WorldWideScience

Sample records for durability tests

  1. Towards a durability test for washing-machines.

    Science.gov (United States)

    Stamminger, Rainer; Tecchio, Paolo; Ardente, Fulvio; Mathieux, Fabrice; Niestrath, Phoebe

    2018-04-01

    Durability plays a key role in enhancing resource conservation and contributing to waste minimization. The washing-machine product group represents a relevant case study for the development of a durability test and as a potential trigger to systematically address durability in the design of products. We developed a procedure to test the durability performance of washing-machines as a main objective of this research. The research method consisted of an analysis of available durability standards and procedures to test products and components, followed by an analysis of relevant references related to frequent failures. Finally, we defined the criteria and the conditions for a repeatable, relatively fast and relevant endurance test. The durability test considered the whole product tested under conditions of stress. A series of spinning cycles with fixed imbalanced loads was run on two washing-machines to observe failures and performance changes during the test. Even though no hard failures occurred, results clearly showed that not all washing-machines can sustain such a test without abrasion or performance deterioration. However, the attempt to reproduce the stress induced on a washing-machine by carrying out a high number of pure spinning cycles with fixed loads did not allow equal testing conditions: the actions of the control procedure regarding imbalanced loads differ from machine to machine. The outcomes of this research can be used as grounds to develop standardised durability tests and to, hence, contribute to the development of future product policy measures.

  2. Quick test for durability factor estimation.

    Science.gov (United States)

    2010-03-01

    The Missouri Department of Transportation (MoDOT) is considering the use of the AASHTO T 161 Durability Factor (DF) as an endresult : performance specification criterion for evaluation of paving concrete. However, the test method duration can exceed ...

  3. DURABILITY TESTING OF FLUIDIZED BED STEAM REFORMER (FBSR) WASTE FORMS

    International Nuclear Information System (INIS)

    Jantzen, C

    2006-01-01

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium aqueous radioactive wastes. The addition of clay and a catalyst as co-reactants converts high sodium aqueous low activity wastes (LAW) such as those existing at the Hanford and Idaho DOE sites to a granular ''mineralized'' waste form that may be made into a monolith form if necessary. Simulant Hanford and Idaho high sodium wastes were processed in a pilot scale FBSR at Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium-bearing waste (SBW). The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The durability of the FBSR waste form products was tested in order to compare the measured durability to previous FBSR waste form testing on Hanford Envelope C waste forms that were made by THOR Treatment Technologies (TTT) and to compare the FBSR durability to vitreous LAW waste forms, specifically the Hanford low activity waste (LAW) glass known as the Low-activity Reference Material (LRM). The durability of the FBSR waste form is comparable to that of the LRM glass for the test responses studied

  4. Assessing the representativeness of durability tests for wood pellets by DEM Simulation - Comparing conditions in a durability test with transfer chutes

    Science.gov (United States)

    Mahajan, Aditya; Dafnomilis, Ioannis; Hancock, Victoria; Lodewijks, Gabriel; Schott, Dingena

    2017-06-01

    Dust generation when handling wood pellets is related to the durability of the product, in other words the wear rate of particles subject to forces. During transport, storage and handling wood pellets undergo different forces when interacting with different pieces of equipment. This paper assesses the representativeness of the tumbling can test in relation to transfer chutes, by comparing forces acting on wood pellets in durability tests and in transfer chutes using DEM. The study also incorporates effects such as shape and size variations. The results showed that the tumbling can test underestimates compressive and tangential forces. Since the tested material is subject to milder conditions than in reality, it can be concluded that this test is not representative for the conditions in the supply chain of wood pellets.

  5. Preliminary results of durability testing with borosilicate glass compositions

    International Nuclear Information System (INIS)

    Adel-Hadadi, M.; Adiga, R.; Barkatt, Aa.

    1987-01-01

    This is a report on the first year of research conducted at the Vitreous State Laboratory of the Catholic University of America in support of the West Valley Demonstration Project. One objective is the vitrification of liquid waste generated by previous nuclear fuel reprocessing. This work has been directed principally at the problem of glass composition optimization. This has necessitated the development of a coordinated program of glass production, durability measurements, and processability assessment. A small-scale continuous melter has been constructed for melting uranium and thorium containing glasses and for studying glass processing characteristics. Glass viscosities have been measured over a range of temperatures. A large number of glasses have also been produced in small crucible melts. Glass durability has been assessed using four types of leach tests: MCC-3, MCC-1, IAEA/ISO, and pulsed-flow tests. Extensive data from these tests are reported. The data have led to the design of very durable glasses (comparable to the Savannah River Laboratory Defense Waste Reference Glass) which have the requisite waste loading and processing characteristics. 14 refs., 4 figs., 77 tabs

  6. Advanced Stirling Convertor Durability Testing: Plans and Interim Results

    Science.gov (United States)

    Meer, David W.; Oriti, Salvatore M.

    2012-01-01

    The U.S. Department of Energy (DOE), Lockheed Martin Corporation (LM), and NASA Glenn Research Center (GRC) have been developing the Advanced Stirling Radioisotope Generator (ASRG) for use as a power system for space science missions. In support of this program, GRC has been involved in testing Stirling convertors, including the Advanced Stirling Convertor (ASC), for use in the ASRG. This testing includes electromagnetic interference/compatibility (EMI/EMC), structural dynamics, advanced materials, organics, and unattended extended operation. The purpose of the durability tests is to experimentally demonstrate the margins in the ASC design. Due to the high value of the hardware, previous ASC tests focused on establishing baseline performance of the convertors within the nominal operating conditions. The durability tests present the first planned extension of the operating conditions into regions beyond those intended to meet the product spec, where the possibility exists of lateral contact, overstroke, or over-temperature events. These tests are not intended to cause damage that would shorten the life of the convertors, so they can transition into extended operation at the conclusion of the tests. This paper describes the four tests included in the durability test sequence: 1) start/stop cycling, 2) exposure to constant acceleration in the lateral and axial directions, 3) random vibration at increased piston amplitude to induce contact events, and 4) overstroke testing to simulate potential failures during processing or during the mission life where contact events could occur. The paper also summarizes the analysis and simulation used to predict the results of each of these tests.

  7. Durability testing of the high-capacity GA-4/GA-9 trailer

    International Nuclear Information System (INIS)

    Zimmer, A.; Lyon, T.

    1995-01-01

    GA designed trailers to transport the GA-4 and GA-9 LWT from-reactor spent nuclear fuel shipping casks. GA designed and fabricated the GA-9 trailer to ANSI N14.30 requirements and is now performing a durability test at the AlliedSignal Automotive Proving Grounds. The trailer, simulated cask and tractor. The test program objective is to evaluate and improve, as necessary, the trailer's durability, reliability and performance

  8. Characterization and durability testing of a glass-bonded ceramic waste form

    International Nuclear Information System (INIS)

    Johnson, S. G.

    1998-01-01

    Argonne National Laboratory is developing a glass bonded ceramic waste form for encapsulating the fission products and transuranics from the conditioning of metallic reactor fuel. This waste form is currently being scaled to the multi-kilogram size for encapsulation of actual high level waste. This paper will present characterization and durability testing of the ceramic waste form. An emphasis on results from application of glass durability tests such as the Product Consistency Test and characterization methods such as X-ray diffraction and scanning electron microscopy. The information presented is based on a suite of tests utilized for assessing product quality during scale-up and parametric testing

  9. Durability Testing of Idlers for Belt Conveyors

    Directory of Open Access Journals (Sweden)

    Andrzej Pytlik

    2013-01-01

    On the basis of the durability tests carried out on both of these idlers it can be concluded that the applied research methodology describes the test conditions of idlers, in a manner as close as possible to their actual operational conditions, which were subject to a variety of factors for a total time of 116 hours, they included: dust, water, loads and variable rotational speed. This methodology allowed us to determine, even at the stage of laboratory tests, the suitability of a particular idler to certain operational conditions.

  10. Relationship between wheelchair durability and wheelchair type and years of test.

    Science.gov (United States)

    Wang, Hongwu; Liu, Hsin-Yi; Pearlman, Jon; Cooper, Rosemarie; Jefferds, Alexandra; Connor, Sam; Cooper, Rory A

    2010-01-01

    To investigate the relationship between the durability of wheelchairs according to American National Standard for Wheechairs/Rehabilitation Engineering and Assistive Technology Society of North America (ANSI/RESNA) Wheelchair Standards and wheelchair type as well as year of test. A retrospective study design with a sample of 246 wheelchairs that were tested in accordance with the ANSI/RESNA standards from 1992 to 2008 including four types of wheelchairs: manual wheelchair (MWC), electrical powered wheelchair (EPW), scooters and pushrim-activated power-assisted wheelchair (PAPAW). Unconditional binary logic regression analysis was chosen to evaluate the relationship between test results and test year as well as wheelchair type. Rehabilitation Engineering Research Center. Wheelchair durability test result (fatigue test: pass or fail) There was no significant correlation between the year when tested and equivalent cycles. A significant relation was found between test results and wheelchair type (Wald score = 10.845, degree of freedom = 3, p = 0.013) with scooters having a significantly higher pass ratio than MWC (OR = 15.629, 95% CI = 2.026-120.579). EPW also had significantly higher pass ratio than MWC (OR = 1.953, 95% CI = 1.049-3.636). No significant difference on pass ratio was found between PAPAW and MWC. No significant improvements in wheelchair test results during the time frame from 1992 to 2008 were discovered. Wheelchair standard tests should be conducted to assure minimum quality of the wheelchairs and for improving the design of wheelchairs. Although the ANSI/RESNA wheelchair durability test procedures have remained consistent, it does not appear that the introduction of new materials, designs and the availability of test data have improved wheelchair fatigue life.

  11. Standard test methods for determining chemical durability of nuclear, hazardous, and mixed waste glasses and multiphase glass ceramics: The product consistency test (PCT)

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2002-01-01

    1.1 These product consistency test methods A and B evaluate the chemical durability of homogeneous glasses, phase separated glasses, devitrified glasses, glass ceramics, and/or multiphase glass ceramic waste forms hereafter collectively referred to as “glass waste forms” by measuring the concentrations of the chemical species released to a test solution. 1.1.1 Test Method A is a seven-day chemical durability test performed at 90 ± 2°C in a leachant of ASTM-Type I water. The test method is static and conducted in stainless steel vessels. Test Method A can specifically be used to evaluate whether the chemical durability and elemental release characteristics of nuclear, hazardous, and mixed glass waste forms have been consistently controlled during production. This test method is applicable to radioactive and simulated glass waste forms as defined above. 1.1.2 Test Method B is a durability test that allows testing at various test durations, test temperatures, mesh size, mass of sample, leachant volume, a...

  12. Performance and durability testing of parabolic trough receivers

    Science.gov (United States)

    Lei, Dongqiang; Fu, Xuqiang; Zhao, Dongming; Yuan, Guofeng; Wang, Zhifeng; Guo, Minghuan

    2017-06-01

    The paper describes the key performance and durability testing facilities of the parabolic trough receiver developed by Institute of Electrical Engineering, Chinese Academy of Sciences. The indoor heat loss test can be applied at 4-7 different temperature levels within 200-550 on receivers. The optical efficiency test bench consists of 12 metal halide lamps as the solar simulator and a 5 m length half-elliptical cylinder reflector with flat end reflectors. 3 ultra-precision temperature sensors are used in receiver each end to get the temperature difference. The residual gas analysis test bench is applied to analyze and predict the vacuum lifetime of the receiver. It can test the variations of composition and partial pressure of residual gases with temperature and time in the receiver annulus space by a high sensitivity quadrupole mass spectrometer gas analyzer. A coating accelerated ageing test bench, which is also used to test the thermal cycle, has been developed. This test bench uses the absorber tube of the recevier as the resistance heater to heat up the whole receiver. The coating lifetime can be predicted by the Arrhenius parameters. For the cycling test, the compressed air is used to directly cool the inner surface of the absorber tube. The thermal cycling test is performed with temperature cycles from 150 °C to 450 °C for 160 cycles. The maximum thermal cycling frequency is 8 cycles per day. The mechanical fatigue test bench is used to test the bellows and the glass-to-metal seals durability at the same time. Both bellows are expanded and compressed to 6.5 mm in turn with 10,000 cycles. A new rotating test bench was also developed to test the thermal efficiency of the receiver.

  13. Weathering durability of commercial polymeric coatings tested by positron annihilation spectroscopy

    International Nuclear Information System (INIS)

    Chen, H.; Peng, Q.; Huang, Y.Y.; Zhang, R.; Li, Y.; Zhang, J.; Wu, Y.C.; Richardson, J.R.; Sandreczki, T.C.; Jean, Y.C.

    2003-01-01

    A series of commercial coatings were prepared according to the industrial specifications and were exposed to Florida natural weathering and controlled UVA irradiation. The Doppler broadening energy spectra (DBES) of positron annihilation were measured as a function of incident positron energy at different periods of weathering. A significant decrease in the S parameter was observed and it was used as an indicator to test coating durability in micro-scale. Application to weathering durability of commercial polymeric coatings under natural weathering and controlled UVA irradiation is investigated by using the S parameter from the DBES

  14. Durability testing of the high-capacity GA-4/GA-9 trailer

    International Nuclear Information System (INIS)

    Zimmer, A.

    1993-01-01

    General Atomics (GA) is under contract to the US Department of Energy (DOE), Idaho Field Office, to develop two legal-weight truck from-reactor spent-fuel shipping casks with trailers. GA is developing these high capacity transport systems to support the Office of Civilian Radioactive Waste Management's (OCRWM) mission to transport spent fuel from reactors to a permanent disposal site. GA's goal is to maximize the number of fuel assemblies that the transport system can safely carry. The GA-4 Cask is being designed to transport four pressurized-water-reactor (PWR) spent-fuel assemblies, and the GA-9 Cask is being designed to transport nine boiling-water-reactor (BWR) spent-fuel assemblies. The use of these high-capacity transport systems will have a large benefit to-public safety since the number of legal-weight truck shipments will be reduced by at least a factor of four over existing spent-fuel shipping cask systems. Achieving these capacities requires that the weight of each component of the transport system. i.e., cask, trailer and tractor, be minimized. The weight of the trailer is of particular importance. With a high load-to-weight ratio, the durability and reliability of the trailer become significant factors in the success of the transport system. In order to verify that the trailer design will meet the durability and performance requirements to safely transport spent-fuel, GA has planned an extensive testing program. The testing program includes non-destructive examination (NDE) of the trailer welds, operational testing, a static load test, an over-the-road performance test, and a test to verify the durability of the trailer up to its 1,000,000-mile design life. Since a prototype cask will not be available for the testing, GA designed and built a dummy payload that simulates the correct weight distribution and approximates the dynamic response of the prototype cask

  15. Durability Evaluation of Superconducting Magnets

    International Nuclear Information System (INIS)

    Inoue, Akihiko; Ogata, Masafumi; Nakauchi, Masahiko; Asahara, Tetsuo; Herai, Toshiki; Nishikawa, Yoichi

    2006-01-01

    It is one of the most essential things to verify the durability of devices and components of JR-Maglev system to realize the system into the future inauguration. Since the load requirements were insufficient in terms of the durability under vibrations under mere running tests carried out on Yamanashi Maglev Test Line hereinafter referred to YMTL, we have developed supplemental method with bench tests. Superconducting magnets hereinafter referred to SCM as used in the experimental running for the last seven years on the YMTL were brought to Kunitachi Technical Research Institute; we conducted tests to evaluate the durability of SCM up to a period of the service life in commercial use. The test results have indicated that no irregularity in each part of SCM proving that SCM are sufficiently durable for the practical application

  16. Durability Evaluation of Superconducting Magnets

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, Akihiko; Ogata, Masafumi; Nakauchi, Masahiko; Asahara, Tetsuo; Herai, Toshiki; Nishikawa, Yoichi

    2006-06-01

    It is one of the most essential things to verify the durability of devices and components of JR-Maglev system to realize the system into the future inauguration. Since the load requirements were insufficient in terms of the durability under vibrations under mere running tests carried out on Yamanashi Maglev Test Line hereinafter referred to YMTL, we have developed supplemental method with bench tests. Superconducting magnets hereinafter referred to SCM as used in the experimental running for the last seven years on the YMTL were brought to Kunitachi Technical Research Institute; we conducted tests to evaluate the durability of SCM up to a period of the service life in commercial use. The test results have indicated that no irregularity in each part of SCM proving that SCM are sufficiently durable for the practical application.

  17. A Test Method for Monitoring Modulus Changes during Durability Tests on Building Joint Sealants

    Science.gov (United States)

    Christopher C. White; Donald L. Hunston; Kar Tean Tan; Gregory T. Schueneman

    2012-01-01

    The durability of building joint sealants is generally assessed using a descriptive methodology involving visual inspection of exposed specimens for defects. It is widely known that this methodology has inherent limitations, including that the results are qualitative. A new test method is proposed that provides more fundamental and quantitative information about...

  18. Testing the durability of concrete with neutron radiography

    International Nuclear Information System (INIS)

    Beer, F.C. de; Le Roux, J.J.; Kearsley, E.P.

    2005-01-01

    The ability of concrete to withstand the penetration of liquid and oxygen can be described as the durability of concrete. The durability of concrete, can in turn, be quantified by certain characteristics of the concrete such as the porosity, sorptivity and permeability. The quantification of neutron radiography images of concrete structures and, therefore, the determination of concrete characteristics validate conventional measurements. This study compares the neutron radiography capability to obtain quantitative data for porosity and sorptivity in concrete to laboratory or conventional measurements. The effects that water to cement ratio and curing time have on the durability of concrete are investigated

  19. Application of Kingview and PLC in friction durability test system

    Science.gov (United States)

    Gao, Yinhan; Cui, Jing; Yang, Kaiyu; Ke, Hui; Song, Bing

    2013-01-01

    Using PLC and Kingview software, a friction durability test system is designed. The overall program, hardware configuration, software structure and monitoring interface are described in detail. PLC ensures the stability of data acquisition, and the KingView software makes the HMI easy to manipulate. The practical application shows that the proposed system is cheap, economical and highly reliable.

  20. Biological durability of wood in relation to end-use - Part 1. Towards a European standard for laboratory testing of the biological durability of wood

    NARCIS (Netherlands)

    Acker, Van J.; Stevens, M.; Carey, J.; Sierra-Alvarez, R.; Militz, H.; Bayon, Le I.; Kleist, G.; Peek, R.D.

    2003-01-01

    The determination of biological durability of wood is an issue requiring sufficient reliability regarding end-use related prediction of performance. Five test institutes joined efforts to check standard test methods and to improve methodology and data interpretation for assessment of natural

  1. Durability testing with West Valley borosilicate glass composition- Phase II

    International Nuclear Information System (INIS)

    Macedo, P.B.; Finger, S.M.; Barkatt, A.A.; Pegg, I.L.; Feng, X.; Freeborn, W.P.

    1988-06-01

    This report presents the research performed by the Catholic University of America Vitreous State Laboratory (VSL) during FY 1987 in support of the West Valley Demonstration Project (WVDP) nuclear waste vitrification process. A principal objective of this work is the optimization of the glass composition be used for the vitrification of the liquid high-level waste generated at West Valley during nuclear fuel reprocessing. This report discusses (1) the experimental investigations to optimize the reference glass composition (the current leading candidates are WVCM-50 and ATM-10) for the WVDP vitrification process; (2) the systematic experimental investigation performed to determine the effects of compositional variations in WVCM-50 and WV-205 reference glasses on their viscosity and durability (including initial results of long-term leach tests of WVCM-50 under repository conditions); (3) the development of short-time and predictive leach tests; (4) the development of a process model for the West Valley vitrification process which predicts the range of glass compositions which may be encountered during normal operations and the effects of deviations in process control parameters; and (5) the development of product models for predicting the durability and viscosity of nuclear waste glasses

  2. Durability Tests of Ball Valve Prototype with Flowmeter Operation

    Science.gov (United States)

    Rogula, J.; Romanik, G.

    2018-02-01

    The results of the investigation of the prototypical ball valve are presented in this article. The innovation of the tested valve is a ball with a built-in measuring orifice. The valve has been subjected to durability tests. Leakage under three temperatures: ambient, -30°C and +100°C was analyzed. Sealing elements of the valve were tested for roughness and deviation of shape before and after the cycles of operation. Ball valve operation means cycles of open/close. It was planned to perform 1000 cycles at each temperature condition accordingly. Tests of the valve were performed under gas pressure equal to 10 MPa. The research was carried out under the Operational Program "Intelligent Development" (POIR 01.01.01-00-0013 / 15 "Development of devices for measurement of media flow on industrial trunk-lines".

  3. Development of an ASTM standard glass durability test, the Product Consistency Test (PCT), for high level radioactive waste glass

    International Nuclear Information System (INIS)

    Jantzen, C.M.; Bibler, N.E.; Beam, D.C.; Ramsey, W.G.

    1994-01-01

    The nation's first, and the world's largest, facility to immobilize high-level nuclear waste in durable borosilicate glass has started operation at the Savannah River Site (SRS) in Aiken, South Carolina. The product specifications on the glass wasteform produced in the Defense Waste Processing Facility (DWPF) required extensive characterization of the glass product before actual production began and for continued characterization during production. To aid in this characterization, a glass durability (leach) test was needed that was easily reproducible, could be performed remotely on highly radioactive samples, and could yield results rapidly. Several standard leach tests were examined with a variety of test configurations. Using existing tests as a starting point, the DWPF Product Consistency Test (PCT was developed in which crushed glass samples are exposed to 90 ± 2 degree C deionized water for seven days. Based on extensive testing, including a seven-laboratory round robin and confirmatory testing with radioactive samples, the PCT is very reproducible, yields reliable results rapidly, and can be performed in shielded cell facilities with radioactive samples

  4. Evaluation of stone durability using a combination of ultrasound, mechanical and accelerated aging tests

    International Nuclear Information System (INIS)

    Molina, E; Cultrone, G; Sebastián, E; Alonso, F J

    2013-01-01

    The durability of a rock when exposed to decay agents is an important criterion when assessing its quality as a building material. Our study focuses on six varieties of natural stone (two limestones, one dolostone, one travertine and two sandstones) that are widely used in both new and historical buildings. In order to assess their quality, we measured and characterized their dynamic elastic properties using ultrasounds, we measured their compressive strength using the uniaxial compression test and we evaluated their durability by means of accelerated aging tests (freeze-thaw and salt crystallization). In order to get a full picture of the decay suffered by the different stones, we determined the composition and amount of the clay fraction of the six stones. We also observed small fragments subjected to the salt crystallization test under an environmental scanning electron microscope to study any textural change and measured the changes of colour on the surface with a spectrophotometer. Finally, we analysed the pore system of the stones before and after their deterioration using mercury injection porosimetry. We then compared the results for the different stones and found that dolostone obtained the best results, while the two limestones proved to be the least durable and had the lowest compressive strength. (paper)

  5. 40 CFR 610.33 - Durability tests.

    Science.gov (United States)

    2010-07-01

    ....33 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) ENERGY POLICY FUEL ECONOMY... problems, deterioration in spark plug life, increase in carburetor or combustion chamber deposits, or..., then a durability run may be made as described in subpart E, in which fuel economy and exhaust...

  6. Integrated durability process in product development

    International Nuclear Information System (INIS)

    Pompetzki, M.; Saadetian, H.

    2002-01-01

    This presentation describes the integrated durability process in product development. Each of the major components of the integrated process are described along with a number of examples of how integrated durability assessment has been used in the ground vehicle industry. The durability process starts with the acquisition of loading information, either physically through loads measurement or virtually through multibody dynamics. The loading information is then processed and characterized for further analysis. Durability assessment was historically test based and completed through field or laboratory evaluation. Today, it is common that both the test and CAE environments are used together in durability assessment. Test based durability assessment is used for final design sign-off but is also critically important for correlating CAE models, in order to investigate design alternatives. There is also a major initiative today to integrate the individual components into a process, by linking applications and providing a framework to communicate information as well as manage all the data involved in the entire process. Although a single process is presented, the details of the process can vary significantly for different products and applications. Recent applications that highlight different parts of the durability process are given. As well as an example of how integration of software tools between different disciplines (MBD, FE and fatigue) not only simplifies the process, but also significantly improves it. (author)

  7. Durability Testing of Biomass Based Oxygenated Fuel Components in a Compression Ignition Engine

    Energy Technology Data Exchange (ETDEWEB)

    Ratcliff, Matthew A [National Renewable Energy Laboratory (NREL), Golden, CO (United States); McCormick, Robert L [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Baumgardner, Marc E. [Gonzaga University; Lakshminarayanan, Arunachalam [Colorado State University; Olsen, Daniel B. [Colorado State University; Marchese, Anthony J. [Colorado State University

    2017-10-18

    Blending cellulosic biofuels with traditional petroleum-derived fuels results in transportation fuels with reduced carbon footprints. Many cellulosic fuels rely on processing methods that produce mixtures of oxygenates which must be upgraded before blending with traditional fuels. Complete oxygenate removal is energy-intensive and it is likely that such biofuel blends will necessarily contain some oxygen content to be economically viable. Previous work by our group indicated that diesel fuel blends with low levels (<4%-vol) of oxygenates resulted in minimal negative effects on short-term engine performance and emissions. However, little is known about the long-term effects of these compounds on engine durability issues such as the impact on fuel injection, in-cylinder carbon buildup, and engine oil degradation. In this study, four of the oxygenated components previously tested were blended at 4%-vol in diesel fuel and tested with a durability protocol devised for this work consisting of 200 hrs of testing in a stationary, single-cylinder, Yanmar diesel engine operating at constant load. Oil samples, injector spray patterns, and carbon buildup from the injector and cylinder surfaces were analyzed. It was found that, at the levels tested, these fuels had minimal impact on the overall engine operation, which is consistent with our previous findings.

  8. Durability predictions from rate of diffusion testing of normal portland cement, fly ash, and slag concrete

    International Nuclear Information System (INIS)

    Philipose, K.E.

    1991-09-01

    A waste repository for the belowground disposal of low-level radioactive waste, labelled IRUS (Intrusion Resistant Underground Structure), is planned at the Chalk River Laboratories. It relies greatly on the durability of concrete for a minimum of 500 years of service life. A research program based on laboratory testing to design a durable concrete and predict its useful engineered service life is in progress. The durability of concrete depends on its resistance to deterioration from both internal and external causes. Since the rate of degradation depends to a major extent on the rate of ingress of aggressive ions into concrete, laboratory testing is in progress to establish the diffusion rates of chlorides and sulphate ions. A total of 1000 concrete specimens and 500 paste specimens are being exposed at 22 degrees and 45 degrees C to twenty-five different combinations of corrosive agents, including CO 2 . Procedures to measure the ionic penetration profile and to determine the factors controlling diffusion of ions in the various concretes have been developed. The paper presents the initial results from the research program and the longevity predictions to qualify concretes for the IRUS waste repository, based on 16 months of diffusion testing on laboratory specimens

  9. Intermediate Ethanol Blends Catalyst Durability Program

    Energy Technology Data Exchange (ETDEWEB)

    West, Brian H; Sluder, Scott; Knoll, Keith; Orban, John; Feng, Jingyu

    2012-02-01

    In the summer of 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends (also known as mid-level blends) on legacy vehicles and other engines. The purpose of the test program was to develop information important to assessing the viability of using intermediate blends as a contributor to meeting national goals for the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20 - gasoline blended with 15% and 20% ethanol - on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This report provides the results of the catalyst durability study, a substantial part of the overall test program. Results from additional projects will be reported separately. The principal purpose of the catalyst durability study was to investigate the effects of adding up to 20% ethanol to gasoline on the durability of catalysts and other aspects of the emissions control systems of vehicles. Section 1 provides further information about the purpose and context of the study. Section 2 describes the experimental approach for the test program, including vehicle selection, aging and emissions test cycle, fuel selection, and data handling and analysis. Section 3 summarizes the effects of the ethanol blends on emissions and fuel economy of the test vehicles. Section 4 summarizes notable unscheduled maintenance and testing issues experienced during the program. The appendixes provide additional detail about the statistical models used in the analysis, detailed statistical analyses, and detailed vehicle specifications.

  10. Long-term durability testing of ceramic cross-flow filter. Final report, September 29, 1987--December 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Lippert, T.E.; Smeltzer, E.E.; Alvin, M.A.; Bachovchin, D.M.

    1993-08-01

    Long term durability testing of the cross flow filter is described. Two high temperature, high pressure test facilities were built and operated. The facilities were designed to simulate dirty gas environments typical of Pressurized Fluidized Bed Combustion (PFBC) and coal gasification. Details of the design and operation of the test facilities and filter testing results are described.

  11. Experimental Study on Color Durability of Color Asphalt Pavement

    Science.gov (United States)

    Ning, Shi; Huan, Su

    2017-06-01

    Aiming at the poor Color durability and the lack of research on Color asphalt pavement, spraying an anti-tire trace seal resin emulsion on the surface, a Color durable asphalt pavement was proposed. After long-term rolling and long-term aging test, the Color durability was evaluated by RGB function in Photoshop and trace residue rate formula. Test results proved that the Evaluation method was simple and effective. After long-term rolling, the Color of the road surface tends to a constant value. Spraying the emulsion on the road surface can resist tire traces. After long-term aging test, the resistance to tire traces was increased by 26.6% compared with the conventional type, while the former was 44.1% higher than the latter without long-term aging. The Color durable asphalt pavement can effectively improve the ability of Color asphalt pavement to resist tire traces, and significantly improve the Color durability of Color asphalt pavement.

  12. Performance and durability tests of smart icephobic coatings to reduce ice adhesion

    Energy Technology Data Exchange (ETDEWEB)

    Janjua, Zaid A.; Turnbull, Barbara [Faculty of Engineering, University of Nottingham (United Kingdom); Choy, Kwang-Leong; Pandis, Christos [Institute for Materials Discovery, University College London (UCL) (United Kingdom); Liu, Junpeng; Hou, Xianghui; Choi, Kwing-So [Faculty of Engineering, University of Nottingham (United Kingdom)

    2017-06-15

    Highlights: • Repeated ice adhesion and removal occurs on nanocoatings. • Icephobicity of nanocoatings reduces with each test cycle. • Adhesion strength linked to contact angle hysteresis in Gaussian fit. • Icephobicity not linked to hydrophobicity. - Abstract: The accretion of ice can cause damage in applications ranging from power lines and shipping decks, to wind turbines and rail infrastructure. In particular on aircraft, it can change aerodynamic characteristics, greatly affecting the flight safety. Commercial aircraft are therefore required to be equipped with de-icing devices, such as heating mats over the wings. The application of icephobic coatings near the leading edge of a wing can in theory reduce the high power requirements of heating mats, which melt ice that forms there. Such coatings are effective in preventing the accretion of runback ice, formed from airborne supercooled droplets, or the water that the heating mats generate as it is sheared back over the wing's upper surface. However, the durability and the practicality of applying them over a large wing surface have been prohibitive factors in deploying this technology so far. Here, we evaluated the ice adhesion strength of four non-conductive coatings and seven thermally conductive coatings by shearing ice samples from coated plates by spinning them in a centrifuge device. The durability of the coating performance was also assessed by repeating the tests, each time regrowing ice samples on the previously-used coatings. Contact angle parameters of each coating were tested for each test to determine influence on ice adhesion strength. The results indicate that contact angle hysteresis is a crucial parameter in determining icephobicity of a coating and hydrophobicity is not necessarily linked to icephobicity.

  13. Effect of glass composition on waste form durability: A critical review

    International Nuclear Information System (INIS)

    Ellison, A.J.G.; Mazer, J.J.; Ebert, W.L.

    1994-11-01

    This report reviews literature concerning the relationship between the composition and durability of silicate glasses, particularly glasses proposed for immobilization of radioactive waste. Standard procedures used to perform durability tests are reviewed. It is shown that tests in which a low-surface area sample is brought into contact with a very large volume of solution provide the most accurate measure of the intrinsic durability of a glass composition, whereas high-surface area/low-solution volume tests are a better measure of the response of a glass to changes in solution chemistry induced by a buildup of glass corrosion products. The structural chemistry of silicate and borosilicate glasses is reviewed to identify those components with the strongest cation-anion bonds. A number of examples are discussed in which two or more cations engage in mutual bonding interactions that result in minima or maxima in the rheologic and thermodynamic properties of the glasses at or near particular optimal compositions. It is shown that in simple glass-forming systems such interactions generally enhance the durability of glasses. Moreover, it is shown that experimental results obtained for simple systems can be used to account for durability rankings of much more complex waste glass compositions. Models that purport to predict the rate of corrosion of glasses in short-term durability tests are evaluated using a database of short-term durability test results for a large set of glass compositions. The predictions of these models correlate with the measured durabilities of the glasses when considered in large groupings, but no model evaluated in this review provides accurate estimates of durability for individual glass compositions. Use of these models in long-term durability models is discussed. 230 refs

  14. New alternative accelerated durability test for flow sensors of measurement devices of thermal energy; Neue alternative beschleunigte Abnutzungspruefung fuer Durchflusssensoren von Messgeraeten fuer ausgetauschte thermische Energie

    Energy Technology Data Exchange (ETDEWEB)

    Rose, Juergen; Fenske, Helmut; Gerdes, Oda [Physikalisch-Technische Bundesanstalt, Berlin (Germany). Fachbereich 7.6 Waerme

    2009-07-01

    To assess the durability, the sub-assembly 'flow sensor' of heat meters must, in EC conformity tests carried out in accordance with the provisions for the national implementation of the European Measuring Instruments Directive as well as in national type tests of cooling meters, also be subjected to durability tests [1;2]. For this purpose, the harmonized standard CEN EN 1434 [3], the normative document OIML R 75 [4] and the technical directive K 7.2 of PTB apply [5]. Due to the fact that the load exchange tests take as long as a quarter of a year, the current normative requirements for the durability test bring about a very high expenditure of time and cost. The investigations carried out by PTB in cooperation with manufacturers of the Association of the German Water and Heat Meter Industry e. V. (VDDW) allow the presently used durability test - which is, from the viewpoint of the manufacturers, uneconomic due to its long duration - to be replaced by a test which will take only 600 hours and which can, in addition, be scaled in time to the predicted durability duration. This became possible by transmitting the load-exchange processes prevailing in the sequence of operations of static heat-exchanger circulation systems into temporarily folded test load exchange cycles. (orig.)

  15. Fabrication and Testing of Durable Redundant and Fluted-Core Joints for Composite Sandwich Structures

    Science.gov (United States)

    Lin, Shih-Yung; Splinter, Scott C.; Tarkenton, Chris; Paddock, David A.; Smeltzer, Stanley S.; Ghose, Sayata; Guzman, Juan C.; Stukus, Donald J.; McCarville, Douglas A.

    2013-01-01

    The development of durable bonded joint technology for assembling composite structures is an essential component of future space technologies. While NASA is working toward providing an entirely new capability for human space exploration beyond low Earth orbit, the objective of this project is to design, fabricate, analyze, and test a NASA patented durable redundant joint (DRJ) and a NASA/Boeing co-designed fluted-core joint (FCJ). The potential applications include a wide range of sandwich structures for NASA's future launch vehicles. Three types of joints were studied -- splice joint (SJ, as baseline), DRJ, and FCJ. Tests included tension, after-impact tension, and compression. Teflon strips were used at the joint area to increase failure strength by shifting stress concentration to a less sensitive area. Test results were compared to those of pristine coupons fabricated utilizing the same methods. Tensile test results indicated that the DRJ design was stiffer, stronger, and more impact resistant than other designs. The drawbacks of the DRJ design were extra mass and complex fabrication processes. The FCJ was lighter than the DRJ but less impact resistant. With barely visible but detectable impact damages, all three joints showed no sign of tensile strength reduction. No compression test was conducted on any impact-damaged sample due to limited scope and resource. Failure modes and damage propagation were also studied to support progressive damage modeling of the SJ and the DRJ.

  16. Evaluation of the Mechanical Durability of the Egyptian Machine Readable Booklet Passport

    Directory of Open Access Journals (Sweden)

    Ahmed Mahmoud Yosri

    2013-12-01

    Full Text Available In 2008 the first Egyptian booklet Machine Readable Passport/ MRP has been issued and its security and informative standard quality levels were proved in a research published in 2011. Here the durability profiles of the Egyptian MRP have been evaluated. Seven mechanical durability tests were applied on the Egyptian MRP. Such tests are specified in the International Civil Aviation Organization / ICAO standard requirements documents. These seven very severe durability tests resulted in that the Egyptian MRP has achieved better & higher results than the values detected in ICAO-Doc N0232: Durability of Machine Readable Passports - Version: 3.2. Hence, this research had proved the complete conformance between the Egyptian MRP mechanical durability profiles to the international requirements. The Egyptian booklet MRP doesn’t need any obligatory modification concerning its mechanical durability profiles.

  17. International Conference on Durability of Critical Infrastructure

    CERN Document Server

    Cherepetskaya, Elena; Pospichal, Vaclav

    2017-01-01

    This book presents the proceedings of the International Conference on Durability of Critical Infrastructure. Monitoring and Testing held in Satov, Czech Republic from 6 to 9 December 2016. It discusses the developments in the theoretical and practical aspects in the fields of Safety, Sustainability and Durability of the Critical Infrastructure. The contributions are dealing with monitoring and testing of structural and composite materials with a new methods for their using for protection and prevention of the selected objects.

  18. Durability and Design Issues of Thermal/environmental Barrier Coatings on Sic/sic Ceramic Matrix Composites Under 1650 C Test Conditions

    Science.gov (United States)

    Zhu, Dong-Ming; Choi, Sung R.; Ghosn, Louis J.; Miller, Robert A.

    2004-01-01

    Ceramic thermal/environmental barrier coatings for SiC-based ceramics will play an increasingly important role in future gas turbine engines because of their ability to effectively protect the engine components and further raise engine temperatures. However, the coating durability remains a major concern with the ever-increasing temperature requirements. Currently, advanced T/EBC systems, which typically include a high temperature capable zirconia- (or hahia-) based oxide top coat (thermal barrier) on a less temperature capable mullite/barium-strontium-aluminosilicate (BSAS)/Si inner coat (environmental barrier), are being developed and tested for higher temperature capability Sic combustor applications. In this paper, durability of several thermal/environmental barrier coating systems on SiC/SiC ceramic matrix composites was investigated under laser simulated engine thermal gradient cyclic, and 1650 C (3000 F) test conditions. The coating cracking and delamination processes were monitored and evaluated. The effects of temperature gradients and coating configurations on the ceramic coating crack initiation and propagation were analyzed using finite element analysis (FEA) models based on the observed failure mechanisms, in conjunction with mechanical testing results. The environmental effects on the coating durability will be discussed. The coating design approach will also be presented.

  19. Creep Behavior and Durability of Cracked CMC

    Science.gov (United States)

    Bhatt, R. T.; Fox, Dennis; Smith, Craig

    2015-01-01

    To understand failure mechanisms and durability of cracked Ceramic matrix composites (CMCs), Melt Infiltration (MI) SiCSiC composites with Sylramic-iBN fibers and full Chemical vapour infiltration SiCSiC composites with Sylramic-ion bombarded BN (iBN) and Hi-Nicalon -S fibers were pre-cracked between 150 to 200 megapascal and then creep and Sustained Peak Low Cycle Fatigue (SPLCF) tested at 13150 C at stress levels from 35 to 103 megapascal for up to 200 hours under furnace and burner rig conditions. In addition creep testing was also conducted on pre-cracked full Chemical vapour infiltration SiCSiC composites at 14500 C between 35 and 103 megapascal for up to 200 hours under furnace conditions. If the specimens survived the 200 hour durability tests, then they were tensile tested at room temperature to determine their residual tensile properties. The failed specimens were examined by Scanning electron microscope (SEM) to determine the failure modes and mechanisms. The influence of crack healing matrix, fiber types, crack density, testing modes and interface oxidation on durability of cracked Ceramic matrix composites (CMCs) will be discussed.

  20. Textile for heart valve prostheses: fabric long-term durability testing.

    Science.gov (United States)

    Heim, Frederic; Durand, Bernard; Chakfe, Nabil

    2010-01-01

    The rapid developments and success in percutaneous vascular surgery over the last two decades with the now common stent grafts implantation, make the noninvasive surgery technique today attractive even for heart valve replacement. Less traumatic for the patient and also less time consuming, percutaneous heart valve replacement is however at its beginning and restricted to end of life patients. The noninvasive procedure expects from the heart valve prosthesis material to be resistant and adapted to folding requirements of the implantation process (catheter). Polyester fabric could be a suited material for heart valve implanted percutaneously. Highly flexible and resistant, polyester fabric proved to be well adapted to the dynamic behavior of a valve and polyester (Dacron) is also widely used for vascular grafts implantation and shows good biocompatibility and durability. However, today there's no data available on long-term durability of fabric used as heart valve material. The purpose of this work is to study the long term behavior of a microdenier polyester fabric construction under combined in vitro flexure and tension fatigue stress. In the novel in vitro testing technique presented, a fabric specimen was subjected to combined flexural and tensile fatigue generated by fluid flow under physiological pressure conditions. The results obtained show how flexural properties change with fatigue time, which reflects directly on the suitability of a fabric in such devices. It was also observed that these fabric structural changes directly influence the in vitro behavior of the textile heart valve prosthesis. (c) 2009 Wiley Periodicals, Inc.

  1. Durability analysis of gneiss using wear resistance

    Directory of Open Access Journals (Sweden)

    José Luiz Ernandes Dias Filho

    2014-01-01

    Full Text Available This paper presents a study conducted in gneiss in Santo Antonio de Pádua, RJ, BR, including durability analysis of the rock using slake durability test. Rocks in the region of Pádua are mostly used for ornamental purposes. A lab equipment was developed to evaluate the influence of rotation in the test, allowing for the speed variation of 7 RPM to 238 RPM. This study could be implemented in a wide variety of rock materials, targeting them according to their lifetime in the project. With variation of the wear levels, increasing weight loss was observed until the inertia moment in which the sample holds to the machine wall. The results indicate an increase in linear mass loss. These procedures allow a more precise analysis of durability than can be applied in different different regions of the world.

  2. Advanced Durability Analysis. Volume 2. Analytical Predictions, Test Results and Analytical Correlations

    Science.gov (United States)

    1989-02-27

    Deteministic Crack Growth ApprMach ( CApm -DCG-) Ndaft)/dt m 101Ca )I SUVICE TINE Wh Two-stit btei’uinistic-stochastic Crack Groth Approach (WHO-CG) Figure...physical description of the state of damage for a durability- critical component and a logical basis for estimating structural maintenance/repair require...The stress level for each stress region is important for crack growth predictions. Therefore, the stress analysis for durability- critical components

  3. Multi-factor Effects on the Durability of Recycle Aggregate Concrete

    Science.gov (United States)

    Ma, Huan; Cui, Yu-Li; Zhu, Wen-Yu; Xie, Xian-Jie

    2016-05-01

    Recycled Aggregate Concrete (RAC) was prepared with different recycled aggregate replacement ratio, 0, 30%, 70% and 100% respectively. The performances of RAC were examined by the freeze-thaw cycle, carbonization and sulfate attack to assess the durability. Results show that test sequence has different effects on the durability of RAC; the durability is poorer when carbonation experiment was carried out firstly, and then other experiment was carried out again; the durability is better when recycled aggregate replacement ratio is 70%.

  4. Durability of cracked fibre reinforced concrete structures

    DEFF Research Database (Denmark)

    Hansen, Ernst Jan De Place; Nielsen, Laila

    1997-01-01

    (capillary water uptake) is used, involving an in-situ method and a laboratory method. Three different concrete qualities as well as steel fibres (ZP) and polypropylene fibres (PP) are used. Results of the durability tests on cracked FRC-beams are compared to results for uncracked FRC-beams and beams without......Durability studies are carried out by subjecting FRC-beams to combined mechanical and environmental load. Mechanical load is obtained by exposing beams to il-point bending until a predefined crack width is reached, using a newly developed test setup. As environmental load, exposure to water...

  5. Long-Term Durability Test for the Left Ventricular Assist System EVAHEART under the Physiologic Pulsatile Load.

    Science.gov (United States)

    Kitano, Tomoya; Iwasaki, Kiyotaka

    The EVAHEART Left Ventricular Assist System (LVAS) was designed for the long-term support of a patient with severe heart failure. It has an original water lubrication system for seal and bearing and wear on these parts was considered one of its critical failure modes. A durability test focusing on wear was designed herein. We developed a mock loop, which generates a physiologic pulsatile flow and is sufficiently durable for a long-term test. The pulsatile load and the low fluid viscosity enable the creation of a severe condition for the mechanical seal. A total of 18 EVAHEART blood pumps completed 2 years of operation under the pulsatile condition without any failure. It indicated the EVAHEART blood pump had a greater than 90% reliability with a 88% confidence level. The test was continued with six blood pumps and achieved an average of 8.6 years, which was longer than the longest clinical use in Japan. The test result showed that no catastrophic, critical, marginal, or minor failures of the blood pump or their symptoms were observed. The seal performance was maintained after the test. Moreover, the surface roughness did not change, which showed any burn or abnormal wear occurred. The original water lubrication system equipped in EVAHEART LVAS prevent severe wear on the seal and the bearing, and it can be used in the bridge to transplant and destination therapy.

  6. Comparative study of durability test methods for pellets and briquettes

    Energy Technology Data Exchange (ETDEWEB)

    Temmerman, Michaeel; Rabier, Fabienne [Centre wallon de Recherches agronomiques (CRA-W), 146, chaussee de Namur, B-5030, Gembloux (Belgium); Jensen, Peter Daugbjerg [Forest and Landscape, The Royal Veterinary and Agricultural University, Rolighedsvej 23, DK-1958 Frederiksberg C (Denmark); Hartmann, Hans; Boehm, Thorsten [Technologie- und Foerderzentrum fuer Nachwachsende Rohstoffe-TFZ, Schulgasse 18, D-94315 Straubing (Germany)

    2006-11-15

    Different methods for the determination of the mechanical durability (DU) of pellets and briquettes were compared by international round robin tests including different laboratories. The DUs of five briquette and 26 pellet types were determined. For briquettes, different rotation numbers of a prototype tumbler and a calculated DU index are compared. For pellets testing, the study compares two standard methods, a tumbling device according to ASAE S 269.4, the Lignotester according to ONORM M 7135 and a second tumbling method with a prototype tumbler. For the tested methods, the repeatability, the reproducibility and the required minimum number of replications to achieve given accuracy levels were calculated. Additionally, this study evaluates the relation between DU and particle density. The results show for both pellets and briquettes, that the measured DU values and their variability are influenced by the applied method. Moreover, the variability of the results depend on the biofuel itself. For briquettes of DU above 90%, five replications lead to an accuracy of 2%, while 39 replications are needed to achieve an accuracy of 10%, when briquettes of DU below 90% are tested. For pellets, the tumbling device described by the ASAE standard allows to reach acceptable accuracy levels (1%) with a limited number of replications. Finally, for the tested pellets and briquettes no relation between DU and particle density was found. (author)

  7. Pyramiding for Resistance Durability: Theory and Practice.

    Science.gov (United States)

    Mundt, Chris

    2018-04-12

    Durable disease resistance is a key component of global food security, and combining resistance genes into "pyramids" is an important way to increase durability of resistance. The mechanisms by which pyramids impact durability are not well known. The traditional view of resistance pyramids considers the use of major resistance gene (R-gene) combinations deployed against pathogens that are primarily asexual. Interestingly, published examples of the successful use of pyramids in the traditional sense are rare. In contrast, most published descriptions of durable pyramids in practice are for cereal rusts, and tend to indicate an association between durability and cultivars combining major R-genes with incompletely expressed, adult plant resistance genes. Pyramids have been investigated experimentally for a diversity of pathogens, and many reduce disease levels below that of the single best gene. Resistance gene combinations have been identified through phenotypic reactions, molecular markers, and challenge against effector genes. As resistance genes do not express equally in all genetic backgrounds, however, a combination of genetic information and phenotypic analyses provide the ideal scenario for testing of putative pyramids. Not all resistance genes contribute equally to pyramids, and approaches have been suggested to identify the best genes and combinations of genes for inclusion. Combining multiple resistance genes into a single plant genotype quickly is a challenge that is being addressed through alternative breeding approaches, as well as through genomics tools such as resistance gene cassettes and gene editing. Experimental and modeling tests of pyramid durability are in their infancy, but have promise to help direct future studies of pyramids. Several areas for further work on resistance gene pyramids are suggested.

  8. Durability of Bricks Coated with Red mud Based Geopolymer Paste

    Science.gov (United States)

    Singh, Smita; Basavanagowda, S. N.; Aswath, M. U.; Ranganath, R. V.

    2016-09-01

    The present study is undertaken to assess the durability of concrete blocks coated with red mud - fly ash based geopolymer paste. Concrete blocks of size 200 x 200 x 100mm were coated with geopolymer paste synthesized by varying the percentages of red mud and fly ash. Uncoated concrete blocks were also tested for the durability for comparison. In thermal resistance test, the blocks were subjected to 600°C for an hour whereas in acid resistance test, they were kept in 5% sulphuric acid solution for 4 weeks. The specimens were thereafter studied for surface degradation, strength loss and weight loss. Pastes with red mud percentage greater than 50% developed lot of shrinkage cracks. The blocks coated with 30% and 50% red mud paste showed better durability than the other blocks. The use of blocks coated with red mud - fly ash geopolymer paste improves the aesthetics, eliminates the use of plaster and improves the durability of the structure.

  9. Micro-fractures produced in the Cadalso de los Vidrios granite (Madrid) subjected to Freeze-Thaw Durability Testing

    Science.gov (United States)

    Freire-Lista, D. M.; Varas-Muriel, M. J.; Fort, R.

    2012-04-01

    A specific leucogranite (fine to medium grain sized) from Cadalso de los Vidrios, Madrid, Spain, from where it takes the name of the stone variety, which is a traditional heritage building material used in Central Spain, was subjected to freezing-thaw durability tests or accelerated artificial ageing tests (according to Spanish standard EN 12371:2001) to assess its durability by means of ultrasonic velocity measurements (a non-destructive technique), and optical and fluorescence petrography using a polarized optical microscope (destructive technique), both techniques used before, during and after laboratory ageing tests, or in other words, what is determined is the improvement or deterioration in some properties. The measurement of the ultrasonic velocity in the leucogranite cubic test specimens along the freezing-thaw cycles shown that the velocity diminishes with the number of cycles, in relation to the decay that the stones were experiencing. This deterioration can be observed by the loss of crystalline minerals in the surface of the analyzed samples and by the micro-fractures appearance up to one centimeter deep, which have been detected by the petrographic techniques previously mentioned. The images taken by means of the fluorescence microscope clearly show the micro-fractures generated during the durability test. These images have been processed and analyzed by the UTHSCSA Image Tool program with the purpose of being able to quantify the degree of decay that this type of crystalline materials undergone, when subjected to a number of freezing-thaw test cycles. It is therefore an effective, reliable and complementary technique to that of the petrography analysis, both optical and fluorescence ones. In the first cycles of the ageing test, the micro-fractures propagate along crystals edges and during the last cycles of the test, intracrystalline micro-fractures are generated, which are developed in different ways depending on the mineralogy of the crystals. Thus

  10. Enhanced washing durability of hydrophobic coating on cellulose fabric using polycarboxylic acids

    International Nuclear Information System (INIS)

    Huang Wenqi; Xing Yanjun; Yu Yunyi; Shang Songmin; Dai Jinjin

    2011-01-01

    Nine polycarboxylic acids were used to improve washing durability of hydrophobic cellulose fabric finished by sol-gel method. By simultaneous forming ester-bridge between cellulose and silica layer by ester bond, polycarboxylic acids could anchor silica coating onto cellulose fabric to strengthen the adhesion of organic-inorganic hybrid coating. The wettability of treated fabrics was characterized by water contact angle, spray test and hydrostatic pressure test. The results showed that all investigated polycarboxylic acids could improve the durability. The polycarboxylic acid with proper distance between terminal carboxylic acid groups and number of carboxylic acid groups showed the highest durability. 1,2,3,4-butanetetracarboxylic acid (BTCA) led to the best durability of hydrophobic cellulose fabric with water contact angle of 137.6 o (recovery percentage of 94.2%) after 30 washing times. The effect of BTCA on durability was characterized by scanning electron microscopy. This study demonstrated that the surface treatment using polycarboxylic acids and mixed organosilanes is a promising alternative for achieving durable hydrophobic fabrics.

  11. Durability 2007. Injection grout investigations. Background description

    International Nuclear Information System (INIS)

    Orantie, K.; Kuosa, H.

    2008-12-01

    The aim of this project was to evaluate the durability risks of injection grouts. The investigations were done with respect to the application conditions, materials and service life requirements at the ONKALO underground research facility. The study encompassed injection grout mixtures made of ultrafine cement with and without silica fume. Some of the mixtures hade a low pH and thus a high silica fume content. The project includes a background description on durability literature, laboratory testing programme, detailed analysis of results and recommendations for selecting of ideal grout mixtures. The background description was made for the experimental study of low-pH and reference rock injection grouts as regards pore- and microstructure, strength, shrinkage/swelling and thus versatile durability properties. A summary of test methods is presented as well as examples, i.e. literature information or former test results, of expected range of results from the tests. Also background information about how the test results correlate to other material properties and mix designs is presented. Besides the report provides basic information on the pore structure of cement based materials. Also the correlation between the pore structure of cement based materials and permeability is shortly discussed. The test methods included in the background description are compressive strength, measurement of bulk drying, autogenous and chemical shrinkage and swelling, hydraulic conductivity / permeability, capillary water uptake test, mercury intrusion porosimetry (MIP) and thin section analysis. Three main mixtures with water-binder ratio of 0.8, 1.0 and 1.4 and silica fume content of 0, 15 and 40% were studied in the laboratory. Besides two extra mixtures were studied to provide additional information about the effect of varying water-dry-material ratio and silica fume content on durability. The evaluation of water tightness based on water permeability coefficient and micro cracking was

  12. Using Bonding Enamel-Coated Steel Fixtures to Produce More Durable Brick/Masonry Structures

    Science.gov (United States)

    2010-02-01

    Initial tests with enameled metal straps cracked all the test cylinders and straps would not pull out BUILDING STRONG® New Strong Durable Ties...BUILDING STRONG® Using Bonding Enamel -Coated Steel Fixtures to Produce More Durable Brick/Masonry Structures Principal Investigator: Steven C...COVERED 00-00-2010 to 00-00-2010 4. TITLE AND SUBTITLE Using Bonding Enamel -Coated Steel Fixtures to Produce More Durable Brick/Masonry

  13. A durability test rig and methodology for erosion-resistant blade coatings in turbomachinery

    Science.gov (United States)

    Leithead, Sean Gregory

    A durability test rig for erosion-resistant gas turbine engine compressor blade coatings was designed, completed and commissioned. Bare and coated 17-4PH steel V103-profile blades were rotated at up to 11500 rpm and impacted with Garnet sand for 5 hours at an average concentration of 2.51 gm3of air , at a blade leading edge Mach number of 0.50. The rig was determined to be an acceptable first stage axial compressor representation. Two types of 16 microm-thick coatings were tested: Titanium Nitride (TiN) and Chromium-Aluminum-Titanium Nitride (CrAlTiN), both applied using an Arc Physical Vapour Deposition technique at the National Research Council in Ottawa, Canada. A Leithead-Allan-Zhao (LAZ) score was created to compare the durability performance of uncoated and coated blades based on mass-loss and blade dimension changes. The bare blades' LAZ score was set as a benchmark of 1.00. The TiN-coated and CrAlTiN-coated blades obtained LAZ scores of 0.69 and 0.41, respectively. A lower score meant a more erosion-resistant coating. Major modes of blade wear included: trailing edge, leading edge and the rear suction surface. Trailing edge thickness was reduced, the leading edge became blunt, and the rear suction surface was scrubbed by overtip and recirculation zone vortices. It was found that the erosion effects of vortex flow were significant. Erosion damage due to reflected particles was not present due to the low blade solidity of 0.7. The rig is best suited for studying the performance of erosion-resistant coatings after they are proven effective in ASTM standardized testing. Keywords: erosion, compressor, coatings, turbomachinery, erosion rate, blade, experimental, gas turbine engine

  14. Effect Of Climatic Conditions On Durability

    Directory of Open Access Journals (Sweden)

    Ibrahem M. Al Kiki

    2013-04-01

    Full Text Available Durability is one of the most important subjects in the soil stabilization. Since there is no specifications concerned the durability of lime stabilized soils, several factors were selected to show their effects on the durability, namely: wetting, drying, freezing, thawing and slaking.The effect of each one of the above factors as well as the combined effect of two or more factors, were studied on the volume change and soil strength and weight loss of soil samples stabilized with optimum lime content except the slaking test at which soil samples stabilized with different lime content.Tests results showed that the higher the lime content the lower the slaking effect, also its found the soil strength decreased when the period of immersion or freezing increased. The strength of the lime stabilized soils decreased when subjected to the cycles of wetting and drying or to the cycles freezing and thawing. However, the  combined effect of wetting, drying, freezing and thawing has a pronounced effect on reduction of the lime stabilized clayey soil. The worst condition recorded when lime stabilized soil undergo to freezing then drying then wetting which should be avoided in the field

  15. Test validation of environmental barrier coating (EBC) durability and damage tolerance modeling approach

    Science.gov (United States)

    Abdul-Aziz, Ali; Najafi, Ali; Abdi, Frank; Bhatt, Ramakrishna T.; Grady, Joseph E.

    2014-03-01

    Protection of Ceramic Matrix Composites (CMCs) is rather an important element for the engine manufacturers and aerospace companies to help improve the durability of their hot engine components. The CMC's are typically porous materials which permits some desirable infiltration that lead to strength enhancements. However, they experience various durability issues such as degradation due to coating oxidation. These concerns are being addressed by introducing a high temperature protective system, Environmental Barrier Coating (EBC) that can operate at temperature applications1, 3 In this paper, linear elastic progressive failure analyses are performed to evaluate conditions that would cause crack initiation in the EBC. The analysis is to determine the overall failure sequence under tensile loading conditions on different layers of material including the EBC and CMC in an attempt to develop a life/failure model. A 3D finite element model of a dogbone specimen is constructed for the analyses. Damage initiation, propagation and final failure is captured using a progressive failure model considering tensile loading conditions at room temperature. It is expected that this study will establish a process for using a computational approach, validated at a specimen level, to predict reliably in the future component level performance without resorting to extensive testing.

  16. Chemical durability of glasses containing radioactive fission product waste

    International Nuclear Information System (INIS)

    Mendel, J.E.; Ross, W.A.

    1974-04-01

    Measurements made to determine the chemical durability of glasses for disposal of radioactive waste are discussed. The term glass covers materials varying from true glass with only minute quantities of crystallites, such as insoluble RuO 2 , to quasi glass-ceramics which are mostly crystalline. Chemical durability requirements and Soxhlet extractor leach tests are discussed

  17. Application of the cementitious grouts on stability and durability of semi flexible bituminous mixtures

    Science.gov (United States)

    Karami, Muhammad

    2017-11-01

    This paper describes the results of laboratory test for a high durability semi flexible bituminous mixtures (SFBM). The SFBM consists of an open asphalt structure where a high strength mortar is penetrated into the air voids of the bituminous mixtures. The SFBM combines the cement concrete's strength and the asphalt material flexibility. The objective of this study is to involve in the determination of stability and durability of SFBM by located the position of the specimen on an exposed area for 7, 90, 180 and 240 days. The performance of the SFBM was assessed using Marshall and wheel tracking apparatus. Total 18 specimens were prepared and examined for both of test. The Marshall specimens were cylindrical with dimension of 10.16 cm in diameter and 6.35 cm in high. For wheel tracking test, the specimens consisted of slabs with dimension of 30 cm in length, 30 cm in width and 5 cm in height. The results indicated that the first durability index and second durability index increased significantly. For Marshall test, the first and second durability index increased about 0.9% per day and 52.3%, respectively. However, for wheel tracking test, the first and second durability index increased about 1.9% per day and 119%, respectively.

  18. Experimental Study on Durability Improvement of Fly Ash Concrete with Durability Improving Admixture

    OpenAIRE

    Quan, Hong-zhu; Kasami, Hideo

    2014-01-01

    In order to improve the durability of fly ash concrete, a series of experimental studies are carried out, where durability improving admixture is used to reduce drying shrinkage and improve freezing-thawing resistance. The effects of durability improving admixture, air content, water-binder ratio, and fly ash replacement ratio on the performance of fly ash concrete are discussed in this paper. The results show that by using durability improving admixture in nonair-entraining fly ash concrete,...

  19. Long-term durability test of acid recovery evaporators made of Ti-5% Ta alloy and zirconium

    International Nuclear Information System (INIS)

    Takeuchi, Masayuki; Koizumi, Tsutomu; Koyama, Tomozo

    2001-05-01

    Mock-ups of acid recovery evaporators which are made of Ti-5% Ta alloy and Zr were tested under inactive condition for forty thousands hours to improve a corrosion resistance of acid recovery evaporator in Tokai reprocessing plant (TRP). The mock-up unit was designed and produced referring to the specification of acid recovery evaporator in TRP and the evaporation performance of the mock-up was 1/27 of TRP. A long-term durability of both evaporators was demonstrated by results of operation data, evaporation performance and corrosion resistance. The mock-up unit did not suffer from any trouble during the running test and the operation data such as temperature, flow, concentrations of nitric acid and metal ions were fairly stable within standard condition. As for the corrosion resistance, cracks and local corrosion such as intergranular attack were not observed on both evaporators after the running test, and a corrosion of weld was not selective. The average corrosion rates at measuring points were less than 0.1 mm/yr, respectively, however, thickness of the Ti-5% Ta alloy evaporator was slightly reduced at all points of vapor phase region. In addition, from the result by test coupon, it is found that both materials have low susceptibility to stress corrosion cracking in this environment. The destructive inspection showed that the mechanical properties of both materials were not degraded during the running test. Finally, the total running time of the mock-up unit is much more than a maximum running time of acid recovery evaporator made of stainless steel in TRP (nearly 15,000 hours). On the basis of the test results, an excellent durability of Ti-5% Ta alloy and Zr evaporators under was successfully demonstrated throughout the mock-up test from an engineering perspective. (author)

  20. Investigation of the Durability of a Diaphragm for a Total Artificial Heart.

    Science.gov (United States)

    Gräf, Felix; Rossbroich, Ralf; Finocchiaro, Thomas; Steinseifer, Ulrich

    2016-10-01

    One of the most critical components regarding the durability of the ReinHeart total artificial heart (TAH) is its biocompatible diaphragm, which separates the drive unit from the ventricles. Hence, a durability tester was designed to investigate its required 5-year lifetime. The aim of this study was to prove the validity of accelerated testing of the polyurethane diaphragm. The durability tester allows simultaneous testing of 12 diaphragms and mimics physiological conditions. To accelerate the time of testing, it operates with an increased speed at a frequency of 8 Hz. To prove the correctness of this acceleration, a servo-hydraulic testing machine was used to study the effect of different frequencies and their corresponding loads. Thereby the viscoelastic behavior of the polyurethane was investigated. Additionally, high-speed video measurements were performed. The force against frequency and the high-speed video measurements showed constant behavior. In the range of 1-10 Hz, the maximum resulting forces varied by 3%, and the diaphragm movement was identical. Frequencies below 10 Hz allow a valid statement of the diaphragm's mechanical durability. Viscoelasticity of the polyurethane in the considered frequency-range is negligible. The accelerated durability test is applicable to polyurethane diaphragms, and the results are applicable to TAH use. The reliability of the diaphragm for a lifetime of 5 years was found to be 80% with a confidence of 62%. Copyright © 2015 International Center for Artificial Organs and Transplantation and Wiley Periodicals, Inc.

  1. First-order model for durability of Hanford waste glasses as a function of composition

    International Nuclear Information System (INIS)

    Hrma, P.; Piepel, G.F.; Schweiger, M.J.; Smith, D.E.

    1992-04-01

    Two standard chemical durability tests, the static leach test MCC-1 and product consistency test PCT, were conducted on simulated borosilicate glasses that encompass the expected range of compositions to be produced in the Hanford Waste Vitrification Plant (HWVP). A first-order empirical model was fitted to the data from each test method. The results indicate that glass durability is increased by addition of Al 2 O 3 , moderately increased by addition of ZrO 2 and SiO 2 , and decreased by addition of Li 2 O, Na 2 O, B 2 O 3 , and MgO. Addition of Fe 2 O 3 and CaO produce an indifferent or reducing effect on durability according to the test method. This behavior and a statistically significant lack of fit are attributed to the effects of multiple chemical reactions occurring during glass-water interaction. Liquid-liquid immiscibility is suspected to be responsible for extremely low durability of some glasses

  2. Durability evaluation of reversible solid oxide cells

    Science.gov (United States)

    Zhang, Xiaoyu; O'Brien, James E.; O'Brien, Robert C.; Housley, Gregory K.

    2013-11-01

    An experimental investigation on the performance and durability of single solid oxide cells (SOCs) is under way at the Idaho National Laboratory. Reversible operation of SOCs includes electricity generation in the fuel cell mode and hydrogen generation in the electrolysis mode. Degradation is a more significant issue when operating SOCs in the electrolysis mode. In order to understand and mitigate the degradation issues in high temperature electrolysis, single SOCs with different configurations from several manufacturers have been evaluated for initial performance and long-term durability. Cells were obtained from four industrial partners. Cells from Ceramatec Inc. and Materials and Systems Research Inc. (MSRI) showed improved durability in electrolysis mode compared to previous stack tests. Cells from Saint Gobain Advanced Materials Inc. (St. Gobain) and SOFCPower Inc. demonstrated stable performance in the fuel cell mode, but rapid degradation in the electrolysis mode, especially at high current density. Electrolyte-electrode delamination was found to have a significant impact on degradation in some cases. Enhanced bonding between electrolyte and electrode and modification of the electrode microstructure helped to mitigate degradation. Polarization scans and AC impedance measurements were performed during the tests to characterize cell performance and degradation.

  3. A structural bond strength model for glass durability

    International Nuclear Information System (INIS)

    Feng, Xiangdong; Metzger, T.B.

    1996-01-01

    A glass durability model, structural bond strength (SBS) model was developed to correlate glass durability with its composition. This model assumes that the strengths of the bonds between cations and oxygens and the structural roles of the individual elements in the glass arc the predominant factors controlling the composition dependence of the chemical durability of glasses. The structural roles of oxides in glass are classified as network formers, network breakers, and intermediates. The structural roles of the oxides depend upon glass composition and the redox state of oxides. Al 2 O 3 , ZrO 2 , Fe 2 O 3 , and B 2 O 3 are assigned as network formers only when there are sufficient alkalis to bind with these oxides. CaO can also improve durability by sharing non-bridging oxygen with alkalis, relieving SiO 2 from alkalis. The percolation phenomenon in glass is also taken into account. The SBS model is applied to correlate the 7-day product consistency test durability of 42 low-level waste glasses with their composition with an R 2 of 0.87, which is better than 0.81 obtained with an eight-coefficient empirical first-order mixture model on the same data set

  4. Thermodynamic model of natural, medieval and nuclear waste glass durability

    International Nuclear Information System (INIS)

    Jantzen, C.M.; Plodinec, M.J.

    1983-01-01

    A thermodynamic model of glass durability based on hydration of structural units has been applied to natural glass, medieval window glasses, and glasses containing nuclear waste. The relative durability predicted from the calculated thermodynamics correlates directly with the experimentally observed release of structural silicon in the leaching solution in short-term laboratory tests. By choosing natural glasses and ancient glasses whose long-term performance is known, and which bracket the durability of waste glasses, the long-term stability of nuclear waste glasses can be interpolated among these materials. The current Savannah River defense waste glass formulation is as durable as natural basalt from the Hanford Reservation (10 6 years old). The thermodynamic hydration energy is shown to be related to the bond energetics of the glass. 69 references, 2 figures, 1 table

  5. Durability of building joint sealants

    Science.gov (United States)

    Christopher C. White; Kar Tean Tan; Donald L. Hunston; R. Sam Williams

    2009-01-01

    Predicting the service life of building joint sealants exposed to service environments in less than real time has been a need of the sealant community for many decades. Despite extensive research efforts to design laboratory accelerated tests to duplicate the failure modes occurring in field exposures, little success has been achieved using conventional durability...

  6. Durability of lightweight concrete : Phase II : wetting and drying tests, Phase III : freezing and thawing tests.

    Science.gov (United States)

    1966-12-01

    This report describes a laboratory research program on the durability of lightweight concrete. Two phases of a three phase study are covered by this report, while the remaining phase is still under study. The two phases being reported are Phase II - ...

  7. Durability test with fuel starvation using a Pt/CNF catalyst in PEMFC.

    Science.gov (United States)

    Jung, Juhae; Park, Byungil; Kim, Junbom

    2012-01-05

    In this study, a catalyst was synthesized on carbon nanofibers [CNFs] with a herringbone-type morphology. The Pt/CNF catalyst exhibited low hydrophilicity, low surface area, high dispersion, and high graphitic behavior on physical analysis. Electrodes (5 cm2) were prepared by a spray method, and the durability of the Pt/CNF was evaluated by fuel starvation. The performance was compared with a commercial catalyst before and after accelerated tests. The fuel starvation caused carbon corrosion with a reverse voltage drop. The polarization curve, EIS, and cyclic voltammetry were analyzed in order to characterize the electrochemical properties of the Pt/CNF. The performance of a membrane electrode assembly fabricated from the Pt/CNF was maintained, and the electrochemical surface area and cell resistance showed the same trend. Therefore, CNFs are expected to be a good support in polymer electrolyte membrane fuel cells.

  8. Durability Properties of Self Compacting Concrete containing Fly ash, Lime powder and Metakaolin

    Directory of Open Access Journals (Sweden)

    Rizwan Ahmad Khan

    2016-01-01

    Full Text Available This paper investigates the durability properties of Self-compacting concrete (SCC, with different amounts of fly ash (FA, lime powder (LP and metakaolin (MK. A total of 6 mixes were prepared that have a constant water-binder ratio (w/b of 0.41 and superplasticizer dosage of 1% by weight of cement. In addition to compressive strength, the durability properties of SCC mixes were determined by means of Initial surface absorption test (ISAT and Capillary suction test. The test results indicated that the durability properties of the mixes appeared to be very dependent on the type and amount of the mineral admixture used; the mixes containing MK were found to have considerably higher permeability resistance. Good co-relation between strength and absorption were achieved.

  9. Durability of glasses from the Hg-doped Integrated DWPF Melter System (IDMS) campaign

    International Nuclear Information System (INIS)

    Jantzen, C.M.

    1992-01-01

    The Integrated DWPF Melter System (IDMS) for the vitrification of high-level radioactive wastes is designed and constructed to be a 1/9th scale prototype of the full scale Defense Waste Processing Facility (DWPF) melter. The IDMS facility is the first engineering scale melter system capable of processing mercury, and flowsheet levels of halides and noble metals. In order to determine the effects of mercury on the feed preparation process, the off-gas chemistry, glass melting behavior, and glass durability, a three-run mercury (Hg) campaign was conducted. The glasses produced during the Hg campaign were composed of Batch 1 sludge, simulated precipitate hydrolysis aqueous product (PHA) from the Precipitate Hydrolysis Experimental Facility (PHEF), and Frit 202. The glasses were produced using the DWPF process/product models for glass durability, viscosity, and liquidus. The durability model indicated that the glasses would all be more durable than the glass qualified in the DWPF Environmental Assessment (EA). The glass quality was verified by performing the Product Consistency Test (PCT) which was designed for glass durability testing in the DWPF

  10. Predicting the durability of mineral external plaster using accelerated ageing tests; Prognose der Dauerhaftigkeit mineralischer Aussenputze mit Hilfe von beschleunigten Alterungstests

    Energy Technology Data Exchange (ETDEWEB)

    Bochen, Jerzy; Nowak, Henryk A. [Schlesische Technische Universitaet, Lehrstuhl Bauprozesse, Gliwice (Poland)

    2004-08-01

    This article presents a technique for accelerated ageing tests for different plasters. Two models were developed for describing the durability. The models describe changes in selected characteristics due to frost damage and leaching. The first model is based on changes in mass, the second on changes in strength. The models consider the main characteristics that influence durability, such as strength, porosity, permeability, adhesive tensil strength and aggressive environmental influences. Both models enable the durability of external plaster to be predicted. (Abstract Copyright [2004], Wiley Periodicals, Inc.) [German] Der Beitrag stellt eine Methode fuer beschleunigte Alterungstests von verschiedenen Putzen vor. Fuer die Beschreibung der Dauerhaftigkeit wurden zwei Modelle entwickelt. Die Modelle beschreiben Veraenderungen ausgewaehlter Eigenschaften, die infolge von Frostschaeden und Auslaugung auftreten. Das erste Modell basiert auf der Veraenderung der Masse und das zweite auf der Veraenderung der Festigkeit. In den Modellen werden die wesentlichen Eigenschaften beruecksichtigt, die die Dauerhaftigkeit beeinflussen, wie z. B. Festigkeit, Porositaet, Dichtigkeit, Haftzugfestigkeit und agressive Umwelteinwirkungen. Beide Modelle ermoeglichen die Prognose der Dauerhaftigkeit von Aussenputzen. (Abstract Copyright [2004], Wiley Periodicals, Inc.)

  11. Prognostic durability of liver fibrosis tests and improvement in predictive performance for mortality by combining tests.

    Science.gov (United States)

    Bertrais, Sandrine; Boursier, Jérôme; Ducancelle, Alexandra; Oberti, Frédéric; Fouchard-Hubert, Isabelle; Moal, Valérie; Calès, Paul

    2017-06-01

    There is currently no recommended time interval between noninvasive fibrosis measurements for monitoring chronic liver diseases. We determined how long a single liver fibrosis evaluation may accurately predict mortality, and assessed whether combining tests improves prognostic performance. We included 1559 patients with chronic liver disease and available baseline liver stiffness measurement (LSM) by Fibroscan, aspartate aminotransferase to platelet ratio index (APRI), FIB-4, Hepascore, and FibroMeter V2G . Median follow-up was 2.8 years during which 262 (16.8%) patients died, with 115 liver-related deaths. All fibrosis tests were able to predict mortality, although APRI (and FIB-4 for liver-related mortality) showed lower overall discriminative ability than the other tests (differences in Harrell's C-index: P fibrosis, 1 year in patients with significant fibrosis, and liver disease (MELD) score testing sets. In the training set, blood tests and LSM were independent predictors of all-cause mortality. The best-fit multivariate model included age, sex, LSM, and FibroMeter V2G with C-index = 0.834 (95% confidence interval, 0.803-0.862). The prognostic model for liver-related mortality included the same covariates with C-index = 0.868 (0.831-0.902). In the testing set, the multivariate models had higher prognostic accuracy than FibroMeter V2G or LSM alone for all-cause mortality and FibroMeter V2G alone for liver-related mortality. The prognostic durability of a single baseline fibrosis evaluation depends on the liver fibrosis level. Combining LSM with a blood fibrosis test improves mortality risk assessment. © 2016 Journal of Gastroenterology and Hepatology Foundation and John Wiley & Sons Australia, Ltd.

  12. Experimental study on durability improvement of fly ash concrete with durability improving admixture.

    Science.gov (United States)

    Quan, Hong-zhu; Kasami, Hideo

    2014-01-01

    In order to improve the durability of fly ash concrete, a series of experimental studies are carried out, where durability improving admixture is used to reduce drying shrinkage and improve freezing-thawing resistance. The effects of durability improving admixture, air content, water-binder ratio, and fly ash replacement ratio on the performance of fly ash concrete are discussed in this paper. The results show that by using durability improving admixture in nonair-entraining fly ash concrete, the compressive strength of fly ash concrete can be improved by 10%-20%, and the drying shrinkage is reduced by 60%. Carbonation resistance of concrete is roughly proportional to water-cement ratio regardless of water-binder ratio and fly ash replacement ratio. For the specimens cured in air for 2 weeks, the freezing-thawing resistance is improved. In addition, by making use of durability improving admixture, it is easier to control the air content and make fly ash concrete into nonair-entraining one. The quality of fly ash concrete is thereby optimized.

  13. Concrete durability

    OpenAIRE

    Gaspar Tébar, Demetrio

    1991-01-01

    The evidence that the concrete is not a material for ever was noticed from the beginning of its industrial use. In the present work, the author describes the studies carried out during the last century and the early ages of the present one, mainly devoted to the study of the durability in sea water. At the present days, and in spite of the numerous papers published from then, the study of the concrete durability continues focusing the research priorities and economical resources of rese...

  14. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    Energy Technology Data Exchange (ETDEWEB)

    Berggren, M.H.; Jha, M.C.

    1989-10-01

    AMAX Research Development Center (AMAX R D) investigated methods for enhancing the reactivity and durability of zinc ferrite desulfurization sorbents. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For this program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and oxidation. Two base case sorbents, a spherical pellet and a cylindrical extrude used in related METC-sponsored projects, were used to provide a basis for the aimed enhancement in durability and reactivity. Sorbent performance was judged on the basis of physical properties, single particle kinetic studies based on thermogravimetric (TGA) techniques, and multicycle bench-scale testing of sorbents. A sorbent grading system was utilized to quantify the characteristics of the new sorbents prepared during the program. Significant enhancements in both reactivity and durability were achieved for the spherical pellet shape over the base case formulation. Overall improvements to reactivity and durability were also made to the cylindrical extrude shape. The primary variables which were investigated during the program included iron oxide type, zinc oxide:iron oxide ratio, inorganic binder concentration, organic binder concentration, and induration conditions. The effects of some variables were small or inconclusive. Based on TGA studies and bench-scale tests, induration conditions were found to be very significant.

  15. Effect of Soorh Metakaolin on Concrete Compressive Strength and Durability

    Directory of Open Access Journals (Sweden)

    A. Saand

    2017-12-01

    Full Text Available Concrete durability is a key aspect for forecasting the expected life time of concrete structures. In this paper, the effect of compressive strength and durability of concrete containing metakaolin developed from a local natural material (Soorh of Thatta Distict of Sindh, Pakistan is investigated. Soorh is calcined by an electric furnace at 8000C for 2 hours to produce metakaolin. One mix of ordinary concrete and five mixes of metakaolin concrete were prepared, where cement is replaced by developed metakaolin from 5% to 25% by weight, with 5% increment step. The concrete durability was tested for water penetration, carbonation depth and corrosion resistance. The obtained outcomes demonstrated that, 15% replacement level of local developed metakaolin presents considerable improvements in concrete properties. Moreover, a considerable linear relationship was established between compressive strength and concrete durability indicators like water penetration, carbonation depth and corrosion resistance.

  16. Temperature induced effects on the durability of MR fluids

    International Nuclear Information System (INIS)

    Wiehe, A; Maas, J; Kieburg, C

    2013-01-01

    Although commercial MR fluids exist for quite some time now and the feasibility as well as the advantages of the MR technology have been demonstrated for several applications by a variety of MR actuator prototypes, a sustainable market break-through of brake and clutch applications utilizing the shear mode is still missing. Essential impediments are the marginal knowledge about the durability of the MR technology. To overcome this situation, a long-term measurement system was developed for the durability analysis of MR fluid formulations within a technical relevant scale with respect to the volume of MR fluid and the transmitted torque. The focus of the presented series of measurements is given to the analysis of temperature induced effects on the durability. In this context four different failure indicators can be distinguished, namely an apparent negative viscosity, deviations in torque data obtained from different measurements as well as a pressure increase and a drop in the on-state torque. The measurement data of the present durability experiments indicate a significant dependency of the attainable energy intake density on the temperature. The aim of such durability tests is to establish a reliable data base for the industry to estimate the life-time of MR devices.

  17. Concrete aggregate durability study.

    Science.gov (United States)

    2009-06-01

    There are many factors that affect the durability of Portland cement concrete (PCC), including the mix design and the : materials used, the quality of construction, and the environment. Durability is not an intrinsic property of the concrete, but : i...

  18. Highly Dispersed Alloy Catalyst for Durability

    Energy Technology Data Exchange (ETDEWEB)

    Murthi, Vivek S.; Izzo, Elise; Bi, Wu; Guerrero, Sandra; Protsailo, Lesia

    2013-01-08

    Achieving DOE's stated 5000-hr durability goal for light-duty vehicles by 2015 will require MEAs with characteristics that are beyond the current state of the art. Significant effort was placed on developing advanced durable cathode catalysts to arrive at the best possible electrode for high performance and durability, as well as developing manufacturing processes that yield significant cost benefit. Accordingly, the overall goal of this project was to develop and construct advanced MEAs that will improve performance and durability while reducing the cost of PEMFC stacks. The project, led by UTC Power, focused on developing new catalysts/supports and integrating them with existing materials (membranes and gas diffusion layers (GDLs)) using state-of-the-art fabrication methods capable of meeting the durability requirements essential for automotive applications. Specifically, the project work aimed to lower platinum group metals (PGM) loading while increasing performance and durability. Appropriate catalysts and MEA configuration were down-selected that protects the membrane, and the layers were tailored to optimize the movements of reactants and product water through the cell to maximize performance while maintaining durability.

  19. Durability of building materials and components

    CERN Document Server

    Delgado, JMPQ

    2013-01-01

    Durability of Building Materials and Components provides a collection of recent research works to contribute to the systematization and dissemination of knowledge related to the long-term performance and durability of construction and, simultaneously, to show the most recent advances in this domain. It includes a set of new developments in the field of durability, service life prediction methodologies, the durability approach for historical and old buildings, asset and maintenance management and on the durability of materials, systems and components. The book is divided in several chapters that intend to be a resume of the current state of knowledge for benefit of professional colleagues.

  20. The effect of compositional parameters on the TCLP and PCT durability of environmental glasses

    International Nuclear Information System (INIS)

    Resce, J.L.; Overcamp, T.J.

    1995-01-01

    The relationship between glass composition and the chemical durability of environmental waste glass is very important for both the development of glass formulations and the prediction of glass durability for process control. The development of such a model is extremely difficult for several reasons. Firstly, chemical durability is dependent upon the type of leach test employed; the leach tests themselves being only crude approximations of actual environmental conditions or long term behavior. Secondly, devitrification or crystallinity can also play a major role in durability, but is much more difficult to quantify. Lastly, the development of any one model for all glass types is impractical because of the wide variety of wastestreams, the heterogeneity of the wastestreams, and the large variety of components within each wastestream. Several ongoing efforts have been directed toward this goal, but as yet, no model has been proven acceptable

  1. Results of testing the Grambow rate law for use in HWVP glass durability correlations

    International Nuclear Information System (INIS)

    Kuhn, W.L.; Bunnell, L.R.

    1996-03-01

    A theory based on Grambow's work on hydration of glass as linear function of solution composition was evaluated. Use of Grambow's linear rate law for correlation of durability with glass composition is not recommended. Dissolution rate of the glass was determined using the rate of release of sodium with an ion selective electrode. This method was tested first applying it to initial dissolution rate of several glasses at several temperatures with zero initial concentration of silicic acid. HW39-2, HW39-4, and SRL-202 from Savannah River were tested; there was significant scatter in the data, with the dissolution rates of HW39 glasses and the SRL glass being comparable within this scatter. The dissolution rate of SRL-202 at 80 C and pH 7 for silicic acid concentrations 0, 25, 50, and 100% saturation, was found to decrease dramatically at only 25% of the saturated silicic acid concentration, which does not conform to the linear theory

  2. MINERALIZATION OF RADIOACTIVE WASTES BY FLUIDIZED BED STEAM REFORMING (FBSR): COMPARISONS TO VITREOUS WASTE FORMS, AND PERTINENT DURABILITY TESTING

    International Nuclear Information System (INIS)

    Jantzen, C.

    2008-01-01

    The Savannah River National Laboratory (SRNL) was requested to generate a document for the Washington State Department of Ecology and the U.S. Environmental Protection Agency that would cover the following topics: (1) A description of the mineral structures produced by Fluidized Bed Steam Reforming (FBSR) of Hanford type Low Activity Waste (LAW including LAWR which is LAW melter recycle waste) waste, especially the cage structured minerals and how they are formed. (2) How the cage structured minerals contain some contaminants, while others become part of the mineral structure (Note that all contaminants become part of the mineral structure and this will be described in the subsequent sections of this report). (3) Possible contaminant release mechanisms from the mineral structures. (4) Appropriate analyses to evaluate these release mechanisms. (5) Why the appropriate analyses are comparable to the existing Hanford glass dataset. In order to discuss the mineral structures and how they bond contaminants a brief description of the structures of both mineral (ceramic) and vitreous waste forms will be given to show their similarities. By demonstrating the similarities of mineral and vitreous waste forms on atomic level, the contaminant release mechanisms of the crystalline (mineral) and amorphous (glass) waste forms can be compared. This will then logically lead to the discussion of why many of the analyses used to evaluate vitreous waste forms and glass-ceramics (also known as glass composite materials) are appropriate for determining the release mechanisms of LAW/LAWR mineral waste forms and how the durability data on LAW/LAWR mineral waste forms relate to the durability data for LAW/LAWR glasses. The text will discuss the LAW mineral waste form made by FBSR. The nanoscale mechanism by which the minerals form will be also be described in the text. The appropriate analyses to evaluate contaminant release mechanisms will be discussed, as will the FBSR test results to

  3. Mixed hydrocarbon/fluoropolymer membrane/ionomer MEAs for durability studies

    Energy Technology Data Exchange (ETDEWEB)

    Li, Bo [Los Alamos National Laboratory; Kim, Yu Seung [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Borup, Rodney L [Los Alamos National Laboratory; Wilson, Mahlon S [Los Alamos National Laboratory; Welch, Cynthia [Los Alamos National Laboratory; Fenton, James [FLORIDA SOLAR ENERGY CENTER

    2010-01-01

    The durability of polymer electrolyte membrane (PEM) fuel cells is a major barrier to the commercialization of these systems for stationary and transportation power applications. Commercial viability depends on improving the durability of the fuel cell components to increase the system reliability. The aim of this work is to separate ionomer degradation from membrane degradation via mixed membrane/ionomer MEA experiments. The challenges of mixed MEA fabrication due to the incompatibility of the membrane and the electrode are addressed. OCV accelerated testing experiment (AST) were performed. Development of in situ diagnostics and unique experiments to characterize the performance and properties of the ionomer in the electrode as a function of time is reported. These measurements, along with extensive ex situ and post-mortem characterization, can delineate the degradation mechanisms in order to develop more durable fuel cells and fuel cell components.

  4. Atlas 25+太阳能光伏组件耐久性综合试验[1]介绍%Introduction of Durability Test for Atlas 25+Solar Photovoltaic Modules

    Institute of Scientific and Technical Information of China (English)

    江鲁; 冯江涛

    2013-01-01

    Solar photovoltaic plays an important role in world energy. Although it has been fully aware in the industry that the durability is the most important factor affecting the economy of solar PV power generation. there were no appropriate methods to evaluate the durability of PV modules in the past. By taking advantage of the years’ experience on the weathering , the Atlas company summarized its twenty-five years study in the field of climate test for photovoltaic and solar materials, and developed Atlas 25+ PV module durability test (durability test for short). Durability test has proposed the concept of “Global Composite” towards a major aging failure model for PV modules. It combines the advantages of the lab test and outdoor test by considering the effects of both short-term and long-term typical climate on aging failure. In order to give some reference and help to the researchers, who engaged in material and product durability test and the lifetime estimating, the durability test is introduced in this paper.%太阳能光伏组件发电对于世界能源的重要性是毋庸置疑的。虽然业内已经充分地认识到耐久性是影响太阳能光伏组件发电经济性的最重要的方面,但过去一直没有一个可用于评价太阳能光伏组件耐久性的试验方法。Atlas利用其在多年环境气候试验方面的经验,并总结其二十五年以上在光伏和太阳能材料气候试验领域的研究成果,开发了Atlas 25+太阳能光伏组件耐久性综合试验(文中简称光伏组件耐久性试验)。该方法提出了“全球组合气候”的概念,面向太阳能光伏组件主要的老化失效模型,兼顾典型气候的短期和长期对失效老化的影响,综合了人工环境试验与自然环境试验的优点。本文对光伏组件耐久性试验作一介绍,希望对从事材料和产品耐久性试验和寿命预估的研究人员有所启发和帮助。

  5. Durability of fibre reinforced concrete structures

    DEFF Research Database (Denmark)

    Hansen, Ernst Jan De Place; Hansen, Kurt Kielsgaard

    1996-01-01

    The planned research will indicate, whether fibre reinforced concrete has better or worse durability than normal concrete. Durability specimens will be measured on cracked as well as uncracked specimens. Also the pore structure in the concrete will be characterized.Keywords: Fibre reinforced...... concrete, durability, pore structure, mechanical load...

  6. Durability of ITO-MgF2 Films for Space-Inflatable Polymer Structures

    Science.gov (United States)

    Kerslake, Thomas W.; Waters, Deborah L.; Schieman, David A.; Hambourger, Paul D.

    2003-01-01

    This paper presents results from ITO-MgF2 film durability evaluations that included tape peel, fold, thermal cycle, and AO exposure testing. Polymer coupon preparation is described as well as ITO-MgF2 film deposition equipment, procedures and film characterization. Durability testing methods are also described. The pre- and post-test condition of the films is assessed visually, microscopically, and electrically. Results show that at 500 ITO - 9 vol% MgF2 film is suitable to protect polymer surfaces, such as those used in space-inflatable structures of the PowerSphere microsatellite concept, during a 1-year Earth orbiting mission. Future plans for ground-based and orbital testing of this film are also discussed.

  7. Evolution of Durable High-Strength Flowable Mortar Reinforced with Hybrid Fibers

    OpenAIRE

    Dawood, Eethar Thanon; Ramli, Mahyuddin

    2012-01-01

    The production and use of durable materials in construction are considered as one of the most challenging things for the professional engineers. Therefore, this research was conducted to investigate the mechanical properties and the durability by using of different percentages of steel fiber with high-strength flowable mortar (HSFM) and also the use of the hybridization of steel fibers, palm fibers, and synthetic fiber (Barchip). Different experimental tests (compressive strength, splitting t...

  8. Durability studies on the high calcium flyash based GPC

    African Journals Online (AJOL)

    Keywords: Geopolymer concrete, high calcium flyash, durability, corrosion resistance, polarisation test. ... Reddy, et al (2011) reported that excellent resistance to chloride .... being the metal on the higher electro potential range, to the negative ...

  9. Durability of coconut shell powder (CSP) concrete

    Science.gov (United States)

    Leman, A. S.; Shahidan, S.; Senin, M. S.; Shamsuddin, S. M.; Anak Guntor, N. A.; Zuki, S. S. Mohd; Khalid, F. S.; Azhar, A. T. S.; Razak, N. H. S.

    2017-11-01

    The rising cost of construction in developing countries like Malaysia has led concrete experts to explore alternative materials such as coconut shells which are renewable and possess high potential to be used as construction material. Coconut shell powder in varying percentages of1%, 3% and 5% was used as filler material in concrete grade 30 and evaluated after a curing period of 7 days and 28days respectively. Compressive strength, water absorption and carbonation tests were conducted to evaluate the strength and durability of CSP concrete in comparison with normal concrete. The test results revealed that 1%, 3% and 5% of CSP concrete achieved a compressive strength of 47.65 MPa, 45.6 MPa and 40.55% respectively. The rate of water absorption of CSP concrete was recorded as 3.21%, 2.47%, and 2.73% for 1%, 3% and 5% of CSP concrete respectively. Although CSP contained a carbon composition of 47%, the carbonation test showed that CSP no signs of carbon were detected inside the concrete. To conclude, CSP offers great prospects as it demonstrated relatively high durability as a construction material.

  10. Durability Properties of Palm Oil Fuel Ash Self Compacting Concrete

    Directory of Open Access Journals (Sweden)

    T. Ofuyatan

    2015-02-01

    Full Text Available Self Compacting Concrete (SCC is a new innovation in technology that can flow readily into place under its own self weight and fill corner areas of reinforcement structures without the need to vibrate and without segregation of its constitute. The problem of durability of concrete structures due to inadequate compaction by skilled workers has become a source of concern globally. The shortage of skilled manpower, noise and vibration of equipment on construction sites has led to the development of self compacting concrete. This paper presents an experimental study on the durability properties of Self Compacting Concrete with partial placement of Palm Oil Fuel Ash (POFA. Twelve POFA self-compacting concretes of various strength grades were designed at varying percentages of 0, 5, 10, 15, 20, 25 and 30%. The concrete with no placement of ash served as control. Conplast SP432MS was used as superplasticiser in the mix. The experiments are carried out by adopting a water-powder ratio of 0.36. Workability of the fresh concrete is determined by using tests such as: slump flow, T50, V-funnel and L-Box tests. The durability of concrete is tested by acid resistance, sulphate attack and saturated water absorption at the age of 14, 28, 56 and 90 days.

  11. Freeze-thaw durability of air-entrained concrete.

    Science.gov (United States)

    Shang, Huai-Shuai; Yi, Ting-Hua

    2013-01-01

    One of the most damaging actions affecting concrete is the abrupt temperature change (freeze-thaw cycles). The types of deterioration of concrete structures by cyclic freeze-thaw can be largely classified into surface scaling (characterized by the weight loss) and internal crack growth (characterized by the loss of dynamic modulus of elasticity). The present study explored the durability of concrete made with air-entraining agent subjected to 0, 100, 200, 300, and 400 cycles of freeze-thaw. The experimental study of C20, C25, C30, C40, and C50 air-entrained concrete specimens was completed according to "the test method of long-term and durability on ordinary concrete" GB/T 50082-2009. The dynamic modulus of elasticity and weight loss of specimens were measured after different cycles of freeze-thaw. The influence of freeze-thaw cycles on the relative dynamic modulus of elasticity and weight loss was analyzed. The findings showed that the dynamic modulus of elasticity and weight decreased as the freeze-thaw cycles were repeated. They revealed that the C30, C40, and C50 air-entrained concrete was still durable after 300 cycles of freeze-thaw according to the experimental results.

  12. Durability Indicators Comparison for SCC and CC in Tropical Coastal Environments.

    Science.gov (United States)

    Calado, Carlos; Camões, Aires; Monteiro, Eliana; Helene, Paulo; Barkokébas, Béda

    2015-03-27

    Self-compacting concrete (SCC) demands more studies of durability at higher temperatures when subjected to more aggressive environments in comparison to the conventional vibrated concrete (CC). This work aims at presenting results of durability indicators of SCC and CC, having the same water/binder relations and constituents. The applied methodologies were electrical resistivity, diffusion of chloride ions and accelerated carbonation experiments, among others, such as microstructure study, scanning electron microscope and microtomography experiments. The tests were performed in a research laboratory and at a construction site of the Pernambuco Arena. The obtained results shows that the SCC presents an average electrical resistivity 11.4% higher than CC; the average chloride ions diffusion was 63.3% of the CC; the average accelerated carbonation penetration was 45.8% of the CC; and the average open porosity was 55.6% of the CC. As the results demonstrated, the SCC can be more durable than CC, which contributes to elucidate the aspects related to its durability and consequent prolonged life cycle.

  13. Advanced Face Gear Surface Durability Evaluations

    Science.gov (United States)

    Lewicki, David G.; Heath, Gregory F.

    2016-01-01

    The surface durability life of helical face gears and isotropic super-finished (ISF) face gears was investigated. Experimental fatigue tests were performed at the NASA Glenn Research Center. Endurance tests were performed on 10 sets of helical face gears in mesh with tapered involute helical pinions, and 10 sets of ISF-enhanced straight face gears in mesh with tapered involute spur pinions. The results were compared to previous tests on straight face gears. The life of the ISF configuration was slightly less than that of previous tests on straight face gears. The life of the ISF configuration was slightly greater than that of the helical configuration.

  14. Influence of the leaching mode on the durability of a glass for fission product containment

    International Nuclear Information System (INIS)

    Nogues, J.L.; Terki, A.

    1984-06-01

    The chemical durability of a glass containing wastes from light water reactor (LWR) has been studied with three different lixiviation modes: ''static'' leach test, ''soxhlet'' test and ''continuous flow'' test. After a description of these tests, the leaching mode influence on the glass durability is reported as obtained from weight loss measurements, analyses of the leaching solutions and surface analyses of the samples. Finally, the corrosion mechanisms of this type of glass are approached and a phenomenological explanation of attack from an aqueous solution is proposed [fr

  15. Durability aspects of high-performance concretes for a waste repository. Appendix 3: Canada

    International Nuclear Information System (INIS)

    Philipose, K.E.

    2001-01-01

    The IRUS facility for the disposal of low level radioactive waste at the Chalk River Nuclear Laboratories in Ontario, Canada relies on the durability of concrete for the required 500 years of service life. A research programme based on laboratory testing to design a durable concrete and assess its long-term behaviour was initiated in 1988. This appendix discusses the methodology to assess the long-term behaviour of concrete, and some initial observations. Longevity predictions for concrete formulations based on diffusion testing are also presented

  16. Effects of biodiesel on emissions of regulated air pollutants and polycyclic aromatic hydrocarbons under engine durability testing

    International Nuclear Information System (INIS)

    Hsi-Hsien Yang; Shu-Mei Chien; Mei-Yu Lo; John Chi-Wei Lan; Wen-Chang Lu; Yong-Yuan Ku

    2007-01-01

    An 80,000-km durability test was performed on two engines using diesel and biodiesel (methyl ester of waste cooking oil) as fuel in order to examine emissions resulting from the use of biodiesel. The test biodiesel (B20) was blended with 80% diesel and 20% methyl ester derived from waste cooking oil. Emissions of regulated air pollutants, including CO, HC, NO x , particulate matter (PM) and polycyclic aromatic hydrocarbons (PAHs) were measured at 20,000-km intervals. The identical-model engines were installed on a standard dynamometer equipped with a dilution tunnel used to measure the pollutants. To simulate real-world driving conditions, emission measurements were made in accordance with the United States Environmental Protection Agency (USEPA) FTP transient cycle guidelines. At 0 km of the durability test, HC, CO and PM emission levels were lower for the B20 engine than those for diesel. After running for 20,000 km and longer, they were higher. However, the deterioration coefficients for these regulated air pollutants were not statistically higher than 1.0, implying that the emission factors do not increase significantly after 80,000 km of driving. Total (gaseous+particulate phase) PAH emission levels for both B20 and diesel decreased as the driving mileage accumulated. However, for the engine using B20 fuel, particulate PAH emissions increased as engine mileage increased. The average total PAH emission factors were 1097 and 1437 μg bhp h -1 for B20 and diesel, respectively. For B20, the benzo[a]pyrene equivalence emission factors were 0.77, 0.24, 0.20, 7.48, 5.43 and 14.1 μg bhp h -1 for 2-, 3-, 4-, 5-, 6-ringed and total PAHs. Results show that B20 use can reduce both PAH emission and its corresponding carcinogenic potency. (author)

  17. Effects of biodiesel on emissions of regulated air pollutants and polycyclic aromatic hydrocarbons under engine durability testing

    Energy Technology Data Exchange (ETDEWEB)

    Hsi-Hsien Yang; Shu-Mei Chien; Mei-Yu Lo [Chaoyang University of Technology, Wufong (China). Dept. of Environmental Engineering and Management; John Chi-Wei Lan [Yuan Ze University (China). Dept. of Chemical Engineering and Materials Science; Wen-Chang Lu [Industrial Technology Research Institute, Hsinchu (China). New Energy Div.; Yong-Yuan Ku [Automotive Research and Testing Center, Chunhwa (China). Diesel Vehicle Section

    2007-11-15

    An 80,000-km durability test was performed on two engines using diesel and biodiesel (methyl ester of waste cooking oil) as fuel in order to examine emissions resulting from the use of biodiesel. The test biodiesel (B20) was blended with 80% diesel and 20% methyl ester derived from waste cooking oil. Emissions of regulated air pollutants, including CO, HC, NO{sub x}, particulate matter (PM) and polycyclic aromatic hydrocarbons (PAHs) were measured at 20,000-km intervals. The identical-model engines were installed on a standard dynamometer equipped with a dilution tunnel used to measure the pollutants. To simulate real-world driving conditions, emission measurements were made in accordance with the United States Environmental Protection Agency (USEPA) FTP transient cycle guidelines. At 0 km of the durability test, HC, CO and PM emission levels were lower for the B20 engine than those for diesel. After running for 20,000 km and longer, they were higher. However, the deterioration coefficients for these regulated air pollutants were not statistically higher than 1.0, implying that the emission factors do not increase significantly after 80,000 km of driving. Total (gaseous+particulate phase) PAH emission levels for both B20 and diesel decreased as the driving mileage accumulated. However, for the engine using B20 fuel, particulate PAH emissions increased as engine mileage increased. The average total PAH emission factors were 1097 and 1437 {mu}g bhp h{sup -1} for B20 and diesel, respectively. For B20, the benzo[a]pyrene equivalence emission factors were 0.77, 0.24, 0.20, 7.48, 5.43 and 14.1 {mu}g bhp h{sup -1} for 2-, 3-, 4-, 5-, 6-ringed and total PAHs. Results show that B20 use can reduce both PAH emission and its corresponding carcinogenic potency. (author)

  18. Durability of low-pH injection grout. A literature survey

    International Nuclear Information System (INIS)

    Holt, E.

    2008-01-01

    This publication provides an overview of the durability of injection grouts. It is intended for use during planning and construction at the ONKALO underground research facility. The review has been done with respect to the application conditions, materials and service life requirements expressed by Posiva Oy. The publication describes all types of cement-based material durability, with an emphasis on the key issues of shrinkage cracking, leaching and sulphate attack. The second part of the report provides information on how durability expectations have changed with the history of injection grout development. The report gives information specific to low-pH injection grouts containing high amounts of silica fume performance and how their durability is expected to differ from traditional normal cement-based mixtures. The final part of the report provides suggestions for future research needs for ensuring the service life of injection grouts. The key finding from this study is that the low-pH grout material is not expected to have worse durability performance compared to the standard injection grout. Combining high amounts of silica fume with the cement to produce low-pH grout should result in a material having lower permeability and thus greater resistance to leaching and chemical attack. Further laboratory testing is needed to quantitatively verify these findings and to provide inputs for future service life modeling. (orig.)

  19. Recent advances in the mechanical durability of superhydrophobic materials.

    Science.gov (United States)

    Milionis, Athanasios; Loth, Eric; Bayer, Ilker S

    2016-03-01

    Large majority of superhydrophobic surfaces have very limited mechanical wear robustness and long-term durability. This problem has restricted their utilization in commercial or industrial applications and resulted in extensive research efforts on improving resistance against various types of wear damage. In this review, advances and developments since 2011 in this field will be covered. As such, we summarize progress on fabrication, design and understanding of mechanically durable superhydrophobic surfaces. This includes an overview of recently published diagnostic techniques for probing and demonstrating tribo-mechanical durability against wear and abrasion as well as other effects such as solid/liquid spray or jet impact and underwater resistance. The review is organized in terms of various types of mechanical wear ranging from substrate adhesion, tangential surface abrasion, and dynamic impact to ultrasonic processing underwater. In each of these categories, we highlight the most successful approaches to produce robust surfaces that can maintain their non-wetting state after the wear or abrasive action. Finally, various recommendations for improvement of mechanical wear durability and its quantitative evaluation are discussed along with potential future directions towards more systematic testing methods which will also be acceptable for industry. Copyright © 2015 Elsevier B.V. All rights reserved.

  20. Durability and damage tolerance of Large Composite Primary Aircraft Structure (LCPAS)

    Science.gov (United States)

    Mccarty, John E.; Roeseler, William G.

    1984-01-01

    Analysis and testing addressing the key technology areas of durability and damage tolerance were completed for wing surface panels. The wing of a fuel-efficient, 200-passenger commercial transport airplane for 1990 delivery was sized using graphite-epoxy materials. Coupons of various layups used in the wing sizing were tested in tension, compression, and spectrum fatigue with typical fastener penetrations. The compression strength after barely visible impact damage was determined from coupon and structural element tests. One current material system and one toughened system were evaluated by coupon testing. The results of the coupon and element tests were used to design three distinctly different compression panels meeting the strength, stiffness, and damage-tolerance requirements of the upper wing panels. These three concepts were tested with various amounts of damage ranging from barely visible impact to through-penetration. The results of this program provide the key technology data required to assess the durability and damage-tolerance capability or advanced composites for use in commercial aircraft wing panel structure.

  1. Hygrothermal Behavior, Building Pathology and Durability

    CERN Document Server

    Delgado, JMPQ

    2013-01-01

    The main purpose of this book, Hygrothermal, Building Pathology and Durability, is to provide a collection of recent research works to contribute to the systematization and dissemination of knowledge related to construction pathology, hygrothermal behaviour of buildings, durability and diagnostic techniques and, simultaneously, to show the most recent advances in this domain. It includes a set of new developments in the field of building physics and hygrothermal behaviour, durability approach for historical and old buildings and building pathology vs. durability. The book is divided in several chapters that are a resume of the current state of knowledge for benefit of professional colleagues, scientists, students, practitioners, lecturers and other interested parties to network.

  2. Monetary Policy with Sectoral Linkages and Durable Goods

    DEFF Research Database (Denmark)

    Petrella, Ivan; Rossi, Raffaele; Santoro, Emiliano

    We study the normative implications of a New Keynesian model featuring intersectoral trade of intermediate goods between two sectors that produce durables and non-durables. The interplay between durability and sectoral production linkages fundamentally alters the intersectoral stabilization trade....... Aggregating durable and non-durable inflation depending on the relative degrees of sectoral price stickiness may induce a severe bias. Input materials attenuate the response of sectoral inflations to movements in the real marginal costs, so that the effective slopes of the sectoral supply schedules...

  3. Freeze-Thaw Durability of Air-Entrained Concrete

    Directory of Open Access Journals (Sweden)

    Huai-Shuai Shang

    2013-01-01

    Full Text Available One of the most damaging actions affecting concrete is the abrupt temperature change (freeze-thaw cycles. The types of deterioration of concrete structures by cyclic freeze-thaw can be largely classified into surface scaling (characterized by the weight loss and internal crack growth (characterized by the loss of dynamic modulus of elasticity. The present study explored the durability of concrete made with air-entraining agent subjected to 0, 100, 200, 300, and 400 cycles of freeze-thaw. The experimental study of C20, C25, C30, C40, and C50 air-entrained concrete specimens was completed according to “the test method of long-term and durability on ordinary concrete” GB/T 50082-2009. The dynamic modulus of elasticity and weight loss of specimens were measured after different cycles of freeze-thaw. The influence of freeze-thaw cycles on the relative dynamic modulus of elasticity and weight loss was analyzed. The findings showed that the dynamic modulus of elasticity and weight decreased as the freeze-thaw cycles were repeated. They revealed that the C30, C40, and C50 air-entrained concrete was still durable after 300 cycles of freeze-thaw according to the experimental results.

  4. Durability Indicators Comparison for SCC and CC in Tropical Coastal Environments

    Directory of Open Access Journals (Sweden)

    Carlos Calado

    2015-03-01

    Full Text Available Self-compacting concrete (SCC demands more studies of durability at higher temperatures when subjected to more aggressive environments in comparison to the conventional vibrated concrete (CC. This work aims at presenting results of durability indicators of SCC and CC, having the same water/binder relations and constituents. The applied methodologies were electrical resistivity, diffusion of chloride ions and accelerated carbonation experiments, among others, such as microstructure study, scanning electron microscope and microtomography experiments. The tests were performed in a research laboratory and at a construction site of the Pernambuco Arena. The obtained results shows that the SCC presents an average electrical resistivity 11.4% higher than CC; the average chloride ions diffusion was 63.3% of the CC; the average accelerated carbonation penetration was 45.8% of the CC; and the average open porosity was 55.6% of the CC. As the results demonstrated, the SCC can be more durable than CC, which contributes to elucidate the aspects related to its durability and consequent prolonged life cycle.

  5. Effect of manufactured sand on the durability characteristics of concrete

    Directory of Open Access Journals (Sweden)

    S. S. SARAVANAN

    2016-12-01

    Full Text Available Concrete is the most sought after material due to increase in construction activities and infrastructural developments. Availability of natural sand is decreasing thereby increase in the cost of construction. In the present work undertaken, an attempt has been made to give an alternative to natural sand. Optimization of replacement of natural sand with manufactured sand in concrete, durability studies such as water absorption, rapid chloride permeability test, sorptivity, acid resistance, alkaline resistance, impact resistance and abrasion resistance of M40 and M50 grades of concrete have been studied with manufactured sand as fine aggregate and compared the results with the conventional sand concrete. The results shows that there is an increase in the durability properties up to 70 % level of replacements of sand with manufactured sand as fine aggregate and for 100 % use of manufactured sand also gives the better durability than the conventional sand concrete.

  6. Durability Improvements Through Degradation Mechanism Studies

    Energy Technology Data Exchange (ETDEWEB)

    Borup, Rodney L. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mukundan, Rangachary [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Spernjak, Dusan [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Baker, Andrew M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Lujan, Roger W. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Langlois, David Alan [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Ahluwalia, Rajesh [Argonne National Lab. (ANL), Argonne, IL (United States); Papadia, D. D. [Argonne National Lab. (ANL), Argonne, IL (United States); Weber, Adam Z. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kusoglu, Ahmet [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Shi, Shouwnen [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); More, K. L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Grot, Steve [Ion Power, New Castle, DE (United States)

    2015-08-03

    The durability of polymer electrolyte membrane (PEM) fuel cells is a major barrier to the commercialization of these systems for stationary and transportation power applications. By investigating cell component degradation modes and defining the fundamental degradation mechanisms of components and component interactions, new materials can be designed to improve durability. To achieve a deeper understanding of PEM fuel cell durability and component degradation mechanisms, we utilize a multi-institutional and multi-disciplinary team with significant experience investigating these phenomena.

  7. Durability assessment to environmental impact of nano-structured consolidants on Carrara marble by field exposure tests.

    Science.gov (United States)

    Bonazza, Alessandra; Vidorni, Giorgia; Natali, Irene; Ciantelli, Chiara; Giosuè, Chiara; Tittarelli, Francesca

    2017-01-01

    The EU policy of reducing the emissions of combustion generated pollutants entails climate induced deterioration to become more important. Moreover, products applied to preserve outdoor built heritage and their preliminary performance tests often turn out to be improper. In such context, the paper reports the outcomes of the methodology adopted to assess the durability and efficiency of nano-based consolidating products utilized for the conservation of carbonate artworks, performing field exposure tests on Carrara marble model samples in different sites in the framework of the EC Project NANOMATCH. Surface properties and cohesion, extent and penetration of the conservative products and their interactions with marble substrates and environmental conditions are here examined after outdoor exposure for eleven months in four different European cities and compared with the features of undamaged and of untreated damaged specimens undergoing the same exposure settings. Copyright © 2016 Elsevier B.V. All rights reserved.

  8. Compositional threshold for Nuclear Waste Glass Durability

    International Nuclear Information System (INIS)

    Kruger, Albert A.; Farooqi, Rahmatullah; Hrma, Pavel R.

    2013-01-01

    Within the composition space of glasses, a distinct threshold appears to exist that separates 'good' glasses, i.e., those which are sufficiently durable, from 'bad' glasses of a low durability. The objective of our research is to clarify the origin of this threshold by exploring the relationship between glass composition, glass structure and chemical durability around the threshold region

  9. Beta cloth durability assessment for Space Station Freedom (SSF) Multi-Layer Insulation (MLI) blanket covers

    International Nuclear Information System (INIS)

    Koontz, S.L.; Jacobs, S.; Le, J.

    1993-03-01

    MLI blankets for the Space Station Freedom (SSF) must comply with general program requirements and recommendations for long life and durability in the low-Earth orbit (LEO) environment. Atomic oxygen and solar ultraviolet/vacuum ultraviolet are the most important factors in the SSF natural environment which affect materials life. Two types of Beta cloth (Teflon coated woven glass fabric), which had been proposed as MLI blanket covers, were tested for long-term durability in the LEO environment. General resistance to atomic oxygen attack and permeation were evaluated in the high velocity atomic oxygen beam system at Los Alamos National Laboratories. Long-term exposure to the LEO environment was simulated in the laboratory using a radio frequency oxygen plasma asher. The plasma asher treated Beta cloth specimens were tested for thermo-optical properties and mechanical durability. Space exposure data from the Long Duration Exposure Facility and the Intelsat Solar Array Coupon were also used in the durability assessment. Beta cloth fabricated to Rockwell specification MBO 135-027 (Chemglas 250) was shown to have acceptable durability for general use as an MLI blanket cover material in the LEO environment while Sheldahl G414500 should be used only in locations which are protected from direct Ram atomic oxygen

  10. Durability studies on the high calcium flyash based GPC ...

    African Journals Online (AJOL)

    Three different grades namely GM20, GM30 and GM40 are designed and common durability related properties like water absorption, acid resitance and corrosion resistance by constant voltage polarization test are determined using relevant concrete specimens and compared with similar grades of conventional concrete.

  11. Follow-up durability measurements and mitigation-performance improvement tests in 38 Eastern Pennsylvania houses having indoor radon-reduction systems. Final report, Oct 89-Feb 90

    International Nuclear Information System (INIS)

    Findlay, W.O.; Robertson, A.; Scott, A.G.

    1991-03-01

    The report gives results of follow-up tests in 38 difficult-to-mitigate Pennsylvania houses where indoor radon reduction systems had been installed 2 to 4 years earlier. Objectives were to assess system durability, methods for improving performance, and methods for reducing installation and operating costs. The durability tests indicated that the 38 systems have not experienced any significant degradation in indoor radon levels or in system flows/suctions, except in 6 houses where system fans failed, and in houses where homeowners turned off the systems. Tests to improve performance indicated that nearly all of the elevated residual radon levels are due to re-entrainment back into the house of very-high-radon exhaust gas from the soil depressurization systems, and to radon release from well water. Tests to reduce system costs showed that premitigation sub-slab suction field measurements can help prevent installation of too many suction pipes when communication is good, but suggest a need for too many pipes when communication is poor. Soil depressurization fans could not be turned down to the extent expected in some systems that were over-designed. Between 6 and 42% of the exhausted air was withdrawn from the house

  12. Glycogen with short average chain length enhances bacterial durability

    Science.gov (United States)

    Wang, Liang; Wise, Michael J.

    2011-09-01

    Glycogen is conventionally viewed as an energy reserve that can be rapidly mobilized for ATP production in higher organisms. However, several studies have noted that glycogen with short average chain length in some bacteria is degraded very slowly. In addition, slow utilization of glycogen is correlated with bacterial viability, that is, the slower the glycogen breakdown rate, the longer the bacterial survival time in the external environment under starvation conditions. We call that a durable energy storage mechanism (DESM). In this review, evidence from microbiology, biochemistry, and molecular biology will be assembled to support the hypothesis of glycogen as a durable energy storage compound. One method for testing the DESM hypothesis is proposed.

  13. Highly Durable Platinum Single-Atom Alloy Catalyst for Electrochemical Reactions

    DEFF Research Database (Denmark)

    Kim, Jiwhan; Roh, Chi-Woo; Sahoo, Suman Kalyan

    2018-01-01

    Single atomic Pt catalyst can offer efficient utilization of the expensive platinum and provide unique selectivity because it lacks ensemble sites. However, designing such a catalyst with high Pt loading and good durability is very challenging. Here, single atomic Pt catalyst supported on antimony...... functional theory calculations show that replacing Sb sites with Pt atoms in the bulk phase or at the surface of SbSn or ATO is energetically favorable. The Pt1/ATO shows superior activity and durability for formic acid oxidation reaction, compared to a commercial Pt/C catalyst. The single atomic Pt...... structure is retained even after a harsh durability test, which is performed by repeating cyclic voltammetry in the range of 0.05–1.4 V for 1800 cycles. A full cell is fabricated for direct formic acid fuel cell using the Pt1/ATO as an anode catalyst, and an order of magnitude higher cell power is obtained...

  14. Carbon nanocages: a new support material for Pt catalyst with remarkably high durability.

    Science.gov (United States)

    Wang, Xiao Xia; Tan, Zhe Hua; Zeng, Min; Wang, Jian Nong

    2014-03-24

    Low durability is the major challenge hindering the large-scale implementation of proton exchange membrane fuel cell (PEMFC) technology, and corrosion of carbon support materials of current catalysts is the main cause. Here, we describe the finding of remarkably high durability with the use of a novel support material. This material is based on hollow carbon nanocages developed with a high degree of graphitization and concurrent nitrogen doping for oxidation resistance enhancement, uniform deposition of fine Pt particles, and strong Pt-support interaction. Accelerated degradation testing shows that such designed catalyst possesses a superior electrochemical activity and long-term stability for both hydrogen oxidation and oxygen reduction relative to industry benchmarks of current catalysts. Further testing under conditions of practical fuel cell operation reveals almost no degradation over long-term cycling. Such a catalyst of high activity, particularly, high durability, opens the door for the next-generation PEMFC for "real world" application.

  15. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Volume 1, Bench-scale testing and analysis

    Energy Technology Data Exchange (ETDEWEB)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  16. Design of durability test protocol for vehicular fuel cell systems operated in power-follow mode based on statistical results of on-road data

    Science.gov (United States)

    Xu, Liangfei; Reimer, Uwe; Li, Jianqiu; Huang, Haiyan; Hu, Zunyan; Jiang, Hongliang; Janßen, Holger; Ouyang, Minggao; Lehnert, Werner

    2018-02-01

    City buses using polymer electrolyte membrane (PEM) fuel cells are considered to be the most likely fuel cell vehicles to be commercialized in China. The technical specifications of the fuel cell systems (FCSs) these buses are equipped with will differ based on the powertrain configurations and vehicle control strategies, but can generally be classified into the power-follow and soft-run modes. Each mode imposes different levels of electrochemical stress on the fuel cells. Evaluating the aging behavior of fuel cell stacks under the conditions encountered in fuel cell buses requires new durability test protocols based on statistical results obtained during actual driving tests. In this study, we propose a systematic design method for fuel cell durability test protocols that correspond to the power-follow mode based on three parameters for different fuel cell load ranges. The powertrain configurations and control strategy are described herein, followed by a presentation of the statistical data for the duty cycles of FCSs in one city bus in the demonstration project. Assessment protocols are presented based on the statistical results using mathematical optimization methods, and are compared to existing protocols with respect to common factors, such as time at open circuit voltage and root-mean-square power.

  17. Durability and efficiency tests for direct methanol fuel cell's long-term performance assessment

    International Nuclear Information System (INIS)

    Yeh, Pulin; Chang, Chu Hsiang; Shih, Naichien; Yeh, Naichia

    2016-01-01

    This research assessed the long-term performance of direct methanol fuel cells. The experiment was performed at room temperature using 0.51 mol/L ∼0.651 mol/L methanol with a fuel consumption rate of 0.8 ± 0.1 cc/Wh at stack temperature of 60 °C–70 °C. DuPont Nafion115 proton exchange membrane was used as the base material of MEA (membrane electrode assembly), which is then examined via a series of processes that include I−V curve test, humidity cycle test, load cycle test, and hydrogen penetration test. The study employs membrane modification and cell structure adjustment approaches to reduce the methanol crossover in the cathode and identify the cell performance effect of the carbon paper gas diffusion layer. The test results indicated an efficiency of 25% can be achieved with a three-piece MEA assembly. According to the durability test, the stack power-generation efficiency has maintained at 15%–25% level. With such efficiency, the stack voltage output has been able to stay above 7.8-V for over 5000 h. This result is in line with industry standard. - Highlights: • Assess DMFC performance under non-optimal conditions for production readiness. • Output of 26-cell DMFC stack stays beyond 7.8v after 5000 operation hours. • Power-generation efficiency of 26-cell DMFC stack maintains between 15%–20%.

  18. Durability and Strength of Sustainable Self-Consolidating Concrete Containing Fly Ash

    Science.gov (United States)

    Mohamed, O.; Hawat, W. Al

    2018-03-01

    In this paper, the durability and strength of self-consolidating concrete (SCC) is assessed through development and testing of six binary mixes at fixed water-to-binder (w/b) ratio of 0.36. In each of the six SCC mixes, a different percentage of cement is replaced with fly ash. The development of compressive strength for each of the mixes is assessed by testing samples after 3, 7, and 28 days of curing. Durability of each of the six SCC mixes is assessed by measuring the charge passed in Rapid Chloride Permeability (RCP) test. Charge passed was measured in samples cured for 1, 3, 7, 14, 28, and 40 days of curing. All mixes out-performed the control mix in terms of resistance to chloride penetration. Binary mix in which 20% of cement is replaced with fly ash exhibited 28-day strength slightly surpassing the control mix.

  19. 40 CFR 86.094-13 - Light-duty exhaust durability programs.

    Science.gov (United States)

    2010-07-01

    ... conformity for the affected engine families void ab initio. (e) Alternative Service Accumulation Durability... shall propose sample sizes, recruitment procedures, testing procedures, optional provisions for the...) of this section, the manufacturer shall provide reliability data that shows to the Administrator's...

  20. Strength and durability tests of pipeline supports for the areas of above-ground routing under the influence of operational loads

    Directory of Open Access Journals (Sweden)

    Surikov Vitaliy Ivanovich

    2014-03-01

    Full Text Available The present article deals with integrated research works and tests of pipeline supports for the areas of above-ground routing of the pipeline system “Zapolyarye - Pur-pe” which is laid in the eternally frozen grounds. In order to ensure the above-ground routing method for the oil pipeline “Zapolyarye - Pur-pe” and in view of the lack of construction experience in case of above-ground routing of oil pipelines, the leading research institute of JSC “Transneft” - LLC “NII TNN” over the period of August, 2011 - September, 2012 performed a research and development work on the subject “Development and production of pipeline supports and pile foundation test specimens for the areas of above-ground routing of the pipeline system “Zapolyarye - Pur-pe”. In the course of the works, the test specimens of fixed support, linear-sliding and free-sliding pipeline supports DN1000 and DN800 were produced and examined. For ensuring the stable structural reliability of the supports constructions and operational integrity of the pipelines the complex research works and tests were performed: 1. Cyclic tests of structural elements of the fixed support on the test bed of JSC “Diascan” by means of internal pressure and bending moment with the application of specially prepared equipment for defining the pipeline supports strength and durability. 2. Tests of the fixed support under the influence of limit operating loads and by means of internal pressure for confirming the support’s integrity. On the test bed there were simulated all the maximum loads on the support (vertical, longitudinal, side loadings, bending moment including subsidence of the neighboring sliding support and, simultaneously, internal pressure of the carried medium. 3. Cyclic tests of endurance and stability of the displacements of sliding supports under the influence of limit operating loads for confirming their operation capacity. Relocation of the pipeline on the sliding

  1. Durability assessment of recycled concrete aggregates for use in new concrete.

    Science.gov (United States)

    2012-06-01

    The primary goal of this research project was to investigate the long-term durability of concrete incorporating : recycled concrete aggregate (RCA) through accelerated laboratory testing. Overall it was found that modifications to : standard aggregat...

  2. Bond durability of universal adhesive to bovine enamel using self-etch mode.

    Science.gov (United States)

    Suzuki, Soshi; Takamizawa, Toshiki; Imai, Arisa; Tsujimoto, Akimasa; Sai, Keiichi; Takimoto, Masayuki; Barkmeier, Wayne W; Latta, Mark A; Miyazaki, Masashi

    2018-04-01

    The purpose of this study was to examine the enamel bond durability of universal adhesives in the self-etch mode under 2-year water storage and thermal cycling conditions. Three commercially available universal adhesives and a gold standard two-step self-etch adhesive were used. Ten specimens of bovine enamel were prepared per test group, and shear bond strength (SBS) was measured to determine the bonding durability after thermal cycling (TC) or long-term water storage (WS). The bonded specimens were divided into three groups: (1) specimens subjected to TC, where the bonded specimens were stored in 37 °C distilled water for 24 h before being subjected to 3000, 10,000, 20,000 or 30,000 TC; (2) specimens stored in 37 °C distilled water for 3 months, 6 months, 1 year or 2 year; and (3) specimens stored in 37 °C distilled water for 24 h, serving as a baseline. The two-step self-etch adhesive showed significantly higher SBS than the universal adhesives tested, regardless of the type of degradation method. All universal adhesives showed no significant enamel SBS reductions in TC and WS, when compared to baseline and the other degradation conditions. Compared to the bond strengths obtained with the two-step self-etch adhesive, significantly lower bond strengths were obtained with universal adhesives. However, the enamel bond durability of universal adhesives was relatively stable under both degradation conditions tested. The present data indicate that the enamel bond durability of universal adhesives in the self-etch mode might be sufficient for clinical use.

  3. Effect of W/C Ratio on Durability and Porosity in Cement Mortar with Constant Cement Amount

    Directory of Open Access Journals (Sweden)

    Yun-Yong Kim

    2014-01-01

    Full Text Available Water is often added to concrete placing for easy workability and finishability in construction site. The additional mixing water can help easy mixing and workability but causes increased porosity, which yields degradation of durability and structural performances. In this paper, cement mortar samples with 0.45 of W/C (water to cement ratio are prepared for control case and durability performances are evaluated with additional water from 0.45 to 0.60 of W/C. Several durability tests including strength, chloride diffusion, air permeability, saturation, and moisture diffusion are performed, and they are analyzed with changed porosity. The changing ratios and patterns of durability performance are evaluated considering pore size distribution, total porosity, and additional water content.

  4. Radiometric emanation method for the assessment of the durability of building materials towards aggressive media

    International Nuclear Information System (INIS)

    Balek, V.; Beckman, I.N.

    1991-01-01

    A new express method has been suggested for testing durability of building materials in contact with aggressive liquids and gases. The method is based on the measurement of radon released from samples studied, continuously during the interaction of the sample with the aggressive medium. The samples are previously labeled by the source of radon atoms, i.e. thorium Th-228 and radium Ra-224 are incorporated in the samples to be tested. Due to high sensitivity of the method the first stages of the interaction between the cement stone (concrete) sample and aggressive liquid or gas can be followed. The express information about the relative durability of the building materials was obtained. This method was also advantageously used for the investigation of corrosion early stage of marble (calcium carbonate) by sulphur dioxide (in the concentrations of 500-3,000 ppm). The most advantageous application of the method is for rapid assessment of the relative durability of building materials, e.g. the information about the relative durability of the samples studied was obtained within several minutes, resp. hours, whereas by means of traditional chemical methods it needs several weeks or months

  5. Production and remediation of low sludge simulated Purex waste glasses, 2: Effects of sludge oxide additions on glass durability

    International Nuclear Information System (INIS)

    Ramsey, W.G.

    1993-01-01

    Glass produced during the Purex 4 campaigns of the Integrated DWPF Melter System (IDMS) and the 774 Research Melter contained a lower fraction of sludge components than targeted by the Product Composition Control System (PCCS). Purex 4 glass was more durable than the benchmark (EA) glass, but was less durable than most other simulated SRS high-level waste glasses. Further, the measured durability of Purex 4 glass was not as well correlated with the durability predicted from the DWPF process control algorithm, probably because the algorithm was developed to predict the durability of SRS high-level waste glasses with higher sludge content than Purex 4. A melter run, designated Purex 4 Remediation, was performed using the 774 Research Melter to determine if the initial PCCS target composition determined for Purex 4 would produce acceptable glass whose durability could be accurately modeled by the DWPF glass durability algorithm. Reagent grade oxides and carbonates were added to Purex 4 melter feed stock to simulate a higher sludge loading. Each canister of glass produced was sampled and the glass durability was determined by the Product Consistency Test method. This document details the durability data and subsequent analysis

  6. Rapid chloride permeability test as durability index of the concrete structure

    Directory of Open Access Journals (Sweden)

    Martínez-Sánchez, B.

    2003-12-01

    Full Text Available From the RCPT publication, this test has been frequently used in the concrete structures durability assessment. This test it could be determined in a relatively short time the material permeability, within a rank or quality level that allows comparing concretes as far as their characteristics. In this document, is present an intense investigation to evaluate mix designs with the principal objective to measure the participation and contribution of the components that take part in the concrete manufacture. A detailed review of the components contribution is applied to know specifically the properties in the product during any state: fresh or hard path. In this paper, are identified and included the most influence variables in the concrete properties modification.

    Desde su lanzamiento, la prueba de permeabilidad rápida a la penetración de cloruros ha sido usada frecuentemente en la evaluación de la durabilidad en las estructuras de hormigón, ya que se puede establecer, en un tiempo relativamente corto, la determinación de la permeabilidad del material, dentro de un nivel de calidad que permite comparar hormigones en cuanto a esta característica. En este articulo se presenta una investigación en donde se evalúan diseños de mezcla con la finalidad de medir la participación y contribución de cada uno de los componentes que intervienen en la fabricación del hormigón, revisando con detalle su contribución en las propiedades finales del producto, sin olvidar sus efectos en su comportamiento en estado fresco o cuando se encuentra en fase de endurecimiento. En el trabajo se incluyen e identifican las variables de mayor influencia y su relación con la propiedad que modificaron en el hormigón.

  7. Sustainability and durability analysis of reinforced concrete structures

    Science.gov (United States)

    Horáková, A.; Broukalová, I.; Kohoutková, A.; Vašková, J.

    2017-09-01

    The article describes an assessment of reinforced concrete structures in terms of durability and sustainable development. There is a short summary of findings from the literature on evaluation methods for environmental impacts and also about corrosive influences acting on the reinforced concrete structure, about factors influencing the durability of these structures and mathematical models describing the corrosion impacts. Variant design of reinforced concrete structure and assessment of these variants in terms of durability and sustainability was performed. The analysed structure was a concrete ceiling structure of a parking house for cars. The variants differ in strength class of concrete and thickness of concrete slab. It was found that in terms of durability and sustainable development it is significantly preferable to use higher class of concrete. There are significant differences in results of concrete structures durability for different mathematical models of corrosive influences.

  8. Durability of an inorganic polymer concrete coating

    Science.gov (United States)

    Wasserman, Kenneth

    The objective of the research program reported in this thesis is to evaluate the durability of an inorganic polymer composite coating exposed to freeze/thaw cycling and wet-dry cycling. Freeze/thaw cycling is performed following ASTM D6944-09 Standard Practice for Resistance of Cured Coatings to Thermal Cycling and wet/dry cycling is performed following guidelines set forth in a thesis written by Ronald Garon at Rutgers University. For both sets of experiments, four coating mixture proportions were evaluated. The variables were: silica/alumina ratio, mixing protocol using high shear and normal shear mixing, curing temperatures of 70 and 120 degrees Fahrenheit and use of nano size constituent materials. The mix with highest silica/alumina ratio was designated as Mix 1 and mixes with lower ratios were designated as Mix 2 and Mix 3. Mix 4 had nano silica particles. Four prisms were used for each variable including control that had no coating. The performance of the coating was evaluated using adhesion strength measured using: ASTM D7234 Test Method for Pull-Off Strength of Coatings on Concrete Using Portable Adhesion Testers. Tests were performed after every five consecutive cycles of thermal conditioning and six consecutive cycles of wet-dry exposure. Results from the thermal cycling and wet-dry testing demonstrate that all coating formulations are durable. The minimum adhesion strength was 300 psi even though a relatively weak base concrete surface was chosen for the study. The weak surface was chosen to simulate aged concrete surfaces present in actual field conditions. Due to the inherent nature of the test procedure the variation in test results is high. However, based on the test results, high shear mixer and high temperature curing are not recommended. As expected nano size constituent materials provide better performance.

  9. THE EFFECT OF HEAT TREATMENT ON THE DURABILITY OF BAMBOO Gigantochloa scortechinii

    Directory of Open Access Journals (Sweden)

    Norashikin Kamarudin

    2012-07-01

    Full Text Available Bamboo signifies as one of the fastest growing plants and it can be used for various products. In tropical countries such as Indonesia and Malaysia, bamboo is abundantly available at reasonable prices, therefore it is used for numerous purposes. However, as lignocellulosic material, bamboo is susceptible to fungal and insect attacks. Heat treatment is an option to improve bamboo's durability. The objective of this study was to improve the durability of bamboo using hot oil palm treatment. A Malaysian grown bamboo species, Buluh Semantan (Gigantochloa scortechinii, as a study material was soaked in hot oil palm for various temperatures and soaking time, before being inoculated with the basidiomycete Coriolus versicolor in an agar block test. The results demonstrated that the longer the heating time, the more improved the durability of bamboo. Altering the temperature in the palm oil treatment produced varying results. Bamboo blocks that heated in hot oil palm at 100°C for 60 minutes shows considerably less weight eduction that indicates less fungal attack. Overall, the higher the temperature, the better the durability of bamboo. Please indicates what the meaning of heat treatment in this experiment, it is not clear.

  10. Influence of surface topography on the surface durability of steam oxidised sintered iron

    Directory of Open Access Journals (Sweden)

    José Daniel Biasoli de Mello

    2005-06-01

    Full Text Available Durability of surfaces has been reported as the main factor affecting tribological behavior of steam oxidised sintered iron. The presence of surface pores and their negative influence on load bearing capacity, suggest that surface topography might play an important role on the durability of the oxide layer. In this paper, the influence of compaction pressure and powder grade on surface topography, and as a consequence, its effect on the tribological behavior of steam oxidised sintered iron has been analysed. Specimens prepared from atomised iron powders with different sizes were compacted using 4 different pressures, sintered, and then subjected to steam treatment. Tribological characterisation was carried out in a reciprocating sliding wear test. Although the processing parameters affected the surface topography to a considerable extent, the main influence may be attributed to powder grade. A strong influence of surface topography on the durability distance, evaluated in terms of the evolution of contact resistance with total sliding distance, has been highlighted. Surfaces which were smoother and had high load-carrying capacity were always associated with a higher durability distance.

  11. Study on the durability of concrete using granulated blast furnace slag as fine aggregate

    Science.gov (United States)

    Shi, Dongsheng; Liu, Qiang; Xue, Xinxin; He, Peiyuan

    2018-03-01

    In order to assessing the durability of concrete using granulated blastfurnace slag (GBS) as fine aggregate and compare it with natural river sand concrete, three different size of specimen were produced by using the same mix proportion with 3 different water cement ratios and 3 replacement ratios, and using it to measure the three aspects on the durability of concrete including freeze-thaw performance, dry-shrinkage performance and anti-chloride-permeability performance. In this paper. The test results show that using GBS as fine aggregate can slightly improve anti-chloride-permeability performance and dry-shrinkage performance of concrete in the condition of low water cement ratio, on the other hand, using GBS or natural river sand as fine aggregate has almost similar durability of concrete.

  12. DURABILITY OF ASPHALT CONCRETE MIXTURES USING DOLOMITE AGGREGATES

    Directory of Open Access Journals (Sweden)

    Imad Al-Shalout

    2015-12-01

    Full Text Available This study deals with the durability of asphalt concrete, including the effects of different gradations, compaction temperatures and immersion time on the durability potential of mixtures. The specific objectives of this study are: to investigate the effect of compaction temperature on the mechanical properties of asphalt concrete mixtures; investigate the effect of bitumen content and different aggregate gradations on the durability potential of bituminous mixtures.

  13. Reliability and durability in solar energy systems

    Energy Technology Data Exchange (ETDEWEB)

    Godolphin, D.

    1982-10-01

    The reliability and durability in solar energy systems for residential buildings is discussed. It is concluded that although strides have been made in design and manufacturing over the past years, the reliability and durability of the equipment depends on the proper installation. (MJF)

  14. Durability as integral characteristic of concrete

    Science.gov (United States)

    Suleymanova, L. A.; Pogorelova, I. A.; Suleymanov, K. A.; Kirilenko, S. V.; Marushko, M. V.

    2018-03-01

    The carried-out research provides insight into the internal bonds energy in material as the basis of its durability, deformability, integrity and resistance to different factors (combined effects of external loadings and (or) environment), into the limits of technical possibilities, durability and physical reality of the process of concrete deterioration, which allows designing reliable and cost-effective ferroconcrete constructions for different purposes.

  15. Durability of composites in a marine environment

    CERN Document Server

    Rajapakse, Yapa

    2014-01-01

    Composites are widely used in marine applications. There is considerable experience of glass reinforced resins in boats and ships but these are usually not highly loaded. However, for new areas such as offshore and ocean energy there is a need for highly loaded structures to survive harsh conditions for 20 years or more. High performance composites are therefore being proposed. This book provides an overview of the state of the art in predicting the long term durability of composite marine structures. The following points are covered: •       Modelling water diffusion •       Damage induced by water •       Accelerated testing •       Including durability in design •       In-service experience. This is essential reading for all those involved with composites in the marine industry, from initial design and calculation through to manufacture and service exploitation. It also provides information unavailable elsewhere on the mechanisms involved in degradation and how to t...

  16. Durability of filament-wound composite flywheel rotors

    Science.gov (United States)

    Koyanagi, Jun

    2012-02-01

    This paper predicts the durability of two types of flywheels, one assumes to fail in the radial direction and the other assumes to fail in the circumferential direction. The flywheel failing in the radial direction is a conventional filament-wound composite flywheel and the one failing in the circumferential direction is a tailor-made type. The durability of the former is predicted by Micromechanics of Failure (MMF) (Ha et al. in J. Compos. Mater. 42:1873-1875, 2008), employing time-dependent matrix strength, and that of the latter is predicted by Simultaneous Fiber Failure (SFF) (Koyanagi et al. in J. Compos. Mater. 43:1901-1914, 2009), employing identical time-dependent matrix strength. The predicted durability of the latter is much greater than that of the former, depending on the interface strength. This study suggests that a relatively weak interface is necessary for high-durability composite flywheel fabrication.

  17. Chemical durability of borosilicate glasses containing simulated high-level nuclear wastes, 1

    International Nuclear Information System (INIS)

    Hara, Shigeo; Terai, Ryohei; Yamanaka, Hiroshi

    1983-01-01

    The Soxhlet-type leaching test apparatus has been developed to evaluate the chemical durability of some borosilicate glasses containing simulated High-Level nuclear Wastes, HLW. After the leaching over the temperature range of 50 0 -95 0 C, the weight loss of specimens with time was determined on both the samples of blocks and grains, and various components dissolved into water were analyzed by atomic absorption and colorimetry technique. It was found that Soxhlet-type test method was more useful than JIS test method, because the specimens in Soxhlet type apparatus were forced always to react with pure water and the mechanism of leaching could be evaluate accurately. The chemical durability of commercial glasses decreases generally with increasing of alkali contents in glasses. In the case of these borosilicate glasses containing HLW, however, the leachability was apparently independent on the alkali contents because of the complexity of these glass compositions. The variation of leaching rate with temperature suggests that dissolution mechanism changes with temperature. (author)

  18. Increase of cyclic durability of pressure vessels

    International Nuclear Information System (INIS)

    Vorona, V.A.; Zvezdin, Yu.I.

    1980-01-01

    The durability of multilayer pressure vessels under cyclic loading is compared with single-layer vessels. The relative conditional durability is calculated taking into account the assumption on the consequent destruction of layers and viewing a vessel wall as an indefinite plate. It is established that the durability is mainly determined by the number of layers and to a lesser degree depends on the relative size of the defect for the given layer thickness. The advantage of the multilayer vessels is the possibility of selecting layer materials so that to exclude the effect of agressive corrosion media on the strength [ru

  19. 40 CFR 86.1823-01 - Durability demonstration procedures for exhaust emissions.

    Science.gov (United States)

    2010-07-01

    ...) Discussion of the manufacturer's in-use verification procedures including testing performed, vehicle... performed should also be documented in the manufacturer's submission. The in-use verification program shall...), the Alternate Service Accumulation Durability Program described in § 86.094-13(e) or the Standard Self...

  20. Durability and Shrinkage Characteristics of Self-Compacting Concretes Containing Recycled Coarse and/or Fine Aggregates

    Directory of Open Access Journals (Sweden)

    Mehmet Gesoglu

    2015-01-01

    Full Text Available This paper addresses durability and shrinkage performance of the self-compacting concretes (SCCs in which natural coarse aggregate (NCA and/or natural fine aggregate (NFA were replaced by recycled coarse aggregate (RCA and/or recycled fine aggregate (RFA, respectively. A total of 16 SCCs were produced and classified into four series, each of which included four mixes designed with two water to binder (w/b ratios of 0.3 and 0.43 and two silica fume replacement levels of 0 and 10%. Durability properties of SCCs were tested for rapid chloride penetration, water sorptivity, gas permeability, and water permeability at 56 days. Also, drying shrinkage accompanied by the water loss and restrained shrinkage of SCCs were monitored over 56 days of drying period. Test results revealed that incorporating recycled coarse and/or fine aggregates aggravated the durability properties of SCCs tested in this study. The drying shrinkage and restrained shrinkage cracking of recycled aggregate (RA concretes had significantly poorer performance than natural aggregate (NA concretes. The time of cracking greatly prolonged as the RAs were used along with the increase in water/binder ratio.

  1. Durability of capital goods: taxes and market structure

    Energy Technology Data Exchange (ETDEWEB)

    Raviv, A [Carnegie-Mellon Univ., Pittsburgh; Zemel, E

    1977-04-01

    This paper examines the durability of capital goods produced under different market structures when tax considerations are included. Since investment tax credit and depreciation allowances are realized by the owner of the durable good, the durability of products produced by an industry which sells its output differs from that of an industry which rents. For each of these two commercial forms, both monopolistic and competitive market structure are considered. Potential gains from different forms of regulation are discussed.

  2. Durability testing of an iodate-substituted hydroxyapatite designed for the conditioning of {sup 129}I

    Energy Technology Data Exchange (ETDEWEB)

    Coulon, Antoine [CEA, DEN, DTCD, SECM, Laboratoire d' étude et de Développement de Matrices de Conditionnement, Marcoule, F-30207 Bagnols sur Cèze (France); Grandjean, Agnes [CEA, DEN, DTCD, SPDE, Laboratoire des Procédés Supercritiques et de Décontamination, Marcoule, F-30207 Bagnols sur Cèze (France); Laurencin, Danielle [Institut Charles Gerhardt Montpellier ICGM, UMR 5253 CNRS-UM-ENSCM, Université de Montpellier, Place E. Bataillon, CC1701, F-34095 Montpellier Cedex 5 (France); Jollivet, Patrick [CEA, DEN, DTCD, SECM, Laboratoire d' étude du Comportement à Long Terme, Centre de Marcoule, F-30207 Bagnols sur Cèze (France); Rossignol, Sylvie [Groupe d' Etude des Matériaux Hétérogènes, CEC-GEMH-ENSCI, 12 rue de l' Atlantis, F-87068 Limoges Cedex (France); Campayo, Lionel, E-mail: lionel.campayo@cea.fr [CEA, DEN, DTCD, SECM, Laboratoire d' étude et de Développement de Matrices de Conditionnement, Marcoule, F-30207 Bagnols sur Cèze (France)

    2017-02-15

    The safe management of iodine coming from spent nuclear fuels by storage in deep geological repositories requires durable materials. For this purpose, we have recently developed an iodate-substituted hydroxyapatite (HA-CaI). In the present article, the chemical durability of this material is assessed as a function of leaching media and apatite stoichiometry. First, the maximum rate for iodine release was determined in unsaturated conditions leading to a congruent dissolution of HA-CaI. In these conditions, the forward rate was equal to 2 × 10{sup −2} g m{sup −2} d{sup −1} at 50 °C independently of apatite stoichiometry. During this regime, dissolution was controlled by surface reaction and diffusion phenomena. When concentrations of calcium and phosphate ions in solution increased, the system became saturated towards non-substituted hydroxyapatite Ca{sub 10}(PO{sub 4}){sub 6}(OH){sub 2} and the rate of iodine release consecutively decreased. Consequently, tests were carried out to determine the behaviour of HA-CaI in such experimental conditions (saturated conditions), which were thought to be time-prevalent given the half-life of {sup 129}I (15.7 million years). During this regime, also called residual regime, iodine was released in the solution at a constant rate without being trapped in a secondary phase. The residual rate at 50 °C on the basis of iodine release was of 10{sup −4} g m{sup −2} d{sup −1} in an initially deionized water, and it fell by one order of magnitude (r = 10{sup −5} g m{sup −2} d{sup −1}) in a clay-equilibrated groundwater (hereafter called Callovo-oxfordian (COx) groundwater). This singular behaviour was ascribed to the presence of calcium in COx water. These preliminary results on the chemical durability of HA-CaI suggest that this material is a viable candidate as repository iodine waste form. - Highlights: • A two-step mechanism can account for the resistance to leaching in pure water of iodate

  3. The influence of humidity on strengths and durability of light guides fibers

    International Nuclear Information System (INIS)

    Karimov, S.N.; Kuksenko, V.S.; Sultonov, U.; Abdumanonov, A.; Shamsidinov, M.I.

    1993-01-01

    Humidity influence on durability and light water durability fibres is studied are studied in this article. Humidity energy under influence of process destruction decreases activity, durability and durability decreases is shown

  4. Durability comparison of four different types of high-power batteries in HEV and their degradation mechanism analysis

    International Nuclear Information System (INIS)

    Yan, Dongxiang; Lu, Languang; Li, Zhe; Feng, Xuning; Ouyang, Minggao; Jiang, Fachao

    2016-01-01

    Highlights: • Utilize a realistic current profile for an HEV to study the degradation mechanism of batteries. • Compare the durability of four different types of high-power battery. • Degradation mechanisms of four different types of high-power battery are analyzed by IC curves. • The prognostic model is used to quantitatively clarify the aging mechanism of batteries. - Abstract: There are many types of high-power batteries used in HEVs, and their durabilities and degradation mechanisms are different. In this paper, four types of commercial high-power batteries, including two types of LTO/NCM lithium-ion battery from two different manufacturers, a C/LMO battery and a supercapacitor (SC), are studied. A durability test with a realistic current profile for an HEV is used so that the durability results more closely reflect real operating conditions than a general cycle life test. Incremental capacity (IC) curves are used to qualitatively analyze the degradation mechanism. To compensate for defects in the IC method, a prognosis model, using a genetic algorithm to reconstruct constant current charge voltage curves, is adopted to quantitatively identify the battery aging mechanism.

  5. Durability and inflammogenic impact of carbon nanotubes compared with asbestos fibres

    Directory of Open Access Journals (Sweden)

    Clark Steve

    2011-05-01

    Full Text Available Abstract Background It has been suggested that carbon nanotubes might conform to the fibre pathogenicity paradigm that explains the toxicities of asbestos and other fibres on a continuum based on length, aspect ratio and biopersistence. Some types of carbon nanotubes satisfy the first two aspects of the fibre paradigm but only recently has their biopersistence begun to be investigated. Biopersistence is complex and requires in vivo testing and analysis. However durability, the chemical mimicking of the process of fibre dissolution using in vitro treatment, is closely related to biopersistence and more readily determined. Here, we describe an experimental process to determine the durability of four types of carbon nanotubes in simulated biological fluid (Gambles solution, and their subsequent pathogenicity in vivo using a mouse model sensitive to inflammogenic effects of fibres. The in vitro and in vivo results were compared with well-characterised glass wool and asbestos fibre controls. Results After incubation for up to 24 weeks in Gambles solution, our control fibres were recovered at percentages consistent with their known in vitro durabilities and/or in vivo persistence, and three out of the four types of carbon nanotubes tested (single-walled (CNTSW and multi-walled (CNTTANG2, CNTSPIN showed no, or minimal, loss of mass or change in fibre length or morphology when examined by electron microscopy. However, the fourth type [multi-walled (CNTLONG1] lost 30% of its original mass within the first three weeks of incubation, after which there was no further loss. Electron microscopy of CNTLONG1 samples incubated for 10 weeks confirmed that the proportion of long fibres had decreased compared to samples briefly exposed to the Gambles solution. This loss of mass and fibre shortening was accompanied by a loss of pathogenicity when injected into the peritoneal cavities of C57Bl/6 mice compared to fibres incubated briefly. CNTSW did not elicit an

  6. Durability of crystalline phase in concrete microstructure modified by the mineral powders: evaluation by nanoindentation tests

    Directory of Open Access Journals (Sweden)

    Rajczakowska Magdalena

    2016-03-01

    Full Text Available This paper presents the nanoindentation investigation of the evolution of concrete microstructure modified by the Internal Crystallization Technology mineral powders. The samples under study were retrieved from a fragment of a circular concrete lining of the vertical mine shaft at a depth of approximately 1,000 m. Due to the aggressive environment and exposure to contaminated water, the internal surface of the structure was deteriorated, decreasing its strength significantly. The mineral powders were applied directly on the surface lining. The specimens were investigated one month, three months and one year after the application of the aforementioned substance in order to verify the time dependence of the strengthening processes and durability of the crystalline phase. The microstructural changes of concrete were assessed with the use of nanoindentation technique. The testing procedure involved including the previously cut specimens in the epoxy resin and grinding and polishing in order to reduce the surface roughness. As a result of the nanoindentation tests the hardness as well as Young’s modulus of the material were evaluated. The results were then compared and statistically analyzed. As a consequence, the disintegration time of the crystalline network in the pores of concrete was identified.

  7. Durable Glass For Thousands Of Years

    International Nuclear Information System (INIS)

    Jantzen, C.

    2009-01-01

    The durability of natural glasses on geological time scales and ancient glasses for thousands of years is well documented. The necessity to predict the durability of high level nuclear waste (HLW) glasses on extended time scales has led to various thermodynamic and kinetic approaches. Advances in the measurement of medium range order (MRO) in glasses has led to the understanding that the molecular structure of a glass, and thus the glass composition, controls the glass durability by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. During the early stages of glass dissolution, a 'gel' layer resembling a membrane forms through which ions exchange between the glass and the leachant. The hydrated gel layer exhibits acid/base properties which are manifested as the pH dependence of the thickness and nature of the gel layer. The gel layer ages into clay or zeolite minerals by Ostwald ripening. Zeolite mineral assemblages (higher pH and Al 3+ rich glasses) may cause the dissolution rate to increase which is undesirable for long-term performance of glass in the environment. Thermodynamic and structural approaches to the prediction of glass durability are compared versus Ostwald ripening.

  8. DURABLE GLASS FOR THOUSANDS OF YEARS

    Energy Technology Data Exchange (ETDEWEB)

    Jantzen, C.

    2009-12-04

    The durability of natural glasses on geological time scales and ancient glasses for thousands of years is well documented. The necessity to predict the durability of high level nuclear waste (HLW) glasses on extended time scales has led to various thermodynamic and kinetic approaches. Advances in the measurement of medium range order (MRO) in glasses has led to the understanding that the molecular structure of a glass, and thus the glass composition, controls the glass durability by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. During the early stages of glass dissolution, a 'gel' layer resembling a membrane forms through which ions exchange between the glass and the leachant. The hydrated gel layer exhibits acid/base properties which are manifested as the pH dependence of the thickness and nature of the gel layer. The gel layer ages into clay or zeolite minerals by Ostwald ripening. Zeolite mineral assemblages (higher pH and Al{sup 3+} rich glasses) may cause the dissolution rate to increase which is undesirable for long-term performance of glass in the environment. Thermodynamic and structural approaches to the prediction of glass durability are compared versus Ostwald ripening.

  9. Durable fiber reinforced self-compacting concrete

    International Nuclear Information System (INIS)

    Corinaldesi, V.; Moriconi, G.

    2004-01-01

    In order to produce thin precast elements, a self-compacting concrete was prepared. When manufacturing these elements, homogenously dispersed steel fibers instead of ordinary steel-reinforcing mesh were added to the concrete mixture at a dosage of 10% by mass of cement. An adequate concrete strength class was achieved with a water to cement ratio of 0.40. Compression and flexure tests were carried out to assess the safety of these thin concrete elements. Moreover, serviceability aspects were taken into consideration. Firstly, drying shrinkage tests were carried out in order to evaluate the contribution of steel fibers in counteracting the high concrete strains due to a low aggregate-cement ratio. Secondly, the resistance to freezing and thawing cycles was investigated on concrete specimens in some cases superficially treated with a hydrophobic agent. Lastly, both carbonation and chloride penetration tests were carried out to assess durability behavior of this concrete mixture

  10. Mechanistic Enhancement of SOFC Cathode Durability

    Energy Technology Data Exchange (ETDEWEB)

    Wachsman, Eric [Univ. of Maryland, College Park, MD (United States)

    2016-02-01

    Durability of solid oxide fuel cells (SOFC) under “real world” conditions is an issue for commercial deployment. In particular cathode exposure to moisture, CO2, Cr vapor (from interconnects and BOP), and particulates results in long-term performance degradation issues. Here, we have conducted a multi-faceted fundamental investigation of the effect of these contaminants on cathode performance degradation mechanisms in order to establish cathode composition/structures and operational conditions to enhance cathode durability.

  11. Microcracking and durability of high strength concretes

    International Nuclear Information System (INIS)

    Yssorche, M.P.

    1995-07-01

    Durability of 28 days compressive strength concrete of 20 to 120 MPa has been studied. The ability of concrete to transport aggressive agents has been determined for four properties: the air permeability, the chloride diffusivity, the water absorption and the carbonation. A chloride migration test for high and very high strength concrete (HSC and VHSC) has been built. The relationship between transport properties and the compressive strength after one and 28 days of humid curing has always the same shape: transport decreases when strength increases. However, transport properties often vary in the ordinary concrete field. Beyond, the domain is much more limited. The relationship between transport properties and strength valid for ordinary concrete can not be simply extrapolated for HSC and VHSC. To determine the part of microcracking of HSC and VHSC, concrete behaviour stored in two mediums has been studied: the ones shaming the storing condition of concrete in auto-desiccation, the others reproducing the storing conditions of concrete in desiccation. Auto-desiccation (measuring relative humidity at balance) and desiccation (measuring mass losses) have been showed. Microcracks and shrinkage strains have been measured. It has been showed that auto-desiccation microcracks proving in HSC or VHSC don't question the durability. Microcracks, as for permeability, do not develop between 28 days and one year. On the contrary, desiccation microcracks observed in HSC and VHSC, increase with transport properties between 28 days and 1.5 year. Thus, a bulk concrete is always more durable than a cover concrete. At last, the good influence of increase of curing of 1 to 28 days on the transport of all concretes has been emphasized. (author)

  12. DURABILITY OF FLEXIBLE PAVEMENTS: A CASE STUDY OF ...

    African Journals Online (AJOL)

    user

    years, ranking, predominant factors affecting pavement durability and the estimate of durability. In this regard .... subgrade soil into the base course and provide the drainage of ..... [3] Oguara T. M. “A management model for road infrastructure ...

  13. Durability of air lime mortar

    DEFF Research Database (Denmark)

    Nielsen, Anders

    2016-01-01

    This contribution deals with the physical and chemical reasons why pure air lime mortars used in masonry of burned bricks exposed to outdoor climate have shown to be durable from the Middle Ages to our days. This sounds strange in modern times where pure air lime mortars are regarded as weak...... materials, which are omitted from standards for new masonry buildings, where use of hydraulic binders is prescribed. The reasons for the durability seam to be two: 1. The old mortars have high lime contents. 2. The carbonation process creates a pore structure with a fine pored outer layer and coarser pores...

  14. Study on durability and reliability of strut type suspension noise based on experimental methods

    International Nuclear Information System (INIS)

    Kim, Gu Gyong; Kang, Sung Su; Lee, Yong Jun; Park, Soon Cheol; Jung, Won Wook

    2012-01-01

    When cars are released from the factory, strut noises are very small and therefore it is difficult to perceive them. As the use time and travel distance increase, however, strut noises get larger so as to cause users much uneasiness. The noises generated at the field include engine noises and flow noises and therefore it is difficult to clearly discern the noises generated from struts. This study developed a test method which can reproduce field strut noises in the lab. Using the newly developed noise evaluation test, this study analyzed the effects that insulator performance degradation and failure can have on car noises. The study also confirmed that the insulator durability test by the simple back-and-forth motion cannot completely reflect the state of the parts failure in the field. Based on this, the study also confirmed that field noises can be reproduced through a durability test that considers heat aging

  15. Determination of Stone-Mastic Asphalt Concrete Durability

    Science.gov (United States)

    Yastremsky, D. A.; Abaidullina, T. N.; Chepur, P. V.

    2018-05-01

    The paper is focused on determination of durability of the stone-mastic asphalt (SMA) concrete, containing various stabilizing additives: "Armidon" (authors’ development) and "Viatop". At the first stage of experiments, the APA method was used to determine the rutting in the SMA containing these additives. Strength test for only top layers of asphalt concrete surface is insufficient for the calculation of the pavement fatigue resistance limits. Due to this fact, a comprehensive approach was employed which incorporates the interaction of the surface and subgrade natural soil. To analyze the road surface stress-strain state and to determine the durability margin, a numerical model was used (describes the processes of fatigue life). The model was developed basing on the finite element method (FEM) in the ANSYS program. Conducted studies and numerical calculations allowed obtaining the minimum and maximum stress values in the structure affected zones and in the zones of plastic deformations occurrence in artificial and natural bases. It allows predicting deformation processes during repeated wheel loads caused by moving vehicles. In course of studies, the results of static stresses in the pavement were also obtained.

  16. The durability of fired brick incorporating textile factory waste ash and basaltic pumice

    Energy Technology Data Exchange (ETDEWEB)

    Binici, Hanifi [Kahramanmaras Sutcu Imam Univ., Kahramanmaras (Turkey). Dept. of Civil Engineering; Yardim, Yavuz [Epoka Univ., Tirana (Albania). Dept. of Civil Engineering

    2012-07-15

    This study investigates the durability of fired brick produced with additives of textile factories' waste ash and basaltic pumice. The effects of incorporating waste ash and basaltic pumice on durability and mechanical properties of the clay bricks were studied. Samples were produced with different ratios of the textile factories' waste ash and basaltic pumice added and at different fire temperatures of 700, 900, and 1 050 C for 8 h. The bricks with additives were produced by adding equal amounts of textile factories' waste ash and basaltic pumice, separately and together, with rates of 5, 10 and 20 wt.%. The produced samples were kept one year in sodium sulphate and sodium nitrate and tested under freezing - unfreezing and drying - wetting conditions. Then compression strength and mass loss of the samples with and without additives were investigated. The test results were compared with standards and results obtained from control specimens. The results showed that incorporations up to 10 wt.% of textile factories' waste ash and basaltic pumice is beneficial to the fired brick. Both textile factories' waste ash and basaltic pumice were suitable additives and could be used for more durable clay brick production at 900 C fire temperature. (orig.)

  17. Durability of Low Platinum Fuel Cells Operating at High Power Density

    Energy Technology Data Exchange (ETDEWEB)

    Polevaya, Olga [Nuvera Fuel Cells Inc.; Blanchet, Scott [Nuvera Fuel Cells Inc.; Ahluwalia, Rajesh [Argonne National Lab; Borup, Rod [Los-Alamos National Lab; Mukundan, Rangachary [Los-Alamos National Lab

    2014-03-19

    Understanding and improving the durability of cost-competitive fuel cell stacks is imperative to successful deployment of the technology. Stacks will need to operate well beyond today’s state-of-the-art rated power density with very low platinum loading in order to achieve the cost targets set forth by DOE ($15/kW) and ultimately be competitive with incumbent technologies. An accelerated cost-reduction path presented by Nuvera focused on substantially increasing power density to address non-PGM material costs as well as platinum. The study developed a practical understanding of the degradation mechanisms impacting durability of fuel cells with low platinum loading (≤0.2mg/cm2) operating at high power density (≥1.0W/cm2) and worked out approaches for improving the durability of low-loaded, high-power stack designs. Of specific interest is the impact of combining low platinum loading with high power density operation, as this offers the best chance of achieving long-term cost targets. A design-of-experiments approach was utilized to reveal and quantify the sensitivity of durability-critical material properties to high current density at two levels of platinum loading (the more conventional 0.45 mgPt.cm–1 and the much lower 0.2 mgPt.cm–2) across several cell architectures. We studied the relevance of selected component accelerated stress tests (AST) to fuel cell operation in power producing mode. New stress tests (NST) were designed to investigate the sensitivity to the addition of electrical current on the ASTs, along with combined humidity and load cycles and, eventually, relate to the combined city/highway drive cycle. Changes in the cathode electrochemical surface area (ECSA) and average oxygen partial pressure on the catalyst layer with aging under AST and NST protocols were compared based on the number of completed cycles. Studies showed elevated sensitivity of Pt growth to the potential limits and the initial particle size distribution. The ECSA loss

  18. A study on the effects of seawater on the durable life of concrete structures(II)

    Energy Technology Data Exchange (ETDEWEB)

    Oh, Byung Hwan; Jang, Bong Suk; Jang, Seung Yeop; Jeon, Se Jin; Yu, Yeong; Park, Dae Gyun; Hyeong, Sang Soo [Seoul National Univ., Seoul (Korea, Republic of)

    1999-02-15

    Recently, large scale concrete structures such as nuclear power plants and offshore structures are actively being built in this country. These structures are subject to heavy attack due to seawater environment. A reasonable consideration for corrosion has not been paid to the structures in the past decades due to insufficient research data and guidelines. The durability is emerging as one of the most important factors. In the design and construction of concrete structures. The purpose of the present study is, therefore, to explore the corrosion mechanism and penetration mechanism of chloride ion, and to establish the evaluation procedure of durability life of concrete structures. In this study, the chloride ion concentration of seawater around our country have been analyzed and the deterioration mechanism of concrete structures have been also analyzed. The penetration mechanism of seawater into the concrete has been also studied. To this end, a comprehensive experimental program has been setup. The major test variables include the type of cement and the type of mineral admixture. The strength test as well as corrosion test have been conducted to explore the effects of chloride ion penetration on the properties of concrete. The corrosion mechanism and the penetration of chloride ion into concrete structures have been studied. These results will allow the estimation of durable life of concrete structures in nuclear power plants. The experimental results and the developed theory in the present study can be efficiently used to analyze the chloride ion penetration and to estimate the durability of concrete structures In nuclear power plants. The present study may also provide strong basis to evaluate the remaining service life of concrete structures in nuclear power plants.

  19. Carbonation-Related Microstructural Changesin Long-Term Durability Concrete

    Directory of Open Access Journals (Sweden)

    Cláudio A. Rigo da Silva

    2002-09-01

    Full Text Available This paper discusses the effects of carbonation on the microstructure of Portland cement concrete for long-term durability applications. A class C40 concrete (characteristic compression strength between 40 MPa and 44 MPa on the 28th day, according to Brazilian standard NBR 8953 was chosen for the experimental study of the carbonation effects, from which test samples were molded for accelerated test under a 100%-CO2 atmosphere after physical and mechanical characterization. It was observed that carbonation provoked a reduction of 5% to 12% of the concrete open porosity accessible to water. Flexural strength values obtained after the carbonation tests revealed a decrease of 12% and 25% in relation to the values obtained before tests on the 28th and 91st days, respectively.

  20. Factors influencing chemical durability of nuclear waste glasses

    International Nuclear Information System (INIS)

    Feng, Xiangdong; Bates, J.K.

    1993-01-01

    A short summary is given of our studies on the major factors that affect the chemical durability of nuclear waste glasses. These factors include glass composition, solution composition, SA/V (ratio of glass surface area to the volume of solution), radiation, and colloidal formation. These investigations have enabled us to gain a better understanding of the chemical durability of nuclear waste glasses and to accumulate.a data base for modeling the long-term durability of waste glass, which will be used in the risk assessment of nuclear waste disposal. This knowledge gained also enhances our ability to formulate optimal waste glass compositions

  1. Nanocomposites for Improved Physical Durability of Porous PVDF Membranes

    Science.gov (United States)

    Lai, Chi Yan; Groth, Andrew; Gray, Stephen; Duke, Mikel

    2014-01-01

    Current commercial polymer membranes have shown high performance and durability in water treatment, converting poor quality waters to higher quality suitable for drinking, agriculture and recycling. However, to extend the treatment into more challenging water sources containing abrasive particles, micro and ultrafiltration membranes with enhanced physical durability are highly desirable. This review summarises the current limits of the existing polymeric membranes to treat harsh water sources, followed by the development of nanocomposite poly(vinylidene fluoride) (PVDF) membranes for improved physical durability. Various types of nanofillers including nanoparticles, carbon nanotubes (CNT) and nanoclays were evaluated for their effect on flux, fouling resistance, mechanical strength and abrasion resistance on PVDF membranes. The mechanisms of abrasive wear and how the more durable materials provide resistance was also explored. PMID:24957121

  2. A generalized definition for waste form durability

    International Nuclear Information System (INIS)

    Fanning, T. H.; Bauer, T. H.; Morris, E. E.; Wigeland, R. A.

    2002-01-01

    When evaluating waste form performance, the term ''durability'' often appears in casual discourse, but in the technical literature, the focus is often on waste form ''degradation'' in terms of mass lost per unit area per unit time. Waste form degradation plays a key role in developing models of the long-term performance in a repository environment, but other factors also influence waste form performance. These include waste form geometry; density, porosity, and cracking; the presence of cladding; in-package chemistry feedback; etc. The paper proposes a formal definition of waste form ''durability'' which accounts for these effects. Examples from simple systems as well as from complex models used in the Total System Performance Assessment of Yucca Mountain are provided. The application of ''durability'' in the selection of bounding models is also discussed

  3. Flexible, durable proton energy degraders for the GE PETtrace

    DEFF Research Database (Denmark)

    Engle, J. W.; Gagnon, K.; Severin, Gregory

    2012-01-01

    In order to limit the formation of radioisotopic impurities during proton bombardments of solid targets, two methods of introducing degrader foils into the beam upstream of the target were tested. The first design uses a 445 μm thick fixed degrader machined from a single piece of aluminum....... The second design permits introduction of foils made of any material and was tested with foils as thick as 635 μm (also aluminium). In both cases, the foils are cooled with by water flowing through an annular channel outside the radius of the beam. Both designs proved durable and tolerated proton beam...

  4. Polylactic Acid-Based Polymer Blends for Durable Applications

    Science.gov (United States)

    Finniss, Adam

    , showing that no matter the treatment or formulation, PLA achieved a maximum of 30-35 percent crystallinity. Samples receiving no treatment as well as those with annealing, the addition of graphene, and in some cases annealing/graphene were subjected to both solvent and hydrolytic degradation in order to find the most stable blend or treatment. Both pellets and molded parts of varying thicknesses were investigated to evaluate the effect of diffusional resistance on long term durability. It was determined that while the addition of crystallinity or graphene platelets can provide a temporary barrier against diffusion of attacking species, PLA polymer itself is not dimensionally stable over the long lifecycle required for durable applications such as for automotive parts. In fact, PLA-only molded panels aged in distilled water at 50°C for 42 days experienced over 99% viscosity loss regardless of which treatment was applied, and nearly all mechanical strength was lost during this time. Furthermore, while the addition of graphene and the heat treatment produced diffusion barriers which could slightly enhance PLA's degradation resistance, the treatments caused the already fragile polymer to become very brittle. Solvent degradation experiments also showed that molded parts containing more than 40% PLA loading lost in excess of 75% of the original viscosity no matter what treatment was used. This showed that these materials are likely to fail well before a sufficiently long lifecycle for durable goods is achieved. Polycarbonate rich blends with less than 30% PLA as the dispersed phase showed excellent property retention after the accelerated aging tests. Formulations with up to 20% PLA content had degradation results that were nearly identical to those of 100% polycarbonate, which literature has shown to have useful lifecycles for durable applications of up to 20 years. By completely encapsulating the PLA in the polycarbonate matrix, which occurred at about 30% PLA by maximum, it

  5. Concrete durability

    Directory of Open Access Journals (Sweden)

    Gaspar Tébar, Demetrio

    1991-03-01

    Full Text Available The evidence that the concrete is not a material for ever was noticed from the beginning of its industrial use. In the present work, the author describes the studies carried out during the last century and the early ages of the present one, mainly devoted to the study of the durability in sea water. At the present days, and in spite of the numerous papers published from then, the study of the concrete durability continues focusing the research priorities and economical resources of researchers and industries related with this material. Moreover, the new laboratory techniques are allowing to understand old problems and even to open again the discussion on reaction mechanisms which were believed to be completely understood. The article finalizes with a brief description of the numerous studies carried out at the Institute Eduardo Torroja on concrete durability, mainly those related with the resistance against gypsum attack (so abundant in our country land and against sea water attack.

    La realidad de que el hormigón no es un material eterno y es susceptible de sufrir ataques por agentes químicos, fue constatada desde el comienzo mismo de su uso industrial. En el presente trabajo el autor enumera los estudios realizados el siglo pasado y a comienzos del presente sobre la durabilidad del hormigón en agua de mar. En la actualidad y a pesar de los numerosos trabajos desarrollados desde entonces, el estudio de la durabilidad del hormigón sigue centrando la atención prioritaria y los recursos económicos de los investigadores e industrias relacionadas con este material. Además las nuevas técnicas de estudio están permitiendo comprender antiguos problemas e incluso reabrir la discusión sobre mecanismos de reacción que se creían completamente explicados. Finaliza el artículo con una descripción somera de los múltiples trabajos realizados en el Instituto Eduardo Torreja sobre la materia, en especial los estudios realizados sobre

  6. Influence of chloride admixtures on cement matrix durability

    International Nuclear Information System (INIS)

    Sheikh, I.A.; Zamorani, E.; Serrini, G.

    1989-01-01

    The influence of various inorganic salts, as chloride admixtures to Portland cement, on the mechanical properties and the durability of the matrix has been studied. The salts used in this study are chromium, nickel and cadmium chlorides. Improved compressive strength values are obtained which have been correlated to the stable metal hydroxide formation in high pH environment. Under static water conditions at 50 0 C, hydrolyzed chloride ions exhibit adverse effects on the matrix durability through rapid release of calcium as calcium chloride in the initial period of leaching. On the contrary, enhanced matrix durability is obtained on long term leaching in the case of cement containing chromium chloride

  7. Effect of Unprofessional Supervision on Durability of Buildings.

    Science.gov (United States)

    Yahaghi, Javad

    2018-02-01

    The durability of buildings which depends on the nature of the supervisory system used in their construction is an important feature of the construction industry. This article tries to draw the readers' attention to the effect of untrained and unprofessional building supervisors and their unethical performance on the durability of buildings.

  8. Mechanical and Durability Properties of Concrete Made with Used Foundry Sand as Fine Aggregate

    Directory of Open Access Journals (Sweden)

    G. Ganesh Prabhu

    2015-01-01

    Full Text Available In recent years, the construction industry has been faced with a decline in the availability of natural sand due to the growth of the industry. On the other hand, the metal casting industries are being forced to find ways to safely dispose of waste foundry sand (FS. With the aim of resolving both of these issues, an investigation was carried out on the reuse of waste FS as an alternative material to natural sand in concrete production, satisfied with relevant international standards. The physical and chemical properties of the FS were addressed. The influence of FS on the behaviour of concrete was evaluated through strength and durability properties. The test results revealed that compared to the concrete mixtures with a substitution rate of 30%, the control mixture had a strength value that was only 6.3% higher, and this enhancement is not particularly high. In a similar manner, the durability properties of the concrete mixtures containing FS up to 30% were relatively close to those of control mixture. From the test results, it is suggested that FS with a substitution rate of up to 30% can be effectively used in concrete production without affecting the strength and durability properties of the concrete.

  9. Mechanical and Durability Properties of Fly Ash Based Concrete Exposed to Marine Environment

    Science.gov (United States)

    Kagadgar, Sarfaraz Ahmed; Saha, Suman; Rajasekaran, C.

    2017-06-01

    Efforts over the past few years for improving the performance of concrete suggest that cement replacement with mineral admixtures can enhance the strength and durability of concrete. Feasibility of producing good quality concrete by using alccofine and fly ash replacements is investigated and also the potential benefits from their incorporation were looked into. In this study, an attempt has been made to assess the performance of concrete in severe marine conditions exposed upto a period of 150 days. This work investigates the influence of alccofine and fly ash as partial replacement of cement in various percentages (Alccofine - 5% replacement to cement content) and (fly ash - 0%, 15%, 30%, 50% & 60% to total cementitious content) on mechanical and durability properties (Permit ion permeability test and corrosion current density) of concrete. Usage of alccofine and high quantity of fly ash as additional cementitious materials in concrete has resulted in higher workability of concrete. Inclusion of alccofine shows an early strength gaining property whereas fly ash results in gaining strength at later stage. Concrete mixes containing 5% alccofine with 15% fly ash replacement reported greater compressive strength than the other concrete mixes cured in both curing conditions. Durability test conducted at 56 and 150 days indicated that concrete containing higher percentages of fly ash resulted in lower permeability as well lesser corrosion density.

  10. NiCrNx interlayer thickness dependence of spectral performance and environmental durability of protected-silver mirrors

    Science.gov (United States)

    Xu, Xu; Li, Bincheng; He, Wenyan; Wang, Changjun; Wei, Ming

    2018-04-01

    Gemini-style protected-silver mirror (Sub / NiCrNx / Ag / NiCrNx / SiNx / Air) is a suitable choice for optical instruments requiring both long-term environmental durability and high broadband reflectance. Three Gemini-style protected-silver mirrors with NiCrNx interlayer thicknesses between 0.1 and 0.6 nm were prepared by magnetron sputtering, and the dependences of spectral properties and environmental durability of these protected-silver mirrors on the thickness of NiCrNx interlayer between the silver layer and SiNx layer were investigated in-depth. The reflectance, transmittance and total scattering loss measurements, optical microscope, and scanning electron microscope imaging were employed to characterize the spectral properties and surface morphology, and accelerated environmental tests, including humidity test and salt fog test, were applied to investigate the environmental durability. The experimental results showed that both optical and corrosion-resistant properties of protected-silver mirrors were NiCrNx interlayer thickness dependent, and an optimum NiCrNx interlayer thickness should be ˜0.3 nm for Gemini-style protected-silver mirrors to have reasonably both high reflectance in a broadband spectral range from visible to far infrared and good corrosion resistance for long-lifetime applications in harsh environments.

  11. Durability of high performance concrete in seawater

    International Nuclear Information System (INIS)

    Amjad Hussain Memon; Salihuddin Radin Sumadi; Rabitah Handan

    2000-01-01

    This paper presents a report on the effects of blended cements on the durability of high performance concrete (HPC) in seawater. In this research the effect of seawater was investigated. The specimens were initially subjected to water curing for seven days inside the laboratory at room temperature, followed by seawater curing exposed to tidal zone until testing. In this study three levels of cement replacement (0%, 30% and 70%) were used. The combined use of chemical and mineral admixtures has resulted in a new generation of concrete called HPC. The HPC has been identified as one of the most important advanced materials necessary in the effort to build a nation's infrastructure. HPC opens new opportunities in the utilization of the industrial by-products (mineral admixtures) in the construction industry. As a matter of fact permeability is considered as one of the fundamental properties governing the durability of concrete in the marine environment. Results of this investigation indicated that the oxygen permeability values for the blended cement concretes at the age of one year are reduced by a factor of about 2 as compared to OPC control mix concrete. Therefore both blended cement concretes are expected to withstand in the seawater exposed to tidal zone without serious deterioration. (Author)

  12. Research on Grooved Concrete Pavement Based on the Durability of Its Anti-Skid Performance

    Directory of Open Access Journals (Sweden)

    Mulian Zheng

    2018-05-01

    Full Text Available The objectives of the present study are to investigate the anti-skid performance of concrete pavement and to attempt to enhance its durability by two different methods: using a longitudinally-transversely grooved (LT form, and using a self-developed composite curing agent containing paraffin and Na2SiO3 as the main ingredients. The friction coefficient (μ was measured by self-developed equipment to evaluate the anti-skid performance of samples with three different groove forms (LT, longitudinally grooved (L, and transversely grooved (T. Abrasion tests were then carried out to evaluate the durability of the anti-skid performance. The results indicated that anti-skid performance of LT samples was approximately 46.2% greater than that of T samples, but its durability was not as significant as that of T samples. However, the resistance to abrasion could be improved by using the aforementioned curing agent. Comparisons were carried out between samples sprayed the curing agent and control samples without any curing agent under standard conditions. It was found that the application of the curing agent increased the anti-skid durability of concrete by 35.4%~47.8%, proving it to be a useful and promising technique.

  13. Chemical durability and degradation mechanisms of HT9 based alloy waste forms with variable Zr content

    Energy Technology Data Exchange (ETDEWEB)

    Olson, L. N. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-10-30

    In Corrosion studies were undertaken on alloy waste forms that can result from advanced electrometallurgical processing techniques to better classify their durability and degradation mechanisms. The waste forms were based on the RAW3-(URe) composition, consisting primarily of HT9 steel and other elemental additions to simulate nuclear fuel reprocessing byproducts. The solution conditions of the corrosion studies were taken from an electrochemical testing protocol, and meant to simulate conditions in a repository. The alloys durability was examined in alkaline and acidic brines.

  14. Durability and degradation of HT9 based alloy waste forms with variable Ni and Cr content

    Energy Technology Data Exchange (ETDEWEB)

    Olson, L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-12-31

    Short-term electrochemical and long-term hybrid electrochemical corrosion tests were performed on alloy waste forms in reference aqueous solutions that bound postulated repository conditions. The alloy waste forms investigated represent candidate formulations that can be produced with advanced electrochemical treatment of used nuclear fuel. The studies helped to better understand the alloy waste form durability with differing concentrations of nickel and chromium, species that can be added to alloy waste forms to potentially increase their durability and decrease radionuclide release into the environment.

  15. A durability study of a paracorporeal pulsatile electro-mechanical pneumatic biventricular assist device.

    Science.gov (United States)

    Choi, Hyuk; Lee, Heung-Man; Nam, Kyoung Won; Choi, Jaesoon; Lee, Jung-Joo; Kim, Ho Chul; Song, Seung Joon; Ahn, Chi Bum; Son, Ho Sung; Lim, Choon Hak; Son, Kuk Hui; Park, Yong Doo; Jeong, Gi Seok; Sun, Kyung

    2011-06-01

    In 2002, the paracorporeal pulsatile electro-mechanical pneumatic ventricular assist device (VAD) began to be developed by the Korea Artificial Organ Center at Korea University under a Health & Medical Technology Research and Development program which finished in 2008. In vitro durability testing was conducted on the paracorporeal pulsatile pneumatic VAD to determine device durability and to evaluate device failures. The 1- and 2-year reliability of the paracorporeal pulsatile pneumatic VAD was shown to be 91.2% and 54.9%, respectively, with an 80% confidence level. Failure modes were analyzed using fault tree analysis, with customized software continuously acquiring data during the test period. After this period, 21 in vivo animal tests were done, with 14 cases of left atrium to left ventricle (LV) inflow cannulation (36Fr)/outflow grafting to descending aorta, and seven cases of apex cannulation of LV to descending aorta (12 mm). The longest postoperative day (182 days) in Korea was recently recorded in in vivo animal testing (bovine, 90 kg, male, 3.5-4.0 L/min flow rate, and 55 bpm). © 2011, Copyright the Authors. Artificial Organs © 2011, International Center for Artificial Organs and Transplantation and Wiley Periodicals, Inc.

  16. Extremely Durable, Flexible Supercapacitors with Greatly Improved Performance at High Temperatures.

    Science.gov (United States)

    Kim, Sung-Kon; Kim, Hae Jin; Lee, Jong-Chan; Braun, Paul V; Park, Ho Seok

    2015-08-25

    The reliability and durability of energy storage devices are as important as their essential characteristics (e.g., energy and power density) for stable power output and long lifespan and thus much more crucial under harsh conditions. However, energy storage under extreme conditions is still a big challenge because of unavoidable performance decays and the inevitable damage of components. Here, we report high-temperature operating, flexible supercapacitors (f-SCs) that can provide reliable power output and extreme durability under severe electrochemical, mechanical, and thermal conditions. The outstanding capacitive features (e.g., ∼40% enhancement of the rate capability and a maximum capacitances of 170 F g(-1) and 18.7 mF cm(-2) at 160 °C) are attributed to facilitated ion transport at elevated temperatures. Under high-temperature operation and/or a flexibility test in both static and dynamic modes at elevated temperatures >100 °C, the f-SCs showed extreme long-term stability of 100000 cycles (>93% of initial capacitance value) and mechanical durability after hundreds of bending cycles (at bend angles of 60-180°). Even at 120 °C, the versatile design of tandem serial and parallel f-SCs was demonstrated to provide both desirable energy and power requirements at high temperatures.

  17. Encapsulation of TRISO particle fuel in durable soda-lime-silicate glasses

    International Nuclear Information System (INIS)

    Heath, Paul G.; Corkhill, Claire L.; Stennett, Martin C.; Hand, Russell J.; Meyer, Willem C.H.M.; Hyatt, Neil C.

    2013-01-01

    Tri-Structural Isotropic (TRISO) coated particle-fuel is a key component in designs for future high temperature nuclear reactors. This study investigated the suitability of three soda lime silicate glass compositions, for the encapsulation of simulant TRISO particle fuel. A cold press and sinter (CPS) methodology was employed to produce TRISO particle–glass composites. Composites produced were determined to have an aqueous durability, fracture toughness and Vickers’ hardness comparable to glasses currently employed for the disposal of high level nuclear wastes. Sintering at 700 °C for 30 min was found to remove all interconnected porosity from the composite bodies and oxidation of the outer pyrolytic carbon layer during sintering was prevented by processing under a 5% H 2 /N 2 atmosphere. However, the outer pyrolytic carbon layer was not effectively wetted by the encapsulating glass matrix. The aqueous durability of the TRISO particle–glass composites was investigated using PCT and MCC-1 tests combined with geochemical modelling. It was found that durability was dependent on silicate and calcium solution saturation. This study provides significant advancements in the preparation of TRISO particle encapsulant waste forms. The potential for the use of non-borosilicate sintered glass composites for TRISO particle encapsulation has been confirmed, although further refinements are required

  18. Encapsulation of TRISO particle fuel in durable soda-lime-silicate glasses

    Energy Technology Data Exchange (ETDEWEB)

    Heath, Paul G.; Corkhill, Claire L.; Stennett, Martin C.; Hand, Russell J. [Immobilisation Science Laboratory, Department of Materials Science and Engineering, Robert Hadfield Building, University of Sheffield, Sheffield S1 3JD (United Kingdom); Meyer, Willem C.H.M. [Necsa, South African Nuclear Energy Corporation, PO Box 582, Pretoria, Gauteng (South Africa); Hyatt, Neil C., E-mail: n.c.hyatt@sheffield.ac.uk [Immobilisation Science Laboratory, Department of Materials Science and Engineering, Robert Hadfield Building, University of Sheffield, Sheffield S1 3JD (United Kingdom)

    2013-05-15

    Tri-Structural Isotropic (TRISO) coated particle-fuel is a key component in designs for future high temperature nuclear reactors. This study investigated the suitability of three soda lime silicate glass compositions, for the encapsulation of simulant TRISO particle fuel. A cold press and sinter (CPS) methodology was employed to produce TRISO particle–glass composites. Composites produced were determined to have an aqueous durability, fracture toughness and Vickers’ hardness comparable to glasses currently employed for the disposal of high level nuclear wastes. Sintering at 700 °C for 30 min was found to remove all interconnected porosity from the composite bodies and oxidation of the outer pyrolytic carbon layer during sintering was prevented by processing under a 5% H{sub 2}/N{sub 2} atmosphere. However, the outer pyrolytic carbon layer was not effectively wetted by the encapsulating glass matrix. The aqueous durability of the TRISO particle–glass composites was investigated using PCT and MCC-1 tests combined with geochemical modelling. It was found that durability was dependent on silicate and calcium solution saturation. This study provides significant advancements in the preparation of TRISO particle encapsulant waste forms. The potential for the use of non-borosilicate sintered glass composites for TRISO particle encapsulation has been confirmed, although further refinements are required.

  19. Adhesives for Achieving Durable Bonds with Acetylated Wood

    Science.gov (United States)

    Charles Frihart; Rishawn Brandon; James Beecher; Rebecca Ibach

    2017-01-01

    Acetylation of wood imparts moisture durability, decay resistance, and dimensional stability to wood; however, making durable adhesive bonds with acetylated wood can be more difficult than with unmodified wood. The usual explanation is that the acetylated surface has fewer hydroxyl groups, resulting in a harder-to-wet surface and in fewer hydrogen bonds between wood...

  20. 30 CFR 816.73 - Disposal of excess spoil: Durable rock fills.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Disposal of excess spoil: Durable rock fills...-SURFACE MINING ACTIVITIES § 816.73 Disposal of excess spoil: Durable rock fills. The regulatory authority may approve the alternative method of disposal of excess durable rock spoil by gravity placement in...

  1. 30 CFR 817.73 - Disposal of excess spoil: Durable rock fills.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Disposal of excess spoil: Durable rock fills...-UNDERGROUND MINING ACTIVITIES § 817.73 Disposal of excess spoil: Durable rock fills. The regulatory authority may approve the alternative method of disposal of excess durable rock spoil by gravity placement in...

  2. Long-term acceptability, durability and bio-efficacy of ZeroVector® durable lining for vector control in Papua New Guinea.

    Science.gov (United States)

    Kuadima, Joseph J; Timinao, Lincoln; Naidi, Laura; Tandrapah, Anthony; Hetzel, Manuel W; Czeher, Cyrille; Pulford, Justin

    2017-02-28

    This study examined the acceptability, durability and bio-efficacy of pyrethroid-impregnated durable lining (DL) over a three-year period post-installation in residential homes across Papua New Guinea (PNG). ZeroVector ® ITPS had previously been installed in 40 homes across four study sites representing a cross section of malaria transmission risk and housing style. Structured questionnaires, DL visual inspections and group interviews (GIs) were completed with household heads at 12- and 36-months post-installation. Three DL samples were collected from all households in which it remained 36-months post-installation to evaluate the bio-efficacy of DL on Anopheles mosquitoes. Bio-efficacy testing followed WHO guidelines for the evaluation of indoor residual spraying. The DL was still intact in 86 and 39% of study homes at the two time periods, respectively. In homes in which the DL was still intact, 92% of household heads considered the appearance at 12-months post installation to be the same as, or better than, that at installation compared to 59% at 36-months post-installation. GIs at both time points confirmed continuing high acceptance of DL, based in large part of the perceived attractiveness and functionality of the material. However, participants frequently asserted that they, or their family members, had ceased or reduced their use of mosquito nets as a result of the DL installation. A total of 16 houses were sampled for bio-efficacy testing across the 4 study sites at 36-months post-installation. Overall, combining all sites and samples, both knock-down at 30 min and mortality at 24 h were 100%. The ZeroVector ® DL installation remained highly acceptable at 36-months post-installation, the material and fixtures proved durable and the efficacy against malaria vectors did not decrease. However, the DL material had been removed from over 50% of the original study homes 3 years post-installation, largely due to deteriorating housing infrastructure

  3. A testing platform for durability studies of polymers and fiber-reinforced polymer composites under concurrent hygrothermo-mechanical stimuli.

    Science.gov (United States)

    Gomez, Antonio; Pires, Robert; Yambao, Alyssa; La Saponara, Valeria

    2014-12-11

    The durability of polymers and fiber-reinforced polymer composites under service condition is a critical aspect to be addressed for their robust designs and condition-based maintenance. These materials are adopted in a wide range of engineering applications, from aircraft and ship structures, to bridges, wind turbine blades, biomaterials and biomedical implants. Polymers are viscoelastic materials, and their response may be highly nonlinear and thus make it challenging to predict and monitor their in-service performance. The laboratory-scale testing platform presented herein assists the investigation of the influence of concurrent mechanical loadings and environmental conditions on these materials. The platform was designed to be low-cost and user-friendly. Its chemically resistant materials make the platform adaptable to studies of chemical degradation due to in-service exposure to fluids. An example of experiment was conducted at RT on closed-cell polyurethane foam samples loaded with a weight corresponding to ~50% of their ultimate static and dry load. Results show that the testing apparatus is appropriate for these studies. Results also highlight the larger vulnerability of the polymer under concurrent loading, based on the higher mid-point displacements and lower residual failure loads. Recommendations are made for additional improvements to the testing apparatus.

  4. A Testing Platform for Durability Studies of Polymers and Fiber-reinforced Polymer Composites under Concurrent Hygrothermo-mechanical Stimuli

    Science.gov (United States)

    Gomez, Antonio; Pires, Robert; Yambao, Alyssa; La Saponara, Valeria

    2014-01-01

    The durability of polymers and fiber-reinforced polymer composites under service condition is a critical aspect to be addressed for their robust designs and condition-based maintenance. These materials are adopted in a wide range of engineering applications, from aircraft and ship structures, to bridges, wind turbine blades, biomaterials and biomedical implants. Polymers are viscoelastic materials, and their response may be highly nonlinear and thus make it challenging to predict and monitor their in-service performance. The laboratory-scale testing platform presented herein assists the investigation of the influence of concurrent mechanical loadings and environmental conditions on these materials. The platform was designed to be low-cost and user-friendly. Its chemically resistant materials make the platform adaptable to studies of chemical degradation due to in-service exposure to fluids. An example of experiment was conducted at RT on closed-cell polyurethane foam samples loaded with a weight corresponding to ~50% of their ultimate static and dry load. Results show that the testing apparatus is appropriate for these studies. Results also highlight the larger vulnerability of the polymer under concurrent loading, based on the higher mid-point displacements and lower residual failure loads. Recommendations are made for additional improvements to the testing apparatus. PMID:25548950

  5. Evaluation on the long-term durability and leachability of cemented waste form

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ki Hong; Lee, Jae Won; Ryue, Young Gerl [Korea Atomic Energy Research Institute, Taejon (Korea)

    1998-08-01

    The long-term durability and leachability on the cemented waste form containing boric acids produced in domestic nuclear nuclear power plants were evaluated. Compressive strength of waste form after durability test such as thermal stability and water immersion cycle was higher than before test and consistently increased with increasing of test time in range of 83 of 286 kgf/cm{sup 2}. Long-term leachability was evaluated by standard test methods, leach affecting factors, and prediction of long-term leachability with result data of short-term leach test. In all leach tests, the release of Cs-137 was controlled by diffusion, whereas release of Co-60 was not controlled by diffusion. Leach rate of Cs-137 was relatively constant at standard leach test methods such as NAS 16.1, IAEA, ISO-6961, and MCC-1, but that of Co-60 increased with leachant-renewal frequencies. The leach rate of both Cs-137 and Co-60 increased as test temperature raised. The release of Co-137 decreased in simulated seawater as leachant, but increased with increasing leachant volume. The prediciton of long-term release of Cs-137 from large-scale waste form using the results from short-term leach test of small-scale waste form were within {+-} 5% of actual release. The leachability indexes of Cs-137 were between 6.5 and 7.5 and those of Co-60 were ranged from 11.6 to 13.3, increasing as cumulative leaching time increased. (author). 22 refs., 14 figs., 15 tabs.

  6. Highly efficient and durable TiN nanofiber electrocatalyst supports.

    Science.gov (United States)

    Kim, Hyun; Cho, Min Kyung; Kwon, Jeong An; Jeong, Yeon Hun; Lee, Kyung Jin; Kim, Na Young; Kim, Min Jung; Yoo, Sung Jong; Jang, Jong Hyun; Kim, Hyoung-Juhn; Nam, Suk Woo; Lim, Dong-Hee; Cho, EunAe; Lee, Kwan-Young; Kim, Jin Young

    2015-11-28

    To date, carbon-based materials including various carbon nanostructured materials have been extensively used as an electrocatalyst support for proton exchange membrane fuel cell (PEMFC) applications due to their practical nature. However, carbon dissolution or corrosion caused by high electrode potential in the presence of O2 and/or water has been identified as one of the main failure modes for the device operation. Here, we report the first TiN nanofiber (TNF)-based nonwoven structured materials to be constructed via electrospinning and subsequent two-step thermal treatment processes as a support for the PEMFC catalyst. Pt catalyst nanoparticles (NPs) deposited on the TNFs (Pt/TNFs) were electrochemically characterized with respect to oxygen reduction reaction (ORR) activity and durability in an acidic medium. From the electrochemical tests, the TNF-supported Pt catalyst was better and more stable in terms of its catalytic performance compared to a commercially available carbon-supported Pt catalyst. For example, the initial oxygen reduction performance was comparable for both cases, while the Pt/TNF showed much higher durability from an accelerated degradation test (ADT) configuration. It is understood that the improved catalytic roles of TNFs on the supported Pt NPs for ORR are due to the high electrical conductivity arising from the extended connectivity, high inertness to the electrochemical environment and strong catalyst-support interactions.

  7. Oxidative degradation of acid doped polybenzimidazole membranes and fuel cell durability in the presence of ferrous ions

    DEFF Research Database (Denmark)

    Liao, Jianhui; Yang, Jingshuai; Li, Qingfeng

    2013-01-01

    Phosphoric acid doped polybenzimidazole membranes have been explored as proton exchange membranes for high temperature polymer electrolyte membrane fuel cells. Long-term durability of the membrane is of critical concern and has been evaluated by accelerated degradation tests under Fenton conditions...... of the polymer. Fuel cell durability tests with contaminations of ferrous ions did show considerable performance degradation, however, primarily due to the catalyst deterioration rather than the membrane degradation........ In this study effects of phosphoric acid and ferrous ions were investigated by measurements of the weight loss, intrinsic viscosity and size exclusion chromatography (SEC) of the polymer membranes. Ferrous ions resulted in, as expected, catalytic formation of peroxide radicals and hence the accelerated polymer...

  8. Flexible, durable proton energy degraders for the GE PETtrace

    Energy Technology Data Exchange (ETDEWEB)

    Engle, J. W.; Gagnon, K.; Severin, G. W.; Valdovinos, H. F.; Nickles, R. J.; Barnhart, T. E. [Chemistry Division - Isotopes, Inorganics and Actinides, Los Alamos National Laboratory, Los Alamos, NM (United States); Department of Radiation Oncology, University of Washington, Seattle, WA (United States); Hevesy Laboratory, Danish Technical University, Risoe (Denmark); Department of Medical Physics, University of Wisconsin, WI, Madison (United States)

    2012-12-19

    In order to limit the formation of radioisotopic impurities during proton bombardments of solid targets, two methods of introducing degrader foils into the beam upstream of the target were tested. The first design uses a 445 {mu}m thick fixed degrader machined from a single piece of aluminum. The second design permits introduction of foils made of any material and was tested with foils as thick as 635 {mu}m (also aluminium). In both cases, the foils are cooled with by water flowing through an annular channel outside the radius of the beam. Both designs proved durable and tolerated proton beam currents in excess of 80 {mu}A.

  9. ACCELERATED METHODS FOR ESTIMATING THE DURABILITY OF PLAIN BEARINGS

    Directory of Open Access Journals (Sweden)

    Myron Czerniec

    2014-09-01

    Full Text Available The paper presents methods for determining the durability of slide bearings. The developed methods enhance the calculation process by even 100000 times, compared to the accurate solution obtained with the generalized cumulative model of wear. The paper determines the accuracy of results for estimating the durability of bearings depending on the size of blocks of constant conditions of contact interaction between the shaft with small out-of-roundedness and the bush with a circular contour. The paper gives an approximate dependence for determining accurate durability using either a more accurate or an additional method.

  10. Bases for extrapolating materials durability in fuel storage pools

    International Nuclear Information System (INIS)

    Johnson, A.B. Jr.

    1994-12-01

    A major body of evidence indicates that zirconium alloys have the most consistent and reliable durability in wet storage, justifying projections of safe wet storage greater than 50 y. Aluminum alloys have the widest range of durabilities in wet storage; systematic control and monitoring of water chemistry have resulted in low corrosion rates for more than two decades on some fuels and components. However, cladding failures have occurred in a few months when important parameters were not controlled. Stainless steel is extremely durable when stress, metallurgical and water chemistry factors are controlled. LWR SS cladding has survived for 25 y in wet storage. However, sensitized, stressed SS fuels and components have seriously degraded in fuel storage pools (FSPs) at ∼ 30 C. Satisfactory durability of fuel assembly and FSP component materials in extended wet storage requires investments in water quality management and surveillance, including chemical and biological factors. The key aspect of the study is to provide storage facility operators and other decision makers a basis to judge the durability of a given fuel type in wet storage as a prelude to basing other fuel management plans (e.g. dry storage) if wet storage will not be satisfactory through the expected period of interim storage

  11. Integrated approach for investigating the durability of self-consolidating concrete to sulfate attack

    Science.gov (United States)

    Bassuoni, Mohamed Tamer F.

    The growing use of self-consolidating concrete (SCC) in various infrastructure applications exposed to sulfate-rich environments necessitates conducting comprehensive research to evaluate its durability to external sulfate attack. Since the reliability and adequacy of standard sulfate immersion tests have been questioned, the current thesis introduced an integrated testing approach for assessing the durability of a wide scope of SCC mixtures to external sulfate attack. This testing approach involved progressive levels of complexity from single to multiple damage processes. A new series of sulfate attack tests involving multiple field-like parameters and combined damage mechanisms (various cations, controlled pH, wetting-drying, partial immersion, freezing-thawing, and cyclic cold-hot conditions with or without sustained flexural loading) were designed to evaluate the performance (suitability) of the SCC mixtures under various sulfate attack exposure scenarios. The main mixture design variables of SCC included the type of binder (single, binary, ternary and quaternary), air-entrainment, sand-to-aggregate mass ratio and hybrid fibre reinforcement. The comprehensive database and knowledge obtained from this research were used to develop smart models (fuzzy and neuro-fuzzy inference systems) based on artificial-intelligence to evaluate and predict the performance of the SCC mixtures under various sulfate attack exposure regimes implemented in this study. In full immersion tests involving high concentration sodium and magnesium sulfate solutions with controlled pH, the low penetrability of SCC was responsible for the high durability of specimens. Ternary and quaternary cementitious systems with or without limestone materials provided a passivating layer, with or without acid neutralization capacity, which protected SCC from severe damage in the aggressive sulfuric acid and ammonium sulfate solutions. In contrast to conclusions drawn from the sodium sulfate immersion

  12. Durability and degradation analysis of hydrocarbon ionomer membranes in polymer electrolyte fuel cells accelerated stress evaluation

    Science.gov (United States)

    Shimizu, Ryo; Tsuji, Junichi; Sato, Nobuyuki; Takano, Jun; Itami, Shunsuke; Kusakabe, Masato; Miyatake, Kenji; Iiyama, Akihiro; Uchida, Makoto

    2017-11-01

    The chemical durabilities of two proton-conducting hydrocarbon polymer electrolyte membranes, sulfonated benzophenone poly(arylene ether ketone) (SPK) semiblock copolymer and sulfonated phenylene poly(arylene ether ketone) (SPP) semiblock copolymer are evaluated under accelerated open circuit voltage (OCV) conditions in a polymer electrolyte fuel cell (PEFC). Post-test characterization of the membrane electrodes assemblies (MEAs) is carried out via gel permeation chromatography (GPC) and nuclear magnetic resonance (NMR) spectroscopy. These results are compared with those of the initial MEAs. The SPP cell shows the highest OCV at 1000 h, and, in the post-test analysis, the SPP membrane retains up to 80% of the original molecular weight, based on the GPC results, and 90% of the hydrophilic structure, based on the NMR results. The hydrophilic structure of the SPP membrane is more stable after the durability evaluation than that of the SPK. From these results, the SPP membrane, with its simple hydrophilic structure, which does not include ketone groups, is seen to be significantly more resistant to radical attack. This structure leads to high chemical durability and thus impedes the chemical decomposition of the membrane.

  13. Intrahousehold Bargaining and the Demand for Consumer Durables in Brazil

    OpenAIRE

    Polato e Fava, Ana Claudia; Arends-Kuenning, Mary P.

    2013-01-01

    In Brazil, wives do most of the household work. About sixty percent of them also work outside the household, working a total of about 10 hours more per week than men. Because of this unequal distribution of household work, husbands and wives might have different priorities regarding the purchase of durable goods. Although both husbands and wives enjoy entertainment durable goods, wives might have a relative preference for household-production durable goods such as washing machines over entert...

  14. High temperature PEM fuel cells - Degradation and durability

    Energy Technology Data Exchange (ETDEWEB)

    Araya, S.S.

    2012-12-15

    This work analyses the degradation issues of a High Temperature Proton Exchange Membrane Fuel Cell (HT-PEMFC). It is based on the assumption that given the current challenges for storage and distribution of hydrogen, it is more practical to use liquid alcohols as energy carriers for fuel cells. Among these, methanol is very attractive, as it can be obtained from a variety of renewable sources and has a relatively low reforming temperature for the production of hydrogen rich gaseous mixture. The effects on HT-PEMFC of the different constituents of this gaseous mixture, known as a reformate gas, are investigated in the current work. For this, an experimental set up, in which all these constituents can be fed to the anode side of a fuel cell for testing, is put in place. It includes mass flow controllers for the gaseous species, and a vapor delivery system for the vapor mixture of the unconverted reforming reactants. Electrochemical Impedance Spectroscopy (EIS) is used to characterize the effects of these impurities. The effects of CO were tested up to 2% by volume along with other impurities. All the reformate impurities, including ethanol-water vapor mixture, cause loss in the performance of the fuel cell. In general, CO{sub 2} dilutes the reactants, if tested alone at high operating temperatures (180 C), but tends to exacerbate the effects of CO if they are tested together. On the other hand, CO and methanol-water vapor mixture degrade the fuel cell proportionally to the amounts in which they are tested. In this dissertation some of the mechanisms with which the impurities affect the fuel cell are discussed and interdependence among the effects is also studied. This showed that the combined effect of reformate impurities is more than the arithmetic sum of the individual effects of reformate constituents. The results of the thesis help to understand better the issues of degradation and durability in fuel cells, which can help to make them more durable and

  15. Increased Durability of Concrete Made with Fine Recycled Concrete Aggregates Using Superplasticizers.

    Science.gov (United States)

    Cartuxo, Francisco; de Brito, Jorge; Evangelista, Luis; Jiménez, José Ramón; Ledesma, Enrique F

    2016-02-08

    This paper evaluates the influence of two superplasticizers (SP) on the durability properties of concrete made with fine recycled concrete aggregate (FRCA). For this purpose, three families of concrete were tested: concrete without SP, concrete made with a regular superplasticizer and concrete made with a high-performance superplasticizer. Five volumetric replacement ratios of natural sand by FRCA were tested: 0%, 10%, 30%, 50% and 100%. Two natural gravels were used as coarse aggregates. All mixes had the same particle size distribution, cement content and amount of superplasticizer. The w/c ratio was calibrated to obtain similar slump. The results showed that the incorporation of FRCA increased the water absorption by immersion, the water absorption by capillary action, the carbonation depth and the chloride migration coefficient, while the use of superplasticizers highly improved these properties. The incorporation of FRCA jeopardized the SP's effectiveness. This research demonstrated that, from a durability point of view, the simultaneous incorporation of FRCA and high-performance SP is a viable sustainable solution for structural concrete production.

  16. Development of a global, predictive and performance approach of reinforced concrete structure durability based on durability indicators. Overview and future prospects. Microstructure characterization of concretes, study of their hydric and transport properties, assessment of free deformations and prediction of buildings lifetime

    International Nuclear Information System (INIS)

    Baroghel-Bouny, Veronique

    2008-12-01

    This document synthesizes the objectives, the adopted approach, as well as the main scientific results and the products (test methods, for example), obtained during the researches carried out or supervised by the author within various frameworks, primarily over the period 1995-2005, at LCPC as Head of the Section 'Microstructure and Durability of Concretes'. This document presents in particular a performance-based, global and predictive approach of the durability of (reinforced) concrete structures, based on the concept of durability indicators, and combining lab tests and numerical simulations. This type of approach was developed for the protection against rebar corrosion of reinforced concrete and against the degradations generated by alkali-silica reaction, within the framework of the Working Group of the French Association of Civil Engineering (AFGC) 'Concrete design for a given service life of structures - Durability indicators'. The objectives of this new approach and the selected durability indicators - simple but particularly relevant parameters with respect to the implied physicochemical mechanisms in a given environment - as well as the bases of this selection, are first of all presented. Significant examples, resulting in particular from the Research Project 'Transfers in concretes and durability of structures', from the Research Project 'Durability of reinforced concrete and of its components: management and performance-based approach', as well as from studies carried out within the framework of the Topic 'Durability' of the French National Project BHP 2000, are then presented. These examples address the understanding of the mechanisms (moisture transport, carbonation, chloride penetration, freezing, non-restrained deformations,.) or the development of tools for the characterization of concrete microstructure and of parameters related to the durability with respect to reinforcement corrosion. Among the examples given, are reported the quantification of

  17. Geochemical and petrographic studies and the relationships to durability and leach resistance of vitrified products from the in situ vitrification process

    International Nuclear Information System (INIS)

    Timmons, D.M.; Thompson, L.E.

    1996-01-01

    Soil and sludge contaminated with hazardous and radioactive materials from sites in the United States and Australia were vitrified using in situ vitrification. Some of the resulting products were subjected to detailed geochemical, leach and durability testing using a variety of analytical techniques. The leach resistance and durability performance was compared to that of vitrified high level waste with borosilicate composition. Particular attention was given to crystallization behavior, the effects of crystallization on residual melt chemistry and how crystallization influences the behavior of contaminant ions. The results of this work show that the vitrified material studied has superior chemical durability and leach resistance relative to typical borosilicate waste glasses. Crystallization behavior was variable depending upon melt chemistry and cooling history. Crystallization was not observed to adversely affect chemical durability or leach resistance

  18. Chemical durability of simulated nuclear glasses containing water

    International Nuclear Information System (INIS)

    Li, H.; Tomozawa, M.

    1995-04-01

    The chemical durability of simulated nuclear waste glasses having different water contents was studied. Results from the product consistency test (PCT) showed that glass dissolution increased with water content in the glass. This trend was not observed during MCC-1 testing. This difference was attributed to the differences in reactions between glass and water. In the PCT, the glass network dissolution controlled the elemental releases, and water in the glass accelerated the reaction rate. On the other hand, alkali ion exchange with hydronium played an important role in the MCC-1. For the latter, the amount of water introduced into a leached layer from ion-exchange was found to be much greater than that of initially incorporated water in the glass. Hence, the initial water content has no effect on glass dissolution as measured by the MCC-1 test

  19. The household decision making process in replacement of durable goods

    OpenAIRE

    Marell Molander, Agneta

    1998-01-01

    As durables are essential in many households, the level of ownership is high and, due to the high degree of penetration, a vast proportion of the current sales are replacement purchases. Even though a lot of research attention has been paid to decision making and decision processes many models are oriented towards non-durable goods and although a majority of purchases of many durable goods are replacements, few studies seem to make a distinction between a replacement purchase decision and a d...

  20. Durable solid oxide electrolysis cells and stacks

    Energy Technology Data Exchange (ETDEWEB)

    Ming Chen

    2010-08-15

    The purpose of this project was to make a substantial contribution to development of a cost competitive electrolysis technology based on solid oxide cells. The strategy was to address what had been identified as the key issues in previous research projects. Accordingly five lines of work were carried out in the here reported project: 1) Cell and stack element testing and post test characterization to identify major degradation mechanisms under electrolysis operation. 2) Development of interconnects and coatings to allow stable electrolysis operation at approx850 deg. C or above. 3) Development of seals with reduced Si emission. 4) Development of durable SOEC cathodes. 5) Modeling. Good progress has been made on several of the planned activities. The outcome and most important achievements of the current project are listed for the five lines of the work. (LN)

  1. Decoration and durability

    DEFF Research Database (Denmark)

    Riisberg, Vibeke; Munch, Anders V.

    2015-01-01

    Throughout the scales of design there has been an exploding interest in the ornament that seems to be fuelled by different kinds of digital technology and media from CAD to digital printing in both 2D and 3D. In architecture and industrial design, it is discussed as a “return of ornament” because...... from fashion and tableware to archi- tecture and link ornamentation to the aesthetics of durability....

  2. A zwitterionic macro-crosslinker for durable non-fouling coatings.

    Science.gov (United States)

    Wang, Wei; Lu, Yang; Xie, Jinbing; Zhu, Hui; Cao, Zhiqiang

    2016-03-28

    A novel zwitterionic macro-crosslinker was developed and applied to fabricate durable non-fouling coatings on a polyurethane substrate. The zwitterionic macro-crosslinker coating exhibited superior durability over the traditional brush polymer coating and was able to retain its non-fouling property even after weeks of shearing in flowing liquid.

  3. Durability of compressed soil-cement bricks

    Directory of Open Access Journals (Sweden)

    Acosta Valle, A.

    2001-06-01

    Full Text Available This papers shows the evaluation process of the durability of compressed soil-cement bricks. A great number of tests were made to determine the behavior of bricks when they are compression loaded and under the influence of moisture. Two different types of soils were used to produce the bricks, a lime-clay soil and a sand one. The sand soil is very resistant. The other one has a limited use. An experimental design was used to test the bricks. It is a rotational and quadratic method with a hexagonal figure which contains replicas at the central point. This method ensures the reliability of test results. Otherwise, it would reduce the amount of specimens necessary for the tests. The optimun moisture content is obtained by using a press machine. It is more rational than the standard Proctor compactation test, because it applies the same type and amount of energy used to produce the bricks. The obtained results show the behavior differences between the two compressed soil-cement bricks subjected to the compression test, water absorption and wetting and drying tests. The durability tests results are very important in the possible use of the bricks produced.

    En el trabajo se evalúa la durabilidad de elementos aglomerados de suelo estabilizado. Se realiza un amplio número de ensayos encaminados a determinar el comportamiento frente a la acción de las cargas y la humedad de dos suelos con características diferentes: uno limo-arcilloso y el otro arenoso. Este último presenta resultados muy favorables en ambas direcciones. El otro, con un posible uso más limitado. Se emplea un método de diseño experimental del tipo rotacional cuadrático en hexágono, con réplicas en el punto central, el que garantiza la confiabilidad de los resultados de los ensayos, a la vez que disminuye la cantidad de especímenes a ensayar. Se determina la humedad óptima a utilizar en las diferentes dosificaciones empleando la máquina compactadora, que resulta m

  4. Experimental Investigation of the Mechanical and Durability Properties of Crumb Rubber Concrete.

    Science.gov (United States)

    Liu, Hanbing; Wang, Xianqiang; Jiao, Yubo; Sha, Tao

    2016-03-07

    Recycling waste tire rubber by incorporating it into concrete has become the preferred solution to dispose of waste tires. In this study, the effect of the volume content of crumb rubber and pretreatment methods on the performances of concrete was evaluated. Firstly, the fine aggregate and mixture were partly replaced by crumb rubber to produce crumb rubber concrete. Secondly, the mechanical and durability properties of crumb rubber concrete with different replacement forms and volume contents had been investigated. Finally, the crumb rubber after pretreatment by six modifiers was introduced into the concrete mixture. Corresponding tests were conducted to verify the effectiveness of pretreatment methods as compared to the concrete containing untreated crumb rubber. It was observed that the mechanical strength of crumb rubber concrete was reduced, while durability was improved with the increasing of crumb rubber content. 20% replacement of fine aggregate and 5% replacement of the total mixture exhibited acceptable properties for practical applications. In addition, the results indicated that the modifiers had a positive impact on the mechanical and durability properties of crumb rubber concrete. It avoided the disadvantage of crumb rubber concrete having lower strength and provides a reference for the production of modified crumb rubber concrete.

  5. Experimental Investigation of the Mechanical and Durability Properties of Crumb Rubber Concrete

    Directory of Open Access Journals (Sweden)

    Hanbing Liu

    2016-03-01

    Full Text Available Recycling waste tire rubber by incorporating it into concrete has become the preferred solution to dispose of waste tires. In this study, the effect of the volume content of crumb rubber and pretreatment methods on the performances of concrete was evaluated. Firstly, the fine aggregate and mixture were partly replaced by crumb rubber to produce crumb rubber concrete. Secondly, the mechanical and durability properties of crumb rubber concrete with different replacement forms and volume contents had been investigated. Finally, the crumb rubber after pretreatment by six modifiers was introduced into the concrete mixture. Corresponding tests were conducted to verify the effectiveness of pretreatment methods as compared to the concrete containing untreated crumb rubber. It was observed that the mechanical strength of crumb rubber concrete was reduced, while durability was improved with the increasing of crumb rubber content. 20% replacement of fine aggregate and 5% replacement of the total mixture exhibited acceptable properties for practical applications. In addition, the results indicated that the modifiers had a positive impact on the mechanical and durability properties of crumb rubber concrete. It avoided the disadvantage of crumb rubber concrete having lower strength and provides a reference for the production of modified crumb rubber concrete.

  6. Enhancing the Chemical and Mechanical Durability of Polymer Electrolyte Membranes for Fuel Cell Applications

    Science.gov (United States)

    Baker, Andrew M.

    Polymer electrolyte membrane (PEM) fuel cells are energy conversion devices which generate electricity from the electrochemical reaction of hydrogen and oxygen. Currently, widespread adoption of PEM fuel cell technology is hindered by low component durability and high costs. In this work, strategies were investigated to improve the mechanical and chemical durability of the ion conducting polymer, or ionomer, which comprises the PEM, in order to directly address these limitations. Owing to their exceptional mechanical properties, carbon nanotubes (CNTs) were investigated for mechanical reinforcement of the PEM. Because of their electronic conductivity, which diminishes cell performance, two strategies were developed to enable the use of CNTs as PEM reinforcement. These systems result in enhanced mechanical properties without sacrificing performance of the PEM during operation. Further, when coated with ceria (CeO2), which scavenges radicals that are generated during operation and cause PEM chemical degradation by attacking vulnerable chemical groups in the ionomer, MWCNTs further improved PEM chemical durability. During cell fabrication, conditioning, and discharge, Ce rapidly migrates between the PEM and catalyst layers (CLs), which reduces catalyst efficiency and leaves areas of the cell defenseless against radical attacks. Therefore, in order to stabilize Ce and localize it to areas of highest radical generation, it is critical to understand and identify the relative influences of different migration mechanisms. Using a novel elemental analysis technique, Ce migration was characterized due to potential and concentration gradients, water flux, and degradation of Ce-exchanged sulfonic acid groups within the PEM. Additionally, Zr-doped ceria was employed to resist migration due to ionomer degradation which improved cell durability, without reducing performance, resulting in PEM Ce stabilization near its initial concentrations after > 1,400 hours of testing. Ce was

  7. Characterization of a well performing and durable Ni:CGO-infiltrated anode for metal-supported SOFC

    DEFF Research Database (Denmark)

    Nielsen, Jimmi; Klemensø, Trine; Graves, Christopher R.

    3000 hours of 0.25A/cm2 galvanostatic testing at 650 ºC was shown. Furthermore, it was shown on button cells that if the cathode side consisted of a dense CGO barrier layer in combination with a LSC cathode, a performance with an area specific resistance (ASR) of 0.27 Ω cm2 at 650 ºC could be obtained....... These performance and durability characteristics are very encouraging but despite several papers on metal supported SOFC with this type of infiltrated anode [1-3], the performance and the factors controlling the performance and durability is not yet well understood. Only some initial data on symmetrical cells...

  8. Durable crystalline Si photovoltaic modules based on silicone-sheet encapsulants

    Science.gov (United States)

    Hara, Kohjiro; Ohwada, Hiroto; Furihata, Tomoyoshi; Masuda, Atsushi

    2018-02-01

    Crystalline Si photovoltaic (PV) modules were fabricated with sheets of poly(dimethylsiloxane) (silicone) as an encapsulant. The long-term durability of the silicone-encapsulated PV modules was experimentally investigated. The silicone-based modules enhanced the long-term durability against potential-induced degradation (PID) and a damp-heat (DH) condition at 85 °C with 85% relative humidity (RH). In addition, we designed and fabricated substrate-type Si PV modules based on the silicone encapsulant and an Al-alloy plate as the substratum, which demonstrated high impact resistance and high incombustible performance. The high chemical stability, high volume resistivity, rubber-like elasticity, and incombustibility of the silicone encapsulant resulted in the high durability of the modules. Our results indicate that silicone is an attractive encapsulation material, as it improves the long-term durability of crystalline Si PV modules.

  9. Evaluating the in situ loading and accelerated durability of barbs located on bifurcated aorto-iliac stent-grafts.

    Science.gov (United States)

    Conti, J C; Strope, E R

    2000-01-01

    A special three-part protocol has been generated for the isolated durability testing of stent barbs. This triple protocol includes an initial evaluation on a cardiovascular duplicator to determine the loading per barb that occurs during normal flow through the stent-graft. The next stage of this protocol determined the frequency response characteristics of the bending point where the barb attaches to the stent to allow for the determination of the appropriate frequency to carry out the accelerated testing. The final part of the test includes high speed bend testing at frequencies determined in the second part of the methods to determine the long term durability of the isolated barb stent unit. The results of this testing indicated that under normal cardiovascular conditions each barb is experiencing a loading of 20 grams peak during maximum forward flow. Loading the isolated barb/stent segment at 600 beats per minute (bpm) for 400 million cycles indicated no tendency for these barbs to experience a change in physical properties. During this testing there were no barbs that broke.

  10. 75 FR 51245 - Agency Information Collection Activities; Proposed Collection; Comment Request; Durable Nursery...

    Science.gov (United States)

    2010-08-19

    ... CONSUMER PRODUCT SAFETY COMMISSION [Docket No. CPSC-2010-0088] Agency Information Collection Activities; Proposed Collection; Comment Request; Durable Nursery Products Exposure Survey AGENCY: Consumer... efforts on durable infant and toddler products. The draft Durable Nursery Products Exposure Survey...

  11. Durability of fibre reinforced concrete structures exposed to combined mechanical and environmental load

    DEFF Research Database (Denmark)

    Hansen, Ernst Jan De Place; Hansen, Kurt Kielsgaard

    1999-01-01

    The main conclusions from a research project on durability of cracked fibre reinforced concrete structures exposed to chlorides, water or freeze-thaw are presented. The effect of fibres and cracks on the durability of concrete is studied.......The main conclusions from a research project on durability of cracked fibre reinforced concrete structures exposed to chlorides, water or freeze-thaw are presented. The effect of fibres and cracks on the durability of concrete is studied....

  12. Highly Durable Direct Methanol Fuel Cell with Double-Layered Catalyst Cathode

    Directory of Open Access Journals (Sweden)

    Jing Liu

    2015-01-01

    Full Text Available Polymer electrolyte membrane (PEM is one of the key components in direct methanol fuel cells. However, the PEM usually gets attacked by reactive oxygen species during the operation period, resulting in the loss of membrane integrity and formation of defects. Herein, a double-layered catalyst cathode electrode consisting of Pt/CeO2-C as inner catalyst and Pt/C as outer catalyst is fabricated to extend the lifetime and minimize the performance loss of DMFC. Although the maximum power density of membrane electrode assembly (MEA with catalyst cathode is slightly lower than that of the traditional one, its durability is significantly improved. No obvious degradation is evident in the MEA with double-layered catalyst cathode within durability testing. These results indicated that Pt/CeO2-C as inner cathode catalyst layer greatly improved the stability of MEA. The significant reason for the improved stability of MEA is the ability of CeO2 to act as free-radical scavengers.

  13. The Effectiveness of Materials Different with Regard to Increasing the Durability

    Directory of Open Access Journals (Sweden)

    Erofeev Vladimir

    2016-01-01

    Full Text Available The article considers contemporary materials and structures for construction of buildings. The article conducts an economic study of the problem of durability. It addresses the issue of increasing longevity, affecting the term of service to building structures and the efficiency of their operation. Revealed the main factors affecting the durability. It identifies measures its realisation. The method of calculation of economic efficiency of improving the durability of building constructions.

  14. The Dynamic Pricing of Next Generation Consumer Durables

    OpenAIRE

    Barry L. Bayus

    1992-01-01

    Learning curve effects, aspects of consumer demand models (e.g., reservation price distributions, intertemporal utility maximizing behavior), and competitive activity are reasons which have been offered to explain why prices of new durables decline over time. This paper presents an alternative rationale based on the buying behavior for products with overlapping replacement cycles (i.e., next generation products). A model for consumer sales of a new durable is developed by incorporating the re...

  15. Roller Testing to Mimic Damage of the ISS SARJ Ring and Durability Test to Simulate Fifteen Years of SARJ Operation Using the Damaged Surface

    Science.gov (United States)

    Krantz, Timothy L.; Elchert, Justin P.; DellaCorte, Christopher; Dube, Michael J.

    2016-01-01

    The International Space Station's starboard Solar Alpha Rotary Joint (SARJ) experienced a breakdown of the joint's race ring surface. The starboard SARJ mechanism was cleaned and lubricated with grease. To provide some guidance on the expected behavior of the damaged SARJ ring with continued operations, experiments were conducted using rollers and a vacuum roller test rig. The approach of the experimental work involved three main steps: (1) initiate damage using conditions representative of the SARJ with inadequate lubrication; (2) propagate the damage by operating the test rollers without lubrication; and (3) assess the durability of the roller by testing to simulate the equivalent of 15 years of SARJ operation on the damaged surface assuming adequate grease lubrication. During the rig testing, additional and/or replacement grease was introduced at regular intervals to maintain good lubrication in the rig. The damage to the nitride layer continued even after application of grease. The grease lubrication proved to be effective for limiting the value of the axial force that can be developed. Limiting the axial force on the SARJ mechanism is important since the larger the axial force the more concentrated the load pressure becomes on the blend-radius location on the SARJ roller. After the testing simulating 15 years of SARJ operations, the wear depths were the order of 0.2 mm for the nitrided 15-5 roller and the order of 0.06 mm for the mating 440C roller. Metallographic inspections were done to search for indications of impending fatigue or other fracture indications that might eventually propagate and cause structural failure. There were no indications or features found that could eventually compromise structural integrity.

  16. Neural network analysis of nuclear waste glass composition vs durability

    International Nuclear Information System (INIS)

    Seibel, C.K.

    1994-01-01

    The relationship between the chemical composition of oxide glasses and their physical properties is poorly understood, but it is becoming more important as vitrification (transformation into glass) of high-level nuclear waste becomes the favored method for long-term storage. The vitrified waste will be stored deep in geologic repositories where it must remain intact for at least 10,000 years. A strong resistance to groundwater exposure; i.c. a slow rate of glass dissolution, is of great importance. This project deals specifically with glass samples developed and tested for the nuclear fuel reprocessing facility near West Valley, New York. This facility needs to dispose of approximately 2.2 million liters of high-level radioactive liquid waste currently stored in stainless steel tanks. A self-organizing, artificial neural network was used to analyze the trends in the glass dissolution data for the effects of composition and the resulting durability of borosilicate glasses in an aqueous environment. This durability data can be used to systematically optimize the properties of the complex nuclear glasses and slow the dissolution rate of radionuclides into the environment

  17. Recent results on the effect of gamma radiation on the durability and microstructure of DWPF glass

    International Nuclear Information System (INIS)

    Bibler, N.E.; Tosten, M.H.; Beam, D.C.

    1989-01-01

    The effect of gamma radiation on the durability and microstructure of a simulated nuclear waste glass from the Savannah River Site has been carefully investigated. Three large pieces of glass were irradiated with a Co-60 source to three doses up to a maximum dose of 3.1 x 10 10 rad. Internal samples of the large pieces of irradiated and unirradiated glass were leached in deionized water to investigate durability changes and were examined by transmission electron microscopy (TEM) to investigate microstructure changes. Leach tests were performed in triplicate at 90 degree C with crushed glass samples in deionized water. A statistical analysis of the results indicated to the 95% confidence level that the radiation did not affect the glass durability. Careful examination by TEM indicated no effect of gamma radiation on the microstructure of the glass although severe damage could be induced by the electron beam from the microscope. 19 refs., 2 figs., 3 tabs

  18. Teeth: Among Nature's Most Durable Biocomposites

    Science.gov (United States)

    Lawn, Brian R.; Lee, James J.-W.; Chai, Herzl

    2010-08-01

    This paper addresses the durability of natural teeth from a materials perspective. Teeth are depicted as smart biocomposites, highly resistant to cumulative deformation and fracture. Favorable morphological features of teeth at both macroscopic and microscopic levels contribute to an innate damage tolerance. Damage modes are activated readily within the brittle enamel coat but are contained from spreading catastrophically into the vulnerable tooth interior in sustained occlusal loading. Although tooth enamel contains a multitude of microstructural defects that can act as sources of fracture, substantial overloads are required to drive any developing cracks to ultimate failure—nature's strategy is to contain damage rather than avoid it. Tests on model glass-shell systems simulating the basic elements of the tooth enamel/dentin layer structure help to identify important damage modes. Fracture and deformation mechanics provide a basis for analyzing critical conditions for each mode, in terms of characteristic tooth dimensions and materials properties. Comparative tests on extracted human and animal teeth confirm the validity of the model test approach and point to new research directions. Implications in biomechanics, especially as they relate to dentistry and anthropology, are outlined.

  19. Probabilistic Durability Analysis in Advanced Engineering Design

    Directory of Open Access Journals (Sweden)

    A. Kudzys

    2000-01-01

    Full Text Available Expedience of probabilistic durability concepts and approaches in advanced engineering design of building materials, structural members and systems is considered. Target margin values of structural safety and serviceability indices are analyzed and their draft values are presented. Analytical methods of the cumulative coefficient of correlation and the limit transient action effect for calculation of reliability indices are given. Analysis can be used for probabilistic durability assessment of carrying and enclosure metal, reinforced concrete, wood, plastic, masonry both homogeneous and sandwich or composite structures and some kinds of equipments. Analysis models can be applied in other engineering fields.

  20. Durability reliability analysis for corroding concrete structures under uncertainty

    Science.gov (United States)

    Zhang, Hao

    2018-02-01

    This paper presents a durability reliability analysis of reinforced concrete structures subject to the action of marine chloride. The focus is to provide insight into the role of epistemic uncertainties on durability reliability. The corrosion model involves a number of variables whose probabilistic characteristics cannot be fully determined due to the limited availability of supporting data. All sources of uncertainty, both aleatory and epistemic, should be included in the reliability analysis. Two methods are available to formulate the epistemic uncertainty: the imprecise probability-based method and the purely probabilistic method in which the epistemic uncertainties are modeled as random variables. The paper illustrates how the epistemic uncertainties are modeled and propagated in the two methods, and shows how epistemic uncertainties govern the durability reliability.

  1. Nanocoating of ionic liquid and polypyrrole for durable electro-active paper actuators working under ambient conditions

    International Nuclear Information System (INIS)

    Mahadeva, Suresha K; Kim, Jaehwan

    2010-01-01

    This paper reports that nanocoating of polypyrrole (PPy) and ionic liquid (IL) on cellulose film improves the electromechanical performance and durability of a cellulose electro-active paper actuator. Cellulose-PPy-IL nanocomposites were fabricated by the polymerization-induced adsorption process of PPy followed by subsequent activation in IL solutions. X-ray photoelectron spectroscopy, transmission electron microscopy and secondary ion mass spectroscopy analyses validated the successful nanocoating of the PPy and IL layers on the cellulose. The results revealed that the cellulose-PPy-IL nanocomposites are suitable for durable bending actuators working under ambient conditions. Preparation, characterization and performance test of the nanocomposites are explained.

  2. Prediction of fracture toughness and durability of adhesively bonded composite joints with undesirable bonding conditions

    Science.gov (United States)

    Musaramthota, Vishal

    Advanced composite materials have enabled the conventional aircraft structures to reduce weight, improve fuel efficiency and offer superior mechanical properties. In the past, materials such as aluminum, steel or titanium have been used to manufacture aircraft structures for support of heavy loads. Within the last decade or so, demand for advanced composite materials have been emerging that offer significant advantages over the traditional metallic materials. Of particular interest in the recent years, there has been an upsurge in scientific significance in the usage of adhesively bonded composite joints (ABCJ's). ABCJ's negate the introduction of stress risers that are associated with riveting or other classical techniques. In today's aircraft transportation market, there is a push to increase structural efficiency by promoting adhesive bonding to primary joining of aircraft structures. This research is focused on the issues associated with the durability and related failures in bonded composite joints that continue to be a critical hindrance to the universal acceptance of ABCJ's. Of particular interest are the short term strength, contamination and long term durability of ABCJ's. One of the factors that influence bond performance is contamination and in this study the influence of contamination on composite-adhesive bond quality was investigated through the development of a repeatable and scalable surface contamination procedure. Results showed an increase in the contaminant coverage area decreases the overall bond strength significantly. A direct correlation between the contaminant coverage area and the fracture toughness of the bonded joint was established. Another factor that influences bond performance during an aircraft's service life is its long term strength upon exposure to harsh environmental conditions or when subjected to severe mechanical loading. A test procedure was successfully developed in order to evaluate durability of ABCJ's comprising severe

  3. Hanford enhanced waste glass characterization. Influence of composition on chemical durability

    International Nuclear Information System (INIS)

    Fox, K. M.; Edwards, T. B.

    2016-01-01

    This report provides a review of the complete high-level waste (HLW) and low-activity waste (LAW) data sets for the glasses recently fabricated at Pacific Northwest National Laboratory and characterized at Savannah River National Laboratory (SRNL). The review is from the perspective of relating the chemical durability performance to the compositions of these study glasses, since the characterization work at SRNL focused on chemical analysis and ASTM Product Consistency Test (PCT) performance.

  4. The candidate TB vaccine, MVA85A, induces highly durable Th1 responses.

    Directory of Open Access Journals (Sweden)

    Michele Tameris

    Full Text Available Vaccination against tuberculosis (TB should provide long-term protective immunity against Mycobacterium tuberculosis (M.tb. The current TB vaccine, Bacille Calmette-Guerin (BCG, protects against disseminated childhood TB, but protection against lung TB in adolescents and adults is variable and mostly poor. One potential reason for the limited durability of protection may be waning of immunity through gradual attrition of BCG-induced T cells. We determined if a MVA85A viral-vector boost could enhance the durability of mycobacteria-specific T cell responses above those induced by BCG alone.We describe a long-term follow-up study of persons previously vaccinated with MVA85A. We performed a medical history and clinical examination, a tuberculin skin test and measured vaccine-specific T cell responses in persons previously enrolled as adults, adolescents, children or infants into three different Phase II trials, between 2005 and 2011.Of 252 potential participants, 183 (72.6% consented and completed the study visit. Vaccine-induced Ag85A-specific CD4+ T cell responses were remarkably persistent in healthy, HIV-uninfected adults, adolescents, children and infants, up to 6 years after MVA85A vaccination. Specific CD4+ T cells expressed surface markers consistent with either CD45RA-CCR7+ central memory or CD45RA-CCR7- effector memory T cells. Similarly durable Ag85A-specific CD4+ T cell responses were detected in HIV-infected persons who were on successful antiretroviral therapy when MVA85A was administered. By contrast, Ag85A-specific CD4+ T cell frequencies in untreated MVA85A-vaccinated HIV-infected persons were mostly undetectable 3-5 years after vaccination.MVA85A induces remarkably durable T cell responses in immunocompetent persons. However, results from a recent phase IIb trial of MVA85A, conducted in infants from the same geographic area and study population, showed no vaccine efficacy, suggesting that these durable T cell responses do not

  5. Design and technology parameters influence on durability for heat exchangers tube to tubesheet joints

    Science.gov (United States)

    Ripeanu, R. G.

    2017-02-01

    The main failures of heat exchangers are: corrosion of tubes and jacket, tubes blockage and failures of tube to tubesheet joints also by corrosion. The most critical zone is tube to tubesheet joints. Depending on types of tube to tubesheet joints, in order to better respect conditions of tension and compression, this paper analyses the tubesheet holes shapes, smooth and with a grove, on corrosion behavior. In the case of welding tubes with tubesheet, welding parameters modify corrosion behavior. Were realized welded joints by three welding regimes and tested at corrosion in two media, tap water and industrial water. Were tested also samples made of smooth tubes, finned tubes and tubes coated with a passive product as applied by a heat exchanger manufacturer. For all samples, the roughness parameters were measured, before and after the corrosion tests. The obtained corrosion rates show that stress values and their distribution along the joint modify the corrosion behavior. The optimum welding parameters were established in order to increase the joint durability. The paper has shown that passive product used is not proper chosen and the technology of obtaining rolled thread pipes diminishes tubes’ durability by increasing the corrosion rate.

  6. Determinants of Long-Term Durable Glycemic Control in New-Onset Type 2 Diabetes Mellitus

    Directory of Open Access Journals (Sweden)

    Kyoung Jin Kim

    2017-08-01

    Full Text Available BackgroundLong-term durable glycemic control is a difficult goal in the management of type 2 diabetes mellitus (T2DM. We evaluated the factors associated with durable glycemic control in a real clinical setting.MethodsWe retrospectively reviewed the medical records of 194 new-onset, drug-naïve patients with T2DM who were diagnosed between January 2011 and March 2013, and were followed up for >2 years. Glycemic durability was defined as the maintenance of optimal glycemic control (glycosylated hemoglobin [HbA1c] <7.0% for 2 years without substitution or adding other glucose-lowering agents. Clinical factors and glycemic markers associated with glycemic durability were compared between two groups: a durability group and a non-durability group.ResultsPatients in the durability group had a higher baseline body mass index (26.1 kg/m2 vs. 24.9 kg/m2 and lower HbA1c (8.6% vs. 9.7% than the non-durability group. The initial choice of glucose-lowering agents was similar in both groups, except for insulin and sulfonylureas, which were more frequently prescribed in the non-durability group. In multiple logistic regression analyses, higher levels of education, physical activity, and homeostasis model assessment of β-cell function (HOMA-β were associated with glycemic durability. Notably, lower HbA1c (<7.0% at baseline and first follow-up were significantly associated with glycemic durability (adjusted odds ratio [OR], 7.48; 95% confidence interval [CI], 2.51 to 22.3 (adjusted OR, 9.27; 95% CI, 1.62 to 53.1, respectively, after adjusting for confounding variables including the types of glucose-lowering agents.ConclusionEarly achievement of HbA1c level within the glycemic target was a determinant of long-term glycemic durability in new-onset T2DM, as were higher levels of education, physical activity, and HOMA-β.

  7. Influence Of Density On The Durabilities Of Three Ghanaian Timbers ...

    African Journals Online (AJOL)

    Review of factors influencing wood durability shows although density varies depending on trunk position, its role appears controversial for many timber species. Thus, for the first time, the influence of density on the durability of three Ghanaian timbers (Nauclea diderrichii (de Wild.) Merr., Nesogordonia papaverifera (A. Chev ...

  8. A study on the effects of seawater on the durable life of concrete structures(I)

    Energy Technology Data Exchange (ETDEWEB)

    Oh, Byung Hwan; Chang, Bong Seok; Chang, Seung Yeob; Cheon, Se Jin; Cheong, Sang Hwa; Yu, Yeong; Shin, Yong Seok; Shin, Myeong Su; Hyeong, Sang Su [Seoul Nationl Univ., Seoul (Korea, Republic of)

    1998-06-15

    Recently, large scale concrete structures such as Nuclear Power Plants and offshore structures are actively being built in this country. These structures are subject to heavy attack due to seawater environment. A reasonable consideration for corrosion has not been paid to the structures in the past decades due to insufficient research data and guidelines. The durability os emerging as one of the most important factors in the design and construction of concrete structures. The purpose of the present study is, therefore, to explore the corrosion mechanism and penetration mechanism of chloride ion, and to establish the evaluation procedure of durability life of concrete structures. A comprehensive experimental program has been set up and severe the types and amount of cement and mineral admixtures. The test results on the corrosion and strength characteristics of various concrete with be reported in the second-year report since the corrosion tests need long time. The results can be used in the design and construction of concrete structures in the future.

  9. Durability, Performance, and Emission of Diesel Engines Using Carbon Fiber Piston and Liner

    Science.gov (United States)

    Afify, E. M.; Roberts, W. L.

    1999-01-01

    This report summarizes the research conducted by NC State University in investigating the durability, performance and emission of a carbon fiber piston and liner in our single cylinder research Diesel engine. Both the piston and liner were supplied to NC State University by NASA LaRC and manufactured by C-CAT under a separate contract to NASA LaRC. The carbon-carbon material used to manufacture the piston and liner has significantly lower thermal conductivity, coefficient of thermal expansion, and superior strength characteristics at elevated temperatures when compared to conventional piston materials such as aluminum. The results of the carbon-carbon fiber piston testing were compared to a baseline configuration, which used a conventional aluminum piston in a steel liner. The parameters measured were the brake specific fuel consumption, ignition delay, frictional horsepower, volumetric efficiency, and durability characteristics of the two pistons. Testing was performed using a naturally aspirated Labeco Direct Injection single cylinder diesel engine. Two test cases were performed over a range of loads and speeds. The fixed test condition between the aluminum and carbon-carbon piston configurations was the brake mean effective pressure. The measured data was the fuel consumption rate, volumetric efficiency, load, speed, cylinder pressure, needle lift, and exhaust gas temperature. The cylinder pressure, and fuel consumption, exhaust gas temperature, and needle lift were recorded using a National Instruments DAQ board and a PC. All test cases used Diesel no. 2 for fuel.

  10. Durability of heavyweight concrete containing barite

    International Nuclear Information System (INIS)

    Binici, Hanifi

    2010-01-01

    The supplementary waste barite aggregates deposit in Osmaniye, southern Turkey, has been estimated at around 500 000 000 tons based on 2007 records. The aim of the present study is to investigate the durability of concrete incorporating waste barite as coarse and river sand (RS), granule blast furnace slag (GBFS), granule basaltic pumice (GBP) and ≤ 4 mm granule barite (B) as fine aggregates. The properties of the fresh concrete determined included the air content, slump, slump loss and setting time. They also included the compressive strength, flexural and splitting tensile strengths and Young's modulus of elasticity, resistance to abrasion and sulphate resistance of hardened concrete. Besides these, control mortars were prepared with crushed limestone aggregates. The influence of waste barite as coarse aggregates and RS, GBFS, GBP and B as fine aggregates on the durability of the concretes was evaluated. The mass attenuation coefficients were calculated at photon energies of 1 keV to 100 GeV using XCOM and the obtained results were compared with the measurements at 0.66 and 1.25 MeV. The results showed the possibility of using these waste barite aggregates in the production of heavy concretes. In several cases, some of these properties have been improved. Durability of the concrete made with these waste aggregates was improved. Thus, these materials should be preferably used as aggregates in heavyweight concrete production. (orig.)

  11. Durable superhydrophobic paper enabled by surface sizing of starch-based composite films

    Science.gov (United States)

    Chen, Gang; Zhu, Penghui; Kuang, Yudi; Liu, Yu; Lin, Donghan; Peng, Congxing; Wen, Zhicheng; Fang, Zhiqiang

    2017-07-01

    Superhydrophobic paper with remarkable durability is of considerable interest for its practical applications. In this study, a scalable, inexpensive, and universal surface sizing technique was implemented to prepare superhydrophobic paper with enhanced durability. A thin layer of starch-based composite, acting as a bio-binder, was first coated onto the paper surface by a sophisticated manufacturing technique called surface sizing, immediately followed by a spray coating of hexamethyl disilazane treated silica nanoparticles (HMDS-SiNPs) dispersed in ethanol on the surface of the wet starch-coated sheet, and the dual layers dried at the same time. Consequently, durable superhydrophobic paper with bi-layer structure was obtained after air drying. The as-prepared superhydrophobic paper not only exhibited a self-cleaning behavior, but also presented an enhanced durability against scratching, bending/deformation, as well as moisture. The universal surface sizing of starch-based composites may pave the way for the up-scaled and cost-effective production of durable superhydrophobic paper.

  12. Highly durable, coking and sulfur tolerant, fuel-flexible protonic ceramic fuel cells.

    Science.gov (United States)

    Duan, Chuancheng; Kee, Robert J; Zhu, Huayang; Karakaya, Canan; Chen, Yachao; Ricote, Sandrine; Jarry, Angelique; Crumlin, Ethan J; Hook, David; Braun, Robert; Sullivan, Neal P; O'Hayre, Ryan

    2018-05-01

    Protonic ceramic fuel cells, like their higher-temperature solid-oxide fuel cell counterparts, can directly use both hydrogen and hydrocarbon fuels to produce electricity at potentially more than 50 per cent efficiency 1,2 . Most previous direct-hydrocarbon fuel cell research has focused on solid-oxide fuel cells based on oxygen-ion-conducting electrolytes, but carbon deposition (coking) and sulfur poisoning typically occur when such fuel cells are directly operated on hydrocarbon- and/or sulfur-containing fuels, resulting in severe performance degradation over time 3-6 . Despite studies suggesting good performance and anti-coking resistance in hydrocarbon-fuelled protonic ceramic fuel cells 2,7,8 , there have been no systematic studies of long-term durability. Here we present results from long-term testing of protonic ceramic fuel cells using a total of 11 different fuels (hydrogen, methane, domestic natural gas (with and without hydrogen sulfide), propane, n-butane, i-butane, iso-octane, methanol, ethanol and ammonia) at temperatures between 500 and 600 degrees Celsius. Several cells have been tested for over 6,000 hours, and we demonstrate excellent performance and exceptional durability (less than 1.5 per cent degradation per 1,000 hours in most cases) across all fuels without any modifications in the cell composition or architecture. Large fluctuations in temperature are tolerated, and coking is not observed even after thousands of hours of continuous operation. Finally, sulfur, a notorious poison for both low-temperature and high-temperature fuel cells, does not seem to affect the performance of protonic ceramic fuel cells when supplied at levels consistent with commercial fuels. The fuel flexibility and long-term durability demonstrated by the protonic ceramic fuel cell devices highlight the promise of this technology and its potential for commercial application.

  13. Effects of Irradiation on Albite's Chemical Durability.

    Science.gov (United States)

    Hsiao, Yi-Hsuan; La Plante, Erika Callagon; Krishnan, N M Anoop; Le Pape, Yann; Neithalath, Narayanan; Bauchy, Mathieu; Sant, Gaurav

    2017-10-19

    Albite (NaAlSi 3 O 8 ), a framework silicate of the plagioclase feldspar family and a common constituent of felsic rocks, is often present in the siliceous mineral aggregates that compose concrete. When exposed to radiation (e.g., in the form of neutrons) in nuclear power plants, the crystal structure of albite can undergo significant alterations. These alterations may degrade its chemical durability. Indeed, careful examinations of Ar + -implanted albite carried out using Fourier transform infrared spectroscopy (FTIR) and molecular dynamics simulations show that albite's crystal structure, upon irradiation, undergoes progressive disordering, resulting in an expansion in its molar volume (i.e., a reduction of density) and a reduction in the connectivity of its atomic network. This loss of network connectivity (i.e., rigidity) results in an enhancement of the aqueous dissolution rate of albite-measured using vertical scanning interferometry (VSI) in alkaline environments-by a factor of 20. This enhancement in the dissolution rate (i.e., reduction in chemical durability) of albite following irradiation has significant impacts on the durability of felsic rocks and of concrete containing them upon their exposure to radiation in nuclear power plant (NPP) environments.

  14. Optimal Monetary Policy with Durable Consumption Goods and Factor Demand Linkages

    DEFF Research Database (Denmark)

    Petrella, Ivan; Santoro, Emiliano

    of production in both sectors, according to an input-output matrix calibrated on the US economy. As shown in a number of recent contributions, this roundabout technology allows us to reconcile standard two-sector New Keynesian models with the empirical evidence showing co-movement between durable and non......-durable spending in response to a monetary policy shock. A main result of our monetary policy analysis is that strategic complementarities generated by factor demand linkages amplify social welfare loss. As the degree of interconnection between sectors increases, the cost of misperceiving the correct production......This paper deals with the implications of factor demand linkages for monetary policy design. We develop a dynamic general equilibrium model with two sectors that produce durable and non-durable goods, respectively. Part of the output produced in each sector is used as an intermediate input...

  15. Durability of Compressed Earth Bricks: Assessing Erosion Resistance Using the Modified Spray Testing

    Directory of Open Access Journals (Sweden)

    Malarvizhi Baskaran

    2010-11-01

    Full Text Available The discussion in this paper is part of research directed at establishing optimal stabilization strategy for compressed bricks. The deployment context for the use of the compressed bricks was Dar es Salaam (Tanzania where manually fabricated bricks are increasingly being used in low cost housing units. This discussion specifically focuses on strategies that can be used to counter deterioration due to wind-driven rain erosion. The impact of using cement, lime, fiber and a commercial stabilizing fluid was assessed. Factory-produced bricks were used for benchmarking. The durability of the bricks was assessed using the “modified” Bulletin 5 Spray Test. The different brick specimens were sprayed with water at 2.07 MPa and 4.14 MPa over one-hour time period while measuring the depth of erosion every 15 minutes. Factory-produced bricks hardly eroded at both 2.07 MPa and 4.14 MPa pressure levels. The maximum depth of erosion for Soil-Cement bricks ranged from a maximum of 0.5 mm at 2.07 MPa water pressure to 0.8 mm at 4.14 MPa. The maximum and minimum depths of erosion for Soil-Cement-Lime bricks were 25mm and 17 mm respectively. The inclusion of natural fiber in the bricks resulted in a sharp increase of the erosion depth to a maximum of 40 mm at 2.07 MPa and 55 mm at 4.14 Mpa. As the use of natural fibers and lime enhances some physio-mechanical properties, further research is necessary to determine ways of achieving this goal while maintaining acceptable levels of erosion resistance.

  16. Evolutionary model of an anonymous consumer durable market

    Science.gov (United States)

    Kaldasch, Joachim

    2011-07-01

    An analytic model is presented that considers the evolution of a market of durable goods. The model suggests that after introduction goods spread always according to a Bass diffusion. However, this phase will be followed by a diffusion process for durable consumer goods governed by a variation-selection-reproduction mechanism and the growth dynamics can be described by a replicator equation. The theory suggests that products play the role of species in biological evolutionary models. It implies that the evolution of man-made products can be arranged into an evolutionary tree. The model suggests that each product can be characterized by its product fitness. The fitness space contains elements of both sites of the market, supply and demand. The unit sales of products with a higher product fitness compared to the mean fitness increase. Durables with a constant fitness advantage replace other goods according to a logistic law. The model predicts in particular that the mean price exhibits an exponential decrease over a long time period for durable goods. The evolutionary diffusion process is directly related to this price decline and is governed by Gompertz equation. Therefore it is denoted as Gompertz diffusion. Describing the aggregate sales as the sum of first, multiple and replacement purchase the product life cycle can be derived. Replacement purchase causes periodic variations of the sales determined by the finite lifetime of the good (Juglar cycles). The model suggests that both, Bass- and Gompertz diffusion may contribute to the product life cycle of a consumer durable. The theory contains the standard equilibrium view of a market as a special case. It depends on the time scale, whether an equilibrium or evolutionary description is more appropriate. The evolutionary framework is used to derive also the size, growth rate and price distribution of manufacturing business units. It predicts that the size distribution of the business units (products) is lognormal

  17. Electrostimulated recovery of welded joint durability: experiment and model

    International Nuclear Information System (INIS)

    Semakin, E.V.; Chirakadze, D.Z.; Tsellermaer, V.Ya.; Gromov, V.E.; Sosnin, O.V.

    1997-01-01

    The possibility to increase the durability of welded joints operating under conditions of low cycle fatigue is shown to be brought about using electric current pulses. Experimental method of recovery of operational capability is demonstrated on welded joints of tool steels R6M5 and 40Kh/ The onset of critical stage of fatigue in the welded joint was determined by ultrasonic testing. Then the specimens were treated with 20 Hz electric pulses with amplitude of 250 MA/M 2 for 100 μs. Such treatment resulted in an increase of time to fracture. The phenomenological model of the process is proposed

  18. Measuring Happiness: From Fluctuating Happiness to Authentic–Durable Happiness

    Science.gov (United States)

    Dambrun, Michaël; Ricard, Matthieu; Després, Gérard; Drelon, Emilie; Gibelin, Eva; Gibelin, Marion; Loubeyre, Mélanie; Py, Delphine; Delpy, Aurore; Garibbo, Céline; Bray, Elise; Lac, Gérard; Michaux, Odile

    2012-01-01

    On the basis of the theoretical distinction between self-centeredness and selflessness (Dambrun and Ricard, 2011), the main goal of this research was to develop two new scales assessing distinct dimensions of happiness. By trying to maximize pleasures and to avoid displeasures, we propose that a self-centered functioning induces a fluctuating happiness in which phases of pleasure and displeasure alternate repeatedly (i.e., Fluctuating Happiness). In contrast, a selfless psychological functioning postulates the existence of a state of durable plenitude that is less dependent upon circumstances but rather is related to a person’s inner resources and abilities to deal with whatever comes his way in life (i.e., Authentic–Durable Happiness). Using various samples (n = 735), we developed a 10-item Scale measuring Subjective Fluctuating Happiness (SFHS) and a 13-item scale assessing Subjective Authentic–Durable Happiness (SA–DHS). Results indicated high internal consistencies, satisfactory test–retest validities, and adequate convergent and discriminant validities with various constructs including a biological marker of stress (salivary cortisol). Consistent with our theoretical framework, while self-enhancement values were related only to fluctuating happiness, self-transcendence values were related only to authentic–durable happiness. Support for the distinction between contentment and inner-peace, two related markers of authentic happiness, also was found. PMID:22347202

  19. Ancient analogues concerning stability and durability of cementitious wasteform

    International Nuclear Information System (INIS)

    Jiang, W.; Roy, D.M.

    1994-01-01

    The history of cementitious materials goes back to ancient times. The Greeks and Romans used calcined limestone and later developed pozzolanic cement by grinding together lime and volcanic ash called open-quotes pozzolanclose quotes which was first found near Port Pozzuoli, Italy. The ancient Chinese used lime-pozzolanic mixes to build the Great Wall. The ancient Egyptians used calcined impure gypsum to build the Great Pyramid of Cheops. The extraordinary stability and durability of these materials has impressed us, when so much dramatically damaged infrastructure restored by using modern portland cement now requires rebuilding. Stability and durability of cementitious materials have attracted intensive research interest and contractors' concerns, as does immobilization of radioactive and hazardous industrial waste in cementitious materials. Nuclear waste pollution of the environment and an acceptable solution for waste management and disposal constitute among the most important public concerns. The analogy of ancient cementitious materials to modern Portland cement could give us some clues to study their stability and durability. This present study examines selected results of studies of ancient building materials from France, Italy, China, and Egypt, combined with knowledge obtained from the behavior of modern portland cement to evaluate the potential for stability and durability of such materials in nuclear waste forms

  20. SEM investigation of incandescent lamp mantle structure on durability

    International Nuclear Information System (INIS)

    Gerneke, D.; Lang, C.

    2002-01-01

    Full text: The incandescent mantle as used on pressure and non-pressure liquid fuel lamps has been in use for over 100 years. What remains unexplained is the way in which the resistance to mechanical shock and the decline in tensile strength with usage is experienced. It has been suggested that to improve durability it is necessary to continuously burn a new mantle for the first two to three hours. The known factors in mantle durability and mechanical strength are chemical composition and fabric weave. This study was undertaken to investigate the effects of burning time and temperature on thorium oxide mantles. The operating temperature of mantles on a range of kerosene pressure lamps was measured and found to be between 800 and 1100 deg C. Heat treatments of thorium based Coleman mantles were carried out in a laboratory furnace within these ranges of temperatures for periods ranging from 2 minutes to 2 hours. The mantles were then viewed in a LEO S440 analytical SEM. Results at 800 deg C show a distinct change in surface morphology with increasing exposure time. At the shorter times (2-5 minutes) the surface was relatively smooth. With increased time periods (15 - 120 minutes) the surface was observed to have a large lumpy structure. At 1100 deg C the difference in surface morphology was not apparent between the shortest and longest times. The surface appears much smoother and no lumpy structure was observed. This suggests that when a mantle is operated at the higher temperature of 1100 deg C the structure of the Thorium oxide is quickly transformed into the known stronger amorphous form. This is taken as the observed smooth structure seen in the SEM images of the 1100 deg C samples. Thus the mantle is expected to be more resistant to mechanical shock and have increased durability. Practical field test results confirm these observations. The mantle on a lamp that is operating efficiently, burns brightly, will far outlast a mantle on an inefficient lamp which bums

  1. State of the art of durability-performance evaluation of hardened cement based on phase compositions

    International Nuclear Information System (INIS)

    Kurashige, Isao; Imoto, Harutake; Yamamoto, Takeshi; Hironaga, Michihiko

    2006-01-01

    Upgrading durability-performance evaluation technique for concrete is urgently demanded in connection to its application to radio-active waste repository which needs ultra long-term durability. Common concrete structures also require an advanced method for minimizing the life-cycle cost. The purpose of this research is to investigate current problems and future tasks on durability-performance evaluation of hardened cement from the view point of phase composition. Although the phase composition of hardened cement has not fully been reflected to durability-performance evaluation, it influences concrete durability as well as its pore structure. This report reviews state of the art of the factors affecting phase composition, analytical and experimental evaluation techniques for phase composition, and durability-performance evaluation methods of hardened cement based on phase composition. (author)

  2. [The durability of three self-etch adhesives bonded to dentin].

    Science.gov (United States)

    Tian, Fu-Cong; Wang, Xiao-Yan; Gao, Xue-Jun

    2013-04-01

    To investigate the durability of self-etch adhesives bonded to dentin in vitro. Forty-two extracted human molars were selected and occlusal dentin surfaces were exposed. The teeth were randomly distributed into three groups based on adhesives applied. The one-step self-etch adhesive B(Adper Prompt) and C(G-Bond) and two-step self-etch adhesive A (Clearfil SE bond) were used. After application of the adhesives to the dentin surfaces, composite crowns were built up, after 24 h water storage, the teeth were sectioned longitudinally into sticks (1.0 mm×1.0 mm bonding area) for microtensile testing or slabs (1 mm thick) for scanning electron microscopec (SEM) observation. Bonding strength (mTBS) and nano-leakage were evaluated immediately after cutting or after 6 months in water. The mTBS was analyzed using one-way ANOVA (SPSS 13.0). The nanoleakage was observed by SEM with a backscattered electron detector. Both adhesives and water storage time affected the mTBS. All adhesives showed decreased bond strength after six-month water aging [A dropped from (40.60 ± 5.76) MPa to (36.04 ± 3.15) MPa; B dropped from (19.06 ± 1.50) MPa to (11.19 ± 1.97) MPa; C dropped from (17.75 ± 1.10) MPa to (9.14 ± 1.15) MPa] (P adhesives tested were probably influenced by water aging, however, the two-step adhesive showed better durability than the one-step adhesives.

  3. Experimental research on durability of recycled aggregate concrete under freeze- thaw cycles

    Science.gov (United States)

    Cheng, Yanqiu; Shang, Xiaoyu; Zhang, Youjia

    2017-07-01

    The freeze-thaw durability of recycled aggregate concrete has significance for the concrete buildings in the cold region. In this paper, the rapid freezing and thawing cycles experience on recycle aggregate concrete was conducted to study on the effects of recycle aggregate amount, water-binder ratio and fly ash on freeze-thaw durability of recycle aggregate concrete. The results indicates that recycle aggregate amount makes the significant influence on the freeze-thaw durability. With the increase of recycled aggregates amount, the freeze-thaw resistance for recycled aggregate concrete decreases. Recycled aggregate concrete with lower water cement ratio demonstrates better performance of freeze-thaw durability. It is advised that the amount of fly ash is less than 30% for admixture of recycled aggregates in the cold region.

  4. Evaluation of permanent deformation and durability of epoxidized natural rubber modified asphalt mix

    Science.gov (United States)

    Al-Mansob, Ramez A.; Ismail, Amiruddin; Rahmat, Riza Atiq O. K.; Nazri Borhan, Muhamad; Alsharef, Jamal M. A.; Albrka, Shaban Ismael; Rehan Karim, Mohamed

    2017-09-01

    The road distresses have caused too much in maintenance cost. However, better understandings of the behaviours and properties of asphalt, couples with greater development in technology, have allowed paving technologists to examine the benefits of introducing additives and modifiers. As a result, modifiers such as polymers are the most popular modifiers used to improve the performance of asphalt mix. This study was conducted to investigate the use of epoxidized natural rubber (ENR) to be mixed with asphalt mix. Tests were conducted to investigate the performance characteristics of ENR-asphalt mixes, where the mixes were prepared according to the wet process. Mechanical testing on the ENR-asphalt mixes have demonstrated that the asphalt mix permanent deformation performance at high temperature was found to be improved compared to the base mixes. However, the durability studies have indicated that ENR-asphalt mixes are slightly susceptible with the presence of moisture. The durability of the ENR-asphalt mixes were found to be enhanced in term of permanent deformation at high and intermediate temperatures compared to the base asphalt mixes. As conclusion, asphalt pavement performance can be enhanced by using ENR as modifier to face the major road distresses.

  5. Performance-based specifications and control of concrete durability state-of-the-art report RILEM TC 230-PSC

    CERN Document Server

    Luco, Luis

    2016-01-01

    This work gives an overview of significant research from recent years concerning performance-based design and quality control for concrete durability and its implementation. In engineering practice, performance approaches are often still used in combination with prescriptive requirements. This is largely because, for most durability test methods, sufficient practical experience still has to be gained before engineers and owners are prepared to fully rely on them.   This book, compiled by RILEM TC 230-PSC, is intended to assist efforts to successfully build the foundation for the full implementation of performance-based approaches through the exchange of relevant knowledge and experience between researchers and practitioners worldwide.  .

  6. Thermomechanical and Environmental Durability of Environmental Barrier Coated Ceramic Matrix Composites Under Thermal Gradients

    Science.gov (United States)

    Zhu, Dongming; Bhatt, Ramakrishna T.; Harder, Bryan

    2016-01-01

    This paper presents the developments of thermo-mechanical testing approaches and durability performance of environmental barrier coatings (EBCs) and EBC coated SiCSiC ceramic matrix composites (CMCs). Critical testing aspects of the CMCs will be described, including state of the art instrumentations such as temperature, thermal gradient, and full field strain measurements; materials thermal conductivity evolutions and thermal stress resistance; NDE methods; thermo-mechanical stress and environment interactions associated damage accumulations. Examples are also given for testing ceramic matrix composite sub-elements and small airfoils to help better understand the critical and complex CMC and EBC properties in engine relevant testing environments.

  7. Performance based durability design of a bored tunnel with concrete lining

    NARCIS (Netherlands)

    Vries, H. de; Siemes, A.J.M.

    2002-01-01

    Design for durability is gradually changing from a deem-to-satisfy approach to a performance based approach. The conventional building codes give in principle only construction rules. If these rules are fulfilled, it is assumed that the structure will have an adequate durability. But specifications

  8. Durability of cracked fibre reinforced concrete exposed to freeze-thaw and deicing salt

    DEFF Research Database (Denmark)

    Hansen, Ernst Jan De Place

    1998-01-01

    Durability studies are carried out by subjecting FRC-beams to combined mechanical and environmental load. Mechanical load is obtained by subjecting beams to 4-point bending until a predefined crack width is reached. Specimens sawn from the beams after unloading are exposed to freeze-thaw and deic......Durability studies are carried out by subjecting FRC-beams to combined mechanical and environmental load. Mechanical load is obtained by subjecting beams to 4-point bending until a predefined crack width is reached. Specimens sawn from the beams after unloading are exposed to freeze-thaw...... and deicing salt. The concrete has a water-powder ratio of 0.38 including both fly ash and silica fume. Both steel fibres (ZP, 0.4 vol%) and polypropylene fibres (PP, 1 vol%) are used as well as main reinforcement. The freeze-thaw test emphasizes the need for a critical evaluation of the mix design and mixing...

  9. Overview of ORNL/NRC programs addressing durability of concrete structures

    International Nuclear Information System (INIS)

    Naus, D.J.; Oland, C.B.

    1994-01-01

    The role of reinforced concrete relative to its applications as either safety-related structures in nuclear power or engineered barriers of low-level radioactive waste disposal facilities is described. Factors that can affect the long-term durability of reinforced concrete are identified. Overviews are presented of the Structural Aging Program, which is addressing the aging management of safety-related concrete structures in nuclear power plants, and the Permeability Test Methods and Data Program, which is identifying pertinent data and information for use in performance assessments of engineered barriers for low-level radioactive waste disposal

  10. Decoration and Durability

    DEFF Research Database (Denmark)

    Riisberg, Vibeke; Munch, Anders V.

    2015-01-01

    Throughout the scales of design there has been an exploding interest in the ornament that seems to be fuelled by different kinds of digital technology and media from CAD to digital printing in both 2D and 3D. In architecture and industrial design it is discussed as a Return of ornament, because...... appropriate or not. This leads us to suggest an array of parameters that points out different situations and meanings of ornamentation: Product categories, Durability of materials, Styles, Aesthetic experience, Emotional attachment and Historical references. We discuss these parameters in cases from fashion...

  11. PtRu nanoparticles embedded in nitrogen doped carbon with highly stable CO tolerance and durability

    Science.gov (United States)

    Ling, Ying; Yang, Zehui; Yang, Jun; Zhang, Yunfeng; Zhang, Quan; Yu, Xinxin; Cai, Weiwei

    2018-02-01

    As is well known, the lower durability and sluggish methanol oxidation reaction (MOR) of PtRu alloy electrocatalyst blocks the commercialization of direct methanol fuel cells (DMFCs). Here, we design a new PtRu electrocatalyst, with highly stable CO tolerance and durability, in which the PtRu nanoparticles are embedded in nitrogen doped carbon layers derived from carbonization of poly(vinyl pyrrolidone). The newly fabricated electrocatalyst exhibits no loss in electrochemical surface area (ECSA) and MOR activity after potential cycling from 0.6-1.0 V versus reversible hydrogen electrode, while commercial CB/PtRu retains only 50% of its initial ECSA. Meanwhile, due to the same protective layers, the Ru dissolution is decelerated, resulting in stable CO tolerance. Methanol oxidation reaction (MOR) testing indicates that the activity of newly fabricated electrocatalyst is two times higher than that of commercial CB/PtRu, and the fuel cell performance of the embedded PtRu electrocatalyst was comparable to that of commercial CB/PtRu. The embedded PtRu electrocatalyst is applicable in real DMFC operation. This study offers important and useful information for the design and fabrication of durable and CO tolerant electrocatalysts.

  12. Degradation mechanisms and accelerated testing in PEM fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Borup, Rodney L [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory

    2010-01-01

    The durability of PEM fuel cells is a major barrier to the commercialization of these systems for stationary and transportation power applications. Although there has been recent progress in improving durability, further improvements are needed to meet the commercialization targets. Past improvements have largely been made possible because of the fundamental understanding of the underlying degradation mechanisms. By investigating component and cell degradation modes; defining the fundamental degradation mechanisms of components and component interactions new materials can be designed to improve durability. Various factors have been shown to affect the useful life of PEM fuel cells. Other issues arise from component optimization. Operational conditions (such as impurities in either the fuel and oxidant stream), cell environment, temperature (including subfreezing exposure), pressure, current, voltage, etc.; or transient versus continuous operation, including start-up and shutdown procedures, represent other factors that can affect cell performance and durability. The need for Accelerated Stress Tests (ASTs) can be quickly understood given the target lives for fuel cell systems: 5000 hours ({approx} 7 months) for automotive, and 40,000 hrs ({approx} 4.6 years) for stationary systems. Thus testing methods that enable more rapid screening of individual components to determine their durability characteristics, such as off-line environmental testing, are needed for evaluating new component durability in a reasonable turn-around time. This allows proposed improvements in a component to be evaluated rapidly and independently, subsequently allowing rapid advancement in PEM fuel cell durability. These tests are also crucial to developers in order to make sure that they do not sacrifice durability while making improvements in costs (e.g. lower platinum group metal [PGM] loading) and performance (e.g. thinner membrane or a GDL with better water management properties). To

  13. Durability and CMAS Resistance of Advanced Environmental Barrier Coatings Systems for SiC/SiC Ceramic Matrix Composites

    Science.gov (United States)

    Zhu, Dongming

    2015-01-01

    Environmental barrier coatings (EBCs) and SiCSiC ceramic matrix composites (CMCs) systems will play a crucial role in next generation turbine engines for hot-section component applications because of their ability to significantly increase engine operating temperatures with improved efficiency, reduce engine weight and cooling requirements. This paper will emphasize advanced environmental barrier coating developments for SiCSiC turbine airfoil components, by using advanced coating compositions and processing, in conjunction with mechanical and environment testing and durability validations. The coating-CMC degradations and durability in the laboratory simulated engine fatigue-creep and complex operating environments are being addressed. The effects of Calcium-Magnesium-Alumino-Silicate (CMAS) from road sand or volcano-ash deposits on the degradation mechanisms of the environmental barrier coating systems will be discussed. The results help understand the advanced EBC-CMC system performance, aiming at the durability improvements of more robust, prime-reliant environmental barrier coatings for successful applications of the component technologies and lifing methodologies.

  14. Durability of Self Compacting Concrete

    International Nuclear Information System (INIS)

    Benmarce, A.; Boudjehem, H.; Bendjhaiche, R.

    2011-01-01

    Self compacting concrete (SCC) seem to be a very promising materials for construction thanks to their properties in a fresh state. Studying of the influence of the parameters of specific designed mixes to their mechanical, physical and chemical characteristics in a state hardened is an important stage so that it can be useful for new-to-the-field researchers and designers (worldwide) beginning studies and work involving self compacting concrete. The objective of this research is to study the durability of self compacting concrete. The durability of concrete depends very much on the porosity; the latter determines the intensity of interactions with aggressive agents. The pores inside of concrete facilitate the process of damage, which began generally on the surface. We are interested to measure the porosity of concrete on five SCC with different compositions (w/c, additives) and vibrated concrete to highlight the influence of the latter on the porosity, thereafter on the compressive strength and the transfer properties (oxygen permeability, chloride ion diffusion, capillary absorption). (author)

  15. The effects of crystallization and residual glass on the chemical durability of iron phosphate waste forms containing 40 wt% of a high MoO3 Collins-CLT waste

    Science.gov (United States)

    Hsu, Jen-Hsien; Bai, Jincheng; Kim, Cheol-Woon; Brow, Richard K.; Szabo, Joe; Zervos, Adam

    2018-03-01

    The effects of cooling rate on the chemical durability of iron phosphate waste forms containing up to 40 wt% of a high MoO3 Collins-CLT waste simulant were determined at 90 °C using the product consistency test (PCT). The waste form, designated 40wt%-5, meets appropriate Department of Energy (DOE) standards when rapidly quenched from the melt (as-cast) and after slow cooling following the CCC (canister centerline cooling)-protocol, although the quenched glass is more durable. The analysis of samples from the vapor hydration test (VHT) and the aqueous corrosion test (differential recession test) reveals that rare earth orthophosphate (monazite) and Zr-pyrophosphate crystals that form on cooling are more durable than the residual glass in the 40wt%-5 waste form. The residual glass in the CCC-treated samples has a greater average phosphate chain length and a lower Fe/P ratio, and those contribute to its faster corrosion kinetics.

  16. Gram-Scale Synthesis of Highly Active and Durable Octahedral PtNi Nanoparticle Catalysts for Proton Exchange Membrane Fuel Cell

    DEFF Research Database (Denmark)

    Choi, Juhyuk; Jang, Jue-Hyuk; Roh, Chi-Woo

    2018-01-01

    for the commercialization of PEMFCs. In this study, we focus on gram-scale synthesis of octahedral PtNi nanoparticles with Pt overlayers (PtNi@Pt) supported on the carbon, resulting in enhanced catalytic activity and durability. Such PtNi@Pt catalysts show high mass activity (1.24 A mgPt−1) at 0.9 V (vs RHE) for the ORR......Proton exchange membrane fuel cells (PEMFC) are regarded as a promising renewable energy source for a future hydrogen energy society. However, highly active and durable catalysts are required for the PEMFCs because of their intrinsic high overpotential at the cathode and operation under the acidic...... condition for oxygen reduction reaction (ORR). Since the discovery of the exceptionally high surface activity of Pt3Ni(111), the octahedral PtNi nanoparticles have been synthesized and tested. Nonetheless, their milligram-scale synthesis method and poor durability make them unsuitable...

  17. FAA/NASA International Symposium on Advanced Structural Integrity Methods for Airframe Durability and Damage Tolerance

    Energy Technology Data Exchange (ETDEWEB)

    Harris, C.E.

    1994-09-01

    International technical experts in durability and damage tolerance of metallic airframe structures were assembled to present and discuss recent research findings and the development of advanced design and analysis methods, structural concepts, and advanced materials. The symposium focused on the dissemination of new knowledge and the peer-review of progress on the development of advanced methodologies. Papers were presented on: structural concepts for enhanced durability, damage tolerance, and maintainability; new metallic alloys and processing technology; fatigue crack initiation and small crack effects; fatigue crack growth models; fracture mechanics failure, criteria for ductile materials; structural mechanics methodology for residual strength and life prediction; development of flight load spectra for design and testing; and advanced approaches to resist corrosion and environmentally assisted fatigue. Separate abstracts have been indexed for articles from this report.

  18. Final Report - MEA and Stack Durability for PEM Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Yandrasits, Michael A.

    2008-02-15

    Proton exchange membrane fuel cells are expected to change the landscape of power generation over the next ten years. For this to be realized one of the most significant challenges to be met for stationary systems is lifetime, where 40,000 hours of operation with less than 10% decay is desired. This project conducted fundamental studies on the durability of membrane electrode assemblies (MEAs) and fuel cell stack systems with the expectation that knowledge gained from this project will be applied toward the design and manufacture of MEAs and stack systems to meet DOE’s 2010 stationary fuel cell stack systems targets. The focus of this project was PEM fuel cell durability – understanding the issues that limit MEA and fuel cell system lifetime, developing mitigation strategies to address the lifetime issues and demonstration of the effectiveness of the mitigation strategies by system testing. To that end, several discoveries were made that contributed to the fundamental understanding of MEA degradation mechanisms. (1) The classically held belief that membrane degradation is solely due to end-group “unzipping” is incorrect; there are other functional groups present in the ionomer that are susceptible to chemical attack. (2) The rate of membrane degradation can be greatly slowed or possibly eliminated through the use of additives that scavenge peroxide or peroxyl radicals. (3) Characterization of GDL using dry gases is incorrect due to the fact that fuel cells operate utilizing humidified gases. The proper characterization method involves using wet gas streams and measuring capillary pressure as demonstrated in this project. (4) Not all Platinum on carbon catalysts are created equally – the major factor impacting catalyst durability is the type of carbon used as the support. (5) System operating conditions have a significant impact of lifetime – the lifetime was increased by an order of magnitude by changing the load profile while all other variables remain

  19. Moisture Durability with Vapor-Permeable Insulating Sheathing

    Energy Technology Data Exchange (ETDEWEB)

    Lepage, R. [Building Science Corporation, Somerville, MA (United States); Lstiburek, J. [Building Science Corporation, Somerville, MA (United States)

    2013-09-01

    Exterior sheathing insulation is an effective strategy in increasing the overall R-value of wall assemblies; other benefits include decreasing the effects of thermal bridging and increasing the moisture durability of the built assembly. Vapor-permeable exterior insulation, such as mineral board or expanded polystyrene foam, are one such product that may be used to achieve these benefits. However, uncertainty exists on the effects of inward driven moisture and the interaction of increased sheathing temperatures on the moisture durability of the edifice. To address these concerns, Building Science Corporation (BSC) conducted a series of hygrothermal models for cities representing a range of different climate zones. This report describes the research project, key research questions, and the procedures utilized to analyse the problems.

  20. Moisture Durability with Vapor-Permeable Insulating Sheathing

    Energy Technology Data Exchange (ETDEWEB)

    Lepage, R. [Building Science Corporation, Somerville, MA (United States); Lstiburek, J. [Building Science Corporation, Somerville, MA (United States)

    2013-09-01

    Exterior sheathing insulation is an effective strategy in increasing the overall R-value of wall assemblies; other benefits include decreasing the effects of thermal bridging and increasing the moisture durability of the built assembly. Vapor-permeable exterior insulation, such as mineral board or expanded polystyrene foam, are one such product that may be used to achieve these benefits. However,uncertainty exists on the effects of inward driven moisture and the interaction of increased sheathing temperatures on the moisture durability of the edifice. To address these concerns, Building Science Corporation (BSC) conducted a series of hygrothermal models for cities representing a range of different climate zones. This report describes the research project, key research questions, and theprocedures utilized to analyse the problems.

  1. The chemical durability of alkali aluminosilicate glasses

    International Nuclear Information System (INIS)

    Tait, J.C.; Mandolesi, D.L.

    1983-09-01

    The aqueous durabilities of a series of glasses based on the sodium aluminosilicate system (Na 2 O-Al 2 O 3 -SiO 2 ) have been studied. The effects of molecular substitution of K 2 O or CaO for Na 2 O, and B 2 O 3 for Al 2 O 3 have been investigated. The temperature dependence of leaching in the Na 2 O-B 2 O 3 -Al 2 O 3 -SiO 2 system was studied with glasses containing 2 wt percent simulated UO 2 fuel recycle waste. The results confirm that aluminosilicate glasses are more durable than their borosilicate counterparts. The leaching results are explained in terms of glass structure and bonding, and a general leaching mechanism for aluminosilicate glasses is presented

  2. Review of durability of cementitious engineered barriers in repository environments

    International Nuclear Information System (INIS)

    Parrott, L.J.; Lawrence, C.D.

    1992-01-01

    This report is concerned with the durability of cementitious engineered barriers in a repository for low and intermediate level nuclear waste. Following the introduction the second section of the review identifies the environmental conditions associated with a deep, hard rock repository for ILW and LLW that are relevant to the durability of cementitious barriers. Section three examines the microstructure and macrostructure of cementitious materials and considers the physical and chemical processes of radionuclide immobilization. Potential repository applications and compositions of cementitious materials are reviewed in Section four. The main analysis of durability is dealt with in Section five. The different types of cementitious barrier are considered separately and their most probable modes of degradation are analysed. Concluding remarks that highlight critical technical matters are given in Section six. (author)

  3. Manufacturing of Low Cost, Durable Membrane Electrode Assemblies Engineered for Rapid Conditioning

    Energy Technology Data Exchange (ETDEWEB)

    Busby, Colin [W. L. Gore & Associates Inc., Newark, DE (United States)

    2017-05-23

    Over the past 20 years significant progress in membrane-electrode assembly (MEA) technology development for polymer electrolyte fuel cells (PEMFCs) has resulted in the PEMFC technology approaching a commercial reality for transportation applications. However, there remain two primary technical challenges to be addressed in the MEA. First and foremost is meeting the automotive cost targets: Producing a fuel cell stack cost competitive with today’s internal combustion engine. In addition to the material cost, MEA (and other components) and stack assembly production methods must be amenable for use in low cost, high speed, automotive assembly line. One impediment to this latter goal is that stack components must currently go through a long and tedious conditioning procedure before they produce optimal power. This so-called “break-in” can take many hours, and can involve quite complex voltage, temperature and/or pressure steps. These break-in procedures must be simplified and the time required reduced if fuel cells are to become a viable automotive engine. The second challenge is to achieve the durability targets in real-world automotive duty cycle operations. Significant improvements in cost, break-in time, and durability for the key component of fuel cell stacks, MEAs were achieved in this project. Advanced modeling was used to guide design of the new MEA to maximize performance and durability. A new, innovative process and manufacturing approach utilizing direct in-line coating using scalable, cost-competitive, continuous high volume 3-layer rolled-good manufacturing processes was developed and validated by single cell and short stack testing. In addition, the direct coating methods employed were shown to reduce the cost for sacrificial films. Furthermore, Gore has demonstrated a 10 µm reinforced membrane that is used in the new low-cost process and can meet automotive power density and durability targets. Across a wide range of operating conditions, the

  4. Durability of sealants exposed to outdoor weathering and hot compression cycles

    Science.gov (United States)

    Gregory T. Schueneman; Steven Lacher; Christopher G. Hunt; Christopher C. White; Donald L. Hunston

    2011-01-01

    Sealants play an important role in weatherproofing structures by filling gaps and preventing air and water intrusion. When incorrectly selected or improperly applied, they may fail quickly, compromising durability of the structure. To ensure reliability and prevent the need for costly repairs to structures, it is necessary to measure durability and predict life...

  5. Recommendations for Glass Durability Test Criteria

    International Nuclear Information System (INIS)

    Strachan, D.M.

    1999-01-01

    The objective of this short report is to define a set of activities that should lead to a specification for a test that can be used as one of the acceptance criteria and as an indicator of acceptable long-term behavior in contact with water. Since the glass composition is not yet defined and is likely to change as the composition of the waste changes, a strategy for developing criteria for what is acceptable involves a series of tests and modeling activities. The results of these activities lead to a criterion for an acceptable product and the data that are needed to reliably determine the behavior of the glass in the storage environment

  6. Recyclable magnetite-silver heterodimer nanocomposites with durable antibacterial performance

    Directory of Open Access Journals (Sweden)

    Chunyan Yong

    2018-03-01

    Full Text Available There is a significant need for magnetite-silver nanocomposites that exhibit durable and recyclable antimicrobial activity. In this study, magnetic iron oxide nanoparticles (Fe3O4 NPs coated with ethylenediamine-modified chitosan/polyacrylic acid copolymeric layer (Fe3O4@ECS/PAA were fabricated. Subsequently, directly deposited silver (Ag NPs procedure was carried out to form the antibacterial heterodimers of Fe3O4@ECS/PAA-Ag NPs. The composition and morphology of the resultant nanostructures were confirmed by FT-IR, XRD, TEM and TGA. The overall length of the heterodimers was approximately 45 nm, in which the mean diameter of Fe3O4@ECS/PAA NPs reached up to 35 nm, and that of Ag NPs was around 15 nm. The mass fraction of silver NPs in the nanocomposites was about 63.1%. The obtained Fe3O4@ECS/PAA NPs exhibited good colloidal stability, and excellent response to additional magnetic field, making the NPs easy to recover after antibacterial tests. In particular, the Fe3O4@ECS/PAA-Ag NPs retained nearly 100% biocidal efficiency (106–107 CFU/mg nanoparticles for both Gram-negative bacteria E. coli and Gram-positive bacteria S. aureus throughout ten cycles without washing with any solvents or water, exhibiting potent and durable antibacterial activity.

  7. Quantify and improve PEM fuel cell durability. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Grahl-Madsen, L.; Odgaard, M.; Munksgaard Nielsen, R. (IRD Fuel Cell A/S, Svendborg (Denmark)); Li, Q.; Jensen, Jens Oluf (Technical Univ. of Denmark, Dept. of Chemistry, Kgs. Lyngby (Denmark)); Andersen, Shuang Ma; Speder, J.; Skou, E. (Syddansk Univ. (SDU), Odense (Denmark))

    2010-07-01

    The aim of the present project is to systematically quantify and improve the durability of the PEM FC including the following three PEM FC variants: LT PEM FC, DMFC, and HT PEM FC. Different factors influencing dissolution properties of noble metal catalyst platinum and platinum-ruthenium alloy has been studied. The dissolution was found to increase by increasing the CV cycle upper potential limit, number of potential cycles, solution acidity, oxygen partial pressure, involvement of chloride, and temperature. Ruthenium was found to deteriorate ten (10) times faster than platinum catalyst; and carbon supported catalyst (Pt: 20%, Ru: up to 100%) deteriorate ten (10) times faster than non-supported catalyst (Pt: 2%, Ru: 30%) at the same condition. Loss of sulphonic acid groups and fluoride from perfluorinated sulfonic acid membrane was confirmed by different techniques, which locally leads to loss of acidity, and consequently enhances dissolution of noble metal catalyst. Degradation of Nafion ionomer in the electrode was enhanced by noble metal catalyst and the thermal decomposition properties has synergetic effect with carbon degradation. Hydrophobicity of GDL and electrode on GDL were found to degrade e.g. radical attack, oxidation, and physical wear out. The very top micro surface structure turned out to be responsible for wetting property after chemical ageing. Optimal catalyst and ionomer ratio is also reflected in contact angle value, which can be understood in terms of catalyst/carbon - ionomer affinity and layered structure. Long-term tested and 'virgin' LT PEM MEAs have been characterised with respect to SEM, TEM, EDS, and XRD. Both failed and well-functioning MEAs have been characterised. The Post Mortem analysis has shown and quantified degradation mechanisms like catalyst growth and carbon corrosion. Furthermore, the effect of fuel starvation was shown by pronounced Ru-catalyst band within the membrane. The catalyst coarsening observed after

  8. Durability of critical infrastructures

    OpenAIRE

    Raluca Pascu; Ramiro Sofronie

    2011-01-01

    The paper deals with those infrastructures by which world society, under the pressure ofdemographic explosion, self-survives. The main threatening comes not from terrorist attacks, but fromthe great natural catastrophes and global climate change. It’s not for the first time in history when suchmeasures of self-protection are built up. First objective of this paper is to present the background fordurability analysis. Then, with the aid of these mathematical tools the absolute durability of thr...

  9. Durability and Performance of High Performance Infiltration Cathodes

    DEFF Research Database (Denmark)

    Samson, Alfred Junio; Søgaard, Martin; Hjalmarsson, Per

    2013-01-01

    The performance and durability of solid oxide fuel cell (SOFC) cathodes consisting of a porous Ce0.9Gd0.1O1.95 (CGO) infiltrated with nitrates corresponding to the nominal compositions La0.6Sr0.4Co1.05O3-δ (LSC), LaCoO3-δ (LC), and Co3O4 are discussed. At 600°C, the polarization resistance, Rp......, varied as: LSC (0.062Ωcm2)cathode was found to depend on the infiltrate firing temperature and is suggested to originate...... of the infiltrate but also from a better surface exchange property. A 450h test of an LSC-infiltrated CGO cathode showed an Rp with final degradation rate of only 11mΩcm2kh-1. An SOFC with an LSC-infiltrated CGO cathode tested for 1,500h at 700°C and 0.5Acm-2 (60% fuel, 20% air utilization) revealed no measurable...

  10. Self-curing concrete types; water retention and durability

    Directory of Open Access Journals (Sweden)

    Magda I. Mousa

    2015-09-01

    This study was carried out to compare among concretes without or with silica fume (SF along with chemical type of shrinkage reducing admixture, polyethylene-glycol (Ch, and leca as self-curing agents for water retention even at elevated temperature (50 °C and their durability. The cement content of 400 kg/m3, silica fume of 15% by weight of cement, polyethylene-glycol of 2% by weight of cement, pre-saturated lightweight aggregate (leca 15% by volume of sand and water with Ch/binder ratio of 0.4 were selected in this study. Some of the physical and mechanical properties were determined periodically up to 28 days in case of exposure to air curing in temperature of (25 °C and (50 °C while up to 6 months of exposure to 5% of carbon dioxide and wet/dry cycles in 8% of sodium chloride for durability study. The concrete mass loss and the volumetric water absorption were measured, to evaluate the water retention of the investigated concretes. Silica fume concrete either without or with Ch gave the best results under all curing regimes; significant water retention and good durability properties.

  11. In vitro head-to-head comparison of the durability, versatility and efficacy of the NGage and novel Dakota stone retrieval baskets.

    Science.gov (United States)

    Bechis, Seth K; Abbott, Joel E; Sur, Roger L

    2017-12-01

    To compare head to head two end-engaging nitinol stone retrieval devices available to urologists, in terms of durability, versatility and efficacy. For durability testing, 30 NGage and Dakota baskets were cycled 20 times between grasping and releasing synthetic stone models and evaluated for damage or device failure. For versatility and efficacy testing, baskets were assessed in their ability to capture and release stone models from 1 to 11 mm. Each stone was raised above the capture site and the basket was opened to passively release the stone. If the stone did not release, the basket handle was shaken and the OpenSure feature employed if needed. Manual release was used as a last resort. Durability-the Cook NGage demonstrated a statistically significant increased rate of visible device breakdown (P=0.0046) in 8 of 30 (26.7%) devices vs. 0 of 30 Dakota devices, with mean damage at 13.5 cycles. Versatility and efficacy-both 8 mm baskets successfully captured stones from 1-8 mm. The Dakota more effectively released 7-8 mm stones (PDakota. For 11 mm baskets, the Dakota released all stones up to 10 mm with simple opening, while the NGage released 10 of 15 (67%) of 9 mm stones and 1 of 15 (7%) of 10 mm stones by simple opening. For 11 mm stones, the Dakota captured 100% whereas NGage could not capture any. Both baskets showed similar durability characteristics. The Dakota basket more effectively captured and released stones over 7 mm, as compared to the NGage basket. The OpenSure aspect conferred an advantage in handling and release of larger stones. These in vitro results demonstrate potential versatility, durability and efficacy of the Dakota basket.

  12. Study on determination of durability analysis process and fatigue damage parameter for rubber component

    International Nuclear Information System (INIS)

    Moon, Seong In; Cho, Il Je; Woo, Chang Su; Kim, Wan Doo

    2011-01-01

    Rubber components, which have been widely used in the automotive industry as anti-vibration components for many years, are subjected to fluctuating loads, often failing due to the nucleation and growth of defects or cracks. To prevent such failures, it is necessary to understand the fatigue failure mechanism for rubber materials and to evaluate the fatigue life for rubber components. The objective of this study is to develop a durability analysis process for vulcanized rubber components, that can predict fatigue life at the initial product design step. The determination method of nonlinear material constants for FE analysis was proposed. Also, to investigate the applicability of the commonly used damage parameters, fatigue tests and corresponding finite element analyses were carried out and normal and shear strain was proposed as the fatigue damage parameter for rubber components. Fatigue analysis for automotive rubber components was performed and the durability analysis process was reviewed

  13. Fatigue behaviour analysis for the durability prequalification of strengthening mortars

    International Nuclear Information System (INIS)

    Bocca, P; Grazzini, A; Masera, D

    2011-01-01

    An innovative laboratory procedure used as a preliminary design stage for the pre-qualification of strengthening mortars applied to historical masonry buildings is described. In the analysis of the behaviour of masonry structures and their constituent materials, increasing importance has been assumed by the study of the long-term evolution of deformation and mechanical characteristics, which may be affected by both loading and environmental conditions. Through static and fatigue tests on mixed specimens historical brick-reinforced mortar it has been possible to investigate the durability of strengthening materials, in order to select, from a range of alternatives, the most suitable for the historical masonry. Cyclic fatigue stress has been applied to accelerate the static creep and to forecast the corresponding creep behaviour of the historical brick-strengthening mortar system under static long-time loading. This methodology has proved useful in avoiding the errors associated with materials that are not mechanically compatible and guarantees the durability of strengthening work. The experimental procedure has been used effectively in the biggest restoration building site in Europe, the Royal Palace of Venaria, and it is in progress of carrying out at the Special Natural Reserve of the Sacro Monte di Varallo, in Piedmont (Italy).

  14. Influence of ceria on the thermally durability of Pt/Rh automotive catalyst

    International Nuclear Information System (INIS)

    Muraki, H.; Zhang, G.

    1998-01-01

    Full text: The use of cerium oxide as an oxygen storage component in automotive three-way catalysts has been well established. More recently the requirement of the three-way catalysts against the increase of the severity in emission standards has focused attention on the development of more active, durable catalysts. The thermally durability of Pt/Rh catalyst can be achieved by the utilization of thermally stable ceria as well as optimization of washcoat composition and structure in order to control the extent of interaction between PGM and ceria. In the present paper, we describe the influence of newly developed washcoat components and PGM interaction with ceria on catalytic performance. First, to clear that the interaction between PGM and ceria contributes to catalytic performance, several kinds of catalysts which have the varied interactions between PGM and ceria were prepared using engineered washcoat techniques and evaluated in the model gas reactor. It was obvious that the difference in performance among them after aging derived from a diversity of interactions between Pt, Rh, and ceria. Second, for the purpose of determining the thermally durability of the developed Pt/Rh catalyst, the catalysts including the current catalyst were aged under three different temperatures and evaluated on engine dynamometer. Result of engine dynamometer evaluation revealed that significant improvement in the thermal durability can be achieved by optimizing the PGM-ceria interaction. In conclusion, we recognize that a thermal durability of a three-way catalyst can be improved by the stabilization of proper PGM-ceria interaction after aging as well as the utilization of thermally durable ceria material

  15. The prospective buyer of consumer durables

    NARCIS (Netherlands)

    Jonge, Leendert de; Oppedijk van Veen, Walle Melis

    1982-01-01

    In this book, an empirical investigation is reported wich aims at the specification of models of individual households’ purchase behaviour for particular consumer durable goods, such as private passenger cars and television sets. In particular, the focus is on models wich can be used for predicting

  16. Durable flame retardant finish for silk fabric using boron hybrid silica sol

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Qiang-hua; Gu, Jiali; Chen, Guo-qiang [National Engineering Laboratory for Modern Silk, Soochow University (China); Xing, Tie-ling, E-mail: xingtieling@suda.edu.cn [National Engineering Laboratory for Modern Silk, Soochow University (China); Jiangsu HuaJia Group (China)

    2016-11-30

    Highlights: • Highly homogeneous boron hybrid silica sol flame retardant system was prepared through sol-gel method. • The silk samples treated and cross-linked by this hybrid sol and BTCA solution showed a higher limiting oxygen index (LOI) more than 31.0% and a better washing durability for more than 30 times washing. • The smoke suppression, combustion performance and thermal stability properties of the treated samples have a significant improvement. - Abstract: A hybrid silica sol was prepared via sol gel method using tetraethoxysilane (TEOS) as a precursor and boric acid (H{sub 3}BO{sub 3}) as flame retardant additive and then applied to silk fabric. In order to endow silk fabric with durable flame retardancy, 1,2,3,4-butanetetracarboxylic acid (BTCA) was used as cross-linking agent for the sake of strong linkage formation between the hybrid silica sol and silk fabric. The FT-IR and XPS analysis demonstrated the Si-O-B formation in the sol system, as well as the linkage between the sol and silk after the treatment. The limiting oxygen index (LOI) and smoke density test indicated good flame retardancy and smoke suppression of the treated silk fabrics. The micro calorimeter combustion (MCC) test and thermo gravimetric (TG) analysis showed that the treated samples had less weight loss in the high temperature and lower heat release rate when burning. The washing durability evaluation results indicated that there was a distinct improvement for the silk samples treated with BTCA even after 30 times washing. In addition, the influence of the processing order of BTCA and silica sol treatment on the limiting oxygen index (LOI) of the finished silk fabric was also investigated. And the results demonstrated that the sample treated with BTCA first and then with the silica sol exhibited better LOI value (32.3%) than that of the sample by the conversed treatment order. Moreover the tensile property of treated samples was nearly unchanged, but the handle of sol treated

  17. Evaluation of gamma ray durability and its application of shielded RF tags

    International Nuclear Information System (INIS)

    Teraura, Nobuyuki; Ito, Kunio; Kobayashi, Daisuke; Sakurai, Kouichi

    2015-01-01

    In this study, the RF (Radio Frequency) tag with radiation shield is developed and its gamma ray durability is evaluated. RFID (RF Identification) is a radio-wave-based identification technology that can be used for various items. RF tags find use in many applications, including item tracing, access control, etc. RF tags can be classified as active RF tags, which have inbuilt voltaic cells, and passive RF tags without these cells. Passive RF tags, known for their low price and durability, are used in various fields. For instance, they are used for equipment maintenance in factories and thermal power plants. Several frequencies are used for RF tags. Further, RF tagging on the UHF (Ultra High Frequency) frequencies allows a communication range of approximately 10 m, and thus, remote reading is possible. When used in radiation environments such as in nuclear power plants, remote reading can contribute to the reduction of radiation exposure. However, because semiconductors are the primary elements used in the manufacture of RF tags, they can be damaged by radiation, and operational errors can occur. Therefore, this technology has not been used in environments affected by relatively high radiation levels. Therefore, in nuclear power plants, the use of RF tags is limited in areas of low radiation levels. In our study, we develop and manufacture a new RF tag with a radiation shield cover that provides error correction functionality. It is expected that radiation shielded RF tags will improve the radiation-proof feature, and its application range will be expanded. Using the radiation-proof RF tag, we have conducted radiation durability tests. These tests are of two types: one using low energy gamma ray, and the other using high-energy gamma ray. Experimental results are then analyzed. The number of applications for radiation shielded RF tags is considerably increasing, because it can be used in various radiation environments other than nuclear power plants as well, such as

  18. Durability assessment of soft elastomeric capacitor skin for SHM of wind turbine blades

    Science.gov (United States)

    Downey, Austin; Pisello, Anna Laura; Fortunati, Elena; Fabiani, Claudia; Luzi, Francesca; Torre, Luigi; Ubertini, Filippo; Laflamme, Simon

    2018-03-01

    Renewable energy production has become a key research driver during the last decade. Wind energy represents a ready technology for large-scale implementation in locations all around the world. While important research is conducted to optimize wind energy production efficiency, a critical issue consists of monitoring the structural integrity and functionality of these large structures during their operational life cycle. This paper investigates the durability of a soft elastomeric capacitor strain sensing membrane, designed for structural health monitoring of wind turbines, when exposed to aggressive environmental conditions. The sensor is a capacitor made of three thin layers of an SEBS polymer in a sandwich configuration. The inner layer is doped with titania and acts as the dielectric, while the external layers are filled with carbon black and work as the conductive plates. Here, a variety of samples, not limited to the sensor configuration but also including its dielectric layer, were fabricated and tested within an accelerated weathering chamber (QUV) by simulating thermal, humidity, and UV radiation cycles. A variety of other tests were performed in order to characterize their mechanical, thermal, and electrical performance in addition to their solar reflectance. These tests were carried out before and after the QUV exposures of 1, 7, 15, and 30 days. The tests showed that titania inclusions improved the sensor durability against weathering. These findings contribute to better understanding the field behavior of these skin sensors, while future developments will concern the analysis of the sensing properties of the skin after aging.

  19. Durability of Dukovany shallow land repository engineered barriers. Appendix 7: Czech Republic

    International Nuclear Information System (INIS)

    Vokal, A.; Nachmilner, L.; Wasserbauer, R.; Dohnalek, J.

    2001-01-01

    The main aim of this project was to explore the durability of engineering barriers used at Dukovany shallow land repository as a support of safety assessments. This appendix summarises the principal results focused on durability of asphaltopropyleneconcrete (APC) hydroisolation and steel reinforced concrete construction

  20. Technical Note: Updated durability/composition relationships for Hanford high-level waste glasses

    International Nuclear Information System (INIS)

    Piepel, G.F.; Hartley, S.A.; Redgate, P.E.

    1996-03-01

    This technical note presents empirical models developed in FYI 995 to predict durability as functions of glass composition. Models are presented for normalized releases of B, Li, Na, and Si from the 7-day Product Consistency Test (PCT) applied to quenched and canister centerline cooled (CCC) glasses as well as from the 28-day Materials Characterization Center-1 (MCC-1) test applied to quenched glasses. Models are presented for Composition Variation Study (CVS) data from low temperature melter (LTM) studies (Hrma, Piepel, et al. 1994) and high temperature melter (HTM) studies (Vienna et al. 1995). The data used for modeling in this technical note are listed in Appendix A

  1. Investigation on Stress-Rupture Behavior of a Chopped-Glass-Fiber Composite for Automotive Durability Design Criteria

    Energy Technology Data Exchange (ETDEWEB)

    Ren, W

    2001-08-24

    Practical and inexpensive testing methods were developed to investigate stress-rupture properties of a polymeric composite with chopped glass fiber reinforcement for automotive applications. The material was tested in representative automotive environments to generate experimental data. The results indicate that environments have substantial effects on the stress-rupture behavior. The data were analyzed and developed into stress-rupture design criteria to address one of the durability aspects of the material for automotive structural applications.

  2. Durable superhydrophobic surfaces made by intensely connecting a bipolar top layer to the substrate with a middle connecting layer.

    Science.gov (United States)

    Zhi, Jinghui; Zhang, Li-Zhi

    2017-08-30

    This study reported a simple fabrication method for a durable superhydrophobic surface. The superhydrophobic top layer of the durable superhydrophobic surface was connected intensely to the substrate through a middle connecting layer. Glycidoxypropyltrimethoxysilane (KH-560) after hydrolysis was used to obtain a hydrophilic middle connecting layer. It could be adhered to the hydrophilic substrate by covalent bonds. Ring-open reaction with octadecylamine let the KH-560 middle layer form a net-like structure. The net-like sturcture would then encompass and station the silica particles that were used to form the coarse micro structures, intensely to increase the durability. The top hydrophobic layer with nano-structures was formed on the KH-560 middle layer. It was obtained by a bipolar nano-silica solution modified by hexamethyldisilazane (HMDS). This layer was connected to the middle layer intensely by the polar Si hydroxy groups, while the non-polar methyl groups on the surface, accompanied by the micro and nano structures, made the surface rather hydrophobic. The covalently interfacial interactions between the substrate and the middle layer, and between the middle layer and the top layer, strengthened the durability of the superhydrophobic surface. The abrasion test results showed that the superhydrophobic surface could bear 180 abrasion cycles on 1200 CW sandpaper under 2 kPa applied pressure.

  3. The influence of the curing conditions of concrete on durability after freeze-thaw accelerated testing

    Directory of Open Access Journals (Sweden)

    Al-Assadi, G.

    2015-12-01

    Full Text Available This work relates the curing conditions of concrete with the damage caused by rapid freeze-thaw cycles (ASTM C 666. The “potential” durability of concrete after testing is also studied. In countries with a continental climate, the curing of concrete in summer is performed under high-temperature and low-humidity conditions, and during the winter the concrete undergoes freezing and thawing. This paper shows the experimental results of the behaviour of concrete specimens cured under climatic summer conditions and then subjected to freeze-thaw cycles. Curing of the specimens includes conditions of good and bad practice in relation to wetting and protection of the concrete. Mechanical properties, cement hydration, volume and pore sizes, oxygen permeability, chloride diffusion and water penetration under pressure tests of the concrete are assessed. These tests were performed before and after the application of the freeze-thaw cycles. Statistical analysis of the correlation among variables is also included.Este trabajo relaciona las condiciones de curado del hormigón con los daños causados por ciclos hielo-deshielo (ASTM C 666. Estudia la durabilidad “potencial” del hormigón dañado por este ensayo. En países con clima continental, el curado del hormigón en verano se realiza con alta temperatura y baja humedad, y durante el invierno sufre condiciones de hielo-deshielo. Se presentan los resultados experimentales de probetas de hormigón curadas bajo condiciones climáticas del verano y luego sometidas a ciclos hielo-deshielo. El curado de las probetas incluye condiciones de buenas y malas prácticas en relación con el curado del hormigón. Se miden las propiedades mecánicas, grado de hidratación, volumen de poros y distribución de tamaños, permeabilidad al oxígeno, penetración de agua bajo presión y coeficiente de difusión de cloruros antes y después de la aplicación de los ciclos de hielo-deshielo. Se incluye un estudio estad

  4. Quantitative Resistance to Plant Pathogens in Pyramiding Strategies for Durable Crop Protection

    Directory of Open Access Journals (Sweden)

    Marie-Laure Pilet-Nayel

    2017-10-01

    Full Text Available Quantitative resistance has gained interest in plant breeding for pathogen control in low-input cropping systems. Although quantitative resistance frequently has only a partial effect and is difficult to select, it is considered more durable than major resistance (R genes. With the exponential development of molecular markers over the past 20 years, resistance QTL have been more accurately detected and better integrated into breeding strategies for resistant varieties with increased potential for durability. This review summarizes current knowledge on the genetic inheritance, molecular basis, and durability of quantitative resistance. Based on this knowledge, we discuss how strategies that combine major R genes and QTL in crops can maintain the effectiveness of plant resistance to pathogens. Combining resistance QTL with complementary modes of action appears to be an interesting strategy for breeding effective and potentially durable resistance. Combining quantitative resistance with major R genes has proven to be a valuable approach for extending the effectiveness of major genes. In the plant genomics era, improved tools and methods are becoming available to better integrate quantitative resistance into breeding strategies. Nevertheless, optimal combinations of resistance loci will still have to be identified to preserve resistance effectiveness over time for durable crop protection.

  5. Bio-inspired polymeric patterns with enhanced wear durability for microsystem applications

    International Nuclear Information System (INIS)

    Singh, R. Arvind; Siyuan, L.; Satyanarayana, N.; Kustandi, T.S.; Sinha, Sujeet K.

    2011-01-01

    At micro/nano-scale, friction force dominates at the interface between bodies moving in relative motion and severely affects their smooth operation. This effect limits the performance of microsystem devices such as micro-electro-mechanical systems (MEMS). In addition, friction force also leads to material removal or wear and thereby reduces the durability i.e. the useful operating life of the devices. In this work, we fabricated bio-inspired polymeric patterns for tribological applications. Inspired by the surface features on lotus leaves namely, the protuberances and wax, SU-8 polymeric films spin-coated on silicon wafers were topographically and chemically modified. For topographical modification, micro-scale patterns were fabricated using nanoimprint lithography and for chemical modification, the micro-patterns were coated with perfluoropolyether nanolubricant. Tribological investigation of the bio-inspired patterns revealed that the friction coefficients reduced significantly and the wear durability increased by several orders. In order to enhance the wear durability much further, the micro-patterns were exposed to argon/oxygen plasma and were subsequently coated with the perfluoropolyether nanolubricant. Bio-inspired patterns with enhanced wear durability, such as the ones investigated in the current work, have potential tribological applications in MEMS/Bio-MEMS actuator-based devices. Highlights: →Bio-inspired polymeric patterns for tribological applications in microsystems. →Novel surface modification for the patterns to enhance tribological properties. →Patterns show low friction properties and extremely high wear durability.

  6. Highly durable and low permeable concrete for LLW facilities

    International Nuclear Information System (INIS)

    Yanagibashi, Kunio; Saito, Toshio; Odagawa, Masaro.

    1997-01-01

    Concrete used for LLW facilities is required to be highly durable. The authors evaluated concrete containing glycol ether derivatives and silica fume as admixtures. Compressive strength, diffusion coefficient of water, depth of accelerated carbonation, drying shrinkage, depth of chlorides penetration and resistance to freezing and thawing were investigated using concrete specimens. Compressive strength, depth of accelerated carbonation, diffusion coefficient of 137 Cs were investigated using mortar specimens before and after irradiation of gamma rays. Results showed that using glycol ether derivatives and silica fume was effective in improving the durability. (author)

  7. Durability study on material of wooden panel elements used for the old living hut built in 1969 at Syowa Station, Antarctica

    Directory of Open Access Journals (Sweden)

    Toshimasa Konishi

    2002-09-01

    Full Text Available The purpose of this study is to determine the durability of the old living hut built in 1969 at Syowa Station, Japan's permanent Antarctic observation facility, especially of its wooden panels. The hut, of high floor type wooden panel construction, was built in January 1969. To determine the durability, part of the hut, which was brought back to Japan after 30 years, was rebuilt, then taken apart again under controlled test conditions. Tests included visual observation, testing of the wooden material, and testing of the performance of the thermal insulation material. The results showed that the material in the roof panels deteriorated considerably more than that in the walls and floors. In the severe polar conditions, the strength of the overall structure depends heavily on the joints between panels. It is clear that material on the indoor sides, and in the interiors of the panels, hardly deteriorated at all after 30 years.

  8. Durable fear memories require PSD-95

    Science.gov (United States)

    Fitzgerald, Paul J.; Pinard, Courtney R.; Camp, Marguerite C.; Feyder, Michael; Sah, Anupam; Bergstrom, Hadley; Graybeal, Carolyn; Liu, Yan; Schlüter, Oliver; Grant, Seth G.N.; Singewald, Nicolas; Xu, Weifeng; Holmes, Andrew

    2014-01-01

    Traumatic fear memories are highly durable but also dynamic, undergoing repeated reactivation and rehearsal over time. While overly persistent fear memories underlie anxiety disorders such as posttraumatic stress disorder, the key neural and molecular mechanisms underlying fear memory durability remain unclear. Post-synaptic density 95 (PSD-95) is a synaptic protein regulating glutamate receptor anchoring, synaptic stability and certain types of memory. Employing a loss-of-function mutant mouse lacking the guanylate kinase domain of PSD-95 (PSD-95GK), we analyzed the contribution of PSD-95 to fear memory formation and retrieval, and sought to identify the neural basis of PSD-95-mediated memory maintenance using ex vivo immediate-early gene mapping, in vivo neuronal recordings and viral-mediated knockdown approaches. We show that PSD-95 is dispensable for the formation and expression of recent fear memories, but essential for the formation of precise and flexible fear memories and for the maintenance of memories at remote time points. The failure of PSD-95GK mice to retrieve remote cued fear memories was associated with hypoactivation of the infralimbic cortex (IL) (not anterior cingulate (ACC) or prelimbic cortex), reduced IL single-unit firing and bursting, and attenuated IL gamma and theta oscillations. Adeno-associated PSD-95 virus-mediated knockdown in the IL, not ACC, was sufficient to impair recent fear extinction and remote fear memory, and remodel IL dendritic spines. Collectively, these data identify PSD-95 in the IL as a critical mechanism supporting the durability of fear memories over time. These preclinical findings have implications for developing novel approaches to treating trauma-based anxiety disorders that target the weakening of overly persistent fear memories. PMID:25510511

  9. Influence of Some Nuclear Waste on The Durability and Mechanical Properties of Borosilicate glass

    International Nuclear Information System (INIS)

    El-Alaily, N.A.

    2003-01-01

    Various glass systems have been shown to be suitable for producing waste glass forms that are thermally and mechanically stable and exhibit good chemical durability. In this study borosilicate glass containing sodium oxide and aluminum oxide was prepared as a host for high level nuclear waste. The glass durability when the samples were immersed either in distilled water or ground water at 70 degree was studied. The density, porosity and mechanical properties were also investigated. The effects of exposing the samples immersed in groundwater to gamma rays in the glass durability and all other mentioned properties were also studied. The results showed that immersing the glass in ground water causing a decrease in the glass durability. The exposure of the glass immersed in ground water to the gamma rays increases the durability of the glass. The mechanical properties of the prepared glass were good. Although these properties decrease for the corroded glass but they were still good

  10. Durable Viral Suppression and Transmission Risk Potential Among Persons With Diagnosed HIV Infection: United States, 2012-2013.

    Science.gov (United States)

    Crepaz, Nicole; Tang, Tian; Marks, Gary; Mugavero, Michael J; Espinoza, Lorena; Hall, H Irene

    2016-10-01

    We examined durable viral suppression, cumulative viral load (VL) burden, and transmission risk potential among human immunodeficiency virus (HIV)-diagnosed persons in care. Using data from the National HIV Surveillance System from 17 jurisdictions with complete reporting of VL test results, we determined the percentage of persons in HIV care who achieved durable viral suppression (all VL results suppression. The remaining 38% had high VL burden (geometric mean of viremia copy-years, 7261) and spent an average of 438 days, 316 days, and 215 days (60%, 43.2%, and 29.5% of the 2-year period) above 200, 1500, and 10 000 copies/mL. Women, blacks/African Americans, Hispanics/Latinos, persons with HIV infection attributed to transmission other than male-to-male sexual contact, younger age groups, and persons with gaps in care had higher viral burden and transmission risk potential. Two-thirds of persons in HIV care had durable viral suppression during a 2-year period. One-third had high VL burden and spent substantial time above VL levels with increased risk of onward transmission. More intervention efforts are needed to improve retention in care and medication adherence so that more persons in HIV care achieve durable viral suppression. Published by Oxford University Press for the Infectious Diseases Society of America 2016. This work is written by (a) US Government employee(s) and is in the public domain in the US.

  11. Chemical durability of silicoborate glasses

    International Nuclear Information System (INIS)

    Nieto, M.I.; Rodriguez, M.A.; Rubio, J.; Fernandez, A.; Oteo, J.L.

    1987-01-01

    A general view of the durability in silicoborate glasses is presented with more emphasis on the etching factors (chemical composition, lattice structure, pH...) the techniques used for this study and the experimental results. Likewise, the research presently developed in this area at the Instituto de Ceramica y Vidrio, CSIC, is related to the applications. Future research in this field is also mentioned. (author) 15 figs

  12. FAA/NASA International Symposium on Advanced Structural Integrity Methods for Airframe Durability and Damage Tolerance, part 2

    Science.gov (United States)

    Harris, Charles E. (Editor)

    1994-01-01

    The international technical experts in the areas of durability and damage tolerance of metallic airframe structures were assembled to present and discuss recent research findings and the development of advanced design and analysis methods, structural concepts, and advanced materials. The principal focus of the symposium was on the dissemination of new knowledge and the peer-review of progress on the development of advanced methodologies. Papers were presented on the following topics: structural concepts for enhanced durability, damage tolerance, and maintainability; new metallic alloys and processing technology; fatigue crack initiation and small crack effects; fatigue crack growth models; fracture mechanics failure criteria for ductile materials; structural mechanics methodology for residual strength and life prediction; development of flight load spectra for design and testing; and corrosion resistance.

  13. Facile Fabrication of Durable Copper-Based Superhydrophobic Surfaces via Electrodeposition.

    Science.gov (United States)

    Jain, R; Pitchumani, R

    2018-03-13

    Superhydrophobic surfaces have myriad industrial applications, yet their practical utilization has been limited by their poor mechanical durability and longevity. We present a low-cost, facile process to develop superhydrophobic copper-based coatings via an electrodeposition route, that addresses this limitation. Through electrodeposition, a stable, multiscale, cauliflower shaped fractal morphology was obtained and upon modification by stearic acid, the prepared coatings show extreme water repellency with contact angle of 162 ± 2° and roll-off angle of about 3°. Systematic studies are presented on coatings fabricated under different processing conditions to demonstrate good durability, mechanical and underwater stability, corrosion resistance, and self-cleaning effect. The study also presents an approach for rejuvenation of slippery superhydrophobic nature (roll-off angle <10°) on the surfaces after long-term water immersion. The presented process can be scaled to larger, durable coatings with controllable wettability for diverse applications.

  14. Advantage from Funding Durable Centers Leasing

    Directory of Open Access Journals (Sweden)

    Alina Zając

    2009-09-01

    Full Text Available In present market conditions huge number of businessmen has problems from gain over from banks capital on purchase of durable centers not only, but also on develop - ment and operating activity Individual can use with different forms funding investment, it which is between different leasing.

  15. Preparation of durable hydrophobic cellulose fabric from water glass and mixed organosilanes

    Science.gov (United States)

    Shang, Song-Min; Li, Zhengxiong; Xing, Yanjun; Xin, John H.; Tao, Xiao-Ming

    2010-12-01

    Durable superhydrophobic cellulose fabric was prepared from water glass and n-octadecyltriethoxysilane (ODTES) with 3-glycidyloxypropyltrimethoxysilane (GPTMS) as crosslinker by sol-gel method. The result showed that the addition of GPTMS could result in a better fixation of silica coating from water glass on cellulose fabric. The silanization of hydrolyzed ODTES at different temperatures and times was studied and optimized. The results showed that silanization time was more important than temperature in forming durable hydrophobic surface. The durability of superhydrophobicity treatment was analyzed by XPS. As a result, the superhydrophobic cotton treated under the optimal condition still remained hydrophobic properties after 50 washing cycles.

  16. Price freezes, durables and residential electricity demand - Evidence from the Greater Buenos Aires

    Energy Technology Data Exchange (ETDEWEB)

    Casarin, Ariel; Delfino, Maria Eugenia

    2010-09-15

    This paper examines the determinants of residential electricity demand in the Greater Buenos Aires between 1997 and 2006. During the second half of this period, residential tariffs remained nominally fixed, while an income boom boosted up the sales of durables. This study differs from previous works in that it explicitly considers the impact of the stock of air-conditioners on residential demand. The paper reports short- and long-run elasticities and examines the contribution of prices and durables to recent demand growth. Simulations illustrate the impact of prices and durables on future demand.

  17. Bonding Durability of Four Adhesive Systems

    Directory of Open Access Journals (Sweden)

    Leila Atash Biz Yeganeh

    2016-04-01

    Full Text Available Objectives: This study aimed to compare the durability of four adhesive systems by assessing their microtensile bond strength (MTBS and microleakage during six months of water storage.Materials and Methods: A total of 128 human third molars were used. The adhesives tested were Scotch Bond Multipurpose (SBMP, Single Bond (SB, Clearfil-SE bond (CSEB, and All-Bond SE (ABSE. After sample preparation for MTBS testing, the microspecimens were subjected to microtensile tester after one day and six months of water storage. For microleakage evaluation, facial and lingual class V cavities were prepared and restored with composite. After thermocycling, microleakage was evaluated. Bond strength values were subjected to one-way ANOVA and Tamhane’s test, and the microleakage data were analyzed by the Kruskal-Wallis, Dunn, Mann Whitney and Wilcoxon tests (P<0.05.Results: Single Bond yielded the highest and ABSE yielded the lowest bond strength at one day and six months. Short-term bond strength of SBMP and CSEB was similar. After six months, a significant decrease in bond strength was observed in ABSE and SBMP groups. At one day, ABSE showed the highest microleakage at the occlusal margin; however, at the gingival margin, there was no significant difference among groups. Long-term microleakage of all groups at the occlusal margins was similar, whilst gingival margins of SBMP and SB showed significantly higher microleakage.Conclusion: The highest MTBS and favorable sealability were obtained by Clearfil SE bond. Water storage had no effect on microleakage of self-etch adhesives at the gingival margin or MTBS of CSEB and SB. 

  18. Design of concrete structures for durability. Example: Chloride penetration in the lining of a bored tunnel

    NARCIS (Netherlands)

    Siemes, A.J.M.

    1998-01-01

    The present design method for durability of concrete is based on a set of rules that give no objective in-sight in the service life to expect from the concrete structure. An objective comparison between different durability measures is therefor not possible. Especially if the lack of durability can

  19. Investigation on Stress-Rupture Behavior of a Chopped-Glass-Fiber Composite for Automotive Durability Design Criteria; FINAL

    International Nuclear Information System (INIS)

    Ren, W

    2001-01-01

    Practical and inexpensive testing methods were developed to investigate stress-rupture properties of a polymeric composite with chopped glass fiber reinforcement for automotive applications. The material was tested in representative automotive environments to generate experimental data. The results indicate that environments have substantial effects on the stress-rupture behavior. The data were analyzed and developed into stress-rupture design criteria to address one of the durability aspects of the material for automotive structural applications

  20. Use of blast-furnace slag in making durable concrete for waste management repositories

    International Nuclear Information System (INIS)

    Feldman, R.F.; Beaudoin, J.J.; Philipose, K.E.

    1991-02-01

    Waste repositories for the belowground disposal of low-level radioactive waste rely greatly on the durability of concrete for their required 500-year service life. A research program is in progress based on laboratory testing of concretes containing either Type 1 cement or cements containing 65 and 75 percent of blast-furnace slag, each at 4 water-cement ratios. It has been established that the degradation of the concrete will depend on the rate of ingress of corrosive agents - chlorides, sulphate ions and CO 2 . The ionic profiles and the kinetics of diffusion of these ions in the concretes have been measured by Secondary Electron Microscope (SEM) and Energy Dispersive X-ray Analysis (EDXA) techniques, and the results plotted according to a mathematical model. Predictions for service life of the concrete have been made from this model. These predictions have been correlated with properties of the concrete obtained from micro-structural, thermochemical and permeability measurements. The improvements in concrete durability due to blast-furnace slag additions are illustrated and discussed

  1. Review of research on the hygrothermal environmental durability of structural adhesively bonded joints

    Directory of Open Access Journals (Sweden)

    Xiao HAN

    2017-06-01

    Full Text Available In recent years, structural adhesive bonding technology has been widely used in many industrial fields, with many advantages over traditional mechanical connection methods, such as riveting, welding and bolt connection. Due to the adhesive characteristics of polymer materials, the environmental durability of adhesive joint becomes the key problems in engineering structure connection feasibility and long-term service reliability. On the basis of the review of the research of the hot-humid environmental durability of structural adhesive joints, the effects of temperature, moisture and coupled condition on the structural mechanical behaviour are discussed, introducing the published research progress and results both at home and abroad. The prospects are provided: the future research work can be combined with a variety of observation scales of environmental aging test and numerical simulation method, delve into sub hygroscopic, creep, thermal expansion and hygroscopic expansion aging behavior, such as the environment of model prediction method simulation in more than a variety of mechanical performance degradation behavior of coupling conditions, and provide more reliable theoretical modeling and experimental data for engineering design and application of cementing structure.

  2. Use of blast-furnace slag in making durable concrete for waste management repositories

    Energy Technology Data Exchange (ETDEWEB)

    Feldman, R. F.; Beaudoin, J. J. [National Research Council of Canada, Ottawa, ON (Canada); Philipose, K. E.

    1991-02-15

    Waste repositories for the belowground disposal of low-level radioactive waste rely greatly on the durability of concrete for their required 500-year service life. A research program is in progress based on laboratory testing of concretes containing either Type 1 cement or cements containing 65 and 75 percent of blast-furnace slag, each at 4 water-cement ratios. It has been established that the degradation of the concrete will depend on the rate of ingress of corrosive agents - chlorides, sulphate ions and CO{sub 2}. The ionic profiles and the kinetics of diffusion of these ions in the concretes have been measured by Secondary Electron Microscope (SEM) and Energy Dispersive X-ray Analysis (EDXA) techniques, and the results plotted according to a mathematical model. Predictions for service life of the concrete have been made from this model. These predictions have been correlated with properties of the concrete obtained from micro-structural, thermochemical and permeability measurements. The improvements in concrete durability due to blast-furnace slag additions are illustrated and discussed.

  3. Recent Advances in Durability and Damage Tolerance Methodology at NASA Langley Research Center

    Science.gov (United States)

    Ransom, J. B.; Glaessgen, E. H.; Raju, I. S.; Harris, C. E.

    2007-01-01

    Durability and damage tolerance (D&DT) issues are critical to the development of lighter, safer and more efficient aerospace vehicles. Durability is largely an economic life-cycle design consideration whereas damage tolerance directly addresses the structural airworthiness (safety) of the vehicle. Both D&DT methodologies must address the deleterious effects of changes in material properties and the initiation and growth of damage that may occur during the vehicle s service lifetime. The result of unanticipated D&DT response is often manifested in the form of catastrophic and potentially fatal accidents. As such, durability and damage tolerance requirements must be rigorously addressed for commercial transport aircraft and NASA spacecraft systems. This paper presents an overview of the recent and planned future research in durability and damage tolerance analytical and experimental methods for both metallic and composite aerospace structures at NASA Langley Research Center (LaRC).

  4. Durability of wood-plastic composite lumber

    Science.gov (United States)

    Rebecca E. Ibach

    2010-01-01

    Wood-plastic composite (WPC) lumber has been marketed as a low-maintenance, high-durability product. Retail sales in the United States were slightly less than $1 billion in 2008. Applications include docking, railing, windows, doors, fencing, siding, moldings, landscape timbers, car interior parts, and furniture. The majority of these products are used outdoors and...

  5. Design of durability and lifetime assessment method under thermomechanical stress for thermal barrier coatings

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Hyun Gyoo; Choi, Young Kue; Jeon, Seol; Lee, Hee Soo [Pusan National University, Busan (Korea, Republic of); Jeon, Min Seok [Korea Testing Laboratory, Seoul (Korea, Republic of)

    2014-01-15

    A durability testing method under thermo-mechanical stress for thermal barrier coatings (TBC) specimens was designed by a combination of an electric furnace and a tensile testing machine, which was done on TBCs on NIMONIC 263 substrates by an atmospheric plasma spraying (APS) deposition method. The testing conditions were chosen according to a preliminary experiment that identified the elastic deformation region of the top coating and the substrate during mechanical loading. Surface cracking and a decrease in the thickness of the top coating, which are typical degradation behaviors under conventional thermal shock testing, were observed after the designed thermal fatigue test, and delamination at the top coating-bond coating interface occurred by the mechanical load. Lifetime assessment was conducted by statistical software using life cycle data which were obtained after the thermal fatigue test.

  6. Fabrication of recyclable and durable superhydrophobic materials with wear/corrosion-resistance properties from kaolin and polyvinylchloride

    International Nuclear Information System (INIS)

    Qu, Mengnan; Liu, Shanshan; He, Jinmei; Feng, Juan; Yao, Yali; Ma, Xuerui; Hou, Lingang; Liu, Xiangrong

    2017-01-01

    Highlights: • The scraped debris can be recycled and easily reused to fabricate the superhydrophobic materials. • The obtained materials displayed liquid-repellent toward water and several other liquids of daily life. • The superhydrophobic materials can retain excellent chemical stability and mechanical durability after rigorous tests. • This as-prepared material can be regarded as a real superhydrophobic “material”, not just the superhydrophobic “surface”. - Abstract: In this study, mechanically stable and recyclable superhydrophobic materials were prepared from polyvinylchloride (PVC) and kaolin nanoparticles modified by stearic acid using a simple and low-cost drop-coating. The obtained materials displayed liquid-repellent toward water and several other liquids of daily life (such as orange juice, coffee, milk, coca cola and ink). These superhydrophobic materials showed remarkable robustness against sandpaper abrasion, UV-irradiation and ultrasonication test, while retaining its superhydrophobicity even after 60 abrasion cycles loaded of 500 g with sandpaper, 7 days UV-irradiation or 120 min ultrasonication test. The excellent durability against complex conditions was attributed to the hierarchical structure and strong interfacial adhesion of the materials. More significantly, the materials used in the coating could be recycled and reconstructed without losing its superhydrophobicity. The current superhydrophobic materials tolerate rigorous environment, opening a new avenue to a variety of practical applications.

  7. Fabrication of recyclable and durable superhydrophobic materials with wear/corrosion-resistance properties from kaolin and polyvinylchloride

    Energy Technology Data Exchange (ETDEWEB)

    Qu, Mengnan, E-mail: mnanqu@gmail.com; Liu, Shanshan; He, Jinmei, E-mail: jinmhe@gmail.com; Feng, Juan; Yao, Yali; Ma, Xuerui; Hou, Lingang; Liu, Xiangrong

    2017-07-15

    Highlights: • The scraped debris can be recycled and easily reused to fabricate the superhydrophobic materials. • The obtained materials displayed liquid-repellent toward water and several other liquids of daily life. • The superhydrophobic materials can retain excellent chemical stability and mechanical durability after rigorous tests. • This as-prepared material can be regarded as a real superhydrophobic “material”, not just the superhydrophobic “surface”. - Abstract: In this study, mechanically stable and recyclable superhydrophobic materials were prepared from polyvinylchloride (PVC) and kaolin nanoparticles modified by stearic acid using a simple and low-cost drop-coating. The obtained materials displayed liquid-repellent toward water and several other liquids of daily life (such as orange juice, coffee, milk, coca cola and ink). These superhydrophobic materials showed remarkable robustness against sandpaper abrasion, UV-irradiation and ultrasonication test, while retaining its superhydrophobicity even after 60 abrasion cycles loaded of 500 g with sandpaper, 7 days UV-irradiation or 120 min ultrasonication test. The excellent durability against complex conditions was attributed to the hierarchical structure and strong interfacial adhesion of the materials. More significantly, the materials used in the coating could be recycled and reconstructed without losing its superhydrophobicity. The current superhydrophobic materials tolerate rigorous environment, opening a new avenue to a variety of practical applications.

  8. Some Durability Characteristics of Micro Silica and Nano Silica Contained Concrete

    Directory of Open Access Journals (Sweden)

    Mohammed Salah Nasr

    2016-12-01

    Full Text Available This paper aims to investigate the influence of replacement of cement with nano and micro silica admixtures on some durability properties of concrete such as water absorption, chloride content and pH tests. Three replacement ratios (5%,10%,15% of micro silica and four replacement proportions (0.5%,1.5%,3%,5% for nano silica were used in this study. Two exposure conditions were considered for chloride content test: wetting-drying and full immersing exposure in 6% of chloride ions solution, NaCl type. Results showed that mixes of %5 micro silica and 5% nano silica had lower content of chloride (about 0.19% and 0.18% for wetting-drying and full immersing exposure respectively. For water absorption test, all mixes incorporated micro and nano silica, except for %5 micro silica mix, showed lower absorption than control mixes. For pH test, results indicated that the adding of nano and micro silica didn’t affect adversely the alkalinity of concrete.

  9. Synthesis on the durability of composite fiberglass/epoxy resin structures

    International Nuclear Information System (INIS)

    Thevenin, P.

    1997-01-01

    The purpose of this paper is to collect together in a systematic way information and results relating to the durability of composite fiberglass/ epoxy resin structures. First it is a matter of assessing the average level of understanding the long term behaviour of these structures which change under the combined effects of varied mechanical loading and stresses of a physico-chemical type linked to the environment. Looking at phenomena encountered and facts from current analyses, it will then be advisable to specify a methodology which can be applied to industrial piping used in PWR cooling systems for transporting raw water under pressure. In fact assessment of their service life is at present based on long and costly testing (ASTM D 2992 B standard), the appearance of which is inherited from metal piping testing.. Therefore it appears essential to study substitution test procedures, more composite specific and at the same time which can be conducted in reasonable time. For this purpose, by coherently accelerating and combining them in order not to underestimate their effects, ageing tests shall reproduce mechanisms representative of operating conditions. (author)

  10. Durable terrestrial bedrock predicts submarine canyon formation

    Science.gov (United States)

    Smith, Elliot; Finnegan, Noah J.; Mueller, Erich R.; Best, Rebecca J.

    2017-01-01

    Though submarine canyons are first-order topographic features of Earth, the processes responsible for their occurrence remain poorly understood. Potentially analogous studies of terrestrial rivers show that the flux and caliber of transported bedload are significant controls on bedrock incision. Here we hypothesize that coarse sediment load could exert a similar role in the formation of submarine canyons. We conducted a comprehensive empirical analysis of canyon occurrence along the West Coast of the contiguous United States which indicates that submarine canyon occurrence is best predicted by the occurrence of durable crystalline bedrock in adjacent terrestrial catchments. Canyon occurrence is also predicted by the flux of bed sediment to shore from terrestrial streams. Surprisingly, no significant correlation was observed between canyon occurrence and the slope or width of the continental shelf. These findings suggest that canyon incision is promoted by greater yields of durable terrestrial clasts to the shore.

  11. A multi-scale investigation of the mechanical behavior of durable sisal fiber cement composites

    OpenAIRE

    Silva, Flávio de Andrade; Toledo Filho, Romildo D.; Mobasher, Barzin; Chawla, Nikhilesh

    2010-01-01

    Durable sisal fiber cement composites reinforced with long unidirectional aligned fibers were developed and their mechanical behavior was characterized in a multi-scale level. Tensile tests were performed in individual sisal fibers. Weibull statistics were used to quantify the degree of variability in fiber strength at different gage lengths. The fiber-matrix pull-out behavior was evaluated at several curing ages and embedded lengths. The composite's mechanical response was measured under dir...

  12. Performance and Durability of Environmental Barrier Coatings on SiC/SiC Ceramic Matrix Composites

    Science.gov (United States)

    Zhu, Dongming; Harder, Bryan; Bhatt, Ramakrishna

    2016-01-01

    This presentation highlights advanced environmental barrier coating (EBC) and SiC-SiC Ceramic Matrix Composites (CMC) systems for next generation turbine engines. The emphasis will be placed on fundamental coating and CMC property evaluations; and the integrated system performance and degradation mechanisms in simulated laboratory turbine engine testing environments. Long term durability tests in laser rig simulated high heat flux the rmomechanical creep and fatigue loading conditions will also be presented. The results can help improve the future EBC-CMC system designs, validating the advanced EBC-CMC technologies for hot section turbine engine applications.

  13. Durability and service life design of concrete structures. Experiences and the way to prove in The Netherlands

    NARCIS (Netherlands)

    Siemes, A.J.M.; Vrouwenvelder, A.C.W.M.

    2002-01-01

    After the introduction of reinforced concrete it was believed that the material was extremely durable. Soon it was found however, that reinforced concrete could have serious durability problems and that special care should be taken to avoid them. Durability became an issue.

  14. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    Energy Technology Data Exchange (ETDEWEB)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  15. Durability evaluation method on rebar corrosion of reinforced concrete

    International Nuclear Information System (INIS)

    Kitsutaka, Yoshinori

    2013-01-01

    In this paper, method on the durability evaluation in nuclear power plant concrete structures was investigated. In view of the importance of evaluating the degree of deterioration of reinforced concrete structures, relationships should be formulated among the number of years elapsed, t, the amount of action of a deteriorative factor, F, the degree of material deterioration, D, and the performance of the structure, P. Evaluation by PDFt diagrams combining these relationships may be effective. A detailed procedure of durability evaluation for a reinforced concrete structure using PDFt concept is presented for the deterioration of rebar corrosion caused by neutralization and penetration of salinity by referring to the recent papers. (author)

  16. THE RELEVANCE OF ELECTRONIC COMMERCE FOR DURABLE DEVELOPMENT. CHALLENGES FOR ROMANIA

    OpenAIRE

    Assist. Ph.D Student Maruntelu Irina

    2009-01-01

    This article aims to approach the topic of the electronic commerce considering the context of the durable development, without exclusively limiting to the economic dimension of sustainable development. This paper aims to offer a vision on the e-commerce based on an optimistic approach of the reconciliation between economic growth and durable development, but moderate by the current realities (digital divide between countries/regions, economic crisis etc). Furthermore, by identifying some of t...

  17. The effect of composition and thermodynamics on the surface morphology of durable superhydrophobic polymer coatings

    Directory of Open Access Journals (Sweden)

    Nahum T

    2017-02-01

    Full Text Available Tehila Nahum,1 Hanna Dodiuk,2 Samuel Kenig,2 Artee Panwar,1 Carol Barry,1 Joey Mead,1 1Department of Plastics Engineering, University of Massachusetts Lowell, Lowell, MA, USA; 2Department of Polymers and Plastics Engineering, Shenkar College of Engineering Design and Art, Ramat Gan, Israel Abstract: Durable superhydrophobic coatings were synthesized using a system of silica nanoparticles (NPs to provide nanoscale roughness, fluorosilane to give hydrophobic chemistry, and three different polymer binders: urethane acrylate, ethyl 2-cyanoacrylate, and epoxy. Coatings composed of different binders incorporating NPs in various concentrations exhibited different superhydrophobic attributes when applied on polycarbonate (PC and glass substrates and as a function of coating composition. It was found that the substrate surface characteristics and wettability affected the superhydrophobic characteristics of the coatings. Interfacial tension and spreading coefficient parameters (thermodynamics of the coating components were used to predict the localization of the NPs for the different binders’ concentrations. The thermodynamic analysis of the NPs localization was in good agreement with the experimental observations. On the basis of the thermodynamic analysis and the experimental scanning electron microscopy, X-ray photoelectron spectroscopy, profilometry, and atomic force microscopy results, it was concluded that localization of the NPs on the surface was critical to provide the necessary roughness and resulting superhydrophobicity. The durability evaluated by tape testing of the epoxy formulations was the best on both glass and PC. Several coating compositions retained their superhydrophobicity after the tape test. In summary, it was concluded that thermodynamic analysis is a powerful tool to predict the roughness of the coating due to the location of NPs on the surface, and hence can be used in the design of superhydrophobic coatings. Keywords

  18. Développement durable de l'agriculture urbaine

    International Development Research Centre (IDRC) Digital Library (Canada)

    La gestion concertée et durable des filières maraîchères urbaines, Paule Moustier, Michel ..... avec des eaux usées, le plus souvent non traitées : dans quelle mesure cette agriculture peut-elle ...... Le contrôle des performances zootechniques

  19. Durable and Robust Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Hjalmarsson, Per; Knibbe, Ruth; Hauch, Anne

    project had as one of its’ overarching goals to improve durability and robustness of the Danish solid oxide fuel cells. The project focus was on cells and cell components suitable for SOFC operation in the temperature range 600 – 750 °C. The cells developed and/or studied in this project are intended......The solid oxide fuel cell (SOFC) is an attractive technology for the generation of electricity with high efficiency and low emissions. Risø DTU (now DTU Energy Conversion) works closely together with Topsoe Fuel Cell A/S in their effort to bring competitive SOFC systems to the market. This 2-year...... for use within the CHP (Combined Heat and Power) market segment with stationary power plants in the range 1 – 250 kWe in mind. Lowered operation temperature is considered a good way to improve the stack durability since corrosion of the interconnect plates in a stack is lifetime limiting at T > 750 °C...

  20. Enhancing composite durability : using thermal treatments

    Science.gov (United States)

    Jerrold E. Winandy; W. Ramsay Smith

    2007-01-01

    The use of thermal treatments to enhance the moisture resistance and aboveground durability of solid wood materials has been studied for years. Much work was done at the Forest Products Laboratory in the last 15 years on the fundamental process of both short-and long-term exposure to heat on wood materials and its interaction with various treatment chemicals. This work...

  1. Chemical durability of soda-lime-aluminosilicate glass for radioactive waste vitrification

    International Nuclear Information System (INIS)

    Eppler, F.H.; Yim, M.S.

    1998-01-01

    Vitrification has been identified as one of the most viable waste treatment alternatives for nuclear waste disposal. Currently, the most popular glass compositions being selected for vitrification are the borosilicate family of glasses. Another popular type that has been around in glass industry is the soda-lime-silicate variety, which has often been characterized as the least durable and a poor candidate for radioactive waste vitrification. By replacing the boron constituent with a cheaper substitute, such as silica, the cost of vitrification processing can be reduced. At the same time, addition of network intermediates such as Al 2 O 3 to the glass composition increases the environmental durability of the glass. The objective of this study is to examine the ability of the soda-lime-aluminosilicate glass as an alternative vitrification tool for the disposal of radioactive waste and to investigate the sensitivity of product chemical durability to variations in composition

  2. The influence of adherent surface preparation on bond durability

    International Nuclear Information System (INIS)

    Rider, A.N.; Arnott, D.R.; Olsson-Jacques, C.L.

    1999-01-01

    Full text: One of the major factors limiting the use of adhesive bonding is the problem associated with the production of adhesive joints that can maintain their initial strength over long periods of time in hostile environments. It is well known that the adherent surface preparation method is critical to the formation of a durable adhesive bond. Work presented in this paper focuses on the critical aspects of the surface preparation of aluminium employed for the manufacture of aluminium-epoxy joints. The surface preparation procedure examined is currently employed by the RAAF for repairs requiring metal to adhesive bonding. The influence of each step in the surface preparation on the ultimate bond durability performance of the adhesive joint is examined by a combination of methods. Double cantilever wedge style adhesive joints are loaded in mode 1 opening and then exposed to a humid environment. X-ray photoelectron spectroscopy (XPS) and contact angle measurements of the aluminium adherent before bonding provides information about the adherent surface chemistry. XPS is also employed to analyse the surfaces of the bonded specimens post failure to establish the locus of fracture. This approach provides important information regarding the properties influencing bond durability as well as the bond failure mechanisms. A two step bond degradation model was developed to qualitatively describe the observed bond durability performance and fracture data. The first step involves controlled moisture ingress by stress induced microporosity of the adhesive in the interfacial region. The second step determines the locus of fracture through the relative dominance of one of three competitive processes, viz: oxide degradation, polymer desorption, or polymer degradation. A key element of the model is the control exercised over the interfacial microporosity by the combined interaction of stress and the relative densities of strong and weak linkages at the metal to adhesive interface

  3. Research notes : durability of composite repairs on bridges.

    Science.gov (United States)

    2009-08-01

    The research showed that conditions that allow moisture to get under the carbon fiber reinforced polymer composites (CFRP) combined with freeze-thaw were detrimental to durability. In addition, the results showed that the American Concrete Institute ...

  4. Some Durability Aspects of Ambient Cured Bottom Ash Geopolymer Concrete

    Directory of Open Access Journals (Sweden)

    Saravanakumar R.

    2017-09-01

    Full Text Available The present study examines some durability aspects of ambient cured bottom ash geopolymer concrete (BA GPC due to accelerated corrosion, sorptivity, and water absorption. The bottom ash geopolymer concrete was prepared with sodium based alkaline activators under ambient curing temperatures. The sodium hydroxide used concentration was 8M. The performance of BA GPC was compared with conventional concrete. The test results indicate that BA GPC developes a strong passive layer against chloride ion diffusion and provides better protection against corrosion. Both the initial and final rates of water absorption of BA GPC were about two times less than those of conventional concrete. The BA GPC significantly enhanced performance over equivalent grade conventional concrete (CC.

  5. FAA/NASA International Symposium on Advanced Structural Integrity Methods for Airframe Durability and Damage Tolerance, part 2

    Energy Technology Data Exchange (ETDEWEB)

    Harris, C.E.

    1994-09-01

    The international technical experts in the areas of durability and damage tolerance of metallic airframe structures were assembled to present and discuss recent research findings and the development of advanced design and analysis methods, structural concepts, and advanced materials. The principal focus of the symposium was on the dissemination of new knowledge and the peer-review of progress on the development of advanced methodologies. Papers were presented on the following topics: structural concepts for enhanced durability, damage tolerance, and maintainability; new metallic alloys and processing technology; fatigue crack initiation and small crack effects; fatigue crack growth models; fracture mechanics failure criteria for ductile materials; structural mechanics methodology for residual strength and life prediction; development of flight load spectra for design and testing; and corrosion resistance. Separate articles from this report have been indexed into the database.

  6. An Experimental Study on Strength and Durability for Utilization of Fly Ash in Concrete Mix

    Directory of Open Access Journals (Sweden)

    Abdulhalim Karaşin

    2014-01-01

    Full Text Available The intention of this study is to discuss the variation of concrete exposed to high sulfate environment of a specific region with respect to strength and durability. Secondly, it is aimed to discuss the possibility of reducing the cement amount in construction of concrete structures. For this purpose, laboratory tests were conducted to investigate compressive strength and sulfate resisting capacity of concrete by using 20% fly ash as mineral additives, waste materials, instead of cement. As a case study the soil samples, received from Siirt Province areas which contain high sulfate rate, have been compared with respect to sulfate standard parameters of TS 12457-4. In such regions contact of underground water seep into hardened concrete substructures poses a risk of concrete deterioration. In order to determine the variation of strength and durability for concrete exposed to such aggressive environment, the samples were rested in a solution of Na2SO4 (150 g/lt in accordance with ASTM C 1012 for the tests. As a result of this experimental study, it is noted that the use of 20% fly ash, replacement material instead of cement, has no significant effect on compressive strength of concrete over time.

  7. Durability of thin-walled concrete structures

    International Nuclear Information System (INIS)

    Salomon, M.; Gallias, J.L.

    1991-01-01

    The aim of the present document is to draw up a survey of knowledge of the problems of ageing of reinforced concrete shell structure atmospheric coolers. The exposure conditions are particularly favourable to the induction and development of degradation which, because of the thinness of the reinforced concrete can compromise the stability and the durability of coolers. The study will be axed on the link between the specific characteristics of coolers from the point of view of operation, design and environment, also the durability of reinforced concrete. The set of factors exerting their influence on the reinforced concrete of the shell structure (condensates, rain water, temperature and humidity gradients, dynamic loads, weathering, etc.) is particularly complex. The principal degradation reactions involved are classified according to the chemical and physical action on concrete and on the reinforcement. Particular emphasis is placed on the analysis of degradation processes and the influence of the characteristics of the materials and of the medium. The aim is to determine the mechanisms which present the greatest risk for coolers. The interaction between the degradation to concrete and the change in mechanical characteristics is also studied [fr

  8. Old materials and techniques to improve the durability of earth buildings

    OpenAIRE

    Camões, Aires; Eires, R.; Jalali, Said

    2012-01-01

    Quite a big part of the world’s heritage is still made by earth constructions. The durability of the existent heritage, as well as the new earth buildings is particularly conditioned by erosion caused by water action, especially in countries with high rainfall index. With this research one intends to value the ancient knowledge in order to allow higher durability. Analysing the old building techniques to protect the earth material from the water action it is possible to understand how ear...

  9. Reliability algorithms applied to reinforced concrete structures durability assessment

    Directory of Open Access Journals (Sweden)

    C. G. Nogueira

    Full Text Available This paper addresses the analysis of probabilistic corrosion time initiation in reinforced concrete structures exposed to ions chloride penetration. Structural durability is an important criterion which must be evaluated in every type of structure, especially when these structures are constructed in aggressive atmospheres. Considering reinforced concrete members, chloride diffusion process is widely used to evaluate the durability. Therefore, at modelling this phenomenon, corrosion of reinforcements can be better estimated and prevented. These processes begin when a threshold level of chlorides concentration is reached at the steel bars of reinforcements. Despite the robustness of several models proposed in the literature, deterministic approaches fail to predict accurately the corrosion time initiation due to the inherently randomness observed in this process. In this regard, the durability can be more realistically represented using probabilistic approaches. A probabilistic analysis of ions chloride penetration is presented in this paper. The ions chloride penetration is simulated using the Fick's second law of diffusion. This law represents the chloride diffusion process, considering time dependent effects. The probability of failure is calculated using Monte Carlo simulation and the First Order Reliability Method (FORM with a direct coupling approach. Some examples are considered in order to study these phenomena and a simplified method is proposed to determine optimal values for concrete cover.

  10. Improved dental implant drill durability and performance using heat and wear resistant protective coatings.

    Science.gov (United States)

    Er, Nilay; Alkan, Alper; İlday, Serim; Bengu, Erman

    2018-03-02

    Dental implant drilling procedure is an essential step for implant surgery and frictional heat appeared in bone during drilling is a key factor affecting the success of an implant. The aim of this study is to increase the dental implant drill lifetime and performance using heat- and wear-resistant protective coatings hence to decrease the alveolar bone temperature caused by the dental implant drilling procedure. Commercially obtained stainless steel drills were coated with titanium aluminum nitride, diamond-like carbon, titanium boron nitride, and boron nitride coatings via magnetron-sputter deposition. Drilling procedure was performed on a bovine femoral cortical bone under the conditions mimicking clinical practice, where the tests were performed both under water-assisted cooling and under the conditions without any cooling was applied. Coated drill performances and durabilities were compared to that of three commonly used commercial drills which surfaces are made from namely; zirconia, black diamond and stainless steel. Protective coatings with boron nitride, titanium boron nitride and diamond-like carbon have significantly improved drill performance and durability. Especially boron nitride-coated drills have performed within safe bone temperature limits for 50 drillings even without any cooling is applied. Titanium aluminium nitride coated drills did not show any improvement over commercially obtained stainless steel drills. Surface modification using heat and wear resistant coatings is an easy and highly effective way to improve implant drill performance and durability, which can reflect positively on surgical procedure and healing period afterwards. The noteworthy success of different types of coatings is novel and likely to be applicable to various other medical systems.

  11. OPTIONS D'INTENSIFICATION DURABLE DES CULTURES ...

    African Journals Online (AJOL)

    (Received 14 August, 2001 ; accepted 10 May, 2002) RÉSUMÉ Pour intensifier de manière durable les cultures vivrières dans les zones de terres de barre dégradées au sud du Togo, plusieurs options ont été évaluées avec les paysans. Grâce à des entretiens collectifs de type participatif, sept différents groupes ...

  12. The durability of waveguide fibers at cyclic change of loading, temperature and humidity

    International Nuclear Information System (INIS)

    Karimov, S.N.; Sultonov, U.; Shamsidinov, M.I.

    1992-01-01

    Present article is devoted to durability of waveguide fibers at cyclic change of loading, temperature and humidity. The mounting scheme and loading of sample is presented. The dependence of glass fiber durability on number of thermal cycles at various humidity rates was considered. The dependence of number of cycles on maximal loading at cyclic temperature change was studied.

  13. The Effect of Thermooxidative Aging on the Durability of Glass Fiber-Reinforced Epoxy

    Directory of Open Access Journals (Sweden)

    Amin Khajeh

    2015-01-01

    Full Text Available Thin-skinned organic matrix composites within aeronautical structures are subjected to thermooxidative aging during their service life, leading to reductions in their durability. In this paper, a durability evaluation of fiberglass epoxy prepreg is performed on the original composite thickness before and after 800 h isothermal aging at 82°C. The characterization of both aged and unaged composites comprised tensile tests, DMA, FTIR, weight loss measurements, SEM, and DSC. The tensile strength and modulus of the composites increased after being exposed to pronounced aging conditions, whereas a decrease was observed in the toughness. DMA results revealed that the glass transition temperature and rubbery state modulus increased as a result of the thermooxidative aging. FTIR spectroscopy demonstrated the formation of carbonyl compounds due to oxidation of the chemical structure of the resin. SEM observations indicated the existence of minor superficial cracking and poor fiber-matrix adhesion after aging. In addition, a minor mass change was observed from mass loss monitoring methods. The overall findings suggest that postcuring and physical aging enhanced the brittleness of the resin, leading to a significant decline in the useful structural life of the thin-skinned composite.

  14. Durability postproduction of three species of Kalanchoe (Crassulaceae in vessels with different substrates

    Directory of Open Access Journals (Sweden)

    Antonio Anderson de Jesus Rodrigues

    2015-04-01

    Full Text Available Potted plants have wide appeal among ornamental plants and one of the most produced for the market belong to the genus Kalanchoe. One aspect to be observed in potted plants is their durability post-production when maintained in indoors conditions as offices and homes. This study aimed to evaluate the durability of the pot post-production life of three species of Kalanchoe (K. marmorata, K. thyrsiflora and K. tubiflora on different substrates. The experiment was arranged in a completely randomized design with 40 replicates per treatment in factorial 3 x 2 (three species of Kalanchoe x two substrates - washed sand and coconut fiber. After 30 days, it was evaluated the general aspects as changes in color, leaf abscission and shading of the stem apex. It was found significant differences between species and also between the substrates tested, but only in relation to the general aspects. The species Kalanchoe marmorata and K. tubiflora stood out by receiving top grades in most of the evaluated characteristics. The best substrate that provided plants the maintenance of the most of their ornamental characteristics over the 30 days was the coconut fiber.

  15. Ga-Doped Pt-Ni Octahedral Nanoparticles as a Highly Active and Durable Electrocatalyst for Oxygen Reduction Reaction.

    Science.gov (United States)

    Lim, JeongHoon; Shin, Hyeyoung; Kim, MinJoong; Lee, Hoin; Lee, Kug-Seung; Kwon, YongKeun; Song, DongHoon; Oh, SeKwon; Kim, Hyungjun; Cho, EunAe

    2018-04-11

    Bimetallic PtNi nanoparticles have been considered as a promising electrocatalyst for oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cells (PEMFCs) owing to their high catalytic activity. However, under typical fuel cell operating conditions, Ni atoms easily dissolve into the electrolyte, resulting in degradation of the catalyst and the membrane-electrode assembly (MEA). Here, we report gallium-doped PtNi octahedral nanoparticles on a carbon support (Ga-PtNi/C). The Ga-PtNi/C shows high ORR activity, marking an 11.7-fold improvement in the mass activity (1.24 A mg Pt -1 ) and a 17.3-fold improvement in the specific activity (2.53 mA cm -2 ) compared to the commercial Pt/C (0.106 A mg Pt -1 and 0.146 mA cm -2 ). Density functional theory calculations demonstrate that addition of Ga to octahedral PtNi can cause an increase in the oxygen intermediate binding energy, leading to the enhanced catalytic activity toward ORR. In a voltage-cycling test, the Ga-PtNi/C exhibits superior stability to PtNi/C and the commercial Pt/C, maintaining the initial Ni concentration and octahedral shape of the nanoparticles. Single cell using the Ga-PtNi/C exhibits higher initial performance and durability than those using the PtNi/C and the commercial Pt/C. The majority of the Ga-PtNi nanoparticles well maintain the octahedral shape without agglomeration after the single cell durability test (30,000 cycles). This work demonstrates that the octahedral Ga-PtNi/C can be utilized as a highly active and durable ORR catalyst in practical fuel cell applications.

  16. Robust superhydrophobic tungsten oxide coatings with photochromism and UV durability properties

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, Ting [Hubei Collaborative Innovation Centre for Advanced Organic Chemical Materials and Ministry-of-Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei University, Wuhan, 430062 (China); State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000 (China); Guo, Zhiguang, E-mail: zguo@licp.cas.cn [Hubei Collaborative Innovation Centre for Advanced Organic Chemical Materials and Ministry-of-Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei University, Wuhan, 430062 (China); State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000 (China)

    2016-11-30

    Highlights: • Superhydrophobic tungsten oxide (TO) coatings with a water contact angle (WCA) of 155° and rolling angle of 3.5° were developed. • The superhydrophobic coatings have excellent mechanical robustness and UV durability. • The superhydrophobic TO coatings show the reversible convert of photochromism. • The coating exhibited excellent self-cleaning behavior due to its high WCA and low rolling angle. - Abstract: Robust superhydrophobic tungsten oxide (TO) coatings with a water contact angle (WCA) of 155° were developed for photochromism via a facile and substrate-independent route. Importantly, after scatch test on both a single and two orthogonal direction, the TO coating still exhibited superhydrophobic behavior, indicating excellent mechanical robustness. It is worth mentioning that the superhydrophobic TO coatings showed the reversible convert of photochromism of WO{sub 3} induced by alternating UV and visible light irradiation. Besides that, the TO coating remained superhydrophobicity after UV irradiation for 36 h, showing excellent UV durability. In addition, the coating showed good resistance to acidic droplets. Moreover, it can also be applied on other substrates, such as copper mesh, steel, paper and fiber. The coating exhibited excellent self-cleaning behavior due to its high WCA and low rolling angle. Overall, this work is a promising approach to design and produce functional superhydrophobic coatings for various substrates.

  17. Am/Cm target glass durability dependence on pH (U). Revision 1

    International Nuclear Information System (INIS)

    Daniel, W.E.; Best, D.R.

    1996-03-01

    At the Westinghouse Savannah River Company near Aiken, South Carolina, a process is being developed to safely vitrify all of the highly radioactive americium/curium (Am/Cm) material and a portion of the other fissile actinide materials stored on site. One goal of this campaign is to provide Oak Ridge National Laboratory with the excess Am/Cm so it can be recycled as opposed to simply disposing of it as waste. The vitrification will allow safe transportation of the Am/Cm to Oak Ridge as well as safe storage once it arrives. The Am/Cm Target glass being used in this project has been specifically designed to be extremely durable in aqueous environments while it can be selectively attacked by nitric acid to recover the valuable Am and Cm isotopes. Similar glass compositions could be used for storage and retrieval of other actinides on the WSRC site. Previous reports have presented the time, temperature, and compositional dependence of the Am/Cm glass durability. This paper will show results from a pH study on the Am/Cm Target glass durability. The data indicate that the Am/Cm Target Glass durability decreases as pH decreases from a neutral reading. These findings support the extraction of the valuable isotopes from the glass using nitric acid

  18. Effect of nanoclay on durability and mechanical properties of flax fabric reinforced geopolymer composites

    Directory of Open Access Journals (Sweden)

    H. Assaedi

    2017-03-01

    Full Text Available The main concern of using natural fibres as reinforcement in geopolymer composites is the durability of the fibres. Geopolymers are alkaline in nature because of the alkaline solution that is required for activating the geopolymer reaction. The alkalinity of the matrix, however, is the key reason of the degradation of natural fibres. The purpose of this study is to determine the effect of nanoclay (NC loading on the mechanical properties and durability of flax fabric (FF reinforced geopolymer composites. The durability of composites after 4 and 32 weeks at ambient temperature is presented. The microstructure of geopolymer matrices was investigated using X-ray diffraction (XRD, Fourier transform infrared spectroscopy (FTIR and scanning electron microscopy (SEM. The results showed that the incorporation of NC has a positive impact on the physical properties, mechanical performance, and durability of FF reinforced geopolymer composites. The presence of NC has a positive impact through accelerating the geopolymerization, reducing the alkalinity of the system and increasing the geopolymer gel.

  19. Effects of heat treatment and formulation on the phase composition and chemical durability of the EBR-II ceramic waste form

    International Nuclear Information System (INIS)

    Ebert, W. E.; Dietz, N. L.; Janney, D. E.

    2006-01-01

    High-level radioactive waste salts generated during the electrometallurgical treatment of spent sodium-bonded nuclear fuel from the Experimental Breeder Reactor-II will be immobilized in a ceramic waste form (CWF). Tests are being conducted to evaluate the suitability of the CWF for disposal in the planned federal high-level radioactive waste repository at Yucca Mountain. In this report, the results of laboratory tests and analyses conducted to address product consistency and thermal stability issues called out in waste acceptance requirements are presented. The tests measure the impacts of (1) variations in the amounts of salt and binder glass used to make the CWF and (2) heat treatments on the phase composition and chemical durability of the waste form. A series of CWF materials was made to span the ranges of salt and glass contents that could be used during processing: between 5.0 and 15 mass% salt loaded into the zeolite (the nominal salt loading is 10.7%, and the process control range is 10.6 to 11.2 mass%), and between 20 and 30 mass% binder glass mixed with the salt-loaded zeolite (the nominal glass content is 25% and the process control range is 20 to 30 mass%). In another series of tests, samples of two CWF products made with the nominal salt and glass contents were reheated to measure the impact on the phase composition and durability: long-term heat treatments were conducted at 400 and 500 C for durations of 1 week, 4 weeks, 3 months, 6 months, and 1 year; short-term heat treatments were conducted at 600, 700, 800, and 850 C for durations of 4, 28, 52, and 100 hours. All of the CWF products that were made with different amounts of salt, zeolite, and glass and all of the heat-treated CWF samples were analyzed with powder X-ray diffraction to measure changes in phase compositions and subjected to 7-day product consistency tests to measure changes in the chemical durability. The salt loading had the greatest impact on phase composition and durability. A

  20. Durable flame retardant and antibacterial finishing on cotton fabrics with cyclotriphosphazene/polydopamine/silver nanoparticles hybrid coatings

    Science.gov (United States)

    Li, Yingzhan; Wang, Bijia; Sui, Xiaofeng; Xie, Ruyi; Xu, Hong; Zhang, Linping; Zhong, Yi; Mao, Zhiping

    2018-03-01

    Durable flame retardant and antibacterial hybrid coatings were developed for cotton fabrics via simultaneous polymerization of dopamine and hydrolytic condensation of N3P3[NH(CH2)3Si(OC2H5)3]6. Silver nanoparticles were also introduced to the coatings by in situ reaction of AgNO3 with catechol moieties on polydopamine (PDA) in the absence of any external reducing agents. Energy dispersive spectrometer (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) were employed to study the morphology and constitution of the coatings. Thermal stability and combustion behaviors were characterized with thermogravimetric analysis (TGA) and vertical flammability tests. Considerable flame retardancy was obtained for the modified cotton fabrics, which also exhibited decent antibacterial activities (99.99%) against Gram-positive bacteria S. aureus and Gram-negative bacteria E. coli. The modification was durable with largely intact flame retardancy and antimicrobial properties after 30 washing cycles.

  1. Experimental research on the durability cutting tools for cutting-off steel profiles

    Directory of Open Access Journals (Sweden)

    Cristea Alexandru

    2017-01-01

    Full Text Available The production lines used for manufacturing U-shaped profiles are very complex and they must have high productivity. One of the most important stages of the fabrication process is the cutting-off. This paper presents the experimental research and analysis of the durability of the cutting tools used for cutting-off U-shaped metal steel profiles. The results of this work can be used to predict the durability of the cutting tools.

  2. An Accelerated Test Method of Simultaneous Carbonation and Chloride Ion Ingress: Durability of Silica Fume Concrete in Severe Environments

    Directory of Open Access Journals (Sweden)

    S. A. Ghahari

    2016-01-01

    Full Text Available The effects of simultaneous carbonation and chloride ion attack on mechanical characteristics and durability of concrete containing silica fume have been investigated through an accelerated test method. Specimens containing different amounts of silica fume were maintained in an apparatus in which carbon dioxide pressure and concentration and relative humidity were kept constant, and wetting and drying cycles in saline water were applied. Surface resistivity, sorptivity, CO2 consumption, and carbonation and chloride ion ingress depths measurements were taken. Phase change due to carbonation and chloride ion attack was monitored by XRD analysis, and microstructures and interfacial transition zones were studied by implementing SEM as well as mercury intrusion porosimetry. It was expected to have a synergistic effect in the tidal zone where simultaneous carbonation and chloride ion attack happen. However, the observed reduced surface resistivity, compared to specimens maintained in CO2 gas, could be due to the moisture that is available near the surface, hindering CO2 from penetrating into the pores of the specimens. Moreover, the porosity analysis of the specimens showed that the sample containing silica fume cured in the tidal zone had 50.1% less total porosity than the plain cement paste cured in the same condition.

  3. Test report : alternative fuels propulsion durability evaluation

    Science.gov (United States)

    2012-08-28

    This document, prepared by Honeywell Aerospace, Phoenix, AZ (Honeywell), contains the final : test report (public version) for the U.S. Department of Transportation/Federal Aviation : Administration (USDOT/FAA) Alternative Fuels Propulsion Engine Dur...

  4. Durable chemical sensors based on field-effect transistors

    NARCIS (Netherlands)

    Reinhoudt, David

    1995-01-01

    The design of durable chemical sensors based on field-effect transistors (FETs) is described. After modification of an ion-sensitive FET (ISFET) with a polysiloxane membrane matrix, it is possible to attach all electroactive components covalently. Preliminary results of measurements with a

  5. Creep and Environmental Durability of EBC/CMCs Under Imposed Thermal Gradient Conditions

    Science.gov (United States)

    Appleby, Matthew; Morscher, Gregory N.; Zhu, Dongming

    2013-01-01

    Interest in SiC fiber-reinforced SiC ceramic matrix composite (CMC) environmental barrier coating (EBC) systems for use in high temperature structural applications has prompted the need for characterization of material strength and creep performance under complex aerospace turbine engine environments. Stress-rupture tests have been performed on SiC/SiC composites systems, with varying fiber types and coating schemes to demonstrate material behavior under isothermal conditions. Further testing was conducted under exposure to thermal stress gradients to determine the effect on creep resistance and material durability. In order to understand the associated damage mechanisms, emphasis is placed on experimental techniques as well as implementation of non-destructive evaluation; including electrical resistivity monitoring. The influence of environmental and loading conditions on life-limiting material properties is shown.

  6. Durability of building stones against artificial salt crystallization

    Science.gov (United States)

    Min, K.; Park, J.; Han, D.

    2005-12-01

    Salts have been known as the most powerful weathering agents, especially when combined with frost action. Salt crystallization test along with freezing-thawing test and acid immersion test was carried out to assess the durability of building stones against weathering. Granite, limestone, marble and basalt were sampled from different quarries in south Korea for this study. One cycle of artificial salt crystallization test was composed of immersion of cored rock specimens in oversaturated solutions of CaCl2, KCl, NaCl and Na2SO4, respectively for 15 hours and successive drying in an oven of 105°C for 3 hours and cooling at room temperature. Tests were performed up to 30 cycles, and specific gravity and ultrasonic velocity were measured after experiencing every 10 cycles and uniaxial compressive strength was measured only after 30 cycles. During the repeated Na2SO4 salt crystallization, some rock samples were gradually deformed excessively and burst after 20 to 30 cycles of test. The variation patterns of physical properties during the salt crystallization tests are too variable to generalize the effect of salt weathering on physical properties but limestone, marble and basalt samples showed relatively greater change of physical properties than granite samples. The recrystallized salts were well observed in the cracks of rock samples through the scanning electron microscope. In the all salt crystallization tests, apparent specific gravities for all tested samples increased generally but not so significantly due to recrystallization of salts. It can be inferred that filling the pores with salt crystals cause the increase of ultrasonic velocity during the early stage of salt crystallization and then in later stages the repeated cycles of salt crystallization result in development of cracks leading decrease of ultrasonic velocity for some rock samples.

  7. Durability of cement and geopolimer composites

    Science.gov (United States)

    Błaszczyński, T.; Król, M.

    2017-10-01

    Concrete structures are constantly moving in the direction of improving the durability. This main feature depends on many factors, which are the composition of concrete mix, the usage of additives and admixtures and the place, where material will work and carry the load. The introduction of new geopolymer binders for geopolymer structures adds a new aspect that is type of used activator. This substance with strongly alkaline reaction is divided because of the physical state, the alkaline degree and above all the chemical composition. Taking into account, that at present the geopolymer binders are made essentially from waste materials or by products from the combustion of coal or iron ore smelting, unambiguous determination of the effect of the activator on the properties of the geopolymer material requires a number of trials, researches and observation. This paper shows the influence of the most alkaline activators on the basic parameters of the durability of geopolymer binders. In this study there were used a highly alkaline hydroxides, water glasses and granules, which are waste materials in a variety of processes taking place in a chemical plants. As the substrate of geopolymer binders there were used fly ash which came from coal and high calcium ash from the burning of lignite.

  8. Advanced Environmental Barrier Coating and SA Tyrannohex SiC Composites Integration for Improved Thermomechanical and Environmental Durability

    Science.gov (United States)

    Zhu, Dongming; Halbig, Michael; Singh, Mrityunjay

    2018-01-01

    The development of 2700 degF capable environmental barrier coating (EBC) systems, particularly, the Rare Earth "Hafnium" Silicon bond coat systems, have significantly improved the temperature capability and environmental stability of SiC/SiC Ceramic Matrix Composite Systems. We have specifically developed the advanced 2700 degF EBC systems, integrating the EBC to the high temperature SA Tyrannohex SiC fiber composites, for comprehensive performance and durability evaluations for potential turbine engine airfoil component applications. The fundamental mechanical properties, environmental stability and thermal gradient cyclic durability performance of the EBC - SA Tyrannohex composites were investigated. The paper will particularly emphasize the high pressure combustion rig recession, cyclic thermal stress resistance and thermomechanical low cycle fatigue testing of uncoated and environmental barrier coated Tyrannohex SiC SA composites in these simulated turbine engine combustion water vapor, thermal gradients, and mechanical loading conditions. We have also investigated high heat flux and flexural fatigue degradation mechanisms, determined the upper limits of operating temperature conditions for the coated SA composite material systems in thermomechanical fatigue conditions. Recent progress has also been made by using the self-healing rare earth-silicon based EBCs, thus enhancing the SA composite hexagonal fiber columns bonding for improved thermomechanical and environmental durability in turbine engine operation environments. More advanced EBC- composite systems based on the new EBC-Fiber Interphases will also be discussed.

  9. Durable and Sustainable Road Constructions for Developing Countries

    NARCIS (Netherlands)

    Molenaar, A.A.A.

    2013-01-01

    This paper discusses the possibilities to build durable and sustainable pavement structures in developing countries. Attention will be paid to geometric design aspects which have a significant effect on pavement life. Following this attention will be paid to the importance of controlling wheel loads

  10. Utilization of Durability Criterion to Develop Automotive Components

    DEFF Research Database (Denmark)

    Ricardo, Luiz Carlos Hernandes

    2010-01-01

    Today the automotive companies must reduce the time to development of new products with improvement in performance, durability and low cost reductions where possible. To achieve this goal the carmakers need to improve the design criterion of car systems like body, chassis and suspension component...

  11. Framework for a procedure for design for durability

    NARCIS (Netherlands)

    Siemes, A.J.M.

    1996-01-01

    The design for durability of structures and building components is in general based on implicit requirements with respect to the quality and dimensions of the composing building materials and components. These requirements are based on long term experience. This approach has disadvantages. It is

  12. Estimating Durability of Reinforced Concrete

    Science.gov (United States)

    Varlamov, A. A.; Shapovalov, E. L.; Gavrilov, V. B.

    2017-11-01

    In this article we propose to use the methods of fracture mechanics to evaluate concrete durability. To evaluate concrete crack resistance characteristics of concrete directly in the structure in order to implement the methods of fracture mechanics, we have developed special methods. Various experimental studies have been carried out to determine the crack resistance characteristics and the concrete modulus of elasticity during its operating. A comparison was carried out for the results obtained with the use of the proposed methods and those obtained with the standard methods for determining the concrete crack resistance characteristics.

  13. Creating durable and esthetic gingival anatomy on a polyoxymethylene overdenture by using a chairside procedure.

    Science.gov (United States)

    Login, Gary R

    2017-07-01

    Snap-On Smile (DenMat) appliances are tooth-borne overdentures used for a variety of temporary esthetic applications. However, their benefit can be limited in patients with high smile lines and altered gingival architecture because the teeth look too large. In this report, the author shows the chairside application of a silicone denture reline material used to recreate gingival anatomy on an overdenture fabricated from crystallized acetyl resin, the material used in a Snap-On Smile appliance. The author shows the gingival application's durability of greater than 2 years in a 78-year-old patient with multiple missing teeth and a severe mandibular ridge deformity. The author tested several commonly available denture reline materials and their bonding agents, which are known to bond to acrylic resin but have not been shown to bond to crystallized acetyl resin. The author observed no candida colonization during the 2-year reporting period. The author presents a simple and durable chairside technique to reproduce gingival tissue esthetically on Snap-On Smile appliances. Copyright © 2017 American Dental Association. Published by Elsevier Inc. All rights reserved.

  14. Enhanced performance and durability of low catalyst loading PEM water electrolyser based on a short-side chain perfluorosulfonic ionomer

    International Nuclear Information System (INIS)

    Siracusano, Stefania; Baglio, Vincenzo; Van Dijk, Nicholas; Merlo, Luca; Aricò, Antonino Salvatore

    2017-01-01

    Graphical abstract: Tripling current density (>3 A·cm"−"2) with respect to the state of the art of commercial PEM electrolyser can be achieved also in the presence of a significant reduction, about 4-fold, of the total noble metal loading (0.5 mg·cm"−"2) while achieving high efficiency (>80%) and proper durability. - Highlights: • Current density >3 A·cm"−"2 is achieved in electrolysis cells with efficiency >80%. • A 4-fold reduction of noble metal loading is demonstrated in electrolysis cells. • Degradation rate <5 μV/h is achieved in a 1000 h durability test at 1 A·cm"−"2. • Degradation associated to a change in Lewis acidity characteristics is observed. - Abstract: Water electrolysis supplied by renewable energy is the foremost technology for producing “green” hydrogen for fuel cell vehicles. In addition, the ability to rapidly follow an intermittent load makes electrolysis an ideal solution for grid-balancing caused by differences in supply and demand for energy generation and consumption. Membrane-electrode assemblies (MEAs) designed for polymer electrolyte membrane (PEM) water electrolysis, based on a novel short-side chain (SSC) perfluorosulfonic acid (PFSA) membrane, Aquivion®, with various cathode and anode noble metal loadings, were investigated in terms of both performance and durability. Utilizing a nanosized Ir_0_._7Ru_0_._3O_x solid solution anode catalyst and a supported Pt/C cathode catalyst, in combination with the Aquivion® membrane, gave excellent electrolysis performances exceeding 3.2 A·cm"−"2 at 1.8 V terminal cell voltage (∼80% efficiency) at 90 °C in the presence of a total catalyst loading of 1.6 mg⋅cm"−"2. A very small loss of efficiency, corresponding to 30 mV voltage increase, was recorded at 3 A⋅cm"−"2 using a total noble metal catalyst loading of less than 0.5 mg·cm"−"2 (compared to the industry standard of 2 mg·cm"−"2). Steady-state durability tests, carried out for 1000 h at 1 A

  15. THE STUDY ON THE DURABILITY OF SUBMERGED STRUCTURE DISPLACEMENT DUE TO CONCRETE FAILURE

    Directory of Open Access Journals (Sweden)

    M. Mohd

    2016-09-01

    Full Text Available Concrete structures that exposed to marine environments are subjected to multiple deterioration mechanisms. An overview of the existing technology for submerged concrete, pressure resistant, concrete structures which related such as cracks, debonds, and delamination are discussed. Basic knowledge related to drowning durability such as submerged concrete structures in the maritime environment are the durability of a concrete and the ability to resist to weathering, chemical attack, abrasion or other deterioration processes. The measuring techniques and instrumentation for geometrical monitoring of submerged structural displacements have traditionally been categorized into two groups according to the two main groups, namely as geodetic surveying and geotechnical structural measurements of local displacements. This paper aims to study the durability of submerged concrete displacement and harmful effects of submerged concrete structures.

  16. Influence of Etching Mode on Enamel Bond Durability of Universal Adhesive Systems.

    Science.gov (United States)

    Suzuki, T; Takamizawa, T; Barkmeier, W W; Tsujimoto, A; Endo, H; Erickson, R L; Latta, M A; Miyazaki, M

    2016-01-01

    The purpose of this study was to determine the enamel bond durability of three universal adhesives in different etching modes through fatigue testing. The three universal adhesives used were Scotchbond Universal, Prime&Bond Elect universal dental adhesive, and All-Bond Universal light-cured dental adhesive. A single-step self-etch adhesive, Clearfil S 3 Bond Plus was used as a control. The shear bond strength (SBS) and shear fatigue strength (SFS) to human enamel were evaluated in total-etch mode and self-etch mode. A stainless steel metal ring with an internal diameter of 2.4 mm was used to bond the resin composite to the flat-ground (4000-grit) tooth surfaces for determination of both SBS and SFS. For each enamel surface treatment, 15 specimens were prepared for SBS and 30 specimens for SFS. The staircase method for fatigue testing was then used to determine the SFS of the resin composite bonded to the enamel using 10-Hz frequencies for 50,000 cycles or until failure occurred. Scanning electron microscopy was used to observe representative debonded specimen surfaces and the resin-enamel interfaces. A two-way analysis of variance and the Tukey post hoc test were used for analysis of the SBS data, whereas a modified t-test with Bonferroni correction was used for the SFS data. All adhesives in total-etch mode showed significantly higher SBS and SFS values than those in self-etch mode. Although All-Bond Universal in self-etch mode showed a significantly lower SBS value than the other adhesives, there was no significant difference in SFS values among the adhesives in this mode. All adhesives showed higher SFS:SBS ratios in total-etch mode than in self-etch mode. With regard to the adhesive systems used in this study, universal adhesives showed higher enamel bond strengths in total-etch mode. Although the influence of different etching modes on the enamel-bonding performance of universal adhesives was found to be dependent on the adhesive material, total-etch mode

  17. Development of a CB Resistant Durable, Flexible Hydration System

    National Research Council Canada - National Science Library

    Hall, Peyton W; Zeller, Frank T; Bulluck, John W; Dingus, Michael L

    2002-01-01

    A durable, flexible hydration system resistant to contamination by contact with VX, GD, and HD chemical agents, as well as damage by the decontaminants sodium hypochlorite and DS-2 is being developed for aviator use...

  18. Enhancing durability of wood-based composites with nanotechnology

    Science.gov (United States)

    Carol Clausen

    2012-01-01

    Wood protection systems are needed for engineered composite products that are susceptible to moisture and biodeterioration. Protection systems using nano-materials are being developed to enhance the durability of wood-based composites through improved resistance to biodeterioration, reduced environmental impact from chemical leaching, and improved resistance to...

  19. Durability of anti-graffiti coatings on stone: natural vs accelerated weathering.

    Science.gov (United States)

    Carmona-Quiroga, Paula M; Jacobs, Robert M J; Martínez-Ramírez, Sagrario; Viles, Heather A

    2017-01-01

    Extending the use of novel anti-graffiti coatings to built heritage could be of particular interest providing the treatments are efficient enough in facilitating graffiti removal and long-lasting to maintain their protective properties without interfering with the durability of the substrates. However, studies of the durability of these coatings are scarce and have been mainly carried out under accelerated weathering conditions, the most common practice for assessing the durability of materials but one that does not reproduce accurately natural working conditions. The present study aimed to assess the durability of the anti-graffiti protection afforded by two anti-graffiti treatments (a water dispersion of polyurethane with a perfluoropolyether backbone and a water based crystalline micro wax) on Portland limestone and Woodkirk sandstone after 1 year of outdoor exposure in the South of England with periodic painting and cleaning episodes taking place. A parallel study under artificial weathering conditions in a QUV chamber for 2000 hours was also carried out. Changes to the coatings were assessed by measuring colour, gloss, water-repellency, roughness and microstructure, the latter through micro-Raman and optical microscope observations, periodically during the experiments. The results show that both anti-graffiti treatments deteriorated under both artificial and natural weathering conditions. For the polyurethane based anti-graffiti treatment, artificial ageing produced more deterioration than 1 year of outdoor exposure in the south of England due to loss of adhesion from the stones, whereas for micro wax coating there were no substantial differences between the two types of weathering.

  20. Durability of anti-graffiti coatings on stone: natural vs accelerated weathering.

    Directory of Open Access Journals (Sweden)

    Paula M Carmona-Quiroga

    Full Text Available Extending the use of novel anti-graffiti coatings to built heritage could be of particular interest providing the treatments are efficient enough in facilitating graffiti removal and long-lasting to maintain their protective properties without interfering with the durability of the substrates. However, studies of the durability of these coatings are scarce and have been mainly carried out under accelerated weathering conditions, the most common practice for assessing the durability of materials but one that does not reproduce accurately natural working conditions. The present study aimed to assess the durability of the anti-graffiti protection afforded by two anti-graffiti treatments (a water dispersion of polyurethane with a perfluoropolyether backbone and a water based crystalline micro wax on Portland limestone and Woodkirk sandstone after 1 year of outdoor exposure in the South of England with periodic painting and cleaning episodes taking place. A parallel study under artificial weathering conditions in a QUV chamber for 2000 hours was also carried out. Changes to the coatings were assessed by measuring colour, gloss, water-repellency, roughness and microstructure, the latter through micro-Raman and optical microscope observations, periodically during the experiments. The results show that both anti-graffiti treatments deteriorated under both artificial and natural weathering conditions. For the polyurethane based anti-graffiti treatment, artificial ageing produced more deterioration than 1 year of outdoor exposure in the south of England due to loss of adhesion from the stones, whereas for micro wax coating there were no substantial differences between the two types of weathering.

  1. Engine rotor health monitoring: an experimental approach to fault detection and durability assessment

    Science.gov (United States)

    Abdul-Aziz, Ali; Woike, Mark R.; Clem, Michelle; Baaklini, George

    2015-03-01

    Efforts to update and improve turbine engine components in meeting flights safety and durability requirements are commitments that engine manufacturers try to continuously fulfill. Most of their concerns and developments energies focus on the rotating components as rotor disks. These components typically undergo rigorous operating conditions and are subject to high centrifugal loadings which subject them to various failure mechanisms. Thus, developing highly advanced health monitoring technology to screen their efficacy and performance is very essential to their prolonged service life and operational success. Nondestructive evaluation techniques are among the many screening methods that presently are being used to pre-detect hidden flaws and mini cracks prior to any appalling events occurrence. Most of these methods or procedures are confined to evaluating material's discontinuities and other defects that have mature to a point where failure is eminent. Hence, development of more robust techniques to pre-predict faults prior to any catastrophic events in these components is highly vital. This paper is focused on presenting research activities covering the ongoing research efforts at NASA Glenn Research Center (GRC) rotor dynamics laboratory in support of developing a fault detection system for key critical turbine engine components. Data obtained from spin test experiments of a rotor disk that relates to investigating behavior of blade tip clearance, tip timing and shaft displacement based on measured data acquired from sensor devices such as eddy current, capacitive and microwave are presented. Additional results linking test data with finite element modeling to characterize the structural durability of a cracked rotor as it relays to the experimental tests and findings is also presented. An obvious difference in the vibration response is shown between the notched and the baseline no notch rotor disk indicating the presence of some type of irregularity.

  2. Possibilities of testing capillary absorption on microcores

    Directory of Open Access Journals (Sweden)

    Čeh Arpad

    2016-01-01

    Full Text Available During inspection of reinforced concrete structures from the aspect of durability evaluation of concrete, the present methods generally use the test results obtained by the sophisticated and expensive equipment, which are usually not universal purpose, ie. they can be used only for one segment of durability evaluation of the concrete. This way any additional information about the condition of concrete is valuable, especially if it is not require an additional testing with special equipment. Tests of concrete and reinforced concrete with microcore drilling is considered to be a semi- destructive method, which slightly damages the structure itself, and it is primarily used for testing carbonation, density and absorption of concrete. The paper presents the results of capillary absorption according to SRPS EN 480-5 on standard-size samples and on the microcores extracted from cube form samples with edge length of 20 cm. In the article the testing results of penetration of water under pressure are also presented on the same samples, on which we previously gained microcores. These tests were carried out on with concrete mixtures designed for the most demanding exposure classes according to EN 206-1 and using a variety of additives that are known to affect the structure of pores and consequently also the durability of a hardened concrete.

  3. Will It Every Fly? Modeling the Takeoff of Really New Consumer Durables

    OpenAIRE

    Peter N. Golder; Gerard J. Tellis

    1997-01-01

    A consistent pattern observed for really new household consumer durables is a takeoff or dramatic increase in sales early in their history. The takeoff tends to appear as an elbow-shaped discontinuity in the sales curve showing an average sales increase of over 400%. In contrast, most marketing textbooks as well as diffusion models generally depict the growth of new consumer durables as a smooth sales curve. Our discussions with managers indicate that they have little idea about the takeoff a...

  4. Research report for fiscal 1995 on analysis and evaluation of demonstration tests for establishment of residential photovoltaic power generation load leveling technology. Evaluation on durability of device installed with inverter to protect grid connection; 1995 nendo kenkyu hokokusho. Jutaku you taiyoko hatsuden fuka heijunka gijutsu tou kakuritsu jissho shiken ni kansuru kaiseki hyoka - Inbata tsuki keito renkei hogo sochi no taikyusei hyoka

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Discussions and evaluations have been performed on the safety and durability of the device installed with inverter to protect grid connection being an important device in the photovoltaic power generation system. In discussing the durability test items, electrical property changes were observed on AC overvoltage, AC undervoltage, frequency rise, and frequency fall, as the continuation from the previous fiscal year, in order to evaluate temperature rise in different parts due to lapse of operation time and the effects of thermal stress in each component on the stress of the entire product. Furthermore, verification of single operation detecting function, tests on sudden input power change, sudden grid voltage change, and measurement of conductive high frequency terminal voltage were conducted in addition to the above observations. In discussing the durability test methods, repetition of operation and shutdown during the rated operation was adopted in place of the simulated operation using variation in the insolation having been discussed in the previous year. As a result of the tests, no noticeable changes were recognized from the evaluation result after a lapse of 5,000 hours from the start of the operation, as compared to those after the aging operation. (NEDO)

  5. Aligned carbon nanotube based ultrasonic microtransducers for durability monitoring in civil engineering.

    Science.gov (United States)

    Lebental, B; Chainais, P; Chenevier, P; Chevalier, N; Delevoye, E; Fabbri, J-M; Nicoletti, S; Renaux, P; Ghis, A

    2011-09-30

    Structural health monitoring of porous materials such as concrete is becoming a major component in our resource-limited economy, as it conditions durable exploitation of existing facilities. Durability in porous materials depends on nanoscale features which need to be monitored in situ with nanometric resolution. To address this problem, we put forward an approach based on the development of a new nanosensor, namely a capacitive micrometric ultrasonic transducer whose vibrating membrane is made of aligned single-walled carbon nanotubes (SWNT). Such sensors are meant to be embedded in large numbers within a porous material in order to provide information on its durability by monitoring in situ neighboring individual micropores. In the present paper, we report on the feasibility of the key building block of the proposed sensor: we have fabricated well-aligned, ultra-thin, dense SWNT membranes that show above-nanometer amplitudes of vibration over a large range of frequencies spanning from 100 kHz to 5 MHz.

  6. Amenagements sportifs et developpement durable : Des enjeux ...

    African Journals Online (AJOL)

    ... contredite » éprouvée par (Jeu, 1977), comme l'apanage d'une double hybridation culturelle des pays en développement. Derrière l'apparence de la dislocation des héritages, doit émerger une définition nouvelle sur les rapports que les sports devraient entretenir avec l'environnement pour un développement durable.

  7. Novel Arrangements for High Performance and Durable Dielectric Elastomer Actuation

    Directory of Open Access Journals (Sweden)

    Runan Zhang

    2016-07-01

    Full Text Available This paper advances the design of Rod Pre-strained Dielectric Elastomer Actuators (RP-DEAs in their capability to generate comparatively large static actuation forces with increased lifetime via optimized electrode arrangements. RP-DEAs utilize thin stiff rods to constrain the expansion of the elastomer and maintain the in-plane pre-strain in the rod longitudinal direction. The aim is to study both the force output and the durability of the RP-DEA. Initial design of the RP-DEA had poor durability, however, it generated significantly larger force compared with the conventional DEA due to the effects of pre-strain and rod constraints. The durability study identifies the in-electro-active-region (in-AR lead contact and the non-uniform deformation of the structure as causes of pre-mature failure of the RP-DEA. An optimized AR configuration is proposed to avoid actuating undesired areas in the structure. The results show that with the optimized AR, the RP-DEA can be effectively stabilized and survive operation at least four times longer than with a conventional electrode arrangement. Finally, a Finite Element simulation was also performed to demonstrate that such AR design and optimization can be guided by analyzing the DEA structure in the state of pre-activation.

  8. Use of recycled fine aggregate in concretes with durable requirements.

    Science.gov (United States)

    Zega, Claudio Javier; Di Maio, Angel Antonio

    2011-11-01

    The use of construction waste materials as aggregates for concrete production is highly attractive compared to the use of non-renewable natural resources, promoting environmental protection and allowing the development of a new raw material. Several countries have recommendations for the use of recycled coarse aggregate in structural concrete, whereas the use of the fine fraction is limited because it may produce significant changes in some properties of concrete. However, during the last decade the use of recycled fine aggregates (RFA) has achieved a great international interest, mainly because of economic implications related to the shortage of natural sands suitable for the production of concrete, besides to allow an integral use of this type of waste. In this study, the durable behaviour of structural concretes made with different percentage of RFA (0%, 20%, and 30%) is evaluated. Different properties related to the durability of concretes such as absorption, sorptivity, water penetration under pressure, and carbonation are determined. In addition, the results of compressive strength, static modulus of elasticity and drying shrinkage are presented. The obtained results indicate that the recycled concretes have a suitable resistant and durable behaviour, according to the limits indicated by different international codes for structural concrete. Copyright © 2011 Elsevier Ltd. All rights reserved.

  9. Sports, genre et developpement durable : l'heritage d'une ...

    African Journals Online (AJOL)

    Sports, genre et developpement durable : l'heritage d'une distribution ... to new populations in situation of confrontation with the difference that Goffman (1975) ... and women (gender), maintain the sports field and behind the appearance of a ...

  10. E-Area Vault Concrete Material Property And Vault Durability/Degradation Projection Recommendations

    Energy Technology Data Exchange (ETDEWEB)

    Phifer, M. A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2014-03-11

    Subsequent to the 2008 E-Area Low-Level Waste Facility (ELLWF) Performance Assessment (PA) (WSRC 2008), two additional E-Area vault concrete property testing programs have been conducted (Dixon and Phifer 2010 and SIMCO 2011a) and two additional E-Area vault concrete durability modeling projections have been made (Langton 2009 and SIMCO 2012). All the information/data from these reports has been evaluated and consolidated herein by the Savannah River National Laboratory (SRNL) at the request of Solid Waste Management (SWM) to produce E-Area vault concrete hydraulic and physical property data and vault durability/degradation projection recommendations that are adequately justified for use within associated Special Analyses (SAs) and future PA updates. The Low Activity Waste (LAW) and Intermediate Level (IL) Vaults structural degradation predictions produced by Carey 2006 and Peregoy 2006, respectively, which were used as the basis for the 2008 ELLWF PA, remain valid based upon the results of the E-Area vault concrete durability simulations reported by Langton 2009 and those reported by SIMCO 2012. Therefore revised structural degradation predictions are not required so long as the mean thickness of the closure cap overlying the vaults is no greater than that assumed within Carey 2006 and Peregoy 2006. For the LAW Vault structural degradation prediction (Carey 2006), the mean thickness of the overlying closure cap was taken as nine feet. For the IL Vault structural degradation prediction (Peregoy 2006), the mean thickness of the overlying closure cap was taken as eight feet. The mean closure cap thicknesses as described here for both E-Area Vaults will be included as a key input and assumption (I&A) in the next revision to the closure plan for the ELLWF (Phifer et al. 2009). In addition, it has been identified as new input to the PA model to be assessed in the ongoing update to the new PA Information UDQE (Flach 2013). Once the UDQE is approved, the SWM Key I

  11. E-Area Vault Concrete Material Property And Vault Durability/Degradation Projection Recommendations

    International Nuclear Information System (INIS)

    Phifer, M. A.

    2014-01-01

    Subsequent to the 2008 E-Area Low-Level Waste Facility (ELLWF) Performance Assessment (PA) (WSRC 2008), two additional E-Area vault concrete property testing programs have been conducted (Dixon and Phifer 2010 and SIMCO 2011a) and two additional E-Area vault concrete durability modeling projections have been made (Langton 2009 and SIMCO 2012). All the information/data from these reports has been evaluated and consolidated herein by the Savannah River National Laboratory (SRNL) at the request of Solid Waste Management (SWM) to produce E-Area vault concrete hydraulic and physical property data and vault durability/degradation projection recommendations that are adequately justified for use within associated Special Analyses (SAs) and future PA updates. The Low Activity Waste (LAW) and Intermediate Level (IL) Vaults structural degradation predictions produced by Carey 2006 and Peregoy 2006, respectively, which were used as the basis for the 2008 ELLWF PA, remain valid based upon the results of the E-Area vault concrete durability simulations reported by Langton 2009 and those reported by SIMCO 2012. Therefore revised structural degradation predictions are not required so long as the mean thickness of the closure cap overlying the vaults is no greater than that assumed within Carey 2006 and Peregoy 2006. For the LAW Vault structural degradation prediction (Carey 2006), the mean thickness of the overlying closure cap was taken as nine feet. For the IL Vault structural degradation prediction (Peregoy 2006), the mean thickness of the overlying closure cap was taken as eight feet. The mean closure cap thicknesses as described here for both E-Area Vaults will be included as a key input and assumption (I and A) in the next revision to the closure plan for the ELLWF (Phifer et al. 2009). In addition, it has been identified as new input to the PA model to be assessed in the ongoing update to the new PA Information UDQE (Flach 2013). Once the UDQE is approved, the SWM Key I and

  12. Efficiency of Sodium Polyacrylate to Improve Durability of Concrete under Adverse Curing Condition

    Directory of Open Access Journals (Sweden)

    Tanvir Manzur

    2015-01-01

    Full Text Available The conventional external curing process requires supply of large amount of water in addition to mixing water as well as strict quality control protocol. However, in a developing country like Bangladesh, many local contractors do not have awareness and required knowledge on importance of curing which often results in weaker concrete with durability issues. Moreover, at times it is difficult to maintain proper external curing process due to nonavailability of water and skilled laborer. Internal curing can be adopted under such scenario since this method is simple and less quality intensive. Usually, naturally occurring porous light weight aggregates (LWA are used as internal curing agent. However, naturally occurring LWA are not available in many countries like Bangladesh. Under these circumstances, Super Absorbent Polymer (SAP can be utilized as an alternative internal curing agent. In this study, sodium polyacrylate (SP as SAP has been used to produce internally cured concrete. Desorption isotherm of SP has been developed to investigate its effectiveness as internal curing agent. Test results showed that internally cured concrete with SP performed better in terms of both strength and durability as compared to control samples when subjected to adverse curing conditions where supply of additional water for external curing was absent.

  13. Proton Exchange Membrane Fuel Cell With Enhanced Durability Using Fluorinated Carbon As Electrocatalyst

    Directory of Open Access Journals (Sweden)

    Ahmad Yasser

    2017-01-01

    Full Text Available This study evaluates the fluorination of a carbon aerogel and its effects on the durability of the resulting electrocatalyst for Proton Exchange Membrane Fuel Cell (PEMFC. Fluorine has been introduced before or after platinum deposition. The different electrocatalysts are physico-chemically and electrochemically characterized, and the results discussed by comparison with commercial Pt/XC72 from E-Tek. The results demonstrate that the level of fluorination of the carbon aerogel can be controlled. The fluorination modifies the texture of the carbons by increasing the pore size and decreasing the specific surface area, but the textures remain appropriate for PEMFC applications. Two fluorination sites are observed, leading to both high covalent C-F bond and weakened ones, the quantity of which depends on whether the treatment is done before or after platinum deposition. The order of the different treatments is very important. The presence of platinum contributes to the fluorination mechanism, but leads to amorphous platinum rather inactive towards the Oxygen Reduction Reaction. Finally, a better durability was demonstrated for the fluorinated then platinized catalyst compared both to the same but not fluorinated catalyst and to the reference commercial material (based on the loss of the electrochemical real surface area after accelerated stress tests.

  14. Adjuvant-enhanced CD4 T Cell Responses are Critical to Durable Vaccine Immunity.

    Science.gov (United States)

    Martins, Karen A O; Cooper, Christopher L; Stronsky, Sabrina M; Norris, Sarah L W; Kwilas, Steven A; Steffens, Jesse T; Benko, Jacqueline G; van Tongeren, Sean A; Bavari, Sina

    2016-01-01

    Protein-based vaccines offer a safer alternative to live-attenuated or inactivated vaccines but have limited immunogenicity. The identification of adjuvants that augment immunogenicity, specifically in a manner that is durable and antigen-specific, is therefore critical for advanced development. In this study, we use the filovirus virus-like particle (VLP) as a model protein-based vaccine in order to evaluate the impact of four candidate vaccine adjuvants on enhancing long term protection from Ebola virus challenge. Adjuvants tested include poly-ICLC (Hiltonol), MPLA, CpG 2395, and alhydrogel. We compared and contrasted antibody responses, neutralizing antibody responses, effector T cell responses, and T follicular helper (Tfh) cell frequencies with each adjuvant's impact on durable protection. We demonstrate that in this system, the most effective adjuvant elicits a Th1-skewed antibody response and strong CD4 T cell responses, including an increase in Tfh frequency. Using immune-deficient animals and adoptive transfer of serum and cells from vaccinated animals into naïve animals, we further demonstrate that serum and CD4 T cells play a critical role in conferring protection within effective vaccination regimens. These studies inform on the requirements of long term immune protection, which can potentially be used to guide screening of clinical-grade adjuvants for vaccine clinical development.

  15. Improved thermal cycling durability and PCR compatibility of polymer coated quantum dot

    International Nuclear Information System (INIS)

    Xun Zhe; Guan Yifu; Zhao Xiaoyun

    2013-01-01

    Quantum dots have experienced rapid development in imaging, labeling and sensing in medicine and life science. To be suitable for polymerase chain reaction (PCR) assay, we have tested QD thermal cycling durability and compatibility, which have not been addressed in previous reports. In this study, we synthesized CdSe/ZnS QDs with a surface modification with high-MW amphiphilic copolymers and observed that Mg 2+ ions in the PCR reaction could induce the QDs to precipitate and reduce their fluorescence signal significantly after thermal cycling. To overcome this problem, we used mPEG2000 to conjugate the QD surface for further protection, and found that this modification enables QDs to endure 40 thermal cycles in the presence of other components essential for PCR reactions. We have also identified that QDs have different effects on rTaq and Ex Taq polymerization systems. A high QD concentration could apparently reduce the PCR efficiency, but this inhibition was relieved significantly in the Ex PCR system as the concentration of Ex Taq polymerase was increased. Real-time PCR amplification results showed that QDs could provide a sufficiently measurable fluorescence signal without excessively inhibiting the DNA amplification. Based on this improved thermal cycling durability and compatibility with the PCR system, QDs have the potential to be developed as stable fluorescent sensors in PCR and real-time PCR amplification. (paper)

  16. Durable transparent carbon nanotube films for flexible device components

    International Nuclear Information System (INIS)

    Sierros, K.A.; Hecht, D.S.; Banerjee, D.A.; Morris, N.J.; Hu, L.; Irvin, G.C.; Lee, R.S.; Cairns, D.R.

    2010-01-01

    This paper describes a durable carbon nanotube (CNT) film for flexible devices and its mechanical properties. Films as thin as 10 nm thick have properties approaching those of existing electrodes based on indium tin oxide (ITO) but with significantly improved mechanical properties. In uniaxial tension, strains as high as 25% are required for permanent damage and at lower strains resistance changes are slight and consistent with elastic deformation of the individual CNTs. A simple model confirms that changes in electrical resistance are described by a Poisson's ratio of 0.22. These films are also durable to cyclic loading, and even at peak strains of 10% no significant damage occurs after 250 cycles. The scratch resistance is also high as measured by nanoscratch, and for a 50 μm tip a load of 140 mN is required to cause initial failure. This is more than 5 times higher than is required to cause cracking in ITO. The robustness of the transparent conductive coating leads to significant improvement in device performance. In touch screen devices fabricated using CNT no failure occurs after a million actuations while for devices based on ITO electrodes 400,000 cycles are needed to cause failure. These durable electrodes hold the key to developing robust, large-area, lightweight, optoelectronic devices such as lighting, displays, electronic-paper, and printable solar cells. Such devices could hold the key to producing inexpensive green energy, providing reliable solid-state lighting, and significantly reducing our dependence on paper.

  17. The Overjustification Effect in Retarded Children: Durability and Generalizability.

    Science.gov (United States)

    Ogilvie, Lee; Prior, Margot

    1982-01-01

    Generalizability and durability of the overjustification effect (on decline in intrinsic motivation due to the lack of rewards in behavior modification programs) were examined in 35 normal preschool children and 17 mental age-matched retarded children. (Author/SW)

  18. Generator Set Durability Testing Using 25% ATJ Fuel Blend

    Science.gov (United States)

    2016-02-01

    UNCLASSIFIED UNCLASSIFIED 3 Table 1. Chemical & Physical Properties of Evaluated 25% ATJ Blend Test ASTM Method Units SwRI Sample ID...25% ATJ Blend Test ASTM Method Units SwRI Sample ID CL15-8613 Results Min Max Flash Point D93 °C 56.5 38 Density D4052 Test...Chemical & Physical Properties of Evaluated 25% ATJ Blend Test ASTM Method Units SwRI Sample ID CL15-8613 Results Min Max Fuel System Icing Inhibitor

  19. Durability Improvement of Pt/RGO Catalysts for PEMFC by Low-Temperature Self-Catalyzed Reduction.

    Science.gov (United States)

    Sun, Kang Gyu; Chung, Jin Suk; Hur, Seung Hyun

    2015-12-01

    Pt/C catalyst used for polymer electrolyte membrane fuel cells (PEMFCs) displays excellent initial performance, but it does not last long because of the lack of durability. In this study, a Pt/reduced graphene oxide (RGO) catalyst was synthesized by the polyol method using ethylene glycol (EG) as the reducing agent, and then low-temperature hydrogen bubbling (LTHB) treatment was introduced to enhance the durability of the Pt/RGO catalyst. The cyclic voltammetry (CV), oxygen reduction reaction (ORR) analysis, and transmittance electron microscopy (TEM) results suggested that the loss of the oxygen functional groups, because of the hydrogen spillover and self-catalyzed dehydration reaction during LTHB, reduced the carbon corrosion and Pt agglomeration and thus enhanced the durability of the electrocatalyst.

  20. Durability of incinerator ash waste encapsulated in modified sulfur cement

    International Nuclear Information System (INIS)

    Kalb, P.D.; Heiser, J.H. III; Pietrzak, R.; Colombo, P.

    1991-01-01

    Waste form stability under anticipated disposal conditions is an important consideration for ensuring continued isolation of contaminants from the accessible environment. Modified sulfur cement is a relatively new material and has only recently been applied as a binder for encapsulation of mixed wastes. Little data are available concerning its long-term durability. Therefore, a series of property evaluation tests for both binder and waste-binder combinations have been conducted to examine potential waste form performance under storage and disposal conditions. These tests include compressive strength, biodegradation, radiation stability, water immersion, thermal cycling, and leaching. Waste form compressive strength increased with ash waste loadings to 30.5 MPa at a maximum incinerator ash loading of 43 wt %. Biodegradation testing resulted in no visible microbial growth of either bacteria or fungi. Initial radiation stability testing did not reveal statistically significant deterioration in structural integrity. Results of 90 day water immersion tests were dependent on the type of ash tested. There were no statistically significant changes in compressive strength detected after completion of thermal cycle testing. Radionuclides from ash waste encapsulated in modified sulfur cement leached between 5 and 8 orders of magnitude slower than the leach index criterion established by the Nuclear Regulatory Commission (NRC) for low-level radioactive waste. Modified sulfur cement waste forms containing up to 43 wt % incinerator fly ash passed EPA Toxicity Characteristic Leaching Procedure (TCLP) criteria for lead and cadmium leachability. 11 refs., 2 figs., 5 tabs

  1. Enhanced Activity and Durability of Nanosized Pt-SnO2/IrO2/CNTs Catalyst for Methanol Electrooxidation.

    Science.gov (United States)

    Wang, Hongjuan; Wang, Xiaohui; Zheng, Jiadao; Peng, Feng; Yu, Hao

    2015-05-01

    Pt-SnO2/IrO2/CNTs anode catalyst for direct methanol fuel cell was designed and prepared with IrO2/CNTs as support for the subsequent immobilization of Pt and SnO2 at the same time. The structure of the catalysts and their catalytic performance in methanol electrooxidation were investigated and the roles of IrO2 and SnO2 in methanol electrooxidation were discussed as well. Results show that Pt-SnO2/IrO2/CNTs catalyst exhibits the best activity and durability for methanol electrooxidation when compared with Pt/CNTs, Pt/IrO2/CNTs and Pt-SnO2/CNTs. According to the results of electrochemical tests and physicochemical characterizations, the enhancements of Pt-SnO2/IrO2/CNTs were attributed to the special properties of IrO2 and SnO2, in which IrO2 mainly increases the methanol oxidation activity and SnO2 mainly improves the CO oxidation ability and durability. Therefore, Pt-SnO2/IrO2/CNTs exhibits excellent performance for methanol oxidation with higher electrocatalytic activity (I(f) of 1054 A g(Pt(-1)) and powerful anti-poisoning ability (the onset potential for CO oxidation of 0.3 V) and outstanding durability (the sustained time t in CP of 617 s), revealing a suitable anode catalyst for DMFCs.

  2. Reliability Testing Using the Vehicle Durability Simulator

    Science.gov (United States)

    2017-11-20

    techniques are employed to reduce test and simulation time. Through application of these processes and techniques the reliability characteristics...remote parameter control (RPC) software. The software is specifically designed for the data collection, analysis, and simulation processes outlined in...the selection process for determining the desired runs for simulation . 4.3 Drive File Development. After the data have been reviewed and

  3. Durability Issues and Status of PBI-Based Fuel Cells

    DEFF Research Database (Denmark)

    Jakobsen, Mark Tonny Dalsgaard; Jensen, Jens Oluf; Cleemann, Lars Nilausen

    2016-01-01

    This chapter briefly reviews durability and stability issues with key materials and components for HT-PEMFCs, including the polymer membrane, the doping acid, the electrocatalyst, the catalyst support and bipolar plates. Degradation mechanisms and their dependence on fuel cell operating condition...

  4. Canonical correlation of waste glass compositions and durability, including pH

    International Nuclear Information System (INIS)

    Oeksoy, D.; Pye, L.D.; Bickford, D.F.; Ramsey, W.G.

    1993-01-01

    Control of waste glass durability is a major concern in the immobilization of radioactive and mixed wastes. Leaching rate in standardized laboratory tests is being used as a demonstration of consistency of the response of waste glasses in the final disposal environment. The leaching of silicate and borosilicate glasses containing alkali or alkaline earth elements is known to be autocatalytic, in that the initial ion exchange of alkali in the glass for hydrogen ions in water results in the formation of OH and increases the pH of the leachate. The increased pH then increases the rate of silicate network attack, accelerating the leaching effect. In well formulated glasses this effect reaches a thermodynamic equilibrium when leachate saturation of a critical species, such as silica, or a dynamic equilibrium is reached when the pH shift caused by incremental leaching has negligible effect on pH. This report analyzes results of a seven leach test on waste glasses

  5. Durability properties of high volume fly ash self compacting concretes

    Energy Technology Data Exchange (ETDEWEB)

    P. Dinakar; K.G. Babu; Manu Santhanam [Indian Institute of Technology, Chennai (India). Building Technology Division

    2008-11-15

    This paper presents an experimental study on the durability properties of self compacting concretes (SCCs) with high volume replacements of fly ash. Eight fly ash self compacting concretes of various strength grades were designed at desired fly ash percentages of 0, 10, 30, 50, 70 and 85%, in comparison with five different mixtures of normal vibrated concretes (NCs) at equivalent strength grades. The durability properties were studied through the measurement of permeable voids, water absorption, acid attack and chloride permeation. The results indicated that the SCCs showed higher permeable voids and water absorption than the vibrated normal concretes of the same strength grades. However, in acid attack and chloride diffusion studies the high volume fly ash SCCs had significantly lower weight losses and chloride ion diffusion.

  6. Low-Li2O Frits: Selecting Glasses that Support the Melt Rate Studies and Challenge the Current Durability Model

    International Nuclear Information System (INIS)

    Peeler, D. K.; Edwards, T. B.

    2005-01-01

    During the progressive development of the cold cap model (as it applies to a potential melt rate predictive tool), the formation of an Al-Li-silicate phase was identified as an intermediate reaction phase that could possibly hinder melt rate for SB4. To test this theory, six glasses were designed (using Frit 320's composition as the baseline) to maintain a constant 20 wt% sum of alkali content (in frit) by varying Na 2 O to Li 2 O ratios. The Li 2 O concentration ranged from 8 wt% down to 0% in either 2% or 1% increments with the differences being accounted for by an increase in Na 2 O concentration. Although the primary objective of the ''lower Li 2 O'' frits was to evaluate the potential for melt rate improvements, assessments of durability (as measured by the Product Consistency Test (PCT)) were also performed. The results suggest that durable glasses can be produced with these ''lower Li 2 O'' frits should it be necessary to pursue this option for improving melt rate. In addition to the series of glasses to support melt rate assessments, a series of frits were also developed to challenge the current durability model based on the limits proposed by Edwards et al. (2004). Although the ''new'' limits allow access into compositional regions of interest (i.e., higher alkali systems) which can improve melt rate and/or waste loading, there may still be ''additional'' conservatism. In this report, two series of glasses were developed to challenge the ''new'' durability limits for the SB4 system. In the first series, the total alkali of the Frit 320-based glasses (designed to support the melt rate program) was increased from 20 wt% to 21 wt% (in the frit), but the series also evaluated the possible impact of various Na 2 O and Li 2 O mass ratio differences. The second series pushed the alkali limit in the frit even further with frits containing either 22 or 24 wt% total alkali as well as various Na 2 O and Li 2 O mass ratios. The results of the PCT evaluation indicated

  7. The hydrogen: a clean and durable energy; L'hydrogene: une energie propre et durable

    Energy Technology Data Exchange (ETDEWEB)

    Alleau, Th. [Association Francaise de l' Hydrogene (France); Nejat Veziroglu, T. [Clean Energy Research Institute, University of Miami (United States); Lequeux, G. [Commission europeenne, DG de la Recherche, Bruxelles (Belgium)

    2000-07-01

    All the scientific experts agree, the hydrogen will be the energy vector of the future. During this conference day on the hydrogen, the authors recalled the actual economic context of the energy policy with the importance of the environmental policy and the decrease of the fossil fuels. The research programs and the attitudes of the France and the other countries facing the hydrogen are also discussed, showing the great interest for this clean and durable energy. They underline the importance of an appropriate government policy, necessary to develop the technology of the hydrogen production, storage and use. (A.L.B.)

  8. Tensile strength and durability characteristics of high-performance fiber reinforced concrete

    International Nuclear Information System (INIS)

    Ramadoss, P.; Nagamani, K.

    2008-01-01

    This paper presents investigations towards developing a better understanding of the contribution of steel fibers to the tensile strength of high-performance fiber reinforced concrete (HPFRC). For 32 series of mixes, flexural and splitting tensile strengths were determined at 28 days. The variables investigated were fiber volume fraction (0%, 0.5%, 1% and 1.5% with an aspect of 80), silica fume replacement level (SF/CM=0.05 and 0.10) and matrix composition (w/cm ratios ranging from 0.25 t 0.40). The influence of fiber content in terms of fiber reinforcing index on the flexural and splitting tensile strengths of HPFRC is presented. Comparative studies were performed on the tensile behavior of SFRC measured by two different loading tests: flexural test and splitting test. Based on the test results, using the least square method, empirical expressions were developed to predict 28-day tensile strength of HPFRC in terms of fiber reinforcing index. Durability tests were carried out to examine the performance of the SFRC. Relationship between flexural and splitting tensile strengths has been developed using regression analysis. The experimental values of previous researchers were compared with the values predicted by the empirical equations and the absolute variation obtained was within 6% and 5% for flexural and splitting tensile strengths respectively. (author)

  9. Durability of Flexible Ureteroscopes: A Prospective Evaluation of Longevity, the Factors that Affect it, and Damage Mechanisms.

    Science.gov (United States)

    Legemate, Jaap D; Kamphuis, Guido M; Freund, Jan Erik; Baard, Joyce; Zanetti, Stefano P; Catellani, Michele; Oussoren, Harry W; de la Rosette, Jean J

    2018-03-10

    Flexible ureteroscopy is an established treatment modality for evaluating and treating abnormalities in the upper urinary tract. Reusable ureteroscope (USC) durability is a significant concern. To evaluate the durability of the latest generation of digital and fiber optic reusable flexible USCs and the factors affecting it. Six new flexible USCs from Olympus and Karl Storz were included. The primary endpoint for each USC was its first repair. Data on patient and treatment characteristics, accessory device use, ureteroscopy time, image quality, USC handling, disinfection cycles, type of damage, and deflection loss were collected prospectively. Ureteroscopy. USC durability was measured as the total number of uses and ureteroscopy time before repair. USC handling and image quality were scored. After every procedure, maximal ventral and dorsal USC deflection were documented on digital images. A total of 198 procedures were performed. The median number of procedures was 27 (IQR 16-48; 14h) for the six USCs overall, 27 (IQR 20-56; 14h) for the digital USCs, and 24 (range 10-37; 14h) for the fiber optic USCs. Image quality remained high throughout the study for all six USCs. USC handling and the range of deflection remained good under incremental use. Damage to the distal part of the shaft and shaft coating was the most frequent reason for repair, and was related to intraoperative manual forcing. A limitation of this study is its single-center design. The durability of the latest reusable flexible USCs in the current study was limited to 27 uses (14h). Damage to the flexible shaft was the most important limitation to the durability of the USCs evaluated. Prevention of intraoperative manual forcing of flexible USCs maximizes their overall durability. Current flexible ureteroscopes proved to be durable. Shaft vulnerability was the most important limiting factor affecting durability. Copyright © 2018 European Association of Urology. Published by Elsevier B.V. All rights

  10. Effects of annealing temperature on mechanical durability of indium-tin oxide film on polyethylene terephthalate substrate

    International Nuclear Information System (INIS)

    Machinaga, Hironobu; Ueda, Eri; Mizuike, Atsuko; Takeda, Yuuki; Shimokita, Keisuke; Miyazaki, Tsukasa

    2014-01-01

    Effects of the annealing temperature on mechanical durability of indium-tin oxide (ITO) thin films deposited on polyethylene terephthalate (PET) substrates were investigated. The ITO films were annealed at the range from 150 °C to 195 °C after the DC sputtering deposition for the production of polycrystalline ITO layers on the substrates. The onset strains of cracking in the annealed ITO films were evaluated by the uniaxial stretching tests with electrical resistance measurements during film stretching. The results indicate that the onset strain of cracking in the ITO film is clearly increased by increasing the annealing temperature. The in-situ measurements of the inter-planer spacing of the (222) plane in the crystalline ITO films during film stretching by using synchrotron radiation strongly suggest that the large compressive stress in the ITO film increases the onset strain of cracking in the film. X-ray stress analyses of the annealed ITO films and thermal mechanical analyses of the PET substrates also clarifies that the residual compressive stress in the ITO film is enhanced with increasing the annealing temperature due to the considerably larger shrinkage of the PET substrate. - Highlights: • Indium-tin oxide (ITO) films were deposited on polyethylene terephthalate (PET). • Mechanical durability of the ITO is improved by high temperature post-annealing. • The shrinkage in the PET increases with rising the post-annealing temperature. • The shrinkage of the PET enhances the compressive stress in the ITO film. • Large compressive stress in the ITO film may improve its mechanical durability

  11. Synthesis and Characterization of Pt-Ag Alloy Nanocages with Enhanced Activity and Durability toward Oxygen Reduction.

    Science.gov (United States)

    Yang, Xuan; Roling, Luke T; Vara, Madeline; Elnabawy, Ahmed O; Zhao, Ming; Hood, Zachary D; Bao, Shixiong; Mavrikakis, Manos; Xia, Younan

    2016-10-12

    Engineering the elemental composition of metal nanocrystals offers an effective strategy for the development of catalysts or electrocatalysts with greatly enhanced activity. Herein, we report the synthesis of Pt-Ag alloy nanocages with an outer edge length of 18 nm and a wall thickness of about 3 nm. Such nanocages with a composition of Pt 19 Ag 81 could be readily prepared in one step through the galvanic replacement reaction between Ag nanocubes and a Pt(II) precursor. After 10 000 cycles of potential cycling in the range of 0.60-1.0 V as in an accelerated durability test, the composition of the nanocages changed to Pt 56 Ag 44 , together with a specific activity of 1.23 mA cm -2 toward oxygen reduction, which was 3.3 times that of a state-of-the-art commercial Pt/C catalyst (0.37 mA cm -2 ) prior to durability testing. Density functional theory calculations attributed the increased activity to the stabilization of the transition state for breaking the O-O bond in molecular oxygen. Even after 30 000 cycles of potential cycling, the mass activity of the nanocages only dropped from 0.64 to 0.33 A mg -1 Pt , which was still about two times that of the pristine Pt/C catalyst (0.19 A mg -1 Pt ).

  12. Durability of adhesive glass-metal connections for structural applications

    NARCIS (Netherlands)

    Van Lancker, B.; Dispersyn, J.; De Corte, W.; Belis, J.

    2016-01-01

    The use of adhesive bonds for structural glass-metal connections in the building envelope has increased in recent years. Despite the multiple advantages compared to more traditional bolted connections, long-term behaviour and durability of the adhesives have to be investigated accurately. Because,

  13. Product consistency testing of three reference glasses in stainless steel and perfluoroalkoxy resin vessels

    International Nuclear Information System (INIS)

    Olson, K.M.; Smith, G.L.; Marschman, S.C.

    1995-03-01

    Because of their chemical durability, silicate glasses have been proposed and researched since the mid-1950s as a medium for incorporating high-level radioactive waste (HLW) generated from processing of nuclear materials. A number of different waste forms were evaluated and ranked in the early 1980s; durability (leach resistance) was the highest weighted factor. Borosilicate glass was rated the best waste form available for incorporation of HLW. Four different types of vessels and three different glasses were used to study the possible effect of vessel composition on durability test results from the Production Consistency Test (PCT). The vessels were 45-m 304 stainless steel vessels, 150-m 304 L stainless steel vessels, and 60-m perfluoroalkoxy (PFA) fluoropolymer resin vessels. The three glasses were the Environmental Assessment glass manufactured by Corning Incorporated and supplied by Westinghouse Savannah River company, and West Valley Nuclear Services reference glasses 5 and 6, manufactured and supplied by Catholic University of America. Within experimental error, no differences were found in durability test results using the 3 different glasses in the 304L stainless steel or PFA fluoropolymer resin vessels over the seven-day test period

  14. Durability of polymer matrix composites for automotive structural applications: A state-of-the-art review

    Energy Technology Data Exchange (ETDEWEB)

    Corum, J.M.; Simpson, W.A. Jr.; Sun, C.T.; Talreja, R.; Weitsman, Y.J.

    1995-07-01

    A key unanswered question that must be addressed before polymeric composites will be widely used in automotive structural components is their known durability. Major durability issues are the effects that cyclic loadings, creep, automotive fluid environments, and low-energy impacts have on dimensional stability, strength, and stiffness throughout the required life of a composite component. This report reviews the current state of understanding in each of these areas. It also discusses the limited information that exists on one of the prime candidate materials for automotive structural applications--an isocyanurate reinforced with a continuous strand, swirl mat. Because of the key role that nondestructive evaluations must play in understanding damage development and progression, a chapter is included on ultrasonic techniques. A final chapter then gives conclusions and recommendations for research needed to resolve the various durability issues. These recommendations will help provide a sound basis for program planning for the Durability of Lightweight Composite Structures Project sponsored by the US Department of Energy in cooperation with the Automotive Composites Consortium of Chrysler, Ford, and General Motors.

  15. Durable Tactile Glove for Human or Robot Hand

    Science.gov (United States)

    Butzer, Melissa; Diftler, Myron A.; Huber, Eric

    2010-01-01

    A glove containing force sensors has been built as a prototype of tactile sensor arrays to be worn on human hands and anthropomorphic robot hands. The force sensors of this glove are mounted inside, in protective pockets; as a result of this and other design features, the present glove is more durable than earlier models.

  16. Experimental Investigation on the Durability of Glass Fiber-Reinforced Polymer Composites Containing Nanocomposite

    Directory of Open Access Journals (Sweden)

    Weiwen Li

    2013-01-01

    Full Text Available Nanoclay layers incorporated into polymer/clay nanocomposites can inhibit the harmful penetration of water and chemicals into the material, and thus the durability of glass fiber-reinforced polymer (GFRP composites should be enhanced by using polymer/clay nanocomposite as the matrix material. In this study, 1.5 wt% vinyl ester (VE/organoclay and 2 wt% epoxy (EP/organoclay nanocomposites were prepared by an in situ polymerization method. The dispersion states of clay in the nanocomposites were studied by performing XRD analysis. GFRP composites were then fabricated with the prepared 1.5 wt% VE/clay and 2.0 wt% EP/clay nanocomposites to investigate the effects of a nanocomposite matrix on the durability of GFRP composites. The durability of the two kinds of GFRP composites was characterized by monitoring tensile properties following degradation of GFRP specimens aged in water and alkaline solution at 60°C, and SEM was employed to study fracture behaviors of aged GFRP composites under tension. The results show that tensile properties of the two types of GFRP composites with and without clay degrade significantly with aging time. However, the GFRP composites with nanoclay show a lower degradation rate compared with those without nanoclay, supporting the aforementioned hypothesis. And the modification of EP/GFRP enhanced the durability more effectively.

  17. Immediate extinction causes a less durable loss of performance than delayed extinction following either fear or appetitive conditioning

    OpenAIRE

    Woods, Amanda M.; Bouton, Mark E.

    2008-01-01

    Five experiments with rat subjects compared the effects of immediate and delayed extinction on the durability of extinction learning. Three experiments examined extinction of fear conditioning (using the conditioned emotional response method), and two experiments examined extinction of appetitive conditioning (using the food-cup entry method). In all experiments, conditioning and extinction were accomplished in single sessions, and retention testing took place 24 h after extinction. In both f...

  18. Effect of storage time, thermocycling and resin coating on durability of dentin bonding systems

    Directory of Open Access Journals (Sweden)

    Seyed-Mostafa Mousavinasab

    2009-01-01

    Full Text Available Background:Along with development of different dental adhesives, concerns about hydrolytic deg-radation of the adhesive components have arisen. The purpose of this study was to evaluate the in-vitro influence of thermocycling, water storage and resin coating on the microshear bond strength of total etch and self etch adhesive systems to dentin. Methods:The superficial coronal dentin of eighty intact third molars were exposed and divided into 5 equal groups. Dental adhesives including Scotch Bond Multi Purpose (SBMP, Single Bond (SB, Clearfil SE Bond (CSE, Prompt L-Pop (PLP, and Prompt L-Pop plus Margin bond (PLPM were applied according to the manufacturers′ instructions on prepared surfaces in the study groups, respectively. Then composite cylinders were bonded and specimens were divided into two subgroups. One subgroup was stored in water for 24 hours. The second subgroup was subjected to 3000 thermocycle shocks and then was stored in 37°C water for 3 months. Finally, all teeth were subjected to the mi-croshear bond strength test. Data were analyzed using two-way ANOVA and Tukey HSD tests. One specimen similar to each subgroup was also prepared for SEM evaluation. Results:After one-day storage, the SBMP showed the highest bond strength followed by CSE, PLPM, SB and PLP. After three months storage, the highest bond strength was observed in SBMP followed by PLPM, CSE, SB, and PLP. Conclusion: SBMP showed the best bond strength while CSE represented acceptable bond durabil-ity. Resin coating on PLP improved bond strength and durability.

  19. Fostering a durable relationship between a waste management facility and its host community

    International Nuclear Information System (INIS)

    2007-01-01

    Any long-term radioactive waste management project is likely to last decades to centuries. It requires a physical site and will impact in a variety of ways on the surrounding community over that whole period. The societal durability of an agreed solution is essential to success. This report identifies a number of design elements (including functional, cultural and physical features) that favour a durable relationship between the facility and its host community by improving prospects for quality of life across generations

  20. A durability model incorporating safe life methodology and damage tolerance approach to assess first inspection and maintenance period for structures

    International Nuclear Information System (INIS)

    Xiong, J.J.; Shenoi, R.A.

    2009-01-01

    This paper outlines a new durability model to assess the first inspection and maintenance period for structures. Practical scatter factor formulae are presented to determine the safe fatigue crack initiation and propagation lives from the results of a single full-scale test of a complete structure. New theoretical solutions are proposed to determine the s a -s m -N surfaces of fatigue crack initiation and propagation. Prediction techniques are then developed to establish the relationship equation between safe fatigue crack initiation and propagation lives with a specific reliability level using a two-stage fatigue damage cumulative rule. A new durability model incorporating safe life and damage tolerance design approaches is derived to assess the first inspection and maintenance period. Finally, the proposed models are applied to assess the first inspection and maintenance period of a fastening structure at the root of helicopter blade.

  1. Highly Sensitive, Transparent, and Durable Pressure Sensors Based on Sea-Urchin Shaped Metal Nanoparticles.

    Science.gov (United States)

    Lee, Donghwa; Lee, Hyungjin; Jeong, Youngjun; Ahn, Yumi; Nam, Geonik; Lee, Youngu

    2016-11-01

    Highly sensitive, transparent, and durable pressure sensors are fabricated using sea-urchin-shaped metal nanoparticles and insulating polyurethane elastomer. The pressure sensors exhibit outstanding sensitivity (2.46 kPa -1 ), superior optical transmittance (84.8% at 550 nm), fast response/relaxation time (30 ms), and excellent operational durability. In addition, the pressure sensors successfully detect minute movements of human muscles. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Toward a new spacecraft optimal design lifetime? Impact of marginal cost of durability and reduced launch price

    Science.gov (United States)

    Snelgrove, Kailah B.; Saleh, Joseph Homer

    2016-10-01

    The average design lifetime of satellites continues to increase, in part due to the expectation that the satellite cost per operational day decreases monotonically with increased design lifetime. In this work, we challenge this expectation by revisiting the durability choice problem for spacecraft in the face of reduced launch price and under various cost of durability models. We first provide a brief overview of the economic thought on durability and highlight its limitations as they pertain to our problem (e.g., the assumption of zero marginal cost of durability). We then investigate the merging influence of spacecraft cost of durability and launch price, and we identify conditions that give rise cost-optimal design lifetimes that are shorter than the longest lifetime technically achievable. For example, we find that high costs of durability favor short design lifetimes, and that under these conditions the optimal choice is relatively robust to reduction in launch prices. By contrast, lower costs of durability favor longer design lifetimes, and the optimal choice is highly sensitive to reduction in launch price. In both cases, reduction in launch prices translates into reduction of the optimal design lifetime. Our results identify a number of situations for which satellite operators would be better served by spacecraft with shorter design lifetimes. Beyond cost issues and repeat purchases, other implications of long design lifetime include the increased risk of technological slowdown given the lower frequency of purchases and technology refresh, and the increased risk for satellite operators that the spacecraft will be technologically obsolete before the end of its life (with the corollary of loss of value and competitive advantage). We conclude with the recommendation that, should pressure to extend spacecraft design lifetime continue, satellite manufacturers should explore opportunities to lease their spacecraft to operators, or to take a stake in the ownership

  3. Comparison of the Absorbable Polymer Sirolimus-Eluting Stent (MiStent) to the Durable Polymer Everolimus-Eluting Stent (Xience) (from the DESSOLVE I/II and ISAR-TEST-4 Studies).

    Science.gov (United States)

    Lansky, Alexandra J; Kastrati, Adnan; Edelman, Elazer R; Parise, Helen; Ng, Vivian G; Ormiston, John; Wijns, William; Byrne, Robert A

    2016-02-15

    We compared the outcomes of a novel, thin-strut, cobalt-chromium, absorbable, polymer sirolimus-eluting stent (APSES; MiStent) to the durable polymer cobalt-chromium everolimus-eluting stent (EES; Xience). A propensity-matched analysis was performed comparing data from the DES With Sirolimus and a Bioabsorbable Polymer for the Treatment of Patients With De Novo Lesions in the Native Coronary Arteries (DESSOLVE) I and II studies, evaluating the APSES to the EES arm of the Intracoronary Stenting and Angiographic Results: Test Efficacy of 3 Limus-Eluting Stents-4 study. Target lesion failure (TLF) and its components were evaluated at 12 months and annually to 3 years; 805 patients (APSES = 153; EES = 652) were included with propensity matching in 204 patients (APSES = 102; EES = 102). APSES compared with EES had lower TLF at 1 year (3.0% vs 8.0%, p = 0.12) driven by a difference in target lesion revascularization (TLR; 1% vs 6%, p = 0.05), with no difference in target vessel myocardial infarction (p = 0.56) or stent thrombosis (p = 0.31). At 3 years, TLF (5.0% vs 12.5%, p = 0.07) and TLR (2.0% vs 8.4%, p = 0.04) remained lower with APSES. By landmark analysis, there was no significant difference in TLF between 1 and 3 years (p = 0.36). In conclusion, in a propensity-matched analysis, the APSES demonstrated reduced clinically indicated TLR rates at 1 and 3 years compared with the durable polymer EES, with minimal accrual of events between 1 and 3 years. Copyright © 2016 Elsevier Inc. All rights reserved.

  4. Comparative durability of timber bridges in the USA

    Science.gov (United States)

    James P. Wacker; Brian K. Brashaw

    2017-01-01

    As engineers begin to utilize life-cycle-cost design approaches for timber bridges, there is a necessity for more reliable data about their durability and expected service life. This paper summarizes a comprehensive effort to assess the current condition of more than one hundred timber highway bridge superstructures throughout the United States. This national study was...

  5. Long-term durability of polyethylene for encapsulation of low-level radioactive, hazardous, and mixed wastes

    International Nuclear Information System (INIS)

    Kalb, P.D.; Heiser, J.H.; Colombo, P.

    1991-01-01

    The durability of polyethylene waste forms for treatment of low-level radioactive, hazardous, and mixed wastes is examined. Specific potential failure mechanisms investigated include biodegradation, radiation, chemical attack, flammability, environmental stress cracking, and photodegradation. These data are supported by results from waste form performance testing including compressive yield strength, water immersion, thermal cycling, leachability of radioactive and hazardous species, irradiation, biodegradation, and flammability. Polyethylene was found to be extremely resistant to each of these potential failure modes under anticipated storage and disposal conditions. 16 refs., 3 figs., 1 tab

  6. A highly durable fuel cell electrocatalyst based on double-polymer-coated carbon nanotubes.

    Science.gov (United States)

    Berber, Mohamed R; Hafez, Inas H; Fujigaya, Tsuyohiko; Nakashima, Naotoshi

    2015-11-23

    Driven by the demand for the commercialization of fuel cell (FC) technology, we describe the design and fabrication of a highly durable FC electrocatalyst based on double-polymer-coated carbon nanotubes for use in polymer electrolyte membrane fuel cells. The fabricated electrocatalyst is composed of Pt-deposited polybenzimidazole-coated carbon nanotubes, which are further coated with Nafion. By using this electrocatalyst, a high FC performance with a power density of 375 mW/cm(2) (at 70 ˚C, 50% relative humidity using air (cathode)/H2(anode)) was obtained, and a remarkable durability of 500,000 accelerated potential cycles was recorded with only a 5% loss of the initial FC potential and 20% loss of the maximum power density, which were far superior properties compared to those of the membrane electrode assembly prepared using carbon black in place of the carbon nanotubes. The present study indicates that the prepared highly durable fuel cell electrocatalyst is a promising material for the next generation of PEMFCs.

  7. Key Durability Issues with Mullite-Based Environmental Barrier Coatings for Si-Based Ceramics

    Science.gov (United States)

    Lee, Kang N.

    2000-01-01

    Plasma-sprayed mullite (3Al2O3.2SiO2) and mullite/yttria-stabilized-zirconia (YSZ) dual layer coatings have been developed to protect silicon -based ceramics from environmental attack. Mullite-based coating systems show excellent durability in air. However, in combustion environments, corrosive species such as molten salt or water vapor penetrate through cracks in the coating and attack the Si-based ceramics along the interface. Thus the modification of the coating system for enhanced crack-resistance is necessary for long-term durability in combustion environments. Other key durability issues include interfacial contamination and coating/substrate bonding. Interfacial contamination leads to enhanced oxidation and interfacial pore formation, while a weak coating/substrate bonding leads to rapid attack of the interface by corrosive species, both of which can cause a premature failure of the coating. Interfacial contamination can be minimized by limiting impurities in coating and substrate materials. The interface may be modified to improve the coating/substrate bond.

  8. The use of a flow test and a flow model in evaluating the durability of various nuclear waste-form materials

    International Nuclear Information System (INIS)

    Barkatt, A.; Barkatt, A.; Boroomand, M.A.

    1983-01-01

    The comprehensive predictive model described in this paper has been briefly outlined for a single particular set of repository parameters in an earlier paper. A general detailed derivation and a detailed illustration of the use of this method in comparative evaluation of a variety of waste-form materials are given. The model focuses on the long-term leach rate of materials under all possible water flow rates through a repository site, given any exposure configuration (i.e., ratio between the exposed area of the waste form and the volume of water with which it is in effective contact) which is considered most representative of the actual repository conditions. The model permits direct calculation of the annual fractional release rate of the major matrix elements as well as of any other components of a waste form. This makes it possible to evaluate how well various waste forms meet long-term durability criteria such as those proposed by the U.S. Nuclear Regulatory Commission, makes it possible to obtain such release rates, corresponding to the entire range of flow conditions expected in a repository down to very slow flow rates by conducting dynamic laboratory tests at practical rates of leachant exchange at relatively high surfaceto-volume ratios, following the leachate composition until the leach rates approach constant values, and normalizing the data to the surface-to-volume ratio expected under repository conditions. The purpose of this paper is to outline the general derivation of the model and to describe the results of applying the model in dynamic leach tests carried out on five different waste-form materials over the entire range of effective flow rates expected under repository conditions

  9. Estimation of metallic structure durability for a known law of stress variation

    Science.gov (United States)

    Mironov, V. I.; Lukashuk, O. A.; Ogorelkov, D. A.

    2017-12-01

    Overload of machines working in transient operational modes leads to such stresses in their bearing metallic structures that considerably exceed the endurance limit. The estimation of fatigue damages based on linear summation offers a more accurate prediction in terms of machine durability. The paper presents an alternative approach to the estimation of the factors of the cyclic degradation of a material. Free damped vibrations of the bridge girder of an overhead crane, which follow a known logarithmical decrement, are studied. It is shown that taking into account cyclic degradation substantially decreases the durability estimated for a product.

  10. Effect of the addition of Na2O on the thermal properties and chemical durability of glasses of iron and uranium phosphates

    International Nuclear Information System (INIS)

    Arboleda Zuluaga, P.A; Rodriguez, D.S; Gonzalez Oliver, C; Rincon Lopez, J.M; Soldera, F

    2012-01-01

    A series of glass compositions including (54,6-73,5P 2 O 5 .14-22Fe 2 O 3.x Na 2 O.2,8-4,25 UO 2 ) %mol. x=0-28,4 were studied in function of sodium oxide content for the thermal properties and chemical durability. By means differential dilatometer measurements was possible establish the variation of Tg, and α Tsoft and analysis of the kinetics of sintering by means of High Temperature Microscopy (MAT) and dilatometric data of pressed pellets. The presence of modifier oxides in the structure of iron phosphate glasses causes slightly onset sintering anticipation in almost 25 o C The chemical durability was estimated performing the named Product Consistency Test (PCT-B) focused on determining the resistance of glasses for nuclear wastes. These glasses exhibit good chemical durability but it is significant impaired by the addition of x≥6wt%Na 2 O. It is aimed to achieve more stable compositions and get glass matrixes able to contain more uranium oxides allowing evaluating the potential application of these iron phosphate glasses for special, industrial and nuclear waste immobilization

  11. Are Press Depictions of Affordable Care Act Beneficiaries Favorable to Policy Durability?

    Science.gov (United States)

    Chattopadhyay, Jacqueline

    2015-01-01

    If successfully implemented and enduring, the Affordable Care Act (ACA) stands to expand health insurance access in absolute terms, reduce inter-group disparities in that access, and reduce exposure to the financial vulnerabilities illness entails. Its durability--meaning both avoidance of outright retrenchment and fidelity to its policy aims--is thus of scholarly interest. Past literature suggests that social constructions of a policy's beneficiaries may impact durability. This paper first describes media portrayals of ACA beneficiaries with an eye toward answering three descriptive questions: (1) Do portrayals depict beneficiaries as economically heterogeneous? (2) Do portrayals focus attention on groups that have acquired new political relevance due to the ACA, such as young adults? (3) What themes that have served as messages about beneficiary "deservingness" in past social policy are most frequent in ACA beneficiary portrayals? The paper then assesses how the portrayal patterns that these questions uncover may work both for and against the ACA's durability, finding reasons for confidence as well as caution. Using manual and automated methods, this paper analyzes newspaper text from August 2013 through January 2014 to trace portrayals of two ACA "target populations" before and during the new law's first open-enrollment period: those newly eligible for Medicaid, and those eligible for subsidies to assist in the purchase of private health insurance under the ACA. This paper also studies newspaper text portrayals of two groups informally crafted by the ACA in this timeframe: those gaining health insurance and those losing it. The text data uncover the following answers to the three descriptive questions for the timeframe studied: (1) Portrayals may underplay beneficiaries' economic heterogeneity. (2) Portrayals pay little attention to young adults. (3) Portrayals emphasize themes of workforce participation, economic self-sufficiency, and insider status. Health

  12. Evaluation of models of waste glass durability

    International Nuclear Information System (INIS)

    Ellison, A.

    1995-01-01

    The main variable under the control of the waste glass producer is the composition of the glass; thus a need exists to establish functional relationships between the composition of a waste glass and measures of processability, product consistency, and durability. Many years of research show that the structure and properties of a glass depend on its composition, so it seems reasonable to assume that there also is relationship between the composition of a waste glass and its resistance to attack by an aqueous solution. Several models have been developed to describe this dependence, and an evaluation their predictive capabilities is the subject of this paper. The objective is to determine whether any of these models describe the ''correct'' functional relationship between composition and corrosion rate. A more thorough treatment of the relationships between glass composition and durability has been presented elsewhere, and the reader is encouraged to consult it for a more detailed discussion. The models examined in this study are the free energy of hydration model, developed at the Savannah River Laboratory, the structural bond strength model, developed at the Vitreous State Laboratory at the Catholic University of America, and the Composition Variation Study, developed at Pacific Northwest Laboratory

  13. A Framework of Retailer-Manufacturer Cooperation and Coopetition: Consumer Durable Goods Retailers’ Case Studies

    Directory of Open Access Journals (Sweden)

    Marzanna Katarzyna Witek-Hajduk

    2017-03-01

    Full Text Available Objective: The purpose of this paper is to develop a framework of cooperation and coopetition between retailers and key manufacturers from a perspective of retailers offering consumer durables. Research Design & Methods: In order to answer the research questions semi-structured, in-depth and face-to-face interviews with managers of six SMEs or large retailers operating in Poland and offering consumer durables were carried out. Findings: The empirical studies confirm both cooperation and coopetition between retailers and manufacturers – suppliers of consumer durables depending on, among others, the category of consumer goods and the balance of power between retailers and manufacturers. The scope of cooperation is not too wide, and concerns only some of the value chain processes indicated in the literature. Implications & Recommendations: Conducted studies are exploratory and need to be deepen with the use of quantitative research that will help determine the impact of the balance of power between manufacturers and retailers and the strength of retailer-manufacturer relations on the range / areas and financial and non-financial performance of this cooperation. Contribution & Value Added: The originality of this work lies in studying some aspects of retailers’ relations with their key suppliers operating in consumer durables market.

  14. Distribution Patterns of Polyphosphate Metabolism Pathway and Its Relationships With Bacterial Durability and Virulence

    Directory of Open Access Journals (Sweden)

    Liang Wang

    2018-04-01

    Full Text Available Inorganic polyphosphate (polyP is a linear polymer of orthophosphate residues. It is reported to be present in all life forms. Experimental studies showed that polyP plays important roles in bacterial durability and virulence. Here we investigated the relationships of polyP with bacterial durability and virulence theoretically. Bacterial lifestyle, environmental persistence, virulence factors (VFs, and species evolution are all included in the analysis. The presence of seven genes involved in polyP metabolism (ppk1, ppk2, pap, surE, gppA, ppnK, and ppgK and 2595 core VFs were verified in 944 bacterial reference proteomes for distribution patterns via HMMER. Proteome size and VFs were compared in terms of gain and loss of polyP pathway. Literature mining and phylogenetic analysis were recruited to support the study. Our analyzes revealed that the presence of polyP metabolism is positively correlated with bacterial proteome size and the number of virulence genes. A potential relationship of polyP in bacterial lifestyle and environmental durability is suggested. Evolutionary analysis shows that polyP genes are randomly lost along the phylogenetic tree. In sum, based on our theoretical analysis, we confirmed that bacteria with polyP metabolism are associated with high environmental durability and more VFs.

  15. Studies of The Durability of Belt Conveyor Idlers with Working Loads Taken into Account

    Science.gov (United States)

    Król, Robert

    2017-12-01

    The results of laboratory and operational studies conducted in the Machinery Systems Division of Wroclaw University of Technology in recent years have became the basis for selecting proper belt conveyor roller designs optimized for specific strength and operational criteria. The usefulness of the results for assessing the energy intensity of idlers, estimating their durability and determining modernization policies has been confirmed. Methods of estimating the durability of carrying idlers on the basis of the identified output stream distributions are presented. Results of studies carried out using an analytical method and a laboratory method are reported. It has been shown that the operational durability of a roller is determined by its design, the roller set parameters (the spacing and the angle of bevel) and the operating conditions having a bearing on the irregularity of the transported output stream.

  16. Sodium citrate assisted facile synthesis of AuPd alloy networks for ethanol electrooxidation with high activity and durability

    Science.gov (United States)

    Zhai, Yanling; Zhu, Zhijun; Lu, Xiaolin; Zhou, H. Susan

    2016-10-01

    The direct ethanol fuel cell is an emerging energy conversion device for which palladium is considered as the one of the most effective components for anode catalyst, however, its widespread application has been still limited by the activity and durability of the anode catalyst. In this work, AuPd alloy networks (NWs) are synthesized using H2PdCl4 and HAuCl4 as precursors reduced by NaBH4 in the presence of sodium citrate (SC). The results reveal that SC plays significant role in network structure, resulting in the enhanced electrocatalytic activity of the catalyst. This self-supported AuPd NWs catalyst exhibits much higher electrochemical catalytic activity than commercial Pd/C catalyst toward ethanol electrooxidation in alkaline solution. Significantly, AuPd NWs catalyst shows extremely high durability at the beginning of the chronoamperometry test, and as high as 49% of the mass current density (1.41 A/mgPd) remains after 4000 s current-time test at -0.3 V (vs. Ag/AgCl) in N2-saturated KOH-ethanol solution. This strategy provides a facile method for the preparation of alloy networks with high electrochemical activity, and can be potentially expanded to a variety of electrochemical applications.

  17. Hierarchically rough, mechanically durable and superhydrophobic epoxy coatings through rapid evaporation spray method

    International Nuclear Information System (INIS)

    Simovich, Tomer; Wu, Alex H.; Lamb, Robert N.

    2015-01-01

    A mechanically durable and scalable superhydrophobic coating was fabricated by combining the advantages of both bottom-up and top-down approaches into a one-pot, one-step application method. This is achieved by spray coating a solution consisting of silica nanoparticles, which are embedded within epoxy resin, onto a heated substrate to rapidly drive both solvent evaporation and curing simultaneously. By maintaining a high substrate temperature, the arrival of spray-delivered micrometer-sized droplets are rapidly cured onto the substrate to form surface microroughness, while simultaneously, rapid solvent evaporation within each droplet results in the formation of a nanoporous structure. SEM, dual-beam FIB, and cross-sectional TEM/EDAX elemental mapping were used to confirm both the chemistry and the requisite micro- and nano-porosity within the coating structure requisite for superhydrophobicity. The resultant coatings exhibit contact angles greater than 150° (153.8° ± 0.8°) and roll-off angles of 8° ± 2°, with a coating hardness of 6H on the pencil hardness scale, and a rating of 5 on an ASTM crosshatch test. - Highlights: • A highly superhydrophobic coating was fabricated utilizing epoxy and nanoparticles. • The coating was demonstrated to be very durable and abrasion resistant. • The fabrication involves a novel, scalable one-pot synthesis technique

  18. Hierarchically rough, mechanically durable and superhydrophobic epoxy coatings through rapid evaporation spray method

    Energy Technology Data Exchange (ETDEWEB)

    Simovich, Tomer; Wu, Alex H.; Lamb, Robert N., E-mail: rnlamb@unimelb.edu.au

    2015-08-31

    A mechanically durable and scalable superhydrophobic coating was fabricated by combining the advantages of both bottom-up and top-down approaches into a one-pot, one-step application method. This is achieved by spray coating a solution consisting of silica nanoparticles, which are embedded within epoxy resin, onto a heated substrate to rapidly drive both solvent evaporation and curing simultaneously. By maintaining a high substrate temperature, the arrival of spray-delivered micrometer-sized droplets are rapidly cured onto the substrate to form surface microroughness, while simultaneously, rapid solvent evaporation within each droplet results in the formation of a nanoporous structure. SEM, dual-beam FIB, and cross-sectional TEM/EDAX elemental mapping were used to confirm both the chemistry and the requisite micro- and nano-porosity within the coating structure requisite for superhydrophobicity. The resultant coatings exhibit contact angles greater than 150° (153.8° ± 0.8°) and roll-off angles of 8° ± 2°, with a coating hardness of 6H on the pencil hardness scale, and a rating of 5 on an ASTM crosshatch test. - Highlights: • A highly superhydrophobic coating was fabricated utilizing epoxy and nanoparticles. • The coating was demonstrated to be very durable and abrasion resistant. • The fabrication involves a novel, scalable one-pot synthesis technique.

  19. Adjuvant-enhanced CD4 T Cell Responses are Critical to Durable Vaccine Immunity

    Directory of Open Access Journals (Sweden)

    Karen A.O. Martins

    2016-01-01

    Full Text Available Protein-based vaccines offer a safer alternative to live-attenuated or inactivated vaccines but have limited immunogenicity. The identification of adjuvants that augment immunogenicity, specifically in a manner that is durable and antigen-specific, is therefore critical for advanced development. In this study, we use the filovirus virus-like particle (VLP as a model protein-based vaccine in order to evaluate the impact of four candidate vaccine adjuvants on enhancing long term protection from Ebola virus challenge. Adjuvants tested include poly-ICLC (Hiltonol, MPLA, CpG 2395, and alhydrogel. We compared and contrasted antibody responses, neutralizing antibody responses, effector T cell responses, and T follicular helper (Tfh cell frequencies with each adjuvant's impact on durable protection. We demonstrate that in this system, the most effective adjuvant elicits a Th1-skewed antibody response and strong CD4 T cell responses, including an increase in Tfh frequency. Using immune-deficient animals and adoptive transfer of serum and cells from vaccinated animals into naïve animals, we further demonstrate that serum and CD4 T cells play a critical role in conferring protection within effective vaccination regimens. These studies inform on the requirements of long term immune protection, which can potentially be used to guide screening of clinical-grade adjuvants for vaccine clinical development.

  20. Technology of combined chemical-mechanical fabrication of durable coatings

    Science.gov (United States)

    Smolentsev, V. P.; Ivanov, V. V.; Portnykh, A. I.

    2018-03-01

    The article presents the scientific fundamentals of methodology for calculating the modes and structuring the technological processes of combined chemical-mechanical fabrication of durable coatings. It is shown that they are based on classical patterns, describing the processes of simultaneous chemical and mechanical impact. The paper demonstrates the possibility of structuring a technological process, taking into account the systematic approach to impact management and strengthening the reciprocal positive influence of each impact upon the combined process. The combined processes have been planned for fabricating the model types of chemical-mechanical coatings of durable products in machine construction. The planning methodology is underpinned by a scientific hypothesis of a single source of impact management through energy potential of process components themselves, or by means of external energy supply through mechanical impact. The control of it is fairly thoroughly studied in the case of pulsed external strikes of hard pellets, similar to processes of vibroimpact hardening, thoroughly studied and mastered in many scientific schools of Russia.

  1. Durability test of geomembrane liners presumed to avail near surface disposal facilities for low-level waste generated from research, industrial and medical facilities

    International Nuclear Information System (INIS)

    Nakata, Hisakazu; Amazawa, Hiroya; Sakai, Akihiro; Kurosawa, Ryohei; Sakamoto, Yoshiaki; Kanno, Naohiro; Kashima, Takahiro

    2014-02-01

    The Low-level Radioactive Waste Disposal Project Center will construct near surface disposal facilities for radioactive wastes from research, industrial and medical facilities. The disposal facilities consist of “concrete pit type” for low-level radioactive wastes and “trench type” for very low level radioactive wastes. As for the trench type disposal facility, two kinds of facility designs are on projects – one for a normal trench type disposal facility without any of engineered barriers and the other for a trench type disposal facility with geomembrane liners that could prevent from causing environmental effects of non radioactive toxic materials contained in the waste packages. The disposal facility should be designed taking basic properties of durability on geomembrane liners into account, for it is exposed to natural environment on a long-term basis. This study examined mechanical strength and permeability properties to assess the durability on the basis of an indoor accelerated exposure experiment targeting the liner materials presumed to avail the conceptual design so far. Its results will be used for the basic and detailed design henceforth by confirming the empirical degradation characteristic with the progress of the exposure time. (author)

  2. Electro-active paper for a durable biomimetic actuator

    International Nuclear Information System (INIS)

    Yun, Sung-Ryul; Yun, Gyu Young; Kim, Jung Hwan; Chen, Yi; Kim, Jaehwan

    2009-01-01

    Cellulose electro-active paper (EAPap), known as a smart material, has merits in terms of low voltage operation, light weight, dryness, low power consumption, biodegradability, abundance and low price. Since EAPap requires low power consumption, a remotely driven actuator has been proposed using microwave power transmission. This concept is attractive for many biomimetic systems such as crawling micro-insect robots, flying objects like dragon flies and smart wallpapers. However, the actuation performance of EAPap is sensitive to humidity and degrades with time. Thus, in this paper, a durable EAPap is studied. The fabrication of EAPap is explained and the actuation performance is shown with applied electric field, frequency, humidity level and time. The fabrication process includes dissolving cellulose fibers, eliminating solvent and Li ions with a mixture of deionized water and isopropyl alcohol, washing with water, drying and coating with gold. The morphology of the fabricated EAPap is analyzed by taking scanning electron microscope images and x-ray diffractograms. The actuation performance is tested in terms of bending displacement with frequency, time and humidity level

  3. Durability of recycled aggregate concrete using pozzolanic materials.

    Science.gov (United States)

    Ann, K Y; Moon, H Y; Kim, Y B; Ryou, J

    2008-01-01

    In this study, pulverized fuel ash (PFA) and ground granulated blast furnace slag (GGBS) were used to compensate for the loss of strength and durability of concrete containing recycled aggregate. As a result, 30% PFA and 65% GGBS concretes increased the compressive strength to the level of control specimens cast with natural granite gravel, but the tensile strength was still lowered at 28 days. Replacement with PFA and GGBS was effective in raising the resistance to chloride ion penetrability into the concrete body, measured by a rapid chloride ion penetration test based on ASTM C 1202-91. It was found that the corrosion rate of 30% PFA and 65% GGBS concretes was kept at a lower level after corrosion initiation, compared to the control specimens, presumably due to the restriction of oxygen and water access. However, it was less effective in increasing the chloride threshold level for steel corrosion. Hence, it is expected that the corrosion time for 30% PFA and 65% GGBS concrete containing recycled aggregate mostly equates to the corrosion-free life of control specimens.

  4. THE PROBLEM OF ESTIMATING THE DURABILITY OF THE REINFORCED CONCRETE BRIDGES

    Directory of Open Access Journals (Sweden)

    O. I. Lantukh-Liashchenko

    2007-10-01

    Full Text Available This paper presents an assessment and prediction of service life for reinforced concrete bridges. The deterministic and probabilistic approach prediction models of durability are proposed.

  5. 40 CFR 86.1822-01 - Durability data vehicle selection.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Durability data vehicle selection. 86... PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty Vehicles, Light...

  6. The durability and mechanical strenght properties of bamboo in ...

    African Journals Online (AJOL)

    The durability and mechanical strenght properties of bamboo in reinforced concrete. GA Alade, FA Olutoge, AA Alade. Abstract. No Abstract. Journal of Applied Science, Engineering and Technology Vol. 4(2) 2004: 35-40. Full Text: EMAIL FULL TEXT EMAIL FULL TEXT · DOWNLOAD FULL TEXT DOWNLOAD FULL TEXT.

  7. AGRICULTURE DURABLE De nouvelles pratiques sont source de ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    17 nov. 2010 ... Depuis 1970, les travaux de recherche soutenus par le CRDI ont permis à des agriculteurs et à des collectivités de pays en développement d'adopter des pratiques agricoles durables. Le résultant? Une productivité accrue, un recul de la pauvreté, une plus grande sécurité alimentaire et un environnement ...

  8. Durability of saw-cut joints in plain cement concrete pavements.

    Science.gov (United States)

    2011-01-01

    The objective of this project was to evaluate factors influencing the durability of the joints in portland cement concrete : pavement in the state of Indiana. Specifically this work evaluated the absorption of water, the absorption of deicing solutio...

  9. Improving the Efficiency and Durability of Reversible Solid Oxide Cells for Energy Storage

    Science.gov (United States)

    Hughes, Gareth Allen

    This thesis presents research on the use of solid oxide cells (SOCs) as energy storage devices, and covers methods to improve their efficiency and durability for this use. It specifically covers two main topics: the durability of the oxygen electrode under forced alternating current, and the effect of pressurization on various oxygen electrode materials. Additionally, research was completed on thermodynamic modeling of a pressurized SOC energy storage system, and a new experimental testing apparatus was constructed to enable investigation of SOC samples operating under pressure. Forced alternating current using a symmetric sample structure was used to simulate the operation of a reversible SOC, effectively isolating the measurement of the performance response of the oxygen electrode. Cells consisting of La 0.8Sr0.2MnO3-delta - 8mol% Y2O 3-stabilized ZrO2 (LSM-YSZ) oxygen electrodes on YSZ electrolytes were tested. Early testing utilizing Ag current collectors showed that forced currents and the elevated operating temperature of SOCs cause silver to vaporize and deposit at the active region of the electrode. To avoid this artifact, a new test setup utilizing LSM current collectors was created. It was found that a shorter current cycling time of 1 hour helps prevent degradation compared to 12 hour cycles. Additionally, both cycling times showed improvement compared cells operated with dc current. Further study showed that operating at current densities of 0.8 A/cm2 and below can prevent degradation entirely. Pressurization of oxygen electrodes showed, as expected, that polarization resistance decreases with increasing oxygen pressure. The materials tested were LSM-YSZ and La0.6Sr0.4Fe0.8Co0.2 O3-d - Ce0.8Gd0.2O1.95 (LSCF-GDC), both in single-phase and composite electrode structures. Additionally, LSM-infiltrated YSZ was tested. The resistance typically decreased following power-law behavior with exponents ranging from -0.17 to -0.30, with similar trends found in all

  10. New Method to Synthesize Highly Active and Durable Chemically Ordered fct-PtCo Cathode Catalyst for PEMFCs.

    Science.gov (United States)

    Jung, Won Suk; Popov, Branko N

    2017-07-19

    In the bottom-up synthesis strategy performed in this study, the Co-catalyzed pyrolysis of chelate-complex and activated carbon black at high temperatures triggers the graphitization reaction which introduces Co particles in the N-doped graphitic carbon matrix and immobilizes N-modified active sites for the oxygen reduction reaction (ORR) on the carbon surface. In this study, the Co particles encapsulated within the N-doped graphitic carbon shell diffuse up to the Pt surface under the polymer protective layer and forms a chemically ordered face-centered tetragonal (fct) Pt-Co catalyst PtCo/CCCS catalyst as evidenced by structural and compositional studies. The fct-structured PtCo/CCCS at low-Pt loading (0.1 mg Pt cm -2 ) shows 6% higher power density than that of the state-of-the-art commercial Pt/C catalyst. After the MEA durability test of 30 000 potential cycles, the performance loss of the catalyst is negligible. The electrochemical surface area loss is less than 40%, while that of commercial Pt/C is nearly 80%. After the accelerated stress test, the uniform catalyst distribution is retained and the mean particle size increases approximate 1 nm. The results obtained in this study indicated that highly stable compositional and structural properties of chemically ordered PtCo/CCCS catalyst contribute to its exceptional catalyst durability.

  11. Fused Microknot Optical Resonators in Folded Photonic Tapers for in-Liquid Durable Sensing

    Directory of Open Access Journals (Sweden)

    Alexandra Logvinova

    2018-04-01

    Full Text Available Optical microknot fibers (OMFs serve as localized devices, where photonic resonances (PRs enable self-interfering elements sensitive to their environment. However, typical fragility and drifting of the knot severely limit the performance and durability of microknots as sensors in aqueous settings. Herein we present the fabrication, electrical fusing, preparation, and persistent detection of volatile liquids in multiple wetting–dewetting cycles of volatile compounds and quantify the persistent phase shifts with a simple model relating to the ambient liquid, enabling durable in-liquid sensing employing OMF PRs.

  12. The identification and treatment of poor durability Karoo dolerite base course aggregate – evidence from case studies

    CSIR Research Space (South Africa)

    Leyland, RC

    2016-03-01

    Full Text Available that the poor performance of the case study materials was likely due to the poor durability of the materials, manifesting as a reduction in resistance to abrasion and attrition. The identification of the observed poor durability could not have been performed...

  13. Durability Evolution of RC Bridge under Coupling Action of Chloride Corrosion and Carbonization Based on DLA Model

    Directory of Open Access Journals (Sweden)

    Haoxiang He

    2015-01-01

    Full Text Available Chloride attack and carbonization are the main factors which affect the durability of concrete structures, and the respective theoretical models are systematically established. However, the quantitative analysis and models about the coupling effect of chloride attack and carbonization are less, so the precision and level of durability analysis of reinforced concrete are restricted. Diffusion-limited aggregation (DLA model can finely simulate the process of gas diffusion and condensation with randomness and fractal characteristics, which is suitable for revealing the durability evolution process of the chloride attack, carbonization, and the coupling action in concrete. Based on the principle of DLA, considering the factors such as diffusion depth, concrete properties, and exposure conditions which influence the characteristics of chloride diffusion and carbonization, as well as the coupling effect, an integrated DLA model is established. The concentration of carbon dioxide and chloride at any time and any location can be obtained and dynamically displayed based on the DLA model. The performance predict method for concrete and steel bars considering fatigue effect is presented based on DLA, according to the demand for bridge durability analysis. Numerical examples show that the method can dynamically and intensively simulate the durability evolution process of reinforced concrete bridge.

  14. Durability and safety of concrete structures in the nuclear context. The case of the containment vessel

    Energy Technology Data Exchange (ETDEWEB)

    Torrenti, J.M. [Universite Paris Est, LCPC (France); Nahas, G. [IRSN/DSR (France)

    2011-07-01

    The durability of structures, because of its economic and environmental implications, is one of the actual hot topics in civil engineering. In the field of nuclear energy, we are facing very challenging problems like: how could we prolong the service life of actual nuclear containments and how can we assure the durability of a radioactive storage on the very long term (several centuries)? These already difficult questions in a classical civil engineering view are even more complicated in the field of nuclear energy where the structures are massive and the safety of the installations has to be considered. For the containment of nuclear power plants, these stakes will be lit with some examples of research concerning the mechanical behaviour of concrete and concrete structures (at early age, in service on long scales of time and in the event of an accident), the durability of the concrete structures (leaching, swelling due to delayed ettringite formation - DEF -) and the couplings between mechanics and durability. Finally, the importance of probabilistic aspects and the inherent difficulties will be shown. (authors)

  15. Durability and safety of concrete structures in the nuclear context. The case of the containment vessel

    International Nuclear Information System (INIS)

    Torrenti, J.M.; Nahas, G.

    2011-01-01

    The durability of structures, because of its economic and environmental implications, is one of the actual hot topics in civil engineering. In the field of nuclear energy, we are facing very challenging problems like: how could we prolong the service life of actual nuclear containments and how can we assure the durability of a radioactive storage on the very long term (several centuries)? These already difficult questions in a classical civil engineering view are even more complicated in the field of nuclear energy where the structures are massive and the safety of the installations has to be considered. For the containment of nuclear power plants, these stakes will be lit with some examples of research concerning the mechanical behaviour of concrete and concrete structures (at early age, in service on long scales of time and in the event of an accident), the durability of the concrete structures (leaching, swelling due to delayed ettringite formation - DEF -) and the couplings between mechanics and durability. Finally, the importance of probabilistic aspects and the inherent difficulties will be shown. (authors)

  16. A durability model incorporating safe life methodology and damage tolerance approach to assess first inspection and maintenance period for structures

    Energy Technology Data Exchange (ETDEWEB)

    Xiong, J.J. [Aircraft Department, Beihang University, Beijing 100083 (China); Shenoi, R.A. [School of Engineering Sciences, University of Southampton, Southampton SO17 1BJ (United Kingdom)], E-mail: r.a.shenoi@ship.soton.ac.uk

    2009-08-15

    This paper outlines a new durability model to assess the first inspection and maintenance period for structures. Practical scatter factor formulae are presented to determine the safe fatigue crack initiation and propagation lives from the results of a single full-scale test of a complete structure. New theoretical solutions are proposed to determine the s{sub a}-s{sub m}-N surfaces of fatigue crack initiation and propagation. Prediction techniques are then developed to establish the relationship equation between safe fatigue crack initiation and propagation lives with a specific reliability level using a two-stage fatigue damage cumulative rule. A new durability model incorporating safe life and damage tolerance design approaches is derived to assess the first inspection and maintenance period. Finally, the proposed models are applied to assess the first inspection and maintenance period of a fastening structure at the root of helicopter blade.

  17. Mankiw's Puzzle on Consumer Durables: A Misspecification

    OpenAIRE

    Tam Bang Vu

    2005-01-01

    Mankiw (1982) shows that consumer durables expenditures should follow a linear ARMA(1,1) process, but the data analyzed supports an AR(1) process instead; thus, a puzzle. In this paper, we employ a more general utility function than Mankiw's quadratic one. Further, the disturbance and depreciation rate are respecified, respectively, as multiplicative and stochastic. The analytical consequence is a nonlinear ARMA(infinity,1) process, which implies that the linear ARMA(1,1) is a misspecificatio...

  18. ICP experiments more durable pavements

    International Nuclear Information System (INIS)

    Carta Petrolera

    1994-01-01

    A new asphalts technology that will make more durable the pavement in the highways and roads of the cities of Colombia investigates the Colombian Institute of the Petroleum ICP. The project that will have important incidence in the solution of one of the main problems in the roads of cities like Bogota, is only one of the 35 investigation programs and application of new technologies that with relationship to the sector of the hydrocarbons and its influence branches the ICP advances. The investigation looks for to elevate the current average of useful life of the pavements, with that it would be reached a standard that has the developed countries in this field

  19. Asphalt durability and self-healing modelling with discrete particles approach

    NARCIS (Netherlands)

    Magnanimo, V.; ter Huerne, H.L.; Luding, S.; Scarpas, A.; Kringos, N.; Al-Qadi, I.; Loizos, A.

    2012-01-01

    Asphalt is an important road paving material, where besides an acceptable price, durability, surface conditions (like roughening and evenness), age-, weather- and traffic-induced failures and degradation are relevant aspects. In the professional road engineering branch empirical models are used to

  20. Durable superhydrophobic carbon soot coatings for sensor applications

    Science.gov (United States)

    Esmeryan, K. D.; Radeva, E. I.; Avramov, I. D.

    2016-01-01

    A novel approach for the fabrication of durable superhydrophobic (SH) carbon soot coatings used in quartz crystal microbalance (QCM) based gas or liquid sensors is reported. The method uses modification of the carbon soot through polymerization of hexamethyldisiloxane (HMDSO) by means of glow discharge RF plasma. The surface characterization shows a fractal-like network of carbon nanoparticles with diameter of ~50 nm. These particles form islands and cavities in the nanometer range, between which the plasma polymerized hexamethyldisiloxane (PPHMDSO) embeds and binds to the carbon chains and QCM surface. Such modified surface structure retains the hydrophobic nature of the soot and enhances its robustness upon water droplet interactions. Moreover, it significantly reduces the insertion loss and dynamic resistance of the QCM compared to the commonly used carbon soot/epoxy resin approach. Furthermore, the PPHMDSO/carbon soot coating demonstrates durability and no aging after more than 40 probing cycles in water based liquid environments. In addition, the surface layer keeps its superhydrophobicity even upon thermal annealing up to 540 °C. These experiments reveal an opportunity for the development of soot based SH QCMs with improved electrical characteristics, as required for high-resolution gas or liquid measurements.

  1. Gallium oxide nanorods as novel, safe and durable anode material for Li- and Na-ion batteries

    International Nuclear Information System (INIS)

    Meligrana, Giuseppina; Lueangchaichaweng, Warunee; Colò, Francesca; Destro, Matteo; Fiorilli, Sonia; Pescarmona, Paolo P.; Gerbaldi, Claudio

    2017-01-01

    Highlights: • Gallium oxide nanorods applied for the first time as anode material for Li-/Na-ion batteries. • Durable ambient temperature cycling (400 cycles) was observed in Li-based cells. • Stable reversible cycling (> 200 mAh g"−"1) was achieved for the first time in Na-based cells. - Abstract: Gallium oxide nanorods prepared by template-free synthesis are reported for the first time as safe and durable anode material for lithium- and sodium-ion batteries. The ambient temperature electrochemical response of the nanorods, tested by cyclic voltammetry and constant-current reversible cycling, is highly satisfying in terms of remarkable stability and capacity retention upon long-term operation (400 cycles), even at high current densities. The newly proposed application of gallium oxide nanorods as electrode material is notable also because this material can preserve the electrical pathway without the need of any “buffer matrix” to compensate for the expansion upon lithium or sodium reversible storage. The highly promising electrochemical performance is attributed to the high aspect ratio and high surface area that stem from the nanorod morphology and which can lead to short diffusion path and fast kinetics of both cations (Li"+ or Na"+) and electrons.

  2. Liquidus temperature and chemical durability of selected glasses to immobilize rare earth oxides waste

    Energy Technology Data Exchange (ETDEWEB)

    Mohd Fadzil, Syazwani, E-mail: mfsyazwani86@postech.ac.kr [Division of Advanced Nuclear Engineering, Pohang University of Science and Technology, 790784 Pohang, Gyeongbuk (Korea, Republic of); School of Applied Physics, Faculty of Science and Technology, The National University of Malaysia, 43650 Bandar Baru Bangi, Selangor (Malaysia); Hrma, Pavel [Division of Advanced Nuclear Engineering, Pohang University of Science and Technology, 790784 Pohang, Gyeongbuk (Korea, Republic of); Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA (United States); Schweiger, Michael J.; Riley, Brian J. [Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA (United States)

    2015-10-15

    Pyroprocessing is are processing method for managing and reusing used nuclear fuel (UNF) by dissolving it in an electrorefiner with a molten alkali or alkaline earth chloride salt mixture while avoiding wet reprocessing. Pyroprocessing UNF with a LiCl–KCl eutectic salt releases the fission products from the fuel and generates a variety of metallic and salt-based species, including rare earth (RE) chlorides. If the RE-chlorides are converted to oxides, borosilicate glass is a prime candidate for their immobilization because of its durability and ability to dissolve almost any RE waste component into the glass matrix at high loadings. Crystallization that occurs in waste glasses as the waste loading increases may complicate glass processing and affect the product quality. This work compares three types of borosilicate glasses in terms of liquidus temperature (T{sub L}): the International Simple Glass designed by the International Working Group, sodium borosilicate glass developed by Korea Hydro and Nuclear Power, and the lanthanide aluminoborosilicate (LABS) glass established in the United States. The LABS glass allows the highest waste loadings (over 50 mass% RE{sub 2}O{sub 3}) while possessing an acceptable chemical durability. - Highlights: • We investigated crystallization in borosilicate glasses containing rare earth oxides. • New crystallinity and durability data are shown for glasses proposed in the literature. • Both liquidus temperature and chemical durability increased as the waste loading increased.

  3. Relationship between enamel bond fatigue durability and surface free-energy characteristics with universal adhesives.

    Science.gov (United States)

    Nagura, Yuko; Tsujimoto, Akimasa; Barkmeier, Wayne W; Watanabe, Hidehiko; Johnson, William W; Takamizawa, Toshiki; Latta, Mark A; Miyazaki, Masashi

    2018-04-01

    The relationship between enamel bond fatigue durability and surface free-energy characteristics with universal adhesives was investigated. The initial shear bond strengths and shear fatigue strengths of five universal adhesives to enamel were determined with and without phosphoric acid pre-etching. The surface free-energy characteristics of adhesive-treated enamel with and without pre-etching were also determined. The initial shear bond strength and shear fatigue strength of universal adhesive to pre-etched enamel were higher than those to ground enamel. The initial shear bond strength and shear fatigue strength of universal adhesive to pre-etched enamel were material dependent, unlike those to ground enamel. The surface free-energy of the solid (γ S ) and the hydrogen-bonding force (γSh) of universal adhesive-treated enamel were different depending on the adhesive, regardless of the presence or absence of pre-etching. The bond fatigue durability of universal adhesives was higher to pre-etched enamel than to ground enamel. In addition, the bond fatigue durability to pre-etched enamel was material dependent, unlike that to ground enamel. The surface free-energy characteristics of universal adhesive-treated enamel were influenced by the adhesive type, regardless of the presence or absence of pre-etching. The surface free-energy characteristics of universal adhesive-treated enamel were related to the results of the bond fatigue durability. © 2018 Eur J Oral Sci.

  4. Effects of crystallization on thermal properties and chemical durability of the glasses containing simulated high level radioactive wastes

    International Nuclear Information System (INIS)

    Kawamoto, Takamichi; Terai, Ryohei; Hara, Shigeo

    1978-01-01

    In order to improve the thermodynamic stability of the glasses containing high level radioactive wastes, the conversion to glass-ceramics by the heat-treatment was carried out with two kinds of glasses, and the change of thermal properties and chemical durability by crystallization was investigated. One of the glasses has a composition of SiO 2 -Al 2 O 3 -ZnO-TiO 2 system, and another one has a composition which could grow the nephelite crystals from Na 2 O in wastes and Al 2 O 3 and SiO 2 added as glass-forming materials. Transition and yield points shifted to higher temperatures by the conversion and the glass-ceramics were found to be more stable than the original glasses. The glass-ceramics of the composition of SiO 2 -Al 2 O 3 -ZnO-TiO 2 showed poor durability, whereas the chemical durability of the glass-ceramics containing nephelite crystals was considerably improved. In the latter case, improvement of the durability is attributable to that some parts of glass are converted to nephelite crystals and the crystals are more durable than glass under most conditions. (auth.)

  5. Elastocaloric effect vs fatigue life: Exploring the durability limits of Ni-Ti sheets under pre-strain conditions for elastocaloric cooling

    DEFF Research Database (Denmark)

    Tusek, Jaka; Zerovnik, Andrej; Cebron, Matjaz

    2018-01-01

    that on polished samples, durable operation of 105 cycles can be reached with a strain amplitude of 0.50% at the loading plateau, which corresponds to adiabatic temperature changes of approximately 5 K. At the unloading plateau (after initial pre-strain of 10%), durable operation was reached at a strain amplitude...... for the design and operation of efficient and durable elastocaloric devices in the future....

  6. Comparison of enamel bond fatigue durability between universal adhesives and two-step self-etch adhesives: Effect of phosphoric acid pre-etching.

    Science.gov (United States)

    Suda, Shunichi; Tsujimoto, Akimasa; Barkmeier, Wayne W; Nojiri, Kie; Nagura, Yuko; Takamizawa, Toshiki; Latta, Mark A; Miyazaki, Masashi

    2018-03-30

    The effect of phosphoric acid pre-etching on enamel bond fatigue durability of universal adhesives and two-step self-etch adhesives was investigated. Four universal adhesives and three two-step self-etch adhesives were used. The initial shear bond strengths and shear fatigue strengths to enamel with and without phosphoric acid pre-etching using the adhesives were determined. SEM observations were also conducted. Phosphoric acid pre-etching of enamel was found to increase the bond fatigue durability of universal adhesives, but its effect on two-step self-etch adhesives was material-dependent. In addition, some universal adhesives with phosphoric acid pre-etching showed similar bond fatigue durability to the two-step self-etch adhesives, although the bond fatigue durability of universal adhesives in self-etch mode was lower than that of the two-step self-etch adhesives. Phosphoric acid pre-etching enhances enamel bond fatigue durability of universal adhesives, but the effect of phosphoric acid pre-etching on the bond fatigue durability of two-step self-etch adhesives was material-dependent.

  7. The influence of fly ash as substitute of cement in the durability of concrete

    OpenAIRE

    Molina Bas, Omar I.; Moragues Terrades, Amparo; Gálvez Ruíz, Jaime; Guerrero Bustos, Ana

    2008-01-01

    Limitation of transport capacity through the concrete is one of the key points in the improvement of the material’s durability. The use of fly ash as an admixture to concrete is widely extended; a general consensus has been established due to the pore size reduction produced by the ashes. Nevertheless, the importance of the micro-structural and composition changes in mechanical and durable properties is not well defined. In the present study the use of fly ash has been considered as substitut...

  8. Relational Benefit on Satisfaction and Durability in Strategic Corporate Social Responsibility

    Directory of Open Access Journals (Sweden)

    Minseok Kim

    2018-04-01

    Full Text Available These days, companies are moving from Corporate Social Responsibility (CSR activities for short-term profit generation to the ones for achieving economic and social long-term goals. This phenomenon results from the idea that CSR is not a mere cost but can be used as a source of opportunity, innovation and competitive advantage. Deemed as a great business strategy, strategic CSR activities are being emphasized by various stakeholders in the global market. The purpose of this study is to present specific implications and to empirically research the relations among relational benefits, commitment, and authenticity. It identifies the main factors of relationship management in expanding the stakeholder pool and forming relationships for strategic CSR activities. To this end, we conducted a questionnaire survey of 113 CSR practitioners in Korea and analyzed how social, psychological, and economic benefits affect the satisfaction and durability of strategic CSR activities through relational commitment and authenticity. Consequently, social, psychological, and economic benefits have an impact on relationships and, by extension, have a positive effect on relational satisfaction and durability. However, economic benefits affect relational authenticity, but social and psychological benefits do not. As a result, relational benefits cannot affect satisfaction through relationships. Therefore, relational benefits and commitment are more important variables for the satisfaction and durability of strategic CSR activities.

  9. Assessment of cement durability in repository environment

    International Nuclear Information System (INIS)

    Ferreira, E.G.A.; Vicente, R.; Isiko, V.L.K.; Miyamoto, H.; Marumo, J.T.; Gobbo, L.A.

    2015-01-01

    The present research aimed at investigating the durability of cement paste under nuclear waste repository conditions using accelerated tests. Cement paste samples are examined after being exposed to the environmental conditions that are expected to prevail in the repository environment and the results are compared with those obtained with unexposed specimens or specimens exposed to reference conditions. The following exposure conditions were selected: a) Immersion in salt solution, distilled water, or kept in dry storage; b) Room temperature (20 C. degrees) or high temperature (60 C. degrees); c) Immersion time of 30 days or 60 days (not for dry storage); d) Irradiation to a dose of (400 kGy) or background radiation (0 kGy). After exposure to the stressing conditions, the effects of each factor on the cement paste samples were observed by changes in their characteristics. Compressive strength tests were performed on all samples and some of them were investigated in terms of changes in mineralogy by X-ray diffraction (XRD) and thermo-gravimetric analysis (TGA). With the results obtained so far it was possible to point out the following conclusions. First, after a period of immersion in water, cement paste samples further hydrated and presented higher mechanical resistance, as expected. Secondly, dry storage did not allow a complete hydration as a consequence of pore water evaporation. High temperatures intensified this process and led to the ettringite decomposition to meta-ettringite. Thirdly, higher temperature accelerated hydration kinetics and promoted higher mechanical resistance in samples kept under immersion. Fourthly, the irradiation dose applied was unable to change the mineralogy of cement paste samples and fifthly, no statistically significant differences were observed between 30 or 60 days exposure time, for the test conditions

  10. The durability of public goods changes the dynamics and nature of social dilemmas.

    Directory of Open Access Journals (Sweden)

    Sam P Brown

    Full Text Available An implicit assumption underpins basic models of the evolution of cooperation, mutualism and altruism: The benefits (or pay-offs of cooperation and defection are defined by the current frequency or distribution of cooperators. In social dilemmas involving durable public goods (group resources that can persist in the environment-ubiquitous from microbes to humans this assumption is violated. Here, we examine the consequences of relaxing this assumption, allowing pay-offs to depend on both current and past numbers of cooperators. We explicitly trace the dynamic of a public good created by cooperators, and define pay-offs in terms of the current public good. By raising the importance of cooperative history in determining the current fate of cooperators, durable public goods cause novel dynamics (e.g., transient increases in cooperation in Prisoner's Dilemmas, oscillations in Snowdrift Games, or shifts in invasion thresholds in Stag-hunt Games, while changes in durability can transform one game into another, by moving invasion thresholds for cooperation or conditions for coexistence with defectors. This enlarged view challenges our understanding of social cheats. For instance, groups of cooperators can do worse than groups of defectors, if they inherit fewer public goods, while a rise in defectors no longer entails a loss of social benefits, at least not in the present moment (as highlighted by concerns over environmental lags. Wherever durable public goods have yet to reach a steady state (for instance due to external perturbations, the history of cooperation will define the ongoing dynamics of cooperators.

  11. Corrosion resistance and durability of superhydrophobic surface formed on magnesium alloy coated with nanostructured cerium oxide film and fluoroalkylsilane molecules in corrosive NaCl aqueous solution.

    Science.gov (United States)

    Ishizaki, Takahiro; Masuda, Yoshitake; Sakamoto, Michiru

    2011-04-19

    The corrosion resistant performance and durability of the superhydrophobic surface on magnesium alloy coated with nanostructured cerium oxide film and fluoroalkylsilane molecules in corrosive NaCl aqueous solution were investigated using electrochemical and contact angle measurements. The durability of the superhydrophobic surface in corrosive 5 wt% NaCl aqueous solution was elucidated. The corrosion resistant performance of the superhydrophobic surface formed on magnesium alloy was estimated by electrochemical impedance spectroscopy (EIS) measurements. The EIS measurements and appropriate equivalent circuit models revealed that the superhydrophobic surface considerably improved the corrosion resistant performance of magnesium alloy AZ31. American Society for Testing and Materials (ASTM) standard D 3359-02 cross cut tape test was performed to investigate the adhesion of the superhydrophobic film to the magnesium alloy surface. The corrosion formation mechanism of the superhydrophobic surface formed on the magnesium alloy was also proposed. © 2011 American Chemical Society

  12. Durability of reinforced concrete beams strengthened with fiber reinforced polymers under varying environmental conditions

    International Nuclear Information System (INIS)

    El-Sadani, R.A.M.G

    2008-01-01

    Fiber reinforced polymers (FRP) materials were adopted by the aerospace and marine industries, not only for their lightweight and high strength characteristics but also due to their tough and durable nature . As the engineering community has become more familiar with the performance advantages of these materials, new applications have been investigated and implemented. Researches and design guidelines concluded that externally bonded FRP to concrete elements could efficiently increase the capacity of RC elements. Long-term exposure to harsh environments deteriorates concrete and the need for repair and rehabilitation is evident. In order to accept these FRP materials, they must be evaluated for durability in harsh environments. An experimental program was conducted at the materials laboratory- faculty of engineering-Ain Shams university to study the durability of RC beams strengthened with FRP sheets and to compare them with un strengthened beams.The effect of gamma rays on FRP materials and concrete specimens bonded to FRP sheets were also investigated.

  13. Demaria C., 2004, Développement durable et finance, Paris : Maxima Laurent du Mesnil Editeur, 255 p.

    Directory of Open Access Journals (Sweden)

    Marianne Rubinstein

    2005-05-01

    Full Text Available L’objectif de l’ouvrage de Cyril Demaria est de mettre à jour le lien existant entre développement durable et logique financière, de traiter du paradoxe apparent selon lequel la transition des sociétés vers le développement durable doit plus aux forces de marché qu’à toute autre dynamique : « le fait que les principaux leviers au service du développement durable soient les fonds d’investissement et les marchés financiers rompt donc avec une vision ‘révolutionnaire’ associée au développement d...

  14. Thermal Conductivity and Erosion Durability of Composite Two-Phase Air Plasma Sprayed Thermal Barrier Coatings

    Science.gov (United States)

    Schmitt, Michael P.; Rai, Amarendra K.; Zhu, Dongming; Dorfman, Mitchell R.; Wolfe, Douglas E.

    2015-01-01

    To enhance efficiency of gas turbines, new thermal barrier coatings (TBCs) must be designed which improve upon the thermal stability limit of 7 wt% yttria stabilized zirconia (7YSZ), approximately 1200 C. This tenant has led to the development of new TBC materials and microstructures capable of improved high temperature performance. This study focused on increasing the erosion durability of cubic zirconia based TBCs, traditionally less durable than the metastable t' zirconia based TBCs. Composite TBC microstructures composed of a low thermal conductivity/high temperature stable cubic Low-k matrix phase and a durable t' Low-k secondary phase were deposited via APS. Monolithic coatings composed of cubic Low-k and t' Low-k were also deposited, in addition to a 7YSZ benchmark. The thermal conductivity and erosion durability were then measured and it was found that both of the Low-k materials have significantly reduced thermal conductivities, with monolithic t' Low-k and cubic Low-k improving upon 7YSZ by approximately 13 and approximately 25%, respectively. The 40 wt% t' Low-k composite (40 wt% t' Low-k - 60 wt% cubic Low-k) showed a approximately 22% reduction in thermal conductivity over 7YSZ, indicating even at high levels, the t' Low-k secondary phase had a minimal impact on thermal in the composite coating. It was observed that a mere 20 wt% t' Low-k phase addition can reduce the erosion of a cubic Low-k matrix phase composite coating by over 37%. Various mixing rules were then investigated to assess this non-linear composite behavior and suggestions were made to further improve erosion durability.

  15. 76 FR 35950 - Agency Information Collection Activity (Living Will and Durable Power of Attorney for Health Care...

    Science.gov (United States)

    2011-06-20

    ... (Living Will and Durable Power of Attorney for Health Care) Under OMB Review AGENCY: Department of... INFORMATION Title: Living Will and Durable Power of Attorney for Health Care, VA Form 10-0137. OMB Control... about his or her medical treat and to record specific instructions about their treatment preferences in...

  16. Durability and plasticity of a material under different trajectories cycle loading in dependence on the loading prehistory

    International Nuclear Information System (INIS)

    Mozharovskij, N.S.; Bobyr', N.I.

    1979-01-01

    Results of investigations into the durability and plasticity of a material under combined proportional cyclic loading over different trajectories depending upon the values of intensity of preliminary plastic deformation obtained by different loading methods are presented. The effect of loading prehistory type on material plastic properties and its durability are shown

  17. Durability and plasticity of a material under different trajectories cycle loading in dependence on the loading prehistory

    Energy Technology Data Exchange (ETDEWEB)

    Mozharovskii, N S; Bobyr, N I [Kievskij Politekhnicheskij Inst. (Ukrainian SSR)

    1979-12-01

    Results of investigations into the durability and plasticity of a material under combined proportional cyclic loading over different trajectories depending upon the values of intensity of preliminary plastic deformation obtained by different loading methods are presented. The effect of loading prehistory type on material plastic properties and its durability are shown.

  18. Evaluation of curing compound application time on concrete surface durability : [brief].

    Science.gov (United States)

    2015-05-01

    Roadways that are both durable and aesthetically pleasing are primary goals of Wisconsin : Department of Transportation (WisDOT) paving projects. Recently, Portland Cement Concrete : (PCC) pavement projects constructed by WisDOT have experienced incr...

  19. Influence of degradation conditions on dentin bonding durability of three universal adhesives.

    Science.gov (United States)

    Sai, Keiichi; Shimamura, Yutaka; Takamizawa, Toshiki; Tsujimoto, Akimasa; Imai, Arisa; Endo, Hajime; Barkmeier, Wayne W; Latta, Mark A; Miyazaki, Masashi

    2016-11-01

    This study aims to determine dentin bonding durability of universal adhesives using shear bond strength (SBS) tests under various degradation conditions. G-Premio Bond (GP, GC), Scotchbond Universal (SU, 3M ESPE) and All Bond Universal (AB, Bisco) were compared with conventional two-step self-etch adhesive Clearfil SE Bond (SE, Kuraray Noritake Dental). Bonded specimens were divided into three groups of ten, and SBSs with bovine dentin were determined after the following treatments: 1) Storage in distilled water at 37°C for 24h followed by 3000, 10,000, 20,000 or 30,000 thermal cycles (TC group), 2) Storage in distilled water at 37°C for 3 months, 6 months or 1year (water storage, WS group) and 3) Storage in distilled water at 37°C for 24h (control). SE bonded specimens showed significantly higher SBSs than universal adhesives, regardless of TC or storage periods, although AB specimens showed significantly increased SBSs after 30,000 thermal cycles. In comparisons of universal adhesives under control and degradation conditions, SBS was only reduced in SU after 1year of WS. Following exposure of various adhesive systems to degradation conditions of thermal cycling and long term storage, SBS values of adhesive systems varied primarily with degradation period. Although universal adhesives have lower SBSs than the two-step self-etch adhesive SE, the present data indicate that the dentin bonding durability of universal adhesives in self-etch mode is sufficient for clinical use. Copyright © 2016 Elsevier Ltd. All rights reserved.

  20. Moving towards a virtual durability of vehicles; Auf dem Weg zur virtuellen Festigkeit im Fahrzeugbau

    Energy Technology Data Exchange (ETDEWEB)

    Heuler, P.; Birk, O.; Beste, A. [Audi AG, Ingolstadt (Germany). Abt. I/EG-32

    2001-04-01

    The dualism of experimental and virtual durability assessment is addressed. The possibilities and limitations of the virtual concepts are discussed with regard to the different steps of the durability assessment. It is outlined from a user's point of view where the use of these concepts is presently seen. It is important to rate the potentials of each step ranging from the definition of load requirements to the life time calculation. (orig.)

  1. Energy and durable development: the place of the renewable energies; Energie et developpement durable: la place des energies renouvelables

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    The 29 may 2000, took place at the UNESCO, a colloquium on the place of the renewable energies facing the economic development. This document presents the opening presentation of A. Antolini and L. Jospin and the colloquium papers and debates in the following four domains: the energy challenges of the durable development, the renewable energies sources facing the european directive, the thermal renewable energies (solar, geothermics and biomass) and the greenhouse effect, the world market of the renewable energies. (A.L.B.)

  2. Catalytic performance and durability of Ni/AC for HI decomposition in sulfur–iodine thermochemical cycle for hydrogen production

    International Nuclear Information System (INIS)

    Fu, Guangshi; He, Yong; Zhang, Yanwei; Zhu, Yanqun; Wang, Zhihua; Cen, Kefa

    2016-01-01

    Highlights: • The relation between Ni content and Ni particle dispersion were disclosed. • The effect of Ni content on the catalytic activity of Ni/AC catalyst was revealed. • The optimal content of Ni for Ni/AC catalysts in HI decomposition was found. - Abstract: This work reports the Ni content effect on the Ni/AC catalytic performance in the HI decomposition reaction of the sulfur–iodine (SI) thermochemical cycle for hydrogen production and the Ni/AC catalyst durability in a long-term test. Accordingly, five catalysts with the Ni content ranging from 5% to 15% were prepared by an incipient-wetness impregnation method. The activity of all catalysts was examined under the temperature range of 573–773 K. The catalytic performance evaluation suggests that Ni content plays a significant role in the Ni dispersion, Ni particle size, and eventually the catalytic activity in HI decomposition. 12% is the optimal Ni content for Ni/AC catalysts in HI decomposition which is balanced between poor dispersion of Ni particles and increasing active center. The results of 24 h durability test, which incorporated with BET and TEM investigations of the 12%Ni/AC catalyst before and after the reaction, indicate that establishing a better Ni particle dispersion pattern and improving the stability of Ni particles on the support should be considered in the future.

  3. Durable superhydrophobic and superoleophilic filter paper for oil–water separation prepared by a colloidal deposition method

    International Nuclear Information System (INIS)

    Du, Chuan; Wang, Jiadao; Chen, Zhifu; Chen, Darong

    2014-01-01

    Graphical abstract: - Highlights: • A method for fabricating durable superhydrophobic filter paper was developed. • Oil–water separation efficiency exceeds 99% using the as-prepared filter paper. • The as-prepared filter paper has good recyclability and durability. • The method is easy, low cost and can be industrialized. - Abstract: A method for manufacturing durable superhydrophobic and superoleophilic filter paper for oil–water separation was developed via colloidal deposition. A porous film composed of PTFE nanoparticles was formed on filter paper, which was superhydrophobic with a water contact angle of 155.5° and superoleophilic with an oil contact angle of 0°. The obtained filter paper could separate a series of oil–water mixtures effectively with high separation efficiencies over 99%. Besides, the as-prepared filter paper kept stable superhydrophobicity and high separation efficiency even after 30 cycle times and could also work well under harsh environmental conditions like strong acidic or alkaline solutions, high temperature and ultraviolet irradiation. Compared with other approaches for fabricating oil–water materials, this approach is able to fabricate full-scale durable and practical oil–water materials easily and economically. The as-prepared filter paper is a promising candidate for oil–water separation

  4. One-step Synthesis of Pt Nanoparticles Highly Loaded on Graphene Aerogel as Durable Oxygen Reduction Electrocatalyst

    International Nuclear Information System (INIS)

    Huang, Qinghong; Tao, Feifei; Zou, Liangliang; Yuan, Ting; Zou, Zhiqing; Zhang, Haifeng; Zhang, Xiaogang; Yang, Hui

    2015-01-01

    Synthesis of highly active and durable Pt based catalysts with a high metal loading for fuel cells’ applications still remains a big challenge. The three-dimensional (3D) graphene aerogel (GA) not only possess the intrinsic property of graphene, but also have abundant pore architecture for anchoring metal nanoparticles, thus would be suitable as metal catalysts’ support. This work reports a simple and mild one-step co-reduction synthesis of Pt nanoparticles highly loaded on 3D GA and the use as durable oxygen reduction catalyst. Both X-ray diffraction and TEM measurements confirm that Pt nanoparticles (ca. 60 wt.% Pt loading) with an average diameter of ca. 3.2 nm are uniformly decorated on the homogeneously interconnected pores of 3D GA even after a heat treatment at 300 °C. Such a Pt/GA catalyst exhibits significantly enhanced electrocatalytic activity and improved durability for the oxygen reduction reaction. The enhancement in both catalytic activity and durability may result from the unique 3-D architecture structure of GA, the uniform dispersion of Pt nanoparticles, and the interaction between the Pt nanoparticles and GA. The GA-supported Pt can serve as a highly active catalyst for fuel cell applications

  5. Maintenance and Durability of the Concrete External Layer of Curtain Walls in Prefabricated Technological Poznan Large Panel System

    Science.gov (United States)

    Jasiczak, Józef; Girus, Krzysztof

    2017-10-01

    The issue of usability and durability of large-panel building constructed several decades ago is a subject of an in-depth analysis of many domestic and foreign investments. When considering the durability of specific large-panel system, one should consider, among others, the process of making external walls. The long-term and direct impact of weather conditions on the external layer of curtain walls is significant for the durability of large-panel buildings. For the needs of the presented paper, in 2016, the survey of cracks and a series of other tests of large-panel façade, residential building constructed in 1986, in Poland, in the PLP process system - Rataje was executed. Several hundred large-size, triple-layer curtain-wall slab with a 6-cm, concrete exterior cladding layer anchored using pins and hangers with the load-bearing layer, a 9-cm insulation layer made of mineral wool, and a 21-cm structural layer were surveyed. Significant deviations in thicknesses of particular wall layers were proven. Other significant damages and defects of external layers were found. At the second stage, many tests, both nondestructive and destructive, were conducted. They involved determining mechanical properties of an external layer. The concrete thickness was measured using with a type N Schmidt sclerometer and core samples were taken from this layer in order to mark concrete’s compressive strength. The range of carbonation (by phenolphthalein method) and the actual location and condition of reinforcement were estimated using a ferromagnetic device to determine the condition of the external layer. The diagnosis conducted in such a manner was the verification of necessary repair of the walls and their thermal efficiency improvement while ensuring safe conditions of their operation and modern functional and utility requirements. It should be also emphasized that the method of diagnosing the external walls presented in this paper may be popularized when evaluating such

  6. Lightweight, Durable Army Antennas Using Carbon Nanotube Technology

    Science.gov (United States)

    2013-01-01

    may be adjusted by collecting the sheet on a revolving substrate conveyor belt (e.g., Teflon belt ), as shown in figure 15 (12). SEM images of the... designated by other authorized documents. Citation of manufacturer’s or trade names does not constitute an official endorsement or approval of the use...CNT) materials to produce lightweight, flexible, and durable alternatives to existing and future Army antenna designs is explored through fabrication

  7. Durability of aircraft composite materials

    Science.gov (United States)

    Dextern, H. B.

    1982-01-01

    Confidence in the long term durability of advanced composites is developed through a series of flight service programs. Service experience is obtained by installing secondary and primary composite components on commercial and military transport aircraft and helicopters. Included are spoilers, rudders, elevators, ailerons, fairings and wing boxes on transport aircraft and doors, fairings, tail rotors, vertical fins, and horizontal stabilizers on helicopters. Materials included in the evaluation are boron/epoxy, Kevlar/epoxy, graphite/epoxy and boron/aluminum. Inspection, maintenance, and repair results for the components in service are reported. The effects of long term exposure to laboratory, flight, and outdoor environmental conditions are reported for various composite materials. Included are effects of moisture absorption, ultraviolet radiation, and aircraft fuels and fluids.

  8. Processing and Characterization of Thousand-Hour 500 C Durable 4H-SiC JFET Integrated Circuits

    Science.gov (United States)

    Spry, David J.; Neudeck, Philip G.; Chen, Liangyu; Lukco, Dorothy; Chang, Carl W.; Beheim, Glenn M.; Krasowski, Michael J.; Prokop, Norman F.

    2016-01-01

    This work reports fabrication and testing of integrated circuits (ICs) with two levels of interconnect that consistently achieve greater than 1000 hours of stable electrical operation at 500 C in air ambient. These ICs are based on 4H-SiC junction field effect transistor (JFET) technology that integrates hafnium ohmic contacts with TaSi2 interconnects and SiO2 and Si3N4 dielectric layers over 1-m scale vertical topology. Following initial burn-in, important circuit parameters remain stable for more than 1000 hours of 500 C operational testing. These results advance the technology foundation for realizing long-term durable 500 C ICs with increased functional capability for sensing and control combustion engine, planetary, deep-well drilling, and other harsh-environment applications.

  9. Freeze-thaw performance testing of whole concrete railroad ties.

    Science.gov (United States)

    2013-10-01

    Freezing and thawing durability tests of prestressed concrete ties are normally performed according to ASTM C666 specifications. Small specimens are cut from the shoulders of concrete ties and tested through 300 cycles of freezing and thawing. Saw-cu...

  10. The Sit-and-Wait Hypothesis in Bacterial Pathogens: A Theoretical Study of Durability and Virulence

    Directory of Open Access Journals (Sweden)

    Liang Wang

    2017-11-01

    Full Text Available The intriguing sit-and-wait hypothesis predicts that bacterial durability in the external environment is positively correlated with their virulence. Since its first proposal in 1987, the hypothesis has been spurring debates in terms of its validity in the field of bacterial virulence. As a special case of the vector-borne transmission versus virulence tradeoff, where vector is now replaced by environmental longevity, there are only sporadic studies over the last three decades showing that environmental durability is possibly linked with virulence. However, no systematic study of these works is currently available and epidemiological analysis has not been updated for the sit-and-wait hypothesis since the publication of Walther and Ewald’s (2004 review. In this article, we put experimental evidence, epidemiological data and theoretical analysis together to support the sit-and-wait hypothesis. According to the epidemiological data in terms of gain and loss of virulence (+/- and durability (+/- phenotypes, we classify bacteria into four groups, which are: sit-and-wait pathogens (++, vector-borne pathogens (+-, obligate-intracellular bacteria (--, and free-living bacteria (-+. After that, we dive into the abundant bacterial proteomic data with the assistance of bioinformatics techniques in order to investigate the two factors at molecular level thanks to the fast development of high-throughput sequencing technology. Sequences of durability-related genes sourced from Gene Ontology and UniProt databases and virulence factors collected from Virulence Factor Database are used to search 20 corresponding bacterial proteomes in batch mode for homologous sequences via the HMMER software package. Statistical analysis only identified a modest, and not statistically significant correlation between mortality and survival time for eight non-vector-borne bacteria with sit-and-wait potentials. Meanwhile, through between-group comparisons, bacteria with higher

  11. Investigation of freeze/thaw durability in polymer electrolyte fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Lim, Soo-Jin; Park, Gu-Gon; Sohn, Young-Jun; Yim, Sung-Dae; Yang, Tae-Hyun; Kim, Chang-Soo [Fuel Cell Research Center, Korea Institute of Energy Research, 102, Gajeong-ro, Yuseong-gu, Daejeon 305-343 (Korea, Republic of); Park, Jin-Soo [Department of Environmental Engineering, College of Engineering, Sanmyung University, 300 Anseo-dong, Dongnam-gu, Cheonam, Chungnam Province 330-720 (Korea, Republic of); Hong, Bo Ki [Fuel Cell Vehicle Team 1, Ecotechnology Center, Hyundai-Kia Motors Company, 104, Mabuk-dong, Giheung-gu, Yongin-si, Gyeonggi-do 446-912 (Korea, Republic of)

    2010-12-15

    This study aims to investigate the effect of different gas diffusion layers (GDLs) on freeze/thaw condition durability in polymer electrolyte fuel cells (PEFCs). Three kinds of GDLs-cloth, felt and paper type - with similar basic properties except thickness and bending stiffness were used. The changes in the properties and cell performance were investigated from the -30 to 70 C range of freeze/thaw cycles. The I-V performance degradation was observed to be negligible for the felt GDL whereas the cloth and paper GDLs showed a marked I-V performance loss. No distinctive correlation between the changes in electrochemical properties, such as active metal surface area, hydrogen crossover rates and decreased I-V performance, was observed except an increase in ohmic resistance revealed by ac-impedance spectroscopy. The physical destruction of electrodes was also shown by scanning electron microscope (SEM) analysis. The present study found that sufficient mechanical supporting force between the interfaces of materials enhances PEFC durability in sub-zero temperature conditions. (author)

  12. Operational durability of a giant ER valve for Braille display

    Science.gov (United States)

    Luning, Xu; Han, Li; Yufei, Li; Shen, Rong; Kunquan, Lu

    2017-05-01

    The compact configuration of giant ER (electrorheological) valves provides the possibility of realizing a full-page Braille display. The operational durability of ER valves is a key issue in fulfilling a Braille display. A giant ER valve was used to investigate the variations in pressure drops and critical pressure drops of the valves over a long period under some typical operational parameters. The results indicate that neither the pressure drops nor critical pressure drops of giant ER valves show apparent deterioration over a long period. Without ER fluid exchange, a blockage appears in the channel of the valve because the ER structures induced by an external electric field cannot be broken by the Brownian motion of hydraulic oil molecules when the external electric field is removed. Forcing ER fluid flow is an effective and necessary method to keep the channel of the valve unblocked. Thus the operational durability of the valve using giant ER fluids is able to meet the demands of Braille display.

  13. UV Ink-Jet printability and durability of stone and foil

    Directory of Open Access Journals (Sweden)

    Tadeja Muck

    2014-07-01

    Full Text Available he use of ultraviolet (UV printing technology has impacted printing industry in last years due to its applicability on many different »absorptive« as well as »non-absorptive« printing materials. The printability of building materials and recycled foils is relatively unknown. For primary building materials like stones, functionality can be explored with the use of UV printing technology; increased visual, informative effect or even “creative printing” of buildings. Also several aspects of recycled foils reusability as a printing material could be find (printed packaging material or also like secondary building materials. In the present study, printability of the stone and recycled foil and durability of UV prints was explored by means of macroscopically and microscopically characterization. Results indicate that higher print quality can be achieved on polished stone and on coated foil, which surfaces have higher smoothness. Durability of UV prints at freezing is higher at unpolished stone and coated foil that is at materials with the higher surface energy.

  14. An experimental survey on combined effects of fibers and nanosilica on the mechanical, rheological, and durability properties of self-compacting concrete

    International Nuclear Information System (INIS)

    Beigi, Morteza H.; Berenjian, Javad; Lotfi Omran, Omid; Sadeghi Nik, Aref; Nikbin, Iman M.

    2013-01-01

    Highlights: • We investigate combine effects of fibers and nanosilica on SCC. • The mechanical, rheological, and durability properties were tested and compared. • Microstructural properties of concrete were assessed using AFM and XRD techniques. • Nanosilica and fibers can improve the mechanical properties and durability of SCC. - Graphical abstract: - Abstract: Previous studies have shown that application of fibers in concrete enhances scratching, flexural and tensile strength. Self-Compacting Concrete (SCC) is a highly flowable and coherent concrete able to self-compact under its own weight. On the other hand, nanosilica particles and artificial pozzolans possessing high efficiency in concrete technology can improve structural properties of cement-based materials. Previous studies have suggested self-compacting and fiber-reinforced concretes for more stable and efficient buildings. Therefore, the present study aimed to evaluate the effects of nanosilica and different concrete reinforcing fibers including steel, polypropylene and glass on the performance of concrete. In this study mechanical (compressive, splitting tensile and flexural strength, toughness and modulus of elasticity), rheological (L-Box, slump flow, T50) and durability (resist chloride ion penetration (RCPT) and water absorption) properties are assessed. In addition, microstructural properties of concrete were assessed using Atomic Force Microscopy (AFM) and X-Ray Diffraction (XRD) techniques. Totally, 40 concrete mixes , labeled as A, B, C and D, with nanosilica contents of 0, 2, 4 and 6 weight percent (wt.%) of cement, respectively and three types of reinforcing fibers (steel: 0.2, 0.3 and 0.5 volume percent (v%) and polypropylene: 0.1, 0.15 and 0.2 v% and glass: 0.15, 0.2 and 0.3 v%) were evaluated. The results of the study showed that the presence of both nanosilica and reinforcing fibers in optimal percentages, can improve the mechanical properties and durability of self

  15. Polyurethane-Based Ionogels Exhibiting Durable Thermoresponsive Optical Behavior Under High-Temperature Conditions.

    Science.gov (United States)

    Sato, Tomoya; England, Matt W; Wang, Liming; Urata, Chihiro; Kakiuchida, Hiroshi; Hozumi, Atsushi

    2018-01-01

    Polyurethane (PU)-based transparent and flexible ionogels, showing unusual thermo-responsive optical properties, were successfully prepared by mixing PU-precursor and a hydrophobic ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (EMIM-TFSI). Although the initial ionogels were transparent at room temperature, significant increases in opacity were observed with increasing temperature up to 120°C, because of macroscopic phase separation of the PU-matrix and hydrophobic EMIM-TFSI. In addition, the optical transition temperature could be arbitrarily controlled simply by varying the mixing ratio of EMIM-TFSI within the PU-matrix. As confirmed by UV-Vis spectra acquired at different temperatures, this thermo-responsive optical behavior was found to be reversible, repeatable and durable even after 30 cycles of a thermal-stress testing between 30 and 100°C.

  16. Progressive Damage Modeling of Durable Bonded Joint Technology

    Science.gov (United States)

    Leone, Frank A.; Davila, Carlos G.; Lin, Shih-Yung; Smeltzer, Stan; Girolamo, Donato; Ghose, Sayata; Guzman, Juan C.; McCarville, Duglas A.

    2013-01-01

    The development of durable bonded joint technology for assembling composite structures for launch vehicles is being pursued for the U.S. Space Launch System. The present work is related to the development and application of progressive damage modeling techniques to bonded joint technology applicable to a wide range of sandwich structures for a Heavy Lift Launch Vehicle. The joint designs studied in this work include a conventional composite splice joint and a NASA-patented Durable Redundant Joint. Both designs involve a honeycomb sandwich with carbon/epoxy facesheets joined with adhesively bonded doublers. Progressive damage modeling allows for the prediction of the initiation and evolution of damage. For structures that include multiple materials, the number of potential failure mechanisms that must be considered increases the complexity of the analyses. Potential failure mechanisms include fiber fracture, matrix cracking, delamination, core crushing, adhesive failure, and their interactions. The joints were modeled using Abaqus parametric finite element models, in which damage was modeled with user-written subroutines. Each ply was meshed discretely, and layers of cohesive elements were used to account for delaminations and to model the adhesive layers. Good correlation with experimental results was achieved both in terms of load-displacement history and predicted failure mechanisms.

  17. Environmental Degradation and Durability of Epoxy-Clay Nanocomposites

    Directory of Open Access Journals (Sweden)

    Raman P. Singh

    2010-01-01

    Full Text Available This experimental investigation reports on the durability of epoxy-clay nanocomposites upon exposure to multiple environments. Nanocomposites are fabricated by mixing the clay particles using various combinations of mechanical mixing, high-shear dispersion, and ultrasonication. Clay morphology is characterized using X-ray diffraction and transmission electron microscopy. Specimens of both neat epoxy and the epoxy-clay nanocomposite are subjected to two environmental conditions: combined UV radiation and condensation on 3-hour repeat cycle and constant temperature-humidity, for a total exposure duration of 4770 hours. The presence of nanoscale clay inhibits moisture uptake, as demonstrated by exposure to constant temperature-humidity. Nonetheless, both materials lose mass under exposure to combined UV radiation and condensation due to the erosion of epoxy by a synergistic process. Surprisingly, the epoxy-clay specimens exhibit greater mass loss, as compared to neat epoxy. Mechanical testing shows that either environment does not significant affect the flexure modulus of either material. On the other hand, both materials undergo degradation in flexural strength when exposed to either environment. However, the epoxy-clay nanocomposite retains 37% more flexure strength than the neat epoxy after 4072 hours of exposure.

  18. Environmental Degradation and Durability of Epoxy-Clay Nanocomposites

    International Nuclear Information System (INIS)

    Singh, R.P.; Zunjarrao, S.C.; Pandey, G.; Khait, M.; Korach, C.S.

    2010-01-01

    This experimental investigation reports on the durability of epoxy-clay nanocomposites upon exposure to multiple environments. Nanocomposites are fabricated by mixing the clay particles using various combinations of mechanical mixing, high-shear dispersion, and ultrasonication. Clay morphology is characterized using X-ray diffraction and transmission electron microscopy. Specimens of both neat epoxy and the epoxy-clay nanocomposite are subjected to two environmental conditions: combined UV radiation and condensation on 3-hour repeat cycle and constant temperature-humidity, for a total exposure duration of 4770 hours. The presence of nanoscale clay inhibits moisture uptake, as demonstrated by exposure to constant temperature-humidity. Nonetheless, both materials lose mass under exposure to combined UV radiation and condensation due to the erosion of epoxy by a synergistic process. Surprisingly, the epoxy-clay specimens exhibit greater mass loss, as compared to neat epoxy. Mechanical testing shows that either environment does not significant affect the flexure modulus of either material. On the other hand, both materials undergo degradation in flexural strength when exposed to either environment. However, the epoxy-clay nanocomposite retains 37% more flexure strength than the neat epoxy after 4072 hours of exposure.

  19. FORECASTING OF DURABILITY OF ASPHALT PAVEMENT ON THE BASIS OF LEVELS OF THEIR VIBRATION LOADING

    Directory of Open Access Journals (Sweden)

    V. A. Osinovskaya

    2015-01-01

    Full Text Available The problem of low durability of flexible pavement is one of the most important problems of road economy. For example, the actual service life of asphalt pavement in Russia about 3 … 5 years. The bad condition of highways is an obstacle for the development of the national economy and leads to a significant annual economic losses.At present, this problem has no exact solution. Even at the seeming good road conditions of Europe and America the problem of low durability is no less important in these countries. And this problem becomes more and more actual every year.Our scientific researches allowed to make a hypothesis that the projected of pavements are not have the necessary durability yet not of a stage of designing because in strength calculations did not take into account the vibration of road constructions.Very actual the vibration loading becomes today as is now significantly changed the nature of loading of pavements. As a result the deflections of a pavements are reduced, but the increased vibration of pavements accelerated processes of destruction and significantly reduced durability.The theory of vibration destruction developed by the author allows to adjust the vibration, to form the vibration resistance pavements, and also to forecast a residual life of pavements that will more effectively develop repair actions.

  20. Construction of Polarized Carbon-Nickel Catalytic Surfaces for Potent, Durable, and Economic Hydrogen Evolution Reactions.

    Science.gov (United States)

    Zhou, Min; Weng, Qunhong; Popov, Zakhar I; Yang, Yijun; Antipina, Liubov Yu; Sorokin, Pavel B; Wang, Xi; Bando, Yoshio; Golberg, Dmitri

    2018-05-22

    Electrocatalytic hydrogen evolution reaction (HER) in alkaline solution is hindered by its sluggish kinetics toward water dissociation. Nickel-based catalysts, as low-cost and effective candidates, show great potentials to replace platinum (Pt)-based materials in the alkaline media. The main challenge regarding this type of catalysts is their relatively poor durability. In this work, we conceive and construct a charge-polarized carbon layer derived from carbon quantum dots (CQDs) on Ni 3 N nanostructure (Ni 3 N@CQDs) surfaces, which simultaneously exhibit durable and enhanced catalytic activity. The Ni 3 N@CQDs shows an overpotential of 69 mV at a current density of 10 mA cm -2 in a 1 M KOH aqueous solution, lower than that of Pt electrode (116 mV) at the same conditions. Density functional theory (DFT) simulations reveal that Ni 3 N and interfacial oxygen polarize charge distributions between originally equal C-C bonds in CQDs. The partially negatively charged C sites become effective catalytic centers for the key water dissociation step via the formation of new C-H bond (Volmer step) and thus boost the HER activity. Furthermore, the coated carbon is also found to protect interior Ni 3 N from oxidization/hydroxylation and therefore guarantees its durability. This work provides a practical design of robust and durable HER electrocatalysts based on nonprecious metals.

  1. Can the deterrence survive to nuclear tests ban

    International Nuclear Information System (INIS)

    Gaffney, F.J. Jr.

    1996-01-01

    The problem of the soundness of the nuclear tests stopping is discussed here. The safety, the durability of nuclear weapons need nuclear tests. So, unless other means able to guarantee the deterrence, it is prejudicial to stop nuclear tests and to sign a non proliferation treaty with the option of zero nuclear explosion. (N.C.)

  2. 49 CFR 180.605 - Requirements for periodic testing, inspection and repair of portable tanks.

    Science.gov (United States)

    2010-10-01

    ... surface of all joints under pressure must be coated with or immersed in a solution of soap and water... test markings. (1) Each IM or UN portable tank must be durably and legibly marked, in English, with the...) Each Specification DOT 51, 56, 57 or 60 portable tank must be durably and legibly marked, in English...

  3. Durability analysis of a reinforced concrete member using probabilistic SBRA method

    Czech Academy of Sciences Publication Activity Database

    Pustka, D.; Marek, Pavel

    2007-01-01

    Roč. 2007, č. 7 (2007), s. 91-94 ISSN 1505-8425 R&D Projects: GA ČR(CZ) GA103/07/0557 Institutional research plan: CEZ:AV0Z20710524 Keywords : Reliability * Durability * SBRA method Subject RIV: JM - Building Engineering

  4. To the question of reliability and durability ballastless deck of bridge

    Directory of Open Access Journals (Sweden)

    V.V. Prystynskaya

    2012-12-01

    Full Text Available The principal causes of operational defects in bridge ballastless deck plates are considered in the article. The drawbacks of these plates construction that prevent from achieving a higher level of bridge framework reliability and durability have been analysed.

  5. Life cycle and economic efficiency analysis phase II : durable pavement markings.

    Science.gov (United States)

    2011-04-01

    This report details the Phase II analysis of the life cycle and economic efficiency of inlaid tape : and thermoplastic. Waterborne paint was included as a non-durable for comparison purposes : only. In order to find the most economical product for sp...

  6. Modeling of asphalt durability and self-healing with discrete particles method

    NARCIS (Netherlands)

    Magnanimo, Vanessa; ter Huerne, Henderikus L.; Luding, Stefan; Beuving, E.; Dewez, P.; Malkoc, G.; Southern, M.

    2012-01-01

    Asphalt is an important road paving material. Besides an acceptable price, durability, surface conditions (like roughening and evenness), age-, weather- and traffic-induced failures and degradation are relevant aspects. In the professional road-engineering branch empirical models are used to

  7. Review: Durability and degradation issues of PEM fuel cell components

    NARCIS (Netherlands)

    Bruijn, de F.A.; Dam, V.A.T.; Janssen, G.J.M.

    2008-01-01

    Besides cost reduction, durability is the most important issue to be solved before commercialisation of PEM Fuel Cells can be successful. For a fuel cell operating under constant load conditions, at a relative humidity close to 100% and at a temperature of maximum 75 °C, using optimal stack and flow

  8. Ceramics: Durability and radiation effects

    Energy Technology Data Exchange (ETDEWEB)

    Ewing, R.C.; Lutze, W. [Univ. of New Mexico, Albuquerque, NM (United States); Weber, W.J. [Pacific Northwest National Lab., Richland, WA (United States)

    1996-05-01

    At present, there are three seriously considered options for the disposition of excess weapons plutonium: (1) incorporation, partial burn-up and direct disposal of MOX-fuel; (2) vitrification with defense waste and disposal as glass {open_quotes}logs{close_quotes}; (3) deep borehole disposal. The first two options provide a safeguard due to the high activity of fission products in the irradiated fuel and the defense waste. The latter option has only been examined in a preliminary manner, and the exact form of the plutonium has not been identified. In this paper, we review the potential for the immobilization of plutonium in highly durable crystalline ceramics apatite, pyrochlore, zirconolite, monazite and zircon. Based on available data, we propose zircon as the preferred crystalline ceramic for the permanent disposition of excess weapons plutonium.

  9. Lightweight, durable lead-acid batteries

    Science.gov (United States)

    Lara-Curzio, Edgar; An, Ke; Kiggans, Jr., James O; Dudney, Nancy J; Contescu, Cristian I; Baker, Frederick S; Armstrong, Beth L

    2013-05-21

    A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

  10. Glass Durability Modeling, Activated Complex Theory (ACT)

    International Nuclear Information System (INIS)

    CAROL, JANTZEN

    2005-01-01

    The most important requirement for high-level waste glass acceptance for disposal in a geological repository is the chemical durability, expressed as a glass dissolution rate. During the early stages of glass dissolution in near static conditions that represent a repository disposal environment, a gel layer resembling a membrane forms on the glass surface through which ions exchange between the glass and the leachant. The hydrated gel layer exhibits acid/base properties which are manifested as the pH dependence of the thickness and nature of the gel layer. The gel layer has been found to age into either clay mineral assemblages or zeolite mineral assemblages. The formation of one phase preferentially over the other has been experimentally related to changes in the pH of the leachant and related to the relative amounts of Al +3 and Fe +3 in a glass. The formation of clay mineral assemblages on the leached glass surface layers ,lower pH and Fe +3 rich glasses, causes the dissolution rate to slow to a long-term steady state rate. The formation of zeolite mineral assemblages ,higher pH and Al +3 rich glasses, on leached glass surface layers causes the dissolution rate to increase and return to the initial high forward rate. The return to the forward dissolution rate is undesirable for long-term performance of glass in a disposal environment. An investigation into the role of glass stoichiometry, in terms of the quasi-crystalline mineral species in a glass, has shown that the chemistry and structure in the parent glass appear to control the activated surface complexes that form in the leached layers, and these mineral complexes ,some Fe +3 rich and some Al +3 rich, play a role in whether or not clays or zeolites are the dominant species formed on the leached glass surface. The chemistry and structure, in terms of Q distributions of the parent glass, are well represented by the atomic ratios of the glass forming components. Thus, glass dissolution modeling using simple

  11. Effect of green tea extract on bonding durability of an etch-and-rinse adhesive system to caries-affected dentin

    Directory of Open Access Journals (Sweden)

    Carolina CARVALHO

    Full Text Available ABSTRACT Objective Green tea extract has been advocated as a matrix metalloproteinase (MMP inhibitor; however, its effect on bond durability to caries-affected dentin has never been reported. Thus, the aim of this in vitro study was to evaluate the effect of two MMP inhibitors (2% chlorhexidine and 2% green tea extract, applied after acid etching, on bond durability of an etch-and-rinse adhesive system to caries-affected dentin. Material and Methods Occlusal enamel was removed from third molars to expose the dentin surface, and the molars were submitted to a caries induction protocol for 15 days. After removal of infected dentin, specimens were conditioned with 37% phosphoric acid (15 seconds and randomly divided into three groups, according to the type of dentin pretreatment (n=10: NT: no treatment; GT: 2% green tea extract; CLX: 2% chlorhexidine. The etch-and-rinse adhesive system (Adper™ Single Bond 2, 3M ESPE, St. Paul, MN, USA was applied according to the manufacturer's instructions, and composite resin restorations were built on the dentin. After 24 hours, at 37°C, the resin-tooth blocks were sectioned perpendicularly to the adhesive interface in the form of sticks (0.8 mm2 of adhesive area and randomly subdivided into two groups according to when they were to be submitted to microtensile bond strength (μTBS testing: immediately or 6 months after storage in distilled water. Data were reported in MPa and submitted to two-way ANOVA for completely randomized blocks, followed by Tukey’s test (α=0.05. Results After 24 hours, there was no significant difference in the μTBS of the groups. After 6 months, the GT group had significantly higher μTBS values. Conclusion It was concluded that the application of 2% green tea extract was able to increase bond durability of the etch-and-rinse system to dentin. Neither the application of chlorhexidine nor non-treatment (NT - control had any effect on bond strength after water storage.

  12. The chemical durability of glasses suitable for the storage of high level radioactive wastes, (1)

    International Nuclear Information System (INIS)

    Terai, Ryohei; Hara, Shigeo; Kawamoto, Takamichi; Nanbu, Tadahiko; Nakamura, Takao.

    1975-01-01

    To develop the glassy materials suitable for the long-term storage of high level radioactive wastes, the chemical durability of the glasses of borax-alumina-silica system has been investigated. The test was carried out by the following three ways, (1) glass-disk immersion method, (2) continuous leach method and (3) method prescribed in JIS-R3502. In the continuous leach method, glass grains were exposed to circulating water at a constant temperature for a week to obtain the leach factor or leach rate. It was found from the experimental results that, as the silica content increased, the melting temperature of the glasses progressively increased and the chemical durability was considerably improved, and that B 2 O 3 and Na 2 O constituents were preferentially dissolved in water leaving relatively insoluble components such as SiO 2 and Al 2 O 3 . The rate at which B 2 O 3 and Na 2 O in glass are leached out is governed by three processes, that is, (1) the boundary reaction on the glass surface, (2) the diffusion process through the hydrated layer, and (3) the disintegration of hydrated layer. The first process probably corresponds to the hydration of boric oxides on the glass surface or to the ion exchange between protons in solution and Na + ions in glass, and the second process seems to correspond to the diffusion of protons through the hydrated layer on the glass surface. Although the ratio of [Na-BO 4 ]/[BO 3 ] in the borax-silica glasses was determined to be 0.5 by means of NMR measurement, Na 2 O/B 2 O 3 ratio in leached solution was less than 0.5, indicating that [BO 3 ] groups in glass were more soluble than [Na-BO 4 ] groups. From the viewpoint of appreciation of safety, the chemical durability of the glasses of borax-aluminasilica system was rather unsatisfactory, but that of the glasses containing silica in quantities was comparable to the soda-lime silicate sheet glasses. (auth.)

  13. The morphology of durability issues in PEM fuel cells

    International Nuclear Information System (INIS)

    Kundu, S.; Fowler, M.; Simon, L.; Grot, S.

    2004-01-01

    'Full text:' The work presented here examines durability issues in PEM fuel cell materials by examining material morphology and linking morphological features to performance. Scanning electron microscope (SEM) techniques have been able to identify a variety of features on the catalyst layer, each with their own implication to the overall performance and durability of the membrane electrode assembly (MEA). These features include cracking, delamination of the catalyst layer, catalyst clustering, electrolyte clustering, and thickness variations. Links between several of these features and catalyst dispersion conditions was also examined, showing that how the material was manufactured influences the type of morphological features present. The SEM has also been used with accelerated aging techniques to closely examine aging of the gas diffusion layer (GDL). It can be shown that over time the GDL will loose its hydrophobic character and hence become more susceptible to flooding in a fuel cell. The impact of morphological changes were determined using fuel cell models and experimental work. The ultimate aim of this work is to provide material developers with the tools and knowledge necessary to design better materials and therefore bring fuel cells closer to commercialization. (author)

  14. Fundamental Investigations and Rational Design of Durable High-Performance SOFC Cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Yu [Georgia Inst. of Technology, Atlanta, GA (United States); Ding, Dong [Georgia Inst. of Technology, Atlanta, GA (United States); Wei, Tao [Georgia Inst. of Technology, Atlanta, GA (United States); Liu, Meilin [Georgia Inst. of Technology, Atlanta, GA (United States)

    2016-03-31

    The main objective of this project is to unravel the degradation mechanism of LSCF cathodes under realistic operating conditions with different types of contaminants, aiming towards the rational design of cathodes with high-performance and enhanced durability by combining a porous backbone (such as LSCF) with a thin catalyst coating. The mechanistic understanding will help us to optimize the composition and morphology of the catalyst layer and microstructure of the LSCF backbone for better performance and durability. More specifically, the technical objectives include: (1) to unravel the degradation mechanism of LSCF cathodes under realistic operating conditions with different types of contaminants using in situ and ex situ measurements performed on specially-designed cathodes; (2) to examine the microstructural and compositional evolution of LSCF cathodes as well as the cathode/electrolyte interfaces under realistic operating conditions; (3) to correlate the fuel cell performance instability and degradation with the microstructural and morphological evolution and surface chemistry change of the cathode under realistic operating conditions; (4) to explore new catalyst materials and electrode structures to enhance the stability of the LSCF cathode under realistic operating conditions; and (5) to validate the long term stability of the modified LSCF cathode in commercially available cells under realistic operating conditions. We have systematically evaluated LSCF cathodes in symmetrical cells and anode supported cells under realistic conditions with different types of contaminants such as humidity, CO2, and Cr. Electrochemical models for the design of test cells and understanding of mechanisms have been developed for the exploration of fundamental properties of electrode materials. It is demonstrated that the activity and stability of LSCF cathodes can be degraded by the introduction of contaminants. The microstructural and compositional evolution of LSCF

  15. Composition models for the viscosity and chemical durability of West Valley related nuclear waste glasses

    International Nuclear Information System (INIS)

    Feng, X.; Saad, E.E.; Freeborn, W.P.; Macedo, P.B.; Pegg, I.L.; Sassoon, R.E.; Barkatt, A.; Finger, S.M.

    1988-01-01

    There are two important criteria that must be satisfied by a nuclear waste glass durability and processability. The chemical composition of the glass must be such that it does not dissolve or erode appreciably faster than the decay of the radioactive materials embedded in it. The second criterion, processability, means that the glass must melt with ease, must be easily pourable, and must not crystallize appreciably. This paper summarizes the development of simple models for predicting the durability and viscosity of nuclear waste glasses from their composition

  16. The effects of moisture and temperature variations on the long term durability of polymer concrete

    DEFF Research Database (Denmark)

    Barbosa, Ricardo; Hansen, Kurt Kielsgaard; Grelk, Bent

    2013-01-01

    The use of polymer concrete to precast products in construction presents normally many advantages compared to traditional concrete. Higher strength, lower permeability, shorter curing periods, better chemical resistances and a better durability is normally predicated, however this is a research...... and after exposure to different thermal conditions is very important. In this paper, an experimental study concerning the influence of temperature and moisture in cyclic conditions on the durability of polymer concrete based on an unsaturated polyester resin is described and the results are presented...

  17. Durability of fired clay bricks containing granite powder

    OpenAIRE

    Xavier, G. C.; Saboya, F.; Maia, P. C.; Alexandre, J.

    2012-01-01

    Over the past few decades, hundreds of papers have been published on the benefits of including rock powder as a raw material in fired clay brick manufacture. Very little has been written, however, about the durability and long-term behaviour of the final product. As a rule, the ceramic bricks used in construction in developing countries are fired at low temperatures, which detracts from their mechanical performance. This is particularly visible in harsh environmental conditions, where weather...

  18. Durability of light steel framing in residential applications

    OpenAIRE

    Lawson, RM; Popo-Ola, S.O.; Way, A.; Heatley, T; Pedreschi, Remo

    2010-01-01

    This paper presents a summary and analysis of research findings on the durability of galvanised cold-formed steel sections used in housing in order to deduce their design life. These cold-formed sections are produced from pre-galvanised strip steel. It reviews reports and publications from research projects carried out by Corus and the Steel Construction Institute on zinc-coated, cold-formed steel products. New data have also been gathered from measurements on houses and similar buildings tha...

  19. Durable-Goods Monopolists, Network Effects and Penetration Pricing

    OpenAIRE

    Cyrus C.Y. Chu; Hung-Ken Chien

    2005-01-01

    We study the pricing problem of a durable-goods monopolist. With network effects, consumption externalities among heterogeneous groups of consumers generate a discontinuous demand function. Consequently, the lessor has to offer a low price in order to reach the mass market, whereas the seller has the option to build a customer base by setting a lower initial price and raise the price later in the mass market, which explains the practice of introductory pricing. Contrary to the existing litera...

  20. Durability of certain configurations for providing skid resistance on concrete pavements.

    Science.gov (United States)

    1974-01-01

    The main objective of this study was to establish the factors that influence the durability of the surface configurations that are used or can be used to provide high and long lasting skid resistance for portland cement concrete pavements. In the dev...