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Sample records for energetic combustion devices

  1. Fast Reacting Nano Composite Energetic Materials: Synthesis and Combustion Characterization

    Science.gov (United States)

    2015-08-24

    Office P.O. Box 12211 Research Triangle Park, NC 27709-2211 aluminum combustion; energetic materials; fluorine ; reaction kinetics; fluoropolymers; self...techniques will be examined to quantify combustion performance. All of this information will provide a basis for future research and applications involving... fluorine content in the acids and their structural differences contribute to difference in burn velocity. The mechanisms controlling reactivity will be

  2. Practical Multi-Disciplinary Analysis Tools for Combustion Devices Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The use of multidisciplinary analysis (MDA) techniques for combustion device environment prediction, including complex fluid mixing phenomena, is now becoming...

  3. Combustion aspects of the reapplication of energetic materials as fuels as a viable demil technology

    Energy Technology Data Exchange (ETDEWEB)

    Baxter, L.; Davis, K.; Sinquefield, S.; Huey, S.; Lipkin, J.; Shah, D.; Ross, J.; Sclippa, G. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility

    1996-05-01

    This investigation addresses the combustion-related aspects of the reapplication of energetic materials as fuels in boilers as an economically viable and environmentally acceptable use of excess energetic materials. The economics of this approach indicate that the revenues from power generation and chemical recovery approximately equal the costs of boiler modification and changes in operation. The primary tradeoff is the cost of desensitizing the fuels against the cost of open burn/open detonation (OB/OD) or other disposal techniques. Two principal combustion-related obstacles to the use of energetic-material-derived fuels are NO{sub x} generation and the behavior of metals. NO{sub x} measurements obtained in this investigation indicate that the nitrated components (nitrocellulose, nitroglycerin, etc.) of energetic materials decompose with NO{sub x} as the primary product. This can lead to high uncontrolled NO{sub x} levels (as high as 2,600 ppm on a 3% O{sub 2} basis for a 5% blend of energetic material in the fuel). NO{sub x} levels are sensitive to local stoichiometry and temperature. The observed trends resemble those common during the combustion of other nitrogen-containing fuels. Implications for NO{sub x} control strategies are discussed. The behavior of inorganic components in energetic materials tested in this investigation could lead to boiler maintenance problems such as deposition, grate failure, and bed agglomeration. The root cause of the problem is the potentially extreme temperature generated during metal combustion. Implications for furnace selection and operation are discussed.

  4. Combustion performance of porous silicon-based energetic composites

    Energy Technology Data Exchange (ETDEWEB)

    Mason, Benjamin Aaron [Los Alamos National Laboratory; Son, Steve F [Los Alamos National Laboratory; Asay, Blaine W [Los Alamos National Laboratory; Cho, Kevin Y [PURDUE UNIV

    2009-01-01

    The combustion performance of oxidizer filled porous silicon(PSi) was studied. PSi samples with diameters of 2.54 cm were fabricated by electrochemical etching. The % porosity of the samples ranged from 55 to 82%. The samples were cut into 3-5 mm strips and filled with the oxidizers NaClO{sub 4} x 1H{sub 2}O, Ca(ClO{sub 4}){sub 2} x 4H{sub 2}O, S and perfluoropolyether (PFPE). The filled PSi was then burned by igniting the sample with a hot NiChrome{trademark} wire. The burns were recorded using high speed photography from which bring rates were calculated. That burning rates showed a strong dependency on quality of the oxidizer loading. The % porosity did not appear to have a direct affect on the burning rates for those studied. PSi loaded with NaClO{sub 4} x 1H{sub 2}O produced burning rates that ranged from 216-349 cm/s. PSi loaded with Ca(ClO{sub 4}){sub x}x 4 H{sub 2}O had burning rates of 154-285 cm/s. An S filled PSi sample burned a rate of 16 to 290 cm/s, and perfluoropolyether loaded PSi burned at a rate of 1.4 cm/s.

  5. Specifics of phytomass combustion in small experimental device

    Directory of Open Access Journals (Sweden)

    Lenhard Richard

    2015-01-01

    Full Text Available A wood pellet combustion carries out with high efficiency and comfort in modern pellet boilers. These facts help to increase the amount of installed pellet boilers in households. The combustion process quality depends besides the combustion conditions also on the fuel quality. The wood pellets, which don`t contain the bark and branches represent the highest quality. Because of growing pellet demand, an herbal biomass (phytomass, which is usually an agricultural by-product becomes economically attractive for pellet production. Although the phytomass has the net calorific value relatively slightly lower than the wood biomass, it is often significantly worse in view of the combustion process and an emission production. The combustion of phytomass pellets causes various difficulties in small heat sources, mainly due to a sintering of fuel residues. We want to avoid the ash sintering by a lowering of temperature in the combustion chamber below the ash sintering temperature of phytomass via the modification of a burner design. For research of the phytomass combustion process in the small boilers is constructed the experimental combustion device. There will investigate the impact of cooling intensity of the combustion chamber on the combustion process and emissions. Arising specific requirements from the measurement will be the basis for the design of the pellet burner and for the setting of operating parameters to the trouble-free phytomass combustion was guaranteed.

  6. Deep energetic trap states in organic photovoltaic devices

    KAUST Repository

    Shuttle, Christopher G.

    2011-11-23

    The nature of energetic disorder in organic semiconductors is poorly understood. In photovoltaics, energetic disorder leads to reductions in the open circuit voltage and contributes to other loss processes. In this work, three independent optoelectronic methods were used to determine the long-lived carrier populations in a high efficiency N-alkylthieno[3,4-c]pyrrole-4,6-dione (TPD) based polymer: fullerene solar cell. In the TPD co-polymer, all methods indicate the presence of a long-lived carrier population of ∼ 10 15 cm -3 on timescales ≤100 μs. Additionally, the behavior of these photovoltaic devices under optical bias is consistent with deep energetic lying trap states. Comparative measurements were also performed on high efficiency poly-3-hexylthiophene (P3HT): fullerene solar cells; however a similar long-lived carrier population was not observed. This observation is consistent with a higher acceptor concentration (doping) in P3HT than in the TPD-based copolymer. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Enhancement of hybrid rocket combustion performance using nano-sized energetic particles

    Science.gov (United States)

    Risha, Grant Alexander

    Until now, the regression rate of classical hybrid rocket engines have typically been an order of magnitude lower than solid propellant motors; thus, hybrids require a relatively large fuel surface area for a given thrust level. In addition to low linear regression rates, relatively low combustion efficiency (87 to 92%), low mass burning rates, varying oxidizer-to-fuel ratio during operation, and lack of scaling laws have been reported. These disadvantages can be ameliorated by introducing nano-sized energetic powder additives into the solid fuel. The addition of nano-sized energetic particles into the solid fuel enhances performance as measured by parameters such as: density specific impulse, mass and linear burning rates, and thrust. Thermophysical properties of the solid fuel such as density, heat of combustion, thermal diffusivity, and thermal conductivity are also enhanced. The types of nano-sized energetic particles used in this study include aluminum, boron, boron carbide, and some Viton-A coated particles. Since the combustion process of solid fuels in a hybrid rocket engine is governed by the mass flux of the oxidizer entering the combustion chamber, the rate-limiting process is the mixing and reacting of the pyrolysis products of the fuel grain with the incoming oxidizer. The overall goal of this research was to determine the relative propulsive and combustion behavior for a family of newly-developed HTPB-based solid-fuel formulations containing various nano-sized energetic particles. Seventeen formulations contained 13% additive by weight, one formulation (SF4) contained 6.5% additive by weight, and one formulation (SF19) contained 5.65% boron by weight. The two hybrid rocket engines which were used in this investigation were the Long Grain Center-Perforated (LGCP) rocket engine and the X-Ray Transparent Casing (XTC) rocket engine. The smaller scale LGCP rocket engine was used to evaluate all of the formulations because conducting experiments using the

  8. Scaling of Performance in Liquid Propellant Rocket Engine Combustion Devices

    Science.gov (United States)

    Hulka, James R.

    2008-01-01

    This paper discusses scaling of combustion and combustion performance in liquid propellant rocket engine combustion devices. In development of new combustors, comparisons are often made between predicted performance in a new combustor and measured performance in another combustor with different geometric and thermodynamic characteristics. Without careful interpretation of some key features, the comparison can be misinterpreted and erroneous information used in the design of the new device. This paper provides a review of this performance comparison, including a brief review of the initial liquid rocket scaling research conducted during the 1950s and 1960s, a review of the typical performance losses encountered and how they scale, a description of the typical scaling procedures used in development programs today, and finally a review of several historical development programs to see what insight they can bring to the questions at hand.

  9. Scaling Techniques for Combustion Device Random Vibration Predictions

    Science.gov (United States)

    Kenny, R. J.; Ferebee, R. C.; Duvall, L. D.

    2016-01-01

    This work presents compares scaling techniques that can be used for prediction of combustion device component random vibration levels with excitation due to the internal combustion dynamics. Acceleration and unsteady dynamic pressure data from multiple component test programs are compared and normalized per the two scaling approaches reviewed. Two scaling technique are reviewed and compared against the collected component test data. The first technique is an existing approach developed by Barrett, and the second technique is an updated approach new to this work. Results from utilizing both techniques are presented and recommendations about future component random vibration prediction approaches are given.

  10. Gas flow control device for internal combustion engines

    Energy Technology Data Exchange (ETDEWEB)

    Matesic, A.; Castella, J.P.

    1996-08-29

    A gas flow control device for internal combustion engines, consisting of a single or double linearly movable member for controlling the flow rate of air in an intake duct, followed by a throttling mechanism for varying the cross-section of the duct. Both these devices may be common to all cylinders or provided plurally. Said including petrol engines or unsupercharged or turbocharged diesel engines, but is particularly suitable for four-stroke fuel ignition engines, i.e. those without a carburettor. (author)

  11. Device and method for determining the combustion value of a fuel

    NARCIS (Netherlands)

    Lötters, Joost Conrad; Lammerink, Theodorus S.J.; Wiegerink, Remco J.; Mouris, Albertus Johannes; Pap, Marco Gabor; de Boer, Meint J.; Sanders, Remco G.P.

    2012-01-01

    The invention relates to a device (1) for determining the combustion value of a fuel. The device (1) comprises a fuel inlet (40) for supplying the fuel to be measured to the device (1). A gas inlet (50) is provided for supplying an oxygen-containing gas to the device (1). The device (1) further

  12. Variable compression ratio device for internal combustion engine

    Science.gov (United States)

    Maloney, Ronald P.; Faletti, James J.

    2004-03-23

    An internal combustion engine, particularly suitable for use in a work machine, is provided with a combustion cylinder, a cylinder head at an end of the combustion cylinder and a primary piston reciprocally disposed within the combustion cylinder. The cylinder head includes a secondary cylinder and a secondary piston reciprocally disposed within the secondary cylinder. An actuator is coupled with the secondary piston for controlling the position of the secondary piston dependent upon the position of the primary piston. A communication port establishes fluid flow communication between the combustion cylinder and the secondary cylinder.

  13. Ventricular Energetics in Pediatric Left Ventricular Assist Device Patients: A Retrospective Clinical Study.

    Science.gov (United States)

    Di Molfetta, Arianna; Ferrari, Gianfranco; Iacobelli, Roberta; Filippelli, Sergio; Di Chiara, Luca; Guccione, Paolo; Amodeo, Antonio

    The aim of this study is to estimate the trend of right and left energetic parameters in left ventricular assist device (LVAD) pediatric patients. Echocardiographic data were retrospectively collected at the baseline, in the acute phase after and at the monthly follow-ups till the LVAD explantation to estimate left and right ventricular energetic parameters. A significant relationship between the left and right ventricular energetic parameter trends was found along all the study period. Left ventricular end-systolic pressure-volume relationship improved till the follow-up of 2 months and then progressively decreases. Left arteroventricular coupling decreases after the LVAD, and right arteroventricular coupling decreases at the short-term follow-up. Left ventricular external work, potential energy, and pressure-volume area decrease at the short-term follow-up and then increase progressively. Right ventricular external work, potential energy, and pressure-volume area increase after the LVAD implantation. Left (right) cardiac mechanical efficiency is improved (worsened) by the LVAD. Energetic variables show that the LVAD benefits could decrease over time. A continuous and patient tailored LVAD setting could contribute to prolong LVAD benefits. The introduction of energetic parameters could lead to a more complete evaluation of LVAD patients' outcome which is a multiparametric process.

  14. Operation Evaluation Method for Marine Turbine Combustion Engines in Terms of Energetics

    Directory of Open Access Journals (Sweden)

    Dzida Marek

    2016-12-01

    Full Text Available An evaluation proposal (quantitative determination of any combustion turbine engine operation has been presented, wherein the impact energy occurs at a given time due to Energy conversion. The fact has been taken into account that in this type of internal combustion engines the energy conversion occurs first in the combustion chambers and in the spaces between the blade of the turbine engine. It was assumed that in the combustion chambers occurs a conversion of chemical energy contained in the fuel-air mixture to the internal energy of the produced exhaust gases. This form of energy conversion has been called heat. It was also assumed that in the spaces between the blades of the rotor turbine, a replacement occurs of part of the internal energy of the exhaust gas, which is their thermal energy into kinetic energy conversion of its rotation. This form of energy conversion has been called the work. Operation of the combustion engine has been thus interpreted as a transmission of power receivers in a predetermined time when there the processing and transfer in the form (means of work and heat occurs. Valuing the operation of this type of internal combustion engines, proposed by the authors of this article, is to determine their operation using physical size, which has a numerical value and a unit of measurement called joule-second [joule x second]. Operation of the combustion turbine engine resulting in the performance of the turbine rotor work has been presented, taking into account the fact that the impeller shaft is connected to the receiver, which may be a generator (in the case of one-shaft engine or a propeller of the ship (in the case of two or three shaft engine.

  15. Characterization of Ignition and Combustion Properties of Nanowire-based Energetics

    Science.gov (United States)

    2013-07-23

    We have first investigated the morphology effect on ignition of nanoscale energetic materials. Specifically, we successfully synthesized thermites ...exothermic reaction of the core/shell NWs were similar to those of nanoparticle (NP)-based thermites in terms of magnitude, insensitivity to...equivalence ratios and sensitivity to heating rates. Moreover, the core/shell NW thermites , compared to NP-based thermites , exhibit greatly improved mixing

  16. Pelletizing of fuel blends mixed with lignin for energetic use in small scale combustion units

    Directory of Open Access Journals (Sweden)

    Frank Döhling

    2015-03-01

    Full Text Available As part of future bio-economy concepts technical lignin, by-products derived from the pulp- and paper industry, may be recycled for further utilization. Via a specially developed process the liquid lignin lye can be converted into a solid state. The lignin granules were mixed with a blend of canola straw and peeled oat bran in different proportions (1–2 wt.-% to adjust the characteristics of the mixtures for pelletizing. Combustion tests with the produced pellets were carried out in a small scale combustion unit (25 kW showing that depending on the amount and kind of lignin CO-, SO2- and particulate matter emissions are affected. Through further optimization of fuel mixtures and by means of secondary measures existing emission limits could be complied.

  17. Combustion Dynamics of Biocidal Metal-Based Energetic Components in Turbulent Reactive Flows

    Science.gov (United States)

    2015-11-01

    and Technology, 177(3):485- 511, 2005. 5. W. K. Lewis, C. G. Rumchik, P. B. Broughton , and C. M. Lindsay. Time-resolved spectroscopic studies of...Mamen, A. Higgins, T. Bazyn, N. Glumac, and H. Krier. Emission spectroscopy of flame fronts in aluminum suspensions . Proceedings of the Combustion...absorptions in exploding bridge wires (EBW). Finally, the diagnostic is used to obtain spectra from diatomic species of metal-fluorocarbon reactions (MgF

  18. SIZE ANALYSIS OF SOLID PARTICLES AT THE EXPERIMENTAL DEVICE FOR MULTI-STAGE BIOMASS COMBUSTION

    Directory of Open Access Journals (Sweden)

    Michaela Hrnčířová

    2014-02-01

    Full Text Available This paper presents the results of an analysis of ash content particles produced in biomass combustion at an experimental device. The main parts of the device are: the water heater, the gasifying chamber, the air preheater, and the fuel feeder. This device can be modified for combustion in an oxygen-enriched atmosphere. Sawdust and wood chips were used as fuel, and were laid loosely into the device. Ash specimens were extracted from various parts of the device. For the measurements themselves, we used the Analysette 22 MicroTec Plus universal laser diffraction device manufactured by the Fritch Company, in the size range from 0.08 μm to 2000 μm. The device utilizes laser diffraction for particle size analysis.

  19. Combustion of porous energetic materials in the merged-flame regime

    Energy Technology Data Exchange (ETDEWEB)

    Margolis, S.B. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Williams, F.A.; Telengator, A.M. [Univ. of California, San Diego, La Jolla, CA (United States). Dept. of Applied Mechanics and Engineering Sciences

    1996-02-01

    The structure and burning rate of an unconfined deflagration propagating through a porous energetic material is analyzed in the limit of merged condensed and gas-phase reaction zones. A global two-step reaction mechanism, applicable to certain types of degraded nitramine propellants and consisting of sequential condensed and gaseous steps, is postulated. Taking into account important effects due to multiphase flow and exploiting the limit of large activation energies, a theoretical analysis based on activation energy asymptotics leads to explicit formulas for the deflagration velocity in a specifically identified regime that is consistent with the merged-flame assumption. The results clearly indicate the influences of two-phase flow and the multiphase, multi-step chemistry on the deflagration structure and the burning rate, and define conditions that support the intrusion of the primary gas flame into the two-phase condensed decomposition region at the propellant surface.

  20. Combustion

    CERN Document Server

    Glassman, Irvin

    1987-01-01

    Combustion, Second Edition focuses on the underlying principles of combustion and covers topics ranging from chemical thermodynamics and flame temperatures to chemical kinetics, detonation, ignition, and oxidation characteristics of fuels. Diffusion flames, flame phenomena in premixed combustible gases, and combustion of nonvolatile fuels are also discussed. This book consists of nine chapters and begins by introducing the reader to heats of reaction and formation, free energy and the equilibrium constants, and flame temperature calculations. The next chapter explores the rates of reactio

  1. Altered combustion characteristics of metallized energetics due to stable secondary material inclusion

    Science.gov (United States)

    Terry, Brandon C.

    Though metals and metalloids have been widely considered as reactive fuels, the ability to tune their ignition and combustion characteristics remains challenging. One means to accomplish this may be through low-level inclusion of secondary materials into the metallized fuel. While there are several potential methods to stably introduce secondary inclusion materials, this work focuses on the use of mechanical activation (MA) and metal alloys. Recent work has shown that low-level inclusion of fluoropolymers into aluminum particles can have a substantial effect on their combustion characteristics. The reflected shock ignition of mechanically activated aluminum/polytetrafluoroethylene (MA Al/PTFE) is compared to a physical mixture (PM) of Al/PTFE, neat spherical aluminum, and flake aluminum. It was found that the powders with higher specific surface areas ignited faster than the spherical particles of the same size, and had ignition delay times comparable to agglomerates of aluminum particles that were two orders of magnitude smaller in size. Flake aluminum powder had the same ignition delay as MA Al/PTFE, indicating that any initial aluminum/fluoropolymer reactions did not yield an earlier onset of aluminum oxidation. However, MA Al/PTFE did have a shorter total burn time. The PM of Al/PTFE powder had a shorter ignition delay than neat spherical aluminum due to the rapid decomposition of PTFE into reactive fluorocarbon compounds, but the subsequent fluorocarbon reactions also created a secondary luminosity profile that significantly increased the total burn time of the system. The explosive shock ignition of aluminum and aluminum-silicon eutectic alloy compacts was evaluated with and without polymer inclusions. A statistical analysis was completed, investigating the effects of: detonation train orientation (into or not into a hard surface); the high explosive driver; whether the metal/polymer system is mechanically activated; particle size; particle morphology

  2. Energetic study of combustion instabilities and genetic optimisation of chemical kinetics; Etude energetique des instabilites thermo-acoustiques et optimisation genetique des cinetiques reduites

    Energy Technology Data Exchange (ETDEWEB)

    Martin, Ch.E.

    2005-12-15

    Gas turbine burners are now widely operated in lean premixed combustion mode. This technology has been introduced in order to limit pollutants emissions (especially the NO{sub x}), and thus comply with environment norms. Nevertheless, the use of lean premixed combustion decreases the stability margin of the flames. The flames are then more prone to be disturbed by flow disturbances. Combustion instabilities are then a major problem of concern for modern gas turbine conception. Some active control systems have been used to ensure stability of gas turbines retro-fitted to lean premixed combustion. The current generation of gas turbines aims to get rid of these control devices getting stability by a proper design. To do so, precise and adapted numerical tools are needed even it is impossible at the moment to guarantee the absolute stability of a combustion chamber at the design stage. Simulation tools for unsteady combustion are now able to compute the whole combustion chamber. Its intrinsic precision, allows the Large Eddy Simulation (LES) to take into account numerous phenomena involved in combustion instabilities. Chemical modelling is an important element for the precision of reactive LES. This study includes the description of an optimisation tools for the reduced chemical kinetics. The capacity of the LES to capture combustion instabilities in gas turbine chamber is also demonstrated. The acoustic energy analysis points out that the boundary impedances of the combustion systems are of prime importance for their stability. (author)

  3. Linking molecular level chemistry to macroscopic combustion behavior for nano-energetic materials with halogen containing oxides.

    Science.gov (United States)

    Farley, Cory W; Pantoya, Michelle L; Losada, Martin; Chaudhuri, Santanu

    2013-08-21

    Coupling molecular scale reaction kinetics with macroscopic combustion behavior is critical to understanding the influences of intermediate chemistry on energy propagation, yet bridging this multi-scale gap is challenging. This study integrates ab initio quantum chemical calculations and condensed phase density functional theory to elucidate factors contributing to experimentally measured high flame speeds (i.e., >900 m∕s) associated with halogen based energetic composites, such as aluminum (Al) and iodine pentoxide (I2O5). Experiments show a direct correlation between apparent activation energy and flame speed suggesting that flame speed is directly influenced by chemical kinetics. Toward this end, the first principle simulations resolve key exothermic surface and intermediate chemistries contributing toward the kinetics that promote high flame speeds. Linking molecular level exothermicity to macroscopic experimental investigations provides insight into the unique role of the alumina oxide shell passivating aluminum particles. In the case of Al reacting with I2O5, the alumina shell promotes exothermic surface chemistries that reduce activation energy and increase flame speed. This finding is in contrast to Al reaction with metal oxides that show the alumina shell does not participate exothermically in the reaction.

  4. Transition metal oxides for organic electronics: energetics, device physics and applications.

    Science.gov (United States)

    Meyer, Jens; Hamwi, Sami; Kröger, Michael; Kowalsky, Wolfgang; Riedl, Thomas; Kahn, Antoine

    2012-10-23

    During the last few years, transition metal oxides (TMO) such as molybdenum tri-oxide (MoO(3) ), vanadium pent-oxide (V(2) O(5) ) or tungsten tri-oxide (WO(3) ) have been extensively studied because of their exceptional electronic properties for charge injection and extraction in organic electronic devices. These unique properties have led to the performance enhancement of several types of devices and to a variety of novel applications. TMOs have been used to realize efficient and long-term stable p-type doping of wide band gap organic materials, charge-generation junctions for stacked organic light emitting diodes (OLED), sputtering buffer layers for semi-transparent devices, and organic photovoltaic (OPV) cells with improved charge extraction, enhanced power conversion efficiency and substantially improved long term stability. Energetics in general play a key role in advancing device structure and performance in organic electronics; however, the literature provides a very inconsistent picture of the electronic structure of TMOs and the resulting interpretation of their role as functional constituents in organic electronics. With this review we intend to clarify some of the existing misconceptions. An overview of TMO-based device architectures ranging from transparent OLEDs to tandem OPV cells is also given. Various TMO film deposition methods are reviewed, addressing vacuum evaporation and recent approaches for solution-based processing. The specific properties of the resulting materials and their role as functional layers in organic devices are discussed. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Problematic issues of air protection during thermal processes related to the energetic uses of sewage sludge and other waste. Case study: Co-combustion in peaking power plant.

    Science.gov (United States)

    Hroncová, Emília; Ladomerský, Juraj; Musil, Juraj

    2017-08-19

    Currently, it is necessary to deal with issues related to the emissions as there is a constantly increasing interest in combusting sludge from sewage treatment plants in the boilers for wood. An analysis of the energetic importance of the combustion of sewage sludge has already been carried out, but the effects of various treatments of the sludge are not always clear, e.g. composting and subsequent combustion to the air pollution. Investments in other thermal processes of energetic utilisation of sewage sludge and organic waste are not always successfully implemented. The objective of this paper is to point out some problematic cases for acceptance of thermal processes related to energetic use of waste in terms of the air protection. The other aim is to mention the experience with solutions of such issues in Slovakia. There are mentioned first results of the operational validation experiments during the energy generation in circulating fluidized bed boiler in peaking power plant (Power 110MW) with the addition of the so-called alternative fuel based on wood and sewage sludge to the main fuel - black coal (anthracite). And there has already been achieved the highest share of 12.4%w. (dry matter) of sewage sludge in form of compost in blend with black coal, which is technologically viable. Moreover analyzed the problems of the authorization and operation of the co-combustion of sewage sludge and of combustion of products of various kinds of pyrolysis waste - pyrolysis gas and pyrolysis oil are analyzed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. Control device for controlling the fuel-air ratio of an internal combustion engine

    Energy Technology Data Exchange (ETDEWEB)

    Rado, W.G.

    1982-04-08

    The invention deals with a control device for controlling the fuel-air ratio of a combustion engine. The oxygen content in the exhaust gas is measured in certain time intervals thereby determining whether a pre-determined number of measurements shows the result ''lean'' or ''rich'', the control device adjusts the mixture according to the measured results if necessary.

  7. Method and device for diagnosing and controlling combustion instabilities in internal combustion engines operating in or transitioning to homogeneous charge combustion ignition mode

    Science.gov (United States)

    Wagner, Robert M [Knoxville, TN; Daw, Charles S [Knoxville, TN; Green, Johney B [Knoxville, TN; Edwards, Kevin D [Knoxville, TN

    2008-10-07

    This invention is a method of achieving stable, optimal mixtures of HCCI and SI in practical gasoline internal combustion engines comprising the steps of: characterizing the combustion process based on combustion process measurements, determining the ratio of conventional and HCCI combustion, determining the trajectory (sequence) of states for consecutive combustion processes, and determining subsequent combustion process modifications using said information to steer the engine combustion toward desired behavior.

  8. Devices and methods for in-situ combustion ignition

    Energy Technology Data Exchange (ETDEWEB)

    Shallcross, D C

    1989-10-01

    One of the most important tasks during a fireflood is to ensure the ignition of the oil-bearing stratum efficiently and safely. Many different devices have been developed and employed to achieve this aim. The target zone may ignite spontaneously upon injection of an oxygen-containing gas without the aid of special equipment. Alternatively, ignition may be hastened or enhanced by the use of gas-fired downhole burners, catalytic heaters, electric downhole heaters, or other, chemical means. Other methods involve increasing the reactivity of the formation contents by doping the stratum with compounds that ignite and burn more readily than the reservoir oil. This report surveys the range of ignition methods and devices that have been developed and applied in the field. Not only are successful ignition systems discussed, but also those designs that failed to ignite a formation. In discussing the various techniques, factors considered include reliability, specialized equipment and material requirements, and safety. Another consideration is whether a system or device may be easily reused if ignition is not successful on the first attempt. The use of oxidizing gases than air is also discussed. 108 refs., 3 tabs.

  9. The energetic behaviour of single heating devices; Der Energieaufwand der Nutzenuebergabe bei Einzelheizgeraeten

    Energy Technology Data Exchange (ETDEWEB)

    Dipper, J.

    2002-07-01

    In this thesis the energetic behaviour of single heating devices is analysed. The combined simulation of building and heating systems is used as tool for the calculations. Within the simulations the building model is varied in regard to the standard of insulation, the massiness and the glazing fraction of the cladding. The utilization is reproduced by different set point profiles of the room temperature and different profiles of the internal loads. The effort figures are calculated for an electrical storage heating system, an electrical direct heating device and a tiled stove. Mathematical models which exist already partially are extended and calibrated with measurements. For the electrical direct heating device and the tiled stove new models are generated and compared with values from the literature. The result of the calculations is the total effort figure e{sub ges} which represents the ratio of effort to the reference requirement. It is shown how the energy effort depends on the behaviour of the occupants. (orig.) [German] In der vorliegenden Arbeit wird das energetische Verhalten von Einzelheizgeraeten untersucht. Als Werkzeug wird die gekoppelte Simulation von Gebaeude und Anlage eingesetzt, mit der Jahressimulationen durchgefuehrt werden. Beim Gebaeudemodell werden dabei der Daemmstandard (ALTBAU, WSV95 und ESV), die Bauschwere (leicht und schwer) sowie der Fensterflaechenanteil (20%, 40% und 60% Anteil an der Fassadenflaeche) variiert. Die Nutzung wird ueber unterschiedliche Solltemperaturprofile und Innenlastprofile abgebildet. Fuer ein Elektrospeichergeraet, ein elektrisches Direktheizgeraet und einen Kachelofen wird der Energieaufwand der Nutzuebergabe berechnet. Teilweise bestehende Rechenmodelle werden erweitert und durch Messungen kalibriert. Fuer das Direktheizgeraet und den Kachelofen werden neue Rechenmodelle erstellt und die Ergebnisse mit Literaturwerten verglichen. Ergebnis der Simulationsrechnungen ist die Gesamtaufwandszahl e{sub ges}, die das

  10. High-Resolution Photoionization, Photoelectron and Photodissociation Studies. Determination of Accurate Energetic and Spectroscopic Database for Combustion Radicals and Molecules

    Energy Technology Data Exchange (ETDEWEB)

    Ng, Cheuk-Yiu [Univ. of California, Davis, CA (United States)

    2016-04-25

    The main goal of this research program was to obtain accurate thermochemical and spectroscopic data, such as ionization energies (IEs), 0 K bond dissociation energies, 0 K heats of formation, and spectroscopic constants for radicals and molecules and their ions of relevance to combustion chemistry. Two unique, generally applicable vacuum ultraviolet (VUV) laser photoion-photoelectron apparatuses have been developed in our group, which have used for high-resolution photoionization, photoelectron, and photodissociation studies for many small molecules of combustion relevance.

  11. Challenges in Propellants and Combustion: 100 Years after Nobel

    National Research Council Canada - National Science Library

    Kuo, Kenneth

    1997-01-01

    .... The Topics covered include: chemical kinetics of propellant combustion, environmental considerations in combustion of solid and liquid propellants, commercial application in the combustion of energetic materials, effective...

  12. SILICON CARBIDE MICRO-DEVICES FOR COMBUSTION GAS SENSING UNDER HARSH CONDITIONS

    Energy Technology Data Exchange (ETDEWEB)

    Ruby N. Ghosh; Peter Tobias; Roger G. Tobin

    2004-10-01

    A sensor based on the wide bandgap semiconductor, silicon carbide (SiC), has been developed for the detection of combustion products in power plant environments. The sensor is a catalytic gate field effect device that can detect hydrogen containing species in chemically reactive, high temperature environments. For these capacitive sensors we have determined that the optimum sensor operating point in terms of sensor lifetime and response time is at midgap. Detailed measurements of the oxide leakage current as a function of temperature were performed to investigate the high temperature reliability of the devices. In addition, robust metallization and electrical contacting techniques have been developed for device operation at elevated temperatures. To characterize the time response of the sensor responses in the millisecond range, a conceptually new apparatus has been built. Using laser induced fluorescence imaging techniques we have shown that the gas underneath the sensor can be completely exchanged with a time constant under 1 millisecond. Ultrahigh vacuum studies of the surface chemistry of the platinum gate have shown that sensor deactivation by adsorbed sulfur is a possible problem. Investigations on the chemical removal of sulfur by catalytic oxidation or reduction are continuing.

  13. Numerically Simulated Impact of Gas Prandtl Number and Flow Model on Efficiency of the Machine-less Energetic Separation Device

    Directory of Open Access Journals (Sweden)

    K. S. Egorov

    2015-01-01

    Full Text Available The presented paper regards the influence of one of similarity criteria – the Prandtl number of gas (Pr - on the efficiency of the machine-less energetic separation device (Leontiev pipe, using numerical modeling in ANSYS software. This device, equally as Rank-Hilsch and Hartman-Schprenger pipes, is designed to separate one gas flow into two flows with different temperatures. One flow (supersonic streams out of the pipe with a temperature higher than initial and the other (subsonic flows out with a temperature lower than initial. This direction of energetic separation is true if the Prandtl number is less than 1 that corresponds to gases.The Prandtl number affects the efficiency of running Leontiev pipe indirectly both through a temperature difference on which a temperature recovery factor has an impact and through a thermal conductivity coefficient that shows the impact of heat transfer intensity between gas and solid wall.The Prandtl number range in the course of research was from 0.1 to 0.7. The Prandtl number value equal to 0.7 corresponds to the air or pure gases (for example, inert argon gas. The Prandtl number equal to 0.2 corresponds to the mixtures of inert gases such as helium-xenon.The numerical modeling completed for the supersonic flow with Mach number 2.0 shows that efficiency of the machine-less energetic separation device has been increased approximately 2 times with the Prandtl number decreasing from 0.7 to 0.2. Moreover, for the counter-flow scheme this effect is a little higher due to its larger heat efficiency in comparison with the straight-flow one.Also, the research shows that the main problem for the further increase of the Leontiev pipe efficiency is a small value of thermal conductivity coefficient, which requires an intensification of the heat exchange, especially in the supersonic flow. It can be obtained, for example, by using a system of oblique shock waves in the supersonic channel.

  14. Energetic retrofitting of industrial heat supply systems. Possibilities of enhancing the efficiency and energy conservation at large combustion engineering plants; Energetische Modernisierung industrieller Waermeversorgungssysteme. Moeglichkeiten der Effizienzsteigerung und der Energieeinsparung an grossen feuerungstechnischen Anlagen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-12-15

    In the contribution under consideration, the Deutsche Energie-Agentur GmbH (Berlin, Federal Republic of Germany) reports on an energetic modernization of industrial heat supply systems. Possibilities of an enhancement of the energetic efficiency and energy conservation at large combustion engineering plants are described. After an introduction to this theme, the author of this contribution provides an overview of the optimization of heat supply systems, and reports on the following aspects: Optimisation of the heat demand; energy efficient heat generation; heat recovery; energy efficient conversion technology and generation technology; associate partners for more energy efficiency in industry and commerce; best practice examples.

  15. Silicon Carbide Micro-devices for Combustion Gas Sensing under Harsh Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Ruby Ghosh; Reza Loloee; Roger Tobin

    2008-09-30

    A sensor based on the wide bandgap semiconductor, silicon carbide (SiC), has been developed for the detection of combustion products in power plant environments. The sensor is a catalytic gate field effect device, Pt/SiO{sub 2}/SiC that can detect hydrogen-containing species in chemically reactive, high temperature (600 C) environments. We demonstrate that the device can be used as a hydrogen monitor in syngas applications of common interferants as well as sulfur and water vapor. These measurements were made in the Catalyst Screening Unit at NETL, Morgantown under atmospheric conditions. The sensor response to hydrogen gas at 350 C is 240 mV/decade, this is significantly higher than the device response to room temperature gas or that predicted from vacuum chamber studies. The enhanced catalytic activity of the platinum sensing film under energy plant operating conditions was investigated via AFM, x-ray diffraction, TEM and x-ray photoelectron spectroscopy. Our characterization indicated that exposure to high temperature gases significantly modifies the morphology of the Pt catalytic film and the Pt/SiO{sub 2} interfacial region, which we tentatively attribute to the enhanced hydrogen sensitivity of the sensing film. A model for the hydrogen/oxygen response of the SiC device under atmospheric conditions was developed. It is based on two independent phenomena: a chemically induced shift in the metal-semiconductor work function difference and the passivation/creation of charged states at the SiO{sub 2}-SiC interface. The optimum operating set point for the SiC sensor with respect to response time and long term reliability was determined to be close to mid-gap. Ultrahigh vacuum (UHV) techniques were used to investigate the effects of sulfur contamination on the Pt gate. Exposure to hydrogen sulfide, even in the presence of hydrogen or oxygen at partial pressures of 20-600 times greater than the H2S level, rapidly coated the gate with a monolayer of sulfur. Although

  16. Biofunctionalization of surfaces by energetic ion implantation: Review of progress on applications in implantable biomedical devices and antibody microarrays

    Science.gov (United States)

    Bilek, Marcela M. M.

    2014-08-01

    Despite major research efforts in the field of biomaterials, rejection, severe immune responses, scar tissue and poor integration continue to seriously limit the performance of today's implantable biomedical devices. Implantable biomaterials that interact with their host via an interfacial layer of active biomolecules to direct a desired cellular response to the implant would represent a major and much sought after improvement. Another, perhaps equally revolutionary, development that is on the biomedical horizon is the introduction of cost-effective microarrays for fast, highly multiplexed screening for biomarkers on cell membranes and in a variety of analyte solutions. Both of these advances will rely on effective methods of functionalizing surfaces with bioactive molecules. After a brief introduction to other methods currently available, this review will describe recently developed approaches that use energetic ions extracted from plasma to facilitate simple, one-step covalent surface immobilization of bioactive molecules. A kinetic theory model of the immobilization process by reactions with long-lived, mobile, surface-embedded radicals will be presented. The roles of surface chemistry and microstructure of the ion treated layer will be discussed. Early progress on applications of this technology to create diagnostic microarrays and to engineer bioactive surfaces for implantable biomedical devices will be reviewed.

  17. Research Update: The electronic structure of hybrid perovskite layers and their energetic alignment in devices

    Directory of Open Access Journals (Sweden)

    Selina Olthof

    2016-09-01

    Full Text Available In recent years, the interest in hybrid organic–inorganic perovskites has increased at a rapid pace due to their tremendous success in the field of thin film solar cells. This area closely ties together fundamental solid state research and device application, as it is necessary to understand the basic material properties to optimize the performances and open up new areas of application. In this regard, the energy levels and their respective alignment with adjacent charge transport layers play a crucial role. Currently, we are lacking a detailed understanding about the electronic structure and are struggling to understand what influences the alignment, how it varies, or how it can be intentionally modified. This research update aims at giving an overview over recent results regarding measurements of the electronic structure of hybrid perovskites using photoelectron spectroscopy to summarize the present status.

  18. Combined effects of space charge and energetic disorder on photocurrent efficiency loss of field-dependent organic photovoltaic devices

    Science.gov (United States)

    Yoon, Sangcheol; Park, Byoungchoo; Hwang, Inchan

    2015-11-01

    The loss of photocurrent efficiency by space-charge effects in organic solar cells with energetic disorder was investigated to account for how energetic disorder incorporates space-charge effects, utilizing a drift-diffusion model with field-dependent charge-pair dissociation and suppressed bimolecular recombination. Energetic disorder, which induces the Poole-Frenkel behavior of charge carrier mobility, is known to decrease the mobility of charge carriers and thus reduces photovoltaic performance. We found that even if the mobilities are the same in the absence of space-charge effects, the degree of energetic disorder can be an additional parameter affecting photocurrent efficiency when space-charge effects occur. Introducing the field-dependence parameter that reflects the energetic disorder, the behavior of efficiency loss with energetic disorder can differ depending on which charge carrier is subject to energetic disorder. While the energetic disorder that is applied to higher-mobility charge carriers decreases photocurrent efficiency further, the efficiency loss can be suppressed when energetic disorder is applied to lower-mobility charge carriers.

  19. Device to lower NOx in a gas turbine engine combustion system

    Science.gov (United States)

    Laster, Walter R; Schilp, Reinhard; Wiebe, David J

    2015-02-24

    An emissions control system for a gas turbine engine including a flow-directing structure (24) that delivers combustion gases (22) from a burner (32) to a turbine. The emissions control system includes: a conduit (48) configured to establish fluid communication between compressed air (22) and the combustion gases within the flow-directing structure (24). The compressed air (22) is disposed at a location upstream of a combustor head-end and exhibits an intermediate static pressure less than a static pressure of the combustion gases within the combustor (14). During operation of the gas turbine engine a pressure difference between the intermediate static pressure and a static pressure of the combustion gases within the flow-directing structure (24) is effective to generate a fluid flow through the conduit (48).

  20. Furnace devices aerodynamics optimization for fuel combustion efficiency improvement and nitrogen oxide emission reduction

    Science.gov (United States)

    Volkov, E. P.; Prokhorov, V. B.; Arkhipov, A. M.; Chernov, S. L.; Kirichkov, V. S.; Kaverin, A. A.

    2017-11-01

    MPEI conducts researches on physical and mathematical models of furnace chambers for improvement of power-generation equipment fuel combustion efficiency and ecological safety. Results of these researches are general principles of furnace aerodynamics arrangement for straight-flow burners and various fuels. It has been shown, that staged combustion arrangement with early heating and igniting with torch distribution in all furnace volume allows to obtain low carbon in fly ash and nitrogen oxide emission and also to improve boiler operation reliability with expand load adjustment range. For solid fuel combustion efficiency improvement it is practical to use high-placed and strongly down-tilted straight-flow burners, which increases high-temperature zone residence time for fuel particles. In some cases, for this combustion scheme it is possible to avoid slag-tap removal (STR) combustion and to use Dry-bottom ash removal (DBAR) combustion with tolerable carbon in fly ash level. It is worth noting that boilers with STR have very high nitrogen oxide emission levels (1200-1800 mg/m3) and narrow load adjustment range, which is determined by liquid slag output stability, so most industrially-developed countries don’t use this technology. Final decision about overhaul of boiler unit is made with regard to physical and mathematical modeling results for furnace and zonal thermal calculations for furnace and boiler as a whole. Overhaul of boilers to provide staged combustion and straight-flow burners and nozzles allows ensuring regulatory nitrogen oxide emission levels and corresponding best available technology criteria, which is especially relevant due to changes in Russian environmental regulation.

  1. Computational Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Westbrook, C K; Mizobuchi, Y; Poinsot, T J; Smith, P J; Warnatz, J

    2004-08-26

    Progress in the field of computational combustion over the past 50 years is reviewed. Particular attention is given to those classes of models that are common to most system modeling efforts, including fluid dynamics, chemical kinetics, liquid sprays, and turbulent flame models. The developments in combustion modeling are placed into the time-dependent context of the accompanying exponential growth in computer capabilities and Moore's Law. Superimposed on this steady growth, the occasional sudden advances in modeling capabilities are identified and their impacts are discussed. Integration of submodels into system models for spark ignition, diesel and homogeneous charge, compression ignition engines, surface and catalytic combustion, pulse combustion, and detonations are described. Finally, the current state of combustion modeling is illustrated by descriptions of a very large jet lifted 3D turbulent hydrogen flame with direct numerical simulation and 3D large eddy simulations of practical gas burner combustion devices.

  2. Performance and Stability Analyses of Rocket Combustion Devices Using Liquid Oxygen/Liquid Methane Propellants

    Science.gov (United States)

    Hulka, James R.; Jones, G. W.

    2010-01-01

    Liquid rocket engines using oxygen and methane propellants are being considered by the National Aeronautics and Space Administration (NASA) for in-space vehicles. This propellant combination has not been previously used in flight-qualified engine systems, so limited test data and analysis results are available at this stage of early development. NASA has funded several hardware-oriented programs with oxygen and methane propellants over the past several years with the Propulsion and Cryogenic Advanced Development (PCAD) project, under the Exploration Technology Development Program. As part of this effort, NASA Marshall Space Flight Center has conducted combustion, performance, and combustion stability analyses of several of the configurations on these programs. This paper summarizes these analyses. Test and analysis results of impinging and coaxial element injectors using liquid oxygen and liquid methane propellants are included. Several cases with gaseous methane are included for reference. Several different thrust chamber configurations have been modeled, including thrust chambers with multi-element like-on-like and swirl coax element injectors tested at NASA MSFC, and a unielement chamber with shear and swirl coax injectors tested at The Pennsylvania State University. Configurations were modeled with two one-dimensional liquid rocket combustion analysis codes, the Rocket Combustor Interaction Design and Analysis (ROCCID), and the Coaxial Injector Combustion Model (CICM). Significant effort was applied to show how these codes can be used to model combustion and performance with oxygen/methane propellants a priori, and what anchoring or calibrating features need to be applied or developed in the future. This paper describes the test hardware configurations, presents the results of all the analyses, and compares the results from the two analytical methods.

  3. Energetic Systems

    Data.gov (United States)

    Federal Laboratory Consortium — The Energetic Systems Division provides full-spectrum energetic engineering services (project management, design, analysis, production support, in-service support,...

  4. DEVELOPMENT OF SiC DEVICES FOR DIAGNOSTICS AND CONTROL OF COMBUSTION PRODUCTS IN ENERGY PLANT ENVIRONMENTS

    Energy Technology Data Exchange (ETDEWEB)

    Ruby N. Ghosh; Peter Tobias

    2003-12-01

    A sensor based on the wide bandgap semiconductor, silicon carbide (SiC), has been developed for the detection of combustion products in power plant environments. The sensor is a catalytic gate field effect device that can detect hydrogen containing species in chemically reactive, high temperature environments. The response of these metal/insulator/SiC (MISiC) devices to reducing gases has been assumed to be due to the reduction in the metal work function at the metal/oxide interface that shifts the capacitance to lower voltages. From in-situ capacitance-voltage measurements taken under sensor operating conditions we have discovered that two independent mechanisms are responsible for the sensor response to hydrogen and oxygen. We present a model of the device response based on the chemically induced shift of the metal/semiconductor barrier height as well as the passivation and creation of charged states at the SiO{sub 2}/SiC interface. The latter mechanism is much slower than the barrier height shift. Preliminary photoemission experiments have been performed to independently monitor the contribution of the two phenomena. We discuss in detail the effect of these results on sensor design and the choice of operating point for high temperature operation.

  5. Design and Development of a TEG Cogenerator Device Integrated into a Self-Standing Natural Combustion Gas Stove

    Science.gov (United States)

    Codecasa, Matteo Paolo; Fanciulli, Carlo; Gaddi, Roberto; Gomez-Paz, Francisco; Passaretti, Francesca

    2015-01-01

    Heating by gas combustion, by use of different types of systems and plants, is widespread in residential and industrial environments. One example is the gas stove, the heat-radiating unit of which operates autonomously with a local gas feed and, possibly, electricity for an optional fan convector. A thermoelectric generator (TEG) can be integrated within this type of autonomous gas heater for local production of electric power, to support electrical auxiliaries, where desired, without the need for any connection to the electricity grid. This approach can lead to easier installation and operation and increases overall efficiency. A new prototype of an autonomous gas heater has been implemented by integration of a TEG device of simple and robust design, easily operated by the end user. A small amount of heat is withdrawn and converted into electricity by the TEG. This enables self-sustaining operation and, moreover, powers new ancillary functions (e.g. fan convector) without extra electrical requirements and no need for an electrical connection.

  6. Process for intermittent injection of fuel into the combustion space of an internal combustion engine and device to carry out this process. Verfahren zum intermittierenden Einspritzen von Brennstoff in den Brennraum einer Brennkraftmaschine, sowie Vorrichtung zur Durchfuehrung dieses Verfahrens

    Energy Technology Data Exchange (ETDEWEB)

    Henkel, D.

    1991-05-16

    The invention refers to a process for the intermittent injection of fuel into the combustion space of an internal combustion engine, and a device to carry out this process. The efforts to improve the exhaust gas values and the noise behaviour of Diesel engines are aimed at control of the course of heating. According to the invention, this is done by the nozzle needle of the injection nozzle itself acting as the control organ for supplying fuel to the pressure space of the nozzle body, so that the nozzle needle is actuated for very frequent opening and closing in small cycles. Together with the high fuel pressure, a good drop spectrum is obtained, which leads to a homogeneous fuel/air mixture. The division of injection into small cycles by comparatively simple means leads to an extension of the course of heating, which has a positive effect on the NO{sub x} content (of the exhaust).

  7. Boosting Electrical Performance of High-κ Nanomultilayer Dielectrics and Electronic Devices by Combining Solution Combustion Synthesis and UV Irradiation.

    Science.gov (United States)

    Carlos, Emanuel; Branquinho, Rita; Kiazadeh, Asal; Martins, Jorge; Barquinha, Pedro; Martins, Rodrigo; Fortunato, Elvira

    2017-11-22

    In the past decade, solution-based dielectric oxides have been widely studied in electronic applications enabling the use of low-cost processing technologies and device improvement. The most promising are the high-κ dielectrics, like aluminum (AlOx) and hafnium oxide (HfOx), that allow an easier trap filling in the semiconductor and the use of low operation voltage. However, in the case of HfOx, a high temperature usually is needed to induce a uniform and condensed film, which limits its applications in flexible electronics. This paper describes how to obtain HfOx dielectric thin films and the effect of their implementation in multilayer dielectrics (MLD) at low temperatures (150 °C) to apply in thin film transistors (TFTs) using the combination of solution combustion synthesis (SCS) and ultraviolet (UV) treatment. The single layers and multilayers did not show any trace of residual organics and exhibited a small surface roughness (2.7 MV·cm-1). The resulting TFTs presented a high performance at a low operation voltage (<3 V), with high saturation mobility (43.9 ± 1.1 cm2·V-1·s-1), a small subthreshold slope (0.066 ± 0.010 V·dec-1), current ratio of 1 × 106 and a good idle shelf life stability after 2 months. To our knowledge, the results achieved surpass the actual state-of-the-art. Finally, we demonstrated a low-voltage diode-connected inverter using MLD/IGZO TFTs working with a maximum gain of 1 at 2 V.

  8. Effect of solution combusted TiO2 nanopowder within commercial BaTiO3 dielectric layer on the photoelectric properties for AC powder electroluminescence devices.

    Science.gov (United States)

    Park, Sung; Choi, Gil Rak; Kim, Youn Cheol; Lee, Jae Chun; Lee, Ju Hyeon

    2013-05-01

    A unique synthesis method was developed, which is called solution combustion method (SCM). TiO2 nanopowder was synthesized by this method. This SCM TiO2 nanopowder (-35 nm) was added to the dielectric layer of AC powder electroluminescence (EL) device. The dielectric layer was made of commercial BaTiO3 powder (-1.2 microm) and binding polymer. 0, 5, 10 and 15 wt% of SCM TiO2 nanopowder was added to the dielectric layer during fabrication of AC powder EL device respectively. Dielectric constant of these four kinds of dielectric layers was measured. The brightness and current density of AC powder EL device were also measured. When 10 wt% of SCM TiO2 nanopowder was added, dielectric constant and brightness were increased by 30% and 101% respectively. Furthermore, the current density was decreased by 71%. This means that the brightness was double and the power consumption was one third.

  9. Bubble Combustion

    Science.gov (United States)

    Corrigan, Jackie

    2004-01-01

    A method of energy production that is capable of low pollutant emissions is fundamental to one of the four pillars of NASA s Aeronautics Blueprint: Revolutionary Vehicles. Bubble combustion, a new engine technology currently being developed at Glenn Research Center promises to provide low emissions combustion in support of NASA s vision under the Emissions Element because it generates power, while minimizing the production of carbon dioxide (CO2) and nitrous oxides (NOx), both known to be Greenhouse gases. and allows the use of alternative fuels such as corn oil, low-grade fuels, and even used motor oil. Bubble combustion is analogous to the inverse of spray combustion: the difference between bubble and spray combustion is that spray combustion is spraying a liquid in to a gas to form droplets, whereas bubble combustion involves injecting a gas into a liquid to form gaseous bubbles. In bubble combustion, the process for the ignition of the bubbles takes place on a time scale of less than a nanosecond and begins with acoustic waves perturbing each bubble. This perturbation causes the local pressure to drop below the vapor pressure of the liquid thus producing cavitation in which the bubble diameter grows, and upon reversal of the oscillating pressure field, the bubble then collapses rapidly with the aid of the high surface tension forces acting on the wall of the bubble. The rapid and violent collapse causes the temperatures inside the bubbles to soar as a result of adiabatic heating. As the temperatures rise, the gaseous contents of the bubble ignite with the bubble itself serving as its own combustion chamber. After ignition, this is the time in the bubble s life cycle where power is generated, and CO2, and NOx among other species, are produced. However, the pollutants CO2 and NOx are absorbed into the surrounding liquid. The importance of bubble combustion is that it generates power using a simple and compact device. We conducted a parametric study using CAVCHEM

  10. Multiphase Combustion of Metalized Nanocomposite Energetic Materials

    Science.gov (United States)

    2014-12-19

    Homan , Kevin McNesby, • Mr. B1yan Bockmon (Rocky Brad Forch (APG, ARL) Mountain Scientific Lab) • Drs. Stephen Howard, Richard Beyer , • Dr. Emily...We ru·e also actively working with the Almy Research Laboratory and Drs. Richard Beyer and Ben ie Homan . We m·e working with all of these

  11. Community-Wide Distribution of a Catalytic Device to Reduce Winter Ambient Fine Particulate Matter from Residential Wood Combustion: A Field Study.

    Directory of Open Access Journals (Sweden)

    Olivia Johnston

    Full Text Available Residential wood combustion is the main source of elevated concentrations of fine particulate matter (PM2.5 during winter in many towns of Tasmania, Australia. A commercially available firebox catalyst in Australia has previously been shown to reduce visible smoke emissions and the manufacturer reports reductions in particle emissions generated from individual wood heaters in laboratory settings. This study aimed to evaluate the potential for community-wide distribution of the catalyst to improve the ambient winter air quality in the field. The study was set in four rural towns in northern Tasmania with similar topography, population size, and proportion of houses using wood heaters for space heating. Hourly PM2.5 concentrations and meteorological conditions were monitored in all locations by fixed stations from May-September, 2013 and 2014. In June 2014, residents of one town, Perth, were offered a free catalyst for placement in their fireboxes. A general linear model evaluated the impact of the intervention using an indicator variable adjusted for hourly conditions of weather. Almost 80% of wood heater owners in Perth accepted a catalytic device. However, no significant changes in ambient PM2.5 concentrations were associated with the catalyst trial. Future community-level research should address maintenance of the catalyst in the firebox, and the adequacy of conditions that facilitate catalysed combustion in individual heaters.

  12. Community-Wide Distribution of a Catalytic Device to Reduce Winter Ambient Fine Particulate Matter from Residential Wood Combustion: A Field Study.

    Science.gov (United States)

    Johnston, Olivia; Johnston, Fay; Todd, John; Williamson, Grant

    2016-01-01

    Residential wood combustion is the main source of elevated concentrations of fine particulate matter (PM2.5) during winter in many towns of Tasmania, Australia. A commercially available firebox catalyst in Australia has previously been shown to reduce visible smoke emissions and the manufacturer reports reductions in particle emissions generated from individual wood heaters in laboratory settings. This study aimed to evaluate the potential for community-wide distribution of the catalyst to improve the ambient winter air quality in the field. The study was set in four rural towns in northern Tasmania with similar topography, population size, and proportion of houses using wood heaters for space heating. Hourly PM2.5 concentrations and meteorological conditions were monitored in all locations by fixed stations from May-September, 2013 and 2014. In June 2014, residents of one town, Perth, were offered a free catalyst for placement in their fireboxes. A general linear model evaluated the impact of the intervention using an indicator variable adjusted for hourly conditions of weather. Almost 80% of wood heater owners in Perth accepted a catalytic device. However, no significant changes in ambient PM2.5 concentrations were associated with the catalyst trial. Future community-level research should address maintenance of the catalyst in the firebox, and the adequacy of conditions that facilitate catalysed combustion in individual heaters.

  13. Reapplication of energetic materials at fuels

    Energy Technology Data Exchange (ETDEWEB)

    Baxter, L.; Sinquefield, S.; Huey, S.; Lipkin, J.; Shah, D.; Ross, J.; Sclippa, G. [Sandia National Labs., Livermore, CA (United States); Davis, K. [Reaction Engineering Internaional, Salt Lake City, UT (United States)

    1995-05-01

    This investigation addresses the combustion-related aspects of the reapplication of energetic materials as fuels in boilers as an economically viable and environmentally acceptable use of excess energetic materials. The economics of this approach indicate that the revenues from power generation and chemical recovery approximately equal the costs of boiler modification and changes in operation. The primary tradeoff is the cost of desensitizing the fuels against the cost of open burn/open detonation (OB/OD) or other disposal techniques. Two principal combustion-related obstacles to the use of energetic-material-derived fuels are NO{sub x} generation and the behavior of metals. NO{sub x} measurements obtained in this investigation indicate that the nitrated components (nitrocellulose, nitroglycerin, etc.) of energetic materials decompose with NO{sub x} as the primary product. This can lead to high uncontrolled NO{sub x} levels (as high as 2600 ppM on a 3% O{sub 2} basis for a 5% blend of energetic material in the fuel). NO{sub x} levels are sensitive to local stoichiometry and temperature. The observed trends resemble those common during the combustion of other nitrogen containing fuels. Implications for NO{sub x} control strategies are discussed. The behavior of inorganic components in energetic materials tested in this investigation could lead to boiler maintenance problems such as deposition, grate failure, and bed agglomeration. The root cause of the problem is the potentially extreme temperature generated during metal combustion. Implications for furnace selection and operation are discussed.

  14. Utilizing the Power of Nanostructures to Their Fullest Capability in Energetic Formulations

    Science.gov (United States)

    2016-02-01

    release, more efficient combustion, and controllable explosive performance consistent with the introduction of nanostructured metallics to energetic ... Energetic Formulations by N Scott Weingarten, Jennifer L Gottfried, Iskander G Batyrev, Eric S Collins, and Michael R Zachariah...ARL-TR-7604 ● FEB 2016 US Army Research Laboratory Utilizing the Power of Nanostructures to Their Fullest Capability in Energetic

  15. Automatic classification process and device for nuclear fuel pellets; Procede et dispositif de tri automatique de pastilles de combustible nucleaire

    Energy Technology Data Exchange (ETDEWEB)

    Bernardin, M.; Bouvet, P.; Wache, C.

    1994-07-01

    The device arranges the fuel pellets in several parallel files. The end pellet of each file are then removed and aligned. These pellets are then simultaneously transferred on an optical inspection arrangement and are turned simultaneously for examination. The light signal is analysed to determine if each pellet is correct, acceptable or reject. The pellets are then held by individual grabs which displace to a separation system where the individual grabs are controlled to open in response to the result of the signal analysis. 13 figs.

  16. Smoldering Combustion

    OpenAIRE

    Rein, G

    2016-01-01

    Smoldering combustion is the slow, low temperature, flameless burning of porous fuels and is the most persistent type of combustion phenomena. It is especially common in porous fuels which form a char on heating, like cellulosic insulation, polyurethane foam or peat. Smoldering combustion is among the leading causes of residential fires, and it is a source of safety concerns in industrial premises as well as in commercial and space flights. Smoldering is also the dominant combustion phenomena...

  17. Improving post-detonation energetics residues estimations for the Life Cycle Environmental Assessment process for munitions.

    Science.gov (United States)

    Walsh, Michael; Gullett, Brian; Walsh, Marianne; Bigl, Matthew; Aurell, Johanna

    2018-03-01

    The Life Cycle Environmental Assessment (LCEA) process for military munitions tracks possible environmental impacts incurred during all phases of the life of a munition. The greatest energetics-based emphasis in the current LCEA process is on manufacturing. A review of recent LCEAs indicates that energetics deposition on ranges from detonations and disposal during training is only peripherally examined through assessment of combustion products derived from closed-chamber testing or models. These assessments rarely report any measurable energetic residues. Field-testing of munitions for energetics residues deposition has demonstrated that over 30% of some energetic compounds remain after detonation, which conflicts with the LCEA findings. A study was conducted in the open environment to determine levels of energetics residue deposition and if combustion product results can be correlated with empirical deposition results. Energetics residues deposition, post-detonation combustion products, and fine aerosolized energetics particles following open-air detonation of blocks of Composition C4 (510 g RDX/block) were quantified. The deposited residues amounted to 3.6 mg of energetic per block of C4, or less than 0.001% of the original energetics. Aerial emissions of energetics were about 7% of the amount of deposited energetics. This research indicates that aerial combustion products analysis can provide a valuable supplement to energetics deposition data in the LCEA process but is insufficient alone to account for total residual energetics. This study demonstrates a need for the environmental testing of munitions to quantify energetics residues from live-fire training. Published by Elsevier Ltd.

  18. Stochastic Energetics of Quantum Transport

    OpenAIRE

    Ghosh, Pulak Kumar; Ray, Deb Shankar

    2006-01-01

    We examine the stochastic energetics of directed quantum transport due to rectification of non-equilibrium thermal fluctuations. We calculate the quantum efficiency of a ratchet device both in presence and absence of an external load to characterize two quantifiers of efficiency. It has been shown that the quantum current as well as efficiency in absence of load (Stokes efficiency) is higher as compared to classical current and efficiency, respectively, at low temperature. The conventional ef...

  19. Energetics Conditioning Facility

    Data.gov (United States)

    Federal Laboratory Consortium — The Energetics Conditioning Facility is used for long term and short term aging studies of energetic materials. The facility has 10 conditioning chambers of which 2...

  20. Energy Harvesting from Energetic Porous Silicon

    Science.gov (United States)

    2016-07-01

    wafers backed with platinum are patterned into 2- mm devices with bridge wires (Fig. 1 [left]). Using a silicon nitride layer as a mask, the silicon is...ARL-TR-7719 ● JULY 2016 US Army Research Laboratory Energy Harvesting from Energetic Porous Silicon by Louis B Levine, Matthew...Harvesting from Energetic Porous Silicon by Louis B Levine Academy of Applied Science, Concord, NH Matthew H Ervin and Wayne A Churaman Sensors and

  1. Combustion engineering

    CERN Document Server

    Ragland, Kenneth W

    2011-01-01

    Introduction to Combustion Engineering The Nature of Combustion Combustion Emissions Global Climate Change Sustainability World Energy Production Structure of the Book   Section I: Basic Concepts Fuels Gaseous Fuels Liquid Fuels Solid Fuels Problems Thermodynamics of Combustion Review of First Law Concepts Properties of Mixtures Combustion StoichiometryChemical EnergyChemical EquilibriumAdiabatic Flame TemperatureChemical Kinetics of CombustionElementary ReactionsChain ReactionsGlobal ReactionsNitric Oxide KineticsReactions at a Solid SurfaceProblemsReferences  Section II: Combustion of Gaseous and Vaporized FuelsFlamesLaminar Premixed FlamesLaminar Flame TheoryTurbulent Premixed FlamesExplosion LimitsDiffusion FlamesGas-Fired Furnaces and BoilersEnergy Balance and EfficiencyFuel SubstitutionResidential Gas BurnersIndustrial Gas BurnersUtility Gas BurnersLow Swirl Gas BurnersPremixed-Charge Engine CombustionIntroduction to the Spark Ignition EngineEngine EfficiencyOne-Zone Model of Combustion in a Piston-...

  2. Burning mechanism of aluminized solid rocket propellants based on energetic binders

    Energy Technology Data Exchange (ETDEWEB)

    Babuk, Valery A.; Dolotkazin, Ildar N.; Glebov, Andrey A. [Baltic State Technical University (BSTU), First Krasnoarmeyskaya Str. 1, Saint Petersburg (Russian Federation)

    2005-09-01

    This paper reports results obtained from an experimental study of the combustion mechanism of aluminized propellants based on an energetic binder. The techniques used in this investigation include:. (Abstract Copyright [2005], Wiley Periodicals, Inc.)

  3. Polymorphism in Energetic Materials

    Science.gov (United States)

    2008-01-01

    the classic cases of polymorphism at ambient conditions in the energetic field are TNT, HMX , and CL20 (Fig. 1). TNT [2,4,6-trinitrotoluene] is known...2008 NRL REVIEW 71 Polymorphism in Energetic Materials J.R. Deschamps,1 D.A. Parrish,1 and R.J. Butcher2 1Laboratory for Structure of Matter...2Department of Chemistry, Howard University Polymorphism often occurs in energetic materials. Differences in the forms range from conformational changes in

  4. Traveling-Wave Thermoacoustic Engines With Internal Combustion

    Science.gov (United States)

    Weiland, Nathan Thomas; Zinn, Ben T.; Swift, Gregory William

    2004-05-11

    Thermoacoustic devices are disclosed wherein, for some embodiments, a combustion zone provides heat to a regenerator using a mean flow of compressible fluid. In other embodiments, burning of a combustible mixture within the combustion zone is pulsed in phase with the acoustic pressure oscillations to increase acoustic power output. In an example embodiment, the combustion zone and the regenerator are thermally insulated from other components within the thermoacoustic device.

  5. Pulsating combustion - Combustion characteristics and reduction of emissions

    Energy Technology Data Exchange (ETDEWEB)

    Lindholm, Annika

    1999-11-01

    In the search for high efficiency combustion systems pulsating combustion has been identified as one of the technologies that potentially can meet the objectives of clean combustion and good fuel economy. Pulsating combustion offers low emissions of pollutants, high heat transfer and efficient combustion. Although it is an old technology, the interest in pulsating combustion has been renewed in recent years, due to its unique features. Various applications of pulsating combustion can be found, mainly as drying and heating devices, of which the latter also have had commercial success. It is, however, in the design process of a pulse combustor, difficult to predict the operating frequency, the heat release etc., due to the lack of a well founded theory of the phenomenon. Research concerning control over the combustion process is essential for developing high efficiency pulse combustors with low emissions. Natural gas fired Helmholtz type pulse combustors have been the experimental objects of this study. In order to investigate the interaction between the fluid dynamics and the chemistry in pulse combustors, laser based measuring techniques as well as other conventional measuring techniques have been used. The experimental results shows the possibilities to control the combustion characteristics of pulsating combustion. It is shown that the time scales in the large vortices created at the inlet to the combustion chamber are very important for the operation of the pulse combustor. By increasing/decreasing the time scale for the large scale mixing the timing of the heat release is changed and the operating characteristics of the pulse combustor changes. Three different means for NO{sub x} reduction in Helmholtz type pulse combustors have been investigated. These include exhaust gas recirculation, alteration of air/fuel ratio and changed inlet geometry in the combustion chamber. All used methods achieved less than 10 ppm NO{sub x} emitted (referred to stoichiometric

  6. Biofuels combustion.

    Science.gov (United States)

    Westbrook, Charles K

    2013-01-01

    This review describes major features of current research in renewable fuels derived from plants and from fatty acids. Recent and ongoing fundamental studies of biofuel molecular structure, oxidation reactions, and biofuel chemical properties are reviewed, in addition to combustion applications of biofuels in the major types of engines in which biofuels are used. Biofuels and their combustion are compared with combustion features of conventional petroleum-based fuels. Two main classes of biofuels are described, those consisting of small, primarily alcohol, fuels (particularly ethanol, n-butanol, and iso-pentanol) that are used primarily to replace or supplement gasoline and those derived from fatty acids and used primarily to replace or supplement conventional diesel fuels. Research efforts on so-called second- and third-generation biofuels are discussed briefly.

  7. Sandia combustion research program: Annual report, 1987

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, R.E.; Sanders, B.R.; Ivanetich, C.A. (eds.)

    1988-01-01

    More than a decade ago, in response to a national energy crisis, Sandia proposed to the US Department of Energy a new, ambitious program in combustion research. Our strategy was to apply the rapidly increasing capabilities in lasers and computers to combustion science and technology. Shortly thereafter, the Combustion Research Facility (CRF) was established at Sandia's Livermore location. Designated a ''User Facility,'' the charter of the CRF was to develop and maintain special-purpose resources to support a nationwide initiative--involving US universities, industry, and national laboratories--to improve our understanding and control of combustion. This report includes descriptions of several research projects which have been stimulated by Working Groups and involve the on-site participation of industry scientists. DOE's Industry Technology Fellowship Program has been instrumental in the success of some of the joint efforts. The remainder of this report presents research results of calendar year 1987, separated thematically into nine categories. Refereed journal articles appearing in print during 1987, along with selected other publications, are included at the end of Section 10. In addition to our ''traditional'' research--chemistry, reacting flow, diagnostics, engine combustion, and coal combustion--you will note continued progress in somewhat recent themes: pulse combustion, high temperature materials, and energetic materials, for example. Moreover, we have just started a small, new effort to understand combustion-related issues in the management of toxic and hazardous materials.

  8. Energetics Laboratory Facilities

    Data.gov (United States)

    Federal Laboratory Consortium — These energetic materials laboratories are equipped with explosion proof hoods with blow out walls for added safety, that are certified for safe handling of primary...

  9. Turbulent combustion

    Energy Technology Data Exchange (ETDEWEB)

    Talbot, L.; Cheng, R.K. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01

    Turbulent combustion is the dominant process in heat and power generating systems. Its most significant aspect is to enhance the burning rate and volumetric power density. Turbulent mixing, however, also influences the chemical rates and has a direct effect on the formation of pollutants, flame ignition and extinction. Therefore, research and development of modern combustion systems for power generation, waste incineration and material synthesis must rely on a fundamental understanding of the physical effect of turbulence on combustion to develop theoretical models that can be used as design tools. The overall objective of this program is to investigate, primarily experimentally, the interaction and coupling between turbulence and combustion. These processes are complex and are characterized by scalar and velocity fluctuations with time and length scales spanning several orders of magnitude. They are also influenced by the so-called {open_quotes}field{close_quotes} effects associated with the characteristics of the flow and burner geometries. The authors` approach is to gain a fundamental understanding by investigating idealized laboratory flames. Laboratory flames are amenable to detailed interrogation by laser diagnostics and their flow geometries are chosen to simplify numerical modeling and simulations and to facilitate comparison between experiments and theory.

  10. Autoignition characterization of primary reference fuels and n-heptane/n-butanol mixtures in a constant volume combustion device and homogeneous charge compression ignition engine

    KAUST Repository

    Baumgardner, Marc E.

    2013-12-19

    In this study, the autoignition behavior of primary reference fuels (PRF) and blends of n-heptane/n-butanol were examined in a Waukesha Fuel Ignition Tester (FIT) and a Homogeneous Charge Compression Engine (HCCI). Fourteen different blends of iso-octane, n-heptane, and n-butanol were tested in the FIT - 28 test runs with 25 ignition measurements for each test run, totaling 350 individual tests in all. These experimental results supported previous findings that fuel blends with high alcohol content can exhibit very different ignition delay periods than similarly blended reference fuels. The experiments further showed that n-butanol blends behaved unlike PRF blends when comparing the autoignition behavior as a function of the percentage of low reactivity component. The HCCI and FIT experimental results favorably compared against single and multizone models with detailed chemical kinetic mechanisms - both an existing mechanism as well as one developed during this study were used. The experimental and modeling results suggest that that the FIT instrument is a valuable tool for analysis of high pressure, low temperature chemistry, and autoignition for future fuels in advanced combustion engines. Additionally, in both the FIT and engine experiments the fraction of low temperature heat release (fLTHR) was found to correlate very well with the crank angle of maximum heat release and shows promise as a useful metric for fuel reactivity in advanced combustion applications. © 2013 American Chemical Society.

  11. Highly energetic compositions based on functionalized carbon nanomaterials

    Science.gov (United States)

    Yan, Qi-Long; Gozin, Michael; Zhao, Feng-Qi; Cohen, Adva; Pang, Si-Ping

    2016-02-01

    In recent years, research in the field of carbon nanomaterials (CNMs), such as fullerenes, expanded graphite (EG), carbon nanotubes (CNTs), graphene, and graphene oxide (GO), has been widely used in energy storage, electronics, catalysts, and biomaterials, as well as medical applications. Regarding energy storage, one of the most important research directions is the development of CNMs as carriers of energetic components by coating or encapsulation, thus forming safer advanced nanostructures with better performances. Moreover, some CNMs can also be functionalized to become energetic additives. This review article covers updated preparation methods for the aforementioned CNMs, with a more specific orientation towards the use of these nanomaterials in energetic compositions. The effects of these functionalized CNMs on thermal decomposition, ignition, combustion and the reactivity properties of energetic compositions are significant and are discussed in detail. It has been shown that the use of functionalized CNMs in energetic compositions greatly improves their combustion performances, thermal stability and sensitivity. In particular, functionalized fullerenes, CNTs and GO are the most appropriate candidate components in nanothermites, solid propellants and gas generators, due to their superior catalytic properties as well as facile preparation methods.

  12. Tubular combustion

    CERN Document Server

    Ishizuka, Satoru

    2014-01-01

    Tubular combustors are cylindrical tubes where flame ignition and propagation occur in a spatially confined, highly controlled environment, in a nearly flat, elongated geometry. This allows for some unique advantages where extremely even heat dispersion is required over a large surface while still maintaining fuel efficiency. Tubular combustors also allow for easy flexibility in type of fuel source, allowing for quick changeover to meet various needs and changing fuel pricing. This new addition to the MP sustainable energy series will provide the most up-to-date research on tubular combustion--some of it only now coming out of private proprietary protection. Plentiful examples of current applications along with a good explanation of background theory will offer readers an invaluable guide on this promising energy technology. Highlights include: * An introduction to the theory of tubular flames * The "how to" of maintaining stability of tubular flames through continuous combustion * Examples of both small-scal...

  13. Energetic Materials Laboratory

    Science.gov (United States)

    2015-04-30

    bomb calorimeter (Parr 6220), a semimicro calorimeter (Parr 6725), and a high-speed video camera (Vision Research Phantom v1210). This acquisition...Paper 3.00 4.00 Daniel A. Rodriguez, Edward L. Dreizin, Evgeny Shafirovich. Hydrogen generation from ammonia borane and water through combustion...Symposium. 04-APR-15, . : , Sergio E. Guerrero, Daniel A. Rodriguez, Edward L. Dreizin, Evgeny Shafirovich. Combustible Mixtures for Hydrogen and Iodine

  14. Advanced Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Holcomb, Gordon R. [NETL

    2013-03-11

    The activity reported in this presentation is to provide the mechanical and physical property information needed to allow rational design, development and/or choice of alloys, manufacturing approaches, and environmental exposure and component life models to enable oxy-fuel combustion boilers to operate at Ultra-Supercritical (up to 650{degrees}C & between 22-30 MPa) and/or Advanced Ultra-Supercritical conditions (760{degrees}C & 35 MPa).

  15. Strobes: an oscillatory combustion.

    Science.gov (United States)

    Corbel, Justine M L; Lingen, Joost N J; Zevenbergen, John F; Gijzeman, Onno L J; Meijerink, Andries

    2012-04-26

    Strobe compositions belong to the class of solid combustions. They are mixtures of powdered ingredients. When ignited, the combustion front evolves in an oscillatory fashion, and flashes of light are produced by intermittence. They have fascinated many scientists since their discovery at the beginning of the 20th century. However, the chemical and physical processes involved in this curious oscillatory combustion remain unknown. Several theories have been proposed: One claims that two different reactions occur: one during the slow dark phase and another during the fast flash phase. The alternation between the phases is ascribed to heat variations. Other theories suggest that the formation of intermediate species during the dark phase and the change of phase are caused by variations in their concentration. A ternary strobe composition with ammonium perchlorate, magnalium, and barium sulfate is analyzed. The role of barium sulfate is studied by replacing it by other metal sulfates that have different physical properties (melting points), and the burning of the compositions is recorded with a high-speed camera and a spectrometer coupled with a charge-coupled device (CCD) camera. Experimental results show noticeable differences in the physical and chemical processes involved in the strobe reactions.

  16. Photoactive energetic materials

    Energy Technology Data Exchange (ETDEWEB)

    Chavez, David E.; Hanson, Susan Kloek; Scharff, Robert Jason; Veauthier, Jacqueline Marie; Myers, Thomas Winfield

    2018-02-27

    Energetic materials that are photoactive or believed to be photoactive may include a conventional explosive (e.g. PETN, nitroglycerine) derivatized with an energetic UV-absorbing and/or VIS-absorbing chromophore such as 1,2,4,5-tetrazine or 1,3,5-triazine. Absorption of laser light having a suitably chosen wavelength may result in photodissociation, decomposition, and explosive release of energy. These materials may be used as ligands to form complexes. Coordination compounds include such complexes with counterions. Some having the formula M(L).sub.n.sup.2+ were synthesized, wherein M is a transition metal and L is a ligand and n is 2 or 3. These may be photoactive upon exposure to a laser light beam having an appropriate wavelength of UV light, near-IR and/or visible light. Photoactive materials also include coordination compounds bearing non-energetic ligands; in this case, the counterion may be an oxidant such as perchlorate.

  17. INTENSE ENERGETIC GAS DISCHARGE

    Science.gov (United States)

    Luce, J.S.

    1960-03-01

    A method and apparatus for initiating and sustaining an energetic gas arc discharge are described. A hollow cathode and a hollow anode are provided. By regulating the rate of gas flow into the interior of the cathode, the arc discharge is caused to run from the inner surface of the cathode with the result that adequate space-charge neutralization is provided inside the cathode but not in the main arc volume. Thus, the gas fed to the cathode is substantially completely ionized before it leaves the cathode, with the result that an energetic arc discharge can be maintained at lower operating pressures.

  18. Microscale combustion and power generation

    CERN Document Server

    Cadou, Christopher; Ju, Yiguang

    2014-01-01

    Recent advances in microfabrication technologies have enabled the development of entirely new classes of small-scale devices with applications in fields ranging from biomedicine, to wireless communication and computing, to reconnaissance, and to augmentation of human function. In many cases, however, what these devices can actually accomplish is limited by the low energy density of their energy storage and conversion systems. This breakthrough book brings together in one place the information necessary to develop the high energy density combustion-based power sources that will enable many of these devices to realize their full potential. Engineers and scientists working in energy-related fields will find: An overview of the fundamental physics and phenomena of microscale combustion; Presentations of the latest modeling and simulation techniques for gasphase and catalytic micro-reactors; The latest results from experiments in small-scale liquid film, microtube, and porous combustors, micro-thrusters, a...

  19. Fluid-Structure Interaction in Combustion System of a Gas Turbine—Effect of Liner Vibrations

    NARCIS (Netherlands)

    Pozarlik, Artur Krzysztof; Kok, Jacobus B.W.

    2014-01-01

    Prediction of mutual interaction between flow, combustion, acoustic, and vibration phenomena occurring in a combustion chamber is crucial for the reliable operation of any combustion device. In this paper, this is studied with application to the combustion chamber of a gas turbine. Very dangerous

  20. Nanostructured Energetic Materials

    Science.gov (United States)

    2006-11-01

    Microencapsulation of energetic nanoparticles Microencapsulated Nanoparticles granules Microencapsulated granulesNanoparticles Encapsulation MIC MATERIAL...PRESSURE MEASUREMENTS IN MILLIMETER SCALE CELL Experimental Setup MIC Material Powder Loaded into MilliCell Hot Wire for Powder Initiation MIC Powder...Loaded into MilliCell Pressure Sensor Pressure measurements on lexane millicell 20mg of each material. Volume of the cell 30 cubic mm. HMT

  1. Combustion Research Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — The Combustion Research Laboratory facilitates the development of new combustion systems or improves the operation of existing systems to meet the Army's mission for...

  2. Tunable optical sensitivity of composite energetic materials

    Science.gov (United States)

    Rashkeev, Sergey; Wang, Fenggong; Tsyshevskiy, Roman; Kuklja, Maija; University of Maryland College Park Team

    Optical initiation to detonation of energetic materials is compelling because it opens up new ways for safe handling, storage, and use of high explosives. Despite this, laser irradiation has been mainly perceived as a source of heat for vibrational excitation rather than viable means of photo-stimulated initiation of energy release. Limitations of our knowledge on photo-stimulated energy release from high energy density materials hampers progress in design and manufacturing of efficient optical devices for energy storage and conversion. Here we show how electronic and optical properties of interfaces formed between nitro energetic materials and various metal oxides can be effectively tuned to achieve highly controllable surface chemistry. We discuss mechanisms of photo stimulated reactions triggered by defects on these interfaces. We demonstrate that the key in achieving tunable sensitivity is the proper alignment of the filled and vacant electronic states of oxide defects and energetic materials and provide guidelines for design composite energetic materials suitable for optical initiation. Research is supported by the US ONR (Grants N00014-16-1-2069 and N00014-16-1-2346) and NSF. We used NERSC, XSEDE and MARCC computational resources.

  3. Combustion chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Brown, N.J. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01

    This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

  4. Nitroamino and Nitro Energetics

    Science.gov (United States)

    2012-09-13

    strongly recommend using 59 immediately after synthesis and avoiding storage. Based on our calculations using the Gaussian 03 (Revision D.01) suite...Azolylacetic acids give trinitromethyl-substituted compounds in one - pot reactions.220 5-Amino- l,2,4-triazolyl-5-acetic acid (49) was prepared by...Parrish, D. " Synthesis of an energetic nitrate ester ," Angew. Chem. Int. Ed., 2008, 47, 8307-8309; (d) Liu, W.-G.; Zybin, S. V.; Dasgupta, S.; Klapötke

  5. Detonation and combustion of explosives: A selected bibliography

    Energy Technology Data Exchange (ETDEWEB)

    Dobratz, B. [comp.

    1998-08-01

    This bibliography consists of citations pertinent to the subjects of combustion and detonation of energetic materials, especially, but not exclusively, of secondary solid high explosives. These references were selected from abstracting sources, conference proceedings, reviews, and also individual works. The entries are arranged alphabetically by first author and numbered sequentially. A keyword index is appended.

  6. Comparative mutagenicity and genotoxicity of particles and aerosols emitted by the combustion of standard vs. rapeseed methyl ester supplemented bio-diesel fuels: impact of after treatment devices: oxidation catalyst and particulate filter.

    Science.gov (United States)

    André, V; Barraud, C; Capron, D; Preterre, D; Keravec, V; Vendeville, C; Cazier, F; Pottier, D; Morin, J P; Sichel, F

    2015-01-01

    Diesel exhausts are partly responsible for the deleterious effects on human health associated with urban pollution, including cardiovascular diseases, asthma, COPD, and possibly lung cancer. Particulate fraction has been incriminated and thus largely investigated for its genotoxic properties, based on exposure conditions that are, however, not relevant for human risk assessment. In this paper, original and more realistic protocols were used to investigate the hazards induced by exhausts emitted by the combustion of standard (DF0) vs. bio-diesel fuels (DF7 and DF30) and to assess the impact of exhaust treatment devices (DOC and DPF). Mutagenicity and genotoxicity were evaluated for (1) resuspended particles ("off line" exposure that takes into account the bioavailability of adsorbed chemicals) and for (2) the whole aerosols (particles+gas phase components) under continuous flow exposure ("on line" exposure). Native particles displayed mutagenic properties associated with nitroaromatic profiles (YG1041), whereas PAHs did not seem to be involved. After DOC treatment, the mutagenicity of particles was fully abolished. In contrast, the level of particle deposition was low under continuous flow exposure, and the observed mutagenicity in TA98 and TA102 was thus attributable to the gas phase. A bactericidal effect was also observed in TA102 after DOC treatment, and a weak but significant mutagenicity persisted after DPF treatment for bio-diesel fuels. No formation of bulky DNA-adducts was observed on A549 cells exposed to diesel exhaust, even in very drastic conditions (organic extracts corresponding to 500 μg equivalent particule/mL, 48 h exposure). Taken together, these data indicate that the exhausts issued from the bio-diesel fuels supplemented with rapseed methyl ester (RME), and generated by current diesel engines equipped with after treatment devices are less mutagenic than older ones. The residual mutagenicity is linked to the gas phase and could be due to pro

  7. Oxygen-enhanced combustion

    CERN Document Server

    Baukal, Charles E

    2013-01-01

    Combustion technology has traditionally been dominated by air/fuel combustion. However, two developments have increased the significance of oxygen-enhanced combustion-new technologies that produce oxygen less expensively and the increased importance of environmental regulations. Advantages of oxygen-enhanced combustion include less pollutant emissions as well as increased energy efficiency and productivity. Oxygen-Enhanced Combustion, Second Edition compiles information about using oxygen to enhance industrial heating and melting processes. It integrates fundamental principles, applications, a

  8. Thermal analysis to derive energetic quality parameters of soil organic matter?

    Science.gov (United States)

    Peikert, Benjamin; Schaumann, Gabriele Ellen

    2014-05-01

    Many studies have dealt with thermal analysis for characterisation of soil and soil organic matter. It is a versatile tool assessing various physicochemical properties of the sample during heating and/or cooling. Especially the combination of different detection methods is highly promising. In this contribution, we will discuss the combination of thermogravimetry (TGA) with differential scanning calorimetry (DSC) in one single thermal analysis device. TGA alone helps distinguishment of soil and soil organic matter fractions with respect to their resistance towards combustion and allows a quantitative assignment of thermolabile and recalcitrant OM fractions. Combination with DSC in the same device, allows determination of energy transformation during the combustion process. Therefore, it becomes possible to determine not only the calorific value of the organic matter, but also of its fractions. We will show the potential of using the calorific values of OM fractions as quality parameter - exemplified for the analysis of soils polluted with organic matter from the olive oil production. The pollution history of these samples is largely unknown. As expected, TGA indicated a relative enrichment of the labile carbon fraction in contaminated samples with respect to the controls. The calorific values of the thermolabile and the recalcitrant fractions differ from each other, and those of the recalcitrant fractions of the polluted samples were higher than of those of the unpolluted controls. Further analyses showed correlation of the calorific value of this fraction with soil water repellency and the carbon isotopic ratio. The synthesis of our current data suggests that the content of thermolabile fraction, the isotopic ratio and calorific value of the recalcitrant fraction are useful indicators for characterizing the degree of decomposition of OMW organic matter. In this contribution, we will further discuss the potential of using the energetic parameters a quality

  9. Combustion 2000

    Energy Technology Data Exchange (ETDEWEB)

    A. Levasseur; S. Goodstine; J. Ruby; M. Nawaz; C. Senior; F. Robson; S. Lehman; W. Blecher; W. Fugard; A. Rao; A. Sarofim; P. Smith; D. Pershing; E. Eddings; M. Cremer; J. Hurley; G. Weber; M. Jones; M. Collings; D. Hajicek; A. Henderson; P. Klevan; D. Seery; B. Knight; R. Lessard; J. Sangiovanni; A. Dennis; C. Bird; W. Sutton; N. Bornstein; F. Cogswell; C. Randino; S. Gale; Mike Heap

    2001-06-30

    . To achieve these objectives requires a change from complete reliance of coal-fired systems on steam turbines (Rankine cycles) and moving forward to a combined cycle utilizing gas turbines (Brayton cycles) which offer the possibility of significantly greater efficiency. This is because gas turbine cycles operate at temperatures well beyond current steam cycles, allowing the working fluid (air) temperature to more closely approach that of the major energy source, the combustion of coal. In fact, a good figure of merit for a HIPPS design is just how much of the enthalpy from coal combustion is used by the gas turbine. The efficiency of a power cycle varies directly with the temperature of the working fluid and for contemporary gas turbines the optimal turbine inlet temperature is in the range of 2300-2500 F (1260-1371 C). These temperatures are beyond the working range of currently available alloys and are also in the range of the ash fusion temperature of most coals. These two sets of physical properties combine to produce the major engineering challenges for a HIPPS design. The UTRC team developed a design hierarchy to impose more rigor in our approach. Once the size of the plant had been determined by the choice of gas turbine and the matching steam turbine, the design process of the High Temperature Advanced Furnace (HITAF) moved ineluctably to a down-fired, slagging configuration. This design was based on two air heaters: one a high temperature slagging Radiative Air Heater (RAH) and a lower temperature, dry ash Convective Air Heater (CAH). The specific details of the air heaters are arrived at by an iterative sequence in the following order:-Starting from the overall Cycle requirements which set the limits for the combustion and heat transfer analysis-The available enthalpy determined the range of materials, ceramics or alloys, which could tolerate the temperatures-Structural Analysis of the designs proved to be the major limitation-Finally the commercialization

  10. Energetics Manufacturing Technology Center (EMTC)

    Data.gov (United States)

    Federal Laboratory Consortium — The Energetics Manufacturing Technology Center (EMTC), established in 1994 by the Office of Naval Research (ONR) Manufacturing Technology (ManTech) Program, is Navy...

  11. Environmental optimisation of waste combustion

    Energy Technology Data Exchange (ETDEWEB)

    Schuster, Robert [AaF Energikonsult, Stockholm (Sweden); Berge, Niclas; Stroemberg, Birgitta [TPS Termiska Processer AB, Nykoeping (Sweden)

    2000-12-01

    The regulations concerning waste combustion evolve through R and D and a strive to get better and common regulations for the European countries. This study discusses if these rules of today concerning oxygen concentration, minimum temperature and residence time in the furnace and the use of stand-by burners are needed, are possible to monitor, are the optimum from an environmental point of view or could be improved. No evidence from well controlled laboratory experiments validate that 850 deg C in 6 % oxygen content in general is the best lower limit. A lower excess air level increase the temperature, which has a significant effect on the destruction of hydrocarbons, favourably increases the residence time, increases the thermal efficiency and the efficiency of the precipitators. Low oxygen content is also necessary to achieve low NO{sub x}-emissions. The conclusion is that the demands on the accuracy of the measurement devices and methods are too high, if they are to be used inside the furnace to control the combustion process. The big problem is however to find representative locations to measure temperature, oxygen content and residence time in the furnace. Another major problem is that the monitoring of the operation conditions today do not secure a good combustion. It can lead to a false security. The reason is that it is very hard to find boilers without stratifications. These stratifications (stream lines) has each a different history of residence time, mixing time, oxygen and combustible gas levels and temperature, when they reach the convection area. The combustion result is the sum of all these different histories. The hydrocarbons emission is in general not produced at a steady level. Small clouds of unburnt hydrocarbons travels along the stream lines showing up as peaks on a THC measurement device. High amplitude peaks has a tendency to contain higher ratio of heavy hydrocarbons than lower peaks. The good correlation between some easily detected

  12. METHOD AND APPARATUS FOR PRODUCING INTENSE ENERGETIC GAS DISCHARGES

    Science.gov (United States)

    Bell, P.R.; Luce, J.S.

    1960-01-01

    A device for producing an energetic gas arc discharge employing the use of gas-fed hollow cathode and anode electrodes is reported. The rate of feed of the gas to the electrodes is regulated to cause complete space charge neutralization to occur within the electrodes. The arc discharge is closely fitted within at least one of the electrodes so tint the gas fed to this electrode is substantially completely ionized before it is emitted into the vacuum chamber. It is this electrode design and the axial potential gradient that exists in the arc which permits the arc to be operated in low pressures and at volthges and currents that permit the arc to be energetic. The use of the large number of energetic ions that are accelerated toward the cathode as a propulsion device for a space vehicle is set forth.

  13. Energetic utilisation of refuse derived fuels from landfill mining.

    Science.gov (United States)

    Rotheut, Martin; Quicker, Peter

    2017-04-01

    The residence of municipal solid waste within a landfill body results in a significant change of material properties. Experiences with the energetic utilisation of the burnable fractions from formerly landfilled waste are hardly documented, the influence of refuse derived fuels (RDF) from such materials on the performance of modern waste-to-energy plants is not sufficiently described in scientific literature. Therefore this study focuses on the energetic utilisation of refuse derived fuel from landfilled waste, processed in a mechanical waste treatment facility, and the impact of the material on the operation of the incineration plant. Additionally, the possibility of direct combustion of non-pre-treated excavated landfill material has been evaluated in the same facility. First, sampling and analysis of the fuel has been carried out. Based on this, a large-scale combustion experiment was planned and conducted in an industrial waste-to-energy plant. Steam mass flow rate, concentration of harmful substances in the raw gas, as well as total emissions of the facility have been monitored in detail. Furthermore, the influence of the landfilled material on the additive consumption has been determined. The combustion residues (bottom ash) were also sampled and analysed. Based on the evaluation of operating data and analysis of both fuel and residue, suitable thermal treatment approaches for the refuse-derived fuel and the non-pre-treated excavated material have been assessed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Combustion Research Facility

    Data.gov (United States)

    Federal Laboratory Consortium — For more than 30 years The Combustion Research Facility (CRF) has served as a national and international leader in combustion science and technology. The need for a...

  15. Fluidized bed combustion and its application to refused fuels. Combustion en leche fluido y su aplicacion a combustibles residuales

    Energy Technology Data Exchange (ETDEWEB)

    Euba, J.

    1994-01-01

    As a consequence of the energetic crisis produced in th 70's it was proposed to find new power supplies and it also was the start of the use of traditional energy, which up to that date had not been profitable. At the same time, the worry about the pollutant emissions to the environment was increasing and finally it was approved a new legislation on atmosphere pollution, which is the Directive of the European community Council of 24th November 1988. Under these circumstances there are very important the new technologies for the supply of residual combustion with low values of pollution, where it is very important the combustion in fluidized bed. (Author)

  16. Two phase exhaust for internal combustion engine

    Science.gov (United States)

    Vuk, Carl T [Denver, IA

    2011-11-29

    An internal combustion engine having a reciprocating multi cylinder internal combustion engine with multiple valves. At least a pair of exhaust valves are provided and each supply a separate power extraction device. The first exhaust valves connect to a power turbine used to provide additional power to the engine either mechanically or electrically. The flow path from these exhaust valves is smaller in area and volume than a second flow path which is used to deliver products of combustion to a turbocharger turbine. The timing of the exhaust valve events is controlled to produce a higher grade of energy to the power turbine and enhance the ability to extract power from the combustion process.

  17. Millisecond burning of confined energetic materials during cookoff

    Energy Technology Data Exchange (ETDEWEB)

    Schmitt, R.G.; Baer, T.A.

    1997-11-01

    The response of a system containing an energetic material (EM) to an abnormal thermal environment is termed cookoff. To predict the violence of reaction of confined energetic materials during cookoff requires a description of the relevant physical processes that occur on time scales Ranging from days to submicroseconds. The time-to-ignition can be characterized accurately using heat transfer with chemistry and quasistatic mechanics. After ignition the energetic material deflagrates on a millisecond time scale. During this time the mechanical processes become dynamic. If the confinement survives burning then accelerated deflagration can lead to shock formation and deflagration to detonation transition. The focus of this work is the dynamic combustion regime in the millisecond time domain. Due to the mathematical stiffness of the chemistry equations and the prohibitively fine spatial resolution requirements needed to resolve the structure of the flame, an interface tracking approach is used to propagate the burn front. Demonstrative calculations are presented that illustrate the dynamic interaction of the deflagrating energetic material with its confinement.

  18. Evaluation of nanoparticles in the performance of energetic materials

    Directory of Open Access Journals (Sweden)

    José Atílio Fritz Fidel Rocco

    2010-04-01

    Full Text Available The addition of nanosized metal particles in propulsion systems such as solid and liquid propellants, hybrid propellant and ramjet motors has recently became a major focus of research. Significant increases in the burning velocity and in the specific impulse are some of the advantages of using nano-scale energetic materials in many different types of propulsion systems. Aluminum has been largely employed as a metallic additive in energetic materials, also in a recently new propulsion system (aluminum/ice propulsion, “Alice”, and some studies show that the advantages of using nanosized aluminum instead of microsized aluminum are facilitating the ignition of the systems and allowing better incorporation of the components in the formulations and improving its homogeneity. Some of the combustion processes that require high pressures and even higher temperatures can occur in moderate conditions due to the increase of the surface area of the reactants, in this case, the metallic additive.

  19. Electrical initiation of an energetic nanolaminate film

    Science.gov (United States)

    Tringe, Joseph W.; Gash, Alexander E.; Barbee, Jr., Troy W.

    2010-03-30

    A heating apparatus comprising an energetic nanolaminate film that produces heat when initiated, a power source that provides an electric current, and a control that initiates the energetic nanolaminate film by directing the electric current to the energetic nanolaminate film and joule heating the energetic nanolaminate film to an initiation temperature. Also a method of heating comprising providing an energetic nanolaminate film that produces heat when initiated, and initiating the energetic nanolaminate film by directing an electric current to the energetic nanolaminate film and joule heating the energetic nanolaminate film to an initiation temperature.

  20. Combustion modeling in internal combustion engines

    Science.gov (United States)

    Zeleznik, F. J.

    1976-01-01

    The fundamental assumptions of the Blizard and Keck combustion model for internal combustion engines are examined and a generalization of that model is derived. The most significant feature of the model is that it permits the occurrence of unburned hydrocarbons in the thermodynamic-kinetic modeling of exhaust gases. The general formulas are evaluated in two specific cases that are likely to be significant in the applications of the model.

  1. Boiler using combustible fluid

    Science.gov (United States)

    Baumgartner, H.; Meier, J.G.

    1974-07-03

    A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

  2. Energetical fly ashes – separation and utilization of metallic valuable components

    Directory of Open Access Journals (Sweden)

    Michalíková Františka

    2000-12-01

    Full Text Available In the contribution, methods of separating metals – Fe, Al, Ge from energetic wastes – fly ashes are presented along with further possibilities of utilization of particular valuable components for industrial purposes.In the contribution, properties of energetic wastes are presented influencing the contents, separability, and utilizability of metal-bearing valuable components. From among physical properties these are grain size distribution and surface area. Chemical properties are characterized by elements contained in combusted coal whose content after combustion is increased 2 to 4 times, depending on the content of ash and combustible matters in original coal. Mineralogical properties of energetic wastes are determined by the combustion process conditions in the course of which mineral novelties are produced in concentrations suitable for separation.In the contribution, methods of separation and utilization of metals such as Fe, Al, Ge are described. From literature information on the processing of Fe component, as well as from results of experiments made at the Department of Mineral Processing and Environmental Protection, Technical University of Kosice follows that the highest concentration and mass yield of the component can be obtained from black coal fly ashes produced in smelting boilers. The content of Al in Slovak energetic wastes is lower than the 30 % Al2O3 limit that conditions an economic technological processing. Only in the case of black coal fly ash from TEKO Kosice and EVO Vojany was the Al2O3 content of 32.93 %. Therefore, in an indirect way – by separating the residues of uncombusted coal and magnetite Fe – the content of Al in fly ash was increased.For Ge, a principle of selective sizing has been utilized.A complex utilization of energetic wastes, that is the separation of metallic components, elimination of particular metals and the subsequent treatment of nonmetallic residue, should be an effective solution in various

  3. Real-Time Combustion Controls and Diagnostics Sensors (CCADS)

    Energy Technology Data Exchange (ETDEWEB)

    Thornton, J.D.; Richard, G.A.; Dodrill, K.A.; Nutter, R.S. Jr; Straub, D.

    2005-05-03

    The present invention is directed to an apparatus for the monitoring of the combustion process within a combustion system. The apparatus comprises; a combustion system, a means for supplying fuel and an oxidizer, a device for igniting the fuel and oxidizer in order to initiate combustion, and a sensor for determining the current conducted by the combustion process. The combustion system comprises a fuel nozzle and an outer shell attached to the combustion nozzle. The outer shell defines a combustion chamber. Preferably the nozzle is a lean premix fuel nozzle (LPN). Fuel and an oxidizer are provided to the fuel nozzle at separate rates. The fuel and oxidizer are ignited. A sensor positioned within the combustion system comprising at least two electrodes in spaced-apart relationship from one another. At least a portion of the combustion process or flame is between the first and second electrodes. A voltage is applied between the first and second electrodes and the magnitude of resulting current between the first and second electrodes is determined.

  4. Lump wood combustion process

    Science.gov (United States)

    Kubesa, Petr; Horák, Jiří; Branc, Michal; Krpec, Kamil; Hopan, František; Koloničný, Jan; Ochodek, Tadeáš; Drastichová, Vendula; Martiník, Lubomír; Malcho, Milan

    2014-08-01

    The article deals with the combustion process for lump wood in low-power fireplaces (units to dozens of kW). Such a combustion process is cyclical in its nature, and what combustion facility users are most interested in is the frequency, at which fuel needs to be stoked to the fireplace. The paper defines the basic terms such as burnout curve and burning rate curve, which are closely related to the stocking frequency. The fuel burning rate is directly dependent on the immediate thermal power of the fireplace. This is also related to the temperature achieved in the fireplace, magnitude of flue gas losses and the ability to generate conditions favouring the full burnout of the fuel's combustible component, which, at once ensures the minimum production of combustible pollutants. Another part of the paper describes experiments conducted in traditional fireplaces with a grate, at which well-dried lump wood was combusted.

  5. Combustion Byproducts Recycling Consortium

    Energy Technology Data Exchange (ETDEWEB)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    Ashlines: To promote and support the commercially viable and environmentally sound recycling of coal combustion byproducts for productive uses through scientific research, development, and field testing.

  6. Combustion Velocity of Benzine-Benzol-Air Mixtures in High-Speed Internal-Combustion Engines

    Science.gov (United States)

    Schnauffer, Kurt

    1932-01-01

    The present paper describes a device whereby rapid flame movement within an internal-combustion engine cylinder may be recorded and determined. By the aid of a simple cylindrical contact and an oscillograph the rate of combustion within the cylinder of an airplane engine during its normal operation may be measured for gas intake velocities of from 30 to 35 m/s and for velocities within the cylinder of from 20 to 25 m/s. With it the influence of mixture ratios, of turbulence, of compression ratio and kind of fuel on combustion velocity may be determined. Besides the determination of the influence of the above factors on combustion velocity, the degree of turbulence may also be determined. As a unit of reference in estimating the degree of turbulence, the intake velocity of the charge is chosen.

  7. High pressure optical combustion probe

    Energy Technology Data Exchange (ETDEWEB)

    Woodruff, S.D.; Richards, G.A.

    1995-06-01

    The Department of Energy`s Morgantown Energy Technology Center has developed a combustion probe for monitoring flame presence and heat release. The technology involved is a compact optical detector of the OH radical`s UV fluorescence. The OH Monitor/Probe is designed to determine the flame presence and provide a qualitative signal proportional to the flame intensity. The probe can be adjusted to monitor a specific volume in the combustion zone to track spatial fluctuations in the flame. The probe is capable of nanosecond time response and is usually slowed electronically to fit the flame characteristics. The probe is a sapphire rod in a stainless steel tube which may be inserted into the combustion chamber and pointed at the flame zone. The end of the sapphire rod is retracted into the SS tube to define a narrow optical collection cone. The collection cone may be adjusted to fit the experiment. The fluorescence signal is collected by the sapphire rod and transmitted through a UV transmitting, fused silica, fiber optic to the detector assembly. The detector is a side window photomultiplier (PMT) with a 310 run line filter. A Hamamatsu photomultiplier base combined with a integral high voltage power supply permits this to be a low voltage device. Electronic connections include: a power lead from a modular DC power supply for 15 VDC; a control lead for 0-1 volts to control the high voltage level (and therefore gain); and a lead out for the actual signal. All low voltage connections make this a safe and easy to use device while still delivering the sensitivity required.

  8. Hot gas handling device and motorized vehicle comprising the device

    NARCIS (Netherlands)

    Klein Geltink, J.; Beukers, A.; Van Tooren, M.J.L.; Koussios, S.

    2012-01-01

    The invention relates to a device for handling hot exhaust gasses discharged from an internal combustion engine. The device comprises a housing (2), enclosing a space (3) for transporting the exhaust gasses. The housing (2) is provided with an entrance - opening (4) for the exhaust gasses discharged

  9. Lectures on combustion theory

    Energy Technology Data Exchange (ETDEWEB)

    Burstein, S.Z.; Lax, P.D.; Sod, G.A. (eds.)

    1978-09-01

    Eleven lectures are presented on mathematical aspects of combustion: fluid dynamics, deflagrations and detonations, chemical kinetics, gas flows, combustion instability, flame spread above solids, spark ignition engines, burning rate of coal particles and hydrocarbon oxidation. Separate abstracts were prepared for three of the lectures. (DLC)

  10. Strobes: An Oscillatory Combustion

    NARCIS (Netherlands)

    Corbel, J.M.L.|info:eu-repo/dai/nl/341356034; van Lingen, J.N.J.|info:eu-repo/dai/nl/311441769; Zevenbergen, J.F.; Gijzeman, O.L.J.|info:eu-repo/dai/nl/073464708; Meijerink, A.|info:eu-repo/dai/nl/075044986

    2012-01-01

    Strobe compositions belong to the class of solid combustions. They are mixtures of powdered ingredients. When ignited, the combustion front evolves in an oscillatory fashion, and flashes of light are produced by intermittence. They have fascinated many scientists since their discovery at the

  11. Strobes: An oscillatory combustion

    NARCIS (Netherlands)

    Corbel, J.M.L.; Lingen, J.N.J. van; Zevenbergen, J.F.; Gijzeman, O.L.J.; Meijerink, A.

    2012-01-01

    Strobe compositions belong to the class of solid combustions. They are mixtures of powdered ingredients. When ignited, the combustion front evolves in an oscillatory fashion, and flashes of light are produced by intermittence. They have fascinated many scientists since their discovery at the

  12. Rocket Combustion Chamber Coating

    Science.gov (United States)

    Holmes, Richard R. (Inventor); McKechnie, Timothy N. (Inventor)

    2001-01-01

    A coating with the ability to protect (1) the inside wall (i.e., lining) of a rocket engine combustion chamber and (2) parts of other apparatuses that utilize or are exposed to combustive or high temperature environments. The novelty of this invention lies in the manner a protective coating is embedded into the lining.

  13. Improvement of energy efficiency of natural gas combustion by applying a homogeneous combustion

    Directory of Open Access Journals (Sweden)

    Szymczyk Jacek

    2017-01-01

    Full Text Available In many heat devices designers and operators meet the problem of low efficiency of combustion and restricted emission standards. This process should be improved to maximize its efficiency and satisfy additional requirements as, for example, uniform temperature fieldin combustion chamber, low noise level or very low NOx emission. These requirements are satisfied by homogeneous combustion. Such combustion method is particularly attractive for the steel or glass industry or power industry based in particular on natural gas. In this paper factors, which have the biggest influence on performance of flameless combustion, are discussed, among others: momentum of fuel and oxidizer, composition of the mixture, the temperature of the inlet gases. Additionally, blind simulations of combustion in a combustion chamber of a furnace are run to assess how high is the influence of these factors individually. Numerical simulations are performed in a CFD code AVL Fire. The detailed chemical kinetics mechanism GRI-mech 3.0 is used for combustion calculations. Calculations results are correlated with experimental data. Blind simulations and experiment provide similar level of NOX emission (~6-8 ppm. Experiments showed that the effect of the addition of ethylene to fuel on emissions of NOX, CO, THC is not significant. Similarly, numerical simulations predict that influence of ethylene is negligible. CO, THC and CO2 were on a stable level across all cases. NOX emissions increases when mass flow of air and fuel increases due to higher heat release in the same volume, what results in higher temperature of combustion products. When temperature of fuel increases NOX level decreases.

  14. PDF Modeling of Turbulent Combustion

    National Research Council Canada - National Science Library

    Pope, Stephen B

    2006-01-01

    .... The PDF approach to turbulent combustion has the advantages of fully representing the turbulent fluctuations of species and temperature, and of allowing realistic combustion chemistry to be implemented...

  15. Fuels and Combustion

    KAUST Repository

    Johansson, Bengt

    2016-08-17

    This chapter discusses the combustion processes and the link to the fuel properties that are suitable for them. It describes the basic three concepts, including spark ignition (SI) and compression ignition (CI), and homogeneous charge compression ignition (HCCI). The fuel used in a CI engine is vastly different from that in an SI engine. In an SI engine, the fuel should sustain high pressure and temperature without autoignition. Apart from the dominating SI and CI engines, it is also possible to operate with a type of combustion: autoignition. With HCCI, the fuel and air are fully premixed before combustion as in the SI engine, but combustion is started by the increased pressure and temperature during the compression stroke. Apart from the three combustion processes, there are also a few combined or intermediate concepts, such as Spark-Assisted Compression Ignition (SACI). Those concepts are discussed in terms of the requirements of fuel properties.

  16. The Principle of Energetic Consistency

    Science.gov (United States)

    Cohn, Stephen E.

    2009-01-01

    A basic result in estimation theory is that the minimum variance estimate of the dynamical state, given the observations, is the conditional mean estimate. This result holds independently of the specifics of any dynamical or observation nonlinearity or stochasticity, requiring only that the probability density function of the state, conditioned on the observations, has two moments. For nonlinear dynamics that conserve a total energy, this general result implies the principle of energetic consistency: if the dynamical variables are taken to be the natural energy variables, then the sum of the total energy of the conditional mean and the trace of the conditional covariance matrix (the total variance) is constant between observations. Ensemble Kalman filtering methods are designed to approximate the evolution of the conditional mean and covariance matrix. For them the principle of energetic consistency holds independently of ensemble size, even with covariance localization. However, full Kalman filter experiments with advection dynamics have shown that a small amount of numerical dissipation can cause a large, state-dependent loss of total variance, to the detriment of filter performance. The principle of energetic consistency offers a simple way to test whether this spurious loss of variance limits ensemble filter performance in full-blown applications. The classical second-moment closure (third-moment discard) equations also satisfy the principle of energetic consistency, independently of the rank of the conditional covariance matrix. Low-rank approximation of these equations offers an energetically consistent, computationally viable alternative to ensemble filtering. Current formulations of long-window, weak-constraint, four-dimensional variational methods are designed to approximate the conditional mode rather than the conditional mean. Thus they neglect the nonlinear bias term in the second-moment closure equation for the conditional mean. The principle of

  17. Combustion stability with baffles, absorbers and velocity sensitive combustion. [liquid propellant rocket combustors

    Science.gov (United States)

    Mitchell, C. E.

    1980-01-01

    Analytical and computational techniques were developed to predict the stability behavior of liquid propellant rocket combustors using damping devices such as acoustic liners, slot absorbers, and injector face baffles. Models were developed to determine the frequency and decay rate of combustor oscillations, the spatial and temporal pressure waveforms, and the stability limits in terms of combustion response model parameters.

  18. FY 1994 annual report. Advanced combustion science utilizing microgravity

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-10-01

    Researches on combustion in microgravity were conducted to develop combustion devices for advanced combustion techniques, and thereby to cope with the requirements for diversification of energy sources and abatement of environmental pollution by exhaust gases. This project was implemented under the research cooperation agreement with US's NASA, and the Japanese experts visited NASA's test facilities. NASA's Lewis Research Center has drop test facilities, of which the 2.2-sec drop test facilities are useful for researches by Japan. The cooperative research themes for combustion in microgravity selected include interactions between fuel droplets, high-pressure combustion of binary fuel sprays, and ignition and subsequent flame propagation in microgravity. An ignition test equipment, density field measurement equipment and flame propagation test equipment were constructed in Japan to conduct the combustion tests in microgravity for, e.g., combustion and evaporation of fuel droplets, combustion characteristics of liquid fuels mixed with solid particles, combustion of coal/oil mixture droplets, and estimating flammability limits. (NEDO)

  19. Periodic oscillations observed in swirling flows with and without combustion

    Science.gov (United States)

    Gouldin, F. C.; Halthore, R. N.; Vu, B. T.

    1985-01-01

    Data obtained by laser induced Rayleigh scattering and hot-wire anemometry are used to study periodic oscillations in swirling flows with and without combustion present. Power spectral density functions reveal the presence of energetic, periodic oscillations in the flow. A band of low frequency oscillations (25-100 Hz) is observed on and near the centerline in the presence of a recirculation zone and is attributed to axial oscillations of the recirculation zone which are amplified with combustion by an interaction between the mechanism for flow recirculation and flow changes induced by combustion. High frequency oscillations between 300-500 Hz are observed in an annular region located in the vortex core. A stability analysis is performed, and it is concluded that these oscillations are most likely helical waves resulting from hydrodynamic instability in the vortex core upstream of the test section.

  20. Energetic-electron-driven instability in the helically symmetric experiment.

    Science.gov (United States)

    Deng, C B; Brower, D L; Breizman, B N; Spong, D A; Almagri, A F; Anderson, D T; Anderson, F S B; Ding, W X; Guttenfelder, W; Likin, K M; Talmadge, J N

    2009-07-10

    Energetic electrons generated by electron cyclotron resonance heating are observed to drive instabilities in the quasihelically symmetric stellarator device. The coherent, global fluctuations peak in the plasma core and are measured in the frequency range of 20-120 kHz. Mode propagation is in the diamagnetic drift direction of the driving species. When quasihelical symmetry is broken, the mode is no longer observed. Experimental observations indicate that the unstable mode is acoustic rather than Alfvénic.

  1. Thermography of flame during diesel fuel combustion with steam gasification

    Science.gov (United States)

    Anufriev, I. S.; Arsentyev, S. S.; Agafontsev, M. V.; Kopyev, E. P.; Loboda, E. L.; Shadrin, E. Yu; Sharypov, O. V.

    2017-11-01

    The paper represents a study concerning the combustion of liquid hydrocarbon fuel in a perspective burner device with the controlled forced supply of overheated steam into the combustion zone, using diesel fuel. The thermal imaging measurements are conducted for the outer flame of the burner device in the wide range of regime parameters (flow rate and temperature of steam). A thermal imaging camera (FLIR, JADE J530SB) is used in the experiments. The effective emissivity coefficient of flame is obtained versus the flow rate of steam supplied. The steam parameters are found to influence on the temperature in the outer flame of the burner device.

  2. Liquid rocket combustion chamber acoustic characterization

    Directory of Open Access Journals (Sweden)

    Cândido Magno de Souza

    2010-09-01

    Full Text Available Over the last 40 years, many solid and liquid rocket motors have experienced combustion instabilities. Among other causes, there is the interaction of acoustic modes with the combustion and/or fluid dynamic processes inside the combustion chamber. Studies have been showing that, even if less than 1% of the available energy is diverted to an acoustic mode, combustion instability can be generated. On one hand, this instability can lead to ballistic pressure changes, couple with other propulsion systems such as guidance or thrust vector control, and in the worst case, cause motor structural failure. In this case, measures, applying acoustic techniques, must be taken to correct/minimize these influences on the combustion. The combustion chamber acoustic behavior in operating conditions can be estimated by considering its behavior in room conditions. In this way, acoustic tests can be easily performed, thus identifying the cavity modes. This paper describes the procedures to characterize the acoustic behavior in the inner cavity of four different configurations of a combustion chamber. Simple analytical models are used to calculate the acoustic resonance frequencies and these results are compared with acoustic natural frequencies measured at room conditions. Some comments about the measurement procedures are done, as well as the next steps for the continuity of this research. The analytical and experimental procedures results showed good agreement. However, limitations on high frequency band as well as in the identification of specific kinds of modes indicate that numerical methods able to model the real cavity geometry and an acoustic experimental modal analysis may be necessary for a more complete analysis. Future works shall also consider the presence of passive acoustic devices such as baffles and resonators capable of introducing damping and avoiding or limiting acoustic instabilities.

  3. Testing fireproof materials in a combustion chamber

    Directory of Open Access Journals (Sweden)

    Kulhavy Petr

    2017-01-01

    Full Text Available This article deals with a prototype concept, real experiment and numerical simulation of a combustion chamber, designed for testing fire resistance some new insulating composite materials. This concept of a device used for testing various materials, providing possibility of monitoring temperatures during controlled gas combustion. As a fuel for the combustion process propane butane mixture has been used and also several kinds of burners with various conditions of inlet air (forced, free and fuel flows were tested. The tested samples were layered sandwich materials based on various materials or foams, used as fillers in fire shutters. The temperature distribution was measured by using thermocouples. A simulation of whole concept of experimental chamber has been carried out as the non-premixed combustion process in the commercial final volume sw Pyrosim. The result was to design chamber with a construction suitable, according to the international standards, achieve the required values (temperature in time. Model of the combustion based on a stoichiometric defined mixture of gas and the tested layered samples showed good conformity with experimental results – i.e. thermal distribution inside and heat release rate that has gone through the sample.

  4. Testing fireproof materials in a combustion chamber

    Science.gov (United States)

    Kulhavy, Petr; Martinec, Tomas; Novak, Ondrej; Petru, Michal; Srb, Pavel

    This article deals with a prototype concept, real experiment and numerical simulation of a combustion chamber, designed for testing fire resistance some new insulating composite materials. This concept of a device used for testing various materials, providing possibility of monitoring temperatures during controlled gas combustion. As a fuel for the combustion process propane butane mixture has been used and also several kinds of burners with various conditions of inlet air (forced, free) and fuel flows were tested. The tested samples were layered sandwich materials based on various materials or foams, used as fillers in fire shutters. The temperature distribution was measured by using thermocouples. A simulation of whole concept of experimental chamber has been carried out as the non-premixed combustion process in the commercial final volume sw Pyrosim. The result was to design chamber with a construction suitable, according to the international standards, achieve the required values (temperature in time). Model of the combustion based on a stoichiometric defined mixture of gas and the tested layered samples showed good conformity with experimental results - i.e. thermal distribution inside and heat release rate that has gone through the sample.

  5. ENERGETIC REQUIREMENTS FOR GROWTH AND ...

    African Journals Online (AJOL)

    ENERGETICS OF CAPE GANNET. 311. TABLE 1. Mean food and energy intake, guano and energy excreted, metabolized energy and assimilation efficiency in hand-reared Cape gannet chicks. Food. Food. Energy. Guano. Energy. Age intake dry mas&! content. Energy excreted content. Ener8Y Metabolized Assimilation.

  6. A secular carbon debt from atmospheric high temperature combustion of stem wood?

    DEFF Research Database (Denmark)

    Czeskleba-Dupont, Rolf

    2012-01-01

    Basically, combustion of woody biomass in high temperature processes that react with atmospheric air results in a long lasting addition of carbon dioxide to the atmosphere. When harvesting large extra amounts of stem tree for energetic use, a global as well as secular time frame is needed to assess...

  7. Sandia Combustion Research: Technical review

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-07-01

    This report contains reports from research programs conducted at the Sandia Combustion Research Facility. Research is presented under the following topics: laser based diagnostics; combustion chemistry; reacting flow; combustion in engines and commercial burners; coal combustion; and industrial processing. Individual projects were processed separately for entry onto the DOE databases.

  8. Computational survey of representative energetic materials as propellants for microthruster applications

    Science.gov (United States)

    Fuchs, Brian; Stec, Daniel, III

    2007-04-01

    Microthrusters are critical for the development of terrestrial micromissiles and nano air vehicles for reconnaissance, surveillance, and sensor emplacement. With the maturation of MEMS manufacturing technology, the physical components of the thrusters can be readily fabricated. The thruster type that is the most straightforward is chemical combustion of a propellant that is ignited by a heating element giving a single shot thrust. Arrays of MEMS manufactured thrusters can be ganged to give multiple firings. The basic model for such a system is a solid rocket motor. The desired elements for the propellant of a chemical thruster are high specific impulse (I sp), high temperature and pressure, and low molecular weight combustion gases. Since the combustion chamber of a microthruster is extremely small, the propellant material must be able to ignite, sustain and complete its burn inside the chamber. The propellant can be either a solid or a liquid. There are a large number of energetic materials available as candidates for a propellant for microthrusters. There has been no systematic evaluation of the available energetic materials as propellant candidates for microthrusters. This report summarizes computations done on a series of energetic materials to address their suitabilities as microthruster propellants.

  9. Clean coal combustion in domestic sector

    Energy Technology Data Exchange (ETDEWEB)

    Dreszer, K.; Kubica, K.; Sciazko, M. [Institute for Chemical Processing of Coal, Zabrze (Poland)

    1998-12-31

    Combustion of raw coal in existing domestic furnaces with a low efficiency (usually below 50%) is a source of pollutants generation like dust, SO{sub 2} and PAH including cancerogenic BAP, resulting in serious environmental problems. Emission of pollutants depends on solid fuels quality and fuel combustion parameters. Pollutants emission can be decreased by the use of upgraded coal derived solid fuels or replacement of old heating appliances with new ones with high thermal efficiency and ecological affectivity. Several ecological fuels manufacturing methods have been elaborated in the Institute for Chemical Processing of Coal. Thermal and emission tests of heating devices and solid fuels were performed with the use of IChPW experimental plant. Results were confirmed in heating devices in real heating objects. Taking results into account proposal of legal regulation for Polish domestic sector was elaborated. 4 figs., 2 tabs.

  10. Clean coal combustion in domestic sector

    Energy Technology Data Exchange (ETDEWEB)

    Dreszer, K.; Kubica, K.; Sciazko, M. (Institute for Chemical Processing of Coal, Zabrze (Poland))

    1998-01-01

    Combustion of raw coal in existing domestic furnaces with a low efficiency (usually below 50%) is a source of pollutants generation like dust, SO[sub 2] and PAH including cancerogenic BAP, resulting in serious environmental problems. Emission of pollutants depends on solid fuels quality and fuel combustion parameters. Pollutants emission can be decreased by the use of upgraded coal derived solid fuels or replacement of old heating appliances with new ones with high thermal efficiency and ecological affectivity. Several ecological fuels manufacturing methods have been elaborated in the Institute for Chemical Processing of Coal. Thermal and emission tests of heating devices and solid fuels were performed with the use of IChPW experimental plant. Results were confirmed in heating devices in real heating objects. Taking results into account proposal of legal regulation for Polish domestic sector was elaborated. 4 figs., 2 tabs.

  11. Microelectromechanical safe arm device

    Science.gov (United States)

    Roesler, Alexander W [Tijeras, NM

    2012-06-05

    Microelectromechanical (MEM) apparatus and methods for operating, for preventing unintentional detonation of energetic components comprising pyrotechnic and explosive materials, such as air bag deployment systems, munitions and pyrotechnics. The MEM apparatus comprises an interrupting member that can be moved to block (interrupt) or complete (uninterrupt) an explosive train that is part of an energetic component. One or more latching members are provided that engage and prevent the movement of the interrupting member, until the one or more latching members are disengaged from the interrupting member. The MEM apparatus can be utilized as a safe and arm device (SAD) and electronic safe and arm device (ESAD) in preventing unintentional detonations. Methods for operating the MEM apparatus include independently applying drive signals to the actuators coupled to the latching members, and an actuator coupled to the interrupting member.

  12. Combustion Technology Outreach

    Science.gov (United States)

    1995-01-01

    Lewis' High Speed Research (HSR) Propulsion Project Office initiated a targeted outreach effort to market combustion-related technologies developed at Lewis for the next generation of supersonic civil transport vehicles. These combustion-related innovations range from emissions measurement and reduction technologies, to diagnostics, spray technologies, NOx and SOx reduction of burners, noise reduction, sensors, and fuel-injection technologies. The Ohio Aerospace Institute and the Great Lakes Industrial Technology Center joined forces to assist Lewis' HSR Office in this outreach activity. From a database of thousands of nonaerospace firms considered likely to be interested in Lewis' combustion and emission-related technologies, the outreach team selected 41 companies to contact. The selected companies represent oil-gas refineries, vehicle/parts suppliers, and manufacturers of residential furnaces, power turbines, nonautomobile engines, and diesel internal combustion engines.

  13. Influence of Small Furnaces Construction Type on TSP Emissions During Wood and Brown Coal Combustion

    Directory of Open Access Journals (Sweden)

    Jiří HORÁK

    2011-06-01

    Full Text Available Solid fuel burning household heat sources are considered to be significant producers of total suspended particulates (TSP. In the year 2005, c. 35% of the total particulate matter emissions PM10 (in The Czech Republic came out from household heating [1]. However, low-power combustion devices cannot be considered as identical pollution sources because they can operate on different combustion principles and feature dramatically different emission factors. The article presents results of an experimental determination of particulate matter emissions including TSP dividing into PM10 and PM2.5 fractions from wood and brown coal combustion in five types of combustion devices.

  14. The location of energetic compartments affects energetic communication in cardiomyocytes

    Directory of Open Access Journals (Sweden)

    Rikke eBirkedal

    2014-09-01

    Full Text Available The heart relies on accurate regulation of mitochondrial energy supply to match energy demand. The main regulators are Ca2+ and feedback of ADP and Pi. Regulation via feedback has intrigued for decades. First, the heart exhibits a remarkable metabolic stability. Second, diffusion of ADP and other molecules is restricted specifically in heart and red muscle, where a fast feedback is needed the most. To explain the regulation by feedback, compartmentalization must be taken into account. Experiments and theoretical approaches suggest that cardiomyocyte energetic compartmentalization is elaborate with barriers obstructing diffusion in the cytosol and at the level of the mitochondrial outer membrane (MOM. A recent study suggests the barriers are organized in a lattice with dimensions in agreement with those of intracellular structures. Here, we discuss the possible location of these barriers. The more plausible scenario includes a barrier at the level of MOM. Much research has focused on how the permeability of MOM itself is regulated, and the importance of the creatine kinase system to facilitate energetic communication. We hypothesize that at least part of the diffusion restriction at the MOM level is not by MOM itself, but due to the close physical association between the sarcoplasmic reticulum (SR and mitochondria. This will explain why animals with a disabled creatine kinase system exhibit rather mild phenotype modifications. Mitochondria are hubs of energetics, but also ROS production and signaling. The close association between SR and mitochondria may form a diffusion barrier to ADP added outside a permeabilised cardiomyocyte. But in vivo, it is the structural basis for the mitochondrial-SR coupling that is crucial for the regulation of mitochondrial Ca2+-transients to regulate energetics, and for avoiding Ca2+-overload and irreversible opening of the mitochondrial permeability transition pore.

  15. Sandia Combustion Research Program

    Energy Technology Data Exchange (ETDEWEB)

    Johnston, S.C.; Palmer, R.E.; Montana, C.A. (eds.)

    1988-01-01

    During the late 1970s, in response to a national energy crisis, Sandia proposed to the US Department of Energy (DOE) a new, ambitious program in combustion research. Shortly thereafter, the Combustion Research Facility (CRF) was established at Sandia's Livermore location. Designated a ''user facility,'' the charter of the CRF was to develop and maintain special-purpose resources to support a nationwide initiative-involving US inventories, industry, and national laboratories--to improve our understanding and control of combustion. This report includes descriptions several research projects which have been simulated by working groups and involve the on-site participation of industry scientists. DOE's Industry Technology Fellowship program, supported through the Office of Energy Research, has been instrumental in the success of some of these joint efforts. The remainder of this report presents results of calendar year 1988, separated thematically into eleven categories. Referred journal articles appearing in print during 1988 and selected other publications are included at the end of Section 11. Our traditional'' research activities--combustion chemistry, reacting flows, diagnostics, engine and coal combustion--have been supplemented by a new effort aimed at understanding combustion-related issues in the management of toxic and hazardous materials.

  16. Particle Emissions from Biomass Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Szpila, Aneta; Bohgard, Mats [Lund Inst. of Technology (Sweden). Div. of Ergonomics and Aerosol Technology; Strand, Michael; Lillieblad, Lena; Sanati, Mehri [Vaexjoe Univ. (Sweden). Div. of Bioenergy Technology; Pagels, Joakim; Rissler, Jenny; Swietlicki, Erik; Gharibi, Arash [Lund Univ. (Sweden). Div. of Nuclear Physics

    2003-05-01

    We have shown that high concentrations of fine particles of the order of 2-7x10{sup -7} particles per cm{sup 3} are being formed in all the combustion units studied. There was a higher difference between the units in terms of particle mass concentrations. While the largest differences was found for gas-phase constituents (CO and THC) and polyaromatic hydrocarbons. In 5 out of 7 studied units, multi-cyclones were the only measure for flue-gas separation. The multicyclones had negligible effect on the particle number concentration and a small effect on the mass of particles smaller than 5 {mu}m. The separation efficiency was much higher for the electrostatic precipitators. The boiler load had a dramatic influence on the coarse mode concentration during combustion of forest residue. PM0.8-6 increased from below 5 mg/m{sup 3} to above 50 mg/m{sup 3} even at a moderate change in boiler load from medium to high. A similar but less pronounced trend was found during combustion of dry wood. PM0.8-PM6 increased from 12 to 23 mg/m{sup 3} when the load was changed from low to high. When increasing the load, the primary airflow taken through the grate is increased; this itself may lead to a higher potential of the air stream to carry coarse particles away from the combustion zone. Measurements with APS-instrument with higher time-resolution showed a corresponding increase in coarse mode number concentration with load. Additional factor influencing observed higher concentration of coarse mode during combustion of forest residues, could be relatively high ash content in this type of fuel (2.2 %) in comparison to dry wood (0.3 %) and pellets (0.5 %). With increasing load we also found a decrease in PM1 during combustion of forest residue. Whether this is caused by scavenging of volatilized material by the high coarse mode concentration or a result of a different amount of volatilized material available for formation of fine particles needs to be shown in future studies. The

  17. Experimental facility for analysis of biomass combustion characteristics

    Directory of Open Access Journals (Sweden)

    Miljković Biljana M.

    2015-01-01

    Full Text Available The objective of the present article is to present an experimental facility which was designed and built at the Faculty of Technical Sciences in order to study the combustion of different sorts of biomass and municipal solid waste. Despite its apparent simplicity, direct combustion is a complex process from a technological point of view. Conventional combustion equipment is not designed for burning agricultural residues. Devices for agricultural waste combustion are still in the development phase, which means that adequate design solution is presently not available at the world market. In order to construct a boiler and achieve optimal combustion conditions, it is necessary to develop a mathematical model for biomass combustion. Experimental facility can be used for the collection of data necessary for detailed modelling of real grate combustor of solid biomass fuels. Due to the complexity of the grate combustion process, its mathematical models and simulation software tools must be developed and verified using experimental data. This work highlights the properties required for the laboratory facility designed for the examination of biomass combustion and discusses design and operational issues.

  18. The energetic significance of cooking.

    Science.gov (United States)

    Carmody, Rachel N; Wrangham, Richard W

    2009-10-01

    While cooking has long been argued to improve the diet, the nature of the improvement has not been well defined. As a result, the evolutionary significance of cooking has variously been proposed as being substantial or relatively trivial. In this paper, we evaluate the hypothesis that an important and consistent effect of cooking food is a rise in its net energy value. The pathways by which cooking influences net energy value differ for starch, protein, and lipid, and we therefore consider plant and animal foods separately. Evidence of compromised physiological performance among individuals on raw diets supports the hypothesis that cooked diets tend to provide energy. Mechanisms contributing to energy being gained from cooking include increased digestibility of starch and protein, reduced costs of digestion for cooked versus raw meat, and reduced energetic costs of detoxification and defence against pathogens. If cooking consistently improves the energetic value of foods through such mechanisms, its evolutionary impact depends partly on the relative energetic benefits of non-thermal processing methods used prior to cooking. We suggest that if non-thermal processing methods such as pounding were used by Lower Palaeolithic Homo, they likely provided an important increase in energy gain over unprocessed raw diets. However, cooking has critical effects not easily achievable by non-thermal processing, including the relatively complete gelatinisation of starch, efficient denaturing of proteins, and killing of food borne pathogens. This means that however sophisticated the non-thermal processing methods were, cooking would have conferred incremental energetic benefits. While much remains to be discovered, we conclude that the adoption of cooking would have led to an important rise in energy availability. For this reason, we predict that cooking had substantial evolutionary significance.

  19. Computational Studies of Energetic Nitramines

    Science.gov (United States)

    1991-09-11

    not readily be treated by means of the electrostatic potential because the effects of the nuclei are so strong that they often mask local maxima that...Results", Technical Report Submitted to ONR, March 1987. 2. P. Politzer, J. S. Murray, M. E. Grice and P. Sjoberg, in Chemistr of Energetic Materials...S. Murray, Trans Amer. Cryst. Assoc. 26, in press. 44. J. S. Murray, T. Brinck, M. E. Grice and P. Politzer, J. Mol. Struct. (Theochem), in press

  20. Nano Engineered Energetic Materials (NEEM)

    Science.gov (United States)

    2011-01-12

    assembly of nano-engineered energetic materials (NEEMs), which will also provide concurrent improvement in performance and managed energy release while...thermodynamic reaction limit. These results were corroborated by tandem XPS measurements on similar systems. Depositions carried out an elevated...degree of supersaturation and the seeded particles should act as a nucleation catalysis . Therefore, the metastable RDX wants to nucleate onto anything in

  1. Process for preparing energetic materials

    Science.gov (United States)

    Simpson, Randall L [Livermore, CA; Lee, Ronald S [Livermore, CA; Tillotson, Thomas M [Tracy, CA; Hrubesh, Lawrence W [Pleasanton, CA; Swansiger, Rosalind W [Livermore, CA; Fox, Glenn A [Livermore, CA

    2011-12-13

    Sol-gel chemistry is used for the preparation of energetic materials (explosives, propellants and pyrotechnics) with improved homogeneity, and/or which can be cast to near-net shape, and/or made into precision molding powders. The sol-gel method is a synthetic chemical process where reactive monomers are mixed into a solution, polymerization occurs leading to a highly cross-linked three dimensional solid network resulting in a gel. The energetic materials can be incorporated during the formation of the solution or during the gel stage of the process. The composition, pore, and primary particle sizes, gel time, surface areas, and density may be tailored and controlled by the solution chemistry. The gel is then dried using supercritical extraction to produce a highly porous low density aerogel or by controlled slow evaporation to produce a xerogel. Applying stress during the extraction phase can result in high density materials. Thus, the sol-gel method can be used for precision detonator explosive manufacturing as well as producing precision explosives, propellants, and pyrotechnics, along with high power composite energetic materials.

  2. Modeling internal ballistics of gas combustion guns.

    Science.gov (United States)

    Schorge, Volker; Grossjohann, Rico; Schönekess, Holger C; Herbst, Jörg; Bockholdt, Britta; Ekkernkamp, Axel; Frank, Matthias

    2016-05-01

    Potato guns are popular homemade guns which work on the principle of gas combustion. They are usually constructed for recreational rather than criminal purposes. Yet some serious injuries and fatalities due to these guns are reported. As information on the internal ballistics of homemade gas combustion-powered guns is scarce, it is the aim of this work to provide an experimental model of the internal ballistics of these devices and to investigate their basic physical parameters. A gas combustion gun was constructed with a steel tube as the main component. Gas/air mixtures of acetylene, hydrogen, and ethylene were used as propellants for discharging a 46-mm caliber test projectile. Gas pressure in the combustion chamber was captured with a piezoelectric pressure sensor. Projectile velocity was measured with a ballistic speed measurement system. The maximum gas pressure, the maximum rate of pressure rise, the time parameters of the pressure curve, and the velocity and path of the projectile through the barrel as a function of time were determined according to the pressure-time curve. The maximum gas pressure was measured to be between 1.4 bar (ethylene) and 4.5 bar (acetylene). The highest maximum rate of pressure rise was determined for hydrogen at (dp/dt)max = 607 bar/s. The muzzle energy was calculated to be between 67 J (ethylene) and 204 J (acetylene). To conclude, this work provides basic information on the internal ballistics of homemade gas combustion guns. The risk of injury to the operator or bystanders is high, because accidental explosions of the gun due to the high-pressure rise during combustion of the gas/air mixture may occur.

  3. Chemical Dynamics, Molecular Energetics, and Kinetics at the Synchrotron

    Energy Technology Data Exchange (ETDEWEB)

    Leone, Stephen R.; Ahmed, Musahid; Wilson, Kevin R.

    2010-03-14

    Scientists at the Chemical Dynamics Beamline of the Advanced Light Source in Berkeley are continuously reinventing synchrotron investigations of physical chemistry and chemical physics with vacuum ultraviolet light. One of the unique aspects of a synchrotron for chemical physics research is the widely tunable vacuum ultraviolet light that permits threshold ionization of large molecules with minimal fragmentation. This provides novel opportunities to assess molecular energetics and reaction mechanisms, even beyond simple gas phase molecules. In this perspective, significant new directions utilizing the capabilities at the Chemical Dynamics Beamline are presented, along with an outlook for future synchrotron and free electron laser science in chemical dynamics. Among the established and emerging fields of investigations are cluster and biological molecule spectroscopy and structure, combustion flame chemistry mechanisms, radical kinetics and product isomer dynamics, aerosol heterogeneous chemistry, planetary and interstellar chemistry, and secondary neutral ion-beam desorption imaging of biological matter and materials chemistry.

  4. Environmentally conscious coal combustion

    Energy Technology Data Exchange (ETDEWEB)

    Hickmott, D.D.; Brown, L.F.; Currier, R.P. [and others

    1997-08-01

    This is the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The objective of this project was to evaluate the environmental impacts of home-scale coal combustion on the Navajo Reservation and develop strategies to reduce adverse health effects associated with home-scale coal combustion. Principal accomplishments of this project were: (1) determination of the metal and gaseous emissions of a representative stove on the Navajo Reservation; (2) recognition of cyclic gaseous emissions in combustion in home-scale combustors; (3) `back of the envelope` calculation that home-scale coal combustion may impact Navajo health; and (4) identification that improved coal stoves require the ability to burn diverse feedstocks (coal, wood, biomass). Ultimately the results of Navajo home-scale coal combustion studies will be extended to the Developing World, particularly China, where a significant number (> 150 million) of households continue to heat their homes with low-grade coal.

  5. Combustion and regulation; Combustion et reglementation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    This conference was organized after the publication of the French by-law no 2010 relative to combustion installations and to the abatement of atmospheric pollution. Five topics were discussed during the conference: the new regulations, their content, innovations and modalities of application; the means of energy suppliers to face the new provisions and their schedule; the manufacturers proposals for existing installations and the new equipments; the administration control; and the impact of the new measures on exploitation and engineering. Twenty papers and 2 journal articles are reported in these proceedings. (J.S.)

  6. Combustible structural composites and methods of forming combustible structural composites

    Science.gov (United States)

    Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D.; Swank, W. David

    2013-04-02

    Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

  7. Simulation of lean premixed turbulent combustion

    Energy Technology Data Exchange (ETDEWEB)

    Bell, John B.; Day, Marcus S.; Almgren, Ann S.; Lijewski, MichaelJ.; Rendleman, Charles A.; Cheng, Robert K.; Shepherd, Ian G.

    2006-06-25

    There is considerable technological interest in developingnew fuel-flexible combustion systems that can burn fuels such ashydrogenor syngas. Lean premixed systems have the potential to burn thesetypes of fuels with high efficiency and low NOx emissions due to reducedburnt gas temperatures. Although traditional scientific approaches basedon theory and laboratory experiment have played essential roles indeveloping our current understanding of premixed combustion, they areunable to meet the challenges of designing fuel-flexible lean premixedcombustion devices. Computation, with itsability to deal with complexityand its unlimited access to data, hasthe potential for addressing thesechallenges. Realizing this potential requires the ability to perform highfidelity simulations of turbulent lean premixed flames under realisticconditions. In this paper, we examine the specialized mathematicalstructure of these combustion problems and discuss simulation approachesthat exploit this structure. Using these ideas we can dramatically reducecomputational cost, making it possible to perform high-fidelitysimulations of realistic flames. We illustrate this methodology byconsidering ultra-lean hydrogen flames and discuss how this type ofsimulation is changing the way researchers study combustion.

  8. Internal combustion engine

    Science.gov (United States)

    Baker, Quentin A.; Mecredy, Henry E.; O'Neal, Glenn B.

    1991-01-01

    An improved engine is provided that more efficiently consumes difficult fuels such as coal slurries or powdered coal. The engine includes a precombustion chamber having a portion thereof formed by an ignition plug. The precombustion chamber is arranged so that when the piston is proximate the head, the precombustion chamber is sealed from the main cylinder or the main combustion chamber and when the piston is remote from the head, the precombustion chamber and main combustion chamber are in communication. The time for burning of fuel in the precombustion chamber can be regulated by the distance required to move the piston from the top dead center position to the position wherein the precombustion chamber and main combustion chamber are in communication.

  9. Simulation study of high-frequency energetic particle driven geodesic acoustic mode

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hao, E-mail: wanghao@nifs.ac.jp; Ido, Takeshi; Osakabe, Masaki [National Institute for Fusion Science, Toki 509-5292 (Japan); Todo, Yasushi [National Institute for Fusion Science, Toki 509-5292 (Japan); The Graduate University for Advanced Studies, Toki 509-5292 (Japan)

    2015-09-15

    High-frequency energetic particle driven geodesic acoustic modes (EGAM) observed in the large helical device plasmas are investigated using a hybrid simulation code for energetic particles and magnetohydrodynamics (MHD). Energetic particle inertia is incorporated in the MHD momentum equation for the simulation where the beam ion density is comparable to the bulk plasma density. Bump-on-tail type beam ion velocity distribution created by slowing down and charge exchange is considered. It is demonstrated that EGAMs have frequencies higher than the geodesic acoustic modes and the dependence on bulk plasma temperature is weak if (1) energetic particle density is comparable to the bulk plasma density and (2) charge exchange time (τ{sub cx}) is sufficiently shorter than the slowing down time (τ{sub s}) to create a bump-on-tail type distribution. The frequency of high-frequency EGAM rises as the energetic particle pressure increases under the condition of high energetic particle pressure. The frequency also increases as the energetic particle pitch angle distribution shifts to higher transit frequency. It is found that there are two kinds of particles resonant with EGAM: (1) trapped particles and (2) passing particles with transit frequency close to the mode frequency. The EGAMs investigated in this work are destabilized primarily by the passing particles whose transit frequencies are close to the EGAM frequency.

  10. Fluidised Bed Combustion: A Novel Technology for the Combustion ...

    African Journals Online (AJOL)

    A firing technology, which is increasingly becoming popular for the combustion of fuels with difficult combustion properties, is fluidised bed combustion (FBC). In the current paper, the special features of FBC have been reviewed and their advantages as compared to conventional firing systems highlighted. This has been ...

  11. Alcohol combustion chemistry

    KAUST Repository

    Sarathy, Mani

    2014-10-01

    Alternative transportation fuels, preferably from renewable sources, include alcohols with up to five or even more carbon atoms. They are considered promising because they can be derived from biological matter via established and new processes. In addition, many of their physical-chemical properties are compatible with the requirements of modern engines, which make them attractive either as replacements for fossil fuels or as fuel additives. Indeed, alcohol fuels have been used since the early years of automobile production, particularly in Brazil, where ethanol has a long history of use as an automobile fuel. Recently, increasing attention has been paid to the use of non-petroleum-based fuels made from biological sources, including alcohols (predominantly ethanol), as important liquid biofuels. Today, the ethanol fuel that is offered in the market is mainly made from sugar cane or corn. Its production as a first-generation biofuel, especially in North America, has been associated with publicly discussed drawbacks, such as reduction in the food supply, need for fertilization, extensive water usage, and other ecological concerns. More environmentally friendly processes are being considered to produce alcohols from inedible plants or plant parts on wasteland. While biofuel production and its use (especially ethanol and biodiesel) in internal combustion engines have been the focus of several recent reviews, a dedicated overview and summary of research on alcohol combustion chemistry is still lacking. Besides ethanol, many linear and branched members of the alcohol family, from methanol to hexanols, have been studied, with a particular emphasis on butanols. These fuels and their combustion properties, including their ignition, flame propagation, and extinction characteristics, their pyrolysis and oxidation reactions, and their potential to produce pollutant emissions have been intensively investigated in dedicated experiments on the laboratory and the engine scale

  12. Scramjet Combustion Processes

    Science.gov (United States)

    2010-09-01

    Propulsion a vitesse elevee : Conception du moteur - integration et gestion thermique ) 14. ABSTRACT 15. SUBJECT TERMS 16. SECURITY CLASSIFICATION OF...entrance to the combustion duct, where the production of the chemical radicals, which are a first stage in Scramjet Combustion Processes RTO-EN-AVT-185...314KM) Nosecone Eject (47SEC,73KM,M7.7) Orion Burnout (39SEC,56KM,M7.1) Orion Ignition (12SEC,9.4KM,M3.2) Terrier Ignition (0SEC,0KM,M0) Stage

  13. Radiative Augmented Combustion.

    Science.gov (United States)

    1985-08-12

    86-0085 In 00I to RADIATIVE AUGMENTED COMBUSTION MOSHE LAVID M.L. ENERGIA , INC. P.O. BOX 1468 1 PRINCETON, NEW JERSEY 08542 AUGUST 1985 *.. plo...Combustion conducted at M.L. ENERGIA . It is funded by the Air Force Office of Scientific Research under Contract No. F49620-83-C-0133, with Dr. J.M...reported. It covers the second year of the contract, from July 15, 1984 through July 14, 1985. The work was performed at ENERGIA , Princeton, New Jersey

  14. Studies in combustion dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Koszykowski, M.L. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01

    The goal of this program is to develop a fundamental understanding and a quantitative predictive capability in combustion modeling. A large part of the understanding of the chemistry of combustion processes comes from {open_quotes}chemical kinetic modeling.{close_quotes} However, successful modeling is not an isolated activity. It necessarily involves the integration of methods and results from several diverse disciplines and activities including theoretical chemistry, elementary reaction kinetics, fluid mechanics and computational science. Recently the authors have developed and utilized new tools for parallel processing to implement the first numerical model of a turbulent diffusion flame including a {open_quotes}full{close_quotes} chemical mechanism.

  15. Toxicology of Biodiesel Combustion products

    Science.gov (United States)

    1. Introduction The toxicology of combusted biodiesel is an emerging field. Much of the current knowledge about biological responses and health effects stems from studies of exposures to other fuel sources (typically petroleum diesel, gasoline, and wood) incompletely combusted. ...

  16. Energetics of the midlatitude thermosphere

    Science.gov (United States)

    Stolarski, R. S.

    1976-01-01

    Thermospheric energetics is examined from the point of view of atomic and molecular processes which convert solar EUV radiative energy into kinetic energy of the ambient electron, ion, and neutral gases. The energy flow from photon to photoelectron-ion pair through energy loss and ion-molecule transfer to eventual electron-ion recombination is traced in detail. Upper and lower bounds are placed on the efficiency of conversion of radiative to thermal energy. Implications for the question of consistency of measured solar EUV fluxes and ionospheric models are discussed.

  17. Energetics, physiology and vertebrate ecology.

    Science.gov (United States)

    Karasov, W H

    1986-10-01

    The magnitude of energy flow through individual animals and their populations is potentially limited by several physiological factors. These include thermal constraints affecting the time available for foraging, physiological design constraints affecting foraging mode and the rate of prey capture, and digestive constraints on how much food can be processed per day. Over short periods (hours or less), maximal rates of metabolism may determine survival during exposure to cold or when fleeing predators. Energetics, physiology and ecology can be usefully integrated within the context of the concept of maximum rate of energy flow. Copyright © 1986. Published by Elsevier Ltd.

  18. Energetic particles in the heliosphere

    CERN Document Server

    Simnett, George M

    2017-01-01

    This monograph traces the development of our understanding of how and where energetic particles are accelerated in the heliosphere and how they may reach the Earth. Detailed data sets are presented which address these topics. The bulk of the observations are from spacecraft in or near the ecliptic plane. It is timely to present this subject now that Voyager-1 has entered the true interstellar medium. Since it seems unlikely that there will be a follow-on to the Voyager programme any time soon, the data we already have regarding the outer heliosphere are not going to be enhanced for at least 40 years.

  19. Fuel-Rich Catalytic Combustion

    Science.gov (United States)

    Brabbs, Theodore A.; Olson, Sandra L.

    1987-01-01

    Two-stage combustion system reduces particulate emissions. Program on catalytic oxidation of iso-octane demonstrates feasibility of two-stage combustion system for reducing particulate emissions. With fuel-rich (fuel/air equivalence ratios of 4.8 to 7.8) catalytic-combustion preburner as first stage, combustion process free of soot at reactor-outlet temperatures of 1,200 K or less.

  20. Coal combustion research

    Energy Technology Data Exchange (ETDEWEB)

    Daw, C.S.

    1996-06-01

    This section describes research and development related to coal combustion being performed for the Fossil Energy Program under the direction of the Morgantown Energy Technology Center. The key activity involves the application of chaos theory for the diagnosis and control of fossil energy processes.

  1. Nonlinear Combustion Instability Prediction

    Science.gov (United States)

    Flandro, Gary

    2010-01-01

    The liquid rocket engine stability prediction software (LCI) predicts combustion stability of systems using LOX-LH2 propellants. Both longitudinal and transverse mode stability characteristics are calculated. This software has the unique feature of being able to predict system limit amplitude.

  2. Supersonic Combustion Ramjet Research

    Science.gov (United States)

    2012-08-01

    engine). As noted above in USAF scramjet flight scenarios , high vehicle heat loads will ensure that the fuel (initially a liquid hydrocarbon such as a... cinema stereoscopic PIV system for the measurement of micro- and meso-scale turbulent premixed flame dynamics,” Paper B13, 5th US Combustion

  3. Solar Energetic Particle Warnings from a Coronagraph

    Science.gov (United States)

    St Cyr, O. C.; Posner, A.; Burkepile, J. T.

    2017-01-01

    We report here the concept of using near-real time observations from a coronagraph to provide early warning of a fast coronal mass ejection (CME) and the possible onset of a solar energetic particle (SEP) event. The 1 January 2016, fast CME, and its associated SEP event are cited as an example. The CME was detected by the ground-based K-Cor coronagraph at Mauna Loa Solar Observatory and by the SOHO Large Angle and Spectrometric Coronagraph. The near-real-time availability of the high-cadence K-Cor observations in the low corona leads to an obvious question: Why has no one attempted to use a coronagraph as an early warning device for SEP events? The answer is that the low image cadence and the long latency of existing spaceborne coronagraphs make them valid for archival studies but typically unsuitable for near-real-time forecasting. The January 2016 event provided favorable CME viewing geometry and demonstrated that the primary component of a prototype ground-based system for SEP warnings is available several hours on most days. We discuss how a conceptual CME-based warning system relates to other techniques, including an estimate of the relative SEP warning times, and how such a system might be realized.

  4. An ignition and combustion supporting burner for pulverized solid fossil fuel comprising of a combustion chamber with main burners. Bruleur d'allumage et de soutien de combustion pour combustible solide fossile pulverise, et chambre de combustion comportant de tels bruleurs

    Energy Technology Data Exchange (ETDEWEB)

    Vidal, J.; Malaubier, F.; Mevel, J-C.

    1989-01-25

    An ignition and combustion supporting burner for pulverized solid fuel, comprising: (a) a refractory-tap-hole shaped to allow the confinement of the initial portion of the flame, (b) a conduit for feeding pulverized solid fuel into a primary oxidegas, disposed coaxially to the refractory tap-hole, (c) a first annular conduit for feeding a first portion of secondary combustive gas, equipped at its end with means for creating a turbulent flow of the combustive gas, (d) a second annular conduit for feeding a second portion of secondary combustive gas, equipped at its end with means for creating a turbulent flow of the combustive gas, (e) a conduit for feeding tertiary combustive gas, this conduit partially or entirely surrounding the tap-hole and being supplied at a rate sufficient for ensuring, complementary to the flowrates of the primary and secondary combustive gas, the total combustion of the solid fuel, (f) an ignition element disposed in the refractory tap-hole or in the axial conduit for feeding pulverized fossil fuel, characterized in that the conduit for feeding pulverized solid fuels is provided with translation mean; allowing to adjust the length of the chamber for premixing the solid fuel with the first portion of secondary combustive gas comprised between the end of this conduit and the inlet of the tap-hole, and that a flame detection device is disposed near its tap-hole.

  5. Energetic materials and methods of tailoring electrostatic discharge sensitivity of energetic materials

    Energy Technology Data Exchange (ETDEWEB)

    Daniels, Michael A.; Heaps, Ronald J.; Wallace, Ronald S.; Pantoya, Michelle L.; Collins, Eric S.

    2016-11-01

    An energetic material comprising an elemental fuel, an oxidizer or other element, and a carbon nanofiller or carbon fiber rods, where the carbon nanofiller or carbon fiber rods are substantially homogeneously dispersed in the energetic material. Methods of tailoring the electrostatic discharge sensitivity of an energetic material are also disclosed.

  6. Sulfur Chemistry in Combustion I

    DEFF Research Database (Denmark)

    Johnsson, Jan Erik; Glarborg, Peter

    2000-01-01

    Most fossil fuels contain sulphur and also biofuels and household waste have a sulphur content. As a consequence sulphur species will often be present in combustion processes. In this paper the fate and influence of fuel sulphur species in combustion will be treated. First a description...... of the sulphur compounds in fossil fuels and the possibilities to remove them will be given. Then the combustion of sulphur species and their influence on the combustion chemistry and especially on the CO oxidation and the NOx formation will be described. Finally the in-situ removal of sulphur in the combustion...

  7. Low emission internal combustion engine

    Science.gov (United States)

    Karaba, Albert M.

    1979-01-01

    A low emission, internal combustion compression ignition engine having a cylinder, a piston movable in the cylinder and a pre-combustion chamber communicating with the cylinder near the top thereof and in which low emissions of NO.sub.x are achieved by constructing the pre-combustion chamber to have a volume of between 70% and 85% of the combined pre-chamber and main combustion chamber volume when the piston is at top dead center and by variably controlling the initiation of fuel injection into the pre-combustion chamber.

  8. The Reactivity of Energetic Materials At Extreme Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Fried, L E

    2006-10-23

    Energetic materials are unique for having a strong exothermic reactivity, which has made them desirable for both military and commercial applications. Energetic materials are commonly divided into high explosives, propellants, and pyrotechnics. We will focus on high explosive (HE) materials here, although there is a great deal of commonality between the classes of energetic materials. Although the history of HE materials is long, their condensed-phase properties are poorly understood. Understanding the condensed-phase properties of HE materials is important for determining stability and performance. Information regarding HE material properties (for example, the physical, chemical, and mechanical behaviors of the constituents in plastic-bonded explosive, or PBX, formulations) is necessary for efficiently building the next generation of explosives as the quest for more powerful energetic materials (in terms of energy per volume) moves forward. In modeling HE materials there is a need to better understand the physical, chemical, and mechanical behaviors from fundamental theoretical principles. Among the quantities of interest in plastic-bonded explosives (PBXs), for example, are thermodynamic stabilities, reaction kinetics, equilibrium transport coefficients, mechanical moduli, and interfacial properties between HE materials and the polymeric binders. These properties are needed (as functions of stress state and temperature) for the development of improved micro-mechanical models, which represent the composite at the level of grains and binder. Improved micro-mechanical models are needed to describe the responses of PBXs to dynamic stress or thermal loading, thus yielding information for use in developing continuum models. Detailed descriptions of the chemical reaction mechanisms of condensed energetic materials at high densities and temperatures are essential for understanding events that occur at the reactive front under combustion or detonation conditions. Under

  9. Influence of intake air temperature on internal combustion engine operation

    Science.gov (United States)

    Birtok-Băneasă, C.; Raţiu, S.; Hepuţ, T.

    2017-01-01

    This paper presents three methods for reduce thermal losses in the intake system with improvement of airflow and thermal protection. In the experiment are involved two patented devices conceived by the author and one PhD theme device: 1- Dynamic device for air transfer, 2-Integrated thermal deflector, and, 3-Advanced thermal protection. The tests were carried on different vehicle running in real traffic and in the Internal Combustion Engines Laboratory, within the specialization “Road vehicle” belonging to the Faculty of Engineering Hunedoara, component of Politehnica University of Timişoara. The results have been processed and compared whit the ones obtained without these devices.

  10. Alternative Energetics DC Microgrid With Hydrogen Energy Storage System

    Directory of Open Access Journals (Sweden)

    Zaļeskis Genadijs

    2016-12-01

    Full Text Available This paper is related to an alternative energetics microgrid with a wind generator and a hydrogen energy storage system. The main aim of this research is the development of solutions for effective use of the wind generators in alternative energetics devices, at the same time providing uninterrupted power supply of the critical loads. In this research, it was accepted that the alternative energetics microgrid operates in an autonomous mode and the connection to the conventional power grid is not used. In the case when wind speed is low, the necessary power is provided by the energy storage system, which includes a fuel cell and a tank with stored hydrogen. The theoretical analysis of the storage system operation is made. The possible usage time of the stored hydrogen depends on the available amount of hydrogen and the consumption of the hydrogen by the fuel cell. The consumption, in turn, depends on used fuel cell power. The experimental results suggest that if the wind generator can provide only a part of the needed power, the abiding power can be provided by the fuel cell. In this case, a load filter is necessary to decrease the fuel cell current pulsations.

  11. Fluid Mud in Energetic Systems: FLUMES II

    Science.gov (United States)

    2014-09-30

    FINAL REPORT Fluid Mud in Energetic Systems: FLUMES II Gail C. Kineke Dept of...the dynamics of fluid mud and its role in the transport and deposition of sediment in coastal environments. In particular, we sought greater...understanding of the processes that influence the formation and maintenance of fluid mud in energetic environments. OBJECTIVES The research is a process

  12. Energetic model of metal hardening

    Directory of Open Access Journals (Sweden)

    Ignatova O.N.

    2011-01-01

    Full Text Available Based on Bailey hypothesis on the link between strain hardening and elastic lattice defect energy this paper suggests a shear strength energetic model that takes into consideration plastic strain intensity and rate as well as softening related to temperature annealing and dislocation annihilation. Metal strain hardening was demonstrated to be determined only by elastic strain energy related to the energy of accumulated defects. It is anticipated that accumulation of the elastic energy of defects is governed by plastic work. The suggested model has a reasonable agreement with the available experimental data for copper up to P = 70 GPa , for aluminum up to P = 10 GPa and for tantalum up to P = 20 GPa.

  13. Multiscale measurement of cardiac energetics.

    Science.gov (United States)

    Goo, Soyeon; Pham, Toan; Han, Jun-Chiew; Nielsen, Poul; Taberner, Andrew; Hickey, Anthony; Loiselle, Denis

    2013-09-01

    Herein we describe our laboratories' experimental methods for interrogating cardiac energetics at the organ (whole heart), tissue (trabecula) and perforated fibre (mitochondrial) levels. In whole heart and trabecula experiments, we focus on measuring pressure-volume (force-length) work and oxygen consumption (heat production) from which mechanical efficiency is derived. In both preparations (i.e. across scales differing by three orders of magnitude) we find efficiency values of 10%-15%. Mitochondrial experiments invoke a trio of titration protocols to yield information on oxygen consumption, ATP flux, membrane potential, electron leak and reactive oxygen species production, the latter two of which index energy transfer inefficiencies. Copyright © 2013 Wiley Publishing Asia Pty Ltd.

  14. Cosmic Ray Energetics and Mass

    CERN Multimedia

    Baylon cardiel, J L; Wallace, K C; Anderson, T B; Copley, M

    The cosmic-ray energetics and mass (CREAM) investigation is designed to measure cosmic-ray composition to the supernova energy scale of 10$^{15}$ eV in a series of ultra long duration balloon (ULDB) flights. The first flight is planned to be launched from Antarctica in December 2004. The goal is to observe cosmic-ray spectral features and/or abundance changes that might signify a limit to supernova acceleration. The particle ($\\{Z}$) measurements will be made with a timing-based charge detector and a pixelated silicon charge detector to minimize the effect of backscatter from the calorimeter. The particle energy measurements will be made with a transition radiation detector (TRD) for $\\{Z}$ > 3 and a sampling tungsten/scintillator calorimeter for $\\{Z}$ $\\geq$1 particles, allowing inflight cross calibration of the two detectors. The status of the payload construction and flight preparation are reported in this paper.

  15. Aerosols from biomass combustion

    Energy Technology Data Exchange (ETDEWEB)

    Nussbaumer, T.

    2001-07-01

    This report is the proceedings of a seminar on biomass combustion and aerosol production organised jointly by the International Energy Agency's (IEA) Task 32 on bio energy and the Swiss Federal Office of Energy (SFOE). This collection of 16 papers discusses the production of aerosols and fine particles by the burning of biomass and their effects. Expert knowledge on the environmental impact of aerosols, formation mechanisms, measurement technologies, methods of analysis and measures to be taken to reduce such emissions is presented. The seminar, visited by 50 participants from 11 countries, shows, according to the authors, that the reduction of aerosol emissions resulting from biomass combustion will remain a challenge for the future.

  16. Fluid-bed combustion

    Energy Technology Data Exchange (ETDEWEB)

    Hunt, G.; Schoebotham, N.

    1981-02-01

    In Energy Equipment Company's two-stage fluidized bed system, partial combustion in a fluidized bed is followed by burn-off of the generated gases above the bed. The system can be retrofitted to existing boilers, and can burn small, high ash coal efficiently. It has advantages when used as a hot gas generator for process drying. Tests on a boiler at a Cadbury Schweppes plant are reported.

  17. Premixed Supersonic Combustion (Rev)

    Science.gov (United States)

    2015-02-20

    lean and low temperature flameout points). Figure 11. Chemiluminescence image (0.6 ms capture) at global φ = 0.41 (cavity-side = 0.27...mixing can still be rate-controlling if the flow temperature is high or if a flame holder is present and there is an adequate source of combustion... temperature associated with kinetic energy and ΔTc is the change in temperature associated with the chemistry [3]. If the rise in temperature

  18. Theory of Combustion Noise

    Science.gov (United States)

    1973-07-01

    The overall sound generation processes have been classi- fied in terms of the sound due to an isolated turbulent flame and that due to the...of the fluid mechanics of the reacting gas. The overall sound generation processes have been classified in terms of the sound due to an isolated ...steady intercoupling between various aerothermochemical modes excited in the combustion zone. To be specific, the non-steady exo- thermic and

  19. Combustion science and engineering

    CERN Document Server

    Annamalai, Kalyan

    2006-01-01

    Introduction and Review of Thermodynamics Introduction Combustion Terminology Matter and Its Properties Microscopic Overview of Thermodynamics Conservation of Mass and Energy and the First Law of Thermodynamics The Second Law of Thermodynamics Summary Stoichiometry and Thermochemistry of Reacting Systems Introduction Overall Reactions Gas Analyses Global Conservation Equations for Reacting Systems Thermochemistry Summary Appendix Reaction Direction and Equilibrium Introduction Reaction Direction and Chemical Equilibrium Chemical Equilibrium Relations Vant Hoff Equation Adi

  20. Combustion Characteristics of Sprays

    Science.gov (United States)

    1989-08-01

    regarded by implication or otherwise, or in any way licensing the holder or any other person or corporation, or conveying any rights or permission to...00 _’N 1. TI TLE inctuat Security CZaaafication5 Combustion Characteristics of Sprays 12. PERSONAL AUTHOR(S) Sohrab, Siavash H. 13& TYPE OF REPORT...to ?!HF of rich butane/air 3unsen flames. .lso, the rotacion speed and :he oerodic temDeracure fluc:uations of rotacfng ?HF are examined. :’!naily

  1. Internal combustion piston engines

    Energy Technology Data Exchange (ETDEWEB)

    Segaser, C.L.

    1977-07-01

    Current worldwide production of internal combustion piston engines includes many diversified types of designs and a very broad range of sizes. Engine sizes range from a few horsepower in small mobile units to over 40,000 brake horsepower in large stationary and marine units. The key characteristics of internal combustion piston engines considered appropriate for use as prime movers in Integrated Community Energy Systems (ICES) are evaluated. The categories of engines considered include spark-ignition gas engines, compression-ignition oil (diesel) engines, and dual-fuel engines. The engines are evaluated with respect to full-load and part-load performance characteristics, reliability, environmental concerns, estimated 1976 cost data, and current and future status of development. The largest internal combustion piston engines manufactured in the United States range up to 13,540 rated brake horsepower. Future development efforts are anticipated to result in a 20 to 25% increase in brake horsepower without increase in or loss of weight, economy, reliability, or life expectancy, predicated on a simple extension of current development trends.

  2. Issues in waste combustion

    Energy Technology Data Exchange (ETDEWEB)

    Gustavsson, Lennart; Robertson, Kerstin; Tullin, Claes [Swedish National Testing and Research Inst., Boraas (Sweden); Sundquist, Lena; Wrangensten, Lars [AaF-Energikonsult AB, Stockholm (Sweden); Blom, Elisabet [AaF-Processdesign AB, Stockholm (Sweden)

    2003-05-01

    The main purpose of this review is to provide an overview of the state-of-the-art on research and development issues related to waste combustion with relevance for Swedish conditions. The review focuses on co-combustion in grate and fluidised bed furnaces. It is primarily literature searches in relevant databases of scientific publications with to material published after 1995. As a complement, findings published in different report series, have also been included. Since the area covered by this report is very wide, we do not claim to cover the issues included completely and it has not been possitile to evaluate the referred studies in depth. Basic knowledge about combustion issues is not included since such information can be found elsewhere in the literature. Rather, this review should be viewed as an overview of research and development in the waste-to-energy area and as such we hope that it will inspire scientists and others to further work in relevant areas.

  3. Spray combustion stability

    Science.gov (United States)

    Liang, Pak-Yan; Jeng, S. M.; Litchford, Ronald

    1995-01-01

    The central purpose of this project is the improvement of liquid-fueled rocket motor design technology in order to assist the establishment of economical commercial access to space through the development of engines with enhanced performance and reliability. Specific research effort in the project is focused on spray physics and associated combustion instability phenomena. Results garnered from this work will contribute to the development of new computational tools for design of stable liquid propellant rocket engines. The specific objectives of the research effort include identifying and evaluating physical submodels which pertain to spray combustion stability with the idea of enhancing or refining existing submodels with a more comprehensive approach. In particular, any refinements to the spray combustion physical submodels which are achieved during the project will be channeled back to Rocketdyne for incorporation in their ARICC liquid rocket combustor code as second generation improvements. Also, as the ARICC code forms the basis or future CFD development, some effort is devoted to an evaluation of the code's capability for modeling oscillating pressure waves within the combustor.

  4. The Diesel Combustion Collaboratory: Combustion Researchers Collaborating over the Internet

    Energy Technology Data Exchange (ETDEWEB)

    C. M. Pancerella; L. A. Rahn; C. Yang

    2000-02-01

    The Diesel Combustion Collaborator (DCC) is a pilot project to develop and deploy collaborative technologies to combustion researchers distributed throughout the DOE national laboratories, academia, and industry. The result is a problem-solving environment for combustion research. Researchers collaborate over the Internet using DCC tools, which include: a distributed execution management system for running combustion models on widely distributed computers, including supercomputers; web-accessible data archiving capabilities for sharing graphical experimental or modeling data; electronic notebooks and shared workspaces for facilitating collaboration; visualization of combustion data; and video-conferencing and data-conferencing among researchers at remote sites. Security is a key aspect of the collaborative tools. In many cases, the authors have integrated these tools to allow data, including large combustion data sets, to flow seamlessly, for example, from modeling tools to data archives. In this paper the authors describe the work of a larger collaborative effort to design, implement and deploy the DCC.

  5. Internal combustion engine using premixed combustion of stratified charges

    Science.gov (United States)

    Marriott, Craig D [Rochester Hills, MI; Reitz, Rolf D [Madison, WI

    2003-12-30

    During a combustion cycle, a first stoichiometrically lean fuel charge is injected well prior to top dead center, preferably during the intake stroke. This first fuel charge is substantially mixed with the combustion chamber air during subsequent motion of the piston towards top dead center. A subsequent fuel charge is then injected prior to top dead center to create a stratified, locally richer mixture (but still leaner than stoichiometric) within the combustion chamber. The locally rich region within the combustion chamber has sufficient fuel density to autoignite, and its self-ignition serves to activate ignition for the lean mixture existing within the remainder of the combustion chamber. Because the mixture within the combustion chamber is overall premixed and relatively lean, NO.sub.x and soot production are significantly diminished.

  6. Development of flameless combustion; Desarrollo de la combustion sin flama

    Energy Technology Data Exchange (ETDEWEB)

    Flores Sauceda, M. Leonardo; Cervantes de Gortari, Jaime Gonzalo [Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico)]. E-mail: 8344afc@prodigy.net.mx; jgonzalo@servidor.unam.mx

    2010-11-15

    The paper intends contribute to global warming mitigation joint effort that develops technologies to capture the CO{sub 2} produced by fossil fuels combustion and to reduce emission of other greenhouse gases like the NO{sub x}. After reviewing existing combustion bibliography is pointed out that (a) touches only partial aspects of the collective system composed by Combustion-Heat transfer process-Environment, whose interactions are our primary interest and (b) most specialists think there is not yet a clearly winning technology for CO{sub 2} capture and storage. In this paper the study of combustion is focused as integrated in the aforementioned collective system where application of flameless combustion, using oxidant preheated in heat regenerators and fluent gas recirculation into combustion chamber plus appropriated heat and mass balances, simultaneously results in energy saving and environmental impact reduction. [Spanish] El trabajo pretende contribuir al esfuerzo conjunto de mitigacion del calentamiento global que aporta tecnologias para capturar el CO{sub 2} producido por la combustion de combustibles fosiles y para disminuir la emision de otros gases invernadero como NOx. De revision bibliografica sobre combustion se concluye que (a) trata aspectos parciales del sistema compuesto por combustion-proceso de trasferencia de calor-ambiente, cuyas interacciones son nuestro principal interes (b) la mayoria de especialistas considera no hay todavia una tecnologia claramente superior a las demas para captura y almacenaje de CO{sub 2}. Se estudia la combustion como parte integrante del mencionado sistema conjunto, donde la aplicacion de combustion sin flama, empleando oxidante precalentado mediante regeneradores de calor y recirculacion de gases efluentes ademas de los balances de masa y energia adecuados, permite tener simultaneamente ahorros energeticos e impacto ambiental reducido.

  7. Fuel properties to enable lifted-flame combustion

    Energy Technology Data Exchange (ETDEWEB)

    Kurtz, Eric [Ford Motor Company, Dearborn, MI (United States)

    2015-03-15

    The Fuel Properties to Enable Lifted-Flame Combustion project responded directly to solicitation DE-FOA-0000239 AOI 1A, Fuels and Lubricants for Advanced Combustion Regimes. This subtopic was intended to encompass clean and highly-efficient, liquid-fueled combustion engines to achieve extremely low engine-out nitrogen oxides (NOx) and particulate matter (PM) as a target and similar efficiency as state-of-the-art direct injection diesel engines. The intent of this project was to identify how fuel properties can be used to achieve controllable Leaner Lifted Flame Combustion (LLFC) with low NOx and PM emissions. Specifically, this project was expected to identify and test key fuel properties to enable LLFC and their compatibility with current fuel systems and to enhance combustion models to capture the effect of fuel properties on advanced combustion. Successful demonstration of LLFC may reduce the need for after treatment devices, thereby reducing costs and improving thermal efficiency. The project team consisted of key technical personnel from Ford Motor Company (FMC), the University of Wisconsin-Madison (UW), Sandia National Laboratories (SNL) and Lawrence Livermore National Laboratories (LLNL). Each partner had key roles in achieving project objectives. FMC investigated fuel properties relating to LLFC and sooting tendency. Together, FMC and UW developed and integrated 3D combustion models to capture fuel property combustion effects. FMC used these modeling results to develop a combustion system and define fuel properties to support a single-cylinder demonstration of fuel-enabled LLFC. UW investigated modeling the flame characteristics and emissions behavior of different fuels, including those with different cetane number and oxygen content. SNL led spray combustion experiments to quantify the effect of key fuel properties on combustion characteristics critical for LLFC, as well as single cylinder optical engine experiments to improve fundamental

  8. Energetic Particle Loss Estimates in W7-X

    Science.gov (United States)

    Lazerson, Samuel; Akaslompolo, Simppa; Drevlak, Micheal; Wolf, Robert; Darrow, Douglass; Gates, David; W7-X Team

    2017-10-01

    The collisionless loss of high energy H+ and D+ ions in the W7-X device are examined using the BEAMS3D code. Simulations of collisionless losses are performed for a large ensemble of particles distributed over various flux surfaces. A clear loss cone of particles is present in the distribution for all particles. These simulations are compared against slowing down simulations in which electron impact, ion impact, and pitch angle scattering are considered. Full device simulations allow tracing of particle trajectories to the first wall components. These simulations provide estimates for placement of a novel set of energetic particle detectors. Recent performance upgrades to the code are allowing simulations with > 1000 processors providing high fidelity simulations. Speedup and future works are discussed. DE-AC02-09CH11466.

  9. Combustion mechanism of high energy composite propellants (V). Combustion of azide/nitramine propellants

    Energy Technology Data Exchange (ETDEWEB)

    Mazaki, H.; Iida, A.; Mitarai, Y. [Asahi Chemical Industry Co. Ltd., Osaka (Japan)

    1998-01-01

    Theoretical and experimental studies have been carried out on the combustion of azide polymers used as a binder in high-energy propellants. AMMO (3-azidemethyl-3`-methyloxetane) is one of the energetic azide polymers which contain N3 groups in their molecular structures. EDNA (ethylenedinitramine) is a linear nitramine which has modest properties in the flame temperature and the molecular weight of burned gases as compared with HMX (cyclotetramethylenetetranitramine) and NQ (nitroguanidine). In this study, the burning rate characteristics of azide/nitramine propellants were investigated in order to gain a wide spectrum of burning rate. As a result, the burning rate of AMMO/EDNA propellant is higher than that of AMMO/HMX propellant and the pressure exponent of AMMO/EDNA propellant is lower than that of AMMO/HMX propellant. Both AMMO/EDNA and AMMO/HMX propellants exhibited the same combustion wave structure as inert polymer/nitramine propellants. The burning surface temperature and the temperature at the end of the first-stage reaction zone for AMMO/EDNA and AMMO/HMX propellants are approximately the same in the pressure range between 1.0 and 5.0 MPa. 12 refs., 7 figs., 2 tabs.

  10. Piezoelectric Ignition of Nanocomposite Energetic Materials

    Science.gov (United States)

    2013-01-01

    Sensitivity, Piezoelectric Crystals, Nanoparticles, Thermites Eric Collins, Michelle L Pantoya, Andreas Neuber, Michael Daniels, Daniel Prentice...use of PZT as an alternative ignition source. Key Words: Aluminum, Ignition, Combustion, Piezocrystal, Nanoparticles, Thermites ... thermites ,” Combustion and Flame, vol. 138, no. 4, pp. 373–383, Sep. 2004. [13] T. Bazyn, N. Glumac, H. Krier, T. S. Ward, M. Schoenitz, and E. L

  11. Combustion from basics to applications

    CERN Document Server

    Lackner, Maximilian; Winter, Franz

    2013-01-01

    Combustion, the process of burning, is defined as a chemical reaction between a combustible reactant (the fuel) and an oxidizing agent (such as air) in order to produce heat and in most cases light while new chemical species (e.g., flue gas components) are formed. This book covers a gap on the market by providing a concise introduction to combustion. Most of the other books currently available are targeted towards the experienced users and contain too many details and/or contain knowledge at a fairly high level. This book provides a brief and clear overview of the combustion basics, suitable f

  12. The modes of gaseous combustion

    CERN Document Server

    Rubtsov, Nickolai M

    2016-01-01

    This book provides an analysis of contemporary problems in combustion science, namely flame propagation, detonation and heterophaseous combustion based on the works of the author. The current problems in the area of gas combustion, as well as the methods allowing to calculate and estimate limiting conditions of ignition, and flame propagation on the basis of experimental results are considered. The book focuses on the virtually inaccessible works of Russian authors and will be useful for experienced students and qualified scientists in the area of experimental studies of combustion processes.

  13. Active Combustion Control Valve Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Over the past decade, research into active combustion control has yielded impressive results in suppressing thermoacoustic instabilities and widening the operational...

  14. Light Duty Efficient, Clean Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Stanton, Donald W. [Cummins Inc., Columbus, IN (United States)

    2011-06-03

    Cummins has successfully completed the Light Duty Efficient Clean Combustion (LDECC) cooperative program with DoE. This program was established in 2007 in support of the Department of Energy’s Vehicles Technologies Advanced Combustion and Emissions Control initiative to remove critical barriers to the commercialization of advanced, high efficiency, emissions compliant internal combustion (IC) engines for light duty vehicles. Work in this area expanded the fundamental knowledge of engine combustion to new regimes and advanced the knowledge of fuel requirements for these diesel engines to realize their full potential. All of our objectives were met with fuel efficiency improvement targets exceeded.

  15. Mathematical Modeling in Combustion Science

    CERN Document Server

    Takeno, Tadao

    1988-01-01

    An important new area of current research in combustion science is reviewed in the contributions to this volume. The complicated phenomena of combustion, such as chemical reactions, heat and mass transfer, and gaseous flows, have so far been studied predominantly by experiment and by phenomenological approaches. But asymptotic analysis and other recent developments are rapidly changing this situation. The contributions in this volume are devoted to mathematical modeling in three areas: high Mach number combustion, complex chemistry and physics, and flame modeling in small scale turbulent flow combustion.

  16. Microgravity Smoldering Combustion Takes Flight

    Science.gov (United States)

    1996-01-01

    The Microgravity Smoldering Combustion (MSC) experiment lifted off aboard the Space Shuttle Endeavour in September 1995 on the STS-69 mission. This experiment is part of series of studies focused on the smolder characteristics of porous, combustible materials in a microgravity environment. Smoldering is a nonflaming form of combustion that takes place in the interior of combustible materials. Common examples of smoldering are nonflaming embers, charcoal briquettes, and cigarettes. The objective of the study is to provide a better understanding of the controlling mechanisms of smoldering, both in microgravity and Earth gravity. As with other forms of combustion, gravity affects the availability of air and the transport of heat, and therefore, the rate of combustion. Results of the microgravity experiments will be compared with identical experiments carried out in Earth's gravity. They also will be used to verify present theories of smoldering combustion and will provide new insights into the process of smoldering combustion, enhancing our fundamental understanding of this frequently encountered combustion process and guiding improvement in fire safety practices.

  17. Performance of CdZnTe detectors passivated with energetic oxygen atoms

    Energy Technology Data Exchange (ETDEWEB)

    Prettyman, T.H.; Hoffbauer, M.A.; Rennie, J. [and others

    1998-12-01

    Noise caused by surface-leakage current can degrade the performance of CdZnTe spectrometers, particularly devices with closely spaced contacts such as coplanar grid detectors. In order to reduce surface leakage, the authors are treating CdZnTe detector surfaces with energetic, neutral oxygen atoms. Energetic oxygen atoms react with the surface to form a resistive oxide layer. Because the reaction is effective at room temperature, deleterious heating of the substrate is avoided. In most cases, leakage current and noise are shown to decrease significantly after treatment. The effect of the treatment on the performance of coplanar grid detectors is presented.

  18. Volumetric Combustion Diagnostics

    Science.gov (United States)

    2017-01-03

    i.e., the central plane of the burner and the plane where the PLIF measurement was taken) was extracted and plotted in Fig. 7b. Fig. 7c directly...Hsu, Particle Image Velocimetry in a Nonreacting and Reacting High-Speed Cavity, Journal of Propulsion and Power, 30(3) (2014) 576-591. [7] Y.W...quantitative laser sensors to kinetics, propulsion and practical energy systems, Proceedings of the Combustion Institute, 33(1) (2011) 1-40. [13] A.W

  19. Alternate fuels; Combustibles alternos

    Energy Technology Data Exchange (ETDEWEB)

    Romero Paredes R, Hernando; Ambriz G, Juan Jose [Universidad Autonoma Metropolitana. Iztapalapa (Mexico)

    2003-07-01

    In the definition and description of alternate fuels we must center ourselves in those technological alternatives that allow to obtain compounds that differ from the traditional ones, in their forms to be obtained. In this article it is tried to give an overview of alternate fuels to the conventional derivatives of petroleum and that allow to have a clear idea on the tendencies of modern investigation and the technological developments that can be implemented in the short term. It is not pretended to include all the tendencies and developments of the present world, but those that can hit in a relatively short term, in accordance with agreed with the average life of conventional fuels. Nevertheless, most of the conversion principles are applicable to the spectrum of carbonaceous or cellulosic materials which are in nature, are cultivated or wastes of organic origin. Thus one will approach them in a successive way, the physical, chemical and biological conversions that can take place in a production process of an alternate fuel or the same direct use of the fuel such as burning the sweepings derived from the forests. [Spanish] En la definicion y descripcion de combustibles alternos nos debemos centrar en aquellas alternativas tecnologicas que permitan obtener compuestos que difieren de los tradicionales, al menos en sus formas de ser obtenidos. En este articulo se pretende dar un panorama de los combustibles alternos a los convencionales derivados del petroleo y que permita tener una idea clara sobre las tendencias de la investigacion moderna y los desarrollos tecnologicos que puedan ser implementados en el corto plazo. No se pretende abarcar todas las tendencias y desarrollos del mundo actual, sino aquellas que pueden impactar en un plazo relativamente corto, acordes con la vida media de los combustibles convencionales. Sin embargo, la mayor parte de los principios de conversion son aplicables al espectro de materiales carbonaceos o celulosicos los cuales se

  20. Combustion Stratification for Naphtha from CI Combustion to PPC

    KAUST Repository

    Vallinayagam, R.

    2017-03-28

    This study demonstrates the combustion stratification from conventional compression ignition (CI) combustion to partially premixed combustion (PPC). Experiments are performed in an optical CI engine at a speed of 1200 rpm for diesel and naphtha (RON = 46). The motored pressure at TDC is maintained at 35 bar and fuelMEP is kept constant at 5.1 bar to account for the difference in fuel properties between naphtha and diesel. Single injection strategy is employed and the fuel is injected at a pressure of 800 bar. Photron FASTCAM SA4 that captures in-cylinder combustion at the rate of 10000 frames per second is employed. The captured high speed video is processed to study the combustion homogeneity based on an algorithm reported in previous studies. Starting from late fuel injection timings, combustion stratification is investigated by advancing the fuel injection timings. For late start of injection (SOI), a direct link between SOI and combustion phasing is noticed. At early SOI, combustion phasing depends on both intake air temperature and SOI. In order to match the combustion phasing (CA50) of diesel, the intake air temperature is increased to 90°C for naphtha. The combustion stratification from CI to PPC is also investigated for various level of dilution by displacing oxygen with nitrogen in the intake. The start of combustion (SOC) was delayed with the increase in dilution and to compensate for this, the intake air temperature is increased. The mixture homogeneity is enhanced for higher dilution due to longer ignition delay. The results show that high speed image is initially blue and then turned yellow, indicating soot formation and oxidation. The luminosity of combustion images decreases with early SOI and increased dilution. The images are processed to generate the level of stratification based on the image intensity. The level of stratification is same for diesel and naphtha at various SOI. When O concentration in the intake is decreased to 17.7% and 14

  1. Global Positioning System (GPS) Energetic Particle Data

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Energetic particle data from the CXD and BDD instrument on the GPS constellation are available to the space weather research community. The release of these data...

  2. Energetic particle observations at the subsolar magnetopause

    Directory of Open Access Journals (Sweden)

    A. A. Eccles

    2002-04-01

    Full Text Available The pitch-angle distributions (PAD of energetic particles are examined as the ISEE-1 satellite crosses the Earth’s magnetopause near the subsolar point. The investigation focuses on the possible existence of a particular type of distribution that would be associated with a source of energetic particles in the high-latitude magnetosphere. PADs, demonstrating broad, persistent field-aligned fluxes filling a single hemisphere (upper/northern or lower/southern, were observed just sunward of the magnetopause current layer for an extended period of many minutes. These distributions are a direct prediction of a possible source of energetic particles located in the high altitude dayside cusp and we present five examples in detail of the three-dimensional particle distributions to demonstrate their existence. From these results, other possible causes of such PADs are examined.Key words. Magnetospheric physics (energetic particles, precipitating; magnetopause, cusp and boundary layers; magnetospheric configuration and dynamics

  3. Energetic salt of trinitrophloroglucinol and melamine

    Science.gov (United States)

    Bowden, Patrick R.; Leonard, Philip W.; Lichthardt, Joseph P.; Tappan, Bryce C.; Ramos, Kyle J.

    2017-01-01

    We hope to harness the field of energetic co-crystals for development of insensitive, high-performing explosives. As demonstrated by other groups, co-crystals of energetic materials are diverse in their resultant properties versus the native materials. Herein, we discuss the synthesis, characterization, and testing of an energetic co-crystal of trinitrophloroglucinol (1,3,5-trihydroxy-2,4,6-trinitrobenzene) and melamine. Although melamine is not an energetic material, high nitrogen content and insensitivity can be of benefit in a co-crystal. Currently, trinitrophloroglucinol (TNPG) and melamine have been found to exist as a 1:1 ionic co-crystal. Characterization by NMR, IR, small-scale sensitivity, thermal stability and powder X-ray diffraction have all been used to characterize the individual compounds as well as the co-crystals developed.

  4. Some Factors Affecting Combustion in an Internal-Combustion Engine

    Science.gov (United States)

    Rothrock, A M; Cohn, Mildred

    1936-01-01

    An investigation of the combustion of gasoline, safety, and diesel fuels was made in the NACA combustion apparatus under conditions of temperature that permitted ignition by spark with direct fuel injection, in spite of the compression ratio of 12.7 employed. The influence of such variables as injection advance angle, jacket temperature, engine speed, and spark position was studied. The most pronounced effect was that an increase in the injection advance angle (beyond a certain minimum value) caused a decrease in the extent and rate of combustion. In almost all cases combustion improved with increased temperature. The results show that at low air temperatures the rates of combustion vary with the volatility of the fuel, but that at high temperatures this relationship does not exist and the rates depend to a greater extent on the chemical nature of the fuel.

  5. AIR EMISSIONS FROM SCRAP TIRE COMBUSTION

    Science.gov (United States)

    The report discusses air emissions from two types of scrap tire combustion: uncontrolled and controlled. Uncontrolled sources are open tire fires, which produce many unhealthful products of incomplete combustion and release them directly into the atmosphere. Controlled combustion...

  6. Plasma igniter for internal-combustion engines

    Science.gov (United States)

    Breshears, R. R.; Fitzgerald, D. J.

    1978-01-01

    Hot ionized gas (plasma) ignites air/fuel mixture in internal combustion engines more effectively than spark. Electromagnetic forces propel plasma into combustion zone. Combustion rate is not limited by flame-front speed.

  7. Photoactive energetic materials: linear and nonlinear photochemistry of chromophore linked energetic materials

    Science.gov (United States)

    Greenfield, Margo; McGrane, Shawn; Bolme, Cindy; Chavez, David; Veauthier, Jacqueline; Hanson, Susan; Myers, Thomas; Scharff, Jason

    2015-06-01

    In general, conventional molecular explosives are white to off-white in color and only absorb ultraviolet light. A novel approach to synthetically link optically active energetic chromophores to existing molecular energetic materials has resulted in increased photoactivity in the visible (532 nm) region of the electromagnetic spectrum. Tetrazine, an energetic optically active chromophore, which absorbs around 532 nm, has been derivatized with various energetic materials including pentaeythritol tetranitrate (PETN), nitroglycerine (NG) and dinitroazetidine (DNAZ). We report the corresponding photochemistry and photochemical quantum yields of these new materials under various wavelength and intensity regimes.

  8. Combustion of Methane Hydrate

    Science.gov (United States)

    Roshandell, Melika

    A significant methane storehouse is in the form of methane hydrates on the sea floor and in the arctic permafrost. Methane hydrates are ice-like structures composed of water cages housing a guest methane molecule. This caged methane represents a resource of energy and a potential source of strong greenhouse gas. Most research related to methane hydrates has been focused on their formation and dissociation because they can form solid plugs that complicate transport of oil and gas in pipelines. This dissertation explores the direct burning of these methane hydrates where heat from the combustion process dissociates the hydrate into water and methane, and the released methane fuels the methane/air diffusion flame heat source. In contrast to the pipeline applications, very little research has been done on the combustion and burning characteristics of methane hydrates. This is the first dissertation on this subject. In this study, energy release and combustion characteristics of methane hydrates were investigated both theoretically and experimentally. The experimental study involved collaboration with another research group, particularly in the creation of methane hydrate samples. The experiments were difficult because hydrates form at high pressure within a narrow temperature range. The process can be slow and the resulting hydrate can have somewhat variable properties (e.g., extent of clathration, shape, compactness). The experimental study examined broad characteristics of hydrate combustion, including flame appearance, burning time, conditions leading to flame extinguishment, the amount of hydrate water melted versus evaporated, and flame temperature. These properties were observed for samples of different physical size. Hydrate formation is a very slow process with pure water and methane. The addition of small amounts of surfactant increased substantially the hydrate formation rate. The effects of surfactant on burning characteristics were also studied. One finding

  9. Manifold methods for methane combustion

    Energy Technology Data Exchange (ETDEWEB)

    Yang, B.; Pope, S.B. [Cornell Univ., Ithaca, NY (United States)

    1995-10-01

    Great progresses have been made in combustion research, especially, the computation of laminar flames and the probability density function (PDF) method in turbulent combustion. For one-dimensional laminar flames, by considering the transport mechanism, the detailed chemical kinetic mechanism and the interactions between these two basic processes, today it is a routine matter to calculate flame velocities, extinction, ignition, temperature, and species distributions from the governing equations. Results are in good agreement with those obtained for experiments. However, for turbulent combustion, because of the complexities of turbulent flow, chemical reactions, and the interaction between them, in the foreseeable future, it is impossible to calculate the combustion flow field by directly integrating the basic governing equations. So averaging and modeling are necessary in turbulent combustion studies. Averaging, on one hand, simplifies turbulent combustion calculations, on the other hand, it introduces the infamous closure problems, especially the closure problem with chemical reaction terms. Since in PDF calculations of turbulent combustion, the averages of the chemical reaction terms can be calculated, PDF methods overcome the closure problem with the reaction terms. It has been shown that the PDF method is a most promising method to calculate turbulent combustion. PDF methods have been successfully employed to calculate laboratory turbulent flames: they can predict phenomena such as super equilibrium radical levels, and local extinction. Because of these advantages, PDF methods are becoming used increasingly in industry combustor codes.

  10. Liquid propellant rocket combustion instability

    Science.gov (United States)

    Harrje, D. T.

    1972-01-01

    The solution of problems of combustion instability for more effective communication between the various workers in this field is considered. The extent of combustion instability problems in liquid propellant rocket engines and recommendations for their solution are discussed. The most significant developments, both theoretical and experimental, are presented, with emphasis on fundamental principles and relationships between alternative approaches.

  11. Combustion & Laser Diagnostics Research Complex (CLDRC)

    Data.gov (United States)

    Federal Laboratory Consortium — Description: The Combustion and Laser Diagnostics Research Complex (CLRDC) supports the experimental and computational study of fundamental combustion phenomena to...

  12. 29 CFR 1926.154 - Temporary heating devices.

    Science.gov (United States)

    2010-07-01

    ... 29 Labor 8 2010-07-01 2010-07-01 false Temporary heating devices. 1926.154 Section 1926.154 Labor... Temporary heating devices. (a) Ventilation. (1) Fresh air shall be supplied in sufficient quantities to... heating devices shall be installed to provide clearance to combustible material not less than the amount...

  13. High Temperature Chemical Kinetic Combustion Modeling of Lightly Methylated Alkanes

    Energy Technology Data Exchange (ETDEWEB)

    Sarathy, S M; Westbrook, C K; Pitz, W J; Mehl, M

    2011-03-01

    Conventional petroleum jet and diesel fuels, as well as alternative Fischer-Tropsch (FT) fuels and hydrotreated renewable jet (HRJ) fuels, contain high molecular weight lightly branched alkanes (i.e., methylalkanes) and straight chain alkanes (n-alkanes). Improving the combustion of these fuels in practical applications requires a fundamental understanding of large hydrocarbon combustion chemistry. This research project presents a detailed high temperature chemical kinetic mechanism for n-octane and three lightly branched isomers octane (i.e., 2-methylheptane, 3-methylheptane, and 2,5-dimethylhexane). The model is validated against experimental data from a variety of fundamental combustion devices. This new model is used to show how the location and number of methyl branches affects fuel reactivity including laminar flame speed and species formation.

  14. Creation of electromechanical device for electric vehicle traction

    Directory of Open Access Journals (Sweden)

    Денис Юрьевич Зубенко

    2016-10-01

    Full Text Available The problems of creation of electromechanical device for electric vehicle traction are considered in the article. The aim of creation this design are the replacement of the internal combustion engine on electromechanical device. For this electromechanical device are constructed model, which describe processes that occur in the electric drive of electromechanical device. Characteristics of the main modes of motion were recorded. The introduction of electromechanical device will reduce the level of emissions and reduce noise in the cities

  15. Aspen Simulation of Diesel-Biodiesel Blends Combustion

    Directory of Open Access Journals (Sweden)

    Pérez-Sánchez Armando

    2015-01-01

    Full Text Available Biodiesel is a fuel produced by transesterification of vegetable oils or animal fats, which currently is gaining attention as a diesel substitute. It represents an opportunity to reduce CO2, SO2, CO, HC, PAH and PM emissions and contributes to the diversification of fuels in Mexico's energetic matrix. The results of the simulation of the combustion process are presented in this paper with reference to an engine specification KUBOTA D600-B, operated with diesel-biodiesel blends. The physicochemical properties of the compounds and the operating conditions of equipment were developed using the simulator Aspen® and supplementary information. The main aspects of the engine working conditions were considered such as diesel-biodiesel ratio, air/fuel mixture, temperature of the combustion gases and heat load. Diesel physicochemical specifications were taken from reports of PEMEX and SENER. Methyl esters corresponding to the transesterification of fatty acids that comprise castor oil were regarded as representative molecules of biodiesel obtained from chromatographic analysis. The results include CO2, water vapor, combustion efficiency, power and lower calorific value of fuels.

  16. Co-combustion of coal and meat and bone meal

    Energy Technology Data Exchange (ETDEWEB)

    I. Gulyurtlu; D. Boavida; P. Abelha; M.H. Lopes; I. Cabrita [DEECA-INETI, Lisbon (Portugal)

    2005-12-01

    Feeding meat and bone meal (MBM) to cattle, sheep or other animals has been banned within the EU since 1 of July 1994. The quantities to be eliminated are measured in millions of tons. Disposal to landfill is not an option, as simply burying the material cannot destroy any potential bovine spongiform encephalopathy (BSE) pathogens. One disposal option is the co-combustion of coal and MBM, to ensure that any living organism is totally thermally destroyed and at the same time valorising its energetic potential. Fluidised bed co-combustion of MBM is considered a viable technological option as it has the flexibility to burn coal with different materials in an efficient way, at relatively low temperatures (750-850{sup o}C) with lower environmental impact. For this purpose, co-combustion tests of coal and MBM were carried out on a pilot scale FBC, to investigate the implications of the results. This involved the determination of the emissions of pollutants like NOx, N{sub 2}O, VOC, CO{sub 2}, as well as the composition and the valorisation of the ashes produced. The ashes from the bed, the cyclones and the stack were collected and analyzed for biological activity, ecotoxicity, heavy metal concentration and leachability. The results obtained suggest that the ashes were suitable to be deposited in municipal landfills. 23 refs., 10 figs., 10 tabs.

  17. On the combustion mechanisms of ZrH2 in double-base propellant.

    Science.gov (United States)

    Yang, Yanjing; Zhao, Fengqi; Yuan, Zhifeng; Wang, Ying; An, Ting; Chen, Xueli; Xuan, Chunlei; Zhang, Jiankan

    2017-12-13

    Metal hydrides are regarded as a series of promising hydrogen-supplying fuel for solid rocket propellants. Their effects on the energetic and combustion performances of propellants are closely related to their reaction mechanisms. Here we report a first attempt to determine the reaction mechanism of ZrH2, a high-density metal hydride, in the combustion of a double-base propellant to evaluate its potential as a fuel. ZrH2 is determined to possess good resistance to oxidation by nitrocellulose and nitroglycerine. Thus its combustion starts with dehydrogenation to generate H2 and metallic Zr. Subsequently, the newly formed Zr and H2 participate in the combustion and, especially, Zr melts and then combusts on the burning surface which favors the heat feedback to the propellant. This phenomenon is completely different from the combustion behavior of the traditional fuel Al, where the Al particles are ejected off the burning surface of the propellant to get into the luminous flame zone to burn. The findings in this work validate the potential of ZrH2 as a hydrogen-supplying fuel for double-base propellants.

  18. Evolution of Submicrometer Organic Aerosols during a Complete Residential Coal Combustion Process.

    Science.gov (United States)

    Zhou, Wei; Jiang, Jingkun; Duan, Lei; Hao, Jiming

    2016-07-19

    In the absence of particulate matter (PM) control devices, residential coal combustion contributes significantly to ambient PM pollution. Characterizing PM emissions from residential coal combustion with high time resolution is beneficial for developing control policies and evaluating the environmental impact of PM. This study reports the evolution of submicrometer organic aerosols (OA) during a complete residential coal combustion process, that is, from fire start to fire extinction. Three commonly used coal types (bituminous, anthracite, and semicoke coals) were evaluated in a typical residential stove in China. For all three types of coal, the OA emission exhibited distinct characteristics in the four stages, that is, ignition, fierce combustion, relatively stable combustion, and ember combustion. OA emissions during the ignition stage accounted for 58.2-85.4% of the total OA emission of a complete combustion process. The OA concentration decreased rapidly during the fierce combustion stage and remained low during the relatively stable combustion stage. During these two stages, a significant ion peak of m/z 73 from organic acids were observed. The degree of oxidation of the OA increased from the first stage to the last stage. Implications for ambient OA source-apportionment and residential PM emission characterization and control are discussed.

  19. Spying on spontaneous combustion

    Energy Technology Data Exchange (ETDEWEB)

    1994-11-01

    The British Coal Technical Services and Research Executive (TSRE) has carried out a project to investigate potential applications of fibre optic based distributed temperature sensing (DTS) technology within a mining environment. The objective was to determine whether DTS could identify and locate spontaneous combustion earlier than conventional systems. The trials took place in a British mine from April to September 1992 and from August to November 1993 using a commercially available system from York Sensors Ltd. Results indicate that DTS is capable of very sensitive temperature monitoring, revealing sub-degree thermal trends resulting from various activities and local heatings. DTS has several prospective mining applications, e.g. monitoring known hot spots, investigating ventilation and heat flow through mine workings. The trials show that the system can be installed, calibrated, operated and maintained by relatively inexperienced personnel. 1 photo.

  20. Forced cocurrent smoldering combustion

    Science.gov (United States)

    Dosanjh, Sudip S.; Pagni, Patrick J.; Fernandez-Pello, A. Carlos

    1987-01-01

    An analytical model of cocurrent smoldering combustion through a very porous solid fuel is developed. Smoldering is initiated at the top of a long radially insulated uniform fuel cylinder, so that the smolder wave propagates downward, opposing an upward-forced flow of oxidizer, with the solid fuel and the gaseous oxidizer entering the reaction zone from the same direction (hence, cocurrent). Radiative heat transfer was incorporated using a diffusion approximation, and smoldering was modeled using a one-step reaction mechanism. The results indicate that, for a given fuel, the final temperature depends only on the initial oxygen mass flux, increasing logarithmically with the mass flux. The smolder velocity is linearly dependent on the initial oxygen mass flux, and, at a fixed value of the flux, increases with initial oxygen mass fraction. The mathematical relationship determining the conditions for steady smolder propagation is presented.

  1. COOPERATIVE MODE OF ELECTRIC MOTOR AND INTERNAL COMBUSTION ENGINE OPERATION IN THE CONVERSION HYBRID CAR

    Directory of Open Access Journals (Sweden)

    V. Dvadnenko

    2016-12-01

    Full Text Available In the given article the authors proposed a method to control the car, which is converted into a hybrid one. The electric motor and combustion engine operate alternately in the car. They proposed a device for implementing this method and a circuit design for the device in question. They also calculated the dynamics of the vehicle under the joint acceleration.

  2. Reduction of combustion noise and instabilities using porous inert material with a swirl-stabilized burner

    Science.gov (United States)

    Sequera, Daniel

    Combustion instabilities represent a major problem during operation of power generation systems that can lead to costly shutdown. Combustion instabilities are self excited large amplitude pressure oscillations caused by the coupling of unsteady heat release and acoustic modes of the combustor. These oscillations cause fluctuating mechanical loads and fluctuating heat transfer that can result in catastrophic premature failure of components. Combustion noise, a significant source of noise in gas turbines, can lead to combustion instabilities. Combustion noise and instabilities are different phenomena; however, they both occur due to unsteady heat release of turbulent flames that excites acoustic modes of the combustor. The instabilities self excite when flame adds energy to the acoustic field at a faster rate than it can dissipate it. Swirl-stabilized combustion and porous inert medium (PIM) combustion are two methods that have extensively been used, although independently, for flame stabilization. In this study, the two concepts are combined so that PIM serves as a passive device to mitigate combustion noise and instabilities. A PIM insert is placed within the lean premixed, swirl-stabilized combustor to affect the turbulent flow field reducing combustion noise. This study is the first step for eventual implementation in liquid fuel systems. After presenting the concept, a numerical investigation of the changes in the mean flow field caused by the PIM is presented. Changes in the flow field can be beneficial for noise reduction by optimizing the geometric parameters of the PIM. Next, atmospheric pressure experiments were conducted at low reactant inlet velocity (interior combustion modes were identified and PIM geometric parameters were optimized. Next, a laboratory facility to conduct experiments at high reactant inlet velocity, high inlet air temperature, and high pressure was designed and developed. Results show that the porous insert substantially reduces

  3. Chemical Pollution from Combustion of Modern Spacecraft Materials

    Science.gov (United States)

    Mudgett, Paul D.

    2013-01-01

    Fire is one of the most critical contingencies in spacecraft and any closed environment including submarines. Currently, NASA uses particle based technology to detect fires and hand-held combustion product monitors to track the clean-up and restoration of habitable cabin environment after the fire is extinguished. In the future, chemical detection could augment particle detection to eliminate frequent nuisance false alarms triggered by dust. In the interest of understanding combustion from both particulate and chemical generation, NASA Centers have been collaborating on combustion studies at White Sands Test Facility using modern spacecraft materials as fuels, and both old and new technology to measure the chemical and particulate products of combustion. The tests attempted to study smoldering pyrolysis at relatively low temperatures without ignition to flaming conditions. This paper will summarize the results of two 1-week long tests undertaken in 2012, focusing on the chemical products of combustion. The results confirm the key chemical products are carbon monoxide (CO), hydrogen cyanide (HCN), hydrogen fluoride (HF) and hydrogen chloride (HCl), whose concentrations depend on the particular material and test conditions. For example, modern aerospace wire insulation produces significant concentration of HF, which persists in the test chamber longer than anticipated. These compounds are the analytical targets identified for the development of new tunable diode laser based hand-held monitors, to replace the aging electrochemical sensor based devices currently in use on the International Space Station.

  4. Active Control of Mixing and Combustion, from Mechanisms to Implementation

    Science.gov (United States)

    Ghoniem, Ahmed F.

    2001-11-01

    Implementation of active control in complex processes, of the type encountered in high Reynolds number mixing and combustion, is predicated upon the identification of the underlying mechanisms and the construction of reduced order models that capture their essential characteristics. The mechanisms of interest must be shown to be amenable to external actuations, allowing optimal control strategies to exploit the delicate interactions that lead to the desired outcome. Reduced order models are utilized in defining the form and requisite attributes of actuation, its relationship to the monitoring system and the relevant control algorithms embedded in a feedforward or a feedback loop. The talk will review recent work on active control of mixing in combustion devices in which strong shear zones concur with mixing, combustion stabilization and flame anchoring. The underlying mechanisms, e.g., stability of shear flows, formation/evolution of large vortical structures in separating and swirling flows, their mutual interactions with acoustic fields, flame fronts and chemical kinetics, etc., are discussed in light of their key roles in mixing, burning enhancement/suppression, and combustion instability. Subtle attributes of combustion mechanisms are used to suggest the requisite control strategies.

  5. Nano Scale Energetic Materials: Theoretical and Experimental Updates

    Science.gov (United States)

    Martirosyan, Karen S.; Ramazanova, Zamarta; Zyskin, M.

    Recent advances in nanoscience are providing capabilities to fabricate materials with complex molecular patterns using various novel assembly approaches. This talk will summarize our current progress towards developing a framework of principles for design and fabrication of nano-tailored energetic materials for emerging applications. Nanoscale particles have a significantly higher surface area to volume ratio than microparticles, providing a closer contact between solid particles in a mixture.Kinetics of oxidation of metal nanoparticles acquired practical importance with rapidly developing nanoenergetic systems and materials. Nanoenergetic thermites include mixtures of Al and metal oxides in nanoscale. Our research focuses on modeling aluminum combustion in nanoscale. We consider oxidation in the spherically symmetric case, assuming that aluminum particle of radius 10 to 50 nm is covered by a thin oxide layer (1-4nm) and is surrounded by abundant amount of oxygen stored by oxidizers. The particle is rapidly heated up to ignition temperature to initiate self-sustaining oxidation reaction as a result of highly exothermic reaction. We use nonlinear Cabrera-Mott model with a self-consistent electric potential to compute oxidation reaction power (watts), as a function of temperature and oxidized metal proportion. Knowledge of such reaction power together with a self-heating model allows to predict oxidation time and reaction temperature dynamics. We compare modeling of self-heating based on matched experimentally known maximal reaction temperature with a detailed heat transfer model taking into account heat loss due to convection and radiation.

  6. Structure and Stability of Deflagrations in Porous Energetic Materials

    Energy Technology Data Exchange (ETDEWEB)

    stephen B. Margolis; Forman A. Williams

    1999-03-01

    Theoretical two-phase-flow analyses have recently been developed to describe the structure and stability of multi-phase deflagrations in porous energetic materials, in both confined and unconfined geometries. The results of these studies are reviewed, with an emphasis on the fundamental differences that emerge with respect to the two types of geometries. In particular, pressure gradients are usually negligible in unconfined systems, whereas the confined problem is generally characterized by a significant gas-phase pressure difference, or overpressure, between the burned and unburned regions. The latter leads to a strong convective influence on the burning rate arising from the pressure-driven permeation of hot gases into the solid/gas region and the consequent preheating of the unburned material. It is also shown how asymptotic models that are suitable for analyzing stability may be derived based on the largeness of an overall activation-energy parameter. From an analysis of such models, it is shown that the effects of porosity and two-phase flow are generally destabilizing, suggesting that degraded propellants, which exhibit greater porosity than their pristine counterparts, may be more readily subject to combustion instability and nonsteady deflagration.

  7. Filtration combustion: Smoldering and SHS

    Science.gov (United States)

    Matkowsky, Bernard J.

    1995-01-01

    Smolder waves and SHS (self-propagating high-temperature synthesis) waves are both examples of combustion waves propagating in porous media. When delivery of reactants through the pores to the reaction site is an important aspect of the process, it is referred to as filtration combustion. The two types of filtration combustion have a similar mathematical formulation, describing the ignition, propagation and extinction of combustion waves in porous media. The goal in each case, however, is different. In smoldering the desired goal is to prevent propagation, whereas in SHS the goal is to insure propagation of the combustion wave, leading to the synthesis of desired products. In addition, the scales in the two areas of application may well differ. For example, smoldering generally occurs at a relatively low temperature and with a smaller propagation velocity than SHS filtration combustion waves. Nevertheless, the two areas of application have much in common, so that mechanisms learned about in one application can be used to advantage in the other. In this paper we discuss recent results in the areas of filtration combustion.

  8. Catalytic Combustion of Gasified Waste

    Energy Technology Data Exchange (ETDEWEB)

    Kusar, Henrik

    2003-09-01

    This thesis concerns catalytic combustion for gas turbine application using a low heating-value (LHV) gas, derived from gasified waste. The main research in catalytic combustion focuses on methane as fuel, but an increasing interest is directed towards catalytic combustion of LHV fuels. This thesis shows that it is possible to catalytically combust a LHV gas and to oxidize fuel-bound nitrogen (NH{sub 3}) directly into N{sub 2} without forming NO{sub x} The first part of the thesis gives a background to the system. It defines waste, shortly describes gasification and more thoroughly catalytic combustion. The second part of the present thesis, paper I, concerns the development and testing of potential catalysts for catalytic combustion of LHV gases. The objective of this work was to investigate the possibility to use a stable metal oxide instead of noble metals as ignition catalyst and at the same time reduce the formation of NO{sub x} In paper II pilot-scale tests were carried out to prove the potential of catalytic combustion using real gasified waste and to compare with the results obtained in laboratory scale using a synthetic gas simulating gasified waste. In paper III, selective catalytic oxidation for decreasing the NO{sub x} formation from fuel-bound nitrogen was examined using two different approaches: fuel-lean and fuel-rich conditions. Finally, the last part of the thesis deals with deactivation of catalysts. The various deactivation processes which may affect high-temperature catalytic combustion are reviewed in paper IV. In paper V the poisoning effect of low amounts of sulfur was studied; various metal oxides as well as supported palladium and platinum catalysts were used as catalysts for combustion of a synthetic gas. In conclusion, with the results obtained in this thesis it would be possible to compose a working catalytic system for gas turbine application using a LHV gas.

  9. Combustion synthesis and characterization of nanocrystalline WO3.

    Science.gov (United States)

    Morales, Walter; Cason, Michael; Aina, Olawunmi; de Tacconi, Norma R; Rajeshwar, Krishnan

    2008-05-21

    The energy payback time associated with the semiconductor active material is an important parameter in a photovoltaic solar cell device. Thus lowering the energy requirements for the semiconductor synthesis step or making it more energy-efficient is critical toward making the overall device economics more competitive relative to other nonpolluting energy options. In this communication, combustion synthesis is demonstrated to be a versatile and energy-efficient method for preparing inorganic oxide semiconductors such as tungsten trioxide (WO3) for photovoltaic or photocatalytic solar energy conversion. The energy efficiency of combustion synthesis accrues from the fact that high process temperatures are self-sustained by the exothermicity of the combustion process, and the only external thermal energy input needed is for dehydration of the fuel/oxidizer precursor mixture and bringing it to ignition. Importantly, we show that, in this approach, it is also possible to tune the optical characteristics of the oxide semiconductor (i.e., shift its response toward the visible range of the electromagnetic spectrum) in situ by doping the host semiconductor during the formative stage itself. As a bonus, the resultant material shows enhanced surface properties such as markedly improved organic dye uptake relative to benchmark samples obtained from commercial sources. Finally, this synthesis approach requires only very simple equipment, a feature that it shares with other "mild" inorganic semiconductor synthesis routes such as sol-gel chemistry, chemical bath deposition, and electrodeposition. The present study constitutes the first use of combustion synthesis for preparing WO3 powder comprising nanosized particles.

  10. Generation of Energetic Species by RF Microplasma Arrays

    Science.gov (United States)

    Rawlins, W. T.; Lee, S.; Fenner, D. B.; Davis, S. J.; Hoskinson, A. R.; Hopwood, J.

    2012-10-01

    We present preliminary results from the first implementation of a prototype single-board RF micro-discharge, linear array device in a discharge-flow reactor for quantitative determinations of ozone and singlet-oxygen production from microplasmas in O2 and air at 1 atm. The ultimate objective is to develop compact, portable low-power micro-discharge based systems to generate energetic species for atmospheric-pressure applications including decontamination and disinfection. The technology uses application of low DC voltages and low applied powers (˜25 W) at ˜1 GHz frequencies, across small gaps in arrays of resonators to ignite and sustain highly energetic microplasmas at elevated pressures. A set of 15-resonator micro-discharge assemblies was designed, fabricated, and tested in static and flowing environments for O2, air, and Ar flows at pressures of 20 Torr to 1 atm. O3 production was measured by UV absorption spectrometry, and O2(a^1delta-g) (``singlet-oxygen'') concentrations were determined by absolute near-infrared emission spectroscopy. Near-infrared emission spectra from an argon plasma were also recorded, and showed extensive excitation of the Ar(I) 3p^54p -- 3p^54s emission system near 12 eV.

  11. On Lean Turbulent Combustion Modeling

    Directory of Open Access Journals (Sweden)

    Constantin LEVENTIU

    2014-06-01

    Full Text Available This paper investigates a lean methane-air flame with different chemical reaction mechanisms, for laminar and turbulent combustion, approached as one and bi-dimensional problem. The numerical results obtained with Cantera and Ansys Fluent software are compared with experimental data obtained at CORIA Institute, France. First, for laminar combustion, the burn temperature is very well approximated for all chemical mechanisms, however major differences appear in the evaluation of the flame front thickness. Next, the analysis of turbulence-combustion interaction shows that the numerical predictions are suficiently accurate for small and moderate turbulence intensity.

  12. Electronic control of magnonic and spintronic devices

    OpenAIRE

    Tannous, C.; Gieraltowski, J.

    2016-01-01

    Nanometric magnonic and spintronic devices need magnetic field control in addition to conventional electronic control. In this work we review ways to replace magnetic field control by an electronic one in order to circumvent appearance of stray magnetic fields or the difficulty of creating large magnetic fields over nanometric distances. Voltage control is compared to current control and corresponding devices are compared from their energetic efficiency point of view.

  13. Combustion of Solid Propellants (La Combustion des Propergols Solides)

    Science.gov (United States)

    1991-07-01

    poudres modificateurs balistiques, des noirs de A mouler de caract~ristiques volontairement carbone sont souvent incorpor~s car ils ont diffdrontes ce...de antilueurs (suppresseurs de la post noir de carbone eat souvent utilisd combustion). Ceux-ci, g~ndralement des sels industriellemont comae param...devient compressible at is vitesse de combustion Pour 6tablir un bilan sur le risque eat modifide. La figure 7 illustre cet d’appariticn d’instabilit~s

  14. Measures for a quality combustion (combustion chamber exit and downstream); Mesures pour une combustion de qualite (sortie de chambre de combustion et en aval)

    Energy Technology Data Exchange (ETDEWEB)

    Epinat, G. [APAVE Lyonnaise, 69 (France)

    1996-12-31

    After a review of the different pollutants related to the various types of stationary and mobile combustion processes (stoichiometric, reducing and oxidizing combustion), measures and analyses than may be used to ensure the quality and efficiency of combustion processes are reviewed: opacimeters, UV analyzers, etc. The regulation and control equipment for combustion systems are then listed, according to the generator capacity level

  15. Computational Modeling of Turbulent Spray Combustion

    NARCIS (Netherlands)

    Ma, L.

    2016-01-01

    The objective of the research presented in this thesis is development and validation of predictive models or modeling approaches of liquid fuel combustion (spray combustion) in hot-diluted environments, known as flameless combustion or MILD combustion. The goal is to combine good physical insight,

  16. Energetic deposition of thin metal films

    CERN Document Server

    Al-Busaidy, M S K

    2001-01-01

    deposited films. The primary aim of this thesis was to study the physical effect of energetic deposition metal thin films. The secondary aim is to enhance the quality of the films produced to a desired quality. Grazing incidence X-ray reflectivity (GIXR) measurements from a high-energy synchrotron radiation source were carried out to study and characterise the samples. Optical Profilers Interferometery, Atomic Force Microscope (AFM), Auger electron spectroscopy (AES), Medium energy ion spectroscopy (MEIS), and the Electron microscope studies were the other main structural characterisation tools used. AI/Fe trilayers, as well as multilayers were deposited using a Nordico planar D.C. magnetron deposition system at different voltage biases and pressures. The films were calibrated and investigated. The relation between energetic deposition variation and structural properties was intensely researched. Energetic deposition refers to the method in which the deposited species possess higher kinetic energy and impact ...

  17. Energetic utilize municipal waste – technik combined combustion coal and waste

    Directory of Open Access Journals (Sweden)

    Augustínová Edita

    2000-03-01

    Full Text Available The Coal -Waste System (CWS demonstrates how convencional power station steam generation can be intelligently combined with enwironmentally responsible waste disposal. A grate-firing instalation, operated as a plant satellite parallel to a power station steam generator, converts the chemical energy of the household waste into thermal energy in the form of hot flue gas. This flue gas is introduced as a coal substitute into the lower section of the steam generator and supplies a part of the thermal energy reqiured. The application of this process engineering offers a series of economic and ecological advantages.

  18. Quantum technology past, present, future: quantum energetics (Conference Presentation)

    Science.gov (United States)

    Choi, Sang H.

    2017-04-01

    Since the development of quantum physics in the early part of the 1900s, this field of study has made remarkable contributions to our civilization. Some of these advances include lasers, light-emitting diodes (LED), sensors, spectroscopy, quantum dots, quantum gravity and quantum entanglements. In 1998, the NASA Langley Research Center established a quantum technology committee to monitor the progress in this area and initiated research to determine the potential of quantum technology for future NASA missions. The areas of interest in quantum technology at NASA included fundamental quantum-optics materials associated with quantum dots and quantum wells, device-oriented photonic crystals, smart optics, quantum conductors, quantum information and computing, teleportation theorem, and quantum energetics. A brief review of the work performed, the progress made in advancing these technologies, and the potential NASA applications of quantum technology will be presented.

  19. Fifth International Microgravity Combustion Workshop

    Science.gov (United States)

    Sacksteder, Kurt (Compiler)

    1999-01-01

    This conference proceedings document is a compilation of 120 papers presented orally or as poster displays to the Fifth International Microgravity Combustion Workshop held in Cleveland, Ohio on May 18-20, 1999. The purpose of the workshop is to present and exchange research results from theoretical and experimental work in combustion science using the reduced-gravity environment as a research tool. The results are contributed by researchers funded by NASA throughout the United States at universities, industry and government research agencies, and by researchers from at least eight international partner countries that are also participating in the microgravity combustion science research discipline. These research results are intended for use by public and private sector organizations for academic purposes, for the development of technologies needed for the Human Exploration and Development of Space, and to improve Earth-bound combustion and fire-safety related technologies.

  20. Sixth International Microgravity Combustion Workshop

    Science.gov (United States)

    Sacksteder, Kurt (Compiler)

    2001-01-01

    This conference proceedings document is a compilation of papers presented orally or as poster displays to the Sixth International Microgravity Combustion Workshop held in Cleveland, Ohio on May 22-24, 2001. The purpose of the workshop is to present and exchange research results from theoretical and experimental work in combustion science using the reduced-gravity environment as a research tool. The results are contributed by researchers funded by NASA throughout the United States at universities, industry and government research agencies, and by researchers from international partner countries that are also participating in the microgravity combustion science research discipline. These research results are intended for use by public and private sector organizations for academic purposes, for the development of technologies needed for Human Exploration and Development of Space, and to improve Earth-bound combustion and fire-safety related technologies.

  1. Energetics and dynamics in organic-inorganic halide perovskite photovoltaics and light emitters.

    Science.gov (United States)

    Sum, Tze Chien; Chen, Shi; Xing, Guichuan; Liu, Xinfeng; Wu, Bo

    2015-08-28

    The rapid transcendence of organic-inorganic metal halide perovskite solar cells to above the 20% efficiency mark has captivated the broad photovoltaic community. As the efficiency race continues unabated, it is essential that fundamental studies keep pace with these developments. Further gains in device efficiencies are expected to be increasingly arduous and harder to come by. The key to driving the perovskite solar cell efficiencies towards their Shockley-Queisser limit is through a clear understanding of the interfacial energetics and dynamics between perovskites and other functional materials in nanostructured- and heterojunction-type devices. In this review, we focus on the current progress in basic characterization studies to elucidate the interfacial energetics (energy-level alignment and band bending) and dynamical processes (from the ultrafast to the ultraslow) in organic-inorganic metal halide perovskite photovoltaics and light emitters. Major findings from these studies will be distilled. Open questions and scientific challenges will also be highlighted.

  2. Catalytically stabilized combustion of lean methane-air-mixtures: a numerical model

    Energy Technology Data Exchange (ETDEWEB)

    Dogwiler, U.; Benz, P.; Mantharas, I. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    The catalytically stabilized combustion of lean methane/air mixtures has been studied numerically under conditions closely resembling the ones prevailing in technical devices. A detailed numerical model has been developed for a laminar, stationary, 2-D channel flow with full heterogeneous and homogeneous reaction mechanisms. The computations provide direct information on the coupling between heterogeneous-homogeneous combustion and in particular on the means of homogeneous ignitions and stabilization. (author) 4 figs., 3 refs.

  3. Coal Combustion Wastes Reuse in Low Energy Artificial Aggregates Manufacturing

    OpenAIRE

    Raffaele Cioffi; Barbara Liguori; Fabio Iucolano; Francesco Colangelo; Francesco Messina; Claudio Ferone

    2013-01-01

    Sustainable building material design relies mostly on energy saving processes, decrease of raw materials consumption, and increase of waste and by-products recycling. Natural and lightweight artificial aggregates production implies relevant environmental impact. This paper addresses both the issues of residues recycling and energy optimization. Particularly, three coal combustion wastes (Weathered Fly Ash, WFA; Wastewater Treatment Sludge, WTS; Desulfurization Device Sludge, DDS) supplied by ...

  4. Smoldering Combustion Experiments in Microgravity

    Science.gov (United States)

    Walther, David C.; Fernandez-Pello, A. Carlos; Urban, David L.

    1997-01-01

    The Microgravity Smoldering Combustion (MSC) experiment is part of a study of the smolder characteristics of porous combustible materials in a microgravity environment. Smoldering is a non-flaming form of combustion that takes place in the interior of porous materials and takes place in a number of processes ranging from smoldering of porous insulation materials to high temperature synthesis of metals. The objective of the study is to provide a better understanding of the controlling mechanisms of smolder, both in microgravity and normal-gravity. As with many forms of combustion, gravity affects the availability of oxidizer and transport of heat, and therefore the rate of combustion. Microgravity smolder experiments, in both a quiescent oxidizing environment, and in a forced oxidizing flow have been conducted aboard the NASA Space Shuttle (STS-69 and STS-77 missions) to determine the effect of the ambient oxygen concentration and oxidizer forced flow velocity on smolder combustion in microgravity. The experimental apparatus is contained within the NASA Get Away Special Canister (GAS-CAN) Payload. These two sets of experiments investigate the propagation of smolder along the polyurethane foam sample under both diffusion driven and forced flow driven smoldering. The results of the microgravity experiments are compared with identical ones carried out in normal gravity, and are used to verify present theories of smolder combustion. The results of this study will provide new insights into the smoldering combustion process. Thermocouple histories show that the microgravity smolder reaction temperatures (Ts) and propagation velocities (Us) lie between those of identical normal-gravity upward and downward tests. These observations indicate the effect of buoyancy on the transport of oxidizer to the reaction front.

  5. A Refrigerated Web Camera for Photogrammetric Video Measurement inside Biomass Boilers and Combustion Analysis

    Directory of Open Access Journals (Sweden)

    Enrique Granada

    2011-01-01

    Full Text Available This paper describes a prototype instrumentation system for photogrammetric measuring of bed and ash layers, as well as for flying particle detection and pursuit using a single device (CCD web camera. The system was designed to obtain images of the combustion process in the interior of a domestic boiler. It includes a cooling system, needed because of the high temperatures in the combustion chamber of the boiler. The cooling system was designed using CFD simulations to ensure effectiveness. This method allows more complete and real-time monitoring of the combustion process taking place inside a boiler. The information gained from this system may facilitate the optimisation of boiler processes.

  6. Insertion devices

    CERN Document Server

    Bahrdt, J

    2006-01-01

    The interaction of an insertion device with the electron beam in a storage ring is discussed. The radiation property including brightness, ux and polarization of an ideal and real planar and helical / elliptical device is described. The magnet design of planar, helical, quasiperiodic devices and of devices with a reduced on axis power density are resumed.

  7. Polycyclic Aromatic Hydrocarbons (PAHs) produced in the combustion of fatty acid alkyl esters from different feedstocks: Quantification, statistical analysis and mechanisms of formation.

    Science.gov (United States)

    Llamas, Alberto; Al-Lal, Ana-María; García-Martínez, María-Jesús; Ortega, Marcelo F; Llamas, Juan F; Lapuerta, Magín; Canoira, Laureano

    2017-05-15

    Polycyclic Aromatic Hydrocarbons (PAHs) are pollutants of concern due to their carcinogenic and mutagenic activity. Their emissions are mainly related with the combustion or pyrolysis of the organic matter, such as in fossil fuels combustion. It is important to characterize PAHs in the combustions of biofuels due to their increasing importance in the actual energetic setting. There is a lot of research focused in PAHs emission due to the combustion in diesel engines; but only few of them have analyzed the effect of raw material and type of alcohol used in the transesterification process. Different raw materials (i.e. animal fat, palm, rapeseed, linseed, peanut, coconut, and soybean oils) have been used for obtaining FAME and FAEE. A method for measuring PAHs generated during combustion in a bomb calorimeter has been developed. Combustion was made at different oxygen pressures and the samples were taken from the bomb after each combustion. Samples were extracted and the PAHs amounts formed during combustion were analyzed by GC-MS. This research shows the statistical relationships among the 16 PAHs of concern, biodiesel composition and oxygen pressure during combustion. Copyright © 2017 Elsevier B.V. All rights reserved.

  8. Techniques de combustion Combustin Techniques

    Directory of Open Access Journals (Sweden)

    Perthuis E.

    2006-11-01

    Full Text Available L'efficacité d'un processus de chauffage par flamme est étroitement liée à la maîtrise des techniques de combustion. Le brûleur, organe essentiel de l'équipement de chauffe, doit d'une part assurer une combustion complète pour utiliser au mieux l'énergie potentielle du combustible et, d'autre part, provoquer dans le foyer les conditions aérodynamiques les plus propices oux transferts de chaleur. En s'appuyant sur les études expérimentales effectuées à la Fondation de Recherches Internationales sur les Flammes (FRIF, au Groupe d'Étude des Flammes de Gaz Naturel (GEFGN et à l'Institut Français du Pétrole (IFP et sur des réalisations industrielles, on présente les propriétés essentielles des flammes de diffusion aux combustibles liquides et gazeux obtenues avec ou sans mise en rotation des fluides, et leurs répercussions sur les transferts thermiques. La recherche des températures de combustion élevées conduit à envisager la marche à excès d'air réduit, le réchauffage de l'air ou son enrichissement à l'oxygène. Par quelques exemples, on évoque l'influence de ces paramètres d'exploitation sur l'économie possible en combustible. The efficiency of a flame heating process is closely linked ta the mastery of, combustion techniques. The burner, an essential element in any heating equipment, must provide complete combustion sa as to make optimum use of the potential energy in the fuel while, at the same time, creating the most suitable conditions for heat transfers in the combustion chamber. On the basis of experimental research performed by FRIF, GEFGN and IFP and of industrial achievements, this article describesthe essential properties of diffusion flames fed by liquid and gaseous fuels and produced with or without fluid swirling, and the effects of such flames on heat transfers. The search for high combustion temperatures means that consideration must be given to operating with reduced excess air, heating the air or

  9. Energetic materials standards – Chemical compatibility

    NARCIS (Netherlands)

    Tuukkanen, I.M.; Bouma, R.H.B.

    2014-01-01

    Subgroup A Energetic Materials Team, SG/A (EMT), develops and maintains standards that are relevant to all life-cycle phases of ammunition/weapon systems. STANAG 4147 is the standard regarding chemical compatibility of explosives with munition components, and is a document of prime importance.

  10. Error propagation in energetic carrying capacity models

    Science.gov (United States)

    Pearse, Aaron T.; Stafford, Joshua D.

    2014-01-01

    Conservation objectives derived from carrying capacity models have been used to inform management of landscapes for wildlife populations. Energetic carrying capacity models are particularly useful in conservation planning for wildlife; these models use estimates of food abundance and energetic requirements of wildlife to target conservation actions. We provide a general method for incorporating a foraging threshold (i.e., density of food at which foraging becomes unprofitable) when estimating food availability with energetic carrying capacity models. We use a hypothetical example to describe how past methods for adjustment of foraging thresholds biased results of energetic carrying capacity models in certain instances. Adjusting foraging thresholds at the patch level of the species of interest provides results consistent with ecological foraging theory. Presentation of two case studies suggest variation in bias which, in certain instances, created large errors in conservation objectives and may have led to inefficient allocation of limited resources. Our results also illustrate how small errors or biases in application of input parameters, when extrapolated to large spatial extents, propagate errors in conservation planning and can have negative implications for target populations.

  11. Estimating Instantaneous Energetic Cost During Gait Adaptation

    Science.gov (United States)

    2014-08-31

    energetic penalties imposed by various gait disabilities, and the 30   evaluation of the effectiveness of rehabilitation interventions at mitigating...of level walking with powered ankle 410   exoskeletons . Journal of Experimental Biology 211: 1402–1413, 2008. 411   25. Schmalz T, Blumentritt S

  12. Energetic utilization of dietary fiber in pigs

    NARCIS (Netherlands)

    Rijnen, M.M.J.A.

    2003-01-01

    The energetic utilization of fermentable dietary fiber (fDF) of different fiber sources and its relation to physical activity and housing conditions was studied in three experiments. In all experiments the daily intake of digestible nutrients, nitrogen and energy balances, heat production, and

  13. Energetic particle instabilities in fusion plasmas

    NARCIS (Netherlands)

    Sharapov, S. E.; Alper, B.; Berk, H. L.; Borba, D. N.; Breizman, B. N.; Challis, C. D.; Classen, I.G.J.; Edlund, E. M.; Eriksson, J.; Fasoli, A.; Fredrickson, E. D.; Fu, G. Y.; M. García-Muñoz,; Gassner, T.; Ghantous, K.; Goloborodko, V.; Gorelenkov, N. N.; Gryaznevich, M. P.; Hacquin, S.; Heidbrink, W. W.; Hellesen, C.; Kiptily, V. G.; Kramer, G. J.; Lauber, P.; Lilley, M. K.; Lisak, M.; Nabais, F.; Nazikian, R.; Nyqvist, R.; Osakabe, M.; C. Perez von Thun,; Pinches, S. D.; Podesta, M.; Porkolab, M.; Shinohara, K.; Schoepf, K.; Todo, Y.; Toi, K.; VanZeeland, M. A.; Voitsekhovich, I.; White, R. B.; Yavorskij, V.; ITPA EP TG Contributors,; JET-EFDA Contributors,

    2013-01-01

    Remarkable progress has been made in diagnosing energetic particle instabilities on present-day machines and in establishing a theoretical framework for describing them. This overview describes the much improved diagnostics of Alfvén instabilities and modelling tools developed world-wide, and

  14. Micro-initiators as the fundamental building blocks of micro-energetic systems

    Science.gov (United States)

    Desai, Amish; Fuchs, Brian

    2007-04-01

    The need for smaller and less expensive MIL-STD 1901A compliant safe and arm-fire (S&A/A-F) devices to safely initiate rocket motors requires a better understanding of energetic initiation and firing train functionality. Applications broadly include NLOS artillery rocket-assist motors, high I sp miniature thrusters for UAVs, composite molded thrusters for hypersonic flow temperatures, and smart munitions. Every energetic system needs an initiation mechanism. For the past decade, many groups have worked on reducing the footprint of these systems through batch processing and miniaturization. However, the typical miniaturization and semiconductor-style benefits such as "faster, smaller, cheaper" are only now being investigated for micro-energetics. Advancement of this field requires key breakthroughs in the following areas: 1) a SAFE and batch micro-energetics deposition and patterning step, 2) The compatibility of subsequent (post or pre) MEMS processing steps, 3) better understanding of the micro-initiation energetic train, and 4) special environmental standards for the manufacturer and specialized product qualification/testing. This body of work spotlights 'low-cost' MEMS-based initiators, typical chemical compounds used today in the industry and the associated sensitivities and dangers to be encountered. The micro-scale firing trains required for smart munitions, including warhead and propellant applications, can be made multifunctional for use with legacy and IM-compliant energetics. Methods of focusing industry on reliability and the importance of characterizing formulation, composition, and performance will also be discussed. Most importantly, however, is the need to focus industry on implementing a low-cost micro initiator methodology.

  15. Jet plume injection and combustion system for internal combustion engines

    Science.gov (United States)

    Oppenheim, Antoni K.; Maxson, James A.; Hensinger, David M.

    1993-01-01

    An improved combustion system for an internal combustion engine is disclosed wherein a rich air/fuel mixture is furnished at high pressure to one or more jet plume generator cavities adjacent to a cylinder and then injected through one or more orifices from the cavities into the head space of the cylinder to form one or more turbulent jet plumes in the head space of the cylinder prior to ignition of the rich air/fuel mixture in the cavity of the jet plume generator. The portion of the rich air/fuel mixture remaining in the cavity of the generator is then ignited to provide a secondary jet, comprising incomplete combustion products which are injected into the cylinder to initiate combustion in the already formed turbulent jet plume. Formation of the turbulent jet plume in the head space of the cylinder prior to ignition has been found to yield a higher maximum combustion pressure in the cylinder, as well as shortening the time period to attain such a maximum pressure.

  16. Combustion Byproducts Recycling Consortium

    Energy Technology Data Exchange (ETDEWEB)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    The Combustion Byproducts Recycling Consortium (CBRC) program was developed as a focused program to remove and/or minimize the barriers for effective management of over 123 million tons of coal combustion byproducts (CCBs) annually generated in the USA. At the time of launching the CBRC in 1998, about 25% of CCBs were beneficially utilized while the remaining was disposed in on-site or off-site landfills. During the ten (10) year tenure of CBRC (1998-2008), after a critical review, 52 projects were funded nationwide. By region, the East, Midwest, and West had 21, 18, and 13 projects funded, respectively. Almost all projects were cooperative projects involving industry, government, and academia. The CBRC projects, to a large extent, successfully addressed the problems of large-scale utilization of CCBs. A few projects, such as the two Eastern Region projects that addressed the use of fly ash in foundry applications, might be thought of as a somewhat smaller application in comparison to construction and agricultural uses, but as a novel niche use, they set the stage to draw interest that fly ash substitution for Portland cement might not attract. With consideration of the large increase in flue gas desulfurization (FGD) gypsum in response to EPA regulations, agricultural uses of FGD gypsum hold promise for large-scale uses of a product currently directed to the (currently stagnant) home construction market. Outstanding achievements of the program are: (1) The CBRC successfully enhanced professional expertise in the area of CCBs throughout the nation. The enhanced capacity continues to provide technology and information transfer expertise to industry and regulatory agencies. (2) Several technologies were developed that can be used immediately. These include: (a) Use of CCBs for road base and sub-base applications; (b) full-depth, in situ stabilization of gravel roads or highway/pavement construction recycled materials; and (c) fired bricks containing up to 30%-40% F

  17. Practical Multi-Disciplinary Analysis Tools for Combustion Devices Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The use of multidisciplinary analysis (MDA) techniques for complex fluid/structure interaction phenomena is increasing as proven numerical and visualization...

  18. Speed control device for internal combustion engines. Drehzahlregelanordnung fuer Brennkraftmaschinen

    Energy Technology Data Exchange (ETDEWEB)

    Le Bihan, B.

    1991-05-16

    In order to keep the speed constant, or even to increase it at high torque, a further controller is provided apart from the existing centrifugal force controller in a first example of the invention, which replaces the conventional adjustment screw for the basic speed setting, and permanently changes the basic speed setting on load change. According to a second example, an electronic speed control is provided, which has a setting member, which is operated electrically, hydraulically or pneumatically and which acts directly on the carburettor. The control of the setting member is done via a controller which sets the carburettor based on a manual speed signal and the actual speed.

  19. Additively Manufactured Combustion Devices Components for LOX/Methane Applications

    Science.gov (United States)

    Greene, Sandra Elam; Protz, Christopher; Garcia, Chance; Goodman, Dwight; Baker, Kevin

    2016-01-01

    Marshall Space Flight Center (MSFC) has designed, fabricated, and hot-fire tested a variety of successful injectors, chambers, and igniters for potential liquid oxygen (LOX) and methane (CH4) systems since 2005. The most recent efforts have focused on components with additive manufacturing (AM) to include unique design features, minimize joints, and reduce final machining efforts. Inconel and copper alloys have been used with AM processes to produce a swirl coaxial injector and multiple methane cooled thrust chambers. The initial chambers included unique thermocouple ports for measuring local coolant channel temperatures along the length of the chamber. Results from hot-fire testing were used to anchor thermal models and generate a regeneratively cooled thruster for a 4,000 lbf LOX/CH4 engine. The completed thruster will be hot-fire tested in the summer of 2016 at MSFC. The thruster design can also be easily scaled and used on a 25,000 lbf engine. To further support the larger engine design, an AM gas generator injector has been designed. Hot-fire testing on this injector is planned for the summer of 2016 at MSFC.

  20. Solution combustion synthesis of oxide semiconductors

    Science.gov (United States)

    Thomas, Abegayl Lorenda Shara-Lynn

    The quest for stable and efficient photocatalytic materials beyond TiO2 and WO3 has over the years led to the development of new materials that possess varied interfacial energetics. This dissertation study focused on using for the first time a novel method, solution combustion synthesis (SCS), to prepare two distinct families of binary metal-based oxide semiconductor materials. Detailed studies on material characteristics and applications were carried out on tungsten- and niobium-based oxide semiconductors with varying principal metals. Initial emphasis was placed on the SCS of tungsten-based oxide semiconductors (ZnWO4, CuWO4, and Ag2WO4). The influence of different tungsten precursor's on the resultant product was of particular relevance to this study, with the most significant effects highlighted. Upon characterization, each sample's photocatalytic activity towards methyl orange dye degradation was studied, and benchmarked against their respective commercial oxide sample, obtained by solid-state ceramic synthesis. Detailed analysis highlighted the importance of the SCS process as a time- and energy-efficient method to produce crystalline nano-sized materials even without additional or excessive heat treatment. It was observed that using different tungstate precursors does influence the structural and morphological make-up of the resulting materials. The as-synthesized tungstate materials showed good photocatalytic performance for the degradation of methyl orange dye, while taking into account specific surface area and adsorbed dye amount on the surface of the material. Like the tungstate's, niobium-based oxide semiconductors CuNb 2O6 and ZnNb2O6 were the first to be synthesized via solution combustion synthesis. Particular attention was placed on the crystal structures formed while using an oxalate niobium precursor during the reaction process. X-ray patterns yielded a multiphase structure for the ZnNb2O6 and a single phase structure for CuNb 2O6

  1. Premixed CH4/O2-enriched air combustion: Identification of thermal, chemical and aerodynamic effects

    Science.gov (United States)

    Most, J.-M.; Dahikar, S.; Pal, S.; Claverie, A.; Denis, D.; Pillier, L.; de Persis, S.

    2012-11-01

    This work contributes to the evaluation of a new innovative process focused on the reduction of the cost of a post-combustion capture of CO2 in a Carbon Capture and Storage system (CCS). The process based on the separation of dried fumes composed mainly by CO2 and N2 by using membranes, which should lead to a lower energetic separation cost than amines. But the membranes become efficient if the upstream CO2 concentration is higher than 30% at their entrance that requires enriching the oxidizer flow by O2. To maintain the exhaust temperature compatible with materials thermal resistance, the reactants are diluted by a recirculation of a part of the flue gases (like N2/O2/CO2). But, the chemical kinetic, the energetic efficiencies, the radiation transfer, the transport and thermal properties of the flow can be affected by CO2. The objective of this work will be to identify the behaviour of the combustion of premixed CH4/O2-enriched air, both diluted in N2 and CO2 and to determine the combustion parameters. This allows to recover the CH4/air conditions in terms of CO2 concentration in reactants, O2 excess, dilution rate, temperature of the reactants, etc. Experiments are performed on the laminar premixed flame using counterflow burner. To characterize the combustion behaviour, the flammability limits are determined and flame thickness and position are measured from PLIF-OH diagnostic. Further, CHEMKIN simulations are performed to check the validity of the GRI3.0 chemical kinetic mechanism for premixed CH4/air synthetic combustion and identify the leading phenomena.

  2. Energetic statistics of Baleares Islands in 1993. Estatistiques energetiques de les Illes Balears 1993

    Energy Technology Data Exchange (ETDEWEB)

    1994-01-01

    This annual report summarizes the energetic and demand. It is focussed to analyze the energetic fuel (natural gas). The environment, and energetic supplies. Statistical data of energetic production, distribution and consumption in 1992 and 1993 are introduced.

  3. Assessing Spontaneous Combustion Instability with Nonlinear Time Series Analysis

    Science.gov (United States)

    Eberhart, C. J.; Casiano, M. J.

    2015-01-01

    Considerable interest lies in the ability to characterize the onset of spontaneous instabilities within liquid propellant rocket engine (LPRE) combustion devices. Linear techniques, such as fast Fourier transforms, various correlation parameters, and critical damping parameters, have been used at great length for over fifty years. Recently, nonlinear time series methods have been applied to deduce information pertaining to instability incipiency hidden in seemingly stochastic combustion noise. A technique commonly used in biological sciences known as the Multifractal Detrended Fluctuation Analysis has been extended to the combustion dynamics field, and is introduced here as a data analysis approach complementary to linear ones. Advancing, a modified technique is leveraged to extract artifacts of impending combustion instability that present themselves a priori growth to limit cycle amplitudes. Analysis is demonstrated on data from J-2X gas generator testing during which a distinct spontaneous instability was observed. Comparisons are made to previous work wherein the data were characterized using linear approaches. Verification of the technique is performed by examining idealized signals and comparing two separate, independently developed tools.

  4. Contact diagnostics of combustion products of rocket engines, their units, and systems

    Science.gov (United States)

    Ivanov, N. N.; Ivanov, A. N.

    2013-12-01

    This article is devoted to a new block-module device used in the diagnostics of condensed combustion products of rocket engines during research and development with liquid-propellant rocket engines (Glushko NPO Energomash; engines RD-171, RD-180, and RD-191) and solid-propellant rocket motors. Soot samplings from the supersonic high-temperature jet of a high-power liquid-propellant rocket engine were taken by the given device for the first time in practice for closed-exhaust lines. A large quantity of significant results was also obtained during a combustion investigation of solid propellants within solid-propellant rocket motors.

  5. Characterisation of wood combustion ashes

    DEFF Research Database (Denmark)

    Maresca, Alberto

    for their composition and leaching properties. Despite the relatively large variations in the contents of nutrients and trace metals, the overall levels were comparable to typical ranges reported in the literature for other wood combustion ashes, as well as with regards to leaching. In general, the composition......The combustion of wood chips and wood pellets for the production of renewable energy in Denmark increased from 5.7 PJ to 16 PJ during the period 2000-2015, and further increases are expected to occur within the coming years. In 2012, about 22,300 tonnes of wood ashes were generated in Denmark....... Currently, these ashes are mainly landfilled, despite Danish legislation allowing their application onto forest and agricultural soils for fertilising and/or liming purposes. During this PhD work, 16 wood ash samples generated at ten different Danish combustion plants were collected and characterised...

  6. Combustion of droplets and sprays

    Science.gov (United States)

    Eigenbrod, Christian; Sattelmayer, Thomas; Bäßler, Stefan; Mauss, Fabian; Meisl, Jürgen; Oomens, Bas; Rackwitz, Leif; Tait, Nigel; Angelberger, Christian; Eilts, Peter; Magnusson, Ingemar; Lauvergne, Romain; Tatschl, Reinhard

    2005-10-01

    The combustion of liquid hydrocarbon fuels in internal combustion engines and gas turbines for energy production and aircraft propulsion is intrinsically tied to the formation of pollutants. Apart from aiming for the highest combustion efficiencies in order to lower the operational costs and the emission of CO2, the reduction of poisonous and environmentally harmful exhaust constituents is a challenging task for scientists and engineers. The most prominent pollutants are soot, identified to trigger respiratory diseases and cancer, and nitric oxides such as NO and NO2, which promote the formation of ozone affecting the cardiovascular system when released in the lower atmosphere. Soot and nitric oxides are greenhouse pollutants in the upper atmosphere. Even though only 2-3% of the anthropogenic emission of nitric oxides are contributed by aircraft, it is the only emission at high altitudes. Unfortunately, it has the greatest impact on climate there and it does not matter whether the fuels are fossil or, in the future, biomass.

  7. Novel Active Combustion Control Valve

    Science.gov (United States)

    Caspermeyer, Matt

    2014-01-01

    This project presents an innovative solution for active combustion control. Relative to the state of the art, this concept provides frequency modulation (greater than 1,000 Hz) in combination with high-amplitude modulation (in excess of 30 percent flow) and can be adapted to a large range of fuel injector sizes. Existing valves often have low flow modulation strength. To achieve higher flow modulation requires excessively large valves or too much electrical power to be practical. This active combustion control valve (ACCV) has high-frequency and -amplitude modulation, consumes low electrical power, is closely coupled with the fuel injector for modulation strength, and is practical in size and weight. By mitigating combustion instabilities at higher frequencies than have been previously achieved (approximately 1,000 Hz), this new technology enables gas turbines to run at operating points that produce lower emissions and higher performance.

  8. Building energetic material from novel salix leaf-like CuO and nano-Al through electrophoretic deposition

    Energy Technology Data Exchange (ETDEWEB)

    Yin, Yan Jun; Li, Xueming [College of Chemistry and Chemical Engineering, Chongqing University, Chongqing (China)

    2016-11-15

    In this study, an energetic material was prepared by depositing nano-Al on CuO arrays via electrophoretic deposition (EPD), which offers a feasible route for nano-Al integration. The morphology and structure of the CuO arrays and Al/CuO composites were characterized by scanning electron microscopy and X-ray diffraction. The CuO arrays were homogenously salix leaf-like structure with a width of ⁓150 to 200 nm. The energy density of Al/CuO composites was approximate to 1454.5 J/g by integrating the differential scanning calorimetry (DSC) plot and the combustion performance was recorded by a high-speed camera. Moreover, the combustion flames were violent and the whole reaction process only lasted 72.2 ms, indicating that the energy of the Al/CuO nanothermite can be released effectively.

  9. Photovoltaic device

    Science.gov (United States)

    Reese, Jason A.; Keenihan, James R.; Gaston, Ryan S.; Kauffmann, Keith L.; Langmaid, Joseph A.; Lopez, Leonardo C.; Maak, Kevin D.; Mills, Michael E.; Ramesh, Narayan; Teli, Samar R.

    2015-09-01

    The present invention is premised upon an improved photovoltaic device ("PV device"), more particularly to an improved photovoltaic device (10) with a multilayered photovoltaic cell assembly (100) and a body portion (200) joined at an interface region (410) and including an intermediate layer (500), at least one interconnecting structural member (1500), relieving feature (2500), unique component geometry, or any combination thereof.

  10. Photovoltaic device

    Energy Technology Data Exchange (ETDEWEB)

    Reese, Jason A; Keenihan, James R; Gaston, Ryan S; Kauffmann, Keith L; Langmaid, Joseph A; Lopez, Leonardo; Maak, Kevin D; Mills, Michael E; Ramesh, Narayan; Teli, Samar R

    2017-03-21

    The present invention is premised upon an improved photovoltaic device ("PV device"), more particularly to an improved photovoltaic device with a multilayered photovoltaic cell assembly and a body portion joined at an interface region and including an intermediate layer, at least one interconnecting structural member, relieving feature, unique component geometry, or any combination thereof.

  11. Concentration device

    DEFF Research Database (Denmark)

    2013-01-01

    A concentration device (2) for filter filtration concentration of particles (4) from a volume of a fluid (6). The concentration device (2) comprises a filter (8) configured to filter particles (4) of a predefined size in the volume of the fluid (6). The concentration device (2) comprises...

  12. Autodesk Combustion 4 fundamentals courseware

    CERN Document Server

    Autodesk,

    2005-01-01

    Whether this is your first experience with Combustion software or you're upgrading to take advantage of the many new features and tools, this guide will serve as your ultimate resource to this all-in-one professional compositing application. Much more than a point-and-click manual, this guide explains the principles behind the software, serving as an overview of the package and associated techniques. Written by certified Autodesk training specialists for motion graphic designers, animators, and visual effects artists, Combustion 4 Fundamentals Courseware provides expert advice for all skill le

  13. Chemical kinetics and combustion modeling

    Energy Technology Data Exchange (ETDEWEB)

    Miller, J.A. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01

    The goal of this program is to gain qualitative insight into how pollutants are formed in combustion systems and to develop quantitative mathematical models to predict their formation rates. The approach is an integrated one, combining low-pressure flame experiments, chemical kinetics modeling, theory, and kinetics experiments to gain as clear a picture as possible of the process in question. These efforts are focused on problems involved with the nitrogen chemistry of combustion systems and on the formation of soot and PAH in flames.

  14. Catalytic Combustion of Ethyl Acetate

    OpenAIRE

    ÖZÇELİK, Tuğba GÜRMEN; ATALAY, Süheyda; ALPAY, Erden

    2014-01-01

    The catalytic combustion of ethyl acetate over prepared metal oxide catalysts was investigated. CeO, Co2O3, Mn2O3, Cr2O3, and CeO-Co2O3 catalysts were prepared on monolith supports and they were tested. Before conducting the catalyst experiments, we searched for the homogeneous gas phase combustion reaction of ethyl acetate. According to the homogeneous phase experimental results, 45% of ethyl acetate was converted at the maximum reactor temperature tested (350 °C). All the prepare...

  15. Assessment of CRBR core disruptive accident energetics

    Energy Technology Data Exchange (ETDEWEB)

    Theofanous, T.G.; Bell, C.R.

    1984-03-01

    The results of an independent assessment of core disruptive accident energetics for the Clinch River Breeder Reactor are presented in this document. This assessment was performed for the Nuclear Regulatory Commission under the direction of the CRBR Program Office within the Office of Nuclear Reactor Regulation. It considered in detail the accident behavior for three accident initiators that are representative of three different classes of events; unprotected loss of flow, unprotected reactivity insertion, and protected loss of heat sink. The primary system's energetics accommodation capability was realistically, yet conservatively, determined in terms of core events. This accommodation capability was found to be equivalent to an isentropic work potential for expansion to one atmosphere of 2550 MJ or a ramp rate of about 200 $/s applied to a classical two-phase disassembly.

  16. Energetics in robotic flight at small scales.

    Science.gov (United States)

    Karydis, Konstantinos; Kumar, Vijay

    2017-02-06

    Recent advances in design, sensing and control have led to aerial robots that offer great promise in a range of real-world applications. However, one critical open question centres on how to improve the energetic efficiency of aerial robots so that they can be useful in practical situations. This review paper provides a survey on small-scale aerial robots (i.e. less than 1 m 2 area foot print, and less than 3 kg weight) from the point of view of energetics. The paper discusses methods to improve the efficiency of aerial vehicles, and reports on recent findings by the authors and other groups on modelling the impact of aerodynamics for the purpose of building energy-aware motion planners and controllers.

  17. Quantitative Analysis of Hohlraum Energetics Modeling

    Science.gov (United States)

    Patel, Mehul V.; Mauche, Christopher W.; Jones, Odgen S.; Scott, Howard A.

    2016-10-01

    New 1D/2D hohlraum models have been developed to enable quantitative studies of ICF hohlraum energetics. The models employ sufficient numerical resolution (spatial, temporal discetization, radiation energy groups, laser rays, IMC photons) to satisfy a priori convergence criteria on the observables to be compared. For example, we aim for numerical errors of less than 5% in the predicted X-ray flux. Post shot simulations using the new models provide quantitative assessments of the accuracy of energetics modeling across a range of ICF platforms. The models have also been used to reexamine physics sensitivities in the modeling of the NLTE wall plasma. This work is guiding improvements in the underlying DCA atomic physics models and the radiation hydrodynamics code (HYDRA). Prepared by LLNL under Contract DE-AC52-07NA27344.

  18. Energetic Particle Estimates for Stellar Flares

    Science.gov (United States)

    Youngblood, Allison; Chamberlin, Phil; Woods, Tom

    2018-01-01

    In the heliosphere, energetic particles are accelerated away from the Sun during solar flares and/or coronal mass ejections where they frequently impact the Earth and other solar system bodies. Solar (or stellar) energetic particles (SEPs) not only affect technological assets, but also influence mass loss and chemistry in planetary atmospheres (e.g., depletion of ozone). SEPs are increasingly recognized as an important factor in assessing exoplanet habitability, but we do not yet have constraints on SEP emission from any stars other than the Sun. Until indirect measurements are available, we must assume solar-like particle production and apply correlations between solar flares and SEPs detected near Earth to stellar flares. We present improved scaling relations between solar far-UV flare flux and >10 MeV proton flux near Earth. We apply these solar scaling relations to far-UV flares from exoplanet host stars and discuss the implications for modeling chemistry and mass loss in exoplanet atmospheres.

  19. Application of the FIRST Combustion model to Spray Combustion

    NARCIS (Netherlands)

    de Jager, B.; Kok, Jacobus B.W.

    2004-01-01

    Liquid fuel is of interest to apply to gas turbines. The large advantage is that liquids are easily storable as compared to gaseous fuels. Disadvantage is that liquid fuel has to be sprayed, vaporized and mixed with air. Combustion occurs at some stage of mixing and ignition. Depending on the

  20. Scramjet Combustion Stability Behavior Modeling Project

    Data.gov (United States)

    National Aeronautics and Space Administration — A recent breakthrough in combustion stability analysis (UCDS) offers the means to accurately predict the combustion stability of a scramjet. This capability is very...

  1. Scramjet Combustion Stability Behavior Modeling Project

    Data.gov (United States)

    National Aeronautics and Space Administration — A recent breakthrough in combustion stability analysis (UCDS) offers the potential to predict the combustion stability of a scramjet. This capability is very...

  2. Free Energy and Internal Combustion Engine Cycles

    OpenAIRE

    Harris, William D.

    2012-01-01

    The performance of one type (Carnot) of Internal Combustion Engine (ICE) cycle is analyzed within the framework of thermodynamic free energies. ICE performance is different from that of an External Combustion Engine (ECE) which is dictated by Carnot's rule.

  3. The energetic alpha particle transport method EATM

    Energy Technology Data Exchange (ETDEWEB)

    Kirkpatrick, R.C.

    1998-02-01

    The EATM method is an evolving attempt to find an efficient method of treating the transport of energetic charged particles in a dynamic magnetized (MHD) plasma for which the mean free path of the particles and the Larmor radius may be long compared to the gradient lengths in the plasma. The intent is to span the range of parameter space with the efficiency and accuracy thought necessary for experimental analysis and design of magnetized fusion targets.

  4. Energetic ion leakage from foreshock transient cores

    Science.gov (United States)

    Liu, Terry Z.; Angelopoulos, Vassilis; Hietala, Heli

    2017-07-01

    Earth's foreshock is filled with backstreaming particles that can interact with the ambient solar wind and its discontinuities to form foreshock transients. Many foreshock transients have a core with low dynamic pressure that can significantly perturb the bow shock and the magnetosphere-ionosphere system. Foreshock transients have also been recently recognized as sites of particle acceleration, which may be important for seeding the parent shock with energetic particles. A relevant step of this seeding would be energetic ion leakage into the surrounding foreshock environment. On the other hand, such leakage would also suppress the energetic particle flux contrast across foreshock transients' boundaries masking their perceived contribution to ion energization. To further examine this hypothesis of ion leakage, we report on multipoint case studies of three foreshock transient events selected from a large database. The cases were selected to exemplify, in increasing complexity, the nature and consequences of energetic ion leakage. Ion energy dispersion, observed upstream and/or downstream of the foreshock transients, is explained with a simple, ballistic model of ions leaking from the foreshock transients. Larger energies are required for leaked ions to reach the spacecraft as the distance between the transient and spacecraft increases. Our model, which explains well the observed ion energy dispersion and velocity distributions, can also be used to reveal the shape of the foreshock transients in three dimensions. Our results suggest that ion leakage from foreshock transient cores needs to be accounted for both in statistical studies and in global models of ion acceleration under quasi-parallel foreshock conditions.

  5. Energetic particle instabilities in fusion plasmas

    Science.gov (United States)

    Sharapov, S. E.; Alper, B.; Berk, H. L.; Borba, D. N.; Breizman, B. N.; Challis, C. D.; Classen, I. G. J.; Edlund, E. M.; Eriksson, J.; Fasoli, A.; Fredrickson, E. D.; Fu, G. Y.; Garcia-Munoz, M.; Gassner, T.; Ghantous, K.; Goloborodko, V.; Gorelenkov, N. N.; Gryaznevich, M. P.; Hacquin, S.; Heidbrink, W. W.; Hellesen, C.; Kiptily, V. G.; Kramer, G. J.; Lauber, P.; Lilley, M. K.; Lisak, M.; Nabais, F.; Nazikian, R.; Nyqvist, R.; Osakabe, M.; Perez von Thun, C.; Pinches, S. D.; Podesta, M.; Porkolab, M.; Shinohara, K.; Schoepf, K.; Todo, Y.; Toi, K.; Van Zeeland, M. A.; Voitsekhovich, I.; White, R. B.; Yavorskij, V.; TG, ITPA EP; Contributors, JET-EFDA

    2013-10-01

    Remarkable progress has been made in diagnosing energetic particle instabilities on present-day machines and in establishing a theoretical framework for describing them. This overview describes the much improved diagnostics of Alfvén instabilities and modelling tools developed world-wide, and discusses progress in interpreting the observed phenomena. A multi-machine comparison is presented giving information on the performance of both diagnostics and modelling tools for different plasma conditions outlining expectations for ITER based on our present knowledge.

  6. Energetic particle instabilities in fusion plasmas

    CERN Document Server

    Sharapov, S E; Berk, H L; Borba, D N; Breizman, B N; Challis, C D; Classen, I G J; Edlund, E M; Eriksson, J; Fasoli, A; Fredrickson, E D; Fu, G Y; Garcia-Munoz, M; Gassner, T; Ghantous, K; Goloborodko, V; Gorelenkov, N N; Gryaznevich, M P; Hacquin, S; Heidbrink, W W; Hellesen, C; Kiptily, V G; Kramer, G J; Lauber, P; Lilley, M K; Lisak, M; Nabais, F; Nazikian, R; Nyqvist, R; Osakabe, M; von Thun, C Perez; Pinches, S D; Podesta, M; Porkolab, M; Shinohara, K; Schoepf, K; Todo, Y; Toi, K; Van Zeeland, M A; Voitsekhovich, I; White, R B; Yavorskij, V; TG, ITPA EP; Contributors, JET-EFDA

    2013-01-01

    Remarkable progress has been made in diagnosing energetic particle instabilities on present-day machines and in establishing a theoretical framework for describing them. This overview describes the much improved diagnostics of Alfven instabilities and modelling tools developed world-wide, and discusses progress in interpreting the observed phenomena. A multi-machine comparison is presented giving information on the performance of both diagnostics and modelling tools for different plasma conditions outlining expectations for ITER based on our present knowledge.

  7. Energetic cost of walking in fossil hominins.

    Science.gov (United States)

    Vidal-Cordasco, M; Mateos, A; Zorrilla-Revilla, G; Prado-Nóvoa, O; Rodríguez, J

    2017-11-01

    Many biomechanical studies consistently show that a broader pelvis increases the reaction forces and bending moments across the femoral shaft, increasing the energetic costs of unloaded locomotion. However, a biomechanical model does not provide the real amount of metabolic energy expended in walking. The aim of this study is to test the influence of pelvis breadth on locomotion cost and to evaluate the locomotion efficiency of extinct Pleistocene hominins. The current study measures in vivo the influence of pelvis width on the caloric cost of locomotion, integrating anthropometry, body composition and indirect calorimetry protocols in a sample of 46 subjects of both sexes. We show that a broader false pelvis is substantially more efficient for locomotion than a narrower one and that the influence of false pelvis width on the energetic cost is similar to the influence of leg length. Two models integrating body mass, femur length and bi-iliac breadth are used to estimate the net and gross energetic costs of locomotion in a number of extinct hominins. The results presented here show that the locomotion of Homo was not energetically more efficient than that of Australopithecus and that the locomotion of extinct Homo species was not less efficient than that of modern Homo sapiens. The changes in the anatomy of the pelvis and lower limb observed with the appearance of Homo ergaster probably did not fully offset the increased expenditure resulting from a larger body mass. Moreover, the narrow pelvis in modern humans does not contribute to greater efficiency of locomotion. © 2017 Wiley Periodicals, Inc.

  8. Novel Energetic Materials for Counter WMD Applications

    Science.gov (United States)

    2011-09-01

    TNT. Thermal and hydrolytic stabilities are acceptable. Polymer salts ofN-vinyl triazolium monomeric salts were prepared by polymerization of the N...0 0 _, 0 •1. .1𔃿. ’SUBJECT TERMS ,. high energy heterocycles , pentafluorosulfanyl monomers and polymers , high nitrogen species, density, heat...Nitroimino tetrazoles were considerably more energetic than their nitroimino triazole counterparts; however, the triazoles are more stable thermally . In

  9. Probing Kill Mechanisms and Tuning Energetic Biocides

    Science.gov (United States)

    2018-02-01

    attributed to the unique porous inner structure combined with energetic gas generator nitrocellulose which we have previously shown minimizes sintering among...as the temperature increased 373 suggesting that HCl/HOCl is more effective in spore neutralization. HCl and HOCl have unique 374 chemical properties...Disinfection of Bacillus subtilis spore-contaminated surface 512 materials with a sodium hypochlorite and a hydrogen peroxide-based sanitizer, Lett

  10. Energetic Materials for Bio-Agent Destruction

    Science.gov (United States)

    2017-03-01

    work was to produce known energetic materials or design and produce new materials which upon detonation will destroy support/storage facilities while...permit prediction of the likelihood and desirability of synthesis of the proposed materials based on density, heat of formation and detonation...sensitive the compound is. Based upon electrostatic potential ( ESP ) calculations, 18 has wider and stronger positive potentials, and 20 has the weakest

  11. Fundamental energetic limits of radio communication systems

    Science.gov (United States)

    Baudais, Jean-Yves

    2017-02-01

    The evaluation of the energy consumption of a radiocommunication requires to analyse the life cycle of the elements used. However, this analysis does not specify the energetic limits. Theoretical approaches allow one to draw these limits, which are known in multiple cases of information transmission. However, the answers are not always satisfactory, in particular in the case of time-varying channels. After a brief presentation of the notion of energetic limits of a radiocommunication, and beginning with a global approach, we show that, contrary to the published results, the energetic limits always differ from zero if the physical constraints are correctly expressed. xml:lang="fr" Cependant, les réponses ne sont pas toujours satisfaisantes, particulièrement dans le cas de canaux variants dans le temps. Après une rapide présentation des notions d'énergie limite d'une radiocommunication, et en commençant par une approche globale du problème, nous montrons que, contrairement aux résultats publiés, les limites énergétiques sont toujours différentes de zéro si les contraintes physiques sont correctement exprimées.

  12. Energetic particle investigation using the ERNE instrument

    Directory of Open Access Journals (Sweden)

    J. Torsti

    1996-05-01

    Full Text Available During solar flares and coronal mass ejections, nuclei and electrons accelerated to high energies are injected into interplanetary space. These accelerated particles can be detected at the SOHO satellite by the ERNE instrument. From the data produced by the instrument, it is possible to identify the particles and to calculate their energy and direction of propagation. Depending on variable coronal/interplanetary conditions, different kinds of effects on the energetic particle transport can be predicted. The problems of interest include, for example, the effects of particle properties (mass, charge, energy, and propagation direction on the particle transport, the particle energy changes in the transport process, and the effects the energetic particles have on the solar-wind plasma. The evolution of the distribution function of the energetic particles can be measured with ERNE to a better accuracy than ever before. This gives us the opportunity to contribute significantly to the modeling of interplanetary transport and acceleration. Once the acceleration/transport bias has been removed, the acceleration-site abundance of elements and their isotopes can be studied in detail and compared with spectroscopic observations.

  13. Calculation of the energetics of chemical reactions

    Energy Technology Data Exchange (ETDEWEB)

    Dunning, T.H. Jr.; Harding, L.B.; Shepard, R.L.; Harrison, R.J.

    1988-01-01

    To calculate the energetics of chemical reactions we must solve the electronic Schroedinger equation for the molecular conformations of importance for the reactive encounter. Substantial changes occur in the electronic structure of a molecular system as the reaction progresses from reactants through the transition state to products. To describe these changes, our approach includes the following three elements: the use of multiconfiguration self-consistent field wave functions to provide a consistent zero-order description of the electronic structure of the reactants, transition state, and products; the use of configuration interaction techniques to describe electron correlation effects needed to provide quantitative predictions of the reaction energetics; and the use of large, optimized basis sets to provide the flexibility needed to describe the variations in the electronic distributions. With this approach we are able to study reactions involving as many as 5--6 atoms with errors of just a few kcal/mol in the predicted reaction energetics. Predictions to chemical accuracy, i.e., to 1 kcal/mol or less, are not yet feasible, although continuing improvements in both the theoretical methodology and computer technology suggest that this will soon be possible, at least for reactions involving small polyatomic species. 4 figs.

  14. High Frequency Combustion Instabilities of LOx/CH4 Spray Flames in Rocket Engine Combustion Chambers

    NARCIS (Netherlands)

    Sliphorst, M.

    2011-01-01

    Ever since the early stages of space transportation in the 1940’s, and the related liquid propellant rocket engine development, combustion instability has been a major issue. High frequency combustion instability (HFCI) is the interaction between combustion and the acoustic field in the combustion

  15. Light emitting ceramic device

    Science.gov (United States)

    Valentine, Paul; Edwards, Doreen D.; Walker, Jr., William John; Slack, Lyle H.; Brown, Wayne Douglas; Osborne, Cathy; Norton, Michael; Begley, Richard

    2010-05-18

    A light-emitting ceramic based panel, hereafter termed "electroceramescent" panel, is herein claimed. The electroceramescent panel is formed on a substrate providing mechanical support as well as serving as the base electrode for the device. One or more semiconductive ceramic layers directly overlay the substrate, and electrical conductivity and ionic diffusion are controlled. Light emitting regions overlay the semiconductive ceramic layers, and said regions consist sequentially of a layer of a ceramic insulation layer and an electroluminescent layer, comprised of doped phosphors or the equivalent. One or more conductive top electrode layers having optically transmissive areas overlay the light emitting regions, and a multi-layered top barrier cover comprising one or more optically transmissive non-combustible insulation layers overlay said top electrode regions.

  16. Automatic shading effects on the energetic performance of building systems; Efeito do sombreamento automatico no desempenho de sistemas prediais

    Energy Technology Data Exchange (ETDEWEB)

    Prado, Racine Tadeu Araujo

    1996-12-31

    This thesis develops a theoretic-experimental study dealing with the effects of an automatic shading device on the energetic performance of a dimmable lighting system and a cooling equipment. Some equations related to fenestration optical and thermal properties are rebuilt, while some others are created, under a theoretical approach. In order to collect field data, the energy demand-and other variables - was measured in two distinct stories, with the same fenestration features, of the Test Tower. New data was gathered after adding an automatic shading device to the window of one story. The comparison of the collected data allows the energetic performance evaluation of the shading device. (author) 136 refs., 55 figs., 6 tabs.

  17. Straw combustion on slow-moving grates

    DEFF Research Database (Denmark)

    Kær, Søren Knudsen

    2005-01-01

    Combustion of straw in grate-based boilers is often associated with high emission levels and relatively poor fuel burnout. A numerical grate combustion model was developed to assist in improving the combustion performance of these boilers. The model is based on a one-dimensional ‘‘walking...

  18. 30 CFR 56.4104 - Combustible waste.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Combustible waste. 56.4104 Section 56.4104... Control Prohibitions/precautions/housekeeping § 56.4104 Combustible waste. (a) Waste materials, including... properly, waste or rags containing flammable or combustible liquids that could create a fire hazard shall...

  19. Laboratory Test of Reciprocating Internal Combustion Engines

    Science.gov (United States)

    2016-02-04

    700, Laboratory Tests of Reciprocating Internal Combustion Engines , dated 24 January 1985. Marginal notations are not used in this revision to...performance and endurance of reciprocating internal combustion engines . Test equipment includes engine dynamometers, precision fuel flow meters, oil...D-1 *This TOP supersedes TOP 02-2-700, Laboratory Tests of Reciprocating Internal Combustion Engines , dated 24

  20. Furnaces with multiple ?ameless combustion burners

    NARCIS (Netherlands)

    Danon, B.

    2011-01-01

    In this thesis three different combustion systems, equipped with either a single or multiple ?ameless combustion burner(s), are discussed. All these setups were investigated both experimentally and numerically, i.e., using Computational Fluid Dynamics (CFD) simulations. Flameless combustion is a

  1. Effect of the grinding behaviour of coal blends on coal utilisation for combustion

    Energy Technology Data Exchange (ETDEWEB)

    Rubiera, F.; Arenillas, A.; Fuente, E.; Pis, J.J. [Inst. Nacional del Carbon, CSIC, Oviedo (Spain); Miles, N. [School of Chemical, Environmental and Mining Engineering, Nottingham Univ. (United Kingdom)

    1999-11-01

    Grinding of a high volatile bituminous coal was performed in three comminution devices: Raymond Mill (RM), Rolls Crusher (RC) and Ball Mill (BM). The pulverised samples were sieved to obtain four particle size fractions, and temperature-programmed combustion (TPC) was used for the evaluation of their combustion behaviour. In addition, three coals of different hardness and rank were mixed in various proportions in order to compare the combustibility characteristics of the binary coal blends with those of the individual coals. The effect of coal blending on grindability was also studied. It was found that grindability was non-additive especially when coals of very different hardgrove grindability index (HGI) were blended. The combustion studies also suggested that there exists an interaction between individual coals when they are burnt as a blend. (orig.)

  2. Sulfur Chemistry in Combustion II

    DEFF Research Database (Denmark)

    Johnsson, Jan Erik; Kiil, Søren

    2000-01-01

    Several options are available to control the emission of SO2 from combustion processes. One possibility is to use a cleaner technology, i.e. fuel switching from oil and coal to natural gas or biomass, or to desulphurize coal and oil. Another possibility is to change to a different technology...

  3. Structural Analysis of Combustion Models

    CERN Document Server

    Tóth, J; Zsély, I

    2013-01-01

    Using ReactionKinetics, a Mathematica based package a few dozen detailed models for combustion of hydrogen, carbon monoxide and methanol are investigated. Essential structural characteristics are pulled out, and similarities and differences of the mechanisms are highlighted. These investigations can be used before or parallel with usual numerical investigations, such as pathway analysis, sensitivity analysis, parameter estimation, or simulation.

  4. 75 FR 3881 - Combustible Dust

    Science.gov (United States)

    2010-01-25

    ... may form combustible dust include, but are not limited to, wood, coal, plastics, biosolids, candy..., pharmaceutical manufacturing, tire manufacturing, production of rubber and plastics, plastics and rubber products manufacturing, recycling, wastewater treatment, and coal handling. OSHA is developing a standard that will...

  5. Ignition Sensitivity and Electrical Conductivity of a Composite Energetic Material with Conductive Nanofillers

    Energy Technology Data Exchange (ETDEWEB)

    Eric S. Collins; Brandon R. Skelton; Michelle L. Pantoya; Fahmida Irin; Micah J. Green; Michael A. Daniels

    2014-12-01

    The safe handling of powdered composite energetic materials requires an understanding of their response to electrostatic ignition stimuli. A binary composite comprised of Al and polytetrafluoroethylene (PTFE) was tailored for ESD ignition sensitivity with varied concentrations of highly conductive nanofillers. The goal was to control the ESD ignition response of the Al+PTFE with small concentrations of nanofillers that may not significantly affect the overall combustion performance of the mixture. The nanofillers examined include carbon nanotubes (CNTs) and graphene nanoplatelets (GNPs). Adding CNTs created percolation at a lower volumetric percentage than GNPs and were found to be the controlling nanofiller, creating percolation for the mixture containing both CNTs and GNPs. Various mixing methods were examined. Ignition was achieved only for adding nanofillers at a volumetric percentage and mixing method that led to a bulk conductivity of approximately 5x10-3 ?S/cm.

  6. CFD analysis of the pulverized coal combustion processes in a 160 MWe tangentially-fired-boiler of a thermal power plant

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Cristiano V. da; Beskow, Arthur B. [Universidade Regional Integrada do Alto Uruguai e das Misses (LABSIM/GEAPI/URI), Erechim, RS (Brazil). Dept. de Engenharia e Ciencia da Computacao. Grupo de Engenharia Aplicada a Processos Industriais], Emails: cristiano@uricer.edu.br, Arthur@uricer.edu.br; Indrusiak, Maria Luiza S. [Universidade do Vale do Rio dos Sinos (UNISINOS), Sao Leopoldo, RS (Brazil). Programa de Engenharia Mecanica], E-mail: sperbindrusiak@via-rs.net

    2010-10-15

    The strategic role of energy and the current concern with greenhouse effects, energetic and exegetic efficiency of fossil fuel combustion greatly enhance the importance of the studies of complex physical and chemical processes occurring inside boilers of thermal power plants. The state of the art in computational fluid dynamics and the availability of commercial codes encourage numeric studies of the combustion processes. In the present work the commercial software CFX Ansys Europe Ltd. was used to study the combustion of coal in a 160 MWe commercial thermal power plant with the objective of simulating the operational conditions and identifying factors of inefficiency. The behavior of the flow of air and pulverized coal through the burners was analyzed, and the three-dimensional flue gas flow through the combustion chamber and heat exchangers was reproduced in the numeric simulation. (author)

  7. Gaseous emissions from waste combustion.

    Science.gov (United States)

    Werther, Joachim

    2007-06-18

    An overview is given on methods and technologies for limiting the gaseous emissions from waste combustion. With the guideline 2000/76/EC recent European legislation has set stringent limits not only for the mono-combustion of waste in specialized incineration plants but also for co-combustion in coal-fired power plants. With increased awareness of environmental issues and stepwise decrease of emission limits and inclusion of more and more substances into the network of regulations a multitude of emission abatement methods and technologies have been developed over the last decades. The result is the state-of-the-art waste incinerator with a number of specialized process steps for the individual components in the flue gas. The present work highlights some new developments which can be summarized under the common goal of reducing the costs of flue gas treatment by applying systems which combine the treatment of several noxious substances in one reactor or by taking new, simpler routes instead of the previously used complicated ones or - in the case of flue gas desulphurisation - by reducing the amount of limestone consumption. Cost reduction is also the driving force for new processes of conditioning of nonhomogenous waste before combustion. Pyrolysis or gasification is used for chemical conditioning whereas physical conditioning means comminution, classification and sorting processes. Conditioning yields a fuel which can be used in power plants either as a co-fuel or a mono-fuel and which will burn there under much better controlled conditions and therefore with less emissions than the nonhomogeneous waste in a conventional waste incinerator. Also for cost reasons, co-combustion of wastes in coal-fired power stations is strongly pressing into the market. Recent investigations reveal that the co-firing of waste can also have beneficial effects on the operating behavior of the boiler and on the gaseous emissions.

  8. Combustion Kinetic Studies of Gasolines and Surrogates

    KAUST Repository

    Javed, Tamour

    2016-11-01

    Future thrusts for gasoline engine development can be broadly summarized into two categories: (i) efficiency improvements in conventional spark ignition engines, and (ii) development of advance compression ignition (ACI) concepts. Efficiency improvements in conventional spark ignition engines requires downsizing (and turbocharging) which may be achieved by using high octane gasolines, whereas, low octane gasolines fuels are anticipated for ACI concepts. The current work provides the essential combustion kinetic data, targeting both thrusts, that is needed to develop high fidelity gasoline surrogate mechanisms and surrogate complexity guidelines. Ignition delay times of a wide range of certified gasolines and surrogates are reported here. These measurements were performed in shock tubes and rapid compression machines over a wide range of experimental conditions (650 – 1250 K, 10 – 40 bar) relevant to internal combustion engines. Using the measured the data and chemical kinetic analyses, the surrogate complexity requirements for these gasolines in homogeneous environments are specified. For the discussions presented here, gasolines are classified into three categories: (i)\\tLow octane gasolines including Saudi Aramco’s light naphtha fuel (anti-knock index, AKI = (RON + MON)/2 = 64; Sensitivity (S) = RON – MON = 1), certified FACE (Fuels for Advanced Combustion Engines) gasoline I and J (AKI ~ 70, S = 0.7 and 3 respectively), and their Primary Reference Fuels (PRF, mixtures of n-heptane and iso-octane) and multi-component surrogates. (ii)\\t Mid octane gasolines including FACE A and C (AKI ~ 84, S ~ 0 and 1 respectively) and their PRF surrogates. Laser absorption measurements of intermediate and product species formed during gasoline/surrogate oxidation are also reported. (iii)\\t A wide range of n-heptane/iso-octane/toluene (TPRF) blends to adequately represent the octane and sensitivity requirements of high octane gasolines including FACE gasoline F and G

  9. A test procedure for energetic and performance analysis of cold appliances for the food industry

    Science.gov (United States)

    Armani, F.; Boscolo, A.

    2013-09-01

    In this article we present a novel approach for the characterization of cold appliances and in particular of refrigerators based on the standard vapour compression cycle with a reciprocating on/off compressor. The test procedure is based on a virtual instrument that perform both the stimulus and the data acquisition on the device under test. Acquired data is elaborated to fit a semi-empirical model based on the energetic balances between thermal and electrical sub systems and the heat exchanged with the environment. This approach results in a simple method to calculate useful parameters of the refrigerator, such as energetic performance, cooling effect and limit values of thermal loads. The test procedure requires only a few temperatures and the electric power consumption to be monitored, resulting in a low impact on the refrigerator. Preliminary tests showed a good estimation of parameters and prediction of energy consumption and heat extraction capacity of the refrigerator under test.

  10. Combustion waves and fronts in flows flames, shocks, detonations, ablation fronts and explosion of stars

    CERN Document Server

    Clavin, Paul

    2016-01-01

    Combustion is a fascinating phenomenon coupling complex chemistry to transport mechanisms and nonlinear fluid dynamics. This book provides an up-to-date and comprehensive presentation of the nonlinear dynamics of combustion waves and other non-equilibrium energetic systems. The major advances in this field have resulted from analytical studies of simplified models performed in close relation with carefully controlled laboratory experiments. The key to understanding the complex phenomena is a systematic reduction of the complexity of the basic equations. Focusing on this fundamental approach, the book is split into three parts. Part I provides physical insights for physics-oriented readers, Part II presents detailed technical analysis using perturbation methods for theoreticians, and Part III recalls the necessary background knowledge in physics, chemistry and fluid dynamics. This structure makes the content accessible to newcomers to the physics of unstable fronts in flows, whilst also offering advanced mater...

  11. Heat storage for a bus petrol internal-combustion engine

    Science.gov (United States)

    Vasiliev, Leonard L.; Burak, Victor S.; Kulakov, Andry G.; Mishkinis, Donatas A.; Bohan, Pavel V.

    The heat storage (HS) system for pre-heating a bus petrol internal combustion engine to starting was mathematically modelled and experimentally investigated. The development of such devices is an extremely urgent problem especially for regions with a cold climate. We discuss how HS works on the effect of absorption and rejection of heat energy at a solid-liquid phase change of a HS substance. In the first part of the paper a numerical method to calculate the HS mass-dimensional parameters and their characteristics are described. In the experimental part of the paper results are given of experiments on the pre-heating device aiding to start a carburettor engine under operational conditions and analysis of data received. Practical confirmation of the theoretical development of HS devices for a bus engine for starting by pre-heating is given.

  12. Highly energetic phenomena in water electrolysis.

    Science.gov (United States)

    Postnikov, A V; Uvarov, I V; Lokhanin, M V; Svetovoy, V B

    2016-12-16

    Water electrolysis performed in microsystems with a fast change of voltage polarity produces optically invisible nanobubbles containing H2 and O2 gases. In this form the gases are able to the reverse reaction of water formation. Here we report extreme phenomena observed in a millimeter-sized open system. Under a frequency of driving pulses above 100 kHz the process is accompanied by clicking sounds repeated every 50 ms or so. Fast video reveals that synchronously with the click a bubble is growing between the electrodes which reaches a size of 300 μm in 50 μs. Detailed dynamics of the system is monitored by means of a vibrometer by observing a piece of silicon floating above the electrodes. The energy of a single event is estimated as 0.3 μJ and a significant part of this energy is transformed into mechanical work moving the piece. The observations are explained by the combustion of hydrogen and oxygen mixture in the initial bubble with a diameter of about 40 μm. Unusual combustion mechanism supporting spontaneous ignition at room temperature is responsible for the process. The observed effect demonstrates a principal possibility to build a microscopic internal combustion engine.

  13. Highly energetic phenomena in water electrolysis

    Science.gov (United States)

    Postnikov, A. V.; Uvarov, I. V.; Lokhanin, M. V.; Svetovoy, V. B.

    2016-12-01

    Water electrolysis performed in microsystems with a fast change of voltage polarity produces optically invisible nanobubbles containing H2 and O2 gases. In this form the gases are able to the reverse reaction of water formation. Here we report extreme phenomena observed in a millimeter-sized open system. Under a frequency of driving pulses above 100 kHz the process is accompanied by clicking sounds repeated every 50 ms or so. Fast video reveals that synchronously with the click a bubble is growing between the electrodes which reaches a size of 300 μm in 50 μs. Detailed dynamics of the system is monitored by means of a vibrometer by observing a piece of silicon floating above the electrodes. The energy of a single event is estimated as 0.3 μJ and a significant part of this energy is transformed into mechanical work moving the piece. The observations are explained by the combustion of hydrogen and oxygen mixture in the initial bubble with a diameter of about 40 μm. Unusual combustion mechanism supporting spontaneous ignition at room temperature is responsible for the process. The observed effect demonstrates a principal possibility to build a microscopic internal combustion engine.

  14. Microfabricated fuel heating value monitoring device

    Science.gov (United States)

    Robinson, Alex L [Albuquerque, NM; Manginell, Ronald P [Albuquerque, NM; Moorman, Matthew W [Albuquerque, NM

    2010-05-04

    A microfabricated fuel heating value monitoring device comprises a microfabricated gas chromatography column in combination with a catalytic microcalorimeter. The microcalorimeter can comprise a reference thermal conductivity sensor to provide diagnostics and surety. Using microfabrication techniques, the device can be manufactured in production quantities at a low per-unit cost. The microfabricated fuel heating value monitoring device enables continuous calorimetric determination of the heating value of natural gas with a 1 minute analysis time and 1.5 minute cycle time using air as a carrier gas. This device has applications in remote natural gas mining stations, pipeline switching and metering stations, turbine generators, and other industrial user sites. For gas pipelines, the device can improve gas quality during transfer and blending, and provide accurate financial accounting. For industrial end users, the device can provide continuous feedback of physical gas properties to improve combustion efficiency during use.

  15. Light Duty Efficient, Clean Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Donald Stanton

    2010-12-31

    Cummins has successfully completed the Light Duty Efficient Clean Combustion (LDECC) cooperative program with DoE. This program was established in 2007 in support of the Department of Energy's Vehicles Technologies Advanced Combustion and Emissions Control initiative to remove critical barriers to the commercialization of advanced, high efficiency, emissions compliant internal combustion (IC) engines for light duty vehicles. Work in this area expanded the fundamental knowledge of engine combustion to new regimes and advanced the knowledge of fuel requirements for these diesel engines to realize their full potential. All of the following objectives were met with fuel efficiency improvement targets exceeded: (1) Improve light duty vehicle (5000 lb. test weight) fuel efficiency by 10.5% over today's state-of-the-art diesel engine on the FTP city drive cycle; (2) Develop and design an advanced combustion system plus aftertreatment system that synergistically meets Tier 2 Bin 5 NOx and PM emissions standards while demonstrating the efficiency improvements; (3) Maintain power density comparable to that of current conventional engines for the applicable vehicle class; and (4) Evaluate different fuel components and ensure combustion system compatibility with commercially available biofuels. Key accomplishments include: (1) A 25% improvement in fuel efficiency was achieved with the advanced LDECC engine equipped with a novel SCR aftertreatment system compared to the 10.5% target; (2) An 11% improvement in fuel efficiency was achieved with the advanced LDECC engine and no NOx aftertreamtent system; (3) Tier 2 Bin 5 and SFTP II emissions regulations were met with the advanced LDECC engine equipped with a novel SCR aftertreatment system; (4) Tier 2 Bin 5 emissions regulations were met with the advanced LDECC engine and no NOx aftertreatment, but SFTP II emissions regulations were not met for the US06 test cycle - Additional technical barriers exist for the no NOx

  16. Combustion Aerosols from Pulverised Coal Combustion and Biomass Grate Combustion. Filtration aspects

    Energy Technology Data Exchange (ETDEWEB)

    Lillieblad, Lena [Vaexjoe Univ. (Sweden). Div. of Bioenergy Technology

    2005-06-01

    Combustion processes generate particles, which are formed both from the inorganic content in the fuel and from organic compounds as a result of incomplete combustion. The particles are removed from the flue gas by cyclones, electrostatic precipitators (ESPs) or fabric filters (FFs). The particle removal capacity is strongly depending on the particle properties, operating conditions and selected particle removal technology. The particle properties are depending on fuel type, combustion technique and combustion conditions. In this study the particle properties for two different types of solid fuel combustion were investigated and compared. The two processes were pulverised coal combustion and grate boilers operating on woody biomass. Characterisation of fuels was made both with standard analyses and more sophisticated methods like computer controlled scanning electron microscopy (CCSEM) and subsequent leaching procedures. A major difference between coal and woody biomass is the occurrence of potassium. In woody biofuel potassium is a reactive components, mainly water-soluble or organically associated, whereas it in coal it is associated to minerals like illite. The particle number size and particle mass size distributions were measured with low-pressure impactors (LPI), electrical mobility analysers and electrical low-pressure impactors (ELPI). The submicrometer particle mass concentration was similar for the two combustion processes. There is a difference between different coals and also between different woody biofuels. The coarse particle fraction is considerably larger for coal combustion, due to the high content of minerals in the coal. Potassium, sulphur and chlorine dominate the submicrometer particle chemical composition from wood fired grate boilers. Coarser particles have a high content of calcium. Silicon and aluminium are the major elements in particles from pulverised coal combustion. An enrichment of calcium, sulphur and phosphorous in the submicrometer

  17. Insensitive high-energy energetic structural material of tungsten-polytetrafluoroethylene-aluminum composites

    Directory of Open Access Journals (Sweden)

    Liu Wang

    2015-11-01

    Full Text Available Energetic structural material is a kind of materials that are inert under normal conditions but could produce exothermic chemical reaction when subjected to impact. This report shows a kind of energetic structural material of tungsten (W-polytetrafluoroethylene (PTFE-aluminum (Al with density of 4.12 g/cm3, excellent ductility and dynamic compressive strength of 96 MPa. Moreover, 50W-35PTFE-15Al (wt% can exhibit a high reaction energy value of more than 2 times of TNT per unit mass and 5 times of TNT per unit volume, respectively, but with excellent insensitivity compared with traditional explosives. Under thermal conditions, the W-PTFE-Al composite can keep stable at 773 K. Under impact loading, when the strain rate up to ∼4820 s−1 coupled with the absorbed energy per unit volume of 120 J/cm3, deflagration occurs and combustion lasts for 500 μs. During impact compressive deformation, the PTFE matrix is elongated into nano-fibers, thus significantly increases the reaction activity of W-PTFE-Al composites. The nano-fiber structure is necessary for the reaction of W-PTFE-Al composites. The formation of PTFE nano-fibers must undergo severe plastic deformation, and therefore the W-PTFE-Al composites exhibit excellent insensitivity and safety. Furthermore, the reaction mechanisms of W-PTFE-Al composites in argon and in air are revealed.

  18. Energetic Ion Interactions with the Galilean Satellites

    Science.gov (United States)

    Cooper, John F.

    2000-01-01

    The principal research tasks of this investigation are: (1) specification of the energetic (keV to MeV) ion environments upstream of the four Galilean satellites and (2) data analysis and numerical modeling of observed ion interactions with the satellites. Differential flux spectra are being compiled for the most abundant ions (protons, oxygen, and sulfur) from measurements at 20 keV to 100 MeV total energy by the Energetic Particle Detector (EPD) experiment and at higher ion energies by the Heavy Ion Counter (HIC) experiment. Runge-Kutta and other numerical techniques are used to propagate test particles sampled from the measured upstream spectra to the satellite surface or spacecraft through the local magnetic and corotational electric field environment of each satellite. Modeling of spatial variations in directional flux anisotropies measured during each close flyby provides limits on atomic charge states for heavy (O, S) magnetospheric ions and on internal or induced magnetic fields of the satellites. Validation of models for magnetic and electric field configurations then allows computation of rates for ion implantation, sputtering, and energy deposition into the satellite surfaces for further modeling of observable chemical changes induced by irradiation. Our ongoing work on production of oxidants and other secondary species by ice irradiation on Europa's surface has significant applications, already acknowledged in current literature, to astrobiological evolution. Finally, the work will improve understanding of energetic ion sources and sinks at the satellite orbits for improved modeling of magnetospheric transport processes. The scope of the research effort mainly includes data from the primary Galileo mission (1995-1997) but may also include some later data where directly relevant (e.g., comparison of J0 and I27 data for Io) to the primary mission objectives. Funding for this contract also includes partial support for our related education and public

  19. Complex nanostructures: synthesis and energetic applications

    Energy Technology Data Exchange (ETDEWEB)

    Liou, X.; Lin, Y.; Zhou, S.; Sheehan, S.; Wang, D. [Department of Chemistry, Merkert Chemistry Center, Boston College, 2609 Beacon St., Chestnut Hill, MA 02467 (United States)

    2010-07-01

    Connected through single crystalline junctions, low dimensional materials such as nanowires and nanorods form complex nanostructures. These new materials exhibit mechanical strengths and electrical conductivities superior to their constituents while maintaining comparable surface areas, an attribute ideal for energetic applications. More efficient solar cells, higher capacity batteries and better performing photoelectrochemical cells have been built using these materials. This article reviews this exciting new class of materials and covers topics from controlled syntheses to applications in photovoltaics, chemical energy conversion and electrical charge storage. Mechanisms responsible for the improved performance are discussed. The prospect of their applications in a broader energy-related field is analyzed. (author)

  20. Simmer analysis of prompt burst energetics experiments

    Energy Technology Data Exchange (ETDEWEB)

    Hitchcock, J.T.

    1982-03-01

    The Prompt Burst Energetics experiments are designed to measure the pressure behavior of fuel and coolant as working fluids during a hypothetical prompt burst disassembly in an LMFBR. The work presented in this report consists of a parametric study of PBE-5S, a fresh oxide fuel experiment, using SIMMER-II. The various pressure sources in the experiment are examined, and the dominant source identified as incondensable contaminant gasses in the fuel. The important modeling uncertainties and limitations of SIMMER-II as applied to these experiments are discussed.

  1. Reversibly formed bilayer vesicles: Energetics and polydispersity

    DEFF Research Database (Denmark)

    Bergstöm, M.

    1997-01-01

    orders of magnitude larger than where the local free energy minima of the equilibrium vesicle actually occur. Moreover, according to our analysis, the relative width of a vesicle size distribution, sigma(R)/R-max, is generally at full equilibrium equal to 0.283, independently of the energetic vesicle....... and a statistical-mechanical factor that accounts for the fluctuations in composition, chain packing density and shape. We demonstrate that the free energy required to form a spherical vesicle is made up of two main contributions: the (size-independent) work of bending the constituent monolayers and the work...

  2. Nonlinear Electromagnetic Interactions in Energetic Materials

    Science.gov (United States)

    Wood, M. A.; Dalvit, D. A. R.; Moore, D. S.

    2016-01-01

    We study the scattering of electromagnetic waves in anisotropic energetic materials. Nonlinear light-matter interactions in molecular crystals result in frequency-conversion and polarization changes. Applied electromagnetic fields of moderate intensity can induce these nonlinear effects without triggering chemical decomposition, offering a mechanism for the nonionizing identification of explosives. We use molecular-dynamics simulations to compute such two-dimensional THz spectra for planar slabs made of pentaerythritol tetranitrate and ammonium nitrate. We discuss third-harmonic generation and polarization-conversion processes in such materials. These observed far-field spectral features of the reflected or transmitted light may serve as an alternative tool for standoff explosive detection.

  3. Complex Nanostructures: Synthesis and Energetic Applications

    Directory of Open Access Journals (Sweden)

    Dunwei Wang

    2010-02-01

    Full Text Available Connected through single crystalline junctions, low dimensional materials such as nanowires and nanorods form complex nanostructures. These new materials exhibit mechanical strengths and electrical conductivities superior to their constituents while maintaining comparable surface areas, an attribute ideal for energetic applications. More efficient solar cells, higher capacity batteries and better performing photoelectrochemical cells have been built using these materials. This article reviews this exciting new class of materials and covers topics from controlled syntheses to applications in photovoltaics, chemical energy conversion and electrical charge storage. Mechanisms responsible for the improved performance are discussed. The prospect of their applications in a broader energy-related field is analyzed.

  4. Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Ojeda, William de

    2010-07-31

    The project which extended from November 2005 to May of 2010 demonstrated the application of Low Temperature Combustion (LTC) with engine out NOx levels of 0.2 g/bhp-hr throughout the program target load of 12.6bar BMEP. The project showed that the range of loads could be extended to 16.5bar BMEP, therefore matching the reference lug line of the base 2007 MY Navistar 6.4L V8 engine. Results showed that the application of LTC provided a dramatic improvement over engine out emissions when compared to the base engine. Furthermore LTC improved thermal efficiency by over 5% from the base production engine when using the steady state 13 mode composite test as a benchmark. The key enablers included improvements in the air, fuel injection, and cooling systems made in Phases I and II. The outcome was the product of a careful integration of each component under an intelligent control system. The engine hardware provided the conditions to support LTC and the controller provided the necessary robustness for a stable combustion. Phase III provided a detailed account on the injection strategy used to meet the high load requirements. During this phase, the control strategy was implemented in a production automotive grade ECU to perform cycle-by-cycle combustion feedback on each of the engine cylinders. The control interacted on a cycle base with the injection system and with the Turbo-EGR systems according to their respective time constants. The result was a unique system that could, first, help optimize the combustion system and maintain high efficiency, and secondly, extend the steady state results to the transient mode of operation. The engine was upgraded in Phase IV with a Variable Valve Actuation system and a hybrid EGR loop. The impact of the more versatile EGR loop did not provide significant advantages, however the application of VVA proved to be an enabler to further extend the operation of LTC and gain considerable benefits in fuel economy and soot reduction. Finally

  5. Characterization of energetic and non-energetic polymers for laser ablation propulsion applications

    Science.gov (United States)

    Paturi, Prem Kiran; Chelikani, Leela; Billa, Narasimha Rao; Guthikonda, Nagaraju; Jana, Tushar; Acrhem Team; School Of Chemistry Team

    2015-06-01

    Energetic Polymers, considered to be cleaner, environmental friendly materials are one of the primary candidates for future plasma thrusters. For e.g., energetic hydroxyl terminated polybutadiene (HTPB) is being used as a binder for high-performance composite propellants. Understanding the conversion of optical energy to kinetic energy is essential in evaluating these materials as thrusters. Spatio-temporal evolution of laser ablative (LA) and blow-off (BO) shock waves (SW) during laser excitation provide a valuable insight into the energy release of the polymers. LASW and LBOSW during 7 ns laser pulse (532 nm, 10Hz) interaction with ~ 200 micron thick HTPB and its variants with energetic additives taken in the form of a sheet were studied simultaneously using defocused shadowgraphic imaging over 0.2 - 30 μs time scales. The results were compared with non-energetic polyvinyl chloride (PVC) under same experimental conditions. The SW was observed to propagate faster through the HTPB variant compared to HTPB. Appearance of LBOSW at different time scales for the polymers revealed the shock propagation characteristics through the polymers. The work is supported by Defence Research and Developement Organization, India through Grants-in-Aid Program.

  6. Energetics of hydrogen bonding in proteins: a model compound study.

    OpenAIRE

    Habermann, S. M.; Murphy, K. P.

    1996-01-01

    Differences in the energetics of amide-amide and amide-hydroxyl hydrogen bonds in proteins have been explored from the effect of hydroxyl groups on the structure and dissolution energetics of a series of crystalline cyclic dipeptides. The calorimetrically determined energetics are interpreted in light of the crystal structures of the studied compounds. Our results indicate that the amide-amide and amide-hydroxyl hydrogen bonds both provide considerable enthalpic stability, but that the amide-...

  7. Fundamental studies of spray combustion

    Energy Technology Data Exchange (ETDEWEB)

    Li, S.C.; Libby, P.A.; Williams, F.A. [Univ. of California, San Diego, CA (United States)

    1997-12-31

    Our research on spray combustion involves both experiment and theory and addresses the characteristics of individual droplets and of sprays in a variety of flows: laminar and turbulent, opposed and impinging. Currently our focus concerns water and fuel sprays in two stage laminar flames, i.e., flames arising, for example from a stream of fuel and oxidizer flowing opposite to an air stream carrying a water spray. Our interest in these flames is motivated by the goals of reducing pollutant emissions and extending the range of stable spray combustion. There remains considerable research to be carried out in order to achieve these goals. Thus far our research on the characteristics of sprays in turbulent flows has been limited to nonreacting jets impinging on a plate but this work will be extended to opposed flows with and without a flame. In the following we discuss details of these studies and our plans for future work.

  8. Oxy-coal Combustion Studies

    Energy Technology Data Exchange (ETDEWEB)

    Wendt, J. [Univ. of Utah, Salt Lake City, UT (United States); Eddings, E. [Univ. of Utah, Salt Lake City, UT (United States); Lighty, J. [Univ. of Utah, Salt Lake City, UT (United States); Ring, T. [Univ. of Utah, Salt Lake City, UT (United States); Smith, P. [Univ. of Utah, Salt Lake City, UT (United States); Thornock, J. [Univ. of Utah, Salt Lake City, UT (United States); Y Jia, W. Morris [Univ. of Utah, Salt Lake City, UT (United States); Pedel, J. [Univ. of Utah, Salt Lake City, UT (United States); Rezeai, D. [Univ. of Utah, Salt Lake City, UT (United States); Wang, L. [Univ. of Utah, Salt Lake City, UT (United States); Zhang, J. [Univ. of Utah, Salt Lake City, UT (United States); Kelly, K. [Univ. of Utah, Salt Lake City, UT (United States)

    2012-01-06

    The objective of this project is to move toward the development of a predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. This validation research brings together multi-scale experimental measurements and computer simulations. The combination of simulation development and validation experiments is designed to lead to predictive tools for the performance of existing air fired pulverized coal boilers that have been retrofitted to various oxy-firing configurations. In addition, this report also describes novel research results related to oxy-combustion in circulating fluidized beds. For pulverized coal combustion configurations, particular attention is focused on the effect of oxy-firing on ignition and coal-flame stability, and on the subsequent partitioning mechanisms of the ash aerosol.

  9. Combustion synthesis continuous flow reactor

    Energy Technology Data Exchange (ETDEWEB)

    Maupin, G.D.; Chick, L.A.; Kurosky, R.P.

    1998-01-06

    The present invention is a reactor for combustion synthesis of inorganic powders. The reactor includes a reaction vessel having a length and a first end and a second end. The reaction vessel further has a solution inlet and a carrier gas inlet. The reactor further has a heater for heating both the solution and the carrier gas. In a preferred embodiment, the reaction vessel is heated and the solution is in contact with the heated reaction vessel. It is further preferred that the reaction vessel be cylindrical and that the carrier gas is introduced tangentially into the reaction vessel so that the solution flows helically along the interior wall of the reaction vessel. As the solution evaporates and combustion produces inorganic material powder, the carrier gas entrains the powder and carries it out of the reactor. 10 figs.

  10. Combustion synthesis continuous flow reactor

    Energy Technology Data Exchange (ETDEWEB)

    Maupin, Gary D. (Richland, WA); Chick, Lawrence A. (West Richland, WA); Kurosky, Randal P. (Maple Valley, WA)

    1998-01-01

    The present invention is a reactor for combustion synthesis of inorganic powders. The reactor includes a reaction vessel having a length and a first end and a second end. The reaction vessel further has a solution inlet and a carrier gas inlet. The reactor further has a heater for heating both the solution and the carrier gas. In a preferred embodiment, the reaction vessel is heated and the solution is in contact with the heated reaction vessel. It is further preferred that the reaction vessel be cylindrical and that the carrier gas is introduced tangentially into the reaction vessel so that the solution flows helically along the interior wall of the reaction vessel. As the solution evaporates and combustion produces inorganic material powder, the carrier gas entrains the powder and carries it out of the reactor.

  11. Fluctuations in the Energetic Properties of a Spark-Ignition Engine Model with Variability

    Directory of Open Access Journals (Sweden)

    Fernando Angulo-Brown

    2013-08-01

    Full Text Available We study the energetic functions obtained in a simulated spark-ignited engine that incorporates cyclic variability through a quasi-dimensional combustion model. Our analyses are focused on the effects of the fuel-air equivalence ratio of the mixture simultaneously over the cycle-to-cycle fluctuations of heat release (QR and the performance outputs, such as the power (P and the efficiency (QR. We explore the fluctuant behavior for QR, P and n related to random variations of the basic physical parameters in an entrainment or eddy-burning combustion model. P and n show triangle shaped first return maps, while QR exhibits a structured map, especially at intermediated fuel-air ratios. Structure disappears to a considerable extent in the case of heat release and close-to-stoichiometry fuel-air ratios. By analyzing the fractal dimension to explore the presence of correlations at different scales, we find that whereas QR displays short-range correlations for intermediate values of the fuel ratio, both P and n are characterized by a single scaling exponent, denoting irregular fluctuations. A novel noisy loop-shaped P vs. n plot for a large number of engine cycles is obtained. This plot, which evidences different levels of irreversibilities as the fuel ratio changes, becomes the observed loop P vs. n curve when fluctuations are disregarded, and thus, only the mean values for efficiency and power are considered.

  12. PUCA pump and IABP comparison: analysis of hemodynamic and energetic effects using a digital computer model of the circulation.

    Science.gov (United States)

    Fresiello, Libera; Gu, Y John; Ferrari, Gianfranco; Di Molfetta, Arianna; Rakhorst, Gerhard

    2011-05-01

    The pulsatile catheter pump (PUCA pump) is a left ventricular assist device that provides additional flow to the left ventricle. It is usually run in order to ensure a counterpulsation effect, as in the case of the intra-aortic balloon pump (IABP). Because of this similarity, a comparison between the PUCA pump and the IABP was conducted from both the hemodynamic and energetic points of view. Numerical models of the two devices were created and connected to the CARDIOSIM cardiovascular simulator. The PUCA and IABP models were then verified using in vivo experimental data and literature data, respectively. Numerical experiments were conducted for different values of left ventricular end systolic elastance (Els) and systemic arterial compliance (Csa). The energetic comparison was conducted taking into account the diastolic pressure time index and the endocardial viability ratio. Hemodynamic results expressed as cardiac output (CO) and mean coronary blood flow (CBF) show that both the IABP and the PUCA pump efficacy decrease with higher values of Els and Csa. The IABP especially shows higher sensitivity to these parameters, to the extent that in some cases CO actually drops and CBF does not increase. On the other hand, for lower values of Csa, IABP performance improves so much that the PUCA pump flow needs to be increased in order to ensure a hemodynamic effect comparable to that of the IABP. Energetic results show a trend similar to the hemodynamic ones. The study will be continued by investigating other energetic variables and the autonomic response of the cardiovascular system.

  13. Steady Nuclear Combustion in Rockets

    Science.gov (United States)

    Saenger, E.

    1957-01-01

    The astrophysical theory of stationary nuclear reactions in stars is applied to the conditions that would be met in the practical engineering cases that would differ from the former, particularly with respect to the much lower combustion pressures, dimensions of the reacting volume, and burnup times. This application yields maximum rates of hear production per unit volume of reacting gas occurring at about 10(exp 8) K in the cases of reactions between the hydrogen isotopes, but yields higher rates for heavier atoms. For the former, with chamber pressures of the order of 100 atmospheres, the energy production for nuclear combustion reaches values of about 10(exp 4) kilocalories per cubic meter per second, which approaches the magnitude for the familiar chemical fuels. The values are substantially lower for heavier atoms, and increase with the square of the combustion pressure. The half-life of the burnup in the fastest reactions may drop to values as low as those for chemical fuels so that, despite the high temperature, the radiated energy can remain smaller than the energy produced, particularly if an inefficiently radiating (i.e., easily completely ionized reacting material like hydrogen), is used. On the other hand, the fraction of completely ionized particles in the gases undergoing nuclear combustion must not exceed a certain upper limit because the densities (approximately 10(exp -10) grams per cubic centimeter)) lie in the range of high vacua and only for the previously mentioned fraction of nonionized particles can mean free paths be retained small enough so that the chamber diameters of several dozen meters will suffice. Under these conditions it appears that continuously maintained stable nuclear reactions at practical pressures and dimensions are fundamentally possible and their application can be visualized as energy sources for power plants and propulsion units.

  14. Coal combustion by wet oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

    1980-11-15

    The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

  15. Status of Boron Combustion Research

    Science.gov (United States)

    1984-10-01

    Chemical M. K. King, ARC L. Cook, NBS C. E. Kolb, Aerodyne *T. Curran, AFWAL/PO C. K. Law, U. Cal.-Davi3 P. Davidovits , Boston College *C. R. Martel...Homogeneous Combustion Kinetics of Boron Compounds. A. Fontijn, RPI. 1030 Simple Boron Atom Reactions. P. Davidovits , Boston College. 1050 Ultra-Fast Energy... DAVIDOVITS . J. Chem. Phys. 74, 3287 (1981). DED - T. G. DIGIUSEPPI. Rt. ESTES, and P. DAVIDOVITS . J. Phys. Chem.. 6, 260 (1982). ERF -A. J. ENGLISH

  16. Preliminary Hazard Analysis of Supercritical Fluid Separation of Energetic Materials

    National Research Council Canada - National Science Library

    1997-01-01

    .... Army Research Laboratory (ARL) and elsewhere, particularly at the Phasex Corporation, Lawrence, MA, has demonstrated the feasibility of separating the energetic moieties by use of supercritical CO2...

  17. Perspective -- Aerodynamic control of combustion

    Energy Technology Data Exchange (ETDEWEB)

    Oppenheim, A.K. [Univ. of California, Berkeley, CA (United States). Mechanical Engineering

    1993-12-01

    To do useful work, the exothermic process of combustion should be carried out in an enclosure, as is typically the case with i.c. engines -- the subject of this paper`s particular concern. To meet the requirements of high efficiency and low pollutant production, this process should be executed at a relatively low temperature -- a condition attainable by the use of lean air-fuel mixtures. For this purpose it has to be distributed in space upon multipoint initiation and kept away from the walls to minimize their detrimental effects. In principle, all this can be accomplished by a system referred to as fireball combustion that takes advantage of entrainment and spiral mixing associated with large scale vortex structures of jet plumes. As demonstrated in this paper, the success in such an endeavor depends crucially upon the utilization of the essential elements of classical aerodynamics: the properly distributed sources, expressed in terms of velocity divergences prescribed by the thermodynamic process of combustion and of the vorticity field generated by shear between the jets and the fluid into which they are injected.

  18. Combustion instability modeling and analysis

    Energy Technology Data Exchange (ETDEWEB)

    Santoro, R.J.; Yang, V.; Santavicca, D.A. [Pennsylvania State Univ., University Park, PA (United States)] [and others

    1995-10-01

    It is well known that the two key elements for achieving low emissions and high performance in a gas turbine combustor are to simultaneously establish (1) a lean combustion zone for maintaining low NO{sub x} emissions and (2) rapid mixing for good ignition and flame stability. However, these requirements, when coupled with the short combustor lengths used to limit the residence time for NO formation typical of advanced gas turbine combustors, can lead to problems regarding unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions, as well as the occurrence of combustion instabilities. Clearly, the key to successful gas turbine development is based on understanding the effects of geometry and operating conditions on combustion instability, emissions (including UHC, CO and NO{sub x}) and performance. The concurrent development of suitable analytical and numerical models that are validated with experimental studies is important for achieving this objective. A major benefit of the present research will be to provide for the first time an experimentally verified model of emissions and performance of gas turbine combustors.

  19. Demonstration of Active Combustion Control

    Science.gov (United States)

    Lovett, Jeffrey A.; Teerlinck, Karen A.; Cohen, Jeffrey M.

    2008-01-01

    The primary objective of this effort was to demonstrate active control of combustion instabilities in a direct-injection gas turbine combustor that accurately simulates engine operating conditions and reproduces an engine-type instability. This report documents the second phase of a two-phase effort. The first phase involved the analysis of an instability observed in a developmental aeroengine and the design of a single-nozzle test rig to replicate that phenomenon. This was successfully completed in 2001 and is documented in the Phase I report. This second phase was directed toward demonstration of active control strategies to mitigate this instability and thereby demonstrate the viability of active control for aircraft engine combustors. This involved development of high-speed actuator technology, testing and analysis of how the actuation system was integrated with the combustion system, control algorithm development, and demonstration testing in the single-nozzle test rig. A 30 percent reduction in the amplitude of the high-frequency (570 Hz) instability was achieved using actuation systems and control algorithms developed within this effort. Even larger reductions were shown with a low-frequency (270 Hz) instability. This represents a unique achievement in the development and practical demonstration of active combustion control systems for gas turbine applications.

  20. Modeling the internal combustion engine

    Science.gov (United States)

    Zeleznik, F. J.; Mcbride, B. J.

    1985-01-01

    A flexible and computationally economical model of the internal combustion engine was developed for use on large digital computer systems. It is based on a system of ordinary differential equations for cylinder-averaged properties. The computer program is capable of multicycle calculations, with some parameters varying from cycle to cycle, and has restart capabilities. It can accommodate a broad spectrum of reactants, permits changes in physical properties, and offers a wide selection of alternative modeling functions without any reprogramming. It readily adapts to the amount of information available in a particular case because the model is in fact a hierarchy of five models. The models range from a simple model requiring only thermodynamic properties to a complex model demanding full combustion kinetics, transport properties, and poppet valve flow characteristics. Among its many features the model includes heat transfer, valve timing, supercharging, motoring, finite burning rates, cycle-to-cycle variations in air-fuel ratio, humid air, residual and recirculated exhaust gas, and full combustion kinetics.

  1. Energetics of the terrestrial bow shock

    Science.gov (United States)

    Hamrin, Maria; Gunell, Herbert; Norqvist, Patrik

    2017-04-01

    The solar wind is the primary energy source for the magnetospheric energy budget. Energy can enter through the magnetopause both as kinetic energy (plasma entering via e.g. magnetic reconnection and impulsive penetration) and as electromagnetic energy (e.g. by the conversion of solar wind kinetic energy into electromagnetic energy in magnetopause generators). However, energy is extracted from the solar wind already at the bow shock, before it encounters the terrestrial magnetopause. At the bow shock the supersonic solar wind is slowed down and heated, and the region near the bow shock is known to host many complex processes, including the accelerating of particles and the generation of waves. The processes at and near the bow shock can be discussed in terms of energetics: In a generator (load) process kinetic energy is converted to (from) electromagnetic energy. Bow shock regions where the solar wind is decelerated correspond to generators, while regions where particles are energized (accelerated and heated) correspond to loads. Recently, it has been suggested that currents from the bow shock generator should flow across the magnetosheath and connect to the magnetospause current systems [Siebert and Siscoe, 2002; Lopez et al., 2011]. In this study we use data from the Magnetospheric MultiScale (MMS) mission to investigate the energetics of the bow shock and the current closure, and we compare with the MHD simulations of Lopez et al., 2011.

  2. Bucket transport of energetic ions in tokamaks

    Energy Technology Data Exchange (ETDEWEB)

    Yakovenko, Yu.V., E-mail: yakovenko@kinr.kiev.ua [Institute for Nuclear Research, Prospekt Nauky 47, Kyiv 03680 (Ukraine); National University of Kyiv Mohyla Academy, Vul. Skovorody 2, Kyiv 04070 (Ukraine); Burdo, O.S.; Kolesnichenko, Ya.I.; Tyshchenko, M.H. [Institute for Nuclear Research, Prospekt Nauky 47, Kyiv 03680 (Ukraine)

    2015-09-25

    The so-called “bucket transport” of energetic ions — the spatial mixing of these ions due to spatial displacement of resonances — is studied with special attention to quasi-steady-state magnetic perturbations. A Hamiltonian formalism suitable to the case when the resonance displacement results from the collisional slowing down of the particles and the temporal evolution of the safety factor profile is suggested. The energy flux produced due to the bucket transport is shown to be considerable in configurations with low shear. It is shown that the bucket transport flux associated with magnetic islands tends to be localized at some distance from the islands. The bucket transport caused by perturbations with non-zero frequencies is also discussed. - Highlights: • The bucket transport of energetic ions is the spatial mixing due to spatial displacements of resonances. • The bucket transport may be of importance when the magnetic shear is small. • The particle and energy fluxes are located apart from the magnetic islands causing the transport. • The transport due to non-zero-frequency perturbations is less sensitive to the shear and may contribute to ash removal.

  3. Method and apparatus for active control of combustion rate through modulation of heat transfer from the combustion chamber wall

    Science.gov (United States)

    Roberts, Jr., Charles E.; Chadwell, Christopher J.

    2004-09-21

    The flame propagation rate resulting from a combustion event in the combustion chamber of an internal combustion engine is controlled by modulation of the heat transfer from the combustion flame to the combustion chamber walls. In one embodiment, heat transfer from the combustion flame to the combustion chamber walls is mechanically modulated by a movable member that is inserted into, or withdrawn from, the combustion chamber thereby changing the shape of the combustion chamber and the combustion chamber wall surface area. In another embodiment, heat transfer from the combustion flame to the combustion chamber walls is modulated by cooling the surface of a portion of the combustion chamber wall that is in close proximity to the area of the combustion chamber where flame speed control is desired.

  4. energetic performance analysis of drying agricultural products

    African Journals Online (AJOL)

    user

    The temperatures of tracking and fixed collectors and open air drying were used to estimate the temperature of emitting surface. 3. MATERIALS AND METHOD. 3.1 Equipments and Apparatus. 3.1.1 Solar Tracking Device. This is a device which helps to orientate a solar photovoltaic panel or concentrating solar reflector or.

  5. COMBUSTION SIMULATION IN A SPARK IGNITION ENGINE CYLINDER: EFFECTS OF AIR-FUEL RATIO ON THE COMBUSTION DURATION

    OpenAIRE

    Nureddin Dinler; Nuri Yucel

    2010-01-01

    Combustion is an important subject of internal combustion engine studies. To reduce the air pollution from internal combustion engines and to increase the engine performance, it is required to increase combustion efficiency. In this study, effects of air/fuel ratio were investigated numerically. An axisymmetrical internal combustion engine was modeled in order to simulate in-cylinder engine flow and combustion. Two dimensional transient continuity, momentum, turbulence, energy, and combustion...

  6. TOXIC SUBSTANCES FROM COAL COMBUSTION

    Energy Technology Data Exchange (ETDEWEB)

    A KOLKER; AF SAROFIM; CL SENIOR; FE HUGGINS; GP HUFFMAN; I OLMEZ; J LIGHTY; JOL WENDT; JOSEPH J HELBLE; MR AMES; N YAP; R FINKELMAN; T PANAGIOTOU; W SEAMES

    1998-12-08

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the Federal Energy Technology Center (FETC), the Electric Power Research Institute, the Lignite Research Council, and VTT (Finland), Physical Sciences Inc. (PSI) has teamed with researchers from USGS, MIT, the University of Arizona (UA), the University of Kentucky (UK), the University of Connecticut (UC), the University of Utah (UU) and the University of North Dakota Energy and Environmental Research Center (EERC) to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NO combustion systems, and new power generation x plants. Development of ToPEM will be based on PSI's existing Engineering Model for Ash Formation (EMAF). This report covers the reporting period from 1 July 1998 through 30 September 1998. During this period distribution of all three Phase II coals was completed. Standard analyses for the whole coal samples were also completed. Mössbauer analysis of all project coals and fractions received to date has been completed in order to obtain details of the iron mineralogy. The analyses of arsenic XAFS data for two of the project coals and for some high arsenic coals have been completed. Duplicate splits of the Ohio 5,6,7 and North Dakota lignite samples were taken through all four steps of the selective leaching procedure. Leaching analysis of the Wyodak coal has recently commenced. Preparation of polished coal/epoxy pellets for probe/SEM studies is underway. Some exploratory mercury LIII XAFS work was

  7. Transformations of inorganic coal constituents in combustion systems

    Energy Technology Data Exchange (ETDEWEB)

    Helble, J.J. (ed.); Srinivasachar, S.; Wilemski, G.; Boni, A.A. (PSI Technology Co., Andover, MA (United States)); Kang, Shin-Gyoo; Sarofim, A.F.; Graham, K.A.; Beer, J.M. (Massachusetts Inst. of Tech., Cambridge, MA (United States)); Peterson, T.W.; Wendt, J.O.L.; Gallagher, N.B.; Bool, L. (Arizona Univ., Tucson, AZ (United States)); Huggins, F.E.; Huffman, G.P.; Shah, N.; Shah, A. (Kentucky Univ., Lexingt

    1992-11-01

    The inorganic constituents or ash contained in pulverized coal significantly increase the environmental and economic costs of coal utilization. For example, ash particles produced during combustion may deposit on heat transfer surfaces, decreasing heat transfer rates and increasing maintenance costs. The minimization of particulate emissions often requires the installation of cleanup devices such as electrostatic precipitators, also adding to the expense of coal utilization. Despite these costly problems, a comprehensive assessment of the ash formation and had never been attempted. At the start of this program, it was hypothesized that ash deposition and ash particle emissions both depended upon the size and chemical composition of individual ash particles. Questions such as: What determines the size of individual ash particles What determines their composition Whether or not particles deposit How combustion conditions, including reactor size, affect these processes remained to be answered. In this 6-year multidisciplinary study, these issues were addressed in detail. The ambitious overall goal was the development of a comprehensive model to predict the size and chemical composition distributions of ash produced during pulverized coal combustion. Results are described.

  8. Ferroelectric devices

    CERN Document Server

    Uchino, Kenji

    2009-01-01

    Updating its bestselling predecessor, Ferroelectric Devices, Second Edition assesses the last decade of developments-and setbacks-in the commercialization of ferroelectricity. Field pioneer and esteemed author Uchino provides insight into why this relatively nascent and interdisciplinary process has failed so far without a systematic accumulation of fundamental knowledge regarding materials and device development.Filling the informational void, this collection of information reviews state-of-the-art research and development trends reflecting nano and optical technologies, environmental regulat

  9. Catalytic devices

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Ming; Zhang, Xiang

    2018-01-23

    This disclosure provides systems, methods, and apparatus related to catalytic devices. In one aspect, a device includes a substrate, an electrically insulating layer disposed on the substrate, a layer of material disposed on the electrically insulating layer, and a catalyst disposed on the layer of material. The substrate comprises an electrically conductive material. The substrate and the layer of material are electrically coupled to one another and configured to have a voltage applied across them.

  10. Effects of Large Energetic Vortices on Axial-Flow Hydrokinetic Turbines

    Energy Technology Data Exchange (ETDEWEB)

    Gunawan, Budi [ORNL; Neary, Vincent S [ORNL; Hill, Craig [St. Anthony Falls Laboratory, 2 Third Avenue SE, Minneapolis, MN 55414; Chamorro, Leonardo [St. Anthony Falls Laboratory, 2 Third Avenue SE, Minneapolis, MN 55414

    2012-01-01

    Large scale coherent motions around marine and hydrokinetic (MHK) machines can significantly increase the structural loading and affect the overall performance of the machines. Characterization of the approach turbulence and their impact on the instantaneous response of MHK devices is essential for improving their design and performance. This preliminary study investigates the effect of turbulence and dominant energetic coherent structures induced by a vertical cylinder on the structural load and energy production in a model MHK turbine. Results show that the power generated by the turbine is significantly reduced by the presence of the cylinder. This reduction depends on the distance from the cylinder and the level of turbulence around the rotor area.

  11. Oxy-fuel combustion of solid fuels

    DEFF Research Database (Denmark)

    Toftegaard, Maja Bøg; Brix, Jacob; Jensen, Peter Arendt

    2010-01-01

    Oxy-fuel combustion is suggested as one of the possible, promising technologies for capturing CO2 from power plants. The concept of oxy-fuel combustion is removal of nitrogen from the oxidizer to carry out the combustion process in oxygen and, in most concepts, recycled flue gas to lower the flame...... provide additional options for improvement of process economics are however likewise investigated. Of particular interest is the change of the combustion process induced by the exchange of carbon dioxide and water vapor for nitrogen as diluent. This paper reviews the published knowledge on the oxy......-fuel process and focuses particularly on the combustion fundamentals, i.e. flame temperatures and heat transfer, ignition and burnout, emissions, and fly ash characteristics. Knowledge is currently available regarding both an entire oxy-fuel power plant and the combustion fundamentals. However, several...

  12. Pollutant Formation in Monodisperse Fuel Spray Combustion

    Science.gov (United States)

    Cernansky, N. P.; Sarv, H.

    1983-01-01

    The combustion of liquid sprays represents an extremely important class of combustion processes. In the transition region, encompassing droplet sizes in the range of 25-80 micron diameter, the mixing and evaporation processes are both incomplete at the flame front and burning occurs in a combined diffusive and premixed fashion. Under these conditions, the relative importance of heterogeneous and homogeneous effects in dominating the combustion process is switched and gives rise to a number of interesting phenomena. NO (sub x) formation in monodisperse spray combustion was investigated with the following specific objectives: (1) to quantitatively determine the effect of droplet size, number density, etc. on NO sub x formation in monodisperse fuel spray combustion; and (2) to isolate the important physical and chemical phenomena in NO sub x formation in these combustion systems.

  13. Sandia Combustion Research Program: Annual report, 1986

    Energy Technology Data Exchange (ETDEWEB)

    1986-01-01

    This report presents research results of the past year, divided thematically into some ten categories. Publications and presentations arising from this work are included in the appendix. Our highlighted accomplishment of the year is the announcement of the discovery and demonstration of the RAPRENOx process. This new mechanism for the elimination of nitrogen oxides from essentially all kinds of combustion exhausts shows promise for commercialization, and may eventually make a significant contribution to our nation's ability to control smog and acid rain. The sections of this volume describe the facility's laser and computer system, laser diagnostics of flames, combustion chemistry, reacting flows, liquid and solid propellant combustion, mathematical models of combustion, high-temperature material interfaces, studies of engine/furnace combustion, coal combustion, and the means of encouraging technology transfer. 182 refs., 170 figs., 12 tabs.

  14. Experimental and numerical study of the active control of jets inside combustion chambers; Etude experimentale et numerique du controle actif de jets dans des chambres de combustion

    Energy Technology Data Exchange (ETDEWEB)

    Faivre, V.

    2003-12-15

    Combustion instabilities occur when the flame heat release couples with the acoustic waves propagating in the combustion chamber. This phenomenon can lead to strong vibrations and noise but also, sometimes, to the complete combustion device failure. That is the reason why so many studies focus on the control of those instabilities. The method chosen in this study consists in an active control device (or set of actuators) having a strong effect on the mixing of the burner exhaust flow with the ambient fluid. The model configuration studied consists in a non reactive jet of air controlled by four small tangential secondary jets. Experiments have been carried out to optimize the control device geometry. The configuration identified as the most efficient, in terms of mixing enhancement, has been simulated through Large Eddy Simulations (LES). The objective of the numerical part of the present work is double. First, the numerical simulations provide a better understanding of the phenomena occurring when the control is on. Then, it is shown that LES can be considered as a tool to predict the effects of a control device on a flow. (author)

  15. Multicriteria analysis to evaluate the energetic reuse of riparian vegetation

    Energy Technology Data Exchange (ETDEWEB)

    Recchia, Lucia; Cini, Enrico [Dipartimento di Ingegneria Agraria e Forestale, Universita di Firenze, Piazzale delle Cascine 15, 50144 Firenze (Italy); Corsi, Stefano [Consorzio di Bonifica per la difesa del suolo e la tutela dell' ambiente della Toscana Centrale, via Verdi 16, 50122 Firenze (Italy)

    2010-01-15

    community. In conclusion, the most interesting bio-energy chains, based on technology of direct combustion, are those that require a limited forestry mechanisation, the short transport distances and the medium sized plants. The LCA applied to these most suitable chains has also shown significant environmental benefits to promote the energetic use of riparian biomass instead of fossil fuels. (author)

  16. Combustion and Heat Transfer Studies Utilizing Advanced Diagnostics: Combustion Studies

    Science.gov (United States)

    1992-11-01

    Also, m ass conservation balance in the plane of th 1.0 . ./Id -005 0- bluff body base provided an additional cross-check against (W/Uei U/a...jet than asa thick jet spreading into adump combustor. Ass a . NAlI 2’A.. , 2.0 L K consequence, in Fig. 5b. streamlines around die recirculatiofi zone...Combustio of 23. Rawe., It, and Kremer, H.: EWmtwa Spwsposm IfWhucabon Fucks wih Air NACA Rept. 1300,29M. (nternational) on Combustion, p.667, The

  17. Energetics of lithium ion battery failure

    Energy Technology Data Exchange (ETDEWEB)

    Lyon, Richard E., E-mail: richard.e.lyon@faa.gov; Walters, Richard N.

    2016-11-15

    Highlights: • First measure of anaerobic failure energy of lithium ion batteries. • Novel and simple bomb calorimeter method developed and demonstrated. • Four different cathode chemistries examined. • Full range of charged capacity used as independent variable. • Failure energy identified as primary safety hazard. - Abstract: The energy released by failure of rechargeable 18-mm diameter by 65-mm long cylindrical (18650) lithium ion cells/batteries was measured in a bomb calorimeter for 4 different commercial cathode chemistries over the full range of charge using a method developed for this purpose. Thermal runaway was induced by electrical resistance (Joule) heating of the cell in the nitrogen-filled pressure vessel (bomb) to preclude combustion. The total energy released by cell failure, ΔH{sub f}, was assumed to be comprised of the stored electrical energy E (cell potential × charge) and the chemical energy of mixing, reaction and thermal decomposition of the cell components, ΔU{sub rxn}. The contribution of E and ΔU{sub rxn} to ΔH{sub f} was determined and the mass of volatile, combustible thermal decomposition products was measured in an effort to characterize the fire safety hazard of rechargeable lithium ion cells.

  18. Experimental research on combustion fluorine retention using calcium-based sorbets during coal combustion (I)

    Energy Technology Data Exchange (ETDEWEB)

    Qi, Qing-jie; Lin, Zhi-yan; Liu, Jian-zhong; Wu, Xian; Zhou, Jun-hu; Cen, Ke-fa [Liaoning Technical University, Fuxin (China). College of Resource and Environment Engineering

    2008-06-15

    In order to provide experimental guide to commercial use of fluorine pollution control during coal combustion, with fluorine pollution control during coal combustion in mind, this paper proposed the theory of combustion fluorine retention technology. Feasibility of fluorine retention reaction with calcium-based fluorine retention agent was analyzed through thermodynamic calculation during coal combustion. By simulating the restraining and retention effects and influential factors of calcium-based sorbets on vaporized fluoride during experimental combustion using fixed bed tube furnace, the paper systematically explored the influential law of such factors as combustion temperature, retention time, and added quantities of calcium-based sorbets on effects of fluorine retention. The research result shows that adding calcium-based fluorine retention agent in coal combustion has double effects of fluorine retention and sulfur retention, it lays an experimental foundation for commercial test of combustion fluorine retention. 7 refs., 2 figs., 4 tabs.

  19. ENVIRONMENTAL TECHNOLOGY VERIFICATION REPORT, NOX CONTROL TECHNOLOGIES, CATALYTICA COMBUSTION SYSTEMS, INC., XONON FLAMELESS COMBUSTION SYSTEM

    Science.gov (United States)

    The Environmental Technology Verification report discusses the technology and performance of the Xonon Cool Combustion System manufactured by Catalytica Energy Systems, Inc., formerly Catalytica Combustion Systems, Inc., to control NOx emissions from gas turbines that operate wit...

  20. Energetic efficiency of mass transfer accompanied by chemical reactions in liquid-liquid systems

    Directory of Open Access Journals (Sweden)

    Jasińska Magdalena

    2017-09-01

    Full Text Available Energetic efficiency depicting the fraction of energy dissipation rate used to perform processes of drop breakup and mass transfer in two-phase, liquid-liquid systems is considered. Results of experiments carried out earlier in two types of high-shear mixers: an in-line rotor-stator mixer and a batch rotor-stator mixer, have been applied to identify and compare the efficiency of drop breakage and mass transfer in both types of mixers. The applied method is based on experimental determination of both: the product distribution of chemical test reactions and the drop size distributions. Experimental data are interpreted using a multifractal model of turbulence for drop breakage and the model by Favelukis and Lavrenteva for mass transfer. Results show that the energetic efficiency of the in-line mixer is higher than that of the batch mixer; two stator geometries were considered in the case of the batch mixer and the energetic efficiency of the device equipped with a standard emulsor screen (SES was higher than the efficiency of the mixer equipped with a general purpose disintegrating head (GPDH for drop breakup but smaller for mass transfer.

  1. Study of energetic particle physics with advanced ECEI system on the HL-2A tokamak

    Directory of Open Access Journals (Sweden)

    Shi Zhongbing

    2017-01-01

    Full Text Available Understanding the physics of energetic particles (EP is crucial for the burning plasmas in next generation fusion devices such as ITER. In this work, three types of internal kink modes (a saturated internal kink mode (SK, a resonant internal kink mode (RK, and a double e-fishbone excited by energetic particles in the low density discharges during ECRH/ECCD heating have been studied by the newly developed 24(poloidal × 16(radial = 384 channel ECEI system on the HL-2A tokamak. The SK and RK rotate in the electron diamagnetic direction poloidally and are destabilized by the energetic trapped electrons. The SK is destabilized in the case of qmin > 1, while the RK is destabilized in the case of qmin < 1. The double e-fishbone, which has two m/n = 1/1 modes propagating in the opposite directions poloidally, has been observed during plasma current ramp-up with counter-ECCD. Strong thermal transfer and mode coupling between the two m/n = 1/1 modes have been studied.

  2. Nano-Bio Quantum Technology for Device-Specific Materials

    Science.gov (United States)

    Choi, Sang H.

    2009-01-01

    The areas discussed are still under development: I. Nano structured materials for TE applications a) SiGe and Be.Te; b) Nano particles and nanoshells. II. Quantum technology for optical devices: a) Quantum apertures; b) Smart optical materials; c) Micro spectrometer. III. Bio-template oriented materials: a) Bionanobattery; b) Bio-fuel cells; c) Energetic materials.

  3. The combustion of solid fuels and wastes

    CERN Document Server

    Tillman, David

    1991-01-01

    Careful organization and empirical correlations help clarify the prodigious technical information presented in this useful reference.Key Features* Written for practicing engineers, this comprehensive book supplies an overall framework of the combustion process; It connects information on specific reactions and reaction sequences with current applications and hardware; Each major group of combustion solids is evaluated; Among the many topics covered are:* Various biomass forms* The coalification process* Grate, kiln, and suspension firing* Fluidized bed combustion

  4. Materials for High-Temperature Catalytic Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Ersson, Anders

    2003-04-01

    Catalytic combustion is an environmentally friendly technique to combust fuels in e.g. gas turbines. Introducing a catalyst into the combustion chamber of a gas turbine allows combustion outside the normal flammability limits. Hence, the adiabatic flame temperature may be lowered below the threshold temperature for thermal NO{sub X} formation while maintaining a stable combustion. However, several challenges are connected to the application of catalytic combustion in gas turbines. The first part of this thesis reviews the use of catalytic combustion in gas turbines. The influence of the fuel has been studied and compared over different catalyst materials. The material section is divided into two parts. The first concerns bimetallic palladium catalysts. These catalysts showed a more stable activity compared to their pure palladium counterparts for methane combustion. This was verified both by using an annular reactor at ambient pressure and a pilot-scale reactor at elevated pressures and flows closely resembling the ones found in a gas turbine combustor. The second part concerns high-temperature materials, which may be used either as active or washcoat materials. A novel group of materials for catalysis, i.e. garnets, has been synthesised and tested in combustion of methane, a low-heating value gas and diesel fuel. The garnets showed some interesting abilities especially for combustion of low-heating value, LHV, gas. Two other materials were also studied, i.e. spinels and hexa aluminates, both showed very promising thermal stability and the substituted hexa aluminates also showed a good catalytic activity. Finally, deactivation of the catalyst materials was studied. In this part the sulphur poisoning of palladium, platinum and the above-mentioned complex metal oxides has been studied for combustion of a LHV gas. Platinum and surprisingly the garnet were least deactivated. Palladium was severely affected for methane combustion while the other washcoat materials were

  5. Strategy for intelligent internal combustion engine with homogenous combustion in cylinder

    OpenAIRE

    Weclas, Miroslaw

    2009-01-01

    In this report the author proposes strategy for development of intelligent combustion systems with a goal to approach a near-zero emission internal combustion engine operating in a wide range of speeds and loads. Main requirement for future I.C. engine is to develop a system permitting homogeneous combustion process (minimum of engine emissions) under all operational conditions. The author suggests, that none existing individual combustion system may satisfy these conditions. However, combina...

  6. Selection of technology for the low calorific synthetic gas combustion in the gas turbine combustion chamber

    Science.gov (United States)

    Filippov, Prokopy; Levin, Evgeny; Ryzhkov, Alexander

    2017-10-01

    The leading gas turbines manufacturers are developing the technologies of the environmental friendly combustion of industrial and synthetic gases of low calorific values. In this case they are faced with critical problems concerning combustion stability assurance and the necessity of the gas turbines significant modernization due to the differences between the low calorific and natural gases. The numerical simulation results of the low calorific value synthetic gas combustion in the combustion chamber by means of different technologies are considered in the paper.

  7. Supercritical Combustion of Liquid Oxygen and Hydrocarbon for Staged-Combustion Cycle Engine Technology Development

    Science.gov (United States)

    2009-06-30

    Mixtures," by G. Ribert, N. Zong, V. Yang, L. Pons , N. Darabiha, and S. Candel, Combustion and Flame, Vol. 154, 2008, pp. 319-330. 3. "Mass Transfer...and Combustion in Transcritical Non-Premixed Counterflows," by L. Pons , N. Darabiha, S. Candel, G. Ribert, and V. Yang, Combustion Theory and...supercritical environment," Combust. Sci. Tech. 178, 193 (2006). T. Poinsot and S. Lele , "Boundary conditions for direct simulation of compressible viscous

  8. Pyrolysis reactor and fluidized bed combustion chamber

    Science.gov (United States)

    Green, Norman W.

    1981-01-06

    A solid carbonaceous material is pyrolyzed in a descending flow pyrolysis reactor in the presence of a particulate source of heat to yield a particulate carbon containing solid residue. The particulate source of heat is obtained by educting with a gaseous source of oxygen the particulate carbon containing solid residue from a fluidized bed into a first combustion zone coupled to a second combustion zone. A source of oxygen is introduced into the second combustion zone to oxidize carbon monoxide formed in the first combustion zone to heat the solid residue to the temperature of the particulate source of heat.

  9. Fuel gas combustion research at METC

    Energy Technology Data Exchange (ETDEWEB)

    Norton, T.S.

    1995-06-01

    The in-house combustion research program at METC is an integral part of many METC activities, providing support to METC product teams, project managers, and external industrial and university partners. While the majority of in-house combustion research in recent years has been focussed on the lean premixed combustion of natural gas fuel for Advanced Turbine Systems (ATS) applications, increasing emphasis is being placed on issues of syngas combustion, as the time approaches when the ATS and coal-fired power systems programs will reach convergence. When the METC syngas generator is built in 1996, METC will have the unique combination of mid-scale pressurized experimental facilities, a continuous syngas supply with variable ammonia loading, and a team of people with expertise in low-emissions combustion, chemical kinetics, combustion modeling, combustion diagnostics, and the control of combustion instabilities. These will enable us to investigate such issues as the effects of pressure, temperature, and fuel gas composition on the rate of conversion of fuel nitrogen to NOx, and on combustion instabilities in a variety of combustor designs.

  10. Energetic assessment of soybean biodiesel obtainment in West ...

    African Journals Online (AJOL)

    SAM

    2014-07-16

    Jul 16, 2014 ... This work presents the result of a research that aimed to assess soybean-based biodiesel production in .... and; is the Energetic Efficiency. In order to extract soybean oil, the energetic consumption was measured for the milling of 1 kg of soybean grains. The production ..... Ethanol production using corn,.

  11. Particle coating – a novel trend in energetic materials engineering

    NARCIS (Netherlands)

    Abadjieva, E.; Heijden, A.E.D.M. van der; Creyghton, Y.L.M.

    2010-01-01

    The development of new energetic materials with enhanced blast properties requires better understanding of factors as particle type, size and particle/matrix distribution. The ability of growing a coating on particles opens new possibilities in energetic materials engineering. Functionalities as

  12. Benchtop Energetics: Research Progress, Concept Evaluation, and Apparatus Development

    Science.gov (United States)

    2012-01-31

    spin coater and drying oven. FY05 Objectives: In FY05 we will complete the assembly and testing of the permanent version of the main...Preparation ....................................................... 21 1. Spin Coating of Energetic Thin Films...will produce nanometric energetic film coatings on metal coated substrates via spin coating and spray coating methods. Teflon AF is an amorphous

  13. Energetic parameters in pregnant and lactating rat ( Lasiopodomys ...

    African Journals Online (AJOL)

    Energetic parameters in pregnant and lactating rat (Lasiopodomys brandtii) fed high- or low-fibre diets. OO Adewumi, XY Zhang, DH Wang. Abstract. The effect of diet quality (high-fibre (HF) or low-fibre (LF)) on energetic parameters in pregnant and lactating rats (Lasiopodomys brandtii) was examined. There was no ...

  14. Energetic adaptations persist after bariatric surgery in severely obese adolescents

    Science.gov (United States)

    Energetic adaptations induced by bariatric surgery have not been studied in adolescents or for extended periods postsurgery. Energetic, metabolic, and neuroendocrine responses to Roux-en-Y gastric bypass (RYGB) surgery were investigated in extremely obese adolescents. At baseline and at 1.5, 6, and...

  15. Acceleration and Propagation of Solar Energetic Particles

    Science.gov (United States)

    Klein, Karl-Ludwig; Dalla, Silvia

    2017-11-01

    Solar Energetic Particles (SEPs) are an important component of Space Weather, including radiation hazard to humans and electronic equipment, and the ionisation of the Earth's atmosphere. We review the key observations of SEPs, our current understanding of their acceleration and transport, and discuss how this knowledge is incorporated within Space Weather forecasting tools. Mechanisms for acceleration during solar flares and at shocks driven by Coronal Mass Ejections (CMEs) are discussed, as well as the timing relationships between signatures of solar eruptive events and the detection of SEPs in interplanetary space. Evidence on how the parameters of SEP events are related to those of the parent solar activity is reviewed and transport effects influencing SEP propagation to near-Earth locations are examined. Finally, the approaches to forecasting Space Weather SEP effects are discussed. We conclude that both flare and CME shock acceleration contribute to Space Weather relevant SEP populations and need to be considered within forecasting tools.

  16. Sodium Pentazolate: a Nitrogen Rich Energetic Material

    Science.gov (United States)

    Oleynik, Ivan; Steele, Brad

    Sodium pentazolates NaN5 and Na2N5, new energetic materials, are discovered using first principles crystal structure search for the compounds of varying amounts of elemental sodium and nitrogen. The pentazole anion (N5-s)i stabilized in the condensed phase by sodium Na+ cations at pressures exceeding 20 GPa, and becomes metastable upon release of pressure, i.e. at ambient conditions. The sodium azide (NaN3) precursor for the new compounds is predicted to undergo a chemical transformation above 50 GPa into sodium pentazolates NaN5 and Na2N5. The calculated Raman spectrum of NaN5 is in agreement with the experimental Raman spectrum of a previously unidentified substance appearing upon compression and heating of NaN3 precursor, thus confirming the appearance of the new compound.

  17. Liquid surface model for carbon nanotube energetics

    DEFF Research Database (Denmark)

    Solov'yov, Ilia; Mathew, Maneesh; Solov'yov, Andrey V.

    2008-01-01

    In the present paper we developed a model for calculating the energy of single-wall carbon nanotubes of arbitrary chirality. This model, which we call as the liquid surface model, predicts the energy of a nanotube with relative error less than 1% once its chirality and the total number of atoms...... an important insight in the energetics and stability of nanotubes of different chirality and might be important for the understanding of nanotube growth process. For the computations we use empirical Brenner and Tersoff potentials and discuss their applicability to the study of carbon nanotubes. From...... the calculated energies we determine the elastic properties of the single-wall carbon nanotubes (Young modulus, curvature constant) and perform a comparison with available experimental measurements and earlier theoretical predictions....

  18. Forces and energetics of intermittent swimming

    Science.gov (United States)

    Floryan, Daniel; Van Buren, Tyler; Smits, Alexander J.

    2017-08-01

    Experiments are reported on intermittent swimming motions. Water tunnel experiments on a nominally two-dimensional pitching foil show that the mean thrust and power scale linearly with the duty cycle, from a value of 0.2 all the way up to continuous motions, indicating that individual bursts of activity in intermittent motions are independent of each other. This conclusion is corroborated by particle image velocimetry (PIV) flow visualizations, which show that the main vortical structures in the wake do not change with duty cycle. The experimental data also demonstrate that intermittent motions are generally energetically advantageous over continuous motions. When metabolic energy losses are taken into account, this conclusion is maintained for metabolic power fractions less than 1.

  19. Nonlinear Electromagnetic Interactions in Energetic Materials

    CERN Document Server

    Wood, M A; Moore, D S

    2016-01-01

    We study the scattering of electromagnetic waves in anisotropic energetic materials. Nonlinear light-matter interactions in molecular crystals result in frequency-conversion and polarization changes. Applied electromagnetic fields of moderate intensity can induce these nonlinear effects without triggering chemical decomposition, offering a mechanism for non-ionizing identification of explosives. We use molecular dynamics simulations to compute such two-dimensional Raman spectra in the terahertz range for planar slabs made of PETN and ammonium nitrate. We discuss third-harmonic generation and polarization-conversion processes in such materials. These observed far-field spectral features of the reflected or transmitted light may serve as an alternative tool for stand-off explosive detection.

  20. Very energetic protons in Saturn's radiation belt

    Science.gov (United States)

    Fillius, W.; Mcilwain, C.

    1980-01-01

    Very energetic protons are trapped in the inner Saturnian radiation belt. The University of California at San Diego instrument on Pioneer 11 has definitely identified protons of energy greater than 80 MeV on channel M3 and has tentatively detected protons of energy greater than 600 MeV on channel C3. The spatial distribution of the protons is distinct from that of the trapped electrons, the main difference being that the protons are strongly absorbed by the innermost moons and that the electrons are not. The source strength for injecting protons by the decay of cosmic ray albedo neutrons generated in the rings of Saturn has been estimated. The required proton lifetime is approximately 20 years.

  1. Energetics of swimming of schooling fish

    DEFF Research Database (Denmark)

    Steffensen, John Fleng

    2012-01-01

    , i.e. nearest neighbour distance, water temperature, gill oxygen extraction, gill ventilation capacity, etc. Fish swimming in a school have been shown to have energetic advantages when trailing behind neighbours, resulting in up to 20% energy saving. The effect of this energy saving is that the fish......Soc for experimental Biol Annual Meeting - Salzburg 2012 John F. Steffensen (University of Copenhagen, Denmark) When a fish school swims through the water, every individual consumes a certain amount of oxygen, which means that less will be available for the trailing fish in the school. In 1967 Mc......Farland and Moss reported that the oxygen saturation decreased approximately 30% from the front to the rear of an approximately 150-m long school of mullets swimming in normoxic water. They also observed that the decline in oxygen saturation at the rear resulted in the school disintegrating into smaller separate...

  2. Effect of Sawtooth Oscillations on Energetic Ions

    Energy Technology Data Exchange (ETDEWEB)

    R.B. White; V.V. Lutsenko; Ya. I. Kolesnichenko; Yu. V. Yakovenko

    1999-12-10

    The work summarizes results of the authors' studies on the energetic ion transport induced by sawtooth oscillations in tokamaks. The main attention is paid to description of physical mechanisms responsible for the transport. In addition to overview, the work contains new material. The new results concern the resonant interaction of the particles and the electromagnetic field of the sawtooth crash. In particular, it is discovered that the dominant harmonic of the crash (m = n = 1) can lead to stochastic motion of particles having large orbit width (potatoes). Regular motion of potatoes and quasi-stagnation particles in the presence of an n = 1 mode is studied, and their characteristic displacements associated with quick switching on/off the mode are found.

  3. Towards coherent control of energetic material initiation

    Energy Technology Data Exchange (ETDEWEB)

    Greenfield, Margo T [Los Alamos National Laboratory; Mcgrane, Shawn D [Los Alamos National Laboratory; Scharff, R Jason [Los Alamos National Laboratory; Moore, David S [Los Alamos National Laboratory

    2009-01-01

    Direct optical initiation (DOI) of energetic materials using coherent control of localized energy deposition requires depositing energy into the material to produce a critical size hot spot, which allows propagation of the reaction and thereby initiation, The hot spot characteristics needed for growth to initiation can be studied using quantum controlled initiation (QCI). Achieving direct quantum controlled initiation (QCI) in condensed phase systems requires optimally shaped ultrafast laser pulses to coherently guide the energy flow along the desired paths. As a test of our quantum control capabilities we have successfully demonstrated our ability to control the reaction pathway of the chemical system stilbene. An acousto-optical modulator based pulse shaper was used at 266 nm, in a shaped pump/supercontinuum probe technique, to enhance and suppress th relative yields of the cis- to trans-stilbene isomerization. The quantum control techniques tested in the stilbene experiments are currently being used to investigate QCI of the explosive hexanitroazobenzene (HNAB).

  4. Energetic condensation growth of Nb thin films

    Directory of Open Access Journals (Sweden)

    M. Krishnan

    2012-03-01

    Full Text Available This paper describes energetic condensation growth of Nb films using a cathodic arc plasma, whose 60–120 eV ions penetrate a few monolayers into the substrate and enable sufficient surface mobility to ensure that the lowest energy state (crystalline structure with minimal defects is accessible to the film. Heteroepitaxial films of Nb were grown on a-plane sapphire and MgO crystals with good superconducting properties and crystal size (10  mm×20  mm limited only by substrate size. The substrates were heated to temperatures of up to 700°C and coated at 125°C, 300°C, 500°C, and 700°C. Film thickness was varied from ∼0.25  μm to >3  μm. Residual resistivity ratio (⟨RRR⟩ values (up to a record ⟨RRR⟩=587 on MgO and ⟨RRR⟩=328 on a-sapphire depend strongly on substrate annealing and deposition temperatures. X-ray diffraction spectra and pole figures reveal that RRR increases as the crystal structure of the Nb film becomes more ordered, consistent with fewer defects and, hence, longer electron mean-free path. A transition from Nb(110 to Nb(100 orientation on the MgO(100 lattice occurs at higher temperatures. This transition is discussed in light of substrate heating and energetic condensation physics. Electron backscattered diffraction and scanning electron microscope images complement the XRD data.

  5. Energetic dose: Beyond fire and flint?

    Science.gov (United States)

    Linder, G.; Rattner, B.; Cohen, J.

    2000-01-01

    Nutritional and bioenergetic interactions influence exposure to environmental chemicals and may affect the risk realized when wildlife are exposed in the field. Here, food-chain analysis focuses on prairie voles (Microtus ochrogaster) and the evaluation of chemical risks associated with paraquat following 10-d dietary exposures. Reproductive effects were measured in 60-d trials that followed exposures to paraquat-tainted feed: control (untainted feed); 21 mg paraquat/kg feed; 63 mg paraquat/kg feed; and feed-restricted control (untainted feed restricted to 60% baseline consumption). Reproductive success was evaluated in control and treated breeding pairs, and a preliminary bioenergetics analysis was completed in parallel to derive exposure dose. Although reproductive performance differed among groups, feed-restriction appeared to be the dominant treatment effect observed in these 10-d feeding exposure/limited reproductive trials. Exposure dose ranged from 3.70-3.76 to 9.41-11.51 mg parquat/kg BW/day at 21 and 63 mg paraquat/kg feed stock exposures, respectively. Energetic doses as ug paraquat/kcal yielded preliminary estimates of energetic costs associated with paraquat exposure, and were similar within treatments for both sexes, ranging from 4.2-5.5 and 13.1-15.0 ug paraquat/kcal for voles exposed to 21 mg/kg feed stock and 63 mg/kg feed stock, respectively. Given the increasing likelihood that environmental chemicals will be found in wildlife habitat at 'acceptable levels', the critical role that wildlife nutrition plays in evaluating ecological risks should be fully integrated into the assessment process. Tools applied to the analysis of risk must gain higher resolution than the relatively crude methods we currently bring to the process.

  6. Control of the Development of Swirling Airflow Dynamics and Its Impact on Biomass Combustion Characteristics

    Science.gov (United States)

    Barmina, I.; Valdmanis, R.; Zaķe, M.

    2017-06-01

    The development of the swirling flame flow field and gasification/ combustion dynamics at thermo-chemical conversion of biomass pellets has experimentally been studied using a pilot device, which combines a biomass gasifier and combustor by varying the inlet conditions of the fuel-air mixture into the combustor. Experimental modelling of the formation of the cold nonreacting swirling airflow field above the inlet nozzle of the combustor and the upstream flow formation below the inlet nozzle has been carried out to assess the influence of the inlet nozzle diameter, as well primary and secondary air supply rates on the upstream flow formation and air swirl intensity, which is highly responsible for the formation of fuel-air mixture entering the combustor and the development of combustion dynamics downstream of the combustor. The research results demonstrate that at equal primary axial and secondary swirling air supply into the device a decrease in the inlet nozzle diameter enhances the upstream air swirl formation by increasing swirl intensity below the inlet nozzle of the combustor. This leads to the enhanced mixing of the combustible volatiles with the air swirl below the inlet nozzle of the combustor providing a more complete combustion of volatiles and an increase in the heat output of the device.

  7. Combustion and Gasification Collection of Diesel Soot by Means of Microwave Heating

    Directory of Open Access Journals (Sweden)

    Xueshi YAO

    2014-06-01

    Full Text Available The experiment of integrated purification of diesel soot was made by means of microwave heating. The experiment includes combustion and gasification collection. The catalytic effect of ceramic carrier was used in the combustion process. In order to improve the purification efficiency of PM2.5 particles, the surfactants were used in gasification collection. The model of computer control was set up so that the purification course could be controlled. The experimental principle was analyzed. Experiment result indicated that the diesel soot purifying efficiency is more than 90 %. The purification efficiency can be improved further by the optimization design of experimental device.

  8. COAL’S ROLE IN THE WORLD ENERGETIC SYSTEM

    Directory of Open Access Journals (Sweden)

    Andrei ROTH

    2014-06-01

    Full Text Available The world energy needs are on the rise, and they come from developing economies, especially the emerging ones such as China or India with high demographic and economic growth rates. These countries future demand for energy will shape the world’s energetic system. They will require considerable quantities of energy to fuel their demanding economies. The last decade has shown that the world’s energetic needs are being reoriented from West to East. Coal represents an available, secure and competitive energetic resource which can help the growing need for energy. However it is not that flexible as gas or renewables and it has also a greater impact upon environment due to its greenhouse gas emissions in the context of climate change. For these reasons coal is being less used for the energetic needs of the developed economies. Will the current attributes of coal be sufficient to maintain coal’s place in the world energetic mix?

  9. Pulsed atmospheric fluidized bed combustion

    Energy Technology Data Exchange (ETDEWEB)

    1989-11-01

    In order to verify the technical feasibility of the MTCI Pulsed Atmospheric Fluidized Bed Combustor technology, a laboratory-scale system was designed, built and tested. Important aspects of the operational and performance parameters of the system were established experimentally. A considerable amount of the effort was invested in the initial task of constructing an AFBC that would represent a reasonable baseline against which the performance of the PAFBC could be compared. A summary comparison of the performance and emissions data from the MTCI 2 ft {times} 2 ft facility (AFBC and PAFBC modes) with those from conventional BFBC (taller freeboard and recycle operation) and circulating fluidized bed combustion (CFBC) units is given in Table ES-1. The comparison is for typical high-volatile bituminous coals and sorbents of average reactivity. The values indicated for BFBC and CFBC were based on published information. The AFBC unit that was designed to act as a baseline for the comparison was indeed representative of the larger units even at the smaller scale for which it was designed. The PAFBC mode exhibited superior performance in relation to the AFBC mode. The higher combustion efficiency translates into reduced coal consumption and lower system operating cost; the improvement in sulfur capture implies less sorbent requirement and waste generation and in turn lower operating cost; lower NO{sub x} and CO emissions mean ease of site permitting; and greater steam-generation rate translates into less heat exchange surface area and reduced capital cost. Also, the PAFBC performance generally surpasses those of conventional BFBC, is comparable to CFBC in combustion and NO{sub x} emissions, and is better than CFBC in sulfur capture and CO emissions even at the scaled-down size used for the experimental feasibility tests.

  10. DGMK conference 'Energetic utilisation and recycling of waste and biomass'. Authors' manuscripts; Beitraege zur DGMK-Fachbereichstagung 'Energetische und stoffliche Nutzung von Abfaellen und Biomassen'. Autorenmanuskripte

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    This conference of Deutsche Wissenschaftliche Gesellschaft fuer Erdoel, Erdgas und Kohle focused on energetic utilisation and recycling of waste materials and biomass, i.e. combustion, gasification and pyrolysis. Aspects of process control were gone into as well. [German] Die Fachbereichstagung der Deutschen Wissenschaftlichen Gesellschaft fuer Erdoel, Erdgas und Kohle beschaeftigte sich mit der energetischen und stofflichen Nutzung von Abfall und Biomasse. Verbrennung, Vergasung und Pyrolyse verschiedener Abfallstoffe sowie die Prozesssteuerung wurden eroertert.

  11. Theoretical studies of combustion dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Bowman, J.M. [Emory Univ., Atlanta, GA (United States)

    1993-12-01

    The basic objectives of this research program are to develop and apply theoretical techniques to fundamental dynamical processes of importance in gas-phase combustion. There are two major areas currently supported by this grant. One is reactive scattering of diatom-diatom systems, and the other is the dynamics of complex formation and decay based on L{sup 2} methods. In all of these studies, the authors focus on systems that are of interest experimentally, and for which potential energy surfaces based, at least in part, on ab initio calculations are available.

  12. Leaching from biomass combustion ash

    DEFF Research Database (Denmark)

    Maresca, Alberto; Astrup, Thomas Fruergaard

    2014-01-01

    The use of biomass combustion ashes for fertilizing and liming purposes has been widely addressed in scientific literature. Nevertheless, the content of potentially toxic compounds raises concerns for a possible contamination of the soil. During this study five ash samples generated at four...... in water. The content of the selected heavy metals (i.e. Cr, Ni, Pb and Cd) complied with the Danish Statutory Order on the use of bio-ash for agricultural purposes; however, critical releases of Cr were detected in the leachate extracts, especially in the fly ash. High alkaline pHs were measured in all...

  13. Transient combustion in hybrid rockets

    Science.gov (United States)

    Karabeyoglu, Mustafa Arif

    1998-09-01

    Hybrid rockets regained interest recently as an alternative chemical propulsion system due to their advantages over the solid and liquid systems that are currently in use. Development efforts on hybrids revealed two important problem areas: (1) low frequency instabilities and (2) slow transient response. Both of these are closely related to the transient behavior which is a poorly understood aspect of hybrid operation. This thesis is mainly involved with a theoretical study of transient combustion in hybrid rockets. We follow the methodology of identifying and modeling the subsystems of the motor such as the thermal lags in the solid, boundary layer combustion and chamber gasdynamics from a dynamic point of view. We begin with the thermal lag in the solid which yield the regression rate for any given wall heat flux variation. Interesting phenomena such as overshooting during throttling and the amplification and phase lead regions in the frequency domain are discovered. Later we develop a quasi-steady transient hybrid combustion model supported with time delays for the boundary layer processes. This is integrated with the thermal lag system to obtain the thermal combustion (TC) coupled response. The TC coupled system with positive delays generated low frequency instabilities. The scaling of the instabilities are in good agreement with actual motor test data. Finally, we formulate a gasdynamic model for the hybrid chamber which successfully resolves the filling/emptying and longitudinal acoustic behavior of the motor. The TC coupled system is later integrated to the gasdynamic model to obtain the overall response (TCG coupled system) of gaseous oxidizer motors with stiff feed systems. Low frequency instabilities were also encountered for the TCG coupled system. Apart from the transient investigations, the regression rate behavior of liquefying hybrid propellants such as solid cryogenic materials are also studied. The theory is based on the possibility of enhancement

  14. Buoyancy effects on smoldering combustion

    Science.gov (United States)

    Dosanjh, S.; Peterson, J.; Fernandez-Pello, A. C.; Pagni, P. J.

    1985-01-01

    The effect of buoyancy on the rate of spread of a concurrent smolder reaction through a porous combustible material is investigated theoretically and experimentally. In the experiments, buoyant forces are controlled by varying the density difference, and the smolder rate spread through porous alpha cellulose (0.83 void fraction) is measured as a function of the ambient air pressure. The smolder velocity is found to increase with the ambient pressure; extinction occurs when the buoyancy forces cannot overcome the drag forces, indicating that diffusion by itself cannot support the spread of a smolder reaction. Theoretical predictions are found to be in good qualitative agreement with the experimental results.

  15. COMBUSTION PROPERTIES OF EUCALYPTUS WOOD

    Directory of Open Access Journals (Sweden)

    Yalçın ÖRS

    1999-03-01

    Full Text Available In this study, the combustion properties of some impregnation materials (abiotic and biotic factors used for eucalyptus wood in interior or exterior environments were investigated. The experimental samples were prepared from Eucalyptus wood based on ASTM-D-1413-76 Tanalith-CBC, boric acid, borax, vacsol-WR, immersol-WR, polyethylen glycole-400 and ammonium sulphate were used as an impregnation material. The results indicated that, vacuum treatment on Eucalyptus gave the lowest retention value of salts. Compounds containing boron+salt increased fire resistance however water repellents decreased the wood flammability.

  16. Stable Lobed Mixer With Combustion Demonstrated and Measured

    Science.gov (United States)

    1996-01-01

    The NASA Lewis Research Center collaborated with the Massachusetts Institute of Technology (MIT) on an experiment to study the use of lobed mixers to improve the fuel-air mixing process and increase combustion intensity in combustors with minimal pressure loss. This experiment is the first known stable combusting flow studied for this device, and the data show a much faster and much more uniform combustion process than for flat-plate mixers. Several potential benefits may be realized from this study in future combustors, including a reduction in NO_x emissions because of the more uniform temperature distribution. The experiment was done in Lewis' Planar Reacting Shear Layer facility, which was adapted to accept a lobed mixer in addition to the original planar tip. A graduate student at MIT provided the mixer design concept, and Lewis provided the engineering, operations, and research expertise. The experiment used hydrogen-nitrogen mixtures to react with vitiated hot air at 920 K. A flow speed of about 120 m/sec and a speed ratio of 0.5 were used. Flow diagnostics consisted of traversing fine-wire thermocouples and pitot probes for flow mapping. Supplementary fluorescence images were taken with a charged coupled device (CCD) camera to show the location and temporal behavior of the reaction zone. The data showed that the lobed mixer consumed the reactants between 3 to 10 times faster than a corresponding planar shear layer. The figure shows the dramatic difference in the measured temperature distribution with and without the lobed mixer. The increased mixing rate was due to a larger interfacial area as well as to the secondary flow from the streamwise vortices off the tips of the lobes. In addition, the fluorescence images showed that the lobes acted as flame stabilizers.

  17. Identification device

    Science.gov (United States)

    Lin, Jian-Shian; Su, Chih-Chieh; Chou, Ta-Hsin; Wu, Mount-Learn; Lai, Chieh-Lung; Hsu, Che-Lung; Lan, Hsiao-Chin; Huang, Hung-I.; Liu, Yung-Chih; Tu, Zong-Ru; Lee, Chien-Chieh; Chang, Jenq-Yang

    2007-09-01

    In this Letter, the identification device disclosed in the present invention is comprised of: a carrier and a plurality of pseudo-pixels; wherein each of the plural pseudo-pixels is formed on the carrier and is further comprised of at least a light grating composed of a plurality of light grids. In a preferred aspect, each of the plural light grids is formed on the carrier while spacing from each other by an interval ranged between 50nm and 900nm. As the aforesaid identification device can present specific colors and patterns while it is being viewed by naked eye with respect to a specific viewing angle, the identification device is preferred for security and anti-counterfeit applications since the specific colors and patterns will become invisible when it is viewed while deviating from the specific viewing angle.

  18. Combustion characteristics of SMX and SMX based propellants

    Science.gov (United States)

    Reese, David A.

    This work investigates the combustion of the new solid nitrate ester 2,3-hydroxymethyl-2,3-dinitro-1,4-butanediol tetranitrate (SMX, C6H 8N6O16). SMX was synthesized for the first time in 2008. It has a melting point of 85 °C and oxygen balance of 0% to CO 2, allowing it to be used as an energetic additive or oxidizer in solid propellants. In addition to its neat combustion characteristics, this work also explores the use of SMX as a potential replacement for nitroglycerin (NG) in double base gun propellants and as a replacement for ammonium perchlorate in composite rocket propellants. The physical properties, sensitivity characteristics, and combustion behaviors of neat SMX were investigated. Its combustion is stable at pressures of up to at least 27.5 MPa (n = 0.81). The observed flame structure is nearly identical to that of other double base propellant ingredients, with a primary flame attached at the surface, a thick isothermal dark zone, and a luminous secondary flame wherein final recombination reactions occur. As a result, the burning rate and primary flame structure can be modeled using existing one-dimensional steady state techniques. A zero gas-phase activation energy approximation results in a good fit between modeled and observed behavior. Additionally, SMX was considered as a replacement for nitroglycerin in a double base propellant. Thermochemical calculations indicate improved performance when compared with the common double base propellant JA2 at SMX loadings above 40 wt-%. Also, since SMX is a room temperature solid, migration may be avoided. Like other nitrate esters, SMX is susceptible to decomposition over long-term storage due to the presence of excess acid in the crystals; the addition of stabilizers (e.g., derivatives of urea) during synthesis should be sufficient to prevent this. the addition of Both unplasticized and plasticized propellants were formulated. Thermal analysis of unplasticized propellant showed a distinct melt

  19. Large eddy simulation of unsteady lean stratified premixed combustion

    Energy Technology Data Exchange (ETDEWEB)

    Duwig, C. [Division of Fluid Mechanics, Department of Energy Sciences, Lund University, SE 221 00 Lund (Sweden); Fureby, C. [Division of Weapons and Protection, Warheads and Propulsion, The Swedish Defense Research Agency, FOI, SE 147 25 Tumba (Sweden)

    2007-10-15

    Premixed turbulent flame-based technologies are rapidly growing in importance, with applications to modern clean combustion devices for both power generation and aeropropulsion. However, the gain in decreasing harmful emissions might be canceled by rising combustion instabilities. Unwanted unsteady flame phenomena that might even destroy the whole device have been widely reported and are subject to intensive studies. In the present paper, we use unsteady numerical tools for simulating an unsteady and well-documented flame. Computations were performed for nonreacting, perfectly premixed and stratified premixed cases using two different numerical codes and different large-eddy-simulation-based flamelet models. Nonreacting simulations are shown to agree well with experimental data, with the LES results capturing the mean features (symmetry breaking) as well as the fluctuation level of the turbulent flow. For reacting cases, the uncertainty induced by the time-averaging technique limited the comparisons. Given an estimate of the uncertainty, the numerical results were found to reproduce well the experimental data in terms both of mean flow field and of fluctuation levels. In addition, it was found that despite relying on different assumptions/simplifications, both numerical tools lead to similar predictions, giving confidence in the results. Moreover, we studied the flame dynamics and particularly the response to a periodic pulsation. We found that above a certain excitation level, the flame dynamic changes and becomes rather insensitive to the excitation/instability amplitude. Conclusions regarding the self-growth of thermoacoustic waves were drawn. (author)

  20. Combustion synthesis of ceramic matrices for immobilization of {sup 14}C

    Energy Technology Data Exchange (ETDEWEB)

    Bosc-Rouessac, F. [Institut Charles Gerhardt, UMR 5253, Universite Montpellier II cc1504, Place Eugene Bataillon, 34095 Montpellier Cedex 5 (France); Marin-Ayral, R.M. [Institut Charles Gerhardt, UMR 5253, Universite Montpellier II cc1504, Place Eugene Bataillon, 34095 Montpellier Cedex 5 (France)], E-mail: rose-marie.ayral@univ-montp2.fr; Haidoux, A. [Institut Charles Gerhardt, UMR 5253, Universite Montpellier II cc1504, Place Eugene Bataillon, 34095 Montpellier Cedex 5 (France); Massoni, N.; Bart, F. [CEA Marcoule, Nuclear Energy Division, DTCD/SECM/LM2C, BP 17171, 30200 Bagnols-sur-Ceze Cedex (France)

    2008-10-20

    In this study, the use of combustion synthesis for immobilization of {sup 14}C was considered. Ceramic matrices have been prepared by this method using two different devices: one non-conventional with preheating of the samples and the other conventional device where ignition was produced thanks to tungsten filament. These two devices gave rise to different mechanisms of reactions involving different amounts of unreacted carbon graphite inside the matrix. The SHS samples were characterized by using scanning electron microscopy (SEM) and X-ray diffraction (XRD)

  1. Combustion

    National Research Council Canada - National Science Library

    Glassman, Irvin

    1996-01-01

    ... permission in writing from the publisher. Permissions may be sought directly from Elsevier's Science and Technology Rights Department in Oxford, UK. Phone (44) 1865 843830, Fax: (44) 1865 853333, e-mail: permissions@elsevier.co.uk. You may also complete your request on-line via the Elsevier homepage: http://www.elsevier.com by selecting "...

  2. Measurement and analysis of combustion response to transverse combustion instability

    Science.gov (United States)

    Pomeroy, Brian R.

    This research aimed to gain a better understanding of the response of a gas-centered swirl coaxial injector to transverse combustion instability. The goals of the research were to develop a combustion chamber that would be able to spontaneously produce transverse combustion instability at elevated pressures and temperatures. Methods were also developed to analyze high-speed video images to understand the response of the injector. A combustion chamber was designed that produced high levels of instabilities. The chamber was capable of pressures as high as 1034 kPa (150 psi) and operated using decomposed 90% hydrogen peroxide and JP-8. The chamber used an array of seven gas-centered swirl coaxial injectors that exhibited linear instability to drive the transverse oscillations. The injector elements would operate in a monopropellant configuration flowing only decomposed hydrogen peroxide or in a bipropellant configuration. The location of the bipropellant injectors could be varied to change the level of the instability in the chamber from 10% of the chamber pressure up to 70% of the chamber pressure. A study element was placed in the center of the chamber where it was observed simultaneously by two high-speed video cameras which recorded a backlit video to show the location of the fuel spray and the location of the emitted CH* chemiluminescence. The videos were synchronized with high frequency pressure measurements to gain a full understanding of the physics in the combustion chamber. Results showed that the study element was coupled with the first mode velocity wave. This was expected due to the first mode velocity anti-node being located in the center of the chamber. The velocity is an absolute maximum twice during each cycle so the coupling with the second mode pressure was also investigated showing a possible coupling with both the velocity and pressure. The results of the first mode velocity showed that, as the velocity wave traveled through the chamber, the fuel

  3. Combustion chemistry and formation of pollutants; Chimie de la combustion et formation des polluants

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-31

    This book of proceedings reports on 7 papers on combustion chemistry and formation of pollutants presented during the workshop organized by the `Combustion and Flames` section of the French society of thermal engineers. The chemistry of combustion is analyzed in various situations such as: turbojet engines, spark ignition engines, industrial burners, gas turbines etc... Numerical simulation is used to understand the physico-chemical processes involved in combustion, to describe the kinetics of oxidation, combustion and flame propagation, and to predict the formation of pollutants. (J.S.)

  4. Variable stroke internal combustion engine

    Energy Technology Data Exchange (ETDEWEB)

    Roseby, B.; Hallman, E.P.

    1979-11-20

    An internal combustion engine is described in which the longitudinal center line of the cylinders are parallel to and equally spaced around the longitudinal center line of the engine. The pistons, working within said cylinders, are mounted on a swash plate mechanism, by means of which the reciprocating motion the pistons is translated into the rotary motion of a carrier plate to which the said swash plate is mounted and, from which, is taken the drive into the vehicle transmission. Said swash plate is mounted on a post at the circumference of the carrier plate and pivots around said post when moved, on a longitudinal axis, by a mechanism. As each piston, in turn, passes the point on the swashplate adjacent to the mounting post, it is at the top-dead-center position in its cylinder. As said piston passes the diametrically opposite point on the swash plate it is at the bottom-dead-center position. When the swash plate angle is changed, by moving said mechanism, the bottom dead center position is changed thus causing the stroke of the piston to be changed. A circular form cylinder head contains a combustion chamber for each cylinder and a disc, driven by a forward projecting shaft mounted on the carrier plate, through gearing, and having cam forms on the face actuates the valve mechanism to cause the inlet and exhaust gases to flow to and from the cylinders as required for operation of the running cycle.

  5. Thermally stimulated luminescence studies in combustion ...

    Indian Academy of Sciences (India)

    Synthesis of materials by combustion technique results in homogeneous and fine crystalline product. Further, the technique became more popular since it not only saved time and energy but also was easy to process. Aluminum oxide phosphor was synthesized by using urea as fuel in combustion reaction.

  6. 30 CFR 57.4104 - Combustible waste.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Combustible waste. 57.4104 Section 57.4104... Control Prohibitions/precautions/housekeeping § 57.4104 Combustible waste. (a) Waste materials, including liquids, shall not accumulate in quantities that could create a fire hazard. (b) Waste or rags containing...

  7. Internal combustion engines in hybrid vehicles

    NARCIS (Netherlands)

    Mourad, S.; Weijer, C.J.T. van de; Beckman, D.E.

    1998-01-01

    In this paper the use of internal combustion engines in hybrid powertrains is investigated. The substantial difference between the use of internal combustion engines in conventional and in hybrid vehicles mean that engines for hybrid vehicles should be designed specifically for the purpose. At the

  8. Injector tip for an internal combustion engine

    Science.gov (United States)

    Shyu, Tsu Pin; Ye, Wen

    2003-05-20

    This invention relates to a the tip structure of a fuel injector as used in a internal combustion engine. Internal combustion engines using Homogeneous Charge Compression Ignition (HCCI) technology require a tip structure that directs fuel spray in a downward direction. This requirement necessitates a tip design that is capable of withstanding mechanical stresses associated with the design.

  9. Coal slurry combustion and technology. Volume 2

    Energy Technology Data Exchange (ETDEWEB)

    1983-01-01

    Volume II contains papers presented at the following sessions of the Coal Slurry Combustion and Technology Symposium: (1) bench-scale testing; (2) pilot testing; (3) combustion; and (4) rheology and characterization. Thirty-three papers have been processed for inclusion in the Energy Data Base. (ATT)

  10. A model for premixed combustion oscillations

    Energy Technology Data Exchange (ETDEWEB)

    Janus, M.C.; Richards, G.A.

    1996-09-01

    This paper describes a simulation based on a time dependent, nonlinear control volume analysis. The combustion is modeled as a well-stirred reactor having finite kinetics. Flow properties and species in the nozzle, combustion, and tailpipe regions are determined using a control volume formulation of the conservation equation.

  11. Combustion synthesis and photoluminescence study of silicate ...

    Indian Academy of Sciences (India)

    Silicate based bioceramics are promising candidates as biomaterials for tissue engineering. The combustion synthesis method provides control on the morphology and particle size of the synthesized material. This paper discusses the combustion synthesis of akermanite (Ca2MgSi2O7 and Sr2MgSi2O7), which has been ...

  12. Detection device

    Science.gov (United States)

    Smith, J.E.

    1981-02-27

    The present invention is directed to a detection device comprising: (1) an entrance chamber; (2) a central chamber; and (3) an exit chamber. The central chamber includes an ionizing gas, anode, and means for connecting the anode with an external power supply and pulse counter.

  13. Medical Devices

    NARCIS (Netherlands)

    Verkerke, Gijsbertus Jacob; Mahieu, H.F.; Geertsema, A.A.; Hermann, I.F.; van Horn, J.R.; Hummel, J. Marjan; van Loon, J.P.; Mihaylov, D.; van der Plaats, A.; Schraffordt Koops, H.; Schutte, H.K.; Veth, R.P.H.; de Vries, M.P.; Rakhorst, G.; Shi, Donglu

    2004-01-01

    The development of new medical devices is a very time-consuming and costly process. Besides the time between the initial idea and the time that manufacturing and testing of prototypes takes place, the time needed for the development of production facilities, production of test series, marketing,

  14. Printing Device

    NARCIS (Netherlands)

    Berg, van den M.J.; Markies, P.R.; Zuilhof, H.

    2014-01-01

    An ink jetprinting device includes a pressure chamber formed by a plurality of wall segments, a first aperture extending through a wall segment and communicating with an ink jet orifice and a second aperture extending through a wall segment and communicating with an ink supply duct. The pressure

  15. A predictive model of natural gas mixture combustion in internal combustion engines

    Directory of Open Access Journals (Sweden)

    Henry Espinoza

    2007-05-01

    Full Text Available This study shows the development of a predictive natural gas mixture combustion model for conventional com-bustion (ignition engines. The model was based on resolving two areas; one having unburned combustion mixture and another having combustion products. Energy and matter conservation equations were solved for each crankshaft turn angle for each area. Nonlinear differential equations for each phase’s energy (considering compression, combustion and expansion were solved by applying the fourth-order Runge-Kutta method. The model also enabled studying different natural gas components’ composition and evaluating combustion in the presence of dry and humid air. Validation results are shown with experimental data, demonstrating the software’s precision and accuracy in the results so produced. The results showed cylinder pressure, unburned and burned mixture temperature, burned mass fraction and combustion reaction heat for the engine being modelled using a natural gas mixture.

  16. A predictive model of natural gas mixture combustion in internal combustion engines

    Directory of Open Access Journals (Sweden)

    Henry Espinoza

    2010-04-01

    Full Text Available This study shows the development of a predictive natural gas mixture combustion model for conventional com-bustion (ignition engines. The model was based on resolving two areas; one having unburned combustion mixture and another having combustion products. Energy and matter conservation equations were solved for each crankshaft turn angle for each area. Nonlinear differential equations for each phase’s energy (considering compression, combustion and expansion were solved by applying the fourth-order Runge-Kutta method. The model also enabled studying different natural gas components’ composition and evaluating combustion in the presence of dry and humid air. Validation results are shown with experimental data, demonstrating the software’s precision and accuracy in the results so produced. The results showed cylinder pressure, unburned and burned mixture temperature, burned mass fraction and combustion reaction heat for the engine being modelled using a natural gas mixture.

  17. Effects of calcium magnesium acetate on the combustion of coal-water slurries. Final project report, 1 September 1989--28 February 1993

    Energy Technology Data Exchange (ETDEWEB)

    Levendis, Y.A.; Wise, D.; Metghalchi, H.; Cumper, J.; Atal, A.; Estrada, K.R.; Murphy, B.; Steciak, J.; Hottel, H.C.; Simons, G.

    1993-07-01

    To conduct studies on the combustion of coal water fuels (CWFs) an appropriate facility was designed and constructed. The main components were (1) a high-temperature isothermal laminar flow furnace that facilitates observation of combustion events in its interior. The design of this system and its characterization are described in Chapter 1. (2) Apparatus for slurry droplet/agglomerate particle generation and introduction in the furnace. These devices are described in Chapters 1 and 3 and other attached publications. (3) An electronic optical pyrometer whose design, construction theory of operation, calibration and performance are presented in Chapter 2. (4) A multitude of other accessories, such as particle fluidization devices, a suction thermometer, a velocimeter, high speed photographic equipment, calibration devices for the pyrometer, etc., are described throughout this report. Results on the combustion of CWF droplets and CWF agglomerates made from micronized coal are described in Chapter 3. In the same chapter the combustion of CWF containing dissolved calcium magnesium acetate (CMA) axe described. The combustion behavior of pre-dried CWF agglomerates of pulverized grain coal is contrasted to that of agglomerates of micronized coal in Chapter 4. In the same chapter the combustion of agglomerates of carbon black and diesel soot is discussed as well. The effect of CMA on the combustion of the above materials is also discussed. Finally, the sulfur capture capability of CMA impregnated micronized and pulverized bituminous coals is examined in Chapter 5.

  18. Internal and surface phenomena in metal combustion

    Science.gov (United States)

    Dreizin, Edward L.; Molodetsky, Irina E.; Law, Chung K.

    1995-01-01

    Combustion of metals has been widely studied in the past, primarily because of their high oxidation enthalpies. A general understanding of metal combustion has been developed based on the recognition of the existence of both vapor-phase and surface reactions and involvement of the reaction products in the ensuing heterogeneous combustion. However, distinct features often observed in metal particle combustion, such as brightness oscillations and jumps (spearpoints), disruptive burning, and non-symmetric flames are not currently understood. Recent metal combustion experiments using uniform high-temperature metal droplets produced by a novel micro-arc technique have indicated that oxygen dissolves in the interior of burning particles of certain metals and that the subsequent transformations of the metal-oxygen solutions into stoichiometric oxides are accompanied with sufficient heat release to cause observed brightness and temperature jumps. Similar oxygen dissolution has been observed in recent experiments on bulk iron combustion but has not been associated with such dramatic effects. This research addresses heterogeneous metal droplet combustion, specifically focusing on oxygen penetration into the burning metal droplets, and its influence on the metal combustion rate, temperature history, and disruptive burning. A unique feature of the experimental approach is the combination of the microgravity environment with a novel micro-arc Generator of Monodispersed Metal Droplets (GEMMED), ensuring repeatable formation and ignition of uniform metal droplets with controllable initial temperature and velocity. The droplet initial temperatures can be adjusted within a wide range from just above the metal melting point, which provides means to ignite droplets instantly upon entering an oxygen containing environment. Initial droplet velocity will be set equal to zero allowing one to organize metal combustion microgravity experiments in a fashion similar to usual microgravity

  19. Time Resolved Measurements and Reactive Pathways of Hypergolic Bipropellant Combustion

    National Research Council Canada - National Science Library

    Smith, Jr, James E

    2006-01-01

    This research has improved the fundamental understanding of the physical mechanisms leading to the ignition and combustion of hypergolic propellants from high-speed visualization and combustion diagnostics...

  20. Some characteristics of fine beryllium particle combustion

    Science.gov (United States)

    Davydov, D. A.; Kholopova, O. V.; Kolbasov, B. N.

    2007-08-01

    Beryllium dust will be produced under plasma interaction with beryllium armor of the first wall in ITER. Exothermal reaction of this dust with water steam or air, which can leak into the reactor vacuum chamber in some accidents, gives concern in respect to reactor safety. Results of studies devoted to combustion of fine beryllium particles are reviewed in the paper. A chemically active medium and elevated temperature are prerequisite to the combustion of beryllium particles. Their ignition is hampered by oxide films, which form a diffusion barrier on the particle surface as a result of pre-flame oxidation. The temperature to initiate combustion of particles depends on flame temperature, particle size, composition of combustible mixture, heating rate and other factors. In mixtures enriched with combustible, the flame temperature necessary to ignite individual particles approaches the beryllium boiling temperature.

  1. 2003 Laser Diagnostic in Combustion Conference

    Energy Technology Data Exchange (ETDEWEB)

    Mark G. Allen

    2004-09-10

    The GRC Laser Diagnostics in Combustion aims at bringing together scientists and engineers working in the front edge of research and development to discuss and find new ways to solve problems connected to combustion diagnostics. Laser-based techniques have proven to be very efficient tools for studying combustion processes thanks to features as non-intrusiveness in combination with high spatial and temporal resolution. Major tasks for the community are to develop and apply techniques for quantitative measurements with high precision e.g of species concentrations, temperatures, velocities and particles characteristics (size and concentration). These issues are of global interest, considering that the major part of the World's energy conversion comes from combustion sources and the influence combustion processes have on the environment and society.

  2. Interactive wood combustion for botanical tree models

    KAUST Repository

    Pirk, Sören

    2017-11-22

    We present a novel method for the combustion of botanical tree models. Tree models are represented as connected particles for the branching structure and a polygonal surface mesh for the combustion. Each particle stores biological and physical attributes that drive the kinetic behavior of a plant and the exothermic reaction of the combustion. Coupled with realistic physics for rods, the particles enable dynamic branch motions. We model material properties, such as moisture and charring behavior, and associate them with individual particles. The combustion is efficiently processed in the surface domain of the tree model on a polygonal mesh. A user can dynamically interact with the model by initiating fires and by inducing stress on branches. The flames realistically propagate through the tree model by consuming the available resources. Our method runs at interactive rates and supports multiple tree instances in parallel. We demonstrate the effectiveness of our approach through numerous examples and evaluate its plausibility against the combustion of real wood samples.

  3. Combustion Engines Development Mixture Formation, Combustion, Emissions and Simulation

    CERN Document Server

    Schwarz, Christian; Teichmann, Rüdiger

    2012-01-01

    In the development of engines and vehicles it is nowadays standard practice to use commercially available computing programmes for simulation, not only of the transient reaction of vehicles or of the complete driveshaft, but also of the highly unsteady processes in the combustion chamber of an engine. Normally the source code is not available for these computing programmes and it takes too much time to study the respective specifications, so the users often do not have sufficient knowledge about the physical and chemical contents of the approaches that the programmes are based on. We have often been faced with this fact in talks to employees or in discussions during the presentation of results of simulation. Therefore it is our aim to point out different physical and chemical approaches and to show the possibilities and limits of the models used.

  4. Thermal balance analysis of a micro-thermoelectric gas sensor using catalytic combustion of hydrogen.

    Science.gov (United States)

    Nagai, Daisuke; Akamatsu, Takafumi; Itoh, Toshio; Izu, Noriya; Shin, Woosuck

    2014-01-21

    A thermoelectric gas sensor (TGS) with a combustion catalyst is a calorimetric sensor that changes the small heat of catalytic combustion into a signal voltage. We analyzed the thermal balance of a TGS to quantitatively estimate the sensor parameters. The voltage signal of a TGS was simulated, and the heat balance was calculated at two sections across the thermoelectric film of a TGS. The thermal resistances in the two sections were estimated from the thermal time constants of the experimental signal curves of the TGS. The catalytic combustion heat Q(catalyst) required for 1 mV of ∆V(gas) was calculated to be 46.1 μW. Using these parameters, we find from simulations for the device performance that the expected Q(catalyst) for 200 and 1,000 ppm H₂ was 3.69 μW and 11.7 μW, respectively.

  5. Thermal Balance Analysis of a Micro-Thermoelectric Gas Sensor Using Catalytic Combustion of Hydrogen

    Directory of Open Access Journals (Sweden)

    Daisuke Nagai

    2014-01-01

    Full Text Available A thermoelectric gas sensor (TGS with a combustion catalyst is a calorimetric sensor that changes the small heat of catalytic combustion into a signal voltage. We analyzed the thermal balance of a TGS to quantitatively estimate the sensor parameters. The voltage signal of a TGS was simulated, and the heat balance was calculated at two sections across the thermoelectric film of a TGS. The thermal resistances in the two sections were estimated from the thermal time constants of the experimental signal curves of the TGS. The catalytic combustion heat Qcatalyst required for 1 mV of ∆Vgas was calculated to be 46.1 μW. Using these parameters, we find from simulations for the device performance that the expected Qcatalyst for 200 and 1,000 ppm H2 was 3.69 μW and 11.7 μW, respectively.

  6. Distributed combustion in a cyclonic burner

    Science.gov (United States)

    Sorrentino, Giancarlo; Sabia, Pino; de Joannon, Mara; Cavaliere, Antonio; Ragucci, Raffaele

    2017-11-01

    Distributed combustion regime occurs in several combustion technologies were efficient and environmentally cleaner energy conversion are primary tasks. For such technologies (MILD, LTC, etc…), working temperatures are enough low to boost the formation of several classes of pollutants, such as NOx and soot. To access this temperature range, a significant dilution as well as preheating of reactants is required. Such conditions are usually achieved by a strong recirculation of exhaust gases that simultaneously dilute and pre-heat the fresh reactants. However, the intersection of low combustion temperatures and highly diluted mixtures with intense pre-heating alters the evolution of the combustion process with respect to traditional flames, leading to significant features such as uniformity and distributed ignition. The present study numerically characterized the turbulence-chemistry and combustion regimes of propane/oxygen mixtures, highly diluted in nitrogen, at atmospheric pressure, in a cyclonic combustor under MILD Combustion operating conditions. The velocity and mixing fields were obtained using CFD with focus on mean and fluctuating quantities. The flow-field information helped differentiate between the impact of turbulence levels and dilution ones. The integral length scale along with the fluctuating velocity is critical to determine Damköhler and Karlovitz numbers. Together these numbers identify the combustion regime at which the combustor is operating. This information clearly distinguishes between conventional flames and distributed combustion. The results revealed that major controllers of the reaction regime are dilution and mixing levels; both are significantly impacted by lowering oxygen concentration through entrainment of hot reactive species from within the combustor, which is important in distributed combustion. Understanding the controlling factors of distributed regime is critical for the development and deployment of these novel combustion

  7. Electrical low pressure impactor (ELPI) in characterization of fine particle concentration and size distribution from combustion sources

    Energy Technology Data Exchange (ETDEWEB)

    J. Tikkanen; M. Moisio [Dekati Ltd., Tampere (Finland)

    2005-07-01

    Electrical Low Pressure Impactor (ELPI) is a real time particle size distribution measurement instrument combining a cascade low pressure impactor with a diffusion charger and electrical detection. ELPI is manufactured by Dekati Ltd., and operates on size range of 10 {mu}m to 30 nm with 12 stages. ELPI is an ideal instrument for combustion studies. Its wide size range, real-time capability, size classification and collection in combination with electrical detection makes it a multipurpose tool. In the development of cleaning devices ELPI can be used in both grade efficiency measurements as well as in the study of charging efficiency of the precipitator charger. This is possible by turning off the ELPI charger and monitoring the charge carried by particles charged in the precipitator. Substantial improvements and cost savings can be achieved in the electrostatic precipitators (ESP) development and commissioning work. ELPI can also be used in emission studies, boiler operation studies, etc. The fact that ELPI measures the size distribution and collects the classified particles enables the user to monitor combustion processes in detail, e.g. behavior of heavy metals from coal combustion and ultra fine particle depletion during fluidized bed replenishment pulses. In this study, two coal combustion plants, two peat (mixed) combustion plants, a kraft recovery boiler, two waste combustion plants (CFB and BFB) and a bark combustion plant were considered. 3 refs., 6 figs.

  8. Numerical Modeling and Experimental Validation by Calorimetric Detection of Energetic Materials Using Thermal Bimorph Microcantilever Array: A Case Study on Sensing Vapors of Volatile Organic Compounds (VOCs).

    Science.gov (United States)

    Kang, Seok-Won; Fragala, Joe; Banerjee, Debjyoti

    2015-08-31

    Bi-layer (Au-Si₃N₄) microcantilevers fabricated in an array were used to detect vapors of energetic materials such as explosives under ambient conditions. The changes in the bending response of each thermal bimorph (i.e., microcantilever) with changes in actuation currents were experimentally monitored by measuring the angle of the reflected ray from a laser source used to illuminate the gold nanocoating on the surface of silicon nitride microcantilevers in the absence and presence of a designated combustible species. Experiments were performed to determine the signature response of this nano-calorimeter platform for each explosive material considered for this study. Numerical modeling was performed to predict the bending response of the microcantilevers for various explosive materials, species concentrations, and actuation currents. The experimental validation of the numerical predictions demonstrated that in the presence of different explosive or combustible materials, the microcantilevers exhibited unique trends in their bending responses with increasing values of the actuation current.

  9. Tuning Energetic Material Reactivity Using Surface Functionalization of Aluminum Fuels

    Science.gov (United States)

    2012-10-30

    analysis of three different thermites consisting of aluminum (Al) particles with and without surface functionalization combined with molybdenum...of thermites , aluminum synthesis, aluminum fluoropolymer combustion, acid coatings Keerti S. Kappagantula, Cory Farley, Michelle L. Pantoya, Jillian...Reactivity Using Surface Functionalization of Aluminum Fuels Report Title ABSTRACT Combustion analysis of three different thermites consisting of aluminum (Al

  10. SPIES: Spectropolarimetric Imager for Energetic Sun

    Science.gov (United States)

    Weis, Andrew; Lin, H.

    2012-01-01

    Solar magnetic fields are responsible for the appearance of the solar atmosphere. These magnetic fields are non-uniform, and are strongest over sunspots. Magnetic fields are thought to cause energetic phenomena such as solar flares and coronal mass ejections, which can have damaging consequences in the near-Earth space environment and high latitude regions, providing practical in addition to scientific reasons to study them. Current instrumentation for observations of solar magnetic fields use scanning slit spectrograph or tunable filter, which allow us to resolve the time evolution of the fields to the scale of minutes or longer. We are constructing a new instrument, SPIES, based on a large-format (32 x 64) fiber-optic integral field unit (IFU). The fiber-optic IFU allows us to observe over two spatial dimensions and one spectral dimension simultaneously rather than in steps, thus allowing for resolution of the time evolution to the level of seconds. Due to fiber modal noise and small thermal drift of the instrument over time, flat-fielding of the intensity spectra from the discrete fiber-optic 'slits' becomes time dependent. An observing scheme that records time-sensitive flat-fields was devised for SPIES. We will present preliminary analysis of the full-Stokes polarization spectra of a sunspot obtained with SPIES over a 90 minute time span. This work was conducted through a Research Experience for Undergraduates (REU) position at the University of Hawai'i's Institute for Astronomy and was funded by the NSF.

  11. PLASMA ENERGETIC PARTICLES SIMULATION CENTER (PEPSC)

    Energy Technology Data Exchange (ETDEWEB)

    Berk, Herbert L.

    2014-05-23

    The main effort of the Texas group was to develop theoretical and simplified numerical models to understand chirping phenomena often seen for Alfven and geodesic acoustic waves in experimental plasmas such as D-III-D, NSTX and JET. Its main numerical effort was to modify the AEGIS code, which was originally developed as an eigenvalue solver. To apply to the chirping problem this code has to be able to treat the linear response to the continuum and the response of the plasma to external drive or to an internal drive that comes from the formation of phase space chirping structures. The theoretical underpinning of this investigation still needed to be more fully developed to understand how to best formulate the theoretical problem. Considerable progress was made on this front by B.N. Breizman and his collaborators and a new reduced model was developed by H. L. Berk and his PhD student, G. Wang which can be uses as simplified model to describe chirping in a large aspect ratio tokamak. This final report will concentrate on these two directions that were developed as well as results that were found in the work with the AEGIS code and in the progress in developing a novel quasi-linear formulation for a description of Alfvenic modes destabilized by energetic particles, such as alpha particles in a burning plasma.

  12. Energetics and population ecology of Siberian herders.

    Science.gov (United States)

    Leonard, William R; Katzmarzyk, Peter T; Crawford, Michael H

    1996-01-01

    Methodological advances now permit human biologists to more effectively monitor energy dynamics in traditional societies. This study examines the nutritional ecology and energetics of semisubsistence herders of Siberia (Evenki) during a single season of their annual cycle (late summer). Total energy expenditure (TEE) among adults, as measured by daily heart-rate monitoring, is greater in Evenki men (TEE = 11.9 ± 2.8 MJ/d in men and 8.8 ± 2.1 MJ/d in women; P pattern that reflects the current division of labor under collectivized herding systems. Energy intakes are also greater among men (13.4 ± 5.6 vs. 8.5 ± 3.4 MJ/d; P pattern of fat distribution. Evenki males appear to be undergoing a secular trend in stature, while no such increases are evident in females. These gender differences may reflect the differential impact to the changes associated with collectivization. Reduced metabolic requirements (due to declining activity and fertility levels), along with greater food availability, are likely to be responsible for the higher rates of obesity among Evenki women. © 1996 Wiley-Liss, Inc. Copyright © 1996 Wiley-Liss, Inc.

  13. Reactive thermal waves in energetic materials

    Energy Technology Data Exchange (ETDEWEB)

    Hill, Larry G [Los Alamos National Laboratory

    2009-01-01

    Reactive thermal waves (RTWs) arise in several energetic material applications, including self-propagating high-temperature synthesis (SHS), high explosive cookoff, and the detonation of heterogeneous explosives. In this paper I exmaine ideal RTWs, by which I mean that (1) material motion is neglected, (2) the state dependence of reaction is Arrhenius in the temperature, and (3) the reaction rate is modulated by an arbitrary mass-fraction-based reaction progress function. Numerical simulations demonstrate that one's natural intuition, which is based mainly upon experience with inert materials and which leads one to expect diffusion processes to become relatively slow after a short time period, is invalid for high energy, state-sensitive reactive systems. Instead, theory predicts that RTWs can propagate at very high speeds. This result agrees with estimates for detonating heterogeneous explosives, which indicate that RTWs must spread from hot-spot nucleation sites at rates comparable to the detonation speed in order to produce experimentally-observed reaction zone thicknesses. Using dimensionless scaling and further invoking the high activation energy approximation, I obtain an analytic formula for the steady plane RTW speed from numerical calculations. I then compute the RTW speed for real explosives, and discuss aspects of their behavior.

  14. Running Economy from a Muscle Energetics Perspective

    Directory of Open Access Journals (Sweden)

    Jared R. Fletcher

    2017-06-01

    Full Text Available The economy of running has traditionally been quantified from the mass-specific oxygen uptake; however, because fuel substrate usage varies with exercise intensity, it is more accurate to express running economy in units of metabolic energy. Fundamentally, the understanding of the major factors that influence the energy cost of running (Erun can be obtained with this approach. Erun is determined by the energy needed for skeletal muscle contraction. Here, we approach the study of Erun from that perspective. The amount of energy needed for skeletal muscle contraction is dependent on the force, duration, shortening, shortening velocity, and length of the muscle. These factors therefore dictate the energy cost of running. It is understood that some determinants of the energy cost of running are not trainable: environmental factors, surface characteristics, and certain anthropometric features. Other factors affecting Erun are altered by training: other anthropometric features, muscle and tendon properties, and running mechanics. Here, the key features that dictate the energy cost during distance running are reviewed in the context of skeletal muscle energetics.

  15. Large gradual solar energetic particle events

    Directory of Open Access Journals (Sweden)

    Mihir Desai

    2016-09-01

    Full Text Available Abstract Solar energetic particles, or SEPs, from suprathermal (few keV up to relativistic ( $$\\sim $$ ∼ few GeV energies are accelerated near the Sun in at least two ways: (1 by magnetic reconnection-driven processes during solar flares resulting in impulsive SEPs, and (2 at fast coronal-mass-ejection-driven shock waves that produce large gradual SEP events. Large gradual SEP events are of particular interest because the accompanying high-energy ( $${>}10$$ > 10 s MeV protons pose serious radiation threats to human explorers living and working beyond low-Earth orbit and to technological assets such as communications and scientific satellites in space. However, a complete understanding of these large SEP events has eluded us primarily because their properties, as observed in Earth orbit, are smeared due to mixing and contributions from many important physical effects. This paper provides a comprehensive review of the current state of knowledge of these important phenomena, and summarizes some of the key questions that will be addressed by two upcoming missions—NASA’s Solar Probe Plus and ESA’s Solar Orbiter. Both of these missions are designed to directly and repeatedly sample the near-Sun environments where interplanetary scattering and transport effects are significantly reduced, allowing us to discriminate between different acceleration sites and mechanisms and to isolate the contributions of numerous physical processes occurring during large SEP events.

  16. Energetics of swimming of a sea turtle.

    Science.gov (United States)

    Prange, H D

    1976-02-01

    Young (mean mass 735 g) green turtles (Chelonia mydas) were able to swim in a water channel at sustained speeds between 0-14 and 0-35 m.s-1. Oxygen consumption at rest was was 0-07 l.kg-1.h-1; at maximum swimming speed oxygen consumption was 3-4 times greater than at rest for a given individual. In comparison with other animals of the same body mass the cost of transport for the green turtle (0.186lO2.kg-1.km-1) is less than that for flying birds but greater than that for fish. From drag measurements it was calculated that the aerobic efficiency of swimming was between 1 and 10%; the higher efficiencies were found at the higher swimming speeds. Based upon the drag calculations for young turtles, it is estimated that adult turtles making the round-trip breeding migration between Brazil and Ascension Island (4800 km) would require the equivalent of about 21% of their body mass in fat stores to account for the energetic cost of swimming.

  17. Linking energetics and overwintering in temperate insects.

    Science.gov (United States)

    Sinclair, Brent J

    2015-12-01

    Overwintering insects cannot feed, and energy they take into winter must therefore fuel energy demands during autumn, overwintering, warm periods prior to resumption of development in spring, and subsequent activity. Insects primarily consume lipids during winter, but may also use carbohydrate and proteins as fuel. Because they are ectotherms, the metabolic rate of insects is temperature-dependent, and the curvilinear nature of the metabolic rate-temperature relationship means that warm temperatures are disproportionately important to overwinter energy use. This energy use may be reduced physiologically, by reducing the slope or elevation of the metabolic rate-temperature relationship, or because of threshold changes, such as metabolic suppression upon freezing. Insects may also choose microhabitats or life history stages that reduce the impact of overwinter energy drain. There is considerable capacity for overwinter energy drain to affect insect survival and performance both directly (via starvation) or indirectly (for example, through a trade-off with cryoprotection), but this has not been well-explored. Likewise, the impact of overwinter energy drain on growing-season performance is not well understood. I conclude that overwinter energetics provides a useful lens through which to link physiology and ecology and winter and summer in studies of insect responses to their environment. Copyright © 2014 Elsevier Ltd. All rights reserved.

  18. The energetics of anabolism in natural settings.

    Science.gov (United States)

    LaRowe, Douglas E; Amend, Jan P

    2016-06-01

    The environmental conditions that describe an ecosystem define the amount of energy available to the resident organisms and the amount of energy required to build biomass. Here, we quantify the amount of energy required to make biomass as a function of temperature, pressure, redox state, the sources of C, N and S, cell mass and the time that an organism requires to double or replace its biomass. Specifically, these energetics are calculated from 0 to 125 °C, 0.1 to 500 MPa and -0.38 to +0.86 V using CO2, acetate or CH4 for C, NO3(-) or NH4(+) for N and SO4(2-) or HS(-) for S. The amounts of energy associated with synthesizing the biomolecules that make up a cell, which varies over 39 kJ (g cell)(-1), are then used to compute energy-based yield coefficients for a vast range of environmental conditions. Taken together, environmental variables and the range of cell sizes leads to a ~4 orders of magnitude difference between the number of microbial cells that can be made from a Joule of Gibbs energy under the most (5.06 × 10(11) cells J(-1)) and least (5.21 × 10(7) cells J(-1)) ideal conditions. When doubling/replacement time is taken into account, the range of anabolism energies can expand even further.

  19. Energetic costs of calcification under ocean acidification

    Science.gov (United States)

    Spalding, Christopher; Finnegan, Seth; Fischer, Woodward W.

    2017-05-01

    Anthropogenic ocean acidification threatens to negatively impact marine organisms that precipitate calcium carbonate skeletons. Past geological events, such as the Permian-Triassic Mass Extinction, together with modern experiments generally support these concerns. However, the physiological costs of producing a calcium carbonate skeleton under different acidification scenarios remain poorly understood. Here we present an idealized mathematical model to quantify whole-skeleton costs, concluding that they rise only modestly (up to ˜10%) under acidification expected for 2100. The modest magnitude of this effect reflects in part the low energetic cost of inorganic, calcium carbonate relative to the proteinaceous organic matrix component of skeletons. Our analysis does, however, point to an important kinetic constraint that depends on seawater carbonate chemistry, and we hypothesize that the impact of acidification is more likely to cause extinctions within groups where the timescale of larval development is tightly constrained. The cheapness of carbonate skeletons compared to organic materials also helps explain the widespread evolutionary convergence upon calcification within the metazoa.

  20. Solar energetic particles: Acceleration and transport

    Science.gov (United States)

    Cliver, Edward W.

    2000-06-01

    This paper reviews highlights of the 26th ICRC in the area of acceleration and propagation of solar energetic particles (SEPs). New results on SEP charge state and composition, a lively topic during the Conference, are covered in an accompanying paper by Klecker. I begin with a brief historical review of the field to provide context for the key advances/developments on SEP acceleration/propagation presented in Salt Lake City. These include: (1) the use of gamma-ray emissions as diagnostics of the acceleration process(es) and probes of the interaction region; (2) the observation of ~10 GeV (or higher) protons for the 6 November 1997 ground level event by the Milagrito experiment; (3) observations of coronal Moreton waves as ``smoking pistols'' of shock acceleration/injection of SEPs; (4) an investigation of the role of proton event spectra in the current ``two-class'' picture of SEP events; (5) an analysis of the Gnevyshev Gap in SEP activity; (6) a Ulysses-based determination of the dependence of SEP mean free path on radial distance from the Sun and on heliographic latitude, and (7) an examination of the dissipation range in the power spectrum of interplanetary magnetic field fluctuations. I conclude with a discussion of new instrumentation (e.g., Milagro, HESSI) and a look to the expected level of SEP activity for the approaching maximum of solar cycle 23. .

  1. ARCTIC VECTOR OF BRITISH ENERGETIC STRATEGY

    Directory of Open Access Journals (Sweden)

    Natalia Valerievna Eremina

    2017-03-01

    Full Text Available The aim of the article is to reveal the forms, methods, content of British strategy in Arctic. Arctic is becoming the area of international cooperation among, first of all, Arctic states. Britain has ambitions to get the status of so-called “subarctic state” to prove its international leadership and acquire guarantees of energetic security. Now Britain has been elaborating the two strategies: military and scientific ones. The main instrument to solve the tasks for Britain is to participate in international structures, connected with Arctic. The article pays attention to the aspects that were not previously analyzed, such as: reasons of British interests in Arctic, bilateral and multilateral relationships between Britain and its partners, first of all, cooperation between Russia and Britain; British institutions; positive and negative aspects of British Arctic strategy; factors that have impact on its evolution, mainly EU and Scottish factors. The research allowed to make the conclusion that Britain does not have enough instruments to have a strong disposition in Arctic, though it plans to accelerate its participation in Arctic organizations. The article is based upon system and structural analysis.

  2. Aerodynamic study of a jet of mono-dispersed droplets during evaporation and combustion using optical methods; Etude aerodynamique d'un jet de gouttes monodisperse en evaporation et en combustion a l'aide de methodes optiques

    Energy Technology Data Exchange (ETDEWEB)

    Castanet, G.

    2004-10-01

    The knowledge of aero-thermal phenomena occurring in the combustion chamber is a key point in order to improve propulsive systems. Non intrusive optical diagnostics are necessary to investigate the mechanisms governing the droplets evaporation. A technique based on two colours laser-induced fluorescence allows obtaining the space averaged temperature of streaming droplets and the temperature distribution inside a droplet for linear monodisperse droplet stream. Sizes of droplets are measured with the use of a Phase Doppler Particle Analyser. An energetic budget allows to determine experimentally Nusselt and Sherwood numbers in combustion. Within droplets motions are modelled by a Hill vortex with an intensity adjusted from space averaged temperature measurements or from experimental temperature maps. Vapour transport phenomena inside the gaseous phase are studied by using the Planar Laser Induced Fluorescence technique in order to determine the concentration field of vapour. (author)

  3. Atypical energetic particle events observed prior energetic particle enhancements associated with corotating interaction regions

    Science.gov (United States)

    Khabarova, Olga; Malandraki, Olga; Zank, Gary; Jackson, Bernard; Bisi, Mario; Desai, Mihir; Li, Gang; le Roux, Jakobus; Yu, Hsiu-Shan

    2017-04-01

    Recent studies of mechanisms of particle acceleration in the heliosphere have revealed the importance of the comprehensive analysis of stream-stream interactions as well as the heliospheric current sheet (HCS) - stream interactions that often occur in the solar wind, producing huge magnetic cavities bounded by strong current sheets. Such cavities are usually filled with small-scale magnetic islands that trap and re-accelerate energetic particles (Zank et al. ApJ, 2014, 2015; le Roux et al. ApJ, 2015, 2016; Khabarova et al. ApJ, 2015, 2016). Crossings of these regions are associated with unusual variations in the energetic particle flux up to several MeV/nuc near the Earth's orbit. These energetic particle flux enhancements called "atypical energetic particle events" (AEPEs) are not associated with standard mechanisms of particle acceleration. The analysis of multi-spacecraft measurements of energetic particle flux, plasma and the interplanetary magnetic field shows that AEPEs have a local origin as they are observed by different spacecraft with a time delay corresponding to the solar wind propagation from one spacecraft to another, which is a signature of local particle acceleration in the region embedded in expanding and rotating background solar wind. AEPEs are often observed before the arrival of corotating interaction regions (CIRs) or stream interaction regions (SIRs) to the Earth's orbit. When fast solar wind streams catch up with slow solar wind, SIRs of compressed heated plasma or more regular CIRs are created at the leading edge of the high-speed stream. Since coronal holes are often long-lived structures, the same CIR re-appears often for several consecutive solar rotations. At low heliographic latitudes, such CIRs are typically bounded by forward and reverse waves on their leading and trailing edges, respectively, that steepen into shocks at heliocentric distances beyond 1 AU. Energetic ion increases have been frequently observed in association with CIR

  4. Indirect combustion noise of auxiliary power units

    Science.gov (United States)

    Tam, Christopher K. W.; Parrish, Sarah A.; Xu, Jun; Schuster, Bill

    2013-08-01

    Recent advances in noise suppression technology have significantly reduced jet and fan noise from commercial jet engines. This leads many investigators in the aeroacoustics community to suggest that core noise could well be the next aircraft noise barrier. Core noise consists of turbine noise and combustion noise. There is direct combustion noise generated by the combustion processes, and there is indirect combustion noise generated by the passage of combustion hot spots, or entropy waves, through constrictions in an engine. The present work focuses on indirect combustion noise. Indirect combustion noise has now been found in laboratory experiments. The primary objective of this work is to investigate whether indirect combustion noise is also generated in jet and other engines. In a jet engine, there are numerous noise sources. This makes the identification of indirect combustion noise a formidable task. Here, our effort concentrates exclusively on auxiliary power units (APUs). This choice is motivated by the fact that APUs are relatively simple engines with only a few noise sources. It is, therefore, expected that the chance of success is higher. Accordingly, a theoretical model study of the generation of indirect combustion noise in an Auxiliary Power Unit (APU) is carried out. The cross-sectional areas of an APU from the combustor to the turbine exit are scaled off to form an equivalent nozzle. A principal function of a turbine in an APU is to extract mechanical energy from the flow stream through the exertion of a resistive force. Therefore, the turbine is modeled by adding a negative body force to the momentum equation. This model is used to predict the ranges of frequencies over which there is a high probability for indirect combustion noise generation. Experimental spectra of internal pressure fluctuations and far-field noise of an RE220 APU are examined to identify anomalous peaks. These peaks are possible indirection combustion noise. In the case of the

  5. Filtration Combustion in Smoldering and SHS

    Science.gov (United States)

    Matkowsky, Bernard J.

    2001-01-01

    Smolder waves and SHS (self-propagating high-temperature synthesis) waves are both examples of filtration combustion waves propagating in porous media. Smoldering combustion is important for the study of fire safety. Smoldering itself can cause damage, its products are toxic and it can also lead to the more dangerous gas phase combustion which corresponds to faster propagation at higher temperatures. In SHS , a porous solid sample, consisting of a finely ground powder mixture of reactants, is ignited at one end. A high temperature thermal wave, having a frontal structure, then propagates through the sample converting reactants to products. The SHS technology appears to enjoy a number of advantages over the conventional technology, in which the sample is placed in a furnace and "baked" until it is "well done". The advantages include shorter synthesis times, greater economy, in that the internal energy of the reactions is employed rather than the costly external energy of the furnace, purer products, simpler equipment and no intrinsic limitation on the size of the sample to be synthesized as exists in the conventional technology. When delivery of reactants through the pores to the reaction site is an important aspect of the combustion process, it is referred to as filtration combustion. The two types of filtration combustion have a similar mathematical formulation, describing the ignition, propagation and extinction of combustion waves in porous media. The goal in each case, however, is different. In smoldering the desired goal is to prevent propagation, whereas in SHS the goal is to ensure propagation of the combustion wave, leading to the synthesis of desired products. In addition, the scales in the two areas of application differ. Smoldering generally occurs at lower temperatures and propagation velocities than in SHS nevertheless, the two applications have much in common so that what is learned fit make application can be used to advantage in the other. In porous

  6. Laser device

    Science.gov (United States)

    Scott, Jill R.; Tremblay, Paul L.

    2008-08-19

    A laser device includes a virtual source configured to aim laser energy that originates from a true source. The virtual source has a vertical rotational axis during vertical motion of the virtual source and the vertical axis passes through an exit point from which the laser energy emanates independent of virtual source position. The emanating laser energy is collinear with an orientation line. The laser device includes a virtual source manipulation mechanism that positions the virtual source. The manipulation mechanism has a center of lateral pivot approximately coincident with a lateral index and a center of vertical pivot approximately coincident with a vertical index. The vertical index and lateral index intersect at an index origin. The virtual source and manipulation mechanism auto align the orientation line through the index origin during virtual source motion.

  7. Energetic performance analysis of drying agricultural products ...

    African Journals Online (AJOL)

    Renewable energy sources such as solar energy for drying purposes in a more effective and efficient way is inevitable for preservation of agricultural products in developing nations with inadequate access to electricity. This study investigates the effects of using a solar tracking device on the energy performance of drying ...

  8. Basic Aerodynamics of Combustion Chambers,

    Science.gov (United States)

    1981-05-20

    n layer, an- its rhti re ai ei ar td . te II- to vortical wraXes which are also cplled "vo-tical rolls." r, and r,~=the er-temal 142 GaI M6.12 *%AAtM...8217-2XCC, UMn Th-~ t tr’.~t in ain~zttfror tecit vr’ 0 7 fij74,it ~r ~ h-t >2 h’’tof the jeb ,;p ~ ’ - ~~ *~~~k -. A--w.- - -- Chaptler 8 Tur~l.flftece Jet...G, is very small (the straight line AD), then, it is only possible to have combustion when one has temperature TD ; no other condition will do. If one

  9. Nanoparticle emissions from combustion engines

    CERN Document Server

    Merkisz, Jerzy

    2015-01-01

     This book focuses on particulate matter emissions produced by vehicles with combustion engines. It describes the physicochemical properties of the particulate matter, the mechanisms of its formation and its environmental impacts (including those on human beings). It discusses methods for measuring particulate mass and number, including the state-of-the-art in Portable Emission Measurement System (PEMS) equipment for measuring the exhaust emissions of both light and heavy-duty vehicles and buses under actual operating conditions. The book presents the authors’ latest investigations into the relations between particulate emission (mass and number) and engine operating parameters, as well as their new findings obtained through road tests performed on various types of vehicles, including those using diesel particulate filter regeneration. The book, which addresses the needs of academics and professionals alike, also discusses relevant European regulations on particulate emissions and highlights selected metho...

  10. Catalytic combustion of residual fuels

    Science.gov (United States)

    Bulzan, D. L.; Tacina, R. R.

    1981-01-01

    A noble metal catalytic reactor was tested using two grades of petroleum derived residual fuels at specified inlet air temperatures, pressures, and reference velocities. Combustion efficiencies greater than 99.5 percent were obtained. Steady state operation of the catalytic reactor required inlet air temperatures of at least 800 K. At lower inlet air temperatures, upstream burning in the premixing zone occurred which was probably caused by fuel deposition and accumulation on the premixing zone walls. Increasing the inlet air temperature prevented this occurrence. Both residual fuels contained about 0.5 percent nitrogen by weight. NO sub x emissions ranged from 50 to 110 ppm by volume at 15 percent excess O2. Conversion of fuel-bound nitrogen to NO sub x ranged from 25 to 50 percent.

  11. Carburettor for internal combustion engines. Vergaser fuer Brennkraftmaschinen

    Energy Technology Data Exchange (ETDEWEB)

    Bombe, W.; Stappen, P.; Wagner, H.G.; Woebky, P.

    1991-01-10

    Carburettors of this type may have a throttling orifice as part of a starting device. The pre-throttle is set depending on the signals of a control device, this however, means that a great deal of trouble has to be taken with the design of the control unit and the identification of important operational parameters of the internal combustion engine. The invention's task is to use the throttling orifice for applications other than start-up-warmup period though the control unit shall remain reserved for these purposes only. If the start-up device fails to function, the throttling orifice valve can be moved in direction of closure by a second pneumatic correcting element; the second correcting element is driven by the drive pressure of an electro-pneumatic pressure transformer which reacts to the control device and generates driving pressure which lies between the suction pressure downstream of the throttle valve in the induction part and athmosperic pressure. This carburettor is suited for road vehicles.

  12. "Distinvar" device

    CERN Multimedia

    CERN PhotoLab

    1965-01-01

    The alignment of one of the accelerator magnets being checked by the AR Division survey group. A "distinvar" device, invented by the group, using calibrated invar wires stretched between the fixed survey pillar (on the left) and a fixed point on the magnet. In two days it is thus possible to measure the alignment of the 100 magnets with an accuracy better than 1/10.

  13. Modeling of natural acoustic frequencies of a gas-turbine plant combustion chamber

    Science.gov (United States)

    Zubrilin, I. A.; Gurakov, N. I.; Zubrilin, R. A.; Matveev, S. G.

    2017-05-01

    The paper presents results of determination of natural acoustic frequencies of a gas-turbine plant annular combustion chamber model using 3D-simulation. At the beginning, a calculation procedure for determining natural acoustic frequencies of the gas-turbine plant combustion chamber was worked out. The effect of spatial inhomogeneity of the flow parameters (fluid composition, pressure, temperature) arising in combustion and some geometrical parameters (cooling holes of the flame tube walls) on the calculation results is studied. It is found that the change of the fluid composition in combustion affects the acoustic velocity not more than 5%; therefore, the air with a volume variable temperature can be taken as a working fluid in the calculation of natural acoustic frequencies. It is also shown that the cooling holes of the flame tube walls with diameter less than 2 mm can be neglected in the determination of the acoustic modes in the frequency range of up to 1000 Hz. This reduces the number of the grid-model elements by a factor of six in comparison with a model that considers all of the holes. Furthermore, a method of export of spatial inhomogeneity of the flow parameters from a CFD solver sector model to the annular combustion chamber model in a modal solver is presented. As a result of the obtained model calculation, acoustic modes of the combustion chamber in the frequency range of up to 1000 Hz are determined. For a standard engine condition, a potentially dangerous acoustic mode with a frequency close to the ripple frequency of the precessing vortex core, which is formed behind the burner device of this combustion chamber, is detected.

  14. Time-resolved emission spectroscopy for the combustion analysis of series production engines

    Science.gov (United States)

    Block, Bernd; Moeser, Petra; Hentschel, Werner

    1997-04-01

    This paper presents a device that detects light emerging from the combustion inside a series production automotive engine. Simultaneous time and wavelength resolution is achieved by this system and it can be applied in a simple manner to either diesel or spark ignition (SI) engines without any geometrical modification or the combustion chamber. An optical probe is inserted into spark plug or glow plug. A fiber is connected to the probe and leads the light to a spectrograph, which provides spectral analysis in the UV and visible wavelength ranges. An intensified streak camera with time resolution in the microsecond range completes the detection unit. This measuring system enables time-resolved emission spectroscopy applied to the light emitted during the combustion in a series production engine. Time-resolved emission spectra are presented from both a diesel and an SI engine. The time behavior of the internal temperature in a diesel engine combustion chamber and its dependence on engine speed and load are measured with this setup using a multiple two-color method. In an SI engine, the time behavior of the emissions of specific molecules or radicals is detected. Thus, differences in the combustion process are demonstrated to be caused by operation with different fuels.

  15. Extended lattice Boltzmann scheme for droplet combustion.

    Science.gov (United States)

    Ashna, Mostafa; Rahimian, Mohammad Hassan; Fakhari, Abbas

    2017-05-01

    The available lattice Boltzmann (LB) models for combustion or phase change are focused on either single-phase flow combustion or two-phase flow with evaporation assuming a constant density for both liquid and gas phases. To pave the way towards simulation of spray combustion, we propose a two-phase LB method for modeling combustion of liquid fuel droplets. We develop an LB scheme to model phase change and combustion by taking into account the density variation in the gas phase and accounting for the chemical reaction based on the Cahn-Hilliard free-energy approach. Evaporation of liquid fuel is modeled by adding a source term, which is due to the divergence of the velocity field being nontrivial, in the continuity equation. The low-Mach-number approximation in the governing Navier-Stokes and energy equations is used to incorporate source terms due to heat release from chemical reactions, density variation, and nonluminous radiative heat loss. Additionally, the conservation equation for chemical species is formulated by including a source term due to chemical reaction. To validate the model, we consider the combustion of n-heptane and n-butanol droplets in stagnant air using overall single-step reactions. The diameter history and flame standoff ratio obtained from the proposed LB method are found to be in good agreement with available numerical and experimental data. The present LB scheme is believed to be a promising approach for modeling spray combustion.

  16. Performance Evaluation of a High Bandwidth Liquid Fuel Modulation Valve for Active Combustion Control

    Science.gov (United States)

    Saus, Joseph R.; DeLaat, John C.; Chang, Clarence T.; Vrnak, Daniel R.

    2012-01-01

    At the NASA Glenn Research Center, a characterization rig was designed and constructed for the purpose of evaluating high bandwidth liquid fuel modulation devices to determine their suitability for active combustion control research. Incorporated into the rig s design are features that approximate conditions similar to those that would be encountered by a candidate device if it were installed on an actual combustion research rig. The characterized dynamic performance measures obtained through testing in the rig are planned to be accurate indicators of expected performance in an actual combustion testing environment. To evaluate how well the characterization rig predicts fuel modulator dynamic performance, characterization rig data was compared with performance data for a fuel modulator candidate when the candidate was in operation during combustion testing. Specifically, the nominal and off-nominal performance data for a magnetostrictive-actuated proportional fuel modulation valve is described. Valve performance data were collected with the characterization rig configured to emulate two different combustion rig fuel feed systems. Fuel mass flows and pressures, fuel feed line lengths, and fuel injector orifice size was approximated in the characterization rig. Valve performance data were also collected with the valve modulating the fuel into the two combustor rigs. Comparison of the predicted and actual valve performance data show that when the valve is operated near its design condition the characterization rig can appropriately predict the installed performance of the valve. Improvements to the characterization rig and accompanying modeling activities are underway to more accurately predict performance, especially for the devices under development to modulate fuel into the much smaller fuel injectors anticipated in future lean-burning low-emissions aircraft engine combustors.

  17. Progress Towards a Benchtop Energetics Capability (BRIEFING CHARTS)

    National Research Council Canada - National Science Library

    Fajardo, Mario E; Lewis, William K

    2006-01-01

    The incorporation of nanometric (sub-micron size) metal fuel and oxidizer particles into energetic materials is a promising approach to increasing significantly the systems-level performance of munitions...

  18. Aerial energetic residue data from JBER C4 testing

    Data.gov (United States)

    U.S. Environmental Protection Agency — Aerially-collected energetic residues from surface detonation of C4. This dataset is associated with the following publication: Walsh, M., B. Gullett, M. Walsh, M....

  19. Modelling the Energetics of Encapsulation of Atoms and Atomic ...

    Indian Academy of Sciences (India)

    user

    2015-07-04

    Jul 4, 2015 ... Modelling the Energetics of Encapsulation of. Atoms and Atomic Clusters into Carbon. Nanotubes: Insights from Analytical Approaches. R. S. Swathi. School of Chemistry. Indian Institute of Science Education and Research. Thiruvananthapuram, Kerala, India ...

  20. JUNO J ENERGETIC PARTICLE DETECTOR UNCALIBRATED V1.0

    Data.gov (United States)

    National Aeronautics and Space Administration — Abstract ======== This data set consists of the JUNO JEDI (Jupiter Energetic-Particle Detector) uncalibrated observations, also known as EDRs. The system is made up...

  1. Metal-organic frameworks (MOFs) as safer, structurally reinforced energetics.

    Science.gov (United States)

    Bushuyev, Oleksandr S; Peterson, Geneva R; Brown, Preston; Maiti, Amitesh; Gee, Richard H; Weeks, Brandon L; Hope-Weeks, Louisa J

    2013-01-28

    Second-generation cobalt and zinc coordination architectures were obtained through efforts to stabilize extremely sensitive and energetic transition-metal hydrazine perchlorate ionic polymers. Partial ligand substitution by the tridentate hydrazinecarboxylate anion afforded polymeric 2D-sheet structures never before observed for energetic materials. Carefully balanced reaction conditions allowed the retention of the noncoordinating perchlorate anion in the presence of a strongly chelating hydrazinecarboxylate ligand. High-quality X-ray single-crystal structure determination revealed that the metal coordination preferences lead to different structural motifs and energetic properties, despite the nearly isoformulaic nature of the two compounds. Energetic tests indicate highly decreased sensitivity and DFT calculations suggest a high explosive performance for these remarkable structures. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. A further study of spectral energetics in the winter atmosphere

    Science.gov (United States)

    Chen, T.-C.

    1982-01-01

    The contributions of standing (time-mean) and transient (time-departure) waves to the atmospheric spectral energetics are analyzed using the NMC (National Meteorological Center) data of winter 1976-1977. It is found that the standing long waves are responsible for the major horizontal sensible heat transport and also for the significant horizontal momentum transport. Furthermore, the major contents of eddy available energy and eddy kinetic energy of standing waves are in the long-wave regime. However, the spectral energetics analysis indicates that the standing long waves are energetically less efficient than the transient long and short waves. It is suggested that the lower efficiency of the standing long waves in the atmospheric energetics may be one of the physical factors causing the underforecast of the standing long waves in the numerical weather prediction models.

  3. ENERGETIC EXTREMES IN REEF FISH OCCUPYING HARSH HABITATS

    DEFF Research Database (Denmark)

    Steffensen, John Fleng

    2009-01-01

    document how relatively small changes in fin morphology has afforded some coral reef fish taxa with exceptional locomotor performance and energetic efficiency, and how this key attribute may have played a key role in the evolution and ecology of several diverse Indo-Pacific reef fish families. Using......-swept environment (up to 1 m s-1) whilst incurring a relatively low energetic cost of transport. Paddle-finned sister taxa, which have slightly more rounded fins and occupy sheltered habitats, displayed similar levels of energetic efficiency, but at swimming speeds less than half that of their wing......-finned counterparts. We discuss how such differences in locomotor efficiency are pivotal to the habitat-use of these fishes, and how eco-energetic models may be used to provide new insights into spatial variations in fish demography and ecology among coral reef habitat zones....

  4. Inverse Energy Dispersion of Energetic Ions Observed in the Magnetosheath

    Science.gov (United States)

    Lee, S. H.; Sibeck, D. G.; Hwang, K.-J.; Wang, Y.; Silveira, M. V. D.; Fok, M.-C.; Mauk, B. H.; Cohen, I. J.; Ruohoniemi, J. M.; Kitamura, N.; hide

    2016-01-01

    We present a case study of energetic ions observed by the Energetic Particle Detector (EPD) on the Magnetospheric Multiscale spacecraft in the magnetosheath just outside the subsolar magnetopause that occurred at 1000 UT on 8 December 2015. As the magnetopause receded inward, the EPD observed a burst of energetic (approximately 50-1000 keV) proton, helium, and oxygen ions that exhibited an inverse dispersion, with the lowest energy ions appearing first. The prolonged interval of fast antisunward flow observed in the magnetosheath and transient increases in the H components of global ground magnetograms demonstrate that the burst appeared at a time when the magnetosphere was rapidly compressed. We attribute the inverse energy dispersion to the leakage along reconnected magnetic field lines of betatron-accelerated energetic ions in the magnetosheath, and a burst of reconnection has an extent of about 1.5 R(sub E) using combined Super Dual Auroral Radar Network radar and EPD observations.

  5. Energetic Equipment in the Romanian Tisa Catchment Area

    Directory of Open Access Journals (Sweden)

    DINU ZAHARESCU

    2010-01-01

    Full Text Available The article presents the context of energetic equipment in the TICAD area, traditional and alternative sources of energy, and includes a short presentation and the possibilities of use for each of them

  6. An Interdisciplinary Approach to Dinosaur Fossils, Morphology, Ethology, and Energetics.

    Science.gov (United States)

    Zipko, Stephen J.

    1981-01-01

    Describes an interdisciplinary minicourse on dinosaur fossils, morphology, ethology, and energetics. Suggests and provides examples of hands-on activities for junior high school- through college-level students. (DS)

  7. Catalytic combustion in small wood burning appliances

    Energy Technology Data Exchange (ETDEWEB)

    Oravainen, H. [VTT Energy, Jyvaeskylae (Finland)

    1996-12-31

    There is over a million hand fired small heating appliances in Finland where about 5,4 million cubic meters of wood fuel is used. Combustion in such heating appliances is a batch-type process. In early stages of combustion when volatiles are burned, the formation of carbon monoxide (CO) and other combustible gases are difficult to avoid when using fuels that have high volatile matter content. Harmful emissions are formed mostly after each fuel adding but also during char burnout period. When the CO-content in flue gases is, say over 0.5 %, also other harmful emissions will be formed. Methane (CH{sub 4}) and other hydrocarbons are released and the amount of polycyclic aromatic hydrocarbons (PAH)-compounds can be remarkable. Some PAH-compounds are very carcinogenic. It has been estimated that in Finland even more than 90 % of hydrocarbon and PAH emissions are due to small scale wood combustion. Emissions from transportation is excluded from these figures. That is why wood combustion has a net effect on greenhouse gas phenomena. For example carbon monoxide emissions from small scale wood combustion are two fold compared to that of energy production in power plants. Methane emission is of the same order as emission from transportation and seven fold compared with those of energy production. Emissions from small heating appliances can be reduced by developing the combustion techniques, but also by using other means, for example catalytic converters. In certain stages of the batch combustion, temperature is not high enough, gas mixing is not good enough and residence time is too short for complete combustion. When placed to a suitable place inside a heating appliance, a catalytic converter can oxidize unburned gases in the flue gas into compounds that are not harmful to the environment. (3 refs.)

  8. Hybrid energy converter based on swirling combustion chambers: the hydrocarbon feeding analysis

    Directory of Open Access Journals (Sweden)

    Angelo Minotti

    2017-05-01

    Full Text Available This manuscript reports the latest investigations about a miniaturized hybrid energy power source, compatible with thermal/electrical conversion, by a thermo-photovoltaic cell, and potentially useful for civil and space applications. The converter is a thermally-conductive emitting parallelepiped element and the basic idea is to heat up its emitting surfaces by means of combustion, occurred in swirling chambers, integrated inside the device, and/or by the sun, which may work simultaneously or alternatively to the combustion. The current upgrades consist in examining whether the device might fulfill specific design constraints, adopting hydrocarbons-feeding. Previous papers, published by the author, demonstrate the hydrogen-feeding effectiveness. The project’s constraints are: 1 emitting surface dimensions fixed to 30 × 30 mm, 2 surface peak temperature T > 1000 K and the relative ∆T < 100 K (during the combustion mode, 3 the highest possible delivered power to the ambient, and 4 thermal efficiency greater than 20% when works with solar energy. To this end, a 5 connected swirling chambers configuration (3 mm of diameter, with 500 W of injected chemical power, stoichiometric conditions and detailed chemistry, has been adopted. Reactive numerical simulations show that the stiff methane chemical structure obliges to increase the operating pressure, up to 10 atm, and to add hydrogen, to the methane fuel injection, in order to obtain stable combustion and efficient energy conversion.

  9. Nanoscale device physics science and engineering fundamentals

    CERN Document Server

    Tiwari, Sandip

    2017-01-01

    Nanoscale devices are distinguishable from the larger microscale devices in their specific dependence on physical phenomena and effects that are central to their operation. The size change manifests itself through changes in importance of the phenomena and effects that become dominant and the changes in scale of underlying energetics and response. Examples of these include classical effects such as single electron effects, quantum effects such as the states accessible as well as their properties; ensemble effects ranging from consequences of the laws of numbers to changes in properties arising from different magnitudes of the inter-actions, and others. These interactions, with the limits placed on size, make not just electronic, but also magnetic, optical and mechanical behavior interesting, important and useful. Connecting these properties to the behavior of devices is the focus of this textbook. Description of the book series: This collection of four textbooks in the Electroscience series span the undergrad...

  10. Performance of Installed Cooking Exhaust Devices

    Energy Technology Data Exchange (ETDEWEB)

    Singer, Brett C.; Delp, William W.; Apte, Michael G.; Price, Philip N.

    2011-11-01

    The performance metrics of airflow, sound, and combustion product capture efficiency (CE) were measured for a convenience sample of fifteen cooking exhaust devices, as installed in residences. Results were analyzed to quantify the impact of various device- and installation-dependent parameters on CE. Measured maximum airflows were 70% or lower than values noted on product literature for 10 of the devices. Above-the-cooktop devices with flat bottom surfaces (no capture hood) – including exhaust fan/microwave combination appliances – were found to have much lower CE at similar flow rates, compared to devices with capture hoods. For almost all exhaust devices and especially for rear-mounted downdraft exhaust and microwaves, CE was substantially higher for back compared with front burner use. Flow rate, and the extent to which the exhaust device extends over the burners that are in use, also had a large effect on CE. A flow rate of 95 liters per second (200 cubic feet per minute) was necessary, but not sufficient, to attain capture efficiency in excess of 75% for the front burners. A-weighted sound levels in kitchens exceeded 57 dB when operating at the highest fan setting for all 14 devices evaluated for sound performance.

  11. Flammability characteristics of combustible gases and vapors

    Energy Technology Data Exchange (ETDEWEB)

    Zabetakis, M. G. [Bureau of Mines, Pittsburgh, PA (United States)

    1964-05-01

    This is a summary of the available limit of flammability, autoignition and burning-rate data for more than 200 combustible gases and vapors in air and other oxidants, as well as of empirical rules and graphs that can be used to predict similar data for thousands of other combustibles under a variety of environmental conditions. Spec$c data are presented on the paraffinic, unsaturated, aromatic, and alicyclic hydrocarbons, alcohols, ethers, aldehydes, ketones, and sulfur compounds, and an assortment of fuels, fuel blends, hydraulic fluids, engine oils, and miscellaneous combustible gases and vapors.

  12. Combustion temperature charts for industrial gaseous fuels

    Energy Technology Data Exchange (ETDEWEB)

    Matouskova, V.; Gerak, A.; Hlavacka, V.

    1975-12-01

    Researchers at Czechoslovakia's State Research Institute of Mechanical Engineering offer a method for calculating the theoretical flame temperature that includes the effect of endothermic reactions, especially the dissociation of combustion products. Charts presented for eight types of fuel gases can be used to determine the flame temperature relative to the temperature of the combustion air and to the excess-air ratio. Also considered is the relationship between these parameters and the characteristic temperature relationships for equipment using heat recovered from the flue gases to preheat incoming combustion air.

  13. Novel combustion concepts for sustainable energy development

    CERN Document Server

    Agarwal, Avinash K; Gupta, Ashwani K; Aggarwal, Suresh K; Kushari, Abhijit

    2014-01-01

    This book comprises research studies of novel work on combustion for sustainable energy development. It offers an insight into a few viable novel technologies for improved, efficient and sustainable utilization of combustion-based energy production using both fossil and bio fuels. Special emphasis is placed on micro-scale combustion systems that offer new challenges and opportunities. The book is divided into five sections, with chapters from 3-4 leading experts forming the core of each section. The book should prove useful to a variety of readers, including students, researchers, and professionals.

  14. 3rd International Conference on Numerical Combustion

    CERN Document Server

    Larrouturou, Bernard; Numerical Combustion

    1989-01-01

    Interest in numerical combustion is growing among applied mathematicians, physicists, chemists, engine manufacturers and many industrialists. This proceedings volume contains nine invited lectures and twenty seven contributions carefully selected by the editors. The major themes are numerical simulation of transsonic and supersonic combustion phenomena, the study of supersonic reacting mixing layers, and turbulent combustion. Emphasis is laid on hyperbolic models and on numerical simulations of hydrocarbon planes with a complete set of chemical reactions carried out in two-dimensional geometries as well as on complex reactive flow simulations.

  15. The John Zink Hamworthy combustion handbook

    CERN Document Server

    Baukal, Charles E

    2013-01-01

    Despite the length of time it has been around, its importance, and vast amounts of research, combustion is still far from being completely understood. Issues regarding the environment, cost, and fuel consumption add further complexity, particularly in the process and power generation industries. Dedicated to advancing the art and science of industrial combustion, The John Zink Hamworthy Combustion Handbook, Second Edition: Volume 3 - Applications offers comprehensive, up-to-date coverage of equipment used in the process and power generation industries. Under the leadership of Charles E. Baukal

  16. Annual Report: Advanced Combustion (30 September 2012)

    Energy Technology Data Exchange (ETDEWEB)

    Hawk, Jeffrey [NETL; Richards, George

    2012-09-30

    The Advanced Combustion Project addresses fundamental issues of fire-side and steam-side corrosion and materials performance in oxy-fuel combustion environments and provides an integrated approach into understanding the environmental and mechanical behavior such that environmental degradation can be ameliorated and long-term microstructural stability, and thus, mechanical performance can lead to longer lasting components and extended power plant life. The technical tasks of this effort are Oxy-combustion Environment Characterization, Alloy Modeling and Life Prediction, and Alloy Manufacturing and Process Development.

  17. Ameliorer les performances environnementales des centrales a charbon pulverise via la co-combustion de combustible derive de dechets

    Science.gov (United States)

    Vekemans, Odile Geraldine

    potential SO2 emissions reduction that could be obtain with ReEF(TM) co-combustion for a residence time and a temperature profile measured in an existing pulverized coal boiler. Those simulations indicate that SO2 emissions reduction up to 85% could be obtain at the exit of the furnace chamber with a 20%th coal feed substitution by ReEF(TM) containing limestone and trona. Co-combustion of ReEF(TM) in pulverized coal boiler is therefore sensible from the point of view of pulverized coal boiler environmental performances, as long as the ReEF(TM) composition is chosen wisely and is tested beforehand in conditions similar to that of PCB. Furthermore, since ReEF(TM) co-combustion allows electricity production at high efficiency from waste, it is also sensible in terms of waste energetic valorization.

  18. Cavitation Bubble Nucleation by Energetic Particles

    Energy Technology Data Exchange (ETDEWEB)

    West, C.D.

    1998-12-01

    In the early sixties, experimental measurements using a bubble chamber confirmed quantitatively the thermal spike theory of bubble nucleation by energetic particles: the energy of the slow, heavy alpha decay recoils used in those experiments matched the calculated bubble nucleation energy to within a few percent. It was a triumph, but was soon to be followed by a puzzle. Within a couple of years, experiments on similar liquids, but well below their normal boiling points, placed under tensile stress showed that the calculated bubble nucleation energy was an order of magnitude less than the recoil energy. Why should the theory work so well in the one case and so badly in the other? How did the liquid, or the recoil particle, "know" the difference between the two experiments? Another mathematical model of the same physical process, introduced in 1967, showed qualitatively why different analyses would be needed for liquids with high and low vapor pressures under positive or negative pressures. But, the quantitative agreement between the calculated nucleation energy and the recoil energy was still poor--the former being smaller by a factor of two to three. In this report, the 1967 analysis is extended and refined: the qualitative understanding of the difference between positive and negative pressure nucleation, "boiling" and "cavitation" respectively, is retained, and agreement between the negative pressure calculated to be needed for nucleation and the energy calculated to be available is much improved. A plot of the calculated negative pressure needed to induce bubble formation against the measured value now has a slope of 1.0, although there is still considerable scatter in the individual points.

  19. Detonation Shock Dynamics of Composite Energetic Materials.

    Science.gov (United States)

    Lee, Jaimin

    1990-01-01

    A reaction-rate equation for a composite energetic material was calibrated from two-dimensional steady-state experiment data by using the detonation shock dynamics theory. From experimental detonation velocities and shock -front shapes at different diameters for an ammonium nitrate -based emulsion explosive at 1.248 g/cm^3, the relationship between the detonation velocity normal to the shock-front and the shock-front curvature was obtained. By using this relationship and solving the quasi one-dimensional Euler equations of motion in a problem -conforming intrinsic-coordinate frame obtained from the detonation shock dynamics theory, the reaction rate was determined as a function of pressure and density: {dlambdaover dt} = 20.0 times 10^6 {rm exp}({-}14390/ sqrt{P/rho^{0.8418}})(1 - lambda)^{1.889}where lambda is the reaction extent, t is the time in s, P is the pressure in Pa, and rho is the density in kg/m^3 . The reaction-rate equation obtained for this emulsion explosive shows that the rate is very slow and weakly state dependent. These characteristics of the rate indicated that the nonideal behavior of most industrial-type explosives can be attributed to their slow and state-insensitive rates. By using the above rate equation, one-dimensional initiation experiments (wedge tests) were numerically modeled with a one-dimensional Lagrangian hydrodynamic code. The calculated shock trajectories agreed very well with experimental wedge test data. This agreement also suggested that the small shock-curvature asymptotics may be valid even for a relatively large value of the curvature. The calibration method developed in this study is independent of the form of the rate. Realistic rate equations for explosives can be obtained in a very systematic way from two-dimensional steady-state experiments.

  20. Energetics of metamorphosis in Drosophila melanogaster.

    Science.gov (United States)

    Merkey, Allison B; Wong, Carrie K; Hoshizaki, Deborah K; Gibbs, Allen G

    2011-10-01

    We measured the energetic cost of metamorphosis in the fruitfly, Drosophila melanogaster. Metabolic rates decreased rapidly in the first 24h and remained low until shortly before eclosion, when the rates increased rapidly, thus creating a U-shaped metabolic curve. The primary fuel used during metamorphosis was lipid, which accounted for >80% of total metabolism. The total energy consumed during metamorphosis was lowest at 25°C, compared to 18 and 29°C, due to differences in metabolic rates and the length of pupal development. Temperature differentially affected metabolic rates during different stages of metamorphosis. Prepupal and late pupal stages exhibited typical increases in metabolic rate at high temperatures, whereas metabolic rates were independent of temperature during the first 2/3 of pupal development. We tested two hypotheses for the underlying cause of the U-shaped metabolic curve. The first hypothesis was that pupae become oxygen restricted as a result of remodeling of the larval tracheal system. We tested this hypothesis by exposing pupae to hypoxic and hyperoxic atmospheres, and by measuring lactic acid production during normoxic development. No evidence for oxygen limitation was observed. We also tested the hypothesis that the U-shaped metabolic curve follows changes in metabolically active tissue, such that the early decrease in metabolic rates reflects the histolysis of larval tissues, and the later increase in metabolic rates is associated with organogenesis and terminal differentiation of adult tissues. We assayed the activity of a mitochondrial indicator enzyme, citrate synthase, and correlated it with tissue-specific developmental events during metamorphosis. Citrate synthase activity exhibited a U-shaped curve, suggesting that the pattern of metabolic activity is related to changes in the amount of potentially active aerobic tissue. Copyright © 2011 Elsevier Ltd. All rights reserved.

  1. Inferring crossbridge properties from skeletal muscle energetics.

    Science.gov (United States)

    Barclay, C J; Woledge, R C; Curtin, N A

    2010-01-01

    Work is generated in muscle by myosin crossbridges during their interaction with the actin filament. The energy from which the work is produced is the free energy change of ATP hydrolysis and efficiency quantifies the fraction of the energy supplied that is converted into work. The purpose of this review is to compare the efficiency of frog skeletal muscle determined from measurements of work output and either heat production or chemical breakdown with the work produced per crossbridge cycle predicted on the basis of the mechanical responses of contracting muscle to rapid length perturbations. We review the literature to establish the likely maximum crossbridge efficiency for frog skeletal muscle (0.4) and, using this value, calculate the maximum work a crossbridge can perform in a single attachment to actin (33 x 10(-21) J). To see whether this amount of work is consistent with our understanding of crossbridge mechanics, we examine measurements of the force responses of frog muscle to fast length perturbations and, taking account of filament compliance, determine the crossbridge force-extension relationship and the velocity dependences of the fraction of crossbridges attached and average crossbridge strain. These data are used in combination with a Huxley-Simmons-type model of the thermodynamics of the attached crossbridge to determine whether this type of model can adequately account for the observed muscle efficiency. Although it is apparent that there are still deficiencies in our understanding of how to accurately model some aspects of ensemble crossbridge behaviour, this comparison shows that crossbridge energetics are consistent with known crossbridge properties.

  2. The Cosmic Ray Energetics And Mass Project

    Science.gov (United States)

    Seo, Eun-Suk; Iss-Cream Collaboration

    2017-01-01

    The balloon-borne Cosmic Ray Energetics And Mass (CREAM) experiment was flown for 161 days in six flights over Antarctica, the longest known exposure for a single balloon project. Elemental spectra were measured for Z = 1- 26 nuclei over a wide energy range from 1010 to >1014 eV. Building on the success of those balloon flights, one of the two balloon payloads was transformed for exposure on the International Space Station (ISS) Japanese Experiment Module Exposed Facility (JEM-EF). This ISS-CREAM instrument is configured with redundant and complementary particle detectors. The four layers of its finely segmented Silicon Charge Detector provide precise charge measurements, and its ionization calorimeter provides energy measurements. In addition, scintillator-based Top and Bottom Counting Detectors and the Boronated Scintillator Detector distinguish electrons from nuclei. An order of magnitude increase in data collecting power is expected to reach the highest energies practical with direct measurements. Following completion of its qualification tests at NASA Goddard Space Flight Center, the ISS-CREAM payload was delivered to NASA Kennedy Space Center in August 2015 to await its launch to the ISS. While waiting for ISS-CREAM to launch, the other balloon payload including a Transition Radiation Detector, which is too large for the JEM-EF envelope, has been prepared for another Antarctic balloon flight in 2016. This so-called Boron And Carbon Cosmic rays in the Upper Stratosphere (BACCUS) payload will investigate cosmic ray propagation history. The overall project status and future plans will be presented.

  3. Energetic and spatial constraints of arterial networks

    Directory of Open Access Journals (Sweden)

    Sandro Rossitti

    1995-06-01

    Full Text Available The principle of minimum work (PMW is a parametric optimization model for the growth and adaptation of arterial trees. A balance between energy dissipation due to frictional resistance of laminar flow (shear stress and the minimum volume of the blood and vessel wall tissue is achieved when the vessel radii are adjusted to the cube root of the volumetric flow. The PMW is known to apply over several magnitudes of vessel calibers, and in many different organs, including the brain, in humans and in animals. Animal studies suggest that blood flow in arteries is approximately proportional to the cube of the vessel radius, and that arteries alter their caliber in response to sustained changes of blood flow according to PMW. Remodelling of the retinal arteriolar network to long-term changes in blood flow was observed in humans. Remodelling of whole arterial networks occurs in the form of increase or diminishing of vessel calibers. Shear stress induced endothelial mediation seems to be the regulating mechanism for the maintenance of this optimum blood flow/vessel diameter relation. Arterial trees are also expected to be nearly space filing. The vascular system is constructed in such a way that, while blood vessels occupy only a small percentage of the body volume leaving the bulk to tissue, they also crisscross organs so tightly that every point in the tissue lies on the boundary between an artery and a vein. This review describes how the energetic optimum principle for least energy cost for blood flow is also compatible with the spatial constraints of arterial networks according to concepts derived from fractal geometry.

  4. Energetic aspects of boring tools wear

    Directory of Open Access Journals (Sweden)

    Lazarová Edita

    2002-03-01

    Full Text Available In the process of rock desintegration a boring tool is subjected to the wear. From a viewpoint of the bit wear, changes on the contact of operating tool with rock at its one-shot and rerun load or overload by external forces are technically significant. Theis change results in the degradation of bit working properties and the output of desintegration also decreases. In the major part of cases, together with the bit wear, the contact area of a tool with a rock massifs enhanced and this fact causes an increase of fines (dust creation during the desintegration. The wear is always connected with a friction, forces action, deformation, damage, and the increased mechanical work consumption. As to energetic aspects of bit wear, the wear was observed as a function of bore length and in the most of cases as a dependence of the operating time. A linear dependence between the wear intensity (bit wear per unit of bore length and the specific energy of desintegration (energy consumed per volume unit of desintegrated rock was experimentally verified. Thus, the changes of bit wear can be implicitly observed by monitoring the specific energy. At the same time, the specific energy is a function of input parameters of the desintegration process and in the field of applicable external forces it shows an extreme (minimum. Therefore, the specific energy is useful for the extreme optimisation of the rock desintegration process from the viewpoint of the bit wear. It was mathematically proven that the tool output at the desintegration exponentially decreases with the amount of work consumed in the rock desintegration. The derivation of this knowledge comes out from the Krendelev equation.

  5. Coal Combustion Science quarterly progress report, April--June 1990

    Energy Technology Data Exchange (ETDEWEB)

    Hardesty, D.R. (ed.); Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01

    This document provides a quarterly status report of the Coal Combustion Science Program that is being conducted at the Combustion, Research Facility, Sandia National Laboratories, Livermore, California. Coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 56 refs., 25 figs., 13 tabs.

  6. Numerical modeling of straw combustion in a fixed bed

    DEFF Research Database (Denmark)

    Zhou, Haosheng; Jensen, Anker; Glarborg, Peter

    2005-01-01

    . The straw combustion processes include moisture evaporation, straw pyrolysis, gas combustion, and char combustion. The model provides detailed information of the structure of the ignition flame front. Simulated gas species concentrations at the bed surface, ignition flame front rate, and bed temperature...... packing condition, and heat capacity of the straw have considerable effects on the model predictions of straw combustion in the fixed bed....

  7. Key factors of combustion from kinetics to gas dynamics

    CERN Document Server

    Rubtsov, Nikolai M

    2017-01-01

    This book summarizes the main advances in the mechanisms of combustion processes. It focuses on the analysis of kinetic mechanisms of gas combustion processes and experimental investigation into the interrelation of kinetics and gas dynamics in gas combustion. The book is complimentary to the one previously published, The Modes of Gaseous Combustion.

  8. I. c. engine fuel treatment device

    Energy Technology Data Exchange (ETDEWEB)

    Deadman, L.L.F.; Deadman, J.E.

    1992-04-29

    This invention consists of devices incorporating a magnet in close proximity to a ferrous metal core on which is wound in physical contact a coil of wire consisting essentially of tin, or tin in conjunction with other specified metals. The effect is enhanced by enclosing the devices in a case containing metal dissimilar to the other metals present. The devices provide an array of magnetic, electro-chemical and catalytic processes, which singly or in combination, enable unleaded fuels to be used instead of leaded fuels without substantial modification to the ignition timing or valve metallurgy of the engine and may be inserted into the fuel line, used to treat fuel in bulk, or be incorporated into the carburettor or other metering mechanism. It is a further feature that the devices promote the more complete combustion of internal combustion engine fuels, whether of the ''petrol'' variety or the ''diesel'' variety, thus increasing the distance travelled from a given amount of fuel and reducing the emission of unoxidised fuel. (Author).

  9. Physical properties, evaporation and combustion characteristics of nanofluid-type fuels

    Science.gov (United States)

    Tanvir, Saad

    Nanofluids are liquids with stable suspension of nanoparticles. Limited studies in the past have shown that both energetic and catalytic nanoparticles once mixed with traditional liquid fuels can be advantageous in combustion applications, e.g., increased energy density and shortened ignition delay. Contradictions in existing literature, scarcity of experimental data and lack of understanding on how the added nanoparticles affect the physical properties as well as combustion characteristics of the resulting fuel motivated us to launch a detailed experimental and theoretical investigation. The surface tension of ethanol and n-decane based nanofluid fuels containing suspended nanoparticles were measured using the pendant drop method by solving the Young-Laplace equation. The results show that surface tension increases both with particle concentration (above a critical concentration) and particle size. This is because the Van der Waals forces between particles at the liquid/gas interface increases surface free energy that overcomes any electrostatic repulsion between the particles and increases surface tension. This present work also reports experimental analysis of the latent heat of vaporization ( Hfg) of nanofluids. Results show that the addition of Ag and Fe nanoparticles in water results is a substantial reduction in Hfg. On the contrary Al addition slightly increases Hfg. Similar observations are made for ethanol based nanofluids. Molecular dynamics simulations showed that the strength of bonding between particles and the fluid molecules is the governing factor in the variation of Hfg upon particle addition. The thermal conductivity was measured using KD2-Pro from Decagon Devices based on the transient line heat source method. The rheological properties of the ethanol and ethanol/nanoparticles suspensions are measured using a StresstechRTM rotational rheometer. Both properties increased with increasing particle concentration. Trends are found to be consistent

  10. A study of the current group evaporation/combustion theories

    Science.gov (United States)

    Shen, Hayley H.

    1990-01-01

    Liquid fuel combustion can be greatly enhanced by disintegrating the liquid fuel into droplets, an effect achieved by various configurations. A number of experiments carried out in the seventies showed that combustion of droplet arrays and sprays do not form individual flames. Moreover, the rate of burning in spray combustion greatly deviates from that of the single combustion rate. Such observations naturally challenge its applicability to spray combustion. A number of mathematical models were developed to evaluate 'group combustion' and the related 'group evaporation' phenomena. This study investigates the similarity and difference of these models and their applicability to spray combustion. Future work that should be carried out in this area is indicated.

  11. Energetic mapping of oxide traps in MoS2 field-effect transistors

    Science.gov (United States)

    Illarionov, Yury Yu; Knobloch, Theresia; Waltl, Michael; Rzepa, Gerhard; Pospischil, Andreas; Polyushkin, Dmitry K.; Furchi, Marco M.; Mueller, Thomas; Grasser, Tibor

    2017-06-01

    The performance of MoS2 transistors is strongly affected by charge trapping in oxide traps with very broad distributions of time constants. These defects degrade the mobility and additionally lead to the hysteresis of the gate transfer characteristics, which presents a crucial performance and reliability issue for these new technologies. Here we perform a detailed study of the hysteresis in double-gated MoS2 FETs and show that this issue is nothing else than a combination of threshold voltage shifts resulting from positive and negative bias-temperature instabilities. While these instabilities are well known from silicon devices, they are even more important in 2D devices given the considerably larger defect densities. Most importantly, the magnitudes of these threshold voltage shifts depend strongly on the density and energetic alignment of the active oxide traps. Based on this, we introduce the incremental hysteresis sweep method which allows for an accurate mapping of these defects and extract their energy distributions from simulations. By applying our method to analyze the impact of oxide traps situated in the Al2O3 top gate of several devices, we confirm its versatility. Since all 2D devices investigated so far suffer from a similar hysteresis behavior, the incremental hysteresis sweep method provides a unique and powerful way for the detailed characterization of their defect bands.

  12. Kinetics of coal combustion: Part 2, Mechanisms and kinetics of coal volatiles combustion

    Energy Technology Data Exchange (ETDEWEB)

    Gat, N.; Wolff, M. F.; Petach, M. B. [TRW Space and Technology Group, Redondo Beach, CA (USA)

    1988-12-01

    Presently very little is known about the combustion characteristics of mixtures of hydrocarbon fuels. Even less is known about the combustion of coal volatiles which are complex mixtures of light and high molecular weight hydrocarbons. This issue pertains not only to coal volatiles but also to the combustion of synthetic fuels, liquefaction and coal gasification products. The subject in general has been given very little attention in the literature. As a consequence, current modeling methods are based on assumptions which are not thoroughly validated and verified. The current investigation addressed this very problem of the combustion of mixtures of hydrocarbon fuels. 29 refs., 35 figs., 5 tabs.

  13. DIAGNOSIS OF FAILURE OF COMBUSTION IN THE COMBUSTION CHAMBER WITH A THERMOVISION EQUIPMENT

    Directory of Open Access Journals (Sweden)

    S. V. Vorobiev

    2014-01-01

    Full Text Available The use of thermovision technology to diagnose failure of the combustion flame test tube of the main combustion chamber gas turbine engine is deal with in the article. Join the thermal radiation of the jet of combustion products and the internal elements was carried out using short-wave thermovision system AGA-782 with spectral spectral filters in several ranges from 3.2 to 5.6 microns. Thermovision is mounted on the axis of the flame tube. The output signal was recorded and processed on a computer in real time, allowing monitor the combustion process and the thermal state of the object during the experiment.

  14. Scalable devices

    KAUST Repository

    Krüger, Jens J.

    2014-01-01

    In computer science in general and in particular the field of high performance computing and supercomputing the term scalable plays an important role. It indicates that a piece of hardware, a concept, an algorithm, or an entire system scales with the size of the problem, i.e., it can not only be used in a very specific setting but it\\'s applicable for a wide range of problems. From small scenarios to possibly very large settings. In this spirit, there exist a number of fixed areas of research on scalability. There are works on scalable algorithms, scalable architectures but what are scalable devices? In the context of this chapter, we are interested in a whole range of display devices, ranging from small scale hardware such as tablet computers, pads, smart-phones etc. up to large tiled display walls. What interests us mostly is not so much the hardware setup but mostly the visualization algorithms behind these display systems that scale from your average smart phone up to the largest gigapixel display walls.

  15. Coal Combustion Products Extension Program

    Energy Technology Data Exchange (ETDEWEB)

    Tarunjit S. Butalia; William E. Wolfe

    2006-01-11

    This final project report presents the activities and accomplishments of the ''Coal Combustion Products Extension Program'' conducted at The Ohio State University from August 1, 2000 to June 30, 2005 to advance the beneficial uses of coal combustion products (CCPs) in highway and construction, mine reclamation, agricultural, and manufacturing sectors. The objective of this technology transfer/research program at The Ohio State University was to promote the increased use of Ohio CCPs (fly ash, FGD material, bottom ash, and boiler slag) in applications that are technically sound, environmentally benign, and commercially competitive. The project objective was accomplished by housing the CCP Extension Program within The Ohio State University College of Engineering with support from the university Extension Service and The Ohio State University Research Foundation. Dr. Tarunjit S. Butalia, an internationally reputed CCP expert and registered professional engineer, was the program coordinator. The program coordinator acted as liaison among CCP stakeholders in the state, produced information sheets, provided expertise in the field to those who desired it, sponsored and co-sponsored seminars, meetings, and speaking at these events, and generally worked to promote knowledge about the productive and proper application of CCPs as useful raw materials. The major accomplishments of the program were: (1) Increase in FGD material utilization rate from 8% in 1997 to more than 20% in 2005, and an increase in overall CCP utilization rate of 21% in 1997 to just under 30% in 2005 for the State of Ohio. (2) Recognition as a ''voice of trust'' among Ohio and national CCP stakeholders (particularly regulatory agencies). (3) Establishment of a national and international reputation, especially for the use of FGD materials and fly ash in construction applications. It is recommended that to increase Ohio's CCP utilization rate from 30% in 2005 to

  16. Danish emission inventories for stationary combustion plants

    DEFF Research Database (Denmark)

    Nielsen, Malene; Nielsen, Ole-Kenneth; Plejdrup, Marlene Schmidt

    Emission inventories for stationary combustion plants are presented and the methodologies and assumptions used for the inventories are described. The pollutants considered are SO2, NOx, NMVOC, CH4, CO, CO2, N2O, particulate matter, heavy metals, dioxins, HCB and PAH. The CO2 emission in 2007 was 10...... incineration plants. The combustion of wood in residential plants has increased considerably in recent years resulting in increased emission of PAH, particulate matter and CO. The emission of NMVOC has increased since 1990 as a result of both the increased combustion of wood in residential plants...... and the increased emission from lean-burn gas engines. The dioxin emission decreased since 1990 due to flue gas cleaning on waste incineration plants. However in recent years the emission has increased as a result of the increased combustion of wood in residential plants....

  17. Danish emission inventories for stationary combustion plants

    DEFF Research Database (Denmark)

    Nielsen, Malene; Nielsen, Ole-Kenneth; Plejdrup, Marlene Schmidt

    Emission inventories for stationary combustion plants are presented and the methodologies and assumptions used for the inventories are described. The pollutants considered are SO2, NOx, NMVOC, CH4, CO, CO2, N2O, NH3, particulate matter, heavy metals, dioxins, HCB and PAH. The CO2 emission in 2008...... incineration plants. The combustion of wood in residential plants has increased considerably in recent years resulting in increased emission of PAH, particulate matter and CO. The emission of NMVOC has increased since 1990 as a result of both the increased combustion of wood in residential plants...... and the increased emission from lean-burn gas engines. The dioxin emission decreased since 1990 due to flue gas cleaning on waste incineration plants. However in recent years the emission has increased as a result of the increased combustion of wood in residential plants....

  18. Fuels Combustion Research: Supercritical Fuel Pyrolysis

    National Research Council Canada - National Science Library

    Glassman, Irvin

    2000-01-01

    .... The focus during the subject period was directed to understanding the pyrolysis and combustion of endothermic fuels under subcritical conditions and the pyrolysis of these fuels under supercritical conditions...

  19. Fuels Combustion Research: Supercritical Fuel Pyrolysis

    National Research Council Canada - National Science Library

    Glassman, Irvin

    2001-01-01

    .... The focus during the subject period was directed to understanding the pyrolysis and combustion of endothermic fuels under subcritical conditions and the pyrolysis of these fuels under supercritical conditions...

  20. Combustion properties of Kraft Black Liquors

    Energy Technology Data Exchange (ETDEWEB)

    Frederick, W.J. Jr.; Hupa, M. (Aabo Akademi, Turku (Finland))

    1993-04-01

    In a previous study of the phenomena involved in the combustion of black liquor droplets a numerical model was developed. The model required certain black liquor specific combustion information which was then not currently available, and additional data were needed for evaluating the model. The overall objectives of the project reported here was to provide experimental data on key aspects of black liquor combustion, to interpret the data, and to put it into a form which would be useful for computational models for recovery boilers. The specific topics to be investigated were the volatiles and char carbon yields from pyrolysis of single black liquor droplets; a criterion for the onset of devolatilization and the accompanying rapid swelling; and the surface temperature of black liquor droplets during pyrolysis, combustion, and gasification. Additional information on the swelling characteristics of black liquor droplets was also obtained as part of the experiments conducted.