Low-NO{sub x}, wood chip combustion

Energy Technology Data Exchange (ETDEWEB)

Saastamoinen, J.; Oravainen, H.; Haemaelaeinen, J.; Paakkinen, K. [VTT Energy, Jyvaeskylae (Finland)

1997-10-01

The regulations for nitrogen oxide emissions vary in different countries, but the general trend in the future will probably be that the emissions limits will be lowered also for wood combustion plants, which are small or medium size units. Thus, the development of wood chip burning furnaces (grate furnaces, fluidized bed combustors, stoker furnaces) with lower nitrogen oxide emissions, is important. The wood used in the combustor, its particle size, moisture and fuel properties (nitrogen content) affect the nitrogen emissions. The nitrogen oxide release is also much affected by the design and operation of the combustor (air staging, fuel air preheat, flue gas circulation, air to fuel mass ratio). The fate of nitrogen compounds originally in the virgin wood depends much on the design of the combustor system and by proper planning it is possible to reduce the emission of nitrogen oxides. Basic knowledge of the release of nitrogen compounds from single wood particles is attained. The release of gaseous nitrogen compounds from wood particles during pyrolysis and combustion is studied experimentally and by modelling. Nitrogen release is studied experimentally by two ways, by analysing the gas and by quenching the particle and analysing the char residue. Formation of nitrogen oxide emissions in a fuel bed is studied by modelling and by combustion experiments with a pot furnace. This research gives general information of nitrogen oxide formation in wood bunting especially in fixed beds. The development of a horizontal stoker burner for wood chips with low emissions is the practical aim of the research. (orig.)

COMBUSTION PROPERTIES OF EUCALYPTUS WOOD

Directory of Open Access Journals (Sweden)

Yalçın ÖRS

1999-03-01

Full Text Available In this study, the combustion properties of some impregnation materials (abiotic and biotic factors used for eucalyptus wood in interior or exterior environments were investigated. The experimental samples were prepared from Eucalyptus wood based on ASTM-D-1413-76 Tanalith-CBC, boric acid, borax, vacsol-WR, immersol-WR, polyethylen glycole-400 and ammonium sulphate were used as an impregnation material. The results indicated that, vacuum treatment on Eucalyptus gave the lowest retention value of salts. Compounds containing boron+salt increased fire resistance however water repellents decreased the wood flammability.

Domestic competitiveness in secondary wood industries

Science.gov (United States)

Matthew Bumgardner; Urs Buehlmann; Albert Schuler; Rich Christianson

2004-01-01

As imports capture a substantial portion of the domestic wood furniture market, there is much speculation and concern as to the future of this and related industries. This study sought to obtain an industry perspective of trends in domestic manufacturing and importing, and to identify factors that might enhance domestic competitiveness. A mail survey was conducted...

Mutagenicity assessment of aerosols in emissions from wood combustion in Portugal

International Nuclear Information System (INIS)

Vu, B.; Alves, C.A.; Gonçalves, C.; Pio, C.; Gonçalves, F.; Pereira, R.

2012-01-01

Polycyclic aromatic hydrocarbon (PAH) extracts of fine particles (PM 2.5 ) collected from combustion of seven wood species and briquettes were tested for mutagenic activities using Ames test with Salmonella typhimurium TA98 and TA100. The woods were Pinus pinaster (maritime pine), Eucalyptus globulus (eucalypt), Quercus suber (cork oak), Acacia longifolia (golden wattle), Quercus faginea (Portuguese oak), Olea europea (olive), and Quercus ilex rotundifolia (Holm oak). Burning experiments were done using woodstove and fireplace, hot start and cold start conditions. A mutagenic response was recorded for all species except golden wattle, maritime pine, and briquettes. The mutagenic extracts were not correlated with high emission factors of carcinogenic PAHs. These extracts were obtained both from two burning appliances and start-up conditions. However, fireplace seemed to favour the occurrence of mutagenic emissions. The negative result recorded for golden wattle was interesting, in an ecological point of view, since after confirmation, this invasive species, can be recommended for domestic use. - Highlights: ► Both woodstove and fireplace, either with a cold or hot start, produce emissions with mutagenic potential. ► The high level of carcinogenic PAHs in combustion emissions was not correlated with mutagenicity. ► The golden wattle, an invasive species, produced no mutagenic emissions. - Wood smoke from fireplace burning of dominant forest species displayed strong mutagenic activity without a significant correlation with carcinogenic PAHs emission factors.

In situ high-temperature gas sensors: continuous monitoring of the combustion quality of different wood combustion systems and optimization of combustion process

Directory of Open Access Journals (Sweden)

H. Kohler

2018-03-01

Full Text Available The sensing characteristics and long-term stability of different kinds of CO ∕ HC gas sensors (non-Nernstian mixed potential type during in situ operation in flue gas from different types of low-power combustion systems (wood-log- and wood-chip-fuelled were investigated. The sensors showed representative but individual sensing behaviour with respect to characteristically varying flue gas composition over the combustion process. The long-term sensor signal stability evaluated by repeated exposure to CO ∕ H2 ∕ N2 ∕ synthetic air mixtures showed no sensitivity loss after operation in the flue gas. Particularly for one of the sensors (Heraeus GmbH, this high signal stability was observed in a field test experiment even during continuous operation in the flue gas of the wood-chip firing system over 4 months. Furthermore, it was experimentally shown that the signals of these CO ∕ HC sensing elements yield important additional information about the wood combustion process. This was demonstrated by the adaptation of an advanced combustion airstream control algorithm on a wood-log-fed fireplace and by the development of a combustion quality monitoring system for wood-chip-fed central heaters.

Wood combustion and NOx formation control

International Nuclear Information System (INIS)

Tewksbury, C.

1991-01-01

The control of wood combustion on stoker fed grates for optimum efficiency and the limiting of NO x (oxides of nitrogen) formation are not necessarily contradictory. This paper presents a matrix of air/fuel ratio control options, then discusses simple on-line monitoring techniques and the importance of operator training and alertness. The significance of uniform fuel feed and air distribution is emphasized. The relationships between combustion control and NO x formation are outlined both in theory and as tested. The experience of the McNeil Generating Station (the largest wood-fired, single boiler, stoker grate, utility electric generating station in the world) is used to demonstrate the theoretical principles. It has been observed that NO x emissions firing 100% whole tree chips with moisture contents as low as 40% by weight can be as low as 0.13 lb/MMBtu (MMBtu = 10 6 Btu) while still achieving a boiler efficiency in the range of 68% to 73% (in the high end of the design range) without the use of post-combustion treatment or flue gas recirculation (FGR). Problems of combustion and emissions control at steaming rates other than normal full-load are also examined. 2 figs., 4 tabs

Wood products in the waste stream: Characterization and combustion emissions. Volume 1. Final report

International Nuclear Information System (INIS)

1992-11-01

Waste wood is wood separated from the solid-waste stream and processed into a uniform-sized product that is reused for other purposes such as fuel. As an alternative to the combustion of fossil fuels, it has raised concerns that if it is 'contaminated' with paints, resins, preservatives, etc., unacceptable environmental impacts may be generated during combustion. Given the difficulty of separating contaminated materials from waste wood and the large energy potential existing in the resource, it is important to identify possible problems associated with contaminated waste wood combustion. The study describes research about technical, public policy, and regulatory issues that affect the processing and combustion of waste wood for fuel. The project's purpose was to provide environmental regulators, project developers, and others with data to make informed decisions on the use of waste wood materials as a combustion resource. Potential environmental problems and solutions were identified. A specific project result was the identification of combustion system operation parameters and air pollution control technologies that can minimize emissions of identified air and solid waste contaminants from combustion of wood waste

Mutagenicity assessment of aerosols in emissions from wood combustion in Portugal.

Science.gov (United States)

Vu, B; Alves, C A; Gonçalves, C; Pio, C; Gonçalves, F; Pereira, R

2012-07-01

Polycyclic aromatic hydrocarbon (PAH) extracts of fine particles (PM(2.5)) collected from combustion of seven wood species and briquettes were tested for mutagenic activities using Ames test with Salmonella typhimurium TA98 and TA100. The woods were Pinus pinaster (maritime pine), Eucalyptus globulus (eucalypt), Quercus suber (cork oak), Acacia longifolia (golden wattle), Quercus faginea (Portuguese oak), Olea europea (olive), and Quercus ilex rotundifolia (Holm oak). Burning experiments were done using woodstove and fireplace, hot start and cold start conditions. A mutagenic response was recorded for all species except golden wattle, maritime pine, and briquettes. The mutagenic extracts were not correlated with high emission factors of carcinogenic PAHs. These extracts were obtained both from two burning appliances and start-up conditions. However, fireplace seemed to favour the occurrence of mutagenic emissions. The negative result recorded for golden wattle was interesting, in an ecological point of view, since after confirmation, this invasive species, can be recommended for domestic use. Copyright © 2012 Elsevier Ltd. All rights reserved.

Drying wood waste with a pulse combustion dryer

Energy Technology Data Exchange (ETDEWEB)

Buchkowski, A.G. [Spectrum Engineering Corp., Ltd., Peterborough, Ontario (Canada); Kitchen, J.A. [John A. Kitchen, Ltd., Hastings, Ontario (Canada)

1993-12-31

There is a vast amount of wood waste available to be used as an alternate fuel if its moisture could be reduced efficiently. Tests have been conducted to assess an industrial dryer using pulse combustion as a heating source for drying wood waste; specifically sawdust and pulverized wet hog fuel. Pulse combustion offers the advantage of high heat transfer, efficient combustion, and low NO{sub x} emissions. The material is injected into the exhaust gases in the tailpipe of the combustor which uses natural gas or propane as a fuel. The turbulence created by the pulsations enhance the drying process by reducing the boundary layer thicknesses. The materials is further dried in a rotary drum. The material has been dried without scorching or burning in tests where the inlet moisture content has been as high as 60% on a wet basis. The outlet moisture contents achieved have typically been 10%. Analysis of the test data and cost estimates of the equipment indicate that the pulse combustion drying system is at least comparable to existing systems in terms of operating costs, and offers very significant savings in capital costs. Testing with various other materials such as wood pulp, sludges and peat is continuing to further assess the equipment`s performance.

Measurement of particles at wood combustion - comparison of measurements in chimney and dilution tunnel; Partikelmaetning vid vedeldning - Jaemfoerelse mellan provtagning i skorsten och spaedtunnel

Energy Technology Data Exchange (ETDEWEB)

Ryde, Daniel; Johansson, Linda

2007-07-01

According to the European standard EN 303-5, particle emissions are measured during testing of wood fired boilers. However, it is possible to measure these emissions using any established method. This may contribute to uncertainties when comparing data from boilers measured with different methods. In this project, particle emission measurements in hot gases in chimney (Swedish method) and in a dilution tunnel (Norwegian method) are compared.The value of the ratio between particulate emissions (PM) measured in the dilution tunnel and PM measured in the chimney varied between 2 and 10, while the specific CO emission was 4 - 140 g/kg dry wood supplied. The more unfavourable combustion conditions, the larger difference between the measurement methods was seen. Furthermore, different measurements at the same case were more scattered at poor combustion conditions. Consequently, it is very important to consider if particle emission data have been measured in the chimney or in a dilution tunnel when using emission data from domestic wood combustion

Domestic heating - the biomass challenge

International Nuclear Information System (INIS)

Rakos, C.

1999-01-01

This article highlights currently available efficient, low emission technical concepts for the combustion of wood, log-burning boilers, woodchip boilers, and the use of wood pellets. The economics of domestic heating with wood, the higher costs incurred with modern efficient wood burners as compared with fuelwood costs, and the proposed European Commission's campaign to implement more wood heated dwellings are discussed, and the transition from traditional to modern wood heating, and options for stimulating growth in renewable energy are considered

Influence of Torrefaction on Single Particle Combustion of Wood

DEFF Research Database (Denmark)

Lu, Zhimin; Jian, Jie; Jensen, Peter Arendt

2016-01-01

This study focuses on the influence of torrefaction on the char reactivity, char yield, and combustion time of 3-5 mm spherical wood particles in a single particle combustion reactor (SPC) operating at a nominal temperature of 1231 °C. The devolatilization times were reduced and the char burnout...

Importance of small-scale wood combustion for the air quality at Lycksele and Vaexjoe

International Nuclear Information System (INIS)

Johansson, C.; Hansson, H.C.; Stroem, Johan; Hedberg, Emma; Olivares, Gustavo; Karlsson, Hans; Wideqvist, Ulla

2005-02-01

from Forsdala are however not entirely conclusive in this respect. A more stable method to quantify the contribution of wood smoke to PM concentrations is likely to be a source-receptor modelling based on a number of elements. These elemental concentrations may be derived from a PIXE analysis of filter samples, as in this report. In Teleborg, the TEOM measured PM 1 , but not PM 2.5 . The PM 2.5 concentrations were instead derived from the observed number size distributions. PMF models for measured PM 1 (TEOM), estimated PM 1 (DMPS), and PM 2.5 (DMPS+APS) showed fairly similar results regarding the source apportionment. In Teleborg, a distinct source representing local combustion (wood, oil) could be discerned. The source strength was definitely connected to the local heat demand and outdoor temperature, and was only significant for temperatures below 0 deg C. The other sources do not display this behaviour. The source profile is characteristic of wood combustion, but with a clear contamination from oil combustion. The contribution from the local combustion source (wood, oil) to PM concentrations in Teleborg (4-5.5 pg/m 3 ) was estimated to be approximately the same as that from domestic wood combustion in Forsdala, Lycksele (3-4 μg/m 3 ). While this may not be entirely unrealistic considering the large number of wood stoves in the residential area surrounding the measurement site in Teleborg, it is seemingly contradicted by the estimates made of the energy consumption in the area, and the relatively low concentrations of levoglucosan. A comparison between the concentrations of PM 2.5 in background air with the PM concentrations in Vaexjoe show that there is not much room for any strong local sources in Vaexjoe. The various PM measurements in background air and Vaexjoe respectively are however not directly comparable, and may be reconciled with a local PM source of 4-5.5 μg/m 3

Investigating co-combustion characteristics of bamboo and wood.

Science.gov (United States)

Liang, Fang; Wang, Ruijuan; Jiang, Changle; Yang, Xiaomeng; Zhang, Tao; Hu, Wanhe; Mi, Bingbing; Liu, Zhijia

2017-11-01

To investigate co-combustion characteristics of bamboo and wood, moso bamboo and masson pine were torrefied and mixed with different blend ratios. The combustion process was examined by thermogravimetric analyzer (TGA). The results showed the combustion process of samples included volatile emission and oxidation combustion as well as char combustion. The main mass loss of biomass blends occurred at volatile emission and oxidation combustion stage, while that of torrefied biomass occurred at char combustion stage. With the increase of bamboo content, characteristic temperatures decreased. Compared with untreated biomass, torrefied biomass had a higher initial and burnout temperature. With the increase of heating rates, combustion process of samples shifted to higher temperatures. Compared with non-isothermal models, activation energy obtained from isothermal model was lower. The result is helpful to promote development of co-combustion of bamboo and masson pine wastes. Copyright © 2017 Elsevier Ltd. All rights reserved.

Chemical composition and speciation of particulate organic matter from modern residential small-scale wood combustion appliances.

Science.gov (United States)

Czech, Hendryk; Miersch, Toni; Orasche, Jürgen; Abbaszade, Gülcin; Sippula, Olli; Tissari, Jarkko; Michalke, Bernhard; Schnelle-Kreis, Jürgen; Streibel, Thorsten; Jokiniemi, Jorma; Zimmermann, Ralf

2018-01-15

Combustion technologies of small-scale wood combustion appliances are continuously developed decrease emissions of various pollutants and increase energy conversion. One strategy to reduce emissions is the implementation of air staging technology in secondary air supply, which became an established technique for modern wood combustion appliances. On that account, emissions from a modern masonry heater fuelled with three types of common logwood (beech, birch and spruce) and a modern pellet boiler fuelled with commercial softwood pellets were investigated, which refer to representative combustion appliances in northern Europe In particular, emphasis was put on the organic constituents of PM2.5, including polycyclic aromatic hydrocarbons (PAHs), oxygenated PAHs (OPAHs) and phenolic species, by targeted and non-targeted mass spectrometric analysis techniques. Compared to conventional wood stoves and pellet boilers, organic emissions from the modern appliances were reduced by at least one order of magnitude, but to a different extent for single species. Hence, characteristic ratios of emission constituents and emission profiles for wood combustion identification and speciation do not hold for this type of advanced combustion technology. Additionally, an overall substantial reduction of typical wood combustion markers, such as phenolic species and anhydrous sugars, were observed. Finally, it was found that slow ignition of log woods changes the distribution of characteristic resin acids and phytosterols as well as their thermal alteration products, which are used as markers for specific wood types. Our results should be considered for wood combustion identification in positive matrix factorisation or chemical mass balance in northern Europe. Copyright © 2017 Elsevier B.V. All rights reserved.

Estimated contribution from wood combustion to air pollution in Hamar, Lillehammer and Gjoevik

International Nuclear Information System (INIS)

Schjoldager, J.

1996-07-01

The report analyses the level of air pollution from wood combustion in urban areas in Norway. From the analysis of potassium and soot in samples from January 1992, there were large uncertainties in the estimation of particle contributions from the combustion. Concentration estimates of formaldehyde from wood combustion were comparable to measurements, while estimated PAH (Polycyclic Aromatic Hydrocarbons) concentrations were lower than measurements. 18 refs., 1 fig., 6 tabs

Combustion properties of wood impregnated with commercial ...

African Journals Online (AJOL)

The objective of this study was to determine some combustion properties of Calabrian pine (Pinus brutia Ten.) wood specimens impregnated with aqueous solutions of commercial fertilizers. Ammonium sulphate (AS) and diammonium phosphate (DAP) were used as commercial fertilizers. Diammonium phosphate and ...

Small scale wood combustion in Germany. Recent research and trends

Energy Technology Data Exchange (ETDEWEB)

Maier, H.; Unterberger, S.; Hein, K.R.G. [Institute of Process Engineering and Power Plant Technology, University of Stuttgart (Germany)

1998-12-31

To reduce Europe`s greenhouse gas emission CO{sub 2} it is a challenging task utilising biomass fuels as there are wood or wood residues from the forest industry. The utilisation can be done either in commercially operated medium (> 50 kWth) or full scale (> 1 MWth) decentralised heat and power stations or in small scale (< 50 kWth) domestic heating systems. In small scale heating systems untreated wood logs, wood briquette or wood pellets and in few cases wood chips are used. The present market in Germany is focused on the use of wood logs. Presently, the use of wood pellets in small scale automatically operated boilers < 15 kW especially for low energy houses is discussed more and more. Since 1980 the installation of new wood fired small scale domestic heating systems reached a significant size due to the interest of the customers to have a alternative inhouse heating system and to increase the living comfort. In 1994 the amount of sold small scale heaters in Germany were in total about 133.258 units. The thermal power of in 1994 sold units is estimated of about 1350 MW which is a significant size in total with regard to domestic heating purposes. Since few years there is a clear market trend in Germany towards the installation of open fire stoves. Due to this trend in Germany and the design characteristic of open fire stoves using huge glass doors of glass windows it is very difficult to achieve a further reduction of emissions like CO and unburned volatile hydrocarbons (VOC). In the text the requirements for modern small scale wood fired stoves in Germany as well as the actual stage and trend of research and development (R and D) are discussed 4 refs.

Interactive wood combustion for botanical tree models

KAUST Repository

Pirk, Sören

2017-11-22

We present a novel method for the combustion of botanical tree models. Tree models are represented as connected particles for the branching structure and a polygonal surface mesh for the combustion. Each particle stores biological and physical attributes that drive the kinetic behavior of a plant and the exothermic reaction of the combustion. Coupled with realistic physics for rods, the particles enable dynamic branch motions. We model material properties, such as moisture and charring behavior, and associate them with individual particles. The combustion is efficiently processed in the surface domain of the tree model on a polygonal mesh. A user can dynamically interact with the model by initiating fires and by inducing stress on branches. The flames realistically propagate through the tree model by consuming the available resources. Our method runs at interactive rates and supports multiple tree instances in parallel. We demonstrate the effectiveness of our approach through numerous examples and evaluate its plausibility against the combustion of real wood samples.

Environmental assessment of wood domestic heating. Synthetic report

International Nuclear Information System (INIS)

2005-12-01

This report proposes a synthesis of the results of an environmental assessment of wood domestic heating. This study is based on a life cycle analysis which quantifies the impacts on the environment of all the related activities: fuel extraction, retailing, final use, and so on. Environmental impacts are assessed by means of different indicators: energetic assessment, greenhouse effect assessment, air pollution (acidification), water pollution (eutrophication), toxic material emissions in air and into the soils. Wood is compared to other heating sources (gas, fuel, electricity). Ways to improve this environmental assessment are discussed for the different types of wood (logs, pellets)

Emissions from small scale combustion of pelletized wood fuels

International Nuclear Information System (INIS)

Bachs, A.

1998-01-01

Combustion of wood pellets in small scale heating systems with an effect below 20 kW has increased. During the winter season 1995/96 1500 small plants for heating houses are estimated to be in operation. Stack emissions from three pellet burners and two pellet stoves have been studied at laboratory. Different pellet qualities were tested. When the fraction of fines increased also the NO x emissions increased with about 10 %. As reference fuel 8 mm pellets was used. Tests with 6 mm pellets gave, in most cases, significant lower emissions of CO and THC. Eleven stoves, burners and boilers were studied in a field test. The results show that all the plants generally have higher emissions in the field than during conditions when the plants are adjusted with a stack gas monitoring instrument. A conclusion is that it is difficult for the operator to adjust the plant without a monitoring instrument. The emissions from the tested plants give an estimation of stack gas emissions from small scale pellet plants. The difference between the 'best' and 'worst' technologies is big. The span of emissions with the best technology to the worst is given below. The interval is concerning normal combustion . During abnormal conditions the emissions are on a significant higher level: * CO 80-1 000 mg/MJ; * Tar 0,3-19 mg/MJ; * THC (as methane equivalents) 2-100 mg/MJ; * NO x 50-70 mg/W;, and * Dust emissions 20-40 mg/MJ. Emissions from pellets heating are lower than from wood combustion and the best technology is close to the emission from oil burners. Wood and pellets have the same origin but the conditions to burn them in an environmental friendly way differ. Combustion of pellets could be improved through improved control of the air and fuel ratio that will create more stable conditions for the combustion

A practical approach in porous medium combustion for domestic application: A review

Science.gov (United States)

Ismail, A. K.; Ibrahim, N. H.; Shamsuddin, K. A.; Abdullah, M. Z.; Zubair, M.

2018-05-01

Combustion in porous media has been widely studied. Many application involving the combustion of porous media has been reported in various way with most consider on numerical works and industrial application. Besides, recent application of porous medium combustion for domestic is the topic of interest among researchers. In this paper, a review was conducted on the combustion of porous media in term of practical application for domestic consumers. Details on the type of fuel used including bio fuel and their system have been search thoroughly. Most of the system have utilized compressed air system to provide lean combustion in domestic application. Some self-aspirating system of porous medium burner was also reported. The application of new technology such as cogeneration by using thermoelectric cells in tandem with porous medium combustion is also revised according to recent work which have already been published. Besides, the recent advances which include coating of porous material is also considered at the end of this paper.

Thermochemical Modeling and Experimental Validation of Wood Pyrolysis Occurring During Pre-ignition Combustion

Science.gov (United States)

Fawaz, M.; Lautenberger, C.; Bond, T. C.

2017-12-01

The use of wood as a solid fuel for cooking and heating is associated with high particle emission which largely contribute to the dispersion of particulate matter (PM) in the atmosphere. The majority of those particles are released during the "pre-ignition" phase, i.e., before flaming of the wood occurs. In this work, we investigate the factors that influence the emission of PM during pre-ignition and lead to high particle emission to the atmosphere. During this combustion phase, at elevated temperature, pyrolysis is responsible for wood degradation and the production of gaseous materials that travel and exit the wood. We model the thermal degradation using Gpyro, an open source finite volume method numerical model to simulate heat, mass, and momentum transfer in the wood. In our analysis, we study factors that vary during combustion and that influence emission of PM: wood sample size and boundary conditions. In a fire the boundary conditions represent the thermal energy a piece of wood receives from the surrounding in the form of heat flux. We find that heat transfer is the limiting process governing the production and transport of gas from the wood, and that the amount of emitted PM is dependent on the size of the wood. The dependence of heat transfer from the boundaries on PM emission becomes more important with increasing wood log size. The model shows that a small log of wood (6cm by 2cm) emits close values of total mass of gas at low and high heat fluxes. For a large log of wood (20cm by 5cm) the total mass of gas emitted increases by 30% between low and high heat flux. We validate the model results with a controlled-temperature reactor that accommodates centimeter scale wood samples. The size of the wood used, indicates the abundance of wood in the region where wood is used a solid fuel. Understanding those factors will allow for defining conditions that result in reducing particle emissions during combustion.

RESIDENTIAL WOOD COMBUSTION TECHNOLOGY REVIEW - VOLUME 2. APPENDICES

Science.gov (United States)

The report gives results of a review of the current state-of-the-art of residential wood combustion (RWC). The key environmental parameter of concern was the air emission of particles. The technological status of all major RWC categories--cordwood stoves, fireplaces, masonry heat...

Changes of indoor climate by the adoption of retrofitted wood-burning stoves

DEFF Research Database (Denmark)

Luis Teles de Carvalho, Ricardo; Jensen, Ole Michael; Tarelho, Luis A. C.

2014-01-01

More than 3 billion people in the world rely on local solid-fuels for domestic cooking and heating through inefficient combustion, causing indoor air pollution and overheating worldwide. Technological regimes were categorized in 18 popular stove models to describe how residential wood combustion ...

Emission factors of particulate matter, polycyclic aromatic hydrocarbons, and levoglucosan from wood combustion in south-central Chile.

Science.gov (United States)

Jimenez, Jorge; Farias, Oscar; Quiroz, Roberto; Yañez, Jorge

2017-07-01

In south-central Chile, wood stoves have been identified as an important source of air pollution in populated areas. Eucalyptus (Eucalyptus globulus), Chilean oak (Nothofagus oblique), and mimosa (Acacia dealbata) were burned in a single-chamber slow-combustion wood stove at a controlled testing facility located at the University of Concepción, Chile. In each experiment, 2.7-3.1 kg of firewood were combusted while continuously monitoring temperature, exhaust gases, burn rate, and collecting particulate matter samples in Teflon filters under isokinetic conditions for polycyclic aromatic hydrocarbon and levoglucosan analyses. Mean particulate matter emission factors were 2.03, 4.06, and 3.84 g/kg dry wood for eucalyptus, oak, and mimosa, respectively. The emission factors were inversely correlated with combustion efficiency. The mean emission factors of the sums of 12 polycyclic aromatic hydrocarbons in particle phases were 1472.5, 2134.0, and 747.5 μg/kg for eucalyptus, oak, and mimosa, respectively. Fluoranthene, pyrene, benzo[a]anthracene, and chrysene were present in the particle phase in higher proportions compared with other polycyclic aromatic hydrocarbons that were analyzed. Mean levoglucosan emission factors were 854.9, 202.3, and 328.0 mg/kg for eucalyptus, oak, and mimosa, respectively. Since the emissions of particulate matter and other pollutants were inversely correlated with combustion efficiency, implementing more efficient technologies would help to reduce air pollutant emissions from wood combustion. Residential wood burning has been identified as a significant source of air pollution in populated areas. Local wood species are combusted for home cooking and heating, which releases several toxic air pollutants, including particulate matter, carbon monoxide, and polycyclic aromatic hydrocarbons. Air pollutant emissions depend on the type of wood and the technology and operational conditions of the wood stove. A better understanding of emissions from

Emissions from three wood-fired domestic central heating boilers - heat load dependence

International Nuclear Information System (INIS)

Karlsson, M.L.

1992-01-01

The flue gases from three wood-fired domestic central heating boilers have been characterized. Measurements were made at three part loads; 3, 7 and 15 kW. Two of the boilers were modern multi-fuel boilers, with inverse firing and natural draught. The third boiler was a single-fuel wood boiler, with inverse firing and combustion air supply through a fan. All boilers were environmentally approved; the tar emissions were below 30 mg/MJ at nominal heat load. The following parameters were measured: - CO, CO 2 , NO x , total hydrocarbons (THC), - tar and particulates, - twelve volatile organic compounds (VOC). The limit value for tar emission was heavily exceeded for all three boilers at the part loads at which they were tested. For the two multi-fuel boilers the tar emissions decreased with increasing load level, while the opposite was found for the wood boiler with a fan. The NO x emissions varied between 20 and 120 mg/MJ. The multi-fuel boilers showed increasing NO x emissions with increasing heat load. The single-fuel wood boiler showed NO x emissions at about 60 mg/MJ, independent of load level. The CO and THC levels in general were high. The CO levels varied between 1000 and 2000 mg/MJ. While the THC levels varied between 300 and 4000 mg/MJ. Broadly speaking, the CO and THC levels decreased with increasing load levels for the multi-fuel boilers. For the single-fuel wood boiler the CO and THC levels were roughly the same at all load levels. Out of the twelve VOC compounds which were measured, the following could be detected and quantified. With FTIR analysis: Methane, ethylene, propene and acetylene. With GC analysis: Methanol, phenol and acetic acid. (1 ref., 31 figs., 7 tabs.)

Morphology, composition, and mixing state of primary particles from combustion sources - crop residue, wood, and solid waste.

Science.gov (United States)

Liu, Lei; Kong, Shaofei; Zhang, Yinxiao; Wang, Yuanyuan; Xu, Liang; Yan, Qin; Lingaswamy, A P; Shi, Zongbo; Lv, Senlin; Niu, Hongya; Shao, Longyi; Hu, Min; Zhang, Daizhou; Chen, Jianmin; Zhang, Xiaoye; Li, Weijun

2017-07-11

Morphology, composition, and mixing state of individual particles emitted from crop residue, wood, and solid waste combustion in a residential stove were analyzed using transmission electron microscopy (TEM). Our study showed that particles from crop residue and apple wood combustion were mainly organic matter (OM) in smoldering phase, whereas soot-OM internally mixed with K in flaming phase. Wild grass combustion in flaming phase released some Cl-rich-OM/soot particles and cardboard combustion released OM and S-rich particles. Interestingly, particles from hardwood (pear wood and bamboo) and softwood (cypress and pine wood) combustion were mainly soot and OM in the flaming phase, respectively. The combustion of foam boxes, rubber tires, and plastic bottles/bags in the flaming phase released large amounts of soot internally mixed with a small amount of OM, whereas the combustion of printed circuit boards and copper-core cables emitted large amounts of OM with Br-rich inclusions. In addition, the printed circuit board combustion released toxic metals containing Pb, Zn, Sn, and Sb. The results are important to document properties of primary particles from combustion sources, which can be used to trace the sources of ambient particles and to know their potential impacts in human health and radiative forcing in the air.

Modelling and simulation of wood chip combustion in a hot air generator system.

Science.gov (United States)

Rajika, J K A T; Narayana, Mahinsasa

2016-01-01

This study focuses on modelling and simulation of horizontal moving bed/grate wood chip combustor. A standalone finite volume based 2-D steady state Euler-Euler Computational Fluid Dynamics (CFD) model was developed for packed bed combustion. Packed bed combustion of a medium scale biomass combustor, which was retrofitted from wood log to wood chip feeding for Tea drying in Sri Lanka, was evaluated by a CFD simulation study. The model was validated by the experimental results of an industrial biomass combustor for a hot air generation system in tea industry. Open-source CFD tool; OpenFOAM was used to generate CFD model source code for the packed bed combustion and simulated along with an available solver for free board region modelling in the CFD tool. Height of the packed bed is about 20 cm and biomass particles are assumed to be spherical shape with constant surface area to volume ratio. Temperature measurements of the combustor are well agreed with simulation results while gas phase compositions have discrepancies. Combustion efficiency of the validated hot air generator is around 52.2 %.

Using monosaccharide anhydrides to estimate the impact of wood combustion on fine particles in the Helsinki Metropolitan Area

Energy Technology Data Exchange (ETDEWEB)

Saarnio, K.; Saarikoski, S. [Finnish Meteorological Institute, Helsinki (Finland); Niemi, J.V. [HSY Helsinki Region Environmental Services Authority, Helsinki (Finland)

2012-11-01

The spatiotemporal variation of ambient particles under the influence of biomass burning emissions was studied in the Helsinki Metropolitan Area (HMA) in selected periods during 2005-2009. Monosaccharide anhydrides (MAs; levoglucosan, mannosan and galactosan), commonly known biomass burning tracers, were used to estimate the wood combustion contribution to local particulate matter (PM) concentration levels at three urban background sites close to the city centre, and at three suburban sites influenced by local small-scale wood combustion. In the cold season (October-March), the mean MAs concentrations were 115-225 ng m{sup -3} and 83-98 ng m{sup -} {sup 3}at the suburban and urban sites, respectively. In the warm season, the mean MAs concentrations were low (19-78 ng m{sup -3}), excluding open land fire smoke episodes (222-378 ng m{sup -}3{sup )}. Regionally distributed wood combustion particles raised the levels over the whole HMA while particles from local wood combustion sources raised the level at suburban sites only. The estimated average contribution of wood combustion to fine particles (PM{sub 2.5}) ranged from 18% to 29% at the urban sites and from 31% to 66% at the suburban sites in the cold season. The PM measurements from ambient air and combustion experiments showed that the proportions of the three MAs can be utilised to separate the wildfire particles from residential wood combustion particles. (orig.)

Emissions from fireplace and woodstove combustion of prevalent Portuguese woods

Science.gov (United States)

Alves, Célia

2010-05-01

P. Fernandes, C. Gonçalves, C.A. Alves, L. Tarelho, F. Mirante, T. Nunes and C. Pio Centre for Environmental and Marine Studies, Department of Environment, University of Aveiro, 3810-193 Aveiro, Portugal In Portugal, it was estimated that around 390000 ton/year of wood is burned in fireplaces, although the chemical characterisation of emission profiles has not yet been performed. Emission inventories and source apportionment, photochemistry and climate change models use values obtained for American or Alpine wood-fuels, uncommon in South Europe. Previous work has suggested that the species of wood used can have a huge influence on the particle emissions. Since the distribution of compounds emitted differs by species and burning conditions and there are many variations among published profiles, it is desirable to obtain specific data at a regional level on the chemical characterisation of wood smoke. A series of source tests was performed to compare the emission profiles from the woodstove combustion to those of fireplaces. Eight types of biomass were burned in the laboratory: seven species of wood grown in Portugal (Pinus pinaster, Eucalyptus globulus, Quercus suber, Acacia longifolia, Quercus faginea, Olea europea, Quercus ilex rotundifolia), and briquettes of biomass residues. The gas sampling was carried out in the exhaust ducts of both combustion systems. The collection of particles (PM2.5) was conducted in the dilution tunnel that was directly coupled to the chimney. Dilution sampling was used to characterise fine particle emissions from the combustion sources because it simulates the rapid cooling and dilution that occurs as exhaust mixes with the atmosphere. During each burning cycle, the concentrations of O2, CO2 and CO, as well as operational parameters (e.g. temperatures, flows, etc.), were automatically monitored. The PM2.5 samples were analysed by a thermal optical technique in order to obtain their organic carbon (OC) and elemental carbon (EC) content

Cold shock on the wood fuel industry

International Nuclear Information System (INIS)

Queyrel, A.

2008-01-01

The development of the wood fuel industry represents one of the pillars of the European energy plan, and in particular of the French energy policy, as it fulfills both objectives of development of renewable energy sources and CO 2 balance. The wood fuel industry supplies 6% of the French energy consumption and has permitted to save more than 9 million tons of petroleum equivalent. However, the conclusions of the European project CARBOSOL stress on the strong health impacts of wood-fueled combustion systems, in particular in the case of domestic individual systems and appliances. The combustion of biomass (fireplaces and agriculture) is responsible for 50 to 70% of the winter carbon pollution in Europe. The situation of collective or industrial wood-fueled facilities is different since pollution control solutions can be more easily implemented. (J.S.)

Faecal-wood biomass co-combustion and ash composition analysis.

Science.gov (United States)

Somorin, Tosin Onabanjo; Kolios, Athanasios J; Parker, Alison; McAdam, Ewan; Williams, Leon; Tyrrel, Sean

2017-09-01

Fuel blending is a widely used approach in biomass combustion, particularly for feedstocks with low calorific value and high moisture content. In on-site sanitation technologies, fuel blending is proposed as a pre-treatment requirement to reduce moisture levels and improve the physiochemical properties of raw faeces prior to drying. This study investigates the co-combustion performance of wood dust: raw human faeces blends at varying air-to-fuel ratios in a bench-scale combustor test rig. It concludes with ash composition analyses and discusses their potential application and related problems. The study shows that a 50:50 wood dust (WD): raw human faeces (FC) can reduce moisture levels in raw human faeces by ∼40% prior to drying. The minimum acceptable blend for treating moist faeces without prior drying at a combustion air flow rate of 14-18 L/min is 30:70 WD: FC. For self-sustained ignition and flame propagation, the minimum combustion temperature required for conversion of the fuel to ash is ∼400 °C. The most abundant elements in faecal ash are potassium and calcium, while elements such as nickel, aluminium and iron are in trace quantities. This suggests the potential use of faecal ash as a soil conditioner, but increases the tendency for fly ash formation and sintering problems.

Particulate emissions from residential wood combustion

DEFF Research Database (Denmark)

Luis Teles de Carvalho, Ricardo; Jensen, Ole Michael; Tarelho, Luis A. C.

Residential wood combustion (RWC) in fireplaces and conventional appliances is the main contributor to fine particulate matter (PM2.5) emissions in Denmark and Portugal representing more than 30% of the total emissions [1;2]. Such estimations are uncertain concerning the wood consumption...... and official emission factors, not taking into account actual burning conditions in dwellings [3]. There is limited knowledge on the real-life performance and spatial distribution of existing appliance types. Few studies have been targeting to understand the influence of fuel operation habits on PM2...... the available estimations for Denmark and Portugal, suggesting a methodology to increase the accuracy of activity data and emission factors. This work is based on new studies carried out to quantify the PM2.5 emissions in daily life through field experiments in Danish dwellings and by considering typical...

Study of PAH emission from the solid fuels combustion in residential furnaces

International Nuclear Information System (INIS)

Kakareka, Sergey V.; Kukharchyk, Tamara I.; Khomich, Valery S.

2005-01-01

The procedure for and results of a test study of polycyclic aromatic hydrocarbon (PAH) emission from a few types of solid fuels combustion in residential furnaces of various designs typical for Belarus are discussed. Greatest levels of PAH emission were detected from domestic wastes and wood waste combustion. Lowest levels of PAH emission are from peat briquette combustion. It was found that PAH concentration in off-gases from firewood combustion also varies significantly depending on the type of wood: the highest values of PAH are typical for waste gases from birch firewood combustion in comparison with pine firewood combustion. Draft PAH emission factors are proposed with intended application for emission inventory of such installations

Emissions from co-combustion of wood and household refuse

International Nuclear Information System (INIS)

Zhang, X.J.; Peterson, F.

1996-01-01

An investigation was carried out on the emissions produced in a 20 kW experimental boiler burning a combination of wood and household refuse. The wood content ranged form 10 to 50%. Direct sampling with Tenax adsorbent was used to cover a range of volatile organic compounds (VOCs). The measurements also included unburned hydrocarbons, carbon monoxide, carbon dioxide, oxygen and flue gas temperature. Combustion and emission parameters were recorded continuously with a multi-point data logger. VOCs were analyzed by gas chromatography and mass spectrometer (GC/MS). The main emphasis was placed on the effect of wood on VOC emissions. The results showed that as the wood content increased from 10 to 50%, there was a roughly linear increase in emissions of total VOCs. Carbon monoxide and unburned hydrocarbon emissions also increased. These results suggest that household refuse is a good substitute for wood as a boiler fuel, as it has a similar calorific value but fewer emissions. (Author)

Challenges in assessing air pollution from residential wood combustion

DEFF Research Database (Denmark)

Olesen, Helge Rørdam

2016-01-01

The paper highlights a number of important challenges in quantifying the impact of residential wood combustion on air quality. The fact that real life emissions are controlled by the behaviour of the users makes it a challenge to determine representative emission factors. Further, in respect...

RESIDENTIAL WOOD COMBUSTION TECHNOLOGY REVIEW VOLUME 1. TECHNICAL REPORT

Science.gov (United States)

This report gives results of a review of the current state-of-the-art of residential wood combustion (RWC). The key environmental parameter of concern was the air emission of particles. The technological status of all major RWC categories -- cordwood stoves, fireplaces, masonry h...

Spatial emission modelling for residential wood combustion in Denmark

DEFF Research Database (Denmark)

Plejdrup, Marlene Schmidt; Nielsen, Ole-Kenneth; Brandt, Jørgen

2016-01-01

Residential wood combustion (RWC) is a major contributor to atmospheric pollution especially for particulate matter. Air pollution has significant impact on human health, and it is therefore important to know the human exposure. For this purpose, it is necessary with a detailed high resolution sp...

Combustion in fluidized bed reactors; Verbrennung in Wirbelschichtreaktoren

Energy Technology Data Exchange (ETDEWEB)

Thome-Kozmiensky, Karl J. [vivis CONSULT GmbH, Nietwerder (Germany)

2013-03-01

Since the first application for the coal gasification, the fluidized bed technology has passed an impressive development. Nowadays, the fluidized bed technology is utilized at chemical processes, drying and cooling, gasification, combustion and purification of exhaust gas. In the firing technology, the fluidized technology initially has been proved in the combustion of very high ash coal and sewage sludge. Recently, the fluidized bed technology also is applied in the drying of sewage sludge, combustion of domestic waste - as in Japan and Sweden - as well as in the gasification and combustion of substitute fuels, biomass - wood pellets, wood chips, straw, cocoa shells and so forth - and residues from the paper manufacturing - such as in Germany and Austria. Under this aspect, the author of the contribution under consideration reports on the combustion of sewage sludge, substitute fuels and biomass.

[Environmental and health impacts of wood combustion to produce heat and power].

Science.gov (United States)

Valerio, Federico

2012-01-01

Toxic chemicals such as benzene, polycyclic aromatic hydrocarbons, dioxins, and ultra fine particles were found in the smoke produced by wood combustion. Emission factors confirm that, to produce the same energy amount, many more pollutants are emitted by wood than by natural gas. Biomass burning produces a relevant deterioration of air quality inside and outside houses, notably due to emissions of fine and ultra fine dust (PM10, PM2.5) according to reviewed studies. Important improvements in emission quality are obtained with the use of more efficient household heating systems, both in developed and in developing countries. Numerous studies have assessed the possible health effects produced by wood smoke, providing sufficient evidence that the indoor exposure to wood smoke, even in developed countries, can have adverse effects on human health. In 2010 IARC classified wood smoke as a possible human carcinogen. In Europe, electricity generation from biomass combustion is increasing (12% each year) thanks to incentives provided to reduce greenhouse gas emissions and use of fossil fuels.Today adequate studies to assess the environmental and health effects of emissions from power plants fuelled by solid biomasses are still needed.

Source apportionment of PM2.5 at multiple Northwest U.S. sites: Assessing regional winter wood smoke impacts from residential wood combustion

Science.gov (United States)

Kotchenruther, Robert A.

2016-10-01

Wood smoke from residential wood combustion is a significant source of elevated PM2.5 in many communities across the Northwest U.S. Accurate representation of residential wood combustion in source-oriented regional scale air quality models is challenging because of multiple uncertainties. As an alternative to source-oriented source apportionment, this work provides, through receptor-oriented source apportionment, an assessment of winter residential wood combustion impacts at multiple Northwest U.S. locations. Source apportionment was performed on chemically speciated PM2.5 from 19 monitoring sites using the Positive Matrix Factorization (PMF) receptor model. Each site was modeled independently, but a common data preparation and modeling protocol was used so that results were as comparable as possible across sites. Model solutions had from 4 to 8 PMF factors, depending on the site. PMF factors at each site were associated with a source classification (e.g., primary wood smoke), a dominant chemical composition (e.g., ammonium nitrate), or were some mixture. 15 different sources or chemical compositions were identified as contributing to PM2.5 across the 19 sites. The 6 most common were; aged wood smoke and secondary organic carbon, motor vehicles, primary wood smoke, ammonium nitrate, ammonium sulfate, and fugitive dust. Wood smoke was identified at every site, with both aged and primary wood smoke identified at most sites. Wood smoke contributions to PM2.5 were averaged for the two winter months of December and January, the months when wood smoke in the Northwest U.S. is mainly from residential wood combustion. The total contribution of residential wood combustion, that from primary plus aged smoke, ranged from 11.4% to 92.7% of average December and January PM2.5 depending on the site, with the highest percent contributions occurring in smaller towns that have fewer expected sources of winter PM2.5. Receptor modeling at multiple sites, such as that conducted in this

Combustion behaviour of pulverised wood - Numerical and experimental studies

Energy Technology Data Exchange (ETDEWEB)

Lixin Tao [TPS Termiska Processer AB, Nykoeping (Sweden)

2002-05-01

This report presents the experimental results achieved in an on-going project financed by STEM (Energimyndigheten) within the research program 'Gasification and combustion of solid fuels', during the first phase of the project (2001-03-05 to 2002-03-05). The project is a collaboration project between LTH and TPS on combined numerical modelling/experimental investigation on combustion of pulverised wood. Particularly TPS carry out the experimental investigation in a laboratory vertical furnace. During the project, the experimental rig has been developed. The experimental furnace has an inner diameter of 0.25 m and a height of 4 m. A pulverised wood flame is established using an axial burner that is installed on the top of the furnace. Experimental study on a selected pulverised wood with determined size distribution and anisotropy character has been carried out in this furnace. During the experiment, the wall temperatures of the furnace were continuously measured using 8 thermocouples of type K that are installed on the wall with a spacing about 0.5 m. The gas temperatures in the furnace were monitored using 5 fixed suction pyrometers that are placed along the centre of the furnace. At the bottom of the furnace, a fixed gas-sampling probe was installed. The flue gas concentrations were continuously monitored with on-line gas analysers. The extent of combustion was measured through the analysis of sampled gaseous products and condensable solid products. A movable liquid quench probe was used to carry out the gas and solid sampling through a number of sampling holes that are opened along the furnace wall. The quench liquor used is an alkaline water solution containing a small amount of a detergent to dissolve HCN and tar. The quench liquor and solid samples were separated and collected in a knockout pot. The gas was filtered and passed through two bubblers with acidic solution to collect NH{sub 3}. The gas concentrations were then analysed with on-line gas

Ambient air pollution associated to domestic wood burning heating systems

International Nuclear Information System (INIS)

Friboulet, I.; Durif, M.; Malherbe, L.

2009-01-01

Main publications are considering effects of wood burning appliances on indoor air quality, which is a major issue in some countries. But impacts on ambient air, close environment and human exposure are rather poorly characterised so far. Besides, woods burning for domestic purpose may develop in the next years while promoting bio fuels. The aim of the ongoing study is to assess in which conditions associated air pollution and population exposure could be significant, this poster shows preliminary results of the impact of a village of 98 houses equipped with a wood burning heating system. (N.C.)

Morphology, composition, and mixing state of primary particles from combustion sources ? crop residue, wood, and solid waste

OpenAIRE

Liu, Lei; Kong, Shaofei; Zhang, Yinxiao; Wang, Yuanyuan; Xu, Liang; Yan, Qin; Lingaswamy, A. P.; Shi, Zongbo; Lv, Senlin; Niu, Hongya; Shao, Longyi; Hu, Min; Zhang, Daizhou; Chen, Jianmin; Zhang, Xiaoye

2017-01-01

Morphology, composition, and mixing state of individual particles emitted from crop residue, wood, and solid waste combustion in a residential stove were analyzed using transmission electron microscopy (TEM). Our study showed that particles from crop residue and apple wood combustion were mainly organic matter (OM) in smoldering phase, whereas soot-OM internally mixed with K in flaming phase. Wild grass combustion in flaming phase released some Cl-rich-OM/soot particles and cardboard combusti...

Release of Inorganic Elements during Wood Combustion. Release to the Gas Phase of Inorganic Elements during: Wood Combustion. Part 1: Development and Evaluation of Quantification Methods

DEFF Research Database (Denmark)

van Lith, Simone Cornelia; Alonso-Ramírez, Violeta; Jensen, Peter Arendt

2006-01-01

During wood combustion, inorganic elements such as alkali metals, sulfur, chlorine, and some heavy metals are partly released to the gas phase, which may cause problems in combustion facilities because of deposit formation and corrosion. Furthermore, it may cause harmful emissions of gases......) in this reactor, whereas methods B and C involved initial pyrolysis and combustion, respectively, of a large fuel sample (~5 kg) in a bench-scale fixed-bed reactor at 500 C. The methods were evaluated by comparing the data on the release of Cl, S, K, Na, Zn, and Pb from fiber board obtained by the three methods...

Recycling of impregnated wood and impregnating agents - combustion plant technology; Kyllaestetyn puutavaran ja kyllaestysaineiden kierraetys - polttolaitostekniikka

Energy Technology Data Exchange (ETDEWEB)

Syrjaenen, T.; Kangas, E. [Kestopuu Oy, Helsinki (Finland)

2000-07-01

It has been estimated that in the 20th century it is possible to recycle about 70 000 m{sup 3} of impregnated wood, corresponding to about 48 % of the total amount of annually demolished impregnated wood. The amount is estimated to grow up to 130 000 m{sup 3} in 2015 (about 65% of demolished impregnated wood). In the beginning half of the recyclable impregnated wood is poles, but the share of sawn timber will increase as the time goes by. The poles and pieces of them are demolished and transported to an intermediate storage e.g. on the yard of an electricity supply company, from which they can be fetched in larger quantities. Even wood impregnation plant can act as intermediate storage sites. Collection points for impregnated construction timber can be established on timer sales companies, but most of it will be collected at waste processing sites. The economy of impregnated wood recycling chain depends on the sales income of generated energy. Calculations show that collection, transportation and processing costs can be covered with the sales of impregnated wood for energy generation and with recycling fees. The recycling fee for sawn timber would be 20 FIM/m{sup 3} and that for poles 64 FIM/m{sup 3}. In 2001 recycling fees were set for impregnated wood, the fees being 11 FIM/m{sup 3} for sawn timber and 42 FIM/m{sup 3} for poles. Collected impregnated wood can be crushed with either fixed or movable crushers used for crushing of waste wood. The impurities of wood (bolts, nails, stones, etc.), large dimensions of wood, in- homogenous material and dust require special features for the crushing equipment. Crushing device can be equipped with feeding crane and saw for processing of large-dimension wood, and metal detectors and magnetic separators if needed, but the large metal scrap has to be removed before crushing. At present in Finland there is not a combustion plant capable for combustion of impregnated wood without any modification. Improvements of flue gas

Elemental and organic carbon in flue gas particles of various wood combustion systems

Energy Technology Data Exchange (ETDEWEB)

Gaegauf, C.; Schmid, M.; Guentert, P.

2005-12-15

The airborne particulate matter (PM) in the environment is of ever increasing concern to authorities and the public. The major fractions of particles in wood combustion processes are in the size less than 1 micron, typically in the range of 30 to 300 nm. Of specific interest is the content of the elemental carbon (EC) and organic carbon (OC) in the particles since these substances are known for its particular potential as carcinogens. Various wood combustion systems have been analysed (wood chip boiler, pellet boiler, wood log boiler, wood stove and open fire). The sampling of the particles was done by mean of a multi-stage particle sizing sampler cascade impactor. The impactor classifies the particles collected according to their size. The 7 stages classify the particles between 0.4 and 9 microns aerodynamic diameter. The analytical method for determining the content of EC and OC in the particles is based on coulometry. The coulometer measures the conductivity of CO{sub 2} released by oxidation of EC in the samples at 650 {sup o}C. The OC content is determined by pyrolysis of the particle samples in helium atmosphere.

Experimental investigation and mathematical modelling of wood combustion in a moving grate boiler

International Nuclear Information System (INIS)

Zhang, Xiaohui; Chen, Qun; Sharifi, Vida; Swithenbank, Jim; Bradford, Richard

2010-01-01

The use of biomass to generate energy offers significant environmental advantages for the reduction in emissions of greenhouse gases. The main objective of this study was to investigate the performance of a small scale biomass heating plant: i.e. combustion characteristics and emissions. An extensive series of experimental tests was carried out at a small scale residential biomass heating plant i.e. wood chip fired boiler. The concentrations of CO, NO x , particulate matter in the flue gas were measured. In addition, mathematical modelling work using FLIC and FLUENT codes was carried out in order to simulate the overall performance of the wood fired heating system. Results showed that pollutant emissions from the boiler were within the relative emission limits. Mass concentration of CO emission was 550-1600 mg/m 3 (10% O 2 ). NO x concentration in the flue gas from the wood chips combustion varied slightly between 28 and 60 ppmv. Mass concentration of PM 10 in the flue gas was 205 mg/m 3 (10% O 2 ) The modelling results showed that most of the fuel was burnt inside the furnace and little CO was released from the system due to the high flue gas temperature in the furnace. The injection of the secondary air provided adequate mixing and favourable combustion conditions in the over-bed chamber in the wood chips fired boiler. This study has shown that the use of wood heating system result in much lower CO 2 emissions than from a fossil fuel e.g. coal fired heating system. (author)

Wood pellets in a power plant - mixed combustion of coal and wood pellets

International Nuclear Information System (INIS)

Nupponen, M.

2001-01-01

The author reviews in his presentation the development of Turku Energia, the organization of the company, the key figures of the company in 2000, as well as the purchase of energy in 2000. He also presents the purchase of basic heat load, the energy production plants of the company, the sales of heat in 2000, the emissions of the plants, and the fuel consumption of the plants in 2000. The operating experiences of the plants are also presented. The experiences gained in Turku Energia on mixed combustion of coal and wood pellets show that the mixing ratios, used at the plants, have no effect on the burning properties of the boiler, and the use of wood pellets with coal reduce the SO 2 and NO x emissions slightly. Simultaneously the CO 2 share of the wood pellets is removed from the emissions calculations. Several positive effects were observed, including the disappearance of the coal smell of the bunker, positive publicity of the utilization of wood pellets, and the subsidies for utilization of indigenous fuels in power generation. The problems seen include the tendency of wood pellets to arc the silos, especially when the pellets include high quantities of dust, and the loading of the trucks and the pneumatic unloading of the trucks break the pellets. Additionally the wood pellets bounce on the conveyor so they drop easily from the conveyor, the screw conveyors designed for conveying grain are too weak and they get stuck easily, and static electricity is easily generated in the plastic pipe used as the discharge pipe for wood pellet (sparkling tendency). This disadvantage has been overcome by using metal net and grounding

Elemental analysis of ash residue from combustion of CCA treated wood waste before and after electrodialytic extraction

DEFF Research Database (Denmark)

Pedersen, Anne Juul; Ottosen, Lisbeth M.

2006-01-01

Element distribution in a combined fly ash and bottom ash from combustion of copper chromate arsenate (CCA) treated wood waste was investigated by scanning electron microscopy (SEM/EDX) before and after electrodialytic extraction. The untreated ash contained various particles, including pieces...... of incompletely combusted wood rich in Cr and Ca, and irregular particles rich in Si, Al and K. Cr was also found incorporated in silica-based matrix particles. As was associated with Ca in porous (char) particles, indicating that Ca-arsenates had been formed during combustion. Cu was associated with Cr...... in the incompletely combusted wood pieces and was also found in almost pure form in a surface layer of some matrix particles – indicating surface condensation of volatile Cu species. In treated ash, Ca and As were no longer found together, indicating that Ca-arsenates had been dissolved due to the electrodialytic...

Contribution of Fossil Fuels and Wood Combustion to Carcinogenic PAHs in the Ambient Atmosphere of a Tropical Megacity

Science.gov (United States)

Jyethi, D. S.; Khillare, P. S.; Sarkar, S.

2015-12-01

Weekly particulate matter sampling was carried out at a peri-urban site located in megacity Delhi, India for 1 year (2009-2010) and the annual mean PM10 level was found to be ˜9 times the World Health Organization limit. Seasonal variation of PAHs (range 37.2-74.0 ng m-3) was significant with winter values being 72% and 68% higher than summer and monsoon respectively. Principal component analysis coupled with multiple linear regression identified diesel, natural gas and lubricating oil combustion (49.5%), wood combustion (25.4%), gasoline (15.5%) and coal combustion (9.6%) sources for the observed PAHs. Heavy traffic on the national highway and arterial roads and domestic emissions from suburban households in the vicinity of the site appeared to have significantly affected its air quality. A substantial portion (˜55%) of the aerosol PAH load was comprised of carcinogenic species, which yielded a considerably high lifetime inhalation cancer risk estimate (8.7E-04). If considered as a conservative lower-bound estimate, this risk translates into ˜211 excess cancer cases for lifetime inhalation exposure to the observed PAH concentrations in Delhi.

The influence of design and fuel parameters on the particle emissions from wood pellets combustion. Final report

Energy Technology Data Exchange (ETDEWEB)

Wiinikka, Henrik; Gebart, Rikard [Energy Technology Centre, Piteaa (Sweden)

2005-02-01

Combustion of solid biomass under fixed bed conditions is a common technique to generate heat and power in both small and large scale grate furnaces (domestic boilers, stoves, district heating plants). Unfortunately, combustion of biomass will generate particle emissions containing both large fly ash particles and fine particles that consist of fly ash and soot. The large fly ash particles have been produced from fusion of non-volatile ash-forming species in burning char particle. The inorganic fine particles have been produced from nucleation of volatilised ash elements (K, Na, S, Cl and Zn). If the combustion is incomplete, soot particles are also produced from secondary reaction of tar. The particles in the fine fraction grows by coagulation and coalescence to a particle diameter around 0.1 pm. Since the smallest particles are very hard to collect in ordinary cleaning devices they contribute to the ambient air pollution. Furthermore, fine airborne particles have been correlated to adverse effects on the human health. It is therefore essential to minimize particle formation from the combustion process and thereby reduce the emissions of particulates to the ambient air. The aim with this project is to study particle emissions from small scale combustion of wood pellets and to investigate the impact of different operating, construction and fuel parameters on the amount and characteristic of the combustion generated particles. To address these issues, experiments were carried out in a 10 kW updraft fired wood pellets reactor that has been custom designed for systematic investigations of particle emissions. In the flue gas stack, particle emissions were sampled on a filter. The particle mass and number size distributions were analysed by a low pressure cascade impactor and a SMPS (Scanning Electron Mobility Particle Sizer). The results showed that the temperature and the flow pattern in the combustion zone affect the particle emissions. Increasing combustion

Long-term leaching of nutrients and contaminants from wood combustion ashes

DEFF Research Database (Denmark)

Maresca, Alberto; Hyks, J.; Astrup, Thomas Fruergaard

2018-01-01

With increasing amounts of woody biomass being combusted for energy purposes worldwide, more wood ash is being generated and needs management. As an alternative to landfilling, residues may be utilised for liming and fertilising purposes on forest soils. Comprehensive evaluations of long-term lea......With increasing amounts of woody biomass being combusted for energy purposes worldwide, more wood ash is being generated and needs management. As an alternative to landfilling, residues may be utilised for liming and fertilising purposes on forest soils. Comprehensive evaluations of long......-term leaching from these residues are needed in order to assess potential environmental impacts associated with their utilisation. Two Danish wood ash samples, one fly ash and one mixed ash (a combination of fly ash and bottom ash), were evaluated in long-term percolation column tests (up to L/S ∼2000 L....../kg), in order to quantify the release of major, minor and trace metal(loid)s. While columns of three different lengths were used, the leaching of individual elements could be described as a function of the L/S ratio – irrespective of the column length. At L/S 1000 L/kg, the cumulative releases of K, S, Na, Ca...

Acute wood or coal exposure with carbon monoxide intoxication induces sister chromatid exchange

Energy Technology Data Exchange (ETDEWEB)

Ozturk, S.; Vatansever, S.; Cefle, K.; Palanduz, S.; Guler, K.; Erten, N.; Erk, O.; Karan, M.A.; Tascioglu, C. [University of Istanbul, Istanbul (Turkey). Istanbul Faculty of Medicine

2002-07-01

The object of this study was to investigate the genotoxic effect of acute overexposure to combustion products originating from coal or wood stoves in patients presenting with acute carbon monoxide intoxication. The authors analyzed the frequency of sister chromatid exchange and the carboxyhemoglobin concentration in 20 consecutive patients without a history of smoking or drug use who had been treated in the Emergency Care Unit of Istanbul Medical Faculty due to acute carbon monoxide intoxication. All of these cases were domestic accidents due to dysfunctioning coal or wood stoves. The results were compared with a control group of 20 nonsmoking, nondrug-using healthy individuals matched for age, sex, and absence of other chemical exposure. It was concluded that acute exposure to combustion products of wood or coal is genotoxic to DNA. Potential causes of genotoxicity include known mutagenic compounds present in coal or wood smoke and ash, oxygen radicals formed during combustion, as well as hypoxic and reperfusion injury mechanisms initiated by carbon monoxide intoxication.

Co-combustion of wood biomass in coal power plants, a contribution to energy turnaround and climate protection?; Die Mitverbrennung holzartiger Biomasse in Kohlekraftwerken. Ein Beitrag zur Energiewende und zum Klimaschutz?

Energy Technology Data Exchange (ETDEWEB)

Vogel, Claudia; Herr, Michael; Edel, Matthias; Seidl, Hannes

2011-08-15

Co-combustion of wood biomass in coal power plants is feasible at short notice and can is a low-cost option for climate protection. While other EU states have already provided funding mechanism, Germany has not followed this lead so far. Domestic wood resources are limited and unevenly distributed among the German regions, so that wood materials will have to be imported. During the past few years, the basic requirements for imports of wood were provided with the initiation of a global pellets market. Sustainability criteria for wood consumption were defined, and international certification systems were developed. The sustainability criteria should be extended to cover also wood-like materials and other biomass for power generation. The German EEG (Renewables Act) is a first step in this direction. Further, investments must be made in logistics capacities. The available logistics of coal power plants can be used with some minor modifications. In all, successful and sustainable international biomass markets may soon be available.

Atmospheric emission of mercury due to combustion of steam coal and domestic coal in China

Science.gov (United States)

Wang, Shaobin; Luo, Kunli

2017-08-01

To study the mercury emission due to the combustion of steam coal and domestic coal in China, we analyzed the mercury contents of coal, fly ash, bottom ash and sluicing water in thermal power plants, steam boilers as well as domestic coal-stoves, in Shaanxi, Shanxi, Shandong and Yunnan Provinces. This study conduct an estimate of the Hg emission rates from steam coal and domestic coal combustion based on the method of mass distribution ratio of fly ash and bottom ash. The results show that the Hg emission rate of coal combustion in thermal power plants is about 50.21% (electrostatic precipitators + wet flue gas desulfurization), and that in heating boilers is about 67.23%, and 92.28% in industrial boilers without flue gas desulphurisation equipment. Furthermore, Hg emission rate is 83.61% due to domestic coal combustion in coal-stoves. The Hg emission amount into the atmosphere from power and heat generation, industrial boilers, domestic coal-stoves and spontaneous combustion of coal gangue is roughly estimated to be 133 ± 4, 100 ± 17, 11 ± 0.1 and 47 ± 26 tons in China in 2014, respectively, and the total Hg emission amount from this paper is estimated at 292 tons. The trends of Hg emission in China from 1991 to 2014 show an accelerating growth after 2002. The proportion of mercury emission due to thermal power, heating generation and industrial energy utilization continuously increased. The atmospheric emission of mercury due to combustion of steam coal, domestic coal and coal gangue accounts nearly 50% in total anthropogenic Hg emissions in China, indicating one of the largest sources of Hg emission in China which should draw more public and scientific attention in the future.

Corrosivity of hot flue gases in the fluidized bed combustion of recovered waste wood

Energy Technology Data Exchange (ETDEWEB)

Enestam, S.

2011-07-01

In recent years, recovered waste wood has become a fuel of interest due to its green energy benefits and low price compared to virgin wood-based fuels. However, waste wood is often contaminated with paint, plastic, and metal components, producing concentrations of heavy metals such as zinc and lead, chlorine, sodium, and sometimes sulphur that are elevated relative to those in virgin wood. In several cases, boilers burning waste wood have experienced increased fouling and corrosion of furnace walls, superheaters, and economizers, problems associated with chlorine, zinc, lead, and alkali metals in the deposits. The location of the deposits and the corrosion as well as the composition of the deposits vary with the fuel composition, boiler design, combustion parameters, flue gas temperature, and material temperature. Experience gained from the operation of biofuel and waste boilers shows that corrosion damage can be reduced, or even avoided, by the selection of optimum materials or for heat exchanger surfaces, by the use of fuel mixtures or additives that decrease the corrosivity of the combustion environment, by the placement of superheaters in a less corrosive environment, and by adjusting the steam parameters. Finding the right solutions for boilers burning RWW requires a thorough understanding of the whole process, including the fuel fed into the boiler, the combustion atmosphere, the corrosivity of the flue gas and the deposits, and the corrosion resistance of different boiler materials under the prevailing conditions. The objective of this work was to shed more light on the combustion environment in bubbling fluidized bed boilers burning RWW and thus increase knowledge about the corrosivity of zinc- and lead-rich deposits formed during the combustion of RWW, with the final goal of developing a corrosion prediction tool for use in the design of boilers for RWW combustion. With such a tool, it would be possible to optimize boiler design and material selection with

Impact of wood combustion on particle levels in a residential area in Denmark

DEFF Research Database (Denmark)

Glasius, M.; Ketzel, M.; Wåhlin, P.

2006-01-01

The influence of residential wood-combustion on local air quality was studied during two periods in 2002 and 2003/04 in a small rural town with widespread use of wood combustion for heating. During one 6-week winter period, particle levels (PM2.5) in the residential area were about 4 μg m-3 higher...... than at a nearby background site. This was comparable to the local traffic contribution observed at a busy street (about 70,000 vehicles per day) in the city of Copenhagen. The diurnal variation in the residential area showed increased particle levels (PM2.5) in the evening and night as expected from...... local heating sources. Particle size distributions showed highest volume concentrations of particles with diameters of 400-500 nm, and the diurnal variation of particle volume was similar to PM2.5. The particle measurements were supported by measurements of combustion gases in both the residential area...

Volatiles and char combustion rates of demineralised lignite and wood blends

International Nuclear Information System (INIS)

Yilgin, Melek; Pehlivan, Dursun

2009-01-01

Today, much interest is given to the utilisation of materials of plant origin as substitutions of fossil fuels in meeting energy needs to reduce the level of atmospheric pollutant emissions and global warming threat, and emphasis has been placed on the co-combustion of coal and biomass. In this study, volatiles and char combustion behaviour of the fuel pellets composed from demineralised lignite and poplar wood sawdust, were investigated in a cylindrical wire mesh basket placed in a preheated tube furnace. The results have shown that ignition times of the pellets decreased with the burning temperature and shortened further due to demineralisation of lignite. Volatiles combustion rates of the samples did not correlate well with combustion times. However, they can be correlated with their respective proximate volatile matter contents. Char burnout times decreased with increasing combustion rates and correlated well with the respective proximate fixed carbon contents of the samples. Deviations were more considerable in the case of rate data. (author)

Analytical electron microscopy of combustion particles: a comparison of vehicle exhaust and residential wood smoke

International Nuclear Information System (INIS)

Kocbach, A.; Johansen, B.V.; Schwarze, P.E.; Namork, E.

2005-01-01

Particulate matter has been associated with a number of adverse health effects. Since combustion particles from vehicle exhaust and wood smoke are common constituents of ambient air, the morphology and elemental composition of particles from these two sources were analysed and compared using single particle analysis. Ambient air particles were collected in locations dominated by vehicle exhaust or residential wood smoke. To verify the source contributions to the ambient air samples, particles were collected directly from the combustion sources. All particulate samples were analysed on carbon extraction replica by transmission electron microscopy (TEM) and X-ray microanalysis (XRMA). The particles were classified into four groups based on morphology and elemental composition. Carbon aggregates were the only particles identified to originate from combustion sources and accounted for more than 88% of the particle numbers in the ambient air samples from both sources. The carbon aggregates were therefore further analysed with respect to morphology and elemental composition on germanium extraction replica. Carbon aggregates from vehicle exhaust were characterised by higher levels of Si and Ca compared to wood smoke aggregates that contained higher levels of K. The S content in aggregates from both sources was probably caused by interaction with gases in the air. Furthermore, the diameters of primary particles from vehicle exhaust were significantly smaller (27±7 nm) than the diameters for wood smoke (38±11 nm). The observed differences in elemental profiles and primary particle diameters for vehicle exhaust and wood smoke may influence the health effects caused by these particles

Kinetics of pyrolysis and combustion of spherical wood particles in a fluidized bed

International Nuclear Information System (INIS)

Mazziotti di Celso, Giuseppe; Rapagnà, Sergio; Prisciandaro, Marina; Zanoelo, Everton Fernando

2014-01-01

Highlights: • H 2 , CO 2 , CO and CH 4 released during wood pyrolysis were experimentally monitored. • CO 2 formed by burning the residual tar/char mixture was experimentally determined. • The kinetics of species production was reproduced with two simplified models. • The increase of the bed reactor temperature statistically enhanced the gas yield. • The pyrolysis time is statistically reduced by decreasing the particle size. - Abstract: The kinetics of wood pyrolysis and combustion of residual fuel at different particle diameters and temperatures was investigated. A known mass of wooden spheres was fed at the top of a fluidized bed reactor filled with olivine particles and fluidized with nitrogen. The concentration of H 2 , CO 2 , CO and CH 4 was on-line monitored with gas analyzers. An irreversible first order reaction was applied to describe the biomass pyrolysis. The rate constant was dependent on the average temperature of wood particle, obtained by solving the transient one-dimensional problem of heat conduction in a sphere. The rate for an irreversible second order reaction between the residual fuel and oxygen at the fluid–solid interface, which takes a finite resistance to mass transfer into account, was adopted to describe the combustion. The semi-empirical kinetic models for pyrolysis and combustion were able to describe, with certain limitations inherent to model simplifications, the experimental transient results of molar flow rates of major released species. A statistical model based on the results of the factorial design of experiments (3 2 ) confirmed a statistical significant effect of temperature and wood particle diameter on the gas yield and time of pyrolysis, respectively

The effect of control parameters to the quality of small-scale wood pellet combustion

Energy Technology Data Exchange (ETDEWEB)

Ruusunen, M. (Oulu Univ. (Finland). Contol Engineering Lab.), Email: mika.ruusunen@oulu.fi; Korpela, T.; Bjoerkqvist, T. (Tampere Univ. of Technology (Finland). Dept. of Automation Science and Engineering), Email: timo.korpela@tut.fi, Email: tomas.bjorqvist@tut.fi

2009-07-01

The target is to clear out control variables and requirements for clean small-scale wood pellet combustion (<100 kW{sub th}). Experimental runs were carried out in the form of design of experiments (DOE) with two commercial 15 kW pellet burners, namely a horizontal gas-burner and a conventional horizontal burner in a 20 kW commercial pellet boiler. Analysed variables were fuel power, draught, air flows, and fuel feed period, and research variables were CO, O{sub 2} and efficiency. The target was to identify and characterise separately the magnitude and direction of the effect of each factor. After process identification and variable optimisation, the results show strong influence of the studied control parameters on the efficiency and the emissions. The effects and interactions between different process variables were rather similar with both burners. The major effects for CO levels were fuel feed and additionally draught affected in case of wood gas combustion. Additionally, the effects on combustion efficiency is described by draught, air feed and fuel feed period. Furthermore, the fuel feed period affected the excess air level in case of direct combustion principle. It was noticed, however, that the combustion properties and optimal parameter values vary significantly between the two cases. (orig.)

Toxic emissions during co-combustion of biomass-waste wood-lignite blends in an industrial boiler.

Science.gov (United States)

Samaras, P; Skodras, G; Sakellaropoulos, G P; Blumenstock, M; Schramm, K W; Kettrup, A

2001-01-01

The objectives of this work were to study the PCDD/F emissions during the co-combustion of waste wood/coal co-combustion in an industrial boiler and to determine the relation of the toxic emissions to the fuel properties. Co-combustion experiments were performed in a 13.8 MWthermal industrial moving grate combustor. The fuels which were examined in this study included Greek lignite, natural uncontaminated wood, power poles and medium density fibers (MDFs) which were by-products of the plant production process. Fuel blends were prepared by mixing single components in various concentrations. PCDD/F emissions were collected during experimental runs and were analyzed according to standard methods. Low PCDD/F emissions were obtained during the co-combustion tests, lower than the limit value of 0.1 ng TEQ/Nm3. The lowest values were observed during the combustion of fuel blends containing MDF, possibly due to the inhibitory action of some of the N-containing MDF ingredients, such as urea. No direct correlation was found between the PCDD/F and the copper emissions, while examination of the PCDD/F homologue patterns revealed the predominance of the lower chlorinated isomers over the higher ones.

Chemical characterzation of fine particle emissions from the fireplace combustion of woods grown in the Southern United States.

Science.gov (United States)

Fine, Philip M; Cass, Glen R; Simoneit, Bernd R T

2002-04-01

The fireplace combustion of wood is a significant and largely unregulated source of fine particle pollution in the United States. Source apportionment techniques that use particulate organic compounds as tracers have been successful in determining the contribution of wood smoke to ambient fine particle levels in specific areas in California. To apply these techniques to the rest of the United States, the differences in emissions profiles between different wood smoke sources and fuel types should be resolved. To this end, a series of fireplace source tests was conducted on six fuel wood species found in the Southern United States to determine fine particulate emission factors for total mass, ionic and elemental species, elemental and organic carbon, and over 250 individual organic compounds. The wood species tested, chosen for their high abundance and availability in the Southern U.S. region, were yellow poplar, white ash, sweetgum, mockernut hickory, loblolly pine, and slash pine. The differences in the emissions of compounds such as substituted phenols and resin acids help to distinguish between the smoke from hardwood and softwood combustion. Levoglucosan, a cellulose pyrolysis product which may serve as a tracer for wood smoke in general, was quantified in the emissions from all the wood species burned. The furofuran lignan, yangambin, which was emitted in significant quantities from yellow poplar combustion and not detected in any of the other North American wood smokes, is a potential species-specific molecular tracer which may be useful in qualitatively identifying particulate emissions from a specific geographical area where yellow poplar is being burned.

Regulations and standardization relative to the biomass combustion

International Nuclear Information System (INIS)

Autret, E.

2009-01-01

It does not exist regulations on pollutants emissions on domestic wood burning furnaces, however, these appliances are submitted to the European and french standardization concerning the safety rules, the use rules and the tests methods. Since 2007, these wood burning appliances on the market must have the European Community label. The green flame label was elaborated by the environment and energy control Agency (A.D.E.M.E.), and manufacturers of domestic appliances to promote the use of competitive wood burning appliances. concerning the collective and industrial heating, the installations of more 2 MW are framed by different categories of the installations classified for environment protection (I.C.P.E.) regulation according their fuel and power. The combustion installations of less than 2 MW are a particular case, they are framed by a sanitary department regulation and are controlled by the department directions of sanitary and social affairs. the limit values of emissions are summarized in tables. (N.C.)

Wood Combustion Behaviour in a Fixed Bed Combustor

Science.gov (United States)

Tokit, Ernie Mat; Aziz, Azhar Abdul; Ghazali, Normah Mohd

2010-06-01

Waste wood is used as feedstock for Universiti Teknologi Malaysia's newly-developed two-stage incinerator system. The research goals are to optimize the operation of the thermal system to the primary chamber, to improve its combustion efficiency and to minimize its pollutants formation. The combustion process is evaluated with the variation of fuel's moisture content. For optimum operating condition, where the gasification efficiency is 95.53%, the moisture content of the fuel is best set at 17%; giving outlet operating temperature of 550°C and exhaust gas concentrations with 1213 ppm of CO, 6% of CO2 and 14% of O2 respectively. In line to the experimental work, a computational fluid dynamics software, Fluent is used to simulate the performance of the primary chamber. Here the predicted optimum gasification efficiency stands at 95.49% with CO, CO2 and O2 concentrations as 1301 ppm, 6.5% and 13.5% respectively.

Survey of usage patterns for domestic stoves/fireplaces. Prestudy

International Nuclear Information System (INIS)

Cooper, David; Joeborn, Inger; Sjoedin, Aake; Munkhammar, Inger; Gustavsson, Lennart

2005-02-01

We have investigated the use of domestic wood burning for wood stoves and open fireplaces. The results from a closer examination of existing national energy statistics for residential heating has enabled a division of the average consumption of firewood for each house by the category 'fireplace for open fire' and 'tiled stove/heating stove/fireplace for wood'. The estimation of emissions can therefore be improved by differentiating emission factors for different wood stoves and open fireplaces. Today, only one emission factor is used. An insight into general firing procedures, wood storage routines etc. was investigated using a questionnaire for the Teleborg area of the city Vaexjoe. The results of this study provide a foundation for further work, which will subsequently enable improvements for emission inventories on small-scale biomass combustion from household appliances

Volatile organic compound analysis in wood combustion and meat cooking emissions

International Nuclear Information System (INIS)

Zielinska, B.; McDonald, J.

1999-01-01

Residential wood combustion and meat cooking emissions were each analyzed for volatile organic compounds (VOC). Emissions were diluted 60--100 times, cooled to ambient temperature, and allowed 80 seconds for condensation prior to collection with the aid of a DRI-constructed dilution stack sampler. Fireplace and wood-stove emissions testing was conducted at the DRI facilities. Wood type, wood moisture, burn rate, and fuel load were varied for different experiments. Meat emissions testing was conducted at the CE-CERT stationary emissions lab, University of California, Riverside. Meat type, fat content, and cooking appliance were changed in different tests. VOCs were collected using stainless-steel 6 L canisters and Tenax cartridges, whereas for carbonyl compound collection 2,4-dinitrophenylhydrazine (DNPH)-impregnated C 18 SepPack cartridges were used. Analysis of VOC collected with canisters and Tenax cartridges was conducted by Gas Chromatography/Mass Spectrometry (GC/MS) and by GC/FID/ECD (flame ionization detection/electron capture detection). DNPH-impregnated cartridges were analyzed for fourteen C 1 --C 7 carbonyl compounds, using the HPLC method. The results of these measurements are discussed

Characterisation of PM 10 emissions from woodstove combustion of common woods grown in Portugal

Science.gov (United States)

Gonçalves, Cátia; Alves, Célia; Evtyugina, Margarita; Mirante, Fátima; Pio, Casimiro; Caseiro, Alexandre; Schmidl, Christoph; Bauer, Heidi; Carvalho, Fernando

2010-11-01

A series of source tests was performed to evaluate the chemical composition of particle emissions from the woodstove combustion of four prevalent Portuguese species of woods: Pinus pinaster (maritime pine), Eucalyptus globulus (eucalyptus), Quercus suber (cork oak) and Acacia longifolia (golden wattle). Analyses included water-soluble ions, metals, radionuclides, organic and elemental carbon (OC and EC), humic-like substances (HULIS), cellulose and approximately l80 organic compounds. Particle (PM 10) emission factors from eucalyptus and oak were higher than those from pine and acacia. The carbonaceous matter represented 44-63% of the particulate mass emitted during the combustion process, regardless of species burned. The major organic components of smoke particles, for all the wood species studied, with the exception of the golden wattle (0.07-1.9% w/w), were anhydrosugars (0.2-17% w/w). Conflicting with what was expected, only small amounts of cellulose were found in wood smoke. As for HULIS, average particle mass concentrations ranged from 1.5% to 3.0%. The golden wattle wood smoke presented much higher concentrations of ions and metal species than the emissions from the other wood types. The results of the analysis of radionuclides revealed that the 226Ra was the naturally occurring radionuclide more enriched in PM 10. The chromatographically resolved organics included n-alkanes, n-alkenes, PAH, oxygenated PAH, n-alkanals, ketones, n-alkanols, terpenoids, triterpenoids, phenolic compounds, phytosterols, alcohols, n-alkanoic acids, n-di-acids, unsaturated acids and alkyl ester acids.

Wood pellets : a worldwide fuel commodity

International Nuclear Information System (INIS)

Melin, S.

2005-01-01

Aspects of the wood pellet industry were discussed in this PowerPoint presentation. Details of wood pellets specifications were presented, and the wood pellet manufacturing process was outlined. An overview of research and development activities for wood pellets was presented, and issues concerning quality control were discussed. A chart of the effective calorific value of various fuels was provided. Data for wood pellet mill production in Canada, the United States and the European Union were provided, and various markets for Canadian wood pellets were evaluated. Residential sales as well as Canadian overseas exports were reviewed. Production revenues for British Columbia and Alberta were provided. Wood pellet heat and electricity production were discussed with reference to prefabricated boilers, stoves and fireplaces. Consumption rates, greenhouse gas (GHG) emissions, and fuel ratios for wood pellets and fossil fuels were compared. Price regulating policies for electricity and fossil fuels have prevented the domestic expansion of the wood pellet industry. There are currently no incentives for advanced biomass combustion to enter British Columbia markets, and this has led to the export of wood pellets. It was concluded that climate change mitigation policies will be a driving force behind market expansion for wood pellets. tabs., figs

Chemical source characterization of residential wood combustion emissions in Denver, Colorado; Bakersfield, California; and Mammoth Lakes, California

International Nuclear Information System (INIS)

Houck, J.E.; Goulet, J.M.; Chow, J.C.; Watson, J.G.

1989-01-01

The chemical composition of residential wood combustion particulate emissions was determined for fireplaces and woodstoves. Burn rates, burn patterns, wood burning appliances, and cordwood types characteristic of Denver, Colorado; Bakersfield, California; and Mammoth Lakes, California, were used during sample collection. Samples were collected using a dilution/cooling system to ensure that condensible compounds were captured. Analyses for 44 chemical species were conducted. Source profiles for use in chemical mass balance (CMB) modeling were calculated from the analytical data. The principal chemical species comprising the profiles were organic compounds and elemental carbon. The minor chemical species were sulfur, chlorine, potassium, sodium, calcium, zinc, nitrate, and ammonium. Virtually all potassium was in a water-soluble form, and sulfur emissions between fireplaces and woodstoves were noted. Area-specific source profiles for fireplaces, woodstoves, and overall residential wood combustion are presented

Cytotoxic and genotoxic responses of human lung cells to combustion smoke particles of Miscanthus straw, softwood and beech wood chips

Science.gov (United States)

Arif, Ali Talib; Maschowski, Christoph; Garra, Patxi; Garcia-Käufer, Manuel; Petithory, Tatiana; Trouvé, Gwenaëlle; Dieterlen, Alain; Mersch-Sundermann, Volker; Khanaqa, Polla; Nazarenko, Irina; Gminski, Richard; Gieré, Reto

2017-08-01

Inhalation of particulate matter (PM) from residential biomass combustion is epidemiologically associated with cardiovascular and pulmonary diseases. This study investigates PM0.4-1 emissions from combustion of commercial Miscanthus straw (MS), softwood chips (SWC) and beech wood chips (BWC) in a domestic-scale boiler (40 kW). The PM0.4-1 emitted during combustion of the MS, SWC and BWC were characterized by ICP-MS/OES, XRD, SEM, TEM, and DLS. Cytotoxicity and genotoxicity in human alveolar epithelial A549 and human bronchial epithelial BEAS-2B cells were assessed by the WST-1 assay and the DNA-Alkaline Unwinding Assay (DAUA). PM0.4-1 uptake/translocation in cells was investigated with a new method developed using a confocal reflection microscope. SWC and BWC had a inherently higher residual water content than MS. The PM0.4-1 emitted during combustion of SWC and BWC exhibited higher levels of Polycyclic Aromatic Hydrocarbons (PAHs), a greater variety of mineral species and a higher heavy metal content than PM0.4-1 from MS combustion. Exposure to PM0.4-1 from combustion of SWC and BWC induced cytotoxic and genotoxic effects in human alveolar and bronchial cells, whereby the strongest effect was observed for BWC and was comparable to that caused by diesel PM (SRM 2 975), In contrast, PM0.4-1 from MS combustion did not induce cellular responses in the studied lung cells. A high PAH content in PM emissions seems to be a reliable chemical marker of both combustion efficiency and particle toxicity. Residual biomass water content strongly affects particulate emissions and their toxic potential. Therefore, to minimize the harmful effects of fine PM on health, improvement of combustion efficiency (aiming to reduce the presence of incomplete combustion products bound to PM) and application of fly ash capture technology, as well as use of novel biomass fuels like Miscanthus straw is recommended.

Inventory of usage pattern for wood burning appliances

International Nuclear Information System (INIS)

Cooper, David; Joeborn, Inger; Sjoedin, Aake; Munkhammar, Inger; Gustavsson, Lennart

2005-02-01

The Swedish Environmental Research Institute (IVL) in co-operation with the Swedish National Testing and Research Institute (SP) and Statistics Sweden (SCB) have investigated the use of domestic wood burning for wood stoves and open fireplaces. The results from a closer examination of existing national energy statistics for residential heating has enabled a division of the average consumption of firewood for each house by the category 'fireplace for open fire' and 'tiled stove/heating stove/fireplace for wood'. The estimation of emissions can therefore be improved by differentiating emission factors for different wood stoves and open fireplaces. Today, only one emission factor is used. An insight into general firing procedures, wood storage routines etc. was investigated using a questionnaire for the Teleborg area of the city Vaexjoe. The results of this study provide a foundation for further work, which will subsequently enable improvements for emission inventories on small-scale biomass combustion from household appliances

Chemical characterization and stable carbon isotopic composition of particulate Polycyclic Aromatic Hydrocarbons issued from combustion of 10 Mediterranean woods

Directory of Open Access Journals (Sweden)

A. Guillon

2013-03-01

Full Text Available The objectives of this study were to characterize polycyclic aromatic hydrocarbons from particulate matter emitted during wood combustion and to determine, for the first time, the isotopic signature of PAHs from nine wood species and Moroccan coal from the Mediterranean Basin. In order to differentiate sources of particulate-PAHs, molecular and isotopic measurements of PAHs were performed on the set of wood samples for a large panel of compounds. Molecular profiles and diagnostic ratios were measured by gas chromatography/mass spectrometry (GC/MS and molecular isotopic compositions (δ13C of particulate-PAHs were determined by gas chromatography/combustion/isotope ratio mass spectrometry (GC/C/IRMS. Wood species present similar molecular profiles with benz(aanthracene and chrysene as dominant PAHs, whereas levels of concentrations range from 1.8 to 11.4 mg g−1 OC (sum of PAHs. Diagnostic ratios are consistent with reference ratios from literature but are not sufficient to differentiate the species of woods. Concerning isotopic methodology, PAH molecular isotopic compositions are specific for each species and contrary to molecular fingerprints, significant variations of δ13C are observed for the panel of PAHs. This work allows differentiating wood combustion (with δ13CPAH = −28.7 to −26.6‰ from others origins of particulate matter (like vehicular exhaust using isotopic measurements but also confirms the necessity to investigate source characterisation at the emission in order to help and complete source assessment models. These first results on woodburnings will be useful for the isotopic approach to source tracking.

Reactivity and burnout of wood fuels

DEFF Research Database (Denmark)

Dall'Ora, Michelangelo

This thesis deals with the combustion of wood in pulverised fuel power plants. In this type of boiler, the slowest step in the wood conversion process is char combustion, which is one of the factors that not only determine the degree of fuel burnout, but also affect the heat release profile...... of different aspects relevant to wood combustion, including wood structure and composition, wood pyrolysis, wood char properties and wood char oxidation. The full scale campaign, which is the subject of Chapter 3, included sampling of wood fuel before and after milling and sampling of gas and particles...... at the top of the combustion chamber. The collected samples and data are used to obtain an evaluation of the mills in operation at the power plant, the particle size distribution of the wood fuel, as well as the char conversion attained in the furnace. In Chapter 4 an experimental investigation...

Energy wood. Part 2b: Wood pellets and pellet space-heating systems

International Nuclear Information System (INIS)

Nussbaumer, T.

2002-01-01

The paper gives an overview on pellet utilization including all relevant process steps: Potential and properties of saw dust as raw material, pellet production with drying and pelletizing, standardization of wood pellets, storage and handling of pellets, combustion of wood pellets in stoves and boilers and applications for residential heating. In comparison to other wood fuels, wood pellets show several advantages: Low water content and high heating value, high energy density, and homogeneous properties thus enabling stationary combustion conditions. However, quality control is needed to ensure constant properties of the pellets and to avoid the utilization of contaminated raw materials for the pellet production. Typical data of efficiencies and emissions of pellet stoves and boilers are given and a life cycle analysis (LCA) of wood pellets in comparison to log wood and wood chips is described. The LCA shows that wood pellets are advantageous thanks to relatively low emissions. Hence, the utilization of wood pellet is proposed as a complementary technology to the combustion of wood chips and log wood. Finally, typical fuel cost of wood pellets in Switzerland are given and compared with light fuel oil. (author)

Report from the working group on combustion of domestic animal manure fractions; Rapport fra arbejdsgruppen om afbraending af fraktioner af husdyrgoedning

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-06-01

During the past few years there has been a considerable development of new technology for treatment of domestic animal manure. The development implies that environmental problems connected with storage and use of domestic animal manure for fertilization are reduced. Through several years experiences with utilization of domestic animal manure's energy potential in biogas plants have been compiled, and the technological basis for connecting slurry separation and biogas production is present. In order to promote this development, the agricultural sector has a growing desire to be able to dispose of parts from the separated slurry through combustion, hereby using the energy content to the energy production. However, there are a number of barriers that make combustion of domestic animal manure impossible. In order to uncover existing barriers for combustion of domestic animal manure fractions the Danish Minister of food appointed an inter ministerial committee on 30 March 2005. The committee should: 1. Describe the regulations within the ministerial areas that affect combustion of domestic animal manure, and also describe the regulations that act as barriers, 2. Describe binding international agreements, directives and regulations that affect combustion of domestic animal manure and which of these that act as barriers, 3. Evaluate the potential for regulation adjustments and other actions, that might further the development of sustainable energy production in which domestic animal manure is a part, 4. Evaluate socio-economic pros and cons in the light of environmental and climatic impacts, and 5. Describe estimated governmental financial consequences of potential adjustments of regulations and other actions. (BA)

Determination of Plant-Available Nutrients in Two Wood Ashes: the Influence of Combustion Conditions

Czech Academy of Sciences Publication Activity Database

Perná, Ivana; Ochecová, P.; Száková, J.; Hanzlíček, Tomáš; Tlustoš, P.

2016-01-01

Roč. 47, 13/14 (2016), 1664-1674 ISSN 0010-3624 R&D Projects: GA MZe QI102A207 Institutional support: RVO:67985891 Keywords : combustion condition * crystal phases * fertilizer * plant-available nutrients * wood ash Subject RIV: DM - Solid Waste and Recycling Impact factor: 0.589, year: 2016

Production of wood pellets. Influence of additives on production, quality, storage, combustion and life cycle analysis of wood pellets; Herstellung von Holzpellets. Einfluss von Presshilfsmitteln auf Produktion, Qualitaet, Lagerung, Verbrennung sowie Energie- und Oekobilanz von Holzpellets

Energy Technology Data Exchange (ETDEWEB)

Hasler, P.; Nussbaumer, T. [Verenum, Zuerich (Switzerland); Buerli, J. [Buerli Pellets, Willisau (Switzerland)

2001-07-01

This report for the Swiss Federal Office of Energy (SFOE) presents the results of a study concerning the influence of additives on the various factors related to the manufacture of wood pellets and their use. Results of tests concerning the production, storage and combustion of wood pellets with and without additives are presented. Process modifications are discussed. The report shows that for all investigated additives neither energy consumption nor pellet throughput was improved. The influence of additives on the mechanical strength of the pellets is discussed, as are the combustion characteristics of the pellets, which emit significantly lower levels of NO{sub x} and particulate matter than typical wood chips. The authors recommend the application of advanced control technology to ensure optimum combustion conditions. A life-cycle analysis is presented which shows that pellets are ecologically more favourable than wood chips. The ecological potential for improvement in the manufacturing process is discussed, including emission reductions and heat recovery.

LCA of domestic and centralized biomass combustion: The case of Lombardy (Italy)

International Nuclear Information System (INIS)

Caserini, S.; Livio, S.; Giugliano, M.; Grosso, M.; Rigamonti, L.

2010-01-01

This paper analyzes and compares the environmental impacts of biomass combustion in small appliances such as domestic open fireplaces and stoves, and in two types of centralized combined heat and power plants, feeding district heating networks. The analysis is carried out following a Life Cycle Assessment (LCA) approach. The expected savings of GHG (greenhouse gases) emissions due to the substitution of fossil fuels with biomass are quantified, as well as emissions of toxic pollutants and substances responsible for acidification and ozone formation. The LCA results show net savings of GHG emissions when using biomass instead of conventional fuels, varying from 0.08 to 1.08 t of CO 2 eq. per t of dry biomass in the different scenarios. Avoided GHG emissions thanks to biomass combustion in Lombardy are 1.32 Mt year -1 (1.5% of total regional GHG emissions). For the other impact categories, the use of biomass in district heating systems can again cause a consistent reduction of impacts, whereas biomass combustion in residential devices shows higher impacts than fossil fuels with a particular concern for PAH, VOC and particulate matter emissions. For example, in Lombardy, PM10 emissions from domestic devices are about 8100 t year -1 , corresponding to almost one third of the total particulate emissions in 2005. (author)

Devolatilization and Combustion of Tire Rubber and Pine Wood in a Pilot Scale Rotary Kiln

DEFF Research Database (Denmark)

Nielsen, Anders R.; Larsen, Morten B.; Glarborg, Peter

2012-01-01

Cement production is highly energy intensive and requires large quantities of fuels. For both economical and environmental reasons, there is an increasing tendency for utilization of alternative fuels in the cement industry, examples being tire derived fuels, waste wood, or different types...... of industrial waste. In this study, devolatilization and combustion of large particles of tire rubber and pine wood with equivalent diameters of 10 mm to 26 mm are investigated in a pilot scale rotary kiln able to simulate the process conditions present in the material inlet end of cement rotary kilns...

Air quality and residential wood combustion - application of the model system SIMAIRrwc for some Swedish municipalities; Luftkvalitet och smaaskalig biobraensleeldning. Tillaempningar av SIMAIRved foer naagra kommuner

Energy Technology Data Exchange (ETDEWEB)

Omstedt, Gunnar; Andersson, Stefan; Johansson, Christer; Loefgren, Bengt-Erik

2008-11-15

SIMAIRrwc is a Web based evaluation tool for meeting the EU directive on air pollution limits in residential areas using wood combustion. The background is a four-year research program (2001-2004) called Biomass Combustion Health and Environment. Some conclusions from this program were that emissions from small scale wood combustion can influence human health mainly due to high emitting old wood stoves during cold weather conditions and that the air quality in such areas can improve significantly if old wood stoves were replaced by modern wood boilers attached to a storage tank or with a pellet boiler. SIMAIRrwc is based on the same principles as SIMAIRroad, which is a Web based evaluation tool for road traffic i.e. coupled model system using different models on local, urban and regional geographical scales, best available emission data, but at the same time presented in a very simplified way. In this project SIMAIRrwc has been applied in five different Swedish municipalities. The aim has been to apply and improve the model in cooperation with the municipalities. The conclusions from the project are: Small scale wood combustions in residential areas are local problems which sometimes include only a few houses and/or wood-burners. Air quality problems related to the EU directive are mainly due to particles. Combinations of residential areas with wood combustion and emissions from nearby dense traffic roads might give rise to bad air quality. Actions require knowledge about individual equipment which needs information from the local chimney sweeps. The best way to identify problem areas is to use model calculations. If model calculations indicate risks of exceeding air quality limits, then new calculations should be made with improved input data taking into account for example information of district heating or other installations that can effect the emissions. Before actions are taken it may also be useful to make measurements. The measurement site can then be

Impact of Coal Fly Ash Addition on Combustion Aerosols (PM2.5) from Full-Scale Suspension-Firing of Pulverized Wood

DEFF Research Database (Denmark)

Damø, Anne Juul; Wu, Hao; Frandsen, Flemming

2014-01-01

The formation of combustion aerosols was studied in an 800 MWth suspension-fired power plant boiler, during combustion of pulverized wood pellets with and without addition of coal fly ash as alkali capture additive. The aerosol particles were sampled and characterized by a low-pressure cascade im...

Findings on pollutant formation in wood and chip board combustion. Erkenntnisse zur Schadstoffbildung bei der Verbrennung von Holz und Spanplatten

Energy Technology Data Exchange (ETDEWEB)

Marutzky, R.

1991-10-01

Combustion experiments were carried out using wood and several types of chip boards with binders on the basis of urea, melamine and phenol formaldehyde resins, polyureas, and PVC. The combustion process was observed, and the flue gas constituents in case of incomplete combustion were analyzed. The origins of the various organic and inorganic materials were discussed taking account of the results of pyrolysis experiments. (orig.).

In-Home Coal and Wood Use and Lung Cancer Risk: A Pooled Analysis of the International Lung Cancer Consortium

OpenAIRE

Hosgood, H. Dean; Boffetta, Paolo; Greenland, Sander; Lee, Yuan-Chin Amy; McLaughlin, John; Seow, Adeline; Duell, Eric J.; Andrew, Angeline S.; Zaridze, David; Szeszenia-Dabrowska, Neonila; Rudnai, Peter; Lissowska, Jolanta; Fabiánová, Eleonóra; Mates, Dana; Bencko, Vladimir

2010-01-01

Background Domestic fuel combustion from cooking and heating is an important public health issue because roughly 3 billion people are exposed worldwide. Recently, the International Agency for Research on Cancer classified indoor emissions from household coal combustion as a human carcinogen (group 1) and from biomass fuel (primarily wood) as a probable human carcinogen (group 2A). Objectives We pooled seven studies from the International Lung Cancer Consortium (5,105 cases and 6,535 controls)...

Mathematical modelling of the combustion of a single wood particle

Energy Technology Data Exchange (ETDEWEB)

Porteiro, J.; Miguez, J.L.; Granada, E.; Moran, J.C. [Departamento de Ingenieria Mecanica, Maquinas y Motores Termicos y Fluidos. Universidad de Vigo, Lagoas Marcosende 9 36200 Vigo (Spain)

2006-01-15

A mathematical model describing the thermal degradation of densified biomass particles is presented here. The model uses a novel discretisation scheme and combines intra-particle combustion processes with extra-particle transport processes, thereby including thermal and diffusional control mechanisms. The influence of structural changes on the physical-thermal properties of wood in its different stages is studied together with shrinkage of the particle during its degradation. The model is used to compare the predicted data with data on the mass loss dynamics and internal temperature of several particles from previous works and relevant literature, with good agreement. (author)

Particulate Matter 2.5 Exposure and Self-Reported Use of Wood Stoves and Other Indoor Combustion Sources in Urban Nonsmoking Homes in Norway.

Directory of Open Access Journals (Sweden)

Annah B Wyss

Full Text Available Few studies have examined particulate matter (PM exposure from self-reported use of wood stoves and other indoor combustion sources in urban settings in developed countries. We measured concentrations of indoor PM < 2.5 microns (PM2.5 for one week with the MicroPEM™ nephelometer in 36 households in the greater Oslo, Norway metropolitan area. We examined indoor PM2.5 levels in relation to use of wood stoves and other combustion sources during a 7 day monitoring period using mixed effects linear models with adjustment for ambient PM2.5 levels. Mean hourly indoor PM2.5 concentrations were higher (p = 0.04 for the 14 homes with wood stove use (15.6 μg/m3 than for the 22 homes without (12.6 μg/m3. Moreover, mean hourly PM2.5 was higher (p = 0.001 for use of wood stoves made before 1997 (6 homes, 20.2 μg/m3, when wood stove emission limits were instituted in Norway, compared to newer wood stoves (8 homes, 11.9 μg/m3 which had mean hourly values similar to control homes. Increased PM2.5 levels during diary-reported burning of candles was detected independently of concomitant wood stove use. These results suggest that self-reported use of wood stoves, particularly older stoves, and other combustion sources, such as candles, are associated with indoor PM2.5 measurements in an urban population from a high income country.

Wood burning

Energy Technology Data Exchange (ETDEWEB)

Winkelmann, H

1955-01-01

Discussed are the use of wood as a fuel, the technique of wood combustion and the operation of wood-burning stoves for cooking and heating. In addition, there is a section which reviews the use of wood stoves in various countries and lists manufacturers of stoves, central heating furnaces and in some cases sawdust burners.

Combustion Characteristics of Impregnated and Surface-treated Chestnut (Castanea sativa Mill. Wood Left Outdoors for One Year

Directory of Open Access Journals (Sweden)

Muhammed Said Fidan

2016-01-01

Full Text Available Treating wood with impregnating materials in order to improve resistance to burning is a commonly employed safety measure. In this study, chestnut (Castanea sativa Mill. wood samples were impregnated using either Tanalith-E or Wolmanit-CB according to ASTM-D 1413-76 and surface-treated using water-based or synthetic varnish according to ASTM-D 3023. These samples were used to investigate the combustion characteristics of samples left outdoors for one year as detailed in ASTM-E 160-50. The combustion temperatures of the samples left outdoors were similar upon impregnation with either Tanalith-E or Wolmanit-CB. However, the combustion temperature of the samples treated with synthetic varnish was lower than those that were treated with water-based varnish. The time to collapse and the total duration of combustion of the samples left outdoors were shorter for those impregnated with Wolmanit-CB. Weight loss of the samples left outdoors was higher for those that were impregnated with Tanalith-E and treated with water-based varnish. Gas analysis of the samples that were left outdoors indicated that the O2 content of flue gas from samples that were impregnated with Wolmanit-CB and treated with synthetic varnish was high and the CO content of flue gas from the same samples was low.

Residential wood combustion technology review: Volume 1. Final technical report, July 1997--July 1998

International Nuclear Information System (INIS)

Houck, J.E.; Tiegs, P.E.

1998-12-01

The report gives results of a review of the current state-of-the-art of residential wood combustion (RWC). The key environmental parameter of concern was the air emission of particles. The technological status of all major RWC categories--cordwood stoves, fireplaces, masonry heaters, pettel stoves, and wood-fired central heating furnaces--was reviewed. Advances in technology achieved since the mid-1980s were the primary focus. Key findings of the review included: (1) the new source performance standard (NSPS) certification procedure only qualitatively predicts the level of emissions from wood heaters under actual use in homes; (2) woodstove durability varies with model, and a method to assess the durability problem is controversial; (3) nationally, the overwhelming majority of RWC air emissions are from noncertified devices (primarily from older noncertified woodstoves); (4) new technology appliances and fuels can reduce emissions significantly; (5) the International Organization for Standardization and EPA NSPS test procedures are quite dissimilar, and data generated by the two procedures would not be comparable; and (6) the effect of wood moisture and wood type on particulate emission appears to be real but less than an order of magnitude

Residential wood combustion technology review: Volume 2 -- Appendices. Final report, July 1997--July 1998

International Nuclear Information System (INIS)

Houck, J.E.; Tiegs, P.E.

1998-12-01

The report gives results of a review of the current state-of-the-art of residential wood combustion (RWC). The key environmental parameter of concern was the air emission of particles. The technological status of all major RWC categories--cordwood stoves, fireplaces, masonry heaters, pettel stoves, and wood-fired central heating furnaces--was reviewed. Advances in technology achieved since the mid-1980s were the primary focus. Key findings of the review included: (1) the new source performance standard (NSPS) certification procedure only qualitatively predicts the level of emissions from wood heaters under actual use in homes; (2) woodstove durability varies with model, and a method to assess the durability problem is controversial; (3) nationally, the overwhelming majority of RWC air emissions are from noncertified devices (primarily from older noncertified woodstoves); (4) new technology appliances and fuels can reduce emissions significantly; (5) the International Organization for Standardization and EPA NSPS test procedures are quite dissimilar, and data generated by the two procedures would not be comparable; and (6) the effect of wood moisture and wood type on particulate emission appears to be real but less than an order of magnitude

Combined particle emission reduction and heat recovery from combustion exhaust-A novel approach for small wood-fired appliances

International Nuclear Information System (INIS)

Messerer, A.; Schmatloch, V.; Poeschl, U.; Niessner, R.

2007-01-01

Replacing fossil fuels by renewable sources of energy is one approach to address the problem of global warming due to anthropogenic emissions of greenhouse gases. Wood combustion can help to replace fuel oil or gas. It is advisable, however, to use modern technology for combustion and exhaust gas after-treatment in order to achieve best efficiency and avoid air quality problems due to high emission levels often related to small scale wood combustion. In this study, simultaneous combustion particle deposition and heat recovery from the exhaust of two commercially available wood-fired appliances has been investigated. The experiments were performed with a miniature pipe bundle heat exchanger operating in the exhaust gas lines of a fully automated pellet burner or a closed fireplace. The system has been characterised for a wide range of aerosol inlet temperatures (135-295 deg. C) and flow velocities (0.13-1.0ms -1 ), and particle deposition efficiencies up to 95% have been achieved. Deposition was dominated by thermophoresis and diffusion and increased with the average temperature difference and retention time in the heat exchanger. The aerosols from the two different appliances exhibited different deposition characteristics, which can be attributed to enhanced deposition of the nucleation mode particles generated in the closed fire place. The measured deposition efficiencies can be described by simple linear parameterisations derived from laboratory studies. The results of this study demonstrate the feasibility of thermophoretic particle removal from biomass burning flue gas and support the development of modified heat exchanger systems with enhanced capability for simultaneous heat recovery and particle deposition

Retene Emission from Residential Solid Fuels in China and Evaluation of Retene as a Unique Marker for Soft Wood Combustion

Science.gov (United States)

Shen, Guofeng; Tao, Shu; Wei, Siye; Zhang, Yanyan; Wang, Rong; Wang, Bin; Li, Wei; Shen, Huizhong; Huang, Ye; Yang, Yifeng; Wang, Wei; Wang, Xilong; Massey Simonich, Staci L.

2012-01-01

Retene (1-methyl-7-isopropylphenanthrene) is often used as a marker for softwood combustion and for polycyclic aromatic hydrocarbon (PAH) source apportionment. The emission factors of retene (EFRET) from 11 crop residues, 27 firewood and 5 coals were measured using traditional rural Chinese stoves. Retene was measured in combustion emissions from all of the residential fuels tested and EFRET varied significantly among the fuels due to the differences in fuel properties and combustion conditions. EFRET for pine (0.34±0.08 mg/kg) and larch (0.29±0.22 mg/kg) were significantly higher than those of other wood types, including fir and cypress (0.081±0.058 mg/kg). However, EFRET for crop residues varied from 0.048±0.008 to 0.37±0.14 mg/kg and were not significantly lower than those for softwood (0.074±0.026 to 0.34±0.08 mg/kg). The EFRET for coal were very high and ranged from 2.2±1.5 (anthracite briquette) to 187±113 mg/kg (raw bituminous chunk). EFRET was positively correlated with EFs of co-emitted particulate matter (EFPM) and phenanthrene (EFPHE) for crop residue and coal, but not for wood. In addition, the ratios of EFPHE/EFRET and EFPM/EFRET for coals were much lower than those for crop residues and wood. These data suggest that retene is not a unique PAH marker for softwood combustion and that coal combustion, in particular, should be taken into account when retene is used for PAH source apportionment. PMID:22452486

Quantification and characterization of emissions from small-scale biofuel combustion; Kvantifiering och karakterisering av faktiska utslaepp fraan smaaskalig biobraensleeldning

Energy Technology Data Exchange (ETDEWEB)

Johansson, Linda; Gustavsson, Lennart; Johansson, Mathias; Oesterberg, Stefan; Tullin, Claes; Persson, Henrik [Swedish National Testing and Research Inst., Boraas (Sweden); Cooper, David; Sjoedin, Aake; Potter, Annika; Brorstroem-Lunden, Eva [Swedish Environmental Research Institute, Goeteborg (Sweden)

2003-09-01

This report is the final report of a project within the BHM research program. A comprehensive set of emission measurements has been conducted on domestic biomass boilers for wood logs and wood pellets. Within the project development of a simple method for field sampling has also been included. During the emission studies, different boilers with respect to age, design, and biomass fuels are included in the study, which also covers two oil-fired boilers for comparison. The total number of measurements cases was 29, from which 25 were measured at the laboratory and the remaining in field. Two of the cases were domestic oil burning, and were included as a comparison. The gas measurements comprised carbon monoxide (CO), carbon dioxide (CO{sub 2} ), oxygen (O{sub 2} ), total organic carbons (TOC), nitrogen oxides (NO{sub x} ), polycyclic aromatic hydrocarbons (PAH), and 33 volatile organic compounds (VOC). Particle emissions were characterised by mass concentration, number concentration, and the corresponding particle size distributions. The mass concentration of particles ranged from 13 mg/MJ (wood pellets) up to 2200 mg/MJ for a water cooled wood boiler without heat storage tank. The CO emission increased with increased air ratio, which indicates that air supply was not the limiting parameter for CO burnout. Poor combustion conditions could instead be explained by poor mixing conditions, or that the excess air was that large that it can be suspected to cool the combustion chamber, resulting in high CO emissions. The TOC emission was shown to correlate to the CO emission. TOC varied between 1 and 4800 mg/MJ, presented as methane-equivalents, and CO-emissions between 30 and 16400 mg/MJ. Both TOC and CO are indicators of combustion conditions. The large variations in concentrations can be explained by the large differences in combustion devices, operation of the equipment, and fuel-quality, investigated. Methane made up the largest fraction of the VOC emissions in all of

Combustion chambers for wood furnaces with low particle emissions; Brennkammern fuer Holzfeuerstaetten mit geringen Partikelemissionen. Erste Messergebnisse zum Stand der Technik

Energy Technology Data Exchange (ETDEWEB)

Gaegauf, Ch.; Sattler, M.

2007-12-15

This interim report for the Swiss Federal Office of Energy (SFOE) takes a look at the results of a study made on the particle emissions of wood-burning ovens and furnaces by the Eco-Centre Langenbruck, Switzerland, in co-operation with the North-West Switzerland University of Applied Sciences. The work concentrated on finding innovative ways of reducing the emission of fine dust and aerosols by domestic heating units. Initial analysis has shown that present-day installations exhibit a potential for improvement both when firing-up as well as when in full operation. The measurement and analysis methods used in the tests are described. The results obtained are presented in graphical form and discussed. Measurements made on a storage-oven are presented and the results of extended particle analysis are discussed. Further development of the combustion technologies used in this area is suggested in the report's conclusions.

ERA-Net Evaluation of technology status for small-scale combustion of pellets from new ash rich biomasses - combustion tests in residential burners

Energy Technology Data Exchange (ETDEWEB)

Roennbaeck, Marie; Johansson, Mathias; Frida Claesson

2008-07-01

In this project, pellets with higher ash content compared to the wood pellets used today on the Swedish market were tested in three domestic-scale burners. The tests were carried out based on EN 303-5. In the flue gas, combustion parameters as carbon monoxide, carbon dioxide, oxygen and hydro carbons were measured, and also more fuel specific parameters such as nitrogen oxides, sulphur dioxide, hydrogen chloride, total dust and particle mass- and number concentration. The dust (fly ash) and bottom ash were characterized chemically. The implications of high ash content on combustion performance are discussed in the report. Altogether five pellets with 8 mm diameter were tested: oilseed straw pellet, reed canary grass pellet (RCG), barley straw pellet, bark pellet and wood pellet. All fuels were dry ranging from 6.5-12 % moisture. The ash content varied from 0.3 weight-% dm in wood to 7.9 % in RCG. Barley straw has a noticeable low ash melting temperature, < 980 deg C, and could not be combusted in any of the burners. The nitrogen content varied nine times and sulphur more than 10 times. The chlorine content was very low in wood and bark and more than 20 times higher in oilseed and barley. The composition of inorganic species in the fuel ash was dominated by calcium, potassium and silica in wood, bark and oilseed pellet, while RCG and barley straw were dominated by silica. The three burners used were commercial and known to fulfil high quality requirements. Burner A is a pellet burner where fuel is supplied on top of the grate with no mechanical mean for moving bottom ash on the grate during combustion. Bottom ash is blown away, and any slag remaining on the grate is removed with a scrape before ignition. Burner B is an upward burning pellet burner where fuel and ash is pushed upwards and the glow bed is exposed to the surrounding combustion department. Burner C is a forward burning grain burner that pushes fuel and ash forwards, inside a cylinder. From the

Particle-bound reactive oxygen species (PB-ROS) emissions and formation pathways in residential wood smoke under different combustion and aging conditions

Science.gov (United States)

Zhou, Jun; Zotter, Peter; Bruns, Emily A.; Stefenelli, Giulia; Bhattu, Deepika; Brown, Samuel; Bertrand, Amelie; Marchand, Nicolas; Lamkaddam, Houssni; Slowik, Jay G.; Prévôt, André S. H.; Baltensperger, Urs; Nussbaumer, Thomas; El-Haddad, Imad; Dommen, Josef

2018-05-01

Wood combustion emissions can induce oxidative stress in the human respiratory tract by reactive oxygen species (ROS) in the aerosol particles, which are emitted either directly or formed through oxidation in the atmosphere. To improve our understanding of the particle-bound ROS (PB-ROS) generation potential of wood combustion emissions, a suite of smog chamber (SC) and potential aerosol mass (PAM) chamber experiments were conducted under well-determined conditions for different combustion devices and technologies, different fuel types, operation methods, combustion regimes, combustion phases, and aging conditions. The PB-ROS content and the chemical properties of the aerosols were quantified by a novel ROS analyzer using the DCFH (2',7'-dichlorofluorescin) assay and a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). For all eight combustion devices tested, primary PB-ROS concentrations substantially increased upon aging. The level of primary and aged PB-ROS emission factors (EFROS) were dominated by the combustion device (within different combustion technologies) and to a greater extent by the combustion regimes: the variability within one device was much higher than the variability of EFROS from different devices. Aged EFROS under bad combustion conditions were ˜ 2-80 times higher than under optimum combustion conditions. EFROS from automatically operated combustion devices were on average 1 order of magnitude lower than those from manually operated devices, which indicates that automatic combustion devices operated at optimum conditions to achieve near-complete combustion should be employed to minimize PB-ROS emissions. The use of an electrostatic precipitator decreased the primary and aged ROS emissions by a factor of ˜ 1.5 which is however still within the burn-to-burn variability. The parameters controlling the PB-ROS formation in secondary organic aerosol were investigated by employing a regression model, including the fractions of

Organic compounds in PM 2.5 emitted from fireplace and woodstove combustion of typical Portuguese wood species

Science.gov (United States)

Gonçalves, Cátia; Alves, Célia; Fernandes, Ana Patrícia; Monteiro, Cristina; Tarelho, Luís; Evtyugina, Margarita; Pio, Casimiro

2011-09-01

The aim of this study is the further characterisation of PM 2.5 emissions from the residential wood combustion of common woods grown in Portugal. This new research extends to eight the number of biomass fuels studied and tries to understand the differences that the burning appliance (fireplace versus woodstove) and the combustion temperature (cold and hot start) have on emissions. Pinus pinaster (Maritime pine), Eucalyptus globulus (eucalypt), Quercus suber (cork oak), Acacia longifolia (Golden wattle), Quercus faginea (Portuguese oak), Olea europea (Olive), Quercus ilex rotundifolia (Holm oak) and briquettes produced from forest biomass waste were used in the combustion tests. Determinations included fine particle emission factors, carbonaceous content (OC and EC) by a thermal-optical transmission technique and detailed identification and quantification of organic compounds by gas chromatography-mass spectrometry. Fine particle emission factors from the woodstove were lower than those from the fireplace. For both combustion appliances, the OC/EC ratio was higher in "cold start" tests (1.56 ± 0.95 for woodstove and 2.03 ± 1.34 for fireplace). These "cold start" OC/EC values were, respectively, for the woodstove and the fireplace, 51% and 69% higher than those obtained in "hot start" experiments. The chromatographically resolved organics included n-alkanes, n-alkenes, PAHs, n-alkanals, ketones, n-alkanols, terpenoids, triterpenoids, phenolic compounds, phytosterols, alcohols, n-alkanoic acids, n-di-acids, unsaturated acids and alkyl esters of acids. The smoke emission rate and composition varied widely depending on fuel type, burning appliance and combustion temperature.

Preliminary study about refining wood fuel with torrefaction; Esiselvitys puupolttoaineen jalostamisesta torrefiointitekniikalla

Energy Technology Data Exchange (ETDEWEB)

Haemaelaeinen, E.; Heinimoe, J.

2006-07-01

The EU has started to reduce greenhouse gases which are the result of using fossil fuels. One way to do this is emission trade. There are plans to generate biofuels to replace non-renewable fuels. These biofuels can be processed with the old equipment in power plants. The advantage of biofuels is that their emission factor of carbon dioxide is agreed to be zero because wood consumes the same amount of carbon dioxide while it grows as it releases in combustion. One of these refined biofuels is torrefied wood. Its characteristics mostly correspond to coal, and it can be used in coal-fired power plants without changing equipment. Torrefaction means, in a manner of speaking, roasting wood in 250-270 deg C in oxygen-free conditions. In this process all the water is removed, as well as some of the volatile gases. The colour of the wood changes to chocolate brown, it gets lighter, does not smoke in combustion, repels water, is pulverized easily and releases only small amounts of particulate emissions. The durability and operating properties of torrefied wood are significantly different compared to the raw material. Torrefied wood also has better properties than e.g. wood coal. Torrefaction has been studied a little, and its combustion on the power plant scale has been tested on a small scale. Torrefied material is difficult and expensive to transport because of its proper-ties, so its density must be raised for transporting, e.g. by pelleting. Torrefaction combined with pelleting is, at its best, would be a competitive alternative when biomass, substituting coal, is processed off-site and transported in bulk by sea. Based on the data collected in this preliminary study it can be estimated that producing torrefied wood fuel in Finland has technical-economical possibilities. However, the application of the torrefaction process to Finnish conditions and domestic raw material demands investment in further studies before moving on to the actual implementation phase. (orig.)

Electrodialytic remediation of fly ash from co-combustion of wood and straw

DEFF Research Database (Denmark)

Chen, Wan; Jensen, Pernille Erland; Ottosen, Lisbeth M.

2015-01-01

The heavy metal content in fly ash from biomass combustion, such as straw, wood and sludge, often needs reducing before the ash can be used as fertilizer for agricultural land or as a component in the production of construction materials. In this study, fly ash from a boiler fueled with wood chips...... and straw was treated either by electrodialytic remediation (EDR) directly or by a combination of EDR and pre-wash with distilled water to investigate the possibilities of reducing the heavy metal content and reusing nutrients as fertilizer and bulk material in construction materials. Different experimental....../pre-wash-EDR treated ash mainly contained quartz, and the X-ray diffraction (XRD) peaks of K salts had disappeared. This shows that the potassium fertilizer potential was lost in the treated ashes, but the quartz mineral is beneficial in construction materials, such as ceramics. The K fertilizer could be recovered...

Emission of PCDD/Fs from Domestic Combustion Using Various Woods, Biofuel and Coals

Czech Academy of Sciences Publication Activity Database

Ocelka, T.; Tomšej, T.; Horák, J.; Šyc, Michal; Krpec, K.; Hopan, F.; Stáňa, M.

LVI, č. 2 (2010), s. 149-154 ISSN 1210-0471 R&D Projects: GA MŽP(CZ) SP/1A2/116/07; GA MŠk 2B08048 Institutional research plan: CEZ:AV0Z40720504 Keywords : combustion * solid fuels * emission factors Subject RIV: DI - Air Pollution ; Quality http://transactions.fs.vsb.cz/2010-2/1793.pdf

Chemical characterisation of PM10 emissions from combustion in a closed stove of common woods grown in Portugal

Science.gov (United States)

Gonçalves, C.; Alves, C.; Pio, C.; Rzaca, M.; Schmidl, C.; Puxbaum, H.

2009-04-01

A series of source tests were conducted to determine the wood elemental composition, combustion gases and the chemical constitution of PM10 emissions from the closed stove combustion of four species of woods grown in Portugal: Eucalyptus globulos, Pinus pinaster, Quercus suber and Acacia longifolia. The burning tests were made in a closed stove with a dilution source sampler. To ascertain the combustion phase and conditions, continuous emission monitors measured O2, CO2, CO, NO, hydrocarbons, temperature and pressure, during each burning cycle. Woodsmoke samples have been collected and analysed to estimate the contribution of plant debris and biomass smoke to atmospheric aerosols. At this stage of work, cellulose, anhydrosugars and humic-like substances (HULIS) have been measured. Cellulose was determined photometrically after its conversion to D-Glucose. The determination of levoglucosan and other anhydrosugars, including mannosan and galactosan, was carried out by high performance liquid chromatography with electrochemical detection. HULIS determination was made with a total organic carbon analyser and an infrared non dispersive detector, after the isolation of substances. Cellulose was present in PM10 at mass fractions (w/w) of 0.13%, 0.13%, 0.05% and 0.08% for Eucalyptus globulos, Pinus pinaster, Quercus suber and Acacia longifolia, respectively. Levoglucosan was the major anhydrosugar present in the samples, representing mass fractions of 14.71%, 3.80%, 6.78% and 1.91%, concerning the above mentioned wood species, respectively. The levoglucosan-to-mannosan ratio, usually used to evaluate the proportion of hardwood or softwood smoke in PM10, gave average values of 34.9 (Eucalyptus globulos), 3.40 (Pinus pinaster), 24.8 (Quercus suber) and 10.4 (Acacia longifolia). HULIS were present at mass fractions of 2.35%, 2.99%, 1.52% and 1.72% for the four wood species listed in the same order as before.

Effects of Different Wood Preservatives on The Some Physical Properties of Wood Species Used in Furniture and Building Industry

Directory of Open Access Journals (Sweden)

Abdi Atılgan

2012-04-01

Full Text Available This study aims to determine the combustion, density values of Fagus and Pinus sylvestris’ woods impregranted with Ammonium tetra fluoro borate (1 - 3 % and the mixture of cement and borax (6 % – 9 % according to ASTM-D 1413-76 standards. In the combustion test carried out according to ASTM-D 160-50, the combustion resulted from flame, the self-combustion and the combustion as glowing processes were completed and the amount of lux, combustion duration, decomposition and ash were determined. According to experimental results, it is determined that Fogus’ wood has the highest retention (42,43 kg/m3 in the mixture of cement and borax 9 %, combustion tempature (587 o C in the mixture of cement and borax 6 % , the value of lux (267 lux in the the combustion as glowing and Pinus sylvestris’ wood has the longest combustion duration (29,03 min. Ammonium tetrafluoro borate 1%, the most weight loss (94 %.

Combustion of impregnated wood. Test combustion in a biofuel boiler at Orrefors; Foerbraenning av impregnerat virke. Testfoerbraenning i en biobraenslepanna, Orrefors

Energy Technology Data Exchange (ETDEWEB)

Bergman, Goeran; Erlandsson, Martin; Hemstroem, Kristian; Hoegberg, Bengt; Oesterberg, Helen

2010-10-15

It is possible to burn impregnated wood containing copper in a biofuel boiler if the boiler has suitable flue gas cleaning equipment. The studied facility needs to complete its flue gas treatment with a dust control step (such as electrostatic precipitator, fabric or bag filter). If the incineration surpasses 50 tonnes of waste per year a special permission is required. Smaller quantities requires only a notification. In combustion of wood chips with an admixture of up to 20% copper-impregnated wood (50% sapwood and 50% kernel) the bottom ash stands clear of all minimum and maximum levels according to the Forestry Board's recommendations for using the ash as a fertilizer in forestry. The findings from the ash leaching tests show that chromium leaching from bottom ash of samples 4 and 5 is too high to allow deposition of the ashes in landfills along with non-hazardous wastes (the rest of the ash passed all the benchmarks). A hazard analysis has been carried out where the concept of toxicity index (TI) has been applied

Effect of combustion condition on cytotoxic and inflammatory activity of residential wood combustion particles

Science.gov (United States)

Jalava, Pasi I.; Salonen, Raimo O.; Nuutinen, Kati; Pennanen, Arto S.; Happo, Mikko S.; Tissari, Jarkko; Frey, Anna; Hillamo, Risto; Jokiniemi, Jorma; Hirvonen, Maija-Riitta

2010-05-01

Residential heating is an important local source of fine particles and may cause significant exposure and health effects in populations. We investigated the cytotoxic and inflammatory activity of particulate emissions from normal (NC) and smouldering (SC) combustion in one masonry heater. The PM 1-0.2 and PM 0.2 samples were collected from the dilution tunnel with a high-volume cascade impactor (HVCI). Mouse RAW 264.7 macrophages were exposed to the PM-samples for 24 h. Inflammatory mediators, (IL-6, TNFα and MIP-2), and cytotoxicity (MTT-test), were measured. Furthermore, apoptosis and cell cycle of macrophages were analyzed. The HVCI particulate samples were characterized for ions, elements and PAH compounds. Assays of elemental and organic carbon were conducted from parallel low volume samples. All the samples displayed mostly dose-dependent inflammatory and cytotoxic activity. SC samples were more potent than NC samples at inducing cytotoxicity and MIP-2 production, while the order of potency was reversed in TNFα production. SC-PM 1-0.2 sample was a significantly more potent inducer of apoptosis than the respective NC sample. After adjustment for the relative toxicity with emission factor (mg MJ -1), the SC-PM emissions had clearly higher inflammatory and cytotoxic potential than the NC-PM emissions. Thus, operational practice in batch burning of wood and the resultant combustion condition clearly affect the toxic potential of particulate emissions.

Catalytic reduction of emissions from small scale wood combustion. State of the art

Energy Technology Data Exchange (ETDEWEB)

Hargitai, T.; Silversand, F.A. [Katator AB, Lund (Sweden)

1998-12-31

Small-scale combustion of big-fuel often results in excessive emissions of volatile organic compounds (VOC), polyaromatic compounds (PAM) and carbon monoxide (CO). These compounds have a negative impact on human health and urban air quality. The predominant volatile organic compounds present in flue gases from big-fuel combustion are propylene, ethylene, butadiene, methanol, ethanol, methane, phenol and benzene. The poor combustion performance of some wood stoves has in certain cases led to legislation against small-scale combustion of big-fuel in urban areas. Catalytic cleaning is one very efficient way of decreasing the environmental impacts of big-fuel combustion. Several studies concerning catalytic purification of flue gases from big-fuel combustion have been presented over the years. Several problems must be addressed when designing a catalyst for this application: Clogging problems from deposition of ashes and particulates in the catalyst; Catalyst poisoning by sulphur, phosphorus, alkali metals etc.; Catalyst fouling due to deposition of ashes and particulates; Catalyst overheating at high flue-gas temperatures and Poor catalyst performance during start-up Most studies have been focused on monolith-type catalysts and- the conversion of CO, VOC and PAH typically is above 80 %. The observed problems are associated with increased pressure drop due to catalyst clogging and decreased catalyst performance due to fouling and poisoning. In most cases precious metals, preferably Pt. have been used as active combustion catalyst. Precious metals have a high activity for the combustion of CO and hydrocarbons and a fair stability against poisoning with compounds present in flue gases from big-fuel, e.g. sulphur and alkali metals. The majority of the studies on precious metals have been focused on Pt. Rh and Pd, which are especially active in catalytic combustion. Some metal oxides are used in catalytic combustion, especially at low temperatures (e.g. in VOC abatement

Chemical speciation of PM2.5 emissions from residential wood combustion and meat cooking

International Nuclear Information System (INIS)

McDonald, J.; Zielinska, B.; Fujita, E.; Chow, J.; Watson, J.; Sagebiel, J.; Sheetz, L.; Batie, S.

1998-01-01

Residential wood combustion and meat cooking emissions were each analyzed to develop a chemical emissions profile. Samples were collected using a DRI-constructed dilution stack sampler equipped with a 2.5 mm particle selective cyclone. Emissions were diluted 30-100 times, cooled to ambient temperature, and were allowed 80 seconds for condensation prior to collection. Fireplace and wood-stove emissions testing was conducted at the DRI facilities. Wood type, wood moisture, burn rate, and fuel load were varied for different experiments. Meat emissions testing was conducted at the CE-CERT stationary emissions lab in Riverside, California. Meat type, fat content, and the cooking appliance used were changed in different tests. Fine particle and semi-volatile organic compounds were collected on filter/PUF/XAD/PUF cartridges. Inorganic samples were collected on Teflon and quartz filters, which were analyzed for mass by gravimetry, elements by x-ray fluorescence, ammonium by automated colorimetry, organic and elemental carbon by thermal/optical reflectance, as well as chloride, nitrate, and sulfate by ion chromatography. Analysis of organic species was conducted by gas chromatography/mass spectrometry (GC/MS). These data have been utilized for constructing specific profiles for use in the Chemical Mass Balance model for apportionment of fine particle sources in the Denver, Colorado, region

Characterization and electrodialytic treatment of wood combustion fly ash for removal of cadmium

DEFF Research Database (Denmark)

Pedersen, Anne Juul

2003-01-01

especially contain amounts of the toxic heavy metal cadmium that may exceed the limiting values for agricultural utilisation given by the Danish Environmental Protection Agency.In this work the advances of using an electrodialytic remediation method to reduce the Cd content in wood combustion fly ash...... conditions. However, significant amounts of Cd could be extracted at neutral to alkaline conditions using an ammonium citrate solution as a desorption agent.Electrodialytic remediation experiments showed that, under optimised remediation conditions using a mixture of ammonium citrate (0.25M) and NH"3 (1.......25%) as an assisting agent, more than 70% of the initial Cd could be removed from the wood fly ash. The results also indicated that a continuous out-separation of Cd from the aqueous process solutions is possible. Thereby, recycling of the (nutrient rich) process solutions as well as of the remediated ash seems...

Combustion Behaviour of Pulverised Wood - Numerical and Experimental Studies. Part 1 Numerical Study

Energy Technology Data Exchange (ETDEWEB)

Elfasakhany, A.; Xue-Song Bai [Lund Inst. of Tech. (Sweden). Dept. of Heat and Power Engineering

2002-12-01

This report describes a theoretical/numerical investigation of the particle motion and the particle drying, pyrolysis, oxidation of volatile and char in a pulverised biofuel (wood) flame. This work, along with the experimental measurement of a pulverised wood flame in a vertical furnace at TPS, is supported by the Swedish Energy Agency, STEM. The fundamental combustion process of a pulverised wood flame with determined size distribution and anisotropy character is studied. Comprehensive submodels are studied and some models not available in the literature are developed. The submodels are integrated to a CFD code, previously developed at LTH. The numerical code is used to simulate the experimental flame carried out at TPS (as sub-task 2 within the project). The sub-models describe the drying, devolatilization, char formation of wood particles, and the oxidation reaction of char and the gas phase volatile. At the present stage, the attention is focused on the understanding and modelling of non-spherical particle dynamics and the drying, pyrolysis, and oxidation of volatile and char. Validation of the sub-models against the experimental data is presented and discussed in this study. The influence of different factors on the pulverised wood flame in the TPS vertical furnace is investigated. This includes shape of the particles, the effect of volatile release, as well as the orientation of the particles on the motion of the particles. The effect of particle size on the flame structure (distribution of species and temperature along the axis of the furnace) is also studied. The numerical simulation is in close agreement with the TPS experimental data in the concentrations of species O{sub 2}, CO{sub 2} as well as temperature. Some discrepancy between the model simulations and measurements is observed, which suggests that further improvement in our understanding and modeling the pulverised wood flame is needed.

Assessment of Combustion and Potash Production as Options for ...

African Journals Online (AJOL)

This study assessed combustion and potash production as options for management of wood waste. The percentage reduction in volume by combustion and potash generation potential of wood waste from nine different common species of wood obtained from a wood factory in Ibadan were evaluated. Potash from the ashes ...

Pelletizing and combustion of wood from thinning; Pelletering och foerbraenning av gallringsvirke

Energy Technology Data Exchange (ETDEWEB)

Oerberg, Haakan; Thyrel, Mikael; Kalen, Gunnar; Larsson, Sylvia

2007-12-14

This work has been done in order to find new raw material sources for an expanding pellet industry, combined with finding a use for a forest product that has no market today. The raw material has been forest from early thinning in two typical stands in Vaesterbotten. The purpose has been to evaluate this material as a raw material for producing pellets. Two typical stands have been chosen. One stand with only pine trees and one mixed stand dominated by birch. The soil of these stands was poor. Half of the trees were delimbed by harvest and half of the trees were not delimbed. This formed four different assortments that were handled in the study. After harvesting the assortments were transported to an asphalt area to be stored. Half of the material was stored during one summer and half of the material was stored during one year and one summer. The different assortments were upgraded to pellets and test combusted in the research plant BTC at the Swedish University of Agricultural Sciences, in Umeaa. The upgrading process contains of the following steps: 1.Chipping by a mobile chipper. 2.Low temperature drying (85 deg C). 3. Coarse shredding ({phi}15 mm). 4. Fine shredding ({phi}4-6 mm) and 5. Pelletizing (Die: {phi}8). Samples for fuel analysis were taken during the chipping. Analyses shows that the net calorific value for delimbed assortments are about 0,3 MJ/kg DM higher than for limbed assortments. Pellets made of the assortments Mixed limbed and Pine limbed has shown a net calorific value comparable to stem wood pellets. Pellets made of Birch delimbed show a net calorific value 0,4 MJ/kg DM lower than stem wood pellets. Analyses show that ash contents of the assortment Mixed delimbed was 1 %-unit higher compared to stem wood pellets. The assortment Pine delimbed and Birch delimbed has showed an ash contents comparable with stem wood pellets. The ash melting characteristics can reduce the value of a raw material. Low ash melting temperature for a fuel might cause

Environmental implications of the use of wood in domestic activities by the rural population of Usme

International Nuclear Information System (INIS)

Sierra Vargas, Fabio Emiro; Mejia Barragan, Fabiola

2011-01-01

Usme is the fifth locality of Bogota; it is located at the south of the city and has an estimated population of 294,580 inhabitants, approximately 6500 are located in rural areas. Most rural dwellers of Usme have not access to electricity, so for cooking they use firewood obtained from the surroundings or by direct purchase. Through field work, conducted surveys and information collected by direct experimentation in some kitchens in the area, were identified and collected samples of the woody species most used for cooking, to characterize its energy potential and were determined the efficiency of the stoves. Was identified that many families are buying the wood, either because they have no time to collect it or because of the distances they must travel. In general, the stoves technology generates low efficiency (less than 15%) because the combustion process is incomplete, leading additionally high production of CO. The most used woods are Eucalyptus, Pine and remnant of carpentry including Formica with MDF, a material that has not been reported in Colombia, it raises the need to study the impacts of its combustion. (author)

Implementation of new technologies in wood industry and their effect in wood products quality

OpenAIRE

ELVA ÇAUSHI; PANDELI MARKU

2014-01-01

There are about 300 companies producing furniture and about 250 small and medium enterprises (SME) producing sawn timber, which operate in the field of wood industry in Albania. This wood industry production is being challenged by the increasing demand in the domestic market, ranging from kitchen furniture to office and schools furniture, bedroom furniture, doors, windows, and saw timber in different dimensions. The production from the wood industry can fulfill about 80% of the domestic mark...

Wood energy and air quality. Synthetic report

International Nuclear Information System (INIS)

2009-07-01

This report presents and comments some reference data about the current and prospective (2010, 2020) pollutant emissions through wood combustion as a source of energy. It indicates and compares greenhouse gas emissions by the different sources for household, collective and industrial heating (fuel, gas, electricity, pellets, logs, grinds, wood wastes), gives an overview of atmospheric emissions due to biomass combustion. It compares emissions due to wood combustion with respect to the activity sectors and to combustion equipment. It highlights the challenges of the development of the household sector in terms of improvement and renewal of the quality of the burning equipment. It comments the implemented policies which notably aim at reducing the emission of particles, and at defining quality labels

Evaluation of the health impact of nanoparticles emitted from combustion sources: Comprehensive characterization of the physicochemical properties of nanoparticle emissions from wood combustion compliances, car- and ship diesel-engines as well as investigation of their toxicological effects on human lung cells and macrophages.

Science.gov (United States)

Zimmermann, R.; Dittmar, G.; Kanashova, T.; Buters, J.; Öder, S.; Paur, H. R.; Mülhopt, S.; Dilger, M.; Weiss, C.; Harndorf, H.; Stengel, B.; Hirvonen, M. R.; Jokiniemi, J.; Hiller, K.; Sapcariu, S.; Sippula, O.; Streibel, T.; Karg, E.; Weggler, B.; Schnelle-Kreis, J.; Lintelmann, J.; Sklorz, M.; Orasche, J.; Müller, L.; Passig, J.; Gröger, T.; BéruBé, K.; Krebs, T.

2016-12-01

Combustion emissions cause health effects. The HICE-Aerosol and Health project team studies the physicochemical properties as well as biological and toxicological effects on lung cells of combustion particle emissions. The chemical composition and physical parameters thoroughly characterized. Human lung cells are exposed to the diluted combustion exhaust fumes at the air-liquid interface (ALI), allowing a realistic lung-cell exposure by simulation of the lung situation. After exposure, cellular responses of the exposed lung cells are studied by multi-omics molecular biological analyses on transcriptomic, proteomic and metabolomic level. Emissions of wood combustion (log wood, pellet heater), ship diesel engines and car gasoline engines are addressed. Special field deployable ALI-exposition systems in a mobile S2-biological laboratory were set up and applied. Human alveolar epithelial cells (A549, BEAS2B and primary cells) as well as murine macrophages were ALI-exposed to diluted emissions. The cellular effects were then comprehensively characterized (viability, cyto-toxicology, multi-omics effects monitoring) and put in context with the chemical and physical aerosol data. The following order of overall cellular response-strength was observed: A relatively mild cellular effect is observed for the diluted wood combustion emissions. Interestingly the effects-strength for log-wood and pellet burner emissions are similar, although PM-concentrations are much higher for the log-wood heater. Similar mild biological effects are observed for the gasoline car emissions. The ship diesel engine emissions induced the most intense biological responses. A surprising result in this context is, that heavy fuel oil (HFO)-emissions showed lower biological effect strengths than the supposedly cleaner diesel fuel emissions (DF). The HFO-emission contain high concentrations of known toxicants (transition metals, polycyclic aromatics). This result was recently confirmed by experiments

Fireplace and woodstove fine particle emissions from combustion of western Mediterranean wood types

Science.gov (United States)

Alves, Célia; Gonçalves, Cátia; Fernandes, Ana Patrícia; Tarelho, Luís; Pio, Casimiro

2011-08-01

Wood from seven species of trees grown in the Portuguese forest ( Pinus pinaster, Eucalyptus globulus, Quercus suber, Acacia longifolia, Quercus faginea, Olea europea and Quercus ilex rotundifolia), and briquettes produced from forest biomass waste were burned in a fireplace and in a woodstove to determine the chemical composition of fine particle (PM 2.5) emissions. Samples were analysed for organic and elemental carbon (OC/EC), water soluble ions (Na +, NH 4+, K +, Mg 2+, Ca 2+, Cl -, NO 3- and SO 42-) and 67 elements. The PM 2.5 emission factors (g kg - 1 fuel burned, dry basis) were in the ranges 9.9-20.2 and 4.2-16.3, respectively, for the fireplace and the woodstove. Organic carbon contributed to about 50% of the fine particle mass in the emissions from every wood species studied in both burning appliances. The carbonaceous component of PM 2.5 was dominated by organic carbon, accounting for more than 85% of the total carbon (TC): OC/TC ranged from 0.85 to 0.96 (avg. 0.92) for the fireplace and from 0.86 to 0.97 (avg. 0.93) for the woodstove. The water-soluble ions accounted for 0.64 to 11.3% of the PM 2.5 mass emitted from the fireplace, whereas mass fractions between 0.53 and 13.6% were obtained for the woodstove. The golden wattle wood smoke showed a much higher ionic content than the emissions from the other wood types. Trace elements represented 0.4 to 2.5% and 0.2 to 2.2% of the PM 2.5 mass emitted, respectively, from the fireplace and the woodstove, which corresponded to average total emissions of 132 ± 77.3 mg kg - 1 and 93.4 ± 60.8 mg kg - 1 of wood burned. Among these, K, Pb, Al, Mn and Sr were present in all samples. From the emission profiles of the individual experiments, composite wood combustion profiles are suggested with the aid of a cluster analysis.

Manufacture of wood-pellets doubles. Biowatti Oy started a wood pellet plant in Turenki

International Nuclear Information System (INIS)

Rantanen, M.

1999-01-01

Wood pellets have many advantages compared to other fuels. It is longest processed biofuel with favorable energy content. It is simple to use, transport and store. Heating with wood pellets is cheaper than with light fuel oil, and approximately as cheap as utilization of heavy fuel oil, about 110 FIM/MWh. The taxable price of wood pellets is about 550 FIM/t. Stokers and American iron stoves are equally suitable for combustion of wood pellets. Chip fueled stokers are preferred in Finland, but they are also suitable for the combustion of wood pellets. Wood pellets is an environmentally friendly product, because it does not increase the CO 2 load in the atmosphere, and its sulfur and soot emissions are relatively small. The wood pelletizing plant of Biowatti Oy in Turenki was started in an old sugar mill. The Turenki sugar mill was chosen because the technology of the closed sugar factory was suitable for production of wood pellets nearly as such, and required only by slight modifications. A press, designed for briquetting of sugar beat clippings makes the pellets. The Turenki mill will double the volume of wood pellet manufacture in Finland during the next few years. At the start the annual wood pellet production will be 20 000 tons, but the environmental permit allows the production to be increased to 70 000 tons. At first the mill uses planing machine chips as a raw material in the production. It is the most suitable raw material, because it is already dry (moisture content 8-10%), and all it needs is milling and pelletizing. Another possible raw material is sawdust, which moisture content is higher than with planing machine chips. Most of the wood pellets produced are exported e.g. to Sweden, Denmark and Middle Europe. In Sweden there are over 10 000 single-family houses using wood pellets. Biowatti's largest customer is a power plant located in Stockholm, which combusts annually about 200 000 tons of wood pellets

Abatement of emissions from small-scale combustion of biofuels

International Nuclear Information System (INIS)

Cowburn, D.A.; Holtham, R.D.

1999-01-01

This report summarises the findings of a study examining the feasibility of designing a free-standing stove for heating a room using a downburning combustion system with air introduced above the bed of the fire to minimise the deposition of tar on the glass door of the stove. Details of the construction and operation of the appliance and the testing methods are given. Emission measurements, modeling, and work on pre-production of the prototype and production model stoves are reported. A paper on the development of low smoke stoves for domestic wood use is presented in an appendix. (UK)

Characterization and electrodialytic treatment of wood combustion fly ash for the removal of cadmium

International Nuclear Information System (INIS)

Pedersen, A.J.

2003-01-01

Due to a high content of macronutrients and a potential liming capacity, recycling of ashes from biomass combustion to agricultural fields as fertilisers and/or for soil improvement is considered in Denmark and other countries utilising biomass as an energy source. However, the fly ash fractions especially contain amounts of the toxic heavy metal cadmium that may exceed the limiting values for agricultural utilisation given by the Danish Environmental Protection Agency. In this work the advances of using an electrodialytic remediation method to reduce the Cd content in wood combustion fly ash--for the aim of recycling--was described. Initial characterisation of the experimental ash showed that the Cd content exceeded the limiting values for agricultural use and therefore needed treatment before being recycled. The pH in the ash was very high (13.3), and the Cd was not soluble at these alkaline conditions. However, significant amounts of Cd could be extracted at neutral to alkaline conditions using an ammonium citrate solution as a desorption agent. Electrodialytic remediation experiments showed that, under optimised remediation conditions using a mixture of ammonium citrate (0.25 M) and NH 3 (1.25%) as an assisting agent, more than 70% of the initial Cd could be removed from the wood fly ash. The results also indicated that a continuous out-separation of Cd from the aqueous process solutions is possible. Thereby, recycling of the (nutrient rich) process solutions as well as of the remediated ash seems achievable

Global burden of mortalities due to chronic exposure to ambient PM2.5 from open combustion of domestic waste

Science.gov (United States)

Kodros, John K.; Wiedinmyer, Christine; Ford, Bonne; Cucinotta, Rachel; Gan, Ryan; Magzamen, Sheryl; Pierce, Jeffrey R.

2016-12-01

Uncontrolled combustion of domestic waste has been observed in many countries, creating concerns for air quality; however, the health implications have not yet been quantified. We incorporate the Wiedinmyer et al (2014 Environ. Sci. Technol. 48 9523-30) emissions inventory into the global chemical-transport model, GEOS-Chem, and provide a first estimate of premature adult mortalities from chronic exposure to ambient PM2.5 from uncontrolled combustion of domestic waste. Using the concentration-response functions (CRFs) of Burnett et al (2014 Environ. Health Perspect. 122 397-403), we estimate that waste-combustion emissions result in 270 000 (5th-95th: 213 000-328 000) premature adult mortalities per year. The confidence interval results only from uncertainty in the CRFs and assumes equal toxicity of waste-combustion PM2.5 to all other PM2.5 sources. We acknowledge that this result is likely sensitive to choice of chemical-transport model, CRFs, and emission inventories. Our central estimate equates to 9% of adult mortalities from exposure to ambient PM2.5 reported in the Global Burden of Disease Study 2010. Exposure to PM2.5 from waste combustion increases the risk of premature mortality by more than 0.5% for greater than 50% of the population. We consider sensitivity simulations to uncertainty in waste-combustion emission mass, the removal of waste-combustion emissions, and model resolution. A factor-of-2 uncertainty in waste-combustion PM2.5 leads to central estimates ranging from 138 000 to 518 000 mortalities per year for factors-of-2 reductions and increases, respectively. Complete removal of waste combustion would only avoid 191 000 (5th-95th: 151 000-224 000) mortalities per year (smaller than the total contributed premature mortalities due to nonlinear CRFs). Decreasing model resolution from 2° × 2.5° to 4° × 5° results in 16% fewer mortalities attributed to waste-combustion PM2.5, and over Asia, decreasing resolution from 0.5° × 0.666° to 2° × 2

Catalysts for cleaner combustion of coal, wood and briquettes sulfur dioxide reduction options for low emission sources

Energy Technology Data Exchange (ETDEWEB)

Smith, P.V. [Global Environmental Solutions, Inc., Morton Grove, IL (United States)

1995-12-31

Coal fired, low emission sources are a major factor in the air quality problems facing eastern European cities. These sources include: stoker-fired boilers which feed district heating systems and also meet local industrial steam demand, hand-fired boilers which provide heat for one building or a small group of buildings, and masonary tile stoves which heat individual rooms. Global Environmental Systems is marketing through Global Environmental Systems of Polane, Inc. catalysts to improve the combustion of coal, wood or fuel oils in these combustion systems. PCCL-II Combustion Catalysts promotes more complete combustion, reduces or eliminates slag formations, soot, corrosion and some air pollution emissions and is especially effective on high sulfur-high vanadium residual oils. Glo-Klen is a semi-dry powder continuous acting catalyst that is injected directly into the furnace of boilers by operating personnel. It is a multi-purpose catalyst that is a furnace combustion catalyst that saves fuel by increasing combustion efficiency, a cleaner of heat transfer surfaces that saves additional fuel by increasing the absorption of heat, a corrosion-inhibiting catalyst that reduces costly corrosion damage and an air pollution reducing catalyst that reduces air pollution type stack emissions. The reduction of sulfur dioxides from coal or oil-fired boilers of the hand fired stoker design and larger, can be controlled by the induction of the Glo-Klen combustion catalyst and either hydrated lime or pulverized limestone.

PAH emissions from old and new types of domestic hot water boilers.

Science.gov (United States)

Horak, Jiri; Kubonova, Lenka; Krpec, Kamil; Hopan, Frantisek; Kubesa, Petr; Motyka, Oldrich; Laciok, Vendula; Dej, Milan; Ochodek, Tadeas; Placha, Daniela

2017-06-01

Five different domestic heating boilers (automatic, over-fire, with down-draft combustion and gasification) and three types of fuel (lignite, wood and mixed fuel) were examined in 25 combustion tests and correlated with the emissions of particulate matter (PM), carbon monoxide (CO), total organic carbon (TOC) and 12 polycyclic aromatic hydrocarbons (PAHs with MW = 178-278 g/mol) focusing on particle phase. However, the distribution of 12 PAHs in gas phase was considered as well due to the presence mainly of lighter PAHs in gas phase. The PAHs, as well as the CO and TOC, are the indicators of incomplete combustion, and in this study PAH emission increased significantly with increasing emissions of CO and TOC. The PAHs were mainly detected on PM 2.5 , their contents were increasing linearly with increasing PM 2.5 emissions. The highest emission factors of PAHs were measured for boilers of old construction, such as over-fire boiler (5.8-929 mg/kg) and boiler with down-draft combustion (3.1-54.1 mg/kg). Modern types of boilers produced much lower emissions of PAHs, in particular, automatic boiler (0.3-3.3 mg/kg) and gasification boilers (0.2-6.7 mg/kg). In general, the inefficient combustion at reduced output of boilers generated 1.4-17.7 times more emissions of PAHs than the combustion at nominal output of boilers. It is recommended to operate boilers at nominal output with sufficient air supply and to use the proper fuel to minimise PAHs emissions from domestic heating appliances. Copyright © 2017 Elsevier Ltd. All rights reserved.

Danish emission inventories for stationary combustion plants

DEFF Research Database (Denmark)

Nielsen, Malene; Nielsen, Ole-Kenneth; Plejdrup, Marlene Schmidt

Emission inventories for stationary combustion plants are presented and the methodologies and assumptions used for the inventories are described. The pollutants considered are SO2, NOx, NMVOC, CH4, CO, CO2, N2O, NH3, particulate matter, heavy metals, dioxins, HCB and PAH. The CO2 emission in 2008...... incineration plants. The combustion of wood in residential plants has increased considerably in recent years resulting in increased emission of PAH, particulate matter and CO. The emission of NMVOC has increased since 1990 as a result of both the increased combustion of wood in residential plants...... and the increased emission from lean-burn gas engines. The dioxin emission decreased since 1990 due to flue gas cleaning on waste incineration plants. However in recent years the emission has increased as a result of the increased combustion of wood in residential plants....

Danish emission inventories for stationary combustion plants

DEFF Research Database (Denmark)

Nielsen, Malene; Nielsen, Ole-Kenneth; Plejdrup, Marlene Schmidt

Emission inventories for stationary combustion plants are presented and the methodologies and assumptions used for the inventories are described. The pollutants considered are SO2, NOx, NMVOC, CH4, CO, CO2, N2O, particulate matter, heavy metals, dioxins, HCB and PAH. The CO2 emission in 2007 was 10...... incineration plants. The combustion of wood in residential plants has increased considerably in recent years resulting in increased emission of PAH, particulate matter and CO. The emission of NMVOC has increased since 1990 as a result of both the increased combustion of wood in residential plants...... and the increased emission from lean-burn gas engines. The dioxin emission decreased since 1990 due to flue gas cleaning on waste incineration plants. However in recent years the emission has increased as a result of the increased combustion of wood in residential plants....

A novel field measurement method for determining fine particle and gas emissions from residential wood combustion

Science.gov (United States)

Tissari, Jarkko; Hytönen, Kati; Lyyränen, Jussi; Jokiniemi, Jorma

Emission data from residential wood combustion are usually obtained on test stands in the laboratory but these measurements do not correspond to the operational conditions in the field because of the technological boundary conditions (e.g. testing protocol, environmental and draught conditions). The field measurements take into account the habitual practice of the operators and provide the more reliable results needed for emission inventories. In this study, a workable and compact method for measuring emissions from residential wood combustion in winter conditions was developed. The emissions for fine particle, gaseous and PAH compounds as well as particle composition in real operational conditions were measured from seven different appliances. The measurement technique worked well and was evidently suitable for winter conditions. It was easy and fast to use, and no construction scaffold was needed. The dilution of the sample with the combination of a porous tube diluter and an ejector diluter was well suited to field measurement. The results indicate that the emissions of total volatile organic carbon (TVOC) (17 g kg -1 (of dry wood burned)), carbon monoxide (CO) (120 g kg -1) and fine particle mass (PM 1) (2.7 g kg -1) from the sauna stove were higher than in the other measured appliances. In the masonry heaters, baking oven and stove, the emissions were 2.9-9 g kg -1 TVOC, 28-68 g kg -1 CO and 0.6-1.6 g kg -1 PM 1. The emission of 12 PAHs (PAH 12) from the sauna stove was 164 mg kg -1 and consisted mainly of PAHs with four benzene rings in their structure. PAH 12 emission from other appliances was, on average, 21 mg kg -1 and was dominated by 2-ring PAHs. These results indicate that despite the non-optimal operational practices in the field, the emissions did not differ markedly from the laboratory measurements.

Experimental investigation on flue gas emissions of a domestic biomass boiler under normal and idle combustion conditions-super-†

OpenAIRE

Hao Liu; Guoquan Qiu; Yingjuan Shao; Saffa B. Riffat

2010-01-01

Biomass plays an important role in the world primary energy supplies, currently providing ∼14% of the world's primary energy needs and being the fourth largest contributor following coal, oil and natural gas. Over the past decade, domestic biomass heating has received more governmental and public supports than ever before in many developed countries, such as the UK. Although biomass combustion releases some combustion pollutants, biomass is renewable and produces little net CO 2 emissions to ...

Effect of raw material particle-size distribution on combustion characteristics of stem wood pellets; Paaverkan av partikelfraktionsfoerdelningen paa utbraenningshastigheten hos traepellets vid nyttjande av olika soenderdelningsmetoder

Energy Technology Data Exchange (ETDEWEB)

Israelsson, Samuel; Henriksson, Gunnar; Boman, Christoffer; Oehman, Marcus

2007-01-15

The objective of the project was to determine the effect of raw material particle-size distribution on combustion characteristics of stem wood pellets. Several well defined pellet qualities were produced from raw materials (stem wood of pine and spruce) which had both different particle-size distributions and were produced with different milling equipments (hammer mill/refiner). The pellets were produced in a traditional (bench-scale) pellet mill and in a laboratory pellet mill/press. The combustion characteristics of the individual pellets were determined in a laboratory scale oven. Char yield, -shrinkage, -density and the micro pore volume of the produced char were also determined. Differences in total conversion times of approximately 5 % at experimental condition relevant for typical pellets equipment were determined for the different pellet qualities. The underlying reasons for the obtained differences in the combustion characteristics between the different pellet qualities are discussed in the report

Wood pellets for stoker burner

International Nuclear Information System (INIS)

Nykaenen, S.

2000-01-01

The author of this article has had a stoker for several years. Wood chips and sod peat has been used as fuels in the stoker, either separately or mixed. Last winter there occurred problems with the sod peat due to poor quality. Wood pellets, delivered by Vapo Oy were tested in the stoker. The price of the pellets seemed to be a little high 400 FIM/500 kg large sack. If the sack is returned in good condition 50 FIM deposit will be repaid to the customer. However, Vapo Oy informed that the calorific value of wood pellets is three times higher than that of sod peat so it should not be more expensive than sod peat. When testing the wood pellets in the stoker, the silo of the stoker was filled with wood pellets. The adjustments were first left to position used for sod peat. However, after the fire had ignited well, the adjustments had to be decreased. The content of the silo was combusted totally. The combustion of the content of the 400 litter silo took 4 days and 22 hours. Respectively combustion of 400 l silo of good quality sod peat took 2 days. The water temperature with wood pellets remained at 80 deg C, while with sod peat it dropped to 70 deg C. The main disadvantage of peat with small loads is the unhomogenous composition of the peat. The results of this test showed that wood pellets will give better efficiency than peat, especially when using small burner heads. The utilization of them is easier, and the amount of ash formed in combustion is significantly smaller than with peat. Wood pellets are always homogenous and dry if you do not spoil it with unproper storage. Pellets do not require large storages, the storage volume needed being less than a half of the volume needed for sod peat. When using large sacks the amount needed can even be transported at the trunk of a passenger car. Depending on the area to be heated, a large sack is sufficient for heating for 2-3 weeks. Filling of stoker every 2-5 day is not an enormous task

Fate of Cu, Cr, and As during combustion of impregnated wood with and without peat additive

Energy Technology Data Exchange (ETDEWEB)

Karin Lundholm; Dan Bostroem; Anders Nordin; Andrei Shchukarev [Umeaa University, Umeaa (Sweden). Energy Technology and Thermal Process Chemistry

2007-09-15

The EU Directive on incineration of waste regulates the harmful emissions of particles and twelve toxic elements, including copper, chromium, and arsenic. Using a 15 kW pellets-fueled grate burner, experiments were performed to determine the fate of copper, chromium, and arsenic during combustion of chromate copper arsenate (CCA) preservative wood. The fate and speciation of copper, chromium, and arsenic were determined from analysis of the flue gas particles and the bottom ash using SEM-EDS, XRD, XPS, and ICP-AES. Chemical equilibrium model calculations were performed to interpret the experimental findings. The results revealed that about 5% copper, 15% chromium, and 60% arsenic were volatilized during combustion of pure CCA-wood, which is lower than predicted volatilization from the individual arsenic, chromium, and copper oxides. This is explained by the formation of more stable refractory complex oxide phases for which the stability trends and patterns are presented. When co-combusted with peat, an additional stabilization of these phases was obtained and thus a small but noteworthy decrease in volatilization of all three elements was observed. The major identified phases for all fuels were CuCrO{sub 2}(s), (Fe,Mg,Cu)(Cr,Fe,Al)O{sub 4}(s), Cr{sub 2}O{sub 3}(s), and Ca{sub 3}(AsO{sub 4}){sub 2}(s). Arsenic was also identified in the fine particles as KH{sub 2}AsO{sub 4}(s) and As{sub 2}O{sub 3}). A strong indication of hexavalent chromium in the form of K{sub 2}CrO{sub 4} or as a solid solution between K{sub 3}Na(CrO{sub 4}){sub 2} and K{sub 3}Na(SO{sub 4}){sub 2} was found in the fine particles. Good qualitative agreement was observed between experimental data and chemical equilibrium model calculations. 38 refs., 6 figs., 2 tabs.

Specifics of phytomass combustion in small experimental device

Science.gov (United States)

Lenhard, Richard; Mičieta, Jozef; Jandačka, Jozef; Gavlas, Stanislav

2015-05-01

A wood pellet combustion carries out with high efficiency and comfort in modern pellet boilers. These facts help to increase the amount of installed pellet boilers in households. The combustion process quality depends besides the combustion conditions also on the fuel quality. The wood pellets, which don`t contain the bark and branches represent the highest quality. Because of growing pellet demand, an herbal biomass (phytomass), which is usually an agricultural by-product becomes economically attractive for pellet production. Although the phytomass has the net calorific value relatively slightly lower than the wood biomass, it is often significantly worse in view of the combustion process and an emission production. The combustion of phytomass pellets causes various difficulties in small heat sources, mainly due to a sintering of fuel residues. We want to avoid the ash sintering by a lowering of temperature in the combustion chamber below the ash sintering temperature of phytomass via the modification of a burner design. For research of the phytomass combustion process in the small boilers is constructed the experimental combustion device. There will investigate the impact of cooling intensity of the combustion chamber on the combustion process and emissions. Arising specific requirements from the measurement will be the basis for the design of the pellet burner and for the setting of operating parameters to the trouble-free phytomass combustion was guaranteed.

Specifics of phytomass combustion in small experimental device

Directory of Open Access Journals (Sweden)

Lenhard Richard

2015-01-01

Full Text Available A wood pellet combustion carries out with high efficiency and comfort in modern pellet boilers. These facts help to increase the amount of installed pellet boilers in households. The combustion process quality depends besides the combustion conditions also on the fuel quality. The wood pellets, which don`t contain the bark and branches represent the highest quality. Because of growing pellet demand, an herbal biomass (phytomass, which is usually an agricultural by-product becomes economically attractive for pellet production. Although the phytomass has the net calorific value relatively slightly lower than the wood biomass, it is often significantly worse in view of the combustion process and an emission production. The combustion of phytomass pellets causes various difficulties in small heat sources, mainly due to a sintering of fuel residues. We want to avoid the ash sintering by a lowering of temperature in the combustion chamber below the ash sintering temperature of phytomass via the modification of a burner design. For research of the phytomass combustion process in the small boilers is constructed the experimental combustion device. There will investigate the impact of cooling intensity of the combustion chamber on the combustion process and emissions. Arising specific requirements from the measurement will be the basis for the design of the pellet burner and for the setting of operating parameters to the trouble-free phytomass combustion was guaranteed.

Dioxin emissions from coal combustion in domestic stove: Formation in the chimney and coal chlorine content influence

Directory of Open Access Journals (Sweden)

Paradiz Bostjan

2015-01-01

Full Text Available Combustion experiments conducted in domestic stove burning hard coal demonstrated a predominant influence of the coal chlorine content on the PCDD/F emissions, together with a pronounced effect of the flue gas temperature. PCDD/F concentrations of over 100 ng TEQ/m3, three orders of magnitude higher than in a modern waste incinerator, were measured in the flue gases of a domestic stove when combusting high chlorine coal (0.31 %. The PCDD/F concentrations in the flue gases dropped below 0,5 ng TEQ/m3, when low chlorine coal (0.07 % was used. When low chlorine coal was impregnated with NaCl to obtain 0.38 % chlorine content, the emission of the PCDD/Fs increased by two orders of magnitude. Pronounced nonlinearity of the PCDD/F concentrations related to chlorine content in the coal was observed. The combustion of the high chlorine coal yielded PCDD/F concentrations in flue gases one order of magnitude lower in a fan cooled chimney when compared to an insulated one, thus indicating formation in the chimney. The influence of flue gas temperature on the PCDD/F emissions was less pronounced when burning low chlorine coal. The predominant pathway of the PCDD/F emissions is via flue gases, 99 % of the TEQ in the case of the high chlorine coal for insulated chimney.

Power generation from waste wood

Energy Technology Data Exchange (ETDEWEB)

Nitsche, H

1980-04-18

Since the energy crisis, power generation from waste wood has become increasingly important. The most profitable way to use waste wood in woodworking plants with an annual production of 100 to 150,000 m/sup 3/ solid measure of wood chips and bark is by combustion and thermal energy recovery. In plants with an annual production of 10,000 m/sup 3/ solid measure of wood chips and bark, electric power generation is a suitable application.

Equipment for biomass. Wood burners; Materiels pour la biomasse, les chaudieres bois

Energy Technology Data Exchange (ETDEWEB)

Chieze, B. [SA Compte R., 63 - Arlanc (France)

1997-12-31

A review of the French classification of biomass wastes (and more especially wood and wood wastes) concerning classified burning equipment, is presented: special authorization is thus needed for burning residues from wood second transformation processes. Limits for combustion product emission levels are detailed and their impact on wood burning and process equipment is examined: feeder, combustion chamber, exchanger, fume treatment device, residue disposal. Means for reducing pollutant emissions are reviewed

Producer for vegetal combustibles for internal-combustion motors

Energy Technology Data Exchange (ETDEWEB)

1943-12-28

A producer is described for internal-combustion motors fed with wood or agricultural byproducts characterized by the fact that its full operation is independent of the degree of wetness of the material used.

Wood would burn

International Nuclear Information System (INIS)

Swithenbank, Jim; Chen, Qun; Zhang, Xiaohui; Sharifi, Vida; Pourkashanian, Mohamed

2011-01-01

Absract: In view of the world-wide problem of energy sustainability and greenhouse gas production (carbon dioxide), it is timely to review the issues involved in generating heat and power from all fuels and especially new (to the UK) solid fuels, including high moisture fuels such as wood, SRF, oil shale, tar sands and brown coal, which will become major international fuels as oil and gas become depleted. The combustion properties of some of these materials are significantly different from traditional coal, oil and gas fuels, however the technology proposed herein is also applicable to these conventional fuels. This paper presents some innovative combustion system options and the associated technical factors that must be considered for their implementation. For clarity of understanding, the novel concepts will be largely presented in terms of a currently developing solid fuel market; biomass wood chips. One of the most important characteristics of many solid fuels to be used in the future (including oil shale and brown coal) is their high moisture content of up to 60%. This could be removed by utilising low grade waste heat that is widely available in industry to dry the fuel and thus reduce transport costs. Burning such dried wood for power generation also increases the energy available from combustion and thus acts as a thermal transformer by upgrading the low grade heat to heat available at combustion temperatures. The alternative approach presented here is to recover the latent heat by condensing the extrinsic moisture and the water formed during combustion. For atmospheric combustion, the temperature of the condensed combustion products is below the dew point at about 55-65 o C and is only suitable for recovery in an efficient district heating system. However, in order to generate power from the latent heat, the condensation temperature must be increased to the level where the heat can be used in the thermodynamic power cycle. This can be achieved by

Reactivity and burnout of wood fuels

Energy Technology Data Exchange (ETDEWEB)

Dall' Ora, M.

2011-07-01

This thesis deals with the combustion of wood in pulverised fuel power plants. In this type of boiler, the slowest step in the wood conversion process is char combustion, which is one of the factors that not only determine the degree of fuel burnout, but also affect the heat release profile in the boiler and thereby the overall operation and efficiency of the plant. Chapter 1 consists of an introduction to thermal conversion of biomass fuels as well as a description of a Danish power plant where a measuring campaign was carried out as part of this project. Chapter 2 is a brief literature review of different aspects relevant to wood combustion, including wood structure and composition, wood pyrolysis, wood char properties and wood char oxidation. The full scale campaign, which is the subject of Chapter 3, included sampling of wood fuel before and after milling and sampling of gas and particles at the top of the combustion chamber. The collected samples and data are used to obtain an evaluation of the mills in operation at the power plant, the particle size distribution of the wood fuel, as well as the char conversion attained in the furnace. In Chapter 4 an experimental investigation on the relation between pyrolysis of wood in boiler-like conditions and wood char properties is presented. Chars from pine and beech wood were produced by fast pyrolysis in an entrained flow reactor and by slow pyrolysis in a thermogravimetric analyser. The influence of pyrolysis temperature, heating rate and particle size on char yield and morphology was investigated. The applied pyrolysis temperature varied in the range 673-1673 K for slow pyrolysis and 1073-1573 K for fast pyrolysis. The chars were oxidised in a thermogravimetric analyser and the mass loss data were used to determine char oxidation reactivity. Char yield from fast pyrolysis (104-105 K/s) was as low as 1-6% on a dry ash free basis, whereas it was about 15-17% for slow pyrolysis (10-20 K/min); char yield decreased as

Toxicology of Biodiesel Combustion products

Science.gov (United States)

1. Introduction The toxicology of combusted biodiesel is an emerging field. Much of the current knowledge about biological responses and health effects stems from studies of exposures to other fuel sources (typically petroleum diesel, gasoline, and wood) incompletely combusted. ...

Utilisation of Estonian energy wood resources

Energy Technology Data Exchange (ETDEWEB)

Muiste, P.; Tullus, H.; Uri, V. [Estonian Agricultural University, Tartu (Estonia)

1996-12-31

In the end of the Soviet period in the 1980s, a long-term energy programme for Estonia was worked out. The energy system was planned to be based on nuclear power and the share of domestic alternative sources of energy was low. The situation has greatly changed after the re-establishment of the Estonian independence, and now wood and peat fuels play an important role in the energy system. Energy consumption in Estonia decreased during the period 1970-1993, but this process has less influenced the consumption of domestic renewable fuels - peat and wood. It means that the share of these fuels has grown. The investment on substitution of imported fossil fuels and on conversion of boiler plants from fossil fuels to domestic fuels has reached the level of USD 100 million. The perspectives of the wood energy depend mainly on two factors; the resources and the price of wood energy compared with other fuels. The situation in wood market influences both the possible quantities and the price. It is typical that the quickly growing cost of labour power in Estonia is greatly affecting the price of energy wood. Though the price level of fuel peat and wood chips is lower than the world market price today, the conditions for using biofuels could be more favourable, if higher environmental fees were introduced. In conjunction with increasing utilisation of biofuels it is important to evaluate possible emissions or removal of greenhouse gases from Estonian forests 3 refs.

Utilisation of Estonian energy wood resources

Energy Technology Data Exchange (ETDEWEB)

Muiste, P; Tullus, H; Uri, V [Estonian Agricultural University, Tartu (Estonia)

1997-12-31

In the end of the Soviet period in the 1980s, a long-term energy programme for Estonia was worked out. The energy system was planned to be based on nuclear power and the share of domestic alternative sources of energy was low. The situation has greatly changed after the re-establishment of the Estonian independence, and now wood and peat fuels play an important role in the energy system. Energy consumption in Estonia decreased during the period 1970-1993, but this process has less influenced the consumption of domestic renewable fuels - peat and wood. It means that the share of these fuels has grown. The investment on substitution of imported fossil fuels and on conversion of boiler plants from fossil fuels to domestic fuels has reached the level of USD 100 million. The perspectives of the wood energy depend mainly on two factors; the resources and the price of wood energy compared with other fuels. The situation in wood market influences both the possible quantities and the price. It is typical that the quickly growing cost of labour power in Estonia is greatly affecting the price of energy wood. Though the price level of fuel peat and wood chips is lower than the world market price today, the conditions for using biofuels could be more favourable, if higher environmental fees were introduced. In conjunction with increasing utilisation of biofuels it is important to evaluate possible emissions or removal of greenhouse gases from Estonian forests 3 refs.

Preliminary correlation of organic molecular tracers in residential wood smoke with the source of fuel

Science.gov (United States)

Standley, Laurel J.; Simoneit, Bernd R. T.

Polar cyclic di- and triterpenoids were analyzed in the extracts of residential wood combustion aerosols collected in suburban sections of Eugene, Oakridge and Corvallis, Oregon. Additional samples collected included alder wood, smoke from two wood stoves burning only alder or pine as fuel, soot from a stove burning alder and a fireplace where oak was the predominant fuel. Due to the relatively cooler temperatures present under the smoldering conditions of residential wood combustion, as compared to the active burning of forest fires and slash burns, incomplete combustion resulted in the preservation of high levels of the natural products. There were three distinct signatures which could be used to trace relative input from coniferous, alder and oak combustion products, i.e. diterpenoids, lupane-derived triterpenoids and friedelin, respectively. Conifer combustion products dominated the suburban smoke aerosols.

A secular carbon debt from atmospheric high temperature combustion of stem wood?

DEFF Research Database (Denmark)

Czeskleba-Dupont, Rolf

2012-01-01

' approach for smokestack emissions that was propagated within the Kyoto process, the first phase of which is terminating in 2012. Otherwise, it is tolerated that the substitution of wood pellets for coal or other fossil fuels creates long lasting extra emissions of carbon dioxide – a mistake of climate......Basically, combustion of woody biomass in high temperature processes that react with atmospheric air results in a long lasting addition of carbon dioxide to the atmosphere. When harvesting large extra amounts of stem tree for energetic use, a global as well as secular time frame is needed to assess...... overall consequences with due attention given to biosphere processes, including the complex productivity of whole ecosystems. Analytically, a time dependent variable of carbon neutralization can be traced by a simple carbon neutrality or CN factor. Using the forgotten Marland approach, project managers...

Techno-economic analysis of wood biomass boilers for the greenhouse industry

International Nuclear Information System (INIS)

Chau, J.; Sowlati, T.; Sokhansanj, S.; Preto, F.; Melin, S.; Bi, X.

2009-01-01

The objective of this study is to perform a techno-economic analysis on a typical wood pellet and wood residue boiler for generation of heat to an average-sized greenhouse in British Columbia. The variables analyzed included greenhouse size and structure, boiler efficiency, fuel types, and source of carbon dioxide (CO 2 ) for crop fertilization. The net present value (NPV) show that installing a wood pellet or a wood residue boiler to provide 40% of the annual heat demand is more economical than using a natural gas boiler to provide all the heat at a discount rate of 10%. For an assumed lifespan of 25 years, a wood pellet boiler system could generate NPV of C$259,311 without electrostatic precipitator (ESP) and C$74,695 with ESP, respectively. While, installing a wood residue boiler with or without an ESP could provide NPV of C$919,922 or C$1,104,538, respectively. Using a wood biomass boiler could also eliminate over 3000 tonne CO 2 equivalents of greenhouse gases annually. Wood biomass combustion generates more particulate matters than natural gas combustion. However, an advanced emission control system could significantly reduce particulate matters emission from wood biomass combustion which would bring the particulate emission to a relatively similar level as for natural gas

Interactive wood combustion for botanical tree models

KAUST Repository

Pirk, Sö ren; Jarząbek, Michał; Hadrich, Torsten; Michels, Dominik L.; Palubicki, Wojciech

2017-01-01

We present a novel method for the combustion of botanical tree models. Tree models are represented as connected particles for the branching structure and a polygonal surface mesh for the combustion. Each particle stores biological and physical

Air pollution from wood combustion. Measurements at Elverum, Norway during the winters 1981 and 1982. Luftforurensning fra vedfyring. Maalinger i Elverum, Norge vintrene 1981 og 1982

Energy Technology Data Exchange (ETDEWEB)

Ramdahl, T; Schjoldager, J; Hanssen, J E; Moeller, M

1983-01-01

Ambient sampling and anlysis of air pollutants related to wood combustion have been carried out at the town of Elverum, Norway during the winters of 1981 and 1982. Two measurement sites were selected, Elverum (within the town) and Strandfossen. The concentration of fine particles, PAH and benzene on cold days in Elverum was similar to average winter concentrations in central parts of Oslo. The concentrations in Elverum were highest during a cold period in January, second highest during a cold period in February, and lowest during a mild period between the two cold periods. The same variation was found for mutagenicity. The concentration at the site Elverum was considerably higher than at the site Stranfossen. Organic compounds characteristic of wood smoke have been found in the ambient particulate samples, especially on cold days. The concentration of total particulate carbon and carbon from biomass showed similar variations as fine particles and PAH. The average fraction of carbon from biomass relative to the total carbon concentration was 70 percent, and the fraction was highest on cold days. The average fraction corresponded quite well with an emission estimate of PAH giving an average PAH contribution from wood combustion of 60-70 percent in the winter season. The analyses of lead indicated a contribution of 3-6 percent from gasoline cars to the fine particle concentreration, which corresponds well with the emission estimate of PAH, giving an average PAH contribution from automobile traffic of 4-5 percent in the winter season. The study claerly indicates that the combustion of wood contrubutes significantly to the concentration of air pollutants in Elverum on cold days, especially fine particles, PAH and other carbonaceous compounds.

Environmental issues: New techniques for managing and using wood fuel ash

Energy Technology Data Exchange (ETDEWEB)

Fehrs, J.E.; Donovan, C.T. [C.T. Donovan Associates, Inc., Burlington, VT (United States)

1993-12-31

Continued research and development of environmentally-acceptable and cost-effective end uses for wood ash is having a significant affect on the ability to use wood and wood waste for fuel. This is particularly true for ash resulting from treated wood combustion. Concerns about the contents of ash from wood containing paint, stain, preservatives, or other chemicals is one of the largest regulatory barriers to its use as fuel. The purpose of this paper is to: (1) Identify the physical and chemical characteristics of ashes produced from the combustion of untreated and treated wood; (2) Explain the types of {open_quotes}clean, untreated{close_quotes} and {open_quotes}treated{close_quotes} wood that are likely to produce ash that can beneficially used; (3) Describe existing and potential products and end uses for untreated and treated wood ash.

The Spontaneous Combustion of Railway Ties and Asphalt Shingles

Science.gov (United States)

Leslie, Geoffrey

Many Low Carbon Fuels (LCFs) present unknown spontaneous combustion risks, which must be quantified before their use as fossil fuel replacements. Wood and coal spontaneous combustion is well understood; however, LCFs weather, and subsequent chemical changes could affect their spontaneous combustion properties. LCF spontaneous combustion could lead to accidental fires with possible loss of life, limb and property. The spontaneous combustion risks of two LCFs, discarded creosote-treated wooden railway ties and roofing asphalt shingles, were investigated with calorimetry and heat transfer experiments. Chemical changes due to weathering were studied with pyrolysis-Gas Chromatography/Mass Spectrometry (py-GC/MS). Creosote-treated wooden railway tie dust, roofing asphalt shingle particles, poplar wood pellets, and petroleum coke self-heating were studied with isothermal calorimetry. Railway tie dust and asphalt shingle heat transfer were characterized with a guarded hot plate. Petroleum coke self-heating was consistent with coal, while both poplar pellets and railway tie dust were found to be more reactive compared to oven test results of similar materials. The observed increase in reactivity was probably a result of significant moisture contenint in the pellet and railway tie dust. Critical conditions for spontaneous combustion were evaluated with the Frank-Kamenetskii parameter, assuming an ambient temperature of 40°C and constant moisture content. Kamenetskii calculations indicate that a 1.6 m cube of railway tie dust, or a 58 m cube of asphalt particles, would be unstable and combust. LCF chemistry may have been affected by weathering, which would cause chemical changes that affect their spontaneous combustion properties. Therefore, railway tie wood and roofing asphalt shingle chemistry were investigated by identifying products of 250° and 550°C pyrolysis with py-GC/MS. Railway tie wood pyrolyzates did not show signs of weathering; in contrast, asphalt pyrolysis

Full-scale Milling Tests of Wood Pellets for Combustion in a Suspension-Fired Power Plant Boiler

DEFF Research Database (Denmark)

Masche, Marvin; Puig Arnavat, Maria; Wadenbäck, Johan

The size reduction of pelletized wood is crucial in suspension-fired power plants, and hence its milling characteristics are of interest to optimize the milling and combustion process. The objective of the study was to compare the size and shape of pellets disintegrated in hot water with that from......), and analyzing the comminuted particle shape and particle size distribution (PSD). Large-scale pellet comminution produced finer and wider PSDs than pellet disintegration in hot water, but only slightly altered the particle shape. The mill pressure loss, absorbed mill power, and hence SGEC depended on the pellet...

Wood energy-commercial applications

Science.gov (United States)

Kennel, R. P.

1978-01-01

Wood energy is being widely investigated in many areas of the country because of the many obvious benefits of wood fuel such as the low price per million Btus relative to coal, oil, and gas; the wide availability of noncommercial wood and the proven ability to harvest it; established technology which is reliable and free of pollution; renewable resources; better conservation for harvested land; and the potential for jobs creation. The Southeastern United States has a specific leadership role in wood energy based on its established forest products industry experience and the potential application of wood energy to other industries and institutions. Significant questions about the widespread usage of wood energy are being answered in demonstrations around the country as well as the Southeast in areas of wood storage and bulk handling; high capitalization costs for harvesting and combustion equipment; long term supply and demand contracts; and the economic feasibility of wood energy outside the forest products industry.

Characterisation of ashes produced by co-combustion of recovered fuels and peat

Energy Technology Data Exchange (ETDEWEB)

Frankenhaeuser, M. [Borealis Polymers Oy, Porvoo (Finland)

1997-10-01

The current project focuses on eventual changes in ash characteristics during co-combustion of refuse derived fuel with coal, peat, wood or bark, which could lead to slagging, fouling and corrosion in the boiler. Ashes were produced at fluidised bed (FB) combustion conditions in the 15 kW reactor at VTT Energy, Jyvaeskylae, the fly ash captured by the cyclone was further analysed by XRF at Outokumpu Geotechnical Laboratory, Outokumpu. The sintering behaviour of these ashes was investigated using a test procedure developed at the Combustion Chemistry Research Group at Aabo Akademi University. The current extended programme includes a Danish refuse-derived fuel (RDF), co-combusted with bark/coal (5 tests) and wood/coal (2 tests), a RF from Jyvaskyla (2 tests with peat/coal) and de-inking sludges co- combusted at full-scale with wood waste or paper mill sludge (4 ashes provided by IVO Power). Ash pellets were thermally treated in nitrogen in order to avoid residual carbon combustion. The results obtained show no sintering tendencies below 600 deg C, significant changes in sintering are seen with pellets treated at 1000 deg C. Ash from 100 % RDF combustion does not sinter, 25 % RDF co-combustion with wood and peat, respectively, gives an insignificant effect. The most severe sintering occurs during co-combustion of RDF with bark. Contrary to the earlier hypothesis a 25 % coal addition seems to have a negative effect on all fuel blends. Analysis of the sintering results versus ash chemical composition shows, that (again), in general, an increased level of alkali chlorides and sulphates gives increased sintering. Finally, some results on sintering tendency measurements on ashes from full-scale CFB co-combustion of deinking sludge with wood waste and paper mill sludge are given. This shows that these ashes show very little, if any, sintering tendency, which can be explained from ash chemistry

Thermogravimetric analysis of combustible waste components

DEFF Research Database (Denmark)

Munther, Anette; Wu, Hao; Glarborg, Peter

In order to gain fundamental knowledge about the co-combustion of coal and waste derived fuels, the pyrolytic behaviors of coal, four typical waste components and their mixtures have been studied by a simultaneous thermal analyzer (STA). The investigated waste components were wood, paper, polypro......In order to gain fundamental knowledge about the co-combustion of coal and waste derived fuels, the pyrolytic behaviors of coal, four typical waste components and their mixtures have been studied by a simultaneous thermal analyzer (STA). The investigated waste components were wood, paper...

The case for wood-fuelled heating

International Nuclear Information System (INIS)

Bent, Ewan

2001-01-01

This article looks at the wood heating industry in the UK and examines the heat market and the growth potential in the domestic, public, agricultural and commercial sectors. The current status of wood-fueled heating technology is considered, along with log and chip boilers, and the use of pellet fuel. The economics of wood-fuelled heating, the higher level of utilisation of wood-fuelled heating by utilities in northern European countries compared with the UK, and the barriers to the exploitation of wood fuelled heating are examined

Guide for construction of wood power systems. Construction - economic efficiency - technology; Leitfaden fuer die Errichtung von Holzenergie-Anlagen. Umsetzung - Wirtschaftlichkeit - Technologie

Energy Technology Data Exchange (ETDEWEB)

Ruchser, M. [Forum fuer Zukunftsenergien e.V., Bonn (Germany)

2001-07-01

The Guidebook serves as a handbook for the entire operational sequence, which is necessary for the establishment of a wood combustion plant in Germany with an installed capacity larger than 100 kW{sub th}, for the use of fuel woods such as forest chips, wood and forest residues, pellets, wood waste, etc. within the limits of the laws and regulations prescribed for the respective performance classes. The Guidebook's purpose is to give potential investors and operators of wood combustion plants as well as the appropriate authorities a quick and global overview of the energetic use of wood in order to contribute to an increased application of this technology. The Guidebook introduces a Quality Model in Chapters 2 and 3, which describes the establishment of a wood combustion system in six phases. Eleven Management Aspects are differentiated, which can be helpful during the conversion of a project. Thus, potential investors and operators of wood combustion plants become acquainted with the most important aspects of this kind of project conversion. In addition, Chapter 4 provides an overview of the operating costs of wood combustion plants. The relevant licensing and planning procedures depending on the installed capacity and fuelwood use are comprehensively described in Chapter 5. Chapter 6 supplies a concrete overview of the environmental aspects and emissions of wood combustion. Since wood combustion plants must be - as all other investments - financially secured Chapter 7 provides a description of the relevant information on public means and subsidies. Besides all important promotion programmes, the new German Renewable Energy Law (Erneuerbare-Energien-Gesetz - EEG) of April 2000 is described in detail. Many examples of already realised wood combustion plant projects are described in Chapter 8. As an additional service, all significant addresses from ministries to energy agencies and associations are listed in Chapter 9. (orig.)

Particulate and gaseous emissions from residential biomass combustion

International Nuclear Information System (INIS)

Boman, Christoffer

2005-04-01

Biomass is considered to be a sustainable energy source with significant potentials for replacing electricity and fossil fuels, not at least in the residential sector. However, present wood combustion is a major source of ambient concentrations of hydrocarbons (e.g. VOC and PAH) and particulate matter (PM) and exposure to these pollutants have been associated with adverse health effects. Increased focus on combustion related particulate emissions has been seen concerning the formation, characteristics and implications to human health. Upgraded biomass fuels (e.g. pellets) provide possibilities of more controlled and optimized combustion with less emission of products of incomplete combustion (PICs). For air quality and health impact assessments, regulatory standards and evaluations concerning residential biomass combustion, there is still a need for detailed emission characterization and quantification when using different fuels and combustion techniques. This thesis summarizes the results from seven different papers. The overall objective was to carefully and systematically study the emissions from residential biomass combustion with respect to: i) experimental characterization and quantification, ii) influences of fuel, appliance and operational variables and iii) aspects of ash and trace element transformations and aerosol formation. Special concern in the work was on sampling, quantification and characterization of particulate emissions using different appliances, fuels and operating procedures. An initial review of health effects showed epidemiological evidence of potential adverse effect from wood smoke exposure. A robust whole flow dilution sampling set-up for residential biomass appliances was then designed, constructed and evaluated, and subsequently used in the following emission studies. Extensive quantifications and characterizations of particulate and gases emissions were performed for residential wood and pellet appliances. Emission factor ranges for

WOOD STOVE EMISSIONS: PARTICLE SIZE AND CHEMICAL COMPOSITION

Science.gov (United States)

The report summarizes wood stove particle size and chemical composition data gathered to date. [NOTE: In 1995, EPA estimated that residential wood combustion (RWC), including fireplaces, accounted for a significant fraction of national particulate matter with aerodynamic diameter...

Energy wood. Part 2b: Wood pellets and pellet space-heating systems; Holzenergie Teil 2b: Holzpellets und Pelletheizungen / Energie du bois Partie 2b: Granules de bois et installations de chauffage a granules de bois

Energy Technology Data Exchange (ETDEWEB)

Nussbaumer, T. [Verenum, Zuerich (Switzerland)

2002-07-01

The paper gives an overview on pellet utilization including all relevant process steps: Potential and properties of saw dust as raw material, pellet production with drying and pelletizing, standardization of wood pellets, storage and handling of pellets, combustion of wood pellets in stoves and boilers and applications for residential heating. In comparison to other wood fuels, wood pellets show several advantages: Low water content and high heating value, high energy density, and homogeneous properties thus enabling stationary combustion conditions. However, quality control is needed to ensure constant properties of the pellets and to avoid the utilization of contaminated raw materials for the pellet production. Typical data of efficiencies and emissions of pellet stoves and boilers are given and a life cycle analysis (LCA) of wood pellets in comparison to log wood and wood chips is described. The LCA shows that wood pellets are advantageous thanks to relatively low emissions. Hence, the utilization of wood pellet is proposed as a complementary technology to the combustion of wood chips and log wood. Finally, typical fuel cost of wood pellets in Switzerland are given and compared with light fuel oil. (author)

Technologies for the commercial energetic utilisation of waste wood and used wood; Technologien zur energetischen Nutzung von Holzabfaellen und Gebrauchsholz im gewerblichen Bereich

Energy Technology Data Exchange (ETDEWEB)

Marutzky, R.

1998-12-31

Due to the frequent contamination of wood with wood preservatives, coatings, adhesives, paints and other non-wood materials the conversion of production residues and various types of used wood to energy appears to be fraught with problems. However, extensive studies conducted during the past years have shown that most problems regarding combustion residues and emissions have been overestimated. Thanks to new technologies it is now possible to avoid or at least reduce the formation of pollutants during combustion of even complexly contaminated waste wood. Environmentally acceptable combustion of wood presupposes complete combustion, effective dedusting, and primary measures for nitrogen oxide control. Depending on the type of feedstock and the relevant emission limit values one may optionally include secondary nitric oxides removal measures and control techniques for partially volatile heavy metals and halocarbons. Moreover, firing plants must be so conditioned as to keep the new synthesis of dioxins at a low level. [Deutsch] Die energetische Verwertung von Produktionsabfaellen und Gebrauchtholzsortimenten scheint wegen der haeufig vorhandenen Belastung der Hoelzer mit Holzschutzmitteln, Oberflaechenbeschichtungen, Klebstoffen, Farbanstrichen und andere holzfremden Bestandteilen schwierig zu sein. Tatsaechlich sind - wie umfangreiche Untersuchungen der letzten Jahre gezeigt haben - die meisten Probleme in Hinblick auf Ausbrand und Emissionen ueberschaetzt worden. Durch Weiterentwicklung von Anlagen- und Regelungstechnik ist es heute moeglich, die Schadstoffbildung bei der Verbrennung auch komplex belasteter Holzabfaelle zu vermeiden oder zu vermindern. Voraussetzungen einer umweltvertraeglichen Verbrennung von Holz sind - ein guter Ausbrand, - eine effektive Entstaubung, - und primaere Massnahmen der Stickstoffoxidminderung. Optional kommen je nach Brennstoff und Emissionsgrenzwert noch sekundaere Entstickungsmassnahmen und Minderungstechniken fuer partiell

Emissions of toxic pollutants from co-combustion of demolition and construction wood and household waste fuel blends.

Science.gov (United States)

Edo, Mar; Ortuño, Núria; Persson, Per-Erik; Conesa, Juan A; Jansson, Stina

2018-07-01

Four different types of fuel blends containing demolition and construction wood and household waste were combusted in a small-scale experimental set-up to study the effect of fuel composition on the emissions of polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs), biphenyls (PCBs), chlorobenzenes (PCBzs), chlorophenols (PCPhs) and polycyclic aromatic hydrocarbons (PAHs). Two woody materials, commercial stemwood (ST) and demolition and construction wood (DC) were selected because of the differences in their persistent organic pollutants (POPs), ash and metals content. For household waste, we used a municipal solid waste (MSW) and a refuse-derived fuel (RDF) from MSW with 5-20 wt% and up to 5 wt% food waste content respectively. No clear effect on the formation of pollutants was observed with different food waste content in the fuel blends tested. Combustion of ST-based fuels was very inefficient which led to high PAH emissions (32 ± 3.8 mg/kg fuel ). The use of DC clearly increased the total PCDD and PCDF emissions (71 ± 26 μg/kg fuel ) and had a clear effect on the formation of toxic congeners (210 ± 87 ng WHO 2005 -TEQ/kg fuel ). The high PCDD and PCDF emissions from DC-based fuels can be attributed to the presence of material contaminants such as small pieces of metals or plastics as well as timber treated with chromated copper arsenate preservatives and pentachlorophenol in the DC source. Copyright © 2018 Elsevier Ltd. All rights reserved.

Estimated health impact of a shift from light fuel to residential wood-burning in Upper Austria.

Science.gov (United States)

Haluza, Daniela; Kaiser, August; Moshammer, Hanns; Flandorfer, Claudia; Kundi, Michael; Neuberger, Manfred

2012-07-01

The dependency on carbon-based fossil energy and growing awareness of climate change issues has induced ambitious policy initiatives to promote renewable energy sources for indoor heating. Combustion of regionally available material such as wood is considered a carbon-neutral alternative for oil and gas, but unregulated revival of wood stoves may cause detrimental health effects. For the prognosis of the health impact of air pollution due to the use of wood stoves, Upper Austria served for a case study. On the basis of recent measurements of particulate matter fuel oil by either fossil gas or biomass, and for scenario 3, replacement of light fuel oil by biomass only. Compared with the current exposure from scenario 1, the increased annual mean PM10 levels are estimated to lead to 101 (95% CI 56;146) and 174 (95% CI 92;257) additional deaths among 1.4 million inhabitants per year for scenarios 2 and 3, respectively. Without adequate strategies for reducing the emissions of domestic heating facilities, replacement of fossil energy sources could lead to an increased health risk.

Effects of Operating Conditions and Dusty Fuel on the NOx, N2O and CO Emissions in PFB Co-Combustion of Coal and Wood

Czech Academy of Sciences Publication Activity Database

Svoboda, Karel; Pohořelý, Michael; Hartman, Miloslav

2003-01-01

Roč. 17, č. 4 (2003), s. 1091-1099 ISSN 0887-0624 R&D Projects: GA AV ČR IAA4072801 Institutional research plan: CEZ:AV0Z4072921 Keywords : pressurized fluidized bed * co-combustion * wood Subject RIV: JE - Non-nuclear Energetics, Energy Consumption ; Use Impact factor: 1.303, year: 2003

Emissions from laboratory combustor tests of manufactured wood products

Energy Technology Data Exchange (ETDEWEB)

Wilkening, R.; Evans, M.; Ragland, K. [Univ. of Wisconsin, Madison, WI (United States); Baker, A. [USDA Forest Products Lab., Madison, WI (United States)

1993-12-31

Manufactured wood products contain wood, wood fiber, and materials added during manufacture of the product. Manufacturing residues and the used products are burned in a furnace or boiler instead of landfilling. Emissions from combustion of these products contain additional compounds from the combustion of non-wood material which have not been adequately characterized to specify the best combustion conditions, emissions control equipment, and disposal procedures. Total hydrocarbons, formaldehyde, higher aldehydes and carbon monoxide emissions from aspen flakeboard and aspen cubes were measured in a 76 mm i.d. by 1.5 m long fixed bed combustor as a function of excess oxygen, and temperature. Emissions of hydrocarbons, aldehydes and CO from flakeboard and from clean aspen were very sensitive to average combustor temperature and excess oxygen. Hydrocarbon and aldehyde emissions below 10 ppM were achieved with 5% excess oxygen and 1,200{degrees}C average temperature for aspen flakeboard and 1,100{degrees}C for clean aspen at a 0.9 s residence time. When the average temperature decreased below these levels, the emissions increased rapidly. For example, at 950{degrees}C and 5% excess oxygen the formaldehyde emissions were over 1,000 ppM. These laboratory tests reinforce the need to carefully control the temperature and excess oxygen in full-scale wood combustors.

Furniture wood wastes: Experimental property characterisation and burning tests

International Nuclear Information System (INIS)

Tatano, Fabio; Barbadoro, Luca; Mangani, Giovanna; Pretelli, Silvia; Tombari, Lucia; Mangani, Filippo

2009-01-01

Referring to the industrial wood waste category (as dominant in the provincial district of Pesaro-Urbino, Marche Region, Italy), this paper deals with the experimental characterisation and the carrying out of non-controlled burning tests (at lab- and pilot-scale) for selected 'raw' and primarily 'engineered' ('composite') wood wastes. The property characterisation has primarily revealed the following aspects: potential influence on moisture content of local weather conditions at outdoor wood waste storage sites; generally, higher ash contents in 'engineered' wood wastes as compared with 'raw' wood wastes; and relatively high energy content values of 'engineered' wood wastes (ranging on the whole from 3675 to 5105 kcal kg -1 for HHV, and from 3304 to 4634 kcal kg -1 for LHV). The smoke qualitative analysis of non-controlled lab-scale burning tests has primarily revealed: the presence of specific organic compounds indicative of incomplete wood combustion; the presence exclusively in 'engineered' wood burning tests of pyrroles and amines, as well as the additional presence (as compared with 'raw' wood burning) of further phenolic and containing nitrogen compounds; and the potential environmental impact of incomplete industrial wood burning on the photochemical smog phenomenon. Finally, non-controlled pilot-scale burning tests have primarily given the following findings: emission presence of carbon monoxide indicative of incomplete wood combustion; higher nitrogen oxide emission values detected in 'engineered' wood burning tests as compared with 'raw' wood burning test; and considerable generation of the respirable PM 1 fraction during incomplete industrial wood burning.

Effects of combustion and operating conditions on PCDD/PCDF emissions from power boilers burning salt-laden wood waste.

Science.gov (United States)

Leclerc, Denys; Duo, Wen Li; Vessey, Michelle

2006-04-01

This paper discusses the effects of combustion conditions on PCDD/PCDF emissions from pulp and paper power boilers burning salt-laden wood waste. We found no correlation between PCDD/PCDF emissions and carbon monoxide emissions. A good correlation was, however, observed between PCDD/PCDF emissions and the concentration of stack polynuclear aromatic hydrocarbons (PAHs) in the absence of TDF addition. Thus, poor combustion conditions responsible for the formation of products of incomplete combustion (PICs), such as PAHs and PCDD/PCDF precursors, increase PCDD/PCDF emissions. PAH concentrations increased with higher boiler load and/or low oxygen concentrations at the boiler exit, probably because of lower available residence times and insufficient excess air. Our findings are consistent with the current understanding that high ash carbon content generally favours heterogeneous reactions leading to either de novo synthesis of PCDD/PCDFs or their direct formation from precursors. We also found that, in grate-fired boilers, a linear increase in the grate/lower furnace temperature produces an exponential decrease in PCDD/PCDF emissions. Although the extent of this effect appears to be mill-specific, particularly at low temperatures, the results indicate that increasing the combustion temperature may decrease PCDD/PCDF emissions. It must be noted, however, that there are other variables, such as elevated ESP and stack temperatures, a high hog salt content, the presence of large amounts of PICs and a high Cl/S ratio, which contribute to higher PCDD/PCDFs emissions. Therefore, higher combustion temperatures, by themselves, will not necessarily result in low PCDD/PCDFs emissions.

Differences between co-cultures and monocultures in testing the toxicity of particulate matter derived from log wood and pellet combustion

Science.gov (United States)

Happo, Mikko S.; Rönkkö, Teemu J.; Orasche, Jürgen; Jokiniemi, Jorma; Kortelainen, Miika; Tissari, Jarkko; Zimmermann, Ralf; Hirvonen, Maija-Riitta; Jalava, Pasi I.

2018-01-01

Background In vitro studies with monocultures of human alveolar cells shed deeper knowledge on the cellular mechanisms by which particulate matter (PM) causes toxicity, but cannot account for mitigating or aggravating effects of cell-cell interactions on PM toxicity. Methods We assessed inflammation, oxidative stress as well as cytotoxic and genotoxic effects induced by PM from the combustion of different types of wood logs and softwood pellets in three cell culture setups: two monocultures of either human macrophage-like cells or human alveolar epithelial cells, and a co-culture of these two cell lines. The adverse effects of the PM samples were compared between these setups. Results We detected clear differences in the endpoints between the mono- and co-cultures. Inflammatory responses were more diverse in the macrophage monoculture and the co-culture compared to the epithelial cells where only an increase of IL-8 was detected. The production of reactive oxygen species was the highest in epithelial cells and macrophages seemed to have protective effects against oxidative stress from the PM samples. With no metabolically active cells at the highest doses, the cytotoxic effects of the PM samples from the wood log combustion were far more pronounced in the macrophages and the co-culture than in the epithelial cells. All samples caused DNA damage in macrophages, whereas only beech and spruce log combustion samples caused DNA damage in epithelial cells. The organic content of the samples was mainly associated with cytotoxicity and DNA damage, while the metal content of the samples correlated with the induction of inflammatory responses. Conclusions All of the tested PM samples induce adverse effects and the chemical composition of the samples determines which pathway of toxicity is induced. In vitro testing of the toxicity of combustion-derived PM in monocultures of one cell line, however, is inadequate to account for all the possible pathways of toxicity. PMID

Pollution-free combustion of waste wood in Swiss joineries

Energy Technology Data Exchange (ETDEWEB)

NONE

1994-12-31

The exploitation of scrap wood for heat generation in the wood processing industry makes sense not only in the context of energy conservation but also on environmental grounds. Existing energy requirements can be provided by renewable energy sources, relieving the burden on the public waste disposal facility. The wood-fired heating plant for a joinery in Pratteln, Switzerland consumes 150 to 180 tonnes of waste wood per year, enabling approximately 80 tonnes of heating oil to be saved. The heat produced is used in a local scheme to heat the joinery and adjacent housing. A new fibrous filter system for the retention of fine particles was installed, enabling the particle concentration in the exhaust to be reduced from 292 mg/m{sup 3} to 24 mg/m{sup 3}. (UK)

Discover the benefits of residential wood heating

International Nuclear Information System (INIS)

2003-01-01

This publication described how residential wood-heating systems are being used to reduce energy costs and increase home comfort. Biomass energy refers to all forms are renewable energy that is derived from plant materials. The source of fuel may include sawmills, woodworking shops, forest operations and farms. The combustion of biomass is also considered to be carbon dioxide neutral, and is not considered to be a major producer of greenhouse gases (GHG) linked to global climate change. Wood burning does, however, release air pollutants, particularly if they are incompletely burned. Incomplete combustion of wood results in dense smoke consisting of toxic gases. Natural Resources Canada helped create new safety standards and the development of the Wood Energy Technical Training Program to ensure that all types of wood-burning appliances are installed correctly and safely to reduce the risk of fire and for effective wood heating. In Canada, more than 3 million families heat with wood as a primary or secondary heating source in homes and cottages. Wood heating offers security from energy price fluctuations and electrical power failures. This paper described the benefits of fireplace inserts that can transform old fireplaces into modern heating systems. It also demonstrated how an add-on wood furnace can be installed next to oil furnaces to convert an oil-only heating system to a wood-oil combination system, thereby saving thousands of dollars in heating costs. Wood pellet stoves are another wood burning option. The fuel for the stoves is produced from dried, finely ground wood waste that is compressed into hard pellets that are loaded into a hopper. The stove can run automatically for up to 24 hours. New high-efficiency advanced fireplaces also offer an alternative heating system that can reduce heating costs while preserving Canada's limited supply of fossil fuels such as oil and gas. 13 figs

Formation and emission of PM10 in combustion of biofuels. Final report

International Nuclear Information System (INIS)

Johansson, Linda; Tullin, Claes; Leckner, Bo

2004-02-01

Epidemiological studies have shown correlations between negative health effects and increased particle concentrations in the ambient air. Because of this correlation and the increasing biofuel combustion, there is a need to more carefully investigate formation and emissions from biofuel combustion to secure good air quality in the future. This project is limited to primary combustion particles emitted from small-scale biofuel combustion. Small-scale is here defined as combustion devices with an output less than 10 MW. The project is divided into two parts. In the first part, particles from small-scale biofuel combustion have been characterised. In the second part, the formation of particles during biofuel combustion is studied. Characterisation of particle emissions has been performed for a range of different combustion units, i.e. pellet stove with a thermal output of a few kW, domestic wood and pellet boilers and district-heating boilers with thermal outputs around 2 MW. Mass concentration of particles was measured according to Swedish Standard method. Particle mass size distribution was measured using Dekati Low Pressure Impactor (DLPI, size range 30 nm - 10 μm). The number of particles and corresponding size distribution were measured with an Electrical Low Pressure Impactor (ELPI, 30 nm - 10 μm). To some extent, the particle emissions were investigated regarding chemical content and morphology. In all measurement cases, gas concentrations were measured in the flue gas as a control of combustion conditions. The highest mass concentration of particles (2,200 mg/MJ fuel ) was recorded in the flue gas from an old domestic wood log boiler with poor combustion conditions resulting in very high emissions of unburnt (soot). On the other hand, the lowest mass concentration of particles (20 mg/MJ fueI ) was recorded during optimally adjusted pellet combustion, where 83 % of the particles were found to be inorganic. The remaining part consists of unburnt material (e

Firing with wood chips in heating and cogeneration plants

International Nuclear Information System (INIS)

Kofman, P.D.

1992-01-01

The document was produced for use as detailed teaching material aimed at spreading information on the use of wood chips as fuel for heating and cogeneration plants. It includes information and articles on wood fuels generally, combustion values, chopping machines, suppliers, occupational health hazards connected with the handling of wood chips, measuring amounts, the selection of types, prices, ash, environmental aspects and information on the establishment of a wood-chip fired district heating plant. (AB)

CFD modeling and experience of waste-to-energy plant burning waste wood

DEFF Research Database (Denmark)

Rajh, B.; Yin, Chungen; Samec, N.

2013-01-01

Computational Fluid Dynamics (CFD) is being increasingly used in industry for in-depth understanding of the fundamental mixing, combustion, heat transfer and pollutant formation in combustion processes and for design and optimization of Waste-to-Energy (WtE) plants. In this paper, CFD modeling...... the conversion of the waste wood in the fuel bed on the grate, which provides the appropriate inlet boundary condition for the freeboard 3D CFD simulation. The CFD analysis reveals the detailed mixing and combustion characteristics in the waste wood-fired furnace, pinpointing how to improve the design...

Combustion of Corn Stover Bales in a Small 146-kW Boiler

Directory of Open Access Journals (Sweden)

Joey Villeneuve

2011-07-01

Full Text Available Spring harvested corn stover was used for direct combustion in a 146 kW dual chamber boiler designed for wood logs. Stover had a very low moisture content (6.83 ± 0.17%, a gross calorific value (GCV of 18.57 MJ/kg of dry matter (±0.32 MJ/kg DM and an ash content of 5.88% (±1.15%. Small stover bales (8.83 ± 0.90 kg were placed manually in the upper combustion chamber at a rate of 10.5 to 12.8 kg/h over a 24-h period, with three replications, and compared to a control wood combustion trial (12.1 kg/h during 24 h. The overall heat transfer efficiency for stover was lower than for wood (57% vs. 77%. Stover bales produced on average 7.5% ash which included about 2% of unburned residues while wood produced 1.7% ash. CO gas emissions averaged 1324 mg/m³ for stover (118 mg/m³ for wood. The corn stover showed a good calorific potential, but it would have to be densified and the boiler should be modified to improve airflow, completeness of combustion and handling of the large amount of ash formed.

Biomass is beginning to threaten the wood-processors

International Nuclear Information System (INIS)

Beer, G.; Sobinkovic, B.

2004-01-01

In this issue an exploitation of biomass in Slovak Republic is analysed. Some new projects of constructing of the stoke-holds for biomass processing are published. The grants for biomass are ascending the prices of wood raw material, which is thus becoming less accessible for the wood-processors. An excessive wood export threatens the domestic processors

Yearbook 1998. TULISIJA Research Programme for Wood Firing Technology; Vuosikirja - Aarsbok 1997. TULISIJA

Energy Technology Data Exchange (ETDEWEB)

Ljung, M.; Kilpinen, P. [eds.

1999-11-01

TULISIJA is the 3-year national research programme for small scale wood firing technology with the aim to assist manufacturers in their efforts to develop the most emission-free, yet efficient, wood firing equipment in the world. The following ten projects have been in progress during the year 1998: The behaviour of fuel; Computational fluid dynamics simulation of combustion in small scale wood ovens; computational fluid dynamics simulation of combustion in small scale wood ovens and modelling of emission chemistry; Modelling of heat transfer in fireplace walls and constructions; Detailed emission and temperature measurements in the TULISIJA test oven; Measurement environment for fireplace testing; Reduction of emissions from soapstone fireplaces; Development of a new modular method for fireplace manufacture; Replacement of energy intensive raw material with recycled industrial waste and further development of combustion processes in fireplaces and Instructions for dimensioning and design of fireplaces for optimum living atmosphere in residences

Danish emission inventories for stationary combustion plants

DEFF Research Database (Denmark)

Nielsen, Malene; Nielsen, Ole-Kenneth; Plejdrup, Marlene Schmidt

Emission inventories for stationary combustion plants are presented and the methodologies and assumptions used for the inventories are described. The pollutants considered are SO2, NOx, NMVOC, CH4, CO, CO2, N2O, NH3, particulate matter, heavy metals, PCDD/F, HCB and PAH. The CO2 emission in 2011...... of decreased emissions from large power plants and waste incineration plants. The combustion of wood in residential plants has increased considerably until 2007 resulting in increased emission of PAH and particulate matter. The emission of NMVOC has increased since 1990 as a result of both the increased...... combustion of wood in residential plants and the increased emission from lean-burn gas engines. The PCDD/F emission decreased since 1990 due to flue gas cleaning on waste incineration plants....

Antioxidant airway responses following experimental exposure to wood smoke in man

Directory of Open Access Journals (Sweden)

Sehlstedt Maria

2010-08-01

Full Text Available Abstract Background Biomass combustion contributes to the production of ambient particulate matter (PM in rural environments as well as urban settings, but relatively little is known about the health effects of these emissions. The aim of this study was therefore to characterize airway responses in humans exposed to wood smoke PM under controlled conditions. Nineteen healthy volunteers were exposed to both wood smoke, at a particulate matter (PM2.5 concentration of 224 ± 22 μg/m3, and filtered air for three hours with intermittent exercise. The wood smoke was generated employing an experimental set-up with an adjustable wood pellet boiler system under incomplete combustion. Symptoms, lung function, and exhaled NO were measured over exposures, with bronchoscopy performed 24 h post-exposure for characterisation of airway inflammatory and antioxidant responses in airway lavages. Results Glutathione (GSH concentrations were enhanced in bronchoalveolar lavage (BAL after wood smoke exposure vs. air (p = 0.025, together with an increase in upper airway symptoms. Neither lung function, exhaled NO nor systemic nor airway inflammatory parameters in BAL and bronchial mucosal biopsies were significantly affected. Conclusions Exposure of healthy subjects to wood smoke, derived from an experimental wood pellet boiler operating under incomplete combustion conditions with PM emissions dominated by organic matter, caused an increase in mucosal symptoms and GSH in the alveolar respiratory tract lining fluids but no acute airway inflammatory responses. We contend that this response reflects a mobilisation of GSH to the air-lung interface, consistent with a protective adaptation to the investigated wood smoke exposure.

Environmental assessment of wood burning in independent heating devices

International Nuclear Information System (INIS)

Rogaume, C.; Rogaume, Y.; Zoulalian, A.; Trouve, G.

2009-01-01

An environmental assessment has been achieved on two domestic wood-heating devices, a closed fireplace and an open fireplace which represent 80% of the sale market of wood small-scale combustion units and around 65% of the use of wood-energy in France. Not only deals this study with the atmospheric polluting emissions produced in the exhaust stack, but also with the indoor air quality. Therefore, different pollutants were measured at the emission stage and as indoor air concentrations: carbon monoxide (CO), carbon dioxide (CO 2 ), volatile organic compounds (VOC), methane (CH 4 ), nitrogen oxides (NO X ), particulate matter with different sizes (PM 10 to PM 0.1 ), polycyclic aromatic hydrocarbons (PAH) and dioxines and furans. The results concerning indoor air were compared to measurements that showed the influence of residential heating devices. without exhaust duct like an oil stove or a gas stove (space heater) on indoor air quality. Some combustion emission experiments achieved in normal conditions showed that the combustion in open fireplace pollutes more than the combustion in closed fire-place: around 10 times more of PM 2.5 (mass concentration), more than 4 times of total VOC, 1.5 times more of dioxines and furans. On the other hand, the opposite trend was shown for PAH emissions (between 2 and 3 times less depending on the regulations considered). The comparison of the impact of different heating appliances on indoor air quality shows that the rate of CO is the same for all the devices except for the open fireplace which is higher. The CO 2 rate is 10 times higher for the oil stove and 8 times higher for the gas stove than for the fireplaces, which is due to the lack of exhaust duct. The concentration of PM 2.5 is 16 times higher for the open fireplace, 1.6 times higher for the oil stove and 4.4 times higher for the gas stove than the closed fireplace. The percentage of the number distribution of nano-particles, that represents an enhanced health risk

An emissions audit of a biomass combustor burning treated wood waste

International Nuclear Information System (INIS)

Jackson, P.M.; Jones, H.H.; King, P.G.

1993-01-01

This report describes the Emissions Audit carried out on a Biomass Combustor burning treated wood waste at the premises of a furniture manufacturer. The Biomass Combustor was tested in two firing modes; continuous fire and modulating fire. Combustion chamber temperatures and gas residence times were not measured. Boiler efficiencies were very good at greater than 75% in both tests. However, analysis of the flue gases indicated that improved efficiencies are possible. The average concentrations of CO (512mgm -3 ) and THC (34mgm -3 ) for Test 1 were high, indicating that combustion was poor. The combustor clearly does not meet the requirements of the Guidance Note for the Combustion of Wood Waste. CO 2 and O 2 concentrations were quite variable showing that combustion conditions were fairly unstable. Improved control of combustion should lead to acceptable emission concentrations. (Author)

The use of wood waste for energy production

International Nuclear Information System (INIS)

Karlopoulos, E.; Pavloudakis, F.

1999-01-01

The paper presents some technical aspects and management issues of wood waste reuse end disposal. It refers to the Greek and European legislation which determines the framework for rational and environmental friendly practices for woos waste management. It refers also to the wood waste classification systems and the currently applied methods of wood waste disposal and reuse. Emphasis is given to the wood waste-to-energy conversion system, particularly to the pretreatment requirements, the combustion techniques, and the environmental constrains. Finally, the decision making process for the investments in the wood waste firing thermal units is discussed

Stationary Engineers Apprenticeship. Related Training Modules. 16.1-16.5 Combustion.

Science.gov (United States)

Lane Community Coll., Eugene, OR.

This learning module, one in a series of 20 related training modules for apprentice stationary engineers, deals with combustion. Addressed in the individual instructional packages included in the module are the following topics: the combustion process, types of fuel, air and flue gases, heat transfer during combustion, and wood combustion. Each…

Hazardous emissions, operating practices, and air regulations at industrial wood-fired facilities in Wisconsin

International Nuclear Information System (INIS)

Hubbard, A.J.

1993-01-01

Since October of 1988 the State of Wisconsin Department of Natural Resources has regulated over four hundred substances as hazardous air pollutants. The rule regulates new as well as existing sources of air pollution in Wisconsin. Consequently, all permits to operate an air pollution source in Wisconsin must address the hazardous air emissions potential of the source. While widely perceived as a clean-burning fuel, wood is often burned in a manner which clearly results in significant emissions of very hazardous air pollutants. Research conducted on a 20 million BTU per hour wood-fired spreader stoker boiler in northern Wisconsin showed that this boiler has the potential to emit 0.022 pound of benzene and 0.012 pound of formaldehyde per ton (lb/ton) of wood fired. Recent stack tests at more than a dozen other small industrial wood-fired facilities in Wisconsin show a range of formaldehyde emissions of 0.0007--0.1950 lb/ton. Work at Birchwood Lumber ampersand Veneer showed that the benzene and formaldehyde emission rates under good firing conditions are an order of magnitude lower than the benzene and formaldehyde emission rates under poor firing conditions. This finding has supported Wisconsin's regulatory approach of encouraging wood-fired facilities to enhance the quality of the combustion process as a technique to minimize the hazardous air pollution potential of industrial wood combustion. The Wisconsin strategy is to define open-quotes good combustion technologyclose quotes through easily measurable combustion parameters rather than emission standards. This paper presents several techniques in use in Wisconsin to comply with open-quotes good combustion technologyclose quotes for industrial wood-fired furnaces. These techniques include fuel blending overfire air, furnace insulation, and proper grate design

Chimney emissions from small-scale burning of pellets and fuelwood - examples referring to different combustion appliances

International Nuclear Information System (INIS)

Kjaellstrand, Jennica; Olsson, Maria

2004-01-01

Most wood boilers used for residential heating today are old-fashioned and emit large quantities of organic compounds. The installation of a pellet burner and a change to wood pellets as fuel normally decreases the emissions remarkably. In this study, the emissions from different equipment for burning of wood and pellets are compared. The organic fraction of smoke from traditional wood burning is to a great extent composed of methoxyphenols, with antioxidant effects. Methoxyphenols were also identified in smoke from pellet stoves. A fuel wood boiler or a furnace with an inserted pellet burner is heated to a higher combustion temperature, decreasing the total amount of organic compounds in the smoke. Above 800 deg C, methoxyphenols are thermally decomposed and carcinogenic polycyclic aromatic compounds (PACs) are formed. The combustion-formed aromatic hydrocarbon benzene is present in smoke from all kinds of burning, but the proportion relative to primary organic compounds increases with increasing combustion temperature. In smoke from an environmentally labelled wood boiler and from some pellet burning devices, the levels of PAC and benzene were found to be low. Evidently, the combustion was nearly complete. Although the change from wood to pellets significantly decreases the emissions, considerable differences exist between various combinations of pellet burners and boiler furnaces. (Author)

Research into properties of dust from domestic central heating boiler fired with coal and solid biofuels

Directory of Open Access Journals (Sweden)

Konieczyński Jan

2017-06-01

Full Text Available The aim of this research was to assess the content and composition of the pollutants emitted by domestic central heating boilers equipped with an automatic underfeed fuel delivery system for the combustion chamber. The comparative research was conducted. It concerned fuel properties, flue gas parameters, contents of dust (fl y ash and gaseous substances polluting the air in the flue gases emitted from a domestic CH boiler burning bituminous coal, pellets from coniferous wood, cereal straw, miscanthus, and sunflower husks, coniferous tree bark, and oats and barley grain. The emission factors for dust and gaseous air pollutants were established as they are helpful to assess the contribution of such boilers in the atmospheric air pollution. When assessing the researched boiler, it was found out that despite the development in design and construction, flue gases contained fly ash with a significant EC content, which affected the air quality.

78 FR 30329 - Multilayered Wood Flooring from China

Science.gov (United States)

2013-05-22

...)] Multilayered Wood Flooring from China AGENCY: United States International Trade Commission. ACTION: Notice of...-1179 (Final) concerning multilayered wood flooring (``MLWF'') from China. For further information... reconsider ``its decision not to investigate domestic producers of hardwood plywood used for flooring'' 2. to...

Numerical modeling of combustion of low-calorific-producer-gas from Mangium wood within a late mixing porous burner (LMPB

Directory of Open Access Journals (Sweden)

Kanokkarn Jirakulsomchok

2017-08-01

Full Text Available This article presents a numerical study of combustion of low-calorific-producer-gas from Mangium wood within a late mixing porous burner (LMPB. The LMPB consists of four main components, i.e., the fuel preheating porous (FP, the porous combustor (PC, the air jacket, and the mixing chamber. Interestingly, this LMPB was able to highly preheated and it still maintained high safety in operation. A single-step global reaction, steady state approach and a one-dimensional model were considered. The necessary information for burner characteristics, i.e., temperature profile, flame location and maximum temperature were also presented. The results indicated that stable combustion of a low-calorific-producer-gas within LMPB was possible achieved. Increasing equivalence ratio resulted in increasing in the flame temperature. Meanwhile, increasing the firing rate caused slightly decrease in flame temperature. The flame moved to downstream zone of the PC when the firing rate increased. Finally, it was found that the equivalence ratio did not affect the flame location.

2000-2006 National Wood Energy Programme. 2000-2005 Activities Report

International Nuclear Information System (INIS)

2006-01-01

2005 was marked by key decisions which were taken with the aim of developing the biomass sector as a substitute for fossil fuels. Indeed, to achieve the ambitious objectives for renewable sources of energy set out by the July 2005 Energy Policy Orientation Programme (POPE), we must make great use of biomass, particularly to increase by 50% the share of renewable thermal energy between now and 2010 and to enable biofuels to represent 7% of all fuels used at the same date. To a lesser extent, and in conjunction with heat production, the share of biomass in renewable electricity production also needs to rise. Both the resource and key supply players are there and are ready to get organised in order to rise to these challenges. There is an abundant supply of agricultural and forest by-products. More than sixty companies organise and deliver heating wood. More than 300 government and professional promotion, regulatory, PR, finance, equipment construction and operation, research and engineering organizations are involved in this market. The strategic and economic context is highly favourable in the light of laws, directives and international agreements aiming to combat greenhouse gas emissions, but also due to the structural pressure on the price of fossil fuels. Wood energy, as a renewable energy source, has an important role to play in this context of growth. Furthermore, the wood energy sector should be developed using an exemplary sustainable development approach, which means that all the economic, social and environmental effects are taken into account. In order to comprehensively assess the sector's environmental impact, a full chapter of this report presents the work and programmes set up by ADEME to reduce pollutant emissions produced by biomass combustion, particularly from private households. Moreover, consultation and dialogue between those involved must be widened in order to enable all wood users to benefit from 'best forest use' which will be a key

Bio-energy in the wood processing industry. Manual for energy production from residual matter for the wood processing industry

International Nuclear Information System (INIS)

Van Halen, C.J.G.; Arninkhof, M.J.C.; Rommens, P.J.M.; Karsch, P.

2000-04-01

This manual is published within the framework of a project, financed by Novem (EWAB programme) and the European Commission (Altener programme). Similar manuals were drafted in Germany, England and Sweden. The basis of the project was the manual 'Quality manual for small-scale wood incineration and wood gasification', published by Novem in 1998. That quality manual was drafted on the basis of an evaluation of a number of wood combustion and wood gasification projects. The original manual has been improved as a result of comments made by experts in the field of bio-energy. Updated information was added with respect to legislation, financing options and new technology. Also the manual is focused more on the wood processing industry

Air pollution from wood combustion. Measurements at Elverum, Norway during the winters 1981 and 1982. Luftforurensning fra vedfyring. Maalinger i Elverum, Norge vintrene 1981 og 1982

Energy Technology Data Exchange (ETDEWEB)

Ramdahl, T; Schjoldager, J; Hanssen, J E; Moeller, M

1983-01-01

Ambient sampling and analysis of air pollutants related to wood combustion have been carried out at the town of Elverum, Norway during the winters of 1981 and 1982. Two measurement sites were selected, Elverum (within the town) and Strandfossen. The concentration of fine particles, PAH and benzene on cold days in Elverum was similar to average winter concentrations in central parts of Oslo. The concentrations in Elverum were highest during a cold period in January, second highest during a cold period in February, and lowest during a mild period between the two cold periods. The same variation was found for mutagenicity. The concentration at the site Elverum was considerably higher than at the site Stranfossen. Organic compounds characteristic of wood smoke have been found in the ambient particulate samples, especially on cold days. The concentration of total particulate carbon and carbon from biomass showed similar variations as fine particles and PAH. The average fraction of carbon from biomass relative to the total carbon concentration was 70 percent, and the fraction was highest on cold days. The average fraction corresponded quite well with an emission estimate of PAH giving an average PAH contribution from wood combustion of 60-70 percent in the winter season. The analyses of lead indicated a contribution of 3-6 percent from gasoline cars to the fine particle concentreration.

Intelligent Heat System - High-Energy Efficient Wood Stoves with Low Emissions. Emissions of Gases and Particles

DEFF Research Database (Denmark)

Illerup, Jytte Boll; Hansen, Brian Brun; Lin, Weigang

2015-01-01

performance has been verified by field tests in private homes. The main components of an Autopilot IHS wood stove are: a modern wood stove with three separate combustion air inlets, and a control system composing of measuring devices for vital process parameters and a system of controlling valves to regulate...... combustion charges and phases. The experiments showed that the digital control of the combustion process ensures constant and optimal temperatures and overall oxygen concentrations in the combustion chamber resulting in low PM and CO emissions.......A collaboration project between the CHEC research Centre, at DTU Chemical Engineering, and the stove manufacturing company HWAM A/S has been established during the last years and has led to development and marketing of wood stoves (Autopilot IHS) equipped with a digital control system. The improved...

Chapter 5: Organopollutant Degradation by Wood Decay Basidiomycetes

Science.gov (United States)

Yitzhak Hadar; Daniel Cullen

2013-01-01

Wood decay fungi are obligate aerobes, deriving nutrients from the biological ‘combustion’ of wood, using molecular oxygen as terminal electron acceptor (Kirk and Farrell 1987; Blanchette 1991). Non-specific extracellular enzymes are generally viewed as key components in lignin depolymerization. The major enzymes implicated in lignin degradation are lignin peroxidase (...

Biomass equipments. The wood-fueled heating plants; Materiels pour la biomasse. Les chaudieres bois

Energy Technology Data Exchange (ETDEWEB)

Chieze, B. [SA Compte R, 63 - Arlanc (France)

1997-12-31

This paper analyzes the consequences of the classification of biomass fuels in the French 2910 by-law on the classification of biomass-fueled combustion installations. Biomass fuels used in such installations must be only wood wastes without any treatment or coating. The design of biomass combustion systems must follow several specifications relative to the fueling system, the combustion chamber, the heat exchanger and the treatment of exhaust gases. Other technical solutions must be studied for other type of wood wastes in order to respect the environmental pollution laws. (J.S.)

Wood energy barometer. 43 million toe produced in 2003

International Nuclear Information System (INIS)

Anon.

2004-01-01

The use of wood in the form of energy contributes in fighting global warming since, unlike fossil energies, the carbon dioxide emitted by its combustion is reabsorbed by the forests. These environmental and energetic advantages explain why the European Union large wood countries are preparing programmes to develop both wood energy technologies and wood energy consumption; This document takes stock or gives information on the breakdown of valorization of wood energy origin primary energy, the gross electricity generation from wood energy in the 15 european union countries and Poland, the primary energy from wood energy, the comparative between different wood energy fuel prices in Europe, the number of direct and indirect job created in different sectors, the wood energy sector industrialists and a comparison between current trend and white paper objectives. (A.L.B.)

Signal correlations in biomass combustion. An information theoretic analysis

Energy Technology Data Exchange (ETDEWEB)

Ruusunen, M.

2013-09-01

Increasing environmental and economic awareness are driving the development of combustion technologies to efficient biomass use and clean burning. To accomplish these goals, quantitative information about combustion variables is needed. However, for small-scale combustion units the existing monitoring methods are often expensive or complex. This study aimed to quantify correlations between flue gas temperatures and combustion variables, namely typical emission components, heat output, and efficiency. For this, data acquired from four small-scale combustion units and a large circulating fluidised bed boiler was studied. The fuel range varied from wood logs, wood chips, and wood pellets to biomass residue. Original signals and a defined set of their mathematical transformations were applied to data analysis. In order to evaluate the strength of the correlations, a multivariate distance measure based on information theory was derived. The analysis further assessed time-varying signal correlations and relative time delays. Ranking of the analysis results was based on the distance measure. The uniformity of the correlations in the different data sets was studied by comparing the 10-quantiles of the measured signal. The method was validated with two benchmark data sets. The flue gas temperatures and the combustion variables measured carried similar information. The strongest correlations were mainly linear with the transformed signal combinations and explicable by the combustion theory. Remarkably, the results showed uniformity of the correlations across the data sets with several signal transformations. This was also indicated by simulations using a linear model with constant structure to monitor carbon dioxide in flue gas. Acceptable performance was observed according to three validation criteria used to quantify modelling error in each data set. In general, the findings demonstrate that the presented signal transformations enable real-time approximation of the studied

Deposition of biomass combustion aerosol particles in the human respiratory tract.

Science.gov (United States)

Löndahl, Jakob; Pagels, Joakim; Boman, Christoffer; Swietlicki, Erik; Massling, Andreas; Rissler, Jenny; Blomberg, Anders; Bohgard, Mats; Sandström, Thomas

2008-08-01

Smoke from biomass combustion has been identified as a major environmental risk factor associated with adverse health effects globally. Deposition of the smoke particles in the lungs is a crucial factor for toxicological effects, but has not previously been studied experimentally. We investigated the size-dependent respiratory-tract deposition of aerosol particles from wood combustion in humans. Two combustion conditions were studied in a wood pellet burner: efficient ("complete") combustion and low-temperature (incomplete) combustion simulating "wood smoke." The size-dependent deposition fraction of 15-to 680-nm particles was measured for 10 healthy subjects with a novel setup. Both aerosols were extensively characterized with regard to chemical and physical particle properties. The deposition was additionally estimated with the ICRP model, modified for the determined aerosol properties, in order to validate the experiments and allow a generalization of the results. The measured total deposited fraction of particles from both efficient combustion and low-temperature combustion was 0.21-0.24 by number, surface, and mass. The deposition behavior can be explained by the size distributions of the particles and by their ability to grow by water uptake in the lungs, where the relative humidity is close to saturation. The experiments were in basic agreement with the model calculations. Our findings illustrate: (1) that particles from biomass combustion obtain a size in the respiratory tract at which the deposition probability is close to its minimum, (2) that particle water absorption has substantial impact on deposition, and (3) that deposition is markedly influenced by individual factors.

Comparison of neighborhood-scale residential wood smoke emissions inventories using limited and intensive survey data

International Nuclear Information System (INIS)

Baxter, T.E.

1998-01-01

Emission inventory based estimations of pollutants resulting from residential combustion of wood are typically determined by collecting survey data that represent a single but relatively large area. While the pollutants in wood smoke emissions may represent a relatively low fraction (<10%) of an area's total annual emissions mass inventory, they can concentrate within the specific neighborhood areas where emitted. Thus, while the representativeness of a large-area survey approach is valid and useful, its application for estimating wood smoke pollutant levels within any particular neighborhood may be limited. The ability to obtain a better estimation of pollutant levels for evaluating potential health-related impacts within neighborhoods where wood smoke pollutants can concentrate requires survey data more representative of the particular area. This study compares residential wood combustion survey data collected from six residential neighborhoods in the metropolitan area of Flagstaff, Arizona. The primary purpose of this study is to determine the ability of data collected from a limited neighborhood-scale survey effort to represent that neighborhood's wood fuel consumption characteristics and wood smoke emissions. In addition, the variation that occurs between different neighborhoods regarding residential consumption of wood is also evaluated. Residential wood combustion survey data were collected compare wood burning device distribution, wood types and quantities burned, and emission rates. One neighborhood was surveyed once at approximately a 10% distribution rate and again at a 100% distribution rate providing data for evaluating the ability of a limited-effort survey to represent a more intensive survey. Survey methodology, results and recommendations are presented

Wood pellets offer a competitive energy option in Sweden

International Nuclear Information System (INIS)

2001-01-01

The market for wood pellets in Sweden grew rapidly during the 1990s and production now stands at around 550,000 tonnes/year. More efficient combustion technology, pellet transportation, pellet storage and pellet delivery have also been developed. The pellets, which are produced by some 25 plants, are used in family houses, large-scale district heating plants, and combined heat and power (CHP) plants. Most of the pellets are made from biomass resources such as forest residues and sawdust and shavings from wood mills. Pellet production, the energy content of saw mill by-products, the current market and its potential for future expansion, the way in which the pellets are used in different combustion systems, the theoretical market potential for wood pellet heating installations in small houses and the Swedish P-certificate system for the certification of pellet stoves and burners are described

Health effects engineering: Perspectives for environmental health and environmental engineering studies-domestic biomass combustion as an example

International Nuclear Information System (INIS)

Gao Xiang; Yu Qi; Chen Limin

2007-01-01

Health effects engineering (HEE) is a newly developed research field, which involves collaboration with environmental scientists, engineering researchers, and toxicologists. By employing the methods of HEE, one can not only confirm which attributes of the project are likely to contribute to certain health effects, but can also get rid of the adverse health effects by engineering technologies. HEE is thought to be particularly important to domestic projects in which there is a lack of environmental assessment. This paper presented the authors' viewpoints of the principles of HEE in the field of the environmental health and engineering studies by using programs of domestic biomass combustion as an example. The authors showed that there are three sub-fields of HEE, which are as follows: engineering behavior, the pollution characteristics, and the health effects. The authors conclude that the principles of HEE compose a helix with the studies in the fields of environmental science, health, and engineering, and give suggestions on how to perform HEE in a practical field

Combustion Aerosols from Full-Scale Suspension-Firing of Wood Pellets

DEFF Research Database (Denmark)

Damø, Anne Juul; Wu, Hao; Frandsen, Flemming

2012-01-01

The objectives of the present work were to investigate the aerosol formation mechanisms during full-scale suspension firing of wood, and, to evaluate the effect of coal fly ash addition on the formation of aerosols under different ash load conditions. Tests with suspension firing of 100 % wood...

Wood supply at the edge of the world

DEFF Research Database (Denmark)

Pinta, Elie; Baittinger, Claudia

Wood used in construction and boat building, in domestic productions or as a fuel resource was a key material for medieval North European societies. For people living in Medieval Scandinavia, trees and timber were common in both landscapes and mythology and therefore essential cultural items...... is to present the current research on the identification of wood species (both local and imported) used by European settlers in Greenland. An analysis of wood will help us to understand and retrace the origin and circulation of wood resources in the Norse settlements. What was the nature of woodworking...

Particle Emissions from Biomass Combustion

Energy Technology Data Exchange (ETDEWEB)

Szpila, Aneta; Bohgard, Mats [Lund Inst. of Technology (Sweden). Div. of Ergonomics and Aerosol Technology; Strand, Michael; Lillieblad, Lena; Sanati, Mehri [Vaexjoe Univ. (Sweden). Div. of Bioenergy Technology; Pagels, Joakim; Rissler, Jenny; Swietlicki, Erik; Gharibi, Arash [Lund Univ. (Sweden). Div. of Nuclear Physics

2003-05-01

We have shown that high concentrations of fine particles of the order of 2-7x10{sup -7} particles per cm{sup 3} are being formed in all the combustion units studied. There was a higher difference between the units in terms of particle mass concentrations. While the largest differences was found for gas-phase constituents (CO and THC) and polyaromatic hydrocarbons. In 5 out of 7 studied units, multi-cyclones were the only measure for flue-gas separation. The multicyclones had negligible effect on the particle number concentration and a small effect on the mass of particles smaller than 5 {mu}m. The separation efficiency was much higher for the electrostatic precipitators. The boiler load had a dramatic influence on the coarse mode concentration during combustion of forest residue. PM0.8-6 increased from below 5 mg/m{sup 3} to above 50 mg/m{sup 3} even at a moderate change in boiler load from medium to high. A similar but less pronounced trend was found during combustion of dry wood. PM0.8-PM6 increased from 12 to 23 mg/m{sup 3} when the load was changed from low to high. When increasing the load, the primary airflow taken through the grate is increased; this itself may lead to a higher potential of the air stream to carry coarse particles away from the combustion zone. Measurements with APS-instrument with higher time-resolution showed a corresponding increase in coarse mode number concentration with load. Additional factor influencing observed higher concentration of coarse mode during combustion of forest residues, could be relatively high ash content in this type of fuel (2.2 %) in comparison to dry wood (0.3 %) and pellets (0.5 %). With increasing load we also found a decrease in PM1 during combustion of forest residue. Whether this is caused by scavenging of volatilized material by the high coarse mode concentration or a result of a different amount of volatilized material available for formation of fine particles needs to be shown in future studies. The

Fire extinguishing strength of the combustion product of wood saw ...

African Journals Online (AJOL)

Forty saw dust samples from four mature hard wood plants grown in southwestern part of Nigeria were analyzed for their ash contents, moisture contents, metallic contents and hence the fire extinguishing strength of the saw dust ash by classical and instrumental methods of analyses. Mahogany (Khaya ivorensis) wood saw ...

Semivolatile and Volatile Organic Compound Emissions from Wood-Fired Hydronic Heaters

Science.gov (United States)

Four commercially available HH technologies were studied: a single-stage combustor with natural updraft, a three-stage downdraft combustion system, a bottom-fed pellet burner, and a two-stage heater with both a combustion and gasification chamber. The fuel consisted of three wood...

Integration of Thermoelectric Generators and Wood Stove to Produce Heat, Hot Water, and Electrical Power

Science.gov (United States)

Goudarzi, A. M.; Mazandarani, P.; Panahi, R.; Behsaz, H.; Rezania, A.; Rosendahl, L. A.

2013-07-01

Traditional fire stoves are characterized by low efficiency. In this experimental study, the combustion chamber of the stove is augmented by two devices. An electric fan can increase the air-to-fuel ratio in order to increase the system's efficiency and decrease air pollution by providing complete combustion of wood. In addition, thermoelectric generators (TEGs) produce power that can be used to satisfy all basic needs. In this study, a water-based cooling system is designed to increase the efficiency of the TEGs and also produce hot water for residential use. Through a range of tests, an average of 7.9 W was achieved by a commercial TEG with substrate area of 56 mm × 56 mm, which can produce 14.7 W output power at the maximum matched load. The total power generated by the stove is 166 W. Also, in this study a reasonable ratio of fuel to time is described for residential use. The presented prototype is designed to fulfill the basic needs of domestic electricity, hot water, and essential heat for warming the room and cooking.

Impact of operating wood-burning fireplace ovens on indoor air quality.

Science.gov (United States)

Salthammer, Tunga; Schripp, Tobias; Wientzek, Sebastian; Wensing, Michael

2014-05-01

The use of combustion heat sources like wood-burning fireplaces has regained popularity in the past years due to increasing energy costs. While the outdoor emissions from wood ovens are strictly regulated in Germany, the indoor release of combustion products is rarely considered. Seven wood burning fireplaces were tested in private homes between November 2012 and March 2013. The indoor air quality was monitored before, during and after operation. The following parameters were measured: ultra-fine particles (5.6-560 nm), fine particles (0.3-20 μm), PM2.5, NOx, CO, CO2, formaldehyde, acetaldehyde, volatile organic compounds (VOCs) and benzo[a]pyrene (BaP). Most ovens were significant sources of particulate matter. In some cases, an increase of benzene and BaP concentrations was observed in the indoor air. The results illustrate that wood-burning fireplaces are potential sources of indoor air contaminants, especially ultra-fine particles. Under the aspect of lowering indoor air exchange rates and increasing the use of fuels with a net zero-carbon footprint, indoor combustion sources are an important topic for the future. With regards to consumer safety, product development and inspection should consider indoor air quality in addition to the present fire protection requirements. Copyright © 2013 Elsevier Ltd. All rights reserved.

ALS annual report 2005 - Main issue 5: 5. IVD colloquium on wood burning - systems management for the future. Fine dust reduction, condensing boiler technology, storage heaters. Contributions

International Nuclear Information System (INIS)

2005-01-01

This proceedings volume contains the papers presented at the 18th colloquium of the Stuttgart University WG on air pollution abatement, which was held jointly with the 5th Stuttgart wood furnaces colloquium this year. This was a good combination as wood has high relevance for air pollution abatement: On the one hand, wood as a fuel will reduce CO2 emissions, improve air quality and save resources. On the other hand, wood combustion may cause fine dust emissions, unpleasant smells and other side effects of incomplete combustion, especially in small furnaces. Fine dust emissions were characterized and future requirements on biomass combustion defined. After this, strategies for optimum design and construction, modern off-gas treatment technologies, high-efficiency combustion technologies, flameless combustion, and efficient combinations of wood furnaces and heat stores were gone into. The utilisation of pellets from cereals and straw was mentioned as well. (orig.)

Experimental Study on Dry Torrefaction of Beech Wood and Miscanthus

Directory of Open Access Journals (Sweden)

Eyerusalem M. Gucho

2015-05-01

Full Text Available Torrefaction is a thermochemical pre-treatment process for upgrading the properties of biomass to resemble those of fossil fuels such as coal. Biomass properties of particular interest are chemical composition, physical property and combustion characteristics. In this work, torrefaction of beech wood and miscanthus (sinensis was carried out to study the influence of torrefaction temperature (240–300 °C and residence time (15–150 min on the aforementioned properties of the biomass. Results of the study revealed that torrefaction temperature has a significant influence on mass and energy yields, whereas the influence of the residence time becomes more apparent for the higher torrefaction temperatures (>280 °C. Torrefied miscanthus resulted in higher energy densification compared to beech wood for a residence time of 30 min. A significant improvement in grindability of the torrefied beech wood was obtained even for lightly torrefied beech wood (at 280 °C and 15 min of residence time. Observation from the combustion study showed that the ignition temperature is slightly affected by the torrefaction temperature. As a whole, the torrefaction temperature determines the characteristics of the torrefied fuel compared to other process parameters like residence time. Furthermore, with optimal process conditions, torrefaction produces a solid fuel with combustion reactivity and porosity comparable to raw biomass, whereas grindability and heating value are comparable to low quality coal.

Recycling of wood for particle board production: accounting of greenhouse gases and global warming contributions

DEFF Research Database (Denmark)

Merrild, Hanna Kristina; Christensen, Thomas Højlund

2009-01-01

of virgin wood does not change the results radically (—665 to —125 kg CO2-equivalents tonne— 1 wood waste). However, if in addition it is assumed that the GHG emissions from combustion of wood has no global warming potential (GWP) and that the energy produced from excess wood due to recycling substitutes...

Effects of backing board materials on wood combustion performance

Science.gov (United States)

Mathew J. Hagge; Kenneth M. Bryden; Mark A. Dietenberger

2004-01-01

Cone calorimeter tests show that backing board materials do not affect the ignition time, initial heat release rate, or the total heat released of combustion for redwood slabs. However, it has been observed that backing board materials alter combustion performance by altering the secondary heat release peak observed when the pyrolysis reaction front nears the unheated...

Effects of chlorine and sulphur on particle formation in wood combustion performed in a laboratory scale reactor

Energy Technology Data Exchange (ETDEWEB)

Olli Sippula; Terttaliisa Lind; Jorma Jokiniemi [University of Kuopio, Kuopio (Finland). Fine Particle and Aerosol Technology Laboratory, Department of Environmental Sciences

2008-09-15

Fine particle formation in wood combustion was studied in a laboratory scale laminar flow reactor at various flue gas chlorine and sulphur concentrations. Aerosol samples were quenched at around 850{sup o}C using a porous tube diluter. Fine particle number concentrations, mass concentrations, size distributions and chemical compositions were measured. In addition, flue gas composition, including SO{sub 2} and HCl, was monitored. Experimental results were interpreted by thermodynamic equilibrium calculations. Addition of HCl clearly raised fine particle mass concentration (PM1.0) which was because of increased release of ash-forming material to fine particles. Especially the release of K, Na, Zn and Cd to fine particles increased. These species form chlorides which apparently increases their volatilization from the fuel. When a sufficient amount of SO{sub 2} was supplied in a chlorine rich combustion (S/Cl molar ratio from 4.7 to 7.5), most of the HCl stayed in the gas phase, release of ash-forming elements decreased and also fine particle concentrations dropped significantly. The sulphation of alkali metals is suggested to play a key role in the observed decrease in the fine particle concentration. It seems that the formation of sulphates leads to alkali metal retention in the coarse particle fraction. 27 refs., 11 figs., 1 tab.

Electrodialytic removal of Cd from biomass combustion fly ash suspensions

DEFF Research Database (Denmark)

Kirkelund, Gunvor M.; Ottosen, Lisbeth M.; Damoe, Anne J.

2013-01-01

was investigated with the aim of enabling reuse of the ashes. The ashes originated from combustion of straw (two ashes), wood chips, and co-firing of wood pellets and fuel oil, respectively. A series of laboratory scale electrodialytic remediation experiments were conducted with each ash. The initial Cd...

Expression of adhesion molecules, monocyte interactions and oxidative stress in human endothelial cells exposed to wood smoke and diesel exhaust particulate matter

DEFF Research Database (Denmark)

Forchhammer, Lykke; Loft, Steffen; Roursgaard, Martin

2012-01-01

Toxicological effects of wood smoke particles are less investigated than traffic-related combustion particles. We investigated the effect of wood smoke particles, generated by smouldering combustion conditions, on human umbilical endothelial cells (HUVECs) co-cultured with or without monocytic TH...

Particulate emissions from the combustion of birch, beech, and spruce logs cause different cytotoxic responses in A549 cells.

Science.gov (United States)

Kasurinen, Stefanie; Jalava, Pasi I; Happo, Mikko S; Sippula, Olli; Uski, Oskari; Koponen, Hanna; Orasche, Jürgen; Zimmermann, Ralf; Jokiniemi, Jorma; Hirvonen, Maija-Riitta

2017-05-01

According to the World Health Organization particulate emissions from the combustion of solid fuels caused more than 110,000 premature deaths worldwide in 2010. Log wood combustion is the most prevalent form of residential biomass heating in developed countries, but it is unknown how the type of wood logs used in furnaces influences the chemical composition of the particulate emissions and their toxicological potential. We burned logs of birch, beech and spruce, which are used commonly as firewood in Central and Northern Europe in a modern masonry heater, and compared them to the particulate emissions from an automated pellet boiler fired with softwood pellets. We determined the chemical composition (elements, ions, and carbonaceous compounds) of the particulate emissions with a diameter of less than 1 µm and tested their cytotoxicity, genotoxicity, inflammatory potential, and ability to induce oxidative stress in a human lung epithelial cell line. The chemical composition of the samples differed significantly, especially with regard to the carbonaceous and metal contents. Also the toxic effects in our tested endpoints varied considerably between each of the three log wood combustion samples, as well as between the log wood combustion samples and the pellet combustion sample. The difference in the toxicological potential of the samples in the various endpoints indicates the involvement of different pathways of toxicity depending on the chemical composition. All three emission samples from the log wood combustions were considerably more toxic in all endpoints than the emissions from the pellet combustion. © 2016 Wiley Periodicals, Inc. Environ Toxicol 32: 1487-1499, 2017. © 2016 Wiley Periodicals, Inc.

Ash-forming elements in four Scandinavian wood species part 3: Combustion of five spruce samples

Energy Technology Data Exchange (ETDEWEB)

Werkelin, Johan; Lindberg, Daniel; Skrifvars, Bengt-Johan; Hupa, Mikko [Aabo Akademi Process Chemistry Centre, Piispankatu 8, FI-20500 Turku (Finland); Bostroem, Dan [Energy Technology and Thermal Process Chemistry, Umeaa University, SE-901 87 Umeaa (Sweden)

2011-01-15

Forest residue is the remaining fraction after the outtake of timber, which comprises the tree tops and branches. It may as fuel cause damage to the combustion device through ash slagging and fouling. The objective of this work was to model the ash composition from well-specified samples of a spruce tree: wood, bark, twigs, needles, and shoots. Their ash at 1000 C was modelled using global chemical equilibrium calculations, and laboratory-made ash of the five samples was analyzed by XRD and SEM-EDXA. According to the results, the risk of slagging arises from the spruce foliage: molten alkali silicates from spruce needles and probably molten alkali phosphates from spruce shoots may cause problems in the furnace. Fouling caused by condensing alkali vapours can be produced by all five samples. The amount of alkali vapours in the flue gas was in the same order of magnitude for all five samples, in spite of large differences in their original alkali contents. (author)

Granulated wood ash to forest soil - Ecological effects

International Nuclear Information System (INIS)

Rosen, K.; Eriksson, H.; Clarholm, M.; Lundkvist, H.; Rudebeck, A.

1993-01-01

This report describes research concerning ecological effects of wood ash recycling to forest soils. The main part of the minerals in the wood fuels are retained in the ashes after combustion. By returning the ashes back to the cleared forest areas, the mineral losses can be reduced. Adding ashes and limestone is a method to vitalize acidified forest soils and restore the production capacity. 48 refs, 26 figs, 8 tabs

Kinetics of gasification and combustion of residues, biomass and coal in a bubbling fluidized bed; Die Kinetik der Vergasung und Verbrennung unterschiedlicher Abfaelle, Biomassen und Kohlen in der blasenbildenden Wirbelschicht

Energy Technology Data Exchange (ETDEWEB)

Hamel, S; Krumm, W [Siegen Univ. (Gesamthochschule) (Germany). Lehrstuhl fuer Energie- und Umweltverfahrenstechnik

1998-09-01

The combustion and gasification characteristics of Rhenish brown coal, domestic waste, waste plastics, wood and sewage sludge were investigated in a bubbling atmospheric fluidized bed in the laboratory scale. The materials were pyrolyzed in the fluidized bed in a nitrogen atmosphere. The residual coke was combuted in the presence of oxygen with varying operating parameters or else gasified in the presence of carbon dioxide. The different materials were characterized by global combustion rates, and kinetic parameters were determined for residual coke combustion. (orig.) [Deutsch] Das Verbrennungs- und Vergasungsverhalten von Rheinischer Braunkohle, Hausmuell, Restkunststoff, Holz und Klaerschlamm wurde in einer blasenbildenden, atmosphaerischen Laborwirbelschicht untersucht. Die Einsatzstoffe wurden in der mit Stickstoff fluidisierten Wirbelschicht pyrolysiert. Der verbleibende Restkoks wurde anschliessend unter Variation der Betriebsparameter mit Sauerstoff verbrannt oder mit Kohlendioxid vergast. Die unterschiedlichen Einsatzstoffe wurden durch globale Vebrennungsraten charakterisiert. Fuer die Restkoksverbrennung wurden kinetische Parameter ermittelt. (orig.)

Combustion characterization of rape seed meal and suggestions for optimal use in combustion appliances; Foerbraenningskarakterisering av rapsmjoel och foerslag till optimalt nyttjande i olika foerbraenningsanlaeggningar

Energy Technology Data Exchange (ETDEWEB)

Eriksson, Gunnar; Hedman, Henry; Oehman, Marcus; Bostroem, Dan; Pettersson, Esbjoern; Pommer, Linda; Lindstroem, Erica; Backman, Rainer; Oehman, Rikard

2007-12-15

When rape oil is chemically extracted, rape seed meal, a solid residue remains. Currently, it is used as animal feed. Several plants for the production of rape methyl ester (RME, biodiesel) are in operation or under construction. Combustion properties have been studied for rape seed meal produced as a by product to rape-methyl esther (RME, biodiesel). Composition of the material has been measured, using proximate and ultimate analysis. The lower heating value was 18.2 +- 0.3 MJ/kg d.w. and the ash content was 7-8 percent d.w. The material is rich in nitrogen and sulphur. Concentrations of K, P, Ca and Mg are high in the fuel. Rape seed meal was mixed with bark and pelletised. Bark pellets were also used as a reference fuel. Pellets with 10 and 30 percent rape seed meal were produced. Material with 80 percent rape seed meal and 20 percent planer shavings was also pelletised. Wood had to be added to provide enough friction in the pelletising process, with adapted equipment rape seed meal could probably be easily pelletised). The material was studied using Thermo-Gravimetric Analysis (TGA), and compared with data from tests with wood powder. The pyrolysis of the rape seed meal has a characteristic temperature of 320 deg C. Devolatilisation starts at 150 deg C (at a lower temperature than for wood powder), and proceeds within a rather wide temperature range. The probable cause is the difference in organic content, in particular protein content. The result does not suggest that the material will be difficult to ignite. Experiments in a bench-scale fluidised bed (5 kW) showed that pellets containing only bark, and the mixture rape seed meal/wood had a bed agglomeration temperature well over the normal operational bed temperature. For the fuel mixtures rape seed meal and bark, the agglomeration temperature was slightly over the operational temperature. Particle emissions from fluidised bed combustion and grate combustion were, the latter simulated using a commercial

Thermogravimetric investigation on the degradation properties and combustion performance of bio-oils.

Science.gov (United States)

Ren, Xueyong; Meng, Jiajia; Moore, Andrew M; Chang, Jianmin; Gou, Jinsheng; Park, Sunkyu

2014-01-01

The degradation properties and combustion performance of raw bio-oil, aged bio-oil, and bio-oil from torrefied wood were investigated through thermogravimetric analysis. A three-stage process was observed for the degradation of bio-oils, including devolatilization of the aqueous fraction and light compounds, transition of the heavy faction to solid, and combustion of carbonaceous residues. Pyrolysis kinetics parameters were calculated via the reaction order model and 3D-diffusion model, and combustion indexes were used to qualitatively evaluate the thermal profiles of tested bio-oils for comparison with commercial oils such as fuel oils. It was found that aged bio-oil was more thermally instable and produced more combustion-detrimental carbonaceous solid. Raw bio-oil and bio-oil from torrefied wood had comparable combustion performance to fuel oils. It was considered that bio-oil has a potential to be mixed with or totally replace the fuel oils in boilers. Copyright © 2013 Elsevier Ltd. All rights reserved.

Combustion Characteristics of Torrefied Wood Samples of Pinus Carrebea and Leucaena Leucocephala Grown in Nigeria

Directory of Open Access Journals (Sweden)

Francis Akinyele FARUWA

2016-12-01

Full Text Available Torrefaction of selected wood samples of Pinus Carrebea and Leucaena Leucocephala were carried out at temperatures ranging from 200 to 300°C to improve the energy parameters of biomass and to determine the effect of torrefication temperature on the physical and combustion properties of wood selected from Pinus carrebea and Leuceanea leucocephala grown in Nigeria. In this process the biomass hemicellulose is degraded, maintaining its cellulose and lignin content. The samples were dried and heated to 225, 250, 275, and 300°C. Then the torrefied mass was subjected to basic property testing on proximate analysis and heating value was calculated in order to understand the differences between raw material and its torrefied products. Specifically, the wood blocks changed from light brown to black, stemming from the partial carbonization at the wood surface. When the temperature is 225°C, the color of the wood is between dark brown and once the torrefaction temperatures are 250 and 275°C, the colors of the wood become dark and darker respectively. The results of the proximate analysis also showed that increasing of torrefied temperature; volatile fraction was reduced while fixed carbon was increased with increase in temperature from 21.34 to 52.74 and 18.58 to 56.83 for Leucaena leucocephala and Pinus carreabeanus respectively at 225 to 300°C. The volatile content is decreased from 78.58% to 62.76% with increase in temperature. Ash content of were within 1.57-3.41% of torrefied wood. It could be observed that the High calorific value (HCV for pine ranged between 19.80 and 28.06MJ/Kg for the top, 19.93and 24.96MJ/kg for middle with 19.72and 25.96MJ/Kg for base. The values recorded for raw sample and at 275°C been the lowest and highest respectively. The High calorific value (HCV were found to be on the increase and nose dive at 300°C for the tree parts used in this research. The result revealed that for Leuceana the value increased from raw up to

COMBUSTION CHARACTERISTICS OF TORREFIED WOOD SAMPLES OF PINUS CARREBEA AND LEUCAENA LEUCOCEPHALA GROWN IN NIGERIA

Directory of Open Access Journals (Sweden)

Joseph Adeola FUWAPE

2016-12-01

Full Text Available Torrefaction of selected wood samples of Pinus Carrebea and Leucaena Leucocephala were carried out at temperatures ranging from 200 to 300°C to improve the energy parameters of biomass and to determine the effect of torrefication temperature on the physical and combustion properties of wood selected from Pinus carrebea and Leuceanea leucocephala grown in Nigeria. In this process the biomass hemicellulose is degraded, maintaining its cellulose and lignin content. The samples were dried and heated to 225, 250, 275, and 300°C. Then the torrefied mass was subjected to basic property testing on proximate analysis and heating value was calculated in order to understand the differences between raw material and its torrefied products. Specifically, the wood blocks changed from light brown to black, stemming from the partial carbonization at the wood surface. When the temperature is 225°C, the color of the wood is between dark brown and once the torrefaction temperatures are 250 and 275°C, the colors of the wood become dark and darker respectively. The results of the proximate analysis also showed that increasing of torrefied temperature; volatile fraction was reduced while fixed carbon was increased with increase in temperature from 21.34 to 52.74 and 18.58 to 56.83 for Leucaena leucocephala and Pinus carreabeanus respectively at 225 to 300°C. The volatile content is decreased from 78.58% to 62.76% with increase in temperature. Ash content of were within 1.57-3.41% of torrefied wood. It could be observed that the High calorific value (HCV for pine ranged between 19.80 and 28.06MJ/Kg for the top, 19.93and 24.96MJ/kg for middle with 19.72and 25.96MJ/Kg for base. The values recorded for raw sample and at 275°C been the lowest and highest respectively. The High calorific value (HCV were found to be on the increase and nose dive at 300°C for the tree parts used in this research. The result revealed that for Leuceana the value increased from raw up to

Handling of corn stover bales for combustion in small and large furnaces

Energy Technology Data Exchange (ETDEWEB)

Morissette, R.; Savoie, P.; Villeneuve, J. [Agriculture and Agri-Food Canada, Quebec City, PQ (Canada)

2010-07-01

This paper reported on a study in which dry corn stover was baled and burned in 2 furnaces in the province of Quebec. Small and large rectangular bale formats were considered for direct combustion. The first combustion unit was a small 500,000 BTU/h dual chamber log wood furnace located at a hay growing farm in Neuville, Quebec. The heat was initially transferred to a hot water pipe system and then transferred to a hot air exchanger to dry hay bales. The small stover bales were placed directly into the combustion furnace. The low density of the bales compared to log wood, required filling up to 8 times more frequently. Stover bales produced an average of 6.4 per cent ash on a DM basis and required an automated system for ash removal. Combustion gas contained levels of particulate matter greater than 1417 mg/m{sup 3}, which is more than the local acceptable maximum of 600 mg/m{sup 3} for combustion furnaces. The second combustion unit was a high capacity 12.5 million BTU/h single chamber furnace located in Saint-Philippe-de-neri, Quebec. It was used to generate steam for a feed pellet mill. Large corn stover bales were broken up and fed on a conveyor and through a screw auger to the furnace. The stover was light compared to the wood chips used in this furnace. For mechanical reasons, the stover could not be fed continuously to the furnace.

Does replacing coal with wood lower CO2 emissions? Dynamic lifecycle analysis of wood bioenergy

Science.gov (United States)

Sterman, John D.; Siegel, Lori; Rooney-Varga, Juliette N.

2018-01-01

Bioenergy is booming as nations seek to cut their greenhouse gas emissions. The European Union declared biofuels to be carbon-neutral, triggering a surge in wood use. But do biofuels actually reduce emissions? A molecule of CO2 emitted today has the same impact on radiative forcing whether it comes from coal or biomass. Biofuels can only reduce atmospheric CO2 over time through post-harvest increases in net primary production (NPP). The climate impact of biofuels therefore depends on CO2 emissions from combustion of biofuels versus fossil fuels, the fate of the harvested land and dynamics of NPP. Here we develop a model for dynamic bioenergy lifecycle analysis. The model tracks carbon stocks and fluxes among the atmosphere, biomass, and soils, is extensible to multiple land types and regions, and runs in ≈1s, enabling rapid, interactive policy design and sensitivity testing. We simulate substitution of wood for coal in power generation, estimating the parameters governing NPP and other fluxes using data for forests in the eastern US and using published estimates for supply chain emissions. Because combustion and processing efficiencies for wood are less than coal, the immediate impact of substituting wood for coal is an increase in atmospheric CO2 relative to coal. The payback time for this carbon debt ranges from 44-104 years after clearcut, depending on forest type—assuming the land remains forest. Surprisingly, replanting hardwood forests with fast-growing pine plantations raises the CO2 impact of wood because the equilibrium carbon density of plantations is lower than natural forests. Further, projected growth in wood harvest for bioenergy would increase atmospheric CO2 for at least a century because new carbon debt continuously exceeds NPP. Assuming biofuels are carbon neutral may worsen irreversible impacts of climate change before benefits accrue. Instead, explicit dynamic models should be used to assess the climate impacts of biofuels.

Domestic Wood Products Manufacturing Trends and Factors to Enhance Competitiveness

Science.gov (United States)

Urs Buehlmann; Matthew Bumgardner; Albert Schuler; Rich Christianson; Rich Christianson

2003-01-01

There is little question that imports have captured a substantial portion of the domestic furniture market. However, there is much speculation and concern as to the future of this and related industries. This study sought to obtain industry perspectives of trends in domestic manufacturing and importing, and to identify factors that can enhance domestic competitiveness...

FIRE RESISTANCE OF DOUGLAS FIR [Pseudotsuga menziesii (Mirb. Franco] WOOD TREATED WITH SOME CHEMICALS

Directory of Open Access Journals (Sweden)

M. Kemal YALINKILIÇ

1998-02-01

Full Text Available Combustible properties of treated douglas wood specimens and fire-retardancy of some preservatives were tested in this study. Crib test of ASTM E 160-150 was followed. Results indicated that, aqueous solutions of boric acid (BA, borax (Bx (Na2BO7 10H2O or BA + Bx mixture (7: 3, w: w had fire retardant efficacy (FRE over untreated wood and reduced the combustibility of vinil monomers (Styrene and methylmetacrylate which were applied as secondary treatment.

Introducing wood pellet fuel to the UK

Energy Technology Data Exchange (ETDEWEB)

Cotton, R A; Giffard, A

2001-07-01

Technical and non-technical issues affecting the introduction of wood pellet-fired heating to the UK were investigated with the aim of helping to establish a wood pellet industry in the UK. The project examined the growth and status of the industry in continental Europe and North America, reviewed relevant UK standards and legislation, identified markets for pellet heating in the UK, organised workshops and seminars to demonstrate pellet burning appliances, carried out a trial pelletisation of a range of biomass fuels, helped to set up demonstration installations of pellet-fired appliances, undertook a promotional campaign for wood pellet fuel and compiled resource directories for pellet fuel and pellet burning appliances in the UK. The work was completed in three phases - review, identification and commercialisation. Project outputs include UK voluntary standards for wood pellet fuel and combustion appliances, and a database of individuals with an interest in wood pellet fuel.

New technologies reducing emissions from combustion of biofuels

International Nuclear Information System (INIS)

Oravainen, H.

1997-01-01

In reducing CO 2 emissions, bioenergy will be the most important source of renewable energy in the next few decades. In principle, combustion of biomass is friendly to the environment because CO 2 released during combustion is recycled back into natural circulation. Biofuels normally contain little nitrogen and sulphur. However, depending on the combustion technology used, emissions may be quite high. This is true of combustion of biomass fuels in small appliances like wood stoves, fireplaces, small boilers etc. When fuels having high content of volatile matter are burnt in appliances using batch type combustion, the process is rather an unsteady-state combustion. Emissions of carbon monoxide, other combustible gases and particulates are quite difficult to avoid. With continuous combustion processes this is not normally a problem. This conference paper presents some means of reducing emissions from combustion of biofuels. 5 refs., 4 figs

Use of an Individual Plant Examination (IPE) to enhance outage management

International Nuclear Information System (INIS)

Putney, B.; Averett, M.; Riley, J.

1992-10-01

A comparative emissions study was conducted on combustion products of various solid domestic cooking fuels; the objective was to compare relative levels of organic and inorganic toxic emissions from traditional Pakistani fuels (wood, wood charcoal, and dried animal dung) with manufactured low-rank coal briquettes (Lakhra and Sor-Range coals) under conditions simulating domestic cooking. A small combustion shed 12 m 3 internal volume, air exchange rate 14 h -1 was used to simulate south Asian cooking rooms. 200-g charges of the various fueb were ignited in an Angethi stove located inside the shed, then combusted to completion; effluents from this combustion were monitored as a function of time. Measurements were made of respirable particulates, volatile and semi-volatile organics, CO, SO 2 , and No x . Overall it appears that emissions from coal briquettes containing combustion amendments (slaked lime, clay, and potassium nitrate oxidizer) are no greater than emissions Erom traditional fuels, and in some cases are significantly lower; generally, emissions are highest for afl fuels in the early stages of combustion

Verification of Conditions for use of Combustion Products‘ Heat

Directory of Open Access Journals (Sweden)

Kažimírová Viera

2015-06-01

Full Text Available Presented contribution deals with the verification of conditions for use of combustion products‘ heat, generated by combustion of wood in a fireplace used in a household. It is necessary to know the temperature behaviour of the fireplace to determine the adequacy of the technical solution for using combustion products‘ heat. The combustion products‘ temperature at the upper part of the chimney is 80-120 °C. The dew point value was established to be below 51 °C. The average observed value of combustion product velocity is 1.6 m s-1. The volume flow rate of combustion products is 12 m3 h-1. Measured values allow for effective solution of the use of combustion products‘ heat.

MOLECULAR CHARACTERIZATION OF SMOKE FROM CAMPFIRE BURNING OF PINE WOOD (PINUS ELLIOTTII). (R823990)

Science.gov (United States)

AbstractAlthough campfires are typically enjoyable events, people are exposed to high concentrations of gaseous and particulate pollutants. The combustion conditions of wood burned in campfires are different from those of indoor wood burning in stoves or fireplaces. T...

Advanced CFD modelling of air and recycled flue gas staging in a waste wood-fired grate boiler for higher combustion efficiency and greater environmental benefits.

Science.gov (United States)

Rajh, Boštjan; Yin, Chungen; Samec, Niko; Hriberšek, Matjaž; Kokalj, Filip; Zadravec, Matej

2018-07-15

Grate-fired boilers are commonly used to burn biomass/wastes for heat and power production. In spite of the recent breakthrough in integration of advanced secondary air systems in grate boilers, grate-firing technology needs to be advanced for higher efficiency and lower emissions. In this paper, innovative staging of combustion air and recycled flue gas in a 13 MW th waste wood-fired grate boiler is comprehensively studied based on a numerical model that has been previously validated. In particular, the effects of the jet momentum, position and orientation of the combustion air and recycled flue gas streams on in-furnace mixing, combustion and pollutant emissions from the boiler are examined. It is found that the optimized air and recycled flue gas jets remarkably enhance mixing and heat transfer, result in a more uniform temperature and velocity distribution, extend the residence time of the combustibles in the hot zone and improve burnout in the boiler. Optimizing the air and recycled flue gas jet configuration can reduce carbon monoxide emission from the boiler by up to 86%, from the current 41.0 ppm to 5.7 ppm. The findings of this study can serve as useful guidelines for novel design and optimization of the combustion air supply and flue gas recycling for grate boilers of this type. Copyright © 2018 Elsevier Ltd. All rights reserved.

Experimental investigation of wood combustion in a fixed bed with hot air

Energy Technology Data Exchange (ETDEWEB)

Markovic, Miladin, E-mail: m.markovic@utwente.nl; Bramer, Eddy A.; Brem, Gerrit

2014-01-15

Highlights: • Upward combustion is a new combustion concept with ignition by hot primary air. • Upward combustion has three stages: short drying, rapid devolatilization and char combustion. • Variation of fuel moisture and inert content have little influence on the combustion. • Experimental comparison between conventional and upward combustion is presented. - Abstract: Waste combustion on a grate with energy recovery is an important pillar of municipal solid waste (MSW) management in the Netherlands. In MSW incinerators fresh waste stacked on a grate enters the combustion chamber, heats up by radiation from the flame above the layer and ignition occurs. Typically, the reaction zone starts at the top of the waste layer and propagates downwards, producing heat for drying and devolatilization of the fresh waste below it until the ignition front reaches the grate. The control of this process is mainly based on empiricism. MSW is a highly inhomogeneous fuel with continuous fluctuating moisture content, heating value and chemical composition. The resulting process fluctuations may cause process control difficulties, fouling and corrosion issues, extra maintenance, and unplanned stops. In the new concept the fuel layer is ignited by means of preheated air (T > 220 °C) from below without any external ignition source. As a result a combustion front will be formed close to the grate and will propagate upwards. That is why this approach is denoted by upward combustion. Experimental research has been carried out in a batch reactor with height of 4.55 m, an inner diameter of 200 mm and a fuel layer height up to 1 m. Due to a high quality two-layer insulation adiabatic conditions can be assumed. The primary air can be preheated up to 350 °C, and the secondary air is distributed via nozzles above the waste layer. During the experiments, temperatures along the height of the reactor, gas composition and total weight decrease are continuously monitored. The influence of

Impact of impregnation with boron compounds on combustion ...

African Journals Online (AJOL)

user

2011-04-11

Apr 11, 2011 ... 2Gazi University, Industrial Arts Education Faculty, Department of ... security. Key words: Combustion, flame retardance, coatings, boron compounds, varnish. ..... attack in wood deterioration and its prevention by preservative.

Minimizing fuel wood consumption through the evolution of hot ston ...

African Journals Online (AJOL)

The central objective of this paper is to minimize fuelwood consumption through evolving alternative domestic energy. Data on alternative domestic energy sources, and use fuel wood consumption during scarcity of petroleum were collected using structured questionnaires. Data on time spent to cook yam, race and beans ...

Emissions from small-scale combustion of biomass fuels - extensive quantification and characterization

Energy Technology Data Exchange (ETDEWEB)

Boman, Christoffer; Nordin, Anders; Oehman, Marcus; Bostroem, Dan [Umeaa Univ. (Sweden). Energy Technology and Thermal Process Chemistry; Westerholm, Roger [Stockholm Univ., Arrhenius Laboratory (Sweden). Analytical Chemistry

2005-02-01

This work was a part of the Swedish national research program concerning emissions and air quality with the sub-programme concerning biomass, health and environment - BHM. The main objective of the work was to systematically determine the quantities and characteristics of gaseous and particulate emissions from combustion in residential wood log and biomass fuel pellet appliances and report emission factors for the most important emission components. The specific focus was on present commercial wood and pellet stoves as well as to illustrate the potentials for future technology development. The work was divided in different subprojects; 1) a literature review of health effects of ambient wood smoke, 2) design and evaluation of an emission dilution sampling set-up, 3) a study of the effects of combustion conditions on the emission formation and characteristics and illustrate the potential for emission minimization during pellets combustion, 4) a study of the inorganic characteristics of particulate matter during combustion of different pelletized woody raw materials and finally 5) an extensive experimental characterization and quantification of gaseous and particulate emissions from residential wood log and pellet stoves. From the initial literature search, nine relevant health studies were identified, all focused on effects of short-term exposure. Substantial quantitative information was only found for acute asthma in relation to PM10. In comparison with the general estimations for ambient PM and adverse health effects, the relative risks were even stronger in the studies where residential wood combustion was considered as a major PM source. However, the importance of other particle properties than mass concentration, like chemical composition, particle size and number concentration remain to be elucidated. A whole flow dilution sampling set-up for residential biomass fired appliances was designed, constructed and evaluated concerning the effects of sampling

Emissions from small-scale combustion of biomass fuels - extensive quantification and characterization

Energy Technology Data Exchange (ETDEWEB)

Boman, Christoffer; Nordin, Anders; Oehman, Marcus; Bostroem, Dan [Umeaa Univ. (Sweden). Energy Technology and Thermal Process Chemistry; Westerholm, Roger [Stockholm Univ., Arrhenius Laboratory (Sweden). Analytical Chemistry

2005-02-01

This work was a part of the Swedish national research program concerning emissions and air quality with the sub-programme concerning biomass, health and environment - BHM. The main objective of the work was to systematically determine the quantities and characteristics of gaseous and particulate emissions from combustion in residential wood log and biomass fuel pellet appliances and report emission factors for the most important emission components. The specific focus was on present commercial wood and pellet stoves as well as to illustrate the potentials for future technology development. The work was divided in different subprojects; 1) a literature review of health effects of ambient wood smoke, 2) design and evaluation of an emission dilution sampling set-up, 3) a study of the effects of combustion conditions on the emission formation and characteristics and illustrate the potential for emission minimization during pellets combustion, 4) a study of the inorganic characteristics of particulate matter during combustion of different pelletized woody raw materials and finally 5) an extensive experimental characterization and quantification of gaseous and particulate emissions from residential wood log and pellet stoves. From the initial literature search, nine relevant health studies were identified, all focused on effects of short-term exposure. Substantial quantitative information was only found for acute asthma in relation to PM10. In comparison with the general estimations for ambient PM and adverse health effects, the relative risks were even stronger in the studies where residential wood combustion was considered as a major PM source. However, the importance of other particle properties than mass concentration, like chemical composition, particle size and number concentration remain to be elucidated. A whole flow dilution sampling set-up for residential biomass fired appliances was designed, constructed and evaluated concerning the effects of sampling

Consideration of the energetic use of waste wood versus re-use of materials

International Nuclear Information System (INIS)

Bergsma, G.C.; Sas, H.

1997-01-01

Recycling of wood wastes to chipboard is compared with the combustion of waste wood in combination with high-efficient energy recovery. Both options show much better environmental effects than the disposal of wood wastes. The differences between the environmental effects of the first two options can be neglected. The reprocessing of wood wastes to chipboard results in a decrease of the production of gypsum board. That benefit is equal to the benefit of cocombustion of wood wastes in a coal-fired power plant, i.e. saving coal. 18 refs

Supply of wood fuel from small-scale woodlands for small-scale heating

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-07-01

This report summarises the findings of a study aimed at stimulating a market for wood fuels. A desk study of harvesting in existing small woodland was conducted, and thirteen case studies covering early broadleaved thinnings, mixed broadleaved coppice, and crownwood, scrub and residues were examined to obtain information on woodland types, wood fuel supply, and combustion equipment. Details are given of the measurement of moisture content of woodchips and stacked roundwood, wood volume and green density, harvesting options, crop and site variables, and production and costs of wood fuels. Usage of wood fuels, and the drying of small roundwood was considered. (UK)

Emission of PCDD/F, PCB, and HCB from combustion of firewood and pellets in residential stoves and boilers.

Science.gov (United States)

Hedman, Björn; Naslund, Morgan; Marklund, Stellan

2006-08-15

To assess potential emissions of polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), polychlorinated biphenyls (PCBs), and hexachlorobenzene (HCB) from residential combustion of biofuels, experiments were performed in which various types of pellets and firewood were combusted in four types of stoves and boilers, with both full and reduced rates of air supply. Intermittent combustion of wood pellets resulted in emissions of 11 ng-(WHO-TEQ)/kg combusted fuel (dry weight). A modern, environmentally certified boiler yielded somewhat lower emissions of PCCD/F and PCB than a wood stove. Both gave <0.1 ng(WHO-TEQ)/m3n (1.3-6.5 ng(WHO-TEQ)/kg) and considerably lower emissions than an old boiler (7.0-13 ng(WHO-TEQ)/kg). No positive effect on emissions could be observed in full air combustion (simulating the use of a heat storage tank) compared to combustion with reduced air. Two of the wood combustion experiments included paper and plastic waste fuels. Chlorine-containing plastic waste gave rise to high emissions: ca. 310 ng(WHO-TEQ)/ kg over the whole combustion cycle. The homologue profiles of PCDD/Fs show characteristic differences between ashes and flue gas from combustions with different levels of air supply. These differences do not, however, seem to have any correlation to the relative amount of toxic congeners.

Hazardous air emissions potential from a wood-fired furnace

International Nuclear Information System (INIS)

Hubbard, A.J.

1995-01-01

During the first week of April, 1991 the Wisconsin Department of Natural Resources (WDNR) conducted a series of air emissions tests of a small industrial wood-fired boiler in northern Wisconsin. The boiler was firing a virgin hogged wood/wood waste fuel with a moisture content of about 35 percent. The pollutants measured were particulates, nitrogen oxides (NOx), carbon monoxide (GO), total hydrocarbons (THC), benzene, formaldehyde (CHOH), polycyclic organic matter (POM, e.g. Benzo (a) pyrene), aldehydes, and trace metals (As, Ba, Cu, Pb, Mn, Ni, K, Se, Na, and Zn). For two and a half days continuous emissions data were recorded by laboratory-certified continuous emissions monitors for CO, NOx, 0-2, THC, and COq2 while the EPA reference method stack tests were being conducted for the other pollutants. In addition, a WDNR test team measured CO, 0-2, and flue gas temperature with a Rosemount portable combustion analyzer for several hours over the course of those two and a half days. The principal purpose behind the study was to evaluate the hazardous air emissions potential of a small industrial furnace firing a virgin wood fuel. To that end, it was hoped that a surrogate pollutant could be identified which would represent the levels of hazardous air emissions (e.g., benzene) present in the wood-fired furnace flue gases. If a readily monitorable pollutant could be identified, then a regulatory strategy of measuring one representative pollutant could be put in place to continually assess the hazardous emissions potential of virgin wood combustion. (UK)

Market Assessment of Biomass Gasification and Combustion Technology for Small- and Medium-Scale Applications

Energy Technology Data Exchange (ETDEWEB)

Peterson, D.; Haase, S.

2009-07-01

This report provides a market assessment of gasification and direct combustion technologies that use wood and agricultural resources to generate heat, power, or combined heat and power (CHP) for small- to medium-scale applications. It contains a brief overview of wood and agricultural resources in the U.S.; a description and discussion of gasification and combustion conversion technologies that utilize solid biomass to generate heat, power, and CHP; an assessment of the commercial status of gasification and combustion technologies; a summary of gasification and combustion system economics; a discussion of the market potential for small- to medium-scale gasification and combustion systems; and an inventory of direct combustion system suppliers and gasification technology companies. The report indicates that while direct combustion and close-coupled gasification boiler systems used to generate heat, power, or CHP are commercially available from a number of manufacturers, two-stage gasification systems are largely in development, with a number of technologies currently in demonstration. The report also cites the need for a searchable, comprehensive database of operating combustion and gasification systems that generate heat, power, or CHP built in the U.S., as well as a national assessment of the market potential for the systems.

Wood-burning stoves in low-carbon dwellings

DEFF Research Database (Denmark)

Luis Teles de Carvalho, Ricardo; Jensen, Ole Michael; Afshari, Alireza

2013-01-01

The European climate change strategy intends to encourage the erection of low-carbon buildings and the upgrading of existing buildings to low-carbon level. At the same time, it is an EU vision to maximise the use of renewable energy resources. In this strategy, small-scale wood......-burning is an overlooked source for heating. A wood-burning stove is considered low-carbon technology since its fuel is based on local residual biomass. A field study investigating how modern wood-burning stoves operated in modern single-family houses showed that intermittent heat supply occasionally conflicted...... combustion technology and automatics, controlling the interplay between stove and house, can make wood-burning stoves suitable for low-carbon dwellings and meet the remaining heat demand during the coldest period. It was further concluded that new guidelines need to be elaborated about how to install...

Residential wood heating: The forest, the atmosphere and the public consciousness

International Nuclear Information System (INIS)

Gulland, J.F.; Hendrickson, O.Q.

1993-01-01

It is generally agreed by both energy and forestry scientists that, provided harvesting is conducted in a sustainable manner, the combustion of wood for energy production is essentially carbon dioxide neutral when the normal forest regeneration period is considered. When wood combustion replaces the consumption of fossil fuels, however, the net reduction in carbon dioxide release is almost immediate. In addition to the requirement of sustainable forestry practices, the maintenance of site biodiversity must also be considered. A preliminary review of the literature reveals that periodic selective harvesting can actually have a positive impact on the biodiversity of the forest. Despite the fact that the harvesting, processing and transportation of wood fuel invariably consumes fossil fuels, it has been shown in case studies that the energy return on investment can easily exceed a ratio of 25:1. Approximately 20 percent of the single family dwellings in Canada are heated to some extent with wood and the potential exists for an increasing contribution of wood fuel to residential energy requirements. However, there is evidence of confusion among the public regarding the environmental impact of woodburning, particularly as it relates to CO 2 emissions and carbon storage in forests. The confusion could impede the increased use of wood for residential heating because it calls into question the appropriateness of using wood for energy purposes. The forms of residential wood energy use that have evolved in rural North America provide important but neglected models of sustainable development. This could serve as the central theme of public information program to clarify the role of wood energy in the reduction of greenhouse gas emissions

Analysis of the chemical composition of ultrafine particles from two domestic solid biomass fired room heaters under simulated real-world use

Science.gov (United States)

Ozgen, Senem; Becagli, Silvia; Bernardoni, Vera; Caserini, Stefano; Caruso, Donatella; Corbella, Lorenza; Dell'Acqua, Manuela; Fermo, Paola; Gonzalez, Raquel; Lonati, Giovanni; Signorini, Stefano; Tardivo, Ruggero; Tosi, Elisa; Valli, Gianluigi; Vecchi, Roberta; Marinovich, Marina

2017-02-01

Two common types of wood (beech and fir) were burned in commercial pellet (11.1 kW) and wood (8.2 kW) stoves following a combustion cycle simulating the behavior of a real-world user. Ultrafine particulate matter (UFP, dp pellets and wood UFP samples, where high TC levels characterize the wood log combustion and potassium salts are dominant in every pellet sample. Crucial aspects determining the UFP composition in the wood stove experiments are critical situations in terms of available oxygen (a lack or an excess of combustion air) and high temperatures. Whereas for the automatically controlled pellets stove local situations (e.g., hindered air-fuel mixing due to heaps of pellets on the burner pot) determine the emission levels and composition. Wood samples contain more potentially carcinogenic PAHs with respect to pellets samples. Some diagnostic ratios related to PAH isomers and anhydrosugars compiled from experimental UFP data in the present study and compared to literature values proposed for the emission source discrimination for atmospheric aerosol, extend the evaluation usually limited to higher particle size fractions also to UFP.

Legislation of combustion of recovered bio fuels; Regelverk foer eldning av returtraeflis

Energy Technology Data Exchange (ETDEWEB)

Harnevie, Henrik; Olvstam, Marie Louise [SwedPower AB, Stockholm (Sweden)

2001-03-01

A research programme, concerning combustion of sorted waste wood with the objective to solve and answer the following questions has been started: * What types of problems can arise?, * What causes the problems?, and * How can the problems be solved? This first stage of the programme has focused on the first two questions. The problem when using chips from waste wood can be divided into different categories; operational problems, environmental problems as well as restrictions related to new EC-regulations. The environmental problems when burning wood waste are related to the chemical composition of the fuel. In some fuel deliveries, sorted waste wood has a content of heavy metals in the same range as for ordinary biofuels. In other cases, the degree of contamination is unacceptable. Fouling of heating surfaces is one of the most significant combustion problems for chips from waste wood. The rate of fouling and deposition on the heating surfaces will increase three to five times compared to ordinary biomass combustion in the same boiler and under the same conditions. Fouling has been shown to occur regardless of the furnace used, whereas the dimensions and design of the heating surfaces have a more significant influence. The deposits formed are more corrosive over a broader temperature range compared to deposits formed during combustion of ordinary wood chips. This expands the corrosion problems to surfaces constructed of lower alloyed steels such as furnace walls and primary superheaters. In addition to the typical components of wood ash (such as calcium, potassium and sulphur), zinc, lead and sometimes titanium are enriched in the deposits. Most fuel fractions of sorted waste wood will be affected by the new EC-restrictions for combustion of waste. This is due to the fact that analysis of these fuels show higher content of halogens and most heavy metals than for example analysis of clean wood chips. The EC-restriction will mean more stringent rules for emissions

The use of wood for wind turbine blade construction

Science.gov (United States)

Gougeon, M.; Zuteck, M.

1979-01-01

The interrelationships between moisture and wood, conditions for dry rot spore activity, the protection of wood fibers from moisture, wood resin composites, wood laminating, quality control, and the mechanical properties of wood are discussed. The laminated veneer and the bonded sawn stock fabrication techniques, used in the construction of a turbine blade with a monocoque 'D' section forming the leading edge and a built up trailing edge section, are described. A 20 foot root end sample complete with 24 bonded-in studs was successfully subjected to large onetime loads in both the flatwise and edgewise directions, and to fatigue tests. Results indicate that wood is both a viable and advantageous material for use in wind turbine blades. The basic material is reasonably priced, domestically available, ecologically sound, and easily fabricated with low energy consumption.

Smoke emissions in small-scale burning of wood

International Nuclear Information System (INIS)

Tuomi, S.

1993-01-01

The article is based on research carried out in Finland and Sweden on the subject of emissions of smoke in the small-scale burning of wood and the factors affecting it. Due to incomplete combustion, small-scale burning of wood is particularly typified by its emissions of solid particles, carbon monoxide, hydrocarbons and PAH compounds. Included among factors influencing the volume of emissions are the load imposed on the heating device, the manner in which the fuel is fed into the firebox, fuel quality, and heating device structure. Emissions have been found to be at their minimum in connection with heating systems based on accumulators. Emissions can be significantly reduced by employing state-of-the-art technology, appropriate ways of heating and by dry fuel. A six-year bioenergy research programme was launched early in 1993 in Finland. All leading research institutions and enterprises participate in this programme. Reduction of emissions has been set as the central goal in the part dealing with small-scale burning of wood. Application of catalytic combustion in Finnish-made heating devices is one of the programmes development targets. Up to this date, the emissions produced in the small-scale burning of wood are not mentioned in official regulations pertaining to approved heating devices. In Sweden tar emissions are applied as a measure of the environmental impact imposed by heating devices

Ashes from straw and wood-chip fired plants for agricultural usage. Pilot project

International Nuclear Information System (INIS)

Morsing, M.; Westborg, S.

1994-08-01

The content of nutrients and heavy metals in ashes from the combustion of straw and wood chips at district heating plants is studied, on the basis of results of analyses from Danish municipalities, to determine whether such ashes are suitable for use as fertilizers. Results of the analysis of ashes from 9 wood-chip fired and 26 straw-fired plants are presented. They show significant variations in nutrient and heavy metal content which could be caused by combustion and operational conditions and/or testing methods. On condition that the phosphorous content of straw and wood-chip ashes amount to 1% of the dry matter, 50%-75% of the straw ashes and under 50% of wood chip ashes analyses are within the limit for cadmium stipulated in the Danish Ministry of the Environment's Executive Order no. 736 on the use of wastes for agricultural purposes. This is found to be unsatisfactory. It is suggested that a closer investigation should be undertaken in order to determine which amount of straw and wood-chip ashes can be accepted for use as fertilizers in consideration of the stipulated limits for cadmium content of wastes to be used for agricultural purposes. In addition the technological and economic potentials of dosing of these ashes for this use should be investigated. Fly ash and slag were also included in the analysis results studied and it was found that the cadmium content of slag did not prevent its use as fertilizer, but that the distribution of cadmium in slag, in fly ash and in slam from flue gas cleaning systems related to the combustion of wood chips should be further investigated. (AB)

Measures on fireside emission reduction during wood combustion in industrial furnaces; Massnahmen zur feuerungsseitigen Emissionsminderung bei der Holzverbrennung in gewerblichen Feuerungsanlagen

Energy Technology Data Exchange (ETDEWEB)

Zuberbuehler, U.

2002-07-01

The combustion of natural wood chips in current automatic firing systems leads to emissions of NO{sub x} < 200 mg/m{sup 3} and Particular Matter (PM)<50 mg/m{sup 3}. During the combustion of chipboard residues NO{sub x} emissions can reach 1000 mg/m{sup 3} and PM 500 mg/m{sup 3}, as they accrue particularly at furniture industry and carpenters. To achieve better particle burnout and lower NO{sub x} concentrations a new firing concept has been developed and tested. State of the art in the area of commercial wood firings was the {lambda}- and temperature controlled underfeed firing. Based on this firing type, a stage combustion was realized by a separation of the furnace in primary and secondary combustion chamber. Within the first step of development the burnout zone was optimised to improve particle burnout with simultaneous particle separation. Secondary air supply was made with a special fan to produce a swirl flow inside the cylindrical combustion chamber. Similar as in a cyclone particles were carried in a reverse flow to the furnace wall where is sufficient time for burnout. The good mixing performance of air and combustion gases is another benefit of the produced swirl flow. The aim of further development was to achieve the necessary conditions for primary NO{sub x} reduction with a new design of the primary zone of the furnace. Therefore hot gas from the end of combustion chamber or exhaust gas was recirculated to reduce the amount of primary air. The new primary zone of the combustion chamber was combined with the well working burnout zone with integrated particle separation. The combustion behaviour of this combined furnace was investigated and optimised on a test stand. During continuous combustion of coated chipboards (fuel N-content 4,3%) NO{sub x} concentrations of 450 mg/m{sup 3} were measured, which correspond to a 40% reduction in comparison with a common underfed firing. CO concentrations of 30 mg/m{sup 3} were on a very low level and particle

Fuel Wood: A Conventional Source Of Energy In Mountains Of The ...

African Journals Online (AJOL)

The use of fuel wood in the Garhwal Himalaya as a primary source of energy for domestic purposes is causing severe deforestation in the Garhwal Himalaya. The fuel wood consumption patterns have been studied in six villages selected two each in tropical (Ganga Bhogpur and Kunow), sub-tropical (Bhainswara and ...

A combustion model of vegetation burning in "Tiger" fire propagation tool

Science.gov (United States)

Giannino, F.; Ascoli, D.; Sirignano, M.; Mazzoleni, S.; Russo, L.; Rego, F.

2017-11-01

In this paper, we propose a semi-physical model for the burning of vegetation in a wildland fire. The main physical-chemical processes involved in fire spreading are modelled through a set of ordinary differential equations, which describe the combustion process as linearly related to the consumption of fuel. The water evaporation process from leaves and wood is also considered. Mass and energy balance equations are written for fuel (leaves and wood) assuming that combustion process is homogeneous in space. The model is developed with the final aim of simulating large-scale wildland fires which spread on heterogeneous landscape while keeping the computation cost very low.

Combustion physics

Science.gov (United States)

Jones, A. R.

1985-11-01

Over 90% of our energy comes from combustion. By the year 2000 the figure will still be 80%, even allowing for nuclear and alternative energy sources. There are many familiar examples of combustion use, both domestic and industrial. These range from the Bunsen burner to large flares, from small combustion chambers, such as those in car engines, to industrial furnaces for steel manufacture or the generation of megawatts of electricity. There are also fires and explosions. The bountiful energy release from combustion, however, brings its problems, prominent among which are diminishing fuel resources and pollution. Combustion science is directed towards finding ways of improving efficiency and reducing pollution. One may ask, since combustion is a chemical reaction, why physics is involved: the answer is in three parts. First, chemicals cannot react unless they come together. In most flames the fuel and air are initially separate. The chemical reaction in the gas phase is very fast compared with the rate of mixing. Thus, once the fuel and air are mixed the reaction can be considered to occur instantaneously and fluid mechanics limits the rate of burning. Secondly, thermodynamics and heat transfer determine the thermal properties of the combustion products. Heat transfer also plays a role by preheating the reactants and is essential to extracting useful work. Fluid mechanics is relevant if work is to be performed directly, as in a turbine. Finally, physical methods, including electric probes, acoustics, optics, spectroscopy and pyrometry, are used to examine flames. The article is concerned mainly with how physics is used to improve the efficiency of combustion.

Liquefaction of aspen poplar wood

Energy Technology Data Exchange (ETDEWEB)

Eager, R L; Mathews, J F; Pepper, J M

1982-01-01

Dried and green aspen poplar wood suspended in water containing alkali catalysts was converted completely to an oil, water-soluble chemical, and gases by heating for 1 hour in the presence of CO in a rocking batch reactor. Within the ranges of parameters studied: temperature of 593-633 K; nominal reaction times of less than or equal to 1 hour; water-to-wood ratio of 0.5:1-5:1; Na/sub 2/CO/sub 3/, K/sub 2/CO/sub 3/, and NaOH catalysts; amount of catalyst 7.0-12.5%; and initial H-CO ratios of 2:1-0:1, the water-to-wood ratio was most important. Oil yields of approximately 50% with a C plus H content of approximately 80% and representing a C recovery of approximately 66% were obtained. The higher heats of combustion were 32.2-36.0 MJ/kg.

Adapting Chinese Forest Operations to Socio-Economic Developments: What is the Potential of Plantations for Strengthening Domestic Wood Supply?

Directory of Open Access Journals (Sweden)

Stephan Hoffmann

2018-04-01

Full Text Available Over recent decades, China’s forestry sector went through a transition phase characterized by a management and institutional reform process, with a constant rethinking of the ecological and societal role of forests within a unique political system. Nevertheless, despite impressive achievements in forest restoration and conservation efforts, the enhancement of ecosystem services and forest area expansion through plantation development, China was not able to improve its domestic timber supply capacities according to its demands. Consequently, the continually growing wood processing industry is facing a severe demand-and-supply gap, causing high dependencies on timber imports. Outdated forest operations practices, dominated by manual labour, are not able to meet supply demands or to implement new silvicultural strategies for enhancing forest quality and productivity and are a widely unnoted disruption of a sustainable development. Therefore, this review presents the status quo of China’s forest operations sector, how it is shaped by forest policy reforms and recent socio-economic developments. In addition, suggestions are developed how the sector can progress through policy adaptations in order to develop sustainable timber supply capacities based on a domestic plantation sector.

National Wood-fuel Programme 2000-2006. Activity Report 2000-2006

International Nuclear Information System (INIS)

2008-01-01

When ADEME launched its Wood-fuel programme throughout all of France in late 1999, its aim was to guide this resource supply chain to maturity and stable development in all user sectors: domestic, multi-family housing, commercial/institutional and industrial applications. To this end the Wood-fuel Programme 2000-2006 was assigned objectives and endowed with significant financial means for studies and coordination in order to support and carry out general-interest projects, piloted by ADEME. The stated goal was to replace fossil fuels, avoid carbon emissions and establish quality assurance standards for household firewood and wood-fired devices. This report presents: 1 - the Wood Energy stakes for the environment, for employment, and for the economy, the biomass energy net benefits; 2 - the Wood Energy key figures: Production and consumption, Single-family homes and wood heating, Breakdown of types of devices used, Sales of wood-fired devices, Number of housing/institutional boilers in use, Number of industrial boilers in use; 3 - the Wood Energy objectives: Domestic heating, Industrial boiler plants, District heating for housing/institutional/commercial uses; 4 - the Wood Energy program operation: Program coordination by ADEME, Partnerships and State-Region planning agreements, 2000-2006 funding system (modified in 2004) and Other financial instruments; 5 - the 2000-2006 assessment: Main results, Conclusions and recommendations, Evaluation contributions: five key points, Evaluation of employment in the solid biofuels supply chain, Supply for community, institutional and commercial boilers; 6 - Information and communication: Initiatives supported or accompanied by ADEME between 2000 and 2004, Publications supported by ADEME. In appendix: fuels and energy content, regional assessments, national research program on bio-energies - PNRB 2006 (Review and stakes, PNRB results in 2006), wood heating R and D, studies funded by ADEME, 2006 ADEME's correspondents, glossary

Combustion Characterization of Individual Bio-oil Droplets

DEFF Research Database (Denmark)

Hansen, Brian Brun; Jensen, Peter Arendt

2015-01-01

Single droplet combustion characteristics has been investigated for bio-oil slurries, containing biomass residue, and compared to conventional fuels for pulverized burners, such as fuel oil (start up) and wood chips (solid biomass fuel). The investigated fuels ignition delays and pyrolysis behavior...

NOx emissions from the underfeed combustion of coal and biomass

International Nuclear Information System (INIS)

Purvis, M.R.I.; Tadulan, E.L.; Tariq, A.S.

2000-01-01

Underfeed stokers have an inherent ability to minimise smoke emissions, thus providing environmental benefits in the combustion of solid fuels, such as biomass materials, which have a high volatile matter content. An evaluation of this attribute requires comparisons of the performance of combustion equipment using these fuels against reference data for coals. However, the recent literature is virtually devoid of studies of coal combustion in underfeed stokers and, in particular, information on nitrogen oxide emissions. In the UK, this reflects a lack of commercial interest in small-scale coal firing due to the wide availability of inexpensive gas and oil fuels. An experimental investigation has been carried out into the combustion of bituminous coal, anthracite and a 50:50 blend by mass of anthracite and oak wood chips on a modified commercial underfeed stoker. The intention was to obtain operational experiences in burning the fuels and reference data for nitrogen oxide emissions. Problems in the combustion of the fuels are described and related to the determination of nitrogen oxide emission values found under optimised plant conditions. These values, expressed at 6% O 2 , were 265 ppm for bituminous coal, 90 ppm for anthracite and 106 ppm for the anthracite/wood chip blend. (Author)

Preservation of forest wood chips

Energy Technology Data Exchange (ETDEWEB)

Kofman, P.D.; Thomsen, I.M.; Ohlsson, C.; Leer, E.; Ravn Schmidt, E.; Soerensen, M.; Knudsen, P.

1999-01-01

As part of the Danish Energy Research Programme on biomass utilisation for energy production (EFP), this project concerns problems connected to the handling and storing of wood chips. In this project, the possibility of preserving wood chips of the Norway Spruce (Picea Abies) is addressed, and the potential improvements by anaerobic storage are tested. Preservation of wood chips aims at reducing dry matter losses from extensive heating during storage and to reduce production of fungal spores. Fungal spores pose a health hazards to workers handling the chips. Further the producers of wood chips are interested in such a method since it would enable them to give a guarantee for the delivery of homogeneous wood chips also during the winter period. Three different types of wood chips were stored airtight and further one of these was stored in accordance with normal practise and use as reference. The results showed that airtight storage had a beneficial impact on the quality of the chips: no redistribution of moisture, low dry matter losses, unfavourable conditions for microbial activity of most fungi, and the promotion of yeasts instead of fungi with airborne spores. Likewise the firing tests showed that no combustion problems, and no increased risk to the environment or to the health of staff is caused by anaerobic storage of wood chips. In all, the tests of the anaerobic storage method of forest wood chips were a success and a large-scale test of the method will be carried out in 1999. (au)

Technique for in-place welding of aluminum backed up by a combustible material

Science.gov (United States)

Spagnuolo, A. C.

1971-01-01

Welding external aluminum jacket, tightly wrapped around inner layer of wood composition fiberboard, in oxygen free environment prevents combustion and subsequent damage to underlying fiberboard. Technique also applies to metal cutting in similar assemblies without disassembly to remove combustible materials from welding heat proximity.

Oxidative damage to DNA and repair induced by Norwegian wood smoke particles in human A549 and THP-1 cell lines

DEFF Research Database (Denmark)

Danielsen, Pernille Høgh; Loft, Steffen; Kocbach, Anette

2009-01-01

Genotoxic effects of traffic-generated particulate matter (PM) are well described, whereas little data are available on PM from combustion of biomass and wood, which contributes substantially to air pollution world wide. The aim of this study was to compare the genotoxicity of wood smoke particul......Genotoxic effects of traffic-generated particulate matter (PM) are well described, whereas little data are available on PM from combustion of biomass and wood, which contributes substantially to air pollution world wide. The aim of this study was to compare the genotoxicity of wood smoke...... than PM collected from vehicle exhaust with respect to development of lung cancer....

Wood ethanol and synthetic natural gas pathways

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-11-30

This report provided details of updates to the wood ethanol pathway recently added to the GHGenius model, an analytical tool used to analyze emissions from conventional and alternative fuel combustion processes. The pathway contains data developed by the United States Department of Energy. A number of co-products were added to the wood and agricultural residue pathways, including furfural, xylitol, lignin, and glycerol. New chemical inputs included nitrogen gas, ammonia, enzymes and yeast. Biological ethanol pathways were reviewed, and separate inputs for wood, agricultural residues, corn ethanol, and wheat ethanol were added. The model was updated to reflect current research conducted on the gasification of wood and the upgrading of the gas to produce pipeline quality natural gas. New process developments in producing pipeline quality gas from coal were also added. The ability to model enzyme consumption was added to all ethanol pathways. 25 refs., 41 tabs., 8 figs.

Wood ethanol and synthetic natural gas pathways

International Nuclear Information System (INIS)

2006-01-01

This report provided details of updates to the wood ethanol pathway recently added to the GHGenius model, an analytical tool used to analyze emissions from conventional and alternative fuel combustion processes. The pathway contains data developed by the United States Department of Energy. A number of co-products were added to the wood and agricultural residue pathways, including furfural, xylitol, lignin, and glycerol. New chemical inputs included nitrogen gas, ammonia, enzymes and yeast. Biological ethanol pathways were reviewed, and separate inputs for wood, agricultural residues, corn ethanol, and wheat ethanol were added. The model was updated to reflect current research conducted on the gasification of wood and the upgrading of the gas to produce pipeline quality natural gas. New process developments in producing pipeline quality gas from coal were also added. The ability to model enzyme consumption was added to all ethanol pathways. 25 refs., 41 tabs., 8 figs

Development of steam generators for combustion of biofuels up to 10 t/h

Energy Technology Data Exchange (ETDEWEB)

Bentzin, H

1985-01-01

Combustion parameters are compared for raw brown coal, rice hulls and coconut shells as fuel in small steam generators. Combustion of native biofuel is seen as a power generation alternative in developing countries. Experiments were conducted on a 6.5 t/h moving grate steam generator with a firing grate surface of 7.2 m/sup 2/. Combustion results are shown in a table. Technological modifications carried out in adapting brown coal-fired steam generators to biofuels are also listed. A series of small steam generators for combustion of brown coal, biofuels including wood chips, as well as heating oil as back-up has been developed by the Karl-Marx-Stadt Dampfkesselbau Plant, GDR, with steam capacities ranging from 3.2 to 10 t/h. Technical specifications and diagrams of this series design (DGK-3, DGK-45, DWK 2S) are given. A larger steam generator with 20 t/h steam capacity for combustion of raw brown coal, bagasse, wood chips with heating oil and for rice hulls as support fuels is being developed by the Berlin Dampferzeugerbau Plant, GDR. 5 references.

CFD Modelling of Biomass Combustion in Small-Scale Boilers. Final Report

Energy Technology Data Exchange (ETDEWEB)

Xue-Song Bai; Griselin, Niklas; Klason, Torbern; Nilsson, Johan [Lund Inst. of Tech. (Sweden). Dept. of Heat and Power Engineering

2002-10-01

This project deals with CFD modeling of combustion of wood in fixed bed boilers. A flamelet model for the interaction between turbulence and chemical reactions is developed and applied to study small-scale boiler. The flamelet chemistry employs 43 reactive species and 174 elementary reactions. It gives detailed distributions of important species such as CO and NO{sub x} in the flow field and flue gas. Simulation of a small-scale wood fired boiler measured at SP Boraas (50 KW) shows that the current flamelet model yields results agreeable to the available experimental data. A detailed chemical kinetic model is developed to study the bed combustion process. This model gives boundary conditions for the CFD analysis of gas phase volatile oxidation in the combustion chambers. The model combines a Functional Group submodel with a Depolymerisation, Vaporisation and Crosslinking submodel. The FG submodel simulates how functional groups decompose and form light gas species. The DVC submodell predicts depolymerisation and vaporisation of the macromolecular network and this includes bridge breaking and crosslinking processes, where the wood structure breaks down to fragments. The light fragments form tar and the heavy ones form metaplast. Two boilers firing wood log/chips are studied using the FG-DVC model, one is the SP Boraas small-scale boiler (50 KW) and the other is the Sydkraft Malmoe Vaerme AB's Flintraennan large-scale boiler (55 MW). The fix bed is assumed to be two zones, a partial equilibrium drying/devolatilisation zone and an equilibrium zone. Three typical biomass conversion modes are simulated, a lean fuel combustion mode, a near-stoichiometric combustion and a fuel rich gasification mode. Detailed chemical species and temperatures at different modes are obtained. Physical interpretation is provided. Comparison of the computational results with experimental data shows that the model can reasonably simulate the fixed bed biomass conversion process. CFD

Fly ash classification efficiency of electrostatic precipitators in fluidized bed combustion of peat, wood, and forest residues.

Science.gov (United States)

Ohenoja, Katja; Körkkö, Mika; Wigren, Valter; Österbacka, Jan; Illikainen, Mirja

2018-01-15

The increasing use of biomasses in the production of electricity and heat results in an increased amount of burning residue, fly ash which disposal is becoming more and more restricted and expensive. Therefore, there is a great interest in utilizing fly ashes instead of just disposing of it. This study aimed to establish whether the utilization of fly ash from the fluidized bed combustion of peat, wood, and forest residues can be improved by electrostatic precipitator separation of sulfate, chloride, and some detrimental metals. Classification selectivity calculations of electrostatic precipitators for three different fuel mixtures from two different power plants were performed by using Nelson's and Karnis's selectivity indices. Results showed that all fly ashes behaved similarly in the electrostatic separation process SiO 2 resulted in coarse fractions with Nelson's selectivity of 0.2 or more, while sulfate, chloride, and the studied detrimental metals (arsenic, cadmium, and lead) enriched into fine fractions with varying selectivity from 0.2 to 0.65. Overall, the results of this study suggest that it is possible to improve the utilization potential of fly ashes from fluidized bed combustion in concrete, fertilizer, and earth construction applications by using electrostatic precipitators for the fractionating of fly ashes in addition to their initial function of collecting fly ash particles from flue gases. The separation of the finer fractions (ESP 2 and 3) from ESP 1 field fly ash is recommended. Copyright © 2017 Elsevier Ltd. All rights reserved.

Time-resolved characterization of primary emissions from residential wood combustion appliances.

Science.gov (United States)

Heringa, M F; DeCarlo, P F; Chirico, R; Lauber, A; Doberer, A; Good, J; Nussbaumer, T; Keller, A; Burtscher, H; Richard, A; Miljevic, B; Prevot, A S H; Baltensperger, U

2012-10-16

Primary emissions from a log wood burner and a pellet boiler were characterized by online measurements of the organic aerosol (OA) using a high-resolution time-of-flight aerosol mass spectrometer (HR-TOF-AMS) and of black carbon (BC). The OA and BC concentrations measured during the burning cycle of the log wood burner, batch wise fueled with wood logs, were highly variable and generally dominated by BC. The emissions of the pellet burner had, besides inorganic material, a high fraction of OA and a minor contribution of BC. However, during artificially induced poor burning BC was the dominating species with ∼80% of the measured mass. The elemental O:C ratio of the OA was generally found in the range of 0.2-0.5 during the startup phase or after reloading of the log wood burner. During the burnout or smoldering phase, O:C ratios increased up to 1.6-1.7, which is similar to the ratios found for the pellet boiler during stable burning conditions and higher than the O:C ratios observed for highly aged ambient OA. The organic emissions of both burners have a very similar H:C ratio at a given O:C ratio and therefore fall on the same line in the Van Krevelen diagram.

Preparation of wood for energy use

Science.gov (United States)

Donald L. Sirois; Bryce J. Stokes

1985-01-01

This paper presents an overview & current sources and forms of raw materials for wood energy use and the types of machines available to convert them to the desired form for boiler fuel. Both the fuel source or raw material, and the combustion furnace will dictate the requirements for the processing system. Because of the wide range of processing equipment...

Thermal oxidative degradation of wood modified with aminophenylborates

Directory of Open Access Journals (Sweden)

Klyachenkova Olga

2016-01-01

Full Text Available Comparative thermal analysis in the presence of oxygen was carried out for samples of native pine wood and wood samples modified with aminophenylborates. Significant decrease in the amount of heat released during thermal decomposition of the modified samples was established, which is due to the increase of carbonaceous residues on the surface. Reduction of heat release during decomposition of the modified samples may be explained by the lower yield of combustible volatile products as well as by thin film of boron oxide, formed on the surface of the modified wood, that partially reflects heat flow. Produced upon the modifier decomposition water vapor and inert nitrogen oxides dilute gaseous mixture near the wood surface and isolate it from oxygen. This enhances fire-resistance of wood modified with mono- and diethanolamine(N→Bphenylborates. Hydroxyl group at the sixth carbon atom of the glucopyranose ring of cellulose participates in reactions of cellulose modification, which prevents formation of flammable levoglucosan and, consequently, improves the fire-resistance of the modified wood.

Particle Emission Characteristics of Modern and Old-Type Residential Boilers Fired with Wood Logs and Wood Pellets

International Nuclear Information System (INIS)

Johansson, L.S.; Gustavsson, L.; Tullin, C.; Potter, A.; Leckner, B.

2005-01-01

Residential biofuel combustion for heating can be performed in two ways: in a stove heating the surrounding room, or in a boiler heating water to be circulated through a piping system to heat an entire house. In contrast to stoves, wood boilers can be connected to heat storage tanks, which is an advantage from an emission point of view. The present work focuses on comparing emissions from old-type and modern boilers by means of systematic variation of combustion device, fuel quality, firing behaviour, and the influence of heat storage tank. User habits are simulated in a schematic way. The purpose of the comparison is to determine the emission differences between old-type and modern residential biofuel boilers and to quantify emission characteristics of different kind of biofuel combustion

Heating with wood. A guide to clean and proper heating; Heizen mit Holz. Ein Ratgeber zum richtigen und sauberen Heizen

Energy Technology Data Exchange (ETDEWEB)

Behnke, Anja [Umweltbundesamt, Dessau (Germany); Kemper, Bernd-Michael [Landesanstalt fuer Umwelt, Messungen und Naturschutz Baden-Wuerttemberg (LUBW), Karlsruhe (Germany)

2013-01-15

When correctly used, wood is an eco-friendly fuel. By using well-processed wood from local sources in a properly handled modern fireplace, you can enjoy the cosy warmth from your wood-burning stove or boiler without causing significant environmental damage. The environment and your neighbours will be grateful for this. This brochure is intended to give you tips on how to properly operate a wood-based heating system - in technical terms referred to as a small combustion installation. Especially the burning of poor quality wood in old and insufficiently maintained stoves and unfavourable combustion conditions will result in the emission of unnecessarily high levels of greenhouse gases having adverse effects on the climate, and pollutants detrimental to your health. Particularly in urban agglomerations and valleys, the air quality is affected by wood heating systems due to low chimneys. Often, neighbours will feel annoyed.

Health effects assessment of exposure to particles from wood smoke

DEFF Research Database (Denmark)

Nielsen, Elsa

2007-01-01

distribution of wood smoke particles, essentially all will be contained in the PM2.5 fraction. In Denmark, recent results indicate that about 10,000 tonnes PM2.5 per year, about half of the total particle emission in Denmark, come from residential wood combustion. Based on a few measurement campaigns conducted...... in Denmark in selected residential areas with different kinds of heating, the annual average PM2.5 exposure from wood smoke can be estimated at 0.4–2 mg/m3 as a preliminary estimate for the whole Danish population. Epidemiological studies evaluating adverse health effects from ambient air pollution...

Pilot study on using an alternative method of estimating emission of heavy metals from wood combustion

Science.gov (United States)

Olszowski, Tomasz; Bożym, Marta

2014-09-01

This thesis presents pilot studies concerning the assessment of the possibility of using organic materials of vegetative origin as indices of heavy metals emissions (Cd, Cr, Cu, Ni, Pb and Zn) from domestic wood-fired fireplaces. Mosses of the Pleurozium schreberi species as well as cellulose and cotton wool were used during the study as the potential indices for the elements emission. It was proved that mosses are more reliable as indices of metals emissions than cellulose or cotton wool. It was found that the quantity of Ni accumulated in the moss tissue is comparable with the concentration of this compound in the dust assessed with the reference method. A correlation between the Ni, Cr, Zn and Pb concentrations defined in the mosses and dust filter was found. It was proved that mosses as adsorbers, more clearly than in the case of cellulose and cotton, react to the change of the size of the particulates emitted.

Development of newly designed wood burning systems with low emissions and high efficiency; Tehokkaan ja vaehaepaeaestoeisen puulaemmitysjaerjestelmaen kehittaeminen

Energy Technology Data Exchange (ETDEWEB)

Hyytiaeinen, H [Tulisydaen Oy, Vantaa (Finland)

1997-12-01

The investigations in the project will focus on the combustion behaviour of wood burning systems of untreated wood fuels with batch-wise and quasi-continuous mechanical feeding. The objectives will be to minimise the pollutant release of these combustion systems during the different operational phases by a consequent optimisation of the fuel burning technique and to reduce the CO release by increasing the efficiency of the combustion. To reduce the pollutant release during the operation phases and to increase the efficiency, products of incomplete combustion i.e. carbon monoxide, toxic organic compounds like benzene, polycyclic aromatic hydrocarbons and soot have to be minimised in a further extent. For that the following goals will be attained: improvement of the mixing process of combustion gases in the reaction zones, averaging the residence time spectrum in the burnout zone reduction, of emissions during initial and burnout phase in firings with batch-wise feeding reduction of emissions under partial-load conditions in firings with quasi-continuous feeding, higher combustion stability even in case of changing fuel qualities, defining guidelines for the design of stoves and boilers with low emissions and high efficiency. By the foreseen reduction of the pollutant release and improved efficiency the environmental acceptance of wood combustion firings can be increased and for instance local restrictions can be removed. The project is funded in part by The European Commission in the framework of The Non Nuclear Energy Programme. (orig.)

Co-combustion and gasification of various biomasses

Energy Technology Data Exchange (ETDEWEB)

Mutanen, K [A. Ahlstrom Corporation, Varkaus (Finland). Ahlstrom Pyropower

1997-12-31

During the last twenty years the development of fluidized bed combustion and gasification technology has made it possible to increase significantly utilisation of various biomasses in power and heat generation. The forerunner was the pulp and paper industry that has an adequate biomass fuel supply and energy demand on site. Later on municipalities and even utilities have seen biomass as a potential fuel. The range of available biomasses includes wood-based fuels and wastes like bark, wood chips, and saw dust, agricultural wastes like straw, olive waste and rice husk, sludges from paper mills and de-inking plants, other wastes like municipal sludges, waste paper and RDF. Recently new environmental regulations and taxation of fossil fuels have further increased interest in the use of biomasses in energy generation. However, in many cases available quantities and/or qualities of biomasses are not adequate for only biomass-based energy generation in an economic sense. On the other hand plant owners want to maintain a high level of fuel flexibility and fuel supply security. In some cases disposing by burning is the only feasible way to handle certain wastes. In many cases the only way to fulfil these targets and utilize the energy is to apply co-combustion or gasification of different fuels and wastes. Due to the fact that fluidized bed combustion technology offers a very high fuel flexibility and high combustion efficiency with low emissions it has become the dominating technology in co-combustion applications. This presentation will present Alhstrom`s experiences in co-combustion of biomasses in bubbling beds and Ahlstrom Pyroflow circulating fluidized beds based on about 200 operating references worldwide. CFB gasification will also be discussed 9 refs.

Co-combustion and gasification of various biomasses

Energy Technology Data Exchange (ETDEWEB)

Mutanen, K. [A. Ahlstrom Corporation, Varkaus (Finland). Ahlstrom Pyropower

1996-12-31

During the last twenty years the development of fluidized bed combustion and gasification technology has made it possible to increase significantly utilisation of various biomasses in power and heat generation. The forerunner was the pulp and paper industry that has an adequate biomass fuel supply and energy demand on site. Later on municipalities and even utilities have seen biomass as a potential fuel. The range of available biomasses includes wood-based fuels and wastes like bark, wood chips, and saw dust, agricultural wastes like straw, olive waste and rice husk, sludges from paper mills and de-inking plants, other wastes like municipal sludges, waste paper and RDF. Recently new environmental regulations and taxation of fossil fuels have further increased interest in the use of biomasses in energy generation. However, in many cases available quantities and/or qualities of biomasses are not adequate for only biomass-based energy generation in an economic sense. On the other hand plant owners want to maintain a high level of fuel flexibility and fuel supply security. In some cases disposing by burning is the only feasible way to handle certain wastes. In many cases the only way to fulfil these targets and utilize the energy is to apply co-combustion or gasification of different fuels and wastes. Due to the fact that fluidized bed combustion technology offers a very high fuel flexibility and high combustion efficiency with low emissions it has become the dominating technology in co-combustion applications. This presentation will present Alhstrom`s experiences in co-combustion of biomasses in bubbling beds and Ahlstrom Pyroflow circulating fluidized beds based on about 200 operating references worldwide. CFB gasification will also be discussed 9 refs.

Danish emission inventories for stationary combustion plants. Inventories until 2008

Energy Technology Data Exchange (ETDEWEB)

Nielsen, Malene; Nielsen, Ole-Kenneth; Plejdrup, M.; Hjelgaard, K.

2010-10-15

Emission inventories for stationary combustion plants are presented and the methodologies and assumptions used for the inventories are described. The pollutants considered are SO{sub 2}, NO{sub x}, NMVOC, CH{sub 4}, CO, CO{sub 2}, N{sub 2}O, NH{sub 3}, particulate matter, heavy metals, dioxins, HCB and PAH. The CO{sub 2} emission in 2008 was 16 % lower than in 1990. However, fluctuations in the emission level are large as a result of electricity import/export. The emission of CH{sub 4} has increased due to increased use of lean-burn gas engines in combined heating and power (CHP) plants. However, the emission has decreased in recent years due to structural changes in the Danish electricity market. The N{sub 2}O emission was higher in 2008 than in 1990 but the fluctuations in the time-series are significant. A considerable decrease of the SO{sub 2}, NO{sub x} and heavy metal emissions is mainly a result of decreased emissions from large power plants and waste incineration plants. The combustion of wood in residential plants has increased considerably in recent years resulting in increased emission of PAH, particulate matter and CO. The emission of NMVOC has increased since 1990 as a result of both the increased combustion of wood in residential plants and the increased emission from lean-burn gas engines. The dioxin emission decreased since 1990 due to flue gas cleaning on waste incineration plants. However in recent years the emission has increased as a result of the increased combustion of wood in residential plants. (Author)

Domestic Wood Burning in a Residential Area: PM2.5 Trace Elements and Black Smoke

International Nuclear Information System (INIS)

Molnar, P.; Gustafson, P.; Johannesson, S.; Barregaard, L.; Saellsten, G.; Boman, J.

2005-01-01

Indoor and outdoor levels of PM2.5 have been studied in a residential area in Hagfors, a small town in Sweden. The sampling took place during typical Swedish winter conditions with sub-zero temperatures and full snow cover between February 10th and Mars 6th, 2003. The area consists of single houses having different heating systems. Some of the houses are heated by burning wood; some use heat pumps while others use direct electrical heating. 13 houses burning wood in boilers or similar for heating and 10 houses heated by other means but situated in the same area were selected for this study. Only houses without tobacco smoke were selected since this is one of the major sources of indoor particles. The objectives of the study were to identify levels and differences in composition of aerosol particles outdoors and inside houses with boilers using wood as fuel and houses heated in other ways. For K, Ca, Mn, Zn and Rb significantly higher (p < 0.05) indoor concentration for wood burners were found. The elements most often referred to as markers for wood burning are K and Zn. In addition, Si, S, Cl, Br and Rb are also mentioned as markers (Hedberg et al., 2002, Moloi et al., 2003). Black smoke was linked to wood burning, although not fully significant (p-value 0.07), as seen in figure 1a. Within the wood-burning group, some houses have concentrations comparable to the concentrations in the houses where no wood is used, while the others have much higher concentrations. These houses also have higher concentrations of K compared to the other wood burners. The possible reasons are different types of wood burning appliances and their placement in the houses as well as possible leakage. Sulphur, although sometimes linked to wood burning, shows no relationship to wood burning in this study. In figure 1b it can be seen that the indoor concentrations of sulphur is clearly lower compared to outdoor concentrations and that the levels indoors do not differ between wood and non-wood

Wood-energy - The sector get worried

International Nuclear Information System (INIS)

Mary, Olivier; Signoret, Stephane; Bohlinger, Philippe; Guilhem, Jean; De Santis, Audrey; Sredojevic, Alexandre; Defaye, Serge; Maindrault, Marc

2017-01-01

Wood energy is, today and certainly also tomorrow, one of the most important renewable energies in France. However, the wood-energy sector seems to slow down as hydrocarbon prices stay extremely low. This document presents 8 articles, describing the context and the characteristics of this evolution, plus some examples of developments in France. The themes of the articles are: the activity of the wood-energy sector should be reinforced to meet the objectives of the French energy multi-year plan; The 2035 prospective of the wood yield in the French forest will meet the future demand, however this evaluation does not take into consideration the effects of the climatic change; the conversion to biomass of the 'Fort de l'Est' (near Paris) heating system (equipped with a boiling fluidized bed boiler) has enabled the heat network to beat the 50 pc share of renewable energy; wood-energy professionals use the 'quality' lever to challenge their fossil fuel competitors; the city of Orleans is now equipped with an innovative biomass cogeneration plant; the example of wood waste valorization in a French sawmill; the French ONF (Forest Administration) Wood-Energy actor has just inaugurated its largest biomass dryer, in order to develop the domestic market for wood as a fuel; analysis of the technical and economical feasibility of using wood to generate electric power or replacing electric space heating by heat network

Evaluation of cellular effects of fine particulate matter from combustion of solid fuels used for indoor heating on the Navajo Nation using a stratified oxidative stress response model

Science.gov (United States)

Li, Ning; Champion, Wyatt M.; Imam, Jemal; Sidhu, Damansher; Salazar, Joseph R.; Majestic, Brian J.; Montoya, Lupita D.

2018-06-01

Communities in the Navajo Nation face public health burdens caused in part by the combustion of wood and coal for indoor heating using stoves that are old or in disrepair. Wood and coal combustion emits particulate matter (PM) with aerodynamic diameter combustion-derived PM2.5 on Navajo Nation residents. This study tested the hypothesis that PM2.5 generated from solid fuel combustion in stoves commonly used by Navajo residents would induce stratified oxidative stress responses ranging from activation of antioxidant defense to inflammation and cell death in mouse macrophages (RAW 264.7). PM2.5 emitted from burning Ponderosa Pine (PP) and Utah Juniper (UJ) wood and Black Mesa (BM) and Fruitland (FR) coal in a stove representative of those widely used by Navajo residents were collected, and their aqueous suspensions used for cellular exposure. PM from combustion of wood had significantly more elemental carbon (EC) (15%) and soluble Ni (0.0029%) than the samples from coal combustion (EC: 3%; Ni: 0.0019%) and was also a stronger activator of antioxidant enzyme heme oxygenase-1 (11-fold increase vs. control) than that from coal (5-fold increase). Only PM from PP-wood (12-fold) and BM-coal (3-fold) increased the release of inflammatory cytokine tumor necrosis factor alpha. Among all samples, PP-wood consistently had the strongest oxidative stress and inflammatory effects. PM components, i.e. low-volatility organic carbon, EC, Cu, Ni and K were positively correlated with the cellular responses. Results showed that, at the concentrations tested, emissions from all fuels did not have significant cytotoxicity. These findings suggest that PM2.5 emitted from combustion of wood and coal commonly used by Navajo residents may negatively impact the health of this community.

INPUT DATA OF BURNING WOOD FOR CFD MODELLING USING SMALL-SCALE EXPERIMENTS

Directory of Open Access Journals (Sweden)

Petr Hejtmánek

2017-12-01

Full Text Available The paper presents an option how to acquire simplified input data for modelling of burning wood in CFD programmes. The option lies in combination of data from small- and molecular-scale experiments in order to describe the material as a one-reaction material property. Such virtual material would spread fire, develop the fire according to surrounding environment and it could be extinguished without using complex reaction molecular description. Series of experiments including elemental analysis, thermogravimetric analysis and difference thermal analysis, and combustion analysis were performed. Then the FDS model of burning pine wood in a cone calorimeter was built. In the model where those values were used. The model was validated to HRR (Heat Release Rate from the real cone calorimeter experiment. The results show that for the purpose of CFD modelling the effective heat of combustion, which is one of the basic material property for fire modelling affecting the total intensity of burning, should be used. Using the net heat of combustion in the model leads to higher values of HRR in comparison to the real experiment data. Considering all the results shown in this paper, it was shown that it is possible to simulate burning of wood using the extrapolated data obtained in small-size experiments.

Development of a Wood Powder Fuelled 35 kW Stirling CHP Unit

DEFF Research Database (Denmark)

Pålsson, M.; Carlsen, Henrik

2003-01-01

For biomass fuelled CHP in sizes below 100 kW, Stirling engines are the only feasible alternative today. Using wood powder as fuel, the Stirling engine can be heated directly by the flame like when using a gaseous or liquid fuel burner. However, the combustion chamber will have to be much larger...... recirculation (CGR) a smaller air preheater can be used, while system efficiency will increase compared with using excess air for flame cooling. In a three-year project, a wood powder fuelled Stirling engine CHP unit will be developed and run in field test. The project will use the double-acting four......-cylinder Stirling engine SM3D with an electric output of 35 kW. This engine is a further development of the engine SM3B that has been developed at the Technical University of Denmark. The engine heater is being adapted for use with wood powder as fuel. During a two-year period a combustion system for this engine...

The impact of co-combustion of polyethylene plastics and wood in a small residential boiler on emissions of gaseous pollutants, particulate matter, PAHs and 1,3,5- triphenylbenzene.

Science.gov (United States)

Tomsej, Tomas; Horak, Jiri; Tomsejova, Sarka; Krpec, Kamil; Klanova, Jana; Dej, Milan; Hopan, Frantisek

2018-04-01

The aim of this study was to simulate a banned but widely spread practice of co-combustion of plastic with wood in a small residential boiler and to quantify its impact on emissions of gaseous pollutants, particulate matter (PM), polycyclic aromatic hydrocarbons (PAHs), and 1,3,5-triphenylbenzene (135TPB), a new tracer of polyethylene plastic combustion. Supermarket polyethylene shopping bags (PE) and polyethylene terephthalate bottles (PET) were burnt as supplementary fuels with beech logs (BL) in an old-type 20 kW over-fire boiler both at a nominal and reduced heat output. An impact of co-combustion was more pronounced at the nominal heat output: an increase in emissions of PM, total organic carbon (TOC), toxic equivalent (TEQ) of 7 carcinogenic PAHs (c-PAHs) and a higher ratio of c-PAHs TEQ in particulate phase was observed during co-combustion of both plastics. 135TPB was found in emissions from both plastics both at a nominal and reduced output. In contrast to findings reported in the literature, 135TPB was a dominant compound detected by mass spectrometry on m/z 306 exclusively in emissions from co-combustion of PE. Surprisingly, six other even more abundant compounds of unknown identity were found on this m/z in emissions from co-combustion of PET. One of these unknown compounds was identified as p-quaterphenyl (pQ). Principal component analysis revealed strong correlation among 135TPB, pQ and five unknown compounds. pQ seems to be suitable tracers of polyethylene terephthalate plastic co-combustion, while 135TPB proved its suitability to be an all-purpose tracer of polyethylene plastics combustion. Copyright © 2017 Elsevier Ltd. All rights reserved.

Liquefaction of torrefied wood using microwave irradiation

Science.gov (United States)

Mengchao Zhou; Thomas Eberhardt; Pingping Xin; Chung-Yun Hse; Hui Pan

2016-01-01

Torrefaction is an effective pretreatment method to improve the uniformity and quality of lignocellulosic biomass before further thermal processing (e.g., gasification, combustion). The objective of this study was to determine the impacts of torrefaction as a pretreatment before liquefaction. Wood chips were torrefied for 2 h at three different temperatures (230, 260,...

Thermophotovoltaics, wood powder and fuel quality

Energy Technology Data Exchange (ETDEWEB)

Marks, J [Swedish Univ. of Agricultural Sciences, Uppsala (Sweden). Dept. of Operational Efficiency; Broman, L; Jarefors, K [Solar Energy Research Center, Borlaenge (Sweden)

1998-06-01

PV cells can be used for electricity production based on other heat sources than the sun. If the temperature of the source is around 1500 K it is possible to get reasonably high conversion efficiency from heat radiation to electricity. This is due to recent advances in low-bandgap PV cells and selectively emitting fibrous emissive burners. There are some different biomass fuels capable of producing this temperature in the flame, especially gas and liquid fuels of different kinds. Wood powder is the only solid wood fuel with a sufficiently stable quality and properties for this high temperature combustion. A joint project between SERC, SLU and National Renewable Energy Laboratory NREL in Golden, Colorado, USA aims at building a wood powder fuelled thermophotovoltaic (TPV) generator for cogeneration of heat and electricity. A stable flame temperature of 1500 K has been achieved in a prototype pilot-scale burner that includes feeder and combustion chamber. Furthermore, a setup for measuring TPV cell efficiency for a wide region of black body emitter temperatures and cell irradiation has been constructed and several 0.6 eV GaInAs TPV cells have been investigated. A setup for testing the chain IR emitter - selectively reflecting filter - TPV cell has been designed. In order to limit the region of filter incident angles, which will make the filter act more efficiently, a special geometry of the internally reflecting tube that transmits the radiation is considered 23 refs, 4 figs

Energy from wood - part 3: automatic wood furnaces; Holzenergie, Teil 3: automatische Holzfeuerungen - Energie du bois, Partie 3: installations automatiques de chauffage au bois

Energy Technology Data Exchange (ETDEWEB)

Nussbaumer, T. [Verenum, Zuerich (Switzerland)

2001-07-01

The paper gives an overview on the technologies and applications of automatic wood furnaces. The combustion systems are defined by the flow condition: With increasing gas velocity, fixed bed, stationary fluidized bed (SFB), circulating fluidized bed (CFB), and entrained flow reactors are distinguished. The furnace design and typical applications are described. Further, a comparison is presented which gives data of the typical size range and fuel types for the different combustion systems. The most common fixed bed reactors are under-stoker and grate furnaces. While under-stoker furnaces are applied in the size range from 20 kW to 2.5 MW, grate furnaces cover the size range from a few 100 kW up to more than 50 MW. Under-stoker furnaces are well suited for wood fuel with low ash content, moderate water content and limited fuel size. Grate furnaces are also suited for fuel with high ash and water content and large fuel sizes. Hence grate furnaces are nowadays most common. Due to the higher technical needs, fluidized bed reactors are dedicated to large-scale applications, typically > 5 MW for SFB and > 15 MW for CFB. Furthermore, fluidized bed combustion needs more intensive fuel pre-treatment, since the fuel size is smaller than < 10 mm. On the other hand, it enables very high combustion efficiency, the utilization of difficult fuels and fuel mixtures. Dust burners using forced-flow conditions are limited to the application of fine fuel particles such as saw dust and often applied in combination with a grate furnaces > 5 MW. Beside the combustion technology, the most relevant measures for process control and pollutant emission abatement are described. Automatic wood furnaces are relevant sources of nitric oxide emissions and of particulates smaller than 10 micron (PM 10). Hence electrostatic precipitators and fabric filters are applied for efficient particle removal in large plants, while only cyclones with limited efficiency are used in applications up to 2 to 5 MW

Survey regarding the prices of wood fuels over the 2014 - 2015 period - Synthesis

International Nuclear Information System (INIS)

Fautrad, Alice

2015-11-01

The study conducted by CODA Strategies contains, in a first part, the synthesis and the full report of the results of a survey realized in 2015 among distributors of wood fuels for domestic, commercial, industrial and collective housing purposes. A second report presents the 2014-2015 fuel prices for commercial, industrial and collective housing markets only. This report is based on data published by the CEEB and proposes a method to estimate the cost of delivery. A third report presents the 2014-2015 results of a survey realized among distributors of wood fuels for domestic purposes only. This report also presents data regarding wood pellets price, in order to place the French market in its international context. A last report presents a French/English synthesis of the the 2014-2015 survey results

Investigation of the particle size distribution and particle density characteristics of Douglas fir hogged fuel fly ash collected under known combustion conditions. Technical Progress Report No. 2

Energy Technology Data Exchange (ETDEWEB)

Lang, A.J.; Junge, D.C.

1978-12-01

The increased interest in wood as a fuel source, coupled with the increasing demand to control the emission generated by wood combustion, has created a need for information characterizing the emissions that occur for given combustion conditions. This investigation characterizes the carbon char and inorganic fly ash size and density distribution for each of thirty-eight Douglas fir bark samples collected under known conditions of combustion.

Electrodialytic remediation of fly ash from co-combustion of wood and straw

International Nuclear Information System (INIS)

Chen, Wan; Jensen, Pernille E.; Ottosen, Lisbeth M.; Kirkelund, Gunvor M.

2015-01-01

The heavy metal content in fly ash from biomass combustion, such as straw, wood and sludge, often needs reducing before the ash can be used as fertilizer for agricultural land or as a component in the production of construction materials. In this study, fly ash from a boiler fueled with wood chips and straw was treated either by electrodialytic remediation (EDR) directly or by a combination of EDR and pre-wash with distilled water to investigate the possibilities of reducing the heavy metal content and reusing nutrients as fertilizer and bulk material in construction materials. Different experimental set-ups were tested for EDR treatment primarily of Cd and Pb as well as of Cu and Zn. Elemental contents such as K, P and Ni were compared in ash samples before and after treatment. The results showed that pre-washing caused an increase in total concentrations of most heavy metals because the highly soluble fraction, mainly KCl and K 2 SO 4 , was removed. After EDR treatment, the Cd concentration was reduced to below 2 mg kg −1 in all ash samples with high and stable average removal of above 95%, no matter how high the initial concentration was. The amount of Pb removed varied from 12% to 67%. Even though Pb was extracted from the ash samples, its concentrations in the treated ash samples were elevated due to the ash dissolution, except in the case of pre-washed ash treated in a two-compartment EDR cell, where the mass of Pb removed was the highest with a final concentration of about 100 mg kg −1 . The two-compartment EDR cell probably performed better due to a fast acidification process. In addition, this process was less energy-consuming. However, the fast acidification did in turn affect the leaching property of the treated ash, such as As and Ni, exceeding the limiting concentrations. The EDR/pre-wash-EDR treated ash mainly contained quartz, and the X-ray diffraction (XRD) peaks of K salts had disappeared. This shows that the potassium fertilizer potential was

Programme wood/energy 2000-2006. Activity Report for 2000-2004

International Nuclear Information System (INIS)

2006-01-01

When ADEME launched its Wood fuel programme throughout all of France in late 1999, its aim was to guide this resource supply chain to maturity and stable development in all user sectors: domestic, multi-family housing, commercial/institutional and industrial applications. To this end the Wood fuel Programme 2000-2006 was assigned objectives and endowed with significant financial means for studies and coordination in order to support and carry out general-interest projects, piloted by ADEME. The stated goal was to replace fossil fuels, avoid carbon emissions and establish quality assurance standards for household firewood and wood-fired devices. This report makes a status of ADEME's Wood fuel programme for the 2000-2004 era: - Domestic heating: After a drop during the 1990's, figures since 1999 of sales of wood-fuel domestic heating equipment (closed heaters, glass-door fires and stoves) have shown a significant rise. On average over 30 years, wood consumption has risen to 7.2 million TOE (40 million cubic metres) per year; - Industry: It is thought there are 1000 wood-fired heaters (above 1 megawatt) used in French industry. These are found mainly in timber-based industries and in timber crushing plants. This amounts to a total power output of 2.5 gigawatts. In the primary and secondary wood processing industries, the increase in the number of wood-fired boilers and energy produced has reached 5% per year Results of a call for carbon energy projects (APEC) was 61 submitted of which 52 were selected; 9 projects pending (166.5 K of aid from ADEME); and 35 projects begun (1,649 K of aid from ADEME). - Local authority and service sector wood-fired heating systems: At the end of 2004, the number of local authority active boilers was 641, producing 430 megawatts. This is an increase of an average of 13% year on year since 2000. By the end of 2004, the target had already been met for the number of boilers being financed (1,090). By 2006 however we still need to generate a

Impacts of Combustion Conditions and Photochemical Processing on the Light Absorption of Biomass Combustion Aerosol.

Science.gov (United States)

Martinsson, J; Eriksson, A C; Nielsen, I Elbæk; Malmborg, V Berg; Ahlberg, E; Andersen, C; Lindgren, R; Nyström, R; Nordin, E Z; Brune, W H; Svenningsson, B; Swietlicki, E; Boman, C; Pagels, J H

2015-12-15

The aim was to identify relationships between combustion conditions, particle characteristics, and optical properties of fresh and photochemically processed emissions from biomass combustion. The combustion conditions included nominal and high burn rate operation and individual combustion phases from a conventional wood stove. Low temperature pyrolysis upon fuel addition resulted in "tar-ball" type particles dominated by organic aerosol with an absorption Ångström exponent (AAE) of 2.5-2.7 and estimated Brown Carbon contributions of 50-70% to absorption at the climate relevant aethalometer-wavelength (520 nm). High temperature combustion during the intermediate (flaming) phase was dominated by soot agglomerates with AAE 1.0-1.2 and 85-100% of absorption at 520 nm attributed to Black Carbon. Intense photochemical processing of high burn rate flaming combustion emissions in an oxidation flow reactor led to strong formation of Secondary Organic Aerosol, with no or weak absorption. PM1 mass emission factors (mg/kg) of fresh emissions were about an order of magnitude higher for low temperature pyrolysis compared to high temperature combustion. However, emission factors describing the absorption cross section emitted per kg of fuel consumed (m(2)/kg) were of similar magnitude at 520 nm for the diverse combustion conditions investigated in this study. These results provide a link between biomass combustion conditions, emitted particle types, and their optical properties in fresh and processed plumes which can be of value for source apportionment and balanced mitigation of biomass combustion emissions from a climate and health perspective.

Health effects assessment of exposure to particles from wood smoke

Energy Technology Data Exchange (ETDEWEB)

Nielsen, Elsa; Dybdahl, M [Technical Univ. of Denmark, National Food Institute, Dept. of Toxicology and Risk Assessment, Soeborg (Denmark); Larsen, Poul Bo [Danish Environmental Protection Agency, Copenhagen (Denmark)

2008-07-01

The number of residential wood burning devices has increased in Denmark during the latest years and it has been estimated that there in 2005 were about 551,000 wood stoves and about 48,000 wood boilers in Denmark. This has resulted in an increased exposure of the general Danish population to pollutants associated with residential wood smoke. New Danish monitoring results on particulate matter (PM) in ambient air have shown elevated PM levels in areas with many wood stoves, particularly during wintertime when wood burning is common. Due to the size distribution of wood smoke particles essentially all will be contained in the PM{sub 2.5} fraction. It has been estimated that about 17,665 tonnes PM{sub 2.5} per year (2005) in Denmark come from residential wood combustion. Therefore, there is an increasing concern that adverse human health effects might be associated with the increased exposure to residential wood smoke. This project has been set up in order to review the scientific literature concerning adverse health effects of pollutants associated with residential wood smoke with the main focus on particulate matter and to quantify and evaluate, if possible, the impact on human health of the increased exposure to particles in residential wood smoke. (au)

URBAN WOOD/COAL CO-FIRING IN THE NIOSH BOILERPLANT

Energy Technology Data Exchange (ETDEWEB)

James T. Cobb, Jr.; Gene E. Geiger; William W. Elder III; Thomas Stickle; Jun Wang; Hongming Li; William P. Barry

2002-06-13

During the third quarter, the experimental portion of the project was carried out. Three one-day tests using wood/coal blends of 33% wood by volume (both construction wood and demolition wood) were conducted at the NIOSH Boiler Plant (NBP). Blends using hammer-milled wood were operationally successful and can form the basis of Phase II. Emissions of SO{sub 2} and NOx decreased and that of CO increased when compared with combusting coal alone. Mercury emissions were measured and the mathematical modeling of mercury speciation reactions continued, yielding many interesting results. Material and energy balances for the test periods at the NBP, as well as at the Bellefield Boiler Plant, were prepared. Steps were taken to remove severe constraints from the Pennsylvania Switchgrass Energy and Conservation Project and to organize the supplying of landfill gas to the Bruceton federal complex. Two presentations were made to meetings of the Electric Power Research Institute and the National Energy Technology Laboratory.

Absorption cycle commercial refrigerator using wood burning cook stove; Geladeira de absorcao acionada por fogao a lenha

Energy Technology Data Exchange (ETDEWEB)

Pereira, Jose Tomaz Vieira; Martins, Gilberto [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Energia

1991-12-31

The current utilization of wood burning cook stoves in Brazil and the socio-economical profile of their users were surveyed. A traditional heavy-mass wood-burning cook stove was studied as a thermal equipment. Simple changes in the geometry of the combustion chamber were suggested to improve the cooking efficiency. A closed two-phase thermosyphon using water as working fluid was designed, built and connected between the combustion chamber of the cook stove and a depressurized absorption refrigeration system to determine the heat flux and the temperature level. A commercial refrigerator unit, using the absorption cycle, was coupled with the wood stove through the thermosyphon. The overall results of the coupling point to successful country-side applications. (author) 12 refs., 9 figs., 4 tabs.

Danish emission inventories for stationary combustion plants. Inventories until year 2007

Energy Technology Data Exchange (ETDEWEB)

Nielsen, Malene; Nielsen, Ole-Kenneth; Plejdrup, M.; Hjelgaard, K.

2009-10-15

Emission inventories for stationary combustion plants are presented and the methodologies and assumptions used for the inventories are described. The pollutants considered are SO{sub 2}, NO{sub x}, NMVOC, CH{sub 4}, CO, CO{sub 2}, N{sub 2}O, particulate matter, heavy metals, dioxins, HCB and PAH. The CO{sub 2} emission in 2007 was 10% lower than in 1990. However fluctuations in the emission level are large as a result of electricity import/export. The emission of CH{sub 4} has increased due to increased use of lean-burn gas engines in combined heating and power (CHP) plants. However the emission has decreased in recent years due to structural changes in the Danish electricity market. The N{sub 2}O emission was higher in 2007 than in 1990 but the fluctuations in the timeseries are significant. A considerable decrease of the SO{sub 2}, NO{sub x} and heavy metal emissions is mainly a result of decreased emissions from large power plants and waste incineration plants. The combustion of wood in residential plants has increased considerably in recent years resulting in increased emission of PAH, particulate matter and CO. The emission of NMVOC has increased since 1990 as a result of both the increased combustion of wood in residential plants and the increased emission from lean-burn gas engines. The dioxin emission decreased since 1990 due to flue gas cleaning on waste incineration plants. However in recent years the emission has increased as a result of the increased combustion of wood in residential plants. (author)

Fuel Wood Consumption and Species Degradation in South-Western Nigeria: The Ecological Relevance

Directory of Open Access Journals (Sweden)

Orimoogunje Oluwagbenga O.I.

2015-01-01

Full Text Available The continuous dependence of man on fuel and service wood has resulted in serious degradation of the fragile forest ecosystem. Therefore, this study evaluated the sources and patterns of fuel wood and examined the rate of consumption in the study area. This was with the aim to assess the ecological implications of fuelwood consumption on species degradation. The study utilized both, primary and secondary data. Information was extracted from topographic map on the scale of 1: 50,000 and satellites imageries that cover the study area. Questionnaire administration, field observation and weight measurement of fuel wood were carried out. The results showed that the sources of fuel wood for domestic cooking were forest, nearby bush and abandoned farm while the sources of domestic energy were fuel wood (61.17%, charcoal (27%, kerosene (10%, electricity (1.33% and gas (0.5%. Fuel wood for small scale industries were: forest (49.23%, farmland (34.62 and fallow land (16.15%. The trend of fuel wood consumption was on the high side from 1995 to 2011, it was 58% in 1995, 70% in 2000, 82% in 2005 and 92% in 2010 and 2011 respectively. Many valuable economic tree species such as Triplochiton scleroxylon, Nesogordonia papaverifera, and Cordia spp. are near their extinction. Animals such as antelope, wolf and fox are going into extinction while monkey, grasscutter, hare, rabbit were endemic in the study area. The study concluded that the patterns of fuel wood use and fuel wood saturation presents a great danger for biodiversity products and services.

Wood-Fired Boiler System Evaluation at Fort Stewart, GA

National Research Council Canada - National Science Library

Potts, Noel

2002-01-01

Part of the plan to modernize the central energy plant (CEP) at Fort Stewart, GA is focused on the installations wood-fired boiler, which provides steam for heating, cooling, and domestic hot water. The U.S...

The wood household furniture and kitchen cabinet industries: a contrast in fortune

Science.gov (United States)

William G. Luppold; Matthew S. Bumgardner

2009-01-01

In 1977, the value of wood household furniture shipments from domestic manufacturers exceeded kitchen cabinet shipments by 170 percent; conversely, in 2006 shipments of cabinets exceeded shipments of furniture by 78 percent. The most apparent reason for the decrease in domestic furniture shipments is the increase in furniture imports, whereas cabinet demand has...

Danish emission inventories for stationary combustion plants

DEFF Research Database (Denmark)

Nielsen, M.; Illerup, J. B.

Emission inventories for stationary combustion plants are presented and the methodologies and assumptions used for the inventories are described. The pollutants considered are: SO2, NOx, NMVOC, CH4, CO, CO2, N2O, particulate matter, heavy metals, dioxins and PAH. Since 1990 the fuel consumption...... in stationary combustion has increased by 12% - the fossil fuel consumption however only by 6%. Despite the increased fuel consumption the emission of several pollutants have decreased due to the improved flue gas cleaning technology, improved burner technology and the change of fuel type used. A considerable...... plants. The emission of PAH increased as a result of the increased combustion of wood in residential boilers and stoves. Uncertainties for the emissions and trends have been estimated....

Danish emission inventories for stationary combustion plants

DEFF Research Database (Denmark)

Nielsen, M.; Illerup, J. B.

Emission inventories for stationary combustion plants are presented and the methodologies and assumptions used for the inventories are described. The pollutants considered are SO2, NOX, NMVOC, CH4, CO, CO2, N2O, particulate matter, heavy metals, dioxins and PAH. Since 1990 the fuel consumption...... in stationary combustion has increased by 14% - the fossil fuel consumption however only by 8%. Despite the increased fuel consumption the emission of several pollutants has decreased due to the improved flue gas cleaning technology, improved burner technology and the change of fuel type used. A considerable...... plants. The emission of PAH increased as a result of the increased combustion of wood in residential boilers and stoves. Uncertainties for the emissions and trends have been estimated...

Dynamic simulation of a biomass domestic boiler under thermally thick considerations

NARCIS (Netherlands)

Gómez, M. A.; Porteiro, J.; De la Cuesta de Cal, Daniel; Patiño, D.; Míguez, J. L.

2017-01-01

A biomass combustion model with a thermally thick approach is presented and applied to the simulation of a commercial biomass domestic boiler. A subgrid scale model is used to divide the particles into several grid points, each representing one of the different combustion stages. These grid points

Online elemental analysis of process gases with ICP-OES: A case study on waste wood combustion

International Nuclear Information System (INIS)

Wellinger, Marco; Wochele, Joerg; Biollaz, Serge M.A.; Ludwig, Christian

2012-01-01

Highlights: ► Simultaneous measurements of 23 elements in process gases of a waste wood combustor. ► Mobile ICP spectrometer allows measurements of high quality at industrial plants. ► Continuous online measurements with high temporal resolution. ► Linear correlations among element concentrations in the raw flue gas were detected. ► Novel sampling and calibration methods for ICP-OES analysis of process gases. - Abstract: A mobile sampling and measurement system for the analysis of gaseous and liquid samples in the field was developed. An inductively coupled plasma optical emission spectrometer (ICP-OES), which is built into a van, was used as detector. The analytical system was calibrated with liquid and/or gaseous standards. It was shown that identical mass flows of either gaseous or liquid standards resulted in identical ICP-OES signal intensities. In a field measurement campaign trace and minor elements in the raw flue gas of a waste wood combustor were monitored. Sampling was performed with a highly transport efficient liquid quench system, which allowed to observe temporal variations in the elemental process gas composition. After a change in feedstock an immediate change of the element concentrations in the flue gas was detected. A comparison of the average element concentrations during the combustion of the two feedstocks showed a high reproducibility for matrix elements that are expected to be present in similar concentrations. On the other hand elements that showed strong differences in their concentration in the feedstock were also represented by a higher concentration in the flue gas. Following the temporal variations of different elements revealed strong correlations between a number of elements, such as chlorine with sodium, potassium and zinc, as well as arsenic with lead, and calcium with strontium.

Simulation of fuel demand for wood-gas in combustion engine

Directory of Open Access Journals (Sweden)

Botwinska Katarzyna

2017-01-01

Full Text Available In the era of the oil crisis and proceeding contamination of the natural environment, it is attempted to substitute fossil raw materials with alternative carriers. For many years, road transport has been considered as one of the main sources of the substances deteriorating air quality. Applicable European directives oblige the member states to implement biofuels and biocomponents into the general fuel market, however, such process is proceeding gradually and relatively slowly. So far, alternative fuels have been used on a large scale to substitute diesel fuel or petrol. Derivatives of vegetable raw materials, such as vegetable oils or their esters and ethanol extracted from biomass, are used to that end. It has been noticed that there is no alternative to LPG which, due to financial reasons, is more and more popular as fuel in passenger cars. In relation to solutions adopted in the past, it has been decided to analyse the option of powering a modern passenger car with wood gas - syngas. Such fuel has been practically used since the 1920's. To that end, a computer simulation created in SciLab environment was carried out. Passenger car Fiat Seicento, fitted with Fire 1.1 8V petrol engine with power of 40kW, whose parameters were used to prepare the model, was selected as the model vehicle. The simulation allows the determination of engine demand on the given fuel. Apart from the wood gas included in the title, petrol, methane and LPG were used. Additionally, the created model enables the determination of the engine power at the time of the indicated fuels supply. The results obtained in the simulation revealed considerable decrease in the engine power when the wood gas was supplied and the increased consumption of this fuel. On the basis of the analysis of the professional literature describing numerous inconveniences connected with the use of this fuel as well as the obtained results, it has been established that using the wood gas as alternative

Simulation of fuel demand for wood-gas in combustion engine

Science.gov (United States)

Botwinska, Katarzyna; Mruk, Remigiusz; Tucki, Karol; Wata, Mateusz

2017-10-01

In the era of the oil crisis and proceeding contamination of the natural environment, it is attempted to substitute fossil raw materials with alternative carriers. For many years, road transport has been considered as one of the main sources of the substances deteriorating air quality. Applicable European directives oblige the member states to implement biofuels and biocomponents into the general fuel market, however, such process is proceeding gradually and relatively slowly. So far, alternative fuels have been used on a large scale to substitute diesel fuel or petrol. Derivatives of vegetable raw materials, such as vegetable oils or their esters and ethanol extracted from biomass, are used to that end. It has been noticed that there is no alternative to LPG which, due to financial reasons, is more and more popular as fuel in passenger cars. In relation to solutions adopted in the past, it has been decided to analyse the option of powering a modern passenger car with wood gas - syngas. Such fuel has been practically used since the 1920's. To that end, a computer simulation created in SciLab environment was carried out. Passenger car Fiat Seicento, fitted with Fire 1.1 8V petrol engine with power of 40kW, whose parameters were used to prepare the model, was selected as the model vehicle. The simulation allows the determination of engine demand on the given fuel. Apart from the wood gas included in the title, petrol, methane and LPG were used. Additionally, the created model enables the determination of the engine power at the time of the indicated fuels supply. The results obtained in the simulation revealed considerable decrease in the engine power when the wood gas was supplied and the increased consumption of this fuel. On the basis of the analysis of the professional literature describing numerous inconveniences connected with the use of this fuel as well as the obtained results, it has been established that using the wood gas as alternative fuel is currently

Intelligent Heat System – high energy efficient wood stoves with low emissions

DEFF Research Database (Denmark)

Illerup, Jytte Boll; Nickelsen, Joachim; Hansen, Brian Brun

2016-01-01

This development and demonstration project conducted by HWAM A/S and DTU Chemical Engineering has contributed to the development of an automatically controlled wood stove (HWAM IHS), which is on the market today. The new digital control system ensures optimal combustion conditions by keeping...... compared to traditional manually controlled stoves. The tests also showed that in many cases it is impossible to visually tell if non-optimal combustion occurs. Also, in practice it is impossible to manually control the combustion air as fast and optimally as the automatically controlled air inlet valves...

Acquisition of wood fuel at the Joseph C. McNeil Generating Station

Energy Technology Data Exchange (ETDEWEB)

Kropelin, W. [Burlington Electric Dept., VT (United States)

1993-12-31

The Joseph C. McNeil Generating Station is the world`s largest single boiler, municipally-owned, wood-fired electrical generating plant. The 50 megawatt McNeil Station is located in Burlington, Vermont and is owned by several Vermont public and private electric utilities. The operator and majority owner is the City of Burlington Electric Department (BED). Wood fuel procurement for the McNeil Station has been conducted in an environmentally sensitive way. Harvesting is carried out in conformance with a comprehensive wood chip harvesting policy and monitored by professional foresters. Unpredictable levels of Station operation require rigid adherence to a wood storage plan that minimizes the risk of over heating and spontaneous combustion of stockpiled fuel.

Pollutant emissions of commercial and industrial wood furnaces

International Nuclear Information System (INIS)

Baumbach, G.; Angerer, M.

1993-03-01

Based on literature surveys, personal contacts to designers, manufactures and users of woold furnaces, as well as informations of experts from Austria and Switzerland, the used wood fuels and combustion techniques and the potentially by commercial and industrial wood burning emitted air pollutants are described; including the mechanism of pollutant formation, concentrations, and their environmental relevance. The actual situation in Baden-Wuerttemberg concerning the used wood fuels, the state of installed and operated furnaces and the amount of emitted pollutants is presented basing on informations of the 'Statistical Country Bureau' and a country-wide inquiry round the chimney-sweepers. In order to realize the described existing possibilities to reduce pollutant emissions the introduction of a general brand test and certification mode is proposed. (orig.). 53 figs., 118 refs [de

AFBnet - Wood and field energy information from Europe

International Nuclear Information System (INIS)

Alakangas, E.

2001-01-01

The objective of EU's ALTENER program is to promote the use of renewable energy sources. The European bioenergy network AFBnet produces and delivers information on bioenergy research and utilization of them in different countries. Import and export of biofuels, as well as the prices of biofuels in twenty European countries have been studied during past two years. The potential of combined heat and power generation with biofuels has also been estimated. The network has evaluated these projects and the factors, which have affected the successfulness and unsuccessfulness of the projects in different countries. In Finland the promotion of the utilization of wood fuels in municipal projects was evaluated in a 'Heat Entrepreneur competition' carried out first time in 2000. AFBnet analyzed the operation of 21 plants using mixed fuels as energy sources. One of the objectives was to collect information on experiences of production and processing phase of fuels at district heating and power plants in Finland, Italy, Austria, Portugal, Sweden, Germany and Denmark. The plants consumed different kinds of biofuels (industrial wood residues, straw and other agricultural wastes) and the mixture of them. Plants using different combustion technologies (grate, fluidized bed and pulverized fuel combustion, and biomass gasifiers). The consumption rate of wood and agricultural biofuels in plants was about 30% of the total fuel consumption. The main mixed fuel was coal, the share of which was 28% of the total. A detailed report has been published on all the plants. The reports analyze the fuel production and processing chains of the plants up to the boiler. Data was gathered also from the investments and maintenance costs of the plants. In EU countries there is no comprehensive survey on the prices of biofuels. Only Sweden publishes the prices of biofuels regularly. AFBnet collected in 1999 data on fuel prices, import and export of the fuels, and present utilization and potential of

Effects of species information and furniture price on consumer preferences for selected woods

Science.gov (United States)

Matthew Bumgardner; David Nicholls; Geoffrey Donovan

2007-01-01

Changing consumer tastes and species availability are influencing the design and manufacture of hardwood products. In addition, the globalization of wood product markets is exposing U.S. consumers to new species. This research evaluates consumer preferences for six domestic wood species--three from the eastern United States and three from the western United States. The...

Laboratory evaluation of the particle size effect on the performance of an elastomeric half-mask respirator against ultrafine combustion particles.

Science.gov (United States)

He, Xinjian; Grinshpun, Sergey A; Reponen, Tiina; Yermakov, Michael; McKay, Roy; Haruta, Hiroki; Kimura, Kazushi

2013-08-01

This study quantified the particle size effect on the performance of elastomeric half-mask respirators, which are widely used by firefighters and first responders exposed to combustion aerosols. One type of elastomeric half-mask respirator equipped with two P-100 filters was donned on a breathing manikin while challenged with three combustion aerosols (originated by burning wood, paper, and plastic). Testing was conducted with respirators that were fully sealed, partially sealed (nose area only), or unsealed to the face of a breathing manikin to simulate different faceseal leakages. Three cyclic flows with mean inspiratory flow (MIF) rates of 30, 85, and 135 L/min were tested for each combination of sealing condition and combustion material. Additional testing was performed with plastic combustion particles at other cyclic and constant flows. Particle penetration was determined by measuring particle number concentrations inside and outside the respirator with size ranges from 20 to 200 nm. Breathing flow rate, particle size, and combustion material all had significant effects on the performance of the respirator. For the partially sealed and unsealed respirators, the penetration through the faceseal leakage reached maximum at particle sizes >100 nm when challenged with plastic aerosol, whereas no clear peaks were observed for wood and paper aerosols. The particles aerosolized by burning plastic penetrated more readily into the unsealed half-mask than those aerosolized by the combustion of wood and paper. The difference may be attributed to the fact that plastic combustion particles differ from wood and paper particles by physical characteristics such as charge, shape, and density. For the partially sealed respirator, the highest penetration values were obtained at MIF = 85 L/min. The unsealed respirator had approximately 10-fold greater penetration than the one partially sealed around the bridge of the nose, which indicates that the nose area was the primary leak

Wood pellets. The cost-effective fuel

International Nuclear Information System (INIS)

Anon.

2001-01-01

The article is based on an interview with Juhani Hakkarainen of Vapo Oy. Wood pellets are used in Finland primarily to heat buildings such as schools and offices and in the home. They are equally suitable for use in larger installations such as district heating plants and power stations. According to him wood pellets are suitable for use in coal-fired units generating heat, power, and steam. Price-wise, wood pellets are a particularly competitive alternative for small coal-fired plants away from the coast. Price is not the only factor on their side, however. Wood pellets also offer a good environmental profile, as they burn cleanly and generate virtually no dust, an important plus in urban locations. The fact that pellets are a domestically produced fuel is an added benefit, as their price does not fluctuate in the same way that the prices of electricity, oil, coal, and natural gas do. The price of pellets is largely based on direct raw material and labour costs, which are much less subject to ups and downs

Effect of boron compounds on the thermal and combustion properties of wood-plastic composites

OpenAIRE

Altuntaş, Ertuğrul; Karaoğul, Eyyup; Alma, Mehmet Hakkı

2017-01-01

In this study, the thermal properties and fire resistancesof the wood plastic composites produced with waste lignocellulosic materialswere investigated. For this purpose, lignocellulosic waste, high densitypolyethylene, (HDPE) sodium borate (borax) and boric acid was used to producethe wood-plastic composites. A twin-screw extruder was used during theproduction of the wood plastic composites. The produced composite granule waspressed at 175 °C hot press. The effects of boric acid and borax ad...

The role of primary and secondary air on wood combustion in cookstoves

Science.gov (United States)

Kirch, Thomas; Birzer, Cristian H.; Medwell, Paul R.; Holden, Liam

2018-03-01

A two-stage solid fuel research furnace was used to examine the claim that through forced draught greater mixing and more complete combustion could be achieved. By varying the primary air (PA) and secondary air (SA) flow the influence on the combustion process was investigated. In the first part of the combustion, when the release of volatile compounds predominates, the variation of neither PA nor SA had a significant influence. In the second part when mainly char is oxidised an increase in both PA and SA lead to a rising nominal combustion efficiency (?)), with a greater impact observed with SA. Furthermore higher air flows caused the heat transfer, to a pot above the furnace, to decline. Therefore forced draught does lead to greater mixing and mitigation of emissions, but in the presented configuration a trade-off between a higher NCE and a lower heat transfer needs consideration.

Emission of harmful substances from the combustion of wood, straw and biogas; Schadstoffemissionen bei der Verbrennung von Stroh, Holz und Biogas

Energy Technology Data Exchange (ETDEWEB)

Seidel, Torben

2013-06-27

Wood combustion of solid fuels in stoves and furnaces is widely used for residential heating in Germany. Approximately 15 million of 40 million households own small-scale furnaces (Struschka M. 2008). Biomass burning as an alternative to fossil fuel heat supply might play an important role in the future to achieve a reduction of greenhouse gases, to counteract a possible shortage of fossil energy sources and, to achieve autonomy from fossil fuels in Germany. The growing contribution of energy from biomass burning can have adverse effects, such as higher emissions of elements and organic substances when compared to fossil fuels like oil and gas. In the present thesis, we used state-of-the-art furnaces to investigate to what extent harmful elements are exhausted into the atmosphere from the combustion of wood and straw. Besides the fuels, we analyzed all the resulting ashes - grate ash, deposits in the heat exchanger and electrostatic precipitator respectively and fly ash - to construct element fluxes and to calculate emissions normalized to energy input. The input/output balance calculations have shown that some elements - such as cadmium, zinc, tin, thallium, lead, bismuth and antimony - have very low recovery rates. These elements might be retained within the cooler zones of the furnace, in the chimney, or in the refractory lining material where samples could not be taken. Therefore we try to answer the question to what extent the refractory lining material can act as an element sink. Since other elements have excessively high recovery rates, we also investigated the question to what extent the refractory lining material can act as a source for some elements found in the ash. It can be taken as certain that the elements collected by the filters correspond to the element amount in the flue gas which is emitted into the ambient air. The pollutants are bound in fine (<1 μm) particles or gaseous compounds and can enter the lungs' alveoli and therefore poison the

Black clay. Domestic stove based on counter current combustion, a principle used during the Iron Age and utilized in a baking oven from the Middle Ages; Sortemuld; Braendovn med modstroemsforbraending et princip fra jernalderen anvendt i bageovne fra middelalderen

Energy Technology Data Exchange (ETDEWEB)

Lund, E.

1994-01-01

Sortemuld (Black clay) ovens, based on the counter-current combustion principle, were used during the Iron Age and throughout the following centuries. It is claimed that the use of this technique results in the wood fuel being burnt so quickly that the oven temperature remains so high and for such a long time that the heat will be retained in the walls of such clay ovens. Prototype ovens were constructed, based on this principle, and various types of wood fuel were burnt in them. About 20 - 40 kg of fuel was combusted with each firing which lasted from 2-4 hours, answering to 20 - 40 kW/hrs. The carbon dioxide content reached 0.1% at times. The designs and construction of the prototypes ovens are described in detail and their performance documented. The text is illustrated with diagrams and the results of the performance testing are given in detail. (AB)

Wood fuel from early thinning and plantation cleaning. Summary of an international review

International Nuclear Information System (INIS)

Puttock, D.

1998-01-01

This paper summaries the results of an international of wood fuel from early thinning and plantation cleaning. The economic and biological benefits from early thinning have been well documented. However, removing forest biomass during early stages of stand development from sites which are low in one or more nutrients may contribute a loss of nutrients and organic matter. Depending on the pre-thinning density and the thinning intensity, the potential yield of wood fuel from early thinning may be as much as 79 dry tons per hectare. Thus, wood fuel from the thinnings could be an important source of revenue to forest owners and would contribute to domestic energy requirements. Motor-manual felling predominates in early thinning, mainly due to the lack of appropriate technology for thinning small trees. However, the productivity of motor-manual felling is greatly affected by the initial stand density and declines dramatically at densities greater than 10 000 stems per ha. Under these conditions, purpose-built wood fuel harvesters with small-tree harvesting capability offer the greatest potential for increasing felling productivity and reducing the cost of wood fuel. The cost of wood fuel from early thinnings varies widely between countries from USD 25.00 - 87.50 per dry ton depending on stand conditions, harvesting system, transport distance, domestic tax rates, and stumpage prices. At the low end of this range, wood fuel chips from early thinning are competitive with wood fuel produced from mill waste, the residues from clearfell operations, or from later thinnings

Modeling JP-8 Fuel Effects on Diesel Combustion Systems

National Research Council Canada - National Science Library

Schihl, Peter; Hoogterp, Laura; Pangilinan, Harold; Schwarz, Ernest; Bryzik, Walter

2006-01-01

.... Since engine manufacturers rely solely on DF-2 for commercial vehicle applications most domestic industry, university, and national laboratory lead diesel engine combustion system research activities...

Emissions from residential combustion of different solid fuels. Roekgasemissioner vid anvaendning av olika fasta braenslen i smaaskaliga system

Energy Technology Data Exchange (ETDEWEB)

Rudling, L

1983-01-01

The emission from different types of solid fuels during combustion in residential furnaces and stoves has been investigated. The following fules were investigated: wood pellets, peat-bark pellets, wood chips, wood logs,wood-briquets, peat briquets, lignite briquets, fuel oil. Three different 20-25 kW boilers were used and one stove and one fire place. The flue gases were analysed for carbon dioxide, carbon monoxide, nitrogen oxides, hydrocarbons, particulates, tar and fluoranthen.

Direct radiative effect due to brownness in organic carbon aerosols generated from biomass combustion

International Nuclear Information System (INIS)

Rathod, T.D.; Sahu, S.K.; Tiwari, M.; Pandit, G.G.

2016-01-01

We report the enhancement in the direct radiative effect due the presence of Brown carbon (BrC) as a part of organic carbon aerosols. The optical properties of organic carbon aerosols generated from pyrolytic combustion of mango tree wood (Magnifera Indica) and dung cake at different temperatures were considered. Mie codes were used to calculate absorption and scattering coefficients coupled with experimentally derived imaginary complex refractive index. The direct radiative effect (DRE) for sampled organic carbon aerosols was estimated using a wavelength dependent radiative transfer equation. The BrC DRE was estimated taking virtually non absorbing organic aerosols as reference. The BrC DRE from wood and dung cake was compared at different combustion temperatures and conditions. The BrC contributed positively to the direct top of the atmosphere radiative effect. Dung cake generated BrC aerosols were found to be strongly light absorbing as compared to BrC from wood combustion. It was noted that radiative effects of BrC from wood depended on its generation temperature and conditions. For BrC aerosols from dung cake such strong dependence was not observed. The average BrC aerosol DRE values were 1.53±0.76 W g"−"1 and 17.84±6.45 W g"−"1 for wood and dung cake respectively. The DRE contribution of BrC aerosols came mainly (67–90%) from visible light absorption though they exhibited strong absorption in shorter wavelengths of the UV–visible spectrum. - Highlights: • Biomass fuels (wood and dung cake) were studied for brown carbon direct radiative effects. • Model calculations predicted positive contribution of Brown carbon aerosols to organic carbon direct radiative effect. • Average direct radiative values for brown carbon from dung cake were higher compare to wood. • The visible light absorption played major role in brown carbon contribution (67–90 %) to total direct radiative effect.

Experimental investigation of wood combustion in a fixed bed with hot air

NARCIS (Netherlands)

Markovic, Miladin; Bramer, Eduard A.; Brem, Gerrit

2014-01-01

Waste combustion on a grate with energy recovery is an important pillar of municipal solid waste (MSW) management in the Netherlands. In MSW incinerators fresh waste stacked on a grate enters the combustion chamber, heats up by radiation from the flame above the layer and ignition occurs. Typically,

Wood chemistry symposium: from muka to lignin

Energy Technology Data Exchange (ETDEWEB)

MacLeod, M.

1979-01-01

The Canadian Wood Chemistry Symposium held during September, 1979, is reviewed. The chemical and physical explanations of delignification were debated. Problems of mechanical pulping include insufficient brightness, yellowing, and low strength relative to energy consumption. A session on chemicals, energy, and food from wood began with criteria for a viable project, which included adequate return on investment, modest capital investment requirements, identified pre-existing markets, and favorable thermodynamic balances. The pulp and paper industry should improve its methods of using bark and wood waste in direct combustion (by pre-drying wastes and improving furnace efficiency) rather than supporting oil-from-wood projects, since using a waste for fuel will free fossil fuels for uses in synthetic fibers and thermoplastics. In the area of food, there are modest successes with cellulose fiber additives to bread and snack food and single cell protein (which, though made from wastes, cannot compete with soy protein). However, making monomeric sugars from wood polysaccharides is not an efficient process, and muka, animal feed supplement from foliage, is successful only in Russia. In Canada it cannot compete with agricultural products. Alpha cellulose is a major wood chemical product. Promising uses include cellulose derived thermoplastics and lignosulphonates for secondary oil recovery. Instead of breaking wood polysaccharides and lignin into monomers and then repolymerizing them, it is possible to use the pre-built polymers; such an approach is illustrated by use of lignin in polyurethane foams, adhesives, and coatings.

A Fire-Retardant Composite Made from Domestic Waste and PVA

Directory of Open Access Journals (Sweden)

Neni Surtiyeni

2016-01-01

Full Text Available We report the synthesis of a composite from domestic waste with the strength of wood building materials. We used original domestic waste with only a simple pretreatment to reduce the processing cost. The wastes were composed of organic components (generally originating from foods, paper, plastics, and clothes; the average fraction of each type of waste mirrored the corresponding fractions of wastes in the city of Bandung, Indonesia. An initial survey of ten landfills scattered through Bandung was conducted to determine the average fraction of each component in the waste. The composite was made using a hot press. A large number of synthesis parameters were tested to determine the optimum ones. The measured mechanical strength of the produced composite approached the mechanical properties of wood building materials. A fire-retardant powder was added to retard fire so that the composite could be useful for the construction of residential homes of lower-income people who often have problems with fire. Fire tests showed that the composites were more resistant to fire than widely used wood building materials.

Technological physics and special materials: wood-plastic composites obtained by radiation polymerization

International Nuclear Information System (INIS)

Peteu, Gh.; Iliescu, V.

1995-01-01

General estimates and references are made in connection with the role of technological physics in obtaining materials with specific features. The first part of the paper presents the modification of weak wood essences as well as technological processes at bench-scale and semi industrial scale of wood-plastic composites, under various irradiation conditions. Two technological installations for the fabrication of wood-plastic composites on both scales with technical and practical specifications of their performances are presented. Experimental data for different wood-plastic composite systems using some local wood essences in combination with several polymer and copolymer systems are given. Impregnation and polymerization levels are mentioned for every specific system. The radiation dose rate and integrated dose are given for every experimental polymerization system. The features of the wood-plastic composites are compared with the initial wood essences. Finally, a few technical and economic assessments of wood-plastic composites and their implications in the domestic economy are presented. (author)

Impact of impregnation with boron compounds on combustion ...

African Journals Online (AJOL)

This study examined the impacts of varnishing after impregnation with boron compounds on combustion properties of oriental beech. The test samples prepared from oriental beech (Fagus orientalis Lipsky) wood were impregnated according to ASTM D 1413–76–99 with boric acid (Ba) or borax (Bx) using a vacuum ...

Use of wood as an energy source in the state of Maine

Energy Technology Data Exchange (ETDEWEB)

von Foerster, T.

1978-09-01

A detailed study is presented of the availability and use of wood as an energy resource for the State of Maine. Although there are no good data on the total resources of Maine's forests, the best estimates indicate that one could obtain about 1/2 quad (10/sup 15/ Btu) per year from thinning overstocked stands and harvesting dead trees; current logging operations could produce about the same amount of energy in the form of logging residues and thinnings, an amount that could be increased manyfold by intensive forest management. The costs of wood for fuel can be estimated on the basis of current logging and transportation costs. The corresponding energy prices, while high, are competitive with current fossil fuel prices. Using any energy source requires not only the fuel but also a furnace. The total energy costs are thus not only the cost of current fuel use but also those of the capital investment in the furnace. We have estimated these for systems of two sizes, one for a small house, the other for an apartment building or small commercial establishment. In both cases, our estimated indicate, that woodfueled systems can be economically competitive. Wood is currently used as a fuel on a large scale in the pulp and paper industry. With some increase in wood harvesting efforts and some alterations of furnaces that industry could achieve energy self sufficiency. Other large-scale uses are still speculative but deserve further investigation. A state-owned energy corporation could serve to provide a market for currently wasted wood and to investigate the conversion of wood to other forms of energy. The combustion of wood is not associated with environmental effects that are different kind in magnitude from those associated with the combustion of fossil fuel.

Fluidized bed combustion of low-grade coal and wastes: Research and development

Energy Technology Data Exchange (ETDEWEB)

Borodulya, V.A.; Dikalenko, V.I.; Palchonok, G.I.; Vinogradov, L.M. [Academy of Sciences of Belarus, Minsk (Belarus). A.V. Luikov Heat and Mass Transfer Inst.; Dobkin, S.M.; Telegin, E.M. [Special Design Office, Brest (Belarus)

1994-12-31

Experimental studies were carried out to investigate devolatilization of fuel as single spherical particles of wood, hydrolytic lignin, leather sewage sludge and Belarussian brown coals in a fluidized bed of sand. It is found that the devolatilization process depends on moisture and ash contents in fuel and on the external heat and mass transfer rate. The char combustion occurs largely in the intermediate region. Kinetic parameters of the devolatilization and char combustion are obtained. A low-capacity fluidized bed boiler suitable for combustion of coal and different wastes is described.

Wood pyrolysis oil for diesel engines

Energy Technology Data Exchange (ETDEWEB)

Paro, D.; Gros, S.; Hellen, G.; Jay, D.; Maekelae, T.; Rantanen, O.; Tanska, T. [Wartsila Diesel International Ltd Oy, Vaasa (Finland)

1996-12-01

Wood Pyrolysis oil (WPO) has been identified by the Technical Research Centre of Finland (VTT) as the most competitive biofuel product which can be produced from biomass. The fuel is produced by a fast pyrolysis technique, using wood chipping`s or sawdust. The process can be applied to other recycling products such as straw etc. The use of WPO as a Diesel power plant fuel has been studied, and a fuel specification has been developed. The fuel characteristics have been analysed. There are several fuel properties addressed in the paper which have had to be overcome. New materials have been used in the fuel injection system. The fuel injection system development has progressed from a pump-line-pipe system to a common rail system. The fuel requires a pilot fuel oil injection to initiate combustion. The targets for the fuel injection system have been 1500 bar and 30 deg C injection period with a fuel of 15 MJ/kg lower heating value and 1220 Kg/m{sup 3} density. The combustion characteristics from both a small 80 mm bore engine initially, and then later with a single cylinder test of a 320 mm bore Waertsilae engine, have been evaluated. (author)

Crescimento da firma e comércio exterior: revisitando a teoria de Adrian Wood Growth of the firm and foreign trade: Adrian Wood's theory revisited

Directory of Open Access Journals (Sweden)

Fabrício Catermol

2006-06-01

Full Text Available This paper analyzes the growth of the firm by foreign trade. The theory of Adrian Wood is revisited for the analysis of growth and profit trade-off and improved to cope with growth by exports. The main outcome of this paper is that low domestic demand can be a very important factor to firm choices growth by foreign market. However, the growth of domestic demand does not necessarily reduce exports.

A chemometric investigation of aromatic emission profiles from a marine engine in comparison with residential wood combustion and road traffic: Implications for source apportionment inside and outside sulphur emission control areas

Science.gov (United States)

Czech, Hendryk; Stengel, Benjamin; Adam, Thomas; Sklorz, Martin; Streibel, Thorsten; Zimmermann, Ralf

2017-10-01

Ship emissions are known to cause severe impacts on human health, but are less restricted than land-based emissions. A regulation to improve air quality in coastal regions and frequented waterways is the limitation of fuel sulphur content to 0.1% in sulphur emission control areas (SECAs), which has caused a switch from heavy fuel oil (HFO) towards diesel-like marine gas oil (MGO) or marine diesel oil (MDO). The fraction of aromatic organic vapours in the exhaust from a marine engine, operating on HFO and MGO, was investigated by resonance-enhanced multi-photon ionisation time-of-flight mass spectrometry (REMPI-TOFMS). MGO with fuel sulphur content (FSC) below 0.1% and HFO with an average FSC of 2.7% denote representative marine fuels inside and outside SECAs, respectively. The obtained emission spectra were combined with data of previous REMPI-TOFMS studies of combustion engines and wood combustion in statistical analyses to derive marker substances for ship emissions inside and outside SECAs. A diagnostic ratio of C2-naphthalenes to methyl-naphthalenes was found to hold for a good discriminator between ship emissions on the one hand and road traffic and wood combustion on the other hand. Furthermore, random REMPI spectra from all emission sources were mixed with different proportions in a simulation to create a model based on partial least square (PLS) regression for the prediction of ship contribution to aromatic organic vapours. We point out that in particular PAHs with higher degree of alkylation are significant markers for primary ship emissions which may support source apportionment studies inside and outside SECAs to assess the benefits of fuel sulphur content regulation on air quality.

Wood burning pollution in southern Chile: PM2.5 source apportionment using CMB and molecular markers.

Science.gov (United States)

Villalobos, Ana M; Barraza, Francisco; Jorquera, Héctor; Schauer, James J

2017-06-01

Temuco is a mid-size city representative of severe wood smoke pollution in southern Chile; i.e., ambient 24-h PM 2.5 concentrations have exceeded 150 μg/m 3 in the winter season and the top concentration reached 372 μg/m 3 in 2010. Annual mean concentrations have decreased but are still above 30 μg/m 3 . For the very first time, a molecular marker source apportionment of ambient organic carbon (OC) and PM 2.5 was conducted in Temuco. Primary resolved sources for PM 2.5 were wood smoke (37.5%), coal combustion (4.4%), diesel vehicles (3.3%), dust (2.2%) and vegetative detritus (0.7%). Secondary inorganic PM 2.5 (sulfates, nitrates and ammonium) contributed 4.8% and unresolved organic aerosols (generated from volatile emissions from incomplete wood combustion), including secondary organic aerosols, contributed 47.1%. Adding the contributions of unresolved organic aerosols to those from primary wood smoke implies that wood burning is responsible for 84.6% of the ambient PM 2.5 in Temuco. This predominance of wood smoke is ultimately due to widespread poverty and a lack of efficient household heating methods. The government has been implementing emission abatement policies but achieving compliance with ambient air quality standards for PM 2.5 in southern Chile remains a challenge. Copyright © 2017 Elsevier Ltd. All rights reserved.

Waste wood as bioenergy feedstock. Climate change impacts and related emission uncertainties from waste wood based energy systems in the UK.

Science.gov (United States)

Röder, Mirjam; Thornley, Patricia

2018-04-01

Considering the urgent need to shift to low carbon energy carriers, waste wood resources could provide an alternative energy feedstock and at the same time reduce emissions from landfill. This research examines the climate change impacts and related emission uncertainties of waste wood based energy. For this, different grades of waste wood and energy application have been investigated using lifecycle assessment. Sensitivity analysis has then been applied for supply chain processes and feedstock properties for the main emission contributing categories: transport, processing, pelletizing, urea resin fraction and related N 2 O formation. The results show, depending on the waste wood grade, the conversion option, scale and the related reference case, that emission reductions of up to 91% are possible for non-treated wood waste. Compared to this, energy from treated wood waste with low contamination can achieve up to 83% emission savings, similar to untreated waste wood pellets, but in some cases emissions from waste wood based energy can exceed the ones of the fossil fuel reference - in the worst case by 126%. Emission reductions from highly contaminated feedstocks are largest when replacing electricity from large-scale coal and landfill. The highest emission uncertainties are related to the wood's resin fraction and N 2 O formation during combustion and, pelletizing. Comparing wood processing with diesel and electricity powered equipment also generated high variations in the results, while emission variations related to transport are relatively small. Using treated waste wood as a bioenergy feedstock can be a valid option to reduce emissions from energy production but this is only realisable if coal and landfill gas are replaced. To achieve meaningful emission reduction in line with national and international climate change targets, pre-treatment of waste wood would be required to reduce components that form N 2 O during the energy conversion. Copyright © 2017

Scale-up study on combustibility and emission formation with two biomass fuels (B quality wood and pepper plant residue) under BFB conditions

Energy Technology Data Exchange (ETDEWEB)

Khan, Atif Ahmed; de Jong, Wiebren; Jansens, Peter Johannes [Department of Process and Energy, Section Energy Technology, Faculty 3ME, Delft University of Technology, Leeghwaterstraat 44, NL-2628 CA, Delft (Netherlands); Aho, Martti; Vainikka, Pasi [VTT Processes, P.O. Box 1603, 40101 Jyvaeskylae (Finland); Spliethoff, Hartmut [TU Munich, Lehrstuhl fuer Thermische Kraftanlagen, Boltzmannstrasse 15, D-85748 Garching (Germany)

2008-12-15

Combustion of two biomass fuels: demolition wood (DW) and pepper plant residue (PPR), was investigated from an emission viewpoint in a 20 kW{sub th} fluidized bubbling bed reactor and a 1 MW{sub th} fluidized bubbling bed test boiler. Fluidization velocity and boiler output were varied in the larger facility whereas they were kept constant in the smaller reactor. Traditional flue gases were analyzed. In addition, impactor measurements were carried out to determine the mass flow of the finest fly ash and toxic elements. These measurements were compared with EU emission directives for biomass co-incineration. It was possible to combust DW without operational problems. However, the DW was contaminated with lead, which tended to get strongly enriched in the fine fly ash. Pb tends to be adsorbed on the measurement line surfaces stronger than many other toxic elements and therefore proved difficult to collect and measure. Enrichment of Pb in the fine fly ash can be weakened by co-firing DW with PPR. Increasing the share of PPR up to 50% markedly reduces the toxic metal concentration in the finest fly ash. This, however, leads to increased mass flow of fine fly ash and increases the potential risks of operational problems such as bed agglomeration and fouling. (author)

Oxygen Carrier Aided Combustion (OCAC of Wood Chips in a Semi-Commercial Circulating Fluidized Bed Boiler Using Manganese Ore as Bed Material

Directory of Open Access Journals (Sweden)

Magnus Rydén

2016-11-01

Full Text Available Oxygen Carrier Aided Combustion (OCAC is realized by using an active oxygen-carrying bed material in fluidized bed boilers. The active material is reduced in fuel rich parts of the boiler and oxidized in air rich parts. Advantages could be achieved such as new mechanisms for oxygen transport in space and time. Here calcined manganese ore has been used as active bed material in a 12 MWth circulating fluidized bed boiler. The fuel was wood chips and the campaign lasted more than two weeks. From an operational point of view, manganese ore worked excellently. From the temperature profile of the boiler it can be concluded that fuel conversion was facilitated, especially in the dense bottom bed. The effect did not always translate to reduced emissions, which suggests that final combustion in the cyclone outlet was also influenced. Substituting 10% of the sand bed with manganese ore made it possible to reduce the air to fuel ratio without generating large amounts of CO. The use of 100% manganese ore resulted in higher emissions of CO than the sand reference, but, when combined sulphur feeding, dramatic reductions in CO emissions, up to 90% compared to sand reference, was achieved.

Growth of the firm and foreign trade: Adrian Wood's theory revisited

OpenAIRE

Catermol, Fabrício

2006-01-01

This paper analyzes the growth of the firm by foreign trade. The theory of Adrian Wood is revisited for the analysis of growth and profit trade-off and improved to cope with growth by exports. The main outcome of this paper is that low domestic demand can be a very important factor to firm choices growth by foreign market. However, the growth of domestic demand does not necessarily reduce exports.

Influence of moisture content of combusted wood on the thermal efficiency of a boiler

Science.gov (United States)

Dzurenda, Ladislav; Banski, Adrián

2017-03-01

In the paper the influence of moisture content of wood on the heat losses and thermal efficiency of a boiler is analysed. The moisture content of wood has a negative effect, especially on flue gas loss. The mathematical dependence of the thermal efficiency of a boiler is presented for the following boundary conditions: the moisture content of wood 10-60%, range of temperatures of emitted flue gases from the boiler into the atmosphere 120-200 C, the emissions meeting the emission standards: carbon monoxide 250 mgm-3, fly ash 50 mgm-3 and the heat power range 30-100%.

Influence of moisture content of combusted wood on the thermal efficiency of a boiler

Directory of Open Access Journals (Sweden)

Dzurenda Ladislav

2017-03-01

Full Text Available In the paper the influence of moisture content of wood on the heat losses and thermal efficiency of a boiler is analysed. The moisture content of wood has a negative effect, especially on flue gas loss. The mathematical dependence of the thermal efficiency of a boiler is presented for the following boundary conditions: the moisture content of wood 10-60%, range of temperatures of emitted flue gases from the boiler into the atmosphere 120-200 C, the emissions meeting the emission standards: carbon monoxide 250 mgm−3, fly ash 50 mgm−3 and the heat power range 30-100%.

Efficiency analysis of wood processing industry in China during 2006-2015

Science.gov (United States)

Zhang, Kun; Yuan, Baolong; Li, Yanxuan

2018-03-01

The wood processing industry is an important industry which affects the national economy and social development. The data envelopment analysis model (DEA) is a quantitative evaluation method for studying industrial efficiency. In this paper, the wood processing industry of 8 provinces in southern China is taken as the study object, and the efficiency of each province in 2006 to 2015 was measured and calculated with the DEA method, and the efficiency changes, technological changes and Malmquist index were analyzed dynamically. The empirical results show that there is a widening gap in the efficiency of wood processing industry of the 8 provinces, and the technological progress has shown a lag in the promotion of wood processing industry. According to the research conclusion, along with the situation of domestic and foreign wood processing industry development, the government must introduce relevant policies to strengthen the construction of the wood processing industry technology innovation policy system and the industrial coordinated development system.

Wood-burning appliances and indoor air quality

Energy Technology Data Exchange (ETDEWEB)

Levesque, Benoit; Allaire, Sylvain; Gauvin, Denis; Gingras, Suzanne; Rhainds, Marc; Prud' Homme, Henri; Duchesne, Jean-Francois [CHUQ-Centre de Recherche du CHUL, Unite de Recherche en Sante Publique, 2400, d' Estimauville, Beauport, G1E 7G9 Quebec (Canada); Koutrakis, Petros [Harvard School of Public Health, 677 Huntington Avenue, Boston, MA 02115 (United States)

2001-12-17

Wood heating represents an interesting economic alternative to electrical or heating oil and gas systems. However, many people are concerned about poor indoor air quality in homes equipped with wood-burning appliances. We conducted a study in the Quebec City region (Canada) to verify the extent of indoor air contamination, and to examine the frequency of respiratory symptoms and illnesses among occupants of wood-heated homes. One child attending primary school (median=8 years old; range=5-14 years old) and an adult (median=37 years old; range=23-52 years old) were recruited in each eligible house. Eligible houses were without known sources of combustion products (smokers, attached garage, oil or gas furnace, gas stove, etc.) except for wood-burning appliance. Out of the 89 houses included in the study, 59 had wood-burning appliances. Formaldehyde, nitrogen dioxide, respirable particles (PM10) and carbon monoxide were measured in a sub-set of 49 houses (41 with a wood-burning appliance and 8 without). The frequency of respiratory symptoms and diseases among participants were documented using a daily symptom diary. Concentrations of contaminants were low in most houses, both with or without a wood-burning appliance. Globally, there was no consistent relationship between the presence of a wood-burning appliance and respiratory morbidity in residents. Nevertheless, residents who mentioned being exposed to fumes emitted by such an appliance reported more respiratory illnesses and symptoms. The presence of animals or molds, and keeping windows closed most of the time in winter were other factors associated with respiratory problems. We conclude that wood burning appears to be a respiratory health risk for occupants if the appliance is not maintained and used properly.

CCA-treated wood disposed in landfills and life-cycle trade-offs with waste-to-energy and MSW landfill disposal.

Science.gov (United States)

Jambeck, Jenna; Weitz, Keith; Solo-Gabriele, Helena; Townsend, Timothy; Thorneloe, Susan

2007-01-01

Chromated copper arsenate (CCA)-treated wood is a preservative treated wood construction product that grew in use in the 1970s for both residential and industrial applications. Although some countries have banned the use of the product for some applications, others have not, and the product continues to enter the waste stream from construction, demolition and remodeling projects. CCA-treated wood as a solid waste is managed in various ways throughout the world. In the US, CCA-treated wood is disposed primarily within landfills; however some of the wood is combusted in waste-to-energy (WTE) facilities. In other countries, the predominant disposal option for wood, sometimes including CCA-treated wood, is combustion for the production of energy. This paper presents an estimate of the quantity of CCA-treated wood entering the disposal stream in the US, as well as an examination of the trade-offs between landfilling and WTE combustion of CCA-treated wood through a life-cycle assessment and decision support tool (MSW DST). Based upon production statistics, the estimated life span and the phaseout of CCA-treated wood, recent disposal projections estimate the peak US disposal rate to occur in 2008, at 9.7 million m(3). CCA-treated wood, when disposed with construction and demolition (C&D) debris and municipal solid waste (MSW), has been found to increase arsenic and chromium concentrations in leachate. For this reason, and because MSW landfills are lined, MSW landfills have been recommended as a preferred disposal option over unlined C&D debris landfills. Between landfilling and WTE for the same mass of CCA-treated wood, WTE is more expensive (nearly twice the cost), but when operated in accordance with US Environmental Protection Agency (US EPA) regulations, it produces energy and does not emit fossil carbon emissions. If the wood is managed via WTE, less landfill area is required, which could be an influential trade-off in some countries. Although metals are concentrated

Fluidized bed combustion with the use of Greek solid fuels

Directory of Open Access Journals (Sweden)

Kakaras Emmanuel

2003-01-01

Full Text Available The paper is an overview of the results obtained up to date from the combustion and co-combustion activities with Greek brown coal in different installations, both in semi-industrial and laboratory scale. Combustion tests with Greek lignite were realized in three different Circulating Fluidized Bed Combustion (CFBC facilities. Low rank lignite was burned in a pilot scale facility of approx. 100kW thermal capacity, located in Athens (NTUA and a semi-industrial scale of 1.2 MW thermal capacity, located at RWE's power station Niederaussem in Germany. Co-combustion tests with Greek xylitic lignite and waste wood were carried out in the 1 MWth CFBC installation of AE&E, in Austria. Lab-scale co-combustion tests of Greek pre-dried lignite with biomass were accomplished in a bubbling fluidized bed in order to investigate ash melting problems. The obtained results of all aforementioned activities showed that fluidized bed is the appropriate combustion technology to efficiently exploit the low quality Greek brown coal either alone or in conjunction with biomass species.

Scaling housing interventions for wood-burning stoves worldwide

DEFF Research Database (Denmark)

Luis Teles de Carvalho, Ricardo; Jensen, Ole Michael; da Cruz Tarelho, Luís António

2013-01-01

The wood-burning stove is the most popular energy technology in the world since about 3 billion people rely on it for both domestic cooking and heating purposes. It is estimated that in 2030 more than 200 million people will be affected by this abundant energy source. Large-scale clean stove prog...

Air pollution from residential wood combustion in a Danish village. Measuring campaign and analysis of results

Energy Technology Data Exchange (ETDEWEB)

Waahlin, P; Roerdam Olesen, H; Bossi, R; Stubkjaer, J

2010-05-15

A campaign took place in the winter 2006/2007 comprising measurements of many air pollution components at two sites: a wood smoke exposed site within the village Slagslunde, and a background site 500 m outside of the village. The report describes the campaign and its results. A central result is a so-called 'wood smoke source profile', which relates several measures of wood smoke pollution to each other. This is based on a 'cleaned' data set, for which the effect of other sources than wood smoke was small. The wood smoke profile links the measures PM2.5, particle volume, soot, monosaccharide anhydrides (levoglucosan and mannosan) and different PAHs to each other. Particle number N does not have a close link to the other measures. (author)

Co-combustion of gasified contaminated waste wood in a coal fired power plant

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-07-01

This project demonstrates the technical and economical feasibility of the producing and cofiring of product gas from demolition waste wood. For this purpose LCV product gas is generated in an atmospheric circulating fluidized bed (CFB) gasification plant, cooled and cleaned and transported to the boiler of a 600 MWe pulverized coal fired power plant. Gas cooling and cleaning takes place in a waste heat boiler and a multi stage wet gas cleaning train. Steam raised in the waste heat boiler is exported to the power plant. On an annual basis 70,000 tons of steam coal are substituted by 150,000 tons of contaminated demolition waste wood (50,000 tons oil equivalent), resulting in a net CO2 emission reduction of 170,000 tons per year, while concurrently generating 205 GWh of electrical power. The wood gasification plant was built by NV EPZ (now incorporated in Essent Energi BV) for Amergas BV, now a 100% subsidiary of Essent Energie BV. The gasification plant is located at the Amer Power Station of NV EPZ Production (now Essent Generation) at Geertruidenberg, The Netherlands. Demonstrating several important design features in wood gasification, the plant started hot service in the Spring of 2000, with first gasification accomplished in the Summer of 2000 and is currently being optimized. (au)

World trade in forest products and wood fuel

International Nuclear Information System (INIS)

Hillring, Bengt

2006-01-01

Wood fuel is a strategic resource for future energy supply and is usually utilised locally. Traditional use of wood fuel and other bioenergy has a share of 10-15% energy supply, used mainly for the household sector. The utilisation for industrial purposes is much smaller but is a strategic resource in the effort to fulfil the Kyoto agreement to replace fossil fuels and to mitigate greenhouse gas emissions. Many industrialised countries already use a significant share of biofuels in their energy supply e.g. Nordic countries while others like some other European Union countries are planning to increase their use. Production and use of biofuels need to be carried out sustainable. Official statistics do not report trade in such detail that international trade in different biomass types can be fully identified. However, FAO and European Forestry Institute are important sources. In some countries, there is a growing interest in the international trade, because the trade can provide biofuels at lower prices, larger quantities and better quality than domestic alternatives. The first signs of an international market price for wood fuel are indicated in Europe. For the future both the use and the trade of wood fuel is expected to increase. Analyses for trade in charcoal, wood chips, fuel wood and wood residues made in this report identify 'hot' trade spots in Europe, in south East Asia and in North America

Experimental study of cyclone combustion of wood powder for gas turbine applications

Energy Technology Data Exchange (ETDEWEB)

Fredriksson, J; Kallner, P [Royal Inst. of Tech., Stockholm (Sweden). Dept. of Energy Technology

1994-12-31

The objective of the present project is to study to what extent various elements in the ash, in particular Na and K, can be separated in the first stage of a two-stage combustor, with the first stage being a separation cyclone. Mass balances for the elements in the ash are determined from the fuel flow, the char collected from the cyclone bottom and particles in the combustor outlet gas. Experiments have been carried out at atmospheric pressure for wood powder feeding rates of 5-21 kg/h. The conditions in the cyclone have been kept fuel rich. The gas outlet temperature from this stage has been varied from 750 to 1150 deg C through control of the air/fuel ratio. Second stage combustion is achieved in a separate combustor. The results show that significant separation of Na and K is possible, and that the separation is improved when the cyclone temperature is kept low. At an outlet temperature of around 800 deg C about 60% of the input alkali is found in the char residue. At 1000 deg C, only 30% is separated. Mass balances show that about 80% of the ash elements in the fuel input are identified in char and fly ash. With 60% separation of Na and K the content of these elements in the gas would be less than 7 mg/kg gas for a turbine inlet temperature of 850 deg C. The total dust load would be 30-60 mg/kg gas. Ash sticking temperature tests on bottom char and fly ash show no ash sticking up to 1040 deg C. It is therefore concluded that the ash may pass through the turbine as solid particles and cause minimal deposits or corrosion. 15 refs

Experimental study of cyclone combustion of wood powder for gas turbine applications

Energy Technology Data Exchange (ETDEWEB)

Fredriksson, J.; Kallner, P. [Royal Inst. of Tech., Stockholm (Sweden). Dept. of Energy Technology

1993-12-31

The objective of the present project is to study to what extent various elements in the ash, in particular Na and K, can be separated in the first stage of a two-stage combustor, with the first stage being a separation cyclone. Mass balances for the elements in the ash are determined from the fuel flow, the char collected from the cyclone bottom and particles in the combustor outlet gas. Experiments have been carried out at atmospheric pressure for wood powder feeding rates of 5-21 kg/h. The conditions in the cyclone have been kept fuel rich. The gas outlet temperature from this stage has been varied from 750 to 1150 deg C through control of the air/fuel ratio. Second stage combustion is achieved in a separate combustor. The results show that significant separation of Na and K is possible, and that the separation is improved when the cyclone temperature is kept low. At an outlet temperature of around 800 deg C about 60% of the input alkali is found in the char residue. At 1000 deg C, only 30% is separated. Mass balances show that about 80% of the ash elements in the fuel input are identified in char and fly ash. With 60% separation of Na and K the content of these elements in the gas would be less than 7 mg/kg gas for a turbine inlet temperature of 850 deg C. The total dust load would be 30-60 mg/kg gas. Ash sticking temperature tests on bottom char and fly ash show no ash sticking up to 1040 deg C. It is therefore concluded that the ash may pass through the turbine as solid particles and cause minimal deposits or corrosion. 15 refs

The fate of heavy metals during combustion and gasification of contaminated biomass—A brief review

Energy Technology Data Exchange (ETDEWEB)

Nzihou, Ange, E-mail: ange.nzihou@mines-albi.fr [Université de Toulouse, Mines Albi, CNRS, Centre RAPSODEE, Campus Jarlard, F-81013 Albi cedex 09 (France); Stanmore, Brian [Formerly of the University of Queensland, Brisbane, QLD 4072 (Australia)

2013-07-15

Highlights: ► A review on metal behaviour during the thermal treatment of contamined biomass. ► Wide range of biomass waste reported. ► Distribution of metals in the ash, and in the sub-micron particles discussed. -- Abstract: The literature on the presence of heavy metals in contaminated wastes is reviewed. Various categories of materials produced from domestic and industrial activities are included, but municipal solid waste, which is a more complex material, is excluded. This review considers among the most abundant the following materials – wood waste including demolition wood, phytoremediation scavengers and chromated copper arsenate (CCA) timber, sludges including de-inking sludge and sewage sludge, chicken litter and spent pot liner. The partitioning of the metals in the ashes after combustion or gasification follows conventional behaviour, with most metals retained, and higher concentrations in the finer sizes due to vaporisation and recondensation. The alkali metals have been shown to catalyse the biomass conversion, particularly lithium and potassium, although other metals are active to a lesser extent. The most prevalent in biomass is potassium, which is not only inherently active, but volatilises to become finely distributed throughout the char mass. Because the metals are predominantly found in the ash, the effectiveness of their removal depends on the efficiency of the collection of particulates. The potential for disposal into soil depends on the initial concentration in the feed material.

The fate of heavy metals during combustion and gasification of contaminated biomass—A brief review

International Nuclear Information System (INIS)

Nzihou, Ange; Stanmore, Brian

2013-01-01

Highlights: ► A review on metal behaviour during the thermal treatment of contamined biomass. ► Wide range of biomass waste reported. ► Distribution of metals in the ash, and in the sub-micron particles discussed. -- Abstract: The literature on the presence of heavy metals in contaminated wastes is reviewed. Various categories of materials produced from domestic and industrial activities are included, but municipal solid waste, which is a more complex material, is excluded. This review considers among the most abundant the following materials – wood waste including demolition wood, phytoremediation scavengers and chromated copper arsenate (CCA) timber, sludges including de-inking sludge and sewage sludge, chicken litter and spent pot liner. The partitioning of the metals in the ashes after combustion or gasification follows conventional behaviour, with most metals retained, and higher concentrations in the finer sizes due to vaporisation and recondensation. The alkali metals have been shown to catalyse the biomass conversion, particularly lithium and potassium, although other metals are active to a lesser extent. The most prevalent in biomass is potassium, which is not only inherently active, but volatilises to become finely distributed throughout the char mass. Because the metals are predominantly found in the ash, the effectiveness of their removal depends on the efficiency of the collection of particulates. The potential for disposal into soil depends on the initial concentration in the feed material

Evaluation of the environmental impacts of wood products for bio-energy through Life Cycle Assessment (LCA)

OpenAIRE

Pierobon, Francesca

2015-01-01

The use of wood for energy has grown in the last years as an alternative to fossil fuels. National and international laws promote the use of wood in the policies for the mitigation of climate change, based on the assumption that wood has a neutral carbon balance because the combustion emissions are offset by the absorption in forest (assumption of carbon neutrality). However, this assumption does not take into account the emissions associated with the life cycle of the product, e.g. related t...

Air pollution from residential wood combustion in a Danish village. Measuring campaign and analysis of results

Energy Technology Data Exchange (ETDEWEB)

Waahlin, P.; Roerdam Olesen, H.; Bossi, R.; Stubkjaer, J.

2010-05-15

A campaign took place in the winter 2006/2007 comprising measurements of many air pollution components at two sites: a wood smoke exposed site within the village Slagslunde, and a background site 500 m outside of the village. The report describes the campaign and its results. A central result is a so-called 'wood smoke source profile', which relates several measures of wood smoke pollution to each other. This is based on a 'cleaned' data set, for which the effect of other sources than wood smoke was small. The wood smoke profile links the measures PM2.5, particle volume, soot, monosaccharide anhydrides (levoglucosan and mannosan) and different PAHs to each other. Particle number N does not have a close link to the other measures. (author)

Use of residual wood in the cement manufacturing process

International Nuclear Information System (INIS)

Gue, R.

2005-01-01

This PowerPoint presentation discussed the use of wood residuals in the cement manufacturing process. An outline of the cement manufacturing process was presented. Raw materials are combined in exact proportions to create a chemically correct mix, which is then pulverized in a mill. The mix is then burned in a kiln. The end product is cooled to form the pellet sized material known as clinker, which is then milled to form cement. The combustion and destruction characteristics of a cement kiln were presented. Modern cement kilns require approximately 3.2 Gj of energy to produce one tonne of cement. It was noted that wood residuals do not contain halogens, sulfur or other materials detrimental to the cement manufacturing process. Possible injection points for kilns were presented. Various studies have shown that wood residuals can be safely used as a fuel in the manufacture of cement. Environmental benefits derived from using wood included the complete destruction of organic portions, and the fact that residual ash becomes an indistinguishable part of the final product. It was concluded that wood residual materials are a satisfactory alternative fuel for the cement industry. tabs., figs

Combustion, cofiring and emissions characteristics of torrefied biomass in a drop tube reactor

International Nuclear Information System (INIS)

Ndibe, Collins; Maier, Jörg; Scheffknecht, Günter

2015-01-01

The study investigates cofiring characteristics of torrefied biomass fuels at 50% thermal shares with coals and 100% combustion cases. Experiments were carried out in a 20 kW, electrically heated, drop-tube reactor. Fuels used include a range of torrefied biomass fuels, non-thermally treated white wood pellets, a high volatile bituminous coal and a lignite coal. The reactor was maintained at 1200 °C while the overall stoichiometric ratio was kept constant at 1.15 for all combustion cases. Measurements were performed to evaluate combustion reactivity, emissions and burn-out. Torrefied biomass fuels in comparison to non-thermally treated wood contain a lower amount of volatiles. For the tests performed at a similar particle size distribution, the reduced volatile content did not impact combustion reactivity significantly. Delay in combustion was only observed for test fuel with a lower amount of fine particles. The particle size distribution of the pulverised grinds therefore impacts combustion reactivity more. Sulphur and nitrogen contents of woody biomass fuels are low. Blending woody biomass with coal lowers the emissions of SO 2 mainly as a result of dilution. NO X emissions have a more complex dependency on the nitrogen content. Factors such as volatile content of the fuels, fuel type, furnace and burner configurations also impact the final NO X emissions. In comparison to unstaged combustion, the nitrogen conversion to NO X declined from 34% to 9% for air-staged co-combustion of torrefied biomass and hard coal. For the air-staged mono-combustion cases, nitrogen conversion to NO X declined from between 42% and 48% to about 10%–14%. - Highlights: • Impact of torrefaction on cofiring was studied at high heating rates in a drop tube. • Cofiring of torrefied biomasses at high thermal shares (50% and higher) is feasible. • Particle size impacts biomass combustion reactivity more than torrefaction. • In a drop tube reactor, torrefaction has no negative

Sources and contributions of wood smoke during winter in London

Science.gov (United States)

Crilley, Leigh; Bloss, William; Yin, Jianxin; Beddows, David; Harrison, Roy; Zotter, Peter; Prevot, Andre; Green, David

2014-05-01

Determining the contribution of wood smoke in large urban centres such as London is becoming increasingly important with the changing nature of domestic heating partly due to the installation of biomass burning heaters to meet renewable energy targets imposed by the EU and also a rise in so-called recreational burning for aesthetic reasons (Fuller et al., 2013). Recent work in large urban centres (London, Paris and Berlin) has demonstrated an increase in the contribution of wood smoke to ambient particles during winter that can at times exceed traffic emissions. In Europe, biomass burning has been identified as a major cause of exceedances of European air quality limits during winter (Fuller et al., 2013). In light of the changing nature of emissions in urban areas there is a need for on-going measurements to assess the impact of biomass burning in cities like London. Therefore we aimed to determine quantitatively the contribution of biomass burning in London and surrounding rural areas. We also aimed to determine whether local emissions or regional sources were the main source of biomass burning in London. Sources of wood smoke during winter in London were investigated at an urban background site (North Kensington) and two surrounding rural sites (Harwell and Detling) by analysing selected wood smoke chemical tracers. Concentrations of levoglucosan, elemental carbon (EC), organic carbon (OC) and K+ were generally well correlated, indicating a similar source of these species at the three sites. Based on the conversion factor for levoglucosan, mean wood smoke mass at Detling, North Kensington and Harwell was 0.78, 0.87 and 1.0 µg m-3, respectively. At all the sites, biomass burning was found to be a source of OC and EC, with the largest source of OC and EC found to be secondary organic aerosols and traffic emissions, respectively. Peaks in levoglucosan concentrations at the sites were observed to coincide with low ambient temperature, suggesting domestic heating as

Environmental assessment of wood industrial and collective (with heat network) heating. Synthetic report

International Nuclear Information System (INIS)

2005-12-01

This report proposes a synthesis of the results of an environmental assessment of wood industrial and collective heating. This study is based on a life cycle analysis which quantifies the impacts on the environment of all the related activities: fuel extraction, retailing, final use, and so on. Environmental impacts are assessed by means of different indicators: energetic assessment, greenhouse effect assessment, air pollution (acidification), water pollution (eutrophication), toxic material emissions in air and into the soils. Wood is compared to other heating sources (gas, fuel, electricity). Ways to improve this environmental assessment are discussed with respect to wood supply, boiler auxiliary equipment, boiler and combustion

Sources of heavy metal contamination in Swedish wood waste used for combustion

International Nuclear Information System (INIS)

Krook, J.; Martensson, A.; Eklund, M.

2006-01-01

In this paper, wood waste (RWW) recovered for heat production in Sweden was studied. Previous research has concluded that RWW contains elevated amounts of heavy metals, causing environmental problems during waste management. This study extends previous work on RWW by analysing which pollution sources cause this contamination. Using existing data on the metal contents in various materials, and the amounts of these materials in RWW, the share of the elevated amounts of metals in RWW that these materials explain was quantified. Six different materials occurring in RWW were studied and the results show that they explain from 70% to 100% of the amounts of arsenic, chromium, lead, copper and zinc in RWW. The most important materials contributing to contamination of RWW are surface-treated wood, industrial preservative-treated wood, plastic and galvanised fastening systems. These findings enable the development and evaluation of strategies aiming to decrease pollution and resource loss from handling RWW. It is argued that source separation and measures taken further downstream from the generation site, such as treatment, need to be combined to substantially decrease the amount of heavy metals in RWW

Preparation and Flame Retardant and Smoke Suppression Properties of Bamboo-Wood Hybrid Scrimber Filled with Calcium and Magnesium Nanoparticles

Directory of Open Access Journals (Sweden)

Bin Fu

2014-01-01

Full Text Available The physical and mechanical properties of bamboo-wood hybrid scrimber filled with different loadings of nanoparticles were studied. The effects of nanoparticles on flame retardant and smoke suppression properties of bamboo-wood hybrid scrimber were studied by means of thermogravimetric analysis (TGA, cone calorimeter (CONE, and scanning electron microscope (SEM. The results showed that the physical and mechanical properties of bamboo-wood hybrid scrimber were improved by adding a moderate loading of nanoparticles; the optimal loading of nanoparticles was 10%. The heat transfer in bamboo-wood hybrid scrimber was prevented and the escaping channel of combustible gas was blocked by the uniformly filling effect of nanoparticles. The gas concentration was diluted by the noncombustible gas produced by pyrolysis of nanoparticles; the combustion chain reaction was suppressed by highly reactive free radicals produced by pyrolysis of nanoparticles. The residual mass of bamboo-wood hybrid scrimber filled with nanoparticles in thermogravimetric (TG curve at 900 s and burned by method of cone calorimeter (CONE at 600 s was increased compared to that of untreated one, which showed that inorganic mineral powder has the effect of catalytic charring.

Wood pellets : is it a reliable, sustainable, green energy option?

International Nuclear Information System (INIS)

Swaan, J.

2006-01-01

The Wood Pellet Association of Canada was formerly called the BC Pellet Fuel Manufacturers Association, and was renamed and re-organized in January 2006. The association serves as an advocate for the wood pellet industry in addition to conducting research projects. This power point presentation presented an overview of the wood pellet industry in North America and Europe. Canada's 23 pellet plants currently produce just over 1,000,000 tons of wood pellets annually. Pellet producers in the United States produce approximately 800,000 tons annually for the residential bagged market. There are currently 240 pellet plants in Europe, and district heating is the largest growth market for wood pellets in Europe. British Columbia (BC) pellet producers will ship 450,000 tons to European power plants in 2005. Wood pellet specifications were presented, with details of calorific values, moisture and ash contents. An outline of wood pellet production processes was provided. New pellet plants currently under construction were reviewed. Domestic, North American and overseas exports were discussed, along with production estimates for BC for the next 5 years. A chart of world production and consumption of wood pellets between 2000 to 2010 was presented. North American wood pellet technologies were described. The impact of the pine beetle infestation in BC on the wood pellet industry was evaluated, and a worldwide wood pellet production growth forecast was presented. Issues concerning off-gassing, emissions, and torrifracation were also discussed. tabs., figs

Availability and conversion to energy potentials of wood-based industry residues in Cameroon

International Nuclear Information System (INIS)

Simo, A.; Siyam Siew, S.

2000-01-01

The importance of biomass as the most accessible primary energy source in Cameroon is presented. The valorization of wood wastes and residues is seen as a way of implementing the sustainable use of biomass resources. A recent survey of wood-based industries in Cameroon reveals that large volumes of industrial wood residues are generated in the rain forest areas and are inefficiently used. Important quantities are lost in the form of burning in the four main forestry provinces, while other parts of the country suffer from fuelwood shortage. With the exception of the plywood factories, the wood industry is essentially dependent on commercial energy. An analysis made to show the economic and environmental benefits of converting wood residues to energy for industrial and domestic use is presented. (author)

Power generation using coir-pith and wood derived producer gas in diesel engines

Energy Technology Data Exchange (ETDEWEB)

Ramadhas, A.S.; Jayaraj, S.; Muraleedharan, C. [Department of Mechanical Engineering, National Institute of Technology Calicut, Calicut-673 601, Kerala State (India)

2006-10-15

Partial combustion of biomass in the gasifier generates producer gas that can be used for heating purposes and as supplementary or sole fuel in internal combustion engines. In this study, the potential of coir-pith and wood chips as the feedstock for gasifier is analyzed. The performance of the gasifier-engine system is analyzed by running the engine for various producer gas-air flow ratios and at different load conditions. The system is experimentally optimized with respect to maximum diesel savings and lower emissions in the dual fuel mode operation while using coir-pith and wood chips separately. The performance and emission characteristics of the dual fuel engine are compared with that of diesel engine at different load conditions. Specific energy consumption in the dual fuel mode of operation is found to be in the higher side at all load conditions. The brake thermal efficiency of the engine while using wood chips in the dual mode operation is higher than that of coir-pith. The CO emission is higher in the case of dual fuel mode of operation as compared to that of diesel mode. In the dual fuel mode of operation, the higher diesel savings is achieved while using wood chips as compared to that of coir-pith. The comparison of the performance and emission characteristics of the dual fuel engine with diesel engine is also described. (author)

Sulfur Release from Cement Raw Materials during Solid Fuel Combustion

DEFF Research Database (Denmark)

Nielsen, Anders Rooma; Larsen, Morten B.; Glarborg, Peter

2011-01-01

During combustion of solid fuels in the material inlet end of cement rotary kilns, local reducing conditions can occur and cause decomposition of sulfates from cement raw materials. Decomposition of sulfates is problematic because it increases the gas-phase SO2 concentration, which may cause...... deposit formation in the kiln system. SO2 release from cement raw materials during combustion of solid fuels has been studied experimentally in a high temperature rotary drum. The fuels were tire rubber, pine wood, petcoke, sewage sludge, and polypropylene. The SO2 release from the raw materials...

Analysis of existing structure and emissions of wood combustion plants for the production of heat and electricity in Bavaria

International Nuclear Information System (INIS)

Joa, Bettina

2014-01-01

This work deals with the detailed analysis of the existing structure of all Bavarian wood burning plants for the generation of heat and electricity as well as the determination of the resulting emission emissions in 2013. The number of wood burning plants in the single-chamber fireplaces, wood central heating and wood-fired heating plants which are in operation in the year 2013 were determined, and how many plants are existing in the various areas like pellet stoves, traditional ovens, wood-burning fireplace, pellet central heating systems, wood chips central heating systems, fire-wood central heating systems, wood combined heat and power plant (electricity and heat) and wood power plants (heat). In addition, the regional distribution of the wood burning plants in the Bavarian governmental districts is investigated as well as the type and amount of energy produced by them (heat, electricity). [de

Renewable Energy Laboratory Development for Biofuels Advanced Combustion Studies

Energy Technology Data Exchange (ETDEWEB)

Soloiu, Valentin A. [Georgia Southern Univ., Statesboro, GA (United States)

2012-03-31

The research advanced fundamental science and applied engineering for increasing the efficiency of internal combustion engines and meeting emissions regulations with biofuels. The project developed a laboratory with new experiments and allowed investigation of new fuels and their combustion and emissions. This project supports a sustainable domestic biofuels and automotive industry creating economic opportunities across the nation, reducing the dependence on foreign oil, and enhancing U.S. energy security. The one year period of research developed fundamental knowledge and applied technology in advanced combustion, emissions and biofuels formulation to increase vehicle's efficiency. Biofuels combustion was investigated in a Compression Ignition Direct Injection (DI) to develop idling strategies with biofuels and an Indirect Diesel Injection (IDI) intended for auxiliary power unit.

Working group report: methane emissions from fuel combustion and industrial processes

International Nuclear Information System (INIS)

Berdowski, J.J.M.; Beck, L.; Piccot, S.; Olivier, J.G.J.; Veldt, C.

1993-01-01

This paper lists the source categories which are currently recognised as minor sources of methane. These fall into five broad groups: stationary fuel combustion (residential combustion of fuels, solid waste incineration at home sites, on-site agricultural waste burning, industrial and utility combustion of coal, wood, oil and gas, commercial and industrial waste incineration); mobile fuel combustion; non-combustion industrial processes (primary metals production, chemical manufacturing processes, petroleum refining, commercial charcoal manufacturing waste treatments); minor energy production sources (storage and distribution of automotive fuels, geothermal energy production; peat mining operations, oil shale mining operations); and miscellaneous sources. The paper also presents a preliminary estimate of global methane emissions from these minor sources and the results of the working group's discussion on recommendations for the IPCC/OECD methodology and specific research needs. A list of control options for emissions from minor sources is provided. 2 tabs

Oxidative stress, inflammation, and DNA damage in rats after intratracheal instillation or oral exposure to ambient air and wood smoke particulate matter

DEFF Research Database (Denmark)

Danielsen, Pernille Høgh; Loft, Steffen; Jacobsen, Nicklas Raun

2010-01-01

Wood combustion is a significant source of ambient particulate matter (PM) in many regions of the world. Exposure occurs through inhalation or ingestion after deposition of wood smoke particulate matter (WSPM) on crops and food. We investigated effects of ambient PM and WSPM by intragastric...

Effect of wood fuels on power plant operability

International Nuclear Information System (INIS)

Orjala, M.; Ingalsuo, R.

2001-01-01

The objective of the research is to determine the critical properties of wood fuels on the basis of power plant operability, to determine the optimal conditions for reduction of harmful detriments, and to study how the storage and processing of wood fuels effect on the operability. Both the CFB and BFB technologies are studied. The project started in December 2000 and it will be ended by the end of 2002. Experts of the Fuels and Combustion research field of VTT Energy carry out the main parts of the research. Experts of the research field of Mineral Processing of VTT Chemical Technology, located in Outokumpu, and Kemian tutkimuspalvelut Oy/Oulu University, located in Outokumpu, participate in the analytics, and the research field of Materials and Manufacturing Technology of VTT Manufacturing Technology in Otaniemi participates in the research on material effects. System Technology Laboratory of Oulu University carries out the power plant automation and boiler control technology research under supervision of Professor Urpo Kortela. Co-operation with the materials research unit of EU's JRC, located in Petten, which started in the research 'Combustion of Forest Chips', will be continues in this research. Co-operation will be made with Swedish Vaermeforsk in the field of information exchange on experiences in utilisation of wood fuels in Swedish power plants and possibilities to join in the projects of Vaermeforsk in this research field. Following companies participate in the project: Etelae-Savon Energia Oy, Foster Wheeler Energia Oy, Kvaerner Pulping Oy, Simpele pasteboard factory of M-Real Oyj and Vaermeforsk AB (Sweden). (orig.)

Biomass downdraft gasifier with internal cyclonic combustion chamber: design, construction, and experimental results.

Science.gov (United States)

Patil, Krushna; Bhoi, Prakash; Huhnke, Raymond; Bellmer, Danielle

2011-05-01

An exploratory downdraft gasifier design with unique biomass pyrolysis and tar cracking mechanism is evolved at Oklahoma State University. This design has an internal separate combustion section where turbulent, swirling high-temperature combustion flows are generated. A series of research trials were conducted using wood shavings as the gasifier feedstock. Maximum tar cracking temperatures were above 1100°C. Average volumetric concentration levels of major combustible components in the product gas were 22% CO and 11% H(2). Hot and cold gas efficiencies were 72% and 66%, respectively. Copyright © 2011 Elsevier Ltd. All rights reserved.

The competitiveness of wood processing industry in the Republic of Serbia during the period 1995-2015

Directory of Open Access Journals (Sweden)

Milićević Srđan

2017-01-01

Full Text Available The paper considers the competitiveness of wood processing industry in the Republic of Serbia in the period 1995-2015 by using six partial indicators of competitiveness: Revealed comparative advantage (RCA, Competitiveness growth index (RCA1, Index of net business performance (RCA2, Index of contribution to the trade balance (CTB, Grubel-Lloyd index (GLI and Michaely index (MI. The research reveals that the values of RCA were positive in all years, which points to comparative advantage of wood processing industry on the domestic market. Since RCA1 has significantly higher value than one, it means that it is highly competitive on international market as well. Positive values of RCA2 in the period 1995-2015 speak of the contribution of this branch to international economic balance. The indicator RCA2 is connected with the CTB index, which points to the contribution of the sector in formation of active national trade balance and economic growth. The average value of CTB index of wood processing industry in Serbia and positive annual values of CTB of wood processing industry show that the contribution in the total trade balance of the sector is positive. The course of GLI values points to the loss of capabilities of the sector to create the surplus of national trade balance. Finally, positive annual values of MI confirmed the competitiveness of domestic wood processing industry, but at the same time its low specialisation. Taken as a whole, the weakness of competitiveness of wood processing industry in Serbia can be seen in the fact that its competitive advantage is visible in its favourable price, not in manufacturing complex products with high value added. The aim of the paper is to investigate whether Serbian wood processing industry has comparative precedence on domestic and international markets and whether the structure of exchange is positive, i.e. whether appropriate specialisation of production and export exists or the focus should shift

The evolutionary fate of phenotypic plasticity and functional traits under domestication in manioc: changes in stem biomechanics and the appearance of stem brittleness.

Science.gov (United States)

Ménard, Léa; McKey, Doyle; Mühlen, Gilda S; Clair, Bruno; Rowe, Nick P

2013-01-01

Domestication can influence many functional traits in plants, from overall life-history and growth form to wood density and cell wall ultrastructure. Such changes can increase fitness of the domesticate in agricultural environments but may negatively affect survival in the wild. We studied effects of domestication on stem biomechanics in manioc by comparing domesticated and ancestral wild taxa from two different regions of greater Amazonia. We compared mechanical properties, tissue organisation and wood characteristics including microfibril angles in both wild and domesticated plants, each growing in two different habitats (forest or savannah) and varying in growth form (shrub or liana). Wild taxa grew as shrubs in open savannah but as lianas in overgrown and forested habitats. Growth form plasticity was retained in domesticated manioc. However, stems of the domesticate showed brittle failure. Wild plants differed in mechanical architecture between shrub and liana phenotypes, a difference that diminished between shrubs and lianas of the domesticate. Stems of wild plants were generally stiffer, failed at higher bending stresses and were less prone to brittle fracture compared with shrub and liana phenotypes of the domesticate. Biomechanical differences between stems of wild and domesticated plants were mainly due to changes in wood density and cellulose microfibril angle rather than changes in secondary growth or tissue geometry. Domestication did not significantly modify "large-scale" trait development or growth form plasticity, since both wild and domesticated manioc can develop as shrubs or lianas. However, "finer-scale" developmental traits crucial to mechanical stability and thus ecological success of the plant were significantly modified. This profoundly influenced the likelihood of brittle failure, particularly in long climbing stems, thereby also influencing the survival of the domesticate in natural situations vulnerable to mechanical perturbation. We

The evolutionary fate of phenotypic plasticity and functional traits under domestication in manioc: changes in stem biomechanics and the appearance of stem brittleness.

Directory of Open Access Journals (Sweden)

Léa Ménard

Full Text Available Domestication can influence many functional traits in plants, from overall life-history and growth form to wood density and cell wall ultrastructure. Such changes can increase fitness of the domesticate in agricultural environments but may negatively affect survival in the wild. We studied effects of domestication on stem biomechanics in manioc by comparing domesticated and ancestral wild taxa from two different regions of greater Amazonia. We compared mechanical properties, tissue organisation and wood characteristics including microfibril angles in both wild and domesticated plants, each growing in two different habitats (forest or savannah and varying in growth form (shrub or liana. Wild taxa grew as shrubs in open savannah but as lianas in overgrown and forested habitats. Growth form plasticity was retained in domesticated manioc. However, stems of the domesticate showed brittle failure. Wild plants differed in mechanical architecture between shrub and liana phenotypes, a difference that diminished between shrubs and lianas of the domesticate. Stems of wild plants were generally stiffer, failed at higher bending stresses and were less prone to brittle fracture compared with shrub and liana phenotypes of the domesticate. Biomechanical differences between stems of wild and domesticated plants were mainly due to changes in wood density and cellulose microfibril angle rather than changes in secondary growth or tissue geometry. Domestication did not significantly modify "large-scale" trait development or growth form plasticity, since both wild and domesticated manioc can develop as shrubs or lianas. However, "finer-scale" developmental traits crucial to mechanical stability and thus ecological success of the plant were significantly modified. This profoundly influenced the likelihood of brittle failure, particularly in long climbing stems, thereby also influencing the survival of the domesticate in natural situations vulnerable to mechanical

Heat transfer mechanisms in poplar wood undergoing torrefaction

Science.gov (United States)

Sule, Idris O.; Mahmud, Shohel; Dutta, Animesh; Tasnim, Syeda Humaira

2016-03-01

Torrefaction, a thermal treatment process of biomass, has been proved to improve biomass combustible properties. Torrefaction is defined as a thermochemical process in reduced oxygen condition and at temperature range from 200 to 300 °C for shorter residence time whereby energy yield is maximized, can be a bridging technology that can lead the conventional system (e.g. coal-fired plants) towards a sustainable energy system. In efforts to develop a commercial operable torrefaction reactor, the present study examines the minimum input condition at which biomass is torrefied and explores the heat transfer mechanisms during torrefaction in poplar wood samples. The heat transfer through the wood sample is numerically modeled and analyzed. Each poplar wood is torrefied at temperature of 250, 270, and 300 °C. The experimental study shows that the 270 °C-treatment can be deduced as the optimal input condition for torrefaction of poplar wood. A good understanding of heat transfer mechanisms can facilitate the upscaling and downscaling of torrefaction process equipment to fit the feedstock input criteria and can help to develop treatment input specifications that can maximize process efficiency.

Investigation of black and brown carbon multiple-wavelength-dependent light absorption from biomass and fossil fuel combustion source emissions

Science.gov (United States)

Michael R. Olson; Mercedes Victoria Garcia; Michael A. Robinson; Paul Van Rooy; Mark A. Dietenberger; Michael Bergin; James Jay Schauer

2015-01-01

Quantification of the black carbon (BC) and brown carbon (BrC) components of source emissions is critical to understanding the impact combustion aerosols have on atmospheric light absorption. Multiple-wavelength absorption was measured from fuels including wood, agricultural biomass, coals, plant matter, and petroleum distillates in controlled combustion settings....

Report on the survey of the commercialization of wood biomass energy. Project on the production of wood pellet fuel; 2001 nendo mokushitsu baiomasu energy jigyoka chosa hokokusho. Mokushitsu peretto nenryo seizo jigyo

Energy Technology Data Exchange (ETDEWEB)

NONE

2002-02-01

For the purpose of regenerating forestry and contributing to the policy for prevention of global warming, a potential study was made of the commercialization of the wood pellet using low-quality wood materials such as thinnings and wood pieces from lumber mill. In the study, based on the survey of raw materials of wood pellet and the demand amount, the scale of pellet production was assumed, and subjects were arranged toward the basic design of plant, evaluation of economical efficiency and commercialization. As a result of the study, the following subjects were extracted. In the study, the supply of lumbers of 2,800 t/y and securing of demand of about 1,600 t/y were set forth as a premise, but the subject was to secure the initial demand. The pellet combustor was higher in price than the kerosene combustor, and for the imported combustion equipment, the combustion of white pellet was supposed. It is necessary to develop combustor of pellets including the bark. In the trial calculation of the unit price of heat utilization (yen/Mcal), the pellet stove was about 3.3 times as high in price as the kerosene stove. It is necessary to reduce the pellet price down to 30 yen/kg or so by decreasing the cost of pellet production. (NEDO)

Bed agglomeration in fluidized combustor fueled by wood and rice straw blends

DEFF Research Database (Denmark)

Thy, Peter; Jenkins, Brian; Williams, R.B.

2010-01-01

Abstract Petrographic techniques have been used to examine bed materials from fluidized bed combustion experiments that utilized wood and rice straw fuel blends. The experiments were conducted using a laboratory-scale combustor with mullite sand beds, firing temperatures of 840 to 1030 °C, and ru...

Bed agglomeration in fluidized combustor fueled by wood and rice straw blends

NARCIS (Netherlands)

Thy, P.; Jenkins, B.M.; Williams, R.B.; Lesher, C.E.; Bakker, R.R.

2010-01-01

Petrographic techniques have been used to examine bed materials from fluidized bed combustion experiments that utilized wood and rice straw fuel blends. The experiments were conducted using a laboratory-scale combustor with mullite sand beds, firing temperatures of 840 to 1030 °C, and run durations

Emission Factors of Selected Organic Compounds from Domestic Hardwood Combustion

Czech Academy of Sciences Publication Activity Database

Hopan, F.; Šyc, Michal; Horák, J.; Dej, M.; Krpec, K.; Ocelka, T.; Tomšej, T.; Pekárek, Vladimír

LVI, č. 3 (2009), s. 81-85 ISSN 1210-0471 R&D Projects: GA MŽP(CZ) SP/1A2/116/07; GA MŠk 2B08048 Institutional research plan: CEZ:AV0Z40720504 Keywords : wood * small sources * emission factors Subject RIV: DI - Air Pollution ; Quality http://transactions.fs.vsb.cz/2009-3/12hop.pdf

Empirically Estimated Heats of Combustion of Oxygenated Hydrocarbon Bio-type Oils

Directory of Open Access Journals (Sweden)

Dmitry A. Ponomarev

2015-04-01

Full Text Available An empirical method is proposed by which the heats of combustion of oxygenated hydrocarbon oils, typically found from wood pyrolysis, may be calculated additively from empirically predicted heats of combustion of individual compounds. The predicted values are in turn based on four types of energetically inequivalent carbon and four types of energetically inequivalent hydrogen atomic energy values. A method is also given to estimate the condensation heats of oil mixtures based on the presence of four types of intermolecular forces. Agreement between predicted and experimental values of combustion heats for a typical mixture of known compounds was ± 2% and < 1% for a freshly prepared mixture of known compounds.

Combustion characteristics and retention-emission of selenium during co-firing of torrefied biomass and its blends with high ash coal.

Science.gov (United States)

Ullah, Habib; Liu, Guijian; Yousaf, Balal; Ali, Muhammad Ubaid; Abbas, Qumber; Zhou, Chuncai

2017-12-01

The combustion characteristics, kinetic analysis and selenium retention-emission behavior during co-combustion of high ash coal (HAC) with pine wood (PW) biomass and torrefied pine wood (TPW) were investigated through a combination of thermogravimetric analysis (TGA) and laboratory-based circulating fluidized bed combustion experiment. Improved ignition behavior and thermal reactivity of HAC were observed through the addition of a suitable proportion of biomass and torrefied. During combustion of blends, higher values of relative enrichment factors in fly ash revealed the maximum content of condensing volatile selenium on fly ash particles, and depleted level in bottom ash. Selenium emission in blends decreased by the increasing ratio of both PW and TPW. Higher reductions in the total Se volatilization were found for HAC/TPW than individual HAC sample, recommending that TPW have the best potential of selenium retention. The interaction amongst selenium and fly ash particles may cause the retention of selenium. Copyright © 2017 Elsevier Ltd. All rights reserved.

Aerosols from biomass combustion. Particle formation, relevance on air quality, and measures for particle reduction

International Nuclear Information System (INIS)

Nussbaumer, Thomas

2005-01-01

Biomass combustion is a relevant source of particle emissions. In Switzerland, wood combustion contributes with 2% to the energy supply but with more than 4% to Particulate Matter smaller 10 microns (PM 10) in the ambient air. In areas with high density of residential wood heating (e.g. in the south of Chile), wood particles are the dominant source of PM 10 resulting in heavy local smog situations. Since combustion particles are regarded as health relevant and since immission limit values on PM 10 are widely exceeded, measures for particle reduction from biomass combustion are of high priority. With respect to aerosols from biomass combustion, two sources of particles are distinguished: 1. an incomplete combustion can lead to soot and organic matter contained in the particles, 2. ash constituents in the fuel lead to the formation of inorganic fly ash particles mainly consisting of salts such as chlorides and oxides. The theory of aerosol formation from fuel constituents is described and two hypotheses to reduce inorganic particles from biomass combustion are proposed: 1. a reduced oxygen content in the solid fuel conversion zone (glow bed in a fixed bed combustion) is assumed to reduce the particle mass concentration due to three mechanisms: a) reduced oxidation of fuel constituents to compounds with higher volatility, b) reduced local temperature for solid fuel conversion, c) a reduced entrainmed of fuel constituents 2. a reduced total excess air can reduce the particle number due to enhanced coagulation. The proposed low-particle concept has been implemented for an automatic furnace for wood pellets in the size range from 100 kW to 500 kW. Furthermore, the furnace design was optimised to enable a part load operation without increased emissions of carbon monoxide (CO) and particles. In a 100 kW prototype furnace the low-particle conditions resulted in particle emissions between 6 mg/m n 3 to 11 mg/m n 3 at 13 vol.-% O2 and CO emissions below 70 mg/m n 3 in the

Ash quality and environmental quality assurance system in co-combustion - Co-combustion of forest industry waste

International Nuclear Information System (INIS)

Laine-Ylijoki, J.; Wahlstroem, M.

2000-01-01

The environmental acceptability and possible utilization of co-combustion ashes will have a significant influence on the wider use of co-combustion in the future. At present the correlation between currently used fuels, their mixture ratios, and quality variations in ashes are not known, which complicates the assessment of possible utilization and environmental acceptability of co-combustion ashes. The composition of ashes has also been found to vary significantly. Effective utilization requires that process variations to alter ash composition and quality variations are known in advance. The aim of the research was to characterize the fly ash from co- combustion of peat, wood and biological paper mill sludge produced under different fuel loadings, especially with and without sludge addition, ant to identify critical parameters influencing on the ash composition. The variations in the leaching properties of ashes collected daily were followed up. The environmental acceptability of the ashes produced under different fuel loadings, especially their suitability for use in road constructions, were evaluated. The project included also the preparation of laboratory reference material from ash material. Guidelines were developed for sampling, sample preparation and analysis, and leaching tests. Furthermore, a quality control system, including sampling strategies, sample analysis and leaching testing, was established

Rheology of fly ashes from coal and biomass co-combustion

DEFF Research Database (Denmark)

Arvelakis, Stelios; Frandsen, Flemming

2010-01-01

The presence of large amounts of alkali metals, chlorine and sulphur in most biomass fuels - compared to coal - can create serious ash-related problems such as deposition, agglomeration and/or corrosion. This paper discusses the viscosity characteristics of fly ash from the co-combustion of various...... coal/biomass blends in a pilot scale pf-boiler. The produced data provide information on the melting of the ash and its flow characteristics, as a function of temperature, which may be used to modify the temperature profile of the boiler in order to avoid slagging. Straw co-firing lowers the ash...... viscosity leading to higher stickiness of the ash particles. Wood co-firing has only minor effects, due to the composition of wood ash and the low percentage of wood in the coal/biomass blend....

Evaluation of methods for the physical characterization of the fine particle emissions from two residential wood combustion appliances

Science.gov (United States)

Kinsey, John S.; Kariher, Peter H.; Dong, Yuanji

The fine particle emissions from a U. S. certified non-catalytic wood stove and a zero-clearance fireplace burning Quercus rubra L. (northern red oak) and Pseudotsuga menziesii (Douglas fir) cordwood each at two different moisture levels were determined. Emission testing was performed using both time-integrated and continuous instrumentation for total particle mass, particle number, particle size distribution, and fixed combustion gases using an atmospheric wind tunnel, full-flow laboratory dilution tunnel, and dilution stack sampler with a comparison made between the three dilution systems and two sampling filter types. The total mass emission factors (EFs) for all dilution systems and filter media are extremely variable ranging from fireplace emissions burning wet oak averaged 11 g kg -1. A substantial number of ultrafine particles in the accumulation size range were also observed during all tests as determined by an Electrical Low Pressure Impactor (ELPI) and Scanning Mobility Particle Sizer. The PM-2.5 (particles ≤2.5 μm in aerodynamic diameter) fractions determined from the ELPI electrometer data ranged from 93 to 98% (mass) depending on appliance type as reported previously by Hays et al. (Aerosol Science, 34, 1061, 2003).

Disentangling effects of key coarse woody debris fuel properties on its combustion, consumption and carbon gas emissions during experimental laboratory fire

NARCIS (Netherlands)

Zhao, Weiwei; van Logtestijn, Richard S.P.; van der Werf, Guido R.; van Hal, Jurgen R.; Cornelissen, Johannes H.C.

2018-01-01

Coarse woody debris is a key terrestrial carbon pool, and its turnover through fire plays a fundamental role in global carbon cycling. Coarse dead wood fuel properties, which vary between tree species and wood decay stages, might affect its combustion, consumption and carbon gas emissions during

Avaliação de parâmetros de consumo de combustível do Tritrem no transporte de madeira Evaluation of fuel consumption parameters on Tritrem wood transport

Directory of Open Access Journals (Sweden)

Glauco Lima da Silveira

2004-02-01

ções superiores a 2.000 rpm implicam desperdício de combustível. O ponto de rotação máxima ideal para o motor dos veículos nas condições estudadas está na faixa de 1.700 rpm. Um pequeno número de equipes foi responsável pelo elevado número de infrações cometidas. A falta de treinamento dos motoristas contribui para o aumento de consumo de combustível. O cumprimento das normas sobre condução econômica ajuda a reduzir os custos com combustível.The parameters low gear, excess engine rotation over 2,000 rpm, neutral gear and speed superior to 80 km/h were evaluated to monitor fuel consumption of two wood transporters (A and B using data from a board computer installed on a Mercedes-Benz, LS 2638 model. Low gear increased fuel consumption cost by R$ 19,164.50 (91.32% and R$ 17,449.61 (99.09% per month, since, on average, the vehicle engines functioned about 24.47% and 25.79% of the running time for the transporters A and B, respectively. Excess engine rotation also increased fuel consumption cost by R$ 69.45 (0.33% and R$ 155.62 (0.88% for the transporters A and B, respectively. Neutral Gear contributed to fuel consumption cost of R$ 1,751.73 (8.35% and R$ 4.80 (0.03%, respectively, for transporters A and B. The methodology used is specific for the OM 457 LA engine, but it could be used in other studies, provided some adaptation is made; low gear had the highest fuel consumption in wood transport followed by neutral gear and excess engine rotation. Significant fuel consumption reduction is possible in wood transport in relation to low gear, due to the long waiting time (loading, unloading, lines, and mandatory stops Neutral gear and excess vehicle speed do not save fuel and compromise safety. Engine rotations superior to 2,000 rpm waste fuel. The ideal maximum rotation point for vehicle engine was about 1,700 rpm. A few teams were accounted responsible for the high number of driving violations. The lack of trained drivers contributed to fuel consumption increase

Archaeological Palimpsest Dissection at Cova del Parco (Lleida, Spain) through Microstratigraphic Investigation of Combustion Structures. Preliminary Results.

Science.gov (United States)

Égüez, Natalia; Mallol, Carolina; Mangado, Xavier; Tejero, José Miguel; Fullola, Josep Maria

2014-05-01

We present preliminary data from ongoing microstratigraphic investigations of Cova del Parco (Lleida, Spain), a Magdalenian karstic cave site in North western Catalonia. Excavations of the Upper Magdalenian levels are currently underway, with radiometric dates between 15,690 and 16,390 cal BP. This period has yielded a complex anthropogenic sedimentary deposit including combustion features and local accumulations of anthropogenic debris near the cave walls. On of the working hypothesis is that the Magdalenian hunter-gatherers who occupied the site did so for short periods, possibly seasonally. Support of this hypothesis comes the presence of overlapping, very thin flat combustion structures, which appear to have been short-lived and close to each other in time. In order to investigate this issue, we carried out micromorphological analysis of some of the mentioned combustion features. Preliminary results show significant microstratification and presence of unburned spherulites mixed in with reprecipitated calcitic wood ash, both of which point towards the existence of hiatuses between combustion events. This is supported by the observation of scattered, lightly burned microscopic flint and bone fragments in the sediment between ash layers, which could represent renewed occupation floor debris. Our case study adds to the growing number of combustion feature microstratigraphic investigations contributing to a correct characterization of anthropogenic palimpsest deposits. Key words: Microstratigraphy; Micromorphology; Magdalenian; Combustion features; Wood ash; Palimpsest; Iberian Peninsula.

Modeling future U.S. forest sector market and trade impacts of expansion in wood energy consumption

Science.gov (United States)

Peter J. Ince; Andrew D. Kramp; Kenneth E. Skog; Do-il Yoo; V. Alaric Sample

2011-01-01

This paper describes an approach to modeling U.S. forest sector market and trade impacts of expansion in domestic wood energy consumption under hypothetical future U.S. wood biomass energy policy scenarios. The U.S. Forest Products Module (USFPM) was created to enhance the modeling of the U.S. forest sector within the Global Forest Products Model (GFPM), providing a...

Emission of toxic air pollutants from biomass combustion

International Nuclear Information System (INIS)

Houck, J.E.; Barnett, S.G.; Roholt, R.B.; Rock, M.E.

1991-01-01

Combustion of biomass for power generation, home heating, process steam generation, and waste disposal constitutes a major source of air pollutants nationwide. Emissions from hog-fueled boilers, demolition wood-fired power plants, municipal waste incinerators, woodstoves, fireplaces, pellet stoves, agricultural burning, and forestry burning have been characterized for a variety of purposes. These have included risk assessment, permitting, emission inventory development, source profiling for receptor modeling, and control technology evaluations. From the results of the source characterization studies a compilation of emission factors for criteria and non-criteria pollutants are presented here. Key among these pollutants are polycyclic aromatic hydrocarbons, priority pollutant metals, carbon monoxide, sulfur dioxide, nitrous oxides, and PM 10 particles. The emission factors from the biomass combustion processes are compared and contrasted with other pollutant sources. In addition, sampling and analysis procedures most appropriate for characterizing emissions from the biomass combustion sources are also discussed

Effects of biomass on dynamics of combustion in circulating fluidized beds

Directory of Open Access Journals (Sweden)

Tourunen Antti

2004-01-01

Full Text Available Fluidized bed technology is very suitable for the combustion of biomass Nevertheless substitution of coal with biomass affects boiler operation and especially dynamics and controllability. Non-homogeneity of biomass and fuel feeding disturbances cause process instability, such as variations in temperatures and pressures, which reduce lifetime of equipment and structures. Because of process instability higher air coefficient must be used in order to avoid CO emissions, which is not economical. Combustion profiles for coal, wood and peat, measured at the VTT Processes Pilot circulating fluidized bed reactor, have been compared. Process stability and char inventories have been studied by the measurements and the model. Biofuel are usually very reactive and their combustion profiles are quite different compared to coals. Because of high reactivity and low char content combustion process with biofuel is very sensitive for fuel feeding. Also low char inventory effect on load changes combined with combustion profile that differs from coals. Because of different combustion profile heat transfer can be a limiting factor in load changes despite the high reactivity and fast oxygen response.

Assessment of the wood-energy programme 2000-2006. Synthesis

International Nuclear Information System (INIS)

2007-04-01

This report proposes an assessment of a nationwide programme launched in 2000 to help wood energy to become a well-structured value chain with a self-development capacity. This programme addressed the three sectors of domestic, industrial and community/urban heating, and more notably the latter. Based on interviews and on a survey, this study aims at giving a quantitative as well as a qualitative assessment of the whole wood energy activity financed or led by the French energy conservation agency (ADEME) at the national or regional level, at assessing the programme efficiency and highlighting the impacts of the supported actions, at defining recommendations for the 'renewable heat' (chaleur renouvelable) programme

Test Firing of chunk wood - Is it possible to automate the fuel supply?; Proveldning av knubbved - Aer det moejligt att automatisera braenslematningen?

Energy Technology Data Exchange (ETDEWEB)

Persson, Tomas; Danielsson, Bengt-Olof

2013-05-15

Chunk wood is a wood fuel with a fuel particle length typically between 50 and 150 mm. The ad-vantage of chunk wood compared to wood chips is that the fuel dry as fast as fuel wood, but can be produced and handled as wood chip. Technologies for efficient producing, drying and distribution of Chunk wood have been developed since the 1970:s and machines for manufacturing the fuel is available on the market, but still there is no small-scale heating equipment in operation to burn the fuel automatically. The aim of the study was to investigate how the feeding and firing of chunk wood works in a standard 200 kW biomass boiler for various types of biofuels. The main focus was on studying how the fuel feeding system works using chunk wood and if the combustion and emissions are satisfactory. The boiler have a main fuel feeding auger screw connected to the bottom of the fuel storage, followed by a cell feeder and another auger screw that is feeding the fuel into the combustion chamber. The power consumption for the fuel feeding auger screws and the CO-emissions were measured during the firing period. In order to obtain reference values for the stresses in the fuel feeding system and the CO-emissions, regular wood chips were initially fired followed by the chunk wood firing. During the chunk wood firing period several interruptions in the fuel feeding occurred, as the trigger mechanism for the motor protection stopped the fuel supply. Most of the interruptions, however, could be resolved through manual reversing of the fuel feeding auger screw. Only at two occasions the entrance to the auger screw were manually cleared from large fuel pieces. The cell feeder and the auger screw feeding the fuel into the combustion chamber were stopped twice, and to continue operating the boiler it was enough to restart the feeding system. However, as they are both operated by the same motor we do not know whether the two shutdowns that occurred were caused by feeding problems in the auger

Evaluation of challenges of wood imports to Iran using Fuzzy Delphi Analytical Hierarchy Process

Directory of Open Access Journals (Sweden)

amin arian

2017-08-01

Full Text Available Abstract:Considering the increasing consumption of wood and wood products in Iran and limited domestic sources of wood and shortage of wood raw material in Iran, wood raw material imports is a solution for Iranian developing wood industries' wood procurement.But, wood imports to Iran, always faced with a lot of challenges. The aim of this research is to determine and evaluate the challenges in the way of wood imports to Iran. The research method used in this study is a descriptive-analytic method. The analytic method used in the study to evaluate the challenges is the Fuzzy Delphi Analytical Hierarchy Process (FDAHP. First the findings of previous researches in the field and the literature were studied and doing interviews with industry experts, the challenges in the way of wood imports to Iran were extracted and classified in 5 groups and 35 factors and were evaluated.The results shows that in the first level (groups the regulation, economic, politic, infrastructure and management groups have the most importance respectively. In second level (challenges, plant protection regulations have the most importance. After that, exchange rate tolerance, oil income, banking support and GDP have most importance respectively.

Pelly Crossing wood chip boiler

Energy Technology Data Exchange (ETDEWEB)

1985-03-11

The Pelly wood chip project has demonstrated that wood chips are a successful fuel for space and domestic water heating in a northern climate. Pelly Crossing was chosen as a demonstration site for the following reasons: its extreme temperatures, an abundant local supply of resource material, the high cost of fuel oil heating and a lack of local employment. The major obstacle to the smooth operation of the boiler system was the poor quality of the chip supply. The production of poor quality chips has been caused by inadequate operation and maintenance of the chipper. Dull knives and faulty anvil adjustments produced chips and splinters far in excess of the one centimetre size specified for the system's design. Unanticipated complications have caused costs of the system to be higher than expected by approximately $15,000. The actual cost of the project was approximately $165,000. The first year of the system's operation was expected to accrue $11,600 in heating cost savings. This estimate was impossible to confirm given the system's irregular operation and incremental costs. Consistent operation of the system for a period of at least one year plus the installation of monitoring devices will allow the cost effectiveness to be calculated. The wood chip system's impact on the environment was estimated to be minimal. Wood chip burning was considered cleaner and safer than cordwood burning. 9 refs., 6 figs., 6 tabs.

The wood-electricity: development perspectives for the wood-based production of energy in France by 2015. Soil pollution. Soil contamination by hydrocarbon effluents: rehabilitation market analysis

International Nuclear Information System (INIS)

Barbier, C.

1996-09-01

A report proposes an economical analysis of the wood-based production of electricity in France, describes the different stages of this process, from supply (crop, tearing, transport, storage) through conversion (technologies, combustion or gasification) and to the output kWh (cost sensitivity analysis with respect to the evolution of other parameters). It describes the environmental impacts of wood-based electricity production and compares the quantities of pollutants emitted by this process with those emitted by other processes based on fossil energies. It identifies the main obstacles to the development of wood-based electricity production and proposes political and institutional measures inspired by the Danish experience. A second article is aimed at presenting an economic analysis of the cost of decontamination of hydrocarbon polluted sites in France (a majority of which are gas stations and storage sites)

Nature of unresolved complex mixture in size-distributed emissions from residential wood combustion as measured by thermal desorption-gas chromatography-mass spectrometry

Science.gov (United States)

Hays, Michael D.; Smith, N. Dean; Dong, Yuanji

2004-08-01

Unresolved complex mixture (UCM) is an analytical artifact of gas chromatographs of combustion source-related fine aerosol extracts. In this study the UCM is examined in size-resolved fine aerosol emissions from residential wood combustion. The aerosols are sorted by size in an electrical low-pressure impactor (ELPI) and subsequently analyzed by thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS). A semiquantitative system for predicting the branched alkane, cycloalkane, alkylbenzene, C3-, C4-, C5-alkylbenzene, methylnaphthalene, C3-, C4-, C5-alkylnaphthalene, methylphenanthrene C2-, C3-alkylphenanthrene, and dibenzothiophene concentrations in the UCM is introduced. Analysis by TD/GS/MS detects UCM on each ELPI stage for all six combustion tests. The UCM baseline among the different fuel types is variable. In particular, the UCM of Pseudotsuga sp. is enriched in later-eluting compounds of lower volatility. A high level of reproducibility is achieved in determining UCM areas. UCM fractions (UCM ion area/total extracted ion chromatograph area) by individual ELPI stage return a mean relative standard deviation of 19.1% over the entire combustion test set, indicating a highly consistent UCM fraction across the ELPI size boundaries. Among the molecular ions investigated, branched alkane (m/z 57) and dibenzothiophene (m/z 212 and 226) constituents are most abundant in UCM emissions from RWC, collectively accounting for 64-95% of the targeted chemical species. The total UCM emissions span 446-756 mg/kg of dry biomass burned and correspond to an upper limit of 7.1% of the PM2.5 mass. The UCM emissions are primarily accumulation mode (0.1 μm ≤ aerodynamic diameter (da) ≤ 1 μm), with a geometric mean diameter (dg) range of 120.3-518.4 nm. UCM in PM2.5 is chemically asymmetric (shifted to finer da), typically clustering at da ≤ 1 μm. Measurable shifts in dg and changes in distribution widths (σg) on an intratest basis suggest that the particle density

Highly-controlled, reproducible measurements of aerosol emissions from African biomass combustion

Science.gov (United States)

Haslett, Sophie; Thomas, J. Chris; Morgan, William; Hadden, Rory; Liu, Dantong; Allan, James; Williams, Paul; Sekou, Keïta; Liousse, Catherine; Coe, Hugh

2017-04-01

Particulate emissions from biomass burning can alter the atmosphere's radiative balance and cause significant harm to human health. However, the relationship between these emissions and fundamental combustion processes is, to date, poorly characterised. In atmospheric models, aerosol emissions are represented by emission factors based on mass loss, which are averaged over an entire combustion event for each particulate species. This approach, however, masks huge variability in emissions during different phases of the combustion period. Laboratory tests have shown that even small changes to the burning environment can lead to huge variation in observed aerosol emission factors (Akagi et al., 2011). In order to address this gap in understanding, in this study, small wood samples sourced from Côte D'Ivoire were burned in a highly-controlled laboratory environment. The shape and mass of samples, available airflow and surrounding heat were carefully regulated. Organic aerosol and refractory black carbon emissions were measured in real-time using an Aerosol Mass Spectrometer and a Single Particle Soot Photometer, respectively. Both of these instruments are used regularly to measure aerosol concentrations in the field. This methodology produced remarkably repeatable results, allowing three different phases of combustion to be identified by their emissions. Black carbon was emitted predominantly during flaming combustion; organic aerosols were emitted during pyrolysis before ignition and from smouldering-dominated behaviour near the end of combustion. During the flaming period, there was a strong correlation between the emission of black carbon and the rate of mass loss, which suggests there is value in employing a mass-based emission factor for this species. However, very little correlation was seen between organic aerosol and mass loss throughout the tests. As such, results here suggest that emission factors averaged over an entire combustion event are unlikely to be

Crescimento da firma e comércio exterior: revisitando a teoria de Adrian Wood

OpenAIRE

Catermol,Fabrício

2006-01-01

This paper analyzes the growth of the firm by foreign trade. The theory of Adrian Wood is revisited for the analysis of growth and profit trade-off and improved to cope with growth by exports. The main outcome of this paper is that low domestic demand can be a very important factor to firm choices growth by foreign market. However, the growth of domestic demand does not necessarily reduce exports.

Cleaner heat from wood. TULISIJA research programme for wood firing technology 1997-1999

International Nuclear Information System (INIS)

1998-01-01