lower energy density than in a secondary battery. Therefore, high voltage withstanding organic electrolyte was used, and electrode activated carbon was given discussions starting from its raw material structures. The efforts resulted in obtaining as high energy density as 43 Wh/kg (about 20 times as much as in conventional materials, and comparable to lead-acid batteries). In order to minimize heat generation due to the increased internal resistance, a switching converter was used to suppress charge/discharge currents to the minimum required levels. Although the capacitor still has insufficient voltage withstanding power and short life, the energy density is increasing beyond the initial estimation. The next problem to be solved is reduction in production cost for its industrialization. 4 refs., 4 figs., 2 tabs.

Battery energy storage market feasibility study

International Nuclear Information System (INIS)

Kraft, S.; Akhil, A.

1997-07-01

Under the sponsorship of the Department of Energy's Office of Utility Technologies, the Energy Storage Systems Analysis and Development Department at Sandia National Laboratories (SNL) contracted Frost and Sullivan to conduct a market feasibility study of energy storage systems. The study was designed specifically to quantify the energy storage market for utility applications. This study was based on the SNL Opportunities Analysis performed earlier. Many of the groups surveyed, which included electricity providers, battery energy storage vendors, regulators, consultants, and technology advocates, viewed energy storage as an important enabling technology to enable increased use of renewable energy and as a means to solve power quality and asset utilization issues. There are two versions of the document available, an expanded version (approximately 200 pages, SAND97-1275/2) and a short version (approximately 25 pages, SAND97-1275/1)

Energy Storage Project

Science.gov (United States)

Mercer, Carolyn R.; Jankovsky, Amy L.; Reid, Concha M.; Miller, Thomas B.; Hoberecht, Mark A.

2011-01-01

NASA's Exploration Technology Development Program funded the Energy Storage Project to develop battery and fuel cell technology to meet the expected energy storage needs of the Constellation Program for human exploration. Technology needs were determined by architecture studies and risk assessments conducted by the Constellation Program, focused on a mission for a long-duration lunar outpost. Critical energy storage needs were identified as batteries for EVA suits, surface mobility systems, and a lander ascent stage; fuel cells for the lander and mobility systems; and a regenerative fuel cell for surface power. To address these needs, the Energy Storage Project developed advanced lithium-ion battery technology, targeting cell-level safety and very high specific energy and energy density. Key accomplishments include the development of silicon composite anodes, lithiated-mixed-metal-oxide cathodes, low-flammability electrolytes, and cell-incorporated safety devices that promise to substantially improve battery performance while providing a high level of safety. The project also developed "non-flow-through" proton-exchange-membrane fuel cell stacks. The primary advantage of this technology set is the reduction of ancillary parts in the balance-of-plant--fewer pumps, separators and related components should result in fewer failure modes and hence a higher probability of achieving very reliable operation, and reduced parasitic power losses enable smaller reactant tanks and therefore systems with lower mass and volume. Key accomplishments include the fabrication and testing of several robust, small-scale nonflow-through fuel cell stacks that have demonstrated proof-of-concept. This report summarizes the project s goals, objectives, technical accomplishments, and risk assessments. A bibliography spanning the life of the project is also included.

Design and thermodynamic analysis of a hybrid energy storage system based on A-CAES (adiabatic compressed air energy storage) and FESS (flywheel energy storage system) for wind power application

International Nuclear Information System (INIS)

Zhao, Pan; Dai, Yiping; Wang, Jiangfeng

2014-01-01

Electricity generated from renewable wind sources is highly erratic due to the intermittent nature of wind. This uncertainty of wind power can lead to challenges regarding power system operation and dispatch. Energy storage system in conjunction with wind energy system can offset these effects, making the wind power controllable. Moreover, the power spectrum of wind power exhibits that the fluctuations of wind power include various components with different frequencies and amplitudes. Thus, the hybrid energy storage system is more suitable for smoothing out the wind power fluctuations effectively rather than the independent energy storage system. A hybrid energy storage system consisting of adiabatic compressed air energy storage (A-CAES) system and flywheel energy storage system (FESS) is proposed for wind energy application. The design of the proposed system is laid out firstly. The A-CAES system operates in variable cavern pressure, constant turbine inlet pressure mode, whereas the FESS is controlled by constant power strategy. Then, the off-design analysis of the proposed system is carried out. Meanwhile, a parametric analysis is also performed to investigate the effects of several parameters on the system performance, including the ambient conditions, inlet temperature of compressor, storage cavern temperature, maximum and minimum pressures of storage cavern. - Highlights: • A wind-hybrid energy storage system composed of A-CAES and FESS is proposed. • The design of the proposed hybrid energy storage system is laid out. • The off-design analysis of the proposed system is carried out. • A parametric analysis is conducted to examine the system performance

Electrochemistry serving people and nature: high-energy ecocapacitors based on redox-active electrolytes.

Science.gov (United States)

Frackowiak, Elzbieta; Fic, Krzysztof; Meller, Mikolaj; Lota, Grzegorz

2012-07-01

Positive Poles: A new type of electrochemical capacitor with two different aqueous solutions, separated by a Nafion membrane is described. High capacitance values as well as excellent energy/power characteristics are reported and discussed. The neutral character of the applied electrolytes makes this capacitor an environmentally friendly, easy to assemble, and cost-effective device for energy storage. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Energy Storage Publications | Transportation Research | NREL

Science.gov (United States)

, California. 23 pp.; NREL Report No. PR-5400-60290. Optimal Sizing of Energy Storage and Photovoltaic Power (11) 2017 pp. 1095-1118. Life Prediction Model for Grid-Connected Li-ion Battery Energy Storage System Prediction Model for Grid-Connected Li-ion Battery Energy Storage System - Preprint Paper Source: Smith

Hydrogen based energy storage for solar energy systems

Energy Technology Data Exchange (ETDEWEB)

Vanhanen, J.; Hagstroem, M.; Lund, P. [Helsinki Univ. of Technology, Otaniemi (Finland). Advanced Energy Systems

1998-10-01

The main technical constraint in solar energy systems which operate around the year is the lack of suitable long-term energy storage. Conventional solutions to overcome the problem of seasonal storage in PV power systems are to use oversized batteries as a seasonal energy storage, or to use a diesel back-up generator. However, affordable lead-acid batteries are not very suitable for seasonal energy storage because of a high self-discharge rate and enhanced deterioration and divergence of the single cells during prolonged periods of low state of charge in times of low irradiation. These disadvantages can be avoided by a back-up system, e.g. a diesel generator, which car supply energy to the loads and charge the battery to the full state of charge to avoid the above mentioned disadvantages. Unfortunately, diesel generators have several disadvantages, e.g. poor starting reliability, frequent need for maintenance and noise

Soft capacitor fibers using conductive polymers for electronic textiles

Science.gov (United States)

Gu, Jian Feng; Gorgutsa, Stephan; Skorobogatiy, Maksim

2010-11-01

A novel, highly flexible, conductive polymer-based fiber with high electric capacitance is reported. In its cross section the fiber features a periodic sequence of hundreds of conductive and isolating plastic layers positioned around metallic electrodes. The fiber is fabricated using the fiber drawing method, where a multi-material macroscopic preform is drawn into a sub-millimeter capacitor fiber in a single fabrication step. Several kilometers of fibers can be obtained from a single preform with fiber diameters ranging between 500 and 1000 µm. A typical measured capacitance of our fibers is 60-100 nF m-1 and it is independent of the fiber diameter. Analysis of the fiber frequency response shows that in its simplest interrogation mode the capacitor fiber has a transverse resistance of 5 kΩ m L-1, which is inversely proportional to the fiber length L and is independent of the fiber diameter. Softness of the fiber materials, the absence of liquid electrolyte in the fiber structure, ease of scalability to large production volumes and high capacitance of our fibers make them interesting for various smart textile applications ranging from distributed sensing to energy storage.

Soft capacitor fibers using conductive polymers for electronic textiles

International Nuclear Information System (INIS)

Gu, Jian Feng; Gorgutsa, Stephan; Skorobogatiy, Maksim

2010-01-01

A novel, highly flexible, conductive polymer-based fiber with high electric capacitance is reported. In its cross section the fiber features a periodic sequence of hundreds of conductive and isolating plastic layers positioned around metallic electrodes. The fiber is fabricated using the fiber drawing method, where a multi-material macroscopic preform is drawn into a sub-millimeter capacitor fiber in a single fabrication step. Several kilometers of fibers can be obtained from a single preform with fiber diameters ranging between 500 and 1000 µm. A typical measured capacitance of our fibers is 60–100 nF m −1 and it is independent of the fiber diameter. Analysis of the fiber frequency response shows that in its simplest interrogation mode the capacitor fiber has a transverse resistance of 5 kΩ m L −1 , which is inversely proportional to the fiber length L and is independent of the fiber diameter. Softness of the fiber materials, the absence of liquid electrolyte in the fiber structure, ease of scalability to large production volumes and high capacitance of our fibers make them interesting for various smart textile applications ranging from distributed sensing to energy storage

Heat pipe based cold energy storage systems for datacenter energy conservation

International Nuclear Information System (INIS)

Singh, Randeep; Mochizuki, Masataka; Mashiko, Koichi; Nguyen, Thang

2011-01-01

In the present paper, design and economics of the novel type of thermal control system for datacenter using heat pipe based cold energy storage has been proposed and discussed. Two types of cold energy storage system namely: ice storage system and cold water storage system are explained and sized for datacenter with heat output capacity of 8800 kW. Basically, the cold energy storage will help to reduce the chiller running time that will save electricity related cost and decrease greenhouse gas emissions resulting from the electricity generation from non-renewable sources. The proposed cold energy storage system can be retrofit or connected in the existing datacenter facilities without major design changes. Out of the two proposed systems, ice based cold energy storage system is mainly recommended for datacenters which are located in very cold locations and therefore can offer long term seasonal storage of cold energy within reasonable cost. One of the potential application domains for ice based cold energy storage system using heat pipes is the emergency backup system for datacenter. Water based cold energy storage system provides more compact size with short term storage (hours to days) and is potential for datacenters located in areas with yearly average temperature below the permissible cooling water temperature (∼25 o C). The aforesaid cold energy storage systems were sized on the basis of metrological conditions in Poughkeepsie, New York. As an outcome of the thermal and cost analysis, water based cold energy storage system with cooling capability to handle 60% of datacenter yearly heat load will provide an optimum system size with minimum payback period of 3.5 years. Water based cold energy storage system using heat pipes can be essentially used as precooler for chiller. Preliminary results obtained from the experimental system to test the capability of heat pipe based cold energy storage system have provided satisfactory outcomes and validated the proposed

A Comprehensive Review of Thermal Energy Storage

Directory of Open Access Journals (Sweden)

Ioan Sarbu

2018-01-01

Full Text Available Thermal energy storage (TES is a technology that stocks thermal energy by heating or cooling a storage medium so that the stored energy can be used at a later time for heating and cooling applications and power generation. TES systems are used particularly in buildings and in industrial processes. This paper is focused on TES technologies that provide a way of valorizing solar heat and reducing the energy demand of buildings. The principles of several energy storage methods and calculation of storage capacities are described. Sensible heat storage technologies, including water tank, underground, and packed-bed storage methods, are briefly reviewed. Additionally, latent-heat storage systems associated with phase-change materials for use in solar heating/cooling of buildings, solar water heating, heat-pump systems, and concentrating solar power plants as well as thermo-chemical storage are discussed. Finally, cool thermal energy storage is also briefly reviewed and outstanding information on the performance and costs of TES systems are included.

Energy Storage Economics

Energy Technology Data Exchange (ETDEWEB)

Elgqvist, Emma M [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

2017-09-07

This presentation provides an overview on energy storage economics including recent market trends, battery terminology and concepts, value streams, challenges, and an example of how photovoltaics and storage can be used to lower demand charges. It also provides an overview of the REopt Lite web tool inputs and outputs.

Solar Energy Grid Integration Systems -- Energy Storage (SEGIS-ES).

Energy Technology Data Exchange (ETDEWEB)

Hanley, Charles J.; Ton, Dan T. (U.S. Department of Energy, Washington, D.C.); Boyes, John D.; Peek, Georgianne Huff

2008-07-01

This paper describes the concept for augmenting the SEGIS Program (an industry-led effort to greatly enhance the utility of distributed PV systems) with energy storage in residential and small commercial applications (SEGIS-ES). The goal of SEGIS-ES is to develop electrical energy storage components and systems specifically designed and optimized for grid-tied PV applications. This report describes the scope of the proposed SEGIS-ES Program and why it will be necessary to integrate energy storage with PV systems as PV-generated energy becomes more prevalent on the nation's utility grid. It also discusses the applications for which energy storage is most suited and for which it will provide the greatest economic and operational benefits to customers and utilities. Included is a detailed summary of the various storage technologies available, comparisons of their relative costs and development status, and a summary of key R&D needs for PV-storage systems. The report concludes with highlights of areas where further PV-specific R&D is needed and offers recommendations about how to proceed with their development.

Study of Aquifer Thermal Energy Storage

Science.gov (United States)

Okuyama, Masaaki; Umemiya, Hiromichi; Shibuya, Ikuko; Haga, Eiji

Yamagata University 'Aquifer Thermal Energy Storage (ATES)' is the experimental system which has been running since 1982. From the results for along terms of experiments, we obtain many important knowledge. This paper presents the accomplishments for 16 years and the characteristics of thermal energy storage in thermal energy storage well. The conclusions show as follows. 1)In recent years, the thermal recovery factor of warm energy storage well becomes almost constant at about 60%. 2) The thermal recovery factor of cool energy storage well increases gradually and becomes at about 15%. 3) Since the ferric colloidal dam is formed in aquifer, thermal recovery factor increase year after year. 4) Back wash can remove clogging for ferric colloidal dam. 5) The apparent thermal diffusivity decrease gradually due to ferric colloidal dam.

Energy Storage System with Voltage Equalization Strategy for Wind Energy Conversion

Directory of Open Access Journals (Sweden)

Cheng-Tao Tsai

2012-07-01

Full Text Available In this paper, an energy storage system with voltage equalization strategy for wind energy conversion is presented. The proposed energy storage system provides a voltage equalization strategy for series-connected lead-acid batteries to increase their total storage capacity and lifecycle. In order to draw the maximum power from the wind energy, a perturbation-and-observation method and digital signal processor (DSP are incorporated to implement maximum power point tracking (MPPT algorithm and power regulating scheme. In the proposed energy storage system, all power switches have zero-voltage-switching (ZVS feature at turn-on transition. Therefore, the conversion efficiency can be increased. Finally, a prototype energy storage system for wind energy conversion is built and implemented. Experimental results have verified the performance and feasibility of the proposed energy storage system for wind energy conversion.

The dynamic characteristics of harvesting energy from mechanical vibration via piezoelectric conversion

International Nuclear Information System (INIS)

Fan Kang-Qi; Ming Zheng-Feng; Xu Chun-Hui; Chao Feng-Bo

2013-01-01

As an alternative power solution for low-power devices, harvesting energy from the ambient mechanical vibration has received increasing research interest in recent years. In this paper we study the transient dynamic characteristics of a piezoelectric energy harvesting system including a piezoelectric energy harvester, a bridge rectifier, and a storage capacitor. To accomplish this, this energy harvesting system is modeled, and the charging process of the storage capacitor is investigated by employing the in-phase assumption. The results indicate that the charging voltage across the storage capacitor and the gathered power increase gradually as the charging process proceeds, whereas the charging rate slows down over time as the charging voltage approaches to the peak value of the piezoelectric voltage across the piezoelectric materials. In addition, due to the added electrical damping and the change of the system natural frequency when the charging process is initiated, a sudden drop in the vibration amplitude is observed, which in turn affects the charging rate. However, the vibration amplitude begins to increase as the charging process continues, which is caused by the decrease in the electrical damping (i.e., the decrease in the energy removed from the mechanical vibration). This electromechanical coupling characteristic is also revealed by the variation of the vibration amplitude with the charging voltage. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

Numerical investigation of a joint approach to thermal energy storage and compressed air energy storage in aquifers

International Nuclear Information System (INIS)

Guo, Chaobin; Zhang, Keni; Pan, Lehua; Cai, Zuansi; Li, Cai; Li, Yi

2017-01-01

Highlights: •One wellbore-reservoir numerical model was built to study the impact of ATES on CAESA. •With high injection temperature, the joint of ATES can improve CAESA performance. •The considerable utilization of geothermal occurs only at the beginning of operations. •Combination of CAESA and ATES can be achieved in common aquifers. -- Abstract: Different from conventional compressed air energy storage (CAES) systems, the advanced adiabatic compressed air energy storage (AA-CAES) system can store the compression heat which can be used to reheat air during the electricity generation stage. Thus, AA-CAES system can achieve a higher energy storage efficiency. Similar to the AA-CAES system, a compressed air energy storage in aquifers (CAESA) system, which is integrated with an aquifer thermal energy storage (ATES) could possibly achieve the same objective. In order to investigate the impact of ATES on the performance of CAESA, different injection air temperature schemes are designed and analyzed by using numerical simulations. Key parameters relative to energy recovery efficiencies of the different injection schemes, such as pressure distribution and temperature variation within the aquifers as well as energy flow rate in the injection well, are also investigated in this study. The simulations show that, although different injection schemes have a similar overall energy recovery efficiency (∼97%) as well as a thermal energy recovery efficiency (∼79.2%), the higher injection air temperature has a higher energy storage capability. Our results show the total energy storage for the injection air temperature at 80 °C is about 10% greater than the base model scheme at 40 °C. Sensitivity analysis reveal that permeability of the reservoir boundary could have significant impact on the system performance. However, other hydrodynamic and thermodynamic properties, such as the storage reservoir permeability, thermal conductivity, rock grain specific heat and rock

Optimized use of superconducting magnetic energy storage for electromagnetic rail launcher powering

Science.gov (United States)

Badel, Arnaud; Tixador, Pascal; Arniet, Michel

2012-01-01

Electromagnetic rail launchers (EMRLs) require very high currents, from hundreds of kA to several MA. They are usually powered by capacitors. The use of superconducting magnetic energy storage (SMES) in the supply chain of an EMRL is investigated, as an energy buffer and as direct powering source. Simulations of direct powering are conducted to quantify the benefits of this method in terms of required primary energy. In order to enhance further the benefits of SMES powering, a novel integration concept is proposed, the superconducting self-supplied electromagnetic launcher (S3EL). In the S3EL, the SMES is used as a power supply for the EMRL but its coil serves also as an additional source of magnetic flux density, in order to increase the thrust (or reduce the required current for a given thrust). Optimization principles for this new concept are presented. Simulations based on the characteristics of an existing launcher demonstrate that the required current could be reduced by a factor of seven. Realizing such devices with HTS cables should be possible in the near future, especially if the S3EL concept is used in combination with the XRAM principle, allowing current multiplication.

Optimized use of superconducting magnetic energy storage for electromagnetic rail launcher powering

International Nuclear Information System (INIS)

Badel, Arnaud; Tixador, Pascal; Arniet, Michel

2012-01-01

Electromagnetic rail launchers (EMRLs) require very high currents, from hundreds of kA to several MA. They are usually powered by capacitors. The use of superconducting magnetic energy storage (SMES) in the supply chain of an EMRL is investigated, as an energy buffer and as direct powering source. Simulations of direct powering are conducted to quantify the benefits of this method in terms of required primary energy. In order to enhance further the benefits of SMES powering, a novel integration concept is proposed, the superconducting self-supplied electromagnetic launcher (S 3 EL). In the S 3 EL, the SMES is used as a power supply for the EMRL but its coil serves also as an additional source of magnetic flux density, in order to increase the thrust (or reduce the required current for a given thrust). Optimization principles for this new concept are presented. Simulations based on the characteristics of an existing launcher demonstrate that the required current could be reduced by a factor of seven. Realizing such devices with HTS cables should be possible in the near future, especially if the S 3 EL concept is used in combination with the XRAM principle, allowing current multiplication.

Photovoltaic power systems energy storage

International Nuclear Information System (INIS)

Buldini, P.L.

1991-01-01

Basically, the solar photovoltaic power system consists of: Array of solar panels; Charge/voltage stabilizer; Blocking diode and Storage device. The storage device is a very important part of the system due to the necessity to harmonize the inevitable time shift between energy supply and demand. As energy storage, different devices can be utilized, such as hydropumping, air or other gas compression, flywheel, superconducting magnet, hydrogen generation and so on, but actually secondary (rechargeable) electrochemical cells appear to be the best storage device, due to the direct use for recharge of the d.c. current provided by the solar panels, without any intermediate step of energy transformation and its consequent loss of efficiency

Hybrid Hydro Renewable Energy Storage Model

Science.gov (United States)

Dey, Asit Kr

2018-01-01

This paper aims at presenting wind & tidal turbine pumped-storage solutions for improving the energy efficiency and economic sustainability of renewable energy systems. Indicated a viable option to solve problems of energy production, as well as in the integration of intermittent renewable energies, providing system flexibility due to energy load’s fluctuation, as long as the storage of energy from intermittent sources. Sea water storage energy is one of the best and most efficient options in terms of renewable resources as an integrated solution allowing the improvement of the energy system elasticity and the global system efficiency.

Smart households: Dispatch strategies and economic analysis of distributed energy storage for residential peak shaving

International Nuclear Information System (INIS)

Zheng, Menglian; Meinrenken, Christoph J.; Lackner, Klaus S.

2015-01-01

Highlights: • Cost-effectiveness of building-based storage for peak shaving has hitherto not been well understood. • Several existing storage technologies are shown to provide cost-effective peak shaving. • Setting grid demand targets rather than hard demand limits improves economics. • Accounting for seasonal demand variations in storage dispatch strategy improves economics further. • Total-energy-throughput approach is used to determine storage lifetimes. - Abstract: Meeting time-varying peak demand poses a key challenge to the U.S. electricity system. Building-based electricity storage – to enable demand response (DR) without curtailing actual appliance usage – offers potential benefits of lower electricity production cost, higher grid reliability, and more flexibility to integrate renewables. DR tariffs are currently available in the U.S. but building-based storage is still underutilized due to insufficiently understood cost-effectiveness and dispatch strategies. Whether DR schemes can yield a profit for building operators (i.e., reduction in electricity bill that exceeds levelized storage cost) and which particular storage technology yields the highest profit is yet to be answered. This study aims to evaluate the economics of providing peak shaving DR under a realistic tariff (Con Edison, New York), using a range of storage technologies (conventional and advanced batteries, flywheel, magnetic storage, pumped hydro, compressed air, and capacitors). An agent-based stochastic model is used to randomly generate appliance-level demand profiles for an average U.S. household. We first introduce a levelized storage cost model which is based on a total-energy-throughput lifetime. We then develop a storage dispatch strategy which optimizes the storage capacity and the demand limit on the grid. We find that (i) several storage technologies provide profitable DR; (ii) annual profit from such DR can range from 1% to 39% of the household’s non-DR electricity

Layer-by-layer assembled polyaniline nanofiber/multiwall carbon nanotube thin film electrodes for high-power and high-energy storage applications.

Science.gov (United States)

Hyder, Md Nasim; Lee, Seung Woo; Cebeci, Fevzi Ç; Schmidt, Daniel J; Shao-Horn, Yang; Hammond, Paula T

2011-11-22

Thin film electrodes of polyaniline (PANi) nanofibers and functionalized multiwall carbon nanotubes (MWNTs) are created by layer-by-layer (LbL) assembly for microbatteries or -electrochemical capacitors. Highly stable cationic PANi nanofibers, synthesized from the rapid aqueous phase polymerization of aniline, are assembled with carboxylic acid functionalized MWNT into LbL films. The pH-dependent surface charge of PANi nanofibers and MWNTs allows the system to behave like weak polyelectrolytes with controllable LbL film thickness and morphology by varying the number of bilayers. The LbL-PANi/MWNT films consist of a nanoscale interpenetrating network structure with well developed nanopores that yield excellent electrochemical performance for energy storage applications. These LbL-PANi/MWNT films in lithium cell can store high volumetric capacitance (~238 ± 32 F/cm(3)) and high volumetric capacity (~210 mAh/cm(3)). In addition, rate-dependent galvanostatic tests show LbL-PANi/MWNT films can deliver both high power and high energy density (~220 Wh/L(electrode) at ~100 kW/L(electrode)) and could be promising positive electrode materials for thin film microbatteries or electrochemical capacitors. © 2011 American Chemical Society

Cellulose triacetate, thin film dielectric capacitor

Science.gov (United States)

Yen, Shiao-Ping S. (Inventor); Jow, T. Richard (Inventor)

1995-01-01

Very thin films of cellulose triacetate are cast from a solution containing a small amount of high boiling temperature, non-solvent which evaporates last and lifts the film from the casting surface. Stretched, oriented, crystallized films have high electrical breakdown properties. Metallized films less than about 2 microns in thickness form self-healing electrodes for high energy density, pulsed power capacitors. Thicker films can be utilized as a dielectric for a capacitor.

Solution-Processed Graphene/MnO 2 Nanostructured Textiles for High-Performance Electrochemical Capacitors

KAUST Repository

Yu, Guihua

2011-07-13

Large scale energy storage system with low cost, high power, and long cycle life is crucial for addressing the energy problem when connected with renewable energy production. To realize grid-scale applications of the energy storage devices, there remain several key issues including the development of low-cost, high-performance materials that are environmentally friendly and compatible with low-temperature and large-scale processing. In this report, we demonstrate that solution-exfoliated graphene nanosheets (∼5 nm thickness) can be conformably coated from solution on three-dimensional, porous textiles support structures for high loading of active electrode materials and to facilitate the access of electrolytes to those materials. With further controlled electrodeposition of pseudocapacitive MnO2 nanomaterials, the hybrid graphene/MnO2-based textile yields high-capacitance performance with specific capacitance up to 315 F/g achieved. Moreover, we have successfully fabricated asymmetric electrochemical capacitors with graphene/MnO 2-textile as the positive electrode and single-walled carbon nanotubes (SWNTs)-textile as the negative electrode in an aqueous Na 2SO4 electrolyte solution. These devices exhibit promising characteristics with a maximum power density of 110 kW/kg, an energy density of 12.5 Wh/kg, and excellent cycling performance of ∼95% capacitance retention over 5000 cycles. Such low-cost, high-performance energy textiles based on solution-processed graphene/MnO2 hierarchical nanostructures offer great promise in large-scale energy storage device applications. © 2011 American Chemical Society.

Impedance measurement and modelling of super-capacitors for railway applications

Energy Technology Data Exchange (ETDEWEB)

Hammar, A.; Chabas, J. [Societe Nationale des Chemins de fer Francais (SNCF), Dir. de la Recherche, 75 - Paris (France); Coquery, G.; Lallemand, R. [Institut National de Recherche sur les Transports et leur Securite (INRETS), Lab. des Technologies Nouvelles, 94 - Arcueil (France); Rojat, G.; Venet, P. [Lyon-1 Univ. Claude Bernard, CEGELY, 69 - Villeurbanne (France)

2004-07-01

Railways and electrical traction systems require high power rates to achieve their operating performances. Systems of power supply based on super-capacitors should offer high power density along with good energy efficiency and expected operating safety. We investigate general behaviours of super-capacitors with two powerful methods of analysis. The first is constant charge/discharge current at high level value (500 A), the second is impedance spectroscopy which leads to the acquisition of a set of parameters that are considered sufficient to describe general properties of super-capacitor, in particular the state of health and the available energy in any operating conditions. An electrical circuit model is defined for super-capacitors based on activated carbon and organic electrolyte. It takes into account the dependence of super-capacitor to voltage and current. The mixture of data of the two methods permits to obtain a representative model for power applications. Matlab/Simulink simulations are shown to verify the validity of the model. (authors)

Improving wind power quality with energy storage

DEFF Research Database (Denmark)

Rasmussen, Claus Nygaard

2009-01-01

The results of simulation of the influence of energy storage on wind power quality are presented. Simulations are done using a mathematical model of energy storage. Results show the relation between storage power and energy, and the obtained increase in minimum available power from the combination...... of wind and storage. The introduction of storage enables smoothening of wind power on a timescale proportional to the storage energy. Storage does not provide availability of wind power at all times, but allows for a certain fraction of average power in a given timeframe to be available with high...... probability. The amount of storage capacity necessary for significant wind power quality improvement in a given period is found to be 20 to 40% of the energy produced in that period. The necessary power is found to be 80 to 100% of the average power of the period....

Research on the Orientation and Application of Distributed Energy Storage in Energy Internet

Science.gov (United States)

Zeng, Ming; Zhou, Pengcheng; Li, Ran; Zhou, Jingjing; Chen, Tao; Li, Zhe

2018-01-01

Energy storage is indispensable resources to achieve a high proportion of new energy power consumption in electric power system. As an important support to energy Internet, energy storage system can achieve a variety of energy integration operation to ensure maximum energy efficiency. In this paper, firstly, the SWOT analysis method is used to express the internal and external advantages and disadvantages of distributed energy storage participating in the energy Internet. Secondly, the function orientation of distributed energy storage in energy Internet is studied, based on which the application modes of distributed energy storage in virtual power plant, community energy storage and auxiliary services are deeply studied. Finally, this paper puts forward the development strategy of distributed energy storage which is suitable for the development of China’s energy Internet, and summarizes and prospects the application of distributed energy storage system.

Split-phase motor running as capacitor starts motor and as capacitor run motor

Directory of Open Access Journals (Sweden)

Yahaya Asizehi ENESI

2016-07-01

Full Text Available In this paper, the input parameters of a single phase split-phase induction motor is taken to investigate and to study the output performance characteristics of capacitor start and capacitor run induction motor. The value of these input parameters are used in the design characteristics of capacitor run and capacitor start motor with each motor connected to rated or standard capacitor in series with auxiliary winding or starting winding respectively for the normal operational condition. The magnitude of capacitor that will develop maximum torque in capacitor start motor and capacitor run motor are investigated and determined by simulation. Each of these capacitors is connected to the auxiliary winding of split-phase motor thereby transforming it into capacitor start or capacitor run motor. The starting current and starting torque of the split-phase motor (SPM, capacitor run motor (CRM and capacitor star motor (CSM are compared for their suitability in their operational performance and applications.

Storage of energies - Translating potential into actions

International Nuclear Information System (INIS)

Signoret, Stephane; Mary, Olivier; Petitot, Pauline; Dejeu, Mathieu; De Santis, Audrey

2015-01-01

In this set of articles, a first one evokes issues discussed during a colloquium held in Paris by the European association for storage of energy, the possibilities mentioned about energy storage development in the French bill project for energy transition, and the importance of non-interconnected areas in the development of energy storage. A second article proposes an overview of developments and advances in energy storage in California which adopted suitable laws. The German situation is then briefly described: needs are still to be defined and a road map has been published in 2014, as technologies are expensive and the legal framework is still complex. The next article outlines the conditions of development of the power-to-gas sector (as a process of valorisation of excess electricity). An article gives an overview of technological developments in the field of electrochemical energy storage (batteries). The results of the PEPS study (a study on the potential of energy storage) in Europe are commented. An interview with a member of the French BRGM (Bureau of Mines) outlines the major role which underground storage could play in energy transition. The Seti project for an intelligent thermal energy storage and a better use of renewable energies is then presented. An article comments how to use foodstuff cold to make consumption cut-offs. A last article comments how superconductors could be used in the future for batteries. Few examples are briefly presented: a molten salt-based storage by Areva, a local production of green hydrogen in France, an innovating project of solar energy storage in Switzerland, and the Toucan solar plant in French Guyana

Matching Properties of Femtofarad and Sub-Femtofarad MOM Capacitors

KAUST Repository

Omran, Hesham

2016-04-21

Small metal-oxide-metal (MOM) capacitors are essential to energy-efficient mixed-signal integrated circuit design. However, only few reports discuss their matching properties based on large sets of measured data. In this paper, we report matching properties of femtofarad and sub-femtofarad MOM vertical-field parallel-plate capacitors and lateral-field fringing capacitors. We study the effect of both the finger-length and finger-spacing on the mismatch of lateral-field capacitors. In addition, we compare the matching properties and the area efficiency of vertical-field and lateral-field capacitors. We use direct mismatch measurement technique, and we illustrate its feasibility using experimental measurements and Monte Carlo simulations. The test-chips are fabricated in a 0.18 \\\\mutext{m} CMOS process. A large number of test structures is characterized (4800 test structures), which improves the statistical reliability of the extracted mismatch information. Despite conventional wisdom, extensive measurements show that vertical-field and lateral-field MOM capacitors have the same matching properties when the actual capacitor area is considered. Measurements show that the mismatch depends on the capacitor area but not on the spacing; thus, for a given mismatch specification, the lateral-field MOM capacitor can have arbitrarily small capacitance by increasing the spacing between the capacitor fingers, at the expense of increased chip area.

Matching Properties of Femtofarad and Sub-Femtofarad MOM Capacitors

KAUST Repository

Omran, Hesham; Alahmadi, Hamzah; Salama, Khaled N.

2016-01-01

Small metal-oxide-metal (MOM) capacitors are essential to energy-efficient mixed-signal integrated circuit design. However, only few reports discuss their matching properties based on large sets of measured data. In this paper, we report matching properties of femtofarad and sub-femtofarad MOM vertical-field parallel-plate capacitors and lateral-field fringing capacitors. We study the effect of both the finger-length and finger-spacing on the mismatch of lateral-field capacitors. In addition, we compare the matching properties and the area efficiency of vertical-field and lateral-field capacitors. We use direct mismatch measurement technique, and we illustrate its feasibility using experimental measurements and Monte Carlo simulations. The test-chips are fabricated in a 0.18 \\mutext{m} CMOS process. A large number of test structures is characterized (4800 test structures), which improves the statistical reliability of the extracted mismatch information. Despite conventional wisdom, extensive measurements show that vertical-field and lateral-field MOM capacitors have the same matching properties when the actual capacitor area is considered. Measurements show that the mismatch depends on the capacitor area but not on the spacing; thus, for a given mismatch specification, the lateral-field MOM capacitor can have arbitrarily small capacitance by increasing the spacing between the capacitor fingers, at the expense of increased chip area.

Southern company energy storage study :

Energy Technology Data Exchange (ETDEWEB)

Ellison, James; Bhatnagar, Dhruv; Black, Clifton; Jenkins, Kip

2013-03-01

This study evaluates the business case for additional bulk electric energy storage in the Southern Company service territory for the year 2020. The model was used to examine how system operations are likely to change as additional storage is added. The storage resources were allowed to provide energy time shift, regulation reserve, and spinning reserve services. Several storage facilities, including pumped hydroelectric systems, flywheels, and bulk-scale batteries, were considered. These scenarios were tested against a range of sensitivities: three different natural gas price assumptions, a 15% decrease in coal-fired generation capacity, and a high renewable penetration (10% of total generation from wind energy). Only in the elevated natural gas price sensitivities did some of the additional bulk-scale storage projects appear justifiable on the basis of projected production cost savings. Enabling existing peak shaving hydroelectric plants to provide regulation and spinning reserve, however, is likely to provide savings that justify the project cost even at anticipated natural gas price levels. Transmission and distribution applications of storage were not examined in this study. Allowing new storage facilities to serve both bulk grid and transmission/distribution-level needs may provide for increased benefit streams, and thus make a stronger business case for additional storage.

Reliability Evaluation of Power Capacitors in a Wind Turbine System

DEFF Research Database (Denmark)

Zhou, Dao; Blaabjerg, Frede

2018-01-01

With the increasing penetration of wind power, reliable and cost-effective wind energy production is of more and more importance. The doubly-fed induction generator based partial-scale wind power converter is still dominating in the existing wind farms. In this paper, the reliability assessment...... block diagram is used to bridge the gap between the Weibull distribution based component-level individual capacitor and the capacitor bank. A case study of a 2 MW wind power converter shows that the lifetime is significantly reduced from the individual capacitor to the capacitor bank. Besides, the dc...... of power capacitors is studied considering the annual mission profile. According to an electro-thermal stress evaluation, the time-to-failure distribution of both the dc-link capacitor and ac-side filter capacitor is detailed investigated. Aiming for the systemlevel reliability analysis, a reliability...

Superconducting magnetic energy storage, possibilities and limitations

International Nuclear Information System (INIS)

Bace, M.; Knapp, V.

1981-01-01

Energy storage is of great importance for the exploitation of new energy sources as well as for the better utilisation of conventional ones. Several proposals in recent years have suggested that superconducting magnets could be used as energy storage in large electricity networks. It is a purpose of this note to point out that the requirements which have to be met by energy storage in a large electricity network place serious limitation on the possible use of superconducting energy storage. (author)

Superconducting magnetic energy storage

International Nuclear Information System (INIS)

Rogers, J.D.

1976-01-01

Fusion power production requires energy storage and transfer on short time scales to create confining magnetic fields and for heating plasmas. The theta-pinch Scyllac Fusion Test Reactor (SFTR) requires 480 MJ of energy to drive the 5-T compression field with a 0.7-ms rise time. Tokamak Experimental Power Reactors (EPR) require 1 to 2 GJ of energy with a 1 to 2-s rise time for plasma ohmic heating. The design, development, and testing of four 300-kJ energy storage coils to satisfy the SFTR needs are described. Potential rotating machinery and homopolar energy systems for both the Reference Theta-Pinch Reactor (RTPR) and tokamak ohmic-heating are presented

An automatic device for charging a storage battery

Energy Technology Data Exchange (ETDEWEB)

Pasyukov, A A

1984-01-01

The purpose of the invention is to increase the service life of storage batteries (AB) through ensuring automatic protection of the device from overloads with short circuits (KZ) and from incorrect switching polarity of the storage batteries. The device contains a transformer, a rectifier, a smoothing capacitor, a trigger capacitor, a charge current control transistor, a controllable transistor, a shielding transistor, two resistors, a diode, a resistor and a voltage divider, another resistor, a reference voltage stabilitron, a resistor and another diode and the storage battery.

Li-Ion, Ultra-capacitor Based Hybrid Energy Module

National Research Council Canada - National Science Library

Daboussi, Zaher; Paryani, Anil; Khalil, Gus; Catherino, Henry; Gargies, Sonya

2007-01-01

Ultra-capacitors in multi kilo-farad ranges are now starting to be considered as alternatives or complimentary to batteries for products ranging from toys to hybrid vehicles as well as for space applications...