WorldWideScience

Sample records for emission ceilings eu

  1. Ammonia emissions in Europe

    DEFF Research Database (Denmark)

    Jacobsen, Brian H.

    2012-01-01

    The NEC (National Emission Ceiling) directive has set targets for the 2010 ammonia emissions from a number of European countries. The target will be reached by most EU-countries and the total emission for EU-27 has been reduced by 22% from 1990 to 2007. Denmark is one of the countries with the la......The NEC (National Emission Ceiling) directive has set targets for the 2010 ammonia emissions from a number of European countries. The target will be reached by most EU-countries and the total emission for EU-27 has been reduced by 22% from 1990 to 2007. Denmark is one of the countries...

  2. Climate, energy and emissions trading in the EU and DK

    International Nuclear Information System (INIS)

    Dyck-Madsen, S.

    2004-04-01

    European Union member states are facing two serious challenges: human-induced climatic changes and oil shortage. Evidence that human-induced global heating is threatening the climatic balance is piling up and the conflicts over the last oil resources are becoming critical. The European Union has neither large oil resources nor foreign-political or military power to conquer additional oil resources. The EU Commission's awareness of these facts is influencing the EU energy and climate policy. Recently EU launched the directive on carbon dioxide emissions trading within certain energy-heavy sectors. The greenhouse gas emission allowance trading directive requires a national ceiling on the allocation of CO 2 quotas for the heavy industry and energy sectors, thus adapting the quantity of quotas to the Kyoto requirements. This requirement can be quite extensive for the sectors affected by the greenhouse gas emission allowance trading directive, if national governments choose to abstain from political intervention in order to reduce release of greenhouse gases in sectors outside the emissions trading, e.g. agriculture, transportation, households, and smaller industry and service. Lack of action in these sectors will require the governments to impose either large burdens or use of national Joint Implementation and Clean Development agreements on the heavy industry and energy sectors outside national borders, thus conflicting with the Kyoto Protocol. (BA)

  3. Evaluation of progress under the EU National Emission Ceilings Directive. Progress towards EU air quality objectives

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-10-15

    The objective of this report was to assess to what extent the NEC Directive's environmental and health objectives concerning acidification, eutrophication and ground-level ozone exposure for the year 2010 have been achieved. The main basis for the assessment is the emission inventory data officially reported by Member States. The analysis was conducted by using the same scientific methods of 2001 (original knowledge) and 2010 (present knowledge) that support European air pollution abatement policies. The original knowledge consisted of modelling concentrations and exposure using the older Lagrangian EMEP model (utilising a 150 x 150 km{sup 2} grid for the computation of grid-average S and N depositions and ground-level ozone concentrations, together with the 1998 European critical load database for assessing the risk of acidification and eutrophication). The assessment performed on the basis of present knowledge used the current Eulerian EMEP model on a 50 x 50 km{sup 2} grid for the computation of ecosystem-specific depositions and ground-level ozone concentrations, in combination with the 2008 European critical loads database. When assessing progress using original knowledge, the NEC Directive's interim environmental acidification objective has been met in almost all grid cells, while the eutrophication objective - provided in a footnote within the NEC Directive and which was formulated on the European Union area as a whole - has been met both for the EU-15 and the EU-27 regions as a whole. If, in contrast, the eutrophication objective had been required to be met in individual grid cells (as for acidification) or in individual Member States, it would be exceeded in many grid cells and in 11 Member States. While acidification has been markedly reduced, eutrophication is now recognised as a major environmental problem in Europe, especially in the context of its potential adverse impacts on biodiversity. An assessment using present knowledge indicates that

  4. Strategic partitioning of emission allowances under the EU Emission Trading Scheme

    Energy Technology Data Exchange (ETDEWEB)

    Boehringer, Christoph [Univ. of Oldenburg, Department of Economics, and Centre for European Economic Research (ZEW) (Germany); Rosendahl, Knut Einar [Statistics Norway, Research Department, Pob. 8131 Dep., N-0033 Oslo (Norway)

    2009-08-15

    The EU Emission Trading Scheme (ETS) is breaking new ground in the experience with emission trading regimes across multiple jurisdictions. Since the EU ETS covers only some industries, it implies a hybrid emission control scheme where EU member states must apply complementary domestic emissions regulation for the non-trading sectors of their economies in order to comply with their national emission reduction targets. The EU ETS thus opens up for strategic partitioning of national emissions budgets by the member states between trading and non-trading sectors. In this paper we examine the potential effects of such strategic behavior on compliance cost and emissions prices. We show that concerns on efficiency losses from strategic partitioning are misplaced. In turn, our analysis implicitly indicates significant political economy forces behind EU climate policy, as both cost-effective and strategically motivated partitioning of national emission budgets are far off from the actual break-down between trading and non-trading sectors. (author)

  5. EU Energy Law. Volume 4. The EU Greenhouse Gas Emissions Trading Scheme

    International Nuclear Information System (INIS)

    Delbeke, J.; Hartridge, O.; Lefevere, J.; Meadows, D.; Runge-Metzger, A.; Slingenberg, Y.; Vainio, M.; Vis, P.; Zapfel, P.

    2006-06-01

    Gives valuable insights in the why's, how's, trade-offs, and critical design choices of the Emission Trading System of the European Union (EU ETS). The chapters deal with (1) The EU ETS: the result of a decade of policy action on the economic dimension of EU environmental policy; (2) The international climate policy developments of the 1990s: UNFCCC, the Kyoto Protocol, the Marrakech Agreements and the EU's Kyoto ratification decision; (3) Emissions trading: What is it? Design options and misconceptions; (4) The EU ETS Directive 2003/87/EEC explained; (5) The EU ETS Linking Directive explained; (6) The economic efficiency benefits of the EU ETS; (7) The NAP I experience; (8) The key importance of the Registry Regulation and of solid monitoring and verification; and (9) The potential role of the EU ETS for the elaboration of the post-2012 international climate regime. Conclusions are in chapter 10

  6. The EU Greenhouse Gas Emissions Trading Scheme

    NARCIS (Netherlands)

    Woerdman, Edwin; Woerdman, Edwin; Roggenkamp, Martha; Holwerda, Marijn

    2015-01-01

    This chapter explains how greenhouse gas emissions trading works, provides the essentials of the Directive on the European Union Emissions Trading Scheme (EU ETS) and summarizes the main implementation problems of the EU ETS. In addition, a law and economics approach is used to discuss the dilemmas

  7. EU emissions trading: Distinctive behavior of small companies

    OpenAIRE

    Naegele, Helene; Zaklan, Aleksandar

    2016-01-01

    The EU Emissions Trading System (EU ETS) is the cornerstone of the European Union's climate policy and covers just under half of the EU's greenhouse gas emissions. More than ten years since the EU ETS was first introduced, there continues to be substantial research interest regarding its functioning and the behavior of participating companies. DIW Berlin conducted three econometric studies based on microdata at company and/or installation level. The findings suggest that, overall, there are o...

  8. EU GHG Emission Targets: 'Mind the gap'

    International Nuclear Information System (INIS)

    Lojodice, Ilaria

    2012-06-01

    In Durban, the European Union has been able to overcome the traditional dividing lines between developed and developing countries, setting a 'road-map' for a post-Kyoto framework. This would see countries conclude an 'agreed outcome with legal force' on emissions targets by 2015. Was this a key goal or a partial success for EU climate diplomacy? The main concerns are that the second commitment period would only come into force by 2021, and that necessary carbon cuts are not be increased before 2020. The direct by-product for the EU victory has been the awakening of the debate about raising emissions reductions to 30%. In fact, as stated in the Low Carbon Road-map, the EU has adopted a target of cutting emissions by 20% to by 2020, and of moving to a 30% reduction target if the conditions are right. Is this finally the time for Europe to improve its performance, even if it means going it alone? The EU has always been a strong defender of the Kyoto Protocol under certain constraints, such as developing and emerging countries entering into the deal. But does the EU have all the right assets to fight for this? Where is Europe in achieving its 2020 goal? In essence, this paper provides an estimate of what EU emissions could be in 2020, and how they stand compared to Kyoto and 20% objective of the 2020 strategy. (author)

  9. NEC-2020 emission reduction scenarios

    DEFF Research Database (Denmark)

    Slentø, Erik; Nielsen, Ole-Kenneth; Hoffmann, Leif

    The upcoming NEC-2020 EU directive sets up emission ceilings for NOX, SO2, NH3, NMVOC and PM in order to meet the environmental exposure targets of the Thematic Strategy. This report contains an assessment of intermediary emission reduction scenarios for Denmark, computed by the GAINS model 2007,......, which serves as the basis for the pending negotiations in EU. The assessment is brought up to date by including a brief evaluation of the new reduction scenarios published in 2008, founding the European Commission NEC-2020 directive proposal....

  10. Emissions Trading - An Internet site on the EU Emissions Trading Scheme (ETS); Utslappshandel - En Internetsida om handel med utslaeppsraetter inom EU

    Energy Technology Data Exchange (ETDEWEB)

    2009-07-01

    Utslappshandel.se is a one-stop shop for overall information about the EU Emissions Trading Scheme (ETS) as applied in Sweden (the site is available in Swedish and English). It also offers a gateway to the Swedish Emissions Trading Registry (SUS), where companies report their transactions on an ongoing basis and surrender emission allowances once a year. The Swedish Energy Agency is in charge of the Swedish registry. The Swedish Environmental Protection Agency decides on the allocation of emission allowances and is responsible for following up companies' annual reporting on their CO{sub 2} emissions. The EU ETS is expected to cover installations equivalent to approximately 50 per cent of total CO{sub 2} emissions in the EU. In Sweden, it is expected to cover only 40 per cent of emissions, mainly owing to the very low level of fossil electricity production

  11. Market analysis and risk management of EU emissions trading

    International Nuclear Information System (INIS)

    Ollikainen, M.; Ollikka, K.; Aatola, P.; Ahonen, H.M.; Pohjola, T.; Kumpulainen, A.; Lappalainen, E.

    2006-01-01

    The first EU emissions trading period commenced on 1 January 2005. It implies new challenges to companies included in the scheme. A central challenge is the uncertainty related to the markets. In order to manage risks and profitability companies need to be able to estimate future price developments of emission allowances. University of Helsinki is conducting a research project in cooperation with Helsinki University of Technology that will provide necessary information for analyzing emission allowance markets and create risk management competence. The objectives of the research project are 1) to develop a price estimation model for EU emission allowances and 2) to develop risk management competence related to EU emission allowances. With the price estimation model the short-term price developments of EU emission allowances can be estimated. By utilizing the model companies can reduce uncertainties related to the markets. The project will also deliver a general risk management model for emission allowances that aims at improving competitiveness of companies. (orig.)

  12. EU Emission Trading - better job second time around?

    International Nuclear Information System (INIS)

    Schleich, Joachim |; Betz, Regina; Rogge, Karoline |

    2007-01-01

    The EU Emission Trading Scheme (EU ETS) for CO 2 -emissions from energy and industry installations reflects a paradigm shift towards market-based instruments for environmental policy in the EU. The centerpieces of the EU ETS are National Allocation Plans (NAPs), which individual Member States (MS) design for each phase. NAPs state the total quantity of allowances available in each period (ET-budget) and determine how MS allocate allowances to individual installations. The NAPs thus govern investments and innovation in energy efficient technologies and the energy sector. In terms of distribution, they predetermine winners and losers. In this paper we analyze and evaluate 25 NAPs submitted to the European Commission (EC) for phase 2 (2008-2012) of the EU ETS. At the macro level, we assess whether the submitted ET-budgets are stringent, and whether they imply a cost-efficient split of the required emission reductions between the EU ETS sectors (energy and industry) and the remaining sectors (transportation, tertiary and households). Comparing the submitted ET-budgets with those already approved by the EC suggests that the EC's decisions significantly improved the effectiveness and economic efficiency of the EU ETS. But given the high share of Kyoto Mechanisms companies are allowed to use, the EU ETS is unlikely to require substantial emission reductions within the EU. At the micro level, we assess (across countries and phases) the allocation methods for existing and new installations, for closures and for clean technologies. A comparison of the NAPs for the second phase and the first phase (2005-2007) provides insights into the (limited) adaptability and flexibility of the scheme. The findings provide guidance for the future design of the EU ETS and applications to other sectors and regions

  13. Blue emission in photoluminescence spectra of the red phosphor CaAlSiN3:Eu2+ at low Eu2+ concentration

    Science.gov (United States)

    Suda, Yoriko; Kamigaki, Yoshiaki; Yamamoto, Hajime

    2018-04-01

    In red phosphor CaAlSiN3:Eu2+, unintentional blue emission occurs with increasing intensity at low Eu2+ concentrations and also at low measurement temperatures. Time-resolved photoluminescence measurements were used to confirm the decrease in red emission and increase in blue emission with the decreasing Eu2+ concentration. The peak timing of blue emission occurred faster than that of red emission, and long lasting luminescence of red emission was observed as well as that of blue emission. The Eu2+ concentration dependences of the red and blue emissions were similar to those of the g values 4.75 (Eu2+) and 2.0025 (nitrogen vacancies), respectively, which were observed from electron spin resonance (ESR) measurements. The origin of the blue emission is proposed to be nitrogen vacancy defects, which had about the same ESR signal intensity as that of Eu2+ ions in CaAlSiN3:Eu2+ containing 0.01 at. % Eu2+. The possibility of red emission also arising from excited electron tunneling or thermal pathways via nitrogen vacancies is discussed. Long lasting red emission was observed, which is proposed to involve trapped electrons remaining at nitrogen vacancies, yielding blue emission and inducing red emission from Eu2+ ions.

  14. Eu-emission quenching by electron screening in VO2 thin films

    International Nuclear Information System (INIS)

    Liu, H.; Lysenko, S.; Rua, A.; Vikhnin, V.; Vasquez, O.; Fernandez, F.E.

    2006-01-01

    As a kind of phase transition functional material, Vanadium dioxide (VO 2 ) thin films deposited on fused quartz substrate were fabricated using pulsed laser deposition (PLD) technique. Europium was introduced for structure study. By laser excitation at 526 nm, VO 2 thin film undergoes a reversible and ultrafast phase transition from semiconductor to metallic state, which results in a change of optical properties. In fluorescence measurement, Eu emission was found severely quenched in all as-grown thin films. After annealing the sample in air, a red Eu-emission appeared. The emission spectrum is characterized by a pronounced twin peak, centered at 617 nm ( 5 D - 7 F 2 ), surrounded by a set of broad, but relatively weaker bands (emission from 5 D to 7 F j manifold). The emission lifetime increased when the sample annealed at higher temperature for longer time. Each spectral component is actually a doublet which is the spectral overlap of emissions from Eu 3+ situated in two sites with different configurations. One is a linear h-Eu 3+ -h, where h stands for holes. Another is a right-angle configuration of h-Eu 3+ -h with Eu 3+ in the corner. In as-grown VO 2 film, Eu 3+ ions can either substitute V 4+ , leaving a negative charge around (Eu 3+ -O) - , or substitute V 5+ , leaving two negative charges around (Eu 3+ -O) -- . Due to trapped electrons in a large radius state, it covers Eu 3+ V 4+ -V 5+ complexes. It suggests that the screening by degenerate electronic gas may result in switching off the Eu-related optical response for a wide spectral region, causing emission quenching in VO 2 films

  15. Microbial Volatile Organic Compound Emissions from Stachybotrys chartarum growing on Gypsum Wallboard and Ceiling tile

    Science.gov (United States)

    This study compared seven toxigenic strains of S. chartarum found in water-damaged buildings to characterize the microbial volatile organic compound (MVOC) emissions profile while growing on gypsum wallboard (W) and ceiling tile (C) coupons. The inoculated coupons with their sub...

  16. MTU locomotive drive systems for EU emissions stage IIIB

    Energy Technology Data Exchange (ETDEWEB)

    Wintruff, Ingo [MTU Friedrichshafen GmbH, Friedrichshafen (Germany)

    2011-05-15

    Emissions limits for diesel locomotives within the European Union are regulated by EU Non-road Directive 97/68/EC which places restrictions on the pollutants NOx, particulate, CO and HC. MTU has developed suitable diesel engines for EU Emissions stage IIIB. (orig.)

  17. EU Action against Climate Change. EU emissions trading. An open scheme promoting global innovation

    International Nuclear Information System (INIS)

    2005-01-01

    The European Union is committed to global efforts to reduce the greenhouse gas emissions from human activities that threaten to cause serious disruption to the world's climate. Building on the innovative mechanisms set up under the Kyoto Protocol to the 1992 United Nations Framework Convention on Climate Change (UNFCCC) - joint implementation, the clean development mechanism and international emissions trading - the EU has developed the largest company-level scheme for trading in emissions of carbon dioxide (CO2), making it the world leader in this emerging market. The emissions trading scheme started in the 25 EU Member States on 1 January 2005

  18. Potential Global Benefits of Improved Ceiling Fan Energy Efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Sathaye, Nakul [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Phadke, Amol [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Shah, Nihar [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Letschert, Virginie [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2012-10-31

    Ceiling fans contribute significantly to residential electricity consumption, both in an absolute sense and as a proportion of household consumption in many locations, especially in developing countries in warm climates. However, there has been little detailed assessment of the costs and benefits of efficiency improvement options for ceiling fans and the potential resulting electricity consumption and greenhouse gas (GHG) emissions reductions. We analyze the costs and benefits of several options to improve the efficiency of ceiling fans and assess the global potential for electricity savings and GHG emission reductions with more detailed assessments for India, China, and the U.S. We find that ceiling fan efficiency can be cost-effectively improved by at least 50% using commercially available technology. If these efficiency improvements are implemented in all ceiling fans sold by 2020, 70 terrawatt hours per year (TWh/year) could be saved and 25 million metric tons of carbon dioxide (CO2) emissions per year could be avoided, globally. We assess how policies and programs such as standards, labels, and financial incentives can be used to accelerate the adoption of efficient ceiling fans in order to realize this savings potential.

  19. Emission abatement: Untangling the impacts of the EU ETS and the economic crisis

    International Nuclear Information System (INIS)

    Bel, Germà; Joseph, Stephan

    2015-01-01

    In this study we use historical emission data from installations under the European Union Emissions Trading System (EU ETS) to evaluate the impact of this policy on greenhouse gas emissions during the first two trading phases (2005–2012). As such the analysis seeks to disentangle two causes of emission abatement: that attributable to the EU ETS and that attributable to the economic crisis that hit the EU in 2008/09. To do so, we use a dynamic panel data approach. Our results suggest that, by far, the biggest share of abatement was attributable to the effects of the economic crisis. This finding has serious implications for future policy adjustments affecting core elements of the EU ETS, including the distribution of EU emission allowances. - Highlights: • We untangle the effects of the EU ETS from those of the economic crisis on industrial emission abatement. • The empirical analysis uses verified emission data instead of estimated emission data. • Abatement of emissions in EU in the last years has been mainly due to the impact of the economic crisis. • Low level of abatement attributable to the EU ETS suggests that important changes must be made in environmental policy

  20. Market Analysis and Risk Management of EU Emissions Trading - MARMET

    International Nuclear Information System (INIS)

    Ollikainen, M.; Aatola, P.; Ollikka, K.; Kumpulainen, A.; Pohjola, T.; Lappalainen, E.

    2007-01-01

    The first period of the EU Emissions Trading Scheme (EU ETS) commenced on January 1st 2005. It implies new challenges to companies included in the scheme. A central challenge is the uncertainty related to the markets. In order to manage their risks and profitability companies need to be able to estimate future price developments of emission allowances. The University of Helsinki is conducting a research project in cooperation with the Helsinki University of Technology that will provide necessary information for analyzing European Union emission allowance (EUA) markets and create risk management competence. The objectives of the research project are (1) to develop a price estimation model for EU emission allowances and (2) to develop risk management competence related to EU ETS. With the price estimation model the short-term price developments of EUAs can be estimated. By utilizing the model companies can reduce uncertainties related to the markets. The project also delivers a general risk management model for EU ETS that aims at improving competitiveness of companies. (orig.)

  1. MTU engines for locomotives satisfying the EU stage IIIB emission standard; MTU-Lokomotivantriebe fuer die Emissionsstufe EU IIIB

    Energy Technology Data Exchange (ETDEWEB)

    Wintruff, Ingo; Reich, Christian; Geiselmann, Wolfgang; Gottschalch, Harald; Jansen, Eddy [MTU Friedrichshafen GmbH, Friedrichshafen (Germany)

    2011-07-01

    The emission limits for diesel locomotives inside the European Union are included within the scope of Directive 97/68/EC, which is sometimes referred to as the ''non-road directive''. The pollutants limited by it are NO{sub x}, particulates, CO and HCs. The aim, through the directive, is to reduce railway emissions by a factor of ten by the year 2020. The EU stage IIIB standard is due to take effect on 1 January 2012. This envisages a further drastic reduction in limit values compared with EU stage IIIA, which is applicable today. For diesel locomotives, EU stage IIIA only came into force as recently as 2009. The manufacturers of engines and locomotives are thus having to face up to the huge challenge of getting the technologies needed for EU stage IIIB ready for the production line within a period of only three years. MTU has succeeded in developing engines for diesel locomotives that comply with the EU stage IIIB emission standard, which appreciably lower emissions compared with engines satisfying EU stage IIIA, thanks to the incorporation of the most modern technologies available, and has even gone as far as preparing them for the EU stage IV, the next one to come into force. (orig.)

  2. Banning banking in EU emissions trading?

    International Nuclear Information System (INIS)

    Schleich, Joachim; Ehrhart, Karl-Martin; Hoppe, Christian; Seifert, Stefan

    2006-01-01

    Admitting banking in emissions trading systems reduces overall compliance costs by allowing for inter-temporal flexibility: cost savings can be traded over time. However, unless individual EU Member States (MS) decide differently, the transfer of unused allowances from the period of 2005-2007 into the first commitment period under the Kyoto Protocol, i.e. 2008-2012, will be prohibited. In this paper, we first explore the implications of such a ban on banking when initial emission targets are lenient. This analysis is based on a simulation which was recently carried out in Germany with companies and with a student control group. The findings suggest that a EU-wide ban on banking would lead to efficiency losses in addition to those losses which arise from the lack of inter-temporal flexibility. Second, we use simple game-theoretic considerations to argue that, under reasonable assumptions, such a EU-wide ban on banking will be the equilibrium outcome. Thus, to avoid a possible prisoners' dilemma, MS should have co-ordinated their banking decisions

  3. Costs and benefits of energy efficiency improvements in ceiling fans

    Energy Technology Data Exchange (ETDEWEB)

    Shah, Nihar; Sathaye, Nakul; Phadke, Amol; Letschert, Virginie [Lawrence Berkeley National Lab., CA (United States). Environmental Energy Technology Division

    2013-10-15

    Ceiling fans contribute significantly to residential electricity consumption, especially in developing countries with warm climates. The paper provides analysis of costs and benefits of several options to improve the efficiency of ceiling fans to assess the global potential for electricity savings and green house gas (GHG) emission reductions. Ceiling fan efficiency can be cost-effectively improved by at least 50% using commercially available technology. If these efficiency improvements are implemented in all ceiling fans sold by 2020, 70 terawatt hours per year could be saved and 25 million metric tons of carbon dioxide equivalent (CO2-e) emissions per year could be avoided, globally. We assess how policies and programs such as standards, labels, and financial incentives can be used to accelerate the adoption of efficient ceiling fans in order to realize potential savings.

  4. Eu{sup 3+} emission in phosphate glasses with high UV transparency

    Energy Technology Data Exchange (ETDEWEB)

    Silva, G.H. [Laboratório de Espectroscopia de Materiais (LEM), Departamento de Física, Universidade Federal de Juiz de Fora, CEP 36036-900 Juiz de Fora, MG (Brazil); Anjos, V., E-mail: virgilio@fisica.ufjf.br [Laboratório de Espectroscopia de Materiais (LEM), Departamento de Física, Universidade Federal de Juiz de Fora, CEP 36036-900 Juiz de Fora, MG (Brazil); Bell, M.J.V. [Laboratório de Espectroscopia de Materiais (LEM), Departamento de Física, Universidade Federal de Juiz de Fora, CEP 36036-900 Juiz de Fora, MG (Brazil); Carmo, A.P. [Instituto Federal Fluminense-Campus Cabo Frio, CP 112015, CEP 28909-971 Cabo Frio, RJ (Brazil); Pinheiro, A.S.; Dantas, N.O. [Laboratório de Novos Materiais Isolantes e Semicondutores (LNMIS), Instituto de Física, Universidade Federal de Uberlândia, CP 593, CEP 38400-902 Uberlândia, MG (Brazil)

    2014-10-15

    We report a study of the phosphate glass PZABP (P{sub 2}O{sub 5}–ZnO–Al{sub 2}O{sub 3}–BaO–PbO) doped with europium (Eu{sup 3+}) in different concentrations. Absorption, photoluminescence and time resolved photoluminescence were used to investigate the influence of increasing Eu{sup 3+} concentrations. The present glass exhibits Eu{sup 3+} absorption bands in the ultraviolet region (about 300 nm) due to the high transparency of the system compared to other phosphate glasses. In this way, it was possible to obtain the Judd–Ofelt parameters from the emission and absorption spectra. Moreover, a strong red emission attributed to the transition {sup 5}D{sub 0}→{sup 7}F{sub 2} of Eu{sup 3+} (611 nm) was observed. It was found that the radiative lifetime and the quantum efficiency of the Eu{sup 3+} level, {sup 5}D{sub 0}, do not suffer a significant change as the concentration of Eu{sup 3+} ions increases. - Highlights: • UV transparent glass matrix is used for Eu{sup 3+} doping. • Judd–Ofelt parameters from the emission and absorption spectra were obtained. • Red emission attributed to the transition {sup 5}D{sub 0}→{sup 7}F{sub 2} of Eu{sup 3+} (611 nm) was observed.

  5. Production of 147Eu for gamma-ray emission probability measurement

    International Nuclear Information System (INIS)

    Katoh, Keiji; Marnada, Nada; Miyahara, Hiroshi

    2002-01-01

    Gamma-ray emission probability is one of the most important decay parameters of radionuclide and many researchers are paying efforts to improve the certainty of it. The certainties of γ-ray emission probabilities for neutron-rich nuclides are being improved little by little, but the improvements of those for proton-rich nuclides are still insufficient. Europium-147 that decays by electron capture or β + -particle emission is a proton-rich nuclide and the γ-ray emission probabilities evaluated by Mateosian and Peker have large uncertainties. They referred to only one report concerning with γ-ray emission probabilities. Our final purpose is to determine the precise γ-ray emission probabilities of 147 Eu from disintegration rates and γ-ray intensities by using a 4πβ-γ coincidence apparatus. Impurity nuclides affect largely to the determination of disintegration rate; therefore, a highly pure 147 Eu source is required. This short note will describe the most proper energy for 147 Eu production through 147 Sm(p, n) reaction. (author)

  6. Cross-border electricity market effects due to price caps in an emission trading system : An agent-based approach

    NARCIS (Netherlands)

    Richstein, J.C.; Chappin, E.J.L.; De Vries, L.J.

    2014-01-01

    The recent low CO2 prices in the European Union Emission Trading Scheme (EU ETS) have triggered a discussion whether the EU ETS needs to be adjusted. We study the effects of CO2 price floors and a price ceiling on the dynamic investment pathway of two interlinked electricity markets (loosely based

  7. Eu emission trading scheme and its implications on energy sector of Lithuania

    International Nuclear Information System (INIS)

    Streimikiene, D.; Mikalauskiene, A.

    2004-01-01

    The main objectives of the article are to analyse the theoretical principles of emission trading and to emphasize the main features and requirements of EU emission trading scheme. The goal of the article to assess the impact of GHG emission trading on economy and GHG emission reduction in EU and Lithuania

  8. The evolution of emissions trading in the EU. Tensions between national trading schemes and the proposed EU directive

    International Nuclear Information System (INIS)

    Boemare, Catherine; Quirion, Philippe; Sorrell, Steve

    2003-12-01

    The EU is pioneering the development of greenhouse gas emissions trading, but there is a tension between the 'top-down' and 'bottom-up' evolution of trading schemes. While the Commission is introducing a European emissions trading scheme (EU ETS) in 2005, several member states have already introduced negotiated agreements that include trading arrangements. Typically, these national schemes have a wider scope than the proposed EU directive and allow firms to use relative rather than absolute targets. The coexistence of 'top-down' and 'bottom-up' trading schemes may create some complex problems of policy interaction. This paper explores the potential interactions between the EU ETS and the negotiated agreements in France and UK and uses these to illustrate some important generic issues. The paper first describes the proposed EU directive, outlines the UK and French policies and compares their main features to the EU ETS. It then discusses how the national and European policies may interact in practice. Four issues are highlighted, namely, double regulation, double counting of emission reductions, equivalence of effort and linking trading schemes. The paper concludes with some recommendations for the future development of UK and French climate policy

  9. The EU system for emissions trading after year 2012; EU:s system foer handel med utslaeppsraetter efter 2012

    Energy Technology Data Exchange (ETDEWEB)

    Normand, Mathias; Mjureke, David (eds.)

    2007-01-15

    The Government has instructed the Swedish Energy Agency and the Swedish Environmental Protection Agency to put forward a proposal for how the EU Emissions Trading Scheme (EU ETS) should be developed after 2012, subject to the overall objective of continuing to reduce emissions with the aim of achieving the long-term objectives of the Convention on Climate Change. In its Council Conclusions (7619/1/05) the EU has interpreted the long-term objectives of the Convention on Climate Change as aiming to achieve emission reductions of 15-30 % in the industrialised countries by 2020. According to Council Conclusions (13435/05), the EU has also decided that the Emissions Trading Scheme should continue after 2012. The starting point for this report is that, after 2012, the Scheme will be a key instrument in achieving cost-efficient emission reductions, not only within the EU but also globally, and regardless of whether, with effect from 2013, the Scheme has become a part of an international climate regime, or is serving as a transition to some future new international climate regime. The purpose of this report is to provide a proposal for how the Emissions Trading Scheme should be developed after 2012. The aim is to construct a system that helps to reduce global emissions of greenhouse gases (maintaining climate integrity), that assists measures being taken where they are cheapest (cost efficiency), that is accepted by parties concerned and by the general public (confidence inspiring), and which does not adversely affect the competitiveness of business or industry (competition-neutral). The Agencies recommend that Sweden should adopt the following standpoints concerning development of the EU Emissions Trading Scheme after 2012. (Recommended changes to the system presuppose a harmonised implementation throughout the EU.): In connection with international negotiations, Sweden should press for the Emissions Trading Scheme to be developed in such a way as to make it possible to

  10. Reduction emissions from transport sector - EU action against climate change

    Science.gov (United States)

    2009-08-01

    This paper explores and discusses the initiation and development of the EU's policies and strategies against climate change and the share experiences in the EU transport sector to reduce CO2 emission.

  11. UV light induced red emission in Eu3+-doped zincborophosphate glasses

    Science.gov (United States)

    Hima Bindu, S.; Siva Raju, D.; Vinay Krishna, V.; Rajavardhana Rao, T.; Veerabrahmam, K.; Linga Raju, Ch.

    2016-12-01

    This paper reports the preparation of transparent zincborophosphate (ZBP) glasses doped with Eu3+ ions by the conventional melt quenching technique. The prepared glasses were characterized using powder XRD, FTIR, optical absorption, photoluminescence and decay curves. Judd-Ofelt (JO) intensity parameters calculated under various constraints using absorption and emission spectra. These JO intensity parameters have been used to predict the radiative properties such as radiative life time, branching ratios and stimulated emission cross section of the 5D0→7FJ (J = 0-4) transitions. Decay curves for the 5D0 level of Eu3+ ions shows single exponential for all concentrations. Luminescence properties of 5D0→7F2 transitions of Eu3+ions have revealed that the present ZBP:Eu3+ glasses have significant in optical applications at around 613 nm. An intense red luminescence has been observed due to 5D0→7F2 transition of Eu3+ ion in these glasses. From the CIE color coordinate diagram, it is observed that the present glass system is prominent material for red emission.

  12. Greenhouse gas emission accounting for EU member states from 1991 to 2012

    International Nuclear Information System (INIS)

    Su, Meirong; Pauleit, Stephan; Yin, Xuemei; Zheng, Ying; Chen, Shaoqing; Xu, Chao

    2016-01-01

    Highlights: • GHG emissions for the EU28 during 1991–2012 are accounted. • The EU28 are classified into four groups based on GHG emission structure. • It can facilitate classified management of GHG emissions. • The EU case shows the common but differentiated principle in emission reduction. - Abstract: Collectively, the EU is among the world’s largest greenhouse gas (GHG) emitters, though remarkable decreases in GHG emissions have been observed in recent years. In this work the GHG emissions for the 28 EU member states between 1991 and 2012 are accounted for and compared according to the inventory method of the Intergovernmental Panel on Climate Change (IPCC). The structure of GHG emissions at a national level, their distribution between countries, and trends across the period are then analyzed. National emission sources and sinks are decomposed for each country to elucidate the contribution of each sector (energy, industrial processes, solvents and other product use, agriculture, land use/land-use change and forestry, and waste) to the national totals. Germany was the largest emitter, with net emissions totaling 939 Tg CO_2 equivalent in 2012, 60% more than the UK and 89% more than France, the second and third biggest emitters, respectively. The energy sector and agriculture were found to be the largest sources of emissions in most countries. Four quadrants were established to compare countries’ performance in emission intensity, carbon removal rate, and net reduction rate of GHG emissions. Slovenia, Portugal, Sweden, and Finland were located in Quadrant II as they displayed relatively low emission intensities and high carbon removal rates. Conversely, Hungary, Greece, Cyprus, the Czech Republic, and Poland were located in Quadrant IV because of their relatively high emission intensities and low carbon removal rates. Some suggestions for integrating the annual results and the trends both within and among countries into national and regional emissions

  13. Border tax adjustments and the EU-ETS. A quantitative assessment

    International Nuclear Information System (INIS)

    Manders, T.; Veenendaal, P.

    2008-10-01

    If the EU stands alone in adopting climate policy and imposes a strict emissions ceiling, competitiveness of EU energy-intensive sectors will be affected negatively. Relocation of EU energy-intensive firms to countries with a lax regime also leads to carbon leakage. However, when use is made of the opportunities of the Clean Development Mechanism these impacts are very modest. Border tax adjustments (BTAs) to 'level the playing field' between domestic and foreign producers may be considered to address the concerns about both competitiveness and carbon leakage. It is far from clear whether these measures are WTO-proof. Simulations show that both an import levy and an export refund restore competitiveness to a certain extent. BTAs may lower the costs for energy-intensive sectors, but induce higher costs for other sectors. This paper uses a general equilibrium model to quantify and assess the implications of a number of policy scenarios

  14. Blue emission of Eu{sup 2+}-doped translucent alumina

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yan [Kazuo Inamori School of Engineering, New York State College of Ceramics, Alfred University, Alfred, NY 14802 (United States); Wei, Hua [Scintillation Materials Research Center, University of Tennessee, Knoxville 37996 (United States); Zhang, Lihua; Kisslinger, Kim [Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY 11973-5000 (United States); Melcher, Charles L. [Scintillation Materials Research Center, University of Tennessee, Knoxville 37996 (United States); Wu, Yiquan, E-mail: wuy@alfred.edu [Kazuo Inamori School of Engineering, New York State College of Ceramics, Alfred University, Alfred, NY 14802 (United States)

    2015-12-15

    Inorganic scintillators are very important in medical and industrial measuring systems in the detection and measurement of ionizing radiation. In addition to Ce{sup 3+}, a widely used dopant ion in oxide scintillators, divalent Europium (Eu{sup 2+}) has shown promise as a high-luminescence, fast-response luminescence center useful in the detection of ionizing radiation. In this research, aluminum oxide (Al{sub 2}O{sub 3}) was studied as a host material for the divalent europium ion. Polycrystalline samples of Eu{sup 2+}-doped translucent Al{sub 2}O{sub 3} were fabricated, and room temperature luminescence behavior was observed. Al{sub 2}O{sub 3} ceramics doped with 0.1 at% Eu{sup 2+} were fabricated with a relative density of 99.75% theoretical density and in-line transmittance of 22% at a wavelength of 800 nm. The ceramics were processed by a gel-casting method, followed by sintering under high vacuum. The gelling agent, a copolymer of isobutylene and maleic anhydride, is marketed under the commercial name ISOBAM, and has the advantage of simultaneously acting as both a gelling agent and as a dispersant. The microstructure and composition of the vacuum-sintered Eu{sup 2+}:Al{sub 2}O{sub 3} were characterized by Scanning Electric Microscopy (SEM), Transmission Electron Microscopy (TEM), and Energy-dispersive X-ray spectroscopy (EDS). The phase composition was determined by X-ray diffraction measurements (XRD) combined with Rietveld analysis. The photoluminescence behavior of the Eu{sup 2+}:Al{sub 2}O{sub 3} was characterized using UV light as the excitation source, which emitted blue emission at 440 nm. The radio-luminescence of Eu{sup 2+}:Al{sub 2}O{sub 3} was investigated by illumination with X-ray radiation, showing three emission bands at 376 nm, 575 nm and 698 nm. Multiple level traps at different depths were detected in the Eu{sup 2+}:Al{sub 2}O{sub 3} by employing thermoluminescence measurements. - Highlights: • Eu{sup 2+} : Al{sub 2}O{sub 3} was

  15. Does EU emissions trading bite? An event study

    International Nuclear Information System (INIS)

    Jong, Thijs; Couwenberg, Oscar; Woerdman, Edwin

    2014-01-01

    The aim of this paper is to examine whether shareholders consider the EU Emissions Trading Scheme (EU ETS) as value-relevant for the participating firms. An analysis is conducted of the share prices changes as caused by the first publication of compliance data in April, 2006, which disclosed an over-allocation of emission allowances. Through an event study, it is shown that share prices actually increased as a result of the allowance price drop when firms have a lower carbon-intensity of production and larger allowance holdings. There was no significant value impact from firms' allowance trade activity or from the pass-through of carbon-related production costs (carbon leakage). The conclusion is that the EU ETS does ‘bite’. The main impact on the share prices of firms arises from their carbon-intensity of production. The EU ETS is thus valued as a restriction on pollution. - Highlights: • Firms are more positively valued with lower carbon-intensities of production. • Firms are more negatively valued with smaller holdings of allowances. • The stock market does not value the firms' allowance trade activity. • The stock market does not seem to value the pass-through of carbon costs in product prices

  16. Tuning Eu"3"+ emission in europium sesquioxide films by changing the crystalline phase

    International Nuclear Information System (INIS)

    Mariscal, A.; Quesada, A.; Camps, I.; Palomares, F.J.; Fernández, J.F.; Serna, R.

    2016-01-01

    Highlights: • PLD production of high quality europium sesquioxide (Eu_2O_3) films. • The deposition of Al_2O_3 capping and/or buffer layers modifies the crystallization for Eu_2O_3 films upon annealing. • The formation of cubic or monoclinic phases can be favored. • Eu"3"+ emission tuning is achieved as a consequence of crystal field effects. - Abstract: We report the growth of europium sesquioxide (Eu_2O_3) thin films by pulsed laser deposition (PLD) in vacuum at room temperature from a pure Eu_2O_3 ceramic bulk target. The films were deposited in different configurations formed by adding capping and/or buffer layers of amorphous aluminum oxide (a-Al_2O_3). The optical properties, refractive index and extinction coefficient of the as deposited Eu_2O_3 layers were obtained. X-ray photoelectron spectroscopy (XPS) measurements were done to assess its chemical composition. Post-deposition annealing was performed at 500 °C and 850 °C in air in order to achieve the formation of crystalline films and to accomplish photoluminescence emission. According to the analysis of X-ray diffraction (XRD) spectra, cubic and monoclinic phases were formed. It is found that the relative amount of the phases is related to the different film configurations, showing that the control over the crystallization phase can be realized by adequately designing the structures. All the films showed photoluminescence emission peaks (under excitation at 355 nm) that are attributed to the intra 4f-transitions of Eu"3"+ ions. The emission spectral shape depends on the crystalline phase of the Eu_2O_3 layer. Specifically, changes in the hypersensitive "5D_0 → "7F_2 emission confirm the strong influence of the crystal field effect on the Eu"3"+ energy levels.

  17. Public Interest vs. Interest Groups: Allowance Allocation in the EU Emission Trading Scheme

    Energy Technology Data Exchange (ETDEWEB)

    Anger, Niels; Oberndorfer, Ulrich (Centre for European Economic Research, Mannheim (Germany)); Boehringer, Christoph (Carl von Ossietzky Univ., Oldenburg (Germany))

    2008-07-01

    We assess the political-economy determinants of allowance allocation in the EU Emissions Trading Scheme (EU ETS). A common-agency model suggests that the government considers the preferences of sectoral interest groups when allocating emissions permits, so that industries with a more powerful lobby face a lower regulatory burden. An empirical analysis of the first trading phase of the EU ETS corroborates our theoretical prediction, but also reveals that the political-economy determinants of permit allocation are more complex. Employing instrumental-variable estimation technique, we find that large carbon emitters that were represented by powerful interest groups received higher levels of emissions allowances

  18. An emerging equilibrium in the EU emissions trading scheme

    International Nuclear Information System (INIS)

    Bredin, Don; Muckley, Cal

    2011-01-01

    The European Union's Emissions Trading Scheme (ETS) is the key policy instrument of the European Commission's Climate Change Program aimed at reducing greenhouse gas emissions to eight percent below 1990 levels by 2012. A critically important element of the EU ETS is the establishment of a market determined price for EU allowances. This article examines the extent to which several theoretically founded factors including, economic growth, energy prices and weather conditions determine the expected prices of the European Union CO 2 allowances during the 2005 through to the 2009 period. The novel aspect of our study is that we examine heavily traded futures instruments that have an expiry date in Phase 2 of the EU ETS. Our study adopts both static and recursive versions of the Johansen multivariate cointegration likelihood ratio test as well as a variation on this test with a view to controlling for time varying volatility effects. Our results are indicative of a new pricing regime emerging in Phase 2 and point to a maturing market driven by the fundamentals. These results are valuable both for traders of EU allowances and for those policy makers seeking to improve the design of the European Union ETS.

  19. Imported palm oil for biofuels in the EU: Profitability, greenhouse gas emissions and social welfare effects

    International Nuclear Information System (INIS)

    Saikkonen, Liisa; Ollikainen, Markku; Lankoski, Jussi

    2014-01-01

    We examine the social desirability of renewable diesel production from imported palm oil in the EU when greenhouse gas emissions are taken into account. Using a partial market equilibrium model, we also study the sectoral social welfare effects of a biofuel policy consisting of a blend mandate in a small EU country (Finland), when palm oil based diesel is used to meet the mandated quota for biofuels. We develop a market equilibrium model for three cases: i) no biofuel policy, ii) biofuel policy consisting of socially optimal emission-based biofuel tax credit and iii) actual EU biofuel policy. Our results for the EU biofuel market, Southeast Asia and Finland show very little evidence that a large scale use of imported palm oil in diesel production in the EU can be justified by lower greenhouse gas emission costs. Cuts in emission costs may justify extensive production only if low or negative land-use change emissions result from oil palm cultivation and if the estimated per unit social costs of emissions are high. In contrast, the actual biofuel policies in the EU encourage the production of palm oil based diesel. Our results indicate that the sectoral social welfare effects of the actual biofuel policy in Finland may be negative and that if emissions decrease under actual biofuel policy, the emission abatement costs can be high regardless of the land use change emissions. - Highlights: • We study the social desirability of renewable diesel production from palm oil in EU. • We also study sectoral social welfare impacts of actual biofuel policy in Finland. • Life cycle GHG emission costs of diesels are included in the economic analysis. • Extensive use of palm oil diesel in EU is difficult to justify by climate benefits. • The social welfare effects of the actual biofuel policy in Finland can be negative

  20. Strategic partitioning of emissions allowances in the EU ETS

    Energy Technology Data Exchange (ETDEWEB)

    Boehringer, Christoph (Carl von Ossietzky Univ. Oldenburg (Germany)); Rosendahl, Knut Einar (Research Dept., Statistics Norway, Oslo (Norway))

    2008-07-01

    The EU ETS opens up for strategic partitioning of emissions allowances by the Member States. In this paper we examine the potential effects of such strategic behavior on quota prices and abatement costs. We show that although marginal abatement costs in the sectors outside the EU ETS become quite differentiated, the effects on the quota price and total abatement costs are small. More abatement, however, takes place in the old Member States that are importers of allowances, compared to the cost-effective outcome. Single countries can nevertheless significantly affect the outcome of the EU ETS by exploiting their market power

  1. Reddish-orange, neutral and warm white emissions in Eu3+, Dy3+ and Dy3+/Eu3+ doped CdO-GeO2-TeO2 glasses

    Science.gov (United States)

    Rodríguez-Carvajal, David A.; Meza-Rocha, A. N.; Caldiño, U.; Lozada-Morales, R.; Álvarez, E.; Zayas, Ma. E.

    2016-11-01

    Eu3+, Dy3+ and Dy3+/Eu3+ doped CdO-GeO2-TeO2 glasses were prepared using the melt-quenching process and analyzed by X-diffraction, Raman spectroscopy, excitation and emission spectra, and emission decay time profiles. The lack of X ray diffraction peaks revealed that all samples are amorphous. Vibrational modes associated with Tesbnd Osbnd Te and Gesbnd Osbnd Ge related bonds and molecular oxygen were detected by Raman spectroscopy. The luminescence characteristics were studied upon excitations that correspond with the emission of InGaN (370-420 nm) based LEDs. The Eu3+ singly doped glass displayed reddish-orange global emission, with x = 0.601 and y = 0.349 CIE1931 chromaticity coordinates, upon 393 nm excitation. Neutral emission with x = 0.373 and y = 0.412 CIE1931 chromaticity coordinates and correlated color temperature (CCT) of 4400 K, was achieved in the Dy3+ singly doped glass excited at 388 nm. The Dy3+/Eu3+ co-doped glass exhibited warm, neutral and soft warm white emissions with CCT values of 3435, 4153 and 2740 K, under excitations at 382, 388 and 393 nm, respectively, depending mainly on the Dy3+ and Eu3+ relative excitation. The Dy3+ excitation bands observed in the Dy3+/Eu3+ glass by monitoring the 611 nm Eu3+ emission, suggest that Dy3+ → Eu3+ energy transfer takes place, despite the fact that the Dy3+ emission decays in the Dy3+ and Dy3+/Eu3+ doped glass, remain without changes. The shortening of Eu3+ decay in presence of Dy3+ was attributed to an Eu3+ → Dy3+ non-radiative energy transfer process, which according with the Inokuti-Hirayama model might be dominated through an electric quadrupole-quadrupole interaction, with efficiency and probability of 5.5% and 51.6 s-1, respectively.

  2. The efficiency costs of separating carbon markets under the EU emissions trading scheme: A quantitative assessment for Germany

    International Nuclear Information System (INIS)

    Boehringer, Christoph; Hoffmann, Tim; Manrique-de-Lara-Penate, Casiano

    2006-01-01

    From 1 January 2005 onwards the European Union has launched the first large-scale international carbon emissions trading program. As the EU Emissions Trading Scheme (EU-ETS) covers only part of domestic carbon emissions, it implies a segmented environmental regulation scheme: Each EU Member State must specify additional domestic abatement policies for the sectors outside the EU-ETS in order to meet its emissions budget under the EU Burden Sharing Agreement. We highlight the generic problems of segmented carbon regulation in terms of information requirements for international carbon prices and domestic abatement costs of sectors outside the EU-ETS. Based on numerical simulations for Germany, we quantify the excess costs of segmented carbon regulation and conclude that inefficiencies can be much better explained by lobbying of influential EU-ETS sectors than by information problems. (Author)

  3. Tuning Eu{sup 3+} emission in europium sesquioxide films by changing the crystalline phase

    Energy Technology Data Exchange (ETDEWEB)

    Mariscal, A., E-mail: antonio.mariscal@csic.es [Laser Processing Group, Instituto de Óptica, CSIC, C/ Serrano 121, 28006 Madrid (Spain); Quesada, A. [Ceramics for Smart Systems Group, Instituto de Cerámica y Vidrio, C/ Kelsen 5, 28049 Madrid (Spain); Camps, I. [Laser Processing Group, Instituto de Óptica, CSIC, C/ Serrano 121, 28006 Madrid (Spain); Palomares, F.J. [Instituto de Ciencia de Materiales de Madrid, C/ Sor Juana Inés de la Cruz 3, 28049 Madrid (Spain); Fernández, J.F. [Ceramics for Smart Systems Group, Instituto de Cerámica y Vidrio, C/ Kelsen 5, 28049 Madrid (Spain); Serna, R. [Laser Processing Group, Instituto de Óptica, CSIC, C/ Serrano 121, 28006 Madrid (Spain)

    2016-06-30

    Highlights: • PLD production of high quality europium sesquioxide (Eu{sub 2}O{sub 3}) films. • The deposition of Al{sub 2}O{sub 3} capping and/or buffer layers modifies the crystallization for Eu{sub 2}O{sub 3} films upon annealing. • The formation of cubic or monoclinic phases can be favored. • Eu{sup 3+} emission tuning is achieved as a consequence of crystal field effects. - Abstract: We report the growth of europium sesquioxide (Eu{sub 2}O{sub 3}) thin films by pulsed laser deposition (PLD) in vacuum at room temperature from a pure Eu{sub 2}O{sub 3} ceramic bulk target. The films were deposited in different configurations formed by adding capping and/or buffer layers of amorphous aluminum oxide (a-Al{sub 2}O{sub 3}). The optical properties, refractive index and extinction coefficient of the as deposited Eu{sub 2}O{sub 3} layers were obtained. X-ray photoelectron spectroscopy (XPS) measurements were done to assess its chemical composition. Post-deposition annealing was performed at 500 °C and 850 °C in air in order to achieve the formation of crystalline films and to accomplish photoluminescence emission. According to the analysis of X-ray diffraction (XRD) spectra, cubic and monoclinic phases were formed. It is found that the relative amount of the phases is related to the different film configurations, showing that the control over the crystallization phase can be realized by adequately designing the structures. All the films showed photoluminescence emission peaks (under excitation at 355 nm) that are attributed to the intra 4f-transitions of Eu{sup 3+} ions. The emission spectral shape depends on the crystalline phase of the Eu{sub 2}O{sub 3} layer. Specifically, changes in the hypersensitive {sup 5}D{sub 0} → {sup 7}F{sub 2} emission confirm the strong influence of the crystal field effect on the Eu{sup 3+} energy levels.

  4. A Ten-Year Rule to guide the allocation of EU emission allowances

    International Nuclear Information System (INIS)

    Ahman, Markus; Burtraw, Dallas; Kruger, Joseph; Zetterberg, Lars

    2007-01-01

    Member States in the European Union (EU) are responsible for National Allocation Plans governing the initial distribution of emission allowances in the CO 2 Emission Trading System, including rules governing allocations to installations that close and to new entrants. The European Commission has provided guidelines to discourage the use of allocation methodologies that provide incentives affecting firms' compliance behavior, for example by rewarding one type of compliance investment over another. We find that the treatment of closures and new entrants by Member States is inconsistent with the general guidelines provided by the EU. We propose stronger EU guidance regarding closures and new entrants, a more precise compensation criterion on which to justify free allocations, and a Ten-Year Rule as a component of future EU policy that can guide a transition from current practice to an approach that places greater weight on efficiency

  5. EU policies on car emissions and fuel quality. Reducing the climate impact from road transport

    Energy Technology Data Exchange (ETDEWEB)

    Christensen, Anne Raaum; Gulbrandsen, Lars H.

    2012-07-01

    Transport is the second biggest source of greenhouse gas (GHG) emissions in the EU, and contributes about one-quarter of the EU's total emissions of CO{sub 2}. Significant reductions in GHG emissions from transport are required if the EU is to achieve its long-term climate goals. This report examines the making and implementation of two of the regulations the EU has put in place to lower emissions from the transport sector: the EU's revised Fuel Quality Directive (Directive 2009/30/EC) and the cars/CO{sub 2} regulation (Regulation (EC) 443/2009). It was found that the relevance of various theories of policymaking in the EU varies with different policy phases. A policy-network understanding of EU policymaking is strengthened when assessing the policy-initiation phase. The Commission played a key role in this phase and drafted legislation in close collaboration with the car and oil refining industries. An intergovernmentalist understanding of EU policy-making is strengthened when assessing the decision-making phase. In this phase, member states defending the interests of their domestic industries had strong influence, but the European Parliament played an important role in this phase too, employing its power in the co-decision procedure. Finally, the implementation process is best understood as a multi-level governance process in which several actors and institutions - notably the Commission, member states, industries, and NGOs - influenced the process. (Author)

  6. Multiple Glass Ceilings

    OpenAIRE

    Russo, Giovanni; Hassink, Wolter

    2011-01-01

    Both vertical (between job levels) and horizontal (within job levels) mobility can be sources of wage growth. We find that the glass ceiling operates at both margins. The unexplained part of the wage gap grows across job levels (glass ceiling at the vertical margin) and across the deciles of the intra-job-level wage distribution (glass ceiling at the horizontal margin). This implies that women face many glass ceilings, one for each job level above the second, and that the glass ceiling is a p...

  7. Do emission ceilings ruin coal-fired power plants?; Emissieplafonds nekken kolencentrales?

    Energy Technology Data Exchange (ETDEWEB)

    Wijmenga, J. [Ministerie van Infrastructuur en Milieu, Den Haag (Netherlands)

    2011-04-15

    The case of the new coal-fired power plants has already racked the brains of many. The advice offered to the court by the attorney-general constitutes the next step in this process. A temporary solution has been found for the coal-fired plants, but one question remains unanswered so far: how should an emission ceiling be used as a test instrument for permits? This article provides a direction in which a solution can be found. [Dutch] De zaak betreffende de nieuwe kolencentrales heeft al tot heel wat hoofdbrekens geleid. Het advies dat de advocaat-generaal heeft uitgebracht aan het hof is een volgende stap in dit proces. Voor de kolencentrales is een tijdelijke oplossing gevonden, maar de vraag is nog niet beantwoord hoe een emissieplafond moet worden gebruikt als toetsinstrument voor vergunningen. In dit artikel wordt aangegeven in welke richting een oplossing kan worden gezocht.

  8. The Impact of the EU Emissions Trading System on CO{sub 2} Intensity in Electricity Generation

    Energy Technology Data Exchange (ETDEWEB)

    Widerberg, Anna (Dept. of Economics, Goeteborgs Univ., Goeteborg (Sweden)); Wraake, Markus (Swedish Environmental Research Institute Ltd., Stockholm (Sweden)). e-mail: markus.wrake@ivl.se

    2009-07-15

    Prior to the launch of the EU Emissions Trading System (EU ETS) in 2005, the electricity sector was widely proclaimed to have more low-cost emission abatement opportunities than other sectors. If this were true, effects of the EU ETS on carbon dioxide (CO{sub 2}) emissions would likely be visible in the electricity sector. Our study looks at the effect of the price of emission allowances (EUA) on CO{sub 2} emissions from Swedish electricity generation, using an econometric time series analysis for the period 2004-2008. We control for effects of other input prices and hydropower reservoir levels. Our results do not indicate any link between the price of EUA and the CO{sub 2} emissions of Swedish electricity production. A number of reasons may explain this result and we conclude that other determinants of fossil fuel use in Swedish electricity generation probably diminished the effects of the EU ETS

  9. Firm performance and employment in the EU emissions trading scheme: An empirical assessment for Germany

    International Nuclear Information System (INIS)

    Anger, Niels; Oberndorfer, Ulrich

    2008-01-01

    This paper empirically investigates the role of the EU Emissions Trading Scheme (EU ETS) for firm performance and employment in Germany. We provide an overview of relative allowance allocation within the EU ETS as well as an econometric analysis for a large sample of German firms covered by the scheme in order to assess the impacts of EU emissions regulation on both firm revenues and employment. The dataset indicates that the EU ETS was in an overall long position in 2005, although allowance allocation was very heterogeneous across member states. Our econometric analysis suggests that, within the first phase of the EU ETS, relative allowance allocation did not have a significant impact on firm performance and employment of regulated German firms

  10. EU Emission Trading: Starting with Carbon Dioxide

    DEFF Research Database (Denmark)

    Vesterdal, Morten; Svendsen, Gert Tinggaard

    2003-01-01

    The Commission of the European Union wants to start a limited emission trading scheme by 2005 within the Community to enable "learning-by-doing" prior to the Kyoto Protocol. This to accomplish the desired 8% target level for six different greenhouse gases. However, in the EU it is not clear whether...... all the six relevant greenhouse gases or only CO2 should be traded. What is the simplest and most practicable solution? We argue in favour of the latter option for three main reasons: the possible dominating global warming potential of CO2, expected future developments in CO2 emissions and the fact...

  11. Convergence of per capita carbon dioxide emissions in the EU: Legend or reality?

    International Nuclear Information System (INIS)

    Jobert, Thomas; Karanfil, Fatih; Tykhonenko, Anna

    2010-01-01

    Designing appropriate environmental and energy policies, in order to meet the Kyoto protocol's carbon dioxide (CO 2 ) reduction targets in the European Union (EU), requires a detailed examination and thorough understanding of CO 2 emission trends across the EU member states. This paper investigates whether CO 2 emissions have converged across 22 European countries over the 1971 to 2006 period. The Bayesian shrinkage estimation method is employed to do this work and the results reveal the following: first, the hypothesis of absolute convergence in per capita CO 2 emissions is supported and a slight upward convergence is observed; second, the fact that countries differ considerably in both their speed of convergence and volatility in emissions makes it possible to identify different groups of countries; third, the results with respect to convergence do not vary much once the share of industry in GDP is accounted for in a conditional convergence analysis. However, a decreasing share of industry in GDP seems to contribute to a decline in per capita emissions. These findings may carry important implications for both national and EU environmental policies.

  12. Examining the role of policy design and policy interaction in EU automotive emissions performance gaps

    International Nuclear Information System (INIS)

    Skeete, Jean-Paul

    2017-01-01

    In the wake of the 2015 ‘Dieselgate’ scandal, the US and European governments publicly confronted automakers about their behaviour, which raised concerns about the integrity of the current emissions legislation regimes. In this article, I argue that ‘flexibilities’ within the EU's emissions legislative framework afforded automakers the opportunity to legally sidestep strict performance standards laid out in the law and resulted in a significant performance gap in real world driving emissions. This article provides a timely examination of EU emission legislation policy design and policy interaction within the European Union with the aim of explaining why the EU policy framework failed to regulate the regional automotive industry. Current research is mostly concerned with the typology and effectiveness of individual environmental policy instruments, be it regulatory or economic incentives, that aim to influence industry behaviour. This article approaches the current EU policy regime in a more holistic manner and focuses on the exploitation of weaknesses in the regulatory framework by private firms, which has received little academic attention in the innovation and transition literature. A major contribution of this article therefore is a body of primary qualitative interview data from industry elites concerning relevant emissions policies. - Highlights: • Significant performance gaps exist between stated and real-world car emissions. • Real-world performance gaps exist due to exploitation of flawed EU policy design. • Diesels have the widest performance gaps and are most harmful to air quality. • Policy interaction compounds EU air quality problems and promotes path-dependency. • Closing performance gaps requires policy revisions and more enforcement autonomy.

  13. Hydrothermal synthesis and white light emission of cubic ZrO2:Eu3+ nanocrystals

    International Nuclear Information System (INIS)

    Meetei, Sanoujam Dhiren; Singh, Shougaijam Dorendrajit

    2014-01-01

    Highlights: • White light emitting cubic ZrO 2 :Eu 3+ nanocrystal is synthesized by hydrothermal technique. • Eu 3+ is used to stabilize crystalline phase and to get red counterpart of the white light. • Defect emission and Eu 3+ emission combined to give white light. • The white light emitted from this nanocrystal resembles vertical daylight of the Sun. • Lifetime corresponding to red counterpart of the sample is far longer than conventional white light emitters. -- Abstract: Production of white light has been a promising area of luminescence studies. In this work, white light emitting nanocrystals of cubic zirconia doped with Eu 3+ are synthesized by hydrothermal technique. The dopant Eu 3+ is used to stabilize crystalline phase to cubic and at the same time to get red counterpart of the white light. The synthesis procedure is simple and precursor required no further annealing for crystallization. X-ray diffraction patterns show the crystalline phase of ZrO 2 :Eu 3+ to be cubic and it is confirmed by Fourier Transform Infrared spectroscopy. From transmission electron microscopy images, size of the crystals is found to be ∼5 nm. Photoluminescence emission spectrum of the sample, on monitoring excitation at O 2− –Eu 3+ charge transfer state shows broad peak due to O 2− of the zirconia and that of Eu 3+ emission. Commission Internationale de l’éclairage co-ordinate of this nanocrystal (0.32, 0.34) is closed to that of the ideal white light (0.33, 0.33). Correlated color temperature of the white light (5894 K) is within the range of vertical daylight. Lifetime (1.32 ms) corresponding to 5 D 0 energy level of the Eu 3+ is found to be far longer than conventional red counterparts of white light emitters. It suggests that the ZrO 2 :Eu 3+ nanocrystals synthesized by hydrothermal technique may find applications in simulating the vertical daylight of the Sun

  14. Research paper no. 18. Trading rules for CO2 emission permits systems. A proposal for ceilings on quantities and prices

    International Nuclear Information System (INIS)

    Criqui, P.; Viguier, L.

    2000-01-01

    Tradable emission permit (TEP) systems for greenhouse gases (GHGs) as they could develop following the Kyoto Protocol - that is if they are limited to Annex B countries and are not bound by exchange regulations) - do not appear to be greatly acceptable today, either to the United States or to the European Union. The problem of the uncertainty related to the cost of reducing emissions is strongly highlighted in the United States: in fact, the approach adopted in the Kyoto Protocol, that of quantitative emissions targets, leaves the question of the reduction programme costs wide open. For the European Union, the unregulated TEP system is hardly acceptable because it would not guarantee that the principle of 'supplementarity' adopted in the Kyoto Protocol, that is, the fact that the purchase of permits should be in addition to action taken within each of the Annex B countries. The section two of this paper is an in-depth economic analysis of the european proposal for ''concrete ceilings''. The alternative proposals, formulated in the United States and relating more to permit price ceilings or''trigger price'', are examined in Section 3. After showing that each of the foregoing proposals could have consequences unacceptable to some or others of the parties to the Protocol, Section 4 offers the proposal of a hybrid formula for regulating the rights market. In fact, the main aim of this paper is to show that the implementation of a 'hybrid solution', consisting of limiting the volume of exchanges while at the same time introducing a TEP price ceiling, could provide a market regulation framework effect allowing the benefits of most of the economic advantages to be enjoyed and also having characteristics acceptable to the various parties from an environmental as well as from an international fairness point of view. (A.L.B.)

  15. Emission Trading - Effects of the EU directive; Emission Trading - Auswirkungen der EG-Richtlinie

    Energy Technology Data Exchange (ETDEWEB)

    Meller, E. [Verband der Elektrizitaetswirtschaft -VDEW- e.V., Berlin (Germany)

    2004-07-01

    The EU-Directive on 'Establishing a Scheme for Greenhouse Gas Emission Allowance Trading within the Community' came into force after it had been published in the Official Journal of the EU. The electricity industry has pursued carefully and constructively the development of this Directive. A number of suggestions were taken into consideration. Currently, the focus - in connection with the adaptation by national legislation - is on the development of a national allocation plan. (orig.) [German] Knapp zwei Jahre nach der Vorlage eines Richtlinien-Entwurfs durch die Europaeische Kommission ist die Richtlinie zur 'Einfuehrung eines EU-weiten Handels mit Treibhausgas-Emissionszertifikaten' in Kraft getreten. Im Mittelpunkt der Umsetzung der Richtlinie in nationales Recht steht die Erstellung eines Nationalen Allokationsplans, dem Kernelement des Zertifikatehandels. Fuer die Stromwirtschaft relevante Aspekte werden eroertert. (orig.)

  16. Social impact of air pollution abatement. Societal cost benefit analysis of possible National Emission Ceilings

    International Nuclear Information System (INIS)

    Doenszelmann, C.E.P.; De Bruyn, S.M.; Korteland, M.H.; De Jong, F.; Sevenster, M.N.; Briene, M.; Wienhoven, M.; Bovens, J.

    2008-07-01

    In 2008, the European Commission will launch new proposals for revision of the NEC guideline (2001/81/EG) in which new emission ceilings are proposed for the year 2020. In order to determine which stand the Netherlands should take during the negotiations, the Dutch Ministry of Economic Affairs (also on behalf of the Ministry of Agriculture, Nature and Food Quality) asked CE Delft and Ecorys to conduct a societal cost benefit analysis in collaboration with the Environmental Assessment Agency. This report describes the results of the analysis of two alternative NEC targets for 2020. [mk] [nl

  17. Self-reduction process and enhanced blue emission in SrAl{sub 2}Si{sub 2}O{sub 8}: Eu, Tb via electron transfer from Tb{sup 3+} to Eu{sup 3+}

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Hongwei; Wang, Lili; Li, Minhong; Ran, Weiguang; Deng, Zhihan; Houzong, Ruizhi; Shi, Jinsheng [Department of Chemistry and Pharmaceutical Science, Qingdao Agricultural University, Qingdao 266109, Shandong, (China)

    2017-06-15

    Eu, Tb co-doped SrAl{sub 2}Si{sub 2}O{sub 8} luminescent materials were synthesized via a high-temperature solid-state reaction. Excitation spectra of SrAl{sub 2}Si{sub 2}O{sub 8}: Eu{sup 2+} gives two broad excitation bands maximizing at 270 and 330 nm, resulting from splitting Eu{sup 2+} energy levels in octahedral crystal field. Eu single doped SrAl{sub 2}Si{sub 2}O{sub 8} luminescent material exhibits two emission bands at about 406 and 616 nm. Intensity of the blue emission from Eu{sup 2+} is always strong, compared with that of the red emission band of Eu{sup 3+}. Reduction from Eu{sup 3+} to Eu{sup 2+} can be explained with the model of charge compensation. Blue emission in SrAl{sub 2}Si{sub 2}O{sub 8}: xEu was strengthened after incorporation of Tb, which can be explained by electron transfer from Tb{sup 3+} to Eu{sup 3+} (Tb{sup 3+} + Eu{sup 3+} → Tb{sup 4+} + Eu{sup 2+}). Under 230 nm excitation, intensity of Tb{sup 3+} emission was nearly unchanged and that of Eu{sup 2+} was increased, obviously due to the delivery of more electrons to Eu{sup 3+}. The strongest emission of Eu{sup 2+} in 0.09Eu/0.06Tb co-doped SrAl{sub 2}Si{sub 2}O{sub 8} and excited at 270 and 330 nm was remarkably enhanced by about four times compared to that of 0.15Eu Single doped SrAl{sub 2}Si{sub 2}O{sub 8}. All of the results indicate that SrAl{sub 2}Si{sub 2}O{sub 8}:xEu, yTb are potential blue emitting luminescent materials for UV-LEDs. More importantly, this research may provide a new perspective in designing broad band blue luminescent materials. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  18. Assessment of Nitrogen Ceilings for Dutch Agricultural Soils to Avoid Adverse Environmental Impacts

    Directory of Open Access Journals (Sweden)

    Wim de Vries

    2001-01-01

    Full Text Available In the Netherlands, high traffic density and intensive animal husbandry have led to high emissions of reactive nitrogen (N into the environment. This leads to a series of environmental impacts, including: (1 nitrate (NO3 contamination of drinking water, (2 eutrophication of freshwater lakes, (3 acidification and biodiversity impacts on terrestrial ecosystems, (4 ozone and particle formation affecting human health, and (5 global climate change induced by emissions of N2O. Measures to control reactive N emissions were, up to now, directed towards those different environmental themes. Here we summarize the results of a study to analyse the agricultural N problem in the Netherlands in an integrated way, which means that all relevant aspects are taken into account simultaneously. A simple N balance model was developed, representing all crucial processes in the N chain, to calculate acceptable N inputs to the farm (so-called N ceiling and to the soil surface (application in the field by feed concentrates, organic manure, fertiliser, deposition, and N fixation. The N ceilings were calculated on the basis of critical limits for NO3 concentrations in groundwater, N concentrations in surface water, and ammonia (NH3 emission targets related to the protection of biodiversity of natural areas. Results show that in most parts of the Netherlands, except the western and the northern part, the N ceilings are limited by NH3 emissions, which are derived from critical N loads for nature areas, rather than limits for both ground- and surface water. On the national scale, the N ceiling ranges between 372 and 858 kton year–1 depending on the choice of critical limits. The current N import is 848 kton year–1. A decrease of nearly 60% is needed to reach the ceilings that are necessary to protect the environment against all adverse impacts of N pollution from agriculture.

  19. Infrequent blue and green emission transitions from Eu3+ in heavy metal tellurite glasses with low phonon energy

    International Nuclear Information System (INIS)

    Lin, H.; Tanabe, S.; Lin, L.; Yang, D.L.; Liu, K.; Wong, W.H.; Yu, J.Y.; Pun, E.Y.B.

    2006-01-01

    Eu 3+ doped alkali-barium-bismuth-tellurite (Eu 3+ :LKBBT) glasses were prepared by conventional melt quenching. Twelve emission bands including infrequent blue and green bands are observed and they almost cover whole visible spectral region under violet light radiation. The blue and green emissions of Eu 3+ rarely appeared in oxide glasses before, but they have been clearly recorded in Eu 3+ :LKBBT glasses even in the case of high concentration doping of Eu 3+ . The analysis based on spontaneous-radiative rate, energy gap and Raman scattering reveals that the obtaining of the abundant multichannel emissions of Eu 3+ is due to the higher refractive index and the lower phonon energy in LKBBT glass system

  20. Cross-border electricity market effects due to price caps in an emission trading system: An agent-based approach

    International Nuclear Information System (INIS)

    Richstein, Jörn C.; Chappin, Emile J.L.; Vries, Laurens J. de

    2014-01-01

    The recent low CO 2 prices in the European Union Emission Trading Scheme (EU ETS) have triggered a discussion whether the EU ETS needs to be adjusted. We study the effects of CO 2 price floors and a price ceiling on the dynamic investment pathway of two interlinked electricity markets (loosely based on Great Britain, which already has introduced a price floor, and on Central Western Europe). Using an agent-based electricity market simulation with endogenous investment and a CO 2 market (including banking), we analyse the cross-border effects of national policies as well as system-wide policy options. A common, moderate CO 2 auction reserve price results in a more continuous decarbonisation pathway. This reduces CO 2 price volatility and the occurrence of carbon shortage price periods, as well as the average cost to consumers. A price ceiling can shield consumers from extreme price shocks. These price restrictions do not cause a large risk of an overall emissions overshoot in the long run. A national price floor lowers the cost to consumers in the other zone; the larger the zone with the price floor, the stronger the effect. Price floors that are too high lead to inefficiencies in investment choices and to higher consumer costs. - Highlights: • Cross-border effects of CO 2 policies were investigated with an agent-based model. • The current EU ETS might cause CO 2 price shocks and CO 2 price volatility. • A CO 2 auction reserve price does not lower welfare, but lowers CO 2 price volatility. • A national CO 2 price floor lowers consumer cost in the other countries. • A CO 2 price ceiling does not lead to an overshoot of emissions

  1. Enforcement of emissions trading: Sanction regimes of greenhouse gas emissions trading in the EU and China

    NARCIS (Netherlands)

    Peeters, M.G.W.M.; Chen, Huizhen

    2015-01-01

    Abstract: This chapter aims to further the debate regarding the role of law for establishing an adequate enforcement strategy for an emissions trading scheme. We focus on sanction regimes within the EU ETS and the Chinese emissions trading pilot projects. Section 2 sets the scene by pointing at the

  2. Diffuse ceiling ventilation

    DEFF Research Database (Denmark)

    Zhang, Chen

    Diffuse ceiling ventilation is an innovative ventilation concept where the suspended ceiling serves as air diffuser to supply fresh air into the room. Compared with conventional ventilation systems, diffuse ceiling ventilation can significantly reduce or even eliminate draught risk due to the low...

  3. EU Emission Allowances and the stock market Evidence from the electricity industry

    International Nuclear Information System (INIS)

    Oberndorfer, Ulrich

    2009-01-01

    This paper constitutes - to our best knowledge - the first econometric analysis on stock market effects of the EU Emission Trading Scheme (EU ETS). Our results suggest that EU Emission Allowance (EUA) price developments matter to the stock performance of electricity firms: EUA price changes and stock returns of the most important European electricity corporations are shown to be positively related. This effect does not work asymmetrically, so that stock markets do not seem to react differently to EUA appreciations in comparison to depreciations. The carbon market effect is shown to be both time- and country-specific: It is particularly strong for the period of EUA market shock in early 2006, and differs with respect to the countries where the electricity corporations analysed are headquartered. Stock market reactions to EUA volatility could not be shown. (author)

  4. Enforcement of emissions trading - sanction regimes of greenhouse gas emissions trading in the EU and China

    NARCIS (Netherlands)

    Peeters, Marjan; Chen, Huizhen; Weishaar, Stefan

    2016-01-01

    This chapter aims to further the debate regarding the role of law for establishing an adequate enforcement strategy for an emissions trading scheme. We focus on sanction regimes within the EU ETS and the Chinese emissions trading pilot projects. Section 2 sets the scene by pointing at the need of an

  5. Diffuse Ceiling Ventilation

    DEFF Research Database (Denmark)

    Zhang, Chen; Heiselberg, Per; Nielsen, Peter V.

    2014-01-01

    As a novel air distribution system, diffuse ceiling ventilation combines the suspended acoustic ceiling with ventilation supply. Due to the low-impulse supply from the large ceiling area, the system does not generate draught when supplying cold air. However, heat sources play an important role...

  6. The impact of the EU emissions trading scheme on the price of electricity in the Netherlands

    International Nuclear Information System (INIS)

    Sijm, J.P.M.

    2004-02-01

    In this paper a specific aspect of the proposed EU Emissions Trading System (EU ETS) is discussed, namely the potential impact of the EU ETS on the price of electricity in the Netherlands and, hence, the potential implications for Dutch power producers and consumers. It shows that the EU ETS may lead to a significant increase in the price of electricity in the Netherlands (and other EU Member States), depending on the marginal costs of emissions trading (i.e. the price of an emission allowance), the emission factor of the marginal production technology to generate electricity, and the extent to which the costs of emissions trading will be passed on to the end-users of electricity. If, for one reason or another, these costs will not be passed on to power consumers, it will have an adverse impact on overall efficiency from both an energy and economic point of view. On the other hand, if - as expected - these costs are indeed passed on to end-users of electricity, it will benefit power producers (mainly owing to the economic rent of allocating emission allowances for free), while it will harm those energy-intensive industries that, in turn, are not able to pass the higher electricity costs to their customers (resulting in a loss of economic production and income). To some degree, these effects can be best avoided by auctioning emission allowances mandatory throughout the EU ETS and using the auction revenues to reduce the overall level of taxation and social premiums in order to improve the overall competitiveness of domestic industries and to (partly) compensate power consumers for the ET-induced increase in the price of electricity

  7. An evaluation of possible EU air transport emissions trading scheme allocation methods

    International Nuclear Information System (INIS)

    Morrell, Peter

    2007-01-01

    The European Commission has been requested by member states to study the incorporation of air transport into their existing emissions trading scheme (ETS). Only CO 2 is to be included, at least initially. This paper focuses on the method of allocation of emissions permits in the EU context. It has been assumed here that the EU ETS will be applied only to intra-EU flights and that airlines will be the entities selected for implementation. Three UK airlines were selected to evaluate three main types of allocation: grandfathering, auctioning and benchmarking. The airlines were representative of the three major airline business models: network, low-cost carrier and charter/leisure. Based on 2003/2004 aircraft/engine type and operating data, the per passenger impact of each allocation option was analysed for each airline. A new benchmarking approach is proposed that takes into account both the landing and take-off (LTO) cycle and per kilometre emissions: this avoids penalising shorter sector operators and focuses on the damage caused by aircraft and their engines and not on passengers. (author)

  8. Ratiometric luminescence thermometry with different combinations of emissions from Eu3+ doped Gd2Ti2O7 nanoparticles

    International Nuclear Information System (INIS)

    Lojpur, Vesna; Ćulubrk, Sanja; Dramićanin, Miroslav D.

    2016-01-01

    Herein, Eu 3+ doped Gd 2 Ti 2 O 7 nanoparticles were tested for application in ratiometric luminescence thermometry. It is shown that two combinations of emissions: one that uses two emissions of Eu 3+ ions and one that uses one emission of Eu 3+ ions and trap emission of Gd 2 Ti 2 O 7 provide thermometry over the 303–423 K temperature range with relative sensitivities between 0.14% K −1 and 0.95% K −1 . Thermometry based on two Eu 3+ emissions from 5 D 0 to 5 D 1 levels has a higher relative sensitivity, but lower absolute sensitivity than thermometry based on one Eu 3+ emission and trap emission of Gd 2 Ti 2 O 7 . The tested material is prepared by Pechini-type polymerized complex route and is composed of agglomerated nanoparticles of ~30–50 nm in size with pure-phase cubic structure (space group Fd-3m) as evidenced from electron microscopy and X-ray diffraction measurements. - Highlights: • Eu 3+ doped Gd 2 Ti 2 O 7 nanoparticles can serve as probes for luminescence thermometry. • Gd 2 Ti 2 O 7 trap emission is an excellent internal standard for luminescence thermometry. • Temperature is measured over 303–423 K range with sensitivity ranging 0.14–0.95% K −1 .

  9. Climate and competitiveness: An economic impact assessment of EU leadership in emission control policies

    Energy Technology Data Exchange (ETDEWEB)

    Alexeeva-Talebi, V.; Boehringer, C.; Moslener, U. [Centre for European Economic Research, Mannheim (Germany)

    2007-07-01

    The European Council has recently claimed to consider ambitious emission reduction targets (15 to 30 percent by 2020 as compared to 1990 levels) to limit global climate change. In light of the coexistent EU priorities under the Lisbon process, the authors analyze alternative unilateral EU emission control policies against their effects on EU (sectoral and economy-wide) competitiveness using a multi-sector, multi-region computable general equilibrium (CGE) model framework. For a given emission reduction target, the simulations show that alternative implementation rules (uniform versus sectorally differentiated carbon taxes) induce ambiguous impacts on sectoral competitiveness: For a uniform tax, relatively carbon-intensive EU industries face competitiveness losses, while carbon-extensive sectors improve their ability to compete internationally. Losses and gains are reinforced by the stringency of unilateral emission reduction targets. Thus, the implementation of an (economically efficient) uniform carbon tax induces structural change which inevitably goes at the expense of carbon-intensive industries. Vice versa, the authors find that more pronounced tax differentiation in favor of carbon-intensive industries can largely neutralize the negative impacts of emission constraints on their competitiveness, but goes at the expense of overall efficiency. In this case, adjustment costs of emission abatement will to a large extent be born by energy-extensive sectors in terms of a deteriorated ability to compete. As a middle course, moderate tax differentiation allows to sectorally balance competitiveness effects of emission control policies and at the same time limit overall efficiency losses. The authors find also that the level of tax differentiation to balance sectoral competitiveness effects and to limit overall efficiency losses is independent of the emission reduction target. Furthermore, the results indicate that the magnitude of sectoral competitiveness effects is

  10. Key Questions for Achieving EU Emission Reductions without Abandoning Other Energy Goals

    International Nuclear Information System (INIS)

    Stang, G.

    2014-01-01

    What considerations must be addressed to ensure that efforts to achieve the EU's new 2030 emissions and renewables targets are compatible with the other energy goals of the EU and its member states: energy security, and energy affordability? How should these other energy goals be addressed when pursuing energy efficiency improvements, upgrading electricity systems to handle different renewable energy sources, and developing policies to reduce overall CO2 emissions? Markets have been defined as being central to achieving all of Europe's energy goals - both the creation of an EU internal energy market and the use of the Emissions Trading System (ETS) to allow a market for managing a portion of the continent's greenhouse gas emissions. But once these markets are in place and operational, there will still be great variances among the goals, instruments, and level of market integration available for the different countries and regions of Europe. Choosing the most cost effective mechanisms for pursuing the new goals will require effective use of the flexibility that is available - an improved ETS, tradable national targets for non-ETS emissions, and a rapidly widening array of cost-effective renewable energy options. Sufficient use of this flexibility should facilitate the flow of energy investments toward energy system improvements where there is low-hanging fruit - anywhere in the continent - without requiring that local or continental energy security goals be sacrificed. (author).

  11. From the glass door to the glass ceiling: An analysis of the gender wage gap by age groups

    OpenAIRE

    Elena Dalla Chiara; Eleonora Matteazzi; Ilaria Petrarca

    2014-01-01

    Using 2009 EU-SILC data for France, Italy, the Netherlands and the United Kingdom, we decompose the gender wage gap for prime age workers. We adopt an age group approach to identify when and how the glass door and the glass ceiling effects arise and their persistency over time. The empirical results verify that the raw gender wage gap increases with age. In all considered countries, the glass ceiling effect is completely realized by the age of 30 and increases over time. French, Italian and B...

  12. Synthesis and tunable luminescent properties of Eu-doped Ca2NaSiO4F – Coexistence of the Eu2+ and Eu3+ centers

    Directory of Open Access Journals (Sweden)

    Mubiao Xie

    Full Text Available Novel phosphors Ca2NaSiO4F:Eu were synthesized successfully by the conventional solid-state method in CO atmosphere, and their spectroscopic properties in UV−vis region were investigated. The photoluminescence properties show that Eu3+ ions were partially reduced to Eu2+ in Ca2NaSiO4F. As a result of radiation and re-absorption energy transfer from Eu2+ to Eu3+, both Eu2+ bluish-green emission at around 520 nm and Eu3+ red emission are observed in the emission spectra under the n-UV light excitation. Furthermore, the ratio between Eu2+ and Eu3+ emissions varies with increasing content of overall Eu. Because relative intensity of the red component from Eu3+ became systematically stronger, white light emission can be realized by combining the emission of Eu2+ and Eu3+ in a single host lattice under n-UV light excitation. These results indicate that the Ca2NaSiO4F:Eu phosphors have potential applications as a n-UV convertible phosphor for light-emitting diodes. Keywords: Phosphors, Luminescence, White LED, Optical materials

  13. Norway and the EU may trade emission quotas from 2005

    International Nuclear Information System (INIS)

    Tjernshaugen, Andreas

    2002-01-01

    The EU commission wants to implement quota trade with climate gases from 2005. The proposal, which came in October 2001, describes a quota system limited to the emission of CO 2 in certain industrial sectors. Sources like road traffic and heating of buildings are not comprised by the proposal. It is intended that the agreement will later include more climate gases and more types of activities. This expansion of the implementation becomes most important from 2008-2012, for then the Kyoto Protocol sets the limits for six types of climate gases and lays down rules for international trade with emission quotas. Norway is likely to go in for a limited quota system for 2005 to 2007 and apply for an agreement with the quota market of the EU. It is not certain, however, that the Norwegian authorities will limit the national quota system the same way

  14. Fracto-mechanoluminescent light emission of EuD4TEA-PDMS composites subjected to high strain-rate compressive loading

    Science.gov (United States)

    Ryu, Donghyeon; Castaño, Nicolas; Bhakta, Raj; Kimberley, Jamie

    2017-08-01

    The objective of this study is to understand light emission characteristics of fracto-mechanoluminescent (FML) europium tetrakis(dibenzoylmethide)-triethylammonium (EuD4TEA) crystals under high strain-rate compressive loading. As a sensing material that can play a pivotal role for the self-powered impact sensor technology, it is important to understand transformative light emission characteristics of the FML EuD4TEA crystals under high strain-rate compressive loading. First, EuD4TEA crystals were synthesized and embedded into polydimethylsiloxane (PDMS) elastomer to fabricate EuD4TEA-PDMS composite test specimens. Second, the prepared EuD4TEA-PDMS composites were tested using the modified Kolsky bar setup equipped with a high-speed camera. Third, FML light emission was captured to yield 12 bit grayscale video footage, which was processed to quantify the FML light emission. Finally, quantitative parameters were generated by taking into account pixel values and population of pixels of the 12 bit grayscale images to represent FML light intensity. The FML light intensity was correlated with high strain-rate compressive strain and strain rate to understand the FML light emission characteristics under high strain-rate compressive loading that can result from impact occurrences.

  15. How to restrain electroplex emission and enhance red emission intensity of Eu 3+ complex?

    Science.gov (United States)

    Zhang, Fujun; Zhao, Suling; Xu, Zheng; Huang, Jinzhao; Yuan, Guancai; Li, Yuan; Wang, Yong; Xu, Xurong

    2007-11-01

    The electroluminescence (EL) of lanthanide complex profits from the intramolecular energy transfer from the triplet state of ligand to Ln (III) ions, but electroplex emission between ligand and host material may occur when the energy transfer is inefficient. The electroplex emission is completely restrained when 4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7,-tetramethyljulolidy-9-enyl)-4Hpyran (DCJTB) and Eu(o-BBA)3(phen) are co-doped in poly (N-vinycarbzaole) (PVK). There are great spectra overlapping between electroplex emission and the excitation of DCJTB. The chromaticity coordinates of EL of co-doped device is kept constant (x = 0.55, y = 0.37) under different driving voltage.

  16. Interaction of the EU emissions Trading Directive with climate policy instrument in the Netherlands. Policy Brief

    International Nuclear Information System (INIS)

    Sijm, J.P.M.

    2003-11-01

    This policy brief presents an overview of the implications of the proposed EU Emissions Trading Scheme (EU ETS) for some selected energy and climate policy instruments in the Netherlands. It summarises the results of research that has been conducted by the Energy research Centre of the Netherlands (ECN) as part of the EU-funded project Interaction in EU Climate Policy

  17. The impact of the Nitrates Directive on nitrogen emissions from agriculture in the EU-27 during 2000-2008.

    Science.gov (United States)

    Velthof, G L; Lesschen, J P; Webb, J; Pietrzak, S; Miatkowski, Z; Pinto, M; Kros, J; Oenema, O

    2014-01-15

    A series of environmental policies have been implemented in the European Union (EU) to decrease nitrogen (N) emissions from agriculture. The Nitrates Directive (ND) is one of the main policies; it aims to reduce nitrate leaching from agriculture through a number of measures. A study was carried out to quantify the effects of the ND in the EU-27 on the leaching and runoff of nitrate (NO3(-)) to groundwater and surface waters, and on the emissions of ammonia (NH3), nitrous oxide (N2O), nitrogen oxides (NO(x)) and dinitrogen (N2) to the atmosphere. We formulated a scenario with and a scenario without implementation of the ND. The model MITERRA-Europe was used to calculate N emissions on a regional level in the EU-27 for the period 2000-2008. The calculated total N loss from agriculture in the EU-27 was 13 Mton N in 2008, with 53% as N2, 22% as NO3, 21% as NH3, 3% as N2O, and 1% as NO(x). The N emissions and leaching in the EU-27 slightly decreased in the period 2000-2008. Total emissions in the EU in 2008 were smaller with implementation of the ND than without the ND, by 3% for NH3, 6% for N2O, 9% for NO(x), and 16% for N leaching and runoff in 2008. However, regional differences were large. The lower emissions with ND were mainly due to the lower N inputs by fertilizers and manures. In conclusion, implementation of the ND decreased both N leaching losses to ground and surface waters, and gaseous emissions to the atmosphere. It is expected that the ND will result in a further decrease in N emissions in EU-27 in the near future, because the implementation of the measures for the ND is expected to become more strict. Copyright © 2013 Elsevier B.V. All rights reserved.

  18. Suspended ceilings

    Energy Technology Data Exchange (ETDEWEB)

    Talamo, C.

    1991-05-01

    The retrofitting of existing conventional ceiling systems to suspended ceiling type systems represents an interesting energy savings solution since this method, in addition to providing additional protection against space heat loss and thermal bridges, also creates the possibility of housing, in the void, additional mechanical and electrical lines which may be necessary due to other savings interventions. This paper reviews the various suspended ceiling systems (e.g., those making use of mineral fibre, gypsum panels, wood, vermiculite, etc.) currently marketed in Europe, and reports, for each, some key technical, economic and architectural advantages which include thermal efficiency, noise abatement, as well as, resistance to fire and humidity. Information is also given on the relative installation and maintenance requirements.

  19. Extension of EU Emissions Trading Scheme to Other Sectors and Gases: Consequences for Uncertainty of Total Tradable Amount

    International Nuclear Information System (INIS)

    Monni, S.; Syri, S.; Pipatti, R.; Savolainen, I.

    2007-01-01

    Emissions trading in the European Union (EU), covering the least uncertain emission sources of greenhouse gas emission inventories (CO 2 from combustion and selected industrial processes in large installations), began in 2005. During the first commitment period of the Kyoto Protocol (2008-2012), the emissions trading between Parties to the Protocol will cover all greenhouse gases (CO 2 , CH 4 , N 2 O, HFCs, PFCs, and SF 6 ) and sectors (energy, industry, agriculture, waste, and selected land-use activities) included in the Protocol. In this paper, we estimate the uncertainties in different emissions trading schemes based on uncertainties in corresponding inventories. According to the results, uncertainty in emissions from the EU15 and the EU25 included in the first phase of the EU emissions trading scheme (2005-2007) is ±3% (at 95% confidence interval relative to the mean value). If the trading were extended to CH 4 and N 2 O, in addition to CO 2 , but no new emissions sectors were included, the tradable amount of emissions would increase by only 2% and the uncertainty in the emissions would range from -4 to +8%. Finally, uncertainty in emissions included in emissions trading under the Kyoto Protocol was estimated to vary from -6 to +21%. Inclusion of removals from forest-related activities under the Kyoto Protocol did not notably affect uncertainty, as the volume of these removals is estimated to be small

  20. Red light emission from ZnO:Eu"3"+|CuSCN hetero-junction under cathodic polarization

    International Nuclear Information System (INIS)

    Sirimanne, P.M.; Minoura, H.

    2015-01-01

    Eu"3"+ ions were bonded to ZnO ceramic via organic ligand. Surface bonded Eu"3"+ ions were exhibited specific luminescence bands due to electron transitions between f–f intra-configurationally transitions. Further enhancement of luminescence bands was observed by attaching selected oligomers to Eu"3"+ ions. A hetero-junction was prepared by depositing copper-thiocyanate on Eu"3"+ ions bonded ZnO ceramic. Red light emission was observed from surface bonded Eu"3"+ ions in ZnO:Eu"3"+|CuSCN hetero-junction under reverse bias. - Highlights: • Europium doped ZnO ceramic exhibits photo-luminescence. • Semiconductor hetro-junction was prepared. • ZnO:Eu"3"+|CuSCN hetero-junction emits red light under reverse bias.

  1. Temperature dependent emission characteristics of monoclinic YBO{sub 3}: Eu{sup 3+}/Tb{sup 3+} phosphor

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Suchinder K., E-mail: suchindersharma@gmail.com [AMO-Physics Division, Physical Research Laboratory, Navrangpura, Ahmedabad 380009 (India); Malik, M. Manzar [Department of Physics, Maulana Azad National Institute of Technology (MANIT), Bhopal (India)

    2016-05-15

    YBO{sub 3}:Eu{sup 3+}/Tb{sup 3+} phosphor samples synthesized by modified combustion method are studied in the present work using powder X-ray diffraction, UV–visible absorption spectroscopy, X-ray excited luminescence spectroscopy and optical parametric oscillator (OPO) based laser excited emission spectroscopy. The temperature dependence of luminescence emission is also studied. The structural analysis suggests that the samples possess monoclinic structure with C2/c space group. The emission maximum was excitation wavelength dependent and prominent emission was observed at 593 nm (241 nm excitation) and 613 nm (300 nm excitation) for YBO{sub 3}:Eu{sup 3+} samples. The prominent magnetic/ electric (593/613 nm) dipole-moment allowed transitions are attributed to the presence of Eu{sup 3+} at different sites. For YBO{sub 3}:Tb{sup 3+} phosphor, 543 nm emission was prominent and had no impact of the cite symmetry. The increase in PL intensity in Eu{sup 3+} doped samples above 225 K is associated with the carrier mobility. An energy level scheme showing the positions of the 4f and 5d energy levels of all divalent and trivalent lanthanide ions relative to the valence and conduction band of the YBO{sub 3} has been constructed opening the possibility of using YBO{sub 3} for other interesting applications. - Highlights: • Synthesis of YBO{sub 3} by modified combustion method using glycine as fuel. • Crystallization in monoclinic phase (rarely investigated). • Eu and Tb doping and investigation of temperature dependent PL. • VRBE diagram generated in YBO{sub 3} to develop new optical materials.

  2. Energy transfer driven tunable emission of Tb/Eu co-doped lanthanum molybdate nanophosphors

    Science.gov (United States)

    Thomas, Kukku; Alexander, Dinu; Sisira, S.; Gopi, Subash; Biju, P. R.; Unnikrishnan, N. V.; Joseph, Cyriac

    2018-06-01

    Tb3+/Eu3+ co-doped lanthanum molybdate nanophosphors were synthesized by conventional co-precipitation method. The Powder X-ray diffractogram revealed the formation of highly crystalline tetragonal nanocrystals with space group I41/a and the detailed analysis of the small variation of lattice parameters with Tb/Eu co-doping on the host lattice were carried out based on the ionic radii of the dopants. The FTIR spectra is employed to identify the fundamental vibrational modes in La2-x-y (MoO4)3:xTb, yEu nanocrystals. The formation of nanocrystals by oriented attachment was recognized from the HR TEM images and the d-spacing calculated was in accordance with that corresponding to highest intensity diffraction peak in the XRD patterns. The constituent elements present in the samples were identified with the aid of EDAX and elemental mapping analysis. The broad Mo6+- O2- CTB and the sharp excitation peaks of Tb and Eu identified from the UV-Vis absorption spectra facilitates the suitability of exciting the phosphors effectively over NUV and visible region of the spectra. The possibility of energy transfer from host to Tb3+/Eu3+ ions and from Tb3+ to Eu3+ ions were confirmed from the PL excitation spectra monitoring 5D0→7F2 transition of Eu3+ ions around 615 nm. The correlated analysis of PL emission spectra, life time measurements and CIE diagram, upon different excitation channels elucidate the excellent luminescent properties of La2-x-y (MoO4)3:xTb, yEu nanophosphors with tunable emission colours in a wide range varying from yellow green region to reddish orange region and the efficient energy transfer from Tb3+ to Eu3+ ions in lanthanum molybdate host lattice. The Tb→Eu energy transfer efficiency and probability were calculated from the decay measurements and the values were found to be satisfactory for exploiting the prepared nanophosphors for the development of multifunctional luminescent nanophosphors.

  3. Emissions trading in the Netherlands

    International Nuclear Information System (INIS)

    Zapfel, P.

    2002-01-01

    In the article 'Emissions trading in the Netherlands. The optimal route towards an international scheme?' (issue 1, 2002) Mulder asks the question to what extent a Dutch national CO2 trading scheme is a worthwhile effort toward an international trading scheme (i.e. is it a first step toward a European-wide emissions trading scheme) when presenting the proposal of the Dutch Commission on CO2 trade and related economic analysis. His conclusion, underlined by modeling results, is that a national scheme along the lines proposed by the Dutch Commission is an expensive policy instrument due to the high transaction costs. The first-best option according to Mulder is to impose CO2-emissions trading with an absolute ceiling on an international level. In the meantime, he states, improving the design of the energy tax system may be an efficient alternative. In this comment I would like to address two issues. First, does the approach proposed by the Dutch Commission make sense from a European perspective towards an EU-wide cap and trade allowance scheme as proposed by the European Commission in October 2001? and Second, what might this Dutch model and philosophy, scaled up to the EU level, look like?

  4. Energy Transfer Efficiency from ZnO-Nanocrystals to Eu3+ Ions Embedded in SiO₂ Film for Emission at 614 nm.

    Science.gov (United States)

    Mangalam, Vivek; Pita, Kantisara

    2017-08-10

    In this work, we study the energy transfer mechanism from ZnO nanocrystals (ZnO-nc) to Eu 3+ ions by fabricating thin-film samples of ZnO-nc and Eu 3+ ions embedded in a SiO₂ matrix using the low-cost sol-gel technique. The time-resolved photoluminescence (TRPL) measurements from the samples were analyzed to understand the contribution of energy transfer from the various ZnO-nc emission centers to Eu 3+ ions. The decay time obtained from the TRPL measurements was used to calculate the energy transfer efficiencies from the ZnO-nc emission centers, and these results were compared with the energy transfer efficiencies calculated from steady-state photoluminescence emission results. The results in this work show that high transfer efficiencies from the excitonic and Zn defect emission centers is mostly due to the energy transfer from ZnO-nc to Eu 3+ ions which results in the radiative emission from the Eu 3+ ions at 614 nm, while the energy transfer from the oxygen defect emissions is most probably due to the energy transfer from ZnO-nc to the new defects created due to the incorporation of the Eu 3+ ions.

  5. Evaluation of policy options to reform the EU Emissions Trading System. Effects on carbon price, emissions and the economy

    Energy Technology Data Exchange (ETDEWEB)

    Verdonk, M.; Brink, C.; Vollebergh, H.; Roelfsema, M.

    2013-04-15

    The EU Emissions Trading System (EU ETS) is a key instrument of EU climate policy, providing a clear reduction pathway for CO2 emissions. The current carbon price (of about 3 euros per tonne of CO2, April 2013) is much lower than previously expected (which was around 30 euros) and is likely to remain low for a long time. This fuels doubts about whether the ETS will remain a key policy instrument in the long term. Such doubts also increase investment uncertainty, which is likely to have a negative impact on further investments in low-carbon technologies needed for a low-carbon economy in 2050. In November 2012, the European Commission put forward six options for a more structural reform of the EU ETS. The proposed options vary from reducing the cap and expanding the ETS to include other sectors, to strengthening the ETS by measures directly affecting allowance prices. The Dutch Ministry of Infrastructure and the Environment (IenM) asked the PBL Netherlands Environmental Assessment Agency to assess the impact of these options. Four categories of options for reforming the ETS were evaluated: (1) reducing the supply of emission allowances; (2) expanding the ETS by including other sectors; (3) a minimum price for auctioned allowances; and (4) combining ETS with a carbon tax. Recently, the European Parliament voted against the European Commission's proposal to temporarily set aside emission allowances. In an earlier assessment of this proposal, PBL concluded that the impact of this backloading proposal on CO2 prices is likely to be limited, because the total amount of allowances up to 2020 would remain unchanged. All options analysed would reduce emissions and cause the emission price to increase. A minimum price on carbon, however, would provide the best opportunity to make the ETS more robust against unforeseen events, such as a further deterioration of the economy. Such a minimum price would result in more emission reductions if abatement proves to be cheaper

  6. Incentives for energy efficiency in the EU emission trading scheme

    Energy Technology Data Exchange (ETDEWEB)

    Schleich, Joachim [Fraunhofer-Institut fuer Systemtechnik und Innovationsforschung (ISI), Karlsruhe (Germany); Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States); Rogge, Karoline [Fraunhofer-Institut fuer Systemtechnik und Innovationsforschung (ISI), Karlsruhe (Germany); ETH Zurich (Switzerland). Group for Sustainability and Technology; Betz, Regina [New South Wales Univ. (Australia). Centre for Energy and Environmental Markets

    2008-07-01

    This paper explores the incentives for energy efficiency induced by the European Union Emissions Trading Scheme (EU ETS) for installations in the energy and industry sectors. Our analysis of the National Allocation Plans for 27 EU Member States for phase 2 of the EU ETS (2008-2012) suggests that the price and cost effects for improvements in carbon and energy efficiency in the energy and industry sectors will be stronger than in phase 1 (2005-2007), but only because the European Commission has substantially reduced the number of allowances to be allocated by the Member States. To the extent that companies from these sectors (notably power producers) pass through the extra costs for carbon, higher prices for allowances translate into stronger incentives for demand- side energy efficiency. With the cuts in allocation to energy and industry sectors these will be forced to greater reductions, thus the non-ET sectors like household, tertiary and transport will have to reduce less, which is more in line with the cost-efficient share of emission reductions. The findings also imply that domestic efficiency improvements in the energy and industry sectors may remain limited since companies can make substantial use of credits from the Kyoto mechanisms. The analysis of the rules for existing installations, new projects and closures suggests that incentives for energy efficiency are higher in phase 2 than in phase 1 because of the increased application of benchmarking to new and existing installations and because a lower share of allowances will be allocated for free. Nevertheless, there is still ample scope to further improve the EU ETS so that the full potential for energy efficiency can be realized. (orig.)

  7. The Best (and Worst) of GHG Emission Trading Systems: Comparing the EU ETS with Its Followers

    International Nuclear Information System (INIS)

    Borghesi, Simone; Montini, Massimiliano

    2016-01-01

    The European Emission Trading System (EU ETS) is generally considered as the prototype system for the other Emission Trading Systems (ETSs) for the reduction of greenhouse gases (GHGs) that are rapidly spreading around the world. To get a deeper understanding on the actual capacity of the EU ETS to stand as a model for the other ETSs, the present paper discusses the differences and similarities of the EU ETS with respect to the other main ETSs and the emerging trends that these systems seem to share, comparing the different cap-and-trade regimes in order to identify the best practices and the desirable features that future ETSs should have. As emerges from the comparative analysis performed in this article, although the followers share some common flaws with the EU ETS, they have also shown the capacity to innovate and possibly devise alternative ways to manage their own ETS regimes, which may in the long term jeopardize the EU leadership in the ETSs context.

  8. The Best (and Worst) of GHG Emission Trading Systems: Comparing the EU ETS with Its Followers

    Energy Technology Data Exchange (ETDEWEB)

    Borghesi, Simone, E-mail: simone.borghesi@unisi.it; Montini, Massimiliano [University of Siena, Siena (Italy)

    2016-07-29

    The European Emission Trading System (EU ETS) is generally considered as the prototype system for the other Emission Trading Systems (ETSs) for the reduction of greenhouse gases (GHGs) that are rapidly spreading around the world. To get a deeper understanding on the actual capacity of the EU ETS to stand as a model for the other ETSs, the present paper discusses the differences and similarities of the EU ETS with respect to the other main ETSs and the emerging trends that these systems seem to share, comparing the different cap-and-trade regimes in order to identify the best practices and the desirable features that future ETSs should have. As emerges from the comparative analysis performed in this article, although the followers share some common flaws with the EU ETS, they have also shown the capacity to innovate and possibly devise alternative ways to manage their own ETS regimes, which may in the long term jeopardize the EU leadership in the ETSs context.

  9. Interaction between the EU emissions trading scheme and energy policy instruments in the Netherlands. Implications of the EU Directive for Dutch Climate Policies

    International Nuclear Information System (INIS)

    Sijm, J.P.M.; Van Dril, A.W.N.

    2003-11-01

    The present study analyses the potential interactions between the EU Emissions Trading Scheme (EU ETS) and some selected energy and climate policy instruments in the Netherlands. These instruments include: (1) The Benchmarking Covenant (BC): a negotiated agreement with energy-intensive industries in order to improve their energy efficiency; (2) The Regulatory Energy Tax (REB): an ecotax (or levy) on the consumption of gas and electricity, including the partial exemption of this ecotax on renewable electricity; (3) The Environmental Quality of Electricity Production (MEP): a feed-in subsidy system for producers of renewable electricity; and (4) The system of Tradable Green Certificates (TGCs): a system of guarantees of origin to promote renewable electricity based on the partial exemption of the REB. A general finding of the present report is that once the EU ETS becomes operational, the effectiveness of all other policies to reduce CO2 emissions of the participating sectors becomes zero. The report explores the specific implications of this general finding for the coexistence of the EU ETS and the selected policy instruments in the Netherlands. It concludes that this coexistence will have a significant impact on the performance of both the EU ETS and the selected instruments in the Netherlands

  10. White-emission in single-phase Ba2Gd2Si4O13:Ce3 +,Eu2 +,Sm3 + phosphor for white-LEDs

    Science.gov (United States)

    Jiang, Xiumin; Zhang, Yuqian; Zhang, Jia

    2018-03-01

    To develop new white-light-emitting phosphor, a series of Ce3 +-Eu2 +-Sm3 + doped Ba2Gd2Si4O13 (BGS) phosphors were prepared by the solid-state reaction method, and their photoluminescence properties were studied. The Ce3 + and Eu2 + single-doped BGS show broad emission bands around in the region of 350-550 and 420-650 nm, respectively. By co-doping Ce3 +-Eu2 + into BGS, the energy transfer (ET) from Ce3 + to Eu2 + is inefficient, which could be due to the competitive absorption between the two activator ions. The Sm3 +-activated BGS exhibits an orangey-red emission in the region of 550-750 nm. To achieve white emission, the BGS:0.06Ce3 +,0.04Eu2 +,ySm3 + (0 ≤ y ≤ 0.18) phosphors were designed, in which the ET from Ce3 +/Eu2 + to Sm3 + was observed. The emission color can be tuned by controlling the Sm3 + concentration, and white emission was obtained in the BGS:0.06Ce3 +,0.04Eu2 +,0.06Sm3 + sample. The investigation of thermal luminescence stability for the typical BGS:0.06Ce3 +,0.04Eu2 +,0.06Sm3 + sample reveals that the emission intensities of both Eu2 + and Sm3 + demonstrate continuous decrease but the Ce3 + emission is enhanced gradually with increasing temperature. The corresponding reason has been discussed.

  11. Fluorescence emission behavior of Eu(III) sorbed on calcium silicate hydrates as a secondary mineral formed without drying process

    International Nuclear Information System (INIS)

    Niibori, Yuichi; Narita, Masayuki; Chida, Taiji; Mimura, Hitoshi; Kirishima, Akira

    2014-01-01

    Calcium silicate hydrate (CSH) is a main component of cement-based material required for constructing the geological repository. As in many countries, since the repository in Japan is constructed below water table, we must consider the interaction of radionuclide with cement materials altered around the repository after the backfill. Using fluorescence emission spectra, so far, the authors have investigated the interaction of Eu(III) (as a chemical analog of Am(III)) with CSH gels as a secondary mineral formed without drying process, considering a condition saturated with groundwater. However, in such fluorescence emission behaviors, a deexcitation process of OH vibrators of light water and a quenching effect caused by Eu-Eu energy transfer between Eu atoms incorporated in the CSH gel must be considered. This study examined the fluorescence emission behavior of Eu(III) sorbed on CSH gels, by using La(III) (non-fluorescent ions) as a diluent of Eu(III). Furthermore, CSH samples were synthesized with CaO, SiO 2 , and heavy water (D 2 O) as a solvent in order to avoid the obvious deexcitation process of OH vibrators of light water. In the results, the peak around 618 nm was split into two peaks of 613 nm and 622 nm in the cases of Ca/Si=1.0 and 1.6. Then, the peak of 613 nm decreased with increment of Eu(III)/La(III) ratio. This means that the relative intensity of 613 nm is useful to quantify the amount of Eu(III) incorporated in CSH gel. Besides, the decay behavior of the fluorescence emission did not depend on the Eu/La concentration ratio. That is, such a quenching effect is neglectable. Additionally, the fluorescence emission spectra of Eu(III) showed that the state of Eu(III) depended on Ca/Si ratio of CSH. This suggested that there was several sites in CSH to incorporate Eu(III). When CSH is altered, whole cementitious material in repository must be altered forming cracks and leaching some calcium compositions. Therefore, the adsorptive capacity of CSH might

  12. Substantial enhancement of red emission intensity by embedding Eu-doped GaN into a microcavity

    Directory of Open Access Journals (Sweden)

    Tomohiro Inaba

    2016-04-01

    Full Text Available We investigate resonantly excited photoluminescence from a Eu,O-codoped GaN layer embedded into a microcavity, consisting of an AlGaN/GaN distributed Bragg reflector and a Ag reflecting mirror. The microcavity is responsible for a 18.6-fold increase of the Eu emission intensity at ∼10K, and a 21-fold increase at room temperature. We systematically investigate the origin of this enhancement, and we conclude that it is due to the combination of several effects including, the lifetime shortening of the Eu emission, the strain-induced piezoelectric effect, and the increased extraction and excitation field efficiencies. This study paves the way for an alternative method to enhance the photoluminescence intensity in rare-earth doped semiconductor structures.

  13. The next step in Europe's climate action. Setting targets for 2030. Reviving the EU emissions trading system and bringing EU greenhouse gas emissions on a 2C track. Policy brief

    Energy Technology Data Exchange (ETDEWEB)

    Hoehne, N.; Gilbert, A.; Hagemann, M.; Fekete, H.; Lam, Long; De Vos, R. [Ecofys, Utrecht (Netherlands)

    2013-06-15

    This paper explains how setting 2030 targets will reinvigorate the ETS and will put EU emissions on track to limit global temperature increase below two degrees Celsius (2C). This paper describes four key findings for EU policymakers engaged in preparing EU energy and climate measures for 2030 and for the longer term. The European Commission estimates that by 2020, the companies participating in the ETS will have accumulated a surplus of 1.5 to 2.3 billion allowances, which may be banked and used beyond 2020. This is about the same size as the annual emissions budget of ETS companies (just below 2 billion tonnes). Applying equity principles to the global distribution of efforts in reaching the 2C goal, an indicative 'fair' EU contribution would be a reduction of EU greenhouse gas emissions by around 49% (median of a full range from 39 to 79%) by 2030 compared to 1990 levels. The 2030 targets can be set in a way to also accommodate the surplus expected until 2020. If the entire surplus of allowances from the ETS were to be used after 2020, the 2030 target has to become around 7 percentage points more stringent to compensate for that. Alternatively, the trajectory of the target from 2021 to 2030 could be set to compensate for the surplus. In addition, a more ambitious trajectory towards 2030 would cast its shadow on the mitigation in the period 2013-2020. It would strengthen the ETS, in conjunction with any other ETS recalibration options such as shifting the auctioning ('backloading') or cancelling allowances before 2020.

  14. New transparent flexible nanopaper as ultraviolet filter based on red emissive Eu(III) nanofibrillated cellulose

    Science.gov (United States)

    Zhang, Zhao; Chang, Hui; Xue, Bailiang; Han, Qing; Lü, Xingqiang; Zhang, Sufeng; Li, Xinping; Zhu, Xunjin; Wong, Wai-kwok; Li, Kecheng

    2017-11-01

    A new kind of highly red emissive and transparent nanopapers as ultraviolet filter are produced from lanthanide complex Eu(TTA)3(H2O)2 grafted nanofibrillated cellulose (NFC) by a filtration process using a Buchner funnel. The nanopapers Eu-NFC 1-4 with different thickness (0.023 mm, 1; 0.04 mm, 2; 0.081 mm, 3 and 0.1 mm, 4) possess a fibres with dimensions of approximately 50 nm in diameter and several micrometres in length. Those nanopapers exhibit excellent ultraviolet A (UVA; 320-400 nm) filter property and high optical transmittance (>73% at wavelength of 600 nm). The presence of Eu(TTA)3(H2O)2 in Eu-NFC nanopapers can block 97% UVA (at 348 nm) light and convert it into pure red emission (CIE: x = 0.663, y = 0.333) through the efficient triplet-triplet energy transfer process. The efficient red emission can significantly improve the photo-stability of β-diketones type UVA filter. It can sustain for 10 h without decomposition under UV irradiation at 365 nm, which makes it possible to be applied in UVA filters. Moreover, its low coefficient of thermal expansion (CTE: 6.39 ppm K-1 of nanocellulose), is superior to petroleum-based materials for red organic light-emitting devices.

  15. Energy transfer and color tunable emission in Tb3+,Eu3+ co-doped Sr3LaNa(PO4)3F phosphors.

    Science.gov (United States)

    Li, Shuo; Guo, Ning; Liang, Qimeng; Ding, Yu; Zhou, Huitao; Ouyang, Ruizhuo; Lü, Wei

    2018-02-05

    A group of color tunable Sr 3 LaNa(PO 4 ) 3 F:Tb 3+ ,Eu 3+ phosphors were prepared by conventional high temperature solid state method. The phase structures, luminescence properties, fluorescence lifetimes and energy transfer were investigated in detail. Under 369nm excitation, owing to efficient energy transfer of Tb 3+ →Eu 3+ , the emission spectra both have green emission of Tb 3+ and red emission of Eu 3+ . An efficient energy transfer occur in Tb 3+ , Eu 3+ co-doped Sr 3 LaNa(PO 4 ) 3 F phosphors. The most possible mechanism of energy transfer is dipole-dipole interaction by Dexter's theoretical model. The energy transfer of Tb 3+ and Eu 3+ was confirmed by the variations of emission and excitation spectra and Tb 3+ /Eu 3+ decay lifetimes in Sr 3 LaNa(PO 4 ) 3 F:Tb 3+ ,Eu 3+ . The color tone can tuned from yellowish-green through yellow and eventually to reddish-orange with fixed Tb 3+ content by changing Eu 3+ concentrations. The results show that the prepared Tb 3+ , Eu 3+ co-doped color tunable Sr 3 LaNa(PO 4 ) 3 F phosphor can be used for white LED. Copyright © 2017 Elsevier B.V. All rights reserved.

  16. Energy transfer and color tunable emission in Tb3 +,Eu3 + co-doped Sr3LaNa(PO4)3F phosphors

    Science.gov (United States)

    Li, Shuo; Guo, Ning; Liang, Qimeng; Ding, Yu; Zhou, Huitao; Ouyang, Ruizhuo; Lü, Wei

    2018-02-01

    A group of color tunable Sr3LaNa(PO4)3F:Tb3 +,Eu3 + phosphors were prepared by conventional high temperature solid state method. The phase structures, luminescence properties, fluorescence lifetimes and energy transfer were investigated in detail. Under 369 nm excitation, owing to efficient energy transfer of Tb3 + → Eu3 +, the emission spectra both have green emission of Tb3 + and red emission of Eu3 +. An efficient energy transfer occur in Tb3 +, Eu3 + co-doped Sr3LaNa(PO4)3F phosphors. The most possible mechanism of energy transfer is dipole-dipole interaction by Dexter's theoretical model. The energy transfer of Tb3 + and Eu3 + was confirmed by the variations of emission and excitation spectra and Tb3 +/Eu3 + decay lifetimes in Sr3LaNa(PO4)3F:Tb3 +,Eu3 +. The color tone can tuned from yellowish-green through yellow and eventually to reddish-orange with fixed Tb3 + content by changing Eu3 + concentrations. The results show that the prepared Tb3 +, Eu3 + co-doped color tunable Sr3LaNa(PO4)3F phosphor can be used for white LED.

  17. Efficient 1.54-μm emission through Eu2+ sensitization of Er3+ in thin films of Eu2+/Er3+ codoped barium strontium silicate under broad ultraviolet light excitation

    International Nuclear Information System (INIS)

    Li, Leliang; Zheng, Jun; Zuo, Yuhua; Cheng, Buwen; Wang, Qiming

    2015-01-01

    Thin films of Eu 2+ /Er 3+ codoped barium strontium silicate were deposited on a thermal oxide Si substrate by magnetron sputtering. Optical properties suggest that after a rapid annealing process, these films can lead to efficient Er 3+ emission at 1.54 μm with a lifetime of about 7.9 ms. Intense 1.54-μm light emission was achieved under broad ultraviolet light excitation through efficient energy transfer from Eu 2+ to Er 3+ . These results indicate that the Eu 2+ /Er 3+ thin films have potential applications as low cost and compact erbium doped waveguide amplifiers pumped by LEDs. - Highlights: • The Er 0.07 Eu 0.14 Sr 1.14 Ba 0.79 SiO 4 films are fabricated by magnetron sputtering. • Efficient energy transfer from Eu 2+ to Er 3+ ions by the dipole–dipole interaction. • Intense 1.54 μm emission is achieved under broad excitation spectrum. • The films have potential applications as low cost and compact EDWAs

  18. EU climate policy impact in 2020. With a focus on the effectiveness of emissions trading policy in an economic recession scenario

    International Nuclear Information System (INIS)

    Graus, W.; Sreenivasamurthy, U.; Wesselink, B.

    2009-06-01

    PBL's Environmental Balance 2009 provides information on the current status and trends of environmental and climate policies. Ecofys contributes to the climate policy section of the report by developing the following three indicators: (1) ex-post and ex-ante policy impacts until 2020 at EU level (wedge diagram); (2) business-as-usual emissions of EU ETS sectors until 2020, revised for the current economic recession; (3) a latest literature review of EUA (EU emission allowances) price band expected until 2020. Based on the latter two analyses, a brief note on the impact of the current economic recession on the effectiveness of the EU emission trading scheme until 2020 is presented.An economic recession of two years or longer will considerably decrease the effectiveness of the Emissions Trading Scheme (ETS) in stimulating low-carbon technologies. In order to meet EU climate targets in the longer term, new governmental policies will be needed to compensate for this.

  19. The effects of Eu-concentrations on the luminescent properties of SrF2:Eu nanophosphor

    International Nuclear Information System (INIS)

    Yagoub, M.Y.A.; Swart, H.C.; Noto, L.L.; O’Connel, J.H.; Lee, M.E.; Coetsee, E.

    2014-01-01

    SrF 2 :Eu nanophosphors were successfully synthesized by the hydrothermal method. The structure of the nanophosphors was investigated with x-ray diffraction. The average crystallite size calculated using the Scherrer equation was in the range of 7.0 nm. The photoluminescence of Eu doped as-prepared SrF 2 nanophosphors were studied using different excitation sources. The samples showed emission from both the Eu oxidation states, Eu 2+ and Eu 3+ . At low Eu concentrations the emission from Eu 2+ centered at 416 nm was more dominant. While the narrow band of Eu 3+ emission intensity increased with an increase in the Eu concentration. High resolution x-ray photoelectron spectroscopy results indicated that the Eu was indeed in both Eu 2+ and Eu 3+ valance states. The presence of Eu 2+ and Eu 3+ in the system largely enhanced the response of the Eu 3+ under ultraviolet excitation. The time of flight-secondary ion mass spectrometry results suggested that the energy transfer between two ions was likely to occur. The relative photoluminescence intensity of the Eu 2+ rapidly decreased with an increasing laser beam irradiating time. This result would make the current Eu 2+ doped SrF 2 samples unsuitable candidates for several applications, such as white light-emitting diodes and wavelength conversion films for silicon photovoltaic cells. - Highlights: • SrF 2 : Eu nanophosphors were successfully synthesised (hydrothermal technique). • PL and XPS results showed enhanced absorption response of Eu 3+ UV excitation. • Eu concentrations more than 5 mol% improved fluorescence emission. • TOF-SIMS results suggested that the energy transfer from Eu 2+ to Eu 3+ is dominant

  20. Carbon pricing in the EU: Evaluation of different EU ETS reform options

    International Nuclear Information System (INIS)

    Brink, Corjan; Vollebergh, Herman R.J.; Werf, Edwin van der

    2016-01-01

    This paper studies various options to support allowance prices in the EU Emissions Trading System (ETS), such as adjusting the cap, an auction reserve price, and fixed and variable carbon taxes in addition to the EU ETS. We use a dynamic computable general equilibrium model that explicitly allows for allowance banking and for a detailed cost-effectiveness analysis at the EU Member State level. We find that tightening the cap provides an ad hoc solution to the fundamental issue of the robustness of the effective carbon price, while introducing a price component to the ETS brings structural carbon price support in times of negative demand shocks for emission allowances. These price-based policies still benefit from the intertemporal flexibility through the banking provision in the EU ETS by re-allocating emissions over time with stronger emission reductions in early years and emission increases in later years. A higher emission price has a larger negative impact on the new Member States' economies than on other Member States. Furthermore, introducing a carbon tax in addition to the EU ETS decreases the price of allowances, resulting in welfare gains for net buyers of allowances while net sellers are worse off. - Highlights: • We analyse reform options for European Union Emission Trading System (EU ETS) with a CGE model. • Variable carbon tax and auction reserve price support carbon price at least cost. • Price-based reforms decrease early emissions but increase later emissions through banking. • New Member States' economies are affected more than others by higher CO_2 prices. • Lower allowance prices due to a carbon tax are unfavourable to net sellers of allowances.

  1. Host composition dependent tunable multicolor emission in the single-phase Ba2(Ln(1-z)Tb(z))(BO3)2Cl:Eu phosphors.

    Science.gov (United States)

    Xia, Zhiguo; Zhuang, Jiaqing; Meijerink, Andries; Jing, Xiping

    2013-05-14

    A new strategy based on the host composition design has been adopted to obtain efficient color-tunable emission from Ba2Ln(0.97-z)Tb(z)(BO3)2Cl:0.03Eu (Ln = Y, Gd and Lu, z = 0-0.97) phosphors. This study reveals that the single-phase Ba2Ln(1-z)Tb(z)(BO3)2Cl compounds can be applied to use allowed Eu(2+) absorption transitions to sensitize Eu(3+) emission via the energy transfer Eu(2+) → (Tb(3+))n → Eu(3+). The powder X-ray diffraction (XRD) and Rietveld refinement analysis shows single-phase Ba2Ln(1-z)Tb(z)(BO3)2Cl. As-prepared Ba2Ln(0.97-z)Tb(z)(BO3)2Cl:0.03Eu phosphors show intense green, yellow, orange and red emission under 377 nm near ultraviolet (n-UV) excitation due to a variation in the relative intensities of the Eu(2+), Tb(3+) and Eu(3+) emission depending on the Tb content (z) in the host composition, allowing color tuning. The variation in emission color is explained by energy transfer and has been investigated by photoluminescence and lifetime measurements and is further characterized by the Commission Internationale de l'éclairage (CIE) chromaticity indexes. The quantum efficiencies of the phosphors are high, up to 74%, and show good thermal stabilities up to 150 °C. This investigation demonstrates the possibility to sensitize Eu(3+) line emission by Eu(2+)via energy migration over Tb(3+) resulting in efficient color tunable phosphors which are promising for use in solid-state white light-emitting diodes (w-LEDs).

  2. Substantial enhancement of red emission intensity by embedding Eu-doped GaN into a microcavity

    NARCIS (Netherlands)

    Inaba, T.; Lee, D.-G.; Wakamatsu, R.; Kojima, T.; Mitchell, B.; Capretti, A.; Gregorkiewicz, T.; Koizumi, A.; Fujiwara, Y.

    2016-01-01

    We investigate resonantly excited photoluminescence from a Eu,O-codoped GaN layer embedded into a microcavity, consisting of an AlGaN/GaN distributed Bragg reflector and a Ag reflecting mirror. The microcavity is responsible for a 18.6-fold increase of the Eu emission intensity at ∼10K, and a

  3. ENERGY STAR Certified Ceiling Fans

    Science.gov (United States)

    Certified models meet all ENERGY STAR requirements as listed in the Version 3.0 ENERGY STAR Program Requirements for Ceiling Fans that are effective as of April 1, 2012. A detailed listing of key efficiency criteria are available at http://www.energystar.gov/index.cfm?c=ceiling_fans.pr_crit_ceiling_fans

  4. The development of new phosphors of Tb3+/Eu3+ co-doped Gd3Al5O12 with tunable emission

    Science.gov (United States)

    Teng, Xin; Wang, Wenzhi; Cao, Zhentao; Li, Jinkai; Duan, Guangbin; Liu, Zongming

    2017-07-01

    The gadolinium aluminum garnets Gd3Al5O12 (GdAG) activated with Tb3+/Eu3+ were successfully prepared via co-precipitation method at 1500 °C in this work. The crystal structure stabilization, elements analysis, microphotograph, PL/PLE spectra, decay behavior and quantum efficiency were discussed in detail. The metastable GdAG compounds been effectively stabilized by doping with smaller 10 at.% Tb3+, which then allows the development of new phosphors of (Gd0.9-xTb0.1Eux)3Al5O12 (GdAG:Tb3+/Eu3+, x = 0-0.03) for opto-functionality explorations. The PLE/PL spectra displays that the strongest PLE peak was located at ∼276 nm, which overlaps the 8S7/2 → 6IJ transition of Gd3+. Under 276 nm excitation, the phosphors exhibited both Tb3+ and Eu3+ emissions at 548 nm (green, 5D4 → 7F5 transition of Tb3+) and 592 nm (orange-red, 5D0 → 7F1 transition of Eu3+), respectively. The emission intensities of Tb3+ and Eu3+ remarkably varied with the Eu3+ incorporation. As a consequence, the emission color can be readily tuned from approximately green to orange-red. Fluorescence decay analysis found that the lifetime for the Tb3+ emission rapidly decreased conforming to the Tb3+ → Eu3+ energy transfer, and the energy transfer efficiency was calculated. Owing to the Gd3+ → Eu3+ and Gd3+ → Tb3+ energy transfer, the emission intensities of Tb3+ and Eu3+ in (Gd0.9-xTb0.1Eux)AG phosphor were higher than (Y0.87Tb0.1Eu0.03)AG and (Lu0.87Tb0.1Eu0.03)AG system. The (Gd0.9-xTb0.1Eux)AG garnet phosphors developed in this work may serve as a new type of phosphor which hopefully meets the requirements of various lighting and optical display applications.

  5. Leco. Thermo-active Ceilings & Free Cooling. Using free cooling in combination with thermo-active ceilings for integrated heating and cooling

    OpenAIRE

    Murphy, Mark Allen

    2010-01-01

    The largest potential for decreasing green house gas emissions, and therewith mitigating the effects of global climate change, comes from improving energy efficiency. Through the integration of heating and cooling systems into building elements, such as the thermo-active ceiling, improvements in energy efficiency can be achieved. Utilizing thermal mass to buffer temperature variations and to level out peak loads reduces the instantaneous power demands and enables traditional cooling e...

  6. Leco. Thermo-active Ceilings & Free Cooling. Using free cooling in combination with thermo-active ceilings for integrated heating and cooling

    OpenAIRE

    Murphy, Mark Allen

    2010-01-01

    - The largest potential for decreasing green house gas emissions, and therewith mitigating the effects of global climate change, comes from improving energy efficiency. Through the integration of heating and cooling systems into building elements, such as the thermo-active ceiling, improvements in energy efficiency can be achieved. Utilizing thermal mass to buffer temperature variations and to level out peak loads reduces the instantaneous power demands and enables traditional cool...

  7. Impacts of the EU emissions trading scheme on the industrial competitiveness in Germany

    Energy Technology Data Exchange (ETDEWEB)

    Graichen, Verena; Schumacher, Katja; Matthes, Felix C.; Mohr, Lennart [Oeko Institut e.V., Berlin (Germany); Duscha, Vicky; Schleich, Joachim [Fraunhofer-Institut fuer Systemtechnik und Innovationsforschung (ISI), Karlsruhe (Germany); Diekmann, Jochen [DIW, Berlin (Germany)

    2008-09-15

    The authors of the contribution under consideration present a discussion of methods, and provide empirical results for the analysis of effects of the EU Emissions Trading Scheme on product costs and subsequent impacts on international competitiveness. The discussion shows that the combination of intensity of trade indicators and value at stake indicators reveals meaningful results that allow assessing the potential for distortion in competitiveness by the EU Emissions Trading Schemes. The analysis of trade intensities and value at stake showed that a small number of sectors may in fact be exposed to distortions in competitiveness due to both high trade intensity and high value at stake. For Germany, these include 'basic iron and steel', 'fertilizers and nitrogen compounds', 'paper and paperboard', 'aluminium and aluminium products' and 'other basic inorganic chemicals'. A number of other sectors reveal a high intensity of trade but low value at stake which implies that the increase in product costs due to the EU Emissions Trading Scheme is relatively small and negative effects on competitiveness may not be likely. For the sectors that reveal high values at stake and high trade intensities, market positions are likely to change under the EU Emissions Trading system due to increased production costs and high exposure to international competition. When deciding on which sectors are highly exposed to possible distortions in competitiveness and which measures should be implemented to address competitiveness and leakage it should be kept in mind that CO{sub 2} costs are only one of multiple factors affecting companies' production and investment decisions. Other factors that may deserve detailed investigation include product differentiation and market segmentation within a sector (including specialty products), close cooperation with domestic/European partners and intrafirm trade, differences across countries in the

  8. Economic impacts of EU climate policy until 2020; EU:n ilmastopolitiikan talousvaikutukset vuoteen 2020

    Energy Technology Data Exchange (ETDEWEB)

    Rantala, O. E-mail: olavi.rantala@etla.fi

    2012-07-01

    The study evaluates the impacts of EU climate policy on the emission allowance price, electricity prices, the competitiveness of industry and macroeconomic developments in the third EU emission trading period 2013-2020. The economic impacts of climate policy on Finland are compared to the impacts on the entire EU area. It turns out that due to its cold climate and heating energy demand, higher export intensity of the economy and higher energy intensity of the industry Finland pays a higher price for EU climate policy in terms of output and employment losses than the EU on average. The study examines the macroeconomic effects of climate policy also in the more distant future, assuming that climate policy is tightened further in the 2020s. Climate policy implemented by emission trading means that the long-term economic growth in the EU area depends essentially on emission-free electricity production, and no longer on other growth factors, such as the labour supply and productivity growth. (orig.)

  9. Broadband sensitized white light emission of g-C_3N_4/Y_2MoO_6:Eu"3"+ composite phosphor under near ultraviolet excitation

    International Nuclear Information System (INIS)

    Han, Bing; Xue, Yongfei; Li, Pengju; Zhang, Jingtao; Zhang, Jie; Shi, Hengzhen

    2015-01-01

    The g-C_3N_4/Y_2MoO_6:Eu"3"+ composite phosphors were synthesized and characterized by X-ray diffraction, Fourier transform-infrared spectroscopy, ultraviolet visible diffuse reflection spectra, photoluminescence spectra and luminescence decay curves. Under the excitation of 360 nm near ultraviolet light, these composite phosphors show tunable emission from blue to red region, in which white light emission can be obtained in term of appropriate quality proportion of Y_2MoO_6:Eu"3"+ relative to g-C_3N_4/Y_2MoO_6:Eu"3"+. In addition, the emission color can be also dependent on the excitation wavelength in g-C_3N_4/Y_2MoO_6:Eu"3"+ composite phosphor. - Graphical abstract: Under the excitation of 360 nm near ultraviolet light, the g-C_3N_4/Y_2MoO_6:Eu"3"+ composite phosphors show tunable emission from blue to red region, in which white light emission can be obtained. - Highlights: • The g-C3N4/Y2MoO6:Eu"3"+ composite phosphors were synthesized and characterized. • White light emission was realized in the g-C3N4/Y2MoO6:Eu"3"+ composites under UV excitation. • A novel idea to realize the broadband sensitized white light emission in phosphors was provided.

  10. The central importance of the EU emission trading scheme for achievement of the German climate protection target of 40% until 2020

    International Nuclear Information System (INIS)

    Hermann, Hauke; Cludius, Johanna

    2014-02-01

    Both Germany and the European Union have set themselves targets for the reduction of greenhouse gas (GHG) emissions. The EU was the forerunner in 2008 when it adopted the Climate and Energy package and set a target of reducing GHG emissions by 20 % by 2020 compared to 1990. Two years later, Germany adopted a range of national GHG targets in the context of the German government's Energy Concept. This includes a 40% emissions reduction target to be met by 2020. One of the main instruments for achieving GHG emissions reduction targets is the EU Emissions Trading Scheme (EU ETS), which covers all large industrial and combustion installations in Europe. According to the agreement made in 2008 (Climate and Energy Package), the effort to achieve the EU's 20 % reduction target by 2020 was split between the ETS sector (2/3 of the reduction effort, representing a 21 % reduction in GHG emissions for installations covered under the ETS compared to 2005) and the non-ETS sector (1/3 of the reduction effort, representing a 10 % reduction compared to 2005). Logically, GHG emissions reductions occurring in German ETS installations count both towards the EU and the national target. This research project has been commissioned to analyse whether the ETS in its cur-rent design can contribute its fair share in efforts to meet the national emissions reduc-tion target. This question is particularly relevant in light of the following considerations: - The new German Coalition Agreement, signed in December 2013, reiterated the national target of a 40 % reduction of GHG emissions by 2020 compared to 1990 levels. - At the same time, the new Coalition Agreement stated that changes to the ETS are only to be considered if the EU GHG emissions reduction target will not be met. - There is a surplus of CO2 allowances on the ETS market, which undermines the credibility of the instrument as well as the integrity of the emissions reduction tar-gets (both European and national). At the same time, the

  11. The EU climate policy: Is the will to reduce the emission of greenhouse gases greater than the capability to do it?

    International Nuclear Information System (INIS)

    Wetterstad, Joergen

    2002-01-01

    The climate policy of the EU is rapidly developing. The EU is emerging as an ideal in the international cooperation that aims to initiate trade of emission quotas. The EU was playing a major role on the Johannesburg conference of 2002 and has always supported the Kyoto Protocol, which may come into force in 2003. However, the development of emission situation in most of the member countries, the slow follow-up of the goals and the coming expansion into Eastern Europe raises the question if the EU is a climate political instigator on unsafe ground

  12. Methodology for the free allocation of emission allowances in the EU ETS post 2012. Sector report for the chemical industry

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-11-15

    In 2013, the third trading period of the EU emission trading scheme (EU ETS) will start. With a few exceptions, no free allocation of emission allowances is foreseen in this third trading period for the emissions related to the production of electricity. These emission allowances will be auctioned. For other emissions, transitional free allocation of emission allowances is envisioned. This free allocation will be based on Community wide allocation rules that will, to the extent feasible, be based on ex-ante benchmarks. In 2013, the free allocation is 80% of the quantity determined via these rules, going down to 30% in 2020. An exception is made for activities that are deemed to be exposed to a significant risk of carbon leakage. These activities will receive an allocation of 100% of the quantity determined via the rules. The benchmarks should in principle be calculated for products, i.e. a specific performance per unit productive output, to ensure that they maximize greenhouse gas reductions throughout each production process of the sectors concerned. In this study for the European Commission, a blueprint for a methodology based on benchmarking is developed to determine the allocation rules in the EU ETS from 2013 onwards. In case where benchmarking is not regarded feasible, alternative approaches are suggested. The methodology allows determining the allocation for each EU ETS installation eligible for free allocation of emission allowances. The focus of this study is on preparing a first blueprint of an allocation methodology for free allocation of emission allowances under the EU Emission Trading Scheme for the period 2013-2020 for installations in the refinery industry. The report should be read in conjunction with the report on the project approach and general issues.

  13. Methodology for the free allocation of emission allowances in the EU ETS post 2012. Sector report for the refinery industry

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-11-15

    In 2013, the third trading period of the EU emission trading scheme (EU ETS) will start. With a few exceptions, no free allocation of emission allowances is foreseen in this third trading period for the emissions related to the production of electricity. These emission allowances will be auctioned. For other emissions, transitional free allocation of emission allowances is envisioned. This free allocation will be based on Community wide allocation rules that will, to the extent feasible, be based on ex-ante benchmarks. In 2013, the free allocation is 80% of the quantity determined via these rules, going down to 30% in 2020. An exception is made for activities that are deemed to be exposed to a significant risk of carbon leakage. These activities will receive an allocation of 100% of the quantity determined via the rules. The benchmarks should in principle be calculated for products, i.e. a specific performance per unit productive output, to ensure that they maximize greenhouse gas reductions throughout each production process of the sectors concerned. In this study for the European Commission, a blueprint for a methodology based on benchmarking is developed to determine the allocation rules in the EU ETS from 2013 onwards. In case where benchmarking is not regarded feasible, alternative approaches are suggested. The methodology allows determining the allocation for each EU ETS installation eligible for free allocation of emission allowances. The focus of this study is on preparing a first blueprint of an allocation methodology for free allocation of emission allowances under the EU Emission Trading Scheme for the period 2013-2020 for installations in the refinery industry. The report should be read in conjunction with the report on the project approach and general issues.

  14. EU Emissions Trading Scheme and Investments in the power sector

    Energy Technology Data Exchange (ETDEWEB)

    Sapienza, M.D.; Stefanoni, S.

    2007-07-01

    How environmental regulation affects electricity players' investment decisions? Should policy makers look beyond for alternative mechanisms - such as energy efficiency, capture and storage of carbon dioxide, and incentives for renewables - to fulfill the environmental objectives set by Kyoto Protocol? This paper suggests - through a Real Option approach - how the efficacy of the EU Emission Trading Scheme on technological innovation, emissions reduction and energy price dynamics, is strongly affected by the 'hysteresis' emerging from the capital budgeting process of main utilities. As a matter of fact, long-term substitutions between coal-fired units and Combined Cycle Gas Turbine plants production only take place under quite restrictive conditions. (auth)

  15. The effects of Eu-concentrations on the luminescent properties of SrF{sub 2}:Eu nanophosphor

    Energy Technology Data Exchange (ETDEWEB)

    Yagoub, M.Y.A.; Swart, H.C.; Noto, L.L. [Department of Physics, University of the Free State, PO Box 339, Bloemfontein ZA9300 (South Africa); O’Connel, J.H.; Lee, M.E. [Department of Physics and Centre for HRTEM, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth ZA6031 (South Africa); Coetsee, E., E-mail: CoetseeE@ufs.ac.za [Department of Physics, University of the Free State, PO Box 339, Bloemfontein ZA9300 (South Africa)

    2014-12-15

    SrF{sub 2}:Eu nanophosphors were successfully synthesized by the hydrothermal method. The structure of the nanophosphors was investigated with x-ray diffraction. The average crystallite size calculated using the Scherrer equation was in the range of 7.0 nm. The photoluminescence of Eu doped as-prepared SrF{sub 2} nanophosphors were studied using different excitation sources. The samples showed emission from both the Eu oxidation states, Eu{sup 2+} and Eu{sup 3+}. At low Eu concentrations the emission from Eu{sup 2+} centered at 416 nm was more dominant. While the narrow band of Eu{sup 3+} emission intensity increased with an increase in the Eu concentration. High resolution x-ray photoelectron spectroscopy results indicated that the Eu was indeed in both Eu{sup 2+} and Eu{sup 3+} valance states. The presence of Eu{sup 2+} and Eu{sup 3+} in the system largely enhanced the response of the Eu{sup 3+} under ultraviolet excitation. The time of flight-secondary ion mass spectrometry results suggested that the energy transfer between two ions was likely to occur. The relative photoluminescence intensity of the Eu{sup 2+} rapidly decreased with an increasing laser beam irradiating time. This result would make the current Eu{sup 2+} doped SrF{sub 2} samples unsuitable candidates for several applications, such as white light-emitting diodes and wavelength conversion films for silicon photovoltaic cells. - Highlights: • SrF{sub 2}: Eu nanophosphors were successfully synthesised (hydrothermal technique). • PL and XPS results showed enhanced absorption response of Eu{sup 3+} UV excitation. • Eu concentrations more than 5 mol% improved fluorescence emission. • TOF-SIMS results suggested that the energy transfer from Eu{sup 2+} to Eu{sup 3+} is dominant.

  16. Modeling of Ceiling Fire Spread and Thermal Radiation.

    Science.gov (United States)

    1981-10-01

    under a PMMA ceiling and flame lengths under an inert ceiling are found to be in reasonable agreement with full-scale behavior. Although fire spread...5 3 Flame Lengths under Full-Scale Ceilings 12 4 Correlation of Flame Length under Inert Ceilings 16 5 Correlation of Flame Length under No 234 Model...Ceilings 17 6 Correlation of Flame Length under No B8811 Model Ceilings 18 7 Correlation of Flame Length under No. 223 Model Ceilings 19 8

  17. Stochastic carbon sinks for combating carbon dioxide emissions in the EU

    International Nuclear Information System (INIS)

    Gren, Ing-Marie; Carlsson, Mattias; Elofsson, Katarina; Munnich, Miriam

    2012-01-01

    This paper carries out numerical calculations on the potential of carbon sinks in the EU Emissions Trading Scheme (ETS) and national commitments under conditions of stochastic carbon dioxide emissions from fossil fuels and carbon sequestration by forests. Chance constraint programming is used to analyze the role of stochastic carbon sinks for national and EU-wide compliance costs. The analytical results show that the inclusion of the carbon sink option can reduce costs for low enough marginal cost and risk discount, but also that costless carbon sinks as by-products from forestry are not part of a cost-effective solution under a high reliability concern. Cost savings are reduced due to risk discounting under a reliability concern, in particular when assigning Chebyshev's inequality as compared with a normal probability distribution. It is also shown that the supply of forest sinks on the market depends on the differences in marginal abatement cost between the trading and the non-trading sectors, and in risk discounting between achievements of the ETS cap and the national commitment. Relatively low marginal abatement cost in the non-trading sector and high risk discounting of national commitment achievements increase the supply of sinks in the market and, hence, reduces the equilibrium price. The empirical application illustrates the importance of risk discounting for the magnitude of cost savings obtained from introducing forest carbon sinks in the EU ETS and national commitments.

  18. Luminescence properties of different Eu sites in LiMgPO4:Eu2+, Eu3+

    International Nuclear Information System (INIS)

    Baran, A; Mahlik, S; Grinberg, M; Cai, P; Kim, S I; Seo, H J

    2014-01-01

    The effect of temperature on the luminescence properties of LiMgPO 4 doped with Eu 3+ and Eu 2+ are presented. Depending on the excitation wavelength, luminescence spectra consist of two distinct broad emission bands peaking at 380 nm and 490 nm related to 4f 6 5d 1  → 4f 7 ( 8 S 7/2 ) luminescence of Eu 2+ and to europium-trapped exciton, respectively, and/or several sharp lines between the 580 nm and 710 nm region, ascribed to the 5 D 0  →  7 F J (J = 0, 1, 2, 3 and 4) transitions in Eu 3+ . To explain all the features of the Eu 2+ and Eu 3+ luminescence we discussed the existence of two different Eu sites substituting for Li + , with short and long distance compensation. The evident effect of increasing the intensity of the Eu 2+ luminescence with increasing temperature was observed. It was considered that the charge compensation mechanism for Eu 3+ and Li + as well as Eu 2+ replacing Li + in the LiMgPO 4 is a long distance compensation that allows for the existence of some of the europium ions either as Eu 3+ at low temperature or as Eu 2+ at high temperature. We concluded that Eu 2+ in the Li + site with long distance compensation yields only 4f 6 5d 1  → 4f 7 luminescence, whereas Eu 2+ in the Li + site with short distance compensation yields 4f 6 5d 1  → 4f 7 luminescence and europium-trapped exciton emission. (paper)

  19. Exploring the limits for CO2 emission abatement in the EU power and industry sectors—Awaiting a breakthrough

    International Nuclear Information System (INIS)

    Rootzén, Johan; Johnsson, Filip

    2013-01-01

    This study assesses the prospects for presently available abatement technologies to achieve significant reductions in CO 2 emissions from large stationary sources of CO 2 in the EU up to year 2050. The study covers power generation, petroleum refining, iron and steel, and cement production. By simulating capital stock turnover, scenarios that assume future developments in the technology stock, energy intensities, fuel and production mixes, and the resulting CO 2 emissions were generated for each sector. The results confirm that the EU goal for reductions in Greenhouse Gas Emission in the sectors covered by the EU Emission Trading System, i.e., 21% reduction by 2020 as compared to the levels in 2005, is attainable with the abatement measures that are already available. However, despite the optimism regarding the potential for, and implementation of, available abatement strategies within current production processes, our results indicate that the power and industrial sectors will fail to comply with more stringent reduction targets in both the medium term (2030) and long term (2050). Deliberate exclusion from the analysis of mitigation technologies that are still in the early phases of development (e.g., CO 2 capture and storage) provides an indirect measure of the requirements for novel low-carbon technologies and production processes. - Highlights: • Explore the limits for CO 2 emission abatement within current production processes. • Analysis of scenarios for CO 2 emissions from EU power and industrial sectors 2010–2050. • Short-term (2020) emission targets are attainable with available abatement measures. • Fail to comply with more stringent reduction targets in the long term (2050). • Efforts to develop new low-carbon production processes need to be accelerated

  20. Swedish biomass strategies to reduce CO2 emission and oil use in an EU context

    International Nuclear Information System (INIS)

    Joelsson, Jonas; Gustavsson, Leif

    2012-01-01

    Swedish energy strategies for transportation, space heating and pulp industries were evaluated with a focus on bioenergy use. The aims were to 1) study trade-offs between reductions in CO 2 emission and oil use and between Swedish reductions and EU reductions, 2) compare the potential contributions of individual reduction measures, 3) quantify the total CO 2 emission and oil use reduction potentials. Swedish energy efficiency measures reduced EU CO 2 emission by 45–59 Mt CO 2 /a, at current biomass use and constant oil use. Doubling Swedish bioenergy use yielded an additional 40 Mt CO 2 /a reduction. Oil use could be reduced, but 36–81 kt of reductions in CO 2 emission would be lost per PJ of oil use reduction. Swedish fossil fuel use within the studied sectors could be nearly eliminated. The expansion of district heating and cogeneration of heat with a high electricity yield were important measures. Plug-in hybrid electric cars reduced CO 2 emission compared with conventional cars, and the difference was larger with increasing oil scarcity. The introduction of black liquor gasification in pulp mills also gave large CO 2 emission reduction. Motor fuel from biomass was found to be a feasible option when coal is the marginal fuel for fossil motor fuel production. -- Highlights: ► Bioenergy is compared to optimized fossil fuel use under different oil availability constraints. ► Swedish strategies are evaluated with respect to CO 2 emission and oil use reduction within Sweden and the EU. ► Efficiency measures give the largest reductions but increased bioenergy use is also important. ► District heating expansion, high electricity yield CHP, increased vehicle efficiency and PHEVs are important options. ► The studied sectors in Sweden could become nearly fossil-fuel free and yield an energy surplus.

  1. 48 CFR 452.216-74 - Ceiling Price.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 4 2010-10-01 2010-10-01 false Ceiling Price. 452.216-74... SOLICITATION PROVISIONS AND CONTRACT CLAUSES Texts of Provisions and Clauses 452.216-74 Ceiling Price. As prescribed in 416.670, insert the following clause: Ceiling Price (FEB 1988) The ceiling price of this...

  2. Diffuse Ceiling Ventilation

    DEFF Research Database (Denmark)

    Zhang, Chen; Yu, Tao; Heiselberg, Per Kvols

    cooling capacity, energy saving, low investment cost and low noise level; while the limitations include condensation risk and the limit on the room geometry. Furthermore, the crucial design parameters are summarized and their effects on the system performance are discussed. In addition to the stand...... is not well structured with this system. These become the motivations in developing the design guide. This design guide aims to establish a systematic understanding of diffuse ceiling ventilation and provide assistance in designing of such a system. The guide is targeted at design engineers, architects...... and manufacturers and the users of diffuse ceiling technology. The design guide introduces the principle and key characteristics of room air distribution with diffuse ceiling ventilation. It provides an overview of potential benefit and limitations of this technology. The benefits include high thermal comfort, high...

  3. Possibility of RGB emission by Eu2+ ion doped MIIMIIIMVI phosphors for color inorganic electro- luminescent displays

    International Nuclear Information System (INIS)

    Jabbarov, R.B.; Tagiev, B.G.; Tagiev, O.B.; Musaeva, N.N.; Benalloul, P.; Barthou, C.

    2004-01-01

    Full text: Eu 2+ ion give broad-band emission due to f-d transitions. The 5d orbital are not shelled from the host lattice by any occupied orbital. Therefore the wavelength positions of the emission bands depend on host and change from hear UV to red. With increasing crystal field strength, the emission bands shift to longer wavelength. The broad band absorption and luminescence of Eu 2+ is parity-and spin-allowed and lifetime is sub-microseconds. In resent years, many efforts have been devoted to luminescence studies of thio gallates and thio-aluminates doped with rare-earth ions because of their chemical stability in ambient environments. In ternary compounds both the ligand field at the divalent cation site and the nephelauxetic effect are reduced by the presence of trivalent or tetravalent ions. This effect is more pronounced with Al than with Ga. In a same family of compounds, the emission band generally shifts to shorter wavelengths with increasing M II /M IV or M VI /M III ratio. In this paper we revisited the luminescence of the phosphors CaGa 2 S 4 , BaGa 2 S 4 , BaAl 2 S 4 activated by Eu 2+ ion. Influence of temperature and Eu 2+ concentration on the luminescence characteristics of these phosphors are studied. These dates will be useful to evaluate the quality oi the powder or thin films prepared for devices

  4. Lanthanoplatins: emissive Eu(iii) and Tb(iii) complexes staining nucleoli targeted through Pt-DNA crosslinking.

    Science.gov (United States)

    Singh, Khushbu; Singh, Swati; Srivastava, Payal; Sivakumar, Sri; Patra, Ashis K

    2017-06-01

    Two highly luminescent water-soluble heterometallic LnPt 2 complexes, [{cis-PtCl(NH 3 ) 2 } 2 Ln(L)(H 2 O)](NO 3 ) 2 (Ln = Eu (1), Tb (2)), have been designed for their selective nucleoli staining through formation of Pt-DNA crosslinks. The complexes showed significant cellular uptake and distinctive nucleoli localization through intrinsic emission from Eu III or Tb III observed through confocal fluorescence microscopy.

  5. Synthesis and luminescent properties of Eu{sup 3+}/Eu{sup 2+} co-doped calcium aluminosilicate glass–ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Bouchouicha, H. [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France); Panczer, G., E-mail: gerard.panczer@univ-lyon1.fr [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France); Ligny, D. de [Universität Erlangen-Nürnberg, Department Werkstoffwissenschaften, Lehrstuhl für Glas und Keramik, D-91058 Erlangen (Germany); Guyot, Y. [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France); Baesso, M.L. [Departemento de Fisica, Universidade Estadual de Maringa, 87020-900 Maringa, PR (Brazil); Andrade, L.H.C.; Lima, S.M. [Grupo de Espectroscopia Óptica e Fototérmica, Universidade Estadual de Mato Grosso do Sul – UEMS, C.P. 351, Dourados, MS (Brazil); Ternane, R. [Laboratoire d' Application de la Chimie aux Ressources et Substances Naturelles et à l' Environnement (LACReSNE), Université de Carthage, Faculté des Sciences de Bizerte, 7021 Zarzouna, Bizerte (Tunisia)

    2016-01-15

    Eu{sup 3+} and Eu{sup 2+} co-doped calcium aluminosilicate glass–ceramics have been prepared by devitrification of calcium aluminosilicate glass using heat-treatment. Control of crystallization in the glass–ceramics was studied by X-ray diffraction (XRD) and Raman spectroscopy. The results showed that crystalline phases in glass–ceramic belong to the family of melilite Ca{sub 2}Mg{sub 0.25}Al{sub 1.5}Si{sub 1.25}O{sub 7} as the major phase and anorthite CaAl{sub 2}Si{sub 2}O{sub 8} as the minor phase. Luminescent properties were investigated by emission; lifetime and the color points were calculated. Emission spectra showed that Eu{sup 2+} entered into the crystalline phase in a two steps mechanism: first as Eu{sup 3+} which is then reduced to Eu{sup 2+}. This incorporation in the crystal enhanced Eu{sup 2+} emission with increasing time of heat-treatment and therefore crystallization. - Highlights: • Crystallization of doped glass–ceramics by heat-treatment controlled by microRaman. • Crystalline phases consist of melilite and anorthite. • Eu{sup 3+} and Eu{sup 2+} emissions characterized by their lifetime and color indexes. • Crystallization process modified efficiently the emission color point.

  6. Greenhouse gas emissions for the EU in four future scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Lesschen, J.P.; Rienks, W.; Staritsky, I. [Alterra, Wageningen-UR, Wageningen (Netherlands); Eickhout, B.; Prins, A.G. [Netherlands Environmental Assessment Agency PBL, Bilthoven (Netherlands)

    2009-12-15

    The European Common Agricultural Policy (CAP) will be revised in the near future. A proposed agricultural policy reform will affect many dimensions of the sustainable development of agriculture. One of these dimensions are greenhouse gas (GHG) emissions. The objective of this study was to assess the impact of four scenarios of the future, from the Eururalis study, and the effects of CAP options on GHG emissions from agriculture. The results provide an indication of the range of GHG emissions between the four diverging base scenarios and the differences with current emission levels in Member States and on EU level. Analysis of the possible impact of the measures on GHG emissions showed that this would be much larger from mitigation measures than from CAP options. Full implementation of the mitigation measures could lead to a reduction in GHG emissions from agriculture of 127 Mt CO2 equivalents. This is about a quarter of current GHG emissions from agriculture. Promoting mitigation measures, therefore, is more effective for reducing GHG emissions from agriculture, than influencing income and price subsidies within the CAP. On the global scale, CAP options hardly play a role in total GHG emissions from land use. Much more important are developments in global population, economic growth, policies and technological developments, as depicted in the various scenarios.

  7. Reducing Carbon Dioxide Emissions from the EU Power and Industry Sectors. An assessment of key technologies and measures

    Energy Technology Data Exchange (ETDEWEB)

    Rootzen, Johan

    2012-11-01

    In February 2011, the European Council reconfirmed the goal of reducing EU greenhouse gas emissions by at least 80 % by 2050, as compared to the levels in 1990. The power and industrial sectors currently account for almost half of the total GHG emissions in the EU. The overall objective of the work presented in this thesis is to provide a technology-based perspective on the feasibility of significant reductions in CO{sub 2} emissions in the EU power and industrial sectors, with the emphasis on expected turnover in the capital stock of the existing infrastructure. Three sectors of industry are included: petroleum refining; iron and steel production; and cement manufacturing. The analysis is based on a thorough description and characterization of the current industry infrastructure and of the key mitigation technologies and measures in each sector. The analysis comprises investigations of how specific factors, such as the age structure of the capital stock, technology and fuel mix, and spatial distribution of the plant stock, contribute to facilitating or hindering the shift towards less-emission-intensive production processes. The results presented here are the synthesis of the results described in the following three papers: Paper I investigates the potential for CCS in industrial applications in the EU by considering branch- and plant-specific conditions; Paper II assesses strategies for CO{sub 2} abatement in the European petroleum refining industry; and Paper III explores in a scenario analysis the limits for CO{sub 2} emission abatement within current production processes in the power and industrial sectors. Together, the three papers provide a comprehensive assessment of the roles of technologies and measures that are commercially available today, as well as those of emerging technologies that are still in their early phases of development. The results presented in Paper III show that the EU goal for emissions reductions in the sectors covered by the EU ETS, i

  8. Reducing Greenhouse Gas Emissions in India. Financial mechanisms and opportunities for EU-India collaboration

    Energy Technology Data Exchange (ETDEWEB)

    Atteridge, Aaron; Nilsson Axberg, Goeran; Goel, Nitu; Kumar, Atul; Lazarus, Michael; Ostwald, Madelene; Polycarp, Clifford; Tollefsen, Petter; Torvanger, Asbjoern; Upadhyaya, Prabhat; Zetterberg, Lars

    2009-10-15

    This report illuminates potential areas for collaboration between the EU and India on actions that reduce greenhouse gas emissions in India. If human-induced climate change is to have any hope of being limited to 2 degrees, it is essential that ways are found to address rapidly rising greenhouse gas emissions in India, as elsewhere. This is a challenging proposition: even though India's per capita emissions are very low, her 1.15 billion people are collectively a major source of greenhouse gas emissions. This fact, coupled with the immediate task of tackling widespread poverty, means that the international community must play a major role in providing financial and technological resources to support India's domestic efforts. As India's 2008 National Action Plan on Climate Change recognises, tackling the country's greenhouse gas emissions means not least finding ways to transform a rapidly growing energy sector. International financial mechanisms such as the Clean Development Mechanism and the Global Environment Facility have been unable to deliver the scale of transformative change needed to shift India's emissions trajectory. While the Indian government has already initiated some ambitious policy measures - particularly pertaining to solar energy and energy efficiency- the effectiveness of international finance mechanisms and other forms of international partnership will be crucial in determining the success of greenhouse gas mitigation efforts. The EU India Summit is held a month before COP15 negotiations in Copenhagen. While this provides challenges in terms of seeking concrete agreements on questions of finance, it is also an important opportunity to devise complementary efforts outside the UNFCCC process. Genuine, productive collaboration could not only be used to foster the sorts of transformative changes that are needed in India's growing economy but could also create a spirit of cooperation that spills over into UNFCCC

  9. Cost distribution for the EU ETS. Who pays for the costs of the third phase of the European Emissions Trading System?

    International Nuclear Information System (INIS)

    De Bruyn, S.M; De Jong, F.L.; Korteland, M.H.; Nelissen, D.; Markowska, A.Z.

    2010-06-01

    After 2012, the third phase of the EU Emissions Trading Scheme (EU ETS) that lasts until 2020 will come into effect. New in this phase is the European harmonized rights issue in which for each sector the basic emission rights and the issue of those rights is fixed. Also, a significantly larger proportion of those rights will be auctioned. For the Netherlands the third phase of the EU ETS means that the emissions of companies in 2020 should be reduced by 21% compared to 2005. This involves costs for these companies, including the purchase of rights or taking technical and organizational measures to cut CO2 emissions. This study provides insight into the magnitude of these costs, who will bear the cost and the total direct income effects on businesses, consumers and government. [nl

  10. Energy transfer mechanism in CsI:Eu crystal

    International Nuclear Information System (INIS)

    Yakovlev, V.; Trefilova, L.; Karnaukhova, A.; Ovcharenko, N.

    2014-01-01

    This paper studies the scintillation process in CsI:Eu crystal exposed to the pulse electron irradiation (E=0.25 MeV, t 1/2 =15 ns and W=0.003 J/cm 2 ). It has been proved that the energy transfer from the lattice to Eu 2+ ions in CsI:Eu occurs through the re-absorption of STE emission. The proposed model rests on the following experimental facts: (1) the activator emission at 2.68 eV rises gradually after the decay of the excitation pulse even at temperature lower than 90 K when V k centers are immobile; (2) the rise time of 2.68 eV emission and the decay time of STE emission have the same temperature dependences at T=78–300 K; (3) the excitation spectrum of 2.68 eV emission overlaps the emission spectrum of STE. -- Highlights: • The scintillation process in CsI:Eu was studied under pulsed electron irradiation. • A model of the energy transfer from the lattice to Eu 2+ ions in CsI:Eu was proposed. • Eu 2+ ions in CsI:Eu reabsorb the π-emission of self-trapped excitons

  11. Should the EU climate policy framework be reformed?

    Directory of Open Access Journals (Sweden)

    David ELLISON

    2011-12-01

    Full Text Available Though to-date the European Union (EU has played the most significant leadership role in international negotiations to reduce greenhouse gas (GHG emissions, the emission-reducing performance of individual EU Member states has for many been less than stellar. Several EU15 Member states continue to raise rather than lower emissions. Analysing the most successful policy instruments, this paper argues EU policy efforts could benefit from three important innovations. The following strategies – the adoption of an EU-wide FIT (feed-in tariff, an EU-wide carbon tax and more flexibility in the trading of carbon credits – could significantly improve emission reductions, their relative cost-efficiency and spread burden-sharing more evenly across technologies and Member states. This raises important questions, both about the effectiveness of EU and Kyoto-style commitments, as well as the EU Emission Trading Scheme (ETS. The commitment strategy, and in particular the EU ETS mechanism, have had the smallest impact on emission reductions. The proposed set of strategies could make a far greater contribution to future EU efforts and potentially lock in the impressive progress already made. Such a policy shift, if successful, would also greatly enhance the EU’s already significant credibility and bargaining power in international climate negotiations.

  12. Further development of the EU Emissions Trading Scheme in Germany and the European Union under consideration of experiences in other EU Member States; Weiterentwicklung des Emissionshandels - national und auf EU-Ebene

    Energy Technology Data Exchange (ETDEWEB)

    Wartmann, S; Klaus, S; Scharte, M; Harnisch, J [Ecofys GmbH, Nuernberg (Germany); Heilmann, S; Bertenrath, R [FiFo Koeln (Germany)

    2008-02-15

    The study analyses options for further development of the EU Emissions Trading Scheme (EU-ETS) after 2012. The first analysis focuses on the effects of the EU-ETS on companies, power prices, competitiveness and employment. It is followed by an analysis of overlaps or lacking coverage regarding the climate policies EU-ETS, Eco-Tax (Oekosteuer) resp. Energy Tax, the Renewable Energy Sources Act and the Combined Heat and Powert Act. These instruments are analysed with regards to their coherence. As a next step, the national allocation plans of France, The Netherlands, the United Kingdom and Poland are evaluated and recommendations are developed. Best practice recommendations for further developing the EU-ETS after 2012 both at the European and the national level are developed from the comparison of these European national allocation plans. Finally, design features of certificate systems relevant for international linking of such systems are addressed. In the analysis such design features are identified and approaches for problems potentially arising when certificate systems are linked, are developed. (orig.)

  13. Jagged Edges of the Glass Ceiling

    Science.gov (United States)

    Robinson, Victoria L.

    2004-01-01

    Although many aspiring young women might believe the glass ceiling was shattered a decade ago, they still need to understand how that glass ceiling impacted an older generation of women in educational leadership. They also must be aware that some segments of the glass ceiling might still exist. This article provides a historical overview of the…

  14. New Possibilities for Technology Development in the Auspices of Low-Emission EU Strategy

    International Nuclear Information System (INIS)

    Car, S.; Jelavic, V.

    2016-01-01

    United Nations Framework Convention on Climate Change has elevated the level of responsibility of the international community for implementation of measures for climate preservation and CO2 reduction. After the Paris Agreement, the base for carrying out the measures lies in the following: contribution to emissions reduction determined on a national level, establishing new platforms for energy management based on low-emission development, new technological and economy development and technology transfer. European Development Fund is an opportunity for accelerating the technological development of Croatian economy and to coordinate it with EU low-emission strategy, taking into account the advanced specialization economy strategy which was recently approved by the EC and adopted in the Parliament. Technological development, based on available local resources, new technologies, innovations and global market, is a basis of a long-term sustainable development and it is expected that it will be supported not just from the EU funds but also with local fiscal and other measures. Visions for development of some technologies will be shown, as well as examples of new possibilities for Croatian electro industry that is already present on the global market and only confirms the possibility and necessity of such technological development.(author).

  15. Emmission trading in EU law. The EU emission trading directive as a new tool in European air pollution abatement policy; Emissionshandel im Gemeinschaftsrecht. Die EG-Emissionshandelsrichtlinie als neues Instrument europaeischer Klimaschutzpolitik

    Energy Technology Data Exchange (ETDEWEB)

    Kerth, Y.

    2004-07-01

    The publication investigates in how far the EU followed up its voiced political intentions to reduce air pollution by legal actions. The climate protection tools of the EU are investigated both from a historical and a structural view. After this analysis of the status quo, the new EU emission trading system is analyzed in detail because of its innovative character. (orig.)

  16. Controlled fabrication of the strong emission YVO4:Eu3+ nanoparticles and nanowires by microwave assisted chemical synthesis

    International Nuclear Information System (INIS)

    Huong, Tran Thu; Vinh, Le Thi; Phuong, Ha Thi; Khuyen, Hoang Thi; Anh, Tran Kim; Tu, Vu Duc; Minh, Le Quoc

    2016-01-01

    In this report, we are presenting the controlled fabrication results of the strong emission YVO 4 : Eu 3+ nanoparticles and nanowires by microwave which is assisted chemical synthesis. The effects of incorporated synthesis conditions such as microwave irradiated powers, pH values and concentration of chemical composition on properties of nanomaterials are also investigated to obtain the controllable size and homogenous morphology. Morphological and optical properties of YVO 4 : Eu 3+ prepared products which have been characterized by X-ray diffraction (XRD), field emission micrcroscopy (FESEM) and photoluminescence spectroscopy. As based from result of synthesized samples, we found that the changing of pH values, microwave irradiated powers and chemical composition rise to change reform the size and shape of materials from nanoparticles (diameter about 20 nm) to wires shape (with about 500÷800 nm length and 10÷20 nm width). The photoluminescence (PL) spectroscopy measurements of YVO 4 : Eu 3+ nanostructure materials under UV excitation showed that: the strong luminescence in red region with narrow lines corresponding to the intra-4f transitions of 5 D 0 – 7 F j (j=1, 2, 3, and 4) of Eu 3+ ions with the highest luminescence intensity of 5 D 0 → 7 F 2 transition. - Highlights: • The strong emission YVO 4 :Eu 3+ nanostructure materials were successfully synthesized by microwave assisted chemical synthesis. • The size, morphology and luminescence of the YVO 4 :Eu 3+ nanostructure materials can be controlled by the solution pH, microwave irradiated powers and chemical composition. • These YVO 4 :Eu 3+ nanostructure materials above can potentially applied in various fields of application, especially in luminescent labeling and visualization in biomedical application.

  17. Enhanced red emission of LaVO4:Eu3+ phosphors by Li-doping

    International Nuclear Information System (INIS)

    Park, Sung Wook; Yang, Hyun Kyoung; Chung, Jong Won; Moon, Byung Kee; Choi, Byung Chun; Jeong, Jung Hyun; Jang, Ki Wan; Lee, Ho Sueb; Yi, Soung Soo

    2010-01-01

    LaVO 4 phosphors were synthesized by using a solid state reaction, and were characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence (PL). The XRD patterns of the Li-doped LaVO 4 :Eu 3+ powder phosphors revealed a mixture of tetragonal and monoclinic phases. The tetragonal phase of the LaVO 4 :Eu 3+ phosphor showed a higher PL intensity than the monoclinic one, despite the presence of both monoclinic and tetragonal structures. The Li-doped LaVO 4 :Eu 3+ powder phosphors absorbed strongly at 396 nm and exhibited strong red emission at approximately 619.5 nm due to the 5 D 0 → 7 F 2 transition. The incorporation of Li + ions into the LaVO 4 :Eu 3+ powder can lead to a remarkable increase in photoluminescence. The enhanced luminescence is attributed to the incorporation of Li + ions that may act as a sensitizers for effective energy transfer. This phosphor has promising applications in near-UV light-emitting diodes(LEDs).

  18. The central importance of the EU emission trading scheme for achievement of the German climate protection target of 40% until 2020; Die zentrale Bedeutung des EU-Emissionshandels zur Erreichung des deutschen Klimaziels in Hoehe von 40 % bis 2020

    Energy Technology Data Exchange (ETDEWEB)

    Hermann, Hauke; Cludius, Johanna

    2014-02-15

    Both Germany and the European Union have set themselves targets for the reduction of greenhouse gas (GHG) emissions. The EU was the forerunner in 2008 when it adopted the Climate and Energy package and set a target of reducing GHG emissions by 20 % by 2020 compared to 1990. Two years later, Germany adopted a range of national GHG targets in the context of the German government's Energy Concept. This includes a 40% emissions reduction target to be met by 2020. One of the main instruments for achieving GHG emissions reduction targets is the EU Emissions Trading Scheme (EU ETS), which covers all large industrial and combustion installations in Europe. According to the agreement made in 2008 (Climate and Energy Package), the effort to achieve the EU's 20 % reduction target by 2020 was split between the ETS sector (2/3 of the reduction effort, representing a 21 % reduction in GHG emissions for installations covered under the ETS compared to 2005) and the non-ETS sector (1/3 of the reduction effort, representing a 10 % reduction compared to 2005). Logically, GHG emissions reductions occurring in German ETS installations count both towards the EU and the national target. This research project has been commissioned to analyse whether the ETS in its cur-rent design can contribute its fair share in efforts to meet the national emissions reduc-tion target. This question is particularly relevant in light of the following considerations: - The new German Coalition Agreement, signed in December 2013, reiterated the national target of a 40 % reduction of GHG emissions by 2020 compared to 1990 levels. - At the same time, the new Coalition Agreement stated that changes to the ETS are only to be considered if the EU GHG emissions reduction target will not be met. - There is a surplus of CO2 allowances on the ETS market, which undermines the credibility of the instrument as well as the integrity of the emissions reduction tar-gets (both European and national). At the same

  19. Enhanced emission from Eu(III) beta-diketone complex combined with ether-type oxygen atoms of di-ureasil organic-inorganic hybrids

    CERN Document Server

    Molina, C; Messaddeq, Y; Ribeiro, S J L; Silva, M A P; Zea-Bermudez, V D; Carlos, L D

    2003-01-01

    Organic-inorganic hybrids, named di-ureasils and described by polyether-based chains grafted to both ends to a siliceous backbone through urea cross linkages, were used as hosts for incorporation of the well-known coordination complex of trivalent europium (Eu sup 3 sup +) ions described by the formula [Eu(TTA) sub 3 (H sub 2 O) sub 2] (where TTA stands for thenoyltrifluoroacetone). By comparing with Eu sup 3 sup + -doped di-ureasil without complex form the new materials prepared here enhanced the quantum efficiency for photoemission of Eu sup 3 sup + ions. The enhancement can be explained by the coordination ability of the organic counterpart of the host structure which is strong enough to displace water molecules in [Eu(TTA) sub 3 (H sub 2 O) sub 2] from the rare earth neighbourhood after the incorporation process. High intensity of Eu sup 3 sup + emission was observed with a low non-radiative decay rate under ultraviolet excitation. The quantum efficiency calculated from the decay of sup 5 D sub 0 emission...

  20. 6. Analisis Implementasi Cyber Security Di Uni Eropa: Studi Kasus Carbon Credits Hacking Dalam European Union Emission Trading Scheme (EU ETS) Tahun 2010-2013

    OpenAIRE

    Aisya, Naila Sukma; Putranti, Ika Riswanti; Wahyudi, Fendy Eko

    2017-01-01

    Since the last two decades in the 20th century, the European Union (EU) has presented itself as a leader in climate change issues. The leadership manifested in the formation of the European Union Emission Trading Scheme (EU ETS) as an effort to fulfill the commitments of the Kyoto Protocol to reduce emissions in the region. But the existence of the EU ETS has been challenged by the emergence of carbon credits hacking case in some national registration systems in the EU ETS. This study discuss...

  1. 16 CFR 305.13 - Labeling for ceiling fans.

    Science.gov (United States)

    2010-01-01

    ... 16 Commercial Practices 1 2010-01-01 2010-01-01 false Labeling for ceiling fans. 305.13 Section... Disclosures § 305.13 Labeling for ceiling fans. (a) Ceiling fans—(1) Content. Any covered product that is a ceiling fan shall be labeled clearly and conspicuously on the principal display panel with the following...

  2. Diversity, culture and the glass ceiling.

    Science.gov (United States)

    Wilson, Eleanor

    2014-01-01

    A reference to the term, the glass ceiling, has come to embody more than gender equality among women and men. Today the term embraces the quest of all minorities and their journey towards equality in the workplace. The purpose of this article is to bring attention to the subject of diversity, culture, and the glass ceiling. The article will discuss the history of the glass ceiling and how its broadened meaning is relevant in today's workplace. It will also provide statistics showing how diversity and culture are lacking among the top echelon of today's executives, the barriers faced by minorities as they journey towards executive leadership, and how to overcome these barriers to truly shatter the glass ceiling.

  3. Measuring perceived ceiling height in a visual comparison task.

    Science.gov (United States)

    von Castell, Christoph; Hecht, Heiko; Oberfeld, Daniel

    2017-03-01

    When judging interior space, a dark ceiling is judged to be lower than a light ceiling. The method of metric judgments (e.g., on a centimetre scale) that has typically been used in such tasks may reflect a genuine perceptual effect or it may reflect a cognitively mediated impression. We employed a height-matching method in which perceived ceiling height had to be matched with an adjustable pillar, thus obtaining psychometric functions that allowed for an estimation of the point of subjective equality (PSE) and the difference limen (DL). The height-matching method developed in this paper allows for a direct visual match and does not require metric judgment. It has the added advantage of providing superior precision. Experiment 1 used ceiling heights between 2.90 m and 3.00 m. The PSE proved sensitive to slight changes in perceived ceiling height. The DL was about 3% of the physical ceiling height. Experiment 2 found similar results for lower (2.30 m to 2.50 m) and higher (3.30 m to 3.50 m) ceilings. In Experiment 3, we additionally varied ceiling lightness (light grey vs. dark grey). The height matches showed that the light ceiling appeared significantly higher than the darker ceiling. We therefore attribute the influence of ceiling lightness on perceived ceiling height to a direct perceptual rather than a cognitive effect.

  4. Structural and spectroscopic diagnosis of Eu:ZnO and Eu:Yb:ZnO glass and ceramics.

    Science.gov (United States)

    Bahadur, A; Dwivedi, Y; Rai, S B

    2012-06-01

    Eu and Eu:Yb codoped ZnO nanocrystals embedded in B(2)O(3) glass matrix were synthesized and their structural, optical properties were discussed. On excitation with 532 nm laser radiation intense orange/red emissions from Eu(3+) ions were observed. The fluorescence intensity was found to enhance on annealing. Frequency upconversion emissions from Eu(3+) ions were observed in presence of Yb(3+) ions on excitation with NIR (976 nm) laser. The enhancement in emission intensity was explained and the photo-physics involved is linked with the unique structural properties of the crystallites formed. Ion interactions and the different energy transfer parameters were also calculated. Copyright © 2012 Elsevier B.V. All rights reserved.

  5. Phosphor thermometry: On the synthesis and characterisation of Y{sub 3}Al{sub 5}O{sub 12}:Eu (YAG:Eu) and YAlO{sub 3}:Eu (YAP:Eu)

    Energy Technology Data Exchange (ETDEWEB)

    Kissel, T. [Fachgebiet Reaktive Strömungen und Messtechnik (RSM), Center of Smart Interfaces (CSI), Technische Universität Darmstadt, Petersenstraße 32, 64287 Darmstadt (Germany); Brübach, J., E-mail: bruebach@ekt.tu-darmstadt.de [Fachgebiet Reaktive Strömungen und Messtechnik (RSM), Center of Smart Interfaces (CSI), Technische Universität Darmstadt, Petersenstraße 32, 64287 Darmstadt (Germany); Euler, M. [Fachgebiet Reaktive Strömungen und Messtechnik (RSM), Center of Smart Interfaces (CSI), Technische Universität Darmstadt, Petersenstraße 32, 64287 Darmstadt (Germany); Frotscher, M.; Litterscheid, C.; Albert, B. [Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Petersenstraße 18, 64287 Darmstadt (Germany); Dreizler, A. [Fachgebiet Reaktive Strömungen und Messtechnik (RSM), Center of Smart Interfaces (CSI), Technische Universität Darmstadt, Petersenstraße 32, 64287 Darmstadt (Germany)

    2013-07-15

    With regard to phosphor thermometry, the materials Y{sub 3}Al{sub 5}O{sub 12}:Eu (YAG:Eu) and YAlO{sub 3}:Eu (YAP:Eu) were synthesised and characterised in order to substitute the commonly used thermographic phosphor Y{sub 2}O{sub 3}:Eu, whose temperature sensitive luminescence lifetime exhibits a strong and most often undesirable cross-sensitivity to the oxygen concentration of the surrounding gas phase. The synthesis is outlined in detail and the crystallographic structure was characterised by X-ray diffraction. In a second step, the luminescence properties following pulsed UV laser excitation were determined. In this context, the emission spectra and the temperature lifetime characteristics were monitored. For Y{sub 3}Al{sub 5}O{sub 12}:Eu and YAlO{sub 3}:Eu, temperature sensitive ranges of 1000 K–1470 K and 850 K–1300 K were identified. Contrary to Y{sub 2}O{sub 3}:Eu, both materials do show much lower cross-sensitivities to the oxygen concentration of the surrounding gas phase. - Highlights: ► Y{sub 3}Al{sub 5}O{sub 12}:Eu and YAlO{sub 3}:Eu were synthesised and characterised. ► The synthesis is outlined and the crystallographic structure was characterised. ► Emission spectra and the temperature lifetime characteristics were monitored. ► Compared to Y{sub 2}O{sub 3}:Eu lower sensitivities to the oxyg. conc. of the gas phase emerged.

  6. 48 CFR 1352.216-77 - Ceiling price.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 5 2010-10-01 2010-10-01 false Ceiling price. 1352.216-77... SOLICITATION PROVISIONS AND CONTRACT CLAUSES Text of Provisions and Clauses 1352.216-77 Ceiling price. As prescribed in 48 CFR 1316.601-70 and 1316.602-70, insert the following clause: Ceiling Price (APR 2010) The...

  7. EU emission trading. Requirement of adaptation of the Cap as a consequence of external shocks and unexpected developments?; EU-Emissionshandel. Anpassungsbedarf des Caps als Reaktion auf externe Schocks und unerwartete Entwicklungen?

    Energy Technology Data Exchange (ETDEWEB)

    Diekmann, Jochen [DIW, Berlin (Germany)

    2012-11-15

    The effectivity of the European emission trading system (EU-ETS) with respect to the reduction of greenhouse gas emissions based essentially on the quantity of the emission caps. The regional, sectorial and temporal boundaries of this system as well as the regulations covering international flexible mechanisms and banking have to be considered in the evaluation of the effectivity of the EU-ETS. Under this aspect, the authors of the contribution under consideration discuss the advantages and disadvantages of the different variants of adjustment. First of all, the criteria for an identification of a possible justified needs of adaptation are investigated. Furthermore, the authors discuss the question about suitable points in time for an intervention.

  8. An Economic Theory of Glass Ceiling

    OpenAIRE

    Paul A. Grout; In-Uck Park; Silvia Sonderegger

    2009-01-01

    In the 'glass ceiling' debate there appear to be two strongly held and opposing interpretations of the evidence, one suggesting it is really the result of gender differences and the other that there is discrimination by gender. This paper provides an economic theory of the glass ceiling and one of the main insights of our analysis is that in some real sense these two interpretations are not in conflict with each other. The glass ceiling emerges as an equilibrium phenomenon when firms compete ...

  9. Swedish biomass strategies to reduce CO{sub 2} emission and oil use in an EU context

    Energy Technology Data Exchange (ETDEWEB)

    Joelsson, Jonas [Ecotechnology and Environmental Science, Mid Sweden University, SE-831 25 Oestersund (Sweden); Gustavsson, Leif [Linnaeus University, SE-351 95 Vaexjoe (Sweden)

    2012-07-15

    Swedish energy strategies for transportation, space heating and pulp industries were evaluated with a focus on bioenergy use. The aims were to 1) study trade-offs between reductions in CO{sub 2} emission and oil use and between Swedish reductions and EU reductions, 2) compare the potential contributions of individual reduction measures, 3) quantify the total CO{sub 2} emission and oil use reduction potentials. Swedish energy efficiency measures reduced EU CO{sub 2} emission by 45-59 Mt CO{sub 2}/a, at current biomass use and constant oil use. Doubling Swedish bioenergy use yielded an additional 40 Mt CO{sub 2}/a reduction. Oil use could be reduced, but 36-81 kt of reductions in CO{sub 2} emission would be lost per PJ of oil use reduction. Swedish fossil fuel use within the studied sectors could be nearly eliminated. The expansion of district heating and cogeneration of heat with a high electricity yield were important measures. Plug-in hybrid electric cars reduced CO{sub 2} emission compared with conventional cars, and the difference was larger with increasing oil scarcity. The introduction of black liquor gasification in pulp mills also gave large CO{sub 2} emission reduction. Motor fuel from biomass was found to be a feasible option when coal is the marginal fuel for fossil motor fuel production. -- Highlights: Black-Right-Pointing-Pointer Bioenergy is compared to optimized fossil fuel use under different oil availability constraints. Black-Right-Pointing-Pointer Swedish strategies are evaluated with respect to CO{sub 2} emission and oil use reduction within Sweden and the EU. Black-Right-Pointing-Pointer Efficiency measures give the largest reductions but increased bioenergy use is also important. Black-Right-Pointing-Pointer District heating expansion, high electricity yield CHP, increased vehicle efficiency and PHEVs are important options. Black-Right-Pointing-Pointer The studied sectors in Sweden could become nearly fossil-fuel free and yield an energy

  10. Effect of structural evolution of ZnO/HfO2 nanocrystals on Eu2+/Eu3+ emission in glass-ceramic waveguides for photonic applications.

    Science.gov (United States)

    Ghosh, Subhabrata; Bhaktha B N, Shivakiran

    2018-06-01

    Eu-doped 70SiO 2 -23HfO 2 -7ZnO (mol%) glass-ceramic waveguides have been fabricated by sol-gel method as a function of heat-treatment temperatures for on-chip blue-light emitting source applications. Structural evolution of spherical ZnO and spherical as well as rod-like HfO 2 nanocrystalline structures have been observed with heat-treatments at different temperatures. Initially, in the as-prepared samples at 900 ◦ C, both, Eu 2+ as well as Eu 3+ ions are found to be present in the ternary matrix. With controlled heat-treatments of up to 1000 ◦ C for 2 h, local environment of Eu-ions become more crystalline in nature and the reduction of Eu 3+ to Eu 2+ takes place in such ZnO/HfO 2 crystalline environments. In these ternary glass-ceramic waveguides, heat-treated at higher temperatures, the blue-light emission characteristic, which is the signature of 4f 6 5d [Formula: see text] 4f 7 energy level transition of Eu 2+ ions is found to be greatly enhanced. The as-prepared glass-ceramic waveguides exhibit a propagation loss of 0.4 ± 0.2 dB cm -1 at 632.8 nm. Though the propagation losses increase with the growth of nanocrystals, the added functionalities achieved in the optimally heat-treated Eu-doped 70SiO 2 -23HfO 2 -7ZnO (mol%) waveguides, make them a viable functional optical material for the fabrication of on-chip blue-light emitting sources for integrated optic applications.

  11. Effect of structural evolution of ZnO/HfO2 nanocrystals on Eu2+/Eu3+ emission in glass-ceramic waveguides for photonic applications

    Science.gov (United States)

    Ghosh, Subhabrata; N, Shivakiran Bhaktha B.

    2018-06-01

    Eu-doped 70SiO2–23HfO2–7ZnO (mol%) glass-ceramic waveguides have been fabricated by sol-gel method as a function of heat-treatment temperatures for on-chip blue-light emitting source applications. Structural evolution of spherical ZnO and spherical as well as rod-like HfO2 nanocrystalline structures have been observed with heat-treatments at different temperatures. Initially, in the as-prepared samples at 900 ◦C, both, Eu2+ as well as Eu3+ ions are found to be present in the ternary matrix. With controlled heat-treatments of up to 1000 ◦C for 2 h, local environment of Eu-ions become more crystalline in nature and the reduction of Eu3+ to Eu2+ takes place in such ZnO/HfO2 crystalline environments. In these ternary glass-ceramic waveguides, heat-treated at higher temperatures, the blue-light emission characteristic, which is the signature of 4f 65d \\to 4f 7 energy level transition of Eu2+ ions is found to be greatly enhanced. The as-prepared glass-ceramic waveguides exhibit a propagation loss of 0.4 ± 0.2 dB cm‑1 at 632.8 nm. Though the propagation losses increase with the growth of nanocrystals, the added functionalities achieved in the optimally heat-treated Eu-doped 70SiO2–23HfO2–7ZnO (mol%) waveguides, make them a viable functional optical material for the fabrication of on-chip blue-light emitting sources for integrated optic applications.

  12. Challenges of a common climate policy. An analysis of the development of the EU Emissions Trading Scheme

    International Nuclear Information System (INIS)

    Aufenanger, Vanessa

    2012-01-01

    The emissions trading scheme (EU ETS) adopted by the European Union in 2003 was a new instrument for the EU and its Member States. It is one of the most important strategies of achieving the EU's greenhouse gas reduction target under the Kyoto Protocol. This book analyses the policy cycle of the EU ETS Directive, focusing on the crucial implementation phase. The revised EU ETS Directive of 2009 includes significant changes for greater ecological effectiveness, changes that were unlikely to have been adopted in 2003. It is evident that the experiences of the first phase influenced not only the second implementation phase but also the revision. The intensive learning process that took place on all levels was necessary to overcome institutional constraints so that the EU ETS could be successfully established and further developed. The EU ETS policy-making is a good example to demonstrate that output legitimacy challenges input legitimacy. With the centralisation of the EU ETS in 2013 it is likely to become a more effective system; however, the legislators from the Member States may lose influence. This problem will have to be addressed.

  13. Ex-ante evaluation of EU ETS during 2013–2030: EU-internal abatement

    International Nuclear Information System (INIS)

    Hu, Jing; Crijns-Graus, Wina; Lam, Long; Gilbert, Alyssa

    2015-01-01

    This study investigates CO 2 emission reduction within the EU resulting from the Emissions Trading Scheme (ETS) up to 2030. This is performed by constructing a baseline scenario without the ETS and assessing the impacts of the ETS, as currently designed. The results indicate that the ETS will start to impact emissions primarily after 2025 due to the prevalence of a sizable allowance surplus. The impact of approved (i.e. back-loading and 2.2% linear reduction factor (LRF)) and proposed (i.e. market stability reserve (MSR)) policy interventions and the inclusion of aviation, could accelerate the exhaustion of surplus and increase emission reductions during the investigated period. However, these measures would be insufficient to restore the scarcity of allowances and the corresponding carbon price before the start of ETS Phase IV, and the effectiveness of EU-internal abatement cannot be guaranteed until 2023. The effectiveness could be further reduced in the case of the economic shocks or the exclusion of international aviation. To restore the scarcity of allowances, other reform options are necessary. This paper extends the reasoning for the early removal of the back-loaded 900 Mtonne allowances by 2020 and broadening the scope of ETS to other sectors with potential high demand for allowances. - Highlights: • Quantification of CO 2 emission abatement in the EU resulting from the ETS up to 2030. • The impact of policy interventions and the inclusion of aviation is quantified. • The effectiveness of EU ETS in EU-internal abatement is limited until 2023

  14. Stars on the Ceiling

    Science.gov (United States)

    Krupp, E. C.

    2016-01-01

    Astronomy and celestial imagery have been incorporated into architectural ceilings from antiquity to the present to reference the sky on behalf of a variety of agendas. Burial chambers in Egyptian pyramids and tombs, the Osiris chapel on the roof of Ptolemaic Egypt's Temple of Dendera, ancient Chinese tombs, painted rock shelters in California and the American Southwest, the cupola above a hot bath from medieval Jordan, elaborately illustrated ceilings in Italian cathedrals and palaces, the main concourse in New York's Grand Central Terminal, and a variety of other public buildings in America all brought the sky inside to convey relationships between the architecture, people, and the cosmos. In these interior environments, the symbolic function of the astronomical ceiling is driven by the thematic function of the building. At Griffith Observatory in Los Angeles three signature spaces are equipped with astronomically illustrated ceilings. In content and location, these prominent murals operate symbolically to convey meaning through public display and unexpectedly prompt people to think more expansively about the universe. This artwork is familiar in Los Angeles, but its use in a public observatory puts it outside the range of most commentaries on public art. Although experienced by more than seventy-six million persons over the last eighty years, Griffith Observatory's celestial murals are not well known. Their history, content, character, meaning, and purpose are detailed here.

  15. Controlled fabrication of the strong emission YVO{sub 4}:Eu{sup 3+} nanoparticles and nanowires by microwave assisted chemical synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Huong, Tran Thu, E-mail: tthuongims@gmail.com [Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Road, Cau Giay District, Hanoi (Viet Nam); Vinh, Le Thi [Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Road, Cau Giay District, Hanoi (Viet Nam); Department of Chemistry, Hanoi University of Mining and Geology (Viet Nam); Phuong, Ha Thi [Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Road, Cau Giay District, Hanoi (Viet Nam); Department of Chemistry, Hanoi University of Medicine (Viet Nam); Khuyen, Hoang Thi [Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Road, Cau Giay District, Hanoi (Viet Nam); Anh, Tran Kim [Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Road, Cau Giay District, Hanoi (Viet Nam); Duy Tan University, 14/25 Quang Trung, Da Nang (Viet Nam); Tu, Vu Duc [Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Road, Cau Giay District, Hanoi (Viet Nam); Physics, National Chung Cheng University, 168 University Road, Min-Hsiung, Chia-Yi 62102, Taiwan (China); Minh, Le Quoc [Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Road, Cau Giay District, Hanoi (Viet Nam); Duy Tan University, 14/25 Quang Trung, Da Nang (Viet Nam)

    2016-05-15

    In this report, we are presenting the controlled fabrication results of the strong emission YVO{sub 4}: Eu{sup 3+} nanoparticles and nanowires by microwave which is assisted chemical synthesis. The effects of incorporated synthesis conditions such as microwave irradiated powers, pH values and concentration of chemical composition on properties of nanomaterials are also investigated to obtain the controllable size and homogenous morphology. Morphological and optical properties of YVO{sub 4}: Eu{sup 3+} prepared products which have been characterized by X-ray diffraction (XRD), field emission micrcroscopy (FESEM) and photoluminescence spectroscopy. As based from result of synthesized samples, we found that the changing of pH values, microwave irradiated powers and chemical composition rise to change reform the size and shape of materials from nanoparticles (diameter about 20 nm) to wires shape (with about 500÷800 nm length and 10÷20 nm width). The photoluminescence (PL) spectroscopy measurements of YVO{sub 4}: Eu{sup 3+} nanostructure materials under UV excitation showed that: the strong luminescence in red region with narrow lines corresponding to the intra-4f transitions of {sup 5}D{sub 0}–{sup 7}F{sub j} (j=1, 2, 3, and 4) of Eu{sup 3+} ions with the highest luminescence intensity of {sup 5}D{sub 0}→{sup 7}F{sub 2} transition. - Highlights: • The strong emission YVO{sub 4}:Eu{sup 3+} nanostructure materials were successfully synthesized by microwave assisted chemical synthesis. • The size, morphology and luminescence of the YVO{sub 4}:Eu{sup 3+} nanostructure materials can be controlled by the solution pH, microwave irradiated powers and chemical composition. • These YVO{sub 4}:Eu{sup 3+} nanostructure materials above can potentially applied in various fields of application, especially in luminescent labeling and visualization in biomedical application.

  16. Experimental study of diffuse ceiling ventilation in classroom

    DEFF Research Database (Denmark)

    Hviid, Christian Anker; Terkildsen, Søren

    Diffuse ceiling ventilation is a novel air distribution device that combines the suspended acoustic ceiling with ventilation supply. A diffuse ceiling distributes the supply air above the acoustic tiles and has proven performance in laboratory experiments. To study the performance in real conditi...

  17. The EU as a frontrunner on greenhouse gas emissions trading. How did it happen and will the EU succeed?

    International Nuclear Information System (INIS)

    Christiansen, Atle C.; Wettestad, Joergen

    2003-01-01

    The objective of this paper is first to provide empirical evidence of what can be seen as a rather remarkable change in EU's position on the use of greenhouse gas (GHG) emissions trading (ET) in climate policy, from the role of a sceptic in the run-up to Kyoto towards more of a frontrunner. The paper argues that there is a synergistic and multilevel mix of explanatory factors for this 'U-turn', including developments at the international, EU, Member State, sub-national, and even down to the personal level. Second, the paper explores and discusses the philosophy behind the Commission's proposal for a directive on GHG ET. Third, the paper examines the prospects for 'success' of a scheme for EU-wide ET using a multifaceted set of metrics. In brief, we argue that output success - the chances for having a directive adopted - hinges on the resolution of two key issues. First, whether the preliminary phase is to be mandatory or voluntary, and second, incompatibilities with domestic ET schemes. Outcome success - steering and cost-effectiveness - will in turn depend on factors like the coverage of the scheme and inclusion of project-based credits, while more long-term political implications hinges on the successful adoption and operation of the scheme

  18. Energy transfer and colour tunability in UV light induced Tm3+/Tb3+/Eu3+: ZnB glasses generating white light emission.

    Science.gov (United States)

    Naresh, V; Gupta, Kiran; Parthasaradhi Reddy, C; Ham, Byoung S

    2017-03-15

    A promising energy transfer (Tm 3+ →Tb 3+ →Eu 3+ ) approach is brought forward to generate white light emission under ultraviolet (UV) light excitation for solid state lightening. Tm 3+ /Tb 3+ /Eu 3+ ions are combinedly doped in zinc borate glass system in view of understanding energy transfer process resulting in white light emission. Zinc borate (host) glass displayed optical and luminescence properties due to formation of Zn(II) x -[O(-II)] y centres in the ZnB glass matrix. At 360nm (UV) excitation, triply doped Tm 3+ /Tb 3+ /Eu 3+ : ZnB glasses simultaneously shown their characteristic emission bands in blue (454nm: 1 D 2 → 3 F 4 ), green (547nm: 5 D 4 → 7 F 5 ) and red (616nm: 5 D 0 → 7 F 2 ) regions. In triple ions doped glasses, energy transfer dynamics is discussed in terms of Forster-Dexter theory, excitation & emission profiles, lifetime curves and from partial energy level diagram of three ions. The role of Tb 3+ in ET from Tm 3+ →Eu 3+ was discussed using branch model. From emission decay analysis, energy transfer probability (P) and efficiency (η) were evaluated. Colour tunability from blue to white on varying (Tb 3+ , Eu 3+ ) content is demonstrated from Commission Internationale de L'Eclairage (CIE) chromaticity coordinates. Based on chromaticity coordinates, other colour related parameters like correlated colour temperature (CCT) and colour purity are also computed for the studied glass samples. An appropriate blending of such combination of rare earth ions could show better suitability as potential candidates in achieving multi-colour and warm/cold white light emission for white LEDs application in the field of solid state lightening. Copyright © 2016 Elsevier B.V. All rights reserved.

  19. Does EU ETS lead to emission reductions through trade? The case of the Swedish emissions trading sector participants

    International Nuclear Information System (INIS)

    Sandoff, Anders; Schaad, Gabriela

    2009-01-01

    The first trading period of the European Emissions Trading Scheme (EU ETS) has recently come to an end. The experiences of the actors in the trading sector will be of great importance in evaluating the aim and direction of this 'Grand Policy Experiment'. This paper gives an account of the attitudes and actions of the companies included in the Swedish emissions trading sector after about 15 months of experience with the system. The data are based on a study commissioned by the Swedish Environmental Protection Agency, and is a comprehensive survey that encompasses all companies operating installations included in the Swedish Emission Trading Registry. However, the results point in a somewhat disquieting direction. Although the Swedish companies have shown significant interest in reducing emissions, this survey indicates that this is done without close attention to the pricing mechanism of the market-based instruments. If this praxis is widespread within the European trading sector, it can have a serious negative effect on the efficiency of the system.

  20. Color improvement of white-light through Mn-enhancing yellow-green emission of SrSi2O2N2:Eu phosphor for white light emitting diodes

    International Nuclear Information System (INIS)

    Fei Qinni; Liu Yanhua; Gu Tiecheng; Wang Dajian

    2011-01-01

    Photoluminescence (PL) enhancement of SrSi 2 O 2 N 2 :Eu and the resultant color improvement of white-light were investigated via co-doping Mn with Eu. We observed that a unique absorption of host lattice of SrSi 2 O 2 N 2 and its visible band emission peaked at around ∼550 nm for SrSi 2 O 2 N 2 :Mn 2+ in the wavelength range of 450-600 nm. This highly eye-sensitive ∼550 nm-peaked band emission of SrSi 2 O 2 N 2 doped with Mn 2+ happens to overlap the 535 nm-peaked band emission of SrSi 2 O 2 N 2 doped with Eu 2+ , resulting in an intensified photoluminescence in a maximum by 355%. By combining this as-prepared Mn intensified SrSi 2 O 2 N 2 :Eu phosphor with blue InGaN chip, the quality of white-light was improved to 93.3% for color rendering index and 3584 K for correlated color temperature. - Research highlights: Photoluminescence enhancement and resultant color improvement of SrSi 2 O 2 N 2 : Eu can be adjusted via co-doping Mn with Eu. The band emission peaked at ∼550 for Mn2+ overlaps that at ∼535 nm for Eu 2+ . A white-light with 93.3% for CRI and 3584 K for CCT is achieved.

  1. New reddish-orange and greenish-yellow light emitting phosphors: Eu3+ and Tb3+/Eu3+ in sodium germanate glass

    International Nuclear Information System (INIS)

    Álvarez, E.; Zayas, Ma. E.; Alvarado-Rivera, J.; Félix-Domínguez, F.; Duarte-Zamorano, R.P.; Caldiño, U.

    2014-01-01

    A spectroscopic analysis of sodium germanate glasses activated with Eu 3+ , Tb 3+ and Eu 3+ /Tb 3+ is performed from their photoluminescence spectra and decay times. In the Eu 3+ -singly doped glass reddish-orange light emission, with x=0.64 and y=0.35 CIE1931 chromaticity coordinates, is obtained upon Eu 3+ excitation at 393 nm. Such chromaticity coordinates are close to those (0.67, 0.33) proposed by the National Television Standard Committee for the red phosphor. When the sodium germanate glass is co-doped with Tb 3+ and Eu 3+ greenish-yellow light emission, with (0.41, 0.46) CIE1931 chromaticity coordinates, is obtained upon Tb 3+ excitation at 344 nm. Such greenish-yellow luminescence is due mainly to the terbium 5 D 4 → 7 F 6,5 and europium 5 D 0 → 7 F 1,2 emissions, Eu 3+ being sensitized by Tb 3+ through a non-radiative energy transfer. The non-radiative nature of this energy transfer is inferred from the increase in the decay rate of the Tb 3+ emission when the glass is co-doped with Eu 3+ . From an analysis of the Tb 3+ emission decay time curves it is inferred that such energy transfer might take place between Tb 3+ and Eu 3+ clusters through a short-range interaction mechanism. - Highlights: • Sodium germanate glasses are optically activated with Eu 3+ (GNE) and Tb 3+ /Eu 3+ (GNTE). • Reddish-orange light (0.64, 0.35) is generated by GNE pumped with 393 nm light. • Greenish-yellow light (0.41, 0.46) is generated by GNTE pumped with 344 nm light. • Non-radiative energy transfer Tb 3+ →Eu 3+ takes place in GNTE

  2. Energy transfer between the Eu2+ dipole and aggregate centers in CsBr:Eu crystals

    International Nuclear Information System (INIS)

    Zorenko, Yu.; Turchak, R.; Voznjak, T.

    2007-01-01

    The energy transfer between the Eu 2+ -V Cs dipole centers and presumable CsEuBr 3 aggregate centers has been studied in CsBr:Eu crystals by means of investigation of their time-resolved emission spectra and luminescence decay kinetics at 300 K

  3. Numerical analysis of diffuse ceiling ventilation and its integration with a radiant ceiling system

    DEFF Research Database (Denmark)

    Zhang, Chen; Heiselberg, Per Kvols; Chen, Qingyan

    2017-01-01

    A novel system combining diffuse ceiling ventilation and radiant ceiling was proposed recently, with the aim of providing energy efficient and comfort environment to office buildings. Designing of such a system is challenging because of complex interactions between the two subsystems and a large ......-uniformity air distribution and further led to the draught problem in the occupied zone. This system was recommended to apply in the small offices instead of large, open spaces....

  4. The impacts of U.S. withdrawal from the Paris Agreement on the carbon emission space and mitigation cost of China, EU, and Japan under the constraints of the global carbon emission space

    Directory of Open Access Journals (Sweden)

    Han-Cheng Dai

    2017-12-01

    Full Text Available Based on the Computable General Equilibrium (CGE model and scenario analysis, the impacts of the U.S. withdrawal from the Paris Agreement on the carbon emission space and mitigation cost in China, European Union (EU, and Japan are assessed under Nationally Determined Contributions (NDCs and 2 °C scenarios due to the changed emission pathway of the U.S. The results show that, under the condition of constant global cumulative carbon emissions and a fixed burden-sharing scheme among countries, the failure of the U.S. to honor its NDC commitment to different degrees will increase the U.S. carbon emission space and decrease its mitigation cost. However, the carbon emission space of other parties, including China, EU, and Japan, will be reduced and their mitigation costs will be increased. In 2030, under the 2 °C target, the carbon price will increase by 4.4–14.6 US$ t−1 in China, by 9.7–35.4 US$ t−1 in the EU, and by 16.0–53.5 US$ t−1 in Japan. In addition, China, EU, and Japan will incur additional Gross Domestic Production (GDP loss. Under the 2 °C target, the GDP loss of China would increase by US$22.0–71.1 billion (equivalent to 16.4–53.1 US$ per capita, the EU's GDP loss would increase by US$9.4–32.1 billion (equivalent to 20.7–71.1 US$ per capita, and Japan's GDP loss will increase by US$4.1–13.5 billion (equivalent to 34.3–111.6 US$ per capita.

  5. Broadband sensitized white light emission of g-C{sub 3}N{sub 4}/Y{sub 2}MoO{sub 6}:Eu{sup 3+} composite phosphor under near ultraviolet excitation

    Energy Technology Data Exchange (ETDEWEB)

    Han, Bing, E-mail: hanbing@zzuli.edu.cn [School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002 (China); Xue, Yongfei; Li, Pengju [School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002 (China); Zhang, Jingtao [School of Food and Bioengineering, Zhengzhou University of Light Industry, Zhengzhou 450002 (China); Zhang, Jie [School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002 (China); Shi, Hengzhen, E-mail: shihz@zzuli.edu.cn [School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002 (China)

    2015-12-15

    The g-C{sub 3}N{sub 4}/Y{sub 2}MoO{sub 6}:Eu{sup 3+} composite phosphors were synthesized and characterized by X-ray diffraction, Fourier transform-infrared spectroscopy, ultraviolet visible diffuse reflection spectra, photoluminescence spectra and luminescence decay curves. Under the excitation of 360 nm near ultraviolet light, these composite phosphors show tunable emission from blue to red region, in which white light emission can be obtained in term of appropriate quality proportion of Y{sub 2}MoO{sub 6}:Eu{sup 3+} relative to g-C{sub 3}N{sub 4}/Y{sub 2}MoO{sub 6}:Eu{sup 3+}. In addition, the emission color can be also dependent on the excitation wavelength in g-C{sub 3}N{sub 4}/Y{sub 2}MoO{sub 6}:Eu{sup 3+} composite phosphor. - Graphical abstract: Under the excitation of 360 nm near ultraviolet light, the g-C{sub 3}N{sub 4}/Y{sub 2}MoO{sub 6}:Eu{sup 3+} composite phosphors show tunable emission from blue to red region, in which white light emission can be obtained. - Highlights: • The g-C3N4/Y2MoO6:Eu{sup 3+} composite phosphors were synthesized and characterized. • White light emission was realized in the g-C3N4/Y2MoO6:Eu{sup 3+} composites under UV excitation. • A novel idea to realize the broadband sensitized white light emission in phosphors was provided.

  6. EU energy-intensive industries and emissions trading: losers becoming winners?

    Energy Technology Data Exchange (ETDEWEB)

    Wettestad, Joergen

    2008-11-15

    The EU Emissions Trading System (ETS) initially treated power producers and energy-intensive industries similarly, despite clear structural differences between these industries regarding pass through of costs and vulnerability to global competition. Hence, the energy-intensive industries could be seen as losing out in the internal distribution. In the January 2008 proposal for a reformed ETS post-2012, a differentiated system was proposed where the energy-intensive industries come out relatively much better. What is the explanation for the change taking place? Although power producers still have a dominant position in the system, the increasing consensus about windfall profits has weakened their standing. Conversely, the energy-intensive industries have become better organised and more active. This balance shift is first and foremost noticeable in several important EU-level stake holder consultation processes. Energy-intensive industries have, however, also successfully utilised the national pathway to exert influence on Brussels policy-making. Finally, growing fear of lax global climate policies and related carbon leakage has strengthened the case of these industries further. The latter dimension indicates that although energy-intensive industries have managed to reduce internal distribution anomalies, external challenges remain. (author). 9 refs

  7. The Glass Ceiling Initiative. A Report.

    Science.gov (United States)

    Department of Labor, Washington, DC.

    While minorities and women have made considerable gains in entering the workforce in the last few decades, there remains a dearth of minorities and women at management levels. This phenomenon has come to be known as the "glass ceiling." The Department of Labor defines the glass ceiling as those artificial barriers based on attitudinal or…

  8. -30 per cent EU-wide emission cut from the perspective of the Finnish economy; 30 prosentin vaehennystavoitteeseen siirtymisen energia- ja kansantaloudelliset vaikutukset

    Energy Technology Data Exchange (ETDEWEB)

    Honkatukia, J.; Koljonen, T.; Lehtilae, A.

    2013-03-15

    The Eu is considering the adoption of a tighter emission target, to replace the agreed -20 per cent emission target already agreed on. In this study, we analyze the implications of the proposed -30 per cent EU-wide emission cut from the perspective of the Finnish economy. We use an energy system model to study the technological choices and direct energy and investment costs of the stricter target, and an applied general equilibrium model to analyse its economic implications at industry and macroeconomic levels. We find that the stricter target increases the economic costs roughly proportionally to the abatement effort and consist mostly of the welfare losses of taxation. (orig.)

  9. The glass ceiling in nursing management.

    Science.gov (United States)

    Crawford, D I

    1993-01-01

    Women managers in business and health care have experienced discrimination related to advancement in management. Nurse executives must understand the strategies to overcome the barriers, the "glass ceiling," as well as implications for future practice. Women executives need an organized blueprint and the tools to dismantle the glass ceiling and overcome the political and discriminatory barriers to success.

  10. Decoupling Economic Growth From Carbon Dioxide Emissions in the EU Countries

    Directory of Open Access Journals (Sweden)

    Mariola Piłatowska

    2018-03-01

    Full Text Available This paper aims to look at the long-run equilibrium relationship between CO2 emissions and economic growth (the EKC hypothesis in an asymmetric framework using the non-linear threshold cointegration. In order to avoid the problem of omitted variables bias, the dynamic relationship between pollutant emissions, economic development and energy consumption are also examined (the extended EKC model. The research hypothesis is that the economic growth decouples from CO2 emissions growth, i.e. the EKC hypothesis holds. The empirical study is carried out for the European Union countries (EU-14 divided into three groups depending on a category of knowledge-advanced economies in order to explain the differences in the dynamic linkage between CO2 emissions and economic growth, as well as in the energy consumption impact on this cointegrating relationship. We have found that the EKC hypothesis is valid for the most high-level and some middle-level knowledge advanced economies. The addition of energy consumption to the standard EKC model has improved the results in terms of the presence of linear or threshold cointegration for all low-level knowledge based economies. Moreover, the causality pattern between CO2 emissions and income has changed after energy consumption adding to the EKC model and some similarities are found in the countries belonging to the same category of knowledge-advanced economies

  11. Synthesis, structure, and luminescence properties of SrSiAl2O3N2:Eu(2+) phosphors for light-emitting devices and field emission displays.

    Science.gov (United States)

    Wang, Xicheng; Zhao, Zhengyan; Wu, Quansheng; Li, Yanyan; Wang, Chuang; Mao, Aijun; Wang, Yuhua

    2015-06-28

    A series of SrSiAl2O3N2:Eu(2+) (0.005 ≤x≤ 0.05) phosphors were successfully synthesized through a pressureless, facile, and efficient solid state route. The crystal structure, band structure, and their photoluminescence and cathodoluminescence properties were investigated in detail. The phosphors exhibit rod shape morphology with a uniform Eu(2+) distribution. Under n-UV excitation the emission spectra shift from 477 to 497 nm with an increase of Eu(2+) concentration. The concentration quenching mechanism of Eu(2+) emission was dominated by the dipole-dipole interaction. The thermal stability is comparable to that of the commercial Ba2SiO4:Eu(2+) phosphor. The phosphor also exhibits high current saturation and high resistance under low voltage electron bombardment. All the results indicate that the SrSiAl2O3N2:Eu(2+) phosphors can be considered as candidates for application in both white LEDs and FEDs.

  12. The impacts of EU CO2 emissions trading on electricity markets and electricity consumers in Finland

    International Nuclear Information System (INIS)

    Kara, M.; Syri, S.; Lehtilae, A.; Helynen, S.; Kekkonen, V.; Ruska, M.; Forsstroem, J.

    2008-01-01

    In this paper, the likely impacts of the EU emission trading system on the Nordic electricity market and on the position of various market actors are assessed. In its first phase, the EU CO 2 emission trading system includes power plants with thermal capacity greater than 20 MW, metals industry, pulp and paper industry, mineral industry and oil refineries. This paper describes the assessment done for the Finnish Minister of Trade and Industry, analysing the likely impacts on power plant operators, on energy-intensive industries, on other industries and on other consumer groups. The impacts of emissions trading were studied with the VTT electricity market model and with the TIMES energy system model. The annual average electricity price was found to rise 0.74 EUR MW h -1 for every 1 Euro tonne CO 2 -1 in the Nordic area. Large windfall profits were estimated to incur to electricity producers in the Nordic electricity market. In Finland, metals industry and private consumers were estimated to be most affected by the electricity market price increases. Expanded nuclear power generation could limit the increases in the prices of electricity to one-third compared to those in the base case

  13. The EU Emissions Trading Scheme and Biomass. Final Report

    International Nuclear Information System (INIS)

    Schwaiger, H.; Tuerk, A.; Arasto, A.; Vehlow, J.; Kautto, N.; Sijm, J.; Hunder, M.; Brammer, J.

    2009-02-01

    Within its Energy and Climate Package, adopted by the European Parliament in December 2008, the European commission set a 10% minimum for the market share of renewables in the transport sector in 2020. To find the appropriate instruments to reach this target and the instrument mix with which biomass use in general could be best stimulated are the main questions of this project. An important instrument of the European Climate Policy is the European Emissions Trading Scheme (EU-ETS), which started operation in 2005. Previous work done within Bioenergy NoE showed that only a high share of auctioning of allowances and a high CO2 price provide necessary incentives for a higher biomass use. According to the Energy and Climate Package, all allowances will be auctioned in the energy sector from 2013 on, with exceptions for a few CEE countries. Based on work done within the project, a model has been developed to analyse at which CO2 price biomass becomes competitive in case of 100 per cent auctioning or at a lower level. The European Commission furthermore decided not to include the road transport sector into the EU-ETS until 2020. Whether the inclusion of the road transport sector in the EU-ETS, could help introducing biofuels, a separate trading scheme for biofuels should be set up, or biofuels should be addressed with other policy instruments, was another main question of this project. The first result shows that an integrated scheme would hardly have any effects on the use of liquid biofuels in the transportation sector, but might cause higher CO2 prices for the energy and industry sector. A separate trading scheme has been implemented in the UK in 2008, California is planning such as scheme in addition to include the road transport sector into the future ETS. Within this project the design of such as system has been elaborated based on the comparison of several policy instruments to increase the use of liquid biofuels in the transportation sector. Policy interaction

  14. Emission Scenario Document for Biocides Emission scenarios for all 23 product types of the Biocidal Products Directive (EU Directive 98/8/EC)

    NARCIS (Netherlands)

    Poel P van der; Bakker J; CSR

    2002-01-01

    This report presents an overview of all available emission scenarios for all 23 product types of biocides according to EU Directive 98/8/EC. The scenarios presented are already present in USES 3.0 or have been reported by RIVM or within the scope of the project "Gathering, review and development of

  15. Emissions of nitrogen oxides from road traffic - regulations, emissions and effects

    International Nuclear Information System (INIS)

    Sjoedin, Aake; Pihl-Karlsson, Gunilla; Johansson, Manne; Forsberg, Bertil; Erlandsson, Lennart

    2004-10-01

    The report is a review that aims to improve the basis for additional measures against the road traffic emissions of, in particular, NO x . An important question in the context is whether health effects of NO 2 should serve as a norm for the actions for emission reductions of NO x , or if the environmental effects of NO x -emissions in the form of acidification, eutrophication and ozone should play this role. WHO notes, in its latest review of health effect research, that one cannot demonstrate that NO 2 alone has any direct effects in concentrations at the current whole-year mean norm (40 μg/m 3 ). Such health effects that has been demonstrated in epidemiologic studies at these concentrations are caused by other traffic related emissions (e. g. particles) for which NO 2 constitutes a good indicator. WHO indicates the need for additional sharpening of the norms for ozone and particles. In this context, it is important to note that emissions of NO x on a regional scale contributes to formation of ozone as well as particles. Therefore there exist reasons to decrease the emissions of NO x in order to reach future recommended values for ozone and particles emissions. In the evaluations that will be done during 2004-2005 of the so called Goeteborg protocol, the EU's Ceiling Directives and the CAFE-programme, it is expected that new emissions objective for NO x will be suggested for 2015-2020, to cope with health and environment objectives in Europe. The report shows that that development that currently happens within the vehicle industry, for engines and exhaust emission control system are pursued to meet future exhaust requirement in the USA gives good conditions for the road traffic sector to contribute to that these objectives will reached

  16. Dy:Eu doped CaBAl glasses for white light applications

    Science.gov (United States)

    Lodi, T. A.; Sandrini, M.; Medina, A. N.; Barboza, M. J.; Pedrochi, F.; Steimacher, A.

    2018-02-01

    The combination of Eu3+ and Dy3+ in co-doped glassy materials provides interesting applicability for white light emission devices. In this work, Dy:Eu doped Calcium Boroaluminate (CaBAl) glasses were prepared by conventional melting quenching, with 3 wt% of Dy2O3 and Eu2O3 content varying from 0 to 3 wt%, and results of absorption spectra, photoluminescence and photoluminescence lifetime are discussed in terms of Eu2O3 content. The photoluminescence of the samples was studied under excitation of 365 and 405 nm light source. The 365 nm excitation shows favor to the Dy3+ ion emission. The results of photoluminescence lifetime at 575 nm (Dy3+) shows a decrease due to Eu2O3 addition, which suggests an energy transfer from Dy3+ (donor) to the Eu3+ (acceptor). On the other hand, under excitation of 405 nm, the photoluminescence lifetime at 575 nm (Dy3+) shows no significant changes due to Eu2O3 amount, which indicates that the energy transfer from Dy3+ to Eu3+ (under λexc = 405 nm) is negligible. However, the results of photoluminescence under 405 nm excitation present a white yellowish emission in the CIE diagram, which shifts to red with Eu2O3 addition. The combination of a Blue LED (BL) emission with the emission of the samples was also studied in the CIE diagram, in order to improve light emission and to obtain ideal White Light (WL). The results show that by modifying the emission intensity of BL, it is possible to achieve a route for smart lighting, close to the circadian light cycle.

  17. Enhanced red emission of LaVO{sub 4}:Eu{sup 3+} phosphors by Li-doping

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sung Wook; Yang, Hyun Kyoung; Chung, Jong Won; Moon, Byung Kee; Choi, Byung Chun; Jeong, Jung Hyun [Pukyoung National University, Busan (Korea, Republic of); Jang, Ki Wan; Lee, Ho Sueb [Changwon National University, Changwon (Korea, Republic of); Yi, Soung Soo [Silla University, Busan (Korea, Republic of)

    2010-12-15

    LaVO{sub 4} phosphors were synthesized by using a solid state reaction, and were characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence (PL). The XRD patterns of the Li-doped LaVO{sub 4}:Eu{sup 3+} powder phosphors revealed a mixture of tetragonal and monoclinic phases. The tetragonal phase of the LaVO{sub 4}:Eu{sup 3+} phosphor showed a higher PL intensity than the monoclinic one, despite the presence of both monoclinic and tetragonal structures. The Li-doped LaVO{sub 4}:Eu{sup 3+} powder phosphors absorbed strongly at 396 nm and exhibited strong red emission at approximately 619.5 nm due to the {sup 5}D{sub 0} {yields} {sup 7}F{sub 2} transition. The incorporation of Li{sup +} ions into the LaVO{sub 4}:Eu{sup 3+} powder can lead to a remarkable increase in photoluminescence. The enhanced luminescence is attributed to the incorporation of Li{sup +} ions that may act as a sensitizers for effective energy transfer. This phosphor has promising applications in near-UV light-emitting diodes(LEDs).

  18. Trader types and volatility of emission allowance prices. Evidence from EU ETS Phase I

    International Nuclear Information System (INIS)

    Balietti, Anca Claudia

    2016-01-01

    This paper studies the relation between the trading activity of market participants and the volatility of the European Emission Allowance price during Phase I of the European Union Emission Trading System (EU ETS). We focus on the contrasting roles of different trader types. We find evidence of a positive and significant trading activity–volatility relation, which appears to be stronger when accounting for trader type. The positive relation can be mainly attributed to energy providers. In contrast, industrial companies seem to have traded more frequently when volatility levels were lower. Finally, the non-liable players, represented by financial intermediaries, appear to have acted as a flexible counterparty, trading more with the energy sector when volatility was higher, and more with the industrial firms when volatility was lower. We discuss possible explanations for these contrasted positions. Understanding the trading activity–volatility link is relevant for evaluating the efficiency of the EU ETS. Although the relation is generally positive, many players remained often inactive and traded mostly when volatility levels were lower. Policies targeting the engagement of less active players could lead to a smoother incorporation of information into prices and to an increase in market efficiency. - Highlights: • We study the permit price volatility–trading activity link in the EU ETS Phase I. • We focus on the contrasting roles of different market players. • We show that the relation was overall positive, mainly due to energy providers. • Many other players remained inactive and traded more when volatility was lower. • Policies for the engagement of less active traders could increase market efficiency.

  19. Glass Ceiling : Women in management

    OpenAIRE

    Rantala, Virve

    2010-01-01

    This study has examined the phenomenon called Glass Ceiling. It has approached the phenomenon in two different views. One is career development and another one is women in management. Main purpose for this study was to inspect women working life and career opportunities. Why women’s career developments end in a certain level? What is glass ceiling and how to break it? Paper also investigates reasons behind the effect. Prejudices and biases are the worst enemies for women’s career. How to chan...

  20. Site and local structure of activator Eu{sup 2+} in phosphor Ca{sub 10−x}(PO{sub 4}){sub 6}Cl{sub 2}:xEu{sup 2+}

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Chun-Hai, E-mail: chwang81@gmail.com [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, Mianyang 621900 (China); Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); School of Physics, Peking University, Beijing 100871 (China); Gui, Dong-Yun; Qin, Rui [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, Mianyang 621900 (China); Yang, Feng-Li [Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Jing, Xi-Ping, E-mail: xpjing@pku.edu.cn [Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Tian, Guang-Shan [School of Physics, Peking University, Beijing 100871 (China); Zhu, Wenjun [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, Mianyang 621900 (China)

    2013-10-15

    The site and local structure of activator Eu{sup 2+} in phosphor Ca{sub 10−x}(PO{sub 4}){sub 6}Cl{sub 2}:xEu{sup 2+} is investigated by experiment measurements, first-principle calculations and XAFS simulations. From first-principle calculations, the “local” structure [bond length L(M–O)≤R(M{sup 2+})+R(O{sup 2−})] of host shows a significant deformation (expansion) when Ca{sup 2+} is substituted by Eu{sup 2+}, and Eu{sup 2+} should prefer 6h site to 4f site in the host. The d→f emission of Eu{sup 2+} at 4f site should show a longer wavelength than that of Eu{sup 2+} at 6h site. The XAFS measurement and simulations suggest that the Eu{sup 2+} in our Ca{sub 9.9}(PO{sub 4}){sub 6}Cl{sub 2}:0.1Eu{sup 2+} sample mainly locates at 6h site. In the emission spectrum, two emission profiles of Ca{sub 9.9}(PO{sub 4}){sub 6}Cl{sub 2}:0.1Eu{sup 2+} sample are obtained and assigned. The major one (2.71 eV≈456 nm) should be the emission of Eu{sup 2+} at 6h site. The minor one (2.61 eV≈465 nm) should be that of Eu{sup 2+} at 4f site. - Graphical abstract: The d→f emission of Eu{sup 2+} in Ca{sub 9.9}(PO{sub 4}){sub 6}Cl{sub 2}:0.1Eu{sup 2+} can be assigned as: emission profile at 2.71 eV and 2.61 eV are Eu{sup 2+} at 6h and 4f site, respectively. Display Omitted - Highlights: • Eu{sup 2+} in Ca{sub 10−x}(PO{sub 4}){sub 6}Cl{sub 2}:xEu{sup 2+} causes deformation to “local” structure. • Eu{sup 2+} should prefer 6h site to 4f site in the host from energy aspect. • Emission at 2.71 eV and 2.61 eV should be Eu{sup 2+} at 6h and 4f site.

  1. 48 CFR 217.7404-2 - Price ceiling.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 3 2010-10-01 2010-10-01 false Price ceiling. 217.7404-2 Section 217.7404-2 Federal Acquisition Regulations System DEFENSE ACQUISITION REGULATIONS SYSTEM... Contract Actions 217.7404-2 Price ceiling. UCAs shall include a not-to-exceed price. ...

  2. Investigation of intrinsic and extrinsic defects effective role on producing intense red emission in ZnO:Eu nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Najafi, Mehrdad, E-mail: najafi@shahroodut.ac.ir; Haratizadeh, Hamid

    2015-05-15

    Highlights: • Effective role of defects on producing red emission at indirect excitation. • V{sub Zn} and V{sub O} defects have important role on energy transfer. • Mg related defects and Zn{sub i} defects were responsible for blue emission. • Extrinsic and intrinsic defects mediated energy transfer to sensitize Eu{sup 3+} ions. • Decrease of red emission because of diminishing in oxygen vacancy. - Abstract: Europium doped ZnO nanorads and nanosheets were synthesized by hydrothermal method. Effects of Mg doping, morphology and annealing in oxygen ambient on structural and optical properties of ZnO nanostructures were investigated using X-ray diffraction (XRD), particle size analysis (PSA), thermo gravimetric analysis (TGA), differential thermal analysis (DTA), differential thermo gravimetry (DTG), scanning electron microscopy (SEM) and photoluminescence spectroscopy (PL). This study recommends that both of intrinsic and extrinsic defects facilitate energy transfer (ET) from the ZnO host to Eu{sup 3+} ions and consequently have efficient role on producing intense red emission at indirect excitation. The results also showed that annealing process improved the crystal structure of ZnO nanosheets due to decrease of surface defects; however decreased ET and red emission because of diminishing in oxygen vacancy. In addition in ZnO nanorods sample with more surface area in comparison with ZnO nanosheets sample deep level emissions are enhanced.

  3. Energy transfer and tunable multicolor emission and paramagnetic properties of GdF3:Dy(3+),Tb(3+),Eu(3+) phosphors.

    Science.gov (United States)

    Guan, Hongxia; Sheng, Ye; Xu, Chengyi; Dai, Yunzhi; Xie, Xiaoming; Zou, Haifeng

    2016-07-20

    A series of Dy(3+), Tb(3+), Eu(3+) singly or doubly or triply doped GdF3 phosphors were synthesized by a glutamic acid assisted one-step hydrothermal method. The samples were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and photoluminescence (PL) spectroscopy. The results show that the synthesized samples are all pure GdF3. The obtained samples have a peanut-like morphology with a diameter of about 270 nm and a length of about 600 nm. Under UV excitation, GdF3:Dy(3+), GdF3:Tb(3+) and GdF3:Eu(3+) samples exhibit strong blue, green and red emissions, respectively. By adjusting their relative doping concentrations in the GdF3 host, the different color hues of green and red light are obtained by co-doped Dy(3+), Tb(3+) and Tb(3+), Eu(3+) ions in the GdF3 host, respectively. Besides, there exist two energy transfer pairs in the GdF3 host: (1) Dy(3+) → Tb(3+) and (2) Tb(3+) → Eu(3+). More significantly, in the Dy(3+), Tb(3+), and Eu(3+) tri-doped GdF3 phosphors, white light can also be achieved upon excitation of UV light by adjusting the doping concentration of Eu(3+). In addition, the obtained samples also exhibit paramagnetic properties at room temperature (300 K) and low temperature (2 K). It is obvious that multifunctional Dy(3+), Tb(3+), Eu(3+) tri-doped GdF3 materials including tunable multicolors and intrinsic paramagnetic properties may have potential applications in the field of full-color displays.

  4. EU climate policy up to 2020. An economic impact assessment

    Energy Technology Data Exchange (ETDEWEB)

    Boehringer, Christoph [Department of Economics, University of Oldenburg (Germany); Centre for European Economic Research (ZEW) Mannheim (Germany); Loeschel, Andreas [Centre for European Economic Research (ZEW) Mannheim (Germany); Moslener, Ulf [KfW Development Bank, Frankfurt (Germany); Rutherford, Thomas F. [Center for Energy Policy and Economy (CEPE), ETH Zuerich (Switzerland)

    2009-07-01

    In its fight against climate change the EU is committed to reducing its overall greenhouse gas emissions to at least 20% below 1990 levels by 2020. To meet this commitment, the EU builds on segmented market regulation with an EU-wide cap-and-trade system for emissions from energy-intensive installations (ETS sectors) and additional measures by each EU Member State covering emission sources outside the cap-and-trade system (the non-ETS sector). Furthermore, the EU has launched additional policy measures such as renewable energy subsidies in order to promote compliance with the climate policy target. Basic economic reasoning suggests that emission market segmentation and overlapping regulation can create substantial excess costs if we focus only on the climate policy target. In this paper, we evaluate the economic impacts of EU climate policy based on numerical simulations with a computable general equilibrium model of international trade and energy use. Our results highlight the importance of initial market distortions and imperfections as well as alternative baseline projections for the appropriate assessment of EU compliance cost. (author)

  5. EU climate policy up to 2020: An economic impact assessment

    Energy Technology Data Exchange (ETDEWEB)

    Boehringer, Christoph, E-mail: boehringer@uni-oldenburg.d [Department of Economics, University of Oldenburg (Germany); Centre for European Economic Research (ZEW) Mannheim (Germany); Loeschel, Andreas [Centre for European Economic Research (ZEW) Mannheim (Germany); Moslener, Ulf [KfW Development Bank, Frankfurt (Germany); Rutherford, Thomas F. [Center for Energy Policy and Economy (CEPE), ETH Zuerich (Switzerland)

    2009-07-01

    In its fight against climate change the EU is committed to reducing its overall greenhouse gas emissions to at least 20% below 1990 levels by 2020. To meet this commitment, the EU builds on segmented market regulation with an EU-wide cap-and-trade system for emissions from energy-intensive installations (ETS sectors) and additional measures by each EU Member State covering emission sources outside the cap-and-trade system (the non-ETS sector). Furthermore, the EU has launched additional policy measures such as renewable energy subsidies in order to promote compliance with the climate policy target. Basic economic reasoning suggests that emission market segmentation and overlapping regulation can create substantial excess costs if we focus only on the climate policy target. In this paper, we evaluate the economic impacts of EU climate policy based on numerical simulations with a computable general equilibrium model of international trade and energy use. Our results highlight the importance of initial market distortions and imperfections as well as alternative baseline projections for the appropriate assessment of EU compliance cost.

  6. EU climate policy up to 2020. An economic impact assessment

    International Nuclear Information System (INIS)

    Boehringer, Christoph; Loeschel, Andreas; Moslener, Ulf; Rutherford, Thomas F.

    2009-01-01

    In its fight against climate change the EU is committed to reducing its overall greenhouse gas emissions to at least 20% below 1990 levels by 2020. To meet this commitment, the EU builds on segmented market regulation with an EU-wide cap-and-trade system for emissions from energy-intensive installations (ETS sectors) and additional measures by each EU Member State covering emission sources outside the cap-and-trade system (the non-ETS sector). Furthermore, the EU has launched additional policy measures such as renewable energy subsidies in order to promote compliance with the climate policy target. Basic economic reasoning suggests that emission market segmentation and overlapping regulation can create substantial excess costs if we focus only on the climate policy target. In this paper, we evaluate the economic impacts of EU climate policy based on numerical simulations with a computable general equilibrium model of international trade and energy use. Our results highlight the importance of initial market distortions and imperfections as well as alternative baseline projections for the appropriate assessment of EU compliance cost. (author)

  7. CO{sub 2} emissions of newly homologated private cars in Switzerland: EU orientation; CO{sub 2}-Emissionen der PW-Neuzulassungen der Schweiz: Orientierung an der EU - Schlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Haan, P. de

    2009-05-15

    In this final report for the Swiss Federal Office of Energy (SFOE), the Institute for Environmental Decisions at the Swiss Federal Institute of Technology ETH in Zurich reports on the carbon dioxide emissions of newly homologated vehicles in Switzerland. The report examines if, how, until when and with which pricing-signals Switzerland can adopt the EU's strategy for attaining an average CO{sub 2} emission rate of 130 g/km for newly homologated vehicles. It is noted that the Swiss car market is completely integrated into the EU market. The models used are looked at and demand-side tools such as models on the basis of sanctions and certificates are considered. Further points examined include measures for attaining a further 10 g/km saving, as well as rebound effects and economic feasibility aspects. Finally, monitoring using annual data for result-checking and Swiss joint CO{sub 2} monitoring reporting are discussed.

  8. Narrow spectral emission CaMoO{sub 4}: Eu{sup 3+}, Dy{sup 3+}, Tb{sup 3+} phosphor crystals for white light emitting diodes

    Energy Technology Data Exchange (ETDEWEB)

    Khanna, A. [Smart Lighting Engineering Research Center, 110, 8th Street, Troy, New York, 12180 (United States); Electrical, Computer and Systems Engineering Department, Rensselaer Polytechnic Institute, 110, 8th Street, Troy, New York, 12180 (United States); Dutta, P.S., E-mail: duttap@rpi.edu [Smart Lighting Engineering Research Center, 110, 8th Street, Troy, New York, 12180 (United States); Electrical, Computer and Systems Engineering Department, Rensselaer Polytechnic Institute, 110, 8th Street, Troy, New York, 12180 (United States)

    2013-02-15

    Alkaline earth metal molybdates are promising candidates as a host material for high efficiency narrow spectral emission phosphors. These phosphors could potentially be used for the fabrication of phosphor-converted light emitting diodes (pc-LEDs). Phosphor crystals of calcium molybdate doped with rare earth dopant Ln{sup 3+}(Ln=Eu, Dy, Tb) grown using flux growth method have been shown to exhibit higher excitation efficiency than the powders synthesized by solid-state reaction process. Molybdenum (VI) oxide has been found to be a suitable flux for growing large size optically transparent high quality crystals at a temperature around 1100 Degree-Sign C. Using the excitation wavelengths of 465 nm, 454 nm and 489 nm for CaMoO{sub 4}: Eu{sup 3+}, CaMoO{sub 4}: Dy{sup 3+} and CaMoO{sub 4}: Tb{sup 3+}, respectively, intense emission lines at wavelengths of 615 nm, 575 nm and 550 nm were observed. The optimized doping concentrations of 12%, 2% and 5% for Eu{sup 3+}, Dy{sup 3+} and Tb{sup 3+}, respectively, provided the highest luminescence intensity. - Graphical Abstract: CaMoO{sub 4}: Eu{sup 3+} phosphor crystals grown using a molybdenum (VI) oxide flux exhibited around 1.5 times the emission intensity of powders obtained from solid-state reaction at the same synthesis temperature. These crystals were found to efficiently emit 615 nm red light when excited by near UV light up to a wavelength of 395 nm. Highlights: Black-Right-Pointing-Pointer CaMoO{sub 4}: Ln{sup 3+} (Ln=Eu{sup 3+}, Dy{sup 3+}, Tb{sup 3+}) phosphor crystals were successfully grown using high temperature flux (solutions) containing molybdenum (VI) oxide or lithium chloride. Black-Right-Pointing-Pointer Narrow spectral emission at 615 nm, 575 nm and 550 nm, respectively, was observed from CaMoO{sub 4}: Ln{sup 3+} (Ln=Eu{sup 3+}, Dy{sup 3+}, Tb{sup 3+}) phosphor crystals. Black-Right-Pointing-Pointer The optimized doping concentrations of Eu{sup 3+}, Dy{sup 3+}, Tb{sup 3+} in CaMoO{sub 4} for highest

  9. Yellow light emission from Ta2O5:Er, Eu, Ce thin films deposited using a simple co-sputtering method

    Directory of Open Access Journals (Sweden)

    K. Miura

    2015-01-01

    Full Text Available Erbium, europium, and cerium co-doped tantalum oxide (Ta2O5:Er, Eu, Ce thin films were prepared using a simple co-sputtering method, and yellow light emission was observed by the naked eye from a sample annealed at 900 °C for 20 min. The hexagonal Ta2O5 phase is very important, but the hexagonal CeTa7O19 phase should be avoided to obtain strong yellow light emission from Ta2O5:Er, Eu, Ce films. The co-sputtered films can be used as high-refractive-index and yellow-light-emitting materials of autocloned photonic crystals that can be applied to novel light-emission devices, and they will also be used as anti-reflection and down-conversion layers toward high-efficiency silicon solar cells.

  10. Principle, function, experiences, hybrid chilled ceilings; Prinzip, Funktion, Erfahrungen. Hybrid-Kuehldecken

    Energy Technology Data Exchange (ETDEWEB)

    Schulz, Uwe W. [Hochschule Luzern (Switzerland). Technik und Architektur

    2010-12-15

    Hybrid chilled ceilings combine a radiation chilled ceiling with thermal activations of a concrete ceiling. The activation permits the utilization of alternative and/or small cold generators for the efficient night cooling. The traditional chilled ceiling grants a speedy reaction to load variations as well as a reduction of the reverberation periods. In addition, the combination supplies a draught-free insertion of air. Beside established solutions, MWH Barcol-Air (Staefa, Switzerland) also offers project-specific hybrid chilled ceilings.

  11. Breaking the glass ceiling.

    Science.gov (United States)

    Lazarus, A

    1997-03-01

    The glass ceiling is a form of organizational bias and discrimination that prevents qualified professionals from achieving positions of top governance and leadership. This article examines glass ceiling barriers that keep physicians from the upper reaches of management. While these factors apply mainly to women and minority physicians in academia, and are attributable to sexual harassment and discrimination, physicians as a class are frequently denied executive management positions. Such denial results from inadequate preparation for a career in health care administration. Important issues in the professional development of physician executives include mentoring, training and education, administrative experience, and cultural and personality factors. All of those must be considered when making the transition from medicine to management.

  12. Diffuse Ceiling Ventilation

    DEFF Research Database (Denmark)

    Zhang, Chen; Yu, Tao; Heiselberg, Per Kvols

    with conventional ventilation systems (mixing or displacement ventilation), diffuse ceiling ventilation can significantly reduce or even eliminate draught risk in the occupied zone. Moreover, this ventilation system presents a promising opportunity for energy saving, because of the low pressure loss, extended free...

  13. Why quota trade should be restricted: The arguments behind the EU position on emissions trading

    International Nuclear Information System (INIS)

    Westskog, Hege

    2001-01-01

    In this paper I try to clarify the background and arguments behind the EU position on emissions trading in negotiating the Kyoto Protocol and their suggestions of how the supplementary cap in the Kyoto agreement can be operationalized. I discuss economic arguments for restricting quota trade with a focus on the market power issue, transaction costs, and ancillary benefits of reducing emissions of climate gases. I also address the problem of hot air as an important argument to restrict quota trade, and arguments for restrictions connected to technological innovation. Finally, I look into the ethical considerations of restrictions. (author)

  14. Why quota trade should be restricted: The arguments behind the EU position on emissions trading

    Energy Technology Data Exchange (ETDEWEB)

    Westskog, Hege

    2001-07-01

    In this paper I try to clarify the background and arguments behind the EU position on emissions trading in negotiating the Kyoto Protocol and their suggestions of how the supplementarity cap in the Kyoto agreement can be operationalized. I discuss economic arguments for restricting quota trade with a focus on the market power issue, transaction costs, and ancillary benefits of reducing emissions of climate gases. I also address the problem of hot air as an important argument to restrict quota trade, and arguments for restrictions connected to technological innovation. Finally, I look into the ethical considerations of restrictions. (author)

  15. Optical spectroscopy and optical waveguide fabrication in Eu3+ and Eu3+/Tb3+ doped zinc–sodium–aluminosilicate glasses

    International Nuclear Information System (INIS)

    Caldiño, U.; Speghini, A.; Berneschi, S.; Bettinelli, M.; Brenci, M.; Pasquini, E.; Pelli, S.; Righini, G.C.

    2014-01-01

    Optical and spectroscopic properties of 2.0% Eu(PO 3 ) 3 singly doped and 5.0% Tb(PO 3 ) 3 –2.0% Eu(PO 3 ) 3 codoped zinc–sodium–aluminosilicate glasses were investigated. Reddish-orange light emission, with x=0.64 and y=0.36 CIE1931 chromaticity coordinates, is obtained in the europium singly doped glass excited at 393 nm. Such chromaticity coordinates are close to those (0.67,0.33) standard of the National Television System Committee for the red phosphor. When the sodium–zinc–aluminosilicate glass is co-doped with Tb 3+ and Eu 3+ , reddish-orange light emission, with (0.61,0.37) CIE1931 chromaticity coordinates, is obtained upon Tb 3+ excitation at 344 nm. This reddish-orange luminescence is generated mainly by 5 D 0 → 7 F 1 and 5 D 0 → 7 F 2 emissions of Eu 3+ , europium being sensitized by terbium through a non-radiative energy transfer. From an analysis of the Tb 3+ emission decay curves it is inferred that the Tb 3+ →Eu 3+ energy transfer might take place between Tb 3+ and Eu 3+ clusters through a short-range interaction mechanism, so that an electric dipole–quadrupole interaction appears to be the most probable transfer mechanism. The efficiency of this energy transfer is about 62% upon excitation at 344 nm. In the singly doped and codoped glasses multimode optical waveguides were successfully produced by Ag + –Na + ion exchange, and they could be characterized at various wavelengths. -- Highlights: • Reddish-orange light emission can be generated from Tb 3+ and Eu 3+ codoped zinc–sodium–aluminosilicate glasses excited at 344 nm. • The Eu 3+ is sensitized by Tb 3+ through a non-radiative energy transfer. • Highly multimode waveguides can be fabricated by diluted silver–sodium exchange. • This type of AlGaN LEDs pumped glass phosphors might be useful for generation of reddish-orange light

  16. CO2 price dynamics. The implications of EU emissions trading for the price of electricity

    International Nuclear Information System (INIS)

    Sijm, J.P.M.; Bakker, S.J.A.; Harmsen, H.W.; Lise, W.; Chen, Y.

    2005-09-01

    The present study analyses the relationship between EU emissions trading and power prices, notably the implications of free allocation of emissions allowances for the price of electricity in countries of North-western Europe. To study this impact, it uses a variety of analytical approaches, including interviews with stakeholders, empirical and statistical analyses, theoretical explorations, and analyses by means of the COMPETES model. The study shows that a significant part of the costs of freely allocated allowances is passed through to power price and discusses its implications in terms of higher electricity prices for consumers and windfall profits for producers. It concludes that free allocation of emission allowances is a highly questionable policy option for a variety of reasons and suggests that auctioning might offer a better perspective

  17. Enhanced luminescence in Eu-doped ZnO nanocrystalline films

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Keigo, E-mail: ksuzuki@murata.com; Murayama, Koji; Tanaka, Nobuhiko [Murata Manufacturing Co., Ltd., 10-1, Higashikotari 1-chome, Nagaokakyo, Kyoto 617-8555 (Japan)

    2015-07-20

    We found an enhancement of Eu{sup 3+} emissions in Eu-doped ZnO nanocrystalline films fabricated by microemulsion method. The Eu{sup 3+} emission intensities were increased by reducing annealing temperatures from 633 K to 533 K. One possible explanation for this phenomenon is that the size reduction enhances the energy transfer from ZnO nanoparticles to Eu{sup 3+} ions. Also, the shift of the charge-transfer band into the low-energy side of the absorption edge is found to be crucial, which seems to expedite the energy transfer from O atoms to Eu{sup 3+} ions. These findings will be useful for the material design of Eu-doped ZnO phosphors.

  18. New reddish-orange and greenish-yellow light emitting phosphors: Eu{sup 3+} and Tb{sup 3+}/Eu{sup 3+} in sodium germanate glass

    Energy Technology Data Exchange (ETDEWEB)

    Álvarez, E. [Departamento de Física, Universidad de Sonora (UNISON), Boulevard Luis Encinas y Rosales s/n, Hermosillo 83000, Sonora (Mexico); Zayas, Ma. E. [Departamento de Investigación en Física, Universidad de Sonora (UNISON), Boulevard Luis Encinas y Rosales s/n, Hermosillo 83000, Sonora (Mexico); Alvarado-Rivera, J. [Departamento de Física, Universidad de Sonora (UNISON), Boulevard Luis Encinas y Rosales s/n, Hermosillo 83000, Sonora (Mexico); Félix-Domínguez, F. [Departamento de Física, Universidad de Sonora (UNISON), Boulevard Luis Encinas y Rosales s/n, Hermosillo 83000, Sonora (Mexico); Centro de investigación en Materiales Avanzados, S.C. Miguel de Cervantes 120, Complejo industrial Chihuahua, Chihuahua 31109, Chihuahua (Mexico); Duarte-Zamorano, R.P. [Departamento de Física, Universidad de Sonora (UNISON), Boulevard Luis Encinas y Rosales s/n, Hermosillo 83000, Sonora (Mexico); Caldiño, U., E-mail: cald@xanum.uam.mx [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, PO Box 55-534, México City 09340, Distrito Federal (Mexico)

    2014-09-15

    A spectroscopic analysis of sodium germanate glasses activated with Eu{sup 3+}, Tb{sup 3+} and Eu{sup 3+}/Tb{sup 3+} is performed from their photoluminescence spectra and decay times. In the Eu{sup 3+}-singly doped glass reddish-orange light emission, with x=0.64 and y=0.35 CIE1931 chromaticity coordinates, is obtained upon Eu{sup 3+} excitation at 393 nm. Such chromaticity coordinates are close to those (0.67, 0.33) proposed by the National Television Standard Committee for the red phosphor. When the sodium germanate glass is co-doped with Tb{sup 3+} and Eu{sup 3+} greenish-yellow light emission, with (0.41, 0.46) CIE1931 chromaticity coordinates, is obtained upon Tb{sup 3+} excitation at 344 nm. Such greenish-yellow luminescence is due mainly to the terbium {sup 5}D{sub 4}→{sup 7}F{sub 6,5} and europium {sup 5}D{sub 0}→{sup 7}F{sub 1,2} emissions, Eu{sup 3+} being sensitized by Tb{sup 3+} through a non-radiative energy transfer. The non-radiative nature of this energy transfer is inferred from the increase in the decay rate of the Tb{sup 3+} emission when the glass is co-doped with Eu{sup 3+}. From an analysis of the Tb{sup 3+} emission decay time curves it is inferred that such energy transfer might take place between Tb{sup 3+} and Eu{sup 3+} clusters through a short-range interaction mechanism. - Highlights: • Sodium germanate glasses are optically activated with Eu{sup 3+} (GNE) and Tb{sup 3+}/Eu{sup 3+} (GNTE). • Reddish-orange light (0.64, 0.35) is generated by GNE pumped with 393 nm light. • Greenish-yellow light (0.41, 0.46) is generated by GNTE pumped with 344 nm light. • Non-radiative energy transfer Tb{sup 3+}→Eu{sup 3+} takes place in GNTE.

  19. Sectoral agreements and competitive distortions - a Swedish perspective; Effects of EU Emissions Trading System for European industry

    Energy Technology Data Exchange (ETDEWEB)

    Zetterberg, Lars; Holmgren, Kristina

    2009-03-15

    The objectives of this study are to: Give an overview of the current discussion concerning competition distortion in relation to climate policy; Describe results from some studies estimating the actual competition situation for selected activities; Describe what sector agreement models are suggested/ discussed by EU; Describe what sectors are most interesting to target with a sector agreement from a Swedish point of view; Analyse what parameters are important for reducing competition distortion for Swedish Industry. Two studies, for the United Kingdom and Germany, have recently assessed the potential cost impact for different industrial sectors of CO{sub 2}-prices due to the EU ETS. The sectors with high potential impact, with a maximum value at stake larger than 10%, are in the United Kingdom Lime and cement, Basic iron and steel, Starches, Refined petroleum, Fertilizers and Nitrogen compounds and Aluminium. In Germany: Cement and lime, Fertilizers and nitrogen compounds, Basic iron and steel, Aluminium, Paper and board, Other basic inorganic compounds and Coke, refined petroleum and nuclear fuels. Ex-ante studies of the impacts of competitiveness and carbon leakage due to the EU ETS fail to find actual impacts. However, that does not mean that there will be no impact in the future, which hold changes both in the EU ETS (method for allowance allocation, allowance prices etc) and possibly also other important circumstances. In this study, based on official Swedish statistics, the maximum value a stake has been calculated for 52 Swedish sectors. Seven sectors have a maximum value a stake of more than 4%: Coke and refined petroleum (21%), Pulp and paper (11%), Basic metals (10%), Non-metallic mineral (9%), Metal ore mines (6%), Air transport (5%) and Electricity, gas and heat (4%). If Air transport and Electricity, gas and heat are omitted, the five remaining sectors account for 22% of Sweden's carbon emissions. In late 2008, the EU proposed three types of

  20. Next allocation phase of the EU emissions trading scheme: How tough will the future be?

    International Nuclear Information System (INIS)

    Georgopoulou, E.; Sarafidis, Y.; Mirasgedis, S.; Lalas, D.P.

    2006-01-01

    The development of National Allocation Plans (NAPs) for the first phase 2005-2007 of the EU emissions trading scheme (EU-ETS) was accompanied by the stated concern of the industrial enterprises with installations that fall under the scope of the relevant Directive 2003/87, since the impacts of the allocation in their financial and technical modes of operation were judged to be severe. Thus, the intensity of the negotiations for the next allocation phase (i.e. 2008-2012), is expected to be heated. With a view to assisting enterprises, especially in the energy sector or for which energy use and its management is a crucial part of their activity, to incorporate in their business plans the impacts of the Directive in an informed manner, an attempt is made here to explore the constraints and the available options that will guide the coming EU-ETS potential allocations. In the analysis, the credits derived from the use of CDM are specifically taken into account. The results show that the next allocations would tend to be significantly more stringent than the current ones because of the combined effect of no inter-period transfer of allowances, the amount of CDM credits expected to be available compared to the amount of effort that would be required and the yield of emission reductions from existing or planned policies and measures. It becomes then crucial, if not imperative, for the enterprises involved as well as national governments to examine carefully means to address their obligations under the Directive

  1. Excitation-dependent local symmetry reversal in single host lattice Ba2A(BO3)2:Eu3+ [A = Mg and Ca] phosphors with tunable emission colours.

    Science.gov (United States)

    Jayakiruba, S; Chandrasekaran, S Selva; Murugan, P; Lakshminarasimhan, N

    2017-07-05

    Eu 3+ activated phosphors are widely used as red emitters in various display devices and light emitting diodes (LEDs). The emission characteristics of Eu 3+ depend on the local site symmetry. The present study demonstrates the role of excitation-dependent local symmetry changes due to the structural reorganization on the emission colour tuning of Eu 3+ from orange-red to orange in single host lattices, Ba 2 Mg(BO 3 ) 2 and Ba 2 Ca(BO 3 ) 2 . The choice of these lattices was based on the difference in the extent of strain experienced by the oxygen atoms. The samples with Eu 3+ at Ba or Mg (Ca) sites were synthesized using the conventional high-temperature solid-state reaction method. The samples were characterized using powder XRD, 11 B MAS-NMR, FT-IR, and diffuse reflectance UV-Vis spectroscopic techniques. The room temperature photoluminescence (PL) recorded using different excitation wavelengths revealed a clear difference in the PL emission features due to symmetry reversal from non-inversion to inversion symmetry around Eu 3+ . The reorganization of highly strained oxygen atoms leads to such symmetry reversal. First-principles calculations were used to deduce the optimized structures of the two borate host lattices, and local geometries and their distortions upon Eu 3+ substitution. The outcomes of these calculations support the experimental findings.

  2. What Glass Ceiling?

    Science.gov (United States)

    Lynch, Michael; Post, Katherine

    1996-01-01

    A recent study drawing on data from the Census Bureau and the Bureau of Labor Statistics suggests that the wage gap between men and women has virtually disappeared, and that the so-called "glass ceiling" results more from age and qualifications than from explicit discrimination. (SLD)

  3. Parental leave and the glass ceiling in Sweden

    OpenAIRE

    Albrecht, James; Skogman Thoursie, Peter; Vroman, Susan

    2015-01-01

    In this paper, we update and extend "Is There a Glass Ceiling in Sweden?" (Albrecht et al. 2003) by documenting the extent to which the gender log wage gap across the distribution in Sweden has changed over the period 1998-2008. We then examine the Swedish glass ceiling in 2008 in more detail by documenting how it differs for white-collar versus blue-collar workers and for private- versus public-sector workers. We also examine when in the life cycle the glass ceiling effect arises and how thi...

  4. The Glass Ceiling: Progress and Persistent Challenges

    Science.gov (United States)

    McLlwain, Wendy M.

    2012-01-01

    It has been written that since 2001, there has not been any significant progress and the glass ceiling is still intact. Women are still underrepresented in top positions (Anonymous, 2004). If this is true, the glass ceiling presents a major barrier between women and their desire to advance into executive or senior management positions. In addition…

  5. Evaluation of ceiling lifts in health care settings: patient outcome and perceptions.

    Science.gov (United States)

    Alamgir, Hasanat; Li, Olivia Wei; Gorman, Erin; Fast, Catherine; Yu, Shicheng; Kidd, Catherine

    2009-09-01

    Ceiling lifts have been introduced into health care settings to reduce manual patient lifting and thus occupational injuries. Although growing evidence supports the effectiveness of ceiling lifts, a paucity of research links indicators, such as quality of patient care or patient perceptions, to the use of these transfer devices. This study explored the relationship between ceiling lift coverage rates and measures of patient care quality (e.g., incidence of facility-acquired pressure ulcers, falls, urinary infections, urinary incontinence, and assaults [patient to staff] in acute and long-term care facilities), as well as patient perceptions of satisfaction with care received while using ceiling lifts in a complex care facility. Qualitative semi-structured interviews were used to generate data. A significant inverse relationship was found between pressure ulcer rates and ceiling lift coverage; however, this effect was attenuated by year. No significant relationships existed between ceiling lift coverage and patient outcome indicators after adding the "year" variable to the model. Patients generally approved of the use of ceiling lifts and recognized many of the benefits. Ceiling lifts are not detrimental to the quality of care received by patients, and patients prefer being transferred by ceiling lifts. The relationship between ceiling lift coverage and pressure ulcer rates warrants further investigation. Copyright (c) 2009, SLACK Incorporated.

  6. Enhancement of white-light-emission from single-phase Sr5(PO4)3F:Eu(2+),Mn(2+) phosphors for near-UV white LEDs.

    Science.gov (United States)

    Feng, Yaomiao; Huang, Jinping; Liu, Lili; Liu, Jie; Yu, Xibin

    2015-09-07

    A series of single-phase broadband white-light-emitting Sr5(PO4)3F:Eu(2+),Mn(2+) phosphors were prepared by a solid state reaction. The luminescence property, and the crystal and electronic structures of the fluorophosphates were studied by photoluminescence analysis, XRD Rietveld refinement and density functional theory calculation (DFT), respectively. Under near ultraviolet excitation in the 250 to 430 nm wavelength range, the phosphors exhibit two emission bands centered at 440 and 556 nm, caused by the Eu(2+) and Mn(2+) ions. By altering the relative ratios of Eu(2+) and Mn(2+) in the compounds, the emission color could be modulated from blue to white. The efficient energy transfer from the Eu(2+) to Mn(2+) ions could be ascribed to the well crystallized host lattice and the facile substitution of Eu(2+) and Mn(2+) for Sr(2+) sites due to similar ionic radii. A series of fluxes were investigated to improve the photoluminescence intensity. When KCl was used as flux in the synthesis, the photoluminescence intensity of Sr5(PO4)3F:Eu(2+),Mn(2+) was enhanced by 85% compared with no fluxes added. These results demonstrate that the single-phase Sr5(PO4)3F:Eu(2+),Mn(2+) with enhanced luminescence efficiency could be promising as a near UV-convertible direct white-light-emitting phosphor for WLED applications.

  7. METHOD FOR EVALUATING MOLD GROWTH ON CEILING TILE

    Science.gov (United States)

    A method to extract mold spores from porous ceiling tiles was developed using a masticator blender. Ceiling tiles were inoculated and analyzed using four species of mold. Statistical analysis comparing results obtained by masticator extraction and the swab method was performed. T...

  8. Synthesis and investigation of photo/cathodoluminescence properties of a novel green emission phosphor Sr{sub 8}ZnLu(PO{sub 4}){sub 7}:Eu{sup 2+}

    Energy Technology Data Exchange (ETDEWEB)

    Long, Qiang; Wang, Chuang; Li, Yanyan; Ding, Jianyan [Department of Materials Science, School of Physical Science and Technology, Lanzhou University (China); Key Laborary of Special Function Materials and Structure Design, Ministry of Education, Lanzhou University, Tianshui South Road No. 222, Lanzhou, Gansu 730000 (China); Wang, Yuhua, E-mail: wyh@lzu.edu.cn [Department of Materials Science, School of Physical Science and Technology, Lanzhou University (China); Key Laborary of Special Function Materials and Structure Design, Ministry of Education, Lanzhou University, Tianshui South Road No. 222, Lanzhou, Gansu 730000 (China)

    2016-06-25

    An Eu{sup 2+}-activated Sr{sub 8}ZnLu(PO{sub 4}){sub 7} (SZLP:Eu{sup 2+}) green emitting phosphor was synthesized and its crystal structure has been refined and determined from the XRD profiles by Rietveld refinement method. The excitation spectra of the SZLP:Eu{sup 2+} phosphors covered the range from 250 to 450 nm, which matches well with n-UV chips. SZLP:Eu{sup 2+} exhibited broad-band green emission centered at about 520 nm under 400 nm irradiation with a high quantum efficiency (QE) value of 67.4% and good thermal stability, its emission intensity remains 77% at 150 °C of that measured at room temperature. In addition, to investigate its application in field emission displays, the cathodoluminescence spectra of SZLP:Eu{sup 2+} as a function of the accelerating voltage, probe current and the electron radiation time were also measured and discussed in detail. Excellent degradation resistance properties with good color stability were obtained by continuous low-voltage electron-beam excitation of the phosphor. - Highlights: • An novel green emitting phosphor was firstly synthesized by solid state reaction. • The excitation spectra match well with n-UV chips and the quantum efficiency is 67.4%. • The thermal stability of the phosphor is superior to commercial phosphors.

  9. Nanophosphor CaSO4:Eu2+ for photoluminescence liquid crystal display (PLLCD)

    Science.gov (United States)

    Patle, Anita; Patil, R. R.; Moharil, S. V.

    2018-05-01

    In this work PL enhancement of CaSO4:Eu2+ nanophosphor which was synthesized with 0.01M molarity by co-precipitation method is presented. Synthesized phosphor was characterized by XRD, SEM, TEM and PL measurements. Average particle size is found to be in the range 80-100nm with Hexagonal morphology and PL studies showed emission peaks at 380nm, when samples were excited by 254nm. The observed PL emission is characteristic emission of Eu2+ similar to that observed in bulk CaSO4:Eu2. However under identical condition it is observed that intensity of emission get enhanced for 0.01M size which is doubled to that of 0.1M with similar emission at 380nm. A phosphor with narrow emission band around 390 nm is desirable, since at this wavelength the transmission of standard glass, polarizing plastic, other coating and LCD material is at acceptable level. Strong Eu2+ emission is observed in CaSO4:Eu nanophosphor which finds applications for PLLCD (photoluminescent liquid crystal display).

  10. Non-ETS emission targets for 2030. Indication of emission targets for the Netherlands and other EU Member States under the European Effort Sharing Decision

    Energy Technology Data Exchange (ETDEWEB)

    Verdonk, M.; Hof, A.

    2013-10-15

    As European Member States are making progress towards their 2020 targets in the Effort Sharing Decision, the attention of policymakers is shifting to a framework beyond 2020. The European Commission launched a discussion with its Green Paper on a possible policy framework for 2030. This PBL Note aims to contribute to that discussion by analysing the effects of various assumptions on Member States' non-ETS emission targets for 2030. The effort sharing of the current European target for 2020 has resulted in an emission target of +20% relative to 2005 levels for the least wealthy Member State and -20% for the three wealthiest Member States. The targets for all other Member States were determined based on per-capita income levels of 2005. For possible non-ETS targets for 2030, we assumed a Europe-wide emission reduction target of 40% for 2030, compared to 1990 levels. This target is considered by the European Commission as the most cost-efficient to achieve a low-carbon economy by 2050. The 2030 target was split into a target for emissions covered by the EU Emissions Trading System (ETS) and one for emissions that are not covered by the ETS (non-ETS). According to our estimations, European non-ETS emissions need to be reduced by around 30% by 2030, compared to 2005 levels. We distributed the non-ETS reduction target of 30% over the Member States by using similar effort sharing principles that are applied in the EU Effort Sharing Decision for 2020, but with different targets assumed for the least wealthy Member State. We also took recent per-capita income levels into account. However, we did not take into account the costs and effects of emission reductions on GDP. This PBL Note analyses two possible scenarios that differ in the target assumed for the least wealthy Member State, in order to assess the effects of differing assumptions on the 2030 non-ETS targets. These scenarios should be considered as 'what if' scenarios and not as political positions

  11. Red emission enhancement from CaMoO4:Eu3+ by co-doping of Bi3+ for near UV/blue LED pumped white pcLEDs: Energy transfer studies

    Science.gov (United States)

    Wangkhem, Ranjoy; Yaba, Takhe; Shanta Singh, N.; Ningthoujam, R. S.

    2018-03-01

    CaMoO4:Eu3+ (3 at. %)/Bi3+ (x at. %) nanophosphors were synthesized hydrothermally. All the samples can be excited by 280, 320, 393, and 464 nm (blue) wavelengths for generation of red color emission. Enhancement in 5D0 → 7F2 (615 nm) emission (f-f transition) of Eu3+ is observed when Bi3+ is incorporated in CaMoO4:Eu3+. This is due to the efficient energy transfer from Bi3+ to Eu3+ ions. Introduction of Bi3+ in the system does not lead to the change of emission wavelength of Eu3+. However, Bi3+ incorporation in the system induces a shift in Mo-O charge transfer band absorption from 295 to 270 nm. This may be due to the increase in electronegativity between Mo and O bond in the presence of Bi3+ leading to change in crystal field environment of Mo6+ in MoO42-. At the optimal concentration of Bi3+, an enhancement in emission by a factor of ˜10 and 4.2 in the respective excitation at 393 (7F0 → 5L6) and 464 nm (7F0 → 5D2) is observed. The energy transfer efficiency from Bi3+ to Eu3+ increases from 75% to 96%. The energy transfer is observed to occur mainly via dipole-dipole interactions. Maximum quantum yield value of 55% is observed from annealed CaMoO4:Eu3+ (3 at. %) when sensitized with Bi3+ (15 at. %) under 464 nm excitation. From Commission International de I'Eclairage chromaticity coordinates, the color (red) saturation is observed to be nearly 100%.

  12. The EU Emissions Trading Scheme. Allowance Prices, Trade Flows, Competitiveness Effects

    International Nuclear Information System (INIS)

    Klepper, G.; Peterson, S.

    2004-03-01

    The upcoming European Emissions Trading Scheme (ETS) is one of the more controversial climate policy instruments. Predictions about its likely impact and its performance can at present only be made to a certain degree. As long as the National Allocations Plans are not finally settled the overall supply of allowances is not determined. In this paper we will identify key features and key impacts of the EU ETS by scanning the range of likely allocation plans using the simulation model DART. The analysis of the simulation results highlights a number of interesting details in terms of allowance trade flows between member countries, of allowance prices, and in terms of the role of the accession countries in the ETS

  13. Free allocations in EU ETS Phase 3: The impact of emissions performance benchmarking for carbon-intensive industry - Working Paper No. 2013-14

    International Nuclear Information System (INIS)

    Lecourt, S.; Palliere, C.; Sartor, O.

    2013-02-01

    From Phase 3 (2013-20) of the European Union Emissions Trading Scheme, carbon-intensive industrial emitters will receive free allocations based on harmonised, EU-wide benchmarks. This paper analyses the impacts of these new rules on allocations to key energy-intensive sectors across Europe. It explores an original dataset that combines recent data from the National Implementing Measures of 20 EU Member States with the Community Independent Transaction Log and other EU documents. The analysis reveals that free allocations to benchmarked sectors will be reduced significantly compared to Phase 2 (2008-12). This reduction should both increase public revenues from carbon auctions and has the potential to enhance the economic efficiency of the carbon market. The analysis also shows that changes in allocation vary mostly across installations within countries, raising the possibility that the carbon-cost competitiveness impacts may be more intense within rather than across countries. Lastly, the analysis finds evidence that the new benchmarking rules will, as intended, reward installations with better emissions performance and will improve harmonisation of free allocations in the EU ETS by reducing differences in allocation levels across countries with similar carbon intensities of production. (authors)

  14. Role of Eu"2"+ on the blue‐green photoluminescence of In_2O_3:Eu"2"+ nanocrystals

    International Nuclear Information System (INIS)

    Devi, Konsam Reenabati; Meetei, Sanoujam Dhiren; Singh, Shougaijam Dorendrajit

    2016-01-01

    Blue‐green light emitting undoped and europium doped indium oxide nanocrystal were synthesized by simple precipitation method. X-ray diffraction (XRD) pattern confirmed the cubic phase of undoped and europium doped samples. Further, transmission electron microscopy (TEM), scanning electron microscopy (SEM) , energy dispersive analysis of X-rays (EDAX), Fourier transform infra-red (FT-IR), photoluminescence (PL), electron paramagnetic resonance (EPR) studies were performed to characterise the samples. PL analysis of the samples is the core of the present research. It includes excitation, emission and CIE (Commission Internationale de l’e´ clairage) studies of the samples. On doping europium to In_2O_3 lattice, ln"3"+ site is substituted by Eu"2"+ thereby increasing the concentration of singly ionized oxygen vacancy and hence blue–green emission from the host is found to increase. Further, this increase in blue–green emission after doping may also be attributed to 4f → 5d transitions of Eu"2"+. However, the blue–green PL emission is found to decrease after an optimum dopant concentration (Eu"2"+ = 4%) due to luminescence and size quenching. CIE co-ordinates of the samples are calculated to know colour of light emitted from the samples. It suggests that this blue–green light emitting In_2O_3: Eu"2"+ nanocrystals may find application in lighting such as in generation of white light. - Highlight: • XRD and TEM study confirms the synthesis of cubic doped and europium doped nanocrystals. • EPR study reveals the doped europium is in + 2 oxidation state. • Enhance PL emission intensity of host material due to increase in singly ionized oxygen vacancy and 4f–5d transitions of Eu"2"+ • CIE co-ordinates suggest the blue–green colour of the samples.

  15. 48 CFR 243.204-70-2 - Price ceiling.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 3 2010-10-01 2010-10-01 false Price ceiling. 243.204-70..., DEPARTMENT OF DEFENSE CONTRACT MANAGEMENT CONTRACT MODIFICATIONS Change Orders 243.204-70-2 Price ceiling. Unpriced change orders shall include a not-to-exceed price. [75 FR 48277, Aug. 10, 2010] ...

  16. EU effect: Exporting emission standards for vehicles through the global market economy.

    Science.gov (United States)

    Crippa, M; Janssens-Maenhout, G; Guizzardi, D; Galmarini, S

    2016-12-01

    Emission data from EDGAR (Emissions Database for Global Atmospheric Research), rather than economic data, are used to estimate the effect of policies and of the global exports of policy-regulated goods, such as vehicles, on global emissions. The results clearly show that the adoption of emission standards for the road transport sector in the two main global markets (Europe and North America) has led to the global proliferation of emission-regulated vehicles through exports, regardless the domestic regulation in the country of destination. It is in fact more economically convenient for vehicle manufacturers to produce and sell a standard product to the widest possible market and in the greatest possible amounts. The EU effect (European Union effect) is introduced as a global counterpart to the California effect. The former is a direct consequence of the penetration of the EURO standards in the global markets by European and Japanese manufacturers, which effectively export the standard worldwide. We analyze the effect on PM 2.5 emissions by comparing a scenario of non-EURO standards against the current estimates provided by EDGAR. We find that PM 2.5 emissions were reduced by more than 60% since the 1990s worldwide. Similar investigations on other pollutants confirm the hypothesis that the combined effect of technological regulations and their diffusion through global markets can also produce a positive effect on the global environment. While we acknowledge the positive feedback, we also demonstrate that current efforts and standards will be totally insufficient should the passenger car fleets in emerging markets reach Western per capita figures. If emerging countries reach the per capita vehicle number of the USA and Europe under current technological conditions, then the world will suffer pre-1990 emission levels. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. GROWTH EVALUATION OF FUNGI (PENICILLIUM AND ASPERGILLUS SPP.) ON CEILING TILES

    Science.gov (United States)

    The paper gives results of an evaluation of the potential for fungal growth on four different ceiling tiles in static chambers. It was found that even new ceiling tiles supported fungal growth under favorable conditions. Used ceiling tiles appeared to be more susceptible to funga...

  18. Synthesis and optical properties of red/blue-emitting Sr2MgSi2O7:Eu3+/Eu2+ phosphors for white LED

    Directory of Open Access Journals (Sweden)

    Tong Thi Hao Tam

    2016-06-01

    Full Text Available Phosphor-converted white light emitting diodes (white LEDs have received great attention in recent years since they have several excellent features such as high lumen output, low power consumption, long lifetime and environmentally friendly. In this work, we report the co-precipitation synthesis of red/blue Sr2MgSi2O7:Eu3+/Eu2+ phosphors with various Eu doping concentration. The results show that the obtained Sr2MgSi2O7:Eu3+/Eu2+ phosphors have good crystallinity and emit strong red (Sr2MgSi2O7:Eu3+ and blue (Sr2MgSi2O7:Eu2+ emissions under near UV light excitation. The sharp emission peaks at 577, 590, 612, 653, and 701 nm corresponded to the typical 5D0 → 7Fj (j = 0,1,2,3,4 transitions of Eu3+, and the blue emission peaking at 460 nm is attributed to the typical 4f65d1-4f7 transition of Eu2+ in the same Sr2MgSi2O7 host lattice. Both phosphors can be well excited in the wavelength range of 260–400 nm where the near UV-LED is well matched. The above results suggest that the Sr2MgSi2O7:Eu3+/Eu2+ phosphors are promising red/blue-emitting phosphors for the application in near UV pumped phosphor-converted white LEDs.

  19. Tailored white light emission in Eu3+/Dy3+ doped tellurite glass phosphors containing Al3+ ions

    Science.gov (United States)

    Walas, Michalina; Piotrowski, Patryk; Lewandowski, Tomasz; Synak, Anna; Łapiński, Marcin; Sadowski, Wojciech; Kościelska, Barbara

    2018-05-01

    Tellurite glass systems modified by addition of aluminum fluoride AlF3 have been successfully synthesized as host matrices for optically active rare earth ions RE3+ (RE3+ = Eu3+, Dy3+). Samples with different Eu3+ to Dy3+ molar ratio have been studied in order to determine possibility of white light emission via UV excitation. Structural investigations confirmed amorphous character of materials whereas spectroscopic studies brought more insight into glass network's nature. FTIR results shown presence of two features related to tellurite glass matrix (in 490-935 cm-1 spectral region) and another one (940-1250 cm-1) due to aluminum addition. Especially, Al-O and Te-O-Al bonds of AlO4 tetrahedrons have been found. AlO4 units are considered as glass formers that improve network's strength and thermal resistivity against devitrification. Based on XPS studies of Al3+ photoelectron band the existence of Al-O and also Al-F bonds have been examined. Moreover, signals originating from Eu3+ and Dy3+ have been found confirming their valence state. Luminescence results revealed possibility of simultaneous UV excitation of Eu3+ and Dy3+ ions. Excitation with λexc = 390 and 393 nm resulted in white light generation starting from warm white to neutral and cool white depending on Eu3+ concentration and used excitation wavelength. Additionally, increase of decay lifetime of Eu3+ induced by Al3+ presence have been revealed based on luminescence decay analysis. Thus, tellurite glass systems modified by AlF3 and doped with Eu3+/Dy3+ may be considered as promising candidates for white light emitting sources.

  20. Optically active centers in Eu implanted, Eu in situ doped GaN, and Eu doped GaN quantum dots

    International Nuclear Information System (INIS)

    Bodiou, L.; Braud, A.; Doualan, J.-L.; Moncorge, R.; Park, J. H.; Munasinghe, C.; Steckl, A. J.; Lorenz, K.; Alves, E.; Daudin, B.

    2009-01-01

    A comparison is presented between Eu implanted and Eu in situ doped GaN thin films showing that two predominant Eu sites are optically active around 620 nm in both types of samples with below and above bandgap excitation. One of these sites, identified as a Ga substitutional site, is common to both types of Eu doped GaN samples despite the difference in the GaN film growth method and in the doping technique. High-resolution photoluminescence (PL) spectra under resonant excitation reveal that in all samples these two host-sensitized sites are in small amount compared to the majority of Eu ions which occupy isolated Ga substitutional sites and thus cannot be excited through the GaN host. The relative concentrations of the two predominant host-sensitized Eu sites are strongly affected by the annealing temperature for Eu implanted samples and by the group III element time opening in the molecular beam epitaxy growth. Red luminescence decay characteristics for the two Eu sites reveal different excitation paths. PL dynamics under above bandgap excitation indicate that Eu ions occupying a Ga substitutional site are either excited directly into the 5 D 0 level or into higher excited levels such as 5 D 1 , while Eu ions sitting in the other site are only directly excited into the 5 D 0 level. These differences are discussed in terms of the spectral overlap between the emission band of a nearby bound exciton and the absorption bands of Eu ions. The study of Eu doped GaN quantum dots reveals the existence of only one type of Eu site under above bandgap excitation, with Eu PL dynamics features similar to Eu ions in Ga substitutional sites

  1. Light emission efficiency and imaging performance of Lu{sub 2}O{sub 3}:Eu nanophosphor under X-ray radiography conditions: Comparison with Gd{sub 2}O{sub 2}S:Eu

    Energy Technology Data Exchange (ETDEWEB)

    Seferis, I. [Faculty of Chemistry, Wroclaw University, 14F Joliot-Curie Street, 50-383 Wroclaw (Poland); Department of Medical Physics, Medical School, University of Patras, 265 00 Patras (Greece); Michail, C.; Valais, I. [Department of Biomedical Engineering, Technological Educational Institute of Athens, 122 10 Athens (Greece); Zeler, J. [Faculty of Chemistry, Wroclaw University, 14F Joliot-Curie Street, 50-383 Wroclaw (Poland); Liaparinos, P.; Fountos, G.; Kalyvas, N.; David, S. [Department of Biomedical Engineering, Technological Educational Institute of Athens, 122 10 Athens (Greece); Stromatia, F. [Department of Radiology and Nuclear Medicine, “IASO” General Hospital, Mesogion 264, 15562 Holargos (Greece); Zych, E. [Faculty of Chemistry, Wroclaw University, 14F Joliot-Curie Street, 50-383 Wroclaw (Poland); Kandarakis, I., E-mail: kandarakis@teiath.gr [Department of Biomedical Engineering, Technological Educational Institute of Athens, 122 10 Athens (Greece); Panayiotakis, G. [Department of Medical Physics, Medical School, University of Patras, 265 00 Patras (Greece)

    2014-07-01

    Nanocrystallic europium-activated lutetium oxide (Lu{sub 2}O{sub 3}:Eu) is a strong candidate for use in digital medical imaging applications, due to its spectroscopic and structural properties. The aim of the present study was to investigate the imaging and efficiency properties of a 33.3 mg/cm{sup 2} Lu{sub 2}O{sub 3}:Eu scintillating screen coupled to a high resolution RadEye HR CMOS photodetector under radiographic imaging conditions. Since Lu{sub 2}O{sub 3}:Eu emits light in the red wavelength range, the light emission efficiency and the imaging performance were compared with results for a Gd{sub 2}O{sub 2}S:Eu phosphor screen. Parameters such as the Absolute Efficiency (AE), the X-ray Luminescence Efficiency (XLE), and the Detector Quantum Gain (DQG), were investigated. The imaging characteristics of Lu{sub 2}O{sub 3}:Eu nanophosphor screen were investigated in terms of the Modulation Transfer Function (MTF), the Normalized Noise Power Spectrum (NNPS) and the Detective Quantum Efficiency (DQE). It was found that Lu{sub 2}O{sub 3}:Eu nanophosphor has higher AE and XLE by a factor of 1.32 and 1.37 on average, respectively, in the whole radiographic energy range in comparison with the Gd{sub 2}O{sub 2}S:Eu screen. DQG was also found higher in the energy range from 50 kVp to 100 kVp and comparable thereafter. The imaging quality of Lu{sub 2}O{sub 3}:Eu nanophosphor coupled to the CMOS sensor was found to outmatch in any aspect in comparison with the Gd{sub 2}O{sub 2}S:Eu screen. These results indicate that Lu{sub 2}O{sub 3}:Eu nanophosphor could be considered for further research in order to be used in medical imaging applications. - Highlights: • AE and XLE of Lu{sub 2}O{sub 3}:Eu nanophosphor were higher by a factor of 1.32 and 1.37 than Gd{sub 2}O{sub 2}S:Eu. • DQG was higher from 50 to 100 kVp and comparable thereafter. • Imaging performance of Lu{sub 2}O{sub 3}:Eu/CMOS was better than that of Gd{sub 2}O{sub 2}S:Eu/CMOS.

  2. The IFIEC method for the allocation of CO2 allowances in the EU Emissions Trading Scheme. A review applied to the electricity sector

    International Nuclear Information System (INIS)

    Bart Wesselink; Sebastian Klaus Alyssa; Gilbert Kornelis Blok

    2008-03-01

    Recently the European Commission has published a proposal to improve the function of the EU-ETS by amending the Directive which establishes the EU-ETS. The main changes proposed are the establishment of one EU-wide cap and the use of auctioning for a much greater share of allowances than is currently the case, replacing most of the allocation free of charge. Auctioning of allowances will eliminate the so-called windfall profits that occur under the current allocation free of charge that is based on historic production and emission levels; a grandfathering approach. IFIEC EUROPE, the international federation of industrial energy consumers, asked Ecofys to review the method that IFIEC has developed in recent years to allocate CO2 allowances in the EU emissions trading scheme (EU-ETS). According to IFIEC, their allocation method guarantees the same environmental outcome as other methods, without causing windfall profits and with lower risks of competitiveness loss for so-called exposed industrial users of electricity. It was decided to focus this study on the European electricity sector. This was done for several reasons: CO2 emissions from electricity generation cover a large part of the overall emission under EU-ETS, the electricity sector has a single well defined output (electricity) that can be used to illustrate the potential impact of the IFIEC benchmark based allocation approach, and electricity is a substantial cost factor for IFIEC members. This evaluation covers many aspects of IFIEC's method and compares these with two other allocation methods: auctioning and historic grandfathering. Within the IFIEC method two example approaches are evaluated: a single benchmark for electricity production and fuel-specific benchmarks for coal and gas fired electricity production. In the evaluation, we cover the following aspects: What is the IFIEC method; how does it differ from other allocation methods in character (chapter 2); What is the impact of different allocation

  3. 78 FR 25626 - Energy Conservation Program for Consumer Products: Energy Conservation Standards for Ceiling Fans...

    Science.gov (United States)

    2013-05-02

    ... Conservation Program for Consumer Products: Energy Conservation Standards for Ceiling Fans and Ceiling Fan... for residential ceiling fans and ceiling fan light kits in the Federal Register. This document... other aspect of the rulemaking for ceiling fans and ceiling fan light kits. The comment period is...

  4. Multichannel Luminescence Properties of Mixed-Valent Eu2+/Eu3+ Coactivated SrAl3BO7 Nanocrystalline Phosphors for Near-UV LEDs.

    Science.gov (United States)

    Liu, Xiaoming; Xie, Weijie; Lü, Ying; Feng, Jingchun; Tang, Xinghua; Lin, Jun; Dai, Yuhua; Xie, Yu; Yan, Liushui

    2017-11-20

    Up to now, orchestrating the coexistence of Eu 2+ and Eu 3+ activators in a single host lattice has been an extremely difficult task, especially for the appearance of the characteristic emission of Eu 2+ and Eu 3+ in order to generate white light. Nevertheless, here we demonstrate a new Eu 2+ /Eu 3+ coactivated SrAl 3 BO 7 nanocrystalline phosphor with abundant and excellent multichannel luminescence properties. A series of Eu 2+ /Eu 3+ coactivated SrAl 3 BO 7 nanocrystalline phosphors were prepared through a Pechini-type sol-gel method followed by a reduction process. With excitation of UV/NUV light, the prepared SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphors show not only the characteristic f-f transitions of Eu 3+ ion ( 5 D J → 7 F J,J' , J, J' = 0-3), but also the 5d → 4f transitions of Eu 2+ ion with comparable intensity from 400 to 700 nm in the whole visible spectral region. The luminescence color of the SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphor can be tuned from blue, blue-green, white, and orange to orange-red by changing the excitation wavelength, the overall doping concentration of europium ions (Eu 2+ , Eu 3+ ), and the relative ratio of Eu 2+ to Eu 3+ ions to some extent. A single-phase white-light emission has been realized in SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphor. The obtained SrAl 3 BO 7 :Eu 2+ ,Eu 3+ phosphor has potential application in the area of NUV white-light-emitting diodes.

  5. Research paper 2000-B-3: the implementation of the EU large combustion plant directive (88/609) in France

    Energy Technology Data Exchange (ETDEWEB)

    Schucht, S.

    2000-07-01

    This paper constitutes a contribution to the project 'IMPOL - The Implementation of EU Environmental Policies: Efficiency Issues'. The main objective of this paper is twofold: a description of the implementation process in a historic review and an evaluation according to economic criteria of the implementation of the 1988 EEC Large Combustion Plant Directive (LCPD) in France. The analysis focuses on the electricity supply industry (ESI) and the Directive's provisions towards SO{sub 2} emissions from existing large combustion plants (LCPs), as defined by the Directive. These provisions take the form of national emission ceilings defined for the years 1993, 1998 and 2003 which are presented in the form of overall national emission reduction objectives for the LCP sector. The reference year is 1980. The question of how these emission ceilings were to be reached, i.e. which instruments were to be applied, was left to the discretion of the Member States. In France, we find a large over-compliance with the Directive's targets. This result is, largely, explained by the French nuclear power programme, which was set up after the first oil crisis and which took effects between 1980 and 1990. Furthermore, we find that there were no demands towards existing ESI LCPs or measures taken by the ESI that could be linked to the LCPD. Policy directed at SO{sub 2} and NO{sub x} emissions from existing ESI LCPs is limited to a voluntary commitment ('EDF-programme') of Electricite de France (EDF), France's largest electricity supplier and - only in a few cases - to requirements related to the French air quality law, i.e. to requirements defined for local protection areas. Owing to a lack of measures related to the LCP Directive, we analyse the implementation of the EDF programme as well. The economic evaluation is based on criteria of environmental effectiveness and of cost efficiency, productive efficiency and administrative costs. Environmental

  6. Measurements on Buoyant Jet Flows from a Ceiling-Mounted Slot Diffuser

    DEFF Research Database (Denmark)

    Nielsen, Peter V.; Möller, Åke T. A.

    Ceiling-mounted slot diffusers in ventilated rooms will often generate a flow of the wall jet type. The jet follows the ceiling, entrains air from the occupied zone and generates a recirculating flow in the whole room. This paper will deal with the flow in the ceiling region. The wall jet flow...

  7. Mitigation of Nitrogen Emissions from Animal Agriculture in Europe

    Science.gov (United States)

    Oenema, O.

    2011-12-01

    More than 70% of the utilized agricultural area (187 Mha) in the 27 Member States of the European Union (EU-27) is used for animal production. In addition, a considerable amount of animal feed is imported. Dairy and beef cattle, pigs, and poultry are the dominant animal species. Total livestock density is highest in the Netherlands, Belgium, Ireland, Denmark and some regions in France, Germany and Italy. The mean nitrogen (N) retention in animal products in EU-27 in 2005 was 20% for milk, 8% for beef, 25% for pork, 38% for poultry and 28% for egg production. This indicates that dairy cows excreted on average 80% of the N intake, beef cattle 92%, pigs 75%, poultry 62% and layers 72%. There was a large variation in N retention between countries. Animal manures and nitrogen (N) fertilizers are main sources of N emissions. In 2005, mean N excretion by animals ranged from less than 25 kg per ha per year in Bulgaria to nearly 250 kg per ha in The Netherlands. On average 25% of the total amount of N excreted was lost as ammonia (NH3) to the atmosphere, though with a considerable variation between countries. About 10% was lost as NH3-N from housing systems, 9% from manure application to land, 4% from manure storage and treatment facilities, and 3% from grazing. Nitrogen leaching was in the same order of magnitude. Animal production also had a considerable share in the total emissions of greenhouse gases to the atmosphere (range 5-25%). Especially dairy cattle and beef cattle contribute to the emissions of methane (CH4) and nitrous oxide (N2O) to the atmosphere. Considerable efforts are being made to decrease N emissions from agriculture in EU-27. Good agricultural practices and mandatory emission mitigation measures are enforced through EU environmental policies, including Nitrates Directive, National Emissions Ceiling Directive, and Water Framework Directive. Some countries have succeeded to decrease the NH3 emissions to air and N leaching losses to groundwater and

  8. Red/blue-shift dual-directional regulation of α-(Ca, Sr)2SiO4:Eu(2+) phosphors resulting from the incorporation content of Eu(2+)/Sr(2+) ions.

    Science.gov (United States)

    Lu, Zhijuan; Mao, Zhiyong; Chen, Jingjing; Wang, Dajian

    2015-09-21

    In this work, tunable emission from green to red and the inverse tuning from red to green in α-(Ca, Sr)2SiO4:Eu(2+) phosphors were demonstrated magically by varying the incorporation content of Eu(2+) and Sr(2+) ions, respectively. The tunable emission properties and the tuning mechanism of red-shift resulting from the Eu(2+) content as well as that of blue-shift induced by the Sr(2+) content were investigated in detail. As a result of fine-controlling the incorporation content of Eu(2+), the emission peak red-shifts from 541 nm to 640 nm. On the other hand, the emission peak inversely blue-shifts from 640 nm to 546 nm through fine-adjusting the incorporation content of Sr(2+). The excellent tuning characteristics for α-(Ca, Sr)2SiO4:Eu(2+) phosphors presented in this work exhibited their various application prospects in solid-state lighting combining with a blue chip or a near-UV chip.

  9. The perception of the glass ceiling phenomenon

    OpenAIRE

    2012-01-01

    M.B.A. Barriers that hinder career advancement of women are both complex and varied. They have become top priority for organizations and the government. The "glass ceiling" is a term that symbolizes a variety of barriers that prevent individuals from advancing up the corporate hierarchy. Although many women hold management positions, few have made the breakthrough to toplevel positions. To determine what conditions are required for women to break the glass ceiling and attain management pos...

  10. Ammonia volatilization from crop residues and frozen green manure crops

    NARCIS (Netherlands)

    Ruijter, de F.J.; Huijsmans, J.F.M.; Rutgers, B.

    2010-01-01

    Agricultural systems can lose substantial amounts of nitrogen (N). To protect the environment, the European Union (EU) has adopted several directives that set goals to limit N losses. National Emission Ceilings (NEC) are prescribed in the NEC directive for nitrogen oxides and ammonia. Crop residues

  11. Host composition dependent tunable multicolor emission in the single-phase Ba2(Ln1-zTbz)(BO3)2Cl:Eu phosphors

    NARCIS (Netherlands)

    Xia, Z.; Zhuang, J.; Meijerink, A.; Jing, X.

    2013-01-01

    A new strategy based on the host composition design has been adopted to obtain efficient color-tunable emission from Ba2Ln0.97−zTbz(BO3)2Cl:0.03Eu (Ln = Y, Gd and Lu, z = 0–0.97) phosphors. This study reveals that the single-phase Ba2Ln1−zTbz(BO3)2Cl compounds can be applied to use allowed Eu2+

  12. Existence of Glass Ceiling in Public Universities of Lahore (Pakistan)

    OpenAIRE

    Asifa Ilyas

    2014-01-01

    Glass ceiling is a set of unseen factors which adversely affect females upward career growth and prevent them to get to top positions. This study is meant to explore existence of glass ceiling in public universities of Lahore (Pakistan); and factors responsible for creating this glass ceiling effect. The respondents of this study are females heading different departments in their respective universities. The results of this study show that different cultural and social, family and organizatio...

  13. 78 FR 16443 - Energy Efficiency Program for Consumer Products: Energy Conservation Standards for Ceiling Fans...

    Science.gov (United States)

    2013-03-15

    ... Standards for Ceiling Fans and Ceiling Fan Light Kits AGENCY: Office of Energy Efficiency and Renewable... consider amending the energy conservation standards for ceiling fans and ceiling fan light kits. DOE also....gov . Follow the instructions for submitting comments. Email: CeilingFan[email protected

  14. Approximated EU GHG inventory: Early estimates for 2011

    Energy Technology Data Exchange (ETDEWEB)

    Herold, A. [Oeko-Institut (Oeko), Freiburg (Germany); Fernandez, R. [European Environment Agency (EEA), Copenhagen (Denmark)

    2012-10-15

    The objective of this report is to provide an early estimate of greenhouse gas (GHG) emissions in the EU-15 and EU-27 for the year 2011. The official submission of 2011 data to the United Nations Framework Convention on Climate Change (UNFCCC) will occur in 2013. In recent years, the EEA and its European Topic Centre on Air Pollution and Climate Change Mitigation have developed a methodology to estimate GHG emissions using a bottom up approach - based on data or estimates for individual countries, sectors and gases - to derive EU GHG estimates in the preceding year (t-1). For transparency, this report shows the country-level GHG estimates from which the EU estimates have been derived. The 2011 estimates are based on the latest activity data available at country level and assume no change in emission factors or methodologies as compared to the official 2012 submissions to UNFCCC (which relate to emissions in 2010). Some Member States estimate and publish their own early estimates of GHG emissions for the preceding year. Where such estimates exist they are clearly referenced in this report in order to ensure complete transparency regarding the different GHG estimates available. Member State early estimates were also used for quality assurance and quality control of the EEA's GHG early estimates for 2011. Finally, the EEA has also used the early estimates of 2011 GHG emissions produced by EEA member countries to assess progress towards the Kyoto targets in its annual trends and projections report (due to be published alongside the present report). In that report, the EEA's early estimates for 2011 were only used for countries that lack their own early estimates to track progress towards national and EU targets. (LN)

  15. Approximated EU GHG inventory: Early estimates for 2010

    Energy Technology Data Exchange (ETDEWEB)

    Herold, A.; Busche, J.; Hermann, H.; Joerss, W.; Scheffler, M. (OEko-Institut, Freiburg (Germany))

    2011-10-15

    The objective of this report is to provide an early estimate of greenhouse gas (GHG) emissions in the EU-15 and EU-27 for the year 2010. The official submission of 2010 data to the United Nations Framework Convention on Climate Change (UNFCCC) will occur in 2012. In recent years, the EEA and its European Topic Centre on Air Pollution and Climate Change Mitigation have developed a methodology to estimate GHG emissions using a bottom up approach - based on data or estimates for individual countries, sectors and gases - to derive EU GHG estimates in the preceding year (t-1). For transparency, this report shows the country-level GHG estimates from which the EU estimates have been derived. The 2010 estimates are based on the latest activity data available at country level and assume no change in emission factors or methodologies as compared to the official 2011 submissions to UNFCCC (which re-late to emissions in 2009). Some Member States estimate and publish their own early estimates of GHG emissions for the preceding year. Where such estimates exist they are clearly referenced in this report in order to ensure complete transparency regarding the different GHG estimates available. Member State early estimates were also used for quality assurance and quality control of the EEA's GHG early estimates for 2010. Finally, EEA has also used the early estimates of 2010 GHG emissions produced by EEA member countries to assess progress towards the Kyoto targets in its annual trends and projections report (due to be published alongside the present report). In that report, the EEA's early estimates for 2010 were only used for countries that lack their own early estimates to track progress towards national and EU targets. (Author)

  16. Unilateral emission reductions of the EU and multilateral emission reductions of the developed countries. Assessing the impact on Finland with TIMES model

    International Nuclear Information System (INIS)

    Ekholm, T.; Lehtilae, A.; Savolainen, I.

    2008-03-01

    This report assesses the impact of the unilateral greenhouse gas emission reductions proposed by the EU on the structure of European and Finnish energy systems with TIMES models. The two models used are techno-economical energy system models including an extensive description of technologies on energy production and consumption. The models derive the sectoral energy demand from given economic projections and calculate the optimal way of satisfying the energy demand through market equilibrium. The basis for EU wide calculations was the Common POLES-IMAGE economic scenarios which project a GDP growth of 2.4 % p.a. until 2020. A sensitivity analysis was conducted with a lower economic growth projection. The results indicated that a reduction of 20 % compared to 1990 emission levels by 2020 would lead to most reductions being conducted at the electricity sector. The consumption of coal in electricity generation would decrease considerably. In the long term some of the natural gas based production would incorporate carbon capture and storage (CCS), and the use of wind power would grow substantially. The value of carbon would lie at levels around 20 to 30 euro/t CO 2 by 2020 were the reductions carried out without flexibility mechanisms. With a reduction target of -30 % by 2050, the value of carbon would rise to 40 . 50 euro/t CO 2 by 2050, and nearly to 100 euro/t CO 2 with a target of -60 % in 2050. The calculations on Finland were based on economic projections by the Ministry of Finance and the Government Institute of Economic Research. The scenarios asses the optimal way of reducing Finnish emissions with a range of prices for emission rights between 20 and 50 euro/t CO 2 . The sectors not included in the emission trading scheme were assumed to conduct reductions with costs up to the value of emission rights. The use of coal was reduced after 2010, accompanied by an increase in the use of natural gas. The utilization of bioenergy increases considerable in the total

  17. Green-emissive transparent BaSi 2O 5:Eu 2 + film phosphor on quartz glass created by a sputtering thermal diffusion process

    Science.gov (United States)

    Seo, K. I.; Park, J. H.; Kim, J. S.; Na, Y. H.; Choi, J. C.; Bae, J. S.

    2009-10-01

    Eu 2+-doped BaSi 2O 5 film phosphors on quartz substrates are fabricated by radio-frequency magnetron sputtering thermal diffusion. The BaSi 2O 5: Eu 2+ phosphor crystals have some preferred orientations that are lattice-spacing matched with the crystallized β- SiO 2 crystals, and they show pore and grain boundary-free morphology with a rod-like shape fused into the crystallized β- SiO 2 crystals. The BaSi 2O 5: Eu 2+ film phosphor has a high transparency, with a transmittance of about 30% in visible light. The BaSi 2O 5: Eu 2+ film phosphor shows 510 nm green emission from the f-d transition of the Eu 2+ ions, and in particular the best sample shows a green photoluminescence brightness of about 5% of a BaSi 2O 5: Eu 2+ powder phosphor screen. These excellences in optical properties can be explained by less optical scattering at pores or grain boundaries, and less reflection at the continuously index-changed interface.

  18. Tendances Carbone no. 84 'Climate and energy policies in the EU: a major role in reducing CO2 emissions from the energy and industry sectors'

    International Nuclear Information System (INIS)

    Alberola, Emilie; Gloaguen, Olivier

    2013-01-01

    Among the publications of CDC Climat Research, 'Tendances Carbone' bulletin specifically studies the developments of the European market for CO 2 allowances. This issue addresses the following points: This month, the European Environmental Agency revealed that the European Union had reduced emissions between 1990 and 2012 by approximately 18%, close to the 20% emissions reduction target by 2020. On May 15 2013, the European Commission had already announced that the verified CO 2 emissions generated by installations covered by the EU ETS amounted to 1,867 MtCO 2 in 2012, a 2% decline compared with 2011. In total, by excluding the aviation sector and on a like-for-like basis, the EU ETS' CO 2 emissions decreased by 12.3% between 2005 and 2012. Should we applaud this fall in CO 2 emissions? In other words, is this a structural decrease encouraged by climate and energy policies, or a circumstantial decrease triggered solely by the economic downturn?

  19. PROPERTIES OF Eu3+ LUMINESCENCE IN THE MONOCLINIC Ba2MgSi2O7

    Directory of Open Access Journals (Sweden)

    Shansh an Yao

    2011-09-01

    Full Text Available Red-emitting phosphors Ba2-xMgSi2O7: Eux3+ was prepared by combustion-assisted synthesis method and an efficient red emission under near-ultraviolet (UV was observed. The luminescence and crystallinity were investigated using luminescence spectrometry and X-ray diffractometer. The emission spectrum shows that the most intense peak is located at 614 nm, which corresponds to the 5D0 → 7F2 transitions of Eu3+. The phosphor has two main excitation peaks located at 394 and 465 nm, which match the emission of UV and blue light-emitting diodes, respectively. The effect of Eu3+ concentration on the emission spectrum of Ba2MgSi2O7:Eu3+ phosphor was studied. The results showed that the emission intensity increased with increasing Eu3+ concentration, and then decreased because of concentration quenching. The critical quenching concentration of Eu3+ in Ba2MgSi2O7: Eu3+ phosphor is about 0.05 mol. The mechanism of concentration quenching of Ba2MgSi2O7: Eu3+ luminescence is energy transfer between Eu3+ ions casued by the dipole-dipole interaction.

  20. Etude Climat no. 42 'Power sector in Phase 2 of the EU ETS: fewer CO2 emissions, but just as much coal'

    International Nuclear Information System (INIS)

    Berghmans, Nicolas; Alberola, Emilie

    2013-01-01

    Among the publications of CDC Climat Research, 'Climate Reports' offer in-depth analyses on a given subject. This issue addresses the following points: Since 2005, 1,453 power and combined heat and power (CHP) generation plants have participated in the European Union Emission Trading Scheme, or EU ETS, which requires them to comply with an annual CO 2 emission cap set by the European Commission. Thermal power plants that use coal (bituminous coal, lignite, and other kinds of coal) and natural gas as their primary fuel jointly account for 86% of the generation capacity included in the EU ETS. There are twice as many gas-fired power plants as coal-fired ones, with 671 gas-fired power plants compared with 352 coal-fired ones

  1. Preparation, photoluminescent properties and luminescent dynamics of BaAlF5:Eu2+ nanophosphors

    International Nuclear Information System (INIS)

    Zhang, Wei; Hua, Ruinian; Liu, Tianqing; Zhao, Jun; Na, Liyan; Chen, Baojiu

    2014-01-01

    Graphical abstract: Rice-shaped BaAlF 5 :Eu 2+ nanophosphors were synthesized via one-pot hydrothermal process. The as-prepared BaAlF 5 :Eu 2+ are composed of many particles with an average diameter of 40 nm. When excited at 260 nm, the sharp line emission located at 361 nm of Eu 2+ was observed. The optimum doping concentration of Eu 2+ was confirmed to be 5 mol%. The strong ultraviolet emission of Eu 2+ ions in BaAlF 5 :Eu 2+ nanoparticles suggests that these nanoparticles may have potential applications for sensing, solid-state lasers and spectrometer calibration. - Highlights: • BaAlF 5 :Eu 2+ nanophosphors were synthesized via a mild hydrothermal process. • The Van and Huang models were used to research the mechanism of concentration quenching. • The optimum doping concentration of Eu2+ was confirmed to be 5 mol%. - Abstract: Eu 2+ -doped BaAlF 5 nanophosphors were synthesized via a facile one-pot hydrothermal method. The final products were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and photoluminescence (PL) spectroscopy. XRD results showed that the prepared samples are single-phase. The FE-SEM and TEM images indicated that the prepared BaAlF 5 :Eu 2+ nanophosphors are composed of many rice-shaped particles with an average diameter of 40 nm. When excited at 260 nm, BaAlF 5 :Eu 2+ nanophosphors exhibit the sharp line emissions of Eu 2+ at room temperature. The optimum doping concentration of Eu 2+ was confirmed to be 5 mol%. The Van and Huang models were used to study the mechanism of concentration quenching and the electric dipole–dipole interaction between Eu 2+ can be deduced to be a dominant for quenching fluorescence in BaAlF 5 :Eu 2+ nanophosphors. The strong ultraviolet emission of Eu 2+ in BaAlF 5 :Eu 2+ nanophosphors suggests that these nanoparticles may have potential applications for sensing, spectrometer calibration and solid-state lasers

  2. An Economic Theory of the Glass Ceiling

    OpenAIRE

    Paul A. Grout; In-Uck Park; Silvia Sonderegger

    2007-01-01

    The glass ceiling is one of the most controversial and emotive aspects of employment in organisations. This paper provides a model of the glass ceiling that exhibits the following features that are frequently thought to characterise the problem: (i) there is a lower number of female employees in higher positions, (ii) women have to work harder than men to obtain equivalent jobs, (iii) women are then paid less than men when promoted, and (iv) some organisations are more female friendly than ot...

  3. Brilliant blue, green and orange-red emission band on Tm{sup 3+}-, Tb{sup 3+}- and Eu{sup 3+}-doped ZrO{sub 2} nanocrystals

    Energy Technology Data Exchange (ETDEWEB)

    Romero, V H; De la Rosa, E; Lopez-Luke, T [Centro de Investigaciones en Optica, A.P. 1-948, Leon Gto., 37160 (Mexico); Salas, P [Centro de Fisica Aplicada y TecnologIa Avanzada, Universidad Nacional Autonoma de Mexico, A.P. 1-1010, Queretaro, Qro. 76000 (Mexico); Angeles-Chavez, C, E-mail: elder@cio.m [Instituto Mexicano del Petroleo, Programa de IngenierIa Molecular, A.P. 11-848, Mexico, D.F. 07730 (Mexico)

    2010-11-24

    Tm{sup 3+}-, Tb{sup 3+}- and Eu{sup 3+}-doped ZrO{sub 2} nanocrystals were prepared by a facile precipitation method with a hydrothermal process. Structural characterization showed a crystallite size ranging from 30 to 40 nm, and monoclinic and tetragonal zirconia phases were observed depending on the dopant concentration. The monoclinic phase was dominant for 0.5 mol% of Tb{sup 3+} and Eu{sup 3+}, and the tetragonal phase was 100% stabilized for 2 mol% of Tm{sup 3+} and Tb{sup 3+}. The structure of emission bands associated with Eu{sup 3+} confirms the substitution of Zr{sup 4+} located at C{sub 1} and D{sub 2h} symmetry sites for the monoclinic and tetragonal phases. The emission of three primary colours, red, green and blue, was obtained from Eu{sup 3+}, Tb{sup 3+} and Tm{sup 3+}, respectively, which makes this nanophosphor an excellent candidate for use in photonics applications. The emitted signal was analysed as a function of ion concentration and the optimum concentration was determined.

  4. An acoustical research of the undulating wooden ceiling in the Vyborg Library

    DEFF Research Database (Denmark)

    Mortensen, Bo

    2004-01-01

    Much has been written about the Undulating Ceiling at the lecture hall of the Vyborg Library. Alvar Aalto himself claimed the ceiling to be "ninety-nine per cent acoustically perfect" and the sketches showing the acoustical considerations behind the ceiling-design is often reproduced. But how did...

  5. Coordination of the EU's emissions trading, energy taxation and subsidies for energy production. Interim Report by the Working Group

    International Nuclear Information System (INIS)

    2004-01-01

    The Working Group was to make preparations for the coordination of emissions trading in the European Union, energy taxation and energy production subsidies. It was supposed to issue an interim report on the role of energy taxation by 15 December 2003. In its interim report, the Working Group examined the present energy taxation scheme and the needs for its development upon the start-up of EU-wide emissions trading in 2005. The aim has been to recognise the immediate needs for amending energy taxation and energy tax subsidies in the near future while taking account of the outlines set out in the Government Programme. From the climate policy perspective, emissions trading is an efficient means of steering, because the commitment set for the emissions trading sector can be met by means of it. At the first stage, the EU's emissions trading will concern carbon dioxide emissions only, and in the future probably also other greenhouse gas emissions mentioned in the Kyoto Protocol. Its steering effect does not extend to other emissions, such as acidifying emissions. Other measures will be required for curbing them. Emissions trading is not a sufficient instrument for energy policy, although it partly directs development in a direction that is favourable for energy policy targets. On top of that, the most important steering mechanism of emissions trading, the price of an emission allowance, is beyond the reach of Finnish energy policy. It is determined on the EU-wide emission allowances market. The current energy taxation and energy tax subsidies safeguard the position of renewable energy sources in the circumstances of emissions trading. The competitiveness of domestic fuels, too, can be partly secured with current taxes. In the energy production of communities and industry, energy wood often replaces peat. i.e. two domestic and local fuels are competing against one another. In condensing power production peat is clearly losing more of its competitive edge the higher the

  6. ENERGY STAR Certified Ceiling Fans

    Data.gov (United States)

    U.S. Environmental Protection Agency — Certified models meet all ENERGY STAR requirements as listed in the Version 3.1 ENERGY STAR Program Requirements for Ceiling Fans that are effective as of April 1,...

  7. Rare earths (Ce, Eu, Tb) doped Y2Si2O7 phosphors for white LED

    International Nuclear Information System (INIS)

    Sokolnicki, Jerzy

    2013-01-01

    Nanocrystalline yttrium pyrosilicate Y 2 Si 2 O 7 (YPS) singly, doubly or triply doped with Ce 3+ , Eu 3+ , Tb 3+ was obtained by the reaction of nanostructured Y 2 O 3 :Ln 3+ and colloidal SiO 2 at high temperatures. X-ray diffraction analysis confirmed the formation of a single phase of α-YPS at 1200 °C. Two series of YPS samples doped with Eu 3+ or Eu 3+ /Tb 3+ were obtained by applying the reducing atmosphere (75%N 2 +25%H 2 ) at different temperatures. The luminescence and excitation spectra are reported. The singly Eu 3+ doped YPS emit from both Eu 3+ and Eu 2+ ions, with the spectral position and width of the Eu 2+ emission different in both series. The presence of Eu 2+ in the samples was confirmed by electron paramagnetic resonance (EPR) spectra. A broadband emission of Eu 2+ (380–650 nm), combined with the red emission of Eu 3+ is perceived by the naked eye as white light. Co-doping of YPS:Eu 3+ with Tb 3+ results in enhancement of the green component of the emission, and well-balanced white luminescence. The colour of this emission is tunable, and it is possible to get Commission International de I'Eclairage (CIE) chromaticity coordinates of (0.327, 0.327), colour-rendering index (CRI) of 85, and quantum efficiency (QE) of 71%. These phosphors are efficiently excited in the wavelength range of 300–420 nm, which perfectly matches a near UV-emitting InGaN chip. It was shown that for triply (Ce 3+ , Eu 3+ and Tb 3+ ) doped samples the three emissions from the particular activators can be generated using one excitation wavelength. The white light resulting from the superposition of the blue (Ce 3+ ), green (Tb 3+ ) and red (Eu 3+ ) emissions can be obtained by varying the concentration of the active ions and the treating atmosphere, i.e. reducing or oxidising. Eu 2+ was not detected in the triply doped samples, and hence line emissions mostly exhibit CRI values equal to or below 30. - Highlights: ► Nanocrystalline Y 2 Si 2 O 7 was obtained by the

  8. Facing the challenges of the Eu emissions trading scheme

    International Nuclear Information System (INIS)

    Bryers, S.

    2006-01-01

    Carbon Capital Markets, a specialist trader in the EU ETS has helped a number of cement and chalk producers in Europe manage their CO 2 (or EU Allowance (EUA)) position. From its experience with working with these companies, it recommends ways in which manufacturers can manage their CO 2 position more effectively. (author)

  9. Optical spectroscopy and optical waveguide fabrication in Eu{sup 3+} and Eu{sup 3+}/Tb{sup 3+} doped zinc–sodium–aluminosilicate glasses

    Energy Technology Data Exchange (ETDEWEB)

    Caldiño, U., E-mail: cald@xanum.uam.mx [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, P.O. Box 55-534, 09340 México D.F. (Mexico); Speghini, A. [Dipartimento di Biotecnologie, Università di Verona and INSTM, UdR Verona, Strada Le Grazie 15, I-37314 Verona (Italy); Istituto di Fisica Applicata Nello Carrara, C.N.R., Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze) (Italy); Berneschi, S. [Istituto di Fisica Applicata Nello Carrara, C.N.R., Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze) (Italy); Bettinelli, M. [Dipartimento di Biotecnologie, Università di Verona and INSTM, UdR Verona, Strada Le Grazie 15, I-37314 Verona (Italy); Brenci, M. [Istituto di Fisica Applicata Nello Carrara, C.N.R., Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze) (Italy); Pasquini, E. [Istituto di Fisica Applicata Nello Carrara, C.N.R., Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze) (Italy); Dipartimento di Fisica e Astronomia, Università di Firenze, Via Sansone 1, 50019 Sesto Fiorentino (Firenze) (Italy); Pelli, S. [Istituto di Fisica Applicata Nello Carrara, C.N.R., Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze) (Italy); Righini, G.C. [Istituto di Fisica Applicata Nello Carrara, C.N.R., Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze) (Italy); Museo Storico della Fisica e Centro Studi e Ricerche “Enrico Fermi”, Piazza del Viminale 2, 00184 Roma (Italy)

    2014-03-15

    Optical and spectroscopic properties of 2.0% Eu(PO{sub 3}){sub 3} singly doped and 5.0% Tb(PO{sub 3}){sub 3}–2.0% Eu(PO{sub 3}){sub 3} codoped zinc–sodium–aluminosilicate glasses were investigated. Reddish-orange light emission, with x=0.64 and y=0.36 CIE1931 chromaticity coordinates, is obtained in the europium singly doped glass excited at 393 nm. Such chromaticity coordinates are close to those (0.67,0.33) standard of the National Television System Committee for the red phosphor. When the sodium–zinc–aluminosilicate glass is co-doped with Tb{sup 3+} and Eu{sup 3+}, reddish-orange light emission, with (0.61,0.37) CIE1931 chromaticity coordinates, is obtained upon Tb{sup 3+} excitation at 344 nm. This reddish-orange luminescence is generated mainly by {sup 5}D{sub 0}→{sup 7}F{sub 1} and {sup 5}D{sub 0} →{sup 7}F{sub 2} emissions of Eu{sup 3+}, europium being sensitized by terbium through a non-radiative energy transfer. From an analysis of the Tb{sup 3+} emission decay curves it is inferred that the Tb{sup 3+}→Eu{sup 3+} energy transfer might take place between Tb{sup 3+} and Eu{sup 3+} clusters through a short-range interaction mechanism, so that an electric dipole–quadrupole interaction appears to be the most probable transfer mechanism. The efficiency of this energy transfer is about 62% upon excitation at 344 nm. In the singly doped and codoped glasses multimode optical waveguides were successfully produced by Ag{sup +}–Na{sup +} ion exchange, and they could be characterized at various wavelengths. -- Highlights: • Reddish-orange light emission can be generated from Tb{sup 3+} and Eu{sup 3+} codoped zinc–sodium–aluminosilicate glasses excited at 344 nm. • The Eu{sup 3+} is sensitized by Tb{sup 3+} through a non-radiative energy transfer. • Highly multimode waveguides can be fabricated by diluted silver–sodium exchange. • This type of AlGaN LEDs pumped glass phosphors might be useful for generation of reddish-orange light.

  10. Tunable blue-green emission and energy transfer properties in β-Ca3(PO4)2:Eu(2+), Tb(3+) phosphors with high quantum efficiencies for UV-LEDs.

    Science.gov (United States)

    Li, Kai; Zhang, Yang; Li, Xuejiao; Shang, Mengmeng; Lian, Hongzhou; Lin, Jun

    2015-03-14

    A series of Eu(2+) and Tb(3+) singly-doped and co-doped β-Ca3(PO4)2 phosphors have been synthesized via the high-temperature solid-state reaction method. Thermogravimetric (TG) analysis, fourier transform infrared (FT-IR) spectra, X-ray diffraction (XRD) patterns and Rietveld refinements, photoluminescence (PL) spectra including temperature-dependent PL and quantum efficiency, and fluorescence decay lifetimes have been used to characterise the as-prepared samples. Under UV excitation, β-Ca3(PO4)2:Eu(2+) presents a broad emission band centered at 415 nm, which can be decomposed into five symmetrical bands peaking at 390, 408, 421, 435 and 511 nm based on the substitution of five kinds of Ca(2+) sites by Eu(2+) ions. β-Ca3(PO4)2:Tb(3+) shows characteristic emission lines under Tb(3+) 4f-5d transition excitation around 223 nm. In β-Ca3(PO4)2:Eu(2+), Tb(3+) phosphors, similar excitation spectra monitored at 415 and 547 nm have been observed, which illustrates the possibility of energy transfer from Eu(2+) to Tb(3+) ions. The variations in the emission spectra and decay lifetimes further demonstrate the existence of energy transfer from Eu(2+) to Tb(3+) ions under UV excitation. The energy transfer mechanism has been confirmed to be dipole-quadrupole, which can be validated via the agreement of critical distances obtained from the concentration quenching (12.11 Å) and spectrum overlap methods (9.9-13.2 Å). The best quantum efficiency can reach 90% for the β-Ca3(PO4)2:0.01Eu(2+), 0.15Tb(3+) sample under 280 nm excitation. These results show that the developed phosphors may possess potential applications in UV-pumped white light-emitting diodes.

  11. Diffuse Ceiling Inlet Systems and the Room Air Distribution

    DEFF Research Database (Denmark)

    Nielsen, Peter V.; Jensen, Rasmus Lund; Rong, Li

    2010-01-01

    A diffuse ceiling inlet system is an air distribution system which is supplying the air through the whole ceiling. The system can remove a large heat load without creating draught in the room. The paper describes measurements in the case of both cooling and heating, and CFD predictions are given...

  12. Does the Glass Ceiling Exist? A Cross-National Perspective on

    OpenAIRE

    Gang, Ira N.; Landon-Lane, John S.; Yun, Myeong-Su

    2003-01-01

    We compare male and female upward labor income mobility in Germany and the United States using the GSOEP-PSID Cross National Equivalent File. Our main interest is to test whether a glass ceiling exists for women. The standard glass ceiling hypothesis highlights the belief that the playing field is level for women and men in the labor market up to a point, after which there is an effective limit on advancement for women. We examine the glass ceiling hypothesis by looking at the dynamics of the...

  13. Analysis of Rapidly Developing Low Cloud Ceilings in a Stable Environment

    Science.gov (United States)

    Bauman, William H., III; Barrett, Joe H., III; Case, Jonathan L.; Wheeler, Mark M.; Baggett, G. Wayne

    2006-01-01

    Forecasters at the Space Meteorology Group (SMG) issue 30 to 90 minute forecasts for low cloud ceilings at the Space Shuttle Landing Facility (TTS) to support Space Shuttle landings. Mission verification statistics have shown ceilings to be the number one forecast challenge for SMG. More specifically, forecasters at SMG are concerned with any rapidly developing clouds/ceilings below 8000 ft in a stable, capped thermodynamic environment. Therefore, the Applied Meteorology Unit (AMU) was tasked to examine archived events of rapid stable cloud formation resulting in ceilings below 8000 ft, and document the atmospheric regimes favoring this type of cloud development. The AMU examined the cool season months of November to March during the years of 1993-2003 for days that had low-level inversions and rapid, stable low cloud formation that resulted in ceilings violating the Space Shuttle Flight Rules. The AMU wrote and modified existing code to identify inversions from the morning (-10 UTC) Cape Canaveral, FL rawinsonde (XMR) during the cool season and output pertinent sounding information. They parsed all days with cloud ceilings below 8000 ft at TTS, forming a database of possible rapidly-developing low ceiling events. Days with precipitation or noticeable fog burn-off situations were excluded from the database. In the first phase of this work, only the daytime hours were examined for possible ceiling development events since low clouds are easier to diagnose with visible satellite imagery. Phase II of this work includes expanding the database to include nighttime cases which is underway as this abstract is being written. For the nighttime cases, the AMU will analyze both the 00 UTC soundings and the 10 UTC soundings to examine those data for the presence of a low-level inversion. The 00 UTC soundings will probably not have a surface-based inversion, but the presence of inversions or "neutral" layers aloft and below 8,000 ft will most likely help define the stable

  14. Reform of the EU's climate policy. Small step or big hit?; Reform der EU-Klimapolitik. Kleiner Schritt oder grosser Wurf?

    Energy Technology Data Exchange (ETDEWEB)

    Janssen, Matthias; Peichert, Patrick; Perner, Jens; Riechmann, Christoph [Frontier Economics Ltd., Koeln (Germany)

    2015-11-15

    Emissions trading listed as a flexible mechanism under the Kyoto Protocol is regarded as a market economy way in climate protection. Since 2005 the European Emissions Trading System (EU ETS) is the central climate policy instrument for reducing the emissions of greenhouse gases, in particular for carbon dioxide (CO{sub 2}). For years, however, the CO{sub 2} price is too low to direct the politically and socially targeted technical innovations in the electricity sector and the industry. The article analyses the temporary and structural causes of this problem, highlights the EU's reform efforts and points to areas of activity, the basis of which the EU ETS may act in the future as a central instrument for climate protection in the European Union. [German] Der im Kyoto-Protokoll als flexibler Mechanismus aufgefuehrte Emissionshandel gilt als marktwirtschaftlicher Weg in den Klimaschutz. Das Europaeische Emissionshandelssystem (EU ETS) ist seit 2005 das zentrale klimapolitische Instrument zur Senkung des Ausstosses von Treibhausgasen, insbesondere fuer Kohlenstoffdioxid (CO{sub 2}). Seit Jahren ist der CO{sub 2}-Preis jedoch zu gering, um die politisch und gesellschaftlich angestrebten technischen Innovationen im Stromsektor und der Industrie zu lenken. Der Artikel untersucht die temporaeren und strukturellen Ursachen dieses Problems, beleuchtet die Reformbestrebungen der EU und zeigt Handlungsfelder auf, anhand derer das EU ETS auch in Zukunft als zentrales Instrument fuer Klimaschutz in der Europaeischen Union fungieren kann.

  15. Evaluation of ceiling lifts: transfer time, patient comfort and staff perceptions.

    Science.gov (United States)

    Alamgir, Hasanat; Li, Olivia Wei; Yu, Shicheng; Gorman, Erin; Fast, Catherine; Kidd, Catherine

    2009-09-01

    Mechanical lifting devices have been developed to reduce healthcare worker injuries related to patient handling. The purpose of this study was to evaluate ceiling lifts in comparison to floor lifts based on transfer time, patient comfort and staff perceptions in three long-term care facilities with varying ceiling lift coverage. The time required to transfer or reposition patients along with patient comfort levels were recorded for 119 transfers. Transfers performed with ceiling lifts required on average less time (bed to chair transfers: 156.9 seconds for ceiling lift, 273.6 seconds for floor lift) and were found to be more comfortable for patients. In the three facilities, 143 healthcare workers were surveyed on their perceptions of patient handling tasks and equipment. For both transferring and repositioning tasks, staff preferred to use ceiling lifts and also found them to be less physically demanding. Further investigation is needed on repositioning tasks to ensure safe practice.

  16. Emissions of nitrogen oxides from road traffic - regulations, emissions and effects; Vagtrafikens utslaepp av kvaeveoxider - reglering, utslaepp och effekter

    Energy Technology Data Exchange (ETDEWEB)

    Sjoedin, Aake; Pihl-Karlsson, Gunilla; Johansson, Manne [Swedish Environmental Research Inst., Goeteborg (Sweden); Forsberg, Bertil [Umeaa Univ. (Sweden). Public Health and Clinical Medicine; Ahlvik, Peter [Ecotraffic ERD3 AB, Stockholm (Sweden); Erlandsson, Lennart [AVL MTC AB, Stockholm (Sweden)

    2004-10-01

    The report is a review that aims to improve the basis for additional measures against the road traffic emissions of, in particular, NO{sub x}. An important question in the context is whether health effects of NO{sub 2} should serve as a norm for the actions for emission reductions of NO{sub x}, or if the environmental effects of NO{sub x}-emissions in the form of acidification, eutrophication and ozone should play this role. WHO notes, in its latest review of health effect research, that one cannot demonstrate that NO{sub 2} alone has any direct effects in concentrations at the current whole-year mean norm (40 {mu}g/m{sup 3}). Such health effects that has been demonstrated in epidemiologic studies at these concentrations are caused by other traffic related emissions (e. g. particles) for which NO{sub 2} constitutes a good indicator. WHO indicates the need for additional sharpening of the norms for ozone and particles. In this context, it is important to note that emissions of NO{sub x} on a regional scale contributes to formation of ozone as well as particles. Therefore there exist reasons to decrease the emissions of NO{sub x} in order to reach future recommended values for ozone and particles emissions. In the evaluations that will be done during 2004-2005 of the so called Goeteborg protocol, the EU's Ceiling Directives and the CAFE-programme, it is expected that new emissions objective for NO{sub x} will be suggested for 2015-2020, to cope with health and environment objectives in Europe. The report shows that that development that currently happens within the vehicle industry, for engines and exhaust emission control system are pursued to meet future exhaust requirement in the USA gives good conditions for the road traffic sector to contribute to that these objectives will reached.

  17. Non-adiabatic description of proton emission from the odd-odd nucleus 130Eu

    Directory of Open Access Journals (Sweden)

    Patial Monika

    2014-03-01

    Full Text Available We discuss the non-adiabatic quasiparticle approach for calculating the rotational spectra and decay width of odd-odd proton emitters. The Coriolis effects are incorporated in both the parent and daughter wave functions. Results for the two probable ground states (1+ and 2+ of the proton emitter 130Eu are discussed. With our calculations, we confirm the proton emitting state to be the Iπ = 1+ state, irrespective of the strength of the Coriolis interaction. This study provides us with an opportunity to look into the details of wave functions of deformed odd-odd nuclei to which the proton emission halflives are quite sensitive.

  18. Glass ceilings of professionalisation.

    Science.gov (United States)

    Stott, Dawn L

    2016-04-01

    The term glass ceiling is a political term often used to describe an unbreakable barrier that isnot visible with the human eye, but it keeps minorities from rising up i.e. it is a barrier to minoritygroups, in the past (and sometimes still) for women, that stops them from achieving theirtrue potential.

  19. Perceptions of the Glass Ceiling Effect in Community Colleges

    Science.gov (United States)

    Myers, Cheryl E.

    2010-01-01

    The purpose of this study was to determine the existence of a glass ceiling effect within community colleges by examining faculty, staff and administrator's perceptions of a glass ceiling as it relates to the advancement of women at their institutions. This was done by using a cross-sectional survey administered electronically to faculty, staff…

  20. Glass Ceiling in Academic Administration in Turkey: 1990s versus 2000s

    Science.gov (United States)

    Gunluk-Senesen, Gulay

    2009-01-01

    This paper assesses the glass ceiling for academics in the Turkish universities with reference to top administration positions: rectors and deans. Glass ceiling indicators show that the glass ceiling thickened from the 1990s to late 2000s. The findings are discussed against the background of the transformation in the Turkish universities in the…

  1. EU's CO2 trade a high risk project

    International Nuclear Information System (INIS)

    Wellander, Dag

    2003-01-01

    The uncertainty about the planned CO 2 trade of the European Union (EU) is very great. For the possible buyers in this politically created market the risks may be great and difficult to assess. The most effective way of forcing a reduction of emissions is trading emission licences. But this requires taking a stand on issues of very unpleasant nature. And the Kyoto protocol evades these questions, it is a thin document right from the beginning. Trade in emission licences is one of the three so-called flexible mechanisms of the Kyoto agreement. The second mechanism is joint implementation in which one industrialized country carries out emission reduction actions in another industrialized country. The third is the mechanism of clean development, in which one industrialized country takes remedial actions in a developing country. It is unclear how these mechanisms are to act in accordance with each other, both in the Kyoto Protocol and on the level of the EU. The biggest and most fundamental uncertainty, both on the EU and global levels, relates to the fact that the partners have not decided how to define the right of ownership of emissions of a certain size

  2. Policy options to improve the effectiveness of the EU emissions trading system: A multi-criteria analysis

    International Nuclear Information System (INIS)

    Clò, Stefano; Battles, Susan; Zoppoli, Pietro

    2013-01-01

    This paper considers several policy options which have been proposed to improve the functioning of the ETS. These options require an intervention either on the ETS cap (−30% target, set-aside, carbon central bank, long-term target) or on the carbon price (European and national price floor). We analyse the impact of each policy on the ETS carbon price and emissions. A multi-criteria evaluation method is applied to compare the policy options against a plurality of environmental, economic and procedural criteria. We find that the final ranking depends on the goals to be achieved, i.e., the relative weights attributed to the criteria. When policymakers want mainly to support the carbon price both in the short and long-run, while improving ETS flexibility and harmonization, the CCB and the EU price floor are, respectively ranked as first and second-best options. As the preference for environmental and implementation goals gradually increases, the position of the EU price floor and CCB options tend to invert. The −30% target should be adopted when reducing emissions is the priority goal, while a national price floor is the worst option, in this case. Nevertheless, self-interested States looking for a relatively quick, feasible solution, may find it optimal. - Highlights: ► A multi-criteria analysis is adopted to compare policy options to improve the ETS effectiveness. ► An ETS cap reversible adjustment by a carbon central bank is the first-best option. ► The establishment of a EU-wide price floor would represent a second-best solution. ► A national price floor is the worst option but self-interest states may find it optimal. ► A post-2020 target is not a mutually exclusive option and should be set

  3. Possibility of RGB emission by Eu{sup 2+} ion doped M{sup II}M{sup III}M{sup VI} phosphors for color inorganic electro- luminescent displays

    Energy Technology Data Exchange (ETDEWEB)

    Jabbarov, R B; Tagiev, B G; Tagiev, O B; Musaeva, N N [Inst. of Physics Azerbaijan National Academy of Sciences, Baku (Azerbaijan); Benalloul, P; Barthou, C [Univ. P. et. M. Curie, Paris (France)

    2004-07-01

    Full text: Eu{sup 2+} ion give broad-band emission due to f-d transitions. The 5d orbital are not shelled from the host lattice by any occupied orbital. Therefore the wavelength positions of the emission bands depend on host and change from hear UV to red. With increasing crystal field strength, the emission bands shift to longer wavelength. The broad band absorption and luminescence of Eu{sup 2+} is parity-and spin-allowed and lifetime is sub-microseconds. In resent years, many efforts have been devoted to luminescence studies of thio gallates and thio-aluminates doped with rare-earth ions because of their chemical stability in ambient environments. In ternary compounds both the ligand field at the divalent cation site and the nephelauxetic effect are reduced by the presence of trivalent or tetravalent ions. This effect is more pronounced with Al than with Ga. In a same family of compounds, the emission band generally shifts to shorter wavelengths with increasing M{sup II}/M{sup IV} or M{sup VI}/M{sup III} ratio. In this paper we revisited the luminescence of the phosphors CaGa{sub 2}S{sub 4}, BaGa{sub 2}S{sub 4}, BaAl{sub 2}S{sub 4} activated by Eu{sup 2+} ion. Influence of temperature and Eu{sup 2+} concentration on the luminescence characteristics of these phosphors are studied. These dates will be useful to evaluate the quality oi the powder or thin films prepared for devices.

  4. New greenish-yellow and yellowish-green emitting glass phosphors: Tb{sup 3+}/Eu{sup 3+} and Ce{sup 3+}/Tb{sup 3+}/Eu{sup 3+} in zinc phosphate glasses

    Energy Technology Data Exchange (ETDEWEB)

    Caldino, U., E-mail: cald@xanum.uam.mx [Departamento de Fisica, Universidad Autonoma Metropolitana-Iztapalapa, P.O. Box 55-534, 09340 Mexico D.F. (Mexico); Alvarez, E. [Departamento de Fisica, Universidad de Sonora (UNISON), Boulevard Luis Encinas y Rosales s/n, Hermosillo, Sonora 83000, Mexico (Mexico); Speghini, A. [Dipartimento di Biotecnologie, Universita di Verona, and INSTM, UdR Verona, Strada Le Grazie 15, I-37314 Verona (Italy); IFAC CNR, Nello Carrara Institute of Applied Physics, MDF Lab, I-50019 Sesto Fiorentino, FI (Italy); Bettinelli, M. [Dipartimento di Biotecnologie, Universita di Verona, and INSTM, UdR Verona, Strada Le Grazie 15, I-37314 Verona (Italy)

    2013-03-15

    A spectroscopic investigation of zinc phosphate glasses activated with Eu{sup 3+}, Tb{sup 3+}/Eu{sup 3+} and Ce{sup 3+}/Tb{sup 3+}/Eu{sup 3+} ions is performed through photoluminescence spectra and decay time measurements. Greenish-yellow light emission, with x=0.42 and y=0.50 CIE1931 chromaticity coordinates, is obtained in the 5.0% Tb(PO{sub 3}){sub 3}-2.0% Eu(PO{sub 3}){sub 3} codoped zinc phosphate glass upon Tb{sup 3+} excitation at 340 nm. Such greenish-yellow luminescence is generated mainly by the {sup 5}D{sub 4}{yields}{sup 7}F{sub 6,5} and {sup 5}D{sub 0}{yields}{sup 7}F{sub 1,2} emissions of Tb{sup 3+} and Eu{sup 3+}, respectively, europium being sensitized by terbium through a non-radiative energy transfer. By codoping with 0.1 Ce(PO{sub 3}){sub 3} in addition to Tb{sup 3+}/Eu{sup 3+} yellowish-green light emission with CIE1931 chromaticity coordinates, x=0.33 and y=0.48, is achieved through non-radiative energy transfer from Ce{sup 3+} to Tb{sup 3+} and from Ce{sup 3+} via Tb{sup 3+} to Eu{sup 3+} upon 280 nm excitation (peak emission wavelength of AlGaN-based LEDs). - Highlights: Black-Right-Pointing-Pointer Zn(PO{sub 3}){sub 2} glasses are optically activated with Tb{sup 3+}/Eu{sup 3+} (ZPO5Tb2Eu) and Ce{sup 3+}/Eu{sup 3+}/Tb{sup 3+} (ZPOCe5Tb2Eu). Black-Right-Pointing-Pointer Non-radiative energy transfer Tb{sup 3+}{yields}Eu{sup 3+} takes place in ZPO5Tb2Eu. Black-Right-Pointing-Pointer Greenish-yellow light is generated by ZPO5Tb2Eu pumped with 340 nm-UV light. Black-Right-Pointing-Pointer Non-radiative energy transfer Ce{sup 3+}{yields}Tb{sup 3+} and Ce{sup 3+}{yields}Eu{sup 3+} via Tb{sup 3+} takes place in ZPOCe5Tb2Eu. Black-Right-Pointing-Pointer Yellowish-green light is generated by ZPOCe5Tb2Eu pumped with 280 nm-UV light (AlGaN-LEDs).

  5. The innovation impact of EU emission trading. Findings of company case studies in the German power sector

    Energy Technology Data Exchange (ETDEWEB)

    Rogge, Karoline S. [Fraunhofer-Institut fuer Systemtechnik und Innovationsforschung (ISI), Karlsruhe (Germany); Swiss Federal Inst. of Technology Zurich (ETH Zurich) (Switzerland). Dept. of Management, Technology, and Economics; Schneider, Malte; Hoffmann, Volker H. [Swiss Federal Inst. of Technology Zurich (ETH Zurich) (Switzerland). Dept. of Management, Technology, and Economics

    2010-05-01

    This paper provides a comprehensive analysis of how the European Emission Trading System (EU ETS) as the core climate policy instrument of the European Union has impacted innovation. Towards this end, we investigate the impact of the EU ETS on research, development, and demonstration (RD and D), adoption, and organizational change. In doing so, we pay particular attention to the rela-tive influences of context factors (policy mix, market factors, public acceptance) as well as firm characteristics (value chain position, technology portfolio, size, vision). Empirically, our analysis is based on multiple case studies with 19 power generators, technology providers, and project developers in the German power sector which we conducted from June 2008 until June 2009. We find that the innovation impact of the EU ETS has remained limited so far because of the scheme's initial lack in stringency and predictability and the relatively greater importance of context factors. Additionally, the impact varies tremendously across technologies, firms, and innovation dimensions, and is most pronounced for RD and D on carbon capture technologies and corporate procedural change. Our analysis suggests that the EU ETS by itself may not provide sufficient incentives for fundamental changes in corporate climate innovation activities at a level adequate for reaching political long-term targets. Based on the study's findings, we derive a set of policy and research recommendations. (orig.)

  6. The initial impact of EU ETS verification events on stock prices

    International Nuclear Information System (INIS)

    Brouwers, Roel; Schoubben, Frederiek; Van Hulle, Cynthia; Van Uytbergen, Steve

    2016-01-01

    This paper studies the impact of verified emissions publications in the European Emissions Trading Scheme (EU ETS) on the market value of participating companies. Using event study methodology on a unique sample of 368 listed companies, we show that verified emissions only resulted in statistically significant market responses when the carbon price was high and allowance scarcity was anticipated. The cross-section analysis of abnormal returns surrounding the publication of verified emissions shows that share prices decrease when actual emissions relative to allocated emissions increase. This negative relationship between allocation shortfalls and firm value is only significant for firms that are either carbon-intensive, compared to sector peers, or are less likely to pass through carbon-related costs in their product prices. The results suggest that although the EU ETS has been deemed unsuccessful so far due to over-allocation and low carbon price, shareholders initially perceived allowance holdings as value relevant. Our results highlight that a significant carbon market price and addressing pass-through costing are essential for successful future reforms of the EU ETS and other analogous carbon cap-and-trade systems implemented or planned worldwide. - Highlights: •We study the impact of EU ETS verified emissions disclosure on firms' market value. •Disclosure is relevant if carbon price is high and permits scarcity is anticipated. •We find a negative relationship between allocation shortfalls and firm value. •Stronger relationship for carbon – intensive and no cost pass-through firms. •High carbon price and addressing cost pass-through are crucial for EU ETS reforms.

  7. Why Does Emissions Trading under the EU ETS Not Affect Firms' Competitiveness? Empirical Findings from the Literature

    OpenAIRE

    Joltreau, Eugénie; Sommerfeld, Katrin

    2017-01-01

    Environmental policies may have important consequences for firms’ competitiveness or profitability. However, the empirical literature shows that hardly any statistically significant effects on firms can be detected for the European Union Emissions Trading Scheme (EU ETS). On the basis of existing literature, we focus on potential explanations for why the empirical literature finds hardly any significant competitiveness effects on firms, least not during the first two phases of the scheme (...

  8. Online Determination of Sm, Eu and Yb in Environmental Samples by Inductively Coupled Plasma – Optical Emission Spectrometry

    Directory of Open Access Journals (Sweden)

    J. Dilip Kumar

    2007-01-01

    Full Text Available A procedure was developed for the determination of Sm, Eu and Yb in water samples by inductively coupled plasma-optical emission spectrometry (ICP-OES after preconcentration on synthesized 5-(4-pyridyl azo-8-quinolinol supported by Borassus flabellifer inflorescence (BFI. The sorbed element was subsequently eluted with 0.4 M HNO3 and the acid eluates were analyzed by ICP-OES. Under the optimal conditions, Sm, Eu and Yb in aqueous samples were concentrated 100-fold. Recoveries were obtained by the proposed method in the range of 98.6 -99.8%. This method was also applied for the analysis of spiked and natural water samples. The results provide strong evidence to support the hypothesis of an adsorption mechanism.

  9. Noticeable red emission and Raman active modes in nanoscale gadolinium oxyfluoride (Gd4O3F6) systems with Eu3+ inclusion

    International Nuclear Information System (INIS)

    Hazarika, Samiran; Mohanta, Dambarudhar

    2017-01-01

    Eu 3+ doped gadolinium oxyfluoride (Gd 4 O 3 F 6 , GOF) nanoscale systems have been synthesized following a modified Pechini method. While exhibiting a tetragonal crystal structure, the GOF nanosystem gave an average crystallite size (d) of ∝21-26 nm. The Lotgering factor (L F ), which is a measure of orientation of crystallites along the preferred direction was found to vary between 0.22 and 0.48. In the photoluminescence spectra, ∝595 and ∝613 nm peaks were identified as magnetically driven ( 5 D 0 → 7 F 1 ) and electrically driven ( 5 D 0 → 7 F 2 ) transitions with latter (red emission) being strongly manifested with Eu 3+ doping concentration and intrinsic defects. Moreover, several Raman active modes have been probed in the Raman spectra with low frequency peaks (<300 cm -1 ) and moderate frequency peaks (∝481 and 567 cm -1 ) assigned to observable vibration of heavy atom Gd-Gd pairs and Gd-O groups, respectively. Apart from manifestation of phononic features, inclusion of Eu 3+ in the host lattice would bring new insight on improving the red emission response prior to concentration quenching. (orig.)

  10. Solar passive ceiling system. Final report. [Passive solar heating system with venetian blind reflectors and latent heat storage in ceiling

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, A.R.

    1980-01-01

    The construction of a 1200 square foot building, with full basement, built to be used as a branch library in a rural area is described. The primary heating source is a passive solar system consisting of a south facing window system. The system consists of: a set of windows located in the south facing wall only, composed of double glazed units; a set of reflectors mounted in each window which reflects sunlight up to the ceiling (the reflectors are similar to venetian blinds); a storage area in the ceiling which absorbs the heat from the reflected sunlight and stores it in foil salt pouches laid in the ceiling; and an automated curtain which automatically covers and uncovers the south facing window system. The system is totally passive and uses no blowers, pumps or other active types of heat distribution equipment. The building contains a basement which is normally not heated, and the north facing wall is bermed four feet high around the north side.

  11. Study on Laws, Regulations and Standards on Energy Efficiency, Energy Conserving and Emission Reduction of Industrial Boilers in EU

    Science.gov (United States)

    Liu, Ren; Zhao, Yuejin; Chen, Haihong; Liang, Xiuying; Yang, Ming

    2017-12-01

    Industrial boilers are widely applied in such fields as factory power, building heating, and people’s lives; China is the world’s largest producer and user of industrial boilers, with very high annual energy consumption; clear requirements have been put forward by China on the energy efficiency since the “11th Five-year Plan” with the hope to save energy and reduce emission by means of energy efficiency standards and regulations on the supervision and control of various special equipment. So far, the energy efficiency of industrial boilers in China has been improved significantly but there is still a gap with the EU states. This paper analyzes the policies of energy efficiency, implementation models and methods of supervision and implementation at the EU level from laws, regulations, directives as well as standards; the paper also puts forward suggestions of energy conserving and emission reduction on the improvement of energy conserving capacity of industrial boilers in China through studying the legislations and measures of the developed countries in energy conserving of boilers.

  12. EU policy objectives and energy investment decisions

    OpenAIRE

    Alario, Juan

    2007-01-01

    EU energy policies have changed focus in the last few years with a view to substantially reducing energy import dependency and greenhouse gas emissions. The EU Commission has played a leading role in defining the new orientations. The implementation of the EU policy objectives approved by the Council of March 2007 will require a substantial expansion of energy investments. However, the degree of uncertainty affecting investment decisions remains high, notably in relation to the pricing of CO2...

  13. Anthropogenic Nitrogen and Phosphorus Emissions and Related Grey Water Footprints Caused by EU-27′s Crop Production and Consumption

    Directory of Open Access Journals (Sweden)

    Mesfin M. Mekonnen

    2016-01-01

    Full Text Available Water is a prerequisite for life on our planet. Due to climate change and pollution, water availability for agricultural production, industry and households is increasingly put at risk. With agriculture being the largest water user as well as polluter worldwide, we estimate anthropogenic nitrogen and phosphorus emissions to fresh water related to global crop production at a spatial resolution level of 5 by 5 arc min and calculate the grey water footprints (GWF related to EU-27′s crop production. A multiregional input-output model is used to trace the the GWF embodied in the final consumption of crop products by the EU-27. The total GWF related to crop production in the EU-27 in 2007 was 1 × 1012 m3/year. Spain contributed about 40% to this total. Production of cereals (wheat, rice and other cereals take the largest share, accounting for 30% of the GWF, followed by fruits (17%, vegetables (14%, and oil crops (13%. The total agricultural GWF of the EU-27 related to crop consumption was 1830 billion m3/year, which is 3700 m3/year per capita on average. Overall, the EU-27 was able to externalize about 41% of the GWF to the rest of the world through imports of crop products.

  14. Multiprocessor Priority Ceiling Emulation for Safety-Critical Java

    DEFF Research Database (Denmark)

    Strøm, Torur Biskopstø; Schoeberl, Martin

    2015-01-01

    Priority ceiling emulation has preferable properties on uniprocessor systems, such as avoiding priority inversion and being deadlock free. This has made it a popular locking protocol. According to the safety-critical Java specication, priority ceiling emulation is a requirement for implementations....... However, implementing the protocol for multiprocessor systemsis more complex so implementations might perform worse than non-preemptive implementations. In this paper we compare two multiprocessor lock implementations with hardware support for the Java optimized processor: non-preemptive locking...

  15. How to design greenhouse gas trading in the EU?

    DEFF Research Database (Denmark)

    Svendsen, Gert Tinggaard; Vesterdal, Morten

    2001-01-01

    A new and remarkable Green Paper about how to trade Greenhouse gases (GHG) in the EU has recently been published by the Commission of the European Union. This to achieve the stated 8% reduction target level. The Green Paper raises ten questions about how greenhouse gas permit trading should...... be designed in the EU before year 2005. These ten questions can be compressed into four main issues, namely target group, allocation of emission allowances, how to mix emission trading with other instruments and fourth enforcement. In the literature, there is a strong need to guide decision...... concerning the future design of GHG permit trading in the EU....

  16. How to Design Greenhouse Gas Trading in the EU?

    DEFF Research Database (Denmark)

    Svendsen, Gert Tinggaard; Vesterdal, Morten

    2003-01-01

    A new and remarkable Green Paper about how to trade Greenhouse gases (GHG) in the EU has recently been published by the Commission of the European Union. This to achieve the stated 8% reduction target level. The Green Paper raises ten questions about how greenhouse gas permit trading should...... be designed in the EU before year 2005. These ten questions can be compressed into four main issues, namely target group, allocation of emission allowances, how to mix emission trading with other instruments and fourth enforcement. In the literature, there is a strong need to guide decision...... concerning the future design of GHG permit trading in the EU. Udgivelsesdato: NOV...

  17. Performance analysis of a new design of office diffuse ceiling ventilation system

    DEFF Research Database (Denmark)

    Fan, Jianhua; Hviid, Christian Anker; Yang, Honglu

    2013-01-01

    This paper aims to document and analyse performance of a new design of diffuse ceiling ventilation system in a typical office room. A full scale measurement is carried out in a climate chamber with an office setup at the Technical University of Denmark. Indoor air temperatures, air speeds, wall...... surface temperatures, pressure loss of the ceiling and ventilation effectiveness are measured for an air change rate of 3.5 h-1 and 5.1 h -1 respectively. A computational fluid dynamics model of the office with the diffuse ceiling ventilation system is built and validated by the full scale measurement....... The measurements of pressure loss across the ceiling show a low pressure drop between the plenum and the occupied zone. Ventilation effectiveness is measured to be close to 1 on average under the tested conditions. It is shown that the diffuse ceiling ventilation system is able to remove indoor pollutant...

  18. Luminescence and energy transfer of Sm3+ and Eu3+ in Ca2PO4Cl

    International Nuclear Information System (INIS)

    Wang, Zhijun; Li, Panlai; Yang, Zhiping; Guo, Qinglin

    2014-01-01

    Sm 3+ , Eu 3+ , and Sm 3+ –Eu 3+ doped Ca 2 PO 4 Cl phosphors are synthesized by a solid-state method. Ca 2 PO 4 Cl:Sm 3+ can produce red emission under the 400 nm radiation excitation, and the emission peak is located at 601 nm, which is assigned to the 4 G 5/2 → 6 H 7/2 transition of Sm 3+ . Ca 2 PO 4 Cl:Eu 3+ can create red emission under the 392 nm radiation excitation, and the strongest peak is located at 620 nm, which is attributed to the 5 D 0 → 7 F 2 transition of Eu 3+ . The energy transfer from Sm 3+ to Eu 3+ in Ca 2 PO 4 Cl has been validated and the critical distance (R c ) of Sm 3+ to Eu 3+ in Ca 2 PO 4 Cl is calculated to be 1.14 nm. With increasing Eu 3+ doping concentration, the energy transfer efficiency (Sm 3+ →Eu 3+ ) gradually increases to 53.7%. The luminescence property of Ca 2 PO 4 Cl:Sm 3+ , Eu 3+ can be tuned by properly tuning the relative ratio of Sm 3+ –Eu 3+ , and the emission intensity of Ca 2 PO 4 Cl:Eu 3+ can be greatly enhanced by codoped Sm 3+ . - Highlights: • Ca 2 PO 4 Cl:Sm 3+ , Eu 3+ can produce red emission under the 400 nm radiation excitation. • The energy transfer from Sm 3+ to Eu 3+ in Ca 2 PO 4 Cl has been validated. • The critical distance of Sm 3+ to Eu 3+ in Ca 2 PO 4 Cl is calculated to be 1.14 nm

  19. Air Distribution in Rooms with Ceiling-mounted Obstacles and Three-Dimensional Isothermal Flow

    DEFF Research Database (Denmark)

    Nielsen, Peter V.; Evensen, Louis; Grabau, Peter

    The air supply openings in ventilated rooms are often placed close to the ceiling. A recirculating flow is generated in the room, and the region between the ceiling and the occupied zone serves as an entrainment and velocity decay area for the wall jets. Ceiling-mounted obstacles may disturb...

  20. Best Available Techniques (BAT) Reference Document for the Production of Wood-based Panels: Industrial Emissions Directive 2010/75/EU (Integrated Pollution Prevention and Control)

    OpenAIRE

    STUBDRUP KAREN KRISTINE RAUNKJAER; KARLIS PANAGIOTIS; ROUDIER Serge; DELGADO SANCHO Luis

    2016-01-01

    The BAT reference document (BREF) entitled ‘Production of Wood-based Panels' forms part of a series presenting the results of an exchange of information between EU Member States, the industries concerned, non-governmental organisations promoting environmental protection, and the Commission, to draw up, review and, where necessary, update BAT reference documents as required by Article 13(1) of the Directive 2010/75/EU on industrial emissions. This document is published by the European Commissi...

  1. Combustion synthesis of Eu 2+ and Dy 3+ activated Sr 3 (VO 4 ) 2 ...

    Indian Academy of Sciences (India)

    2:Eu,Dy phosphors are presented in this paper. PL emission of Sr3(VO4)2:Eu phosphor shows green broad emission band centring at 511 nm and a red sharp band at 614 nm by excitation wavelength of 342 nm. The PL emission spectrum of ...

  2. Thermoluminescence of KI:Eu2+ Stimulated by Ultraviolet Irradiation at Different Temperatures

    International Nuclear Information System (INIS)

    Aguirre de Carcer, I.; Jaque, F.; Townsend, P.D.

    1999-01-01

    The thermoluminescence (TL) of KI:Eu 2+ after ultraviolet (254 nm) irradiation at different temperatures from -40 deg. C to +40 deg. C has been studied. Two main glow peaks and some minor features have been identified on the thermoluminescence glow curves. Irradiating at low temperature gives a strong peak at γ5 deg. C and a less pronounced one at 230 deg. C. The TL glow peak emission spectra were analysed as consisting of the addition of several Gaussian shaped emission bands. The position of the Gaussian peaks, and their widths, are coincident with divalent europium emission at different sites of the KI:Eu 2+ system. A new emission band centred at 3.05 eV, 0.16 eV FWHM for Eu 2+ has been observed from the TL emission spectra. The changes in the spectral distribution of the TL emission with irradiation temperature are discussed. (author)

  3. Ceiling art in a radiation therapy department: its effect on patient treatment experience

    International Nuclear Information System (INIS)

    Bonett, Jotham

    2015-01-01

    A new initiative has been implemented at the Sunshine Hospital Radiation Therapy Centre, to provide a calming and comforting environment for patients attending radiation therapy treatment. As part of this initiative, the department's computed tomography (CT) room and radiation therapy bunkers were designed to incorporate ceiling art that replicates a number of different visual scenes. The study was undertaken to determine if ceiling art in the radiation therapy treatment CT and treatment bunkers had an effect on a patient's experience during treatment at the department. Additionally, the study aimed to identify which of the visuals in the ceiling art were most preferred by patients. Patients were requested to complete a 12-question survey. The survey solicited a patient's opinion/perception on the unit's unique ceiling display with emphasis on aesthetic appeal, patient treatment experience and the patient's engagement due to the ceiling display. The responses were dichotomised to ‘positive’ or ‘negative’. Every sixth patient who completed the survey was invited to have a general face-to-face discussion to provide further information about their thoughts on the displays. The results demonstrate that the ceiling artwork solicited a positive reaction in 89.8% of patients surveyed. This score indicates that ceiling artwork contributed positively to patients’ experiences during radiation therapy treatment. The study suggests that ceiling artwork in the department has a positive effect on patient experience during their radiation therapy treatment at the department

  4. Ceiling art in a radiation therapy department: its effect on patient treatment experience

    Energy Technology Data Exchange (ETDEWEB)

    Bonett, Jotham [Sunshine Hospital Radiation Therapy Centre, Melbourne, Vic. (Australia)

    2015-09-15

    A new initiative has been implemented at the Sunshine Hospital Radiation Therapy Centre, to provide a calming and comforting environment for patients attending radiation therapy treatment. As part of this initiative, the department's computed tomography (CT) room and radiation therapy bunkers were designed to incorporate ceiling art that replicates a number of different visual scenes. The study was undertaken to determine if ceiling art in the radiation therapy treatment CT and treatment bunkers had an effect on a patient's experience during treatment at the department. Additionally, the study aimed to identify which of the visuals in the ceiling art were most preferred by patients. Patients were requested to complete a 12-question survey. The survey solicited a patient's opinion/perception on the unit's unique ceiling display with emphasis on aesthetic appeal, patient treatment experience and the patient's engagement due to the ceiling display. The responses were dichotomised to ‘positive’ or ‘negative’. Every sixth patient who completed the survey was invited to have a general face-to-face discussion to provide further information about their thoughts on the displays. The results demonstrate that the ceiling artwork solicited a positive reaction in 89.8% of patients surveyed. This score indicates that ceiling artwork contributed positively to patients’ experiences during radiation therapy treatment. The study suggests that ceiling artwork in the department has a positive effect on patient experience during their radiation therapy treatment at the department.

  5. Experimental study of perforated suspended ceilings as diffuse ventilation air inlets

    DEFF Research Database (Denmark)

    Hviid, Christian Anker; Svendsen, Svend

    2013-01-01

    An experimental study is reported in this paper for a diffuse ceiling ventilation concept. The analyses were carried out with two different porous surfaces mounted in a suspended ceiling: perforated tiles of aluminium and of gypsum. Ventilation air was supplied above the suspended ceiling effecti...... surface which increases the potential and applicability of the concept. Risk of thermal discomfort was not disclosed but the study did show evidence of large fluctuating air movements which could stem from transient behaviour creating sensations of draught to the occupants....

  6. The impact of the EU ETS on prices, profits and emissions in the power sector. Simulation results with the COMPETES model

    International Nuclear Information System (INIS)

    Lise, W.; Sijm, J.; Hobbs, B.F.

    2009-06-01

    This paper analyses the impact of the EU Emissions Trading Scheme (ETS) on electricity wholesale in 20 European countries. The analyses show that the costs of (freely allocated) CO2 emission allowances are nearly fully passed through to power prices, which also depend on the structure of the power market, i.e., the incidence of market power, and the price responsiveness of power demand. Finally, the analyses show that internalization and pass-through of carbon costs are needed to reduce CO2 emissions by both changing the mix of power generation technologies and lowering total electricity demand

  7. The impact of the EU ETS on prices, profits and emissions in the power sector. Simulation results with the COMPETES model

    Energy Technology Data Exchange (ETDEWEB)

    Lise, W. [IBS Research and Consultancy, Istanbul (Turkey); Sijm, J. [ECN Policy Studies, Petten (Netherlands); Hobbs, B.F. [Department of Geography and Environmental Engineering, Johns Hopkins University, Baltimore, Maryland (United States)

    2009-06-15

    This paper analyses the impact of the EU Emissions Trading Scheme (ETS) on electricity wholesale in 20 European countries. The analyses show that the costs of (freely allocated) CO2 emission allowances are nearly fully passed through to power prices, which also depend on the structure of the power market, i.e., the incidence of market power, and the price responsiveness of power demand. Finally, the analyses show that internalization and pass-through of carbon costs are needed to reduce CO2 emissions by both changing the mix of power generation technologies and lowering total electricity demand.

  8. Comparative study of the thermoluminescence between the materials α-Al2O3:C, KCl:Eu2+, KBr: Eu2+ and VYCOR

    International Nuclear Information System (INIS)

    Pedroza M, M.; Melendrez, R.; Perez S, R.; Aceves, R.; Piters, T.M.; Barboza F, M.

    1999-01-01

    It is presented some investigation results related to the thermoluminescence curves (Tl), Tl emission and the spectra of excitation of thermoluminescence in the ultraviolet region of 190 to 250 nm in the materials α-Al 2 O 3 :C, KCl: Eu 2+ , KBr: Eu 2+ and the Vycor glass. It was able to be observed that the Tl emission for the first three materials exists around 420 nm and in the case of Vycor the emission consists of two Tl peaks where the most low temperature is a band more wide centered in 460 nm and the other band of high temperature emits in 470 nm. In the excitation curves of Tl were obtained centered bands around 230 nm for KCl: Eu 2+ , 235 nm for KBr: Eu 2+ , 220 nm for the alumina and 195 nm for the Vycor. From the results it was able to be appreciated that this last has a minor relative intensity with respect to the others materials but also the region in which works there was an alone band between the 190 to 205 nm. This fact makes the material be very selective in the ultraviolet region of greatest energy. (Author)

  9. Optimized photoluminescence of SrB 2O 4:Eu 3+ red-emitting phosphor by charge compensation

    Science.gov (United States)

    Zhao, Lai-Shi; Liu, Jie; Wu, Zhan-Chao; Kuang, Shao-Ping

    2012-02-01

    A novel red-emitting phosphor, SrB 2O 4:Eu 3+, was synthesized by high temperature solid-state reaction and its photoluminescence properties were studied. The emission spectrum consists of four major emission bands. The emission peaks are located at 593, 612, 650 and 703 nm, corresponding to the 5D0 → 7F1, 5D0 → 7F2, 5D0 → 7F3 and 5D0 → 7F4 typical transitions of Eu 3+, respectively. The effects of Eu 3+ doping content and charge compensators (Li +, Na +, K +) on photoluminescence of SrB 2O 4:Eu 3+ phosphor were studied. The results show that the emission intensity can be affected by above factors and Na + is the optimal charge compensator for SrB 2O 4:Eu 3+. The photoluminescence of NaSrB 2O 4:Eu 3+ was compared with that of Y 2O 2S:Eu 3+. It implies that SrB 2O 4:Eu 3+ is a good candidate as a red-emitting phosphor pumped by near-ultraviolet (NUV) InGaN chip for fabricating white light-emitting diodes (WLEDs).

  10. High-pressure luminescence spectroscopy of EuAl2O4 phosphor

    International Nuclear Information System (INIS)

    Zorenko, Yu.; Gorbenko, V.; Grinberg, M.; Turos-Matysiak, R.; Kuklinski, B.

    2007-01-01

    EuAl 2 O 4 powder phosphor was prepared by solid-state reaction of EuO and Al 2 O 3 oxides in vacuum. The influence of conditions of preparation on spectral lineshape of Eu 2+ emission was analyzed. It was found that the fluorescence spectra of vacuum-prepared EuAl 2 O 4 samples at 300 K present the superposition of three bands peaked at 430, 500 and 528 nm, corresponding to the 4f 6 5d 1 →4f 7 ( 8 S 7/2 ) transition of Eu 2+ ions in the different sites of EuAl 2 O 4 lattice. The luminescence of Eu 2+ centers in EuAl 2 O 4 host was also studied using the high-pressure spectroscopy up to 67 kbar. It was found that the bright green-yellow fluorescence of EuAl 2 O 4 at 300 K in the band peaked at 520-530nm range can be presented by superposition of two Gaussian sub-bands. The different pressure shifts -23 and -27cm -1 /kbar for two sub-bands were found. Such a structure of the emission spectrum was attributed to the existence of two different Eu 2+ centers in the Eu II 2+ sites of EuAl 2 O 4 lattice with higher coordination number

  11. The EU Decarbonisation Roadmap 2050—What way to walk?

    International Nuclear Information System (INIS)

    Hübler, Michael; Löschel, Andreas

    2013-01-01

    We carry out a detailed computable general equilibrium (CGE) analysis of the EU Decarbonisation Roadmap 2050 on a macroeconomic and on a sectoral level. Herein, we study a Reference scenario that implements existing EU policies as well as 3 unilateral and 3 global climate action scenarios. We identify global climate action with international emissions trading and the full equalisation of CO 2 prices across all (EU) sectors as an economically reasonable policy option to avoid additional costs of the Decarbonisation Roadmap to a large extent. This policy option may include CDM (Clean Development Mechanism in the sense of ‘where’-flexibility) in an extended form if there are countries without emissions caps. Moreover, we identify diverse sectoral effects in terms of output, investment, emissions and international competitiveness. We conclude that the successful realisation of the EU Decarbonisation Roadmap probably requires a wise and joint consideration of technology, policy design and sectoral aspects. - Highlights: ► We extend the CGE model PACE until 2050 and include energy technologies. ► We assess the newest EU Decarbonisation Roadmap in six policy scenarios. ► Global action with ETS and CDM credits from non-participants create low(est) costs. ► Mitigation costs can strongly increase at CO 2 reductions around 80%. ► The policy effects vary strongly across EU sectors

  12. Surprising luminescent properties of the polyphosphates Ln(PO3)3:Eu (Ln = Y, Gd, Lu).

    Science.gov (United States)

    Höppe, Henning A; Kazmierczak, Karolina; Kacprzak, Sylwia; Schellenberg, Inga; Pöttgen, Rainer

    2011-10-21

    The optical emission properties of the lanthanoid catena-polyphosphates Ln(PO(3))(3) (Ln = Y, Gd, Lu) doped with europium were investigated. Incommensurately modulated β-Y(PO(3))(3):Eu (super space group Cc (0|0.364|0)0) and Gd(PO(3))(3):Eu (space group I2/a) show the usual emission characteristics of Eu(3+), while in Lu(PO(3))(3):Eu (space group Cc) the europium is unprecedentedly partially reduced to the divalent state, as proven by both a broad emission band at 406 nm excited at 279 nm and an EPR spectroscopic investigation. (151)Eu-Mössbauer spectroscopy showed that only a very small part of the europium is reduced in Lu(PO(3))(3):Eu. An explanation for this unusual behaviour is given. This journal is © The Royal Society of Chemistry 2011

  13. Hardware Locks with Priority Ceiling Emulation for a Java Chip-Multiprocessor

    DEFF Research Database (Denmark)

    Strøm, Torur Biskopstø; Schoeberl, Martin

    2015-01-01

    According to the safety-critical Java specification, priority ceiling emulation is a requirement for implementations, as it has preferable properties, such as avoiding priority inversion and being deadlock free on uni-core systems. In this paper we explore our hardware supported implementation...... of priority ceiling emulation on the multicore Java optimized processor, and compare it to the existing hardware locks on the Java optimized processor. We find that the additional overhead for priority ceiling emulation on a multicore processor is several times higher than simpler, non-premptive locks, mainly...

  14. Glass ceiling in SMEs? Women, managerialization and performance

    OpenAIRE

    L. Songini; L. Gnan

    2012-01-01

    This article analyses the role of women in a sample of Italian small and medium sized enterprises (SMEs), both non-family and family owned businesses. We assume that the existence of a glass ceiling implies that women are not in a position to exercise an active role in the company; ownership per se does not assure the elimination of the glass ceiling, while the broader involvement of women in governance and management roles, as we may suppose in family firms, may represent a better situation ...

  15. The European Climate Change Programme. EU Action against Climate Change

    International Nuclear Information System (INIS)

    2006-01-01

    The European Union has long been committed to international efforts to tackle climate change and felt the duty to set an example through robust policy-making at home. At European level a comprehensive package of policy measures to reduce greenhouse gas emissions has been initiated through the European Climate Change Programme (ECCP). Each of the 25 EU Member States has also put in place its own domestic actions that build on the ECCP measures or complement them. The European Commission established the ECCP in 2000 to help identify the most environmentally effective and most cost-effective policies and measures that can be taken at European level to cut greenhouse gas emissions. The immediate goal is to help ensure that the EU meets its target for reducing emissions under the Kyoto Protocol. This requires the 15 countries that were EU members before 2004 to cut their combined emissions of greenhouse gases to 8% below the 1990 level by 2012

  16. The innovation impact of the EU Emission Trading System. Findings of company case studies in the German power sector

    International Nuclear Information System (INIS)

    Rogge, Karoline S.; Schneider, Malte; Hoffmann, Volker H.

    2011-01-01

    This paper provides a detailed analysis of how the European Emission Trading System (EU ETS) as the core climate policy instrument of the European Union has impacted innovation. Towards this end, we investigate the impact of the EU ETS on research, development and demonstration (RD and D), adoption, and organizational change. In doing so, we pay particular attention to the relative influences of context factors (policy mix, market factors and public acceptance) and firm characteristics (value chain position, technology portfolio, size and vision). Empirically, our qualitative analysis is based on multiple case studies with 19 power generators, technology providers and project developers in the German power sector which were conducted in 2008/09. We find that the innovation impact of the EU ETS has remained limited so far because of the scheme's initial lack of stringency and predictability and the relatively greater importance of context factors. Additionally, the impact varies significantly across technologies, firms, and innovation dimensions and is most pronounced for RD and D on carbon capture technologies and organizational changes. Our analysis suggests that the EU ETS on its own may not provide sufficient incentives for fundamental changes in corporate innovation activities at a level which ensures political long-term targets can be achieved. (author)

  17. Strong red-emission of Eu{sup 3+}:Li{sub 4}Ti{sub 5}O{sub 12} powders for phosphor applications

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yan [Kazuo Inamori School of Engineering, New York State College of Ceramics, Alfred University, Alfred, NY 14802 (United States); Jiménez, José A. [Department of Chemistry, University of North Florida, Jacksonville, FL 32224 (United States); Wu, Yiquan, E-mail: wuy@alfred.edu [Kazuo Inamori School of Engineering, New York State College of Ceramics, Alfred University, Alfred, NY 14802 (United States)

    2016-08-15

    The synthesis and photoluminescence properties of trivalent europium doped lithium titanate (Eu{sup 3+}:Li{sub 4}Ti{sub 5}O{sub 12}) with different Eu{sup 3+} concentrations (0.1 mol%, 0.3 mol%, 1.0 mol%, 3.0 mol%) are reported and analyzed as a phosphor. Europium (III) nitrate (Eu(NO{sub 3}){sub 3}) was employed as Eu{sup 3+} source, while lithium acetate dihydrate (CH{sub 3}COOLi·2H{sub 2}O) and titanium n-butoxide (Ti(OC{sub 4}H{sub 9}){sub 4}) were adopted as raw materials to synthesize the host lithium titanate with a Li:Ti stoichiometry of 4.5:1. Phase identification was performed using X-ray diffraction (XRD), and morphology was examined using scanning electron microscopy (SEM). Eu{sup 3+}:Li{sub 4}Ti{sub 5}O{sub 12} powders showed strong red emission at 612 nm, corresponding to the {sup 5}D{sub 0}–{sup 7}F{sub 2} transition, with the strongest excitation peak observed in the blue light region at 464 nm. Decay time analyses revealed relatively short lifetimes accompanying typical exponential decay rates. The effect of Eu{sup 3+} concentration (0.1 mol%, 0.3 mol%, 1.0 mol%, 3.0 mol%) on photoluminescence intensity and decay time was explored, and is reported here. It was determined that the CIE color coordinates (0.66, 0.34) of the doped Li{sub 4}Ti{sub 5}O{sub 12} powders were independent of Eu{sup 3+} concentration, and that the coordinates are very similar to the ideal red chromaticity (0.67, 0.33) designated by the National Television Standard Committee (NTSC) system.

  18. A Strategy for Synthesizing CaZnOS:Eu{sup 2+} Phosphor and Comparison of Optical Properties with CaS:Eu{sup 2+}

    Energy Technology Data Exchange (ETDEWEB)

    Qiu, Zhongxian; Rong, Chunying; Zhou, Wenli; Zhang, Jilin; Li, Chengzhi; Yu, Liping; Liu, Shubin; Lian, Shixun, E-mail: shixunlian@gmail.com

    2014-01-15

    Graphical abstract: Pure-phase CaZnOS:Eu{sup 2+},Ce{sup 3+}phosphor with good chemical and thermal stability can be synthesized by co-doping with Ce{sup 3+} as deoxidizer rather than reduction atmosphere. The broad bluish-green excitation and broad red emission show it is a better phosphor than CaS:Eu{sup 2+} for white LED and for sunlight harvesting of plants. -- Highlights: • Pure-phase phosphor CaZnOS:Eu{sup 2+} was synthesized by co-doping with Ce{sup 3+} as deoxidizer. • Energy transfer mechanism from Ce{sup 3+} to Eu{sup 2+} in CaZnOS host is proposed. • CaZnOS:Eu{sup 2+}, Ce{sup 3+} phosphor has good chemical and thermal stability performance. • The similarities and differences between CaZnOS:Eu{sup 2+} and CaS:Eu{sup 2+} were analyzed. • The green excitation and red emission show superior solar harvesting for plants. -- Abstract: The red-emitting phosphor CaZnOS:Eu{sup 2+} was synthesized from CaCO{sub 3}, ZnS, Eu{sub 2}O{sub 3} and CeCl{sub 3} by controlling the sintering condition. It was found that Ce{sup 3+} ions can play a role of reductant to contribute to the formation of Eu{sup 2+} in CaZnOS matrix under inert protective atmosphere. While the gas flow changed to H{sub 2}/N{sub 2}, the product turned to CaS easily. XRD, photoluminescence spectra, UV–vis and IR absorption spectra were evaluated to investigate the origin of the distinctions of the optical properties and stabilities between the two divalent europium ions doped phosphors CaZnOS:Eu{sup 2+} and CaS:Eu{sup 2+}. The similarities and differences between them were analyzed.

  19. Synthesis of luminescent YVO4:Eu3+ submicrometer crystals through hydrogels as directing agents

    International Nuclear Information System (INIS)

    Li, Yan; Zheng, Yuhui; Wang, Qianming; Zhang, Cheng Cheng

    2012-01-01

    The innovative hydrogel template (polyacrylamide or polyacrylic acid) directed synthesis of YVO 4 :Eu 3+ phosphor in a controlled manner was thoroughly studied. Photoluminescence spectra show the europium(III)-doped yttrium orthovanadate could exhibit strong red emissions within the soft matrix (polyacrylamide) and remain relatively stable even when the temperature reached nearly 100 °C. After calcination process, X-ray powder diffraction patterns, SEM and DLS measurements implied that the sample was in agreement with pure tetragonal phase and the particle sizes were in the range of 100–200 nm. More importantly, YVO 4 :Eu 3+ products prepared based on hydrogels have remarkable improvement in emission intensities compared to phosphors synthesized by conventional approach. Similar results of overall quantum efficiency also support that YVO 4 :Eu 3+ assembled by PAM hydrogel (1.94%) is better than the routine way (0.91%). -- Highlights: ► YVO 4 :Eu 3+ could be formed within the soft matrix. ► The as-derived YVO 4 :Eu 3+ exhibited red emissions and remain relatively stable nearly 100 °C. ► YVO 4 :Eu 3+ prepared by hydrogels has remarkable improvement in emission intensities.

  20. Combustion synthesis of red emitting borate host PDP phosphor YCaBO4: Eu3+

    International Nuclear Information System (INIS)

    Ingle, J.T.; Hargunani, S.P.; Sonekar, R.P.; Nagpure, P.A.; Omanwar, S.K.; Moharil, S.V.

    2012-01-01

    The red emitting borate host phosphor YCaBO 4 : Eu 3+ has been prepared by a novel solution combustion technique. The synthesis is based on the exothermic reaction between the fuel (Urea) and Oxidizer (Ammonium nitrate). The photoluminescence properties of the powder samples of YCaBO 4 : Eu 3+ has been investigated under UV and VUV excitation. The phosphor shows strong absorption in UV and VUV region and exhibits intense red emission upon excited by 254 nm UV and 173 nm VUV radiation. Under UV 254 nm excitation, YCaBO 4 : Eu 3+ exhibits intense red emission around 610 nm. Under VUV excitation of 173 nm, the phosphor emits intense red emission around 610 nm and few weak emissions. These weak emissions could be suppressed by annealing the sample repeatedly at proper temperature and the borate phosphor YCaBO 4 : Eu 3+ could be a good red emitting phosphor for PDP display and mercury free lamps. (author)

  1. PL and EL characterizations of ZnO:Eu3+, Li+ films derived by sol-gel process

    International Nuclear Information System (INIS)

    Xue Daoqi; Zhang Junying; Yang Chun; Wang Tianmin

    2008-01-01

    ZnO:Eu 3+ , Li + films prepared by the dip-coating method were characterized by photoluminescence (PL) and electroluminescence (EL). When the ZnO:Eu 3+ , Li + films were excited using UV light with energy corresponding to the band-to-band excitation of the host matrix, the PL spectra showed emissions from both ZnO and Eu 3+ ions, while their EL spectra showed emissions only from Eu 3+ ions, and no emission from ZnO could be detected. It is found that the EL emission intensity B is dependent on the applied voltage, B=B o exp(-bV -1/2 ). With increasing frequency, the EL intensity dramatically increases at lower frequencies ( 1000 Hz)

  2. Contribution of Eu ions on the precipitation of silver nanoparticles in Ag-Eu co-doped borate glasses

    International Nuclear Information System (INIS)

    Jiao, Qing; Qiu, Jianbei; Zhou, Dacheng; Xu, Xuhui

    2014-01-01

    Graphical abstract: - Highlights: • Silver nanoparticles are precipitated from the borate glasses during the melting process without any further heat treatment. • The reduction of Eu 3+ ions to Eu 2+ ions is presented in this material. • The intensity of Ag + luminescence. • The introduction of Eu ions accelerated the reaction between Eu 2+ ions and silver ions inducing the silver clusters formation. - Abstract: Ag + doped sodium borate glasses with different Eu ions concentration were prepared by the melt-quenching method. The absorption at about 410 nm which was caused by the surface plasmon resonance (SPR) of Ag nanoparticles (NPs) is promoted with increasing of Eu ions concentration. Meanwhile, the luminescent spectra showed that the emission intensity of Ag + decreased while that of the Ag aggregates increased simultaneously. The results indicated that the Ag ions intend to form the high-polymeric state such as Ag aggregates and nanoparticles with increasing of europium ions. Owing to the self-reduction of Eu 3+ to Eu 2+ in our glass system, it revealed that Ag + has been reduced by the neighboring Eu 2+ which leads to the formation of Ag aggregates and the precipitation of Ag NPs in the matrix. In addition, energy transfer (ET) process from Ag + /Ag aggregates to the Eu 3+ was investigated for the enhancement of Eu 3+ luminescence

  3. Comparing the luminescence processes of YVO{sub 4}:Eu and core-shell YVO{sub 4}@YF{sub 3} nanocrystals with bulk-YVO{sub 4}:Eu

    Energy Technology Data Exchange (ETDEWEB)

    Shirmane, L., E-mail: liana.shirmane@gmail.com [Institute of Solid State Physics, University of Latvia, 8 Kengaraga iela, LV-1063 Riga (Latvia); Feldmann, C. [Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstrasse 15, D-76131 Karlsruhe (Germany); Pankratov, V., E-mail: vladimirs.pankratovs@oulu.fi [Institute of Solid State Physics, University of Latvia, 8 Kengaraga iela, LV-1063 Riga (Latvia); MAX IV Laboratory, Box 118, S-221 00 Lund (Sweden); Research Center of Molecular Materials, University of Oulu, P.O. Box 3000, FIN-90014 Oulu (Finland)

    2017-01-01

    Comparative analysis of bulk, non-coated and core-shelled nanocrystalline YVO{sub 4}:Eu was performed by means of time-resolved luminescence and VUV excitation luminescence spectroscopy techniques. Nanocrystalline YVO{sub 4}:Eu samples – both as-prepared and YF{sub 3} core-shelled – have been synthesized by means of a microwave-assisted synthesis in ionic liquids, which allows to obtain 10–12 nm nanoparticles with high crystallinity. The results show noticeable differences between bulk and nanocrystalline YVO{sub 4}:Eu in photoluminescence experimental data, which explains by influence of the nanocrystal surface. A YF{sub 3} core-shell layer around YVO{sub 4}:Eu nanoparticles partially recovers the intensity of the Eu{sup 3+} emission. It is demonstrated that the Eu{sup 3+} luminescence recovery is achieved at the expense of the suppression of the intrinsic emission but not due to the passivation of surface loss centers in core-shelled nanocrystals. It is also shown that surface loss processes are the reason of the degradation of energy transfer efficiency from the host lattice to Eu{sup 3+} under high-energy excitations in vacuum ultraviolet spectral range.

  4. Controlling the energy transfer via multi luminescent centers to achieve white light/tunable emissions in a single-phased X2-type Y2SiO5:Eu(3+),Bi(3+) phosphor for ultraviolet converted LEDs.

    Science.gov (United States)

    Kang, Fengwen; Zhang, Yi; Peng, Mingying

    2015-02-16

    So far, more than 1000 UV converted phosphors have been reported for potential application in white light-emitting diodes (WLEDs), but most of them (e.g., Y2O2S:Eu, YAG:Ce or CaAlSiN3:Eu) suffer from intrinsic problems such as thermal instability, color aging or re-absorption by commixed phosphors in the coating of the devices. In this case, it becomes significant to search a single-phased phosphor, which can efficiently convert UV light to white lights. Herein, we report a promising candidate of a white light emitting X2-type Y2SiO5:Eu(3+),Bi(3+) phosphor, which can be excitable by UV light and address the problems mentioned above. Single Bi(3+)-doped X2-type Y2SiO5 exhibits three discernible emission peaks at ∼355, ∼408, and ∼504 nm, respectively, upon UV excitation due to three types of bismuth emission centers, and their relative intensity depends tightly on the incident excitation wavelength. In this regard, proper selection of excitation wavelength can lead to tunable emissions of Y2SiO5:Bi(3+) between blue and green, which is partially due to the energy transfer among the Bi centers. As a red emission center Eu(3+) is codoped into Y2SiO5:Bi(3+), energy transfer has been confirmed happening from Bi(3+) to Eu(3+) via an electric dipole-dipole (d-d) interaction. Our experiments reveal that it is easily realizable to create the white or tunable emissions by adjusting the Eu(3+) content and the excitation schemes. Moreover, a single-phased white light emission phosphor, X2-type Y1.998SiO5:0.01Eu(3+),0.01 Bi(3+), has been achieved with excellent resistance against thermal quenching and a QE of 78%. At 200 °C, it preserves >90% emission intensity of that at 25 °C. Consequent three time yoyo experiments of heating-cooling prove no occurrence of thermal degradation. A WLED lamp has been successfully fabricated with a CIE chromaticity coordinate (0.3702, 0.2933), color temperature 4756 K, and color rendering index of 65 by applying the phosphor onto a UV LED

  5. Enhanced orange-red emission by using Mo codoped in Ba2CaWO6: Eu3+, Li+ phosphor under near UV excitation

    International Nuclear Information System (INIS)

    Sun, Xiaoyuan; Hao, Zhendong; Li, Chunjie; He, Xiaoguang; Qi, Haiyan; Yu, Lijun; Luo, Yongshi; Zhang, Jiahua; Gao, Jiwei; Zhong, Ruixia

    2013-01-01

    The orange-red emitting phosphors Ba 2 Ca 0.9 Mo x W 1−x O 6 :Eu 3+ 0.05 , Li + 0.05 (x=0, 0.05, 0.1, 0.15, 0.2, 0.25, 0.5, 0.75, and 1.0) and Ba 2 Ca 1−2y Mo 0.2 W 0.8 O 6 :Eu 3+ y , Li + y (y=0.03, 0.05, 0.07, 0.1, and 0.15) were synthesized. The crystalline structure and photoluminescence properties of these phosphors were described. The strong orange-red emission of Eu 3+ ( 5 D 0 — 7 F 1 transition) at around 593 nm was observed. Addition of Mo strongly enhances the charge transfer band absorption in the near ultraviolet region that corresponds to near ultraviolet white light emitting diode. The dependence of photoluminescence intensities on Eu 3+ concentrations with optimal Mo concentration under 400 nm excitation was studied. The phosphor is considered to be a promising orange-red emitting phosphor for near ultraviolet GaN-based white light emitting diode. - Highlights: ► The samples form solid solutions when Mo is added into Ba 2 CaWO 6 : Eu 3+ , Li + phosphors. ► Addition of Mo in Ba 2 CaWO 6 : Eu 3+ , Li + shifts the PLE spectra maximum from UV region to near UV region. ► In Ba 2 CaMo x W 1−x O 6 :Eu 3+ , Li + , the most efficient concentrations occur at 0.1 and 0.2 for Eu and Mo.

  6. Essential EU Climate Law

    NARCIS (Netherlands)

    Woerdman, Edwin; Roggenkamp, Martha; Holwerda, Marijn

    2015-01-01

    This innovative textbook takes a broad approach to EU climate law and presents all available legal instruments to combat climate change, ranging from greenhouse gas emissions trading to the use of renewable energy sources and energy efficiency mechanisms. After providing a definition of climate law,

  7. Convergence of EU nitrogen surplus, the RDP indicator of water quality

    NARCIS (Netherlands)

    Reinhard, S.; Linderhof, V.G.M.

    2015-01-01

    The EU Water Framework Directive (WFD), EU Nitrate Directive and EU Rural Development Policy (RDP) aim to improve water quality. The nutrient content of water can be decreased by reducing nitrogen emission. In this article a novel approach is applied to the evaluation of the impact of Agri

  8. Assessing the factors behind CO2 emissions changes over the phases 1 and 2 of the EU ETS: an econometric analysis. CDC Climat Research - Working Paper No. 2013-15

    International Nuclear Information System (INIS)

    Gloaguen, Olivier; Alberola, Emilie

    2013-10-01

    It has been repeatedly said that the economic slowdown that began in 2008 largely explains the fall in carbon emissions recorded in Europe since the introduction of the European Union Emissions Trading Scheme (EU ETS). In fact, the European Union stated this very clearly in its initial report on the operation of the EU ETS in November 2012. Using an econometric analysis based on a business-as-usual scenario, it is shown that reductions of around 1.1 GtCO 2 are likely to have been achieved within the scope of the 11.000 installations covered by the EU ETS. Of those reductions, between 600 and 700 million tonnes are said to have resulted from the two policies in the 2020 Climate and Energy Package, which aims to achieve a 20% renewable energy target (a decrease of around 500 million tonnes) and a 20% improvement in energy intensity (a decrease of between 100 and 200 million tonnes). The economic downturn also played a significant, although not dominant role in the decrease in CO 2 emissions, the impact of which was estimated at 300 million tonnes. Price substitution effects induced by coal and gas prices also seem to have affected emissions, within an order of magnitude of around 200 million tonnes. The study does not enable any impact created by the carbon price to be identified. It is important. However, to emphasize that the economic downturn and the development of RE were responsible for the decrease of the carbon price, and specifically marginalised its influence in terms of CO 2 emission reductions at the installations covered within the EU. (authors)

  9. Preparation, photoluminescent properties and luminescent dynamics of BaAlF{sub 5}:Eu{sup 2+} nanophosphors

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Wei [Stem Cell and Tissue Engineering Laboratory, Dalian University of Technology, Dalian, Liaoning 116023 (China); College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Hua, Ruinian, E-mail: rnhua@dlnu.edu.cn [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Liu, Tianqing, E-mail: liutq@dlut.edu.cn [Stem Cell and Tissue Engineering Laboratory, Dalian University of Technology, Dalian, Liaoning 116023 (China); Zhao, Jun [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); Na, Liyan [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Chen, Baojiu [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China)

    2014-12-15

    Graphical abstract: Rice-shaped BaAlF{sub 5}:Eu{sup 2+} nanophosphors were synthesized via one-pot hydrothermal process. The as-prepared BaAlF{sub 5}:Eu{sup 2+} are composed of many particles with an average diameter of 40 nm. When excited at 260 nm, the sharp line emission located at 361 nm of Eu{sup 2+} was observed. The optimum doping concentration of Eu{sup 2+} was confirmed to be 5 mol%. The strong ultraviolet emission of Eu{sup 2+} ions in BaAlF{sub 5}:Eu{sup 2+} nanoparticles suggests that these nanoparticles may have potential applications for sensing, solid-state lasers and spectrometer calibration. - Highlights: • BaAlF{sub 5}:Eu{sup 2+} nanophosphors were synthesized via a mild hydrothermal process. • The Van and Huang models were used to research the mechanism of concentration quenching. • The optimum doping concentration of Eu2+ was confirmed to be 5 mol%. - Abstract: Eu{sup 2+}-doped BaAlF{sub 5} nanophosphors were synthesized via a facile one-pot hydrothermal method. The final products were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and photoluminescence (PL) spectroscopy. XRD results showed that the prepared samples are single-phase. The FE-SEM and TEM images indicated that the prepared BaAlF{sub 5}:Eu{sup 2+} nanophosphors are composed of many rice-shaped particles with an average diameter of 40 nm. When excited at 260 nm, BaAlF{sub 5}:Eu{sup 2+} nanophosphors exhibit the sharp line emissions of Eu{sup 2+} at room temperature. The optimum doping concentration of Eu{sup 2+} was confirmed to be 5 mol%. The Van and Huang models were used to study the mechanism of concentration quenching and the electric dipole–dipole interaction between Eu{sup 2+} can be deduced to be a dominant for quenching fluorescence in BaAlF{sub 5}:Eu{sup 2+} nanophosphors. The strong ultraviolet emission of Eu{sup 2+} in BaAlF{sub 5}:Eu{sup 2+} nanophosphors suggests that

  10. EU emissions trading. The need for cap adjustment in response to external shocks and unexpected developments?

    Energy Technology Data Exchange (ETDEWEB)

    Diekmann, Jochen [DIW, Berlin (Germany)

    2012-11-15

    In this paper the advantages and disadvantages of the various adaptation options will be discussed from an economic perspective. Firstly, the criteria for identifying a need for potentially legitimate adaptation should be investigated. Furthermore, the issue of appropriate timely intervention points prior to or within the trading period will be discussed. In what periods and scenarios are adjustments to the cap worthwhile from an economic perspective? To what extent could minimum prices or price ranges make sense? What role could a strategic reserve play? By addressing these issues, it will be fundamentally discussed as to how the emissions trading scheme could be further developed and strengthened by greater flexibility. After a brief characterisation of emissions trading in theory and practice in Chapter 2, Chapter 3 will identify potential external shocks and unexpected developments which may impair the functioning of an emissions trading scheme. The current problems of cap setting for the third trading period of the EU ETS will be described in Chapter 4. Against this background, cap adjustments will be discussed in Chapter 5, minimum and maximum prices in Chapter 6 and strategic reserves in emissions trading in Chapter 7. The conclusions are summarised in Chapter 8.

  11. Studies in crystal structure and luminescence properties of Eu3+-doped metal tungstate phosphors for white LEDs

    International Nuclear Information System (INIS)

    Lee, Gwan-Hyoung; Kang, Shinhoo

    2011-01-01

    The correlation between the crystal structure and luminescent properties of Eu 3+ -doped metal tungstate phosphors for white LEDs was investigated. Red-emitting A 4-3x (WO 4 ) 2 :Eu x 3+ (A=Li, Na, K) and B (4-3x)/2 (WO 4 ) 2 :Eu x 3+ (B=Mg, Ca, Sr) phosphors were synthesized by solid-state reactions. The findings confirmed that these phosphors exhibited a strong absorption in the near UV to green range, due to the intra-configurational 4f-4f electron transition of Eu 3+ ions. The high doping concentration of Eu 3+ enhanced the absorption of near UV light and red emission without any detectable concentration quenching. Based on the results of a Rietveld refinement, it was attributed to the unique crystal structure. In the crystal structure of the Eu 3+ -doped metal tungstate phosphor, the critical energy transfer distance is larger than 5 A so that exchange interactions between Eu 3+ ions would occur with difficulty, even at a high doping concentration. The energy transfer between Eu 3+ ions, which causes a decrease in red emission with increasing concentration of Eu 3+ , appears to be due to electric multi-polar interactions. In addition, the Eu-O distance in the host lattice affected the shape of emission spectrum by splitting of emission peak at the 5 D 0 → 7 F 2 transition of Eu 3+ . - Highlights: → Eu 3+ -doped metal tungstate was synthesized as a red phosphor for white LEDs. → Crystal structure is tetragonal with a space group of I4 1 /c. → A strong absorption in the near UV to green range was observed. → High doping of Eu 3+ enhanced the absorption of near UV light and red emission.

  12. Synthesis and characterization of a liquid Eu precursor (EuCppm2) allowing for valence control of Eu ions doped into GaN by organometallic vapor phase epitaxy

    International Nuclear Information System (INIS)

    Mitchell, Brandon; Koizumi, Atsushi; Nunokawa, Takumi; Wakamatsu, Ryuta; Lee, Dong-gun; Saitoh, Yasuhisa; Timmerman, Dolf; Kuboshima, Yoshinori; Mogi, Takayuki; Higashi, Shintaro; Kikukawa, Kaoru; Ofuchi, Hironori; Honma, Tetsuo; Fujiwara, Yasufumi

    2017-01-01

    A liquid Eu precursor, bis(normal-propyl-tetramethylcyclopentadienyl)europium has been synthesized. This precursor exists as a liquid at temperatures higher than 49 °C, has a moderately high vapor pressure, contains no oxygen in its molecular structure, and can be distilled to high purity. These properties make it ideal for doping using a chemical vapor or atomic layer deposition method, and provide a degree of control previously unavailable. As a precursor the Eu exists in the divalent valance state, however, once doped into GaN by organometallic vapor phase epitaxy, the room-temperature photoluminescence of the Eu-doped GaN exhibited the typical red emission due to the intra-4f shell transition of trivalent Eu. After variation of the growth temperature, it was found that divalent Eu could be stabilized in the GaN matrix. By tuning the Fermi level through donor doping, the ratio of Eu 2+ to Eu 3+ could be controlled. The change in valence state of the Eu ions was confirmed using X-ray absorption near-edge structure. - Highlights: • A liquid Eu precursor was synthesized and its properties were characterized. • Precursor has a low melting point and a moderately high vapor pressure. • Does not contain oxygen in its molecular structure. • Eu can changed its valance state when incorporated into GaN. • Valence state of Eu in GaN can be controlled by donor doping.

  13. Emissions trading for business and industry. A new instrument to achieve environmental goals

    International Nuclear Information System (INIS)

    2001-05-01

    Key components of the Kyoto Protocol are the flexible instruments or mechanisms: namely trading emissions, Joint Implementation and the Clean Development Mechanism. These mechanisms make it possible to trade in CO2 emissions or emission permits, thereby enabling the Kyoto Protocol targets that have been imposed on all states, to be attained in the most cost-effective way. Although the Kyoto targets are binding only on states, it is likely that governments will pass responsibility for meeting them on to specific target groups and impose absolute or relative (energy efficiency or CO2 per unit) targets on them. Flexible instruments, especially Joint Implementation (JI) and the Clean Development Mechanism (CDM), can also be used by companies to achieve their emission targets. Until now, the VNO-NCW Confederation of Netherlands Industry has generally been positive about the use of flexible instruments. However, various developments have persuaded the VNO-NCW that it is a good idea to examine more specific questions with regard to flexible instruments. First, the CO2 trade committee (the Vogtlaender Committee) has been asked to issue recommendations concerning the possibilities inherent in a national system for emissions trading. A basic variant will be explored, in which protected sectors (households, the service industry, small industrial enterprises) will be assigned absolute ceilings and internationally operating companies will be assigned with relative targets. Second, in March 2000 the European Commission published a Green Paper on trade in greenhouse gas emissions within the European Union in order to launch an European Union (EU)-wide debate on the introduction of an EU system for trade in emissions in 2005. In common with the Netherlands, various EU member states are studying the possibilities for phasing in a system of trade in CO2 emissions; only in Denmark has such a system actually been introduced. In industry, too, many initiatives have been taken in

  14. MgO:Eu3+ red nanophosphor: Low temperature synthesis and photoluminescence properties

    Science.gov (United States)

    Devaraja, P. B.; Avadhani, D. N.; Prashantha, S. C.; Nagabhushana, H.; Sharma, S. C.; Nagabhushana, B. M.; Nagaswarupa, H. P.; Premkumar, H. B.

    2014-03-01

    Nanoparticles of Eu3+ doped (0-9 mol%) MgO were prepared using low temperature (400 °C) solution combustion technique with metal nitrate as precursor and glycine as fuel. The powder X-ray diffraction (PXRD) patterns of the as-formed products show single cubic phase and no further calcination was required. The crystallite size was obtained using Scherer's formula and was found to be 5-6 nm. The effect of Eu3+ ions on luminescence characteristics of MgO was studied and the results were discussed in detail. These phosphors exhibit bright red emission upon 395 nm excitation. The characteristic photoluminescence (PL) emission peaks at ∼580, 596, 616, 653, 696 and 706 nm (5D0 → 7Fj= 0, 1, 2, 3, 4) were recorded due to Eu3+ ions. The electronic transition corresponding to 5D0 → 7F2 of Eu3+ ions (616 nm) was stronger than the magnetic dipole transition corresponding to 5D0 → 7F1 of Eu3+ ions (596 nm). The international commission on illumination (CIE) chromaticity co-ordinates were calculated from emission spectra, the values (x, y) were very close to national television system committee (NTSC) standard value of red emission. Therefore the present phosphor was highly useful for display applications.

  15. Parametrical analysis on the diffuse ceiling ventilation by experimental and numerical studies

    DEFF Research Database (Denmark)

    Zhang, Chen; Kristensen, Martin Heine; Jensen, Jakob Sølund

    2016-01-01

    This paper aims to investigate the performance of diffuse ceiling ventilation in a classroom. An experimental study is carried out in a test chamber to examine the impact of diffuse ceiling opening area on the system cooling capacity and thermal comfort. The results indicate that diffuse ceiling ....... The numerical results reveal that even distribution of heat sources gives a lower draught risk environment than centralized distribution. In addition, there is a significant increase on the draught risk with increase of room height....

  16. Tunable Yellow-Red Photoluminescence and Persistent Afterglow in Phosphors Ca4LaO(BO3)3:Eu3+ and Ca4EuO(BO3)3.

    Science.gov (United States)

    Chen, Zhen; Pan, Yuexiao; Xi, Luqing; Pang, Ran; Huang, Shaoming; Liu, Guokui

    2016-11-07

    In most Eu 3+ activated phosphors, only red luminescence from the 5 D 0 is obtainable, and efficiency is limited by concentration quenching. Herein we report a new phosphor of Ca 4 LaO(BO 3 ) 3 :Eu 3+ (CLBO:Eu) with advanced photoluminescence properties. The yellow luminescence emitted from the 5 D 1,2 states is not thermally quenched at room temperature. The relative intensities of the yellow and red emission bands depend strongly on the Eu 3+ doping concentration. More importantly, concentration quenching of Eu 3+ photoluminescence is absent in this phosphor, and the stoichiometric compound of Ca 4 EuO(BO 3 ) 3 emits stronger luminescence than the Eu 3+ doped compounds of CLBO:Eu; it is three times stronger than that of a commercial red phosphor of Y 2 O 3 :Eu 3+ . Another beneficial phenomenon is that ligand-to-metal charge transfer (CT) transitions occur in the long UV region with the lowest charge transfer band (CTB) stretched down to about 3.67 eV (∼330 nm). The CT transitions significantly enhance Eu 3+ excitation, and thus result in stronger photoluminescence and promote trapping of excitons for persistent afterglow emission. Along with structure characterization, optical spectra and luminescence dynamics measured under various conditions as a function of Eu 3+ doping, temperature, and excitation wavelength are analyzed for a fundamental understanding of electronic interactions and for potential applications.

  17. Human Response to Personalized Ventilation Combined with Chilled Ceiling

    DEFF Research Database (Denmark)

    Lipczynska, Aleksandra; Kaczmarczyk, Jan; Marcol, Bartosz

    2014-01-01

    Personalized ventilation (PV) improves inhaled air quality, because it provides fresh air to each workstation and directly to occupant’s breathing zone. Previous research was focused on combining PV with additional total volume air distribution, i.e. mixing ventilation or displacement ventilation......, the use of radiant ceiling cooling will provide operative temperature lower than the air temperature and will improve further occupants’ thermal comfort at warm environment. Therefore combining PV with chilled ceiling may be an effective way to provide thermal comfort in rooms at temperature higher than...... temperature for chilled ceiling was 15,5/16,8°C at room air temperature of 26°C and 19,5/20,6°C at 28°C. During the experiment the subjects were performing typical office tasks at workstations with computers. Exposure included also increased activity level office work for a period of 25 min...

  18. The effect of diffuse ceiling panel on the energy performance of thermally activated building construction

    DEFF Research Database (Denmark)

    Zhang, Chen; Heiselberg, Per Kvols; Pomianowski, Michal Zbigniew

    2016-01-01

    An integrated system combining diffuse ceiling ventilation with thermally activated building construction (TABS) was proposed recently. In this system, TABS is encapsulated by diffuse ceiling panel and cannot have directly heat exchange with the room. The aim of this study is to investigate...... the effect of diffuse ceiling panel on the energy performance of TABS in both heat and cooling mode. Experiments are carried out in a full-scale test facility with the integrated system, and the cases without diffuse ceiling are also measured as references. The results indicate that the diffuse ceiling has...... an opposite effect on the heating and cooling capacity of TABS. In addition, a numerical model is built and validated by the measured data. The validated model is further applied to conduct a paramedical study on the materials of the diffuse ceiling panel....

  19. Photoluminescence and thermoluminescence properties of Eu2+ doped and Eu2+ ,Dy3+ co-doped Ba2 MgSi2 O7 phosphors.

    Science.gov (United States)

    Sao, Sanjay Kumar; Brahme, Nameeta; Bisen, D P; Tiwari, Geetanjali

    2016-11-01

    In this work, we report the preparation, characterization, comparison and luminescence mechanisms of Eu 2 + -doped and Eu 2 + ,Dy 3 + -co-doped Ba 2 MgSi 2 O 7 (BMSO) phosphors. Prepared phosphors were synthesized via a high temperature solid-state reaction method. All prepared phosphors appeared white. The phase structure, particle size, and elemental analysis were analyzed using X-ray diffraction (XRD), transmission electron microscopy (TEM) and energy-dispersive X-ray (EDX) analysis. The luminescence properties of the phosphors were investigated by thermoluminescence (TL) and photoluminescence (PL). The PL excitation and emission spectra of Ba 2 MgSi 2 O 7 :Eu 2 + showed the peak to be around 381 nm and 490 nm respectively. The PL excitation spectrum of Ba 2 MgSi 2 O 7 :Eu 2 + Dy 3 + showed the peak to be around 341 nm and 388 nm, and the emission spectrum had a broad band around 488 nm. These emissions originated from the 4f 6 5d 1 to 4f 7 transition of Eu 2 + . TL analysis revealed that the maximum TL intensity was found at 5 mol% of Eu 2 + doping in Ba 2 MgSi 2 O 7 phosphors after 15 min of ultraviolet (UV) light exposure. TL intensity was increased when Dy 3 + ions were co-doped in Ba 2 MgSi 2 O 7 :Eu 2 + and maximum TL intensity was observed for 2 mol% of Dy 3 + . TL emission spectra of Ba 1.95 MgSi 2 O 7 :0.05Eu 2 + and Ba 1.93 MgSi 2 O 7 :0.05Eu 2 + ,0.02Dy 3 + phosphors were found at 500 nm. TL intensity increased with UV exposure time up to 15 min, then decreased for the higher UV radiation dose for both Eu doping and Eu,Dy co-doping. The trap depths were calculated to be 0.54 eV for Ba 1.95 MgSi 2 O 7 :0.05Eu 2 + and 0.54 eV and 0.75 eV for Ba 1.93 MgSi 2 O 7 :0.05Eu 2 + ,0.02Dy 3 + phosphors. It was observed that co-doping with small amounts of Dy 3 + enhanced the thermoluminescence properties of Ba 2 MgSi 2 O 7 phosphor. Copyright © 2016 John Wiley & Sons, Ltd. [Correction added on 5 April 2016, after first online publication: The

  20. Energy transfer and colorimetric properties of Eu3+/Dy3+ co-doped Gd2(MoO4)3 phosphors

    International Nuclear Information System (INIS)

    Wan Jing; Cheng Lihong; Sun Jiashi; Zhong Haiyang; Li Xiangping; Lu Weili; Tian Yue; Lin Hai; Chen Baojiu

    2010-01-01

    Dy 3+ single-doped and Eu 3+ /Dy 3+ co-doped gadolinium molybdate (Gd 2 (MoO 4 ) 3 ) phosphors were synthesized by a traditional solid-state reaction method. The XRD was used to confirm the crystal structure of the phosphors. The energy transfer between Eu 3+ and Dy 3+ was observed and studied. The Eu 3+ concentration can hardly affect the blue and yellow emission intensities of Dy 3+ , and the Eu 3+ emission intensity increases with the increase of Eu 3+ concentration. Co-doping with Eu 3+ compensated the red emission component of the Dy 3+ doped Gd 2 (MoO 4 ) 3 phosphor. Introducing proper amount of Eu 3+ can improve the colorimetric performance of the phosphors.

  1. How to design greenhouse gas trading in the EU?

    International Nuclear Information System (INIS)

    Svendsen, G.T.

    2003-01-01

    A new and remarkable Green Paper about how to trade greenhouse gases (GHG) in the EU has recently been published by the Commission of the European Union. This to achieve the stated 8% reduction target level. The Green Paper raises ten questions about how greenhouse gas permit trading should be designed in the EU before year 2005. These ten questions can be compressed into four main issues, namely target group, allocation of emission allowances, how to mix emission trading with other instruments and fourth enforcement. In the literature, there is a strong need to guide decision-makers and stimulate academic debates concerning the actual design of a simple and workable GHG market model for the EU. This model must take both economic, administrative and political concerns into account so that it is feasible in practice. Based on our findings, we therefore develop a policy recommendation concerning the future design of GHG permit trading in the EU. (author)

  2. How to design greenhouse gas trading in the EU?

    International Nuclear Information System (INIS)

    Tinggaard Svendsen, G.; Vesterdal, M.

    2001-01-01

    A new and remarkable Green Paper about how to trade Greenhouse gases (GHG) in the EU has recently been published by the Commission of the European Union. This to achieve the stated 8% reduction target level. The Green paper raises ten questions about how greenhouse gas permit trading should be designed in the EU before year 2005. These ten questions can be compressed into four main issues, namely target group, allocation of emission allowances, how to mix emission trading with other instruments and fourth enforcement. In the literature, there is a strong need to guide decision-makers and stimulate academic debates concerning the actual design of a simple and workable GHG market model for the EU. This model must take both economic, administrative and political concerns into account so that it is feasible in practice. Based on our findings, we therefore develop a policy recommendation concerning the future design of GHG permit trading in the EU. (au)

  3. How to design greenhouse gas trading in the EU?

    Energy Technology Data Exchange (ETDEWEB)

    Tinggaard Svendsen, G; Vesterdal, M

    2001-07-01

    A new and remarkable Green Paper about how to trade Greenhouse gases (GHG) in the EU has recently been published by the Commission of the European Union. This to achieve the stated 8% reduction target level. The Green paper raises ten questions about how greenhouse gas permit trading should be designed in the EU before year 2005. These ten questions can be compressed into four main issues, namely target group, allocation of emission allowances, how to mix emission trading with other instruments and fourth enforcement. In the literature, there is a strong need to guide decision-makers and stimulate academic debates concerning the actual design of a simple and workable GHG market model for the EU. This model must take both economic, administrative and political concerns into account so that it is feasible in practice. Based on our findings, we therefore develop a policy recommendation concerning the future design of GHG permit trading in the EU. (au)

  4. Dependence of photoluminescence (PL) emission intensity on Eu3+ and ZnO concentrations in Y2O3:Eu3+ and ZnO·Y2O3:Eu3+ nanophosphors

    CSIR Research Space (South Africa)

    Mhlongo, GH

    2011-08-01

    Full Text Available Y2O3:Eu3+ and ZnO·Y2O3:Eu3+ nanophosphor powders with different concentrations of Eu3+ ions were synthesized by a sol–gel method and their luminescence properties were investigated. The red photoluminescence (PL) from Eu3+ ions with the main...

  5. The impact of the rebound effect of the use of first generation biofuels in the EU on greenhouse gas emissions: A critical review

    NARCIS (Netherlands)

    Smeets, E.M.W.; Tabeau, A.A.; Berkum, van S.; Moorad, J.; Meijl, van J.C.M.; Woltjer, G.B.

    2014-01-01

    An important objective of the mandated blending of biofuel in conventional gasoline and diesel in the EU is reducing greenhouse gas (GHG) emissions. An important assumption thereby is that biofuels replace the production and consumption of oil. However, recent literature challenges this assumption,

  6. Policy options for carbon taxation in the EU

    International Nuclear Information System (INIS)

    Laurent, Eloi; Le Cacheux, Jacques

    2010-06-01

    Even though the EU clearly leads the global fight against climate change and despite the additional reduction in emissions due to the global crisis and European recession, the ambitious objectives flagged in the '20-20-20 by 2020' strategy and 'climate-energy package' are probably out of reach if a more resolute and consistent policy of carbon taxation is not rapidly put in place. First, the EU is not as 'virtuous' as it may seem, and shows signs of a 'fatigue' in mitigating climate change; this is explained by the weak incentive structure of current climate institutions, due to both narrow coverage and insufficient stringency of the European 'Emission Trading Scheme' (ETS) - the European 'carbon market'-, and to excessive reliance on emission standards combined with weak energy taxation. Fears of losing competitiveness are a major argument against imposing a higher carbon price on industries, feeding tax competition both within the EU and vis-a-vis the rest of the world. Though not fully satisfactory, the Commission's recent proposal (a revision of the 2003 energy taxation directive introducing floors on national excises based on carbon content) would help solving the intra-EU conundrum. Alternatively, an extension of the EU ETS to households and the transport sector via the 'upstream' inclusion of fossil fuel dealers would also be a feasible solution. In order to answer the 'carbon leakage' argument and to send appropriate price signals to European consumers on extra-EU imports, a border adjustment mechanism - carbon levy or inclusion of importers into the EU ETS - is also necessary. Ultimately though, in order to make sure that economic agents face a uniform carbon price, a generalized carbon tax, in the form of a European 'Carbon Added Tax' (ECAT), would be the most effective instrument in the fight against climate change, as well as the pillar of a thorough tax

  7. Concentration quenching of Eu{sup 2+} doped Ca{sub 2}BO{sub 3}Cl

    Energy Technology Data Exchange (ETDEWEB)

    Seed Ahmed, H.A.A. [Department of Physics, University of the Free State, Bloemfontein, ZA 9300 (South Africa); Department of Physics, University of Khartoum, Khartoum (Sudan); Swart, H.C. [Department of Physics, University of the Free State, Bloemfontein, ZA 9300 (South Africa); Bergman, Peber [Department of Physics, Chemistry and Biology, Linköping University, Linköping (Sweden); Kroon, R.E., E-mail: KroonRE@Uufs.ac.za [Department of Physics, University of the Free State, Bloemfontein, ZA 9300 (South Africa)

    2016-03-15

    Highlights: • Ca{sub 2}BO{sub 3}Cl doped with Eu{sup 2+} prepared by solid state reaction. • Concentration quenching studied by intensity and lifetime measurements. • Accurate determination of the critical transfer distance. • Interaction mechanism verified to be dipole–dipole interactions. - Abstract: With the aim of determining the concentration quenching mechanism of Eu{sup 2+} doped Ca{sub 2}BO{sub 3}Cl, a series of phosphors with a varied Eu{sup 2+} concentration (Ca{sub 2−x}BO{sub 3}Cl:xEu{sup 2+}) was synthesized by the solid state reaction method. The phase structure was determined by X-ray diffraction. Photoluminescence (PL) measurements showed broad excitation and emission signatures of the allowed f–d transition of Eu{sup 2+} ions. The PL emission intensity was found to be increased by increasing the concentration of Eu{sup 2+} ions up to x = 0.03 and then decreased as a result of the concentration quenching effect. The lifetime of the emission from the Eu{sup 2+} ions was measured and the decrease in the lifetime with increasing Eu{sup 2+} concentration confirmed that non-radiative energy transfer occurred between Eu{sup 2+} ions. From the luminescence data, the value of the critical transfer distance was calculated as 1.5 nm and the corresponding concentration quenching mechanism was verified to be a dipole–dipole interaction.

  8. A cost–benefit analysis of the EU 20/20/2020 package

    International Nuclear Information System (INIS)

    Tol, Richard S.J.

    2012-01-01

    The European Commission did not publish a cost–benefit analysis for its 2020 climate package. This paper fills that gap, comparing the marginal costs and benefits of greenhouse gas emission reduction. The uncertainty about the marginal costs of climate change is large and skewed, and estimates partly reflect ethical choices (e.g., the discount rate). The 2010 carbon price in the EU Emissions Trading System can readily be justified by a cost–benefit analysis. Emission reduction is not expensive provided that policy is well-designed, a condition not met by planned EU policy. It is probably twice as expensive as needed, costing one in ten years of economic growth. The EU targets for 2020 are unlikely to meet the benefit–cost test. For a standard discount rate (3% pure rate of time preference), the benefit–cost ratio is rather poor (1/30)—so that benefits need to be very much higher, or costs very much lower than typically assumed to justify the 2020 targets. Only a very low discount rate (0% PRTP) would justify the 20% emission reduction target for 2020. - Highlights: ► First cost–benefit analysis of EU climate policy for 2020. ► Current carbon price in ETS can readily be justified by CBA. ► Emission targets for 2020 cannot be supported unless a low discount rate is chosen.

  9. Analisa Persepsi Glass Ceiling Pada Grup Hotel Accor Di Surabaya

    OpenAIRE

    Hariono, Ardhi Ananta Kurnia; Theios, Jefson

    2017-01-01

    Tujuan dilakukannya penelitian ini adalah untuk mengetahui persepsi karyawan perempuan akan glass ceiling pada grup hotel Accor Surabaya melalui hambatan pribadi, hambatan situasional, dan hambatan sosial. Penelitian ini di fokuskan pada kelompok umur dan status pernikahan. Metode pengumpulan data menggunakan survei kepada 50 karyawan perempuan yang mejabat pada posisi manajerial di grup Hotel Accor Surabaya. Hasil penelitian menunjukkan persepsi glass ceiling pada interval kecil. Untuk kelom...

  10. Constructing post-carbon institutions: Assessing EU carbon reduction efforts through an institutional risk governance approach

    International Nuclear Information System (INIS)

    LaBelle, Michael

    2012-01-01

    This paper examines three different governance approaches the European Union (EU) and Member States (MS) are relying on to reach a low carbon economy by 2050. Current governance literature explains the operational methods of the EU's new governance approach to reduce carbon emissions. However, the literature neglects to account for the perceived risks that inhibit the roll-out of new low carbon technology. This article, through a novel approach, uses a grounded theoretical framework to reframe traditional risk literature and provides a connection to governance literature in order to assess the ability of EU governance mechanisms to reduce carbon emissions. The empirical research is based on responses from European energy stakeholders who participated in a Delphi method discussion and in semi-structured interviews; these identified three essential requirements for carbon emissions to be reduced to near zero by 2050: (1) an integrated European energy network, (2) carbon pricing and (3) demand reduction. These features correspond to institutionalized responses by the EU and MS: the Agency for the Cooperation of Energy Regulators (ACER); European Union Emission Trading Scheme (EU ETS) and energy efficiency directives and policies integrated into existing MS institutions. The theoretical and empirical findings suggest that governance by facilitation (energy efficiency) fails to induce significant investment and new policy approaches and cannot be relied on to achieve requisite reductions in demand. Governance by negotiation (ACER) and governance by hierarchy (EU ETS) do reduce risks and may encourage the necessary technological uptake. The term ‘risk governance’ is used to explain the important role governance plays in reducing risks and advancing new technology and thereby lowering carbon emissions in the energy sector. - Highlights: ► This article assesses the role of EU institutions in reducing carbon emissions by 2050. ► Empirical research is based on Delphi

  11. Electron-spin polarization in tunnel junctions with ferromagnetic EuS barriers

    International Nuclear Information System (INIS)

    Hao, X.; Moodera, J.S.; Meservey, R.

    1989-01-01

    The authors report here spin-polarized tunneling experiments using non-ferromagnetic electrodes and ferromagnetic EuS barriers. Because of the conduction band in EuS splits into spin-up and spin-down subbands when the temperature is below 16.7 K, the Curie temperature of EuS, the tunnel barrier for electrons with different spin directions is different, therefore giving rise to tunnel current polarization. The spin-filter effect, as it may be called, was observed earlier, directly or indirectly, by several groups: Esaki et al. made a tunneling study on junctions having EuS and EuSe barriers; Thompson et al. studied Schottky barrier tunneling between In and doped EuS; Muller et al. and Kisker et al. performed electron field emission experiments on EuS-coated tungsten tips. The field emission experiments gave a maximum polarization of (89 + 7)% for the emitted electrons. Although the previous tunneling studies did not directly show electron polarization, their results were explained by the same spin- filter effect. This work uses the spin-polarized tunneling technique to show directly that tunnel current is indeed polarized and polarization can be as high as 85%

  12. Influence of ligands on the photoluminescent properties of Eu3+ in europium β-diketonate/PMMA-doped systems

    International Nuclear Information System (INIS)

    Liu, H.-G.; Park, Seongtae; Jang, Kiwan; Feng, X.-S.; Kim, Changdae; Seo, H.-J.; Lee, Y.-I.

    2004-01-01

    Three kinds of europium β-diketonates Eu(DBM) 3 , Eu(BA) 3 and Eu(TTA) 3 (DBM: Dibenzoylmethane; BA: 1-Benzoylacetone; TTA: Thenoyltrifluoroacetone) were doped in poly(methyl methacrylate) (PMMA) matrix. The doped systems were studied by using photoluminescent (PL) spectroscopy, emission decay experiments and X-ray diffractometry. Eu(III) ions in the doped Eu(DBM) 3 /PMMA systems have two distinct symmetric sites and the emission band changes greatly with the compositions. Eu(III) in the Eu(BA) 3 /PMMA systems gives only one symmetric site in the doped systems and the emission band changes slightly with the compositions. Although two distinct symmetric sites of Eu(III) can be distinguished in the doped systems of Eu(TTA) 3 /PMMA, the two sites have similar 5 D 0 lifetimes and the luminescent spectra almost do not change with the compositions. XRD reveals that crystallites were formed in the doped Eu(DBM) 3 /PMMA systems that have different crystalline structure from that of the chelate, and Eu(BA) 3 and Eu(TTA) 3 exist in amorphous state in the doped systems. The difference between the PL properties and structures of the doped systems for the three kinds of chelates should be attributed to different interactions between the chelate molecules and between the chelate and PMMA

  13. Good things do not always come in threes: On the excess cost of overlapping regulation in EU climate policy

    International Nuclear Information System (INIS)

    Böhringer, Christoph; Keller, Andreas; Bortolamedi, Markus; Rahmeier Seyffarth, Anelise

    2016-01-01

    Since the mid-1990's the European Union (EU) aims at pushing global climate policy. The objective is to promote international cooperation by the adoption of substantial EU-wide greenhouse gas emission reduction targets and their least-cost implementation. Our quantitative impact assessment of the EU Climate and Energy Package shows that the myriad of instruments used in the EU to curb greenhouse gas emissions is doomed to generate substantial excess cost. We conclude that EU climate and energy policy should better disentangle its choices of objectives, targets, and policy instruments on rigorous economic grounds in order to improve the coherence and overall cost-effectiveness of policy initiatives. - Highlights: •EU Climate and Energy Package almost quintuples costs for EU-wide emission abatement. •The main source of excess cost of EU climate policy are energy efficiency mandates.

  14. Production-phase greenhouse gas emissions arising from deliberate withdrawal and destruction of fresh fruit and vegetables under the EU's Common Agricultural Policy.

    Science.gov (United States)

    Porter, Stephen D; Reay, David S; Bomberg, Elizabeth; Higgins, Peter

    2018-08-01

    Since 1962 the Common Agriculture Policy (CAP) of the European Union (EU) has enabled payment of subsidy to some food producers for withdrawal of specific commodities - including fresh fruit and vegetables (FFV) - where market prices have fallen below a pre-set level. These deliberate withdrawals have led to large amounts of usable food (~60% of withdrawals) being destroyed on farms across the EU. Such wasted food incurs a significant climate change cost through its production-phase greenhouse gas (GHG) emissions. Here, we assess the magnitude of this FFV withdrawal and destruction, its spatial and temporal trends, and its associated GHG emissions between 1989 and 2015. We find the total mass of avoidable FFV losses occurring as a result of these EU CAP market interventions for this 26-year period to be 23.6Mt. The production-phase GHG emissions associated with the withdrawn FFV that was subsequently destroyed amount to 5.1Mt CO 2 e over this period. We also find that, with each successive Common Market Organisation (CMO) reform there has been a marked reduction (~95% between 1989 and 2015) in the quantity of such deliberate withdrawals. Surprisingly, however, whilst the absolute quantity of FFV withdrawn and destroyed has fallen, the proportion of withdrawals that is destroyed remained roughly static at an average of about 60%. Finally, to inform debate on action needed to address FFV specifically, and food loss and waste more generally, we highlight potential scenarios and mechanisms to reduce withdrawals, avoid FFV destruction and improve alternative use of withdrawn food in the future. Copyright © 2018 Elsevier B.V. All rights reserved.

  15. Integrated Environmental Assessment Modelling. Estimates of Emission and Measurement of Impacts. Final Report of the Spanish Subproject EU/Life Project

    International Nuclear Information System (INIS)

    Guardans, R.; Gimeno, B.S.; Bermejo, V.; Elvira, S.; Martin, F.; Palacios, M.; Rodriguez, E.; Donaire, I.

    2000-01-01

    This report describes the results of the Spanish participation in the project Coupling CORINAIR data to cost-effective emission reduction strategies based on critical thresholds. (EU/LIFE97/ENV/ FIN/336). The sub project has focused on three tasks: Develop tools to improve knowledge on the spatial and temporal details of emissions of air pollutants in Spain, Exploit existing experimental information on plant response to air pollutants in temperate ecosystems and Integrate these findings in a modelling framework that can asses with more accuracy the impact of air pollutants to temperate ecosystems. The results obtained during the execution of this project have significantly improved the models of the impact of alterative emission control strategies on ecosystems and crops in the Iberian Peninsula. (Author) 375 refs

  16. Effect of Number of Blades on Performance of Ceiling Fans

    Directory of Open Access Journals (Sweden)

    Adeeb Ehsan

    2015-01-01

    Full Text Available In this paper, the effect of number of blades on ceiling fan performance is discussed. This approach helps to satisfy tradeoff between high air flow (performance and power consumption (energy efficiency. Specifically, variation from two to six blades is considered with nonlinear forward sweep profile. Reynolds Averaged Navier-Stokes (RANS technique is used to model the flow field induced by the ceiling fan inside a generic room. The performance is gauged through response parameters namely volumetric flow rate, mass flow rate, torque and energy efficiency. The results indicate that mass and volumetric flow rates are maximized for six blade configuration and energy efficiency is maximized for two blade configuration. The study indicates the importance of tradeoff between high air flow through ceiling fan and associated energy efficiency.

  17. Do Asian American Faculty Face a Glass Ceiling in Higher Education?

    Science.gov (United States)

    Lee, Sharon M.

    2002-01-01

    Evaluated the glass ceiling hypothesis in relation to Asian American faculty using data from the 1993 National Study of Post-Secondary Faculty for 1,019 Asian American faculty members. Data limitations prevent concluding that such faculty do or do not face a glass ceiling; however, baseline findings for future research are established. (SLD)

  18. Multicolor light emitters based on energy exchange between Tb and Eu ions co-doped into ultrasmall β-NaYF 4 nanocrystals

    KAUST Repository

    Podhorodecki, Artur P.

    2012-01-01

    Multicolor emission is reported from ultrasmall (<10 nm) β-NaYF4:Eu,Tb nanocrystals depending on the excitation wavelengths or emission detection delay time. Detailed optical investigations of three samples (NaYF4:Eu, NaYF4:Tb and NaYF4:Eu,Tb) obtained by a co-thermolysis method have been carried out. Photoluminescence, photoluminescence excitation and emission decay time obtained at different excitation wavelengths have been measured. Excitation mechanisms of Eu and Tb ions have been explained based on the experimental results and calculations using Judd-Ofelt theory. It has been shown that efficient energy transfer from Tb to Eu ions accounts for the efficient red emission of NaYF4:Tb,Eu nanocrystals. © The Royal Society of Chemistry 2012.

  19. Photoluminescence varied by selective excitation in BiGdWO6:Eu3+ phosphor

    Science.gov (United States)

    Pavani, K.; Graça, M. P. F.; Kumar, J. Suresh; Neves, A. J.

    2017-12-01

    Eu3+ doped bismuth gadolinium tungstate (BGW), a simplest member of Aurivillius family of layered perovskites, was synthesized by solid-state reaction method. Structural characterisation has been performed by X-Ray diffraction (XRD), Raman spectroscopy, Fourier Transform Infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). Band gap of the host matrix has been calculated using reflectance and absorption spectra. Three different mechanisms were found to explain the excitation of Eu3+ ions and are described in detail. Photoluminescence (PL) spectra of the BGW phosphor doped with Eu3+ ions consist of major emission lines associated with 5D0 → 7FJ (J = 0, 1, 2, 3 and 4) of Eu3+ ion. Site selective PL excitation and emission indicates that Eu3+ ions doped in BiGdWO6 are sensitive to the excitation wavelength without change in the structure. Change in emission spectra were observed when the excitation wavelength was changed. Judd-Ofelt (J-O) parameters were determined from the indirect method to interpret the interactions between the host and dopant ions along with detailed analysis of lifetime measurements.

  20. Luminescent properties of green- or red-emitting Eu2+-doped Sr3Al2O6 for LED

    International Nuclear Information System (INIS)

    Zhang Jilin; Zhang Xinguo; Shi Jianxin; Gong Menglian

    2011-01-01

    Eu 2+ -doped Sr 3 Al 2 O 6 (Sr 3-x Eu x Al 2 O 6 ) was synthesized by a solid-state reaction under either H 2 and N 2 atmosphere or CO atmosphere. When H 2 was used as the reducing agent, the phosphor exhibited green emission under near UV excitation, while CO was used as the reducing agent, the phosphor mainly showed red emission under blue light excitation. Both emissions belong to the d-f transition of Eu 2+ ion. The relationship between the emission wavelengths and the occupation of Eu 2+ at different crystallographic sites was studied. The preferential substitution of Eu 2+ into different Sr 2+ cites at different reaction periods and the substitution rates under different atmospheres were discussed. Finally, green-emitting and red-emitting LEDs were fabricated by coating the phosphor onto near UV- or blue-emitting InGaN chips. - Highlights: →Sr 3 Al 2 O 6 :Eu 2+ is synthesized by a solid-state reaction under different atmospheres. →Phosphor obtained under H 2 +N 2 atmosphere emits green light under NUV excitation. →Phosphor obtained under CO atmosphere emits red light under blue light excitation. →Different emission wavelengths are due to Eu 2+ in different Sr 2+ sites. →The preferential substitution and the substitution rates of Eu 2+ are discussed.

  1. Carbon Emission Trading. A survey of regional and national emission trading schemes outside the European Union; Handel med utslaeppsraetter. Kartlaeggning av EU-externa regionala och nationella system foer handel med koldioxidutslaepp

    Energy Technology Data Exchange (ETDEWEB)

    Widegren, Karin

    2007-03-15

    For those countries that ratified the Kyoto Protocol this is naturally one of the most important incentives for the introduction of mandatory measures such as emissions trading schemes. At the same time, there are major similarities between the political discussions in countries that ratified the Kyoto Protocol and countries that did not. In all countries there is a great interest in market-based regulation such as emissions trading, at the same time as the political difficulties in achieving unity on the limits and shaping of the systems are very substantial. In countries with a federal government, operators at the regional level frequently have a prominent role. The driving force for the regional players is frequently a desire to influence the federal policy from below at the same time as goodwill is created and a learning process is developed that may become a competitive advantage the day a federal system is introduced. Regional initiatives and the introduction of different voluntary programs for emissions trading have also contributed to an increased interest on the part of industry and industrial operators. They have in several cases actively participated in the design of such programs. When it comes to the operational status of the different schemes none of the studied countries is expected to have a nationally compulsory trading system in operation prior to 2010. Most initiatives are at the initial stage and have been delayed many times on account of significant administrative and political difficulties. It may be established that as regards market volume, liquidity and practical experiences EU ETS is in a class of its own. The most common trading system that is planned or debated is of the type 'cap and trade'. Systems focus almost without exception on the energy sector and on emissions of carbon dioxide. Frequently, proposals include a wide variety of approved emission credits (offset). The design of these emission credits often reflects other

  2. Carbon Emission Trading. A survey of regional and national emission trading schemes outside the European Union; Handel med utslaeppsraetter. Kartlaeggning av EU-externa regionala och nationella system foer handel med koldioxidutslaepp

    Energy Technology Data Exchange (ETDEWEB)

    Widegren, Karin

    2007-03-15

    For those countries that ratified the Kyoto Protocol this is naturally one of the most important incentives for the introduction of mandatory measures such as emissions trading schemes. At the same time, there are major similarities between the political discussions in countries that ratified the Kyoto Protocol and countries that did not. In all countries there is a great interest in market-based regulation such as emissions trading, at the same time as the political difficulties in achieving unity on the limits and shaping of the systems are very substantial. In countries with a federal government, operators at the regional level frequently have a prominent role. The driving force for the regional players is frequently a desire to influence the federal policy from below at the same time as goodwill is created and a learning process is developed that may become a competitive advantage the day a federal system is introduced. Regional initiatives and the introduction of different voluntary programs for emissions trading have also contributed to an increased interest on the part of industry and industrial operators. They have in several cases actively participated in the design of such programs. When it comes to the operational status of the different schemes none of the studied countries is expected to have a nationally compulsory trading system in operation prior to 2010. Most initiatives are at the initial stage and have been delayed many times on account of significant administrative and political difficulties. It may be established that as regards market volume, liquidity and practical experiences EU ETS is in a class of its own. The most common trading system that is planned or debated is of the type 'cap and trade'. Systems focus almost without exception on the energy sector and on emissions of carbon dioxide. Frequently, proposals include a wide variety of approved emission credits (offset). The design of these emission credits often reflects other political

  3. EU ETS Allocation. Evaluation of present system and options beyond 2012

    Energy Technology Data Exchange (ETDEWEB)

    Sijm, J.P.M. (ed.) [ECN Policy Studies, Petten (Netherlands); Berk, M.M.; Den Elzen, M.G.J.; Van den Wijngaart, R.A. [Netherlands Environmental Assessment Agency NMP, Bilthoven (Netherlands)

    2007-03-15

    This study assesses various options for EU (European Union) burden sharing and EU ETS (Emissions Trading System) allocation beyond 2012, based on a sample of policy evaluation criteria and a review of the literature on (1) international and EU burden sharing of future GHG mitigation commitments, and (2) allocation of GHG emission allowances among countries, sectors and emitting installations. It shows that these options score differently with regard to a variety of individual evaluation criteria (such as environmental effectiveness, economic efficiency, social equity or political acceptability), while the overall performance of these options depends on both the selection, interpretation, weighing and adding of these criteria.

  4. Optical and spectroscopic properties of Eu-doped tellurite glasses and glass ceramics

    International Nuclear Information System (INIS)

    Stambouli, W.; Elhouichet, H.; Gelloz, B.; Férid, M.

    2013-01-01

    Tellurite glasses doped with trivalent europium were prepared by the conventional melt quenching technique, in the chemical composition of (85−x) TeO 2 +5La 2 O 3 +10TiO 2 +xEu 2 O 3 by varying the concentration of the rare-earth ion in the order 0.5, 1 and 1.5 mol%. Using Judd–Ofelt analysis, we calculated intensity parameters (Ω 2 and Ω 4 ), spontaneous emission probabilities, the radiative lifetime, luminescence branching factors, the quantum yield of luminescence, and the stimulated emission cross-sections for 5 D 0 → 7 F 2 transition. The change in optical properties with the variation of Eu 3+ ion concentration have been discussed and compared with other glasses. The luminescence intensity ratio, quantum efficiency and emission cross-section values support that the TeEu1.5 tellurite glass is a suitable candidate for red laser source applications. Optical properties for Eu 3+ doped tellurite glass, heated for different temperature, were investigated. Crystalline phases for α-TeO 2 , γ-TeO 2 and TiTe 3 O 8 system were determined by the XRD method. The effect of heat treatment on luminescence properties in the tellurite glass was discussed. By using Eu 3+ as a probe, the local structure of rare-earth ion in tellurite glass, vitro-ceramic and ceramic glass has been investigated. The evaluated J–O intensity parameters have been used to calculate different radiative and laser characteristic parameters of the 5 D 0 excited level. The large magnitudes of stimulated emission cross-section (σ e ), branching ratio (β) and Gain bandwidth (σ e ×Δλ eff ) obtained for 5 D 0 → 7 F 2 (613 nm) transition for ceramic glass indicate that the present glass ceramic is promising host material for Eu 3+ doped fiber amplifiers. The measured lifetime of 5 D 0 excited state increases with increase of the heat treatment which further indicate that some Eu 3+ ions were successfully embedded in the crystal phase and prove the low phonon energy environment of Eu 3+ ions

  5. Orange and reddish-orange light emitting phosphors: Sm{sup 3+} and Sm{sup 3+}/Eu{sup 3+} doped zinc phosphate glasses

    Energy Technology Data Exchange (ETDEWEB)

    Meza-Rocha, A.N., E-mail: ameza@fis.cinvestav.mx [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, P.O. Box 55-534, 09340 México D.F., México (Mexico); Speghini, A. [Dipartimento di Biotecnologie, Universita di Verona and INSTM, UdR Verona, Strada Le Grazie 15, I-37314 Verona (Italy); IFAC CNR, Nello Carrara Institute of Applied Physics, MDF Lab, I-50019 Sesto Fiorentino, FI (Italy); Bettinelli, M. [Dipartimento di Biotecnologie, Universita di Verona and INSTM, UdR Verona, Strada Le Grazie 15, I-37314 Verona (Italy); Caldiño, U. [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, P.O. Box 55-534, 09340 México D.F., México (Mexico)

    2015-11-15

    A spectroscopy study of Sm{sup 3+} and Sm{sup 3+}/Eu{sup 3+} doped zinc phosphate glasses is performed through photoluminescence spectra and decay time profile measurements. Under Sm{sup 3+} excitation at 344 nm, the Sm{sup 3+} singly doped glass shows an orange global emission with x=0.579 and y=0.414 CIE1931 chromaticity coordinates, whereas the Sm{sup 3+}/Eu{sup 3+} co-doped sample exhibits orange overall emissions (x=0.581 and y=0.398, and x=0.595 and y=0.387) and reddish-orange overall emission (x=0.634 and y=0.355) upon excitations at 344, 360 and 393 nm, respectively. Such luminescence from the co-doped sample is originated by the simultaneous emission of Sm{sup 3+} and Eu{sup 3+}. Under Sm{sup 3+} excitation at 344 and 360 nm, the Eu{sup 3+} emission is sensitized and enhanced by Sm{sup 3+} through a non-radiative energy transfer process. The non-radiative nature was inferred from the shortening of the Sm{sup 3+} lifetime observed in the Sm{sup 3+}/Eu{sup 3+} co-doped sample. An analysis of the Sm{sup 3+} emission decay time profiles using the Inokuti–Hirayama model suggests that an electric quadrupole–quadrupole interaction into Sm–Eu clusters might dominate the energy transfer process, with an efficiency of 0.17. - Highlights: • Zinc phosphate glasses are optically activated with Sm{sup 3+}/Eu{sup 3+} (ZPOSmEu). • Non-radiative energy transfer Sm{sup 3+}→Eu{sup 3+} takes place in ZPOSmEu. • ZPOSmEu overall emission can be modulated with the excitation wavelength. • ZPOSmEu might be useful as orange/reddish-orange phosphor for UV-white LEDs.

  6. Analysis of the EU policy package on climate change and renewables

    International Nuclear Information System (INIS)

    Capros, Pantelis; Mantzos, Leonidas; Parousos, Leonidas; Tasios, Nikolaos; Klaassen, Ger; Van Ierland, Tom

    2011-01-01

    In 2009 the EU decided to reduce greenhouse gas emissions at least by 20% in 2020 compared to 1990 and to supply 20% of energy needs by 2020 from renewable energy sources. This paper uses an energy model coupled with a non-CO 2 greenhouse gas model to assess the range of policy options that were debated to meet both targets. Policy options include trading of renewable targets, carbon trading in power plants and industry and the use of the Clean Development Mechanism to improve cost-efficiency. The models also examined fairness by analysing the distribution of emission reduction in the non-emission trading sector, the distribution of CO 2 allowances in the emission trading sector and the reallocation of renewable targets across Member States. The overall costs of meeting both targets range from 0.4% to 0.6% of GDP in 2020 for the EU as a whole. The redistribution mechanisms employed significantly improve fairness compared to a cost-effective solution. - Research highlights: → Meeting the EU's greenhouse gas and renewable targets costs 0.4-0.6% of GDP. → Trading national targets for renewable energy reduces costs. → Carbon trading in power plants and industry and CDM also lowers costs. → The redistribution mechanisms agreed by the EU significantly improve fairness.

  7. Assessing the EU Commission's proposals for the new EU ETS directive by 2030: French public-private initiative 'COPEC' - first results Partnership Market Readiness Assembly, 12 March, 2015

    International Nuclear Information System (INIS)

    2015-01-01

    The Enerdata research program - 'Coordination of EU Policies on Energy and CO_2 by 2030' (COPEC) was designed to provide trustful and independent quantified analysis of the functioning of the EU ETS. The program is focused on the economic impacts and examines the conditions for improving its environmental and economic effectiveness. The analysis consists of: - The overview of academic work to an audience of decision makers; - The production of new economic and environmental analyses; - The modeling of different 2030 scenarios. The main findings about the interactions between EU ETS, RES and EE targets are the following: In 2005-2012, 2020 RES and EE targets played an important role on EU ETS emissions abatements and therefore on the price of CO_2 in the EU ETS. By 2030, the GHG target alone is enough to achieve GHG emission reductions and RES integration, economic viability of an energy efficiency objective is not given. (authors)

  8. Numerical Prediction of Airflow in a Room with Ceiling-Mounted Obstacles

    DEFF Research Database (Denmark)

    Svidt, Kjeld

    In ventilated rooms the air inlet device is often placed close to the ceiling. The air inlet will form a wall jet or a reattached wall jet. The wall jet may be disturbed by ceilingmounted obstacles such as light fittings or ceiling beams which, in some cases, can cause the air jet to be deflected...

  9. Eu-, Tb-, and Dy-Doped Oxyfluoride Silicate Glasses for LED Applications

    DEFF Research Database (Denmark)

    Zhu, C.F.; Wang, J.; Zhang, M.M.

    2014-01-01

    Luminescence glass is a potential candidate for the light-emitting diodes (LEDs) applications. Here, we study the structural and optical properties of the Eu-, Tb-, and Dy-doped oxyfluoride silicate glasses for LEDs by means of X-ray diffraction, photoluminescence spectra, Commission Internationale...... de L’Eclairage (CIE) chromaticity coordinates, and correlated color temperatures (CCTs). The results show that the white light emission can be achieved in Eu/Tb/Dy codoped oxyfluoride silicate glasses under excitation by near-ultraviolet light due to the simultaneous generation of blue, green, yellow......, and red-light wavelengths from Tb, Dy, and Eu ions. The optical performances can be tuned by varying the glass composition and excitation wavelength. Furthermore, we observed a remarkable emission spectral change for the Tb3+ single-doped oxyfluoride silicate glasses. The 5D3 emission of Tb3+ can...

  10. Eu/Tb ions co-doped white light luminescence Y2O3 phosphors

    International Nuclear Information System (INIS)

    Tu Dong; Liang Yujun; Liu Rong; Li Daoyi

    2011-01-01

    Y 2 O 3 :Eu 3+ , Tb 3+ phosphors with white emission are prepared with different doping concentration of Eu 3+ and Tb 3+ ions and synthesizing temperatures from 750 to 950 deg. C by the co-precipitation method. The resulted phosphors were characterized by X-ray diffraction (XRD) and photoluminescence (PL) spectroscopy. The results of XRD indicate that the crystallinity of the synthesized samples increases with enhancing the firing temperature. The photoluminescence spectra indicate the Eu 3+ and Tb 3+ co-doped Y 2 O 3 phosphors show five main emission peaks: three at 590, 611 and 629 nm originate from Eu 3+ and two at 481 and 541 nm originate from Tb 3+ , under excitation of 250-320 nm irradition. The white light luminescence color could be changed by varying the excitation wavelength. Different concentrations of Eu 3+ and Tb 3+ ions were induced into the Y 2 O 3 lattice and the energy transfer from Tb 3+ →Eu 3+ ions in these phosphors was found. The Commission International de l'Eclairage (CIE) chromaticity shows that the Y 2 O 3 :Eu 3+ , Tb 3+ phosphors can obtain an intense white emission. - Highlights: → Novel phosphors Y 2 O 3 :Eu 3+ , Tb 3+ have been synthesized by co-precipitation method. → Samples emit white light with excellent color coordinates under UV excitation. → Luminescence color could be changed by varying the excitation wavelength. → Energy transfer from Tb 3+ →Eu 3+ ions in these phosphors was found.

  11. Expression of sensitized Eu(3+) luminescence at a multivalent interface

    NARCIS (Netherlands)

    Hsu, Shu-Han; Yilmaz, M Deniz; Blum, Christian; Subramaniam, Vinod; Reinhoudt, David N; Velders, Aldrik H; Huskens, Jurriaan

    2009-01-01

    Assembly of a mixture of guest-functionalized antenna and Eu(3+)-complexed ligand molecules in a patterned fashion onto a receptor surface provides efficient localized sensitized emission. Coordination of a carboxylate group of the antenna to the Eu(3+) center and noncovalent anchoring of both

  12. Luminescent characteristic of the CsBr phosphor activated with Eu{sup 2+} and Mn{sup 2+} ions

    Energy Technology Data Exchange (ETDEWEB)

    Téllez-Flores, E., E-mail: bluedays8i@hotmail.com [Programa de Posgrado en Ciencias (Física), Departamento de Investigación en Física, Universidad de Sonora, Rosales y Blvd. Transversal S/N, 83000 Hermosillo, Son., México (Mexico); Aceves, R., E-mail: raceves@cifus.uson.mx [Centro de Investigación en Física, Universidad de Sonora, Apartado Postal 5-88, 83190 Hermosillo, Son., México (Mexico); Pérez-Salas, R., E-mail: rperez@cifus.uson.mx [Centro de Investigación en Física, Universidad de Sonora, Apartado Postal 5-88, 83190 Hermosillo, Son., México (Mexico); Camarillo, I., E-mail: as99@xanum.uam.mx [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, Col. Vicentina, Delegación Iztapalapa, C.P. 09340 México D.F. (Mexico); Caldiño, U., E-mail: cald@xanum.uam.mx [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, Col. Vicentina, Delegación Iztapalapa, C.P. 09340 México D.F. (Mexico)

    2013-12-15

    Spectra of excitation and emission were measured at RT and 15 K in crystals quenched (Q) of CsBr:Eu{sup 2+}, CsBr:Mn{sup 2+} and CsBr:Eu{sup 2+},Mn{sup 2+}. Emission bands at 444, 480, 520 and 570 nm with different relative intensities are generated in the samples after UV excitation. The blue band at 444 nm was ascribed with unknown clusters or aggregated centers (AC) of dipoles type Eu{sup 2+}–V{sub C}{sup −} and insulated dipole centers (IDC) like Eu{sup 2+}–O{sup 2−}. The bands at 480, 520 and 570 nm were assigned to Cs{sub 4}EuBr{sub 6} nanocrystals; AC containing MnBr{sub 4}{sup 2−} units in tetrahedral symmetry and another yet unidentified AC defect, respectively. In crystals of CsBr:Eu{sup 2+},Mn{sup 2+} the excitation and emission spectra taken at 15 K show no clear evidence of an energy transfer mechanism. Instead, the results suggest that the emission is produced by direct excitation of the ions of Eu{sup 2+} and Mn{sup 2+}. Accordingly, single- or double-doped CsBr crystals may contain the same type of defects, either AC and/or IDC. -- Highlights: • The PL consists of several overlapping bands in the entire visible region. • The emission bands were ascribed to dipoles, aggregated and nanocrystals of different nature. • No clear evidence of energy transfer, meaning Eu and Mn pairs are not formed. • The material shows potential characteristics for its use as LED to white emission.

  13. Comparative study of the thermoluminescence between the materials {alpha}-Al{sub 2}O{sub 3}:C, KCl:Eu{sup 2+}, KBr: Eu{sup 2+} and VYCOR; Estudio comparativo de la termoluminiscencia entre los materiales {alpha}-Al{sub 2}O{sub 3}: C, KCl:Eu{sup 2+}, KBr: Eu{sup 2+} y VYCOR

    Energy Technology Data Exchange (ETDEWEB)

    Pedroza M, M. [Programa de Posgrado en Fisica de Materiales, Centro de Investigacion Cientifica y de Educacion Superior de Ensenada, Apdo. Postal 2681, C.P. 22800, Ensenada, Baja California (Mexico); Melendrez, R.; Perez S, R.; Aceves, R.; Piters, T.M.; Barboza F, M. [Centro de Investigacion en Fisica, Universidad de Sonora, Apdo. Postal 5-088, C.P. 83190 Hermosillo, Sonora (Mexico)

    1999-07-01

    It is presented some investigation results related to the thermoluminescence curves (Tl), Tl emission and the spectra of excitation of thermoluminescence in the ultraviolet region of 190 to 250 nm in the materials {alpha}-Al{sub 2}O{sub 3}:C, KCl: Eu{sup 2+}, KBr: Eu{sup 2+} and the Vycor glass. It was able to be observed that the Tl emission for the first three materials exists around 420 nm and in the case of Vycor the emission consists of two Tl peaks where the most low temperature is a band more wide centered in 460 nm and the other band of high temperature emits in 470 nm. In the excitation curves of Tl were obtained centered bands around 230 nm for KCl: Eu{sup 2+}, 235 nm for KBr: Eu{sup 2+}, 220 nm for the alumina and 195 nm for the Vycor. From the results it was able to be appreciated that this last has a minor relative intensity with respect to the others materials but also the region in which works there was an alone band between the 190 to 205 nm. This fact makes the material be very selective in the ultraviolet region of greatest energy. (Author)

  14. An Efficient Ceiling-view SLAM Using Relational Constraints Between Landmarks

    Directory of Open Access Journals (Sweden)

    Hyukdoo Choi

    2014-01-01

    Full Text Available In this paper, we present a new indoor 'simultaneous localization and mapping‘ (SLAM technique based on an upward-looking ceiling camera. Adapted from our previous work [17], the proposed method employs sparsely-distributed line and point landmarks in an indoor environment to aid with data association and reduce extended Kalman filter computation as compared with earlier techniques. Further, the proposed method exploits geometric relationships between the two types of landmarks to provide added information about the environment. This geometric information is measured with an upward-looking ceiling camera and is used as a constraint in Kalman filtering. The performance of the proposed ceiling-view (CV SLAM is demonstrated through simulations and experiments. The proposed method performs localization and mapping more accurately than those methods that use the two types of landmarks without taking into account their relative geometries.

  15. Frameworks for pricing greenhouse gas emissions and the policy objectives they promote

    International Nuclear Information System (INIS)

    Higgins, Paul A.T.

    2013-01-01

    Four cost-effective frameworks for pricing greenhouse gas emissions currently receive widespread attention: cap-and-trade, emission fees, and hybrid cap-and-trade approaches that include upper or lower limits on permit prices (price ceilings or floors). This paper develops a fifth framework that uses an emission fee with an upper limit on the quantity of emissions—a quantity ceiling—and compares the impact of each framework on emission prices and quantities. Cap-and-trade with a price ceiling minimizes price increases for emitting activities in all cases whereas an emission fee with a quantity ceiling maximizes emissions reductions. Thus, the choice of framework influences policy outcomes because each framework is more or less suited to particular policy goals. Whether pursuing one potential policy goal serves society's interests best depends on the eventual consequences of climate damage and emissions pricing, which are uncertain when policy choices are made. Policy updating over time may reduce but likely cannot entirely eliminate the differences in outcome that arise due to framework choice. Therefore, the “best” framework for emissions pricing depends on subjective preferences regarding the relative importance of different policy objectives, most notably whether one is more risk averse to climate damages or emissions price increases. - Highlights: • This article develops and examines a carbon tax that includes a quantity constraint on emissions. • This approach maximizes climate protection in all cases, unlike existing policy alternatives. • This promotes rapid reductions in emissions if mitigation is easy without risk to long term targets. • This analysis reveals that different policy frameworks promote different policy goals. • The analysis helps round out ongoing policy discussions over how to deal with climate change

  16. A new promising phosphor, Na3La2(BO3)3:Ln (Ln=Eu, Tb)

    International Nuclear Information System (INIS)

    Li Zhihua; Zeng Jinghui; Zhang Guochun; Li Yadong

    2005-01-01

    We present an efficient way to search a host for ultraviolet (UV) phosphor from UV nonlinear optical (NLO) materials. With the guidance, Na 3 La 2 (BO 3 ) 3 (NLBO), as a promising NLO material with a broad transparency range and high damage threshold, was adopted as a host material for the first time. The lanthanide ions (Tb 3+ and Eu 3+ )-doped NLBO phosphors have been synthesized by solid-state reaction. Luminescent properties of the Ln-doped (Ln=Tb 3+ , Eu 3+ ) sodium lanthanum borate were investigated under UV ray excitation. The emission spectrum was employed to probe the local environments of Eu 3+ ions in NLBO crystal. For red phosphor, NLBO:Eu, the measured dominating emission peak was at 613 nm, which is attributed to 5 D - 7 F 2 transition of Eu 3+ . The luminescence indicates that the local symmetry of Eu 3+ in NLBO crystal lattice has no inversion center. Optimum Eu 3+ concentration of NLBO:Eu 3+ under UV excitation with 395 nm wavelength is about 30 mol%. The green phosphor, NLBO:Tb, showed bright green emission at 543 with 252 nm excited light. The measured concentration quenching curve demonstrated that the maximum concentration of Tb 3+ in NLBO was about 20%. The luminescence mechanism of Ln-doped NLBO (Tb 3+ and Eu 3+ ) was analyzed. The relative high quenching concentration was also discussed

  17. Implementing the EU climate and energy package with the economic crisis

    International Nuclear Information System (INIS)

    Kerebel, C.

    2009-01-01

    In March 2007, the European heads of state and government agreed at their European Council upon a 20% greenhouse gas (GHG) emission reduction target compared to 1990-levels and a 20% share of renewable energies in EU's final energy consumption by 2020. To implement these commitments, the European Commission prepared a set of legislative proposals - the so-called 'Climate and Energy Package' - which was jointly endorsed by the European Parliament and the European Council in Dec. 2008 and formally adopted in April 2009. This new policy will run from 2013 to 2020. Hence, the reinforcement of European Union's energy and climate policy in the decade to come was decided and prepared in 2007-2008. But in the meantime, the economic conditions worldwide and in Europe more particularly have radically changed compared to what they were in 2007-2008 when the package was designed. The European Commission has drafted its proposals for the Climate and Energy Package following the outcomes of an impact assessment based on several modeling tools. These modeling tools were not used for determining the 20-20 in 2020 targets or checking their feasibility - those were political targets decided by the European Council in March 2007. The models served to assess the effects and costs of different allocation methodologies. In its drafting proposals, the Commission projected an annual Gross Domestic Product (GDP) growth of 2.2% on average until 2010 in the EU and a 2.4% growth between 2010 and 2020. But because of the economic crisis, the European Union has on the contrary seen a sharp fall of its GDP in 2009: according to the latest forecast by the International Monetary Fund (IMF), which is quite similar with forecasts from other organizations, such as the European Commission or the OECD, the EU-27 should see its GDP decrease by 4.2% in 2009. Opinions are divided when it comes to the question of when and how fast the economy recovers. The IMF has predicted a rather flat GDP growth in 2010

  18. Implementing the EU climate and energy package with the economic crisis

    Energy Technology Data Exchange (ETDEWEB)

    Kerebel, C.

    2009-07-01

    In March 2007, the European heads of state and government agreed at their European Council upon a 20% greenhouse gas (GHG) emission reduction target compared to 1990-levels and a 20% share of renewable energies in EU's final energy consumption by 2020. To implement these commitments, the European Commission prepared a set of legislative proposals - the so-called 'Climate and Energy Package' - which was jointly endorsed by the European Parliament and the European Council in Dec. 2008 and formally adopted in April 2009. This new policy will run from 2013 to 2020. Hence, the reinforcement of European Union's energy and climate policy in the decade to come was decided and prepared in 2007-2008. But in the meantime, the economic conditions worldwide and in Europe more particularly have radically changed compared to what they were in 2007-2008 when the package was designed. The European Commission has drafted its proposals for the Climate and Energy Package following the outcomes of an impact assessment based on several modeling tools. These modeling tools were not used for determining the 20-20 in 2020 targets or checking their feasibility - those were political targets decided by the European Council in March 2007. The models served to assess the effects and costs of different allocation methodologies. In its drafting proposals, the Commission projected an annual Gross Domestic Product (GDP) growth of 2.2% on average until 2010 in the EU and a 2.4% growth between 2010 and 2020. But because of the economic crisis, the European Union has on the contrary seen a sharp fall of its GDP in 2009: according to the latest forecast by the International Monetary Fund (IMF), which is quite similar with forecasts from other organizations, such as the European Commission or the OECD, the EU-27 should see its GDP decrease by 4.2% in 2009. Opinions are divided when it comes to the question of when and how fast the economy recovers. The IMF has predicted a rather

  19. Synthesis and characterization of a liquid Eu precursor (EuCp{sup pm}{sub 2}) allowing for valence control of Eu ions doped into GaN by organometallic vapor phase epitaxy

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Brandon, E-mail: bmitchell@wcupa.edu [Department of Physics, West Chester University, West Chester, PA, 19383 (United States); Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871 (Japan); Koizumi, Atsushi; Nunokawa, Takumi; Wakamatsu, Ryuta; Lee, Dong-gun; Saitoh, Yasuhisa; Timmerman, Dolf [Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871 (Japan); Kuboshima, Yoshinori; Mogi, Takayuki; Higashi, Shintaro; Kikukawa, Kaoru [Kojundo Chemical Laboratory Co., Ltd., 5-1-28 Chiyoda, Sakado, Saitama, 350-0284 (Japan); Ofuchi, Hironori; Honma, Tetsuo [Japan Synchrotron Radiation Research Institute (JASRI/SPring-8), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo, 679-5198 (Japan); Fujiwara, Yasufumi, E-mail: fujiwara@mat.eng.osaka-u.ac.jp [Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871 (Japan)

    2017-06-01

    A liquid Eu precursor, bis(normal-propyl-tetramethylcyclopentadienyl)europium has been synthesized. This precursor exists as a liquid at temperatures higher than 49 °C, has a moderately high vapor pressure, contains no oxygen in its molecular structure, and can be distilled to high purity. These properties make it ideal for doping using a chemical vapor or atomic layer deposition method, and provide a degree of control previously unavailable. As a precursor the Eu exists in the divalent valance state, however, once doped into GaN by organometallic vapor phase epitaxy, the room-temperature photoluminescence of the Eu-doped GaN exhibited the typical red emission due to the intra-4f shell transition of trivalent Eu. After variation of the growth temperature, it was found that divalent Eu could be stabilized in the GaN matrix. By tuning the Fermi level through donor doping, the ratio of Eu{sup 2+} to Eu{sup 3+} could be controlled. The change in valence state of the Eu ions was confirmed using X-ray absorption near-edge structure. - Highlights: • A liquid Eu precursor was synthesized and its properties were characterized. • Precursor has a low melting point and a moderately high vapor pressure. • Does not contain oxygen in its molecular structure. • Eu can changed its valance state when incorporated into GaN. • Valence state of Eu in GaN can be controlled by donor doping.

  20. Diffuse Ceiling Ventilation and the Influence of Room Height and Heat Load Distribution

    DEFF Research Database (Denmark)

    Nielsen, Peter Vilhelm; Vilsbøll, Rasmus W; Liu, Li

    2015-01-01

    Diffuse ceiling (inlet) ventilation is an air distribution system that supplies air from the entire ceiling surface, giving a low supply velocity. The flow pattern in the room is controlled by the heat sources. The system generates high mixing flow and the air velocities in the room are expected...... to be not much influenced by the flow rate to the room but dependent on the heat load. Previous studies have shown that diffuse ceiling ventilation has an ability to remove large heat loads without compromising the indoor climate. However, recent experiments indicate that the maximum accepted heat load decreases...... with a large room height and it decreases in connection with certain heat load distributions. Room geometries and heat load distributions that are optimal for diffuse ceiling ventilation are discussed. A simplified design procedure is introduced....

  1. Redox reactions and mechanism of luminescence in BaFCl:Eu

    CERN Document Server

    Upadeo, S V; Gundurao, T K

    1998-01-01

    The phenomenon of stimulable luminescence of phosphors pre-irradiated with high-energy radiation is widely used in the field of imaging. Phosphors such as BaFX:Eu (X = Cl, Br) are extensively used in x-ray screens for digital image processing. There is, however, divided opinion regarding the mechanism responsible for the luminescence process in these materials. In this paper we have discussed the role of Eu sup 3 sup +reversible Eu sup 2 sup + conversion in BaFCl:Eu phosphor using PL, TL, TL emission and ESR techniques. (author)

  2. Spectroscopic properties of Eu{sup 3+}:KLa(WO{sub 4}){sub 2} novel red phosphors

    Energy Technology Data Exchange (ETDEWEB)

    Rasu, K. Kavi; Balaji, D.; Babu, S. Moorthy, E-mail: babusm@yahoo.com

    2016-02-15

    Eu{sup 3+}:KLa(WO{sub 4}){sub 2} (Eu:KLW) phosphors were prepared through Pechini type sol–gel method. Low temperature synthesis was achieved through polyesterification between citric acid and ethylene glycol during the growth procedure. The properties of phosphors were analysed using X-ray diffractogram (XRD), scanning electron microscopy (SEM), Raman and luminescence spectroscopy. An effective energy transfer from the tungstate matrix to the activator Eu{sup 3+} was observed. Intense red emission in Eu:KLW phosphors was observed while excited with f–f transitions of Eu{sup 3+}. The Judd–Ofelt (J–O) intensity parameters Ω{sub 2} and Ω{sub 4} were obtained from the emission intensities of {sup 5}D{sub 0}→{sup 7}F{sub 2},{sub 4,} respectively by taking the magnetic dipole {sup 5}D{sub 0}→{sup 7}F{sub 1} emission band intensity as reference. The CIE colour co-ordinates of the Eu:KLW red phosphors was calculated (x=0.650, y=0.348), which are close to NTSC standard values. - Highlights: • Eu:KLW phosphors were synthesized by pechini type sol–gel method. • Structural, morphological, vibrational and luminescence properties were well investigation. • Eu{sup 3+}:KLa(WO{sub 4}){sub 2} phosphors has strong red emission at about 615 nm ({sup 5}D{sub 0}→{sup 7}F{sub 2}) under the excitation of near UV and blue LEDs regions. • Decay measurement and Judd–Ofelt parameter were calculated and dicussed. • These phosphors can serve as a potential candidate for red source for White LEDs application.

  3. Coordenação local do Eu(III em híbridos orgânicos/inorgânicos emissores de luz branca Eu(III local coordination in white light emitters organic-inorganic hybrids

    Directory of Open Access Journals (Sweden)

    Luís D. Carlos

    2001-08-01

    Full Text Available Eu3+ luminescence and EXAFS (Extended X-ray Absorption Fine Structure results are presented for organic-inorganic hybrid gel hosts composed of a siliceous network to which small chains of oxyethylene units are covalently grafted by means of urea bridges. Coordination numbers for Eu3+ ions range from 12.8 to 9.7 with increasing Eu3+ concentration while the Eu3+-first neighbours mean distance is found to be constant at 2.48-2.49 Å in the same concentration range. Emission spectra display a broad band in the green/blue spectral region superposed to narrow lines appearing in the yellow/red region in such a way that for the eyes emission appears white. The broad band is assigned to intrinsic NH groups emission and also to electron-hole recombination in the nanosised siliceous domains. The narrow lines are assigned to intra-4f6, 5D0->7F0-4 Eu3+ transitions and from the energy position of the 7F0-4 levels a mean distance could be calculated for the Eu3+-first neighbours. The calculated results are in good agreement with the experimental ones obtained from EXAFS analysis.

  4. Tb3+ and Eu3+ luminescence in imidazolium ionic liquids

    International Nuclear Information System (INIS)

    Hopkins, Todd; Goldey, Matt

    2009-01-01

    The luminescence properties of Tb 3+ and Eu 3+ dissolved in ionic liquids are studied. Solutes in this study include simple lanthanide compounds (e.g., EuBr 3 , TbCl 3 ) and lanthanide complexes (e.g., Eu(dpa) 3 3- where dpa = 2,6 pyridine dicarboxylate dianion) dissolved in a 1-butyl-3-methylimidazolium bromide(BMIBr)/water mixture. Emission, excitation, and time-resolved emission measurements are utilized to characterize the spectroscopic properties. It is well established in the literature that the solubility and spectroscopic properties of lanthanides in ionic liquids are highly dependent upon environmental factors including purity, and water content [K. Binnemans, Chemical Reviews (2007); I. Billard, S. Mekki, C. Gaillard, P. Hesemann, C. Mariet, G. Moutiers, A. Labet, J.-C.G. Buenzli, European Journal of Inorganic Chemistry 6 (2004) 1190-1197; S. Samikkanu, K. Mellem, M. Berry, P.S. May, Inorganic Chemistry 46 (2007) 7121-7128]. The water in this ionic liquid system acts as a co-solvent to facilitate solubility of Tb 3+ and Eu 3+ compounds. The observed spectroscopic properties of Eu 3+ and Tb 3+ salts are expectedly impacted by the high water content, but unexpectedly impacted by the BMIBr ionic liquid. However, the spectroscopy of Eu(dpa) 3 3- is unaffected by the presence of BMIBr.

  5. Influences from the European Parliament on EU emissions prices

    International Nuclear Information System (INIS)

    Deeney, Peter; Cummins, Mark; Dowling, Michael; Smeaton, Alan F.

    2016-01-01

    The decisions of the European Parliament (EP) are shown to influence both EU emission allowance (EUA) prices and volatility. Reductions in price and increases in volatility are observed when EP decisions are (i) not “party-political” in origin, (ii) made during times of low market sentiment, or (iii) made during times of low market attention. Daily EUA prices from 2007 to 2014 are used in the study, with decisions analysed using an event study approach for price impact, and a GARCH specification for volatility impact. Our findings suggest the need for policymakers to improve communication of long-term strategies for the EUA market. This aims to reduce the evident ongoing uncertainty experienced by traders around each decision made by the EP. The finding that sentiment and market attention at the time of an EP decision influences the market's reaction indicates a need to consider market dynamics in terms of decision timing, so that market turbulence is not an unintended by-product of an EP decision. Some form of medium term forward guidance may be called for. - Highlights: • Specific types of EP decisions lead to reduced carbon prices and increased volatility. • Decisions proposed by non-party-political groups have a significant effect. • There is a similar impact when market sentiment or news exposure is low. • Recommendation for some form of forward guidance.

  6. Does the Glass Ceiling Exist?: A Cross-National Perspective on Gender Income Mobility

    OpenAIRE

    Ira N. Gang; John Landon-Lane; Myeong-Su Yun

    2003-01-01

    We compare male and female upward labor income mobility in Germany and the United States using the GSOEP-PSID Cross-National Equivalent File. Our main interest is to test whether a glass ceiling exists for women. Conventional thinking about the glass ceiling highlights the belief that the playing field is level for women and men in the labor market up to a certain point, after which there is an effective limit on advancement for women. We examine the glass ceiling hypothesis by looking at the...

  7. Reform of the EU's climate policy. Small step or big hit?

    International Nuclear Information System (INIS)

    Janssen, Matthias; Peichert, Patrick; Perner, Jens; Riechmann, Christoph

    2015-01-01

    Emissions trading listed as a flexible mechanism under the Kyoto Protocol is regarded as a market economy way in climate protection. Since 2005 the European Emissions Trading System (EU ETS) is the central climate policy instrument for reducing the emissions of greenhouse gases, in particular for carbon dioxide (CO 2 ). For years, however, the CO 2 price is too low to direct the politically and socially targeted technical innovations in the electricity sector and the industry. The article analyses the temporary and structural causes of this problem, highlights the EU's reform efforts and points to areas of activity, the basis of which the EU ETS may act in the future as a central instrument for climate protection in the European Union. [de

  8. Recent Developments in EU Environmental Policy and Legislation (Sept, 2016 - March, 2017)

    OpenAIRE

    Gordeeva, Yelena M.

    2017-01-01

    This article describes the significant political initiatives and acts of legislation in the environmental field adopted in the period from September 2016 until March 2017. UHasselt clean energy for all Europeans (winter package); circular economy package; waste; forest law enforcement governance and trade (flegt); national emission ceilings directive; noise pollution report; legislative priorities for 2017; commission infringement decisions; sustainable development priorities; protecti...

  9. The EU's Biofuel Strategy

    International Nuclear Information System (INIS)

    2006-01-01

    The EU is supporting biofuels, with the aim of reducing greenhouse-gas emission, encouraging the decarbonisation of fuels used in transportation, diversifying energy procurement, offering new earning opportunities in rural areas, and developing long-term replacements for oil. We publish lengthy excerpts from the recent Communication, COM(2006) 34def. which describes the strategy adopted by the Commission [it

  10. A project-based system for including farmers in the EU ETS.

    Science.gov (United States)

    Brandt, Urs Steiner; Svendsen, Gert Tinggaard

    2011-04-01

    Farmers in the EU do not trade greenhouse gases under the Kyoto agreement. This is an empirical puzzle because agriculture is a significant contributor of greenhouse gases (GHG) in the EU and may harvest private net gains from trade. Furthermore, the US has strongly advocated land-use practices as 'the missing link' in past climate negotiations. We argue that farmers have relatively low marginal reduction costs and that consequences in terms of the effect on permit price and technology are overall positive in the EU Emission Trading System (ETS). Thus, we propose a project-based system for including the farming practices in the EU ETS that reduces the uncertainty from measuring emission reduction in this sector. The system encourages GHG reduction either by introducing a new and less polluting practice or by reducing the polluting activity. When doing so, farmers will receive GHG permits corresponding to the amount of reduction which can be stored for later use or sold in the EU ETS. Copyright © 2010 Elsevier Ltd. All rights reserved.

  11. A project-based system for including farmers in the EU ETS

    DEFF Research Database (Denmark)

    Brandt, Urs Steiner; Svendsen, Gert Tinggaard

    2011-01-01

    as ‘the missing link’ in past climate negotiations. We argue that farmers have relatively low marginal reduction costs and that consequences in terms of the effect on permit price and technology are overall positive in the EU Emission Trading System (ETS). Thus, we propose a project-based system......Farmers in the EU do not trade greenhouse gases under the Kyoto agreement. This is an empirical puzzle because agriculture is a significant contributor of greenhouse gases (GHG) in the EU and may harvest private net gains from trade. Furthermore, the US has strongly advocated land-use practices...... for including the farming practices in the EU ETS that reduces the uncertainty from measuring emission reduction in this sector. The system encourages GHG reduction either by introducing a new and less polluting practice or by reducing the polluting activity. When doing so, farmers will receive GHG permits...

  12. 380 keV proton irradiation effects on photoluminescence of Eu-doped GaN

    International Nuclear Information System (INIS)

    Okada, Hiroshi; Nakanishi, Yasuo; Wakahara, Akihiro; Yoshida, Akira; Ohshima, Takeshi

    2008-01-01

    The effect of 380 keV proton irradiation on the photoluminescence (PL) properties has been investigated for undoped and Eu-doped GaN. As the proton irradiation exceeds 1x10 13 cm -2 , a drastic decrease of PL intensity of the near band-edge emission of undoped GaN was observed. On the other hand, for Eu-doped GaN, the PL emission corresponding to the 5 D 0 → 7 F 2 transition in Eu 3+ kept the initial PL intensity after the proton irradiation up to 1x10 14 cm -2 . Present results, together with our previous report on electron irradiation results, suggest that Eu-doped GaN is a strong candidate for light emitting devices in high irradiation environment

  13. Women's Career Development at the Glass Ceiling.

    Science.gov (United States)

    Inman, Pamela L.

    1998-01-01

    For women, success in shattering the glass ceiling lies not in adapting to a male workplace culture but in using career strategies such as self-knowledge, multiple mentors, integration of body and soul, and fluid, customized careers. (SK)

  14. Single-phased white-light-emitting Sr3NaLa(PO4)3F: Eu2+,Mn2+ phosphor via energy transfer

    International Nuclear Information System (INIS)

    Shanshan, Hu; Wanjun, Tang

    2014-01-01

    Single-phased white-light-emitting Sr 3 NaLa(PO 4 ) 3 F:Eu 2+ ,Mn 2+ phosphor is synthesized via the combustion-assisted synthesis technique. Upon excitation of 344 nm ultraviolet (UV) light, two intense broad bands have clearly been obtained due to the allowed 5d–4f transition of Eu 2+ and the forbidden 4 T 1 − 6 A 1 transition of Mn 2+ , respectively. As a result of fine-tuning of the emission composition of the Eu 2+ and Mn 2+ ions, white-light emission can be realized by combining the emission of Eu 2+ and Mn 2+ in a single host lattice under UV light excitation. The obtained phosphor exhibits a strong excitation band between 250 and 420 nm, matching well with the dominant emission band of a UV light-emitting-diode (LED) chip, which could be a promising candidate for UV-converting white-light-emitting diodes (LEDs). -- Highlights: • Single-phased Sr 3 NaLa(PO 4 ) 3 F:Eu 2+ ,Mn 2+ phosphors are synthesized. • Sr 3 NaLa(PO 4 ) 3 F:Eu 2+ ,Mn 2+ shows a blue emission band and a yellow emission band. • White-emitting can be obtained by tuning the compositions of the Eu 2+ and Mn 2+

  15. Synthesis of luminescent YVO{sub 4}:Eu{sup 3+} submicrometer crystals through hydrogels as directing agents

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yan; Zheng, Yuhui [School of Chemistry and Environment, South China Normal University, Guangzhou 510006 (China); Wang, Qianming, E-mail: qmwang@scnu.edu.cn [School of Chemistry and Environment, South China Normal University, Guangzhou 510006 (China); Ministry of Education (MOE) Key Laboratory of Theoretical and Environmental Chemistry, School of Chemistry and Environment, South China Normal University, Guangzhou 510006 (China); Zhang, Cheng Cheng [Departments of Physiology and Developmental Biology, University of Texas Southwestern MedicalCenter, Dallas (United States)

    2012-08-15

    The innovative hydrogel template (polyacrylamide or polyacrylic acid) directed synthesis of YVO{sub 4}:Eu{sup 3+} phosphor in a controlled manner was thoroughly studied. Photoluminescence spectra show the europium(III)-doped yttrium orthovanadate could exhibit strong red emissions within the soft matrix (polyacrylamide) and remain relatively stable even when the temperature reached nearly 100 Degree-Sign C. After calcination process, X-ray powder diffraction patterns, SEM and DLS measurements implied that the sample was in agreement with pure tetragonal phase and the particle sizes were in the range of 100-200 nm. More importantly, YVO{sub 4}:Eu{sup 3+} products prepared based on hydrogels have remarkable improvement in emission intensities compared to phosphors synthesized by conventional approach. Similar results of overall quantum efficiency also support that YVO{sub 4}:Eu{sup 3+} assembled by PAM hydrogel (1.94%) is better than the routine way (0.91%). -- Highlights: Black-Right-Pointing-Pointer YVO{sub 4}:Eu{sup 3+} could be formed within the soft matrix. Black-Right-Pointing-Pointer The as-derived YVO{sub 4}:Eu{sup 3+} exhibited red emissions and remain relatively stable nearly 100 Degree-Sign C. Black-Right-Pointing-Pointer YVO{sub 4}:Eu{sup 3+} prepared by hydrogels has remarkable improvement in emission intensities.

  16. A novel red phosphor Mg2GeO4 doped with Eu3+ for PDP applications

    International Nuclear Information System (INIS)

    Yang Hongmei; Shi Jianxin; Liang Hongbin; Gong Menglian

    2006-01-01

    A novel red emitting phosphor, Eu 3+ -doped Mg 2 GeO 4 , was prepared by the solid-state reaction. X-ray powder diffraction (XRD) analysis confirmed the formation of Mg 2 GeO 4 :Eu 3+ . Field-emission-scanning electron microscopy (FE-SEM) observation indicated a narrow size-distribution of about 0.5-2 μm nm for the particles with spindle-like shape. Photoluminescence (PL) and vacuum ultraviolet (VUV) excitation characteristics of the phosphor Mg 2 GeO 4 :Eu 3+ were studied. We have also studied the effect of preparation conditions such as temperature, heating time on the PL data. Photoluminescence measurements indicated that the phosphor exhibits bright red emission at about 609 nm under UV excitation. And the vacuum ultraviolet spectra present that the novel red phosphor Mg 2 GeO 4 :Eu 3+ shows strong absorption in the VUV region, which ensures the efficient absorption of the Xe plasma emission lines. The phosphor Mg 2 GeO 4 :Eu 3+ shows the strongest emission at 613 nm corresponding to the electric dipole 5 D - 7 F 2 transition of Eu 3+ excited at 147 nm. The optical properties study suggests that it is a potential candidate for plasma display panels (PDPs) application

  17. Investigation on photoluminescence, electrical and positron lifetime of Eu"3"+ activated Gd_2O_3 phosphors

    International Nuclear Information System (INIS)

    Selvalakshmi, Thangaraj; Sellaiyan, Selvakumar; Uedono, Akira; Chandra Bose, Arumugam

    2015-01-01

    In the present study, red emitting Gd_2O_3:Eu"3"+ phosphors are prepared by citrate-based sol–gel process and the as-prepared samples are annealed at various annealing temperatures. The photoluminescence properties of Gd_2O_3:Eu"3"+ is explained from the excitation and emission spectra. The excitation spectra include peaks corresponding to charge transfer and 4f–4f transitions of Eu"3"+ and Gd"3"+. The phosphors exhibit a weak energy transfer process from Gd"3"+ to Eu"3"+. Under the excitation of 254 nm, a sharp red emission peak is observed at 611 nm and the emission intensity increases with the annealing temperature. The presence of defects in the phosphor is investigated by positron annihilation lifetime and Doppler broadening spectroscopy. The relation between visible emission and lattice defects of the phosphors is presented. The electrical and dielectric properties of the phosphor are also discussed in detail. Such red emitting phosphors pave the way towards the fabrication of light emitting diodes (LEDs). - Highlights: • Positron annihilation lifetime spectroscopy of Gd_2O_3:Eu"3"+. • Relation between positron lifetime and photoluminescence. • Conductivity and dielectric properties of Gd_2O_3:Eu"3"+.

  18. Photoluminescence properties of color-tunable SrMgAl10O17:Eu2+,Mn2+ phosphors for UV LEDs

    International Nuclear Information System (INIS)

    Ju Guifang; Hu Yihua; Chen Li; Wang Xiaojuan

    2012-01-01

    Aluminate phosphors SrMgAl 10 O 17 codoped with Eu 2+ and Mn 2+ ions were prepared by solid-state reaction. The phase structure and photoluminescence properties of the as-prepared phosphors were characterized by powder X-ray diffraction, photoluminescence excitation and emission spectra. Upon excitation of UV light, two broad emission bands centered at 470 and 515 nm were observed, and they were assigned to Eu 2+ and Mn 2+ emissions, respectively. The emission color of the phosphors can be tuned from blue to cyan and finally to green by adjusting the concentration ratios of Eu 2+ and Mn 2+ . Effective energy transfer occurs from Eu 2+ to Mn 2+ in the host due to the spectral overlap between the emission band of Eu 2+ and the excitation bands of Mn 2+ . The energy transfer mechanism was demonstrated to be electric dipole–quadrupole interaction. The energy transfer efficiency and critical distance were also calculated. The phosphors exhibit strong absorption in near UV spectral region and therefore they are potentially useful as UV-convertible phosphors for white LEDs. - Highlights: ► The strong absorption of phosphors matches well with the emission band of UV LED. ► The energy transfer from Eu 2+ to Mn 2+ in SrMgAl 10 O 17 was investigated in detail. ► The emission color can be tuned by adjusting the content of Eu 2+ and Mn 2+ . ► Two methods were employed to calculate the critical distance of energy transfer.

  19. Tendances Carbone no. 104. Towards a re-calibrated EU ETS for 2030: assessment of the legislative proposal to revise the EU ETS Directive

    International Nuclear Information System (INIS)

    Jalard, Matthieu; Alberola, Emilie

    2015-07-01

    Among the publications of CDC Climat Research, 'Tendances Carbone' bulletin specifically studies the developments of the European market for CO 2 allowances. Beside some statistical figures about energy production/consumption and carbon markets, this issue specifically addresses the following points: - EU ETS -Directive: On July 15, the EU Commission released a legislative proposal to revise the EU ETS Directive post-2020, translating into legislation the October 2014 Council Conclusions. - EU ETS carbon leakages provisions: The legislative proposal includes a 43% share of free allocation from 2021 to 2030, a new Carbon leakage list representing 93% of industrial emissions, an update of production levels and benchmarks every five years

  20. Reference projection energy and emissions 2010-2020

    International Nuclear Information System (INIS)

    Daniels, B.; Kruitwagen, S.

    2010-12-01

    The Reference Projection 2010-2020 examines the future development of Dutch energy use, greenhouse gas emissions and air pollution up to 2020. The Reference projection is based on assumptions regarding economic, structural, technological and policy developments. With regard to the latter, the 'Schoon en Zuinig' (Clean and Efficient) policy programme for energy and climate, introduced in 2007, plays an important role. According to Schoon en Zuinig, greenhouse gas emissions have to be reduced by 30% in 2020 compared to 1990; the annual energy efficiency improvement has to increase to 2% and the target share of renewable energy production in total consumption in 2020 is 20%. To assess the effects of the policy measures from the 'Schoon en Zuinig' policy programme, the Reference projection explores three policy variants: one without policies introduced after 2007, one including only post-2007 policies that are already fixed, and one including proposed policy measures as well. Here, policies refer to Dutch as well as to European policies. The results indicate that the climate and energy targets will not be reached with the current instruments. Including proposed policy measures, the estimated greenhouse gas reduction will amount to 16-24% relative to 1990, the renewable energy share will rise to 13-16% and the annual energy efficiency improvement between 2011 and 2020 will amount to between 1.1 and 1.6%. European targets for greenhouse gas emissions can be reached, especially in the case of implementation of the proposed policies. As for renewable energy, the implementation of proposed policies is imperative for attaining the target, but likely to be insufficient. Current European targets for air pollutants are within reach. 2020 emission levels of most air pollutants are lower than the current 2010 National Emission Ceilings, with the exception of ammonia, where there is a substantial chance that the 2020 emissions will exceed the 2010 ceiling. However, ceilings are

  1. Reducing ammonia emissions in Europe

    DEFF Research Database (Denmark)

    Jacobsen, Brian H.

    2011-01-01

    The NEC directive has set targets for the 2010 ammonia emissions from a number of European countries. The target will be reached by most EU-countries and the total emission for EU-27 has been reduced by 22% from 1990 to 2007. Denmark is one of the countries with the largest reductions since 1990...

  2. Creating a level playing field? The concentration and centralisation of emissions in the European Union Emissions Trading System

    International Nuclear Information System (INIS)

    Bryant, Gareth

    2016-01-01

    This article questions the assumption that carbon markets create a level playing field by exploring the relationship between the organisation of capital and the organisation of emissions in the European Union Emissions Trading System (EU ETS). It constructs a database by matching installations and owners to reveal that a relatively small number of large-scale coal-fired power stations, owned by a very small group of states and corporations, are responsible for a significant proportion of greenhouse gas emissions. The findings are analysed by considering how technological dependence on coal together with the corporate institutional form combine to support the socio-spatial concentration and centralisation of capital and emissions. Case studies of the consolidation of the seven largest polluting owners from Europe's coal-dependent electricity sector and the carbon trading strategies of the two largest polluters, RWE and E.ON, then assess the impacts of energy liberalisation and emissions trading policies. The article concludes that EU energy and climate policies are pulling in different directions by clustering responsibility for greenhouse gas emissions and diffusing responsibility to address climate change. The uneven distribution of emissions within the EU ETS makes an alternative policy approach that directly targets the biggest corporate and state polluters both feasible and necessary. - Highlights: • 20 ultimate owners are responsible for one-half of 2005–12 EU ETS emissions. • 83 installations are responsible for one-third of 2005–12 EU ETS emissions. • Focus on technological dependence on coal and the corporate institutional form. • Energy liberalisation policy has consolidated responsibility for emissions. • Carbon markets have diffused responsibility for addressing climate change.

  3. Evaluation of environmental and physiological factors of a whole ceiling-type air conditioner using a salivary biomarker

    Energy Technology Data Exchange (ETDEWEB)

    Tahara, Yusuke; Yamaguchi, Masaki [Graduate School of Engineering, Iwate University, 4-3-5 Ueda, Morioka 020-8551 (Japan); Morito, Naomi; Nishimiya, Hajime; Yamagishi, Hideyuki [Asahi Kasei Homes Corporation, R and D Laboratories, 2-1 Samejima, Fuji, Shizuoka 416-8501 (Japan)

    2009-06-15

    In order to improve environmental condition such as humidity and airflow in living spaces, a whole ceiling-type air conditioner is proposed. This novel air conditioner exhaust dispersed airflow from the whole ceiling by using a 3-dimensional knit fabric. The purpose of this paper is to reveal the effects when controlling humidity and airflow using the whole ceiling-type air conditioner compared to a commercialized concentrated exhaust air conditioner (normal-type air conditioner) under the same temperature. Salivary {alpha}-amylase activity (SAA) was used as an index of sympathetic nervous activity. An acute experiment for a 15 min period was conducted using 12 healthy young female adults. No significant differences in room and skin temperatures were observed between the whole ceiling-type air conditioner and the normal-type air conditioner. The whole ceiling-type air conditioner showed 11.1% lower humidity than the normal-type air conditioner. The whole ceiling-type air conditioner showed one-thirteenth the airflow of the normal-type air conditioner. As a result, the PMV of the whole ceiling-type air conditioner was more comfortable level than the normal one. Moreover, subjective evaluation questionnaire revealed a significant difference was observed in wind perception (windy). The SAA of subjects under the whole ceiling-type air conditioner showed significantly low values compared with the normal-type air conditioner. It was found that the subject's sympathetic nervous activity has been inactivated under the conditions of the whole ceiling-type air conditioner. Thus, it was revealed that the whole ceiling-type air conditioner provides a more comfortable air environment by reducing physical stimulations to humans. (author)

  4. State of the Low-Carbon Energy Union: Assessing the EU's progress towards its 2030 and 2050 climate objectives

    International Nuclear Information System (INIS)

    Spencer, Thomas; Pierfederici, Roberta; Sartor, Oliver; Berghmans, Nicolas; Samadi, Sascha; Fischedick, Manfred; Knoop, Katharina; Pye, Steve; Criqui, Patrick; Mathy, Sandrine; Capros, Pantelis; Fragkos, Panagiotis; Bukowski, Maciej; Sniegocki, Aleksander; Virdis, Maria Rosa; Gaeta, Maria; Pollier, Karine; Cassisa, Cyril

    2016-11-01

    Rather than examining aggregate emissions trends, this study delves deep into the dynamics affecting each sector of the EU energy system. It examines the structural changes taking place in power production, transport, buildings and industry, and benchmarks these with the changes required to reach the 2030 and 2050 targets. In so doing it aims to influence both the ambition and direction of future policy decisions, both at Member State and EU level. In order to assess the adequacy of the EU and its Member States policies with the 2030 and 2050 decarbonization objectives, this study goes beyond the aggregate GHG emissions or energy use figures and analyse the underlying drivers of emission changes, following a sectoral approach (power generation, buildings, industry, and transport). Historical trends of emission drivers are compared with the required long-term deep decarbonization pathways, which provide sectoral 'benchmarks' or 'corridors' against which to analyse the rate and direction of historical change for each Member State and the EU in aggregate. This approach allows the identification of the necessary structural changes in the energy system and policy interventions to reach deep decarbonization, and therefore the comparison with the current policy programs at European and Member State level. The EU has made significant progress in the structural decarbonization of its energy system. However, despite of this progress, the EU is currently 'off-track' to achieve its objectives by 2030 and 2050. First, the rate of change is insufficient across a large number of the indicators assessed. Second, too much of the change in aggregate emissions has been driven by cyclical effects rather than structural decarbonization, notably the impact of the financial crisis and subsequent slow recovery. Third, long-term decarbonization options, for example to decarbonize industrial processes and materials, are not being adequately prepared. While some policies under the EU's 2030

  5. FY 2000 report on the survey on global warming prevention measures in main E.U. countries; 2000 nendo EU shuyokoku ni okeru ondanka boshi taisaku no gaiyo ni tsuite hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    This report dealt with the background of energy policies in E.U. countries and energy plans. At COP3, E.U. countries internationally gave a pledge that they will reduce the emission of greenhouse effect gas 8% from that as of 1990 during 2008-2012, which is stricter than those given by Japan and the U.S. Actually, the European Commission made public 'Toward the European Climate Change Programme' and 'Green Paper on Emissions Trading in the E.U.' These are correspondent to E.U.' global warming preventive strategy which is called the twin track approach by the European Commission. The former is a frame for coordinating individual reduction measures taken under the responsibility of member countries as the whole E.U. As to the latter, for the specified sectors from energy supply sectors to large energy consumption industries, it was planned to be started in 2005. And, the basic policy on the trade and concrete subjects/problems on the trading system were arranged. (NEDO)

  6. Luminescence and thermal stability tuning in (Ba,Mn)3(Gd,Y)Na(PO4)5F:Eu2+ phosphors via cation-substitution

    Science.gov (United States)

    Mei, Juan; Lv, Lemin; Gao, Junsong; Wei, Yi; Feng, Yuxin; Yan, Chunjie; Li, Guogang

    2018-04-01

    In this work, [Y3+-Gd3+] and [Mn2+-Ba2+] substitutions were designed in Ba3GdNa(PO4)5F:Eu2+ system, which were marked as BG1-xYxNPF:Eu2+ and B1-yMyGNPF:Eu2+, respectively. It is found that their luminescence properties and thermal stability could be obviously tuned. For BG1-xYxNPF:Eu2+ series, under 365 nm UV light, the emission spectra exhibited a continuous red-shift from 458 nm (x = 0) to 485 nm (x = 1) with the corresponding luminescence varying from blue light to cyan light. For B1-yMyGNPF:Eu2+ series, it was observed the coexistence of blue-green and enhanced red emission of Eu2+ and the appearance of Eu3+ emission when Mn2+ partly substituted Ba2+, resulting in a final white emission. In addition, the thermal stabilities of B1-yMyGNPF:Eu2+ were obviously improved with Mn2+ doping. The corresponding luminescence and thermal stability tuning mechanisms were investigated.

  7. Preparation and luminescence properties of Eu{sup 2+}doped {gamma}-aluminum oxynitride transparent ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Fang; Yuan, Xianyuan; Wang, Shaohua [Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai (China); Wang, Shiwei, E-mail: swwang51@mail.sic.ac.cn [Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai (China)

    2013-01-15

    Eu{sup 2+} doped {gamma}-AlON transparent ceramics have been prepared by the solid-state reaction sintering method. The influences of Eu concentration on both strength, transparency and luminescence properties of the as-prepared samples were discussed. The strength and transparency decreased as Eu content increased. Two bands were observed in the emission spectrum of each sample. One (B{sub 1}) was narrow and centered at around 401 nm, the other (B{sub 2}) was comparatively broader, and the location of its center as well as the intensity ratio of peak values of B{sub 2} to that of B{sub 1} varied with Eu content. - Highlights: Black-Right-Pointing-Pointer Eu{sub 2}O{sub 3} was an effective sintering aid in fabrication of transparent {gamma}-AlON ceramics. Black-Right-Pointing-Pointer Eu-doped transparent {gamma}-AlON ceramics exhibited broad emission spectra composed of two bands. Black-Right-Pointing-Pointer The relationship between crystal position of Eu{sup 2+} ions and luminescent properties was given.

  8. The Real Glass Ceiling. Your Career.

    Science.gov (United States)

    Savage, Adrian

    2002-01-01

    There is a powerful and common glass ceiling (barrier that prevents capable employees from being promoted) that affects men as much as women. Between middle management and the executive level, corporate culture shifts to one based on power and a worker must play by new rules even if these have never been explained. (JOW)

  9. The effect of interaction between surface plasmons of gold nanoparticles and optical active centers on luminescence of Eu3+- doped Zn2SnO4 nanocrystals

    Science.gov (United States)

    Thien, Nguyen Duy; Vu, Le Van; Long, Nguyen Ngoc

    2018-04-01

    The enhancement and quenching of Eu3+ ion emission were investigated in Zn2SnO4:Eu3+@Au (ZTO:Eu3+@Au) nanocomposites. Under 361 nm excitation we revealed the extinction of the intrinsic defect emission and the enhancement of Eu3+ ion emission when Au content in samples is increased, but under excitation wavelength of 394 nm we observed only the suppression of Eu3+ ion emission. The cause of the observed PL behavior is related to the interaction between surface plasmon induced by gold nanoparticles and luminescence centers in the samples.

  10. The effect of low ceiling on the external combustion of the cabin fire

    Science.gov (United States)

    Su, Shichuan; Chen, Changyun; Wang, Liang; Wei, Chengyin; Cui, Haibing; Guo, Chengyu

    2018-06-01

    External combustion is a phenomenon where the flame flares out of the window and burns outside. Because of the particularity of the ship's cabin structure, there is a great danger in the external combustion. In this paper, the numerical calculation and analysis of three kinds of low ceiling ship cabin fire are analyzed based on the large eddy numerical simulation technique. Through the analysis of temperature, flue gas velocity, heat flux density and so on, the external combustion phenomenon of fire development is calculated. The results show that when external combustion occurs, the amount of fuel escaping decreases with the roof height. The temperature above the window increases with the height of the ceiling. The heat flux density in the external combustion flame is mainly provided by radiation, and convection is only a small part; In the plume area there is a time period, in this time period, the convective heat flux density is greater than the radiation heat flux, this time with the ceiling height increases. No matter which ceiling height, the external combustion will seriously damage the structure of the ship after a certain period of time. The velocity distribution of the three roof is similar, but with the height of the ceiling, the area size is also increasing.

  11. Seville City Hall Chapter Room ceiling decoration

    Directory of Open Access Journals (Sweden)

    Robador, M. D.

    2010-02-01

    Full Text Available The present article describes a chemical and physical study of the colour, chemical composition and mineral phases of the decorative materials in the Seville City Hall Chapter House ceiling. The findings showed that the inner most layer of material, calcite, was covered with white lead, in turn concealed under a layer of gilded bole. The ceiling underwent re-gilding, also over bole, due in all likelihood to wear on the original gold leaf. In the nineteenth century, the entire ceiling with the exception of the inscriptions was whitewashed with calcite and white lead. Silver was employed on King John I’s sword (coffer 27. Gold leaf was used to adorn the royal attributes: crowns, belts, sceptres, swords and rosary beads. The high reliefs were likewise gilded. The pigments identified on the ceiling adornments included azurite, malachite, vermilion and gas black. A lime and ground dolomite mortar was used throughout.

    El objetivo de este trabajo es el estudio de diferentes aspectos, como el color, la composición química y las fases mineralógicas presentes en los diferentes materiales que forman la ornamentación del techo de la Sala Capitular del Ayuntamiento de Sevilla, mediante métodos físicos y químicos. Nuestros resultados muestran que el dorado fue realizado sobre una capa de bol previamente depositada sobre una lámina de blanco de plomo que cubría un estrato de calcita. Posteriormente, y probablemente debido a alteraciones en el dorado original, el techo fue de nuevo dorado usando una técnica similar. En el siglo XIX, casi todo el techo, excepto las zonas con inscripciones, fue blanqueado usando una mezcla de calcita y blanco de plomo. Se empleó plata para cubrir la espada del rey Juan I (casetón 27. Finísimas láminas de oro se usaron para decorar los atributos reales: coronas, cinturones, cetros, espadas y rosarios. En diferentes partes de la decoración fueron detectados pigmentos como azurita, malaquita, bermellón y

  12. Study of electron vibrational interaction parameters in chlorophosphate activated with Eu2+ ion

    International Nuclear Information System (INIS)

    Bhoyar, Priyanka D.; Dhoble, S.J.

    2014-01-01

    We present the results of theoretical study of photoluminescence of Eu 2+ ions activated chlorophosphate M 5.17 (PO 4 ) 3 Cl 5 :Eu 2+ with M = Ca, Sr and Ba estimating electron-vibrational interaction (EVI) parameters such as Huang–Rhys factor, effective phonon energy, Stokes shift and zero phonon line position. Validity of the calculated result was established by modeling the emission line which was found to be in good agreement with the measured photoluminescence spectrum of Eu 2+ doped chorophosphates. - Highlights: • The EVI parameters such as Huang–Rhys factor, effective phonon energy and zero phonon line position were estimated. • Eu 2+ ion emission observed in chlorophosphate. • Material analyzed in this work have intermediate Huang–Rhys factor, high Stokes shift and low effective phonon energy

  13. Modeling of a hydronic ceiling system and its environment as energetic auditing tool

    Energy Technology Data Exchange (ETDEWEB)

    Fonseca Diaz, Nestor [Universidad Tecnologica de Pereira, Facultad de Ingenieria Mecanica (Colombia); University of Liege Belgium, Thermodynamics Laboratory Campus du Sart Tilman - Bat: B49 - P33, B-4000 Liege (Belgium)

    2011-03-15

    As a part of a commissioning study, the chilled ceiling system of a large commercial building located in Belgium is evaluated. A representative office has been instrumented and data on the chilled ceiling system operating in real conditions have been collected. The simulation of the whole system is performed by means of a transient thermal model of the building and its HVAC system. The model considers the hydronic panels as a transient-state finned heat exchanger connected to a simplified lumped transient model of the building. The behavior of the hydronic ceiling system and the interactions with its environment (walls, ventilated facade, internal loads and ventilation system) has been experimentally and numerically evaluated. Commissioning test results show that the influence of surfaces temperatures inside the room, especially the facade, is considerable. Then, it is clear that the hydronic ceiling system must be evaluated together with its designed environment and not as a separate HVAC equipment. (author)

  14. Tunable luminescence properties and efficient energy transfer in Eu2+, Tb3+ co-doped NaBaPO4

    Directory of Open Access Journals (Sweden)

    Qiuhong Zhang

    2014-01-01

    Full Text Available Eu2 + and Tb3+ singly doped and co-doped NaBaPO4 phosphors were synthesized by solid state reaction. The structure character, photoluminescence properties and the lifetime were investigated. The emission spectra of NaBaPO4:Eu2+, Tb3+, Na+ phosphor show both broad blue emission band and sharp green emission peaks. The energy transfer mechanism from Eu2+ to Tb3+ in NaBaPO4 host was discussed. The excitation spectra of NaBaPO4: Eu2+, Tb3+, Na+ phosphor show broad excitation band in the 250–400 nm range, which was in agreement with the near-ultraviolet (n-UV chip. The hue of the NaBaPO4: Eu2+, Tb3+, Na+ phosphors could be appropriately tuned by adjusting the contents of activators.

  15. Energy Climate Change - Challenges and Prospects of the EU Policy

    International Nuclear Information System (INIS)

    Blecic, P.; Bosnjakovic, B.; Frankovic, B.

    2013-01-01

    The paper discusses the main challenges and prospects of EU policy in the field of energy and climate change, without going into technical details, but establishes the main themes of sustainability: economy, environment and new jobs. It describes the foundations and the objectives of the current EU energy policy, and the reasons why the current approach to reduction of greenhouse gases emissions is disappointing. Also, the question is whether EU will achieve the renewable energy goals for the year 2020. The security of energy supply and availability is also considered, especially in view of high dependence on import energy in the today fragmented market. For the way forward to mid-century, the targets to year 2030 are of critical importance. Also, the paper gives an overview of the state of renewable energy and greenhouse gas emissions in Croatia.(author)

  16. Optical excitation and external photoluminescence quantum efficiency of Eu3+ in GaN

    NARCIS (Netherlands)

    de Boer, W.D.A.M.; McGonigle, C.; Gregorkiewicz, T.; Fujiwara, Y.; Stallinga, P.

    2014-01-01

    We investigate photoluminescence of Eu-related emission in a GaN host consisting of thin layers grown by organometallic vapor-phase epitaxy. By comparing it with a reference sample of Eu-doped Y2O3, we find that the fraction of Eu3+ ions that can emit light upon optical excitation is of the order of

  17. Luminescent properties of Mg3Ca3(PO4)4: Eu2+ blue-emitting phosphor for white light emitting diodes

    International Nuclear Information System (INIS)

    Li Yinqun; Deng Degang; Wang Qian; Li Gaofeng; Hua Youjie; Jia Guohua; Huang Lihui; Zhao Shilong; Wang Huanping; Li Chenxia; Xu Shiqing

    2012-01-01

    A blue-emitting phosphor, Eu 2+ -activated Mg 3 Ca 3 (PO 4 ) 4 phosphor was synthesized by conventional solid-state reaction. X-ray powder diffraction (XRD) analysis confirmed the phase formation. Photoluminescence (PL) results showed that Mg 3 Ca 3 (PO 4 ) 4 : Eu 2+ could be efficiently excited by UV–visible light from 250 to 430 nm, which matched well with the emission wavelengths of near-UV and UV LED chips. The effects of the doped-Eu 2+ concentration in Mg 3 Ca 3 (PO 4 ) 4 : Eu 2+ on the PL were also investigated. The result reveals that Mg 3 Ca 3 (PO 4 ) 4 : Eu 2+ is a potential blue-emitting phosphor for white LEDs. - Graphical Abstract: The excitation spectra show a broad peak from 250 to 430 nm, which means Mg 3 Ca 3 (PO 4 ) 4 : Eu 2+ phosphor can be suitable for application in white LEDs excited by the near-UV and UV LEDs. The emission spectrum peaked at 456 nm with the full-width half-maximum (FWHM) of 102 nm is attributed to the 4f 6 5d 1 –4f 7 transition of the Eu 2+ ion. The asymmetric emission spectra show that Eu 2+ has more one emission center in Mg 3 Ca 3 (PO 4 ) 4 , which can be deconvoluted into at least four Gaussian components peaked at 423, 446, 483 and 510 nm. Highlights: ► Mg 3 Ca 3 (PO 4 ) 4 : Eu 2+ phosphor could be effectively excited by UV chips (360–430 nm). ► Mg 3 Ca 3 (PO 4 ) 4 : Eu 2+ phosphor is a potential blue-emitting phosphor for white LEDs. ► Mg 3 Ca 3 (PO 4 ) 4 : Eu 2+ phosphor shows a broadband emission.

  18. Optical properties of Eu(III) doped strontium gadolinium niobate oxide

    Energy Technology Data Exchange (ETDEWEB)

    Vishwnath, Verma, E-mail: mnsmsu@gmail.com, E-mail: vermavicky.1988@gmail.com; Srinivas, M.; Patel, Nimesh; Modi, Dhaval [Luminescent Materials Laboratory, Physics Department, Faculty of Science, The M. S. University of Baroda, Vadodara-390002 (India); Murthy, K. V. R. [Display Materials Laboratory, Applied Physics Department, Faculty of Technology and Engineering, The M. S. University of Baroda, Vadodara-390001, Gujarat (India)

    2016-05-23

    Sr{sub 2}GdNbO{sub 6} doped with trivalent ion of Eu phosphors having monoclinic phase of space group P2{sub 1}/n have been synthesized via solid state reaction method, and their photoluminescence properties have been examined under UV excitation. The emission peaks exhibited around 580, 596, and 610 nm wavelength. By using xenon lamp as a source of excitation having wavelengths at 254 and 262 nm, it is observed that the maximum light emission yielded in red region. It is inferred that the dopant Eu{sup +3} ions may take the substitutional positions at non-centrosymmetric site.

  19. Business as usual in spite of the CO2 trade of the EU

    International Nuclear Information System (INIS)

    Wellander, Dag

    2004-01-01

    The trade system that is going to be launched by the EU at the turn of the year (2004/2005) has some serious shortcomings as it was originally formulated. It is limited to the EU. It is only partial; it applies only to emission sources in the energy sector and some energy-intensive sectors. Both limitations raise the costs of cutting down on the emissions, which would have hit the EU unilaterally. According to the author, work is now in progress to make the trade system as inefficient as possible, aiming at ''business as usual''. The climate problems cannot be solved without global cooperation, which is not in sight

  20. Performance of personalized ventilation combined with chilled ceiling in an office room: inhaled air quality and contaminant distribution

    DEFF Research Database (Denmark)

    Lipczynska, Aleksandra; Kaczmarczyk, Jan; Melikov, Arsen Krikor

    2014-01-01

    people (exhaled air, bioeffluents) and building materials (wall painting). Personalized ventilation combined with chilled ceiling ensured highest air quality at the workstation under all conditions. Pollutant concentration in the occupied zone away from the workstations did not differ substantially...... between the tested systems. Chilled ceiling combined with personalized ventilation working as the only air supplying system may be optimal solution in many buildings.......In a simulated two persons’ office room inhaled air quality and contaminant distribution provided with personalized ventilation combined with chilled ceiling, mixing ventilation only, chilled ceiling with mixing ventilation and chilled ceiling with mixing and personalized ventilation was studied...

  1. Final report development of a regional nitrogen ceiling; Eindrapportage ontwikkeling regionaal stikstofplafond

    Energy Technology Data Exchange (ETDEWEB)

    Bleeker, A.; Hensen, A. [ECN Environment and Energy Engineering, Petten (Netherlands); Rougoor, C. [Centrum voor Landbouw en Milieu CLM, Culemborg (Netherlands)

    2013-01-15

    The development of a methodology in which integrated nitrogen ceilings can be studied on a regional level is described. Next to the agricultural sector, also other sectors are taken into consideration (traffic, industry, etc.) with respect to the development of the nitrogen ceiling methodology. The study consists of two parts: the feasibility of a nitrogen ceiling system and the actual development of such a system [Dutch] Deze rapportage beschrijft de ontwikkeling van een methodiek waarbij integrale stikstofplafonds op gebiedsniveau kunnen worden bestudeerd. Dit onderzoek beschouwt, naast landbouw, ook andere sectoren (verkeer, industrie, etc.) voor het ontwikkelen van de stikstofplafond methodiek. Het onderzoek bestaat uit twee onderdelen: bestuderen van de haalbaarheid van een stikstofplafond systematiek en het feitelijke ontwikkelen van een dergelijke systematiek.

  2. Air Distribution and Ventilation Effectiveness in a room with Floor/Ceiling Heating and Mixing/Displacement Ventilation

    DEFF Research Database (Denmark)

    Wu, Xiaozhou; Fang, Lei; Olesen, Bjarne W.

    2014-01-01

    vertical air temperature differences and air velocities for different hybrid systems are less than 3 C and 0.2 m/s when supply air temperature is 19 C, air change rate is 4.2 h-1, and heated surface temperature of floor/ceiling heating system is 25 C. Ventilation effectiveness of mixing ventilation system...... combined with floor/ceiling heating systems is approximately equal to 1.0, and ventilation effectiveness of displacement ventilation system combined with floor/ceiling heating systems ranges from 1.0 to 1.2. The floor/ceiling heating systems combined with mixing ventilation system have more uniform indoor...... air distribution but smaller ventilation effectiveness compared with the floor/ceiling heating systems combined with displacement ventilation system. With regard to the building heat loss increased by non-uniform indoor air distribution and small ventilation effectiveness, there should be an optimal...

  3. Femtosecond laser-induced reduction in Eu-doped sodium borate glasses

    Energy Technology Data Exchange (ETDEWEB)

    Lim, Ki-Soo [Department of Physics and Basic Science Research Institute, Chungbuk National University, Cheongju 361-763 (Korea, Republic of)]. E-mail: kslim@chungbuk.ac.kr; Lee, Sunkyun [Department of Physics and Basic Science Research Institute, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Trinh, Minh-Tuan [Department of Physics and Basic Science Research Institute, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Kim, Suk-Ho [Department of Physics and Basic Science Research Institute, Chungbuk National University, Cheongju 361-763 (Korea, Republic of); Lee, Myeongkyu [Departent of Materials Science and Engineering, Yonsei University, 134 Shinchon-dong, Seoul 120-749 (Korea, Republic of); Hamilton, Douglas S. [Department of Physics, University of Connecticut, Storrs, CT 06269 (United States); Gibson, George N. [Department of Physics, University of Connecticut, Storrs, CT 06269 (United States)

    2007-01-15

    In this work, we report permanent reduction of Eu{sup 3+} to Eu{sup 2+} in sodium borate glasses by irradiation of near-infrared femtosecond laser. Glass composition of sodium borate was 85B{sub 2}O{sub 3}-15Na{sub 2}O. The glasses were doped with 0.05, 0.1, and 0.5 mol% Eu{sub 2}O{sub 3}. Absorption and fluorescence dynamics were studied to investigate valence state change of europium ions and the energy transfer between Eu{sup 2+} and Eu{sup 3+} ions. As the femtosecond laser intensity or exposure time increases, the emission band at 400 nm becomes stronger. However, the photoreduction efficiency decreases as the dopant concentration increases. We discuss the photoreduction mechanism under multiphoton absorption.

  4. Investigation of floor Nusselt number in floor heating system for insulated ceiling conditions

    International Nuclear Information System (INIS)

    Karadag, Refet; Teke, Ismail

    2007-01-01

    In this study, in a floor heated room, natural convection heat transfer over the floor is analysed numerically for different thermal conditions. An equation relevant to Nusselt number over the floor has been obtained by using the numerical data. Different equations are given in the literature. They consider the effect of floor Rayleigh number while neglecting the effect of wall and ceiling thermal conditions. Numerical data obtained in this study show that the Nusselt number over the floor depends on not only the floor Rayleigh number but also the wall Rayleigh number (for insulated ceiling conditions). The equations given in the literature are different from each other due to their not considering the effect of wall and ceiling Rayleigh numbers. This difference between the equations may be eliminated by obtaining an equation containing the effect of floor, wall and ceiling Rayleigh numbers. In this new approach, an equation relevant to the floor Nusselt number that depends on the floor and wall Rayleigh numbers has been obtained in the floor heating system for insulated ceiling conditions. The equation obtained in this study has been compared with the equations given in the literature. It has been seen that the equation obtained in this study matches the numerical values under more extensive thermal conditions than the equations given in the literature. The maximum deviation for the equations given in the literature is 35%, but in the current study, the maximum deviation has been found to be 10%. As a result, it is more convenient to use the equation found in the new approach as a function of Rayleigh number over the floor and wall for insulated ceiling conditions

  5. Synthesis and luminescence properties of Eu"2"+ doped CaSO_4 phosphor

    International Nuclear Information System (INIS)

    Aghalte, G.A.; Dhoble, S.J.; Pawar, N.R.

    2016-01-01

    Eu"2"+ doped CaSO_4 Phosphor were synthesized by precipitation method. PL analysis of Eu"2"+ activated CaSO_4 phosphor exhibited characteristic emission properties; CaSO_4:Eu Phosphor has received considerable attention because of its high sensitivity to X-ray and λ ray irradiation. CaSO_4:Eu phosphor powder was successfully synthesized by the wet chemical co-precipitation method. The structure morphology and luminescent properties of the phosphor were characterized by X-ray diffraction, scanning electron microscopy and photoluminescence spectroscopy

  6. A Research on Glass Ceiling Syndrome Career Barriers of Women Academics

    OpenAIRE

    Serdar Öge; Alpay Karasoy; Özlem Kara

    2014-01-01

    Although women have merit in their jobs, they still are located very few in the top management in many sectors. There are many causes of such situation. Such a situation creates obstacles; especially invisible ones are called “glass ceiling syndrome”. Also, studies which handle this subject in academic community are very few. The aim of this research is to reach the results about glass ceiling obstacles in terms of female teaching staff (academics) working in higher educa...

  7. The European carbon balance. Part 1: fossil fuel emissions

    NARCIS (Netherlands)

    Ciais, P.; Paris, J.D.; Marland, G.; Peylin, P.; Piao, S.L.; levin, I.; Pregger, T.; Scholz, Y.; Friedrich, R.; Rivier, L.; Houweling, S.; Schulze, E.D.

    2010-01-01

    We analyzed the magnitude, the trends and the uncertainties of fossil-fuel CO2 emissions in the European Union 25 member states (hereafter EU-25), based on emission inventories from energy-use statistics. The stability of emissions during the past decade at EU-25 scale masks decreasing trends in

  8. Noticeable red emission and Raman active modes in nanoscale gadolinium oxyfluoride (Gd{sub 4}O{sub 3}F{sub 6}) systems with Eu{sup 3+} inclusion

    Energy Technology Data Exchange (ETDEWEB)

    Hazarika, Samiran; Mohanta, Dambarudhar [Tezpur University, Nanoscience and Soft Matter Laboratory, Department of Physics, Tezpur, Assam (India)

    2017-05-15

    Eu{sup 3+} doped gadolinium oxyfluoride (Gd{sub 4}O{sub 3}F{sub 6}, GOF) nanoscale systems have been synthesized following a modified Pechini method. While exhibiting a tetragonal crystal structure, the GOF nanosystem gave an average crystallite size (d) of ∝21-26 nm. The Lotgering factor (L{sub F}), which is a measure of orientation of crystallites along the preferred direction was found to vary between 0.22 and 0.48. In the photoluminescence spectra, ∝595 and ∝613 nm peaks were identified as magnetically driven ({sup 5}D{sub 0} → {sup 7}F{sub 1}) and electrically driven ({sup 5}D{sub 0} → {sup 7}F{sub 2}) transitions with latter (red emission) being strongly manifested with Eu{sup 3+} doping concentration and intrinsic defects. Moreover, several Raman active modes have been probed in the Raman spectra with low frequency peaks (<300 cm{sup -1}) and moderate frequency peaks (∝481 and 567 cm{sup -1}) assigned to observable vibration of heavy atom Gd-Gd pairs and Gd-O groups, respectively. Apart from manifestation of phononic features, inclusion of Eu{sup 3+} in the host lattice would bring new insight on improving the red emission response prior to concentration quenching. (orig.)

  9. Physics of Efficiency Droop in GaN:Eu Light-Emitting Diodes.

    Science.gov (United States)

    Fragkos, Ioannis E; Dierolf, Volkmar; Fujiwara, Yasufumi; Tansu, Nelson

    2017-12-01

    The internal quantum efficiency (IQE) of an electrically-driven GaN:Eu based device for red light emission is analyzed in the framework of a current injection efficiency model (CIE). The excitation path of the Eu +3 ion is decomposed in a multiple level system, which includes the carrier transport phenomena across the GaN/GaN:Eu/GaN active region of the device, and the interactions among traps, Eu +3 ions and the GaN host. The identification and analysis of the limiting factors of the IQE are accomplished through the CIE model. The CIE model provides a guidance for high IQE in the electrically-driven GaN:Eu based red light emitters.

  10. NIR emitting K2SrCl4:Eu2+, Nd3+ phosphor as a spectral converter for CIGS solar cell

    Science.gov (United States)

    Tawalare, P. K.; Bhatkar, V. B.; Omanwar, S. K.; Moharil, S. V.

    2018-05-01

    Intense near-infrared emitting phosphor K2SrCl4:Eu2+,Nd3+ with various concentrations of Nd3+ were synthesized. These are characterized with X-ray diffraction, reflectance, photoluminescence emission and photoluminescence excitation spectroscopy, PL lifetime measurements. The emission can be excited by a broad band in near ultra violet region as a consequence of Eu2+→Nd3+ energy transfer. The efficiency of Eu2+→Nd3+ energy transfer is as high as 95%. Fluorescence decay curves for Eu2+ doped samples are almost exponential and described by τ = 500 ns. Eu2+ lifetimes are shortened after Nd3+ doping. Near infrared Emission intensity is limited by Nd3+→Nd3+ energy transfer and the consequent concentration quenching. Nd3+ emission matches well with the spectral response of CIGS and CIS solar cells. Absorption of near ultra violet radiations followed by conversion to near infrared indicates the potential application in solar photovoltaics.

  11. Piercing the sovereign ceiling: Issues in oil and gas project financing

    International Nuclear Information System (INIS)

    Coleman, T.S.

    1998-01-01

    In the oil and gas sector, corporations and governments face huge capital spending requirements in order to transform large resource discoveries into producing, cash-generating assets. A significant portion of this funding is expected to be done on a project finance basis, where bank lenders or bond investors take a secured position in financing a discrete project, with the expectation of being paid back by the cash flows from that project after completion. This trend is increasing demand for crediting rating services to provide credit ratings for these project financings. A key challenge is to analyze and rate credit-worthy projects in countries that have relatively low foreign currency sovereign ceilings due to economic, political, and financial risks. In most cases, the credit ratings for projects financed in currencies outside the host country are capped at the country''s foreign currency ceiling. However, in a few instances, mainly in the oil and gas sector, Moody''s has pierced the foreign currency ceiling or rated certain projects above the sovereign ratings of the countries where they are domiciled. The purpose of this article is to briefly explain some of the qualitative factors and considerations that have allowed Moody''s to pierce the ceiling in the oil and gas sector, with a focus on two recent and noteworthy projects: Ras Laffan Liquefied Natural Gas in Qatar and Petrozuata in Venezuela

  12. Environmental control policy change in the EU between ideas and reality; Umweltpolitischer Steuerungswechsel in der EU zwischen Ideen und Realitaet

    Energy Technology Data Exchange (ETDEWEB)

    Heumader, Katja

    2014-07-01

    The study on the environmental policy change in the EU covers the following issues: theoretical frame work: the scientific policy debate on political control and governance; boom of ideas: development in the discussion on European environmental policy; discrepancies: the change of political control between intention and realization; case studies: EU policy concerning the enhancement of energy efficiency, the groundwater guideline, waste policy and waste stream priorities, the European emission trading system, access to jurisdiction for environmental issues, the soil protection guideline.

  13. The Common Agricultural Policy and the Greenhouse Gases Emissions

    OpenAIRE

    BRITO SOARES, F.; Ronco, R.

    2005-01-01

    The evolution of greenhouse gases emissions in the EU-15 countries is accessed. While the absolute level of emissions turns out to be declining in the last thirty years in EU-15 Member States, emissions per output tend to rise. A relationship between the adoption of the Common Agricultural policy and the emissions level can be detected for Spain, Austria, Finland and Sweden.

  14. Synthesis and photoluminescence properties of Ba2CaZn2Si6O17:Eu3+ red phosphors for white LED applications

    International Nuclear Information System (INIS)

    Annadurai, G.; Kennedy, S. Masilla Moses

    2016-01-01

    Novel pellyite type Ba 2 CaZn 2 Si 6 O 17 :Eu 3+ red emitting phosphors with different Eu 3+ contents were synthesized by the solid state reaction method. The crystal structure, photoluminescence properties and concentration quenching of Ba 2 CaZn 2 Si 6 O 17 :Eu 3+ phosphors were investigated. Powder X-ray diffraction measurements confirmed the structure of the samples. The photoluminescence emission (PL) and excitation (PLE) spectra were measured. The results showed that the dominant hypersensitive red emission peak of the phosphors Ba 2 CaZn 2 Si 6 O 17 :Eu 3+ was located at 613 nm attributed to the Eu 3+ transition ( 5 D 0 → 7 F 2 ) which could be effectively excited by 395 nm (near-UV). The latter band matched well with the emission from the near-UV LED chips. The intensity ratio of 5 D 0 → 7 F 2 to 5 D 0 → 7 F 1 transition showed slight variation with Eu 3+ concentrations. The Eu 3+ emission intensity was maximum for 9 mol%. The luminescence quantum efficiency was determined and also the decay profiles were obtained and analyzed. In addition, the Commission International del'Eclairage (CIE) chromaticity coordinates of Ba 2 CaZn 2 Si 6 O 17 :0.09Eu 3+ phosphor were calculated to be 0.637 and 0.362. The experimental results demonstrated that the Ba 2 CaZn 2 Si 6 O 17 :Eu 3+ red emitting phosphor is a potential candidate for white light emitting diodes (WLEDs) pumped by near-UV chip. - Highlights: • A novel Ba 2 CaZn 2 Si 6 O 17 :Eu 3+ red phosphor was synthesized. • The samples yielded a dominant PL emission of Eu 3+ at 613 nm. • Eu 3+ concentration was optimized to be 9 mol% in Ba 2 CaZn 2 Si 6 O 17. • CIE chromaticity coordinates were estimated from the emission spectrum.

  15. Pipelines of Progress: An Update on the Glass Ceiling Initiative. A Status Report.

    Science.gov (United States)

    Department of Labor, Washington, DC.

    The "glass ceiling" refers to those barriers that have prevented the advancement of women and minorities into the top levels of executive management in major U.S. corporations. In 1991, the U.S. Department of Labor released a report describing the Glass Ceiling Initiative. This document reports on what occurred in the year following the…

  16. Economic Impacts of the 1997 EU Energy Tax: Simulations with Three EU-Wide Models

    International Nuclear Information System (INIS)

    Jansen, H.; Klaassen, G.

    2000-01-01

    In March 1997 the European Commission adopted a proposal that increases existing minimum levels of taxation on mineral oils by around 10 to 25% and introduces excises for other energy products. This paper analyses the macroeconomic impacts of the proposal. It employs three models: HERMES, GEM-E3, and E3ME. All models confirm that the proposal will have positive macroeconomic impacts when the tax revenues are used to reduce social security contributions paid by employers. For the EU as a whole, both GDP and employment are expected to be higher and CO2 emissions are 0.9 to 1.6 percent lower. The positive EU-wide effects can be observed in practically all member states. The sector impacts are modest, with the energy sector expected to face the most negative impacts. Differences between model results are due to the model type (general equilibrium or macro-econometric), the EU countries covered and the way tax exemptions were handled. Crucial assumptions to obtain the 'double dividend' are the modelling of the labour market and the impacts on EU external trade. The sensitivity of the results for the use of tax revenues, tax exemptions and tax rate increases is assessed. 21 refs

  17. Window screening, ceilings and closed eaves as sustainable ways to control malaria in Dar es Salaam, Tanzania

    Directory of Open Access Journals (Sweden)

    Chaki Prosper P

    2009-09-01

    Full Text Available Abstract Background Malaria transmission in Africa occurs predominantly inside houses where the primary vectors prefer to feed. Human preference and investment in blocking of specific entry points for mosquitoes into houses was evaluated and compared with known entry point preferences of the mosquitoes themselves. Methods Cross-sectional household surveys were conducted in urban Dar es Salaam, Tanzania to estimate usage levels of available options for house proofing against mosquito entry, namely window screens, ceilings and blocking of eaves. These surveys also enabled evaluation of household expenditure on screens and ceilings and the motivation behind their installation. Results Over three quarters (82.8% of the 579 houses surveyed in Dar es Salaam had window screens, while almost half (48.9% had ceilings. Prevention of mosquito entry was cited as a reason for installation of window screens and ceilings by 91.4% (394/431 and 55.7% (127/228 of respondents, respectively, but prevention of malaria was rarely cited (4.3%, 22/508. The median cost of window screens was between US $ 21-30 while that of ceilings was between US $301-400. The market value of insecticide-treated nets, window screening and ceilings currently in use in the city was estimated as 2, 5 and 42 million US$. More than three quarters of the respondents that lacked them said it was too expensive to install ceilings (82.2% or window screens (75.5%. Conclusion High coverage and spending on screens and ceilings implies that these techniques are highly acceptable and excellent uptake can be achieved in urban settings like Dar es Salaam. Effective models for promotion and subsidization should be developed and evaluated, particularly for installation of ceilings that prevent entry via the eaves, which are the most important entry point for mosquitoes that cause malaria, a variety of neglected tropical diseases and the nuisance which motivates uptake.

  18. Preparation of Ca0.5Zr2(PO4)3 and Ca0.45Eu0.05Zr2(PO4)3 nanopowders: structural characterization and luminescence emission study

    International Nuclear Information System (INIS)

    Alcaraz, L; Isasi, J; Díaz-Guerra, C; Peiteado, M; Caballero, A C

    2016-01-01

    Ca 0.5 Zr 2 (PO 4 ) 3 and Ca 0.45 Eu 0.05 Zr 2 (PO 4 ) 3 nanophosphors have been synthesized by a sol–gel process under acid and basic conditions. In order to achieve the reduction of Eu 3+ to Eu 2+ , europium-doped samples were treated in a reducing atmosphere flow. The effects of the different synthesis conditions and the partial substitution of calcium by europium ions on the structure of the samples were analyzed by x-ray diffraction (XRD) transmission electron microscopy (TEM) and micro-Raman spectroscopy. Luminescence and magnetic properties were investigated by photoluminescence (PL) spectroscopy and magnetic susceptibility measurements. XRD patterns can be indexed to a rhombohedral symmetry of space group R-3 with Z  =  6, consistent with a NASICON-type structure. A higher crystallinity was found in the samples prepared under basic conditions. TEM images of all the synthesized samples show spherically shaped particles. A broadening of the Raman bands as a result of non-equivalent vibrations of the orthophosphate groups is observed for samples prepared under acid conditions. The same effect was found when calcium is substituted by europium into the Ca 0.5 Zr 2 (PO 4 ) 3 host. PL spectra exhibit strong emission in the blue-green spectral range due to Eu 2+ 4f 6 5d 1 -4f 7 transitions and no evidence of Eu 3+ emission. Magnetic measurements confirm the 2+  oxidation state of europium ions in all samples. (paper)

  19. Synthesis and effect of Ce and Mn co-doping on photoluminescence characteristics of Ca6AlP5O20:Eu novel phosphors.

    Science.gov (United States)

    Shinde, K N; Dhoble, S J

    2013-01-01

    A series of Ca6AlP5O20 doped with rare earths (Eu and Ce) and co-doped (Eu, Ce and Eu,Mn) were prepared by combustion synthesis. Under Hg-free excitation, Ca6AlP5O20:Eu exhibited Eu(2+) (486 nm) emission in the blue region of the spectrum and under near Hg excitation (245 nm), Ca6AlP5O20:Ce phosphor exhibited Ce(3+) emission (357 nm) in the UV range. Photoluminescence (PL) peak intensity increased in Ca6AlP5O20:Eu,Ce and Ca6AlP5O20:Eu, Mn phosphors due to co-activators of Ce(3+) and Mn(2+) ions. As a result, these ions played an important role in PL emission in the present matrix. Ca6AlP5O20:Eu, Ce and Ca6AlP5O20:Eu, Mn phosphors provided energy transfer mechanisms via Ce(3+) → Eu(2+) and Eu(2+) → Mn(2+), respectively. Eu ions acted as activators and Ce ions acted as sensitizers. Ce emission energy was well matched with Eu excitation energy in the case of Ca6AlP5O20:Eu, Ce and Eu ions acted as activators and Mn ions acted as sensitizers in Ca6AlP5O20:Eu, Mn. This study included synthesis of new and efficient phosphate phosphors. The impact of doping and co-doping on photoluminescence properties and energy transfer mechanisms were investigated and we propose a feasible interpretation. Copyright © 2012 John Wiley & Sons, Ltd.

  20. Tendances Carbone no. 70 'The EU ETS and the economic downturn: falling emissions and increasing use of credits'

    International Nuclear Information System (INIS)

    Berghmans, Nicolas; Stephan, Nicolas

    2012-01-01

    Among the publications of CDC Climat Research, 'Tendances Carbone' bulletin specifically studies the developments of the European market for CO 2 allowances. This issue addresses the following points: The publication of the 2011 compliance data confirms that the EU ETS carbon price will remain at a low level in the short and medium term. These data indicate a drop in CO 2 emissions by 2.1% and the return of 254.7 million Kyoto credits up 86% compared to 2010. In the context of a growing surplus of allowances since 2008, these two trends further weaken the demand for allowances

  1. 2D and 3D GPR imaging of structural ceilings in historic and existing constructions

    Science.gov (United States)

    Colla, Camilla

    2014-05-01

    GPR applications in civil engineering are to date quite diversified. With respect to civil constructions and monumental buildings, detection of voids, cavities, layering in structural elements, variation of geometry, of moisture content, of materials, areas of decay, defects, cracks have been reported in timber, concrete and masonry elements. Nonetheless, many more fields of investigation remain unexplored. This contribution gives an account of a variety of examples of structural ceilings investigation by GPR radar in reflection mode, either as 2D or 3D data acquisition and visualisation. Ceilings have a pre-eminent role in buildings as they contribute to a good structural behaviour of the construction. Primarily, the following functions can be listed for ceilings: a) they carry vertical dead and live loads on floors and distribute such loads to the vertical walls; b) they oppose to external horizontal forces such as wind loads and earthquakes helping to transfer such forces from the loaded element to the other walls; c) they contribute to create the box skeleton and behaviour of a building, connecting the different load bearing walls and reducing the slenderness and flexural instability of such walls. Therefore, knowing how ceilings are made in specific buildings is of paramount importance for architects and structural engineers. According to the type of building and age of construction, ceilings may present very different solutions and materials. Moreover, in existing constructions, ceilings may have been substituted, modified or strengthened due to material decay or to change of use of the building. These alterations may often go unrecorded in technical documentation or technical drawings may be unavailable. In many cases, the position, orientation and number of the load carrying elements in ceilings may be hidden or not be in sight, due for example to the presence of false ceilings or to technical plants. GPR radar can constitute a very useful tool for

  2. Energy Efficiency and Emissions Trading. A PEEREA perspective after the entry into force of the Kyoto Protocol and of the EU ETS

    International Nuclear Information System (INIS)

    2006-01-01

    The year 2005 was of particular importance for the climate change discussions. The Kyoto Protocol entered into force in February, following the Russian ratification. At the same time, the largest emission-trading scheme for CO2, the EU ETS came into operation. By the end of the year the first Meeting of the Parties to the UNFCCC took place in Montreal. The PEEREA Group discussed on several occasions the contribution of the Kyoto flexible mechanisms to boosting energy efficiency improvements. The role of energy efficiency projects in achieving climate change objectives was equally underlined. In 2004 a report was elaborated and subsequently printed on Carbon Trading and Energy Efficiency, with the understanding that the PEEREA Group will revisit the subject in order to reflect on new developments in this area. This paper, prepared by the Secretariat with the consultancy support of EcoSecurities, served the discussion and debate in the PEEREA Group on the latest developments and opportunities for energy efficiency in the climate change process. The paper provides only a brief introduction of the main concepts, as they were presented and discussed in the 2004 report. The focus is now on the operation of the EU ETS and on the implications for both EU and non EU PEEREA countries of the Linking Directive on the use of JI/CDM mechanisms in relation to improving energy efficiency

  3. Tricolor emission Ca3Si2O7:Ln (Ln=Ce, Tb, Eu) phosphors for near-UV white light-emitting-diode

    International Nuclear Information System (INIS)

    Mao, Zhi-yong; Zhu, Ying-chun; Gan, Lin; Zeng, Yi; Xu, Fang-fang; Wang, Yang; Tian, Hua; Li, Jian; Wang, Da-jian

    2013-01-01

    Tricolor emission in a same Ca 3 Si 2 O 7 host with independent Ln (Ln=Ce 3+ , Eu 2+ , Tb 3+ ) dopants is demonstrated to construct a near-UV white light emitting diode (LED). The luminescence properties and thermal quenching properties, as well as the applications in near-UV white LED are investigated. These phosphors show typical blue, red, and green, three-basal-color, luminescence in the CIE chromaticity diagram for Ce 3+ , Eu 2+ and Tb 3+ dopants, respectively. Thermal quenching properties show that the luminescence thermal stability strongly depends on the different dopant types; better thermal quenching property of Ce 3+ and Tb 3+ is recorded in comparison with that of Eu 2+ . The white LED prototype fabricated with near-UV chip and as-prepared tricolor phosphors exhibits acceptable CIE chromaticity coordinates (0.32, 0.30) with a CCT of 6000 K and a CRI of 87, indicating the potential application of Ca 3 Si 2 O 7 :Ln phosphors in near-UV white LED. - Highlights: ► Tricolor Ca 3 Si 2 O 7 : Ln phosphors were demonstrated to construct near-UV white LED. ► Eu 2+ doped Ca 3 Si 2 O 7 red-emitting phosphor was confirmed by this work once again. ► Thermal quenching properties for Ca 3 Si 2 O 7 :Ln phosphors were reported for the first time. ► Performances of fabricated white LED indicated the potential application of phosphors.

  4. Control of the dew point for refreshing ceiling

    Energy Technology Data Exchange (ETDEWEB)

    Abrach, R.; Nitz, T.

    1996-03-01

    The functioning of a refreshing ceiling, delivered in water, needs a global regulation which must take in consideration, the local, the building and its environment. Then efficiency and energy and investments economy are optimized. 11 figs., 3 tabs.

  5. Rethinking Sensitized Luminescence in Lanthanide Coordination Polymers and MOFs: Band Sensitization and Water Enhanced Eu Luminescence in [Ln(C15H9O5)3(H2O)3]n (Ln = Eu, Tb).

    Science.gov (United States)

    Einkauf, Jeffrey D; Kelley, Tanya T; Chan, Benny C; de Lill, Daniel T

    2016-08-15

    A coordination polymer [Ln(C15H9O9)3(H2O)3]n (1-Ln = Eu(III), Tb(III)) assembled from benzophenonedicarboxylate was synthesized and characterized. The organic component is shown to sensitize lanthanide-based emission in both compounds, with quantum yields of 36% (Eu) and 6% (Tb). Luminescence of lanthanide coordination polymers is currently described from a molecular approach. This methodology fails to explain the luminescence of this system. It was found that the band structure of the organic component rather than the molecular triplet state was able to explain the observed luminescence. Deuterated (Ln(C15H9O9)3(D2O)3) and dehydrated (Ln(C15H9O9)3) analogues were also studied. When bound H2O was replaced by D2O, lifetime and emission increased as expected. Upon dehydration, lifetimes increased again, but emission of 1-Eu unexpectedly decreased. This reduction is reasoned through an unprecedented enhancement effect of the compound's luminescence by the OH/OD oscillators in the organic-to-Eu(III) energy transfer process.

  6. Carbon dioxide storage. EU legal framework for carbon capture and storage

    International Nuclear Information System (INIS)

    Heller, W.

    2008-01-01

    In the correct opinion of the EU Commission, fossil fuels are going to remain the most important energy source worldwide also in the decades to come. The intention of the EU to reduce by 50% the 1990 level of greenhouse gas emission by 2050 can become reality, in the light of worldwide developments, only if the energy potential of coal can be tapped without multiplying emissions. The EU therefore initiated measures to make carbon capture and storage a standard technology in new fossil fired power plants. The CCS technology is to be demonstrated so as to make it available commercially for plant renewal after 2020 (CCS = Carbon Capture and Storage). To outline the future legal framework in the European Union, the EU Commission on January 23, 2008 presented the proposal of a Directive on Geologic Storage of Carbon Dioxide (CO 2 ). That proposal mainly focuses on the storage of CO 2 and the removal of obstacles in the way of CO 2 storage. The capture and pipeline transport of CO 2 are taken into account in the appropriate amendments to existing directives. (orig.)

  7. Consistency of policy instruments. How the EU could move to a -30% greenhouse gas reduction target

    Energy Technology Data Exchange (ETDEWEB)

    Hoehne, N.; Hagemann, M.; Moltmann, S.; Escalante, D. [Ecofys Germany, Berlin (Germany)

    2011-04-15

    The report provides options for how to achieve a 30% reduction in greenhouse gas emissions, in the EU, from 1990 to 2020. The EU has agreed a set of goals (objectives) and related instruments for 2020. The most significant objectives are the 20% or 30% reduction of greenhouse gases (all emissions, both within and outside the Emissions Trading System), the 20% improvement of energy efficiency and the 20% of renewable energy use by 2020. The stringency of the instruments used to reach these goals, must be set carefully to ensure overall consistency. Particularly after the economic crisis of 2008/2009, the Climate and Energy Package has to be 'tuned' again to be fully consistent, e.g. fast take up of renewable energy and fewer emissions due to the recession may cause an over-allocation in the EU-ETS.

  8. Tendances Carbone no. 101. Will anybody dare resuscitating the EU ETS?

    International Nuclear Information System (INIS)

    Schleicher, Stefan

    2015-04-01

    Among the publications of CDC Climat Research, 'Tendances Carbone' bulletin specifically studies the developments of the European market for CO 2 allowances. Beside some statistical figures about energy production/consumption and carbon markets, this issue specifically addresses the following points: - EU ETS - MSR timetable: The first Trilogue meeting between EU institutions took place on 30 March. The second is scheduled on 5 May. The Committee of Permanent Representatives of the Member States approved an implementation of the MSR in 2021. - EU's INDC: On 6 March, the EU Environment Council approved the EU's intended nationally determined contribution to achieve at least 40% domestic reduction in GHG emissions by 2030 compared to 1990 levels. - Consultations: On 26 March, the EU Commission launched two parallel consultations running until 18 June on the development of 2030 climate and energy policies in the sectors not covered by the EU ETS

  9. Time-resolved luminescence of Eu2+-aggregate centers in CsBr crystals

    International Nuclear Information System (INIS)

    Zorenko, Yu.V.; Turchak, R.M.; Voznjak, T.I.; Stryganjuk, G.B.

    2005-01-01

    The luminescence of Eu 2+ -V Cs dipole centers and CsEuBr 3 aggregate centers, as well as the features of the energy transfer to these centers by excitons have been studied in CsBr:Eu crystals by means of investigation of the time-resolved emission spectra and luminescence decay kinetics under excitation by synchrotron radiation at RT. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  10. Linking project-based mechanisms with domestic greenhouse gas emissions trading schemes

    International Nuclear Information System (INIS)

    Bygrave, S.; Bosi, M.

    2004-01-01

    Although there are a number of possible links between emission trading and project-based mechanisms, the focus of this paper is on linking domestic GHG emission trading schemes with: (1) domestic; and, (2) international (JI and CDM) GHG reduction project activities. The objective is to examine some of the challenges in linking DETs and project-based mechanisms, as well as some possible solutions to address these challenges. The link between JI / CDM and intergovernmental international emissions trading (i.e. Article 17 of the Kyoto Protocol) is defined by the Kyoto Protocol, and therefore is not covered in this paper. The paper is written in the context of: (a) countries adhering to the Kyoto Protocol and elaborating their strategies to meet their GHG emission commitments, including through the use of the emissions trading and project-based mechanisms. For example, the European Union (EU) will be commencing a GHG Emissions Trading Scheme in January 2005, and recently, the Council of ministers and the European Parliament agreed on a text for an EU Linking Directive allowing the use of JI and CDM emission units in the EU Emission Trading Scheme (EU-ETS); and (b) all countries (and/or regions within countries) with GHG emission obligations that may choose to use domestic emissions trading and project-based mechanisms to meet their GHG commitments. The paper includes the following elements: (1) an overview of the different flexibility mechanisms (i.e. GHG emissions trading and PBMs), including a brief description and comparisons between the mechanisms (Section 3); (2) an exploration of the issues that emerge when project-based mechanisms link with domestic emissions trading schemes, as well as possible solutions to address some of the challenges raised (Section 4); (3) a case study examining the EU-ETS and the EU Linking Directive on project-based mechanisms, in particular on how the EU is addressing in a practical context relevant linking issues (Section 5); (4) a

  11. Enhanced luminescence properties of YBO{sub 3}:Eu{sup 3+} phosphors by Li-doping

    Energy Technology Data Exchange (ETDEWEB)

    Balakrishnaiah, R. [Department of Electronic Materials Engineering, Silla University, Busan 617-736 (Korea, Republic of); Department of Physics, Pukyong National University, Busan 608-737 (Korea, Republic of); Yi, Soung Soo, E-mail: ssyi@silla.ac.kr [Department of Electronic Materials Engineering, Silla University, Busan 617-736 (Korea, Republic of); Jang, Kiwan; Lee, Ho Sueb [Department of Physics, Changwon National University, Changwon 641-773 (Korea, Republic of); Moon, Byung Kee; Jeong, Jung Hyun [Department of Physics, Pukyong National University, Busan 608-737 (Korea, Republic of)

    2011-04-15

    Different concentrations of Li-doped YBO{sub 3}:Eu{sup 3+} phosphors have been prepared by the conventional solid state reaction method and were characterized by X-ray diffraction, field emission scanning electron microscopy, photoluminescence excitation and emission measurements. An intense reddish orange emission is observed under UV excitation and the emitted radiation was dominated by an orange peak at 594 nm resulted from the {sup 5}D{sub 0} {yields} {sup 7}F{sub 1} transitions of Eu{sup 3+} ions. The brightness of the YBO{sub 3}:Eu{sup 3+} phosphor was found greatly improved with Li-doping accompanied by slight improvement in the purity of the color which might be attributed to improvement in crystallinity, grain sizes and creation of oxygen vacancies with Li-doping. The observed results have been discussed in comparison with similar reported works.

  12. Effects of a thermal ceiling on postoperative hypothermia

    DEFF Research Database (Denmark)

    Henneberg, S; Eklund, A; Joachimsson, P O

    1985-01-01

    postoperatively with or without external heating from a heating ceiling. Central and peripheral temperatures, oxygen consumption, plasma catecholamines and shivering were measured. A method for continuous measurement of oxygen consumption and carbon dioxide production during spontaneous breathing is described...

  13. Economic impact assessment of Turkey's post-Kyoto vision on emission trading

    International Nuclear Information System (INIS)

    Akın Olçum, Gökçe; Yeldan, Erinç

    2013-01-01

    For the post-Kyoto period, Turkey strongly emphasizes the establishment of national emission trading system by 2015 and its integration with the EU ETS along its accession process to the EU. In this paper, we study the mechanisms of adjustment and economic welfare consequences of various ETS regimes that Turkey considers to apply by 2020, i.e. regional ETS and international trading within the EU ETS. We conduct our analysis under the current EU 20–20–20 emission target, 20%, and also under its revised version, 30%. We find that Turkey has economic gains from linking with the EU ETS under the 20% cap, in comparison to the domestic ETSs. Despite the EU's welfare loss under linkage in comparison to the case where Turkey has domestic abatement efforts, it still prefers linking as it increases economic well being compared to the case where Turkey does not abate. Under 30% cutback, Turkey has critical output loss under linkage due to high abatement burden on the EU, while the EU is better off as it passes some of its abatement burden to Turkey. Therefore, emission quotas and their allocation across the ETS and non ETS sectors become highly critical in distributing the overall economic gains from bilateral trading. - Highlights: • We conduct welfare analysis of Turkey's post-Kyoto vision on emission trading. • Welfare impacts of having Turkey in the EU ETS via EU accession are analyzed. • Analysis is done with the current EU target of 20%, and the revised target of 30%. • Welfare impacts of linkage on both regions highly depend on the emission targets. • The EU has welfare gains when Turkey engages in abatement actions

  14. Voltage color tunable OLED with (Sm,Eu)-β-diketonate complex blend

    Science.gov (United States)

    Reyes, R.; Cremona, M.; Teotonio, E. E. S.; Brito, H. F.; Malta, O. L.

    2004-09-01

    Light emission from organic electroluminescent diodes (OLEDs) in which mixed samarium and europium β-diketonate complexes, [Sm 0.7Eu 0.3(TTA) 3(TPPO) 2], was used as the emitting layer is described. The electroluminescence spectra exhibit narrow peaks arising from 4f-intraconfigurational transitions of the Sm 3+ and Eu 3+ ions and a broad emission band attributed to the electrophosphorescence of the TTA ligand. The intensity ratio of the peaks determined by the bias voltage applied to the OLED, together with the ligand electrophosphorescence, allows to obtain a voltage-tunable color light source.

  15. Environmental policy instruments towards lignite-fired power plants in Turkey

    International Nuclear Information System (INIS)

    2006-01-01

    A proposition is made that Turkey considers a pilot emission trading system for SO 2 , Nox and/or PM emissions from its coal and lignite fired power plant in the efforts to comply with the EU Integrated Pollution Prevention Control (IPPC), the Large Combustion Plant (LCP) and the National Emissions Ceiling (NEC) Directives. Model calculations indicate that this could yield substantial cost savings compared to a traditional command and control approach. However, requirements in the IPPC Directive would be a major obstacle against emissions trading. The Turkish emission permitting system needs a major overhaul, including improving monitoring and enforcement practices to comply with the directives and to be able to implement and operate an emission trading system

  16. Environmental policy instruments towards lignite-fired power plants in Turkey

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    A proposition is made that Turkey considers a pilot emission trading system for SO{sub 2}, Nox and/or PM emissions from its coal and lignite fired power plant in the efforts to comply with the EU Integrated Pollution Prevention Control (IPPC), the Large Combustion Plant (LCP) and the National Emissions Ceiling (NEC) Directives. Model calculations indicate that this could yield substantial cost savings compared to a traditional command and control approach. However, requirements in the IPPC Directive would be a major obstacle against emissions trading. The Turkish emission permitting system needs a major overhaul, including improving monitoring and enforcement practices to comply with the directives and to be able to implement and operate an emission trading system.

  17. Tuning of "antenna effect" of Eu(III) in ternary systems in aqueous medium through binding with protein.

    Science.gov (United States)

    Ghorai, Shyamal Kr; Samanta, Swarna Kamal; Mukherjee, Manini; Saha Sardar, Pinki; Ghosh, Sanjib

    2013-02-04

    A simple ternary system containing a protein [human serum albumin (HSA)/bovine serum albumin (BSA)], tetracycline hydrochloride (TC), and Eu(III) in suitable aqueous buffer medium at physiological pH (= 7.2) has been shown to exhibit highly efficient "antenna effect" compared to the binary complex of TC with Eu(III) (Eu(3)TC). The ternary system containing E. coli alkaline phosphatase (AP), TC, and Eu(III), however, shows a slight enhancement of Eu(III) emission, although the binding constant of AP with TC is 2 orders of magnitude greater than with BSA/HSA. The enhanced emission of bound TC in the binary systems containing proteins and TC gets quenched in the ternary systems containing HSA/BSA, showing the efficient energy transfer (ET) from TC to Eu(III). Steady state and time-resolved emission studies of each component in all the ternary systems in H(2)O and in D(2)O medium reveal that Eu(III) is very well protected from the O-H oscillator in the ternary system containing HSA/BSA compared to that containing AP. The docking studies locating the binding site of TC in the proteins suggest that TC binds near the surface of AP. In the case of HSA/BSA, TC resides in the interior of the protein resulting in a large shielding effect of Eu(III). The rotational correlation time (θ(c)) determined from the anisotropy decay of bound TC in the complexes and the accessible surface area (ASA) of the ligand in the complexes obtained from the docking studies also support the contention that Eu(3)TC is more exposed to solvent in the case of the ternary system consisting of AP, TC, and Eu(III). The calculated radiative lifetime and the sensitization efficiency ratio of Eu(III) in all the systems clearly demonstrate the protein mediated tuning of "antenna effect" in Eu(III).

  18. Effects of Pb doping on the magneto-optical properties of EuPbTe epitaxial films

    Energy Technology Data Exchange (ETDEWEB)

    Heredia, E.; Motisuke, P. [Laboratório Associado de Sensores e Materiais, Instituto Nacional de Pesquisas Espaciais, São José dos Campos, 12227-010 SP (Brazil); Couto, O.D.D. Jr. [Instituto de Física “Gleb Wataghin” – Universidade Estadual de Campinas, Campinas, 13083-859 SP (Brazil); Lang, R. [Instituto de Física “Gleb Wataghin” – Universidade Estadual de Campinas, Campinas, 13083-859 SP (Brazil); Institute of Science and Technology, UNIFESP, São José dos Campos, 12231-280 SP (Brazil); Balanta, M.A.G.; Brasil, M.J.S.P. [Instituto de Física “Gleb Wataghin” – Universidade Estadual de Campinas, Campinas, 13083-859 SP (Brazil); Oliveira Rappl, P.H. de [Laboratório Associado de Sensores e Materiais, Instituto Nacional de Pesquisas Espaciais, São José dos Campos, 12227-010 SP (Brazil); Iikawa, F., E-mail: iikawa@ifi.unicamp.br [Laboratório Associado de Sensores e Materiais, Instituto Nacional de Pesquisas Espaciais, São José dos Campos, 12227-010 SP (Brazil); Instituto de Física “Gleb Wataghin” – Universidade Estadual de Campinas, Campinas, 13083-859 SP (Brazil)

    2015-11-15

    We investigate the magneto-optical properties of magnetic-semiconductor Eu{sub 1−x}Pb{sub x}Te epitaxial layers with Pb contents up to 5%. We show that the inclusion of a small amount of Pb atoms in EuTe affects the optical and magnetic properties of the resulting alloy. The incorporation of Pb gives rise to a reduction of the Néel temperature and of the slope of the giant magneto-red-shift of the magnetic polaron optical emission. All those effects can be understood in terms of the magnetic dilution effect due to the reduced Eu concentration. The introduction of Pb also reveals a splitting of the high emission energy side-band under applied magnetic field, presenting a more complex feature of the band structure of the alloys. Our results cannot be fully explained on the basis of the current theoretical knowledge of the EuTe band structure and, therefore, we expect that they can stimulate future theoretical investigations and encourage applied investigations of spintronic devices based on these materials. - Highlights: • Reduction of the Néel temperature when small amount of Pb is introduced into EuTe. • The saturation magnetic field needed to fully order the magnetic moments of Eu also reduces increasing Pb content. • Splitting of the high energy optical emission line under applied magnetic field, which is more evident for Pb doped samples.

  19. Ouch! Or ESL and the Glass Ceiling.

    Science.gov (United States)

    Migliacci, Naomi

    The realities of the glass ceiling, which prevents qualified women, minorities, and many English-as-a-Second-Language (ESL) students from advancement and promotion, are rarely discussed in English for Special Purposes (ESP)/ESL programs and courses. This paper explores the barriers to success, focusing on the sociolinguistic factors of verbal and…

  20. Glass Ceiling for Women in Higher Education.

    Science.gov (United States)

    Schedler, Petra; Glastra, Folke; Hake, Barry

    2003-01-01

    Discusses the place of women in higher education in the Netherlands. Suggests that it is not a question of numbers but of orientation, field, and the glass ceiling. Asserts that despite some improvement, higher education may be one of the last bastions against the recognition of women's worth. (Contains 42 references.) (JOW)

  1. Low temperature synthesis, characterization and tunable optical properties of Eu3+, Tb3+ doped CaMoO4 nanoparticles

    International Nuclear Information System (INIS)

    Sharma, K. Gayatri; Singh, Th. Prasanta; Singh, N. Rajmuhon

    2014-01-01

    Highlights: • Red and green nanophosphors of CaMoO 4 :Eu 3+ and Tb 3+ were synthesized via an ethylene glycol route at very low temperature. • The prepared nanoparticles have tetragonal structure. • The luminescence properties of the nanoparticles are also studied extensively. • CIE chromaticity coordinates of the phosphors are also studied. • The blue-green emission of host could be easily tuned to red or green by varying the dopant ion used in the host. - Abstract: CaMoO 4 doped with Eu 3+ and Tb 3+ nanoparticles are obtained using ethylene glycol as the solvent. The synthesis has been carried out at 130 °C temperature. The XRD patterns reveal that all the doped samples are well assigned to the scheelite structure of the CaMoO 4 phase. Upon excitation by ultraviolet radiation, the CaMoO 4 :Eu 3+ , Tb 3+ phosphors show the characteristic emission lines of Eu 3+ and Tb 3+ . For Eu 3+ doped samples, red emission dominates over other transitions and for Tb 3+ doped, green emission is the predominant one. The blue-green emission of the host could be easily tuned to red and green by doping with activator ions. The emission intensity is also dependent on the concentration of the dopant ions. The prepared nanoparticles could find applications in LEDs and other optical devices

  2. A new process for NOx reduction in combustion systems for the generation of energy from waste.

    Science.gov (United States)

    Gohlke, Oliver; Weber, Toralf; Seguin, Philippe; Laborel, Yann

    2010-07-01

    In the EU, emissions from energy from waste plants are largely reduced by applying the Waste Incineration Directive with its limit of 200 mg/m3(s) for NO(x) emissions. The need for further improvement is reflected by new German legislation effective as of 27 January 2009, requiring 100 mg/m3(s). Other countries are expected to follow this example due to the national emission ceilings of the Gothenburg protocol and the concluding EU directive 2001/81/EC. On the other hand, an increase in energy efficiency will be encouraged by the EU Waste Framework Directive. This is why there is a need for new technologies that make it possible to reconcile both requirements: reduced emissions and increased energy efficiency. A new process combining the internal recirculation of flue gas with ammonia or urea injection in order to achieve less then 80 mg/m3(s) of NO(x) is described. Important additional features of the process are an R1 efficiency above the required 0.65 of the EU Waste Framework Directive even with standard steam parameters of 40 bar/380 degrees C as well as low ammonia slip in the flue gas at the boiler outlet of below 10 mg/m3(s). Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  3. THE IMPACT OF ORGANIZATIONAL STRUCTURE ON GLASS CEILING: AEGEAN REGION AGENCIES IN TURKEY

    OpenAIRE

    İNEL, Merve; GARAYEV, Vener; BAKAY, Aziz

    2014-01-01

    This study examined the relationship between organizationalstructure (mechanistic/organic) and glass ceiling, the concept known asnegative discrimination against women in workplace. The data collected fromrandomly selected 81 organizations in Aegean Region of Turkey was analyzedthrough hierarchical stepwise multiple regression. The results of the finalregression model suggest that glass ceiling is not dependent on organizationalstructure, while the control variable gender has a negative relat...

  4. Photoluminescence properties of the Eu-doped alpha-Al2O3 microspheres

    International Nuclear Information System (INIS)

    Liu, Dianguang; Zhu, Zhenfeng

    2014-01-01

    Highlights: • Al 2 O 3 :Eu 3+ phosphors were prepared via a microwave solvothermal route. • The particles were hierarchically nanostructured microspheres packaged by nanosheets. • The powders presented excellent orange–red emission when excited at 393 nm. • Critical concentration and distance of Eu 3+ in Al 2 O 3 is 0.007, 18 Å, respectively. -- Abstract: Al 2 O 3 :Eu 3+ samples were synthesized via microwave solvothermal method and thermal decomposition of Eu 3+ doped precursors. The sample characterizations were carried out by means of X-ray diffraction (XRD), scanning electron microscope (SEM) and photoluminescence (PL) spectra. XRD results indicated that Eu 3+ doped samples were most of α-Al 2 O 3 phase after being calcined at 1473 K. SEM results showed that the obtained α-Al 2 O 3 based powders via microwave solvothermal method were microspheres with an average diameter about 1.6 μm. PL spectra showed that upon excitation at 393 nm, the orange–red emission bands at the wavelength longer than 560 nm were from 5 D 0 → 7 F J (J = 1, 2) transitions. The asymmetry ratio of ( 5 D 0 → 7 F 2 )/( 5 D 0 → 7 F 1 ) intensity is about 1 and this value suggests that Eu 3+ ions occupy the same ratio of symmetry and asymmetry sites. It is shown that the 0.7 mol% of doping concentration of Eu 3+ ions in α-Al 2 O 3 :Eu 3+ is optimum. According to Dexter’s theory, the critical distance between Eu 3+ ions for energy transfer was determined to be 18 Å

  5. Point Climat no. 12 'The EU ETS carbon price: To intervene, or not to intervene?'

    International Nuclear Information System (INIS)

    Sartor, Oliver

    2012-01-01

    Among the publications of CDC Climat Research, 'Climate Briefs' presents, in a few pages, hot topics in climate change policy. This issue addresses the following points: Extraordinary economic circumstances and interactions between climate and energy policies have meant that the EU's industrial CO 2 emissions are now much lower than expectations when the EU ETS' emissions reduction objectives were set. Since this has reduced the demand for EU ETS emissions allowances relative to a fixed supply, the price of allowances has fallen significantly. Although this is a normal market reaction, it has led to demands for intervention in the market to support the price. This brief discusses this issue. It concludes that, above all, a robust and effective CO 2 price signal requires a more credible commitment on the part of policy-makers to an ambitious post-2020 emissions budget. Barring that, if any intervention is to occur, the way it is 'framed' will be extremely important for the precedent it sets

  6. Panorama 2016 - Overview of the refining industry in the European Union Emissions Trading System (EU ETS)

    International Nuclear Information System (INIS)

    Coussy, Paula; Jalard, Matthieu

    2015-12-01

    Since 2008, emissions from the refining sector have fallen by more than 12%, reaching 128 MtCO 2 e in 2014. Germany was the largest emitter of CO 2 e for the 2005- 2014 period. With Italy, Spain, the United Kingdom, France and the Netherlands, these six countries accounted for 71% of the industry's emissions in the EU ETS for 2014. During the 2008-2014 period, the European refining sector had a surplus of 74 MtCO 2 e, but since 2013 has had an annual deficit. Estimates show that the overall surplus of 74 MtCO 2 e should vanish by 2015. In the future, European demand for petroleum products will drop, and forecasts for crude processing are expected to decline. IFPEN estimates that, by 2035, this decline should reach 30%, leading to a 20% drop in the sector's emissions. Against this background, the amount of free allowances in the refining sector will fall, from 80% in 2014 to nearly 75% in 2020, leading to compliance costs for the European refining sector of approximately euro 600 million for 2020 alone, compared with the $6 billion needed for investment in Europe by 2035. Due to the great disparity in efficiency among European refineries (difference when compared with the benchmark), it is clear that it will be extremely costly for certain refineries to remain in operation. This will lead to the likely closure of refineries that are less efficient in terms of GHG emissions. (authors)

  7. A multi-level analysis of the EU linking directive process: the controversial connection between EU and global climate policy

    Energy Technology Data Exchange (ETDEWEB)

    Flaam, Karoline Haegstad

    2007-10-15

    Despite initial scepticism in the EU towards the Kyoto Protocol's project mechanisms (the CDM and JI), the 'Linking Directive' was adopted in October 2004, connecting the EU emissions trading scheme with the project mechanisms. Not only was the Linking Directive settled remarkably quickly, the decision-making process also left a more liberal text, with fewer restrictions on the use of the project mechanisms, as compared to the initial directive proposal. This report examines possible explanations to this puzzle, evaluating whether Member State preferences, EU institutions or external influence from the climate regime best can contribute to understanding the process. On the basis of the analysis of written sources stemming from the decision-making process, as well as seven in-depth interviews, the report finds that Member State preferences were the main driver in the Linking Directive process. This gives support to the intergovernmentalist mantra, that Member States are the main decision-makers in the EU. It also challenges much recent research claiming that EU policy-making is increasingly being taken out of the hands of the nation-state and into supranational actors such as the Commission and the European Parliament. (author). 41 refs., figs., tabs

  8. A multi-level analysis of the EU linking directive process: the controversial connection between EU and global climate policy

    Energy Technology Data Exchange (ETDEWEB)

    Flaam, Karoline Haegstad

    2007-10-15

    Despite initial scepticism in the EU towards the Kyoto Protocol's project mechanisms (the CDM and JI), the 'Linking Directive' was adopted in October 2004, connecting the EU emissions trading scheme with the project mechanisms. Not only was the Linking Directive settled remarkably quickly, the decision-making process also left a more liberal text, with fewer restrictions on the use of the project mechanisms, as compared to the initial directive proposal. This report examines possible explanations to this puzzle, evaluating whether Member State preferences, EU institutions or external influence from the climate regime best can contribute to understanding the process. On the basis of the analysis of written sources stemming from the decision-making process, as well as seven in-depth interviews, the report finds that Member State preferences were the main driver in the Linking Directive process. This gives support to the intergovernmentalist mantra, that Member States are the main decision-makers in the EU. It also challenges much recent research claiming that EU policy-making is increasingly being taken out of the hands of the nation-state and into supranational actors such as the Commission and the European Parliament. (author). 41 refs., figs., tabs

  9. A Modest Manifesto for Shattering the Glass Ceiling.

    Science.gov (United States)

    Meyerson, Debra E.; Fletcher, Joyce K.

    2000-01-01

    Approaches to the glass ceiling--encouraging women to adopt "masculine" attributes, accommodating women's unique needs, or celebrating women's differences--have shortcomings. A fourth approach links equity and effectiveness. "Small wins" recognizes that gender inequity is rooted in cultural patterns and uses small initiatives…

  10. An equity assessment of introducing uncertain forest carbon sequestration in EU climate policy

    International Nuclear Information System (INIS)

    Münnich Vass, Miriam; Elofsson, Katarina; Gren, Ing-Marie

    2013-01-01

    Large emissions of greenhouse gases are expected to cause major environmental problems in the future. European policy makers have therefore declared that they aim to implement cost-efficient and fair policies to reduce carbon emissions. The purpose of this paper is to assess whether the cost of the EU policies for 2020 can be reduced through the inclusion of carbon sequestration as an abatement option while equity is also improved. The assessment is done by numerical calculations using a chance-constrained partial equilibrium model of the EU Emissions Trading Scheme and national effort-sharing targets, where forest sequestration is introduced as an uncertain abatement option. Fairness is evaluated by calculation of Gini-coefficients for six equity criteria to policy outcomes. The estimated Gini-coefficients range between 0.11 and 0.32 for the current policy, between 0.16 and 0.66 if sequestration is included and treated as certain, and between 0.19 and 0.38 when uncertainty about sequestration is taken into account and policy-makers wish to meet targets with at least 90 per cent probability. The results show that fairness is reduced when sequestration is included and that the impact is larger when sequestration is treated as certain. - Highlights: • We model EU's CO 2 emission reduction targets to 2020 for the 27 member states. • We assess the equity of including forest carbon sequestration in EU policy with six equity criteria. • A stochastic partial equilibrium model is used, in which abatement cost is minimised. • Current burden sharing within the EU is quite fair when compared with current income inequality. • The abatement cost is reduced and inequality increased when including sequestration

  11. Optical studies on Eu3+ doped boro-tellurite glasses

    Science.gov (United States)

    Maheshvaran, K.; Marimuthu, K.

    2012-06-01

    Eu3+ doped boro-tellurite glasses with the chemical composition (39-x)B2O3+30TeO2+15MgO+15K2O +xEu2O3 (where x = 0.01, 0.1, 1, 2 and 3 wt%) have been prepared by following conventional melt quenching technique. Spectroscopic properties of the Eu3+ doped boro-tellurite glasses have been studied by recording the optical absorption and luminescence measurements. Through the optical absorption spectra, bonding parameters (β¯, δ) have been calculated to identify the ionic/covalent nature of the glasses. Judd-Ofelt (JO) analysis have been carried out using the luminescence spectra. The JO parameters (Ωλ = 2, 4 and 6) were used to calculate the radiative properties for the 5D0 → 7FJ (J = 1, 2, 3 and 4) emission transitions of the Eu3+ ions. The change in optical properties with the variation of Eu3+ ion concentration have been studied and discussed with similar studies.

  12. The Perception of 'Glass Ceiling' and its Impact on Career Progression of Female Managers in Malaysia

    OpenAIRE

    Khan, Maria

    2013-01-01

    The glass ceiling is a transparent barrier that prevents women and minorities from moving up in the management hierarchy. Glass ceiling researchers have attempted to determine whether a glass ceiling exists by examining the actual promotion decision to top management, the percentage of management positions held by women in an organization, salary of male versus female managers, and ratings of potential promotion candidates to top management. The aim of this research is to investigate the vari...

  13. Volatility Spillovers and Causality of Carbon Emissions, Oil and Coal Spot and Futures for the EU and USA

    Directory of Open Access Journals (Sweden)

    Chia-Lin Chang

    2017-10-01

    Full Text Available Recent research shows that the efforts to limit climate change should focus on reducing the emissions of carbon dioxide over other greenhouse gases or air pollutants. Many countries are paying substantial attention to carbon emissions to improve air quality and public health. The largest source of carbon emissions from human activities in some countries in Europe and elsewhere is from burning fossil fuels for electricity, heat, and transportation. The prices of fuel and carbon emissions can influence each other. Owing to the importance of carbon emissions and their connection to fossil fuels, and the possibility of [1] Granger (1980 causality in spot and futures prices, returns, and volatility of carbon emissions, crude oil and coal have recently become very important research topics. For the USA, daily spot and futures prices are available for crude oil and coal, but there are no daily futures prices for carbon emissions. For the European Union (EU, there are no daily spot prices for coal or carbon emissions, but there are daily futures prices for crude oil, coal and carbon emissions. For this reason, daily prices will be used to analyse Granger causality and volatility spillovers in spot and futures prices of carbon emissions, crude oil, and coal. As the estimators are based on quasi-maximum likelihood estimators (QMLE under the incorrect assumption of a normal distribution, we modify the likelihood ratio (LR test to a quasi-likelihood ratio test (QLR to test the multivariate conditional volatility Diagonal BEKK model, which estimates and tests volatility spillovers, and has valid regularity conditions and asymptotic properties, against the alternative Full BEKK model, which also estimates volatility spillovers, but has valid regularity conditions and asymptotic properties only under the null hypothesis of zero off-diagonal elements. Dynamic hedging strategies by using optimal hedge ratios are suggested to analyse market fluctuations in the

  14. Li{sub 3}Gd{sub 3}Te{sub 2}O{sub 12}:Eu{sup 3+}- an intense red phosphor for solid state lighting applications

    Energy Technology Data Exchange (ETDEWEB)

    Tiwari, Hansnath [Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036 (India); Asiri Naidu, S. [Department of Chemistry, Rajiv Gandhi University of Knowledge Technologies, Nuzvid, Andhra Pradesh 521202 (India); Varadaraju, U.V., E-mail: varada@iitm.ac.in [Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036 (India)

    2017-02-15

    Li{sub 3}Gd{sub 3−3x}Eu{sub 3x}Te{sub 2}O{sub 12} (x=0.05−1.0) phases with garnet structure were synthesized by high temperature solid state reaction and the photoluminescence properties were investigated. The appearance of bands due to intra 4 f transitions of Gd{sup 3+} in the excitation spectra recorded by monitoring the 612 nm emission line of the activator indicates Gd{sup 3+}→Eu{sup 3+} energy transfer in this host lattice. Under 395 nm excitation, the electric dipole transition is predominant in the emission spectrum of Eu{sup 3+} and is in agreement with the C{sub 2} point group (noncentrosymmetric) of the EuO{sub 8} polyhedron. The critical concentration of the Eu{sup 3+} activator in this series was found to be 0.6 (x=0.2) above which, concentration quenching occurs. The emission intensity of the phosphor composition, Li{sub 3}Gd{sub 2.4}Eu{sub 0.6}Te{sub 2}O{sub 12} is ~4 times that of the commercial sample of Y{sub 2}O{sub 3}:Eu{sup 3+} phosphor. - Highlights: • New Eu{sup 3+} doped garnet. • Intense electric dipole emission. • Gd{sup 3+}→Eu{sup 3+} energy transfer.

  15. Hydrothermal synthesis of 4ZnO·B2O3·H2O:Ln3 + (Ln = Eu, Tb) phosphors: Morphology-tunable and luminescence properties

    Science.gov (United States)

    Cao, Shiwei; Jiao, Yang; Han, Weifang; Ge, Chunhua; Song, Bo; Wang, Jie; Zhang, Xiangdong

    2018-02-01

    4ZnO·B2O3·H2O:Ln3 + (Ln = Eu, Tb) phosphors with different morphologies have been successfully synthesized via one-step hydrothermal method through regulating the molar amount of Eu3 + and Tb3 +. Comprehensive scanning electron microscopy (SEM), X-ray diffraction (XRD) Fourier transform infrared spectrum (FT-IR) and inductively coupled plasma atomic emission spectrometer (ICP-AES) characterizations all confirm that obtained products are 4ZnO·B2O3·H2O:Ln3 + (Ln = Eu, Tb). The experimental results displayed that the morphology and photoluminescence of compounds is regularly changed with increased the molar amount of rare earth ions. For the Eu3 +-doped, Tb3 +-doped and Eu3 +/Tb3 + co-doped 4ZnO·B2O3·H2O phosphors of morphologies, the rod-like structures gradually changed to flower-like structures, fine wire-like structure and hybrid structure, respectively. To their photoluminescence, the Eu3 + shows a red emission (615 nm); the Tb3 + shows a green emission (545 nm); for the Eu3 +/Tb3 + co-doped 4ZnO·B2O3·H2O phosphors, a combination of blue (5d-4f of Eu2 +), green (5D4-7F5 of Tb3 +) and red (5D0-7F2 of Eu3 +) emissions emerges to achieve white emission. In addition, the energy transfer among Eu3 +, Eu2 + and Tb3 + ions was also discussed.

  16. Life cycle greenhouse gas emissions impacts of the adoption of the EU Directive on biofuels in Spain. Effect of the import of raw materials and land use changes

    International Nuclear Information System (INIS)

    Lechon, Y.; Cabal, H.; Saez, R.

    2011-01-01

    The objective of this paper is to evaluate the greenhouse gas (GHG) emissions impacts of the use of different alternative biofuels in passenger vehicles in Spain in order to meet EU biofuel goals. Different crop production alternatives are analysed, including the possible import of some raw materials. Availability of land for national production of the raw materials is analysed and indirect land use changes and associated GHG emissions are quantified. There are important differences in GHG emissions of biofuels depending on the raw material used and whether this is domestically produced or imported. Ethanol production using imported cereals and FAME production using domestic rapeseed have the highest GHG emissions per kilometre driven. Fatty acid methyl ester (FAME) production from sunflower has shown the lowest emissions. When taking into account the results of GHG emissions savings per hectare, these findings are somehow reversed. Production of ethanol and around 12% of FAME can be done domestically. The rest will need to be imported and will cause indirect land use change (ILUC). Therefore, ethanol production will not displace any land, whereas FAME production will displace some amounts of land. Calculated ILUC factors are 29%-34%. The additional GHG emissions due to these indirect land use changes are significant (67%-344% of life cycle GHG emissions). Standalone, the EU biofuel targets can have important benefits for Spain in terms of global warming emissions avoided. However, when considering the impact of land use change effects, these benefits are significantly reduced and can even be negative. -- Highlights: → Biofuel greenhouse gas emissions in Spain using domestic and imported raw materials. → Availability of land, indirect land use changes (ILUC) and GHG emissions quantified. → Important differences in biofuels GHG emissions depending on the raw material found. → All ethanol and 12% FAME can be produced domestically with ILUC factors of 29

  17. Observation of intermediate bands in Eu3+ doped YPO4 host: Li+ ion effect and blue to pink light emitter

    Directory of Open Access Journals (Sweden)

    Abdul Kareem Parchur

    2012-09-01

    Full Text Available This article explores the tuning of blue to pink colour generation from Li+ ion co-doped YPO4:5Eu nanoparticles prepared by polyol method at ∼100-120 °C with ethylene glycol (EG as a capping agent. Interaction of EG molecules capped on the surface of the nanoparticles and/or created oxygen vacancies induces formation of intermediate/mid gap bands in the host structure, which is supported by UV-Visible absorption data. Strong blue and pink colors can be observed in the cases of as-prepared and 500 °C annealed samples, respectively. Co-doping of Li+ enhances the emission intensities of intermediate band as well as Eu3+. On annealing as-prepared sample to 500 °C, the intermediate band emission intensity decreases, whereas Eu3+ emission intensity increases suggesting increase of extent of energy transfer from the intermediate band to Eu3+ on annealing. Emission intensity ratio of electric to magnetic dipole transitions of Eu3+ can be varied by changing excitation wavelength. The X-ray photoelectron spectroscopy (XPS study of as-prepared samples confirms the presence of oxygen vacancies and Eu3+ but absence of Eu2+. Dispersed particles in ethanol and polymer film show the strong blue color, suggesting that these materials will be useful as probes in life science and also in light emitting device applications.

  18. Smoke flow temperature beneath tunnel ceiling for train fire at subway station: Reduced-scale experiments and correlations

    International Nuclear Information System (INIS)

    Meng, Na; Wang, Qiang; Liu, Zhaoxia; Li, Xiao; Yang, He

    2017-01-01

    Highlights: • Reduced-scale experiments on train fire at subway station. • Smoke flow temperature beneath tunnel ceiling measured and correlated. • Effect of platform-tunnel conjunction door type on smoke temperature is clarified. - Abstract: This paper is to investigate the smoke flow temperature beneath tunnel ceiling for a train on fire stopping besides a subway station. Experiments were carried out in a reduced-scale (1:10) subway station model to study the maximum smoke temperature and the longitudinal temperature distribution beneath the tunnel ceiling by considering platform-tunnel conjunction doors of two types: the full-seal platform screen door (PSD) and the full-height safety door. For the maximum temperature beneath the tunnel ceiling, it is found to be well correlated non-dimensionally with heat release rate by a 3.65 and a 2.92 power law function for the full-seal platform screen door and the full-height safety door, respectively. For the longitudinal temperature distribution along the tunnel ceiling, it can be well correlated by an exponential function for both types of platform-tunnel conjunction doors. Concerning the effect of the door type, the maximum temperature is lower and the longitudinal temperature decays faster for full-height safety door than that for full-seal PSD. This is due to that with the full-height safety door, the effective width of the tunnel ceiling is widened, which results in more heat losses from the smoke flow to the ceiling.

  19. Luminescence and energy transfer properties of Eu3+ and Gd3+ in ZrO2

    International Nuclear Information System (INIS)

    Villabona-Leal, E.G.; Diaz-Torres, L.A.; Desirena, H.; Rodríguez-López, J.L.; Pérez, Elías; Meza, Octavio

    2014-01-01

    Red luminescence emission in ZrO2:Gd 3+ –Eu 3+ nanocrystal under 250 nm radiation excitation is achieved. These materials exhibit a tetragonal phase that is retained by the presence of lanthanide ions. Thus, a study of the optical properties as a function of the dopant concentration was been carried out without the deleterious effects of having segregation of other crystalline phases. We analyze the emission and lifetime curves as a function of dopant concentration through a rate equation simulation, finding an excellent fitting. As results, the nonradiative and radiative relaxation constants, as well as a quantitative estimation of the energy transfer processes among Eu 3+ , Gd 3+ and O 2− ions are reported for the first time. The proposed model can be extended (or applicable) to explain the fluorescence dynamics in other nanomaterials doped with Eu 3+ and Gd 3+ under UV excitation. -- Highlights: • ZrO 2 nanocrystal exhibits a tetragonal phase in the presence of Eu and Gd dopants. • Emission and lifetimes as a function of dopant concentration were analyzed by rate equation model. • Quantitative estimation of the energy transfer processes among Eu 3+ , Gd 3+ and O 2− ions are reported

  20. The study of structural and optical properties of (Eu, La, Sm) codoped ZnO nanoparticles via a chemical route

    Energy Technology Data Exchange (ETDEWEB)

    Lang, Jihui; Zhang, Qi; Han, Qiang; Fang, Yue; Wang, Jiaying; Li, Xiuyan; Liu, Yanqing [Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Siping, 136000 (China); Wang, Dandan [Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China); Yang, Jinghai, E-mail: jhyang1@jlnu.edu.cn [Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Siping, 136000 (China); Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China)

    2017-06-15

    The (Eu, La, Sm) ions were doped into ZnO nanoparticles by a chemical route, and the substitution of (Eu, La, Sm) for Zn{sup 2+} ions was proved by analytic techniques of X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman, transmission electron microscope (TEM), photoluminescence (PL) and UV–vis absorption spectroscopy. The results revealed that the codoping did not change the wurtzite structure of ZnO nanoparticles, but the diameter of the nanoparticles decreased with increasing the rare earth (RE) doping concentrations. The optical bandgaps calculated through UV–visible absorption spectroscopy were found to decrease from 3.26 to 3.14 eV with increasing the RE doping concentrations, which also proved by the slight shift of UV positions in PL spectra. The sharp red emissions located at 578.2, 590.1 and 615.7 nm were originated from the 4f-4f transitions in Eu{sup 3+} ions under excitation of 325 nm. And these red emissions of Eu{sup 3+} ions showed a strong correlation with the energy storage centers of oxygen vacancies in the samples which was introduced by the other RE ions of La{sup 3+} and Sm{sup 3+} codoping. - Highlights: • Doping of (Eu, La, Sm) ions into ZnO nanoparticles is realized by a chemical route. • Eu{sup 3+}-related red emissions from intra-4f follow a similar trend as broad defect emission. • Red emissions of Eu{sup 3+} enhance with RE codoping due to oxygen vacancies as energy storage centers. • The bandgap can be tuned by RE codoping, which shows a prospect for the visible utilization.

  1. Sintering process of Eu doped luminescent glass prepared from porous glass

    International Nuclear Information System (INIS)

    Akai, T; Murakami, M; Yamashita, M; Okajima, T; Umesaki, N

    2011-01-01

    Eu doped high silica glass prepared by sintering porous glass exhibits blue luminescence with high quantum efficiency. In this work, we studied effects of sintering temperature on valance state of europium ion. To investigate a change of valance state of Eu, X-ray absorption near edge structure (XANES) spectroscopy measurements were carried out. Intensity of blue emission at around 430nm drastically increases when the sintering temperature is above 1000 deg. C. From XANES spectra, it is found that almost all the Eu exist as Eu 3+ in a samples sintered below 900 deg. C, while more than 70% of Eu exist as Eu 2+ in the sample sintered at 1050 deg. C and 1100 deg. C. The drastic change of oxidation state of europium ion between 900 and 1050 deg. C is discussed in relation to the structural change probed by infrared (IR) spectroscopy.

  2. Demonstration of an advanced solar garden with a water ceiling. Final technical report, July 1, 1979-June 30, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Maes, R.; Riseng, C.; Thomas, G.; Mandeville, M.

    1980-09-01

    A history of the solar garden with the addition of the transparent water ceiling is presented, and a statement of the overall goals of the program is given. The objectives of the water ceiling grant are detailed. The rationale of the transparent water ceiling is developed and its implementation in the solar garden is described. The experimental procedures for evaluating the water ceiling as an integral part of an ongoing garden agricultural experiment are discussed and the results presented. The water ceiling has proven useful in providing extra thermal capacity to the solar garden. It provides heat at night after the water has been warmed during the day and retards overheating in the daytime by absorbing infrared energy into the water. In growing non-flowering plants, such as lettuce and Chinese cabbage, the water ceiling showed no noticeable degradation in yield or maturation rate. In flowering plants, such as tomatoes, the reduced light levels delayed yields by a couple of weeks but the total yield was only slightly diminished. In geographic areas where there is less cloud cover than in Michigan the water ceiling could be much more effective.

  3. Extended Challenges for the EU's Climate and Energy Policy

    International Nuclear Information System (INIS)

    Haslauer, F.

    2015-01-01

    Market-driven climate and energy policies are far more effective than regulation-driven policies. It is time for the EU to rethink its energy strategy. The world is in the throes of a global energy transition as countries seek to meet rising demand by fundamentally changing their energy sectors. Global energy demand is expected to increase by 1.4 percent through 2030, with demand for electricity (a renewable) rising by more than 2 percent during this time period. The European Union has been front and center in this energy transition, seeking to meet three climate and energy targets by 2020: (1) reduce CO2 emissions, (2) increase renewables, and (3) become more energy efficient. Most countries are on track to meet the first two targets but meeting the third one has proved to be more difficult. This is largely because there is no single European power market. Energy policies and regulations are still driven by individual nations. If this continues, the EU energy transition will be costly - prices will shoot up and global competitiveness will suffer. It's time for the EU to work as one large entity and adopt market-driven policies. The advantages include a smoother energy transition in a growing economy, ability to leverage size for more competitive energy costs, and lower prices for consumers. In an ideal scenario, there is one overriding EU target for reducing CO2 emissions, and then the other two - renewables and energy efficiency - act as levers to meet that target. Essentially, the market decides which solutions are the most efficient. A market-driven energy strategy is funded from a CO2-emissions certificate market - to send the right price signals - or a CO2 tax to allocate costs to CO2 emissions. Rather than concentrating funds on feed in tariffs, funds are geared toward improving energy efficiency, research and development of renewables and running pilot programs. In this way, the EU 'incentivizes' innovation and funding is far less than what

  4. The photoluminescence/excitation (PL/E) spectroscopy of Eu-implanted GaN

    KAUST Repository

    O'Donnell, Kevin Peter

    2011-05-01

    Several distinct luminescent centres form in GaN samples doped with Eu. One centre, Eu2, recently identified as the isolated, substitutional Eu impurity, EuGa, is dominant in ion-implanted samples annealed under very high pressures (1 GPa) of N2. According to structural determinations, such samples exhibit an essentially complete removal of lattice damage caused by the implantation process. A second centre, Eu1, probably comprising EuGa in association with an intrinsic lattice defect, produces a more complex emission spectrum. In addition there are several unidentified features in the 5D0 to 7F2 spectral region near 620 nm. We can readily distinguish Eu1 and Eu2 by their excitation spectra, in particular through their different sensitivities to above-gap and below-gap excitation. The present study extends recent work on photoluminescence/ excitation (PL/E) spectroscopy of Eu1 and Eu2 to arrive at an understanding of these mechanisms in terms of residual optically active defect concentrations. We also report further on the \\'host-independent\\' excitation mechanism that is active in the case of a prominent minority centre. The relevance of this work to the operation of the red GaN:Eu light-emitting diode is discussed. © 2010 Elsevier B.V. All rights reserved.

  5. The photoluminescence/excitation (PL/E) spectroscopy of Eu-implanted GaN

    KAUST Repository

    O'Donnell, Kevin Peter; Roqan, Iman S.; Wang, Ke; Lorenz, Katharina; Alves, Eduardo Jorge; Boćkowski, Michał X.

    2011-01-01

    Several distinct luminescent centres form in GaN samples doped with Eu. One centre, Eu2, recently identified as the isolated, substitutional Eu impurity, EuGa, is dominant in ion-implanted samples annealed under very high pressures (1 GPa) of N2. According to structural determinations, such samples exhibit an essentially complete removal of lattice damage caused by the implantation process. A second centre, Eu1, probably comprising EuGa in association with an intrinsic lattice defect, produces a more complex emission spectrum. In addition there are several unidentified features in the 5D0 to 7F2 spectral region near 620 nm. We can readily distinguish Eu1 and Eu2 by their excitation spectra, in particular through their different sensitivities to above-gap and below-gap excitation. The present study extends recent work on photoluminescence/ excitation (PL/E) spectroscopy of Eu1 and Eu2 to arrive at an understanding of these mechanisms in terms of residual optically active defect concentrations. We also report further on the 'host-independent' excitation mechanism that is active in the case of a prominent minority centre. The relevance of this work to the operation of the red GaN:Eu light-emitting diode is discussed. © 2010 Elsevier B.V. All rights reserved.

  6. Options introduction and volatility in the EU ETS

    International Nuclear Information System (INIS)

    Chevallier, Julien; Le Pen, Yannick; Sevi, Benoit

    2009-01-01

    To improve risk management in the European Union Emissions Trading Scheme (EU ETS), the European Climate Exchange (ECX) has introduced option instruments in October 2006 after regulatory authorization. The central question we address is: can we identify a potential destabilizing effect of the introduction of options on the underlying market (EU ETS futures)? Indeed, the literature on commodities futures suggest that the introduction of derivatives may either decrease (due to more market depth) or increase (due to more speculation) volatility. As the identification of these effects ultimately remains an empirical question, we use daily data from April 2005 to April 2008 to document volatility behavior in the EU ETS. By instrumenting various GARCH models, endogenous break tests, and rolling window estimations, our results overall suggest that the introduction of the option market had no effect on the volatility in the EU ETS. These finding are robust to other likely influences linked to energy and commodity markets. (authors)

  7. Impacts of EU carbon emission trade directive on energy-intensive industries. Indicative micro-economic analyses

    International Nuclear Information System (INIS)

    Lund, Peter

    2007-01-01

    The cost impacts from the European emission trading system (ETS) on energy-intensive manufacturing industries have been investigated. The effects consist of direct costs associated to the CO 2 reduction requirements stated in the EU Directive, and of indirect costs of comparable magnitude that originate from a higher electricity price triggered by the ETS in the power sector. The total cost impacts remain below 2% of the production value for most industries within the ETS in the Kyoto period. In the post-Kyoto phase assuming a 30% CO 2 reduction, the total cost impact may raise up to 8% of production value in the heaviest industry sectors. In steel and cement industries the cost impacts are 3-4 fold compared to the least affected pulp and paper and oil refining. Electricity-intensive industries outside the ETS will also be affected, for example in aluminum and chlorine production the indirect cost impacts from ETS could come up to 10% of production value already in the Kyoto period. As industry sectors are affected differently by the ETS some correcting mechanisms may be worthwhile to consider in securing the operation of the most electricity-intensive sectors, e.g. balancing taxation schemes that may include as income source a levy on the wind-fall profits of the power sector due to ETS. A future improvement in ETS for industries within the scheme could be scaling of the emission reduction requirement so that the relative total emission reduction costs are at about the same level. (author)

  8. Luminescence and thermoluminescence properties of Sr{sub 3}WO{sub 6}:Eu{sup 3+} phosphor

    Energy Technology Data Exchange (ETDEWEB)

    Emen, F.M., E-mail: femen106@gmail.com [Department of Chemistry, Faculty of Arts and Science, Mehmet Akif Ersoy University, TR 15030, Burdur (Turkey); Altinkaya, R. [Department of Chemistry, Faculty of Arts and Science, Mersin University, TR 33343, Mersin (Turkey)

    2013-02-15

    Sr{sub 3-x}WO{sub 6}:xEu{sup 3+} (x varies from 0.01 to 0.06) phosphors have been prepared at high temperature by the solid-state method. The crystal structure of Sr{sub 2.95}WO{sub 6}:0.05Eu{sup 3+} phosphor has been determined as a triclinic P-1 space group with a=8.3608 (19) A, b=8.2903 (24) A, c=8.2145 (23) A, {alpha}=89.79 (3){sup Degree-Sign }, {beta}=89.82 (3){sup Degree-Sign }, and {gamma}=89.753 (22){sup Degree-Sign }. The excitation spectrum of Sr{sub 2.95}WO{sub 6}:0.05Eu{sup 3+} phosphor reveals five excitation bands: one is assigned to the charge-transfer (CTLM) band of Sr{sub 3}WO{sub 6} host at 307 nm, and another is assigned to intra-4f transitions between 393 nm and 600 nm. The emission spectrum of Sr{sub 2.95}WO{sub 6}:0.05Eu{sup 3+} phosphor exhibits a series of emission bands, which are attributed to the {sup 5}D{sub 0}{yields}{sup 7}F{sub j} (j=0-4) transitions of Eu{sup 3+} ions. The luminescence studies revealed that the Eu{sup 3+} ions show high luminescent efficiency in emitting red light at 616 nm. The thermoluminescence glow curve shows one dominant glow peak observed at 56 Degree-Sign C which is related to the defects at shallow trap depth. The trap parameters mainly activation energy (E{sub a}) and the order of the kinetics (b) were evaluated by using Rasheedy's three points method (TPM). - Highlights: Black-Right-Pointing-Pointer The Sr{sub 3}WO{sub 6}:Eu{sup 3+} phosphor was prepared by using conventional ceramic method. Black-Right-Pointing-Pointer The diffraction peaks of phosphor have been indexed to triclinic system. Black-Right-Pointing-Pointer The emission peak at 616 nm belongs to {sup 5}D{sub 0}{yields}{sup 7}F{sub 2} electric dipole transitions of Eu{sup 3+}. Black-Right-Pointing-Pointer The emission band of WO{sub 6} and excitation bands of Eu{sup 3+} are overlapping each other. Black-Right-Pointing-Pointer The energy transfer from WO{sub 6} groups to the Eu{sup 3+} ions occurs under the UV excitation.

  9. Definition of an intramolecular Eu-to-Eu energy transfer within a discrete [Eu2L] complex in solution.

    Science.gov (United States)

    Nonat, Aline; Regueiro-Figueroa, Martín; Esteban-Gómez, David; de Blas, Andrés; Rodríguez-Blas, Teresa; Platas-Iglesias, Carlos; Charbonnière, Loïc J

    2012-06-25

    Ligand L, based on two do3a moieties linked by the methylene groups of 6,6'-dimethyl-2,2'-bipyridine, was synthesized and characterized. The addition of Ln salts to an aqueous solution of L (0.01 M Tris-HCl, pH 7.4) led to the successive formation of [LnL] and [Ln(2)L] complexes, as evidenced by UV/Vis and fluorescence titration experiments. Homodinuclear [Ln(2)L] complexes (Ln = Eu, Gd, Tb, Yb, and Lu) were prepared and characterized. The (1)H and (13)C NMR spectra of the Lu and Yb complexes in D(2)O solution (pD = 7.0) showed C(1) symmetry of these species in solution, pointing to two different chemical environments for the two lanthanide cations. The analysis of the chemical shifts of the Yb complex indicated that the two coordination sites present square antiprismatic (SAP) coordination environments around the metal ions. The spectroscopic properties of the [Tb(2)L] complex upon ligand excitation revealed conventional behavior with τ(H2O) = 2.05(1) ms and ϕ(H2O) = 51%, except for the calculation of the hydration number obtained from the luminescent lifetimes in H(2)O and D(2)O, which pointed to a non-integer value of 0.6 water molecules per Tb(III) ion. In contrast, the Eu complex revealed surprising features such as: 1) the presence of two and up to five components in the (5)D(0)→(7)F(0) and (5)D(0)→(7)F(1) emission bands, respectively; 2) marked differences between the normalized spectra obtained in H(2)O and D(2)O solutions; and 3) unconventional temporal evolution of the luminescence intensity at certain wavelengths, the intensity profile first displaying a rising step before the occurrence of the expected decay. Additional spectroscopic experiments performed on [Gd(2-x)Eu(x)L] complexes (x = 0.1 and 1.9) confirmed the presence of two distinct Eu sites with hydration numbers of 0 (site I) and 2 (site II), and showed that the unconventional temporal evolution of the emission intensity is the result of an unprecedented intramolecular Eu-to-Eu

  10. Costs and Benefits to EU Member States of 2030 Climate and Energy Targets - February 2014

    International Nuclear Information System (INIS)

    2014-01-01

    Costs and Benefits to EU Member States of 2030 Climate and Energy Targets is based on analyses using the POLES-Enerdata model and presents an overview of the main European energy and climate policies: reduction of CO_2 emissions, development of renewable energies, and promotion of energy efficiency. The report looks forward to 2030 and beyond to evaluate possible targets and the goal of maintaining global temperature rise to 2 deg. C. This publication was produced by Enerdata's Global Energy Forecasting team, including the modelling and scenario analysis, within the framework of an external service contract to the UK's Department of Energy and Climate Change. This project looks ahead to 2030. To do this, scenarios were developed using the POLES-Enerdata model, a world energy-economy model that fully describes the energy system and associated GHG emissions. This report analyses the costs and benefits to all EU Member States under different scenarios of the level and type of EU targets defined within a 2030 climate and energy framework. Scenarios include progressively more stringent GHG targets in 2030 (40%, 50%, and 60% reductions compared to 1990), alternative assumptions on access to international credits (0%, 5% and 10% of 1990 emissions), the addition of RES burden shares by Member State, accelerated CCS commercial availability and reduced renewables learning rates. These are the sensitivities commissioned as part of this report; however, they are not a comprehensive range covering all possible outcomes that could arise in reality. What are the costs and benefits to Member States under different scenarios of the level and type of EU targets? The analysis assesses the benefits of different scenarios to improved air quality and health, diversity of energy supply, and reduced costs of meeting longer term emission reduction targets (notably the EU's commitment to reduce emissions by 80-95% by 2050). Relying on more low-carbon, domestic, or diversified sources of

  11. The glass ceiling of corporate social responsibility : Consequences of a business case approach towards CSR

    NARCIS (Netherlands)

    Nijhof, A.H.J.; Jeurissen, R.J.M.

    2010-01-01

    Purpose – This paper aims to clarify that corporate social responsibility (CSR) has come a long way by the prevailing business case approach, but increasingly hits a glass ceiling. The glass ceiling metaphor refers to the inherent limitations created by a business case approach towards CSR.

  12. Individually controlled localized chilled beam in conjunction with chilled ceiling: Part 2 – Human response

    DEFF Research Database (Denmark)

    Arghand, Taha; Pastuszka, Zuzanna; Bolashikov, Zhecho Dimitrov

    2016-01-01

    The response of 24 subjects to the local environment established by localized chilled beam combined with chilled ceiling (LCBCC) was studied and compared with response to the environment generated by mixing ventilation combined with chilled ceiling (CCMV) at two temperature conditions of 26°C and...

  13. Individually controlled localized chilled beam in conjunction with chilled ceiling: Part 1 – Physical environment

    DEFF Research Database (Denmark)

    Arghand, Taha; Bolashikov, Zhecho Dimitrov; Kosonen, Risto

    2016-01-01

    This study investigates the indoor environment generated by localized chilled beam coupled with chilled ceiling (LCBCC) and compares it with the environment generated by mixing ventilation coupled with chilled ceiling (CCMV). The experiments were performed in a mock-up of single office (4.1 m × 4...

  14. Breaking through the glass ceiling: an industrial perspective.

    Science.gov (United States)

    Harlander, S K

    1996-11-01

    Many companies have recognized that the workforce of the future will be significantly more diverse than in the past. A substantial number of these new employees will be women. Industry must create an environment that attracts the best, brightest, and most talented women and provide an environment that empowers them to reach their full potential. Barriers to advancement, such as the real or perceived "glass ceiling," inhibit the individual and ultimately negatively affect the company. Successful companies will recognize that gender diversity is a critical business strategy and implement aggressive programs to assist women in breaking through the glass ceiling. Gender diversity initiatives should include examination of quality of life issues, training and development, organizational policies and practices, and management accountability. Mentoring programs clearly play an important role in gender diversity programs. Personal mentoring experiences in academic and corporate environments, as well as a pilot mentoring program at Land O'Lakes, will be discussed.

  15. Photoluminescence Properties of Red-Emitting Ca3Sr3-x(PO4)4:xEu3+ Phosphors for White Light-Emitting Diodes.

    Science.gov (United States)

    Hakeem, D A; Park, K

    2015-07-01

    The photoluminescent properties of the Eu(3+)-activated Ca3Sr3(PO4)4 phosphors prepared by a solution combustion method were investigated. The excitation spectra of Ca3Sr3-x(PO4)4:xEu3+ (0.05 ≤ x ≤ 0.6) phosphors under 614 nm wavelength showed a broad band centered at 266 nm along with other peaks at 320, 362, 381, 394, 414, 464, and 534 nm. The emission spectra observed in the range of 450 to 750 nm under excitation at 394 nm were ascribed to the 5D0-7F1-4 transitions of Eu3+ ions. The Ca3Sr3-x(PO4)4:xEu3+ phosphors showed the strongest red emission at 614 nm due to the electric dipole 5DO -->7F2 transition of Eu3+. The strongest emission intensity was obtained for the Eu3+ ions of x = 0.5. The prepared Ca3Sr3-x(PO4)4:xEu3+ can be used as an efficient red phosphor for UV-based white LEDs.

  16. Luminescent properties of stabled hexagonal phase Sr1-xBaxAl2O4:Eu2+ (x=0.37-0.70)

    International Nuclear Information System (INIS)

    Wu Qiaoli; Liu Zhen; Jiao Huan

    2009-01-01

    Stabled hexagonal phase Sr 1-x Ba x Al 2 O 4 :Eu 2+ (x=0.37-0.70) was prepared by solid-state method. Result revealed that the structure behavior of the SrAl 2 O 4 :Eu 2+ calcined at 1350 deg. C in a reducing atmosphere for 5 h strongly depended on the Ba 2+ concentration. With increasing Ba 2+ concentration, a characteristic hexagonal phase can be observed. When 37-70% of the strontium is replaced by barium, the structure of the prepared sample is pure hexagonal. Photoluminescence and excitation spectra of the samples with different x and doped with 2% Eu 2+ were investigated. Changes in the emission spectra were observed in the two different phases. The green emission at 505 nm from Eu 2+ was found to be quite strong in the hexagonal phase. The intensity and peak position of the green luminescence from Eu 2+ changed with increasing content of Ba 2+ . The strongest green emission was obtained from Sr 0.61 Ba 0.37 Al 2 O 4 :Eu 2+ . The decay characteristics of Sr 1-x Ba x Al 2 O 4 :Eu 2+ (x=0.37-0.70) showed that the life times also varied with the value of x. Furthermore, the emission colors and decay times varying with x could be ascribed to the variation of crystal lattice.

  17. Potential gains from CO2 trading in the EU

    DEFF Research Database (Denmark)

    Svendsen, Gert Tinggaard; Vesterdal, Morten

    2003-01-01

    A new Green Paper from the European Commission on emissions trading foresees the setting-up of a CO2 trading system within the EU for the energy sector. Because any such international environmental agreement is self-enforcing, the participants must have an economic net gain from joining the propo......A new Green Paper from the European Commission on emissions trading foresees the setting-up of a CO2 trading system within the EU for the energy sector. Because any such international environmental agreement is self-enforcing, the participants must have an economic net gain from joining...... the proposed system. Our contribution is therefore to follow the Green Paper proposal and investigate whether member countries and the largest industrial boilers in the electricity sector actually will get significant net gains from CO2 trade in the European Union rather than undertaking domestic actions...... solely. We show, based on PRIMES model, that a full CO2 emission trading system between Annex B countries suggest overall cost savings in the order of 40 % compared to a situation with no trading at all between Member States. A tradable CO2 permit scheme with comprehensive coverage of emissions within...

  18. Origin and Luminescence of Anomalous Red-Emitting Center in Rhombohedral Ba9Lu2Si6O24:Eu(2+) Blue Phosphor.

    Science.gov (United States)

    Liu, Yongfu; Zhang, Changhua; Cheng, Zhixuan; Zhou, Zhi; Jiang, Jun; Jiang, Haochuan

    2016-09-06

    We obtain a blue phosphor, Ba9Lu2Si6O24:Eu(2+) (BLS:Eu(2+)), which shows a strong emission peak at 460 nm and a weak tail from 460 to 750 nm. A 610 nm red emission is observed for the first time in this kind of rhombohedral structure material, which is much different from the same crystal structure of Ba9Sc2Si6O24:Eu(2+) and Ba9Y2Si6O24:Eu(2+). The luminescence properties and decays from 10 to 550 K are discussed. The new red emission arises from a trapped exciton state of Eu(2+) at the Ba site with a larger coordination number (12-fold). It exhibits abnormal luminescence properties with a broad bandwidth and a large Stokes shift. Under the 400 nm excitation, the external quantum efficiency of BLS:Eu(2+) is 45.4%, which is higher than the 35.7% for the commercial blue phosphor BAM:Eu(2+). If the thermal stability of BLS:Eu(2+) can be improved, it will show promising applications in efficient near-UV-based white LEDs.

  19. Tunable photoluminescence and magnetic properties of Dy(3+) and Eu(3+) doped GdVO4 multifunctional phosphors.

    Science.gov (United States)

    Liu, Yanxia; Liu, Guixia; Dong, Xiangting; Wang, Jinxian; Yu, Wensheng

    2015-10-28

    A series of Dy(3+) or/and Eu(3+) doped GdVO4 phosphors were successfully prepared by a simple hydrothermal method and characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectrometry (EDS), photoluminescence (PL) spectroscopy and vibrating sample magnetometry (VSM). The results indicate that the as-prepared samples are pure tetragonal phase GdVO4, taking on nanoparticles with an average size of 45 nm. Under ultraviolet (UV) light excitation, the individual Dy(3+) or Eu(3+) ion activated GdVO4 phosphors exhibit excellent emission properties in their respective regions. The mechanism of energy transfer from the VO4(3-) group and the charge transfer band (CTB) to Dy(3+) and Eu(3+) ions is proposed. Color-tunable emissions in GdVO4:Dy(3+),Eu(3+) phosphors are realized through adopting different excitation wavelengths or adjusting the appropriate concentration of Dy(3+) and Eu(3+) when excited by a single excitation wavelength. In addition, the as-prepared samples show paramagnetic properties at room temperature. This kind of multifunctional color-tunable phosphor has great potential applications in the fields of photoelectronic devices and biomedical sciences.

  20. CO2 trade and market power in the EU electricity sector

    International Nuclear Information System (INIS)

    Tinggaard Svendsen, G.; Vesterdal, M.

    2002-01-01

    The EU commission is planning to launch an emission trading market for greenhouse gases within near future. This to meet its obligations under the United Nations Framework Convention on Climate Change and the Kyoto Protocol. After a theoretical discussion on market power in such a market, wc turn to the empirical evidence which suggests that a reasonable number of sources of C02 emissions in the power sector exists for bollers larger than 25MW. Overall, together with the contestable single market for electricity, the risk of significant strategies behaviour seems negligible. Thus, the electric utility sector seems a suitable testing ground for an EU-scheme of emissions trading. In the longer run, it will be important to broaden the scope of the trading scheme as the inclusion of other sectors will further limit the risk of market power. (au)

  1. CO2 trade and market power in the EU electricity sector

    Energy Technology Data Exchange (ETDEWEB)

    Tinggaard Svendsen, G; Vesterdal, M

    2002-07-01

    The EU commission is planning to launch an emission trading market for greenhouse gases within near future. This to meet its obligations under the United Nations Framework Convention on Climate Change and the Kyoto Protocol. After a theoretical discussion on market power in such a market, wc turn to the empirical evidence which suggests that a reasonable number of sources of C02 emissions in the power sector exists for bollers larger than 25MW. Overall, together with the contestable single market for electricity, the risk of significant strategis behaviour seems negligible. Thus, the electric utility sector seems a suitable testing ground for an EU-scheme of emissions trading. In the longer run, it will be important to broaden the scope of the trading scheme as the inclusion of other sectors will further limit the risk of market power. (au)

  2. Luminescence properties of rare earth doped metal oxide nanostructures: A case of Eu-ZnO

    Energy Technology Data Exchange (ETDEWEB)

    Sahu, D. [School of Basic Sciences, Centurion University of Technology and Management, Odisha-752050 India (India); Acharya, B. S. [Department of Physics, C.V. Raman College of Engineering, Bhubaneswar, Odisha, India-752054 (India); Panda, N. R., E-mail: nihar@iitbbs.ac.in [School of Basic Sciences, Indian Institute of Technology Bhubaneswar, Odisha-751013 India (India)

    2016-05-06

    The present study reports the growth and luminescence properties of Eu doped ZnO nanostructures. The experiment has been carried out by synthesizing the materials by simple wet-chemical method. X-ray diffraction (XRD) studies show expansion of ZnO lattice with the incorporation of Eu ions which has been confirmed from the appearance of Eu{sub 2}O{sub 3} as a minor phase in the XRD pattern. The estimation of crystallite size from XRD results matches closely with the results obtained from transmission electron microscopy. Further, these results show the formation of nanosized Eu-ZnO particles of average size around 60 nm stacked on each other. FTIR studies show the presence of both Zn-O and Eu-O modes in the spectra supporting the results obtained from XRD. The interesting results obtained from photoluminescence (PL) measurements show the presence of both band edge emission in UV region and the defect emissions in violet, blue and green region. The appearance of {sup 5}D{sub 0}→{sup 7}F{sub J} transitions of Eu{sup 3+} ions in red region clearly suggests the possible occurrence of energy transfer between the energy states of ZnO host and Eu{sup 3+} ions.

  3. Long lasting yellow phosphorescence and photostimulated luminescence in Sr3SiO5 : Eu2+ and Sr3SiO5 : Eu2+, Dy3+ phosphors

    International Nuclear Information System (INIS)

    Sun Xiaoyuan; Zhang Jiahua; Zhang Xia; Luo Yongshi; Wang Xiaojun

    2008-01-01

    We report the observation of long lasting yellow phosphorescence and photostimulated luminescence (PSL) in Sr 3 SiO 5 : Eu 2+ and Sr 3 SiO 5 : Eu 2+ , Dy 3+ phosphors. The decay patterns of phosphorescence and thermoluminescence curves demonstrate that introduction of Dy 3+ into Sr 3 SiO 5 : Eu 2+ can generate a large number of shallow traps and deep traps. The generated deep traps prolong the phosphorescence up to 6 h after UV irradiation. The PSL is studied under 808 nm excitation. Slow rising and falling edges of the emission in Sr 3 SiO 5 : Eu 2+ , Dy 3+ are observed, showing a retrapping process by the generated shallow traps due to co-doping Dy 3+ .

  4. Smashing into the Glass Ceiling for Women Managers.

    Science.gov (United States)

    Veale, Camilla; Gold, Jeff

    1998-01-01

    Interviews with 10 women administrators in a British metropolitan district council revealed the glass ceiling to be a complex phenomenon reaching beyond the employment sphere. Their career progression was hindered by lack of career counseling, family-work conflicts, lack of management development for women, and particularly a managerial culture…

  5. Investigations on optical properties of Eu3+ ion doped magnesium telluroborate glasses for red laser applications

    Science.gov (United States)

    Arunkumar, S.; Annapoorani, K.; Marimuthu, K.

    2018-04-01

    Eu3+ doped Magnesium telluroborate glasses were prepared with the chemical composition (40-x)H3BO3+35 TeO2+15MgCO3+10MgF2+xEu2O3 (where x = 0.1, 0.5, 1.0 and 2.0 in wt%) following the melt quenching technique and labeled as MTB0.1Eu, MTB0.5Eu, MTB1.0Eu and MTB2.0Eu respectively. The absorption spectra exhibit seven peaks in the visible and NIR region. Five emission peaks corresponding to the 5D0→7FJ (J=0, 1, 2, 3, 4) transitions were observed while exciting at 465 nm. The luminescence intensity ratio (R) and Ω2 parameter values were found to be higher for the MTB0.5Eu glass thus indicates the higher asymmetry around the Eu3+ ions site compared to other prepared glasses. The CIE color chromaticity coordinates of the present glasses are found to lie in the prominent red region in the chromaticity diagram. The stimulated emission cross-section value of the MTB0.5Eu glass was found to be higher pertaining to the 5D0 → 7F2 transition compared to the other prepared glasses and reported literature thus suggests its suitability for red laser applications.

  6. Mechano-luminescence studies of nano ZnMgAl10O17:Eu phosphor under UV irradiation

    Science.gov (United States)

    Verma, Akshkumar; Verma, Ashish; Panda, Maheswar

    2018-05-01

    ZnMgAl10O17:Eu nano phosphors were prepared successfully, using the combustion route by employing urea as a fuel. The structural, and Morphological, properties were measured using x-ray diffraction (XRD) Scanning electron microscopy (SEM) transition electron microscopy. The BET surface area of sample were found to be of ˜13.92 m2/g. The ML (Mechano-luminescence) were measured to the home made instrument. The phosphor showed more strong and high ML intensity to the without UV irradiated material. Therefore ZnMgAl10O17:Eu2+ phosphor may use as a damage sensor and dosimetry material. The ML emission spectra of the Zn0.99MgAl10O17:Eu0.01 phosphor showed the characteristic Eu2+ emission peaks ˜453nm (blue) originating from the transitions 4f65d1→4f7, Therefore ZnMgAl10O17:Eu2+ phosphor may use as a blue phosphor material.

  7. Graphite-modified cooling ceiling. A comparative evaluation of the performance; Graphitmodifizierte Kuehldecken. Eine vergleichende Bewertung zur Leistungsfaehigkeit

    Energy Technology Data Exchange (ETDEWEB)

    Hauser, Gerd [Technische Univ. Muenchen (Germany); Fraunhofer-Institut fuer Bauphysik, Stuttgart (Germany); Hausladen, Gerhard [Technische Univ. Muenchen (Germany); Ingenieurbuero Hausladen GmbH, Muenchen (Germany); Jacobsen, Cornelia; Hutter, Christina; Hanusch, Christoph [Ingenieurbuero Hausladen GmbH, Muenchen (Germany); Schlitzberger, Stephan [Ingenieurbuero fuer Bauphysik Prof. Dr. Hauser GmbH, Kassel (Germany)

    2013-03-01

    In most cases, the utilization of graphite-modified building materials enhances their thermal conductivity. Thus, chilled ceiling systems achieve an enhanced thermal absorption in comparison to commercial chilled ceiling systems. For this, a simulation for the estimation of the thermal comfort as well as for the quantification of the impacts on the demand of electricity for the refrigeration is performed. The enhanced cooling capacity of the graphite-modified cooling ceiling 'Ecophit' affects the operation positively.

  8. Allowance Allocation and CO2 intensity of the EU15 and Norwegian refineries

    International Nuclear Information System (INIS)

    Nilsson, Kristina; Zetterberg, Lars; Aahman, Markus

    2005-02-01

    On 1 January 2005, the European Union Emission Trading Scheme (EU ETS) was launched. The launch has been preceded by an allocation process in each of the Member States. The main objective of this study was to analyse the allocation in relation to CO 2 efficiency for the mineral oil refining sector. A CO 2 intensity index for mineral oil refineries has been defined and calculated for the refineries within the EU15 and Norway. The IVL CO 2 intensity index is based both on the Solomon Energy Intensity Index (EII), an assumed fuel mix, and process-specific emissions. Due to uncertainties in input data, the determined values for the individual refineries are quite uncertain. However, the regional values can be used to identify trends. It was concluded that there are substantial differences in the CO 2 intensity between refineries within different regions/countries in the EU and these differences have not been considered in the allocation process. Only a few countries have mentioned energy efficiency or reduction potential due to CO 2 intensity of fuels used. Only one country (Denmark) has explicitly given a benchmark that will be used for allocation to new mineral oil refineries. The allocation has generally been based on historic emissions, which will result in refineries with historically higher emissions being allocated larger amounts than refineries with historically lower emissions. This might be favourable for refineries that recently have performed emission-reducing measures but might be less favourable for refineries that during a long time period have implemented emission-reducing measures

  9. Eu2+-doped OH− free calcium aluminosilicate glass: A phosphor for smart lighting

    International Nuclear Information System (INIS)

    Lima, S.M.; Andrade, L.H.C.; Rocha, A.C.P.; Silva, J.R.; Farias, A.M.; Medina, A.N.; Baesso, M.L.; Nunes, L.A.O.; Guyot, Y.; Boulon, G.

    2013-01-01

    In this paper, a broad emission band from Eu 2+ -doped OH − free calcium aluminosilicate glass is reported. By changing the excitation wavelengths, the results showed it is possible to tune the emission from green to orange, what combined with the scattered light from the same blue LED used for excitation, provided a color rendering index of 71 and a correlated color temperature of 6550 K. Our preliminary tests indicate this material as a promising phosphor towards the development of smart lighting devices. -- Highlights: • We report a broad emission band from Eu 2+ -doped OH − free calcium aluminosilicate glass. • The maximum emission peak can be tune from green to orange region. • The test with a LED provided a color rendering index of 71 and a correlated color temperature of 6550 K

  10. Sources of conflicts in climate policy within the EU. An economic analysis

    Energy Technology Data Exchange (ETDEWEB)

    Aaheim, H. Asbjoern; Bretteville, Camilla

    1999-09-01

    This report is a part of a study of the potential for the EU to take on leadership in the climate negotiations. The aim is to sort out factors that may explain the different economic interests in cutting CO{sub 2}-emissions within the EU. It is based on the idea that interests occur as a result of different perception of the cost of emission cuts among stakeholders. Sector-based comparisons of France, Germany, Italy, the Netherlands, Spain and United Kingdom indicate that the conflicts resulting from an announcement of emission cuts are likely to be moderate in Germany, the Netherlands and UK, while the possibilities for conflicts in France, Italy and Spain are significantly higher. The explanation can to a large extent be found by the possibilities for reducing emissions in the electricity sector. The differences facing the different countries when it comes to emission cuts might explain why the EU has not succeeded in implementing common measures across the member countries. To prepare for a common policy, a co-ordination of the electricity market should be given priority. Meanwhile, the differentiation of targets agreed upon after Kyoto clearly contributes to mitigate conflicts. However, new conflicts may occur as a result. The present analysis points out that Italy has got very strict targets compared with the other countries, while the targets for the Netherlands and Spain are moderate. 21 refs., 15 figs., 8 tabs.

  11. Luminescence thermometry with Eu{sup 3+} doped GdAlO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Lojpur, Vesna, E-mail: vesna.lojpur@yahoo.com; Ćulubrk, Sanja; Medić, Mina; Dramicanin, Miroslav

    2016-02-15

    Eu{sup 3+} doped GdAlO{sub 3} powder synthesized by solid state reaction was investigated for application in luminescence thermometry. Phase composition of material was confirmed by X-ray powder diffraction analysis. The photoluminescence emission spectra were collected under excitation of 399 nm, while elevating the temperature of the sample from the room temperature to 793 K. Emissions from {sup 5}D{sub 1}→{sup 7}F{sub 1} and {sup 5}D{sub 0}→{sup 7}F{sub 2} characteristic transitions of Eu{sup 3+} ions are selected for the temperature-dependence study using the fluorescence intensity ratio method. Emission decay curves measured at the strongest emission peak centered at 614 nm were recorded in a same temperature range. Data analysis showed that thermometry by fluorescence intensity ratio method can be used over the temperature region 293–793 K with the maximal relative sensitivity of 2.96% K{sup −1} (at 293 K). Temporal dependence of emission (lifetime) provides temperature sensing from 620 to 793 K with the maximal relative sensitivity of 2.28% K{sup −1}. - Highlights: • GdAlO{sub 3}: 4 at% of Eu{sup 3+} can be used for luminescence thermometry in the 293–793 K range. • Combined FIR and lifetime thermometry provide >0.5% K{sup −1} relative sensitivity. • Temperature dependence of lifetime is well described energy gap law model.

  12. The Impact of Roof Pitch and Ceiling Insulation on Cooling Load of Naturally-Ventilated Attics

    Directory of Open Access Journals (Sweden)

    Linxia Gu

    2012-07-01

    Full Text Available A 2D unsteady computational fluid dynamics (CFD model is employed to simulate buoyancy-driven turbulent ventilation in attics with different pitch values and ceiling insulation levels under summer conditions. The impacts of roof pitch and ceiling insulation on the cooling load of gable-roof residential buildings are investigated based on the simulation of turbulent air flow and natural convection heat transfer in attic spaces with roof pitches from 3/12 to 18/12 combined with ceiling insulation levels from R-1.2 to R-40. The modeling results show that the air flows in the attics are steady and exhibit a general streamline pattern that is qualitatively insensitive to the investigated variations of roof pitch and ceiling insulation. Furthermore, it is predicted that the ceiling insulation plays a control role on the attic cooling load and that an increase of roof pitch from 3/12 to 8/12 results in a decrease in the cooling load by around 9% in the investigated cases. The results suggest that the increase of roof pitch alone, without changing other design parameters, has limited impact on attics cooling load and airflow pattern. The research results also suggest both the predicted ventilating mass flow rate and attic cooling load can be satisfactorily correlated by simple relationships in terms of appropriately defined Rayleigh and Nusselt numbers.

  13. Fabrication and Luminescent properties of ZnWO{sub 4}:Eu{sup 3+}, Dy{sup 3+} white light-emitting phosphors

    Energy Technology Data Exchange (ETDEWEB)

    Zhai, Yongqing, E-mail: zhaiyongqinghbu@163.com; Wang, Meng; Zhao, Qian; Yu, Jiabao; Li, Xuemin

    2016-04-15

    ZnWO{sub 4}:Eu{sup 3+},Dy{sup 3+} white light-emitting phosphors were prepared by a hydrothermal method followed with calcination process. The as-synthesized phosphors were characterized by X-ray powder diffraction (XRD), Fourier transform infrared (FTIR) spectrum, Raman spectra, scanning electron microscope (SEM), transmission electron microscope (TEM), diffused reflectance spectra, photoluminescence excitation and emission spectra, and photoluminescence decay curves. Furthermore, external quantum efficiency of ZnWO{sub 4}:Eu{sup 3+},Dy{sup 3+} was determined. The results showed that the obtained phosphors have monoclinic wolframite structure. The particles of the phosphors was nearly spherical in shape, and the particle size was about 70–100 nm. Upon excitation at UV light, the white light-emitting can be obtained by combining the blue–green emission of tungstate group and characteristic emission of Eu{sup 3+} and Dy{sup 3+}. Based on the excitation/emission spectra and decay curves, the energy transfer and photoluminescence mechanism for ZnWO{sub 4}:Eu{sup 3+}, Dy{sup 3+} system were discussed.

  14. Luminescence and luminescence quenching of highly efficient Y2Mo4O15:Eu(3+) phosphors and ceramics.

    Science.gov (United States)

    Janulevicius, Matas; Marmokas, Paulius; Misevicius, Martynas; Grigorjevaite, Julija; Mikoliunaite, Lina; Sakirzanovas, Simas; Katelnikovas, Arturas

    2016-05-16

    A good LED phosphor must possess strong enough absorption, high quantum yields, colour purity, and quenching temperatures. Our synthesized Y2Mo4O15:Eu(3+) phosphors possess all of these properties. Excitation of these materials with near-UV or blue radiation yields bright red emission and the colour coordinates are relatively stable upon temperature increase. Furthermore, samples doped with 50% Eu(3+) showed quantum yields up to 85%, what is suitable for commercial application. Temperature dependent emission spectra revealed that heavily Eu(3+) doped phosphors possess stable emission up to 400 K and lose half of the efficiency only at 515 K. In addition, ceramic disks of Y2Mo4O15:75%Eu(3+) phosphor with thickness of 0.71 and 0.98 mm were prepared and it turned out that they efficiently convert radiation of 375 and 400 nm LEDs to the red light, whereas combination with 455 nm LED yields purple colour.

  15. Luminescence and luminescence quenching of highly efficient Y2Mo4O15:Eu3+ phosphors and ceramics

    Science.gov (United States)

    Janulevicius, Matas; Marmokas, Paulius; Misevicius, Martynas; Grigorjevaite, Julija; Mikoliunaite, Lina; Sakirzanovas, Simas; Katelnikovas, Arturas

    2016-01-01

    A good LED phosphor must possess strong enough absorption, high quantum yields, colour purity, and quenching temperatures. Our synthesized Y2Mo4O15:Eu3+ phosphors possess all of these properties. Excitation of these materials with near-UV or blue radiation yields bright red emission and the colour coordinates are relatively stable upon temperature increase. Furthermore, samples doped with 50% Eu3+ showed quantum yields up to 85%, what is suitable for commercial application. Temperature dependent emission spectra revealed that heavily Eu3+ doped phosphors possess stable emission up to 400 K and lose half of the efficiency only at 515 K. In addition, ceramic disks of Y2Mo4O15:75%Eu3+ phosphor with thickness of 0.71 and 0.98 mm were prepared and it turned out that they efficiently convert radiation of 375 and 400 nm LEDs to the red light, whereas combination with 455 nm LED yields purple colour. PMID:27180941

  16. Climate policy and trade policy - The French proposal for a EU-wide border tax adjustment for CO2 emissions

    International Nuclear Information System (INIS)

    Damian, M.; Abbasn, M.

    2007-01-01

    The paper examines the French proposal to establish a EU-wide border tax adjustment for CO 2 emissions. The tax seeks to offset competitive distortions toward European industries which incur the cost of the Kyoto Protocol and to prompt European competitors to join the Kyoto Protocol. So far, the debate has chiefly focused on the compatibility of such a border tax adjustment with the rules of the multilateral trading system of the World Trade Organization. Without auguring how a dispute would eventually be settled within the WTO frame-work, the paper argues that the implementation of a border tax adjustment is not as much an issue of technical feasibility or compatibility with the multilateral trading system, as a matter of collective determination to drastically reduce greenhouse gas emissions. The French proposal is a yardstick for climate policy after the expiration of the Kyoto Protocol in 2012. The paper looks in more details into the core directions of pending negotiations. (authors)

  17. Impact of personalized ventilation combined with chilled ceiling on eye irritation symptoms

    DEFF Research Database (Denmark)

    Lipczynska, Aleksandra; Marcol, Bartosz; Kaczmarczyk, Jan

    2014-01-01

    Personalized ventilation (PV) improves inhaled air quality, because it provides fresh air to each workstation and directly to occupant’s breathing zone. The PV alone can be used for room ventilation when applied in conjunction with ceiling radiant cooling system, which removes sensible heat loads...... from the space. Combining PV with chilled ceiling may be an effective way to provide thermal comfort in rooms at air temperature higher than the recommended in the standards upper limit of 26°C (category II), because the operative temperature will be lower. However, combination of high air temperature...

  18. TIME-RESOLVED SPECTROSCOPY OF THE POLAR EU CANCRI IN THE OPEN CLUSTER MESSIER 67

    International Nuclear Information System (INIS)

    Williams, Kurtis A.; Howell, Steve B.; Liebert, James; Smith, Paul S.; Bellini, Andrea; Rubin, Kate H. R.; Bolte, Michael

    2013-01-01

    We present time-resolved spectroscopic and polarimetric observations of the AM Her system EU Cnc. EU Cnc is located near the core of the old open cluster Messier 67; new proper motion measurements indicate that EU Cnc is indeed a member of the star cluster, and this system therefore is useful to constrain the formation and evolution of magnetic cataclysmic variables. The spectra exhibit two-component emission features with independent radial velocity variations as well as time-variable cyclotron emission indicating a magnetic field strength of 41 MG. The period of the radial velocity and cyclotron hump variations are consistent with the previously known photometric period, and the spectroscopic flux variations are consistent in amplitude with previous photometric amplitude measurements. The secondary star is also detected in the spectrum. We also present polarimetric imaging measurements of EU Cnc that show a clear detection of polarization, and the degree of polarization drops below our detection threshold at phases when the cyclotron emission features are fading or not evident. The combined data are all consistent with the interpretation that EU Cnc is a low-state polar in the cluster Messier 67. The mass function of the system gives an estimate of the accretor mass of M WD ≥ 0.68 M ☉ with M WD ≈ 0.83 M ☉ for an average inclination. We are thus able to place a lower limit on the progenitor mass of the accreting white dwarf of ≥1.43 M ☉ .

  19. Structural and optical characterization of Eu3+ doped beta-Ga2O3 nanoparticles using a liquid-phase precursor method.

    Science.gov (United States)

    Kim, Moung-O; Kang, Bongkyun; Yoon, Daeho

    2013-08-01

    Eu3+ doped beta-Ga2O3 and non-doped beta-Ga2O3 nanoparticles were synthesized at 800 degrees C using a liquid-phase precursor (LPP) method, with different annealing times and Eu3+ ion concentrations. Eu3+ doped beta-Ga2O3 nanoparticles showed broad XRD peaks, revealing a second phase compared with the non-doped beta-Ga2O3 nanoparticles. The cathode luminescence (CL) spectra of beta-Ga2O3 and Eu3+ doped beta-Ga2O3 nanoparticles showed a broad band emission (300-500 nm) of imperfection and two component emissions. The luminescence quenching properties of Eu3+ dopant ion concentration appeared gradually beyond 5 mol% in our investigation.

  20. Nitrate-assisted photocatalytic efficiency of defective Eu-doped Pr(OH)3 nanostructures.

    Science.gov (United States)

    Aškrabić, S; Araújo, V D; Passacantando, M; Bernardi, M I B; Tomić, N; Dojčinović, B; Manojlović, D; Čalija, B; Miletić, M; Dohčević-Mitrović, Z D

    2017-12-06

    Pr(OH) 3 one-dimensional nanostructures are a less studied member of lanthanide hydroxide nanostructures, which recently demonstrated an excellent adsorption capacity for organic pollutant removal from wastewater. In this study, Pr 1-x Eu x (OH) 3 (x = 0, 0.01, 0.03, and 0.05) defective nanostructures were synthesized by a facile and scalable microwave-assisted hydrothermal method using KOH as an alkaline metal precursor. The phase and surface composition, morphology, vibrational, electronic and optical properties of the as-prepared samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma optical emission spectrometry (ICP-OES), transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), Raman, infrared (IR), photoluminescence (PL), and diffuse reflectance spectroscopy (DRS). It was deduced that the incorporation of Eu 3+ ions promoted the formation of oxygen vacancies in the already defective Pr(OH) 3 , subsequently changing the Pr(OH) 3 nanorod morphology. The presence of KNO 3 phase was registered in the Eu-doped samples. The oxygen-deficient Eu-doped Pr(OH) 3 nanostructures displayed an improved photocatalytic activity in the removal of reactive orange (RO16) dye under UV-vis light irradiation. An enhanced photocatalytic activity of the Eu-doped Pr(OH) 3 nanostructures was caused by the synergetic effect of oxygen vacancies and Eu 3+ (NO 3 - ) ions present on the Pr(OH) 3 surface, the charge separation efficiency and the formation of the reactive radicals. In addition, the 3% Eu-doped sample exhibited very good adsorptive properties due to different morphology and higher electrostatic attraction with the anionic dye. Pr 1-x Eu x (OH) 3 nanostructures with the possibility of tuning their adsorption/photocatalytic properties present a great potential for wastewater treatment.