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Sample records for end-groups ii ir

  1. Redesign of the End Group in the 3.9 GHz LCLS-II Cavity

    Energy Technology Data Exchange (ETDEWEB)

    Lunin, Andrei [Fermilab; Gonin, Ivan [Fermilab; Khabiboulline, Timergali [Fermilab; Solyak, Nikolay [Fermilab

    2017-05-01

    Development and production of Linac Coherent Light Source II (LCLS-II) is underway. The central part of LCLS-II is a continuous wave superconducting RF (CW SCRF) electron linac. The 3.9 GHz third harmonic cavity similar to the XFEL design will be used in LCLS-II for linearizing the longitudinal beam profile*. The initial design of the 3.9 GHz cavity developed for XFEL project has a large, 40 mm, beam pipe aperture for better higher-order mode (HOM) damping. It is resulted in dipole HOMs with frequencies nearby the operating mode, which causes difficulties with HOM coupler notch filter tuning. The CW linac operation requires an extra caution in the design of the HOM coupler in order to prevent its possible overheating. In this paper we present the modified 3.9 GHz cavity End Group for meeting the LCLS-II requirements

  2. Fourier Transform Infrared Spectroscopy: Part II. Advantages of FT-IR.

    Science.gov (United States)

    Perkins, W. D.

    1987-01-01

    This is Part II in a series on Fourier transform infrared spectroscopy (FT-IR). Described are various advantages of FT-IR spectroscopy including energy advantages, wavenumber accuracy, constant resolution, polarization effects, and stepping at grating changes. (RH)

  3. Metal-Mesh Optical Filter Technology for Mid IR, Far IR, and Submillimeter, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — The innovative, high transmission band-pass filter technology proposed here is an improvement in multilayer metal-mesh filter design and manufacture for the far IR...

  4. Proposal of LDR Ir-192 Production in the TRIGA Mark II Research Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Karimzadeh, S.; Khan, R.; Boeck, H., E-mail: Sam.karimzadeh@ati.ac.a, E-mail: Nrustam@ati.ac.a, E-mail: Boeck@ati.ac.a [Institute of Atomic and Subatomic Physics (ATI), Vienna University of Technology (TU-Vienna) Stadionallee 2, 1020-Vienna (Austria)

    2011-07-01

    The TRIGA MARK II research reactor in Vienna provides some irradiation positions with different flux distribution. In this regard, a case study is under investigation to appraise the possibility of medical radioisotope production in Vienna. For this purpose, neutron flux mapping and the axial neutron flux distribution are calculated by MCNP5 for the TRIGA Mark II core. This paper describes the feasibility of Low Dose Rate (LDR) {sup 192}Ir production in the core of the low power research reactor. (author)

  5. IR and UV-visible spectra of iron(II) phthalocyanine complexes with ...

    African Journals Online (AJOL)

    In the IR spectra, the position of the νFeN4 band is linked to the coordination number; in the spectra of pentacoordinated complexes, its frequency is almost the same as that in the FePc spectrum but in hexacoordinated complexes, it moves to high frequencies. KEY WORDS: Iron(II) phthalocyanine complexes, Phosphine, ...

  6. Characterization of dioxygenated cobalt(II)-carnosine complexes by Raman and IR spectroscopy.

    Science.gov (United States)

    Torreggiani, A; Taddei, P; Fini, G

    2002-01-01

    Raman and IR studies are carried out on carnosine (beta-alanyl-L-histidine, Carnos) and its complexes with cobalt(II) at different metal/ligand ratios and basic pH. Binuclear complexes that bind molecular oxygen are formed and information regarding the O-O bridge is obtained from the Raman spectra. When the Co(II)/Carnos ratio is complexes are the predominant species and two forms (monobridged and dibridged) are identified by the presence of two Raman peaks in the nuO-O region (750-850 cm(-1)). These peroxo complexes can be oxidized to yield a superoxo complex when the metal slightly exceeds the Carnos concentration, and there are consequent shifts of the nuO-O band to higher wavenumbers. In addition, the chelated species in the 2 : 1 Co(II)/Carnos system is found to bind oxygen to a lesser degree. With respect to the coordination sites, each Co(II) ion of the binuclear dioxygenated complexes is bound to one oxygen atom and four nitrogen atoms: N(pi) and N(tau) of two Carnos molecules, the peptide, and the terminal amino nitrogen atoms. Conversely, when the metal/ligand ratio is 2, in addition to the dioxygenated complexes, a complex is formed in which the imidazole moiety of Carnos binds two different cobalt ions because the N(pi) and N(tau) nitrogens are both deprotonated. Copyright 2002 John Wiley & Sons, Inc.

  7. Separation of rare earths by ion exchange method: ion retainer Zn (II) and Cu (II) and Dowex-50 X-4 and Amberlite IR-120 resins

    International Nuclear Information System (INIS)

    Pavanin, L.A.; Tfouni, E.; Serra, O.A.

    1982-01-01

    The separation of rare earths from Brazilian monazite by ion exchange method is presented. The performance of Dowex-50 X-4 (50 to 100 mesh) and Amberlite IR-120 (20-30 mesh) and Cu (II) and Zn (II) is compared. (A.R.H.) [pt

  8. IR Up Grade Plans for the PEP-II B-Factory

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, M.

    2004-07-07

    PEP-II, the SLAC, LBNL, LLNL B-factory has achieved a peak luminosity of over 9 x 10{sup 33} cm{sup -2}s{sup -1}, more than 3 times the design luminosity, and plans to obtain a luminosity of over 1 x 10{sup 34} cm{sup -2} sec{sup -1} in the next year. In order to push the luminosity performance of PEP-II to even higher levels an upgrade to the interaction region (IR) is being designed. In the present design, the interaction point (IP) is a head-on collision with two strong horizontal dipole magnets located between 21-70 cm from the IP that bring the beams together and separate the beams after the collision. The first parasitic crossing (PC) is 63 cm from the IP in the present by2 bunch spacing. Future improvements to PEP-II performance include lowering the {beta}*{sub y} values of both rings. This will increase the {beta}{sub y} value at the PCs which increases the beam-beam effect at these non-colliding crossings. Introducing a horizontal crossing angle at the IP quickly increases the beam separation at the PCs but recent beam-beam studies indicate that a significant luminosity reduction occurs when a crossing angle is introduced at the IP. We discuss these issues and describe the present interaction region upgrade design.

  9. Spectroscopic (FT-IR, FT-Raman, 1H, 13C NMR, UV/VIS), thermogravimetric and antimicrobial studies of Ca(II), Mn(II), Cu(II), Zn(II) and Cd(II) complexes of ferulic acid

    Science.gov (United States)

    Kalinowska, M.; Piekut, J.; Bruss, A.; Follet, C.; Sienkiewicz-Gromiuk, J.; Świsłocka, R.; Rzączyńska, Z.; Lewandowski, W.

    2014-03-01

    The molecular structure of Mn(II), Cu(II), Zn(II), Cd(II) and Ca(II) ferulates (4-hydroxy-3-methoxycinnamates) was studied. The selected metal ferulates were synthesized. Their composition was established by means of elementary and thermogravimetric analysis. The following spectroscopic methods were used: infrared (FT-IR), Raman (FT-Raman), nuclear magnetic resonance (13C, 1H NMR) and ultraviolet-visible (UV/VIS). On the basis of obtained results the electronic charge distribution in studied metal complexes in comparison with ferulic acid molecule was discussed. The microbiological study of ferulic acid and ferulates toward Escherichia coli, Bacillus subtilis, Candida albicans, Pseudomonas aeruginosa, Staphylococcus aureus and Proteus vulgaris was done.

  10. Quantum-chemical, NMR, FT IR, and ESI MS studies of complexes of colchicine with Zn(II).

    Science.gov (United States)

    Jankowski, Wojciech; Kurek, Joanna; Barczyński, Piotr; Hoffmann, Marcin

    2017-04-01

    Colchicine is a tropolone alkaloid from Colchicinum autumnale. It shows antifibrotic, antimitotic, and anti-inflammatory activities, and is used to treat gout and Mediterranean fever. In this work, complexes of colchicine with zinc(II) nitrate were synthesized and investigated using DFT, 1 H and 13 C NMR, FT IR, and ESI MS. The counterpoise-corrected and uncorrected interaction energies of these complexes were calculated. We also calculated their 1 H, 13 C NMR, and IR spectra and compared them with the corresponding experimentally obtained data. According to the ESI MS mass spectra, colchicine forms stable complexes with zinc(II) nitrate that have various stoichiometries: 2:1, 1:1:1, and 2:1:1 with respect to colchichine, Zn(II), and nitrate ion. All of the complexes were investigated using the quantum theory of atoms in molecules (QTAIM). The calculated and the measured spectra showed differences before and after the complexation process. Calculated electron densities and bond critical points indicated the presence of bonds between the ligands and the central cation in the investigated complexes that satisfied the quantum theory of atoms in molecules. Graphical Abstract DFT, NMR, FT IR, ESI MS, QTAIM and puckering studies of complexes of colchicine with Zn(II).

  11. One-Dimensional Tunable Photonic-Crystal IR Filter, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — MetroLaser proposes to design and develop an innovative narrowband tunable IR filter based on the properties of a one-dimensional photonic crystal structure with a...

  12. Observations of the Ca II IR Triplet in High Luminosity Quasars ...

    Indian Academy of Sciences (India)

    supplement the sample presented by Martínez-Aldama et al. (2015) – allow us to confirm the constraints on physical conditions and location of the region emitting the low ionization lines, as well as the relation between. Ca II and Fe II. Key words. Quasars: general—quasars: emission lines—lines: profiles— star formation. 1.

  13. Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba4Ni2Ir2O12 Containing Ir2NiO12 Mixed-Metal-Cation Trimers.

    Science.gov (United States)

    Ferreira, Timothy; Heald, Steve M; Smith, Mark D; Zur Loye, Hans-Conrad

    2018-03-19

    The crystal chemistry and magnetic properties of two hexagonal nickel(IV)-containing perovskites, Ba 4 Ni 1.94 Ir 2.06 O 12 and BaNiO 3 , are reported. The 12R perovskite, Ba 4 Ni 1.94 Ir 2.06 O 12 , possesses an unexpected coexistence of nickel(II) and nickel(IV). This quadruple perovskite structure contains Ir 2 NiO 12 mixed-metal-cation units in which direct metal-metal bonding between nickel(IV) and iridium(V) is inferred. X-ray absorption near-edge spectroscopy and X-ray photoelectron spectroscopy measurements were conducted to confirm the simultaneous presence of nickel(II) and nickel(IV).

  14. Near-IR search for lensed supernovae behind galaxy clusters. II. First detection and future prospects

    OpenAIRE

    Goobar, A.; Paech, K.; Stanishev, V.; Amanullah, R.; Dahlén, T.; Jönsson, J.; Kneib, J. P.; Lidman, C.; Limousin, M.; Mörtsell, E.; Nobili, S.; Richard, J.; Riehm, T.; von Strauss, M.

    2009-01-01

    Aims. Powerful gravitational telescopes in the form of massive galaxy clusters can be used to enhance the light collecting power over a limited field of view by about an order of magnitude in flux. This effect is exploited here to increase the depth of a survey for lensed supernovae at near-IR wavelengths. Methods. We present a pilot supernova search programme conducted with the ISAAC camera at VLT. Lensed galaxies behind the massive clusters A1689, A1835, and AC114 were observed for a tot...

  15. Expression of IGF‐I, IGF‐II, and IGF‐IR in gallbladder carcinoma. A systematic analysis including primary and corresponding metastatic tumours

    Science.gov (United States)

    Kornprat, P; Rehak, P; Rüschoff, J; Langner, C

    2006-01-01

    Aims The insulin‐like growth factor (IGF) system has been implicated in tumour development and progression. This study was designed to analyse the expression of the IGF‐I receptor (IGF‐IR) and its ligands (IGF‐I, IGF‐II) in gallbladder cancer. Methods IGF‐I, IGF‐II, and IGF‐IR immunoreactivity was investigated in 57 gallbladder carcinomas and corresponding lymph node (n  =  11) and hepatic (n  =  7) metastases using a tissue microarray technique and correlated with tumour stage, grade, and patient outcome. Results Cancer tissue allowing a reliable evaluation of IGF‐I, IGF‐II, and IGF‐IR was present in 55 of 57 primary tumours and 17 of 18 metastases. IGF‐I and IGF‐II immunoreactivity was seen in 25 and 14 of the 55 primary tumours, in addition to six and three of the 17 metastases, respectively. No associations with tumour stage, grade, or prognosis were detected. IGF‐IR was expressed in 52 of 55 primary tumours and all 17 metastases. IGF‐IR staining intensity decreased with tumour cell dedifferentiation. Moreover, IGF‐IR expression in less than 50% of cancer cells was an independent marker of poor prognosis in multivariate analysis (risk ratio, 4.0; 95% confidence interval, 1.4 to 11.2; p  =  0.01). Conclusions The expression of IGF‐IR and its ligands provides evidence for the existence of an auto/paracrine loop of tumour cell stimulation in gallbladder cancer and makes this type of cancer a candidate for therapeutic strategies aimed at interfering with the IGF pathway. The recognition of IGF‐IR as a new independent prognostic biomarker may help to identify patients who might benefit from adjuvant treatment. PMID:16443739

  16. Multicolor (UV-IR) Photodetectors Based on Lattice-Matched 6.1 A II/VI and III/V Semiconductors

    Science.gov (United States)

    2015-08-27

    AFRL-AFOSR-VA-TR-2015-0251 MULTICOLOR ( UV -IR) PHOTODETECTORS BASED ON LATTICE MATCHED 6.1A II/IV AND III/V SEMICONDUCTORS Yong-Hang Zhang ARIZONA...14-05-2015 4. TITLE AND SUBTITLE Multicolor ( UV -IR) Photodetectors Based on Lattic Matched 61A IIIV and IIIV Semiconductors 5a. CONTRACT NUMBER 5b...DISTRIBUTION A: Distribution approved for public release. The Final Report for the ASU/ARL AFOSR Program Multicolor ( UV -IR) photodetectors based on

  17. Structural and IR-spectroscopic characterization of cadmium and lead(II) acesulfamates

    Energy Technology Data Exchange (ETDEWEB)

    Echeverria, Gustavo A.; Piro, Oscar E. [Univ. Nacional de La Plata (Argentina). Dept. de Fisica y Inst. IFLP (CONICET- CCT-La Plata); Parajon-Costa, Beatriz S.; Baran, Enrique J. [Univ. Nacional de La Plata (Argentina). Centro de Quimica Inorganica (CEQUINOR/CONICET- CCT-La Plata)

    2017-07-01

    Cadmium and lead(II) acesulfamate, Cd(C{sub 4}H{sub 4}NO{sub 4}S){sub 2} . 2H{sub 2}O and Pb(C{sub 4}H{sub 4}NO{sub 4}S){sub 2}, were prepared by the reaction of acesulfamic acid and the respective metal carbonates in aqueous solution, and characterized by elemental analysis. Their crystal structures were determined by single crystal X-ray diffraction methods. The Cd(II) compound crystallizes in the monoclinic space group P2{sub 1}/c with Z=4 and the corresponding Pb(II) salt in the triclinic space group P anti 1 with Z=2. In both salts, acesulfamate acts both as a bi-dentate ligand through its nitrogen and carbonyl oxygen atoms and also as a mono-dentate ligand through this same oxygen atom, giving rise to polymeric structures; in the Pb(II) salt the ligand also binds the cation through its sulfoxido oxygen atoms. The FTIR spectra of the compounds were recorded and are briefly discussed. Some comparisons with other related acesulfamate and saccharinate complexes are made.

  18. INVESTIGATION OF CLINOPTILOLITE MODIFIED WITH IONS OF HYDROGEN, PALLADIUM(II, AND COPPER(II BY IR AND DIFFUSE REFLECTANCE SPECTRAL METHODS

    Directory of Open Access Journals (Sweden)

    T. L. Rakytskaya

    2016-07-01

    Full Text Available Changes appeared in IR and diffuse reflectance UV-vis spectra of clinoptilolite as a result of its modification by boiling in nitric acid solutions (0.25-3 M and anchoring active components on it were analyzed. As was shown by IR spectroscopy, the increase in acid concentration caused a high-frequency shift of the band attributed to asymmetric stretching vibrations of the Si-O-Al fragment due to the clinoptilolite dealumination. The values of this shift were not changed after active components anchoring on the acid modified clinoptilolite samples.  The band of deformation vibrations of OH groups in water molecules (at 1633 cm-1 for natural clinoptilolite was weakly affected (a slight high-frequency shift by the acid concentration increase and remained practically unaffected by anchoring palladium and copper ions. However,  the effect of Pd(II and Cu(II anchoring on IR spectra could be observed through a low-frequency shift of the band characterizing stretching vibration νОН of OH groups in water molecules indicating some disturbance of hydrogen bonds in H2O molecules and a change in their energy. The UV region of diffuse reflectance UV-vis spectra of all anchored catalyst samples showed the appearance of new intense bands at 224-226, 279-284, and 327-334 nm which were absent Pd-Cu complexes which attendance is necessary for catalytic low-temperature oxidation of carbon monoxide with air oxygen. It should be noted that a new band appeared at 351-363 nm would be assigned to individual Pd(II indicating that some portion of palladium(II ions did not participate in the formation of the catalytically active bimetallic Pd-Cu complexes. The presence of individual palladium(II was confirmed by the fact that only the bends characteristic of square planar palladium(II complexes were observed in the palladium(II absorbing region in the visible part of diffuse reflectance UV-vis spectra. Additionaly, theses spectra also contained the bends corresponding

  19. The measurement of derivative i.r. spectra—II. Experimental measurements

    Science.gov (United States)

    Hawkes, S.; Maddams, W. F.; Mead, W. L.; Southon, M. J.

    The performances of the Butler and Hopkins, and Savitzky and Golay methods, used in conjunction with the Trott and Beynon smoothing technique, for generating derivative i.r. spectra have been assessed experimentally, primarily in the context of peak finding. The test bands used were tert.-butyl benzene (761 cm- -1), 1,2,3-trimethylbenzene (764.5 cm -1) and m-xylene (766.5 cm -1), together with doublets from two component mixtures of these hydrocarbons and a computer-generated doublet from the 1,2,3-trimethylbenzene band. Measurements were made on Perkin-Elmer 577 and 580 spectrometers, with off-line data processing; very satisfactory second and fourth derivative spectra were obtained. Conditions for the optimum compromise between signal to noise ratio and resolution, in terms of the derivatization and smoothing parameters, were established and prove to be similar to those previously deduced from a study of synthetic Lorentzian peak systems. Of the two derivatization techniques the Butler and Hopkins method gives the somewhat superior performance.

  20. Quantitative impact of aerosols on numerical weather prediction. Part II: Impacts to IR radiance assimilation

    Science.gov (United States)

    Marquis, J. W.; Campbell, J. R.; Oyola, M. I.; Ruston, B. C.; Zhang, J.

    2017-12-01

    This is part II of a two-part series examining the impacts of aerosol particles on weather forecasts. In this study, the aerosol indirect effects on weather forecasts are explored by examining the temperature and moisture analysis associated with assimilating dust contaminated hyperspectral infrared radiances. The dust induced temperature and moisture biases are quantified for different aerosol vertical distribution and loading scenarios. The overall impacts of dust contamination on temperature and moisture forecasts are quantified over the west coast of Africa, with the assistance of aerosol retrievals from AERONET, MPL, and CALIOP. At last, methods for improving hyperspectral infrared data assimilation in dust contaminated regions are proposed.

  1. Rigidly linking cyclometallated Ir(iii) and Pt(ii) centres: an efficient approach to strongly absorbing and highly phosphorescent red emitters.

    Science.gov (United States)

    Turnbull, Graeme; Williams, J A Gareth; Kozhevnikov, Valery N

    2017-02-28

    The synthesis and photophysical properties of an unprecedented tetranuclear complex are described, in which a fac-tris-cyclometallated Ir(iii) centre is rigidly connected to three cyclometallated Pt(ii) centres. The complex absorbs strongly up to ∼600 nm and emits red light with unusually high efficiency.

  2. SOFIA-EXES Mid-IR Observations of [Fe II] Emission from the Extended Atmosphere of Betelgeuse

    Science.gov (United States)

    Harper, G. M.; DeWitt, C.; Richter, M. J.; Greathouse, T. K.; Ryde, N.; Guinan, E. F.; O'Gorman, E.; Vacca, W. D.

    2017-02-01

    We present a NASA-DLR SOFIA-Echelon Cross Echelle Spectrograph (EXES) and NASA Infrared Telescope Facility-Texas Echelon Cross Echelle Spectrograph (TEXES) mid-IR R≃ {{50,000}} spectral study of forbidden Fe II transitions in the early-type M supergiants, Betelgeuse (α Ori: M2 Iab) and Antares (α Sco: M1 Iab + B3 V). With EXES, we spectrally resolve the ground term [Fe II] 25.99 μm (a{}6{D}J=7/2{--9/2}: {E}{up}=540 K) emission from Betelgeuse. We find a small centroid blueshift of 1.9 ± 0.4 {km} {{{s}}}-1 that is a significant fraction (20%) of the current epoch wind speed, with a FWHM of 14.3 ± 0.1 {km} {{{s}}}-1. The TEXES observations of [Fe II] 17.94 μm (a{}4{F}J=7/2-9/2: {E}{up}={{3400}} K) show a broader FWHM of 19.1 ± 0.2 {km} {{{s}}}-1, consistent with previous observations, and a small redshift of 1.6 ± 0.6 {km} {{{s}}}-1 with respect to the adopted stellar center-of-mass velocity of {V}{CoM}=20.9+/- 0.3 {km} {{{s}}}-1. To produce [Fe II] 25.99 μm blueshifts of 20% wind speed requires that the emission arises closer to the star than existing thermal models for α Ori’s circumstellar envelope predict. This implies a more rapid wind cooling to below 500 K within 10{R}* ({θ }* =44 mas, dist = 200 pc) of the star, where the wind has also reached a significant fraction of the maximum wind speed. The line width is consistent with the turbulence in the outflow being close to the hydrogen sound speed. EXES observations of [Fe II] 22.90 μm (a{}4{D}J=5/2{--7/2}: {E}{up}={{11,700}} K) reveal no emission from either star. These findings confirm the dominance of cool plasma in the mixed region where hot chromospheric plasma emits copiously in the UV, and they also constrain the wind heating produced by the poorly understood mechanisms that drive stellar outflows from these low variability and weak-dust signature stars.

  3. Degradation behavior of polymer blend of isotactic polypropylenes with and without unsaturated chain end group

    Science.gov (United States)

    Nakatani, Hisayuki; Kurniawan, Dodik; Taniike, Toshiaki; Terano, Minoru

    2008-04-01

    In this work, the relationship between the unsaturated chain end group content and the thermal oxidative degradation rate was systematically studied with binary polymer blends of isotactic polypropylene (iPP) with and without the unsaturated chain end group. The iPPs with and without the unsaturated chain end group were synthesized by a metallocene catalyst in the absence of hydrogen and by a Ziegler catalyst in the presence of one, respectively. The thermal oxidative degradation rate of the binary iPP blends was estimated from the molecular weight and the apparent activation energy (ΔE), which were obtained through size exclusion chromatography (SEC) and thermogravimetric analysis (TGA) measurements, respectively. These values exhibited a negative correlation against the mole content of the unsaturated chain end group. The thermal oxidative degradation rate apparently depends on the content of the unsaturated chain end group. This tendency suggests that the unsaturated chain end acts as a radical initiator of the iPP degradation reaction.

  4. Degradation behavior of polymer blend of isotactic polypropylenes with and without unsaturated chain end group

    International Nuclear Information System (INIS)

    Nakatani, Hisayuki; Kurniawan, Dodik; Taniike, Toshiaki; Terano, Minoru

    2008-01-01

    In this work, the relationship between the unsaturated chain end group content and the thermal oxidative degradation rate was systematically studied with binary polymer blends of isotactic polypropylene (iPP) with and without the unsaturated chain end group. The iPPs with and without the unsaturated chain end group were synthesized by a metallocene catalyst in the absence of hydrogen and by a Ziegler catalyst in the presence of one, respectively. The thermal oxidative degradation rate of the binary iPP blends was estimated from the molecular weight and the apparent activation energy (ΔE), which were obtained through size exclusion chromatography (SEC) and thermogravimetric analysis (TGA) measurements, respectively. These values exhibited a negative correlation against the mole content of the unsaturated chain end group. The thermal oxidative degradation rate apparently depends on the content of the unsaturated chain end group. This tendency suggests that the unsaturated chain end acts as a radical initiator of the iPP degradation reaction.

  5. Degradation behavior of polymer blend of isotactic polypropylenes with and without unsaturated chain end group

    Directory of Open Access Journals (Sweden)

    Hisayuki Nakatani et al

    2008-01-01

    Full Text Available In this work, the relationship between the unsaturated chain end group content and the thermal oxidative degradation rate was systematically studied with binary polymer blends of isotactic polypropylene (iPP with and without the unsaturated chain end group. The iPPs with and without the unsaturated chain end group were synthesized by a metallocene catalyst in the absence of hydrogen and by a Ziegler catalyst in the presence of one, respectively. The thermal oxidative degradation rate of the binary iPP blends was estimated from the molecular weight and the apparent activation energy (ΔE, which were obtained through size exclusion chromatography (SEC and thermogravimetric analysis (TGA measurements, respectively. These values exhibited a negative correlation against the mole content of the unsaturated chain end group. The thermal oxidative degradation rate apparently depends on the content of the unsaturated chain end group. This tendency suggests that the unsaturated chain end acts as a radical initiator of the iPP degradation reaction.

  6. Polycyclic Aromatic Hydrocarbon Emission in Spitzer /IRS Maps. II. A Direct Link between Band Profiles and the Radiation Field Strength

    Energy Technology Data Exchange (ETDEWEB)

    Stock, D. J.; Peeters, E., E-mail: dstock84@gmail.com [Department of Physics and Astronomy, University of Western Ontario, London, ON, N6A 3K7 (Canada)

    2017-03-10

    We decompose the observed 7.7 μ m polycyclic aromatic hydrocarbon (PAH) emission complexes in a large sample of over 7000 mid-infrared spectra of the interstellar medium using spectral cubes observed with the Spitzer /IRS-SL instrument. In order to fit the 7.7 μ m PAH emission complex we invoke four Gaussian components, which are found to be very stable in terms of their peak positions and widths across all of our spectra, and subsequently define a decomposition with fixed parameters, which gives an acceptable fit for all the spectra. We see a strong environmental dependence on the interrelationships between our band fluxes—in the H ii regions all four components are intercorrelated, while in the reflection nebulae (RNs) the inner and outer pairs of bands correlate in the same manner as previously seen for NGC 2023. We show that this effect arises because the maps of RNs are dominated by emission from strongly irradiated photodissociation regions, while the much larger maps of H ii regions are dominated by emission from regions much more distant from the exciting stars, leading to subtly different spectral behavior. Further investigation of this dichotomy reveals that the ratio of two of these components (centered at 7.6 and 7.8 μ m) is linearly related to the UV-field intensity (log G {sub 0}). We find that this relationship does not hold for sources consisting of circumstellar material, which are known to have variable 7.7 μ m spectral profiles.

  7. A New Heteroleptic Biquinoline Ruthenium(II Sensitizer for Near-IR Sensitization of Nanocrystalline TiO2

    Directory of Open Access Journals (Sweden)

    Surya Prakash Singh

    2013-01-01

    Full Text Available Ruthenium(II complex containing cis-[Ru(H2dcbiq(L(NCS2], where H2dcbiq = 4,4′-dicarboxy-2,2′-biquinoline and L = 4,4′-di-tert-butyl-2-2′-dipyridyl coded as SPS-02, was synthesized and fully characterized. This complex showed appreciably broad absorption range. The new complex was used as photosensitizer in nanocrystalline TiO2 dye-sensitized solar cell application. cis-[Ru(H2dcbiq(L(NCS2] (SPS-02 achieved efficient sensitization of nanocrystalline TiO2 over the whole visible range, extending into the near-IR region (ca. 1000 nm with superior short-circuit photocurrent density ( = 9.13 mA cm−2 and conversion efficiency (η = 2.09% compared with complex cis-[Ru(H2dcbiq2(NCS2] (1 under an irradiation of full sunlight (100 mW cm−2.

  8. Pentafluorobenzene end-group as a versatile handle for para fluoro "click" functionalization of polythiophenes.

    Science.gov (United States)

    Boufflet, Pierre; Casey, Abby; Xia, Yiren; Stavrinou, Paul N; Heeney, Martin

    2017-03-01

    A convenient method of introducing pentafluorobenzene (PFB) as a single end-group in polythiophene derivatives is reported via in situ quenching of the polymerization. We demonstrate that the PFB-group is a particularly useful end-group due to its ability to undergo fast nucleophilic aromatic substitutions. Using this molecular handle, we are able to quantitatively tether a variety of common nucleophiles to the polythiophene backbone. The mild conditions required for the reaction allows sensitive functional moieties, such as biotin or a cross-linkable trimethoxysilane, to be introduced as end-groups. The high yield enabled the formation of a diblock rod-coil polymer from equimolar reactants under transition metal-free conditions at room temperature. We further demonstrate that water soluble polythiophenes end-capped with PFB can be prepared via the hydrolysis of an ester precursor, and that such polymers are amenable to functionalization under aqueous conditions.

  9. A High-Leverage Language Teaching Practice: Leading an Open-Ended Group Discussion

    Science.gov (United States)

    Kearney, Erin

    2015-01-01

    In response to calls for more practice-based teacher education, this study investigated the way in which two high-performing novice world language teachers, one in Spanish and one in Latin, implemented a high-leverage teaching practice, leading an open-ended group discussion. Observational data revealed a number of constituent micro-practices. The…

  10. Synthesis, characterization and use of ATRP bifunctional initiator with trichloromethyl end-groups

    Czech Academy of Sciences Publication Activity Database

    Toman, Luděk; Janata, Miroslav; Spěváček, Jiří; Masař, Bohumil; Vlček, Petr; Látalová, Petra

    2002-01-01

    Roč. 43, č. 2 (2002), s. 18-19 ISSN 0032-3934 R&D Projects: GA ČR GA203/01/0513 Institutional research plan: CEZ:AV0Z4050913 Keywords : bifunctional initiator * ATRP polymerization * trichloromethyl end-groups Subject RIV: CD - Macromolecular Chemistry

  11. Monophosphate end groups produced in radiation induced strand breakage in DNA

    International Nuclear Information System (INIS)

    Kay, E.; Ward, J.F.

    1976-01-01

    A solution of DNA was gamma-irradiated and treated with monophosphatase for studies on the amount of inorganic phosphate released as a function of time. Studies were also conducted on: effect of alkali on yield of monophosphate end groups; induction of DNA strand breaks by treatment with DNAase; initial G values for monophosphate termini; and effect of alkali on radioinduced DNA damage

  12. Test and evaluation of IR detectors and arrays II; Proceedings of the Meeting, Orlando, FL, Apr. 22, 23, 1992

    Science.gov (United States)

    Hoke, Forney M.

    The present conference discusses a radiometric calibration system for IR cameras, a methodology for testing IR focal-plane arrays in simulated nuclear radiation environments, process optimization for Si:As In-bumped focal-plane arrays, precise MTF measurements for focal-plane arrays, and IR focal-plane array crosstalk measurement. Also discussed are an imaging metric for IR focal-plane arrays, optical stimuli for high-volume automated testing of 2D HgCdTe focal-plane arrays, the evaluation of a solid-state photomultiplier focal-plane array for SDI, spectral effects on bulk photoconductors operated at cryogenic temperatures, and a novel technique for measuring the ionizing radiation effects in MOS transistors.

  13. Exploiting end group functionalization for the design of antifouling bioactive brushes

    Czech Academy of Sciences Publication Activity Database

    Kuzmyn, Andrii; de los Santos Pereira, Andres; Pop-Georgievski, Ognen; Bruns, M.; Brynda, Eduard; Rodriguez-Emmenegger, Cesar

    2014-01-01

    Roč. 5, č. 13 (2014), s. 4124-4131 ISSN 1759-9954 R&D Projects: GA ČR GAP205/12/1702; GA ČR(CZ) GAP108/11/1857; GA MŠk(CZ) ED1.1.00/02.0109 Institutional support: RVO:61389013 Keywords : click chemistry * end-group functionalization * non-fouling Subject RIV: CD - Macromolecular Chemistry Impact factor: 5.520, year: 2014

  14. IR intensity

    DEFF Research Database (Denmark)

    Spanget-Larsen, Jens

    2015-01-01

    Definitions, formulas, and code for producing epsilon values (molar absorption coefficients) and IR spectral curve from 'Gaussian' FREQ output.......Definitions, formulas, and code for producing epsilon values (molar absorption coefficients) and IR spectral curve from 'Gaussian' FREQ output....

  15. IR, UV-Vis, magnetic and thermal characterization of chelates of some catecholamines and 4-aminoantipyrine with Fe(III) and Cu(II)

    Science.gov (United States)

    Mohamed, Gehad G.; Zayed, M. A.; El-Dien, F. A. Nour; El-Nahas, Reham G.

    2004-07-01

    The dopamine derivatives participate in the regulation of wide variety of physiological functions in the human body and in medication life. Increase and/or decrease in the concentration of dopamine in human body reflect an indication for diseases such as Schizophrenia and/or Parkinson diseases. α-Methyldopa (α-MD) in tablets is used in medication of hypertension. The Fe(III) and Cu(II) chelates with coupled products of adrenaline hydrogen tartarate (AHT), levodopa (LD), α-MD and carbidopa (CD) with 4-aminoantipyrine (4-AAP) are prepared and characterized. Different physico-chemical methods like IR, magnetic and UV-Vis spectra are used to investigate the structure of these chelates. Fe(III) form 1:2 (M:catecholamines) chelates while Cu(II) form 1:1 chelates. Catecholamines behave as a bidentate mono- or dibasic ligands in binding to the metal ions. IR spectra show that the catecholamines are coordinated to the metal ions in a bidentate manner with O,O donor sites of the phenolic - OH. Magnetic moment measurements reveal the presence of Fe(III) chelates in octahedral geometry while the Cu(II) chelates are square planar. The thermal decomposition of Fe(III) and Cu(II) complexes is studied using thermogravimetric (TGA) and differential thermal analysis (DTA) techniques. The water molecules are removed in the first step followed immediately by decomposition of the ligand molecules. The activation thermodynamic parameters, such as, energy of activation, enthalpy, entropy and free energy change of the complexes are evaluated and the relative thermal stability of the complexes are discussed.

  16. Optimizing end-group cross-linking polymer electrolytes for fuel cell applications

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Yu Seung [Los Alamos National Laboratory; Lee, Kwan Soo [Los Alamos National Laboratory; Jeong, Myung - Hwan [GIST, KOREA; Lee, Jae - Suk [GIST, KOREA

    2009-01-01

    This paper demonstrates the optimization of proton conductivity and water uptake for cross-linkable polymer electrolytes through synthesis and characterization of end-group cross-linkable sulfonated poly(arylene ether) copolymers (ESF-BPs). The extent of reaction of cross-linking was controlled by reaction time resulting in a series of polymers with two, independent tunable parameters, degree of sulfonation (DS) and degree of cross-linking (DC). For the polymers presented, cross-linking improved proton conductivity while reducing water uptake, an uncommon trend in polymer electrolytes where water is critical for proton conduction. Other trends relating to changes are reported and the results yield insight into the role of DS and DC and how to optimize electrochemical properties and performance of polymer electrolytes through these tunable parameters. Select polymer electrolytes were tested in fuel cells where performance and durability with accelerated relative humidity cycling were compared with Nafion{reg_sign}.

  17. Lead (II) biosorption equilibrium and characterization through FT-IR and SEM-EDAX crosslinked pectin from orange peels

    International Nuclear Information System (INIS)

    Garcia Villegas, Victor R.; Ale Borja, Neptali; Guzman Lezama, Enrique G.; Maldonado Garcia, Holger J.; Yipmantin Ojeda, Andrea G.

    2013-01-01

    Pectic material extracted from orange peels was previously cross-linked to diminish hydration and swelling capacity when pectin is found in aqueous solution medium. Degree of metoxilation (DM), galacturonic acid anhydrous (% AGA) and pKa determination allowed characterizing biosorbent. Maximum sorption capacity was obtained at pH between 4.5 and 5.5. For data processing and statistical treatment informatics Orign 6.0 version program was used. Data from biosorption equilibrium had a better fit on Langmuir sorption equation model, obtaining q max = 186 mg/g as a maximum adsorption capacity. Fourier transform infrared spectroscopy analysis (FT-IR) allowed recognizing characteristic functional groups presents as well as biomass modifications. Biosorbent surface morphologic was studied by scanning electron microscope (SEM) and elemental composition biomass before biosorption process was obtained through Energy-dispersive X-ray spectroscopy (EDAX). (author)

  18. A new tridentate Schiff base Cu(II) complex: synthesis, experimental and theoretical studies on its crystal structure, FT-IR and UV-Visible spectra.

    Science.gov (United States)

    Saheb, Vahid; Sheikhshoaie, Iran; Setoodeh, Nasim; Rudbari, Hadi Amiri; Bruno, Giuseppe

    2013-06-01

    A new Cu(II) complex [Cu(L)(NCS)] has been synthesized, using 1-(N-salicylideneimino)-2-(N,N-methyl)-aminoethane as tridentate ONN donor Schiff base ligand (HL). The dark green crystals of the compound are used for single-crystal X-ray analysis and measuring Fourier Transform Infrared (FT-IR) and UV-Visible spectra. Electronic structure calculations at the B3LYP and MP2 levels of theory are performed to optimize the molecular geometry and to calculate the UV-Visible and FT-IR spectra of the compound. Vibrational assignments and analysis of the fundamental modes of the compound are performed. Time-dependent density functional theory (TD-DFT) method is used to calculate the electronic transitions of the complex. A scaling factor of 1.015 is obtained for vibrational frequencies computed at the B3LYP level using basis sets 6-311G(d,p). It is found that solvent has a profound effect on the electronic absorption spectrum. The UV-Visible spectrum of the complex recorded in DMSO and DMF solution can be correctly predicted by a model in which DMSO and DMF molecules are coordinated to the central Cu atom via their oxygen atoms. Copyright © 2013 Elsevier B.V. All rights reserved.

  19. Interaction of nitrogen oxides with sublimed layers of (meso-tetraphenylporphyrinato)cobalt(II); IR evidence of oxo-transfer from (nitro)porphyrinatocobalt(III) to free nitric oxide.

    Science.gov (United States)

    Kurtikyan, Tigran S; Mardyukov, Arthur N; Goodwin, John A

    2003-12-15

    Interaction of a low-pressure NO2 with sublimed layers of (meso-tetraphenylporphyrinato)cobalt(II) (Co(TPP)) leads to formation of 5-coordinate nitro complex Co(III)(TPP)(NO2). Upon exposure of these layers to pyridine vapors, the fast reaction with formation of 6-coordinate nitro-pyridine porphyrins (Py)Co(III)(TPP)(NO2) occurs. By means of IR spectroscopy and use of nitrogen oxide isotopomers, it is shown that an oxo-transfer reaction occurs from 5-coordinate species to free nitric oxide (NO) while the 6-coordinate complex is rather inert. It is also demonstrated that the stepwise addition of low-pressure NO2 to nitrosyl complex Co(TPP)(NO) leads to formation of the nitro complex most likely by an exchange reaction.

  20. Synthesis, spectral (IR, UV-Vis and variable temperature NMR) characterization and crystal structure of (N-benzyl-N-furfuryldithicarbamato-S,S‧)(thiocyanato-N)(triphenylphosphine)nickel(II)

    Science.gov (United States)

    Valarmathi, P.; Thirumaran, S.; Sarmal, Lovely; Kant, Rajni

    2014-08-01

    Planar (N-benzyl-N-furfuryldithiocarbamato-S,S‧)(thiocyanato-N)(triphenylphospine)nickel(II), [Ni(bfdtc)(NCS)(PPh3)], (1) was prepared from bis(N-benzyl-N-furfuryldithiocarbamato-S,S‧)nickel(II), [Ni(bfdtc)2], (2) and characterized by elemental analysis, cyclic voltammetry, electronic, IR and variable temperature 1H and 13C NMR spectra. For complex 1, the thioureide vCsbnd N value is shifted to higher wavenumber compared to 2 and N13CS2 carbon signal observed for 1 is additionally shielded compared to the parent complex 2, suggesting increased strength of the thioureide bond due to the presence of the π-accepting phosphine. In the room temperature 13C NMR spectrum of 1, two pseudo doublets are observed in the aliphatic region. Variable temperature 13C NMR spectral studies suggest that the fast thiocyanate exchange appears to be responsible for the appearance of pseudo doublets. Single crystal X-ray structural analysis of 1 and 2 confirm the presence of four coordinated nickel in a distorted square planar arrangement with the NiS2PN and NiS4 chromophores, respectively. The Nisbnd S bonds are symmetric in 2 (2.1914(14) and 2.2073(13) Å). But significant asymmetry in Nisbnd S bond distances was observed in 1 (2.2202(8) Å and 2.1841 Å). This observation clearly supports the less effective trans effect of SCN- over PPh3. Cyclic voltammetric studies revealed easier reduction of nickel(II) to nickel(I) in complex 1 compared to 2.

  1. Synthesis of copolymers with cyclodextrin as pendants and its end group effect as superplasticizer.

    Science.gov (United States)

    Li, Yinwen; Guo, Huilong; Zhang, Yunfei; Zheng, Jian; Li, Zhaoxia; Yang, Chenghua; Lu, Mangeng

    2014-02-15

    In this paper, the efficient approach for the synthesis of β-cyclodextrin (CD) based functional monomers was described. Based on the monovinyl β-CD monomer (GMA-EDA-CD), a new type poly(AA-co-GMA-EDA-CD) (PCDs) copolymer bearing pendent CD groups was synthesized and used as superplasticizer. Their chemical compositions were characterized by FT-IR, NMR, MALDI-TOF and GPC. The effects of PCDs on dispersion and adsorption in cement mortars were detailed discussed. The results indicated that PCD copolymers behaved excellent dispersion ability and strong retarding effect. PCD2 with molar ratio (%) for monomer (AA:GMA-EDA-CD=80:20) had the best dispersion and dispersion maintaining abilities, which were mainly attributed to the synergistic effects of steric hindrance and electrostatic repulsive force, and the retarding effect of PCD copolymers resulted from steric hindrance repulsion of CD pendants and the large number of hydroxyl groups, which affected the hydration reaction of cement. Copyright © 2013 Elsevier Ltd. All rights reserved.

  2. Photoaquation Mechanism of Hexacyanoferrate(II) Ions: Ultrafast 2D UV and Transient Visible and IR Spectroscopies.

    Science.gov (United States)

    Reinhard, Marco; Auböck, Gerald; Besley, Nicholas A; Clark, Ian P; Greetham, Gregory M; Hanson-Heine, Magnus W D; Horvath, Raphael; Murphy, Thomas S; Penfold, Thomas J; Towrie, Michael; George, Michael W; Chergui, Majed

    2017-05-31

    Ferrous iron(II) hexacyanide in aqueous solutions is known to undergo photoionization and photoaquation reactions depending on the excitation wavelength. To investigate this wavelength dependence, we implemented ultrafast two-dimensional UV transient absorption spectroscopy, covering a range from 280 to 370 nm in both excitation and probing, along with UV pump/visible probe or time-resolved infrared (TRIR) transient absorption spectroscopy and density functional theory (DFT) calculations. As far as photoaquation is concerned, we find that excitation of the molecule leads to ultrafast intramolecular relaxation to the lowest triplet state of the [Fe(CN) 6 ] 4- complex, followed by its dissociation into CN - and [Fe(CN) 5 ] 3- fragments and partial geminate recombination, all within <0.5 ps. The subsequent time evolution is associated with the [Fe(CN) 5 ] 3- fragment going from a triplet square pyramidal geometry, to the lowest triplet trigonal bipyramidal state in 3-4 ps. This is the precursor to aquation, which occurs in ∼20 ps in H 2 O and D 2 O solutions, forming the [Fe(CN) 5 (H 2 O/D 2 O)] 3- species, although some aquation also occurs during the 3-4 ps time scale. The aquated complex is observed to be stable up to the microsecond time scale. For excitation below 310 nm, the dominant channel is photooxidation with a minor aquation channel. The photoaquation reaction shows no excitation wavelength dependence up to 310 nm, that is, it reflects a Kasha Rule behavior. In contrast, the photooxidation yield increases with decreasing excitation wavelength. The various intermediates that appear in the TRIR experiments are identified with the help of DFT calculations. These results provide a clear example of the energy dependence of various reactive pathways and of the role of spin-states in the reactivity of metal complexes.

  3. Isocyanate-Free Route to Caprolactam-Blocked Oligomeric Isocyanates via Carbonylbiscaprolactam- (CBC-) Mediated End Group Conversion

    NARCIS (Netherlands)

    Maier, Steffen; Loontjens, Ton; Scholtens, Boudewijn; Mülhaupt, Rolf

    2003-01-01

    Blocked isocyanate functional oligomers and liquid rubbers are prepared by a novel, solvent-free carbonylbiscaprolactam (CBC) mediated end group conversion reaction of amine-terminated oligodimethylsiloxanes (PDMS) and oligopropyleneoxides (PPO), with molar masses varying between 400 and 3140 g/mol,

  4. Inyang, IR

    African Journals Online (AJOL)

    Inyang, IR. Vol 5, No 4 (2009) - Articles Changes in Total Protein and Transaminase Activities in Clarias Gariepinus Exposed to Diazinon Abstract. ISSN: 0794-4721. AJOL African Journals Online. HOW TO USE AJOL... for Researchers · for Librarians · for Authors · FAQ's · More about AJOL · AJOL's Partners · Terms and ...

  5. A Phase I/II Trial of DCVac/IR Dendritic Cell Immunotherapy Combined with Irradiation in Cases of Refractory Colorectal Cancer with Multiple Liver Metastases

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Young-Min; Lee, Hyung-Sik; Kwon, Hyuk-Chan; Han, Sang-Young; Choi, Jong-Cheol [Donga Univ. School of Medicine, Busan (Korea, Republic of); Chung, Ju-Seop; Kim, Chang-Won; Kim, Dong-Won; Kang, Chi-Duk [Busan National University College of Medicine, Busan (Korea, Republic of)

    2008-06-15

    injections. Moreover, of the 14 patients that applied for the tolerance test, only 11 patients completed it because 3 patients withdrew their testing agreement. A grade 3 or more side effect, which was possibly related to the DC injection, did not occur in additional patients. The 12x10{sup 6} DC injection was identified as the maximum tolerable dose, and was then injected in an additional 8 patients. Patients tolerated the injection fairly well, with no fatal side effects. In order to assess the feasibility of DC immunotherapy, the response was evaluated in other hepatic lesions outside of the targeted hepatic lesion. The response evaluation was performed in 15 of the 17 patients who received at least 4 injections. Stable and progressive disease was found in 4 and 11 patients, respectively. The DC-based immunotherapy and radiotherapy is theoretically synergistic for the local control and systemic control. The DCVac/IR immunotherapy combined with irradiation was tolerable and safe in the evaluated cases of refractory colorectal cancer with multiple liver metastases. Future work should include well designed a phase II clinical trials.

  6. Intervalent bis(mu-aziridinato)M-II-M-I complexes (M = Rh, Ir): Delocalized metallo-radicals or delocalized aminyl radicals?

    NARCIS (Netherlands)

    Tejel, C.; Ciriano, M.A.; Passarelli, V.; López, J.A.; de Bruin, B.

    2008-01-01

    Reactions of the methoxo complexes [{M([mu-OMe)(cod)}(2)] (cod = 1,5-cyclooctadiene, M=Rh, Ir) with 2,2-dimethylaziridine (Haz) give the mixed-bridged complexes [{M-2(mu-az)([mu-OMe)(cod)(2)}] [(M = Rh, 1; M = Ir, 2). These compounds are isolated intermediates in the stereospecific synthesis of the

  7. The nature of peptide interactions with acid end-group PLGAs and facile aqueous-based microencapsulation of therapeutic peptides

    OpenAIRE

    Sophocleous, Andreas M.; Desai, Kashappa-Goud H.; Mazzara, J. Maxwell; Tong, Ling; Cheng, Ji-Xin; Olsen, Karl F.; Schwendeman, Steven P.

    2013-01-01

    An important poorly understood phenomenon in controlled-release depots involves the strong interaction between common cationic peptides and low Mw free acid end-group poly(lactic-co-glycolic acids) (PLGAs) used to achieve continuous peptide release kinetics. The kinetics of peptide sorption to PLGA was examined by incubating peptide solutions of 0.2-4 mM octreotide or leuprolide acetate salts in 0.1 M HEPES buffer, pH 7.4, with polymer particles or films at 4-37 °C for 24 h. The extent of abs...

  8. End group functionalization of poly(ethylene glycol with phenolphthalein: towards star-shaped polymers based on supramolecular interactions

    Directory of Open Access Journals (Sweden)

    Carolin Fleischmann

    2014-09-01

    Full Text Available The synthesis of a new phenolphthalein azide derivative, which can be easily utilized in polymer analogous reactions, is presented. The subsequent cycloaddition reaction with propargyl-functionalized methoxypoly(ethylene glycol yielded polymers bearing phenolphthalein as the covalently attached end group. In presence of per-β-cyclodextrin-dipentaerythritol, the formation of stable inclusion complexes was observed, representing an interesting approach towards the formation of star shaped polymers. The decolorization of a basic polymer solution caused by the complexation was of great advantage since this behavior enabled following the complex formation by UV–vis spectroscopy and even the naked eye.

  9. End group functionalization of poly(ethylene glycol) with phenolphthalein: towards star-shaped polymers based on supramolecular interactions.

    Science.gov (United States)

    Fleischmann, Carolin; Wöhlk, Hendrik; Ritter, Helmut

    2014-01-01

    The synthesis of a new phenolphthalein azide derivative, which can be easily utilized in polymer analogous reactions, is presented. The subsequent cycloaddition reaction with propargyl-functionalized methoxypoly(ethylene glycol) yielded polymers bearing phenolphthalein as the covalently attached end group. In presence of per-β-cyclodextrin-dipentaerythritol, the formation of stable inclusion complexes was observed, representing an interesting approach towards the formation of star shaped polymers. The decolorization of a basic polymer solution caused by the complexation was of great advantage since this behavior enabled following the complex formation by UV-vis spectroscopy and even the naked eye.

  10. End Group Modification

    DEFF Research Database (Denmark)

    Jahnsen, Rasmus O; Sandberg-Schaal, Anne; Frimodt-Møller, Niels

    2015-01-01

    modification with hydrophobic moieties led to increased activity towards the Gram-negative Acinetobacter baumannii. Despite increased cytotoxicity against murine fibroblasts and human umbilical vein endothelial cells, the optimized peptide analogues exhibited significantly improved cell selectivity. Overall...

  11. Caracterização por FT-IR de agentes de cura utilizados em resinas epoxídicas-II-polimercaptana, poliaminoamida e amina modificada

    Directory of Open Access Journals (Sweden)

    Romão Benedita M. V.

    2003-01-01

    Full Text Available Amostras de resina epoxídica (EP curadas com compostos à base depolimercaptana (SH, SH na presença de poliamino amida, e amina modificada, constituindo, respectivamente, os sistemas epoxídicos (SE 1, 2 e 3, foram preparadas segundo condições estabelecidas pelas curvas de calorimetria exploratória diferencial (DSC de EP e agentes de cura, ou endurecedores (AC e analisadas, antes e após preparação do SE, por espectroscopia no infravermelho com transformada de Fourier (FT-IR por meio de técnicas de transmissão (pastilha de KBr, pirólise por bico de Bunsen, e pirólisecontrolada (CONTROLPIR/FT-IR dentro da faixa de temperatura fornecida pela análise termogravimétrica (TG dos SE 1, 2 e 3, para a caracterização de cada AC. Para tal fim, as absorções FT-IR do pirolisado líquido obtido pela metodologia CONTROLPIR/FT-IR foram avaliadas, em comparação ao espectro do AC de referência. A caracterização dos agentes de cura foi feita com a técnica TG/FT-IR do gás liberado de cada SE, em comparação ao espectro de referência do produto de degradação do respectivo AC.

  12. The role of water in B-DNAs B I to B II conformer substates interconversion: a combined study by calorimetry, FT-IR spectroscopy and computer simulation

    Science.gov (United States)

    Pichler, Arthur; Rüdisser, Simon; Winger, Rudolf H.; Liedl, Klaus R.; Hallbrucker, Andreas; Mayer, Erwin

    2000-08-01

    Conformational substates of B-DNA had been observed so far in synthetic oligonucleotides but not in naturally occurring highly polymeric B-DNA. Our low-temperature experiments show that native B-DNA from salmon testes and the d(CGCGAATTCGCG) 2 dodecamer have the same B I and B II substates. Nonequilibrium distribution of conformer population was generated by quenching hydrated nonoriented films or fibers into the glassy state, and isothermal structural relaxation towards equilibrium by interconversion of substates was followed either by differential scanning calorimetry or by Fourier transform infrared spectroscopy. B I converts to B II on isothermal relaxation between 180 and 220 K, whereas on slow cooling from ambient temperature, B II converts to B I. State-of-the-art molecular dynamics simulation of the d(CGCGAATTCGCG) 2 dodecamer revealed that the B I→B II transition involves not only destacking of adjacent base pairs, but is coupled with migration of water from ionic phosphate to the sugar oxygen. These results are consistent with pronounced infrared spectral changes observed upon B I→B II interconversion. The B II substate is stabilized in comparison to B I by enhanced hydrogen-bond interaction with the migrating water. Curve resolution of infrared spectra showed that in hydrated nonoriented films of the d(CGCGAATTCGCG) 2 dodecamer, the B II population is enhanced in comparison to that in single crystals. Thus, the B II substate could be of biological relevance, and the B I to B II substate interconversion could be a major contributor to the protein recognition process.

  13. Copper(II) complex with 6-methylpyridine-2-carboxyclic acid: Experimental and computational study on the XRD, FT-IR and UV-Vis spectra, refractive index, band gap and NLO parameters

    Science.gov (United States)

    Altürk, Sümeyye; Avcı, Davut; Başoğlu, Adil; Tamer, Ömer; Atalay, Yusuf; Dege, Necmi

    2018-02-01

    Crystal structure of the synthesized copper(II) complex with 6-methylpyridine-2-carboxylic acid, [Cu(6-Mepic)2·H2O]·H2O, was determined by XRD, FT-IR and UV-Vis spectroscopic techniques. Furthermore, the geometry optimization, harmonic vibration frequencies for the Cu(II) complex were carried out by using Density Functional Theory calculations with HSEh1PBE/6-311G(d,p)/LanL2DZ level. Electronic absorption wavelengths were obtained by using TD-DFT/HSEh1PBE/6-311G(d,p)/LanL2DZ level with CPCM model and major contributions were determined via Swizard/Chemissian program. Additionally, the refractive index, linear optical (LO) and non-nonlinear optical (NLO) parameters of the Cu(II) complex were calculated at HSEh1PBE/6-311G(d,p) level. The experimental and computed small energy gap shows the charge transfer in the Cu(II) complex. Finally, the hyperconjugative interactions and intramolecular charge transfer (ICT) were studied by performing of natural bond orbital (NBO) analysis.

  14. The nature of peptide interactions with acid end-group PLGAs and facile aqueous-based microencapsulation of therapeutic peptides.

    Science.gov (United States)

    Sophocleous, Andreas M; Desai, Kashappa-Goud H; Mazzara, J Maxwell; Tong, Ling; Cheng, Ji-Xin; Olsen, Karl F; Schwendeman, Steven P

    2013-12-28

    An important poorly understood phenomenon in controlled-release depots involves the strong interaction between common cationic peptides and low Mw free acid end-group poly(lactic-co-glycolic acids) (PLGAs) used to achieve continuous peptide release kinetics. The kinetics of peptide sorption to PLGA was examined by incubating peptide solutions of 0.2-4mM octreotide or leuprolide acetate salts in a 0.1M HEPES buffer, pH7.4, with polymer particles or films at 4-37°C for 24h. The extent of absorption/loading of peptides in PLGA particles/films was assayed by two-phase extraction and amino acid analysis. Confocal Raman microspectroscopy, stimulated Raman scattering (SRS) and laser scanning confocal imaging, and microtome sectioning techniques were used to examine peptide penetration into the polymer phase. The release of sorbed peptide from leuprolide-PLGA particles was evaluated both in vitro (PBST+0.02% sodium azide, 37°C) and in vivo (male Sprague-Dawley rats). We found that when the PLGA-COOH chains are sufficiently mobilized, therapeutic peptides not only bind at the surface, a common belief to date, but also can be internalized and distributed throughout the polymer phase at physiological temperature forming a salt with low-molecular weight PLGA-COOH. Importantly, absorption of leuprolide into low MW PLGA-COOH particles yielded ~17 wt.% leuprolide loading in the polymer (i.e., ~70% of PLGA-COOH acids occupied), and the absorbed peptide was released from the polymer for >2 weeks in a controlled fashion in vitro and as indicated by sustained testosterone suppression in male Sprague-Dawley rats. This new approach, which bypasses the traditional encapsulation method and associated production cost, opens up the potential for facile production of low-cost controlled-release injectable depots for leuprolide and related peptides. © 2013.

  15. Rapid and simple determination of polyphyllin I, II, VI, and VII in different harvest times of cultivated Paris polyphylla Smith var. yunnanensis (Franch.) Hand.-Mazz by UPLC-MS/MS and FT-IR.

    Science.gov (United States)

    Wu, Zhe; Zhang, Ji; Xu, Furong; Wang, Yuanzhong; Zhang, Jinyu

    2017-01-01

    Paris Polyphylla Smith var. yunnanensis (Franch.) Hand.-Mazz ("Dian Chonglou" in Chinese) is a famous herbal medicine in China, which is usually well known for activities of anti-cancer, hemolysis, and cytotoxicity. In this study, Fourier transform infrared (FT-IR) spectroscopy coupled with principal component analysis (PCA) and partial least-squares regression (PLSR) was applied to discriminate samples of P. polyphylla var. yunnanensis harvested in different years and determine the content of polyphyllin I, II, VI, and VII in P. polyphylla var. yunnanensis. Meanwhile, ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) was used to study the dynamic changes of P. polyphylla var. yunnanensis harvested in different years (4, 5, 7, 8, 9, 12, and 13 years old). According to the UPLC-MS/MS result, the optimum harvest time of P. polyphylla var. yunnanensis is 8 years, due to the highest yield of four active components. By the PCA model, P. polyphylla var. yunnanensis could be exactly discriminated, except that two 8-year-old samples were misclassified as 9-year-old samples. For the prediction of polyphyllin I, II, VI, and VII, the quantitative results are satisfactory, with a high value for the determination coefficient (R 2 ) and low values for the root-mean-square error of estimation (RMSEE), root-mean-square error of cross-validation (RMSECV), and root-mean-square error of prediction (RMSEP). In conclusion, FT-IR combined with chemometrics is a promising method to accurately discriminate samples of P. polyphylla var. yunnanensis harvested in different years and determine the content of polyphyllin I, II, VI, and VII in P. polyphylla var. yunnanensis.

  16. Comparison of simple and chelated amberlite IR-120 for ...

    African Journals Online (AJOL)

    In the present study, the efficiency of simple and chelating Amberlite IR-120 with α-nitroso β-naphthol (IR-αNβN) and with 8-hydroxy quinoline (IR-8HQ) has been compared for the removal of Cu(II) from aqueous solutions. The chelation was confirmed using different characterization techniques like SEM, TGA and FTIR.

  17. Synthesis and characterization of near-IR absorbing metal-free and zinc(II phthalocyanines modified with aromatic azo groups

    Directory of Open Access Journals (Sweden)

    Mukaddes Özçeşmeci

    2015-05-01

    Full Text Available Metal-free and zinc(II phthalocyanine complexes bearing peripheral (E-4-((2-hydroxynaphthalen-1-yldiazenyl units have been synthesized. Novel phthalonitrile derivative required for the preparation of phthalocyanine complexes was prepared by coupling 4-aminophthalonitrile and 2-naphthol. The structures of these new compounds were characterized by using elemental analyses, proton nuclear magnetic resonance, fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, fluorescence spectroscopy and mass spectrometry. In the UV-Vis spectra a broad absorption band appears for phthalocyanine complexes at around 450–500 nm resulting from azo-group introduced onto the phthalocyanine ring. The photophysical properties of metal-free and zinc(II phthalocyanines were studied in tetrahydrofuran.

  18. Synthesis and evaluation of new polynuclear organometallic Ru(II), Rh(III) and Ir(III) pyridyl ester complexes as in vitro antiparasitic and antitumor agents.

    Science.gov (United States)

    Chellan, Prinessa; Land, Kirkwood M; Shokar, Ajit; Au, Aaron; An, Seung Hwan; Taylor, Dale; Smith, Peter J; Riedel, Tina; Dyson, Paul J; Chibale, Kelly; Smith, Gregory S

    2014-01-14

    New polynuclear organometallic Platinum Group Metal (PGM) complexes containing di- and tripyridyl ester ligands have been synthesised and characterised using analytical and spectroscopic techniques including (1)H, (13)C NMR and infrared spectroscopy. Reaction of these polypyridyl ester ligands with either [Ru(p-cymene)Cl2]2, [Rh(C5Me5)Cl2]2 or [Ir(C5Me5)Cl2]2 dimers yielded the corresponding di- or trinuclear organometallic complexes. The polyaromatic ester ligands act as monodentate donors to each metal centre and this coordination mode was confirmed upon elucidation of the molecular structures for two of the dinuclear complexes. The di- and trinuclear PGM complexes synthesized were evaluated for inhibitory effects on the human protozoal parasites Plasmodium falciparum strain NF54 (chloroquine sensitive), Trichomonas vaginalis strain G3 and the human ovarian cancer cell lines, A2780 (cisplatin-sensitive) and A2780cisR (cisplatin-resistant) cell lines. All of the complexes were observed to have moderate to high antiplasmodial activities and the compounds with the best activities were evaluated for their ability to inhibit formation of synthetic hemozoin in a cell free medium. The in vitro antitumor evaluation of these complexes revealed that the trinuclear pyridyl ester complexes demonstrated moderate activities against the two tumor cell lines and were also less toxic to model non-tumorous cells.

  19. THE SWIFT GRB HOST GALAXY LEGACY SURVEY. II. REST-FRAME NEAR-IR LUMINOSITY DISTRIBUTION AND EVIDENCE FOR A NEAR-SOLAR METALLICITY THRESHOLD

    Energy Technology Data Exchange (ETDEWEB)

    Perley, D. A. [Department of Astronomy, California Institute of Technology, MC 249-17, 1200 East California Blvd., Pasadena, CA 91125 (United States); Tanvir, N. R. [Department of Physics and Astronomy, University of Leicester, University Road, Leicester, LE1 7RH (United Kingdom); Hjorth, J.; Fynbo, J. P. U.; Krühler, T. [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 København Ø (Denmark); Laskar, T.; Berger, E. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Chary, R. [US Planck Data Center, MS220-6, Pasadena, CA 91125 (United States); Postigo, A. de Ugarte [Instituto de Astrofísica de Andalucía (IAA-CSIC), Glorieta de la Astronomía s/n, E-18008, Granada (Spain); Levan, A. J. [Department of Physics, University of Warwick, Coventry CV4 7AL (United Kingdom); Michałowski, M. J. [Scottish Universities Physics Alliance, Institute for Astronomy, University of Edinburgh, Royal Observatory, Edinburgh, EH9 3HJ (United Kingdom); Schulze, S., E-mail: dperley@dark-cosmology.dk [Instituto de Astrofísica, Facultad de Física, Pontificia Universidad Católica de Chile, Vicuña Mackenna 4860, 7820436 Macul, Santiago 22 (Chile)

    2016-01-20

    We present rest-frame near-IR (NIR) luminosities and stellar masses for a large and uniformly selected population of gamma-ray burst (GRB) host galaxies using deep Spitzer Space Telescope imaging of 119 targets from the Swift GRB Host Galaxy Legacy Survey spanning 0.03 < z < 6.3, and we determine the effects of galaxy evolution and chemical enrichment on the mass distribution of the GRB host population across cosmic history. We find a rapid increase in the characteristic NIR host luminosity between z ∼ 0.5 and z ∼ 1.5, but little variation between z ∼ 1.5 and z ∼ 5. Dust-obscured GRBs dominate the massive host population but are only rarely seen associated with low-mass hosts, indicating that massive star-forming galaxies are universally and (to some extent) homogeneously dusty at high redshift while low-mass star-forming galaxies retain little dust in their interstellar medium. Comparing our luminosity distributions with field surveys and measurements of the high-z mass–metallicity relation, our results have good consistency with a model in which the GRB rate per unit star formation is constant in galaxies with gas-phase metallicity below approximately the solar value but heavily suppressed in more metal-rich environments. This model also naturally explains the previously reported “excess” in the GRB rate beyond z ≳ 2; metals stifle GRB production in most galaxies at z < 1.5 but have only minor impact at higher redshifts. The metallicity threshold we infer is much higher than predicted by single-star models and favors a binary progenitor. Our observations also constrain the fraction of cosmic star formation in low-mass galaxies undetectable to Spitzer to be small at z < 4.

  20. Dust Properties of C II Detected z ˜ 5.5 Galaxies: New HST/WFC3 Near-IR Observations

    Science.gov (United States)

    Barisic, I.; Faisst, A. L.; Capak, P. L.; Pavesi, R.; Riechers, D. A.; Scoville, N. Z.; Cooke, K.; Kartaltepe, J. S.; Casey, C. M.; Smolcic, V.

    2017-08-01

    We examine the rest-frame ultraviolet (UV) properties of 10 [C II]λ158 μm-detected galaxies at z ˜ 5.5 in COSMOS using new Hubble Space Telescope/Wide Field Camera 3 near-infrared imaging. Together with pre-existing 158 μm continuum and [C II] line measurements by the Atacama Large Millimeter/submillimeter Array, we study their dust attenuation properties on the IRX-β diagram, which connects the total dust emission (\\propto {IRX}={log}({L}{FIR}/{L}1600)) to the line-of-sight dust column (∝ β). We find systematically bluer UV continuum spectral slopes (β) compared to previous low-resolution ground-based measurements, which relieves some of the tension between models of dust attenuation and observations at high redshifts. While most of the galaxies are consistent with local starburst or Small Magellanic Cloud-like dust properties, we find galaxies with low IRX values and a large range in β that cannot be explained by models of a uniform dust distribution well mixed with stars. A stacking analysis of Keck/DEIMOS optical spectra indicates that these galaxies are metal-poor with young stellar populations that could significantly alter their spatial dust distribution.

  1. IR spectroscopy study of SBA-15 silicas functionalized with the ethylthiocarbamidepropyl groups and their interactions with Ag(I) and Hg(II) ions

    Science.gov (United States)

    Melnyk, Inna V.; Nazarchuk, Galyna I.; Václavíková, Miroslava; Zub, Yuriy L.

    2018-04-01

    Mesoporous structure of silica is determined by the type of template, but the introduction of functional groups during the synthesis has additional influence. The structure of SBA-15 may be violated by the introduction of long functions, such as ≡Si(CH2)3NHC(=S)NHC2H5. These ethylthiocarbamidepropyl groups can form complexes with metal ions in thiol or thione tautomeric forms. We determined that the 2D hexagonal p6 mm structure is preserved for SBA-15 with thiourea groups at maximal TEOS:trifunctional silane ratio (mol) = 10:2, which was confirmed by TEM and by the presence of an intense reflex in the small-angle region of diffractograms of the final product. It was shown that the obtained sorbents possess high kinetic characteristics. The experimental data fit pseudo-second-order kinetic equation, but the rate constants depend on the content of functional groups in the surface layer. Template Pluronic P-123 defines the porosity of functional mesoporous silica materials even at increasing content of trifunctional silane in the initial solution. Infrared spectroscopy analysis showed that thione form of thiourea ligand is prevalent on the surface of pores of mesoporous samples. However, during the sorption of silver(I) ions, there are both thione and thiol forms on the surface. Thione form is transformed into thiol with increasing concentration of mercury(II) ions in the sorption solution. Adsorption experiments showed that the SBA-15 silicas functionalized with ethylthiocarbamidepropyl groups had high selectivity for silver(I) ions and could concentrate Ag(I) ions from metal ions mixture at pH 2.

  2. Reaction of oxygen with γ, δ-ethylenic phenylhydrazones. Model reaction of end-group behavior in phenylhydrazine-accelerated oxidation of natural rubber

    International Nuclear Information System (INIS)

    El Hamdaoui, A.; Reyx, D.; Campistron, I.

    1995-01-01

    An accurate definition of terminal groups of chains in the liquid polymers obtained by the phenylhydrazine-accelerated oxidation of natural rubber is needed. The object of the work was to use model molecules to explore the behavior of γ,δ-ethylenic methylketone phenylhydrazone end-groups in oxidation conditions. We have investigated the synthesis and characterization of models of these hypothetical end-groups, methylketones and phenones 1, their phenylhydrazones 2, the α-(phenyldiazenyl)hydroperoxides 3 resulting from reaction of 2 with oxygen, and the α-(phenyldiazenyl)alcohols 4 as characteristic derivatives of 3 or as models of possible reduced structures in oxidized liquid natural rubber. Three original syntheses of γ,δ-ethylenic ketones were carried out. In the case of γ,δ-ethylenic phenylhydrazones, the oxidation led to the expected α-(phenyldiazenyl)hydroperoxides and to epoxide derivatives of α-(phenyldiazenyl)alcohols 5 and ketones 6. An intramolecular mechanism is proposed. The results are used to predict the possibilities of identification of the corresponding end-groups in liquid rubbers produced in this way. (authors). 16 refs., 12 figs., 3 tabs

  3. IOT Overview: IR Instruments

    Science.gov (United States)

    Mason, E.

    In this instrument review chapter the calibration plans of ESO IR instruments are presented and briefly reviewed focusing, in particular, on the case of ISAAC, which has been the first IR instrument at VLT and whose calibration plan served as prototype for the coming instruments.

  4. IR Hot Wave

    Energy Technology Data Exchange (ETDEWEB)

    Graham, T. B.

    2010-04-01

    The IR Hot Wave{trademark} furnace is a breakthrough heat treatment system for manufacturing metal components. Near-infrared (IR) radiant energy combines with IR convective heating for heat treating. Heat treatment is an essential process in the manufacture of most components. The controlled heating and cooling of a metal or metal alloy alters its physical, mechanical, and sometimes chemical properties without changing the object's shape. The IR Hot Wave{trademark} furnace offers the simplest, quickest, most efficient, and cost-effective heat treatment option for metals and metal alloys. Compared with other heat treatment alternatives, the IR Hot Wave{trademark} system: (1) is 3 to 15 times faster; (2) is 2 to 3 times more energy efficient; (3) is 20% to 50% more cost-effective; (4) has a {+-}1 C thermal profile compared to a {+-}10 C thermal profile for conventional gas furnaces; and (5) has a 25% to 50% smaller footprint.

  5. Joint IAEA/NEA IRS guidelines

    International Nuclear Information System (INIS)

    1997-01-01

    The Incident Reporting System (IRS) is an international system jointly operated by the International Atomic Energy Agency (IAEA) and the Nuclear Energy Agency of the Organization for Economic Cooperation and Development (OECD/NEA). The fundamental objective of the IRS is to contribute to improving the safety of commercial nuclear power plants (NPPs) which are operated worldwide. This objective can be achieved by providing timely and detailed information on both technical and human factors related to events of safety significance which occur at these plants. The purpose of these guidelines, which supersede the previous IAEA Safety Series No. 93 (Part II) and the NEA IRS guidelines, is to describe the system and to give users the necessary background and guidance to enable them to produce IRS reports meeting a high standard of quality while retaining the high efficiency of the system expected by all Member States operating nuclear power plants

  6. IR aperture measurement at β*=40 cm

    CERN Document Server

    Bruce, Roderik; Hermes, Pascal Dominik; Kwee-Hinzmann, Regina; Mereghetti, Alessio; Mirarchi, Daniele; Redaelli, Stefano; Salvachua Ferrando, Belen Maria; Skowronski, Piotr Krzysztof; Valentino, Gianluca; Valloni, Alessandra; CERN. Geneva. ATS Department

    2015-01-01

    This note summarizes MD 307, performed on August 27 2015, during which we measured with beam the global apertures at 6.5 TeV with IR1 and IR5 squeezed to β* =40 cm and a half crossing angle of 205 rad. The measurement technique involved opening collimators in steps, while inducing beam losses at each step, until the main loss location moved from the collimators to the global bottleneck in one of the triplets. Measurements were performed in both beams and planes, and each measurement gave the minimum triplet aperture over IR1 and IR5. The results are in very good agreement with theoretical predictions. At the end of the MD, an asynchronous beam dump test was performed with all collimators moved in to so-called 2-σ retraction settings. This MD is one in a series meant to address various open points for the reach in β* in Run II.

  7. Iš lietuvių kalbos žodžių istorijos: I. Lie. gáirė; II. Lie. tóbulas, tóbūlas

    Directory of Open Access Journals (Sweden)

    Birutė Kabašinskaitė

    2011-11-01

    Full Text Available AUS DER LITAUISCHEN WORTGESCHICHTE: I. Lit. gáirė. II. Lit. tóbulas, tóbūlasZusammenfassung1. Lit. gáirė ‘Zugluft; zugiger Ort’, gairùs ‘zugig’ haben, wie bisher übersehen wurde, eine Entsprechung in air. gaith, mir. gaíth, goíth, nir. gaoth f. ‘Wind’ < urkelt. *gai̯tā-. Die Grundlage der litauischen Wörter bildet ein Adjektiv *gaĩra-s ‘zugig’, das in nlit. gairùs fortlebt. Vom Adjektiv *gairas ‘zugig’ wurde mit dem Suffix -ē in Kombination mit Métatonie rude gáirė (1 als Abstraktum ‘Zugig-Sein, das dem-Zugwind-ausgesetzt-Sein’ abgeleitet. Diese Bedeutung bildet den Ausgang für eine weitere semantische Entwicklung, deren Ergebnis etwa in folgender Weise aufzufächern ist: 1. ‘Durchzug, Luftzug, Zugwind’; 2. ‘ein dem Wind ausgesetzter Ort, ein vom Wind durchwehter Ort, zugiger Ort’; 2a. ‘hochgelegener Ort, Erhebung im Gelände’; 3. ‘etwas vom Wind Bewegtes, etwas im Wind Flatterndes, das die Windrichtung anzeigt, Wetterfahne, Windfahne, Windzeiger’; 3a. ‘eine in den Boden gesteckte Stange mit einer Wetterfahne’; 3b. ‘in den Boden gesteckte Stange zur Stütze sich in die Höhe rankender Pflanzen’; 3c. ‘(allgemein Kennzeichen, Merkmal, Markierungszeichen’. Die im Litauischen zu beobachtende Bedeutungsentwicklung läßt es möglich erscheinen, gr. χαίτη ‘frei herabwallendes Haar, fliegendes Haupthaar (von Menschen; Mähne (von Pferden’ als ‘das im Wind flatternde (Haar’ mit kelt. *gai̯tā- ‘Wind’ unter einem urindogermanischen Ansatz *ghái̯-tah2- (oder *ghh2ái̯-tah2- zu vereinen. Für das Litauische wäre dann von einem Adjektiv *gha i̯-ro- auszugehen.2. Die Herkunft von lit. tóbulas, tóbūlas kann auf zwei verschiedene Weisen erklärt werden. Bei beiden Deutungen ergibt sich die Schwierigkeit, daß mit nicht belegtem (wohl aber mit als möglicherweise vorhanden anzunehmendem Material zu argumentieren ist. Ein Vorteil der ersten Erkl

  8. Structure and end-group analysis of complex hexanediol-neopentylglycol-adipic acid copolyesters by matrix-assisted laser desorption/ionization collision-induced dissociation tandem mass spectrometry.

    Science.gov (United States)

    Weidner, Steffen M; Falkenhagen, Jana; Knop, Karin; Thünemann, Andreas

    2009-09-01

    Sequences and end groups of complex copolyesters were determined by fragmentation analysis by means of matrix-assisted laser desorption/ionization collision-induced dissociation tandem mass spectrometry (MALDI CID MS/MS). The complexity of the crude copolyester mixture was reduced by a chromatographic separation followed by a MALDI time-of-flight (TOF) investigation of fractions. Due to overlapping compositional and end-group information a clear assignment of end groups was very difficult. However, the fragmentation of suitable precursor ions resulted in typical fragment ion patterns and, therefore, enabled a fast and unambiguous determination of the end groups and composition of this important class of polymers. Copyright (c) 2009 John Wiley & Sons, Ltd.

  9. Studies on a novel multi-sensitive hydrogel: influence of the biomimetic phosphorylcholine end-groups on the PEO-PPO-PEO tri-block co-polymers.

    Science.gov (United States)

    Meng, Sheng; Guo, Zhang; Wang, Qiong; Liu, ZongJun; Wang, QiHong; Zhong, Wei; Du, QiangGuo

    2011-01-01

    In the present study, a biomimetic phosphorylcholine group was employed in the end-capping modification of PEO-PPO-PEO tri-block co-polymers (Pluronic(®)). The structures of the resulting materials were characterized by (1)H-NMR and GPC. The effects of the additional phosphorylcholine end-groups to the thermo-sensitive sol-gel transition behaviors of the aqueous solutions of the resulting polymers were studied by rheology test in neutral (0.1 M NaCl) aqueous solutions and in acidic solutions (pH 3). It was found that the phosphorylcholine-end-capped Pluronic hydrogels still kept their thermo-sensitive mechanical properties with a slight change on the sol-gel transition behaviors. The phosphorylcholine-modified Pluronics exhibited a response to the change of the pH value, which made this kind of material a multi-sensitive hydrogel system. Also, the resulting polymers showed improved hemocompatibilities in the blood coagulation test using full human blood.

  10. FT-IR Study of CO2 Adsorption in a Dynamic Copper(II) Benzoate-Pyrazine Host with CO2-CO2 Interactions in the Adsorbed State

    Energy Technology Data Exchange (ETDEWEB)

    Kauffman, Kristi L. [National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); Culp, Jeffrey T. [National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); Goodman, Angela [National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); Matranga, Christopher [National Energy Technology Lab. (NETL), Pittsburgh, PA (United States)

    2011-02-10

    A detailed correlation is presented between the in situ Fourier transform-infrared (FT-IR) spectra of adsorbed CO2, CuBzPyz host bands, and CO2 adsorption sites using previously reported crystal structures of CO2- loaded CuBzPyz and CO2 adsorption. isotherms. Through the analysis of both in situ attenuated total reflectance FT-IR spectra taken at several points on the high pressure isotherm and in situ transmission FT-IR spectra acquired at low pressures and cryogenic temperatures, we provide additional insight into the pore-filling mechanism of CO2 on the structurally dynamic CuBzPyz host. The FT-IR spectrum of adsorbed CO2 shows distinct v2 and v3 spectral features that can be attributed to known CO2 adsorption sites observed in the reported crystal structure of the CO2-saturated phase of CuBzPyz. The availability of detailed high quality CO2-loaded structural data for CuBzPyz makes this system a case study for associating infrared spectral features with CO2 adsorption sites and should prove valuable for future interpretations of CO2 host-guest and guest-guest interactions when X-ray quality structural data is unavailable.

  11. IR and the Earth

    DEFF Research Database (Denmark)

    Corry, Olaf; Stevenson, Hayley

    2017-01-01

    politics and offers an account of how this builds on older ways in which the natural world has made up part of the stuff of international politics. Second, it surveys the main traditions and approaches to studying International Relations of the environment, painting a picture of diversification in two......, ‘what has the environment ever done for IR?’, before the plan for the rest of the book sketches the content and direction of the ensuing chapters that explore the problematique of International Relations and the Earth....

  12. Detailed IR aperture measurements

    CERN Document Server

    Bruce, Roderik; Garcia Morales, Hector; Giovannozzi, Massimo; Hermes, Pascal Dominik; Mirarchi, Daniele; Quaranta, Elena; Redaelli, Stefano; Rossi, Carlo; Skowronski, Piotr Krzysztof; Wretborn, Sven Joel; CERN. Geneva. ATS Department

    2016-01-01

    MD 1673 was carried out on October 5 2016, in order to investigate in more detail the available aperture in the LHC high-luminosity insertions at 6.5 TeV and β∗=40 cm. Previous aperture measurements in 2016 during commissioning had shown that the available aperture is at the edge of protection, and that the aperture bottleneck at β∗=40 cm in certain cases is found in the separation plane instead of in the crossing plane. Furthermore, the bottlenecks were consistently found in close to the upstream end of Q3 on the side of the incoming beam, and not in Q2 on the outgoing beam as expected from calculations. Therefore, this MD aimed at measuring IR1 and IR5 separately (at 6.5 TeV and β∗=40 cm, for 185 µrad half crossing angle), to further localize the bottlenecks longitudinally using newly installed BLMs, investigate the difference in aperture between Q2 and Q3, and to see if any aperture can be gained using special orbit bumps.

  13. The IRS-1 signaling system.

    Science.gov (United States)

    Myers, M G; Sun, X J; White, M F

    1994-07-01

    Insulin-receptor substrate 1 (IRS-1) is a principal substrate of the receptor tyrosine kinase for insulin and insulin-like growth factor 1, and a substrate for a tyrosine kinase activated by interleukin 4. IRS-1 undergoes multisite tyrosine phosphorylation and mediates downstream signals by 'docking' various proteins that contain Src homology 2 domains. IRS-1 appears to be a unique molecule; however, 4PS, a protein found mainly in hemopoietic cells, may represent another member of this family.

  14. Poly(ethylene glycol or Poly(ethylene oxide?: Magnitude of end-group Contribution to the Partitioning of Ethylene Oxide Oligomers and Polymers between Water and Organic Phases

    Directory of Open Access Journals (Sweden)

    Spitzer Marcos

    2002-01-01

    Full Text Available PEO partitioning from water to CH2Cl2 and CHCl3 increases with its molar mass, leveling off at ca. 3 000 g mol-1. Such a behaviour is related to PEO end-group contributions, suggesting a polyglycol to polyether transition at ca. 3 000 g mol-1.

  15. IR seeker simulator and IR scene generation to evaluate IR decoy effectiveness; 2005BU1-EO

    NARCIS (Netherlands)

    Jong, W. de; Dam, F.A.M.; Kunz, G.J.; Schleijpen, H.M.A.

    2005-01-01

    IR decoys can be an effective countermeasure against IR guided anti ship missiles. However, it's not so easy to determine how the decoys should be deployed to get maximum effectiveness. A limitation of trials is that results are obtained for the specific trial condition only. Software tools have

  16. Ultrafast 2D IR microscopy.

    Science.gov (United States)

    Baiz, Carlos R; Schach, Denise; Tokmakoff, Andrei

    2014-07-28

    We describe a microscope for measuring two-dimensional infrared (2D IR) spectra of heterogeneous samples with μm-scale spatial resolution, sub-picosecond time resolution, and the molecular structure information of 2D IR, enabling the measurement of vibrational dynamics through correlations in frequency, time, and space. The setup is based on a fully collinear "one beam" geometry in which all pulses propagate along the same optics. Polarization, chopping, and phase cycling are used to isolate the 2D IR signals of interest. In addition, we demonstrate the use of vibrational lifetime as a contrast agent for imaging microscopic variations in molecular environments.

  17. CCD and IR array controllers

    Science.gov (United States)

    Leach, Robert W.; Low, Frank J.

    2000-08-01

    A family of controllers has bene developed that is powerful and flexible enough to operate a wide range of CCD and IR focal plane arrays in a variety of ground-based applications. These include fast readout of small CCD and IR arrays for adaptive optics applications, slow readout of large CCD and IR mosaics, and single CCD and IR array operation at low background/low noise regimes as well as high background/high speed regimes. The CCD and IR controllers have a common digital core based on user- programmable digital signal processors that are used to generate the array clocking and signal processing signals customized for each application. A fiber optic link passes image data and commands to VME or PCI interface boards resident in a host computer to the controller. CCD signal processing is done with a dual slope integrator operating at speeds of up to one Megapixel per second per channel. Signal processing of IR arrays is done either with a dual channel video processor or a four channel video processor that has built-in image memory and a coadder to 32-bit precision for operating high background arrays. Recent developments underway include the implementation of a fast fiber optic data link operating at a speed of 12.5 Megapixels per second for fast image transfer from the controller to the host computer, and supporting image acquisition software and device drivers for the PCI interface board for the Sun Solaris, Linux and Windows 2000 operating systems.

  18. Research resource: new and diverse substrates for the insulin receptor isoform a revealed by quantitative proteomics after stimulation with igf-ii or insulin

    DEFF Research Database (Denmark)

    Morcavallo, Alaide; Gaspari, Marco; Pandini, Giuseppe

    2011-01-01

    The isoform A of the insulin receptor (IR) (IR-A) is a bifunctional receptor, because it binds both insulin and IGF-II. IR-A activation by IGF-II plays a role in development, but its physiological role in adults is unknown. IGF-II signaling through IR-A is deregulated in cancer and favors tumor p...

  19. Ligand binding affinity at the insulin receptor isoform A (IR-A and subsequent IR-A tyrosine phosphorylation kinetics are important determinants of mitogenic biological outcomes.

    Directory of Open Access Journals (Sweden)

    Harinda eRajapaksha

    2015-07-01

    Full Text Available The insulin receptor (IR is a tyrosine kinase receptor that can mediate both metabolic and mitogenic biological actions. The IR isoform-A (IR-A arises from alternative splicing of exon 11 and has different ligand binding and signalling properties compared to the IR isoform-B. The IR-A not only binds insulin but also insulin-like growth factor-II (IGF-II with high affinity. IGF-II acting through the IR-A promotes cancer cell proliferation, survival and migration by activating some unique signalling molecules compared to those activated by insulin. This observation led us to investigate whether the different IR-A signalling outcomes in response to IGF-II and insulin could be attributed to phosphorylation of a different subset of IR-A tyrosine residues or to the phosphorylation kinetics. We correlated IR-A phosphorylation to activation of molecules involved in mitogenic and metabolic signalling (MAPK and Akt and receptor internalisation rates (related to mitogenic signalling. We also extended this study to incorporate two ligands that are known to promote predominantly mitogenic ([His4, Tyr15, Thr49, Ile51] IGF-I, qIGF-I or metabolic (S597 peptide biological actions, to see if common mechanisms can be used to define mitogenic or metabolic signalling through the IR-A. The 3-fold lower mitogenic action of IGF-II compared to insulin was associated with a decreased potency in activation of Y960, Y1146, Y1150, Y1151, Y1316 and Y1322, in MAPK phosphorylation and in IR-A internalization. With the poorly mitogenic S597 peptide it was a decreased rate of tyrosine phosphorylation rather than potency that was associated with a low mitogenic potential. We conclude that both decreased affinity of IR-A binding and the kinetics of IR-A phosphorylation can independently lead to a lower mitogenic activity. None of the studied parameters could account for the lower metabolic activity of qIGF-I.

  20. A importância do estado excitado 3MLCT de compostos de Ru(II, Re(I e Ir(III no desenvolvimento de fotossensores, oleds e fotorredução de CO2

    Directory of Open Access Journals (Sweden)

    Andressa V. Müller

    Full Text Available The photochemistry and photophysics of coordination compounds have been extensively investigated not only because their structure, stability, reactivity dependence on the metal center oxidation state and the coordinated ligand; but also for their electronic transitions in a wide range of visible radiation. The knowledge of light absorption, excited state deactivation, sensitization and quenching processes are crucial to their manipulation aiming the development of systems capable of execute useful functions such as photosensors and/or probes, luminescent devices and molecular systems to convert sunlight into other types of energy. In this review, the progresses and challenges of biomolecules photosensors, organic light emitting diodes and CO2 photoreduction catalysts based on ruthenium(II, rhenium(I or iridium(III coordination compounds are discussed based on their photochemical and photophysical processes.

  1. Validation of the thermal code of RadTherm-IR, IR-Workbench, and F-TOM

    Science.gov (United States)

    Schwenger, Frédéric; Grossmann, Peter; Malaplate, Alain

    2009-05-01

    System assessment by image simulation requires synthetic scenarios that can be viewed by the device to be simulated. In addition to physical modeling of the camera, a reliable modeling of scene elements is necessary. Software products for modeling of target data in the IR should be capable of (i) predicting surface temperatures of scene elements over a long period of time and (ii) computing sensor views of the scenario. For such applications, FGAN-FOM acquired the software products RadTherm-IR (ThermoAnalytics Inc., Calumet, USA; IR-Workbench (OKTAL-SE, Toulouse, France). Inspection of the accuracy of simulation results by validation is necessary before using these products for applications. In the first step of validation, the performance of both "thermal solvers" was determined through comparison of the computed diurnal surface temperatures of a simple object with the corresponding values from measurements. CUBI is a rather simple geometric object with well known material parameters which makes it suitable for testing and validating object models in IR. It was used in this study as a test body. Comparison of calculated and measured surface temperature values will be presented, together with the results from the FGAN-FOM thermal object code F-TOM. In the second validation step, radiances of the simulated sensor views computed by RadTherm-IR and IR-Workbench will be compared with radiances retrieved from the recorded sensor images taken by the sensor that was simulated. Strengths and weaknesses of the models RadTherm-IR, IR-Workbench and F-TOM will be discussed.

  2. #Occupy IR: Exposing the Orthodoxy

    Directory of Open Access Journals (Sweden)

    Ivan Manokha

    2012-03-01

    Full Text Available The #occupy IR/IPE initiative was created in response to the #occupy movement, whose own roots can be traced backed to the latest crisis of global finance. In this contribution, we link #occupy and the crisis in a different way. We argue that we must occupy IR/IPE because of the discipline’s failure to apprehend and acknowledge the crisis itself, just as the Occupy movement is calling for their overarching authorities to notice and help address the social and economic inequalities produced by this crisis. More precisely, we argue that the dominant academic orthodoxy, via a series of continuously reproduced dichotomies, has rendered IR/IPE incapable of dealing with a phenomenon as complex as the financial crisis...

  3. Impaired Insulin Signaling is Associated with Hepatic Mitochondrial Dysfunction in IR+/−-IRS-1+/− Double Heterozygous (IR-IRS1dh Mice

    Directory of Open Access Journals (Sweden)

    Andras Franko

    2017-05-01

    Full Text Available Mitochondria play a pivotal role in energy metabolism, but whether insulin signaling per se could regulate mitochondrial function has not been identified yet. To investigate whether mitochondrial function is regulated by insulin signaling, we analyzed muscle and liver of insulin receptor (IR+/−-insulin receptor substrate-1 (IRS-1+/− double heterozygous (IR-IRS1dh mice, a well described model for insulin resistance. IR-IRS1dh mice were studied at the age of 6 and 12 months and glucose metabolism was determined by glucose and insulin tolerance tests. Mitochondrial enzyme activities, oxygen consumption, and membrane potential were assessed using spectrophotometric, respirometric, and proton motive force analysis, respectively. IR-IRS1dh mice showed elevated serum insulin levels. Hepatic mitochondrial oxygen consumption was reduced in IR-IRS1dh animals at 12 months of age. Furthermore, 6-month-old IR-IRS1dh mice demonstrated enhanced mitochondrial respiration in skeletal muscle, but a tendency of impaired glucose tolerance. On the other hand, 12-month-old IR-IRS1dh mice showed improved glucose tolerance, but normal muscle mitochondrial function. Our data revealed that deficiency in IR/IRS-1 resulted in normal or even elevated skeletal muscle, but impaired hepatic mitochondrial function, suggesting a direct cross-talk between insulin signaling and mitochondria in the liver.

  4. Impaired Insulin Signaling is Associated with Hepatic Mitochondrial Dysfunction in IR+/--IRS-1+/-Double Heterozygous (IR-IRS1dh) Mice.

    Science.gov (United States)

    Franko, Andras; Kunze, Alexander; Böse, Marlen; von Kleist-Retzow, Jürgen-Christoph; Paulsson, Mats; Hartmann, Ursula; Wiesner, Rudolf J

    2017-05-30

    Mitochondria play a pivotal role in energy metabolism, but whether insulin signaling per se could regulate mitochondrial function has not been identified yet. To investigate whether mitochondrial function is regulated by insulin signaling, we analyzed muscle and liver of insulin receptor (IR) +/- -insulin receptor substrate-1 (IRS-1) +/- double heterozygous (IR-IRS1dh) mice, a well described model for insulin resistance. IR-IRS1dh mice were studied at the age of 6 and 12 months and glucose metabolism was determined by glucose and insulin tolerance tests. Mitochondrial enzyme activities, oxygen consumption, and membrane potential were assessed using spectrophotometric, respirometric, and proton motive force analysis, respectively. IR-IRS1dh mice showed elevated serum insulin levels. Hepatic mitochondrial oxygen consumption was reduced in IR-IRS1dh animals at 12 months of age. Furthermore, 6-month-old IR-IRS1dh mice demonstrated enhanced mitochondrial respiration in skeletal muscle, but a tendency of impaired glucose tolerance. On the other hand, 12-month-old IR-IRS1dh mice showed improved glucose tolerance, but normal muscle mitochondrial function. Our data revealed that deficiency in IR/IRS-1 resulted in normal or even elevated skeletal muscle, but impaired hepatic mitochondrial function, suggesting a direct cross-talk between insulin signaling and mitochondria in the liver.

  5. Mechanism of CO 2 Fixation by Ir I -X Bonds (X = OH, OR, N, C)

    KAUST Repository

    Vummaleti, Sai V. C.

    2015-09-08

    Density functional theory calculations have been used to investigate the CO2 fixation mechanism proposed by Nolan et al. for the IrI complex [Ir(cod)(IiPr)(OH)] (1; cod = 1,5-cyclooctadiene; IiPr = 1,3-diisopropylimidazol-2-ylidene) and its derivatives. For 1, our results suggest that CO2 insertion is the rate-limiting step rather than the dimerization step. Additionally, in agreement with the experimental results, our results show that CO2 insertion into the Ir-OR1 (R1 = H, methyl, and phenyl) and Ir-N bonds is kinetically facile, and the calculated activation energies span a range of only 12.0-23.0 kcal/mol. Substantially higher values (35.0-50.0 kcal/mol) are reported for analogous Ir-C bonds. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Novel oligocarbosilazanes bearing promesogenic end groups

    Directory of Open Access Journals (Sweden)

    2009-07-01

    Full Text Available A series of novel oligomers with promesogenic groups on both termini were prepared by a hydrosilylation reaction between well-defined telechelic oligocarbosilazanes end-fitted with vinylsilane (SiVi groups and promesogenic compounds containing one reactive hydrosilane (SiH group. We investigated the correlations between the structure of the resulting mesogen end-capped oligomers and their phase behavior as examined by differential scanning calorimetry (DSC and polarizing optical microscopy (POM.

  7. Carbosilane Metallodendrimers with Titanocene Dichloride end Groups

    Czech Academy of Sciences Publication Activity Database

    Strašák, Tomáš; Čermák, Jan; Sýkora, Jan; Horský, Jiří; Walterová, Zuzana; Jaroschik, F.; Harakat, D.

    2012-01-01

    Roč. 31, č. 19 (2012), s. 6779-6786 ISSN 0276-7333 R&D Projects: GA MŠk(CZ) LC06070 Institutional support: RVO:67985858 ; RVO:61389013 Keywords : dendrimers * titanocene * hydrosilylation Subject RIV: CC - Organic Chemistry Impact factor: 4.145, year: 2012

  8. Shaped Ir-Ni bimetallic nanoparticles for minimizing Ir utilization in oxygen evolution reaction.

    Science.gov (United States)

    Lim, Jinkyu; Yang, Sungeun; Kim, Chanyeon; Roh, Chi-Woo; Kwon, Yongwoo; Kim, Yong-Tae; Lee, Hyunjoo

    2016-04-25

    Shaped Ir-Ni bimetallic nanoparticles were synthesized and used for electrocatalytic oxygen evolution reaction (OER). The obtained bimetallic nanoparticles showed significantly enhanced Ir mass activity and durability compared with Ir nanoparticles.

  9. WFC3 IR subarray anomaly

    Science.gov (United States)

    Bushouse, Howard

    2009-07-01

    Certain combinations of WFC3 IR subarray size and sample sequence yield images that show a sharp change in background level that exactly bi-sects each detector amplifier quadrant. The change in level has an amplitude of a few DN per pixel. The cause of this anomaly and its apparent correlation with subarray size and sample sequence is not understood. Given the 4 available subarray sizes and 11 available readout sample sequences, there are a total of 44 possible subarray mode readout combinations. To date, 14 of those combinations have been used on-orbit in either calibration and GO programs. Of those, 3 combinations show the anomaly. This program will obtain IR dark exposures in the remaining 30 readout combinations that have not yet been explored. This will add to our knowledge of which combinations show the anomaly and will therefore help us to understand its origin.

  10. Oferta ir akceptas vartojimo sutartyse

    OpenAIRE

    Ežerskytė, Ramunė

    2011-01-01

    Sutarčiai sudaryti paprastai reikia, kad viena šalis pasiūlytų sudaryti sutartį (oferta), o kita šalis sutiktų su pasiūlymu (akceptas). Sutarčių įvairovėje išskiriamos vartojimo sutartys, kurios dėl silpnesnės šalies apsaugos principo įgyvendinimo pasižymi tam tikrais ypatumais. Vartojimo sutarčių sudarymas pateikiant ofertą ir akceptą yra šio magistro baigiamojo darbo objektas. Magistro baigiamąjį darbą sudaro trys dalys. Pirmojoje darbo dalyje analizuojama vartojimo sutarties sąvoka ir spec...

  11. Hidroenergijos panaudojimo raida ir perspektyvos

    OpenAIRE

    Vizbaras, Andrius

    2008-01-01

    Ilgą laiko tarpą hidroenergetika vertinta kaip sėkminga žmonijos vystimosi ir akivaizdžios naudos išraiška, pastaruoju metu siejama su reikšmingu poveikiu gamtinei aplinkai bei įtaka klimato kaitai. Lygumų šalyse, net ir mažos galios hidroelektrinių statyba pareikalauja didelių užliejamų žemės plotų. Šiame darbe atlikome aštuoniasdešimties iki 2007 metų pastatytų hidroelektrinių poveikio aplinkai analizę bei aptarėme galimą „Lietuvos hidroenergetinių išteklių schemoje„ numatytų statyti HE pov...

  12. Synthesis and Characterization of Multimetallic Fe(II) and Mn(II ...

    African Journals Online (AJOL)

    Iron(II) and Manganese(II) complexes of the resulting ligand were obtained from its reactions with Fe(II) and Mn(II) salts in absolute methanol for the metal to ligand ratio 2:3. These complexes were characterized by Solubility, Conductivity, IR and UV-VIS spectrometry, elemental analysis and mass spectrometry. Keywords: ...

  13. Syntheses and spectroscopic properties of mercury(II) and nickel(II ...

    African Journals Online (AJOL)

    Mercury(II) complex, [Hg2(BPTU-2H)Cl2] and nickel(II) complex, [Ni(BPTU-H)2] were prepared by reacting Bis(N-phenylthiourea), BPTU, with mercury(II) chloride and nickel(II) acetate respectively. The complexes were characterized by IR, diffuse reflectance, 1H NMR spectra and elemental analysis. BPTU acts as ...

  14. Climate Prediction Center IR 4km Dataset

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — CPC IR 4km dataset was created from all available individual geostationary satellite data which have been merged to form nearly seamless global (60N-60S) IR...

  15. Isolated Gramicidin Peptides Probed by IR Spectroscopy

    NARCIS (Netherlands)

    Rijs, A. M.; Kabelac, M.; Abo-Riziq, A.; Hobza, P.; de Vries, M. S.

    2011-01-01

    We report double-resonant IR/UV ion-dip spectroscopy of neutral gramicidin peptides in the gas phase. The IR spectra of gramicidin A and C, recorded in both the 1000 cm(-1) to 1800 cm(-1) and the 2700 to 3750 cm(-1) region, allow structural analysis. By studying this broad IR range, various local

  16. Diffraction-limited IR Microspectroscopy with IRENI

    Science.gov (United States)

    J. Sedlmair; B. Illman; M. Unger; C. Hirschmugl

    2012-01-01

    In a unique way, IRENI (Infrared environmental Imaging), operated at the Synchrotron Radiation Center in Madison, combines IR spectroscopy and IR imaging, revealing the chemical morphology of a sample. Most storage ring based IR confocal microscopes have to overcome a trade-off between spatial resolution versus...

  17. Pulsating stars in ω Centauri. Near-IR properties and period-luminosity relations

    Directory of Open Access Journals (Sweden)

    Navarrete Camila

    2017-01-01

    Full Text Available ω Centauri (NGC 5139 contains many variable stars of different types, including the pulsating type II Cepheids, RR Lyrae and SX Phoenicis stars. We carried out a deep, wide-field, near-infrared (IR variability survey of ω Cen, using the VISTA telescope. We assembled an unprecedented homogeneous and complete J and KS near-IR catalog of variable stars in the field of ω Cen. In this paper we compare optical and near-IR light curves of RR Lyrae stars, emphasizing the main differences. Moreover, we discuss the ability of near-IR observations to detect SX Phoenicis stars given the fact that the amplitudes are much smaller in these bands compared to the optical. Finally, we consider the case in which all the pulsating stars in the three different variability types follow a single period-luminosity relation in the near-IR bands.

  18. Synthesis and spectroscopic studies of biologically active tetraazamacrocyclic complexes of Mn(II, Co(II, Ni(II, Pd(II and Pt(II

    Directory of Open Access Journals (Sweden)

    Monika Tyagi

    2014-01-01

    Full Text Available Complexes of Mn(II, Co(II, Ni(II, Pd(II and Pt(II were synthesized with the macrocyclic ligand, i.e., 2,3,9,10-tetraketo-1,4,8,11-tetraazacycoletradecane. The ligand was prepared by the [2 + 2] condensation of diethyloxalate and 1,3-diamino propane and characterized by elemental analysis, mass, IR and 1H NMR spectral studies. All the complexes were characterized by elemental analysis, molar conductance, magnetic susceptibility measurements, IR, electronic and electron paramagnetic resonance spectral studies. The molar conductance measurements of Mn(II, Co(II and Ni(II complexes in DMF correspond to non electrolyte nature, whereas Pd(II and Pt(II complexes are 1:2 electrolyte. On the basis of spectral studies an octahedral geometry has been assigned for Mn(II, Co(II and Ni(II complexes, whereas square planar geometry assigned for Pd(II and Pt(II. In vitro the ligand and its metal complexes were evaluated against plant pathogenic fungi (Fusarium odum, Aspergillus niger and Rhizoctonia bataticola and some compounds found to be more active as commercially available fungicide like Chlorothalonil.

  19. Coprates Chasma Landslides in IR

    Science.gov (United States)

    2005-01-01

    [figure removed for brevity, see original site] Today's daytime IR image is of a portion of Coprates Chasma, part of Valles Marineris. As with yesterday's image, this image shows multiple large landslides. Image information: IR instrument. Latitude -8.2, Longitude 300.2 East (59.8 West). 100 meter/pixel resolution. Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time. NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the prime contractor for the Odyssey project, and developed and built the orbiter. Mission operations are conducted jointly from Lockheed Martin and from JPL, a division of the California Institute of Technology in Pasadena.

  20. From UV/IR mixing to closed strings

    International Nuclear Information System (INIS)

    Lopez, Esperanza

    2003-01-01

    It was shown in [1] that the leading UV/IR mixing effects in noncommutative gauge theories on D-branes are able to capture information about the closed string spectrum of the parent string theory. The analysis was carried out for D-branes on nonsupersymmetric C 3 /Z N orbifolds of Type IIB. In this paper we consider D-branes on twisted circles compactifications of Type II string theory. We find that the signs of the leading UV/IR mixing effects know about the (mass) 2 gap between the lowest modes in NSNS and RR closed string towers. Moreover, the relevant piece of the field theory effective action can be reproduced purely in the language of closed strings. Remarkably, this approach unifies in a single structure, that of a closed string exchange between D-branes, both the leading planar and nonplanar effects associated to the absence of supersymmetry. (author)

  1. Innovations in IR projector arrays

    Science.gov (United States)

    Cole, Barry E.; Higashi, B.; Ridley, Jeff A.; Holmen, J.; Newstrom, K.; Zins, C.; Nguyen, K.; Weeres, Steven R.; Johnson, Burgess R.; Stockbridge, Robert G.; Murrer, Robert Lee; Olson, Eric M.; Bergin, Thomas P.; Kircher, James R.; Flynn, David S.

    2000-07-01

    In the past year, Honeywell has developed a 512 X 512 snapshot scene projector containing pixels with very high radiance efficiency. The array can operate in both snapshot and raster mode. The array pixels have near black body characteristics, high radiance outputs, broad band performance, and high speed. IR measurements and performance of these pixels will be described. In addition, a vacuum probe station that makes it possible to select the best die for packaging and delivery based on wafer level radiance screening, has been developed and is in operation. This system, as well as other improvements, will be described. Finally, a review of the status of the present projectors and plans for future arrays is included.

  2. cobalt (ii), nickel (ii)

    African Journals Online (AJOL)

    DR. AMINU

    ABSTRACT. The manganese (II), cobalt (II), nickel (II) and copper (II) complexes of N, N' – bis(benzoin)ethylenediiminato have been prepared and characterized by infrared, elemental analysis, conductivity measurements and solubility. The potentiometric, and elemental analyses studies of the complexes revealed 1:1 ...

  3. IR Thermography NDE of ISS Radiator Panels

    Science.gov (United States)

    Koshti, Ajay; Winfree, William; Morton, Richard; Wilson, Walter; Reynolds, Gary

    2010-01-01

    The presentation covers an active and a passive infrared (IR) thermography for detection of delaminations in the radiator panels used for the International Space Station (ISS) program. The passive radiator IR data was taken by a NASA astronaut in an extravehicular activity (EVA) using a modified FLIR EVA hand-held camera. The IR data could be successfully analyzed to detect gross facesheet disbonds. The technique used the internal hot fluid tube as the heat source in analyzing the IR data. Some non-flight ISS radiators were inspected using an active technique of IR flash thermography to detect disbond of face sheet with honeycomb core, and debonds in facesheet overlap areas. The surface temperature and radiated heat emission from flight radiators is stable during acquisition of the IR video data. This data was analyzed to detect locations of unexpected surface temperature gradients. The flash thermography data was analyzed using derivative analysis and contrast evolutions. Results of the inspection are provided.

  4. Feminist Challenge to the Mainstream IR

    OpenAIRE

    Aydın, Gülşen

    2016-01-01

    This study deals with the Feminist challenge to the Mainstream International Relations Discipline (IR) - rationalist theories, especially Realism - and the mainstream's responses to this challenge. It addresses the issue in five steps. Firstly, it sheds light on how Feminism is related to International Relations. Secondly, it examines how Feminist IR theorists criticize the Mainstream IR due to its state-centric approach and argue that being obsessed with anarchic international system prevent...

  5. Measuring Collimator Infrared (IR) Spectral Transmission

    Science.gov (United States)

    2016-05-01

    TECHNICAL REPORT RDMR-WD-16-15 MEASURING COLLIMATOR INFRARED ( IR ) SPECTRAL TRANSMISSION Christopher L. Dobbins Weapons...AND DATES COVERED Final 4. TITLE AND SUBTITLE Measuring Collimator Infrared ( IR ) Spectral Transmission 5. FUNDING NUMBERS 6. AUTHOR(S) Christopher L...release; distribution is unlimited. 12b. DISTRIBUTION CODE A 13. ABSTRACT (Maximum 200 Words) Several Infrared ( IR ) imaging systems have been measured

  6. How to remedy Eurocentrism in IR?

    DEFF Research Database (Denmark)

    Bilgin, Pinar

    2016-01-01

    While IR's Eurocentric limits are usually acknowledged, what those limits mean for theorizing about the international is seldom clarified. In The Global Transformation, Buzan and Lawson offer a 'composite approach' that goes some way towards addressing IR's Eurocentrism, challenging existing myths...... helps us recognize what is missing from IR theorizing - conceptions of the international by 'others' who also constitute the international. I illustrate this point by focussing on a landmark text on Ottoman history, Ortayll's The Longest Century of the Empire....

  7. Increasing Medical Student Exposure to IR through Integration of IR into the Gross Anatomy Course.

    Science.gov (United States)

    DePietro, Daniel M; Kiefer, Ryan M; Redmond, Jonas W; Workman, Alan D; Nadolski, Gregory J; Gade, Terence P; Trerotola, Scott O; Hunt, Stephen J

    2017-10-01

    To compare medical student knowledge of and interest in interventional radiology (IR) before and after the integration of an IR lecture series within the gross anatomy course. Four elective IR lectures were scheduled to coincide with the relevant anatomy dissection curriculum. Anonymous surveys were distributed to 146 students before and after the lectures regarding students' knowledge of and interest in IR, responsibilities of an IR physician, and IR training pathways. Those who did not attend served as controls. Response rates were 67% (n = 98) in the prelecture group, 55% (n = 22) in the group who attended the lecture, and 28% (n = 30) in the control group. A total of 73% of the prelecture group reported little knowledge of IR compared with other specialties. This decreased to 27% in those who attended the lecture (P IR than any other specialty, compared with 7% of controls (P value not significant) and 2% of the prelecture group (P IR procedures (mean, 1.82) than the prelecture group (mean, 0.57; P IR, compared with 24% in the prelecture group and 33% in the control group (P IR residency, compared with 5% in the prelecture group and 33% in the control group (P IR education into the gross anatomy course proved to be a highly effective way of teaching preclinical students about IR and generating interest in the field. Copyright © 2017 SIR. All rights reserved.

  8. Silver electrodeposition over an Ir/Ir oxide electrode

    International Nuclear Information System (INIS)

    Lezna, R.O.; Tacconi, N.R. de; Arvia, A.J.

    1984-01-01

    Changes in electrochemical response brought about by the electrodeposition of small amounts of silver on oxide covered iridium electrodes are examined in relation to the semiconducting properties of the oxide. The charge involved in both silver and hydrogen atoms was found to remain practically constant and independent of the oxide thickness which was gradually increased by potentiodynamic cycling up to greater anodic switching potentials. This result suggests that the charge transfer for both processes takes place at the bare metal. The considerable increase in the film conductivity when the potential is above ductivity when the potential is above oV (MSE) is shown by the fact that under certain controlled conditions the silver electroreduction/ electroxidation reactions are shifted to a more anodic potential region where the oxide becomes conductor and participates in the charge transfer process. Silver loading increases the electrical conductivity of the oxide providing a large cross section for the electroxidation of Ir, particularly in a region where the oxide conductivity is poor (E [pt

  9. Atmospheric Entry Experiments at IRS

    Science.gov (United States)

    Auweter-Kurtz, M.; Endlich, P.; Herdrich, G.; Kurtz, H.; Laux, T.; Löhle, S.; Nazina, N.; Pidan, S.

    2002-01-01

    Entering the atmosphere of celestial bodies, spacecrafts encounter gases at velocities of several km/s, thereby being subjected to great heat loads. The thermal protection systems and the environment (plasma) have to be investigated by means of computational and ground facility based simulations. For more than a decade, plasma wind tunnels at IRS have been used for the investigation of TPS materials. Nevertheless, ground tests and computer simulations cannot re- place space flights completely. Particularly, entry mission phases encounter challenging problems, such as hypersonic aerothermodynamics. Concerning the TPS, radiation-cooled materials used for reuseable spacecrafts and ablator tech- nologies are of importance. Besides the mentioned technologies, there is the goal to manage guidance navigation, con- trol, landing technology and inflatable technologies such as ballutes that aim to keep vehicles in the atmosphere without landing. The requirement to save mass and energy for planned interplanetary missions such as Mars Society Balloon Mission, Mars Sample Return Mission, Mars Express or Venus Sample Return mission led to the need for manoeuvres like aerocapture, aero-breaking and hyperbolic entries. All three are characterized by very high kinetic vehicle energies to be dissipated by the manoeuvre. In this field flight data are rare. The importance of these manoeuvres and the need to increase the knowledge of required TPS designs and behavior during such mission phases point out the need of flight experiments. As result of the experience within the plasma diagnostic tool development and the plasma wind tunnel data base, flight experiments like the PYrometric RE-entry EXperiment PYREX were developed, fully qualified and successfully flown. Flight experiments such as the entry spectrometer RESPECT and PYREX on HOPE-X are in the conceptual phase. To increase knowledge in the scope of atmospheric manoeuvres and entries, data bases have to be created combining both

  10. Teaching IR to Medical Students: A Call to Action.

    Science.gov (United States)

    Lee, Aoife M; Lee, Michael J

    2018-02-01

    Interventional radiology (IR) has grown rapidly over the last 20 years and is now an essential component of modern medicine. Despite IR's increasing penetration and reputation in healthcare systems, IR is poorly taught, if taught at all, in most medical schools. Medical students are the referrers of tomorrow and potential IR recruits and deserve to be taught IR by expert IRs. The lack of formal IR teaching curricula in many medical schools needs to be addressed urgently for the continued development and dissemination of, particularly acute, IR services throughout Europe. We call on IRs to take up the baton to teach IR to the next generation of doctors.

  11. Spectroscopic and thermal degradation behavior of Mg(II, Ca(II, Ba(II and Sr(II complexes with paracetamol drug

    Directory of Open Access Journals (Sweden)

    Moamen S. Refat

    2017-05-01

    Full Text Available Complexes of Mg(II, Ca(II, Ba(II and Sr(II with paracetamol drug were synthesized and characterized by elemental analysis, conductivity, UV–Vis, IR, and 1H NMR spectroscopy and thermal analysis, as well as screened for antimicrobial activity. The IR spectral data suggested that the ligand behaves as paracetamol behaves as a neutral bidentate ligand coordinated to the metal ions via the lone pair of electrons of nitrogen and carbonyl-O atoms of the amide group. From the microanalytical data, the stoichiometry of the complexes reacts with Mg(II, Ca(II, Ba(II and Sr(II by molar ratios (2:1 (paracetamol:metal ion. The thermal behavior (TG/DTG of the complexes was studied. The ligand and their metal complexes were screened against both of antibacterial and fungicidal activities.

  12. Telechelic polyisobutylene with unsaturated end groups and with anhydride end groups

    NARCIS (Netherlands)

    Walch, E.; Walch, E.; Gaymans, R.J.

    1994-01-01

    Anhydride terminated polyisobutylene (PIB) oligomers were synthesized in a one- or two-step process from chlorine terminated oligomers. In the one-step process, chlorine functional oligomers were just heated in the presence of maleic anhydride (MA) for 12 h at 190°C without a catalyst. In the

  13. Synthesis, characterisation and electrochemical behaviour of Cu(II)

    Indian Academy of Sciences (India)

    Neutral tetradentate N2O2 type complexes of Cu(II), Ni(II), Co(II) and Zn(II) have been synthesised using the Schiff base formed by the condensation of acetylacetone and p-anisidine. Microanalysis, molar conductance, magnetic susceptibility, IR, UV-Vis, 1H NMR, CV and EPR studies have been carried out to determine the ...

  14. Premier's imaging IR limb sounder

    Science.gov (United States)

    Kraft, Stefan; Bézy, Jean-Loup; Meynart, Roland; Langen, Jörg; Carnicero Dominguez, Bernardo; Bensi, Paolo; Silvestrin, Pierluigi

    2017-11-01

    The Imaging IR Limb Sounder (IRLS) is one of the two instruments planned on board of the candidate Earth Explorer Core Mission PREMIER. PREMIER stands for PRocess Exploration through Measurements of Infrared and Millimetre-wave Emitted Radiation. PREMIER went recently through the process of a feasibility study (Phase A) within the Earth Observation Envelope Program. Emerging from recent advanced instrument technologies IRLS shall, next to a millimetre-wave limb sounder (called STEAMR), explore the benefits of three-dimensional limb sounding with embedded cloud imaging capability. Such 3D imaging technology is expected to open a new era of limb sounding that will allow detailed studies of the link between atmospheric composition and climate, since it will map simultaneously fields of temperature and many trace gases in the mid/upper troposphere and stratosphere across a large vertical and horizontal field of view and with high vertical and horizontal resolution. PREMIER shall fly in a tandem formation looking backwards to METOP's swath and thereby improve meteorological and environmental analyses.

  15. Atom condensation on an atomically smooth surface: Ir, Re, W, and Pd on Ir(111)

    International Nuclear Information System (INIS)

    Wang, S.C.; Ehrlich, G.

    1991-01-01

    The distribution of condensing metal atoms over the two types of sites present on an atomically smooth Ir(111) has been measured in a field ion microscope. For Ir, Re, W, and Pd from a thermal source, condensing on Ir(111) at ∼20 K, the atoms are randomly distributed, as expected if they condense at the first site struck

  16. Biochemical applications of FT-IR spectroscopy

    NARCIS (Netherlands)

    Pistorius, A.M.A.

    1996-01-01

    This thesis describes the use of (FT-)IR spectroscopy in general biochemical research. In chapter 3, IR spectroscopy is used in the quantitation of residual detergent after reconstitution of an integral membrane protein in a pre-defined lipid matrix. This chapter discusses the choice of the

  17. Status Of Sofradir IR-CCD Detectors

    Science.gov (United States)

    Tribolet, Philippe; Radisson, Patrick

    1988-05-01

    The topics of this paper deal with the IR-CCD detectors manufactured by SOFRADIR the new French joint venture. Description of the IRCCD technology and the advantages of this approach are given. In conclusion, some IR-CCD typical results are given.

  18. Cr(III,Mn(II,Fe(III,Co(II,Ni(II,Cu(II and Zn(II Complexes with Diisobutyldithiocarbamato Ligand

    Directory of Open Access Journals (Sweden)

    Mohammad Tarique

    2011-01-01

    Full Text Available The synthesis of sulphur and nitrogen containing dithiocarbamato ligand derived from diisobutylamine as well as its coordination compounds with 3d series transition metals is presented. These synthesized compounds were characterized on the basis of elemental analysis, conductometric measurements and IR spectral studies. The analytical data showed the stoichiometry 1:2 and 1:3 for the compounds of the types ML2 {M=Mn(II, Co(II, Ni(II, Cu(II and Zn(II} and M'L3{M'=Cr(III and Fe(III} respectively. The conductometric measurements proved the non-electrolytic behaviour of all the compounds. The bidentate nature of dithiocarbamato moiety was confirmed on the basis of IR spectral data.

  19. 2D IR spectroscopy of high-pressure phases of ice

    NARCIS (Netherlands)

    Tran, Halina; Cunha, Ana V.; Shephard, Jacob J.; Shalit, Andrey; Hamm, Peter; Jansen, Thomas L. C.; Salzmann, Christoph G.

    2017-01-01

    We present experimental and simulated 2D IR spectra of some high-pressure forms of isotope-pure D2O ice and compare the results to those of ice Ih published previously [F. Perakis and P. Hamm, Phys. Chem. Chem. Phys. 14, 6250 (2012); L. Shi et al., ibid. 18, 3772 (2016)]. Ice II, ice V, and ice XIII

  20. Visualizing Infrared (IR) Spectroscopy with Computer Animation

    Science.gov (United States)

    Abrams, Charles B.; Fine, Leonard W.

    1996-01-01

    IR Tutor, an interactive, animated infrared (IR) spectroscopy tutorial has been developed for Macintosh and IBM-compatible computers. Using unique color animation, complicated vibrational modes can be introduced to beginning students. Rules governing the appearance of IR absorption bands become obvious because the vibrational modes can be visualized. Each peak in the IR spectrum is highlighted, and the animation of the corresponding normal mode can be shown. Students can study each spectrum stepwise, or click on any individual peak to see its assignment. Important regions of each spectrum can be expanded and spectra can be overlaid for comparison. An introduction to the theory of IR spectroscopy is included, making the program a complete instructional package. Our own success in using this software for teaching and research in both academic and industrial environments will be described. IR Tutor consists of three sections: (1) The 'Introduction' is a review of basic principles of spectroscopy. (2) 'Theory' begins with the classical model of a simple diatomic molecule and is expanded to include larger molecules by introducing normal modes and group frequencies. (3) 'Interpretation' is the heart of the tutorial. Thirteen IR spectra are analyzed in detail, covering the most important functional groups. This section features color animation of each normal mode, full interactivity, overlay of related spectra, and expansion of important regions. This section can also be used as a reference.

  1. PKCδ-mediated IRS-1 Ser24 phosphorylation negatively regulates IRS-1 function

    International Nuclear Information System (INIS)

    Greene, Michael W.; Ruhoff, Mary S.; Roth, Richard A.; Kim, Jeong-a; Quon, Michael J.; Krause, Jean A.

    2006-01-01

    The IRS-1 PH and PTB domains are essential for insulin-stimulated IRS-1 Tyr phosphorylation and insulin signaling, while Ser/Thr phosphorylation of IRS-1 disrupts these signaling events. To investigate consensus PKC phosphorylation sites in the PH-PTB domains of human IRS-1, we changed Ser24, Ser58, and Thr191 to Ala (3A) or Glu (3E), to block or mimic phosphorylation, respectively. The 3A mutant abrogated the inhibitory effect of PKCδ on insulin-stimulated IRS-1 Tyr phosphorylation, while reductions in insulin-stimulated IRS-1 Tyr phosphorylation, cellular proliferation, and Akt activation were observed with the 3E mutant. When single Glu mutants were tested, the Ser24 to Glu mutant had the greatest inhibitory effect on insulin-stimulated IRS-1 Tyr phosphorylation. PKCδ-mediated IRS-1 Ser24 phosphorylation was confirmed in cells with PKCδ catalytic domain mutants and by an RNAi method. Mechanistic studies revealed that IRS-1 with Ala and Glu point mutations at Ser24 impaired phosphatidylinositol-4,5-bisphosphate binding. In summary, our data are consistent with the hypothesis that Ser24 is a negative regulatory phosphorylation site in IRS-1

  2. Mixed-ligand binuclear copper(II)

    Indian Academy of Sciences (India)

    A new mixed-ligand binuclear copper(II) complex [Cu(MS)(bpy)]2.(ClO4)2, built of 5-methylsalicylaldehyde and 2,2'-bipyridyl has been synthesized and characterized by using elemental analysis, IR and UV-Vis spectroscopy. Crystal structure of the complex shows that copper(II) ion lies in a square pyramidal coordination ...

  3. Implementing GPS into Pave-IR.

    Science.gov (United States)

    2009-03-01

    To further enhance the capabilities of the Pave-IR thermal segregation detection system developed at the Texas Transportation Institute, researchers incorporated global positioning system (GPS) data collection into the thermal profiles. This GPS capa...

  4. Novel Wavelength Standards in the Near IR

    National Research Council Canada - National Science Library

    Corwin, Kristan L

    2008-01-01

    .... This research has three major components, consisting of spectroscopy in hollow fiber, the development of a near-IR optical frequency comb with which to characterize the transitions inside the fiber...

  5. Activity uniformity of Ir-192 seeds

    International Nuclear Information System (INIS)

    Ling, C.C.; Gromadzki, Z.C.

    1981-01-01

    A simple device that uses materials and apparatus commonly available in a radiotherapy department has been designed, fabricated and used in routine quality control relative to the activity uniformity of clinical Ir-192 seeds in ribbons. Detailed evaluation indicated that this system is easy to use and can yield relative activity measurements of individual Ir-192 seeds accurate to within 2%. With this device, activity uniformity of commercial Ir-192 seeds from two manufacturers has been assessed. For the seven shipments of Ir-192 seeds studied, the root mean square variations of individual seed strength from the average of each shipment ranged from 3.4 to 7.1%. Variation in seed activity by more than +- 10% from the average is not uncommon

  6. Infrared (IR) remote sensing of gases

    OpenAIRE

    López Martínez, Fernando

    2008-01-01

    The IR Imaging and Remote Sensing Laboratory – LIR-UC3M of Universidad Carlos III, has developed Multi and Hyper spectral Infrared (IR) analysis techniques for gas remote sensing. Design of specific sensors for the determination of gases and their concentration are proposed. Almost all gases (CO2, CO, NO2, O3, HC o NH, …) related to industrial, environmental or military safety can be detected. Companies or centres with interest in the use of specific application sensors are required.

  7. Experimental study and nuclear model calculations on the $^{192}Os (p, n)^{192}$Ir reaction Comparison of reactor and cyclotron production of the therapeutic radionuclide $^{192}$Ir

    CERN Document Server

    Hilgers, K; Sudar, S; 10.1016/j.apradiso.2004.12.010

    2005-01-01

    In a search for an alternative route of production of the important therapeutic radionuclide /sup 192/Ir (T/sub 1/2/=78.83 d), the excitation function of the reaction /sup 192/Os(p, n)/sup 192/Ir was investigated from its threshold up to 20MeV. Thin samples of enriched /sup 192/Os were obtained by electrodeposition on Ni, and the conventional stacked-foil technique was used for cross section measurements. The experimental data were compared with the results of theoretical calculations using the codes EMPIRE-II and ALICE-IPPE. Good agreement was found with EMPIRE-II, but slightly less with the ALICE-IPPE calculations. The theoretical thick target yield of /sup 192/Ir over the energy range E/sub p/=16 to 8MeV amounts to only 0.16MBq/ mu A.h. A comparison of the reactor and cyclotron production methods is given. In terms of yield and radionuclidic purity of /sup 192/Ir the reactor method appears to be superior; the only advantage of the cyclotron method could be the higher specific activity of the product.

  8. Pentafluorobenzene end-group as a versatile handle for para fluoro “click” functionalization of polythiophenes† †Electronic supplementary information (ESI) available: Experimental details, MALDI-TOF, 1H and 19F NMR, UV-visible spectroscopy, and photoluminescence spectroscopy results. See DOI: 10.1039/c6sc04427a Click here for additional data file.

    Science.gov (United States)

    Boufflet, Pierre; Casey, Abby; Xia, Yiren; Stavrinou, Paul N.

    2017-01-01

    A convenient method of introducing pentafluorobenzene (PFB) as a single end-group in polythiophene derivatives is reported via in situ quenching of the polymerization. We demonstrate that the PFB-group is a particularly useful end-group due to its ability to undergo fast nucleophilic aromatic substitutions. Using this molecular handle, we are able to quantitatively tether a variety of common nucleophiles to the polythiophene backbone. The mild conditions required for the reaction allows sensitive functional moieties, such as biotin or a cross-linkable trimethoxysilane, to be introduced as end-groups. The high yield enabled the formation of a diblock rod-coil polymer from equimolar reactants under transition metal-free conditions at room temperature. We further demonstrate that water soluble polythiophenes end-capped with PFB can be prepared via the hydrolysis of an ester precursor, and that such polymers are amenable to functionalization under aqueous conditions. PMID:28507677

  9. Fabrication of flexible Ir and Ir-Rh wires and application for thermocouple

    Science.gov (United States)

    Murakami, Rikito; Kamada, Kei; Shoji, Yasuhiro; Yokota, Yuui; Yoshino, Masao; Kurosawa, Shunsuke; Ohashi, Yuji; Yamaji, Akihiro; Yoshikawa, Akira

    2018-04-01

    The fabrication and thermal electromotive force characteristics of Ir/Ir-Rh thermocouples capable of repeated bending deformation are described. Ir and Ir-Rh wires with a diameter of 0.5 mm were fabricated using the alloy-micro-pulling-down method. Scanning electron microscopy and electron backscattering diffraction of the radial cross section of the grown wires were performed to investigate the microstructure and orientation of the crystal grains. At the start of growth, the microstructure was polycrystalline with diameters of several hundred micrometers, while at the 8-m growth point it was found to be monocrystalline. The observed single crystals of pure Ir and Ir-Rh alloy were oriented in the 〈1 1 3〉 and 〈1 1 2〉 directions, respectively, whereas the polycrystalline Ir-Rh samples showed preferential growth in the 〈1 0 0〉 direction. The thermal electromotive force of the fabricated Ir/Ir-Rh thermocouple was measured by the comparison technique and the fixed-point technique, and the thermoelectric power was estimated to be 5.9 μV/°C in the range from 600°C to 1100°C.

  10. How easy is CO2 fixation by M-C bond containing complexes (M = Cu, Ni, Co, Rh, Ir)?

    KAUST Repository

    Nolan, Steve

    2015-11-27

    A comparison between different M–C bonds (M = Cu(I), Ni(II), Co(I), Rh(I) and Ir(I)) has been reported by using density functional theory (DFT) calculations to explore the role of the metal in the fixation or incorporation of CO2 into such complexes. The systems investigated are various metal based congeners of the Ir-complex 8 [(cod)(IiPr)Ir-CCPh], with a ligand scaffold based on cod and IiPr ligands (cod = 1,5-cyclooctadiene; IiPr = 1,3-bis(isopropyl)imidazol-2-ylidene). The results of this study show that the calculated CO2 insertion barriers follow the trend: Cu(I) (20.8 kcal mol−1) < Rh(I) (30.0 kcal mol−1) < Co(I) (31.3 kcal mol−1) < Ir(I) (37.5 kcal mol−1) < Ni(II) (45.4 kcal mol−1), indicating that the Cu(I) based analogue is the best CO2 fixer, while Ni(II) is the worst in the studied series.

  11. Single-nucleotide polymorphism of INS, INSR, IRS1, IRS2, PPAR-G ...

    Indian Academy of Sciences (India)

    2017-03-02

    Mar 2, 2017 ... Abstract. Polycystic ovary syndrome (PCOS) is the most common and a complex female endocrine disorder, and is one of the leading cause of female infertility. Here, we aimed to investigate the association of single-nucleotide polymorphism of INS, INSR,. IRS1, IRS2, PPAR-G and CAPN10 gene in the ...

  12. Synthesis, Characterization and Thermal Studies of Co(II), Ni(II), Cu ...

    African Journals Online (AJOL)

    NICO

    2010-06-15

    Jun 15, 2010 ... Ni(II) and Zn(II). TG curves indicated that the complexes decompose in three to four steps. The presence of coordinated water in metal complexes was confirmed by thermal and IR data of the complexes. KEY WORDS. Synthesis, Schiff bases, 1,2,4-triazine, thermal study. 1. Introduction. Triazine chemistry ...

  13. Intelligent multi-spectral IR image segmentation

    Science.gov (United States)

    Lu, Thomas; Luong, Andrew; Heim, Stephen; Patel, Maharshi; Chen, Kang; Chao, Tien-Hsin; Chow, Edward; Torres, Gilbert

    2017-05-01

    This article presents a neural network based multi-spectral image segmentation method. A neural network is trained on the selected features of both the objects and background in the longwave (LW) Infrared (IR) images. Multiple iterations of training are performed until the accuracy of the segmentation reaches satisfactory level. The segmentation boundary of the LW image is used to segment the midwave (MW) and shortwave (SW) IR images. A second neural network detects the local discontinuities and refines the accuracy of the local boundaries. This article compares the neural network based segmentation method to the Wavelet-threshold and Grab-Cut methods. Test results have shown increased accuracy and robustness of this segmentation scheme for multi-spectral IR images.

  14. Near-IR imaging and imaging polarimetry of OMC 2

    Science.gov (United States)

    Rayner, John; Mclean, Ian; Aspin, Colin; Mccaughrean, Mark

    1989-01-01

    NIR and 2.2-micron imaging polarimetry of the molecular cloud region OMC 2, reveals a cluster of low- to intermediate-mass premain-sequence stars embedded in circumstellar disks. The 2.2-micron imaging polarimetry indicates that the compact NIR sources OMC 2 IRS1, IRS2, IRS3 and IRS4 N, are illumination centers for the surrounding extended emission. By application of Hubble's relation to the nebulae illuminated by IRS1, IRS2 and IRS4 N, the illuminating geometry is explained and the intrinsic NIR colors of these objects are estimated.

  15. IR Thermometer with Automatic Emissivity Correction

    Directory of Open Access Journals (Sweden)

    A. Dobesch

    2013-12-01

    Full Text Available The paper describes the design and implementation of an infrared (IR thermometer with automatic emissivity correction. The temperature measurement is carried out by the simple digital thermopile sensor MLX90614. The emissivity correction is based on benefits of diffuse reflecting materials and it uses an IR laser diode in conjunction with a selective amplifier. Moreover, the paper includes the design of the control interface with a graphics LCD. Furthermore, this paper describes the power supply unit with a Li-ion cell controlled by basic integrated circuits.

  16. Kas netilpo tarp politikos ir diplomatijos?

    OpenAIRE

    Streikus, Arūnas

    2008-01-01

    The review analyzes A. Kasparavičius’s monograph “Tarp Politikos ir Diplomatijos: Šventasis Sostas ir Lietuvos Respublika” (Vilnius, 2008). The historiographic value of the study is undisputed. A. Kasperavičius had an opportunity to use a broad spectrum of sources, among which two sets of archive documents stand out: the funds of the archives of Ministry of Foreign Affairs of Lithuania and the Lithuanian Embassy under the Holy See in Rome. A. Kasparavičius managed to avoid the arid scientific...

  17. Elecciones Legislativas en Irán

    Directory of Open Access Journals (Sweden)

    José Antonio Sainz de la Peña

    2012-05-01

    Full Text Available Las elecciones legislativas en Irán, una vez eliminados los reformistas se han celebrado en un clima de rivalidad. Las elecciones tenían que dejar claro quién mandaba en Irán, si los clérigos y el Guía el ayatolá Seyed Ali Jamenei o, el Presidente de la República, el laico Mahmud Ahmadineyad, apoyado en el Cuerpo de Guardias Revolucionarios. La realidad ha sido que las facciones conservadoras encabezadas por el Frente Unido Principalista, apoyados por el Guía Supremo, han obtenido el triunfo.

  18. Evaluation of the Radiological Safety of 192 Ir Apparatus for Industrial Gamma Radiography

    International Nuclear Information System (INIS)

    Aquino, J. O.; Silva, F. C. A. da; Ramalho, A. T.; Godoy, J. M. O.

    2004-01-01

    The majority of the 192Ir apparatus for industrial gamma radiography have been in usage in Brazil for more than 20 years. They are portable, and almost all operate according to category II. The main objective of this work was to assess the radiological safety of the 11 models of 192Ir apparatus most used in Brazil. The 11 models of 192Ir apparatus were studied with respect to compliance with the main safety requirements of three editions of international Standards ISO 3999. Six models were already manufactured incorporating the safety devices specified in the first edition of ISO 3999, issued in 1977. However, five models were not. The validity of their type B certificates for transport packages was also evaluated. (Author) 8 refs

  19. Angiotensin II of paraventricular nucleus is exaggerated the renal ischemia-reperfusion injury

    Directory of Open Access Journals (Sweden)

    Behjat Seifi

    2014-05-01

    Conclusion: These data showed that the PVN is a responsive site for central Ang II-induced damage in renal IR injury. We suggested the central effects of Ang II in the PVN on renal IR injury are mediated by oxidative stress in the PVN, and the peripheral effects by a sympathetic pathway.

  20. Increase in homeostasis model assessment of insulin resistance (HOMA-IR) had a strong impact on the development of type 2 diabetes in Japanese individuals with impaired insulin secretion: the Saku study.

    Science.gov (United States)

    Morimoto, Akiko; Tatsumi, Yukako; Soyano, Fumie; Miyamatsu, Naomi; Sonoda, Nao; Godai, Kayo; Ohno, Yuko; Noda, Mitsuhiko; Deura, Kijyo

    2014-01-01

    Our aim was to assess the impact of increase in homeostasis model assessment of insulin resistance (HOMA-IR) on the development of type 2 diabetes in Japanese individuals with impaired insulin secretion (IIS). This study included 2,209 participants aged 30-69 without diabetes at baseline who underwent comprehensive medical check-ups between April 2006 and March 2007 at Saku Central Hospital. Participants were classified into eight groups according to the combination of baseline IIS status (non-IIS and IIS) and category of HOMA-IR change between the baseline and follow-up examinations (decrease, no change/small increase, moderate increase, and large increase). Type 2 diabetes was determined from fasting and 2 h post-load plasma glucose concentrations at the follow-up examination between April 2009 and March 2011. At baseline, 669 individuals (30.3%) were classified as having IIS. At follow-up, 74 individuals developed type 2 diabetes. After adjusting for confounding factors including baseline HOMA-IR values, the multivariable-adjusted odds ratios (95% confidence intervals) for type 2 diabetes in the non-IIS with a decrease (mean change in HOMA-IR: -0.47), non-IIS with a moderate increase (mean change in HOMA-IR: 0.28), non-IIS with a large increase (mean change in HOMA-IR: 0.83), IIS with a decrease (mean change in HOMA-IR: -0.36), IIS with no change/small increase (mean change in HOMA-IR: 0.08), IIS with a moderate increase (mean change in HOMA-IR: 0.27), and IIS with a large increase (mean change in HOMA-IR: 0.73) groups, relative to the non-IIS with no change/small increase (mean change in HOMA-IR: 0.08) group were 0.23 (0.04, 1.11), 1.22 (0.26, 5.72), 2.01 (0.70, 6.46), 1.37 (0.32, 4.28), 3.60 (0.83, 15.57), 5.24 (1.34, 20.52), and 7.01 (1.75, 24.18), respectively. Moderate and large increases in HOMA-IR had a strong impact on the development of type 2 diabetes among individuals with IIS in this Japanese population.

  1. Increase in homeostasis model assessment of insulin resistance (HOMA-IR had a strong impact on the development of type 2 diabetes in Japanese individuals with impaired insulin secretion: the Saku study.

    Directory of Open Access Journals (Sweden)

    Akiko Morimoto

    Full Text Available Our aim was to assess the impact of increase in homeostasis model assessment of insulin resistance (HOMA-IR on the development of type 2 diabetes in Japanese individuals with impaired insulin secretion (IIS. This study included 2,209 participants aged 30-69 without diabetes at baseline who underwent comprehensive medical check-ups between April 2006 and March 2007 at Saku Central Hospital. Participants were classified into eight groups according to the combination of baseline IIS status (non-IIS and IIS and category of HOMA-IR change between the baseline and follow-up examinations (decrease, no change/small increase, moderate increase, and large increase. Type 2 diabetes was determined from fasting and 2 h post-load plasma glucose concentrations at the follow-up examination between April 2009 and March 2011. At baseline, 669 individuals (30.3% were classified as having IIS. At follow-up, 74 individuals developed type 2 diabetes. After adjusting for confounding factors including baseline HOMA-IR values, the multivariable-adjusted odds ratios (95% confidence intervals for type 2 diabetes in the non-IIS with a decrease (mean change in HOMA-IR: -0.47, non-IIS with a moderate increase (mean change in HOMA-IR: 0.28, non-IIS with a large increase (mean change in HOMA-IR: 0.83, IIS with a decrease (mean change in HOMA-IR: -0.36, IIS with no change/small increase (mean change in HOMA-IR: 0.08, IIS with a moderate increase (mean change in HOMA-IR: 0.27, and IIS with a large increase (mean change in HOMA-IR: 0.73 groups, relative to the non-IIS with no change/small increase (mean change in HOMA-IR: 0.08 group were 0.23 (0.04, 1.11, 1.22 (0.26, 5.72, 2.01 (0.70, 6.46, 1.37 (0.32, 4.28, 3.60 (0.83, 15.57, 5.24 (1.34, 20.52, and 7.01 (1.75, 24.18, respectively. Moderate and large increases in HOMA-IR had a strong impact on the development of type 2 diabetes among individuals with IIS in this Japanese population.

  2. Isolated Gramicidin Peptides Probed by IR Spectroscopy

    Czech Academy of Sciences Publication Activity Database

    Rijs, A. M.; Kabeláč, Martin; Abo-Riziq, A.; Hobza, Pavel; de Vries, M. S.

    2011-01-01

    Roč. 12, č. 10 (2011), s. 1816-1821 ISSN 1439-4235 R&D Projects: GA MŠk LC512; GA AV ČR IAA400550808 Institutional research plan: CEZ:AV0Z40550506 Keywords : density functional calculations * gramicidin * IR spectroscopy * protein folding Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.412, year: 2011

  3. IR and OLAP in XML document warehouses

    DEFF Research Database (Denmark)

    Perez, Juan Manuel; Pedersen, Torben Bach; Berlanga, Rafael

    2005-01-01

    In this paper we propose to combine IR and OLAP (On-Line Analytical Processing) technologies to exploit a warehouse of text-rich XML documents. In the system we plan to develop, a multidimensional implementation of a relevance modeling document model will be used for interactively querying...

  4. Column Stores as an IR Prototyping Tool

    NARCIS (Netherlands)

    H.F. Mühleisen (Hannes); T. Samar (Thaer); J.J.P. Lin (Jimmy); A.P. de Vries (Arjen)

    2014-01-01

    textabstract. We make the suggestion that instead of implementing custom index structures and query evaluation algorithms, IR researchers should simply store document representations in a column-oriented relational database and write ranking models using SQL. For rapid prototyping, this is

  5. TIJAH: embracing IR methods in XML databases

    NARCIS (Netherlands)

    J.A. List; V. Mihajlovic; G. Ramirez Camps (Georgina); A.P. de Vries (Arjen); D. Hiemstra; H.E. Blok

    2005-01-01

    textabstractThis paper discusses our participation in INEX (the Initiative for the Evaluation of XML Retrieval) using the TIJAH XML-IR system. TIJAH's system design follows a `standard' layered database architecture, carefully separating the conceptual, logical and physical levels. At the conceptual

  6. High HOMA-IR, adjusted for puberty, relates to the metabolic syndrome in overweight and obese Chilean youths.

    Science.gov (United States)

    Burrows, Raquel A; Leiva, Laura B; Weisstaub, Gerardo; Lera, Lydia M; Albala, Cecilia B; Blanco, Estela; Gahagan, Sheila

    2011-05-01

    To determine how the homeostasis model assessment of insulin resistance (HOMA-IR) is related to metabolic risk in a sample of overweight and obese Chilean youths accounting for Tanner stage. A cross-sectional study assessing 486 overweight and obese youths (aged 5-15 years) recruited from the University of Chile, Pediatric Obesity Clinic. We measured anthropometry, Tanner stage, HOMA-IR, and laboratory tests related to metabolic risk. HOMA-IR was categorized by quartile for children (Tanner stages I and II) and adolescents (Tanner stage III and above) from a normative Chilean sample. Children and adolescents with HOMA-IR in the highest quartile were likely to have higher body mass index (BMI) Z-scores, elevated waist circumference, systolic and diastolic blood pressure, and triglycerides and low high-density lipoprotein. HOMA-IR had good negative predictive value for characteristics of the metabolic syndrome (MetS; 0.82). In a multivariate regression model, BMI Z-score [odds ratio (OR) 1.5] and HOMA-IR (OR 3.3) predicted 22% of the variance for the MetS, with 36% of the explained variance attributed to HOMA-IR. In a large clinical sample of overweight and obese Chilean youths, HOMA-IR ≥ 75th percentile was significantly associated with the cluster of factors referred to as the MetS. We emphasize the importance of establishing percentiles for HOMA-IR based on a normative sample and taking Tanner stage into account. Although BMI is easy to assess and interpret with minimal costs in a clinical setting, adding HOMA-IR explains more of the variance in the MetS than BMI Z-score alone. © 2011 John Wiley & Sons A/S.

  7. Higher-Order Scheme-Independent Series Expansions of $γ_{\\barψψ,IR}$ and $β'_{IR}$ in Conformal Field Theories

    DEFF Research Database (Denmark)

    Ryttov, Thomas A.; Shrock, Robert

    2017-01-01

    $ and $R$, we calculate the scheme-independent series expansions of (i) the anomalous dimension of the fermion bilinear, $\\gamma_{\\bar\\psi\\psi,IR}$, to $O(\\Delta_f^4)$ and (ii) the derivative $\\beta' = d\\beta/d\\alpha$, to $O(\\Delta_f^5)$, both evaluated at $\\alpha_{IR}$, where $\\Delta_f$ is an $N_f$-dependent...... expansion variable. These are the highest orders to which these expansions have been calculated. We apply these general results to theories with $G={\\rm SU}(N_c)$ and $R$ equal to the fundamental, adjoint, and symmetric and antisymmetric rank-2 tensor representations. It is shown that for all...... of these representations, $\\gamma_{\\bar\\psi\\psi,IR}$, calculated to the order $\\Delta_f^p$, with $1 \\le p \\le 4$, increases monotonically with decreasing $N_f$ and, for fixed $N_f$, is a monotonically increasing function of $p$. Comparisons of our scheme-independent calculations of $\\gamma_{\\bar\\psi\\psi,IR}$ and $\\beta...

  8. Probing Gas Adsorption in Zeolites by Variable-Temperature IR Spectroscopy: An Overview of Current Research.

    Science.gov (United States)

    Garrone, Edoardo; Delgado, Montserrat R; Bonelli, Barbara; Arean, Carlos O

    2017-09-15

    The current state of the art in the application of variable-temperature IR (VTIR) spectroscopy to the study of (i) adsorption sites in zeolites, including dual cation sites; (ii) the structure of adsorption complexes and (iii) gas-solid interaction energy is reviewed. The main focus is placed on the potential use of zeolites for gas separation, purification and transport, but possible extension to the field of heterogeneous catalysis is also envisaged. A critical comparison with classical IR spectroscopy and adsorption calorimetry shows that the main merits of VTIR spectroscopy are (i) its ability to provide simultaneously the spectroscopic signature of the adsorption complex and the standard enthalpy change involved in the adsorption process; and (ii) the enhanced potential of VTIR to be site specific in favorable cases.

  9. Near-IR spectral evolution of dusty starburst galaxies

    Science.gov (United States)

    Lançon, Ariane; Rocca-Volmerange, Brigitte

    1996-11-01

    We propose a multicomponent analysis of starburst galaxies, based on a model that takes into account the young and evolved stellar components and the gas emission, with their respective extinction, in the frame of a coherent dust distribution pattern. Near-IR signatures are preferentially investigated, in order to penetrate as deep as possible into the dusty starburst cores. We computed the 1.4-2.5 μm spectra of synthetic stellar populations evolving through strong, short timescale bursts of star formation (continuum and lines, R ≃ 500). The evolution model is specifically sensitive to cool stellar populations (AGB and red supergiant stars). It takes advantage of the stellar library of Lançon & Rocca-Volmerange (1992) [A&ASS, 96, 593], observed with the same instrument (FTS/CFHT) as the analysed galaxy sample, so that the instrumental effects are minimised. The main near-IR observable constraints are the molecular signatures of CO and H2O and the slope of the continuum, observed over a range exceptionally broad for spectroscopic data. The H - K colour determined from the spectra measures the intrinsic stellar energy distribution but also differential extinction, which is further constrained by optical emission line ratios. Other observational constraints are the near-IR emission lines (Brγ, He I 2.06 μm, [Fe II] 1.64 μm, H2 2.12 μm) and the far-IR luminosity. The coherence of the results relies on the interpretation in terms of stellar populations from which all observable properties are derived, so that the link between the various wavelength ranges is secured. The luminosity LK is used for the absolute calibration. We apply this approach to the typical spectrum of the core of NGC 1614. Consistent solutions for the starburst characteristics (star-formation rate, IMF, burst age, morphology) are found and the role of each observational constraint in deriving satisfactory models is extensively discussed. The acceptable contamination of the K band light by the

  10. RESOLVING THE FAR-IR LINE DEFICIT: PHOTOELECTRIC HEATING AND FAR-IR LINE COOLING IN NGC 1097 AND NGC 4559

    International Nuclear Information System (INIS)

    Croxall, Kevin V.; Smith, J. D.; Wolfire, M. G.; Bolatto, A. D.; Roussel, H.; Sandstrom, K. M.; Groves, B. A.; Draine, B. T.; Aniano, G.; Dale, D. A.; Armus, L.; Beirão, P.; Helou, G.; Appleton, P. N.; Brandl, B. R.; Calzetti, D.; Crocker, A. F.; Galametz, M.; Hao, C.-N.; Hunt, L. K.

    2012-01-01

    The physical state of interstellar gas and dust is dependent on the processes which heat and cool this medium. To probe heating and cooling of the interstellar medium over a large range of infrared surface brightness, on sub-kiloparsec scales, we employ line maps of [C II] 158 μm, [O I] 63 μm, and [N II] 122 μm in NGC 1097 and NGC 4559, obtained with the Photodetector Array Camera and Spectrometer on board Herschel. We matched new observations to existing Spitzer Infrared Spectrograph data that trace the total emission of polycyclic aromatic hydrocarbons (PAHs). We confirm at small scales in these galaxies that the canonical measure of photoelectric heating efficiency, ([C II] + [O I])/TIR, decreases as the far-infrared (far-IR) color, νf ν (70 μm) νf ν (100 μm), increases. In contrast, the ratio of far-IR cooling to total PAH emission, ([C II] + [O I])/PAH, is a near constant ∼6% over a wide range of far-IR color, 0.5 ν (70 μm) νf ν (100 μm) ∼ ν (70 μm) νf ν (100 μm) ∼> 0.95, the ratio ([C II] + [O I])/PAH drops rapidly to 4%. We derived representative values of the local ultraviolet radiation density, G 0 , and the gas density, n H , by comparing our observations to models of photodissociation regions. The ratio G 0 /n H , derived from fine-structure lines, is found to correlate with the mean dust-weighted starlight intensity, (U), derived from models of the IR spectral energy distribution. Emission from regions that exhibit a line deficit is characterized by an intense radiation field, indicating that small grains are susceptible to ionization effects. We note that there is a shift in the 7.7/11.3 μm PAH ratio in regions that exhibit a deficit in ([C II] + [O I])/PAH, suggesting that small grains are ionized in these environments.

  11. 2D IR cross peaks reveal hydrogen-deuterium exchange with single residue specificity.

    Science.gov (United States)

    Dunkelberger, Emily B; Woys, Ann Marie; Zanni, Martin T

    2013-12-12

    A form of chemical exchange, hydrogen-deuterium exchange (HDX), has long been used as a method for studying the secondary and tertiary structure of peptides and proteins using mass spectrometry and NMR spectroscopy. Using two-dimensional infrared (2D IR) spectroscopy, we resolve cross peaks between the amide II band and a (13)C(18)O isotope-labeled amide I band, which we show measures HDX with site-specific resolution. By rapidly scanning 2D IR spectra using mid-IR pulse shaping, we monitor the kinetics of HDX exchange on-the-fly. For the antimicrobial peptide ovispirin bound to membrane bilayers, we find that the amide II peak decays with a biexponential with rate constants of 0.54 ± 0.02 and 0.12 ± 0.01 min(-1), which is a measure of the overall HDX in the peptide. The cross peaks between Ile-10-labeled ovispirin and the amide II mode, which specifically monitor HDX kinetics at Ile-10, decay with a single rate constant of 0.36 ± 0.1 min(-1). Comparing this exchange rate to theoretically determined exchange rates of Ile-10 for ovispirin in a solution random coil configuration, the exchange rate at Ile-10 is at least 100 times slower, consistent with the known α-helix structure of ovispirin in bilayers. Because backbone isotope labels produce only a very small shift of the amide II band, site-specific HDX cannot be measured with FTIR spectroscopy, which is why 2D IR spectroscopy is needed for these measurements.

  12. IAEA/NEA incident reporting system (IRS). Reporting guidelines. Feedback from safety related operating experience for nuclear power plants

    International Nuclear Information System (INIS)

    1998-01-01

    The Incident Reporting System (IRS) is an international system jointly operated by the International Atomic Energy Agency (IAEA) and the Nuclear Energy Agency of the Organisation for Economic Cooperation and Development (OECD/NEA). The fundamental objective of the IRS is to contribute to improving the safety of commercial nuclear power plants (NPPs) which are operated worldwide. This objective can be achieved by providing timely and detailed information on both technical and human factors related to events of safety significance which occur at these plants. The purpose of these guidelines, which supersede the previous IAEA Safety Series No. 93 (Part II) and the NEA IRS guidelines, is to describe the system and to give users the necessary background and guidance to enable them to produce IRS reports meeting a high standard of quality while retaining the high efficiency of the system expected by all Member States operating nuclear power plants. These guidelines have been jointly developed and approved by the NEA/IAEA

  13. Metal-Mesh Optical Filter Technology for Mid IR, Far IR, and Submillimeter, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR Phase I proposal describes a method of fabrication of far IR and THZ range multilayer metal-mesh filters. This type of filter consists of alternative...

  14. Metal-Mesh Optical Filter Technology for Mid IR, Far IR, and Submillimeter Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The innovative, high transmission band-pass filter technology proposed here is an improvement in multilayer metal-mesh filter design and manufacture for the far IR...

  15. Synthesis, spectroscopic characterization, molecular modeling and antimicrobial activities of Mn(II), Co(II), Ni(II), Cu(II) complexes containing the tetradentate aza Schiff base ligand

    Science.gov (United States)

    Chandra, Sulekh; Ruchi

    2013-02-01

    Mn(II), Co(II), Ni(II), and Cu(II) complexes with a tetradentate macrocyclic ligand [1.2.5.6tetraoxo-3,4,7,8tetraaza-(1,2,3,4,5,6,7,8)tetrabenzene(L)] were synthesized and characterized by elemental analysis, molar conductance measurements, mass, nmr, i.r., electronic and e.p.r. spectral studies. All the complexes are non electrolytes in nature and may be formulated as [M(L)X2] [where, M = Mn(II), Co(II), Ni(II), Cu(II) and X = Cl-, CH3COO-]. On the basis of i.r., electronic and e.p.r. spectral studies a distorted octahedral geometry has been assigned for all complexes. The antimicrobial activities and LD50 values of the ligand and its complexes, as growth inhibiting agents, have been screened in vitro against two different species of bacteria and plant pathogenic fungi.

  16. Suppression of superconductivity in Nb by IrMn in IrMn/Nb bilayers

    KAUST Repository

    Wu, B. L.

    2013-10-10

    Effect of antiferromagnet on superconductivity has been investigated in IrMn/Nb bilayers. Significant suppression of both transition temperature (Tc) and lower critical field (Hc1) of Nb is found in IrMn/Nb bilayers as compared to a single layer Nb of same thickness; the suppression effect is even stronger than that of a ferromagnet in NiFe/Nb bilayers. The addition of an insulating MgO layer at the IrMn-Nb interface nearly restores Tc to that of the single layer Nb, but Hc1 still remains suppressed. These results suggest that, in addition to proximity effect and magnetic impurity scattering, magnetostatic interaction also plays a role in suppressing superconductivity of Nb in IrMn/Nb bilayers. In addition to reduced Tc and Hc1, the IrMn layer also induces broadening in the transition temperature of Nb, which can be accounted for by a finite distribution of stray field from IrMn.

  17. Supergene neoformation of Pt-Ir-Fe-Ni alloys: multistage grains explain nugget formation in Ni-laterites

    Science.gov (United States)

    Aiglsperger, Thomas; Proenza, Joaquín A.; Font-Bardia, Mercè; Baurier-Aymat, Sandra; Galí, Salvador; Lewis, John F.; Longo, Francisco

    2017-10-01

    Ni-laterites from the Dominican Republic host rare but extremely platinum-group element (PGE)-rich chromitites (up to 17.5 ppm) without economic significance. These chromitites occur either included in saprolite (beneath the Mg discontinuity) or as `floating chromitites' within limonite (above the Mg discontinuity). Both chromitite types have similar iridium-group PGE (IPGE)-enriched chondrite normalized patterns; however, chromitites included in limonite show a pronounced positive Pt anomaly. Investigation of heavy mineral concentrates, obtained via hydroseparation techniques, led to the discovery of multistage PGE grains: (i) Os-Ru-Fe-(Ir) grains of porous appearance are overgrown by (ii) Ni-Fe-Ir and Ir-Fe-Ni-(Pt) phases which are overgrown by (iii) Pt-Ir-Fe-Ni mineral phases. Whereas Ir-dominated overgrowths prevail in chromitites from the saprolite, Pt-dominated overgrowths are observed within floating chromitites. The following formation model for multistage PGE grains is discussed: (i) hypogene platinum-group minerals (PGM) (e.g. laurite) are transformed to secondary PGM by desulphurization during serpentinization; (ii) at the stages of serpentinization and/or at the early stages of lateritization, Ir is mobilized and recrystallizes on porous surfaces of secondary PGM (serving as a natural catalyst) and (iii) at the late stages of lateritization, biogenic mediated neoformation (and accumulation) of Pt-Ir-Fe-Ni nanoparticles occurs. The evidence presented in this work demonstrates that in situ growth of Pt-Ir-Fe-Ni alloy nuggets of isometric symmetry is possible within Ni-laterites from the Dominican Republic.

  18. Infrared Measurements of Possible IR Filter Materials

    Energy Technology Data Exchange (ETDEWEB)

    Koller,D.; Ediss, G.; Mihaly, L.; Carr, G.

    2006-01-01

    A Fourier Transform Infrared Spectrometer (FTS) was used to obtain the transmission spectra of candidate materials for use as infrared (IR) filters in cryogenic receivers. The data cover the range from 50 cm-1 ({approx}1.5 THz), well below the peak of the 300 K black body spectrum, to 5000 cm-1 ({approx}150 THz), Z-cut quartz, Gore-Tex, Zitex G and Zitex A, High Density Polyethylene (HDPE), Teflon (PTFE), Fluorogold and Black Polyethylene were measured. The relative effectiveness of each material as a filter is determined by integrating the transmission spectrum multiplied by the Planck distribution to obtain a normalized attenuation for the mid-IR band. Measurements at both room temperature and 8 K are compared.

  19. Development of pixellated Ir-TESs

    International Nuclear Information System (INIS)

    Zen, Nobuyuki; Takahashi, Hiroyuki; Kunieda, Yuichi; Dayanthi, Rathnayaka M.T.; Mori, Fumiakira; Fujita, Kaoru; Nakazawa, Masaharu; Fukuda, Daiji; Ohkubo, Masataka

    2006-01-01

    We have been developing Ir-based pixellated superconducting transition edge sensors (TESs). In the area of material or astronomical applications, the sensor with few eV energy resolution and over 1000 pixels imaging property is desired. In order to achieve this goal, we have been analyzing signals from pixellated TESs. In the case of a 20 pixel array of Ir-TESs, with 45 μmx45 μm pixel sizes, the incident X-ray signals have been classified into 16 groups. We have applied numerical signal analysis. On the one hand, the energy resolution of our pixellated TES is strongly degraded. However, using pulse shape analysis, we can dramatically improve the resolution. Thus, we consider that the pulse signal analysis will lead this device to be used as a practical photon incident position identifying TES

  20. Advances in handheld FT-IR instrumentation

    Science.gov (United States)

    Arnó, Josep; Cardillo, Len; Judge, Kevin; Frayer, Maxim; Frunzi, Michael; Hetherington, Paul; Levy, Dustin; Oberndorfer, Kyle; Perec, Walter; Sauer, Terry; Stein, John; Zuidema, Eric

    2012-06-01

    FT-IR spectroscopy is the technology of choice to identify solid and liquid phase unknown samples. The challenges of ConOps (Concepts of Operation) in emergency response and military field applications require a significant redesign of the stationary FT-IR bench-top instruments typically used in laboratories. Specifically, field portable units require high levels of resistance against mechanical shock and chemical attack, ease of use in restrictive gear, quick and easy interpretation of results, and reduced size. In the last 20 years, FT-IR instruments have been re-engineered to fit in small suitcases for field portable use and recently further miniaturized for handheld operation. This article introduces the advances resulting from a project designed to overcome the challenges associated with miniaturizing FT-IR instruments. The project team developed a disturbance-corrected permanently aligned cube corner interferometer for improved robustness and optimized opto-mechanical design to maximize optical throughput and signal-to-noise ratios. Thermal management and heat flow were thoroughly modeled and studied to isolate sensitive components from heat sources and provide the widest temperature operation range. Similarly, extensive research on mechanical designs and compensation techniques to protect against shock and vibration will be discussed. A user interface was carefully created for military and emergency response applications to provide actionable information in a visual, intuitive format. Similar to the HazMatID family of products, state-of-the-art algorithms were used to quickly identify the chemical composition of complex samples based on the spectral information. This article includes an overview of the design considerations, tests results, and performance validation of the mechanical ruggedness, spectral, and thermal performance.

  1. Synthesis and characterization of heterobimetallic complexes of the type [Cu(pn2][MCl4] where M = Co(II, Ni(II, Cu(II, Zn(II, Cd(II, and Hg(II

    Directory of Open Access Journals (Sweden)

    Seema Yadav

    2016-11-01

    Full Text Available A series of new bimetallic transition metal complexes of the type [Cu(pn2] [MCl4] have been synthesized (where M = Co(II, Ni(II, Cu(II, Zn(II, Cd(II and Hg(II, pn = 1,3-diaminopropane and characterized by elemental analysis, molar conductance, TGA, IR and electronic spectra. All the compounds are 1:1 electrolyte in DMF. The Cu(II ion is square-planar while metal ions in the anionic moiety acquire their usual tetrahedral arrangement. On the basis of these studies it is concluded that anionic moiety is electrically stabilized by its cationic counterpart.

  2. Supplemental Security Income (SSI) / Internal Revenue Service (IRS) 1099

    Data.gov (United States)

    Social Security Administration — A finder file from SSA's Title XVI database is provided to the IRS. The IRS discloses 1099 information to SSA for use in verifying eligibility, amount, and benefits...

  3. ODYSSEY THEMIS IR PBT V2.0

    Data.gov (United States)

    National Aeronautics and Space Administration — The THEMIS IR-PBT data set contains the spatially registered, infrared brightness temperature images derived from the projected radiance (IR-GEO) products. Each...

  4. Coordination compounds of cobalt(II), nickel(II), copper(II), and zinc(II) with pantothenic acid

    Energy Technology Data Exchange (ETDEWEB)

    Shabilalov, A.A.; Yunuskhodzhaev, A.N.; Khodzhaev, O.F.; Azizov, M.A.

    1986-11-01

    The compounds Ni(PANA - H)/sub 2/ x 4H/sub 2/O (PANA stands for pantothenic acid, and - H indicates a deprotonated ligand), Cu(PANA - H)/sub 2/ x 2H/sub 2/O, Zn(PANA - H)/sub 2/ x H/sub 2/O, Co(PANA - H)Cl x H/sub 2/O, and Ni(PANA - H)Cl x 3H/sub 2/O have been synthesized on the basis of pantothenic acid and Co(II), Ni(II), Cu(II), and Zn(II) salts in aqueous media. The compounds have been identified by elemental and x-ray diffraction analysis. Some physicochemical properties (solubility, melting point, molar conductivity) of the compounds obtained have been studied. The structure of the compounds isolated has been established on the basis of an analysis of their IR, ESR, and electronic spectra, as well as derivatograms.

  5. Acquisition of Infrared Variable Angle Spectroscopic Ellipsometer (IR-VASE)

    Science.gov (United States)

    2016-04-22

    SECURITY CLASSIFICATION OF: This award was used to acquire a J.A. Woollam Infrared Variable Angle Spectroscopic Ellipsometer ( IR -VASE). The IR -VASE...unit is capable of obtaining crucial IR information of ultrathin films whilst being complemented with ellipsometry data. This powerful and versatile...Unlimited UU UU UU UU 22-04-2016 1-Feb-2015 31-Jan-2016 Final Report: Acquisition of Infrared Variable Angle Spectroscopic Ellipsometer ( IR -VASE) The

  6. IR Cards: Inquiry-Based Introduction to Infrared Spectroscopy

    Science.gov (United States)

    Bennett, Jacqueline; Forster, Tabetha

    2010-01-01

    As infrared spectroscopy (IR) is frequently used in undergraduate organic chemistry courses, an inductive introduction to IR spectroscopy that uses index cards printed with spectra, structures, and chemical names is described. Groups of students are given an alphabetized deck of these "IR cards" to sort into functional groups. The students then…

  7. IGF-IR targeted therapy: Past, present and future

    NARCIS (Netherlands)

    J.A.M.J.L. Janssen (Joseph); A.J. Varewijck (Aimee)

    2014-01-01

    textabstractThe IGF-I receptor (IGF-IR) has been studied as an anti-cancer target. However, monotherapy trials with IGF-IR targeted antibodies or with IGF-IR specific tyrosine kinase inhibitors have, overall, been very disappointing in the clinical setting. This review discusses potential reasons

  8. Infrared upconversion spectrometer for the mid-ir range

    DEFF Research Database (Denmark)

    2018-01-01

    The invention provides an infrared upconversion spectrometer for determining a mid-IR spectrum of received infrared light with a high resolution. The spectrometer applies upconversion to transform light in the mid-IR to the near-IR range where efficient detectors are available. The upconversion...

  9. Synthesis, characterization and thermal studies of nickel (II), copper (II), zinc (II) and cadmium (II) complexes with some mixed ligands

    International Nuclear Information System (INIS)

    Mitra, Samiran; Kundu, Parimal; Singh, Rajkumar Bhubon

    1998-01-01

    Dichloro-(DCA) and trichloroacetate(TCA) -cyclic ligand morpholine (Morph)/thiomorpholine (Tmorph)/methylmorpholine (Mmorph)/dimethyl-piperazine (DMP) complexes of nickel (II), copper (II), zinc (II) and cadmium (II) with the compositions [Ni(tmorph) 2 (DCA) 2 ], [Ni(tmorph) 2 (TCA) 2 ].2H 2 O, [Cu(DMP) 2 (TCA) 2 ],[ML 2 X 2 ].nH 2 O where M=Zn II or Cd II , L=Morph, DMP or tmorph and X=DCA or TCA and n=O except in case of [Cd (Morph) 2 (TCA) 2 ] where n=1 have been synthesised. Some intermediate complexes have been isolated by temperature arrest technique (pyrolysis) and characterised. Configurational and conformational changes have been studied by elemental analyses, IR and electronic spectra, magnetic moment data (in the case of Ni(II) and Cu(II) complexes) and thermal analysis. E a * , ΔH, and ΔS for the decomposition reaction of these complexes are evaluated and the stability of the complexes with respect to activation energy has also been compared. The linear correlation has been found between E a * and ΔS for the decomposition of the complexes. (author)

  10. and ni (ii) complexes with n

    African Journals Online (AJOL)

    DR. AMINU

    68.06KJmol-1, respectively. The ratio of metal ion to Schiff base determined potentiometrically and spectrophotometrically for the complex compounds is 1: 2. The IR spectrum of the Schiff base shows bands observable in the two Schiff base complex compounds, indicating the coordination of the Schiff base to the cobalt(II) ...

  11. X-ray magnetic circular dichroism at IrL 2,3 edges in Fe 100- Ir

    Indian Academy of Sciences (India)

    3, 10 and 17) and Co100-Ir (=5, 17, 25 and 32) alloys has been investigated by X-ray magnetic circular dichroism (XMCD) at Ir L2,3 absorption edges. Sum rule analysis of the XMCD data show that the orbital moment of Ir is in the range of ...

  12. IR Spectroscopic signs of malignant neoplasms in the thyroid gland

    Science.gov (United States)

    Tolstorozhev, G. B.; Skornyakov, I. V.; Butra, V. A.

    2012-03-01

    We use Fourier transform IR spectroscopy to study thyroid tumor tissues which were removed during surgery. The IR spectra of the tissues with pathological foci are compared with data from histologic examination. In the region of N-H, C-H, and C = O stretching vibrations, the IR spectra of the tissues for thyroid cancer are different from the IR spectra of tissues without malignant formations. We identify the spectral signs of thyroid cancer. We show that IR analysis is promising for identification of thyroid pathology at the molecular level.

  13. Defense Strategy of Aircraft Confronted with IR Guided Missile

    OpenAIRE

    Huang, Hesong; Tong, Zhongxiang; Li, Taorui; Jia, Lintong; Li, Shenbo

    2017-01-01

    Surface-type infrared (IR) decoy can simulate the IR characteristics of the target aircraft, which is one of the most effective equipment to confront IR guided missile. In the air combat, the IR guided missile poses a serious threat to the aircraft when it comes from the front of target aircraft. In this paper, firstly, the model of aircraft and surface-type IR decoy is established. To ensure their authenticity, the aircraft maneuver and radiation models based on real data of flight and exhau...

  14. IR and OLAP in XML document warehouses

    DEFF Research Database (Denmark)

    Perez, Juan Manuel; Pedersen, Torben Bach; Berlanga, Rafael

    2005-01-01

    In this paper we propose to combine IR and OLAP (On-Line Analytical Processing) technologies to exploit a warehouse of text-rich XML documents. In the system we plan to develop, a multidimensional implementation of a relevance modeling document model will be used for interactively querying...... the warehouse by allowing navigation in the structure of documents and in a concept hierarchy of query terms. The facts described in the relevant documents will be ranked and analyzed in a novel OLAP cube model able to represent and manage facts with relevance indexes....

  15. The Near-IR Extinction Law

    Science.gov (United States)

    Stead, Joseph J.; Hoare, Melvin G.

    2010-11-01

    We show that the power-law slope of the near-IR extinction law is significantly steeper than previously thought. Simulated colour-colour diagrams including a stellar population synthesis, realistic extinction distribution along the line-of-sight and synthesis through the filter profiles are compared to data from the UKIDSS Galactic Plane Survey. The slope of extinction with wavelength is found to be 2.14 ± 0.05 for total visual extinctions up to about 25 magnitudes and for a number of locations.

  16. Controlling Hydrogenation of Graphene on Ir(111)

    DEFF Research Database (Denmark)

    Balog, Richard; Andersen, Mie; Jørgensen, Bjarke

    2013-01-01

    Combined fast X-ray photoelectron spectroscopy and density functional theory calculations reveal the presence of two types of hydrogen adsorbate structures at the graphene/ Ir(111) interface, namely, graphane-like islands and hydrogen dimer structures. While the former give rise to a periodic...... pattern, dimers tend to destroy the periodicity. Our data reveal distinctive growth rates and stability of both types of structures, thereby allowing one to obtain well-defined patterns of hydrogen clusters. The ability to control and manipulate the formation and size of hydrogen structures on graphene...... facilitates tailoring of its properties for a wide range of applications by means of covalent functionalization....

  17. Fast IR diodes thermometer for tokamak

    International Nuclear Information System (INIS)

    Chen Xiangbo

    2001-01-01

    A 30 channel fast IR pyrometry array has been constructed for tokamak, which has 0.5 μs time response, 10 mm diameter spatial resolution and 5 degree C temperature resolution. The temperature measuring range is from 250 degree C to 1200 degree C. The two dimensional temperature profiles of the first wall during both major and minor disruptions can be measured with an accuracy of about 1% measuring temperature, which is adequate for tokamak experiments. This gives a very useful tool for the disruption study, especially for the divertor physics and edge heat flux research on tokamak and other magnetic confinement devices

  18. Atsiskaitymai e. versle: ypatumai ir naujos tendencijos

    OpenAIRE

    Vyšniauskas, Jonas

    2014-01-01

    Alternatyvių atsiskaitymų e. versle sistemos pradeda kelti rimtą grėsmę tradiciniams atsiskaitymams elektronine bankininkyste, mokėjimo kortelėmis ar grynaisiais pinigais. Todėl būtina detaliau išsiaiškinti kokie yra alternatyvių atsiskaitymų ypatumai, kurie veiksniai vartotojams yra svarbiausi ir kokie yra alternatyvūs atsiskaitymo būdai. Tai siekiama padaryti išanalizuojant mokslinę literatūrą, pateikiant pagrindines alternatyvių atsiskaitymų sistemas, atliekant alternatyvių atsiskaitymų pa...

  19. β*-Reach – IR7 Collimation Hierarchy Limit and Impedance

    CERN Document Server

    Mereghetti, Alessio; Bruce, Roderik; Carver, Lee Robert; Kwee-Hinzmann, Regina; Metral, Elias; Mirarchi, Daniele; Quaranta, Elena; Redaelli, Stefano; Rossi, Adriana; Rossi, Roberto; Salvachua Ferrando, Belen Maria; Salvant, Benoit; Valentino, Gianluca; Valloni, Alessandra; CERN. Geneva. ATS Department

    2016-01-01

    This report summarises the results of the MD314 about the hierarchy limit of the IR7 collimation system and its impedance. While the activity, the procedures and the results concerning the collimator hierarchy limit are detailed here, the main outcomes from the impedance studies are only briefly reported, as a detailed MD report has been prepared. The MD was carried out during MD block II of 2015, on 29th August, at 6.5 TeV. Different retractions of the IR7 secondary collimators (TCSGs) from the primary collimators (TCPs) were qualified in terms of cleaning inefficiency and impedance. For each retraction, settings of the IR7 movable shower absorbers (TCLAs) tighter than those operationally deployed were qualified as well. Afterwards, the alignment of all IR7 collimators was performed and the beam-based centers compared to those from the alignment done in May 2015, to verify stability. Selected configurations were qualified with loss maps, to spot possible improvements in the cleaning inefficiency due to the ...

  20. Recent events in NPPs and incident reporting system (IRS) activity. Working material

    International Nuclear Information System (INIS)

    1996-01-01

    The IAEA convened the 1996 Joint Meeting to Exchange Information on Recent Events in Nuclear Power Plants and the Technical Committee-Annual Meeting of the Incident Reporting System (IRS) national co-ordinators, organized jointly with the Nuclear Energy Agency (NEA) of the OECD in Paris, France from 22-26 April 1996. These consecutive meetings took place at the OECD Headquarters, 2 rue Andre Pascal. The main objective of the first meeting (22-24 April 1996) was to exchange and discuss information on recent events which occurred in NPPs. The second meeting (25-26 April 1996) was devoted to the IAEA and NEA activity in the framework of the IRS. The main issues of the programme at the meetings were as follows: in-depth discussion on NPP recent events, presented by the participants; panel discussion on operational safety experience issues identified by the participants; IAEA and NEA activities on IRS subjects in 1995-1996 and plans for the future; issues from the inter-agency's IRS Advisory Committee. Annexes I and II provide more information on the programme at the meetings. A list of participants is given in Annex III (50 participants from 22 countries and 3 international organization). Annexes IV and V provide information on national presentations on recent events. Figs, tabs

  1. Topological phase transition in the ternary half-Heusler alloy ZrIrBi

    Science.gov (United States)

    Barman, C. K.; Alam, Aftab

    2018-02-01

    Half-Heusler alloys provide a new platform for deriving a host of topologically exotic compounds through the inherent flexibility of tuning their hybridization strength (via lattice parameters), spin-orbit strength, substitution/doping, etc. Using the first-principles calculation within the density functional theory, we explore the possibility of realizing a topological insulating phase in a new half-Heusler material ZrIrBi. We discovered three routes through which ZrIrBi can be transformed to exhibit a topological nontrivial phase. They are (i) a hydrostatic expansion by 1% causing a band inversion with zero gap, (ii) a uniaxial strain along (001) direction which opens a band gap while preserving the inverted band order, and (iii) substitution of 50% Bi by As and 50% Zr by Hf forming the compounds ZrIr (As0.5Bi0.5 ) and (Zr0.5Hf0.5 )IrBi again showing a topologically nontrivial band inversion. A definitive proof of the surface conduction in all three cases are done by simulating surface band structures. We report the formation energies and the phonon dispersion for the three cases to confirm the chemical and mechanical stability of the compounds.

  2. Mixed-ligand binuclear copper (II) complex of 5 ...

    Indian Academy of Sciences (India)

    A new mixed-ligand binuclear copper(II) complex [Cu(MS)(bpy)]2.(ClO4)2, built of 5-methylsalicylaldehyde and 2,2'-bipyridyl has been synthesized and characterized by using elemental analysis, IR and UV-Vis spectroscopy. Crystal structure of the complex shows that copper(II) ion lies in a square pyramidal coordination ...

  3. The interaction between mercury(II and sulfathiazole

    Directory of Open Access Journals (Sweden)

    Bellú Sebastián

    2003-01-01

    Full Text Available The interaction of mercury(II with sulfathiazole has been analyzed. IR and NMR spectral studies suggest a coordination of Hg(II with the Nthiazolic atom, unlike related Hg-sulfadrugs compounds. The complex was screened for its activity against Escherichia coli, showing an appreciable antimicrobial activity compared with the ligand.

  4. Pb II

    African Journals Online (AJOL)

    Windows User

    ., 2009) biomaterials. However, the ..... reported for various microorganisms by various researchers (Gong et al., 2005). At biomass ... the increase in initial Pb (II) was also observed for removal of Pb (II) by loofa sponge immobilized Aspergillus.

  5. An IR Navigation System for Pleural PDT

    Directory of Open Access Journals (Sweden)

    Timothy C Zhu

    2015-03-01

    Full Text Available Pleural photodynamic therapy (PDT has been used as an adjuvant treatment with lung-sparing surgical treatment for malignant pleural mesothelioma (MPM. In the current pleural PDT protocol, a moving fiber-based point source is used to deliver the light. The light fluences at multiple locations are monitored by several isotropic detectors placed in the pleural cavity. To improve the delivery of light fluence uniformity, an infrared (IR navigation system is used to track the motion of the light source in real-time at a rate of 20 - 60 Hz. A treatment planning system uses the laser source positions obtained from the IR camera to calculate light fluence distribution to monitor the light dose uniformity on the surface of the pleural cavity. A novel reconstruction algorithm is used to determine the pleural cavity surface contour. A dual-correction method is used to match the calculated fluences at detector locations to the detector readings. Preliminary data from a phantom shows superior light uniformity using this method. Light fluence uniformity from patient treatments is also shown with and without the correction method.

  6. Perception range prediction for IR pilot sight

    Science.gov (United States)

    Weiss, A. Robert; Großmann, Peter; Repasi, Endre; Ritt, Gunnar; Wittenstein, Wolfgang

    2008-04-01

    The increasing use of IR pilot sight in helicopters calls for a reliable prediction of perception ranges for a variety of objects, especially those needed for orientation and those posing as a potential hazard, like power poles, masts, isolated trees etc. Since the visibility of objects in the IR depends mainly on the temperature differences between those objects and a given background and only marginally on illumination, range prediction techniques used for the visual range or light-amplified vision are only of very limited use. While range predictions based on the Johnson criterion do offer some insight into expected ranges, the inherently nominal nature of distance estimates thus obtained hampers their use for an actual field-deployable pre-flight consulting procedure. In order to overcome those limitations, long-term simultaneous measurements of relevant objects and background temperatures and weather data were carried out and used for temperature prediction from prevalent weather conditions. Together with a perception model derived from extensive observer experiments based on synthetic images of the UH Tiger Pilot Sight Unit we developed a perception range prediction package which is currently evaluated by the weather service of the Bundeswehr. We will present results from the observer experiments together with the derived perception models. These are then compared to actual perception ranges as obtained from flight experiments.

  7. Enhancing image quality produced by IR cameras

    Science.gov (United States)

    Dulski, R.; Powalisz, P.; Kastek, M.; Trzaskawka, P.

    2010-10-01

    Images produced by IR cameras are a specific source of information. The perception and interpretation of such image greatly depends on thermal properties of observed object and surrounding scenery. In practice, the optimal settings of the camera as well as automatic temperature range control do not guarantee the displayed images is optimal from observer's point of view. The solution to this could be the methods and algorithms of digital image processing implemented in the camera. Such solution should provide intelligent, dynamic contrast control applied not only across entire image but also selectively to specific areas in order to maintain optimal visualization of observed scenery. The paper discusses problems dealing with improvement of the visibility of low-contrast objects and presents method of image enhancement. The algorithm is based on adaptive histogram equalization. The image enhancement algorithm was tested on real IR images. The algorithm significantly improves the image quality and the effectiveness of object detection for the majority of thermal images. Due to its adaptive nature it should be effective for any given thermal image. The application of such algorithm is promising alternative to more expensive opto-electronic components like improved optics and detectors.

  8. Stable states in a strong IR field

    Science.gov (United States)

    Zhong, Changchun; Robicheaux, Francis

    2015-05-01

    It is found that 10% of atoms stay in the quasi-stable states after being exposed to intense laser or microwave (MW) pulses, even though the pulses' intensity is much stronger than that needed for static fields ionization. The reason why atoms survive those strong pulses has attracted growing attentions. A. Arakelyan et al. have observed the optical spectra of the surviving Lithium atoms after interaction with intense 38-GHz MW fields for more than 1000 cycles, and the spectra exhibit a periodic train of peaks 38 GHz apart. It suggests that those weakly bound Rydberg electrons seldom go back to the ionic core, where the cycle average energy exchange happens. In this study, we are interested in the electron behavior in the presence of intense infrared fields with a much shorter wavelength (1000 nm). By solving the full 3D time dependent Schrodinger equation, we calculate the spectra of the surviving atoms under intense IR fields. Our numerical calculations show atoms survive the intense field in quasi-stable states for a long time, and the optical spectra are obviously modulated by the IR frequency. Through tuning the ponderomotive energy, we see how field parameters affect the behavior of electrons. Different atoms, such as Hydrogen, Helium, Lithium, and Sodium, are tested to see how atom's energy structures influence the results.

  9. Qualification tests for 192Ir sealed sources

    Science.gov (United States)

    Iancso, Georgeta; Iliescu, Elena; Iancu, Rodica

    2013-12-01

    This paper describes the results of qualification tests for 192Ir sealed sources, available in Testing and Nuclear Expertise Laboratory of National Institute for Physics and Nuclear Engineering "Horia Hulubei" (I.F.I.N.-HH), Romania. These sources had to be produced in I.F.I.N.-HH and were tested in order to obtain the authorization from The National Commission for Nuclear Activities Control (CNCAN). The sources are used for gammagraphy procedures or in gammadefectoscopy equipments. Tests, measurement methods and equipments used, comply with CNCAN, AIEA and International Quality Standards and regulations. The qualification tests are: 1. Radiological tests and measurements: dose equivalent rate at 1 m; tightness; dose equivalent rate at the surface of the transport and storage container; external unfixed contamination of the container surface. 2. Mechanical and climatic tests: thermal shock; external pressure; mechanic shock; vibrations; boring; thermal conditions for storage and transportation. Passing all tests, it was obtained the Radiological Security Authorization for producing the 192Ir sealed sources. Now IFIN-HH can meet many demands for this sealed sources, as the only manufacturer in Romania.

  10. Wafer level test solutions for IR sensors

    Science.gov (United States)

    Giessmann, Sebastian; Werner, Frank-Michael

    2014-05-01

    Wafer probers provide an established platform for performing electrical measurements at wafer level for CMOS and similar process technologies. For testing IR sensors, the requirements are beyond the standard prober capabilities. This presentation will give an overview about state of the art IR sensor probing systems reaching from flexible engineering solutions to automated production needs. Cooled sensors typically need to be tested at a target temperature below 80 K. Not only is the device temperature important but also the surrounding environment is required to prevent background radiation from reaching the device under test. To achieve that, a cryogenic shield is protecting the movable chuck. By operating that shield to attract residual gases inside the chamber, a completely contamination-free test environment can be guaranteed. The use of special black coatings are furthermore supporting the removal of stray light. Typically, probe card needles are operating at ambient (room) temperature when connecting to the wafer. To avoid the entrance of heat, which can result in distorted measurements, the probe card is fully embedded into the cryogenic shield. A shutter system, located above the probe field, is designed to switch between the microscope view to align the sensor under the needles and the test relevant setup. This includes a completely closed position to take dark current measurements. Another position holds a possible filter glass with the required aperture opening. The necessary infrared sources to stimulate the device are located above.

  11. Plasma thruster development program at the IRS

    Science.gov (United States)

    Auweter-Kurtz, Monika

    Since the early eighties the development of plasma thrusters has been an important research topic at the IRS, where a broad spectrum of stationary plasma thrusters has been investigated experimentally as well as theoretically. High power MPD thrusters (50 kW-1 MW) and a wide range of thermal arcjets (0.5-150 kW) are developed under contracts with ESA, NASA, USAF, USNAVY and with German funding. The IRS has excellent installations for continuous tests of high power accelerators. The high current power supply is a current regulated d.c. thyristor rectifier of 6 MW. The maximum current is 48 kA with a ripple less than 1%. The vacuum system is a roots pump system consisting of four stages with a total suction power of about 250,000 m 3/h at 1 Pa. Eight vacuum tanks of different sizes are connected to this system; six of them are used for plasma thruster development and two serve as plasma wind tunnels. For low power arcjet development and basic cathode erosion experiments four additional independent test stands are available.

  12. Irène Jacob visits CERN

    CERN Multimedia

    CERN Bulletin

    2010-01-01

    French actress Irène Jacob, the daughter of physicist Maurice Jacob, visited the ATLAS and CMS control rooms on Monday 17 May together with Italian theatre actor-director Pippo Delbono, in search of inspiration for a short film. The film will be screened at the “nuit des particules” event accompanying this year’s ICHEP.   Pippo Delbono et Irène Jacob discussing their project. “La nuit des particules” (night of the particles) is an event open to the general public that is being organised for the evening of Tuesday, 27 July, to accompany the 35th International Conference on High Energy Physics (ICHEP). ICHEP is a major highlight in every physicist’s calendar, and this year’s edition is being held in Paris from 22 to 28 July. The short film will be screened during the evening, which will include a lecture and a show at the legendary Parisian cinema Le Grand Rex, with a colossal seating capacity of 2 700 spe...

  13. An IR Navigation System for Pleural PDT

    Science.gov (United States)

    Zhu, Timothy; Liang, Xing; Kim, Michele; Finlay, Jarod; Dimofte, Andreea; Rodriguez, Carmen; Simone, Charles; Friedberg, Joseph; Cengel, Keith

    2015-03-01

    Pleural photodynamic therapy (PDT) has been used as an adjuvant treatment with lung-sparing surgical treatment for malignant pleural mesothelioma (MPM). In the current pleural PDT protocol, a moving fiber-based point source is used to deliver the light. The light fluences at multiple locations are monitored by several isotropic detectors placed in the pleural cavity. To improve the delivery of light fluence uniformity, an infrared (IR) navigation system is used to track the motion of the light source in real-time at a rate of 20 - 60 Hz. A treatment planning system uses the laser source positions obtained from the IR camera to calculate light fluence distribution to monitor the light dose uniformity on the surface of the pleural cavity. A novel reconstruction algorithm is used to determine the pleural cavity surface contour. A dual-correction method is used to match the calculated fluences at detector locations to the detector readings. Preliminary data from a phantom shows superior light uniformity using this method. Light fluence uniformity from patient treatments is also shown with and without the correction method.

  14. (II) complexes

    African Journals Online (AJOL)

    activities of Schiff base tin (II) complexes. Neelofar1 ... Conclusion: All synthesized Schiff bases and their Tin (II) complexes showed high antimicrobial and ...... Singh HL. Synthesis and characterization of tin (II) complexes of fluorinated Schiff bases derived from amino acids. Spectrochim Acta Part A: Molec Biomolec.

  15. HOMA1-IR and HOMA2-IR indexes in identifying insulin resistance and metabolic syndrome: Brazilian Metabolic Syndrome Study (BRAMS).

    Science.gov (United States)

    Geloneze, Bruno; Vasques, Ana Carolina Junqueira; Stabe, Christiane França Camargo; Pareja, José Carlos; Rosado, Lina Enriqueta Frandsen Paez de Lima; Queiroz, Elaine Cristina de; Tambascia, Marcos Antonio

    2009-03-01

    To investigate cut-off values for HOMA1-IR and HOMA2-IR to identify insulin resistance (IR) and metabolic syndrome (MS), and to assess the association of the indexes with components of the MS. Nondiabetic subjects from the Brazilian Metabolic Syndrome Study were studied (n = 1,203, 18 to 78 years). The cut-off values for IR were determined from the 90th percentile in the healthy group (n = 297) and, for MS, a ROC curve was generated for the total sample. In the healthy group, HOMA-IR indexes were associated with central obesity, triglycerides and total cholesterol (p 2.7 and HOMA2-IR > 1.8; and, for MS were: HOMA1-IR > 2.3 (sensitivity: 76.8%; specificity: 66.7%) and HOMA2-IR > 1.4 (sensitivity: 79.2%; specificity: 61.2%). The cut-off values identified for HOMA1-IR and HOMA2-IR indexes have a clinical and epidemiological application for identifying IR and MS in Westernized admixtured multi-ethnic populations.

  16. Mid-IR Plasmonics, Cavity Coupled Excitations, and IR Spectra of Individual Airborne Particulate Matter

    Science.gov (United States)

    Luthra, Antriksh

    With the advances in plasmonics, new fields have evolved involving the mixing of light with various states like Surface Plasmons (SPs), Surface Phonons (SPh), molecular emitters or resonators, and wavelength scale cavities. This work concentrates on the interaction of infrared (IR) light with SPs, cavity modes, and molecular vibrations. In the first chapter, the field of Plasmonics is introduced from a classical and a quantum mechanical perspective and a comparison of both is presented. In Chapter 2, the interaction of cavity modes with vibrations is discussed. Briefly, when IR light is illuminated upon an etalon, its fringes disperse as function of angle. If there is a dielectric in a cavity having a vibrational transition in the fringe region, it leads to a strong interaction that gives rise to a Rabi splitting. Data was obtained from collaborators at the U.S. Naval Research Laboratory (NRL) and a derivation for the dispersion of etalon cavity modes was carried out to model the peak positions of the fringes. In Chapter 3, the excitation of Surface Plasmons Polaritons (SPPs) on metal bi-gratings is discussed. The resonance condition occurs when the momentum of the IR light parallel to the surface plus the grating vector match the momentum of the SPP. Experiments were performed in the GammaX space (ky=0) and the resonance peak positions were modeled with SPP momentum matching equations. In Chapter 4, the application of plasmonics in the mid-IR frequency range that overlaps with the frequencies of molecular vibrations is explored. The plasmonic mesh has interesting optical properties, it focuses more light in the holes and that leads to an enhancement of the IR spectra of a particle trapped in the mesh hole. In this work, plasmonic mesh is used to study airborne particles that are usually difficult to study using FTIR spectroscopy due to strong Mie scattering effect. Respiring dust particles of 4 microns size has significant negative health consequences. Different

  17. Electronic structure, local magnetism, and spin-orbit effects of Ir(IV)-, Ir(V)-, and Ir(VI)-based compounds

    Energy Technology Data Exchange (ETDEWEB)

    Laguna-Marco, M. A.; Kayser, P.; Alonso, J. A.; Martínez-Lope, M. J.; van Veenendaal, M.; Choi, Y.; Haskel, D.

    2015-06-01

    Element- and orbital-selective x-ray absorption and magnetic circular dichroism measurements are carried out to probe the electronic structure and magnetism of Ir 5d electronic states in double perovskite Sr2MIrO6 (M = Mg, Ca, Sc, Ti, Ni, Fe, Zn, In) and La2NiIrO6 compounds. All the studied systems present a significant influence of spin-orbit interactions in the electronic ground state. In addition, we find that the Ir 5d local magnetic moment shows different character depending on the oxidation state despite the net magnetization being similar for all the compounds. Ir carries an orbital contribution comparable to the spin contribution for Ir4+ (5d(5)) and Ir5+ (5d(4)) oxides, whereas the orbital contribution is quenched for Ir6+ (5d(3)) samples. Incorporation of a magnetic 3d atom allows getting insight into the magnetic coupling between 5d and 3d transition metals. Together with previous susceptibility and neutron diffractionmeasurements, the results indicate that Ir carries a significant local magnetic moment even in samples without a 3d metal. The size of the (small) net magnetization of these compounds is a result of predominant antiferromagnetic interactions between local moments coupled with structural details of each perovskite structure

  18. The Introduction of an Undergraduate Interventional Radiology (IR) Curriculum: Impact on Medical Student Knowledge and Interest in IR

    Energy Technology Data Exchange (ETDEWEB)

    Shaikh, M. [Bradford Royal Infirmary, Department of Radiology, Bradford Teaching Hospital Foundation Trust (United Kingdom); Shaygi, B. [Royal Devon and Exeter Hospital, Interventional Radiology Department (United Kingdom); Asadi, H., E-mail: asadi.hamed@gmail.com; Thanaratnam, P.; Pennycooke, K.; Mirza, M.; Lee, M., E-mail: mlee@rcsi.ie [Beaumont Hospital, Interventional Radiology Service, Department of Radiology (Ireland)

    2016-04-15

    IntroductionInterventional radiology (IR) plays a vital role in modern medicine, with increasing demand for services, but with a shortage of experienced interventionalists. The aim of this study was to determine the impact of a recently introduced IR curriculum on perception, knowledge, and interest of medical students regarding various aspects of IR.MethodsIn 2014, an anonymous web-based questionnaire was sent to 309 4th year medical students in a single institution within an EU country, both before and after delivery of a 10-h IR teaching curriculum.ResultsSeventy-six percent (236/309) of the respondents participated in the pre-IR module survey, while 50 % (157/309) responded to the post-IR module survey. While 62 % (147/236) of the respondents reported poor or no knowledge of IR compared to other medical disciplines in the pre-IR module survey, this decreased to 17 % (27/157) in the post-IR module survey. The correct responses regarding knowledge of selected IR procedures improved from 70 to 94 % for venous access, 78 to 99 % for uterine fibroid embolization, 75 to 97 % for GI bleeding embolization, 60 to 92 % for trauma embolization, 71 to 92 % for tumor ablation, and 81 to 94 % for angioplasty and stenting in peripheral arterial disease. With regard to knowledge of IR clinical roles, responses improved from 42 to 59 % for outpatient clinic review of patients and having inpatient beds, 63–76 % for direct patient consultation, and 43–60 % for having regular ward rounds. The number of students who would consider a career in IR increased from 60 to 73 %.ConclusionDelivering an undergraduate IR curriculum increased the knowledge and understanding of various aspects of IR and also the general enthusiasm for pursuing this specialty as a future career choice.

  19. Judicious Design of Cationic, Cyclometalated Ir(III) Complexes for Photochemical Energy Conversion and Optoelectronics.

    Science.gov (United States)

    Mills, Isaac N; Porras, Jonathan A; Bernhard, Stefan

    2018-02-20

    The exponential growth in published studies on phosphorescent metal complexes has been triggered by their utilization in optoelectronics, solar energy conversion, and biological labeling applications. Very recent breakthroughs in organic photoredox transformations have further increased the research efforts dedicated to discerning the inner workings and structure-property relationships of these chromophores. Initially, the principal focus was on the Ru(II)-tris-diimine complex family. However, the limited photostability and lack of luminescence tunability discovered in these complexes prompted a broadening of the research to include 5d transition metal ions. The resulting increase in ligand field splitting prevents the population of antibonding e g * orbitals and widens the energy range available for color tuning. Particular attention was given to Ir(III), and its cyclometalated, cationic complexes have now replaced Ru(II) in the vast majority of applications. At the start, this Account documents the initial efforts dedicated to the color tuning of these complexes for their application in light emitting electrochemical cells, an easy to fabricate single-layer organic light emitting device (OLED). Systematic modifications of the ligand sphere of [Ir(ppy) 2 bpy] + (ppy: 2-phenylpyridine, bpy: 2,2'-bipyridine) with electron withdrawing and donating substituents allowed access to complexes with luminescence emission maxima throughout the visible spectrum exhibiting room temperature excited state lifetimes ranging from nanoseconds to dozens of microseconds and quantum yields up to 15 times that of [Ru(bpy) 3 ] 2+ . The diverse photophysical properties were also beneficial when using these Ir(III) complexes for driving solar fuel-producing reactions. For instance, photocatalytic water-reduction systems were explored to gain access to efficient water splitting systems. For this purpose, a variety of water reduction catalysts were paired with libraries of Ir

  20. Unsaturated b-ketoesters and their Ni(II, Cu(II and Zn(II complexes

    Directory of Open Access Journals (Sweden)

    MUHAMMED BASHEER UMMATHUR

    2009-03-01

    Full Text Available A new series of b-ketoesters in which the keto group is attached to the olefinic linkage were synthesized by the reaction of methyl acetoacetate and aromatic aldehydes under specified conditions. The existence of these compounds predominantly in the intramolecularly hydrogen bonded enol form was well demonstrated from their IR, 1H-NMR and mass spectral data. Details on the formation of their [ML2] complexes with Ni(II, Cu(II and Zn(II and the nature of the bonding are discussed on the basis of analytical and spectral data.

  1. Carbosilane Metallodendrimers with Cyclopentadienyldichlorotitanium(IV) End Groups

    Czech Academy of Sciences Publication Activity Database

    Krupková, Alena; Čermák, Jan

    2012-01-01

    Roč. 22, č. 2 (2012), s. 470-477 ISSN 1574-1443 R&D Projects: GA MŠk(CZ) LC06070 Institutional research plan: CEZ:AV0Z40720504 Keywords : carbosilane dendrimers * cyclopentadienyl ligands * fluorine -containing ligands Subject RIV: CC - Organic Chemistry Impact factor: 1.174, year: 2012

  2. Polydiphenylacetylene with Schiff Base End Groups: Synthesis and Characterization

    Science.gov (United States)

    Kalinova, Radostina; Jossifov, Christo

    The carbonyl-olefin exchange reaction is a new reaction between carbonyl group and olefin double bond, which has a formal similarity with the olefin metathesis - one carbon atom in the latter is replaced with an oxygen atom. Till now the new reaction is performed successfully only when the two functional groups (carbonyl group and olefin double bond) are in one molecule and are conjugated. The α, β-unsaturated carbonyl compounds (substituted propenones) are the compounds with such a structure. They polymerize giving substituted polyacetylenes. The chain propagation step of this polymerization is in fact the carbonyl-olefin exchange reaction. The question arises: is it possible the carbonyl-olefin exchange reaction to take place when the two functional groups are not in one molecule and are not conjugated, and could this reaction become an alternative of the existing carbonyl olefination reactions?

  3. ATF2 tests and CLIC IR study

    CERN Document Server

    Angal-Kalinin, D; Jones, J; Scarfe, A; Tygier, S

    2013-01-01

    This task covered three separate subtasks dealing with ILC and CLIC beam delivery system and Interaction region studies as well as testing the tuning procedures at ATF2 final focus test facility. The proposed local chromaticity correction final focus system for both ILC as well as CLIC is being tested experimentally for the first time at ATF2, various tuning procedures have been applied to study the applicability of various procedures to the ILC and CLIC to optimize the interaction region. The CLIC IR region was studied in detail, and the impact and mitigation of CLIC detector solenoid effects on the beam orbit, coupling and extraction have been considered. The work programme of this task concentrated on central region integration of the ILC following the design changes proposed during the technical design phase of the ILC, participation in ATF2 beam tuning studies and CLIC interaction region studies.

  4. IR-780 Loaded Phospholipid Mimicking Homopolymeric Micelles for Near-IR Imaging and Photothermal Therapy of Pancreatic Cancer.

    Science.gov (United States)

    Chen, Yangjun; Li, Zuhong; Wang, Haibo; Wang, Yin; Han, Haijie; Jin, Qiao; Ji, Jian

    2016-03-23

    IR-780 iodide, a near-infrared (near-IR) fluorescent dye, can be utilized as an effective theranostic agent for both imaging and photothermal therapy. However, its lipophilicity limits its further biomedical applications. Herein, we synthesized a phospholipid mimicking amphiphilic homopolymer poly(12-(methacryloyloxy)dodecyl phosphorylcholine) (PMDPC) via reversible addition-fragmentation chain transfer (RAFT) polymerization. The amphiphilic homopolymer PMDPC can be self-assembled into micelles and used for the encapsulation of IR-780. The IR-780 loaded micelles (PMDPC-IR-780) exhibited low cytotoxicity in the dark, whereas remarkable photothermal cytotoxicity to pancreatic cancer cells (BxPC-3) was observed upon near-IR laser irradiation. We further investigated in vivo biodistribution of PMDPC-IR-780 micelles. Higher accumulation of PMDPC-IR-780 than that of free IR-780 in tumor tissue was verified, which might be ascribed to the enhanced permeability and retention (EPR) effect and long circulation time benefiting from the zwitterionic phosphorylcholine surface. Therefore, the IR-780 loaded phospholipid mimicking homopolymeric micelles could have great potential for cancer theranostics.

  5. Endurance test on IR rig for RI production

    International Nuclear Information System (INIS)

    Chung, Heung June; Youn, Y. J.; Han, H. S.; Hong, S. B.; Cho, Y. G.; Ryu, J. S.

    2000-12-01

    This report presents the pressure drop, vibration and endurance test results for IR rig for RI production which were desigened and fabricated by KAERI. From the pressure drop test results, it is noted that the flow rate through the IR rig corresponding to the pressure drop of 200 kPa is measured to be about 3.12 kg/sec. Vibration frequency for the IR rig ranges from 13 to 17 Hz. RMS(Root Mean Square) displacement for the IR rig is less than 30 μm, and the maximum displacement is less than 110μm. These experimental results show that the design criteria of IR rig meet the HANARO limit conditions. Endurance test results show that the appreciable fretting wear for the IR rig does not occur, however tiny trace of wear between contact points is observed

  6. Study on IR Properties of Reduced Graphene Oxide

    Science.gov (United States)

    Ma, Deyue; Li, Xiaoxia; Guo, Yuxiang; Zeng, Yurun

    2018-01-01

    Firstly, the reduced graphene oxide was prepared by modified hummer method and characterized. Then, the complex refractive index of reduced graphene oxide in IR band was tested and its IR absorption and radiation properties were researched by correlated calculation. The results show that reduced graphene oxide prepared by hummer method are multilayered graphene with defects and functional groups on its surface. Its absorption in near and far IR bands is strong, but it’s weaker in middle IR band. At the IR atmosphere Window, its normal spectral emissivity decreases with wavelength increasing, and its total normal spectral emissivity in 3 ∼ 5μm and 8 ∼ 14μm are 0.75 and 0.625, respectively. Therefore, reduced graphene oxide can be used as IR absorption and coating materials and have a great potential in microwave and infrared compatible materials.

  7. IR sensor for monitoring of burner flame; IR sensor foer oevervakning av braennarflamma

    Energy Technology Data Exchange (ETDEWEB)

    Svanberg, Marcus; Funkquist, Jonas; Clausen, Soennik; Wetterstroem, Jonas

    2007-12-15

    To obtain a smooth operation of the coal-fired power plants many power plant managers have installed online mass flow measurement of coal to all burners. This signal is used to monitor the coal mass flow to the individual burner and match it with appropriate amount of air and also to monitor the distribution of coal between the burners. The online mass flow measurement system is very expensive (approximately 150 kEUR for ten burners) and is not beneficial for smaller plants. The accuracy of the measurement and the sample frequency are also questionable. The idea in this project has been to evaluate a cheaper system that can present the same information and may also provide better accuracy and faster sample frequency. The infrared sensor is a cheap narrow banded light emission sensor that can be placed in a water cooed probe. The sensor was directed at the burner flame and the emitted light was monitored. Through calibration the mass flow of coal can be presented. Two measurement campaigns were performed. Both campaigns were carried out in Nordjyllandsverket in Denmark even though the second campaign was planned to be in Uppsala. Due to severe problems in the Uppsala plant the campaign was moved to Nordjyllandsverket. The pre-requisites for the test plant were that online measurement of coal flow was installed. In Nordjyllandsverket 4 out of 16 burners have the mass flow measurement installed. Risoe Laboratories has vast experiences in the IR technology and they provided the IR sensing equipment. One IR sensor was placed in the flame guard position just behind the flame directed towards the ignition zone. A second sensor was placed at the boiler wall directed towards the flame. The boiler wall position did not give any results and the location was not used during the second campaign. The flame-guard-positioned-sensor- signal was thoroughly evaluated and the results show that there is a clear correlation between the coal mass flow and the IR sensor signal. Tests were

  8. New Ir Bis-Carbonyl Precursor for Water Oxidation Catalysis

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Daria L. [Department of Chemistry, Yale University, 225; Beltrán-Suito, Rodrigo [Department of Chemistry, Yale University, 225; Thomsen, Julianne M. [Department of Chemistry, Yale University, 225; Hashmi, Sara M. [Department of Chemical and Environmental; Materna, Kelly L. [Department of Chemistry, Yale University, 225; Sheehan, Stafford W. [Catalytic Innovations LLC, 70 Crandall; Mercado, Brandon Q. [Department of Chemistry, Yale University, 225; Brudvig, Gary W. [Department of Chemistry, Yale University, 225; Crabtree, Robert H. [Department of Chemistry, Yale University, 225

    2016-02-05

    This paper introduces IrI(CO)2(pyalc) (pyalc = (2-pyridyl)-2-propanoate) as an atom-efficient precursor for Ir-based homogeneous oxidation catalysis. This compound was chosen to simplify analysis of the water oxidation catalyst species formed by the previously reported Cp*IrIII(pyalc)OH water oxidation precatalyst. Here, we present a comparative study on the chemical and catalytic properties of these two precursors. Previous studies show that oxidative activation of Cp*Ir-based precursors with NaIO4 results in formation of a blue IrIV species. This activation is concomitant with the loss of the placeholder Cp* ligand which oxidatively degrades to form acetic acid, iodate, and other obligatory byproducts. The activation process requires substantial amounts of primary oxidant, and the degradation products complicate analysis of the resulting IrIV species. The species formed from oxidation of the Ir(CO)2(pyalc) precursor, on the other hand, lacks these degradation products (the CO ligands are easily lost upon oxidation) which allows for more detailed examination of the resulting Ir(pyalc) active species both catalytically and spectroscopically, although complete structural analysis is still elusive. Once Ir(CO)2(pyalc) is activated, the system requires acetic acid or acetate to prevent the formation of nanoparticles. Investigation of the activated bis-carbonyl complex also suggests several Ir(pyalc) isomers may exist in solution. By 1H NMR, activated Ir(CO)2(pyalc) has fewer isomers than activated Cp*Ir complexes, allowing for advanced characterization. Future research in this direction is expected to contribute to a better structural understanding of the active species. A diol crystallization agent was needed for the structure determination of 3.

  9. Electrical and Optical Characterization System for IR Photodetectors

    Science.gov (United States)

    2015-10-12

    Electrical and Optical Characterization System for IR Photodetectors The views, opinions and/or findings contained in this report are those of the...published in non peer-reviewed journals: Final Report: Electrical and Optical Characterization System for IR Photodetectors Report Title This DURIP project...Final Report for the ARO DURIP Program Electrical and Optical Characterization System for IR Photodetectors Grant No.: W911NF-14-1-0446   Period 01

  10. Adaptive IR Sensing Based on Advanced Nanostructures with Tunable Kinetics

    Science.gov (United States)

    2015-11-05

    AFRL-AFOSR-VA-TR-2015-0360 ADAPTIVE IR SENSING BASED ON ADVANCED NANOSTRUCTURES WITH TUNABLE KINETICS Vladimir Mitin RESEARCH FOUNDATION OF STATE...1 August 2010 - 31 July 2015 4. TITLE AND SUBTITLE Adaptive IR Sensing Based on Advanced Nanostructures with Tunable Kinetics 5a. CONTRACT NUMBER...engineering, and technological basis for further development of IR nanomaterials with nanoscale potential profile that can be effectively controlled by

  11. Room temperature mid-IR single photon spectral imaging

    DEFF Research Database (Denmark)

    Dam, Jeppe Seidelin; Tidemand-Lichtenberg, Peter; Pedersen, Christian

    2012-01-01

    Spectral imaging and detection of mid-infrared (mid-IR) wavelengths are emerging as an enabling technology of great technical and scientific interest; primarily because important chemical compounds display unique and strong mid-IR spectral fingerprints revealing valuable chemical information. Whi...... 20 % for polarized incoherent light at 3 \\mum. The proposed method is relevant for existing and new mid-IR applications like gas analysis and medical diagnostics....

  12. Physicochemical properties of 3,4,5-trimethoxybenzoates of Mn(II, Co(II, Ni(II and Zn(II

    Directory of Open Access Journals (Sweden)

    W. FERENC

    2005-09-01

    Full Text Available The complexes of Mn(II, Co(II, Ni(II, Cu(II and Zn(II with 3,4,5-trimethoxybenzoic acid anion of the formula: M(C10H11O52·nH2O, where n = 6 for Ni(II, n = 1 for Mn(II, Co(II, Cu(II, and n = 0 for Zn, have been synthesized and characterized by elemental analysis, IR spectroscopy, X–ray diffraction measurements, thermogravimetry and magnetic studies. They are crystalline compounds characterized by various symmetry. They decompose in various ways when heated in air to 1273 K. At first, they dehydrate in one step and form anhydrous salts. The final products of decomposition are oxides of the respective metals (Mn2O3, Co3O4, NiO, CuO, ZnO. The solubilities of the analysed complexes in water at 293 K are in the orders of 10-2 – 10-4 mol dm-3. The magnetic susceptibilities of the Mn(II, Co(II, Ni(II and Cu(II complexes were measured over the range of 76–303 K and the magnetic moments were calculated. The results show that the 3,4,5-trimethoxybenzoates of Mn(II, Co(II and Ni(II are high-spin complexes but that of Cu(II forms a dimer [Cu2(C10H11O54(H2O2]. The carboxylate groups bind as monodentate or bidentate chelating or bridging ligands.

  13. Medicare Modernization Act (MMA) IRS Medicare Part D

    Data.gov (United States)

    Social Security Administration — SSA uses the Internal Revenue Service (IRS) information in determing the eligibility of Medicare recipients to receive subsidy payments for Medicare premiums. SSA...

  14. Role of IRS-2 in insulin and cytokine signalling.

    Science.gov (United States)

    Sun, X J; Wang, L M; Zhang, Y; Yenush, L; Myers, M G; Glasheen, E; Lane, W S; Pierce, J H; White, M F

    1995-09-14

    The protein IRS-1 acts as an interface between signalling proteins with Src-homology-2 domains (SH2 proteins) and the receptors for insulin, IGF-1, growth hormone, several interleukins (IL-4, IL-9, IL-13) and other cytokines. It regulates gene expression and stimulates mitogenesis, and appears to mediate insulin/IGF-1-stimulated glucose transport. Thus, survival of the IRS-1-/- mouse with only mild resistance to insulin was surprising. This dilemma is provisionally resolved with our discovery of a second IRS-signalling protein. We purified and cloned a likely candidate called 4PS from myeloid progenitor cells and, because of its resemblance to IRS-1, we designate it IRS-2. Alignment of the sequences of IRS-2 and IRS-1 revealed a highly conserved amino terminus containing a pleckstrin-homology domain and a phosphotyrosine-binding domain, and a poorly conserved carboxy terminus containing several tyrosine phosphorylation motifs. IRS-2 is expressed in many cells, including tissues from IRS-1-/- mice, and may be essential for signalling by several receptor systems.

  15. Supercontinuum based mid-IR imaging spectroscopy for cancer detection

    DEFF Research Database (Denmark)

    Bang, Ole; Møller, Uffe Visbech; Kubat, Irnis

    2014-01-01

    The mid-infrared (IR) spectral region is of significant technical and scientific interest because most molecules display fundamental vibrational absorptions in this region, leaving distinct spectral fingerprints. To date, the limitations of mid-IR light sources, such as thermal emitters, low-powe...... cancer detection with mid-IR imaging spectroscopy.......-project.eu] DTU Fotonik has now demonstrated the first optical fiber based broadband so-called supercontinuum light souce, which covers 1.4-13.3 μm and thereby most of the molecular fingerprint region [1]. This ultra-fast light source is the basic component in the mid-IR camera developed in MINERVA for early...

  16. Local Mode Analysis: Decoding IR Spectra by Visualizing Molecular Details.

    Science.gov (United States)

    Massarczyk, M; Rudack, T; Schlitter, J; Kuhne, J; Kötting, C; Gerwert, K

    2017-04-20

    Integration of experimental and computational approaches to investigate chemical reactions in proteins has proven to be very successful. Experimentally, time-resolved FTIR difference-spectroscopy monitors chemical reactions at atomic detail. To decode detailed structural information encoded in IR spectra, QM/MM calculations are performed. Here, we present a novel method which we call local mode analysis (LMA) for calculating IR spectra and assigning spectral IR-bands on the basis of movements of nuclei and partial charges from just a single QM/MM trajectory. Through LMA the decoding of IR spectra no longer requires several simulations or optimizations. The novel approach correlates the motions of atoms of a single simulation with the corresponding IR bands and provides direct access to the structural information encoded in IR spectra. Either the contributions of a particular atom or atom group to the complete IR spectrum of the molecule are visualized, or an IR-band is selected to visualize the corresponding structural motions. Thus, LMA decodes the detailed information contained in IR spectra and provides an intuitive approach for structural biologists and biochemists. The unique feature of LMA is the bidirectional analysis connecting structural details to spectral features and vice versa spectral features to molecular motions.

  17. Synthesis, magnetic and spectroscopic studies of Ni(II, Cu(II, Zn(II and Cd(II complexes of a newly Schiff base derived from 5-bromo-2-hydroxybezylidene-3,4,5-trihydroxybenzohydrazide

    Directory of Open Access Journals (Sweden)

    Mahmood A. Abdullah

    2012-12-01

    Full Text Available A new hydrazide Shiff base ligand GHL1 (5-bromo-2-hydroxybezylidene-3,4,5-trihydroxybenzohydrazide was prepared by refluxing of trihydroxybenzhydrazide with an ethanolic of 5-bromo-2-hydroxybenzaldehyde. The ligand reacted with Ni(II, Cu(II, Zn(II and Cd(II (acetate salts. All the complexes were characterized by elemental analysis, molar conductivity, TGA, UV-Vis and FT-IR spectral studies. All the complexes have octahedral geometry except Ni(II complex which has tetrahedral geometry.DOI: http://dx.doi.org/10.4314/bcse.v26i1.10

  18. Local structural displacements across the structural phase transition in IrTe2: Order-disorder of dimers and role of Ir-Te correlations

    Science.gov (United States)

    Joseph, B.; Bendele, M.; Simonelli, L.; Maugeri, L.; Pyon, S.; Kudo, K.; Nohara, M.; Mizokawa, T.; Saini, N. L.

    2013-12-01

    We have studied local structure of IrTe2 by Ir L3-edge extended x-ray absorption fine structure (EXAFS) measurements as a function of temperature to investigate origin of the observed structural phase transition at Ts˜270 K. The EXAFS results show an appearance of longer Ir-Te bond length (ΔR ˜0.05 Å) at T Ir-Ir dimerization, characterized by distinct Ir-Ir bond lengths (ΔR ˜0.13 Å), existing both above and below Ts. The results suggest that the phase transition in IrTe2 should be an order-disorder-like transition of Ir-Ir dimers assisted by Ir-Te bond correlations, thus indicating important role of the interaction between the Ir 5d and Te 5p orbitals in this transition.

  19. In-situ IR monitoring of the formation of Zr-fumarate MOF

    CSIR Research Space (South Africa)

    Ren, Jianwei

    2017-05-01

    Full Text Available : (a) Phase I, ZrCl4/DMF solution; (b) Phase II, add formic acid; (c) Phase III, add fumaric acid/DMF solution; (d) Phase IV, heat up the reaction; and (e) the 60 min in-situ IR reaction. The consumptions of both formic acid and DMF were observed... from Figure 2 (pointed out by red arrows) when being added into the ZrCl4/DMF solution, indicating formic acid and DMF participated in the structure formation of Zr-fum MOF crystals. Comparing the results from Figure 1b, Figure 2 and Table S1...

  20. Template Synthesis, Characterization and Biological Activity of Cu(II, Ni(II, Co(II, Zn(IIComplexes with Isonicotinoylhydrazone--2-aldehydefluorene Ligand

    Directory of Open Access Journals (Sweden)

    2010-01-01

    Full Text Available This is about synthesizing new complex combinations of Cu(II, Ni(II,Co(II, Zn(II with aroylhydrazone ligand isonicotinoylhydrazone-2-aldehydefluorene (INHAF made by condensation of isonicotinoylhydrazine with 2-aldehydefluorene. The complexes have been characterized by analytical data, IR, UV-Vis, NMR spectra, magnetic susceptibility values, thermal analysis and for the Cu(II complex the ESR spectrum has been registered. For all complexes the biological activity against the Staphylo-coccus aureus, Escherichia coli, Klebssiella pneumoniae bacteria has been investigated. The experimental data sustain stoichiometry of 1:2 (metal/ligand for the Cu(II, Ni(II, Zn(II complexes and of 1:1 for the complex with Co(II. The electronic spectra and the magnetic moments suggest octahedral stereochemistry at the complexes with Cu(II, Ni(II and the tetrahedral geometry for the Co(II complex. The INHAF ligand is coordinated bidentate by the O=C amide oxygen and the azomethine nitrogen in the complexes of Cu(II, Ni(II, Co(II and monodentate by the azomethine nitrogen in the complex of Zn(II.

  1. An exploration of the online investor relations (IR practices of companies listed on the Johannesburg Stock Exchange (JSE

    Directory of Open Access Journals (Sweden)

    Leana Esterhuyse

    2016-05-01

    Full Text Available Prior research has found that having better investor relations (IR practices contributes towards improved share prices, liquidity of shares and analyst following. The main aim of this study was to determine the extent to which JSE-listed companies comply with international best practice guidelines for IR practices via the company’s website. A secondary objective was to arrive at an opinion regarding the stage of internet adoption for IR practices in which JSE-listed companies find themselves, based on Hedlin’s (1999 three-stage model. A checklist of 201 items was used to assess the websites of 205 JSE-listed companies from the beginning of July to mid-September 2012. The average online IR score for all 205 companies was found to be disappointing, although the top 100 companies in South Africa performed better than companies in other emerging and developing economies, but worse than companies in advanced economies, where size is probably the main differentiator. Bandwidth is also a constraining factor for online IR quality in South Africa. We conclude that instead of moving towards stage III (HTML, video and audio of Hedlin’s model (1999, JSE listed companies still seem to find themselves in stage II (paper-equivalent PDF’s. This should concern Chief Financial Officers (CFOs, as effective and efficient communication with investors could contribute towards attaining optimal share prices and improved liquidity and analyst following.

  2. Epithelial-mesenchymal transition predicts sensitivity to the dual IGF-1R/IR inhibitor OSI-906 in hepatocellular carcinoma cell lines.

    Science.gov (United States)

    Zhao, Hui; Desai, Vidhi; Wang, Jian; Epstein, David M; Miglarese, Mark; Buck, Elizabeth

    2012-02-01

    A growing body of data indicates that inhibiting the type 1 insulin-like growth factor receptor (IGF-1R) might be an effective treatment strategy for hepatocellular carcinoma (HCC). OSI-906 is a dual IGF-1R/IR kinase inhibitor currently in phase II clinical development for HCC. However, biomarkers are lacking to help identify patients with HCC who are more likely to benefit from OSI-906 treatment. We sought to determine the effect of OSI-906 on proliferation against a panel of 21 HCC cell lines and to investigate molecular determinants of responsiveness to OSI-906. We identified a subset of HCC cell lines that was sensitive to OSI-906, and sensitivity is associated with elevated phosphorylation levels of IGF-1R and IR and greater inhibition of AKT signaling. Dual targeting of both receptors seems to be important for maximal inhibition as treatment with a selective IGF-1R-neutralizing antibody was associated with increased IR signaling, whereas OSI-906 fully inhibited both phosphorylated IR and IGF-1R and resulted in greater inhibition of the IRS/AKT pathway. Epithelial-mesenchymal transition (EMT) seems to predict HCC cell sensitivity to OSI-906, as the epithelial phenotype is strongly associated with expression of IGF-2 and IR, activation of IGF-1R and IR, and sensitivity to OSI-906, alone or in combination with erlotinib. Induction of EMT upon treatment with TGFβ reduced sensitivity to OSI-906. Collectively, these data support the concept for dual IGF-1R/IR targeting in HCC, where EMT status and expressions of IGF-2 and IR may be used to identify those patients who are most likely to benefit from treatment with an IGF-1R/IR dual inhibitor.

  3. Copper (II)

    African Journals Online (AJOL)

    CLEMENT O BEWAJI

    ABSTRACT: A Schiff base was prepared from the reaction of 2 - amino - 3 – methylbutanoic acid and 2, 4 - pentanedione. The reaction of the prepared Schiff base with ethanolic solution of copper (II) chloride formed diaquo bis( N – 2 – amino – 3 - methylbutyl - 2, 4 - pentanedionato) copper (II) complex. The Schiff base is ...

  4. Calibrated Mid-wave Infrared (IR) (MidIR) and Long-wave IR (LWIR) Stokes and Degree-of-Liner Polarization (DOLP)

    National Research Council Canada - National Science Library

    Gurton, Kristan P; Felton, Melvin

    2008-01-01

    ...., the 3-5 mu and 8-12 mu regions. Meteorological parameters measured during the study include temperature, relative humidity, wind speed/direction, precipitation, and ambient atmospheric IR loading...

  5. Photonics of a conjugated organometallic Pt-Ir polymer and its model compounds exhibiting hybrid CT excited states.

    Science.gov (United States)

    Soliman, Ahmed M; Fortin, Daniel; Zysman-Colman, Eli; Harvey, Pierre D

    2012-04-13

    Trans- dichlorobis(tri-n-butylphosphine)platinum(II) reacts with bis(2- phenylpyridinato)-(5,5'-diethynyl-2,2'-bipyridine)iridium(III) hexafluorophosphate to form the luminescent conjugated polymer poly[trans-[(5,5'-ethynyl-2,2'-bipyridine)bis(2- phenylpyridinato)-iridium(III)]bis(tri-n-butylphosphine)platinum(II)] hexafluorophosphate ([Pt]-[Ir])n. Gel permeation chromatography indicates a degree of polymerization of 9 inferring the presence of an oligomer. Comparison of the absorption and emission band positions and their temperature dependence, emission quantum yields, and lifetimes with those for models containing only the [Pt] or the [Ir] units indicates hybrid excited states including features from both chromophores. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Spitzer IRS Observations of FU Orionis Objects

    Science.gov (United States)

    Green, J. D.; Hartmann, L.; Calvet, N.; Watson, D. M.; Ibrahimov, M.; Furlan, E.; Sargent, B.; Forrest, W. J.

    2006-09-01

    We present 5-35 μm spectra, taken with the Infrared Spectrograph (IRS) on the Spitzer Space Telescope, of five FU Orionis objects: FU Ori, V1515 Cyg, V1057 Cyg, BBW 76, and V346 Nor. All but V346 Nor reveal amorphous silicate grains in emission at 10 and 20 μm, and show water-vapor absorption bands at 5.8 and 6.8 μm and SiO or possibly methane absorption at 8 μm. These absorption features closely match these bands in model stellar photospheres-signs of the gaseous photospheres of the inner regions of these objects' accretion disks. The continuum emission at 5-8 μm is also consistent with such disks, and, for FU Orionis and BBW 76, longer wavelength emission may be fit by a model that includes moderate disk flaring. V1057 Cyg and V1515 Cyg have much more emission at longer wavelengths than the others, perhaps evidence of a substantial remnant of their natal, infalling envelopes.

  7. Characterization of Hydrogen Bonds by IR Spectroscopy

    Directory of Open Access Journals (Sweden)

    Vojta, D.

    2012-05-01

    Full Text Available In the identification and quantification of hydrogen bond, as one of the most abundant non-covalent interactions in phenomena like self-assembly and molecular recognition, IR spectrosopy has been employed as the most sensitive method. The performance of the high dilution method enables determination of the stability constant of hydrogen-bonded complex as one of the most important thermodynamic quantities used in their characterization. However, the alleged experimental simplicity of the mentioned method is loaded with errors originating not only from researcher intervention but also independent from it. The second source of error is particularly emphasized and elaborated in this paper, which is designed as the recipe for the successful characterization of hydrogen bonds. Besides the enumeration of all steps in the determination of hydrogen-bonded stability constants, the reader can be acquainted with the most important ex perimental conditions that should be fulfilled in order to minimize the naturally occurring errors in this type of investigation. In the spectral analysis, the application of both uni- and multivariate approach has been discussed. Some computer packages, considering the latter, are mentioned, described, and recommended. KUI -10/2012Received August 1, 2011Accepted October 24, 2011

  8. Microstructures as IR-sensors with Staphylococcus aureus bacteria

    Science.gov (United States)

    Baikova, T. V.; Danilov, P. A.; Gonchukov, S. A.; Yermachenko, V. M.; Ionin, A. A.; Khmelnitskii, R. A.; Kudryashov, S. I.; Nguyen, T. T. H.; Rudenko, A. A.; Saraeva, I. N.; Svistunova, T. S.; Zayarny, D. A.

    2017-09-01

    Using a micro-hole grating in a supported silver film as a laser-fabricated novel optical platform for surface-enhanced IR absoprtion/reflection spectroscopy, characteristic absorption bands of Staphylococcus aureus, especially - its buried carotenoid fragments - were detected in FT-IR spectra with 10-fold analytical enhancement, paving the way to spectral express-identification of the pathogenic microorganisms.

  9. Cross calibration of IRS-P4 OCM satellite sensor

    Digital Repository Service at National Institute of Oceanography (India)

    Suresh, T.; Desa, E.; Mascarenhas, A.A.M.Q.; Matondkar, S.G.P.; Naik, P.; Nayak, S.R.

    obtained from the radiative transfer simulations of IRS-P4 OCM and SeaWiFS. The chlorophyll a values derived using the calibrated IRS-P4 OCM are found to be comparable with those derived from SeaWiFS and in close agreement with the measured values...

  10. NaIrO3-A pentavalent post-perovskite

    International Nuclear Information System (INIS)

    Bremholm, M.; Dutton, S.E.; Stephens, P.W.; Cava, R.J.

    2011-01-01

    Sodium iridium (V) oxide, NaIrO 3, was synthesized by a high pressure solid state method and recovered to ambient conditions. It is found to be isostructural with CaIrO 3 , the much-studied structural analog of the high-pressure post-perovskite phase of MgSiO 3 . Among the oxide post-perovskites, NaIrO 3 is the first example with a pentavalent cation. The structure consists of layers of corner- and edge-sharing IrO 6 octahedra separated by layers of NaO 8 bicapped trigonal prisms. NaIrO 3 shows no magnetic ordering and resistivity measurements show non-metallic behavior. The crystal structure, electrical and magnetic properties are discussed and compared to known post-perovskites and pentavalent perovskite metal oxides. -- Graphical abstract: Sodium iridium(V) oxide, NaIrO 3 , synthesized by a high pressure solid state method and recovered to ambient conditions is found to crystallize as the post-perovskite structure and is the first example of a pentavalent ABO 3 post-perovskite. Research highlights: → NaIrO 3 post-perovskite stabilized by pressure. → First example of a pentavalent oxide post-perovskite. → Non-metallic and non-magnetic behavior of NaIrO 3 .

  11. Understanding pave-IR : background, use, and advanced techniques

    Science.gov (United States)

    2010-01-01

    Why Has TxDOT Implemented Pave-IR? : Promote more uniform, higher quality pavements : Minimize/eliminate thermal segregation : Expand range of weather conditions for paving : Special Provision 341-024 : Contains option for contractor to use Pave-IR :...

  12. EXACT DIAGONALIZATION RESULTS FOR MULTIMAGNON IR ABSORPTION IN THE CUPRATES

    NARCIS (Netherlands)

    Lorenzana, J.; Eder, R; Meinders, M.B J; Sawatzky, G.A

    1995-01-01

    Recent measured bands in the mid IR of parent insulating compounds of cuprate superconductors [Perkins et al. Phys. Rev. Lett. 71 1621 (1993)] are interpreted as multimagnon infrared (IR) absorption assisted by phonons. We present results for the coupling constant of light with this excitations and

  13. New Directions for IR, the DQP, and Tuning

    Science.gov (United States)

    Jankowski, Natasha A.; Marshall, David W.

    2015-01-01

    This concluding essay provides a glimpse to the future and alerts IR professionals to related initiatives as well as provides an update to ongoing work with DQP and Tuning. Pulling from the prior chapters it provides some implications for IR offices to consider, not only in their work with the DQP and Tuning, but in terms of general decision…

  14. Bringing NMR and IR Spectroscopy to High Schools

    Science.gov (United States)

    Bonjour, Jessica L.; Hass, Alisa L.; Pollock, David W.; Huebner, Aaron; Frost, John A.

    2017-01-01

    Development of benchtop, portable Fourier transform nuclear magnetic resonance (NMR) and infrared (IR) spectrometers has opened up opportunities for creating university-high school partnerships that provide high school students with hands-on experience with NMR and IR instruments. With recent changes to the international baccalaureate chemistry…

  15. A Simulation Program for Dynamic Infrared (IR) Spectra

    Science.gov (United States)

    Zoerb, Matthew C.; Harris, Charles B.

    2013-01-01

    A free program for the simulation of dynamic infrared (IR) spectra is presented. The program simulates the spectrum of two exchanging IR peaks based on simple input parameters. Larger systems can be simulated with minor modifications. The program is available as an executable program for PCs or can be run in MATLAB on any operating system. Source…

  16. Median Measure: An Approach to IR Systems Evaluation.

    Science.gov (United States)

    Greisdorf, Howard; Spink, Amanda

    2001-01-01

    Results from three studies examining 1295 relevance judgments by 36 information retrieval (IR) system end-users are reported. Both the region of the relevance judgments, from non-relevant to highly relevant, and motivations or levels for the relevance judgments are examined. Implications for relevance theory and IR systems evaluation are…

  17. Operational experience - Lessons learned from IRS-reports in Germany

    International Nuclear Information System (INIS)

    Wetzel, N.; Maqua, M.

    2005-01-01

    The international Incident Reporting System (IRS), jointly operated by IAEA and OECD-NEA, is a main source of safety significant findings and lessons learned of nuclear operating experience. GRS (Gesellschaft fuer Anlagen- und Reaktorsicherheit mbH) is a scientific-technical expert and research organisation. On Behalf of the Federal Minister of Environment, Nature Conservation and Reactor Safety (BMU), GRS provides the IRS officer. The evaluation of IRS-Reports and the dissemination of the main findings including the assessment of the relevance for German NPPs is task of GRS. The value of IRS is among experts undoubted. But nevertheless, the reporting to IRS decreases since some years. This presentation is aimed to show the support of IRS in strengthening the safety of German NPPs. The evaluation of IRS-Reports at GRS is three-fold. It comprises initial screening, quarterly and yearly reporting and the development of specific German Information Notices on safety significant events with direct applicability to German NPPs. Some examples of lessons learned from recent international events are discussed below. These examples shall demonstrate that the use of the IRS enhances significantly the knowledge on operational events. (author)

  18. 78 FR 913 - IRS Truncated Taxpayer Identification Numbers

    Science.gov (United States)

    2013-01-07

    ... using a social security number (SSN), IRS individual taxpayer identification number (ITIN), or IRS... individual's social security account number. Section 6109(d) provides that, except as otherwise specified under regulations, the social security account number issued to an individual under the Social Security...

  19. Simulation of Wakefield Effect in ILC IR Chamber

    Energy Technology Data Exchange (ETDEWEB)

    Pei, S; Seryi, A.; Raubenheimer, T.O.; /SLAC

    2008-06-26

    To achieve super high luminosity, high current beams with very short bunch length are needed, which carry high intensity EM fields. For ILC, two bunch trains with bunch length of 300 {micro}m and bunch charge of 3.2nC are needed to collide at the IR to achieve the ILC luminosity goals. When the 300 {micro}m bunches pass through the IR chamber, wakefields will be excited, which will cause HOM power flowing through the IR chamber beam pipe to the final doublets due to the high frequency characteristic of the induced wakefields. Since superconducting technology is adopted for the final doublets of ILC BDS, whose operation stability might be affected by the HOM power produced at the IR chamber, quench might happen. In this paper, we did some analytical estimation and numerical simulation on the wakefield effects in ILC IR chamber.

  20. Defense Strategy of Aircraft Confronted with IR Guided Missile

    Directory of Open Access Journals (Sweden)

    Hesong Huang

    2017-01-01

    Full Text Available Surface-type infrared (IR decoy can simulate the IR characteristics of the target aircraft, which is one of the most effective equipment to confront IR guided missile. In the air combat, the IR guided missile poses a serious threat to the aircraft when it comes from the front of target aircraft. In this paper, firstly, the model of aircraft and surface-type IR decoy is established. To ensure their authenticity, the aircraft maneuver and radiation models based on real data of flight and exhaust system radiation in the state of different heights and different speeds are established. Secondly, the most effective avoidance maneuver is simulated when the missile comes from the front of the target aircraft. Lastly, combining maneuver with decoys, the best defense strategy is analysed when the missile comes from the front of aircraft. The result of simulation, which is authentic, is propitious to avoid the missile and improve the survivability of aircraft.

  1. Rapid Quantitative Analysis of the Major Components in Soymilk Using Fourier-Transform Infrared Spectroscopy (FT-IR)

    OpenAIRE

    NAKASATO, Katsuhiko; ONO, Tomotada; ISHIGURO, Takahiro; TAKAMATSU, Michihiko; TSUKAMOTO, Chigen; MIKAMI, Masayuki

    2004-01-01

    Fourier-transform infrared spectroscopy (FT-IR) on attenuated total reflectance (ATR) sampling was used for the quantitative analysis of the major components (protein, lipid, and sugar) in soymilk. Since mid-infrared spectroscopy shows specific absorption of each functional group of each molecule, it is possible to determine the amount of each component without complicated statistical computation. The determination of protein content was performed by using amide II absorbance at wavenumber 15...

  2. Protection of p+-n-Si Photoanodes by Sputter-Deposited Ir/IrOxThin Films

    DEFF Research Database (Denmark)

    Mei, Bastian Timo; Seger, Brian; Pedersen, Thomas

    2014-01-01

    Sputter deposition of Ir/IrOx on p+-n-Si without interfacial corrosion protection layers yielded photoanodes capable of efficient water oxidation (OER) in acidic media (1 M H2SO4). Stability of at least 18 h was shown by chronoamperomety at 1.23 V versus RHE (reversible hydrogen electrode) under 38...

  3. The effect of test dose and first IR stimulation temperature on post-IR IRSL measurements of rock slices

    DEFF Research Database (Denmark)

    Liu, Jinfeng; Murray, Andrew; Sohbati, Reza

    2016-01-01

    lies close to the laboratory saturation levels only for higher first IR stimulation temperatures e.g. 200°C or 250°C. Our data confirm earlier suggestions based on sand-grain measurements that, for older sam-ples, accurate measurements close to saturation require that a higher first IR temperature...

  4. Near-IR Electrochromism in Electrodeposited Thin Films of Cyclometalated Complexes.

    Science.gov (United States)

    Ionescu, Andreea; Aiello, Iolinda; La Deda, Massimo; Crispini, Alessandra; Ghedini, Mauro; De Santo, Maria Penelope; Godbert, Nicolas

    2016-05-18

    Homogeneous thin films of controlled thickness obtained from cyclometalated complexes of general formula [(C(∧)N)M(O(∧)N)], where M = Pd(II) or Pt(II), H(C(∧)N) = 2-phenylpyridine and, respectively, 2-thienylpyridine and H(O(∧)N) = a triphenylamine functionalized Schiff base, have been deposited by oxidative electropolymerization. The films have been electrochemically and morphologically characterized. The metallopolymeric thin films present stable reversible redox behavior and typical cauliflower-like textures in agreement with a nucleation-growth electropolymerization mechanism. However, the film growth is greatly influenced by the nature of the metal center, with a higher tendency of the Pt complexes to promote the 3D growth. Furthermore, a complete spectroelectrochemical study has been performed on electrodeposited films showing near-IR absorption in the oxidized state, high contrast ratios (up to 65%) and low response times.

  5. Near-IR period-luminosity relations for pulsating stars in ω Centauri (NGC 5139)

    Science.gov (United States)

    Navarrete, C.; Catelan, M.; Contreras Ramos, R.; Alonso-García, J.; Gran, F.; Dékány, I.; Minniti, D.

    2017-08-01

    Aims: The globular cluster ω Centauri (NGC 5139) hosts hundreds of pulsating variable stars of different types, thus representing a treasure trove for studies of their corresponding period-luminosity (PL) relations. Our goal in this study is to obtain the PL relations for RR Lyrae and SX Phoenicis stars in the field of the cluster, based on high-quality, well-sampled light curves in the near-infrared (IR). Methods: Observations were carried out using the VISTA InfraRed CAMera (VIRCAM) mounted on the Visible and Infrared Survey Telescope for Astronomy (VISTA). A total of 42 epochs in J and 100 epochs in KS were obtained, spanning 352 days. Point-spread function photometry was performed using DoPhot and DAOPHOT crowded-field photometry packages in the outer and inner regions of the cluster, respectively. Results: Based on the comprehensive catalog of near-IR light curves thus secured, PL relations were obtained for the different types of pulsators in the cluster, both in the J and KS bands. This includes the first PL relations in the near-IR for fundamental-mode SX Phoenicis stars. The near-IR magnitudes and periods of Type II Cepheids and RR Lyrae stars were used to derive an updated true distance modulus to the cluster, with a resulting value of (m - M)0 = 13.708 ± 0.035 ± 0.10 mag, where the error bars correspond to the adopted statistical and systematic errors, respectively. Adding the errors in quadrature, this is equivalent to a heliocentric distance of 5.52 ± 0.27 kpc. Based on observations collected at the European Organisation for Astronomical Research in the Southern Hemisphere, Chile, with the VISTA telescope (project ID 087.D-0472, PI R. Angeloni).

  6. Evaluation of the influence of UV/IR radiation on iron release from ferritin

    International Nuclear Information System (INIS)

    Gritzkov, M.; Kochev, V.; Vladimirova, L

    2010-01-01

    In the present work the influence of UV/IR radiation on the iron-releasing process from ferritin is investigated. The ferritins are a family of iron-storing proteins playing a key role in the biochemical reactions between iron and oxygen-processes of exclusive importance for the existence of all living organisms. The iron is stored within the ferritin core in the form of insoluble crystals containing Fe(III). Therefore for its release, the mineral matrix has to be decomposed, usually through a reduction of Fe(III) to Fe(II). Our study considers the action of UV/IR radiation on the structure of the protein molecule. Eventual changes in the ferritin conformation under the irradiation could result in the change of channel forming regions responsible for the iron efflux. This can be assess by the quantity of Fe (II) obtained in a subsequent mobilization procedure evoked by exogenous reducing agents. In our case the content of the reduced iron is determined electrochemically by the method of potentiometric titration. As already was shown, this method promises to become highly useful for quantitative evaluation of released Fe 2+ . (Author)

  7. Near-IR imaging of demineralization under sealants

    Science.gov (United States)

    Tom, Henry; Chan, Kenneth H.; Darling, Cynthia L.; Fried, Daniel

    2014-02-01

    Previous studies have shown that near-IR reflectance and transillumination imaging can be used to acquire high contrast images of early caries lesions and composite restorative materials. The aim of the study was to determine the optimum near-IR wavelengths for imaging demineralized areas under dental sealants. Fifteen natural human premolars and molars with occlusal lesions were used in this in vitro study. Images before and after application of sealants were acquired using near-IR reflectance and near-IR transillumination at wavelengths of 1300 nm, 1460 nm, and 1500 - 1700 nm. Images were also acquired using polarization sensitive optical coherence tomography for comparison. The highest contrast for near- IR reflectance was at 1460 nm and 1500 - 1700 nm. These near-IR wavelengths are coincident with higher water absorption. The clear Delton sealant investigated was not visible in either co-polarization or crosspolarization OCT images. The wavelength region between 1500-1700-nm yielded the highest contrast of lesions under sealants for near-IR reflectance measurements.

  8. Potentiometric and spectrophotometric studies of Mn{sup II} and Ni{sup II} cimetidine complexes

    Energy Technology Data Exchange (ETDEWEB)

    Kanumfre, Francieli; Lima, Eliane M. de; Scheidt, Gabriele; Carneiro, Paulo I.B.; Rosso, Neiva D., E-mail: ndrosso@uepg.b [Universidade Estadual de Ponta Grossa, PR (Brazil). Dept. de Quimica

    2010-07-01

    Cimetidine is an important hydrogen histamine receptor which has the ability to chelate metal ions in blood plasma and in different tissues. This study aimed to determine the stability constants for the cimetidine ligand with Mn{sup II} and Ni{sup II} metallic ions, synthesizing complexes and characterizing them by infrared spectroscopy, IR, and hydrogen nuclear magnetic resonance, {sup 1}H NMR. Cimetidine protonation constant regarding to the imidazole group was log K 7.05 and the stability constants for Mn{sup II} and Ni{sup II} complexes, ML{sub 2} species were log K 3.75 and 2.97, respectively, in 0.100 mol L{sup -1} KCl. The interpretation of IR and {sup H}1 NMR spectra for complexes Mn{sup II}-cim{sub 2} and Ni{sup II}-cim{sub 2} indicated that their formation occurs through the sulfur atoms in the thiol group, nitrogen atoms of imidazole ring, and nitrogen atoms of secondary amine. The nitrile group seems to be involved in the complexation of the Ni{sup II}-cim{sub 2} complex. (author)

  9. IR-inducible clusterin gene expression: a protein with potential roles in ionizing radiation-induced adaptive responses, genomic instability, and bystander effects

    Energy Technology Data Exchange (ETDEWEB)

    Klokov, Dmitry [Laboratory of Molecular Stress Responses, Department of Radiation Oncology, Case Western Reserve University, 2103 Cornell Road, Wolstein Research Building 3-531, Cleveland, OH 44106-4942 (United States); Criswell, Tracy [Laboratory of Molecular Stress Responses, Department of Radiation Oncology, Case Western Reserve University, 2103 Cornell Road, Wolstein Research Building 3-531, Cleveland, OH 44106-4942 (United States); Program in Molecular and Cellular Basis of Disease, Case Western Reserve University School of Medicine, Cleveland, OH 44106-4942 (United States); Leskov, Konstantin S. [Laboratory of Molecular Stress Responses, Department of Radiation Oncology, Case Western Reserve University, 2103 Cornell Road, Wolstein Research Building 3-531, Cleveland, OH 44106-4942 (United States); Araki, Shinako [Laboratory of Molecular Stress Responses, Department of Radiation Oncology, Case Western Reserve University, 2103 Cornell Road, Wolstein Research Building 3-531, Cleveland, OH 44106-4942 (United States); Mayo, Lindsey [Laboratory of Molecular Stress Responses, Department of Radiation Oncology, Case Western Reserve University, 2103 Cornell Road, Wolstein Research Building 3-531, Cleveland, OH 44106-4942 (United States); Boothman, David A. [Laboratory of Molecular Stress Responses, Department of Radiation Oncology, Case Western Reserve University, 2103 Cornell Road, Wolstein Research Building 3-531, Cleveland, OH 44106-4942 (United States) and Program in Molecular and Cellular Basis of Disease, Case Western Reserve University School of Medicine, Cleveland, OH 44106-4942 (United States)]. E-mail: dab30@po.cwru.edu

    2004-12-02

    Clusterin (CLU) plays numerous roles in mammalian cells after stress. A review of the recent literature strongly suggests potential roles for CLU proteins in low dose ionizing radiation (IR)-inducible adaptive responses, bystander effects, and delayed death and genomic instability. Its most striking and evident feature is the inducibility of the CLU promoter after low, as well as high, doses of IR. Two major forms of CLU, secreted (sCLU) and nuclear (nCLU), possess opposite functions in cellular responses to IR: sCLU is cytoprotective, whereas nCLU (a byproduct of alternative splicing) is a pro-death factor. Recent studies from our laboratory and others demonstrated that down-regulation of sCLU by specific siRNA increased cytotoxic responses to chemotherapy and IR. sCLU was induced after low non-toxic doses of IR (0.02-0.5 Gy) in human cultured cells and in mice in vivo. The low dose inducibility of this survival protein suggests a possible role for sCLU in radiation adaptive responses, characterized by increased cell radioresistance after exposure to low adapting IR doses. Although it is still unclear whether the adaptive response is beneficial or not to cells, survival of damaged cells after IR may lead to genomic instability in the descendants of surviving cells. Recent studies indicate a link between sCLU accumulation and cancer incidence, as well as aging, supporting involvement of the protein in the development of genomic instability. Secreted after IR, sCLU may also alter intracellular communication due to its ability to bind cell surface receptors, such as the TGF-{beta} receptors (types I and II). This interference with signaling pathways may contribute to IR-induced bystander effects. We hypothesize that activation of the TGF-{beta} signaling pathway, which often occurs after IR exposure, can in turn activate the CLU promoter. TGF-{beta} and IR-inducible de novo synthesized sCLU may then bind the TGF-{beta} receptors and suppress downstream growth arrest

  10. Patient Safety in Interventional Radiology: A CIRSE IR Checklist.

    LENUS (Irish Health Repository)

    2012-02-01

    Interventional radiology (IR) is an invasive speciality with the potential for complications as with other invasive specialities. The World Health Organization (WHO) produced a surgical safety checklist to decrease the morbidity and mortality associated with surgery. The Cardiovascular and Interventional Society of Europe (CIRSE) set up a task force to produce a checklist for IR. Use of the checklist will, we hope, reduce the incidence of complications after IR procedures. It has been modified from the WHO surgical safety checklist and the RAD PASS from Holland.

  11. Miesto šventinė įranga ir apipavidalinimas

    OpenAIRE

    Šimoliūnas, Tadas

    2008-01-01

    Magistro darbas “ Miesto šventinė įranga ir apipavidalinimas“ apima kelis objektus. Tai kompleksinio projektavimo darbas, kuriame labai svarbus ansambliškumas, bei harmoninga visuma. Kuriant šventinę įrangą buvo remiamasi bioninėmis formomis. Improvizuotos gyvosios gamtos formos įgalina sukurti neįprastus objektus, turinčius savitą stilistiką, tektoniką, ritmiką ir charakterį. Būtent iš gamtos nesenkančio šaltinio galima semtis naujų idėjų funkciniu ir estetiniu atžvilgiais. Lengvos konstrukc...

  12. Resonant photothermal IR spectroscopy of picogram samples with microstring resonator

    DEFF Research Database (Denmark)

    Yamada, Shoko; Schmid, Silvan; Boisen, Anja

    2013-01-01

    Here, we report a demonstration of resonant photothermal IR spectroscopy using microstrings in mid-infrared region providing rapid identification of picogram samples. In our microelectromechanical resonant photothermal IR spectroscopy system, samples are deposited directly on microstrings using...... an in-situ sampling method and the resonance frequency of the string is measured optically. Resonance frequency shifts, proportional to the absorbed heat, are recorded in real time as monochromatic infrared light is being scanned over the mid-infrared range. These resonant photothermal IR spectroscopy...

  13. Thin Film Electrodeposition of Ir(III Cyclometallated Complexes

    Directory of Open Access Journals (Sweden)

    Andreea Ionescu

    2016-01-01

    Full Text Available Novel electropolymerizable Ir(III cyclometallated complexes have been synthesized and characterized. In these complexes the cyclometallated ligands are either 2-phenylpyridine H(PhPy or benzothiazole-triphenylamine H(BzTh-tpa, while the Ir(III coordination sphere is completed by a Schiff base substituted with a triphenylamine fragment. A complete electrochemical study has been conducted on all complexes, in order to verify the feasibility of electropolymerization and to elucidate the role of the specific position of the triphenylamine moiety in the molecular structure. Homogeneous thin films of Ir(III metallopolymers have been successfully obtained through electropolymerization process.

  14. Linearly Polarized IR Spectroscopy Theory and Applications for Structural Analysis

    CERN Document Server

    Kolev, Tsonko

    2011-01-01

    A technique that is useful in the study of pharmaceutical products and biological molecules, polarization IR spectroscopy has undergone continuous development since it first emerged almost 100 years ago. Capturing the state of the science as it exists today, "Linearly Polarized IR Spectroscopy: Theory and Applications for Structural Analysis" demonstrates how the technique can be properly utilized to obtain important information about the structure and spectral properties of oriented compounds. The book starts with the theoretical basis of linear-dichroic infrared (IR-LD) spectroscop

  15. Chlorination of (PheboxIr(mesityl(OAc by Thionyl Chloride

    Directory of Open Access Journals (Sweden)

    Meng Zhou

    2015-06-01

    Full Text Available Pincer (PheboxIr(mesityl(OAc (2 (Phebox = 3,5-dimethylphenyl-2,6-bis(oxazolinyl complex, formed by benzylic C-H activation of mesitylene (1,3,5-trimethylbenzene using (PheboxIr(OAc2OH2 (1, was treated with thionyl chloride to rapidly form 1-(chloromethyl-3,5-dimethylbenzene in 50% yield at 23 °C. A green species was obtained at the end of reaction, which decomposed during flash column chromatography to form (PheboxIrCl2OH2 in 87% yield.

  16. Investigation of mid-IR picosecond image upconversion

    DEFF Research Database (Denmark)

    Mathez, Morgan David; Pedersen, Christian; Rodrigo, Peter John

    2017-01-01

    Imaging and spectroscopy in the mid-infrared (Mid-IR) wavelength region have received considerable attention in recent years. The reason is the high Mid-IR spectral specificity of many gases and complex molecules. In this pilot study we focus on picosecond upconversion imaging exploiting the χ(2......) nonlinearity of a bulk lithium niobate crystal as a means to convert the optical Mid-IR signal into the visible wavelength region, thus allowing the use of fast and sensitive silicon based CCD cameras. The picosecond upconversion system is synchronously pumped in order to increase the quantum efficiency, hence...

  17. THE STUDY OF CLINOPTILOLITE MODIFIED WITH3d METALS HALIDES BY IR AND DIFFUSE REFLECTANCE SPECTROSCOPY

    Directory of Open Access Journals (Sweden)

    T. L. Rakitskaya

    2015-11-01

    Full Text Available The results of investigation of natural clinoptilolite (N-CLI and that modified with 3d metal halides (MeCl2/N-CLI, where Me are Cu, Co, and Mn by IR and diffuse reflectance spectroscopy are summarized. A band at 3437 cm-1 assigned to stretching vibrations of hydroxyl groups (nOH is found in the IR spectrum of the N-CLI sample. A location of the band was practically the same as for all above MeCl2/N-CLI samples. A band of middle intensity at 1638 cm-1 in the range of deformation vibrations of zeolite water observed in the IR spectrum of N-CLI slightly displays to lower frequencies in the case of the modified samples. An intensive wide band of a complex shape in the range from 1250 to 980 cm-1 assigned to Si–O–Si and Si–O–Al vibrations appears in IR spectra of all samples. A doublet band of middle intensity at 797 and 778 cm-1 is assigned to external symmetric stretching T-O vibrations and a band at 606 cm-1-to vibrations of a double ring. A location of the above bands is the same for all listed samples but their intensity is higher for MnCl2/N-CLI and CoCl2/N-CLI samples. After the reaction with ozone, significant changes in the IR spectra are observed only for MnCl2/N-CLI. They are due to MnO2 formation on the clinoptilolite surface resulting in a high frequency displacement of some bands. Based on UV-vi spectroscopy results, it is reasonable to make conclusions about the coordination and valence state of a central atom in the MeCl2/N-CLI samples under study. A location of charge transfer bands for these samples only slightly differs from that for N-CLI however the intensity of such bands increases for the MeCl2/N-CLI samples. The UV-vis spectrum of MnCl2/N-CLI changes after the reaction with ozone: the appearance of new bands of  charge transfer at 363 and 354 nm and also the two-fold increase in intensity of a charge transfer band at 272 nm in comparison with those of N-CLI and MnCl2/N-CLI are the evidence of change in both the

  18. Characterization and biological studies on Co(II), Ni(II) and Cu(II) complexes of carbohydrazones ending by pyridyl ring

    Science.gov (United States)

    Abu El-Reash, G. M.; El-Gammal, O. A.; Ghazy, S. E.; Radwan, A. H.

    2013-03-01

    The chelating behavior of ligands based on carbohydrazone core modified with pyridine end towards Co(II), Ni(II) and Cu(II) ions have been examined. The ligands derived from the condensation of carbohydrazide with 2-acetylpyridine (H2APC) and 4-acetylpyridine (H2APEC). The 1H NMR, IR data and the binding energy calculations of H2APC revealed the presence of two stereoisomers syn and anti in the solid state and in the solution. The 1H NMR, IR data and the binding energy calculations confirmed the presence of H2APEC in one keto form only in the solid state and in the solution. The spectroscopic data confirmed that H2APC behaves as a monobasic pentadentate in Co(II) and Cu(II) complexes and as mononegative tetradentate in Ni(II) complex. On the other hand, H2APEC acts as a mononegative tridentate in Co(II) complex, neutral tridentate in Ni(II) complex and neutral bidentate in Cu(II) complex. The electronic spectra and the magnetic measurements of complexes as well as the ESR of the copper complexes suggested the octahedral geometry. The bond length and bond angles were evaluated by DFT method using material studio program. The thermal behavior and the kinetic parameters of degradation were determined using Coats-Redfern and Horowitz-Metzger methods. The antioxidant (DDPH and ABTS methods), anti-hemolytic and in vitro Ehrlich ascites of the compounds have been screened.

  19. Benzothiazolylazo derivatives of some β-dicarbonyl compounds and their Cu(II, Ni(II and Zn(II complexes

    Directory of Open Access Journals (Sweden)

    KRISHNANNAIR KRISHNANKUTTY

    2010-05-01

    Full Text Available The coupling of diazotized 2-aminobenzothiazole with 1,3-dicar-bonyl compounds (benzoylacetone, methyl acetoacetate and acetoacetanilide yielded a new series of tridentate ligand systems (HL. Analytical, IR, 1H--NMR, 13C-NMR and mass spectral data indicated that the compounds exist in the intramolecularly hydrogen bonded azo-enol tautomeric form in which one of the carbonyl groups of the dicarbonyl moiety had enolised and hydrogen bonded to one of the azo nitrogen atoms. The compounds formed stable complexes with Ni(II, Cu(II and Zn(II ions. The Cu(II complexes conform to [CuL(OAc] stoichiometry while the Ni(II and Zn(II complexes are in agreement with [ML2] stoichiometry. Analytical, IR, 1H-NMR, 13C-NMR and mass spectral data of the complexes are consistent with the replacement of the chelated enol proton of the ligand with a metal ion, thus leading to a stable six-membered chelate ring involving a cyclic nitrogen, one of the azo nitrogens and the enolate oxygen. The Zn(II chelates are diamagnetic while Cu(II and Ni(II complexes showed a normal paramagnetic moment.

  20. Ion beam synthesis of IrSi3 by implantation of 2 MeV Ir ions

    International Nuclear Information System (INIS)

    Sjoreen, T.P.; Chisholm, M.F.; Hinneberg, H.J.

    1992-11-01

    Formation of a buried IrSi 3 layer in (111) oriented Si by ion implantation and annealing has been studied at an implantation energy of 2 MeV for substrate temperatures of 450--550C. Rutherford backscattering (RBS), ion channeling and cross-sectional transmission electron microscopy showed that a buried epitaxial IrSi 3 layer is produced at 550C by implanting ≥ 3.4 x 10 17 Ir/cm 2 and subsequently annealing for 1 h at 1000C plus 5 h at 1100C. At a dose of 3.4 x 10 17 Ir/cm 2 , the thickness of the layer varied between 120 and 190 nm and many large IrSi 3 precipitates were present above and below the film. Increasing the dose to 4.4 x 10 17 Ir/cm 2 improved the layer uniformity at the expense of increased lattice damage in the overlying Si. RBS analysis of layer formation as a function of substrate temperature revealed the competition between the mechanisms for optimizing surface crystallinity vs. IrSi 3 layer formation. Little apparent substrate temperature dependence was evident in the as-implanted state but after annealing the crystallinity of the top Si layer was observed to deteriorate with increasing substrate temperature while the precipitate coarsening and coalescence improved

  1. Synthesis, characterization and cytotoxicity of mixed ligand Mn(II, Co(II and Ni(II complexes

    Directory of Open Access Journals (Sweden)

    Osman Souad A.

    2014-01-01

    Full Text Available Complexes of the type [ML'L(OH(H2O] {where M= Ni(II, Co(II or Mn(II, L'= isatin and HL= 3-(2-phenylhydrazonoacetylacetone, 3-(2-(4-chlorophenylhydrazonoacetylacetone or 3-(2-(4-bromophenylhydrazono-acetylacetone} have been synthesized by equimolar reaction of a metal(II chloride with isatin and 3-(2-(arylhydrazonoacetylacetone. The resulting complexes have been characterized by elemental analyses, molar conductivity, spectral data (IR, 1H NMR, mass and magnetic moments. Furthermore, the ligands and their metal complexes have been screened for their cytotoxicity against different human cancer cell lines by using SRB assay. The results showed that most of the mixed ligand metal complexes have high cytotoxicity in comparison with the reference drugs used.

  2. Mixed ligand complexes of alkaline earth metals: Part XII. Mg(II, Ca(II, Sr(II and Ba(II complexes with 5-chlorosalicylaldehyde and salicylaldehyde or hydroxyaromatic ketones

    Directory of Open Access Journals (Sweden)

    MITHLESH AGRAWAL

    2002-04-01

    Full Text Available The reactions of alkaline earth metal chlorides with 5-chlorosalicylaldehyde and salicylaldehyde, 2-hydroxyacetophenone or 2-hydroxypropiophenone have been carried out in 1 : 1 : 1 mole ratio and the mixed ligand complexes of the type MLL’(H2O2 (where M = Mg(II, Ca(II, Sr(II and Ba(II, HL = 5-chlorosalicylaldehyde and HL’ = salicylaldehyde, 2-hydroxyacetophenone or 2-hydroxypropiophenone have been isolated. These complexes were characterized by TLC, conductance measurements, IR and 1H-NMR spectra.

  3. Synthesis, investigation and spectroscopic characterization of piroxicam ternary complexes of Fe(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) with glycine and DL-phenylalanine

    Science.gov (United States)

    Mohamed, Gehad G.; El-Gamel, Nadia E. A.

    2004-11-01

    The ternary piroxicam (Pir; 4-hydroxy-2-methyl- N-(2-pyridyl)-2H-1,2-benzothiazine-3-carboxamide 1,1-dioxide) complexes of Fe(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) with various amino acids (AA) such as glycine (Gly) or DL-phenylalanine (PhA) were prepared and characterized by elemental analyses, molar conductance, IR, UV-Vis, magnetic moment, diffuse reflectance and X-ray powder diffraction. The UV-Vis spectra of Pir and the effect of metal chelation on the different interligand transitions are discussed in detailed manner. IR and UV-Vis spectra confirm that Pir behaves as a neutral bidentate ligand coordinated to the metal ions via the pyridine- N and carbonyl group of the amide moiety. Gly molecule acted as a uninegatively monodentate ligand and coordinate to the metal ions through its carboxylic group, in addition PhA acted as a uninegatively bidentate ligand and coordinate to the metal ions through its carboxylic and amino groups. All the chelates have octahedral geometrical structures while Cu(II)- and Zn(II)-ternary chelates with PhA have square planar geometrical structures. The molar conductance data reveal that most of these chelates are non electrolytes, while Fe(III)-Pir-Gly, Co(II)-, Ni(II)-, Cu(II)- and Zn(II)-Pir-PhA cheletes were 1:1 electrolytes. X-ray powder diffraction is used as a new tool to estimate the crystallinity of chelates as well as to elucidate their geometrical structures.

  4. Fleet Protection Using a Small UAV Based IR Sensor

    National Research Council Canada - National Science Library

    Buss, James R; Ax, Jr, George R

    2005-01-01

    A study was performed to define candidate electro-optical and infrared (EO/IR) sensor configurations and assess their potential utility as small UAV-based sensors surveilling a perimeter around surface fleet assets...

  5. FT-IR, RAMAN AND DFT STUDIES ON THE VIBRATIONAL ...

    African Journals Online (AJOL)

    Bis(aminoethoxy)propane, IR spectra, Raman spectra, Molecular structure, DFT. INTRODUCTION. Ketal based linkages have recently been investigated for the development of novel acid- cleavable polymers those are formulated into the ...

  6. Characterization of Momordica charantia Ussing FT-IR Spectroscopy

    Directory of Open Access Journals (Sweden)

    Attila Keseru

    2016-11-01

    In this paper, because earlier claim shows that the plant used as stomachic, carminative, tonic, antipyretic, antidiabetic, in rheumatoid arthritis and gout, the present investigation was carried to characterized a principal components of plant using FT-IR technique

  7. COMPARISON OF SIMPLE AND CHELATED AMBERLITE IR-120 ...

    African Journals Online (AJOL)

    13] have also been used. Many chelating ligands such as quinolone, ... synthesized by covalent bonds are much more resistant to external effects than those by simple adsorption [15]. Amberlite IR-120, a vinyl benzene polymer has good ...

  8. Analysis of effect of cable degradation on SPND IR calculation

    International Nuclear Information System (INIS)

    Tamboli, P.K.; Sharma, A.; Prasad, A.D.; Singh, Nita; Antony, J.; Kelkar, M.G.; Kaurav, Reetesh; Pramanik, M.

    2013-01-01

    Neutron flux is the most vital parameter in the nuclear reactor safety against Neutronic over power. The modern days Indian PHWRs with large core size are loosely coupled reactors and hence In-core Self Power Neutron Detectors (SPNDs) are most suitable for monitoring local neutron power for generating Regional Overpower Trip. However the SPNDs and its Mineral Insulation Cable are prone to IR loss due to use of ceramic insulation which are highly hygroscopic. The present paper covers the online analysis of IR f degraded cable as per the surveillance requirement of monitoring the IR to assess the healthiness of SPNDs which are part of SSC/SSE for Reactor Protection Systems. The paper also proposes an alternative method for monitoring IR for startup//low power range when SPND signals are yet to pick up and Reactor Control and Protection are based on out of core Ionization Chambers. (author)

  9. Dynamic IR Scene Projector Based Upon the Digital Micromirror Device

    National Research Council Canada - National Science Library

    Beasley, D. B; Bender, Matt; Crosby, Jay; Messer, Tim; Saylor, Daniel A

    2001-01-01

    ...). The MAPS is based upon the Texas Instruments Digital Micromirror Device (DMD) which has been modified to project images which are suitable for testing sensor and seekers operating in the UV, visible, and IR wavebands...

  10. Upconversion applied for mid-IR hyperspectral image acquisition

    DEFF Research Database (Denmark)

    Tidemand-Lichtenberg, Peter; Kehlet, Louis Martinus; Sanders, Nicolai Højer

    2015-01-01

    Different schemes for upconversion mid-IR hyperspectral imaging is implemented and compared in terms of spectral coverage, spectral resolution, speed and noise. Phasematch scanning and scanning of the object within the field of view is considered....

  11. PTEN is a protein tyrosine phosphatase for IRS1.

    Science.gov (United States)

    Shi, Yuji; Wang, Junru; Chandarlapaty, Sarat; Cross, Justin; Thompson, Craig; Rosen, Neal; Jiang, Xuejun

    2014-06-01

    The biological function of the PTEN tumor suppressor is mainly attributed to its lipid phosphatase activity. This study demonstrates that mammalian PTEN is a protein tyrosine phosphatase that selectively dephosphorylates insulin receptor substrate-1 (IRS1), a mediator of insulin and IGF signals. IGF signaling was defective in cells lacking NEDD4, a PTEN ubiquitin ligase, whereas AKT activation triggered by EGF or serum was unimpaired. Defective IGF signaling caused by NEDD4 deletion, including phosphorylation of IRS1 and AKT, was rescued by PTEN ablation. We demonstrate the nature of PTEN as an IRS1 phosphatase by direct biochemical analysis and cellular reconstitution, showing that NEDD4 supports insulin-mediated glucose metabolism and is required for the proliferation of IGF1 receptor-dependent but not EGF receptor-dependent tumor cells. Thus, PTEN is a protein phosphatase for IRS1, and its antagonism by NEDD4 promotes signaling by IGF and insulin.

  12. A Modified Harris Corner Detection for Breast IR Image

    Directory of Open Access Journals (Sweden)

    Chia-Yen Lee

    2014-01-01

    Full Text Available Harris corner detectors, which depend on strong invariance and a local autocorrelation function, display poor detection performance for infrared (IR images with low contrast and nonobvious edges. In addition, feature points detected by Harris corner detectors are clustered due to the numerous nonlocal maxima. This paper proposes a modified Harris corner detector that includes two unique steps for processing IR images in order to overcome the aforementioned problems. Image contrast enhancement based on a generalized form of histogram equalization (HE combined with adjusting the intensity resolution causes false contours on IR images to acquire obvious edges. Adaptive nonmaximal suppression based on eliminating neighboring pixels avoids the clustered features. Preliminary results show that the proposed method can solve the clustering problem and successfully identify the representative feature points of IR breast images.

  13. Surface temperature measurements of heterogeneous explosives by IR emission

    Energy Technology Data Exchange (ETDEWEB)

    Henson, B.F.; Funk, D.J.; Dickson, P.M.; Fugard, C.S.; Asay, B.W.

    1998-03-01

    The authors present measurements of the integrated IR emission (1--5 {micro}m) from both the heterogeneous explosive PBX 9501 and pure HMX at calibrated temperatures from 300 C to 2,500 C. The IR power emitted as a function of temperature is that expected of a black body, attenuated by a unique temperature independent constant which the authors report as the thermal emissivity. The authors have utilized this calibration of IR emission in measurements of the surface temperature from PBX 9501 subject to 1 GPa, two dimensional impact, and spontaneous ignition in unconfined cookoff. They demonstrate that the measurement of IR emission in this spectral region provides a temperature probe of sufficient sensitivity to resolve the thermal response from the solid explosive throughout the range of weak mechanical perturbation, prolonged heating to ignition, and combustion.

  14. IceBridge KT19 IR Surface Temperature V001

    Data.gov (United States)

    National Aeronautics and Space Administration — The NASA IceBridge KT19 IR Surface Temperature data set contains surface temperature measurements of Arctic and Antarctic sea ice and land ice acquired using the...

  15. Patient Safety in Interventional Radiology: A CIRSE IR Checklist

    NARCIS (Netherlands)

    Lee, M. J.; Fanelli, F.; Haage, P.; Hausegger, K.; van Lienden, K. P.

    2012-01-01

    Interventional radiology (IR) is an invasive speciality with the potential for complications as with other invasive specialities. The World Health Organization (WHO) produced a surgical safety checklist to decrease the morbidity and mortality associated with surgery. The Cardiovascular and

  16. Microstructure analysis of IrO2 thin films

    Science.gov (United States)

    Hou, Xiuyi; Takahashi, Ryota; Yamamoto, Takahisa; Lippmaa, Mikk

    2017-03-01

    We have grown IrO2 thin films on TiO2(110) substrates to determine the pulsed laser deposition growth window for iridates. Relaxed IrO2 films were obtained at a growth temperature of 500 °C and background oxygen pressure of 100 m Torr; otherwise, either pure Ir metal films or evaporative Ir loss were observed. Although x-ray Φ-scan measurement indicated that the films were epitaxial, a distinct grain structure was seen by atomic force microscopy and transmission electron microscopy. The grain boundaries were found to limit the conductivity of films at low temperature. It appeared that strain relaxation leads to stacking faults at grain boundaries.

  17. US-LHC IR magnet error analysis and compensation

    International Nuclear Information System (INIS)

    Wei, J.; Ptitsin, V.; Pilat, F.; Tepikian, S.; Gelfand, N.; Wan, W.; Holt, J.

    1998-01-01

    This paper studies the impact of the insertion-region (IR) magnet field errors on LHC collision performance. Compensation schemes including magnet orientation optimization, body-end compensation, tuning shims, and local nonlinear correction are shown to be highly effective

  18. Water equivalent phantom materials for 192 Ir brachytherapy

    OpenAIRE

    Schoenfeld, Andreas A.; Harder, Dietrich; Poppe, Björn; Chofor, Ndimofor

    2015-01-01

    Several solid phantom materials have been tested regarding their suitability as water substitutes for dosimetric measurements in brachytherapy with 192Ir as a typical high energy photon emitter. The radial variations of the spectral photon fluence, of the total, primary and scattered photon fluence and of the absorbed dose to water in the transversal plane of the tested cylindrical phantoms surrounding a centric and coaxially arranged Varian GammaMed afterloading 192Ir brach...

  19. Dynamic IR scene projector using the digital micromirror device

    Science.gov (United States)

    Gao, JiaoBo; Wang, Jun; Yang, Bin; Wang, JiLong; Wang, WeiNa; Xie, JunHu; Hu, Yu

    2005-01-01

    We have developed a new dynamic infrared scene projector using the Texas Instruments Digital Micromirror Device (DMD) which has been modified to project images which are suitable for testing sensor and seekers operating in the UV, visible, and IR wavebands. This paper provides an overview of the design and performance of the projection system, as well as example imagery from prototype projector systems. The dynamic IR scene contains 1024×768 pixels and can be updated at a rate of approximately 85 Hz.

  20. A study of the Al–Pt–Ir phase diagram

    Energy Technology Data Exchange (ETDEWEB)

    Grushko, B., E-mail: b.grushko@fz-juelich.de [MaTecK, 52428 Jülich (Germany); PGI-5, Forschungszentrum Jülich, 52425 Jülich (Germany); Samuha, S. [Dept. Materials Engineering, Ben-Gurion University of the Negev, 84105 Beer-Sheva (Israel); NRCN, P.O. Box 9001, 84190 Beer-Sheva (Israel); Meshi, L. [Dept. Materials Engineering, Ben-Gurion University of the Negev, 84105 Beer-Sheva (Israel)

    2015-10-15

    Phase equilibria in Al–Pt–Ir were studied up to 50 at.% Al at 1100 °C, up to 70 at.% Al at 900 °C and up to 75 at.% Al at 810 °C. At elevated temperatures the isostructural AlIr and high-temperature AlPt β-phases probably form a continuous compositional region. The ternary extensions of the phases Al{sub 4}Pt, Al{sub 21}Pt{sub 8}, Al{sub 3}Pt{sub 2} and low-temperature AlPt were revealed along approximately constant Al concentrations up to 15, 11, 20 and 10 at.% Ir, respectively. The Al–Ir C-phase dissolved up to 12 at.% Pt, and the χ-phase propagated up to almost Al{sub 3}Pt. A new ternary B-phase (I4{sub 1}/acd, a = 0.86250, c = 2.18409 nm) was revealed around Al{sub 69}Pt{sub 7}Ir{sub 24}. Its structural model was derived from the electron diffraction data. - Highlights: • The Al–Pt–Ir phase diagram was studied at 810, 900 and 1100 °C. • The majority of binaries extend widely along about constant Al. • The new ternary B-phase of the Ga{sub 4}Ir{sub 8}B type was revealed at Al{sub 69}Pt{sub 7}Ir{sub 24}. • The structural model of the B-phase was derived from electron diffraction.

  1. MERTIS - the design of a highly integrated IR imaging spectrometer

    OpenAIRE

    Walter, Ingo; Hirsch, Helmut; Knollenberg, Jörg; Jahn, Herbert; Säuberlich, Thomas; Venus, Holger; Skrbek, Wolfgang

    2006-01-01

    A belief that Mercury carries unique clues to the origin and evolution of the Solar System has driven the interest for detailed studies of the innermost planet. Here surface mineralogy requires information of the thermal inertia asking for observations by space borne instruments in the near IR and the thermal IR domain. With a background of several instrument developments in the past the German Aerospace Center in Berlin proposed for ESA’s deep space mission BepiColombo an imaging spectro...

  2. Thin Film Electrodeposition of Ir(III) Cyclometallated Complexes

    OpenAIRE

    Ionescu, Andreea; Aiello, Iolinda; Crispini, Alessandra; Godbert, Nicolas

    2016-01-01

    Novel electropolymerizable Ir(III) cyclometallated complexes have been synthesized and characterized. In these complexes the cyclometallated ligands are either 2-phenylpyridine H(PhPy) or benzothiazole-triphenylamine H(BzTh-tpa), while the Ir(III) coordination sphere is completed by a Schiff base substituted with a triphenylamine fragment. A complete electrochemical study has been conducted on all complexes, in order to verify the feasibility of electropolymerization and to elucidate the role...

  3. Fibre-Optic IR-Spectroscopy for Biomedical Diagnostics

    OpenAIRE

    Bindig, Uwe; Gersonde, Ingo; Meinke, Martina; Becker, Yukiyo; Müller, Gerhard

    2003-01-01

    The use of microscopy is a valuable means of gaining vital information for medical diagnostics. Due to a number of recent technological developments advances have been made in IR microscopy and in particular, rapid detection methods. Microscopic examination methods usually involve sampling followed by a method of sample purification or preparation. The advantages of the IR analytical method are that it is based on a direct, non‒destructive measurement of sample material and that the resulting...

  4. Reducing mitochondrial bound hexokinase II mediates transition from non-injurious into injurious ischemia/reperfusion of the intact heart

    NARCIS (Netherlands)

    R. Nederlof (Rianne); Gürel-Gurevin, E. (Ebru); O. Eerbeek (Otto); C. Xie (Chaoqin); Deijs, G.S.; Konkel, M. (Moritz); Hu, J. (Jun); N.C. Weber (Nina); C. Schumacher (Cees); A. Baartscheer (Antonius); E.G. Mik (Egbert); M.W. Hollmann (Markus); F.G. Akar (Fadi); C.J. Zuurbier (Coert J.)

    2016-01-01

    textabstractIschemia/reperfusion (I/R) of the heart becomes injurious when duration of the ischemic insult exceeds a certain threshold (approximately ≥20 min). Mitochondrial bound hexokinase II (mtHKII) protects against I/R injury, with the amount of mtHKII correlating with injury. Here, we examine

  5. UV and IR Photochemistries of Malonaldehyde Trapped in Cryogenic Matrices.

    Science.gov (United States)

    Trivella, A; Wassermann, T N; Manca Tanner, C; Lüttschwager, N O B; Coussan, S

    2018-03-08

    UV and IR photochemistries of malonaldehyde, the simplest molecule exhibiting an intramolecular proton exchange, have been studied in four cryogenic matrices at 4.3 K, N 2 , Ne, Ar, and Xe. Samples have been irradiated using a UV and IR OPO type tunable laser, and with a broad band UV mercury lamp. UV and IR spectra have been recorded and compared with theoretical calculations carried out at the SAC-CI/6-31++G(d,p) (UV transitions) and B3LYP/6-311++G(2d,2p) (IR spectra) levels of theory. After deposition, the intramolecularly H-bonded form is found exclusively, while several open forms are formed upon UV irradiation. These open forms show ability to interconvert upon UV irradiation too. Some of them are also able to isomerize upon selective IR irradiations. The whole set of results allowed us to identify seven isomers among the eight postulated. The photodynamics of the electronic relaxation of malonaldehyde have also been investigated. By following the decay or rise of suited specific vibrational bands in the IR spectra, and by comparing the results with an earlier study of the homologous acetylacetone, we deduced that the electronic relaxation of malonaldehyde proceeds through singlet states, most probably through a 3-fold conical intersection, as postulated from theoretical calculations. In contrast with acetylacetone, malonaldehyde does not show fragmentation after UV excitation.

  6. Serial removal of caries lesions from tooth occlusal surfaces using near-IR image-guided IR laser ablation

    Science.gov (United States)

    Chan, Kenneth H.; Tom, Henry; Darling, Cynthia L.; Fried, Daniel

    2015-02-01

    Previous studies have established that caries lesions can be imaged with high contrast without the interference of stains at near-IR wavelengths greater than 1300-nm. It has been demonstrated that computer controlled laser scanning systems utilizing IR lasers operating at high pulse repetition rates can be used for serial imaging and selective removal of caries lesions. In this study, we report our progress towards the development of algorithms for generating rasterized ablation maps from near-IR reflectance images for the removal of natural lesions from tooth occlusal surfaces. An InGaAs camera and a filtered tungsten-halogen lamp producing near-IR light in the range of 1500-1700-nm were used to collect crosspolarization reflectance images of tooth occlusal surfaces. A CO2 laser operating at a wavelength of 9.3- μm with a pulse duration of 10-15-μs was used for image-guided ablation.

  7. Synthesis and Spectral Investigations of Manganese(II, Cobalt(II, Nickel(II, Copper(II and Zinc(II Complexes of New Polydentate Ligands Containing a 1,8-Naphthyridine Moiety

    Directory of Open Access Journals (Sweden)

    Sunkari Jyothi

    2006-12-01

    Full Text Available 2-(o-Hydroxyphenyl-1,8-naphthyridine (HN, 2-(4-hydroxy-6-methylpyran-2-one-3-yl-1,8-naphthyridine (HMPN and 2-(benzimidazol-2-yl-1,8-naphthyridine(BN react with acetates of Mn(II, Co(II, Ni(II, Cu(II and Zn(II to yield metal ioncomplexes of definite composition. These compounds were characterized by elementalanalyses, molar conductivity, magnetic susceptibility measurements, thermal studies, IR,UV-visible, NMR and mass spectral investigations. The complexes are found to have theformulae [M(HN2(H2O2], [M(HMPN2(H2O2] and [M(BN2(OAc2], respectively.

  8. Cold, Gas-Phase UV and IR Spectroscopy of Protonated Leucine Enkephalin and its Analogues

    Science.gov (United States)

    Burke, Nicole L.; Redwine, James; Dean, Jacob C.; McLuckey, Scott A.; Zwier, Timothy S.

    2014-06-01

    The conformational preferences of peptide backbones and the resulting hydrogen bonding patterns provide critical biochemical information regarding the structure-function relationship of peptides and proteins. The spectroscopic study of cryogenically-cooled peptide ions in a mass spectrometer probes these H-bonding arrangements and provides information regarding the influence of a charge site. Leucine enkephalin, a biologically active endogenous opiod peptide, has been extensively studied as a model peptide in mass spectrometry. This talk will present a study of the UV and IR spectroscopy of protonated leucine enkephalin [YGGFL+H]+ and two of its analogues: the sodiated [YGGFL+Na]+ and C-terminally methyl esterified [YGGFL-OMe+H]+ forms. All experiments were performed in a recently completed multi-stage mass spectrometer outfitted with a cryocooled ion trap. Ions are generated via nano-electrospray ionization and the analyte of interest is isolated in a linear ion trap. The analyte ions are trapped in a 22-pole ion trap held at 5 K by a closed cycle helium cryostat and interrogated via UV and IR lasers. Photofragments are trapped and isolated in a second LIT and mass analyzed. Double-resonance UV and IR methods were used to assign the conformation of [YGGFL+H]+, using the NH/OH stretch, Amide I, and Amide II regions of the infrared spectrum. The assigned structure contains a single backbone conformation at vibrational/rotational temperatures of 10 K held together with multiple H-bonds that self-solvate the NH3+ site. A "proton wire" between the N and C termini reinforces the H-bonding activity of the COO-H group to the F-L peptide bond, whose cleavage results in formation of the b4 ion, which is a prevalent, low-energy fragmentation pathway for [YGGFL+H]+. The reinforced H-bonding network in conjunction with the mobile proton theory may help explain the prevalence of the b4 pathway. In order to elucidate structural changes caused by modifying this H-bonding activity

  9. Copper (II)

    African Journals Online (AJOL)

    CLEMENT O BEWAJI

    Bhardwaj C. N., and Singh V. R., (1994), Synthesis and characterization of thallium (I) complexes of biologically active benzothiazolines, Indian Journal Chemistry 33(3): 423 - 425. Chakraborty H., Paul N., and Rahman M. L., (1994), Catalytic activities of Schiff bases aquo complexes of Cu (II) in the hydrolysis of amino acid ...

  10. New infrared observations of IRS1, IRS3, and the adjacent nebula in the OMC-2 cluster

    Science.gov (United States)

    Pendleton, Y.; Werner, M.; Capps, R.; Dinerstein, H. L.

    1984-01-01

    Observations of the infrared cluster of low luminosity protostars in Orion Molecular Cloud 2 (OMC2) are reported. Results show that the asymmetric distribution of the extended emission seen about IRS1 is another infrared reflection nebula. Energy distributions show that the spectral shape is fairly constant throughout the nebula which indicates there is little internal extinction within this region. Integrated surface brightness values show that the nebula is 5 times brighter than IRS1 at K. Energy distributions show that IRS1 has a more pronounced ice band absorption feature at 3.1 micron; suggesting that there is more extinction along the direct line of sight to IRS1 than along a line from IRS1 to the scattering grains and then to the observer. The distribution of the extended emission around IRS1 is similar to the reflection nebula seen in NGC 7538 (Werner et al. 1979). The asymmetric shapes of the two nebulae are similar and in each case there is excess extinction along line of sight to the illuminating source.

  11. Myocardial loss of IRS1 and IRS2 causes heart failure and is controlled by p38α MAPK during insulin resistance.

    Science.gov (United States)

    Qi, Yajuan; Xu, Zihui; Zhu, Qinglei; Thomas, Candice; Kumar, Rajesh; Feng, Hao; Dostal, David E; White, Morris F; Baker, Kenneth M; Guo, Shaodong

    2013-11-01

    Cardiac failure is a major cause of death in patients with type 2 diabetes, but the molecular mechanism that links diabetes to heart failure remains unclear. Insulin resistance is a hallmark of type 2 diabetes, and insulin receptor substrates 1 and 2 (IRS1 and IRS2) are the major insulin-signaling components regulating cellular metabolism and survival. To determine the role of IRS1 and IRS2 in the heart and examine whether hyperinsulinemia causes myocardial insulin resistance and cellular dysfunction via IRS1 and IRS2, we generated heart-specific IRS1 and IRS2 gene double-knockout (H-DKO) mice and liver-specific IRS1 and IRS2 double-knockout (L-DKO) mice. H-DKO mice had reduced ventricular mass; developed cardiac apoptosis, fibrosis, and failure; and showed diminished Akt→forkhead box class O-1 signaling that was accompanied by impaired cardiac metabolic gene expression and reduced ATP content. L-DKO mice had decreased cardiac IRS1 and IRS2 proteins and exhibited features of heart failure, with impaired cardiac energy metabolism gene expression and activation of p38α mitogen-activated protein kinase (p38). Using neonatal rat ventricular cardiomyocytes, we further found that chronic insulin exposure reduced IRS1 and IRS2 proteins and prevented insulin action through activation of p38, revealing a fundamental mechanism of cardiac dysfunction during insulin resistance and type 2 diabetes.

  12. New hexadentate macrocyclic ligand and their copper(II) and nickel(II) complexes: Spectral, magnetic, electrochemical, thermal, molecular modeling and antimicrobial studies

    Science.gov (United States)

    Chandra, Sulekh; Ruchi; Qanungo, Kushal; Sharma, Saroj. K.

    Ni(II) and Cu(II) complexes were synthesized with a hexadentate macrocyclic ligand [3,4,8,9tetraoxo-2,5,7,10tetraaza-1,6dithio-(3,4,8,9) dipyridinedodecane(L)] and characterized by elemental analysis, molar conductance measurements, mass, NMR, IR, electronic, EPR spectral, thermal and molecular modeling studies. All the complexes are 1:2 electrolytes in nature and may be formulated as [M(L)]X2 [where, M = Ni(II) and Cu(II) and X = Cl-, NO3-, ½SO42-, CH3COO-]. On the basis of IR, electronic and EPR spectral studies an octahedral geometry has been assigned for Ni(II) complexes and tetragonal geometry for Cu(II) complexes. The antimicrobial activities and LD50 values of the ligand and its complexes, as growth inhibiting agents, have been screened in vitro against two different species of bacteria and plant pathogenic fungi.

  13. Coordination Modes of a Schiff Base Derived from Substituted 2-Aminothiazole with Chromium(III, Manganese(II, Iron(II, Cobalt(II, Nickel(II and Copper(II Metal Ions: Synthesis, Spectroscopic and Antimicrobial Studies

    Directory of Open Access Journals (Sweden)

    Ambit Thakar

    2011-01-01

    Full Text Available Transition metal complexes of Cr(III, Mn(II, Fe(II, Co(II, Ni(II and Cu(II metal ions with general stoichiometry [ML2.2H2O] and [ML3], where M= Mn(II, Cr(III, Fe(II, Co(II, Ni(II and Cu(II, L= Schiff base derived from the condensation of 2-amino-4(4’-phenyl/methylphenyl-5-methyl-thiazole with 4-acetyl-1(3-chloro phenyl-3-methyl-2-pyrazoline-5-ones, have been synthesized and structurally characterized by elemental analysis, molar conductance measurements, magnetic susceptibility measurements and spectral techniques like IR, UV, 1H NMR, 13C NMR and Mass Spectra. All the complexes were found to be octahedral geometry. The ligand and its complexes have been screened for their antifungal and antibacterial activities against three fungi, i.e. Alternaria brassicae, Aspergillus niger and Fesarium oxysporum and two bacteria, i.e. Xanthomonas compestris and Pseudomonas aeruginosa.

  14. Tuning brightness and oxygen sensitivity of Ru(II) and Ir(III) luminophores

    NARCIS (Netherlands)

    Ruggi, A.

    2011-01-01

    The design of luminophores with high brightness is of crucial importance for many applications like the realization of Organic Light Emitting Diodes (OLEDs), and for biomedical imaging. However, despite the great number of works dedicated to the definition of the possible strategies for the

  15. Observations of the Ca ${\\rm\\tiny II} $ IR Triplet in High Luminosity ...

    Indian Academy of Sciences (India)

    Abstract. We present a new spectroscopic sample of 11 quasars at intermediate redshift observed with the Infrared Spectrometer and Array Camera (ISAAC) on the ESO Very Large Telescope (VLT), covering O I 8446 and the Ca I I triplet 8498, 8542, 8662. The new observations – that supplement the sample presented by ...

  16. A quantitative analysis of the ν ??? (IR) bands of H-bonds. II. Adipic acid crystals

    Science.gov (United States)

    Marechal, Y.

    1983-08-01

    The theory described in the preceding article is applied to the ν ??? bands (X-H¯???Y) of adipic (H and D) acid monocrystals. The lineshape g(ω) that ν ??? is supposed to exhibit in the absence of Fermi resonances is computed at temperatures ranging from 10 to 300 K. This lineshape has at least two components in the case of H-adipic acid which we preferentially attribute to the ν ???-ν ??? interaction (= 100 cm -1) between the two H-bonds of the cyclic dimers (RCOOH) 2. We cannot however exclude that these two components are due to a tunnelling of the protons through the H-bonds of these dinners. The precise determination of the second centered moments (or width) of g(ω) at various temperatures gives results which are consistent with the value of the first moment and can be simply accounted for with the assumption that the modulation of ν ??? by low-frequency modes is quadratic. The question as to whether this low-frequency mode is a stretching mode or a bending mode in an isolated H-bond remains unanswered.

  17. Detectors with Improved Near-to-Mid IR Performance and Reduced Cooling Requirements, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — This program will develop an ultra-high performance infrared detector manufacturing technology with improved performance and cost effectiveness, and reduced cooling...

  18. IR AND UV-VISIBLE SPECTRA OF IRON(II) PHTHALOCYANINE ...

    African Journals Online (AJOL)

    We have prepared and studied by vibrational and electronic spectrometry of a series of ferrophthalocyanine complexes with phosphine or phosphite axial ligands [PMe3, P(OMe)3, PPh3, P(OPh)3, PPh(OMe)3 and POH(OEt)2]. With PMe3, P(OMe)3 as ligands, only hexacoordinated complexes are obtained but with PPh3, ...

  19. Cu(II), Zn(II)

    African Journals Online (AJOL)

    stereochemistry has been suggested to Zn(II), Cd(II) and Hg(II) complexes. The thermal analysis data provided the kinetic parameters as order of decomposition reaction, activation energy and frequency factor. All theoretical calculations of the ligand and the Cu(II) and Zn(II) complexes were made using Gaussian 03 rev.

  20. PENDIDIKAN AKHLAK MUSLIMAT MELALUISYA’IR : ANALISIS GENDER ATAS AJARAN SYI’IR MUSLIMAT KARYA NYAI WANIFAH KUDUS

    Directory of Open Access Journals (Sweden)

    Nur Said

    2016-03-01

    Full Text Available Penelitian ini difokuskan pada tiga hal: (1 Apakah karakteristik lingkup isi Syi’ir Muslimat?, (2 Bagai-manakah kondisi sosial budaya pada saat naskah ditulis oleh penulis?, (3 Apa nilai-nilai pendidikan moral bagi perempuan Muslim di isi Syi’ir Muslimat dalam perspektif gender?. Penelitian ini menggunakan pendekatan filologi dengan meningkatkan penggunaan analisis gender. Hasil dari penelitian ini adalah: Pertama, Syi’ir Muslimat ditulis oleh Nyai Wanifah, seorang wanita yang hidup pada zaman kolonial Belanda dipesantren tradisi di Kudus, Jawa Tengah. Kedua, beberapa nilai pendidikan moral di Syi’ir Muslimatantara lain: (1 Pentingnya pendidikan moral, (2 Bahaya perempuan bodoh; (3 Pentingnya belajar bagi perempuan di usia dini, (4 Etika menghias diri; (5 Bahaya materialisme, (6 Etika hubungan keluarga; (7 Dari rumah untuk mencapai surga; (8 Berhati-hatilah dengan tipu iblis; (9 Hindari perzinahan; (10 yang penting dari penutupan aurot; (11 yang ditujukan kepada orang tua. Ketiga, meskipun ada beberapa senyawa yang bias gender dalam Syi’ir Muslimat misalnya: (a Ada penjelasan yang menunjukkan bahwa perempuan lebih rendah dibandingkan laki-laki dalam derajat, (2 Pernyataan bahwa wanita bicara dibandingkan laki-laki, (3 wanita hanya cocok di wilayah domestik; Namun secara umum nasihat di syi’ir masih sangat relafen dalam konteks sekarang, terutama untuk memberikan solusi alternatif dalam merespon krisis moral bangsa terutama pada wanita generasi muda. Kata kunci: Syi’ir Muslimat, Pendidikan Karakter, Analisis Gender. This study focused on three things: (1 What is the characteristics of the scope of contents of Syi’ir Muslimat?, (2 What is the socio-cultural conditions at the time the manuscript was written by the author?, (3 What are the moral education values for Muslim women in the content of Syi’ir Muslimat in the perspective of gender?. This research uses a philological approach with enhanced use of gender analysis. The

  1. [HOMA-IR in patients with chronic hepatitis C].

    Science.gov (United States)

    Botshorishvili, T; Vashakidze, E

    2012-02-01

    The aim of investigation was to study the frequency of IR in type of viral hepatitis C, correlation with the degree of hepatic lesion and liver cirrhosis. 130 patients were investigated: 20 with acute hepatitis C; 38 with chronic hepatitis C; 72 with cirrhosis: among them 10 with Stage A, 14 with Stage B and 48 with Stage C. Also we used 30 healthy people as the controls. The study demonstrates significant changes of insulin, glucose, HOMA-IR type of viral hepatitis C, correlation with the degree of hepatic lesion and liver cirrhosis. In patients with liver cirrhosis levels of HOMA-IR is higher than in patients with chronic hepatitis C. In patients with acute hepatitis C levels of HOMA-IR was normal as in the control group. The results showed that various types of chronic viral hepatitis C and stages of cirrhosis set to increase HOMA-IR versus the controls., which were the most prominent in cases of severe hepatic lesion, which indicates that insulin resistance is a frequent companion of CHC.

  2. Ecological and agricultural applications of synchrotron IR microscopy

    Science.gov (United States)

    Raab, T. K.; Vogel, J. P.

    2004-10-01

    The diffraction-limited spot size of synchrotron-based IR microscopes provides cell-specific, spectrochemical imaging of cleared leaf, stem and root tissues of the model genetic organism Arabidopsis thaliana, and mutant plants created either by T-DNA insertional inactivation or chemical mutagenesis. Spectra in the wavelength region from 6 to 12 μm provide chemical and physical information on the cell wall polysaccharides of mutants lacking particular biosynthetic enzymes ("Cellulose synthase-like" genes). In parallel experiments, synchrotron IR microscopy delineates the role of Arabidopsis cell wall enzymes as susceptibility factors to the fungus Erysiphe cichoracearum, a causative agent of powdery mildew disease. Three genes, pmr4, pmr5, and pmr6 have been characterized by these methods, and biochemical relations between two of the genes suggested by IR spectroscopy and multivariate statistical techniques could not have been inferred through classical molecular biology. In ecological experiments, live plants can also be imaged in small microcosms with mid-IR transmitting ZnSe windows. Small exudate molecules may be spatially mapped in relation to root architecture at diffraction-limited resolution, and the effect of microbial symbioses on the quantity and quality of exudates inferred. Synchrotron IR microscopy provides a useful adjunct to molecular biological methods and underground observatories in the ongoing assessment of the role of root-soil-microbe communication.

  3. Crystal structure of the Al2CuIr phase

    International Nuclear Information System (INIS)

    Meshi, L.; Ezersky, V.; Kapush, D.; Grushko, B.

    2010-01-01

    A new ternary Al 2 CuIr phase was revealed in the Al-Cu-Ir system. It is formed below 1063 o C from the β-phase (CsCl-type structure) extending at elevated temperatures from AlIr. The crystal structure of the Al 2 CuIr phase was determined using a combination of precession electron diffraction and X-ray powder diffraction techniques. The phase has an orthorhombic C-centered unit cell with lattice parameters a = 8.1196(7) A, b = 5.0646(2) A and c = 5.18513(3) A; its crystal symmetry can be described by the Cmme (no. 67) space group (Pearson symbol oC16). The unit cell of the new phase contains 8 Al, 4 Cu and 4 Ir atoms and exhibits a new structure type. The reliability factors characterizing the Rietveld refinement procedure are: R p = 4.45%, R wp = 6.45%, R B = 3.69% and R f = 2.41%.

  4. Short infrared (IR) laser pulses can induce nanoporation

    Science.gov (United States)

    Roth, Caleb C.; Barnes, Ronald A.; Ibey, Bennett L.; Glickman, Randolph D.; Beier, Hope T.

    2016-03-01

    Short infrared (IR) laser pulses on the order of hundreds of microseconds to single milliseconds with typical wavelengths of 1800-2100 nm, have shown the capability to reversibly stimulate action potentials (AP) in neuronal cells. While the IR stimulation technique has proven successful for several applications, the exact mechanism(s) underlying the AP generation has remained elusive. To better understand how IR pulses cause AP stimulation, we determined the threshold for the formation of nanopores in the plasma membrane. Using a surrogate calcium ion, thallium, which is roughly the same shape and charge, but lacks the biological functionality of calcium, we recorded the flow of thallium ions into an exposed cell in the presence of a battery of channel antagonists. The entry of thallium into the cell indicated that the ions entered via nanopores. The data presented here demonstrate a basic understanding of the fundamental effects of IR stimulation and speculates that nanopores, formed in response to the IR exposure, play an upstream role in the generation of AP.

  5. IR emission and UV extinction in two open clusters

    International Nuclear Information System (INIS)

    Hackwell, J.A.; Hecht, J.H.

    1989-01-01

    Recent models of interstellar extinction have shown the importance of understanding both the UV and IR properties of interstellar dust grains. IRAS data have shown variations in 60 and 100 micron emissions presumably due to the presence of IR cirrus, while recent observations in the UV by Fitzpatrick and Massa have identified components in the UV extinction curve which vary in different star regions. A Draine and Anderson model connects these results by proposing that different size variations in interstellar grains would cause distinct changes in both the IR emission and the UV extinction. In order to test this model it is necessary to make observations in well defined locations away from peculiar extinction regions. In the infrared this means looking away from the galactic plane so as to limit non-local sources of IR radiation. Two open clusters that are out of the galactic plane and which contain a number of late B and early A stars suitable for UV extinction studies, and whose IRAS data show variations in the 60/100 micron ratio were studied. Based on the Drain and Anderson model, variations were expected in their UV extinction curves that correlate with the IR cirrus emission

  6. IR FPA sensor characterization and analysis using Matlab tm

    Science.gov (United States)

    Burke, Michael J.; Wan, William H.

    1998-08-01

    This paper documents the Matlab routines used to conduct infrared focal plane array (IR-FPA) sensor data analysis. Matlab is a commercially available software package that enables users to conduct a multitude of data analysis, file I/O, and generation of graphics with little or no computer programming skills. This effort was conducted in support of the US Army Tank-automotive and Armaments Command-Armament Research, Development and Engineering Center's (TACOM-ARDEC) 120 mm Precision Guided Mortar Munition (PGMM). PGMM's sensor included a 256 X 256 mid-band IR-FPA. This paper summarizes a primer generated to help train PGMM sensor engineers to use Matlab for conducting IR-FPA image analysis. A brief system description of the PGMM IR sensor will be presented, and follow by discussion on the Matlab IR-FPA image analysis, such as measurement of; FPA operability, Noise Equivalent Temperature Difference, temporal noise, spatial noise, as well as gain and offset calibration for non-uniformity correction.

  7. IR spectral analysis for the diagnostics of crust earthquake precursors

    Directory of Open Access Journals (Sweden)

    R. M. Umarkhodgaev

    2012-11-01

    Full Text Available Some possible physical processes are analysed that cause, under the condition of additional ionisation in a pre-breakdown electric field, emissions in the infrared (IR interval. The atmospheric transparency region of the IR spectrum at wavelengths of 7–15 μm is taken into account. This transparency region corresponds to spectral lines of small atmospheric constituents like CH4, CO2, N2O, NO2, NO, and O3. The possible intensities of the IR emissions observable in laboratories and in nature are estimated. The acceleration process of the electrons in the pre-breakdown electrical field before its adhesion to the molecules is analyzed. For daytime conditions, modifications of the adsorption spectra of the scattered solar emissions are studied; for nighttime, variations of emission spectra may be used for the analysis.

  8. Third-generation intelligent IR focal plane arrays

    Science.gov (United States)

    Caulfield, H. John; Jack, Michael D.; Pettijohn, Kevin L.; Schlesselmann, John D.; Norworth, Joe

    1998-03-01

    SBRC is at the forefront of industry in developing IR focal plane arrays including multi-spectral technology and '3rd generation' functions that mimic the human eye. 3rd generation devices conduct advanced processing on or near the FPA that serve to reduce bandwidth while performing needed functions such as automatic target recognition, uniformity correction and dynamic range enhancement. These devices represent a solution for processing the exorbitantly high bandwidth coming off large area FPAs without sacrificing systems sensitivity. SBRC's two-color approach leverages the company's HgCdTe technology to provide simultaneous multiband coverage, from short through long wave IR, with near theoretical performance. IR systems that are sensitive to different spectral bands achieve enhanced capabilities for target identification and advanced discrimination. This paper will provide a summary of the issues, the technology and the benefits of SBRC's third generation smart and two-color FPAs.

  9. Causality, Analyticity and an IR Obstruction to UV Completion

    CERN Document Server

    Adams, A; Dubovsky, S; Nicolis, A; Rattazzi, R; Adams, Allan; Arkani-Hamed, Nima; Dubovsky, Sergei; Nicolis, Alberto; Rattazzi, Riccardo

    2006-01-01

    We argue that certain apparently consistent low-energy effective field theories described by local, Lorentz-invariant Lagrangians, secretly exhibit macroscopic non-locality and cannot be embedded in any UV theory whose S-matrix satisfies canonical analyticity constraints. The obstruction involves the signs of a set of leading irrelevant operators, which must be strictly positive to ensure UV analyticity. An IR manifestation of this restriction is that the "wrong" signs lead to superluminal fluctuations around non-trivial backgrounds, making it impossible to define local, causal evolution, and implying a surprising IR breakdown of the effective theory. Such effective theories can not arise in quantum field theories or weakly coupled string theories, whose S-matrices satisfy the usual analyticity properties. This conclusion applies to the DGP brane-world model modifying gravity in the IR, giving a simple explanation for the difficulty of embedding this model into controlled stringy backgrounds, and to models of...

  10. IR spectroscopy of gaseous fluorocarbon ions: The perfluoroethyl anion

    Energy Technology Data Exchange (ETDEWEB)

    Crestoni, Maria Elisa; Chiavarino, Barbara [Dipartimento di Chimica e Tecnologie del Farmaco, Universita di Roma ' La Sapienza' , P. le A. Moro 5, I-00185 Roma (Italy); Lemaire, Joel; Maitre, Philippe [Universite Paris Sud, Laboratoire de Chimie Physique - UMR8000 CNRS, Faculte des Sciences - Batiment 350, 91405 Orsay Cedex (France); Fornarini, Simonetta, E-mail: simonetta.fornarini@uniroma1.it [Dipartimento di Chimica e Tecnologie del Farmaco, Universita di Roma ' La Sapienza' , P. le A. Moro 5, I-00185 Roma (Italy)

    2012-04-04

    Highlights: Black-Right-Pointing-Pointer C{sub 2}F{sub 5}{sup -} ions are formed by dissociative electron capture in perfluoropropane. Black-Right-Pointing-Pointer Both their reactivity towards neutrals and IRMPD spectroscopy are investigated. Black-Right-Pointing-Pointer The sampled C{sub 2}F{sub 5}{sup -} ions are best described as covalently bound pentafluoroethyl anions. - Abstract: The first IR spectrum of a perfluorinated carbanion has been obtained in the gas phase by IRMPD spectroscopy. Quantum chemical calculations at the MP2/cc-pVTZ level were performed yielding the optimized geometries and IR spectra for a covalently bound C{sub 2}F{sub 5}{sup -} species and for conceivable loosely bound F{sup -}(C{sub 2}F{sub 4}) complexes. Both the computational results and the IR characterization point to a covalent structure for the assayed species in agreement with the reactivity pattern displayed with selected neutrals.

  11. Jamming effectiveness analysis of IR smoke projectile based on sight optical observation

    Science.gov (United States)

    Wang, Longtao; Liu, Zhenxing; Wang, Falong

    2013-09-01

    This text makes use of the similar of the principle between IR imaging guided missile detection system and the general sight optics probe. In this text, the synopsis analysis on the jamming effectiveness of the IR smoke projectile resist the IR imaging guided missile is discussed. This research of the jamming technique to IR imaging guided missile have a very realistic meaning.

  12. Co(II), Ni(II) and Zn(II)

    Indian Academy of Sciences (India)

    Unknown

    161. Synthesis, characterisation and electrochemical behaviour of. Cu(II), Co(II), Ni(II) and Zn(II) complexes derived from acetylacetone and p-anisidine and their antimicrobial activity. N RAMAN*, V MUTHURAJ, S RAVICHANDRAN and. A KULANDAISAMY. Department of Chemistry, VHNSN College, Virudhunagar 626 001 ...

  13. Using Near-IR Imaging to Probe Accretion-Disk Physics in Powerful Radio Sources

    Science.gov (United States)

    Koekemoer, Anton; O'Dea, Chris; Baum, Stefi

    1999-08-01

    An intriguing question in the study of powerful radio galaxies concerns the reason for their wide diversity of properties: is this related predominantly to external environmental effects, or to intrinsic differences in their central engines and accretion processes? We propose to address this question by using the 2.1m + ONIS to obtain J, H and K imaging of two samples of FR I and FR II radio galaxies, to measure the luminosity and colors of warm circumnuclear dust and determine the near- IR structure and environment of the surrounding host galaxies. The dust absorbs radiation from the AGN and re-radiates it in the near-IR, which can thus be used as a diagnostic of the AGN radiant energy output. This will be compared with the AGN kinetic energy output in the form of radio jets. Our two samples are statistically well-matched in both radio power and redshift space, allowing us to carry out statistical comparisons between AGN properties such as the radiant / kinetic energy conversion, as well as large-scale host galaxy properties. This will indicate whether differences between these classes of active galaxies are related primarily to the central engine, or instead dominated by the large-scale properties of the host galaxy and its environment.

  14. Interaction of zincate with additives turbidimetric, IR and Raman spectral analyses

    Science.gov (United States)

    Renuka, R.; Ramamurthy, S.; Srinivasan, L.

    The interaction of zincate with additives, viz., alkaline earth oxides, cadmium oxide, nickel hydroxide, cobalt hydroxide bismuth oxide, sodium carbonate, and lithium hydroxide is investigated by turbidimetry and Raman spectroscopy. From the pattern of dependence of turbidity on additive concentration, the additives can be classified into three groups: (i) BeO, CdO, MgO, Ni(OH) 2, Co(OH) 2; (ii) CaO, BaO, SrO; (iii) LiOH, Bi 2O 3, Na 2CO 3. An identical grouping of additives has been discerned from Raman spectral analysis. Turbidimetry is a simple inexpensive technique for understanding the processes taking place between the additives and the zincate solution. Products of electrochemical dissolution of zinc in 4 M NaOH containing alkaline earth oxides, SnO, CdO, Ni(OH) 2, CO(OH) 2, or LiOH have been analysed by IR spectroscopy. The effect of heat treatment of the products on IR spectral pattern is described in the light of thermogravimetric analysis.

  15. Interaction of zincate with additives turbidimetric, IR and Raman spectral analyses

    Energy Technology Data Exchange (ETDEWEB)

    Renuka, R.; Ramamurthy, S.; Srinivasan, L. [Central Electrochemical Research Inst., Chennai (India). Madras Unit

    2000-07-01

    The interaction of zincate with additives, viz., alkaline earth oxides, cadmium oxide, nickel hydroxide, cobalt hydroxide bismuth oxide, sodium carbonate, and lithium hydroxide is investigated by turbidimetry and Raman spectroscopy. From the pattern of dependence of turbidity on additive concentration, the additives can be classified into three groups: (i) BeO, CdO, MgO, Ni(OH){sub 2}, Co(OH){sub 2}; (ii) CaO, BaO, SrO; (iii) LiOH, Bi{sub 2}O{sub 3}, Na{sub 2}CO{sub 3}. An identical grouping of additives has been discerned from Raman spectral analysis. Turbidimetry is a simple inexpensive technique for understanding the processes taking place between the additives and the zincate solution. Products of electrochemcial dissolution of zinc in 4 M NaOH containing alkaline earth oxides, SnO, CdO, Ni(OH){sub 2}, Co(OH){sub 2}, or LiOH have been analysed by IR spectroscopy. The effect of heat treatment of the products on IR spectral pattern is described in the light of thermogravimetric analysis. (orig.)

  16. Near-IR Spectroscopy of Luminous LoBAL Quasars at 1 < z < 2.5

    Science.gov (United States)

    Schulze, Andreas; Schramm, Malte; Zuo, Wenwen; Wu, Xue-Bing; Urrutia, Tanya; Kotilainen, Jari; Reynolds, Thomas; Terao, Koki; Nagao, Tohru; Izumiura, Hideyuki

    2017-10-01

    We present near-IR spectroscopy of 22 luminous low-ionization broad absorption line quasars (LoBAL QSOs) at redshift 1.3BAL quasar sample. We do not find any statistically significant difference between LoBAL QSOs and non-BAL QSOs in their black hole mass or Eddington ratio distributions. The mean UV to mid-IR SED of the LoBAL QSOs is consistent with non-BAL QSOs, apart from their stronger reddening. At z> 1 there is no clear difference in their optical emission line properties. We do not see particularly weak [O III] or strong Fe II emission. The LoBAL QSOs do not show a stronger prevalence of ionized gas outflows as traced by the [O III] line, compared to normal QSOs of similar luminosity. We conclude that the optical-MIR properties of LoBAL QSOs are consistent with the general quasar population and do not support them to constitute a special phase of active galactic nucleus evolution.

  17. Rapid discrimination of extracts of Chinese propolis and poplar buds by FT-IR and 2D IR correlation spectroscopy

    Science.gov (United States)

    Wu, Yan-Wen; Sun, Su-Qin; Zhao, Jing; Li, Yi; Zhou, Qun

    2008-07-01

    The extract of Chinese propolis (ECP) has recently been adulterated with that of poplar buds (EPB), because most of ECP is derived from the poplar plant, and ECP and EPB have almost identical chemical compositions. It is very difficult to differentiate them by using the chromatographic methods such as high performance liquid chromatography (HPLC) and gas chromatography (GC). Therefore, how to effectively discriminate these two mixtures is a problem to be solved urgently. In this paper, a rapid method for discriminating ECP and EPB was established by the Fourier transform infrared (FT-IR) spectra combined with the two-dimensional infrared correlation (2D IR) analysis. Forty-three ECP and five EPB samples collected from different areas of China were analyzed by the FT-IR spectroscopy. All the ECP and EPB samples tested show similar IR spectral profiles. The significant differences between ECP and EPB appear in the region of 3000-2800 cm -1 of the spectra. Based on such differences, the two species were successfully classified with the soft independent modeling of class analogy (SIMCA) pattern recognition technique. Furthermore, these differences were well validated by a series of temperature-dependent dynamic FT-IR spectra and the corresponding 2D IR plots. The results indicate that the differences in these two natural products are caused by the amounts of long-chain alkyl compounds (including long-chain alkanes, long-chain alkyl esters and long chain alkyl alcohols) in them, rather than the flavonoid compounds, generally recognized as the bioactive substances of propolis. There are much more long-chain alkyl compounds in ECP than those in EPB, and the carbon atoms of the compounds in ECP remain in an order Z-shaped array, but those in EPB are disorder. It suggests that FT-IR and 2D IR spectroscopy can provide a valuable method for the rapid differentiation of similar natural products, ECP and EPB. The IR spectra could directly reflect the integrated chemical

  18. RADIO MONITORING OF THE PERIODICALLY VARIABLE IR SOURCE LRLL 54361: NO DIRECT CORRELATION BETWEEN THE RADIO AND IR EMISSIONS

    Energy Technology Data Exchange (ETDEWEB)

    Forbrich, Jan, E-mail: jan.forbrich@univie.ac.at [University of Vienna, Department of Astrophysics, Türkenschanzstraße 17, A-1180 Vienna (Austria); Rodríguez, Luis F.; Palau, Aina; Zapata, Luis A. [Instituto de Radioastronomía y Astrofísica, UNAM, Apdo. Postal 3-72 (Xangari), 58089 Morelia, Michoacán (Mexico); Muzerolle, James [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Gutermuth, Robert A. [Department of Astronomy, University of Massachusetts, Amherst, MA 01003 (United States)

    2015-11-20

    LRLL 54361 is an infrared source located in the star-forming region IC 348 SW. Remarkably, its infrared luminosity increases by a factor of 10 over roughly one week every 25.34 days. To understand the origin of these remarkable periodic variations, we obtained sensitive 3.3 cm JVLA radio continuum observations of LRLL 54361 and its surroundings in six different epochs: three of them during the IR-on state and three during the IR-off state. The radio source associated with LRLL 54361 remained steady and did not show a correlation with the IR variations. We suggest that the IR is tracing the results of fast (with a timescale of days) pulsed accretion from an unseen binary companion, while the radio traces an ionized outflow with an extent of ∼100 AU that smooths out the variability over a period of the order of a year. The average flux density measured in these 2014 observations, 27 ± 5 μJy, is about a factor of two less than that measured about 1.5 years before, 53 ± 11 μJy, suggesting that variability in the radio is present, but over larger timescales than in the IR. We discuss other sources in the field, in particular two infrared/X-ray stars that show rapidly varying gyrosynchrotron emission.

  19. Low Dose IR Creates an Oncogenic Microenvironment by Inducing Premature

    Energy Technology Data Exchange (ETDEWEB)

    Yuan, Zhi-Min [Harvard School of Public Health

    2013-04-28

    Introduction Much of the work addressing ionizing radiation-induced cellular response has been carried out mainly with the traditional cell culture technique involving only one cell type, how cellular response to IR is influenced by the tissue microenvironment remains elusive. By use of a three-dimensional (3D) co-culture system to model critical interactions of different cell types with their neighbors and with their environment, we recently showed that low-dose IR-induced extracellular signaling via the tissue environment affects profoundly cellular responses. This proposal aims at determining the response of mammary epithelial cells in a tissue-like setting.

  20. Feminism and IR and the Conditions for Critical Dialogue

    OpenAIRE

    Nicholls, Esteban

    2016-01-01

    My objective in this paper is to problematize the call for dialogue and engagement between feminists and non-feminist International Relations (IR) scholars. I will concentrate on two pieces of scholarship to discuss the issue of dialogue: first, Robert Keohane’s “Beyond Dychotomies: Conversations between International Relations and Feminist Theory’s” (Keohane, 1998); and second, Anne Tickner’s (1997) “You Just don’t Understand: Troubled Engagements between Feminists and IR Theorists.” In both...

  1. Thomas L.Friedman, „Lexus ir alyvmedis“, recenzija

    OpenAIRE

    Karpavičiūtė, Ieva

    2006-01-01

    Vienas dažniausiai cituojamų globalizacijos optimistų, hiperglobalistų - New York Times užsienio reikalų skilties apžvalgininkas Thomas L. Friedman, stengiasi savitai pažvelgti į globalizacijos procesus, išskirti pagrindines tendencijas, pažvelgti į jų teigiamas bei neigiamas pasekmes. T.L. Friedman dar 1999 metais išleistoje knygoje “Lexus ir alyvmedis” analizuoja globalėjimą, teigia technologinį determinizmą ir akcentuoja JAV vaidmens globalizacijos procesuose unikalumą bei svarbą. Knyga „L...

  2. High field Moessbauer study of dilute Ir-(Fe) alloys

    International Nuclear Information System (INIS)

    Takabatake, Toshiro; Mazaki, Hiromasa; Shinjo, Teruya.

    1981-01-01

    The magnetic behavior of very dilute Fe impurities in Ir has been studied by means of Moessbauer measurement in external fields up to 80 kOe at 4.2 K. The saturation hyperfine field increases in proportion to the external field up to the maximum magnetic field available. This means that for a localized spin fluctuation system IrFe, the effective magnetic moment associated with Fe impurities is induced in proportion to the external field. No anomalous spectrum was observed with a very dilute sample (--10 ppm 57 Co), indicating that the interaction between impurities is responsible for the anomalous spectrum previously observed with a less homogeneous sample. (author)

  3. Cost effective method of manual afterloading 192Ir brachytherapy

    International Nuclear Information System (INIS)

    Mohan, R.; Ravishankar, B.; Muralkrishna, B.V.

    2001-01-01

    Full text: In radiotherapy, brachytherapy mode of treatment has equal importance like the external beam radiotherapy. In our hospital we have manual afterloading 137 Cs kit supplied by BRIT for intracavitary treatment of carcinoma cervix and vaginal cases. In July 1999, we also started afterloading 192 Ir brachytherapy. For a hospital like ours, where funds are minimal, it is impossible to procure remote afterloading brachytherapy unit, which is very costly. So we have developed the cost-effective 192 Ir manual brachytherapy and so far we have done 60 cases which include intraluminal and interstitial cases

  4. Measurements of electric quadrupole moments of neutron-deficient Au, Pt, and Ir nuclei with NMR-ON in hcp-Co

    CERN Multimedia

    Smolic, E; Hagn, E; Zech, E; Seewald, G

    2002-01-01

    The aim of the experiments is the measurement of $\\,$i) nuclear magnetic moments and electric quadrupole moments of neutron-deficient isotopes in the region Os-Ir-Pt-Au with the methods of quadrupole-interaction-resolved NMR on oriented nuclei " QI-NMR-ON " and modulated adiabatic passage on oriented nuclei " MAPON " and $\\,$ii) the magnetic hyperfine field, electric field gradient (EFG), and spin-lattice relaxation of 5d elements in ferromagnetic Fe, Ni, fcc-Co and hcp-Co.\\\\ The measurements on Au isotopes have been finished successfully. The quadrupole moments of $^{186}$Au, $^{193m}$Au, $^{195}$Au, $^{195m}$Au, $^{197m}$Au, $^{198}$Au and $^{199}$Au were determined with high precision.\\\\ For neutron-deficient Ir isotopes QI-NMR-ON measurements were performed after implantation of Hg precursors. The EFG of Ir in hcp-Co has been calibrated. Thus precise values for the spectroscopic quadrupole mo...

  5. Ophthalmologic Baseline Characteristics and 2-Year Ophthalmologic Safety Profile of Pramipexole IR Compared with Ropinirole IR in Patients with Early Parkinson’s Disease

    Directory of Open Access Journals (Sweden)

    William Seiple

    2016-01-01

    Full Text Available Background. Parkinson’s disease (PD progressively affects dopaminergic neurotransmission and may affect retinal dopaminergic functions and structures. Objective. This 2-year randomized, open-label, parallel-group, flexible-dose study, NCT00144300, evaluated ophthalmologic safety profiles of immediate-release (IR pramipexole and ropinirole in patients with early idiopathic PD with ≤6 months’ prior dopamine agonist exposure and without preexisting major eye disorders. Methods. Patients received labeled IR regimens of pramipexole (n=121 or ropinirole (n=125 for 2 years. Comprehensive ophthalmologic assessments (COA included corrected acuity, Roth 28-color test, slit-lamp biomicroscopy, intraocular pressure, computerized visual field test, fundus photography, and electroretinography. Results. At baseline, we observed retinal pigmentary epithelium (RPE hypopigmentation not previously reported in PD patients. The estimated relative risk of 2-year COA worsening with pramipexole versus ropinirole was 1.07 (95% CI: 0.71–1.60. Mean changes from baseline in Unified Parkinson’s Disease Rating System parts II+III total scores (pramipexole: 1 year, −4.1±8.9, and 2 years, −0.7±10.1, and ropinirole: 1 year, −3.7±8.2, and 2 years, −1.7±10.5 and Hoehn–Yahr stage distribution showed therapeutic effects on PD symptoms. Safety profiles were consistent with labeling. Conclusions. The risk of retinal deterioration did not differ in early idiopathic PD patients receiving pramipexole versus ropinirole. RPE hypopigmentation at baseline was not previously reported in this population. This trial is registered with NCT00144300.

  6. Coordination behavior of tetraaza [N4] ligand towards Co(II), Ni(II), Cu(II), Cu(I) and Pd(II) complexes: Synthesis, spectroscopic characterization and anticancer activity

    Science.gov (United States)

    El-Boraey, Hanaa A.

    2012-11-01

    Novel eight Co(II), Ni(II), Cu(II), Cu(I) and Pd(II) complexes with [N4] ligand (L) i.e. 2-amino-N-{2-[(2-aminobenzoyl)amino]ethyl}benzamide have been synthesized and structurally characterized by elemental analysis, spectral, thermal (TG/DTG), magnetic, and molar conductivity measurements. On the basis of IR, mass, electronic and EPR spectral studies an octahedral geometry has been proposed for Co(II), Ni(II) complexes and Cu(II) chloride complex, square-pyramidal for Cu(I) bromide complex. For Cu(II) nitrate complex (6), Pd(II) complex (8) square planar geometry was proposed. The EPR data of Cu(II) complexes in powdered form indicate dx2-y2 ground state of Cu(II) ion. The antitumor activity of the synthesized ligand and some selected metal complexes has been studied. The palladium(II) complex (8) was found to display cytotoxicity (IC50 = 25.6 and 41 μM) against human breast cancer cell line MCF-7 and human hepatocarcinoma HEPG2 cell line.

  7. Transition metal M(II complexes with isonicotinoylhydrazone-9-anthraldehyde

    Directory of Open Access Journals (Sweden)

    Dianu M.L.

    2010-01-01

    Full Text Available New complexes of isonicotinoylhydrazone-9-anthraldehyde with Cu(II, Co(II and Ni(II have been prepared and characterized by analytical and physico-chemical techniques, such as elemental and thermal analyses, magnetic susceptibility and conductivity measurements, and electronic, EPR and IR spectral studies. The infrared spectral studies revealed the bidentate or monodentate nature of the Schiff base in the complexes; the pyridine nitrogen does not participate in the coordination. A tetrahedral geometry is suggested for the nitrate-complexes and an octahedral geometry for the others. Thermal studies support the chemical formulation of these complexes.

  8. Differentiation of Candida albicans, Candida glabrata, and Candida krusei by FT-IR and chemometrics by CHROMagar™ Candida.

    Science.gov (United States)

    Wohlmeister, Denise; Vianna, Débora Renz Barreto; Helfer, Virginia Etges; Calil, Luciane Noal; Buffon, Andréia; Fuentefria, Alexandre Meneghello; Corbellini, Valeriano Antonio; Pilger, Diogo André

    2017-10-01

    Pathogenic Candida species are detected in clinical infections. CHROMagar™ is a phenotypical method used to identify Candida species, although it has limitations, which indicates the need for more sensitive and specific techniques. Infrared Spectroscopy (FT-IR) is an analytical vibrational technique used to identify patterns of metabolic fingerprint of biological matrixes, particularly whole microbial cell systems as Candida sp. in association of classificatory chemometrics algorithms. On the other hand, Soft Independent Modeling by Class Analogy (SIMCA) is one of the typical algorithms still little employed in microbiological classification. This study demonstrates the applicability of the FT-IR-technique by specular reflectance associated with SIMCA to discriminate Candida species isolated from vaginal discharges and grown on CHROMagar™. The differences in spectra of C. albicans, C. glabrata and C. krusei were suitable for use in the discrimination of these species, which was observed by PCA. Then, a SIMCA model was constructed with standard samples of three species and using the spectral region of 1792-1561cm -1 . All samples (n=48) were properly classified based on the chromogenic method using CHROMagar™ Candida. In total, 93.4% (n=45) of the samples were correctly and unambiguously classified (Class I). Two samples of C. albicans were classified correctly, though these could have been C. glabrata (Class II). Also, one C. glabrata sample could have been classified as C. krusei (Class II). Concerning these three samples, one triplicate of each was included in Class II and two in Class I. Therefore, FT-IR associated with SIMCA can be used to identify samples of C. albicans, C. glabrata, and C. krusei grown in CHROMagar™ Candida aiming to improve clinical applications of this technique. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Determination of the reference air kerma rate for 192Ir brachytherapy sources and the related uncertainty

    International Nuclear Information System (INIS)

    Dijk, Eduard van; Kolkman-Deurloo, Inger-Karine K.; Damen, Patricia M. G.

    2004-01-01

    Different methods exist to determine the air kerma calibration factor of an ionization chamber for the spectrum of a 192 Ir high-dose-rate (HDR) or pulsed-dose-rate (PDR) source. An analysis of two methods to obtain such a calibration factor was performed: (i) the method recommended by [Goetsch et al., Med. Phys. 18, 462-467 (1991)] and (ii) the method employed by the Dutch national standards institute NMi [Petersen et al., Report S-EI-94.01 (NMi, Delft, The Netherlands, 1994)]. This analysis showed a systematic difference on the order of 1% in the determination of the strength of 192 Ir HDR and PDR sources depending on the method used for determining the air kerma calibration factor. The definitive significance of the difference between these methods can only be addressed after performing an accurate analysis of the associated uncertainties. For an NE 2561 (or equivalent) ionization chamber and an in-air jig, a typical uncertainty budget of 0.94% was found with the NMi method. The largest contribution in the type-B uncertainty is the uncertainty in the air kerma calibration factor for isotope i, N k i , as determined by the primary or secondary standards laboratories. This uncertainty is dominated by the uncertainties in the physical constants for the average mass-energy absorption coefficient ratio and the stopping power ratios. This means that it is not foreseeable that the standards laboratories can decrease the uncertainty in the air kerma calibration factors for ionization chambers in the short term. When the results of the determination of the 192 Ir reference air kerma rates in, e.g., different institutes are compared, the uncertainties in the physical constants are the same. To compare the applied techniques, the ratio of the results can be judged by leaving out the uncertainties due to these physical constants. In that case an uncertainty budget of 0.40% (coverage factor=2) should be taken into account. Due to the differences in approach between the

  10. Upconversion imager measures single mid-IR photons

    DEFF Research Database (Denmark)

    Dam, Jeppe Seidelin; Tidemand-Lichtenberg, Peter; Pedersen, Christian

    2013-01-01

    The most sensitive IR detectors today are based on exotic semicoductor technology such as indium antimonide or mercury cadmium telluride. High quality detectors of these sorts are expensive and suffer from high dark currents. Dark current can be somewhat alleviated by extreme cooling. Comparing t...

  11. SYNTHESIS, IR AND NMR SPECTRAL CORRELATIONS IN SOME ...

    African Journals Online (AJOL)

    Preferred Customer

    correlated with Hammett substituent constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the above spectral data has been studied. KEY WORDS: Diimines, IR and NMR spectra, Spectral correlation, Hammett sigma constants.

  12. Multi-scale Adaptive Gain Control of IR Images

    NARCIS (Netherlands)

    Schutte, K.

    1997-01-01

    IR imagery tends to have a higher dynamic range then typical display devices such as a CRT. Global methods such as stretching and histogram equalization improve the visibility of many images, but some information in the images stays hidden for a human operator. This paper reports about the

  13. Spatially-resolved mid-IR spectroscopy of NGC 1068

    Science.gov (United States)

    Mason, R. E.; Geballe, T. R.; Packham, C.; Levenson, N. A.; Elitzur, M.; Fisher, R. S.; Perlman, E.

    2006-06-01

    We present spatially-resolved, near-diffraction-limited 10μm spectra of the nucleus of the Seyfert 2 galaxy NGC068. The spectra reveal striking variations in continuum slope, silicate feature profile and depth, and fine structure line fluxes on subarcsecond scales, illustrating in unprecedented detail the complexity of the circumnuclear regions of this galaxy at mid-IR wavelengths. The acquisition images show two distinct components: a compact (radius dust in the ionization cones. The observed spectrum of the compact source is compared with clumpy torus models, the first detailed comparison of such models with observational data. The models require most of the clouds to be located within a few parsecs of the central engine, in good agreement with recent mid-IR interferometric observations. However, the mid-IR flux measured with apertures larger than about 1 arcsec dominated by the dust emission from the ionization cones. Many previous attempts to determine the torus spectral energy distribution are thus likely to be significantly affected by contamination from the extended emission, highlighting the importance of spatial resolution in IR studies of nearby AGN.

  14. IR study of Pb–Sr titanate borosilicate glasses

    Indian Academy of Sciences (India)

    Administrator

    to study their structure systematically. IR spectrum of each glass composition shows a number of absorption bands. These bands are strongly influenced by the increasing substitution of SrO for PbO. Various bands shift with composition. Absorption peaks occur due to the vibrational mode of the borate network in these ...

  15. Mock Target Window OTR and IR Design and Testing

    Energy Technology Data Exchange (ETDEWEB)

    Wass, Alexander Joseph [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-09-19

    In order to fully verify temperature measurements made on the target window using infrared (IR) optical non-contact methods, actual comparative measurements are made with a real beam distribution as the heat source using Argonne National Laboratory’s (ANL) 35 MeV electron accelerator. Using Monte Carlo N-Particle (MCNP) simulations and thermal Finite Element Analysis (FEA), a cooled mock target window with thermocouple implants is designed to be used in such a test to achieve window temperatures up to 700°C. An uncoated and blackcoated mock window is designed to enhance the IR temperature measurements and verify optical transmitted radiation (OTR) imagery. This allows us to fully verify and characterize our temperature accuracy with our current IR camera method and any future method we may wish to explore using actual production conditions. This test also provides us with valuable conclusions/concerns regarding the calibration method we developed using our IR test stand at TA-53 in MPF-14.

  16. IR Microspectrometers based on Linear-Variable Optical Filters

    NARCIS (Netherlands)

    Emadi, A.; Wu, H.; De Graaf, G.; Wolffenbuttel, R.F.

    2013-01-01

    This paper presents the design, fabrication and characterization of Infra-Red (IR) Linear Variable Optical Filter (LVOF)-based micro-spectrometers. Two LVOF microspectrometer designs have been realized: one for operating in the 1400 nm to 2500 nm wavelength range and another between 3000 nm and 5000

  17. Historical Materialism and the Postcolonial Challenge to IR

    DEFF Research Database (Denmark)

    Ougaard, Morten

    This paper addresses one of the “exemplary questions” listed by the panel conveners, namely: “How does the postcolonial perspective enable/disable the rethinking of theories and concepts considered central to critical IR?” This requires an explication of how I see the several parts of the exempla...

  18. Score Region Algebra: Building a Transparent XML-IR Database

    NARCIS (Netherlands)

    Mihajlovic, V.; Blok, H.E.; Hiemstra, Djoerd; Apers, Peter M.G.; Chowdhury, A.; Fuhr, N.; Ronthaler, M.; Schek, H-J.; Teiken, W.

    2005-01-01

    A unified database framework that will enable better comprehension of ranked XML retrieval is still a challenge in the XML database field. We propose a logical algebra, named score region algebra, that enables transparent specification of information retrieval (IR) models for XML databases. The

  19. Near-IR imaging of cracks in teeth.

    Science.gov (United States)

    Fried, William A; Simon, Jacob C; Lucas, Seth; Chan, Kenneth H; Darling, Cynthia L; Staninec, Michal; Fried, Daniel

    2014-02-18

    Dental enamel is highly transparent at near-IR wavelengths and several studies have shown that these wavelengths are well suited for optical transillumination for the detection and imaging of tooth decay. We hypothesize that these wavelengths are also well suited for imaging cracks in teeth. Extracted teeth with suspected cracks were imaged at several wavelengths in the near-IR from 1300-1700-nm. Extracted teeth were also examined with optical coherence tomography to confirm the existence of suspected cracks. Several teeth of volunteers were also imaged in vivo at 1300-nm to demonstrate clinical potential. In addition we induced cracks in teeth using a carbon dioxide laser and imaged crack formation and propagation in real time using near-IR transillumination. Cracks were clearly visible using near-IR imaging at 1300-nm in both in vitro and in vivo images. Cracks and fractures also interfered with light propagation in the tooth aiding in crack identification and assessment of depth and severity.

  20. Active IR System for Projectile Detection and Tracking

    Directory of Open Access Journals (Sweden)

    STANCIC, I.

    2017-11-01

    Full Text Available Reliable detection and tracking of high-speed projectiles is crucial in providing modern battlefield protection or to be used as a forensic tool. Subsonic projectiles fired from silenced weapons are difficult to detect, whereas reliable tracking of the projectile trajectory is hard to accomplish. Contemporary radar based counter-battery systems showed to be valuable in detection of incoming artillery fire, but are unable to provide detection at close ranges. In this paper, an active IR system is proposed that aims to detect and track incoming projectiles at close ranges. Proposed system is able to reconstruct projectile’s trajectory in space, predict impact location and estimate direction of projectile origin. Active detector system is based on a pair of high-speed cameras in stereo-configuration synced with computer and IR illuminator that emits coded IR light bursts. Innovative IR light coding enables automated detection and tracking of a nearby projectile and elimination of false positive alarms caused by distant objects.

  1. Phytochemical, IR Spectral and Biological Studies on the Leaf ...

    African Journals Online (AJOL)

    However, the n-hexane and diethyl ether fractions were not active against any of the test organisms even at 2000μg. The IR spectra of crude extract and fractions showed the presence of hydroxyl, carbonyl and aromatic systems which are in good agreement with results of the phytochemical analysis of the crude extract.

  2. The Community College IR Shop and Accreditation: A Case Study

    Science.gov (United States)

    Johnston, George

    2011-01-01

    This article presents results of a study the author recently conducted on the role of traditional institutional research (IR) offices in support of accreditation activities and institutional effectiveness. The purpose of the study was to confirm or disconfirm the utility of a theoretical model developed by Brittingham, O'Brien, and Alig (2008) of…

  3. Neo-Poulantzian Perspectives in IR and the Current Crisis

    DEFF Research Database (Denmark)

    Ougaard, Morten

    This paper is about Poulantzas, historical materialism, international relations, and the current crisis. My purpose is to discuss how some Poulantzian theoretical contributions can be applied to the study of subject matters that are the focus of academic fields such as International Relations (IR...

  4. The IR-4 Program - how it can benefit nurseries

    Science.gov (United States)

    J. Ray Frank

    2002-01-01

    The Interregional Research Project 4 (IR-4) was initiated in 1963 to obtain national pesticide label regsitrations for use on food and fiber. This program has an emphasis on minor uses or specialty crops. In this arena in the United States today it includes 600 crops.

  5. Assessment of the exchange parameters of Amberlite IR-45 (OH ...

    African Journals Online (AJOL)

    CLEMENT O BEWAJI

    ABSTRACT: Simple quantitative technique has been developed for assessing the exchange parameters of Amberlite IR. – 45 (OH) using column chromatographic techniques from the displacement of exchangeable hydroxyl ions of the resin by sulphate ions. The results obtained showed retention time of 33min, retention ...

  6. Isothermal anisotropic magnetoresistance in antiferromagnetic metallic IrMn.

    Science.gov (United States)

    Galceran, R; Fina, I; Cisneros-Fernández, J; Bozzo, B; Frontera, C; López-Mir, L; Deniz, H; Park, K-W; Park, B-G; Balcells, Ll; Martí, X; Jungwirth, T; Martínez, B

    2016-10-20

    Antiferromagnetic spintronics is an emerging field; antiferromagnets can improve the functionalities of ferromagnets with higher response times, and having the information shielded against external magnetic field. Moreover, a large list of aniferromagnetic semiconductors and metals with Néel temperatures above room temperature exists. In the present manuscript, we persevere in the quest for the limits of how large can anisotropic magnetoresistance be in antiferromagnetic materials with very large spin-orbit coupling. We selected IrMn as a prime example of first-class moment (Mn) and spin-orbit (Ir) combination. Isothermal magnetotransport measurements in an antiferromagnetic-metal(IrMn)/ferromagnetic-insulator thin film bilayer have been performed. The metal/insulator structure with magnetic coupling between both layers allows the measurement of the modulation of the transport properties exclusively in the antiferromagnetic layer. Anisotropic magnetoresistance as large as 0.15% has been found, which is much larger than that for a bare IrMn layer. Interestingly, it has been observed that anisotropic magnetoresistance is strongly influenced by the field cooling conditions, signaling the dependence of the found response on the formation of domains at the magnetic ordering temperature.

  7. Misaligned disks in the binary protostar IRS 43

    DEFF Research Database (Denmark)

    Brinch, Christian; Jørgensen, Jes Kristian; Hogerheijde, Michiel R.

    2016-01-01

    Recent high angular resolution (∼ 0\\buildrel{\\prime\\prime}\\over{.} 2) ALMA observations of the 1.1 mm continuum and of HCO+ J = 3–2 and HCN J = 3–2 gas toward the binary protostar IRS 43 reveal multiple Keplerian disks that are significantly misaligned (\\gt 60^\\circ ), both in inclination...

  8. Score Region Algebra: Building a Transparant XML-IR Database

    NARCIS (Netherlands)

    Mihajlovic, V.; Blok, H.E.; Hiemstra, Djoerd; Apers, Peter M.G.

    2005-01-01

    A unied database framework that will enable better comprehension of ranked XML retrieval is still a challenge in the XML database field. We propose a logical algebra, named score region algebra, that enables transparent specification of information retrieval (IR) models for XML databases. The

  9. The TIJAH XML-IR system at INEX 2003

    NARCIS (Netherlands)

    J.A. List; V. Mihajlovic; A.P. de Vries (Arjen); G. Ramirez Camps (Georgina); D. Hiemstra

    2003-01-01

    textabstractThis paper discusses our participation in INEX (the Initiative for the Evaluation of XML Retrieval) using the TIJAH XML-IR system. TIJAH's system design follows a `standard' layered database architecture, carefully separating the conceptual, logical and physical levels. At the conceptual

  10. Phytochemical, IR Spectral and Biological Studies on the Leaf ...

    African Journals Online (AJOL)

    MBI

    investigations some extracts of the root of C. africana were found to possess ... vapour and UV lamp (366+254 nm). IR measurements were ... ChemSearch Journal 4(1): 14 – 17, June, 2013. Publication of Chemical Society of Nigeria, Kano Chapter. Received: 31/05/2013. Accepted: 21/06/2013. C .S. N. C. H. E. M. IC. A.

  11. Assessment of the exchange parameters of Amberlite IR-45 (OH ...

    African Journals Online (AJOL)

    Simple quantitative technique has been developed for assessing the exchange parameters of Amberlite IR – 45 (OH) using column chromatographic techniques from the displacement of exchangeable hydroxyl ions of the resin by sulphate ions. The results obtained showed retention time of 33min, retention volume of ...

  12. IR study of Pb–Sr titanate borosilicate glasses

    Indian Academy of Sciences (India)

    Administrator

    IR study of Pb–Sr titanate borosilicate glasses. C R GAUTAM*, DEVENDRA KUMAR. † and OM PARKASH. †. Department of Physics, University of Lucknow, Lucknow 226 007, India. †. Department of Ceramic Engineering, Institute of Technology, Banaras Hindu University, Varanasi 221 005, India. MS received 3 January ...

  13. Near-IR imaging of cracks in teeth

    Science.gov (United States)

    Fried, William A.; Simon, Jacob C.; Lucas, Seth; Chan, Kenneth H.; Darling, Cynthia L.; Staninec, Michal; Fried, Daniel

    2014-02-01

    Dental enamel is highly transparent at near-IR wavelengths and several studies have shown that these wavelengths are well suited for optical transillumination for the detection and imaging of tooth decay. We hypothesize that these wavelengths are also well suited for imaging cracks in teeth. Extracted teeth with suspected cracks were imaged at several wavelengths in the near-IR from 1300-1700-nm. Extracted teeth were also examined with optical coherence tomography to confirm the existence of suspected cracks. Several teeth of volunteers were also imaged in vivo at 1300-nm to demonstrate clinical potential. In addition we induced cracks in teeth using a carbon dioxide laser and imaged crack formation and propagation in real time using near-IR transillumination. Cracks were clearly visible using near-IR imaging at 1300-nm in both in vitro and in vivo images. Cracks and fractures also interfered with light propagation in the tooth aiding in crack identification and assessment of depth and severity.

  14. Development of nanostructured protective "sight glasses" for IR gas sensors

    DEFF Research Database (Denmark)

    Bergmann, René; Davis, Zachary James; Schmidt, Michael Stenbæk

    2011-01-01

    property of the surface could be enhanced, shown by contact angle and roll-off angle measurements. The "self-cleaning" surface property and chemical robustness towards aggressive environments are demonstrated. FT-IR spectroscopy concerning the optical properties of these nanostructured silicon windows...

  15. FT-IR, NMR SPECTROSCOPIC and QUANTUM MECHANICAL ...

    African Journals Online (AJOL)

    FT-IR, NMR SPECTROSCOPIC and QUANTUM MECHANICAL. INVESTIGATIONS OF TWO FERROCENE DERIVATIVES. Özgür Alver1* and Cemal Parlak2. 1Department of Physics, Science Faculty, Anadolu University, Eskişehir, 26470, Turkey. 2Department of Physics, Science Faculty, Ege University, İzmir, 35100, ...

  16. Iridium Sulfide and Ir Promoted Mo Based Catalysts.

    Czech Academy of Sciences Publication Activity Database

    Vít, Zdeněk

    2007-01-01

    Roč. 322, - (2007), s. 142-151 ISSN 0926-860X R&D Projects: GA ČR(CZ) GA104/06/0870 Institutional research plan: CEZ:AV0Z40720504 Keywords : iridium sulfide * IrMo catalyst * hydrodesulfurization Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.166, year: 2007

  17. New Mn(II, Ni(II, Cd(II, Pb(II complexes with 2-methylbenzimidazole and other ligands. Synthesis, spectroscopic characterization, crystal structure, magnetic susceptibility and biological activity studies

    Directory of Open Access Journals (Sweden)

    Shayma A. Shaker

    2016-11-01

    Full Text Available Synthesis and characterization of Mn(II, Ni(II, Cd(II and Pb(II mixed ligand complexes of 2-methylbenzimidazole with other ligands have been reported. The structure of the ligands and their complexes was investigated using elemental analysis, IR, UV–Vis, (1H, 13C NMR spectroscopy, molar conductivity and magnetic susceptibility measurements. In all the studies of complexes, the 2-methylbenzimidazole behaves as a neutral monodentate ligand which is coordinated with the metal ions through the N atom. While benzotriazole behaves as a neutral bidentate ligand which is coordinated with the Ni(II ion through the two N atoms. Moreover, the N-acetylglycine behaves as a bidentate ligand which is coordinated with the Mn(II, Ni(II and Pb(II ions through the N atom and the terminal carboxyl oxygen atom. The magnetic and spectral data indicate the tetrahedral geometry for Mn(II complex, irregular tetrahedral geometry for Pb(II complex and octahedral geometry for Ni(II complex. The X-ray single crystal diffraction method was used to confirm a centrosymmetric dinuclear Cd(II complex as each two metal ions are linked by a pair of thiocyanate N = S bridge. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted square pyramid geometry around the Cd atom. Besides, different cell types were used to determine the inhibitory effect of Mn(II, Ni(II, Cd(II and Pb(II complexes on cell growth using MTT assay. Cd(II complex showed cytotoxic effect on various types of cancer cell lines with different EC50 values.

  18. and copper(ii)

    African Journals Online (AJOL)

    DELL

    IR Spectra showed that the ligands coordinated in enol form through the deprotonated carbonyl bond (C=O) and the ... BDH and Sigma Aldrich quality and used without .... Infrared Spectra. The structurally significant IR bands for free ligand and its complexes are reported in Table 3. The diagnostic and relevant vibrational.

  19. Using IR Imaging of Water Surfaces for Estimating Piston Velocities

    Science.gov (United States)

    Gålfalk, M.; Bastviken, D.; Arneborg, L.

    2013-12-01

    The transport of gasses dissolved in surface waters across the water-atmosphere interface is controlled by the piston velocity (k). This coefficient has large implications for, e.g., greenhouse gas fluxes but is challenging to quantify in situ. At present, empirical k-wind speed relationships from a small number of studies and systems are often extrapolated without knowledge of model performance. It is therefore of interest to search for new methods for estimating k, and to compare the pros and cons of existing and new methods. Wind speeds in such models are often measured at a height of 10 meters. In smaller bodies of water such as lakes, wind speeds can vary dramatically across the surface through varying degrees of wind shadow from e.g. trees at the shoreline. More local measurements of the water surface, through wave heights or surface motion mapping, could give improved k-estimates over a surface, also taking into account wind fetch. At thermal infrared (IR) wavelengths water has very low reflectivity (depending on viewing angle) than can go below 1%, meaning that more than 99% is heat radiation giving a direct measurement of surface temperature variations. Using an IR camera at about 100 frames/s one could map surface temperature structures at a fraction of a mm depth even with waves present. In this presentation I will focus on IR imaging as a possible tool for estimating piston velocities. Results will be presented from IR field measurements, relating the motions of surface temperature structures to k calculated from other simultaneous measurements (flux chamber and ADV-Based Dissipation Rate), but also attempting to calculate k directly from the IR surface divergence. A relation between wave height and k will also be presented.

  20. 1-Naphthylazo derivatives of some 1,3-dicarbonyl compounds and their Cu(II, Ni(II and Zn(II complexes

    Directory of Open Access Journals (Sweden)

    K. KRISHNANKUTTY

    2009-11-01

    Full Text Available The coupling of diazotized 1-aminonaphthalene with 1,3-dicarbonyl compounds (acetylacetone, methylacetoacetate and acetoacetanilide yielded a new series of bidentate ligand systems (HL. Analytical, IR, 1H-NMR and mass spectral data indicate that the compounds exist in the intramolecularly hydrogen bonded keto-hydrazone form. With Ni(II, Cu(II and Zn(II, these potential monobasic bidentate ligands formed [ML2] type complexes. The IR, 1H-NMR and mass spectral data of the complexes are consistent with the replacement of the chelated hydrazone proton of the ligand by a metal ion, thus leading to a stable six-membered chelate ring involving the hydrazone nitrogen and the hydrogen bonded carbonyl oxygen. The Ni(II and Zn(II chelates are diamagnetic, while the Cu(II complexes are paramagnetic. In the metal complexes of the naphthylazo derivatives of acetylacetone and methylacetoacetate, the acetyl carbonyl is involved in coordination, whereas in the chelates of the naphthylazo derivative of acetoacetanilide, the anilide carbonyl is bonded with the metal ion.

  1. Thermal-to-visible transducer (TVT) for thermal-IR imaging

    Science.gov (United States)

    Flusberg, Allen; Swartz, Stephen; Huff, Michael; Gross, Steven

    2008-04-01

    We have been developing a novel thermal-to-visible transducer (TVT), an uncooled thermal-IR imager that is based on a Fabry-Perot Interferometer (FPI). The FPI-based IR imager can convert a thermal-IR image to a video electronic image. IR radiation that is emitted by an object in the scene is imaged onto an IR-absorbing material that is located within an FPI. Temperature variations generated by the spatial variations in the IR image intensity cause variations in optical thickness, modulating the reflectivity seen by a probe laser beam. The reflected probe is imaged onto a visible array, producing a visible image of the IR scene. This technology can provide low-cost IR cameras with excellent sensitivity, low power consumption, and the potential for self-registered fusion of thermal-IR and visible images. We will describe characteristics of requisite pixelated arrays that we have fabricated.

  2. OGTT results in obese adolescents with normal HOMA-IR values.

    Science.gov (United States)

    Sahin, Nursel Muratoglu; Kinik, Sibel Tulgar; Tekindal, Mustafa Agah

    2013-01-01

    To investigate insulin resistance (IR) with OGTT in obese adolescents who have normal fasting insulin and homeostasis model assessment for insulin resistance (HOMA-IR). A total of 97 obese adolescents who had values of HOMA-IR 2083.5 pmol/L (300 μU/mL) in OGTT. IR risk factors were defined as family history of diabetes mellitus, acanthosis nigricans (AN), and hepatic steatosis. IR was detected in 61 (62.9%) patients. The IR group had significantly more frequent AN (p=0.0001). As the number of risk factors increased, the frequency of IR also increased (p=0.01). We advise to perform OGTT in obese adolescents with normal HOMA-IR, if they have risk factors for IR.

  3. Galaxy Evolution Studies with the SPace IR Telescope for Cosmology and Astrophysics (SPICA): The Power of IR Spectroscopy

    Science.gov (United States)

    Spinoglio, L.; Alonso-Herrero, A.; Armus, L.; Baes, M.; Bernard-Salas, J.; Bianchi, S.; Bocchio, M.; Bolatto, A.; Bradford, C.; Braine, J.; Carrera, F. J.; Ciesla, L.; Clements, D. L.; Dannerbauer, H.; Doi, Y.; Efstathiou, A.; Egami, E.; Fernández-Ontiveros, J. A.; Ferrara, A.; Fischer, J.; Franceschini, A.; Gallerani, S.; Giard, M.; González-Alfonso, E.; Gruppioni, C.; Guillard, P.; Hatziminaoglou, E.; Imanishi, M.; Ishihara, D.; Isobe, N.; Kaneda, H.; Kawada, M.; Kohno, K.; Kwon, J.; Madden, S.; Malkan, M. A.; Marassi, S.; Matsuhara, H.; Matsuura, M.; Miniutti, G.; Nagamine, K.; Nagao, T.; Najarro, F.; Nakagawa, T.; Onaka, T.; Oyabu, S.; Pallottini, A.; Piro, L.; Pozzi, F.; Rodighiero, G.; Roelfsema, P.; Sakon, I.; Santini, P.; Schaerer, D.; Schneider, R.; Scott, D.; Serjeant, S.; Shibai, H.; Smith, J.-D. T.; Sobacchi, E.; Sturm, E.; Suzuki, T.; Vallini, L.; van der Tak, F.; Vignali, C.; Yamada, T.; Wada, T.; Wang, L.

    2017-11-01

    IR spectroscopy in the range 12-230 μm with the SPace IR telescope for Cosmology and Astrophysics (SPICA) will reveal the physical processes governing the formation and evolution of galaxies and black holes through cosmic time, bridging the gap between the James Webb Space Telescope and the upcoming Extremely Large Telescopes at shorter wavelengths and the Atacama Large Millimeter Array at longer wavelengths. The SPICA, with its 2.5-m telescope actively cooled to below 8 K, will obtain the first spectroscopic determination, in the mid-IR rest-frame, of both the star-formation rate and black hole accretion rate histories of galaxies, reaching lookback times of 12 Gyr, for large statistically significant samples. Densities, temperatures, radiation fields, and gas-phase metallicities will be measured in dust-obscured galaxies and active galactic nuclei, sampling a large range in mass and luminosity, from faint local dwarf galaxies to luminous quasars in the distant Universe. Active galactic nuclei and starburst feedback and feeding mechanisms in distant galaxies will be uncovered through detailed measurements of molecular and atomic line profiles. The SPICA's large-area deep spectrophotometric surveys will provide mid-IR spectra and continuum fluxes for unbiased samples of tens of thousands of galaxies, out to redshifts of z 6.

  4. Synthesis, spectroscopic characterization, molecular modeling and potentiometric studies of Co(II), Ni(II), Cu(II) and Zn(II) complexes with 1,1-diaminobutane-Schiff base

    Science.gov (United States)

    Alaghaz, Abdel-Nasser M. A.

    2014-08-01

    Complexes of cobalt(II), nickel(II), copper(II) and zinc(II) of general composition [M(L)(H2O)2]·2H2O have been synthesized [L = N,N";-bis(2-hydroxybenzylidene)-1,1-diaminobutane]. The elemental analysis, molar conductance measurements, magnetic susceptibility measurements, mass, IR, UV, NMR, SEM, EDX, thermal and EPR spectral studies of the compounds led to the conclusion that the ligand acts as a tetradentate manner. The molar conductance of the complexes in fresh solution of DMSO lies in the range of 7.46-9.13 Ω-1 cm2 mol-1 indicating their non-electrolytic behavior. On the basis of analytical and spectroscopic techniques, octahedral geometry of the complexes was proposed. The Schiff base acts as tetradentate ligand, coordinated through deprotonated phenolic oxygen and azomethine nitrogen atoms. The ligand field parameters were calculated for Co(II), Ni(II) and Cu(II) complexes and their values were found in the range reported for a octahedral structure. The molecular parameters of the ligand and its Co(II), Ni(II), Cu(II) and Zn(II) complexes have been calculated. Protonation constants of Schiff base and stability constants of their binary metal complexes have been determined potentiometrically in 50% DMSO-water media at 25 °C and ionic strength 0.10 M sodium perchlorate.

  5. Fe (III), Co(II), Ni(II), Cu(II) and Zn(II) complexes of schiff bases based-on glycine and phenylalanine: Synthesis, magnetic/thermal properties and antimicrobial activity

    Science.gov (United States)

    Sevgi, Fatih; Bagkesici, Ugur; Kursunlu, Ahmed Nuri; Guler, Ersin

    2018-02-01

    Zinc (II), copper (II), nickel (II), cobalt (II) and iron (III) complexes of Schiff bases (LG, LP) derived from 2-hydroxynaphthaldehyde with glycine and phenylalanine were reported and characterized by 1H NMR, 13C NMR, elemental analyses, melting point, FT-IR, magnetic susceptibility and thermal analyses (TGA). TGA data show that iron and cobalt include to the coordinated water and metal:ligand ratio is 1:2 while the complex stoichiometry for Ni (II), Cu (II) and Zn (II) complexes is 1:1. As expected, Ni (II) and Zn (II) complexes are diamagnetic; Cu (II), Co (II) and Fe (III) complexes are paramagnetic character due to a strong ligand of LG and LP. The LG, LP and their metal complexes were screened for their antimicrobial activities against five Gram-positive (Staphylococcus aureus, Methicillin resistant Staphylococcus aureus (MRSA), Bacillus cereus, Streptococcus mutans and Enterococcus faecalis) and three Gram-negative (Escherichia coli, Klebsiella pneumoniae and Pseudomonas aeruginosa) and one fungi (Candida albicans) by using broth microdilution techniques. The activity data show that ligands and their metal complexes exhibited moderate to good activity against Gram-positive bacteria and fungi.

  6. Ankyrin repeat and SOCS box containing protein 4 (Asb-4 colocalizes with insulin receptor substrate 4 (IRS4 in the hypothalamic neurons and mediates IRS4 degradation

    Directory of Open Access Journals (Sweden)

    Xia Zefeng

    2011-09-01

    Full Text Available Abstract Background The arcuate nucleus of the hypothalamus regulates food intake. Ankyrin repeat and SOCS box containing protein 4 (Asb-4 is expressed in neuropeptide Y and proopiomelanocortin (POMC neurons in the arcuate nucleus, target neurons in the regulation of food intake and metabolism by insulin and leptin. However, the target protein(s of Asb-4 in these neurons remains unknown. Insulin receptor substrate 4 (IRS4 is an adaptor molecule involved in the signal transduction by both insulin and leptin. In the present study we examined the colocalization and interaction of Asb-4 with IRS4 and the involvement of Asb-4 in insulin signaling. Results In situ hybridization showed that the expression pattern of Asb-4 was consistent with that of IRS4 in the rat brain. Double in situ hybridization showed that IRS4 colocalized with Asb-4, and both Asb-4 and IRS4 mRNA were expressed in proopiomelanocortin (POMC and neuropeptide Y (NPY neurons within the arcuate nucleus of the hypothalamus. In HEK293 cells co-transfected with Myc-tagged Asb-4 and Flag-tagged IRS4, Asb-4 co-immunoprecipitated with IRS4; In these cells endogenous IRS4 also co-immunoprecipitated with transfected Myc-Asb-4; Furthermore, Asb-4 co-immunoprecipitated with IRS4 in rat hypothalamic extracts. In HEK293 cells over expression of Asb-4 decreased IRS4 protein levels and deletion of the SOCS box abolished this effect. Asb-4 increased the ubiquitination of IRS4; Deletion of SOCS box abolished this effect. Expression of Asb-4 decreased both basal and insulin-stimulated phosphorylation of AKT at Thr308. Conclusions These data demonstrated that Asb-4 co-localizes and interacts with IRS4 in hypothalamic neurons. The interaction of Asb-4 with IRS4 in cell lines mediates the degradation of IRS4 and decreases insulin signaling.

  7. Compensatory insulin receptor (IR) activation on inhibition of insulin-like growth factor-1 receptor (IGF-1R): rationale for cotargeting IGF-1R and IR in cancer.

    Science.gov (United States)

    Buck, Elizabeth; Gokhale, Prafulla C; Koujak, Susan; Brown, Eric; Eyzaguirre, Alexandra; Tao, Nianjun; Rosenfeld-Franklin, Maryland; Lerner, Lorena; Chiu, M Isabel; Wild, Robert; Epstein, David; Pachter, Jonathan A; Miglarese, Mark R

    2010-10-01

    Insulin-like growth factor-1 receptor (IGF-1R) is a receptor tyrosine kinase (RTK) and critical activator of the phosphatidylinositol 3-kinase-AKT pathway. IGF-1R is required for oncogenic transformation and tumorigenesis. These observations have spurred anticancer drug discovery and development efforts for both biological and small-molecule IGF-1R inhibitors. The ability for one RTK to compensate for another to maintain tumor cell viability is emerging as a common resistance mechanism to antitumor agents targeting individual RTKs. As IGF-1R is structurally and functionally related to the insulin receptor (IR), we asked whether IR is tumorigenic and whether IR-AKT signaling contributes to resistance to IGF-1R inhibition. Both IGF-1R and IR(A) are tumorigenic in a mouse mammary tumor model. In human tumor cells coexpressing IGF-1R and IR, bidirectional cross talk was observed following either knockdown of IR expression or treatment with a selective anti-IGF-1R antibody, MAB391. MAB391 treatment resulted in a compensatory increase in phospho-IR, which was associated with resistance to inhibition of IRS1 and AKT. In contrast, treatment with OSI-906, a small-molecule dual inhibitor of IGF-1R/IR, resulted in enhanced reduction in phospho-IRS1/phospho-AKT relative to MAB391. Insulin or IGF-2 activated the IR-AKT pathway and decreased sensitivity to MAB391 but not to OSI-906. In tumor cells with an autocrine IGF-2 loop, both OSI-906 and an anti-IGF-2 antibody reduced phospho-IR/phospho-AKT, whereas MAB391 was ineffective. Finally, OSI-906 showed superior efficacy compared with MAB391 in human tumor xenograft models in which both IGF-1R and IR were phosphorylated. Collectively, these data indicate that cotargeting IGF-1R and IR may provide superior antitumor efficacy compared with targeting IGF-1R alone.

  8. The characterization of natural gemstones using non-invasive FT-IR spectroscopy: New data on tourmalines.

    Science.gov (United States)

    Mercurio, Mariano; Rossi, Manuela; Izzo, Francesco; Cappelletti, Piergiulio; Germinario, Chiara; Grifa, Celestino; Petrelli, Maurizio; Vergara, Alessandro; Langella, Alessio

    2018-02-01

    Fourteen samples of tourmaline from the Real Museo Mineralogico of Federico II University (Naples) have been characterized through multi-methodological investigations (EMPA-WDS, SEM-EDS, LA-ICP-MS, and FT-IR spectroscopy). The samples show different size, morphology and color, and are often associated with other minerals. Data on major and minor elements allowed to identify and classify tourmalines as follows: elbaites, tsilaisite, schorl, dravites, uvites and rossmanite. Non-invasive, non-destructive FT-IR and in-situ analyses were carried out on the same samples to validate this chemically-based identification and classification. The results of this research show that a complete characterization of this mineral species, usually time-consuming and expensive, can be successfully achieved through non-destructive FT-IR technique, thus representing a reliable tool for a fast classification extremely useful to plan further analytical strategies, as well as to support gemological appraisals. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. miR-146b Inhibits Glucose Consumption by Targeting IRS1 Gene in Porcine Primary Adipocytes.

    Science.gov (United States)

    Zhu, Yan-Ling; Chen, Ting; Xiong, Jia-Li; Wu, Di; Xi, Qian-Yun; Luo, Jun-Yi; Sun, Jia-Jie; Zhang, Yong-Liang

    2018-03-09

    Adipose tissue plays an important role in energy metabolism. Adipose dysfunction is closely related to obesity and type II diabetes. Glucose uptake is the key step for fat synthesis in adipocyte. miRNAs have been proven to play a crucial role in adipocyte differentiation, adipogenesis and glucose homeostasis. In this paper, we firstly reported that miR-146b decreased glucose consumption by up-regulating miR-146b in a porcine primary adipocyte model, while the inhibitor of endogenous miR-146b rescued the reduction. Then, miR-146b was predicated to target IRS1 by bioinformatics analysis, and a dual-luciferase reporter assay validated this predication. Western blot analyses indicated both IRS1 and glucose transporter type 4 (GLUT4) were down-regulated by miR-146b overexpression. Our study demonstrated that miR-146b regulated glucose homeostasis in porcine primary pre-adipocyte by targeting IRS1 , and provided new understandings on regulations of lipogenesis by miRNAs.

  10. miR-146b Inhibits Glucose Consumption by Targeting IRS1 Gene in Porcine Primary Adipocytes

    Directory of Open Access Journals (Sweden)

    Yan-Ling Zhu

    2018-03-01

    Full Text Available Adipose tissue plays an important role in energy metabolism. Adipose dysfunction is closely related to obesity and type II diabetes. Glucose uptake is the key step for fat synthesis in adipocyte. miRNAs have been proven to play a crucial role in adipocyte differentiation, adipogenesis and glucose homeostasis. In this paper, we firstly reported that miR-146b decreased glucose consumption by up-regulating miR-146b in a porcine primary adipocyte model, while the inhibitor of endogenous miR-146b rescued the reduction. Then, miR-146b was predicated to target IRS1 by bioinformatics analysis, and a dual-luciferase reporter assay validated this predication. Western blot analyses indicated both IRS1 and glucose transporter type 4 (GLUT4 were down-regulated by miR-146b overexpression. Our study demonstrated that miR-146b regulated glucose homeostasis in porcine primary pre-adipocyte by targeting IRS1, and provided new understandings on regulations of lipogenesis by miRNAs.

  11. IR-based spot weld NDT in automotive applications

    Science.gov (United States)

    Chen, Jian; Feng, Zhili

    2015-05-01

    Today's auto industry primarily relies on destructive teardown evaluation to ensure the quality of the resistance spot welds (RSWs) due to their criticality in crash resistance and performance of vehicles. The destructive teardown evaluation is labor intensive and costly. The very nature of the destructive test means only a few selected welds will be sampled for quality. Most of the welds in a car are never checked. There are significant costs and risks associated with reworking and scrapping the defective welded parts made between the teardown tests. IR thermography as a non-destructive testing (NDT) tool has its distinct advantage — its non-intrusive and non-contact nature. This makes the IR based NDT especially attractive for the highly automated assembly lines. IR for weld quality inspection has been explored in the past, mostly limited to the offline post-processing manner in a laboratory environment. No online real-time RSW inspection using IR thermography has been reported. Typically for postprocessing inspection, a short-pulse heating via xenon flash lamp light (in a few milliseconds) is applied to the surface of a spot weld. However, applications in the auto industry have been unsuccessful, largely due to a critical drawback that cannot be implemented in the high-volume production line - the prerequisite of painting the weld surface to eliminate surface reflection and other environmental interference. This is due to the low signal-to-noise ratio resulting from the low/unknown surface emissivity and the very small temperature changes (typically on the order of 0.1°C) induced by the flash lamp method. An integrated approach consisting of innovations in both data analysis algorithms and hardware apparatus that effectively solved the key technical barriers for IR NDT. The system can be used for both real-time (during welding) and post-processing inspections (after welds have been made). First, we developed a special IR thermal image processing method that

  12. Hybrid nanomaterial and its applications: IR sensing and energy harvesting

    Science.gov (United States)

    Tseng, Yi-Hsuan

    In this dissertation, a hybrid nanomaterial, single-wall carbon nanotubes-copper sulfide nanoparticles (SWNTs-CuS NPs), was synthesized and its properties were analyzed. Due to its unique optical and thermal properties, the hybrid nanomaterial exhibited great potential for infrared (IR) sensing and energy harvesting. The hybrid nanomaterial was synthesized with the non-covalent bond technique to functionalize the surface of the SWNTs and bind the CuS nanoparticles on the surface of the SWNTs. For testing and analyzing the hybrid nanomaterial, SWNTs-CuS nanoparticles were formed as a thin film structure using the vacuum filtration method. Two conductive wires were bound on the ends of the thin film to build a thin film device for measurements and analyses. Measurements found that the hybrid nanomaterial had a significantly increased light absorption (up to 80%) compared to the pure SWNTs. Moreover, the hybrid nanomaterial thin film devices exhibited a clear optical and thermal switching effect, which could be further enhanced up to ten times with asymmetric illumination of light and thermal radiation on the thin film devices instead of symmetric illumination. A simple prototype thermoelectric generator enabled by the hybrid nanomaterials was demonstrated, indicating a new route for achieving thermoelectricity. In addition, CuS nanoparticles have great optical absorption especially in the near-infrared region. Therefore, the hybrid nanomaterial thin films also have the potential for IR sensing applications. The first application to be covered in this dissertation is the IR sensing application. IR thin film sensors based on the SWNTs-CuS nanoparticles hybrid nanomaterials were fabricated. The IR response in the photocurrent of the hybrid thin film sensor was significantly enhanced, increasing the photocurrent by 300% when the IR light illuminates the thin film device asymmetrically. The detection limit could be as low as 48mW mm-2. The dramatically enhanced

  13. Stage I-II squamous cell carcinoma of the oral cavity treated by iridium-192

    International Nuclear Information System (INIS)

    Piedbois, P.; Mazeron, J.J.; Haddad, E.; Coste, A.; Martin, M.; Levy, C.; Raynal, M.; Pavlovitch, J.M.; Peynegre, R.; Perquin, B.; Bourgeois, J.P. le

    1991-01-01

    This is a retrospective analysis of 233 evaluable patients with stage I-II squamous cell carcinoma of the oral cavity treated by definitive brachytherapy. Minimum follow-up is 3 years. Treatment of the neck was chosen by a multidisciplinary team, according to age, medical status and availability for follow-up. One hundred and ten patients (47 percent) underwent elective neck dissection (END), 28 (25 percent) had positive nodes and received neck irradiation post-operatively. One hundred and twenty-three patients (53 percent) were regularly followed up only, with therapeutic neck dissection (TND) reserved for cases of node relapses. In the END group, there were 19 neck relapses (17 percent): 12/60 (20 percent) in patients with mobile tongue carcinoma and 7/50 (14 percent) in patients with floor of the mouth carcinoma. Salvage treatment was successful in 13-21 (62 percent) cases. Ten-year survival is 37 percent for the END-group and 31 percent for the TND group. Tumour stage and infiltration into underlying tissues increased the probability of neck relapse and death. Furthermore, a multivariate analysis showed that patients treated in the TND group had a higher probability of death than patients treated in the END group (p<0.04). (author). 30 refs.; 2 figs.; 7 tabs

  14. IR spectral analysis for the diagnostics of crust earthquake precursors

    Science.gov (United States)

    Umarkhodgaev, R. M.; Liperovsky, V. A.; Mikhailin, V. V.; Meister, C.-V.; Naumov, D. Ju

    2012-04-01

    In regions of future earthquakes, a few days before the seismic shock, the emanation of radon and hydrogen is being observed, which causes clouds of increased ionisation in the atmosphere. In the present work the possible diagnostics of these clouds using infrared (IR) spectroscopy is considered, which may be important and useful for the general geophysical system of earthquake prediction and the observation of industrial emissions of radioactive materials into the atmosphere. Some possible physical processes are analysed, which cause, under the condition of additional ionisation in a pre-breakdown electrical field, emissions in the IR interval. In doing so, the transparency region of the IR spectrum at wavelengths of 7-15 μm is taken into account. This transparency region corresponds to spectral lines of small atmospheric constituents like CH4, CO2, N2O, NO2, NO, and O3. The possible intensities of the IR emissions observable in laboratories and in nature are estimated. The acceleration process of the electrons in the pre-breakdown electrical field before its adhesion to the molecules is analysed. The laboratory equipment for the investigation of the IR absorption spectrum is constructed for the cases of normal and decreased atmospheric pressures. The syntheses of ozone and nitrous oxides are performed in the barrier discharge. It is studied if the products of the syntheses may be used to model atmospheric processes where these components take part. Spectra of products of the syntheses in the wavelength region of 2-10 μm are observed and analysed. A device is created for the syntheses and accumulation of nitrous oxides. Experiments to observe the IR-spectra of ozone and nitrous oxides during the syntheses and during the further evolution of these molecules are performed. For the earthquake prediction, practically, the investigation of emission spectra is most important, but during the laboratory experiments, the radiation of the excited molecules is shifted by a

  15. Assessment of COTS IR image simulation tools for ATR development

    Science.gov (United States)

    Seidel, Heiko; Stahl, Christoph; Bjerkeli, Frode; Skaaren-Fystro, Paal

    2005-05-01

    Following the tendency of increased use of imaging sensors in military aircraft, future fighter pilots will need onboard artificial intelligence e.g. ATR for aiding them in image interpretation and target designation. The European Aeronautic Defence and Space Company (EADS) in Germany has developed an advanced method for automatic target recognition (ATR) which is based on adaptive neural networks. This ATR method can assist the crew of military aircraft like the Eurofighter in sensor image monitoring and thereby reduce the workload in the cockpit and increase the mission efficiency. The EADS ATR approach can be adapted for imagery of visual, infrared and SAR sensors because of the training-based classifiers of the ATR method. For the optimal adaptation of these classifiers they have to be trained with appropriate and sufficient image data. The training images must show the target objects from different aspect angles, ranges, environmental conditions, etc. Incomplete training sets lead to a degradation of classifier performance. Additionally, ground truth information i.e. scenario conditions like class type and position of targets is necessary for the optimal adaptation of the ATR method. In Summer 2003, EADS started a cooperation with Kongsberg Defence & Aerospace (KDA) from Norway. The EADS/KDA approach is to provide additional image data sets for training-based ATR through IR image simulation. The joint study aims to investigate the benefits of enhancing incomplete training sets for classifier adaptation by simulated synthetic imagery. EADS/KDA identified the requirements of a commercial-off-the-shelf IR simulation tool capable of delivering appropriate synthetic imagery for ATR development. A market study of available IR simulation tools and suppliers was performed. After that the most promising tool was benchmarked according to several criteria e.g. thermal emission model, sensor model, targets model, non-radiometric image features etc., resulting in a

  16. THE ORION FINGERS: NEAR-IR SPECTRAL IMAGING OF AN EXPLOSIVE OUTFLOW

    Energy Technology Data Exchange (ETDEWEB)

    Youngblood, Allison; Bally, John [Department of Astrophysical and Planetary Sciences, University of Colorado, UCB 389, Boulder, CO 80309 (United States); Ginsburg, Adam, E-mail: allison.youngblood@colorado.edu [ESO Headquarters, Karl-Schwarzschild-Strasse 2, D-85748 Garching bei München (Germany)

    2016-06-01

    We present near-IR (1.1–2.4 μ m) position–position–velocity cubes of the 500 year old Orion BN/KL explosive outflow with spatial resolution 1″ and spectral resolution 86 km s{sup −1}. We construct integrated intensity maps free of continuum sources of 15 H{sub 2} and [Fe ii] lines while preserving kinematic information of individual outflow features. Included in the detected H{sub 2} lines are the 1-0 S(1) and 1-0 Q(3) transitions, allowing extinction measurements across the outflow. Additionally, we present dereddened flux ratios for over two dozen outflow features to allow for the characterization of the true excitation conditions of the BN/KL outflow. All of the ratios show the dominance of the shock excitation of the H{sub 2} emission, although some features exhibit signs of fluorescent excitation from stellar radiation or J-type shocks. We also detect tracers of the PDR/ionization front north of the Trapezium stars in [O i] and [Fe ii] and analyze other observed outflows not associated with the BN/KL outflow.

  17. SYNTHESIS OF POLYEUGENYL OXYACETIC ACID AS A CARRIER TO SEPARATE HEAVY METAL ION Fe (III, Cr(III, Cu(II, Ni(II, Co(II, AND Pb(II THAT USING SOLVENT EXTRACTION METHOD

    Directory of Open Access Journals (Sweden)

    La Harimu

    2010-06-01

    Full Text Available Polyeugenyl oxyacetic acid has been synthesized from polyeugenol and chloroacetic acid and applied to separate metal Fe(III, Cr(III, Cu(II, Ni(II, Co(II, and Pb(II using solvent extraction method. pH effect, polyeugenyl oxyacetic acid ion carrier concentration, extraction time, and metal concentration optimized to gain optimum condition. The result of experiment indicated that polyeugenyl oxyacetic acid resulted the yellowed brown synthesis with melting point 125 °C and yield 68.9%. The Characterization of spectroscopy IR attributed by absorption to the area 1735,8 cm -1 as carbonyl extend vibration (C=O acid and 1H-NMR that was attributed by chemical shift at 4.6 ppm as carboxy proton (CH2-C=0. The metal separation optimum condition gained pH 3-6 for ion Fe(III, pH 5 for ion Cr(III, Ni(II, and Co(II and pH 6 for ion Cu(II, and Pb(II. Optimum carrier concentraction 5 mL, 10 mL, and 15 mL for ion Fe(III, and ion Cr(III, Ni(II, Co(II, and ion Cu(II, Pb(II respectively. Extraction time 2.5 h for ion Fe(III, 20 h for ion Cr(III, and 36 h for ion Cu(II, Pb(II, Ni(II, and Co(II. Metal concentration that would extracted correctly (0.75-5 x 10-4 M for ion Fe(III, (0.75-2.5 x 10-4 M for ion Cr(III, Ni(II, and Co(II and (0.75-1 x 10-4 M for ion Cu(II and Pb(II. The best polyeugenil oxyacetic acid response to separate ion Fe(III than other ions with selectivity order Fe(III> Cr(III> Cu(II> Pb(II> Ni(II> Co(II.   Keywords: polyeugenil oxyacetic acid, pH, extraction time, metal concentraction, solvent extraction

  18. Synthesis and characterization of nickel(II), cobalt(II), copper(II), manganese(II), zinc(II), zirconium(IV), dioxouranium(VI) and dioxomolybdenum(VI) complexes of a new Schiff base derived from salicylaldehyde and 5-methylpyrazole-3-carbohydrazide

    International Nuclear Information System (INIS)

    Syamal, A.; Maurya, M.R.

    1986-01-01

    Synthesis of a new Schiff base derived from salicylaldehyde and 5-methylpyrazole-3-carbohydrazide, and its coordination compounds with nickel(II), cobalt(II), copper(II), manganese(II), zinc(II), zirconium(IV), dioxouranium(VI) and dioxomolybdenum(VI) are described. The ligand and the complexes have been characterized on the basis of analytical, conductance, molecular weight, i.r., electronic and n.m.r. spectra and magnetic susceptibility measurements. The stoichiometries of the complexes are represented as NiL . 3H 2 O, CoL . 2H 2 O, CuL, MnL . 2H 2 O, ZnL . H 2 O, Zr(OH) 2 (LH) 2 , Zr(OH) 2 L . 2MeOH, UO 2 L . MeOH and MoO 2 L . MeOH (where LH 2 =Schiff base). The copper(II) complex shows a subnormal magnetic moment due to antiferromagnetic exchange interaction while the nickel(II), cobalt(II) and manganese(II) complexes show normal magnetic moments at room temperature. The i.r. and n.m.r. spectral studies show that the Schiff base behaves as a dibasic and tridentate ligand coordinating through the deprotonated phenolic oxygen, enolic oxygen and azomethine nitrogen. (orig.)

  19. Metal oxide-coating PMMA or Talc as a new IR blocker inhibits IR-induced decrease of collagens in human dermal fibroblasts.

    Science.gov (United States)

    Nam, J-J; Lee, K-E; Kim, Y J

    2015-08-01

    The purpose of this study was whether P/M or T/M inhibits IR-induced decrease of collagens in human dermal fibroblasts, using P/M or T/M blocked near-IR (NIR) transmittance significantly in spectrophotometer measurement. As metal oxides are effective inorganic molecules for intercepting IR radiation, we have developed metal oxide-coating PMMA (P/M) or Talc (T/M) as a new IR blocker. Inhibitory effect of the new IR blocker on collagen degradation was measured by gene and protein expressions of procollagens and MMPs, respectively, in IR-irradiated Hs68 cell line. Using P/M or T/M inhibited IR-induced increases of MMP-1, MMP-3 and MMP-9, and IR-induced decreases of type 1 and 4 procollagen in a dose-dependent manner in dermal fibroblasts. In addition, using both P/M and T/M blocked the increase of cell media temperature induced by IR lamp. The results suggest that P/M or T/M can inhibit decrease of collagens by blocking IR-induced heat transmission in human dermal fibroblasts. © 2015 Society of Cosmetic Scientists and the Société Française de Cosmétologie.

  20. Isotope-Labeled Amyloids via Synthesis, Expression, and Chemical Ligation for Use in FTIR, 2D IR, and NMR Studies.

    Science.gov (United States)

    Zhang, Tianqi O; Grechko, Maksim; Moran, Sean D; Zanni, Martin T

    2016-01-01

    This chapter provides protocols for isotope-labeling the human islet amyloid polypeptide (hIAPP or amylin) involved in type II diabetes and γD-crystallin involved in cataract formation. Because isotope labeling improves the structural resolution, these protocols are useful for experiments using Fourier transform infrared (FTIR), two-dimensional infrared (2D IR), and NMR spectroscopies. Our research group specializes in using 2D IR spectroscopy and isotope labeling. 2D IR spectroscopy provides structural information by measuring solvation from 2D diagonal lineshapes and vibrational couplings from cross peaks. Infrared spectroscopy can be used to study kinetics, membrane proteins, and aggregated proteins. Isotope labeling provides greater certainty in the spectral assignment, which enables new structural insights that are difficult to obtain with other methods. For amylin, we provide a protocol for (13)C/(18)O labeling backbone carbonyls at one or more desired amino acids in order to obtain residue-specific structural resolution. We also provide a protocol for expressing and purifying amylin from E. coli, which enables uniform (13)C or (13)C/(15)N labeling. Uniform labeling is useful for measuring the monomer infrared spectrum in an amyloid oligomer or fiber as well as amyloid protein bound to another polypeptide or protein, such as a chaperone or an inhibitor. In addition, our expression protocol results in 2-2.5 mg of amylin peptide per 1 L cell culture, which is a high enough yield to straightforwardly obtain the 2-10 mg needed for high resolution and solid-state NMR experiments. Finally, we provide a protocol to isotope-label either of the two domains of γD-crystallin using expressed protein ligation. Domain labeling makes it possible to resolve the structures of the two halves of the protein in FTIR and 2D IR spectra. With modifications, these strategies and protocols for isotope labeling can be applied to other amyloid polypeptides and proteins.

  1. Plk1 phosphorylation of IRS2 prevents premature mitotic exit via AKT inactivation

    Science.gov (United States)

    Chen, Long; Li, Zhiguo; Ahmad, Nihal; Liu, Xiaoqi

    2016-01-01

    Insulin receptor substrate (IRS) proteins play important roles by acting as a platform in transducing signals from transmembrane receptors upon growth factor stimulation. Although tyrosine phosphorylation on IRS proteins plays critical roles in signal transduction, phosphorylation of IRS proteins on serine/threonine residues are believed to play various regulatory roles on IRS protein function. However, studies on serine/threonine phosphorylation of IRS proteins are very limited, especially for insulin receptor substrate 2 (IRS2), one member of the IRS protein family. In this study, we identify Polo-like kinase 1 (Plk1) as the responsible kinase for phosphorylation of IRS2 on two serine residues, Ser 556 and Ser 1098. Phosphorylation of IRS2 on these two serine residues by Plk1 prevents the activation of the PI3K pathway upon growth factor stimulation by inhibiting the binding between IRS2 and the PI3K pathway components and increasing IRS2 protein degradation. Of significance, we show that IRS2 phosphorylation is cell cycle regulated and that Plk1 phosphorylation of IRS2 prevents premature mitotic exit via AKT inactivation. PMID:25830382

  2. (Ir)reconcilable differences? The debate concerning nursing and technology.

    Science.gov (United States)

    Sandelowski, M

    1997-01-01

    To review and critique the debate concerning nursing and technology. Technology has been considered both at one and at odds with nursing. Mitcham's (1994) concepts of technological optimism and romanticism. Nursing literature since 1960. Historical analysis. Technological optimists in nursing have viewed technology as an extension of and as readily assimilable into humanistic nursing practice, and nursing as socially advantaged by technology. Technological romantics have viewed technology as irreconcilable with nursing culture, as an expression of masculine culture, and as recirculating existing gender and social inequalities. Both optimists and romantics essentialize technology and nursing, treating the two as singular and fixed entities. The (ir)reconcilability of nursing and technology may be a function of how devices are used by people in different contexts, or of the (ir)reconcilability of views of technology in nursing.

  3. IR OPTICS MEASUREMENT WITH LINEAR COUPLING'S ACTION-ANGLE PARAMETERIZATION

    International Nuclear Information System (INIS)

    LUO, Y.; BAI, M.; PILAT, R.; SATOGATA, T.; TRBOJEVIC, D.

    2005-01-01

    A parameterization of linear coupling in action-angle coordinates is convenient for analytical calculations and interpretation of turn-by-turn (TBT) beam position monitor (BPM) data. We demonstrate how to use this parameterization to extract the twiss and coupling parameters in interaction regions (IRs), using BPMs on each side of the long IR drift region. The example of TBT BPM analysis was acquired at the Relativistic Heavy Ion Collider (RHIC), using an AC dipole to excite a single eigenmode. Besides the full treatment, a fast estimate of beta*, the beta function at the interaction point (IP), is provided, along with the phase advance between these BPMs. We also calculate and measure the waist of the beta function and the local optics

  4. Mid-IR laser system for advanced neurosurgery

    Science.gov (United States)

    Klosner, M.; Wu, C.; Heller, D. F.

    2014-03-01

    We present work on a laser system operating in the near- and mid-IR spectral regions, having output characteristics designed to be optimal for cutting various tissue types. We provide a brief overview of laser-tissue interactions and the importance of controlling certain properties of the light beam. We describe the principle of operation of the laser system, which is generally based on a wavelength-tunable alexandrite laser oscillator/amplifier, and multiple Raman conversion stages. This configuration provides robust access to the mid-IR spectral region at wavelengths, pulse energies, pulse durations, and repetition rates that are attractive for neurosurgical applications. We summarize results for ultra-precise selective cutting of nerve sheaths and retinas with little collateral damage; this has applications in procedures such as optic-nerve-sheath fenestration and possible spinal repair. We also report results for cutting cornea, and dermal tissues.

  5. Laser welding parameters for manufacturing iridium-192 (Ir-192) source

    International Nuclear Information System (INIS)

    Anung Pujiyanto; Moch Subechi; Hotman Lubis; Diandono KY

    2013-01-01

    Number of cervical cancer patients in Indonesia is growing every year. One of cervical cancer treatment was fairly effective use brachytherapy treatment with radioisotope sources of iridium-192. Manufacturing of iridium sources for brachytherapy can be done by incorporating the iridium-192 into stainless steel microcapsules then welding using laser welder which the quality of the welding of iridium source (Ir-192) was determined by the welding parameters such as full power, energy frequency, average power and speed. Based on the result of leakage test using pressure -20 inch Hg and tensile test 2.5 bar showed the welding parameters III and IV did not have leakage and damaged. So that parameters III and IV are recommended to be applied to Ir-192 HDR's source. (author)

  6. Photothermal IR spectroscopy with perforated membrane micromechanical resonators

    DEFF Research Database (Denmark)

    Kurek, Maksymilian

    wavelength corresponding to its specific molecular vibrations. This thermal energy heats the resonator and leads to its thermal expansion followed by a decrease of the tensile stress in the resonator. In turn it eventually causes the resonance frequency to shift towards lower values. However, further...... development of this approach was curbed by difficult and inefficient coupling of the IR light beam to a nanometer-sized resonator. In addition, readout of vibration was done by laser Doppler vibrometer, a precise but bulky and expensive instrument. These issues hindered a realworld application of the NAM......-IR method. In order to overcome them, string resonators were replaced by membranes. A reliable sampling technique was maintained by adding perforation to membranes and thereby essentially getting membrane porous filters. Membranes gave also access to fully integrated magnetic transduction that allowed...

  7. Photonics in nature: Yellowstone National Park in IR

    Science.gov (United States)

    Vollmer, Michael; Shaw, Joseph A.; Nugent, Paul W.; Harris, Wilson; Gillis, Kendra; Weiss, William; Carpenter, Logan; Carpenter, Amy; Scherrer, Bryan

    2017-08-01

    Infrared thermal imaging is a valuable tool not only in science but also in optics and photonics education and outreach activities. Observing natural optical phenomena in a different spectral region like the thermal infrared often offers new insights. The commonly used false color images not only allow extraction of useful information about thermal properties of objects, but they can also provide aesthetic sights and are thus an excellent tool for public outreach activities. Recently we have pursued this kind of study using IR imaging within Yellowstone National Park, complementing earlier work on thermal pool colors and spectroscopy. We will discuss and compare images of a variety of VIS and IR cameras of hot springs, geysers, mud pools and other natural phenomena recorded in the park during 2012 and 2016.

  8. IR-ATR investigation of surface anisotropy in silicate glasses

    Science.gov (United States)

    Ivanovski, Vladimir; Mayerhöfer, Thomas G.; Kriltz, Antje; Popp, Jürgen

    2017-02-01

    Several samples of flat soda-lime silicate glass were investigated by the Infrared Attenuated Total Reflection (IR-ATR) spectroscopy technique. The specular reflectance spectra together with the results of the performed dispersion analysis and the generated reflectance spectra, using Fresnel equations, suggest that the samples are isotropic. In contrast, spectra recorded by the ATR technique suggest an anisotropic structure on the surface of the specimen different from that in the bulk. This is established through differences in the s- and p-polarized IR-ATR spectra, which cannot be simply transformed into one another employing Fresnel formula for an isotropic case. It appears that this thin film having a structure different from the bulk is larger than the ATR effective penetration depth of the evanescent ray for each incidence angle above the critical one. The investigation suggests C2 symmetry of the SiO4 unit.

  9. Applications of FT-IR spectrophotometry in cancer diagnostics.

    Science.gov (United States)

    Bunaciu, Andrei A; Hoang, Vu Dang; Aboul-Enein, Hassan Y

    2015-01-01

    This review provides a brief background to the application of infrared spectroscopy, including Fourier transform-infrared spectroscopy, in biological fluids. It is not meant to be complete or exhaustive but to provide the reader with sufficient background for selected applications in cancer diagnostics. Fourier transform-infrared spectroscopy (FT-IR) is a fast and nondestructive analytical method. The infrared spectrum of a mixture serves as the basis to quantitate its constituents, and a number of common clinical chemistry tests have proven to be feasible using this approach. This review focuses on biomedical FT-IR applications, published in the period 2009-2013, used for early detection of cancer through qualitative and quantitative analysis.

  10. Thermal IR exitance model of a plant canopy

    Science.gov (United States)

    Kimes, D. S.; Smith, J. A.; Link, L. E.

    1981-01-01

    A thermal IR exitance model of a plant canopy based on a mathematical abstraction of three horizontal layers of vegetation was developed. Canopy geometry within each layer is quantitatively described by the foliage and branch orientation distributions and number density. Given this geometric information for each layer and the driving meteorological variables, a system of energy budget equations was determined and solved for average layer temperatures. These estimated layer temperatures, together with the angular distributions of radiating elements, were used to calculate the emitted thermal IR radiation as a function of view angle above the canopy. The model was applied to a lodgepole pine (Pinus contorta) canopy over a diurnal cycle. Simulated vs measured radiometric average temperatures of the midcanopy layer corresponded with 2 C. Simulation results suggested that canopy geometry can significantly influence the effective radiant temperature recorded at varying sensor view angles.

  11. Vibrational microspectroscopy of food. Raman vs. FT-IR

    DEFF Research Database (Denmark)

    Thygesen, Lisbeth Garbrecht; Løkke, Mette Marie; Micklander, Elisabeth

    2003-01-01

    FT-IR and Raman spectroscopy are complementary techniques for the study of molecular vibrations and structure. The combination with a microscope results in an analytical method that allows spatially resolved investigation of the chemical composition of heterogeneous foods and food ingredients...... to different heterogeneous food systems. FT-IR and Raman microspectroscopy were applied to a number of different problems related to food analysis: (1) in situ determination of starch and pectin in the potato cell, (2) in situ determination of the distribution of amygdalin in bitter almonds, (3......) the composition of blisters found on the surface of bread, (4) the microstructure of high-lysine barley and (5) the composition of white spots in the shell of frozen shrimps. (C) 2003 Elsevier Science Ltd. All rights reserved....

  12. IR-laser assisted additive freeform optics manufacturing.

    Science.gov (United States)

    Hong, Zhihan; Liang, Rongguang

    2017-08-02

    Computer-controlled additive manufacturing (AM) processes, also known as three-dimensional (3D) printing, create 3D objects by the successive adding of a material or materials. While there have been tremendous developments in AM, the 3D printing of optics is lagging due to the limits in materials and tight requirements for optical applicaitons. We propose a new precision additive freeform optics manufacturing (AFOM) method using an pulsed infrared (IR) laser. Compared to ultraviolet (UV) curable materials, thermally curable optical silicones have a number of advantages, such as strong UV stability, non-yellowing, and high transmission, making it particularly suitable for optical applications. Pulsed IR laser radiation offers a distinct advantage in processing optical silicones, as the high peak intensity achieved in the focal region allows for curing the material quickly, while the brief duration of the laser-material interaction creates a negligible heat-affected zone.

  13. Divertor IR thermography on Alcator C-Moda)

    Science.gov (United States)

    Terry, J. L.; LaBombard, B.; Brunner, D.; Payne, J.; Wurden, G. A.

    2010-10-01

    Alcator C-Mod is a particularly challenging environment for thermography. It presents issues that will similarly face ITER, including low-emissivity metal targets, low-Z surface films, and closed divertor geometry. In order to make measurements of the incident divertor heat flux using IR thermography, the C-Mod divertor has been modified and instrumented. A 6° toroidal sector has been given a 2° toroidal ramp in order to eliminate magnetic field-line shadowing by imperfectly aligned divertor tiles. This sector is viewed from above by a toroidally displaced IR camera and is instrumented with thermocouples and calorimeters. The camera provides time histories of surface temperatures that are used to compute incident heat-flux profiles. The camera sensitivity is calibrated in situ using the embedded thermocouples, thus correcting for changes and nonuniformities in surface emissivity due to surface coatings.

  14. IR-stimulated visible fluorescence in pink and brown diamond

    International Nuclear Information System (INIS)

    Byrne, K S; Luiten, A N; Chapman, J G

    2014-01-01

    Irradiation of natural pink and brown diamond by middle-ultraviolet light (photon energy ϵ ≥ 4.1 eV ) is seen to induce anomalous fluorescence phenomena at N3 defect centres (structure N 3 −V). When diamonds primed in this fashion are subsequently exposed to infrared light (even with a delay of many hours), a transient burst of blue N3 fluorescence is observed. The dependence of this IR-triggered fluorescence on pump wavelength and intensity suggest that this fluorescence phenomena is intrinsically related to pink diamond photochromism. An energy transfer process between N3 defects and other defect species can account for both the UV-induced fluorescence intensity changes, and the apparent optical upconversion of IR light. From this standpoint, we consider the implications of this N3 fluorescence behaviour for the current understanding of pink diamond photochromism kinetics. (paper)

  15. and ni(ii)

    African Journals Online (AJOL)

    userpc

    NI(II) COMPLEXES WITH SCHIFF BASE DERIVED FROM SULPHANILAMINE AND. SALICYLALDEHYDE. ⃰Siraj, I. T. and ... with nickel(II) and cobalt(II) chloride in 2:1 mole ratio yielded Ni(II) and Co(II) complexes respectively. The synthesized .... coordinated ligand (coordination number) was determined using the relation ...

  16. Synthesis and characterisation of Cu (II), Ni (II), Mn (II), Zn (II) and ...

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences; Volume 113; Issue 3. Synthesis and characterisation of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) Schiff base complexes derived from o-phenylenediamine and acetoacetanilide. N Raman Y Pitchaikani Raja A Kulandaisamy. Inorganic Volume 113 Issue 3 June 2001 pp 183-189 ...

  17. Laser Spark Formamide Decomposition Studied by FT-IR Spectroscopy

    Czech Academy of Sciences Publication Activity Database

    Ferus, Martin; Kubelík, Petr; Civiš, Svatopluk

    2011-01-01

    Roč. 115, č. 44 (2011), s. 12132-12141 ISSN 1089-5639 R&D Projects: GA AV ČR IAA400400705; GA AV ČR IAAX00100903; GA ČR GAP208/10/2302 Institutional research plan: CEZ:AV0Z40400503 Keywords : FT-IR spectroscopy * high-power laser * induced dielectric-breakdown Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.946, year: 2011

  18. US-LARP progress on LHC IR upgrades

    CERN Document Server

    Sen, Tanaji; Mokhov, Nikolai; Fischer, Wolfram; Gupta, Ramesh; Qiang, Ji

    2006-01-01

    We review the progress on LHC IR upgrades made by the US-LARP collaboration since the last CARE meeting in November 2004. We introduce a new optics design with doublet focusing, and discuss energy deposition calculations with an open mid-plane dipole. We present the results of a beam-beam experiment at RHIC. This experiment was the first phase of a planned test of the wire compensation principle at RHIC.

  19. MTF measurement of IR optics in different temperature ranges

    Science.gov (United States)

    Bai, Alexander; Duncker, Hannes; Dumitrescu, Eugen

    2017-10-01

    Infrared (IR) optical systems are at the core of many military, civilian and manufacturing applications and perform mission critical functions. To reliably fulfill the demanding requirements imposed on today's high performance IR optics, highly accurate, reproducible and fast lens testing is of crucial importance. Testing the optical performance within different temperature ranges becomes key in many military applications. Due to highly complex IR-Applications in the fields of aerospace, military and automotive industries, MTF Measurement under realistic environmental conditions become more and more relevant. A Modulation Transfer Function (MTF) test bench with an integrated thermal chamber allows measuring several sample sizes in a temperature range from -40 °C to +120°C. To reach reliable measurement results under these difficult conditions, a specially developed temperature stable design including an insulating vacuum are used. The main function of this instrument is the measurement of the MTF both on- and off-axis at up to +/-70° field angle, as well as measurement of effective focal length, flange focal length and distortion. The vertical configuration of the system guarantees a small overall footprint. By integrating a high-resolution IR camera with focal plane array (FPA) in the detection unit, time consuming measurement procedures such as scanning slit with liquid nitrogen cooled detectors can be avoided. The specified absolute accuracy of +/- 3% MTF is validated using internationally traceable reference optics. Together with a complete and intuitive software solution, this makes the instrument a turn-key device for today's state-of- the-art optical testing.

  20. IR Spectra and Bond Energies Computed Using DFT

    Science.gov (United States)

    Bauschlicher, Charles; Andrews, Lester; Arnold, James (Technical Monitor)

    2000-01-01

    The combination of density functional theory (DFT) frequencies and infrared (IR) intensities and experimental spectra is a very powerful tool in the identification of molecules and ions. The computed and measured isotopic ratios make the identification much more secure than frequencies and intensities alone. This will be illustrated using several examples, such as Mn(CO)n and Mn(CO)n-. The accuracy of DFT metal-ligand bond energies will also be discussed.

  1. IR Camera Report for the 7 Day Production Test

    Energy Technology Data Exchange (ETDEWEB)

    Holloway, Michael Andrew [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-02-22

    The following report gives a summary of the IR camera performance results and data for the 7 day production run that occurred from 10 Sep 2015 thru 16 Sep 2015. During this production run our goal was to see how well the camera performed its task of monitoring the target window temperature with our improved alignment procedure and emissivity measurements. We also wanted to see if the increased shielding would be effective in protecting the camera from damage and failure.

  2. Adsorbed or intercalated: Na on graphene/Ir(111)

    Science.gov (United States)

    Pervan, Petar; Lazić, Predrag

    2017-09-01

    Interaction of sodium with graphene (Gr) on Ir(111) was studied with the aim to resolve the issue of Na adsorption/intercalation kinetics. The system Na/Gr/Ir(111) was studied by means of angle-resolved photoemission spectroscopy, low-energy electron diffraction, and ab initio density functional theory (DFT) calculation. It has been found that at room temperature (RT) and low concentrations Na is dominantly adsorbed on graphene. At higher concentrations, an intercalation process sets in so that it is possible to observe the coexistence of these two states. Eventually, all Na atoms are found in the intercalated state as determined by exposure to oxygen. While adsorption of Na on graphene already intercalated by Na [Na/Gr/Na/Ir(111) system] at RT was not possible, we could observe Li adsorption through the increase of Dirac point binding energy. Li coadsorption strongly affects the binding energy of the iridium surface state as well. This finding was supported by DFT calculations of adsorption energy of Na and Li on bare and fully Na intercalated graphene.

  3. Structure and linear spectroscopic properties of near IR polymethine dyes

    International Nuclear Information System (INIS)

    Webster, Scott; Padilha, Lazaro A.; Hu Honghua; Przhonska, Olga V.; Hagan, David J.; Van Stryland, Eric W.; Bondar, Mikhail V.; Davydenko, Iryna G.; Slominsky, Yuriy L.; Kachkovski, Alexei D.

    2008-01-01

    We performed a detailed experimental investigation and quantum-chemical analysis of a new series of near IR polymethine dyes with 5-butyl-7,8-dihydrobenzo[cd]furo[2,3-f]indolium terminal groups. We also synthesized and studied two neutral dyes, squaraine and tetraone, with the same terminal groups and performed a comparison of the spectroscopic properties of this set of 'near IR' dyes (polymethine, squaraine, and tetraone) with an analogous set of 'visible' dyes with simpler benzo[e]indolium terminal groups. From these measurements, we find that the dyes with dihydrobenzo[cd]furo[2,3-f]indolium terminal groups are characterized by a remarkably large shift ∼300 nm (∼200 nm for tetraone) of their absorption bands towards the red region. We discuss the difference in electronic structure for these molecules and show that the 'near IR' dyes are characterized by an additional weak fluorescence band from the higher lying excited states connected with the terminal groups. Absorption spectra for the longest polymethines are solvent-dependent and are characterized by a broadening of the main band in polar solvents, which is explained by ground state symmetry breaking and reduced charge delocalization within the polymethine chromophore. The results of these experiments combined with the agreement of quantum chemical calculations moves us closer to a predictive capability for structure-property relations in cyanine-like molecules

  4. Power-Law Template for IR Point Source Clustering

    Science.gov (United States)

    Addison, Graeme E.; Dunkley, Joanna; Hajian, Amir; Viero, Marco; Bond, J. Richard; Das, Sudeep; Devlin, Mark; Halpern, Mark; Hincks, Adam; Hlozek, Renee; hide

    2011-01-01

    We perform a combined fit to angular power spectra of unresolved infrared (IR) point sources from the Planck satellite (at 217,353,545 and 857 GHz, over angular scales 100 law of the form C_l\\propto I(sup -n) with n = 1.25 +/- 0.06. While the IR sources are understood to lie at a range of redshifts, with a variety of dust properties, we find that the frequency dependence of the clustering power can be described by the square of a modified blackbody, nu(sup beta) B(nu,T_eff), with a single emissivity index beta = 2.20 +/- 0.07 and effective temperature T_eff= 9.7 K. Our predictions for the clustering amplitude are consistent with existing ACT and South Pole Telescope results at around 150 and 220 GHz, as is our prediction for the effective dust spectral index, which we find to be alpha_150-220 = 3.68 +/- 0.07 between 150 and 220 GHz. Our constraints on the clustering shape and frequency dependence can be used to model the IR clustering as a contaminant in Cosmic Microwave Background anisotropy measurements. The combined Planck and BLAST data also rule out a linear bias clustering model.

  5. Revenue Potential for Inpatient IR Consultation Services: A Financial Model.

    Science.gov (United States)

    Misono, Alexander S; Mueller, Peter R; Hirsch, Joshua A; Sheridan, Robert M; Siddiqi, Assad U; Liu, Raymond W

    2016-05-01

    Interventional radiology (IR) has historically failed to fully capture the value of evaluation and management services in the inpatient setting. Understanding financial benefits of a formally incorporated billing discipline may yield meaningful insights for interventional practices. A revenue modeling tool was created deploying standard financial modeling techniques, including sensitivity and scenario analyses. Sensitivity analysis calculates revenue fluctuation related to dynamic adjustment of discrete variables. In scenario analysis, possible future scenarios as well as revenue potential of different-size clinical practices are modeled. Assuming a hypothetical inpatient IR consultation service with a daily patient census of 35 patients and two new consults per day, the model estimates annual charges of $2.3 million and collected revenue of $390,000. Revenues are most sensitive to provider billing documentation rates and patient volume. A range of realistic scenarios-from cautious to optimistic-results in a range of annual charges of $1.8 million to $2.7 million and a collected revenue range of $241,000 to $601,000. Even a small practice with a daily patient census of 5 and 0.20 new consults per day may expect annual charges of $320,000 and collected revenue of $55,000. A financial revenue modeling tool is a powerful adjunct in understanding economics of an inpatient IR consultation service. Sensitivity and scenario analyses demonstrate a wide range of revenue potential and uncover levers for financial optimization. Copyright © 2016 SIR. Published by Elsevier Inc. All rights reserved.

  6. Electromagnetic properties of 181Ir: Evidence of β-stretching?

    International Nuclear Information System (INIS)

    Garg, U.; Reviol, W.; Semmes, P.

    1991-01-01

    We have calculated the B(Ml)/B(E2) ratios in 18l Ir within a shape-fixed particle + rotor model, in order to investigate how sensitive these may be to the nuclear shapes under consideration, and whether or not there is evidence of shape coexistence in the electromagnetic data alone. The model calculations employed the same Woods-Saxon potential that has been used previously for TRS and bandhead calculations and all parameters have been taken at their standard values, without any adjustments. To the extent possible with present models, these calculations should represent predictions for the B(M1)/B(E2) ratios at the deformations expected from the TRS and bandhead calculations. A comparison with the 181 Ir data is stimulated by the fact that this is the lightest-mass Ir nucleus for which the spins and parities am firmly established experimentally; we find that the electromagnetic transition rates in this nucleus are well reproduced under the assumption of a single, fixed shape

  7. A multistage target tracker in IR image sequences

    Science.gov (United States)

    Huang, Qiao; Yang, Jie

    2014-07-01

    In this paper, we propose a robust approach for tracking target in forward looking infrared imagery taken from an airborne moving platform. The tracker is proposed in a two stage algorithm with a coarse to fine manner. First, we introduce a coarse but quick algorithm to roughly locate the target, which based on a model matching procedure by computing the SIFT vector of the target. The raw position and the size of the target are then used to initialize the multistage tracking algorithm. Second, the target's position is refined through a dedicated localization algorithm, which based on a HOG feature tracking procedure to overcome the rapid size and angel changes of the dim target in the IR image sequence. Finally, the target's model can automatically been updated and utilized in the first stage. As confirmed by experimental results on a variety of IR image sequences, the proposed approach efficiently and robustly tracks target under challenging environmental conditions. Moreover, the speed of the multistage algorithm is also convincing in the tested IR imagery.

  8. The IR Sector – Opening new horizons for CERN

    CERN Multimedia

    2016-01-01

    Last week saw the CERN family grow by one, as we welcomed Cyprus as an Associate Member in the pre-stage to Membership. This gives me a good opportunity, three months into the job, to share the vision for the new International Relations (IR) Sector. CERN is and always has been an incredible example of successful, inclusive international collaboration and exchange in the pursuit of common goals. The IR Sector continues and builds on that tradition and spirit.   In the 60-plus years of CERN’s existence, our world has been transformed at all levels. And over the last decade or so, the world of particle physics has evolved beyond recognition. CERN is now a global lab, with a European core, and particle physics is a field that is increasingly planned and coordinated around the world. It is for these reasons that CERN needs to develop its International Relations so we can respond to and navigate these changes. The establishment by the Director-General of the IR Sector is a sign of her commitm...

  9. Near-IR Explorations of Buried AGN in Advanced Mergers

    Science.gov (United States)

    Ferguson, Jason; Constantin, Anca; Satyapal, Shobita; Rothberg, Barry

    2018-01-01

    Close separation dual AGNs provide unambiguous confirmation of ongoing mergers where the black holes experience their most rapid growth. Most of these systems have been discovered serendipitously, and confirmed cases remain, however, extremely rare. We present here the results of the analysis of new near-IR spectroscopy of nine advanced merger systems that display mid-IR colors suggestive of AGNs while lacking signatures of activity in the optical. Using the Large Binocular Telescope's LUCI (LBT Utility Camera for Infrared) 1 & 2 spectrographs we confirm the presence of broadened and/or high-excitation lines indicative of powerful AGN, reveal signs of hidden AGN feedback in the form of kinematic outflows, measure the properties of the host stellar populations, and begin to probe the gas-metallicities in these systems. Our results yield critical evidence that the epoch of peak black hole growth in mergers occurs in a highly obscured phase, consistent with theoretical predictions. We also confirm the effectiveness of using mid-IR colors as a pre-selection technique to identify dual AGN systems. This is one of the first detailed investigations into the physical environment of optically obscured dual AGNs, and provides key indications for finding and characterizing elusive black hole accretion.

  10. Anisotropic Magnetoresistance in Antiferromagnetic Sr_{2}IrO_{4}

    Directory of Open Access Journals (Sweden)

    C. Wang

    2014-11-01

    Full Text Available We report point-contact measurements of anisotropic magnetoresistance (AMR in a single crystal of antiferromagnetic Mott insulator Sr_{2}IrO_{4}. The point-contact technique is used here as a local probe of magnetotransport properties on the nanoscale. The measurements at liquid nitrogen temperature reveal negative magnetoresistances (up to 28% for modest magnetic fields (250 mT applied within the IrO_{2} a-b plane and electric currents flowing perpendicular to the plane. The angular dependence of magnetoresistance shows a crossover from fourfold to twofold symmetry in response to an increasing magnetic field with angular variations in resistance from 1% to 14%. We tentatively attribute the fourfold symmetry to the crystalline component of AMR and the field-induced transition to the effects of applied field on the canting of antiferromagnetic-coupled moments in Sr_{2}IrO_{4}. The observed AMR is very large compared to the crystalline AMRs in 3d transition metal alloys or oxides (0.1%–0.5% and can be associated with the large spin-orbit interactions in this 5d oxide while the transition provides evidence of correlations between electronic transport, magnetic order, and orbital states. The finding of this work opens an entirely new avenue to not only gain a new insight into physics associated with spin-orbit coupling but also to better harness the power of spintronics in a more technically favorable fashion.

  11. Media handling for visual information retrieval in VizIR

    Science.gov (United States)

    Eidenberger, Horst

    2003-06-01

    This paper describes how the handling of visual media objects is implemented in the visual information retrieval project VizIR. Essentially, four areas are concerned: media access, media representation in user interfaces, visualisation of media-related data and media transport over the network. The paper offers detailed technical descriptions of the solutions developed in VizIR for these areas. Unified media access for images and video is implemented through class MediaContent. This class contains methods to access the view on a media object at any point in time as well as methods to change the colour model and read/write format parameters (size, length, frame-rate). Based on this low-level-API class VisualCube allows accessing spatio-temporal areas in temporal media randomly. Transformer-classes allow to modify visual objects in a very simple but effective way. Visualisation of media object is implemented in class MediaRenderer. Each MediaRenderer represents one media object and is responsible for any aspect of its visualisation. In the paper examples for reasonable implementations of MediaRenderer-classes are presented. Visualisation of media-related data is strongly connected to MediaRenderer. MediaRenderer is to a large extent responsible for displaying visual panels created by other framework components. Finally, media object transport in VizIR is based on the Realtime Transfer Protocol (for media objects) and XML-messaging (for XML-data).

  12. Synthesis and characterization of a tetraaza macrocyclic ligand and its cobalt(II, nickel(II and copper(II complexes

    Directory of Open Access Journals (Sweden)

    SULEKH CHANDR

    2010-07-01

    Full Text Available Co(II, Ni(II, and Cu(II complexes with a tetradentate nitrogen donor [N4] macrocyclic ligand, viz. 6,15-dimethyl-8,17diphenyl-7,16-dihydrodibenzo[b,i][1.4.8.11]tetraazacyclotetradecine, were synthesized. Their structures were determined based on elemental analyses, molar conductance and magnetic susceptibility measurements, and IR, 1H-NMR (ligand and electronic spectral studies. Based on analytical and molar conductance data, the complexes may be formulated as [M(LCl2] and [M’(L]Cl2 (where M = Co(II and Cu(II, and M’ = Ni(II due to their non-electrolytic and 1:2 electrolytic nature. Based on spectral studies, an octahedral geometry was assigned for the Co(II complex, whereas square-planar and tetragonal geometry were proposed for the Ni(II and Cu(II complexes, respectively. The synthesized ligand and its complexes were screened for fungicidal activity against two pathogenic fungi (i.e., Fusarium moniliformae and Rhizoctonia solani to assess their growth inhibiting potential.

  13. Synthesis, characterization, DFT and biological studies of isatinpicolinohydrazone and its Zn(II), Cd(II) and Hg(II) complexes

    Science.gov (United States)

    El-Gammal, O. A.; Rakha, T. H.; Metwally, H. M.; Abu El-Reash, G. M.

    2014-06-01

    Isatinpicolinohydrazone (H2IPH) and its Zn(II), Cd(II) and Hg(II) complexes have been synthesized and investigated using physicochemical techniques viz. IR, 1H NMR, 13C NMR, UV-Vis spectrometric methods and magnetic moment measurements. The investigation revealed that H2IPH acts as binegative tetradentate in Zn(II), neutral tridentate in Cd(II) and as neutral bidentate towards Hg(II) complex. Octahedral geometry is proposed for all complexes. The bond length, bond angle, chemical reactivity, energy components (kcal/mol), binding energy (kcal/mol) and dipole moment (Debyes) for all the title compounds were evaluated by DFT and also MEP for the ligand is shown. Theoretical infrared intensities of H2IPH and also the theoretical electronic spectra of the ligand and its complexes were calculated. The thermal behavior and the kinetic parameters of degradation were determined using Coats-Redfern and Horowitz-Metzger methods. The in vitro antibacterial studies of the complexes proved them as growth inhibiting agents. The DDPH antioxidant of the compounds have been screened. Antitumor activity, carried out in vitro on human mammary gland (breast) MCF7, have shown that Hg(II) complex exhibited potent activity followed by Zn(II), Cd(II) complexes and the ligand.

  14. Synthesis and characterization of VO(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes of chromone based azo-linked Schiff base ligand.

    Science.gov (United States)

    Anitha, C; Sheela, C D; Tharmaraj, P; Johnson Raja, S

    2012-12-01

    Azo-Schiff-base complexes of VO(II), Co(II), Ni(II), Cu(II) and Zn(II) have been synthesized and characterized by elemental analysis, IR, UV-Vis, (1)H NMR, mass spectra, molar conductance, magnetic susceptibility measurement, electron spin resonance (EPR), CV, fluorescence, NLO and SEM. The conductance data indicate the nonelectrolytic nature of the complexes, except VO(II) complex which is electrolytic in nature. On the basis of electronic spectra and magnetic susceptibility octahedral geometry has been proposed for the complexes. The EPR spectra of copper and oxovanadium complexes in DMSO at 300 and 77K were recorded and its salient features are reported. The redox behavior of the copper(II) complex was studied using cyclic voltammetry. The in vitro antimicrobial activity against Staphylococcus aureus, Escherichia coli, Salmonella enterica typhi, Bacillus subtilis and Candida strains was studied and compared with that of free ligand by well-diffusion technique. The azo Schiff base exhibited fluorescence properties originating from intraligand (π-π(*)) transitions and metal-mediated enhancement is observed on complexation and so the synthesized complexes can serve as potential photoactive materials as indicated from their characteristic fluorescence properties. On the basis of the optimized structures, the second-order nonlinear optical properties (NLO) are calculated by using second-harmonic generation (SHG) and also the surface morphology of the complexes was studied by SEM. Copyright © 2012 Elsevier B.V. All rights reserved.

  15. Preparation and Spectral Properties of Mixed-Ligand Complexes of VO(IV, Ni(II, Zn(II, Pd(II, Cd(II and Pb(II with Dimethylglyoxime and N-acetylglycine

    Directory of Open Access Journals (Sweden)

    Shayma A. Shaker

    2010-01-01

    Full Text Available A number of mixed-ligand complexes of the general formula [M(D(G] where D=dimethylglyoximato monoanion, G=N-acetylglycinato and M=VO(IV, Ni(II, Zn(II, Pd(II, Cd(II and Pb(II were prepared. Each complex was characterized by elemental analysis, determination of metal, infrared spectra, electronic spectra, (1H and 13C NMR spectra, conductivity and magnetic moments. All these complexes were not soluble in some of the organic solvent but highly soluble in dimethylformamide. The conductivity data showed the non-electrolytic nature of the complexes. The electronic spectra exhibited absorption bands in the visible region caused by the d-d electronic transition such as VO(IV, Ni(II and Pd(II. The IR and (1H, 13C NMR spectra which have indicate that the dimethylglyoxime was coordinated with the metal ions through the N and O atoms of the oxime group and N-acetylglycine was coordinated with metal ions through the N atom and terminal carboxyl oxygen atom.

  16. Mid-IR Properties of an Unbiased AGN Sample of the Local Universe. 1; Emission-Line Diagnostics

    Science.gov (United States)

    Weaver, K. A.; Melendez, M.; Muhotzky, R. F.; Kraemer, S.; Engle, K.; Malumuth. E.; Tueller, J.; Markwardt, C.; Berghea, C. T.; Dudik, R. P.; hide

    2010-01-01

    \\Ve compare mid-IR emission-lines properties, from high-resolution Spitzer IRS spectra of a statistically-complete hard X-ray (14-195 keV) selected sample of nearby (z < 0.05) AGN detected by the Burst Alert Telescope (BAT) aboard Swift. The luminosity distribution for the mid-infrared emission-lines, [O IV] 25.89 microns, [Ne II] 12.81 microns, [Ne III] 15.56 microns and [Ne V] 14.32 microns, and hard X-ray continuum show no differences between Seyfert 1 and Seyfert 2 populations, although six newly discovered BAT AGNs are shown to be under-luminous in [O IV], most likely the result of dust extinction in the host galaxy. The overall tightness of the mid-infrared correlations and BAT luminosities suggests that the emission lines primarily arise in gas ionized by the AGN. We also compared the mid-IR emission-lines in the BAT AGNs with those from published studies of star-forming galaxies and LINERs. We found that the BAT AGN fall into a distinctive region when comparing the [Ne III]/[Ne II] and the [O IV]/[Ne III] quantities. From this we found that sources that have been previously classified in the mid-infrared/optical as AGN have smaller emission line ratios than those found for the BAT AGNs, suggesting that, in our X-ray selected sample, the AGN represents the main contribution to the observed line emission. Overall, we present a different set of emission line diagnostics to distinguish between AGN and star forming galaxies that can be used as a tool to find new AGN.

  17. Will IR Staff Stick? An Exploration of Institutional Researchers' Intention to Remain in or Leave Their Jobs

    Science.gov (United States)

    Knight, William E.; Leimer, Christina L.

    2010-01-01

    The study explored the factors that relate to the likelihood of institutional researchers (IRs) to plan to leave their jobs. Learning more about the effects on IR job turnover can serve to improve the employment experience of IR practitioners, the profession of IR, and, indirectly, higher education. 1,264 IRs responded to a national survey…

  18. Tax Administration: IRS's Innocent Spouse Program Performance Improved; Balanced Performance Measures Needed

    National Research Council Canada - National Science Library

    2002-01-01

    .... Under the Internal Revenue Services (IRS) Innocent Spouse Program, IRS can relieve taxpayers of tax debts on the basis of equity considerations, such as not knowing that their spouse failed to pay taxes due...

  19. Tax Administration: Information on Selected IRS Tax Enforcement and Collection Efforts

    National Research Council Canada - National Science Library

    2001-01-01

    ...) in enforcing the nation's tax laws. These two topics will be discussed: (1) the relationship between IRS audits of taxpayers and other programs IRS uses to ensure that taxpayers returns are accurate, and (2...

  20. Detectors with Improved Near-to-Mid IR Performance and Reduced Cooling Requirements, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — This STTR Phase I proposal addresses a NASA need for improved near-to-mid IR detectors for imaging and spectroscopy. High performance IR detectors with cutoff...

  1. Statewide implementation of Pave-IR in the Texas Department of Transportation.

    Science.gov (United States)

    2012-02-01

    This project conducted work to complement implementation of Pave-IR into the Texas Department of : Transportations hot-mix-asphalt quality control/quality assurance specification. Pave-IR provides real-time : thermal profiling of paving operations...

  2. The use of IAEA-IRS information in Russia's nuclear power industry

    International Nuclear Information System (INIS)

    1996-01-01

    The use of IAEA-IRS information in Russia's nuclear power industry is described, including the following issues: organizational aspects; organization of the information process; assessment of information uses; examples of using IAEA-IRS information. Figs

  3. Tax Administration: IRS Should Evaluate the Changes to Its Offer in Compromise Program

    National Research Council Canada - National Science Library

    2002-01-01

    ...), the demand for offers has increased significantly. Even though IRS added staff to the program, the inventory of unresolved offers and the processing times have grown. IRS now takes about 10 months, on average, to make an offer determination.

  4. Facile Pd(II)- and Ni(II)-Catalyzed Isomerization of Terminal Alkenes into 2-Alkenes

    Science.gov (United States)

    Lim, Hwan Jung; Smith, Craig R.; RajanBabu, T. V.

    2009-01-01

    Mono- and 2,2′-di-substituted terminal alkenes can be isomerized into the more stable internal Z- and E- alkenes by treating them with catalytic amounts of [(allyl)PdCl]2 or [(allyl)NiBr]2, a triarylphosphine and silver triflate at room temperature. The isomeric ratio (E:Z) depends on the alkenes, the (E)-isomer being the major one. The reaction is tolerant to a wide variety of functional groups including other reactive olefins. Unlike the more reactive Ir catalysts, monosubstituted alkenes give almost exclusively the 2-alkenes. Direct comparison to two of the best-known catalysts for this process, (Ir(PCy3)3]+ [BPh4]−, and Grubbs Generation II metathesis catalyst) is also reported. PMID:19441793

  5. Spectroscopic characterization of chromium(III), manganese(II) and nickel(II) complexes with a nitrogen donor tetradentate, 12-membered azamacrocyclic ligand

    Science.gov (United States)

    Chandra, Sulekh; Pundir, Meenakshi

    2008-01-01

    The complexes of Cr(III), Mn(II) and Ni(II) were synthesized with macrocyclic ligand i.e. 5,11-dimethyl-6,12-diethyl-dione-1,2,4,7,9,10-hexazacyclododeca -1,4,6,10-tetraene. The ligand (L) was prepared by [2 + 2] condensation reaction of 2,3-pentanedione and semicarbazide hydrochloride. These complexes were found to have the general composition [Cr(L)X 2]X and [M(L)X 2] (where M = Mn(II) and Ni(II); X = Cl -, NO 3-, (1/2)SO 42-, NCS - and L = ligand [N 6]). The ligand and its transition metal complexes were characterized by the elemental analysis, molar conductance, magnetic susceptibility, mass, IR, electronic and EPR spectral studies. On the basis of IR, electronic and EPR spectral studies, an octahedral geometry has been assigned for these complexes except sulphato complexes which are of five coordinated geometry.

  6. A HERSCHEL SURVEY OF THE [N II] 205 {mu}m LINE IN LOCAL LUMINOUS INFRARED GALAXIES: THE [N II] 205 {mu}m EMISSION AS A STAR FORMATION RATE INDICATOR

    Energy Technology Data Exchange (ETDEWEB)

    Zhao Yinghe; Gao Yu [Purple Mountain Observatory, Chinese Academy of Sciences, Nanjing 210008 (China); Lu, Nanyao; Xu, C. Kevin; Lord, S.; Howell, J.; Appleton, P.; Mazzarella, J.; Schulz, B. [Infrared Processing and Analysis Center, California Institute of Technology, MS 100-22, Pasadena, CA 91125 (United States); Isaak, K. G. [ESA Astrophysics Missions Division, ESTEC, PO Box 299, 2200 AG Noordwijk (Netherlands); Charmandaris, V. [Department of Physics and ITCP, University of Crete, GR-71003 Heraklion (Greece); Diaz-Santos, T.; Surace, J. [Spitzer Science Center, California Institute of Technology, MS 220-6, Pasadena, CA 91125 (United States); Evans, A. [Department of Astronomy, University of Virginia, 530 McCormick Road, Charlottesville, VA 22904 (United States); Iwasawa, K. [ICREA and Institut de Ciencies del Cosmos (ICC), Universitat de Barcelona (IEEC-UB), Marti i Franques 1, E-08028 Barcelona (Spain); Leech, J. [Department of Physics, University of Oxford, Denys Wilkinson Building, Keble Road, Oxford OX1 3RH (United Kingdom); Petric, A. O. [Astronomy Department, California Institute of Technology, Pasadena, CA 91125 (United States); Sanders, D. B. [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Drive, Honolulu, HI 96822 (United States); Van der Werf, P. P., E-mail: yhzhao@ipac.caltech.edu [Leiden Observatory, Leiden University, PO Box 9513, 2300 RA Leiden (Netherlands)

    2013-03-01

    We present, for the first time, a statistical study of [N II] 205 {mu}m line emission for a large sample of local luminous infrared galaxies using Herschel Spectral and Photometric Imaging Receiver Fourier Transform Spectrometer (SPIRE FTS) data. For our sample of galaxies, we investigate the correlation between the [N II] luminosity (L{sub [N{sub II]}}) and the total infrared luminosity (L{sub IR}), as well as the dependence of L{sub [N{sub II]}}/L{sub IR} ratio on L{sub IR}, far-infrared colors (IRAS f{sub 60}/f{sub 100}), and the [O III] 88 {mu}m to [N II] luminosity ratio. We find that L{sub [N{sub II]}} correlates almost linearly with L{sub IR} for non-active galactic nucleus galaxies (all having L{sub IR} < 10{sup 12} L{sub Sun }) in our sample, which implies that L{sub [N{sub II]}} can serve as a star formation rate tracer which is particularly useful for high-redshift galaxies that will be observed with forthcoming submillimeter spectroscopic facilities such as the Atacama Large Millimeter/submillimeter Array. Our analysis shows that the deviation from the mean L{sub [N{sub II]}}-L{sub IR} relation correlates with tracers of the ionization parameter, which suggests that the scatter in this relation is mainly due to the variations in the hardness, and/or ionization parameter, of the ambient galactic UV field among the sources in our sample.

  7. Elizabeth II uus kunstigalerii

    Index Scriptorium Estoniae

    1999-01-01

    Tähistamaks oma troonile asumise 50. aastapäeva, avab Elizabeth II 6. II 2002 Buckinghami palees uue kunstigalerii, mis ehitatakse palee tiibhoonena. Arhitekt John Simpson. Elizabeth II kunstikogust

  8. Cu(II) AND Zn(II)

    African Journals Online (AJOL)

    Preferred Customer

    SYNTHESIS OF 2,2-DIMETHYL-4-PHENYL-[1,3]-DIOXOLANE USING ZEOLITE. ENCAPSULATED Co(II), Cu(II) AND Zn(II) COMPLEXES. B.P. Nethravathi1, K. Rama Krishna Reddy2 and K.N. Mahendra1*. 1Department of Chemistry, Bangalore University, Bangalore-560001, India. 2Department of Chemistry, Government ...

  9. Synthesis of Pb(II Imprinted Carboxymethyl Chitosan and the Application as Sorbent for Pb(II Ion

    Directory of Open Access Journals (Sweden)

    Abu Masykur

    2014-07-01

    Full Text Available The aims of this research is to synthesize Pb(II imprinted polymers with carboxymethyl chitosan (CMC as polymers and bisphenol A diglycidyl ether (BADGE as cross-linker (Pb-IIP. Chitosan (CTS, non imprinted polymer (NIP and Pb-IIP were characterized using infrared (IR spectroscopy, X-ray diffraction (XRD, surface area analyzer (SAA, scanning electron microscopy (SEM, and energy dispersive X-ray (EDX spectroscopy. The result showed that the adsorption was optimum at pH 5 and contact time of 250 min. Adsorption of Pb(II ion with all of adsorbents followed pseudo-second order kinetic equation. Adsorption of Pb(II ion on CTS followed Freundlich isotherm while that on NIP and Pb-IIP followed the Langmuir adsorption isotherm. The adsorbent of Pb-IIP give higher capacity than the NIP and CTS. Adsorption capacity of Pb-IIP, NIP and CTS were 167.1, 128.9 and 76.1 mg/g, respectively. NIP gave higher adsorption selectivity for Pb(II/Ni(II and Pb(II/Cu(II, whereas Pb-IIP showed higher adsorption selectivity for Pb(II/Cd(II.The hydrogen bonding dominated interaction between Pb(II ion on NIP and Pb-IIP.

  10. SPATIAL VARIATIONS OF PAH PROPERTIES IN M17SW REVEALED BY SPITZER /IRS SPECTRAL MAPPING

    Energy Technology Data Exchange (ETDEWEB)

    Yamagishi, M. [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, Chuo-ku, Sagamihara 252-5210 (Japan); Kaneda, H.; Ishihara, D.; Oyabu, S.; Suzuki, T.; Nishimura, A.; Kohno, M. [Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602 (Japan); Onaka, T.; Ohashi, S. [Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Nagayama, T.; Matsuo, M. [Graduate School of Science and Engineering, Kagoshima University, 1-21-35 Korimoto, Kagoshima 890-0065 (Japan); Umemoto, T.; Minamidani, T.; Fujita, S. [Nobeyama Radio Observatory, National Astronomical Observatory of Japan (NAOJ), National Institutes of Natural Sciences (NINS), 462-2, Nobeyama, Minamimaki, Minamisaku, Nagano 384-1305 (Japan); Tsuda, Y., E-mail: yamagish@ir.isas.jaxa.jp [Graduate School of Science and Engineering, Meisei University, 2-1-1 Hodokubo, Hino, Tokyo 191-0042 (Japan)

    2016-12-20

    We present Spitzer /IRS mid-infrared spectral maps of the Galactic star-forming region M17 as well as IRSF/SIRIUS Br γ and Nobeyama 45 m/FOREST {sup 13}CO ( J = 1–0) maps. The spectra show prominent features due to polycyclic aromatic hydrocarbons (PAHs) at wavelengths of 6.2, 7.7, 8.6, 11.3, 12.0, 12.7, 13.5, and 14.2  μ m. We find that the PAH emission features are bright in the region between the H ii region traced by Br γ and the molecular cloud traced by {sup 13}CO, supporting that the PAH emission originates mostly from photo-dissociation regions. Based on the spatially resolved Spitzer /IRS maps, we examine spatial variations of the PAH properties in detail. As a result, we find that the interband ratio of PAH 7.7  μ m/PAH 11.3  μ m varies locally near M17SW, but rather independently of the distance from the OB stars in M17, suggesting that the degree of PAH ionization is mainly controlled by local conditions rather than the global UV environments determined by the OB stars in M17. We also find that the interband ratios of the PAH 12.0  μ m, 12.7  μ m, 13.5  μ m, and 14.2  μ m features to the PAH 11.3  μ m feature are high near the M17 center, which suggests structural changes of PAHs through processing due to intense UV radiation, producing abundant edgy irregular PAHs near the M17 center.

  11. Research into the usage of integrated jamming of IR weakening and smoke-screen resisting the IR imaging guided missiles

    Science.gov (United States)

    Wang, Long-tao; Jiang, Ning; Lv, Ming-shan

    2015-10-01

    With the emergence of the anti-ship missle with the capability of infrared imaging guidance, the traditional single jamming measures, because of the jamming mechanism and technical flaws or unsuitable use, greatly reduced the survival probability of the war-ship in the future naval battle. Intergrated jamming of IR weakening + smoke-screen Can not only make jamming to the search and tracking of IR imaging guidance system , but also has feasibility in conjunction, besides , which also make the best jamming effect. The research conclusion has important realistic meaning for raising the antimissile ability of surface ships. With the development of guidance technology, infrared guidance system has expanded by ir point-source homing guidance to infrared imaging guidance, Infrared imaging guidance has made breakthrough progress, Infrared imaging guidance system can use two-dimensional infrared image information of the target, achieve the precise tracking. Which has Higher guidance precision, better concealment, stronger anti-interference ability and could Target the key parts. The traditional single infrared smoke screen jamming or infrared decoy flare interference cannot be imposed effective interference. So, Research how to effectively fight against infrared imaging guided weapons threat measures and means, improving the surface ship antimissile ability is an urgent need to solve.

  12. Semiclassical relations and IR effects in de Sitter and slow-roll space-times

    DEFF Research Database (Denmark)

    B. Giddings, Steven; Sloth, Martin Snoager

    2010-01-01

    We calculate IR divergent graviton one-loop corrections to scalar correlators in de Sitter space, and show that the leading IR contribution may be reproduced via simple semiclassical consistency relations. One can likewise use such semiclassical relations to calculate leading IR corrections to co...... with a sharp perturbative calculation of "missing information" in Hawking radiation....

  13. Manual for IRS Coding. Joint IAEA/NEA International Reporting System for Operating Experience

    International Nuclear Information System (INIS)

    2011-01-01

    The International Reporting System for Operating Experience (IRS) is jointly operated by the International Atomic Energy Agency (IAEA) and the Nuclear Energy Agency of the Organisation for Economic Co-operation and Development (OECD/NEA). In early 2010, the IAEA and OECD/NEA jointly issued the IRS Guidelines, which described the reporting system and process and gave users the necessary elements to enable them to produce IRS reports to a high standard of quality while retaining the effectiveness of the system expected by all Member States operating nuclear power plants. The purpose of the present Manual for IRS Coding is to provide supplementary guidance specifically on the coding element of IRS reports to ensure uniform coding of events that are reported through IRS. This Coding Manual does not supersede the IRS Guidelines, but rather, supports users and preparers in achieving a consistent and high level of quality in their IRS reports. Consistency and high quality in the IRS reports allow stakeholders to search and retrieve specific event information with ease. In addition, well-structured reports also enhance the efficient management of the IRS database. This Coding Manual will give specific guidance on the application of each section of the IRS codes, with examples where necessary, of when and how these codes are to be applied. As this reporting system is owned by the Member States, this manual has been developed and approved by the IRS National Coordinators with the assistance of the IAEA and NEA secretariats

  14. MODIS_AQUA_L3_SST_MID-IR_ANNUAL_4KM_NIGHTTIME:1

    Data.gov (United States)

    National Aeronautics and Space Administration — SST is derived from the MODIS IR channels using two channels in either the thermal IR (11-12 um) or channels in the mid-IR region (3.8-4.1 um). The approach is...

  15. MODIS_TERRA_L3_SST_MID-IR_MONTHLY_9KM_NIGHTTIME:1

    Data.gov (United States)

    National Aeronautics and Space Administration — SST is derived from the MODIS IR channels using two channels in either the thermal IR (11-12 um) or channels in the mid-IR region (3.8-4.1 um). The approach is...

  16. A Prospective Cohort Study on IRS Gene Polymorphisms in Type 2 ...

    African Journals Online (AJOL)

    Insulin resistance status was determined using the homeostatic model assessment for insulin resistance (HOMA-IR) index. Results: IRS1 polymorphisms were associated with increased insulin resistance (X2 = 5.09, p = 0.023) in T2DM patients with severe/acute hyperglycemia. IRS2 polymorphisms were not associated with ...

  17. DFT study of the structure, chemical ordering and molecular adsorption of Pd-Ir nanoalloys.

    Science.gov (United States)

    Fan, Tian-E; Demiroglu, Ilker; Hussein, Heider A; Liu, Tun-Dong; Johnston, Roy L

    2017-10-11

    The structures and surface adsorption sites of Pd-Ir nanoalloys are crucial to the understanding of their catalytic performance because they can affect the activity and selectivity of nanocatalysts. In this article, density functional theory (DFT) calculations are performed on bare Pd-Ir nanoalloys to systematically explore their stability and chemical ordering properties, before studying the adsorption of CO on the nanoalloys. First, the structural stability of 38-atom and 79-atom truncated octahedral (TO) Pd-Ir nanoalloys are investigated. Then the adsorption properties and preferred adsorption sites of CO on 38-atom Pd-Ir nanoalloys are considered. The Pd shell Ir core structure, which has the lowest energy of all the considered isomers, exhibits the highest structural stability, while the Pd core Ir shell configuration is the least stable. In addition, the adsorption strength of CO on Ir atoms is found to be greater than on Pd for Pd-Ir nanoclusters. The preferred adsorption sites of CO on pure Pd and Ir clusters are in agreement with calculations and experiments on extended Pd and Ir surfaces. In addition, d-band center and charge effects on CO adsorption strength on Pd-Ir nanoalloys are analyzed by comparison with pure clusters. The study provides a valuable theoretical insight into catalytically active Pd-Ir nanoalloys.

  18. MODIS_TERRA_L3_SST_MID-IR_ANNUAL_4KM_NIGHTTIME:1

    Data.gov (United States)

    National Aeronautics and Space Administration — SST is derived from the MODIS IR channels using two channels in either the thermal IR (11-12 um) or channels in the mid-IR region (3.8-4.1 um). The approach is...

  19. MODIS_AQUA_L3_SST_MID-IR_MONTHLY_9KM_NIGHTTIME:1

    Data.gov (United States)

    National Aeronautics and Space Administration — SST is derived from the MODIS IR channels using two channels in either the thermal IR (11-12 um) or channels in the mid-IR region (3.8-4.1 um). The approach is...

  20. MODIS_TERRA_L3_SST_MID-IR_8DAY_9KM_NIGHTTIME:1

    Data.gov (United States)

    National Aeronautics and Space Administration — SST is derived from the MODIS IR channels using two channels in either the thermal IR (11-12 um) or channels in the mid-IR region (3.8-4.1 um). The approach is...

  1. MODIS_TERRA_L3_SST_MID-IR_MONTHLY_4KM_NIGHTTIME:1

    Data.gov (United States)

    National Aeronautics and Space Administration — SST is derived from the MODIS IR channels using two channels in either the thermal IR (11-12 um) or channels in the mid-IR region (3.8-4.1 um). The approach is...

  2. MODIS_AQUA_L3_SST_MID-IR_DAILY_9KM_NIGHTTIME:1

    Data.gov (United States)

    National Aeronautics and Space Administration — SST is derived from the MODIS IR channels using two channels in either the thermal IR (11-12 um) or channels in the mid-IR region (3.8-4.1 um). The approach is...

  3. MODIS_TERRA_L3_SST_MID-IR_ANNUAL_9KM_NIGHTTIME:1

    Data.gov (United States)

    National Aeronautics and Space Administration — SST is derived from the MODIS IR channels using two channels in either the thermal IR (11-12 um) or channels in the mid-IR region (3.8-4.1 um). The approach is...

  4. IR spectroscopy of isolated neutral and protonated adenine and 9-methyladenine

    NARCIS (Netherlands)

    van Zundert, G. C. P.; Jaeqx, S.; Berden, G.; Bakker, J.M.; Kleinermanns, K.; Oomens, J.; Rijs, A.M.

    2011-01-01

    IR spectroscopy is employed to study isolated adenine and its derivative 9-methyladenine in both their neutral and protonated forms. The IR spectra of neutral adenine and 9-methyladenine are measured in a molecular beam expansion via IR-UV ion-dip spectroscopy in the 525 to 1750 cm−1 region. For

  5. IR Spectroscopy of Isolated Neutral and Protonated Adenine and 9-Methyladenine

    NARCIS (Netherlands)

    van Zundert, G. C. P.; Jaeqx, S.; G. Berden,; Bakker, J. M.; Kleinermanns, K.; Oomens, J.; Rijs, A. M.

    2011-01-01

    IR spectroscopy is employed to study isolated adenine and its derivative 9-methyladenine in both their neutral and protonated forms. The IR spectra of neutral adenine and 9-methyladenine are measured in a molecular beam expansion via IR-UV ion-dip spectroscopy in the 525 to 1750 cm(-1) region. For

  6. Comparative study of potentially J{sub eff} = 0 ground state iridium(V) in SrLaNiIrO{sub 6}, SrLaMgIrO{sub 6}, and SrLaZnIrO{sub 6}

    Energy Technology Data Exchange (ETDEWEB)

    Wolff, Klaus K.; Agrestini, Stefano; Tjeng, Liu Hao [Max Planck Institute for Chemical Physics of Solids, Dresden (Germany); Tanaka, Arata [Department of Quantum Matter, AdSM, Hiroshima University, Higashi-Hiroshima (Japan); Jansen, Martin [Max Planck Institute for Chemical Physics of Solids, Dresden (Germany); Max Planck Institute for Solid State Research, Stuttgart (Germany)

    2017-12-13

    A series of polycrystalline double perovskites SrLaBIrO{sub 6} (B = Ni, Mg, Zn) containing Ir{sup 5+} (5d{sup 4}) was synthesized by solid state reactions, and structural, magnetic and electronic properties were investigated. The isotypic fully ordered double perovskites crystallize in space group P2{sub 1}/n and show semiconducting behavior with estimated bandgaps of approximately 0.2 eV for SrLaNiIrO{sub 6} and SrLaZnIrO{sub 6}, and 0.4 eV for SrLaMgIrO{sub 6}. SrLaNiIrO{sub 6} is an antiferromagnet with a Neel temperature of 74 K (μ{sub eff} = 3.3 μ{sub B}, θ{sub W} = -90 K), whereas SrLaMgIrO{sub 6} and SrLaZnIrO{sub 6} are weakly paramagnetic. All title compounds exhibit a temperature-independent contribution to the measured magnetic susceptibility, which supports the notion for a van-Vleck-type response originating from the Ir{sup 5+} (5d{sup 4}, J{sub eff} = 0) ions. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  7. Synthesis and characterisation of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II ...

    Indian Academy of Sciences (India)

    Unknown

    Synthesis and characterisation of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) Schiff base complexes derived from o-phenylenediamine and acetoacetanilide. N RAMAN*, Y PITCHAIKANI RAJA and A KULANDAISAMY. Department of Chemistry, VHNSN College, Virudhunagar 626 001, India e-mail: ra_man@123india.com.

  8. THE SURVEY OF LINES IN M31 (SLIM): INVESTIGATING THE ORIGINS OF [C II] EMISSION

    Energy Technology Data Exchange (ETDEWEB)

    Kapala, M. J.; Sandstrom, K.; Groves, B.; Kreckel, K.; Schinnerer, E.; Walter, F.; Fouesneau, M. [Max Planck Institut für Astronomie, Königstuhl 17, D-69117 Heidelberg (Germany); Croxall, K. [Department of Astronomy, The Ohio State University, 140 West 18th Avenue, Columbus, OH 43210 (United States); Dalcanton, J. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Leroy, A., E-mail: kapala@mpia.de [National Radio Astronomy Observatory, 520 Edgemont Road, Charlottesville, VA 22903 (United States)

    2015-01-01

    The [C II] 158 μm line is one of the strongest emission lines observed in star-forming galaxies and has been empirically measured to correlate with the star-formation rate (SFR) globally and on kiloparsec scales. However, because of the multiphase origins of [C II], one might expect this relation to break down at small scales. We investigate the origins of [C II] emission by examining high spatial resolution observations of [C II] in M31 with the Survey of Lines in M31. We present five ∼700 × 700 pc (3' × 3') fields mapping the [C II] emission, Hα emission, and the ancillary infrared (IR) data. We spatially separate star-forming regions from diffuse gas and dust emission on ∼50 pc scales. We find that the [C II]-SFR correlation holds even at these scales, although the relation typically has a flatter slope than found at larger (kiloparsec) scales. While the Hα emission in M31 is concentrated in the SFR regions, we find that a significant amount (∼20%-90%) of the [C II] emission comes from outside star-forming regions and that the total IR emission (TIR) has the highest diffuse fraction of all SFR tracers. We find a weak correlation of the [C II]/TIR to dust color in each field and find a large-scale trend of increasing [C II]/TIR with galactocentric radius. The differences in the relative diffuse fractions of [C II], Hα, and IR tracers are likely caused by a combination of energetic photon leakage from H II regions and heating by the diffuse radiation field arising from older (B-star) stellar populations. However, we find that by averaging our measurements over kiloparsec scales, these effects are minimized, and the relation between [C II] and SFR found in other nearby galaxy studies is retrieved.

  9. The effect of interligand energy transfer on the emission spectra of heteroleptic Ir complexes.

    Science.gov (United States)

    Cho, Yang-Jin; Kim, So-Yoen; Son, Ho-Jin; Cho, Dae Won; Kang, Sang Ook

    2017-03-29

    In order to understand the causes of the emission shape and colour changes of heteroleptic Ir 3+ complexes containing 2-(2,4-difluorophenyl)pyridine (dfppy) as the main ligands, we introduced two types of ancillary ligands: (1) non-luminescent ancillary ligands, namely tetrakis(pyrazolyl)borate (bor) and picolinate (pic), which were employed for the preparation of Ir(dfppy) 2 (bor) and Ir(dfppy) 2 (pic), respectively, and (2) luminescent ancillary ligands, namely 1,10-phenanthroline (phen), bipyridine (bpy), and 2,3-dipyridylpyrazine (dpp), which were employed for the preparation of Ir(dfppy) 2 (phen), Ir(dfppy) 2 (bpy), and Ir(dfppy) 2 (dpp), respectively. In a glassy matrix at 77 K, the Ir complexes showed well-structured emission spectra, except Ir(dfppy) 2 (dpp). The vibronic structures in the emission spectra of Ir(dfppy) 2 (bor) and Ir(dfppy) 2 (pic) were maintained even at 300 K. However, Ir(dfppy) 2 (phen), Ir(dfppy) 2 (bpy), and Ir(dfppy) 2 (dpp) showed markedly red-shifted and broad emission spectra. The anomalous rigidochromism was attributed to an interligand energy transfer (ILET), and showed a strong temperature dependence. The excited states of dfppy are higher than those of phen, bpy, and dpp; thus, ILET occurs from dfppy to the other ligands lying in lower energy states. The ILET dynamics were probed directly using femtosecond transient absorption (TA) spectroscopy after the excitation of dfppy. As the time delay increased, the intensity of the TA band of dfppy decreased, while those of the bands related to the phen, bpy, and dpp ancillary ligands increased. On the other hand, no changes in the TA spectra were observed for Ir(dfppy) 2 (bor) and Ir(dfppy) 2 (pic). The TA spectral behaviours can be explained in terms of the relative ordering of the emissive states for cyclometalating and ancillary ligands.

  10. Study on seasonal IR signature change of a ship by considering seasonal marine environmental conditions

    Science.gov (United States)

    Kim, Do-Hwi; Han, Kuk-Il; Choi, Jun-Hyuk; Kim, Tae-Kuk

    2017-05-01

    Infrared (IR) signal emitted from objects over 0 degree Kelvin has been used to detect and recognize the characteristics of those objects. Recently more delicate IR sensors have been applied for various guided missiles and they affect a crucial influence on object's survivability. Especially, in marine environment it is more vulnerable to be attacked by IR guided missiles since there are nearly no objects for concealment. To increase the survivability of object, the IR signal of the object needs to be analyzed properly by considering various marine environments. IR signature of a naval ship consists of the emitted energy from ship surface and the reflected energy by external sources. Surface property such as the emissivity and the absorptivity on the naval ship varies with different paints applied on the surface and the reflected IR signal is also affected by the surface radiative property, the sensor's geometric position and various climatic conditions in marine environment. Since the direct measurement of IR signal using IR camera is costly and time consuming job, computer simulation methods are developing rapidly to replace those experimental tasks. In this study, we are demonstrate a way of analyzing the IR signal characteristics by using the measured background IR signals using an IR camera and the estimated target IR signals from the computer simulation to find the seasonal trends of IR threats of a naval ship. Through this process, measured weather data are used to analyze more accurate IR signal conditions for the naval ship. The seasonal change of IR signal contrast between the naval ship and the marine background shows that the highest contrast radiant intensity (CRI) value is appeared in early summer.

  11. NO Reactions Over Ir-Based Catalysts in the Presence of O2

    Directory of Open Access Journals (Sweden)

    Mingxin Guo

    2011-01-01

    Full Text Available The behaviour of a series of Ir-based catalysts supported on SiO2, ZSM-5 and γ-Al2O3 with various Ir loadings prepared by impregnation method was conducted by temperature programmed reaction (TPR technique. The result implies that NO is oxidized to NO2 while simultaneously being reduced to N2 or N2O in the NO reactions over iridium catalysts. The surface active phase over iridium catalysts that promote the NO reactions is IrO2. The catalytic activity increases with the increase of the Ir loading and support materials have a little effect on the catalytic activity. When the loading is less than 0.1%, the catalytic activity was found to be dependent on the nature of support materials and in order: Ir/ZSM-5>Ir/γ-Al2O3>Ir/SiO2. When the loading is higher than 0.1%, the catalytic activity for NO oxidation is in order: Ir/ZSM-5>Ir/SiO2>Ir/γ -Al2O3, which is correlated with Ir dispersion on the surface of support materials and the catalytic activity for NO reduction is in sequence: Ir/γ -Al2O3>Ir/SiO2>Ir/ZSM-5, which is attributed to the adsorbed-dissociation of NO2. Compared to Pt/γ-Al2O3, Ir/γ-Al2O3 catalyst is more benefit for the NO reduction.

  12. THE LOCAL [C ii] 158 μ m EMISSION LINE LUMINOSITY FUNCTION

    Energy Technology Data Exchange (ETDEWEB)

    Hemmati, Shoubaneh; Yan, Lin; Capak, Peter; Faisst, Andreas; Masters, Daniel [Infrared Processing and Analysis Center, Department of Astronomy, California Institute of Technology, 1200 E. California Blvd., Pasadena CA 91125 (United States); Diaz-Santos, Tanio [Nucleo de Astronomia de la Facultad de Ingenieria, Universidad Diego Portales, Av. Ejercito Libertador 441, Santiago (Chile); Armus, Lee, E-mail: shemmati@ipac.caltech.edu [Spitzer Science Center, Department of Astronomy, California Institute of Technology, 1200 E. California Blvd., Pasadena, CA 91125 (United States)

    2017-01-01

    We present, for the first time, the local [C ii] 158 μ m emission line luminosity function measured using a sample of more than 500 galaxies from the Revised Bright Galaxy Sample. [C ii] luminosities are measured from the Herschel PACS observations of the Luminous Infrared Galaxies (LIRGs) in the Great Observatories All-sky LIRG Survey and estimated for the rest of the sample based on the far-infrared (far-IR) luminosity and color. The sample covers 91.3% of the sky and is complete at S{sub 60μm} > 5.24 Jy. We calculate the completeness as a function of [C ii] line luminosity and distance, based on the far-IR color and flux densities. The [C ii] luminosity function is constrained in the range ∼10{sup 7–9} L{sub ⊙} from both the 1/ V{sub max} and a maximum likelihood methods. The shape of our derived [C ii] emission line luminosity function agrees well with the IR luminosity function. For the CO(1-0) and [C ii] luminosity functions to agree, we propose a varying ratio of [C ii]/CO(1-0) as a function of CO luminosity, with larger ratios for fainter CO luminosities. Limited [C ii] high-redshift observations as well as estimates based on the IR and UV luminosity functions are suggestive of an evolution in the [C ii] luminosity function similar to the evolution trend of the cosmic star formation rate density. Deep surveys using the Atacama Large Millimeter Array with full capability will be able to confirm this prediction.

  13. Effect of endocrine therapy on growth of T61 human breast cancer xenografts is directly correlated to a specific down-regulation of insulin-like growth factor II (IGF-II)

    DEFF Research Database (Denmark)

    Brünner, N; Yee, D; Kern, F G

    1993-01-01

    xenograft. Growth of the T61 tumour is inhibited by treatment with E2 and TAM. Ribonuclease (RNAse) protection assays with human- and mouse-specific IGF-II antisense probes were used to study the regulation of IGF-II mRNA by E2 and TAM in the tumour. IGF-II protein expression was studied by radioimmunoassay......-IR3 resulted in inhibition of tumour growth during treatment.(ABSTRACT TRUNCATED AT 400 WORDS)...

  14. Ni(II, Pd(II and Pt(II complexes with ligand containing thiosemicarbazone and semicarbazone moiety: synthesis, characterization and biological investigation

    Directory of Open Access Journals (Sweden)

    SULEKH CHANDRA

    2008-07-01

    Full Text Available The synthesis of nickel(II, palladium(II and platinum(II complexes with thiosemicarbazone and semicarbazone of p-tolualdehyde are reported. All the new compounds were characterized by elemental analysis, molar conductance measurements, magnetic susceptibility measurements, mass, 1H-NMR, IR and electronic spectral studies. Based on the molar conductance measurements in DMSO, the complexes may be formulated as [Ni(L2Cl2] and [M(L2]Cl2 (where M = Pd(II and Pt(II due to their non-electrolytic and 1:2 electrolytic nature, respectively. The spectral data are consistent with an octahedral geometry around Ni(II and a square planar geometry for Pd(II and Pt(II, in which the ligands act as bidentate chelating agents, coordinated through the nitrogen and sulphur/oxygen atoms. The ligands and their metal complexes were screened in vitro against fungal species Alternaria alternata, Aspergillus niger and Fusarium odum, using the food poison technique.

  15. Synthesis, spectroscopic characterization, DNA interaction and biological activities of Mn(II), Co(II), Ni(II) and Cu(II) complexes with [(1H-1,2,4-triazole-3-ylimino)methyl]naphthalene-2-ol

    Science.gov (United States)

    Gaber, Mohamed; El-Wakiel, Nadia A.; El-Ghamry, Hoda; Fathalla, Shaimaa K.

    2014-11-01

    Manganese(II), cobalt(II), nickel(II) and copper(II) complexes of [(1H-1,2,4-triazole-3-ylimino)methyl]naphthalene-2-ol have been synthesized. The structure of complexes have been characterized by elemental analysis, molar conductance, magnetic moment measurements and spectral (IR, 1H NMR, EI-mass, UV-Vis and ESR), and thermal studies. The results showed that the chloro and nitrato Cu(II) complexes have octahedral geometry while Ni(II), Co(II) and Mn(II) complexes in addition to acetato Cu(II) complex have tetrahedral geometry. The possible structures of the metal complexes have been computed using the molecular mechanic calculations using the hyper chem. 8.03 molecular modeling program to confirm the proposed structures. The kinetic and thermodynamic parameters of the thermal decomposition steps were calculated from the TG curves. The binding modes of the complexes with DNA have been investigated by UV-Vis absorption titration. The results showed that the mode of binding of the complexes to DNA is intercalative or non-intercalative binding modes. Schiff base and its metal complexes have been screened for their in vitro antimicrobial activities against Gram positive bacteria (Staphylococcus aureus), Gram negative bacteria (Escherichia coli and Pesudomonas aeruginosa), fungi (Asperigllus flavus and Mucer) and yeast (Candida albicans and Malassezia furfur).

  16. “Contrapuntal Reading” as a Method, an Ethos, and a Metaphor for Global IR

    DEFF Research Database (Denmark)

    Bilgin, Pinar

    2016-01-01

    How to approach Global International Relations (IR)? This is a question asked by students of IR who recognize the limits of our field while expressing their concern that those who strive for a Global IR have been less-than-clear about the “how to?” question. In this article, I point to Edward W....... Said’s approach to “contrapuntal reading” as one way of approaching Global IR that embraces diversity and reflects multiple and overlapping experiences and perspectives of humankind. More specifically, I suggest that contrapuntal reading offers students of IR a method of studying world politics...

  17. Using Fourier transform IR spectroscopy to analyze biological materials.

    Science.gov (United States)

    Baker, Matthew J; Trevisan, Júlio; Bassan, Paul; Bhargava, Rohit; Butler, Holly J; Dorling, Konrad M; Fielden, Peter R; Fogarty, Simon W; Fullwood, Nigel J; Heys, Kelly A; Hughes, Caryn; Lasch, Peter; Martin-Hirsch, Pierre L; Obinaju, Blessing; Sockalingum, Ganesh D; Sulé-Suso, Josep; Strong, Rebecca J; Walsh, Michael J; Wood, Bayden R; Gardner, Peter; Martin, Francis L

    2014-08-01

    IR spectroscopy is an excellent method for biological analyses. It enables the nonperturbative, label-free extraction of biochemical information and images toward diagnosis and the assessment of cell functionality. Although not strictly microscopy in the conventional sense, it allows the construction of images of tissue or cell architecture by the passing of spectral data through a variety of computational algorithms. Because such images are constructed from fingerprint spectra, the notion is that they can be an objective reflection of the underlying health status of the analyzed sample. One of the major difficulties in the field has been determining a consensus on spectral pre-processing and data analysis. This manuscript brings together as coauthors some of the leaders in this field to allow the standardization of methods and procedures for adapting a multistage approach to a methodology that can be applied to a variety of cell biological questions or used within a clinical setting for disease screening or diagnosis. We describe a protocol for collecting IR spectra and images from biological samples (e.g., fixed cytology and tissue sections, live cells or biofluids) that assesses the instrumental options available, appropriate sample preparation, different sampling modes as well as important advances in spectral data acquisition. After acquisition, data processing consists of a sequence of steps including quality control, spectral pre-processing, feature extraction and classification of the supervised or unsupervised type. A typical experiment can be completed and analyzed within hours. Example results are presented on the use of IR spectra combined with multivariate data processing.

  18. Critical Dispersion-Theory Tests of Silicon's IR Refractive Index

    Science.gov (United States)

    Karstens, William; Smith, D. Y.

    Silicon strongly absorbs both visible and UV light, but is highly transparent in the IR. Hence, it is a common choice for infrared windows and lenses. However, optical design is hindered by literature index values that disagree by up to 1%. In contrast optical-glass indices are known to 0.01% or better. The most widely available silicon IR indices are based on bulk measurements using either Snell's-Law refraction by a prism or channel-spectra interference of front- and backsurface reflections from a planar sample. To test the physical acceptability of these data, we have developed criteria based on a Taylor expansion of the Kramers-Kronig relation for the index at energies below strong inter-band transitions. These tests require that the coefficients of the series in powers of energy squared must be positive within the region of transparency. This is satisfied by essentially all prism measurements; their small scatter arises primarily from impurities and doping. In contrast, channel-spectra data fail in the second and third coefficients. A review of the experimental analysis indicates three problems besides purity: incorrect channel number arising from a channel-spectra model that neglects spectrum distortion by the weak lattice absorption; use of a series expansion of mixed parity in photon energy to describe the even-parity index; and use of an incorrect absorption energy in the Li-Sellmeier dispersion formula. Recommendations for IR index values for pure silicon will be discussed. Supported in part by the US Department of Energy, Office of Science, Office of Nuclear Physics under contract DE-AC02-06CH11357.

  19. Wavelet based image visibility enhancement of IR images

    Science.gov (United States)

    Jiang, Qin; Owechko, Yuri; Blanton, Brendan

    2016-05-01

    Enhancing the visibility of infrared images obtained in a degraded visibility environment is very important for many applications such as surveillance, visual navigation in bad weather, and helicopter landing in brownout conditions. In this paper, we present an IR image visibility enhancement system based on adaptively modifying the wavelet coefficients of the images. In our proposed system, input images are first filtered by a histogram-based dynamic range filter in order to remove sensor noise and convert the input images into 8-bit dynamic range for efficient processing and display. By utilizing a wavelet transformation, we modify the image intensity distribution and enhance image edges simultaneously. In the wavelet domain, low frequency wavelet coefficients contain original image intensity distribution while high frequency wavelet coefficients contain edge information for the original images. To modify the image intensity distribution, an adaptive histogram equalization technique is applied to the low frequency wavelet coefficients while to enhance image edges, an adaptive edge enhancement technique is applied to the high frequency wavelet coefficients. An inverse wavelet transformation is applied to the modified wavelet coefficients to obtain intensity images with enhanced visibility. Finally, a Gaussian filter is used to remove blocking artifacts introduced by the adaptive techniques. Since wavelet transformation uses down-sampling to obtain low frequency wavelet coefficients, histogram equalization of low-frequency coefficients is computationally more efficient than histogram equalization of the original images. We tested the proposed system with degraded IR images obtained from a helicopter landing in brownout conditions. Our experimental results show that the proposed system is effective for enhancing the visibility of degraded IR images.

  20. Looking at Art in the IR and UV

    Science.gov (United States)

    Falco, Charles

    2013-03-01

    Starting with the very earliest cave paintings art has been created to be viewed by the unaided eye and, until very recently, it wasn't even possible to see it at wavelengths outside the visible spectrum. However, it is now possible to view paintings, sculptures, manuscripts, and other cultural artifacts at wavelengths from the x-ray, through the ultraviolet (UV), to well into the infrared (IR). Further, thanks to recent advances in technology, this is becoming possible with hand-held instruments that can be used in locations that were previously inaccessible to anything but laboratory-scale image capture equipment. But, what can be learned from such ``non-visible'' images? In this talk I will briefly describe the characteristics of high resolution UV and IR imaging systems I developed for this purpose by modifying high resolution digital cameras. The sensitivity of the IR camera makes it possible to obtain images of art ``in situ'' with standard museum lighting, resolving features finer than 0.35 mm on a 1.0x0.67 m painting. I also have used both it and the UV camera in remote locations with battery-powered illumination sources. I will illustrate their capabilities with images of various examples of Western, Asian, and Islamic art in museums on three continents, describing how these images have revealed important new information about the working practices of artists as famous as Jan van Eyck. I also will describe what will be possible for this type of work with new capabilities that could be developed within the next few years. This work is based on a collaboration with David Hockney, and benefitted from image analys research supported by ARO grant W911NF-06-1-0359-P00001.

  1. Derivatives as an IR regulator for massless fields

    CERN Document Server

    Elmfors, P

    1995-01-01

    The free propagator for the scalar \\lambda \\phi^4--theory is calculated exactly up to the second derivative of a background field. Using this propagator I compute the one--loop effective action, which then contains all powers of the field but with at most two derivatives acting on each field. The standard derivative expansion, which only has a finite number of derivatives in each term, breaks down for small fields when the mass is zero, while the expression obtained here has a well--defined expansion in \\phi. In this way the resummation of derivatives cures the naive IR divergence. The extension to finite temperature is also discussed.

  2. Neo-Poulantzian Perspectives in IR and the Current Crisis

    DEFF Research Database (Denmark)

    Ougaard, Morten

    This paper is about Poulantzas, historical materialism, international relations, and the current crisis. My purpose is to discuss how some Poulantzian theoretical contributions can be applied to the study of subject matters that are the focus of academic fields such as International Relations (IR...... that contains its own theoretical definition of the object under study. This object, with inspiration from Poulantzas’ notion of the imperialist chain and his general theory of society, I will define as the global social formation or for short, world society....

  3. Improved Likelihood Function in Particle-based IR Eye Tracking

    DEFF Research Database (Denmark)

    Satria, R.; Sorensen, J.; Hammoud, R.

    2005-01-01

    In this paper we propose a log likelihood-ratio function of foreground and background models used in a particle filter to track the eye region in dark-bright pupil image sequences. This model fuses information from both dark and bright pupil images and their difference image into one model. Our...... enhanced tracker overcomes the issues of prior selection of static thresholds during the detection of feature observations in the bright-dark difference images. The auto-initialization process is performed using cascaded classifier trained using adaboost and adapted to IR eye images. Experiments show good...

  4. Dynamic IR scene projector based upon the digital micromirror device

    Science.gov (United States)

    Beasley, D. Brett; Bender, Matt W.; Crosby, Jay; Messer, Tim; Saylor, Daniel A.

    2001-08-01

    Optical Sciences Corp. has developed a new dynamic infrared scene projector technology called the Micromirror Array Projector System (MAPS). The MAPS is based upon the Texas Instruments Digital Micromirror DeviceTM which has been modified to project images that are suitable for testing sensors and seekers operating in the UV, visible, and IR wavebands. The projector may be used in several configurations which are optimized for specific applications. This paper provides an overview of the design and performance of the MAPS projection system, as well as example imagery from prototype projector systems.

  5. Metal-carbon nanocomposites based on activated IR pyrolized polyacrylonitrile

    Energy Technology Data Exchange (ETDEWEB)

    Efimov, Mikhail N.; Zhilyaeva, Natalya A.; Vasilyev, Andrey A.; Muratov, Dmitriy G.; Zemtsov, Lev M.; Karpacheva, Galina P. [A.V. Topchiev Institute of Petrochemical Synthesis RAS, Leninskiy Prospekt 29, 119991 Moscow Russia (Russian Federation)

    2016-05-18

    In this paper we report about new approach to preparation of metal-carbon nanocomposites based on activated carbon. Polyacrylonitrile is suggested as a precursor for Co, Pd and Ru nanoparticles carbon support which is prepared under IR pyrolysis conditions of a precursor. The first part of the paper is devoted to study activated carbon structural characteristics dependence on activation conditions. In the second part the effect of type of metal introduced in precursor on metal-carbon nanocomposite structural characteristics is shown. Prepared AC and nanocomposite samples are characterized by BET, TEM, SEM and X-ray diffraction.

  6. Metal-carbon nanocomposites based on activated IR pyrolized polyacrylonitrile

    International Nuclear Information System (INIS)

    Efimov, Mikhail N.; Zhilyaeva, Natalya A.; Vasilyev, Andrey A.; Muratov, Dmitriy G.; Zemtsov, Lev M.; Karpacheva, Galina P.

    2016-01-01

    In this paper we report about new approach to preparation of metal-carbon nanocomposites based on activated carbon. Polyacrylonitrile is suggested as a precursor for Co, Pd and Ru nanoparticles carbon support which is prepared under IR pyrolysis conditions of a precursor. The first part of the paper is devoted to study activated carbon structural characteristics dependence on activation conditions. In the second part the effect of type of metal introduced in precursor on metal-carbon nanocomposite structural characteristics is shown. Prepared AC and nanocomposite samples are characterized by BET, TEM, SEM and X-ray diffraction.

  7. IR-UWB radio-over-fiber system components development

    Science.gov (United States)

    Sultanov, Albert K.; Vinogradova, Irina L.; Meshkov, Ivan K.; Grakhova, Elizaveta P.; Shmidt, Svyatoslav P.; Abdrakhmanova, Guzel I.; Tafur Monroy, Idelfonso

    2016-03-01

    The paper describes the application of IR-UWB technology for organizing the radio part of Radio-over-Fiber system. Four physical layer components are proposed and designed in the paper: three microstrip filters and UWB antenna. Firstly the effective SCRF mask was calculated to ensure electromagnetic compatibility with existing radio services. Then this mask was considered as a cost function for filters design. The simulation was made with Agilent Genesys™ and CST Microwave Studio. All the devices have shown good performance and could be implemented on one circuit board for reducing losses.

  8. Apie filosofijos ir meno sąsajas

    OpenAIRE

    Martinkus, Vytautas

    2008-01-01

    The article provides a review of Leonarda Jekentaitė’s book “De Profundis: Psichoanalitinės Filosofijos Žvilgsniu apie Mąstytojus ir Menininkus” (2007), written by V. Martinkus, according to whom, there are still few original art philosophy studies, published by Lithuanian authors in Lithuania. The review provides an analysis of the structure of the book, the style and main subjects are distinguished. The book provides the author’s articles, written during the period of thirty years. Most of ...

  9. IR Algorithm Development for Fire and Forget Projectiles.

    Science.gov (United States)

    1982-06-18

    its in-house computer . These algorithms are then run against stored IR images of actual foreign tanks to determine the capabilities and -1il-rations of...34"ELECTE- S JUL 212U 0-1 MARCHESE 2. ALGORITHMS USED FOR ARMORED TARGET DETECTION: An algorithm is a set of logical rules or mathenatical instructions used...three adjacent pixels of the array sampled three times while the array rotates) an M2 value is computed . An M2 or variance map of the scene is thus

  10. Quench observation using quench antennas on RHIC IR quadrupole magnets

    International Nuclear Information System (INIS)

    Ogitsu, T.; Terashima, A.; Tsuchiya, K.; Ganetis, G.; Muratore, J.; Wanderer, P.

    1995-01-01

    Quench observation using quench antennas is now being performed routinely on RHIC dipole and quadrupole magnets. Recently, a quench antenna was used on a RHIC IR magnet which is heavily instrumented with voltage taps. It was confirmed that the signals detected in the antenna coils do not contradict the voltage tap signals. The antenna also detects a sign of mechanical disturbance which could be related to a training quench. This paper summarizes signals detected in the antenna and discusses possible causes of these signals

  11. Investigation of IR absorption spectra of oral cavity bacteria

    Science.gov (United States)

    Belikov, Andrei V.; Altshuler, Gregory B.; Moroz, Boris T.; Pavlovskaya, Irina V.

    1996-12-01

    The results of comparative investigation for IR and visual absorption spectra of oral cavity bacteria are represented by this paper. There are also shown the main differences in absorption spectra of such pure bacteria cultures as : E- coli, Candida, Staph, Epidermidis, and absorption spectra of bacteria colonies cultured in tooth root canals suspected to harbour several endodontical problems. The results of experimental research targeted to investigate an effect of such combined YAG:Nd and YAG:Cr; Tm; Ho laser parameters like: wavelength, energy density, average power and etc., to oral cavity bacteria deactivation are given finally.

  12. IR Thermography of International Space Station Radiator Panels

    Science.gov (United States)

    Koshti, Ajay; Winfree, WIlliam; Morton, Richard; Howell, Patricia

    2010-01-01

    Several non-flight qualification test radiators were inspected using flash thermography. Flash thermography data analysis used raw and second derivative images to detect anomalies (Echotherm and Mosaic). Simple contrast evolutions were plotted for the detected anomalies to help in anomaly characterization. Many out-of-family indications were noted. Some out-of-family indications were classified as cold spot indications and are due to additional adhesive or adhesive layer behind the facesheet. Some out-of-family indications were classified as hot spot indications and are due to void, unbond or lack of adhesive behind the facesheet. The IR inspection helped in assessing expected manufacturing quality of the radiators.

  13. Properties of CO Molecular Gas in IR Luminous Galaxies

    OpenAIRE

    Yao, Lihong

    2003-01-01

    We present the properties of the 12CO(1-0) and (3-2) line emission from the nuclei of 60 IR luminous SLUGS galaxies. This subsample is flux limited at S60 > 5.24 Jy with FIR luminosities mostly at LFIR > 10^10 Lo. The emission line strengths of 12CO(1-0) and (3-2) transitions were compared at a common resolution of ~ 15", and the line ratios r31 vary from 0.22 to 1.72 with a mean value of 0.66 for the sources observed, indicating a large spread of the degree of excitation of CO in the sample....

  14. Structure and properties of hydrocarbon radical cations in low-temperature matrices as studied by a combination of EPR and IR spectroscopy

    International Nuclear Information System (INIS)

    Feldman, V.I.

    1997-01-01

    Use of IR spectroscopy (as a supplement to EPR) may provide new insight into the problem of analysis of structure and properties of organic radical cations. In this work, the results of combined EPR/IR studies of the formation, structure and properties of hydrocarbon radical cations in halocarbon and solid rare gas matrices are discussed. Both IR and EPR studies were carried out with matrix deposited samples irradiated with fast electrons at 15 or 77 K. IR spectroscopic data were found to be helpful in three aspects: (i) characterization of the conformation and association and molecule-matrix interactions of the parent molecules; (ii) identification of diamagnetic products of the reactions of radical cations in ground and excited states; (iii) determining the characteristics of vibrational spectra of the radical cations, which are of primary interest for analysis of chemical bonding and reactivity of the radical cations. The applications of the combined approach are illustrated with examples of studies of several alkenes in Freon matrices and alkanes in solid rare gas matrices. The matrix effects on trapping and degradation of radical cations were interpreted as the result of variations in matrix electronic characteristics (IP, polarizability) and molecule-matrix interactions. (au) 48 refs

  15. Fe(II), Ni(II), Ru(II)

    Indian Academy of Sciences (India)

    Administrator

    Ru(II) and Os(II) complexes of modified phenanthroline ligands. C V SASTRI, D EASWARAMOORTHY #, ATHILAKSHMI #,. L GIRIBABU and B G MAIYA. School of Chemistry, University of Hyderabad, Hyderabad 500 046, India. #Present address: Crescent Engineering College, Vandalur, Chennai 600 048,. India.

  16. Equilibrium and kinetic studies of Cu (II), Cd (II), Pb (II) and Fe (II ...

    African Journals Online (AJOL)

    Langmuir isotherm and pseudo-second order models were used to analyse the equilibrium and kinetic experimental data respectively. Equilibrium experimental data of Cu (II), Cd (II), Pb (II) and Fe (II) adsorption onto cocoa pod fitted well to Langmuir model and the kinetic data also fitted well to the pseudo-second order ...

  17. Compact, Dual Channel, Mid-IR Laser Spectrometer Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Small Business Innovative Research Phase II proposal seeks to develop a dual channel, compact mid-infrared laser spectrometer for planetary atmosphere...

  18. Synthesis, characterization and anti-microbial activity of a novel macrocyclic ligand derived from the reaction of 2,6-pyridinedicarboxylic acid with homopiperazine and its Co(II), Ni(II), Cu(II), and Zn(II) complexes

    Science.gov (United States)

    Soleimani, Esmaiel

    2011-05-01

    The preparation of a novel macrocyclic ligand ( 1), N,N'-diethylhomopiperazinyl,2,6-pyridinedicarboxylate and its Co(II), Ni(II), Cu(II), and Zn(II) complexes are described. The ligand was prepared in EtOH from the reaction of dipotassium salt of 2,6-pyridinedicarboxylic acid with 1,2-dibromoethane in the presence of homopiperazine. Reaction of macrocyclic ligand ( 1) in EtOH with CoCl 2.6H 2O, NiCl 2.6H 2O, CuCl 2.2H 2O, and ZnCl 2·2H 2O yielded the complexes with the general formula [M(L)Cl 2] {where M = Co(II) ( 2), Ni(II) ( 3), Cu(II) ( 4), Zn ( 5), respectively}. The analysis of IR, 1H and 13C NMR spectral data of macrocyclic ligand ( 1) and its Zn(II) complex ( 5) together with their molar conductivity values, and the magnetic moments of the complexes suggest that the macrocyclic ligand ( 1) is bonded to metal(II) ions through two oxygen atoms of ester moiety and the two nitrogen atoms of homopiperazine ring. The electronic spectral data of these complexes in DMSO are in good agreement with the octahedral coordination of M(II) ions. The ligand field parameters for these complexes, i.e. splitting energy and Racah parameter were calculated to be 14,945 and 673 cm -1 for the Co(II) ( 2), 16,260 and 774 cm -1 for the Ni(II) ( 3) complexes respectively. The spliting energy of 17,262 cm -1 was obtained for the Cu(II) complex ( 4).

  19. MIXED-METAL COMPLEXES OF MIXED-VALENT DINUCLEAR RUTHENIUM(II,III CARBOXYLATE AND TETRACYANIDONICKELATE(II

    Directory of Open Access Journals (Sweden)

    Masahiro Mikuriya

    2014-06-01

    Full Text Available Mixed-metal chain complexes constructed from lantern-type dinuclear ruthenium(II,III carboxylate unit and tetracyanidonickelate(II, (PPh4n[Ru2(O2CCH34Ni(CN4]n•nH2O (1 and (PPh4n[Ru2{O2CC(CH33}4]3n[Ni(CN4]2n•2nH2O (2, where very weak antiferromagnetic interaction is operating, were synthesized and characterized by elemental analysis and IR and UV-vis spectroscopies and temperature dependence of magnetic susceptibilities (4.5—300K.

  20. High tumour cannabinoid CB1 receptor immunoreactivity negatively impacts disease-specific survival in stage II microsatellite stable colorectal cancer.

    Directory of Open Access Journals (Sweden)

    Sofia B Gustafsson

    Full Text Available BACKGROUND: There is good evidence in the literature that the cannabinoid system is disturbed in colorectal cancer. In the present study, we have investigated whether CB(1 receptor immunoreactive intensity (CB(1IR intensity is associated with disease severity and outcome. METHODOLOGY/PRINCIPAL FINDINGS: CB(1IR was assessed in formalin-fixed, paraffin-embedded specimens collected with a consecutive intent during primary tumour surgical resection from a series of cases diagnosed with colorectal cancer. Tumour centre (n = 483 and invasive front (n = 486 CB(1IR was scored from 0 (absent to 3 (intense staining and the data was analysed as a median split i.e. CB(1IR <2 and ≥2. In microsatellite stable, but not microsatellite instable tumours (as adjudged on the basis of immunohistochemical determination of four mismatch repair proteins, there was a significant positive association of the tumour grade with the CB(1IR intensity. The difference between the microsatellite stable and instable tumours for this association of CB(1IR was related to the CpG island methylation status of the cases. Cox proportional hazards regression analyses indicated a significant contribution of CB(1IR to disease-specific survival in the microsatellite stable tumours when adjusting for tumour stage. For the cases with stage II microsatellite stable tumours, there was a significant effect of both tumour centre and front CB(1IR upon disease specific survival. The 5 year probabilities of event-free survival were: 85±5 and 66±8%; tumour interior, 86±4% and 63±8% for the CB(1IR<2 and CB(1IR≥2 groups, respectively. CONCLUSIONS/SIGNIFICANCE: The level of CB(1 receptor expression in colorectal cancer is associated with the tumour grade in a manner dependent upon the degree of CpG hypermethylation. A high CB(1IR is indicative of a poorer prognosis in stage II microsatellite stable tumour patients.

  1. Data in support of FSH induction of IRS-2 in human granulosa cells: Mapping the transcription factor binding sites in human IRS-2 promoter

    Directory of Open Access Journals (Sweden)

    Surleen Kaur

    2016-03-01

    Full Text Available Insulin receptor substrate-2 (IRS-2 plays critical role in the regulation of various metabolic processes by insulin and IGF-1. The defects in its expression and/or function are linked to diseases like polycystic ovary syndrome (PCOS, insulin resistance and cancer. To predict the transcription factors (TFs responsible for the regulation of human IRS-2 gene expression, the transcription factor binding sites (TFBS and the corresponding TFs were investigated by analysis of IRS-2 promoter sequence using MatInspector Genomatix software (Cartharius et al., 2005 [1]. The ibid data is part of author׳s publication (Anjali et al., 2015 [2] that explains Follicle stimulating hormone (FSH mediated IRS-2 promoter activation in human granulosa cells and its importance in the pathophysiology of PCOS. Further analysis was carried out for binary interactions of TF regulatory genes in IRS-2 network using Cytoscape software tool and R-code. In this manuscript, we describe the methodology used for the identification of TFBSs in human IRS-2 promoter region and provide details on experimental procedures, analysis method, validation of data and also the raw files. The purpose of this article is to provide the data on all TFBSs in the promoter region of human IRS-2 gene as it has the potential for prediction of the regulation of IRS-2 gene in normal or diseased cells from patients with metabolic disorders and cancer.

  2. The insulin receptor substrate 1 (IRS1 in intestinal epithelial differentiation and in colorectal cancer.

    Directory of Open Access Journals (Sweden)

    Diana L Esposito

    Full Text Available Colorectal cancer (CRC is associated with lifestyle factors that affect insulin/IGF signaling, of which the insulin receptor substrate 1 (IRS1 is a key transducer. We investigated expression, localization and pathologic correlations of IRS1 in cancer-uninvolved colonic epithelium, primary CRCs with paired liver metastases and in vitro polarizing Caco2 and HT29 cells. IRS1 mRNA and protein resulted higher, relative to paired mucosa, in adenomas of familial adenomatous polyposis patients and in CRCs that overexpressed c-MYC, ß-catenin, InsRß, and IGF1R. Analysis of IRS1 immunostaining in 24 cases of primary CRC with paired colonic epithelium and hepatic metastasis showed that staining intensity was significantly higher in metastases relative to both primary CRC (P<0.01 and colonic epithelium (P<0.01. Primary and metastatic CRCs, compared to colonic epithelium, contained significantly higher numbers of IRS1-positive cells (P = 0.013 and P = 0.014, respectively. Pathologic correlations in 163 primary CRCs revealed that diffuse IRS1 staining was associated with tumors combining differentiated phenotype and aggressive markers (high Ki67, p53, and ß-catenin. In Caco 2 IRS1 and InsR were maximally expressed after polarization, while IGF1R was highest in pre-polarized cells. No nuclear IRS1 was detected, while, with polarization, phosphorylated IRS1 (pIRS1 shifted from the lateral to the apical plasma membrane and was expressed in surface cells only. In HT29, that carry mutations constitutively activating survival signaling, IRS1 and IGF1R decreased with polarization, while pIRS1 localized in nuclear spots throughout the course. Overall, these data provide evidence that IRS1 is modulated according to CRC differentiation, and support a role of IRS1 in CRC progression and liver metastatization.

  3. Spin orientations of the spin-half Ir{sup 4+} ions in Sr{sub 3}NiIrO{sub 6}, Sr{sub 2}IrO{sub 4}, and Na{sub 2}IrO{sub 3}: Density functional, perturbation theory, and Madelung potential analyses

    Energy Technology Data Exchange (ETDEWEB)

    Gordon, Elijah E.; Whangbo, Myung-Hwan, E-mail: mike-whangbo@ncsu.edu [Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204 (United States); Xiang, Hongjun [Key Laboratory of Computational Physical Sciences (Ministry of Education), State Key Laboratory of Surface Physics, Collaborative Innovation Center of Advanced Microstructures, and Department of Physics, Fudan University, Shanghai 200433 (China); Collaborative Innovation Center of Advanced Microstructures, Nanjing 210093 (China); Köhler, Jürgen [Max-Planck-Institut für Festkörperforschung, D-70569 Stuttgart (Germany)

    2016-03-21

    The spins of the low-spin Ir{sup 4+} (S = 1/2, d{sup 5}) ions at the octahedral sites of the oxides Sr{sub 3}NiIrO{sub 6}, Sr{sub 2}IrO{sub 4}, and Na{sub 2}IrO{sub 3} exhibit preferred orientations with respect to their IrO{sub 6} octahedra. We evaluated the magnetic anisotropies of these S = 1/2 ions on the basis of density functional theory (DFT) calculations including spin-orbit coupling (SOC), and probed their origin by performing perturbation theory analyses with SOC as perturbation within the LS coupling scheme. The observed spin orientations of Sr{sub 3}NiIrO{sub 6} and Sr{sub 2}IrO{sub 4} are correctly predicted by DFT calculations, and are accounted for by the perturbation theory analysis. As for the spin orientation of Na{sub 2}IrO{sub 3}, both experimental studies and DFT calculations have not been unequivocal. Our analysis reveals that the Ir{sup 4+} spin orientation of Na{sub 2}IrO{sub 3} should have nonzero components along the c- and a-axis directions. The spin orientations determined by DFT calculations are sensitive to the accuracy of the crystal structures employed, which is explained by perturbation theory analyses when interactions between adjacent Ir{sup 4+} ions are taken into consideration. There are indications implying that the 5d electrons of Na{sub 2}IrO{sub 3} are less strongly localized compared with those of Sr{sub 3}NiIrO{sub 6} and Sr{sub 2}IrO{sub 4}. This implication was confirmed by showing that the Madelung potentials of the Ir{sup 4+} ions are less negative in Na{sub 2}IrO{sub 3} than in Sr{sub 3}NiIrO{sub 6} and Sr{sub 2}IrO{sub 4}. Most transition-metal S = 1/2 ions do have magnetic anisotropies because the SOC induces interactions among their crystal-field split d-states, and the associated mixing of the states modifies only the orbital parts of the states. This finding cannot be mimicked by a spin Hamiltonian because this model Hamiltonian lacks the orbital degree of freedom, thereby leading to the spin-half syndrome. The

  4. Eight joint BER II and BESSY II users meeting. Abstracts

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2016-07-01

    The following topics were dealt with: Accelerator operation and projecs, photon science and instrumentation at BESSY II, status of energy materials in-situ Lab at BESSY II, high resolution spectrometer PEAXIS at BESSY II, sample environment at BESSY II, molecular control mechanisms in the Brr2 RNA helicase for efficient and regulated splicing, the Li conversion reaction of 4CoFe{sub 2}O{sub 4} nanoparticles, buried interfaces in lithium ion batteries probed with HAXPES, ARPES studies of the STO(001) 2DEG, all-in/all-out magnetic order in rare earth iridates, oxygen reduction reaction on graphene in Li-air batteries, electronic order in high-T{sub c} superconductors, in-siu observation of novel switching phenomena in highly porous metal-organic frameworks, photoinduced demagnetization and insulator-to-metal transition in ferromagnetic insulating BaFeO{sub 3} thin films, ARPES measurement of the ferroelectric bulk Rashba system GeTe, bisphenol A on Cu(111) and Ag(111), reverse water-gas shift or Sabathier methanation on N(110), structural studies of molecular machines, multi-MHz time-of-flight electronic band-structure imaging of graphene on Ir(111), diffusion pathways in ion conductors, ground-state potential energy surfaces around selected atoms from resonant inelastic X-ray scattering, solar energy in an emerging country, in-situ neutron analysis of electrode materials for electrochemical energy storage, structure and transport properties in thermoelectric skutterudites, investigation of the interphase formation on solid lithium-ion conductors by neutron reflectometry, load partitin and damage characterization of cast AlSi{sub 12}CuMgNi alloy with ceramic reinforcement, methane adsorption in highly porous metal-organics, structure and magnetic interactions in dimer system Ba{sub (3-x)}Sr{sub x}Cr{sub 2}O{sub 8}, distribution of S in C-S nanocomposites, current status of HFM-EXED FACITIY; SPIN NEAMTICITY IN s=1/2 frustrated zigzag chaIN β-TeVO{sub 4}, electronic

  5. Structural, thermal, biological and semiconducting properties of Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and VO(IV) complexes of Schiff base derived from resdiacetophenone and S-benzyldithiocarbazate

    International Nuclear Information System (INIS)

    Makode, J.T.; Bhadange, S.G.; Aswar, A.S.

    2003-01-01

    A series of Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and VO(IV) complexes with Schiff base derived from resdiacetophenone and S-benzyldithiocarbazate have been synthesized and characterized by elemental analysis, magnetic moment, IR and electronic spectral studies and thermal analysis. The Schiff base functions as a binucleating tridentate chelating agent and coordinates via the deprotonated phenolic oxygen, azomethine nitrogen and thioenolate sulphur atoms to the metal ion favouring the formation of bimetallic complexes. From dynamic TG data, activation energy and other kinetic parameters have been computed using Freeman-Carroll-Wentworth and Coats-Redfern methods. Electrical conductivity of the complexes have also been studied between 313-473 in pellet forms and the complexes are found to exhibit semiconducting behaviour. The antimicrobial activity of the ligand and its complexes have been screened against various microorganisms and all of them found to be moderately active against the organisms. (author)

  6. Crosstalk between adiponectin and IGF-IR in breast cancer

    Directory of Open Access Journals (Sweden)

    Loredana eMauro

    2015-07-01

    Full Text Available Obesity is a chronic and multifactorial disorder that is reaching epidemic proportions. It is characterized by an enlarged mass of adipose tissue caused by a combination of size increase of preexisting adipocytes (hypertrophy and de novo adipocyte differentiation (hyperplasia. Obesity is related to many metabolic disorders like hypertension, type 2 diabetes, metabolic syndrome, cardiovascular disease, and it is associated with an increased risk of cancer development in different tissues including breast. Adipose tissue is now regarded as not just a storage reservoir for excess energy, but rather as an endocrine organ, secreting a large number of bioactive molecules called adipokines. Among these, adiponectin represents the most abundant adipose tissue-excreted protein, which exhibits insulin-sensitizing, anti-inflammatory and antiatherogenic properties. The serum concentrations of adiponectin are inversely correlated with body mass index. Recently, low levels of plasma adiponectin have been associated with an increased risk for obesity-related cancers and development of more aggressive phenotype, concomitantly with alterations in the bioavailability of Insulin-like Growth Factor-I (IGF-I and IGF-I Receptor (IGF-IR signaling pathways. In this review we discuss the cross-talk between adiponectin/AdipoR1 and IGF-I/IGF-IR in breast cancer.

  7. Uncooled IR imager with 5-mK NEDT

    Science.gov (United States)

    Amantea, Robert; Knoedler, C. M.; Pantuso, Francis P.; Patel, Vipulkumar; Sauer, Donald J.; Tower, John R.

    1997-08-01

    The bi-material concept for room-temperature infrared imaging has the potential of reaching an NE(Delta) T approaching the theoretical limit because of its high responsivity and low noise. The approach, which is 100% compatible with silicon IC foundry processing, utilizes a novel combination of surface micromachining and conventional integrated circuits to produce a bimaterial thermally sensitive element that controls the position of a capacitive plate coupled to the input of a low noise MOS amplifier. This approach can achieve the high sensitivity, the low weight, and the low cost necessary for equipment such as helmet mounted IR viewers and IR rifle sights. The pixel design has the following benefits: (1) an order of magnitude improvement in NE(Delta) T due to extremely high sensitivity and low noise, (2) low cost due to 100% silicon IC compatibility, (3) high image quality and increased yield due to ability to do offset and sensitivity corrections on the imager, pixel-by-pixel; (4) no cryogenic cooler and no high vacuum processing; and (5) commercial applications such as law enforcement, home security, and transportation safety. Two designs are presented. One is a 50 micrometer pixel using silicon nitride as the thermal isolation element that can achieve 5 mK NE(Delta) T; the other is a 29 micrometer pixel using silicon carbide that provides much higher thermal isolation and can achieve 10 mK NE(Delta) T.

  8. Multiplexing of spatial modes in the mid-IR region

    Science.gov (United States)

    Gailele, Lucas; Maweza, Loyiso; Dudley, Angela; Ndagano, Bienvenu; Rosales-Guzman, Carmelo; Forbes, Andrew

    2017-02-01

    Traditional optical communication systems optimize multiplexing in polarization and wavelength both trans- mitted in fiber and free-space to attain high bandwidth data communication. Yet despite these technologies, we are expected to reach a bandwidth ceiling in the near future. Communications using orbital angular momentum (OAM) carrying modes offers infinite dimensional states, providing means to increase link capacity by multiplexing spatially overlapping modes in both the azimuthal and radial degrees of freedom. OAM modes are multiplexed and de-multiplexed by the use of spatial light modulators (SLM). Implementation of complex amplitude modulation is employed on laser beams phase and amplitude to generate Laguerre-Gaussian (LG) modes. Modal decomposition is employed to detect these modes due to their orthogonality as they propagate in space. We demonstrate data transfer by sending images as a proof-of concept in a lab-based scheme. We demonstrate the creation and detection of OAM modes in the mid-IR region as a precursor to a mid-IR free-space communication link.

  9. Measuring the acceleration due to gravity using an IR transceiver

    International Nuclear Information System (INIS)

    AbdElazem, Sohaib; Al-Basheer, Watheq

    2015-01-01

    In this paper, we present a new technique to study the dynamics of a free-falling object in a lab setting and to measure the acceleration due to gravity g using a simple and economic setup. The precise measurement of time taken for an object to fall freely passing an infrared (IR) transceiver is utilized to deduce the acceleration due to gravity. The reflected IR intensity from a free-falling 0.19 m rod of equally spaced white stripes of 0.01 m is detected and sent to a digital oscilloscope to observe and record the falling time period of each stripe. By fitting recorded elapsed falling times to the well-known quadratic equation of motion under constant acceleration, an accurate value of the acceleration due to gravity of g = 9.8092 ± 0.0384 m s −2 is obtained. In addition to its accuracy, the proposed technique is safer and more economic than most of the other currently used setups to determine g in undergraduate teaching labs. This study may provide undergraduate lab instructors with an efficient teaching technique for a traditional classroom experiment. (paper)

  10. Monitoring combat wound healing by IR hyperspectral imaging

    Science.gov (United States)

    Howle, Chris R.; Spear, Abigail M.; Gazi, Ehsan; Crane, Nicole J.

    2016-03-01

    In recent conflicts, battlefield injuries consist largely of extensive soft injuries from blasts and high energy projectiles, including gunshot wounds. Repair of these large, traumatic wounds requires aggressive surgical treatment, including multiple surgical debridements to remove devitalised tissue and to reduce bacterial load. Identifying those patients with wound complications, such as infection and impaired healing, could greatly assist health care teams in providing the most appropriate and personalised care for combat casualties. Candidate technologies to enable this benefit include the fusion of imaging and optical spectroscopy to enable rapid identification of key markers. Hence, a novel system based on IR negative contrast imaging (NCI) is presented that employs an optical parametric oscillator (OPO) source comprising a periodically-poled LiNbO3 (PPLN) crystal. The crystal operates in the shortwave and midwave IR spectral regions (ca. 1.5 - 1.9 μm and 2.4 - 3.8 μm, respectively). Wavelength tuning is achieved by translating the crystal within the pump beam. System size and complexity are minimised by the use of single element detectors and the intracavity OPO design. Images are composed by raster scanning the monochromatic beam over the scene of interest; the reflection and/or absorption of the incident radiation by target materials and their surrounding environment provide a method for spatial location. Initial results using the NCI system to characterise wound biopsies are presented here.

  11. Limewashed mural paintings as seen by VIS-IR reflectography

    Science.gov (United States)

    Fontana, R.; Striova, J.; Barucci, M.; Pampaloni, E.; Raffaelli, M.; Pezzati, L.; Mariotti, P.

    2015-06-01

    Near-Infrared (NIR) reflectography is a well-established technique for painting diagnostics, offering a fundamental contribution to the conservation of paintings. Since the '80s it has been routinely applied to study the execution technique of the author, as well as the presence of pentimenti, retouches, integrations or underdrawing. In the last decades IR reflectography has been extended to the visible (VIS) spectral range, providing information about the pigment composition. Up to now the multispectral analysis is still applied at an experimental level, as the processing of the image set is not straightforward. Rarely multispectral VIS-IR application has been applied to frescos, probably due to the lack, in most cases, of a scattering background. In this work we present the results provided by a multispectral scanning device based on single sensor acquisition, working in the 380-2500 nm spectral range, that is a laboratory prototype specifically built for research-grade imaging. The technique have been applied on a mock up simulating a mural painting substrate where an underdrawing, made of either carbon or iron-gall ink, was covered by different surface layers of limewash, the so-called scialbo.

  12. UV-IR mixing in nonassociative Snyder ϕ4 theory

    Science.gov (United States)

    Meljanac, Stjepan; Mignemi, Salvatore; Trampetic, Josip; You, Jiangyang

    2018-03-01

    Using a quantization of the nonassociative and noncommutative Snyder ϕ4 scalar field theory in a Hermitian realization, we present in this article analytical formulas for the momentum-conserving part of the one-loop two-point function of this theory in D -, 4-, and 3-dimensional Euclidean spaces, which are exact with respect to the noncommutative deformation parameter β . We prove that these integrals are regularized by the Snyder deformation. These results indicate that the Snyder deformation does partially regularize the UV divergences of the undeformed theory, as it was proposed decades ago. Furthermore, it is observed that different nonassociative ϕ4 products can generate different momentum-conserving integrals. Finally, most importantly, a logarithmic infrared divergence emerges in one of these interaction terms. We then analyze sample momentum nonconserving integral qualitatively and show that it could exhibit IR divergence too. Therefore, infrared divergences should exist, in general, in the Snyder ϕ4 theory. We consider infrared divergences at the limit p →0 as UV/IR mixings induced by nonassociativity, since they are associated to the matching UV divergence in the zero-momentum limit and appear in specific types of nonassociative ϕ4 products. We also discuss the extrapolation of the Snyder deformation parameter β to negative values as well as certain general properties of one-loop quantum corrections in Snyder ϕ4 theory at the zero-momentum limit.

  13. Tenoxicam-kollicoat IR binary systems: physicochemical and biological evaluation.

    Science.gov (United States)

    Ibrahim, Mohamed Abbas

    2014-01-01

    Tenoxicam (TNX) binary systems in Kollicoat IR (KL) matrix were prepared in different drug: polymer ratios using kneading and spray-drying method. The prepared binary systems were characterized for drug dissolution rate, differential scanning calorimetry (DSC), IR spectroscopy and x-ray diffractometry. The results showed that the drug dissolution rate was remarkably enhanced by incorporating it in the KL matrix either by kneading or spray-drying, and the dissolution rate was increased by decreasing the drug weight ratio. The DSc and x-ray studies revealed the presence of TNX in less crystalline or amorphous state in its-KL binary systems. Moreover, the spray-dried TNX-KL system in 1:4 ratio, that exhibited the faster dissolution rate, was formulated in oral disintegrating tablets (ODTs). The data indicated that a fast disintegration and higher drug dissolution rate was achieved in case of the ODTs containing the spray-dried form compared to the ODTS containing untreated drug or the commercial tablet (Epicotil). Also, the drug exhibited significantly (p < 0.01) faster onset of the anti-inflammatory analgesic activities in case of the ODTs containing the spray-dried form, that was superior to that observed with both the commercial tablet product and the ODTS containing untreated drug.

  14. Quantifying photometric observing conditions on Paranal using an IR camera

    Science.gov (United States)

    Kerber, Florian; Querel, Richard R.; Hanuschik, Reinhard

    2014-08-01

    A Low Humidity and Temperature Profiling (LHATPRO) microwave radiometer, manufactured by Radiometer Physics GmbH (RPG), is used to monitor sky conditions over ESO's Paranal observatory in support of VLT science operations. In addition to measuring precipitable water vapour (PWV) the instrument also contains an IR camera measuring sky brightness temperature at 10.5 μm. Due to its extended operating range down to -100 °C it is capable of detecting very cold and very thin, even sub-visual, cirrus clouds. We present a set of instrument flux calibration values as compared with a detrended fluctuation analysis (DFA) of the IR camera zenith-looking sky brightness data measured above Paranal taken over the past two years. We show that it is possible to quantify photometric observing conditions and that the method is highly sensitive to the presence of even very thin clouds but robust against variations of sky brightness caused by effects other than clouds such as variations of precipitable water vapour. Hence it can be used to determine photometric conditions for science operations. About 60 % of nights are free of clouds on Paranal. More work will be required to classify the clouds using this technique. For the future this approach might become part of VLT science operations for evaluating nightly sky conditions.

  15. Infrared (IR) photon-sensitive spectromicroscopy in a cryogenic environment

    Science.gov (United States)

    Pereverzev, Sergey

    2016-06-14

    A system designed to suppress thermal radiation background and to allow IR single-photon sensitive spectromicroscopy of small samples by using both absorption, reflection, and emission/luminescence measurements. The system in one embodiment includes: a light source; a plurality of cold mirrors configured to direct light along a beam path; a cold or warm sample holder in the beam path; windows of sample holder (or whole sample holder) are transparent in a spectral region of interest, so they do not emit thermal radiation in the same spectral region of interest; a cold monochromator or other cold spectral device configured to direct a selected fraction of light onto a cold detector; a system of cold apertures and shields positioned along the beam path to prevent unwanted thermal radiation from arriving at the cold monochromator and/or the detector; a plurality of optical, IR and microwave filters positioned along the beam path and configured to adjust a spectral composition of light incident upon the sample under investigation and/or on the detector; a refrigerator configured to maintain the detector at a temperature below 1.0K; and an enclosure configured to: thermally insulate the light source, the plurality of mirrors, the sample holder, the cold monochromator and the refrigerator.

  16. MTG-IRS: from raw measurements to calibrated radiances

    Science.gov (United States)

    Coppens, Dorothee; Theodore, Bertrand; Klaes, Dieter

    2017-09-01

    The Meteosat Third Generation (MTG) series of future European geostationary meteorological satellites consists of two types of satellites, the imaging satellites (MTG-I) and the sounding satellites (MTG-S). The Infrared Sounder (IRS) is one of the two instruments hosted on board the MTG-S satellites. The scope of the IRS mission is to provide the user community with information on time evolution of humidity and temperature distribution, as function of latitude, longitude and altitude. Regarding time and space sampling, the entire Earth disk will be covered, with particular focus on Europe, which will be revisited every 30 minutes. This paper presents a synthetic overview of the mission and the instrument, and will go through the level 1 processing chain which takes instrument raw data to obtain spectrally and radiometrically calibrated and geolocalised radiances, called level 1b products. A discussion will be presented around the radiances uniformisation in space, spectral range and time and its impact for the users community.

  17. Parallel visual information retrieval in VizIR

    Science.gov (United States)

    Eidenberger, Horst

    2004-10-01

    This paper describes how parallel retrieval is implemented in the content-based visual information retrieval framework VizIR. Generally, two major use cases for parallelisation exist in visual retrieval systems: distributed querying and simultaneous multi-user querying. Distributed querying includes parallel query execution and querying multiple databases. Content-based querying is a two-step process: transformation of feature space to distance space using distance measures and selection of result set elements from distance space. Parallel distance measurement is implemented by sharing example media and query parameters between querying threads. In VizIR, parallelisation is heavily based on caching strategies. Querying multiple distributed databases is already supported by standard relational database management systems. The most relevant issues here are error handling and minimisation of network bandwidth consumption. Moreover, we describe strategies for distributed similarity measurement and content-based indexing. Simultaneous multi-user querying raises problems such as caching of querying results and usage of relevance feedback and user preferences for query refinement. We propose a 'real' multi-user querying environment that allows users to interact in defining queries and browse through result sets simultaneously. The proposed approach opens an entirely new field of applications for visual information retrieval systems.

  18. Crystal growth of Mg2Si for IR-detector

    Science.gov (United States)

    Tokairin, Toshio; Ikeda, Junya; Udono, Haruhiko

    2017-06-01

    Semiconducting Mg2Si is known as a thermoelectric material and recently attracts increasing attention as a Si-based, low-cost and environmental friendly material for an infrared (IR) sensor. With the aim of producing cost-effective Mg2Si single crystal substrates for the IR sensor, we have investigated single crystal growth of Mg2Si using the vertical Bridgman (VB) and micro-pulling-down (μ-PD) methods in open-system. Since the evaporation of Mg was not suppressed during the μ-PD, the composition of the Mg2Si single crystal grown by this method was not stoichiometric. On the other hand, single crystalline Mg2Si was produced by the VB method using the Si-treated inner carbon seat and BN-coated carbon crucible. The Mg2Si crystals with a diameter of 30 mm were grown at a growth rate of 0.5 mm/min and a temperature gradient of 5 °C/cm. The electron density and mobility of the crystal so obtained were 1.8×1017 cm-3 and 283 cm2V-1s-1 at 300 K, respectively. The high electron density was due to contamination from the impurities presented in the crucible.

  19. Dual IGF-I/II-neutralizing antibody MEDI-573 potently inhibits IGF signaling and tumor growth.

    Science.gov (United States)

    Gao, Jin; Chesebrough, Jon W; Cartlidge, Susan A; Ricketts, Sally-Ann; Incognito, Leonard; Veldman-Jones, Margaret; Blakey, David C; Tabrizi, Mohammad; Jallal, Bahija; Trail, Pamela A; Coats, Steven; Bosslet, Klaus; Chang, Yong S

    2011-02-01

    Insulin-like growth factors (IGF), IGF-I and IGF-II, are small polypeptides involved in regulating cell proliferation, survival, differentiation, and transformation. IGF activities are mediated through binding and activation of IGF-1R or insulin receptor isoform A (IR-A). The role of the IGF-1R pathway in promoting tumor growth and survival is well documented. Overexpression of IGF-II and IR-A is reported in multiple types of cancer and is proposed as a potential mechanism for cancer cells to develop resistance to IGF-1R-targeting therapy. MEDI-573 is a fully human antibody that neutralizes both IGF-I and IGF-II and inhibits IGF signaling through both the IGF-1R and IR-A pathways. Here, we show that MEDI-573 blocks the binding of IGF-I and IGF-II to IGF-1R or IR-A, leading to the inhibition of IGF-induced signaling pathways and cell proliferation. MEDI-573 significantly inhibited the in vivo growth of IGF-I- or IGF-II-driven tumors. Pharmacodynamic analysis demonstrated inhibition of IGF-1R phosphorylation in tumors in mice dosed with MEDI-573, indicating that the antitumor activity is mediated via inhibition of IGF-1R signaling pathways. Finally, MEDI-573 significantly decreased (18)F-fluorodeoxyglucose ((18)F-FDG) uptake in IGF-driven tumor models, highlighting the potential utility of (18)F-FDG-PET as a noninvasive pharmacodynamic readout for evaluating the use of MEDI-573 in the clinic. Taken together, these results demonstrate that the inhibition of IGF-I and IGF-II ligands by MEDI-573 results in potent antitumor activity and offers an effective approach to selectively target both the IGF-1R and IR-A signaling pathways.

  20. Effect of cyclosporin A administration on the biodistribution and multipinhole {mu}SPECT imaging of [{sup 123}I]R91150 in rodent brain

    Energy Technology Data Exchange (ETDEWEB)

    Blanckaert, P.; Burvenich, I.; Bruyne, S. de; Moerman, L.; Wyffels, L.; Vos, F. de [Faculty of Pharmaceutical Sciences, Ghent University, Laboratory for Radiopharmacy, Gent (Belgium); Staelens, S. [Ghent University - IBBT, MEDISIP, Faculty of Engineering, Gent (Belgium)

    2009-03-15

    P-glycoprotein (Pgp) is an efflux protein found amongst other locations in the blood-brain barrier. It is important to investigate the effect of Pgp modulation on clinically used brain tracers, because brain uptake of the tracer can be altered by blocking of the Pgp efflux transporter. The function of Pgp can be blocked with cyclosporin A. We investigated the effect of cyclosporin A administration on the biodistribution of [{sup 123}I]R91150 in rodents, and the effect of Pgp blocking on the quality of multipinhole {mu}SPECT imaging with [{sup 123}I]R91150. The influence of increasing doses of cyclosporin A on the brain uptake of [{sup 123}I]R91150 was investigated in NMRI mice. A biodistribution study with [{sup 123}I]R91150 was performed in male Sprague-Dawley rats pretreated with cyclosporin A and not pretreated. Brain uptake of [{sup 123}I]R91150 after cyclosporin A injection was compared to the brain uptake in untreated animals, and a displacement study with ketanserin was performed in both groups. A multipinhole {mu}SPECT brain imaging study was also performed using a Milabs U-SPECT-II camera in male Sprague-Dawley rats. To exclude the effect of possible metabolites, a metabolite study was also performed. At the highest cyclosporin A dose (50 mg/kg), a sevenfold increase in brain radioactivity concentration was observed in NMRI mice. Also, a dose-response relationship was established between the dose of cyclosporin A and the brain uptake of [{sup 123}I]R91150 in mice. Compared to the control group, a five-fold increase in [{sup 123}I]R91150 radioactivity concentration was observed in the brain of Sprague-Dawley rats after cyclosporin A treatment (50 mg/kg). Radioactivity concentration in the frontal cortex increased from 0.24{+-}0.0092 to 1.58{+-}0.097% injected dose per gram of tissue after treatment with cyclosporin A (at the 1-h time-point). Blood radioactivity concentrations did not increase to the same extent. The cortical activity was displaced by