WorldWideScience

Sample records for dumps generating acid

  1. Prediction and Control of Air Flow in Acid-Generating Waste Rock Dumps

    Science.gov (United States)

    Wels, C.; Lefebvre, R.; Robertson, A. M.

    2004-05-01

    Air movement and associated oxygen transport through waste rock dumps has the potential to significantly enhance the rate of oxidation of pyrite-bearing material. While this is a desired outcome for most heap leach operations, airflow in waste rock storage facilities can result in significant increases in generation and acceleration of acid rock drainage. Hence, a good understanding of internal airflow through waste rock dumps is required to control ARD and minimize any associated liability. The principal mechanisms contributing to airflow and oxygen transport in a waste rock pile include (i) diffusion, (ii) advection due to a thermal gradient (chimney effect) and/or wind pressure gradients and (iii) advection due to barometric pumping. While diffusion is typically limited to a near-surface zone of a few meters depth, advection and barometric pumping have the potential to move air (and oxygen) to much greater depths into the pile. In general, the more permeable the waste rock material, and the greater the height-to-width ratio of the waste rock pile, the greater is the potential for advective air movement. The reactivity of the waste rock material as well as the coarseness (hence air permeability), and the spatial variability of these properties within a pile, have a strong influence on the magnitude of thermally induced advection. In contrast, air movement due to barometric pumping is controlled by the waste rock porosity, changes in ambient air pressure and the heterogeneity of air permeability of the waste rock dump. Results of field monitoring and numerical modeling using TOUGH AMD are presented to illustrate the concepts on air movement in waste rock piles. During the design and construction phase, airflow can be controlled by judicious placement of reactive waste rock and use of selective placement techniques to control the internal structure of the waste rock facility (e.g. introduction of horizontal layering, prevention of inclined, high

  2. Investigation of the acid mine drainage potential of the Kopanang rock dump, Vaal Reefs / Charl Labuschagne

    OpenAIRE

    Labuschagne, Charl

    2008-01-01

    The Kopanang rock dump is one of several rock dumps in the Vaal Reefs gold mining area that may have an impact on the surface and groundwater quality. Few Acid Mine Drainage (AMD) studies exist on rock dumps in the South African gold industry due to the overwhelming acid generation from slime dams. Due to the existence of sulfide minerals in the Kopanang rock dump, there is a possibility that acid generation can occur, depending on the mineralogical composition of the ...

  3. Microbial diversity at the moderate acidic stage in three different sulfidic mine tailings dumps generating acid mine drainage.

    Science.gov (United States)

    Korehi, Hananeh; Blöthe, Marco; Schippers, Axel

    2014-11-01

    In freshly deposited sulfidic mine tailings the pH is alkaline or circumneutral. Due to pyrite or pyrrhotite oxidation the pH is dropping over time to pH values tailings are only scarcely studied. Here we investigated the microbial diversity via 16S rRNA gene sequence analysis in eight samples (pH range 3.2-6.5) from three different sulfidic mine tailings dumps in Botswana, Germany and Sweden. In total 701 partial 16S rRNA gene sequences revealed a divergent microbial community between the three sites and at different tailings depths. Proteobacteria and Firmicutes were overall the most abundant phyla in the clone libraries. Acidobacteria, Actinobacteria, Bacteroidetes, and Nitrospira occurred less frequently. The found microbial communities were completely different to microbial communities in tailings at

  4. Does Anti-dumping Enforcement Generate Threat?

    OpenAIRE

    Bagchi, Sagnik; Bhattacharyya, Surajit; Narayanan, Krishnan

    2014-01-01

    The last two decades have witnessed that countries across the world are guided by the rules and regulations of multilateral trading institutions (for example, World Trade organization [WTO], International Monetary Fund [IMF]) in order to promote free and fair trade through gradual reduction in trade barriers. The World economy has noticed significant reduction in tariffs, yet we find a rise in non-tariff barriers (NTBs). However, we still find dumping and few other trade strategies of the exp...

  5. CZCS view of an oceanic acid waste dump

    Science.gov (United States)

    Elrod, Jane A.

    1988-01-01

    Plumes from the acid waste dump in the New York Bight were visible in all nine cloud-free Coastal Zone Color Scanner images from April and May 1981. The CZCS subsurface radiance channels displayed consistent spectral characteristics, which consisted of a strong increase in the 550 nm channel and a moderate increase in the 520 nm channel relative to the surrounding coastal waters. The 443 nm channel showed no change or a slight decrease in radiance within the plumes. These anomalous radiances preclude the calculation of pigment in the dump plumes using existing algorithms. However, the high radiances of the 550 nm channel can be used to examine the flow patterns of surface water in the vicinity of the dump.

  6. Quantitative mapping by remote sensing of an ocean acid-waste dump

    Science.gov (United States)

    Ohlhorst, C. W.

    1978-01-01

    Results from quantitative analysis show that airplane remotely sensed spectral data can be used to quantify and map an acid-waste dump in terms of its particulate iron concentration. These same data, however, could not be used to map the dump in terms of total suspended solids, organic suspended solids, or inorganic suspended solids concentrations. A single-variable equation using the ratio of band 2 (440 to 490 nm) radiance to band 4 (540 to 580 nm) radiance was used to quantify the iron concentration in the acid-waste dump. The acid waste that was mapped varied in age from freshly dumped to 31/2 hr. Particulate iron concentrations in the acid waste were estimated to range up to 1.1 mg/l at a depth of 0.46 m. A classification technique was developed to identify pixels in the data set affected by sun glitter.

  7. Effect of sun elevation upon remote sensing of ocean color over an acid waste dump site

    Science.gov (United States)

    Bressette, W. E.

    1978-01-01

    Photographic flights were made over an ocean acid waste dump site while dumping was in progress. The flights resulted in wide angle, broadband, spectral radiance film exposure data between the wavelengths of 500 to 900 nanometers for sun elevation angles ranging from 26 to 42 degrees. It is shown from densitometer data that the spectral signature of acid waste discharged into ocean water can be observed photographically, the influence of sun elevation upon remotely sensed apparent color can be normalized by using a single spectral band ratioing technique, and photographic quantification and mapping of acid waste through its suspended iron precipitate appears possible.

  8. Dumping Syndrome

    Science.gov (United States)

    ... System & How it Works Digestive Diseases A-Z Dumping Syndrome What is dumping syndrome? Dumping syndrome occurs when food, especially sugar, ... the colon and rectum—and anus. What causes dumping syndrome? Dumping syndrome is caused by problems with ...

  9. The content determination of calcium, magnesium and ascorbic acid in sea buckthorn fruits at vulcan coal dump

    Directory of Open Access Journals (Sweden)

    Andreea BRASOVAN

    2009-11-01

    Full Text Available The study presents data on content determination of calcium, magnesium and ascorbic acid in sea buckthorn fruits collected from Vulcan coal dump. The dump was never covered with soil or fertilizers containing azoth, potassium and phosphorus. The sea buckthorn was planted directly on the sterile and it has an important function in stabilizing the acclivity and fixing the atmospheric azoth with the nodosities on the roots. So, the sea buckthorn becomes widespread plant in coal dumps because it helps to the soil formation. The results obtained after the determination of calcium, magnesium and ascorbic acid from the fruits of this plant were compared with the values already reported in various references, concluding that these differences are insignificant (3.7% for magnesium and 9.4% for calcium. Therefore, the sea buckthorn from the dump can be used in food industry, as well as in pharmaceutics and medicine.

  10. A high current sinusoidal pulse generator for the diluter magnets of the LHC beam dump system

    CERN Document Server

    Vossenberg, Eugène B; Ducimetière, L; Schröder, G H

    2000-01-01

    CERN is constructing the Large Hadron Collider (LHC), a superconducting accelerator that will collide protons at a center of mass energy of 14 TeV. The two colliding beams will each store an energy of up to 540 MJ, which must be safely deposited within one beam revolution of 89 mu s on two external absorbers located about 700 m from the extraction points at the end of dedicated extraction tunnels. To avoid evaporation of the graphite absorber material by the very high energy density of the incident beams, the deposition area of the beams on the absorber front face will be increased. This is done by a pair of sinusoidally powered orthogonal magnet systems producing approximately an e-shape figure of about 35 mm diameter, with a minimum velocity of 10 mm/ mu s during the dumping process. The pulse generators of the horizontally and vertically deflecting diluter magnets are composed of capacitor banks, discharged by stacks of solid state closing switches. They are connected to the magnets by 28 m long low induct...

  11. Investigation of the chemical composition of ash generated from Kosovo lignite and the possibility for biological land reclamation on ash dumps

    Energy Technology Data Exchange (ETDEWEB)

    Urosevic, D.; Filipovic, R. [Mining Institute Belgrade, Belgrade (Yugoslavia)

    1997-07-01

    This paper presents the results of investigation of the chemical composition and other properties of ash generated in the coal combustion process in the coal-fired power plants Kosovo, in order to determine the possibilities for biological land reclamation on ash dumps and other degraded soil surfaces. It was established that a certain chemical composition of ash has a beneficial effect on biological land reclamation of ash dumps, thus protecting the environment (i.e. the area surrounding the ash dumps), against pollution. It was concluded that, because of the high percentage of calcium and other earth-alkaline and toxic elements, the ash should not be used as substitution for agricultural production. Ash dumps in Kosovo are not so susceptible to erosion since CaO{sub 3} acts as a binding component. 22 refs., 7 tabs.

  12. Social dumping

    DEFF Research Database (Denmark)

    Pedersen, Klaus

    2010-01-01

    bidrag til, at OK-2010 "landes" fredeligt, fordi aftalen giver fagforeningerne en væsentlig indrømmelse i indsatsen mod social dumping. Aftalen har rigtignok til formål at imødekomme et af fagbevægelsens centrale overenskomstkrav om nye redskaber i indsatsen mod "social dumping". Men hvad er det aftalen...

  13. RIA Fragmentation Line Beam Dumps

    Energy Technology Data Exchange (ETDEWEB)

    Stein, W

    2003-08-08

    The Rare Isotope Accelerator project involves generating heavy-element ion beams for use in a fragmentation target line to produce beams for physics research. The main beam, after passing through the fragmentation target, may be dumped into a beam dump located in the vacuum cavity of the first dipole magnet. For a dump beam power of 100 kW, cooling is required to avoid excessive high temperatures. The proposed dump design involves rotating cylinders to spread out the energy deposition and turbulent subcooled water flow through internal water cooling passages to obtain high, nonboiling, cooling rates.

  14. Techno-Economic Feasibility of Energy Supply of Remote Dump Site in Jordan Badia by Photovoltaic Systems, Diesel Generators and Electrical Grid

    Directory of Open Access Journals (Sweden)

    Mohammed Al-Smairan

    2012-01-01

    Full Text Available In the development of energy sources in remote regions in Jordan at the brink of the 21st century, it is necessary to view the use of solar energy in all applications as one of the most promising new and renewable energy sources. As a contribution to the development program of remote areas in Jordan Badia, this paper presents three energy supply alternatives (photovoltaic system, diesel generator and electric grid for a dump site for providing the electrical loads to the dump site according to their energy requirements. The result of this study shows that remote dump site in Jordan Badia will require about 5.32 kWh/day or 1940 kWh/yr to meet their basic power requirements for such loads as lighting and electronic appliances-radios and fans. Four dynamic indicators were used to compare the economic-effectiveness of these energy systems. It is found that providing electricity to a dump site in a remote zone using photovoltaic systems is very beneficial and competitive with the other types of conventional energy sources, especially considering the decreasing prices of these systems and their increasing efficiencies and reliability. They have also the advantage of maintaining a clean environment. It is recommended that solar photovoltaic-based dump site electrification application should be encouraged by the government, especially for those rural sites without access to a grid supply.

  15. Dumping Syndrome

    Science.gov (United States)

    ... stomach move to your small intestine in an uncontrolled, abnormally fast manner. This is most often related to changes in your stomach associated with surgery. Dumping syndrome can occur after any stomach operation or removal of the esophagus (esophagectomy). Gastric bypass surgery for ...

  16. Generation of pulsed light in the visible spectral region based on non-linear cavity dumping

    DEFF Research Database (Denmark)

    Johansson, Sandra; Andersen, Martin; Tidemand-Lichtenberg, Peter

    We propose a novel generic approach for generation of pulsed light in the visible spectrum based on sum-frequency generation between the high circulating intra-cavity power of a high finesse CW laser and a single-passed pulsed laser. For demonstration, we used a CW 1342 nm laser mixed with a pass...

  17. Dump assembly

    Science.gov (United States)

    Goldmann, Louis H.

    1986-01-01

    A dump assembly having a fixed conduit and a rotatable conduit provided with overlapping plates, respectively, at their adjacent ends. The plates are formed with openings, respectively, normally offset from each other to block flow. The other end of the rotatable conduit is provided with means for securing the open end of a filled container thereto. Rotation of the rotatable conduit raises and inverts the container to empty the contents while concurrently aligning the conduit openings to permit flow of material therethrough.

  18. Generation of pulsed light in the visible spectral region based on non-linear cavity dumping

    DEFF Research Database (Denmark)

    Johansson, Sandra; Andersen, Martin; Tidemand-Lichtenberg, Peter

    We propose a novel generic approach for generation of pulsed light in the visible spectrum based on sum-frequency generation between the high circulating intra-cavity power of a high finesse CW laser and a single-passed pulsed laser. For demonstration, we used a CW 1342 nm laser mixed...... with a passively Q-switched 1064 nm laser to generate pulsed light at 593 nm. Light sources in the yellow spectral region have several applications, e.g. dermatology, laser displays and flow cytometry. Traditionally, copper-vapor lasers at 578 nm and dye lasers are used in this spectral region. These are however...... as the CW light source, using a folded cavity to achieve tight focussing in the non-linear crystal which was a 11 mm long PPKTP. The pulsed light source was a Nd:YVO4 laser emitting at 1064 nm using Cr:YAG as a passive saturable absorber, resulting in a pulse length of 100 ns and a repetition frequency...

  19. High power semiconductor switches in the 12 kV, 50 kA pulse generator of the SPS beam dump kicker system

    CERN Document Server

    Bonthond, J; Faure, P; Vossenberg, Eugène B

    2001-01-01

    Horizontal deflection of the beam in the dump kicker system of the CERN SPS accelerator is obtained with a series of fast pulsed magnets. The high current pulses of 50 kA per magnet are generated with capacitor discharge type generators which, combined with a resistive free-wheel diode circuit, deliver a critically damped half-sine current with a rise-time of 25 ms. Each generator consists of two 25 kA units, connected in parallel to a magnet via a low inductance transmission line.

  20. Environmental impact of differently remediated hard coal overburden and tailings dumps a few decades after remediation

    Energy Technology Data Exchange (ETDEWEB)

    Willscher, S. [Technical Univ. of Dresden (Germany). Inst. of Waste Management and Contaminated Site Treatment; Hertwig, T. [BEAK Consultants GmbH, Freiburg (Germany); Felix, M.; Sohr, A. [Saxonian State Dept. of Environment, Agriculture and Geology, Freiburg (Germany)

    2010-07-01

    Coal mining in the Saxony region of Germany has caused heavy metal and arsenic pollution in adjacent groundwater and surface waters. Coal waste dumping sites are leaching heavy metals and metalloids in the form of fine precipitates into local rivers. This paper studied the different remediation strategies used at 3 different dump sites in the area. The aim of the study was to determine the environmental impact of the dumps and evaluate the long-term effects of remediation measures. The dumps consisted of coarse to fine-grained materials from former processing activities, and contained pyrite in varying concentrations. Samples from different depth as well as groundwater samples were taken from the sites and investigated for their mechanical, geological, geochemical, biogeochemical, and physico-chemical characteristics. Seepage formation rates and contaminant loads at the dump sites were compared. The study showed that the revegetation of dump surfaces can help to prevent against erosion, but cannot prevent acid mine drainage (AMD) generation. The additional seals and covers placed at 2 of the dumps resulted in a high reduction of seepage waters, and almost no acidification of dump materials. 5 refs., 1 fig.

  1. Dumping syndrome (image)

    Science.gov (United States)

    Dumping syndrome occurs when the contents of the stomach empty too quickly into the small intestine. The ... causing nausea, cramping, diarrhea, sweating, faintness, and palpitations. Dumping usually occurs after the consumption of too much ...

  2. Zimbabwean mine dumps and their impacts on river water quality a reconnaissance study

    Science.gov (United States)

    Meck, Maideyi; Love, David; Mapani, Benjamin

    Zimbabwe has a substantial number of mines and 67 minerals have been mined in the country since 1900 but at present only 30 different minerals are being mined. Exploitation of a variety of ores, in rocks of diverse composition, provides the potential for a range of pollution problems. The severity and extent of contamination differs with the type of minerals mined. This paper presents part of the results of a broad study, carried out across Zimbabwe, which assessed the potential of different mine tailings dumps to cause environmental problems. The dumps considered in the study were divided into six dump types, namely: gold-mine dumps, base-metal mine dumps (dumps associated with the mining of nickel, zinc, copper and lead), minor-metals mine dumps (dumps associated with mining of antimony, arsenic, and selenium), platinum-group metal mine dumps, chromite and asbestos mine dumps, and sulphur (pyrite) mine dumps. The elemental chemistry of the dumps and physical characteristics (pH, total dissolved solids) of the dumps, tailings’ leachates, and stream waters around the dumps were used to assess the potential of the dumps to pollute water bodies. Samples were collected in both the dry and wet seasons. The dispersion and pollution patterns were derived from Eh-pH conditions around the dumps after considering the mobility of the elements present in these dumps under different Eh-pH conditions. In this paper potential to pollute is considered as the likelihood of the elements to disperse under the prevailing conditions at the dump. The concentrations of elements, type of elements and the potential dispersion and pollution patterns from each dump were used to characterise potential risk of water pollution associated with the different dump types. The results showed a slight increase in concentrations of most elements studied in downstream waters compared to upstream waters. The dump conditions varied from acidic to alkaline, and so the elements studied have different

  3. Prediction of the acid generating potential of coal mining spoils

    Energy Technology Data Exchange (ETDEWEB)

    Monterroso, C.; Macias, F. [Universidad de Santiago, Santiago (Spain). Dept. de Edafologia y Quimica Agricola

    1998-07-01

    The sulfide oxidation impact on mined land reclamation makes it necessary for mine spoils to be classified according to their acidifying potential. In this paper predictions were made of the acid generating potential of sulfide-containing spoils from the Puentes lignite mine (Galicia, NW Spain), and the limits of sulfur contents allowable for their storage in aerobic conditions, were established. Using samples of fresh spoils, analyses were made of the content and speciation of sulfur, pH was measured after oxidation of the sample with H{sub 2}O{sub 2} (pH of oxidation = pH{sub OX}), and titration of the oxidation extract with 0.1N NaOH to pH = 7 was carried out (Net Acid Production = NAP). The total sulfur content (S{sub T}) varied between {lt} 0.01% and {gt} 3%, with pyritic-S being the most common form ({gt} 80%). pH{sub OX} varied between 1.6 and 6.4 and NAP between 1.2 and 85.0 Kg-CaCO{sub 3}t{sup -1}. A high correlation was found between the NAP and the S{sub T}(r-0.98, p{lt} 0.001). Spoils with S{sub T} {gt} 0.15% cause high risks of mine-soil acidification, and create the need for large doses of CaCO{sub 3} to be used on final surface of the mine dump. Use of fly ash, produced from the combustion of lignite, as an alternative to commercial lime is more effective in the control of acidity generated by spoils with high S{sub T}. 20 refs., 5 figs., 1 tab.

  4. Development and Optimization of a Novel Prolonged Release Formulation to Resist Alcohol-Induced Dose Dumping.

    Science.gov (United States)

    Gujjar, Chaitanya Yogananda; Rallabandi, Balaramesha Chary; Gannu, Ramesh; Deulkar, Vallabh Subashrao

    2016-04-01

    Alcohol-induced dose dumping is a serious concern for the orally administered prolonged release dosage forms. The study was designed to optimize the independent variables, propylene glycol alginate (PGA), Eudragit RS PO (ERS) and coating in mucoadhesive quetiapine prolonged release tablets 200 mg required for preventing the alcohol-induced dose dumping. Optimal design based on response surface methodology was employed for the optimization of the composition. The formulations are evaluated for in vitro drug release in hydrochloric acid alone and with 40% v/v ethanol. The responses, dissolution at 120 min without alcohol (R1) and dissolution at 120 min with alcohol (R2), were statistically evaluated and regression equations are generated. PGA as a hydrophilic polymeric matrix was dumping the dose when dissolutions are carried in 0.1 N hydrochloric acid containing 40% v/v ethanol. ERS addition was giving structural support to the swelling and gelling property of PGA, and thus, was reducing the PGA erosion in dissolution media containing ethanol. Among the formulations, four formulations with diverse composition were meeting the target dissolution (30-40%) in both the conditions. The statistical validity of the mathematical equations was established, and the optimum concentration of the factors was established. Validation of the study with six confirmatory runs indicated high degree of prognostic ability of response surface methodology. Further coating with ReadiLycoat was providing an additional resistance to the alcohol-induced dose dumping. Optimized compositions showed resistance to dose dumping in the presence of alcohol.

  5. Geochemical Characterization of the Waste Rock Dump at the abandoned Geo-pung Mine, Korea

    Science.gov (United States)

    Ji, S.; Lee, H.; Cheong, Y.; Yim, G.; Park, H.

    2008-05-01

    To propose basic data for the establishment of the reclamation plan of the mine waste rock dumps, the geochemical studies including Acid-Base Accounting (ABA) test, water quality analyses of leachate and run-off waters, metal extraction test, and pot test were performed at the abandoned Geo-pung mine, located in the middle part of Korea. The acid generation capacities of the Geo-pung mine waste rocks (samples from ten points at the waste dump) showed high acid forming potential except for one point (G7). The maximum value of NAPP (Net Acid Producing Potential), which calculated by total sulfur (MPA, Maximum Potential Acidity, kg H2SO4/t) and ANC (Acid Neutralizing Capacity), was 80.94 kg H2 SO4/t. The results of the chemical analysis showed that the leachate from the waste rock dump have high concentration of Al (56 mg/l), Mn (39 mg/l), Cu (26.3 mg/l), Zn (155.3 mg/l), SO42- (1430 mg/l) and low pH (3.19). Run-off waters (surface flow of waste dump when rain) were, although partly different, showed high concentration of Al (1.7 ~ 20.2 mg/l), Cu (1.8 ~ 14.7 mg/l), Zn (2.4 ~ 26.5 mg/l) and low pH (3.08 ~ 4.07). From the metal extraction test, concentration of zinc was showed high level, from 579 mg/kg to 3,934 mg/kg. The upper parts of the Geo-pung mine waste dump have very low nutrient which needed for plant growth. The organic content was 9 g/kg, bioavailable phosphate was 0.1 mg/kg, and the exchangeable cation (K, Na, Mg) content also under the limit value (1 mg/kg) for the plant growth. The result of pot test also showed that this waste dump is unsuitable for media for plant growth due to lack of nutrient components. So when establish the reclamation plan of the Geo- pung mine waste dump, the cover system which have the function of prevention of sulfide oxidation and provision of nutrient with neutralize materials for revegetation must be considered. key words : Abandoned Mine, Waste Rock Dump, Acid-Base Accounting, Cover System

  6. Ocean Dumping: International Treaties

    Science.gov (United States)

    The London Convention and London Protocol are global treaties to protect the marine environment from pollution caused by the ocean dumping of wastes. The Marine, Protection, Research and Sanctuaries Act implements the requirements of the LC.

  7. The beam dump tunnels

    CERN Multimedia

    Patrice Loïez

    2002-01-01

    In these images workers are digging the tunnels that will be used to dump the counter-circulating beams. Travelling just a fraction under the speed of light, the beams at the LHC will each carry the energy of an aircraft carrier travelling at 12 knots. In order to dispose of these beams safely, a beam dump is used to extract the beam and diffuse it before it collides with a radiation shielded graphite target.

  8. Geotechnical aspects for the optimization of dump design at Chinh Bac Mine waste dump in Vietnam

    Energy Technology Data Exchange (ETDEWEB)

    Fuchsschwanz, M.; Ziegler, M. [Aachen Univ., Aachen (Germany). Dept. of Geotechnical Engineering; Ahmad, S.; Fernandez, J.B.P.; Martens, P.N. [Aachen Univ., Aachen (Germany). Inst. of Mining Engineering; Deissmann, G. [Brenk Systemplanung GmbH, Aachen (Germany)

    2009-07-01

    Vietnam's Quang Ninh province is one of the country's most important coal producing regions. Several open pit mines are being operated in the area by Nui Beo Coal Company (NBCC). The construction of large waste dumps for overburden removed by blasting have led to environmental problems at the mining sites, including dust emissions from mining and dumping operations; ground and surface water contamination by acid mine drainage; and slope stability problems caused by heavy rainfall and dump movements. This paper discussed investigations regarding the influence of the dump layout on slope stability and erosion. The paper described the project site and ongoing activities for the development of optimized stabilization and rehabilitation concepts with a particular focus on geotechnical aspects. The site was described in terms of coal and waste rock production; Chinh Bac waste rock dump; crack mapping; material properties of dumped material; density; and settlements. Ongoing activities focus on the effect of benches on slope stability; influence of benches on erosion; and layered dumping. 7 refs., 4 figs.

  9. Collective Deceleration: Toward a Compact Beam Dump

    Energy Technology Data Exchange (ETDEWEB)

    Wu, H.-C.; /Munich, Max Planck Inst. Quantenopt.; Tajima, T.; Habs, D.; /Munich, Max Planck Inst. Quantenopt. /Munich U.; Chao, A.W.; /SLAC; Meyer-ter-Vehn, J.; /Munich, Max Planck Inst. Quantenopt.

    2011-11-28

    With the increasing development of laser accelerators, the electron energy is already beyond GeV and even higher in near future. Conventional beam dump based on ionization or radiation loss mechanism is cumbersome and costly, also has radiological hazards. We revisit the stopping power of high-energy charged particles in matter and discuss the associated problem of beam dump from the point of view of collective deceleration. The collective stopping length in an ionized gas can be several orders of magnitude shorter than the Bethe-Bloch and multiple electromagnetic cascades stopping length in solid. At the mean time, the tenuous density of the gas makes the radioactivation negligible. Such a compact and non-radioactivating beam dump works well for short and dense bunches, which is typically generated from laser wakefield accelerator.

  10. Electricity generation devices using formic acid

    KAUST Repository

    Huang, Kuo-Wei

    2017-06-22

    The present disclosure relates generally to new forms of portable energy generation devices and methods. The devices are designed to covert formic acid into released hydrogen, alleviating the need for a hydrogen tank as a hydrogen source for fuel cell power.

  11. Dump valve assembly

    Science.gov (United States)

    Owen, T.J.

    1984-01-01

    A dump valve assembly comprising a body having a bore defined by a tapered wall and a truncated spherical valve member adapted to seat along a spherical surface portion thereof against said tapered wall. Means are provided for pivoting said valve member between a closed position engagable with said tapered wall and an open position disengaged therefrom.

  12. Getting Dumped On

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Chinese shoe manufacturers cry foul over anti-dumping duties imposed by the EU and set up an alliance to lobby for an overturn Hong Guangsheng, General Manager of Guangzhou Yunfang Shoes Co., is feeling the heat over his company's exports to Europe. According to a contract he signed with an Italian client in early April, the vol-

  13. Media in the dump

    OpenAIRE

    Gabrys, Jennifer

    2006-01-01

    'Media in the Dump' examines the phenomenon of electronic waste through five locations, from sites of manufacture (Silicon Valley) to disposal (China). This essay is original in its interdisciplinary approach to the topic of electronic waste. It synthesises fieldwork and scholarship from technology to design and cultural studies. The structure for this essay is original in its surveying of five 'waste ecologies' that traverse the globe.

  14. Premature beam dumps in 2011

    CERN Document Server

    Albert, Markus

    2012-01-01

    The statistical analysis of all non-programmed beam dumps during the 2011 proton run is presented. The selection criteria of fills that got considered were that the beam intensity of each of the two beams exceeded at least 1e12 particles per beam in order to exclude all probe beam dumps and most of the MPS test dumps. A distribution of beam dump causes by system is shown, as well as the time it took to re-establish injection after a non-programmed dump for fills which made it into STABLE BEAMS. This was done in an attempt to evaluate the cost of those non-programmed dumps in terms of time.

  15. The International Linear Collider beam dumps

    OpenAIRE

    Appleby, R.; Keller, L; Markiewicz, T.; Seryi, A.; Sugahara, R.; Walz, D.

    2006-01-01

    The ILC beam dumps are a key part of the accelerator design. At Snowmass 2005, the current status of the beam dump designs were reviewed, and the options for the overall dump layout considered. This paper describes the available dump options for the baseline and the alternatives and considers issues for the dumps that require resolution.

  16. MACROMYCETES OF DUMPING SITES AS BIOINDICATORS OF ANTHROPOGENIC EDAPHOTOP STATUS

    OpenAIRE

    Popovych V.V.

    2012-01-01

    We studied the development of the macromycetes on anthropogenic edaphotop of dumping sites in western wooden-steppes of Ukraine. We considered principal ecological factors, namely acidity, temperature, and connectivity of edaphotop; humidity, temperature, and air humidity, atmospheric pressure, wind speed, equivalent dose of ionizing radiation in the surface ground of macromycetes habitats. The species diversity of macromycetes in dumping sites of western wooden-steppes of Ukraine was conside...

  17. Sterols and fatty acids analysis at the Llobregat River for a wastewater dumping episode; Analisis de esteroles y acidos grasos en el rio Llobrgat por un vertido de aguas residuales

    Energy Technology Data Exchange (ETDEWEB)

    Romero-Lacal, J.; Garcia-Mendi, C.; Vega, A.; Pujadas, M.

    2006-07-01

    The study by gas chromatography (HRGC) and mass spectrometry (MS) of fatty acids and sterols of water samples from Anoia and Llobregat River, allowed to rule out the hypothesis of the Anoia River as the cause of dumping episode and even to determine that the episode was not associated to the faecal or residual contamination. Nevertheless, it has permitted us to have a better knowledge of these families of organic compounds in the basin of the Llobregat River. In the acidic fraction, saturated and unsaturated fatty acids of 14, 16 and 18 atoms of carbon from oil fish, animal fat or hydrogenated oils with industrial and domestic use were found. The application of different sterols indices (coprostanol, cholesterol, cholestanol, stigmasterol, stigmastadienol and sitosterol) permitted us to study the role of the sterols and the significance of the contamination from animal sterols, fitosterols in the studied samples. (Author) 19 refs.

  18. 10 kHz ps 1342 nm laser generation by an electro-optically cavity-dumped mode-locked Nd:YVO4 laser

    Science.gov (United States)

    Chen, Ying; Liu, Ke; He, Li-jiao; Yang, Jing; Zong, Nan; Yang, Feng; Gao, Hong-wei; Liu, Zhao; Yuan, Lei; Lan, Ying-jie; Bo, Yong; Peng, Qin-jun; Cui, Da-fu; Xu, Zu-yan

    2017-01-01

    We have demonstrated an electro-optically cavity-dumped mode-locked (CDML) picosecond Nd:YVO4 laser at 1342 nm with 880 nm diode-laser direct pumping. At a repetition rate of 10 kHz, an average output power of 0.119 W was achieved, corresponding to a pulse energy of 11.9 μJ. Compared with the continuous wave mode-locking pulse energy of 17.5 nJ, the CDML pulse energy was 680 times higher. The pulse width was measured to be 33.4 ps, resulting in the peak power of 356 kW. Meanwhile, the beam quality was nearly diffraction limited with an average beam quality factor M2 of 1.29.

  19. Dumping in a Global World

    NARCIS (Netherlands)

    J.L. Moraga-Gonzalez (José Luis); J.M.A. Viaene (Jean-Marie)

    2004-01-01

    textabstractAnti-dumping actions are now the trade policy of choice of developing and transition economies. To understand why these economies have increasingly applied anti-dumping laws, we build a simple theoretical model of vertical intra-industry trade and investigate the strategic incentives of

  20. MACROMYCETES OF DUMPING SITES AS BIOINDICATORS OF ANTHROPOGENIC EDAPHOTOP STATUS

    Directory of Open Access Journals (Sweden)

    Popovych V.V.

    2012-12-01

    Full Text Available We studied the development of the macromycetes on anthropogenic edaphotop of dumping sites in western wooden-steppes of Ukraine. We considered principal ecological factors, namely acidity, temperature, and connectivity of edaphotop; humidity, temperature, and air humidity, atmospheric pressure, wind speed, equivalent dose of ionizing radiation in the surface ground of macromycetes habitats. The species diversity of macromycetes in dumping sites of western wooden-steppes of Ukraine was considerably low (Simpson index: 0,91; Shannon index: -1,9. Species evenness was calculated by indices of Simpson and Shannon was rather low: 0,43 and -2,71 correspondingly; this indicated limited development of fungi. The main factors were violation of natural environment of macromycetes biotopes and anthropogenic pressure on their development as a result of aerobic and anaerobic processes that occur within the dumping sites. We founded that macromycetes could be bioindicators of the anthropogenic edaphotop of the dumping sites.

  1. Continuous Wheel Momentum Dumping Using Magnetic Torquers and Thrusters

    Science.gov (United States)

    Oh, Hwa-Suk; Choi, Wan-Sik; Eun, Jong-Won

    1996-12-01

    Two momentum management schemes using magnetic torquers and thrusters are sug-gested. The stability of the momentum dumping logic is proved at a general attitude equilibrium. Both momentum dumping control laws are implemented with Pulse-Width- Pulse-Frequency Modulated on-off control, and shown working equally well with the original continuous and variable strength control law. Thrusters are assummed to be asymmetrically configured as a contingency case. Each thruster is fired following separated control laws rather than paired thrusting. Null torque thrusting control is added on the thrust control calculated from the momentum control law for the gener-ation of positive thrusting force. Both magnetic and thrusting control laws guarantee the momentum dumping, however, the wheel inner loop control is needed for the "wheel speed" dumping, The control laws are simulated on the KOrea Multi-Purpose SATellite (KOMPSAT) model.

  2. Characterisation of sulphide-bearing waste-rock dumps using electrical resistivity imaging: the case study of the Rio Marina mining district (Elba Island, Italy).

    Science.gov (United States)

    Mele, Mauro; Servida, Diego; Lupis, Domenico

    2013-07-01

    Sulphide-bearing mine dumps are potential sources of pollution when acid mine drainage (AMD) occurs. Because the generation of AMD depends on the volume and composition of waste materials, their characterisation is crucial for the evaluation of geochemical hazards and for the design of remediation strategies to minimise their environmental impact. In this paper, a cost-effective strategy for the characterisation of an inactive mine dump in the Rio Marina mining district (Elba Island, Italy) using earth resistivity imaging (ERI) is presented. As no information regarding the nature of waste rocks is found in reports for the mine, five ERI profiles were acquired at the top of the waste pile. The results show that waste rocks are heterogeneous with a maximum thickness of 30 m. Due to the large amounts of dispersed sulphide minerals, the waste rocks are characterised by an electrically conductive geophysical signature in comparison to the surrounding resistive metamorphic bedrock. A geostatistical approach was adopted to estimate the elevation of the edges of the mine dump, and the net volume of the waste rocks was computed through a raster analysis of the elevations of the upper and lower boundaries of the mine dump. High-conductivity anomalies were detected within the core of the mine dump. The integration of the hydrogeological, geochemical and geological framework of the Rio Marina mining district suggests that these anomalies could be a geophysical signature of subsurface regions where AMD is currently generated or stored, thus representing sources of environmental pollution.

  3. 30 CFR 77.1608 - Dumping facilities.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Dumping facilities. 77.1608 Section 77.1608... Haulage § 77.1608 Dumping facilities. (a) Dumping locations and haulage roads shall be kept reasonably free of water, debris, and spillage. (b) Where the ground at a dumping place may fail to support...

  4. Acid generation efficiency: EUV photons versus photoelectrons

    Science.gov (United States)

    Goldfarb, Dario L.; Afzali-Ardakani, Ali; Glodde, Martin

    2016-03-01

    EUV photoacid generation efficiency has been described primarily in terms of the EUV photon absorption by the PAG or the resist matrix and the production of low energy photoelectrons, which are reported as being ultimately responsible for the high quantum efficiencies reported in EUV resists (harvesting efficiency. However, such studies either did not disclose the PAG chemical structures, replaced the EUV source with an e-beam source, or lacked a fundamental discussion of the underlying physical mechanisms behind EUV PAG decomposition. In this work, we report the EUV photospeed of a methacrylatebased resist formulated with a battery of openly disclosed isostructural sulfonium PAGs covering a wide range of EA's and Ered's, to unveil any preferential photoelectron scavenging effect. In parallel, several iodonium PAGs are also tested in order to compare the direct EUV photon absorption route to the photoelectron-based decomposition path. Contrarily to what has been widely reported, we have found no direct correlation whatsoever between photospeed and the calculated EA's or experimental Ered's for the isostructural sulfonium PAGs studied. Instead, we found that iodonium PAGs make more efficient use of the available EUV power due to their higher photoabsorption cross-section. Additionally, we determined a cation size effect for both PAG groups, which is able to further modulate the acid generation efficiency. Finally, we present a formal explanation for the unselective response towards photoelectron harvesting based on the stabilization of the PAG cation by bulky substituent groups, the spatial and temporal range of the transient photoelectron and the differences in electron transfer processes for the different systems studied.

  5. Collective deceleration: Toward a compact beam dump

    Directory of Open Access Journals (Sweden)

    H.-C. Wu

    2010-10-01

    Full Text Available With the increasing development of laser electron accelerators, electron energies beyond a GeV have been reached and higher values are expected in the near future. A conventional beam dump based on ionization or radiation loss mechanisms is cumbersome and costly, not to mention the radiological hazards. We revisit the stopping power theory of high-energy charged particles in matter and discuss the associated problem of beam dumping from the point of view of collective deceleration. The collective stopping length in an ionized gas can be several orders of magnitude shorter than that described by the Bethe-Bloch formulas and associated with multiple electromagnetic cascades in solids. At the same time, the tenuous density of the gas makes the radioactivation negligible. Such a compact beam dump without radioactivation works well for short and dense bunches, as they are typically generated from a laser wakefield accelerator. In addition, the nonuniform transverse wakefield can induce microbunching of the electron bunch by betatron oscillation. The microstructure could serve as a prebunched source for coherent radiation or feeding a free electron laser.

  6. Hydrogen generation from magnesium hydride by using organic acid

    Science.gov (United States)

    Ho, Yen-Hsi

    In this paper, the hydrolysis of solid magnesium hydride has been studied with the high concentration of catalyst at the varying temperature. An organic acid (acetic acid, CH3COOH) has been chosen as the catalyst. The study has three objectives: first, using three different weights of MgH 2 react with aqueous solution of acid for the hydrogen generation experiments. Secondly, utilizing acetic acid as the catalyst accelerates hydrogen generation. Third, emphasizing the combination of the three operating conditions (the weight of MgH2, the concentration of acetic acid, and the varying temperature) influence the amount of hydrogen generation. The experiments results show acetic acid truly can increase the rate of hydrogen generation and the weight of MgH2 can affect the amount of hydrogen generation more than the varying temperature.

  7. EU Lobbying and Anti-Dumping Policy

    DEFF Research Database (Denmark)

    Nielsen, Jørgen Ulff-Møller; Svendsen, Gert Tinggaard

    2012-01-01

    of petitioning firms and Council voting in the case of anti-dumping policy. If the political position of countries in anti-dumping cases is influenced by domestic lobbying efforts, we expect that the empirical pattern of country distribution of petitioning firms in EU anti-dumping cases corresponds closely...... to the empirical pattern of EU country distribution in Council voting. Our results show a low petitioning intensity for anti-dumping investigations and a high voting intensity against anti-dumping measures in Northern Europe. Thus, it seems likely that domestic lobbying efforts have influenced the political...... position of countries in the special case of EU anti-dumping policy....

  8. From a dump to a energy park and recycling park. The Rhine-Main dump park in Floersheim-Wicker; Von der Muellkippe zum Energie- und Recyclingpark. Der Rhein-Main-Deponiepark in Floersheim-Wicker

    Energy Technology Data Exchange (ETDEWEB)

    Mehler, Gerd [Rhein-Main Deponie GmbH, Floersheim am Main (Germany)

    2008-07-01

    If dumps are shut down, aftercare measures are necessary for a time period of several decades. The question arises whether the infrastructure, operating equipment and operating personnel of dumps can be used in the aftercare phase for subsequent utilisations. Under this aspect, the author of the contribution under consideration reports on the Rhine-Main dump park in Floersheim-Wicker (Federal Republic of Germany). Subsequently to the introduction according to the subsequent utilisation of dump locations, the author reports on the concept of the Rhine Main dump park, on the power generation in the Rhine-Main dump park, on the processing of wastes to fuels for the power production and on the dump as recycling park.

  9. The 12 kV, 50 kA Pulse Generator for the SPS MKDH Horizontal Beam Dump Kicker System,equipped with Semiconductor Switches

    CERN Document Server

    Bonthond, J; Faure, P; Vossenberg, Eugène B; CERN. Geneva. SPS and LHC Division

    2001-01-01

    The high current pulses for the MKDH magnets are generated with capacitor discharge type generators which, combined with a resistive free-wheel diode circuit, deliver a critically damped half-sine current with a rise-time of 25 ms. Each generator consists of two 25 kA units, connected in parallel to a magnet via low inductance transmission lines. They are equipped with a stack of four Fast High Current Thyristors, together with snubber capacitors, a voltage divider and a specially designed trigger transformer.

  10. Evaluation of geochemical mobility of heavy metals in the dump mine rocks Western Donbass

    Directory of Open Access Journals (Sweden)

    Yatsechko N.Y.

    2014-12-01

    Full Text Available Typification of turn mine rocks of Western Donbas is conducted after a size acid-lye the index of water-soluble complex. It is set that exactly rocks with the low value of it an index characterized the most sizes of middle content of water-soluble forms of heavy metals. It is well-proven that exactly mine dumps are the generating source of contamination of objects of environment of this region by heavy metals. The significant impact on the environment inflicted not only directly in the process of coal mining, but for many years after its completion. The source of contamination of environmental objects are dumps that occupy large areas of fertile land. Every year in the dumps is stored about 40 million. m3 moldboard mine rock. Most of the waste coal industry have potential toxic and mutagenic properties as containing a significant amount of heavy metals, which are practically not biodegradable in the environment and is therefore especially dangerous for living organisms paramount importance score geochemical mobility of heavy metals, ie their property to move from solid to liquid phase, migrate to the natural landscape and absorbed by vegetation. This applies particularly to water-soluble forms of metals, as in warehousing surface mine dump piles of rocks, the priority factor that regulates the processes of migration of heavy metals are leaching precipitation of solid phase wastes. It is the existence and content of heavy metals in water-soluble complex characterized by their solubility and migration activity and can be used to assess the real extent of possible contamination of the hydrosphere.

  11. LHC injection and dump protection

    CERN Document Server

    Bartmann, W; Bracco, C; Goddard, B; Kain, V; Rossi, A; Wollmann, D

    2010-01-01

    The machine protection against fast failures including injection or dump kickers relies on fixed and movable devices. Results will be shown from the low-intensity beam commissioning of the moveable injection protection devices in the SPS to LHC transfer lines and downstream of the LHC injection kickers, and of the LHC dump protection elements in IR6. This paper is almost exclusively focussing on the issues arising during the 2009 commissioning. The implications of these results and a commissioning status report with the planning for 2010 will be addressed.

  12. Dumping in Developing and Transition Economies

    NARCIS (Netherlands)

    J.L. Moraga-Gonzalez (José Luis); J.M.A. Viaene (Jean-Marie)

    2004-01-01

    textabstractWe build a simple theoretical model to understand why developing and transition economies have increasingly applied anti-dumping laws. To that end, we investigate the strategic incentives of oligopolistic exporting firms to undertake dumping in these economies. We show that dumping may b

  13. Chemical munitions dumped at sea

    Science.gov (United States)

    Edwards, Margo; Bełdowski, Jacek

    2016-06-01

    Modern chemical warfare is a byproduct of the industrial revolution, which created factories capable of rapidly producing artillery shells that could be filled with toxic chemicals such as chlorine, phosgene and mustard agent. The trench warfare of World War I inaugurated extensive deployments of modern chemical weapons in 1915. Concomitantly, the need arose to dispose of damaged, captured or excess chemical munitions and their constituents. Whereas today chemical warfare agents (CWA) are destroyed via chemical neutralization processes or high-temperature incineration in tandem with environmental monitoring, in the early to middle 20th century the options for CWA disposal were limited to open-air burning, burial and disposal at sea. The latter option was identified as the least likely of the three to impact mankind, and sea dumping of chemical munitions commenced. Eventually, the potential impacts of sea dumping human waste were recognized, and in 1972 an international treaty, the Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter, was developed to protect the marine environment from pollution caused by the dumping of wastes and other matter into the ocean. By the time this treaty, referred to as the London Convention, was signed by a majority of nations, millions of tons of munitions were known to have been disposed throughout the world's oceans.

  14. High energy laser beam dump

    Science.gov (United States)

    Halpin, John

    2004-09-14

    The laser beam dump is positioned in a housing. An absorbing glass plate means is operatively connected to the housing. A heat sync means for extracting heat from the absorbing glass plate means is operatively connected to the housing and operatively connected to the absorbing glass plate means.

  15. Assessment of impact on health of children working in the garbage dumping site in Dhaka, Bangladesh.

    Science.gov (United States)

    Lahiry, Gargy; Rahman, Tania; Hasan, A K M Mahbub; Dutta, Alak K; Arif, Md; Howlader, Zakir H

    2011-12-01

    Waste dumping is one of the major causes of environment pollution in Bangladesh. This study was designed to assess the impact on health of children working in one of the garbage dumping sites in Dhaka. Blood samples were collected from exposed (n = 20, aged: 8-15 years, exposed to dumped garbage from 6 months to 6 years) and control subjects (n = 15, age matched and never worked in the garbage dumping site). Oxidative stress markers like lipid hydroperoxides, thiobarbituric acid reactive substances and protein carbonyl content were measured. Alkaline comet assay was performed to assess the possible damage in DNA. To check the consequences of possible toxic exposure, we performed liver function tests of the study subjects. Oxidative stress-mediated damage of macromolecules was found to be significantly increased in the exposed children. Liver function tests were found normal. Thus, the children working in garbage dumping site are in severe health risk.

  16. 生物腐植酸对露天矿排土场黑麦草生长的影响%Effects of Biological Humic Acid on Growth of Lolium Multi f lorum in Open-pit Mine Dump

    Institute of Scientific and Technical Information of China (English)

    张志玲; 王东丽; 尹志刚; 刘毅; 雷虹; 姜东奇; 苑子琦

    2016-01-01

    Objective] The effect of biological humic acid on soil improvement in open‐pit mine dump was studied ,in order to provide scientific references for the improvement of soil quality .[Methods] Biological humic acid with different contents (0—400 kg/hm2 ) were added in five different kinds of soil which were derived from five land use types(Robinia pseudoacacia forest ,Ulmus pumila forest ,V itex negundo forest , farming land and unutilized land) .Pot experiments were conducted by planting Lolium multif lorum species . The effects of biological humic acid on soil improvement were investigated .[Results] The maximum emer‐gence rate for the soil from R .pseudoacacia ,U .pumila ,V .negundo ,farming and unutilized land occurred when the amounts of biological humic acid were 200 ,200 ,300 ,300 and 200 kg/hm2 ,respectively .The max‐imum amount of biological humic acid required by Lolium multi f lorum seedling for five different kinds of soil were 200 ,200 ,200 ,300 and 300 kg/hm2 .The maximum root length occurred when the amounts of biologi‐cal humic acid were 300 ,100 ,300 ,300 and 300 kg/hm2 ,respectively ,and the maximum biomass occurred when the amount were 200 ,100 ,200 ,300 and 300 kg/hm2 ,respectively .As the biological humic acid increases ,all the seedling emergence ,seedling height ,root length and seedling biomass showed a downward trend before an increase .[Conclusion] There was a dose effect of the biological humic acid on the plant regeneration and growth in different soil of open‐pit mine dump .The change curves of the relations for the plant regeneration and grow th and the biological humic acid appeared as a “single‐peak”shape ,w hich indicate that a balanced amount of biological humic acid could improve the vegetation recovery in open‐pit mine dump .%[目的]研究生物腐植酸对露天矿排土场土壤改良效果的影响,为进一步提高露天矿排土场的土壤质量提供科学参考。[方法]通过盆栽试验,研究

  17. Influences on the occurrence of dumping syndrome.

    Science.gov (United States)

    Kaushik, S P; Ralphs, D N; Hobsley, M

    1983-03-01

    A dumping provocation test using 50% of glucose solution labeled with Indium 115 m, was performed on 146 occasions pre- and postoperatively in 85 patients. Dumping elicited by the test was defined by the symptoms produced by the test and various objective measures of dumping. The influence of various factors other than the type of operation on the occurrence of dumping has been studied in detail. The incidence of dumping symptoms induced by the test has shown no significant correlation with age, sex, weight, height, smoking habits, race, dose of hypertonic glucose, and the time elapsed since surgery. However, a significant relationship has been observed between the duration of ulcer symptoms before operation and the occurrence of dumping symptoms induced by the test. The test not only reproduced the symptoms patients had reported after eating ordinary foods, it also helped in eliminating patients with borderline symptoms as our objective measures collectively differentiated three patients from those with the dumping syndrome.

  18. Mercury in dumped blast furnace sludge.

    Science.gov (United States)

    Földi, Corinna; Dohrmann, Reiner; Mansfeldt, Tim

    2014-03-01

    Blast furnace sludge (BFS) is a waste generated in the production of pig iron and was dumped in sedimentation ponds. Sixty-five samples from seven BFS locations in Europe were investigated regarding the toxic element mercury (Hg) for the first time. The charge material of the blast furnace operations revealed Hg contents from 0.015 to 0.097mgkg(-1). In comparison, the Hg content of BFS varied between 0.006 and 20.8mgkg(-1) with a median of 1.63mgkg(-1), which indicates enrichment with Hg. For one site with a larger sample set (n=31), Hg showed a stronger correlation with the total non-calcareous carbon (C) including coke and graphite (r=0.695; n=31; p<0.001). It can be assumed that these C-rich compounds are hosting phases for Hg. The solubility of Hg was rather low and did not exceed 0.43% of total Hg. The correlation between the total Hg concentration and total amount of NH4NO3-soluble Hg was relatively poor (r=0.496; n=27; p=0.008) indicating varying hazard potentials of the different BFS. Finally, BFS is a mercury-containing waste and dumped BFS should be regarded as potentially mercury-contaminated sites.

  19. Kickers and dumps

    CERN Document Server

    Mertens, V

    2011-01-01

    Envisaged major interventions on the systems under the responsibility of TE-ABT include the completion of the staged dilution kicker system in LSS6, upgrade of the extraction protection elements TCDQ and possibly the replacement of a number of injection kickers. The reliability overhaul of the extraction and dilution kicker generators will be completed, and numerous improvements of electronics and controls components of the various systems be carried out, followed by a thorough test and re-qualification programme.

  20. Phytoremediation of spoil coal dumps in Western Donbass (Ukraine)

    Science.gov (United States)

    Klimkina, Iryna; Kharytonov, Mykola; Wiche, Oliver; Heilmeier, Hermann

    2017-04-01

    At the moment, in Ukraine about 150 thousand hectares of fertile land are occupied by spoil dumps. Moreover, this figure increases every year. According to the technology used about 1500 m3 of adjacent stratum is dumped at the surface per every 1000 tons of coal mined. Apart from land amortization, waste dumps drastically change the natural landscape and pollute air, soil and water sources as the result of water and wind erosion, as well as self-ignition processes. A serious concern exists with respect to the Western Donbass coal mining region in Ukraine, where the coal extraction is made by the subsurface way and solid wastes are represented by both spoil dumps and wastes after coal processing. Sulphides, mostly pyrite (up to 4% of waste material), are widely distributed in the waste heaps freshly removed due to coal mining in Western Donbass.The oxidation of pyrite with the presence of oxygen and water is accompanied by a sharp drop in the pH from the surface layer to the spoil dumps(from 5.2-6.2 to 3.9-4.2 in soil substrates with chernozen and from 8.3-8.4 to 6.7-7.2 in soil substrates with red-brown clay, stabilizing in dump material in both cases at 2.9-3.2). Low pH generates the transformation of a number of toxic metals and other elementspresent in waste rock (e.g. Fe, Al, Mn, Zn, Mo, Co, As, Cd, Bi, Pb, U) into mobile forms. To stabilize and reduce metal mobility the most resistant plants that occur naturally in specified ecosystems can be used. On coal spoil dumpsin Western Donbas the dominant species are Bromopsis inermis, subdominant Artemisia austriaca; widespread are also Festucas pp., Lathyrus tuberosus, Inula sp., Calamagrostis epigeios, Lotus ucrainicus, and Vicias pp. Identification of plants tolerant to target metals is a key issue in phytotechnology for soil restoration. It is hypothesized that naturally occurring plants growing on coal spoil dumps can be candidates for phytostabilization, phytoextraction (phytoaccumulation) and phytomining

  1. Pioneer vegetation on ash dumps in Oswiecim (southern Poland)

    Energy Technology Data Exchange (ETDEWEB)

    Bojarczuk, T.; Kuczynski, B.

    1972-01-01

    The authors found fifty-three plant species growing on the ash dumps in Oswiecim, while in 1963 twenty-two species only were encountered there. Most of the self-sown plants belong to calciphilous, ruderal and xerophilous species. The pH of the ashes amounts to 9.5. Some of them, e.g. Matricaria chamomilla are index plants for acid habitats; others were hitherto encountered in wet habitats, e.g. Rumex obtusifolias, Myricaria germanica, Epilobium roseum, and others. Their occurrence on ash dumps is possible thanks to the considerable amount of precipitation (465 mm) during the vegetative period. The mosses are the pioneers of these dumps, e.g. Funaria hygromertrica and Bryum argenteum, which usually appear on the site of fire. The authors are of the opinion that a better knowledge of the plants appearing spontaneously on dumps and waste heaps may provide many useful conclusions which will help to obtain positive results at the recultivation of spoil heaps and industrial wastes. 9 references, 3 tables.

  2. 7 CFR 48.7 - Evidence to justify dumping.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 2 2010-01-01 2010-01-01 false Evidence to justify dumping. 48.7 Section 48.7... Dumping § 48.7 Evidence to justify dumping. Any person, receiving produce in interstate commerce or in the..., prior to such destroying, abandoning, discarding or dumping, obtain a dumping certificate or...

  3. 49 CFR 176.97 - Prohibition of dump scows.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false Prohibition of dump scows. 176.97 Section 176.97... Requirements for Barges § 176.97 Prohibition of dump scows. Dump scows are barges having cargo carrying compartments of the hopper type and fitted with a bottom dump or a side dump. This type of barge is...

  4. The LHC Beam Dumping System Trigger Synchronisation and Distribution System

    CERN Document Server

    Antoine, A; Voumard, N

    2005-01-01

    Two LHC beam dumping systems (LBDS) will fast-extract the counter-rotating beams safely from the LHC collider during setting-up of the accelerator, at the end of a physics run and in case of emergencies. They consist of 15 fast pulsed magnets per ring for beam extraction from the accelerator combined with 10 fast pulsed magnets for horizontal and vertical beam dilution. Dump requests will come from 3 different sources: the machine protection system for emergency cases, the machine timing system for scheduled dumps or the LBDS itself in case of internal failures. These spontaneously issued dump requests will be synchronised with the 3 µs beam abort gap within a fail-safe trigger synchronisation unit (TSU) based on a digital phase lock loop (DPLL) locked on the beam revolution frequency with a maximum phase error of 40 ns. Afterwards, the synchronised trigger pulse will be distributed to the fast pulsed magnet high voltage generators through a redundant fault tolerant trigger distribution system based on the...

  5. Independence divergence-generated binary trees of amino acids.

    Science.gov (United States)

    Tusnády, G E; Tusnády, G; Simon, I

    1995-05-01

    The discovery of the relationship between amino acids is important in terms of the replacement ability, as used in protein engineering homology studies, and gaining a better understanding of the roles which various properties of the residues play in the creation of a unique, stable, 3-D protein structure. Amino acid sequences of proteins edited by evolution are anything but random. The measure of nonrandomness, i.e. the level of editing, can be characterized by an independence divergence value. This parameter is used to generate binary tree relationships between amino acids. The relationships of residues presented in this paper are based on protein building features and not on the physico-chemical characteristics of amino acids. This approach is not biased by the tautology present in all sequence similarity-based relationship studies. The roles which various physico-chemical characteristics play in the determination of the relationships between amino acids are also discussed.

  6. 40 CFR 227.14 - Criteria for evaluating the need for ocean dumping and alternatives to ocean dumping.

    Science.gov (United States)

    2010-07-01

    ... ocean dumping and alternatives to ocean dumping. 227.14 Section 227.14 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) OCEAN DUMPING CRITERIA FOR THE EVALUATION OF PERMIT APPLICATIONS FOR OCEAN DUMPING OF MATERIALS Need for Ocean Dumping § 227.14 Criteria for evaluating the need for...

  7. A novel heterogeneous reaction for generating gaseous nitrous acid

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The short-lived reactive specimen nitrous acid HONO was generated in the gas phase by the heterogeneous reaction of gaseous HCl with AgNO2 which can generate higher concentration of HONO than other methods. We investigated the process from generation to dissociation in the gas phase under different controlled temperatures, and discussed the ionization and reaction on the solid surface by com-bination of the photoelectron spectroscopy and photoionization mass spectroscopy (PES-PIMS) and in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS).

  8. Generation and esterification of electrophilic fatty acid nitroalkenes in triacylglycerides.

    Science.gov (United States)

    Fazzari, Marco; Khoo, Nicholas; Woodcock, Steven R; Li, Lihua; Freeman, Bruce A; Schopfer, Francisco J

    2015-10-01

    Electrophilic fatty acid nitroalkenes (NO(2)-FA) are products of nitric oxide and nitrite-mediated unsaturated fatty acid nitration. These electrophilic products induce pleiotropic signaling actions that modulate metabolic and inflammatory responses in cell and animal models. The metabolism of NO(2)-FA includes reduction of the vinyl nitro moiety by prostaglandin reductase-1, mitochondrial β-oxidation, and Michael addition with low molecular weight nucleophilic amino acids. Complex lipid reactions of fatty acid nitroalkenes are not well defined. Herein we report the detection and characterization of NO(2)-FA-containing triacylglycerides (NO(2)-FA-TAG) via mass spectrometry-based methods. In this regard, unsaturated fatty acids of dietary triacylglycerides are targets for nitration reactions during gastric acidification, where NO(2)-FA-TAG can be detected in rat plasma after oral administration of nitro-oleic acid (NO(2)-OA). Furthermore, the characterization and profiling of these species, including the generation of beta oxidation and dehydrogenation products, could be detected in NO(2)-OA-supplemented adipocytes. These data revealed that NO(2)-FA-TAG, formed by either the direct nitration of esterified unsaturated fatty acids or the incorporation of nitrated free fatty acids into triacylglycerides, contribute to the systemic distribution of these reactive electrophilic mediators and may serve as a depot for subsequent mobilization by lipases to in turn impact adipocyte homeostasis and tissue signaling events.

  9. Northwest Russia and the Dumping of Radioactive Waste: The London Convention Implemented

    Energy Technology Data Exchange (ETDEWEB)

    Stokke, Olav Schram

    1997-12-31

    The `Polar Oceans and the Law of the Sea Project`, POLOS, is a three-year international research project in international law and international relations. This report is one of the publications under POLOS. The subject is the Soviet dumping of radioactive waste in the Barents and Kara Seas. The most intensely radioactive waste is a number of submarine reactors still containing high-level spent fuel. Some of this dumping violated Soviet commitments to the 1972 London Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter, and this is the starting point of the report. The discussion focuses on how international regimes may affect the domestic implementation in member states, that is, how international agreements can be converted into behavioural adaptation on the part of target groups. Soviet and later Russian management of nuclear waste in the north has been significantly influenced by regulations and programmes generated under international dumping instruments. These international programmes have been supported by the active participation of the Navy itself in the belief that they would lead to transfer of technology and financial resources to Russia from the West. Inspection of military nuclear waste management is largely left to the Northern Fleet. As for monitoring, measurements were for a long time not taken near the dumping sites. As for regulations, the Northern Fleet continued dumping long into the 1990s without permission. Regarding compliance stimulation, foreign support has helped the Northern Fleet avoid dumping. 113 refs.

  10. Orbiter Water Dump Nozzles Redesign Lessons Learned

    Science.gov (United States)

    Rotter, Hank

    2017-01-01

    Hank Rotter, NASA Technical Fellow for Environmental Control and Life Support System, will provide the causes and lessons learned for the two Space Shuttle Orbiter water dump icicles that formed on the side of the Orbiter. He will present the root causes and the criticality of these icicles, along with the redesign of the water dump nozzles and lessons learned during the redesign phase.

  11. Anti-Dumping on and from China

    Institute of Scientific and Technical Information of China (English)

    Patrick H. Zhao

    2007-01-01

    @@ The past years saw an increased cases of anti-dumping on China mostly from the developed countries, some from developing countries. But Pakistan, a friendly neighbor to China, recently adds up to that list of ranks for an anti-dumping investigation on China.

  12. DUMPING SYNDROME IN A YOUNG-CHILD

    NARCIS (Netherlands)

    DEVRIES, TW; DODDEMA, JW; HEIJMANS, HSA

    1995-01-01

    We describe a 17-month-old child with dumping syndrome after plication of the right diaphragm. He presented with periods of abdominal distension and pallor, recurrent convulsions, glucosuria and refusal of Feeding. After changing the diet the symptoms disappeared. Conclusion Although dumping syndrom

  13. Formative mechanism of preferential solution flow during dump leaching

    Institute of Scientific and Technical Information of China (English)

    WU Ai-xiang; YIN Sheng-hua; LIU Jin-zhi; YANG Bao-hua

    2006-01-01

    Preferential flow is a rapid movement of solution through pores caused by coarse ores. Macropore is the main factor for the preferential flow. Macropore can be defined from three aspects. Segregation of the ores during dumping was studied according to particle kinematics. Small ores become smaller under the effect of acid and weathering. Clay in the rainwater from the hillside precipitates in the dump. Segregation and fine ores are the main causes in macropore. The permeability in coarse ores is better than that in fine ores. The mechanism in the preferential flows was studied combining the fast conducting effect of the macropore. Experimental result shows that, at certain application rate, fine ore area is saturated while large volume of solution flows laterally to the coarse ore area and leaks out quickly through the macropores. Thus the mechanism of preferential solution flows is further illustrated.

  14. THE EFFECT OF BIOSOLIDS ON MEDICAGO SATIVA AND FESTUCA ARUNDINACEEA PLANTS PHYTOREMEDIATION PROCESS OF WASTE DUMP

    Directory of Open Access Journals (Sweden)

    B. LIXANDRU

    2013-12-01

    Full Text Available The storage of waste dump gravely deteriorates the soil’s physical, chemical and biological properties, both in the storage area and the surrounding zones. In time, serious perturbations may occur in the biocenosis from the surrounding ecosystems, through the sweeping away of the inorganic matter or through precipitations. The main problem in this case is to find the most suitable phytoremediation method for these waste dumps, by sowing plant species (grasses, in order to stop the erosion generated by wind and rain. Establishing a herbaceous “carpet” , in time, is very difficult, because the waste dump contains no organic matter, has a weak water retaining capacity and has a high bareness index. The purpose of this study was the experimentation of a method of cultivating the waste dumps using alfalfa, fescue and biosolids as fertilizers.

  15. Heat transfer law in leaching dump

    Institute of Scientific and Technical Information of China (English)

    WU Ai-xiang; WANG Hong-jiang; XI Yong; YANG Bao-hua; LI Jian-feng; YIN Sheng-hua; ZHA Ke-bing

    2005-01-01

    Based on the law of temperature changes in the leaching dump and the forming process of heat flux, the basic balance equation of heat flow in dump was established, the dissipated heat flow from dump to the atmosphere was analyzed to estimate the surface temperature of the ore particle in dump and discover the law of forced heat convection of heat flow transfer in dump. And the lixiviate flow formula taking a certain heat flow out of dump was deduced by using the inversion method. Through theoretic analysis, combining Dexing copper mine heap leaching production practice, the results show that the heat flow of chalcopyrite leaching emitted is not so great, but the heat flow of pyrite leaching and sulphur oxidation produced take up a higher proportion of total heat flow; the dissipated heat flow takes up a lower proportion, and most of heat flow is absorbed by itself, thus the inside temperature rises gradually; and the saturation flow form for leaching is adopted, which makes the lixiviate seepage in the transitional flow or even in the turbulent flow, so as to accelerate the heat flow diffusing and keep the leaching dump temperature suitable for bacteria living.

  16. Investigation on the oxygen transport mechanisms in the Sarcheshmeh waste rock dumps

    Directory of Open Access Journals (Sweden)

    Saeed Yousefi

    2015-04-01

    present in some samples. The carbonate content as the major neutralizing agent was zero in all samples. Due to the presence of sulfide minerals, mainly as pyrite, and also lack of any carbonate minerals, the AMD generation from the Sarcheshmeh waste rocks during the weathering reactions is predictable. At the Sarcheshmeh mine waste, several secondary minerals such as butlerite, jarosite and gypsum were detected by XRD at some depths. Moreover, amorphous iron oxyhydroxide minerals visually observed in waste dumps were not detected by XRD due to being negligible and low level of crystallinity. Hence, they were measured in terms of (Feo-h by ASTM standard test method. The ASTM-D2492 standard test showed that pyrite, sulphate and iron oxyhydroxide minerals (Feo-h are present in all samples. Against the XRD method, the test even detected the negligible content of the minerals. The paste pH tests showed that 15 samples were acid-producing because they had pH lower than 4. On the basis of moisture content results, the samples by name A6, A7, B1 and B2 showed high level of moisture which can be sign of the particular status in them. Discussion According to the field observations, channels with a strong flow of warm and humid air were detected in the depth of 3 to 5 meters of the investigated waste rock dumps. High content of humidity (8.25 and 13.43 percent and sulfate (4.5 and 7.02 percent were observed together with low content of pyrite (1.5 and 6.23 percent and acidic paste pH values (3.13 and 2.88 around these channels. Therefore, from the relation of these occurrences, it can be inferred that the air convection is important for supply oxygen to pyrite oxidation in the waste dumps of Sarcheshmeh. The results also indicate that, two main factors including grain size distribution and formation of hardpan layer on top of old weathered rocks are responsible for the decreasing of oxygen transformation rate via the molecular diffusion mechanism through the waste rock dumps

  17. Modeling acid-gas generation from boiling chloride brines

    Directory of Open Access Journals (Sweden)

    Sonnenthal Eric

    2009-11-01

    Full Text Available Abstract Background This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Results Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150°C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. Conclusion The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual

  18. Modeling acid-gas generation from boiling chloride brines

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent

  19. Anti-Dumping on and from China

    Institute of Scientific and Technical Information of China (English)

    Patrick; H.Zhao

    2007-01-01

    The past years saw an increased cases of anti-dumping on China mostly from the developed countries,some from developing countries.But Pakistan,a friendly neighbor to China,recently adds up to that list of ranks for an anti-dumping investigation on China.It is the national interests that count most,after all. It gives out a signal that anti-dumping would be a frequent tool to defend or to attack. Evidences show China is a target for this trade remedy,but is also targeting others.

  20. Diagnostics for High Power Targets and Dumps

    CERN Document Server

    Gschwendtner, E

    2012-01-01

    High power targets are generally used for neutrino, antiproton, neutron and secondary beam production whereas dumps are needed in beam waste management. In order to guarantee an optimized and safe use of these targets and dumps, reliable instrumentation is needed; the diagnostics in high power beams around targets and dumps is reviewed. The suite of beam diagnostics devices used in such extreme environments is discussed, including their role in commissioning and operation. The handling and maintenance of the instrumentation components in high radiation areas is also addressed.

  1. 27 CFR 19.748 - Dump/batch records.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Dump/batch records. 19.748... OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Records and Reports Processing Account § 19.748 Dump/batch records. (a) Format of dump/batch records. Proprietor's dump/batch records shall contain,...

  2. Beam dumps design and local radiation protection at TERA synchrotron.

    Science.gov (United States)

    Porta, A; Campi, F; Agosteo, S

    2005-01-01

    The realisation of the National Center of Hadrontherapy was funded by the Italian Government in 2002. The Centre will be built in the area of Pavia (Italy). The synchrotron designed in the framework of this programme will accelerate protons and carbon ions up to 250 MeV and 400 MeV u(-1), respectively. Some of the main aspects which were taken into account in the design of the acceleration system are the patient's safety and the beam control. From this point of view an important role is played by the beam dumps in the synchrotron ring and upstream of the extraction system. In particular, an horizontal and a vertical beam dump will be installed in the synchrotron ring: the former will be used for lowering the beam intensity and the latter for beam abortion. The dump at the extraction will absorb the particles during the mounting and the falling ramps of the synchrotron magnetic cycle, thus extracting only the flat top of the ion spill. Beam dumps can produce intense fields of secondary radiation (neutrons, charged light-hadrons and photons) and high rates of induced activity, since they can absorb the beam completely. Usually they have to be shielded to protect the electronics during machine operation and to attenuate the radiation dose below the limits imposed by the law when the personnel access to the synchrotron hall. The part of the shielding design of the beam dumps concerning with the acceleration of protons was made using Monte Carlo simulations with the FLUKA code. Both induced activity and secondary radiation were taken into account. The shields against secondary radiation produced by carbon ions were designed, referring only to secondary neutrons, taking double-differential distributions from the literature as sources for the FLUKA simulations. The induced activity from carbon ions interactions was estimated analytically, using the data generated by the EPAX 2 code. The dose-equivalent rates from the induced radionuclides were calculated at 1 m from the

  3. pH-dependent leaching of dump coal ash - retrospective environmental analysis

    Energy Technology Data Exchange (ETDEWEB)

    Popovic, A.; Djordjevic, D. [University of Belgrade, Belgrade (Serbia). Dept. of Chemistry

    2009-07-01

    Trace and major elements in coal ash particles from dump of 'Nikola Tesla A' power plant in Obrenovac near Belgrade (Serbia) can cause pollution, due to leaching by atmospheric and surface waters. In order to assess this leaching potential, dump ash samples were subjected to extraction with solutions of decreasing pH values (8.50, 7.00, 5.50, and 4.00), imitating the reactions of the alkaline ash particles with the possible alkaline, neutral, and acidic (e.g., acid rain) waters. The most recently deposited ash represents the greatest environmental threat, while 'aged' ash, because of permanent leaching on the dump, was shown to have already lost this pollution potential. On the basis of the determined leachability, it was possible to perform an estimation of the acidity of the regional rainfalls in the last decades.

  4. [The effect of somatostatin in dumping syndrome].

    Science.gov (United States)

    Tulassay, Z; Tulassay, T; Szathmári, M; Gohér, A; Tamás, G

    1990-11-04

    The effect of cyclic somatostatin on early and late dumping syndrome was studied in 12 patients with gastric resection. Each patient underwent two glucose challenges with 75 grams of glucose administered orally. In the control study isotonic sodium chloride was given, while in the other study cyclic somatostatin in a dose of 250 micrograms bolus injection followed by infusion of 80 ng/kg/min for a period of 270 minutes. In the control study all patients showed subjective symptoms of the early dumping syndrome with significant increases in pulse rate, hematocrit, and vasoactive intestinal polypeptide. Ten patients showed asymptomatic hypoglycemia, as a sign of the late dumping syndrome associated with a significant increases of insulin, gastric inhibitory peptide and glucagon levels. During the administration of somatostatin these changes failed to develop. These results indicate that somatostatin alleviates the symptoms of early and late postprandial dumping syndrome.

  5. Technological assessment of a mining-waste dump at the Dexing copper mine, China, for possible conversion to an in situ bioleaching operation.

    Science.gov (United States)

    Wu, Aixiang; Yin, Shenghua; Wang, Hongjiang; Qin, Wenqin; Qiu, Guanzhou

    2009-03-01

    In order to extract copper metal from the waste dump of Dexing copper mine and resolve the environmental problems caused by acidic water and heavy metals, a dump bioleaching plant was designed based on a series of experimental investigations. The investigation shown that the low-grade of the dump, refractoriness of chalcopyrite, leakage of pad, small Acidithiobacillus population and low dump permeability are the main factors that contribute to the challenges faced by the plant. Stability of the high and steep slope of the dump is the other hidden danger to which much attention is not paid. To evaluate the potential unstability of the dump, the leaching process, ore surface erosion, particle size, chemical elements and mechanical properties of the waste rock in DCM were investigated through experiment in this paper.

  6. European Anti-dumping Law and China

    Directory of Open Access Journals (Sweden)

    Piet Eeckhout

    1997-04-01

    Full Text Available The paper examines recent developments in the European Union's anti-dumping policy, as it is applied towards China. It concentrates on recent court cases involving dumping from China and on the basic non-market economy issue. The author essentially argues that the European Union's policy does not take account sufficiently of China's development towards a market economy, and that there are various legal flaws in the way the policy is applied.

  7. [Postgastrectomy dumping treated with octreotide (Sandostatin)].

    Science.gov (United States)

    Møller, T D; Carlsen, C U

    1993-06-07

    Somatostatin and the long acting somatostatin analogue Sandostatin have been shown to be effective in the management of dumping syndrome. We describe a patient with early dumping in whom this management provided total symptomatic relief. The doses was reduced from 50 micrograms to 12.5 micrograms s.c., t.i.d. At this dose clinical and biochemical parameters (blood pressure, pulse rate, packed cell volume, hematocrit, and blood glucose) were found to be within normal levels.

  8. Establishment of ocean dumping area capacity assessment model

    Institute of Scientific and Technical Information of China (English)

    WANG Zhizu; ZUO Juncheng; XU Ren; JIN Zuowen; CHEN Meixiang

    2016-01-01

    Dumping area capacity is mainly affected by the hydrodynamic process (tidal sediment, storm surge and wave, etc.) as well as the size and depth of dumping area. Based on three-dimensional ocean circulation model known as FVCOM (Finite Volume Coast and Ocean Model) and the stochastic dynamic statistical analysis model, taking advantage of dumping ground topography evolution and dumping quantity, the author aims to discuss the influence of hydrodynamic processes and dumping activity so as to built a new model of ocean dumping area capacity. With the data of depth and dumped amount in the dumping area, the changes of bottom topographic which caused by tidal current under the natural condition based on the FVCOM hydrodynamic and sediment module, the author strive to analyze the statistical relation of the changes for dumping amount, tidal current and bottom topographic. Through real data to fit revision coefficient values, which will be regarded as topographic changes reference value affected by wave and storm surges. Thus taking this evaluation as the long-term changes in the dumping capacity. In the premise of setting up the threshold of bottom topographic changes, the dumping area capacity is calculated. Take Yangtze Estuary No. 1 dumping area as an example, As the water depth reduces by 0.5 m annually, the dumping area capacity is about 6.7 million m3/a, the model results are in reasonable agreement with the actual amount. Then the model is validated in Luoyuan Bay dumping area, Shengsishangchuan Mountain dumping area, Dongding dumping area, Dongshan dumping area, and Wenzhou Port dumping area, it is turns out the results are similar to that of the actual observations.

  9. Retinoic acid from the meninges regulates cortical neuron generation.

    Science.gov (United States)

    Siegenthaler, Julie A; Ashique, Amir M; Zarbalis, Konstantinos; Patterson, Katelin P; Hecht, Jonathan H; Kane, Maureen A; Folias, Alexandra E; Choe, Youngshik; May, Scott R; Kume, Tsutomu; Napoli, Joseph L; Peterson, Andrew S; Pleasure, Samuel J

    2009-10-30

    Extrinsic signals controlling generation of neocortical neurons during embryonic life have been difficult to identify. In this study we demonstrate that the dorsal forebrain meninges communicate with the adjacent radial glial endfeet and influence cortical development. We took advantage of Foxc1 mutant mice with defects in forebrain meningeal formation. Foxc1 dosage and loss of meninges correlated with a dramatic reduction in both neuron and intermediate progenitor production and elongation of the neuroepithelium. Several types of experiments demonstrate that retinoic acid (RA) is the key component of this secreted activity. In addition, Rdh10- and Raldh2-expressing cells in the dorsal meninges were either reduced or absent in the Foxc1 mutants, and Rdh10 mutants had a cortical phenotype similar to the Foxc1 null mutants. Lastly, in utero RA treatment rescued the cortical phenotype in Foxc1 mutants. These results establish RA as a potent, meningeal-derived cue required for successful corticogenesis.

  10. Vetiver Grass: a potential tool for phytoremediation of iron ore mine site spoil dump

    Directory of Open Access Journals (Sweden)

    Anita Mukherjee

    2015-06-01

    Full Text Available The impact of mining has lead to the generation of a large amount of spoil dumps that has become dangerous to human health, wildlife and biodiversity. Thus it is essential that the post mining areas and waste land generated need to be rapidly vegetated. Vetiver grass (Chrysopogon zizanioides (L. Roberty is a tropical plant which grows naturally in various soil conditions and is well known for its ability to resist DNA damage while growing on typically polluted soil conditions. The spoil dumps from the iron mine site is unstable and inhospitable for plant growth due to presence of various toxic heavy metals like - Fe, Mn, Zn, Cu, Pb, Ni, Cr, Cd etc. Vetiver system is an efficient bio-engineering tool for reclaiming such spoil dumps. There are 12 known species of Vetiver grass, and many hundreds of different cultivars that are exploited by users depending on need. In the present study we selected the polyploid infertile variety of vetiver and carried pot experiments. Vetiver plants grown on the iron ore mine spoil dump show distinct differences in their growth with fewer numbers of tillers, reduced chlorophyll content, upregulation of antioxidant enzymes and increased proline content. To investigate the level of DNA damage incurred and change in the genetic stability Comet assay and RAPD analysis were performed. Results confirmed that Vetiver grass can serve as a model species for phytoremediating the iron ore mine spoil dumps.

  11. Dumping the decelerated beams of CLIC

    CERN Document Server

    Jeanneret, Bernard

    2011-01-01

    The spent drive beam must be cleanly extracted and bent away from the decelerator axis at the end of each CLIC decelerator in order to leave space for injecting a fresh beam train in the next sector. Then the spent beam must be safely absorbed. A compact extraction system made of a single dipole is proposed. The spent beam is driven to a water dump located at 20m downstream of the extraction point and transversely 6m away of the axis of the main linac. An adequate spread of the beam impact map on the dump offers small temperature excursions in both the dump and its entrance window, allowing for reliable operation and a long lifetime of the system.

  12. Building and shaping overburden dumps in layers

    Energy Technology Data Exchange (ETDEWEB)

    Pichler, E.

    1988-08-01

    Discusses problem of stabilizing overburden dumps soon to be built to heights of 120-220 m at mines in the Krusna Hora brown coalfield. Describes mathematics involved in calculating critical height and stability of dumps with a constant slope angle and in determining critical height of layers with 32-38 degree slope angles. Shows in tabular form the relationship between degree of stability, critical height and type of material. Describes methods of constructing dumps in layers, which has become more viable with increasing development of belt conveyor technology. Methods described require use of ZP 2500 and ZP 6600 spreaders, but in future it is expected that ZP 10000 and ZP 13000 spreaders,which have longer reach, will be used to better effect. Concludes by giving examples of planned layer heights for the Merkur, Ceskoslovenska Armada and Jan Sverma mines, based on calculation of intergranular angle of internal friction. 5 refs.

  13. Measurements and predictions of surface gas fluxes and actual evaporation on mine waste rock dump

    Energy Technology Data Exchange (ETDEWEB)

    Kabwe, L.K.; Wilson, G.W. [British Columbia Univ., Vancouver, BC (Canada). Dept. of Mining and Mineral Process Engineering

    2006-07-01

    Long-term closure issues with respect to the mining industry and acid rock drainage (ARD) management require accurate measurements, predictions and monitoring of surface gas fluxes and actual evaporation on mine waste-rock dumps. This study uses a technique, called the dynamic closed chamber system (DCC) that measures the oxygen flux into mine waste dumps. The technique was used with an oxygen gas analyzer to directly measure the change in the oxygen concentration in the headspace of the chamber installed at the surface of the waste dumps. A SoilCover model was also used to predict evaporation fluxes on a waste-rock pile after heavy rainfall events. Measurement of actual evaporation across the surfaces of waste dumps is important in the design of soil covers. The paper discussed the site locations including the Key Lake uranium mine located at the southern rim of the Athabasca Basin in north central Saskatchewan as well as the Syncrude Canada Ltd. mine, located 30 km north of Fort McMurray, Alberta. Materials and methods used in the study as well as results and subsequent discussion were also presented. The effect of relative humidity and the effect of soil cover system on oxygen diffusion was reviewed. It was concluded that the SoilCover numerical model can be a useful tool for prediction of actual evaporation on mine waste dumps. 21 refs., 4 figs.

  14. LAW PROTECTION FOR DOMESTIC INDUSTRIES DUE TO DUMPING PRACTICE

    Directory of Open Access Journals (Sweden)

    Anita Kamilah

    2015-12-01

    Full Text Available International trade is business transactions conducted across borders, which has the goal accumulated maximum profit (profit optimal. In this implementation, corporations often do business by unfair competition, such as dumping, which could damage the order of the importing country trading system. The problem is what factors are causing a corporation carrying out the practice of dumping, and also; and How is legal protection against a country as a result of dumping practices. Factors that cause dumping, to profit by setting lower prices in the import market and the monopoly in the market of the importing country. A form of protection for countries that suffered losses as a result of dumping practices which could impose "anti-dumping duty", as a punishment for the exporting country. Due to losses caused by dumping, the government should make a law that specifically regulates the protection of domestic industry due to the practice of dumping.

  15. 30 CFR 57.9301 - Dump site restraints.

    Science.gov (United States)

    2010-07-01

    ... SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Loading, Hauling, and Dumping Safety Devices, Provisions, and Procedures for Roadways, Railroads, and Loading and Dumping Sites...

  16. Replacing the Beam Dump at the Booster

    CERN Multimedia

    2013-01-01

    The PS Booster Dump, designed in the 1960’s to cope with beam energies in the order of 800 MeV, has been dismantled and replaced with a new one, capable of withstanding the 2 GeV beam provided by the upcoming LINAC4 at CERN. This video shows the installation of that new dump core inside a one-metre diameter cavity, surrounded by five shielding rings made of concrete and steel. It is the culmination of months of preparation, an interdisciplinary work involving several teams from the Engineering, Beams and Technology Departments, as well as the collaboration and supervision of radio-protection experts.

  17. Replacing the Beam Dump at the Booster

    CERN Multimedia

    2013-01-01

    The PS Booster Dump, designed in the 1960’s to cope with beam energies in the order of 800 MeV, has been dismantled and replaced with a new one, capable of withstanding the 2 GeV beam provided by the upcoming LINAC4 at CERN. This video shows the installation of that new dump core inside a one-metre diameter cavity, surrounded by five shielding rings made of concrete and steel. It is the culmination of months of preparation, an interdisciplinary work involving several teams from the Engineering, Beams and Technology Departments, as well as the collaboration and supervision of radio-protection experts.

  18. Social dumping - supranational regulering og dens implikationer

    OpenAIRE

    Hansen, Mia Pough; Christensen, Nadja Zea Lintrup; Gregersen, Mille Natalie

    2015-01-01

    This paper aims at explaining why the institutional integration in the EU creates social dumping in Denmark. The study is based on a case study, which examines the posting of workers directive (96/71/EC). In explaining how the directive leads to social dumping, we use outcome-explanatory process-tracing. This is to examine how the causal mechanisms X, leads to an outcome Y. Concepts from Historical Institutionalism such as spill-over and Rational Choice Institutionalisms principal-agent theor...

  19. Thermal, mechanical and fluid flow aspects of the high power beam dump for FRIB

    Science.gov (United States)

    Avilov, Mikhail; Aaron, Adam; Amroussia, Aida; Bergez, Wladimir; Boehlert, Carl; Burgess, Thomas; Carroll, Adam; Colin, Catherine; Durantel, Florent; Ferrante, Paride; Fourmeau, Tiffany; Graves, Van; Grygiel, Clara; Kramer, Jacob; Mittig, Wolfgang; Monnet, Isabelle; Patel, Harsh; Pellemoine, Frederique; Ronningen, Reginald; Schein, Mike

    2016-06-01

    The Facility for Rare Isotope Beams (FRIB) under construction at Michigan State University is based on a 400 kW heavy ion accelerator and uses in-flight production and separation to generate rare isotope beams. The first section of the fragment separator houses the rare isotope production target, and the primary beam dump to stop the unreacted primary beam. The experimental program will use 400 kW ion beams from 16O to 238U. After interaction with the production target, over 300 kW in remaining beam power must be absorbed by the beam dump. A rotating water-cooled thin-shell metal drum was chosen as the basic concept for the beam dump. Extensive thermal, mechanical and fluid flow analyses were performed to evaluate the effects of the high power density in the beam dump shell and in the water. Many properties were optimized simultaneously, such as shell temperature, mechanical strength, fatigue strength, and radiation resistance. Results of the analyses of the beam dump performance with different design options will be discussed. For example, it was found that a design modification to the initial water flow pattern resulted in a substantial increase in the wall heat transfer coefficient. A detailed evaluation of materials for the shell is in progress. The widely used titanium alloy, Ti-6Al-4V (wt%), is presently considered as the best candidate, and is the subject of specific tests, such as studies of performance under heavy ion irradiation.

  20. First Operational Experience with the LHC Beam Dump Trigger Synchronisation Unit

    CERN Document Server

    Antoine, A; Magnin, N; Juteau, P; Voumard, N

    2011-01-01

    Two LHC Beam Dumping Systems (LBDS) remove the counter-rotating beams safely from the collider during setting up of the accelerator, at the end of a physics run and in case of emergencies. Dump requests can come from 3 different sources: the machine protection system in emergency cases, the machine timing system for scheduled dumps or the LBDS itself in case of internal failures. These dump requests are synchronized with the 3 μs beam abort gap in a fail-safe redundant Trigger Synchronization Unit (TSU) based on a Digital Phase Locked Loop (DPLL), locked onto the LHC beam revolution frequency with a maximum phase error of 40 ns. The synchronized trigger pulses coming out of the TSU are then distributed to the high voltage generators of the beam dump kickers through a redundant fault-tolerant trigger distribution system. This paper describes the operational experience gained with the TSU since its commissioning with beam in 2009, and highlights the improvements, which have been implemented f...

  1. Landfills - OPEN_DUMPS_IDEM_IN: Open Dump Sites in Indiana (Indiana Department of Environmental Management, Point Shapefile)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — OPEN_DUMPS_IDEM_IN is a point shapefile that contains open dump site locations in Indiana, provided by personnel of Indiana Department of Environmental Management,...

  2. 7 CFR 46.22 - Accounting for dumped produce.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 2 2010-01-01 2010-01-01 false Accounting for dumped produce. 46.22 Section 46.22... Market Receivers § 46.22 Accounting for dumped produce. A clear and complete record shall be maintained... justifying dumping shall be forwarded to the consignor or joint account partner with the accounting and...

  3. 30 CFR 56.19103 - Dumping facilities and loading pockets.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Dumping facilities and loading pockets. 56.19103 Section 56.19103 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR... Personnel Hoisting Shafts § 56.19103 Dumping facilities and loading pockets. Dumping facilities and...

  4. 45 CFR 152.28 - Preventing insurer dumping.

    Science.gov (United States)

    2010-10-01

    ... 45 Public Welfare 1 2010-10-01 2010-10-01 false Preventing insurer dumping. 152.28 Section 152.28...-EXISTING CONDITION INSURANCE PLAN PROGRAM Oversight § 152.28 Preventing insurer dumping. (a) General rule... for a determination of dumping. A PCIP shall establish procedures to identify and report to...

  5. 30 CFR 57.19103 - Dumping facilities and loading pockets.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Dumping facilities and loading pockets. 57.19103 Section 57.19103 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR... MINES Personnel Hoisting Shafts § 57.19103 Dumping facilities and loading pockets. Dumping...

  6. Radio frequency-driven proton source with a back-streaming electron dump.

    Science.gov (United States)

    Ji, Q; Sy, A; Kwan, J W

    2010-02-01

    This article describes an rf ion source with a back-streaming electron dump. A quartz tube, brazed to a metal plug at one end, is fused in the center of a flat quartz plate. rf power (at 13.6 MHz) is coupled to generate hydrogen plasma using a planar external antenna bonded to the window. Bonding the water-cooled rf antenna to the quartz window significantly lowers its temperature. The water-cooled metal plug serves as the back-streaming electron dump. At 1800 W, the current density of extracted hydrogen ions reaches approximately 125 mA/cm(2).

  7. The 40 kA dumping system for the ISR beams

    CERN Document Server

    Schnuriger, J C

    1975-01-01

    It has been necessary to build a fast and reliable system which can dump the beam whenever safety monitors indicate a hardware fault or a beam loss. The beam in each ISR is dumped by means of four fast pulsed magnets deflecting the particles vertically onto an absorber block situated in the same long straight section. The 0.75 Omega , 40 kA pulse generator now energizing the four fast pulsed magnets is described with special attention to the principles and technological solutions which were adopted in order to achieve the necessary reliability of the system for each type of operation, and particularly during long colliding beam experiments. (7 refs).

  8. Unique railcar dump cuts port costs

    Energy Technology Data Exchange (ETDEWEB)

    Harris, M.

    1986-07-01

    A key element in a Suneel Alaska Corp. coal transfer facility is a railcar dumping system, a pit and conveyor arrangement that transfers coal from railcars to temporary stockpiles. The same principles used in the design should have applications at other bulk unloading facilities. The $1.5 million system is compact, minimizes groundwater problems, and allows fast unloading from the railcar.

  9. Weighted Integrate-And-Dump Filter

    Science.gov (United States)

    Sadr, Ramin

    1989-01-01

    Digital weighted integrate-and-dump filter (WIDF) proposed for detection of weak rectangular-pulse signals corrupted by additive white Gaussian noise. Received signal first low-pass prefiltered, and samples taken at multiple of symbol frequency. Improved performance means lower sampling and processing rates used for given symbol rate, reducing cost of system.

  10. Radiation Protection Studies for LCLS Tune Up Dump

    Energy Technology Data Exchange (ETDEWEB)

    Santana-Leitner, M.; Fass, A.; Mao, S.; Nuhn, H.D.; /SLAC; Roesler, S.; /CERN; Rokni, S.; Vollaire, J.; /SLAC

    2010-04-29

    The Linac Coherent Light Source (LCLS) at the Stanford Linear Accelerator Center is a pioneer fourth generation hard x-ray free electron laser that shall start to deliver laser pulses in 2009. Among other components of LCLS that present radiation protection concerns, the tune up dump (tdund) is of special interest because it also constitutes an issue for machine protection, as it is placed close to radiation sensitive components, like electronic devices and permanent magnets in the undulators. This paper first introduces the stopper of tdund looking at the heat load, and then it describes the shielding around the dump necessary to maintain the prompt and residual dose within design values. Next, preliminary comparisons of the magnetization loss in a dedicated on-site magnet irradiation experiment with FLUKA simulations serve to characterize the magnetic response to radiation of magnets like those of LCLS. The previous knowledge, together with the limit for the allowed demagnetization, are used to estimate the lifetime of the undulator. Further simulations provide guidelines on which lifetime can be expected for an electronic device placed at a given distance of tdund.

  11. Rule of oxygen transmission in dump leaching

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    According to the chemical equations, the flux and concentration of oxygen required during bacterial leaching sulfuric mineral were investigated; the rule of air bubble transmitted in granular was researched in the Dump Leaching Plant of Dexing Copper Mine. The results show that lack of oxygen in dump leaching is the critical factor of restricting leaching reaction. Pyrite is the primary oxygen-consuming mineral in bioleaching. When its content is too high, it needs a great deal of oxygen for reaction and competes for the finite oxygen with objective minerals, and thus the leaching velocity decreases greatly. The average size of ore particles and diameter of bubbles are the key parameters affecting the mass transfer coefficient. Reverse analysis was adopted, and it shows that 44.8 m3 air per unit ore can meet the requirement of production if the molar ratio of pyrite to chalcopyrite is 10.

  12. At dumpe på FARMA

    DEFF Research Database (Denmark)

    Johannsen, Bjørn Friis

    Uddrag fra forord: "At dumpe på FARMA peger på flere centrale styrker i farmaceutuddannelsen. For det første at de studerende reelt er interesserede i farmaceutfaget når de optages på studiet, og de oplever velvilje fra underviserne. For det andet at studenterkulturen på studiet er stærk, således...

  13. Between social dumping and social protection

    DEFF Research Database (Denmark)

    Nielsen, Niels Jul; Sandberg, Marie

    2014-01-01

    In a world increasingly challenged by neoliberal restructurings of labour markets within the global economy, labour organisation is continuously challenged. Based on ethnographic fieldwork conducted among Polish construction workers in Denmark, both at their place of work and in their homes in De...... flexibility and availability, and that the composition of the migrant family significantly impacts how migratory practices are made feasible and desirable. Keywords: East-West migrants, labour mobility, social dumping, migrant families, ethnographic fieldwork...

  14. Quantitative mapping of particulate iron in an ocean dump using remotely sensed data

    Science.gov (United States)

    Ohlhorst, C. W.; Bahn, G. S.

    1978-01-01

    A remote sensing experiment was conducted at the industrial acid waste ocean dump site located approximately 38 n mi SE of Cape Henlopen, Delaware, to see if there was a relationship between aircraft remotely sensed spectral signatures and the iron concentration measured in the plume. Results are presented which show that aircraft remotely sensed spectral data can be used to quantify and map an acid waste dump in terms of its particulate iron concentration. A single variable equation using the ratio of band 2 (440-490 nm) radiance to band 4 (540-580 nm) radiance was used to quantify the acid plume and the surrounding water. The acid waste varied in age from freshly dumped to 3 1/2 hours old. Particulate iron concentrations in the acid waste were estimated to range up to 1.1 mg/liter at the 0.46 meter depth. A classification technique was developed to remove sunglitter-affected pixels from the data set.

  15. Vetiver Grass: a potential tool for phytoremediation of iron ore mine site spoil dump

    OpenAIRE

    Anita Mukherjee; Khanindra Pathak

    2015-01-01

    The impact of mining has lead to the generation of a large amount of spoil dumps that has become dangerous to human health, wildlife and biodiversity. Thus it is essential that the post mining areas and waste land generated need to be rapidly vegetated. Vetiver grass (Chrysopogon zizanioides (L.) Roberty) is a tropical plant which grows naturally in various soil conditions and is well known for its ability to resist DNA damage while growing on typically polluted soil conditions. The spoil dum...

  16. Assessment of bioaccumulation of heavy metals by different plant species grown on fly ash dump.

    Science.gov (United States)

    Jambhulkar, Hemlata P; Juwarkar, Asha A

    2009-05-01

    A field experiment was conducted on a 10-hectare area on fly ash dump at Khaperkheda Thermal Power Plant, Nagpur, India, where different ecologically and economically important plant species were planted using bioremediation technology. The technology involves the use of organic amendment and selection of suitable plant species along with site-specific nitrogen-fixing strains of biofertilizers. The study was conducted to find out the metal accumulation potential of different plant species. The total heavy metal contents in fly ash were determined and their relative abundance was found in the order of Fe>Mn>Zn>Cu>Ni>Cr>Pb>Cd. Fly ash samples had acidic pH, low electrical conductivity, low level of organic carbon and trace amounts of N and P. Plantation of divergent species was done on fly ash dump using the bioremediation technique. After 3 years of plantation, luxuriant growth of these species was found covering almost the entire fly ash dump. The results of the metal analysis of these species indicated that iron accumulated to the greatest extent in vegetation followed by Mn, Ni, Zn, Cu, Cr and Pb. Cassia siamea was found to accumulate all metals at higher concentrations compared to other species. The experimental study revealed that C. siamea could be used as a hyper-accumulator plant for bioremediation of fly ash dump.

  17. Arsenic mineralogy and mobility in the arsenic-rich historical mine waste dump.

    Science.gov (United States)

    Filippi, Michal; Drahota, Petr; Machovič, Vladimír; Böhmová, Vlasta; Mihaljevič, Martin

    2015-12-01

    A more than 250 year-old mine dump was studied to document the products of long-term arsenopyrite oxidation under natural conditions in a coarse-grained mine waste dump and to evaluate the environmental hazards associated with this material. Using complementary mineralogical and chemical approaches (SEM/EDS/WDS, XRD, micro-Raman spectroscopy, pore water analysis, chemical extraction techniques and thermodynamic PHREEQC-2 modeling), we documented the mineralogical/geochemical characteristics of the dumped arsenopyrite-rich material and environmental stability of the newly formed secondary minerals. A distinct mineralogical zonation was found (listed based on the distance from the decomposed arsenopyrite): scorodite (locally associated with native sulfur pseudomorphs) plus amorphous ferric arsenate (AFA/pitticite), kaňkite, As-bearing ferric (hydr)oxides and jarosite. Ferric arsenates and ferric (hydr)oxides were found to dissolve and again precipitate from downward migrating As-rich solutions cementing rock fragments. Acidic pore water (pH3.8) has elevated concentrations of As with an average value of about 2.9 mg L(-1). Aqueous As is highly correlated with pH (R2=0.97, pdump and underlying soil has been found to be very effective, suggesting limited environmental impact of the mine waste dump on the surrounding soil ecosystems.

  18. 40 CFR 227.16 - Basis for determination of need for ocean dumping.

    Science.gov (United States)

    2010-07-01

    ... ocean dumping. 227.16 Section 227.16 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) OCEAN DUMPING CRITERIA FOR THE EVALUATION OF PERMIT APPLICATIONS FOR OCEAN DUMPING OF MATERIALS Need for Ocean Dumping § 227.16 Basis for determination of need for ocean dumping. (a) A need for...

  19. 40 CFR 228.15 - Dumping sites designated on a final basis.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Dumping sites designated on a final... DUMPING CRITERIA FOR THE MANAGEMENT OF DISPOSAL SITES FOR OCEAN DUMPING § 228.15 Dumping sites designated on a final basis. (a)(1) The sites identified in this section are approved for dumping the...

  20. Results of the characterisation of the water dumped into the river Turia by dumping control actions in the sewer network in Paterna (Valencia, Spain); Resultados en la caracterizacion de las aguas vertidas al rio Turia por actuaciones en el control de vertidos en la red de saneamiento municipal de Paterna (Valencia)

    Energy Technology Data Exchange (ETDEWEB)

    Monteagudo Marin, V.

    2007-07-01

    In view of the seriousness of the problem of industrial waste dumped into the municipal sewer network in Paterna, the local council, in parallel to the construction of a waste water treatment plant in 2001, put in place a Dumping Control Plan run by Aigues de Paterna. The main aim of this plan is to monitor and control the dumping of waste water generated by industrial activities to make sure that the waste dumped in within the limits laid down by the Municipal Bye-Law on Waste Dumping. It also aims to detect possible focuses of contamination and eradicate them so as to eliminate the contaminating load in waste waters from industrial sources at origin, thereby contributing to the regeneration of the river and providing an appropriate affluent for the good functioning of the sewage works when it comes into service. (Author)

  1. Pd/C synthesized with citric acid: an efficient catalyst for hydrogen generation from formic acid/sodium formate.

    Science.gov (United States)

    Wang, Zhi-Li; Yan, Jun-Min; Wang, Hong-Li; Ping, Yun; Jiang, Qing

    2012-01-01

    A highly efficient hydrogen generation from formic acid/sodium formate aqueous solution catalyzed by in situ synthesized Pd/C with citric acid has been successfully achieved at room temperature. Interestingly, the presence of citric acid during the formation and growth of the Pd nanoparticles on carbon can drastically enhance the catalytic property of the resulted Pd/C, on which the conversion and turnover frequency for decomposition of formic acid/sodium formate system can reach the highest values ever reported of 85% within 160 min and 64 mol H(2) mol(-1) catalyst h(-1), respectively, at room temperature. The present simple, low cost, but highly efficient CO-free hydrogen generation system at room temperature is believed to greatly promote the practical application of formic acid system on fuel cells.

  2. Third generation capture system: precipitating amino acid solvent systems

    NARCIS (Netherlands)

    Sanchez Fernandez, E.; Misiak, K.; Ham, L. van der; Goetheer, E.L.V.

    2013-01-01

    This work summarises the results of the design of novel separation processes for CO2 removal from flue gas based on precipitating amino acid solvents. The processes here described (DECAB, DECAB Plus and pH-swing) use a combination of enhanced CO2 absorption (based on the Le Chatelier’s principle) an

  3. Dynamic characteristics of hydraulic power steering system with accumulator in load-haul-dump vehicle

    Institute of Scientific and Technical Information of China (English)

    杨忠炯; 何清华; 柳波

    2004-01-01

    Using hydraulic power steering system of model EIMCO 922 load-haul-dump vehicle as a simulation example, the dynamic characteristics of hydraulic power steering system in load-haul-dump vehicle were simulated and discussed with SIMULINK software and hydraulic control theory. The results show that the dynamic characteristics of hydraulic power steering system are improved obviously by using bladder accumulator, the hydraulic power steering system of model EIMCO 922 load-haul-dump vehicle generates vibration at the initial stage under the normal steering condition of pulse input, and its static response time is 0.25 s shorter than that without bladder accumulator. Under the normal steering working condition, the capacity of steering accumulator for absorbing pulse is directly proportional to the cross section area of connecting pipeline, and inversely proportional to the length of connecting pipeline. At the same time, the precharge pressure of nitrogen in steering accumulator should be 60%- 80% of the rated minimum working pressure of hydraulic power steering system. Under the abnormal steering working condition, the steering cylinder piston may obtain higher motion velocity, and the dynamic response velocity of hydraulic power steering system can be increased by reducing the pressure drop of hydraulic pipelines between the accumulator and steering cylinder and by increasing the rated pressure of hydraulic power steering system, but the dynamic characteristics of hydraulic power steering system in load-haul-dump vehicle have nothing to do with the precharge pressure of nitrogen in steering accumulator.

  4. Dumping syndrome after esophageal atresia repair without antireflux surgery.

    Science.gov (United States)

    Michaud, Laurent; Sfeir, Rony; Couttenier, Frédéric; Turck, Dominique; Gottrand, Frédéric

    2010-04-01

    In childhood, the surgical treatment of gastroesophageal reflux is the main cause of dumping syndrome. We report the cases of 2 children with esophageal atresia who presented with dumping syndrome without any precipitating known factors, such as gastroesophageal reflux surgery or associated microgastria. Our data suggest (1) that dumping syndrome can occur after primary anastomosis of esophageal atresia without antireflux surgery and (2) that dumping syndrome should be considered in every child treated surgically for esophageal atresia presenting with digestive symptoms, malaise, failure to thrive, or refusal to eat.

  5. Arsenic mineralogy and mobility in the arsenic-rich historical mine waste dump

    Energy Technology Data Exchange (ETDEWEB)

    Filippi, Michal, E-mail: filippi@gli.cas.cz [Institute of Geology, The Czech Academy of Sciences, v.v.i., Rozvojová 269, 165 00 Prague 6 (Czech Republic); Drahota, Petr [Institute of Geochemistry, Mineralogy and Mineral Resources, Faculty of Science, Charles University, Albertov 6, 128 43 Prague 2 (Czech Republic); Machovič, Vladimír [Institute of Chemical Technology Prague, Technická 5, 166 28 Prague 6 (Czech Republic); Böhmová, Vlasta [Institute of Geology, The Czech Academy of Sciences, v.v.i., Rozvojová 269, 165 00 Prague 6 (Czech Republic); Mihaljevič, Martin [Institute of Geochemistry, Mineralogy and Mineral Resources, Faculty of Science, Charles University, Albertov 6, 128 43 Prague 2 (Czech Republic)

    2015-12-01

    A more than 250 year-old mine dump was studied to document the products of long-term arsenopyrite oxidation under natural conditions in a coarse-grained mine waste dump and to evaluate the environmental hazards associated with this material. Using complementary mineralogical and chemical approaches (SEM/EDS/WDS, XRD, micro-Raman spectroscopy, pore water analysis, chemical extraction techniques and thermodynamic PHREEQC-2 modeling), we documented the mineralogical/geochemical characteristics of the dumped arsenopyrite-rich material and environmental stability of the newly formed secondary minerals. A distinct mineralogical zonation was found (listed based on the distance from the decomposed arsenopyrite): scorodite (locally associated with native sulfur pseudomorphs) plus amorphous ferric arsenate (AFA/pitticite), kaňkite, As-bearing ferric (hydr)oxides and jarosite. Ferric arsenates and ferric (hydr)oxides were found to dissolve and again precipitate from downward migrating As-rich solutions cementing rock fragments. Acidic pore water (pH 3.8) has elevated concentrations of As with an average value of about 2.9 mg L{sup −1}. Aqueous As is highly correlated with pH (R{sup 2} = 0.97, p < 0.001) indicating that incongruent dissolution of ferric arsenates controls dissolved As well as the pH of the percolating waste solution. Arsenic released from the dissolution of ferric arsenates into the pore water is, however, trapped by latter and lower-down precipitating jarosite and especially ferric (hydr)oxides. The efficiency of As sequestration by ferric (hydr)oxides in the waste dump and underlying soil has been found to be very effective, suggesting limited environmental impact of the mine waste dump on the surrounding soil ecosystems. - Highlights: • More than 250 year-old arsenopyrite-rich mine waste dump was studied. • Mineral transformation and the environmental stability of different secondary arsenic mineral phases were assessed. • High efficiency of As

  6. The Defects of WTO Anti-Dumping Rules and Related Reform

    Institute of Scientific and Technical Information of China (English)

    Xiao Wenhong

    2008-01-01

    @@ Since Canada made the first anti-dumping code in 1904, United States, Australia and France made their domestic anti-dumping codes successively.In 1947,the contracting parties made anti-dumping rules part of GATT (Article VI).

  7. 78 FR 60240 - Non-Application of Previously Withdrawn Regulatory Provisions Governing Targeted Dumping in...

    Science.gov (United States)

    2013-10-01

    ... Regulatory Provisions Governing Targeted Dumping in Antidumping Duty Investigations AGENCY: Import... implemented, the previously withdrawn regulatory provisions governing targeted dumping in antidumping duty... concerning the calculation of the weighted-average dumping margin and assessment rate in certain...

  8. Physical Composition, Nutrients and Contaminants of Typical Waste Dumping Sites

    Directory of Open Access Journals (Sweden)

    H. Meuser

    2011-01-01

    Full Text Available Problem statement: The composition of wastes is quite variable depending upon the generating source and mode of collection. Most of the material from the domestic activities will be organic in nature and contains essential plant nutrients, whereas the dumping material of commercial and industrial wastes usually contains appreciable amounts of heavy and potentially toxic metals and organic pollutants. Approach: Objective of the present study was to characterize the physico-chemical properties of the waste material and the distribution and extent of toxic pollutants in three selected typical dumping sites in the state of Haryana, India. Results: 62-65% of the waste fine material consisted of mineral particles and biodegradable organic waste, 20-25% consisted of construction and demolition waste and the remaining 10-15% were other materials such as study, plastic, metals, glass and timber, with an amount of polyethene of 3.4-5.7%. The ratio of the plant available concentrations of P, K and S and their total amounts were 3-7% for P and 1-4% for S, whereas the macronutrient potassium reached values of 29-39%. Metals As, Ba, Cd, Cr, Cu, Ni, Pb and Zn were present in all samples (total concentration in aqua regia extract. As, Ba, Ni and Pb did not show clear differences between the three investigates sites. Cd, Cr and Zn concentrations were high but different at the different sites (Cu maximum: 1,964 mg kg−1, Zn maximum: 2,200 mg kg−1. The mobility of the metals was calculated as the ratio of DTPA/aqua regia extraction. Cd showed the highest ratio (18-22%, while the other calculated metals showed much lower ratios (Cu 6.7, Pb 7.9 Ni 2.1, Zn 3.6 and Cr 0.5%. In general, PAH and benzo(apyrene concentrations fell below the detection limit. Also the phenol index did not exceed the detection limit of 1.2 mg kg−1 (with two exceptions. In 14 out of 36 samples a GC-MS screening was conducted in order to get an overview of the organic

  9. Field Assessment of Yeast- and Oxalic Acid-generated Carbon Dioxide for Mosquito Surveillance

    Science.gov (United States)

    2014-12-01

    generated by electro-stripping oxalic acid was produced by a Moustiq- AirTM CO2 generator (Med-e-Cell, San Diego, CA) powered with a lithium iron (Li...Moustiq- AirTM oxalic acid generator in the laboratory, and the positioning of (C) the 2 yeast tanks and (D) the Moustiq-Air when paired with a...Average flow rate (ml/min) 6 S0 generated by a single yeast-fermentation bottle (35 g yeast, 250 g sugar, 2.5 liters water), and by the Moustiq- AirTM

  10. Do mature hydrocarbons have an influence on acid rock drainage generation?

    OpenAIRE

    Jiménez-Castañeda, Martha E.; Boothman, Christopher; Lloyd, Jonathan R.; Vaughan, David J; van Dongen, Bart E.

    2016-01-01

    The generation of acid rock drainage (ARD) is a biogeochemical process that causes severe ecological impacts, threatening human health worldwide. Microbes involved in acid drainage reactions are generally considered autotrophic but heterotrophic and mixotrophic microorganisms have often been identified at ARD sites. This raises questions about the role of organic matter naturally present at these sites, such as mature hydrocarbons, in promoting the microbial processes underpinning ARD generat...

  11. 7 CFR 48.4 - Destroying or dumping.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 2 2010-01-01 2010-01-01 false Destroying or dumping. 48.4 Section 48.4 Agriculture Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards, Inspections, Marketing... dumping. Any person receiving produce in interstate commerce or in the District of Columbia for or...

  12. 7 CFR 46.23 - Evidence of dumping.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 2 2010-01-01 2010-01-01 false Evidence of dumping. 46.23 Section 46.23 Agriculture Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards, Inspections, Marketing... Receivers § 46.23 Evidence of dumping. Reasonable cause for destroying any produce exists when the...

  13. Experimental study on explosive mechanism of spontaneous combustion gangue dump

    Institute of Scientific and Technical Information of China (English)

    PAN Rong-kun; YU Ming-gao; LU Lai-xiang

    2009-01-01

    In order to explore the reason for the frequency explosion of spontaneous combustion coal gangue dump and get to know their explosion mechanism, established the experiment platform about spontaneous combustion coal gangue dump interoperable water. The gangue dump was heated using the external heat source, and rainy weather through water mist was simulated. Simulated experiment about explosion of spontaneous combustion coal gangue dump was carried out on the different conditions of the rainfall or not. The unusual gases produced in the course of gangue combustion and the changes in temperature were observed, and their impacts on the explosion of gangue dump were analyzed. The experimental results show that overall warming phenomenon of the gangue dump after watering occurred, the amount of H2 iS three times than that before watering,and the amount of CO is far greater than that on the conditions of no-watering, at the same time combining with local observation and tests. It is found that the content of the oxygen reduce with the temperature increasing; however, gangue dump internal hydrogen content increase unusually on the rainfall conditions at 90 ℃, but the local measuring points reach the explosion limit. The existence of the CO and H2 iS the main reason for inducing the explosion of spontaneous combustion coal gangue dump.

  14. 7 CFR 58.212 - Hopper or dump room.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Hopper or dump room. 58.212 Section 58.212 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards....212 Hopper or dump room. A separate room shall be provided for the transfer of bulk dry dairy...

  15. 30 CFR 56.9301 - Dump site restraints.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Dump site restraints. 56.9301 Section 56.9301 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE... § 56.9301 Dump site restraints. Berms, bumper blocks, safety hooks, or similar impeding devices...

  16. Argentina Imp Anti-dumping Duties on Tires from China

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    On June 22, Argentina made the final anti-dumping adjudication once tires from China; on July 6, the Argentina authorities released the No. 221 resolution in 2011 issued by the Ministry of Industry: Impose 23% anti-dumping duties off estate car tires, 10% on the tires of machinery or vehicles used for agriculture and forestation,

  17. Fast Dump of the ATLAS Toroids

    CERN Document Server

    Dudarev, A; Volpini, Giovanni; Dudarev, Alexey; Kate, Herman Ten

    2010-01-01

    The toroidal magnet system of the ATLAS Detector at CERN consists of a Barrel Toroid (BT) and two End Cap Toroids (ECT-A and ECT-C). Each toroid is built up from eight racetrack coils wound with an aluminum stabilized NbTi conductor and indirectly cooled by forced flow liquid helium. The three toroids operate in series at 20.5 kA with a total stored energy of 1.5 GJ. In order to verify the reliability and effectiveness of the quench protection system, series of fast dump tests have been performed first of the single toroids and finally of the entire toroidal magnet system. In this paper a model to simulate the fast dump of the ATLAS toroids in single mode operation and in full system configuration is presented. The model is validated through comparison with measured data extracted from the ramp-and-quench runs. The calculated energy dissipation in the various coils is in very good agreement (within 1-2\\%) with the enthalpy changes estimated from the temperature measurements of the different parts of the cold ...

  18. Manufacturing prototypes for LIPAC beam dump

    Energy Technology Data Exchange (ETDEWEB)

    Arranz, F., E-mail: fernando.arranz@ciemat.es [CIEMAT, Madrid (Spain); Brañas, B.; Iglesias, D. [CIEMAT, Madrid (Spain); Nomen, O. [IREC, Barcelona (Spain); Rapisarda, D.; Lapeña, J.; Muñoz, A. [CIEMAT, Madrid (Spain); Szcepaniak, B. [GALVANO-T, Windeck (Germany); Manini, J. [CARMAN, Madrid (Spain); Gómez, J. [TRINOS VACUUM, Valencia (Spain)

    2014-10-15

    Highlights: •Electroforming of copper and electronbeam welding techniques are compared. •Mechanical properties of Cu–stainless steel joint by electroforming are presented. •Achieved manufacturing tolerances are shown. •The difficulties and solutions for the complicated manufacturing are explained. -- Abstract: The purpose of the research is to define the most adequate manufacturing process for the dump of a linear deuteron accelerator. The deuteron beam can be pulsed as well as continuous with energies up to 9 MeV. The maximum beam power is 1.12 MW corresponding to a beam current of 125 mA. The requirements on the surface on which the deuterons will be stopped are quite demanding and the length and slenderness of the cone poses a considerable difficulty in the manufacturing process. The design of the beam dump is based on a copper cone 2500 mm long, 300 mm aperture and 5 to 6.5 mm thickness. Basically only two technologies were found feasible for the manufacturing of the cone: Electroforming and Electron Beam Welding (EBW). The article shows the main results found when manufacturing different prototypes.

  19. Biofertilizers for the revegetation of coal overburden dumps top materials

    Energy Technology Data Exchange (ETDEWEB)

    Nikhil, K. [Central Mining Research Institute, Dhanbad (India). Environmental Management Group

    2001-07-01

    Adding and improving nutrient status of overburden dump top material through biofertilizer for supporting vegetation and for sustainable spoil development, a pot experiment was conducted. In this, two bio-fertilizers namely bactin and phosphin in three doses were applied on overburden dump top material kept in pots growing two grass species. The growths were compared with control on dump and soil both. Results shows that overburden dump amended with bio-fertilizer at lowest dose have significant increase in growth over the control of dump material and soil in vetiver grass but failed to shows the same result in lemon grass. This may be due to different growth behaviour of the grasses. 14 refs., 2 tabs.

  20. The effect of somatostatin in dumping syndrome after gastric surgery.

    Science.gov (United States)

    Tulassay, Z; Tulassay, T; Gupta, R; Tamás, G

    1993-01-01

    The effect of somatostatin on early and late dumping syndrome was studied in 12 patients with gastric resection. Each patient underwent two glucose challenges with 75 gram of glucose administered orally. In the control study isotonic sodium chloride was given, while in the other study cyclic somatostatin in a dose of 80 ng/kg/min was given for a period of 270 minutes. In the control study all patients showed subjective symptoms of the early dumping syndrome with significant (p dumping syndrome associated with a significant (p dumping syndrome partly by inhibiting the vasoactive intestinal polypeptide, gastric inhibitory peptide and insulin release, which are increased in dumping syndrome and may, therefore, be implicated as to have an etiological role.

  1. A Study on Dumping Power Flow Fluctuation at Grid-Connection Point of Residential Micro-Grid with Clustered Photovoltaic Power Generation Systems Considering Difference in Solar Irradiance Patterns in Urban Districts

    Science.gov (United States)

    Kato, Takeyoshi; Yamawaki, Hiroshi; Suzuoki, Yasuo

    Power output fluctuation of photovoltaic power generation systems (PVSs) may cause negative impacts on the existing electric power system when the penetration of PVSs is quite large. A micro-grid consisting of clustered PVSs and a battery system would be one of the promising measures against negative impacts of clustered PVSs, while the capacity of battery system should be reduced as much as possible from the economic point of view. Because of the difference in output fluctuation among PVSs in the various locations, the total output fluctuations of PVSs would be relaxed due to the so-called “smoothing-effect”. By using data on solar irradiance simultaneously observed at five points, this study evaluates the total output fluctuation of several micro-grids and the required capacity of battery system, taking the smoothing effect into account. The main results are as follows. The balancing control is accomplished with the acceptable error by using the small capacity of battery system, while small output fluctuation still remains in each micro-grid. In such the situation, because the total fluctuation of five micro-grids is not so large, the acceptable error in balancing control can be increased by a few percentages, resulting in reduction in the required maximum power of battery system by a few ten percentages.

  2. Improved pretreatment of lignocellulosic biomass using enzymatically-generated peracetic acid.

    Science.gov (United States)

    Yin, DeLu Tyler; Jing, Qing; AlDajani, Waleed Wafa; Duncan, Shona; Tschirner, Ulrike; Schilling, Jonathan; Kazlauskas, Romas J

    2011-04-01

    Release of sugars from lignocellulosic biomass is inefficient because lignin, an aromatic polymer, blocks access of enzymes to the sugar polymers. Pretreatments remove lignin and disrupt its structure, thereby enhancing sugar release. In previous work, enzymatically generated peracetic acid was used to pretreat aspen wood. This pretreatment removed 45% of the lignin and the subsequent saccharification released 97% of the sugars remaining after pretreatment. In this paper, the amount of enzyme needed is reduced tenfold using first, an improved enzyme variant that makes twice as much peracetic acid and second, a two-phase reaction to generate the peracetic acid, which allows enzyme reuse. In addition, the eight pretreatment cycles are reduced to only one by increasing the volume of peracetic acid solution and increasing the temperature to 60 °C and the reaction time to 6h. For the pretreatment step, the weight ratio of peracetic acid to wood determines the amount of lignin removed.

  3. Gas Chromatography Analysis of Resin and Fatty Acids from Laboratory Generated Bleach Plant Effluents

    Institute of Scientific and Technical Information of China (English)

    Chhaya Sharma; S. Mohanty; S. Kumar; N.J. Rao

    2007-01-01

    Laboratory generated spent bleached liquor from the chlorination, caustic extraction stage of mixed wood kraft pulp processing has been analyzed both qualitatively and quantitatively for various resin & fatty acids by using GC. A number of resin acids,saturated and unsaturated fatty acids, chloro fatty and resin acid have been detected and their concentrations are estimated. The results are compared with results on different agriculture residue/hardwood pulps, which were reported earlier. The concentrations of various compounds detected have also been compared with their reported LC50 values.

  4. Changes of the soil environment affected by fly ash dumping site of the electric power plant

    Science.gov (United States)

    Weber, Jerzy; Gwizdz, Marta; Jamroz, Elzbieta; Debicka, Magdalena; Kocowicz, Andrzej

    2014-05-01

    In this study the effect of fly ash dumping site of the electric power plant on the surrounding soil environment was investigated. The fly ash dumping site collect wastes form brown coal combustion of Belchatow electric power station, central Poland. The dumping site is surrounding by forest, where pine trees overgrow Podzols derived from loose quartz sands. The soil profiles under study were located at a distance of 50, 100, 400 and 500 m from the dumping site, while control profiles were located 8 km away from the landfill. In all horizons of soil profiles the mpain hysico-chemical and chemical properties were determined. The humic substances were extracted from ectohumus horizons by Shnitzer's method, purified using XAD resin and freeze-dried. The fulvic acids were passed through a cation exchange column and freeze-dried. Optical density, elemental composition and atomic ratios were determined in the humic and fulvic acids. Organic carbon by KMnO4 oxidation was also determined in the organic soil horizons. The fly ash from the landfill characterized by high salinity and strong alkaline reaction (pH=10), which contributed significantly to the changes of the pH values in soils horizons. The alkalization of soils adjacent to the landfill was found, which manifested in increasing of pH values in the upper soil horizons. The impact of the landfill was also noted in the changes of the soil morphology of Podzols analysed. As a result of the alkalization, Bhs horizons have been converted into a Bs horizons. Leaching of low molecular humus fraction - typical for podzolization - has been minimized as a result of pH changes caused by the impact of the landfill, and originally occurring humic substances in the Bhs horizon (present in the control profiles) have been probably transported out of the soil profile and then into the groundwater.

  5. Dumping syndrome following gastric bypass: validation of the dumping symptom rating scale.

    Science.gov (United States)

    Laurenius, Anna; Olbers, Torsten; Näslund, Ingmar; Karlsson, Jan

    2013-06-01

    There is a lack of prevalent data for dumping syndrome (DS) and methods discriminating between different symptoms of the DS. A self-assessment questionnaire, the Dumping Symptom Rating Scale (DSRS), was developed. The aim was to measure the severity and frequency of nine dumping symptoms and to evaluate the construct validity of the DSRS. Pre- and 1 and 2 years after Roux-en-Y gastric bypass surgery, 47 adults and 82 adolescents completed the DSRS. Cognitive interview was performed. Reliability and construct validity were tested. Effect sizes (ES) of changes were calculated. Patients found the questionnaire relevant. A high proportion of the respondents reported no symptoms affecting them negatively at all (floor effects). However, 12 % stated, quite severe, severe, or very severe problems regarding fatigue after meal and half of them were so tired that they needed to lie down. Nearly 7 % reported quite severe, severe, or very severe problems dominated by nausea and 6 % dominated by fainting esteem. The internal consistency reliability was adequate for both severity (0.81-0.86) and frequency (0.76-0.84) scales. ES were small, since some subjects experienced symptoms already preoperatively. Although most patients reported no or mild dumping symptoms 1 and 2 years after gastric bypass surgery, around 12 % had persistent symptoms, in particular, postprandial fatigue, and needed to lie down. Another 7 % had problems with nausea and 6 % had problems with fainting esteem. The DSRS is a reliable screening tool to identify these patients.

  6. Oxygen dependency of one-electron reactions generating ascorbate radicals and hydrogen peroxide from ascorbic acid.

    Science.gov (United States)

    Boatright, William L

    2016-04-01

    The effect of oxygen on the two separate one-electron reactions involved in the oxidation of ascorbic acid was investigated. The rate of ascorbate radical (Asc(-)) formation (and stability) was strongly dependent on the presence of oxygen. A product of ascorbic acid oxidation was measurable levels of hydrogen peroxide, as high as 32.5 μM from 100 μM ascorbic acid. Evidence for a feedback mechanism where hydrogen peroxide generated during the oxidation of ascorbic acid accelerates further oxidation of ascorbic acid is also presented. The second one-electron oxidation reaction of ascorbic acid leading to the disappearance of Asc(-) was also strongly inhibited in samples flushed with argon. In the range of 0.05-1.2 mM ascorbic acid, maximum levels of measurable hydrogen peroxide were achieved with an initial concentration of 0.2 mM ascorbic acid. Hydrogen peroxide generation was greatly diminished at ascorbic acid levels of 0.8 mM or above.

  7. Was Mono Lake a 14C dump?

    Science.gov (United States)

    Maggs, William Ward

    This is a scientific story without an explanation, called a “mystery” and an “enigma” in articles by the people who discovered it. Confounded by evidence they cannot explain by natural processes, these scientists implicate human beings.One month ago in Eos, (June 7, 1988, p. 633), Wallace Broecker and Scott Stine reported abnormally high levels of radiogenic 14C in California's Mono Lake, now a National Historic Site. The only logical explanation, they proposed, is that someone secretly dumped a total of about 20 curies of 14C into the lake in two doses, sometime between 1952 and 1958 and again between 1966 and 1977. Broecker and Stine, geologists at Lamont-Doherty Geological Observatory in Palisades, N.Y., called on readers for information on the source of the 14C.

  8. Phytic acid suppresses ischemia-induced hydroxyl radical generation in rat myocardium.

    Science.gov (United States)

    Obata, Toshio; Nakashima, Michiko

    2016-03-05

    The present study examined whether ischemia-reperfusion-induced hydroxyl radical (·OH) generation was attenuated by myo-inositol hexaphosphoric acid (phytic acid). A flexibly mounted microdialysis technique was used to detect the generation of ·OH in in vivo rat hearts. To measure the level of ·OH, sodium salicylate in Ringer's solution (0.5mM or 0.5 nmol/μl/min) was infused directly through a microdialysis probe to detect the generation of ·OH as reflected by the nonenzymatic formation of 2,3-dihydroxybenzoic acid (2,3-DHBA). To confirm the generation of ·OH by Fenton-type reaction, iron(II) was infused through a microdialysis probe. A positive linear correlation between iron(II) and the formation of 2,3-DHBA (R(2)=0.983) was observed. However, the level of 2,3-DHBA in norepinephrine (100 μM) plus phytic acid (100 μM) treated group were significantly lower than those observed in norepinephrine-only-treated group (n=6, *pphytic acid on ischemia-reperfusion-induced ·OH generation, the heart was subjected to myocardial ischemia for 15 min by occlusion of the left anterior descending coronary artery (LAD). When the heart was reperfused, the normal elevation of 2,3-DHBA in the heart dialysate was not observed in animals pretreated with phytic acid. These results suggest that phytic acid is associated with antioxidant effect due to the suppression of iron-induced ·OH generation.

  9. Effects of acid accelerators on hydrogen generation from solid sodium borohydride using small scale devices

    Energy Technology Data Exchange (ETDEWEB)

    Murugesan, Sankaran; Subramanian, Vaidyanathan (Ravi) [Department of Chemical and Metallurgical Engineering, University of Nevada, Reno, NV 89557 (United States)

    2009-02-01

    This work describes hydrogen generation using a heterogeneous chemical system for small scale portable applications. Hydrogen generation using acidified water and solid sodium borohydride (NaBH{sub 4}) is presented. The effects of two modes of contacts - (1) a flow through type and (2) a diffusion type - contact in a 5 mm{sup 3} device are discussed. The effects of contacting several mineral and benign acids with NaBH{sub 4} are compared by monitoring hydrogen yield. Among the mineral acids examined, HCl generates a maximum hydrogen yield of 97% of the theoretical yield at 3N concentration. The benign acids are required in higher concentration compared to mineral acids. Formic acid produces 87% of the hydrogen yield at 12N. The products of the reaction have been characterized using scanning electron microscopy and X-ray diffraction. A combination of acid strength, porosity of the interface, and solubility of the byproducts contributes to the different hydrogen yields in the presence of various acids. (author)

  10. Elasticity of substitution and anti-dumping decisions

    DEFF Research Database (Denmark)

    Hansen, Jørgen Drud; Meinen, Philipp; Nielsen, Jørgen Ulff-Møller

    2014-01-01

    Motivated by a monopolistic competition model with market segmentation and international price discrimination, this paper analyzes whether there is an inverse relation between the elasticity of substitution and final ad valorem anti-dumping duties across products. We test this for 19 countries...... using data on anti-dumping from the Global Antidumping Database and US data at the 6-digit HS product level for the elasticity of substitution from Broda and Weinstein (Q J Econ 121(2):541–585, 2006). The results in our empirical investigation support a negative relation between the elasticity...... of substitution and the final ad valorem anti-dumping duties....

  11. Technical and Biological Reclamation of the Topolnica Tailing Dump

    OpenAIRE

    Dambov, Risto; Spasovski, Orce

    2009-01-01

    Flotation waste is disposed of into a canyon type of dump. Discharge has been done in layers for more than twenty-five years that has led to the present state of the tailing dump. Flotation of copper ore is one of the production process in the Buchim Copper Mine which seriously disturbs the surrounding land. The drastic disturbance has severely changed the chemical and physical properties of the dump which entails the need for reclamation of the newly created surrounding. Technical and biolog...

  12. [Prevalence of early and late dumping after gastric bypass].

    Science.gov (United States)

    Héraïef, R; Giusti, V

    2014-03-26

    Gastric bypass surgery is an effective treatment of obesity, bringing a significant weight loss and a major improvement of carbohydrate profile. However, in some patients, a deregulation in carbohydrate metabolism between insulin secretion and sensitivity is observed, whereupon early and late dumping happen. Their prevalence isn't well studied, although it seems that 10 to 20% of patients are affected. We've studied a cohort of 70 patients who undergone gastric bypass surgery at the CHUV. 18 (25.7%) patients have a positive anamnesis for early dumping and 10 (14.3%) for late dumping, being it superior as what is described in the literature.

  13. Challenges and plans for injection and beam dump

    CERN Document Server

    Barnes, M; Mertens, V; Uythoven, J

    2015-01-01

    The injection and beam dumping systems of the LHC will need to be upgraded to comply with the requirements of operation with the HL-LHC beams. The elements of the injection system concerned are the fixed and movable absorbers which protect the LHC in case of an injection kicker error and the injection kickers themselves. The beam dumping system elements under study are the absorbers which protect the aperture in case of an asynchronous beam dump and the beam absorber block. The operational limits of these elements and the new developments in the context of the HL-LHC project are described.

  14. SPIDER beam dump as diagnostic of the particle beam

    Science.gov (United States)

    Zaupa, M.; Dalla Palma, M.; Sartori, E.; Brombin, M.; Pasqualotto, R.

    2016-11-01

    The beam power produced by the negative ion source for the production of ion of deuterium extracted from RF plasma is mainly absorbed by the beam dump component which has been designed also for measuring the temperatures on the dumping panels for beam diagnostics. A finite element code has been developed to characterize, by thermo-hydraulic analysis, the sensitivity of the beam dump to the different beam parameters. The results prove the capability of diagnosing the beam divergence and the horizontal misalignment, while the entity of the halo fraction appears hardly detectable without considering the other foreseen diagnostics like tomography and beam emission spectroscopy.

  15. Beam dump experiment at future electron–positron colliders

    Directory of Open Access Journals (Sweden)

    Shinya Kanemura

    2015-12-01

    Full Text Available We propose a new beam dump experiment at future colliders with electron (e− and positron (e+ beams, BDee, which will provide a new possibility to search for hidden particles, like hidden photon. If a particle detector is installed behind the beam dump, it can detect the signal of in-flight decay of the hidden particles produced by the scatterings of e± beams off materials for dumping. We show that, compared to past experiments, BDee (in particular BDee at e+e− linear collider significantly enlarges the parameter region where the signal of the hidden particle can be discovered.

  16. SPIDER beam dump as diagnostic of the particle beam

    Energy Technology Data Exchange (ETDEWEB)

    Zaupa, M., E-mail: matteo.zaupa@igi.cnr.it; Sartori, E. [Università degli Studi di Padova, Via 8 Febbraio 2, Padova 35122 (Italy); Consorzio RFX, Corso Stati Uniti 4, Padova 35127 (Italy); Dalla Palma, M.; Brombin, M.; Pasqualotto, R. [Consorzio RFX, Corso Stati Uniti 4, Padova 35127 (Italy)

    2016-11-15

    The beam power produced by the negative ion source for the production of ion of deuterium extracted from RF plasma is mainly absorbed by the beam dump component which has been designed also for measuring the temperatures on the dumping panels for beam diagnostics. A finite element code has been developed to characterize, by thermo-hydraulic analysis, the sensitivity of the beam dump to the different beam parameters. The results prove the capability of diagnosing the beam divergence and the horizontal misalignment, while the entity of the halo fraction appears hardly detectable without considering the other foreseen diagnostics like tomography and beam emission spectroscopy.

  17. 30 CFR 56.9303 - Construction of ramps and dumping facilities.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Construction of ramps and dumping facilities... Loading, Hauling, and Dumping Safety Devices, Provisions, and Procedures for Roadways, Railroads, and Loading and Dumping Sites § 56.9303 Construction of ramps and dumping facilities. Ramps and...

  18. VLDL hydrolysis by LPL activates PPAR-alpha through generation of unbound fatty acids.

    Science.gov (United States)

    Ruby, Maxwell A; Goldenson, Benjamin; Orasanu, Gabriela; Johnston, Thomas P; Plutzky, Jorge; Krauss, Ronald M

    2010-08-01

    Recent evidence suggests that lipoproteins serve as circulating reservoirs of peroxisomal proliferator activated receptor (PPAR) ligands that are accessible through lipolysis. The present study was conducted to determine the biochemical basis of PPAR-alpha activation by lipolysis products and their contribution to PPAR-alpha function in vivo. PPAR-alpha activation was measured in bovine aortic endothelial cells following treatment with human plasma, VLDL lipolysis products, or oleic acid. While plasma failed to activate PPAR-alpha, oleic acid performed similarly to VLDL lipolysis products. Therefore, fatty acids are likely to be the PPAR-alpha ligands generated by VLDL lipolysis. Indeed, unbound fatty acid concentration determined PPAR-alpha activation regardless of fatty acid source, with PPAR-alpha activation occurring only at unbound fatty acid concentrations that are unachievable under physiological conditions without lipase action. In mice, a synthetic lipase inhibitor (poloxamer-407) attenuated fasting-induced changes in expression of PPAR-alpha target genes. Apolipoprotein CIII (apoCIII), an endogenous inhibitor of lipoprotein and hepatic lipase, regulated access to the lipoprotein pool of PPAR-alpha ligands, because addition of exogenous apoCIII inhibited, and removal of endogenous apoCIII potentiated, lipolytic PPAR-alpha activation. These data suggest that the PPAR-alpha response is generated by unbound fatty acids released locally by lipase activity and not by circulating plasma fatty acids.

  19. Thermal analysis of injection beam dump of high-intensity rapid-cycling synchrotron in J-PARC

    Science.gov (United States)

    Kamiya, J.; Saha, P. K.; Yamamoto, K.; Kinsho, M.; Nihei, T.

    2017-10-01

    The beam dump at the beam injection area in the J-PARC 3-GeV rapid cycling synchrotron (RCS) accepts beams that pass through the charge exchange foil without ideal electron stripping during the multi-turn beam injection. The injection beam dump consists of the beam pipe, beam stopper, radiation shield, and cooling mechanism. The ideal beam power into the injection beam dump is 400 W in the case of design RCS extraction beam power of 1 MW with a healthy foil, which has 99.7 % charge stripping efficiency. On the other hand, as a radiation generator, the RCS is permitted to be operated with maximum average beam power of 4 kW into the injection beam dump based on the radiation shielding calculation, in consideration of lower charge stripping efficiency due to the foil deterioration. In this research, to evaluate the health of the RCS injection beam dump system from the perspective of the heat generation, a thermal analysis was performed based on the actual configuration with sufficiently large region, including the surrounding concrete and soil. The calculated temperature and heat flux density distribution showed the validity of the mesh spacing and model range. The calculation result showed that the dumped 4 kW beam causes the temperature to increase up to 330, 400, and 140 °C at the beam pipe, beam stopper, and radiation shield, respectively. Although these high temperatures induce stress in the constituent materials, the calculated stress values were lower than the ultimate tensile strength of each material. Transient temperature analysis of the beam stopper, which simulated the sudden break of the charge stripper foil, demonstrated that one bunched beam pulse with the maximum beam power does not lead to a serious rise in the temperature of the beam stopper. Furthermore, from the measured outgassing rate of stainless steel at high temperature, the rise in beam line pressure due to additive outgassing from the heated beam pipe was estimated to have a negligible

  20. Formic Acid Free Flowsheet Development To Eliminate Catalytic Hydrogen Generation In The Defense Waste Processing

    Energy Technology Data Exchange (ETDEWEB)

    Lambert, Dan P.; Stone, Michael E.; Newell, J. David; Fellinger, Terri L.; Bricker, Jonathan M.

    2012-09-14

    The Defense Waste Processing Facility (DWPF) processes legacy nuclear waste generated at the Savannah River Site (SRS) during production of plutonium and tritium demanded by the Cold War. The nuclear waste is first treated via a complex sequence of controlled chemical reactions and then vitrified into a borosilicate glass form and poured into stainless steel canisters. Converting the nuclear waste into borosilicate glass canisters is a safe, effective way to reduce the volume of the waste and stabilize the radionuclides. Testing was initiated to determine whether the elimination of formic acid from the DWPF's chemical processing flowsheet would eliminate catalytic hydrogen generation. Historically, hydrogen is generated in chemical processing of alkaline High Level Waste sludge in DWPF. In current processing, sludge is combined with nitric and formic acid to neutralize the waste, reduce mercury and manganese, destroy nitrite, and modify (thin) the slurry rheology. The noble metal catalyzed formic acid decomposition produces hydrogen and carbon dioxide. Elimination of formic acid by replacement with glycolic acid has the potential to eliminate the production of catalytic hydrogen. Flowsheet testing was performed to develop the nitric-glycolic acid flowsheet as an alternative to the nitric-formic flowsheet currently being processed at the DWPF. This new flowsheet has shown that mercury can be reduced and removed by steam stripping in DWPF with no catalytic hydrogen generation. All processing objectives were also met, including greatly reducing the Slurry Mix Evaporator (SME) product yield stress as compared to the baseline nitric/formic flowsheet. Ten DWPF tests were performed with nonradioactive simulants designed to cover a broad compositional range. No hydrogen was generated in testing without formic acid.

  1. Database Dump - fRNAdb | LSDB Archive [Life Science Database Archive metadata

    Lifescience Database Archive (English)

    Full Text Available List Contact us fRNAdb Database Dump Data detail Data name Database Dump DOI 10.18908/lsdba.nbdc00452-002 De...scription of data contents Dump data from database in the original site: - fRNAdb.pdf: description of database... schema - fRNAdb_schema.sql: database schema - fRNAdb_table.7z: dump data (original) - fRNAdbtsv.zip: dump... data (tab separeted text) Data file File name: Database_Dump File URL: ftp://ftp....biosciencedbc.jp/archive/frnadb/LATEST/Database_Dump File size: 673 MB Simple search URL - Data acquisition

  2. Alcohol dose dumping: The influence of ethanol on hot-melt extruded pellets comprising solid lipids.

    Science.gov (United States)

    Jedinger, N; Schrank, S; Mohr, S; Feichtinger, A; Khinast, J; Roblegg, E

    2015-05-01

    The objective of the present study was to investigate interactions between alcohol and hot-melt extruded pellets and the resulting drug release behavior. The pellets were composed of vegetable calcium stearate as matrix carrier and paracetamol or codeine phosphate as model drugs. Two solid lipids (Compritol® and Precirol®) were incorporated into the matrix to form robust/compact pellets. The drug release characteristics were a strong function of the API solubility, the addition of solid lipids, the dissolution media composition (i.e., alcohol concentration) and correspondingly, the pellet wettability. Pellets comprising paracetamol, which is highly soluble in ethanol, showed alcohol dose dumping regardless of the matrix composition. The wettability increased with increasing ethanol concentrations due to higher paracetamol solubilities yielding increased dissolution rates. For pellets containing codeine phosphate, which has a lower solubility in ethanol than in acidic media, the wettability was a function of the matrix composition. Dose dumping occurred for formulations comprising solid lipids as they showed increased wettabilities with increasing ethanol concentrations. In contrast, pellets comprising calcium stearate as single matrix component showed robustness in alcoholic media due to wettabilities that were not affected by the addition of ethanol. The results clearly indicate that the physico-chemical properties of the drug and the matrix systems are crucial for the design of ethanol-resistant dosage forms. Moreover, hydrophobic calcium stearate can be considered a suitable matrix system that minimizes the risk of ethanol-induced dose dumping for certain API's.

  3. Generation of aliphatic acid anions and carbon dioxide by hydrous pyrolysis of crude oils

    Science.gov (United States)

    Kharaka, Y.K.; Lundegard, P.D.; Ambats, G.; Evans, William C.; Bischoff, J.L.

    1993-01-01

    Two crude oils with relatively high (0.60 wt%) and low (0.18 wt%) oxygen contents were heated in the presence of water in gold-plated reactors at 300??C for 2348 h. The high-oxygen oil was also heated at 200??C for 5711 h. The compositions of aqueous organic acid anions of the oils and of the headspace gases were monitored inn order to investigate the distribution of organic acids that can be generated from liquid petroleum. The oil with higher oxygen content generated about five times as much organic anions as the other oil. The dominant organic anions produced were acetate, propionate and butyrate. Small amounts of formate, succinate, methyl succinate and oxalate were also produced. The dominant oxygen-containing product was CO2, as has been observed in similar studies on the hydrous pyrolysis of kerogen. These results indicate that a significant portion (10-30%) of organic acid anions reported i be generated by thermal alteration of oils in reservoir rocks. The bulk of organic acid anions present in formation waters, however, is most likely generated by thermal alteration of kerogen in source rocks. Kerogen is more abundant than oil in sedimentary basins and the relative yields of organic acid anions reported from the hydrous pyrolysis of kerogen are much higher than the yields obtained for the two oils. ?? 1993.

  4. Tungsten-188/carrier-free rhenium-188 perrhenic acid generator system

    Science.gov (United States)

    Knapp, F.F. Jr.; Lisic, E.C.; Mirzadeh, S.; Callahan, A.P.

    1994-01-04

    A generator system has been invented for providing a carrier-free radioisotope in the form of an acid comprises a chromatography column in tandem fluid connection with an ion exchange column, the chromatography column containing a charge of a radioactive parent isotope. The chromatography column, charged with a parent isotope, is eluted with an alkali metal salt solution to generate the radioisotope in the form of an intermediate solution, which is passed through the ion-exchange column to convert the radioisotope to a carrier-free acid form. 1 figure.

  5. The Next Generation MOD: A Microchip Amino Acid Analyzer for Detecting Extraterrestrial Life

    Science.gov (United States)

    Mathies, R. A.; Hutt, L. D.; Bada, J. L.; Glavin, D.; Grunthaner, F. J.; Grunthaner, P. J.

    2000-01-01

    of an abiotic origin, although we have to consider the possibility that the racemic amino acids were generated from the racemization of biotically produced amino acids.

  6. The Next Generation MOD: A Microchip Amino Acid Analyzer for Detecting Extraterrestrial Life

    Science.gov (United States)

    Mathies, R. A.; Hutt, L. D.; Bada, J. L.; Glavin, D.; Grunthaner, F. J.; Grunthaner, P. J.

    2000-01-01

    of an abiotic origin, although we have to consider the possibility that the racemic amino acids were generated from the racemization of biotically produced amino acids.

  7. Applicability Comparison of Methods for Acid Generation Assessment of Rock Samples

    Science.gov (United States)

    Oh, Chamteut; Ji, Sangwoo; Yim, Giljae; Cheong, Youngwook

    2014-05-01

    Minerals including various forms of sulfur could generate AMD (Acid Mine Drainage) or ARD (Acid Rock Drainage), which can have serious effects on the ecosystem and even on human when exposed to air and/or water. To minimize the hazards by acid drainage, it is necessary to assess in advance the acid generation possibility of rocks and estimate the amount of acid generation. Because of its relatively simple and effective experiment procedure, the method of combining the results of ABA (Acid Base Accounting) and NAG (Net Acid Generation) tests have been commonly used in determining acid drainage conditions. The simplicity and effectiveness of the above method however, are derived from massive assumptions of simplified chemical reactions and this often leads to results of classifying the samples as UC (Uncertain) which would then require additional experimental or field data to reclassify them properly. This paper therefore, attempts to find the reasons that cause samples to be classified as UC and suggest new series of experiments where samples can be reclassified appropriately. Study precedents on evaluating potential acid generation and neutralization capacity were reviewed and as a result three individual experiments were selected in the light of applicability and compatibility of minimizing unnecessary influence among other experiments. The proposed experiments include sulfur speciation, ABCC (Acid Buffering Characteristic Curve), and Modified NAG which are all improved versions of existing experiments of Total S, ANC (Acid Neutralizing Capacity), and NAG respectively. To assure the applicability of the experiments, 36 samples from 19 sites with diverse geologies, field properties, and weathering conditions were collected. The samples were then subject to existing experiments and as a result, 14 samples which either were classified as UC or could be used as a comparison group had been selected. Afterwards, the selected samples were used to conduct the suggested

  8. CBP Active Dumping and Active Countervailing (AD/CVD) Cases

    Data.gov (United States)

    Department of Homeland Security — The datasets provide information from CBP's reference files on active anti-dumping and active countervailing cases. This data includes associated case numbers (if...

  9. Solid waste dumping site suitability analysis using geographic ...

    African Journals Online (AJOL)

    ... system (GIS) and remote sensing for Bahir Dar Town, North Western Ethiopia. ... African Journal of Environmental Science and Technology ... Solid waste dumping is a serious problem in the urban areas because most solid wastes are not ...

  10. Dumping syndrome, a cause of acquired glycogenic hepatopathy.

    Science.gov (United States)

    Resnick, Jeffrey M; Zador, Ivan; Fish, Daryl L

    2011-01-01

    A 2-year-old boy, having undergone fundoplication for gastroesophageal reflux disease and fed by gastrostomy, presented with recurrent emesis, syncope with hypoglycemia, and persistently elevated serum liver transaminase levels. Liver biopsy revealed hepatocellular glycogenosis by light and electron microscopy. Further evaluation showed no evidence of diabetes mellitus, glycogen storage disease, or corticosteroid use. Since the hyperglycemic-hyperinsulinemic state of dumping syndrome would provide a mechanism for hepatocellular glycogenosis, the biopsy findings prompted consideration of dumping syndrome. Metabolic evaluation confirmed the diagnosis of dumping syndrome, and appropriate dietary management led to sustained resolution of symptomatology and hypertransaminasemia. Dumping syndrome is proposed to be a cause of hepatocellular glycogenosis, the latter representing a form of acquired glycogenic hepatopathy.

  11. Numerical analysis of rainfall effects in external overburden dump

    Institute of Scientific and Technical Information of China (English)

    Radhakanta Koner⇑; Debashish Chakravarty

    2016-01-01

    The effect of slope angle for external overburden dump in response to average and heavy rainfall has been analyzed using a two dimensional finite difference method of transient water flow through unsaturated–saturated soil. The external dump stability is evaluated for five geomaterial types on the basis of globally accepted safety factor analysis technique, based on shear strength reduction approach using finite differ-ence method. The results obtained from the finite difference method of analysis indicate that the external dump with more than 30? slope angle is greatly influenced by the rainfall under the studied conditions for geomaterial 3, 4 and 5, whereas dumps with geomaterial 1 and 2 remain safe. The analysis shows that major slope failure is out of preview for the studied rainfall conditions.

  12. The evidence of toxic wastes dumping in Campania, Italy.

    Science.gov (United States)

    Marfe, Gabriella; Di Stefano, Carla

    2016-09-01

    The region of Campania (particularly Naples and Caserta) were subjected to extensive illegal dumping operations of toxic and radioactive wastes since the 1980s. The highly toxic wastes (HTW) dumping operations that have taken place both along the coast and the hinterland, have extremely adverse effects on health, livelihoods and the future prospect of sustainable development of the local population. The toxic wastes dumping in Campania is real and it has compromised (irreversibly) the human health, natural environment, food security and the long-term development prospects of the affected population. To reverse this tragic trend, it is necessery the identification, isolation and reclamation of the polluted sites and full assessment of the nature and the scale of the polluting chemicals and other hazardous wastes. The purpose of this review is to contribute significantly to the available evidence of the long-running toxic waste dumping in Campania and its negative impact on the health of population.

  13. Dump system concepts for the Future Circular Collider

    CERN Document Server

    Bartmann, Wolfgang; Barnes, Mike; Borburgh, Jan; Burkart, Florian; Goddard, Brennan; Kramer, Thomas; Lechner, Anton; Sanz Ull, Alejandro; Schmidt, Rudiger; Stoel, Linda; Ostojic, Ranko; Rodziewicz, Janusz Pawel; van Trappen, Pieter; Barna, Dani

    2017-01-01

    The Future Circular Collider (FCC-hh) beam dump system must provide a safe and reliable extraction and dilution of the stored beam onto a dump absorber. Energy deposition studies show that damage limits of presently used absorber materials will already be reached for single bunches at 50 TeV. A fast field rise of the extraction kicker is required in order to sufficiently separate swept single bunches on the extraction protection absorbers in case of an asynchronous beam dump. In line with this demand is the proposal of a highly segmented extraction kicker system which allows for accepting a single kicker switch erratic and thus, significantly reduces the probability of an asynchronous beam dump. Superconducting septa are foreseen to limit the overall system length and power consumption. Two extraction system concepts are presented and evaluated regarding overall system length, energy deposition on absorbers, hardware requirements, radiation issues, and layout flexibility.

  14. LHC beam dumping system Extraction channel layout and acceptance

    CERN Document Server

    Goddard, B; Uythoven, J; Veness, R; Weterings, W

    2003-01-01

    The LHC beam dumping system must safely abort the LHC beams under all conditions, including those resulting from abnormal behaviour of machine elements or subsystems of the beam dumping system itself. The extraction channels must provide sufficient aperture both for the circulating and extracted beams, over the whole energy range and under various beam parameters. These requirements impose tight constraints on the tolerances of various extraction channel components, and also on the allowed range of beam positions in the region of these components. Operation of the beam dumping system under various fault states has been considered, and the resulting apertures calculated. After describing briefly the beam dumping system and the extraction channel geometry, the various assumptions made in the analysis are presented, before deriving tolerance limits for the relevant equipment and beam parameters.

  15. TCDQ-TCT retraction and losses during asynchronous beam dump

    CERN Document Server

    Bracco, Chiara; Quaranta, Elena; CERN. Geneva. ATS Department

    2016-01-01

    The protection provided by the TCDQs in case of asynchronous beam dump depends strongly on their correct setup. They have to respect the strict hierarchy of the full collimation system and shield the tertiary collimators in the experimental regions. This MD aimed at performing asynchronous beam dump tests with different configurations, in order to assess the minimum allowed retraction between TCTs and TCDQs and, as a consequence, on the The protection provided by the TCDQs in case of asynchronous beam dump depends strongly on their correct setup. They have to respect the strict hierarchy of the full collimation system and shield the tertiary collimators in the experimental regions. This MD aimed at performing asynchronous beam dump tests with different configurations, in order to assess the minimum allowed retraction between TCTs and TCDQs and, as a consequence, on the β* reach.

  16. Results from the LHC Beam Dump Reliability Run

    CERN Document Server

    Uythoven, J; Carlier, E; Castronuovo, F; Ducimetière, L; Gallet, E; Goddard, B; Magnin, N; Verhagen, H

    2008-01-01

    The LHC Beam Dumping System is one of the vital elements of the LHC Machine Protection System and has to operate reliably every time a beam dump request is made. Detailed dependability calculations have been made, resulting in expected rates for the different system failure modes. A 'reliability run' of the whole system, installed in its final configuration in the LHC, has been made to discover infant mortality problems and to compare the occurrence of the measured failure modes with their calculations.

  17. Pricing aspect of valuable metals from tailing dumps

    OpenAIRE

    Bugarin, Mile; Slavković, Gordana; Marinković, Vladan

    2011-01-01

    The last decade is characterized with the trend of higher prices of ferrous and precious metals on the world markets. Copper, gold and silver have been produced for centuries in the Bor mining complex. Flotation tailing dumps were created by copper mining and processing with tested contents of valuable metals. Tailing dumps with significant content of metals can be exploitated and useful raw materials can be evaluated. This paper discusses the pricing aspect of these raw materials or price mo...

  18. Load Dump Analysis in a 42/14V DC-DC Converter for Automotive Applications

    Directory of Open Access Journals (Sweden)

    Mohamed Abdualla Shrud

    2013-07-01

    Full Text Available The paper presents a model for a dc-dc centralised based architecture using Matlab/Simulink for load dump analysis. As the electrical load varies for various driving conditions such as day or night, summer or winter; and city or country side, the analysis of load change is a very important parameter for system behaviour. In order to study the 42V power generation dynamic performance under load variations, step change in loads have been investigated. A detailed mathematical model for a 3-phase, 4 kW and 42V Lundell alternator average electrical equivalent circuit along with the DC/DC converter based architectures for dual-voltage systems has been covered in previous publications. Aspects of the steady-state output current capabilities, transient behaviour due to load dump on the 14/42V buses and the behaviour of the system model under different loads are assessed and results discussed. The performance of the 42V Lundell alternator with the interleaved six-phase buck dc-to-dc converter system is modelled using Simulink software to assess the effectiveness of the model and its transient behaviour. The simulated results are presented for the transient characteristics of the system for load dumps.

  19. Pathophysiology, diagnosis and management of postoperative dumping syndrome.

    Science.gov (United States)

    Tack, Jan; Arts, Joris; Caenepeel, Philip; De Wulf, Dominiek; Bisschops, Raf

    2009-10-01

    Dumping syndrome is a frequent complication of esophageal, gastric or bariatric surgery. Rapid gastric emptying, with the delivery to the small intestine of a significant proportion of solid food as large particles that are difficult to digest, is a key event in the pathogenesis of this syndrome. This occurrence causes a shift of fluid from the intravascular component to the intestinal lumen, which results in cardiovascular symptoms, release of several gastrointestinal and pancreatic hormones and late postprandial hypoglycemia. Early dumping symptoms comprise both gastrointestinal and vasomotor symptoms. Late dumping symptoms are the result of reactive hypoglycemia. Besides the assessment of clinical alertness and endoscopic or radiological imaging, a modified oral glucose tolerance test might help to establish a diagnosis. The first step in treating dumping syndrome is the introduction of dietary measures. Acarbose can be added to these measures for patients with hypoglycemia, whereas several studies advocate guar gum or pectin to slow gastric emptying. Somatostatin analogs are the most effective medical therapy for dumping syndrome, and a slow-release preparation is the treatment of choice. In patients with treatment-refractory dumping syndrome, surgical reintervention or continuous enteral feeding can be considered, but the outcomes of such approaches are variable.

  20. Chevron beam dump for ITER edge Thomson scattering system.

    Science.gov (United States)

    Yatsuka, E; Hatae, T; Vayakis, G; Bassan, M; Itami, K

    2013-10-01

    This paper contains the design of the beam dump for the ITER edge Thomson scattering system and mainly concerns its lifetime under the harsh thermal and electromagnetic loads as well as tight space allocation. The lifetime was estimated from the multi-pulse laser-induced damage threshold. In order to extend its lifetime, the structure of the beam dump was optimized. A number of bent sheets aligned parallel in the beam dump form a shape called a chevron which enables it to avoid the concentration of the incident laser pulse energy. The chevron beam dump is expected to withstand thermal loads due to nuclear heating, radiation from the plasma, and numerous incident laser pulses throughout the entire ITER project with a reasonable margin for the peak factor of the beam profile. Structural analysis was also carried out in case of electromagnetic loads during a disruption. Moreover, detailed issues for more accurate assessments of the beam dump's lifetime are clarified. Variation of the bi-directional reflection distribution function (BRDF) due to erosion by or contamination of neutral particles derived from the plasma is one of the most critical issues that needs to be resolved. In this paper, the BRDF was assumed, and the total amount of stray light and the absorbed laser energy profile on the beam dump were evaluated.

  1. Chevron beam dump for ITER edge Thomson scattering system

    Science.gov (United States)

    Yatsuka, E.; Hatae, T.; Vayakis, G.; Bassan, M.; Itami, K.

    2013-10-01

    This paper contains the design of the beam dump for the ITER edge Thomson scattering system and mainly concerns its lifetime under the harsh thermal and electromagnetic loads as well as tight space allocation. The lifetime was estimated from the multi-pulse laser-induced damage threshold. In order to extend its lifetime, the structure of the beam dump was optimized. A number of bent sheets aligned parallel in the beam dump form a shape called a chevron which enables it to avoid the concentration of the incident laser pulse energy. The chevron beam dump is expected to withstand thermal loads due to nuclear heating, radiation from the plasma, and numerous incident laser pulses throughout the entire ITER project with a reasonable margin for the peak factor of the beam profile. Structural analysis was also carried out in case of electromagnetic loads during a disruption. Moreover, detailed issues for more accurate assessments of the beam dump's lifetime are clarified. Variation of the bi-directional reflection distribution function (BRDF) due to erosion by or contamination of neutral particles derived from the plasma is one of the most critical issues that needs to be resolved. In this paper, the BRDF was assumed, and the total amount of stray light and the absorbed laser energy profile on the beam dump were evaluated.

  2. Acidogenic fermentation of food waste for volatile fatty acid production with co-generation of biohydrogen.

    Science.gov (United States)

    Dahiya, Shikha; Sarkar, Omprakash; Swamy, Y V; Mohan, S Venkata

    2015-04-01

    Fermentation experiments were designed to elucidate the functional role of the redox microenvironment on volatile fatty acid (VFA, short chain carboxylic acid) production and co-generation of biohydrogen (H2). Higher VFA productivity was observed at pH 10 operation (6.3g/l) followed by pH 9, pH 6, pH 5, pH 7, pH 8 and pH 11 (3.5 g/l). High degree of acidification, good system buffering capacity along with co-generation of higher H2 production from food waste was also noticed at alkaline condition. Experiments illustrated the role of initial pH on carboxylic acids synthesis. Alkaline redox conditions assist solubilization of carbohydrates, protein and fats and also suppress the growth of methanogens. Among the carboxylic acids, acetate fraction was higher at alkaline condition than corresponding neutral or acidic operations. Integrated process of VFA production from waste with co-generation of H2 can be considered as a green and sustainable platform for value-addition.

  3. Near-infrared laser-induced generation of three rare conformers of glycolic acid.

    Science.gov (United States)

    Halasa, Anna; Lapinski, Leszek; Reva, Igor; Rostkowska, Hanna; Fausto, Rui; Nowak, Maciej J

    2014-07-31

    Structural transformations were induced in conformers of glycolic acid by selective excitation with monochromatic tunable near-infrared laser light. For the compound isolated in Ar matrixes, near-IR excitation led to generation of two higher-energy conformers (GAC; AAT) differing from the most stable SSC form by 180° rotation around the C-C bond. A detailed investigation of this transformation revealed that one conformer (GAC) is produced directly from the near-IR-excited most stable conformer. The other higher-energy conformer (AAT) was effectively generated only upon excitation of the primary photoproduct (GAC) with another near-IR photon. Once these higher-energy conformers of glycolic acid were generated in an Ar matrix, they could be subsequently transformed into one another upon selective near-IR excitations. Interestingly, no repopulation of the initial most stable SSC conformer occurred upon near-IR excitation of the higher-energy forms of the compound isolated in solid Ar. A dramatically different picture of near-IR-induced conformational transformations was observed for glycolic acid isolated in N2 matrixes. In this case, upon near-IR excitation, the most stable SSC form converted solely into a new conformer (SST), where the acid OH group is rotated by 180°. This conformational transformation was found to be photoreversible. Moreover, SST conformer, photoproduced in the N2 matrix, spontaneously converted to the most stable SSC form of glycolic acid, when the matrix was kept at cryogenic temperature and in the dark.

  4. Brewer’s Spent Grain Valorization Using Phosphoric Acid Pretreatment for Second Generation Bioethanol Production

    DEFF Research Database (Denmark)

    Romero, I.; Ruiz, E.; Cara, C.

    Brewer’s spent grain constitutes a byproduct of beer making process yearly generated in big amounts and lacking of economic feasible applications. This lignocellulosic residue was characterized and pretreated by dilute phosphoric acid according to a rotatable central composite design to evaluate ...

  5. Effect of humic acids on electricity generation integrated with xylose degradation in microbial fuel cells

    DEFF Research Database (Denmark)

    Huang, Liping; Angelidaki, Irini

    2008-01-01

    Pentose and humic acids (HA) are the main components of hydrolysates, the liquid fraction produced during thermohydrolysis of lignocellulosic material. Electricity generation integrated with xylose (typical pentose) degradation as well as the effect of HA on electricity production in microbial fu...

  6. Coal recovery from a coal waste dump

    Directory of Open Access Journals (Sweden)

    Rozanski Zenon

    2016-01-01

    Full Text Available The possibilities and efficiency of coal recovery from the waste material located at the Central Coal Waste Dump in Poland were presented in this paper. The waste material includes significant amount of fly ash. Research conducted into determination of energetic properties of such wastes showed that the average ash content was 75.75% and the average gross calorific value was 7.81 MJ/kg. Coal was gravitationally separated from the waste material in a pulsatory jig and in a spiral washer including size fractions: 30-5 and 8-0 mm (this was crushed to a size <3.2 mm, respectively. The application of the pulsatory jig (pulse classifier allowed to obtain a high-quality energetic concentrate with the ash content lower than 12% and the gross calorific value higher than 26 MJ/kg (with average yield 7.8%. The spiral separator gave much worse results. The average gross calorific value for the concentrate was 11.6 MJ/kg, with the high ash content 56.5% and yield approximately 26%.

  7. Generation of fatty acids by an acyl esterase in the bioluminescent system of Photobacterium phosphoreum

    Energy Technology Data Exchange (ETDEWEB)

    Carey, L.M.; Rodriguez, A.; Meighen, E.

    1984-08-25

    The fatty acid reductase complex from Photobacterium phosphoreum has been discovered to have a long chain ester hydrolase activity associated with the 34K protein component of the complex. This protein has been resolved from the other components (50K and 58K) of the fatty acid reductase complex with a purity of > 95% and found to catalyze the transfer of acyl groups from acyl-CoA primarily to thiol acceptors with a low level of transfer to glycerol and water. Addition of the 50K protein of the complex caused a dramatic change in specificity increasing the transfer to oxygen acceptors. The acyl-CoA hydrolase activity increased almost 10-fold, and hence free fatty acids can be generated by the 34K protein when it is present in the fatty acid reductase complex. Hydrolysis of acyl-S-mercaptoethanol and acyl-1-glycerol and the ATP-dependent reduction of the released fatty acids to aldehyde for the luminescent reaction were also demonstrated for the reconstituted fatty acid reductase complex, raising the possibility that the immediate source of fatty acids for this reaction in vivo could be the membrane lipids and/or the fatty acid synthetase system.

  8. Acceleration of Enantioselective Cycloadditions Catalyzed by Second-Generation Chiral Oxazaborolidinium Triflimidates by Biscoordinating Lewis Acids.

    Science.gov (United States)

    Thirupathi, Barla; Breitler, Simon; Mahender Reddy, Karla; Corey, E J

    2016-08-31

    The activation of second-generation fluorinated oxazaborolidines by the strong acid triflimide (Tf2NH) in CH2Cl2 solution leads to highly active chiral Lewis acids that are very effective catalysts for (4 + 2) cycloaddition. We report herein that this catalytic activity can be further enhanced by the use of Tf2NH in combination with the biscoordinating Lewis acid TiCl4 or SnCl4 as a coactivator. The effective increase in acidity of an exceedingly strong protic acid is greater for biscoordinating TiCl4 and SnCl4 than for monocoordinating salts, even the strong Lewis acids AlBr3 and BBr3 in CH2Cl2 or CH2Cl2/toluene. The increase in the effective acidity of Tf2NH can be understood in terms of a stabilized cyclic anionic complex of Tf2N(-) and TiCl4, which implies a broader utility than that described here. The utility of Tf2NH-TiCl4 activation of fluorinated oxazaborolidines is documented by examples including the first enantioselective (4 + 2) cycloaddition to α,β-unsaturated acid chlorides.

  9. Pre- and post-remediation characterization of acid-generating fluvial tailings material

    Science.gov (United States)

    Smith, Kathleen S.; Walton-Day, Katherine; Hoal, Karin O.; Driscoll, Rhonda L.; Pietersen, K.

    2012-01-01

    The upper Arkansas River south of Leadville, Colorado, USA, contains deposits of fluvial tailings from historical mining operations in the Leadville area. These deposits are potential non-point sources of acid and metal contamination to surface- and groundwater systems. We are investigating a site that recently underwent in situ remediation treatment with lime, fertilizer, and compost. Pre- and post-remediation fluvial tailings material was collected from a variety of depths to examine changes in mineralogy, acid generation, and extractable nutrients. Results indicate sufficient nutrient availability in the post-remediation near-surface material, but pyrite and acid generation persist below the depth of lime and fertilizer addition. Mineralogical characterization performed using semi-quantitative X-ray diffraction and quantitative SEM-based micro-mineralogy (Mineral Liberation Analysis, MLA) reveal formation of gypsum, jarosite, and complex coatings surrounding mineral grains in post-remediation samples.

  10. Second-harmonic generation in mixed stilbazium salt/arachidic acid Langmuir-Blodgett films

    Science.gov (United States)

    Liu, Liying; Zheng, Jiabiao; Wang, Wencheng; Zhang, Zhiming; Tao, Fenggang; Xu, Linxiao; Hu, Jiacong

    1992-10-01

    A stilbazium salt was synthesized and its second-order molecular polarizability was deduced to be 1.2×10 -27 esu. Measurements of second-harmonic generation and small-angle X-ray diffraction on Langmuir-Blodgett films of the stilbazium salt/arachide acid mixtures showed that the mixed compounds with molar ratios of 1:2 and 1:5 could form multilayers with large second- order optical nonlinearity. Second harmonic generation study on the alternate multilayers of stilbazium salt/arachide acid and arachidic acid showed that the second-harmonic signals were increasing monotonously up to 80 bilayers, but the increment was lower than the value predicted theoretically by the quadratic law. Possible reasons are discussed.

  11. Melatonin prevents myeloperoxidase heme destruction and the generation of free iron mediated by self-generated hypochlorous acid.

    Directory of Open Access Journals (Sweden)

    Faten Shaeib

    Full Text Available Myeloperoxidase (MPO generated hypochlorous acid (HOCl formed during catalysis is able to destroy the MPO heme moiety through a feedback mechanism, resulting in the accumulation of free iron. Here we show that the presence of melatonin (MLT can prevent HOCl-mediated MPO heme destruction using a combination of UV-visible photometry, hydrogen peroxide (H2O2-specific electrode, and ferrozine assay techniques. High performance liquid chromatography (HPLC analysis showed that MPO heme protection was at the expense of MLT oxidation. The full protection of the MPO heme requires the presence of a 1:2 MLT to H2O2 ratio. Melatonin prevents HOCl-mediated MPO heme destruction through multiple pathways. These include competition with chloride, the natural co-substrate; switching the MPO activity from a two electron oxidation to a one electron pathway causing the buildup of the inactive Compound II, and its subsequent decay to MPO-Fe(III instead of generating HOCl; binding to MPO above the heme iron, thereby preventing the access of H2O2 to the catalytic site of the enzyme; and direct scavenging of HOCl. Collectively, in addition to acting as an antioxidant and MPO inhibitor, MLT can exert its protective effect by preventing the release of free iron mediated by self-generated HOCl. Our work may establish a direct mechanistic link by which MLT exerts its antioxidant protective effect in chronic inflammatory diseases with MPO elevation.

  12. Monounsaturated Fatty Acids Are Substrates for Aldehyde Generation in Tellurite-Exposed Escherichia coli

    Directory of Open Access Journals (Sweden)

    Gonzalo A. Pradenas

    2013-01-01

    Full Text Available Reactive oxygen species (ROS damage macromolecules and cellular components in nearly all kinds of cells and often generate toxic intracellular byproducts. In this work, aldehyde generation derived from the Escherichia coli membrane oxidation as well as membrane fatty acid profiles, protein oxidation, and bacterial resistance to oxidative stress elicitors was evaluated. Studies included wild-type cells as well as cells exhibiting a modulated monounsaturated fatty acid (MUFA ratio. The hydroxyaldehyde 4-hydroxy 2-nonenal was found to be most likely produced by E. coli, whose levels are dependent upon exposure to oxidative stress elicitors. Aldehyde amounts and markers of oxidative damage decreased upon exposure to E. coli containing low MUFA ratios, which was paralleled by a concomitant increase in resistance to ROS-generating compounds. MUFAs ratio, lipid peroxidation, and aldehyde generation were found to be directly related; that is, the lower the MUFAs ratio, the lower the peroxide and aldehyde generation levels. These results provide additional evidence about MUFAs being targets for membrane lipid oxidation and their relevance in aldehyde generation.

  13. Modelling reactive transport in a phosphogypsum dump, Venezia, Italia

    Science.gov (United States)

    Calcara, Massimo; Borgia, Andrea; Cattaneo, Laura; Bartolo, Sergio; Clemente, Gianni; Glauco Amoroso, Carlo; Lo Re, Fabio; Tozzato, Elena

    2013-04-01

    We develop a reactive-transport porous media flow model for a phosphogypsum dump located on the intertidal deposits of the Venetian Lagoon: 1. we construct a complex conceptual and geologic model from field data using the GMS™ graphical user interface; 2. the geological model is mapped onto a rectangular MODFLOW grid; 3. using the TMT2 FORTRAN90 code we translate this grid into the MESH, INCON and GENER input files for the TOUGH2 series of codes; 4. we run TOUGH-REACT to model flow and reactive transport in the dump and the sediments below it. The model includes 3 different dump materials (phosphogypsum, bituminous and hazardous wastes) with the pores saturated by specific fluids. The sediments below the dump are formed by an intertidal sequence of calcareous sands and silts, in addition to clays and organic deposits, all of which are initially saturated with lagoon salty waters. The recharge rain-water dilutes the dump fluids. In turn, the percolates from the dump react with the underlying sediments and the sea water that saturates them. Simulation results have been compared with chemical sampled analyses. In fact, in spite of the simplicity of our model we are able to show how the pH becomes neutral at a short distance below the dump, a fact observed during aquifer monitoring. The spatial and temporal evolution of dissolution and precipitation reactions occur in our model much alike reality. Mobility of some elements, such as divalent iron, are reduced by specific and concurrent conditions of pH from near-neutrality to moderately high values and positive redox potential; opposite conditions favour mobility of potentially toxic metals such as Cr, As Cd and Pb. Vertical movement are predominant. Trend should be therefore heavily influenced by pH and Eh values. If conditions are favourable to mobility, concentration of these substances in the bottom strata could be high. However, simulation suggest that the sediments tend to reduce the transport potential of

  14. Plant occurrence on burning coal waste – a case study from the Katowice-Wełnowiec dump, Poland

    Directory of Open Access Journals (Sweden)

    Ciesielczuk Justyna

    2015-06-01

    Full Text Available Coal-waste dumps superimposed on former rubbish dump frequently undergo selfheating and selfignition of organic matter dispersed in the waste. The special conditions for plant growth generated as a result have been investigated since 2008 on the municipal dump reclaimed with coal wastes in Katowice-Wełnowiec, Poland. The plants observed most frequently where heating has occurred are Sisymbrium loeselii, Artemisia vulgaris, Sonchus arvensis, Chenopodium album, Achillea millefolium, Cirsium arvense, Amaranthus retroflexus, Atriplex nitens and Solanum nigrum. Some new, rare species such as Portulaca oleracea, first noticed in 2011, may be added. Most of encroaching species are annual, alien archeophytes and neophytes. Native species are mainly perennials. The majority of these species show a tendency to form specimens of huge size (gigantism. The abundance of emitted CO2 and nitrogen compounds is the likely cause of this. Additionally, the plants growing there are not attacked by insects. The heating of the ground liquidates the natural seed bank. After cooling, these places are seeded by species providing seeds at that very moment (pioneer species. Heated places on the dumps allow plant growth even in the middle of winter. As the seasonal vegetation cycle is disturbed, plants may be found seeding, blooming and fruiting at the same time.

  15. Increased saccharification yields from aspen biomass upon treatment with enzymatically generated peracetic acid.

    Science.gov (United States)

    Duncan, Shona; Jing, Qing; Katona, Adrian; Kazlauskas, Romas J; Schilling, Jonathan; Tschirner, Ulrike; Aldajani, Waleed Wafa

    2010-03-01

    The recalcitrance of lignocellulosic biomass to enzymatic release of sugars (saccharification) currently limits its use as feedstock for biofuels. Enzymatic hydrolysis of untreated aspen wood releases only 21.8% of the available sugars due primarily to the lignin barrier. Nature uses oxidative enzymes to selectively degrade lignin in lignocellulosic biomass, but thus far, natural enzymes have been too slow for industrial use. In this study, oxidative pretreatment with commercial peracetic acid (470 mM) removed 40% of the lignin (from 19.9 to 12.0 wt.% lignin) from aspen and enhanced the sugar yields in subsequent enzymatic hydrolysis to about 90%. Increasing the amount of lignin removed correlated with increasing yields of sugar release. Unfortunately, peracetic acid is expensive, and concentrated forms can be hazardous. To reduce costs and hazards associated with using commercial peracetic acid, we used a hydrolase to catalyze the perhydrolysis of ethyl acetate generating 60-70 mM peracetic acid in situ as a pretreatment to remove lignin from aspen wood. A single pretreatment was insufficient, but multiple cycles (up to eight) removed up to 61.7% of the lignin enabling release of >90% of the sugars during saccharification. This value corresponds to a predicted 581 g of fermentable sugars from 1 kg of aspen wood. Improvements in the enzyme stability are needed before the enzymatically generated peracetic acid is a commercially viable alternative.

  16. Uncoupled thermoelasticity solutions applied on beam dumps

    Science.gov (United States)

    Ouzia, A.; Antonakakis, T.

    2016-06-01

    In particle accelerators the process of beam absorption is vital. At CERN particle beams are accelerated at energies of the order of TeV. In the event of a system failure or following collisions, the beam needs to be safely absorbed by dedicated protecting blocks. The thermal shock caused by the rapid energy deposition within the absorbing block causes thermal stresses that may rise above critical levels. The present paper provides a convenient expression of such stresses under hypotheses described hereafter. The temperature field caused by the beam energy deposition is assumed to be Gaussian. Such a field models a non-diffusive heat deposition. These effects are described as thermoelastic as long as the stresses remain below the proportional limit and can be analytically modeled by the coupled equations of thermoelasticity. The analytical solution to the uncoupled thermoelastic problem in an infinite domain is presented herein and matched with a finite unit radius sphere. The assumption of zero diffusion as well as the validity of the match with a finite geometry is quantified such that the obtained solutions can be rigorously applied to real problems. Furthermore, truncated series solutions, which are not novel, are used for comparison purposes. All quantities are nondimensional and the problem reduces to a dependence of five dimensionless parameters. The equations of elasticity are presented in the potential formulation where the shear potential is assumed to be nil due to the source being a gradient and the absence of boundaries. Nevertheless equivalent three-dimensional stresses are computed using the compressive potential and optimized using standard analytical optimization methods. An alternative algorithm for finding the critical points of the three-dimensional stress function is presented. Finally, a case study concerning the proton synchrotron booster dump is presented where the aforementioned analytical solutions are used and the preceding assumptions

  17. Natural vegetation recovery on waste dump in opencast coalmine area

    Institute of Scientific and Technical Information of China (English)

    CHENG Jian-long; LU Zhao-hua

    2005-01-01

    The changes of vegetation compositions, plant species diversity, species important value and succession of plant community were studied on waste dumps in Haizhou opencast coalmine which is located in the west of Liaoning Province, China (41°41(-42°56( N, 121°1(-122°56(E). Four kinds of terraces with different ages (5, 10, 20 and 40 years) were selected for investigation of plants. Total of 63 species of natural colonized plants were recorded on the waste dump and they belong to 23 families. The main families were Compositae (15 species), Fabaceae (11 species) and Leguminosae (8 species), which accounted for 54.0% of total species and play an important role in natural vegetation recovery in waste dump area. The dominant species on 5-, 10-, 20-, 40-year-old terraces were Tribulus terrestris + Echinochloa hispidula + Salsola collina, Echinochloa hispidula + Artemisia sieversiana + Artemisia scoparia, Echinochloa hispidula + Clinelymus dahuricus + Artemisia scoparia + Artemisia sieversiana + Melilotus officinalis, Clinelymus dahuricus+Phragmites communis + Echinochloa hispidula+ Setaria viridis, respectively. According to the important value of species calculated. It is determined that Tribulus terrestris can act as pioneer species on waste dump and Clinelymus dahuricus, Phragmites communis and Echinochloah hispidula are important dominant species in vegetation restoration in Haizhou opencast coalmine. The study results can provide scientific basis for selecting and disposing appropriately plant species and rehabilitating vegetation on waste dumps of coalmine.

  18. Neutral beam dump with cathodic arc titanium gettering.

    Science.gov (United States)

    Smirnov, A; Krivenko, A S; Murakhtin, S V; Savkin, V Ya; Korepanov, S A; Putvinski, S

    2011-03-01

    An incomplete neutral beam capture can degrade the plasma performance in neutral beam driven plasma machines. The beam dumps mitigating the shine-through beam recycling must entrap and retain large particle loads while maintaining the beam-exposed surfaces clean of the residual impurities. The cathodic arc gettering, which provides high evaporation rate coupled with a fast time response, is a powerful and versatile technique for depositing clean getter films in vacuum. A compact neutral beam dump utilizing the titanium arc gettering was developed for a field-reversed configuration plasma sustained by 1 MW, 20-40 keV neutral hydrogen beams. The titanium evaporator features a new improved design. The beam dump is capable of handling large pulsed gas loads, has a high sorption capacity, and is robust and reliable. With the beam particle flux density of 5 × 10(17) H∕(cm(2) s) sustained for 3-10 ms, the beam recycling coefficient, defined as twice the ratio of the hydrogen molecular flux leaving the beam dump to the incident flux of high-energy neutral atoms, is ∼0.7. The use of the beam dump allows us to significantly reduce the recycling of the shine-through neutral beam as well as to improve the vacuum conditions in the machine.

  19. A Large Scintillating Screen for the LHC Dump Line

    CERN Document Server

    Lefèvre, T; Bravin, E; Burger, S; Goddard, B; Hutchins, S; Renaglia, T

    2008-01-01

    The 7 TeV proton beam from the LHC ring is ejected through a long transfer line to beam dump blocks, approximately 100m downstream of the ejection septa, a series of dilution kicker magnets provide a sweeping deflection spreading the extracted beam over a 40 cm diameter area on the face of the beam dump cores. During normal operation, the quality of each dump event must be recorded and verified. The so-called â€ワPost-Mortem” dataset will include information from the beam dumping system (logic signals, kicker pulses…) as well as from the beam diagnostics along the extraction lines. For this purpose, profile monitors in front of the dump blocks must be permanently available during machine operation. With more than 1014 protons stored in LHC, the energy deposited in the screen becomes an issue and thermalresistant materials have to be considered. In this paper, the design of this quite unusual device is presented. The different technical options considered for the choice of the screen material are ...

  20. Simultaneous Hydrogen Generation and Waste Acid Neutralization in a Reverse Electrodialysis System

    KAUST Repository

    Hatzell, Marta C.

    2014-09-02

    Waste acid streams produced at industrial sites are often co-located with large sources of waste heat (e.g., industrial exhaust gases, cooling water, and heated equipment). Reverse electrodialysis (RED) systems can be used to generate electrical power and hydrogen gas using waste heat-derived solutions, but high electrode overpotentials limit system performance. We show here that an ammonium bicarbonate (AmB) RED system can achieve simultaneous waste acid neutralization and in situ hydrogen production, while capturing energy from excess waste heat. The rate of acid neutralization was dependent on stack flow rate and increased 50× (from 0.06 ± 0.04 to 3.0 ± 0.32 pH units min -1 m-2 membrane), as the flow rate increased 6× (from 100 to 600 mL min-1). Acid neutralization primarily took place due to ammonium electromigration (37 ± 4%) and proton diffusion (60 ± 5%). The use of a synthetic waste acid stream as a catholyte (pH ≈ 2) also increased hydrogen production rates by 65% (from 5.3 ± 0.5 to 8.7 ± 0.1 m3 H2 m-3 catholyte day -1) compared to an AmB electrolyte (pH ≈ 8.5). These findings highlight the potential use of dissimilar electrolytes (e.g., basic anolyte and acidic catholyte) for enhanced power and hydrogen production in RED stacks. © 2014 American Chemical Society.

  1. Amino Acid Insertion Frequencies Arising from Photoproducts Generated Using Aliphatic Diazirines

    Science.gov (United States)

    Ziemianowicz, Daniel S.; Bomgarden, Ryan; Etienne, Chris; Schriemer, David C.

    2017-10-01

    Mapping proteins with chemical reagents and mass spectrometry can generate a measure of accessible surface area, which in turn can be used to support the modeling and refinement of protein structures. Photolytically generated carbenes are a promising class of reagent for this purpose. Substituent effects appear to influence surface mapping properties, allowing for a useful measure of design control. However, to use carbene labeling data in a quantitative manner for modeling activities, we require a better understanding of their inherent amino acid reactivity, so that incorporation data can be normalized. The current study presents an analysis of the amino acid insertion frequency of aliphatic carbenes generated by the photolysis of three different diazirines: 3,3'-azibutyl-1-ammonium, 3,3'-azibutan-1-ol, and 4,4'-azipentan-1-oate. Leveraging an improved photolysis system for single-shot labeling of sub-microliter frozen samples, we used EThCD to localize insertion products in a large population of labeled peptides. Counting statistics were drawn from data-dependent LC-MS2 experiments and used to estimate the frequencies of insertion as a function of amino acid. We observed labeling of all 20 amino acids over a remarkably narrow range of insertion frequencies. However, the nature of the substituent could influence relative insertion frequencies, within a general preference for larger polar amino acids. We confirm a large (6-fold) increase in labeling yield when carbenes were photogenerated in the solid phase (77 K) relative to the liquid phase (293 K), and we suggest that carbene labeling should always be conducted in the frozen state to avoid information loss in surface mapping experiments. [Figure not available: see fulltext.

  2. In situ volatile fatty acids influence biogas generation from kitchen wastes by anaerobic digestion.

    Science.gov (United States)

    Xu, Zhiyang; Zhao, Mingxing; Miao, Hengfeng; Huang, Zhenxing; Gao, Shumei; Ruan, Wenquan

    2014-07-01

    Anaerobic digestion is considered to be an efficient way of disposing kitchen wastes, which can not only reduce waste amounts, but also produce biogas. However, the excessive accumulation of volatile fatty acids (VFA) caused by high organic loads will inhibit anaerobic digestion intensively. Effects of the VFA composition on biogas generation and microbial community are still required for the investigation under various organic loads of kitchen wastes. Our results showed that the maximum specific methane production was 328.3 ml g TS(-1), and acetic acid was the main inhibitor in methanogenesis. With the increase of organic load, aceticlastic methanogenesis was more sensitive to acetic acid than hydrogenotrophic methanogenesis. Meanwhile, methanogenic microbial community changed significantly, and few species grew well under excessive organic loads. This study provides an attempt to reveal the mechanism of VFA inhibition in anaerobic digestion of kitchen wastes.

  3. Acinetobacter indicus sp. nov., isolated from a hexachlorocyclohexane dump site.

    Science.gov (United States)

    Malhotra, Jaya; Anand, Shailly; Jindal, Swati; Rajagopal, Raman; Lal, Rup

    2012-12-01

    The taxonomic position of a Gram-negative, non-motile, oxidase negative and catalase positive strain, A648(T), isolated from a hexachlorocyclohexane (HCH) dump site located in Lucknow, India, was ascertained by using a polyphasic approach. A comparative analysis of a partial sequence of the rpoB gene and the 16S rRNA gene sequence revealed that strain A648(T) belonged to the genus Acinetobacter. DNA-DNA relatedness values between strain A648(T) and other closely related members (16S rRNA gene sequence similarity greater than 97%), namely Acinetobacter radioresistens DSM 6976(T), A. venetianus ATCC 31012(T), A. baumannii LMG 1041(T), A. parvus LMG 21765(T) A. junii LMG 998(T) and A. soli JCM 15062(T), were found to be less than 8%. The major cellular fatty acids of strain A648(T) were 18:1ω9c (19.6%), summed feature 3 (15.9%), 16:0 (10.6%) and 12:0 (6.4%). The DNA G+C content was 40.4 mol%. The polar lipid profile of strain A648(T) indicated the presence of diphosphatidylglycerol, phosphatidylethanolamine, followed by phosphatidylglycerol and phosphatidylcholine. The predominant polyamine of strain A648(T) was 1,3-diaminopropane and moderate amounts of putrescine, spermidine and spermine were also detected. The respiratory quinone consisted of ubiquinone with nine isoprene units (Q-9). On the basis of DNA-DNA hybridization, phenotypic characteristics and chemotaxonomic and phylogenetic comparisons with other members of the genus Acinetobacter, strain A648(T) is found to be a novel species of the genus Acinetobacter, for which the name Acinetobacter indicus sp. nov. is proposed. The type strain is A648(T) ( = DSM 25388(T) = CCM 7832(T)).

  4. Amino acids generated from hydrated Titan tholins: Comparison with Miller-Urey electric discharge products

    Science.gov (United States)

    Cleaves, H. James; Neish, Catherine; Callahan, Michael P.; Parker, Eric; Fernández, Facundo M.; Dworkin, Jason P.

    2014-07-01

    Various analogues of Titan haze particles (termed ‘tholins’) have been made in the laboratory. In certain geologic environments on Titan, these haze particles may come into contact with aqueous ammonia (NH3) solutions, hydrolyzing them into molecules of astrobiological interest. A Titan tholin analogue hydrolyzed in aqueous NH3 at room temperature for 2.5 years was analyzed for amino acids using highly sensitive ultra-high performance liquid chromatography coupled with fluorescence detection and time-of-flight mass spectrometry (UHPLC-FD/ToF-MS) analysis after derivatization with a fluorescent tag. We compare here the amino acids produced from this reaction sequence with those generated from room temperature Miller-Urey (MU) type electric discharge reactions. We find that most of the amino acids detected in low temperature MU CH4/N2/H2O electric discharge reactions are generated in Titan simulation reactions, as well as in previous simulations of Triton chemistry. This argues that many processes provide very similar mixtures of amino acids, and possibly other types of organic compounds, in disparate environments, regardless of the order of hydration. Although it is unknown how life began, it is likely that given reducing conditions, similar materials were available throughout the early Solar System and throughout the universe to facilitate chemical evolution.

  5. Amino Acids Generated from Hydrated Titan Tholins: Comparison with Miller-Urey Electric Discharge Products

    Science.gov (United States)

    Cleaves, H. James, II; Neish, Catherine; Callahan, Michael P.; Parker, Eric; Fernandez, Facundo M.; Dworkin, Jason P.

    2014-01-01

    Various analogues of Titan haze particles (termed tholins) have been made in the laboratory. In certain geologic environments on Titan, these haze particles may come into contact with aqueous ammonia (NH3) solutions, hydrolyzing them into molecules of astrobiological interest. A Titan tholin analogue hydrolyzed in aqueous NH3 at room temperature for 2.5 years was analyzed for amino acids using highly sensitive ultra-high performance liquid chromatography coupled with fluorescence detection and time-of-flight mass spectrometry (UHPLC-FDToF-MS) analysis after derivatization with a fluorescent tag. We compare here the amino acids produced from this reaction sequence with those generated from room temperature Miller-Urey (MU) type electric discharge reactions. We find that most of the amino acids detected in low temperature MU CH4N2H2O electric discharge reactions are generated in Titan simulation reactions, as well as in previous simulations of Triton chemistry. This argues that many processes provide very similar mixtures of amino acids, and possibly other types of organic compounds, in disparate environments, regardless of the order of hydration. Although it is unknown how life began, it is likely that given reducing conditions, similar materials were available throughout the early Solar System and throughout the universe to facilitate chemical evolution.

  6. Natural weathering in dry disposed ash dump: Insight from chemical, mineralogical and geochemical analysis of fresh and unsaturated drilled cores.

    Science.gov (United States)

    Akinyemi, S A; Akinlua, A; Gitari, W M; Khuse, N; Eze, P; Akinyeye, R O; Petrik, L F

    2012-07-15

    Some existing alternative applications of coal fly ash such as cement manufacturing; road construction; landfill; and concrete and waste stabilisation use fresh ash directly collected from coal-fired power generating stations. Thus, if the rate of usage continues, the demand for fresh ash for various applications will exceed supply and use of weathered dry disposed ash will become necessary alternative. As a result it's imperative to understand the chemistry and pH behaviour of some metals inherent in dry disposed fly ash. The bulk chemical composition as determined by XRF analysis showed that SiO2, Al2O3 and Fe2O3 were the major oxides in fresh ash and unsaturated weathered ashes. The unsaturated weathered ashes are relatively depleted in CaO, Fe2O3, TiO2, SiO2, Na2O and P2O5 due to dissolution and hydrolysis caused by chemical interaction with ingressing CO2 from the atmosphere and infiltrating rain water. Observed accumulations of Fe2O3, TiO2, CaO, K2O, Na2O and SO3 and Zn, Zr, Sr, Pb, Ni, Cr and Co in the lower layers indicate progressive downward movement through the ash dump though at a slow rate. The bulk mineralogy of unsaturated weathered dry disposed ash, as determined by XRD analysis, revealed quartz and mullite as the major crystalline phases; while anorthite, hematite, enstatite, lime, calcite, and mica were present as minor mineral phases. Pore water chemistry revealed a low concentration of readily soluble metals in unsaturated weathered ashes in comparison with fresh ash, which shows high leachability. This suggests that over time the precipitation of transient minor secondary mineral phases; such as calcite and mica might retard residual metal release from unsaturated weathered ash. Chloride and sulphate species of the water soluble extracts of weathered ash are at equilibrium with Na+ and K+; these demonstrate progressive leaching over time and become supersaturated at the base of unsaturated weathered ash. This suggests that the ash dump does not

  7. Notes on dumping gold beam in the AGS

    Energy Technology Data Exchange (ETDEWEB)

    Gardner, C.J.; Ahrens, L.; Thieberger, P.

    2010-08-01

    Localized losses of gold beam in the AGS during RHIC Run 8 produced vacuum leaks which required the replacement of several vacuum chambers. A review of what happened and why was given by Leif Ahrens at the Run 8 Retreat. The following notes trace the subsequent development of clean dumping of gold beam on the beam dump in the J10 straight. The novel idea of stripping Au77+ ions in order to put them directly into the upstream face of the dump was introduced by Leif Ahrens and developed by all three of us. George Mahler made the actual stripping device and Dave Gassner developed its control. Leif Ahrens successfully commissioned the device with gold beam during Run 10. The reader may find it helpful to first view the figures herein and then refer to the text for details.

  8. Low energy and high energy dumps for ELI-NP accelerator facility: rational and Monte-Carlo calculations results

    Science.gov (United States)

    Esposito, A.; Frasciello, O.; Pelliccioni, M.

    2017-09-01

    ELI-NP will be a new international research infrastructure facility for laser-based Nuclear Physics to be built in Magurele, south west of Bucharest, Romania. For the machine to operate as an intense γ rays' source based on Compton back-scattering, electron beams are employed, undergoing a two stage acceleration to 320 MeV and 740 MeV (and, with an eventual energy upgrade, also to 840 MeV) beam energies. In order to assess the radiation safety issues, concerning the effectiveness of the dumps in absorbing the primary electron beams, the generated prompt radiation field and the residual dose rates coming from the activation of constituent materials, as well as the shielding of the adjacent environments against both prompt and residual radiation fields, an extensive design study by means of Monte Carlo simulations with FLUKA code was performed, for both low energy 320 MeV and high energy 720 MeV (840 MeV) beam dumps. For the low energy dump we discuss also the rational of the choice to place it in the building basement, instead of installing it in one of the shielding wall at the machine level, as it was originally conceived. Ambient dose equivalent rate constraints, according to the Rumenian law in force in radiation protection matter were 0.1 /iSv/h everywhere outside the shielding walls and 1.4 μiSv/h outside the high energy dump area. The dumps' placements and layouts are shown to be fully compliant with the dose constraints and environmental impact.

  9. Generation and dietary modulation of anti-inflammatory electrophilic omega-3 fatty acid derivatives.

    Directory of Open Access Journals (Sweden)

    Chiara Cipollina

    Full Text Available Dietary ω-3 polyunsaturated fatty acids (PUFAs decrease cardiovascular risk via suppression of inflammation. The generation of electrophilic α,β-unsaturated ketone derivatives of the ω-3 PUFAs docosahexaenoic acid (DHA and docosapentaenoic acid (DPA in activated human macrophages is catalyzed by cyclooxygenase-2 (Cox-2. These derivatives are potent pleiotropic anti-inflammatory signaling mediators that act via mechanisms including the activation of Nrf2-dependent phase 2 gene expression and suppression of pro-inflammatory NF-κB-driven gene expression. Herein, the endogenous generation of ω-3 PUFAs electrophilic ketone derivatives and their hydroxy precursors was evaluated in human neutrophils. In addition, their dietary modulation was assessed through a randomized clinical trial.Endogenous generation of electrophilic omega-3 PUFAs and their hydroxy precursors was evaluated by mass spectrometry in neutrophils isolated from healthy subjects, both at baseline and upon stimulation with calcium ionophore. For the clinical trial, participants were healthy adults 30-55 years of age with a reported EPA+DHA consumption of ≤300 mg/day randomly assigned to parallel groups receiving daily oil capsule supplements for a period of 4 months containing either 1.4 g of EPA+DHA (active condition, n = 24 or identical appearing soybean oil (control condition, n = 21. Participants and laboratory technicians remained blinded to treatment assignments.5-lypoxygenase-dependent endogenous generation of 7-oxo-DHA, 7-oxo-DPA and 5-oxo-EPA and their hydroxy precursors is reported in human neutrophils stimulated with calcium ionophore and phorbol 12-myristate 13-acetate (PMA. Dietary EPA+DHA supplementation significantly increased the formation of 7-oxo-DHA and 5-oxo-EPA, with no significant modulation of arachidonic acid (AA metabolite levels.The endogenous detection of these electrophilic ω-3 fatty acid ketone derivatives supports the precept that the

  10. Københavns Kommunes indsats mod social dumping - målopfyldelsesevaluering

    DEFF Research Database (Denmark)

    Baadsgaard, Kelvin; Jørgensen, Henning

    2016-01-01

    Evaluering af, om de politiske intentioner med indsats mod social dumping i Københavns Kommune er blevet indfriet......Evaluering af, om de politiske intentioner med indsats mod social dumping i Københavns Kommune er blevet indfriet...

  11. Calculation notes that support accident scenario and consequence of the evaporator dump

    Energy Technology Data Exchange (ETDEWEB)

    Crowe, R.D., Westinghouse Hanford

    1996-09-09

    The purpose of this calculation note is to provide the basis for evaporator dump consequence for the Tank Farm Safety Analysis Report (FSAR). Evaporator Dump scenario is developed and details and description of the analysis methods are provided.

  12. ECONOMIC EVALUATION OF GOLD-ORE DUMP REPROCESSING EFFICIENCY

    Directory of Open Access Journals (Sweden)

    N. Y. Samsonov

    2010-06-01

    Full Text Available An economic projection is presented in the paper on the heap leaching technology for extracting a residual gold from the gold-ore dumps accumulated at the exploited or closed gold mines. A brief analysis is performed on the legal status of use this source of raw materials, availability and efficiency of the heap leaching method are reviewed, and the potential users of this method are assessed. An investment plan is created for involving anthropogenic dumps of gold-raw materials at one of the ore deposits in Siberia (heap complex of the North-Western flank of the Sovetskoye minefield, Krasnoyarsk region, North-Yenisey area.

  13. Neutronics Assessments for a RIA Fragmentation Line Beam Dump Concept

    CERN Document Server

    Boles, Jason; Reyes, Susana; Stein, Werner

    2005-01-01

    Heavy ion and radiation transport calculations are in progress for conceptual beam dump designs for the fragmentation line of the proposed Rare Isotope Accelerator (RIA). Using the computer code PHITS, a preliminary design of a motor-driven rotating wheel beam dump and adjacent downstream multipole has been modeled. Selected results of these calculations are given, including neutron and proton flux in the wheel, absorbed dose and displacements per atom in the hub materials, and heating from prompt radiation and from decay heat in the multipole.

  14. Environmental application of aerial reconnaissance to search for open dumps

    Science.gov (United States)

    Getz, Thomas J.; Randolph, J. C.; Echelberger, Wayne F.

    1983-11-01

    Three approaches to using aerial photography are evaluated for searching for open dumps in the state of Indiana. Photography with hand-held cameras from a small airplane proved more effective and flexible than either photo-interpretation of existing air photos or subcontracting to a federal agency for new aerial photography. The rationale for our choice of aerial reconnaissance, other uses of low-level aerial surveillance, the utility of small-format camera aerial photography for environmental analysis, and methods used for locating open dumps are discussed.

  15. CycloPs: generating virtual libraries of cyclized and constrained peptides including nonnatural amino acids.

    Science.gov (United States)

    Duffy, Fergal J; Verniere, Mélanie; Devocelle, Marc; Bernard, Elise; Shields, Denis C; Chubb, Anthony J

    2011-04-25

    We introduce CycloPs, software for the generation of virtual libraries of constrained peptides including natural and nonnatural commercially available amino acids. The software is written in the cross-platform Python programming language, and features include generating virtual libraries in one-dimensional SMILES and three-dimensional SDF formats, suitable for virtual screening. The stand-alone software is capable of filtering the virtual libraries using empirical measurements, including peptide synthesizability by standard peptide synthesis techniques, stability, and the druglike properties of the peptide. The software and accompanying Web interface is designed to enable the rapid generation of large, structurally diverse, synthesizable virtual libraries of constrained peptides quickly and conveniently, for use in virtual screening experiments. The stand-alone software, and the Web interface for evaluating these empirical properties of a single peptide, are available at http://bioware.ucd.ie .

  16. Pharmacological Correction of the Negative Effect of Acetylsalicylic Acid on the Energy-Generating System

    Directory of Open Access Journals (Sweden)

    Vladimir V. Udut, ScD

    2012-03-01

    Full Text Available The present paper demonstrates the effect of ASA and its combination with SUC on the energy-producing system of rat heart mitochondria as well as an assessment of SUC preventive application effect on ASA pharmacokinetic parameters. Experiments conducted on outbred male albino rats (200-250 g on a model of a xenobiotic load induced by seven days of intragastric injections of acetylsalicylic acid at a dose of 250 mg/kg have shown inhibition of the oxygen consumption rates in the heart mitochondria as well as a limitation of the succinate-dependent substrate oxidation pathways and a decrease in the mitochondria ATP/ADP coefficient. Succinic acid (50 mg/kg for 7 days was injected as a preventive medication to correct the mitochondrial bioenergetics revealed. A comparative research of the pharmacokinetics of acetylsalicylic acid and acetylsalicylic acid against the background of succinic acid performed on the model of rabbits has shown total similarity in the parameters analyzed. This fact demonstrates the possibility of prevention of mitochondrial dysfunction using the intermediate Krebs cycle. SUC as preventive medication promotes the elimination of ASA-induced negative metabolic shifts in the rat heart mitochondria by normalizing the succinate- and NAD-dependent respiration, oxidative phosphorylation, and therefore, it finds good use in the correction of ASA-induced negative side-effects of an energy-generating system

  17. A combined supplementation of vitamin B12 and omega-3 fatty acids across two generations improves cardiometabolic variables in rats.

    Science.gov (United States)

    Khaire, Amrita; Rathod, Richa; Randhir, Karuna; Kale, Anvita; Joshi, Sadhana

    2016-09-14

    Our earlier studies indicate that micronutrients (vitamin B12, folic acid) and omega-3 fatty acids especially docosahexaenoic acid (DHA) are interlinked in one carbon cycle. The present study examines the effects of a sustained vitamin B12 deficiency/supplementation in the presence of omega-3 fatty acids across two generations on the pregnancy outcome and cardiometabolic profile [blood pressure, plasma lipid profile (cholesterol and triglycerides), plasma/liver fatty acid profile and hepatic lipid metabolism] in the second generation adult Wistar rat offspring. Two generations of animals were fed the following diets: control; vitamin B12 deficient; vitamin B12 supplemented; vitamin B12 deficient diet supplemented with omega-3 fatty acids; vitamin B12 and omega-3 fatty acid supplemented diets. Male offspring were sacrificed at 3 months of age. Vitamin B12 deficiency lowered the weight gain (p B12 supplementation showed weight gain, blood pressure and the fatty acid profile similar to the control. However, it increased (p B12 deficient group lowered the weight gain although the levels of cardiometabolic variables were comparable to the control. Omega-3 fatty acid supplementation in the presence of vitamin B12 improved the pregnancy outcome and all cardio-metabolic variables. Our study highlights the adverse effects of sustained vitamin B12 deficiency across two generations on the pregnancy outcome, fatty acid profile and blood pressure while a combined supplementation of vitamin B12 and omega-3 fatty acids is beneficial.

  18. Devices and approaches for generating specific high-affinity nucleic acid aptamers

    Science.gov (United States)

    Szeto, Kylan; Craighead, Harold G.

    2014-09-01

    High-affinity and highly specific antibody proteins have played a critical role in biological imaging, medical diagnostics, and therapeutics. Recently, a new class of molecules called aptamers has emerged as an alternative to antibodies. Aptamers are short nucleic acid molecules that can be generated and synthesized in vitro to bind to virtually any target in a wide range of environments. They are, in principal, less expensive and more reproducible than antibodies, and their versatility creates possibilities for new technologies. Aptamers are generated using libraries of nucleic acid molecules with random sequences that are subjected to affinity selections for binding to specific target molecules. This is commonly done through a process called Systematic Evolution of Ligands by EXponential enrichment, in which target-bound nucleic acids are isolated from the pool, amplified to high copy numbers, and then reselected against the desired target. This iterative process is continued until the highest affinity nucleic acid sequences dominate the enriched pool. Traditional selections require a dozen or more laborious cycles to isolate strongly binding aptamers, which can take months to complete and consume large quantities of reagents. However, new devices and insights from engineering and the physical sciences have contributed to a reduction in the time and effort needed to generate aptamers. As the demand for these new molecules increases, more efficient and sensitive selection technologies will be needed. These new technologies will need to use smaller samples, exploit a wider range of chemistries and techniques for manipulating binding, and integrate and automate the selection steps. Here, we review new methods and technologies that are being developed towards this goal, and we discuss their roles in accelerating the availability of novel aptamers.

  19. Dumping syndrome after esophageal, gastric or bariatric surgery : pathophysiology, diagnosis, and management

    NARCIS (Netherlands)

    van Beek, A. P.; Emous, M.; Laville, Maurice; Tack, Johannes

    2017-01-01

    Background: Dumping syndrome, a common complication of esophageal, gastric or bariatric surgery, includes early and late dumping symptoms. Early dumping occurs within 1 h after eating, when rapid emptying of food into the small intestine triggers rapid fluid shifts into the intestinal lumen and rele

  20. 78 FR 36560 - Agency Information Collection Activities: Distribution of Continued Dumping and Subsidy Offset to...

    Science.gov (United States)

    2013-06-18

    ... Continued Dumping and Subsidy Offset to Affected Domestic Producers AGENCY: U.S. Customs and Border... of Continued Dumping and Subsidy Offset to Affected Domestic Producers (CDSOA). This request for... concerning the following information collection: Title: Distribution of Continued Dumping and Subsidy...

  1. 77 FR 61819 - WTO Dispute Settlement Proceeding Regarding United States-Countervailing and Anti-Dumping...

    Science.gov (United States)

    2012-10-11

    ...-Dumping Measures on Certain Products From China AGENCY: Office of the United States Trade Representative...-99''), and the countervailing and anti-dumping duty determinations and actions by the Department of....'' China also challenges the concurrent application of anti-dumping and countervailing duties under...

  2. 75 FR 16493 - Agency Information Collection Activities: Distribution of Continued Dumping and Subsidy Offset to...

    Science.gov (United States)

    2010-04-01

    ... Continued Dumping and Subsidy Offset to Affected Domestic Producers (CDSOA) AGENCY: U.S. Customs and Border... Dumping and Subsidy Offset to Affected Domestic Procedures. This request for comment is being made... Continued Dumping and Subsidy Offset to Affected Domestic Producers (CDSOA). OMB Number: 1651-0086....

  3. 78 FR 55280 - Agency Information Collection Activities: Distribution of Continued Dumping and Subsidy Offset to...

    Science.gov (United States)

    2013-09-10

    ... Continued Dumping and Subsidy Offset to Affected Domestic Producers AGENCY: U.S. Customs and Border...: Distribution of Continued Dumping and Subsidy Offset to Affected Domestic Producers (ADPs). This is a proposed... forms of information. Title: Distribution of Continued Dumping and Subsidy Offset to Affected...

  4. 75 FR 81533 - Antidumping Proceedings: Calculation of the Weighted Average Dumping Margin and Assessment Rate...

    Science.gov (United States)

    2010-12-28

    ... Weighted Average Dumping Margin and Assessment Rate in Certain Antidumping Duty Proceedings AGENCY: Import... comments regarding the calculation of the weighted average dumping margin and antidumping duty assessment...-specific export prices and average normal values and does not offset any dumping that is found with...

  5. 78 FR 38672 - Ocean Dumping; Sabine-Neches Waterway (SNWW) Ocean Dredged Material Disposal Site Designation

    Science.gov (United States)

    2013-06-27

    ... AGENCY 40 CFR Part 228 Ocean Dumping; Sabine-Neches Waterway (SNWW) Ocean Dredged Material Disposal Site... Entities B. Background C. Disposal Volume Limit D. Site Management and Monitoring Plan E. Ocean Dumping.... Ocean Dumping Site Designation Criteria In proposing to designate these Sites, the EPA assessed...

  6. 76 FR 5518 - Antidumping Proceedings: Calculation of the Weighted Average Dumping Margin and Assessment Rate...

    Science.gov (United States)

    2011-02-01

    ... Weighted Average Dumping Margin and Assessment Rate in Certain Antidumping Duty Proceedings AGENCY: Import... regarding the calculation of the weighted average dumping margin and antidumping duty assessment rate in... regarding the calculation of the weighted average dumping margin and antidumping duty assessment rate...

  7. 75 FR 33708 - Ocean Dumping; Correction of Typographical Error in 2006 Federal Register Final Rule for...

    Science.gov (United States)

    2010-06-15

    ... AGENCY 40 CFR Part 228 Ocean Dumping; Correction of Typographical Error in 2006 Federal Register Final... typographical error in the Final Rule for the Ocean Dumping; De-designation of Ocean Dredged Material Disposal... amended by revising paragraphs (n)(3) and (n)(4) to read as follows: Sec. 228.15 Dumping sites...

  8. 75 FR 36106 - Agency Information Collection Activities: Distribution of Continued Dumping and Subsidy Offset to...

    Science.gov (United States)

    2010-06-24

    ... Continued Dumping and Subsidy Offset to Affected Domestic Producers (CDSOA) AGENCY: U.S. Customs and Border...: Distribution of Continued Dumping and Subsidy Offset to Affected Domestic Procedures. This is a proposed.... Title: Distribution of Continued Dumping and Subsidy Offset to Affected Domestic Producers (CDSOA)....

  9. 77 FR 73732 - WTO Dispute Settlement Proceeding Regarding United States ; Countervailing and Anti-Dumping...

    Science.gov (United States)

    2012-12-11

    ... Regarding United States ; Countervailing and Anti-Dumping Measures on Certain Products From China AGENCY... countervailing and anti-dumping duty determinations and actions by the Department of Commerce, the U.S... application of anti-dumping and countervailing duties under the nonmarket economy methodology with respect...

  10. 76 FR 52045 - WTO Dispute Settlement Proceeding Regarding United States-Anti-Dumping Measures on Diamond...

    Science.gov (United States)

    2011-08-19

    ... TRADE REPRESENTATIVE WTO Dispute Settlement Proceeding Regarding United States--Anti- Dumping Measures... (``WTO Agreement'') concerning anti-dumping measures regarding diamond sawblades and parts thereof from... request dated February 28, 2001 regarding anti-dumping measures on certain frozen warmwater shrimp...

  11. Dumping syndrome after esophageal, gastric or bariatric surgery : pathophysiology, diagnosis, and management

    NARCIS (Netherlands)

    van Beek, A P; Emous, M; Laville, M; Tack, J

    2017-01-01

    BACKGROUND: Dumping syndrome, a common complication of esophageal, gastric or bariatric surgery, includes early and late dumping symptoms. Early dumping occurs within 1 h after eating, when rapid emptying of food into the small intestine triggers rapid fluid shifts into the intestinal lumen and rele

  12. 77 FR 19745 - WTO Dispute Settlement Proceeding Regarding United States; Anti-Dumping Measures on Certain...

    Science.gov (United States)

    2012-04-02

    ... TRADE REPRESENTATIVE WTO Dispute Settlement Proceeding Regarding United States; Anti- Dumping Measures... order would be likely to lead to the continuation or recurrence of dumping, Certain Frozen Warmwater... methodology for determining margins of dumping in administrative reviews; (8) the practice of...

  13. 7 CFR 58.228 - Dump hoppers, screens, mixers and conveyors.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Dump hoppers, screens, mixers and conveyors. 58.228... Service 1 Equipment and Utensils § 58.228 Dump hoppers, screens, mixers and conveyors. The product contact surfaces of dump hoppers, screens, mixers and conveyors which are used in the process of transferring...

  14. 40 CFR 256.64 - Requirements for public participation in the open dump inventory.

    Science.gov (United States)

    2010-07-01

    ... in the open dump inventory. 256.64 Section 256.64 Protection of Environment ENVIRONMENTAL PROTECTION... MANAGEMENT PLANS Public Participation § 256.64 Requirements for public participation in the open dump... classification of a facility as an open dump to the Federal Government. The State shall accomplish this...

  15. 75 FR 67968 - Arkwright Dump Site, Spartanburg, Spartanburg County, SC; Notice of Settlement

    Science.gov (United States)

    2010-11-04

    ...] Arkwright Dump Site, Spartanburg, Spartanburg County, SC; Notice of Settlement AGENCY: Environmental... Dump Site located in Spartanburg, Spartanburg County, South Carolina for publication. DATES: The Agency..., identified by Docket ID No. EPA-RO4- SFUND-2010-0892 or Site name Arkwright Dump Site by one of the...

  16. Linoleic acid-induced mitochondrial Ca(2+) efflux causes peroxynitrite generation and protein nitrotyrosylation.

    Science.gov (United States)

    Zhang, Hong-Mei; Dang, Howard; Yeh, Chih-Ko; Zhang, Bin-Xian

    2009-06-26

    It is well known that excessive non-esterified fatty acids in diabetes contribute to the pathogenesis of renal complications although the mechanism remains elusive. Enhanced oxidative stress has been hypothesized as a unified factor contributing to diabetic complications and increased protein nitrotyrosylation has been reported in the kidneys of diabetic patients. In the current manuscript we described that linoleic acid (LA) caused mitochondrial Ca(2+) efflux and peroxynitrite production, along with increased nitrotyrosine levels of cellular proteins in primary human mesangial cells. The peroxynitrite production by LA was found to depend on mitochondrial Ca(2+) efflux. Downregulation of hsp90beta1, which has been previously shown to be essential for polyunsaturated fatty acid-induced mitochondrial Ca(2+) efflux, significantly diminished LA-responsive mitochondrial Ca(2+) efflux and the coupled peroxynitrite generation, implicating a critical role of hsp90beta1 in the LA responses. Our results further demonstrated that mitochondrial complexes I and III were directly involved in the LA-induced peroxynitrite generation. Using the well established type 2 diabetic animal model db/db mice, we observed a dramatically enhanced LA responsive mitochondrial Ca(2+) efflux and protein nitrotyrosylation in the kidney. Our study thus demonstrates a cause-effect relationship between LA and peroxynitrite or protein nitrotyrosylation and provides a novel mechanism for lipid-induced nephropathy in diabetes.

  17. Linoleic Acid-Induced Mitochondrial Ca2+ Efflux Causes Peroxynitrite Generation and Protein Nitrotyrosylation

    Science.gov (United States)

    Zhang, Hong-Mei; Dang, Howard; Yeh, Chih-Ko; Zhang, Bin-Xian

    2009-01-01

    It is well known that excessive non-esterified fatty acids in diabetes contribute to the pathogenesis of renal complications although the mechanism remains elusive. Enhanced oxidative stress has been hypothesized as a unified factor contributing to diabetic complications and increased protein nitrotyrosylation has been reported in the kidneys of diabetic patients. In the current manuscript we described that linoleic acid (LA) caused mitochondrial Ca2+ efflux and peroxynitrite production, along with increased nitrotyrosine levels of cellular proteins in primary human mesangial cells. The peroxynitrite production by LA was found to depend on mitochondrial Ca2+ efflux. Downregulation of hsp90β1, which has been previously shown to be essential for polyunsaturated fatty acid-induced mitochondrial Ca2+ efflux, significantly diminished LA-responsive mitochondrial Ca2+ efflux and the coupled peroxynitrite generation, implicating a critical role of hsp90β1 in the LA responses. Our results further demonstrated that mitochondrial complexes I and III were directly involved in the LA-induced peroxynitrite generation. Using the well established type 2 diabetic animal model db/db mice, we observed a dramatically enhanced LA responsive mitochondrial Ca2+ efflux and protein nitrotyrosylation in the kidney. Our study thus demonstrates a cause-effect relationship between LA and peroxynitrite or protein nitrotyrosylation and provides a novel mechanism for lipid-induced nephropathy in diabetes. PMID:19557129

  18. Linoleic acid-induced mitochondrial Ca(2+ efflux causes peroxynitrite generation and protein nitrotyrosylation.

    Directory of Open Access Journals (Sweden)

    Hong-Mei Zhang

    Full Text Available It is well known that excessive non-esterified fatty acids in diabetes contribute to the pathogenesis of renal complications although the mechanism remains elusive. Enhanced oxidative stress has been hypothesized as a unified factor contributing to diabetic complications and increased protein nitrotyrosylation has been reported in the kidneys of diabetic patients. In the current manuscript we described that linoleic acid (LA caused mitochondrial Ca(2+ efflux and peroxynitrite production, along with increased nitrotyrosine levels of cellular proteins in primary human mesangial cells. The peroxynitrite production by LA was found to depend on mitochondrial Ca(2+ efflux. Downregulation of hsp90beta1, which has been previously shown to be essential for polyunsaturated fatty acid-induced mitochondrial Ca(2+ efflux, significantly diminished LA-responsive mitochondrial Ca(2+ efflux and the coupled peroxynitrite generation, implicating a critical role of hsp90beta1 in the LA responses. Our results further demonstrated that mitochondrial complexes I and III were directly involved in the LA-induced peroxynitrite generation. Using the well established type 2 diabetic animal model db/db mice, we observed a dramatically enhanced LA responsive mitochondrial Ca(2+ efflux and protein nitrotyrosylation in the kidney. Our study thus demonstrates a cause-effect relationship between LA and peroxynitrite or protein nitrotyrosylation and provides a novel mechanism for lipid-induced nephropathy in diabetes.

  19. Simulation of acid mine drainage generation around Küre VMS Deposits, Northern Turkey

    Science.gov (United States)

    Demirel, Cansu; Kurt, Mehmet Ali; Çelik Balci, Nurgül

    2015-04-01

    This study investigated comparative leaching characteristics of acidophilic bacterial strains under shifting environmental conditions at proposed two stages as formation stage or post acidic mine drainage (AMD) generation. At the first stage, initial reactions associated with AMD generation was simulated in shaking flasks containing massive pyritic chalcopyrite ore by using a pure strain Acidithiobacillus ferrooxidans and a mixed culture of Acidithiobacillus sp. mostly dominated by A. ferrooxidans and A. thiooxidans at 26oC. At the second stage, long term bioleaching experiments were carried out with the same strains at 26oC and 40oC to investigate the leaching characteristics of pyritic chalcopyrite ore under elevated heavy metal and temperature conditions. During the experiments, physicochemical characteristics (e.i. Eh, pH, EC) metal (Fe, Co, Cu, Zn) and sulfate concentration of the experimental solution were monitored during 180 days. Significant acid generation and sulfate release were determined during bioleaching of the ore by mixed acidophilic cultures containing both iron and sulfur oxidizers. In the early stage of the experiments, heavy metal release from the ore was caused by generation of acid due to accelerated bacterial oxidation of the ore. Generally high concentrations of Co and Cu were released into the solution from the experiments conducted by pure cultures of Acidithiobacillus ferrooxidans whereas high Zn and Fe was released into the solution from the mixed culture experiments. In the later stage of AMD generation and post AMD, chemical oxidation is accelerated causing excessive amounts of contamination, even exceeding the amounts resulted from bacterial oxidation by mixed cultures. Acidithibacillus ferrooxidans was found to be more effective in leaching Cu, Fe and Co at higher temperatures in contrary to mixed acidophiles that are more prone to operate at optimal moderate conditions. Moreover, decreasing Fe values are noted in bioleaching

  20. Neuraminidase-Dependent Degradation of Polysialic Acid Is Required for the Lamination of Newly Generated Neurons.

    Directory of Open Access Journals (Sweden)

    Mari Sajo

    Full Text Available Hippocampal granule cells (GCs are generated throughout the lifetime and are properly incorporated into the innermost region of the granule cell layer (GCL. Hypotheses for the well-regulated lamination of newly generated GCs suggest that polysialic acid (PSA is present on the GC surface to modulate GC-to-GC interactions, regulating the process of GC migration; however, direct evidence of this involvement is lacking. We show that PSA facilitates the migration of newly generated GCs and that the activity of N-acetyl-α-neuraminidase 1 (NEU1, sialidase 1 cleaves PSA from immature GCs, terminating their migration in the innermost GCL. Developing a migration assay of immature GCs in vitro, we found that the pharmacological depletion of PSA prevents the migration of GCs, whereas the inhibition of PSA degradation with a neuraminidase inhibitor accelerates this migration. We found that NEU1 is highly expressed in immature GCs. The knockdown of NEU1 in newly generated GCs in vivo increased PSA presence on these cells, and attenuated the proper termination of GC migration in the innermost GCL. In conclusion, this study identifies a novel mechanism that underlies the proper lamination of newly generated GCs through the modulation of PSA presence by neuronal NEU1.

  1. Neuraminidase-Dependent Degradation of Polysialic Acid Is Required for the Lamination of Newly Generated Neurons.

    Science.gov (United States)

    Sajo, Mari; Sugiyama, Hiroki; Yamamoto, Hideaki; Tanii, Takashi; Matsuki, Norio; Ikegaya, Yuji; Koyama, Ryuta

    2016-01-01

    Hippocampal granule cells (GCs) are generated throughout the lifetime and are properly incorporated into the innermost region of the granule cell layer (GCL). Hypotheses for the well-regulated lamination of newly generated GCs suggest that polysialic acid (PSA) is present on the GC surface to modulate GC-to-GC interactions, regulating the process of GC migration; however, direct evidence of this involvement is lacking. We show that PSA facilitates the migration of newly generated GCs and that the activity of N-acetyl-α-neuraminidase 1 (NEU1, sialidase 1) cleaves PSA from immature GCs, terminating their migration in the innermost GCL. Developing a migration assay of immature GCs in vitro, we found that the pharmacological depletion of PSA prevents the migration of GCs, whereas the inhibition of PSA degradation with a neuraminidase inhibitor accelerates this migration. We found that NEU1 is highly expressed in immature GCs. The knockdown of NEU1 in newly generated GCs in vivo increased PSA presence on these cells, and attenuated the proper termination of GC migration in the innermost GCL. In conclusion, this study identifies a novel mechanism that underlies the proper lamination of newly generated GCs through the modulation of PSA presence by neuronal NEU1.

  2. Hydrogen peroxide generation in a model paediatric parenteral amino acid solution.

    Science.gov (United States)

    Brawley, V; Bhatia, J; Karp, W B

    1993-12-01

    1. Parenteral amino acid solutions undergo photooxidation, which may be an important factor in total parenteral nutrition-associated hepatic dysfunction. Light-exposed parenteral solutions containing amino acids, in addition to vitamins and trace minerals, generate free radicals, which, in turn, may contribute to this type of injury. This study examined the characteristics of H2O2 production in a parenteral amino acid solution modelled on a commercially available paediatric parenteral amino acid solution. 2. The solution was exposed to light in the presence of riboflavin-5'-monophosphate (riboflavin), and peroxide formation in the presence and absence of catalase (H2O2 formation) was assayed using potassium iodide/molybdate. 3. Peak H2O2 production occurred at a light intensity of 8 microW cm-2 nm-1 in the 425-475 nm waveband and was linear to 2 h of light exposure. H2O2 production reached 500 mumol/l at 24 h. 4. H2O2 was directly related to a riboflavin concentration of up to 20 mumol/l and was maximal at 30 mumol/l. 5. H2O2 production was greatest in the amino acid/riboflavin solution at a pH of between 5 and 6. 6. Under the conditions of light exposure intensity, light exposure time, riboflavin concentration and pH found during the administration of parenteral nutrition in neonatal intensive care units, net H2O2 production occurs in solutions modelled on a paediatric parenteral amino acid preparation.

  3. Uric Acid Induces Hepatic Steatosis by Generation of Mitochondrial Oxidative Stress

    Science.gov (United States)

    Lanaspa, Miguel A.; Sanchez-Lozada, Laura G.; Choi, Yea-Jin; Cicerchi, Christina; Kanbay, Mehmet; Roncal-Jimenez, Carlos A.; Ishimoto, Takuji; Li, Nanxing; Marek, George; Duranay, Murat; Schreiner, George; Rodriguez-Iturbe, Bernardo; Nakagawa, Takahiko; Kang, Duk-Hee; Sautin, Yuri Y.; Johnson, Richard J.

    2012-01-01

    Metabolic syndrome represents a collection of abnormalities that includes fatty liver, and it currently affects one-third of the United States population and has become a major health concern worldwide. Fructose intake, primarily from added sugars in soft drinks, can induce fatty liver in animals and is epidemiologically associated with nonalcoholic fatty liver disease in humans. Fructose is considered lipogenic due to its ability to generate triglycerides as a direct consequence of the metabolism of the fructose molecule. Here, we show that fructose also stimulates triglyceride synthesis via a purine-degrading pathway that is triggered from the rapid phosphorylation of fructose by fructokinase. Generated AMP enters into the purine degradation pathway through the activation of AMP deaminase resulting in uric acid production and the generation of mitochondrial oxidants. Mitochondrial oxidative stress results in the inhibition of aconitase in the Krebs cycle, resulting in the accumulation of citrate and the stimulation of ATP citrate lyase and fatty-acid synthase leading to de novo lipogeneis. These studies provide new insights into the pathogenesis of hepatic fat accumulation under normal and diseased states. PMID:23035112

  4. DDQ-promoted dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones by a radical ion mechanism.

    Science.gov (United States)

    Ding, Ye; Huang, Zhangjian; Yin, Jian; Lai, Yisheng; Zhang, Shibo; Zhang, Zhiguo; Fang, Lei; Peng, Sixun; Zhang, Yihua

    2011-09-07

    A novel and facile DDQ-mediated dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones is described. The formation of lactones proceeds by a radical ion mechanism, which has been established by DPPH˙-mediated chemical identification, ESR spectroscopy and an enol intermediate trapping.

  5. Novel Halomonas sp. B15 isolated from Larnaca Salt Lake in Cyprus that generates vanillin and vanillic acid from ferulic acid.

    Science.gov (United States)

    Vyrides, Ioannis; Agathangelou, Maria; Dimitriou, Rodothea; Souroullas, Konstantinos; Salamex, Anastasia; Ioannou, Aristostodimos; Koutinas, Michalis

    2015-08-01

    Vanillin is a high value added product with many applications in the food, fragrance and pharmaceutical industries. A natural and low-cost method to produce vanillin is by microbial bioconversions through ferulic acid. Until now, limited microorganisms have been found capable of bioconverting ferulic acid to vanillin at high yield. This study aimed to screen halotolerant strains of bacteria from Larnaca Salt Lake which generate vanillin and vanillic acid from ferulic acid. From a total of 50 halotolenant/halophilic strains 8 grew in 1 g/L ferulic acid and only 1 Halomonas sp. B15 and 3 Halomonas elognata strains were capable of bioconverting ferulic acid to vanillic acid at 100 g NaCl/L. The highest vanillic acid (365 mg/L) at these conditions generated by Halomonas sp. B15 which corresponds to ferulic acid bioconversion yield of 36.5%. Using the resting cell technique with an initial ferulic acid concentration of 0.5 g/L at low salinity, the highest production of vanillin (245 mg/L) took place after 48 h, corresponding to a bioconversion yield of 49%. This is the first reported Halomonas sp. with high yield of vanillin production from ferulic acid at low salinity.

  6. The Beam Energy Tracking System of the LHC Beam Dumping System

    CERN Document Server

    Barlow, R A; Carlier, E; Gräwer, G; Voumard, N; Gjelsvik, R

    2005-01-01

    The LHC Beam Dumping System (LBDS) of the Large Hadron Collider (LHC), presently under construction at CERN, will be installed around the straight section 6. It comprises per ring 15 horizontally deflecting extraction kickers, followed by 1 quadrupole, 15 vertically deflecting steel septum magnets, 10 dilution kickers and, in a separate cavern several hundred meters away, an external absorber assembly. A beam dump request can occur at any moment during the operation of the collider, from injection at 450 GeV up to top energy at 7 TeV. The Beam Energy Tracking System (BETS) monitors the deflection strength of each active element of the LBDS with respect to the beam energy in order to guarantee the correct extraction trajectory over the complete operational range and under all operational conditions. Its main functions are the acquisition of the beam energy, the generation of the kick strength reference signals for the extraction and dilution kickers, the continuous checking that the kicker high voltage generat...

  7. ALPtraum: ALP production in proton beam dump experiments

    CERN Document Server

    Döbrich, Babette; Kahlhoefer, Felix; Ringwald, Andreas; Schmidt-Hoberg, Kai

    2016-01-01

    With their high beam energy and intensity, existing and near-future proton beam dumps provide an excellent opportunity to search for new very weakly coupled particles in the MeV to GeV mass range. One particularly interesting example is a so-called axion-like particle (ALP), i.e. a pseudoscalar coupled to two photons. The challenge in proton beam dumps is to reliably calculate the production of the new particles from the interactions of two composite objects, the proton and the target atoms. In this work we argue that Primakoff production of ALPs proceeds in a momentum range where production rates and angular distributions can be determined to sufficient precision using simple electromagnetic form factors. Reanalysing past proton beam dump experiments for this production channel, we derive novel constraints on the parameter space for ALPs. We show that the NA62 experiment at CERN could probe unexplored parameter space by running in 'dump mode' for a few days and discuss opportunities for future experiments su...

  8. Environmental assessments of sea dumped chemical warfare agents

    DEFF Research Database (Denmark)

    Sanderson, Hans; Fauser, Patrik

    This is a report on the information gathered during work related to sea dumped chemical warfare agents. It mainly reviews the work conducted in relation to the installation of the two Nord Stream gas pipeline from 2008-2012. The focus was on the weight-of-evidence risk assessment of disturbed CWA...

  9. 29 BABY DUMPING AND EVOLVING BABY FACTORIES IN NIGERIA

    African Journals Online (AJOL)

    Few scholarly works existing on this social problem center on poverty .... their parents. Similarly, Sazali .... Table 5: Number of cases related to baby dumping in Malaysia ..... children from imminent risk of harm, as the nation's present commitment of resources, laws, and .... Stigma: Notes on Management of Spoiled Identity.

  10. Bilge dump detection from SAR imagery using local binary patterns

    CSIR Research Space (South Africa)

    Mdakane, LW

    2015-07-01

    Full Text Available 2015: Remote Sensing: Understanding the Earth for a Safer World, Milan, Italy, 26-31 July 2015 Bilge dump detection from SAR imagery using local binary patterns yz L.W. Mdakane,yz W. Kleynhans,yz C.P. Schwegmann yDepartment of Electrical...

  11. ALPtraum. ALP production in proton beam dump experiments

    Energy Technology Data Exchange (ETDEWEB)

    Doebrich, Babette [European Organization for Nuclear Research (CERN), Geneva (Switzerland); Jaeckel, Joerg [Heidelberg Univ. (Germany). Inst. fuer Theoretische Physik; Kahlhoefer, Felix; Ringwald, Andreas; Schmidt-Hoberg, Kai [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)

    2015-12-15

    With their high beam energy and intensity, existing and near-future proton beam dumps provide an excellent opportunity to search for new very weakly coupled particles in the MeV to GeV mass range. One particularly interesting example is a so-called axion-like particle (ALP), i.e. a pseudoscalar coupled to two photons. The challenge in proton beam dumps is to reliably calculate the production of the new particles from the interactions of two composite objects, the proton and the target atoms. In this work we argue that Primakoff production of ALPs proceeds in a momentum range where production rates and angular distributions can be determined to sufficient precision using simple electromagnetic form factors. Reanalysing past proton beam dump experiments for this production channel, we derive novel constraints on the parameter space for ALPs. We show that the NA62 experiment at CERN could probe unexplored parameter space by running in 'dump mode' for a few days and discuss opportunities for future experiments such as SHiP.

  12. Results of evaluation of tailing dumps dust intensity

    Directory of Open Access Journals (Sweden)

    Masloboev V. A.

    2016-03-01

    Full Text Available A set of most acceptable and well-known methods of dust intensity evaluation has been defined and tested (dependence of Westphal D. L. et al. and DEAD scheme based on the analysis of exiting approaches (deserts, tailing dumps, etc.. The description of the chosen methods has been given. The determination of dynamic velocity u* and velocity at the height of +10 m above the dusting surface u10 which are necessary to evaluate the dust intensity has been demonstrated. The method is based on two-dimensional numerical model of atmosphere aerodynamics in the area of "tailing dumps of ANOF-2 ‒ the town of Apatity". The study provides calculations of horizontal velocity at the height of +10 m above the dusting surface at the wind speed varying from 5 to 23 m/sec. The work also suggests the results of graphical data processing related to tailing grain size distribution from the surface of the firmly established surface of the tailing dumps of ANOF-2. Comparative analysis has been given and the peculiarities of interval (based on grains sizes dust intensity of the tailing dumps of ANOF-2 have been shown using the dependence of Westphal D. L. et al. and DEAD scheme within the wind speed range. The received values of dust intensity at the lower range limit are close to the "maximum specific dust off" value which is used by project specialists for documentation development

  13. Calculation of New Beam Dump Shielding for CYCIAE-100

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    The 100 MeV high intensity cyclotron, CYCIAE-100, places a demanding requirement on the collection device to accept the proton beam. According to the original design, the beam dump would be settled in the cyclotron vault. It uses pure aluminum as the target material,

  14. insect vectors of pathogens in selected undisposed refuse dumps in ...

    African Journals Online (AJOL)

    Administrator

    2012-06-23

    Jun 23, 2012 ... insects and their role in disease transmission are highlighted. Proper disposal of ... Keywords: Insects, refuse dumps, diseases, Kaduna, Nigeria. INTRODUCTION ..... further noted that at present, only individual solutions are used at the household .... to endemic cholera in Douala, Cameroon. PubMed. gov ( ...

  15. Particulate Matter and Noise Impact Studies of Waste Rock Dump*

    African Journals Online (AJOL)

    Michael

    2016-06-01

    Jun 1, 2016 ... pressure level modelling indicates that the waste rock dump has a potential to ... Problems related to noise include stress related illnesses, high blood pressure, speech ... modelling consist of physical parameters that are ... The monitoring activity was ... efficiency of 40% (assumed) will reduce the noise.

  16. On a hypothetical generational relationship between HCN and constituents of the reductive citric acid cycle.

    Science.gov (United States)

    Eschenmoser, Albert

    2007-04-01

    Encouraged by observations made on the course of reactions the HCN-tetramer can undergo with acetaldehyde, I delineate a constitutional and potentially generational relationship between HCN and those constituents of the reductive citric acid cycle that are direct precursors of amino acids in contemporary metabolism. In this context, the robustness postulate of classical prebiotic chemistry is questioned, and, by an analysis of the (hypothetical) reaction-tree of a stepwise hydrolysis of the HCN-tetramer, it is shown how such a non-robust chemical reaction platform could harbor the potential for the emergence of autocatalytic cycles. It is concluded that the chemistry of HCN should be revisited by focussing on its non-robust parts in order to demonstrate its full potential as one of the possible roots of prebiotic self-organizing chemical processes.

  17. Incorporating Geochemical And Microbial Kinetics In Reactive Transport Models For Generation Of Acid Rock Drainage

    Science.gov (United States)

    Andre, B. J.; Rajaram, H.; Silverstein, J.

    2010-12-01

    Acid mine drainage, AMD, results from the oxidation of metal sulfide minerals (e.g. pyrite), producing ferrous iron and sulfuric acid. Acidophilic autotrophic bacteria such as Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans obtain energy by oxidizing ferrous iron back to ferric iron, using oxygen as the electron acceptor. Most existing models of AMD do not account for microbial kinetics or iron geochemistry rigorously. Instead they assume that oxygen limitation controls pyrite oxidation and thus focus on oxygen transport. These models have been successfully used for simulating conditions where oxygen availability is a limiting factor (e.g. source prevention by capping), but have not been shown to effectively model acid generation and effluent chemistry under a wider range of conditions. The key reactions, oxidation of pyrite and oxidation of ferrous iron, are both slow kinetic processes. Despite being extensively studied for the last thirty years, there is still not a consensus in the literature about the basic mechanisms, limiting factors or rate expressions for microbially enhanced oxidation of metal sulfides. An indirect leaching mechanism (chemical oxidation of pyrite by ferric iron to produce ferrous iron, with regeneration of ferric iron by microbial oxidation of ferrous iron) is used as the foundation of a conceptual model for microbially enhanced oxidation of pyrite. Using literature data, a rate expression for microbial consumption of ferrous iron is developed that accounts for oxygen, ferrous iron and pH limitation. Reaction rate expressions for oxidation of pyrite and chemical oxidation of ferrous iron are selected from the literature. A completely mixed stirred tank reactor (CSTR) model is implemented coupling the kinetic rate expressions, speciation calculations and flow. The model simulates generation of AMD and effluent chemistry that qualitatively agrees with column reactor and single rock experiments. A one dimensional reaction

  18. Assessing pollutions of soil and plant by municipal waste dump

    Science.gov (United States)

    Liu, Changli; Zhang, Yun; Zhang, Feng'e.; Zhang, Sheng; Yin, Miying; Ye, Hao; Hou, Hongbing; Dong, Hua; Zhang, Ming; Jiang, Jianmei; Pei, Lixin

    2007-04-01

    Research is few in the literature regarding the investigation and assessment of pollutions of soil and plant by municipal waste dumps. Based upon previous work in seven waste dumping sites (nonsanitary landfills) in Beijing, Shanghai and Shijiazhuang, this study expounds the investigation and assessment method and report major pollutants. Using relative background values, this study assesses soil pollution degree in the seven dumping sites. Preliminary conclusions are: (1) pollution degrees are moderate or heavy; (2) pollution distance by domestic waste that is dumped on a plane ground is 85 m; (3) the horizontal transport distance of pollutants might be up to 120 m if waste leachates are directly connected with water in saturated soils; (4) vertical transport depth is about 3 m in unsaturated silty clayey soils. Furthermore, using relative background values and hygiene standards of food and vegetable this study assesses the pollutions of different parts of reed, sorghum, watermelon and sweet-melon. It is found: (1) in comparison with the relative background values in a large distance to the waste dumping sites, domestic wastes have polluted the roots and stems of reed and sorghum, whereas fine coal ash has polluted the leaves, rattans and fruits of watermelon and sweet-melon; (2) domestic wastes and fine coal ash have heavily polluted the edible parts of sorghum, water melon and sweet-melon. As, Hg, Pb and F have far exceeded standard values, e.g., Hg has exceeded the standard value by up to 650 1,700 times and Cd by 120 275 times, and the comprehensive pollution index is up to 192.9 369.7; (3) the polluted sorghum, watermelon and sweet-melon are inedible.

  19. Peracetic acid treatment generates potent inactivated oral vaccines from a broad range of culturable bacterial species

    Directory of Open Access Journals (Sweden)

    Kathrin eMoor

    2016-02-01

    Full Text Available Our mucosal surfaces are the main sites of non-vector-borne pathogen entry, as well as the main interface with our commensal microbiota. We are still only beginning to understand how mucosal adaptive immunity interacts with commensal and pathogenic microbes to influence factors such as infectivity, phenotypic diversity and within-host evolution. This is in part due to difficulties in generating specific mucosal adaptive immune responses without disrupting the mucosal microbial ecosystem itself. Here we present a very simple tool to generate inactivated mucosal vaccines from a broad range of culturable bacteria. Oral gavage of 1010 peracetic acid-inactivated bacteria induces high-titer specific intestinal IgA in the absence of any measurable inflammation or species invasion. As a proof of principal, we demonstrate that this technique is sufficient to provide fully protective immunity in the murine model of invasive non-typhoidal Salmonellosis, even in the face of severe innate immune deficiency.

  20. Research of waste dump water mutagenicity of bacterial detection system SOS chromotest.

    Science.gov (United States)

    Vojtková, H; Janáková, I

    2011-01-01

    The paper deals with a possible use of the bacterial detection system of SOS chromotest to test mutagenicity of waste dump water checking the mutagenicity degree on real samples from Praksice waste dump, which is a controlled waste dump with mixed industrial, municipal and inert wastes. The waste dump surface water samples were taken from a no-name influent stream springing below the waste dump body between 2005 and 2009. After metabolic activation by microsomal fraction in vitro, medium to high mutagenicity was registered in all the samples. The SOS chromotest is assessed as an effective and economically acceptable method to check and determine the mutagenicity degree of contaminated water.

  1. Design of an internal waste dump within the boundaries of the open pit

    OpenAIRE

    Panov, Zoran; Minov, Kirco; Karanakova Stefanovska, Radmila; Stojanov, Slobodan; Doneva, Blagica

    2011-01-01

    With the deepening of the open pit, the transport distances for the sterile mass and the ore increased. This paper deals with the formation of an internal waste dump within the boundaries of the open pit. The development of such waste dump should be in function of the space for disposing the waste according to existing situation on the field and the space for dumping. The internal waste dump will be used for permanent dumping and waste storage. Modern methods will be used to asses...

  2. Design aspects related to the reliability of the control architecture of the LHC beam dump kicker systems

    CERN Document Server

    Carlier, E; Bobbio, P; Gräwer, G; Marchand, A; Uythoven, J; Verhagen, H

    2003-01-01

    The LHC beam dump extraction kicker system consists per ring of 15 magnets and their pulse generators. Their task is to extract the beams on request, over the whole operational beam energy range and synchronously with the beam abort gap. This operation must be fail-safe to avoid damage to accelerator equipment by undesired beam losses. The control system of the LHC beam dump kickers will be based on a modular architecture composed of different subsystems, each with a specific function like slow control, beam energy tracking, beam abort gap synchronisation, fast pulse signal monitoring and post-mortem data acquisition. Depending on the required functionality, the subsystems will be based either on passive fault-tolerant redundant hardware solutions or on active fail-safe hardware and software solutions. In addition, for the most critical subsystems like the beam energy tracking and the beam abort gap synchronisation, two redundant solutions based on different technologies will be implemented in order to preven...

  3. Enhancement of resistance against high energy laser pulse injection with chevron beam dump

    Energy Technology Data Exchange (ETDEWEB)

    Yatsuka, Eiichi; Hatae, Takaki [Japan Atomic Energy Agency, Mukoyama, Naka, Ibaraki 311-0193 (Japan); Bassan, Michele; Vayakis, George; Walsh, Michael [ITER Organization, St Paul Lez Durance Cedex, Provence 13067 (France); Itami, Kiyoshi [Japan Atomic Energy Agency, Mukoyama, Naka, Ibaraki 311-0193 (Japan)

    2015-11-15

    Highlights: • The laser irradiation tests onto flat-mirror-molybdenum sample were carried out. • The absorbed energy density is the correct figure of the laser-induced damage. • Experiments validated the design of a new beam dump called chevron beam dump. • The chevron beam dump would have much longer lifetime than conventional beam dumps. - Abstract: The laser beam dump of the Edge Thomson scattering (ETS) in ITER is being developed and a new type of beam dump called the chevron beam dump was proposed recently. The laser-induced damage on the surface is one of the most severe issues to be overcome. The key concept of the chevron beam dump is to reduce the laser energy absorption per unit area and to absorb the laser beam gradually. The laser irradiation tests onto flat-mirror-molybdenum sample were carried out. It was clarified that the absorbed (rather than incident) energy density of the laser pulses should be the correct figure of merit for the laser-induced damage. Therefore, the concept of the chevron beam dump design, that minimizes the absorbed laser energy density per unit area, was validated experimentally. The chevron beam dump enables us to extend its lifetime drastically relative to conventional beam dumps. Potential methods to improve the laser-induced damage threshold (LIDT) are also discussed in this paper.

  4. A GIS-based zoning of illegal dumping potential for efficient surveillance.

    Science.gov (United States)

    Tasaki, Tomohiro; Kawahata, Takatsune; Osako, Masahiro; Matsui, Yasuhiro; Takagishi, Susumu; Morita, Akihiro; Akishima, Shigeki

    2007-01-01

    To assist in the efficient surveillance against illegal dumping, this study examined and evaluated two methods to illustrate the illegal dumping potential of sites using GIS (Geographic Information System) data. One approach focused on the occurrence of illegal dumping sites; the other on the size of the illegal dumping. Both approaches to zoning were implemented for the Kanto region of Japan, utilizing seven or eight major geographical attributes most closely related to illegal dumping. The zoning results revealed the areas requiring patrols against illegal dumping. Evaluation of the zoning results using the ROC (Receiver Operating Characteristic) curve showed the number of illegal dumping sites detectable under certain surveillance conditions and that the size-based zoning was superior, but this superiority was insignificant for revealing sites with higher potential for large illegal dumping, for which it would be sufficient to use the occurrence-based zoning. The evaluation also showed the contribution of each geographical attribute. Finally, application of the ROC curve to the surveillance planning process was examined, which enables the total social cost of pollution by illegal dumping, rehabilitation of dumping sites, and illegal dumping surveillance to be minimized.

  5. Sea-dumped chemical weapons: environmental risk, occupational hazard.

    Science.gov (United States)

    Greenberg, M I; Sexton, K J; Vearrier, D

    2016-01-01

    Chemical weapons dumped into the ocean for disposal in the twentieth century pose a continuing environmental and human health risk. In this review we discuss locations, quantity, and types of sea-dumped chemical weapons, related environmental concerns, and human encounters with sea-dumped chemical weapons. We utilized the Ovid (http://ovidsp.tx.ovid.com) and PubMed (http://www.pubmed.org) search engines to perform MEDLINE searches for the terms 'sea-dumped chemical weapons', 'chemical warfare agents', and 'chemical munitions'. The searches returned 5863 articles. Irrelevant and non-English articles were excluded. A review of the references for these articles yielded additional relevant sources, with a total of 64 peer-reviewed articles cited in this paper. History and geography of chemical weapons dumping at sea: Hundreds of thousands of tons of chemical munitions were disposed off at sea following World War II. European, Russian, Japanese, and United States coasts are the areas most affected worldwide. Several areas in the Baltic and North Seas suffered concentrated large levels of dumping, and these appear to be the world's most studied chemical warfare agent marine dumping areas. Chemical warfare agents: Sulfur mustard, Lewisite, and the nerve agents appear to be the chemical warfare agents most frequently disposed off at sea. Multiple other type of agents including organoarsenicals, blood agents, choking agents, and lacrimators were dumped at sea, although in lesser volumes. Environmental concerns: Numerous geohydrologic variables contribute to the rate of release of chemical agents from their original casings, leading to difficult and inexact modeling of risk of release into seawater. Sulfur mustard and the organoarsenicals are the most environmentally persistent dumped chemical agents. Sulfur mustard in particular has a propensity to form a solid or semi-solid lump with a polymer coating of breakdown products, and can persist in this state on the ocean floor

  6. Excluded volume effects caused by high concentration addition of acid generators in chemically amplified resists used for extreme ultraviolet lithography

    Science.gov (United States)

    Kozawa, Takahiro; Watanabe, Kyoko; Matsuoka, Kyoko; Yamamoto, Hiroki; Komuro, Yoshitaka; Kawana, Daisuke; Yamazaki, Akiyoshi

    2017-08-01

    The resolution of lithography used for the high-volume production of semiconductor devices has been improved to meet the market demands for highly integrated circuits. With the reduction in feature size, the molecular size becomes non-negligible in the resist material design. In this study, the excluded volume effects caused by adding high-concentration acid generators were investigated for triphenylsulfonium nonaflate. The resist film density was measured by X-ray diffractometry. The dependences of absorption coefficient and protected unit concentration on acid generator weight ratio were calculated from the measured film density. Using these values, the effects on the decomposition yield of acid generators, the protected unit fluctuation, and the line edge roughness (LER) were evaluated by simulation on the basis of sensitization and reaction mechanisms of chemically amplified extreme ultraviolet resists. The positive effects of the increase in acid generator weight ratio on LER were predominant below the acid generator weight ratio of 0.3, while the negative effects became equivalent to the positive effects above the acid generator weight ratio of 0.3 owing to the excluded volume effects.

  7. Membrane growth can generate a transmembrane pH gradient in fatty acid vesicles.

    Science.gov (United States)

    Chen, Irene A; Szostak, Jack W

    2004-05-25

    Electrochemical proton gradients are the basis of energy transduction in modern cells, and may have played important roles in even the earliest cell-like structures. We have investigated the conditions under which pH gradients are maintained across the membranes of fatty acid vesicles, a model of early cell membranes. We show that pH gradients across such membranes decay rapidly in the presence of alkali-metal cations, but can be maintained in the absence of permeable cations. Under such conditions, when fatty acid vesicles grow through the incorporation of additional fatty acid, a transmembrane pH gradient is spontaneously generated. The formation of this pH gradient captures some of the energy released during membrane growth, but also opposes and limits further membrane area increase. The coupling of membrane growth to energy storage could have provided a growth advantage to early cells, once the membrane composition had evolved to allow the maintenance of stable pH gradients.

  8. Removal of Cu(Ⅱ) from acidic electroplating effluent by biochars generated from crop straws

    Institute of Scientific and Technical Information of China (English)

    Xuejiao Tong; Renkou Xu

    2013-01-01

    The removal efficiency of copper (Cu(Ⅱ)) from an actual acidic electroplating effluent by biochars generated from canola,rice,soybean and peanut straws was investigated.The biochars simultaneously removed Cu(Ⅱ) from the effluent,mainly through the mechanisms of adsorption and precipitation,and neutralized its acidity.The removal efficiency of Cu(Ⅱ) by the biochars followed the order:peanut straw char > soybean straw char > canola straw char > rice straw char >> a commercial activated carbonaceous material,which is consistent with the alkalinity of the biochars.The pH of the effluent was a key factor determining the removal efficiency of Cu(Ⅱ)by biochars.Raising the initial pH of the effluent enhanced the removal of Cu(Ⅱ) from it.The optimum pyrolysis temperature was 400℃ for producing biochar from crop straws for acidic wastewater treatment,and the optimum reaction time was 8 hr.

  9. Dump area restoration at Espírito Santo do Pinhal - SP

    Directory of Open Access Journals (Sweden)

    Gerson Araujo de Medeiros

    2005-06-01

    Full Text Available Espírito Santo do Pinhal, SP, generates about 50 tons of garbage per week, which used to be disposed of in a dump from 1960 up to 2000, when this practice was banned and a plan to recover the area was implemented. The purpose of this work is to assess the evolution of the recovery plan after four years of deactivation of the old dump. The methodology consisted of a photographic survey of the site and a comparison with earlier records, chemical soil and microbiological water analyses and evaluation of the vegetation. The seedlings planted showed vegetative development problems for lack of care; the microbiological analyses revealed water contamination by fecal coliforms (700 NMP 100 mL-1 and the chemical soil analyses indicated high contents of Copper (3.5 mg kg-1, Iron (28 mg kg-1, Manganese (6.2 mg kg-1, Zinc (9.4 mg kg-1 and organic matter (24 mg kg-1.

  10. Generation, Release, and Uptake of the NAD Precursor Nicotinic Acid Riboside by Human Cells.

    Science.gov (United States)

    Kulikova, Veronika; Shabalin, Konstantin; Nerinovski, Kirill; Dölle, Christian; Niere, Marc; Yakimov, Alexander; Redpath, Philip; Khodorkovskiy, Mikhail; Migaud, Marie E; Ziegler, Mathias; Nikiforov, Andrey

    2015-11-06

    NAD is essential for cellular metabolism and has a key role in various signaling pathways in human cells. To ensure proper control of vital reactions, NAD must be permanently resynthesized. Nicotinamide and nicotinic acid as well as nicotinamide riboside (NR) and nicotinic acid riboside (NAR) are the major precursors for NAD biosynthesis in humans. In this study, we explored whether the ribosides NR and NAR can be generated in human cells. We demonstrate that purified, recombinant human cytosolic 5'-nucleotidases (5'-NTs) CN-II and CN-III, but not CN-IA, can dephosphorylate the mononucleotides nicotinamide mononucleotide and nicotinic acid mononucleotide (NAMN) and thus catalyze NR and NAR formation in vitro. Similar to their counterpart from yeast, Sdt1, the human 5'-NTs require high (millimolar) concentrations of nicotinamide mononucleotide or NAMN for efficient catalysis. Overexpression of FLAG-tagged CN-II and CN-III in HEK293 and HepG2 cells resulted in the formation and release of NAR. However, NAR accumulation in the culture medium of these cells was only detectable under conditions that led to increased NAMN production from nicotinic acid. The amount of NAR released from cells engineered for increased NAMN production was sufficient to maintain viability of surrounding cells unable to use any other NAD precursor. Moreover, we found that untransfected HeLa cells produce and release sufficient amounts of NAR and NR under normal culture conditions. Collectively, our results indicate that cytosolic 5'-NTs participate in the conversion of NAD precursors and establish NR and NAR as integral constituents of human NAD metabolism. In addition, they point to the possibility that different cell types might facilitate each other's NAD supply by providing alternative precursors.

  11. Generation, Release, and Uptake of the NAD Precursor Nicotinic Acid Riboside by Human Cells*

    Science.gov (United States)

    Kulikova, Veronika; Shabalin, Konstantin; Nerinovski, Kirill; Dölle, Christian; Niere, Marc; Yakimov, Alexander; Redpath, Philip; Khodorkovskiy, Mikhail; Migaud, Marie E.; Ziegler, Mathias; Nikiforov, Andrey

    2015-01-01

    NAD is essential for cellular metabolism and has a key role in various signaling pathways in human cells. To ensure proper control of vital reactions, NAD must be permanently resynthesized. Nicotinamide and nicotinic acid as well as nicotinamide riboside (NR) and nicotinic acid riboside (NAR) are the major precursors for NAD biosynthesis in humans. In this study, we explored whether the ribosides NR and NAR can be generated in human cells. We demonstrate that purified, recombinant human cytosolic 5′-nucleotidases (5′-NTs) CN-II and CN-III, but not CN-IA, can dephosphorylate the mononucleotides nicotinamide mononucleotide and nicotinic acid mononucleotide (NAMN) and thus catalyze NR and NAR formation in vitro. Similar to their counterpart from yeast, Sdt1, the human 5′-NTs require high (millimolar) concentrations of nicotinamide mononucleotide or NAMN for efficient catalysis. Overexpression of FLAG-tagged CN-II and CN-III in HEK293 and HepG2 cells resulted in the formation and release of NAR. However, NAR accumulation in the culture medium of these cells was only detectable under conditions that led to increased NAMN production from nicotinic acid. The amount of NAR released from cells engineered for increased NAMN production was sufficient to maintain viability of surrounding cells unable to use any other NAD precursor. Moreover, we found that untransfected HeLa cells produce and release sufficient amounts of NAR and NR under normal culture conditions. Collectively, our results indicate that cytosolic 5′-NTs participate in the conversion of NAD precursors and establish NR and NAR as integral constituents of human NAD metabolism. In addition, they point to the possibility that different cell types might facilitate each other's NAD supply by providing alternative precursors. PMID:26385918

  12. Development and characterization of a coronary polylactic acid stent prototype generated by selective laser melting.

    Science.gov (United States)

    Flege, Christian; Vogt, Felix; Höges, Simon; Jauer, Lucas; Borinski, Mauricio; Schulte, Vera A; Hoffmann, Rainer; Poprawe, Reinhart; Meiners, Wilhelm; Jobmann, Monika; Wissenbach, Konrad; Blindt, Rüdiger

    2013-01-01

    In-stent restenosis is still an important issue and stent thrombosis is an unresolved risk after coronary intervention. Biodegradable stents would provide initial scaffolding of the stenosed segment and disappear subsequently. The additive manufacturing technology Selective Laser Melting (SLM) enables rapid, parallel, and raw material saving generation of complex 3- dimensional structures with extensive geometric freedom and is currently in use in orthopedic or dental applications. Here, SLM process parameters were adapted for poly-L-lactid acid (PLLA) and PLLA-co-poly-ε-caprolactone (PCL) powders to generate degradable coronary stent prototypes. Biocompatibility of both polymers was evidenced by assessment of cell morphology and of metabolic and adhesive activity at direct and indirect contact with human coronary artery smooth muscle cells, umbilical vein endothelial cells, and endothelial progenitor cells. γ-sterilization was demonstrated to guarantee safety of SLM-processed parts. From PLLA and PCL, stent prototypes were successfully generated and post-processing by spray- and dip-coating proved to thoroughly smoothen stent surfaces. In conclusion, for the first time, biodegradable polymers and the SLM technique were combined for the manufacturing of customized biodegradable coronary artery stent prototypes. SLM is advocated for the development of biodegradable coronary PLLA and PCL stents, potentially optimized for future bifurcation applications.

  13. Search for Dark Matter with LHC proton Beam Dump

    CERN Document Server

    Kumar, Ashok; Sharma, Archana

    2016-01-01

    Dark Matter (DM) comprising particles in the mass range of a few MeV to GeV is waiting to be explored, given the many theoretical models accommodating cosmological abundance. We hereby propose an experiment with the LHC proton beam of 7 TeV striking onto the beam dump target, emitting neutrinos and possibly, Dark Matter candidates. This experiment would also permit to observe signatures involving elastic and inelastic processes involving DM candidates, electrons and strongly interacting particles present in nuclei of the dump target. There will be residual neutrino background present in each of these signatures, hence the proposed experimental detector sub-systems would be such that they would involve as final states, elastically or inelasticity scattered, standard model particles. The bump or the excess in the tail of the kinematic distributions will eventually give us glimpse of presence of new particles which could possibly be Dark Matter candidates. Given the parameters of the LHC machine, the sensitivity...

  14. Ocean dumping of low-level radioactive wastes

    Science.gov (United States)

    Templeton, W. L.

    1982-10-01

    Scientific bases, developed internationally over the last 20 years, to control and restrict to acceptable levels the resultant radiation doses that potentially could occur from the dumping of low-level radioactive wastes in the deep oceans were presented. It is concluded that present evaluations of the disposal of radioactive wastes into the oceans, coastal and deep ocean, indicate that these are being conducted within the ICRP recommended dose limits. However, there are presently no international institutions or mechanisms to deal with the long-term radiation exposure at low-levels to large numbers of people on a regional basis if not a global level. Recommendations were made to deal with these aspects through the established mechanisms of NEA/OECD and the London Dumping Convention, in cooperation with ICRP, UNSCEAR and the IAEA.

  15. Reclamation of coalmine overburden dump through environmental friendly method

    Directory of Open Access Journals (Sweden)

    Anfal Arshi

    2017-02-01

    Full Text Available Coal mine spoils (-the previous overburden of coal seams, inevitable by-product in the mining process which are usually unfavorable for plant growth have different properties according to dumping years. The reclamation of overburden dumps (OBDs through plantation by using efficient microbes with suitable bio-inoculants is an environmental friendly microbial technique for significant improvement in fertility status and biological activities of the OBD soil. A systematic greenhouse pot experiment program followed by field trial was conducted to investigate the influence of arbuscular mycorrhizal (AM and NFB on the performance of plant growth which have resulted in the development of environmental friendly bio-inoculant package for soil reclamation of abandoned mine land by revegetation.

  16. Augmenting the Stability of OB Dump by Using Fly Ash: A Geo Technical Approach to Sustainably Manage OB Dump at Jharia Coal Field, India

    Directory of Open Access Journals (Sweden)

    Anup Kumar Gupta*

    2016-04-01

    Full Text Available This paper is mainly focused over the possible utilization of fly ash along with OB dump to enhance the stability of OB dump and thus provide a sustainable approach for better waste management of both these materials simultaneously. Instability of coal mine overburden (OB dumps is an important problem in most of the coal mines like Jharia coalfields in India. This is mainly occurring due to sliding nature of the rock material, lack of vegetation etc. Numbers of Environmental and health issues are associated with these unstable OB dumps. As it may easily flow with running water can contaminate the nearby water resource as well as carbonaceous content of the dump causes air pollution due to simultaneous combustion. On the other hand management of coal ash that is produced from thermal plants is also an important task. Dumping of fly ash in open may cause number of environmental problems. Various geotechnical and physical parameters such as particle size analysis, specific gravity, density, and friction angle/cohesion test have been performed to check the stability of OB dump and to analyze impacts of fly ash utilization to stabilize the OB dump.

  17. NCTO Endorses Mexican Anti-dumping Case With China

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    @@ The president of the National Council of Textile Organizations (NCTO) has written a letter to the Mexican Economic Secretary Hugo Diaz strongly endorsing his country's decision to seek a World Trade Organization (WTO) anti-dumping investigation of denim imports from China according to James A. Morrissey, a Washington Correspondent on June 8th. NCTO President Cass Johnson said the action is an important step toward preventing damage to both Mexican and U.S. denim manufacturers.

  18. Modeling of air pollution from the power plant ash dumps

    Science.gov (United States)

    Aleksic, Nenad M.; Balać, Nedeljko

    A simple model of air pollution from power plant ash dumps is presented, with emission rates calculated from the Bagnold formula and transport simulated by the ATDL type model. Moisture effects are accounted for by assumption that there is no pollution on rain days. Annual mean daily sedimentation rates, calculated for the area around the 'Nikola Tesla' power plants near Belgrade for 1987, show reasonably good agreement with observations.

  19. FATIGUE WELDING JOINT RESISTANCE OF MINING DUMP TRUCK BEARING CONSTRUCTIONS

    Directory of Open Access Journals (Sweden)

    A. A. Rakitsky

    2010-01-01

    Full Text Available The paper investigates a possibility to apply European norms on designing of welded constructions for frames of heavy-load mining dump trucks. Comparison of results concerning tests of welding joint specimen made of local steel with recommended standards of fatigue curves is executed in the paper. The paper reveals that while forecasting resource of automotive constructions with the accepted practical accuracy it is possible to use generalized fatigue resistance characteristics of standard welding joints. 

  20. Assessment of the mercury emissions from burning mining waste dumps

    Directory of Open Access Journals (Sweden)

    Barbara Białecka

    2016-04-01

    occur and to which the environment and local inhabitants can be exposed, it is important to define the size of the emission of mercury compounds from these objects. Despite the potential threats so far no measurements of mercury concentration which would a llow quantifying this phenomenon have been done. The analyses presented in this article fill this gap. Additionally, initial calculation of annual mercury emissions from burning coal mining waste dumps in Poland is presented.

  1. Effect of acid pretreatment on different parts of corn stalk for second generation ethanol production.

    Science.gov (United States)

    Li, Ping; Cai, Di; Luo, Zhangfeng; Qin, Peiyong; Chen, Changjing; Wang, Yong; Zhang, Changwei; Wang, Zheng; Tan, Tianwei

    2016-04-01

    In this study, the effects of different parts of corn stalk, including stem, leaf, flower, cob and husk on second generation ethanol production were evaluated. FTIR, XRD and SEM were performed to investigate the effect of dilute acid pretreatment. The bagasse obtained after pretreatment were further hydrolyzed by cellulase and used as the substrate for ethanol fermentation. As results, hemicelluloses fractions in different parts of corn stalk were dramatically removed and the solid fractions showed vivid compositions and crystallinities. Compared with other parts of corn stalk, the cob had higher sugar content and better enzymatic digestibility. The highest glucose yield of 94.2% and ethanol production of 24.0 g L(-1) were achieved when the cob was used as feedstock, while the glucose yield and the ethanol production were only 86.0% and 17.1 g L(-1) in the case of flower.

  2. Generation of Hydrogen from Photolysis of Organic Acids by Photosynthetic Bacteria

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Photodecomposition of ten kinds of organic acids by Rhodopseudomonas palustris for producing hydrogen has been investigated. By using acetate as hydrogen donor, dynamics of hydrogen production and cell growth has been determined; the influences of acetate concentration, temperature, light intensity and the effects of the interaction among metal ions (Fe3+, Ni2+), acetate and glutamate in aqueous solution on hydrogen production have been examined for optimizing the conditions of H2 generation. The results show that H2 production is partially correlated with cell growth; Ni2+ inhibits hydrogen production, but enhances cell growth; Fe3+ promotes hydrogen production evidently. The highest rate of H2 production is 22.1 mL L-1 h-1 under the conditions of 35 ~ 37℃, 6000 ~ 8000 lx, 30 mmolL-1 of acetate, 9 mmolL-1 of glutamate, and 50 (molL-1 of Fe3+.

  3. Deoxyribonucleic acid (DNA methylation and its impact in generation of Cancer

    Directory of Open Access Journals (Sweden)

    Rajeswari J

    2014-07-01

    Full Text Available The arrangement of genes in the chromosome is dependent on histone modifications, deoxyribonucleic acid (DNA binding proteins and methylation of cytosines within 51–cytosine-phosphate-Guanine–31 (CpG dinucleotides. DNA methylation can modify the gene activity without changing the gene sequence. Aberrant hypomethylation and hypermethylations, causal or heritable gene expressions play an important role in tumour initiation and progression. Global hypomethylation at some part of genome and hypermethylation at the promoter regions of the tumour suppressor genes could generate mutations in several types of cancers. Reversal or inhibition of DNA methylation mechanism provides a promising improvement in the treatment of cancer along with chemotherapy. A combined approach utilising epigenetic treatment along with standard chemotherapy appears to hold promise as a future therapy.

  4. Betulinic acid regulates generation of neuroinflammatory mediators responsible for tissue destruction in multiple sclerosis in vitro

    Institute of Scientific and Technical Information of China (English)

    Jana BLA(Z)EVSKI; Filip PETKOVI(C); Miljana MOM(C)ILOVI(C); Reinhard PASCHKE; Goran N KALUDEROVI(C); Marija MOSTARICA STOJKOVI(C); Djordje MILJKOVI(C)

    2013-01-01

    Aim:To investigate the influences of betulinic acid (BA),a triterpenoid isolated from birch bark,on neuroinflammatory mediators involved in the pathogenesis of multiple sclerosis and experimental autoimmune encephalomyelitis in vitro.Methods:Encephalitogenic T cells were prepared from draining lymph nodes and spinal cords of Dark Agouti rats 8 to 10 d after immunization with myelin basic protein (MBP) and complete Freund's adjuvant.Macrophages were isolated from the peritoneal cavity of adult untreated rats.Astrocytes were isolated from neonatal rat brains.The cells were cultured and then treated with different agents.IFN-y,IL-17,iNOS and CXCL12 mRNA levels in the cells were analyzed with RT-PCR.iNOS and CXCL12 protein levels were detected using immunoblot.NO and ROS generation was measured using Griess reaction and flow cytometry,respectively.Results:In encephalitogenic T cells stimulated with MBP (10 μg/mL),addition of BA inhibited IL-17 and IFN-γ production in a dosedependent manner.The estimated IC50 values for IL-17 and IFN y were 11.2 and 63.8 μmol/L,respectively.When the macrophages were stimulated with LPS (10 ng/mL),addition of BA (50 μmol/L) significantly increased ROS generation,and suppressed NO generation.The astrocytes were stimulated with ConASn containing numerous inflammatory mediators,which mimicked the inflammatory milieu within CNS; addition of BA (50 μmol/L) significantly increased ROS generation,and blocked ConASn-induced increases in iNOS and CXCL12 mRNA levels,but did not affect iNOS and CXCL12 protein levels.Importantly,in both the macrophages and astrocytes,addition of BA (50 μmol/L) inhibited lipid peroxidation.Conclusion:Besides inhibiting encephalitogenic T cell cytokines and reducing NO generation,BA induces tissue-damaging ROS generation within CNS.

  5. Design of a Compact Dump Resistor System for LCD Magnet

    CERN Document Server

    Gaddi, A

    2010-01-01

    In this technical note we suggest a possible solution for the choice of the detector magnet dump resistor. The push-pull scenario for Linear Collider Detectors imposes new solutions for magnet powering and protection lines, else than what developed for LHC detectors. The magnet dump resistor is the protecting equipment that has the function of extracting a significant amount of magnetic stored energy, from the coil winding to a dump. The LCD magnet has to move with the experiment from the garage to the beam position, so it has to be compact and reliable at the same time. We make here a proposal for a passive water-cooled dumper, we calculate the minimum amount of water required, the resistor hot-spot temperature, the overall mechanical design. The electrical part is not covered by this note, as it can be assumed that the solutions adopted by LHC detector magnets, in terms of quench instrumentation, energy extraction and maximum voltage, are not significantly affected by the push-pull scenario.

  6. Irradiation Effects on RIA Fragmentation Cu Beam Dump

    CERN Document Server

    Reyes, Susana; Boles, Jason; Stein, Werner; Wirth, Brian

    2005-01-01

    Within the scope of conceptual R&D activities in support of the Rare-Isotope Accelerator (RIA) facility, high priority is given to the development of high-power fragmentation beam dumps. A pre-study was made of a static water-cooled Cu beam dump that can meet requirements for a 400 MeV/u uranium beam. The issue of beam sputtering was addressed and found to be not a significant issue. Preliminary radiation transport simulations show significant damage (dpa) in the vicinity of the Bragg peak of uranium ions. Experimental data show that defects in Cu following neutron or high-energy particle irradiation tend to saturate at doses between 1 and 5 dpa, and this saturation in defect density also results in saturation of mechanical property degradation. However, effects of swift heavy ion irradiation and the production of gaseous and solid transmutant elements still need to be addressed. Initial calculations indicate that He concentrations on the order of 100 appm are produced in the beam dump after several weeks...

  7. Phytoremediation of coal mine spoil dump through integrated biotechnological approach

    Energy Technology Data Exchange (ETDEWEB)

    Juwarkar, A.A.; Jambhulkar, H.P. [National Environmental Engineering Research Institute, Nagpur (India)

    2008-07-15

    Field experiment was conducted on mine spoil dump on an area of 10 ha, to restore the fertility and productivity of the coal mine spoil dump using integrated biotechnological approach. The approach involves use of effluent treatment plant sludge (ETP sludge), as an organic amendment, biofertilizers and mycorrihzal fungi along with suitable plant species. The results of the study indicated that amendment with effluent treatment plant sludge (ETP sludge), at 50 ton/ha improved the physico-chemical properties of coal mine spoil. Due to biofertilizer inoculation different microbial groups such as Rhizobium, Azotobacter and VAM spores, which were practically absent in mine spoil improved greatly. Inoculation of biofertilizer and application of ETP sludge helped in reducing the toxicity of heavy metals such as chromium, zinc, copper, iron, manganese lead, nickel and cadmium, which were significantly reduced to 41%, 43%, 37%, 37%, 34%, 39%, 37% and 40%, respectively, due to the increased organic matter content in the ETP sludge and its alkaline pH (8.10-8.28), at which the metals gets immobilized and translocation of metals is arrested. Thus, amendment and biofertilizer application provided better supportive material for anchorage and growth of the plant on coal mine spoil dump.

  8. American Material Culture: Investigating a World War II Trash Dump

    Energy Technology Data Exchange (ETDEWEB)

    Julie Braun

    2005-10-01

    The Idaho National Laboratory: An Historical Trash Trove Historians and archaeologists love trash, the older the better. Sometimes these researchers find their passion in unexpected places. In this presentation, the treasures found in a large historic dump that lies relatively untouched in the middle of the Idaho National Laboratory (INL) will be described. The U.S. military used the central portion of the INL as one of only six naval proving grounds during World War II. They dumped trash in dry irrigation canals during and after their wartime activities and shortly before the federal government designated this arid and desolate place as the nation’s nuclear reactor testing station in 1949. When read critically and combined with memories and photographs, the 60-year old trash provides a glimpse into 1940s’ culture and the everyday lives of ordinary people who lived and worked during this time on Idaho’s desert. Thanks to priceless stories, hours of research, and the ability to read the language of historic artifacts, the dump was turned from just another trash heap into a treasure trove of 1940s memorabilia. Such studies of American material culture serve to fire our imaginations, enrich our understanding of past practices, and humanize history. Historical archaeology provides opportunities to integrate inanimate objects with animated narrative and, the more recent the artifacts, the more human the stories they can tell.

  9. American Material Culture: Investigating a World War II Trash Dump

    Energy Technology Data Exchange (ETDEWEB)

    Julie Braun

    2005-10-01

    The Idaho National Laboratory: An Historical Trash Trove Historians and archaeologists love trash, the older the better. Sometimes these researchers find their passion in unexpected places. In this presentation, the treasures found in a large historic dump that lies relatively untouched in the middle of the Idaho National Laboratory (INL) will be described. The U.S. military used the central portion of the INL as one of only six naval proving grounds during World War II. They dumped trash in dry irrigation canals during and after their wartime activities and shortly before the federal government designated this arid and desolate place as the nation’s nuclear reactor testing station in 1949. When read critically and combined with memories and photographs, the 60-year old trash provides a glimpse into 1940s’ culture and the everyday lives of ordinary people who lived and worked during this time on Idaho’s desert. Thanks to priceless stories, hours of research, and the ability to read the language of historic artifacts, the dump was turned from just another trash heap into a treasure trove of 1940s memorabilia. Such studies of American material culture serve to fire our imaginations, enrich our understanding of past practices, and humanize history. Historical archaeology provides opportunities to integrate inanimate objects with animated narrative and, the more recent the artifacts, the more human the stories they can tell.

  10. Phytoremediation of coal mine spoil dump through integrated biotechnological approach.

    Science.gov (United States)

    Juwarkar, Asha A; Jambhulkar, Hemlata P

    2008-07-01

    Field experiment was conducted on mine spoil dump on an area of 10 ha, to restore the fertility and productivity of the coal mine spoil dump using integrated biotechnological approach. The approach involves use of effluent treatment plant sludge (ETP sludge), as an organic amendment, biofertilizers and mycorrihzal fungi along with suitable plant species. The results of the study indicated that amendment with effluent treatment plant sludge (ETP sludge), @ 50 ton/ha improved the physico-chemical properties of coal mine spoil. Due to biofertilizer inoculation different microbial groups such as Rhizobium, Azotobacter and VAM spores, which were practically absent in mine spoil improved greatly. Inoculation of biofertilizer and application of ETP sludge helped in reducing the toxicity of heavy metals such as chromium, zinc, copper, iron, manganese lead, nickel and cadmium, which were significantly reduced to 41%, 43%, 37%, 37%, 34%, 39%, 37% and 40%, respectively, due to the increased organic matter content in the ETP sludge and its alkaline pH (8.10-8.28), at which the metals gets immobilized and translocation of metals is arrested. Thus, amendment and biofertilizer application provided better supportive material for anchorage and growth of the plant on coal mine spoil dump.

  11. An ATP and oxalate generating variant tricarboxylic acid cycle counters aluminum toxicity in Pseudomonas fluorescens.

    Directory of Open Access Journals (Sweden)

    Ranji Singh

    Full Text Available Although the tricarboxylic acid (TCA cycle is essential in almost all aerobic organisms, its precise modulation and integration in global cellular metabolism is not fully understood. Here, we report on an alternative TCA cycle uniquely aimed at generating ATP and oxalate, two metabolites critical for the survival of Pseudomonas fluorescens. The upregulation of isocitrate lyase (ICL and acylating glyoxylate dehydrogenase (AGODH led to the enhanced synthesis of oxalate, a dicarboxylic acid involved in the immobilization of aluminum (Al. The increased activity of succinyl-CoA synthetase (SCS and oxalate CoA-transferase (OCT in the Al-stressed cells afforded an effective route to ATP synthesis from oxalyl-CoA via substrate level phosphorylation. This modified TCA cycle with diminished efficacy in NADH production and decreased CO(2-evolving capacity, orchestrates the synthesis of oxalate, NADPH, and ATP, ingredients pivotal to the survival of P. fluorescens in an Al environment. The channeling of succinyl-CoA towards ATP formation may be an important function of the TCA cycle during anaerobiosis, Fe starvation and O(2-limited conditions.

  12. An effective low Pd-loading catalyst for hydrogen generation from formic acid

    DEFF Research Database (Denmark)

    Huang, Yunjie; Xu, Junlei; Ma, Xin

    2017-01-01

    roles. In addition, Ag additive was found to benefit catalyst stability. Most interestingly, the obtained low Pd-loading Pd1Ag6/N-rGO catalyst showed a specific Pd loading turnover frequency of 171 mol Pd−1 h−1 and a specific metal cost turnover frequency of 64.2 $−1 h−1, which were predominant among......As an interesting hydrogen carrier, formic acid is bio-renewable, non-toxic and available in the liquid state at room temperature. The development of active and low-cost catalyst is of significance for hydrogen generation from formic acid. In this study, both a relatively cheap metal (Ag......) and a functional support (nitrogen modified reduced graphene oxide, N-rGO) were applied to prepare Pd catalyst. It was found that the Ag atoms facilitated the formation of Pd-rich surface in the preparation strategy, in which the reductive N-rGO and a two-step feeding process of metal precursors played important...

  13. Deep-cavity cavitand octa acid as a hydrogen donor: photofunctionalization with nitrenes generated from azidoadamantanes.

    Science.gov (United States)

    Choudhury, Rajib; Gupta, Shipra; Da Silva, José P; Ramamurthy, V

    2013-03-01

    1-azidoadamantane and 2-azidoadamantane form a 1:1 complex with hosts octa acid (OA) and cucurbit[7]uril (CB7) in water. Isothermal titration calorimetric measurements suggest these complexes to be very stable in aqueous solution. The complexes have been characterized by (1)H NMR in solution and by ESI-MS in gas phase. In both phases, the complexes are stable. Irradiation of these complexes (λ > 280 nm) results in nitrenes via the loss of nitrogen from the guest azidoadamantanes. The behavior of nitrenes within OA differs from that in solution. Nitrenes included within octa acid attack one of the four tertiary benzylic hydrogens present at the lower interior part of OA. While in solution intramolecular insertion is preferred, within OA intermolecular C-H insertion seems to be the choice. When azidoadamantanes included in CB7 were irradiated (λ > 280 nm) the same products as in solution resulted but the host held them tightly. Displacement of the product required the use of a higher binding guest. In this case, no intermolecular C-H insertion occurred. Difference in reactivity between OA and CB7 is the result of the location of hydrogens; in OA they are in the interior of the cavity where the nitrene is generated, and in CB7 they are at the exterior. Reactivity of nitrenes within OA is different from that of carbenes that do not react with the host.

  14. Salicylic acid-induced superoxide generation catalyzed by plant peroxidase in hydrogen peroxide-independent manner.

    Science.gov (United States)

    Kimura, Makoto; Kawano, Tomonori

    2015-01-01

    It has been reported that salicylic acid (SA) induces both immediate spike and long lasting phases of oxidative burst represented by the generation of reactive oxygen species (ROS) such as superoxide anion radical (O2(•-)). In general, in the earlier phase of oxidative burst, apoplastic peroxidase are likely involved and in the late phase of the oxidative burst, NADPH oxidase is likely involved. Key signaling events connecting the 2 phases of oxidative burst are calcium channel activation and protein phosphorylation events. To date, the known earliest signaling event in response to exogenously added SA is the cell wall peroxidase-catalyzed generation of O2(•-) in a hydrogen peroxide (H2O2)-dependent manner. However, this model is incomplete since the source of the initially required H2O2 could not be explained. Based on the recently proposed role for H2O2-independent mechanism for ROS production catalyzed by plant peroxidases (Kimura et al., 2014, Frontiers in Plant Science), we hereby propose a novel model for plant peroxidase-catalyzed oxidative burst fueled by SA.

  15. Generation of Novel Thyroid Cancer Stem-Like Cell Clones: Effects of Resveratrol and Valproic Acid.

    Science.gov (United States)

    Hardin, Heather; Yu, Xiao-Min; Harrison, April D; Larrain, Carolina; Zhang, Ranran; Chen, Jidong; Chen, Herbert; Lloyd, Ricardo V

    2016-06-01

    Anaplastic thyroid cancer is an aggressive and highly lethal cancer for which conventional therapies have proved ineffective. Cancer stem-like cells (CSCs) represent a small fraction of cells in the cancer that are resistant to chemotherapy and radiation therapy and are responsible for tumor reoccurrence and metastasis. We characterized CSCs in thyroid carcinomas and generated clones of CSC lines. Our study showed that anaplastic thyroid cancers had significantly more CSCs than well-differentiated thyroid cancers. We also showed that Aldefluor-positive cells revealed significantly higher expression of stem cell markers, self-renewal properties, thyrosphere formation, and enhanced tumorigenicity. In vivo passaging of Aldefluor-positive cells resulted in the growth of larger, more aggressive tumors. We isolated and generated two clonal spheroid CSC lines derived from anaplastic thyroid cancer that were even more enriched with stem cell markers and more tumorigenic than the freshly isolated Aldefluor-positive cells. Resveratrol and valproic acid treatment of one of the CSC lines resulted in a significant decrease in stem cell markers, Aldefluor expression, proliferation, and invasiveness, with an increase in apoptosis and thyroid differentiation markers, suggesting that these cell lines may be useful for discovering new adjuvant therapies for aggressive thyroid cancers. For the first time, we have two thyroid CSC lines that will be useful tools for the study of thyroid CSC targeted therapies.

  16. Waste dumps rehabilitation measures based on physico-chemical analyses in Zăghid mining area (Sălaj County, Romania

    Directory of Open Access Journals (Sweden)

    Ildiko M. Varga

    2011-08-01

    Full Text Available The present study deals with an abandoned coal mine from Zăghid area, North-WesternTransylvanian Basin (Sălaj County. The mining activity was stopped in 2005, without any attempt ofecological rehabilitation of the mined area and especially of the waste dumps left behind. The proposedrehabilitation models are based on some physical-chemical analyses of soil and waste samples (e.g. pH,EC, Salinity, humidity, porosity, density, plasticity, organic substances, mineralogical composition, heavymetals. Erosion map has been drawn based on the determined mineralogical composition (accordingSTAS 1913/5-85 – using Galton curve of tailings and the soil type. The values obtained for moisture andplasticity have been used to determine the ideal general inclination angle of the landfill systems in thestudied perimeter. Through chemical analysis, heavy metals like Ni and Cu have been identified, as themain pollution factors for surface and underground water. Therefore, the concentration of heavy metalsin the waters from Zăghid area is high in the water bodies, which are formed on waste dumps, but alsoin the mine water. This analysis is useful in establishing the actual state of the waste dumps and theircontent and the negative effects, which exercise on the environment in order to select the rehabilitationmodel for the waste dumps from Zăghid mining area. The main measures consist in: waste dumpsleveling, soil remediation, perennial plants culture and acid mine water decontamination.

  17. Reclamation of the illegal dump for sustainable development the environment in Sverdlovo of Leningrad Oblast’, Russia

    Directory of Open Access Journals (Sweden)

    Bukova Maria

    2016-01-01

    Full Text Available Illegal dumping is dumping of any waste such as oil, furniture, appliances, trash, litter or landscaping cuttings, upon any land of state, city, village or private ownership without consent of the owner. Illegal dumping has a great negative and fatal impact on our environment and all living organisms both fauna and flora. It also exposes people to various risks of chemicals (fluids or dust and is a big threat to all under-ground and surface water resources. Illegal dumps also attract all kinds of bugs such as rodents and insects. For example, illegal dumps with waste tires provide a practically perfect place for mosquitoes to breed. Mosquitoes can multiply 100 times faster than normal in the warm, stagnant water in waste tires. Exemplary for the illegal dump in Sverdlovo of Leningrad Oblast’ the main purpose of this article is to offer a possible option for the remediation of contaminated area.

  18. Charging for the waste dumping of open-pit metal mines

    Institute of Scientific and Technical Information of China (English)

    Yunbing Hou; Zhaoxiang Zhang; Haifeng Duan; Liming Xue

    2006-01-01

    Based on the externality theory and the environmental value theory, the hypothesis of charging for waste dumping of open-pit metal mines was put forth. The charging methods were designed according to the characteristics of waste dumping of openpit metal mines, including charging based on the dumping amount of the total waste, multi-charging factors, exceeding standard punishment charging, and so on. The main charging parameter is based on the dumping area rather than the total amount of waste dumping.The charging model of waste dumping of open-pit mines was formulated, and the charging rate was divided into two parts, i.e., the standard charging rate and the differential charging rate. The standard charging rate was derived using the equilibrium dynamic model,whereas the differential one was obtained by establishing the fuzzy synthesized evaluation model.

  19. Soils on overburden dumps in the forest-steppe and mountain taiga zones of the Kuzbass

    Science.gov (United States)

    Bragina, P. S.; Tsibart, A. S.; Zavadskaya, M. P.; Sharapova, A. V.

    2014-07-01

    The properties of the soils forming on coal dumps significantly depend on the properties of the parent rocks and the technology of creating the dumps. In the forest-steppe and mountain taiga zones of the Kuznetsk Coal Basin, argillites, siltstones, and sandstones are the overburden and enclosing rocks. They are responsible for the alkaline reaction and the same microelement composition in almost all the soils studied. The nonselective formation of the dumps and the predominance of the coarse fraction in the rocks composing the dumps is a cause of the wide distribution of petrozems and humus petrozems on their surface. The presence of a great amount of coal particles in the substrates and the incorrect planning of the dumps may be the reasons for their self-ignition, which can change the composition of polycyclic aromatic hydrocarbons in the soils of the dumps.

  20. Assessment of relationship between fungal aerosol within a municipal dump and epiphytic mycoflora of crop plants.

    Science.gov (United States)

    Ropek, Dariusz Roman; Fraczek, Krzysztof; Kozdrój, Jacek; Chmiel, Maria

    2013-01-01

    A field study was performed to assess whether fungal aerosol of a municipal dump may impact on quantitative and qualitative characteristics of epiphytic mycoflora of crop plants cultivated in vicinity of the dump. Sampling sites were located at every side of the dump. Plant samples were collected from field bean, spring wheat and potato. The highest concentration of fungal aerosol was found at the field located south of the dump within the zone of 250 m next to its borders. For this zone, the most numerous and diverse mycoflora was ascertained, and the plants cultivated were the most damaged. The results suggest that the municipal dump was not the source of phytopathogenic fungi; however, different emissions of contaminants from the dump might cause a decline in the intrinsic plant resistance against the pathogens.

  1. Generations.

    Science.gov (United States)

    Chambers, David W

    2005-01-01

    Groups naturally promote their strengths and prefer values and rules that give them an identity and an advantage. This shows up as generational tensions across cohorts who share common experiences, including common elders. Dramatic cultural events in America since 1925 can help create an understanding of the differing value structures of the Silents, the Boomers, Gen Xers, and the Millennials. Differences in how these generations see motivation and values, fundamental reality, relations with others, and work are presented, as are some applications of these differences to the dental profession.

  2. Automatic Post-Operational Checks for the LHC Beam Dump System

    CERN Document Server

    Gallet, E; Baggiolini, V; Carlier, E; Goddard, B; Kain, V; Lamont, M; Magnin, N; Verhagen, H; Uythoven, J

    2008-01-01

    In order to ensure the required level of reliability of the LHC beam dump system a series of post-operational checks must be performed after each dump action. This paper describes the various data handling and data analysis systems which are required internally and at different levels of the LHC control system, for postoperational checks, and the experience from the commissioning of the equipment where these systems were used to analyse the dump kicker performance.

  3. Distribution of Fatty Acids and Triethanolamine in Synthetic Metalworking Fluid Aerosols Generated in the Laboratory and Field

    Energy Technology Data Exchange (ETDEWEB)

    Ilgner, R.H., Palausky, A., Jenkins, R.A. [Oak Ridge National Lab., TN (United States) Chemical and Analytical Sciences Div.], Ball, A.M., Lucke, W.E. [Cincinnati Milacron, OH (United States)

    1997-12-31

    Metalworking fluid mists were generated in the laboratory with selected synthetic fluids by nebulization and with an air sparging apparatus. Short chain fatty acid species were determined in the vapor and particulate phase of the resulting aerosols using in-situ trimethyl silyl derivatization. Certain fatty acid species in sparger generated mists were found in the vapor phase in greater quantities relative to the particle phase, compared with the corresponding amounts determined in nebulized mists. With one metalworking fluid, the nonanoic acid vapor phase to particulate phase concentration ratio was over 14 fold higher with air sparged mists (1.0) than with the corresponding nebulized mists (0.07). The nonanoic acid vapor phase concentrations were 0.026 mg/m{sup 3} and 0.002 mg/m{sup 3} for sparged (bubbled) and nebulized mists respectively. This phenomenon was observed with mists generated from several selected synthetic metalworking fluids. This could suggest that in the work place environment, with a variety of mist generation mechanisms occurring simultaneously, significant vapor phase concentrations of certain species could exist in an environment where particulate levels are low. Vapor phase fatty acid levels could remain relatively high in an occupational setting even when mist levels are reduced with efficient air cleaning devices. Results from mist generation experiments performed in the laboratory, were compared with actual field data from a relatively clean metal machining operation. Anecdotal evidence of potential irritation by short chain fatty acids prompted a study of this industrial site. Numerous air scrubbing devices were utilized at this industrial site to reduce airborne particulates, which typically ranged from 0.05 to 0.4 mg/m{sup 3}. Comparisons were made of triethanolamine and short chain fatty acid concentrations in vapor and particulate phases measured in the laboratory and work place environment.

  4. Effects of saline infusion on titratable acid generation and ammonia secretion.

    Science.gov (United States)

    Wilcox, C S; Granges, F; Kirk, G; Gordon, D; Giebisch, G

    1984-09-01

    Short-term hyperchloremic metabolic acidosis can decrease sodium reabsorption by the superficial proximal tubule (PT), increase tubular fluid flow rate, and stimulate aldosterone release. We studied the effects of increased tubular fluid delivery (graded saline infusion) and mineralocorticosteroid administration on tubular fluid pH (TFpH), titratable acid (TA) generation, and ammonium (NH+4) secretion by superficial proximal and distal tubules (DT) of acidotic, phosphate-loaded rats. The TFpH was 6.4 +/- 0.1 at the late proximal tubule (LP); it was unaltered at the early (ED) or late distal tubule (LD), but urine pH (UpH) was 1 unit lower. The major fraction of TA or NH+4 was formed in the superficial PT. There was no net TA generation by the superficial DT even during supplemental mineralocorticosteroid and increased Pi delivery during saline infusion. TA excretion was increased only slightly by saline infusion in acidotic rats despite increased buffer delivery (caused by decreased Pi reabsorption, primarily in the loop segment) because this was offset by a rise in UpH. Ammonia was secreted into tubular fluid in the superficial PT and DT; there was loss of NH+4 in the loop segment and addition after the LD. Saline infusion did not modify TFpH in the PT or DT but increased NH+4 secretion by the DT in direct proportion to tubular fluid flow. DOCA administration increased the addition of NH+4 between the LD and the urine. In conclusion 1) the superficial PT is of major importance for acidification, generation of TA, and secretion of NH+4 in short-term metabolic acidosis. 2) The superficial DT does not generate TA even during dramatically high rates of buffer delivery and mineralocorticosteroid administration. 3) Excretion of NH+4 is increased by saline infusion, which leads to flow-dependent NH+4 secretion by the superficial DT. 4) Chronic administration of DOCA stimulates NH+4 secretion predominantly in the terminal or deep nephrons.

  5. Game Analysis of Implementing Price Undertaking Agreements in Anti-dumping Disputes

    Institute of Scientific and Technical Information of China (English)

    XI Jun-fang; CANG Ping; ZHONG Gen-yuan

    2008-01-01

    The Price Undertaking Agreement is one of the strategies a company accused of dumping often adopts in dealing with anti-dumping disputes. Using static game analysis, this paper compares the impact that anti-dumping duties and price undertaking agreements may have on an importing country's social welfare and an accused company's market performance. We conclude that, compared with anti-dumping duties, price undertakings improve the importing country's social welfare and reduce the accused company's market share in the import country. We also note that, in addition to the financial benefit, price undertakings can prevent escalation of trade disputes in international trade negotiations.

  6. Preliminary studies on trace element contamination in dumping sites of municipal wastes in India and Vietnam

    Science.gov (United States)

    Agusa, T.; Kunito, T.; Nakashima, E.; Minh, T. B.; Tanabe, S.; Subramanian, A.; Viet, P. H.

    2003-05-01

    The disposal of wastes in dumping sites has increasingly caused concem about adverse health effects on the populations living nearby. However, no investigation has been conducted yet on contamination in dumping sites of municipal wastes in Asian developing countries. In this study, concentrations of 11 trace elements (V, Cr, Mn, Co, Cu, Zn, Mo, Ag, Cd, Sb and Pb) were detennined in scalp hair from the population living nearby and in soil from dumping sites and control sites of India and Vietnam. Soil samples in dumping site in India showed significantly higher concentrations of some trace elements than soils in control site, whereas this trend was not notable in Vietnam. This is probably due to the fact that the wastes were covered with the soil in the dumping site of Vietnam. Cadmium concentrations in some hair samples of people living near dumping site in India and Vietnam exceeded the level associated with learning disorder in children. Levels of most of the trace elements in hair were significantly higher in dumping site than those in control site in India and Vietnam, suggesting direct or indirect exposure to those elements from dumping wastes. To our knowledge, this is the first study of trace element contamination in dumping sites in India and Vietnam.

  7. Dumping and injury margins in markets with horizontal as well as vertical product differentiation

    DEFF Research Database (Denmark)

    Nielsen, Jørgen Ulff-Møller; Hansen, Jørgen Drud

    2009-01-01

    This paper examines the GATT/WTO rules for anti-dumping measures in a duopoly model with both horizontal and vertical product differentiation. The GATT/WTO rules allow for anti-dumping measures if domestic producers, exposed to price discrimination, also demonstrate injury where price...... countries in ability to implement anti-dumping measures predominantly favors the developed countries which are specialized in producing high-quality products. The paper suggests an overall critical look at the lenient rules for implementing anti-dumping measures-especially the rules for injury determination...

  8. [Anastomotic false-diverticulum causing an atypical dumping syndrome. A case report].

    Science.gov (United States)

    Covarelli, P; Esperti, L; Fratto, A; Cerroni, M; Marianeschi, P; Cristofani, R

    2003-02-01

    Aim of the study is to evaluate the causes of dumping syndromes following partial gastrectomies, and to report an unusual feature of dumping. A case of early dumping due to diverticular-like dilation of gastro-jejunal anastomosis is described with preoperative imaging and intraoperative picture. The surgical correction led to complete clinical remission; the common causes and physiopathological bases of dumping are reviewed and the role of en-Y gastro-jejunal reconstruction is underlined in order to reduce the risk of developing the syndrome.

  9. Polish legal regulations considering recovery of secondary materials from coal mining dumping grounds

    Directory of Open Access Journals (Sweden)

    Gawor Łukasz

    2014-12-01

    Full Text Available In the article there is presented temporary situation of coal mining dumping grounds in Poland – their inventarization, localization and environmental impacts. The coal mining dumping grounds in Poland are situated in three coal basins: Upper Silesian Coal Basin, Lower Silesian Coal Basin and Lublin Coal Basin. In all mentioned areas occur ca. 270 coal mining waste dumps, covering surface of over 4400 ha. The main environmental impacts connected with dumping grounds are fire hazards, water pollution and a danger of slope sliding. The question of recovery of coal from disposed wastes with regard to legal regulations is discussed. There are presented technical methods of coal recovery considering environmental protection issues. There is a necessity and technical possibility of recovery of coal from the coal-mining waste dumps. The coal recovery reduces hazards of self-ignition and fires of the dump. It is also economically justified. The analysis of required regulations in legal system in Poland for safe exploitation of secondary materials from coal mining dumps is done. Socio-economic aspects of recovery of coal are discussed. The valid legal regulations in Poland regulate the issues connected with coal mining dumping grounds in a very general way. It is necessary to prepare supplements to the legal provisions or new regulations concerning post-mining dumping grounds.

  10. Revegetation of non-Acid-generating, thickened tailings with boreal trees: a greenhouse study.

    Science.gov (United States)

    Larchevêque, Marie; Desrochers, Annie; Bussière, Bruno; Cartier, Hélène; David, Jean-Sébastien

    2013-01-01

    Tree planting presents clear advantages for mine reclamation that is aimed at achieving rapid reclamation of forested landscapes. A greenhouse study was conducted to evaluate the capacity of non-acid-generating, thickened tailings to support six boreal tree species during two growing seasons. One treatment was thickened tailings alone fertilized with inorganic N, P, and K fertilizer or chicken () manure. A thin layer of overburden topsoil was used to cover the tailings and was compared with topsoil alone, where normal tree growth was expected. Two amendments were also tested: overburden topsoil and vermicompost from food wastes. The presence of alkaline thickened tailings under the thin layer of acidic topsoil had a positive effect on tree height and root biomass (broadleaved and jack pine [ Lamb.]) by increasing topsoil pH and available Ca concentrations, which decreased Al, Zn, and Mn phytoavailability to trees; however, root contact with the tailings also increased their Cu concentrations. In thickened tailings that were mixed with topsoil, C/N ratios increased along the experiment from 21 to 40, a value where N immobilization by microorganisms occurred, as suggested by low N concentrations in tree tissues. In consequence, tree height growth (broadleaved) and biomass (conifers) were reduced. Amendment with compost raised the electrical conductivity (3.4 dS cm) to thresholds limiting broadleaved survival, while conifers showed a generalized decrease in biomass production. No trace metal contamination of the trees occurred in the mixtures, probably due to the near-neutral pH conferred by the tailings. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  11. An Investigation of the Acid Rock Drainage Generation from the Road Cut Slope in the Middle Part of South Korea

    Science.gov (United States)

    Ji, S.; Cheong, Y.; Yim, G.

    2006-05-01

    To examine the Acid Rock Drainage (ARD) generation from the road cut slope, a prediction study including Acid-Base Accounting (ABA) test and Net Acid Generation (NAG) test was performed for road cut rock samples (20 samples) at the new construction site of a highway in the middle part of South Korea. This slope is composed of slate and phyllite. It was a pit wall which was operated as a quarry which produced materials for roofing. pH1:2 and EC1:2 measurements were performed to evaluate free hydrogen ion contents and salts in samples. ABA test was performed to estimate the balance of the acid generating minerals (mainly pyrite) and the acid neutralizing minerals (mainly carbonates) in rock samples. Total sulfur was analyzed by sulfur analyzer, and then the maximum potential acidity (MPA, kg H2SO4/t) was calculated. X-ray diffraction (XRD) analysis was performed to identify the mineral composition of rock samples. Acid neutralizing capacity (ANC) test, after the Sobek et al. (1978), was performed to estimate the amount of acid originated from the oxidation of sulfide minerals. NAPP (Net Acid Producing Potential) was calculated by total sulfur (MPA) and ANC. NAG test was performed with grounded samples and 15 % hydrogen peroxide, and then NAG was analyzed by measuring pH (NAGpH) of the mixed solution. pH1:2 and EC1:2 ranged from 2.95 to 7.23 and 17.1 to 3070.0 ¥ìS/cm, respectively. MPA of samples was ranged from 0.0 to 79.9 kg H2SO4/t. From the XRD analysis pyrite was found at the most samples. In the sample from highly weathered dike, goethite was found. Results of the ANC tests indicated that the value of ANC reached up to 59.36 kg H2SO4/t. Rock samples could be classified as Potential Acid Forming rock (PAF) and Non- Acid Forming rock (NAF) by plotting NAPP versus NAGpH. In this study 17 samples were classified as PAF rock. It means that this slope would generate ARD when they reacted with rain. Two samples were grouped as NAF. By application this ARD prediction

  12. Calcium-dependent generation of N-acylethanolamines and lysophosphatidic acids by glycerophosphodiesterase GDE7.

    Science.gov (United States)

    Rahman, Iffat Ara Sonia; Tsuboi, Kazuhito; Hussain, Zahir; Yamashita, Ryouhei; Okamoto, Yoko; Uyama, Toru; Yamazaki, Naoshi; Tanaka, Tamotsu; Tokumura, Akira; Ueda, Natsuo

    2016-12-01

    N-Acylethanolamines form a class of lipid mediators and include an endocannabinoid arachidonoylethanolamide (anandamide), analgesic and anti-inflammatory palmitoylethanolamide, and appetite-suppressing oleoylethanolamide. In animal tissues, N-acylethanolamines are synthesized from N-acylated ethanolamine phospholipids directly by N-acylphosphatidylethanolamine-hydrolyzing phospholipase D or through multi-step pathways via N-acylethanolamine lysophospholipids. We previously reported that glycerophosphodiesterase (GDE) 4, a member of the GDE family, has lysophospholipase D (lysoPLD) activity hydrolyzing N-acylethanolamine lysophospholipids to N-acylethanolamines. Recently, GDE7 was shown to have lysoPLD activity toward lysophosphatidylcholine to produce lysophosphatidic acid (LPA). Here, we examined the reactivity of GDE7 with N-acylethanolamine lysophospholipids as well as the requirement of divalent cations for its catalytic activity. When overexpressed in HEK293 cells, recombinant GDE7 proteins of human and mouse showed lysoPLD activity toward N-palmitoyl, N-oleoyl, and N-arachidonoyl-lysophosphatidylethanolamines and N-palmitoyl-lysoplasmenylethanolamine to generate their corresponding N-acylethanolamines and LPAs. However, GDE7 hardly hydrolyzed glycerophospho-N-palmitoylethanolamine. Overexpression of GDE7 in HEK293 cells increased endogenous levels of N-acylethanolamines and LPAs. Interestingly, GDE7 was stimulated by micromolar concentrations of Ca(2+) but not by millimolar concentrations of Mg(2+), while GDE4 was stimulated by Mg(2+) but was insensitive to Ca(2+). GDE7 was widely distributed in various tissues of humans and mice with the highest levels in their kidney tissues. These results suggested that GDE7 is a novel Ca(2+)-dependent lysoPLD, which is involved in the generation of both N-acylethanolamines and LPAs.

  13. Nucleic acid reactivity: challenges for next-generation semiempirical quantum models.

    Science.gov (United States)

    Huang, Ming; Giese, Timothy J; York, Darrin M

    2015-07-01

    Semiempirical quantum models are routinely used to study mechanisms of RNA catalysis and phosphoryl transfer reactions using combined quantum mechanical (QM)/molecular mechanical methods. Herein, we provide a broad assessment of the performance of existing semiempirical quantum models to describe nucleic acid structure and reactivity to quantify their limitations and guide the development of next-generation quantum models with improved accuracy. Neglect of diatomic differential overlap and self-consistent density-functional tight-binding semiempirical models are evaluated against high-level QM benchmark calculations for seven biologically important datasets. The datasets include: proton affinities, polarizabilities, nucleobase dimer interactions, dimethyl phosphate anion, nucleoside sugar and glycosidic torsion conformations, and RNA phosphoryl transfer model reactions. As an additional baseline, comparisons are made with several commonly used density-functional models, including M062X and B3LYP (in some cases with dispersion corrections). The results show that, among the semiempirical models examined, the AM1/d-PhoT model is the most robust at predicting proton affinities. AM1/d-PhoT and DFTB3-3ob/OPhyd reproduce the MP2 potential energy surfaces of 6 associative RNA phosphoryl transfer model reactions reasonably well. Further, a recently developed linear-scaling "modified divide-and-conquer" model exhibits the most accurate results for binding energies of both hydrogen bonded and stacked nucleobase dimers. The semiempirical models considered here are shown to underestimate the isotropic polarizabilities of neutral molecules by approximately 30%. The semiempirical models also fail to adequately describe torsion profiles for the dimethyl phosphate anion, the nucleoside sugar ring puckers, and the rotations about the nucleoside glycosidic bond. The modeling of pentavalent phosphorus, particularly with thio substitutions often used experimentally as mechanistic

  14. A summary of the test procedures and operational details of a Delaware River and an ocean dumping pollution monitoring experiment conducted 28 August 1975

    Science.gov (United States)

    Hypes, W. D.; Ohlhorst, C. W.

    1977-01-01

    Two remote sensor evaluation experiments are discussed. One experiment was conducted at the DuPont acid-dump site off the Delaware coast. The second was conducted at an organic waste outfall in the Delaware River. The operational objective of obtaining simultaneous sea truth sampling with remote sensors overpasses was met. Descriptions of the test sites, sensors, sensor platforms, flight lines, sea truth data collected, and operational chronology are presented.

  15. Groundwater Quality Deterioration due to Municipal Solid Waste Dumping Practices

    Science.gov (United States)

    Parameswari, Kaliyaperumal; Karunakaran, Krishnasamy

    2011-07-01

    Groundwater is the major source of drinking water in both urban and rural India. The demand for water has increased over the years and this has led to water scarcity. The scarcity situation, especially in urban areas, is aggravated by the problem of water pollution or contamination by solid waste dumping. In many urban centers in India, the quality of groundwater is getting severely affected because of the widespread pollution, due to the discharge of untreated waste water in water bodies and leachate from the unscientific disposal of solid wastes. It is necessary to realize the importance of groundwater and preserve its quality through careful monitoring and remediation. This study focuses on the magnitude of groundwater pollution due to improper solid waste dumping practices prevailing in the southern part of the Chennai Metropolitan Area. The Perungudi dumpsite, a solid waste dumping site in the periphery of Chennai city, India, has been chosen for this study. The chemical characteristic of solid waste and leachate has been studied, and the groundwater samples from various locations around the dumpsite were collected and analyzed. Samples were analyzed for pH, electrical conductivity, total dissolved solids, chlorides, sulfate, calcium, magnesium, total hardness, sodium, potassium, BOD, and COD. Heavy metals such as lead, iron, and zinc have been analyzed. The study reveals that most of the groundwater samples do not conform to drinking water quality standards. The study also indicates that groundwater remediation techniques and proper groundwater quality monitoring on a regular basis are of utmost importance in the study area. A few in-situ groundwater remediation technologies have been suggested to improve the present water quality.

  16. Estimation of dietary folic acid intake in three generations of females in Southern Spain.

    Science.gov (United States)

    Monteagudo, C; Mariscal-Arcas, M; Palacin, A; Lopez, M; Lorenzo, M L; Olea-Serrano, F

    2013-08-01

    An adequate folic acid intake has been related to female fertility. The recommended intake of this vitamin was recently increased to 400μg/day, with an additional 200μg/day during pregnancy. The Mediterranean Diet includes sources of folate such as pulses, green-leaf vegetables, fruit, cereals, and dried fruits; other foods of interest are liver and blue fish. The objectives were to determine the foods that contribute most to folate intake and analyze the factors that influence their consumption by three generations in a female population (n=898; age, 10-75yrs) from Southern Spain: 230 adolescents (10-16yrs), 296 healthy pregnant women (19-45yrs), and 372 menopausal women (>45yrs). Participants completed a previously validated semi-quantitative food frequency questionnaire. Over 90% of their folate intake was supplied by cereals, fruit, natural juice, pulses, and cooked and raw vegetables. The mean (SD) daily intake of folate was 288.27(63.64) μg. A higher Mediterranean Diet Score (MDS) was significantly related to a greater folate intake. The daily folate intake was not significantly influenced by educational level, number of children, or place of residence (rural vs. urban). In logistic regression analysis, the factors related to an adequate folate intake (>2/3 of recommendations) were higher age, higher MDS, and lower BMI.

  17. Numerical Simulations of Static Tested Ramjet Dump Combustor

    Science.gov (United States)

    Javed, Afroz; Chakraborty, Debasis

    2016-06-01

    The flow field of a Liquid Fuel Ram Jet engine side dump combustor with kerosene fuel is numerically simulated using commercial CFD code CFX-11. Reynolds Averaged 3-D Navier-Stokes equations are solved alongwith SST turbulence model. Single step infinitely fast reaction is assumed for kerosene combustion. The combustion efficiency is evaluated in terms of the unburnt kerosene vapour leaving the combustor. The comparison of measured pressures with computed values show that the computation underpredicts (~5 %) pressures for non reacting cases but overpredicts (9-7 %) for reacting cases.

  18. Optimization of Front Axle Suspension System of Articulated Dump Truck

    DEFF Research Database (Denmark)

    Langer, Thomas Heegaard; Christensen, Brian B.; Mouritsen, Ole Ø.

    2010-01-01

    ongoing research collaboration between Hydrema Produktion A/S, Aalborg University and the University of Agder on comfort improvement. The main goal of the research project is to improve ride comfort of articulated construction machinery by use of multibody simulation models. In this paper the application...... that has been subjected to comfort improvement is a two axle articulated dump truck. The comfort has been in terms of whole body vibration exposure and the overall improvement has been made possible by adding front axle suspension. However, a hydraulic stabilizing system between the tractor and trailer...

  19. Beam dumps, stoppers and Faraday cups at the SLC

    Energy Technology Data Exchange (ETDEWEB)

    Walz, D.R.; McFarlane, A.; Lewandowski, E.

    1989-04-01

    This presentation features most of the beam dumps and stoppers necessary to absorb and dissipate SLC e/sup +-/ beams with transverse sizes from several tens to a few hundred microns (..mu..m). Solutions are based on electromagnetic cascade shower calculations for N = 5 /times/ 10/sup 10/ e/bunch and momenta ranging from 1.2 GeV/c in the damping ring transport systems to 50 GeV/c in the arcs matching sections and the Final Focus region. 3 refs., 2 figs.

  20. The early postprandial dumping syndrome: prevention and treatment.

    Science.gov (United States)

    Woodward, E R; Bushkin, F L

    1976-01-01

    The early postprandial dumping syndrome can be prevented or minimized by the appropriate selection of the operative procedure to fit the patient and the peptic ulcer problem he presents, and by proper attention to diet in the early postoperative period. When it does occur, the syndrome usually responds favorably to dietary management and tends to spontaneously regress in severity with time. For these reasons further surgery is seldom required for the early postprandial dumping syndrome. In the patient who fails to improve with diet therapy and time and has disabling symptoms often accompanied by progressive malnutrition, revisional surgery should be undertaken. It is the objective of the surgeon to alter the reconstruction in such a way that emptying from the stomach or gastric remnant is delayed. Therefore, the upper small intestine dose not receive a large, rapidly introduced hyperosmolar bolus to initiate the release of humoral substances causing the syndrome. All revisions utilized are potentially ulcerogenic and if vagotomy has not been a part of the original procedure, it should routinely be performed at the time of revision. Patients who have primarily has a Billroth II gastrectomy will frequently improve markedly with simple conversion to a Billroth I reconstruction. This is particularly true when the residual stomach is moderately large (i.e., after antrectomy) and when the gastrojejunal stoma is larger in diameter than the normal jejunum. Under such circumstances approximately 80 per cent of patients will improve sufficiently so that a more complex procedure need not be utilized at once. Under all other conditions we prefer a 10 cm. segment of reversed jejunum anastomosed proximally to the gastric stump and distally to a 40 cm. isoperistaltic Roux-en-Y jejunal limb. This procedure is so successful that one can justify its use as first recourse even in the anatomically favorable Billroth II patient. It should be pointed out emphatically that an

  1. Human neutrophils dump Candida glabrata after intracellular killing.

    Science.gov (United States)

    Essig, Fabian; Hünniger, Kerstin; Dietrich, Stefanie; Figge, Marc Thilo; Kurzai, Oliver

    2015-11-01

    Interaction between fungal pathogens and human phagocytes can lead to remarkably variable outcomes, ranging from intracellular killing to prolonged survival and replication of the pathogen in the host cell. Using live cell imaging we observed primary human neutrophils that release phagocytosed Candida glabrata yeast cells after intracellular killing. This process, for which we propose the name "dumping", adds a new outcome to phagocyte-fungus interaction which may be of potential immunological importance as it allows professional antigen presenting cells to take up and process neutrophil-inactivated pathogens that in their viable state are able to evade intracellular degradation in these cells.

  2. Calculation of the energy deposition in a water beam dump

    CERN Document Server

    Schönbacher, Helmut

    1975-01-01

    The energy deposition per interacting proton in GeV/cm/sup 3/ and the star density in star/cm/sup 3/ have been calculated in a water cylinder with a Monte Carlo computer program. These calculations permit the estimation of the temperature rise, induced radioactivity, etc., in beam dumps of high energy accelerator and storage rings. The calculation assumed a cylinder of different diameters and lengths and an incident proton beam energy of 20, 200, 300 and 400 GeV. (5 refs).

  3. Dumped Munitions in the Baltic Sea - Evaluation of the Problem

    Science.gov (United States)

    Beldowski, J.; Jakacki, J.; Vanninen, P.; Lang, T.

    2016-12-01

    Dumped Chemical Weapons pose an actual environmental and security hazard in the Baltic Sea Region. Their actual position is unknown, and pollution originating from corroded munitions is only roughly estimated. Several research projects were devoted to evaluate the magnitude of the problem. During three international projects, roughly 2000 km2 were surveyed, and more than 200 ROV missions were performed to investigate found objects. . Results suggest that munitions containing CWAs are more scattered on the seafloor than suspected, and previously undocumented dumpsite was discovered in Gdansk Deep. Chemical Warfare Agents (CWA) degradation products were found in the sediments in immediate vicinity of the objects, and sediment pollution was observed even at 40m distance. Analysis of CWA degradation products in the sediments showed widespread contamination in Bornholm Deep area, and more variable pattern of local hotspots in the Gotland and Gdansk Deeps. The latter seem to contain several contaminated areas, which identifies it rather as an unofficial dumping ground than only containing munitions originating from en-route dumping. Bottom currents observed in the dumpsites were strong enough for sediment re-suspension, and contributed to the transport of polluted sediments. Spreading of CWA was modelled using POP3 hydrodynamic model augmented with sediment erosion and benthic boundary layer modules. It follows from the models, that depending on wind conditions, resuspended contaminated sediemnts may remain in the water column for several days up to few weeks, and be transported over the distances up to 15 km. Biomarkers of environmental stress were measured in fish from the dumpsites and caged mussels, and indicated environmental stress in organisms from dumpsites as compared to control. Toxicity of found CWA degradation products was examined in laboratory studies. . Nonetheless, both species showed significantly elevated molecular and cellular level responses at

  4. SIMULATION OF NEUTRON BACKGROUNDS FROM THE ILC EXTRACTION LINE BEAM DUMP

    Energy Technology Data Exchange (ETDEWEB)

    Darbha, S; Keller, L.; Maruyama, T.

    2008-01-01

    The operation of the International Linear Collider (ILC) as a precision measurement machine is dependent upon the quality of the charge-coupled device (CCD) silicon vertex detector. An integrated fl ux of 1010 neutrons/cm2 incident upon the vertex detector will degrade its performance by causing displacement damage in the silicon. One source of the neutron background arises from the dumping of the spent electron and positron beams into the extraction line beam dumps. The Monte Carlo program FLUKA was used to simulate the collision of the electron beam with the dump and to determine the resulting neutron fl ux at the interaction point (IP). A collimator and tunnel were added and their effect on the fl ux was analyzed. A neutron source was then generated and directed along the extraction line towards a model of the vertex detector to determine the neutron fl ux in its silicon layers. Models of the beampipe and BeamCal, a silicon-tungsten electromagnetic calorimeter in the very forward region of the detector, were placed in the extraction line and their effects on scattering were studied. The IP fl uence was determined to be 3.7x1010 +/- 2.3x1010 neutrons/cm2/year when the tunnel and collimator were in place, with no appreciable increase in statistics when the tunnel was removed. The BeamCal was discovered to act as a collimator by signifi cantly impeding the fl ow of neutrons towards the detector. The majority of damage done to the fi rst layer of the detector was found to come from neutrons with a direct line of sight from the fi rst extraction line quadrupole QDEX1, with only a small fraction scattering off of the beampipe and into the detector. The 1 MeV equivalent neutron fl uence was determined to be 9.3x108 neutrons/cm2/year from the electron beam alone. The two beams collectively contribute double to this fl uence, which is 19% of the threshold value in one year. Future work will improve the detector model and other sources of neutron backgrounds will be

  5. Detection and quantification of protein adduction by electrophilic fatty acids: mitochondrial generation of fatty acid nitroalkene derivatives.

    Science.gov (United States)

    Schopfer, F J; Batthyany, C; Baker, P R S; Bonacci, G; Cole, M P; Rudolph, V; Groeger, A L; Rudolph, T K; Nadtochiy, S; Brookes, P S; Freeman, B A

    2009-05-01

    Nitroalkene fatty acid derivatives manifest a strong electrophilic nature, are clinically detectable, and induce multiple transcriptionally regulated anti-inflammatory responses. At present, the characterization and quantification of endogenous electrophilic lipids are compromised by their Michael addition with protein and small-molecule nucleophilic targets. Herein, we report a trans-nitroalkylation reaction of nitro-fatty acids with beta-mercaptoethanol (BME) and apply this reaction to the unbiased identification and quantification of reaction with nucleophilic targets. Trans-nitroalkylation yields are maximal at pH 7 to 8 and occur with physiological concentrations of target nucleophiles. This reaction is also amenable to sensitive mass spectrometry-based quantification of electrophilic fatty acid-protein adducts upon electrophoretic resolution of proteins. In-gel trans-nitroalkylation reactions also permit the identification of protein targets without the bias and lack of sensitivity of current proteomic approaches. Using this approach, it was observed that fatty acid nitroalkenes are rapidly metabolized in vivo by a nitroalkene reductase activity and mitochondrial beta-oxidation, yielding a variety of electrophilic and nonelectrophilic products that could be structurally characterized upon BME-based trans-nitroalkylation reaction. This strategy was applied to the detection and quantification of fatty acid nitration in mitochondria in response to oxidative inflammatory conditions induced by myocardial ischemia-reoxygenation.

  6. Biologically relevant oxidants and terminology, classification and nomenclature of oxidatively generated damage to nucleobases and 2-deoxyribose in nucleic acids

    DEFF Research Database (Denmark)

    Cadet, Jean; Loft, Steffen; Olinski, Ryszard

    2012-01-01

    A broad scientific community is involved in investigations aimed at delineating the mechanisms of formation and cellular processing of oxidatively generated damage to nucleic acids. Perhaps as a consequence of this breadth of research expertise, there are nomenclature problems for several of the ...

  7. Clavulanic acid inhibits MPP+-induced ROS generation and subsequent loss of dopaminergic cells☆

    OpenAIRE

    Kost, Gina Chun; Selvaraj, Senthil; Lee, Young Bok; Kim, Deog Joong; Ahn, Chang-Ho; Singh, Brij B

    2012-01-01

    Clavulanic acid is a psychoactive compound that has been shown to modulate central nervous system activity. Importantly, in neurotoxin-induced animal models, clavulanic acid has been shown to improve motor function (Huh et al., 2010) suggesting that it can be neuroprotective; however, the mechanism as how clavulanic acid can induce neuroprotection is not known. We demonstrate here that clavulanic acid abrogates the effects of the neurotoxin 1-methyl-4-phenylpyridinium (MPP+) which mimics Park...

  8. Hanford waste vitrification plant hydrogen generation study: Preliminary evaluation of alternatives to formic acid

    Energy Technology Data Exchange (ETDEWEB)

    King, R.B.; Bhattacharyya, N.K.; Kumar, V.

    1996-02-01

    Oxalic, glyoxylic, glycolic, malonic, pyruvic, lactic, levulinic, and citric acids as well as glycine have been evaluated as possible substitutes for formic acid in the preparation of feed for the Hanford waste vitrification plant using a non-radioactive feed stimulant UGA-12M1 containing substantial amounts of aluminum and iron oxides as well as nitrate and nitrite at 90C in the presence of hydrated rhodium trichloride. Unlike formic acid none of these carboxylic acids liberate hydrogen under these conditions and only malonic and citric acids form ammonia. Glyoxylic, glycolic, malonic, pyruvic, lactic, levulinic, and citric acids all appear to have significant reducing properties under the reaction conditions of interest as indicated by the observation of appreciable amounts of N{sub 2}O as a reduction product of,nitrite or, less likely, nitrate at 90C. Glyoxylic, pyruvic, and malonic acids all appear to be unstable towards decarboxylation at 90C in the presence of Al(OH){sub 3}. Among the carboxylic acids investigated in this study the {alpha}-hydroxycarboxylic acids glycolic and lactic acids appear to be the most interesting potential substitutes for formic acid in the feed preparation for the vitrification plant because of their failure to produce hydrogen or ammonia or to undergo decarboxylation under the reaction conditions although they exhibit some reducing properties in feed stimulant experiments.

  9. A novel glutathione-hydroxycinnamic acid product generated in oxidative wine conditions.

    Science.gov (United States)

    Bouzanquet, Quentin; Barril, Celia; Clark, Andrew C; Dias, Daniel A; Scollary, Geoffrey R

    2012-12-12

    This study characterizes a novel glutathione-substituted dihydroxyphenyl compound formed during the oxidation of white wine and model wine solutions, which may contribute to the synergistic role of glutathione and hydroxycinnamic acids in delaying oxidative coloration. The critical components for the formation of the compound were found to be hydroxycinnamic acids and glutathione, while ascorbic acid enabled the product to accumulate to higher concentrations. The presence of the wine components important in other wine oxidation mechanisms, (+)-catechin, ethanol and/or tartaric acid, was not essential for the formation of this new compound. Via LC-MS/MS, HR-MS and (1)H NMR (1D and 2D NMR) analyses, the major isomer of the compound formed from glutathione and caffeic acid was found to be 4-[(E)-2'-(S)-glutathionyl ethenyl]-catechol (GEC). Equivalent products were also confirmed via LC-MS/MS for other hydroxycinnamic acids (i.e., ferulic and coumaric acids). Only trace amounts of GEC were formed with the quinic ester of caffeic acid (i.e., chlorogenic acid), and no equivalent product was found for cinnamic acid. GEC was detected in a variety of white wines supplemented with glutathione and caffeic acid. A radical mechanism for the formation of the styrene-glutathione derivatives is proposed.

  10. 19 CFR 159.58 - Dumping and countervailing duties; action by port director.

    Science.gov (United States)

    2010-04-01

    ... 19 Customs Duties 2 2010-04-01 2010-04-01 false Dumping and countervailing duties; action by port director. 159.58 Section 159.58 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF HOMELAND... Dumping and countervailing duties; action by port director. (a) Antidumping matters. Upon receipt...

  11. Regularities of restoration of plant cover on the dumps of the Kuznetsk Basin

    Directory of Open Access Journals (Sweden)

    A. N. Kupriyanov

    2016-04-01

    Full Text Available The article considers the issues of the restoration vegetation on the dumps of the coal enterprises of the Kuznetsk Basin. Studies have shown that the dumps have a wide range of environmental conditions and are potentially suitable for establishment of plants. To negative environmental factors at the mine dumps include the lack of productive moisture, failed penetration, contrasting temperature regime on the different elements of the relief, and low potential fertility of the embryonic soils. Positive – high humidity in the depressions, the high content of fine-grained deposits in the lower part of the elephant dumps, excessive accumulation of snow in the winter on separate dumping sites. On disturbed lands identified eight technogenic ecotopes, characterized by various microrelief, moisture level, amount of fine fractions of technogenic eluvium determining favorable, moderately favorable and unfavorable conditions for vegetation of disturbed land. Selected three stages of syngenesis: pioneer stage, simple plant communities and complex plant communities. The stage of zonal phytocenosis on the dumps was not detected. The basis of diagnostic signs consists of the projective cover, the nature of the host plants, the number of species part of the zonal species. The selected criteria are universal and can be applicable to most dumps. Speed of syngenetic succession does not depend on calendar age of the dumps, and environmental conditions, which are formed on separate sites.

  12. Københavns Kommunes indsats mod social dumping - målopfyldelsesevaluering

    DEFF Research Database (Denmark)

    Jørgensen, Henning; Baadsgaard, Kelvin

    2017-01-01

    Evaluering af indsatsen i Københavns Kommune for at imødegå social dumping ved hjælp af målopfyldelses-model......Evaluering af indsatsen i Københavns Kommune for at imødegå social dumping ved hjælp af målopfyldelses-model...

  13. Anti-Dumping with Heterogeneous Firms: New Protectionism for the New-New Trade Theory

    DEFF Research Database (Denmark)

    Schmidt, Christian Gormsen

    This paper analyzes anti­-dumping (AD) policies in a two-country model with heterogeneous firms in monopolistic competition. Effective AD legislation in one country imposes a no-dumping condition on firms exporting from the other country, altering their pricing both domestically and abroad. Some...

  14. 77 FR 61818 - WTO Dispute Settlement Proceeding Regarding United States-Anti-Dumping and Countervailing Duties...

    Science.gov (United States)

    2012-10-11

    ... From the Federal Register Online via the Government Publishing Office ] OFFICE OF THE UNITED STATES TRADE REPRESENTATIVE WTO Dispute Settlement Proceeding Regarding United States--Anti- Dumping and...-dumping and countervailing duties on certain automobiles from the United States. That request may be...

  15. 75 FR 33747 - Ocean Dumping; Correction of Typographical Error in 2006 Federal Register Final Rule for...

    Science.gov (United States)

    2010-06-15

    ... From the Federal Register Online via the Government Publishing Office ENVIRONMENTAL PROTECTION AGENCY 40 CFR Part 228 Ocean Dumping; Correction of Typographical Error in 2006 Federal Register Final... Final Rule for the Ocean Dumping; De-designation of Ocean Dredged Material Disposal Site and...

  16. Octreotide improves early dumping syndrome potentially through incretins: a case report.

    Science.gov (United States)

    Sato, Daisuke; Morino, Katsutaro; Ohashi, Natsuko; Ueda, Emi; Ikeda, Kazuhiro; Yamamoto, Hideka; Ugi, Satoshi; Yamamoto, Hiroshi; Araki, Shinichi; Maegawa, Hiroshi

    2013-01-01

    Dumping syndrome, or rapid gastric emptying, is a frequent complication after gastric surgery. In this case, the patient was a 47-year-old woman who 10 years previously had undergone distal gastrectomy with Billroth I reconstruction for early-stage gastric cancer. She presented with symptoms of weakness, headache, palpitation, sweating, dizziness and significant fatigue between one and two hours after a meal. Because a 75 g oral glucose tolerance test (75 g-OGTT) induced both acute postprandial tachycardia (within 1 hour) and postprandial hypoglycemia, we diagnosed this patient with early and late dumping syndrome. Dietary measures and acarbose improved symptoms of late dumping syndrome but did not prevent the symptoms of early dumping syndrome such as postprandial tachycardia, weakness, headache, palpitation, and dizziness. We therefore used the somatostatin analogue octreotide, which has been reported as an effective therapy for early dumping syndrome. Octreotide prevented the symptoms of early dumping syndrome, especially postprandial tachycardia, but caused postprandial hyperglycemia. Glucagon-like peptide-1 (GLP-1) and glucose-dependent insulinotropic polypeptide (GIP) were completely suppressed during the 75 g-OGTT following subcutaneous injection of octreotide. No change was observed in vasoactive intestinal polypeptide (VIP), which is the gastrointestinal peptide hormone generally responsible for early dumping syndrome, suggesting possible contribution of incretins in early dumping syndrome of this patient.

  17. Stability analysis and treatment of No.2 dump of Nanfen iron mine

    Institute of Scientific and Technical Information of China (English)

    Yan XU; Lei NIE; Huangping DING; Yin WANG; Jian LIU; Wei LU; Zhenying ZHANG; Xue GONG; Shiwei SHEN

    2006-01-01

    On the basis of the study on the engineering geological characteristics of No.2 dump of Nanfen iron mine and the analysis of the failure mode of dump landslide, the stability of the present dump, the stability of the dump 20 years later and the stability of double-bench dump are analyzed. Then, the debris flow risk is evaluated by fuzzy mathematics method. Finally, the comprehensive treatment for the dump is suggested. It is concluded that ① In rainy and snowmelt period, the stability would be decreasing sharply when ground water is not drained out in time; ② Double-bench dumping mode will improve stability of the dump little; ③ Debris flow risk is middle danger. The interim debris flow with medium scale may occur. ④ Monitoring, draining and baffling work ought to be well done. ⑤ In order to prevent the damage of landslide and debris flow, three measures are adopted, including setting rockfall net, setting the debris flow barrier and removing the residents.

  18. Solution of the capacity increase of the waste dump at the Merkur surface mine in Czechoslovakia

    Energy Technology Data Exchange (ETDEWEB)

    Musil, P.

    1987-06-01

    The methods used in the past for backfilling the large dump at the Merkur surface mine have, due to an ignorance of the factors influencing dump stability, resulted in significant capacity reductions of the dump. This ignorance was the result of insufficient knowledge, research, and poor practice at the operation. Recent re-evaluation of the actual stability conditions has led to a solution which permits an increase in the dump capacity, such that it is compatible with future mining plans. By considering the structure of the soils being used as backfill, specific technological processes are being defined which enable the preservation of the highest possible shear strength of the clayey soils, and thereby maximize the utilization of the internal capacity with at least short term stability. Questions regarding the behaviour and properties of the loose clayey material are also being answered, and new methods of stability calculation for the high dump are being developed. The key to these solutions has been the knowledge gained regarding the shear strength of the loose clayey material under various effective stress conditions, while realizing that three different zones can exist simultaneously within the body of the dump: the slope areas (having the greatest failure-inducing stress), the temporary areas (having a somewhat lower applied stress), and the dump core (where the tendency to fail is nearly zero). Through a sound application of this knowledge, the capacity of the waste dump at the large Merkur surface mine has been adequately expanded for the future.

  19. Radiation monitoring and beam dump system of the OPAL silicon microvertex detector

    CERN Document Server

    Braibant, S

    1997-01-01

    The OPAL microvertex silicon detector radiation monitoring and beam dump system is described. This system was designed and implemented in order to measure the radiation dose received at every beam crossing and to induce a fast beam dump if the radiation dose exceeds a given threshold.

  20. Joint Norwegian-Russian mission to investigate dumped atomic waste in the Kara Sea

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-11-01

    In autumn 2012, a joint Norwegian-Russian mission will visit areas in the Kara Sea where spent nuclear fuel and radioactive waste have been dumped. The purpose of the mission is to obtain new, up-to-date information about radioactive pollution in these areas and about the condition of the dumped items (Author)

  1. Soil contamination by brominated flame retardants in open waste dumping sites in Asian developing countries.

    Science.gov (United States)

    Eguchi, Akifimi; Isobe, Tomohiko; Ramu, Karri; Tue, Nguyen Minh; Sudaryanto, Agus; Devanathan, Gnanasekaran; Viet, Pham Hung; Tana, Rouch Seang; Takahashi, Shin; Subramanian, Annamalai; Tanabe, Shinsuke

    2013-03-01

    In Asian developing countries, large amounts of municipal wastes are dumped into open dumping sites each day without adequate management. This practice may cause several adverse environmental consequences and increase health risks to local communities. These dumping sites are contaminated with many chemicals including brominated flame retardants (BFRs) such as polybrominated diphenyl ethers (PBDEs) and hexabromocyclododecanes (HBCDs). BFRs may be released into the environment through production processes and through the disposal of plastics and electronic wastes that contain them. The purpose of this study was to elucidate the status of BFR pollution in municipal waste dumping sites in Asian developing countries. Soil samples were collected from six open waste dumping sites and five reference sites in Cambodia, India, Indonesia, Malaysia, and Vietnam from 1999 to 2007. The results suggest that PBDEs are the dominant contaminants in the dumping sites in Asian developing countries, whereas HBCD contamination remains low. Concentrations of PBDEs and HBCDs ranged from ND to 180 μg/kg dry wt and ND to 1.4 μg/kg dry wt, respectively, in the reference sites and from 0.20 to 430 μg/kg dry wt and ND to 2.5 μg/kg dry wt, respectively, in the dumping sites. Contamination levels of PBDEs in Asian municipal dumping sites were comparable with those reported from electronic waste dismantling areas in Pearl River delta, China.

  2. Experimental Study of Preferential Solute Transportation During Dump Leaching

    Institute of Scientific and Technical Information of China (English)

    YIN Sheng-hua; WU Ai-xiang

    2006-01-01

    The production of dump leaching of the Dexing Copper Mine was affected by a preferential solution flow. Formative mechanism of the preferential solution flow was investigated by analyzing the relationship between both dump permeability and surface tension and ore diameter. The preferential solution flow occurred in the fine ore area when the application rate was low. The preferential solution flow entered into the coarse ore area because the negative pore water pressure disappeared with an increase of the application rate. The preferential solute transportation experiment was conducted by selecting NaCl as mineral. Results of the experiment showed that the concentration of the outflow solution reduced over time. The concentration of the coarse ore area outflow solution was greater than that of the fine ore area. The process of NaCl leaching can be divided into two stages. NaCl was carried out directly by diffusion-convection during the first stage, so the leaching rate increased sharply. But in the second stage, only a small amount of NaCl dissolved in the immobile water. The leaching rate increased slowly because NaCl, dissolved in the immobile water, can only be leached by diffusion.

  3. Sequential extraction of inorganic mercury in dumped blast furnace sludge.

    Science.gov (United States)

    Földi, Corinna; Andrée, Corlin-Anna; Mansfeldt, Tim

    2015-10-01

    Blast furnace sludge (BFS) is an industrial waste with elevated mercury (Hg) contents due to the enrichment during the production process of pig iron. To investigate the potential pollution status of dumped BFS, 14 samples with total Hg contents ranging from 3.91 to 20.8 mg kg(-1) from five different locations in Europe were sequentially extracted. Extracts used included demineralized water (fraction 1, F1), 0.1 mol L(-1) CH3COOH + 0.01 mol L(-1) HCl (F2), 1 mol L(-1) KOH (F3), 7.9 mol L(-1) HNO3 (F4), and aqua regia (F5). The total recovery ranged from 72.3 to 114 %, indicating that the procedure was reliable when adapted to this industrial waste. Mercury mainly resided in the fraction of "elemental" Hg (48.5-98.8 %) rather being present as slightly soluble Hg species associated with sludge particles. Minor amounts were found as mercuric sulfide (F5; 0.725-37.3 %) and Hg in crystalline metal ores and silicates (F6; 2.21-15.1 %). The ecotoxically relevant fractions (F1 and F2) were not of significance (F1, dumped for many years has a rather low environmental risk potential regarding Hg.

  4. Municipal solid waste open dumping, implication for land degradation

    Science.gov (United States)

    Yazdani, M.; Monavari, M.; Omrani, G. A.; Shariat, M.; Hosseini, M.

    2015-03-01

    Open dumping is the common procedure for final disposal of MSW in Iran. Several environmental pollutions and land degradation have caused because of poor planning, insufficient financial resources, improper organizational chart for MSW management system, and the lack of rules, guidelines and regulations. In Iran standards and regulations of environmental issues are not perfectly attended, evaluation an open dumping can show existing restrictions and troubles in these areas. So recognition of the municipal solid waste landfill state is required to prevent the increase of environmental problems and decrease the negative environmental impacts. The suitability of Tonekabon existing municipal landfill site in the west area of Mazandaran province, located in north of Iran, and the south coast of the Caspian Sea is the significance of the present study as a case study of land degradation. In order to carry out this evaluation, two guidelines are used. After reviewing all the considered criteria in each of the guidelines, the authenticity of the deposit site of the study area and also the entire city was examined; and eventually the appropriate areas were identified. The conclusion of the results indicated the incoherence in appropriateness of the existing landfill site, with two mentioned methods and field work.

  5. ASPECTS OF REHABILITATION OF WASTE DUMPS USING HERBACEOUS PLANTS

    Directory of Open Access Journals (Sweden)

    Smaranda Masu

    2015-05-01

    Full Text Available There are many arguments that underlie research on rehabilitation of large areas of land that were set aside from the agricultural circuit and became heaps of storage for inert waste materials like bottom and boiler slag and fly ash. On the other hand result of biological materials with potential for land recycling i.e. sewage sludge. On the dumps of boiler slag composed of particles of 2-3 mm was gradually installed a layer of grass with the help of sewage sludge as a fertilizing agent and microbial activity stimulating agent, based on an extract of brown seaweed EKO GEA Slovenia. In the second year the amount of biomass harvested was 2 to 2.9 times higher than in the first year of cultivation. Moreover plants not harvested in the second year of culture bore fruit. Also, the root network strongly stabilized the slag and boiler ash particles against land spreading. Rapid and effective rehabilitation of the landscape destroyed was achieved with the use of herbaceous crops of the species Lolium perenne. Monitoring bioaccumulation of heavy metals i.e. Cd, Cr, Cu, Ni, Pb, Ni, Zn, etc. in aerial plant tissue was needed to decide the sector where the biomass harvested from inert waste dump covered with vegetation.

  6. Generation of Internal-Image Functional Aptamers of Okadaic Acid via Magnetic-Bead SELEX

    Directory of Open Access Journals (Sweden)

    Chao Lin

    2015-12-01

    Full Text Available Okadaic acid (OA is produced by Dinophysis and Prorocentrum dinoflagellates and primarily accumulates in bivalves, and this toxin has harmful effects on consumers and operators. In this work, we first report the use of aptamers as novel non-toxic probes capable of binding to a monoclonal antibody against OA (OA-mAb. Aptamers that mimic the OA toxin with high affinity and selectivity were generated by the magnetic bead-assisted systematic evolution of ligands by exponential enrichment (SELEX strategy. After 12 selection rounds, cloning, sequencing and enzyme-linked immunosorbent assay (ELISA analysis, four candidate aptamers (O24, O31, O39, O40 were selected that showed high affinity and specificity for OA-mAb. The affinity constants of O24, O31, O39 and O40 were 8.3 × 108 M−1, 1.47 × 109 M−1, 1.23 × 109 M−1 and 1.05 × 109 M−1, respectively. Indirect competitive ELISA was employed to determine the internal-image function of the aptamers. The results reveal that O31 has a similar competitive function as free OA toxin, whereas the other three aptamers did not bear the necessary internal-image function. Based on the derivation of the curvilinear equation for OA/O31, the equation that defined the relationship between the OA toxin content and O31 was Y = 2.185X − 1.78. The IC50 of O31 was 3.39 ng·mL−1, which was close to the value predicted by the OA ELISA (IC50 = 4.4 ng·mL−1; the IC10 was 0.33 ng·mL−1. The above data provides strong evidence that internal-image functional aptamers could be applicable as novel probes in a non-toxic assay.

  7. Generation of Internal-Image Functional Aptamers of Okadaic Acid via Magnetic-Bead SELEX.

    Science.gov (United States)

    Lin, Chao; Liu, Zeng-Shan; Wang, Dong-Xu; Li, Lin; Hu, Pan; Gong, Sheng; Li, Yan-Song; Cui, Cheng; Wu, Zong-Cheng; Gao, Yang; Zhou, Yu; Ren, Hong-Lin; Lu, Shi-Ying

    2015-12-17

    Okadaic acid (OA) is produced by Dinophysis and Prorocentrum dinoflagellates and primarily accumulates in bivalves, and this toxin has harmful effects on consumers and operators. In this work, we first report the use of aptamers as novel non-toxic probes capable of binding to a monoclonal antibody against OA (OA-mAb). Aptamers that mimic the OA toxin with high affinity and selectivity were generated by the magnetic bead-assisted systematic evolution of ligands by exponential enrichment (SELEX) strategy. After 12 selection rounds, cloning, sequencing and enzyme-linked immunosorbent assay (ELISA) analysis, four candidate aptamers (O24, O31, O39, O40) were selected that showed high affinity and specificity for OA-mAb. The affinity constants of O24, O31, O39 and O40 were 8.3 × 10⁸ M(-1), 1.47 × 10⁸ M(-1), 1.23 × 10⁸ M(-1) and 1.05 × 10⁸ M(-1), respectively. Indirect competitive ELISA was employed to determine the internal-image function of the aptamers. The results reveal that O31 has a similar competitive function as free OA toxin, whereas the other three aptamers did not bear the necessary internal-image function. Based on the derivation of the curvilinear equation for OA/O31, the equation that defined the relationship between the OA toxin content and O31 was Y = 2.185X - 1.78. The IC50 of O31 was 3.39 ng·mL(-1), which was close to the value predicted by the OA ELISA (IC50 = 4.4 ng·mL(-1)); the IC10 was 0.33 ng·mL(-1). The above data provides strong evidence that internal-image functional aptamers could be applicable as novel probes in a non-toxic assay.

  8. Cryptic female choice via sperm dumping favours male copulatory courtship in a spider.

    Science.gov (United States)

    Peretti, A V; Eberhard, W G

    2010-02-01

    Males of many animals perform 'copulatory courtship' during copulation, but the possible reproductive significance of this behaviour has seldom been investigated. In some animals, including the spider Physocyclus globosus (Pholcidae), the female discards sperm during or immediately following some copulations. In this study, we determined which of several variables associated with copulation correlated with paternity success in P. globosus when two males mate with a single female. Then, by determining which of these variables also correlated with sperm dumping, we inferred which variables may affect paternity via the mechanism of sperm dumping. Male abdomen vibration (a copulatory courtship behaviour) and male genitalic squeezing both correlated with both paternity and sperm dumping; so, these traits may be favoured by biased sperm dumping. Biased sperm dumping may also be the mechanism by which possible cryptic female choice favours another male trait that was the subject of a previous study, responsiveness to female stridulation.

  9. Treatment with acarbose in severe hypoglycaemia due to late dumping syndrome.

    Science.gov (United States)

    Wang, Congcong; Pang, Shuguang; Jiang, Qiang; Duan, Guanglan; Sun, Yongmei; Li, Mei

    2013-12-01

    Dumping syndrome is a serious complication that may occur after gastric surgery in approximately 10% of patients in the 1990s. With the increasing number of patients undergoing bariatric surgery, the incidence of dumping syndrome is likely to increase in recent years. It is necessary for clinicians to recognize the syndrome and master its management. We present a case of recurrent loss of consciousness, which was finally accurately diagnosed as late dumping syndrome twelve years after subtotal gastrectomy and successfully treated with acarbose. A 66-year old lean male was found unconscious repeatedly within one year, oral glucose tolerance tests performed before and after acarbose treatment verified the diagnosis of late dumping syndrome. Hypoglycaemia can damage the body in acute and chronic form. Acarbose can be used as a successful treatment modality for reactive hypoglycaemia due to late dumping syndrome by influencing the release of hormone.

  10. Patient dumping, outlier payments, and optimal healthcare payment policy under asymmetric information.

    Science.gov (United States)

    Takahara, Tsuyoshi

    2016-12-01

    We analyze a rationale for official authorization of patient dumping in the prospective payment policy framework. We show that when the insurer designs the healthcare payment policy to let hospitals dump high-cost patients, there is a trade-off between the disutility of dumped patients (changes in hospitals' rent extraction due to low-severity patients) and the shift in the level of cost reduction efforts for high-severity patients. We also clarify the welfare-improving conditions by allowing hospitals to dump high-severity patients. Finally, we show that if the efficiency of the cost reduction efforts varies extensively and the healthcare payment cost is substantial, or if there are many private hospitals, the patient dumping policy can improve social welfare in a wider environment.

  11. Analysis of underground and surface waters of the dump of the solid communal waste

    Directory of Open Access Journals (Sweden)

    Almášová Kristína

    1997-06-01

    Full Text Available The paper deals with the contamination of underground and surface waters in the surroundings of the dump of the solid communal waste at the locality Cemjata in the East Slovakia,as well as with the development of the contamination in the surrounding of the dump depending on the time on the basis of the analysisof samples withdrawn from the net of drillholes in the observed area. In the area investigated there is described geological, geomorphological, climatic and hydrogeological situation, as well as the dump itself. The results acquired show that the contamination of the area brought about by medium size industrial and agricultural activity in the vicinity of the dump of the solid communal waste and inside the area investigated is comparable with the dangerous effects of the dump of the solid communal waste.

  12. Design of Air-Cooled Beam Dump for Extraction Line of PS Booster

    CERN Document Server

    Perillo-Marcone, A; Venturi, V; Antonakakis, T; Vlachoudis, V; Nowak, E; Mason, G; Battistin, M; Czapski, M; Sgobba, S

    2013-01-01

    A new beam dump has been designed, which withstands the future proton beam extracted from the Proton Syncrotron Booster (PSB) at CERN, consisting of up to 1E14 protons per pulse at 2 GeV after its upgrade in 2018/2019. In order to be able to efficiently release the deposited heat, the new dump will be made out of a single cylindrical block of a copper alloy and cooled by forced ventilation. In order to determine the energy density distribution deposited by the beam in the dump, Monte Carlo simulations were performed using FLUKA, and thermomechanical analyses carried out by importing the energy density into Ansys. In addition, CFD simulations of the airflow were carried out in order to accurately estimate the heat transfer convection coefficient on the surface of the dump. This paper describes the design process and highlights the constraints of integrating a new dump for increased beam power into the existing facility.

  13. Anode modification with formic acid: A simple and effective method to improve the power generation of microbial fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Weifeng; Cheng, Shaoan, E-mail: shaoancheng@zju.edu.cn; Guo, Jian

    2014-11-30

    Highlights: • Carbon cloth anode is modified with formic acid by a simple and reliable approach. • The modification significantly enhances the power output of microbial fuel cells. • The modified anode surface favors the bacterial attachment and growth on anode. • The electron transfer rate of anode is promoted. - Abstract: The physicochemical properties of anode material directly affect the anodic biofilm formation and electron transfer, thus are critical for the power generation of microbial fuel cells (MFCs). In this work, carbon cloth anode was modified with formic acid to enhance the power production of MFCs. Formic acid modification of anode increased the maximum power density of a single-chamber air-cathode MFC by 38.1% (from 611.5 ± 6 mW/m{sup 2} to 877.9 ± 5 mW/m{sup 2}). The modification generated a cleaner electrode surface and a reduced content of oxygen and nitrogen groups on the anode. The surface changes facilitated bacterial growth on the anode and resulted in an optimized microbial community. Thus, the electron transfer rate on the modified anodes was enhanced remarkably, contributing to a higher power output of MFCs. Anode modification with formic acid could be an effective and simple method for improving the power generation of MFCs. The modification method holds a huge potential for large scale applications and is valuable for the scale-up and commercialization of microbial fuel cells.

  14. 19 CFR 351.106 - De minimis net countervailable subsidies and weighted-average dumping margins disregarded.

    Science.gov (United States)

    2010-04-01

    ... weighted-average dumping margins disregarded. 351.106 Section 351.106 Customs Duties INTERNATIONAL TRADE... minimis net countervailable subsidies and weighted-average dumping margins disregarded. (a) Introduction... practice of disregarding net countervailable subsidies or weighted-average dumping margins that were...

  15. 75 FR 20670 - WTO Dispute Settlement Proceeding Regarding United States-Use of Zeroing in Anti-Dumping Measures...

    Science.gov (United States)

    2010-04-20

    ...-Dumping Measures Involving Products From Korea AGENCY: Office of the United States Trade Representative.... Department of Commerce (``Commerce'') of what Korea describes as ``the practice of `zeroing' negative dumping margins in calculating overall weighted average margins of dumping'' in the final and amended...

  16. 75 FR 22524 - Ocean Dumping; Designation of Ocean Dredged Material Disposal Sites Offshore of the Siuslaw River...

    Science.gov (United States)

    2010-04-29

    ... AGENCY 40 CFR Part 228 Ocean Dumping; Designation of Ocean Dredged Material Disposal Sites Offshore of... according to the ocean dumping regulations at 40 CFR 227.13 and guidance developed by EPA and the Corps. In... acceptable for ocean dumping without further testing. Dredged material which does not meet the criteria of...

  17. 76 FR 12400 - WTO Dispute Settlement Proceeding Regarding China-Countervailing and Anti-Dumping Duties on Grain...

    Science.gov (United States)

    2011-03-07

    ... TRADE REPRESENTATIVE WTO Dispute Settlement Proceeding Regarding China--Countervailing and Anti-Dumping... countervailing and anti-dumping duties on Grain Oriented Flat-rolled Electrical Steel (``GOES'') from the United... measures imposing countervailing duties and anti-dumping duties on GOES from the United States...

  18. 75 FR 5708 - Ocean Dumping; Designation of Ocean Dredged Material Disposal Sites Offshore of the Siuslaw River...

    Science.gov (United States)

    2010-02-04

    ... AGENCY 40 CFR Part 228 Ocean Dumping; Designation of Ocean Dredged Material Disposal Sites Offshore of... any person, EPA and the Corps must evaluate the project according to the ocean dumping regulatory criteria (40 CFR part 227) and authorize disposal. EPA independently evaluates proposed dumping and has...

  19. 40 CFR 256.26 - Requirement for schedules leading to compliance with the prohibition of open dumping.

    Science.gov (United States)

    2010-07-01

    ... compliance with the prohibition of open dumping. 256.26 Section 256.26 Protection of Environment... compliance with the prohibition of open dumping. In implementing the section 4005(c) prohibition on open dumping, the State plan shall provide that any entity which demonstrates that it has considered...

  20. Enzymatic transamination of D-kynurenine generates kynurenic acid in rat and human brain.

    Science.gov (United States)

    Pérez-de la Cruz, Veronica; Amori, Laura; Sathyasaikumar, Korrapati V; Wang, Xiao-Dan; Notarangelo, Francesca M; Wu, Hui-Qiu; Schwarcz, Robert

    2012-03-01

    In the mammalian brain, the α7 nicotinic and NMDA receptor antagonist kynurenic acid is synthesized by irreversible enzymatic transamination of the tryptophan metabolite l-kynurenine. d-kynurenine, too, serves as a bioprecursor of kynurenic acid in several organs including the brain, but the conversion is reportedly catalyzed through oxidative deamination by d-amino acid oxidase. Using brain and liver tissue homogenates from rats and humans, and conventional incubation conditions for kynurenine aminotransferases, we show here that kynurenic acid production from d-kynurenine, like the more efficient kynurenic acid synthesis from l-kynurenine, is blocked by the aminotransferase inhibitor amino-oxyacetic acid. In vivo, focal application of 100 μM d-kynurenine by reverse microdialysis led to a steady rise in extracellular kynurenic acid in the rat striatum, causing a 4-fold elevation after 2 h. Attesting to functional significance, this increase was accompanied by a 36% reduction in extracellular dopamine. Both of these effects were duplicated by perfusion of 2 μM l-kynurenine. Co-infusion of amino-oxyacetic acid (2 mM) significantly attenuated the in vivo effects of d-kynurenine and essentially eliminated the effects of l-kynurenine. Thus, enzymatic transamination accounts in part for kynurenic acid synthesis from d-kynurenine in the brain. These results are discussed with regard to implications for brain physiology and pathology.

  1. Generation of fad2 transgenic mice that produce omega-6 fatty acids

    Institute of Scientific and Technical Information of China (English)

    CHEN Qing; LIU Qing; WU ZhiFang; WANG ZongYi; GOU KeMian

    2009-01-01

    Fatty acid desaturase-2 (FAD2)introduces a double bond in position △12 in oleic acid (18:1)to form linoleic acid (18:2 n-6)in higher plants and microbes.A new transgenic expression cassette,containing CMV promoter/fad2 cDNA/SV40 polyA,was constructedto produce transgenic mice.Among 63 healthy offspring,10 founders (15.9%)integrated the cotton fad2 transgene into their genomes,as demonstrated by PCR and Southern blotting analysis.All founder mice were fertile and heterozygous fad2 female and nontransgenic littermates were used for fatty acid analysis using gas chromatography.One fad2 transgenic line showed substantial differences in the fatty acid profiles and the level of linoleic acid was increased 19% (P<0.05)in transgenic muscles compared to their nontransgenic littermates.Moreover,it exhibited an 87% and a 9% increase (P<0.05)in arachidonic acid (20:4 n-6)in muscles and liver,compared to their nontransgenic littermates.The results indicate that the plant fad2 gene can be functionally expressed in transgenic mice and may playan active role in conversion of oleic acid into linoleic acid.

  2. Generation of fad2 transgenic mice that produce omega-6 fatty acids

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Fatty acid desaturase-2 (FAD2) introduces a double bond in position 12 in oleic acid (18:1) to form linoleic acid (18:2 n-6) in higher plants and microbes. A new transgenic expression cassette, containing CMV promoter/fad2 cDNA/SV40 polyA, was constructedto produce transgenic mice. Among 63 healthy offspring, 10 founders (15.9%) integrated the cotton fad2 transgene into their genomes, as demonstrated by PCR and Southern blotting analysis. All founder mice were fertile and heterozygous fad2 female and nontransgenic littermates were used for fatty acid analysis using gas chromatography. One fad2 transgenic line showed substantial differences in the fatty acid profiles and the level of linoleic acid was increased 19% (P<0.05) in transgenic muscles compared to their nontransgenic littermates. Moreover, it exhibited an 87% and a 9% increase (P<0.05) in arachidonic acid (20:4 n-6) in muscles and liver, compared to their nontransgenic littermates. The results indicate that the plant fad2 gene can be functionally expressed in transgenic mice and may playan active role in conversion of oleic acid into linoleic acid.

  3. Clavulanic acid inhibits MPP+-induced ROS generation and subsequent loss of dopaminergic cells☆

    Science.gov (United States)

    Kost, Gina Chun; Selvaraj, Senthil; Lee, Young Bok; Kim, Deog Joong; Ahn, Chang-Ho; Singh, Brij B.

    2013-01-01

    Clavulanic acid is a psychoactive compound that has been shown to modulate central nervous system activity. Importantly, in neurotoxin-induced animal models, clavulanic acid has been shown to improve motor function (Huh et al., 2010) suggesting that it can be neuroprotective; however, the mechanism as how clavulanic acid can induce neuroprotection is not known. We demonstrate here that clavulanic acid abrogates the effects of the neurotoxin 1-methyl-4-phenylpyridinium (MPP+) which mimics Parkinson’s disease (PD) by inducing neurodegeneration. To further establish the mechanism we identified that clavulanic acid inhibits neurotoxin-induced loss of mitochondrial membrane potential and ROS production. Consistent with these results, neurotoxin-induced increase in Bax levels was also decreased in clavulanic acid treated cells. Importantly, neurotoxin-induced release of cytochrome c levels as well as caspase activation was also inhibited in clavulanic acid treated cells. In addition, Bcl-xl levels were also restored and the Bcl-xl/Bax ratio that is critical for inducing apoptosis was increased in clavulanic acid treated cells. Overall, these results suggest that clavulanic acid is intimately involved in inhibiting neurotoxin-induced loss of mitochondrial function and induction of apoptosis that contributes towards neuronal survival. PMID:22750587

  4. Clavulanic acid inhibits MPP⁺-induced ROS generation and subsequent loss of dopaminergic cells.

    Science.gov (United States)

    Kost, Gina Chun; Selvaraj, Senthil; Lee, Young Bok; Kim, Deog Joong; Ahn, Chang-Ho; Singh, Brij B

    2012-08-21

    Clavulanic acid is a psychoactive compound that has been shown to modulate central nervous system activity. Importantly, in neurotoxin-induced animal models, clavulanic acid has been shown to improve motor function (Huh et al., 2010) suggesting that it can be neuroprotective; however, the mechanism as how clavulanic acid can induce neuroprotection is not known. We demonstrate here that clavulanic acid abrogates the effects of the neurotoxin 1-methyl-4-phenylpyridinium (MPP(+)) which mimics Parkinson's disease (PD) by inducing neurodegeneration. To further establish the mechanism we identified that clavulanic acid inhibits neurotoxin-induced loss of mitochondrial membrane potential and ROS production. Consistent with these results, neurotoxin-induced increase in Bax levels was also decreased in clavulanic acid treated cells. Importantly, neurotoxin-induced release of cytochrome c levels as well as caspase activation was also inhibited in clavulanic acid treated cells. In addition, Bcl-xl levels were also restored and the Bcl-xl/Bax ratio that is critical for inducing apoptosis was increased in clavulanic acid treated cells. Overall, these results suggest that clavulanic acid is intimately involved in inhibiting neurotoxin-induced loss of mitochondrial function and induction of apoptosis that contributes towards neuronal survival.

  5. SUBJOULE DIODE-PUMPED YTTERBIUM-ERBIUM GLASS LASER WITH CAVITY DUMPING FOR CATARACT EXTRACTION

    Directory of Open Access Journals (Sweden)

    A. V. Belikov

    2015-11-01

    Full Text Available Subject of Study. The paper discusses the breadboarding results of compact diode pumped laser. The laser is based on Yb,Er:glass slab active element and frustrated total internal reflection (FTIR shutter and features of the impact of generated pulses at the water-containing media. The transmitter working in cavity dumping mode provides generation of single microsecond pulses or regular trains of these pulses with peak power up to 100 kW and average output power up to 8 W. The laser allows varying output parameters of radiation in wide range and is designed for the usage in technology and biomedical applications. The possibilities of the laser radiation parameters adapting for application in a compact laser cataract extraction complex are examined. Method. The energy efficient for three level active medium method of lasing pulses repetition rate increasing was investigated, which comprises the generation of pulse trains by several FTIR shutter switching on one pump pulse. We carried out analysis of application possibility for microsecond laser pulses with peak power of tens of kilowatts at wavelength of 1,54 μm in the processing of water-containing tissues. The acoustic response on the interaction of radiation with a model environment was studied. Main Results. In the modulation mode of useful (active losses lasing pulses have been obtained with microsecond duration and energy more than 100 mJ and trains of pulses with total energy of 0,5 J at the effective pulse repetition rate of more than 50 Hz. The minimal permissible period of laser pulses in train (300 μs has been established experimentally on the basis of optoacoustic studies. It meets the criteria of operation noninvasiveness consisting in prevention of the risk of posterior lens capsule damage with laser radiation. Practical Relevance. The results obtained with the layout of diode pumped Yb,Er:glass laser with cavity dumping and slab active element are presently record for diode

  6. Synthesis and Acid-generation Efficiency of Sulfonium Photoacid Generators%硫鎓盐产酸剂的合成及其产酸效率

    Institute of Scientific and Technical Information of China (English)

    杨幸幸; 邹应全

    2009-01-01

    Six sulfonium photoacid generators(PAGs) which were used in 248 nm photoresists were synthesized, some of which were innovated by our lab for the first time. The synthesis method is very simple and environment-friendly, with high yields at the same time. All the PAGs were identified by IR, HNMR and UV. The max wavelengths of ultraviolet absorption are between 250 nm and 285 nm, and the absorption region are so wide that these PAGs can be used extensively. We used rhodamine B and ultraviolet spectrophotometer to evaluate the acid-generation efficiency of the PAGs in acetonitrile because rhodamine B will change colour by the change of acid concentration. The PAGs synthesized by thioxanthen-9-one and isopropylthioxanthen-9-one were choosed as the best ones. We also studied how the solvent affect the acid-generation by fluorescence, and found that the acid-generation efficiency would be depressed by the decrease of the solvent′s polarity. All the work about the PAGs can provide an important reference to 248 nm photoresists.%合成了6种适用于248 nm光致抗蚀剂的硫鎓盐产酸剂,其中吩噻(噁)体系的产酸剂为自行设计合成. 利用IR、H NMR、UV等测试技术进行了结构表征和紫外吸收测定,各化合物的最大紫外吸收在250~285 nm之间,吸收域较宽,适用性较强.同时,利用酸敏染料罗丹明B遇酸异构变色的特点,使用紫外!可见分光光度计定量检测了6种产酸剂在乙腈溶剂中的产酸效率,其中硫杂蒽酮系列的产酸剂产酸性能最好. 最后使用荧光追踪法研究了溶剂极性对产酸效率的影响,发现产酸剂的产酸性能同溶剂的选取密切相关,随着溶剂极性的减小,产酸效率随之降低. 对6种硫鎓盐的产酸效率检测结果可以为产酸剂进一步用于248 nm光致抗蚀剂配方提供详细的参考.

  7. Leaching of heavy metals in acid mine drainage

    Energy Technology Data Exchange (ETDEWEB)

    Saria, L.; Shimaoka, T.; Miyawaki, K. [Kyushu University, Fukuoka (Japan)

    2006-04-15

    Acid mine drainage is one of the most serious environmental problems that the coal and metal mining industry is currently facing. The generation of low pH drainage enhances the dissolution of heavy metals in water. The samples used in this research originated from three pits at mine dumps. In a study reported in this paper, three types of tests; namely static test, kinetic test and column test were conducted to estimate acid generation and acid neutralization reaction rates, and to predict the solubility of metals and their release rates. Static test showed that all samples had a pH of net acid generation (NAG pH) <4, a net acid producing potential (NAPP) >10 kg H{sub 2}SO{sub 4}tonne{sup -1}, and a S-content >3%, which can be classified as a high acid-forming capacity. Simulated runoff in the column tests was equivalent to 5-year average rainfall in Indonesia, the resultant leachates showed acidic behaviour (pH <3.5). Based on the results, it was found that high mobilization of heavy metals (Cr, Cu, Zn, Cd and Pb) takes place under strong acidic conditions (pH congruent to 2).

  8. Lysophosphatidic acid induces reactive oxygen species generation by activating protein kinase C in PC-3 human prostate cancer cells

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Chu-Cheng; Lin, Chuan-En; Lin, Yueh-Chien [Institute of Zoology, College of Life Science, National Taiwan University, Taipei, Taiwan, ROC (China); Ju, Tsai-Kai [Instrumentation Center, National Taiwan University, Taipei, Taiwan, ROC (China); Technology Commons, College of Life Science, National Taiwan University, Taipei, Taiwan, ROC (China); Huang, Yuan-Li [Department of Biotechnology, Asia University, Taichung, Taiwan, ROC (China); Lee, Ming-Shyue [Institute of Biochemistry and Molecular Biology, College of Medicine, National Taiwan University, Taipei, Taiwan, ROC (China); Chen, Jiun-Hong [Institute of Zoology, College of Life Science, National Taiwan University, Taipei, Taiwan, ROC (China); Department of Life Science, College of Life Science, National Taiwan University, Taipei, Taiwan, ROC (China); Lee, Hsinyu, E-mail: hsinyu@ntu.edu.tw [Institute of Zoology, College of Life Science, National Taiwan University, Taipei, Taiwan, ROC (China); Department of Life Science, College of Life Science, National Taiwan University, Taipei, Taiwan, ROC (China); Center for Biotechnology, National Taiwan University, Taipei, Taiwan, ROC (China); Research Center for Developmental Biology and Regenerative Medicine, National Taiwan University, Taipei, Taiwan, ROC (China)

    2013-11-01

    Highlights: •LPA induces ROS generation through LPA{sub 1} and LPA{sub 3}. •LPA induces ROS generation by activating PLC. •PKCζ mediates LPA-induced ROS generation. -- Abstract: Prostate cancer is one of the most frequently diagnosed cancers in males, and PC-3 is a cell model popularly used for investigating the behavior of late stage prostate cancer. Lysophosphatidic acid (LPA) is a lysophospholipid that mediates multiple behaviors in cancer cells, such as proliferation, migration and adhesion. We have previously demonstrated that LPA enhances vascular endothelial growth factor (VEGF)-C expression in PC-3 cells by activating the generation of reactive oxygen species (ROS), which is known to be an important mediator in cancer progression. Using flow cytometry, we showed that LPA triggers ROS generation within 10 min and that the generated ROS can be suppressed by pretreatment with the NADPH oxidase (Nox) inhibitor diphenylene iodonium. In addition, transfection with LPA{sub 1} and LPA{sub 3} siRNA efficiently blocked LPA-induced ROS production, suggesting that both receptors are involved in this pathway. Using specific inhibitors and siRNA, phospholipase C (PLC) and protein kinase C (PKC) were also suggested to participate in LPA-induced ROS generation. Overall, we demonstrated that LPA induces ROS generation in PC-3 prostate cancer cells and this is mediated through the PLC/PKC/Nox pathway.

  9. Matrix formation in sustained release tablets: possible mechanism of dose dumping.

    Science.gov (United States)

    Krajacic, Aleksandra; Tucker, Ian G

    2003-01-30

    Conditions under which poly(ethyl acrylate, methyl methacrylate) 2:1 (poly(EA-MMA), Eudragit NE) forms a stable matrix were investigated in tablets with diclofenac sodium (DS) as an active substance. DS was granulated with the aqueous polymer dispersion. Granules and/or tablets were cured under various temperature and humidity conditions. A six position rotating disk (200 rpm) apparatus was used for the release studies conducted in 37 degrees C acid then phosphate buffer (0.4 M) pH 6.8 or buffer only as the dissolution media. Morphological characteristics of the tablet surface were observed under SEM. Changes in tablet structure upon curing were evaluated through changes in tablet mechanical characteristics. Modulus of rupture, Young's modulus, AUC, AUC(max), where AUC=AUC(max), were determined by the three-point bending test. Some poorly cured tablets dose-dumped when placed directly into buffer but not if first placed in acid and then buffer. A higher content of polymer in the matrix, led to formation of a stronger polymer network upon higher curing temperature and/or longer curing duration, whereas relative humidity had a minor effect.

  10. Microbial Ecology Assessment of Mixed Copper Oxide/Sulfide Dump Leach Operation

    Energy Technology Data Exchange (ETDEWEB)

    Bruhn, D F; Thompson, D N; Noah, K S

    1999-06-01

    Microbial consortia composed of complex mixtures of autotrophic and heterotrophic bacteria are responsible for the dissolution of metals from sulfide minerals. Thus, an efficient copper bioleaching operation depends on the microbial ecology of the system. A microbial ecology study of a mixed oxide/sulfide copper leaching operation was conducted using an "overlay" plating technique to differentiate and identify various bacterial consortium members of the genera Thiobacillus, Leptospirillum, Ferromicrobium, and Acidiphilium. Two temperatures (30C and 45C) were used to select for mesophilic and moderately thermophilic bacteria. Cell numbers varied from 0-106 cells/g dry ore, depending on the sample location and depth. After acid curing for oxide leaching, no viable bacteria were recovered, although inoculation of cells from raffinate re-established a microbial population after three months. Due to the low pH of the operation, very few non-iron-oxidizing acidophilic heterotrophs were recovered. Moderate thermophiles were isolated from the ore samples. Pregnant liquor solutions (PLS) and raffinate both contained a diversity of bacteria. In addition, an intermittently applied waste stream that contained high levels of arsenic and fluoride was tested for toxicity. Twenty vol% waste stream in PLS killed 100% of the cells in 48 hours, indicating substantial toxicity and/or growth inhibition. The data indicate that bacteria populations can recover after acid curing, and that application of the waste stream to the dump should be avoided. Monitoring the microbial ecology of the leaching operation provided significant information that improved copper recovery.

  11. THE ZOO-ECONOMIC CHALLENGES OF FISCAL DUMPING

    Directory of Open Access Journals (Sweden)

    MARINA LUMINIŢA SÂRBOVAN

    2013-07-01

    Full Text Available In United Europe, the economic policy proves common goals of prosperity and development, still each country is administrating its own policy mix in order to reshape the fiscal pressure and to safeguard the economic body of the society. The fiscal dumping is a feature of the market competition concerning the non-cooperating actions taken among the economic agents targeted to increase the fiscal appealing of their (home-land territory by instrument of apparently favoring fiscal policies. In Romania this disguised tool of the policy promotion is mixed with an explicit expectation of rural and agriculture subvention, abundant in SMEs and rural fields, in line with the local needs of increasing the foreign investments and consolidating growth.

  12. Wheel slip dump valve for railway braking system

    Science.gov (United States)

    Zhang, Xuan; Zhang, LiHao; Li, QingXuan; Shi, YanTao

    2017-09-01

    As we all know, pneumatic braking system plays an important role in the safety of the whole vehicle. In the anti slip braking system, the pressure of braking cylinder can be adjusted by the quick power response of wheel slip dump valve, so that the lock situation won’t occur during vehicle service. During the braking of railway vehicles, the braking force provided by braking disc reduces vehicle’s speed. But the locking slip will happen due to the oversize of braking force or the reduction of sticking coefficient between wheel and rail. It will cause not only the decline of braking performance but also the increase of braking distance. In the meanwhile, it will scratch the wheel and influence the stable running of vehicles. Now, the speed of passenger vehicle has been increased. In order to shorten the braking distance as far as possible, sticking stickiness must be fully applied. So the occurrence probability of wheel slip is increased.

  13. Heavy Flavour Cascade Production in a Beam Dump

    CERN Document Server

    2015-01-01

    SHiP will use a 400~GeV/c proton beam impinging on a several interaction length long Molybdenum target. Heavy flavour hadrons produced in the dump can decay semi-leptonically, which can produce both the Heavy Neutral Leptons as signal, but also potential background from muons and neutrinos. The absolute rate of heavy flavour production is taken from measurements. Pythia is used to predict the phase space distribution of the charm and beauty hadrons which are produced both in the primary interaction of the 400~GeV/c proton and in interactions of the secondaries produced in the cascade. The full cascade production of both HNL and background is compared to that reported in the SHiP Technical Proposal, where only the primary $pN$ interactions were taken into account.

  14. The chemistry of lava-seawater interactions: The generation of acidity

    Energy Technology Data Exchange (ETDEWEB)

    Resing, J.A. [National Oceanic and Atmospheric Administration, Seattle, WA (United States). Pacific Marine Environmental Lab.; Sansone, F.J. [Univ. of Hawaii, Honolulu, HI (United States). Dept. of Oceanography

    1999-08-01

    High concentrations of acid were found to arise from the interaction between molten rock and seawater at the shoreline of Kilauea Volcano, Hawaii. A series of field samplings and experiments show that the acid was derived from two sources: the release of magmatic volatiles and water-rock reactions. Although the bulk of the magmatic volatiles (CO{sub 2}, H{sub 2}O, and SO{sub 2}) are vented at Puu Oo cinder cone before the lava`s transit downslope to the ocean, a portion of the sulfur (S) and fluoride (F) gases are retained by the lava and then are released partially when the lava is quenched by seawater. The primary water-rock reaction responsible for acid formation appears to be Na-metasomatism, which is much different from the predominant acid-forming reaction found in submarine hydrothermal systems, Mg-metasomatism. Analyses of surface seawater and of precipitation (rain) deposited at the shore show that {approximately}30% of the acid comes from magmatic gases with the balance from reactions between the rock and the salts found in seawater. Experimental results show that {approximately}4 {+-} 1.5 mEq of acid are formed per kilogram of lava entering the ocean, and of this 1 {+-} 0.5 mEq/kg of lava came from S and F, with the balance coming from water-rock reactions. On the basis of lava extrusion rates, {approximately}200--720 {times} 10{sup 6} Eq/yr of acid are being formed at this site. The deposition of the acid results in the alteration of subaerial lava flows along the coast, and the lowering of the pH of the adjacent surface ocean waters by more than 1 unit. The ejection of this acid into the atmosphere contributes to the formation of an extensive haze downwind of the lava entries.

  15. The design of the electron beam dump unit of Turkish Accelerator Center (TAC)

    Science.gov (United States)

    Cite, L. H.; Yilmaz, M.

    2016-03-01

    The required simulations of the electron beam interactions for the design of electron beam dump unit for an accelerator which will operate to get two Infra-Red Free Electron Lasers (IR-FEL) covering the range of 3-250 microns is presented in this work. Simulations have been carried out to understand the interactions of a bulk of specially shaped of four different and widely used materials for the dump materials for a 77 pC, 40 MeV, 13 MHz repetition rate e-beam. In the simulation studies dump materials are chosen to absorb the 99% of the beam energy and to restrict the radio-isotope production in the bulk of the dump. A Lead shielding also designed around the dump core to prevent the leakage out of the all the emitted secondary radiations, e.g., neutrons, photons. The necessary dump material requirements, for the overall design considerations and the possible radiation originated effects on the dump unit, are discussed and presented.

  16. Flora and vegetation on dumps of uranium mining in the southern part of the former GDR

    Directory of Open Access Journals (Sweden)

    Hartmut Sänger

    2014-01-01

    Full Text Available From 1946 to 1990 an intensive uranium mining had been carried out with underground mining and also with opencast mining by the Wismut enterprise in the southern part of the former GDR. The mining activity lead also in the surroundings of Ronneburg to a permanent growth of devastated areas, among others in the form of dumps and tailings. These areas form by reason of mining-specific contaminations, extrem biotops which demand high claims on the pioneer organisms during the phase of natural first settlement. From 1990 to 1992 vegetation mappings were carried out on 15 dumps of the Thuringia mining area according to Braun-Blanquet (1964. The utilization of the computer programm Flora _D (Frank and Klotz 1990 enabled the ecological characterisation of the dumps. On the 15 investigated dumps found were 498 higher plants, belonging to 65 families. One hundred species are species with a high dominance. The number of species per dump fluctuates between 1 I and 282. Pioneer plants occur on the berms mostly in the second year after stoppage of the dumping, on the slopes after five to ten years. After nearly ten years the first step of settlement seems to be finished. Among the mechanisms of spreading dominate wind- and burdock spread. According to the form of life forms the dump species are predominantly hemicryptophytes, further therophytes, geophytes and phanerophytes.

  17. Aspects Regarding the Installation of Some Invasive Weeds Species on Old Fly Ash Dumps

    Directory of Open Access Journals (Sweden)

    Anca Pricop

    2010-10-01

    Full Text Available Most Romanian power plants were built in a period when environmental impact of their operation was undervalued, and constraints related to environmental protection were relatively few. Location of power plants and fly ash dumps was chosen most often by arbitrary criteria, and never after the impact that it may have on the environment. Building fly ash dumps have an effect of destruction of soils not only on the surface equivalent to those of dumps but also of the contiguous lands. Old fly ash dumps are a major risk because of the dispersion of pollutants in water and soil by percolation and soil leaching, and because of the unwanted invasion of weeds that are adaptable to arid conditions of the dumps and then invade surrounding areas jeopardizing the surrounding crops. In attempting to install vegetation an old fly ash dumps, the area were invaded by two species of weeds that quickly overgrown the experimental parcel and the surroundings. The present study followed the invasion degree of fly ash dumps with weeds and aspects regarding their development and breeding in the new formed ecosystem.

  18. Mapping Of Construction Waste Illegal Dumping Using Geographical Information System (GIS)

    Science.gov (United States)

    Zainun, Noor Yasmin; Rahman, Ismail Abdul; Azwana Rothman, Rosfazreen

    2016-11-01

    Illegal dumping of solid waste not only affecting the environment but also social life of communities, hence authorities should have an effective system to cater this problem. Malaysia is experiencing extensive physical developments and this has led to an increase of construction waste illegal dumping. However, due to the lack of proper data collection, the actual figure for construction waste illegal dumping in Malaysia are not available. This paper presents a mapping of construction waste illegal dumping in Kluang district, Johor using Geographic Information System (GIS) software. Information of the dumped waste such as coordinate, photos, types of material and quantity of waste were gathered manually through site observation for three months period. For quantifying the dumped waste, two methods were used which are the first method is based on shape of the waste (pyramids or squares) while the second method is based weighing approach. All information regarding the waste was assigned to the GIS for the mapping process. Results indicated a total of 12 types of construction waste which are concrete, tiles, wood, gypsum board, mixed construction waste, brick and concrete, bricks, sand, iron, glass, pavement and tiles, and concrete at 64 points locations of illegal dumping on construction waste in Kluang. These wastes were accounted to an estimated volume of 427.2636 m3. Hopefully, this established map will assist Kluang authority to improve their solid waste management system in Kluang.

  19. The 3-D numerical study of airflow in the compressor/combustor prediffuser and dump diffuser of an industrial gas turbine

    Science.gov (United States)

    Agrawal, Ajay K.; Yang, Tah-Teh

    1993-01-01

    This paper describes the 3D computations of a flow field in the compressor/combustor diffusers of an industrial gas turbine. The geometry considered includes components such as the combustor support strut, the transition piece and the impingement sleeve with discrete cooling air holes on its surface. Because the geometry was complex and 3D, the airflow path was divided into two computational domains sharing an interface region. The body-fitted grid was generated independently in each of the two domains. The governing equations for incompressible Navier-Stokes equations were solved using the finite volume approach. The results show that the flow in the prediffuser is strongly coupled with the flow in the dump diffuser and vice versa. The computations also revealed that the flow in the dump diffuser is highly nonuniform.

  20. Assessment of nonpoint source chemical loading potential to watersheds containing uranium waste dumps and human health hazards associated with uranium exploration and mining, Red, White, and Fry Canyons, southeastern Utah, 2007

    Science.gov (United States)

    Beisner, Kimberly R.; Marston, Thomas M.; Naftz, David L.; Snyder, Terry; Freeman, Michael L.

    2010-01-01

    During May, June, and July 2007, 58 solid-phase samples were collected from abandoned uranium mine waste dumps, background sites, and adjacent streambeds in Red, White, and Fry Canyons in southeastern Utah. The objectives of this sampling program were to (1) assess the nonpoint-source chemical loading potential to ephemeral and perennial drainage basins from uranium waste dumps and (2) assess potential effects on human health due to recreational activities on and around uranium waste dumps on Bureau of Land Management property. Uranium waste-dump samples were collected using solid-phase sampling protocols. After collection, solid-phase samples were homogenized and extracted in the laboratory using a leaching procedure. Filtered (0.45 micron) water samples were obtained from the field leaching procedure and were analyzed for major and trace elements at the Inductively Coupled Plasma-Mass Spectrometry Metals Analysis Laboratory at the University of Utah. A subset of the solid-phase samples also were digested with strong acids and analyzed for major ions and trace elements at the U.S. Geological Survey Geologic Division Laboratory in Denver, Colorado. For the initial ranking of chemical loading potential for uranium waste dumps, results of leachate analyses were compared with existing aquatic-life and drinking-water-quality standards. To assess potential effects on human health, solid-phase digestion values for uranium were compared to soil screening levels (SSL) computed using the computer model RESRAD 6.5 for a probable concentration of radium. One or more chemical constituents exceeded aquatic life and drinking-water-quality standards in approximately 64 percent (29/45) of the leachate samples extracted from uranium waste dumps. Most of the uranium waste dump sites with elevated trace-element concentrations in leachates were located in Red Canyon. Approximately 69 percent (31/45) of the strong acid digestible soil concentration values were greater than a calculated

  1. Long-Term Acid-Generating and Metal Leaching Potential of a Sub-Arctic Oil Shale

    Directory of Open Access Journals (Sweden)

    Kathryn A. Mumford

    2014-04-01

    Full Text Available Shales are increasingly being exploited for oil and unconventional gas. Exploitation of sub-arctic oil shales requires the creation of gravel pads to elevate workings above the heaving effects of ground ice. These gravel pads can potentially generate acidic leachate, which can enhance the mobility of metals from the shale. To examine this potential, pyrite-bearing shale originating from sub-Arctic gravel pad sites were subjected to leaching tests for 600 days at initial pH values ranging from 2 to 5, to simulate potential real world conditions. At set times over the 600 day experiment, pH, oxidation reduction potential (ORP, dissolved oxygen and temperature were recorded and small liquid samples withdrawn and analysed for elemental concentrations using total reflection X-ray fluorescence spectrometry (TRXRF. Six of eight shale samples were found to be acid generating, with pH declining and ORP becoming increasingly positive after 100 days. Two of the eight shale samples produced increasingly alkaline leachate conditions with relatively low ORP after 100 days, indicating an inbuilt buffering capacity. By 600 days the buffering capacity of all samples had been consumed and all leachate samples were acidic. TRXRF analyses demonstrated significant potential for the leaching of S, Fe, Ni, Cu, Zn and Mn with greatest concentrations found in reaction vessels with most acidic pH and highest ORP.

  2. Generation of dose-response relationships to assess the effects of acidity in precipitation on growth and productivity of vegetation

    Energy Technology Data Exchange (ETDEWEB)

    Evans, L.S.

    1981-01-01

    Experiments were performed with several plant species in natural environments as well in a greenhouse and/or tissue culture facilities to establish dose-response functions of plant responses to simulated acidic rain in order to determine environmental risk assessments to ambient levels of acidic rain. Response functions of foliar injury, biomass of leaves and seed of soybean and pinto beans, root yields of radishes and garden beets, and reproduction of bracken fern are considered. The dose-response function of soybean seed yields with the hydrogen ion concentration of simulated acidic rainfalls was expressed by the equation y = 21.06-1.01 log x where y = seed yield in grams per plant and x = the hydrogen concentration if ..mu..eq l/sup -1/. The correlation coefficient of this relationship was -0.90. A similar dose-response function was generated for percent fertilization of ferns in a forest understory. When percent fertilization is plotted on logarithmic scale with hydrogen ion concentration of the simulated rain solution, the Y intercept is 51.18, slope -0.041 with a correlation coefficient of -0.98. Other dose-response functions were generated that assist in a general knowledge as to which plant species and which physiological processes are most impacted by acidic precipitation. Some responses did not produce convenient dose-response relationships. In such cases the responses may be altered by other environmental factors or there may be no differences among treatment means.

  3. Effects of Weathering at Waste Rock Dump on Water Quality Inside the Mine Wastes; A Case Study in Korea

    Science.gov (United States)

    Yim, G.; Cheong, Y.; Park, H.; Ji, S.; Lee, H.

    2008-05-01

    This study was carried out to investigate the route of acid rock drainage production and some of the important factors at the abandoned Geo-pung copper mine in Okcheon, Korea. In this research area, planting and remediation have been carried out to prevent environmental pollution, but these effects turned out to be a failure and that acid rock drainage is observed around waste rock dump and planted vegetation is dying. Currently, the slope of mine waste rock dump in the study site is about 40°. It is composed of particles with a variety of shapes, with the surface exposure to atmosphere being transformed to oxide minerals due to weathering. Since groundwater level underneath the mine wastes is directly related to rainfall, a comparative evaluation of weather records and groundwater level data obtained using on-site measuring device (CTD diver) would allow estimation of locational media-specific pattern of rainfall effect in term of infiltration flux and time of threshold impact on groundwater. Sampling and analysis of there borehole water were conducted in July and September, 2007. It was found that all of the borehole water had highly variable levels of Fe (0.4-588 mg/l), Al (8.2-41.9 mg/l), Cu (6.0-32.2 mg/l), Zn (22.2-226.7 mg/l) and other elements. Also, in general, pH of the borehole waters decreased while electric conducivity measured. Such a high variance in the water quality among different borehole water suggests that geochemical environment inside the mine wastes is largely dependent on the local variation in rainfall infiltration of waste rock dump and underneath groundwater level. Vadose zone which has vertical variation of 2-4 m is directly impacted by amount of rainfall and maintains oxidizing condition due to diffusion of oxygen carred by rainfall. Therefore, sulfide minerals within in the zone continued to be oxidized, producing acid rock drainage. To prevent production of acid rock drainage of mine waste, it is necessary to control infiltration of

  4. A Spring without Water: The Conundrum of Anti-Dumping Duties in South African Law

    Directory of Open Access Journals (Sweden)

    Clive Vinti

    2016-08-01

    Full Text Available The Agreement on the Implementation of Article VI of the General Agreement on Tariffs and Trade (1994 (Anti-Dumping Agreement permits the imposition of anti-dumping duties for as long and to the extent necessary to counteract dumping which is causing injury, subject to the proviso that they must be terminated after five years unless a sunset review has been initiated. A sunset review has the purpose of either permitting or terminating the continuation of an anti-dumping duty. This is significant because if the sunset review is not initiated prior to the expiry of the five-year period, the anti-dumping duties will be terminated. Therefore, this places an emphasis on the determination of the precise date of commencement of the anti-dumping duties. This is because an incorrect determination of the date of the imposition of the anti-dumping duty has obvious financial implications for the interested parties. The Supreme Court of Appeal in South Africa has delivered two salient judgments in this regard: firstly, in Progress Office Machines CC v SARS 2008 2 SA 13 (SCA (POM, and then more recently, in Association of Meat Importers v ITAC 2013 4 All SA 253 (SCA (AMIE. This paper contends that these two judgments are in conflict and are riddled with inconsistencies. Secondly, the paper contends that the SCA has in the recent AMIE case virtually rewritten its earlier judgment of Progress Office Machines. Lastly, the paper shows that the approach of South African courts to whether the Anti-Dumping Agreement is binding on South African law is fraught with uncertainty and ambivalence. The case analysis also reflects on the impact of the newly minted but yet to be implemented Customs Duty Act with a view to assessing the impact of the new legislation on the issues currently plaguing the anti-dumping regime of South Africa.

  5. Feasibility of In-Situ Aeration of Old Dumping Ground for Land Reclamation

    Directory of Open Access Journals (Sweden)

    Huan-Huan Tong

    2013-12-01

    Full Text Available Dumping grounds are characterized by the absence of engineering controls such as base liners and cover layer. Consequently, these dumping grounds present risks for surrounding resources such as soil, groundwater and air. The concern for groundwater contamination by leachate from tropical dumping grounds is heightened due to the greater amounts of rainfall and subsequent infiltration and percolation through the waste mass. The emergent demand for old dumping grounds reclamation drives the need to employ remediation technologies. Generally, in-situ aeration is a remediation method that promotes aerobic conditions in the later stage of dumping ground. It accelerates carbon transfer, reduces remaining organic load, and generally shortens the post closure period. However, high rainfall in tropical areas straitens this technique. For example, pollutants could be easily flushed out and more energy should be required to overcome hydrostatic pressure. Although heavy rainfall could supply sufficient water to the substrate and accelerate degradation of organic matter, it may inhibit aerobic activities due to limited air transfer. The waste characterization from Lorong Halus Dumping Ground (closed dumping ground in Singapore showed that the waste materials were stabilized after 22 years closure. According to the Waste Acceptance Criteria set by European Communities Council, the waste materials could be classified as inert wastes. One interesting finding was that leachate layer detected was about of 5 - 8 meter depth, which entirely soaked the waste materials. Hence, the reclamation design and operation should be carefully adjusted according to these characters. Lorong Halus Dumping Ground case study can provide a guideline for other tropical closed landfills or dumping grounds.

  6. Geochemical Processes Controlling the Generation and Environmental Impacts of Acid Mine Drainage in Semi Arid Conditions

    OpenAIRE

    Magombedze, Chris

    2006-01-01

    This study evaluates the geochemical processes that control the geochemistry of acid mine drainage in semi arid conditions. The central objective is to characterise and understand the evolution of acid mine drainage and its potential environmental impacts on the Mazowe River sub-catchment, in north east Zimbabwe. The work is based on a case study at three neighbouring metal sulphide mines, namely Trojan Nickel Mine, Mazowe Gold Mine and Iron Duke Pyrites.The methodology used in this research ...

  7. A comparison on Anti-dumping against China between Developed and Developing Countries

    Institute of Scientific and Technical Information of China (English)

    杜笑云

    2013-01-01

      In recent years,Chinese exportation suffers greatly from developed countries’and developing countries’anti-dumping against China. Facing to this sort of phenomenon, this article compares the dif erence in the anti-dumping against China from developing and developed countries in three aspects,analyzes the ef ect of anti-dumping from dif erent countries and gives suggestions from a macro view.The paper selects the statistics reported by WTO and National Bureau of Statistics of China,time span from 1995 to 2011.

  8. Motivations of the Anti-dumping of the developed countries and the corresponding strategies to it

    Institute of Scientific and Technical Information of China (English)

    王思涵

    2014-01-01

    Nowadays, anti-dumping is frequently used by economic managers of al countries to suppress the products from other countries. With the continuous expanding of China’s export market, anti-dumping is more and more frequently to be used to suppres China’s export products, which is harmful. Therefore, the motivations of the developed countries which have conducted the anti-dumping wil be analyzed in this thesis and the general means wil be summarized, after which the ef ective solutions to these problems wil be concluded.

  9. The Impact of an Anti-dumping Measure : A Study on EU Imports of Chinese Footwear

    OpenAIRE

    Thuresson, Carin; Andersson, Karolina

    2008-01-01

    This essay analyse the anti-dumping policy of the European Union, with specific focus on the anti-dumping tariff imposed on imports of ertain footwear from the People’s Republic of China from 1997 to 2002. Even though free trade is expected from the members of the World Trade Organization (WTO) there are certain exceptions. One is when there is a suspicion that goods are being dumped in a foreign market, i.e. the exporter sells the product at a lower price in the foreign market than in its ho...

  10. Energy dump of the ATLAS superconducting system simulations of electrical and thermal behaviour of magnet system at slow- and fast dump

    CERN Document Server

    van Beek, Martijn; Dudarev, A

    During the slow dump (discharge) of the Barrel Toroidal (superconducting) magnet of the ATLAS detector, the control system gave an alarm that the differences between the voltages over the conductors were too high. The alarm was not due to any danger, because of some sort of phenomenon observed in the first few seconds after start of the discharge. A possible explanation of the differences of the coil voltages is that the changing current through the conductors may cause induced currents in the coil casing around. The goal was to make a simulation of the electrical behaviour of the magnet system during a slow dump. In this way, an explanation can be found for the start phenomenon of the slow dump of the Barrel Toroid. Some extra analyses on the measurements were performed to describe the energy dissipation during a fast dump. This is done by calculating the resistance of the coils during the dump. With the maximum resistance, the maximum temperature can be estimated, which says something about the enthalpy of ...

  11. Sequential generation of hydrogen and methane from glutamic acid through combined photo-fermentation and methanogenesis.

    Science.gov (United States)

    Xia, Ao; Cheng, Jun; Lin, Richen; Liu, Jianzhong; Zhou, Junhu; Cen, Kefa

    2013-03-01

    Glutamic acid can hardly produce hydrogen via dark- or photo-fermentation without pretreatment. In this study, a novel process of acidogenic pretreatment with bacteria and zeolite treatment for NH4(+) removal was proposed to use glutamic acid as feedstock in photo-fermentation for efficient hydrogen production. Glutamic acid pretreated with acidogenic bacteria produces soluble metabolite products. After zeolite treatment, the acidulated solution, which mainly contains acetate, butyrate, and NH4(+), shows a decrease in NH4(+) concentration from 36.7mM to 3.2mM (NH4(+) removal efficiency of 91.1%). After NH4(+) removal, the treated solution is incubated with photosynthetic bacteria, exhibiting a maximum hydrogen yield of 292.9mL/g(-glutamic acid) during photo-fermentation. The residual solution from photo-fermentation is reused by methanogenic bacteria to produce a maximum methane yield of 102.7mL/g. The heating value conversion efficiency from glutamic acid to gas fuel significantly increases from 18.9% during photo-fermentation to 40.9% in the combined photo-fermentation and methanogenesis process.

  12. Biofilter for generation of concentrated sulphuric acid from H2S.

    Science.gov (United States)

    Rabbani, K A; Charles, W; Kayaalp, A; Cord-Ruwisch, R; Ho, G

    2016-08-01

    Biofilters are used for the conversion of odorous hydrogen sulphide to odourless sulphate in wastewater treatment plants under the right conditions of moisture and pH. One of the consequences of maintaining the suitable pH and moisture content is the production of large volumes of weakly acidic leachate. This paper presents a biofilter with a maximum H2S elimination capacity of 16.3 g m(-3) h(-1) and removal efficiency greater than 95 % which produces small volumes (1 mL of solution L(-1) of reactor day(-1)) of sulphuric acid with a concentration greater than 5.5 M after 150 days of continuous operation. The concentrated sulphuric acid was produced by intermittently trickling a minimum amount of nutrient solution down the upflow biofilter which created a moisture and pH gradient within the biofilter resulting in an environment at the top for the bacterial conversion of H2S, while sulphuric acid was accumulated at the base. Genetic diversity profiling of samples taken from different sections of the biofilter confirms that the upper sections of the biofilter had the best environment for the bacteria to convert H2S to sulphate. The formation of concentrated sulphuric acid presents an opportunity for the recovery of sulphur from the waste stream as a usable product.

  13. Body mass index, gestational weight gain and fatty acid concentrations during pregnancy: the Generation R Study.

    Science.gov (United States)

    Vidakovic, Aleksandra Jelena; Jaddoe, Vincent W V; Gishti, Olta; Felix, Janine F; Williams, Michelle A; Hofman, Albert; Demmelmair, Hans; Koletzko, Berthold; Tiemeier, Henning; Gaillard, Romy

    2015-11-01

    Obesity during pregnancy may be correlated with an adverse nutritional status affecting pregnancy and offspring outcomes. We examined the associations of prepregnancy body mass index and gestational weight gain with plasma fatty acid concentrations in mid-pregnancy. This study was embedded in a population-based prospective cohort study among 5636 women. We obtained prepregnancy body mass index and maximum weight gain during pregnancy by questionnaires. We measured concentrations of saturated fatty acid (SFA), monounsaturated fatty acid (MUFA), n-3 polyunsaturated fatty acid (n-3 PUFA) and n-6 polyunsaturated fatty acid (n-6 PUFA) at a median gestational age of 20.5 (95% range 17.1-24.9) weeks. We used multivariate linear regression models. As compared to normal weight women, obese women had higher total SFA concentrations [difference: 0.10 standard deviation (SD) (95% Confidence Interval (CI) 0, 0.19)] and lower total n-3 PUFA concentrations [difference: - 0.11 SD (95% CI - 0.20, - 0.02)]. As compared to women with sufficient gestational weight gain, those with excessive gestational weight gain had higher SFA concentrations [difference: 0.16 SD (95% CI 0.08, 0.25)], MUFA concentrations [difference: 0.16 SD (95% CI 0.08, 0.24)] and n-6 PUFA concentrations [difference: 0.12 SD (95% CI 0.04, 0.21)]. These results were not materially affected by adjustment for maternal characteristics. Our results suggest that obesity and excessive weight gain during pregnancy are associated with an adverse fatty acids profile. Further studies are needed to assess causality and direction of the observed associations.

  14. Chemical composition of fragmental products fractions of rock dumps and tailing dump as basis for potential geoecological danger estimation in the areas of mining enterprises

    Directory of Open Access Journals (Sweden)

    Vdovina Ol’ga Konstantinovna

    Full Text Available Negative consequences of deposit development on the environment are well know. They manifest themselves most intensively in case of open-cut mining of ore minerals, which is related to the increase of rock dumps masses. The material of rock dumps and tailing dumps actively influence the state of the environment transforming the natural landscapes, first of all, as a reason of migration of waters changed as a result of their contact with mining waste. The authors give their estimation of the consequences of apatite-nephelinic ore crop in Khibini Ore District by the company “Apatit”, which includes the influence on the natural waters. The unique natural conditions of the area are the reason for high-level potential geoecological danger. The mobility of lots of toxic elements is raised because of ligand-ion OH in the waters of alkali rocks of Khibini soil.

  15. [Aspartic Acid Generated in the Process of Chlorination Disinfection By-product Dichloroacetonitrile].

    Science.gov (United States)

    Ding, Chun-sheng; Li, Nai-jun; Zhang, Tao; Zhang, Meng-qing

    2016-05-15

    In this study, a method was developed for the determination of dichloroacetonitrile (DCAN) in drinking water by liquid- liquid micro-extraction and gas chromatography/mass spectrometry ( LLE-GC/MS), which used 1,2-dibromopropane as the internal standard and methyl tertiary butyl ether (MTBE) as the extractant for high accuracy. The aspartic acid was used as the precursor of the DCAN formation during chlorination and the influencing factors were evaluated. The formation mechanism of DCAN was also discussed. The results showed that the DCAN amount increased with the increase of pH value under the neutral and acidic conditions, however, the amount of DCAN decreased with the increase of pH value under the alkali condition. And the final amount of DCAN under the alkali condition was much less than that under the neutral and acidic conditions. It was also found that the DCAN amount increased with the increase of chlorine addition, while the temperature in the range of 10-30°C had little influence on the DCAN formation. The formation process of the DCAN from aspartic acid by chlorination included seven steps, such as substitution, decarboxylation, oxidation, etc and ultimately formed DCAN.

  16. Further Study of Prompt Neutrino Production in a Proton Beam Dump Experiment

    CERN Multimedia

    2002-01-01

    In previous beam dump experiments at CERN, the production of prompt @n^e and @n(@m) in proton-nucleus collisions has been established. A difference in the prompt @n^e and @n(@m) fluxes which would indicate new physics, cannot be ruled out on the basis of existing data.\\\\ \\\\ The main aim of this beam dump experiment is to check with much better accuracy the equality of the prompt @n^e and @n(@m) fluxes. The use of two copper dumps with average density 1 and 1/3 permits the separation of the prompt and conventional neutrino fluxes by extrapolation to infinite density. The dumps will be located at the downstream end of the decay tunnel of the SPS neutrino facility.

  17. Oceanographic studies off Beypore Port, west coast of India to locate a dredge dumping site

    Digital Repository Service at National Institute of Oceanography (India)

    DineshKumar, P.K.; Vethamony, P.; Babu, M.T.; Srinivas, K.; Thottam, T.J.

    at the 15 m water depth contour with coordinates: Latitude 11 degrees 07.00 minutes; Longitude 75 degrees 45.60 minutes, where the environmental impacts on the ecosystem due to dumping operations is considered to be minimum...

  18. The EU Anti-dumping Policy towards China: Challenges for Chinese and Foreign Managers

    DEFF Research Database (Denmark)

    Nielsen, Jørgen Ulff-Møller; Rutkowski, Aleksander Jerzy

    2002-01-01

    This paper investigates the EU anti-dumping policy towards Chinese companies. It is based on the EU anti-dumping cases since 1990 and especially since July 1998. (Since then Chinese firms have been able to apply for market economy status). Based on this analysis, the paper presents some practical...... advice to Chinese or foreign managers in companies in China with export to the EU. First, the CELEX database may give some important information on how to formulate a price policy for exports to the EU so anti-dumping measures can be avoided. Secondly, the owner structure of the company is important......, owner structure counts also in relation to getting individual treatment; here especially freedom in exporting is decisive. Fourthly, if an anti-dumping investigation seems to be against the interests of the company, it should make an offer to the EU Commission to raise its export prices instead...

  19. The Puzzle of Simultaneous Anti-Dumping and Anti-Subsidy Measures

    DEFF Research Database (Denmark)

    Nielsen, Jørgen Ulff-Møller; Hansen, Jørgen Drud

    Quite frequently an anti-subsidy investigation in the EU is paired with an anti-dumping investigation against the same non-EU producers. The final outcome may be a two-component duty where one duty addresses the ‘unfairness’ of the subsidy and the other the dumping behavior. The procedure may...... be a surprise, as the same total level of protection may be obtained by using the anti-dumping procedure exclusively. When calculating the two duties in the EU the outcome depends on whether the subsidies are export subsidies or domestic subsidies and this may also cause surprise. This paper addresses......’ competition completely and because a parallel investigation may increase the probability of a successful outcome for the petitioners. In contrast, we find that the different assumptions about the effect of export subsidies and domestic production subsidies on the dumping margin in the EU dual anti...

  20. EU to Continue 48.5% Anti-dumping Duties on Chinese Bicycles

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    On June 10, European Commission informed the Business Office of the Mission of Ministry of Commerce in EU and disclosed the adjudication on the review of the EU imposing anti-dumping on Chinese bicycles.

  1. 78 FR 37759 - Ocean Dumping; Atchafalaya-West Ocean Dredged Material Disposal Site Designation

    Science.gov (United States)

    2013-06-24

    ... From the Federal Register Online via the Government Publishing Office ENVIRONMENTAL PROTECTION AGENCY 40 CFR Part 228 Ocean Dumping; Atchafalaya-West Ocean Dredged Material Disposal Site Designation AGENCY: Environmental Protection Agency (EPA). ACTION: Proposed rule and draft Environmental...

  2. Estimation of spatial variability of lignite mine dumping ground soil properties using CPTu results

    Directory of Open Access Journals (Sweden)

    Bagińska Irena

    2016-03-01

    Full Text Available The paper deals with application of CPTu test results for the probabilistic modeling of dumping grounds. The statistical measures use results from 42 CPT test points located in the lignite mine dumping ground from the region of Central Europe. Both the tip resistance qc as well as local friction fs are tested. Based on the mean values and standard deviations of measured quantities the specific zones in the dumping site profile are distinguished. For three main zones standard deviations of linearly de-trended functions, distributions of normalized de-trended values for qc and fs are examined. Also the vertical scales of fluctuation for both measured quantities are estimated. The obtained result shows that lignite mine dumping site can be successfully described with the Random Field Theory. Additional use of fs values introduces supplementary statistical information.

  3. Forecast salt regime unwatered mine reclaimed dump in unstable conditions in Western Donbass

    Directory of Open Access Journals (Sweden)

    Yevhrashkina H.P.

    2016-02-01

    Full Text Available On the based theory of physical-chemical hydrodynamic of porous media was executed prognosis salt rate no suppying with water mine dumps of minimum sense transhiration in conditions no established rate.

  4. Tire Dumps, washoe county sheriff's office data, Published in 2006, Washoe County.

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This Tire Dumps dataset, was produced all or in part from Field Survey/GPS information as of 2006. It is described as 'washoe county sheriff's office data'. Data by...

  5. Mine dumps, wheeze, asthma, and rhinoconjunctivitis among adolescents in South Africa: any association?

    Science.gov (United States)

    Nkosi, Vusumuzi; Wichmann, Janine; Voyi, Kuku

    2015-01-01

    The study investigated the association between community proximity to mine dumps, and current wheeze, rhinoconjunctivitis, and asthma among adolescents. This study was conducted during May-November 2012 around five mine dumps in South Africa. Communities in close proximity to mine dumps had an increased likelihood of current wheeze OR 1.38 (95 % CI: 1.10-1.71), rhinoconjunctivitis OR 1.54 (95 % CI: 1.29-1.82), and a protective association with asthma OR 0.29 (95 % CI: 0.23-0.35). Factors associated with health outcomes included other indoor and outdoor pollution sources. Wheeze and rhinoconjunctivitis appear to be a public health problem in these communities. The findings of this study serve as a base for further detailed epidemiological studies for communities in close proximity to the mine dumps e.g. a planned birth cohort study.

  6. CFD simulation of thermodynamic and temperature effects on spontaneous combustion of coal stockpiles and dumps

    CSIR Research Space (South Africa)

    Kekana, J

    2011-01-01

    Full Text Available momentum transfer equation: Energy conservation equation for the solid phase was modeled by the following heat transfer equation: The porosity of the coal dump was calculated from Yuan and Smith, (2009): The Arrhenius rate of oxidation...

  7. 30 CFR 57.9303 - Construction of ramps and dumping facilities.

    Science.gov (United States)

    2010-07-01

    ... METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Loading, Hauling, and Dumping Safety Devices, Provisions, and Procedures for Roadways, Railroads...

  8. Acid-promoted chemoselective introduction of amide functionality onto aromatic compounds mediated by an isocyanate cation generated from carbamate.

    Science.gov (United States)

    Sumita, Akinari; Kurouchi, Hiroaki; Otani, Yuko; Ohwada, Tomohiko

    2014-10-01

    Carbamates have been used as precursors of isocyanates, but heating in the presence of strong acids is required because cleavage of the C-O bond in carbamates is energy-demanding even in acid media. Direct amidation of aromatic compounds by isocyanate cations generated at room temperature from carbamoyl salicylates in trifluoromethanesulfonic acid (TfOH) was examined. Carbamates with ortho-salicylate as an ether group (carbamoyl salicylates) showed dramatically accelerated O-C bond dissociation in TfOH, which resulted in facile generation of the isocyanate cation. These chemoselective intermolecular aromatic amidation reactions proceeded even at room temperature and showed good compatibility with other electrophilic functionalities and high discrimination between N-monosubstituted carbamate and N,N-disubstituted carbamate. The reaction rates of secondary and tertiary amide formation were markedly different, and this difference was utilized to achieve successive (tandem) amidation reactions of molecules with an N-monosubstituted carbamate and an N,N-disubstituted carbamate with two kinds of aromatic compounds. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Regulation of pyruvate dehydrogenase activity and citric acid cycle intermediates during high cardiac power generation.

    Science.gov (United States)

    Sharma, Naveen; Okere, Isidore C; Brunengraber, Daniel Z; McElfresh, Tracy A; King, Kristen L; Sterk, Joseph P; Huang, Hazel; Chandler, Margaret P; Stanley, William C

    2005-01-15

    A high rate of cardiac work increases citric acid cycle (CAC) turnover and flux through pyruvate dehydrogenase (PDH); however, the mechanisms for these effects are poorly understood. We tested the hypotheses that an increase in cardiac energy expenditure: (1) activates PDH and reduces the product/substrate ratios ([NADH]/[NAD(+)] and [acetyl-CoA]/[CoA-SH]); and (2) increases the content of CAC intermediates. Measurements were made in anaesthetized pigs under control conditions and during 15 min of a high cardiac workload induced by dobutamine (Dob). A third group was made hyperglycaemic (14 mm) to stimulate flux through PDH during the high work state (Dob + Glu). Glucose and fatty acid oxidation were measured with (14)C-glucose and (3)H-oleate. Compared with control, the high workload groups had a similar increase in myocardial oxygen consumption ( and cardiac power. Dob increased PDH activity and glucose oxidation above control, but did not reduce the [NADH]/[NAD(+)] and [acetyl-CoA]/[CoA-SH] ratios, and there were no differences between the Dob and Dob + Glu groups. An additional group was treated with Dob + Glu and oxfenicine (Oxf) to inhibit fatty acid oxidation: this increased [CoA-SH] and glucose oxidation compared with Dob; however, there was no further activation of PDH or decrease in the [NADH]/[NAD(+)] ratio. Content of the 4-carbon CAC intermediates succinate, fumarate and malate increased 3-fold with Dob, but there was no change in citrate content, and the Dob + Glu and Dob + Glu + Oxf groups were not different from Dob. In conclusion, compared with normal conditions, at high myocardial energy expenditure (1) the increase in flux through PDH is regulated by activation of the enzyme complex and continues to be partially controlled through inhibition by fatty acid oxidation, and (2) there is expansion of the CAC pool size at the level of 4-carbon intermediates that is largely independent of myocardial fatty acid oxidation.

  10. A new generation of self-etching adhesives: comparison with traditional acid etch technique.

    Science.gov (United States)

    Holzmeier, Marcus; Schaubmayr, Martin; Dasch, Walter; Hirschfelder, Ursula

    2008-03-01

    The aim of this study was to determine the shear bond strength (SBS), etching pattern and depth, and debonding performance of several market-leading, self-etching (SE) adhesives primarily used in restorative dentistry (iBond, Clearfil S(3) Bond, Clearfil Protect Bond, AdheSE, XenoIII), two experimental self-etching adhesives (exp. Bond 1, exp. Bond 2) and one experimental self-etching cement (SE Zement) used with and without prior phosphoric acid-etching, and to compare them to an orthodontic self-etching product (Transbond Plus SE Primer) and to traditional acid-etch technique (Transbond XT Primer, phosphoric acid) All adhesives were applied on pumiced and embedded bovine incisors following the manufacturers' instructions. Then one bracket each (coated with Transbond XT composite) was bonded (n = 20). Transbond XT was polymerized for 20 s from the incisal and gingival sides using a halogen device positioned at a constant 5 mm from and a 45 degrees angle to the specimen. The specimens were stored in distilled water for 24 h at 37 degrees C before measuring SBS. The ARI (adhesive remnant index) for all specimens was determined from the sheared-off brackets of each. After conditioning, the surface texture was morphologically evaluated from scanning electron microscope (SEM) images, while the etching depth was determined using a confocal laser-scanning microscope (CLSM). All groups were tested for normal distribution and analyzed by applying ANOVA, Kruskal-Wallis or the t test. In addition, a Bonferroni correction was used. The median values of the SBS tests were: SE Zement 3.0 MPa, SE Zement preceded by phosphoric acid etching 11.2 MPa, experimental bond 1: 7.4 MPa, experimental bond 2: 5.6 MPa, iBond 8.1 MPa, Clearfil S(3) Bond 14.1 MPa, Clearfil Protect Bond 16.6 MPa, Clearfil SE Bond 15.9 MPa, AdheSE 16.0 MPa, XenoIII 16.1 MPa, Transbond SE Primer 20.7 MPa, acid-etching+Transbond XT Primer 21.0 MPa. With the exception of iBond, we observed no significant

  11. Simultaneous pollutant removal and electricity generation in denitrifying microbial fuel cell with boric acid-borate buffer solution.

    Science.gov (United States)

    Chen, Gang; Zhang, Shaohui; Li, Meng; Wei, Yan

    2015-01-01

    A double-chamber denitrifying microbial fuel cell (MFC), using boric acid-borate buffer solution as an alternative to phosphate buffer solution, was set up to investigate the influence of buffer solution concentration, temperature and external resistance on electricity generation and pollutant removal efficiency. The result revealed that the denitrifying MFC with boric acid-borate buffer solution was successfully started up in 51 days, with a stable cell voltage of 205.1 ± 1.96 mV at an external resistance of 50 Ω. Higher concentration of buffer solution favored nitrogen removal and electricity generation. The maximum power density of 8.27 W/m(3) net cathodic chamber was obtained at a buffer solution concentration of 100 mmol/L. An increase in temperature benefitted electricity generation and nitrogen removal. A suitable temperature for this denitrifying MFC was suggested to be 25 °C. Decreasing the external resistance favored nitrogen removal and organic matter consumption by exoelectrogens.

  12. 77 FR 2119 - WTO Dispute Settlement Proceeding Regarding China-Anti-Dumping and Countervailing Duty Measures...

    Science.gov (United States)

    2012-01-13

    ... From the Federal Register Online via the Government Publishing Office OFFICE OF THE UNITED STATES TRADE REPRESENTATIVE WTO Dispute Settlement Proceeding Regarding China--Anti-Dumping and Countervailing... Anti-dumping Agreement; Articles 10, 12.3, 12.4.1, 12.7, 12.8, 15.1, 15.2, 15.4, 15.5, 16.1, 19.4,...

  13. Why Has China Become a Target of Anti-dumping Activities?

    Institute of Scientific and Technical Information of China (English)

    李月芬

    2007-01-01

    Although the benefits of China’s trade expansion have been distributed much more broadly than those of some early industrialized nations,China has become the primary target of anti-dumping activities.Being a new and relatively efficient new rival in the global market may be an important reason for this.On the other hand,China’s development stage and her trade structure also place her in a disadvantageous position when it comes to anti-dumping activities.

  14. Tracking of the nuclear wavepacket motion in cyanine photoisomerization by ultrafast pump-dump-probe spectroscopy.

    Science.gov (United States)

    Wei, Zhengrong; Nakamura, Takumi; Takeuchi, Satoshi; Tahara, Tahei

    2011-06-01

    Understanding ultrafast reactions, which proceed on a time scale of nuclear motions, requires a quantitative characterization of the structural dynamics. To track such structural changes with time, we studied a nuclear wavepacket motion in photoisomerization of a prototype cyanine dye, 1,1'-diethyl-4,4'-cyanine, by ultrafast pump-dump-probe measurements in solution. The temporal evolution of wavepacket motion was examined by monitoring the efficiency of stimulated emission dumping, which was obtained from the recovery of a ground-state bleaching signal. The dump efficiency versus pump-dump delay exhibited a finite rise time, and it became longer (97 fs → 330 fs → 390 fs) as the dump pulse was tuned to longer wavelengths (690 nm → 950 nm → 1200 nm). This result demonstrates a continuous migration of the leading edge of the wavepacket on the excited-state potential from the Franck-Condon region toward the potential minimum. A slowly decaying feature of the dump efficiency indicated a considerable broadening of the wavepacket over a wide range of the potential, which results in the spread of a population distribution on the flat S(1) potential energy surface. The rapid migration as well as broadening of the wavepacket manifests a continuous nature of the structural dynamics and provides an intuitive visualization of this ultrafast reaction. We also discussed experimental strategies to evaluate reliable dump efficiencies separately from other ultrafast processes and showed a high capability and possibility of the pump-dump-probe method for spectroscopic investigation of unexplored potential regions such as conical intersections.

  15. Development and Optimization of a Novel Prolonged Release Formulation to Resist Alcohol-Induced Dose Dumping

    OpenAIRE

    Gujjar, Chaitanya Yogananda; Rallabandi, Balaramesha Chary; Gannu, Ramesh; Deulkar, Vallabh Subashrao

    2015-01-01

    Alcohol-induced dose dumping is a serious concern for the orally administered prolonged release dosage forms. The study was designed to optimize the independent variables, propylene glycol alginate (PGA), Eudragit RS PO (ERS) and coating in mucoadhesive quetiapine prolonged release tablets 200 mg required for preventing the alcohol-induced dose dumping. Optimal design based on response surface methodology was employed for the optimization of the composition. The formulations are evaluated for...

  16. Status of the OPAL microvertex detector and new radiation monitoring and beam dump system

    Science.gov (United States)

    Jong, Sijbrand de

    1998-11-01

    The status of the OPAL Phase III microvertex detector is discussed briefly. This is followed by a more detailed description of the OPAL microvertex detector radiation monitoring and beam dump system. This system measures AC currents induced by radiation on each passing of the beams in silicon diodes mounted close to the microvertex detector front-end electronics. Examples are shown for incidents leading to a beam dump trigger. The integrated radiation dose is also discussed.

  17. Potentials and problems of the utilization of waste dumps and pit-ponds

    Energy Technology Data Exchange (ETDEWEB)

    Gefferth, K.

    1986-01-01

    The surface damages caused by mining as well as the landscaping duties of the mining enterprises connected with the surface restoration are discussed. The damaging effects of waste dumps on the soil, groundwater and vegetation are enumerated. The possibilities of how to recultivate the waste dumps as well as of how to utilize the flue ash and slacks from thermal power plants are briefly summarized. The required uniform recultivation manner to be applied is emphasized.

  18. BIO-PEDO-GEOGRAPHYCAL REGARDS ON GARBAGE DUMPS FROM TOMEŞTI - IAŞI

    Directory of Open Access Journals (Sweden)

    C. Secu

    2005-10-01

    Full Text Available The garbage dump from Tomeşti (Iaşi represents a water and soil pollution source, as well as a peril for the population’s health. The study has pursued the analysis of some indicators of water quality (which have evidenced exceeds of the currently admitted values, the identification of the plant species from the garbage dump perimeter (table 1 and the presentation of the general geographical landscape.

  19. Impact of Mining Dump on the Accumulation and Mobility of Metals in the Bytomka River Sediments

    Directory of Open Access Journals (Sweden)

    Jabłońska-Czapla Magdalena

    2014-07-01

    Full Text Available The research aim was to determine the long-term impact of the mine waste stored at the coal waste dump Hałda Ruda on the content of heavy metals in the bottom sediments of the Bytomka River. It is a watercourse flowing along this coal waste dump and has been under its influence for over fifty years. The research also attempted to determine the seasonality of changes (2 years and mobility of selected elements.

  20. Identification and Investigation of Solid Waste Dump in Salem District

    Directory of Open Access Journals (Sweden)

    T. Subramani

    2014-12-01

    to facilitate implementation. The Note also includes a few case studies illustrating frameworks and implementation strategies adopted in other jurisdictions and sectors. Frameworks observed include legislation supporting municipalities to priorities regional initiatives to effectively use available resources as well as options for Creation of regional solid waste management authorities or entities empowered by law to undertake waste management activities over a region or state; Creation of solid waste management „regions‟; and Municipalities jointly constituting a company, or common authority, to implement a regional waste management project. The present work aims at identifying, locating and quantifying the industrial and domestic waste dump sites located in and around Salem urban and rural districts of Salem, Tamilnadu state, India. In our project we identify the suitable location and investigation for dumping yard which is not affecting the environment.

  1. Simulation of the Beam Dump for a High Intensity Electron Gun

    CERN Document Server

    Doebert, S; Lefevre, T; Pepitone, K

    2014-01-01

    The CLIC Drive Beam is a high-intensity pulsed electron beam. A test facility for the Drive Beam electron gun will soon be commissioned at CERN. In this contribution we outline the design of a beam dump / Faraday cup capable of resisting the beam’s thermal load. The test facility will operate initially up to 140 keV. At such low energies, the electrons are absorbed very close to the surface of the dump, leading to a large energy deposition density in this thin layer. In order not to damage the dump, the beam must be spread over a large surface. For this reason, a small-angled cone has been chosen. Simulations using Geant4 have been performed to estimate the distribution of energy deposition in the dump. The heat transport both within the electron pulse and between pulses has been modelled using finite element methods to check the resistance of the dump at high repetition rates. In addition, the possibility of using a moveable dump to measure the beam profile and emittance is discussed.

  2. Use of a garbage dump by some mammal species in the Majella massif (Abruzzo, Italy

    Directory of Open Access Journals (Sweden)

    Aldo Martina

    1997-12-01

    Full Text Available Abstract In several previous works the presence of urban solid wastes in the feeding habits of some animal species has been documented. This study was carried out to discover which species visit a rubbish dump located in an area of the Majella massif. Monthly nightime direct observations, from September 1990 to May 1992, revealed the presence of dogs Canis [lupus] familiaris, domestic cats Felis [silvestris] catus, wolves Canis lupus and red foxes Vulpes vulpes. The fox was the most frequently observed species. Fox visits to the dump were distributed more continuously during the entire period of the study then the other species. An "asymmetry analysis" was carried out to find out the animals' favourite time to use the dump. The analysis produced time lag values of 02:00 A.M. to 05:00 A.M. The wolf was observed the least. During the monthly observations a similar trend between the cat and wolf came to light. The two species also visited the dump at similar times (wolf: 07:00-11:00 P.M.; cat: 05:00-10:00 P.M.. Dog visits to the dump were less continuous in comparison with other species: no preferred time was revealed. Some environmental factors, related to the geographical area and management of the dump limited waste availability. This probably had an effect on the presence of the animals.

  3. Efficient Generation of Chemiluminescence during the reduction of manganese(IV) ions with lactic acid

    Science.gov (United States)

    Tsaplev, Yu. B.

    2016-12-01

    The kinetics and mechanism of chemiluminescence during the reduction of manganese(IV) ions with lactic acid in an H2SO4-AcOH medium are studied. Kinetic spectrophotometric measurements are used to determine the profiles of change in the concentrations of Mn(IV) and Mn(III) ions during the reaction. The results from kinetic spectrophotometric measurements are compared to the light yield kinetics. The quantum chemiluminescence and chemiexcitation yields reach record values.

  4. Hydrogen Generation from Catalytic Steam Reforming of Acetic Acid by Ni/Attapulgite Catalysts

    Directory of Open Access Journals (Sweden)

    Yishuang Wang

    2016-11-01

    Full Text Available In this research, catalytic steam reforming of acetic acid derived from the aqueous portion of bio-oil for hydrogen production was investigated using different Ni/ATC (Attapulgite Clay catalysts prepared by precipitation, impregnation and mechanical blending methods. The fresh and reduced catalysts were characterized by XRD, N2 adsorption–desorption, TEM and temperature program reduction (H2-TPR. The comprehensive results demonstrated that the interaction between active metallic Ni and ATC carrier was significantly improved in Ni/ATC catalyst prepared by precipitation method, from which the mean of Ni particle size was the smallest (~13 nm, resulting in the highest metal dispersion (7.5%. The catalytic performance of the catalysts was evaluated by the process of steam reforming of acetic acid in a fixed-bed reactor under atmospheric pressure at two different temperatures: 550 °C and 650 °C. The test results showed the Ni/ATC prepared by way of precipitation method (PM-Ni/ATC achieved the highest H2 yield of ~82% and a little lower acetic acid conversion efficiency of ~85% than that of Ni/ATC prepared by way of impregnation method (IM-Ni/ATC (~95%. In addition, the deactivation catalysts after reaction for 4 h were analyzed by XRD, TGA-DTG and TEM, which demonstrated the catalyst deactivation was not caused by the amount of carbon deposition, but owed to the significant agglomeration and sintering of Ni particles in the carrier.

  5. Remediation of Acid Generating Colliery Spoil Using Steel Slag - Case Studies

    Science.gov (United States)

    Ghataora, Gurmel S.; Ghazireh, Nizar; Hall, Nigel

    2015-06-01

    One of the legacies of the coal mining industry is the existence of numerous colliery spoil mounds. Run-off waters from some of these mounds result in oxidation of sulphur compounds causing pH to drop to perhaps as low as 2.5. At this pH, mobility for metals increases and it results in destruction of both flora and fauna. In order to reduce acidity, a number of solutions have been investigated with varying degree of success. A recent study to reduce acidity in spoil run-off water included the use of Basic Oxygen Steel slag. Its slow release of lime resulted in longer term remediation compared with other techniques. In addition to this, steel slag contains elements which are essential for plant growth and can be regarded as a weak fertiliser. This was substantiated in two field trials, which had the aim of not only remediating acidity from two different types of colliery spoils, but also to develop a composition that supports grass growth. The objectives were achieved at both sites and some of the results of over 5000 chemical tests conducted during these studies are reported in this paper.

  6. Remediation of Acid Generating Colliery Spoil Using Steel Slag – Case Studies

    Directory of Open Access Journals (Sweden)

    Ghataora Gurmel S.

    2015-06-01

    Full Text Available One of the legacies of the coal mining industry is the existence of numerous colliery spoil mounds. Run-off waters from some of these mounds result in oxidation of sulphur compounds causing pH to drop to perhaps as low as 2.5. At this pH, mobility for metals increases and it results in destruction of both flora and fauna. In order to reduce acidity, a number of solutions have been investigated with varying degree of success. A recent study to reduce acidity in spoil run-off water included the use of Basic Oxygen Steel slag. Its slow release of lime resulted in longer term remediation compared with other techniques. In addition to this, steel slag contains elements which are essential for plant growth and can be regarded as a weak fertiliser. This was substantiated in two field trials, which had the aim of not only remediating acidity from two different types of colliery spoils, but also to develop a composition that supports grass growth. The objectives were achieved at both sites and some of the results of over 5000 chemical tests conducted during these studies are reported in this paper.

  7. In situ hypochlorous acid generation for the treatment of distillery spentwash

    Energy Technology Data Exchange (ETDEWEB)

    Vijayaraghavan, K.; Ramanujam, T.K.; Balasubramanian, N. [Indian Inst. of Tech., Madras (India)

    1999-06-01

    Distillery spentwash constitutes a high organic load along with a high acid strength and color, which presents significant disposal or treatment problems. Treatment of high-strength organic waste can normally be achieved only by anaerobic processes, which are time-consuming and subject to environmental stress. Aerobic processes though faster are not economical for high-strength wastes because the aeration cost is prohibitive. High-strength organic waste like distillery spentwash can be effectively treated by electrolysis in the presence of sodium chloride. Because the graphite anode and stainless steel cathode zones were kept unseparated, chlorine produced during electrolysis forms hypochlorous acid. The hypochlorous acid thus formed oxidizes the organic matter present in the wastewater. The COD removal from the spentwash was found to be 99% for an initial COD concentration of 15,000 mg/l at the end of 240 min of electrolysis. The energy requirements were found to be 36 and 27 W{center_dot}h/l for treating 20 l of spentwash at 2.5 and 3% sodium chloride concentration, respectively. The observed energy difference is due to improved conductivity of the electrolyte.

  8. Geochemical and stable isotopic constraints on the generation and passive treatment of acidic, Fe-SO4 rich waters.

    Science.gov (United States)

    Matthies, Romy; Aplin, Andrew C; Boyce, Adrian J; Jarvis, Adam P

    2012-03-15

    Reducing and Alkalinity Producing Systems (RAPS) remediate net-acidic metalliferous mine drainage by creating anoxic conditions in which bacterial sulfate reduction (BSR) raises alkalinity and drives the precipitation of iron and other chalcophilic elements as sulfides. We report chemical and stable isotopic data from a study monitoring the biogeochemical processes involved in the generation of mine waters and their remediation by two RAPS. Sulfur isotopes show that sulfate in all mine waters has a common source (pyrite oxidation), whilst oxygen isotopes show that oxidation of pyritic sulfur is mediated by Fe(III)(aq). The isotopic composition of dissolved sulfide, combined with the sulfur and oxygen isotopic composition of sulfate in RAPS effluents, proves BSR and details its dual isotope systematics. The occurrence and isotopic composition of solid phase iron sulfides indicate the removal of reduced sulfur within the RAPS, with significant amounts of elemental sulfur indicating reoxidation steps. However, only 0 to 9% of solid phase iron occurs as Fe sulfides, with approximately 70% of the removed iron occurs as Fe(III) (hydr)oxides. Some of the (hydr)oxide is supplied to the wetland as solids and is simply filtered by the wetland substrate, playing no role in alkalinity generation or proton removal. However, the majority of iron is supplied as dissolved Fe(II), indicating that acid generating oxidation and hydrolysis reactions dominate iron removal. The overall contribution of BSR to the sulfur geochemistry in the RAPS is limited and sulfate retention is dominated by sulfate precipitation, comparable to aerobic treatment systems, and show that the proton acidity resulting from iron oxidation and hydrolysis must be subsequently neutralised by calcite dissolution and/or BSR deeper in the RAPS sediments. BSR is not as important as previously thought for metal removal in RAPS. The results have practical consequences for the design, treatment performance and long

  9. A new process to improve short-chain fatty acids and bio-methane generation from waste activated sludge.

    Science.gov (United States)

    Dong, Bin; Gao, Peng; Zhang, Dong; Chen, Yinguang; Dai, Lingling; Dai, Xiaohu

    2016-05-01

    As an important intermediate product, short-chain fatty acids (SCFAs) can be generated after hydrolysis and acidification from waste activated sludge, and then can be transformed to methane during anaerobic digestion process. In order to obtain more SCFA and methane, most studies in literatures were centered on enhancing the hydrolysis of sludge anaerobic digestion which was proved as un-efficient. Though the alkaline pretreatment in our previous study increased both the hydrolysis and acidification processes, it had a vast chemical cost which was considered uneconomical. In this paper, a low energy consumption pretreatment method, i.e. enhanced the whole three stages of the anaerobic fermentation processes at the same time, was reported, by which hydrolysis and acidification were both enhanced, and the SCFA and methane generation can be significantly improved with a small quantity of chemical input. Firstly, the effect of different pretreated temperatures and pretreatment time on sludge hydrolyzation was compared. It was found that sludge pretreated at 100°C for 60min can achieve the maximal hydrolyzation. Further, effects of different initial pHs on acidification of the thermal pretreated sludge were investigated and the highest SCFA was observed at initial pH9.0 with fermentation time of 6d, the production of which was 348.63mg COD/gVSS (6.8 times higher than the blank test) and the acetic acid was dominant acid. Then, the mechanisms for this new pretreatment significantly improving SCFA production were discussed. Finally, the effect of this low energy consumption pretreatment on methane generation was investigated.

  10. Generation and transcriptional programming of intestinal dendritic cells: essential role of retinoic acid

    DEFF Research Database (Denmark)

    Zeng, R.; Bscheider, M; Lahl, Katharina

    2016-01-01

    programs, and suppressing proinflammatory nuclear factor-κB-dependent gene expression. Thus, RA is required for transcriptional programming and maturation of intestinal cDC, and with GM-CSF and Flt3L provides a minimal environment for in vitro generation of intestinal cDC1- and cDC2-like cDC from...

  11. Maternal polyunsaturated fatty acid plasma levels during pregnancy and childhood adiposity. The Generation R Study

    Science.gov (United States)

    Vidakovic, Aleksandra Jelena; Gishti, Olta; Voortman, Trudy; Felix, Janine F.; Williams, Michelle A.; Hofman, Albert; Demmelmair, Hans; Koletzko, Berthold; Tiemeier, Henning; Jaddoe, Vincent WV; Gaillard, Romy

    2017-01-01

    Background Maternal polyunsaturated fatty acid (PUFA) levels during pregnancy may have persistent effects on growth and adiposity in the offspring. Suboptimal maternal diet during pregnancy might lead to fetal cardio-metabolic adaptations with persistent consequences in the offspring. Objective We examined the associations of maternal PUFA levels during pregnancy with childhood general and abdominal fat distribution measures. Design In a population-based prospective cohort study among 4,830 mothers and their children, we measured maternal second trimester n-3 and n-6 PUFA plasma levels. At the median age of 6.0 years (95% range, 5.6–7.9), we measured childhood body mass index, fat mass percentage, android/gynoid fat ratio with dual-energy x-ray absorptiometry, and pre-peritoneal abdominal fat area with ultrasound. Analyses were adjusted for maternal and childhood socio-demographic and lifestyle related characteristics. Results We observed that higher maternal total n-3 PUFA levels, and specifically eicosapentaenoic acid (EPA), docosapentaenoic acid (DPA), docosahexaenoic acid (DHA) levels, were associated with lower childhood total body fat percentage and lower android/gynoid fat mass ratio (p-values<0.05), but not with childhood body mass index and abdominal pre-peritoneal fat mass area. Higher maternal total n-6 PUFA levels and specifically dihomo-gamma linolenic acid (DGLA) were associated with a higher childhood total body fat percentage, android/gynoid fat mass ratio and abdominal pre-peritoneal fat mass area (p-values<0.05), but not with childhood body mass index. In line with these findings, a higher maternal n-6/n-3 PUFA ratio was associated with higher childhood total body and abdominal fat mass levels. Conclusions Lower maternal n-3 PUFA levels and higher n-6 PUFA levels during pregnancy are associated with higher total body fat and abdominal fat levels in childhood. Further studies are needed to replicate these observations and to explore the causality

  12. One-pot odourless synthesis of thioesters via in situ generation of thiobenzoic acids using benzoic anhydrides and thiourea

    Directory of Open Access Journals (Sweden)

    Mohammad Abbasi

    2015-07-01

    Full Text Available An efficient and odourless procedure for a one-pot synthesis of thioesters by the reaction of benzoic anhydrides, thiourea and various organic halides (primary, allylic, and benzylic or structurally diverse, electron-deficient alkenes (ketones, esters, and nitriles in the presence of Et3N has been developed. In this method, thiobenzoic acids were in situ generated from the reaction of thiourea with benzoic anhydrides, which were subjected to conjugate addition with electron-deficient alkenes or a nucleophilic displacement reaction with alkyl halides.

  13. Geochemical and stable isotopic constraints on the generation and passive treatment of acidic, Fe-SO{sub 4} rich waters

    Energy Technology Data Exchange (ETDEWEB)

    Matthies, Romy, E-mail: rmatthies@uwaterloo.ca [School of Civil Engineering and Geosciences, Newcastle University, Newcastle upon Tyne, NE1 7RU (United Kingdom); Aplin, Andrew C., E-mail: andrew.aplin@ncl.ac.uk [School of Civil Engineering and Geosciences, Newcastle University, Newcastle upon Tyne, NE1 7RU (United Kingdom); Boyce, Adrian J., E-mail: a.boyce@suerc.gla.ac.uk [Scottish Universities Environment Research Centre, East Kilbride, G75 0QF (United Kingdom); Jarvis, Adam P., E-mail: a.p.jarvis@ncl.ac.uk [School of Civil Engineering and Geosciences, Newcastle University, Newcastle upon Tyne, NE1 7RU (United Kingdom)

    2012-03-15

    Reducing and Alkalinity Producing Systems (RAPS) remediate net-acidic metalliferous mine drainage by creating anoxic conditions in which bacterial sulfate reduction (BSR) raises alkalinity and drives the precipitation of iron and other chalcophilic elements as sulfides. We report chemical and stable isotopic data from a study monitoring the biogeochemical processes involved in the generation of mine waters and their remediation by two RAPS. Sulfur isotopes show that sulfate in all mine waters has a common source (pyrite oxidation), whilst oxygen isotopes show that oxidation of pyritic sulfur is mediated by Fe(III){sub aq}. The isotopic composition of dissolved sulfide, combined with the sulfur and oxygen isotopic composition of sulfate in RAPS effluents, proves BSR and details its dual isotope systematics. The occurrence and isotopic composition of solid phase iron sulfides indicate the removal of reduced sulfur within the RAPS, with significant amounts of elemental sulfur indicating reoxidation steps. However, only 0 to 9% of solid phase iron occurs as Fe sulfides, with approximately 70% of the removed iron occurs as Fe(III) (hydr)oxides. Some of the (hydr)oxide is supplied to the wetland as solids and is simply filtered by the wetland substrate, playing no role in alkalinity generation or proton removal. However, the majority of iron is supplied as dissolved Fe(II), indicating that acid generating oxidation and hydrolysis reactions dominate iron removal. The overall contribution of BSR to the sulfur geochemistry in the RAPS is limited and sulfate retention is dominated by sulfate precipitation, comparable to aerobic treatment systems, and show that the proton acidity resulting from iron oxidation and hydrolysis must be subsequently neutralised by calcite dissolution and/or BSR deeper in the RAPS sediments. BSR is not as important as previously thought for metal removal in RAPS. The results have practical consequences for the design, treatment performance and long

  14. Characterizing toxic Cr(VI) contamination in chromite mine overburden dump and its bacterial remediation.

    Science.gov (United States)

    Dhal, B; Das, N N; Thatoi, H N; Pandey, B D

    2013-09-15

    Cr(VI) generated due to natural oxidation of chromite mineral present in chromite mine overburden (COB) dumps of Sukinda, India, has been characterized by different physico-chemical methods. The Cr(VI) was found to be associated with goethite matrix at a contamination level of 500 mg Cr(VI)kg(-1) of COB. Bacillus sp. isolated from the overburden sample exhibiting high tolerance to the hexavalent chromium, was used for the remediation of Cr(VI) in the overburden. The process was optimized while varying the parameters such as pH (2-9), pulp density (10-60%) and temperature (25-40 °C). Optimal reduction of more than 98% of Cr(VI) in the COB sample was achieved in 16 h at pH∼7.0 and 60% pulp density with the Bacillus sp. (4.05 × 10(7)cells mL(-1)) in absence of media. The exponential rate equation yielded rate constant value of 2.14 × 10(-1)h(-1) at 60% pulp density. The mode of bio-reduction of Cr(VI) in the overburden sample was established by FT-IR, XRD, EPMA and SEM-EDS studies.

  15. Complications of bariatric surgery: dumping syndrome, reflux and vitamin deficiencies.

    Science.gov (United States)

    Tack, Jan; Deloose, Eveline

    2014-08-01

    Bariatric surgical procedure are increasingly and successfully applied in the treatment of morbid obesity. Nevertheless, these procedures are not devoid of potential long-term complications. Dumping syndrome may occur after procedures involving at least partial gastric resection or bypass, including Roux-en-Y gastric bypass (RYGB) and sleeve gastrectomy. Diagnosis is based on clinical alertness and glucose tolerance testing. Treatment may involve dietary measures, acarbose and somatostatin analogues, or surgical reintervention for refractory cases. Gastro-esophageal reflux disease (GERD) can be aggravated by vertical banded gastroplasty and sleeve gastrectomy procedures, but pre-existing GERD may improve after RYGB and with adjustable gastric banding. Nutrient deficiencies constitute the most important long-term complications of bariatric interventions, as they may lead to haematological, metabolic and especially neurological disorders which are not always reversible. Malabsorptive procedures, poor postoperative nutrient intake, recurrent vomiting and poor compliance with vitamin supplement intake and regular follow-up are important risk factors. Preoperative nutritional assessment and rigourous postoperative follow-up plan with administration of multi-vitamin supplements and assessment of serum levels is recommended in all patients.

  16. Sustainable production of a new generation biofuel by lipase-catalyzed esterification of fatty acids from liquid industrial waste biomass.

    Science.gov (United States)

    Foukis, Athanasios; Gkini, Olga A; Stergiou, Panagiota-Yiolanda; Sakkas, Vasilios A; Dima, Agapi; Boura, Konstantina; Koutinas, Athanasios; Papamichael, Emmanuel M

    2017-08-01

    In this work we suggest a methodology comprising the design and use of cost-effective, sustainable, and environmentally friendly process for biofuel production compatible with the market demands. A new generation biofuel is produced using fatty acids, which were generated from acidogenesis of industrial wastes of bioethanol distilleries, and esterified with selected alcohols by immobilized Candida antarctica Lipase-B. Suitable reactors with significant parameters and conditions were studied through experimental design, and novel esterification processes were suggested; among others, the continuous removal of the produced water was provided. Finally, economically sustainable biofuel production was achieved providing high ester yield (<97%) along with augmented concentration (3.35M) in the reaction mixtures at relatively short esterification times, whereas the immobilized lipase maintained over 90% of its initial esterifying ability after reused for ten cycles. Copyright © 2017 Elsevier Ltd. All rights reserved.

  17. Stochastic multicomponent reactive transport analysis of low quality drainage release from waste rock piles: Controls of the spatial distribution of acid generating and neutralizing minerals

    Science.gov (United States)

    Pedretti, Daniele; Mayer, K. Ulrich; Beckie, Roger D.

    2017-06-01

    In mining environmental applications, it is important to assess water quality from waste rock piles (WRPs) and estimate the likelihood of acid rock drainage (ARD) over time. The mineralogical heterogeneity of WRPs is a source of uncertainty in this assessment, undermining the reliability of traditional bulk indicators used in the industry. We focused in this work on the bulk neutralizing potential ratio (NPR), which is defined as the ratio of the content of non-acid-generating minerals (typically reactive carbonates such as calcite) to the content of potentially acid-generating minerals (typically sulfides such as pyrite). We used a streamtube-based Monte-Carlo method to show why and to what extent bulk NPR can be a poor indicator of ARD occurrence. We simulated ensembles of WRPs identical in their geometry and bulk NPR, which only differed in their initial distribution of the acid generating and acid neutralizing minerals that control NPR. All models simulated the same principal acid-producing, acid-neutralizing and secondary mineral forming processes. We show that small differences in the distribution of local NPR values or the number of flow paths that generate acidity strongly influence drainage pH. The results indicate that the likelihood of ARD (epitomized by the probability of occurrence of pHuniversally safe; threshold to ensure non-acidic waters in practical applications. Our results suggest that new methods that explicitly account for mineralogical heterogeneity must be sought when computing effective (upscaled) NPR values at the scale of the piles.

  18. The influence of ashes in waste dump restoration. Evaluation of the vegetation; Influencias de las cenizas en la restauracion de escombreras. Evolucion de la vegetacion

    Energy Technology Data Exchange (ETDEWEB)

    Ibanez Guerra, J. F. [Grupo ENDESA. Madrid (Spain)

    1999-11-01

    Ash is solid waste from coal combustion which is produced at Power Plants in huge quantities, the disposal of which can cause serious problems. Countless studies have been done in order to give it a practical use, and the results give rise to hope regarding construction materials: cement, blocks, floor stabilization, etc. In recent years, research and test have taken place about the possibility of using ash as a neutralizer of acid soils, as well as a supplier of trace elements and micro nutrients necessary for the growth of plants. This paper deals with a test taken place on the Puentes Mine Dump, consisting mainly of adding different quantities of limestone and ash over a waste dump followed by a cover of grass. The close control of the experiment for three years, watching the behaviour of soil and vegetation, confirms that an adequate dose of ash applied upon acid or very acid soils, compensates this acidity on a medium an long term basis, and also improves in many cases soil texture, allowing therefore the setting of a very stable and persistent green cover. (Author)

  19. Singlet oxygen generation from the decomposition of alpha-linolenic acid hydroperoxide by cytochrome c and lactoperoxidase.

    Science.gov (United States)

    Sun, Shuna; Bao, Zhijuan; Ma, Huimin; Zhang, Deqing; Zheng, Xiaoping

    2007-06-01

    Generation of singlet oxygen is first investigated in the decomposition of polyunsaturated lipid peroxide, alpha-linolenic acid hydroperoxide (LAOOH), by heme-proteins such as cytochrome c and lactoperoxidase. Chemiluminescence and electron spin resonance methods are used to confirm the singlet oxygen generation and quantify its yield. Decomposition products of LAOOH are characterized by HPLC-ESI-MS, which suggests that singlet oxygen is produced via the decomposition of a linear tetraoxide intermediate (Russell's mechanism). Free radicals formed in the decomposition are also identified by the electron spin resonance technique, and the results show that peroxyl, alkyl, and epoxyalkyl radicals are involved. The changes of cytochrome c and lactoperoxidase in the reaction are monitored by UV-visible spectroscopy, revealing the action of a monoelectronic and two-electronic oxidation for cytochrome c and lactoperoxidase, respectively. These results suggest that cytochrome c causes a homolytic reaction of LAOOH, generating alkoxyl radical and then peroxyl radical, which in turn releases singlet oxygen following the Russell mechanism, whereas lactoperoxidase leads to a heterolytic reaction of LAOOH, and the resulting ferryl porphyryl radical of lactoperoxidase abstracts the hydrogen atom from LAOOH to give peroxyl radical and then singlet oxygen. This observation would be important for a better understanding of the damage mechanism of cell membrane or lipoprotein by singlet oxygen and various radicals generated in the peroxidation and decomposition of lipids induced by heme-proteins.

  20. Corrective Action Decision Document/Closure Report for Corrective Action Unit 511: Waste Dumps (Piles and Debris) Nevada Test Site, Nevada, Rev. No.: 0

    Energy Technology Data Exchange (ETDEWEB)

    Pastor, Laura

    2005-12-01

    This Corrective Action Decision Document/Closure Report has been prepared for Corrective Action Unit (CAU) 511, Waste Dumps (Piles & Debris). The CAU is comprised of nine corrective action sites (CASs) located in Areas 3, 4, 6, 7, 18, and 19 of the Nevada Test Site, Nevada, in accordance with the ''Federal Facility Agreement and Consent Order'' (1996). Corrective Action Unit 511 is comprised of nine CASs: (1) 03-08-02, Waste Dump (Piles & Debris); (2) 03-99-11, Waste Dump (Piles); (3) 03-99-12, Waste Dump (Piles & Debris); (4) 04-99-04, Contaminated Trench/Berm; (5) 06-16-01, Waste Dump (Piles & Debris); (6) 06-17-02, Scattered Ordnance/Automatic Weapons Range; (7) 07-08-01, Contaminated Mound; (8) 18-99-10, Ammunition Dump; and (9) 19-19-03, Waste Dump (Piles & Debris). The purpose of this Corrective Action Decision Document/Closure Report is to provide justification and documentation supporting the recommendation for closure of CAU 511 with no further corrective action. To achieve this, corrective action investigation (CAI) and closure activities were performed from January 2005 through August 2005, as set forth in the ''Corrective Action Investigation Plan for Corrective Action Unit 511: Waste Dumps (Piles & Debris)'' (NNSA/NSO, 2004) and Record of Technical Change No. 1. The purpose of the CAI was to fulfill the following data needs as defined during the data quality objective process: (1) Determine whether contaminants of concern (COCs) are present. (2) If COCs are present, determine their nature and extent. (3) Provide sufficient information and data to complete appropriate corrective actions. The CAU 511 dataset from the investigation results was evaluated based on the data quality indicator parameters. This evaluation demonstrated the quality and acceptability of the dataset for use in fulfilling the data quality objective data needs. Analytes detected during the CAI were evaluated against appropriate preliminary

  1. Stabilisation of acid generating waste rock with fly ash : immobilization of arsenic under alkaline conditions

    Energy Technology Data Exchange (ETDEWEB)

    Backstrom, M. [Orebro Univ. (Sweden). Man-Technology Environment Research Centre; Sartz, L. [Bergslagen, Kopparberg (Sweden)

    2010-07-01

    This study evaluated the potential for using fly ash as an alkaline material for increasing the pH and decreasing arsenic leaching from highly acidic mine waste. A wood ash sample known to contain high concentrations of both calcium and barium was tested with highly acidic mine waste samples that leached approximately 200 mg/L of arsenic at a liquid/solid ratio of 2. Samples were mixed with the fly ash. Control samples consisted of only mine waste, while the amended samples contained 10 g of mine waste and 10 g of wood ash. Ultra pure water was used as a leachant for both systems until the liquid-solid ratio that corresponded to 900 years of drainage for a waste pile that was 3 m high with an annual run-off of 300 mm. Results of the experimental study showed that the pH in the control increased from 1.7 to 2.7, while the pH in the amended system decreased from 12.6 to 11.5. Initial concentrations of arsenic decreased by almost 3 orders of magnitude in the amended systems. Co-precipitation with the iron, and the calcium arsenate precipitation process were identified as the principal arsenic immobilization mechanisms. The study demonstrated that under the right chemical conditions, alkaline amendments can be used to reduce arsenic leaching from mine wastes. 5 refs., 2 tabs., 1 fig.

  2. Microbial Ecology Assessment of Mixed Copper Oxide/Sulfide Dump Leach Operation

    Energy Technology Data Exchange (ETDEWEB)

    Bruhn, Debby Fox; Thompson, David Neal; Noah, Karl Scott

    1999-06-01

    Microbial consortia composed of complex mixtures of autotrophic and heterotrophic bacteria are responsible for the dissolution of metals from sulfide minerals. Thus, an efficient copper bioleaching operation depends on the microbial ecology of the system. A microbial ecology study of a mixed oxide/sulfide copper leaching operation was conducted using an "overlay" plating technique to differentiate and identify various bacterial consortium members of the genera Thiobacillus, “Leptospirillum”, “Ferromicrobium”, and Acidiphilium. Two temperatures (30°C and 45°C) were used to select for mesophilic and moderately thermophilic bacteria. Cell numbers varied from 0-106 cells/g dry ore, depending on the sample location and depth. After acid curing for oxide leaching, no viable bacteria were recovered, although inoculation of cells from raffinate re-established a microbial population after three months. Due to low the pH of the operation, very few non-iron-oxidizing acidophilic heterotrophs were recovered. Moderate thermophiles were isolated from the ore samples. Pregnant liquor solutions (PLS) and raffinate both contained a diversity of bacteria. In addition, an intermittently applied waste stream that contained high levels of arsenic and fluoride was tested for toxicity. Twenty vol% waste stream in PLS killed 100% of the cells in 48 hours, indicating substantial toxicity and/or growth inhibition. The data indicate that bacteria populations can recover after acid curing, and that application of the waste stream to the dump should be avoided. Monitoring the microbial ecology of the leaching operation provided significant information that improved copper recovery.

  3. The Decrease of n-3 Fatty Acid Energy Percentage in an Equicaloric Diet Fed to B6C3Fe Mice for Three Generations Elicits Obesity

    Directory of Open Access Journals (Sweden)

    Ingeborg Hanbauer

    2009-01-01

    Full Text Available Feeding mice, over 3 generations, an equicaloric diet in which α-linolenic acid, the dietary precursor of n-3 polyunsaturated fatty acids, was substituted by linoleic acid, the dietary precursor of n-6 polyunsaturated fatty acids, significantly increased body weight throughout life when compared with standard diet-fed mice. Adipogenesis observed in the low n-3 fatty acid mice was accompanied by a 6-fold upregulation of stearyl-coenzyme A desaturase 1 (Scd1, whose activity is correlated to plasma triglyceride levels. In total liver lipid and phospholipid extracts, the sum of n-3 fatty acids and the individual longer carbon chain acids, eicosapentaenoic acid (20:5n3, docosapentaenoic acid (22:5n3, and docosahexaenoic acid (22:6n3 were significantly decreased whereas arachidonic acid (20:4n6 was significantly increased. In addition, low n-3 fatty acid-fed mice had liver steatosis, heart, and kidney hypertrophy. Hence, reducing dietary α-linolenic acid, from 1.02 energy% to 0.16 energy% combined with raising linoleic acid intake resulted in obesity and had detrimental consequences on organ function.

  4. The effect of rehabilitation on the rate of oxidation of pyrite in a mine waste rock dump.

    Science.gov (United States)

    Harries, J R; Ritchie, A I

    1987-06-01

    Temperature profiles within a mine waste rock dump undergoing pyritic oxidation have been used to estimate the rate of oxidation and the sites where oxidation was occurring. The waste rock dump is located at the abandoned Rum Jungle mine site in Northern Australia and was a major source of pollution to the local river system. The dump was rehabilitated in 1983-84 by reshaping to reduce erosion and covering with clay and soil to reduce infiltration of water.Heat source distributions were derived from temperature profiles measured in the dump. The oxidation of pyritic material is the main cause of heat in the dump, hence the rate and location of oxidation can be obtained from the distribution of heat sources. A comparison of the heat source distributions before and after rehabilitation showed that rehabilitation greatly reduced or stopped the oxidation of pyrite in the dump.

  5. Evaluating the effect of vehicle impoundment policy on illegal construction and demolition waste dumping: Israel as a case study.

    Science.gov (United States)

    Seror, Nissim; Hareli, Shlomo; Portnov, Boris A

    2014-08-01

    Construction and demolition (C&D) waste dumped alongside roads and in open areas is a major source of soil and underground water pollution. Since 2006, Israeli ministry for environmental protection enacted a policy of vehicle impoundment (VI) according to which track drivers caught while dumping C&D waste illegally have their vehicles impounded. The present study attempted to determine whether the VI policy was effective in increasing the waste hauling to authorized landfill sites, thus limiting the number of illegal unloads of C&D waste at unauthorized landfill sites and in open areas. During the study, changes in the ratio between the monthly amount of C&D waste brought to authorized landfills sites and the estimated total amount of C&D waste generated in different administrative districts of Israel were examined, before and after the enactment of the 2006 VI policy. Short questionnaires were also distributed among local track drivers in order to determine the degree of awareness about the policy in question and estimate its deterrence effects. According to the study's results, in the district of Haifa, in which the VI policy was stringently enacted, the ratio between C&D waste, dumped in authorized landfill sites, and the total amount of generated C&D waste, increased, on the average, from 20% in January 2004 to 35% in October 2009, with the effect attributed to the number of vehicle impoundments being highly statistically significant (t=2.324; p0.1). The analysis of the questionnaires, distributed among the local truck drivers further indicated that the changes observed in the district of Haifa are not coincident and appeared to be linked to the VI policy's enactment. In particular, 62% of the truck drivers, participated in the survey, were aware of the policy and 47% of them personally knew a driver whose vehicle was impounded. Furthermore, the drivers estimated the relative risk of being caught for unloading C&D waste in unauthorized sites, on the average, as

  6. Chemical, mineralogical and morphological changes in weathered coal fly ash: a case study of a brine impacted wet ash dump.

    Science.gov (United States)

    Eze, Chuks P; Nyale, Sammy M; Akinyeye, Richard O; Gitari, Wilson M; Akinyemi, Segun A; Fatoba, Olanrewaju O; Petrik, Leslie F

    2013-11-15

    The mobility of species in coal fly ash (FA), co-disposed with brine using a wet ash handling system, from a coal fired power generating utility has been investigated. The study was conducted in order to establish if the wet ash dump could act as a salt sink. The ash was dumped as a slurry with 5:1 brine/ash ratio and the dam was in operation for 20 years. Weathered FA samples were collected along three cores at a South African power station's wet ash dump by drilling and sampling the ash at 1.5 m depth intervals. A fresh FA sample was collected from the hoppers in the ash collection system at the power station. Characterization of both fresh FA and weathered FA obtained from the drilled cores S1, S2 and S3 was done using X-ray diffraction (XRD) for mineralogy, X-ray fluorescence (XRF) for chemical composition and scanning electron microscopy (SEM) for morphology. Analysis of extracted pore water and moisture content determination of the fresh FA and the weathered FA obtained from the drilled cores S1, S2 and S3 was done in order to evaluate the physico-chemical properties of the FA. The XRD analysis revealed changes in mineralogy along cores S1, S2 and S3 in comparison with the fresh FA. The SEM analysis revealed spherical particles with smooth outer surfaces for the fresh FA while the weathered ash samples obtained from cores S1, S2 and S3 consisted of agglomerated, irregular particles appearing to be encrusted, etched and corroded showing that weathering and leaching had occurred in the ash dump. The moisture content (MC) analysis carried out on the fresh FA (1.8%) and the weathered FA obtained from the drilled cores S1 (41.4-73.2%), S2 (30.3-94%) and S3 (21.7-76.2%)indicated that the ash dump was water logged hence creating favourable conditions for leaching of species. The fresh fly ash (n = 3) had a pH of 12.38 ± 0.15, EC value of 4.98 ± 0.03 mS/cm and TDS value of 2.68 ± 0.03 g/L, the pH of the drilled core S1 (n = 45) was 10.04 ± 0

  7. Sum Frequency Generation Vibrational Spectroscopy of Adsorbed Amino Acids, Peptides and Proteins of Hydrophilic and Hydrophobic Solid-Water Interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Holinga IV, George Joseph [Univ. of California, Berkeley, CA (United States)

    2010-09-01

    Sum frequency generation (SFG) vibrational spectroscopy was used to investigate the interfacial properties of several amino acids, peptides, and proteins adsorbed at the hydrophilic polystyrene solid-liquid and the hydrophobic silica solid-liquid interfaces. The influence of experimental geometry on the sensitivity and resolution of the SFG vibrational spectroscopy technique was investigated both theoretically and experimentally. SFG was implemented to investigate the adsorption and organization of eight individual amino acids at model hydrophilic and hydrophobic surfaces under physiological conditions. Biointerface studies were conducted using a combination of SFG and quartz crystal microbalance (QCM) comparing the interfacial structure and concentration of two amino acids and their corresponding homopeptides at two model liquid-solid interfaces as a function of their concentration in aqueous solutions. The influence of temperature, concentration, equilibration time, and electrical bias on the extent of adsorption and interfacial structure of biomolecules were explored at the liquid-solid interface via QCM and SFG. QCM was utilized to quantify the biological activity of heparin functionalized surfaces. A novel optical parametric amplifier was developed and utilized in SFG experiments to investigate the secondary structure of an adsorbed model peptide at the solid-liquid interface.

  8. Induction of Heat Resistance in Wheat Coleoptiles by 4-Hydroxybenzoic Acid: Connection with the Generation of Reactive Oxygen Species

    Directory of Open Access Journals (Sweden)

    Yastreb T.O.

    2012-08-01

    Full Text Available The effect of 4-hydroxybenzoic acid (4-HBA on resistance of coleoptiles of 4-day-old etiolated seedlings of wheat (Triticum aestivum L., cv. Elegiya to damaging heating (10 min at 43°C and possible dependence of this effect on changes in the activities of enzymes producing and scavenging reactive oxygen species (ROS were investigated. Treatment of coleoptiles with 10 μM 4-HBA resulted in enhancing of superoxide anion-radical generation and maintaining of hydrogen peroxide content there in. Increasing of the rate of ROS production was significantly suppressed by inhibitors of NADPH oxidase (α-naphthol and peroxidase (salicylhydroxamic acid. Under the influence of 4-HBA the activities of superoxide dismutase and apoplastic forms of peroxidase were increased. The activity of oxalate oxidase and catalase has not changed. Exogenous 4-HBA improved coleoptiles heat resistance and its effects were comparable with the influence of salicylic acid. Antioxidant agent BHT (butylhydroxytoluene, inhibitors of NADPH oxidase and peroxidase significantly reduced the increasing of wheat coleoptiles heat resistance, caused by 4-HBA action. It was concluded that 4-HBA influence on coleoptiles heat resistance is realized with the ROS mediation.

  9. Selective Hydrogen Generation from Formic Acid with Well-Defined Complexes of Ruthenium and Phosphorus-Nitrogen PN(3) -Pincer Ligand.

    Science.gov (United States)

    Pan, Yupeng; Pan, Cheng-Ling; Zhang, Yufan; Li, Huaifeng; Min, Shixiong; Guo, Xunmun; Zheng, Bin; Chen, Hailong; Anders, Addison; Lai, Zhiping; Zheng, Junrong; Huang, Kuo-Wei

    2016-05-01

    An unsymmetrically protonated PN(3) -pincer complex in which ruthenium is coordinated by one nitrogen and two phosphorus atoms was employed for the selective generation of hydrogen from formic acid. Mechanistic studies suggest that the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150 h with a turnover number over 1 million was achieved.

  10. A summary of the test procedures and operational details of an ocean dumping pollution monitoring experiment conducted 7 October 1976

    Science.gov (United States)

    Hypes, W. D.; Wallace, J. W.; Gurganus, E. A.

    1977-01-01

    A remote sensor experiment was conducted at a sewage sludge dump site off the Delaware/Maryland coast. Two aircraft serving as remote sensor platforms flew over the dump site during a sludge dump. One aircraft carried a multispectral scanner and the other aircraft carried a rapid scanning spectrometer. Data from sea-truth stations were collected concurrent with overpasses of the aircraft. All sensors were operational and produced good digital data.

  11. Lewis acid-promoted hydrofluorination of alkynyl sulfides to generate α-fluorovinyl thioethers

    Directory of Open Access Journals (Sweden)

    Davide Bello

    2015-10-01

    Full Text Available A new method for the preparation of α-fluorovinyl thioethers is reported which involves the hydrofluorination of alkynyl sulfides with 3HF·Et3N, a process that requires Lewis acid activation using BF3·Et2O and TiF4. The method gives access to a range of α-fluorovinyl thioethers, some in high stereoselectivity with the Z-isomer predominating over the E-isomer. The α-fluorovinyl thioether motif has prospects as a steric and electronic mimetic of thioester enols and enolates, important intermediates in enzymatic C–C bond forming reactions. The method opens access to appropriate analogues for investigations in this direction.

  12. Evaluation of Gas-Cooled Pressurized Phosphoric Acid Fuel Cells for Electric Utility Power Generation

    Science.gov (United States)

    Faroque, M.

    1983-01-01

    Gas cooling is a more reliable, less expensive and a more simple alternative to conventional liquid cooling for heat removal from the phosphoric acid fuel cell (PAFC). The feasibility of gas-cooling was already demonstrated in atmospheric pressure stacks. Theoretical and experimental investigations of gas-cooling for pressurized PAFC are presented. Two approaches to gas cooling, Distributed Gas-Cooling (DIGAS) and Separated Gas-Cooling (SGC) were considered, and a theoretical comparison on the basis of cell performance indicated SGC to be superior to DIGAS. The feasibility of SGC was experimentally demonstrated by operating a 45-cell stack for 700 hours at pressure, and determining thermal response and the effect of other related parameters.

  13. Generation and characterization of low phytic acid germplasm in rice (Oryza sativa L.).

    Science.gov (United States)

    Liu, Qing-Long; Xu, Xiu-Hong; Ren, Xue-Liang; Fu, Hao-Wei; Wu, Dian-Xing; Shu, Qing-Yao

    2007-03-01

    Phytic acid (PA, myo-inositol 1,2,3,4,5,6-hexakisphosphate), or its salt form, phytate, is commonly regarded as the major anti-nutritional component in cereal and legume grains. Breeding of low phytic acid (lpa) crops has recently been considered as a potential way to increase nutritional quality of crop products. In this study, eight independent lpa rice mutant lines from both indica and japonica subspecies were developed through physical and chemical mutagenesis. Among them, five are non-lethal while the other three are homozygous lethal. None of the lethal lines could produce homozygous lpa plants through seed germination and growth under field conditions, but two of them could be rescued through in vitro culture of mature embryos. The non-lethal lpa mutants had lower PA content ranging from 34 to 64% that of their corresponding parent and four of them had an unchanged total P level. All the lpa mutations were inherited in a single recessive gene model and at least four lpa mutations were identified mutually non-allelic, while the other two remain to be verified. One mutation was mapped on chromosome 2 between microsatellite locus RM3542 and RM482, falling in the same region as the previously mapped lpa1-1 locus did; another lpa mutation was mapped on chromosome 3, tightly linked to RM3199 with a genetic distance of 1.198 cM. The latter mutation was very likely to have happened to the LOC_Os03g52760, a homolog of the maize myo-inositol kinase (EC 2.7.1.64) gene. The present work greatly expands the number of loci that could influence the biosynthesis of PA in rice, making rice an excellent model system for research in this area.

  14. Fortification of reduced-fat Cheddar cheese with n-3 fatty acids: effect on off-flavor generation.

    Science.gov (United States)

    Martini, S; Thurgood, J E; Brothersen, C; Ward, R; McMahon, D J

    2009-05-01

    The objective of this study was to fortify 50% reduced fat Cheddar cheese with n-3 fatty acids and evaluate whether this fortification generated specific off-flavors in the cheese. Docosahexaenoic (DHA) and eicosapentaenoic (EPA) fatty acids were added to the cheese to obtain 3 final fortification levels [18, 35, and 71 mg of DHA/EPA per serving size (28 g) of cheese] representing 10, 20, and 40% of the suggested daily intake level for DHA/EPA. The presence of oxidized, rancid, and fishy flavors as a function of fortification level and cheese aging (6 mo) was evaluated using a sensory descriptive panel. No differences were found in the oxidized and rancid flavors as a consequence of DHA/EPA fortification, with only slight intensities of these flavors. The presence of fishy off-flavor was dependent on the fortification level. Cheeses with low fortification levels (18 and 35 mg of DHA/EPA per serving size) did not develop significant fishy off-flavor compared with the control, whereas at the highest fortification level (71 mg of DHA/EPA per serving size) the fishy off-flavor was significantly stronger in young cheeses. The fishy flavor decreased as a function of age and became nonsignificant compared with the control at 3 mo of storage. Even though fishy flavors were detected in the fortified cheeses, the DHA/EPA content during storage remained constant and complied with the suggested values for food fortification. Results obtained from this research indicate that 50% reduced-fat Cheddar cheese aged for 3 mo can be used as a vehicle for delivery of n-3 fatty acids without generation of off-flavors.

  15. A Review On Dump Slope Stabilization By Revegetation With Reference To Indigenous Plant

    Directory of Open Access Journals (Sweden)

    Vibhash Ranjan

    2015-08-01

    Full Text Available Abstract The waste sub-grade ROM and Fines dumps are characterized by high rock fragment contents low moisture retention capacity higher bulk density low nutrients lower pH and elevated metal concentrations. Use of suitable revegetation programme that require the selection of right type of plants to be used vis--vis the site condition and characteristics can enhance the long term stability both mechanical and ecological of dumps waste sub-grade ROM and fines through providing vegetative cover to control soil erosion amp gully formation consolidation of dump top amp side surfaces binding the loose particles through intricate roof system etc. This paper overviews the roles of Revegetation programme that can be used where vegetation is considered to be the long term answer to slope protection and erosion control. Various revegetation processes like Coir matting Lemmon Grass Vetiver Grass and Indigenous plant etc. may find a wide range of usage in Iron ore mines for dump stabilization.Miyawaki method of plantation is more effective than the conventional method of plantation. This will lead to co-existence of plants and as a matter of fact each plant draws from the other vital nutrients and they grow to become strong and healthy. The Miyawaki Plantation technique aim at Survival at fittest the area undergone such plantation have an ecology of their own. The Indigenous Plant has good binding capacity and helps to control soil erosion as well as improve the dump stability. Indigenous plant species like as Shorea robusta Sal CROTON ROXBURGHII Dal-bergia Sisoo SHISHAM KARANJ Azadirachta NEEM etc. The growth of indigenous plants is depending upon the soil quality as well as the organic matter of the dump material. The leaf debris plays important role for improving the organic matter of dump material for successfully implementation of revegetation programme.

  16. Electrocemical Production of Ocean Alkalinity for Carbon Dioxide and Acid Mitigation, and Hydrogen Generation

    Science.gov (United States)

    Rau, G. H.

    2008-12-01

    Various schemes have been proposed to increase air-to-sea CO2 transfer and storage, including the addition of alkalinity to the ocean. Examples include the addition of: Ca(OH)2 derived from the thermal calcination of limestone (Kheshgi, 1995), NaOH from the electrochemical splitting of salt (House et al., 2007), and CaCO3 to carbonate-undersaturated waters (Harvey, 2008). Diluted in the ocean (to pH1/2O2+H2+Ca(HCO3)2aq. Laboratory experiments showed that such a system can generate excess alkalinity and elevated pH in seawater that subsequently allowed the absorption of 0.8 mM atmospheric CO2. Thus at larger scales, wind-, wave-, or solar-powered, fixed/floating platforms at the shoreline, in coastal waters, or in the open ocean might be employed to electrochemically increase ocean alkalinity. Such platforms would then: 1) enhance the ocean's natural absorption of atmospheric CO2, 2) help neutralize or offset the effects of ongoing ocean acidification, via the calcium hydroxide and/or bicarbonate production, and 3) generate carbon-negative H2 in the ratio 22kg CO2 absorbed/kg H2 produced.

  17. Early dumping syndrome is not a complication but a desirable feature of Roux-en-Y gastric bypass surgery.

    Science.gov (United States)

    Laurenius, A; Engström, M

    2016-10-01

    Early dumping syndrome after gastric bypass surgery due to rapid delivery of hyperosmolar nutrients into the bowel causing intense symptoms is often described as a complication. Twelve patients, mean age 47 years, were interviewed approximately 9 years post-operation. The interviews were audiotaped and transcribed verbatim, followed by an inductive content analysis to reveal patients' experience of the dumping syndrome. The core category 'Dumping syndrome is a positive consequence of Roux-en-Y gastric bypass surgery and a tool to control food intake' was identified based on the following four sub-categories: (i) 'The multidimensional emergence and effects of dumping syndrome', (ii) 'Dumping syndrome as something positive although unpleasant', (iii) 'Developing coping mechanisms and ingenious strategies' and (iv) 'My own fault if I expose myself to dumping syndrome'. From the patients' perspective, dumping syndrome gives control over food intake; although the symptoms were unpleasant, patients considered dumping syndrome as a positive protection against over-consumption. Hence, healthcare professionals should not present dumping syndrome as a complication but rather as an aid to control eating behaviour and excessive food intake.

  18. Ranking criteria for assessment of municipal solid waste dumping sites

    Directory of Open Access Journals (Sweden)

    Mahmood Khalid

    2017-03-01

    Full Text Available Priority wise channelization of resources is the key to successful environmental management, especially when funds are limited. The study in hand has successfully developed an algorithmic criterion to compare hazardous effects of Municipal Solid Waste (MSW dumping sites quantitatively. It is a Multi Criteria Analysis (MCA that has made use of the scaling function to normalize the data values, Analytical Hierarchy Process (AHP for assigning weights to input parameters showing their relevant importance, and Weighted Linear Combination (WLC for aggregating the normalized scores. Input parameters have been divided into three classes namely Resident’s Concerns, Groundwater Vulnerability and Surface Facilities. Remote Sensing data and GIS analysis were used to prepare most of the input data. To elaborate the idea, four dumpsites have been chosen as case study, namely Old-FSD, New-FSD, Saggian and Mahmood Booti. The comparison has been made first at class levels and then class scores have been aggregated into environmental normalized index for environmental impact ranking. The hierarchy of goodness found for the selected sites is New-FSD > Old-FSD > Mahmood Booti > Saggian with comparative scores of goodness to environment as 36.67, 28.43, 21.26 and 13.63 respectively. Flexibility of proposed model to adjust any number of classes and parameters in one class will be very helpful for developing world where availability of data is the biggest hurdle in research based environmental sustainability planning. The model can be run even without purchasing satellite data and GIS software, with little inaccuracy, using imagery and measurement tools provided by Google Earth.

  19. Restoration of fly ash dump through biological interventions.

    Science.gov (United States)

    Juwarkar, Asha A; Jambhulkar, Hemlata P

    2008-04-01

    Field experiment on 10 ha area of fly ash dump was conducted to restore and revegetate it using biological interventions, which involves use of organic amendment, selection of suitable plant species along with specialized nitrogen fixing strains of biofertilizer. The results of the study indicated that amendment with farm yard manure at 50 t/ha improved the physical properties of fly ash such as maximum water holding capacity from 40.0 to 62.42% while porosity improved from 56.78 to 58.45%. The nitrogen content was increased by 4.5 times due to addition of nitrogen fixing strains of Bradyrhizobium and Azotobacter species, while phosphate content was increased by 10.0 times due to addition of VAM, which helps in phosphate immobilization. Due to biofertilizer inoculation different microbial groups such as Rhizobium, Azotobacter and VAM spores, which were practically absent in fly ash improved to 7.1 x 10(7), 9.2 x 10(7) CFU/g and 35 VAM spores/10 g of fly ash, respectively. Inoculation of biofertilizer and application of FYM helped in reducing the toxicity of heavy metals such as cadmium, copper, nickel and lead which were reduced by 25, 46, 48 and 47%, respectively, due to the increased organic matter content in the fly ash which complexes the heavy metals thereby decreasing the toxicity of metals. Amendment of fly ash with FYM and biofertilizer helped in profuse root development showing 15 times higher growth in Dendrocalamus strictus plant as compared to the control. Thus amendment and biofertilizer application provided better supportive material for anchorage and growth of the plant.

  20. THE MECHANICAL AND SHIELDING DESIGN OF A PORTABLE SPECTROMETER AND BEAM DUMP ASSEMBLY AT BNLS ACCELERATOR TEST FACILITY.

    Energy Technology Data Exchange (ETDEWEB)

    HU,J.P.; CASEY,W.R.; HARDER,D.A.; PJEROV,S.; RAKOWSKY,G.; SKARITKA,J.R.

    2002-09-05

    A portable assembly containing a vertical-bend dipole magnet has been designed and installed immediately down-beam of the Compton electron-laser interaction chamber on beamline 1 of the Accelerator Test Facility (ATF) at Brookhaven National Laboratory (BNL). The water-cooled magnet designed with field strength of up to 0.7 Tesla will be used as a spectrometer in the Thompson scattering and vacuum acceleration experiments, where field-dependent electron scattering, beam focusing and energy spread will be analyzed. This magnet will deflect the ATF's 60 MeV electron-beam 90{sup o} downward, as a vertical beam dump for the Compton scattering experiment. The dipole magnet assembly is portable, and can be relocated to other beamlines at the ATF or other accelerator facilities to be used as a spectrometer or a beam dump. The mechanical and shielding calculations are presented in this paper. The structural rigidity and stability of the assembly were studied. A square lead shield surrounding the assembly's Faraday Cup was designed to attenuate the radiation emerging from the 1 inch-copper beam stop. All photons produced were assumed to be sufficiently energetic to generate photoneutrons. A safety evaluation of groundwater tritium contamination due to the thermal neutron capturing by the deuterium in water was performed, using updated Monte Carlo neutron-photon coupled transport code (MCNP). High-energy neutron spallation, which is a potential source to directly generate radioactive tritium and sodium-22 in soil, was conservatively assessed in verifying personal and environmental safety.

  1. Evaluation of selected static methods used to estimate element mobility, acid-generating and acid-neutralizing potentials associated with geologically diverse mining wastes

    Science.gov (United States)

    Hageman, Philip L.; Seal, Robert R.; Diehl, Sharon F.; Piatak, Nadine M.; Lowers, Heather

    2015-01-01

    A comparison study of selected static leaching and acid–base accounting (ABA) methods using a mineralogically diverse set of 12 modern-style, metal mine waste samples was undertaken to understand the relative performance of the various tests. To complement this study, in-depth mineralogical studies were conducted in order to elucidate the relationships between sample mineralogy, weathering features, and leachate and ABA characteristics. In part one of the study, splits of the samples were leached using six commonly used leaching tests including paste pH, the U.S. Geological Survey (USGS) Field Leach Test (FLT) (both 5-min and 18-h agitation), the U.S. Environmental Protection Agency (USEPA) Method 1312 SPLP (both leachate pH 4.2 and leachate pH 5.0), and the USEPA Method 1311 TCLP (leachate pH 4.9). Leachate geochemical trends were compared in order to assess differences, if any, produced by the various leaching procedures. Results showed that the FLT (5-min agitation) was just as effective as the 18-h leaching tests in revealing the leachate geochemical characteristics of the samples. Leaching results also showed that the TCLP leaching test produces inconsistent results when compared to results produced from the other leaching tests. In part two of the study, the ABA was determined on splits of the samples using both well-established traditional static testing methods and a relatively quick, simplified net acid–base accounting (NABA) procedure. Results showed that the traditional methods, while time consuming, provide the most in-depth data on both the acid generating, and acid neutralizing tendencies of the samples. However, the simplified NABA method provided a relatively fast, effective estimation of the net acid–base account of the samples. Overall, this study showed that while most of the well-established methods are useful and effective, the use of a simplified leaching test and the NABA acid–base accounting method provide investigators fast

  2. Salvianolic Acid B Inhibits Aβ Generation by Modulating BACE1 Activity in SH-SY5Y-APPsw Cells

    Directory of Open Access Journals (Sweden)

    Ying Tang

    2016-06-01

    Full Text Available Alzheimer’s disease (AD is a neurodegenerative disease in humans. The accumulation of amyloid-β (Aβ plays a critical role in the pathogenesis of AD. Previous studies indicated that Salvianolic acid B (SalB could ameliorate Aβ-induced memory impairment. However, whether SalB could influence the generation of Aβ is unclear. Here, we show that SalB (25, 50, or 100 µM reduces the generation of Aβ40 and Aβ42 in culture media by decreasing the protein expressions of BACE1 and sAPPβ in SH-SY5Y-APPsw cells. Meanwhile, SalB increases the levels of ADAM10 and sAPPα in the cells. However, SalB has no impact on the protein expressions of APP and PS1. Moreover, SalB attenuates oxidative stress and inhibits the activity of GSK3β, which might be related to the suppression of BACE1 expression and amyloidogenesis. Our study suggests that SalB is a promising therapeutic agent for AD by targeting Aβ generation.

  3. Salvianolic Acid B Inhibits Aβ Generation by Modulating BACE1 Activity in SH-SY5Y-APPsw Cells.

    Science.gov (United States)

    Tang, Ying; Huang, Dan; Zhang, Mei-Hua; Zhang, Wen-Sheng; Tang, Yu-Xin; Shi, Zheng-Xiang; Deng, Li; Zhou, Dai-Han; Lu, Xin-Yi

    2016-06-01

    Alzheimer's disease (AD) is a neurodegenerative disease in humans. The accumulation of amyloid-β (Aβ) plays a critical role in the pathogenesis of AD. Previous studies indicated that Salvianolic acid B (SalB) could ameliorate Aβ-induced memory impairment. However, whether SalB could influence the generation of Aβ is unclear. Here, we show that SalB (25, 50, or 100 µM) reduces the generation of Aβ40 and Aβ42 in culture media by decreasing the protein expressions of BACE1 and sAPPβ in SH-SY5Y-APPsw cells. Meanwhile, SalB increases the levels of ADAM10 and sAPPα in the cells. However, SalB has no impact on the protein expressions of APP and PS1. Moreover, SalB attenuates oxidative stress and inhibits the activity of GSK3β, which might be related to the suppression of BACE1 expression and amyloidogenesis. Our study suggests that SalB is a promising therapeutic agent for AD by targeting Aβ generation.

  4. Statistical analysis plan for the WOMAN-ETAPlaT study: Effect of tranexamic acid on platelet function and thrombin generation.

    Science.gov (United States)

    Dallaku, Kastriot; Shakur, Haleema; Edwards, Phil; Beaumont, Danielle; Roberts, Ian; Huque, Sumaya; Delius, Maria; Mansmann, Ulrich

    2016-12-15

    Background. Postpartum haemorrhage (PPH) is a potentially life-threatening complication for women, and the leading cause of maternal mortality. Tranexamic acid (TXA) is an antifibrinolytic used worldwide to treat uterine haemorrhage and to reduce blood loss in general surgery. TXA may have effects on thrombin generation, platelet function and coagulation factors as a result of its inhibition on the plasmin. Methods. WOMAN ETAPlaT is a sub-study of the World Maternal Antifibrinolitic trial (WOMAN trial). All adult women clinically diagnosed with PPH after a vaginal delivery or caesarean section, are eligible for inclusion in the study. Blood samples will be collected at the baseline and 30 minutes after the first dose of study treatment is given. Platelet function will be evaluated in whole blood immediately after sampling with Multiplate® tests (ADPtest and TRAPtest). Thrombin generation, fibrinogen, D-dimer, and coagulation factors vW, V and VIII will be analysed using platelet poor plasma. Results. Recruitment to WOMAN ETAPlaT started on 04 November 2013 and closed on 13 January 2015, during this time  188 patients were recruited. The final participant follow-up was completed on 04 March 2015. This article introduces the statistical analysis plan for the study, without reference to unblinded data.   Conclusion. The data from this study will provide evidence for the effect of TXA on thrombin generation, platelet function and coagulation factors in women with PPH. Trial registration: ClinicalTrials.gov Identifier: NCT00872469; ISRCTN76912190.

  5. Photocatalytic hydrogen generation from hydriodic acid using methylammonium lead iodide in dynamic equilibrium with aqueous solution

    Science.gov (United States)

    Park, Sunghak; Chang, Woo Je; Lee, Chan Woo; Park, Sangbaek; Ahn, Hyo-Yong; Nam, Ki Tae

    2017-01-01

    The solar-driven splitting of hydrohalic acids (HX) is an important and fast growing research direction for H2 production. In addition to the hydrogen, the resulting chemicals (X2/X3-) can be used to propagate a continuous process in a closed cycle and are themselves useful products. Here we present a strategy for photocatalytic hydrogen iodide (HI) splitting using methylammonium lead iodide (MAPbI3) in an effort to develop a cost-effective and easily scalable process. Considering that MAPbI3 is a water-soluble ionic compound, we exploit the dynamic equilibrium of the dissolution and precipitation of MAPbI3 in saturated aqueous solutions. The I- and H+ concentrations of the aqueous solution are determined to be the critical parameters for the stabilization of the tetragonal MAPbI3 phase. Stable and efficient H2 production under visible light irradiation was demonstrated. The solar HI splitting efficiency of MAPbI3 was 0.81% when using Pt as a cocatalyst.

  6. Effect of the chlorinated washing of minimally processed vegetables on the generation of haloacetic acids.

    Science.gov (United States)

    Cardador, Maria Jose; Gallego, Mercedes

    2012-07-25

    Chlorine solutions are usually used to sanitize fruit and vegetables in the fresh-cut industry due to their efficacy, low cost, and simple use. However, disinfection byproducts such as haloacetic acids (HAAs) can be formed during this process, which can remain on minimally processed vegetables (MPVs). These compounds are toxic and/or carcinogenic and have been associated with human health risks; therefore, the U.S. Environmental Protection Agency has set a maximum contaminant level for five HAAs at 60 μg/L in drinking water. This paper describes the first method to determine the nine HAAs that can be present in MPV samples, with static headspace coupled with gas chromatography-mass spectrometry where the leaching and derivatization of the HAAs are carried out in a single step. The proposed method is sensitive, with limits of detection between 0.1 and 2.4 μg/kg and an average relative standard deviation of ∼8%. From the samples analyzed, we can conclude that about 23% of them contain at least two HAAs (<0.4-24 μg/kg), which showed that these compounds are formed during washing and then remain on the final product.

  7. Phenylalanine-induced leucopenia in genetic and dichloroacetic acid generated deficiency of glutathione transferase Zeta.

    Science.gov (United States)

    Theodoratos, Angelo; Tu, Wen Juan; Cappello, Jean; Blackburn, Anneke C; Matthaei, Klaus; Board, Philip G

    2009-04-15

    Glutathione transferase Zeta (GSTZ1-1) is identical to maleylacetoacetate isomerase and catalyses a significant step in the catabolism of phenylalanine and tyrosine. Exposure of GSTZ1-1 deficient mice to high dietary phenylalanine causes a rapid loss of circulating white blood cells (WBCs). The loss was significant (P<0.05) after 2 days and total WBCs were reduced by 60% after 6 days. The rapid loss of WBCs was attributed to the accumulation of the catabolic intermediates maleylacetoacetate or maleylacetone (MA) in the circulation. Serum from GSTZ1-1 deficient mice treated with phenylalanine was cytotoxic to splenocytes from normal BALB/c mice and direct incubation of normal splenocytes with MA caused a rapid loss of viability. Dichloroacetic acid (DCA) has been used therapeutically to treat lactic acidosis and is potentially of use in cancer chemotherapy. Since DCA can inactivate GSTZ1-1 there is a possibility that long-term treatment of patients with DCA could cause GSTZ1-1 deficiency and susceptibility to oxidative stress and phenylalanine/tyrosine-induced WBC loss. However, although we found that DCA at 200mg/(kg day) causes a severe loss of hepatic GSTZ1-1 activity in BALB/c mice, it did not induce WBC cytotoxicity when combined with high dietary phenylalanine.

  8. Coal Mining and Post-Metallurgic Dumping Grounds and Their Connections with Exploitation of Raw Materials in the Region of Ruda Śląska

    Science.gov (United States)

    Jonczy, Iwona; Gawor, Łukasz

    2017-06-01

    Characteristics of mining and metallurgical waste dumps in Ruda Śląska was presented in this article. Special attention was paid to the relationship of waste material accumulated on the dumps with resources exploited on studied area. The possibilities of dumps management were also traced and two directions were indicated. The first one is associated with forming a biological covering on the dumps and the second one - with the dumps liquidation and with recovery areas now occupied by the dumps and thus with the secondary use of material collected on them.

  9. Beneficial effects of omega-3 fatty acids and vitamin B12 supplementation on brain docosahexaenoic acid, brain derived neurotrophic factor, and cognitive performance in the second-generation Wistar rats.

    Science.gov (United States)

    Rathod, Richa S; Khaire, Amrita A; Kale, Anvita A; Joshi, Sadhana R

    2015-01-01

    In vegetarian population, vitamin B12 deficiency coexists with suboptimal levels of omega-3 fatty acids. Studies indicate a need for supplementation/fortification of vitamin B12 and omega-3 fatty acids to reduce the risk of brain disorders. We have described the effects of vitamin B12 and omega-3 fatty acid supplementation on brain development in F1 generation animals. The current study investigates the effects of vitamin B12 and omega-3 fatty acids supplementation on brain function and cognition. Pregnant Wistar rats were assigned the following groups: control, vitamin B12 deficient (BD), vitamin B12 deficient + omega-3 fatty acid (BDO), vitamin B12 supplemented (BS), vitamin B12 supplemented + omega-3 fatty acid (BSO). The same diets were continued for two generations. BDO group showed higher (P acid) in the cortex and hippocampus as compared with the BD group. The cognitive performance was also normalized in this group. BS showed comparable levels of DHA, BDNF (protein and mRNA), and CREB mRNA (cAMP response element-binding protein) to that of control group while Tropomyosin receptor kinase mRNA levels were higher. The combined vitamin B12 and omega-3 fatty acid supplementation further enhanced the levels of DHA (P fatty acid supplementation across two generations on brain development and function.

  10. Determining the radon exhalation rate from a gold mine tailings dump by measuring the gamma radiation.

    Science.gov (United States)

    Ongori, Joash N; Lindsay, Robert; Newman, Richard T; Maleka, Peane P

    2015-02-01

    The mining activities taking place in Gauteng province, South Africa have caused millions of tons of rocks to be taken from underground to be milled and processed to extract gold. The uranium bearing tailings are placed in an estimated 250 dumps covering a total area of about 7000 ha. These tailings dumps contain considerable amounts of radium and have therefore been identified as large sources of radon. The size of these dumps make traditional radon exhalation measurements time consuming and it is difficult to get representative measurements for the whole dump. In this work radon exhalation measurements from the non-operational Kloof mine dump have been performed by measuring the gamma radiation from the dump fairly accurately over an area of more than 1 km(2). Radon exhalation from the mine dump have been inferred from this by laboratory-based and in-situ gamma measurements. Thirty four soil samples were collected at depths of 30 cm and 50 cm. The weighted average activity concentrations in the soil samples were 308 ± 7 Bq kg(-1), 255 ± 5 Bq kg(-1) and 18 ± 1 Bq kg(-1) for (238)U, (40)K and (232)Th, respectively. The MEDUSA (Multi-Element Detector for Underwater Sediment Activity) γ-ray detection system was used for field measurements. The radium concentrations were then used with soil parameters to obtain the radon flux using different approaches such as the IAEA (International Atomic Energy Agency) formula. Another technique the MEDUSA Laboratory Technique (MELT) was developed to map radon exhalation based on (1) recognising that radon exhalation does not affect (40)K and (232)Th activity concentrations and (2) that the ratio of the activity concentration of the field (MEDUSA) to the laboratory (HPGe) for (238)U and (40)K or (238)U and (232)Th will give a measure of the radon exhalation at a particular location in the dump. The average, normalised radon flux was found to be 0.12 ± 0.02 Bq m(-2) s(-1) for the mine dump.

  11. Environmental impact and recovery at two dumping sites for dredged material in the North Sea

    Energy Technology Data Exchange (ETDEWEB)

    Stronkhorst, J.; Ariese, F.; Hattum, B. van; Postma, J.F.; Kluijver, M. de; Besten, P.J. den; Bergman, M.J.N.; Daan, R.; Murk, A.J.; Vethaak, A.D

    2003-07-01

    Marine benthic resources near dumping sites are adversely affected by physical disturbances, but a causal link to contaminant damage could not be found. - The environmental impact and recovery associated with the long and uninterrupted disposal of large volumes of moderately contaminated dredged material from the port of Rotterdam was studied at nearby dumping sites in the North Sea. Observations were made on sediment contamination, ecotoxicity, biomarker responses and benthic community changes shortly after dumping at the 'North' site had ceased and at the start of disposal at the new dumping site 'Northwest'. During the period of dumping, very few benthic invertebrates were found at the North site. Concentrations of cadmium, mercury, polychlorinated biphenyls (PCBs), polyaromatic hydrocarbons (PAHs) and tributyltin (TBT) in the fine sediment fraction (<63 {mu}m) from this site were 2-3 times higher than at the reference site. In four different bioassays with marine invertebrates the sediments showed no acute toxic effects. In tissue (pyloric caeca) of resident starfish Asterias rubens, residual levels of mercury, zinc, PCBs and dioxin-like activity were never more than twice those at the reference site. Four different biomarkers (DNA integrity, cytochrome P450 content, benzo[a]pyrene hydroxylase activity and acetylcholinesterase inhibition) were used on the starfish tissues, but no significant differences were found between North and the reference site. Minor pathological effects were observed in resident dab Limanda limanda. One year after dumping had ceased at the North site, a significant increase in the species richness and abundance of benthic invertebrates and a concomitant decrease in the fine sediment fraction of the seabed were observed. After 8.2 million m{sup 3} of moderately contaminated dredged material had been dumped at the new dumping site Northwest, the species richness and abundance of benthic invertebrates declined over an

  12. Complex female genitalia indicate sperm dumping in armored goblin spiders (Arachnida, Araneae, Oonopidae).

    Science.gov (United States)

    Burger, Matthias

    2010-01-01

    In promiscuous females, sperm ejection from the sperm storage site can be a strong mechanism to influence sperm priority patterns. Sperm dumping is reported from different animals including birds, insects, and humans. In spiders, it has been documented for four species including the oonopid Silhouettella loricatula. Oonopidae are a diverse spider family comprising many species with peculiar female genitalia. Especially in species where studies of mating behavior are difficult, morphological investigations of the genitalia help to understand their function and evolution. In the present study, the genitalia of the oonopids Myrmopopaea sp., Grymeus sp., and Lionneta sp. are investigated by means of histological serial sections and scanning electron microscopy (SEM). The results are compared with previous findings on S. loricatula. In Myrmopopaea sp. and Grymeus sp., the same morphological components are present that are involved in sperm dumping in S. loricatula. Inside the receptaculum, sperm are enclosed in a secretory sac which can be moved to the genital opening and dumped during copulation by muscle contractions. The female genitalia of Lionneta sp. are asymmetric. They show the same characteristics as S. loricatula but all the investigated females were unmated. The results strongly suggest that sperm dumping occurs in Myrmopopaea sp., Grymeus sp., and Lionneta sp. and happens by the same mechanism as in S. loricatula. Sperm dumping might even be common within a clade of oonopids. As in S. loricatula, the sperm transfer forms in the investigated species consist of several spermatozoa. Papillae with unknown function occur on the receptacula of all females.

  13. Plant species from coal mine overburden dumping site in Satui, South Kalimantan, Indonesia

    Directory of Open Access Journals (Sweden)

    Vivi Novianti

    2017-07-01

    Full Text Available Coal mine overburden (OB materials were nutrient-poor, loosely adhered particles of shale, stones, boulders, and cobbles, also contained elevated concentration of trace metals. This condition cause OB substrate did not support plants growth. However, there were certain species that able to grow on overburden dumping site. This investigation sought to identify plants species that presence on coal mine overburden. The research was conducted on opencast coal mine OB dumping site in Satui, South Kalimantan. Vegetation sampling was carried out on six different ages of coal mine OB dumps (7, 10, 11, 42, 59 and 64 month using line transect. Species identification used information from local people, AMDAL report of PT Arutmin Indonesia-Satui mine project, and website. There were 123 plant species, consisted of 79 herbs (Cyperaceae, Poaceae and Asteraceae, 10 lianes, bryophyte, 9 ferns, 10 shrubs, and 14 trees. A number of Poaceae, i.e., Paspalumconjugatum, Paspalumdilatatum, and Echinochloacolona generally present among the stones, boulders, and cobbles. While Cyperaceae such as Fimbristylis miliaceae, Cyperus javanicus, Rhyncospora corymbosa and Scleria sumatrensis most often foundinand around thebasin/pond with its smooth and humid substrate characteristics. Certain species of shrubs and trees present on the 7 month OB dumping site. They wereChromolaena odorata, Clibadium surinamense, Melastoma malabathricum, Trema micrantha, and Solanum torvum (Shrubs, Ochroma pyramidale and Homalanthus populifolius (trees. This plant species could be used for accelerating primary succession purpose on coal mine overburden dumping site. Nevertheless, species selection was needed to avoid planting invasive species.

  14. The possibility of distance methods application for snow dump sites monitoring

    Directory of Open Access Journals (Sweden)

    Pasko Olga

    2016-01-01

    Full Text Available In this article the results of remote sensing of the Earth for monitoring of four snow dump sites in Tomsk are described. Their compliance with permitted type of the territory use was evaluated. Earlier unknown time of the operation start was identified. The spatial-temporal variability of areas was defined. The temperature profiles of snow dump and background sites were analyzed. Use of remote sensing data allowed easy identification of snow dump sites creation time. The fact that the sites are located out of zones of permitted type of the territory use was revealed, that is violation of the law. For the first time the cartographic material was collected and showed that in the recent years their areas increased in average in 18%. The fore-cast for the nearest years was made. The article contains satellite images indicting the degradation of soil-vegetative cover of snow dumps. The reasons are contamination and overcooling of the soil in the beginning of vegetation period. The research results became the initial material for perfection of snow dumps territories management and will be applied in the work of environmental protecting service. Approaches proposed by authors may be used in solving similar problems in any region.

  15. Radionuclides and toxic elements transfer from the princess dump to water in Roodepoort, South Africa.

    Science.gov (United States)

    Dlamini, S G; Mathuthu, M M; Tshivhase, V M

    2016-03-01

    High concentrations of radionuclides and toxic elements in gold mine tailings facilities present a health hazard to the environment and people living near that area. Soil and water samples from selected areas around the Princess Mine dump were collected. Soil sampling was done on the surface (15 cm) and also 100 cm below the surface. Water samples were taken from near the dump, mid-stream and the flowing part of the stream (drainage pipe) passing through Roodepoort from the mine dump. Soil samples were analyzed by gamma-ray spectroscopy using a HPGe detector to determine the activity concentrations of (238)U, (232)Th and (4) (​40)K from the activities of the daughter nuclides in the respective decay chains. The average activity concentrations for uranium and thorium in soil were calculated to be 129 ± 36.1 Bq/kg and 18.1 ± 4.01 Bq/kg, respectively. Water samples were analyzed using Inductively Coupled Plasma Mass Spectrometer. Transfer factors for uranium and thorium from soil to water (at point A closest to dump) were calculated to be 0.494 and 0.039, respectively. At point Z2, which is furthest from the dump, they were calculated to be 0.121 and 0.004, respectively. These transfer factors indicate that there is less translocation of the radionuclides as the water flows.

  16. Conceptual design of Dump resistor for Superconducting CS of SST-1

    Science.gov (United States)

    Roy, Swati; Raj, Piyush; Panchal, Arun; Pradhan, Subrata

    2017-04-01

    Under upgradation activities for SST-1, the existing resistive central solenoid (CS) coil will be replaced with Nb3Sn based superconducting coil. Design of Central solenoid had been completed and some of the initiative has already taken for its manufacturing. The superconducting CS will store upto 3 MJ of magnetic energy per operation cycle with operating current upto 14 kA. During quench, energy stored in the coils has to be extracted rapidly with a time constant of 1.5 s by inserting a 20 mΩ dump resistor in series with the superconducting CS which is normally shorted by circuit breakers. As a critical part of the superconducting CS quench protection system, a conceptual design of the 20 mΩ dump resistor has been proposed. The required design aspects and a dimensional layout of the dump resistor for the new superconducting CS has been presented and discussed. The basic structure of the proposed dump resistor comprises of stainless steel grids connected in series in the form of meander to minimize the stray inductance and increase the surface area for cooling. Such an array of grids connected in series and parallel will cater to the electrical as well as thermal parameters. It will be cooled by natural convection. During operation, the estimated maximum temperature of the proposed dump resistor will raise upto 600 K.

  17. Metropolitan garbage dumps: possible winter migratory raptor monitoring stations in peninsular India

    Directory of Open Access Journals (Sweden)

    S. Pande

    2010-09-01

    Full Text Available Winter raptor migration and movement is poorly documented for peninsular India, mainly due to the lack of geographical bottlenecks. We describe, for the first time, the use of a garbage dump in a metropolitan city as an alternative visual winter raptor monitoring station. The daily count, adult to juvenile ratios and species composition of three migratory raptor species, Steppe Eagle Aquila nipalensis, Black-eared Kite Milvus migrans lineatus and Tawny Eagle Aquila rapax are presented. Ground temperatures at the garbage dump site and surrounding area, and the wing beat rate of migratory raptors before and after arrival in the early morning were measured. A total of 355 raptors migrating over a period of six observation days with 250 adults and 105 juveniles were recorded. The temperature of the garbage dump was significantly higher than the surrounding area, while the wing flapping rate was significantly lower over the garbage dump area. It is possible that migrating raptors use garbage dump thermals in the early morning to save energy with soaring and gliding flight (versus flapping flight. We propose that such sites may be used as visual winter migration monitoring stations in metropolitan cities in peninsular India.

  18. Studying bio-thermal effects at and around MSW dumps using Satellite Remote Sensing and GIS.

    Science.gov (United States)

    Mahmood, Khalid; Batool, Syeda Adila; Chaudhry, Muhammad Nawaz

    2016-09-01

    Estimating negative impacts of MSW dumps on its surrounding environment is the key requirement for any remedial measures. This study has been undertaken to map bio-thermal effects of MSW dumping at and around dumping facilities (non-engineered) using satellite imagery for Faisalabad, Pakistan. Thirty images of Landsat 8 have been selected after validation for the accuracy of their observational details from April 2013 to October 2015. Land Surface Temperature (LST), NDVI, SAVI and MSAVI have been derived from these images through Digital Image Processing (DIP) and have been subjected to spatio-temporal analysis in GIS environment. MSW dump has been found with average temperature elevation of 4.3K and 2.78K from nearby agriculture land and urban settlement respectively. Vegetation health has been used as the bio-indicator of MSW effects and is implemented through NDVI, SAVI, MSAVI. Spatial analyses have been used to mark boundary of bio-thermally affected zone around dumped MSW and measure 700m. Seasonal fluctuations of elevated temperatures and boundary of the bio-thermally affected zones have also been discussed. Based on the direct relation found between vegetation vigor and the level of deterioration within the bio-thermally affected region, use of crops with heavy vigor is recommended to study MSW hazard influence using bio-indicators of vegetation health.

  19. Antioxidant Activity of Caffeic Acid against Iron-Induced Free Radical Generation--A Chemical Approach.

    Directory of Open Access Journals (Sweden)

    Thiago C Genaro-Mattos

    Full Text Available Caffeic acid (CA is a phenolic compound widely found in coffee beans with known beneficial effects in vivo. Many studies showed that CA has anti-inflammatory, anti-mutagenic, antibacterial and anti-carcinogenic properties, which could be linked to its antioxidant activity. Taking in consideration the reported in vitro antioxidant mechanism of other polyphenols, our working hypothesis was that the CA antioxidant activity could be related to its metal-chelating property. With that in mind, we sought to investigate the chemical antioxidant mechanism of CA against in vitro iron-induced oxidative damage under different assay conditions. CA was able to prevent hydroxyl radical formation promoted by the classical Fenton reaction, as determined by 2-deoxyribose (2-DR oxidative degradation and DMPO hydroxylation. In addition to its ability to prevent hydroxyl radical formation, CA had a great inhibition of membrane lipid peroxidation. In the lipid peroxidation assays CA acted as both metal-chelator and as hydrogen donor, preventing the deleterious action promoted by lipid-derived peroxyl and alkoxyl radicals. Our results indicate that the observed antioxidant effects were mostly due to the formation of iron-CA complexes, which are able to prevent 2-DR oxidation and DMPO hydroxylation. Noteworthy, the formation of iron-CA complexes and prevention of oxidative damage was directly related to the pH of the medium, showing better antioxidant activity at higher pH values. Moreover, in the presence of lipid membranes the antioxidant potency of CA was much higher, indicating its enhanced effectiveness in a hydrophobic environment. Overall, our results show that CA acts as an antioxidant through an iron chelating mechanism, preventing the formation of free hydroxyl radicals and, therefore, inhibiting Fenton-induced oxidative damage. The chemical properties of CA described here--in association with its reported signaling effects--could be an explanation to its

  20. Microbial ecology of a novel sulphur cycling consortia from AMD: implications for acid generation

    Science.gov (United States)

    Loiselle, L. M.; Norlund, K. L.; Hitchcock, A. P.; Warren, L. A.

    2009-05-01

    Recent work1 identified a novel microbial consortia consisting of two bacterial strains common to acid mine drainage (AMD) environments (autotrophic sulphur oxidizer Acidithiobacillus ferrooxidans and heterotrophic Acidiphilium spp.) in an environmental enrichment from a mine tailings lake. The two strains showed a specific spatial arrangement within an EPS macrostructure or "pod" allowing linked metabolic redox cycling of sulphur. Sulphur species characterisation of the pods using scanning transmission X-ray microscopy (STXM) indicated that autotrophic tetrathionate disproportionation by A. ferrooxidans producing colloidal elemental sulphur (S0) is coupled to heterotrophic S0 reduction by Acidiphilium spp. Geochemical modelling of the microbial sulphur reactions indicated that if they are widespread in AMD environments, then global AMD-driven CO2 liberation from mineral weathering have been overestimated by 40-90%1. Given the common co-occurrence of these two bacteria in AMD settings, the purpose of this study was to evaluate if these pods could be induced in the laboratory by pure strains and if so, whether their combined sulphur geochemistry mimicked the previous findings. Laboratory batch experiments assessed the development of pods with pure strain type cultures (A. ferrooxidans ATCC 19859 with mixotroph Acidiphilium acidophilum ATCC 738 or strict heterotroph Acp. cryptum ATCC 2158) using fluorescent in situ hybridization (FISH) imaging. The microbial sulphur geochemistry was characterized under autotrophic conditions identical to those used with the environmental AMD enrichment in which the pods were discovered. Results showed that the combined pure strain A. ferrooxidans and Acp. acidophilum form pods identical in structure to the AMD enrichment. To test the hypothesis that these pods form for mutual metabolic benefit, experiments were performed amending pure strain and AMD enrichment bacterial treatments with organic carbon and/or additional sulphur to

  1. Studying microfungi-mineral interactions in sulphide-bearing waste-rock dumps: a 7 years survey in the Libiola mine, North-Eastern Italy

    Science.gov (United States)

    Marescotti, P.; Cecchi, G.; Di Piazza, S.; Lucchetti, G.; Zotti, M.

    2015-12-01

    Sulphide-bearing waste-rock dumps represent complex geological systems characterised by high percentages of low-grade mineralisations and non-valuable sulphides (such as pyrite and pyrrhotite). The sulphide oxidation triggers acid mine drainage (AMD) processes and the release of several metals of environmental concern. The severe physicochemical properties of these metal-contaminated environments tend to inhibit soil forming processes and represent an important stress factor for the biotic communities by exerting a strong selective pressure. Some macro- and micro-fungi are pioneer and extremophile organisms, which may survive and tolerate high concentrations of toxic metals in contaminated environments. Many studies show the fungal capability to bioaccumulate, biosorb, and store in their cells a high concentration of ecotoxic metals. A 7 years multidisciplinary survey was carried out in the Libiola sulphide mine. The results evidenced that the waste rock dumps of the area are characterized by an extremely poor flora and a specific mycobiota, due to the soil acidity, high concentration of trace metals, and unavailability or paucity of nutrients and organic matter. Our studies allowed the complete mineralogical, geochemical, and mycological characterization of one of the biggest dumps of the mine. 30 microfungal vital strains were isolated in pure cultures and studied with molecular and morphological approach, for their identification. The results allowed the isolation of some rare and important extremophilic species. Penicillium was the most recurrent genus, together with Trichoderma and Cladosporium. In particular, Penicillium glandicola is a rare species previously isolated from cave or arid environments, whereas P. brevicompactum is one of the most important fungi for metal corrosion. Hence, some bioaccumulation tests allowed to select a Trichoderma harzianum strain efficient to uptake Cu and Ag from pyrite-bearing soils, highlighting its central role in fungal

  2. Generation of novel cationic antimicrobial peptides from natural non-antimicrobial sequences by acid-amide substitution

    Directory of Open Access Journals (Sweden)

    Tamada Yasushi

    2011-03-01

    Full Text Available Abstract Background Cationic antimicrobial peptides (CAMPs are well recognized to be promising as novel antimicrobial and antitumor agents. To obtain novel skeletons of CAMPs, we propose a simple strategy using acid-amide substitution (i.e. Glu→Gln, Asp→Asn to confer net positive charge to natural non-antimicrobial sequences that have structures distinct from known CAMPs. The potential of this strategy was verified by a trial study. Methods The pro-regions of nematode cecropin P1-P3 (P1P-P3P were selected as parent sequences. P1P-P3P and their acid-amide-substituted mutants (NP1P-NP3P were chemically synthesized. Bactericidal and membrane-disruptive activities of these peptides were evaluated. Conformational changes were estimated from far-ultraviolet circular dichroism (CD spectra. Results NP1P-NP3P acquired potent bactericidal activities via membrane-disruption although P1P-P3P were not antimicrobial. Far-ultraviolet CD spectra of NP1P-NP3P were similar to those of their parent peptides P1P-P3P, suggesting that NP1P-NP3P acquire microbicidal activity without remarkable conformational changes. NP1P-NP3P killed bacteria in almost parallel fashion with their membrane-disruptive activities, suggesting that the mode of action of those peptides was membrane-disruption. Interestingly, membrane-disruptive activity of NP1P-NP3P were highly diversified against acidic liposomes, indicating that the acid-amide-substituted nematode cecropin pro-region was expected to be a unique and promising skeleton for novel synthetic CAMPs with diversified membrane-discriminative properties. Conclusions The acid-amide substitution successfully generated some novel CAMPs in our trial study. These novel CAMPs were derived from natural non-antimicrobial sequences, and their sequences were completely distinct from any categories of known CAMPs, suggesting that such mutated natural sequences could be a promising source of novel skeletons of CAMPs.

  3. Determination of sulfur and nitrogen compounds during the processing of dry fermented sausages and their relation to amino acid generation.

    Science.gov (United States)

    Corral, Sara; Leitner, Erich; Siegmund, Barbara; Flores, Mónica

    2016-01-01

    The identification of odor-active sulfur and nitrogen compounds formed during the processing of dry fermented sausages was the objective of this study. In order to elucidate their possible origin, free amino acids (FAAs) were also determined. The volatile compounds present in the dry sausages were extracted using solvent assisted flavor evaporation (SAFE) and monitored by one and two-dimensional gas chromatography with different detectors: mass spectrometry (MS), nitrogen phosphorous (NPD), flame photometric (FPD) detectors, as well as gas chromatography-olfactometry. A total of seventeen sulfur and nitrogen compounds were identified and quantified. Among them, 2-acetyl-1-pyrroline was the most potent odor active compound, followed by methional, ethylpyrazine and 2,3-dihydrothiophene characterized by toasted, cooked potato, and nutty notes. The degradation of FAAs, generated during processing, was related to the production of aroma compounds, such as methionine forming methional and benzothiazole while ornithine was the precursor compound for 2-acetyl-1-pyrroline and glycine for ethylpyrazine.

  4. PERK Utilizes Intrinsic Lipid Kinase Activity To Generate Phosphatidic Acid, Mediate Akt Activation, and Promote Adipocyte Differentiation

    Science.gov (United States)

    Bobrovnikova-Marjon, Ekaterina; Pytel, Dariusz; Riese, Matthew J.; Vaites, Laura Pontano; Singh, Nickpreet; Koretzky, Gary A.; Witze, Eric S.

    2012-01-01

    The endoplasmic reticulum (ER) resident PKR-like kinase (PERK) is necessary for Akt activation in response to ER stress. We demonstrate that PERK harbors intrinsic lipid kinase, favoring diacylglycerol (DAG) as a substrate and generating phosphatidic acid (PA). This activity of PERK correlates with activation of mTOR and phosphorylation of Akt on Ser473. PERK lipid kinase activity is regulated in a phosphatidylinositol 3-kinase (PI3K) p85α-dependent manner. Moreover, PERK activity is essential during adipocyte differentiation. Because PA and Akt regulate many cellular functions, including cellular survival, proliferation, migratory responses, and metabolic adaptation, our findings suggest that PERK has a more extensive role in insulin signaling, insulin resistance, obesity, and tumorigenesis than previously thought. PMID:22493067

  5. PERK utilizes intrinsic lipid kinase activity to generate phosphatidic acid, mediate Akt activation, and promote adipocyte differentiation.

    Science.gov (United States)

    Bobrovnikova-Marjon, Ekaterina; Pytel, Dariusz; Riese, Matthew J; Vaites, Laura Pontano; Singh, Nickpreet; Koretzky, Gary A; Witze, Eric S; Diehl, J Alan

    2012-06-01

    The endoplasmic reticulum (ER) resident PKR-like kinase (PERK) is necessary for Akt activation in response to ER stress. We demonstrate that PERK harbors intrinsic lipid kinase, favoring diacylglycerol (DAG) as a substrate and generating phosphatidic acid (PA). This activity of PERK correlates with activation of mTOR and phosphorylation of Akt on Ser473. PERK lipid kinase activity is regulated in a phosphatidylinositol 3-kinase (PI3K) p85α-dependent manner. Moreover, PERK activity is essential during adipocyte differentiation. Because PA and Akt regulate many cellular functions, including cellular survival, proliferation, migratory responses, and metabolic adaptation, our findings suggest that PERK has a more extensive role in insulin signaling, insulin resistance, obesity, and tumorigenesis than previously thought.

  6. PHOTO-INDUCED DOPED POLYANILINE BY THE VINYLIDENE CHLORIDE AND METHYL ACRYLATE COPOLYMER AS PHOTO ACID GENERATOR

    Institute of Scientific and Technical Information of China (English)

    LI Suzhen; WAN Meixiang

    1997-01-01

    The emeraldine base form of polyaniline (PANI) can be doped by a photo-induced doping method. In this method a copolymer of vinylidene chloride and methyl acrylate (VCMAC) was used as photo acid generator which can release proton when it is exposed to ultraviolet light (λ = 254 nm). The structure of PANI-VCMAC system before and after irradiation was characterized by elemental analysis, IR, XPS, and SEM images. Results obtained indicate that the photo-induced doping characteristics, such as doping position and type of charge carriers, are similar to that of PANI doped with HCl. The poor roomtemperature conductivity (~ 10-5S/cm) of PANI-VCMAC system after irradiation may be due to low doping degree (~pH= 3) and the difference in morphology as compared with PANI-HCl film.

  7. Generation of trans-arachidonic acid under nitrative stress is associated with upregulation of thromponsdin-1 in diabetic rats

    Institute of Scientific and Technical Information of China (English)

    XU Lin; XU Xun; LIU Yu-min; YAO Zhu-jun; XUN Guo-liang; YU Wen-juan; LIU Kun; SUN Xiao-dong; QIU Yun-ping; WU Hai-xiang

    2011-01-01

    Background Trans-arachidonic acids (TAAs), newly discovered markers of nitrative stress and the major products of nitrogen dioxide (NO2)-mediated isomerization of arachidonic acid (AA), represent a new mechanism of NO2-induced toxicity. It has been reported that TAAs were generated in oxygen-induced microvascular degeneration model and TAAs were also generated in a diabetic retinopathy (DR) model. In this study, we examined high glucose-induced nitrative stress damage and TAAs levels and explored the possible mechanisms for DR caused by reactive nitrogen species. Methods Diabetic rats were induced by intraperitoneal injection of streptozotocin (STZ) at 60 mg/kg. Bovine retinal capillary endothelial cells (BRECs) were selectively cultured and incubated with normal or high glucose. The serum TAAs and AA in diabetic rats were measured by the gas chromatography and mass spectrometry (GC/MS) method. The ratio of peak area of TAAs to AA with selected ion of 79 was estimated by a group (-test. Thrombospondin-1 (TSP-1) in the rat retinas and BRECs extracts were examined by Western blotting. The phosphorylation of extracellular signal-regulated kinase 1/2 (ERK1/2) protein was examined by Western blotting in BRECs incubated with high glucose.Results The TAAs to AA ratio (TAAs/AA) was significantly increased in the serum at 8, 12 and 16 weeks after STZ injection (P 0.05). Expression of TSP-1 in the retina of diabetic rats was progressively elevated according to the duration of diabetes. TSP-1 expression was increased in BRECs incubated with high glucose at 48 hours. Moreover, high glucose also increased ERK1/2 expression, which peaked at 30 minutes and then decreased in the following 48 hours.Conclusion An elevation of TAAs/AA is associated with high glucose-induced nitrative stress, which probably involves upregulation of TSP-1 through activating ERK1/2.

  8. Selective recovery of copper and zinc from mine dump waters of mining enterprises in precipitates

    Science.gov (United States)

    Orekhova, N. N.; Tarybaeva, G. A.; Muravev, D. S.

    2017-01-01

    The acid mine dump waters at mining companies that mining the copper and copperzinc sulphide ore have the high concentrates of metals and classified in our view as the raw materials for selective recovery of metals in precipitates comparable in quality with concentrates of ores enrichment and suitable for further metallurgical processing. Authors have implemented three two-stage schemes for sequential extraction of copper and zinc: cementation-sulphide precipitation, galvanocoagulation-sulphide precipitation, precipitation-precipitation. Moreover, parameters of processes and quality of the obtained precipitates have described. The achieved copper recovery is 89% and 94% respectively with the application of cementation and galvanocoagulation, in sulphide precipitate exceeded 75%. Furthermore, the copper recovery from decoppering in precipitates amounted to more than 65%. Zinc-containing precipitates because of coprecipitation of iron, magnesium and calcium contain zinc from 14% to 28%, in two to three times less than the quality of conditioned zinc concentrates. The content of precipitates allows to apply them for additional charging to concentrates of enrichment or for the production of metals in metallurgical treatment. As a result of the studying the effect of reduced total salinity (S) on mass fraction of zinc in precipitate (β) with the constant concentration of zinc (SZn), the changes in concentration with constant salinity and reduction in total salinity (S) with constant ratio S/CZn, the following dependencies have obtained: ≤ft( {{S}} \\right):{≤ft( {{{\\partial β } \\over {\\partial {cZn}}}} \\right)_S} > 0,{≤ft( {{{\\partial β } \\over {\\partial S}}} \\right){C_{Zn}}} < 0, in the range of an index S from 4.5 to 90.0 g/L {≤ft( {{{\\partial β } \\over {\\partial S}}} \\right){{{C_{Zn}} \\over S}}} < 0, where {≤ft( {{{\\partial x} \\over {\\partial y}}} \\right)_Z} is a partial derivative of x to y, whereas the value z is fixed.

  9. Sphingomonas laterariae sp. nov., isolated from a hexachlorocyclohexane-contaminated dump site.

    Science.gov (United States)

    Kaur, Jasvinder; Kaur, Jaspreet; Niharika, Neha; Lal, Rup

    2012-12-01

    A Gram-staining-negative, non-motile, cream-coloured and rod-shaped bacterium, designated strain LNB2(T), was isolated from a hexachlorocyclohexane-contaminated dump site in the village of Ummari, in northern India. The taxonomic position of the novel strain was investigated by using a polyphasic approach. In a phylogenetic analysis based on 16S rRNA gene sequences, strain LNB2(T) appeared to be most closely related to Sphingomonas haloaromaticamans A175(T) (98.0% sequence similarity) and Sphingomonas histidinilytica UM2(T) (97.3%). In DNA-DNA hybridizations, the levels of DNA-DNA relatedness between the novel strain and S. haloaromaticamans A175(T) and S. histidinilytica UM2(T) were found to be low (8.6% and 5.6%, respectively). The genomic DNA G+C content of strain LNB2(T) was 61.0 mol%. The novel strain's predominant fatty acids were summed feature 8 (C(18:1)ω7c and/or C(18:1)ω6c), C(16:0), summed feature 3 (C(16:1)ω7c and/or C(16:1)ω6c), C(14:0) 2-OH, C(17:1)ω6c and 11-methyl C(18:1)ω7c. The major ubiquinone was Q-10, the predominant polyamine was homospermidine, and the major polar lipids were diphosphatidylglycerol, phosphatidylglycerol, phosphatidylcholine, sphingoglycolipid, phosphatidylethanolamine and phosphatidyldimethylethanolamine. Based on the phylogenetic, biochemical and chemotaxonomic evidence and the results of the DNA-DNA hybridizations, strain LNB2(T) represents a novel species of the genus Sphingomonas, for which the name Sphingomonas laterariae sp. nov. is proposed. The type strain is LNB2(T) ( = MTCC 10873(T) = CCM 7880(T) = DSM 25432(T)).

  10. An energy-efficient process for decomposing perfluorooctanoic and perfluorooctane sulfonic acids using dc plasmas generated within gas bubbles

    Energy Technology Data Exchange (ETDEWEB)

    Yasuoka, K; Sasaki, K; Hayashi, R, E-mail: yasuoka@ee.titech.ac.jp [Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Ookayama, Tokyo (Japan)

    2011-06-15

    Perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) are environmentally harmful and persistent substances. Their decomposition was investigated using dc plasmas generated within small gas bubbles in a solution. The plasma characteristics including discharge voltage, voltage drop in the liquid, plasma shape and the emission spectrum were examined with different gases. The decomposition rate and energy efficiency were evaluated by measuring the concentration of fluoride and sulfate ions released from PFOA/PFOS molecules. The concentration of fluoride ions and energy efficiency in the treatment of a PFOS solution were 17.7 mg l{sup -1} (54.8% of the initial amount of fluorine atoms) and 26 mg kWh{sup -1}, respectively, after 240 min of operation. The addition of scavengers of hydroxyl radicals and hydrated electrons showed little effect on the decomposition. The decomposition processes were analyzed with an assumption that positive species reacted with PFOA/PFOS molecules at the boundary of the plasma-solution surface. This type of plasma showed a much higher decomposition energy efficiency compared with energy efficiencies reported in other studies.

  11. Binding of Na+ and K+ to the Headgroup of Palmitic Acid Monolayers Studied by Vibrational Sum Frequency Generation Spectroscopy

    Science.gov (United States)

    Huang, Zishuai; Allen, Heather C.

    2012-06-01

    Alkali cations are critical in biological systems due to their electrical interaction with cell membranes. While Na+ and K+ share similar chemical and physical properties, they can exhibit differences when interacting with biological membranes. These phenomena may be modeled using a Langmuir monolayer of surfactant on alkali chloride solutions. Vibrational sum frequency generation (VSFG) spectroscopy is an interface specific technique that is widely employed to study molecular organization at surfaces and interfaces. VSFG spectroscopy was used to probe the CO2- vibrational mode for the carboxylic acid headgroup of palmitic acid (PA) spread on the surface of NaCl and KCl solutions in the vibrational region between 1400 and 1500 cm-1. The ability of Na+ and K+ to bind with the carboxylic headgroup of PA is revealed by observing peak positions (˜1410 cm-1 and ˜1470 cm-1) and relative intensity for the CO2- peaks. These results are compared and discussed with perspective toward elucidating interfacial PA headgroup organization. The time evolution for the PA CO2- peaks is also monitored after monolayer spreading via VSFG and these results are presented as well.

  12. Role of lipase-generated free fatty acids in converting mesenteric lymph from a noncytotoxic to a cytotoxic fluid.

    Science.gov (United States)

    Qin, Xiaofa; Dong, Wei; Sharpe, Susan M; Sheth, Sharvil U; Palange, David C; Rider, Therese; Jandacek, Ronald; Tso, Patrick; Deitch, Edwin A

    2012-10-15

    Recent studies have shown that mesenteric lymph plays a very important role in the development of multiple-organ dysfunction syndrome under critical conditions. Great efforts have been made to identify the biologically active molecules in the lymph. We used a trauma-hemorrhagic shock (T/HS) model and the superior mesenteric artery occlusion (SMAO) model, representing a global and a localized intestinal ischemia-reperfusion insult, respectively, to investigate the role of free fatty acids (FFAs) in the cytotoxicity of mesenteric lymph in rats. Lymph was collected before, during, and after (post) shock or SMAO. The post-T/HS and SMAO lymph, but not the sham lymph, manifested cytotoxicity for human umbilical vein endothelial cells (HUVECs). HUVEC cytotoxicity was associated with increased FFAs, especially the FFA-to-protein ratio. Addition of albumin, especially delipidated albumin, reduced this cytotoxicity. Lipase treatment of trauma-sham shock (T/SS) lymph converted it from a noncytotoxic to a cytotoxic fluid, and its toxicity correlated with the FFA-to-protein ratio in a fashion similar to that of the T/HS lymph, further suggesting that FFAs were the key components leading to HUVEC cytotoxicity. Analysis of lymph by gas chromatography revealed that the main FFAs in the post-T/HS or lipase-treated T/SS lymph were palmitic, stearic, oleic, and linoleic acids. When added to the cell culture at levels comparable to those in T/HS lymph, all these FFAs were cytotoxic, with linoleic acid being the most potent. In conclusion, this study suggests that lipase-generated FFAs are the key components resulting in the cytotoxicity of T/HS and SMAO mesenteric lymph.

  13. Generation of novel metabolites of dietary linoleic acid (18:2n6) by guinea pig epidermis

    Energy Technology Data Exchange (ETDEWEB)

    Chapkin, R.S.; Ziboh, V.A.

    1986-03-05

    Although the authors have demonstrated the inability of rat and guinea pig (GP) skin enzyme preparations to desaturate 18:2n6 into gammalinolenic acid (18:3n6) using an in vitro microsomal system, the fate of this dietary essential fatty acid in the GP epidermis is unknown. To explore the fate of 18:2n6, intact tissue slices from GP epidermis were incubated with (1-/sup 14/C)18:2n6. After incubation, the extracted lipids were transesterified using methanolic-HCL. The fatty acid methyl esters were analyzed using a combination of (i) argentation TLC, scanned using a proportional TLC radioscanner, and (ii) reverse phase HPLC, equipped with a flow through radioscanner. The results indicate that the intact epidermis metabolized /sup 14/C-18:2n6 to a group of novel products more polar than 18:2n6. In subsequent experiments, /sup 14/C-18:2n6 was either incubated with the 800 xg supernatant, the 105,000 xg pellet or supernatant from GP epidermis. Metabolism of 18:2n6 by the high speed supernatant resulted in the generation of polar products with chromatographic properties of not greater than 2 double bonds. These results indicate that although the GP epidermis lacks the capacity to desaturate 18:2n6 to 18:3n6, it can convert dietary 18:2n6 into a group of novel polar metabolites via a cytosolic mediated process. The function of these metabolites in the GP integumentary system remains to be determined.

  14. Assessment of metal pollution in soils from a former Havana (Cuba) solid waste open dump.

    Science.gov (United States)

    Díaz Rizo, O; Hernández Merlo, M; Echeverría Castillo, F; Arado López, J O

    2012-02-01

    Concentrations of cobalt, nickel, cooper, zinc and lead in the top-soils (0-10 cm) from a former Havana solid waste open dump were estimated by X-ray fluorescence analysis. The mean metal contents in the dump topsoil samples (in mg kg(-1): 8.4 ± 2.7 for cobalt, 50 ± 27 for nickel, 252 ± 80 for copper, 489 ± 230 for zinc and 276 ± 140 for lead) were compared with mean concentrations from Havana urban soils and from other solid waste disposals around the world. The comparison with Dutch soil quality guidelines showed a serious cooper contamination and a slight contamination with the rest of determined metals. The values of the integrated pollution index (mean index = 3.5) indicated that dump soils are highly contaminated by metals, and the enrichment index values shows that metal concentrations on the studied locations are above the permissible levels for urban agriculture.

  15. Continuous glucose monitoring for suspected dumping syndrome in infants after Nissen fundoplication.

    Science.gov (United States)

    Ueda, Kazutoshi; Mizumoto, Hiroshi; Shibata, Hirofumi; Miyauchi, Yuya; Sato, Masahito; Hata, Daisuke

    2013-12-01

    Dumping syndrome is infrequently reported, but known to occur after Nissen fundoplication in children. However, it may be difficult both to diagnose and manage. Here we presented four infants who received Nissen fundoplication for severe gastroesophageal reflux disease, two of whom developed dumping syndrome whilst the other two did not. Continuous glucose monitoring (CGM) was very useful to clearly detect large glycemic fluctuation around each feeding. CGM was also helpful to prove the effect of treatment to avoid abnormal glucose levels. We believe that dumping syndrome in children may be underdiagnosed if clinicians rely solely on the recognition of symptoms or limited frequency of blood samplings. CGM might be the most sensitive diagnostic tool.

  16. Analysis the Purposes of Land Use Planning on the Hard Coal Tailing Dumps

    Science.gov (United States)

    Zástĕrová, Petra; Niemiec, Dominik; Marschalko, Marian; Durd'ák, Jan; Duraj, Miloš; Yilmaz, Işik; Drusa, Marian

    2016-10-01

    The aim of this publication is to analyse the purposes of land use planning on hard coal tailing dumps. This issue is very topical because there are 46 tailing dumps and 281 reservoirs in the Ostrava-Karvina Mining District. They significantly affect the landscape of this region. A major problem is solving problems of reclamation of these geological environment. This means that it is necessary to think about it and start to solve it. It is clear that such reclamation is not simple both economic as well as environmental point of view. It is necessary to think carefully about what purpose would be tailing dump or reservoirs to utilize in a given location.

  17. A new dump system design for stray light reduction of Thomson scattering diagnostic system on EAST

    Science.gov (United States)

    Xiao, Shumei; Zang, Qing; Han, Xiaofeng; Wang, Tengfei; Yu, Jin; Zhao, Junyu

    2016-07-01

    Thomson scattering (TS) diagnostic is an important diagnostic for measuring electron temperature and density during plasma discharge. However, the measurement of Thomson scattering signal is disturbed by the stray light easily. The stray light sources in the Experimental Advanced Superconducting Tokamak (EAST) TS diagnostic system were analyzed by a simulation model of the diagnostic system, and simulation results show that the dump system is the primary stray light source. Based on the optics theory and the simulation analysis, a novel dump system including an improved beam trap was proposed and installed. The measurement results indicate that the new dump system can reduce more than 60% of the stray light for the diagnostic system, and the influence of stray light on the error of measured density decreases.

  18. Experimental study on preferential solution flow during dump leaching of low-grade ores

    Institute of Scientific and Technical Information of China (English)

    YIN Sheng-hua; WU Ai-xiang; SU Yong-ding; ZHANG Jie

    2007-01-01

    The phenomenon of preferential solution flow during dump leaching of low-grade ores was studied. The formative mechanism of preferential solution flow was investigated through analyzing the relationship between permeability and ore diameter,and the relationship between surface tension and ore diameter. The preferential solution flow happened within the fine ore area when the dump was unsaturated. And it could happen within the coarse ore area when the dump became saturated. The results of experiment show that the outflow of coarse ore area increases sharply with higher applied rate. The outflow of fine ore area is greater than that of coarse ore area when the applied rate is below 3.2 L/min, and the preferential solution flow happens in fine ore area. But the preferential solution flow happens in coarse ore area when the applied rate is higher than 3.2 L/min. The result of the experiment is consistent with the mechanism analyzing.

  19. Radioactivity of dumps in mining areas of the Upper Silesian Coal Basin in Poland

    Directory of Open Access Journals (Sweden)

    Dorda J.

    2012-04-01

    Full Text Available Underground coal mining is associated with large quantities of gangue. In the past, the majority of gangue was not utilized but was placed in the vicinity of the coalmines forming cone-shaped dumps. Some of them contained even millions of tons of rock. Nowadays, environmental precautions extort larger utilization of any kind of waste materials, for example in road construction, civil engineering or as stowing in underground abandoned workings. Examination of the composition of waste dumps, including radioactivity, is thus an important issue. The paper presents results of a radiological survey carried out in several dumps located in the Upper Silesian Coal Basin in the south of Poland. Measurements of samples were carried out with the use of a gamma-ray spectrometer. Activity concentration results for the uranium and thorium decay chains are discussed.

  20. NEUTRALIZING OF WASTE PESTICIDES FROM DUMPING GROUNDS BY MEANS OF EXPLOSIVE BURNING

    Directory of Open Access Journals (Sweden)

    Jolanta Biegańska

    2014-10-01

    Full Text Available Dumping areas of dangerous wastes are big threat for environment in particularly at the moment of release dangerous substances in draining form. Migration of those substances in soil causes pollution of water environment. The attention in article was turned on specific kind of wastes – pesticides, which are accumulated during many years in dumping grounds. The majority of those dumping grounds have been catalogued. The gigantic environmental threat is caused by lack of environmental monitoring of polluted areas. Many physical, chemical and biological methods for neutralizing such waste were invented and patented. The most efficient method of liquidate those waste appeared to be thermal degradation. This kind of method is also, presented in this paper, explosive burning of pesticides.