WorldWideScience

Sample records for elemental mass balance

  1. Quantification of colloidal and aqueous element transfer in soils: The dual-phase mass balance model

    Science.gov (United States)

    Bern, Carleton R.; Thompson, Aaron; Chadwick, Oliver A.

    2015-01-01

    Mass balance models have become standard tools for characterizing element gains and losses and volumetric change during weathering and soil development. However, they rely on the assumption of complete immobility for an index element such as Ti or Zr. Here we describe a dual-phase mass balance model that eliminates the need for an assumption of immobility and in the process quantifies the contribution of aqueous versus colloidal element transfer. In the model, the high field strength elements Ti and Zr are assumed to be mobile only as suspended solids (colloids) and can therefore be used to distinguish elemental redistribution via colloids from redistribution via dissolved aqueous solutes. Calculations are based upon element concentrations in soil, parent material, and colloids dispersed from soil in the laboratory. We illustrate the utility of this model using a catena in South Africa. Traditional mass balance models systematically distort elemental gains and losses and changes in soil volume in this catena due to significant redistribution of Zr-bearing colloids. Applying the dual-phase model accounts for this colloidal redistribution and we find that the process accounts for a substantial portion of the major element (e.g., Al, Fe and Si) loss from eluvial soil. In addition, we find that in illuvial soils along this catena, gains of colloidal material significantly offset aqueous elemental loss. In other settings, processes such as accumulation of exogenous dust can mimic the geochemical effects of colloid redistribution and we suggest strategies for distinguishing between the two. The movement of clays and colloidal material is a major process in weathering and pedogenesis; the mass balance model presented here is a tool for quantifying effects of that process over time scales of soil development.

  2. Characterization and mass balance of trace elements in an iron ore sinter plant

    Directory of Open Access Journals (Sweden)

    Lucas Ladeira Lau

    2016-04-01

    Full Text Available Environmental legislation is becoming more restrictive in several industrial sectors, especially in the steel industry, which is well known for its large pollution potential. With the recent growth of interest in effects of trace elements on the environment and health, the inclusion of emission limits on these elements in this legislation has become increasingly popular. This article aims to describe the partitioning of trace elements between the products (sinter and plant emissions in an iron ore sinter plant, aiming to better understand the behavior of these elements in the sintering process to eventually support interventions to modify these partitions. Chemical characterization of several sintering inputs was initially performed, revealing that the steel-making residues contained large concentrations of trace elements, whereas low concentrations were observed in the flux. Based on the trace element concentrations, we analyzed the injection of trace elements in a sintering pilot using a sintering mixture. Mass balance was then used to determine the theoretical partitioning of trace elements in the sinter and emissions; cadmium, nickel, lead, mercury, and copper exhibited greater tendencies to concentrate in atmospheric emissions.

  3. Ocean Basalt Simulator version 1 (OBS1): Trace element mass balance in adiabatic melting of a pyroxenite-bearing peridotite

    Science.gov (United States)

    Kimura, Jun-Ichi; Kawabata, Hiroshi

    2015-01-01

    We present a new numerical trace element mass balance model for adiabatic melting of a pyroxenite-bearing peridotite for estimating mantle potential temperature, depth of melting column, and pyroxenite fraction in the source mantle for a primary ocean basalt/picrite. The Ocean Basalt Simulator version 1 (OBS1) uses a thermodynamic model of adiabatic melting of a pyroxenite-bearing peridotite with experimentally/thermodynamically parameterized liquidus-solidus intervals and source mineralogy. OBS1 can be used to calculate a sequence of adiabatic melting with two melting models, including (1) melting of peridotite and pyroxenite sources with simple mixing of their fractional melts (melt-melt mixing model), and (2) pyroxenite melting, melt metasomatism in the host peridotite, and melting of the metasomatized peridotite (source-metasomatism model). OBS1 can be used to explore (1) the fractions of peridotite and pyroxenite, (2) mantle potential temperature, (3) pressure of termination of melting, (4) degree of melting, and (5) residual mode of the sources. In order to constrain these parameters, the model calculates a mass balance for 26 incompatible trace elements in the sources and in the generated basalt/picrite. OBS1 is coded in an Excel spreadsheet and runs with VBA macros. Using OBS1, we examine the source compositions and conditions of the mid-oceanic ridge basalts, Loihi-Koolau basalts in the Hawaiian hot spot, and Jurassic Shatsky Rise and Mikabu oceanic plateau basalts and picrites. The OBS1 model shows the physical conditions, chemical mass balance, and amount of pyroxenite in the source peridotite, which are keys to global mantle recycling.

  4. Implications of elevated CO2 on pelagic carbon fluxes in an Arctic mesocosm study – an elemental mass balance approach

    Directory of Open Access Journals (Sweden)

    J. Czerny

    2013-05-01

    Full Text Available Recent studies on the impacts of ocean acidification on pelagic communities have identified changes in carbon to nutrient dynamics with related shifts in elemental stoichiometry. In principle, mesocosm experiments provide the opportunity of determining temporal dynamics of all relevant carbon and nutrient pools and, thus, calculating elemental budgets. In practice, attempts to budget mesocosm enclosures are often hampered by uncertainties in some of the measured pools and fluxes, in particular due to uncertainties in constraining air–sea gas exchange, particle sinking, and wall growth. In an Arctic mesocosm study on ocean acidification applying KOSMOS (Kiel Off-Shore Mesocosms for future Ocean Simulation, all relevant element pools and fluxes of carbon, nitrogen and phosphorus were measured, using an improved experimental design intended to narrow down the mentioned uncertainties. Water-column concentrations of particulate and dissolved organic and inorganic matter were determined daily. New approaches for quantitative estimates of material sinking to the bottom of the mesocosms and gas exchange in 48 h temporal resolution as well as estimates of wall growth were developed to close the gaps in element budgets. However, losses elements from the budgets into a sum of insufficiently determined pools were detected, and are principally unavoidable in mesocosm investigation. The comparison of variability patterns of all single measured datasets revealed analytic precision to be the main issue in determination of budgets. Uncertainties in dissolved organic carbon (DOC, nitrogen (DON and particulate organic phosphorus (POP were much higher than the summed error in determination of the same elements in all other pools. With estimates provided for all other major elemental pools, mass balance calculations could be used to infer the temporal development of DOC, DON and POP pools. Future elevated pCO2 was found to enhance net autotrophic community carbon

  5. Titanium Mass-balance Analysis of Paso Robles Soils: Elemental Gains and Losses as Affected by Acid Alteration Fluids

    Science.gov (United States)

    Sutter, Brad; Ming, Douglas W.

    2010-01-01

    The Columbia Hills soils have been exposed to aqueous alteration in alkaline [1] as well as acid conditions [2,3]. The Paso Robles class soils are bright soils that possess the highest S concentration of any soil measured on Mars [2]. Ferric-sulfate detection by Moessbauer analysis indicated that acid solutions were involved in forming these soils [4]. These soils are proposed to have formed by alteration of nearby rock by volcanic hydrothermal or fumarolic activity. The Paso Robles soils consist of the original Paso Robles-disturbed-Pasadena (PR-dist), Paso Robles- PasoLight (PR-PL), Arad-Samra, Arad-Hula, Tyrone- Berker Island1 and Tyrone-MountDarwin [2 ,3. ]Chemical characteristics indicate that the PR-dist and PR-PL soils could be derived from acid weathering of local Wishstone rocks while the Samra and Hula soils are likely derived from local Algonquin-Iroquet rock [3]. The Paso Robles soils were exposed to acidic sulfur bearing fluids; however, little else is known about the chemistry of the alteration fluid and its effects on the alteration of the proposed parent materials. The objectives of this work are to conduct titanium normalized mass-balance analysis to1) assess elemental gains and losses from the parent materials in the formation of the Paso Robles soils and 2) utilize this information to indicate the chemical nature of the alteration fluids.

  6. The extent of seawater circulation in the aquifer and its role in elemental mass balances: A lesson from the Dead Sea

    Science.gov (United States)

    Kiro, Yael; Weinstein, Yishai; Starinsky, Abraham; Yechieli, Yoseph

    2014-05-01

    This paper shows for the first time a field-based estimation of the volume of dispersive density-driven long-term seawater circulation in coastal aquifers, which is crucial to the understanding of water-rock interaction and to the assessment of its potential impact on elemental mass balances in the sea. The Dead Sea is an ideal place for studying this type of circulation due to the absence of tides and the accessibility of the shallow fresh-saline transition zone. The unique antithetical behavior of 226Ra and 228Ra during seawater circulation in the Dead Sea aquifer, where 228Ra is added and 226Ra is removed, provides a robust new method for quantifying aquifer circulation. Here we estimate water circulation through the Dead Sea aquifer to be 400 million m3/yr (˜2.5 million m3/yr per 1 km of shoreline), which is ˜20% of the fresh water inflow prior to the 1960s. This large volume can affect trace element concentrations in the Dead Sea, e.g. it is a sink for 226Ra, Ba and U and a source for 228Ra and Fe. These results suggest that dispersive density-driven seawater circulation in aquifers may play an important role in mass balances in other lacustrine and oceanic settings.

  7. Miniature Piezoelectric Macro-Mass Balance

    Science.gov (United States)

    Sherrit, Stewart; Trebi-Ollennu, Ashitey; Bonitz, Robert G.; Bar-Cohen, Yoseph

    2010-01-01

    Mass balances usually use a strain gauge that requires an impedance measurement and is susceptible to noise and thermal drift. A piezoelectric balance can be used to measure mass directly by monitoring the voltage developed across the piezoelectric balance, which is linear with weight or it can be used in resonance to produce a frequency change proportional to the mass change (see figure). The piezoelectric actuator/balance is swept in frequency through its fundamental resonance. If a small mass is added to the balance, the resonance frequency shifts down in proportion to the mass. By monitoring the frequency shift, the mass can be determined. This design allows for two independent measurements of mass. Additionally, more than one sample can be verified because this invention allows for each sample to be transported away from the measuring device upon completion of the measurement, if required. A piezoelectric actuator, or many piezoelectric actuators, was placed between the collection plate of the sampling system and the support structure. As the sample mass is added to the plate, the piezoelectrics are stressed, causing them to produce a voltage that is proportional to the mass and acceleration. In addition, a change in mass delta m produces a change in the resonance frequency with delta f proportional to delta m. In a microgravity environment, the spacecraft could be accelerated to produce a force on the piezoelectric actuator that would produce a voltage proportional to the mass and acceleration. Alternatively, the acceleration could be used to force the mass on the plate, and the inertial effects of the mass on the plate would produce a shift in the resonance frequency with the change in frequency related to the mass change. Three prototypes of the mass balance mechanism were developed. These macro-mass balances each consist of a solid base and an APA 60 Cedrat flextensional piezoelectric actuator supporting a measuring plate. A similar structure with 3 APA

  8. TSP, PM depositions, and trace elements in the vicinity of a cement plant and their source apportionments using chemical mass balance model in Izmir, Turkey.

    Science.gov (United States)

    Yatkin, Sinan; Bayram, Abdurrahman

    2010-08-01

    Total suspended particles mass concentrations (TSP) and bulk depositions of particulate matter (PM depositions) were measured around a cement plant located in the multi-impacted area to assess the affect of the plant on the ambient air in the vicinity in Izmir, Turkey. TSP samples were collected five times a month whereas PM depositions were sampled monthly at four sites between August 2003 and January 2004. The concentrations of Al, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, V, and Zn in TSP and PM depositions (except Cu) were reported. Chemical mass balance (CMB) receptor model with local source profiles was run in order to calculate the source contributions of the PM sources to the concentrations of TSP, PM depositions, and trace elements. Traffic was found to be the major contributor to TSP whereas PM depositions dominantly result from area sources including several stone quarries, concrete plants, lime kilns, and asphalt plants in the region. CMB model results indicate that the cement plant is a significant contributor to TSP, PM depositions, and trace elements, particularly Cd.

  9. Elemental balance in soy sauce

    Energy Technology Data Exchange (ETDEWEB)

    Haruyama, Yoichi; Saito, Manabu [Kyoto Prefectural Univ., Kyoto (Japan). Lab. of Applied Physics; Yoshida, Koji

    1996-12-31

    We have measured the elemental concentrations of soy sauce and its actual raw materials which are used in a certain soy sauce factory. In the present measurement, we measured de-fatted soybean, wheat and salt as raw materials and soy sauce and soy sauce waste as final products. Five kinds of elements, such as Mn, Fe, Cu, Zn and Br, were detected. We obtained elemental concentrations of them except for Mn in each materials. The measured elemental concentration in soy sauce agreed well each other with the calculated one within the experimental errors using the measured concentration in the raw materials and their weight in actual producing process. Contrary to our expectation, it was found that wheat contributes to soy sauce bromine concentration dominantly in the present case. (author)

  10. 14 CFR 23.659 - Mass balance.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Mass balance. 23.659 Section 23.659... Surfaces § 23.659 Mass balance. The supporting structure and the attachment of concentrated mass balance...; (b) 12 g fore and aft; and (c) 12 g parallel to the hinge line. Control Systems ...

  11. The Distribution of Platinum-Group Elements and Other Chalcophile Elements Among Mineral Phases of the Ni-Cu-PGE Deposit of Creighton Mine, Sudbury, Canada: A Quantitative Mass Balance

    Science.gov (United States)

    Dare, S. A.; Barnes, S.-; Prichard, H. M.; Fisher, P. C.

    2009-05-01

    The distribution of PGE and other chalcophile elements among minerals of the Creighton Ore Body of the Sudbury Ni-Cu-PGE deposit has been investigated in order to: 1) better understand the petrogenesis of the ores and 2) aid efficient extraction of the PGE which are recovered as a by-product of mining these ores. A mass balance has been carried out by determining the concentrations of the elements in the; whole rock, the base metal sulphides (BMS) and the associated accessory minerals, including platinum-group minerals (PGM). Calculations show that the BMS host the majority (70-95%) of Co, Os, Pd, Ru and Se, that BMS host some (˜ 50%) Ag, Bi, Cd, Te and Zn but very little (electrum AuAg) are present but rare and are hosted by both BMS and silicates. The Ni-cobaltite is estimated to have equilibrated at 550-600°C, and thus the irarsite-hollingworthite cores probably formed at > 600°C possibly by exsolution from the BMS during cooling. Michenerite was observed to infill fractures in amphibole indicating that some Pd can remobilise during metamorphism and deformation at lower temperatures (˜ 490°C).

  12. Mass balance gradients and climatic change

    NARCIS (Netherlands)

    Oerlemans, J.; Hoogendoorn, N.C.

    1989-01-01

    It is generally assumed that the mass-balance gradient on glaciers is more or less conserved under climatic change. In studies of the dynamic response of glaciers to climatic change, one of the following assumptions is normally made: (i) the mass-balance perturbation is independent of altitude

  13. Surface melt dominates Alaska glacier mass balance

    Science.gov (United States)

    Larsen Chris F,; Burgess, E; Arendt, A.A.; O'Neel, Shad; Johnson, A.J.; Kienholz, C.

    2015-01-01

    Mountain glaciers comprise a small and widely distributed fraction of the world's terrestrial ice, yet their rapid losses presently drive a large percentage of the cryosphere's contribution to sea level rise. Regional mass balance assessments are challenging over large glacier populations due to remote and rugged geography, variable response of individual glaciers to climate change, and episodic calving losses from tidewater glaciers. In Alaska, we use airborne altimetry from 116 glaciers to estimate a regional mass balance of −75 ± 11 Gt yr−1 (1994–2013). Our glacier sample is spatially well distributed, yet pervasive variability in mass balances obscures geospatial and climatic relationships. However, for the first time, these data allow the partitioning of regional mass balance by glacier type. We find that tidewater glaciers are losing mass at substantially slower rates than other glaciers in Alaska and collectively contribute to only 6% of the regional mass loss.

  14. On the Mass Balance of Asphaltene Precipitation

    DEFF Research Database (Denmark)

    Andersen, Simon Ivar; Lira-Galeana, C.; Stenby, Erling Halfdan

    2001-01-01

    In the evaluation of experimental data as well as in calculation of phase equilibria the necessity of the application of mass balances is obvious. In the case of asphaltenes the colloidal nature of these compounds may highly affect the mass balance. In the present paper several experiments...... are performed in order to check the consistency of mass balances within asphaltene precipitation. Asphaltenes are precipitated in two step processes either by changing temperature or by changes in precipitant with increasing precipitation power. This has been performed for three different oils. The data...... indicates that in temperature experiments as well as in solvent series experiments the precipitation of heavy asphaltenes affects the following precipitation of lighter asphaltenes. In both cases the mass balance using standard separation techniques cannot be closed, as less material is precipitated...

  15. Petrographic features, geochemical trends and mass balance ...

    African Journals Online (AJOL)

    Petrographic features, geochemical trends and mass balance computation, in relation to the evolution of anatectic migmatites in the granulite facies terrain of the Manalur area, Tamil Nadu, south India.

  16. Greenland ice sheet mass balance: a review

    DEFF Research Database (Denmark)

    Khan, Shfaqat Abbas; Aschwanden, Andy; Bjørk, Anders A.

    2015-01-01

    and to ice discharge, which are forced by internal or external (atmospheric/oceanic/basal) fluctuations. Regardless of the measurement method, observations over the last two decades show an increase in ice loss rate, associated with speeding up of glaciers and enhanced melting. However, both ice discharge......Over the past quarter of a century the Arctic has warmed more than any other region on Earth, causing a profound impact on the Greenland ice sheet (GrIS) and its contribution to the rise in global sea level. The loss of ice can be partitioned into processes related to surface mass balance...... and melt-induced mass losses exhibit rapid short-term fluctuations that, when extrapolated into the future, could yield erroneous long-term trends. In this paper we review the GrIS mass loss over more than a century by combining satellite altimetry, airborne altimetry, interferometry, aerial photographs...

  17. Composting: Mass Balances and Product Quality

    DEFF Research Database (Denmark)

    Boldrin, Alessio; Christensen, Thomas Højlund; Körner, I.

    2011-01-01

    While the basic processes involved in composting of waste are described in Chapter 9.1 and the main composting technologies are presented in Chapter 9.2, this chapter focuses on mass balances, environmental emissions, unit process inventories and the quality of the compost produced. Understanding...... these issues and being able to account for them is a prerequisite in compost engineering and for establishing and running a successful composting facility. Of specific importance is the final use of the compost product. Use in agriculture is described in Chapter 9.10 and the use of compost in soil amendment...

  18. Balancing The Books - A Statistical Theory of Mass Balances

    Science.gov (United States)

    O'Kane, J. P.

    Mass budgets, without a theory, are an empirical "method of choice" in the environ- mental sciences. There is however a difficulty. Budgets are usually presented as perfect balances with no closing error, justified by the law of mass conservation. Neverthe- less, there is always a closing error! Declaring the error, e, simply raises the question of the acceptability of the budget. To answer this we need a reference quantity against which to compare e. This quantity can only be provided by theory and must also be a mathematical function of all the budget data. Two statistical techniques provide the theory and the function: (1) Probability sampling for estimating the terms of the bud- get, the closing error and their sampling precision, and (2) Hypothesis testing that any particular value of e is due to chance alone. Both techniques must satisfy R.A. Fisher's "vital requirement that the actual and physical conduct of experiments should govern the statistical procedure of their interpretation". Probability sampling is any sampling procedure governed by sets of random numbers. Applying the calculus of probability to the chosen procedure, delivers the theoretical probability distribution of the terms of the budget, and the closing error e', on the assumption that there are no systematic errors of measurement or missing fluxes. In the simplest case, we may use simple or stratified random sampling, defined on a spatio- temporal sampling frame, which covers the duration of the budget on the space-filling object. When the number of independent measurements (samples) is statistically large, the central limit theorem implies that e' is normally distributed. The assumption that there are no systematic errors of measurement, sampling bias, or missing fluxes, and the law of mass conservation, together imply that E(e') = 0. Unbiased, independent sampling of the terms of the budget makes the variance Var(e') equal to the sum of the sampling variances of the individual terms in the

  19. Anaerobic Digestion: Mass Balances and Products

    DEFF Research Database (Denmark)

    Møller, Jacob; Christensen, Thomas Højlund; Jansen, Jes la Cour

    2011-01-01

    While the basic processes involved in anaerobic digestion of waste are described in Chapter 9.4 and the main digestion technologies are presented in Chapter 9.5, this chapter focuses on mass balances, gas production and energy aspects, environmental emissions and unit process inventories....... Understanding these issues and being able to account for them is a prerequisite in digestion engineering and for establishing and running a successful anaerobic digestion facility. Of specific importance is the final use of the digestate. Use in agriculture as a fertilizer is described in Chapter 9.10 and use...... after composting of the digestate as a soil amendment product is analogous to issues presented in Chapter 9.9 for compost....

  20. Glacier Mass Balance measurements in Bhutan

    Science.gov (United States)

    Jackson, Miriam; Tenzin, Sangay; Tashi, Tshering

    2014-05-01

    Long-term glacier measurements are scarce in the Himalayas, partly due to lack of resources as well as inaccessibility of most of the glaciers. There are over 600 glaciers in Bhutan in the Eastern Himalayas, but no long-term measurements. However, such studies are an important component of hydrological modelling, and especially relevant to the proposed expansion of hydropower resources in this area. Glaciological studies are also critical to understanding the risk of jøkulhlaups or GLOFS (glacier lake outburst floods) from glaciers in this region. Glacier mass balance measurements have been initiated on a glacier in the Chamkhar Chu region in central Bhutan by the Department of Hydro-Met Services in co-operation with the Norwegian Water Resources and Energy Directorate. Chamkhar Chu is the site of two proposed hydropower plants that will each generate over 700 MW, although the present and future hydrological regimes in this basin, and especially the contribution from glaciers, are not well-understood at present. There are about 94 glaciers in the Chamkhar Chhu basin and total glacier area is about 75 sq. km. The glaciers are relatively accessible for the Himalayas, most of them can be reached after only 4-5 days walk from the nearest road. One of the largest, Thana glacier, has been chosen as a mass balance glacier and measurements were initiated in 2013. The glacier area is almost 5 sq. km. and the elevation range is 500 m (5071 m a.s.l. to 5725 m a.s.l.) making it suitable as a benchmark glacier. Preliminary measurements on a smaller, nearby glacier that was visited in 2012 and 2013 showed 1 m of firn loss (about 0.6 m w.eq.) over 12 months.

  1. Quantifying mass balance processes on the Southern Patagonia Icefield

    DEFF Research Database (Denmark)

    Schaefer, M.; Machguth, Horst; Falvey, M.

    2015-01-01

    measured accumulation of snow of up to 15.4m w.e. yr(-1) (meters water equivalent per year) as well as the high measured ablation of up to 11m w.e. yr(-1) is reproduced by the model. The overall modeled surface mass balance was positive and increasing during 1975-2011. Subtracting the surface mass balance......We present surface mass balance simulations of the Southern Patagonia Icefield (SPI) driven by downscaled reanalysis data. The simulations were evaluated and interpreted using geodetic mass balances, measured point balances and a complete velocity field of the icefield for spring 2004. The high...... from geodetic balances, calving fluxes were inferred. Mass losses of the SPI due to calving were strongly increasing from 1975-2000 to 2000-2011 and higher than losses due to surface melt. Calving fluxes were inferred for the individual glacier catchments and compared to fluxes estimated from velocity...

  2. Variability of surface mass balance in the Mizuho Plateau, Antarctica

    OpenAIRE

    Kazuhide, SATOW

    1985-01-01

    On the basis of the data of surface mass balance along the traverse routes in 1968-1983,mean and variation of the annual balance were obtained in the Mizuho Plateau, Antarctica. A year-to-year variation of the surface mass balance showed a general increase during the period of the measurement. The climatic effect and the effect of surface microrelief, such as sastrugi and dunes, on the mass balance variability were assessed. The former prevailed in a high accumulation zone of the coastal regi...

  3. Reconstruction of specific mass balance for glaciers in Western ...

    Indian Academy of Sciences (India)

    Vinay Kumar Gaddam

    2017-06-12

    Jun 12, 2017 ... temperatures and precipitation estimates of ERA 20CM ensemble climate reanalysis datasets to reconstruct the specific mass balance for a period of 110 years, between 1900 and 2010. Mass balance estimates suggest that the Shaune Garang, Gor-Garang and Gara glaciers have experienced both ...

  4. Mass balance and exergy analysis of a fast pyrolysis system

    Science.gov (United States)

    Mass balance closure and exergetic efficiency is evaluated for a bench scale fast pyrolysis system. The USDA Agricultural Research Service (ARS) has developed this system for processing energy crops and agricultural residues for bio-oil (pyrolysis oil or pyrolysis liquids) production. Mass balance c...

  5. MASS CONCENTRATIONS AND ELEMENTAL COMPOSITION OF ...

    African Journals Online (AJOL)

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    main source of atmospheric PM is road traffic [14-16], with diesel vehicles in particular being associated with higher ... or mass concentration, chemical composition (elemental, organic and ionic), speciation, size distribution .... Kaliti substation site (KSUB) is one of Ethiopian Electric Power Corporation (EEPCO) substation ...

  6. Sea Ice Mass Balance in the Antarctic (SIMBA), Version 1

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set provides different measurements of Antarctic sea ice data collected as part of the Sea Ice Mass Balance in the Antarctic (SIMBA) program. The...

  7. BTD building uranium mass balance study

    Energy Technology Data Exchange (ETDEWEB)

    Sutter, S.L.; Johnston, J.W.; Glissmeyer, J.A.; Athey, G.F.

    1985-01-01

    Fifteen test firings of depleted uranium (DU) munitions were made during the qualification study of the new target building at the BTD Range operated by the US Army Combat Systems Test Activity (CSTA) at Aberdeen Proving Ground, Maryland. Following these test firings, the total mass and mass distribution of DU inside the BTD facility was determined to define decontamination requirements for the new target building. 4 references, 17 figures, 17 tables.

  8. Teaching Mass and Energy Balances by Experiment

    Science.gov (United States)

    Orbey, Nese; De Jesús Vega, Marisel; Zalluhoglu, Fulya Sudur

    2017-01-01

    A general tank-draining problem was used as an experimental project in two undergraduate-level chemical engineering courses. The project aimed to illustrate the critical nature of experimentation in addition to use of mass and energy conservation principles in developing mathematical models that correctly describes a system. The students designed…

  9. Energy balance and mass conservation in reduced order models of fluid flows

    Science.gov (United States)

    Mohebujjaman, Muhammad; Rebholz, Leo G.; Xie, Xuping; Iliescu, Traian

    2017-10-01

    In this paper, we investigate theoretically and computationally the conservation properties of reduced order models (ROMs) for fluid flows. Specifically, we investigate whether the ROMs satisfy the same (or similar) energy balance and mass conservation as those satisfied by the Navier-Stokes equations. All of our theoretical findings are illustrated and tested in numerical simulations of a 2D flow past a circular cylinder at a Reynolds number Re = 100. First, we investigate the ROM energy balance. We show that using the snapshot average for the centering trajectory (which is a popular treatment of nonhomogeneous boundary conditions in ROMs) yields an incorrect energy balance. Then, we propose a new approach, in which we replace the snapshot average with the Stokes extension. Theoretically, the Stokes extension produces an accurate energy balance. Numerically, the Stokes extension yields more accurate results than the standard snapshot average, especially for longer time intervals. Our second contribution centers around ROM mass conservation. We consider ROMs created using two types of finite elements: the standard Taylor-Hood (TH) element, which satisfies the mass conservation weakly, and the Scott-Vogelius (SV) element, which satisfies the mass conservation pointwise. Theoretically, the error estimates for the SV-ROM are sharper than those for the TH-ROM. Numerically, the SV-ROM yields significantly more accurate results, especially for coarser meshes and longer time intervals.

  10. Seasonal Mass Balance and Balance Gradients from Airborne Laser Altimetry, Columbia River Basin, Canada.

    Science.gov (United States)

    Pelto, B. M.; Menounos, B.

    2016-12-01

    Reliable estimates of glacier mass balance allow insight into the meteorological drivers of glacier change, but financial and logistical limitations restrict field-based measurements to only a small number of the world's glaciers. In southwestern Canada, frequent cloud cover and small glacier size also preclude the measurement of seasonal mass change from space. Here, we describe our ongoing research program employing airborne laser altimetry to estimate surface mass balance for six alpine glaciers in the Columbia Basin. Our surveyed glaciers define a north-south transect through the basin and collectively represent 188 km2 of glaciated terrain (about 10% of the basin's glacierized area). Our LiDAR surveys acquire altimetry with a typical sampling density of 2-3 returns per m2 and with a vertical accuracy of 0.15-0.20 m. Since 2014, we have aligned these airborne surveys to coincide with our field-based, mass balance program that collects measurements at the end of the accumulation and ablation seasons. Geodetic and field-based estimates of seasonal to annual mass balance show remarkable agreement, to within 0.1-0.2 m water equivalent (< 10%). The agreement is greatest for glaciers where we have the densest field-based measurements, implying that our traditional mass balance program could be error prone since it may not capture the spatial variability of surface accumulation and melt at a suitably high sampling density. Our repeated LiDAR surveys, in conjunction with measurements of surface ice velocity and thickness, have also allowed us develop a method to estimate surface mass balance gradients. This method can improve regional estimates of mass change and, ultimately, lead to superior forecasts of glacier loss for the twenty-first century.

  11. 50 years of mass balance observations at Vernagtferner, Eastern Alps

    Science.gov (United States)

    Braun, Ludwig; Mayer, Christoph

    2016-04-01

    The determination and monitoring of the seasonal and annual glacier mass balances of Vernagtferner, Austria, started in 1964 by the Commission of Glaciology, Bavarian Academy of Sciences. Detailed and continuous climate- and runoff measurements complement this mass balance series since 1974. Vernagtferner attracted the attention of scientists since the beginning of the 17th century due to its rapid advances and the resulting glacier lake outburst floods in the Ötztal valley. This is one reason for the first photogrammetric survey in 1889, which was followed by frequent topographic surveys, adding up to more than ten digital elevation models of the glacier until today. By including the known maximum glacier extent at the end of the Little Ice Age in 1845, the geodetic glacier volume balances cover a time span of almost 170 years. The 50 years of glacier mass balance and 40 years of water balance in the drainage basin are therefore embedded in a considerably longer period of glacier evolution, allowing an interpretation within an extended frame of climatology and ice dynamics. The direct mass balance observations cover not only the period of alpine-wide strong glacier mass loss since the beginning of the 1990s. The data also contain the last period of glacier advances between 1970 and 1990. The combination of the observed surface mass exchange and the determined periodic volumetric changes allows a detailed analysis of the dynamic reaction of the glacier over the period of half a century. The accompanying meteorological observations are the basis for relating these reactions to the climatic changes during this period. Vernagtferner is therefore one of the few glaciers in the world, where a very detailed glacier-climate reaction was observed for many decades and can be realistically reconstructed back to the end of the Little Ice Age.

  12. Satellite-retrieval and modeling of glacier mass balance

    NARCIS (Netherlands)

    Ruyter de Wildt, Martijn Sybren de

    2002-01-01

    In this research project we use satellite measurements to infer the mean specific mass balance (Bm) of glaciers. Vatnajökull, the largest ice cap in Europe, is being used as a test-case because this ice cap has often been studied. Only one aspect of Vatnajökull has not been investigated so far, and

  13. 1st order mass balance model - Excel and GAMS

    OpenAIRE

    ALS-NSCORT,

    2004-01-01

    Provider Notes:This zipfile contains the Excel files and GAMS code for a solvable version of the NSCORT mass balance.unzip this in an ECN working directory 1. in model_june04.xls, read the intro sheet and update the working directory cell. 2. run the macro create

  14. Nitrogen mass balance in waste stabilization ponds at the University ...

    African Journals Online (AJOL)

    Nitrogen mass balance in waste stabilization pond system at the University of Dar es Salaam was determined using a dynamic mathematical model in order to elucidate the biological nitrogen transformation mechanisms that are effective for removal of nitrogen in this pond system. Results show that the pond system ...

  15. The Balance of Dark and Luminous Mass in Rotating Galaxies

    OpenAIRE

    McGaugh, Stacy

    2005-01-01

    A fine balance between dark and baryonic mass is observed in spiral galaxies. As the contribution of the baryons to the total rotation velocity increases, the contribution of the dark matter decreases by a compensating amount. This poses a fine-tuning problem for \\LCDM galaxy formation models, and may point to new physics for dark matter particles or even a modification of gravity.

  16. A reconciled estimate of ice-sheet mass balance

    DEFF Research Database (Denmark)

    Shepherd, Andrew; Ivins, Erik R; A, Geruo

    2012-01-01

    We combined an ensemble of satellite altimetry, interferometry, and gravimetry data sets using common geographical regions, time intervals, and models of surface mass balance and glacial isostatic adjustment to estimate the mass balance of Earth's polar ice sheets. We find that there is good...... agreement between different satellite methods--especially in Greenland and West Antarctica--and that combining satellite data sets leads to greater certainty. Between 1992 and 2011, the ice sheets of Greenland, East Antarctica, West Antarctica, and the Antarctic Peninsula changed in mass by -142 ± 49, +14...... ± 43, -65 ± 26, and -20 ± 14 gigatonnes year(-1), respectively. Since 1992, the polar ice sheets have contributed, on average, 0.59 ± 0.20 millimeter year(-1) to the rate of global sea-level rise....

  17. High convergence order finite elements with lumped mass matrix

    DEFF Research Database (Denmark)

    Jensen, Morten skårup

    1996-01-01

    A method for deriving hexahedral finite elements with lumped mass matrices for three-dimensional problems is presented. These elements meet the theoretical conditions for high order convergence, and two numerical examples based on the three-dimensional scalar wave equation show that this is also...... the case in practice and that their accuracy is comparable to elements with consistent mass matrices....

  18. Ice-sheet mass balance in central West Greenland

    Energy Technology Data Exchange (ETDEWEB)

    Greuell, W.; Denby, B. [Institute for Marine and Atmospheric Research IMAR, Utrecht University, Utrecht (Netherlands)

    2001-04-01

    Volume changes of the Greenland ice sheet in response to climate change may form a significant contribution to variations in sea level. However, still the sign of the present volume change is unknown. The aim of this project was to increase our understanding of present state of the Greenland ice sheet and of its sensitivity to climate change, with emphasis on the Kangerlussuaq transect (West Greenland, 67 {sup o}N). We have performed mass-balance, meteorological and ice-velocity measurements along the transect. With a record length of 10 years, the mass-balance measurements constitute the longest series of this kind on the Greenland ice sheet. A crucial parameter for the determination of the amount of melt is the albedo (this is the fraction of the solar radiation reflected by the surface). Therefore, we have improved the retrieval methods used to estimate the surface albedo from satellite data. For that purpose we have, among others, measured the albedo from a helicopter. The resulting data were used for validation of the satellite-derived albedos. With the satellite-derived albedos and the mass-balance data we have developed a method for estimating the surface mass balance of the Greenland ice sheet from satellite data. Furthermore, we have developed an atmospheric boundary-layer model, specifically designed for glaciers and ice sheets. The model was used to study the relation between the climate of the free atmosphere and conditions near the surface of the ice sheet, which determine the amount of melt. refs.

  19. Increased snow contribution to Arctic sea ice mass balance

    Science.gov (United States)

    Granskog, M. A.; Rösel, A.; Provost, C.; Sennechael, N.; Dodd, P. A.; Martma, T.; Leng, M. J.

    2016-12-01

    Traditionally snow on Arctic sea ice has not been considered as a significant component of the mass balance of the (solid) ice cover, due to the low snow to ice thickness ratio. In contrast, snow contributes significantly to the mass balance of Antarctic sea ice due to thinner seasonal ice and thicker snow cover, similar to Arctic marginal seas, such as the Baltic and Okhotsk seas. Recent observations from the N-ICE2015 campaign, conducted in January-June 2015 in the rather thin ice pack north of Svalbard, imply that with a thinning of the Arctic ice pack, snow turned into ice, either as refrozen snow meltwater at the ice surface (superimposed ice) or snow-ice formed due to flooding of the bottom of the snow pack by seawater, can contribute significantly to Arctic sea ice mass balance. We provide evidence from both sea ice cores (from textural and isotope data) and ice mass balance buoys (IMB) with thermistor chains using a heating cycle to detect different media (air/snow/ice/water). Observations indicate that snow-ice or superimposed ice has formed in fall/winter likely when the ice was thin due to summer melt and heavy snow fall early in the freezing season. IMB records from winter/spring showcase the rapid formation of snow-ice due to flooding by seawater after re-adjustment of isostacy in response to: i) deformation events (likely related to changes in floe size) and ii) bottom ice melt over warmer Atlantic waters north of Svalbard. In summary the new data indicate that snow-ice or superimposed can contribute up to about 30% of total sea ice thickness, unprecedented from any earlier records in the high-Arctic.

  20. Compact piezoelectric resonance mass balance for sample verification and mass quantification and mixing

    Science.gov (United States)

    Sherrit, Stewart; Lee, Hyeong Jae; Noell, Aaron C.; Merewether, Gene B.; Yahnker, Christopher R.

    2017-04-01

    There is a need for sample verification and mass quantification of rock, soil and/or ice obtained by sample acquisition mechanisms on extraterrestrial bodies. For many scientific instruments information about the mass of the sample would aid in the interpretation of the data and help prevent the portioning system from overloading instrument ports. Additionally, on a potential sample return mission it is likely that a sample confirmation or mass determination requirement would be implemented before the spacecraft would be commanded to return to Earth or Lunar orbit. In an effort to meet these potential requirements, a piezoelectric resonance balance is being developed to measure a frequency change proportional to the sample mass change. In previous work1 we developed a resonance balance which produced large non-linear frequency changes due to the addition of a large mass. In this study we have looked at a variety of resonator geometries in an effort to linearize the frequency shift with mass. In addition, we have investigated the use of oscillator/counter circuitry to track the frequency shift of the piezoelectric mass balance. In this new design the frequency shifts automatically when a mass is placed on the balance and the counter circuit calculates the frequency shift. This frequency is then converted to a mass using calibration tables determined previously. An additional feature we have implemented is the use of a high frequency thickness mode piezoelectric resonator to mix the sample and a reactant or solvent. This allows for measuring both sample and reagent prior to ingestion by the instrument. This paper will focus on the design requirements and how they are affected by the local gravity and acoustic properties of the sample. Designs which allow for easy loading and unloading of the balance will also be discussed.

  1. Mass and energy balance of the cold Io torus

    Science.gov (United States)

    Moreno, M. A.; Barbosa, D. D.

    1986-01-01

    A new model of the cold Io torus is described. Ions and energy are injected into the system by independent processes so that the mass balance is isolated from the energy balance. The primary source of energy is local ionization and acceleration of hot pickup ions resulting from charge exchange between thermal ions and an extended cloud of Iogenic sulfur and oxygen atoms. The primary energy loss mechanism of the plasma is collisionally excited line emission at optical wavelengths. The primary ion source is radial diffusion inward from the hot torus on a time scale of 140-710 days. The primary ion loss mechanism is a novel two-step enhanced recombination mechanism involving charge exchange between thermal ions and an extended cloud of neutral SO2 molecules, followed by rapid dissociative recombination of the resultant molecular ion. The model provides a self-consistent solution which reconciles a number of diverse observations with known physical processes.

  2. Modelled climate sensitivity of the mass balance of Morteratschgletscher and its dependence on albedo parameterization

    NARCIS (Netherlands)

    Klok, E.J.; Oerlemans, J.

    2004-01-01

    This paper presents a study of the climate sensitivity of the mass balance of Morteratschgletscher in Switzerland, estimated from a two-dimensional mass balance model. Since the albedo scheme chosen is often the largest error source in mass balance models, we investigated the impact of using

  3. Balance and Learning: Crucial Elements in Leadership for Democratic Schools.

    Science.gov (United States)

    Mulford, Bill

    2003-01-01

    Discusses need for school principals to strike a balance between continuity and change, dependence and independence, individualism and community, and homogeneity and heterogeneity. Provides key findings from Australian Leadership and Organizational Learning and Student Outcomes research project. Finds, for example, that transformational leadership…

  4. 14 CFR Section 6 - Objective Classification of Balance Sheet Elements

    Science.gov (United States)

    2010-01-01

    ... losses since acquisition. In the event dividends are declared by such companies, the air carrier shall.... However, for purposes of reporting on BTS Form 41, the balance in this account shall be reported under... include the following: (a) Equipment assigned to aircraft or active line operations as opposed to items...

  5. Mass-balance model for predicting nitrate in ground water

    Science.gov (United States)

    Frimpter, Michael H.; Donohue, John J.; Rapacz, Michael V.

    1990-01-01

    A mass-balance accounting model can be used to guide the management of septic systems and fertilizers to control the degradation of ground-water quality in zones of an aquifer that contribute water to public-supply wells. The nitrate concentration of the mixture in the well can be predicted for steady-state conditions by calculating the concentration that results from the total weight of nitrogen and total volume of water entering the zone of contribution to the well. These calculations will allow water-quality managers to predict the nitrate concentrations that would be produced by different types and levels of development, and to plan development accordingly. Computations for different development schemes provide a technical basis for planners and managers to compare water-quality effects and to select alternatives that limit nitrate concentration in wells.

  6. Maintaining Atmospheric Mass and Water Balance Within Reanalysis

    Science.gov (United States)

    Takacs, Lawrence L.; Suarez, Max; Todling, Ricardo

    2015-01-01

    This report describes the modifications implemented into the Goddard Earth Observing System Version-5 (GEOS-5) Atmospheric Data Assimilation System (ADAS) to maintain global conservation of dry atmospheric mass as well as to preserve the model balance of globally integrated precipitation and surface evaporation during reanalysis. Section 1 begins with a review of these global quantities from four current reanalysis efforts. Section 2 introduces the modifications necessary to preserve these constraints within the atmospheric general circulation model (AGCM), the Gridpoint Statistical Interpolation (GSI) analysis procedure, and the Incremental Analysis Update (IAU) algorithm. Section 3 presents experiments quantifying the impact of the new procedure. Section 4 shows preliminary results from its use within the GMAO MERRA-2 Reanalysis project. Section 5 concludes with a summary.

  7. Nitrogen isotope and mass balance approach in the Elbe Estuary

    Science.gov (United States)

    Sanders, Tina; Wankel, Scott D.; Dähnke, Kirstin

    2017-04-01

    The supply of bioavailable nitrogen is crucial to primary production in the world's oceans. Especially in estuaries, which act as a nutrient filter for coastal waters, microbial nitrogen turnover and removal has a particular significance. Nitrification as well as other nitrogen-based processes changes the natural abundance of the stable isotope, which can be used as proxies for sources and sinks as well as for process identification. The eutrophic Elbe estuary in northern Germany is loaded with fertilizer-derived nitrogen, but management efforts have started to reduce this load effectively. However, an internal nitrate source in turn gained in importance and the estuary changed from a sink to a source of dissolved inorganic nitrogen: Nitrification is responsible for significant estuarine nutrient regeneration, especially in the Hamburg Port. In our study, we aimed to quantify sources and sinks of nitrogen based on a mass and stable isotope budget in the Elbe estuary. A model was developed reproduce internal N-cycling and associated isotope changes. For that approach we measured dissolved inorganic nitrogen (DIN), particulate nitrogen and their stable isotopes in a case study in July 2013. We found an almost closed mass balance of nitrogen, with only low lost or gains which we attribute to sediment resuspension. The isotope values of different DIN components and the model approach both support a high fractionation of up to -25‰ during nitrification. However, the nitrogen balance and nitrogen stable isotopes suggest that most important processes are remineralization of organic matter to ammonium and further on the oxidation to nitrate. Denitrification and nitrate assimilation play a subordinate role in the Elbe Estuary.

  8. Redox balance and blood elemental levels in atherosclerosis

    Energy Technology Data Exchange (ETDEWEB)

    Napoleao, P. [Centro de Biologia Ambiental and Departamento de Biologia Animal, Faculdade de Ciencias de Lisboa, C2, Campo Grande, 1749-016 Lisbon (Portugal) and Laboratorio de Feixes de Ioes, Instituto Tecnologico e Nuclear, E.N. no 10, 2685-953 Sacavem (Portugal)]. E-mail: pnapoleao@itn.pt; Lopes, P.A. [Centro de Biologia Ambiental and Departamento de Biologia Animal, Faculdade de Ciencias de Lisboa, C2, Campo Grande, 1749-016 Lisbon (Portugal); Santos, M. [Centro de Quimica e Bioquimica and Departamento de Quimica e Bioquimica, Faculdade de Ciencias de Lisboa, 1749-016 Lisbon (Portugal); Steghens, J.-P. [Federation de Biochimie, Hopital Edouard Herriot, 3 Place d' Arsonval, 69437 03 Lyon (France); Viegas-Crespo, A.M. [Centro de Biologia Ambiental and Departamento de Biologia Animal, Faculdade de Ciencias de Lisboa, C2, Campo Grande, 1749-016 Lisbon (Portugal); Pinheiro, T. [Laboratorio de Feixes de Ioes, Instituto Tecnologico e Nuclear, E.N. no 10, 2685-953 Sacavem (Portugal); Centro de Fisica Nuclear, Universidade de Lisboa, Av. Prof. Egas Moniz, 1700 Lisbon (Portugal)

    2006-08-15

    Oxidation of lipids and proteins represents a causative event for atherogenesis, which can be opposed by antioxidant activity. Elements, such as, Fe, Cu, Zn and Se can be involved in both mechanisms. Thus, evaluation of blood elemental levels, easily detected by PIXE, and of redox parameters may be useful in assessing the risk of atherosclerosis. A group of stable patients suffering from atherosclerosis, was matched with a cohort of normo-tensive and -lipidemic volunteers. Although no major discrepancies were observed for trace elemental levels in blood, increased concentrations of K and Ca were found in atherosclerotic group. Patients presented enhance levels of antioxidant ({alpha}-tocopherol) and decreased of protein oxidation (protein carbonyls), while for the lipid oxidation marker (malondialdehyde) no variation was observed. This study contributes to a better understanding of atherosclerosis development and its relationship with blood elemental levels, and set basis for further clinical trials with pathological groups in acute phase.

  9. The mass balance of the Greenland ice sheet: sensitivity to climate change as revealed by energy-balance modelling

    NARCIS (Netherlands)

    Oerlemans, J.

    1991-01-01

    The sensitivity of the mass balance of the Greenland ice sheet to climate change is studied with an energy-balance model of the ice/snow surface, applied at 200 m elevation intervals for four characteristic regions of the ice sheet. Solar radiation, longwave radiation, turbulent heat fluxes

  10. On the atomic masses (weights? Of the elements

    Directory of Open Access Journals (Sweden)

    Kaptay G.

    2012-01-01

    Full Text Available Atomic masses (weights? is an essential information for mining and metallurgy. The paper discusses four subjects around this problem. First, the classification of all the elements is suggested into 4 classes, based on their isotope features, determining the accuracy of their known atomic masses. As part of that, the class of elements is discussed with uncertain atomic weights in accordance with the 2009 IUPAC recommendations. A better (easier to use format of atomic weights is presented for this class of elements. Third, it is found not informative to leave empty spaces instead of approximate atomic weights for elements with unstable isotopes. Fourth, the term atomic weight vs the term atomic mass is discussed shortly, in agreement with the SI system of units and in contrary to the questionable IUPAC convection.

  11. Simultaneous mass balance inverse modeling of methane and carbon monoxide

    Science.gov (United States)

    Butler, T. M.; Rayner, P. J.; Simmonds, I.; Lawrence, M. G.

    2005-11-01

    We perform a simultaneous mass-balance inversion of atmospheric methane (CH4) and carbon monoxide (CO) using measurements from the NOAA/CMDL Cooperative Air Sampling Network and a model of tropospheric transport and background chemistry over the period 1990-2000. Our method has a spatial resolution of a semihemisphere and a temporal resolution of 1 month. The deduced CO sources show relatively low interannual variability except around the major biomass burning event in 1997-1998, when we calculate an anomalous emission between July 1997 and December 1998 of 270 Tg(CO). This is enough to suppress the modeled global air mass weighted hydroxyl radical (OH) concentration during this time by 2.2%, and account for 75% of the observed increase in CH4 mixing ratios during 1998. We compare our implied CH4/CO emissions factors with published biomass burning emissions factors, suggesting that the remainder of the increase in CH4 observed in 1998 is due to anomalously high biomass burning emissions, with CH4 emissions from wetlands showing a small negative anomaly in 1998.

  12. Sustainability of algae derived biodiesel: a mass balance approach.

    Science.gov (United States)

    Pfromm, Peter H; Amanor-Boadu, Vincent; Nelson, Richard

    2011-01-01

    A rigorous chemical engineering mass balance/unit operations approach is applied here to bio-diesel from algae mass culture. An equivalent of 50,000,000 gallons per year (0.006002 m3/s) of petroleum-based Number 2 fuel oil (US, diesel for compression-ignition engines, about 0.1% of annual US consumption) from oleaginous algae is the target. Methyl algaeate and ethyl algaeate diesel can according to this analysis conceptually be produced largely in a technologically sustainable way albeit at a lower available diesel yield. About 11 square miles of algae ponds would be needed with optimistic assumptions of 50 g biomass yield per day and m2 pond area. CO2 to foster algae growth should be supplied from a sustainable source such as a biomass-based ethanol production. Reliance on fossil-based CO2 from power plants or fertilizer production renders algae diesel non-sustainable in the long term. Copyright © 2010 Elsevier Ltd. All rights reserved.

  13. Direct mass measurements of the heaviest elements with Penning traps

    Energy Technology Data Exchange (ETDEWEB)

    Block, M., E-mail: m.block@gsi.de [GSI Helmholtzzentrum für Schwerionenforschung, Planckstrasse 1, 64291 Darmstadt (Germany); Helmholtzinstitut Mainz, 55099 Mainz (Germany); Johannes Gutenberg-Universität, Institut für Kernchemie, 55099 Mainz (Germany)

    2015-12-15

    Penning-trap mass spectrometry (PTMS) is a mature technique to provide atomic masses with highest precision. Applied to radionuclides it enables us to investigate their nuclear structure via binding energies and derived quantities such as nucleon separation energies. Recent progress in slowing down radioactive ion beams in buffer gas cells in combination with advanced ion-manipulation techniques has opened the door to access even the elements above fermium by PTMS. Such elements are produced in complete fusion–evaporation reactions of heavy ions with lead, bismuth, and actinide targets at very low rates. Pioneering high-precision mass measurements of nobelium and lawrencium isotopes have been performed with SHIPTRAP at the GSI Darmstadt, Germany. These have illustrated that direct mass measurements provide reliable anchor points to pin down decay chains and that they allow mapping nuclear shell effects, the reason for the very existence of the heaviest elements. Thus, accurate masses contribute to our understanding of these exotic nuclei with extreme proton numbers. In this article experimental challenges in mass measurements of the heaviest elements with Penning traps are discussed. Some illustrative examples of the nuclear structure features displayed based on the presently known masses are given.

  14. On achieving element-wise species balance and enforcing non-negative constraint for advection-diffusion-reaction equations

    Science.gov (United States)

    Mudunuru, M. K.; Nakshatrala, K.

    2012-12-01

    Advection-Diffusion-Reaction (ADR) equations naturally arises in many physical phenomena, which include seepage of contaminants in heterogeneous porous media, transport of injected tracers due to the flow of oil in a petroleum reservoir, and degradation of a deformable solid due to diffusing chemical species. Vast literature exists on how to solve this equation in the cases when the medium is isotropic, velocity field being divergence free, and for advection-dominated problems. However, it is well know that many popular finite element formulations (e.g., the standard Galerkin formulation, stabilized methods, variational multi-scale methods, subgrid-scale methods, and primitive least-squares formulations) do not satisfy element-by-element mass/species balance and do not produce non-negative solutions on general computational grids. Various post-processing based methods were developed in order to recover some properties of computed numerical solutions. Most of these post-processing techniques are ad hoc, and are not variationally consistent. In this poster, we shall present a novel numerical methodology for ADR equations that satisfy discrete maximum principles, the non-negative constraint, and element-by-element mass/species balance. The methodology can handle general computational grids, no additional restrictions on time-step, and for heterogeneous anisotropic media. Several numerical results pertinent to advection-dominated ADR problems will be presented to illustrate the performance of the proposed numerical formulation.

  15. Hybrid inventory, gravimetry and altimetry (HIGA) mass balance product for Greenland and the Canadian Arctic

    DEFF Research Database (Denmark)

    Colgan, W.; Abdalati, W.; Citterio, M.

    2015-01-01

    We present a novel inversion algorithm that generates a mass balance field that is simultaneously consistent with independent observations of glacier inventory derived from optical imagery, cryosphere-attributed mass trends derived from satellite gravimetry, and ice surface elevation trends derived...... from airborne and satellite altimetry. We use this algorithm to assess mass balance across Greenland and the Canadian Arctic over the Sep-2003 to Oct-2009 period at 26 km resolution. We evaluate local algorithm-inferred mass balance against forty in situ point observations. This evaluation yields...... Arctic. These magnitudes of mass loss are dependent on the gravimetry-derived spherical harmonic mass trend we invert. We spatially partition the transient glacier continuity equation by differencing algorithm-inferred mass balance from modeled surface mass balance, in order to solve the horizontal...

  16. Meteoritic trace element toxification and the terminal Mesozoic mass extinction

    Energy Technology Data Exchange (ETDEWEB)

    Dickson, S.M.; Erickson, D.J. III

    1985-01-01

    Calculations of trace element fluxes to the earth associated with 5 and 10 kilometer diameter Cl chondrites and iron meteorites are presented. The data indicate that the masses of certain trace elements contained in the bolide, such as Fe, Co, Ni, Cr, Pb, and Cu, are as large as or larger than the world ocean burden. The authors believe that this pulse of trace elements was of sufficient magnitude to perturb the biogeochemical cycles operative 65 million years ago, a probably time of meteorite impact. Geochemical anomalies in Cretaceous-Tertiary boundary sediments suggest that elevated concentrations of trace elements may have persisted for thousands of years in the ocean. Through direct exposure and bioaccumulation, many trophic levels of the global food chain, including that of the dinosaurs, would have been adversely affected by these meteoritic trace elements. The trace element toxification hypothesis may account for the selective extinction of both marine and terrestrial species in the enigmatic terminal Mesozoic event.

  17. Daily physical activity as determined by age, body mass and energy balance

    OpenAIRE

    Westerterp, Klaas R

    2015-01-01

    Aim Insight into the determinants of physical activity, including age, body mass and energy balance, facilitates the design of intervention studies with body mass and energy balance as determinants of health and optimal performance. Methods An analysis of physical activity energy expenditure in relation to age and body mass and in relation to energy balance, where activity energy expenditure is derived from daily energy expenditure as measured with doubly labelled water and body movement is m...

  18. The effects of void handling on geodetic mass balances

    Science.gov (United States)

    McNabb, Robert; Nuth, Chris; Kääb, Andreas; Girod, Luc

    2017-04-01

    Glacier mass balance is a direct expression of climate change, and has implications for changes in sea level, ocean chemistry, and oceanic and terrestrial ecosystems. Glacier mass balance has traditionally been measured through in-situ measurements of surface elevation change on a glacier surface. To estimate changes on a larger spatial scale, however, in-situ measurement is not feasible, and aerial or satellite measurements of digital elevation models (DEMs) over glaciers have been used recently in order to supplement and extend ground-based measurements. Though the resolution and accuracy of these products generally increases with time, there are still often gaps ("voids") in the data, as well as errors and biases that must be addressed. The occurrence and distribution of these voids is at least partially dependent on the sensor or acquisition method used to generate the source DEMs. For example, for optical stereo DEMs, voids can be especially frequent in the accumulation area of glaciers, impacting elevation measurements and the resulting estimates of glacier volume change to an unknown degree. Several methods for handling voids in elevation datasets have been proposed and implemented in the literature, though direct investigation of the uncertainty associated with these methods is generally not reported. In order to estimate the uncertainties associated with various methods for filling voids in elevation data, we simulate typical voids in high-resolution spatially-complete DEMs of glaciers in south-central Alaska (covering the Alaska Range, Chugach, Kenai, and Wrangel Mountains), USA. This region is home to over 7000 individual glaciers covering over 23000 km2, ranging in elevation from sea level to over 6000 m, and representing many different glacier types including surging glaciers, advancing and retreating tidewater glaciers, and large and small valley glaciers. As such, it presents an ideal test region to investigate the impact of various methods for void

  19. Estimates of Regional Equilibrium Line Altitudes and Net Mass Balance from MODIS Imagery

    Science.gov (United States)

    Shea, J. M.; Menounos, B.; Moore, R. D.

    2011-12-01

    Glacier mass balance is a key variable used to assess the health of glaciers and ice sheets. Estimates of glacier mass balance are required to model the dynamic response of glaciers and ice sheets to climate change, estimate sea-level contribution from surface melt, and document the response of glaciers to climate forcing. Annually resolved estimates of regional mass balance for mountain ranges is often inferred from a sparse network of ground-based measurements of mass balance for individual glaciers. Given that net mass balance is highly correlated with the annual equilibrium line altitude (ELA), we develop an automated approach to estimate the ELA, and by inference net mass balance, on large glaciers and icefields using MODIS 250 m imagery (MOD02QKM). We discriminate areas of bare ice and snow/firn using the product of MODIS' red (0.620 - 0.670 μ m) and near infrared (0.841 - 0.876 μ m) bands. To assess the skill in estimating glacier ELAs, we compare ELAs derived from (1) manual delineation and (2) unsupervised classification of the band product to ground-based observations of ELA and net mass balance at seven long term mass-balance monitoring sites in western North America (Gulkana, Wolverine, Lemon Creek, Taku, Place, Peyto, and South Cascade). Spatial and temporal variations in MODIS-derived ELAs provide an opportunity to validate regional mass-balance models, estimate surface melt contributions to sea-level rise, and examine the cryospheric response to climate change.

  20. Mass and energy balance in the 1973 August 9 flare

    Science.gov (United States)

    Dere, K. P.; Cook, J. W.

    1983-01-01

    The mass and energy balance of the thermal plasma during the decay phase of the solar flare of August 9, 1973, are studied. The analysis is based on observationally determined values for the differential emission measure, density, turbulent and bulk velocities, and physical dimensions. The total particle content and total thermal energy content of the flare plasmas with temperatures above 100,000 K and their variation with time are calculated. The particle loss and the energy losses through radiation, conduction, and convection are evaluated. The decrease in total particle content can be accounted for by the convective losses through the loop footprints at 100,000 K. Radiation is the dominant energy loss mechanism although convective losses at 100,000 K can be important. Conductive losses at 100,000 K into cooler chromospheric material appear to be negligible. The decrease in the total energy content during the decay phase is equal to the sum of the energy losses over the period of observation. No requirement is found for continued heating during the decay phase.

  1. Mass balance modeling of arsenic processes in cropland soils.

    Science.gov (United States)

    Bar-Yosef, B; Chang, A C; Page, A L

    2005-04-01

    This study delineated the mathematical forms for the reactions involved in the mass balance of As in cropland soils. Even mathematically simplified, many model parameters are required to define the reactive processes involved. Example simulations were conducted based on the range of parameter values and initial conditions derived from published literature. The outcomes showed that the As inputs due to fertilizers and irrigation water caused total As content of the root zone to gradually increase over time. The plant uptake and leaching were equally important as pathways for removal of the added As. In turn, the dissolution kinetics of the mineral phase and the distribution coefficient of the adsorbed phase affected the availability of the As for plant uptake and leaching. Parameters based on laboratory-derived data on the dissolution of As mineral phase, mineralization and oxidation of As(III), and the As plant uptake however appeared to overestimate the As transformations in soils. While the development of mathematical model was a straightforward process, its application to realistic situations was hindered by difficulties of defining model parameter values with confidence. Current knowledge on the processes and reactions of As transformation in the soil-plant system is inadequate to calibrate or validate the model. Studies are needed to understand the kinetics of soil As mineral dissolution and precipitation and the dynamics of root growth and As uptake by plant in soils.

  2. Surface mass balance reanalysis of Taku and Lemon Creek glaciers, Alaska: 1946-2015

    Science.gov (United States)

    McNeil, Christopher

    We reanalyzed geodetic and glaciological surface mass balance records of Taku and Lemon Creek glaciers for the period 1946--2015 to determine what has driven the contradictory behavior of these glaciers. During the past century, Taku Glacier has been increasing in area and mass, while Lemon Creek Glacier has simultaneously shrunk in area and mass. Between 1948 and 1999 geodetic mass balance rates are +0.33+/-0.34 m w.e. a--1 for Taku Glacier and 0.61+/-0.34 m w.e. a--1 for Lemon Creek Glacier. Geodetic mass balance rates decreased to +0.01+/-0.23 m w.e. a--1 and --0.65 +/-0.23 m w.e. a--1 for Taku and Lemon Creek glaciers respectively, between 1999 and 2013. We updated the glaciological analysis of annual field data, and found no significant difference between updated and previous annual mass balance solutions (p--value Lemon Creek Glacier record. Comparing mass balance anomalies we determined inter--annual variability of surface mass balance is the same for Taku and Lemon Creek glaciers. However, differences in glacier specific hypsometry and mass balance profile drive systematic differences in both annual and long--term glacier mass balance rates.

  3. Lumped Mass Modeling for Local-Mode-Suppressed Element Connectivity

    DEFF Research Database (Denmark)

    Joung, Young Soo; Yoon, Gil Ho; Kim, Yoon Young

    2005-01-01

    For successful topology design optimization of crashworthy “continuum” structures, unstable element-free and local vibration mode-free transient analyses should be ensured. Among these two issues, element instability was shown to be overcome if a recently-developed formulation, the element...... for the standard element density method. Local modes are artificial, numerical modes resulting from the intrinsic modeling technique of the topology optimization method. Even with existing local mode controlling techniques, the convergence of the topology optimization of vibrating structures, especially...... experiencing large structural changes, appears to be still poor. In ECP, the nodes of the domain-discretizing elements are connected by zero-length one-dimensional elastic links having varying stiffness. For computational efficiency, every elastic link is now assumed to have two lumped masses at its ends...

  4. Clusters of Monoisotopic Elements for Calibration in (TOF) Mass Spectrometry

    Science.gov (United States)

    Kolářová, Lenka; Prokeš, Lubomír; Kučera, Lukáš; Hampl, Aleš; Peňa-Méndez, Eladia; Vaňhara, Petr; Havel, Josef

    2017-03-01

    Precise calibration in TOF MS requires suitable and reliable standards, which are not always available for high masses. We evaluated inorganic clusters of the monoisotopic elements gold and phosphorus (Au n +/Au n - and P n +/P n -) as an alternative to peptides or proteins for the external and internal calibration of mass spectra in various experimental and instrumental scenarios. Monoisotopic gold or phosphorus clusters can be easily generated in situ from suitable precursors by laser desorption/ionization (LDI) or matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS). Their use offers numerous advantages, including simplicity of preparation, biological inertness, and exact mass determination even at lower mass resolution. We used citrate-stabilized gold nanoparticles to generate gold calibration clusters, and red phosphorus powder to generate phosphorus clusters. Both elements can be added to samples to perform internal calibration up to mass-to-charge ( m/z) 10-15,000 without significantly interfering with the analyte. We demonstrated the use of the gold and phosphorous clusters in the MS analysis of complex biological samples, including microbial standards and total extracts of mouse embryonic fibroblasts. We believe that clusters of monoisotopic elements could be used as generally applicable calibrants for complex biological samples.

  5. Clusters of Monoisotopic Elements for Calibration in (TOF) Mass Spectrometry.

    Science.gov (United States)

    Kolářová, Lenka; Prokeš, Lubomír; Kučera, Lukáš; Hampl, Aleš; Peňa-Méndez, Eladia; Vaňhara, Petr; Havel, Josef

    2017-03-01

    Precise calibration in TOF MS requires suitable and reliable standards, which are not always available for high masses. We evaluated inorganic clusters of the monoisotopic elements gold and phosphorus (Au n+/Au n- and P n+/P n-) as an alternative to peptides or proteins for the external and internal calibration of mass spectra in various experimental and instrumental scenarios. Monoisotopic gold or phosphorus clusters can be easily generated in situ from suitable precursors by laser desorption/ionization (LDI) or matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS). Their use offers numerous advantages, including simplicity of preparation, biological inertness, and exact mass determination even at lower mass resolution. We used citrate-stabilized gold nanoparticles to generate gold calibration clusters, and red phosphorus powder to generate phosphorus clusters. Both elements can be added to samples to perform internal calibration up to mass-to-charge (m/z) 10-15,000 without significantly interfering with the analyte. We demonstrated the use of the gold and phosphorous clusters in the MS analysis of complex biological samples, including microbial standards and total extracts of mouse embryonic fibroblasts. We believe that clusters of monoisotopic elements could be used as generally applicable calibrants for complex biological samples. Graphical Abstract ᅟ.

  6. Dynamic mass balance model for mercury in the St. Lawrence River near Cornwall, Ontario, Canada.

    Science.gov (United States)

    Lessard, Charlotte R; Poulain, Alexandre J; Ridal, Jeffrey J; Blais, Jules M

    2014-12-01

    A dynamic mass balance model was developed for the St. Lawrence River near Cornwall, Ontario that predicts and hindcasts mercury concentrations and fluxes in three forms, elemental Hg (Hg(0)), divalent mercury (Hg(2+)), and methyl mercury (MeHg), in a six compartment environment (air, water, porewater, sediment, periphyton, and benthic invertebrates). Our objective was to construct a dynamic mass balance model for mercury in the St. Lawrence River near Cornwall, Ontario based on the framework and results of a steady-state mass balance model developed previously for this site. The second objective was to estimate industrial mercury emissions based on mercury residues deposited in sediments prior to 1970, the year when regulations were implemented to reduce mercury pollution in the environment. We compiled mercury concentrations, fluxes, and transformation rates from previous studies completed in this section of the river (area of approximately 100km(2)) to develop the model. Estimated mercury concentrations in all media were similar to measured data (R(2)=0.99), with only minor exceptions, providing a satisfactory overall description of the mercury loadings and transformation rates of the different mercury species. The estimated historical emissions prior to 1970 from local industries along the Cornwall waterfront were approximately 400kgyear(-1). A storm sewer discharge of 5000m(3)/day resulted in a significant increase in mercury concentrations, particularly in sediment (617ngg(-1) to 624ngg(-1); p=0.004). Model results suggest that discharges of mercury from sources such as local industries and storm sewers have an impact on mercury in media such as sediment and water. This model should provide a basis for predicting and hindcasting mercury concentrations in other river environments as well, because it considers three distinct forms of mercury, and contains environmental media common to all rivers, including some (e.g. periphyton) not typically included in

  7. Climate, not atmospheric deposition, drives the biogeochemical mass-balance of a mountain watershed

    Science.gov (United States)

    Baron, Jill S.; Heath, Jared

    2014-01-01

    Watershed mass-balance methods are valuable tools for demonstrating impacts to water quality from atmospheric deposition and chemical weathering. Owen Bricker, a pioneer of the mass-balance method, began applying mass-balance modeling to small watersheds in the late 1960s and dedicated his career to expanding the literature and knowledge of complex watershed processes. We evaluated long-term trends in surface-water chemistry in the Loch Vale watershed, a 660-ha. alpine/subalpine catchment located in Rocky Mountain National Park, CO, USA. Many changes in surface-water chemistry correlated with multiple drivers, including summer or monthly temperature, snow water equivalent, and the runoff-to-precipitation ratio. Atmospheric deposition was not a significant causal agent for surface-water chemistry trends. We observed statistically significant increases in both concentrations and fluxes of weathering products including cations, SiO2, SO4 2−, and ANC, and in inorganic N, with inorganic N being primarily of atmospheric origin. These changes are evident in the individual months June, July, and August, and also in the combined June, July, and August summer season. Increasingly warm summer temperatures are melting what was once permanent ice and this may release elements entrained in the ice, stimulate chemical weathering with enhanced moisture availability, and stimulate microbial nitrification. Weathering rates may also be enhanced by sustained water availability in high snowpack years. Rapid change in the flux of weathering products and inorganic N is the direct and indirect result of a changing climate from warming temperatures and thawing cryosphere.

  8. Regional evaluation of mass element fluxes: Geomon network of small catchments.

    Science.gov (United States)

    Fottová, D

    1995-01-01

    Monitoring of element flows and their mass balances in the natural unit of the biosphere represented by a small catchment appears to be the most suitable for the solution of complex problems such as the deterioration of environmental quality. Long-term collection of comparable biogeochemical data, which will enable the identification of environmental trends, is the main aim of the GEOMON network. One of the most important applications of these data will be the calculation of critical loads. The Czech Geological Survey possesses data from 44 catchments in the former Czechoslovakia. Qualitative and quantitative data on inputs in atmospheric deposition and outputs via surface runoff are available. Simple input-output mass balances yield estimates of total accumulation or loss of individual components. Some examples of interpretations of the GEOMON data, especially in connection with different bedrock types, will be given.

  9. Mass balance investigation of alpine glaciers through LANDSAT TM data

    Science.gov (United States)

    Bayr, Klaus J.

    1989-01-01

    An analysis of LANDSAT Thematic Mapper (TM) data of the Pasterze Glacier and the Kleines Fleisskees in the Austrian Alps was undertaken and compared with meteorological data of nearby weather stations. Alpine or valley glaciers can be used to study regional and worldwide climate changes. Alpine glaciers respond relatively fast to a warming or cooling trend in temperature through an advance or a retreat of the terminus. In addition, the mass balance of the glacier is being affected. Last year two TM scenes of the Pasterze Glacier of Aug. 1984 and Aug. 1986 were used to study the difference in reflectance. This year, in addition to the scenes from last year, one MSS scene of Aug. 1976 and a TM scene from 1988 were examined for both the Pasterze Glacier and the Kleines Fleisskees. During the overpass of the LANDSAT on 6 Aug. 1988 ground truthing on the Pasterze Glacier was undertaken. The results indicate that there was considerable more reflectance in 1976 and 1984 than in 1986 and 1988. The climatological data of the weather stations Sonnblick and Rudolfshuette were examined and compared with the results found through the LANDSAT data. There were relations between the meteorological and LANDSAT data: the average temperature over the last 100 years showed an increase of .4 C, the snowfall was declining during the same time period but the overall precipitation did not reveal any significant change over the same period. With the use of an interactive image analysis computer, the LANDSAT scenes were studied. The terminus of the Pasterze Glacier retreated 348 m and the terminus of the Kleines Fleisskees 121 m since 1965. This approach using LANDSAT MSS and TM digital data in conjunction with meteorological data can be effectively used to monitor regional and worldwide climate changes.

  10. Mass balance, pharmacokinetics, and metabolism of linsitinib in cancer patients.

    Science.gov (United States)

    Poondru, Srinivasu; Chaves, Jorge; Yuen, Geoffrey; Parker, Barbara; Conklin, Elizabeth; Singh, Margaret; Nagata, Masanori; Gill, Stanley

    2016-04-01

    This study characterized the pharmacokinetics, mass balance, routes and extent of elimination, metabolites, and safety of a single oral dose of (14)C-linsitinib, an IGF-1R/IR inhibitor, in patients with advanced solid tumors. The tolerability of linsitinib after multiple-dose administration was assessed in those patients who wished to continue treatment beyond the single (14)C-linsitinib dose. Five patients received a single oral dose of 150 mg (14)C-linsitinib, followed by collection of blood, plasma, urine, and feces for 10 days. The collected material was analyzed for total radioactivity, linsitinib, and metabolites. The safety of 150 mg of unlabeled linsitinib administered twice daily until disease progression was also assessed. The median time to reach the maximum plasma concentration of linsitinib was 3.0 h, median maximum plasma concentration was 1789 ng/mL, median terminal half-life was 2.4 h, and median apparent oral clearance was 12.45 L/h. After a single dose of (14)C-linsitinib, 5.44 and 76.4 % of mean total radioactivity administered were recovered in urine and feces, respectively. Eighteen linsitinib metabolites (M1-M18) were detected in plasma, urine, and feces samples, and their structures were elucidated. The main metabolic reactions of linsitinib in humans were oxidation and sulfate conjugation. Linsitinib was well tolerated after a single dose of (14)C-linsitinib, and fatigue was the most frequent adverse event following multiple doses of unlabeled linsitinib. (14)C-linsitinib is rapidly absorbed and extensively metabolized. Linsitinib excretion via bile into feces is the predominant elimination route from plasma with minor renal elimination.

  11. Basin Excavation, Lower Crust, Composition, and Bulk Moon Mass balance in Light of a Thin Crust

    Science.gov (United States)

    Jolliff, B. L.; Korotev, R. L.; Ziegler, R. A.

    2013-01-01

    New lunar gravity results from GRAIL have been interpreted to reflect an overall thin and low-density lunar crust. Accordingly, crustal thickness has been modeled as ranging from 0 to 60 km, with thinnest crust at the locations of Crisium and Moscoviense basins and thickest crust in the central farside highlands. The thin crust has cosmochemical significance, namely in terms of implications for the Moon s bulk composition, especially refractory lithophile elements that are strongly concentrated in the crust. Wieczorek et al. concluded that the bulk Moon need not be enriched compared to Earth in refractory lithophile elements such as Al. Less Al in the crust means less Al has been extracted from the mantle, permitting relatively low bulk lunar mantle Al contents and low pre- and post-crust-extraction values for the mantle (or the upper mantle if only the upper mantle underwent LMO melting). Simple mass-balance calculations using the method of [4] suggests that the same conclusion might hold for Th and the entire suite of refractory lithophile elements that are incompatible in olivine and pyroxene, including the KREEP elements, that are likewise concentrated in the crust.

  12. Mass balance, energy and exergy analysis of bio-oil production by fast pyrolysis

    Science.gov (United States)

    Mass, energy and exergy balances are analyzed for bio-oil production in a bench scale fast pyrolysis system developed by the USDA’s Agricultural Research Service (ARS) for the processing of commodity crops to fuel intermediates. Because mass balance closure is difficult to achieve due, in part, to ...

  13. Spatial patterns of North Atlantic Oscillation influence on mass balance variability of European glaciers

    Directory of Open Access Journals (Sweden)

    B. Marzeion

    2012-06-01

    Full Text Available We present and validate a set of minimal models of glacier mass balance variability. The most skillful model is then applied to reconstruct 7735 individual time series of mass balance variability for all glaciers in the European Alps and Scandinavia. Subsequently, we investigate the influence of atmospheric variability associated with the North Atlantic Oscillation (NAO on the glaciers' mass balances.

    We find a spatial coherence in the glaciers' sensitivity to NAO forcing which is caused by regionally similar mechanisms relating the NAO forcing to the mass balance: in southwestern Scandinavia, winter precipitation causes a correlation of mass balances with the NAO. In northern Scandinavia, temperature anomalies outside the core winter season cause an anti-correlation between NAO and mass balances. In the western Alps, both temperature and winter precipitation anomalies lead to a weak anti-correlation of mass balances with the NAO, while in the eastern Alps, the influences of winter precipitation and temperature anomalies tend to cancel each other, and only on the southern side a slight anti-correlation of mass balances with the NAO prevails.

  14. Midlatitude Forcing Mechanisms for Glacier Mass Balance Investigated Using General Circulation Models

    NARCIS (Netherlands)

    Reichert, B.K.; Bengtsson, L.; Oerlemans, J.

    2001-01-01

    A process-oriented modeling approach is applied in order to simulate glacier mass balance for individual glaciers using statistically downscaled general circulation models (GCMs). Glacier-specific seasonal sensitivity characteristics based on a mass balance model of intermediate complexity are used

  15. Midlatitude forcing mechanisms for glacier mass balance investigated using general circulation models

    Energy Technology Data Exchange (ETDEWEB)

    Reichert, B.K.; Bengtsson, L. [Max-Planck-Institut fuer Meteorologie, Hamburg (Germany); Oerlemans, J. [Rijksuniversiteit Utrecht (Netherlands). Inst. for Marine and Atmospheric Research

    2000-09-01

    A process-oriented modeling approach is applied in order to simulate glacier mass balance for individual glaciers using statistically downscaled general circulation models (GCMs). Glacier specific Seasonal Sensitivity Characteristics based on a mass balance model of intermediate complexity are used to simulate mass balances of Nigardsbreen (Norway) and Rhonegletscher (Switzerland). Simulations using reanalyses (ECMWF) for the period 1979-1993 are in good agreement with in situ mass balance measurements for Nigardsbreen. The method is applied to multi-century integrations of coupled (ECHAM4/OPYC) and mixed-layer (ECHAM4/MLO) GCMs excluding external forcing. A high correlation between decadal variations in the north atlantic oscillation (NAO) and mass balance of the glaciers is found. The dominant factor for this relationship is the strong impact of winter precipitation associated with the NAO. A high NAO phase means enhanced (reduced) winter precipitation for Nigardsbreen (Rhonegletscher), typically leading to a higher (lower) than normal annual mass balance. This mechanism, entirely due to internal variations in the climate system, can explain observed strong positive mass balances for Nigardsbreen and possibly other maritime Norwegian glaciers within the period 1980-1995. It can also partly be responsible for recent strong negative mass balances of Alpine glaciers. (orig.)

  16. Twenty-one years of mass balance observations along the K-transect, West Greenland

    NARCIS (Netherlands)

    van de Wal, R.S.W.|info:eu-repo/dai/nl/101899556; Boot, W.; Smeets, C.J.P.P.|info:eu-repo/dai/nl/191522236; Snellen, H.; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643; Oerlemans, J.|info:eu-repo/dai/nl/06833656X

    2012-01-01

    A 21-yr record is presented of surface mass balance measurements along the Ktransect. The series covers the period 1990–2011. Data are available at 8 sites along a transect over an altitude range of 390–1850m at approximately 67 N in West Greenland. The surface mass balance gradient is on average

  17. Mass balance of the Amitsulôq ice cap, West Greenland

    DEFF Research Database (Denmark)

    Ahlstrøm, Andreas P.; Bøggild, Carl Egede; Olesen, Ole B.

    2007-01-01

    We present detailed mass balance measurements from the Amitsulôq ice cap in West Greenland spanning from 1982 to 1990. The data includes summer and winter balances from 26 stake locations distributed over five transects covering the whole ice cap. The mass balance measurements are combined...... meltwater, linking the hydropower potential of the basin closely to the fate of the adjoining Greenland ice-sheet margin....

  18. Measuring Air-water Interfacial Area for Soils Using the Mass Balance Surfactant-tracer Method

    Science.gov (United States)

    Araujo, Juliana B.; Mainhagu, Jon; Brusseau, Mark L.

    2015-01-01

    There are several methods for conducting interfacial partitioning tracer tests to measure air-water interfacial area in porous media. One such approach is the mass balance surfactant tracer method. An advantage of the mass-balance method compared to other tracer-based methods is that a single test can produce multiple interfacial area measurements over a wide range of water saturations. The mass-balance method has been used to date only for glass beads or treated quartz sand. The purpose of this research is to investigate the effectiveness and implementability of the mass-balance method for application to more complex porous media. The results indicate that interfacial areas measured with the mass-balance method are consistent with values obtained with the miscible-displacement method. This includes results for a soil, for which solid-phase adsorption was a significant component of total tracer retention. PMID:25950136

  19. Measuring air-water interfacial area for soils using the mass balance surfactant-tracer method.

    Science.gov (United States)

    Araujo, Juliana B; Mainhagu, Jon; Brusseau, Mark L

    2015-09-01

    There are several methods for conducting interfacial partitioning tracer tests to measure air-water interfacial area in porous media. One such approach is the mass balance surfactant tracer method. An advantage of the mass-balance method compared to other tracer-based methods is that a single test can produce multiple interfacial area measurements over a wide range of water saturations. The mass-balance method has been used to date only for glass beads or treated quartz sand. The purpose of this research is to investigate the effectiveness and implementability of the mass-balance method for application to more complex porous media. The results indicate that interfacial areas measured with the mass-balance method are consistent with values obtained with the miscible-displacement method. This includes results for a soil, for which solid-phase adsorption was a significant component of total tracer retention. Copyright © 2015 Elsevier Ltd. All rights reserved.

  20. Ranking of factors determining potassium mass balance in bicarbonate haemodialysis.

    Science.gov (United States)

    Basile, Carlo; Libutti, Pasquale; Lisi, Piero; Teutonico, Annalisa; Vernaglione, Luigi; Casucci, Francesco; Lomonte, Carlo

    2015-03-01

    One of the most important pathogenetic factors involved in the onset of intradialysis arrhytmias is the alteration in electrolyte concentration, particularly potassium (K(+)). Two studies were performed: Study A was designed to investigate above all the isolated effect of the factor time t on intradialysis K(+) mass balance (K(+)MB): 11 stable prevalent Caucasian anuric patients underwent one standard (∼4 h) and one long-hour (∼8 h) bicarbonate haemodialysis (HD) session. The latter were pair-matched as far as the dialysate and blood volume processed (90 L) and volume of ultrafiltration are concerned. Study B was designed to identify and rank the other factors determining intradialysis K(+)MB: 63 stable prevalent Caucasian anuric patients underwent one 4-h standard bicarbonate HD session. Dialysate K(+) concentration was 2.0 mmol/L in both studies. Blood samples were obtained from the inlet blood tubing immediately before the onset of dialysis and at t60, t120, t180 min and at end of the 4- and 8-h sessions for the measurement of plasma K(+), blood bicarbonates and blood pH. Additional blood samples were obtained at t360 min for the 8 h sessions. Direct dialysate quantification was utilized for K(+)MBs. Direct potentiometry with an ion-selective electrode was used for K(+) measurements. Study A: mean K(+)MBs were significantly higher in the 8-h sessions (4 h: -88.4 ± 23.2 SD mmol versus 8 h: -101.9 ± 32.2 mmol; P = 0.02). Bivariate linear regression analyses showed that only mean plasma K(+), area under the curve (AUC) of the hourly inlet dialyser diffusion concentration gradient of K(+) (hcgAUCK(+)) and AUC of blood bicarbonates and mean blood bicarbonates were significantly related to K(+)MB in both 4- and 8-h sessions. A multiple linear regression output with K(+)MB as dependent variable showed that only mean plasma K(+), hcgAUCK(+) and duration of HD sessions per se remained statistically significant. Study B: mean K(+)MBs were -86.7 ± 22.6 mmol

  1. Long-term change of mass balance and the role of radiation

    Science.gov (United States)

    Ohmura, Atsumu; Bauder, Andreas; Müller, Hans; Kappenberger, Giovanni

    2007-10-01

    The effect of climate change in the 20th century is investigated based on measured mass-balance data. Annual, winter and summer mass balances on Claridenfirn, Switzerland, (since 1914/15) Storglaciären, Sweden, (since 1945/46) Storbreen, Norway, (since 1948/49) Glacier de Sarennes, France, (since 1948/49) and Vernagtferner, Austria, (since 1965/66) are studied with air temperature at high-altitude stations and the longest records of solar global radiation in Europe. The mean mass balances of these glaciers during the 20th century were mostly negative except for the first two decades. The fluctuating mass balance reaches the minimum (largest loss) and maximum (almost equilibrium) around 1940 and 1980, respectively, with a drastic loss in the last 15 years. These variations are mostly steered by the variation in summer mass balance. The change in the summer mass balance is determined to 72% by temperature and the remaining 28% by solar radiation. During the colder period (e.g.1960-80), the reduction in solar radiation counteracted the warming trend due to the greenhouse effect. Since 1990 the greenhouse effect of terrestrial radiation and the global brightening effect of solar radiation have both been acting to accelerate the melt, resulting in the unprecedented mass loss of the observational era. The glacier mass balance during the 20th century clearly reacted towards temperature and solar radiation changes, which reflected the greenhouse effect and aerosol and cloud variations.

  2. Glacier modeling in support of field observations of mass balance at South Cascade Glacier, Washington, USA

    Science.gov (United States)

    Josberger, Edward G.; Bidlake, William R.

    2010-01-01

    The long-term USGS measurement and reporting of mass balance at South Cascade Glacier was assisted in balance years 2006 and 2007 by a new mass balance model. The model incorporates a temperature-index melt computation and accumulation is modeled from glacier air temperature and gaged precipitation at a remote site. Mass balance modeling was used with glaciological measurements to estimate dates and magnitudes of critical mass balance phenomena. In support of the modeling, a detailed analysis was made of the "glacier cooling effect" that reduces summer air temperature near the ice surface as compared to that predicted on the basis of a spatially uniform temperature lapse rate. The analysis was based on several years of data from measurements of near-surface air temperature on the glacier. The 2006 and 2007 winter balances of South Cascade Glacier, computed with this new, model-augmented methodology, were 2.61 and 3.41 mWE, respectively. The 2006 and 2007 summer balances were -4.20 and -3.63 mWE, respectively, and the 2006 and 2007 net balances were -1.59 and -0.22 mWE. PDF version of a presentation on the mass balance of South Cascade Glacier in Washington state. Presented at the American Geophysical Union Fall Meeting 2010.

  3. The mass balance of soil evolution on late Quaternary marine terraces, northern California

    Science.gov (United States)

    Merritts, Dorothy J.; Chadwick, Oliver A.; Hendricks, David M.; Brimhall, George H.; Lewis, Christopher J.

    1992-01-01

    Mass-balance interpretation of a soil chronosequence provides a means of quantifying elemental addition, removal, and transformation that occur in soils from a flight of marine terraces in northern California. Six soil profiles that range in age from several to 240,000 yr are developed in unconsolidated, sandy-marine, and eolian parent material deposited on bedrock marine platforms. Soil evolution is dominated by (1) open-system depletion of Si, Ca, Mg, K, and Na; (2) open-system enrichment of P in surface soil horizons; (3) relative immobility of Fe and Al; and (4) transformation of Fe, Si, and Al in the parent material to secondary clay minerals and sesquioxides. Net mass losses of bases and Si are generally uniform with depth and substantial, in some cases approaching 100 percent; however, the rate of loss of each element differs markedly, causing the ranking of each by relative abundance to shift with time. Loss of Si from the sand fraction by dissolution and particle-size diminution, from about 100 percent to less than 35 percent over 240 ky, mirrors a similar gain in the silt and clay size fractions. The Fe originally present in the sand fraction decreases from greater than 80 percent to less than 10 percent, whereas the amount of Fe present in the clay and crystalline oxyhydroxide fractions increases to 25 percent and 70 percent, respectively.

  4. Novel approach for quantitatively estimating element retention and material balances in soil profiles of recharge basins used for wastewater reclamation.

    Science.gov (United States)

    Eshel, Gil; Lin, Chunye; Banin, Amos

    2015-01-01

    We investigated changes in element content and distribution in soil profiles in a study designed to monitor the geochemical changes accruing in soil due to long-term secondary effluent recharge, and its impact on the sustainability of the Soil Aquifer Treatment (SAT) system. Since the initial elemental contents of the soils at the studied site were not available, we reconstructed them using scandium (Sc) as a conservative tracer. By using this approach, we were able to produce a mass-balance for 18 elements and evaluate the geochemical changes resulting from 19 years of effluent recharge. This approach also provides a better understanding of the role of soils as an adsorption filter for the heavy metals contained in the effluent. The soil mass balance suggests 19 years of effluent recharge cause for a significant enrichment in Cu, Cr, Ni, Zn, Mg, K, Na, S and P contents in the upper 4m of the soil profile. Combining the elements lode record during the 19 years suggest that Cr, Ni, and P inputs may not reach the groundwater (20 m deep), whereas the other elements may. Conversely, we found that 58, 60, and 30% of the initial content of Mn, Ca and Co respectively leached from the upper 2-m of the soil profile. These high percentages of Mn and Ca depletion from the basin soils may reduce the soil's ability to buffer decreases in redox potential pe and pH, respectively, which could initiate a reduction in the soil's holding capacity for heavy metals. Copyright © 2014 Elsevier B.V. All rights reserved.

  5. A minimal model for reconstructing interannual mass balance variability of glaciers in the European Alps

    Science.gov (United States)

    Marzeion, B.; Hofer, M.; Jarosch, A. H.; Kaser, G.; Mölg, T.

    2012-01-01

    We present a minimal model of the glacier surface mass balance. The model relies solely on monthly precipitation and air temperatures as forcing. We first train the model individually for 15 glaciers with existing mass balance measurements. Based on a cross validation, we present a thorough assessment of the model's performance outside of the training period. The cross validation indicates that our model is robust, and our model's performance compares favorably to that from a less parsimonious model based on seasonal sensitivity characteristics. Then, the model is extended for application on glaciers without existing mass balance measurements. We cross validated the model again by withholding the mass balance information from each of the 15 glaciers above during the model training, in order to measure its performance on glaciers not included in the model training. This cross validation indicates that the model retains considerable skill even when applied on glaciers without mass balance measurements. As an exemplary application, the model is then used to reconstruct time series of interannual mass balance variability, covering the past two hundred years, for all glaciers in the European Alps contained in the extended format of the world glacier inventory. Based on this reconstruction, we present a spatially detailed attribution of the glaciers' mass balance variability to temperature and precipitation variability.

  6. A minimal model for reconstructing interannual mass balance variability of glaciers in the European Alps

    Directory of Open Access Journals (Sweden)

    B. Marzeion

    2012-01-01

    Full Text Available We present a minimal model of the glacier surface mass balance. The model relies solely on monthly precipitation and air temperatures as forcing. We first train the model individually for 15 glaciers with existing mass balance measurements. Based on a cross validation, we present a thorough assessment of the model's performance outside of the training period. The cross validation indicates that our model is robust, and our model's performance compares favorably to that from a less parsimonious model based on seasonal sensitivity characteristics. Then, the model is extended for application on glaciers without existing mass balance measurements. We cross validated the model again by withholding the mass balance information from each of the 15 glaciers above during the model training, in order to measure its performance on glaciers not included in the model training. This cross validation indicates that the model retains considerable skill even when applied on glaciers without mass balance measurements.

    As an exemplary application, the model is then used to reconstruct time series of interannual mass balance variability, covering the past two hundred years, for all glaciers in the European Alps contained in the extended format of the world glacier inventory. Based on this reconstruction, we present a spatially detailed attribution of the glaciers' mass balance variability to temperature and precipitation variability.

  7. Mass balance re-analysis of Findelengletscher, Switzerland; benefits of extensive snow accumulation measurements

    Directory of Open Access Journals (Sweden)

    Leo eSold

    2016-02-01

    Full Text Available A re-analysis is presented here of a 10-year mass balance series at Findelengletscher, a temperate mountain glacier in Switzerland. Calculating glacier-wide mass balance from the set of glaciological point balance observations using conventional approaches, such as the profile or contour method, resulted in significant deviations from the reference value given by the geodetic mass change over a five-year period. This is attributed to the sparsity of observations at high elevations and to the inability of the evaluation schemes to adequately estimate accumulation in unmeasured areas. However, measurements of winter mass balance were available for large parts of the study period from snow probings and density pits. Complementary surveys by helicopter-borne ground-penetrating radar (GPR were conducted in three consecutive years. The complete set of seasonal observations was assimilated using a distributed mass balance model. This model-based extrapolation revealed a substantial mass loss at Findelengletscher of -0.43m w.e. a^-1 between 2004 and 2014, while the loss was less pronounced for its former tributary, Adlergletscher (-0.30m w.e. a^-1. For both glaciers, the resulting time series were within the uncertainty bounds of the geodetic mass change. We show that the model benefited strongly from the ability to integrate seasonal observations. If no winter mass balance measurements were available and snow cover was represented by a linear precipitation gradient, the geodetic mass balance was not matched. If winter balance measurements by snow probings and snow density pits were taken into account, the model performance was substantially improved but still showed a significant bias relative to the geodetic mass change. Thus the excellent agreement of the model-based extrapolation with the geodetic mass change was owed to an adequate representation of winter accumulation distribution by means of extensive GPR measurements.

  8. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    DEFF Research Database (Denmark)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes...... in glacier melt independently from model output. Here, we present a comprehensive database of Greenland glacier surface mass-balance observations from the ablation area of the ice sheet and local glaciers. The database spans the 123 a from 1892 to 2015, contains a total of similar to 3000 measurements from...

  9. Mass balance of the Greenland ice sheet (2003-2008) from ICESat data

    DEFF Research Database (Denmark)

    Sørensen, Louise Sandberg; Simonsen, Sebastian Bjerregaard; Nielsen, Karina

    2011-01-01

    ICESat has provided surface elevation measurements of the ice sheets since the launch in January 2003, resulting in a unique dataset for monitoring the changes of the cryosphere. Here, we present a novel method for determining the mass balance of the Greenland ice sheet, derived from ICESat...... studies of the Greenland ice sheet mass balance, based on different remote-sensing techniques....... altimetry data. Three different methods for deriving elevation changes from the ICESat altimetry dataset are used. This multi-method approach provides a method to assess the complexity of deriving elevation changes from this dataset. The altimetry alone can not provide an estimate of the mass balance...

  10. A top quark mass measurement using a matrix element method

    Energy Technology Data Exchange (ETDEWEB)

    Linacre, Jacob Thomas [St. John' s College, Annapolis, MD (United States)

    2009-01-01

    A measurement of the mass of the top quark is presented, using top-antitop pair (t$\\bar{t}$) candidate events for the lepton+jets decay channel. The measurement makes use of Tevatron p$\\bar{p}$ collision data at centre-of-mass energy √s = 1.96 TeV, collected at the CDF detector. The top quark mass is measured by employing an unbinned maximum likelihood method where the event probability density functions are calculated using signal (t$\\bar{t}$) and background (W+jets) matrix elements, as well as a set of parameterised jet-to-parton mapping functions. The likelihood function is maximised with respect to the top quark mass, the fraction of signal events, and a correction to the jet energy scale (JES) of the calorimeter jets. The simultaneous measurement of the JES correction (ΔJES) provides an in situ jet energy calibration based on the known mass of the hadronically decaying W boson. Using 578 lepton+jets candidate events corresponding to 3.2 fb -1 of integrated luminosity, the top quark mass is measured to be mt = 172.4± 1.4 (stat+ΔJES) ±1.3 (syst) GeV=c2, one of the most precise single measurements to date.

  11. The Mass Media, Gender Balance and Politics in Nigeria: An ...

    African Journals Online (AJOL)

    The study found out that the media still has a long way to go in the campaign for gender equality as the much they have done is still insignificant considering the miles yet to be covered. It was, therefore, recommended that the media should devote more time in the campaign for gender balance and that women should ...

  12. Mass balance of the Sør Rondane glacial system, East Antarctica

    NARCIS (Netherlands)

    Callens, Denis; Thonnard, Nicolas; Lenaerts, Jan T M; Van Wessem, Jan M.; Van De Berg, Willem Jan; Matsuoka, Kenichi; Pattyn, Frank

    2015-01-01

    Mass changes of polar ice sheets have an important societal impact, because they affect global sea level. Estimating the current mass budget of ice sheets is equivalent to determining the balance between surface mass gain through precipitation and outflow across the grounding line. For the Antarctic

  13. Tree-ring based mass balance estimates along the North Pacific Rim

    Science.gov (United States)

    Malcomb, N.; Wiles, G. C.

    2009-12-01

    Glacier mass balance reconstructions provide a means of placing short-term mass balance observations into a longer-term context. In western North America, most instrumental records of mass balance are limited in duration and capture only a narrow window of glacial behavior over an interval that is dominated by warming and ablation. Tree-ring series from northwestern North America are used to reconstruct annual mass balance for Gulkana and Wolverine Glaciers in Alaska, Peyto and Place Glaciers in British Columbia, and South Cascade and Blue Glaciers in Washington State. Mass balance models rely on the temperature and precipitation sensitivity of the tree-ring chronologies and mass balance records, as well as teleconnections along the North Pacific sector. The reconstructions extend through the latter portions of the Little Ice Age (LIA) and highlight the role of decadal and secular-scale climate change in forcing mass balance. Net mass balance reconstructions are broadly consistent with the moraine record that coincides with two major intervals of positive mass balance and with cooling related to the Maunder and Dalton solar minima. Secular warming in the later portions of the 19th and the 20th centuries corresponds with a pronounced interval of negative mass balance, and model instability after 1980. These trends show that the marked changes in glacier systems over recent decades throughout the Northwestern Cordillera are unique for the last several centuries and furthermore, suggest that modest gains forced by increasing precipitation over the latter 20th century in coastal settings are not sufficient to force glacier expansion or moraine building. Reconstructed (blue) and instrumental (red) net mass balances, Northern Hemisphere Temperature anomalies (Wilson et al., 2007), and PDO index (MacDonald and Case, 2005). A= Gulkana Glacier, B=Wolverine Glacier, C=Peyto Glacier, D=Place Glacier, E=South Cascade, F=Blue Glacier, G=PDO index, and H=Northern Hemisphere

  14. Inter-comparison of ice sheet mass balance products from GRACE: ESA CCI Round Robin results

    DEFF Research Database (Denmark)

    Groth, A.; Horwath, M.; Horvath, A.

    -term satellite-based data products are generated for selected ECVs. Since ice sheet mass balance is an ECV parameter of highest interest, both the AIS_cci and the GIS_cci project will provide mass balance products based on satellite gravimetry data: (a) time series of monthly mass changes for individual drainage...... basins, and (b) gridded mass changes covering the entire ice sheet.Gravimetry Mass Balance (GMB) products are derived from data acquired by the GRACE (Gravity Recovery and Climate Experiment) mission. Although GRACE data have the advantage of being directly sensitive to mass changes, their limited......Both the Antarctic Ice Sheet (AIS) and the Greenland Ice Sheet (GIS) have been identified as key parameters, so called Essential Climate Variables (ECV), in the climate system. Within the framework of the Climate Change Initiative (CCI) of the European Space Agency (ESA), reliable long...

  15. A mass balance model for the Eurasian ice sheet for the last 120,000 years

    NARCIS (Netherlands)

    van den Berg, J.; van de Wal, R.S.W.|info:eu-repo/dai/nl/101899556; Oerlemans, J.|info:eu-repo/dai/nl/06833656X

    2008-01-01

    We present a mass balance model for Eurasia which is based on the calculation of accumulation from a moisture balance concept. The model is forced with 500 hPa temperatures from GCM time slices at LGM and present day. The model simulates key characteristics, such as control on the size of ice sheets

  16. Myths and methodologies: Making sense of exercise mass and water balance.

    Science.gov (United States)

    Cheuvront, Samuel N; Montain, Scott J

    2017-09-01

    What is the topic of this review? There is a need to revisit the basic principles of exercise mass and water balance, the use of common equations and the practice of interpreting outcomes. What advances does it highlight? We propose use of the following equation as a way of simplifying exercise mass and water balance calculations in conditions where food is not consumed and waste is not excreted: ∆body mass - 0.20 g/kcal-1  = ∆body water. The relative efficacy of exercise drinking behaviours can be judged using the following equation: percentage dehydration = [(∆body mass - 0.20 g kcal-1 )/starting body mass] × 100. Changes in body mass occur because of flux in liquids, solids and gases. This knowledge is crucial for understanding metabolism, health and human water needs. In exercise science, corrections to observed changes in body mass to estimate water balance are inconsistently applied and often misinterpreted, particularly after prolonged exercise. Although acute body mass losses in response to exercise can represent a close surrogate for body water losses, the discordance between mass and water balance equivalence becomes increasingly inaccurate as more and more energy is expended. The purpose of this paper is briefly to clarify the roles that respiratory water loss, gas exchange and metabolic water production play in the correction of body mass changes for fluid balance determinations during prolonged exercise. Computations do not include waters of association with glycogen because any movement of water among body water compartments contributes nothing to water or mass flux from the body. Estimates of sweat loss from changes in body mass should adjust for non-sweat losses when possible. We propose use of the following equation as a way of simplifying the study of exercise mass and water balance: ∆body mass - 0.20 g kcal-1  = ∆body water. This equation directly controls for the influence of energy expenditure on body mass balance

  17. Point Measurements of Surface Mass Balance, Eklutna Glacier, Alaska, 2008-2015

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of a time-series of direct measurements of glacier surface mass balance, at Eklutna Glacier, Alaska. It includes seasonal measurements of...

  18. Glacier-Wide Mass Balance and Input Data: Alaska Benchmark Glaciers, 1966-2016

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Since the late 1950s, USGS has maintained a long-term glacier mass-balance program at three North American glaciers. Similar measurements began at Sperry Glacier, MT...

  19. Glacier Mass Balance and Regime Measurements and Analysis, 1945-2003, Version 1

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set consists of glacier regime parameters observed between 1945 and 2003. Data include annual mass balances, ablation, accumulation, and equilibrium-line...

  20. Point measurements of surface mass balance, Eklutna Glacier, Alaska, 2008-2015

    Science.gov (United States)

    Sass, Louis; Loso, Michael G.; Geck, Jason

    2017-01-01

    This data set consists of a time-series of direct measurements of glacier surface mass balance, at Eklutna Glacier, Alaska. It includes seasonal measurements of winter snow accumulation and summer snow and ice ablation.

  1. Daily physical activity as determined by age, body mass and energy balance.

    Science.gov (United States)

    Westerterp, Klaas R

    2015-06-01

    Insight into the determinants of physical activity, including age, body mass and energy balance, facilitates the design of intervention studies with body mass and energy balance as determinants of health and optimal performance. An analysis of physical activity energy expenditure in relation to age and body mass and in relation to energy balance, where activity energy expenditure is derived from daily energy expenditure as measured with doubly labelled water and body movement is measured with accelerometers, was conducted in healthy subjects under daily living conditions over intervals of one or more weeks. Activity energy expenditure as a fraction of daily energy expenditure is highest in adults at the reproductive age. Then, activity energy expenditure is a function of fat-free mass. Excess body mass as fat does not affect daily activity energy expenditure, but body movement decreases with increasing fatness. Overweight and obesity possibly affect daily physical activity energy expenditure through endurance. Physical activity is affected by energy availability; a negative energy balance induces a reduction of activity expenditure. Optimal performance and health require prevention of excess body fat and maintenance of energy balance, where energy balance determines physical activity rather than physical activity affecting energy balance.

  2. Quantifying the Mass Balance of Ice Caps on Severnaya Zemlya, Russian High Arctic. I: Climate and Mass Balance of the Vavilov Ice Cap

    NARCIS (Netherlands)

    Bassford, R.P.; Siegert, M.J.; Dowdeswell, J.A.; Oerlemans, J.; Glazovsky, A.F.; Macheret, Y.Y.

    2006-01-01

    Due to their remote location within the Russian High Arctic, little is known about the mass balance of ice caps on Severnaya Zemlya now and in the past. Such information is critical, however, to building a global picture of the cryospheric response to climate change. This paper provides a numerical

  3. Comparison of direct and geodetic mass balances on a multi-annual time scale

    Directory of Open Access Journals (Sweden)

    A. Fischer

    2011-02-01

    Full Text Available The geodetic mass balances of six Austrian glaciers over 19 periods between 1953 and 2006 are compared to the direct mass balances over the same periods. For two glaciers, Hintereisferner and Kesselwandferner, case studies showing possible reasons for discrepancies between the geodetic and the direct mass balance are presented. The mean annual geodetic mass balance for all periods is −0.5 m w.e. a−1, the mean annual direct mass balance −0.4 m w.e. a−1. The mean cumulative difference is −0.6 m w.e., the minimum −7.3 m w.e., and the maximum 5.6 m w.e. The accuracy of geodetic mass balance may depend on the accuracy of the DEMs, which ranges from 2 m w.e. for photogrammetric data to 0.02 m w.e. for airborne laser scanning (LiDAR data. Basal melt, seasonal snow cover, and density changes of the surface layer also contribute up to 0.7 m w.e. to the difference between the two methods over the investigated period of 10 yr. On Hintereisferner, the fraction of area covered by snow or firn has been changing within 1953–2006. The accumulation area is not identical with the firn area, and both are not coincident with areas of volume gain. Longer periods between the acquisition of the DEMs do not necessarily result in a higher accuracy of the geodetic mass balance. Trends in the difference between the direct and the geodetic data vary from glacier to glacier and can differ systematically for specific glaciers under specific types of climate forcing. Ultimately, geodetic and direct mass balance data are complementary, and great care must be taken when attempting to combine them.

  4. Mass Balance of the Ward Hunt Ice Rise and Ice Shelf: A 10 Year Record,

    Science.gov (United States)

    The results of 10 years’ (1958-68) record of accumulation and ablation from the Ward Hunt ice rise and of 3 years’ (1965-68) record from the Ward... Hunt Ice Shelf are presented. The net mass balances on the ice rise for the 3 years 1962-65 are positive, while the net mass balances measured in the other years on both ice rise and ice shelf are all negative. (Author)

  5. Analysis of balance beam deformation in the inertial mass measurement experiment

    Science.gov (United States)

    Fu, Zhuang; Zhang, Zhonghua; Li, Zhengkun; Li, Shisong

    2017-09-01

    This paper provides an analysis of mechanical balance beam deformation in the inertial mass measurement experiment since 2012. The relation between the applied test masses and three types of mechanical elastic deformation of the balance beam, i.e. the changes of rotational inertia, beam length and mass center, are discussed. It is found that changes in the rotational inertia and beam length are high order small quantities of the test mass, and a mechanically optimized balance beam which has good mechanical strength and a light structure is adopted to decrease the influence of the two types of deformation. The mass center change, being proportional to the test mass, has the most impact and can be compensated by a novel mass center compensation approach. Simulations and experiments confirm the effectiveness of the new balance beam and the mass center compensation method. It is emphasized that the analysis of the beam deformation in this paper can also be applied in other experiments where mechanical deformation of the balance beam needs to be considered.

  6. Recent Changes in Ices Mass Balance of the Amundsen Sea Sector

    Science.gov (United States)

    Sutterley, T. C.; Velicogna, I.; Rignot, E. J.; Mouginot, J.; Flament, T.; van den Broeke, M. R.; van Wessem, M.; Reijmer, C.

    2014-12-01

    The glaciers flowing into the Amundsen Sea Embayment (ASE) sector of West Antarctica were confirmed in the Ice Sheet Mass Balance Inter-comparison Exercise (IMBIE) to be the dominant contributors to the current Antarctic ice mass loss, and recently recognized to be undergoing marine ice sheet instability. Here, we investigate their regional ice mass balance using a time series of satellite and airborne data combined with model output products from the Regional Atmospheric and Climate Model (RACMO). Our dataset includes laser altimetry from NASA's ICESat-1 satellite mission and from Operation IceBridge (OIB) airborne surveys, satellite radar altimetry data from ESA's Envisat mission, time-variable gravity data from NASA/DLR's GRACE mission, surface mass balance products from RACMO, ice velocity from a combination of international synthetic aperture radar satellites and ice thickness data from OIB. We find a record of ice mass balance for the ASE where all the analyzed techniques agree remarkably in magnitude and temporal variability. The mass loss of the region has been increasing continuously since 1992, with no indication of a slow down. The mass loss during the common period averaged 91 Gt/yr and accelerated 20 Gt/yr2. In 1992-2013, the ASE contributed 4.5 mm global sea level rise. Overall, our results demonstrate the synergy of multiple analysis techniques for examining Antarctic Ice Sheet mass balance at the regional scale. This work was performed at UCI and JPL under a contract with NASA.

  7. Recycled Uranium Mass Balance Project Y-12 National Security Complex Site Report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-12-01

    This report has been prepared to summarize the findings of the Y-12 National Security Complex (Y-12 Complex) Mass Balance Project and to support preparation of associated U. S. Department of Energy (DOE) site reports. The project was conducted in support of DOE efforts to assess the potential for health and environmental issues resulting from the presence of transuranic (TRU) elements and fission products in recycled uranium (RU) processed by DOE and its predecessor agencies. The United States government used uranium in fission reactors to produce plutonium and tritium for nuclear weapons production. Because uranium was considered scarce relative to demand when these operations began almost 50 years ago, the spent fuel from U.S. fission reactors was processed to recover uranium for recycling. The estimated mass balance for highly enriched RU, which is of most concern for worker exposure and is the primary focus of this project, is summarized in a table. A discrepancy in the mass balance between receipts and shipments (plus inventory and waste) reflects an inability to precisely distinguish between RU and non-RU shipments and receipts involving the Y-12 Complex and Savannah River. Shipments of fresh fuel (non-RU) and sweetener (also non-RU) were made from the Y-12 Complex to Savannah River along with RU shipments. The only way to distinguish between these RU and non-RU streams using available records is by enrichment level. Shipments of {le}90% enrichment were assumed to be RU. Shipments of >90% enrichment were assumed to be non-RU fresh fuel or sweetener. This methodology using enrichment level to distinguish between RU and non-RU results in good estimates of RU flows that are reasonably consistent with Savannah River estimates. Although this is the best available means of distinguishing RU streams, this method does leave a difference of approximately 17.3 MTU between receipts and shipments. Slightly depleted RU streams received by the Y-12 Complex from ORGDP and

  8. Remote Sensing based modelling of Annual Surface Mass Balances of Chhota Shigiri Glacier, Western Himalayas, India

    Science.gov (United States)

    Chandrasekharan, Anita; Ramsankaran, Raaj

    2017-04-01

    The current study aims at modelling glacier mass balances over Chhota Shigiri glacier (32.28o N; 77.58° E) in Himachal Pradesh, India using the Equilibrium Line Altitude (ELA) gradient approach proposed by Rabatel et al. (2005). The model requires yearly ELA, average mass balance and mass balance gradient to estimate annual mass balance of a glacier which can be obtained either through field measurements or remote sensing observations. However, in view of the general scenario of lack of field data for Himalayan glaciers, in this study the model has been applied only using the inputs derived through multi-temporal satellite remote sensing observations thus eliminating the need for any field measurements. Preliminary analysis show that the obtained results are comparable with the observed field mass balance. The results also demonstrate that this approach with remote sensing inputs has potential to be used for glacier mass balance estimations provided good quality multi-temporal remote sensing dataset are available.

  9. Recent directions of electrospray mass spectrometry for elemental speciation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Schaumloeffel, Dirk [Universite de Pau et des Pays de l' Adour/CNRS UMR 5254, Laboratoire de Chimie Analytique Bio-Inorganique et Environnement/IPREM, Pau (France); Tholey, Andreas [Christian-Albrechts-Universitaet, Institute for Experimental Medicine - Div. Systematic Proteome Research, Kiel (Germany)

    2011-06-15

    A brief survey is given of the last 2 years' literature on electrospray mass spectrometry (ESI-MS) for speciation analysis. As observed for many years, the main recent applications in this field concern arsenic and selenium species, especially in studies encompassing combined use of molecular and element mass spectrometry. A further application field is the stoichiometric characterization of metal complexes by ESI-MS, which in some studies was assisted by nuclear magnetic resonance spectroscopy. A few examples are presented to illustrate arsenic species involved in metabolic pathways, sulfur species in oils and bitumen, and aluminum complexes. On the basis of this review, we also give an outlook of expected future developments and trends in this research field. (orig.)

  10. Understanding the Role of Wind in Reducing the Surface Mass Balance Estimates over East Antarctica

    Science.gov (United States)

    Das, I.; Scambos, T. A.; Koenig, L.; Creyts, T. T.; Bell, R. E.; van den Broeke, M. R.; Lenaerts, J.; Paden, J. D.

    2014-12-01

    Accurate quantification of surface snow-accumulation over Antarctica is important for mass balance estimates and climate studies based on ice core records. An improved estimate of surface mass balance must include the significant role near-surface wind plays in the sublimation and redistribution of snow across Antarctica. We have developed an empirical model based on airborne radar and lidar observations, and modeled surface mass balance and wind fields to produce a continent-wide prediction of wind-scour zones over Antarctica. These zones have zero to negative surface mass balance, are located over locally steep ice sheet areas (>0.002) and controlled by bedrock topography. The near-surface winds accelerate over these zones, eroding and sublimating the surface snow. This scouring results in numerous localized regions (≤ 200 km2) with reduced surface accumulation. Each year, tens of gigatons of snow on the Antarctic ice sheet are ablated by persistent near-surface katabatic winds over these wind-scour zones. Large uncertainties remain in the surface mass balance estimates over East Antarctica as climate models do not adequately represent the small-scale physical processes that lead to mass loss through sublimation or redistribution over the wind-scour zones. In this study, we integrate Operation IceBridge's snow radar over the Recovery Ice Stream with a series of ice core dielectric and depth-density profiles for improved surface mass balance estimates that reflect the mass loss over the wind-scour zones. Accurate surface mass balance estimates from snow radars require spatially variable depth-density profiles. Using an ensemble of firn cores, MODIS-derived surface snow grain size, modeled accumulation rates and surface temperatures from RACMO2, we assemble spatially variable depth-density profiles and use our mapping of snow density variations to estimate layer mass and net accumulation rates from snow radar layer data. Our study improves the quantification of

  11. Greenland ice mass balance from GPS, GRACE and ICESat

    DEFF Research Database (Denmark)

    Khan, Shfaqat Abbas; Kjær, Kurt H.; Korsgaard, Niels Jákup

    Greenland, using stereoscopic coverage by aerial photographs recorded in 1985, and subsequent comparative surface elevation data from ICESat (Ice, Cloud and land Elevation Satellite) and ATM (Airborne Topographic Mapper) supplemented with measurements from GPS and the Gravity Recovery and Climate Experiment......Global warming is predicted to have a profound impact on the Greenland Ice Sheet (GrIS) and its contribution to future sea-level rise. The GrIS has seen dramatic changes over the last two decades and mass loss has been accelerating, owing to a combination of increased runoff and discharge of ice...... glacier speed-ups are a response to recent external forcing and the start of a long-term trend in increasing mass loss, or related to internal variability in the ice sheet-climate system that occurs over a range of timescales. Here, we report multi-decadal observations of ice mass change from northwestern...

  12. Compact Sensitive Piezoelectric Mass Balance for Measurement of Unconsolidated Materials in Space

    Science.gov (United States)

    Sherrit, Stewart; Trebi-Ollennu, Ashitey; Bonitz, Robert; Bar-Cohen, Yoseph; Yen, Jesse T.

    2010-01-01

    In many in-situ instruments information about the mass of the sample could aid in the interpretation of the data and portioning instruments might require an accurate sizing of the sample mass before dispensing the sample. In addition, on potential sample return missions a method to directly assess the captured sample size would be required to determine if the sampler could return or needs to continue attempting to acquire sample. In an effort to meet these requirements piezoelectric balances were developed using flextensional actuators which are capable of monitoring the mass using two methods. A piezoelectric balance could be used to measure mass directly by monitoring the voltage developed across the piezoelectric which is linear with force, or it could be used in resonance to produce a frequency change proportional to the mass change. In this case of the latter, the piezoelectric actuator/balance would be swept in frequency through its fundamental resonance. If a mass is added to the balance the resonance frequency would shift down proportionally to the mass. By monitoring the frequency shift the mass could be determined. This design would allow for two independent measurements of the mass. In microgravity environments spacecraft thrusters could be used to provide acceleration in order to produce the required force for the first technique or to bring the mass into contact with the balance in the second approach. In addition, the measuring actuators, if driven at higher voltages, could be used to fluidize the powder to aid sample movement. In this paper, we outline some of our design considerations and present the results of a few prototype balances that we have developed.

  13. Local reduction of decadal glacier thickness loss through mass balance management in ski resorts

    Science.gov (United States)

    Fischer, Andrea; Helfricht, Kay; Stocker-Waldhuber, Martin

    2016-11-01

    For Austrian glacier ski resorts, established in the 1970s and 1980s during a period of glacier advance, negative mass balances with resulting glacier area loss and decrease in surface elevation present an operational challenge. Glacier cover, snow farming, and technical snow production were introduced as adaptation measures based on studies on the effect of these measures on energy and mass balance. After a decade of the application of the various measures, we studied the transition from the proven short-term effects of the measures on mass balance to long-term effects on elevation changes. Based on lidar digital elevation models and differential GPS measurements, decadal surface elevation changes in 15 locations with mass balance management were compared to those without measures (apart from piste grooming) in five Tyrolean ski resorts on seven glaciers. The comparison of surface elevation changes presents clear local differences in mass change, and it shows the potential to retain local ice thickness over 1 decade. Locally up to 21.1 m ± 0.4 m of ice thickness was preserved on mass balance managed areas compared to non-maintained areas over a period of 9 years. In this period, mean annual thickness loss in 15 of the mass balance managed profiles is 0.54 ± 0.04 m yr-1 lower (-0.23 ± 0.04 m yr-1on average) than in the respective reference areas (-0.78 ± 0.04 m yr-1). At two of these profiles the surface elevation was preserved altogether, which is promising for a sustainable maintenance of the infrastructure at glacier ski resorts. In general the results demonstrate the high potential of the combination of mass balance management by snow production and glacier cover, not only in the short term but also for multi-year application to maintain the skiing infrastructure.

  14. Simulation of incompressible flows with heat and mass transfer using parallel finite element method

    Directory of Open Access Journals (Sweden)

    Jalal Abedi

    2003-02-01

    Full Text Available The stabilized finite element formulations based on the SUPG (Stream-line-Upwind/Petrov-Galerkin and PSPG (Pressure-Stabilization/Petrov-Galerkin methods are developed and applied to solve buoyancy-driven incompressible flows with heat and mass transfer. The SUPG stabilization term allows us to solve flow problems at high speeds (advection dominant flows and the PSPG term eliminates instabilities associated with the use of equal order interpolation functions for both pressure and velocity. The finite element formulations are implemented in parallel using MPI. In parallel computations, the finite element mesh is partitioned into contiguous subdomains using METIS, which are then assigned to individual processors. To ensure a balanced load, the number of elements assigned to each processor is approximately equal. To solve nonlinear systems in large-scale applications, we developed a matrix-free GMRES iterative solver. Here we totally eliminate a need to form any matrices, even at the element levels. To measure the accuracy of the method, we solve 2D and 3D example of natural convection flows at moderate to high Rayleigh numbers.

  15. Improving Estimates of Greenland Ice Sheet Surface Mass Balance with Satellite Observations

    Science.gov (United States)

    Briggs, K.

    2016-12-01

    Mass losses from the Greenland Ice Sheet have been accelerating over recent years (e.g. McMillan et al., 2016; Velicogna et al., 2014). This acceleration has predominantly been linked to increasing rates of negative surface mass balance, and in particular, increasing ice surface melt rates (e.g. McMillan et al., 2016; Velicogna et al., 2014). At the ice sheet scale, SMB is assessed using SMB model outputs, which in addition to enabling understanding of the origin of mass balance signals, are required as ancillary data in mass balance assessments from altimetry and the mass budget method. Due to the importance of SMB for mass balance over Greenland and the sensitivity of mass balance assessments to SMB model outputs, high accuracy of these models is crucial. A critical limiting factor in SMB modeling is however, a lack of in-situ data that is required for model constraint and evaluation. Such data is limited in time and space due to inherent logistical and financial constraints. Remote sensing datasets, being spatially extensive and relatively densely sampled in both space and time, do not suffer such constraints. Here, we show satellite observations of Greenland SMB. McMillan, M., Leeson, A., Shepherd, A., Briggs, K., Armitage, T. W.K., Hogg, A., Kuipers Munneke, P., van den Broeke, M., Noël, B., van de Berg, W., Ligtenberg, S., Horwath, M., Groh, A. , Muir, A. and Gilbert, L. 2016. A high resolution record of Greenland Mass Balance. Geophysical Research Letters. 43, doi:10.1002/2016GL069666 Velicogna, I., Sutterley, T. C. and van den Broeke, M. R. 2014. Regional acceleration in ice mass loss from Greenland and Antarctica using GRACE time-variable gravity data. Geophysical Research Letters. 41, 8130-8137, doi:10.1002/2014GL061052

  16. A 3-axis force balanced accelerometer using a single proof-mass

    Energy Technology Data Exchange (ETDEWEB)

    Lemkin, M.A.; Boser, B.E.; Auslander, D. [Univ. of California, Berkeley, CA (United States); Smith, J. [Sandia National Lab., Albuquerque, NM (United States)

    1997-04-01

    This paper presents a new method for wideband force balancing a proof-mass in multiple axes simultaneously. Capacitive position sense and force feedback are accomplished using the same air-gap capacitors through time multiplexing. Proof of concept is experimentally demonstrated with a single-mass monolithic surface micromachined 3-axis accelerometer.

  17. The 'extrapolated center of mass' concept suggests a simple control of balance in walking

    NARCIS (Netherlands)

    Hof, At L.

    Next to position x and velocity v of the whole body center of mass (CoM) the 'extrapolated center of mass' (XcoM) can be introduced: zeta = x + v/omega(0), where omega(0) is a constant related to stature. Based on the inverted pendulum model of balance, the XcoM enables to formulate the requirements

  18. The pattern of anthropogenic signal emergence in Greenland Ice Sheet surface mass balance

    NARCIS (Netherlands)

    Fyke, J.G.; Vizcaino, M.; Lipscomb, W.H.

    2014-01-01

    Surface mass balance (SMB) trends influence observed Greenland Ice Sheet (GrIS) mass loss, but the component of these trends related to anthropogenic forcing is unclear. Here we study the simulated spatial pattern of emergence of an anthropogenically derived GrIS SMB signal between 1850 and 2100

  19. Water vapor mass balance method for determining air infiltration rates in houses

    Science.gov (United States)

    David R. DeWalle; Gordon M. Heisler

    1980-01-01

    A water vapor mass balance technique that includes the use of common humidity-control equipment can be used to determine average air infiltration rates in buildings. Only measurements of the humidity inside and outside the home, the mass of vapor exchanged by a humidifier/dehumidifier, and the volume of interior air space are needed. This method gives results that...

  20. Can we close the long term mass balance equation for pollutants in highway ponds?

    DEFF Research Database (Denmark)

    Bentzen, Thomas Ruby; Larsen, Torben; Rasmussen, Michael R.

    2007-01-01

    The paper discusses the prospects of finding the long term mass balance on basis of short term simulations. A step in this process is to see to which degree the mass balance equation can be closed by measurements. Accordingly the total accumulation of heavy metals and PAH's in 8 Danish detention...... ponds only receiving runoff from highways have been measured. The result shows that the incoming mass of heavy metals from short term runoff events is accumulated. This is not observable in the same magnitude for the toxic organic compounds. The results also show that the accumulation rates...

  1. Diagnosing the decline in climatic mass balance of glaciers in Svalbard over 1957-2014

    Science.gov (United States)

    Ims Østby, Torbjørn; Vikhamar Schuler, Thomas; Ove Hagen, Jon; Hock, Regine; Kohler, Jack; Reijmer, Carleen H.

    2017-01-01

    Estimating the long-term mass balance of the high-Arctic Svalbard archipelago is difficult due to the incomplete geodetic and direct glaciological measurements, both in space and time. To close these gaps, we use a coupled surface energy balance and snow pack model to analyse the mass changes of all Svalbard glaciers for the period 1957-2014. The model is forced by ERA-40 and ERA-Interim reanalysis data, downscaled to 1 km resolution. The model is validated using snow/firn temperature and density measurements, mass balance from stakes and ice cores, meteorological measurements, snow depths from radar profiles and remotely sensed surface albedo and skin temperatures. Overall model performance is good, but it varies regionally. Over the entire period the model yields a climatic mass balance of 8.2 cm w. e. yr-1, which corresponds to a mass input of 175 Gt. Climatic mass balance has a linear trend of -1.4 ± 0.4 cm w. e. yr-2 with a shift from a positive to a negative regime around 1980. Modelled mass balance exhibits large interannual variability, which is controlled by summer temperatures and further amplified by the albedo feedback. For the recent period 2004-2013 climatic mass balance was -21 cm w. e. yr-1, and accounting for frontal ablation estimated by Błaszczyk et al.(2009) yields a total Svalbard mass balance of -39 cm w. e. yr-1 for this 10-year period. In terms of eustatic sea level, this corresponds to a rise of 0.037 mm yr-1. Refreezing of water in snow and firn is substantial at 22 cm w. e. yr-1 or 26 % of total annual accumulation. However, as warming leads to reduced firn area over the period, refreezing decreases both absolutely and relative to the total accumulation. Negative mass balance and elevated equilibrium line altitudes (ELAs) resulted in massive reduction of the thick (> 2 m) firn extent and an increase in the superimposed ice, thin (< 2 m) firn and bare ice extents. Atmospheric warming also leads to a marked change in the thermal regime

  2. Use of mass and toxicity balances in risk-based corrective action decisions at contaminated sites

    Energy Technology Data Exchange (ETDEWEB)

    Sevigny, J.H. [Komex Consultants Ltd., Calgary, AB (Canada); Lintott, D. [HydroQual Consultants, Inc., Calgary, AB (Canada); Wrubleski, R.M.; Drury, C.R. [Shell Canada Ltd., Calgary, AB (Canada). Calgary Research Centre

    1997-12-31

    The contaminated groundwater at a sour gas plant facility was studied to identify the chemicals of environmental concern. Simple mass balance principles were used to determine the proportion of organic carbon, organic nitrogen and Microtox{sup R} toxicity that can be attributed to two process chemicals that have contaminated several sour gas plants in western Canada. The two process chemicals are sulfolane and diisopropanolamine (DIPA). The organic carbon balance was calculated by determining the molar contribution of sulfolane and DIPA relative to the mass of carboxylic acid-corrected dissolved organic carbon. Organic carbon balances ranged from 44 to 96 per cent. The organic nitrogen balance was calculated by determining the molar contribution of DIPA relative to the mass of ammonium ion-corrected dissolved Kjeldahl nitrogen. The nitrogen balances were highly variable between 8 to 48 per cent for samples with organic nitrogen concentrations between 10 and 32 mg/L. The Microtox{sup R} toxicity balance was calculated by determining the proportions of toxicity that could be accounted for by pure phase sulfolane and DIPA. The Microtox{sup R} toxicity balance for samples that showed significant toxicity ranged from 71 to 122 per cent.

  3. Assessing streamflow sensitivity to variations in glacier mass balance

    Science.gov (United States)

    O'Neel, Shad; Hood, Eran; Arendt, Anthony; Sass, Louis

    2014-01-01

    The mountains ringing the Gulf of Alaska (GOA) receive upwards of 4–8 m yr−1 of precipitation (Simpson et al.2005; Weingartner et al. 2005; O’Neel 2012), much of which runs off into productive coastal waters. The alpine landscape is heavily glacierized, and storage and turnover of water by glaciers substantially influences the regional surface water balance (Neal et al. 2010). In turn, the land-to-ocean flux of freshwater impacts the biogeochemistry, physical oceanography, freshwater and marine ecology of the downstream components of the GOA ecosystem (e.g., Royer et al. 2001; Hood and Scott 2008). In this way, the links between terrestrial and ocean ecosystems along the GOA have widespread impacts on regional socioeconomic issues including water and hydropower resources, fish populations, and sea level change (Dorava and Milner 2000; Royer and Grosch 2006; Cherry et al. 2010; Gardner et al. 2013). Moreover, predicting future changes in physical, chemical and biological processes in near-shore ecosystems along the GOA hinges, in part, on developing a robust understanding of water storage and transfer by glaciers through streams to the ocean.

  4. Impact of Seminal Chemical Elements on the Oxidative Balance in Bovine Seminal Plasma and Spermatozoa

    Science.gov (United States)

    Tvrdá, Eva; Lukáč, Norbert; Schneidgenová, Monika; Lukáčová, Jana; Szabó, Csaba; Goc, Zofia; Greń, Agnieszka; Massányi, Peter

    2013-01-01

    Mutual relationships between selected chemical elements (Na, K, Fe, Cu, Mg, and Zn), basic motility characteristics (motility and progressive motility), and markers of the oxidative balance (superoxide dismutase, catalase, glutathione, albumin, and malondialdehyde) were investigated in bovine seminal plasma and spermatozoa. Computer assisted sperm analysis was used to assess the motility parameters; mineral concentrations were determined by the voltammetric method and flame absorption spectrophotometry; antioxidants and malondialdehyde were evaluated by UV/VIS spectrophotometry. Concentrations of chemical elements in both seminal fractions were in the following descending order: Na > K > Zn > Mg > Fe > Cu. Higher amounts of all minerals and nonenzymatic antioxidants were detected in the seminal plasma (P chemical elements are integral components of bovine semen and are needed for the protection against oxidative stress development. PMID:26464901

  5. Finite Element Analysis of Walking Beam of a New Compound Adjustment Balance Pumping Unit

    Science.gov (United States)

    Wu, Jufei; Wang, Qian; Han, Yunfei

    2017-12-01

    In this paper, taking the designer of the new compound balance pumping unit beam as our research target, the three-dimensional model is established by Solid Works, the load and the constraint are determined. ANSYS Workbench is used to analyze the tail and the whole of the beam, the stress and deformation are obtained to meet the strength requirements. The finite element simulation and theoretical calculation of the moment of the center axis beam are carried out. The finite element simulation results are compared with the calculated results of the theoretical mechanics model to verify the correctness of the theoretical calculation. Finally, the finite element analysis is consistent with the theoretical calculation results. The theoretical calculation results are preferable, and the bending moment value provides the theoretical reference for the follow-up optimization and research design.

  6. The influence of changes in glacier extent and surface elevation on modeled mass balance

    Directory of Open Access Journals (Sweden)

    F. Paul

    2010-12-01

    Full Text Available Glaciers are widely recognized as unique demonstration objects for climate change impacts, mostly due to the strong change of glacier length in response to small climatic changes. However, glacier mass balance as the direct response to the annual atmospheric conditions can be better interpreted in meteorological terms. When the climatic signal is deduced from long-term mass balance data, changes in glacier geometry (i.e. surface extent and elevation must be considered as such adjustments form an essential part of the glacier reaction to new climatic conditions. In this study, a set of modelling experiments is performed to assess the influence of changes in glacier geometry on mass balance for constant climatic conditions. The calculations are based on a simplified distributed energy/mass balance model in combination with information on glacier extent and surface elevation for the years 1850 and 1973/1985 for about 60 glaciers in the Swiss Alps. The results reveal that over this period about 50–70% of the glacier reaction to climate change (here a one degree increase in temperature is "hidden" in the geometric adjustment, while only 30–50% can be measured as the long-term mean mass balance. For larger glaciers, the effect of the areal change is partly reduced by a lowered surface elevation, which results in a slightly more negative balance despite a potential increase of topographic shading. In view of several additional reinforcement feedbacks that are observed in periods of strong glacier decline, it seems that the climatic interpretation of long-term mass balance data is rather complex.

  7. Glaciological measurements and mass balances from Sperry Glacier, Montana, USA, years 2005–2015

    Science.gov (United States)

    Clark, Adam; Fagre, Daniel B.; Peitzsch, Erich H.; Reardon, Blase A.; Harper, Joel T.

    2017-01-01

    Glacier mass balance measurements help to provide an understanding of the behavior of glaciers and their response to local and regional climate. In 2005 the United States Geological Survey established a surface mass balance monitoring program on Sperry Glacier, Montana, USA. This project is the first quantitative study of mass changes of a glacier in the US northern Rocky Mountains and continues to the present. The following paper describes the methods used during the first 11 years of measurements and reports the associated results. From 2005 to 2015, Sperry Glacier had a cumulative mean mass balance loss of 4.37 m w.e. (water equivalent). The mean winter, summer, and annual glacier-wide mass balances were 2.92, −3.41, and −0.40 m w.e. yr−1 respectively. We derive these cumulative and mean results from an expansive data set of snow depth, snow density, and ablation measurements taken at selected points on the glacier. These data allow for the determination of mass balance point values and a time series of seasonal and annual glacier-wide mass balances for all 11 measurement years. We also provide measurements of glacier extent and accumulation areas for select years. All data have been submitted to the World Glacier Monitoring Service and are available at doi:10.5904/wgms-fog-2016-08. This foundational work provides valuable insight about Sperry Glacier and supplies additional data to the worldwide record of glaciers measured using the glaciological method. Future research will focus on the processes that control accumulation and ablation patterns across the glacier. Also we plan to examine the uncertainties related to our methods and eventually quantify a more robust estimate of error associated with our results.

  8. Glaciological measurements and mass balances from Sperry Glacier, Montana, USA, years 2005-2015

    Science.gov (United States)

    Clark, Adam M.; Fagre, Daniel B.; Peitzsch, Erich H.; Reardon, Blase A.; Harper, Joel T.

    2017-01-01

    Glacier mass balance measurements help to provide an understanding of the behavior of glaciers and their response to local and regional climate. In 2005 the United States Geological Survey established a surface mass balance monitoring program on Sperry Glacier, Montana, USA. This project is the first quantitative study of mass changes of a glacier in the US northern Rocky Mountains and continues to the present. The following paper describes the methods used during the first 11 years of measurements and reports the associated results. From 2005 to 2015, Sperry Glacier had a cumulative mean mass balance loss of 4.37 m w.e. (water equivalent). The mean winter, summer, and annual glacier-wide mass balances were 2.92, -3.41, and -0.40 m w.e. yr-1 respectively. We derive these cumulative and mean results from an expansive data set of snow depth, snow density, and ablation measurements taken at selected points on the glacier. These data allow for the determination of mass balance point values and a time series of seasonal and annual glacier-wide mass balances for all 11 measurement years. We also provide measurements of glacier extent and accumulation areas for select years. All data have been submitted to the World Glacier Monitoring Service and are available at doi:10.5904/wgms-fog-2016-08. This foundational work provides valuable insight about Sperry Glacier and supplies additional data to the worldwide record of glaciers measured using the glaciological method. Future research will focus on the processes that control accumulation and ablation patterns across the glacier. Also we plan to examine the uncertainties related to our methods and eventually quantify a more robust estimate of error associated with our results.

  9. A heuristic simulation model of Lake Ontario circulation and mass balance transport

    Science.gov (United States)

    McKenna, J.E.; Chalupnicki, M.A.

    2011-01-01

    The redistribution of suspended organisms and materials by large-scale currents is part of natural ecological processes in large aquatic systems but can contribute to ecosystem disruption when exotic elements are introduced into the system. Toxic compounds and planktonic organisms spend various lengths of time in suspension before settling to the bottom or otherwise being removed. We constructed a simple physical simulation model, including the influence of major tributaries, to qualitatively examine circulation patterns in Lake Ontario. We used a simple mass balance approach to estimate the relative water input to and export from each of 10 depth regime-specific compartments (nearshore vs. offshore) comprising Lake Ontario. Despite its simplicity, our model produced circulation patterns similar to those reported by more complex studies in the literature. A three-gyre pattern, with the classic large counterclockwise central lake circulation, and a simpler two-gyre system were both observed. These qualitative simulations indicate little offshore transport along the south shore, except near the mouths of the Niagara River and Oswego River. Complex flow structure was evident, particularly near the Niagara River mouth and in offshore waters of the eastern basin. Average Lake Ontario residence time is 8 years, but the fastest model pathway indicated potential transport of plankton through the lake in as little as 60 days. This simulation illustrates potential invasion pathways and provides rough estimates of planktonic larval dispersal or chemical transport among nearshore and offshore areas of Lake Ontario. ?? 2011 Taylor & Francis.

  10. Differences in mass balance behavior for three glaciers from different climatic regions on the Tibetan Plateau

    Science.gov (United States)

    Zhu, Meilin; Yao, Tandong; Yang, Wei; Xu, Baiqing; Wu, Guanjian; Wang, Xiaojun

    2017-07-01

    Glacier mass balance shows a spatially heterogeneous pattern in response to global warming on the Tibetan Plateau (TP), and the climate mechanisms controlling this pattern require further study. In this study, three glaciers where systematic glaciological and meteorological observations have been carried out were selected, specifically Parlung No. 4 (PL04) and Zhadang (ZD) glaciers on the southern TP and Muztag Ata No. 15 (MZ15) glacier in the eastern Pamir. The characteristics of the mass and energy balances of these three glaciers during the periods between October 1th, 2008 and September 23rd, 2013 were analyzed and compared using the energy and mass balance model. Results show that differences in surface melt, which mainly result from differences in the amounts of incoming longwave radiation (L in ) and outgoing shortwave radiation (S out ), represent the largest source of the observed differences in mass balance changes between PL04 and ZD glaciers and MZ15 glacier, where air temperature, humidity, precipitation and cloudiness are dramatically different. In addition, sensitivity experiments show that mass balance sensitivity to air temperature change is remarkably higher than that associated with precipitation change on PL04 and ZD glaciers, in contrast results from MZ15 glacier. And significantly higher sensitivities to air temperature change are noted for PL04 and ZD glaciers than for MZ15 glacier. These significant differences in the sensitivities to air temperature change are mainly caused by differences in the ratio of snowfall to precipitation during the ablation season, melt energy (L in +S out ) during the ablation season and the seasonality of precipitation among the different regions occupied by glaciers. In turn, these conditions are related to local climatic conditions, especially air temperature. These factors can be used to explain the different patterns of change in Tibetan glacier mass balance under global warming.

  11. Impact of co-digestion on existing salt and nutrient mass balances for a full-scale dairy energy project.

    Science.gov (United States)

    Camarillo, Mary Kay; Stringfellow, William T; Spier, Chelsea L; Hanlon, Jeremy S; Domen, Jeremy K

    2013-10-15

    Anaerobic digestion of manure and other agricultural waste streams with subsequent energy production can result in more sustainable dairy operations; however, importation of digester feedstocks onto dairy farms alters previously established carbon, nutrient, and salinity mass balances. Salt and nutrient mass balance must be maintained to avoid groundwater contamination and salination. To better understand salt and nutrient contributions of imported methane-producing substrates, a mass balance for a full-scale dairy biomass energy project was developed for solids, carbon, nitrogen, sulfur, phosphorus, chloride, and potassium. Digester feedstocks, consisting of thickened manure flush-water slurry, screened manure solids, sudan grass silage, and feed-waste, were tracked separately in the mass balance. The error in mass balance closure for most elements was less than 5%. Manure contributed 69.2% of influent dry matter while contributing 77.7% of nitrogen, 90.9% of sulfur, and 73.4% of phosphorus. Sudan grass silage contributed high quantities of chloride and potassium, 33.3% and 43.4%, respectively, relative to the dry matter contribution of 22.3%. Five potential off-site co-digestates (egg waste, grape pomace, milk waste, pasta waste, whey wastewater) were evaluated for anaerobic digestion based on salt and nutrient content in addition to bio-methane potential. Egg waste and wine grape pomace appeared the most promising co-digestates due to their high methane potentials relative to bulk volume. Increasing power production from the current rate of 369 kW to the design value of 710 kW would require co-digestion with either 26800 L d(-1) egg waste or 60900 kg d(-1) grape pomace. However, importation of egg waste would more than double nitrogen loading, resulting in an increase of 172% above the baseline while co-digestion with grape pomace would increase potassium by 279%. Careful selection of imported co-digestates and management of digester effluent is required to

  12. Evaluation of a mass-balance approach to determine consumptive water use in northeastern Illinois

    Science.gov (United States)

    Mills, Patrick C.; Duncker, James J.; Over, Thomas M.; Marian Domanski,; ,; Engel, Frank

    2014-01-01

    A principal component of evaluating and managing water use is consumptive use. This is the portion of water withdrawn for a particular use, such as residential, which is evaporated, transpired, incorporated into products or crops, consumed by humans or livestock, or otherwise removed from the immediate water environment. The amount of consumptive use may be estimated by a water (mass)-balance approach; however, because of the difficulty of obtaining necessary data, its application typically is restricted to the facility scale. The general governing mass-balance equation is: Consumptive use = Water supplied - Return flows.

  13. Divergent Surface Mass Balances of Neighboring glaciers: Reanalysis of Taku and Lemon Creek glaciers, Alaska: 1946-2015

    Science.gov (United States)

    McNeil, C.; O'Neel, S.; Loso, M.; Pelto, M. S.; Sass, L.; Candela, S. G.

    2016-12-01

    Despite high mass loss rates of Alaskan glaciers, altimetric observations suggest strong glacier-to-glacier variability of cumulative surface mass balance, which prevents the detection of climate-forced spatial patterns of glacier change. This observation motivated us to reanalyze surface mass balance records from the neighboring Taku and Lemon Creek glaciers. Our reanalysis spans 1946—present and synthesizes all known field and remotely sensed data. Our results include end-of season temperature-index model corrections forced with regional radiosonde data and geodetic calibration using digital elevation models derived from historic stereo imagery and synthetic aperture radar. The results allowed us to examine the role climate and basin hypsometry play in surface mass balance. They suggest no significant differences from previous glaciological estimates and that the 63-year average, annual mass balance is +0.24 m w.e. a-1 at Taku Glacier and -0.56 m w.e. a-1 for Lemon Creek Glacier. Despite the divergence between the long-term trends, the annual mass balance anomaly time series demonstrate coherent inter-annual variability and are not statistically different. Their similarities suggest that climate forcing is unlikely driving the different trends. To explore the role that glacier hypsometry plays in the time-series, we applied the steeper mass balance profile from Lemon Creek Glacier to the Taku hypsometry and vice-versa. Surface mass balances exhibit high sensitivities to the mass balance profile perturbation, but the divergent nature of the cumulative mass balance series was preserved. This simple experiment suggests that hypsometry and the mass balance profile are both important drivers for systematic differences that accumulate in cumulative surface mass balance rates. Thus, accounting for glacier-to-glacier variability of mass balance profiles, as well as hypsometry, would improve our understanding of climate-forced Alaskan glacier change.

  14. Kinetics of inactivation and dilution effects on the mass balance of fungal phytopathogens in anaerobic digesters.

    Science.gov (United States)

    Plöchl, Matthias; Heiermann, Monika; Rodemann, Bernd; Bandte, Martina; Büttner, Carmen

    2014-01-15

    Knowledge of fate and behavior of plant pathogens in the biogas production chain is limited and hampers the estimation and evaluation of the potential phytosanitary risk if digestate is spread on arable land as a fertilizer. Therefore, simulation is an appropriate tool to demonstrate the effects which influence the steady state of pathogen infected plant material in both digesters and digestate. Simple approaches of kinetics of inactivation and mass balances of infected material were carried out considering single-step as well as two-step digestion. The simulation revealed a very fast to fast reduction of infected material after a singular feeding, reaching a cutback to less than 1% of input within 4 days even for D90-values of 68 h. Steady state mass balances below input rate could be calculated with D90-values of less than 2 h at a continuous hourly feeding. At higher D90-values steady state mass balances exceed the input rate but are still clearly below the sum of input mass. Dilution further decreases mass balances to values 10(-5) to 10(-6) Mg m(-3) for first-step digestion and 10(-8) to 10(-9) for second-step. Copyright © 2013 Elsevier Ltd. All rights reserved.

  15. Basin-scale partitioning of Greenland ice sheet mass balance components (2007-2011)

    DEFF Research Database (Denmark)

    Andersen, M.L.; Stenseng, Lars; Skourup, Henriette

    2015-01-01

    The current deficit in Greenland ice sheet mass balance is due to both a decrease in surface mass balance (SMB) input and an increase in ice discharge (D) output. While SMB processes are beginning to be well captured by observationally-constrained climate modeling, insight into D is relatively...... of the gate. Using a 1961-1990 reference climatology SMB field from the MAR regional climate model, we quantify ice sheet mass balance within eighteen basins. We find a 2007-2011 mean D of 515±57 Gtyr-1. We find a 2007-2011 mean total mass balance of -262±21 Gtyr-1, which is equal to a 0.73 mm yr-1 global sea...... limited. We use InSAR-derived velocities, in combination with ice thickness observations, to quantify the mass flux (F) across a flux perimeter around the ice sheet at ~1700 m elevation. To quantify D, we correct F for SMB, as well as changes in volume due to ice dynamics, in the area downstream...

  16. Studying the capture cross sections of structural elements by measuring neutron balance in multiplying media

    Energy Technology Data Exchange (ETDEWEB)

    Golubev, V.N.; Dulin, V.A.; Kazanskij, Yu.A.

    1986-10-01

    To refine neutron capture cross sections for structural elements used in fast power reactors the neutron balance in multiplying media with neutron multiplication factor K/sub infinity/=1 has been studied at KBR and ERMINE critical assemblies. Reactivity of multiplying cells consisting of uranium and structural elements is measured as well as reactivity coefficients of individual structural materials. Corresponding calculations are performed using the versions of group constants applied in designing the fast reactors in the USSR and France. The CARNAVAL 4 constant version predicts well a fraction of neutron absorptions in steel and nickel for the spectra typical for a power reactor (ERMINE assembly). For softer spectra (KBR assembly) the agreement with experiment is better when the BNAB-78 constant version is used.

  17. Comparison of surface mass balance of ice sheets simulated by positive-degree-day method and energy balance approach

    Science.gov (United States)

    Bauer, Eva; Ganopolski, Andrey

    2017-07-01

    Glacial cycles of the late Quaternary are controlled by the asymmetrically varying mass balance of continental ice sheets in the Northern Hemisphere. Surface mass balance is governed by processes of ablation and accumulation. Here two ablation schemes, the positive-degree-day (PDD) method and the surface energy balance (SEB) approach, are compared in transient simulations of the last glacial cycle with the Earth system model of intermediate complexity CLIMBER-2. The standard version of the CLIMBER-2 model incorporates the SEB approach and simulates ice volume variations in reasonable agreement with paleoclimate reconstructions during the entire last glacial cycle. Using results from the standard CLIMBER-2 model version, we simulated ablation with the PDD method in offline mode by applying different combinations of three empirical parameters of the PDD scheme. We found that none of the parameter combinations allow us to simulate a surface mass balance of the American and European ice sheets that is similar to that obtained with the standard SEB method. The use of constant values for the empirical PDD parameters led either to too much ablation during the first phase of the last glacial cycle or too little ablation during the final phase. We then substituted the standard SEB scheme in CLIMBER-2 with the PDD scheme and performed a suite of fully interactive (online) simulations of the last glacial cycle with different combinations of PDD parameters. The results of these simulations confirmed the results of the offline simulations: no combination of PDD parameters realistically simulates the evolution of the ice sheets during the entire glacial cycle. The use of constant parameter values in the online simulations leads either to a buildup of too much ice volume at the end of glacial cycle or too little ice volume at the beginning. Even when the model correctly simulates global ice volume at the last glacial maximum (21 ka), it is unable to simulate complete deglaciation

  18. Comparison of surface mass balance of ice sheets simulated by positive-degree-day method and energy balance approach

    Directory of Open Access Journals (Sweden)

    E. Bauer

    2017-07-01

    Full Text Available Glacial cycles of the late Quaternary are controlled by the asymmetrically varying mass balance of continental ice sheets in the Northern Hemisphere. Surface mass balance is governed by processes of ablation and accumulation. Here two ablation schemes, the positive-degree-day (PDD method and the surface energy balance (SEB approach, are compared in transient simulations of the last glacial cycle with the Earth system model of intermediate complexity CLIMBER-2. The standard version of the CLIMBER-2 model incorporates the SEB approach and simulates ice volume variations in reasonable agreement with paleoclimate reconstructions during the entire last glacial cycle. Using results from the standard CLIMBER-2 model version, we simulated ablation with the PDD method in offline mode by applying different combinations of three empirical parameters of the PDD scheme. We found that none of the parameter combinations allow us to simulate a surface mass balance of the American and European ice sheets that is similar to that obtained with the standard SEB method. The use of constant values for the empirical PDD parameters led either to too much ablation during the first phase of the last glacial cycle or too little ablation during the final phase. We then substituted the standard SEB scheme in CLIMBER-2 with the PDD scheme and performed a suite of fully interactive (online simulations of the last glacial cycle with different combinations of PDD parameters. The results of these simulations confirmed the results of the offline simulations: no combination of PDD parameters realistically simulates the evolution of the ice sheets during the entire glacial cycle. The use of constant parameter values in the online simulations leads either to a buildup of too much ice volume at the end of glacial cycle or too little ice volume at the beginning. Even when the model correctly simulates global ice volume at the last glacial maximum (21 ka, it is unable to simulate

  19. Elastodynamic Effects of Mass-Balancing: Experimental Investigation of a Four-Bar Linkage

    Directory of Open Access Journals (Sweden)

    Alberto Martini

    2013-01-01

    Full Text Available This paper deals with static balancing of closed-loop mechanisms. The long-term goal of the research is enhancing the performance of parallel robots by means of effective static balancing strategies that take into account the system dynamic behaviour. In this contribution, the influence of mass-balancing on the elastodynamic performance of a four-bar linkage, intended as the simplest example of closed-loop mechanism, is experimentally investigated. The design of the experimental apparatus is discussed and the results of tests on both an unbalanced linkage and its balanced variant are presented. Base-transmitted forces and vibrations are monitored for constant-speed operations and for velocity ramp tests in order to characterize the elastodynamic behaviour of the linkages. The analysis is supported by implementing a flexible multibody model of the experimental apparatus that enhances the interpretation of the experimental data.

  20. Elevation change and remote-sensing mass-balance methods on the Greenland ice sheet

    DEFF Research Database (Denmark)

    Ahlstrøm, Andreas P.; Reeh, Niels; Christensen, Erik Lintz

    The mass balance of the Greenland Ice Sheet is virtually impossible to obtain with traditional ground-based methods alone due to its vast size. It is thus desirable to develop mass-balance methods depending on remote sensing instead and this field has experienced a dramatic development within...... of measured surface elevation change over a 50x50~km part of the western Greenland Ice-Sheet margin near Kangerlussuaq. In this region, the mean observed elevation change has been -0.5~m from 2000 to 2003. However, the change is unevenly distributed with the northern and central part generally in balance...... the last decade. Large amounts of data have been collected from satellite and airborne platforms, yielding surface elevation changes and surface velocity fields. Here we present data from the Greenland Ice-Sheet margin acquired with a new small-scale airborne system, designed for regional high...

  1. Transdermal administration of radiolabelled [14C]rotigotine by a patch formulation: A mass balance trial

    NARCIS (Netherlands)

    Cawello, W.; Wolff, H.M.; Meuling, W.J.A.; Horstmann, R.; Braun, M.

    2007-01-01

    Background and objective: The dopamine agonist rotigotine has been formulated in a silicone-based transdermal system for once-daily administration. The objective of the present study was to characterise the mass balance of rotigotine in humans after administration of a single transdermal patch

  2. Uncertainty analysis on simple mass balance model to calculate critical loads for soil acidity

    Science.gov (United States)

    Harbin Li; Steven G. McNulty

    2007-01-01

    Simple mass balance equations (SMBE) of critical acid loads (CAL) in forest soil were developed to assess potential risks of air pollutants to ecosystems. However, to apply SMBE reliably at large scales, SMBE must be tested for adequacy and uncertainty. Our goal was to provide a detailed analysis of uncertainty in SMBE so that sound strategies for scaling up CAL...

  3. Mass balance studies of iron without the need of subsampling using large sample neutron activation analysis

    NARCIS (Netherlands)

    Yagob Mohamed, T.I.; Bode, P.; van de Wiel, A.; Wolterbeek, H.T.

    Accurate assessments of the iron (Fe) intake from food is mandatory for mass balance studies. The reliability of such assessments is strongly dependent on the representativeness of the analytical test portion and, as such, the quality of the homogenization of the double portions collected. Large

  4. Mass, Energy, Entropy and Exergy Rate Balance in a Ranque-Hilsh Vortex Tube

    Science.gov (United States)

    Carrascal Lecumberri, Edorta; Sala Lizarraga, José María

    2013-01-01

    The objective of this paper is to present a laboratory program designed for the Thermodynamics course offered in the Department of Thermal Engineering at the University of the Basque Country. With reference to one of the examples given in the textbook by Moran, Shapiro, Boettner and Bailey (2012), the balances of mass, energy, entropy and exergy…

  5. High variability of climate and surface mass balance induced by Antarctic ice rises

    NARCIS (Netherlands)

    Lenaerts, Jan; Brown, Joel; van den Broeke, Michiel; Matsuoka, Kenichi; Drews, Reinhard; Callens, Denis; Philippe, Morgane; Gorodetskaya, I.V.; van Meijgaard, E.; Tijm - Reijmer, Catharina; Pattyn, F.; van Lipzig, N.P.M.

    2014-01-01

    Ice rises play key roles in buttressing the neighbouring ice shelves and potentially provide palaeoclimate proxies from ice cores drilled near their divides. Little is known, however, about their influence on local climate and surface mass balance (SMB). Here we combine 12 years (2001–12) of

  6. Mass balance-based plant-wide wastewater treatment plant models ...

    African Journals Online (AJOL)

    2006-07-03

    Jul 3, 2006 ... Mass balance-based plant-wide wastewater treatment plant models – Part 3: Biodegradability of activated sludge organics under anaerobic conditions. GA Ekama*, SW Sötemann and MC Wentzel. Water Research Group, Department of Civil Engineering, University of Cape Town, Rondebosch 7701, Cape, ...

  7. Mass-Balance Constraints on Nutrient Cycling in Tropical Seagrass Beds

    NARCIS (Netherlands)

    Erftemeijer, P.L.A.; Middelburg, J.J.

    1995-01-01

    A relatively simple mass balance model is presented to study the cycling of nutrients (nitrogen and phosphorus) in tropical seagrass beds. The model is based on quantitative data on nutrient availability, seagrass primary production, community oxygen metabolism, seagrass tissue nutrient contents,

  8. Higher surface mass balance of the Greenland ice sheet revealed by high-resolution climate modeling

    NARCIS (Netherlands)

    Ettema, J.|info:eu-repo/dai/nl/304831913; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643; van Meijgaard, E.; van de Berg, W.J.|info:eu-repo/dai/nl/304831611; Bamber, Jonathan L.; Box, J.E.; Bales, R.C.

    2009-01-01

    High-resolution (∼11 km) regional climate modeling shows total annual precipitation on the Greenland ice sheet for 1958–2007 to be up to 24% and surface mass balance up to 63% higher than previously thought. The largest differences occur in coastal southeast Greenland, where the much higher

  9. Biological degradation of 2,4-dichlorophenoxyacetic acid: chloride mass balance in stirred tank reactors.

    OpenAIRE

    Kelly, M. P.; Hallberg, K. B.; Tuovinen, O H

    1989-01-01

    A mass balance was developed for the degradation of 2,4-dichlorophenoxyacetic acid by a mixed culture. Batch culture experiments showed the degradation to be an acid-producing step. Inorganic chloride concentration consistently correlated with the expected value and with base consumption to maintain a constant pH.

  10. Seasonal Ice Mass-Balance Buoys: Adapting Tools to the Changing Arctic

    Science.gov (United States)

    2011-01-01

    challenge for ice mass-balance observations is the objective of this study. An overview of the current IMB design is illustrated in Figure 1. The IMB...Arctic warming through the Fram Strait: oceanic heat transport from 3 years of measurements. J. Geophys. Res., 109(C6), C06026. (10.1029/2003JC001823

  11. Improved representation of East Antarctic surface mass balance in a regional atmospheric climate model

    NARCIS (Netherlands)

    Van Wessem, J. M.; Reijmer, C. H.; Morlighem, M.; Mouginot, J.; Rignot, E.; Medley, B.; Joughin, I.; Wouters, B.; Depoorter, M. A.; Bamber, J. L.; Lenaerts, J. T M; Van De Berg, W. J.; Van Den Broeke, M. R.; Van Meijgaard, E.

    2014-01-01

    This study evaluates the impact of a recent upgrade in the physics package of the regional atmospheric climate model RACMO2 on the simulated surface mass balance (SMB) of the Antarctic ice sheet. The modelled SMB increases, in particular over the grounded ice sheet of East Antarctica (+44Gt a-1),

  12. Virtual Reality-Based Center of Mass-Assisted Personalized Balance Training System

    Directory of Open Access Journals (Sweden)

    Deepesh Kumar

    2018-01-01

    Full Text Available Poststroke hemiplegic patients often show altered weight distribution with balance disorders, increasing their risk of fall. Conventional balance training, though powerful, suffers from scarcity of trained therapists, frequent visits to clinics to get therapy, one-on-one therapy sessions, and monotony of repetitive exercise tasks. Thus, technology-assisted balance rehabilitation can be an alternative solution. Here, we chose virtual reality as a technology-based platform to develop motivating balance tasks. This platform was augmented with off-the-shelf available sensors such as Nintendo Wii balance board and Kinect to estimate one’s center of mass (CoM. The virtual reality-based CoM-assisted balance tasks (Virtual CoMBaT was designed to be adaptive to one’s individualized weight-shifting capability quantified through CoM displacement. Participants were asked to interact with Virtual CoMBaT that offered tasks of varying challenge levels while adhering to ankle strategy for weight shifting. To facilitate the patients to use ankle strategy during weight-shifting, we designed a heel lift detection module. A usability study was carried out with 12 hemiplegic patients. Results indicate the potential of our system to contribute to improving one’s overall performance in balance-related tasks belonging to different difficulty levels.

  13. Improving the Xin'anjiang hydrological model based on mass-energy balance

    Science.gov (United States)

    Fang, Yuan-Hao; Zhang, Xingnan; Corbari, Chiara; Mancini, Marco; Niu, Guo-Yue; Zeng, Wenzhi

    2017-07-01

    Conceptual hydrological models are preferable for real-time flood forecasting, among which the Xin'anjiang (XAJ) model has been widely applied in humid and semi-humid regions of China. Although the relatively simple mass balance scheme ensures a good performance of runoff simulation during flood events, the model still has some defects. Previous studies have confirmed the importance of evapotranspiration (ET) and soil moisture content (SMC) in runoff simulation. In order to add more constraints to the original XAJ model, an energy balance scheme suitable for the XAJ model was developed and coupled with the original mass balance scheme of the XAJ model. The detailed parameterizations of the improved model, XAJ-EB, are presented in the first part of this paper. XAJ-EB employs various meteorological forcing and remote sensing data as input, simulating ET and runoff yield using a more physically based mass-energy balance scheme. In particular, the energy balance is solved by determining the representative equilibrium temperature (RET), which is comparable to land surface temperature (LST). The XAJ-EB was evaluated in the Lushui catchment situated in the middle reach of the Yangtze River basin for the period between 2004 and 2007. Validation using ground-measured runoff data proves that the XAJ-EB is capable of reproducing runoff comparable to the original XAJ model. Additionally, RET simulated by XAJ-EB agreed well with moderate resolution imaging spectroradiometer (MODIS)-retrieved LST, which further confirms that the model is able to simulate the mass-energy balance since LST reflects the interactions among various processes. The validation results prove that the XAJ-EB model has superior performance compared with the XAJ model and also extends its applicability.

  14. Antarctic and Greenland ice sheet mass balance products from satellite gravimetry

    Science.gov (United States)

    Horwath, Martin; Groh, Andreas; Horvath, Alexander; Forsberg, René; Meister, Rakia; Barletta, Valentina R.; Shepherd, Andrew

    2017-04-01

    Because of their important role in the Earth's climate system, ESA's Climate Change Initiative (CCI) has identified both the Antarctic Ice Sheet (AIS) and the Greenland Ice Sheet (GIS) as Essential Climate Variables (ECV). Since respondents of a user survey indicated that the ice sheet mass balance is one of the most important ECV data products needed to better understand climate change, the AIS_cci and the GIS_cci project provide Gravimetric Mass Balance (GMB) products based on satellite gravimetry data. The GMB products are derived from GRACE (Gravity Recovery and Climate Experiment) monthly solutions of release ITSG-Grace2016 produced at TU Graz. GMB basin products (i.e. time series of monthly mass changes for the entire ice sheets and selected drainage basins) and GMB gridded products (e.g. mass balance estimates with a formal resolution of about 50km, covering the entire ice sheets) are generated for the period from 2002 until present. The first GMB product was released in mid 2016. Here we present an extended and updated version of the ESA CCI GMB products, which are freely available through data portals hosted by the projects (https://data1.geo.tu-dresden.de/ais_gmb, http://products.esa-icesheets-cci.org/products/downloadlist/GMB). Since the initial product release, the applied processing strategies have been improved in order to further reduce GRACE errors and to enhance the separation of signals super-imposed to the ice mass changes. While a regional integration approach is used by the AIS_cci project, the GMB products of the GIS_cci project are derived using a point mass inversion. The differences between both approaches are investigated through the example of the GIS, where an alternative GMB product was generated using the regional integration approach implemented by the AIS_cci. Finally, we present the latest mass balance estimates for both ice sheets as well as their corresponding contributions to global sea level rise.

  15. Region-wide glacier mass balances over the Pamir-Karakoram-Himalaya during 1999–2011

    Directory of Open Access Journals (Sweden)

    J. Gardelle

    2013-08-01

    Full Text Available The recent evolution of Pamir-Karakoram-Himalaya (PKH glaciers, widely acknowledged as valuable high-altitude as well as mid-latitude climatic indicators, remains poorly known. To estimate the region-wide glacier mass balance for 9 study sites spread from the Pamir to the Hengduan Shan (eastern Himalaya, we compared the 2000 Shuttle Radar Topography Mission (SRTM digital elevation model (DEM to recent (2008–2011 DEMs derived from SPOT5 stereo imagery. During the last decade, the region-wide glacier mass balances were contrasted with moderate mass losses in the eastern and central Himalaya (−0.22 ± 0.12 m w.e. yr−1 to −0.33 ± 0.14 m w.e. yr−1 and larger losses in the western Himalaya (−0.45 ± 0.13 m w.e. yr−1. Recently reported slight mass gain or balanced mass budget of glaciers in the central Karakoram is confirmed for a larger area (+0.10 ± 0.16 m w.e. yr−1 and also observed for glaciers in the western Pamir (+0.14 ± 0.13 m w.e. yr−1. Thus, the "Karakoram anomaly" should be renamed the "Pamir-Karakoram anomaly", at least for the last decade. The overall mass balance of PKH glaciers, −0.14 ± 0.08 m w.e. yr−1, is two to three times less negative than the global average for glaciers distinct from the Greenland and Antarctic ice sheets. Together with recent studies using ICESat and GRACE data, DEM differencing confirms a contrasted pattern of glacier mass change in the PKH during the first decade of the 21st century.

  16. Mass balance of Greenland and the Canadian Ice Caps from combined altimetry and GRACE inversion

    DEFF Research Database (Denmark)

    Forsberg, René; Simonsen, Sebastian Bjerregaard; Sørensen, Louise Sandberg

    The combination of GRACE and altimetry data may yield a high resolution mass balance time series of the Greenlandice sheet, highlighting the varying individual mass loss behaviour of major glaciers. By including the Canadian arctic ice caps in the estimation, a more reliable estimate of the mass...... loss of both Greenlandand the Canadian ice caps may be obtained, minimizing the leakage errors otherwise unavoidable by GRACE. Actually, the absolute value of the Greenlandice sheet mass loss is highly dependent on methods and how the effects of Arctic Canadian ice caps are separated in the GRACE...... loss of the ice caps and ice sheet basins for the period 2003-15. This period shows a marked increase of ice sheet melt, especially in NW and NE Greenland, but also show large variability, with the melt anomaly year of 2012 showing a record mass loss, followed by 2013 with essentially no Greenland mass...

  17. Establishing mass balance observation at Austre Grønfjordbreen, Nordenskjöld land, Svalbard

    Science.gov (United States)

    Elagina, Nelly; Kutuzov, Stanislav; Chernov, Robert; Lavrentiev, Ivan; Vasilyeva, Tatiana; Mavlyudov, Bulat; Kudikov, Arseny

    2017-04-01

    The Arctic archipelago Svalbard consists of a vast glacierized area which contributes significantly to the sea level rise outside of Greenland and Antarctica due to recent warming. The glaciers of Svalbard have already experienced an unprecedented increase in average summer temperatures, melt periods, and rainfall in late autumn and early summer. Glaciers of the Nordenskjöld land were the subject of glaciological studies conducted through the Soviet scientific program at the Institute of Geography RAS, Moscow starting in the 1960s. However, with the collapse of the Soviet Union glaciological monitoring was stopped in the late 1980s. It was resumed in 2003 with direct observations of winter accumulation and summer melt at a number of glaciers in Nordenskjöld land. However, until now snow pit and stake data were inconsistent and were reported randomly. Recent efforts by the Institute of Geography RAS have been aimed at establishing mass balance observation at Austre Grønfjordbreen (7 km2) located 16 km south of Barentsburg. Starting from 2014 observations have included a new ablation stake network of 15 stakes measured biannually, two automatic weather stations located at the glacier tongue and at the accumulation area, and annual high resolution GPR surveys of snow thickness together with snow pit measurements repeated every spring. Special attention has been paid to the evaluation of refreezing ice and superimposed ice distribution. Active layer (10 m) borehole temperatures are measured annually at stake locations. The obtained mass balance gradients are compared with the geodetic mass balance changes in 1990-2005 and recent Arctic DEM data. Additionally glacier bedrock, polythermal structure and surface topography maps have been completed using GPR data and DGPS measurements. All available satellite imagery has been used to reconstruct the snowline elevation changes from 1986 to 2016. Remarkably almost a total absence of accumulation area has been registered in

  18. Higher-order triangular and tetrahedal finite elements with mass lumping for solving the wave equation.

    NARCIS (Netherlands)

    Chin-Joe-Kong, M.J.S.; Mulder, W.A.; van Veldhuizen, M.

    1999-01-01

    The higher-order finite-element scheme with mass lumping for triangles and tetrahedra is an efficient method for solving the wave equation. A number of lower-order elements have already been found. Here the search for elements of higher order is continued. Elements are constructed in a systematic

  19. Influence of Persistent Wind Scour on the Surface Mass Balance of Antarctica

    Science.gov (United States)

    Das, Indrani; Bell, Robin E.; Scambos, Ted A.; Wolovick, Michael; Creyts, Timothy T.; Studinger, Michael; Fearson, Nicholas; Nicolas, Julien P.; Lenaerts, Jan T. M.; vandenBroeke, Michiel R.

    2013-01-01

    Accurate quantification of surface snow accumulation over Antarctica is a key constraint for estimates of the Antarctic mass balance, as well as climatic interpretations of ice-core records. Over Antarctica, near-surface winds accelerate down relatively steep surface slopes, eroding and sublimating the snow. This wind scour results in numerous localized regions (Antarctica. The scour zones are persistent because they are controlled by bedrock topography. On the basis of our Dome A observations, we develop an empirical model to predict wind-scour zones across the Antarctic continent and find that these zones are predominantly located in East Antarctica. We estimate that approx. 2.7-6.6% of the surface area of Antarctica has persistent negative net accumulation due to wind scour, which suggests that, across the continent, the snow mass input is overestimated by 11-36.5 Gt /yr in present surface-mass-balance calculations.

  20. Monthly solutions of ice sheet mass balance at basin scale – and their associated uncertainties

    DEFF Research Database (Denmark)

    Sørensen, Louise Sandberg; Barletta, Valentina Roberta; Forsberg, René

    2012-01-01

    There are still discrepancies in published ice sheet mass balance results, even between ones based on the same data sets. It can be difficult to conclude from where the discrepancies arise, and it is therefore important to cross calibrate methods, data and models in order to determine the uncerta...... in the behaviour of time series. We compare our GRACE derived regional estimates with independent mass change results based on altimetry data from NASA’s Ice Cloud and land Elevation Satellite.......There are still discrepancies in published ice sheet mass balance results, even between ones based on the same data sets. It can be difficult to conclude from where the discrepancies arise, and it is therefore important to cross calibrate methods, data and models in order to determine...

  1. A spatially resolved estimate of High Mountain Asia glacier mass balances from 2000 to 2016

    Science.gov (United States)

    Brun, Fanny; Berthier, Etienne; Wagnon, Patrick; Kääb, Andreas; Treichler, Désirée

    2017-09-01

    High Mountain Asia hosts the largest glacier concentration outside the polar regions. These glaciers are important contributors to streamflow in one of the most populated areas of the world. Past studies have used methods that can provide only regionally averaged glacier mass balances to assess the glacier contribution to rivers and sea level rise. Here we compute the mass balance for about 92% of the glacierized area of High Mountain Asia using time series of digital elevation models derived from satellite stereo-imagery. We calculate a total mass change of -16.3 +/- 3.5 Gt yr-1 (-0.18 +/- 0.04 m w.e. yr-1) between 2000 and 2016, which is less negative than most previous estimates. Region-wide mass balances vary from -4.0 +/- 1.5 Gt yr-1 (-0.62 +/- 0.23 m w.e. yr-1) in Nyainqentanglha to +1.4 +/- 0.8 Gt yr-1 (+0.14 +/- 0.08 m w.e. yr-1) in Kunlun, with large intra-regional variability of individual glacier mass balances (standard deviation within a region ~0.20 m w.e. yr-1). Specifically, our results shed light on the Nyainqentanglha and Pamir glacier mass changes, for which contradictory estimates exist in the literature. They provide crucial information for the calibration of the models used for projecting glacier response to climatic change, as these models do not capture the pattern, magnitude and intra-regional variability of glacier changes at present.

  2. Reconstructing the mass balance of Brewster Glacier, New Zealand, using MODIS-derived glacier-wide albedo

    Directory of Open Access Journals (Sweden)

    P. Sirguey

    2016-10-01

    Full Text Available In New Zealand, direct measurements of mass balance are sparse due to the inaccessibility of glaciers in the Southern Alps and the logistical difficulties associated with maintaining a mass balance record. In order to explore the benefit of remotely sensed imaging to monitor mass balance in the Southern Alps, this research assesses the relationship between measurements of glacier surface albedo derived from Moderate Resolution Imaging Spectroradiometer (MODIS and mass balance observations using the glaciological method on Brewster Glacier over the 2005–2013 period. We confirm that minimum glacier-wide albedo is a reliable predictor for annual mass balance in this maritime environment (R2 = 0.93. Furthermore, we show that regular monitoring of glacier-wide albedo enables a new metric of winter accumulation to be derived, namely the cumulative winter albedo, which is found to correlate strongly with winter mass balance (R2 = 0.88, thus enabling the reconstruction of separate winter and summer mass balance records. This allows the mass balance record for Brewster Glacier to be extended back to the start of MODIS observations in 2000 and to confirm that the annual balance of Brewster Glacier is largely controlled by summer balance (R2  =  92 %. An application of the extended record is proposed whereby the relationship between mass balance and the photographic record of the end-of-summer snowline altitude is assessed. This allowed the annual balance record of Brewster Glacier to be reconstructed over the period 1977–2013, thus providing the longest record of mass balance for a glacier in New Zealand. Over the 37-year period, our results show that Brewster Glacier gained a significant mass of up to 14.5 ± 2.7 m w.e. by 2007. This gain was offset by a marked shift toward negative balances after 2008, yielding a loss of 5.1 ± 1.2 m w.e., or 35 % of the gain accumulated over the previous 30 years. The good

  3. Reconstructing the mass balance of Brewster Glacier, New Zealand, using MODIS-derived glacier-wide albedo

    Science.gov (United States)

    Sirguey, P. J.; Still, H.; Cullen, N. J.; Dumont, M.; Arnaud, Y.; Conway, J. P.

    2016-12-01

    In New Zealand, direct measurements of mass balance are sparse due to the inaccessibility of glaciers in the Southern Alps and the logistical difficulties associated with maintaining a mass balance record. In order to explore the benefit of remotely sensed imaging to monitor mass balance in the Southern Alps, this research assesses the relationship between measurements of glacier surface albedo derived from MODerate resolution Imaging Spectroradiometer (MODIS) and mass balance observations using the glaciological method on Brewster Glacier over the 2005-2013 period. We confirm that minimum glacier-wide albedo is a reliable predictor for annual mass balance in this maritime environment (R2 = 0.93). Furthermore, we show that regular monitoring of glacier-wide albedo enables a new metric of winter accumulation to be derived, namely the cumulative winter albedo, that is found to correlate strongly with winter mass balance (R2 = 0.88), thus enabling the reconstruction of separate winter and summer mass balance records. This allows the mass balance record for Brewster Glacier to be extended back to the start of MODIS observations in 2000 and to confirm that the annual balance of Brewster Glacier is largely controlled by summer balance (R2 = 92 %). An application of the extended record is proposed whereby the relationship between mass balance and the photographic record of the end-of-summer snowline altitude is assessed. This allowed the annual balance record of Brewster Glacier to be reconstructed over the period 1977-2013, thus providing the longest record of mass balance for a glacier in New Zealand. Over the 37-year period, our results show that Brewster Glacier gained significant mass of up to 14.5 ± 2.7 m w.e. by 2007. This gain was offset by a marked shift toward negative balances after 2008, yielding a loss of 5.1 ± 1.2 m w.e., or 35 % of the gain accumulated over the previous 30 years. The good correspondence between mass balance of Brewster Glacier and the

  4. Mass balances of dissolved gases at river network scales across biomes.

    Science.gov (United States)

    Wollheim, W. M.; Stewart, R. J.; Sheehan, K.

    2016-12-01

    Estimating aquatic metabolism and gas fluxes at broad spatial scales is needed to evaluate the role of aquatic ecosystems in continental carbon cycles. We applied a river network model, FrAMES, to quantify the mass balances of dissolved oxygen at river network scales across five river networks in different biomes. The model accounts for hydrology; spatially varying re-aeration rates due to flow, slope, and water temperature; gas inputs via terrestrial runoff; variation in light due to canopy cover and water depth; benthic gross primary production; and benthic respiration. The model was parameterized using existing groundwater information and empirical relationships of GPP, R, and re-aeration, and was tested using dissolved oxygen patterns measured throughout river networks. We found that during summers, internal aquatic production dominates the river network mass balance of Kings Cr., Konza Prairie, KS (16.3 km2), whereas terrestrial inputs and aeration dominate the network mass balance at Coweeta Cr., Coweeta Forest, NC (15.7 km2). At network scales, both river networks are net heterotrophic, with Coweeta more so than Kings Cr. (P:R 0.6 vs. 0.7, respectively). The river network of Kings Creek showed higher network-scale GPP and R compared to Coweeta, despite having a lower drainage density because streams are on average wider so cumulative benthic surface areas are similar. Our findings suggest that the role of aquatic systems in watershed carbon balances will depend on interactions of drainage density, channel hydraulics, terrestrial vegetation, and biological activity.

  5. Gulkana Glacier, Alaska-Mass balance, meteorology, and water measurements, 1997-2001

    Science.gov (United States)

    March, Rod S.; O'Neel, Shad

    2011-01-01

    The measured winter snow, maximum winter snow, net, and annual balances for 1997-2001 in the Gulkana Glacier basin are determined at specific points and over the entire glacier area using the meteorological, hydrological, and glaciological data. We provide descriptions of glacier geometry to aid in estimation of conventional and reference surface mass balances and descriptions of ice motion to aid in the understanding of the glacier's response to its changing geometry. These data provide annual estimates for area altitude distribution, equilibrium line altitude, and accumulation area ratio during the study interval. New determinations of historical area altitude distributions are given for 1900 and annually from 1966 to 2001. As original weather instrumentation is nearing the end of its deployment lifespan, we provide new estimates of overlap comparisons and precipitation catch efficiency. During 1997-2001, Gulkana Glacier showed a continued and accelerated negative mass balance trend, especially below the equilibrium line altitude where thinning was pronounced. Ice motion also slowed, which combined with the negative mass balance, resulted in glacier retreat under a warming climate. Average annual runoff augmentation by glacier shrinkage for 1997-2001 was 25 percent compared to the previous average of 13 percent, in accordance with the measured glacier volume reductions.

  6. Exploring uncertainty in glacier mass balance modelling with Monte Carlo simulation

    Directory of Open Access Journals (Sweden)

    H. Machguth

    2008-12-01

    Full Text Available By means of Monte Carlo simulations we calculated uncertainty in modelled cumulative mass balance over 400 days at one particular point on the tongue of Morteratsch Glacier, Switzerland, using a glacier energy balance model of intermediate complexity. Before uncertainty assessment, the model was tuned to observed mass balance for the investigated time period and its robustness was tested by comparing observed and modelled mass balance over 11 years, yielding very small deviations. Both systematic and random uncertainties are assigned to twelve input parameters and their respective values estimated from the literature or from available meteorological data sets. The calculated overall uncertainty in the model output is dominated by systematic errors and amounts to 0.7 m w.e. or approximately 10% of total melt over the investigated time span. In order to provide a first order estimate on variability in uncertainty depending on the quality of input data, we conducted a further experiment, calculating overall uncertainty for different levels of uncertainty in measured global radiation and air temperature. Our results show that the output of a well calibrated model is subject to considerable uncertainties, in particular when applied for extrapolation in time and space where systematic errors are likely to be an important issue.

  7. Greenland ice sheet surface mass-balance modeling in a 131-Yr perspective, 1950-2080

    DEFF Research Database (Denmark)

    Mernild, Sebastian H.; Liston, Glen E.; Hiemstra, Christopher A.

    2010-01-01

    Fluctuations in the Greenland ice sheet (GrIS) surface mass balance (SMB) and freshwater influx to the surrounding oceans closely follow climate fluctuations and are of considerable importance to the global eustatic sea level rise.Astate-of-the-art snow-evolution modeling system(SnowModel) was used...... to simulate variations in theGrISmelt extent, surfacewater balance components, changes inSMB, and freshwater influx to the ocean. The simulations are based on the Intergovernmental Panel on Climate Change scenario A1B modeled by the HIRHAM4 regional climate model (RCM) using boundary conditions from the ECHAM...

  8. Adjustment of regional climate model output for modeling the climatic mass balance of all glaciers on Svalbard.

    NARCIS (Netherlands)

    Möller, M.; Obleitner, F.; Reijmer, C.H.; Pohjola, V.A.; Glowacki, P.; Kohler, J.

    2016-01-01

    Large-scale modeling of glacier mass balance relies often on the output from regional climate models (RCMs). However, the limited accuracy and spatial resolution of RCM output pose limitations on mass balance simulations at subregional or local scales. Moreover, RCM output is still rarely available

  9. The spatial and temporal variability of the surface mass balance in Antarctica: results from a regional climate model

    NARCIS (Netherlands)

    Lipzig, N.P.M. van; Meijgaard, E. van; Oerlemans, J.

    2002-01-01

    A 14 year integration with a regional atmospheric model (RACMO) is used to obtain detailed information on the Antarctic surface mass balance and to understand the mechanisms that are responsible for the spatial and temporal distribution of the surface mass balance. The model (Δx = 55 km) uses the

  10. The role of crystallization-driven exsolution on the sulfur mass balance in volcanic arc magmas

    Science.gov (United States)

    Su, Yanqing; Huber, Christian; Bachmann, Olivier; Zajacz, Zoltán; Wright, Heather M.; Vazquez, Jorge A.

    2016-01-01

    The release of large amounts of sulfur to the stratosphere during explosive eruptions affects the radiative balance in the atmosphere and consequentially impacts climate for up to several years after the event. Quantitative estimations of the processes that control the mass balance of sulfur between melt, crystals, and vapor bubbles is needed to better understand the potential sulfur yield of individual eruption events and the conditions that favor large sulfur outputs to the atmosphere. The processes that control sulfur partitioning in magmas are (1) exsolution of volatiles (dominantly H2O) during decompression (first boiling) and during isobaric crystallization (second boiling), (2) the crystallization and breakdown of sulfide or sulfate phases in the magma, and (3) the transport of sulfur-rich vapor (gas influx) from deeper unerupted regions of the magma reservoir. Vapor exsolution and the formation/breakdown of sulfur-rich phases can all be considered as closed-system processes where mass balance arguments are generally easier to constrain, whereas the contribution of sulfur by vapor transport (open system process) is more difficult to quantify. The ubiquitous “excess sulfur” problem, which refers to the much higher sulfur mass released during eruptions than what can be accounted for by amount of sulfur originally dissolved in erupted melt, as estimated from melt inclusion sulfur concentrations (the “petrologic estimate”), reflects the challenges in closing the sulfur mass balance between crystals, melt, and vapor before and during a volcanic eruption. In this work, we try to quantify the relative importance of closed- and open-system processes for silicic arc volcanoes using kinetic models of sulfur partitioning during exsolution. Our calculations show that crystallization-induced exsolution (second boiling) can generate a significant fraction of the excess sulfur observed in crystal-rich arc magmas. This result does not negate the important role of

  11. Simulation and reconstruction of parameters of streamflow and glacier mass balance in the Northern Caucasus

    Directory of Open Access Journals (Sweden)

    V. G. Konovalov

    2014-01-01

    Full Text Available The work was aimed at numerical modeling of spatial-temporal variability of the river Terek seasonal (April to September streamflow characteristics and long-term fluctuations of components of annual glacier mass balances in this basin and on the adjacent territories. Mass balance of glaciers Djankuat and Garabashi was calculated. Simulation was performed by means of stochastic modeling and discrete data presenting fields of main meteorological parameters (precipitation, air temperature and humidity having effect on the streamflow. Realization of this approach is complicated by the fact that spatial representativeness of hydrological and meteorological sites are not corresponding one to another. Data on the runoff is clearly related to the total drainage area closed by a gauging station. And for this data we study a relationship with meteorological parameters which are measured at a non-regular observational network whose spatial representativeness is unknown. These stations are generally located beyond the area under investigation (Fig. 2. Similar problem exists when we analyze a relationship between components of the mass balance of individual glaciers (Djankuat and Garabashi and the above climate characteristics measured at some stations located on the whole Caucasus territory. The same takes place when long-term indices of width and density of tree annual rings obtained in upper reaches of the river Kuban’ are used for analysis of variations of the runoff and the glacier mass balance in the river Terek basin located at a distance of 100-150 km from the Kuban’ dendrologic sites.To solve the problem we used a wide number of factors which directly (various information about the climate or indirectly (indices of the climate dryness, wood ring characteristics characterize conditions of formation of annual and seasonal river runoff and components of glacier mass balance in the North Caucasus. Use of all obtained information made possible the

  12. Size resolved chemical mass balance of aerosol particles over rural Hungary

    Science.gov (United States)

    Temesi, D.; Molnár, A.; Mészáros, E.; Feczkó, T.; Gelencsér, A.; Kiss, G.; Krivácsy, Z.

    The mass size distribution of atmospheric aerosol particles was determined by means of an electric low pressure impactor (ELPI) in rural air in Hungary. The particles captured on different stages of the impactor were chemically analyzed by capillary zone electrophoresis to quantify ionic components as well as by catalytic combustion method to detect total carbon in the samples. The results show that fine aerosol consists mainly of ammonium sulfate and organic carbon. These two species have rather different size distributions since very small particles are composed almost of carbon compounds. The analysis of fine aerosol samples collected simultaneously on filters indicates that an important part of organics is soluble in water. The mass balance of fine particles as a function of their size is estimated by taking into account the liquid water adsorbed by ammonium sulfate and by converting the mass of carbon to the mass of carbon compounds. Finally, the size resolved mass balance of fine aerosol particles is presented and discussed as a function of the origin of air masses.

  13. Reconstructing glacier mass balances in the Central Andes of Chile and Argentina using local and regional hydro-climatic data

    Science.gov (United States)

    Masiokas, M. H.; Christie, D. A.; Le Quesne, C.; Pitte, P.; Ruiz, L.; Villalba, R.; Luckman, B. H.; Berthier, E.; Nussbaumer, S. U.; González-Reyes, A.; McPhee, J.; Barcaza, G.

    2015-09-01

    Despite the great number and variety of glaciers in southern South America, in situ glacier mass balance records are extremely scarce and glacier-climate relationships are still poorly understood in this region. Here we use the longest (> 35 years) and most complete in situ mass balance record, available for glaciar Echaurren Norte in the Andes at ~34° S, to develop a minimal glacier surface mass balance model that relies on nearby monthly precipitation and air temperature data as forcing. This basic model is able to explain 78 % of the variance in the annual glacier mass balance record over the 1978-2013 calibration period. An attribution assessment indicates that precipitation variability constitutes the most important forcing modulating annual glacier mass balances at this site. A regionally-averaged series of mean annual streamflow records from both sides of the Andes is then used to estimate, through simple linear regression, this glacier's annual mass balance variations since 1909. The reconstruction model captures 68 % of the observed glacier mass balance variability and shows three periods of sustained positive mass balances embedded in an overall negative trend totaling almost -42 m w.eq. over the past 105 years. The three periods of sustained positive mass balances (centered in the 1920s-1930s, in the 1980s and in the first decade of the 21st century) coincide with several documented glacier advances in this region. Similar trends observed in other shorter glacier mass balance series suggest the glaciar Echaurren Norte reconstruction is representative of larger-scale conditions and could be useful for more detailed glaciological, hydrological and climatological assessments in this portion of the Andes.

  14. Balancing

    Science.gov (United States)

    Harteveld, Casper

    At many occasions we are asked to achieve a “balance” in our lives: when it comes, for example, to work and food. Balancing is crucial in game design as well as many have pointed out. In games with a meaningful purpose, however, balancing is remarkably different. It involves the balancing of three different worlds, the worlds of Reality, Meaning, and Play. From the experience of designing Levee Patroller, I observed that different types of tensions can come into existence that require balancing. It is possible to conceive of within-worlds dilemmas, between-worlds dilemmas, and trilemmas. The first, the within-world dilemmas, only take place within one of the worlds. We can think, for example, of a user interface problem which just relates to the world of Play. The second, the between-worlds dilemmas, have to do with a tension in which two worlds are predominantly involved. Choosing between a cartoon or a realistic style concerns, for instance, a tension between Reality and Play. Finally, the trilemmas are those in which all three worlds play an important role. For each of the types of tensions, I will give in this level a concrete example from the development of Levee Patroller. Although these examples come from just one game, I think the examples can be exemplary for other game development projects as they may represent stereotypical tensions. Therefore, to achieve harmony in any of these forthcoming games, it is worthwhile to study the struggles we had to deal with.

  15. Biomechanical characterization dismount from balance beam on the basis of the analysis of key elements of sports equipment

    Directory of Open Access Journals (Sweden)

    Potop V.A.

    2013-12-01

    Full Text Available Purpose. Biomechanical analysis of sports performance technology with balance beam dismount. Material, methods. The study involved six young gymnasts aged 12 - 14 years old - the reserve team of Romania. Results. Identified nodal elements of sports equipment dismount from balance beam type flip off rondat and rondat - coup ago somersaults with twists caved at 360°, 540°, 720° and 900°. In the preparatory phase of the motor action performed dismount isolated and studied central element of sports equipment - starting posture of the body in the phase of the main motor action - animation body posture in the final phase of motor actions - the final posture of the body - Sustainable landing. Conclusions. The method of video - computer research dismount from balance beam type flip off rondat and rondat - coup ago, in conjunction with the method of postural orientation movements allow you to perform a detailed biomechanical analysis of the key elements of sports equipment, to develop advanced training programs.

  16. The mass and energy balance of ice within the Eisriesenwelt cave, Austria

    Directory of Open Access Journals (Sweden)

    F. Obleitner

    2011-03-01

    Full Text Available Meteorological measurements were performed in a prominent ice cave (Eisriesenwelt, Austria during a full annual cycle. The data show the basic features of a dynamically ventilated cave system with a well distinguished winter and summer regime.

    The calculated energy balance of the cave ice is largely determined by the input of long-wave radiation originating at the host rock surface. On average the turbulent fluxes withdraw energy from the surface. This is more pronounced during winter due to enhanced circulation and lower humidity. During summer the driving gradients reverse sign and the associated fluxes provide energy for melt.

    About 4 cm of ice were lost at the measurement site during a reference year. This was due to some sublimation during winter, while the major loss resulted from melt during summer. Small amounts of accumulation occurred during spring due to refreezing of seepage water.

    These results are largely based on employing a numerical mass and energy balance model. Sensitivity studies prove reliability of the calculated energy balance regarding diverse measurement uncertainties and show that the annual mass balance of the ice strongly depends on cave air temperature during summer and the availability of seepage water in spring.

  17. Geodetic Mass Balance of the Northern Patagonian Icefield from 2000 to 2012 Using Two Independent Methods

    Directory of Open Access Journals (Sweden)

    Inés Dussaillant

    2018-02-01

    Full Text Available We compare two independent estimates of the rate of elevation change and geodetic mass balance of the Northern Patagonian Icefield (NPI between 2000 (3,856 km2 and 2012 (3,740 km2 from space-borne data. The first is obtained by differencing the Shuttle Radar Topography Mission (SRTM digital elevation model (DEM from February 2000 and a Satellite pour l'Observation de la Terre 5 (SPOT5 DEM from March 2012. The second is deduced by fitting pixel-based linear elevation trends over 118 DEMs calculated from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER stereo images acquired between 2000 and 2012. Both methods lead to similar and strongly negative icefield-wide mass balance rates of −1.02 ± 0.21 and −1.06 ± 0.14 m w.e. yr−1 respectively, which is in agreement with earlier studies. Contrasting glacier responses are observed, with individual glacier mass balance rates ranging from −0.15 to −2.30 m w.e. yr−1 (standard deviation = 0.49 m w.e. yr−1; N = 38. For individual glaciers, the two methods agree within error bars, except for small glaciers poorly sampled in the SPOT5 DEM due to clouds. Importantly, our study confirms the lack of penetration of the C-band SRTM radar signal into the NPI snow and firn except for a region above 2,900 m a.s.l. covering <1% of the total area. Ignoring penetration would bias the mass balance by only 0.005 m w.e. yr−1. A strong advantage of the ASTER method is that it relies only on freely available data and can thus be extended to other glacierized areas.

  18. Quantification of Dialytic Removal and Extracellular Calcium Mass Balance during a Weekly Cycle of Hemodialysis

    OpenAIRE

    Waniewski, Jacek; Debowska, Malgorzata; Wojcik-Zaluska, Alicja; Ksiazek, Andrzej; Zaluska, Wojciech

    2016-01-01

    Objectives The removal of calcium during hemodialysis with low calcium concentration in dialysis fluid is generally slow, and the net absorption of calcium from dialysis fluid is often reported. The details of the calcium transport process during dialysis and calcium mass balance in the extracellular fluid, however, have not been fully studied. Methods Weekly cycle of three dialysis sessions with interdialytic breaks of 2-2-3 days was monitored in 25 stable patients on maintenance hemodialysi...

  19. Geometric changes and mass balance of the Austfonna ice cap, Svalbard

    Directory of Open Access Journals (Sweden)

    G. Moholdt

    2010-01-01

    Full Text Available The dynamics and mass balance regime of the Austfonna ice cap, the largest glacier on Svalbard, deviates significantly from most other glaciers in the region and is not fully understood. We have compared ICESat laser altimetry, airborne laser altimetry, GNSS surface profiles and radio echo-sounding data to estimate elevation change rates for the periods 1983–2007 and 2002–2008. The data sets indicate a pronounced interior thickening of up to 0.5 m y−1, at the same time as the margins are thinning at a rate of 1–3 m y−1. The southern basins are thickening at a higher rate than the northern basins due to a higher accumulation rate. The overall volume change in the 2002–2008 period is estimated to be −1.3±0.5 km3 w.e. y−1 (or −0.16±0.06 m w.e. y−1 where the entire net loss is due to a rapid retreat of the calving fronts. Since most of the marine ice loss occurs below sea level, Austfonna's current contribution to sea level change is close to zero. The geodetic results are compared to in-situ mass balance measurements which indicate that the 2004–2008 surface net mass balance has been slightly positive (0.05 m w.e. y−1 though with large annual variations. Similarities between local net mass balances and local elevation changes indicate that most of the ice cap is slow-moving and not in dynamic equilibrium with the current climate. More knowledge is needed about century-scale dynamic processes in order to predict the future evolution of Austfonna based on climate scenarios.

  20. Mass Balance of Multiyear Sea Ice in the Southern Beaufort Sea

    Science.gov (United States)

    2015-09-30

    key regional processes in southern Beaufort Sea affecting MY ice recruitment 3) Improved predictability of the future states of the Arctic ice pack ...will improve understanding of the fate of multiyear sea ice in an increasingly seasonal ice pack and lead to reduced uncertainty in sea ice forecasting...1 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. Mass Balance of Multiyear Sea Ice in the Southern Beaufort

  1. Relative appendicular skeletal muscle mass is associated with isokinetic muscle strength and balance in healthy collegiate men.

    Science.gov (United States)

    Kim, Sung-Eun; Hong, Ju; Cha, Jun-Youl; Park, Jung-Min; Eun, Denny; Yoo, Jaehyun; Jee, Yong-Seok

    2016-11-01

    There are few studies on the relationship between skeletal muscle mass and balance in the young ages. We investigated the relationship between appendicular skeletal muscle mass, isokinetic muscle strength of lower extremity, and balance among healthy young men using relative skeletal muscle index. Thirty men were grouped according to relative appendicular skeletal muscle mass index: higher skeletal muscle group (n = 15) and lower skeletal muscle group (n = 15). Static and dynamic balance abilities were measured using the following: a test where participants stood on one leg with eyes closed, a modified Clinical Test of Sensory Interaction on Balance (mCTSIB) with eyes open and eyes closed, a stability test, and limits of stability test. The muscle strength of lower extremities was measured with an isokinetic analyser in hip, knee, and ankle joints. Participants with higher appendicular skeletal muscle mass were significantly more stable in maintaining dynamic balance than those with lower appendicular skeletal muscle mass. Moreover, appendicular skeletal muscle mass index was positively correlated with dynamic balance ability. Participants with higher appendicular skeletal muscle mass had stronger strength in the lower extremity, and there were significant differences in the isokinetic torque ratios between groups. From these results, it can be inferred that higher appendicular skeletal muscle mass relates to muscle strength and the alteration in the peak torque ratio of the lower extremity, contributing to the maintenance of balance.

  2. Autonomous Ice Mass Balance Observations for Changing Arctic Sea Ice Conditions

    Science.gov (United States)

    Whitlock, J. D.; Planck, C.; Perovich, D. K.; Richter-Menge, J.; Elder, B. C.; Polashenski, C.

    2016-12-01

    Results from observational data and predictive models agree: the state of the Arctic sea ice cover is in transition with a major shift from thick multiyear ice to thinner seasonal ice. The ice mass-balance represents the integration of all surface and ocean heat fluxes, and frequent temporal measurement can aid in attributing the impact of these forcing fluxes on the ice cover. Autonomous Ice Mass Balance buoys (IMB's) have proved to be important measurement tools allowing in situ, long-term data collection at multiple locations. Seasonal IMB's (SIMB's) are free floating versions of the IMB that allow data collection in thin ice and during times of transition. To accomplish this a custom computer was developed to integrate the scientific instruments, power management, and data communications while providing expanded autonomous functionality. This new design also allows for the easy incorporation of other sensors. Additionally, the latest generation of SIMB includes improvements to make it more stable, longer lasting, easier to deploy, and less expensive. Models can provide important insights as to where to deploy the sea ice mass balance buoys and what measurements are the most important. The resulting dataset from the buoys can be used to inform and assess model results.

  3. Long term mass balance of the Helheim and Kangerdlugssuaq glaciers in

    DEFF Research Database (Denmark)

    Khan, Shfaqat Abbas; Fitzner, Antje; Kjær, Kurt

    2013-01-01

    Observations over the past decade show huge ice loss associated with speeding up of glaciers in southeast Greenland in 2003, followed by a deceleration in 2006. These short-term episodic dynamic perturbations have a major impact on the mass balance at decadal scale. However, to improve the projec......Observations over the past decade show huge ice loss associated with speeding up of glaciers in southeast Greenland in 2003, followed by a deceleration in 2006. These short-term episodic dynamic perturbations have a major impact on the mass balance at decadal scale. However, to improve...... the projection of future sea level rise, a long-term data record that reveals the mass balance between episodic events is required. Here, we extend the observational record of marginal thinning of Helheim glacier (HG) and Kangerdlugssuaq glacier (KG) from 7 to 30 years. Our measurements reveal that, although...... in air temperature suggest that both outlet glaciers respond immediately to small fluctuations in both the SST and air temperature. Furthermore, we compare our observations of ice flow speed and elevation changes with predictions based on the The Parallel Ice Sheet Model (PISM) software....

  4. Mass Balance of Perfluorinated Alkyl Acids in a Pristine Boreal Catchment.

    Science.gov (United States)

    Filipovic, Marko; Laudon, Hjalmar; McLachlan, Michael S; Berger, Urs

    2015-10-20

    Mass balances of ten individual perfluorinated alkyl acids (PFAAs) in two nested pristine catchments in Northern Sweden with different sizes and hydrological functions were assembled for 2011-2012. Concentrations of PFAAs in rain and snowmelt, as well as in streamwater at the outlet of the two watersheds were measured and used to calculate PFAA atmospheric inputs to and riverine outputs from the catchments. The results generally showed a great excess of PFAA inputs for both catchments over the whole study year. However, during the spring flood period, the inputs and outputs were within a factor of 2 for several PFAAs and the streamwater showed PFAA patterns resembling the patterns in rain (as opposed to snowmelt), suggesting that snowmelt water infiltrating the ground had displaced water from the previous summer. Comparison of PFAA mass balances between the two catchments further suggested that atmospheric inputs of short-chain (replacement) perfluoroalkyl carboxylic acids had increased in the years before sampling, while inputs of the legacy perfluorooctane sulfonic acid had decreased. Overall, the mass balances indicate that a considerable portion of the PFAAs deposited from the atmosphere are stored in soil and may be released to surface and marine water environments in the future.

  5. Relation between mass balance aperture and hydraulic properties from field experiments in fractured rock in Sweden

    Science.gov (United States)

    Hjerne, Calle; Nordqvist, Rune

    2014-09-01

    Results from tracer tests are often used to infer connectivity and transport properties in bedrock. However, the amount of site-specific data from tracer tests is often very limited, while data from hydraulic tests are more abundant. It is therefore of great interest for predictive transport modeling to use hydraulic data to infer transport properties. In this study, data from cross-hole tracer tests carried out in crystalline bedrock in Sweden were compiled and analysed. The tests were performed within investigations made by the Swedish Nuclear Fuel and Waste Management Company (SKB) between 1978 and 2009 at five different locations. An empirical relationship between mass balance aperture and transmissivity was found and quantified by using 74 observations. The empirical relationship deviates considerably from the cubic law aperture, as mass balance aperture is found to be at least one order of magnitude larger than cubic law aperture. Hence, usage of cubic law aperture, derived from hydraulic testing, for transport predictions is unsuitable, as the advective transport time will be considerably underestimated. Another result, from the data set studied, is that mass balance aperture appears to correlate better to apparent storativity than to transmissivity.

  6. Extending Penning trap mass measurements with SHIPTRAP to the heaviest elements

    Energy Technology Data Exchange (ETDEWEB)

    Block, M.; Ackermann, D.; Herfurth, F.; Hofmann, S. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Blaum, K. [Max-Planck-Institut fuer Kernphysik, 69117 Heidelberg, Germany and Ruprecht-Karls-Universitaet, 69120 Heidelberg (Germany); Droese, C.; Marx, G.; Schweikhard, L. [Ernst-Moritz-Arndt-Universitaet, 17487 Greifswald (Germany); Duellmann, Ch. E. [Johannes Gutenberg-Universitaet, 55099 Mainz, Germany and GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt, Germany and Helmholtz-Institut Mainz, 55099 Mainz (Germany); Eibach, M. [Ruprecht-Karls-Universitaet, 69120 Heidelberg, Germany and Johannes Gutenberg-Universitaet, 55099 Mainz (Germany); Eliseev, S. [Max-Planck-Institut fuer Kernphysik, 69117 Heidelberg (Germany); Haettner, E.; Plass, W. R.; Scheidenberger, C. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt, Germany and Justus-Liebig-Universitaet, 35392 Giessen (Germany); Hessberger, F. P. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt, Germany and Helmholtz-Institut Mainz, 55099 Mainz (Germany); Ramirez, E. Minaya [Helmholtz-Institut Mainz, 55099 Mainz, Germany and GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Nesterenko, D. [Petersburg Nuclear Physics Institute, Gatchina, 188300 St. Petersburg (Russian Federation); and others

    2013-03-19

    Penning-trap mass spectrometry of radionuclides provides accurate mass values and absolute binding energies. Such mass measurements are sensitive indicators of the nuclear structure evolution far away from stability. Recently, direct mass measurements have been extended to the heavy elements nobelium (Z=102) and lawrencium (Z=103) with the Penning-trap mass spectrometer SHIPTRAP. The results probe nuclear shell effects at N=152. New developments will pave the way to access even heavier nuclides.

  7. Glacier albedo decrease in the European Alps: potential causes and links with mass balances

    Science.gov (United States)

    Di Mauro, Biagio; Julitta, Tommaso; Colombo, Roberto

    2016-04-01

    Both mountain glaciers and polar ice sheets are losing mass all over the Earth. They are highly sensitive to climate variation, and the widespread reduction of glaciers has been ascribed to the atmospheric temperature increase. Beside this driver, also ice albedo plays a fundamental role in defining mass balance of glaciers. In fact, dark ice absorbs more energy causing faster glacier melting, and this can drive to more negative balances. Previous studies showed that the albedo of Himalayan glaciers and the Greenland Ice Sheet is decreasing with important rates. In this contribution, we tested the hypothesis that also glaciers in the European Alps are getting darker. We analyzed 16-year time series of MODIS (MODerate resolution Imaging Spectrometer) snow albedo from Terra (MOD13A1, 2000-2015) and Aqua (MYD13A1, 2002-2015) satellites. These data feature a spatial resolution of 500m and a daily temporal resolution. We evaluated the existence of a negative linear and nonlinear trend of the summer albedo values both at pixel and at glacier level. We also calculated the correlation between MODIS summer albedo and glacier mass balances (from the World Glaciological Monitoring Service, WGMS database), for all the glaciers with available mass balance during the considered period. In order to estimate the percentage of the summer albedo that can be explained by atmospheric temperature, we correlated MODIS albedo and monthly air temperature extracted from the ERA-Interim reanalysis dataset. Results show that decreasing trends exist with a strong spatial variability in the whole Alpine chain. In large glaciers, such as the Aletch (Swiss Alps), the trend varies significantly also within the glacier, showing that the trend is higher in the area across the accumulation and ablation zone. Over the 17 glaciers with mass balance available in the WGMS data set, 11 gave significant relationship with the MODIS summer albedo. Moreover, the comparison between ERA-Interim temperature

  8. Active tuned mass damper in vehicles. Integrated mass and energy balance; Mechatronische Schwingungstilger in Fahrzeugen. Ganzheitliche Massen- und Energiebilanz

    Energy Technology Data Exchange (ETDEWEB)

    Granzow, Sebastian

    2012-04-02

    The number of mechatronic automotive applications is growing rapidly and becoming more and more important. On the other hand, the automotive industry is faced with the ambitious challenge to significantly reduce CO{sub 2}-emissions. The vehicle mass is as a part of the driving resistance is a starting point. New innovative approaches are required for lightweight constructions. Taking the two aspects together, this leads inevitably to the question: Is it possible to support automotive lightweight construction by using mechatronic systems? The Mechatronic vibration absorber is a combination of a mechanical oscillating system with an electronically controllable force component. This allows a broadband and situation-dependent influence of vehicle vibration behavior. Mechatronic vibration absorbers are suitable to compensate a loss of riding comfort due to a reduction of the body mass. Essential for this is a multidisciplinary simulation environment. The mechatronic vibration absorber, including appropriate control systems, the nonlinear chassis and the elastic body characteristics, inclusive of mutual interactions are mapped in the simulation environment Matlab. In addition to the representation of the oscillating vehicle the determination of the total energy requirements is necessary. To achieve a CO{sub 2}-reduction target, the overall energy balance of lightweight and the electrical vibration absorber energy, which is offered by the vehicle, is required. The question of the real vibration absorber energy needs to be discussed in the context of the individual driving behavior. Ultimately, the overall energy balance is inherently dependent of the individual driving behavior.

  9. A comprehensive energy and mass balance firn model for simulations over multiple glacial cycles

    Science.gov (United States)

    Imhof, Michael; Born, Andreas; Stocker, Thomas

    2017-04-01

    We present a fast yet physically comprehensive glacier surface mass balance model capable of simulations that cover the entire Northern Hemisphere over several glacial cycles. Fluxes of energy and mass are calculated between the atmosphere and a multilayer snow cover, including internal processes like densification and water percolation as well as snow and ice melt. The model is especially designed to provide upper boundary conditions to force ice sheet models on time scales of up to 106 years. To achieve a high numerical efficiency, the model employs a variable time stepping scheme on the grid point level and a Lagrangian grid attached to the snow mass. The input variables are short wave radiation, air temperature and precipitation with half-weekly or daily time steps. This new surface mass balance model has been tested in extensive ensemble simulations and yields realistic representations of present-day ice sheets. The extent of the intra-annual snow cover on the Northern Hemisphere correlates temporally and spatially well with satellite measurements. Perennial firn aquifers are simulated realistically in Greenland and the simulated densification and snow temperature at two bore hole sites in central Greenland yield promising results.

  10. BALANCED SCORECARDS EVALUATION MODEL THAT INCLUDES ELEMENTS OF ENVIRONMENTAL MANAGEMENT SYSTEM USING AHP MODEL

    Directory of Open Access Journals (Sweden)

    Jelena Jovanović

    2010-03-01

    Full Text Available The research is oriented on improvement of environmental management system (EMS using BSC (Balanced Scorecard model that presents strategic model of measurem ents and improvement of organisational performance. The research will present approach of objectives and environmental management me trics involvement (proposed by literature review in conventional BSC in "Ad Barska plovi dba" organisation. Further we will test creation of ECO-BSC model based on business activities of non-profit organisations in order to improve envir onmental management system in parallel with other systems of management. Using this approach we may obtain 4 models of BSC that includ es elements of environmen tal management system for AD "Barska plovidba". Taking into acc ount that implementation and evaluation need long period of time in AD "Barska plovidba", the final choice will be based on 14598 (Information technology - Software product evaluation and ISO 9126 (Software engineering - Product quality using AHP method. Those standards are usually used for evaluation of quality software product and computer programs that serve in organisation as support and factors for development. So, AHP model will be bas ed on evolution criteria based on suggestion of ISO 9126 standards and types of evaluation from two evaluation teams. Members of team & will be experts in BSC and environmental management system that are not em ployed in AD "Barska Plovidba" organisation. The members of team 2 will be managers of AD "Barska Plovidba" organisation (including manage rs from environmental department. Merging results based on previously cr eated two AHP models, one can obtain the most appropriate BSC that includes elements of environmental management system. The chosen model will present at the same time suggestion for approach choice including ecological metrics in conventional BSC model for firm that has at least one ECO strategic orientation.

  11. Energy and mass balance in the three-phase interstellar medium

    Science.gov (United States)

    Wang, Zhong; Cowie, Lennox L.

    1988-01-01

    Details of the energy and mass balances are considered in the context of a three-phase interstellar medium. The rates of mass exchange between the different phases are derived based on the pressure variations created by supernova remnant expansions. It is shown that the pressure-confined warm and cold gases have stable temperatures under a variety of interstellar conditions. The three-phase quasi-static configuration is found to be a natural outcome, and both warm and cold phases generally contribute about half of the total mass density to the diffuse interstellar gas. The model is also likely to be self-regulatory in the sense that variations of the input parameters do not strongly alter the general result, which is consistent with most current observations. The consequences of extreme conditions on this model are considered, and the possible implications for interstellar medium in other galaxies are briefly discussed.

  12. Reassessment of the mass balance of the Abbot and Getz sectors of West Antarctica

    Science.gov (United States)

    Chuter, Stephen; Martín-Español, Alba; Wouters, Bert; Bamber, Jonathan

    2017-04-01

    Large discrepancies exist in mass balance estimates for the Getz and Abbot drainage basins, primarily due to previous poor knowledge of ice thickness at the grounding line, poor coverage by previous altimetry missions and signal leakage issues for GRACE. This is particularly the case for the Abbot region, where previously there have been contrasting positive ice sheet basin elevation rates from altimetry and negative mass budget estimates. Large errors arise when using ice thickness measurements derived from ERS-1 and/or ICESat altimetry data due to poor track spacing, 'loss of lock' issues near the grounding line and the complex morphology of these shelves, requiring fine resolution to derive robust and accurate elevations close to the grounding line. This was exemplified with the manual adjustments of up to 100 m required at the grounding line during the creation of Bedmap2. However, the advent of CryoSat-2 with its unique orbit and SARIn mode of operation has overcome these issues and enabled the determination of ice shelf thickness at a much higher accuracy than possible from previous satellites, particularly within the grounding zone. We present a reassessment of mass balance estimates for the 2007-2009 epoch using improved CryoSat-2 ice thicknesses. We find that CryoSat-2 ice thickness estimates are systematically thinner by 30% and 16.5% for the Abbot and Getz sectors respectively. Our new mass balance estimate of 8 ± 6 Gt yr-1for the Abbot region resolves the previous discrepancy with altimetry. Over the Getz region, the new mass balance estimate of 7.56 ± 16.6 Gt yr-1is in better agreement with other geodetic techniques. We also find there has been an increase in grounding line velocity of up to 20% since the 2007-2009 epoch, coupled with mean ice sheet thinning rates of -0.67 ± 0.13 m yr-1 derived from CryoSat-2 in fast flow regions. This is in addition to mean snowfall trends of -0.33 m yr-1w.e. since 2006. This suggests the onset of a dynamic

  13. Mass balance of arsenic fluxes in rivers impacted by gold mining activities in Paracatu (Minas Gerais State, Brazil).

    Science.gov (United States)

    Bidone, Edison; Cesar, Ricardo; Santos, Maria Carla; Sierpe, Ricardo; Silva-Filho, Emmanuel Vieira; Kutter, Vinicius; Dias da Silva, Lílian I; Castilhos, Zuleica

    2018-01-16

    Arsenic (As) is a dangerous and carcinogenic element and drinking water is its main pathway of human exposure. Gold mines are widely recognized as important sources of As pollution. This work proposes the assessment of As distribution along watersheds surrounding "Morro do Ouro" gold mine (Paracatu, southeastern Brazil). A balance approach between filtered As fluxes (As  0.1 μm, colloidal  10 kDa, dissolved  1 kDa, and truly dissolved remediation. The mass balance indicated the occurrence of a decreasing gradient from upstream to downstream: (i) of the As concentrations higher than the limit established by Brazilian law (10 μg L-1); (ii) of the ratio between specific fluxes (g As km-2 day-1) and those determined using an uncontaminated watershed (a proxy for estimating the anthropic contribution), from 103 to 101; (iii) of the specific fluxes As  0.1 μm) was almost one order higher to dissolved load (< 1 kDa).

  14. Modeling and experimental validation of water mass balance in a PEM fuel cell stack

    DEFF Research Database (Denmark)

    Liso, Vincenzo; Araya, Samuel Simon; Olesen, Anders Christian

    2016-01-01

    management in PEM fuel cell is crucial in order to avoid an imbalance between water production and water removal from the fuel cell. In the present study, a novel mathematical zero-dimensional model has been formulated for the water mass balance and hydration of a polymer electrolyte membrane. This model...... is validated against experimental data. In the results it is shown that the fuel cell water balance calculated by this model shows better fit with experimental data-points compared with model where only steady state operation were considered. We conclude that this discrepancy is due a different rate of water......Polymer electrolyte membrane (PEM) fuel cells require good hydration in order to deliver high performance and ensure long life operation. Water is essential for proton conductivity in the membrane which increases by nearly six orders of magnitude from dry to fully hydrated. Adequate water...

  15. HUMAN MASS BALANCE STUDY OF TAS-102 USING 14C ANALYZED BY ACCELERATOR MASS SPECTROMETRY

    Science.gov (United States)

    Lee, James J.; Seraj, Jabed; Yoshida, Kenichiro; Mizuguchi, Hirokazu; Strychor, Sandra; Fiejdasz, Jillian; Faulkner, Tyeler; Parise, Robert A.; Fawcett, Patrick; Pollice, Laura; Mason, Scott; Hague, Jeremy; Croft, Marie; Nugteren, James; Tedder, Charles; Sun, Weijing; Chu, Edward; Beumer, Jan Hendrik

    2016-01-01

    Background TAS-102 is an oral fluoropyrimidine prodrug composed of trifluridine (FTD) and tipiracil hydrochloride (TPI) in a 1:0.5 ratio. FTD is a thymidine analog, and it is degraded by thymidine phosphorylase (TP) to the inactive trifluoromethyluracil (FTY) metabolite. TPI inhibits degradation of FTD by TP, increasing systemic exposure to FTD. Methods Patients with advanced solid tumors (6 M/2 F; median age 58 years; PS 0–1) were enrolled on this study. Patients in group A (N = 4) received 60 mg TAS-102 with 200 nCi [14C]-FTD, while patients in group B (N = 4) received 60 mg TAS-102 with 1000 nCi [14C]-TPI orally. Plasma, blood, urine, feces, and expired air (group A only) were collected up to 168 h, and were analyzed for 14C by accelerator mass spectrometry and analytes by LC-MS/MS. Results FTD: 59.8% of the 14C dose was recovered; 54.8% in urine mostly as FTY and FTD glucuronide isomers. The extractable radioactivity in the pooled plasma consisted of 52.7% FTD and 33.2% FTY. TPI: 76.8% of the 14C dose was recovered; 27.0% in urine mostly as TPI, and 49.7% in feces. The extractable radioactivity in the pooled plasma consisted of 53.1% TPI and 30.9% 6-HMU, the major metabolite of TPI. Conclusion Absorbed 14C-FTD was metabolized and mostly excreted in urine. The majority of 14C-TPI was recovered in feces, and the majority of absorbed TPI was excreted in urine. The current data with the ongoing hepatic and renal dysfunction studies will provide an enhanced understanding of the TAS-102 elimination profile. PMID:26787503

  16. Glacier Mass Balance in the Cordillera Vilcanota, Glacier Suyuparina, Cusco - Peru

    Science.gov (United States)

    Sikos, Felipe; Giráldez, Claudia; Schauwecker, Simone; Molina, Edwin; Haeberli, Wilfried; Drenkhan, Fabian; Salzmann, Nadine; Rado, Maxwell; Chaparro, Nicacio; Samata, Jaime; Flores, Andrés; Saito, Carlos; Montoya, Nilton

    2017-04-01

    The Cordillera Vilcanota is the second most glaciated mountain range in Peru, and concentrates approximately 279 km2 of ice extent which corresponds to 25% of Peruvian glaciers. These glaciers have shrunk about 33% within the last 40 years and are a direct indicator of climate change impacts. Hydroclimatic changes in this region pose hazards and consecutive risks for local and regional livelihoods, socioeconomic activities and water supply. Therefore, it is important to understand high-mountain climatic and hydroglacial parameters and dynamics. In 2010/11, the first mass balance measurements were made on the Suyuparina glacier and the adjacent Quisoquipina glacier. In 2013, we have continued measurements through the present, of which we present some of the results for Suyuparina glacier. The net point mass balance for the hydrological year 2013-2014 in the lower zone is highly variable with values between +0.2 m w.e. (accumulation) and up to -6 m w.e. (ablation).; whereas for the hydrological year 2014-2015 values range from +0.004 m w.e. (accumulation) to -0.047 m w.e. (ablation) depending on the particular microtopography (e.g. ice cliffs) of the glacier. In the accumulation zone, the average for two stakes was +1.4 m w.e. for the hydrological year 2012-2013 and 1.3 m w.e.,in 2013-2014, +1.2 m w.e. for 2014-2015; and +0.7 m w.e in 2015-2016, respectively. The water equivalent gain has been gradually reduced in the last estimate, depending exclusively on the rainfall regime. The velocity of the glacial flow from October 2013 to November 2014 is in the range of 10 to 20 m per year. The glacier retreat in the front corresponds to 48.49 m for the period 2010-2014. Total glacier area of Suyuparina has decreased by 7% from about 1.21 km2 in 2009 to 1.13 km2 in 2013. A seasonal pattern can be observed in the point mass balance, indicating less ablation in the wet season (December-May), continuous ablation in the dry period, and a high horizontal ablation due to its

  17. Surface Energy and Mass Balance Model for Greenland Ice Sheet and Future Projections

    Science.gov (United States)

    Liu, Xiaojian

    The Greenland Ice Sheet contains nearly 3 million cubic kilometers of glacial ice. If the entire ice sheet completely melted, sea level would raise by nearly 7 meters. There is thus considerable interest in monitoring the mass balance of the Greenland Ice Sheet. Each year, the ice sheet gains ice from snowfall and loses ice through iceberg calving and surface melting. In this thesis, we develop, validate and apply a physics based numerical model to estimate current and future surface mass balance of the Greenland Ice Sheet. The numerical model consists of a coupled surface energy balance and englacial model that is simple enough that it can be used for long time scale model runs, but unlike previous empirical parameterizations, has a physical basis. The surface energy balance model predicts ice sheet surface temperature and melt production. The englacial model predicts the evolution of temperature and meltwater within the ice sheet. These two models can be combined with estimates of precipitation (snowfall) to estimate the mass balance over the Greenland Ice Sheet. We first compare model performance with in-situ observations to demonstrate that the model works well. We next evaluate how predictions are degraded when we statistically downscale global climate data. We find that a simple, nearest neighbor interpolation scheme with a lapse rate correction is able to adequately reproduce melt patterns on the Greenland Ice Sheet. These results are comparable to those obtained using empirical Positive Degree Day (PDD) methods. Having validated the model, we next drove the ice sheet model using the suite of atmospheric model runs available through the CMIP5 atmospheric model inter-comparison, which in turn built upon the RCP 8.5 (business as usual) scenarios. From this exercise we predict how much surface melt production will increase in the coming century. This results in 4-10 cm sea level equivalent, depending on the CMIP5 models. Finally, we try to bound melt water

  18. Balance Mass Flux and Velocity Across the Equilibrium Line in Ice Drainage Systems of Greenland

    Science.gov (United States)

    Zwally, H. Jay; Giovinetto, Mario B.; Koblinsky, Chester J. (Technical Monitor)

    2001-01-01

    Estimates of balance mass flux and the depth-averaged ice velocity through the cross-section aligned with the equilibrium line are produced for each of six drainage systems in Greenland. (The equilibrium line, which lies at approximately 1200 m elevation on the ice sheet, is the boundary between the area of net snow accumulation at higher elevations and the areas of net melting at lower elevations around the ice sheet.) Ice drainage divides and six major drainage systems are delineated using surface topography from ERS (European Remote Sensing) radar altimeter data. The net accumulation rate in the accumulation zone bounded by the equilibrium line is 399 Gt/yr and net ablation rate in the remaining area is 231 Gt/yr. (1 GigaTon of ice is 1090 kM(exp 3). The mean balance mass flux and depth-averaged ice velocity at the cross-section aligned with the modeled equilibrium line are 0.1011 Gt kM(exp -2)/yr and 0.111 km/yr, respectively, with little variation in these values from system to system. The ratio of the ice mass above the equilibrium line to the rate of mass output implies an effective exchange time of approximately 6000 years for total mass exchange. The range of exchange times, from a low of 3 ka in the SE drainage system to 14 ka in the NE, suggests a rank as to which regions of the ice sheet may respond more rapidly to climate fluctuations.

  19. Mass balance measurements in the Søndre Strømfjord area in the period 1990-1994

    NARCIS (Netherlands)

    Wal, R.S.W. van de; Bintanja, R.; Boot, W.; Broeke, M.R. van den; Conrads, L.A.; Duynkerke, P.G.; Fortuin, P.; Henneken, E.A.C.; Knap, W.; Portanger, M.; Vugts, H.F.; Oerlemans, J.

    1995-01-01

    We present four years of mass balance measurements for a transcct in the ablation zone of the Greenland ice sheet (near Sondre Stromfjord, West Greenland). The measurements cover an altitude range of 337 to 1524 m. The mean equilibrium line-altitudc is found to be 1424 m. The largcst balance

  20. Sensitivity of Greenland Ice Sheet surface mass balance to surface albedo parameterization: a study with a regional climate model

    National Research Council Canada - National Science Library

    van Angelen, J.H; Lenaerts, J.T.M; Lhermitte, S; Fettweis, X; Kuipers Munneke, P; van den Broeke, M.R; van Meijgaard, E; Smeets, C.J.P.P

    2012-01-01

    We present a sensitivity study of the surface mass balance (SMB) of the Greenland Ice Sheet, as modeled using a regional atmospheric climate model, to various parameter settings in the albedo scheme...

  1. Mass balance modeling to elucidate historical and continuing sources of dioxin into an urban estuary.

    Science.gov (United States)

    Rifai, Hanadi S; Lakshmanan, Divagar; Suarez, Monica P

    2013-09-01

    Polychlorinated dibenzo-p-dioxins and dibenzofurans (dioxins) are typically found in sediment, water and tissue as in the case of the Houston Ship Channel and Upper Galveston Bay (HSC-UGB) in Texas studied in this research. While hydrodynamic and fate and transport models are important to understand dioxin distribution in the various media, it is difficult to assimilate modeling results into a decision framework without appropriate tools that can aid in the interpretation of the simulated data. This paper presents the development of a mass-balance modeling tool linked to RMA2 and WASP models of the HSC-UGB system for 2002-2005. The mass-balance tool was used to aggregate modeling results spatially and temporally and estimate the relative contribution of sediments to dioxin loading into the Channel in comparison to runoff, deposition, and permitted effluent discharges. The total sediment associated-dioxin load into the system calculated using the mass balance model was 2.34 × 10(7) ng d(-1) (almost 86% of the toxic equivalent load), and the re-deposited load to the sediment from the water column was 1.48 × 10(7)ng-TEQd(-1), such that 8.6 × 10(6)ng-TEQ d(-1) or approximately 69% of the average daily dioxin flux is transported between model segments as sediment. The external loads to the system contribute approximately 3.83 × 10(6)ng-TEQ d(-1), a value that is an order of magnitude smaller when compared to the contribution from sediment. These findings point to the need for sediment remediation strategies that take into account the spatial locations within the system that serve as sediment sources to dioxin in the water column. Copyright © 2013 Elsevier Ltd. All rights reserved.

  2. Impact of Air Temperature Distributed Calculation in Glacier Mass Balance Modeling

    Science.gov (United States)

    Dalla Fontana, G.; Carturan, L.; Cazorzi, F.

    2014-12-01

    Distributed models of snow and ice mass balance enable a better understanding of processes involved in glacier hydrology and the prediction of glacier runoff under possible future climatic scenarios. The so-called 'Enhanced Temperature-Index' (ETI) melt models are a good compromise between model simplicity, parsimony of input data, and the capability to account for dominant processes in snow and ice mass balance. Accurate spatial calculation of temperature input data is crucial, given the key role of air temperature in modeling ablation and accumulation processes, further emphasized in ETI models. Compared to ambient conditions, lower temperatures (the so-called glacier cooling effect), and temperature variability (the so-called glacier damping effect) generally occur over glaciers, complicating the extrapolation from off-glacier weather stations. A comprehensive dataset of mass balance measurements and high-altitude meteorological observations was collected on La Mare and Careser glaciers (Ortles-Cevedale, Italian Alps) in 2010 and 2011. This dataset was used to analyze the air temperature distribution and wind regime over the glaciers, and to evaluate the impact of different calculation methods proposed in the literature for calculating on-glacier temperatures from off-glacier data. A general-purpose ETI model (EISModel - Energy Index Snow-and-ice Model) was used for simulating snow and ice accumulation and melt processes. Results indicate that i) none of the existing methods fully accounts for the actual temperature distribution over glaciers, ii) even small deviations in air temperature calculations strongly impact the simulations, and iii) there is an important positive feedback related to glacier shrinking and disintegration. Among the tested methods, the more physically-based procedure of Greuell and Bohm (1998) provided the best overall results. Therefore, it was implemented in EISModel for distributed air temperature calculations over glaciers.

  3. NETPATH-WIN: an interactive user version of the mass-balance model, NETPATH

    Science.gov (United States)

    El-Kadi, A. I.; Plummer, L.N.; Aggarwal, P.

    2011-01-01

    NETPATH-WIN is an interactive user version of NETPATH, an inverse geochemical modeling code used to find mass-balance reaction models that are consistent with the observed chemical and isotopic composition of waters from aquatic systems. NETPATH-WIN was constructed to migrate NETPATH applications into the Microsoft WINDOWS® environment. The new version facilitates model utilization by eliminating difficulties in data preparation and results analysis of the DOS version of NETPATH, while preserving all of the capabilities of the original version. Through example applications, the note describes some of the features of NETPATH-WIN as applied to adjustment of radiocarbon data for geochemical reactions in groundwater systems.

  4. Evaluation of total phosphorus mass balance in the lower Boise River and selected tributaries, southwestern Idaho

    Science.gov (United States)

    Etheridge, Alexandra B.

    2013-01-01

    he U.S. Geological Survey (USGS), in cooperation with Idaho Department of Environmental Quality, developed spreadsheet mass-balance models for total phosphorus using results from three synoptic sampling periods conducted in the lower Boise River watershed during August and October 2012, and March 2013. The modeling reach spanned 46.4 river miles (RM) along the Boise River from Veteran’s Memorial Parkway in Boise, Idaho (RM 50.2), to Parma, Idaho (RM 3.8). The USGS collected water-quality samples and measured streamflow at 14 main-stem Boise River sites, two Boise River north channel sites, two sites on the Snake River upstream and downstream of its confluence with the Boise River, and 17 tributary and return-flow sites. Additional samples were collected from treated effluent at six wastewater treatment plants and two fish hatcheries. The Idaho Department of Water Resources quantified diversion flows in the modeling reach. Total phosphorus mass-balance models were useful tools for evaluating sources of phosphorus in the Boise River during each sampling period. The timing of synoptic sampling allowed the USGS to evaluate phosphorus inputs to and outputs from the Boise River during irrigation season, shortly after irrigation ended, and soon before irrigation resumed. Results from the synoptic sampling periods showed important differences in surface-water and groundwater distribution and phosphorus loading. In late August 2012, substantial streamflow gains to the Boise River occurred from Middleton (RM 31.4) downstream to Parma (RM 3.8). Mass-balance model results indicated that point and nonpoint sources (including groundwater) contributed phosphorus loads to the Boise River during irrigation season. Groundwater exchange within the Boise River in October 2012 and March 2013 was not as considerable as that measured in August 2012. However, groundwater discharge to agricultural tributaries and drains during non-irrigation season was a large source of discharge and

  5. Quantitative assay of element mass inventories in single cell biological systems with micro-PIXE

    Energy Technology Data Exchange (ETDEWEB)

    Ogrinc, Nina [Jožef Stefan Institute, Jamova 39, SI-1000 Ljubljana (Slovenia); LOTRIČ Metrology, Selca 163, SI-4227 Selca (Slovenia); Pelicon, Primož, E-mail: primoz.pelicon@ijs.si [Jožef Stefan Institute, Jamova 39, SI-1000 Ljubljana (Slovenia); Vavpetič, Primož; Kelemen, Mitja; Grlj, Nataša; Jeromel, Luka [Jožef Stefan Institute, Jamova 39, SI-1000 Ljubljana (Slovenia); Tomić, Sergej [Medical Faculty of the Military Medical Academy, University of Defense, Crnotravska 17, Belgrade (Serbia); Čolić, Miodrag [Medical Faculty of the Military Medical Academy, University of Defense, Crnotravska 17, Belgrade (Serbia); Medical Faculty, University of Niš, Boulevard of Dr. Zoran Djindjić 81, 18000 Niš (Serbia); Beran, Alfred [Dipartimento di Oceanografia Biologica, Istituto Nazionale di Oceanografia e Geofisica Sperimentale, Via Auguste Piccard 54, 34151 Trieste (Italy)

    2013-07-01

    Elemental concentrations in micro-PIXE (Particle Induced X-ray Emission) maps of elements in biological tissue slices have been determined using auxiliary information on the sample matrix composition from EBS (Elastic Backscattering Spectroscopy) and STIM (Scanning Transmission Ion Microscopy). The thin sample approximation may be used for evaluating micro-PIXE data in cases, where X-ray absorption in the sample can be neglected and the mass of elements in a selected area can be estimated. The resulting sensitivity amounts to an impressive 10{sup −12} g of the selected elements. Two cases are presented as examples. In the first, we determined the total mass of gold nanoparticles internalized by human monocyte-derived dendritic cells (MDDC). In the second, an inventory of the mass of elements in the micro-particulate material adsorbed at the wall of the lorica of the microzooplankton species Tintinnopsis radix has been created.

  6. Surface mass balance model evaluation from satellite and airborne lidar mapping

    Science.gov (United States)

    Sutterley, T. C.; Velicogna, I.; Fettweis, X.; van den Broeke, M. R.

    2016-12-01

    We present estimates of Greenland Ice Sheet (GrIS) surface elevation change from a novel combination of satellite and airborne laser altimetry measurements. Our method combines measurements from the Airborne Topographic Mapper (ATM), the Land, Vegetation and Ice Sensor (LVIS) and ICESat-1 to generate elevation change rates at high spatial resolution. This method allows to extend the records of each instrument, increases the overall spatial coverage compared to a single instrument, and produces high-quality, coherent maps of surface elevation change. In addition by combining the lidar datasets, we are able to investigate seasonal and interannual surface elevation change for years where Spring and Fall Operation IceBridge campaigns are available. We validate our method by comparing with the standard NSIDC elevation change product calculated using overlapping Level-1B ATM data. We use the altimetry-derived mass changes to evaluate the uncertainty in surface mass balance, particularly in the runoff component, from two Regional Climate Models (RCM's), the Regional Atmospheric Climate Model (RACMO) and the Modéle Atmosphérique Régional (MAR), and one Global Climate Model (GCM), MERRA2/GEOS-5. We investigate locations with low ice sheet surface velocities that are within the estimated ablation zones of each regional climate model. We find that the surface mass balance outputs from RACMO and MAR show good correspondence with mass changes derived from surface elevation changes over long periods. At two sites in Northeast Greenland (NEGIS), the MAR model has better correspondence with the altimetry estimate. We find that the differences at these locations are primarily due to the characterization of meltwater refreeze within the ice sheet.

  7. Mass balance of the Greenland ice sheet - a study of ICESat data, surface density and firn compaction modelling

    DEFF Research Database (Denmark)

    Sørensen, L. S.; Simonsen, Sebastian Bjerregaard; Nielsen, K.

    2010-01-01

    ICESat has provided surface elevation measurements of the ice sheets since the launch in January 2003, resulting in a unique data set for monitoring the changes of the cryosphere. Here we present a novel method for determining the mass balance of the Greenland ice sheet derived from ICESat...... in estimating the mass balance of the Greenland ice sheet. We find firn dynamics and surface densities to be important factors in deriving the mass loss from remote sensing altimetry. The volume change derived from ICESat data is corrected for firn compaction, vertical bedrock movement and an intercampaign...... boundary conditions. We find an annual mass loss of the Greenland ice sheet of 210 ± 21 Gt yr-1 in the period from October 2003 to March 2008. This result is in good agreement with other studies of the Greenland ice sheet mass balance, based on different remote sensing techniques....

  8. The impact of Saharan dust and black carbon on albedo and long-term mass balance of an Alpine glacier

    Directory of Open Access Journals (Sweden)

    J. Gabbi

    2015-07-01

    Full Text Available Light-absorbing impurities in snow and ice control glacier melt as shortwave radiation represents the main component of the surface energy balance. Here, we investigate the long-term effect of snow impurities, i.e., mineral dust and black carbon (BC, on albedo and glacier mass balance. The analysis was performed over the period 1914–2014 for two sites on Claridenfirn, Swiss Alps, where an outstanding 100-year record of seasonal mass balance measurements is available. Information on atmospheric deposition of mineral dust and BC over the last century was retrieved from two firn/ice cores of high-alpine sites. A combined mass balance and snow/firn layer model was employed to assess the effects of melt and accumulation processes on the impurity concentration at the surface and thus on albedo and glacier mass balance. Compared to pure snow conditions, the presence of Saharan dust and BC lowered the mean annual albedo by 0.04–0.06 depending on the location on the glacier. Consequently, annual melt was increased by 15–19 %, and the mean annual mass balance was reduced by about 280–490 mm w.e. BC clearly dominated absorption which is about 3 times higher than that of mineral dust. The upper site has experienced mainly positive mass balances and impurity layers were continuously buried whereas at the lower site, surface albedo was more strongly influenced by re-exposure of dust and BC-enriched layers due to frequent years with negative mass balances.

  9. Tectonic controls on the long-term carbon isotope mass balance.

    Science.gov (United States)

    Shields, Graham A; Mills, Benjamin J W

    2017-04-25

    The long-term, steady-state marine carbon isotope record reflects changes to the proportional burial rate of organic carbon relative to total carbon on a global scale. For this reason, times of high δ 13 C are conventionally interpreted to be oxygenation events caused by excess organic burial. Here we show that the carbon isotope mass balance is also significantly affected by tectonic uplift and erosion via changes to the inorganic carbon cycle that are independent of changes to the isotopic composition of carbon input. This view is supported by inverse covariance between δ 13 C and a range of uplift proxies, including seawater 87 Sr/ 86 Sr, which demonstrates how erosional forcing of carbonate weathering outweighs that of organic burial on geological timescales. A model of the long-term carbon cycle shows that increases in δ 13 C need not be associated with increased organic burial and that alternative tectonic drivers (erosion, outgassing) provide testable and plausible explanations for sustained deviations from the long-term δ 13 C mean. Our approach emphasizes the commonly overlooked difference between how net and gross carbon fluxes affect the long-term carbon isotope mass balance, and may lead to reassessment of the role that the δ 13 C record plays in reconstructing the oxygenation of earth's surface environment.

  10. A carbon isotope mass balance for an anoxic marine sediment: Isotopic signatures of diagenesis

    Science.gov (United States)

    Boehme, Susan E.

    1993-01-01

    A carbon isotope mass balance was determined for the sediments of Cape Lookout Bight, NC to constrain the carbon budgets published previously. The diffusive, ebullitive and burial fluxes of sigma CO2 and CH4, as well as the carbon isotope signatures of these fluxes, were measured. The flux-weighted isotopic signature of the remineralized carbon (-18.9 plus or minus 2.7 per mil) agreed with the isotopic composition of the remineralized organic carbon determined from the particulate organic carbon (POC) delta(C-13) profiles (-19.2 plus or minus 0.2), verifying the flux and isotopic signature estimates. The measured delta(C-13) values of the sigma CO2 and CH4 diffusive fluxes were significantly different from those calculated from porewater gradients. The differences appear to be influenced by methane oxidation at the sediment-water interface, although other potential processes cannot be excluded. The isotope mass balance provides important information concerning the locations of potential diagenetic isotope effects. Specifically, the absence of downcore change in the delta(C-13) value of the POC fraction and the identical isotopic composition of the POC and the products of remineralization indicate that no isotopic fractionation is expressed during the initial breakdown of the POC, despite its isotopically heterogeneous composition.

  11. Mass balance-based regression modeling of Cd and Zn accumulation in urban soils of Beijing.

    Science.gov (United States)

    Peng, Chi; Wang, Meie; Chen, Weiping; Chang, Andrew C; Crittenden, John C

    2017-03-01

    Accumulation of heavy metals in urban soil can pose adverse impacts on public health and terrestrial ecosystems. We developed a mass balance-based regression model to simulate the heavy metal accumulation in urban soils as a function of time and to explore connections between metal concentration and urbanization processes. Concentrations of Cd and Zn in 68 residential soil samples in the urban area of Beijing were used. The background concentrations, the loss rates and the input fluxes of Cd and Zn in urban soils of Beijing during the last three decades were estimated using a regression of the time series of accumulations of the metals. Based on the regression estimates, we simulated the general trends of Cd and Zn accumulation in the soils from 1978 to 2078. The concentrations of Cd and Zn in urban soil generally increased with the population growth, vehicle use and coal consumption. The mean concentrations of Cd and Zn in urban soil of Beijing would increase by 3 fold over the next 70years for the current development scenario. The mass balance-based regression approach, which is able to reconstruct the history data of urban soil pollution, provides fundamental information for urban planning and environmental management. Copyright © 2016. Published by Elsevier B.V.

  12. A metabolism perspective on alternative urban water servicing options using water mass balance.

    Science.gov (United States)

    Farooqui, Tauheed A; Renouf, Marguerite A; Kenway, Steven J

    2016-12-01

    Urban areas will need to pursue new water servicing options to ensure local supply security. Decisions about how best to employ them are not straightforward due to multiple considerations and the potential for problem shifting among them. We hypothesise that urban water metabolism evaluation based a water mass balance can help address this, and explore the utility of this perspective and the new insights it provides about water servicing options. Using a water mass balance evaluation framework, which considers direct urban water flows (both 'natural' hydrological and 'anthropogenic' flows), as well as water-related energy, we evaluated how the use of alternative water sources (stormwater/rainwater harvesting, wastewater/greywater recycling) at different scales influences the 'local water metabolism' of a case study urban development. New indicators were devised to represent the water-related 'resource efficiency' and 'hydrological performance' of the urban area. The new insights gained were the extent to which alternative water supplies influence the water efficiency and hydrological performance of the urban area, and the potential energy trade-offs. The novel contribution is the development of new indicators of urban water resource performance that bring together considerations of both the 'anthropogenic' and 'natural' water cycles, and the interactions between them. These are used for the first time to test alternative water servicing scenarios, and to provide a new perspective to complement broader sustainability assessments of urban water. Copyright © 2016 Elsevier Ltd. All rights reserved.

  13. Tectonic controls on the long-term carbon isotope mass balance

    Science.gov (United States)

    Shields, Graham A.; Mills, Benjamin J. W.

    2017-04-01

    The long-term, steady-state marine carbon isotope record reflects changes to the proportional burial rate of organic carbon relative to total carbon on a global scale. For this reason, times of high δ13C are conventionally interpreted to be oxygenation events caused by excess organic burial. Here we show that the carbon isotope mass balance is also significantly affected by tectonic uplift and erosion via changes to the inorganic carbon cycle that are independent of changes to the isotopic composition of carbon input. This view is supported by inverse covariance between δ13C and a range of uplift proxies, including seawater 87Sr/86Sr, which demonstrates how erosional forcing of carbonate weathering outweighs that of organic burial on geological timescales. A model of the long-term carbon cycle shows that increases in δ13C need not be associated with increased organic burial and that alternative tectonic drivers (erosion, outgassing) provide testable and plausible explanations for sustained deviations from the long-term δ13C mean. Our approach emphasizes the commonly overlooked difference between how net and gross carbon fluxes affect the long-term carbon isotope mass balance, and may lead to reassessment of the role that the δ13C record plays in reconstructing the oxygenation of earth’s surface environment.

  14. Tectonic controls on the long-term carbon isotope mass balance

    Science.gov (United States)

    Mills, Benjamin J. W.

    2017-01-01

    The long-term, steady-state marine carbon isotope record reflects changes to the proportional burial rate of organic carbon relative to total carbon on a global scale. For this reason, times of high δ13C are conventionally interpreted to be oxygenation events caused by excess organic burial. Here we show that the carbon isotope mass balance is also significantly affected by tectonic uplift and erosion via changes to the inorganic carbon cycle that are independent of changes to the isotopic composition of carbon input. This view is supported by inverse covariance between δ13C and a range of uplift proxies, including seawater 87Sr/86Sr, which demonstrates how erosional forcing of carbonate weathering outweighs that of organic burial on geological timescales. A model of the long-term carbon cycle shows that increases in δ13C need not be associated with increased organic burial and that alternative tectonic drivers (erosion, outgassing) provide testable and plausible explanations for sustained deviations from the long-term δ13C mean. Our approach emphasizes the commonly overlooked difference between how net and gross carbon fluxes affect the long-term carbon isotope mass balance, and may lead to reassessment of the role that the δ13C record plays in reconstructing the oxygenation of earth’s surface environment. PMID:28396434

  15. A new line element derived from the variable rest mass in gravitational field

    OpenAIRE

    Ben-Amots, N.

    2008-01-01

    This paper presents a new line element based on the assumption of the variable rest mass in gravitational field, and explores some its implications. This line element is not a vacuum solution of Einstein's equations, yet it is sufficiently close to Schwarzschild's line element to be compatible with all of the experimental and observational measurements made so far to confirm the three Einstein's predictions. The theory allows radiation and fast particles to escape from all massive bodies, eve...

  16. Widespread wind-scour sites reduce total surface mass balance of East Antarctica

    Science.gov (United States)

    Das, I.; Bell, R. E.; Scambos, T.; Wolovick, M.; Nicolas, J. P.; Creyts, T. T.; Studinger, M.; Frearson, N.

    2012-12-01

    Accurate quantification of surface accumulation over Antarctica is important for mass balance estimates and climate studies based on chemical and isotopic analysis of ice cores. Significant uncertainties exist in the current compilations of surface mass balance (SMB) over East Antarctica, especially in the interior. Katabatic winds accelerating over steeper ice surface slopes erode and sublimate the surface snow and firn, producing extensive and localized (~ 10 km or less) regions of near-zero or negative surface mass balance. Surface mass balance estimates over Antarctica rely on widely scattered point measurements or atmospheric models that interpolate over large grids and do not capture these local processes, thereby overestimating the net surface accumulation. Here we use unconformities in airborne radar data combined with lidar derived surface roughness to identify extensive and persistent wind-scour zones at high elevations (>3800 m) near Dome A, Antarctica. These wind-scour zones form in areas of relatively steep surface slopes controlled by bedrock topography. Airborne data used in this study was collected during the AGAP survey in 2009. Approximately 125,500 sq. km area over Dome A was surveyed in a dense grid of 5km spacing in the along-track and 35 km in the across-track direction. The radar profile unconformities are observed in ~45 flight lines. Over a broad region (~ 200 km) surrounding the unconformities, lidar derived surface roughness is higher than the regional mean roughness. The elevated surface roughness indicates formation of microscale surface features like sastrugi and dunes due to increased wind activity. Truncation of internal layers by the unconformity in the radar images indicates ablation of near-surface firn layers. We interpret the surface projection of unconformities as wind-scour zones where the SMB is zero or negative. Using a calculated mean slope in the wind direction based on a 1 km DEM, near-surface winds and annual SMB from

  17. Development of design parameters for mass concrete using finite element analysis : final report, February 2010.

    Science.gov (United States)

    2010-02-01

    A finite element model for analysis of mass concrete was developed in this study. To validate the developed model, large concrete blocks made with four different mixes of concrete, typical of use in mass concrete applications in Florida, were made an...

  18. Does mechanistic modeling of filter strip pesticide mass balance and degradation processes affect environmental exposure assessments?

    Science.gov (United States)

    Muñoz-Carpena, Rafael; Ritter, Amy; Fox, Garey A; Perez-Ovilla, Oscar

    2015-11-01

    Vegetative filter strips (VFS) are a widely adopted practice for limiting pesticide transport from adjacent fields to receiving waterbodies. The efficacy of VFS depends on site-specific input factors. To elucidate the complex and non-linear relationships among these factors requires a process-based modeling framework. Previous research proposed linking existing higher-tier environmental exposure models with a well-tested VFS model (VFSMOD). However, the framework assumed pesticide mass stored in the VFS was not available for transport in subsequent storm events. A new pesticide mass balance component was developed to estimate surface pesticide residue trapped in the VFS and its degradation between consecutive runoff events. The influence and necessity of the updated framework on acute and chronic estimated environmental concentrations (EECs) and percent reductions in EECs were investigated across three, 30-year U.S. EPA scenarios: Illinois corn, California tomato, and Oregon wheat. The updated framework with degradation predicted higher EECs than the existing framework without degradation for scenarios with greater sediment transport, longer VFS lengths, and highly sorbing and persistent pesticides. Global sensitivity analysis (GSA) assessed the relative importance of mass balance and degradation processes in the context of other input factors like VFS length (VL), organic-carbon sorption coefficient (Koc), and soil and water half-lives. Considering VFS pesticide residue and degradation was not important if single, large runoff events controlled transport, as is typical for higher percentiles considered in exposure assessments. Degradation processes become more important when considering percent reductions in acute or chronic EECs, especially under scenarios with lower pesticide losses. Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. Glacier mass balance and its potential impacts in the Altai Mountains over the period 1990-2011

    Science.gov (United States)

    Zhang, Yong; Enomoto, Hiroyuki; Ohata, Tetsuo; Kitabata, Hideyuki; Kadota, Tsutomu; Hirabayashi, Yukiko

    2017-10-01

    The Altai Mountains contain 1281 glaciers covering an area of 1191 km2. These glaciers have undergone significant changes in glacial length and area over the past decade. However, mass changes of these glaciers and their impacts remain poorly understood. Here we present surface mass balances of all glaciers in the region for the period 1990-2011, using a glacier mass-balance model forced by the outputs of a regional climate model. Our results indicate that the mean specific mass balance for the whole region is about -0.69 m w.e. yr-1 over the entire period, and about 81.3% of these glaciers experience negative net mass balance. We detect an accelerated wastage of these glaciers in recent years, and marked differences in mass change and its sensitivity to climate change for different regions and size classes. In particular, higher mass loss and temperature sensitivity are observed for glaciers smaller than 0.5 km2. In addition to temperature rise, a decrease in precipitation in the western part of the region and an increase in precipitation in the eastern part likely contribute to significant sub-region differences in mass loss. With significant glacier wastage, the contribution of all glaciers to regional water resources and sea-level change becomes larger than before, but may not be a potential threat to human populations through impacts on water availability.

  20. Mass-spectrometric determination of trace elements in aqueous media without preconcentration

    Energy Technology Data Exchange (ETDEWEB)

    Foss, Gordon Oluf [Iowa State Univ., Ames, IA (United States)

    1981-10-01

    Feasibility of using a low pressure glow discharge as an ion source for the mass spectrometric determination of trace elements in aqueous media was investigated. A cryogenically cooled hollow cathode ion source was developed to analyze aqueous samples without external preconcentration. Aqueous solutions containing seventy elements were analyzed and the detection limits, sensitivity factors, and linear regression correlation coefficients were determined. A standard test solution of trace elements in water was analyzed and the concentrations of trace elements were calculated using the sensitivity factors determined previously. The results compared favorably within the error limits predicted by the semiquantitative survey methods used. Tap water and natural lake water samples were examined and minimal interference effects due to organic compounds and biological compounds were noted. A research ion optical system (RIOS) was developed as a flexible mass analyzer for the development of new ion sources. The RIOS is a double focussing mass analyzer designed utilizing the Mattauch-Herzog geometry with externally adjustable slit assemblies.

  1. Adjustment of regional climate model output for modeling the climatic mass balance of all glaciers on Svalbard.

    Science.gov (United States)

    Möller, Marco; Obleitner, Friedrich; Reijmer, Carleen H; Pohjola, Veijo A; Głowacki, Piotr; Kohler, Jack

    2016-05-27

    Large-scale modeling of glacier mass balance relies often on the output from regional climate models (RCMs). However, the limited accuracy and spatial resolution of RCM output pose limitations on mass balance simulations at subregional or local scales. Moreover, RCM output is still rarely available over larger regions or for longer time periods. This study evaluates the extent to which it is possible to derive reliable region-wide glacier mass balance estimates, using coarse resolution (10 km) RCM output for model forcing. Our data cover the entire Svalbard archipelago over one decade. To calculate mass balance, we use an index-based model. Model parameters are not calibrated, but the RCM air temperature and precipitation fields are adjusted using in situ mass balance measurements as reference. We compare two different calibration methods: root mean square error minimization and regression optimization. The obtained air temperature shifts (+1.43°C versus +2.22°C) and precipitation scaling factors (1.23 versus 1.86) differ considerably between the two methods, which we attribute to inhomogeneities in the spatiotemporal distribution of the reference data. Our modeling suggests a mean annual climatic mass balance of -0.05 ± 0.40 m w.e. a-1 for Svalbard over 2000-2011 and a mean equilibrium line altitude of 452 ± 200 m  above sea level. We find that the limited spatial resolution of the RCM forcing with respect to real surface topography and the usage of spatially homogeneous RCM output adjustments and mass balance model parameters are responsible for much of the modeling uncertainty. Sensitivity of the results to model parameter uncertainty is comparably small and of minor importance.

  2. Monitoring glacier albedo as a proxy to derive summer and annual surface mass balances from optical remote-sensing data

    Science.gov (United States)

    Davaze, Lucas; Rabatel, Antoine; Arnaud, Yves; Sirguey, Pascal; Six, Delphine; Letreguilly, Anne; Dumont, Marie

    2018-01-01

    Less than 0.25 % of the 250 000 glaciers inventoried in the Randolph Glacier Inventory (RGI V.5) are currently monitored with in situ measurements of surface mass balance. Increasing this archive is very challenging, especially using time-consuming methods based on in situ measurements, and complementary methods are required to quantify the surface mass balance of unmonitored glaciers. The current study relies on the so-called albedo method, based on the analysis of albedo maps retrieved from optical satellite imagery acquired since 2000 by the MODIS sensor, on board the TERRA satellite. Recent studies revealed substantial relationships between summer minimum glacier-wide surface albedo and annual surface mass balance, because this minimum surface albedo is directly related to the accumulation-area ratio and the equilibrium-line altitude. On the basis of 30 glaciers located in the French Alps where annual surface mass balance data are available, our study conducted on the period 2000-2015 confirms the robustness and reliability of the relationship between the summer minimum surface albedo and the annual surface mass balance. For the ablation season, the integrated summer surface albedo is significantly correlated with the summer surface mass balance of the six glaciers seasonally monitored. These results are promising to monitor both annual and summer glacier-wide surface mass balances of individual glaciers at a regional scale using optical satellite images. A sensitivity study on the computed cloud masks revealed a high confidence in the retrieved albedo maps, restricting the number of omission errors. Albedo retrieval artifacts have been detected for topographically incised glaciers, highlighting limitations in the shadow correction algorithm, although inter-annual comparisons are not affected by systematic errors.

  3. Alfacalcidol improves muscle power, muscle function and balance in elderly patients with reduced bone mass.

    Science.gov (United States)

    Schacht, E; Ringe, Johann D

    2012-01-01

    We investigated the effect of daily therapy with 1 mcg alfacalcidol (Doss(®)-TEVA/AWD-pharma) on muscle power, muscle function, balance performance and fear of falls in an open, multi-centered, uncontrolled, prospective study on a cohort of patients with reduced bone mass. Among the 2,097 participants, 87.1% were post-menopausal women and 12.9% were men. Mean age was 74.8 years and mean body mass index (BMI) 26.3 kg/m². A total of 75.3% of the study population had osteoporosis, 81% a diagnosis of "increased risk of falls" and 70.1% had a creatinine clearance (CrCl) of power tests at onset and after 3 and 6 months: the timed up and go test (TUG) and the chair rising test (CRT). At baseline and after 6 months, participants performed the tandem gait test (TGT) and filled out a questionnaire evaluating fear of falling. Successful performance in the muscle tests is associated with a significantly lower risk of falls and non-vertebral fractures in elderly patients (successful test performance: TUG ≤ 10 s (sec), CRT ≤ 10 s, TGT ≥ 8 steps). A significant improvement in the performance of the two muscle tests was proved already after 3 months of treatment with alfacalcidol and further increased by the end of the therapeutic intervention. There were significant increases in the number of participants able to successfully perform the tests: 24.6% at baseline and 46.3% at the end of trial for the TUG (P balance test (TGT) increased from 36.0% at onset to 58.6% at the end of the trial (P power, muscle function and balance and reduces fear of falls. The significant improvement in the three muscle and balance tests and fear of falls may have a preventative effect on falls and fractures. We suggest that the quantitative risk tests used in this study could be reliable surrogate parameters for the risk of falls and fractures in elderly patients.

  4. Detecting high spatial variability of ice shelf basal mass balance, Roi Baudouin Ice Shelf, Antarctica

    Directory of Open Access Journals (Sweden)

    S. Berger

    2017-11-01

    Full Text Available Ice shelves control the dynamic mass loss of ice sheets through buttressing and their integrity depends on the spatial variability of their basal mass balance (BMB, i.e. the difference between refreezing and melting. Here, we present an improved technique – based on satellite observations – to capture the small-scale variability in the BMB of ice shelves. As a case study, we apply the methodology to the Roi Baudouin Ice Shelf, Dronning Maud Land, East Antarctica, and derive its yearly averaged BMB at 10 m horizontal gridding. We use mass conservation in a Lagrangian framework based on high-resolution surface velocities, atmospheric-model surface mass balance and hydrostatic ice-thickness fields (derived from TanDEM-X surface elevation. Spatial derivatives are implemented using the total-variation differentiation, which preserves abrupt changes in flow velocities and their spatial gradients. Such changes may reflect a dynamic response to localized basal melting and should be included in the mass budget. Our BMB field exhibits much spatial detail and ranges from −14.7 to 8.6 m a−1 ice equivalent. Highest melt rates are found close to the grounding line where the pressure melting point is high, and the ice shelf slope is steep. The BMB field agrees well with on-site measurements from phase-sensitive radar, although independent radar profiling indicates unresolved spatial variations in firn density. We show that an elliptical surface depression (10 m deep and with an extent of 0.7 km × 1.3 km lowers by 0.5 to 1.4 m a−1, which we tentatively attribute to a transient adaptation to hydrostatic equilibrium. We find evidence for elevated melting beneath ice shelf channels (with melting being concentrated on the channel's flanks. However, farther downstream from the grounding line, the majority of ice shelf channels advect passively (i.e. no melting nor refreezing toward the ice shelf front. Although the absolute, satellite

  5. Geodetic mass balance of the Patagonian Icefields from STRM and TanDEM-X DEMs

    Science.gov (United States)

    Abdel Jaber, W.; Floricioiu, D.; Rott, H.

    2016-12-01

    The Northern and Southern Patagonian Icefields (NPI & SPI), represent the largest mid-latitude ice masses in the Southern Hemisphere. They are mostly drained by outlet glaciers with fronts calving into fresh water lakes or Pacific fjords. Both icefields were affected by significant downwasting in the last decades, as confirmed by published mass change trends obtained by means of gravimetric measurements and geodetic methods. Given their unique characteristics and the significant contribution to sea level rise per unit of area, they represent a fundamental barometer for climate research. The Shuttle Radar Topography Mission (SRTM) of 2000 provided the most complete and accurate Digital Elevation Model (DEM) at the time covering the entire globe from 56°S to 60°N. The present TanDEM-X mission shares the same objective aiming at a global coverage with much higher resolution and accuracy. Their combination leads to a unique multitemporal elevation dataset based solely on SAR single pass bistatic interferometry characterized by 11 to 16 year time span: an ideal setup for monitoring long-term large-scale geophysical phenomena. Using this dataset, detailed and extensive ice elevation change maps were obtained for the 12900 km² SPI for the observation period 2000 - 2011/2012 and for the 3900 km² NPI for the period 2000 - 2014. These maps were used to compute the glacier mass balance of the icefields through the geodetic method. Particular emphasis was set on the estimation of the uncertainty of the geodetic mass balance by quantifying all relevant sources of error. Among these, signal penetration into dry ice and snow can affect considerably radar elevation measurements. For this purpose the backscattering coefficient of the acquisitions along with concurrent meteorological data were analyzed to assess the conditions of the icefield surface. Mass change rates of -3.96±0.14 Gt a-1 and of -13.14±0.42 Gt a-1 (excluding subaqueous loss) were obtained for NPI and SPI

  6. Detecting high spatial variability of ice shelf basal mass balance, Roi Baudouin Ice Shelf, Antarctica

    Science.gov (United States)

    Berger, Sophie; Drews, Reinhard; Helm, Veit; Sun, Sainan; Pattyn, Frank

    2017-11-01

    Ice shelves control the dynamic mass loss of ice sheets through buttressing and their integrity depends on the spatial variability of their basal mass balance (BMB), i.e. the difference between refreezing and melting. Here, we present an improved technique - based on satellite observations - to capture the small-scale variability in the BMB of ice shelves. As a case study, we apply the methodology to the Roi Baudouin Ice Shelf, Dronning Maud Land, East Antarctica, and derive its yearly averaged BMB at 10 m horizontal gridding. We use mass conservation in a Lagrangian framework based on high-resolution surface velocities, atmospheric-model surface mass balance and hydrostatic ice-thickness fields (derived from TanDEM-X surface elevation). Spatial derivatives are implemented using the total-variation differentiation, which preserves abrupt changes in flow velocities and their spatial gradients. Such changes may reflect a dynamic response to localized basal melting and should be included in the mass budget. Our BMB field exhibits much spatial detail and ranges from -14.7 to 8.6 m a-1 ice equivalent. Highest melt rates are found close to the grounding line where the pressure melting point is high, and the ice shelf slope is steep. The BMB field agrees well with on-site measurements from phase-sensitive radar, although independent radar profiling indicates unresolved spatial variations in firn density. We show that an elliptical surface depression (10 m deep and with an extent of 0.7 km × 1.3 km) lowers by 0.5 to 1.4 m a-1, which we tentatively attribute to a transient adaptation to hydrostatic equilibrium. We find evidence for elevated melting beneath ice shelf channels (with melting being concentrated on the channel's flanks). However, farther downstream from the grounding line, the majority of ice shelf channels advect passively (i.e. no melting nor refreezing) toward the ice shelf front. Although the absolute, satellite-based BMB values remain uncertain, we have

  7. Chemical mass balance source apportionment of fine and PM10 in the Desert Southwest, USA

    Directory of Open Access Journals (Sweden)

    Andrea L. Clements

    2016-03-01

    Full Text Available The Desert Southwest Coarse Particulate Matter Study was undertaken in Pinal County, Arizona, to better understand the origin and impact of sources of fine and coarse particulate matter (PM in rural, arid regions of the U.S. southwestern desert. The desert southwest experiences some of the highest PM10 mass concentrations in the country. To augment previously reported results, 6-week aggregated organic speciation data that included ambient concentrations of n-alkanes, polycyclic aromatic hydrocarbons, organic acids, and saccharides were used in chemical mass balance modeling (CMB. A set of re-suspended soil samples were analyzed for specific marker species to provide locally-appropriate source profiles for the CMB analysis. These profiles, as well as previously collected plant and fungal spore profiles from the region, were combined with published source profiles for other relevant sources and used in the CMB analysis. The six new region-specific source profiles included both organic and inorganic species for four crustal material sources, one plant detritus source, and one fungal spore source.Results indicate that up to half of the ambient PM2.5 was apportioned to motor vehicles with the highest regional contribution observed in the small urban center of Casa Grande. Daily levels of apportioned crustal material accounted for up to 50% of PM2.5 mass with the highest contributions observed at the sites closest to active agricultural areas. Apportioned secondary PM, biomass burning, and road dust typically contributed less than 35% as a group to the apportioned PM2.5 mass. Crustal material was the primary source apportioned to PM10 and accounted for between 50–90% of the apportioned mass. Of the other sources apportioned to PM10, motor vehicles and road dust were the largest contributors at the urban and one of the rural sites, whereas road dust and meat cooking operations were the largest contributors at the other rural site.

  8. Uncertainty in alpine snow mass balance simulations due to snow model parameterisation and windflow representation

    Science.gov (United States)

    Musselman, K. N.; Pomeroy, J. W.; Essery, R.; Leroux, N.

    2013-12-01

    Despite advances in alpine snow modelling there remain two fundamental areas of divergent scientific thought in estimating alpine snow mass balances: i) blowing snow sublimation losses, and ii) wind flow representation. Sublimation calculations have poorly understood humidity feedbacks that vary considerably and mathematical representations of alpine windflow vary in complexity - these differences introduce uncertainty. To better estimate and restrain this uncertainty, a variety of physically based, spatially distributed snowmelt models that consider the physics of wind redistribution and sublimation of blowing snow were evaluated for their ability to simulate seasonal snow distribution and melt patterns in a windy alpine environment in the Canadian Rockies. The primary difference in the snow models was their calculation of blowing snow sublimation losses which ranged from large to small estimates. To examine the uncertainty introduced by windflow calculations on the snow model simulations, each model was forced with output from windflow models of varying computational complexity and physical realism from a terrain-based empirical interpolation of station observations to a simple turbulence model to a computational fluid dynamics model that solves for the Navier-Stokes equations. The high-resolution snow simulations were run over a 1 km2 spatial extent centred on a ridgetop meteorological station within the Marmot Creek Research basin, Alberta, Canada. The three windflow simulations all produced reasonable results compared to wind speeds measured on two opposing slopes (bias better than ×0.3 m s-1; RMSE < 1.1 m s-1), however there was great sensitivity in SWE simulated by the snow models to the driving windflow simulation used. Specifically, there were distinct differences in the magnitude and location of snow drifts from all snow models that depended on the windflow scheme. When compared to measurements from airborne LiDAR, snow surveys, and automated snow depth

  9. Mass balance of Djankuat Glacier, Central Caucasus: observations, modeling and prediction

    Science.gov (United States)

    Rybak, Oleg; Mariia, Kaminskaia; Stanislav, Kutuzov; Ivan, Lavrentiev; Polina, Morozova; Victor, Popovnin; Elena, Rybak

    2017-04-01

    Djankuat is a typical valley glacier on the northern slope of the main Caucasus chain. Its present day area is approximately 2.5 square km with the characteristic ice thickness of several tens of meters. As well as other glaciers in the region, Djankuat has been shrinking during the last several decades, its cumulative mass balance in 1968-2016 was equal to -13.6 m w.e. In general, Caucasus' glaciers lost approximately one-third of their area and half of the volume. Prediction of further deradation of glaciers in changing environment is a challenging task because rivers fed by glacier melt water provide from 40 to 70% of the total river run-off in the adjacent piedmont territories. Growing demand in fresh water is rather critical for the local economy development and for growing population, motivating elaboration of an effitient instrument for evaluation and forecasting of the glaciation in the Greater Caucasus. Unfortunately, systematic observations are sparse limiting possibilities for proper model development for the most of the glaciers. Under these circumstances, we have to rely on the models developed for the few well-studied ones, like Djankuat, which is probably one of the most explored glaciers in the world. Accumulation and ablation rates have been observed here systematically and uninterruptedly since mid 60-ies using dense stake network. Together with the mass balance components, changes in flow velocity, ice thickness and geometry were regularly evaluated. During the last several ablation seasons, direct meteorological observations were carried out using an AMS. Long series of meteorological observations at the nearest weather station allow making assessment of the glacier response to climate change in the second half of the 20th century. Abundant observation data gave us the opportunity to elaborate, calibrate and validate an efficient mathematical model of surface mass balance of a typical glacier in the region. Since many glaciers in the Caucasus

  10. Application of terrestrial photogrammetry for the mass balance calculation on Montasio Occidentale Glacier (Julian Alps, Italy)

    Science.gov (United States)

    Piermattei, Livia; Carturan, Luca; Calligaro, Simone; Blasone, Giacomo; Guarnieri, Alberto; Tarolli, Paolo; Dalla Fontana, Giancarlo; Vettore, Antonio

    2014-05-01

    Digital elevation models (DEMs) of glaciated terrain are commonly used to measure changes in geometry and hence infer the mass balance of glaciers. Different tools and methods exist to obtain information about the 3D geometry of terrain. Recent improvements on the quality and performance of digital cameras for close-range photogrammetry, and the development of automatic digital photogrammetric processing makes the 'structure from motion' photogrammetric technique (SfM) competitive for high quality 3D models production, compared to efficient but also expensive and logistically-demanding survey technologies such as airborn and terrestrial laser scanner (TLS). The purpose of this work is to test the SfM approach, using a consumer-grade SLR camera and the low-cost computer vision-based software package Agisoft Photoscan (Agisoft LLC), to monitor the mass balance of Montasio Occidentale glacier, a 0.07km2, low-altitude, debris-covered glacier located in the Eastern Italian Alps. The quality of the 3D models produced by the SfM process has been assessed by comparison with digital terrain models obtained through TLS surveys carried out at the same dates. TLS technique has indeed proved to be very effective in determining the volume change of this glacier in the last years. Our results shows that the photogrammetric approach can produce point cloud densities comparable to those derived from TLS measurements. Furthermore, the horizontal and vertical accuracies are also of the same order of magnitude as for TLS (centimetric to decimetric). The effect of different landscape characteristics (e.g. distance from the camera or terrain gradient) and of different substrata (rock, debris, ice, snow and firn) was also evaluated in terms of SfM reconstruction's accuracy vs. TLS. Given the good results obtained on the Montasio Occidentale glacier, it can be concluded that the terrestrial photogrammetry, with the advantageous features of portability, ease of use and above all low costs

  11. Mass balance and hydrological contribution of glaciers in northern and central Chile

    Science.gov (United States)

    MacDonell, Shelley; Vivero, Sebastian; McPhee, James; Ayala, Alvaro; Pellicciotti, Francesca; Campos, Cristian; Caro, Dennys; Ponce, Rodrigo

    2016-04-01

    Water is a critical resource in the northern and central regions of Chile, as the area supports more than 40% of the country's population, and the regional economy depends on agricultural production and mining, which are two industries that rely heavily on a consistent water supply. Due to relatively low rates of rainfall, meltwater from snow and ice bodies in the highland areas provides a key component of the annual water supply in these areas. Consequently, accurate estimates of the rates of ablation of the cryosphere (i.e. snow and ice) are crucial for predicting current supply rates, and future projections. Whilst snow is generally a larger contributor of freshwater, during periods of drought, glaciers provide a significant source. This study aims to determine the contribution of glaciers to two catchments in northern and central Chile during a 2.5 year period, which largely consisted of extreme dry periods, but also included the recent El Niño event. This study combined field and modelling studies to understand glacier and rock glacier contributions in the Tapado (30°S), Yeso (33°S) catchments. In the field we undertook glaciological mass balance monitoring of three glaciers, monitored albedo and snow line changes using automatic cameras for three glaciers, measured discharge continuously at several points, installed six automatic weather stations and used thermistors to monitor thermal regime changes of two rock glaciers. The combination of these datasets where used to drive energy balance and hydrological models to estimate the contribution of ice bodies to streamflow in the two studied catchments. Over the course of the study all glaciers maintained a negative mass balance, however glaciers in central Chile lost more mass, which is due to the higher melt rates experienced due to lower elevations and higher temperatures. Areas free of debris generally contributed more to streamflow than sediment covered regions, and snow generally contributed more over

  12. Linking glacier annual mass balance and glacier albedo retrieved from MODIS data

    Directory of Open Access Journals (Sweden)

    M. Dumont

    2012-12-01

    Full Text Available Albedo is one of the variables controlling the mass balance of temperate glaciers. Multispectral imagers, such as MODerate Imaging Spectroradiometer (MODIS on board the TERRA and AQUA satellites, provide a means to monitor glacier surface albedo. In this study, different methods to retrieve broadband glacier surface albedo from MODIS data are compared. The effect of multiple reflections due to the rugged topography and of the anisotropic reflection of snow and ice are particularly investigated. The methods are tested on the Saint Sorlin Glacier (Grandes Rousses area, French Alps. The accuracy of the retrieved albedo is estimated using both field measurements, at two automatic weather stations located on the glacier, and albedo values derived from terrestrial photographs. For summers 2008 and 2009, the root mean square deviation (RMSD between field measurements and the broadband albedo retrieved from MODIS data at 250 m spatial resolution was found to be 0.052 or about 10% relative error. The RMSD estimated for the MOD10 daily albedo product is about three times higher. One decade (2000–2009 of MODIS data were then processed to create a time series of albedo maps of Saint Sorlin Glacier during the ablation season. The annual mass balance of Saint Sorlin Glacier was compared with the minimum albedo value (average over the whole glacier surface observed with MODIS during the ablation season. A strong linear correlation exists between the two variables. Furthermore, the date when the average albedo of the whole glacier reaches a minimum closely corresponds to the period when the snow line is located at its highest elevation, thus when the snow line is a good indicator of the glacier equilibrium line. This indicates that this strong correlation results from the fact that the minimal average albedo values of the glacier contains considerable information regarding the relative share of areal surfaces between the ablation zone (i.e. ice with generally

  13. Reducing heavy drinking in college males with the decisional balance: Analyzing an element of Motivational Interviewing

    OpenAIRE

    LaBrie, Joseph W.; Pedersen, Eric R.; Earleywine, Mitch; Olsen, Hutson

    2005-01-01

    The decisional balance, a brief detailing of the advantages and disadvantages of behavior change, serves as a key component to interventions in Motivational Interviewing. The impact of this component alone is not well understood. Forty-seven men completed a Timeline Followback interview assessing alcohol consumption and unsafe sexual practices. They then completed a decisional balance, listing the Pros and Cons of decreasing their drinking, but not one for safer sex. One-month follow-up data ...

  14. Energy and mass balance observations on La Mare Glacier (Ortles-Cevedale, European Alps)

    Science.gov (United States)

    Carturan, L.; Cazorzi, F.; Dalla Fontana, G.

    2009-04-01

    An experimental site was setup in 2005 on the ablation area of La Mare Glacier, at 2990 m a.s.l., to study the energy and mass balance exchanges between the glacier surface and the atmosphere and to investigate the climatic sensitivity of this particular glacier. An Automatic Weather Station was operated, in the framework of a monitoring network which has been implemented in the Upper Val de La Mare experimental watershed (Trentino, Italy). This basin was selected for a study of climate change effects on cryosphere and hydrology at high-altitude catchments. The 36.2 km2 wide basin has an average altitude of 2906 m a.s.l. and at present the 25% of its surface is glacierized; the annual runoff regime is dominated by snow and ice melt. Direct mass balance measurements have been performed since 1967 on Careser glacier (2.83 km2) and since 2003 on La Mare glacier (3.97 km2). The AWS is mounted on a tripod which stands freely on the glacier surface and is solar-powered. The variables measured are: air temperature and relative humidity, wind speed and direction, shortwave and longwave incoming and outgoing radiation, precipitation and surface height. All the data are sampled at five-minute intervals as average values, with the exception of surface height which is sampled at hourly intervals, as instantaneous values. The collected data were used to calculate the point energy and mass balance and to compare the results with similar investigations carried out on glaciers and available in literature. In particular, our attention has been focussed on some processes which regulate the response to climate changes. The relative importance of the energy balance components was examined and a clear predominance of shortwave radiation inputs was found to exist during melt conditions. Given the relevance of the shortwave net balance, the ice albedo temporal variability (values ranging from 0.1 to 0.5) has been investigated and correlated with meteorological variables. Furthermore, a

  15. Tree carbon allocation dynamics determined using a carbon mass balance approach.

    Science.gov (United States)

    Klein, Tamir; Hoch, Günter

    2015-01-01

    Tree internal carbon (C) fluxes between compound and compartment pools are difficult to measure directly. Here we used a C mass balance approach to decipher these fluxes and provide a full description of tree C allocation dynamics. We collected independent measurements of tree C sinks, source and pools in Pinus halepensis in a semi-arid forest, and converted all fluxes to g C per tree d(-1) . Using this data set, a process flowchart was created to describe and quantify the tree C allocation on diurnal to annual time-scales. The annual C source of 24.5 kg C per tree yr(-1) was balanced by C sinks of 23.5 kg C per tree yr(-1) , which partitioned into 70%, 17% and 13% between respiration, growth, and litter (plus export to soil), respectively. Large imbalances (up to 57 g C per tree d(-1) ) were observed as C excess during the wet season, and as C deficit during the dry season. Concurrent changes in C reserves (starch) were sufficient to buffer these transient C imbalances. The C pool dynamics calculated using the flowchart were in general agreement with the observed pool sizes, providing confidence regarding our estimations of the timing, magnitude, and direction of the internal C fluxes. © 2014 The Authors. New Phytologist © 2014 New Phytologist Trust.

  16. Nitrogen mass balance across pilot-scale algae and duckweed-based wastewater stabilisation ponds.

    Science.gov (United States)

    Zimmo, O R; van der Steen, N P; Gijzen, H J

    2004-02-01

    Nitrogen removal processes and nitrogen mass balances in algae-based ponds (ABPs) and duckweed (Lemna gibba)-based ponds (DBPs) were assessed during periods of 4 months, each under different operational conditions. During periods 1 and 2, the effect of cold and warm temperature was studied. During periods 2 and 3, the effect of low- and high-system organic loading (OL) was studied in warm seasons operation. The pilot-scale systems consisted of four similar ponds in series fed with domestic sewage with hydraulic retention time of 7 days in each pond. Overall nitrogen removal was higher during warm temperature in both ABPs and DBPs, but similar during periods 2 and 3. Nitrogen removal in DBPs was lower than in ABPs by 20%, 12% and 8% during cold temperature, warm temperature and high-OL periods, respectively. Depending on temperature and OL rate, ABPs showed higher nitrogen removal via sedimentation (46-245% higher) compared to DBPs. Also, ABPs also showed higher nitrogen removal via denitrification (7-37% higher) compared to DBPs. Ammonia volatilisation in both systems did not exceed 1.1% of influent total nitrogen during the entire experimental period. N uptake by duckweed corresponds to 30% of the influent nitrogen during warm/low OL period and decreased to 10% and 19% during the cold and warm/high OL period, respectively. Predictive models for nitrogen removal presented a good reflection of nitrogen fluxes on overall nitrogen balance under the prevailing experimental conditions.

  17. Mass balance inverse modelling of methane in the 1990s using a Chemistry Transport Model

    Science.gov (United States)

    Butler, T. M.; Simmonds, I.; Rayner, P. J.

    2004-12-01

    A mass balance inverse modelling procedure is applied with a time-dependent methane concentration boundary condition and a chemical transport model to relate observed changes in the surface distribution of methane mixing ratios during the 1990s to changes in its surface sources. The model reproduces essential features of the global methane cycle, such as the latitudinal distribution and seasonal cycle of fluxes, without using a priori knowledge of methane fluxes. A detailed description of the temporal and spatial variability of the fluxes diagnosed by the inverse procedure is presented, and compared with previously hypothesised changes in the methane budget, and previous inverse modelling studies. The sensitivity of the inverse results to the forcing data supplied by surface measurements of methane from the NOAA CMDL cooperative air sampling network is also examined. This work serves as an important starting point for future inverse modelling work examining changes in both the source and sink terms in the methane budget together.

  18. Mass balance inverse modelling of methane in the 1990s using a Chemistry Transport Model

    Directory of Open Access Journals (Sweden)

    T. M. Butler

    2004-01-01

    Full Text Available A mass balance inverse modelling procedure is applied with a time-dependent methane concentration boundary condition and a chemical transport model to relate observed changes in the surface distribution of methane mixing ratios during the 1990s to changes in its surface sources. The model reproduces essential features of the global methane cycle, such as the latitudinal distribution and seasonal cycle of fluxes, without using a priori knowledge of methane fluxes. A detailed description of the temporal and spatial variability of the fluxes diagnosed by the inverse procedure is presented, and compared with previously hypothesised changes in the methane budget, and previous inverse modelling studies. The sensitivity of the inverse results to the forcing data supplied by surface measurements of methane from the NOAA CMDL cooperative air sampling network is also examined. This work serves as an important starting point for future inverse modelling work examining changes in both the source and sink terms in the methane budget together.

  19. Mass balance approach for assessment of pollution load in the Krishna River.

    Science.gov (United States)

    Sekhar, Chandra; Umamahesh, N V

    2004-04-01

    River Krishna in the Southern Peninsula of India is a typical receiving water body of both point and non-point discharges. Comparisons between upstream and downstream monitoring sites reveal changes in the concentrations and load to the river. This information is used to discriminate between point and non-point source contribution to pollution. The pre-monsoon and post-monsoon water quality and flow data are used to assess river pollution loads. The resulting differential loads, if adjusted for uncharacterized non-point source contribution may represent the total point loads to the river minus losses due to volatilization, sedimentation, adsorption and other physical, chemical and biological phenomena. The results of the mass balances indicate that non-point sources to be major contributors to the pollutant loads. The non-point sources in the study area predominantly include pollution due to agricultural practices and activities, soil erosion, dissolution of soil minerals or combination of these sources.

  20. Variability in winter mass balance of Northern Hemisphere glaciers and relations with atmospheric circulation

    Science.gov (United States)

    McCabe, G.J.; Fountain, A.G.; Dyurgerov, M.

    2000-01-01

    An analysis of variability in the winter mass balance (WMB) of 22 glaciers in the Northern Hemisphere indicates two primary modes of variability that explain 46% of the variability among all glaciers. The first mode of variability characterizes WMB variability in Northern and Central Europe and the second mode primarily represents WMB variability in northwestern North America, but also is related to variability in WMB of one glacier in Europe and one in Central Asia. These two modes of WMB variability are explained by variations in mesoscale atmospheric circulation which are driving forces of variations in surface temperature and precipitation. The first mode is highly correlated with the Arctic Oscillation Index, whereas the second mode is highly correlated with the Southern Oscillation Index. In addition, the second mode of WMB variability is highly correlated with variability in global winter temperatures. This result suggests some connection between global temperature trends and WMB for some glaciers.

  1. Mass balance and surface movement of the Greenland Ice Sheet at Summit, Central Greenland

    DEFF Research Database (Denmark)

    Hvidberg, C.S.; Keller, K.; Gundestrup, N.S.

    1997-01-01

    During the GRIP deep drilling in Central Greenland, the ice sheet topography and surface movement at Summit has been mapped with GPS. Measurements of the surface velocity are presented for a strain net consisting of 13 poles at distances of 25-60 km from the GRIP site. Some results are: The GRIP...... site is located approximately 2 km NW of the topographic summit; the surface velocity at the GISP 2 site is 1.7 m/yr in the W direction. The present mass balance at Summit is calculated to be -0.03+/-0.04 m/yr, i.e. close to steady state. This result is the best now available for Summit. A small...... thinning rate might be a transient response of the Greenland Ice Sheet due to the temperature increase at the Wisconsin-Holocene transition....

  2. Soil test phosphorus dynamics in animal waste amended soils: using P mass balance approach.

    Science.gov (United States)

    Shafqat, Mustafa N; Pierzynski, Gary M

    2013-01-01

    Soil test phosphorus (STP) is commonly used for phosphorus (P) fertilizer recommendations in agriculture and in risk assessment of offsite P movement from environmental perspectives. Present guidelines do not differentiate between the P sources and assume that P added to the soil would behave alike. The objective of this study was to understand the influence of different animal P sources applied at three different rates on changes in STP in many different soils using P mass balance approach. Six P sources consisting of three types of monogastric, two ruminant and triple super phosphate (TSP) applied at 0, 50, and 150 mg P kg(-1) in six different soils. Corn (Zea mays L.) was used to remove P and total of seven harvests were achieved. The STP (Bray 1P) was monitored at T(0) and after each harvest and relationship was developed between STP and net P addition/removal to compute the slope. Prior to crop P removal, the Turkey (Meleagris gallopava) litter (TL) produced the smallest slope at both rates and across all soils. Most P sources resulted large slope values in the Woodson soil. The slope value progressively decreased from higher rate to lower rate to the control treatment in P mass balance study. Soil clay content, initial STP, soil pH, and soil organic matter levels were involved in explaining variations in slope value in TL, while initial STP and clay content in Hog (Sus scrofa) manure (HM) and biosolid (SS) amended soils in net P addition/removal study. Copyright © 2012 Elsevier Ltd. All rights reserved.

  3. Sea Ice Mass Balance Buoys (IMBs): First Results from a Data Processing Intercomparison Study

    Science.gov (United States)

    Hoppmann, Mario; Tiemann, Louisa; Itkin, Polona

    2017-04-01

    IMBs are autonomous instruments able to continuously monitor the growth and melt of sea ice and its snow cover at a single point on an ice floe. Complementing field expeditions, remote sensing observations and modelling studies, these in-situ data are crucial to assess the mass balance and seasonal evolution of sea ice and snow in the polar oceans. Established subtypes of IMBs combine coarse-resolution temperature profiles through air, snow, ice and ocean with ultrasonic pingers to detect snow accumulation and ice thermodynamic growth. Recent technological advancements enable the use of high-resolution temperature chains, which are also able to identify the surrounding medium through a „heating cycle". The temperature change during this heating cycle provides additional information on the internal properties and processes of the ice. However, a unified data processing technique to reliably and accurately determine sea ice thickness and snow depth from this kind of data is still missing, and an unambiguous interpretation remains a challenge. Following the need to improve techniques for remotely measuring sea ice mass balance, an international IMB working group has recently been established. The main goals are 1) to coordinate IMB deployments, 2) to enhance current IMB data processing and -interpretation techniques, and 3) to provide standardized IMB data products to a broader community. Here we present first results from two different data processing algorithms, applied to selected IMB datasets from the Arctic and Antarctic. Their performance with regard to sea ice thickness and snow depth retrieval is evaluated, and an uncertainty is determined. Although several challenges and caveats in IMB data processing and -interpretation are found, such datasets bear great potential and yield plenty of useful information about sea ice properties and processes. It is planned to include many more algorithms from contributors within the working group, and we explicitly invite

  4. Surface Mass Balance Distributions: Downscaling of Coarse Climates to drive Ice Sheet Models realistically

    Science.gov (United States)

    Rodehacke, Christian; Mottram, Ruth; Langen, Peter; Madsen, Marianne; Yang, Shuting; Boberg, Fredrik; Christensen, Jens

    2017-04-01

    The surface mass balance (SMB) is the most import boundary conditions for the state of glaciers and ice sheets. Hence its representation in numerical model simulations is of highest interest for glacier, ice cap and ice sheet modeling efforts. While descent SMB distributions of the current climate could be interfered with the help of various observation techniques and platforms, its construction for older past and future climates relies on input from spatially coarse resolved global climate models or reconstructions. These coarse SMB estimates with a footprint in the order of 100 km could hardly resolve the marginal ablations zones where the Greenland ice sheets, for instance, loses snow and ice. We present a downscaling method that is based on the physical calculation of the surface mass and energy balance. By the consequent application of universal and computationally cheap parameterizations we get an astonishing good representation of the SMB distribution including its marginal ablation zone. However the method has its limitations; for example wrong accumulation rates due to an insufficient precipitation field leaves its imprint on the SMB distribution. Also the still not satisfactory description of the bare ice albedo, in particular, in parts of Greenland is a challenge. We inspect our Greenland SMB fields' for various forcings and compare them with some widely used reference fields in the community to highlight the weakness and strength of our approach. We use the ERA-Interim reanalyzes period starting in 1979 directly as well as dynamically downscaled by our regional climate model HIRHAM (5 km resolution). Also SMB distributions obtained from the climate model EC-Earth with a resolution of T159 (approx. 125 km resolution in Greenland) are used either directly or downscaled with our regional climate model HIRHAM. Model-based End-of-the-century SMB estimates give an outlook of the future.

  5. Source identification and mass balance studies of mercury in Lake An-dong, S. Korea

    Science.gov (United States)

    Han, J.; Byeon, M.; Yoon, J.; Park, J.; Lee, M.; Huh, I.; Na, E.; Chung, D.; Shin, S.; Kim, Y.

    2009-12-01

    In this study, mercury and methylmercury were measured in atmospheric, tributary, open-lake water column, sediment, planktons and fish samples in the catchments area of Lake An-dong, S. Korea. Lake An-dong, an artificial freshwater lake is located on the upstream of River Nak-dong. It has 51.5 km2 of open surface water and 1.33 year of hydraulic residence time. It is a source of drinking water for 0.3 million S. Koreans. Recently, the possibilities of its mercury contamination became an issue since current studies showed that the lake had much higher mercury level in sediment and certain freshwater fish species than any other lakes in S. Korea. This catchments area has the possibilities of historical mercury pollution by the location of more than 50 abandoned gold mines and Young-poong zinc smelter. The objective of this study was to develop a mercury mass balance and identify possible mercury sources in the lake. The results of this study are thus expected to offer valuable insights for the sources of mercury loading through the watershed. In order to estimate the mercury flux, TGM, RGM and particulate mercury were measured using TEKRAN 2537 at the five sites surrounding Lake An-dong from May, 2009 with wet and dry deposition. The fate and transport of mercury in water body were predicted by using EFDC (Environmental Dynamic Fluid Code) and Mercury module in WASP7 (Water quality analysis program) after subsequent distribution into water body, sediments, followed by bioaccumulation and ultimate uptake by humans. The mercury mass balance in Young-poong zinc smelter was also pre-estimated by measuring mercury content in zinc ores, emission gases, sludge, wastewater and products.

  6. Climatic Forcing of Glacier Surface Mass Balance Changes Along North-Central Peru: A Modeling Perspective

    Science.gov (United States)

    Mark, B. G.; Fernandez, A.

    2015-12-01

    Most tropical glaciers are Peru, where they are key water sources for communities in mountain environments and beyond. Thus, their sustained shrinkage portrays these glaciers as archetype of global warming impacts on the local scale. However, there is still no deep understanding on the mechanism connecting temperature and these glaciers. Among others, the effect of temperature on the glacier surface mass balance (GSMB) can be expressed within accumulation regimes and hence in surface albedo, or in ablation dynamics through incoming longwave energy (LE). Here, we report a study combining statistical analyses of reanalysis data (~30km grid-cell), regional climate modeling and glacier mass balance simulations at high resolution (2km) to analyze long-term (30 years) and seasonal GSMB along north-central Peru. Our goal is to mechanistically understand climate change impact on these glaciers. Results suggest temperature as the main factor controlling GSMB changes through the lapse rate (LR). Correlations of GSMB with LR, humidity and zonal wind point to vertical homogenization of temperature, causing LE to increase, despite this flux always remaining negative. This "less negative" LE multiplies the impact of the seasonal fluctuation in albedo, thereby enhancing total ablation. As this mechanism only needs a relative increase in temperature, it may even occur in subfreezing conditions. Model output also indicates that turbulent fluxes are small, largely cancelling out. This suggests that the impact of LE is more likely to occur compared to either turbulent fluxes changes or shifts in the proportion of sublimation versus melt, which we find to be regionally stable. These findings imply that glaciers in north-central Peru are sensitive to subtle changes in temperature. We discuss the implications for process-based understanding and how this non-linear and somewhat hidden effect of temperature reduces the skill of temperature index models to simulate GSMB in the Tropics.

  7. Mass balance investigation of perfluorooctanoic acid PFOA environmental levels, emissions and sinks in the northern hemisphere

    Energy Technology Data Exchange (ETDEWEB)

    Cousins, I.T.; Prevedouros, K. [Stockholm Univ., Stockholm (Sweden); Buck, R.C.; Korzeniowski, S.H. [Dupont Chemical Solutions, Wilmington, DE (United States)

    2005-07-01

    Perfluoroalkyl sulfonic acids (PFAS) and perfluoroalkyl carboxylic acids (PFCAs) and their precursors are found in a wide array of environmental samples, and have no known degradation mechanisms. PFCAs have been used for over 50 years as processing aids in the manufacture of fluoropolymers. PFASs and fluorotelomer products are used in a wide variety of products and industrial processes. This study provided a detailed account of direct and indirect sources of perfluorooctanoic acid (PFOA) in the environment. A mass balance investigation between sources and amounts residing in the northern hemisphere was conducted, and the magnitude of historical removal processes was estimated. It was hypothesized that the majority of historical PFOA production use, and emissions occurred in the northern hemisphere. The study considered both direct and indirect sources. Production and emissions were calculated from a number of published and unpublished chemical industry data. A mass balance computation was performed to estimate historical PFOA emissions with existing environmental levels and historical losses. A literature search was used to estimate representative PFOA levels in sediments and biota. The study confirmed the importance of surface water compartments for PFOA storage. Important sink processes included physical mixing and sedimentation to the deep oceans and sediment burial. Maximum and minimum ranges of the sum of the total environmental inventory and historical sink processes overlapped the ranges of emission estimates. It was concluded that a quantitative comparison of the atmospheric transport of PFOA precursors and the aquatic transport of the substances showed that ocean transport is the most significant transport routes of PFOAs. 13 refs., 1 tab., 1 fig.

  8. Rapid weight loss and the body fluid balance and hemoglobin mass of elite amateur boxers.

    Science.gov (United States)

    Reljic, Dejan; Hässler, Eike; Jost, Joachim; Friedmann-Bette, Birgit

    2013-01-01

    Dehydration is assumed to be a major adverse effect associated with rapid loss of body mass for competing in a lower weight class in combat sports. However, the effects of such weight cutting on body fluid balance in a real-life setting are unknown. To examine the effects of 5% or greater loss of body mass within a few days before competition on body water, blood volume, and plasma volume in elite amateur boxers. Case-control study. Sports medicine laboratory. Seventeen male boxers (age = 19.2 ± 2.9 years, height = 175.1 ± 7.0 cm, mass = 65.6 ± 9.2 kg) were assigned to the weight-loss group (WLG; n = 10) or the control group (CON; n = 7). The WLG reduced body mass by restricting fluid and food and inducing excessive sweat loss by adhering to individual methods. The CON participated in their usual precompetition training. During an ordinary training period (t-1), 2 days before competition (t-2), and 1 week after competition (t-3), we performed bioelectrical impedance measurements; calculated total body water, intracellular water, and extracellular water; and estimated total hemoglobin mass (tHbmass), blood volume, and plasma volume by the CO-rebreathing method. In the WLG, the loss of body mass (5.6% ± 1.7%) led to decreases in total body water (6.0% ± 0.9%), extracellular water (12.4% ± 7.6%), tHbmass (5.3% ± 3.8%), blood volume (7.6% ± 2.1%; P .05). At t-3, total body water, extracellular water, and plasma volume had returned to near baseline values, but tHbmass and blood volume still were less than baseline values (P .05). In a real-life setting, the loss of approximately 6% body mass within 5 days induced hypohydration, which became evident by the decreases in body water and plasma volume. The reduction in tHbmass was a surprising observation that needs further investigation.

  9. Mass balance of a highly active rock glacier during the period 1954 and 2016

    Science.gov (United States)

    Kellerer-Pirklbauer, Andreas; Kaufmann, Viktor; Rieckh, Matthias

    2017-04-01

    Active rock glaciers are creep phenomena of permafrost in high-relief terrain moving slowly downwards and are often characterised by distinct flow structures with ridges and furrows. Active rock glaciers consist of ice and rock material. The ice component might be either congelation (refreezing of liquid water) or sedimentary ('glacier') ice whereas the rock material might be either of periglacial or glacial origin. The formation period of rock glaciers lasts for centuries to millennia as judged from relative or absolute dating approaches. The input of ice and debris onto the rock glacier mass transport system over such long periods might change substantially over time. Long-term monitoring of mass transport, mass changes and nourishment processes of rock glaciers are rare. In this study we analysed on a decadal-scale mass transport (based on photogrammetric and geodetic data; series 1969-2016), mass changes (geodetically-based mass balance quantification; series 1954-2012), and mass input (based on optical data from an automatic digital camera; series 2006-2016) onto the Hinteres Langtal Rock Glacier. This rock glacier is 900 m long, up to 300 m wide, covers an area of 0.17 km2 and is one of the most active ones in the Eastern European Alps. Mass transport rates at the surface indicate relatively low mean annual surface velocities until the beginning of this millennium. A first peak in the horizontal surface velocity was reached in 2003/04 followed by a period of deceleration until 2007/08. Afterwards the rates increased again substantially from year to year with maximum values in 2014/15 (exceeding 6 m/a). This increase in surface velocities during the last decades was accompanied by crevasse formation and landslide activities at its front. Mass changes show for all six analysed periods between 1954 and 2012 a clear negative surface elevation change with mean annual values ranging from -0.016 to -0.058 m/a. This implies a total volume decrease of -435,895 m3

  10. Summer-time Mass Balance of Wolverine Glacier, Alaska, Derived from Ground-based Time-lapse Microgravity Measurements

    Science.gov (United States)

    Young, E. V.; Muto, A.; Babcock, E.

    2016-12-01

    Monitoring the mass balance of alpine glaciers is important because alpine glaciers presently account for about half of the cryospheric contribution to the global sea-level rise. Mass balance measurements of alpine glaciers have predominantly relied upon glaciological and hydrological methods. However, these methods can be logistically costly and have potential extrapolation errors. Remote sensing approaches, such as gravimetric methods using data from GRACE satellite missions, have provided monthly mass-balance estimates of aggregates of alpine glaciers but their spatial resolution is far too large for studying a single glacier. On the other hand, ground-based time-lapse microgravity geophysical measurements can potentially circumvent some of the disadvantages of the glaciological and hydrological methods. It may detect the change in a single glacier's mass and its spatial distribution. We conducted ground-based time-lapse microgravity surveys on Wolverine Glacier, Alaska, in May and August of 2016, using a Scintrex CG-5 Autograv gravimeter. We collected data at seventy-nine individual stations on the glacier, roughly five stations per square kilometer. We included repeat-station and base-station measurements made at least twice a day for instrumental drift control. The uncertainty of our gravity measurements is better than 0.03 mGal, which is about 0.7 meters water equivalent of surface mass balance. Our summer-time mass balance of Wolverine Glacier determined from the time-lapse gravity measurements is independent of that derived from the stake-network or stream-gauge measurements, and could provide spatial insight into the mass balance process on Wolverine Glacier and similar glaciers.

  11. Detailed comparison of the geodetic and direct glaciological mass balances on an annual time scale at Hintereisferner, Austria

    Science.gov (United States)

    Klug, Christoph; Bollmann, Erik; Galos, Stephan; Kaser, Georg; Prinz, Rainer; Rieg, Lorenzo; Sailer, Rudolf

    2016-04-01

    The quantification of glacier mass changes is fundamental for glacier monitoring and provides important information for climate change assessments, hydrological applications and sea-level changes. On Alpine glaciers two methods of measuring glacier mass changes are widely applied: the direct glaciological method and the geodetic method. Over the last decades several studies compared the mass balance estimates obtained by both methods to identify and correct stochastic and systematic errors. In almost all of these studies, the time span for comparison between the two methods is about one decade or longer. On Hintereisferner (HEF; Ötztal Alps, Austria) mass balance measurements were initiated in the glaciological year 1952/53, resulting in a consistent mass balance data set with an estimated accuracy of ±0.2 m w.e. a-1. Furthermore, 11 airborne laser scanning (ALS) campaigns were conducted between 2001 and 2011 at HEF, all consistent in accuracy as well as in precision (± 0.04 to 0.10 m for slopes ≤ 50°). This is a world-wide unique ALS dataset of a glacierized alpine catchment. Flight campaigns were performed close to the end of the hydrological year (30th September). Resulting data provide high quality topographic information to derive glacier mass changes by applying the geodetic method. On sub-decadal time-scales such method comparisons are rare, or reveal unexplainable large discrepancies between both mass balance methods. In this study we estimate stochastic and systematic uncertainties of the ALS data for processing volume changes, and quantify methodological differences, such as density assumptions, unequal measurement dates, crevasses and glacier dynamics. Hence, we present a method to compare direct glaciological and geodetic mass balances on an annual basis. In a first step, we calculate the annual geodetic mass balance of HEF between 2001 and 2011, resulting in a thickness change map of the glacier. In a second step, the snow cover, which has

  12. Mass balance monitoring of geological CO2 storage with a superconducting gravimeter - A case study

    Science.gov (United States)

    Kim, Jeong Woo; Neumeyer, Juergen; Kao, Ricky; Kabirzadeh, Hojjat

    2015-03-01

    Although monitoring of geological carbon dioxide (CO2) storage is possible with a number of geophysical and geodetic techniques (e.g., seismic survey), gravimetric monitoring is known to be the most accurate method for measuring total mass changes. Therefore, it can be used for detection of storage pore space content changes and migration of CO2 plumes. A superconducting gravimeter (SG) installed on the Earth's surface provides precise and continuous records of gravity variations over time for periods from minutes to decades, which are required for monitoring subsurface CO2 storage. Due to the fact that gravimeter records combine the gravity effects of surface displacement and subsurface mass change, these two effects must be separated properly for observing CO2 mass balance. The Newtonian attraction gravity effect of stored CO2 is modeled as a function of reservoir depth and CO2 mass for different locations of the gravimeter over the reservoir. The gravity effect of the surface deformation is considered according to the modeled and measured displacement above the CO2 reservoir at the gravimeter's position. For estimation of the detection threshold, an assessment is carried out for the gravity corrections, which must be subtracted from the raw gravity data before obtaining the gravity signal of the stored CO2. A CO2 signal larger than about 0.5 μGal can be detected with an SG's continuous recordings. A measured gravity profile along the reservoir can support the continuous measurements. For providing objective evidence of a CO2 stored gravity signal, real measured raw SG gravity data of the MunGyung site in Korea were superimposed with an artificial uniformly continuous gravity signal up to 1.7 μGal, representing a gravity signal from a CO2 storage site with increasing injections up to about 105 kt at a depth of 600 m. These data were analyzed, and the CO2 storage signal could be clearly identified.

  13. 10Be/9Be Evidence For Stable Quaternary Weathering Fluxes and Carbon Cycle Mass Balance

    Science.gov (United States)

    von Blanckenburg, F.; Bouchez, J.; Ibarra, D. E.; Maher, K.

    2016-12-01

    Removal of atmospheric CO2 by silicate weathering is thought to have balanced the inputs of carbon to within 2% of net CO2 degassing when averaged over the last 600 kyr [1]. Small imbalances, of 0.0-0.5%/Myr (relative to modern inputs) are also thought to characterize the Cenozoic carbon cycle [2]. However, due to the lack of proxies that directly quantify past weathering fluxes, our ability to test these hypotheses has been limited. Moreover, we do not know whether imbalances between CO2 outgassing and withdrawal have prevailed within Quaternary glacial-interglacial oscillations [1]. Relative changes in silicate weathering fluxes can be estimated from the ratio of cosmogenic beryllium-10, produced in the atmosphere, to the stable isotope beryllium-9, introduced into the oceans by the riverine silicate weathering flux. The ratio is preserved by the authigenic phase of well-dated marine sedimentary records [3]. We show that over multiple glacial-interglacial cycles, shifts in global silicate weathering inputs are not detectable beyond the ca. 10% resolution of the proxy, even in areas close to glacial erosion [4]. Hence it is likely that CO2 fluxes were also balanced within a given glacial cycle [1]. Well-dated records also indicate that over the last 2 Myr weathering inputs were constant on average. Because over >10kyr time scales the 10Be/9Be dates the weathering front advance rates, the ratio provides evidence that global weathering rates did not shift during the last 10 Myr [5]. Collectively, the 10Be/9Be supports stable weathering fluxes, and assuming relatively constant degassing rates, balanced CO2 fluxes over these multiple time scales. [1] Zeebe, R.E. and Caldeira, K., 2008. Close mass balance of long-term carbon fluxes from ice-core CO2 and ocean chemistry records. Nat. Geosc., 1. [2] Caves, J.K., et al.., 2016. Cenozoic carbon cycle imbalances and a variable weathering feedback. EPSL, 450. [3] von Blanckenburg, F. and Bouchez, J., 2014. River fluxes to

  14. The Alteration History of Clovis Class Rocks in Gusev Crater as Determined by Ti-Normalzed Mass Balance Analysis

    Science.gov (United States)

    Sutter, Brat; Ming, Douglas W.; Niles, P. B.; Golden, D. C.

    2012-01-01

    The West Spur Clovis class rocks in Gusev Crater are some of the most altered rocks in Gusev Crater and likely contain a mixed sulfate and phyllosilicate mineralogy [1,2]. The high S and Cl content of the Clovis rocks suggests that acidic vapors or fluids of H2SO4 and HCl reacted with the Clovis parent rock to form Ca, Mg,- sulfates, iron-oxyhydroxides and secondary aluminosilicates (approx.60 wt.%) of a poorly crystalline nature (e.g., allophane) [1]. Up to 14-17 wt.% phyllosilicates (e.g., kaolinite, chlorite, serpentine) are hypothesized to exist in the Clovis materials suggesting that Clovis parent materials while possibly exposed to acidic pHs were likely neutralized by basalt dissolution which resulted in mildly acidic pHs (4-6) [1, 2]. This work proposes that subsequent to the alteration of the Clovis rocks, alteration fluids became concentrated in ions resulting in the addition of silicate and salts. The objective of this work is to utilize Ti-normalized mass balance analysis to evaluate (1) mineral gains and losses and (2) elemental gains and losses in the Clovis rocks. Results of this work will be used evaluate the nature of geochemical conditions that affect phyllosilicate and sulfate formation at Gusev crater.

  15. Evaluating the potential for environmental pollution from chromated copper arsenate (CCA)-treated wood waste: a new mass balance approach.

    Science.gov (United States)

    Mercer, T G; Frostick, L E

    2014-07-15

    The potential for pollution from arsenic, chromium and copper in chromated copper arsenate (CCA) treated wood waste was assessed using two lysimeter studies. The first utilised lysimeters containing soil and CCA wood waste mulch exposed to natural conditions over a five month period. The second study used the same lysimeter setup in a regulated greenhouse setting with a manual watering regime. Woodchip, soil and leachate samples were evaluated for arsenic, chromium and copper concentrations. Resultant concentration data were used to produce mass balances, an approach thus far unused in such studies. This novel analysis revealed new patterns of mobility and distribution of the elements in the system. The results suggest that CCA wood waste tends to leach on initial exposure to a leachant and during weathering of the wood. When in contact with soil, metal(loid) transport is reduced due to complexation reactions. With higher water application or where the adsorption capacity of the soil is exceeded, the metal(loid)s are transported through the soil column as leachate. Overall, there was an unexplained loss of metal(loid)s from the system that might be attributed to volatilisation of arsenic and plant uptake. This suggests a hitherto unidentified risk to both the environment and human health. Copyright © 2014 Elsevier B.V. All rights reserved.

  16. Neutrinoless double beta nuclear matrix elements around mass 80 in the nuclear shell-model

    Directory of Open Access Journals (Sweden)

    Yoshinaga N.

    2015-01-01

    Full Text Available The observation of the neutrinoless double-beta decay can determine whether the neutrino is a Majorana particle or not. For theoretical nuclear physics it is particularly important to estimate three types of matrix elements, namely Fermi (F, Gamow-Teller (GT, and tensor (T matrix elements. In this paper, we carry out shell-model calculations and also pair-truncated shell-model calculations to check the model dependence in the case of mass A=82 nuclei.

  17. Re-assessment of recent (2008–2013 surface mass balance over Dome Argus, Antarctica

    Directory of Open Access Journals (Sweden)

    Minghu Ding

    2016-04-01

    Full Text Available At Dome Argus, East Antarctica, the surface mass balance (SMB from 2008 to 2013 was evaluated using 49 stakes installed across a 30×30 km area. Spatial analysis showed that at least 12 and 20 stakes are needed to obtain reliable estimates of SMB at local scales (a few hundred square metres and regional scales (tens of square kilometres, respectively. The estimated annual mean SMB was 22.9±5.9 kg m−2 yr−1, including a net loss by sublimation of −2.22±0.02 kg m−2 yr−1 and a mass gain by deposition of 1.37±0.01 kg m−2 yr−1. Therefore, ca. 14.3% of precipitation was modified after deposition, which should be considered when interpreting snow or ice core records produced by future drilling projects. The surface snow density and SMB in the western portion of Dome Argus are higher than in other areas, and these differences are likely related to the katabatic wind, which is strengthened by topography in this sector. A new digital elevation model (DEM of Dome Argus was generated, confirming that both peaks of the dome can be considered as the summit of the East Antarctic Ice Sheet. Findings from this study should be valuable for validating SMB estimates obtained from regional climate models and DEMs established using remote-sensing data.

  18. Radionuclide mass balance for the TMI-2 accident: data through 1979 and preliminary assessment of uncertainties

    Energy Technology Data Exchange (ETDEWEB)

    Davis, R J; Tonkay, D W; Vissing, E A; Nguyen, T D; Shawn, L W; Goldman, M I

    1984-11-01

    A systematic data base of available information needed to calculate mass balances of key radionuclides arising from the Three-Mile Island Unit 2 (TMI-2) accident as a function of time has been assembled. The sample and analysis data represent the likely major sinks except for the solids remaining in the primary system. Surfaces in the primary system are represented only by preliminary data pertaining to cesium deposition on plenum surfaces. TMI-2 component description data are included for the reactor coolant, makeup and purification, and liquid waste systems and the reactor building. The chronology of liquid transfers through the end of 1979 is included. A mass transfer model has been developed. It is concluded that tritium and cesium released into the reactor coolant traveled with the reactor coolant without losses to other phases during transit and storage. The data also suggest that tritium and cesium were not leached from primary solids and surfaces after the accident, although strontium has gradually leached from the primary solids and surfaces over a long period. Much of the iodine transferred to the reactor building sump/basement is suspected of having transferred to surfaces or solids from the sump/basement water and was therefore not found in basement water samples.

  19. Development of a Water and Enthalpy Budget-based Glacier mass balance Model (WEB-GM) and its preliminary validation

    Science.gov (United States)

    Ding, Baohong; Yang, Kun; Yang, Wei; He, Xiaobo; Chen, Yingying; Lazhu; Guo, Xiaofeng; Wang, Lei; Wu, Hui; Yao, Tandong

    2017-04-01

    This paper presents a new water and energy budget-based glacier mass balance model. Enthalpy, rather than temperature, is used in the energy balance equations to simplify the computation of the energy transfers through the water phase change and the movement of liquid water in the snow. A new parameterization for albedo estimation and state-of-the-art parameterization schemes for rainfall/snowfall type identification and surface turbulent heat flux calculations are implemented in the model. This model was driven with meteorological data and evaluated using mass balance and turbulent flux data collected during a field experiment implemented in the ablation zone of the Parlung No. 4 Glacier on the Southeast Tibetan Plateau during 2009 and 2015-2016. The evaluation shows that the model can reproduce the observed glacier ablation depth, surface albedo, surface temperature, sensible heat flux, and latent heat flux with high accuracy. Comparing with a traditional energy budget-based glacier mass balance model, this enthalpy-based model shows a superior capacity in simulation accuracy. Therefore, this model can reasonably simulate the energy budget and mass balance of glacier melting in this region and be used as a component of land surface models and hydrological models.

  20. Making geodetic glacier mass balances available to the community - Progress and challenges in modifying the WGMS database

    Science.gov (United States)

    Machguth, Horst; Landmann, Johannes; Zemp, Michael; Paul, Frank

    2017-04-01

    The recent years have seen a sharp increase in the publication of geodetically derived glacier mass balances. Internationally coordinated glacier monitoring, however, has so far focused mainly on direct glaciological mass balance measurements. There is thus a need to collect geodetic glacier mass balance data in a standardized format and make the data available to the scientific community. This would allow easy access and data use for, e.g., assessment of regional to global scale glacier changes, re-analysis of glaciological mass balance series, evaluation of and comparison to, other data or model results. It appears logical to build such a data archive where glaciological data are already routinely collected. In the framework of the ESA project Glaciers_cci, the World Glacier Monitoring Service (WGMS) has started an initiative to establish the expertise, the strategy and the infrastructure to make the increasing amount of geodetic glacier mass balance available to the scientific community. The focus is (i) on geodetic (glacier wide) changes as obtained from differencing digital elevation models from two epochs, and (ii) on point elevation change from altimetry. Here we outline the chosen strategy to include gridded data of surface elevation change into the WGMS database. We describe the basic strategy using the netCDF4 data format, summarize the data handling as well as the standardization and discuss major challenges in efficient inclusion of geodetic glacier changes into the WGMS database. Finally, we discuss the potential use of the data and thereby highlight how the added geodetic data influence the calculation of regional to global averages of glacier mass balance.

  1. Mass, energy and material balances of SRF production process. Part 3: solid recovered fuel produced from municipal solid waste.

    Science.gov (United States)

    Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne

    2015-02-01

    This is the third and final part of the three-part article written to describe the mass, energy and material balances of the solid recovered fuel production process produced from various types of waste streams through mechanical treatment. This article focused the production of solid recovered fuel from municipal solid waste. The stream of municipal solid waste used here as an input waste material to produce solid recovered fuel is energy waste collected from households of municipality. This article presents the mass, energy and material balances of the solid recovered fuel production process. These balances are based on the proximate as well as the ultimate analysis and the composition determination of various streams of material produced in a solid recovered fuel production plant. All the process streams are sampled and treated according to CEN standard methods for solid recovered fuel. The results of the mass balance of the solid recovered fuel production process showed that 72% of the input waste material was recovered in the form of solid recovered fuel; 2.6% as ferrous metal, 0.4% as non-ferrous metal, 11% was sorted as rejects material, 12% as fine faction and 2% as heavy fraction. The energy balance of the solid recovered fuel production process showed that 86% of the total input energy content of input waste material was recovered in the form of solid recovered fuel. The remaining percentage (14%) of the input energy was split into the streams of reject material, fine fraction and heavy fraction. The material balances of this process showed that mass fraction of paper and cardboard, plastic (soft) and wood recovered in the solid recovered fuel stream was 88%, 85% and 90%, respectively, of their input mass. A high mass fraction of rubber material, plastic (PVC-plastic) and inert (stone/rock and glass particles) was found in the reject material stream. © The Author(s) 2014.

  2. SITE-94. Natural elemental mass movement in the vicinity of the Aespoe Hard Rock Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Miller, W.M.; Smith, G.M.; Towler, P.A.; Savage, D. [QuantiSci, Melton Mowbray (United Kingdom)

    1997-05-01

    The primary objective of this study is to quantify natural elemental fluxes at a location exhibiting typical characteristics of a site for a spent fuel repository in Sweden. The relevant pathways are considered to be: Groundwater transport; Glacial erosion; Non-glacial weathering; River transport. Calculations are made of elemental mass fluxes from a volume of rock equivalent to that which would hold a KBS-3 style repository. In addition, the radioactive flux associated with the natural series radionuclide mass fluxes from the repository are also calculated. These can be compared directly to performance assessment predictions of the releases from a repository. 88 refs, 13 figs, 24 tabs.

  3. Status of the naval research laboratory trace element accelerator mass spectrometer: Characterization of the Pretzel magnet

    Science.gov (United States)

    Knies, D. L.; Grabowski, K. S.; Hubler, G. K.; Treacy, D. J.; DeTurck, T. M.; Enge, H. A.

    1997-02-01

    A novel design for a trace element accelerator mass spectrometer has been developed at the Naval Research Laboratory and is now under construction. It will allow parallel analysis of a broad range of impurities in electronic, biological, and geological materials. The system includes a modified commercial secondary ion mass spectrometer (Physical Electronics, model 6300) as the source of secondary ions, a recombinator consisting of a Pretzel magnet that serves as a tunable notch mass filter, a 3MV Pelletron tandem accelerator, a large electrostatic analyzer, and a split-pole magnetic spectrograph with a 1.5-m-long focal plane. All other ion optical and steering elements are electrostatic, to maintain parallel transmission of different mass species. This paper summarizes the design concept, and describes in some detail the characteristics of the Pretzel magnet.

  4. MASS BALANCE: A KEY TO ADVANCING MONITORED AND ENHANCED ATTENUATION FOR CHLORINATED SOLVENTS

    Energy Technology Data Exchange (ETDEWEB)

    Looney, B; Karen Vangelas, K; Karen-M Adams, K; Francis H. Chappelle; Tom O. Early; Claire H. Sink

    2006-06-30

    Monitored natural attenuation (MNA) and enhanced attenuation (EA) are two environmental management strategies that rely on a variety of attenuation processes to degrade or immobilize contaminants and are implemented at appropriate sites by demonstrating that contaminant plumes have low risk and are stable or shrinking. The concept of a mass balance between the loading and attenuation of contaminants in a groundwater system is a powerful framework for conceptualizing and documenting the relative stability of a contaminant plume. As a result, this concept has significant potential to support appropriate implementation of monitored natural attenuation (MNA) and enhanced attenuation (EA). For mass balance to be useful in engineering practice, however, it is necessary to quantify it in practical ways that facilitate overall site remediation and which are consistent with existing regulatory guidance. Two divergent philosophies exist for quantifying plume stability--empirical and deterministic. The first relies on historical contaminant concentration data and bulk geochemical information from a monitoring well network and documents plume stability using trend analysis and statistical tools. This empirical approach, when feasible, provides powerful and compelling documentation of plume behavior and mass balance. It provides an interpretation on a relevant scale under field conditions. It integrates the operative attenuation processes measured by observing their actual impact on the plume. The power of the empirical approach was recognized early in the development of MNA guidance and protocols and it is currently the basis of the three lines of evidence used in MNA studies. The empirical approach has some weaknesses, however. It requires a relatively long period of undisturbed historical data. Thus it cannot be effectively applied to sites where active remediation was initiated quickly and is currently operating. It cannot be used as a tool to determine how much source

  5. Evaluation of optimization methods for solving the receptor model for chemical mass balance

    Directory of Open Access Journals (Sweden)

    Anu N.

    2015-01-01

    Full Text Available Balance (CMB model has been extensively used in order to determine source contribution for particulate matters (size diameters less than 10 μm and 2.5 μm in the air quality analysis. A comparison of the source contribution estimated from the three CMB models (CMB 8.2, CMB-fmincon and CMB-GA have been carried out through optimization techniques such as ‘fmincon’ (CMB-fmincon and genetic algorithm (CMB-GA using MATLAB. The proposed approach has been validated using San Joaquin Valley Air Quality Study (SJVAQS California Fresno and Bakersfield PM10 and PM2.5 followed with Oregon PM10 data. The source contribution estimated from CMB-GA was better in source interpretation in comparison with CMB8.2 and CMB-fmincon. The performance accuracy of three CMB approaches were validated using R-square, reduced chi-square and percentage mass tests. The R-square (0.90, 0.67 and 0.81, 0.83, Chi-square (0.36, 0.66 and 0.65, 0.43 and percentage mass (67.36 %, 55.03 % and 94.24 %, 74.85 % of CMB-GA showed high correlation for PM10, PM2.5 Fresno and Bakersfield data respectively. To make a complete decision, the proposed methodology has been bench marked with Portland, Oregon PM10 data with best fit with R2 (0.99, Chi-square (1.6 and percentage mass (94.4 % from CMB-GA. Therefore, the study revealed that CMB with genetic algorithm optimization method holds better stability in determining the source contributions.

  6. Three loop massive operator matrix elements and asymptotic Wilson coefficients with two different masses

    Science.gov (United States)

    Ablinger, J.; Blümlein, J.; De Freitas, A.; Hasselhuhn, A.; Schneider, C.; Wißbrock, F.

    2017-08-01

    Starting at 3-loop order, the massive Wilson coefficients for deep-inelastic scattering and the massive operator matrix elements describing the variable flavor number scheme receive contributions of Feynman diagrams carrying quark lines with two different masses. In the case of the charm and bottom quarks, the usual decoupling of one heavy mass at a time no longer holds, since the ratio of the respective masses, η = mc2/mb2 ∼ 1 / 10, is not small enough. Therefore, the usual variable flavor number scheme (VFNS) has to be generalized. The renormalization procedure in the two-mass case is different from the single mass case derived in [1]. We present the moments N = 2 , 4 and 6 for all contributing operator matrix elements, expanding in the ratio η. We calculate the analytic results for general values of the Mellin variable N in the flavor non-singlet case, as well as for transversity and the matrix element Agq(3). We also calculate the two-mass scalar integrals of all topologies contributing to the gluonic operator matrix element Agg. As it turns out, the expansion in η is usually inapplicable for general values of N. We therefore derive the result for general values of the mass ratio. From the single pole terms we derive, now in a two-mass calculation, the corresponding contributions to the 3-loop anomalous dimensions. We introduce a new general class of iterated integrals and study their relations and present special values. The corresponding functions are implemented in computer-algebraic form.

  7. Three loop massive operator matrix elements and asymptotic Wilson coefficients with two different masses

    Energy Technology Data Exchange (ETDEWEB)

    Ablinger, J.; Hasselhuhn, A.; Schneider, C. [Johannes Kepler Univ., Linz (Austria). Research Inst. for Symbolic Computation (RISC); Bluemlein, J.; Freitas, A. de [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany); Wissbrock, F. [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany); Johannes Kepler Univ., Linz (Austria). Research Inst. for Symbolic Computation (RISC); IHES, Bures-sur-Yvette (France)

    2017-05-15

    Starting at 3-loop order, the massive Wilson coefficients for deep-inelastic scattering and the massive operator matrix elements describing the variable flavor number scheme receive contributions of Feynman diagrams carrying quark lines with two different masses. In the case of the charm and bottom quarks, the usual decoupling of one heavy mass at a time no longer holds, since the ratio of the respective masses, η=m{sup 2}{sub c}/m{sup 2}{sub b}∝1/10, is not small enough. Therefore, the usual variable flavor number scheme (VFNS) has to be generalized. The renormalization procedure in the two-mass case is different from the single mass case derived earlier (I. Bierenbaum, J: Bluemlein, S. Klein, 2009). We present the moments N=2,4 and 6 for all contributing operator matrix elements, expanding in the ratio η. We calculate the analytic results for general values of the Mellin variable N in the flavor non-singlet case, as well as for transversity and the matrix element A{sup (3)}{sub gq}. We also calculate the two-mass scalar integrals of all topologies contributing to the gluonic operator matrix element A{sub gg}. As it turns out, the expansion in η is usually inapplicable for general values of N. We therefore derive the result for general values of the mass ratio. From the single pole terms we derive, now in a two-mass calculation, the corresponding contributions to the 3-loop anomalous dimensions. We introduce a new general class of iterated integrals and study their relations and present special values. The corresponding functions are implemented in computer-algebraic form.

  8. Geodetic glacier mass balancing on ice caps - inseparably connected to firn modelling?

    Science.gov (United States)

    Saß, Björn L.; Sauter, Tobias; Seehaus, Thorsten; Braun, Matthias H.

    2017-04-01

    Observed melting of glaciers and ice caps in the polar regions contribute to the ongoing global sea level rise (SLR). A rising sea level and its consequences are one of the major challenges for coastal societies in the next decades to centuries. Gaining knowledge about the main drivers of SLR and bringing it together is one recent key-challenge for environmental science. The high arctic Svalbard archipelago faced a strong climatic change in the last decades, associated with a change in the cryosphere. Vestfonna, a major Arctic ice cap in the north east of Svalbard, harbors land and marine terminating glaciers, which expose a variability of behavior. We use high resolution remote sensing data from space-borne radar (TanDEM-X, TerraSAR-X, Sentinel-1a), acquired between 2009 and 2015, to estimate glacier velocity and high accurate surface elevation changes. For DEM registration we use space-borne laser altimetry (ICESat) and an existing in-situ data archive (IPY Kinnvika). In order to separate individual glacier basin changes for a detailed mass balance study and for further SLR contribution estimates, we use glacier outlines from the Global Land Ice Measurements from Space (GLIMS) project. Remaining challenges of space-borne observations are the reduction of measurement uncertainties, in the case of Synthetic Aperture Radar most notably signal penetration into the glacier surface. Furthermore, in order to convert volume to mass change one has to use the density of the changed mass (conversion factor) and one has to account for the mass conservation processes in the firn package (firn compaction). Both, the conversion factor and the firn compaction are not (yet) measurable for extensive ice bodies. They have to be modelled by coupling point measurements and regional gridded climate data. Results indicate a slight interior thickening contrasted with wide spread thinning in the ablation zone of the marine terminating outlets. While one glacier system draining to the

  9. Climatic drivers of seasonal glacier mass balances: an analysis of 6 decades at Glacier de Sarennes (French Alps

    Directory of Open Access Journals (Sweden)

    E. Thibert

    2013-01-01

    Full Text Available Refined temporal signals extracted from a winter and summer mass balance series recorded at Glacier de Sarennes (French Alps using variance decomposition are related to local meteorological data and large-scale North Atlantic Oscillation (NAO anomalies in terms of interannual variability, trends of the low-frequency signals, and breaks in the time series. The winter balance has increased by +23% since 1976 due to more precipitation in early and late winter. The summer balance has decreased since 1982 due to a 43% increase in snow and ice melt. A 24-day lengthening of the ablation period – mainly due to longer ice ablation – is the main component in the overall increase in ablation. In addition, the last 25 yr have seen increases in ablation rates of 14 and 10% for snow and ice, respectively. A simple degree-day analysis can account for both the snow/ice melt rate rise and the lengthening of the ablation period as a function of higher air temperatures. From the same analysis, the equilibrium-line altitude of this 45° N latitude south-facing glacier has a sensitivity to temperature of +93 m °C−1 around its mean elevation of 3100 m a.s.l. over 6 decades. The sensitivity of summer balance to temperature is −0.62 m w.e. yr−1 °C−1 for a typical 125-day-long ablation season. Finally, the correlation of winter and summer mass balance terms with NAO anomalies is investigated. Singularly, highest values are obtained between winter NAO anomalies and summer balance. Winter NAO anomalies and winter balance and precipitation are almost disconnected. However, these results strongly depend on how the NAO signal is smoothed, so that the link between Sarennes mass balance seasonal terms and NAO signal remains tenuous and hard to interpret.

  10. Mass, energy and material balances of SRF production process. Part 1: SRF produced from commercial and industrial waste.

    Science.gov (United States)

    Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne

    2014-08-01

    This paper presents the mass, energy and material balances of a solid recovered fuel (SRF) production process. The SRF is produced from commercial and industrial waste (C&IW) through mechanical treatment (MT). In this work various streams of material produced in SRF production process are analyzed for their proximate and ultimate analysis. Based on this analysis and composition of process streams their mass, energy and material balances are established for SRF production process. Here mass balance describes the overall mass flow of input waste material in the various output streams, whereas material balance describes the mass flow of components of input waste stream (such as paper and cardboard, wood, plastic (soft), plastic (hard), textile and rubber) in the various output streams of SRF production process. A commercial scale experimental campaign was conducted on an MT waste sorting plant to produce SRF from C&IW. All the process streams (input and output) produced in this MT plant were sampled and treated according to the CEN standard methods for SRF: EN 15442 and EN 15443. The results from the mass balance of SRF production process showed that of the total input C&IW material to MT waste sorting plant, 62% was recovered in the form of SRF, 4% as ferrous metal, 1% as non-ferrous metal and 21% was sorted out as reject material, 11.6% as fine fraction, and 0.4% as heavy fraction. The energy flow balance in various process streams of this SRF production process showed that of the total input energy content of C&IW to MT plant, 75% energy was recovered in the form of SRF, 20% belonged to the reject material stream and rest 5% belonged with the streams of fine fraction and heavy fraction. In the material balances, mass fractions of plastic (soft), plastic (hard), paper and cardboard and wood recovered in the SRF stream were 88%, 70%, 72% and 60% respectively of their input masses to MT plant. A high mass fraction of plastic (PVC), rubber material and non

  11. Mass, energy and material balances of SRF production process. Part 2: SRF produced from construction and demolition waste.

    Science.gov (United States)

    Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne

    2014-11-01

    In this work, the fraction of construction and demolition waste (C&D waste) complicated and economically not feasible to sort out for recycling purposes is used to produce solid recovered fuel (SRF) through mechanical treatment (MT). The paper presents the mass, energy and material balances of this SRF production process. All the process streams (input and output) produced in MT waste sorting plant to produce SRF from C&D waste are sampled and treated according to CEN standard methods for SRF. Proximate and ultimate analysis of these streams is performed and their composition is determined. Based on this analysis and composition of process streams their mass, energy and material balances are established for SRF production process. By mass balance means the overall mass flow of input waste material stream in the various output streams and material balances mean the mass flow of components of input waste material stream (such as paper and cardboard, wood, plastic (soft), plastic (hard), textile and rubber) in the various output streams of SRF production process. The results from mass balance of SRF production process showed that of the total input C&D waste material to MT waste sorting plant, 44% was recovered in the form of SRF, 5% as ferrous metal, 1% as non-ferrous metal, and 28% was sorted out as fine fraction, 18% as reject material and 4% as heavy fraction. The energy balance of this SRF production process showed that of the total input energy content of C&D waste material to MT waste sorting plant, 74% was recovered in the form of SRF, 16% belonged to the reject material and rest 10% belonged to the streams of fine fraction and heavy fraction. From the material balances of this process, mass fractions of plastic (soft), paper and cardboard, wood and plastic (hard) recovered in the SRF stream were 84%, 82%, 72% and 68% respectively of their input masses to MT plant. A high mass fraction of plastic (PVC) and rubber material was found in the reject material

  12. Mass-Inertial Characteristics and Dimensionless Equations of Two-bearing Rotor Motion with Auto-balancer in Terms of Compensating Body Mass

    Directory of Open Access Journals (Sweden)

    A. N. Gorbenko

    2015-01-01

    Full Text Available Modern rotary machines use auto-balancing devices of passive type to provide automatic balancing of rotors and reduce vibration. Most available researches on the rotor auto-balancing dynamics and stability are based on the assumption that the compensating bodies of the autobalancer, as well as the rotor imbalance, are infinitesimal values. The literature review has shown that the problems concerning the automatic balancing of rotor with its three-dimensional motion are solved approximately and require an in-depth analysis taking into consideration the final mass of the compensating bodies.The paper analyses the effect of an auto-balancer mass on the mass-inertial properties of the three-dimensional rotor motion. It gives the autonomous equations of the system motion. The work shows that attaching the point masses of compensating auto-balancer bodies and imbalance to the rotor causes an increase, however non-identical, in all components of the total inertia tensor of the mechanical system. This leads to a qualitative change in mass-inertial characteristics of the system.The composite rotor becomes an inertia anisotropic body in which the inertia moments about the two transverse own axes are not equal to each other. The rotor anisotropy results in complicated dynamic behavior of the gyroscopic rotor. In this case, the additional critical rotor speeds and the zones of instability of motion may occur.It is shown that in the case of using multi-body auto-balancer the inertial parameters of the rotor system grow into the interval values, i.e. their values are not uniquely determined and may be equal to a variety values from a certain range. Thus, the degree of inertial anisotropy and other auto-balancing parameters are the interval values as well in this case.The system of dimensionless equations of rotary machine motion, which contains the minimum required number of dimensionless parameters, has been obtained. The specific ranges of the dimensionless

  13. Mass balance analyses of nutrients on California dairies to evaluate data quality for regulatory review.

    Science.gov (United States)

    Miller, Christine M F; Price, Patricia L; Meyer, Deanne

    2017-02-01

    Effective regulations may help reduce nitrate contamination of groundwater from agriculture. Dairy farmers in California must maintain a ratio below 1.4 of total nitrogen (N) applied to total N-removed (N-Ratio) on cropland receiving manure application. In annual reports to the regulatory agency, farmers detail nutrients applied to cropland, removed in harvests, and exported off farm. Data were extracted from all available annual reports for 62 dairies from 2011, 2012, and 2013. Excretions of N, phosphorus (P), and potassium (K) were calculated using reported herd demographics and standard excretion equations from the American Society of Agricultural and Biological Engineers. Calculated nutrient excretion values were compared to the reported values of manure nutrients applied to cropland and exported off farm. Reported N-Ratios were compared to mass balance simulations exploring variable crop yields and alfalfa management. In the nutrient excretion balance, the distribution of the percent of N and P recovered in manures applied or exported peaked at 24% (median=31%) and 26% (median=53%) of excreted, respectively. The distribution of recovered K was fairly uniform from 0% to 300% (median=146%) of excreted K. In N-ratio simulations, 62% and 66% of all reported N-ratios were lower than their respective simulated N-ratio, assuming alfalfa crops received no N fertilization and minimal fertilization (26% of N-removed in harvest) respectively. When simulated crop yields were normally (sd=0.25) or Student's t distributed (df=154) around expected crop yields, 28% and 57% of all reported ratios fell within the 95% confidence interval of the simulations, respectively. Low and erratic recovery rates of excreted P and K existed. Additionally, reported N-Ratios were generally lower and more varied than necessary for farmers to maintain crop yields while complying with regulations. Greater understanding of low recovery rates is needed before data are used to assess the impact of

  14. Glacier surface mass balance and freshwater runoff modeling for the entire Andes Cordillera

    Science.gov (United States)

    Mernild, Sebastian H.; Liston, Glen E.; Yde, Jacob C.

    2017-04-01

    Glacier surface mass balance (SMB) observations for the Andes Cordillera are limited and, therefore, estimates of the SMB contribution from South America to sea-level rise are highly uncertain. Here, we simulate meteorological, snow, glacier surface, and hydrological runoff conditions and trends for the Andes Cordillera (1979/80-2013/14), covering the tropical latitudes in the north down to the sub-polar latitudes in the far south, including the Northern Patagonia Ice Field (NPI) and Southern Patagonia Ice Field (SPI). SnowModel - a fully integrated energy balance, blowing-snow distribution, multi-layer snowpack, and runoff routing model - was used to simulate glacier SMBs for the Andes Cordillera. The Randolph Glacier Inventory and NASA Modern-Era Retrospective Analysis for Research and Applications products, downscaled in SnowModel, allowed us to conduct relatively high-resolution simulations. The simulated glacier SMBs were verified against independent directly-observed and satellite gravimetry and altimetry-derived SMB, indicating a good statistical agreement. For glaciers in the Andes Cordillera, the 35-year mean annual SMB was found to be -1.13 m water equivalent. For both NPI and SPI, the mean SMB was positive (where calving is the likely reason for explaining why geodetic estimates are negative). Further, the spatio-temporal freshwater river runoff patterns from individual basins, including their runoff magnitude and change, were simulated. For the Andes Cordillera rivers draining to the Pacific Ocean, 86% of the simulated runoff originated from rain, 12% from snowmelt, and 2% from ice melt, whereas, for example, for Chile, the water-source distribution was 69, 24, and 7%, respectively. Along the Andes Cordillera, the 35-year mean basin outlet-specific runoff (L s-1 km-2) showed a characteristic regional hourglass shape pattern with highest runoff in both Colombia and Ecuador and in Patagonia, and lowest runoff in the Atacama Desert area.

  15. First-order catchment mass balance during the wet season in the Panama Canal Watershed

    Science.gov (United States)

    Niedzialek, Justin M.; Ogden, Fred L.

    2012-09-01

    SummaryTropical hydrology is poorly understood for a number of reasons. Intense biological activity in the tropics introduces complexities to the hydrologic process. Bioturbation, rapid rates of decay, and intensive insect activity all tend to promote rapid flow paths in the upper soil. Aggressive weathering leads to clays depleted of light cations and deep soil profiles. Processes in the seasonal tropics are further complicated by seasonal transitions, and very large changes in catchment storage between seasons. Beginning in 2005, we installed a suite of hydrologic sensors in a 16.7 ha first-order catchment in the Panama Canal Watershed to observe hydrologic variables and identify the dominant streamflow generation processes. The site is located near the village of Gamboa, which is located on the east bank of the Panama Canal at the confluence of Lake Gatun and the Chagres River. The study catchment is located on the north side of a ridge off the eastern flank of a 230 m tall hill known as Cerro Pelado, and is covered by 70-120 year old re-growth triple-canopy forest. Measurements included: rainfall above the canopy, throughfall, stemflow, evapotranspiration, shallow groundwater levels and streamflow. Deep groundwater storage was not measured. This paper describes measurements made, data collected, and the worth of those data in estimating the mass balance closure of a first-order catchment during the wet season. We compare measurements of the different components of the water cycle with observations from other published studies from the tropics. Data analysis results indicate water balance closure errors of approximately 8%.

  16. Direct analysis of samples by mass spectrometry: From elements to bio-molecules using laser ablation inductively couple plasma mass spectrometry and laser desorption/ionization mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Perdian, David C. [Iowa State Univ., Ames, IA (United States)

    2009-01-01

    Mass spectrometric methods that are able to analyze solid samples or biological materials with little or no sample preparation are invaluable to science as well as society. Fundamental research that has discovered experimental and instrumental parameters that inhibit fractionation effects that occur during the quantification of elemental species in solid samples by laser ablation inductively coupled plasma mass spectrometry is described. Research that determines the effectiveness of novel laser desorption/ionization mass spectrometric methods for the molecular analysis of biological tissues at atmospheric pressure and at high spatial resolution is also described. A spatial resolution is achieved that is able to analyze samples at the single cell level.

  17. Reducing heavy drinking in college males with the decisional balance: analyzing an element of Motivational Interviewing.

    Science.gov (United States)

    LaBrie, Joseph W; Pedersen, Eric R; Earleywine, Mitch; Olsen, Hutson

    2006-02-01

    The decisional balance, a brief detailing of the advantages and disadvantages of behavior change, serves as a key component to interventions in Motivational Interviewing. The impact of this component alone is not well understood. Forty-seven men completed a Timeline Followback interview assessing alcohol consumption and unsafe sexual practices. They then completed a decisional balance, listing the Pros and Cons of decreasing their drinking, but not one for safer sex. One-month follow-up data showed that they had statistically significant and clinically meaningful increases in their motivation to alter drinking and decreases in the number of drinks that they intended to drink, the actual drinks consumed per month, the days per month that they drank, their maximum number of drinks consumed on one occasion, and their average number of drinks per occasion. They did not alter their sexual behavior or their motivation to increase safe sex behavior. These results suggest that the decisional balance plays an important role in Motivational Interviewing and could serve as a quick and efficient intervention by itself.

  18. The Elements of Water Balance in the Changing Climate in Poland

    Directory of Open Access Journals (Sweden)

    Małgorzata Szwed

    2015-01-01

    Full Text Available Strong global warming has been observed in the last three decades. Central Europe, including Poland, is not an exception. Moreover, climate projections for Poland foresee further warming as well as changes in the spatial and seasonal distribution and quantity of precipitation. However, climate models do not agree on the sign of change of precipitation. In Poland precipitation is projected to decrease in summer (this finding is not robust, being model-dependent and to increase in winter. Therefore, there is still considerable uncertainty regarding likely climate change impacts on water resources in Poland. However, there is no doubt that changes in the thermal characteristics as well as in precipitation will influence changes in the water balance of the country. In this study, the components of climatic water balance, that is, precipitation, evaporation, and runoff, are calculated for the average conditions in the control period of 1961–1990 and in the future (2071–2100 in Poland. The changes of the water balance components for the present and for the future are compared and analysed. Due to insufficient consistency between climate models a possible range of changes should be presented; hence the multimodel projections from ENSEMBLES Project of the European Union are used in this study.

  19. Mass balance on green liquor pre-pulping extraction of northeast mixed hardwood.

    Science.gov (United States)

    Um, Byung-Hwan; van Walsum, G Peter

    2010-08-01

    A forest biorefinery configuration employing a hemicellulose pre-pulping extraction is being investigated that will retain pulp yields, reduce the organic and inorganic load for liquor recovery, and create a hemicellulose feed stream for the generation of biofuels and biomaterials. Current efforts are focused on developing extract production and conditioning processes that will result in fermentable sugars suitable for conversion to fuel alcohols or organic acid chemical products. As efforts move the process closer to commercial demonstration, it is apparent that a high level of confidence is needed in the analysis of the partitioning of fresh wood into its extracted wood and liquid extract fractions. Of particular interest is the partitioning of the carbohydrates, as these constitute the feedstock for bioconversion to fuels and chemicals. The extraction method employed utilizes green liquor derived from the kraft pulping process for pretreatment of the woodchips. To enable analysis, green liquor extraction was followed by 4% sulfuric acid hydrolysis to complete hydrolysis of the oligomers that were still present. High performance anion-exchange chromatography (HPAEC-PAD) and high performance liquid chromatography (HPLC) methods were used to analyze the carbohydrates in northern hardwood and its extract fractions. The Bio-Rad Aminex HPX-87H column did not separate mannose, xylose, and galactose, but the area of the collective peak corresponds well to the sum of these components as measured by HPAEC. In addition to sugars, standard methods were employed for quantification of the individual components (e.g., lignin, ash, nitrogen, carbon, extractives, uronic and acetic acid). The analytical mass balance closure was 102.2% and 103.6% for raw wood, 99.3% and 102.3% for extracted wood, and 94.7% and 95.6% for hemicellulose extract from the HPAEC and HPLC, respectively. The extraction mass balance was 96.9% and 98.2% for HPAEC and HPLC, respectively. The data generated

  20. New triangular mass-lumped finite elements of degree six for wave propagation

    NARCIS (Netherlands)

    Mulder, W.A.

    2013-01-01

    Mass-lumped continuous finite elements allow for explicit time stepping with the second-order wave equation if the resulting integration weights are positive and provide sufficient accuracy. To meet these requirements on triangular and tetrahedral meshes, the construction of continuous finite

  1. Determining elemental composition of phytochemicals in camelina seed meal by high mass accuracy and spectral accuracy

    Science.gov (United States)

    An optimized single run evaluation that would accurately determine the elemental composition of as many compounds present in an extract would greatly aid in the evaluation of plant tissues. For phytochemicals, we have used accurate mass analysis to quickly characterize the potential chemical formula...

  2. Elemental Bioimaging by Means of Fast Scanning Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry

    Science.gov (United States)

    Wehe, Christoph A.; Thyssen, Georgina M.; Herdering, Christina; Raj, Indra; Ciarimboli, Giuliano; Sperling, Michael; Karst, Uwe

    2015-08-01

    One of the most common setups for elemental bioimaging, the hyphenation of a laser ablation (LA) system and an inductively coupled plasma mass spectrometer (ICP-MS), was expanded by adding full scan mass spectrometric information as another dimension of information. While most studies deal with the analysis of typically not more than up to 10 isotopes per scan cycle, a fast scanning quadrupole mass analyzer was utilized to record the full mass spectrum of interest in this work. Mass-to-charge ratios from 6 to 250 were observed within one cycle. Besides the x- and y-position on the ablated sample and the intensity, the m/z-ratio served as fourth variable for each pixel of the obtained data, closing thereby the gap between "inorganic" and "organic" mass spectrometric imaging techniques. The benefits of this approach include an improved control of interferences, the discovery of unexpected elemental distributions, the possibility to plot isotopic ratios, and to integrate the intensities of a certain number of mass channels recorded for each isotope, thus virtually increasing sensitivity. The respective data are presented for dried droplets as well as embedded animal and human tissue slices. Limits of detection were calculated and found to be in accordance with counting statistics. A dedicated software macro was developed for data manipulation prior to common evaluation and image creation.

  3. Observed Mass Balance of Mountain Glaciers and Greenland Ice Sheet in the 20th Century and the Present Trends

    Science.gov (United States)

    Ohmura, Atsumu

    2011-09-01

    Glacier mass balance and secular changes in mountain glaciers and ice caps are evaluated from the annual net balance of 137 glaciers from 17 glacierized regions of the world. Further, the winter and summer balances for 35 glaciers in 11 glacierized regions are analyzed. The global means are calculated by weighting glacier and regional surface areas. The area-weighted global mean net balance for the period 1960-2000 is -270 ± 34 mm a-1 w.e. (water equivalent, in mm per year) or (-149 ± 19 km3 a-1 w.e.), with a winter balance of 890 ± 24 mm a-1 w.e. (490 ± 13 km3 a-1 w.e.) and a summer balance of -1,175 ± 24 mm a-1 w.e. (-647 ± 13 km3 a-1 w.e.). The linear-fitted global net balance is accelerating at a rate of -9 ± 2.1 mm a-2. The main driving force behind this change is the summer balance with an acceleration of -10 ± 2.0 mm a-2. The decadal balance, however, shows significant fluctuations: summer melt reached its peak around 1945, followed by a decrease. The negative trend in the annual net balance is interrupted by a period of stagnation from 1960s to 1980s. Some regions experienced a period of positive net balance during this time, for example, Europe. The balance has become strongly negative since the early 1990s. These decadal fluctuations correspond to periods of global dimming (for smaller melt) and global brightening (for larger melt). The total radiation at the surface changed as a result of an imbalance between steadily increasing greenhouse gases and fluctuating aerosol emissions. The mass balance of the Greenland ice sheet and the surrounding small glaciers, averaged for the period of 1950-2000, is negative at -74 ± 10 mm a-1 w.e. (-128 ± 18 km3 a-1 w.e.) with an accumulation of 297 ± 33 mm a-1 w.e. (519 ± 58 km3 a-1 w.e.), melt ablation -169 ± 18 mm a-1 w.e. (-296 ± 31 km3 a-1 w.e.), calving ablation -181 ± 19 mm a-1 w.e. (-316 ± 33 km3 a-1 w.e.) and the bottom melt-21 ± 2 mm a-1 w.e. (-35 ± 4 km3 a-1 w.e.). Almost half (-60 ± 3 km3 a

  4. Numerical Solutions to Nonsmooth Dirichlet Problems Based on Lumped Mass Finite Element Discretization

    Directory of Open Access Journals (Sweden)

    Haixiong Yu

    2014-01-01

    Full Text Available We apply a lumped mass finite element to approximate Dirichlet problems for nonsmooth elliptic equations. It is proved that the lumped mass FEM approximation error in energy norm is the same as that of standard piecewise linear finite element approximation. Under the quasi-uniform mesh condition and the maximum angle condition, we show that the operator in the finite element problem is diagonally isotone and off-diagonally antitone. Therefore, some monotone convergent algorithms can be used. As an example, we prove that the nonsmooth Newton-like algorithm is convergent monotonically if Gauss-Seidel iteration is used to solve the Newton's equations iteratively. Some numerical experiments are presented.

  5. Analysing drying unit performance in a continuous pharmaceutical manufacturing line by means of mass – Energy balances

    DEFF Research Database (Denmark)

    Mortier, Séverine Thérèse F.C.; Gernaey, Krist; De Beer, Thomas De Beer

    2014-01-01

    used. In this paper the data of the six-segmented fluidized bed dryer in the line are used for the development and evaluation of a mass and energy balance. The objectives are multiple: (1) prediction of the moisture content of the granules leaving the dryer solely based on the currently logged data...... and (2) prediction of the gas outlet temperature to check the mass balances. Once a validated system is established the gas temperature in different horizontal sections of the drying unit can be predicted. Calculations are also used to identify errors in the system and to propose alternative sensor...... locations. A calibration is performed in order to predict the evaporation rate. The balances were able to predict both the moisture content of the granules at the end of the drying process and the gas outlet temperature quite accurately. Combining the gathered information with the height of the bed...

  6. Recent developments for high-precision mass measurements of the heaviest elements at SHIPTRAP

    Energy Technology Data Exchange (ETDEWEB)

    Minaya Ramirez, E., E-mail: E.Minaya@gsi.de [Helmholtz-Institut Mainz, 55099 Mainz (Germany); GSI Helmholtzzentrum für Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Ackermann, D. [GSI Helmholtzzentrum für Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Blaum, K. [Max-Planck-Institut für Kernphysik, 69117 Heidelberg (Germany); Ruprecht-Karls-Universität, 69120 Heidelberg (Germany); Block, M. [GSI Helmholtzzentrum für Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Droese, C. [Ernst-Moritz-Arndt-Universität, 17487 Greifswald (Germany); Düllmann, Ch. E. [Johannes Gutenberg-Universität, 55099 Mainz (Germany); GSI Helmholtzzentrum für Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Helmholtz-Institut Mainz, 55099 Mainz (Germany); Eibach, M. [Ruprecht-Karls-Universität, 69120 Heidelberg (Germany); Johannes Gutenberg-Universität, 55099 Mainz (Germany); Eliseev, S. [Max-Planck-Institut für Kernphysik, 69117 Heidelberg (Germany); Haettner, E. [GSI Helmholtzzentrum für Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Justus-Liebig-Universität, 35392 Gießen (Germany); Herfurth, F. [GSI Helmholtzzentrum für Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Heßberger, F.P. [GSI Helmholtzzentrum für Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Helmholtz-Institut Mainz, 55099 Mainz (Germany); and others

    2013-12-15

    Highlights: • Direct high-precision mass measurements of No and Lr isotopes performed. • High-precision mass measurements with a count rate of 1 ion/hour demonstrated. • The results provide anchor points for a large region connected by alpha-decay chains. • The binding energies determine the strength of the deformed shell closure N = 152. • Technical developments and new techniques will pave the way towards heavier elements. -- Abstract: Atomic nuclei far from stability continue to challenge our understanding. For example, theoretical models have predicted an “island of stability” in the region of the superheavy elements due to the closure of spherical proton and neutron shells. Depending on the model, these are expected at Z = 114, 120 or even 126 and N = 172 or 184. Valuable information on the road to the island of stability is derived from high-precision mass measurements, which give direct access to binding energies of short-lived trans-uranium nuclei. Recently, direct mass measurements at SHIPTRAP have been extended to nobelium and lawrencium isotopes around the deformed shell gap N = 152. In order to further extend mass measurements to the region of superheavy elements, new technical developments are required to increase the performance of our setup. The sensitivity will increase through the implementation of a new detection method, where observation of one single ion is sufficient. Together with the use of a more efficient gas stopping cell, this will us allow to significantly enhance the overall efficiency of SHIPTRAP.

  7. Greenland ice sheet surface mass balance: evaluating simulations and making projections with regional climate models

    Directory of Open Access Journals (Sweden)

    J. G. L. Rae

    2012-11-01

    Full Text Available Four high-resolution regional climate models (RCMs have been set up for the area of Greenland, with the aim of providing future projections of Greenland ice sheet surface mass balance (SMB, and its contribution to sea level rise, with greater accuracy than is possible from coarser-resolution general circulation models (GCMs. This is the first time an intercomparison has been carried out of RCM results for Greenland climate and SMB. Output from RCM simulations for the recent past with the four RCMs is evaluated against available observations. The evaluation highlights the importance of using a detailed snow physics scheme, especially regarding the representations of albedo and meltwater refreezing. Simulations with three of the RCMs for the 21st century using SRES scenario A1B from two GCMs produce trends of between −5.5 and −1.1 Gt yr−2 in SMB (equivalent to +0.015 and +0.003 mm sea level equivalent yr−2, with trends of smaller magnitude for scenario E1, in which emissions are mitigated. Results from one of the RCMs whose present-day simulation is most realistic indicate that an annual mean near-surface air temperature increase over Greenland of ~ 2°C would be required for the mass loss to increase such that it exceeds accumulation, thereby causing the SMB to become negative, which has been suggested as a threshold beyond which the ice sheet would eventually be eliminated.

  8. Quantification of Dialytic Removal and Extracellular Calcium Mass Balance during a Weekly Cycle of Hemodialysis.

    Directory of Open Access Journals (Sweden)

    Jacek Waniewski

    Full Text Available The removal of calcium during hemodialysis with low calcium concentration in dialysis fluid is generally slow, and the net absorption of calcium from dialysis fluid is often reported. The details of the calcium transport process during dialysis and calcium mass balance in the extracellular fluid, however, have not been fully studied.Weekly cycle of three dialysis sessions with interdialytic breaks of 2-2-3 days was monitored in 25 stable patients on maintenance hemodialysis with calcium concentration in dialysis fluid of 1.35 mmol/L. Total and ionic calcium were frequently measured in blood and dialysate. The volume of fluid compartments was measured by bioimpedance.Weekly dialytic removal of 12.79 ± 8.71 mmol calcium was found in 17 patients, whereas 9.48 ± 8.07 mmol calcium was absorbed per week from dialysis fluid in 8 patients. Ionic calcium was generally absorbed from dialysis fluid, whereas complexed calcium (the difference of total and ionic calcium in dialysis fluid was removed from the body. The concentration of total calcium in plasma increased slightly during dialysis. The mass of total and ionic calcium in extracellular fluid decreased during dialysis in patients with the dialytic removal of calcium from the body and did not change in patients with the absorption of calcium from dialysis fluid.We conclude that about one third of patients on dialysis with calcium 1.35 mmol/L in dialysis fluid may absorb calcium from dialysis fluid and therefore individual prescriptions of calcium concentration in dialysis fluid should be considered for such patients.

  9. The 'Fat Mass and Obesity Related' (FTO) gene: Mechanisms of Impact on Obesity and Energy Balance.

    Science.gov (United States)

    Speakman, John R

    2015-03-01

    A cluster of single nucleotide polymorphisms (SNPs) in the first intron of the fat mass and obesity related (FTO) gene were the first common variants discovered to be associated with body mass index and body fatness. This review summarises what has been later discovered about the biology of FTO drawing together information from both human and animal studies. Subsequent work showed that the 'at risk' alleles of these SNPs are associated with greater food intake and increased hunger/lowered satiety, but are not associated with altered resting energy expenditure or low physical activity in humans. FTO is an FE (II) and 2-oxoglutarate dependent DNA/RNA methylase. Contrasting the impact of the SNPs on energy balance in humans, knocking out or reducing activity of the Fto gene in the mouse resulted in lowered adiposity, elevated energy expenditure with no impact on food intake (but the impact on expenditure is disputed). In contrast, overexpression of the gene in mice led to elevated food intake and adiposity, with no impact on expenditure. In rodents, the Fto gene is widely expressed in the brain including hypothalamic nuclei linked to food intake regulation. Since its activity is 2-oxoglutarate dependent it could potentially act as a sensor of citrate acid cycle flux, but this function has been dismissed, and instead it has been suggested to be much more likely to act as an amino acid sensor, linking circulating AAs to the mammalian target of rapamycin complex 1. This may be fundamental to its role in development but the link to obesity is less clear. It has been recently suggested that although the obesity related SNPs reside in the first intron of FTO, they may not only impact FTO but mediate their obesity effects via nearby genes (notably RPGRIP1L and IRX3).

  10. Ocular Distribution and Pharmacokinetics of Lifitegrast in Pigmented Rabbits and Mass Balance in Beagle Dogs.

    Science.gov (United States)

    Chung, Jou-Ku; Spencer, Elizabeth; Hunt, Matthew; McCauley, Thomas; Welty, Devin

    Lifitegrast is approved in the United States for the treatment of dry eye disease (DED). We assessed lifitegrast's ocular distribution/pharmacokinetic profile in rabbits, and 14 C-lifitegrast mass balance/excretion in dogs. Female pigmented rabbits received a single topical ocular dose of lifitegrast (Formulation No. 1, n = 25; No. 2, n = 25) per eye twice daily (target, 1.75 mg/eye/dose). Blood/ocular tissues were collected on day 5. Beagle dogs received single intravenous (n = 10; target, 3 mg, 262 μCi/animal) and ocular (n = 8, target, 3 mg, 30 μCi/eye) doses of 14 C-lifitegrast (∼8 weeks between doses). Blood, excreta, and cage rinse/wipes were collected. Concentrations were measured by mass spectrometry/liquid scintillation counting. Pharmacokinetic analyses (noncompartmental) included maximum concentration (C max ), time to C max (t max ), and area under the concentration-time curve from 0 to 8 h (AUC 0-8 ). In rabbits, lifitegrast C max and AUC 0-8 were similar between formulations. C max was highest in ocular anterior segment tissues: 5,190-14,200 ng/g [conjunctiva (palpebral/bulbar), cornea, anterior sclera]. Posterior segment tissues had lower concentrations (0-826 ng/g). AUC 0-8 followed a similar trend. Plasma concentrations were low (C max lifitegrast was eliminated primarily through feces. Excreted radioactivity was mainly unchanged lifitegrast. High exposure of lifitegrast in rabbit ocular anterior segment tissues and low exposure in posterior segment tissues/plasma suggests that lifitegrast reaches target tissues for DED treatment, with low potential for off-target systemic/ocular effects. Excretion of unchanged 14 C-lifitegrast suggests minimal drug metabolism in vivo. This is consistent with lifitegrast clinical trial efficacy/safety data.

  11. On the importance of sublimation to an alpine snow mass balance in the Canadian Rocky Mountains

    Directory of Open Access Journals (Sweden)

    M. K. MacDonald

    2010-07-01

    Full Text Available A modelling study was undertaken to evaluate the contribution of sublimation to an alpine snow mass balance in the Canadian Rocky Mountains. Snow redistribution and sublimation by wind, snowpack sublimation and snowmelt were simulated for two winters over an alpine ridge transect located in the Canada Rocky Mountains. The resulting snowcover regimes were compared to those from manual snow surveys. Simulations were performed using physically based blowing snow (PBSM and snowpack ablation (SNOBAL models. A hydrological response unit (HRU-based spatial discretization was used rather than a more computationally expensive fully-distributed one. The HRUs were set up to follow an aerodynamic sequence, whereby eroded snow was transported from windswept, upwind HRUs to drift accumulating, downwind HRUs. That snow redistribution by wind can be adequately simulated in computationally efficient HRUs over this ridge has important implications for representing snow transport in large-scale hydrology models and land surface schemes. Alpine snow sublimation losses, in particular blowing snow sublimation losses, were significant. Snow mass losses to sublimation as a percentage of cumulative snowfall were estimated to be 20–32% with the blowing snow sublimation loss amounting to 17–19% of cumulative snowfall. This estimate is considered to be a conservative estimate of the blowing snow sublimation loss in the Canadian Rocky Mountains because the study transect is located in the low alpine zone where the topography is more moderate than the high alpine zone and windflow separation was not observed. An examination of the suitability of PBSM's sublimation estimates in this environment and of the importance of estimating blowing snow sublimation on the simulated snow accumulation regime was conducted by omitting sublimation calculations. Snow accumulation in HRUs was overestimated by 30% when neglecting blowing snow sublimation calculations.

  12. Estimating Greenland ice sheet surface mass balance contribution to future sea level rise using the regional atmospheric climate model MAR

    NARCIS (Netherlands)

    Fettweis, X.; Franco, B.; Tedesco, M.; van Angelen, J.H.; Lenaerts, J.T.M.; van den Broeke, M.R.; Gallee, H

    2012-01-01

    We report future projections of Surface Mass Balance (SMB) over the Greenland ice sheet (GrIS) obtained with the regional climate model MAR, forced by the outputs of three CMIP5 General Circulation Models (GCMs) when considering two different warming scenarios (RCP 4.5 and RCP 8.5). The GCMs

  13. Contemporary (1960–2012) Evolution of the Climate and Surface Mass Balance of the Greenland Ice Sheet

    NARCIS (Netherlands)

    van Angelen, J. H.; van den Broeke, M. R.; Wouters, B.; Lenaerts, J. T M

    2013-01-01

    We assess the contemporary (1960–2012) surface mass balance (SMB) of the Greenland ice sheet (GrIS), its individual components and trends. We use output of the high-resolution (11 km) regional atmospheric climate model (RACMO2), evaluated with automatic weather stations and GRACE data. A persistent

  14. A Simplified Model of Human Alcohol Metabolism That Integrates Biotechnology and Human Health into a Mass Balance Team Project

    Science.gov (United States)

    Yang, Allen H. J.; Dimiduk, Kathryn; Daniel, Susan

    2011-01-01

    We present a simplified human alcohol metabolism model for a mass balance team project. Students explore aspects of engineering in biotechnology: designing/modeling biological systems, testing the design/model, evaluating new conditions, and exploring cutting-edge "lab-on-a-chip" research. This project highlights chemical engineering's impact on…

  15. Assessment of the surface mass balance along the K-transect (Greenland ice sheet) from satellite-derived albedos

    NARCIS (Netherlands)

    Oerlemans, J.; Greuell, W.

    This paper explores the potential of using satellite-derived albedos to estimate the surface mass balance of the Kangerlussuaq transect (K-transect; Greenland ice sheet). We first retrieved surface albedos from Advanced Very High Resolution Radar data by using, among other techniques, a new

  16. Sensitivity of Greenland Ice Sheet surface mass balance to surface albedo parameterization: a study with a regional climate model

    NARCIS (Netherlands)

    van Angelen, J.H.|info:eu-repo/dai/nl/325922470; Lenaerts, J.T.M.|info:eu-repo/dai/nl/314850163; Lhermitte, S.; Fettweis, X.; Kuipers Munneke, P.|info:eu-repo/dai/nl/304831891; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643; van Meijgaard, E.; Smeets, C.J.P.P.|info:eu-repo/dai/nl/191522236

    2012-01-01

    We present a sensitivity study of the surface mass balance (SMB) of the Greenland Ice Sheet, as modeled using a regional atmospheric climate model, to various parameter settings in the albedo scheme. The snow albedo scheme uses grain size as a prognostic variable and further depends on cloud cover,

  17. Brief Communication: Upper-air relaxation in RACMO2 significantly improves modelled interannual surface mass balance variability in Antarctica

    NARCIS (Netherlands)

    van de Berg, W.J.|info:eu-repo/dai/nl/304831611; Medley, Brooke

    2016-01-01

    The Regional Atmospheric Climate Model (RACMO2) has been a powerful tool for improving surface mass balance (SMB) estimates from GCMs or reanalyses. However, new yearly SMB observations for West Antarctica show that the modelled interannual variability in SMB is poorly simulated by RACMO2, in

  18. A new, high-resolution surface mass balance map of Antarctica (1979–2010) based on regional atmospheric climate modeling

    NARCIS (Netherlands)

    Lenaerts, J.T.M.|info:eu-repo/dai/nl/314850163; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643; van de Berg, W.J.|info:eu-repo/dai/nl/304831611; van Meijgaard, E.; Kuipers Munneke, P.|info:eu-repo/dai/nl/304831891

    2012-01-01

    A new, high resolution (27 km) surface mass balance (SMB) map of the Antarctic ice sheet is presented, based on output of a regional atmospheric climate model that includes snowdrift physics and is forced by the most recent reanalysis data from the European Centre for Medium-Range Weather Forecasts

  19. A daily, 1 km resolution data set of downscaled Greenland ice sheet surface mass balance (1958-2015)

    NARCIS (Netherlands)

    Noël, Brice|info:eu-repo/dai/nl/370612345; Jan Van De Berg, Willem|info:eu-repo/dai/nl/304831611; MacHguth, Horst; Lhermitte, Stef; Howat, Ian; Fettweis, Xavier; Van Den Broeke, Michiel R.|info:eu-repo/dai/nl/073765643

    2016-01-01

    This study presents a data set of daily, 1 km resolution Greenland ice sheet (GrIS) surface mass balance (SMB) covering the period 1958-2015. Applying corrections for elevation, bare ice albedo and accumulation bias, the high-resolution product is statistically downscaled from the native daily

  20. Towards coupling of regional atmosphere models to ice sheet models by mass balance gradients - application to the Greenland Ice Sheet

    NARCIS (Netherlands)

    Helsen, M.M.|info:eu-repo/dai/nl/325802459; van de Wal, R.S.W.|info:eu-repo/dai/nl/101899556; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643; van de Berg, W.J.|info:eu-repo/dai/nl/304831611; Oerlemans, J.|info:eu-repo/dai/nl/06833656X

    2012-01-01

    It is notoriously difficult to couple surface mass balance (SMB) results from climate models to the changing geometry of an ice sheet model. This problem is traditionally avoided by using only accumulation from a climate model, and parameterizing the meltwater run-off as a function of temperature,

  1. Towards coupling of regional atmosphere models to ice sheet models by mass balance gradients - application to the Greenland Ice Sheet

    NARCIS (Netherlands)

    Helsen, M.M.; van de Wal, R.S.W.; van den Broeke, M.R.; van de Berg, W.J.; Oerlemans, J.

    2011-01-01

    It is notoriously difficult to couple surface mass balance (SMB) results from climate models to the changing geometry of an ice sheet model. This problem is traditionally avoided by using only accumulation fields from a climate model, and deriving SMB by parameterizing 5 the run-off as a function of

  2. A daily, 1 km resolution data set of downscaled Greenland ice sheet surface mass balance (1958–2015)

    NARCIS (Netherlands)

    Noël, Brice; van de Berg, Willem Jan; Machguth, Horst; Lhermitte, S.L.M.; Howat, Ian; Fettweis, Xavier; van den Broeke, Michiel R.

    2016-01-01

    This study presents a data set of daily, 1 km resolution Greenland ice sheet (GrIS) surface mass balance (SMB) covering the period 1958–2015. Applying corrections for elevation, bare ice albedo and accumulation bias, the high-resolution product is statistically downscaled from the native daily

  3. On Applicability of a Miniaturised Laser Ablation Time of Flight Mass Spectrometer for Trace Elements Measurements

    Directory of Open Access Journals (Sweden)

    Marek Tulej

    2012-01-01

    Full Text Available We present results from mass spectrometric analysis of NIST standard materials and meteoritic samples conducted by a miniaturised laser ablation mass spectrometer designed for space research. The mass analyser supports investigation with a mass resolution (/Δ ≈ 500–600 and dynamic range within seven decades. Nevertheless, to maintain an optimal spectral quality laser irradiances lower than ~1 GW/cm2 are applied so far which results in a spread of RSC values. To achieve the quantitative performance of mass analyser, various effects influencing RSC factors have to be investigated. In this paper we investigate influence of laser irradiance, sampling procedure and plasma chemistry on the quantitative elemental and isotopic analysis. The studies indicate necessity for accurate control of laser characteristics and acquisition procedure. A relatively low irradiance applied causes a negligible sample damage and allows for accumulation of large number of waveforms from one sample location. The procedure yields statistically well averaged data and allows a sensitive in-depth analysis. The quantitative analyses of isotopic composition can be performed with accuracy and precision better as 1% and 2%, for isotopic patterns of elements and clusters, respectively. The numerical integration methods would be preferred to achieve more accurate results. The measurements of Allende sample yield detection of Pb isotopic pattern, nevertheless cluster species are readily observed in spectrum and make the elemental analysis of other trace elements difficult due to isobaric interferences. These detections are of a considerable interest because of possible application of the instrument for in situ elemental and isotopic analysis and radiometric dating of solids.

  4. Hypsometric control on glacier mass balance sensitivity in Alaska and northwest Canada

    Science.gov (United States)

    McGrath, D.; Sass, L.; O'Neel, S.; Arendt, A.; Kienholz, C.

    2017-03-01

    Glacier hypsometry provides a first-order approach for assessing a glacier's response to climate forcings. We couple the Randolph Glacier Inventory to a suite of in situ observations and climate model output to examine potential change for the ˜27,000 glaciers in Alaska and northwest Canada through the end of the 21st century. By 2100, based on Representative Concentration Pathways (RCPs) 4.5-8.5 forcings, summer temperatures are predicted to increase between +2.1 and +4.6°C, while solid precipitation (snow) is predicted to decrease by -6 to -11%, despite a +9 to +21% increase in total precipitation. Snow is predicted to undergo a pronounced decrease in the fall, shifting the start of the accumulation season back by ˜1 month. In response to these forcings, the regional equilibrium line altitude (ELA) may increase by +105 to +225 m by 2100. The mass balance sensitivity to this increase is highly variable, with the most substantive impact for glaciers with either limited elevation ranges (often small (ELAs, given RCP 6.0 forcings, will exceed the maximum elevation of the glacier, resulting in their eventual demise, while for others, accumulation area ratios will decrease by >60%. Our results highlight the first-order control of hypsometry on individual glacier response to climate change, and the variability that hypsometry introduces to a regional response to a coherent climate perturbation.

  5. Mass and Energy Balances of Dry Thermophilic Anaerobic Digestion Treating Swine Manure Mixed with Rice Straw

    Directory of Open Access Journals (Sweden)

    Sheng Zhou

    2015-01-01

    Full Text Available To evaluate the feasibility of swine manure treatment by a proposed Dry Thermophilic Anaerobic Digestion (DT-AD system, we evaluated the methane yield of swine manure treated using a DT-AD method with rice straw under different C/N ratios and solid retention time (SRT and calculated the mass and energy balances when the DT-AD system is used for swine manure treatment from a model farm with 1000 pigs and the digested residue is used for forage rice production. A traditional swine manure treatment Oxidation Ditch system was used as the study control. The results suggest that methane yield using the proposed DT-AD system increased with a higher C/N ratio and shorter SRT. Correspondently, for the DT-AD system running with SRT of 80 days, the net energy yields for all treatments were negative, due to low biogas production and high heat loss of digestion tank. However, the biogas yield increased when the SRT was shortened to 40 days, and the generated energy was greater than consumed energy when C/N ratio was 20:1 and 30:1. The results suggest that with the correct optimization of C/N ratio and SRT, the proposed DT-AD system, followed by using digestate for forage rice production, can attain energy self-sufficiency.

  6. Mass and Energy Balances of Dry Thermophilic Anaerobic Digestion Treating Swine Manure Mixed with Rice Straw.

    Science.gov (United States)

    Zhou, Sheng; Zhang, Jining; Zou, Guoyan; Riya, Shohei; Hosomi, Masaaki

    2015-01-01

    To evaluate the feasibility of swine manure treatment by a proposed Dry Thermophilic Anaerobic Digestion (DT-AD) system, we evaluated the methane yield of swine manure treated using a DT-AD method with rice straw under different C/N ratios and solid retention time (SRT) and calculated the mass and energy balances when the DT-AD system is used for swine manure treatment from a model farm with 1000 pigs and the digested residue is used for forage rice production. A traditional swine manure treatment Oxidation Ditch system was used as the study control. The results suggest that methane yield using the proposed DT-AD system increased with a higher C/N ratio and shorter SRT. Correspondently, for the DT-AD system running with SRT of 80 days, the net energy yields for all treatments were negative, due to low biogas production and high heat loss of digestion tank. However, the biogas yield increased when the SRT was shortened to 40 days, and the generated energy was greater than consumed energy when C/N ratio was 20 : 1 and 30 : 1. The results suggest that with the correct optimization of C/N ratio and SRT, the proposed DT-AD system, followed by using digestate for forage rice production, can attain energy self-sufficiency.

  7. Aquatic worms eat sludge: Mass balances and processing of worm faeces

    Energy Technology Data Exchange (ETDEWEB)

    Hendrickx, T.L.G., E-mail: tim.hendrickx@wur.nl [Wetsus - Centre of Excellence for Sustainable Water Technology, P.O. Box 1113, 8900 CC Leeuwarden (Netherlands); Sub-department of Environmental Technology, Wageningen University, P.O. Box 8129, 6700 EV Wageningen (Netherlands); Temmink, H. [Wetsus - Centre of Excellence for Sustainable Water Technology, P.O. Box 1113, 8900 CC Leeuwarden (Netherlands); Sub-department of Environmental Technology, Wageningen University, P.O. Box 8129, 6700 EV Wageningen (Netherlands); Elissen, H.J.H. [Wetsus - Centre of Excellence for Sustainable Water Technology, P.O. Box 1113, 8900 CC Leeuwarden (Netherlands); Buisman, C.J.N. [Wetsus - Centre of Excellence for Sustainable Water Technology, P.O. Box 1113, 8900 CC Leeuwarden (Netherlands); Sub-department of Environmental Technology, Wageningen University, P.O. Box 8129, 6700 EV Wageningen (Netherlands)

    2010-05-15

    Reduction of the amount of waste sludge from waste water treatment plants (WWTPs) can be achieved with the aquatic worm Lumbriculus variegatus in a new reactor concept. In addition to reducing the amount of waste sludge, further processing of produced worm faeces and released nutrients should also be considered. This study gives the mass balances for sludge consumed by L. variegatus, showing the fate of the consumed organic material, nutrients and heavy metals associated with the sludge. A distinction is made between conversion into worm biomass, release as dissolved metabolites and what remains in the worm faeces. The results showed that 39% of the nitrogen and 12% of the phosphorus in the sludge digested by the worms are used in the formation of new worm biomass, which has potential for reuse. Experiments showed that settling of the worm faeces leads to a factor 2.5 higher solids concentration, compared to settling of waste sludge. This could lead to a 67% reduction of the volumetric load on thickening equipment. The worm reactor is expected to be most interesting for smaller WWTPs where a decrease on the volumetric load on sludge handling operations will have most impact.

  8. Challenges for Greenland-wide mass balance from Cryosat-2 radar-altimetry

    DEFF Research Database (Denmark)

    Simonsen, Sebastian Bjerregaard; Forsberg, René; Sørensen, Louise Sandberg

    As the Greenland ice sheet warms, a change in the structure of the upper snow/firn occurs. This change further induces changes in the reflective properties of the firn seen from satellite radar altimetry. If not identified as changes in the reflective properties of the firn, these may be interpre......As the Greenland ice sheet warms, a change in the structure of the upper snow/firn occurs. This change further induces changes in the reflective properties of the firn seen from satellite radar altimetry. If not identified as changes in the reflective properties of the firn, these may...... be interpreted as actual surface elevation changes seen from the satellite radar altimetry (Nilsson et al., 2015).Here, we investigate how to correct the elevation change observed from the ESA Cryosat-2 radar altimetry mission to derive elevation change of the air/snow interface of the Greenland ice sheet....... The elevation change of this “real” physical surface is crucial, if the goal is to derive Greenland mass balance as done for LiDAR missions.The investigations look into waveform parameters to correct for the observed bias between Radar and LiDAR observations when using Croysat-2 level-2 data. Based...

  9. Influence of seasonality on glacier mass balance, and implications for palaeoclimate reconstructions

    Energy Technology Data Exchange (ETDEWEB)

    Golledge, Nicholas [Victoria University of Wellington, Antarctic Research Centre, Wellington (New Zealand); Hubbard, Alun [The University of Wales, Institute of Geography and Earth Sciences, Aberystwyth (United Kingdom); Bradwell, Tom [British Geological Survey, Murchison House, Edinburgh (United Kingdom)

    2010-10-15

    Climates inferred from former glacier geometries in some areas exhibit discrepancies with regional palaeoclimates predicted by General Circulation Models (GCMs) and modelling of palaeoecological data, possibly as a consequence of their differing treatments of climatic seasonality. Since glacier-based climate reconstructions potentially offer an important tool in the calibration of GCMs, which themselves need validation if used to predict future climate scenarios, we attempt to resolve mismatches between these techniques by (1) investigating the influence of seasonality on glacier mass balance, and (2) refining the methodology used for the derivation of glacier-based palaeoclimates. Focussing on the Younger Dryas stadial glaciation of Scotland, northeast Atlantic, we show that sea-ice amplified seasonality led to a significantly drier climate than has been suggested by glacier-based interpretations. This was characterised by a relatively short ablation season and the survival of a more substantial winter snowpack. We suggest that if palaeoglaciological studies were to account for changes in seasonal temperature and precipitation variability, their results would agree more closely with the cold, arid, northeast Atlantic palaeoenvironment predicted by atmospheric modelling and northwest European pollen studies, and would therefore provide more accurate constraints for GCM calibration. (orig.)

  10. [Strength, flexibility, balance, resistance and flexibility assessment according to body mass index in active older women].

    Science.gov (United States)

    Vaquero-Cristóbal, Raquel; Martínez González-Moro, Ignacio; Alacid Cárceles, Fernando; Ros Simón, Esperanza

    2013-01-01

    Overweight and obesity are increasing at an alarming rate among older people. This is mainly because this population is predominantly sedentary. The aim of this study was to classify, according to the body mass index (BMI), a group of older active women and to evaluate the different basic physical abilities as a function of this. The BMI and fitness were evaluated in 60 elderly active women (mean age: 66.14 ± 6.59 years) using the 2-minute step test, arm curl test, chair stand test, back scratch test, chair-sit and reach-test, flamenco test, and 8-foot up-and-go test. It was found that 52.23% of the women studied had a normal BMI and 47.76% were slightly overweight. There were no cases of obesity or underweight. Women with normal BMI had better values in all tests than overweight women. Significant differences were found in the flamenco test (P<.05), and 8-foot up-and-go test (P<.01). Older women who usually do physical activity had a normal or slightly overweight BMI. It was also found that women with lower BMI have better resistance, flexibility, balance and strength. Copyright © 2012 SEGG. Published by Elsevier Espana. All rights reserved.

  11. Mass, energy, entropy and exergy rate balance in a ranque-hilsh vortex tube

    Directory of Open Access Journals (Sweden)

    Edorta Carrascal

    2013-12-01

    Full Text Available The purpose of this paper is to exhibit a laboratory practicum designed for the subject of Thermodynamics at the Department of Thermal Engineering of the University of the Basque Country. With reference to one of the problems stated in the text of Moran, Shapiro, Boettner, Bailey (2012, the balances of mass, energy, entropy and exergy are applied in a particular Control Volume, and the ideal gas model is used. Using a Ranque-Hilsh vortex tube (Ranque, 1934, the division of a compressed air flow into two streams at a lower pressure is achieved; one hot  whose temperature can exceed 100 °C and another cold that can reach temperatures below -40 °C. Therefore an air flow is divided into two, one hot and one cold stream, without any thermal interaction with hot or cold focuses. The vortex tube operation can serve to expose the bases of the first and second law of thermodynamics. Even, this practical lab can be used to give sense to one of the most known theoretical experiments in thermodynamics, such as the one of Maxwell's demon (Lewins & Bejan, 1999; Liew, Zeegers, Kuerten & Michalek, 2012. On the other hand once a compressed air source is provided, the material needed to prepare the lab is simple and affordable and it has a very interesting and suggestive appeal.

  12. Solid and liquid fractionation of digestate: Mass balance, chemical characterization, and agronomic and environmental value.

    Science.gov (United States)

    Tambone, Fulvia; Orzi, Valentina; D'Imporzano, Giuliana; Adani, Fabrizio

    2017-11-01

    Solid-liquid (S/L) separation of digestate (D) represents a simple technology able to produce two fractions having different composition. The aim of this work was to study the effect of S/L separation on dry matter (DM), nitrogen (TKN), phosphorus (P2O5) and heavy metals (HM) repartition into these two fractions and to characterize them. Therefore, thirteen full-scale digestion plants were studied and D, LF and SF were collected during three seasons of the year. Results obtained indicated that unexpectedly, on a mass balance, the liquid fraction still contains the majority of DM, i.e. 67% of the total of D. LF also contained 87% and 71% of TKN and P2O5 respectively. HM contents were in line with typical NP-organic fertilizers. Chemical characterization suggested that the LF can be used as a substitute for mineral N fertilizers because of its high N content, while SF can be proposed as an NP-organic fertilizer. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Simulation of mass and energy balances of a chemical-looping combustion system

    Energy Technology Data Exchange (ETDEWEB)

    B. Kronberger; G. Loeffler; H. Hofbauer [Vienna University of Technology, Vienna (Austria). Institute of Chemical Engineering

    2003-07-01

    Chemical-Looping Combustion is constructed from two separate reactors: i) the fuel reactor where the fuel gas is oxidised and ii) the air reactor where the metal oxide re-oxidation reaction takes place. The oxygen transfer is realised by means of oxygen carrier materials, and the oxidation products of the fuel are kept separated from the combustion air. No extra energy for CO{sub 2} separation and further sequestration is needed. A mathematical model of a CLC system with an integrated solution of the mass and energy balances was set up. Evaluation of the effect of numerous design and operating parameters, such as fuel gas composition and reactor cooling arrangement that depend on the oxygen carrier type, were carried out. The results of the model reveal that in many cases additional reactor cooling and oxygen carrier flow have to be chosen properly to guarantee appropriate temperatures in the reactor and complete fuel gas combustion. These are requirements for avoiding thermal and mechanical decomposition of the oxygen carrier, and operation of the electricity generation cycle with high thermal and CO{sub 2}-capture efficiency.

  14. Bayesian treatment of a chemical mass balance receptor model with multiplicative error structure

    Science.gov (United States)

    Keats, Andrew; Cheng, Man-Ting; Yee, Eugene; Lien, Fue-Sang

    The chemical mass balance (CMB) receptor model is commonly used in source apportionment studies as a means for attributing measured airborne particulate matter (PM) to its constituent emission sources. Traditionally, error terms (e.g., measurement and source profile uncertainty) associated with the model have been treated in an additive sense. In this work, however, arguments are made for the assumption of multiplicative errors, and the effects of this assumption are realized in a Bayesian probabilistic formulation which incorporates a 'modified' receptor model. One practical, beneficial effect of the multiplicative error assumption is that it automatically precludes the possibility of negative source contributions, without requiring additional constraints on the problem. The present Bayesian treatment further differs from traditional approaches in that the source profiles are inferred alongside the source contributions. Existing knowledge regarding the source profiles is incorporated as prior information to be updated through the Bayesian inferential scheme. Hundreds of parameters are therefore present in the expression for the joint probability of the source contributions and profiles (the posterior probability density function, or PDF), whose domain is explored efficiently using the Hamiltonian Markov chain Monte Carlo method. The overall methodology is evaluated and results compared to the US Environmental Protection Agency's standard CMB model using a test case based on PM data from Fresno, California.

  15. Biogas production, sludge accumulation and mass balance of carbon in anaerobic ponds.

    Science.gov (United States)

    Picot, B; Paing, J; Sambuco, J P; Costa, R H R; Rambaud, A

    2003-01-01

    This work concerned the application of anaerobic ponds for the primary treatment of urban wastewater in a Mediterranean climate. It was carried out on anaerobic ponds at large scale in Mèze (France). The anaerobic ponds constitute a good primary treatment with the removal of 55% of SS and 30% of BOD5, with a small surface area. The accumulation rate of sludge was only 0.017 m3/capita.year, due to their intensive anaerobic degradation. The anaerobic digestion reached equilibrium after one year of operation. The accumulation of sludge then showed seasonal variations with a substantial accumulation in winter and the digestion of the stock in summer. This change can be related to the influence of the temperature on methanogenesis. The production of biogas (83% CH4) was measured by gas collectors especially developed for this study and was also strongly dependent on temperature. The mass balance of carbon showed that 74% of the removed organic carbon was converted into CH4, 13% into dissolved inorganic carbon and 15% was stored in sludge. However, the anaerobic ponds presented a risk of creating odor nuisances with the emission of H2S.

  16. An updated and quality controlled surface mass balance dataset for Antarctica

    Directory of Open Access Journals (Sweden)

    V. Favier

    2013-04-01

    Full Text Available We present an updated and quality controlled surface mass balance (SMB database for the Antarctic ice sheet. Importantly, the database includes formatted metadata, such as measurement technique, elevation, time covered, etc, which allows any user to filter out the data. Here, we discard data with limited spatial and temporal representativeness, too small measurement accuracy, or lack of quality control. Applied to the database, this filtering process gives four times more reliable data than when applied to previously available databases. New data with high spatial resolution are now available over long traverses, and at low elevation in some areas. However, the quality control led to a considerable reduction in the spatial density of data in several regions, particularly over West Antarctica. Over interior plateaus, where the SMB is low, the spatial density of measurements remains high. This quality controlled dataset was compared to results from ERA-Interim reanalysis to assess whether field data allow us to reconstruct an accurate description of the main SMB distribution features in Antarctica. We identified large areas where data gaps impede model validation: except for very few areas (e.g., Adelie Land, measurements in the elevation range between 200 m and 1000 m above sea level are not regularly distributed and do not allow a thorough validation of models in such regions with complex topography, where the highest scattering of SMB values is reported. Clearly, increasing the spatial density of field measurements at low elevations, in the Antarctic Peninsula and in West Antarctica is a scientific priority.

  17. A sensitivity analysis of the mass balance equation terms in subcooled flow boiling

    Energy Technology Data Exchange (ETDEWEB)

    Braz Filho, Francisco A.; Caldeira, Alexandre D.; Borges, Eduardo M., E-mail: fbraz@ieav.cta.br, E-mail: alexdc@ieav.cta.br, E-mail: eduardo@ieav.cta.br [Instituto de Estudos Avancados (IEAv), Sao Jose dos Campos, SP (Brazil). Div. de Energia Nuclear

    2013-07-01

    In a heated vertical channel, the subcooled flow boiling occurs when the fluid temperature reaches the saturation point, actually a small overheating, near the channel wall while the bulk fluid temperature is below this point. In this case, vapor bubbles are generated along the channel resulting in a significant increase in the heat flux between the wall and the fluid. This study is particularly important to the thermal-hydraulics analysis of Pressurized Water Reactors (PWRs). The computational fluid dynamics software FLUENT uses the Eulerian multiphase model to analyze the subcooled flow boiling. In a previous paper, the comparison of the FLUENT results with experimental data for the void fraction presented a good agreement, both at the beginning of boiling as in nucleate boiling at the end of the channel. In the region between these two points the comparison with experimental data was not so good. Thus, a sensitivity analysis of the mass balance equation terms, steam production and condensation, was performed. Factors applied to the terms mentioned above can improve the agreement of the FLUENT results to the experimental data. Void fraction calculations show satisfactory results in relation to the experimental data in pressures values of 15, 30 and 45 bars. (author)

  18. Geodetic mass balance of key glaciers across High Mountain Asia: a multi-decadal survey

    Science.gov (United States)

    Maurer, J. M.; Schaefer, J. M.; Rupper, S.; Corley, A. D.

    2016-12-01

    Glaciers in High Mountain Asia (HMA) supply seasonal meltwater for large populations, yet field observations are scarce and glacier sensitivities are poorly understood. In order to link complex atmospheric driving factors with heterogeneous glacier responses, detailed remote sensing observations of past changes in ice volume are needed. Here we compile a spatially and temporally extensive satellite-based remote sensing record to quantify multi-decadal geodetic mass balance of large mountain glaciers across key regions in HMA, including the Pamir, Himachal Pradesh, Uttarakhand, Nepal, Sikkim, and Bhutan regions. By utilizing declassified spy satellite imagery from the 1970's, ASTER scenes spanning 2000-present, and the ALOS global digital surface model, a methodologically homogenous assessment of regional and individual glacier responses to climate change over several decades is obtained. Although gaps due to low radiometric contrast result in significant uncertainties, the consistent approach across the HMA provides a useful comparison of relative geodetic changes between climatically diverse regions. Various patterns of ice loss are observed, including dynamic retreat of clean-ice glaciers and downwasting of debris-covered glaciers. In particular, we highlight the pronounced thinning and retreat of glaciers undergoing calving into proglacial lakes, which has important implications regarding ongoing and future ice loss of HMA glaciers.

  19. Kinetic and mass balance analysis of constructed wetlands treating landfill leachate.

    Science.gov (United States)

    Sawaittayothin, V; Polprasert, C

    2006-12-01

    Experiments were conducted to investigate the feasibility of applying constructed wetlands to treat a sanitary landfill leachate containing high nitrogen (TN) and bacterial contents. Two-pilot scale subsurface-flow constructed wetland (SFCW) units located at the Asian Institute of Technology, Thailand, campus, were fed with a synthetic wastewater and landfill leachate collected from a nearby sanitary landfill. Under the tropical conditions (temperature of about 30 degrees C), the SFCW units operating at the hydraulic retention time(HRT) of 8 days yielded the best treatment efficiencies with BOD, removal of 91%, TN removal of 96%, total and fecal coliforms (TC and FC) removal of more than 99% and cadmium removal of 99.7%. The treatment performance was found to follow first-order reaction rate, in which the k20 values of BOD5, COD, TN, TC, FC and Cd were 0.201, 0.121, 0.247, 0.346, 0.354 and 0.690 d(-1), respectively. Mass balance analysis, based on TN contents of the plant biomass and dissolved oxygen (DO) and oxidation- reduction potential (ORP) values, suggested that 88% of the input TN were uptaken by the plant biomass; 8% removed by nitrification-denitrification reactions and adsorption on the wetland media, while the remaining 4% were discharged with the effluent.

  20. Electrodynamic balance-mass spectrometry of single particles as a new platform for atmospheric chemistry research

    Science.gov (United States)

    Birdsall, Adam W.; Krieger, Ulrich K.; Keutsch, Frank N.

    2018-01-01

    New analytical techniques are needed to improve our understanding of the intertwined physical and chemical processes that affect the composition of aerosol particles in the Earth's atmosphere, such as gas-particle partitioning and homogenous or heterogeneous chemistry, and their ultimate relation to air quality and climate. We describe a new laboratory setup that couples an electrodynamic balance (EDB) to a mass spectrometer (MS). The EDB stores a single laboratory-generated particle in an electric field under atmospheric conditions for an arbitrarily long length of time. The particle is then transferred via gas flow to an ionization region that vaporizes and ionizes the analyte molecules before MS measurement. We demonstrate the feasibility of the technique by tracking evaporation of polyethylene glycol molecules and finding agreement with a kinetic model. Fitting data to the kinetic model also allows determination of vapor pressures to within a factor of 2. This EDB-MS system can be used to study fundamental chemical and physical processes involving particles that are difficult to isolate and study with other techniques. The results of such measurements can be used to improve our understanding of atmospheric particles.

  1. Mass and energy balances of sludge processing in reference and upgraded wastewater treatment plants.

    Science.gov (United States)

    Mininni, G; Laera, G; Bertanza, G; Canato, M; Sbrilli, A

    2015-05-01

    This paper describes the preliminary assessment of a platform of innovative upgrading solutions aimed at improving sludge management and resource recovery in wastewater treatment plants. The effectiveness of the upgrading solutions and the impacts of their integration in model reference plants have been evaluated by means of mass and energy balances on the whole treatment plant. Attention has been also paid to the fate of nitrogen and phosphorus in sludge processing and to their recycle back to the water line. Most of the upgrading options resulted in reduced production of dewatered sludge, which decreased from 45 to 56 g SS/(PE × day) in reference plants to 14-49 g SS/(PE × day) in the upgraded ones, with reduction up to 79% when wet oxidation was applied to the whole sludge production. The innovative upgrades generally entail an increased demand of electric energy from the grid, but energy recovery from biogas allowed to minimize the net energy consumption below 10 kWh/(PE × year) in the two most efficient solutions. In all other cases the net energy consumption was in the range of -11% and +28% of the reference scenarios.

  2. Direct mass measurements at the doorway to the region of superheavy elements

    Energy Technology Data Exchange (ETDEWEB)

    Minaya Ramirez, Enrique [Helmholtz-Institut, Mainz (Germany); GSI Helmholtzzentrum fuer Schwerionenforschung, Darmstadt (Germany); Collaboration: SHIPTRAP-Collaboration

    2011-07-01

    The exploration of the nuclear shell structure requires knowledge of the binding energy. A direct way to obtain this quantity is to perform high-precision mass measurements. Furthermore, the combination of {alpha}-decay spectroscopy and directly measured masses in the heavy and superheavy (Z {>=}104) element region allows determining the masses of higher- Z nuclides which supports the search for the island of stability. Recently, the masses of the nuclides {sup 255}No and {sup 255,256}Lr have been measured with high accuracy using the Penning trap mass spectrometer SHIPTRAP at GSI Darmstadt. The radionuclides were produced in fusion-evaporation reactions and separated from the primary beam by the velocity-filter SHIP. In addition, the accuracy of the {sup 252}No and {sup 254}No masses was further improved. Our measurements are the first measurements of the masses of {sup 255,256}Lr that have been only estimated from systematic trends until now. The new investigations follow our pioneering experiments at SHIPTRAP with the first direct mass measurements of three nobelium isotopes {sup 252-254}No. Only 10 nuclides of {sup 256}Lr are produced per minute, which is the lowest rate ever investigated at an on-line Penning trap mass spectrometer.

  3. Evidence of institutionalizing elements in the Balanced Scorecard in the book Strategy in action: a view based on institutional theory

    Directory of Open Access Journals (Sweden)

    Paschoal Tadeu Russo

    2012-04-01

    Full Text Available The Balanced Scorecard (BSC is a methodology that allows managers to define and implement a set of financial or nonfinancial indicators in a balanced way to assess an organization's performance from four viewpoints. Many companies are unsuccessful in their implementation of the BSC. This lack of success may be attributed to different factors, such as strategic problems, planning failures, and poorly defined targets and goals. However, the failed implementation may be attributed in part to the failure to institutionalize habits and routines. In this regard, this objective of this paper is to use institutional theory to determine whether the book Strategy in Action: Balanced Scorecard contains evidence that the BSC model proposed by the authors (Kaplan & Norton includes elements that favor the model's institutionalization. For this purpose, a qualitative bibliographic survey was prepared. The survey revealed 404 clues that were rated according to Tolbert and Zucker's description of the processes inherent to institutionalization and to Scott's proposed framework of legitimation/legitimizing. These findings suggest that the book primarily legitimizes the BSC by examining organizations and describes it as an acknowledged management instrument. The aspects supporting the semi-institutional stage (26% of the findings and the total institutionalization stage (10% of findings suggest that the authors intended to propose a tool without focusing on the institutionalization process, which may partly explain the great difficulty faced by companies attempting to implement this methodology.

  4. [Study on the determination of 14 inorganic elements in coffee by inductively coupled plasma mass spectrometry].

    Science.gov (United States)

    Nie, Xi-Du; Fu, Liang

    2013-07-01

    Samples of coffee were digested by microwave digestion, and inorganic elements amounts of Na, Mg, P, Ca, Cr, Mn, Fe, Co, Cu, Zn, As, Se, Mo and Pb in sample solutions were determined by inductively coupled plasma mass spectrometry (ICP-MS). HNO3 + H2O2 was used to achieve the complete decomposition of the organic matrix in a closed-vessel microwave oven. The working parameters of the instrument were optimized. The results showed that the relative standard deviation (RSD) was less than 3.84% for all the elements, and the recovery was found to be 92.00% -106.52% by adding standard recovery experiment. This method was simple, sensitive and precise and can perform simultaneous multi-elements determination of coffee, which could satisfy the sample examination request and provide scientific rationale for determining inorganic elements of coffee.

  5. Mass balance evolution of Martial Este Glacier, Tierra del Fuego (Argentina) for the period 1960-2099

    Science.gov (United States)

    Buttstädt, M.; Möller, M.; Iturraspe, R.; Schneider, C.

    2009-12-01

    The Martial Este Glacier in southern Tierra del Fuego was studied in order to estimate the surface mass balance from 1960 until 2099. For this reason a degree-day model was calibrated. Air temperature and precipitation data obtained from 3 weather stations as well as glaciological measurements were applied. The model was driven using a vertical air temperature gradient of 0.69 K/100 m, a degree-day factor for snow of 4.7 mm w.e. K-1 day-1, a degree-day factor for ice of 9.4 mm w.e. K-1 day-1 and a precipitation gradient of 22%/100 m. For the purpose of surface mass balance reconstruction for the time period 1960 until 2006 a winter vertical air temperature gradient of 0.57 K/100 m and a summer vertical air temperature gradient of 0.71 K/100 m were added as well as a digital terrain model. The key finding is an almost continuous negative mass balance of -772 mm w.e. a-1 throughout this period. While the calculation of the mass balance for the period 1960-2006 is based on instrumental records, the mass balance for the years 2007 until 2099 was estimated based on the IPCC SRES A2-scenario. To accomplish this estimation, the dataset of the global climate model HadCM3 was statistically downscaled to fit local conditions at Martial Este Glacier. Subsequently, the downscaled air temperature and precipitation were applied to a volume-area scaling glacier change model. Findings reveal an enduring deglaciation resulting in a surface area reduction of nearly 93% until 2099. This implicates that the Martial Este Glacier might be melted off at the beginning of the 22nd century.

  6. Mass balance evolution of Martial Este Glacier, Tierra del Fuego (Argentina for the period 1960–2099

    Directory of Open Access Journals (Sweden)

    M. Buttstädt

    2009-12-01

    Full Text Available The Martial Este Glacier in southern Tierra del Fuego was studied in order to estimate the surface mass balance from 1960 until 2099. For this reason a degree-day model was calibrated. Air temperature and precipitation data obtained from 3 weather stations as well as glaciological measurements were applied. The model was driven using a vertical air temperature gradient of 0.69 K/100 m, a degree-day factor for snow of 4.7 mm w.e. K−1 day−1, a degree-day factor for ice of 9.4 mm w.e. K−1 day−1 and a precipitation gradient of 22%/100 m. For the purpose of surface mass balance reconstruction for the time period 1960 until 2006 a winter vertical air temperature gradient of 0.57 K/100 m and a summer vertical air temperature gradient of 0.71 K/100 m were added as well as a digital terrain model. The key finding is an almost continuous negative mass balance of −772 mm w.e. a−1 throughout this period. While the calculation of the mass balance for the period 1960–2006 is based on instrumental records, the mass balance for the years 2007 until 2099 was estimated based on the IPCC SRES A2-scenario. To accomplish this estimation, the dataset of the global climate model HadCM3 was statistically downscaled to fit local conditions at Martial Este Glacier. Subsequently, the downscaled air temperature and precipitation were applied to a volume-area scaling glacier change model. Findings reveal an enduring deglaciation resulting in a surface area reduction of nearly 93% until 2099. This implicates that the Martial Este Glacier might be melted off at the beginning of the 22nd century.

  7. Influence of meteorological elements on balance control and pain in patients with symptomatic knee osteoarthritis

    Science.gov (United States)

    Peultier, Laetitia; Lion, Alexis; Chary-Valckenaere, Isabelle; Loeuille, Damien; Zhang, Zheng; Rat, Anne-Christine; Gueguen, René; Paysant, Jean; Perrin, Philippe P.

    2017-05-01

    This study aimed to determine if pain and balance control are related to meteorological modifications in patients with knee osteoarthritis (OA). One hundred and thirteen patients with knee OA (mean age = 65 ± 9 years old, 78 women) participated in this study. Static posturography was performed, sway area covered and sway path traveled by the center of foot pressure being recorded under six standing postural conditions that combine three visual situations (eyes open, eyes closed, vision altered) with two platform situations (firm and foam supports). Knee pain score was assessed using a visual analog scale. Balance control and pain measurements recorded in the morning were correlated with the meteorological data. Morning and daily values for temperature, precipitation, sunshine, height of rain in 1 h, wind speed, humidity, and atmospheric pressure were obtained from the nearest data collecting weather station. The relationship between postural control, pain, and weather variations were assessed for each patient on a given day with multiple linear regressions. A decrease of postural stability was observed when atmospheric pressure and maximum humidity decreased in the morning ( p knee pain was more enhanced when it is warmer in the morning ( p < 0.05) and when it is wetter and warmer within a day ( p < 0.05). The relationship between weather, pain, and postural control can help patients and health professionals to better manage daily activities.

  8. Bioessential element-depleted ocean following the euxinic maximum of the end-Permian mass extinction

    Science.gov (United States)

    Takahashi, Satoshi; Yamasaki, Shin-ichi; Ogawa, Yasumasa; Kimura, Kazuhiko; Kaiho, Kunio; Yoshida, Takeyoshi; Tsuchiya, Noriyoshi

    2014-05-01

    We describe variations in trace element compositions that occurred on the deep seafloor of palaeo-superocean Panthalassa during the end-Permian mass extinction based on samples of sedimentary rock from one of the most continuous Permian-Triassic boundary sections of the pelagic deep sea exposed in north-eastern Japan. Our measurements revealed low manganese (Mn) enrichment factor (normalised by the composition of the average upper continental crust) and high cerium anomaly values throughout the section, suggesting that a reducing condition already existed in the depositional environment in the Changhsingian (Late Permian). Other redox-sensitive trace-element (vanadium [V], chromium [Cr], molybdenum [Mo], and uranium [U]) enrichment factors provide a detailed redox history ranging from the upper Permian to the end of the Permian. A single V increase (representing the first reduction state of a two-step V reduction process) detected in uppermost Changhsingian chert beds suggests development into a mildly reducing deep-sea condition less than 1 million years before the end-Permian mass extinction. Subsequently, a more reducing condition, inferred from increases in Cr, V, and Mo, developed in overlying Changhsingian grey siliceous claystone beds. The most reducing sulphidic condition is recognised by the highest peaks of Mo and V (second reduction state) in the uppermost siliceous claystone and overlying lowermost black claystone beds, in accordance with the end-Permian mass extinction event. This significant increase in Mo in the upper Changhsingian led to a high Mo/U ratio, much larger than that of modern sulphidic ocean regions. This trend suggests that sulphidic water conditions developed both at the sediment-water interface and in the water column. Above the end-Permian mass extinction horizon, Mo, V and Cr decrease significantly. On this trend, we provide an interpretation of drawdown of these elements in seawater after the massive element precipitation event

  9. Application of a contaminant mass balance method at an old landfill to assess the impact on water resources

    DEFF Research Database (Denmark)

    Thomsen, Nanna Isbak; Milosevic, Nemanja; Bjerg, Poul Løgstrup

    2012-01-01

    linking soil and groundwater contamination to surface water pollution are required. This paper presents a method which provides an estimate of the contaminant mass discharge, using a combination of a historical investigation and contaminant mass balance approach. The method works at the screening level......Old and unlined landfill sites pose a risk to groundwater and surface water resources. While landfill leachate plumes in sandy aquifers have been studied, landfills in clay till settings and their impact on receiving water bodies are not well understood. In addition, methods for quantitatively...... of chloride to the small Risby Stream down gradient of the landfill was approximately 31kg/year. The contaminant mass balance method worked well for chloride and dissolved organic carbon, but the uncertainties were elevated for ammonium due to substantial spatial variability in the source composition...

  10. The mass balance of production and consumption: Supporting policy-makers for aquatic food security

    Science.gov (United States)

    Lopes, A. S.; Ferreira, J. G.; Vale, C.; Johansen, J.

    2017-03-01

    This work addresses divergences between data on consumption and availability for wild-caught and farmed fish, and normalisation of reported production data, to support integrated fisheries and aquaculture management. The methodologies developed, centred on improved parameterisation and on mass balance closure, were tested in two case studies: (i) the cod fishery in Europe, with particular emphasis on Iceland and the United Kingdom; and (ii) the overall balance of aquatic products for Portugal, the ICES member with the most diverse range of landed marine species. Data for consumption, Illegal, Unreported, or Unregulated (IUU) catch, and official availability statistics were used to identify discrepancies between consumption and official availability data. The identification of discrepancies between supply and demand, when coupled with source-discriminated data, showed a pattern where products with no unmet demand tend to display a considerable IUU percentage-above 9% in three cases (hake, sardine, and horse mackerel). By contrast with fished products with an over-met demand such as cod (144%) and sardine (124%), farmed species display low Optimal Consumption Level (OCL) satisfaction. Atlantic salmon, gilthead seabream, and European seabass register 45%, 58% and 44% respectively; this suggests a considerable unmet demand for these products and/or a high volume of undeclared fish reaching consumers, which may be due to the lack of landings control that exists for wild-caught fish. Improvements to production estimates using live-weight coefficients illustrate the impacts of seafood processing. Different processing methods can generate variations in live-weight estimates, leading to errors in officially reported data, and expose the limitations of the current statistical methods. As an example, the corrected per capita consumption for Portugal for 2014 (the latest FAO data) increases from 57 to 66 kg ind-1 y-1, which places the country as the second-greatest consumer in

  11. Greenland ice sheet surface mass-balance modeling in a 131-year perspective, 1950-2080

    Energy Technology Data Exchange (ETDEWEB)

    Mernild, Sebastian Haugard [Los Alamos National Laboratory; Liston, Glen [COLORADO STATE UNIV.; Hiemstra, Christopher [COLORADO STATE UNIV.; Christensen, Jens [DANISH METEOROLOGICAL INS.

    2009-01-01

    Fluctuations in the Greenland Ice Sheet (GrIS) surface mass-balance (SMB) and freshwater influx to the surrounding oceans closely follow climate fluctuations and are of considerable importance to the global eustatic sea level rise. SnowModel, a state-of-the-art snow-evolution modeling system, was used to simulate variations in the GrIS melt extent, surface water balance components, changes in SMB, and freshwater influx to the ocean. The simulations are based on the IPCC scenario AlB modeled by the HIRHAM4 RCM (using boundary conditions from ECHAM5 AOGCM) from 1950 through 2080. In-situ meteorological station (GC-Net and WMO DMI) observations from inside and outside the GrIS were used to validate and correct RCM output data before it was used as input for SnowModel. Satellite observations and independent SMB studies were used to validate the SnowModel output and confirm the model's robustness. We simulated a {approx}90% increase in end-of-summer surface melt extent (0.483 x 10{sup 6} km{sup 2}) from 1950 to 2080, and a melt index (above 2,000-m elevation) increase of 138% (1.96 x 10{sup 6} km{sup 2} x days). The greatest difference in melt extent occured in the southern part of the GrIS, and the greatest changes in the number of melt days was seen in the eastern part of the GrIS ({approx}50-70%) and was lowest in the west ({approx}20-30%). The rate of SMB loss, largely tied to changes in ablation processes, lead to an enhanced average loss of 331 km{sup 3} from 1950 to 2080, an average 5MB level of -99 km{sup 3} for the period 2070-2080. GrIS surface freshwater runoff yielded an eustatic rise in sea level from 0.8 {+-} 0.1 (1950-1959) to 1.9 {+-} 0.1 mm (2070-2080) sea level equivalent (SLE) y{sup -1}. The accumulated GrIS freshwater runoff contribution from surface melting equaled 160 mm SLE from 1950 through 2080.

  12. Mass balance and surface velocity reconstructions of two reference Caucasus glaciers

    Science.gov (United States)

    Rybak, Oleg; Kaminskaia, Mariia; Kutuzov, Stanislav; Lavrentiev, Ivan; Morozova, Polina; Popovnin, Victor; Rybak, Elena

    2016-04-01

    Total glacial volume of the Greater Caucasus exceeds 40 cubic km and its area exceeds 1 thousand square km. During the 20th century, mountain glaciers at the Greater Caucasus were continuously degrading. According to various estimates, their area reduced more than one-third and their volume almost by half. The process of degradation was accompanied by growing population and economical development on surrounding territories. In the 21st century under proceeding global warming, a tendency of shrinking of area and volume of glaciation is obviously expected to continue. Working out of strategy of sustainable economic development of the region is the main motivation for elaboration of predictions of glaciers' evolution in the changing environment. Growing demand of fresh water is the basic challenge for the local economy, and efficient planning of water resources is impossible without knowing future state of glaciation. Therefore our research aims at obtaining accurate evaluation of probable future change of the most prominent mountain glaciers of the Greater Caucasus in forthcoming decades and at studying impacts of changing characteristics of glaciation on the run-off in the area. Initially, we focus on two so-called reference glaciers - Marukh (Western Caucasus) and Djankuat (Central Caucasus). Intensive field observations on both of them have been conducted during the last half of the century and essential amount of detailed relevant information has been collected on their geometry change and on mass balance. Besides, meteorological measurements were episodically carried out directly on the glaciers providing enough data for correlation of the local weather conditions with the data from the closest meteorological stations. That is why studying of response of Marukh and Djankuat on the environmental change can be accurately verified, which is crucial for understanding mechanisms driving evolution of large glaciated area in the Caucasus. As the instrument of research

  13. FEHMN 1.0: Finite element heat and mass transfer code; Revision 1

    Energy Technology Data Exchange (ETDEWEB)

    Zyvoloski, G.; Dash, Z.; Kelkar, S.

    1992-05-01

    A computer code is described which can simulate non-isothermal multi-phase multicomponent flow in porous media. It is applicable to natural-state studies of geothermal systems and groundwater flow. The equations of heat and mass transfer for multiphase flow in porous and permeable media are solved sing the finite element method. The permeability and porosity of the medium are allowed to depend on pressure and temperature. The code also has provisions for movable air and water phases and noncoupled tracers; that is, tracer solutions that do not affect the heat and mass transfer solutions. The tracers can be passive or reactive. The code can simulate two-dimensional, two-dimensional radial, or three-dimensional geometries. A summary of the equations in the model and the numerical solution procedure are provided in this report. A user`s guide and sample problems are also included. The FEHMN (Finite Element Heat and Mass Nuclear) code, described in this report, is a version of FEHM (Finite Element Heat and Mass, Zyvoloski et al., 1988) developed for the Yucca Mountain Site Characterization Project (YMP). The main use of FEHMN will be to assist in the understanding of flow fields in the saturated zone below the potential Yucca Mountain repository.

  14. Estimation of Groundwater Recharge at Pahute Mesa using the Chloride Mass-Balance Method

    Energy Technology Data Exchange (ETDEWEB)

    Cooper, Clay A [DRI; Hershey, Ronald L [DRI; Healey, John M [DRI; Lyles, Brad F [DRI

    2013-07-01

    Groundwater recharge on Pahute Mesa was estimated using the chloride mass-balance (CMB) method. This method relies on the conservative properties of chloride to trace its movement from the atmosphere as dry- and wet-deposition through the soil zone and ultimately to the saturated zone. Typically, the CMB method assumes no mixing of groundwater with different chloride concentrations; however, because groundwater is thought to flow into Pahute Mesa from valleys north of Pahute Mesa, groundwater flow rates (i.e., underflow) and chloride concentrations from Kawich Valley and Gold Flat were carefully considered. Precipitation was measured with bulk and tipping-bucket precipitation gauges installed for this study at six sites on Pahute Mesa. These data, along with historical precipitation amounts from gauges on Pahute Mesa and estimates from the PRISM model, were evaluated to estimate mean annual precipitation. Chloride deposition from the atmosphere was estimated by analyzing quarterly samples of wet- and dry-deposition for chloride in the bulk gauges and evaluating chloride wet-deposition amounts measured at other locations by the National Atmospheric Deposition Program. Mean chloride concentrations in groundwater were estimated using data from the UGTA Geochemistry Database, data from other reports, and data from samples collected from emplacement boreholes for this study. Calculations were conducted assuming both no underflow and underflow from Kawich Valley and Gold Flat. Model results estimate recharge to be 30 mm/yr with a standard deviation of 18 mm/yr on Pahute Mesa, for elevations >1800 m amsl. These estimates assume Pahute Mesa recharge mixes completely with underflow from Kawich Valley and Gold Flat. The model assumes that precipitation, chloride concentration in bulk deposition, underflow and its chloride concentration, have been constant over the length of time of recharge.

  15. Incorrectly Interpreting the Carbon Mass Balance Technique Leads to Biased Emissions Estimates from Global Vegetation Fires

    Science.gov (United States)

    Surawski, N. C.; Sullivan, A. L.; Roxburgh, S. H.; Meyer, M.; Polglase, P. J.

    2016-12-01

    Vegetation fires are a complex phenomenon and have a range of global impacts including influences on climate. Even though fire is a necessary disturbance for the maintenance of some ecosystems, a range of anthropogenically deleterious consequences are associated with it, such as damage to assets and infrastructure, loss of life, as well as degradation to air quality leading to negative impacts on human health. Estimating carbon emissions from fire relies on a carbon mass balance technique which has evolved with two different interpretations in the fire emissions community. Databases reporting global fire emissions estimates use an approach based on `consumed biomass' which is an approximation to the biogeochemically correct `burnt carbon' approach. Disagreement between the two methods occurs because the `consumed biomass' accounting technique assumes that all burnt carbon is volatilized and emitted. By undertaking a global review of the fraction of burnt carbon emitted to the atmosphere, we show that the `consumed biomass' accounting approach overestimates global carbon emissions by 4.0%, or 100 Teragrams, annually. The required correction is significant and represents 9% of the net global forest carbon sink estimated annually. To correctly partition burnt carbon between that emitted to the atmosphere and that remaining as a post-fire residue requires the post-burn carbon content to be estimated, which is quite often not undertaken in atmospheric emissions studies. To broaden our understanding of ecosystem carbon fluxes, it is recommended that the change in carbon content associated with burnt residues be accounted for. Apart from correctly partitioning burnt carbon between the emitted and residue pools, it enables an accounting approach which can assess the efficacy of fire management operations targeted at sequestering carbon from fire. These findings are particularly relevant for the second commitment period for the Kyoto protocol, since improved landscape fire

  16. A mass balance model for the Mapleson D anaesthesia breathing system.

    Science.gov (United States)

    Lovich, M A; Simon, B A; Venegas, J G; Sims, N M; Cooper, J B

    1993-06-01

    A mathematical model is described which calculates the alveolar concentration of CO2(FACO2) in a patient breathing through a Mapleson D anaesthesia system. The model is derived using a series of mass balances for CO2 in the alveolar space, dead space, breathing system limb volume and reservoir. The variables included in the model are tidal volume (VT), respiratory rate, fresh gas flow rate (Vf), dead space volume, I:E ratio, and expiratory limb volume (Vl) time constant of lung expiration, and carbon dioxide production rate. The model predictions are compared with measurements made using a mechanical lung simulator in both spontaneous and controlled ventilation. Both the model and the experimental data predict that at high fresh gas flow rates and low respiratory rates, FACO2 is independent of Vf; at low fresh gas flow rates and high respiratory rates, FACO2 is independent of respiratory rate. The model and the data show that the VT influences FACO2, independent of minute ventilation alone, during both partial re-breathing and non-rebreathing operation. Therefore, describing the operation in terms of minute ventilation is ambiguous. It is also shown that Vl influences FACO2 such that, for any combination of patient and breathing-system variables, there is a Vl that minimizes the Vf required to maintain FACO2. In addition, expiratory resistance can increase the fresh gas flow rate required to maintain a given FACO2. The respiratory patterns observed with spontaneous and controlled ventilation are responsible for the difference in Vf required with each mode of ventilation.

  17. Mass balance and metabolism of Z-215, a novel proton pump inhibitor, in healthy volunteers.

    Science.gov (United States)

    Toda, Ryoko; Miyagawa, Tomoharu; Masuda, Yuka; Hoshino, Yusuke; Yoshii, Kazuyoshi; Hirayama, Masamichi; Shibuya, Minaka; Kawabata, Yoshihiro

    2017-11-02

    The human mass balance of [(14 )C]Z-215, a novel proton pump inhibitor, was characterised in six healthy male volunteers following single oral administration of [(14 )C]Z-215 (20 mg, 3.7 MBq) to determine the elimination pathway of Z-215 and the distribution of its metabolites in plasma, urine, and faeces (NCT02618629). [(14 )C]Z-215 was rapidly absorbed, with a Cmax of 434 ng/mL at 0.38 h for Z-215 and 732 ng eq./mL at 0.5 h for total radioactivity. Means of 59.61% and 31.36% of the administered radioactive dose were excreted in urine and faeces, respectively, within 168 h post-dose. The majority of the dose was recovered within 24 h in urine and 96 h in faeces. Unchanged Z-215 was excreted in urine at trace levels but was not detected in faeces. The main components in plasma were Z-215 and Z-215 sulphone, accounting for 29.8% and 13.3% of the total circulating radioactivity, respectively. Additionally, Z-215 was metabolised through oxidation, reduction and conjugation. Our in vitro Z-215 metabolism study showed that the major isozyme contributing to the oxidation of Z-215, including the formation of Z-215 sulphone, was CYP3A4. In conclusion, Z-215 is well absorbed in humans and primarily eliminated via metabolism, where CYP3A4 plays an important role.

  18. Studying the capture cross sections of constructional elements from measurements of the neutron balance in breeder media

    Energy Technology Data Exchange (ETDEWEB)

    Golubev, V.I.; Dulin, V.A.; Kazanskii, Yu.A.; Darrouzet, M.; Martin-Deidier, L.; Rimpault, G.

    1987-04-01

    Until recently, the indeterminacy in the group capture cross sections of constructional elements at neutron energies above 1 keV were estimated at 15-20%, leading to an error of 0.2 and 1%, respectively, in calculating K/sub ef/ and the conversion factor of breeder reactors with oxide fuel and sodium coolant. In fact, calculations using the BNAB-78 group constants used in the USSR for the design development of fast reactors show that the mean neutron capture cross section of constructional elements (iron, nickel, and chromium) is approx. 1.4 times greater for a typical breeder reactor than in the case of calculation by the version of Carnaval IV used in France for the Superphoenix reactors. To refine the proportion of neutrons absorbed in stainless steel, the neutron balance in media consisting of uranium fuel and stainless steel with nickel in a proportion ensuring a near-unity breeder coefficient of infinite media of this composition (K/sub infinity/ = 1) has been measured at the Power-Physics Institute in Obninsk and at the Center for Nuclear Research in Caradache. The results obtained allow the accuracy of calculating the proportion of neutrons absorbed in constructional elements to be judged

  19. Impacts of invasive earthworms on soil mercury cycling: Two mass balance approaches to an earthworm invasion in a northern Minnesota forest

    Science.gov (United States)

    Sona Psarska; Edward A. Nater; Randy Kolka

    2016-01-01

    Invasive earthworms perturb natural forest ecosystems that initially developed without them, mainly by consuming the forest floor (an organic rich surficial soil horizon) and by mixing the upper parts of the soil. The fate of mercury (Hg) formerly contained in the forest floor is largely unknown. We used two mass balance approaches (simple mass balance and geochemical...

  20. Force Balance Conditions of Complex Parallel Mechanisms with Mass Equivalent Modeling

    NARCIS (Netherlands)

    van der Wijk, V.

    2016-01-01

    A shaking force balanced mechanism is a mechanism that does not exert dynamic re-action forces to its base and to its surrounding for any motion. For mobile mechanisms such as exoskeletons, humanoid robots, drones, and anthropomorphic hands force balance is an important property for, among others,

  1. Sensitivity of glacier mass balance and equilibrium line altitude to climatic change on King George Island, Antarctic Peninsula.

    Science.gov (United States)

    Falk, Ulrike; Lopez, Damian; Silva-Busso, Adrian

    2017-04-01

    The South Shetland Islands are located at the northern tip of the Antarctic Peninsula which is among the fastest warming regions on Earth. Surface air temperature increases (ca. 3 K in 50 years) are concurrent with retreating glacier fronts, an increase in melt areas, ice surface lowering and rapid break-up and disintegration of ice shelves. Observed surface air temperature lapse rates show a high variability during winter months (standard deviations up to ±1.0 K/100 m), and a distinct spatial heterogeneity reflecting the impact of synoptic weather patterns especially during winter glacial mass accumulation periods. The increased mesocyclonic activity during the winter time in the study area results in intensified advection of warm, moist air with high temperatures and rain, and leads to melt conditions on the ice cap, fixating surface air temperatures to the melting point. The impact on winter accumulation results in even more negative mass balance estimates. Six years of glaciological measurements on mass balance stake transects are used with a glacier melt model to assess changes in melt water input to the coastal waters, glacier surface mass balance and the equilibrium line altitude. The average equilibrium line altitude (ELA) calculated from own glaciological observations for KGI over the time period 2010 - 2015 amounts to ELA=330±100 m. Published studies suggest rather stable condition slightly negative glacier mass balance until the mid 80's with an ELA of approx. 150 m. The calculated accumulation area ratio suggests rather dramatic changes in extension of the inland ice cap for the South Shetland Islands until an equilibrium with concurrent climate conditions is reached.

  2. A systems analysis of biodiesel production from wheat straw using oleaginous yeast: process design, mass and energy balances.

    Science.gov (United States)

    Karlsson, Hanna; Ahlgren, Serina; Sandgren, Mats; Passoth, Volkmar; Wallberg, Ola; Hansson, Per-Anders

    2016-01-01

    Biodiesel is the main liquid biofuel in the EU and is currently mainly produced from vegetable oils. Alternative feedstocks are lignocellulosic materials, which provide several benefits compared with many existing feedstocks. This study examined a technical process and its mass and energy balances to gain a systems perspective of combined biodiesel (FAME) and biogas production from straw using oleaginous yeasts. Important process parameters with a determining impact on overall mass and energy balances were identified and evaluated. In the base case, 41% of energy in the biomass was converted to energy products, primary fossil fuel use was 0.37 MJprim/MJ produced and 5.74 MJ fossil fuels could be replaced per kg straw dry matter. The electricity and heat produced from burning the lignin were sufficient for process demands except in scenarios where the yeast was dried for lipid extraction. Using the residual yeast cell mass for biogas production greatly increased the energy yield, with biogas contributing 38% of total energy products. In extraction methods without drying the yeast, increasing lipid yield and decreasing the residence time for lipid accumulation are important for the energy and mass balance. Changing the lipid extraction method from wet to dry makes the greatest change to the mass and energy balance. Bioreactor agitation and aeration for lipid accumulation and yeast propagation is energy demanding. Changes in sugar concentration in the hydrolysate and residence times for lipid accumulation greatly affect electricity demand, but have relatively small impacts on fossil energy use (NER) and energy yield (EE). The impact would probably be greater if externally produced electricity were used.

  3. Multivariate Analysis, Mass Balance Techniques, and Statistical Tests as Tools in Igneous Petrology: Application to the Sierra de las Cruces Volcanic Range (Mexican Volcanic Belt

    Directory of Open Access Journals (Sweden)

    Fernando Velasco-Tapia

    2014-01-01

    Full Text Available Magmatic processes have usually been identified and evaluated using qualitative or semiquantitative geochemical or isotopic tools based on a restricted number of variables. However, a more complete and quantitative view could be reached applying multivariate analysis, mass balance techniques, and statistical tests. As an example, in this work a statistical and quantitative scheme is applied to analyze the geochemical features for the Sierra de las Cruces (SC volcanic range (Mexican Volcanic Belt. In this locality, the volcanic activity (3.7 to 0.5 Ma was dominantly dacitic, but the presence of spheroidal andesitic enclaves and/or diverse disequilibrium features in majority of lavas confirms the operation of magma mixing/mingling. New discriminant-function-based multidimensional diagrams were used to discriminate tectonic setting. Statistical tests of discordancy and significance were applied to evaluate the influence of the subducting Cocos plate, which seems to be rather negligible for the SC magmas in relation to several major and trace elements. A cluster analysis following Ward’s linkage rule was carried out to classify the SC volcanic rocks geochemical groups. Finally, two mass-balance schemes were applied for the quantitative evaluation of the proportion of the end-member components (dacitic and andesitic magmas in the comingled lavas (binary mixtures.

  4. Coupled porohyperelastic mass transport (PHEXPT) finite element models for soft tissues using ABAQUS.

    Science.gov (United States)

    Vande Geest, Jonathan P; Simon, B R; Rigby, Paul H; Newberg, Tyler P

    2011-04-01

    Finite element models (FEMs) including characteristic large deformations in highly nonlinear materials (hyperelasticity and coupled diffusive/convective transport of neutral mobile species) will allow quantitative study of in vivo tissues. Such FEMs will provide basic understanding of normal and pathological tissue responses and lead to optimization of local drug delivery strategies. We present a coupled porohyperelastic mass transport (PHEXPT) finite element approach developed using a commercially available ABAQUS finite element software. The PHEXPT transient simulations are based on sequential solution of the porohyperelastic (PHE) and mass transport (XPT) problems where an Eulerian PHE FEM is coupled to a Lagrangian XPT FEM using a custom-written FORTRAN program. The PHEXPT theoretical background is derived in the context of porous media transport theory and extended to ABAQUS finite element formulations. The essential assumptions needed in order to use ABAQUS are clearly identified in the derivation. Representative benchmark finite element simulations are provided along with analytical solutions (when appropriate). These simulations demonstrate the differences in transient and steady state responses including finite deformations, total stress, fluid pressure, relative fluid, and mobile species flux. A detailed description of important model considerations (e.g., material property functions and jump discontinuities at material interfaces) is also presented in the context of finite deformations. The ABAQUS-based PHEXPT approach enables the use of the available ABAQUS capabilities (interactive FEM mesh generation, finite element libraries, nonlinear material laws, pre- and postprocessing, etc.). PHEXPT FEMs can be used to simulate the transport of a relatively large neutral species (negligible osmotic fluid flux) in highly deformable hydrated soft tissues and tissue-engineered materials.

  5. Added Mass estimation of square sections coupled with a liquid using finite element method

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Kyeong Hoon [SMART Development Division, Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Jhung, Myung Jo [Safety Research Division, Korea Institute of Nuclear Safety, Daejeon (Korea, Republic of)

    2017-02-15

    Natural frequencies of immersed square sections decrease due to a contribution of added mass to the movement of square sections. In this study, natural frequencies of square sections are obtained as a function of gap size between the square section and a rigid square wall using the finite element method. Additionally, they are used to extract the added mass effect on translational and rotation motions. Published information and studies on the translational and torsional vibration of square beams are also examined for practical use. D coupling of a square section is also investigated for multiple square sections. The suggested added mass estimation can be applicable to the spent fuel storage design of a pressurized light water modulated nuclear power plant.

  6. Measurement of the Top Quark Mass Using the Matrix Element Technique in Dilepton Final States

    CERN Document Server

    Abazov, Victor Mukhamedovich

    2016-08-18

    We present a measurement of the top quark mass in ppbar collisions at a center-of-mass energy of 1.96 TeV at the Fermilab Tevatron collider. The data were collected by the D0 experiment corresponding to an integrated luminosity of 9.7 fb-1. The matrix element technique is applied to ttbar events in the final state containing leptons (electrons or muons) with high transverse momenta and at least two jets. The calibration of the jet energy scale determined in the lepton + jets final state of ttbar decays is applied to jet energies. This correction provides a substantial reduction in systematic uncertainties. We obtain a top quark mass of mt = 173.93 +- 1.84 GeV.

  7. Extending direct mass measurements in the region of the heaviest elements at SHIPTRAP

    Energy Technology Data Exchange (ETDEWEB)

    Giacoppo, Francesca [GSI, Darmstadt (Germany); Helmholtz Institut Mainz (Germany); Collaboration: SHIPTRAP-Collaboration

    2016-07-01

    Penning-trap mass spectrometry allows direct measurements of atomic masses with high precision. This technique is especially suitable to investigate the nuclear structure evolution of radioactive nuclides through binding energies. The heaviest elements investigated so far in pioneering experiments with the SHIPTRAP setup at GSI, Darmstadt, have been nobelium and lawrencium. The existence of such heavy nuclei is closely connected to the nuclear shell effects that stabilize them against spontaneous fission. The direct measurement of the masses of {sup 252-255}No and {sup 255,256}Lr has allowed mapping the evolution of the deformed subshell closure along N=152. In order to extend such studies to heavier and more exotic nuclides, the efficiency and sensitivity of the SHIPTRAP setup has to be further increased. In this talk, an overview of the related developments will be presented. In particular, the online commissioning of a cryogenic buffer gas-stopping cell with improved efficiency will be reported.

  8. The changing impact of snow conditions and refreezing on the mass balance of an idealized Svalbard glacier

    Directory of Open Access Journals (Sweden)

    Ward Van Pelt

    2016-11-01

    Full Text Available Glacier surface melt and runoff depend strongly on seasonal and perennial snow (firn conditions. Not only does the presence of snow and firn directly affect melt rates by reflecting solar radiation, it may also act as a buffer against mass loss by storing melt water in refrozen or liquid form. In Svalbard, ongoing and projected amplified climate change with respect to the global mean change has severe implications for the state of snow and firn and its impact on glacier mass loss. Model experiments with a coupled surface energy balance - firn model were done to investigate the surface mass balance and the changing role of snow and firn conditions for an idealized Svalbard glacier. A climate forcing for the past, present and future (1984-2104 is constructed, based on observational data from Svalbard Airport and a seasonally dependent projection scenario. Results illustrate ongoing and future firn degradation in response to an elevational retreat of the equilibrium line altitude (ELA of 31 m decade−1. The temperate firn zone is found to retreat and expand, while cold ice in the ablation zone warms considerably. In response to pronounced winter warming and an associated increase in winter rainfall, the current prevalence of refreezing during the melt season gradually shifts to the winter season in a future climate. Sensitivity tests reveal that in a present and future climate the density and thermodynamic structure of Svalbard glaciers are heavily influenced by refreezing. Refreezing acts as a net buffer against mass loss. However, the net mass balance change after refreezing is substantially smaller than the amount of refreezing itself, which can be ascribed to melt-enhancing effects after refreezing, which partly offset the primary mass-retaining effect of refreezing.

  9. Seasonal changes in surface albedo of Himalayan glaciers from MODIS data and links with the annual mass balance

    OpenAIRE

    Brun, F.; Dumont, M; Wagnon, P.; Berthier, E.; Azam, M F; J. M. Shea; P. Sirguey; A. Rabatel; Ramanathan, AL

    2015-01-01

    Few glaciological field data are available on glaciers in the Hindu Kush–Karakoram–Himalayan (HKH) region, and remote sensing data are thus critical for glacier studies in this region. The main objectives of this study are to document, using satellite images, the seasonal changes of surface albedo for two Himalayan glaciers, Chhota Shigri Glacier (Himachal Pradesh, India) and Mera Glacier (Everest region, Nepal), and to reconstruct the annual mass balance of these gla...

  10. E-Area Low-Level Waste Facility Vadose Zone Model: Confirmation of Water Mass Balance for Subsidence Scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Dyer, J. A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-11-30

    In preparation for the next revision of the E-Area Low-Level Waste Facility (LLWF) Performance Assessment (PA), a mass balance model was developed in Microsoft Excel to confirm correct implementation of intact- and subsided-area infiltration profiles for the proposed closure cap in the PORFLOW vadose-zone model. The infiltration profiles are based on the results of Hydrologic Evaluation of Landfill Performance (HELP) model simulations for both intact and subsided cases.

  11. Theory of the generalized chloride mass balance method for recharge estimation in groundwater basins characterised by point and diffuse recharge

    OpenAIRE

    N. Somaratne; K. R. J. Smettem

    2014-01-01

    Application of the conventional chloride mass balance (CMB) method to point recharge dominant groundwater basins can substantially under-estimate long-term average annual recharge by not accounting for the effects of localized surface water inputs. This is because the conventional CMB method ignores the duality of infiltration and recharge found in karstic systems, where point recharge can be a contributing factor. When point recharge is present in groundwater basins,...

  12. Mass balance of the Greenland ice sheet - a study of ICESat data, surface density and firn compaction modelling

    OpenAIRE

    Sørensen, L. S.; Simonsen, S.B.; Nielsen, K.; Lucas-Picher, P.; Spada, G.; G. Adalgeirsdottir; Forsberg, R.; Hvidberg, C. S.

    2010-01-01

    ICESat has provided surface elevation measurements of the ice sheets since the launch in January 2003, resulting in a unique data set for monitoring the changes of the cryosphere. Here we present a novel method for determining the mass balance of the Greenland ice sheet derived from ICESat altimetry data.

    Four different methods for deriving the elevation changes from the ICESat altimetry data set are used. This multi method approach gives an understanding of the co...

  13. A case-study on the accuracy of mass balances for xenobiotics in full-scale wastewater treatment plants.

    Science.gov (United States)

    Majewsky, Marius; Farlin, Julien; Bayerle, Michael; Gallé, Tom

    2013-04-01

    Removal efficiencies of micropollutants in wastewater treatment plants (WWTPs) are usually evaluated from mass balance calculations using a small number of observations drawn from short sampling campaigns. Since micropollutant loads can vary greatly in both influent and effluent and reactor tanks exhibit specific hydraulic residence times, these short-term approaches are particularly prone to yield erroneous removal values. A detailed investigation of micropollutant transit times at full-scale and on how this affects mass balancing results was still lacking. The present study used hydraulic residence time distributions to scrutinize the match of influent loads to effluent loads of 10 polar micropollutants with different influent dynamics in a full-scale WWTP. Prior hydraulic modeling indicated that a load sampled over one day in the effluent is composed of influent load fractions of five preceding days. Results showed that the error of the mass balance can be reduced with increasing influent sampling duration. The approach presented leads to a more reliable estimation of the removal efficiencies of those micropollutants which can be constantly detected in influents, such as pharmaceuticals, but provides no advantage for pesticides due to their sporadic occurrence. The mismatch between sampled influent and effluent loads was identified as a major error source and an explanation was provided for the occurrence of negative mass balances regularly reported. This study indicates that the accurate determination of global removal values is only feasible in full-scale investigations with sampling durations much longer than 1 day. In any case, the uncertainty of these values needs to be reported when used in removal assessment, model selection or validation.

  14. Pharmacokinetics, tissue distribution and mass balance of radiolabeled dihydroartemisinin in male rats

    Directory of Open Access Journals (Sweden)

    Weina Peter J

    2009-05-01

    Full Text Available Abstract Background Dihydroartemisinin (DHA, a powerful anti-malarial drug, has been used as monotherapy and artemisinin-based combination therapy (ACT for more than decades. So far, however, the tissue distribution and metabolic profile of DHA data are not available from animal and humans. Methods Pharmacokinetics, tissue distribution, mass balance, and elimination of [14C] DHA have been studieded in rats following a single intravenous administration. Protein binding was performed with rat and human plasma. Drug concentrations were obtained up to 192 hr from measurements of total radioactivity and drug concentration to determine the contribution by the parent and metabolites to the total dose of drug injected from whole blood, plasma, urine and faecal samples. Results Drug was widely distributed after 1 hr and rapidly declined at 24 hr in all tissues except spleen until 96 hrs. Only 0.81% of the total radioactivity was detected in rat brain tissue. DHA revealed a high binding capacity with both rat and human plasma proteins (76–82%. The concentration of total radioactivity in the plasma fraction was less than 25% of that in blood total. Metabolism of DHA was observed with high excretion via bile into intestines and approximately 89–95% dose of all conjugations were accounted for in blood, urine and faeces. However, the majority of elimination of [14C] DHA was through urinary excretion (52% dose. The mean terminal half-lives of plasma and blood radioactivity (75.57–122.13 h were significantly prolonged compared with that of unchanged DHA (1.03 h. Conclusion In rat brain, the total concentration of [14C] was 2-fold higher than that in plasma, indicating the radioactivity could easily penetrate the brain-blood barrier. Total radioactivity distributed in RBC was about three- to four-fold higher than that in plasma, suggesting that the powerful anti-malarial potency of DHA in the treatment of blood stage malaria may relate to the high RBC

  15. A mass balance mercury budget for a mine-dominated lake: Clear Lake, California

    Science.gov (United States)

    Suchanek, T.H.; Cooke, J.; Keller, K.; Jorgensen, S.; Richerson, P.J.; Eagles-Smith, Collin A.; Harner, E.J.; Adam, D.P.

    2009-01-01

    The Sulphur Bank Mercury Mine (SBMM), active intermittently from 1873–1957 and now a USEPA Superfund site, was previously estimated to have contributed at least 100 metric tons (105 kg) of mercury (Hg) into the Clear Lake aquatic ecosystem. We have confirmed this minimum estimate. To better quantify the contribution of the mine in relation to other sources of Hg loading into Clear Lake and provide data that might help reduce that loading, we analyzed Inputs and Outputs of Hg to Clear Lake and Storage of Hg in lakebed sediments using a mass balance approach. We evaluated Inputs from (1) wet and dry atmospheric deposition from both global/regional and local sources, (2) watershed tributaries, (3) groundwater inflows, (4) lakebed springs and (5) the mine. Outputs were quantified from (1) efflux (volatilization) of Hg from the lake surface to the atmosphere, (2) municipal and agricultural water diversions, (3) losses from out-flowing drainage of Cache Creek that feeds into the California Central Valley and (4) biotic Hg removal by humans and wildlife. Storage estimates include (1) sediment burial from historic and prehistoric periods (over the past 150–3,000 years) from sediment cores to ca. 2.5m depth dated using dichloro diphenyl dichloroethane (DDD), 210Pb and 14C and (2) recent Hg deposition in surficial sediments. Surficial sediments collected in October 2003 (11 years after mine site remediation) indicate no reduction (but a possible increase) in sediment Hg concentrations over that time and suggest that remediation has not significantly reduced overall Hg loading to the lake. Currently, the mine is believed to contribute ca. 322–331 kg of Hg annually to Clear Lake, which represents ca. 86–99% of the total Hg loading to the lake. We estimate that natural sedimentation would cover the existing contaminated sediments within ca. 150–300 years.

  16. Observationally constrained surface mass balance of Larsen C ice shelf, Antarctica

    Directory of Open Access Journals (Sweden)

    P. Kuipers Munneke

    2017-11-01

    Full Text Available The surface mass balance (SMB of the Larsen C ice shelf (LCIS, Antarctica, is poorly constrained due to a dearth of in situ observations. Combining several geophysical techniques, we reconstruct spatial and temporal patterns of SMB over the LCIS. Continuous time series of snow height (2.5–6 years at five locations allow for multi-year estimates of seasonal and annual SMB over the LCIS. There is high interannual variability in SMB as well as spatial variability: in the north, SMB is 0.40 ± 0.06 to 0.41 ± 0.04 m w.e. year−1, while farther south, SMB is up to 0.50 ± 0.05 m w.e. year−1. This difference between north and south is corroborated by winter snow accumulation derived from an airborne radar survey from 2009, which showed an average snow thickness of 0.34 m w.e. north of 66° S, and 0.40 m w.e. south of 68° S. Analysis of ground-penetrating radar from several field campaigns allows for a longer-term perspective of spatial variations in SMB: a particularly strong and coherent reflection horizon below 25–44 m of water-equivalent ice and firn is observed in radargrams collected across the shelf. We propose that this horizon was formed synchronously across the ice shelf. Combining snow height observations, ground and airborne radar, and SMB output from a regional climate model yields a gridded estimate of SMB over the LCIS. It confirms that SMB increases from north to south, overprinted by a gradient of increasing SMB to the west, modulated in the west by föhn-induced sublimation. Previous observations show a strong decrease in firn air content toward the west, which we attribute to spatial patterns of melt, refreezing, and densification rather than SMB.

  17. The Mass Balance of Glacier No. 1 at the Headwaters of the Urumqi River in Relation to Northern Hemisphere Teleconnection Patterns

    Directory of Open Access Journals (Sweden)

    Feifei Yuan

    2016-03-01

    Full Text Available Most small glaciers in the world have significantly decreased their volume during the last century, which has caused water shortage problems. Glacier No. 1, at the headwaters of the Urumqi River, Tianshan, China, has been monitored since 1959 and similarly has experienced significant mass and volume losses over the last few decades. Thus, we examined the trend and potential abrupt changes of the mass balance of Glacier No. 1. Principal component analysis and singular value decomposition were used to find significant relations between the mass balance of Glacier No. 1 and Northern Hemisphere teleconnection patterns using climate indices. It was found that the mass balance of Glacier No. 1 had a significantly decreasing trend corresponding to −14.5 mm/year from 1959 to 2010. A change point was detected in 1997 with 99% confidence level. Two time periods with different mass balances were identified as 1959–1996 and 1997–2010. The mass balance for the first period was −136.4 mm/year and up to −663.9 mm/year for the second period. The mass balance of Glacier No. 1 is positively related to the Scandinavian Pattern (SCA, and negatively related to the East Atlantic Pattern (EA. These relationships are useful in better understanding the interaction between glacier mass balance and climate variability.

  18. The Mass Balance of Glacier No. 1 at the Headwaters of the Urumqi River in Relation to Northern Hemisphere Teleconnection Patterns

    Science.gov (United States)

    Yuan, Feifei; Hao, Zhenchun

    2017-04-01

    Most small glaciers in the world have significantly decreased their volume during the last century, which has caused water shortage problems. Glacier No. 1, at the headwaters of the Urumqi River, Tianshan, China, has been monitored since 1959 and similarly has experienced significant mass and volume losses over the last few decades. Thus, we examined the trend and potential abrupt changes of the mass balance of Glacier No. 1. Principal component analysis and singular value decomposition were used to find significant relations between the mass balance of Glacier No. 1 and Northern Hemisphere teleconnection patterns using climate indices. It was found that the mass balance of Glacier No. 1 had a significantly decreasing trend corresponding to -14.5 mm/year from 1959 to 2010. A change point was detected in 1997 with 99% confidence level. Two time periods with different mass balances were identified as 1959-1996 and 1997-2010. The mass balance for the first period was -136.4 mm/year and up to -663.9 mm/year for the second period. The mass balance of Glacier No. 1 is positively related to the Scandinavian Pattern (SCA), and negatively related to the East Atlantic Pattern (EA). These relationships are useful in better understanding the interaction between glacier mass balance and climate variability.

  19. Estimation of Mass Balance of the Grosser Aletschgletscher, Swiss Alps, from ICESat Laser Altimetry Data and Digital Elevation Models

    Directory of Open Access Journals (Sweden)

    Jan Kropáček

    2014-06-01

    Full Text Available Traditional glaciological mass balance measurements of mountain glaciers are a demanding and cost intensive task. In this study, we combine data from the Ice Cloud and Elevation Satellite (ICESat acquired between 2003 and 2009 with air and space borne Digital Elevation Models (DEMs in order to derive surface elevation changes of the Grosser Aletschgletscher in the Swiss Alps. Three different areas of the glacier are covered by one nominal ICESat track, allowing us to investigate the performance of the approach under different conditions in terms of ICESat data coverage, and surface characteristics. In order to test the sensitivity of the derived trend in surface lowering, several variables were tested. Employing correction for perennial snow accumulation, footprint selection and adequate reference DEM, we estimated a mean mass balance of −0.92 ± 0.18 m w.e. a−1. for the whole glacier in the studied time period. The resulting mass balance was validated by a comparison with another geodetic approach based on the subtraction of two DEMs for the years 1999 and 2009. It appears that the processing parameters need to be selected depending on the amount of available ICESat measurements, quality of the elevation reference and character of the glacier surface.

  20. Stable isotope mass balances versus concentration differences of dissolved inorganic carbon - implications for tracing carbon turnover in reservoirs.

    Science.gov (United States)

    Barth, Johannes A C; Mader, Michael; Nenning, Franziska; van Geldern, Robert; Friese, Kurt

    2017-08-01

    The aim of this study was to identify sources of carbon turnover using stable isotope mass balances. For this purpose, two pre-reservoirs in the Harz Mountains (Germany) were investigated for their dissolved and particulate carbon contents (dissolved inorganic carbon (DIC), dissolved organic carbon, particulate organic carbon) together with their stable carbon isotope ratios. DIC concentration depth profiles from March 2012 had an average of 0.33 mmol L-1. Increases in DIC concentrations later on in the year often corresponded with decreases in its carbon isotope composition (δ13CDIC) with the most negative value of -18.4 ‰ in September. This led to a carbon isotope mass balance with carbon isotope inputs of -28.5 ‰ from DOC and -23.4, -31.8 and -30.7 ‰ from algae, terrestrial and sedimentary matter, respectively. Best matches between calculated and measured DIC gains were achieved when using the isotope composition of algae. This shows that this type of organic material is most likely responsible for carbon additions to the DIC pool when its concentrations and δ13CDIC values correlate negatively. The presented isotope mass balance is transferable to other surface water and groundwater systems for quantification of organic matter turnover.

  1. Stability improvement of a four cable-driven parallel manipulator using a center of mass balance system

    Science.gov (United States)

    Salafian, Iman; Stewart, Blake; Newman, Matthew; Zygielbaum, Arthur I.; Terry, Benjamin

    2017-04-01

    A four cable-driven parallel manipulator (CDPM), consisting of sophisticated spectrometers and imagers, is under development for use in acquiring phenotypic and environmental data over an acre-sized crop field. To obtain accurate and high quality data from the instruments, the end effector must be stable during sensing. One of the factors that reduces stability is the center of mass offset of the end effector, which can cause a pendulum effect or undesired tilt angle. The purpose of this work is to develop a system and method for balancing the center of mass of a 12th-scale CDPM to minimize vibration that can cause error in the acquired data. A simple method for balancing the end effector is needed to enable end users of the CDPM to arbitrarily add and remove sensors and imagers from the end effector as their experiments may require. A Center of Mass Balancing System (CMBS) is developed in this study which consists of an adjustable system of weights and a gimbal for tilt mitigation. An electronic circuit board including an orientation sensor, wireless data communication, and load cells was designed to validate the CMBS. To measure improvements gained by the CMBS, several static and dynamic experiments are carried out. In the experiments, the dynamic vibrations due to the translational motion and static orientation were measured with and without CMBS use. The results show that the CMBS system improves the stability of the end-effector by decreasing vibration and static tilt angle.

  2. Glaciological settings and recent mass balance of Blåskimen Island in Dronning Maud Land, Antarctica

    Science.gov (United States)

    Goel, Vikram; Brown, Joel; Matsuoka, Kenichi

    2017-12-01

    The ice-shelf-fringed coast of Dronning Maud Land in East Antarctica contains numerous ice rises that influence the dynamics and mass balance of the region. However, only a few of these ice rises have been investigated in detail. Here, we present field measurements of Blåskimen Island, an isle-type ice rise adjacent to Fimbul Ice Shelf. This ice rise is largely dome shaped, with a pronounced ridge extending to the south-west from its summit (410 m a.s.l.). Its bed is mostly flat and about 100 m below the current sea level. Shallow radar-detected isochrones dated with a firn core reveal that the surface mass balance is higher on the south-eastern (upwind) slope than on the north-western (downwind) slope by ˜ 37 %, and this pattern has persisted for at least the past decade. Moreover, arches in radar stratigraphy suggest that the summit of the ice rise has been stable for ˜ 600 years. Ensemble estimates of the mass balance using the input-output method show that this ice rise has thickened by 0.12-0.37 m ice equivalent per year over the past decade.

  3. The mass balance calculation of hydrothermal alteration in Sarcheshmeh porphyry copper deposit

    Directory of Open Access Journals (Sweden)

    Mohammad Maanijou

    2013-10-01

    Full Text Available Sarcheshmeh porphyry copper deposit is located 65 km southwest of Rafsanjan in Kerman province. The Sarcheshmeh deposit belongs to the southeastern part of Urumieh-Dokhtar magmatic assemblage (i.e., Dehaj-Sarduyeh zone. Intrusion of Sarcheshmeh granodiorite stock in faulted and thrusted early-Tertiary volcano-sedimentary deposits, led to mineralization in Miocene. In this research, the mass changes and element mobilities during hydrothermal process of potassic alteration were studied relative to fresh rock from the deeper parts of the plutonic body, phyllic relative to potassic, argillic relative to phyllic and propylitic alteration relative to fresh andesites surrounding the deposit. In the potassic zone, enrichment in Fe2O3 and K2O is so clear, because of increasing Fe coming from biotite alteration and presence of K-feldspar, respectively. Copper and molybdenum enrichments resulted from presence of chalcopyrite, bornite and molybdenite mineralization in this zone. Enrichment of SiO2 and depletion of CaO, MgO, Na2O and K2O in the phyllic zone resulted from leaching of sodium, calcium and magnesium from the aluminosilicate rocks and alteration of K-feldspar to sericite and quartz. In the argillic zone, Al2O3, CaO, MgO, Na2O and MnO have also been enriched in which increasing Al2O3 may be from kaolinite and illite formation. Also, enrichment in SiO2, Al2O3 and CaO in propylitic alteration zone can be attributed to the formation of chlorite, epidote and calcite as indicative minerals of this zone.

  4. Photon mass energy transfer coefficients for elements z=1 to 92 and 48 additional substances of dosimetric interest.

    Science.gov (United States)

    Kato, Hideki

    2014-07-01

    Photon mass energy transfer coefficient is an essential factor when converting photon energy fluence into kinetic energy released per unit mass (kerma). Although mass attenuation coefficient and mass energy absorption coefficients can be looked up in databases, the mass energy transfer coefficient values are still controversial. In this paper, the photon mass energy transfer coefficients for elements Z=1-92 were calculated based on cross-sectional data for each photon interaction type. Mass energy transfer coefficients for 48 compounds and/or mixtures of dosimetric interest were calculated from coefficient data for elements using Bragg's additivity rule. We additionally developed software that can search these coefficient data for any element or substance of dosimetric interest. The database and software created in this paper should prove useful for radiation measurements and/or dose calculations.

  5. Striking a balance: regulation of transposable elements by Zfp281 and Mll2 in mouse embryonic stem cells.

    Science.gov (United States)

    Dai, Qian; Shen, Yang; Wang, Yan; Wang, Xin; Francisco, Joel Celio; Luo, Zhuojuan; Lin, Chengqi

    2017-12-01

    Transposable elements (TEs) compose about 40% of the murine genome. Retrotransposition of active TEs such as LINE-1 (L1) tremendously impacts genetic diversification and genome stability. Therefore, transcription and transposition activities of retrotransposons are tightly controlled. Here, we show that the Krüppel-like zinc finger protein Zfp281 directly binds and suppresses a subset of retrotransposons, including the active young L1 repeat elements, in mouse embryonic stem (ES) cells. In addition, we find that Zfp281-regulated L1s are highly enriched for 5-hydroxymethylcytosine (5hmC) and H3K4me3. The COMPASS-like H3K4 methyltransferase Mll2 is the major H3K4me3 methylase at the Zfp281-regulated L1s and required for their proper expression. Our studies also reveal that Zfp281 functions partially through recruiting the L1 regulators DNA hydroxymethylase Tet1 and Sin3A, and restricting Mll2 at these active L1s, leading to their balanced expression. In summary, our data indicate an instrumental role of Zfp281 in suppressing the young active L1s in mouse ES cells. © The Author(s) 2017. Published by Oxford University Press on behalf of Nucleic Acids Research.

  6. Chloride mass balance to quantify the wastewater impact on karstified carbonate aquifers

    Science.gov (United States)

    Schmidt, S.; Nuseibeh, M.; Geyer, T.; Abdelghafour, D.; Al-Naji, G.; Bsharat, J.; Sawalhi, B.; Guttman, J.; Sauter, M.

    2012-04-01

    Groundwater resources are vulnerable to anthropogenic influences, like i.e. wastewater disposal in the environment. This is especially critical in karstified carbonate aquifers, because of the partially high flow velocities, resulting in an insufficient attenuation potential against pollutants. To assess the health risk associated with the pollution of the groundwater and for remediation measures planning, the wastewater impact on groundwater resources needs to be quantified. For this purpose the analysis of conservative tracer substances, abundant in the wastewater, is considered a suitable technique. Among the substances considered as tracers, chloride exhibits superior characteristics, the only drawback being the usually high natural background concentration in groundwater. As the chloride ion is not removed by common wastewater treatment processes, it is indicative of both treated and untreated wastewater. In this study, an example for a semi-arid karstified carbonate aquifer system is presented. The study area is located on the western margin of the Lower Jordan Valley (West Bank). The upper aquifer is discharged via several springs. For the springs in the study area, time series of chloride concentration in spring water from 1967-98 were interpreted. The study area displays a high population growth, which results in a steadily increasing wastewater discharge amount. The wastewater is mostly infiltrating into the karst system. First, the long-term average groundwater recharge rate of the local aquifers that fed the springs was quantified with the chloride mass balance method from groundwater data that are little influenced by anthropogenic impacts. The chloride concentration in the local precipitation is 9-10 mg/l and the average value in groundwater is 31 mg/l. This yields a mean recharge rate of around 30 percent. Second, the fraction of groundwater recharge, resulting from the infiltration of wastewater from leaky sewer systems and from wastewater disposal

  7. Determination of elemental composition of metals using ambient organic mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Shiea, Christopher [Department of Medical Laboratory Science and Biotechnology, Kaohsiung Medical University, 100 Shih-Chuan 1st Rd, Kaohsiung 807, Taiwan (China); Huang, Yeou-Lih [Department of Medical Laboratory Science and Biotechnology, Kaohsiung Medical University, 100 Shih-Chuan 1st Rd, Kaohsiung 807, Taiwan (China); Department of Chemistry, National Sun Yat-Sen University, 70 Lien-Hai Rd, Kaohsiung 804, Taiwan (China); Cheng, Sy-Chyi; Chen, Yi-Lun [Department of Chemistry, National Sun Yat-Sen University, 70 Lien-Hai Rd, Kaohsiung 804, Taiwan (China); Shiea, Jentaie, E-mail: jetea@mail.nsysu.edu.tw [Department of Chemistry, National Sun Yat-Sen University, 70 Lien-Hai Rd, Kaohsiung 804, Taiwan (China); Department of Medicinal and Applied Chemistry, Kaohsiung Medical University, 100 Shih-Chuan 1st Rd, Kaohsiung 807, Taiwan (China)

    2017-05-22

    Conventional inorganic mass spectrometric (MS) analysis of metals can require time-consuming and tedious sample preparation. We thus report the novel and direct characterization of metals in solid samples using an organic MS technique known as electrospray laser desorption ionization mass spectrometry (ELDI/MS). No sample pretreatment was needed, and results were rapidly obtained due to the ambient and laser-based nature of ELDI/MS. Metals from samples were desorbed and ionized by laser irradiation, after which they reacted with EDTA and then post-ionized and detected as metal-EDTA complexes. Aluminum, copper, iron, lead, nickel, and zinc from plates, foils, and coins were characterized in seconds. This study demonstrates that an ESI/MS system can be easily modified to analyze metal elements in solids by involving a chelating agent, indicating a potentially promising development in MS towards the analysis of metals using organic MS. - Highlights: • “Organic MS” was utilized as “inorganic MS” to detect metal ions in solid samples. • Element ions desorbed by laser irradiation rapidly reacted with a chelating reagent before they were detected by MS. • Elemental composition of metals was determined by this “Organic MS” method.

  8. Seasonal changes in surface albedo of Himalayan glaciers from MODIS data and links with the annual mass balance

    Directory of Open Access Journals (Sweden)

    F. Brun

    2015-02-01

    Full Text Available Few glaciological field data are available on glaciers in the Hindu Kush–Karakoram–Himalayan (HKH region, and remote sensing data are thus critical for glacier studies in this region. The main objectives of this study are to document, using satellite images, the seasonal changes of surface albedo for two Himalayan glaciers, Chhota Shigri Glacier (Himachal Pradesh, India and Mera Glacier (Everest region, Nepal, and to reconstruct the annual mass balance of these glaciers based on the albedo data. Albedo is retrieved from Moderate Resolution Imaging Spectroradiometer (MODIS images, and evaluated using ground based measurements. At both sites, we find high coefficients of determination between annual minimum albedo averaged over the glacier (AMAAG and glacier-wide annual mass balance (Ba measured with the glaciological method (R2 = 0.75. At Chhota Shigri Glacier, the relation between AMAAG found at the end of the ablation season and Ba suggests that AMAAG can be used as a proxy for the maximum snow line altitude or equilibrium line altitude (ELA on winter-accumulation-type glaciers in the Himalayas. However, for the summer-accumulation-type Mera Glacier, our approach relied on the hypothesis that ELA information is preserved during the monsoon. At Mera Glacier, cloud obscuration and snow accumulation limits the detection of albedo during the monsoon, but snow redistribution and sublimation in the post-monsoon period allows for the calculation of AMAAG. Reconstructed Ba at Chhota Shigri Glacier agrees with mass balances previously reconstructed using a positive degree-day method. Reconstructed Ba at Mera Glacier is affected by heavy cloud cover during the monsoon, which systematically limited our ability to observe AMAAG at the end of the melting period. In addition, the relation between AMAAG and Ba is constrained over a shorter time period for Mera Glacier (6 years than for Chhota Shigri Glacier (11 years. Thus the mass balance reconstruction

  9. High-resolution modeling of coastal freshwater discharge and glacier mass balance in the Gulf of Alaska watershed

    Science.gov (United States)

    Beamer, J. P.; Hill, D. F.; Arendt, A.; Liston, G. E.

    2016-05-01

    A comprehensive study of the Gulf of Alaska (GOA) drainage basin was carried out to improve understanding of the coastal freshwater discharge (FWD) and glacier volume loss (GVL). Hydrologic processes during the period 1980-2014 were modeled using a suite of physically based, spatially distributed weather, energy-balance snow/ice melt, soil water balance, and runoff routing models at a high-resolution (1 km horizontal grid; daily time step). Meteorological forcing was provided by the North American Regional Reanalysis (NARR), Modern Era Retrospective Analysis for Research and Applications (MERRA), and Climate Forecast System Reanalysis (CFSR) data sets. Streamflow and glacier mass balance modeled using MERRA and CFSR compared well with observations in four watersheds used for calibration in the study domain. However, only CFSR produced regional seasonal and long-term trends in water balance that compared favorably with independent Gravity Recovery and Climate Experiment (GRACE) and airborne altimetry data. Mean annual runoff using CFSR was 760 km3 yr-1, 8% of which was derived from the long-term removal of stored water from glaciers (glacier volume loss). The annual runoff from CFSR was partitioned into 63% snowmelt, 17% glacier ice melt, and 20% rainfall. Glacier runoff, taken as the sum of rainfall, snow, and ice melt occurring each season on glacier surfaces, was 38% of the total seasonal runoff, with the remaining runoff sourced from nonglacier surfaces. Our simulations suggests that existing GRACE solutions, previously reported to represent glacier mass balance alone, are actually measuring the full water budget of land and ice surfaces.

  10. Measurement of the top quark mass in the dilepton final state using the matrix element method

    Energy Technology Data Exchange (ETDEWEB)

    Grohsjean, Alexander [Ludwig Maximilian Univ., Munich (Germany)

    2008-12-15

    The top quark, discovered in 1995 by the CDF and D0 experiments at the Fermilab Tevatron Collider, is the heaviest known fundamental particle. The precise knowledge of its mass yields important constraints on the mass of the yet-unobserved Higgs boson and allows to probe for physics beyond the Standard Model. The first measurement of the top quark mass in the dilepton channel with the Matrix Element method at the D0 experiment is presented. After a short description of the experimental environment and the reconstruction chain from hits in the detector to physical objects, a detailed review of the Matrix Element method is given. The Matrix Element method is based on the likelihood to observe a given event under the assumption of the quantity to be measured, e.g. the mass of the top quark. The method has undergone significant modifications and improvements compared to previous measurements in the lepton+jets channel: the two undetected neutrinos require a new reconstruction scheme for the four-momenta of the final state particles, the small event sample demands the modeling of additional jets in the signal likelihood, and a new likelihood is designed to account for the main source of background containing tauonic Z decay. The Matrix Element method is validated on Monte Carlo simulated events at the generator level. For the measurement, calibration curves are derived from events that are run through the full D0 detector simulation. The analysis makes use of the Run II data set recorded between April 2002 and May 2008 corresponding to an integrated luminosity of 2.8 fb-1. A total of 107 t$\\bar{t}$ candidate events with one electron and one muon in the final state are selected. Applying the Matrix Element method to this data set, the top quark mass is measured to be mtopRun IIa = 170.6 ± 6.1(stat.)-1.5+2.1(syst.)GeV; mtopRun IIb = 174.1 ± 4.4(stat.)-1.8+2.5(syst.)GeV; m

  11. Life cycle inventory and mass-balance of municipal food waste management systems: Decision support methods beyond the waste hierarchy.

    Science.gov (United States)

    Edwards, Joel; Othman, Maazuza; Crossin, Enda; Burn, Stewart

    2017-11-01

    When assessing the environmental and human health impact of a municipal food waste (FW) management system waste managers typically rely on the principles of the waste hierarchy; using metrics such as the mass or rate of waste that is 'prepared for recycling,' 'recovered for energy,' or 'sent to landfill.' These metrics measure the collection and sorting efficiency of a waste system but are incapable of determining the efficiency of a system to turn waste into a valuable resource. In this study a life cycle approach was employed using a system boundary that includes the entire waste service provision from collection to safe end-use or disposal. A life cycle inventory of seven waste management systems was calculated, including the first service wide inventory of FW management through kitchen in-sink disposal (food waste disposer). Results describe the mass, energy and water balance of each system along with key emissions profile. It was demonstrated that the energy balance can differ significantly from its' energy generation, exemplified by mechanical biological treatment, which was the best system for generating energy from waste but only 5 th best for net-energy generation. Furthermore, the energy balance of kitchen in-sink disposal was shown to be reduced because 31% of volatile solids were lost in pre-treatment. The study also confirmed that higher FW landfill diversion rates were critical for reducing many harmful emissions to air and water. Although, mass-balance analysis showed that the alternative end-use of the FW material may still contain high impact pollutants. Crown Copyright © 2017. Published by Elsevier Ltd. All rights reserved.

  12. Determination of toxic and essential elements in children's blood with inductively coupled plasma-mass spectrometry.

    Science.gov (United States)

    Bazzi, Ali; Nriagu, Jerome O; Linder, Aaron M

    2008-10-01

    Recent studies have suggested that low blood lead level, less than 50 microg L(-1), can influence the neurobehavioral performance of children. In addition, nutritional deficiencies in some essential elements may increase the toxicity of lead, and some essential elements may influence the blood concentrations of lead and other toxic metals. These findings, coupled with the scarcity of available data on some elements in children's blood and the introduction of methylcyclopentadienyl manganese tricarbonyl (MMT) to gasoline, accentuate the need to monitor the concentrations of lead, manganese, and other heavy metals and essential elements in children's blood. This study reports on the multi-element analysis of blood of South African school children using inductively coupled plasma-mass spectrometry (ICP-MS). The sample preparation consisted of a nitric acid/hydrogen peroxide open digestion and subsequent dilution with MilliQ water. The accuracy and precision were evaluated from quintuplet analyses of Seronorm trace elements whole blood reference material and human blood samples. Concentrations of lead, arsenic, manganese, copper, zinc, selenium, cobalt, and chromium in the blood of South African school children were determined. The average values were: lead 56.4 microg L(-1), arsenic 1.53 microg L(-1), manganese 8.48 microg L(-1), copper 1195 microg L(-1), zinc 3431 microg L(-1), selenium 176 microg L(-1), cobalt 0.80 microg L(-1), and chromium 1.25 microg L(-1). The level of lead was in line with some reported lower concentrations. The concentrations of arsenic and manganese were generally lower than those found in the literature. The concentrations of cobalt, copper, selenium, and chromium were higher than those found in other studies, whereas that of zinc was lower.

  13. Comparing effects of gridded input data from different sources in glacier mass balance modelling using a minimal glacier model

    Science.gov (United States)

    Schröer, Katharina; Marzeion, Ben

    2014-05-01

    The knowledge of the development of glaciers in both past and future is valuable for understanding our climate system. The vast majority of the world's glaciers is poorly observed and often no data or resources are available to study them. Minimal modelling approaches requiring a minimal amount of easily available input data can be a valuable first step to gain valuable information at low cost. This study is concerned with the effects of the spatial and temporal resolution of gridded input data on the applicability of a minimal surface mass balance model. Three sources of temperature and precipitation data freely available for the Alpine region were used to drive a statistical multiple linear regression surface mass balance model (HISTALP 'grid mode 2' instrumental database, monthly, 5' spatial resolution (Auer et al., 2007); CRU TS 3.10.01 instrumental database, monthly, 0.5° spatial resolution (Harris et al., 2013); European temperature and precipitation reconstructions 1500-2000, seasonal, 0.5° spatial resolution (Luterbacher et al., 2004; Pauling et al., 2006)). The model is trained, tested and cross-validated to test the model's robustness using the different datasets. The surface mass balance model is coupled to a simple volume-area and volume-length scaling scheme to roughly include surface mass balance and glacier geometry feedbacks. Observed mass balance data of Hintereisferner in the Ötztal Alps (Austria) allow for a sound validation of the model. The findings of the study reveal that there is only a weak dependency of the reliability of the multiple linear regression model on the spatial resolution of the input data sets. The anomalies of the regional HISTALP 5' grid mode 2 data series were not found to lead to better model results than the anomalies of the 0.5° global CRU TS 3.10.01 data set. An artificial deterioration of the input data quality by aggregating the 5' data grid to 10' and 0.5° of spatial resolution did even lead to slightly enhanced

  14. A method for correcting the structural instability of time-dependent atmospheric trajectory models under perturbations of the mass balance

    Science.gov (United States)

    Núñez, M. A.; Mendoza, R.

    2017-01-01

    Lagrangian trajectory models of atmospheric fluid parcels have been used over a wide range of spatial scales to study the transport and dispersion of pollutants, radioactive materials, ash clouds produced by volcanic eruptions or modeling global carbon cycle. It was pointed out trajectory calculations have three error sources: error in the gridded data from measurements error or from approximations in Eulerian numerical models, error from the spatial and temporal resolution of data, and truncation error from numerical integration of the velocity field. In a recent work we showed that trajectory models can be structurally unstable under perturbations of the mass balance, e.g., the flow can go from hyperbolic to elliptic and vice versa. In this work we propose a mass-consistent approach to correct this structural instability. The orthogonal projection character of this approach guarantees the correction even for large perturbations of the mass-balance. This is illustrated by means of numerical examples. Mass-consistent models have been considered as diagnostic models of the wind field but the results of this work show that such a models can be used for four-dimensional data assimilation of nonstationary flows.

  15. A Preliminary Model for Spacecraft Propulsion Performance Analysis Based on Nuclear Gain and Subsystem Mass-Power Balances

    Science.gov (United States)

    Chakrabarti, Suman; Schmidt, George R.; Thio, Y. C.; Hurst, Chantelle M.

    1999-01-01

    A preliminary model for spacecraft propulsion performance analysis based on nuclear gain and subsystem mass-power balances are presented in viewgraph form. For very fast missions with straight-line trajectories, it has been shown that mission trip time is proportional to the cube root of alpha. Analysis of spacecraft power systems via a power balance and examination of gain vs. mass-power ratio has shown: 1) A minimum gain is needed to have enough power for thruster and driver operation; and 2) Increases in gain result in decreases in overall mass-power ratio, which in turn leads to greater achievable accelerations. However, subsystem mass-power ratios and efficiencies are crucial: less efficient values for these can partially offset the effect of nuclear gain. Therefore, it is of interest to monitor the progress of gain-limited subsystem technologies and it is also possible that power-limited systems with sufficiently low alpha may be competitive for such ambitious missions. Topics include Space flight requirements; Spacecraft energy gain; Control theory for performance; Mission assumptions; Round trips: Time and distance; Trip times; Vehicle acceleration; and Minimizing trip times.

  16. Laser ablation-miniature mass spectrometer for elemental and isotopic analysis of rocks.

    Science.gov (United States)

    Sinha, M P; Neidholdt, E L; Hurowitz, J; Sturhahn, W; Beard, B; Hecht, M H

    2011-09-01

    A laser ablation-miniature mass spectrometer (LA-MMS) for the chemical and isotopic measurement of rocks and minerals is described. In the LA-MMS method, neutral atoms ablated by a pulsed laser are led into an electron impact ionization source, where they are ionized by a 70 eV electron beam. This results in a secondary ion pulse typically 10-100 μs wide, compared to the original 5-10 ns laser pulse duration. Ions of different masses are then spatially dispersed along the focal plane of the magnetic sector of the miniature mass spectrometer (MMS) and measured in parallel by a modified CCD array detector capable of detecting ions directly. Compared to conventional scanning techniques, simultaneous measurement of the ion pulse along the focal plane effectively offers a 100% duty cycle over a wide mass range. LA-MMS offers a more quantitative assessment of elemental composition than techniques that detect ions directly generated by the ablation process because the latter can be strongly influenced by matrix effects that vary with the structure and geometry of the surface, the wavelength of the laser beam, and the not well characterized ionization efficiencies of the elements in the process. The above problems attendant to the direct ion analysis has been minimized in the LA-MMS by analyzing the ablated neutral species after their post-ionization by electron impaction. These neutral species are much more abundant than the directly ablated ions in the ablated vapor plume and are, therefore, expected to be characteristic of the chemical composition of the solid. Also, the electron impact ionization of elements is well studied and their ionization cross sections are known and easy to find in databases. Currently, the LA-MMS limit of detection is 0.4 wt.%. Here we describe LA-MMS elemental composition measurements of various minerals including microcline, lepidolite, anorthoclase, and USGS BCR-2G samples. The measurements of high precision isotopic ratios including (41)K

  17. Long-lived heavy mass elements half-lives (A > 125)

    Energy Technology Data Exchange (ETDEWEB)

    Holden, N.E.

    1985-01-01

    Reported values of half-lives of intermediate mass and heavy elements are evaluated. The evaluation analysis estimates the systematic error the resulting standard deviation. Recommended values are then presented for /sup 128/Te, /sup 130/Te, /sup 129/I, /sup 138/La, /sup 144/Nd, /sup 145/Nd, /sup 146,147,148/Sm, /sup 152/Gd, /sup 154/Dy, /sup 176/Lu, /sup 174/Hf, /sup 180/Ta, /sup 187/Re, /sup 186/Os, /sup 190/Pt, /sup 204,205/Pb, and /sup 230,232/Th. 103 refs., 21 tabs. (WRF)

  18. Mass balance of the Greenland ice sheet (2003-2008) from ICESat data - the impact of interpolation, sampling and firn density

    DEFF Research Database (Denmark)

    Sørensen, L. S.; Simonsen, Sebastian Bjerregaard; Nielsen, K.

    2011-01-01

    ICESat has provided surface elevation measurements of the ice sheets since the launch in January 2003, resulting in a unique dataset for monitoring the changes of the cryosphere. Here, we present a novel method for determining the mass balance of the Greenland ice sheet, derived from ICESat...... of the Greenland ice sheet mass balance, based on different remote-sensing techniques....... altimetry data. Three different methods for deriving elevation changes from the ICESat altimetry dataset are used. This multi-method approach provides a method to assess the complexity of deriving elevation changes from this dataset. The altimetry alone can not provide an estimate of the mass balance...

  19. Estimation of groundwater recharge using the chloride mass-balance method, Pingtung Plain, Taiwan

    Science.gov (United States)

    Ting, Cheh-Shyh; Kerh, Tienfuan; Liao, Chiu-Jung

    Due to rapid economic growth in the Pingtung Plain of Taiwan, the use of groundwater resources has changed dramatically. Over-pumping of the groundwater reservoir, which lowers hydraulic heads in the aquifers, is not only affecting the coastal area negatively but has serious consequences for agriculture throughout the plain. In order to determine the safe yield of the aquifer underlying the plain, a reliable estimate of groundwater recharge is desirable. In the present study, for the first time, the chloride mass-balance method is adopted to estimate groundwater recharge in the plain. Four sites in the central part were chosen to facilitate the estimations using the ion-chromatograph and Thiessen polygon-weighting methods. Based on the measured and calculated results, in all sites, including the mountain and river boundaries, recharge to the groundwater is probably 15% of the annual rainfall, excluding recharge from additional irrigation water. This information can improve the accuracy of future groundwater-simulation and management models in the plain. Résumé Du fait de la croissance économique rapide de la plaine de Pingtung à Taiwan, l'utilisation des ressources en eau souterraine s'est considérablement modifié. La surexploitation des aquifères, qui a abaissé le niveau des nappes, n'affecte pas seulement la région côtière, mais a de sérieuses répercutions sur l'agriculture dans toute la plaine. Afin de déterminer les ressources renouvelables de l'aquifère sous la plaine, une estimation précise de la recharge de la nappe est nécessaire. Dans cette étude, le taux de recharge de la nappe a d'abord été estimé au moyen d'un bilan de matière de chlorure. Quatre sites de la partie centrale ont été sélectionnés pour réaliser ces estimations, à l'aide d'un chromatographe ionique et de la méthode des polygones de Thiessen. A partir des résultats mesurés et calculés, à chaque site, et en prenant comme limites les montagnes et les rivi

  20. Reconnaissance Estimates of Recharge Based on an Elevation-dependent Chloride Mass-balance Approach

    Energy Technology Data Exchange (ETDEWEB)

    Charles E. Russell; Tim Minor

    2002-08-31

    Significant uncertainty is associated with efforts to quantity recharge in arid regions such as southern Nevada. However, accurate estimates of groundwater recharge are necessary to understanding the long-term sustainability of groundwater resources and predictions of groundwater flow rates and directions. Currently, the most widely accepted method for estimating recharge in southern Nevada is the Maxey and Eakin method. This method has been applied to most basins within Nevada and has been independently verified as a reconnaissance-level estimate of recharge through several studies. Recharge estimates derived from the Maxey and Eakin and other recharge methodologies ultimately based upon measures or estimates of groundwater discharge (outflow methods) should be augmented by a tracer-based aquifer-response method. The objective of this study was to improve an existing aquifer-response method that was based on the chloride mass-balance approach. Improvements were designed to incorporate spatial variability within recharge areas (rather than recharge as a lumped parameter), develop a more defendable lower limit of recharge, and differentiate local recharge from recharge emanating as interbasin flux. Seventeen springs, located in the Sheep Range, Spring Mountains, and on the Nevada Test Site were sampled during the course of this study and their discharge was measured. The chloride and bromide concentrations of the springs were determined. Discharge and chloride concentrations from these springs were compared to estimates provided by previously published reports. A literature search yielded previously published estimates of chloride flux to the land surface. {sup 36}Cl/Cl ratios and discharge rates of the three largest springs in the Amargosa Springs discharge area were compiled from various sources. This information was utilized to determine an effective chloride concentration for recharging precipitation and its associated uncertainty via Monte Carlo simulations

  1. Development of a Compact Resonance Ionization Mass Spectrometer for Trace Element Analysis of Potassium

    CERN Document Server

    Iwata, Yoshihiro; Minowa, Makoto

    2010-01-01

    A compact resonance ionization mass spectrometer is developed using two laser diodes and a quadrupole mass spectrometer to perform trace element analysis of potassium. With the help of a narrow linewidth of the laser diode, the isotope shifts of $^{40}{\\rm K}$ and $^{41}{\\rm K}$ of the 405~nm line with respect to $^{39}{\\rm K}$, corresponding to the transition of $4\\,^2$S$_{1/2}\\rightarrow$ $5\\,^2$P$^\\circ_{1/2}$, are measured to be $207\\pm13$~MHz and $451\\pm10$~MHz, respectively, by comparing them to the known hyperfine splitting widths of the $4\\,^2{\\rm S}_{1/2}$ ground state of each potassium isotope. The overall detection efficiency of an order of $\\sim10^{-6}$ in our setup indicates the availability of RIMS to the analysis of the trace metal impurities on or in a certain material such as the contamination assessment of semiconductor wafers.

  2. Mass Balance Evolution of Black Rapids Glacier, Alaska, 1980–2100, and Its Implications for Surge Recurrence

    Directory of Open Access Journals (Sweden)

    Christian Kienholz

    2017-07-01

    Full Text Available Surge-type Black Rapids Glacier, Alaska, has undergone strong retreat since it last surged in 1936–1937. To assess its evolution during the late Twentieth and Twenty-first centuries and determine potential implications for surge likelihood, we run a simplified glacier model over the periods 1980–2015 (hindcasting and 2015–2100 (forecasting. The model is forced by daily temperature and precipitation fields, with downscaled reanalysis data used for the hindcasting. A constant climate scenario and an RCP 8.5 scenario based on the GFDL-CM3 climate model are employed for the forecasting. Debris evolution is accounted for by a debris layer time series derived from satellite imagery (hindcasting and a parametrized debris evolution model (forecasting. A retreat model accounts for the evolution of the glacier geometry. Model calibration, validation and parametrization rely on an extensive set of in situ and remotely sensed observations. To explore uncertainties in our projections, we run the glacier model in a Monte Carlo fashion, varying key model parameters and input data within plausible ranges. Our results for the hindcasting period indicate a negative mass balance trend, caused by atmospheric warming in the summer, precipitation decrease in the winter and surface elevation lowering (climate-elevation feedback, which exceed the moderating effects from increasing debris cover and glacier retreat. Without the 2002 rockslide deposits on Black Rapids' lower reaches, the mass balances would be more negative, by ~20% between the 2003 and 2015 mass-balance years. Despite its retreat, Black Rapids Glacier is substantially out of balance with the current climate. By 2100, ~8% of Black Rapids' 1980 area are projected to vanish under the constant climate scenario and ~73% under the RCP 8.5 scenario. For both scenarios, the remaining glacier portions are out of balance, suggesting continued retreat after 2100. Due to mass starvation, a surge in the Twenty

  3. Mass balance evolution of Black Rapids Glacier, Alaska, 1980-2100, and its implications for surge recurrence

    Science.gov (United States)

    Kienholz, Christian; Hock, Regine; Truffer, Martin; Bieniek, Peter; Lader, Richard

    2017-07-01

    Surge-type Black Rapids Glacier, Alaska, has undergone strong retreat since it last surged in 1936-37. To assess its evolution during the late 20th and 21st centuries and determine potential implications for surge likelihood, we run a simplified glacier model over the periods 1980-2015 (hindcasting) and 2015-2100 (forecasting). The model is forced by daily temperature and precipitation fields, with downscaled reanalysis data used for the hindcasting. A constant climate scenario and an RCP 8.5 scenario based on the GFDL-CM3 climate model are employed for the forecasting. Debris evolution is accounted for by a debris layer time series derived from satellite imagery (hindcasting) and a parametrized debris evolution model (forecasting). A retreat model accounts for the evolution of the glacier geometry. Model calibration, validation and parametrization rely on an extensive set of in situ and remotely sensed observations. To explore uncertainties in our projections, we run the glacier model in a Monte Carlo fashion, varying key model parameters and input data within plausible ranges. Our results for the hindcasting period indicate a negative mass balance trend, caused by atmospheric warming in the summer, precipitation decrease in the winter and surface elevation lowering (climate-elevation feedback), which exceed the moderating effects from increasing debris cover and glacier retreat. Without the 2002 rockslide deposits on Black Rapids' lower reaches, the mass balances would be more negative, by 20% between the 2003 and 2015 mass-balance years. Despite its retreat, Black Rapids Glacier is substantially out of balance with the current climate. By 2100, 8% of Black Rapids' 1980 area are projected to vanish under the constant climate scenario and 73% under the RCP 8.5 scenario. For both scenarios, the remaining glacier portions are out of balance, suggesting continued retreat after 2100. Due to mass starvation, a surge in the 21st century is unlikely. The projected

  4. Climate change threatens archaeologically significant ice patches: insights into their age, internal structure, mass balance and climate sensitivity

    Science.gov (United States)

    Strand Ødegård, Rune; Nesje, Atle; Isaksen, Ketil; Andreassen, Liss Marie; Eiken, Trond; Schwikowski, Margit; Uglietti, Chiara

    2017-04-01

    Despite numerous spectacular archaeological discoveries worldwide related to melting ice patches and the emerging field of glacial archaeology, governing processes related to ice patch development during the Holocene and their sensitivity to climate change are still largely unexplored. Here we present new results from an extensive 6-year (2009-2015) field experiment at the Juvfonne ice patch in Jotunheimen in central southern Norway. Our results show that the ice patch has existed continuously since the late Mesolithic period. Organic-rich layers and carbonaceous aerosols embedded in clear ice show ages spanning from modern at the surface to ca. 7600 cal years BP at the bottom. This is the oldest dating of ice in mainland Norway. The expanding ice patch covered moss mats appearing along the margin of Juvfonne about 2000 years ago. During the study period, the mass balance record showed a strong negative balance, and the annual balance is highly asymmetric over short distances. Snow accumulation is poorly correlated with estimated winter precipitation, and single storm events may contribute significantly to the total winter balance. Snow accumulation is approx. 20% higher in the frontal area compared to the upper central part of the ice patch. There is sufficient meltwater to bring the permeable snowpack to an isothermal state within a few weeks in early summer. Below the seasonal snowpack, ice temperatures are between -2 and -4 °C. Juvfonne has clear ice stratification of isochronic origin. Reference: The Cryosphere, 11, 17-32, 2017.

  5. The Mythic Element of Mass Media and Its Relation to Plato’s Cave

    Directory of Open Access Journals (Sweden)

    Geoff Berry

    2010-04-01

    Full Text Available This paper compares some influential critiques of mass media and the mythic element they diagnose within it. Each theory is compared to the myth of the cave, described by Plato in his Republic, which suggests that whatever the format of our sociocultural communications systems, they falsely maintain a paradigm we assume equates with some kind of abiding truth or reality. This relatively ‘illusory’ quality must be qualified, however, by the transformative power and potential of mass media both as a paradigm and as a vehicle of cultural change. This tension is discussed in regards to Marshall McLuhan’s thesis that The Medium is the Message, the Frankfurt School analysis performed by Theodor Adorno and Max Horkheimer in the ‘Culture Industry’ chapter of their Dialectic of Enlightenment, and in Karl Marx’s theory of the commodity fetish as revised by Jean Baudrillard (in For a Critique of the Political Economy of the Sign and Slavoj Žižek (in The Sublime Object of Ideology. Close readings of these influential critical analyses of the cultural and symbolic elements in the proliferation of mass media and communications industries today reveal an age-old tension between ignorance and knowledge, illusion and truth that is far from settled. My conclusion considers the degree of agency we, as consumers of mass media in the early twenty-first century, might enjoy in terms of its dominant message. It assumes that a Marxist critique of the media and communications industries remains relevant in the twenty-first century.

  6. Muscle Strength Rather Than Muscle Mass Is Associated With Standing Balance in Elderly Outpatients

    NARCIS (Netherlands)

    Bijlsma, A.Y.; Pasma, J.H.; Lambers, D.; Stijntjes, M.; Blauw, G. J.; Meskers, C.G.M.; Maier, A.B.

    2013-01-01

    Objectives: Assessment of the association of muscle characteristics with standing balance is of special interest, as muscles are a target for potential intervention (ie, by strength training). Design: Cross-sectional study. Setting: Geriatric outpatient clinic. Participants: The study included 197

  7. A measurement of the top quark mass with a matrix element method

    Energy Technology Data Exchange (ETDEWEB)

    Gibson, Adam Paul [Univ. of California, Berkeley, CA (United States)

    2006-01-01

    The authors present a measurement of the mass of the top quark. The event sample is selected from proton-antiproton collisions, at 1.96 TeV center-of-mass energy, observed with the CDF detector at Fermilab's Tevatron. They consider a 318 pb-1 dataset collected between March 2002 and August 2004. They select events that contain one energetic lepton, large missing transverse energy, exactly four energetic jets, and at least one displaced vertex b tag. The analysis uses leading-order t$\\bar{t}$ and background matrix elements along with parameterized parton showering to construct event-by-event likelihoods as a function of top quark mass. From the 63 events observed with the 318 pb-1 dataset they extract a top quark mass of 172.0 ± 2.6(stat) ± 3.3(syst) GeV/c2 from the joint likelihood. The mean expected statistical uncertainty is 3.2 GeV/c2 for m $\\bar{t}$ = 178 GTeV/c2 and 3.1 GeV/c2 for m $\\bar{t}$ = 172.5 GeV/c2. The systematic error is dominated by the uncertainty of the jet energy scale.

  8. Sea level changes from monthly solutions of ice sheet mass balance

    DEFF Research Database (Denmark)

    Barletta, Valentina Roberta; Sørensen, Louise Sandberg; Forsberg, René

    also compare our GRACE derived regional estimates with independent mass change results based on altimetry data from NASA’s Ice Cloud and land Elevation Satellite. From the estimated Greenland and Antarctica mass changes we compute the gravitationally self-consistent sea-level changes and its associated......We present mass change time series at basin scale for both Greenland and Antarctica, de-rived from GRACE data, and use these data to find the associated global sea level changes. We use two independent methods for GRACE ice mass loss estimation, including use of different GIA models and estimation...

  9. Influence of oxygen on alcoholic fermentation by a wine strain of Torulaspora delbrueckii: kinetics and carbon mass balance.

    Science.gov (United States)

    Brandam, Cédric; Lai, Quoc Phong; Julien-Ortiz, Anne; Taillandier, Patricia

    2013-01-01

    Torulaspora delbrueckii metabolism was assessed in a synthetic culture medium similar to grape must under various conditions: no aeration and three different oxygen feeds, in order to determine the effect of oxygen on metabolism. Carbon and nitrogen mass balances were calculated to quantify metabolic fluxes. The effect of oxygen was to decrease the flux of carbon going into the fermentation pathway in favor of growth. In the absence of aeration, higher amounts of glycerol were produced, probably to maintain the redox balance. The oxygen requirement of this strain was high, since even for the highest air supply oxygen became limiting after 24 h. Nevertheless, this strain developed well in the absence of oxygen and consumed 220 g/L of sugars (glucose/fructose) in 166 h at 20 °C, giving a good ethanol yield (0.50 g/g).

  10. Analytical and experimental investigation on a multiple-mass-element pendulum impact damper for vibration mitigation

    Science.gov (United States)

    Egger, Philipp; Caracoglia, Luca

    2015-09-01

    Impact dampers are often used in the field of civil, mechanical and aerospace engineering for reducing structural vibrations. The behavior of this type of passive control device has been investigated for several decades. In this research a distributed-mass impact damper, similar to the "chain damper" used in wind engineering, has been examined and applied to the vibration reduction on a slender line-like structural element (stay-cable). This study is motivated by a practical problem and describes the derivation of a reduced-order model for explaining the behavior, observed during a field experiment on a prototype system. In its simplest form, the dynamics of the apparatus is modeled as a "resilient damper", composed of mass-spring-dashpot secondary elements, attached to the primary structure. Various sources of excitation are analyzed: free vibration, external harmonic force and random excitation. The proposed model is general and potentially applicable to the analysis of several structural systems. The study also shows that the model can adequately describe and explain the experimentally observed behavior.

  11. Mass balance reassessment of glaciers draining into the Abbot and Getz Ice Shelves of West Antarctica

    NARCIS (Netherlands)

    Chuter, Stephen; Martin-Espanol, Alba; Wouters, B.; Bamber, Jonathan L.

    2017-01-01

    We present a reassessment of input-output method ice mass budget estimates for the Abbot and Getz regions of West Antarctica using CryoSat-2-derived ice thickness estimates. The mass budget is 8 ± 6 Gt yr−1 and 5 ± 17 Gt yr−1 for the Abbot and Getz sectors, respectively, for the period 2006–2008.

  12. Mass balance of Greenland's three largest outlet glaciers - 2000–2010

    NARCIS (Netherlands)

    Howat, I.M.; Ahn, Y.; Joughin, I.; van den Broeke, M.R.; Lenaerts, J.T.M.; Smith, B.

    2011-01-01

    Acceleration of Greenland's three largest outlet glaciers, Helheim, Kangerdlugssuaq and Jakobshavn Isbræ, accounted for a substantial portion of the ice sheet's mass loss over the past decade. Rapid changes in their discharge, however, make their cumulative mass-change uncertain. We derive monthly

  13. Recent mass balance of the Purogangri Ice Cap, central Tibetan Plateau, by means of differential X-band SAR interferometry

    Directory of Open Access Journals (Sweden)

    N. Neckel

    2013-10-01

    Full Text Available Due to their remoteness, altitude and harsh climatic conditions, little is known about the glaciological parameters of ice caps on the Tibetan Plateau. This study presents a geodetic mass balance estimate of the Purogangri Ice Cap, Tibet's largest ice field between 2000 and 2012. We utilized data from the actual TerraSAR-X mission and its add-on for digital elevation measurements and compared it with elevation data from the Shuttle Radar Topography Mission. The employed data sets are ideal for this approach as both data sets were acquired at X-band at nearly the same time of the year and are available at a fine grid spacing. In order to derive surface elevation changes we employed two different methods. The first method is based on differential synthetic radar interferometry while the second method uses common DEM differencing. Both approaches revealed a slightly negative mass budget of −44 ± 15 and −38 ± 23 mm w.eq. a−1 (millimeter water equivalent respectively. A slightly negative trend of −0.15 ± 0.01 km2 a−1 in glacier extent was found for the same time period employing a time series of Landsat data. Overall, our results show an almost balanced mass budget for the studied time period. Additionally, we detected one continuously advancing glacier tongue in the eastern part of the ice cap.

  14. Estimating ground-water inflow to lakes in central Florida using the isotope mass-balance approach

    Science.gov (United States)

    Sacks, Laura A.

    2002-01-01

    The isotope mass-balance approach was used to estimate ground-water inflow to 81 lakes in the central highlands and coastal lowlands of central Florida. The study area is characterized by a subtropical climate and numerous lakes in a mantled karst terrain. Ground-water inflow was computed using both steady-state and transient formulations of the isotope mass-balance equation. More detailed data were collected from two study lakes, including climatic, hydrologic, and isotopic (hydrogen and oxygen isotope ratio) data. For one of these lakes (Lake Starr), ground-water inflow was independently computed from a water-budget study. Climatic and isotopic data collected from the two lakes were similar even though they were in different physiographic settings about 60 miles apart. Isotopic data from all of the study lakes plotted on an evaporation trend line, which had a very similar slope to the theoretical slope computed for Lake Starr. These similarities suggest that data collected from the detailed study lakes can be extrapolated to the rest of the study area. Ground-water inflow computed using the isotope mass-balance approach ranged from 0 to more than 260 inches per year (or 0 to more than 80 percent of total inflows). Steady-state and transient estimates of ground-water inflow were very similar. Computed ground-water inflow was most sensitive to uncertainty in variables used to calculate the isotopic composition of lake evaporate (isotopic compositions of lake water and atmospheric moisture and climatic variables). Transient results were particularly sensitive to changes in the isotopic composition of lake water. Uncertainty in ground-water inflow results is considerably less for lakes with higher ground-water inflow than for lakes with lower ground-water inflow. Because of these uncertainties, the isotope mass-balance approach is better used to distinguish whether ground-water inflow quantities fall within certain ranges of values, rather than for precise

  15. Acidity of precipitation as influenced by the filtering of atmospheric sulphur and nitrogen compounds - its role in the element balance and effect on soil

    Science.gov (United States)

    Robert Mayer; Bernhard Ulrich

    1976-01-01

    The data presented here are based upon element balance investigations in a beech forest in Central Germany (Ellenberg 1971). Being located in an altitude of about 500 m above sea level with an annual precipitation of about 1000 mm, and an acid soil with loess as the main constituent, the test site represents a typical environment for many Central European forests....

  16. Measurement of the top quark mass in the lepton+jets final state with the matrix element method

    Energy Technology Data Exchange (ETDEWEB)

    Abazov, V.M.; Abbott, B.; Abolins, M.; Acharya, B.S.; Adams, M.; Adams, T.; Agelou, M.; Aguilo, E.; Ahn, S.H.; Ahsan, M.; Alexeev, G.D.; /Buenos Aires U. /Rio de Janeiro,

    2006-09-01

    We present a measurement of the top quark mass with the Matrix Element method in the lepton+jets final state. As the energy scale for calorimeter jets represents the dominant source of systematic uncertainty, the Matrix Element likelihood is extended by an additional parameter, which is defined as a global multiplicative factor applied to the standard energy scale. The top quark mass is obtained from a fit that yields the combined statistical and systematic jet energy scale uncertainty.

  17. Continuous measurement of elemental composition of ambient aerosol by induction-coupled plasma mass spectrometry.

    Science.gov (United States)

    Mishra, Santosh K; Chattopadhyay, Bhargab; Kadjo, Akinde F; Dasgupta, Purnendu K

    2018-01-15

    There is presently no instrumentation that can provide (near) real time information on elemental composition of atmospheric aerosols. We describe an arrangement where air is sampled through a cyclone @30L/min with a 50% cutoff @ ~250nm. The particles deposit into a cup through which deionized water is continuously flowing. High purity HNO3 is added downstream and the mixed stream optionally flows through a quartz photo reactor (185nm, ~90°C, tR ~1.2min) and is aspirated by an induction coupled plasma mass spectrometer (ICP-MS). Comparative batch experiments in which samples were not photodigested at all or thermally digested off-line for an extended period indicated no statistically significant difference in the results. This observation agrees with early theoretical and experimental work. Some 22 elements were quantifiable (S/N > 10) at all times in the aerosol samples collected in our highly urban sampling location; an additional 4 elements were quantifiable at times of construction activity in the general area. Presently attained system limits of detection (LODs) are orders of magnitude higher than the instrumental LOD, both because of the purity of the acid and pump-induced contamination. These aspects can be vastly improved and will need to be improved to determine background concentrations. Copyright © 2017 Elsevier B.V. All rights reserved.

  18. Maternal Prepregnancy Body Mass Index and Their Children's Blood Pressure and Resting Cardiac Autonomic Balance at Age 5 to 6 Years

    NARCIS (Netherlands)

    Gademan, M.G.J.; van Eijsden, M.; Roseboom, T.J.; van der Post, J.A.M.; Stronks, K.; Vrijkotte, T.G.M.

    2013-01-01

    Adverse intrauterine conditions can program hypertension. Because one of the underlying mechanisms is thought to be cardiac autonomic balance, we investigated the association between prepregnancy body mass index (BMI) and blood pressure and indicators of the autonomic balance in the child at age 5

  19. Study on the combined sewage sludge pyrolysis and gasification process: mass and energy balance.

    Science.gov (United States)

    Wang, Zhonghui; Chen, Dezhen; Song, Xueding; Zhao, Lei

    2012-12-01

    A combined pyrolysis and gasification process for sewage sludge was studied in this paper for the purpose of its safe disposal with energy self-balance. Three sewage sludge samples with different dry basis lower heat values (LHV(db)) were used to evaluate the constraints on this combined process. Those samples were pre-dried and then pyrolysed within the temperature range of 400-550 degrees C. Afterwards, the char obtained from pyrolysis was gasified to produce fuel gas. The experimental results showed that the char yield ranged between 37.28 and 53.75 wt% of the dry sludge and it changed with ash content, pyrolysis temperature and LHV(db) of the sewage sludge. The gas from char gasification had a LHV around 5.31-5.65 MJ/Nm3, suggesting it can be utilized to supply energy in the sewage sludge drying and pyrolysis process. It was also found that energy balance in the combined process was affected by the LHV(db) of sewage sludge, moisture content and pyrolysis temperature. Higher LHV(db), lower moisture content and higher pyrolysis temperature benefit energy self-balance. For sewage sludge with a moisture content of 80 wt%, LHV(db) of sewage sludge should be higher than 18 MJ/kg and the pyrolysis temperature should be higher than 450 degrees C to maintain energy self-sufficiency when volatile from the pyrolysis process is the only energy supplier; when the LHV(db) was in the range of 14.65-18 MJ/kg, energy self-balance could be maintained in this combined process with fuel gas from char gasification as a supplementary fuel; auxiliary fuel was always needed if the LHV(db) was lower than 14.65 MJ/kg.

  20. Winter mass balance of Drangajökull ice cap (NW Iceland derived from satellite sub-meter stereo images

    Directory of Open Access Journals (Sweden)

    J. M. C. Belart

    2017-06-01

    Full Text Available Sub-meter resolution, stereoscopic satellite images allow for the generation of accurate and high-resolution digital elevation models (DEMs over glaciers and ice caps. Here, repeated stereo images of Drangajökull ice cap (NW Iceland from Pléiades and WorldView2 (WV2 are combined with in situ estimates of snow density and densification of firn and fresh snow to provide the first estimates of the glacier-wide geodetic winter mass balance obtained from satellite imagery. Statistics in snow- and ice-free areas reveal similar vertical relative accuracy ( <  0.5 m with and without ground control points (GCPs, demonstrating the capability for measuring seasonal snow accumulation. The calculated winter (14 October 2014 to 22 May 2015 mass balance of Drangajökull was 3.33 ± 0.23 m w.e. (meter water equivalent, with ∼ 60 % of the accumulation occurring by February, which is in good agreement with nearby ground observations. On average, the repeated DEMs yield 22 % less elevation change than the length of eight winter snow cores due to (1 the time difference between in situ and satellite observations, (2 firn densification and (3 elevation changes due to ice dynamics. The contributions of these three factors were of similar magnitude. This study demonstrates that seasonal geodetic mass balance can, in many areas, be estimated from sub-meter resolution satellite stereo images.

  1. Satellite-derived submarine melt rates and mass balance (2011–2015 for Greenland's largest remaining ice tongues

    Directory of Open Access Journals (Sweden)

    N. Wilson

    2017-12-01

    Full Text Available Ice-shelf-like floating extensions at the termini of Greenland glaciers are undergoing rapid changes with potential implications for the stability of upstream glaciers and the ice sheet as a whole. While submarine melting is recognized as a major contributor to mass loss, the spatial distribution of submarine melting and its contribution to the total mass balance of these floating extensions is incompletely known and understood. Here, we use high-resolution WorldView satellite imagery collected between 2011 and 2015 to infer the magnitude and spatial variability of melt rates under Greenland's largest remaining ice tongues – Nioghalvfjerdsbræ (79 North Glacier, 79N, Ryder Glacier (RG, and Petermann Glacier (PG. Submarine melt rates under the ice tongues vary considerably, exceeding 50 m a−1 near the grounding zone and decaying rapidly downstream. Channels, likely originating from upstream subglacial channels, give rise to large melt variations across the ice tongues. We compare the total melt rates to the influx of ice to the ice tongue to assess their contribution to the current mass balance. At Petermann Glacier and Ryder Glacier, we find that the combined submarine and aerial melt approximately balances the ice flux from the grounded ice sheet. At Nioghalvfjerdsbræ the total melt flux (14.2 ± 0.96 km3 a−1 w.e., water equivalent exceeds the inflow of ice (10.2 ± 0.59 km3 a−1 w.e., indicating present thinning of the ice tongue.

  2. Snow contribution to first-year and second-year Arctic sea ice mass balance north of Svalbard

    Science.gov (United States)

    Granskog, Mats A.; Rösel, Anja; Dodd, Paul A.; Divine, Dmitry; Gerland, Sebastian; Martma, Tõnu; Leng, Melanie J.

    2017-03-01

    The salinity and water oxygen isotope composition (δ18O) of 29 first-year (FYI) and second-year (SYI) Arctic sea ice cores (total length 32.0 m) from the drifting ice pack north of Svalbard were examined to quantify the contribution of snow to sea ice mass. Five cores (total length 6.4 m) were analyzed for their structural composition, showing variable contribution of 10-30% by granular ice. In these cores, snow had been entrained in 6-28% of the total ice thickness. We found evidence of snow contribution in about three quarters of the sea ice cores, when surface granular layers had very low δ18O values. Snow contributed 7.5-9.7% to sea ice mass balance on average (including also cores with no snow) based on δ18O mass balance calculations. In SYI cores, snow fraction by mass (12.7-16.3%) was much higher than in FYI cores (3.3-4.4%), while the bulk salinity of FYI (4.9) was distinctively higher than for SYI (2.7). We conclude that oxygen isotopes and salinity profiles can give information on the age of the ice and enables distinction between FYI and SYI (or older) ice in the area north of Svalbard.Plain Language SummaryThe role of snow in sea ice mass balance is largely two fold. Firstly, it can slow down growth and melt due to its high insulation and high reflectance, but secondly it can actually contribute to sea ice growth if the snow cover is turned into ice. The latter is largely a consequence of high mass of snow on top of sea ice that can push the surface of the sea ice below sea level and seawater can flood the ice. This mixture of seawater and snow can then freeze and add to the growth of sea ice. This is very typical in the Antarctic but not believed to be so important in the Arctic. In this work we show, for the first time, that snow actually contributes significantly to the growth of Arctic sea ice. This is likely a consequence of the thinning of the Arctic sea ice. The conditions in the Arctic, with thinner and more seasonal ice thus resemble the ice

  3. Development of an in vivo animal model for skin penetration in hairless rats assessed by mass balance

    DEFF Research Database (Denmark)

    Simonsen, Lene; Petersen, Mads B; Benfeldt, Eva

    2002-01-01

    acid and (14)C-butyl salicylate were topically applied. Rapid and differentiated percutaneous absorption of both compounds were shown by urinary excretion data. For (14)C-salicylic acid the amount on the skin surface, in the stratum corneum and in the viable skin was determined. Total mass balance...... rat and free mobility throughout the test period. By consecutive tape stripping, monitored by measurements of transepidermal water loss and confirmed by histological examination of skin biopsies, 10 tape strippings were found to remove the stratum corneum completely. For assessment of the model, (14)C-salicylic...

  4. Decadal-scale joint inversion of NOx and SO2 using a hybrid 4D-Var / mass balance approach

    Science.gov (United States)

    Qu, Z.; Henze, D. K.; Capps, S.; Wang, Y.; Xu, X.; Wang, J.; Keller, M.

    2016-12-01

    Quantifying the emissions of nitrogen oxides (NOx) and sulfur dioxide (SO2) is important for improving our understanding of acid rain, formation of aerosols, and human health problems. Traditional top-down estimates have provided valuable constraints for NOx and SO2 emission inventories in China, but are either time-consuming (e.g., 4D-Var) or only crudely represent the influence of atmospheric transport and chemistry (e.g., mass balance). We develop an approach combining mass balance and an adjoint-based four-dimensional variational (4D-Var) methods that facilitates decadal-scale emission inversions. This hybrid inversion is first evaluated with a single species inversion using NO2 pseudo observations. In a set of seven-year pseudo observation test, hybrid posterior NOx emissions have smaller normalized mean square error (by 54% to 94%) than that of mass balance when compared to true emissions in most cases, and have slightly better performance in detecting emissions magnitudes and trends. Using this hybrid method, NO2 observations from the Ozone Monitoring Instrument (OMI), and the GEOS-Chem chemical transport model, we have derived monthly top-down NOx emissions for China from 2005 to 2012. Our posterior emissions have the same seasonality as recent bottom-up inventories, and smaller emissions (by 13.4% to 23.5%) as well as emission growth rate (by 0.6% to 4.1%). The hybrid method is further implemented for long-term joint inversion of NOx and SO2 emissions in China using combined observations of OMI NO2 and SO2 column densities. A 4D-Var inversion is first performed to optimize NOx and SO2 emissions in the base year using GEOS-Chem adjoint. Mass balance scaling factor is then applied to these posterior to improve their inter-annual variation. Overall, these studies augment the utility of remote sensing data for evaluating emission control strategies and mitigating the impact of NOx and SO2 on human health and the environment.

  5. Influence of albedo parameterization on surface mass balance in the perspective of Greenland ice sheet modelling in EC-Earth

    OpenAIRE

    Helsen, Michiel; Van De Wal, Roderik,; Reerink, Thomas; Bintanja, Richard; Sloth Madsen, Marianne; Yang, Shuting; Li, Qiang; Zhang, Qiong

    2016-01-01

    The albedo of the surface of ice sheets changes as a function of time, due to the effects of deposition of new snow, ageing of dry snow, melting and runoff. Currently, the calculation of the albedo of ice sheets is highly parameterized within the Earth System Model EC-Earth, by taking a constant value for areas with thick perennial snow cover. This is one of the reasons that the surface mass balance (SMB) of the Greenland ice sheet (GrIS) is poorly resolved in the model. To improve this, eigh...

  6. On the importance of the albedo parameterization for the mass balance of the Greenland ice sheet in EC-Earth

    OpenAIRE

    Helsen, M.M.; van de Wal, R. S. W.; Reerink, T. J.; R. Bintanja; Madsen, M.S.; Yang, S; Li, Q; Zhang, Q

    2017-01-01

    The albedo of the surface of ice sheets changes as a function of time due to the effects of deposition of new snow, ageing of dry snow, bare ice exposure, melting and run-off. Currently, the calculation of the albedo of ice sheets is highly parameterized within the earth system model EC-Earth by taking a constant value for areas with thick perennial snow cover. This is an important reason why the surface mass balance (SMB) of the Greenland ice sheet (GrIS) is poorly resolved...

  7. Mass Balance Analyses of Flushing, Evaporation, Infiltration, and Biological Activity in California Park Lakes, Butte County, California

    Science.gov (United States)

    Murphy, W. M.; Sundermann, C. R.

    2002-12-01

    California Park Lakes are retained by dams on Dead Horse Slough, an ephemeral stream network, which flows over volcanic/sedimentary rocks of the Tuscan Formation at the eastern margin of the Sacramento Valley, Butte County, California. Surface area of the lakes is approximately 0.2 km2, maximum depth is 8 m, and approximate lake volume is 700,000 m3. Flow rate and depth measurements in Dead Horse Slough indicate that discharges associated with winter storms flush the lakes repeatedly. During dry summer months no surface water discharges from the lakes and water is pumped from the underlying aquifer to maintain the water level. Average pumping rates are approximately 1250 m3/day. Surface and storm drain runoff, mainly from nearby lawn irrigation, also supply water at fluctuating rates estimated to equal a fraction (e.g., 35 percent) of well water supply. Reported pan evaporation data indicate that summer evaporation from lake surfaces is 1000 to 1500 m3/day. Thus, the estimated evaporation rate approximately equals the well water and runoff supply rate. Periodic chemical analyses of water supplies and lake water have been conducted primarily to evaluate nutrient sources. Typical nitrate and chloride concentrations are 2 to 10 mg/liter, and typical phosphate concentrations are 0.2 to 1 mg/liter. Chloride concentrations in lake water during summer 2002 increased slightly corresponding closely to mass balance calculations for evaporative concentration. Infiltration (including leakage through the terminal dam) is small relative to evaporation and difficult to measure within the uncertainty of chloride measurements and water mass balance estimates. Lake concentrations of nitrate and phosphate are generally lower than source water concentrations consistent with biological consumption. Mass balance analyses of dissolved nutrients in lakes and water sources compared to chloride provide a measure of the rate of biological activity in the lakes, which is a water quality

  8. The Impact of a Mild Sub-Critical Hydrothermal Carbonization Pretreatment on Umbila Wood. A Mass and Energy Balance Perspective

    Directory of Open Access Journals (Sweden)

    Carlos Alberto Cuvilas

    2015-03-01

    Full Text Available Over the last years, the pretreatment of biomass as a source of energy has become one of the most important steps of biomass conversion. In this work the effect of a mild subcritical hydrothermal carbonization of a tropical woody biomass was studied. Results indicate considerable change in carbon content from 52.78% to 65.1%, reduction of oxygen content from 41.14% to 28.72% and ash slagging and fouling potential. Even though decarboxylation, decarbonylation and dehydration reactions take place, dehydration is the one that prevails. The mass and energy balance was affected by the treatment conditions than the severity of the treatment.

  9. The Effects of Musical Elements in Mass Media and Internet on the Social Development of Children and Adolescents

    Science.gov (United States)

    Celasin, Cenk

    2013-01-01

    In this qualitative study, musical elements in mass media and internet mostly intended to children and adolescents, were examined in the context of the dimensions of the social development of them in a general approach, through scientific literature and written, audio, visual and audio-visual documents regarding mass media and internet. Purpose of…

  10. Anaerobic digestion of ultrasonicated sludge at different solids concentrations - Computation of mass-energy balance and greenhouse gas emissions.

    Science.gov (United States)

    Pilli, Sridhar; Yan, S; Tyagi, R D; Surampalli, R Y

    2016-01-15

    Two cases of anaerobic digestion (AD) of sludge, namely (i) with pre-treatment and (ii) without pre-treatment, were assessed using mass-energy balance and the corresponding greenhouse gas (GHG) emissions. For a digestion period of 30 days, volatile solids degradation of the control sludge and the ultrasonicated secondary sludge was 51.4% and 60.1%, respectively. Mass balance revealed that the quantity of digestate required for dewatering, transport and land application was the lowest (20.2 × 10(6) g dry sludge/day) for ultrasonicated secondary sludge at 31.4 g TS/L. Furthermore, for ultrasonicated secondary sludge at 31.4 g TS/L, the maximum net energy (energy output - energy input) of total dry solids (TDS) was 7.89 × 10(-6) kWh/g and the energy ratio (output/input) was 1.0. GHG emissions were also reduced with an increase in the sludge solids concentration (i.e., 40.0 g TS/L < 30.0 g TS/L < 20.0 g TS/L). Ultrasonication pre-treatment proved to be efficient and beneficial for enhancing anaerobic digestion efficiency of the secondary sludge when compared to the primary and mixed sludge. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. A mass balance approach to the fate of viruses in a municipal wastewater treatment plant during summer and winter seasons.

    Science.gov (United States)

    Ulbricht, Katharina; Selinka, Hans-Christoph; Wolter, Stefanie; Rosenwinkel, Karl-Heinz; Nogueira, Regina

    2014-01-01

    In contrast to previous discussion on general virus removal efficiency and identifying surrogates for human pathogenic viruses, this study focuses on virus retention within each step of a wastewater treatment plant (WWTP). Additionally, the influence of weather conditions on virus removal was addressed. To account for the virus retention, this study describes a mass balance of somatic coliphages (bacterial viruses) in a municipal WWTP, performed in the winter and summer seasons of 2011. In the winter season, the concentration of coliphages entering the WWTP was about 1 log lower than in summer. The mass balance in winter revealed a virus inactivation of 85.12 ± 13.97%. During the summer season, virus inactivation was significantly higher (95.25 ± 3.69%, p-value virus removal in the secondary clarifier by insolation. Thus, a total removal of coliphages of about 2.78 log units was obtained in summer compared to 1.95 log units in winter. Rainfall events did not statistically correlate with the concentrations of coliphages entering the WWTP in summer.

  12. Modelling system dynamics and phytoplankton diversity at Ranchi lake using the carbon and nutrient mass balance equations.

    Science.gov (United States)

    Mukherjee, B; Nivedita, M; Mukherjee, D

    2014-05-01

    Modelling system dynamics in a hyper-eutrophic lake is quite complex especially with a constant influx of detergents and sewage material which continually changes the state variables and interferes with the assessment of the chemical rhythm occurring in polluted conditions as compared to unpolluted systems. In this paper, a carbon and nutrient mass balance model for predicting system dynamics in a complex environment was studied. Studies were conducted at Ranchi lake to understand the altered environmental dynamics in hyper-eutrophic conditions, and its impact on the plankton community. The lake was monitored regularly for five years (2007 - 2011) and the data collected on the carbon flux, nitrates, phosphates and silicates was used to design a mass balance model for evaluating and predicting the system. The model was then used to correlate the chemical rhythm with that of the phytoplankton dynamics and diversity. Nitrates and phosphates were not limiting (mean nitrate and phosphate concentrations were 1.74 and 0.83 mgl⁻¹ respectively). Free carbon dioxide was found to control the system and, interacting with other parameters determined the diversity and dynamics of the plankton community. N/P ratio determined which group of phytoplankton dominated the community, above 5 it favoured the growth of chlorophyceae while below 5 cyanobacteria dominates. TOC/TIC ratio determined the abundance. The overall system was controlled by the availability of free carbon dioxide which served as a limiting factor.

  13. Reactions of anionic porphyrin with group 11 elements: a spectrophotometric and electrospray ionization mass spectrometry study.

    Science.gov (United States)

    Giovannetti, Rita; Bartocci, Vito; Pucciarelli, Filippo; Ricciutelli, Massimo

    2004-07-08

    The reaction of 3,8,13,18-tetramethyl-21H,23H-porphine-2,7,12,17-tetrapropionic acid or coproporphyrin-I (CPI) with the elements of 11 group have been studied. CPI is an anionic porphyrin that slowly reacts with copper ion to form Cu(II)CPI and with silver ions to form Ag(II)CPI, Ag(III)CPI complexes and colloidal silver. Gold ions do not form complexes with CPI, but, in the main, colloidal gold and some CPI-N-oxide. The kinetics of the reactions with copper and silver were spectrophotometerically studied and the rate constants were calculated. The identification and characterization of this water-soluble anionic porphyrin and its metal complexes have been performed by electrospray mass spectrometry (ESI-MS) that proved to be an excellent method for these determinations. The multiple charged parent ions for metal free ligand and their metal complexes were identified.

  14. Simultaneous determination of major, minor and trace elements in biocarbonates by inductively coupled plasma mass spectrometry.

    Science.gov (United States)

    Sun, Yali; Sun, Min

    2002-12-01

    A method was developed for simultaneous determination of major (Ca), minor (Mg and Sr) and trace (Ba and U) elements in biocarbonates by inductively coupled plasma mass spectrometry (ICP-MS). The method precision (RSD%) is 0.73% for Ca, 0.77% for Mg, 0.59% for Sr, 2.02% for Ba, 1.13% for U, 0.67% for Mg/Ca, 0.27% for Sr/Ca, 2.06% for Ba/Ca and 1.23% for U/Ca. The ratio precision suggests that ICP-MS is satisfactory for obtaining multi-ratio data from biocarbonates. This technique was applied to 67 continuous coral samples.

  15. Simultaneous determination of major, minor and trace elements in biocarbonates by inductively coupled plasma mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Yali; Sun, Min [Department of Earth Sciences, the University of Hong Kong, Pokfulam Road, Hong Kong (China)

    2002-12-01

    A method was developed for simultaneous determination of major (Ca), minor (Mg and Sr) and trace (Ba and U) elements in biocarbonates by inductively coupled plasma mass spectrometry (ICP-MS). The method precision (RSD%) is 0.73% for Ca, 0.77% for Mg, 0.59% for Sr, 2.02% for Ba, 1.13% for U, 0.67% for Mg/Ca, 0.27% for Sr/Ca, 2.06% for Ba/Ca and 1.23% for U/Ca. The ratio precision suggests that ICP-MS is satisfactory for obtaining multi-ratio data from biocarbonates. This technique was applied to 67 continuous coral samples. (orig.)

  16. Sensitivity analysis of lake mass balance in discontinuous permafrost: the example of disappearing Twelvemile Lake, Yukon Flats, Alaska (USA)

    Science.gov (United States)

    Jepsen, S.M.; Voss, C.I.; Walvoord, Michelle Ann; Rose, J.R.; Minsley, B.J.; Smith, B.D.

    2013-01-01

    Many lakes in northern high latitudes have undergone substantial changes in surface area over the last four decades, possibly as a result of climate warming. In the discontinuous permafrost of Yukon Flats, interior Alaska (USA), these changes have been non-uniform across adjacent watersheds, suggesting local controls on lake water budgets. Mechanisms that could explain the decreasing mass of one lake in Yukon Flats since the early 1980s, Twelvemile Lake, are identified via a scoping analysis that considers plausible changes in snowmelt mass and infiltration, permafrost distribution, and climate warming. Because predicted changes in evaporation (2 cmyr-1) are inadequate to explain the observed 17.5 cmyr-1 reduction in mass balance, other mechanisms are required. The most important potential mechanisms are found to involve: (1) changes in shallow, lateral groundwater flow to the lake possibly facilitated by vertical freeze-thaw migration of the permafrost table in gravel; (2) increased loss of lake water as downward groundwater flow through an open talik to a permeable subpermafrost flowpath; and (3) reduced snow meltwater inputs due to decreased snowpack mass and increased infiltration of snowmelt into, and subsequent evaporation from, fine-grained sediment mantling the permafrost-free lake basin.

  17. Top Quark Mass Measurement in the Lepton plus Jets Channel Using a Modified Matrix Element Method

    Energy Technology Data Exchange (ETDEWEB)

    Aaltonen, T.; /Helsinki Inst. of Phys.; Adelman, J.; /Chicago U., EFI; Akimoto, T.; /Tsukuba U.; Alvarez Gonzalez, B.; /CSIC, Catalunya; Amerio, S.; /INFN, Padua; Amidei, D.; /Michigan U.; Anastassov, A.; /Northwestern U.; Annovi, A.; /Frascati; Antos, J.; /Comenius U.; Apollinari, G.; /Fermilab; Apresyan, A.; /Purdue U. /Waseda U.

    2008-12-01

    The authors report a measurement of the top quark mass, m{sub t}, obtained from p{bar p} collisions at {radical}s = 1.96 TeV at the Fermilab Tevatron using the CDF II detector. They analyze a sample corresponding to an integrated luminosity of 1.9 rfb{sup -1}. They select events with an electron or muon, large missing transverse energy, and exactly four high-energy jets in the central region of the detector, at least one of which is tagged as coming from a b quark. They calculate a signal likelihood using a matrix element integration method, where the matrix element is modified by using effective propagators to take into account assumptions on event kinematics. The event likelihood is a function of m{sub t} and a parameter JES that determines in situ the calibration of the jet energies. They use a neural network discriminant to distinguish signal from background events. They also apply a cut on the peak value of each event likelihood curve to reduce the contribution of background and badly reconstructed events. Using the 318 events that pass all selection criteria, they find m{sub t} = 172.7 {+-} 1.8 (stat. + JES) {+-} 1.2(syst.) GeV/c{sup 2}.

  18. New Balancing Equipment for Mass Production of Small and Medium-Sized Electrical Machines

    DEFF Research Database (Denmark)

    Argeseanu, Alin; Ritchie, Ewen; Leban, Krisztina Monika

    2010-01-01

    The level of vibration and noise is an important feature. It is good practice to explain the significance of the indicators of the quality of electrical machines. The mass production of small and medium-sized electrical machines demands speed (short typical measurement time), reliability...

  19. Mass balance evaluation of polybrominated diphenyl ethers in landfill leachate and potential for transfer from e-waste

    Energy Technology Data Exchange (ETDEWEB)

    Danon-Schaffer, Monica N. [Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, Canada V6T 1Z3 (Canada); Tetra Tech, 800-555 West Hastings Street, Vancouver, Canada V6B 1M1 (Canada); Mahecha-Botero, Andrés, E-mail: andresm@chbe.ubc.ca [Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, Canada V6T 1Z3 (Canada); Grace, John R. [Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, Canada V6T 1Z3 (Canada); Ikonomou, Michael [Institute of Ocean Sciences, P.O. Box 6000, 9860 West Saanich Road, Sidney, B.C., Canada V8L 4B2 (Canada)

    2013-09-01

    Previous research on brominated flame retardants (BFRs), including polybrominated diphenyl ethers (PBDEs) has largely focussed on their concentrations in the environment and their adverse effects on human health. This paper explores their transfer from waste streams to water and soil. A comprehensive mass balance model is developed to track polybrominated diphenyl ethers (PBDEs), originating from e-waste and non-e-waste solids leaching from a landfill. Stepwise debromination is assumed to occur in three sub-systems (e-waste, aqueous leachate phase, and non-e-waste solids). Analysis of landfill samples and laboratory results from a solid-liquid contacting chamber are used to estimate model parameters to simulate an urban landfill system, for past and future scenarios. Sensitivity tests to key model parameters were conducted. Lower BDEs require more time to disappear than high-molecular weight PBDEs, since debromination takes place in a stepwise manner, according to the simplified reaction scheme. Interphase mass transfer causes the decay pattern to be similar in all three sub-systems. The aqueous phase is predicted to be the first sub-system to eliminate PBDEs if their input to the landfill were to be stopped. The non-e-waste solids would be next, followed by the e-waste sub-system. The model shows that mass transfer is not rate-limiting, but the evolution over time depends on the kinetic degradation parameters. Experimental scatter makes model testing difficult. Nevertheless, the model provides qualitative understanding of the influence of key variables. - Graphical abstract: Schematic of the various mass transfer (MT) and input/output steps for sub-systems in the landfill model. NeWS is defined as non-electronic waste solids, including sand and soil added as cover materials. Highlights: • A comprehensive mass balance model is developed to track polybrominated diphenyl ethers (PBDEs). • Landfill samples and laboratory results are used to estimate the model

  20. Reconstruction of the 1979–2006 Greenland ice sheet surface mass balance using the regional climate model MAR

    Directory of Open Access Journals (Sweden)

    X. Fettweis

    2007-10-01

    Full Text Available Results from a 28-year simulation (1979–2006 over the Greenland ice sheet (GrIS reveal an increase of solid precipitation (+0.4±2.5 km3 yr−2 and run-off (+7.9±3.3 km3 yr−2 of surface meltwater. The net effect of these competing factors is a significant Surface Mass Balance (SMB loss of −7.2±5.1 km3 yr−2. The contribution of changes in the net water vapour flux (+0.02±0.09 km3 yr−2 and rainfall (+0.2±0.2 km3 yr−2 to the SMB variability is negligible. The meltwater supply has increased because the GrIS surface has been warming up +2.4°C since 1979. Sensible heat flux, latent heat flux and net solar radiation have not varied significantly over the last three decades. However, the simulated downward infrared flux has increased by 9.3 W m−2 since 1979. The natural climate variability (e.g. the North Atlantic Oscillation does not explain these changes. The recent global warming, due to the greenhouse gas concentration increase induced by human activities, could be a cause of these changes. The doubling of surface meltwater flux into the ocean over the period 1979–2006 suggests that the overall ice sheet mass balance has been increasingly negative, given the likely meltwater-induced acceleration of outlet glaciers. This study suggests that increased melting overshadows over an increased accumulation in a warming scenario and that the GrIS is likely to keep losing mass in the future. An enduring GrIS melting will probably affect in the future an certain effect on the stability of the thermohaline circulation and the global sea level rise.

  1. Mass balance and mass loading of polybrominated diphenyl ethers (PBDEs) in a tertiary wastewater treatment plant using SBSE-TD-GC/MS.

    Science.gov (United States)

    Rocha-Gutiérrez, Beatriz A; Lee, Wen-Yee; Shane Walker, W

    2016-01-01

    A mass loading and mass balance analysis was performed on selected polybromodiphenyl ethers (PBDEs) in the first full-scale indirect potable reuse treatment plant in the United States. Chemical analysis of PBDEs was performed using an environmentally friendly sample preparation technique, called stir-bar sorptive extraction (SBSE), coupled with thermal desorption and gas chromatography/mass spectrometry (GC/MS). The three most dominant PBDEs found in all the samples were: BDE-47, BDE-99 and BDE-100. In the wastewater influent, the concentrations of studied PBDEs ranged from 94 to 775 ng/L, and in the effluent, the levels were below the detection limit. Concentrations in sludge ranged from 50 to 182 ng/g. In general, a removal efficiency of 92-96% of the PBDEs in the plant was accomplished through primary and secondary processes. The tertiary treatment process was able to effectively reduce the aforementioned PBDEs to less than 10 ng/L (>96% removal efficiency) in the effluent. If PBDEs remain in the treated wastewater effluent, they may pose environmental and health impacts through aquifer recharge, irrigation, and sludge final disposal.

  2. Assessment of interannual variations in the surface mass balance of 18 Svalbard glaciers from the Moderate Resolution Imaging Spectroradiometer/Terra albedo product

    NARCIS (Netherlands)

    Greuell, W.|info:eu-repo/dai/nl/074214098; Kohler, J.; Obleitner, F.; Glowacki, P.; Melvold, K.; Bernsen, E.|info:eu-repo/dai/nl/304831964; Oerlemans, J.|info:eu-repo/dai/nl/06833656X

    2007-01-01

    We estimate annual anomalies of the surface mass balance of glaciers on Svalbard for the period 2000–2005 (six years), by calculating the so-called ‘‘satellite-derived mass balance’’ (Bsat) from time series of satellite-derived surface albedos. The method needs no other input variables. Surface

  3. Methods for validation of the mass distribution of a full body finite element model - biomed 2011.

    Science.gov (United States)

    Thompson, A Bradley; Rhyne, Ashley C; Moreno, Daniel P; Gayzik, F Scott; Stitzel, Joel D

    2011-01-01

    Accurate mass distribution in computational human body models is essential for kinematic and kinetic validation. The purpose of this study was to validate the mass distribution of the 50th percentile male model (M50) developed as part of the Global Human Body Models Consortium (GHBMC) project. The body segment centers of gravity (CG) of M50 were compared against published data in two ways: using a homogeneous body surface CAD model, and a Finite Element Model (FEM). Both the CAD and FEM models were generated from image data collected from the same 50th percentile male subject. Each model was partitioned into 11 segments, using segment planes constructed from bony landmarks acquired from the subject. CG’s of the CAD and FEA models were computed using commercially available software packages. Deviation between the literature data CG’s and CG’s of the FEM and CAD were 5.8% and 5.6% respectively when normalized by a regional characteristic length. Deviation between the FEM and CAD CG’s averaged 2.4% when normalized in the same fashion. Unlike the CAD and literature which both assume homogenous mass distribution, the FEM CG data account for varying densities of anatomical structures by virtue of the assigned material properties. This analysis validates the CG’s determined from each model by comparing them directly to well-known literature studies that rely only on anthropometric landmarks to determine the CG’s measurements. The results of this study will help enhance the biofidelity of the GHBMC M50 model.

  4. Energy balance of stellar coronae. III - Effect of stellar mass and radius

    Science.gov (United States)

    Hammer, R.

    1984-01-01

    A homologous transformation is derived which permits the application of the numerical coronal models of Hammer from a star with solar mass and radius to other stars. This scaling requires a few approximations concerning the lower boundary conditions and the temperature dependence of the conductivity and emissivity. These approximations are discussed and found to be surprisingly mild. Therefore, the scaling of the coronal models to other stars is rather accurate; it is found to be particularly accurate for main-sequence stars. The transformation is used to derive an equation that gives the maximum temperature of open coronal regions as a function of stellar mass and radius, the coronal heating flux, and the characteristic damping length over which the corona is heated.

  5. Monitoring glacier albedo as a proxy to derive summer and annual surface mass balances from optical remote-sensing data

    Directory of Open Access Journals (Sweden)

    L. Davaze

    2018-01-01

    Full Text Available Less than 0.25 % of the 250 000 glaciers inventoried in the Randolph Glacier Inventory (RGI V.5 are currently monitored with in situ measurements of surface mass balance. Increasing this archive is very challenging, especially using time-consuming methods based on in situ measurements, and complementary methods are required to quantify the surface mass balance of unmonitored glaciers. The current study relies on the so-called albedo method, based on the analysis of albedo maps retrieved from optical satellite imagery acquired since 2000 by the MODIS sensor, on board the TERRA satellite. Recent studies revealed substantial relationships between summer minimum glacier-wide surface albedo and annual surface mass balance, because this minimum surface albedo is directly related to the accumulation–area ratio and the equilibrium-line altitude. On the basis of 30 glaciers located in the French Alps where annual surface mass balance data are available, our study conducted on the period 2000–2015 confirms the robustness and reliability of the relationship between the summer minimum surface albedo and the annual surface mass balance. For the ablation season, the integrated summer surface albedo is significantly correlated with the summer surface mass balance of the six glaciers seasonally monitored. These results are promising to monitor both annual and summer glacier-wide surface mass balances of individual glaciers at a regional scale using optical satellite images. A sensitivity study on the computed cloud masks revealed a high confidence in the retrieved albedo maps, restricting the number of omission errors. Albedo retrieval artifacts have been detected for topographically incised glaciers, highlighting limitations in the shadow correction algorithm, although inter-annual comparisons are not affected by systematic errors.

  6. Assessing the optimized precision of the aircraft mass balance method for measurement of urban greenhouse gas emission rates through averaging

    Directory of Open Access Journals (Sweden)

    Alexie M. F. Heimburger

    2017-06-01

    Full Text Available To effectively address climate change, aggressive mitigation policies need to be implemented to reduce greenhouse gas emissions. Anthropogenic carbon emissions are mostly generated from urban environments, where human activities are spatially concentrated. Improvements in uncertainty determinations and precision of measurement techniques are critical to permit accurate and precise tracking of emissions changes relative to the reduction targets. As part of the INFLUX project, we quantified carbon dioxide (CO2, carbon monoxide (CO and methane (CH4 emission rates for the city of Indianapolis by averaging results from nine aircraft-based mass balance experiments performed in November-December 2014. Our goal was to assess the achievable precision of the aircraft-based mass balance method through averaging, assuming constant CO2, CH4 and CO emissions during a three-week field campaign in late fall. The averaging method leads to an emission rate of 14,600 mol/s for CO2, assumed to be largely fossil-derived for this period of the year, and 108 mol/s for CO. The relative standard error of the mean is 17% and 16%, for CO2 and CO, respectively, at the 95% confidence level (CL, i.e. a more than 2-fold improvement from the previous estimate of ~40% for single-flight measurements for Indianapolis. For CH4, the averaged emission rate is 67 mol/s, while the standard error of the mean at 95% CL is large, i.e. ±60%. Given the results for CO2 and CO for the same flight data, we conclude that this much larger scatter in the observed CH4 emission rate is most likely due to variability of CH4 emissions, suggesting that the assumption of constant daily emissions is not correct for CH4 sources. This work shows that repeated measurements using aircraft-based mass balance methods can yield sufficient precision of the mean to inform emissions reduction efforts by detecting changes over time in urban emissions.

  7. Using bioprocess stoichiometry to build a plant-wide mass balance based steady-state WWTP model.

    Science.gov (United States)

    Ekama, G A

    2009-05-01

    Steady-state models are useful for design of wastewater treatment plants (WWTPs) because they allow reactor sizes and interconnecting flows to be simply determined from explicit equations in terms of unit operation performance criteria. Once the overall WWTP scheme is established and the main system defining parameters of the individual unit operations estimated, dynamic models can be applied to the connected unit operations to refine their design and evaluate their performance under dynamic flow and load conditions. To model anaerobic digestion (AD) within plant-wide WWTP models, not only COD and nitrogen (N) but also carbon (C) fluxes entering the AD need to be defined. Current plant-wide models, like benchmark simulation model No 2 (BSM2), impose a C flux at the AD influent. In this paper, the COD and N mass balance steady-state models of activated sludge (AS) organics degradation, nitrification and denitrification (ND) and anaerobic (AD) and aerobic (AerD) digestion of wastewater sludge are extended and linked with bioprocess transformation stoichiometry to form C, H, O, N, chemical oxygen demand (COD) and charge mass balance based models so that also C (and H and O) can be tracked through the whole WWTP. By assigning a stoichiometric composition (x, y, z and a in C(x)H(y)O(z)N(a)) to each of the five main influent wastewater organic fractions and ammonia, these, and the products generated from them via the biological processes, are tracked through the WWTP. The model is applied to two theoretical case study WWTPs treating the same raw wastewater (WW) to the same final sludge residual biodegradable COD. It is demonstrated that much useful information can be generated with the relatively simple steady-state models to aid WWTP layout design and track the different products exiting the WWTP via the solid, liquid and gas streams, such as aerobic versus anaerobic digestion of waste activated sludge, N loads in recycle streams, methane production for energy recovery

  8. Evolution of the Digital Society Reveals Balance between Viral and Mass Media Influence

    Directory of Open Access Journals (Sweden)

    Kaj-Kolja Kleineberg

    2014-09-01

    Full Text Available Online social networks (OSNs enable researchers to study the social universe at a previously unattainable scale. The worldwide impact and the necessity to sustain the rapid growth of OSNs emphasize the importance of unraveling the laws governing their evolution. Empirical results show that, unlike many real-world growing networked systems, OSNs follow an intricate path that includes a dynamical percolation transition. In light of these results, we present a quantitative two-parameter model that reproduces the entire topological evolution of a quasi-isolated OSN with unprecedented precision from the birth of the network. This allows us to precisely gauge the fundamental macroscopic and microscopic mechanisms involved. Our findings suggest that the coupling between the real preexisting underlying social structure, a viral spreading mechanism, and mass media influence govern the evolution of OSNs. The empirical validation of our model, on a macroscopic scale, reveals that virality is 4–5 times stronger than mass media influence and, on a microscopic scale, individuals have a higher subscription probability if invited by weaker social contacts, in agreement with the “strength of weak ties” paradigm.

  9. Uncertainty of solute flux estimation in ungauged small streams: potential implications for input-output nutrient mass balances at stream reach scale

    Directory of Open Access Journals (Sweden)

    A. Butturini

    2005-01-01

    Full Text Available Input-output mass balances within stream reaches provide in situ estimates of stream nutrient retention/release under a wide spectrum of hydrological conditions. Providing good estimates of the mass balances for nutrients depends on precise hydrological monitoring and good chemical characterisation of stream water at the input and output ends of the stream reach. There is a need to optimise the hydrological monitoring and the frequencies of water sampling to yield precise annual mass balances, so as to avoid undue cost - high resolution monitoring and subsequent chemical analysis can be labour intensive and costly. In this paper, simulation exercises were performed using a data set created to represent the instantaneous discharge and solute dynamics at the input and output ends of a model stream reach during a one year period. At the output end, stream discharge and water chemistry were monitored continuously, while the input end was assumed to be ungauged; water sampling frequency was changed arbitrarily. Instantaneous discharge at the ungauged sampling point was estimated with an empirical power model linking the discharge to the catchment area (Hooper, 1986. The model thus substitutes for the additional gauge station. Simulations showed that 10 days was the longest chemical sampling interval which could provide reach annual mass balances of acceptable precision. Presently, the relationship between discharge and catchment area is usually assumed to be linear but simulations indicate that small departures from the linearity of this relationship could cause dramatic changes in the mass balance estimations.

  10. The response of surface mass and energy balance of a continental glacier to climate variability, western Qilian Mountains, China

    Science.gov (United States)

    Sun, Weijun; Qin, Xiang; Wang, Yetang; Chen, Jizu; Du, Wentao; Zhang, Tong; Huai, Baojuan

    2017-08-01

    To understand how a continental glacier responds to climate change, it is imperative to quantify the surface energy fluxes and identify factors controlling glacier mass balance using surface energy balance (SEB) model. Light absorbing impurities (LAIs) at the glacial surface can greatly decrease surface albedo and increase glacial melt. An automatic weather station was set up and generated a unique 6-year meteorological dataset for the ablation zone of Laohugou Glacier No. 12. Based on these data, the surface energy budget was calculated and an experiment on the glacial melt process was carried out. The effect of reduced albedo on glacial melting was analyzed. Owing to continuous accumulation of LAIs, the ablation zone had been darkening since 2010. The mean value of surface albedo in melt period (June through September) dropped from 0.52 to 0.43, and the minimum of daily mean value was as small as 0.1. From the records of 2010-2015, keeping the clean ice albedo fixed in the range of 0.3-0.4, LAIs caused an increase of +7.1 to +16 W m-2 of net shortwave radiation and an removal of 1101-2663 mm water equivalent. Calculation with the SEB model showed equivalent increases in glacial melt were obtained by increasing air temperature by 1.3 and 3.2 K, respectively.

  11. Cloud effects on surface energy and mass balance in the ablation area of Brewster Glacier, New Zealand

    Science.gov (United States)

    Conway, J. P.; Cullen, N. J.

    2016-02-01

    The effect of clouds on glacier surface energy balance (SEB) has received increased attention in the last decade, but how clouds interact with other meteorological forcing to influence surface mass balance (SMB) is not as well understood. This paper resolves the SEB and SMB at a site in the ablation zone of Brewster Glacier over a 22-month period, using high-quality radiation data to carefully evaluate SEB terms and define clear-sky and overcast conditions. A fundamental change in glacier SEB in cloudy conditions was driven by increased effective sky emissivity and surface vapour pressure, rather than a minimal change in air temperature and wind speed. During overcast conditions, positive net long-wave radiation and latent heat fluxes allowed melt to be maintained through a much greater length of time compared to clear-sky conditions, and led to similar melt in each sky condition. The sensitivity of SMB to changes in air temperature was greatly enhanced in overcast compared to clear-sky conditions due to more frequent melt and changes in precipitation phase that created a strong albedo feedback. During the spring and autumn seasons, the sensitivity during overcast conditions was strongest. To capture these processes, future attempts to explore glacier-climate interactions should aim to resolve the effects of atmospheric moisture (vapour, cloud, and precipitation) on melt as well as accumulation, through enhanced statistical or physically based methods.

  12. Quantification and reduction of the uncertainty in mass balance models by Monte Carlo analysis of prior data

    Energy Technology Data Exchange (ETDEWEB)

    Lesht, B.M.

    1991-12-31

    The general objective of this workshop is to investigate and discuss methods by which uncertainties in mass balance models for toxics in the Great Lakes may be reduced. As described by the workshop prospectus, this paper is focused on problems of reducing (and quantifying) uncertainty as they relate to ``in situ field observations/system response measurements for the establishment of initial conditions, boundary conditions, calibration/confirmation data sets, and model post-audit data sets.`` I have taken this description to refer not only to the evaluation of uncertainty in the field observations themselves, but also to the uncertainty associated the analyses of in situ observations as they interact in the overall modeling process. Thus, I will be concerned here with quantification and reduction of uncertainty both (1) as they may be applied to descriptions of the system that is being modeled and (2) as they may be associated with model simulations.

  13. Quantification and reduction of the uncertainty in mass balance models by Monte Carlo analysis of prior data

    Energy Technology Data Exchange (ETDEWEB)

    Lesht, B.M.

    1991-01-01

    The general objective of this workshop is to investigate and discuss methods by which uncertainties in mass balance models for toxics in the Great Lakes may be reduced. As described by the workshop prospectus, this paper is focused on problems of reducing (and quantifying) uncertainty as they relate to in situ field observations/system response measurements for the establishment of initial conditions, boundary conditions, calibration/confirmation data sets, and model post-audit data sets.'' I have taken this description to refer not only to the evaluation of uncertainty in the field observations themselves, but also to the uncertainty associated the analyses of in situ observations as they interact in the overall modeling process. Thus, I will be concerned here with quantification and reduction of uncertainty both (1) as they may be applied to descriptions of the system that is being modeled and (2) as they may be associated with model simulations.

  14. A new, high-resolution surface mass balance map of Antarctica (1979-2010) based on regional atmospheric climate modeling

    Science.gov (United States)

    Lenaerts, J. T. M.; van den Broeke, M. R.; van de Berg, W. J.; van Meijgaard, E.; Kuipers Munneke, P.

    2012-02-01

    A new, high resolution (27 km) surface mass balance (SMB) map of the Antarctic ice sheet is presented, based on output of a regional atmospheric climate model that includes snowdrift physics and is forced by the most recent reanalysis data from the European Centre for Medium-Range Weather Forecasts (ECMWF), ERA-Interim (1979-2010). The SMB map confirms high accumulation zones in the western Antarctic Peninsula (>1500 mm y-1) and coastal West Antarctica (>1000 mm y-1), and shows low SMB values in large parts of the interior ice sheet (181 Gt y-1. Snowfall shows modest interannual variability (σ = 114 Gt y-1), but a pronounced seasonal cycle (σ = 30 Gt mo-1), with a winter maximum. The main ablation process is drifting snow sublimation, which also peaks in winter but with little interannual variability (σ = 9 Gt y-1).

  15. Increasing meltwater discharge from the Nuuk region of the Greenland ice sheet and implications for mass balance (1960-2012)

    DEFF Research Database (Denmark)

    van As, Dirk; Langer Andersen, Morten; Petersen, Dorthe

    2014-01-01

    We assess the runoff and surface mass balance (SMB) of the Greenland ice sheet in the Nuuk region (southwest) using output of two regional climate models (RCMs) evaluated by observations. The region encompasses six glaciers that drain into Godthåbsfjord. RCM data (1960-2012) are resampled to a high...... of the marine-terminating glaciers, the region lost 10-20km3w.e. a-1 in 2010-12. If 2010 melting prevails during the remainder of this century, a low-end estimate of sea-level rise of 5mm is expected by 2100 from this relatively small section (2.6%) of the ice sheet alone....

  16. Mass-energy balance analysis for estimation of light energy conversion in an integrated system of biological H2 production

    Directory of Open Access Journals (Sweden)

    A.I. Gavrisheva

    2015-12-01

    Full Text Available The present study investigated an integrated system of biological H2 production, which includes the accumulation of biomass of autotrophic microalgae, dark fermentation of biomass, and photofermentation of the dark fermentation effluent. Particular emphasis was placed on the estimation of the conversion efficiency of light into hydrogen energy at each stage of this system. For this purpose, the mass and energy balance regularities were applied. The efficiency of the energy transformation from light into the microalgal biomass did not exceed 5%. The efficiency of the energy transformation from biomass to biological H2 during the dark fermentation stage stood at about 0.3%. The photofermentation stage using the model fermentation effluent could improve this estimation to 11%, resulting in an overall efficiency 0.55%. Evidently, this scheme is counterproductive for light energy bioconversion due to numerous intermediate steps even if the best published data would be taken into account.

  17. Brief Communication: Upper Air Relaxation in RACMO2 Significantly Improves Modelled Interannual Surface Mass Balance Variability in Antarctica

    Science.gov (United States)

    van de Berg, W. J.; Medley, B.

    2016-01-01

    The Regional Atmospheric Climate Model (RACMO2) has been a powerful tool for improving surface mass balance (SMB) estimates from GCMs or reanalyses. However, new yearly SMB observations for West Antarctica show that the modelled interannual variability in SMB is poorly simulated by RACMO2, in contrast to ERA-Interim, which resolves this variability well. In an attempt to remedy RACMO2 performance, we included additional upper-air relaxation (UAR) in RACMO2. With UAR, the correlation to observations is similar for RACMO2 and ERA-Interim. The spatial SMB patterns and ice-sheet-integrated SMB modelled using UAR remain very similar to the estimates of RACMO2 without UAR. We only observe an upstream smoothing of precipitation in regions with very steep topography like the Antarctic Peninsula. We conclude that UAR is a useful improvement for regional climate model simulations, although results in regions with steep topography should be treated with care.

  18. Boundary-layer isotope dilution/mass balance methods for measurement of nocturnal methane emissions from grazing sheep

    Science.gov (United States)

    Harvey, M. J.; Brailsford, G. W.; Bromley, A. M.; Lassey, K. R.; Mei, Z.; Kristament, I. S.; Reisinger, A. R.; Walker, C. F.; Kelliher, F. M.

    Following advances with methods for 13C/ 12C isotopic analysis of methane in small (⩽4 L) air samples, new isotope dilution techniques are proposed for measurement of methane emissions at the paddock scale from grazing ruminant animals. These techniques combine measurement of the isotopic δ13CH 4 composition of air samples with a non-intrusive mass balance method applied in the nocturnal boundary layer. Flux estimates from trials using the isotope dilution techniques are compared with estimates based on scaling up individual animal emission measurements using a rumen gas tracer technique. The methane flux assessed by the latter technique ranged from 35 to 70 mg (CH 4) m -2 d -1 with a stocking density between 10 and 20 sheep ha -1. The isotope dilution based nocturnal boundary-layer estimates generally agreed to better than a factor of 2 and usually to within 20% of the average of individual animal emission rate per unit area of paddock. Both static and advecting mass balance methods are developed. In the advecting case, the upwind/downwind contrast in δ13C was typically 0.2-0.5‰. Care was necessary with air sampling to avoid error in this small contrast contributing to error in the flux. Agreement between concentration- and isotope-based nocturnal boundary layer methods and the sheep breath measurements indicated that sample representativeness was generally good. Factors which affect the accuracy of the method are examined and include variability in nocturnal mixing height, the assumed δ13CH 4 composition of the source sheep breath and diurnal patterns in sheep emission. This paper establishes new techniques useful in the paddock to landscape scale although widespread application awaits further development of technology for rapid and repeatable field analysis of δ13CH 4 in small samples.

  19. Fine particle sources and cardiorespiratory morbidity: an application of chemical mass balance and factor analytical source-apportionment methods.

    Science.gov (United States)

    Sarnat, Jeremy A; Marmur, Amit; Klein, Mitchel; Kim, Eugene; Russell, Armistead G; Sarnat, Stefanie E; Mulholland, James A; Hopke, Philip K; Tolbert, Paige E

    2008-04-01

    Interest in the health effects of particulate matter (PM) has focused on identifying sources of PM, including biomass burning, power plants, and gasoline and diesel emissions that may be associated with adverse health risks. Few epidemiologic studies, however, have included source-apportionment estimates in their examinations of PM health effects. We analyzed a time-series of chemically speciated PM measurements in Atlanta, Georgia, and conducted an epidemiologic analysis using data from three distinct source-apportionment methods. The key objective of this analysis was to compare epidemiologic findings generated using both factor analysis and mass balance source-apportionment methods. We analyzed data collected between November 1998 and December 2002 using positive-matrix factorization (PMF), modified chemical mass balance (CMB-LGO), and a tracer approach. Emergency department (ED) visits for a combined cardiovascular (CVD) and respiratory disease (RD) group were assessed as end points. We estimated the risk ratio (RR) associated with same day PM concentrations using Poisson generalized linear models. There were significant, positive associations between same-day PM(2.5) (PM with aero-dynamic diameter surrogates of the source-apportioned PM(2.5) values. Despite differences among the source-apportionment methods, these findings suggest that modeled source-apportioned data can produce robust estimates of acute health risk. In Atlanta, there were consistent associations across methods between PM(2.5) from mobile sources and biomass burning with both cardiovascular and respiratory ED visits, and between sulfate-rich secondary PM(2.5) with respiratory visits.

  20. Three-Dimensional Structure and Energy Balance of a Coronal Mass Ejection

    Science.gov (United States)

    Lee, J.-Y.; Raymond, J. C.; Ko, Y.-K.; Kim, K.-S.

    2009-01-01

    UVCS observed Doppler-shifted material of a partial halo coronal mass ejection (CME) on 2001 December 13. The observed ratio of [O VJ/O V] is a reliable density diagnostic important for assessing the state of the plasma. Earlier UVCS observations of CMEs found evidence that the ejected plasma is heated long after the eruption. This paper investigated the heating rates, which represent a significant fraction of the CME energy budget. The parameterized heating and radiative and adiabatic cooling have been used to evaluate the temperature evolution of the CME material with a time-dependent ionization state model. Continuous heating is required to match the UVCS observations. To match the O VI bright knots, a higher heating rate is required such that the heating energy is greater than the kinetic energy.

  1. Katabatic winds diminish precipitation contribution to the Antarctic ice mass balance.

    Science.gov (United States)

    Grazioli, Jacopo; Madeleine, Jean-Baptiste; Gallée, Hubert; Forbes, Richard M; Genthon, Christophe; Krinner, Gerhard; Berne, Alexis

    2017-10-10

    Snowfall in Antarctica is a key term of the ice sheet mass budget that influences the sea level at global scale. Over the continental margins, persistent katabatic winds blow all year long and supply the lower troposphere with unsaturated air. We show that this dry air leads to significant low-level sublimation of snowfall. We found using unprecedented data collected over 1 year on the coast of Adélie Land and simulations from different atmospheric models that low-level sublimation accounts for a 17% reduction of total snowfall over the continent and up to 35% on the margins of East Antarctica, significantly affecting satellite-based estimations close to the ground. Our findings suggest that, as climate warming progresses, this process will be enhanced and will limit expected precipitation increases at the ground level.

  2. Katabatic winds diminish precipitation contribution to the Antarctic ice mass balance

    Science.gov (United States)

    Grazioli, Jacopo; Madeleine, Jean-Baptiste; Gallée, Hubert; Forbes, Richard M.; Genthon, Christophe; Krinner, Gerhard; Berne, Alexis

    2017-10-01

    Snowfall in Antarctica is a key term of the ice sheet mass budget that influences the sea level at global scale. Over the continental margins, persistent katabatic winds blow all year long and supply the lower troposphere with unsaturated air. We show that this dry air leads to significant low-level sublimation of snowfall. We found using unprecedented data collected over 1 year on the coast of Adélie Land and simulations from different atmospheric models that low-level sublimation accounts for a 17% reduction of total snowfall over the continent and up to 35% on the margins of East Antarctica, significantly affecting satellite-based estimations close to the ground. Our findings suggest that, as climate warming progresses, this process will be enhanced and will limit expected precipitation increases at the ground level.

  3. Reanalysis of a 10-year record (2004-2013) of seasonal mass balances at Langenferner/Vedretta Lunga, Ortler Alps, Italy

    Science.gov (United States)

    Galos, Stephan Peter; Klug, Christoph; Maussion, Fabien; Covi, Federico; Nicholson, Lindsey; Rieg, Lorenzo; Gurgiser, Wolfgang; Mölg, Thomas; Kaser, Georg

    2017-06-01

    Records of glacier mass balance represent important data in climate science and their uncertainties affect calculations of sea level rise and other societally relevant environmental projections. In order to reduce and quantify uncertainties in mass balance series obtained by direct glaciological measurements, we present a detailed reanalysis workflow which was applied to the 10-year record (2004 to 2013) of seasonal mass balance of Langenferner, a small glacier in the European Eastern Alps. The approach involves a methodological homogenization of available point values and the creation of pseudo-observations of point mass balance for years and locations without measurements by the application of a process-based model constrained by snow line observations. We examine the uncertainties related to the extrapolation of point data using a variety of methods and consequently present a more rigorous uncertainty assessment than is usually reported in the literature. Results reveal that the reanalyzed balance record considerably differs from the original one mainly for the first half of the observation period. For annual balances these misfits reach the order of > 300 kg m-2 and could primarily be attributed to a lack of measurements in the upper glacier part and to the use of outdated glacier outlines. For winter balances respective differences are smaller (up to 233 kg m-2) and they originate primarily from methodological inhomogeneities in the original series. Remaining random uncertainties in the reanalyzed series are mainly determined by the extrapolation of point data to the glacier scale and are on the order of ±79 kg m-2 for annual and ±52 kg m-2 for winter balances with values for single years/seasons reaching ±136 kg m-2. A comparison of the glaciological results to those obtained by the geodetic method for the period 2005 to 2013 based on airborne laser-scanning data reveals that no significant bias of the reanalyzed record is detectable.

  4. Mass balance and life cycle assessment of the waste electrical and electronic equipment management system implemented in Lombardia Region (Italy)

    Energy Technology Data Exchange (ETDEWEB)

    Biganzoli, L., E-mail: laura.biganzoli@mail.polimi.it; Falbo, A.; Forte, F.; Grosso, M.; Rigamonti, L.

    2015-08-15

    Waste electrical and electronic equipment (WEEE) is one of the fastest growing waste streams in Europe, whose content of hazardous substances as well as of valuable materials makes the study of the different management options particularly interesting. The present study investigates the WEEE management system in Lombardia Region (Italy) in the year 2011 by applying the life cycle assessment (LCA) methodology. An extensive collection of primary data was carried out to describe the main outputs and the energy consumptions of the treatment plants. Afterwards, the benefits and burdens associated with the treatment and recovery of each of the five categories in which WEEE is classified according to the Italian legislation (heaters and refrigerators — R1, large household appliances — R2, TV and monitors — R3, small household appliances — R4 and lighting equipment — R5) were evaluated. The mass balance of the treatment and recovery system of each of the five WEEE categories showed that steel and glass are the predominant streams of materials arising from the treatment; a non-negligible amount of plastic is also recovered, together with small amounts of precious metals. The LCA of the regional WEEE management system showed that the benefits associated with materials and energy recovery balance the burdens of the treatment processes, with the sole exception of two impact categories (human toxicity-cancer effects and freshwater ecotoxicity). The WEEE categories whose treatment and recovery resulted more beneficial for the environment and the human health are R3 and R5. The contribution analysis showed that overall the main benefits are associated with the recovery of metals, as well as of plastic and glass. Some suggestions for improving the performance of the system are given, as well as an indication for a more-in-depth analysis for the toxicity categories and a proposal for a new characterisation method for WEEE. - Highlights: • The WEEE management system in

  5. Fundamental and methodological investigations for the improvement of elemental analysis by inductively coupled plasma mass soectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Ebert, Christopher Hysjulien [Ames Lab., Ames, IA (United States)

    2012-01-01

    This dissertation describes a variety of studies meant to improve the analytical performance of inductively coupled plasma mass spectrometry (ICP-MS) and laser ablation (LA) ICP-MS. The emission behavior of individual droplets and LA generated particles in an ICP is studied using a high-speed, high frame rate digital camera. Phenomena are observed during the ablation of silicate glass that would cause elemental fractionation during analysis by ICP-MS. Preliminary work for ICP torch developments specifically tailored for the improvement of LA sample introduction are presented. An abnormal scarcity of metal-argon polyatomic ions (MAr{sup +}) is observed during ICP-MS analysis. Evidence shows that MAr{sup +} ions are dissociated by collisions with background gas in a shockwave near the tip of the skimmer cone. Method development towards the improvement of LA-ICP-MS for environmental monitoring is described. A method is developed to trap small particles in a collodion matrix and analyze each particle individually by LA-ICP-MS.

  6. MASS BALANCE CHANGES AND ICE DYNAMICS OF GREENLAND AND ANTARCTIC ICE SHEETS FROM LASER ALTIMETRY

    Directory of Open Access Journals (Sweden)

    G. S. Babonis

    2016-06-01

    Full Text Available During the past few decades the Greenland and Antarctic ice sheets have lost ice at accelerating rates, caused by increasing surface temperature. The melting of the two big ice sheets has a big impact on global sea level rise. If the ice sheets would melt down entirely, the sea level would rise more than 60 m. Even a much smaller rise would cause dramatic damage along coastal regions. In this paper we report about a major upgrade of surface elevation changes derived from laser altimetry data, acquired by NASA’s Ice, Cloud and land Elevation Satellite mission (ICESat and airborne laser campaigns, such as Airborne Topographic Mapper (ATM and Land, Vegetation and Ice Sensor (LVIS. For detecting changes in ice sheet elevations we have developed the Surface Elevation Reconstruction And Change detection (SERAC method. It computes elevation changes of small surface patches by keeping the surface shape constant and considering the absolute values as surface elevations. We report about important upgrades of earlier results, for example the inclusion of local ice caps and the temporal extension from 1993 to 2014 for the Greenland Ice Sheet and for a comprehensive reconstruction of ice thickness and mass changes for the Antarctic Ice Sheets.

  7. Textile protection of snow and ice: Measured and simulated effects on the energy- and mass balance

    Science.gov (United States)

    Olefs, Marc; Lehning, Michael

    2010-05-01

    Measurements and simulations of the energy fluxes and mass changes of an artificially covered snow and ice surface (geotextile material) and a reference plot within an Austrian glacier ski resort are presented and compared. A modified version of the snow cover model SNOWPACK is used to successfully reproduce the artificially compacted and the additionally covered snow cover in a physically based way. Supplementary measurements of crucial material properties of the 0.0045 m thin geotextile serve as model input as well. Results indicate that the shortwave reflectivity of the covers is responsible for half the performance (47%). Thermal insulation of the material (14%) and a negative latent heat flux due to evaporation of precipitation from the cover surface (10%) have almost the same contribution. An assumed layer of air between the cover and the snow and ice surface (thickness 0.075 m to 0.12 m) adds the rest, which is at the upper limit of observations and may therefore also compensate for model errors. This generally explains the high performance of the method in glacier skiing resorts and, most importantly, an altitude dependant application limit of the method: the method becomes less effective at lower altitudes, where sensible heat fluxes become more important compared to short wave radiation.

  8. Paleohydrology on Mars constrained by mass balance and mineralogy of pre-Amazonian sodium chloride lakes

    Science.gov (United States)

    Melwani Daswani, M.; Kite, E. S.

    2017-09-01

    Chloride-bearing deposits on Mars record high-elevation lakes during the waning stages of Mars' wet era (mid-Noachian to late Hesperian). The water source pathways, seasonality, salinity, depth, lifetime, and paleoclimatic drivers of these widespread lakes are all unknown. Here we combine reaction-transport modeling, orbital spectroscopy, and new volume estimates from high-resolution digital terrain models, in order to constrain the hydrologic boundary conditions for forming the chlorides. Considering a T = 0°C system, we find that (1) individual lakes were >100 m deep and lasted decades or longer; (2) if volcanic degassing was the source of chlorine, then the water-to-rock ratio or the total water volume were probably low, consistent with brief excursions above the melting point and/or arid climate; (3) if the chlorine source was igneous chlorapatite, then Cl-leaching events would require a (cumulative) time of >10 years at the melting point; and (4) Cl masses, divided by catchment area, give column densities 0.1-50 kg Cl/m2, and these column densities bracket the expected chlorapatite-Cl content for a seasonally warm active layer. Deep groundwater was not required. Taken together, our results are consistent with Mars having a usually cold, horizontally segregated hydrosphere by the time chlorides formed.

  9. Annual and Seasonal Glacier-Wide Surface Mass Balance Quantified from Changes in Glacier Surface State: A Review on Existing Methods Using Optical Satellite Imagery

    Directory of Open Access Journals (Sweden)

    Antoine Rabatel

    2017-05-01

    Full Text Available Glaciers are one of the terrestrial essential climate variables (ECVs as they respond very sensitively to climate change. A key driver of their response is the glacier surface mass balance that is typically derived from field measurements. It deserves to be quantified over long time scales to better understand the accumulation and ablation processes at the glacier surface and their relationships with inter-annual changes in meteorological conditions and long-term climate changes. Glaciers with in situ monitoring of surface mass balance are scarce at the global scale, and satellite remote sensing provides a powerful tool to increase the number of monitored glaciers. In this study, we present a review of three optical remote sensing methods developed to quantify seasonal and annual glacier surface mass balances. These methodologies rely on the multitemporal monitoring of the end-of-summer snow line for the equilibrium-line altitude (ELA method, the annual cycle of glacier surface albedo for the albedo method and the mapping of the regional snow cover at the seasonal scale for the snow-map method. Together with a presentation of each method, an application is illustrated. The ELA method shows promising results to quantify annual surface mass balance and to reconstruct multi-decadal time series. The other two methods currently need a calibration on the basis of existing in situ data; however, a generalization of these methods (without calibration could be achieved. The two latter methods show satisfying results at the annual and seasonal scales, particularly for the summer surface mass balance in the case of the albedo method and for the winter surface mass balance in the case of the snow-map method. The limits of each method (e.g., cloud coverage, debris-covered glaciers, monsoon-regime and cold glaciers, their complementarities and the future challenges (e.g., automating of the satellite images processing, generalization of the methods needing

  10. Mass balance evaluation of polybrominated diphenyl ethers in landfill leachate and potential for transfer from e-waste.

    Science.gov (United States)

    Danon-Schaffer, Monica N; Mahecha-Botero, Andrés; Grace, John R; Ikonomou, Michael

    2013-09-01

    Previous research on brominated flame retardants (BFRs), including polybrominated diphenyl ethers (PBDEs) has largely focussed on their concentrations in the environment and their adverse effects on human health. This paper explores their transfer from waste streams to water and soil. A comprehensive mass balance model is developed to track polybrominated diphenyl ethers (PBDEs), originating from e-waste and non-e-waste solids leaching from a landfill. Stepwise debromination is assumed to occur in three sub-systems (e-waste, aqueous leachate phase, and non-e-waste solids). Analysis of landfill samples and laboratory results from a solid-liquid contacting chamber are used to estimate model parameters to simulate an urban landfill system, for past and future scenarios. Sensitivity tests to key model parameters were conducted. Lower BDEs require more time to disappear than high-molecular weight PBDEs, since debromination takes place in a stepwise manner, according to the simplified reaction scheme. Interphase mass transfer causes the decay pattern to be similar in all three sub-systems. The aqueous phase is predicted to be the first sub-system to eliminate PBDEs if their input to the landfill were to be stopped. The non-e-waste solids would be next, followed by the e-waste sub-system. The model shows that mass transfer is not rate-limiting, but the evolution over time depends on the kinetic degradation parameters. Experimental scatter makes model testing difficult. Nevertheless, the model provides qualitative understanding of the influence of key variables. Copyright © 2013 Elsevier B.V. All rights reserved.

  11. Quantifying element incorporation in multispecies biofilms using nanoscale secondary ion mass spectrometry image analysis

    Energy Technology Data Exchange (ETDEWEB)

    Renslow, Ryan S. [Biological Sciences Division, Earth and Biological Sciences Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99354; Lindemann, Stephen R. [Biological Sciences Division, Earth and Biological Sciences Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99354; Cole, Jessica K. [Biological Sciences Division, Earth and Biological Sciences Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99354; Zhu, Zihua [Environmental Molecular Sciences Laboratory, Earth and Biological Sciences Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99354; Anderton, Christopher R. [Environmental Molecular Sciences Laboratory, Earth and Biological Sciences Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99354

    2016-02-12

    EElucidating nutrient exchange in microbial communities is an important step in understanding the relationships between microbial systems and global biogeochemical cycles, but these communities are complex and the interspecies interactions that occur within them are not well understood. Phototrophic consortia are useful and relevant experimental systems to investigate such interactions as they are not only prevalent in the environment, but some are cultivable in vivo and amenable to controlled scientific experimentation. High spatial resolution secondary ion mass spectrometry (NanoSIMS) is a powerful tool capable of visualizing the metabolic activities of single cells within a biofilm, but quantitative analysis of the resulting data has typically been a manual process, resulting in a task that is both laborious and susceptible to human error. Here, we describe the creation and application of a semi-automated image-processing pipeline that can analyze NanoSIMS-generated data of phototrophic biofilms. The tool employs an image analysis process, which includes both elemental and morphological segmentation, producing a final segmented image that allows for discrimination between autotrophic and heterotrophic biomass, the detection of individual cyanobacterial filaments and heterotrophic cells, the quantification of isotopic incorporation of individual heterotrophic cells, and calculation of relevant population statistics. We demonstrate the functionality of the tool by using it to analyze the uptake of 15N provided as either nitrate or ammonium through the unicyanobacterial consortium UCC-O and imaged via NanoSIMS. We found that the degree of 15N incorporation by individual cells was highly variable when labeled with 15NH4 +, but much more even when biofilms were labeled with 15NO3-. In the 15NH4 +-amended biofilms, the heterotrophic distribution of 15N incorporation was highly skewed, with a large population showing moderate 15N incorporation and a small number of

  12. Mass balance and life cycle assessment of the waste electrical and electronic equipment management system implemented in Lombardia Region (Italy).

    Science.gov (United States)

    Biganzoli, L; Falbo, A; Forte, F; Grosso, M; Rigamonti, L

    2015-08-15

    Waste electrical and electronic equipment (WEEE) is one of the fastest growing waste streams in Europe, whose content of hazardous substances as well as of valuable materials makes the study of the different management options particularly interesting. The present study investigates the WEEE management system in Lombardia Region (Italy) in the year 2011 by applying the life cycle assessment (LCA) methodology. An extensive collection of primary data was carried out to describe the main outputs and the energy consumptions of the treatment plants. Afterwards, the benefits and burdens associated with the treatment and recovery of each of the five categories in which WEEE is classified according to the Italian legislation (heaters and refrigerators - R1, large household appliances - R2, TV and monitors - R3, small household appliances - R4 and lighting equipment - R5) were evaluated. The mass balance of the treatment and recovery system of each of the five WEEE categories showed that steel and glass are the predominant streams of materials arising from the treatment; a non-negligible amount of plastic is also recovered, together with small amounts of precious metals. The LCA of the regional WEEE management system showed that the benefits associated with materials and energy recovery balance the burdens of the treatment processes, with the sole exception of two impact categories (human toxicity-cancer effects and freshwater ecotoxicity). The WEEE categories whose treatment and recovery resulted more beneficial for the environment and the human health are R3 and R5. The contribution analysis showed that overall the main benefits are associated with the recovery of metals, as well as of plastic and glass. Some suggestions for improving the performance of the system are given, as well as an indication for a more-in-depth analysis for the toxicity categories and a proposal for a new characterisation method for WEEE. Copyright © 2015 Elsevier B.V. All rights reserved.

  13. The potential of sedimentary foraminiferal rare earth element patterns to trace water masses in the past

    Science.gov (United States)

    Osborne, Anne H.; Hathorne, Ed C.; Schijf, Johan; Plancherel, Yves; Böning, Philipp; Frank, Martin

    2017-04-01

    Dissolved rare earth element (REE) concentration data from intermediate and deep seawater form an array characterized by higher middle-REE enrichments (MREE/MREE*) in the North Atlantic and a progressive increase in heavy-to-light REE ratios (HREE/LREE) as water masses age. The REEs in foraminifera are fractionated toward higher MREE/MREE* and lower HREE/LREE relative to seawater. Calculations based on a scavenging model show that the REE patterns in uncleaned core-top foraminifera resemble those adsorbed onto calcite, particulate organic material, and hydrous ferric oxides but the full extent of the REE fractionation measured in foraminifera was not reproduced by the model. However, differences in the HREE/LREE and MREE/MREE* ratios and the cerium anomaly between ocean basins are preserved and are in agreement with the seawater REE distribution. Under oxic conditions, the HREE/LREE and MREE/MREE* compositions of uncleaned foraminifera at the sediment/seawater boundary are preserved during burial but the cerium anomaly is sensitive to burial depth. In suboxic sedimentary environments, all uncleaned foraminiferal REE concentrations are elevated relative to core-top values indicating addition of REEs from pore waters. The HREE/LREE ratio is highest when sedimentation rates were greatest and when high Fe/Ca ratios in the uncleaned foraminifera indicate that Fe was mobile. In sediments that have not experienced suboxic conditions during burial, uncleaned foraminifera preserve the seawater signal taken up at the sediment/seawater interface and are therefore suggested to be a suitable archive of changes in the REE signal of past bottom waters.

  14. Catchment conceptualisation for examining applicability of chloride mass balance method in an area with historical forest clearance

    Directory of Open Access Journals (Sweden)

    H. Guan

    2010-07-01

    Full Text Available Of the various approaches for estimating groundwater recharge, the chloride mass balance (CMB method is one of the most frequently used, especially for arid and semiarid regions. Widespread native vegetation clearance, common in many areas globally, has changed the land surface boundary condition, posing the question as to whether the current system has reached new chloride equilibrium, required for a CMB application. Although a one-dimensional CMB can be applied at a point where the water and chloride fluxes are locally in steady state, the CMB method is usually applied at a catchment scale owing to significant lateral flows in mountains. The applicability of the CMB method to several conceptual catchment types of various chloride equilibrium conditions is examined. The conceptualisation, combined with some local climate conditions, is shown to be useful in assessing whether or not a catchment has reached new chloride equilibrium. The six conceptual catchment types are tested with eleven selected catchments in the Mount Lofty Ranges (MLR, a coastal hilly area in South Australia having experienced widespread historical forest clearance. The results show that six of the eleven catchments match a type VI chloride balance condition (chloride non-equilibrium with a gaining stream, with the ratios of stream chloride output (O over atmospheric chloride input (I, or catchment chloride O/I ratios, ranging from 2 to 4. Two catchments match a type V chloride balance condition (chloride non-equilibrium with a losing stream, with catchment chloride O/I ratios about 0.5. For these type V and type VI catchments, the CMB method is not applicable. The results also suggest that neither a chloride O/I ratio less than one nor a low seasonal fluctuation of streamflow chloride concentration (a factor below 4 guarantees a chloride equilibrium condition in the study area. A large chloride O/I value (above one and a large fluctuation of streamflow chloride

  15. Optimal hydrograph separation using a recursive digital filter constrained by chemical mass balance, with application to selected Chesapeake Bay watersheds

    Science.gov (United States)

    Raffensperger, Jeff P.; Baker, Anna C.; Blomquist, Joel D.; Hopple, Jessica A.

    2017-06-26

    Quantitative estimates of base flow are necessary to address questions concerning the vulnerability and response of the Nation’s water supply to natural and human-induced change in environmental conditions. An objective of the U.S. Geological Survey National Water-Quality Assessment Project is to determine how hydrologic systems are affected by watershed characteristics, including land use, land cover, water use, climate, and natural characteristics (geology, soil type, and topography). An important component of any hydrologic system is base flow, generally described as the part of streamflow that is sustained between precipitation events, fed to stream channels by delayed (usually subsurface) pathways, and more specifically as the volumetric discharge of water, estimated at a measurement site or gage at the watershed scale, which represents groundwater that discharges directly or indirectly to stream reaches and is then routed to the measurement point.Hydrograph separation using a recursive digital filter was applied to 225 sites in the Chesapeake Bay watershed. The recursive digital filter was chosen for the following reasons: it is based in part on the assumption that groundwater acts as a linear reservoir, and so has a physical basis; it has only two adjustable parameters (alpha, obtained directly from recession analysis, and beta, the maximum value of the base-flow index that can be modeled by the filter), which can be determined objectively and with the same physical basis of groundwater reservoir linearity, or that can be optimized by applying a chemical-mass-balance constraint. Base-flow estimates from the recursive digital filter were compared with those from five other hydrograph-separation methods with respect to two metrics: the long-term average fraction of streamflow that is base flow, or base-flow index, and the fraction of days where streamflow is entirely base flow. There was generally good correlation between the methods, with some biased

  16. Metabolomic database annotations via query of elemental compositions: Mass accuracy is insufficient even at less than 1 ppm

    Directory of Open Access Journals (Sweden)

    Fiehn Oliver

    2006-04-01

    Full Text Available Abstract Background Metabolomic studies are targeted at identifying and quantifying all metabolites in a given biological context. Among the tools used for metabolomic research, mass spectrometry is one of the most powerful tools. However, metabolomics by mass spectrometry always reveals a high number of unknown compounds which complicate in depth mechanistic or biochemical understanding. In principle, mass spectrometry can be utilized within strategies of de novo structure elucidation of small molecules, starting with the computation of the elemental composition of an unknown metabolite using accurate masses with errors Results High mass accuracy (95% of false candidates. This orthogonal filter can condense several thousand candidates down to only a small number of molecular formulas. Example calculations for 10, 5, 3, 1 and 0.1 ppm mass accuracy are given. Corresponding software scripts can be downloaded from http://fiehnlab.ucdavis.edu. A comparison of eight chemical databases revealed that PubChem and the Dictionary of Natural Products can be recommended for automatic queries using molecular formulae. Conclusion More than 1.6 million molecular formulae in the range 0–500 Da were generated in an exhaustive manner under strict observation of mathematical and chemical rules. Assuming that ion species are fully resolved (either by chromatography or by high resolution mass spectrometry, we conclude that a mass spectrometer capable of 3 ppm mass accuracy and 2% error for isotopic abundance patterns outperforms mass spectrometers with less than 1 ppm mass accuracy or even hypothetical mass spectrometers with 0.1 ppm mass accuracy that do not include isotope information in the calculation of molecular formulae.

  17. The influence of air temperature inversions on snowmelt and glacier mass-balance simulations, Ammassalik island, SE Greenland

    Energy Technology Data Exchange (ETDEWEB)

    Mernild, Sebastian Haugard [Los Alamos National Laboratory; Liston, Glen [COLORADO STATE UNIV.

    2009-01-01

    In many applications, a realistic description of air temperature inversions is essential for accurate snow and glacier ice melt, and glacier mass-balance simulations. A physically based snow-evolution modeling system (SnowModel) was used to simulate eight years (1998/99 to 2005/06) of snow accumulation and snow and glacier ice ablation from numerous small coastal marginal glaciers on the SW-part of Ammassalik Island in SE Greenland. These glaciers are regularly influenced by inversions and sea breezes associated with the adjacent relatively low temperature and frequently ice-choked fjords and ocean. To account for the influence of these inversions on the spatiotemporal variation of air temperature and snow and glacier melt rates, temperature inversion routines were added to MircoMet, the meteorological distribution sub-model used in SnowModel. The inversions were observed and modeled to occur during 84% of the simulation period. Modeled inversions were defined not to occur during days with strong winds and high precipitation rates due to the potential of inversion break-up. Field observations showed inversions to extend from sea level to approximately 300 m a.s.l., and this inversion level was prescribed in the model simulations. Simulations with and without the inversion routines were compared. The inversion model produced air temperature distributions with warmer lower elevation areas and cooler higher elevation areas than without inversion routines due to the use of cold sea-breeze base temperature data from underneath the inversion. This yielded an up to 2 weeks earlier snowmelt in the lower areas and up to 1 to 3 weeks later snowmelt in the higher elevation areas of the simulation domain. Averaged mean annual modeled surface mass-balance for all glaciers (mainly located above the inversion layer) was -720 {+-} 620 mm w.eq. y{sup -1} for inversion simulations, and -880 {+-} 620 mm w.eq. y{sup -1} without the inversion routines, a difference of 160 mm w.eq. y

  18. Origin of CaCl2 brines by basalt-seawater interaction: Insights provided by some simple mass balance calculations

    Science.gov (United States)

    Hardie, Lawrence A.

    1983-06-01

    Modern rift zone hydrothermal brines are typically CaCl2-bearing brines, an unusual chemical signature they share with certain oil field brines, fluid inclusions in ore minerals and a few uncommon saline lakes. Many origins have been suggested for such CaCl2 brines but in the Reykjanes, Iceland, geothermal system a strong empirical case can be made for a basalt-seawater interaction origin. To examine this mechanism of CaCl2 brine evolution some simple mass balance calculations were carried out. Average Reykjanes olivine tholeiite was “reacted” with average North Atlantic seawater to make an albite-chlorite-epidotesphene rock using Al2O3 as the conservative rock component and Cl as the conservative fluid component. The excess components released by the basalt to the fluid were “precipitated” at 275° C as quartz, calcite, anhydrite, magnetite and pyrite to complete the conversion to greenstone. The resulting fluid was a CaCl2 brine of seawater chlorinity with a composition remarkably similar to the actual Reykjanes brine at 1750 m depth. Thus, the calculations strongly support the idea that the Reykjanes CaCl2 brines result from “closed system” oceanic basalt-seawater interaction (albitization — chloritization mechanism) at greenschist facies temperatures. The calculation gives a seawater: basalt mass ratio of 3∶1 to 4∶1 (vol. ratio of 9∶1 to 12∶1), in keeping with experimental results, submarine vent data and with ocean crust cooling calculations. The brine becomes anoxic because there is insufficient dissolved or combined oxygen to balance all the Fe released from the basalt during alteration. Large excesses of Ca are released to the fluid and precipitate out in the form of anhydrite which essentially sweeps the brine free of sulfate leaving an elevated Ca concentration. The calculated rock-water interaction basically involves Na + Mg + SO4 ⇌ Ca + K, simulating chemical differences observed between oceanic basalts and greenstones from many

  19. Evaluation of Primary Production in the Lower Amazon River Based on a Dissolved Oxygen Stable Isotopic Mass Balance

    Energy Technology Data Exchange (ETDEWEB)

    Gagne-Maynard, William C.; Ward, Nicholas D.; Keil, Richard G.; Sawakuchi, Henrique O.; Da Cunha, Alan C.; Neu, Vania; Brito, Daimio C.; Da Silva Less, Diani F.; Diniz, Joel E. M.; De Matos Valerio, Aline; Kampel, Milton; Krusche, Alex V.; Richey, Jeffrey E.

    2017-02-07

    The Amazon River outgasses nearly an equivalent amount of CO2 as the rainforest sequesters on an annual basis due to microbial decomposition of terrigenous and aquatic organic matter. Most research performed in the Amazon has been focused on unraveling the mechanisms driving CO2 production since the recognition of a persistent state of CO2 supersaturation. However, although the river system is clearly net heterotrophic, the interplay between primary production and respiration is an essential aspect to understanding the overall metabolism of the ecosystem and potential transfer of energy up trophic levels. For example, an efficient ecosystem is capable of both decomposing high amounts of organic matter at lower trophic levels, driving CO2 emissions, and accumulating energy/biomass in higher trophic levels, stimulating fisheries production. Early studies found minimal evidence for primary production in the Amazon River mainstem and it has since been assumed that photosynthesis is strongly limited by low light penetration attributed to the high sediment load. Here, we test this assumption by measuring the stable isotopic composition of O218O-O2) and O2 saturation levels in the lower Amazon River from Óbidos to the river mouth and its major tributaries, the Xingu and Tapajós rivers, during high and low water periods. An oxygen mass balance model was developed to estimate the input of photosynthetic oxygen in the discrete reach from Óbidos to Almeirim, midway to the river mouth. Based on the oxygen mass balance we estimate that primary production occurred at a rate of 0.39 ± 0.24 g O m3 d-1 at high water and 1.02 ± 0.55 g O m3 d-1 at low water. This translates to 41 ± 24% of the rate of O2 drawdown via respiration during high water and 67 ± 33% during low water. These primary production rates are 2-7 times higher than

  20. Simulating the mass- and energy balance of Freya Glacier (NE-Greenland) using the physically based snow model AMUNDSEN

    Science.gov (United States)

    Marke, T.; Plach, A.; Hanzer, F.; Strasser, U.; Hynek, B.; Weyss, G.; Schöner, W.

    2012-04-01

    Climate change will increasingly influence terrestrial and aquatic ecosystems in many regions all over the world. The arctic environment is known to be both, particularly affected and extremely sensitive to changes in the earth's climate system. An increase in temperature, which may be accompanied by an increase in precipitation as predicted for some regions in northeast Greenland over the next 100 years, severely affects the temporal storage of water in the snowpack in winter and the melting of snow and ice masses in spring and summer. Increased precipitation in combination with an increase in snow/ice melt results in an increased influx of freshwater and sediment to the oceans contributing to sea level rise and affecting the the thermohaline circulation in the sea surrounding Greenland. Besides the snow/ice reaction on changing climate conditions, the presence of snow/ice feeds back on the climate system itself. To analyze ongoing changes in arctic ecosystems numerical models represent a valuable supplementary source of information to sparsely available field measurements as they are capable to deliver spatially distributed and detailed knowledge on meteorological and hydrological conditions in arctic areas. The FreyEx project continues research that has been initiated in the framework of the preceding projekt GlacierMEMO by using the distributed snow/ice model AMUNDSEN to simulate snow accumulation, distribution, sublimation and surface melt at Freya Glacier, a small valley glacier in the north of Clavering Island (NE-Greenland). The results of GlacierMEMO have indicated a strong need for i) additional meteorological data in the area of interest and ii) a modification of the standard method implemented for the remapping of meteorological parameters in AMUNDSEN. To close these gaps, in the framework of the project FreyEx, an additional energy balance station has been installed on Freya Glacier. The remapping algorithms, particularly that for the interpolation of

  1. Elemental Bioimaging by Means of Fast Scanning Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry

    National Research Council Canada - National Science Library

    Wehe, Christoph A; Thyssen, Georgina M; Herdering, Christina; Raj, Indra; Ciarimboli, Giuliano; Sperling, Michael; Karst, Uwe

    2015-01-01

    .... While most studies deal with the analysis of typically not more than up to 10 isotopes per scan cycle, a fast scanning quadrupole mass analyzer was utilized to record the full mass spectrum of interest in this work...

  2. Inherently balanced 4R four-bar based linkages

    NARCIS (Netherlands)

    van der Wijk, V.; Herder, Justus Laurens; Lenarcis, J.; Husty, M.

    2012-01-01

    Synthesis of mechanisms with their center of mass (CoM) at an invariant point on one of the elements is useful for the design of statically balanced and shaking-force balanced mechanisms and manipulators. For this purpose, a kinematic architecture based on a general 4R four-bar linkage is found by

  3. The impact of a seasonally ice free Arctic Ocean on the temperature, precipitation and surface mass balance of Svalbard

    Directory of Open Access Journals (Sweden)

    J. J. Day

    2012-01-01

    Full Text Available The observed decline in summer sea ice extent since the 1970s is predicted to continue until the Arctic Ocean is seasonally ice free during the 21st Century. This will lead to a much perturbed Arctic climate with large changes in ocean surface energy flux. Svalbard, located on the present day sea ice edge, contains many low lying ice caps and glaciers and is expected to experience rapid warming over the 21st Century. The total sea level rise if all the land ice on Svalbard were to melt completely is 0.02 m.

    The purpose of this study is to quantify the impact of climate change on Svalbard's surface mass balance (SMB and to determine, in particular, what proportion of the projected changes in precipitation and SMB are a result of changes to the Arctic sea ice cover. To investigate this a regional climate model was forced with monthly mean climatologies of sea surface temperature (SST and sea ice concentration for the periods 1961–1990 and 2061–2090 under two emission scenarios. In a novel forcing experiment, 20th Century SSTs and 21st Century sea ice were used to force one simulation to investigate the role of sea ice forcing. This experiment results in a 3.5 m water equivalent increase in Svalbard's SMB compared to the present day. This is because over 50 % of the projected increase in winter precipitation over Svalbard under the A1B emissions scenario is due to an increase in lower atmosphere moisture content associated with evaporation from the ice free ocean. These results indicate that increases in precipitation due to sea ice decline may act to moderate mass loss from Svalbard's glaciers due to future Arctic warming.

  4. Occurrence of UV filter compounds from sunscreens in surface waters: regional mass balance in two Swiss lakes.

    Science.gov (United States)

    Poiger, Thomas; Buser, Hans-Rudolf; Balmer, Marianne E; Bergqvist, Per-Anders; Müller, Markus D

    2004-05-01

    Consumer care products often contain UV filters, organic compounds which absorb ultraviolet light. These compounds may enter surface waters directly (when released from the skin during swimming and bathing) or indirectly via wastewater treatment plants (when released during showering or washed from textiles). Predicted and measured UV filter concentrations were compared in a regional mass balance study for two Swiss lakes: Lake Zurich, a typical midland lake which is also an important drinking water resource, and Hüttnersee, a small bathing lake. Both lakes are extensively used for recreational activities and considerable direct input of UV filters is thus expected. This input was estimated from the number of visitors at swimming areas around the lakes and a survey of the usage of sunscreen products among these visitors. Possible additional indirect input via wastewater treatment plants was not considered in this study. The quantitatively most important UV filters, as indicated by the survey data, ethylhexyl methoxycinnamate, octocrylene, 4-methylbenzylidene camphor, butyl methoxydibenzoylmethane, and benzophenone-3, all lipophilic compounds, were selected for analysis by gas chromatography-mass spectrometry. Concentrations of individual UV filters in water from Lake Zurich were low, ranging from filters assumed to occur during swimming), and (ii) some removal of these compounds from the lakes by degradation and/or sorption/sedimentation. UV filters were also detected in semipermeable membrane devices (SPMDs) deployed at Lake Zurich and Greifensee, another midland lake, at concentrations of 80-950 ng SPMD(-1), confirming the presence of the compounds in surface waters and indicating a certain potential for bioaccumulation. SPMD-derived water concentrations were in the range of 1-10 ng l(-1) and thus corresponded well with those determined in water directly. No UV filters were detected above blank levels in SPMDs deployed at a remote mountain lake used for

  5. Geochemical mass-balance to study the relative weathering rates of various formations in a complex watershed of lower Himalayas

    Science.gov (United States)

    Chattopadhyay, Pallavi; Kar, Swagat; Chouhan, Ramesh

    2017-04-01

    Weathering of rocks is a major process and believed to have the potential to alter Earth's surface. Aglar, a watershed in Garhwal Lesser Himalayas is identified and various formations of this complex geology are studied to understand the weathering process. A stream passes through the fault that divides the watershed into two slopes which have different lithotectonic units. Paligar and Belgar are the two main tributaries of Aglar stream flowing along the slopes respectively and joining at the valley near Thatyur village, India. Rocks like quartzite and limestone are generally hard, massive and resistant to weathering. However, sedimentary rocks are vulnerable to weathering and erosion. On the other hand, phyllites and schists are characterized by flaky minerals which weather quickly and promote instability . Aglar has all of them. The weathering processes are studied first using the hydrochemistry of Aglar river through major cations (Ca2+, Mg2+, Na+, K+) and major anions (SO42-, HCO-3, Cl-, NO3-). The discharges at various sampling points are calculated using area - velocity method. The basic idea in describing the discharge of material in a river is to estimate the mass of the substances transported through a cross section of the river per second. Dominance of Ca2+, Mg2+ and HCO-3 indicates that carbonate weathering is the major chemical weathering process near Belgar river. Paligar river has lower conductivity values compared to Belgar river which illustrates lower ionic concentrations. Mass-balance calculations are found often skewed and suggest the role of subsurface groundwater flow to explain the uncharacterized load. Southern side of the watershed with higher percentage of forest cover is found to have higher chemical weathering rates compared to the other slope having relatively lesser vegetation. These higher rates demonstrate the higher stream discharge load in that slope.

  6. Volume changes of Vatnajökull ice cap, Iceland, due to surface mass balance, ice flow, and subglacial melting at geothermal areas

    DEFF Research Database (Denmark)

    Magnússon, Eyjólfur; Björnson, Helgi; Dall, Jørgen

    2005-01-01

    We present observed changes in the geometry of western Vatnajökull over a period of about ten years which are caused by the surface mass balance, ice flow (both during surges and quiescent periods), and basal melting due to geothermal and volcanic activity. Comparison of two digital elevation...

  7. Future surface mass balance of the Antarctic ice sheet and its influence on sea level change, simulated by a regional atmospheric climate model

    NARCIS (Netherlands)

    Ligtenberg, S.R.M.|info:eu-repo/dai/nl/32821177X; van de Berg, W.J.|info:eu-repo/dai/nl/304831611; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643; Rae, J.G.L.; van Meijgaard, E.

    2013-01-01

    A regional atmospheric climate model with multi-layer snow module (RACMO2) is forced at the lateral boundaries by global climate model (GCM) data to assess the future climate and surface mass balance (SMB) of the Antarctic ice sheet (AIS). Two different GCMs (ECHAM5 until 2100 and HadCM3 until 2200)

  8. Surface mass balance and runoff modeling using HIRHAM4 RCM at Kangerlussuaq (Søndre Strømfjord), West Greenland, 1950-2080

    DEFF Research Database (Denmark)

    Mernild, Sebastian H.; Liston, Glen E.; Hiemstra, Christopher A.

    2011-01-01

    Greenland's Kangerlussuaq drainage. Projected changes in the Greenland Ice Sheet (GrIS) surface mass balance (SMB) and runoff are relevant for potential hydropower production and prediction of ecosystem changes in sensitive Kangerlussuaq Fjord systems. Mean annual surface air temperatures and precipitation...

  9. Modeling glacier mass balance and runoff in the Koxkar river basin on the south slope of the Tianshan Mountains, China, from 1959 to 2009

    Science.gov (United States)

    Xu, M.; Han, H.; Kang, S.

    2016-12-01

    Water resources provided by alpine glaciers are an important pillar for people living in the arid regions in the west of China. In this study, the HBV (Hydrologiska Byrans Vattenavdelning) model was applied to simulate glacier mass balance and runoff in the Koxkar river basin on the south slope of Mt. Tumur, western Tianshan Mountains. Daily temperature and precipitation were calculated by multiple linear regressions and gradient-inverse distance weighting, respectively, based on in-situ observed data by automatic weather stations (AWSs) in the basin (2007-2009) and at four meteorological stations neighbering the basin (1959-2009). In-situ observed daily data for 3-year air temperature and precipitation was input data for HBV. The model was calibrated by runoff in 2007/08 and 2009/10, and validated by runoff in 2008/09 and 2010/11. Generally, the model could simulate runoff very well. Thus, the annual glacier mass balance and runoff were calculated using the HBV model driven by interpolated meteorological data for the period of 1959-2009. The simulated glacier mass balance were reasonable when compared with those observed values at nearby glaciers, indicating a decrease trend of mass balance in the basin with an average value of -370.4 mm a-1 since 1959. The annual runoff showed a slight increase trend (5.51 mm a-1). Futher analysis indicated that the runoff is more sensitive to temperature than precipitation amuont in the Koxkar river basin.

  10. Modeling Glacier Mass Balance and Runoff in the Koxkar River Basin on the South Slope of the Tianshan Mountains, China, from 1959 to 2009

    Directory of Open Access Journals (Sweden)

    Min Xu

    2017-02-01

    Full Text Available Water resources provided by alpine glaciers are an important pillar for people in the arid regions of west China. In this study, the Hydrologiska Byrans Vattenavdelning (HBV light model was applied to simulate glacier mass balance (GMB and runoff in the Koxkar River Basin (KRB on the south slope of Mount Tumur, in the western Tianshan Mountains. Daily temperature and precipitation were calculated by multiple linear regressions and gradient-inverse distance weighting, respectively, based on in-situ observed data by automatic weather stations (AWSs in the Koxkar River Basin (KRB; 2007–2009 and four meteorological stations neighboring the basin (1959–2009. Observed daily air temperature and precipitation were input into HBV model. The runoff data in 2007/2008 and 2008/2009 were used to calibrate and validate the model in 2009/2010 and 2010/2011. Generally, the model simulated runoff very well. The annual glacier mass balance and runoff were calculated by the HBV model and were driven by interpolated meteorological data between 1959 and 2009. The calculated glacier mass balances were reasonable, and were compared with nearby glaciers. The results indicate the decreasing trend of mass balance in the Koxkar Glacier, with an average value of ablation of −370.4 mm·a−1 between 1959 and 2009. The annual runoff showed an increasing trend (5.51 mm·a−1. Further analysis showed that the runoff is more sensitive to temperature than precipitation in KRB.

  11. Internal accumulation on Storglaciären, Sweden, in a multi-layer snow model coupled to a distributed energy- and mass balance model

    NARCIS (Netherlands)

    Reijmer, C.H.; Hock, Regine

    2008-01-01

    To investigate the internal accumulation on Storglaciären, Sweden, we couple a multilayer snow model to a distributed energy- and mass-balance model. The snow model describes the temperature, density and water-content evolution of the snow/ice pack and includes the processes of percolation and

  12. Greenland ice sheet surface mass-balance modelling and freshwater flux for 2007, and in a 1995-2007 perspective

    DEFF Research Database (Denmark)

    Mernild, Sebastian H.; Liston, Glen E.; Hiemstra, Christopher A.

    2009-01-01

    The freshwater flux from the Greenland Ice Sheet (GrIS) to the ocean is of considerable importance to the global eustatic sea level rise. A physical modelling approach using SnowModel, a state-of-the-art snow-evolution modelling system that includes four submodels (MicroMet, EnBal, SnowPack, and ......The freshwater flux from the Greenland Ice Sheet (GrIS) to the ocean is of considerable importance to the global eustatic sea level rise. A physical modelling approach using SnowModel, a state-of-the-art snow-evolution modelling system that includes four submodels (MicroMet, EnBal, Snow......-stations) were used as model inputs. The GrIS minimum surface melt extent of 29% occurred in 1996, while the greatest extent of 51% was present in 2007. The 2007 melt extent was 20% greater than the average for 1995-2006. The year 2007 had the highest GrIS surface runoff (523 km3 y-1) and the lowest SMB (-3 km3...... estimates of GrIS subglacial runoff (from geothermal melt) and GrIS calving to quantify GrIS freshwater flux to the ocean, indicating an average negative mass-balance of 265 (±83) km3 y-1. This study further suggests an average GrIS freshwater flux of approximately 786 km3 y-1 to the ocean, of which 45...

  13. Effects of plant biomass on nitrogen transformation in subsurface-batch constructed wetlands: a stable isotope and mass balance assessment.

    Science.gov (United States)

    Chen, Yi; Wen, Yue; Zhou, Qi; Vymazal, Jan

    2014-10-15

    Nitrate is commonly found in the influent of subsurface-batch constructed wetlands (SSB CWs) used for tertiary wastewater treatments. To understand the effects of plants and the litter on nitrate removal, as well as on nitrogen transformation in SSB CWs, six laboratory-scale SSB CW microcosms were set up in duplicate and were operated as batch systems with hydraulic residence time (HRT) of 5d. The