WorldWideScience

Sample records for des complexes applications

  1. Application of the Moessbauer effect to the study of the structure of transition metal complexes; Applications de l'effet Mossbauer a l'etude de la structure des complexes des metaux de transition

    Energy Technology Data Exchange (ETDEWEB)

    Tsymbal, C [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1968-07-01

    In this survey, the structural investigations of transition metal complexes by the hyperfine interactions in the Moessbauer effect are described. The isomer shift provides a unique tool for estimating s electrons covalency in high spin complexes and one of the best pieces of evidence for the importance of bacle donation in low spin complexes. The electric field gradient deriving from quadrupole coupling measurements is correlated with the energy levels distribution of d orbitals in high spin complexes, whereas in low spin complexes it originates from the unbalanced d electrons. (authors) [French] Dans cette etude, nous decrivons les applications des interactions hyperfines dans l' effet Mossbauer a l'etude de la structure des complexes des metaux de transition. Le deplacement isomerique donne des informations tres utiles sur la covalence des electrons s dans les complexes a spin eleve et met en evidence d'une maniere nette l'importance du phenomene de 'bacle donation' dans les complexes a spin faible. Le gradient de champ electrique qui provient des mesures d'interaction quadripolaire est lie a la distribution des niveaux d'energie des orbitales d dans les complexes a spin eleve alors que dans les complexes a spin faible, il est provoque par des electrons d non apparies. (auteurs)

  2. Gd(III) complexes with tripodal pyridine carboxylate ligands: application to optimized contrast agents for NMR Imaging; Complexes de Gd(III) avec des ligands tripodes pyridinocarboxylate: vers des agents de contraste optimises pour l'IRM

    Energy Technology Data Exchange (ETDEWEB)

    Nonat, A.; Gateau, Ch.; Mallanti, M.; Fries, P. [CEA Grenoble, Dept. de Recherche Fondamentale sur la Matiere Condensee (DRFMC/SCIB/LAI) Lab. de Reconnaissance Ionique, 38 (France)

    2005-07-01

    In order to better understand the influence of the pyridine carboxylate units on the stability and the electronic relaxation time, and with the aim to obtain gadolinium complexes leading to next generation contrast agents having very high relaxivity, the octadente analogous of the tpatcn which has a water molecule bound in the first coordination sphere has been studied. Here is presented the synthesis, the structural studies, the thermodynamic and relaxometric properties of the Ln(III) complexes of this new tripodal compound 1-carboxy-methyl-4,7-bis[(6-carboxy-pyridin-2-yl)methyl] - 1,4,7-tri-aza-cyclo-nonane. (O.M.)

  3. Étude de la compétitivité de complexation des métaux issus des ...

    African Journals Online (AJOL)

    Les analyses chimiques effectuées sur le phosphate naturel révèlent la présence des métaux lourds. Pour étudier les risques de rétrogradation de ces engrais phosphatés, notre étude s'est portée sur la complexation des substances humiques naturelles extraites des sols sur des ions métalliques tels que le calcium, ...

  4. Nitrosyl complexes of technetium; Nitrosylkomplexe des Technetiums

    Energy Technology Data Exchange (ETDEWEB)

    Ackermann, Janine

    2016-09-22

    The presented thesis describes syntheses and characterization of novel technetium nitrosyl compounds with various ligand systems. The main focus is the synthesis of low-valent technetium nitrosyl complexes with cyclopentadienyl ligands. [German] Gegenstand der vorliegenden Arbeit ist die Synthese und Charakterisierung neuer Technetiumnitrosylverbindungen mit unterschiedlichen Ligandensystemen. Hauptaugenmerk wurde dabei auf die Darstellung niedervalenter Tc(NO)-Verbindungen mit Cyclopentadienyl-Liganden gelegt.

  5. Application des TIC à l'atténuation des effets des catastrophes dans ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    L'Amérique centrale est souvent aux prises avec des inondations et des ... (SIG) et de traitement des images, afin de cartographier les dangers et de modéliser les ... de l'Institut d'étude du développement international de l'Université McGill.

  6. Applications of the complex-mass renormalization scheme in effective field theory; Anwendungen des Komplexe-Masse-Renormierungsschemas in effektiver Feldtheorie

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, Torsten

    2012-07-11

    In the first part of the this doctoral thesis the perturbative unitarity in the complex-mass scheme (CMS) is analysed. To that end a procedure for calculating cutting rules for loop integrals containing propagators with finite widths is presented. A toy-model Lagrangian describing the interaction of a heavy vector boson with a light fermion is used to demonstrate that the CMS respects unitarity order by order in perturbation theory provided that the renormalized coupling constant remains real. The second part of the thesis deals with various applications of the CMS to chiral effective field theory (EFT). In particular, mass and width of the delta resonance, elastic electromagnetic form factors of the Roper resonance, form factors of the nucleon-to-Roper transition, pion-nucleon scattering, and pion photo- and electroproduction for center-of-mass energies in the region of the Roper mass are calculated. By choosing appropriate renormalization conditions, a consistent chiral power counting scheme for EFT with resonant degrees of freedom can be established. This allows for a systematic investigation of the above processes in terms of an expansion in small quantities. The obtained results can be applied to the extrapolation of corresponding simulations in the context of lattice QCD to the physical value of the pion mass. Therefore, in addition to the Q{sup 2} dependence of the form factors, also the pion-mass dependence of the magnetic moment and electromagnetic radii of the Roper resonance is explored. Both a partial wave decomposition and a multipole expansion are performed for pion-nucleon scattering and pion photo- and electroproduction, respectively. In this connection the P11 partial wave as well as the M{sub 1-} and S{sub 1-} multipoles are fitted via non-linear regression to empirical data.

  7. Administrateur de programme, Application des connaissances (h/f ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Le programme découle d'un partenariat conclu entre le Department for International Development du Royaume-Uni, la Fondation William et Flora Hewlett et le CRDI. L'administrateur de programme, Application des connaissances, relevant du chef de programme, travaille à la formulation et au profilage des résultats du ...

  8. Application of a radiant heat transfer model to complex industrial reactive flows: combustion chambers, electric arcs; Application d`un modele de transfert radiatif a des ecoulements reactifs industriels complexes: chambres de combustion, arcs electriques

    Energy Technology Data Exchange (ETDEWEB)

    Mechitoua, N; Dalsecco, S; Delalondre, C; Simonin, O [Electricite de France (EDF), 78 - Chatou (France). Lab. National d` Hydraulique

    1997-12-31

    The direction of studies and researches (DER) of Electricite de France (EdF) has been involved for several years in a research program on turbulent reactive flows. The objectives of this program concern: the reduction of pollutant emissions from existing fossil-fueled power plants, the study of new production means (fluidized beds), and the promotion of electric power applications in the industry. An important part of this program is devoted to the development and validation of 3-D softwares and to the modeling of physical phenomena. This paper presents some industrial applications (furnaces, boilers, electric arcs) for which radiant heat transfers play an important role and the radiation models used. (J.S.) 8 refs.

  9. Application of a radiant heat transfer model to complex industrial reactive flows: combustion chambers, electric arcs; Application d`un modele de transfert radiatif a des ecoulements reactifs industriels complexes: chambres de combustion, arcs electriques

    Energy Technology Data Exchange (ETDEWEB)

    Mechitoua, N.; Dalsecco, S.; Delalondre, C.; Simonin, O. [Electricite de France (EDF), 78 - Chatou (France). Lab. National d`Hydraulique

    1996-12-31

    The direction of studies and researches (DER) of Electricite de France (EdF) has been involved for several years in a research program on turbulent reactive flows. The objectives of this program concern: the reduction of pollutant emissions from existing fossil-fueled power plants, the study of new production means (fluidized beds), and the promotion of electric power applications in the industry. An important part of this program is devoted to the development and validation of 3-D softwares and to the modeling of physical phenomena. This paper presents some industrial applications (furnaces, boilers, electric arcs) for which radiant heat transfers play an important role and the radiation models used. (J.S.) 8 refs.

  10. Application of radioisotopes to the investigation of the kinetics and mechanism of reactions of some inorganic complex compounds; Application des radioisotopes a l'etude de la cinetique et du mecanisme des reactions de certains complexes inorganiques; Primenenie radioizotopov k issledovaniyam kinetiki i mekhanizma reaktsij nekotorykh neorganicheskikh slozhnykh soedinenij; Aplicacion de los radioisotopos al estudio de la cinetica y del mecanismo de las reacciones de algunos complejos inorganicos

    Energy Technology Data Exchange (ETDEWEB)

    Harris, Gordon M [Department of Chemistry, University of Buffalo, Buffalo 14, NY (United States)

    1962-03-15

    cyanide is an important end-product. (author) [French] Les radioisotopes sont particulierement precieux dans l'etude de nombreux types de reactions de chimie minerale, notamment de reactions ou interviennent des ions complexes en solution aqueuse. Les recherches sur la vitesse et le mecanisme des echanges isotopiques constituent un aspect important de ces applications. C'est ainsi qu'on a fait une serie d'etudes sur l'echange entre du carbonate ''libre'' marque au carbone-14 et le carbonate qui joue le role de coordinafc dans les ions complexes octaedriques du type CoA{sub 2}CO{sub 3}{sup +}, ou A represente le 2NH{sub 3}, ou l'ethylene-diamine (en), ou la propylene-diamine (pn) ou la trimethylene-diamine (tn). Grace aux etudes ainsi effectuees, on connait assez exactement la nature de ces reactions par substitution de coordinate, ainsi que le role joue par les coordinais amines qui ne participent pas a l'echange. Des etudes analogues sur l'echange entre oxalates dans les complexes tri-oxaliques de forme M (C{sub 2}O{sub 4}){sub 3}{sup 3-}, ou M=Co (III), Cr (III), ou Rh (III), n'ont pas ete moins fecondes en resultats. Une autre technique, applicable seulement lorsqu'on utilise des radioisotopes de faible poids atomique comme le carbone-14, consiste a observer les effets d'equilibre ou les effets cinetiques que les isotopes exercent sur la reaction etudiee. C'est ainsi qu'il a ete possible d'interpreter des differences dans le mecanisme d'echange du coordinat carbonate dans le Coen{sub 2}CO{sub 3}{sup +} et le Cotn{sub 2}CO{sub 3}{sup +}, par mesure de l'effet isotopique a l'etat d'equilibre dans la reaction d'echange des carbonates. De meme, des donnees sur l'effet isotopique cinetique dans l'hydratation avec catalyseur acide de l'ion Co(NH{sub 3}){sub 4}CO{sub 3}{sup +} ont confirme les deductions faites en ce qui concerne l'etape a laquelle se rompt la liaison, etape qui determine la vitesse de ces reactions. Enfin, la determination des positions successives de

  11. Les frameworks au coeur des applications web

    OpenAIRE

    Moro, Arielle; Daehne, Peter

    2010-01-01

    Depuis quelques années, Internet est vraiment entré dans les mœurs : tant dans les entreprises qu’au sein de chaque foyer. En effet, Internet permet de communiquer à travers le monde en quelques secondes, de vendre toute sorte de produits en déployant des solutions e-commerce facilement et bien d’autres choses. Internet est donc un véritable vecteur de communication, de commerce et à présent, avec le Web 2.0, un vrai berceau d’informations (tant des informations personnelles que des informati...

  12. Synthesis and characterization of hybrid silicon based complexing materials: extraction of transuranic elements from high level liquid waste; Synthese et caracterisation de gels hybrides de silice a proprietes complexantes: applications a l'extraction des transuraniens des effluents aqueux

    Energy Technology Data Exchange (ETDEWEB)

    Conocar, O

    1999-07-01

    Hybrid organic/inorganic silica compounds with extractive properties have been developed under an enhanced decontamination program for radioactive aqueous nitric acid waste in nuclear facilities. The materials were obtained by the sol-gel process through hydrolysis and poly-condensation of complexing organo-tri-alkoxy-silanes with the corresponding tetra-alkoxy-silane. Hybrid silica compounds were initially synthesized and characterized from mono- and bis-silyl precursors with malonamide or ethylenediamine patterns. Solids with different specific areas and pore diameters were obtained depending on the nature of the precursor, its functionality and its concentration in the tetra-alkoxy-silane. These compounds were then considered and assessed for use in plutonium and americium extraction. Excellent results-partitioning coefficients and capacities have been obtained with malonamide hybrid silica. The comparison with silica compounds impregnated or grafted with the same type of organic group is significant in this respect. Much of the improved performance obtained with hybrid silica may be attributed to the large quantity of complexing groups that can be incorporated in these materials. The effect of the solid texture on the extraction performance was also studied. Although the capacity increased with the specific area, little effect was observed on the distribution coefficients -notably for americium- indicating that the most favorable complexation sites are found on the outer surface. Macroporous malonamide hybrid silica compounds were synthesized to study the effects of the pore diameter, but the results have been inconclusive to date because of the unexpected molecular composition of the materials. (author)

  13. Réduction des vibrations de structures composites complexes par dispositifs piézoélectriques shuntés : application aux aubes de turbomachines

    OpenAIRE

    Thierry , Olivier

    2016-01-01

    This thesis concerns the vibration reduction in the low frequency range of a composite fan blade of a turbojet engine with piezoelectric devices. The interest is to increase lifespan and avoid flutter phenomena by reducing the vibration amplitude. The purpose of this thesis is to study several shunted piezoelectric devices, in the low frequency range, that can be applied to a woven composite turbojet fan blade. The targeted applications are the LEAP fan blades or the “open-rotor” fan blade, b...

  14. Complex posttraumatic stress disorder: an exploratory investigation of PTSD and DES NOS among Dutch war veterans

    NARCIS (Netherlands)

    Jongedijk, R. A.; Carlier, I. V.; Schreuder, B. J.; Gersons, B. P.

    1996-01-01

    The recently developed concept Disorder of Extreme Stress Not Otherwise Specified (DES NOS) or complex posttraumatic stress disorder (complex PTSD) is designed to encompass long-standing symptoms not present in PTSD. An exploratory investigation of PTSD and DES NOS was performed with the Structured

  15. Data processing in gamma spectrometry. Application to the decay schemes study; Traitement des informations en spectrometrie gamma application a l'etude de schemas de desintegration

    Energy Technology Data Exchange (ETDEWEB)

    Boulanger, J P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires, departement d' electronique generale, service d' instrumentation nucleaire

    1968-06-01

    The purpose of this thesis is the processing of the data issued from a gamma spectrometer, and its applications to the decay schemes study. The mathematical analysis of the full energy peaks, in connection with the very good resolution of semi-conductor detectors, leads to a very accurate determination of the energies. The resolution of complex spectra by the least squares method, completed by a spectra generating process, allows the calculation of branching ratios. Then, the handling of the two dimensional experiments permits the coincidence exam. For each of these methods, the calculation principle, then the systematics tests realized in order to prove their validity and to determine their application ranges as well as some experimental results appropriate to illustrate their possibilities, are presented. The energies of some nuclides, frequently used as standards have been thus measured and the decay schemes of {sup 134}Cs and {sup 110m}Ag determined precisely. (author) [French] Cette these est consacree aux methodes de traitement des informations issues d'un spectrometre {gamma}, et a leur application a l'etude des schemas de desintegration: l'analyse mathematique des pics d'absorption totale, conjuguee avec l'excellent pouvoir de resolution des detecteurs semi-conducteurs, conduit a une determination tres precise des energies. La decomposition des spectres complexes par la methode des moindres carres, completee par un procede de generation de spectres, autorise le calcul des rapports de branchement. Enfin le depouillement des experiences biparametriques permet l'examen des coincidences. Pour chacune de ces methodes, on expose le principe des calculs et les essais systematiques effectues afin d'eprouver leur validite et de definir leurs domaines d'application, ainsi que quelques resultats experimentaux propres a illustrer leurs possibilites. Les energies de quelques isotopes utilises couramment comme etalons ont ainsi ete mesurees, et les schemas de

  16. Soudage des aciers pour application mécanique

    CERN Document Server

    Deveaux, Dominique

    2016-01-01

    Ce guide détermine les bonnes pratiques pour comprendre les risques d’une forme d’assemblage multimatériaux : celui par soudage de nuances à forte teneur en carbone avec des éléments en acier de construction. Dans un premier temps, le rapport passe en revue l’examen des avaries sur des assemblages soudés pour l’application mécanique mettant en cause les aciers. Fissuration par fatigue, rupture fragile, rupture ductile, fissuration à chaud ou à froid sont autant de causes qui seront analysées. Dans un deuxième temps, il se concentre sur la conception des joints soudés. Du choix des nuances à la tenue vis-à-vis de la rupture fragile en passant par l’analyse en fatigue des assemblages soudés, c’est l’ensemble de la problématique qui est pris en compte.

  17. Applications magnétoélectriques des supraconducteurs

    CERN Document Server

    Mangin, Philippe

    2018-01-01

    La supraconductivité est devenue incontournable, par exemple avec l’IRM qui équipe nos hôpitaux. Elle permet de spectaculaires réalisations tels le LHC du CERN qui a mis en évidence le boson de Higgs, le projet de fusion nucléaire ITER, le train à sustentation magnétique, etc. Ces applications dans divers domaines reposent sur l’aptitude des fils supraconducteurs à transporter de très fortes intensités de courant et sur l’énorme champ magnétique que des bobines supraconductrices peuvent créer. Elles sont l’objet du présent ouvrage avec d’abord l’élaboration des fils supraconducteurs, prouesse technologique tant pour les câbles Nb – Ti et Nb3Sn que pour les rubans de cuprates. Ensuite, pour chaque application, sont présentés les phénomènes physiques et le fonctionnement des dispositifs technologiques ; le lecteur peut ainsi acquérir une vision globale des apports scientifiques de ces technologies et de leurs enjeux, scientifiques, médicaux et sociétaux. Trois autres ouvrag...

  18. Applications magnétoélectriques des supraconducteurs

    CERN Document Server

    Mangin, Philippe

    2018-01-01

    La supraconductivité est devenue incontournable, par exemple avec l’IRM qui équipe nos hôpitaux. Elle permet de spectaculaires réalisations tels le LHC du CERN qui a mis en évidence le boson de Higgs, le projet de fusion nucléaire ITER, le train à sustentation magnétique, etc. Ces applications dans divers domaines reposent sur l’aptitude des fils supraconducteurs à transporter de très fortes intensités de courant et sur l’énorme champ magnétique que des bobines supraconductrices peuvent créer. Elles sont l’objet du présent ouvrage avec d’abord l’élaboration des fils supraconducteurs, prouesse technologique tant pour les câbles Nb – Ti et Nb$_{3}$Sn que pour les rubans de cuprates. Ensuite, pour chaque application, sont présentés les phénomènes physiques et le fonctionnement des dispositifs technologiques ; le lecteur peut ainsi acquérir une vision globale des apports scientifiques de ces technologies et de leurs enjeux, scientifiques, médicaux et sociétaux. Trois autres o...

  19. De l'importance des orbites periodiques: Detection et applications

    Science.gov (United States)

    Doyon, Bernard

    L'ensemble des Orbites Periodiques Instables (OPIs) d'un systeme chaotique est intimement relie a ses proprietes dynamiques. A partir de l'ensemble (en principe infini) d'OPIs cachees dans l'espace des phases, on peut obtenir des quantites dynamiques importantes telles les exposants de Lyapunov, la mesure invariante, l'entropie topologique et la dimension fractale. En chaos quantique (i.e. l'etude de systemes quantiques qui ont un equivalent chaotique dans la limite classique), ces memes OPIs permettent de faire le pont entre le comportement classique et quantique de systemes non-integrables. La localisation de ces cycles fondamentaux est un probleme complexe. Cette these aborde dans un premier temps le probleme de la detection des OPIs dans les systemes chaotiques. Une etude comparative de deux algorithmes recents est presentee. Nous approfondissons ces deux methodes afin de les utiliser sur differents systemes dont des flots continus dissipatifs et conservatifs. Une analyse du taux de convergence des algorithmes est aussi realisee afin de degager les forces et les limites de ces schemes numeriques. Les methodes de detection que nous utilisons reposent sur une transformation particuliere de la dynamique initiale. Cette astuce nous a inspire une methode alternative pour cibler et stabiliser une orbite periodique quelconque dans un systeme chaotique. Le ciblage est en general combine aux methodes de controle pour stabiliser rapidement un cycle donne. En general, il faut connaitre la position et la stabilite du cycle en question. La nouvelle methode de ciblage que nous presentons ne demande pas de connaitre a priori la position et la stabilite des orbites periodiques. Elle pourrait etre un outil complementaire aux methodes de ciblage et de controle actuelles.

  20. "Complex" Posttraumatic Stress Disorder/Disorders of Extreme Stress (CP/DES) in Sexually Abused Children: An Exloratory Study.

    Science.gov (United States)

    Hall, Darlene Kordich

    1999-01-01

    Compares three groups of young sexually abused children on seven "Complex" Posttraumatic Stress Disorder/Disorders of Extreme Stress (CP/DES) indices. As cumulative number of types of trauma increased, the number of CP/DES symptoms rose. Results suggest that CP/DES also characterizes sexually abused children, especially those who have…

  1. Complexation de l'aluminium par des hétéropolyanions lacunaires ...

    African Journals Online (AJOL)

    L'objectif visé par cette étude est la dépollution des eaux à partir de la complexation d'un métal toxique, l'aluminium en solution, par des hétéropolyanions lacunaires (HPA) de type Dawson. Les complexes formés sont récupérés par membrane liquide émulsionnée (MEL).Les résultats de la complex1ation de l'aluminium ...

  2. La boîte à outil sur l'application des connaissances | CRDI - Centre ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    1 nov. 2011 ... Gavin Bennett est journaliste, auteur et consultant en communications stratégiques. Nasreen Jessani est conseillère au sein du groupe de l'application des connaissances et des politiques, l'un des deux piliers du groupe de travail chargé des études par pays du Groupe de travail de référence sur ...

  3. Managing complexity insights, concepts, applications

    CERN Document Server

    Helbing, Dirk

    2007-01-01

    Each chapter in Managing Complexity focuses on analyzing real-world complex systems and transferring knowledge from the complex-systems sciences to applications in business, industry and society. The interdisciplinary contributions range from markets and production through logistics, traffic control, and critical infrastructures, up to network design, information systems, social conflicts and building consensus. They serve to raise readers' awareness concerning the often counter-intuitive behavior of complex systems and to help them integrate insights gained in complexity research into everyday planning, decision making, strategic optimization, and policy. Intended for a broad readership, the contributions have been kept largely non-technical and address a general, scientifically literate audience involved in corporate, academic, and public institutions.

  4. Data processing in gamma spectrometry. Application to the decay schemes study; Traitement des informations en spectrometrie gamma application a l'etude de schemas de desintegration

    Energy Technology Data Exchange (ETDEWEB)

    Boulanger, J.P. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires, departement d' electronique generale, service d' instrumentation nucleaire

    1968-06-01

    The purpose of this thesis is the processing of the data issued from a gamma spectrometer, and its applications to the decay schemes study. The mathematical analysis of the full energy peaks, in connection with the very good resolution of semi-conductor detectors, leads to a very accurate determination of the energies. The resolution of complex spectra by the least squares method, completed by a spectra generating process, allows the calculation of branching ratios. Then, the handling of the two dimensional experiments permits the coincidence exam. For each of these methods, the calculation principle, then the systematics tests realized in order to prove their validity and to determine their application ranges as well as some experimental results appropriate to illustrate their possibilities, are presented. The energies of some nuclides, frequently used as standards have been thus measured and the decay schemes of {sup 134}Cs and {sup 110m}Ag determined precisely. (author) [French] Cette these est consacree aux methodes de traitement des informations issues d'un spectrometre {gamma}, et a leur application a l'etude des schemas de desintegration: l'analyse mathematique des pics d'absorption totale, conjuguee avec l'excellent pouvoir de resolution des detecteurs semi-conducteurs, conduit a une determination tres precise des energies. La decomposition des spectres complexes par la methode des moindres carres, completee par un procede de generation de spectres, autorise le calcul des rapports de branchement. Enfin le depouillement des experiences biparametriques permet l'examen des coincidences. Pour chacune de ces methodes, on expose le principe des calculs et les essais systematiques effectues afin d'eprouver leur validite et de definir leurs domaines d'application, ainsi que quelques resultats experimentaux propres a illustrer leurs possibilites. Les energies de quelques isotopes utilises couramment comme etalons ont ainsi ete

  5. Application of general methods for the study of porous materials to the determination of the characteristics of barriers; Application des methodes generales d'etudes des corps poreux a la determination des caracteristiques des barrieres

    Energy Technology Data Exchange (ETDEWEB)

    Plurien, P; Charpin, J; Mommejac, S [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    Barriers foreseen for the separation of uranium isotopes by gaseous diffusion must posses pores of about 100 Angstrom radius and as high an output as possible. They should thus be of small but uniform thickness. In view of these conditions it is necessary to adapt the normal methods available for studying porous materials in order to check the characteristics of the prototypes examined. It has been found that only by cross-comparison of data from various methods can progress in the development of different prototypes be followed. The following account consists of two parts: 1) A review of the main experimental methods we have used: a) various absorption methods, b) electron microscopy, c) X-ray studies, d) mercury porosimetry, e) liquid permeability, f) gas permeability, g) measurement of separation efficiency. 2) Comparison of the results obtained using these various methods and their application with a view to acquiring as complete a knowledge as possible of the structure of the barrier. (author) [French] Les barrieres susceptibles d'etre utilisees pour la separation des isotopes de l'uranium, par diffusion gazeuse, doivent presenter des pores de rayon de l'ordre de 100 Angstrom et un debit aussi grand que possible. Elles doivent donc avoir une epaisseur faible et constante. Ces conditions necessitent une adaptation des methodes usuelles d'etude des corps poreux pour controler les caracteristiques des prototypes etudies. Il est apparu que seul le recoupement entre diverses methodes permet de suivre les progres dans la realisation de differents prototypes. L'expose qui va suivre comprend deux parties: 1) Une revue des principales methodes experimentales que nous utilisons: a) differentes methodes d'absorption, b) microscopie electronique, c) rayons X, d) porosimetrie a mercure, e) permeabilite aux liquides, f) permeabilite aux gaz, g) mesure de l'efficacite de separation. 2) Comparaison des differents resultats obtenus par ces diverses methodes et leur application

  6. Application of the verona coding definitions of emotional sequences (VR-CoDES) on a pediatric data set.

    Science.gov (United States)

    Vatne, Torun M; Finset, Arnstein; Ørnes, Knut; Ruland, Cornelia M

    2010-09-01

    Adult patients present concerns as defined in the Verona Coding Definitions of Emotional Sequences (VR-CoDES), but we do not know how children express their concerns during medical consultations. This study aimed to evaluate the applicability of VR-CoDES to pediatric oncology consultations. Twenty-eight pediatric consultations were coded with the Verona Coding Definitions of Emotional Sequences (VR-CoDES), and the material was also qualitatively analyzed for descriptive purposes. Five consultations were randomly selected for reliability testing and descriptive statistics were computed. Perfect inter-rater reliability for concerns and moderate reliability for cues were obtained. Cues and/or concerns were present in over half of the consultations. Cues were more frequent than concerns, with the majority of cues being verbal hints to hidden concerns or non-verbal cues. Intensity of expressions, limitations in vocabulary, commonality of statements, and complexity of the setting complicated the use of VR-CoDES. Child-specific cues; use of the imperative, cues about past experiences, and use of onomatopoeia were observed. Children with cancer express concerns during medical consultations. VR-CoDES is a reliable tool for coding concerns in pediatric data sets. For future applications in pediatric settings an appendix should be developed to incorporate the child-specific traits. Copyright (c) 2010 Elsevier Ireland Ltd. All rights reserved.

  7. Complexation des groupes oxoet nitruotechnetium par les dithioetherdithiols

    International Nuclear Information System (INIS)

    Drouillard, S.; Apparu, M.; Vidal, M.; Alagui, A.

    1992-01-01

    Complexation of the core 99m TcO 3+ by 2,10-dimethyl-4,8-dithiaundecane-2,10-dithiol (1) was achieved using a tin salt as reducing agent, and led to the formation of a stable neutral species I. With 5-butyl-3,7-dithianonane-1,9-dithiol (2) the same reaction leads to the formation of an unstable complex II which is difficult to isolate. Biological studies on the Swiss mouse have shown that only I is of interest (myocardial fixation greater than that of RP 30). In the case of complexes with a TcN core, two neutral species are always obtained, one from [ 99m TcNCL 4 ] - and one from 99m TcNCL 2 [P(CH 2 CH 2 CN) 3 ] 2 ; depending on the operating conditions it is possible to favour the formation of one or other species and to isolate them by purification. The biological results have proved rather disappointing. (Author)

  8. Effects of ionizing radiations on DNA-protein complexes; Effets des radiations ionisantes sur des complexes ADN-proteine

    Energy Technology Data Exchange (ETDEWEB)

    Gillard, N

    2005-11-15

    The radio-induced destruction of DNA-protein complexes may have serious consequences for systems implicated in important cellular functions. The first system which has been studied is the lactose operon system, that regulates gene expression in Escherichia coli. First of all, the repressor-operator complex is destroyed after irradiation of the complex or of the protein alone. The damaging of the domain of repressor binding to DNA (headpiece) has been demonstrated and studied from the point of view of peptide chain integrity, conformation and amino acids damages. Secondly, dysfunctions of the in vitro induction of an irradiated repressor-unirradiated DNA complex have been observed. These perturbations, due to a decrease of the number of inducer binding sites, are correlated to the damaging of tryptophan residues. Moreover, the inducer protects the repressor when they are irradiated together, both by acting as a scavenger in the bulk, and by the masking of its binding site on the protein. The second studied system is formed by Fpg (for Formamido pyrimidine glycosylase), a DNA repair protein and a DNA with an oxidative lesion. The results show that irradiation disturbs the repair both by decreasing its efficiency of DNA lesion recognition and binding, and by altering its enzymatic activity. (author)

  9. Modeling of the radiative field in complex geometries using computerized graphical tools. Application to comfort characterization in environments equipped with important radiative sources; Modelisation du champ radiatif dans des geometries complexes a l`aide d`outils infographiques. Application a la caracterisation du confort dans les ambiances munies de sources radiatives importantes

    Energy Technology Data Exchange (ETDEWEB)

    Manolescu, M; Sperandio, M; Allard, F [La Rochelle Universite, 17 - La Rochelle, LEPTAB (France)

    1997-12-31

    Bibliographic studies in the domain of radiant heat transfers in complex geometries demonstrate the impossibility of resolving such problems using classical analytical methods. The numerical analysis can theoretically be performed successfully but requires enormous computer means. The contribution of this study consists in using computerized graphical techniques to treat general problems of radiant heat transfers in complex geometries. This paper presents the model used, the calculation technique and the optimizations that allow to greatly reduce the computer memory required and the calculation time. The code developed uses evocative images for the synthetic presentation of results which facilitate the searcher`s and conceiver`s choices. Finally, an application to the characterization of thermal comfort in residential environments is developed to illustrate the potentialities of this method. (J.S.) 19 refs.

  10. Modeling of the radiative field in complex geometries using computerized graphical tools. Application to comfort characterization in environments equipped with important radiative sources; Modelisation du champ radiatif dans des geometries complexes a l`aide d`outils infographiques. Application a la caracterisation du confort dans les ambiances munies de sources radiatives importantes

    Energy Technology Data Exchange (ETDEWEB)

    Manolescu, M.; Sperandio, M.; Allard, F. [La Rochelle Universite, 17 - La Rochelle, LEPTAB (France)

    1996-12-31

    Bibliographic studies in the domain of radiant heat transfers in complex geometries demonstrate the impossibility of resolving such problems using classical analytical methods. The numerical analysis can theoretically be performed successfully but requires enormous computer means. The contribution of this study consists in using computerized graphical techniques to treat general problems of radiant heat transfers in complex geometries. This paper presents the model used, the calculation technique and the optimizations that allow to greatly reduce the computer memory required and the calculation time. The code developed uses evocative images for the synthetic presentation of results which facilitate the searcher`s and conceiver`s choices. Finally, an application to the characterization of thermal comfort in residential environments is developed to illustrate the potentialities of this method. (J.S.) 19 refs.

  11. Numerical analysis of the bearing capacity of complex rock mechanical underground systems with filigree structures in the presence of imponderables. A contribution to the systematization of the investigative process with application/demonstration using the example of the salt cavern ASSE II/south flank; Numerische Analyse des Tragverhaltens komplexer gebirgsmechanischer untertaegiger Systeme mit filigranen Strukturen bei Anwesenheit von Imponderabilien. Ein Beitrag zur Systematisierung des Untersuchungsprozesses mit Anwendung/Demonstration am Beispiel des Salzbergwerks Schacht ASSE II/Suedflanke

    Energy Technology Data Exchange (ETDEWEB)

    Dyogtyev, Oleksandr

    2017-03-02

    The thesis dealing with the numerical analysis of the bearing capacity of complex rock mechanical underground systems with filigree structures in the presence of imponderables covers the following issues: status of science and technology, concept for the performance of numerical studies on the bearing capacity of large-volume underground systems, application example salt cavern ASSE II - application of the developed concept/development of numerical tools for the overall system/application of the global model to the given questions/realization of the modification potential.

  12. Optimisation des proprietes fonctionnelles des alliages a memoire de forme suite a l'application de traitements thermomecaniques

    Science.gov (United States)

    Demers, Vincent

    L'objectif de ce projet est de determiner les conditions de laminage et la temperature de traitement thermique maximisant les proprietes fonctionnelles de l'alliage a memoire de forme Ti-Ni. Les specimens sont caracterises par des mesures de calorimetrie, de microscopie optique, de gene ration de contrainte, de deformation recuperable et des essais mecaniques. Pour un cycle unique, l'utilisation d'un taux d'ecrouissage e=1.5 obtenu avec l'application d'une force de tension FT = 0.1sigma y et d'une huile minerale resulte en un echantillon droit, sans microfissure et qui apres un recuit a 400°C, produit un materiau nanostructure manifestant des proprietes fonctionnelles deux fois plus grandes que le meme materiau ayant une structure polygonisee. Pour des cycles repetes, les memes conditions de laminage sont valables mais le niveau de deformation optimal est situe entre e=0.75-2, et depend particulierement du mode de sollicitation, du niveau de stabilisation et du nombre de cycles a la rupture requis par l'application.

  13. Mécanique des fluides fondements et applications

    CERN Document Server

    Cengel, Yunus A

    2017-01-01

    La mécanique des fluides est un outil performant qui permet d'expliquer les phénomènes qui nous entourent de l'échelle microscopique à l'échelle macroscopique. Elle est aussi à la base du développement de nombreuses technologies. Cet ouvrage à destination des étudiants donne une vision complète de la mécanique des fluides. Bien que la mécanique des fluides puisse souvent paraître rébarbative aux yeux des étudiants, cet ouvrage valorise ce domaine d'enseignement en l'illustrant de nombreux exemples issus de l'ingénierie navale, l'aéronautique, la météorologie, etc.

  14. Statistical treatment of data. Application to nuclear electronics; Traitement des informations en regime statistique. Applications a l'electronique nucleaire

    Energy Technology Data Exchange (ETDEWEB)

    Sicard, F [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    In this report the data of probability calculations are applied to the analyses of counting losses in experiments on chance events encountered in nuclear physics. The distribution of time intervals according to Poisson's law is studied and various applications of this are given: calculation of counting losses on a scale preceded by a fast de-multiplying circuit, decrease of the counting rate on the multichannel selectors, recording of statistical distribution phenomena on magnetic bands. (author) [French] Ce rapport applique les donnees du calcul des probabilites a l'analyse des pertes de comptage dans les experiences sur des evenements aleatoires rencontres en physique nucleaire. La distribution des intervalles de temps suivant une loi de Poisson est etudiee et differentes applications en sont donnees: calcul des pertes de comptage sur une echelle precedee d'un circuit de demultiplication rapide, diminution du taux de comptage sur les selecteurs multicanaux, enregistrement de phenomenes a distribution statistique sur bandes magnetiques. (auteur)

  15. Kinetic Modeling of Complex Catalytic Reactions Modélisation cinétique des réactions catalytiques complexes

    Directory of Open Access Journals (Sweden)

    Froment G. F.

    2006-11-01

    Full Text Available The paper deals with hydrocracking on metal-loaded zeolites. A fundamental approach is presented in which the detailed reaction network of the feed components of a complex feedstock is retained to a maximum extent. The kinetics are developed in terms of the elementary steps and single events involved in the reactions. Plausible assumptions and thermodynamic constraints limit the number of kinetic parameters. These do not depend on the chain length of the hydrocarbons and are not affected by the feed composition. Certainly, chemical analysis still imposes a certain degree of lumping of components and reaction networks, but not to the extent reflected by present day models. L'article traite de l'hydrocraquage sur des zéolites chargés en métaux. Dans l'approche fondamentale qui est présentée, le réseau de réaction des composants d'une charge complexe est retenu au maximum. La cinétique est établie en suivant pas à pas le déroulement et les étapes élémentaires des réactions. Des hypothèses plausibles et des contraintes thermodynamiques limitent le nombre de paramètres cinétiques. Ceux-ci ne dépendent pas de la longueur de la chaîne des hydrocarbures et ne sont pas affectés par la composition de la charge. L'analyse chimique impose bien sûr encore un certain agrégat des composants et des réseaux de réaction, mais moins que ne reflètent les modèles actuels.

  16. Complexation of the An(IV) by NTA; Complexation des An(IV) par le NTA

    Energy Technology Data Exchange (ETDEWEB)

    Bonin, L. [Paris-11 Univ., 91 - Orsay (France)]|[CEA Valrho, Lab. de Chimie des Actinides (LCA), 30 - Marcoule (France)

    2006-07-01

    In the framework of the Nuclear and Environmental Toxicology program, developed in France, it has been decided to take again the studies concerning the actinides decorporation. A similar study of the neptunium complexation by the citrate ions has been carried out on the complexation of Np(IV) with the nitrilotriacetic acid (NTA). The NTA can be considered as a model molecule of the de-corporating molecules (amino-carboxy- ligand). The results of the spectrophotometric measurements being encouraging, the behaviour of several actinides at the same oxidation state (+IV) (Th(IV), U(IV), Np(IV), and Pu(IV)) has been determined. The experimental results are presented. In order to determine the structure of the complexes of stoichiometry 1:2 An(IV)-(NTA){sub 2} in solution, quantic chemistry calculations and EXAFS measurements have been carried out in parallel. These studies confirm the presence of An(IV)-nitrogen bonds whose length decreases from thorium to plutonium and indicate the presence of a water molecule bound to the thorium and the uranium (coordination number 8 for Np/Pu, 9 for Th/U). The evolution of the complexation constants determined in this study in terms of 1/r (r ionic radius of the cation taking into account its coordination number 8 or 9) confirms the change of the coordination number between Th/U and Np/Pu. (O.M.)

  17. Développement de la mémoire de travail et traitement des phrases complexes : Quelle relation ?

    Directory of Open Access Journals (Sweden)

    Frauenfelder Ulrich

    2012-07-01

    Full Text Available La complexité syntaxique d’une phrase en langage oral peut se caractériser par le nombre et la nature des opérations syntaxiques nécessaires à son élaboration, et notamment par la profondeur de son enchâssement. Cette complexité influence l’âge d’acquisition des différentes structures syntaxiques, les énoncés les plus complexes étant maîtrisés plus tardivement par l’enfant. Certains auteurs attribuent cette acquisition de la syntaxe complexe à des contraintes développementales externes au système linguistique lui-même et notamment à des limitations dans les capacités de mémoire de travail (Jakubowicz, 2007. Ainsi, le traitement d’une phrase complexe engendrerait un coût cognitif important et constituerait une surcharge pour des capacités de mémoire de travail davantage limitées chez le jeune enfant. La maturation normale de ce système mnémonique permettrait ensuite à l’enfant de comprendre et de produire des énoncés de plus en plus complexes. La présente recherche a pour objectif d’éclaircir les liens entre le développement de la mémoire de travail et le traitement des phrases complexes chez l’enfant tout-venant âgé de 5 à 12 ans. Suivant le modèle de la mémoire de travail de Baddeley & Hitch (1986 et les travaux de Barrouillet & Camos (2001, 2007, nous avons appréhendé les compétences de la boucle phonologique via des épreuves d’empans simples (empan direct de chiffres, répétition de mots et de pseudo-mots et la mémoire de travail verbale via des tâches d’empans complexes (empan indirect de chiffres, counting span et running span. Les habiletés syntaxiques des enfants ont été évaluées en compréhension et en répétition d’énoncés complexes. Une analyse d’échantillons de langage spontané a enfin permis de récolter les données liées à l’utilisation de la syntaxe complexe en contexte écologique (LME, taux de subordination et taux d’enchâssement profond. Les

  18. Convection in complex shaped vessel; Convection dans des enceintes de forme complexe

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    The 8 november 2000, the SFT (Societe Francaise de Thermique) organized a technical day on the convection in complex shaped vessels. Nine papers have been presented in the domains of the heat transfers, the natural convection, the fluid distribution, the thermosyphon effect, the steam flow in a sterilization cycle and the transformers cooling. Eight papers are analyzed in ETDE and one paper dealing with the natural convection in spent fuels depository is analyzed in INIS. (A.L.B.)

  19. Electroencephalographic changes in the lateral septum complex following systemic administration of DES-TYR1 -[alpha]-endorphin, Des-Tyr1-[gamma]-endorphin and haloperidol in rats

    NARCIS (Netherlands)

    Urban, I.J.A.; Wied, D. de

    1982-01-01

    The influence of systemically administered Des-Tyr1-α-endorphin (DTαE), Des-Tyr1-γ-endorphin (DTγE) and haloperidol on electroencephalographic (EEG) activity of the lateral septum complex (LSC) and the frontal cortex was studied in male rats. DTαE (2 μg) significantly increased whereas DTγE (10 μg)

  20. Geophysical Well Logs Applied to Geothermal Resource Evaluation Application des diagraphies à l'évaluation des ressources géothermiques

    Directory of Open Access Journals (Sweden)

    Fertl W. H.

    2006-11-01

    Full Text Available Well logging in the petroleum industry has been developed over five decades into a mature industry, whereas geothermal well logging is a relatively new enterprise. Fundamental differences also occur in the geologic environments and key objectives of both logging applications. Geothermal reservoirs are frequently in fractured igneous and metamorphic rocks, which contain hot water or stem at temperature exceeding 150°C. The discussion focuses on present day logging technology, geologic and reservoir engineering objectives, and qualitive and quantitative formation interpretation techniques for geothermal resource evaluation. Specific field case studies illustrate the interpretive state-of-the-art, including examples from the Geysers dry steam field in the Imperial Valley of California, hot water fields in California, Nevada, and Idaho, and the LASL Hot Dry Rock test project in the Valles Caldera of New Mexico. Les diagraphies dans les forages pétroliers ont atteint leur maturité, alors que le contrôle diagraphique des sondages géothermiques est une entreprise relativement nouvelle. Des différences fondamentales apparaissent aussi dans les environnements géologiques et dans les objectifs clés des deux types d'applications des diagraphies. Les réservoirs géothermiques se situent souvent dans les roches ignées ou métamorphiques fracturées qui contiennent de l'eau chaude ou de la vapeur à des températures dépassant 150 °C. L'exposé sera concentré sur les techniques actuelles d'enregistrements, les objectifs géologiques et liés à l'exploitation des réserves et sur les techniques qualitatives et quantitatives d'interprétation des formations pour l'évaluation des ressources géothermiques. Quelques cas particuliers illustrent l'état actuel des techniques d'interprétation avec des exemples pris dans le champ de vapeur sèche des geysers dans Imperial Valley de Californie, des champs d'eau chaude en Californie, Nevada et Idaho et

  1. Characterization of protein/ligand interactions by {sup 1}H/{sup 3}H exchange: application to the hAsf{sup 1}/ histone H{sup 3} complex; Caracterisation des interactions proteine / ligand par echange {sup 1}H/{sup 3}H: application au complexe entre la proteine hAsf{sup 1} et l'histone H{sup 3}

    Energy Technology Data Exchange (ETDEWEB)

    Mousseau, G

    2007-05-15

    In the first chapter will be exposed the main current methods of identification to high debit of the interactions protein-protein. Then the methods allowing to characterize the surfaces of interaction or to determine the structures of the complexes will be listed by discussing the main advantages and the inconveniences. Our approach of characterization of the zones of interaction protein-protein is a method of 'foot-printing' 1, based on the identification and radicals' quantification formed on the residues of proteins accessible to the water. The second chapter will so discuss the development of this method of radical identification using the atom of tritium as radioactive label. Our approach will finally be validated in the third chapter by applying it to the characterization of amino acids involved in the interaction enter the human protein anti silencing factor 1 (hAsf11-156) and a fragment of the histone H{sup 3}. (N.C.)

  2. Sigand : une application SIG sous androïd (tablette de la gestion des chantiers

    Directory of Open Access Journals (Sweden)

    CHAKIB SAFAR BATI

    2016-12-01

    Full Text Available L’introduction de données terrain pour les études environnementales ou de gestion de l’espace, régionales ou locales est une nécessité incontournable pour la validation des traitements et des interprétations mais aussi pour fournir des compléments d’informations aux divers travaux. Mais ce retour terrain est également de plus en plus demandé pour les gestionnaires de chantiers et de projets qui ont une exigence de contrôle ou de suivi et donc d’une information temps réel sur l’avancement des travaux, autrement pour introduire de nouvelles informations sur la base de données géoréférencées. Les avancées technologiques en matière de manipulation de l’information géographique (GPS, tablette graphique, téléphone portable, réalité augmentée permettent d’espérer la mise à dispositiondes professionnels, voire d’un plus large public, des outils adéquats pour de tels travaux. Actuellement, les outils d’élaboration, de gestion et d’exploitation des bases de données géographiques (solutions SIG ne sont pas encore complètement opérationnels en version « tablette » ; des applications telles que Qgis ou ArcGis sous Androïd attendent encore des développements. Nous présentons ici la première version d’une application SIG sous Androïd (disponible sur tablette pour la gestion en temps réel des chantiers qui permet de charger des couches vectorielles et de les mettre à jour sur le terrain en fonction de l’observation directe ; les couches (préalablement géoréférencées sont projetées sur des fonds cartographiques fournis par un serveur cartographique Google Maps (Route, Satellite, terrain; dans le cas d’absence de connexion internet, le fond cartographique est ramené d’un cache. Nous utilisons SpatialiteAndroïd pour le stockage et la manipulation des données géographiques. Le contrôleur de cartes Google Maps est employé pour afficher en mode cartographique les données stockées dans

  3. Fabrication et applications des reseaux de Bragg ultra-longs

    Science.gov (United States)

    Gagne, Mathieu

    quality ultra long fiber Bragg gratings. High quality theory matching ultra long fiber Bragg gratings up to 1 meter long are obtained for the first time. The possibility of fabricating high quality ultra long fiber Bragg grating of more than 10 cm (approximately the maximal phase mask length) opens a variety of new applications otherwise impossible with short fiber Bragg grating technology. Ultra long fiber Bragg gratings have unique characteristics such as high reflectivity, high dispersion and ultra narrow bandwidth. Those characteristics can be used to do advanced signal processing, non linear propagation experiments, distributed feedback fiber lasers and dispersion compensator for telecommunication or optical tomography. The second objective of this project is to use these ultra-long fiber Bragg gratings as an optical cavity for fiber lasers. Alot of research in the past years have been concentrated on those lasers, particularly on distributed feedback fiber lasers where the gratings spans all the gain media. A new random fiber laser configuration is presented. It is based on passive or active insertion of phase shifts along the Bragg grating to obtained a phenomenon called light localization which is the optical equivalent of Anderson localization. This complex wave phenomenon has the unique property to mimic the reflection of a uniform photonic crystal with the random diffusion of light among the elements of a random media. Being commonly obtained in fine powders which must respect a certain set of rules, the realization of 1D structures is vastly simplified in optical fibers. Two random fiber laser schemes based on light localization, one using erbium dopant and the other one Raman scattering, are demonstrated for the first time and compared to traditional distributed feedback fiber lasers.

  4. Acquisition des constructions syntaxiques complexes chez l’enfant français entre 2 et 6 ans

    Directory of Open Access Journals (Sweden)

    Canut Emmanuelle

    2014-07-01

    L’étude développementale réalisée en fonction de l’âge et du type de discours montre une évolution dans la verbalisation des complexités syntaxiques, qui s’avère significative pour certaines d’entre elles à 4 et 5 ans. De plus, la narration dialoguée - c’est-à-dire le récit par l’enfant d’une histoire qui lui a été lue, avec le support des illustrations, dans un cadre interactif – joue un rôle majeur dans cette évolution puisqu’elle permet une augmentation significative de la production de constructions complexes à 5 ans, ce qui n’est pas le cas dans les conversations ordinaires.

  5. Application of radioisotopes to studies of crystal imperfections; Application des radioisotopes a l'etude des imperfections des cristaux; Primenenie radioizotopov dlya izucheniya defektov v kristallakh; Aplicaciones de los radioisotopos al estudio de las imperfecciones cristalinas

    Energy Technology Data Exchange (ETDEWEB)

    Sproull, R L; Slack, G A; Moss, M; Pohl, R O; Krumhansl, J A [Laboratory of Atomic and Solid State Physics, Cornell University, Ithaca, NY (United States)

    1962-01-15

    Radioisotopes have been used in two important ways in studying imperfections in alkali halide crystals. The zone refining of the compounds has been monitored by addition of tracers, and segregation coefficients have been determined from such measurements. The other application has been to insert small concentrations of impurity ions into alkali halides in order to study the phonon scattering by such impurities or by the vacancies they introduce; these measurements are carried out at very low temperatures where the phonon mean free path is limited by lattice imperfections. The most commonly used radioisotope in this work has been Ca{sup 45}. This work is reviewed and some current and possible future applications of radioisotopes in this field are mentioned. (author) [French] Les radioisotopes ont recu deux applications importantes dans l'etude des imperfections des cristaux d'halogenures alcalins. Employes comme indicateurs, ils ont permis de controler le raffinage par zones des composes et, par suite, de determiner les coefficients de segregation. La deuxieme application a consiste a introduire dans les halogenures alcalins de faibles concentrations d'ions sous forme d'impuretes afin d'etudier la diffusion des phonons par ces impuretes ou par les lacunes que celles-ci produisent; les mesures sont effectuees a des temperatures tres basses, auxquelles le libre parcours moyen des phonons se trouve limite par les imperfections du reseau. Le radioisotope le plus frequemment employe pour ces operations a ete le {sup 45}Ca. Le memoire passe en revue ces divers travaux et signale quelques applications effectives ou possibles des radioisotopes dans le domaine considere. (author) [Spanish] Los autores han empleado radioisotopos en dos importantes campos del estudio de los cristales de haluros alcalinos. Uno de estos campos es el control de la purificacion por zonas de los compuestos y la determinacion de los coeficientes de segregacion por medida de las actividades de los

  6. Modélisation des processus physiques et biologiques dans des fosses septiques et voies de valorisation des boues de vidange:Application à Bujumbura-Burundi

    OpenAIRE

    Nsavyimana, Gaston

    2014-01-01

    Dans les pays en développement (PED) en général et au Burundi en particulier, la problématique de gestion des eaux usées et des déchets solides constitue un enjeu majeur pour les spécialistes et les autorités locales. En effet, suite à un manque des stations d'épuration collectives au Burundi, les fosses septiques sont les plus utilisées pour gérer les eaux usées produites. Cependant, les processus qui s'y déroulent ne sont pas encore maîtrisés et la gestion des boues de vidange lorsque c...

  7. Optimization strategies for complex engineering applications

    Energy Technology Data Exchange (ETDEWEB)

    Eldred, M.S.

    1998-02-01

    LDRD research activities have focused on increasing the robustness and efficiency of optimization studies for computationally complex engineering problems. Engineering applications can be characterized by extreme computational expense, lack of gradient information, discrete parameters, non-converging simulations, and nonsmooth, multimodal, and discontinuous response variations. Guided by these challenges, the LDRD research activities have developed application-specific techniques, fundamental optimization algorithms, multilevel hybrid and sequential approximate optimization strategies, parallel processing approaches, and automatic differentiation and adjoint augmentation methods. This report surveys these activities and summarizes the key findings and recommendations.

  8. La province des complexes annulaires alcalins sursaturés de l'adrar des Iforas, Mali

    Science.gov (United States)

    Ba, H.; Black, R.; Benziane, B.; Diombana, D.; Hascoet-Fender, J.; Bonin, B.; Fabre, J.; Liégeois, J. P.

    The Cambrian silica-saturated alkaline province of the Iforas is composed of about 15 massifs including typical large size ring complexes (20-30 km in diameter). Its originality is that it follows closely a regime of subduction blocked by the Pan-African collision (600 Ma) and that each stage of the transition from calcalkaline to alkaline can be related to structural elements in a geodynamic setting. Several complexes are described in some detail. The Kidal-Tibeljeljeline complex starts with the intrusion of syenite porphyries forming external ring dykes, often polygonal in outline, which are truncated by a central massif 30 km in diameter which is composed of a dozen major phases. It complexity is due to the individualization of several intrusive centres and to the fact that the erosional level coincides with that of the flat roof structures. Djounhane, Takellout and Timedjelalen (20-30 km in diameter) are simpler and composed of concentric intrusions youing inwards. Other occurrences are described briefly. The emplacement of all these intrusions at shallow depth in a rigid environment under a thick rhyolitic cover of fissural origin is contemporary to movement along a tear fault system with intermittent periods of distension as shown by spectacular associated dyke swarms. The study shows the presence of both peralkaline and aluminous trends, an evolution of the minerals (pyroxenes, amphiboles and micas), and geochemical characteristics that are quite comparable to those of anorogenic provinces such as Niger and Nigeria. It is important to note, however, the absence of cassiterite and the predominance of subsovus granites in the aluminous trend of the Iforas. The striking similarity between the provinces leads the authors to envisage a common mantle origin, the difference being due rather to the influence of the country rock.

  9. Rôle inflammatoire des plaquettes sanguines : application en transfusion

    OpenAIRE

    Nguyen , Thi Kim Anh

    2013-01-01

    Blood platelets are non-nucleated cells and play a major role in primary hemostasis and a key role in inflammation, innate and adaptive immunity. They secrete a large variety of soluble factors including cytokines/chemokines (CK/CH) and immunomodulator factors. The emergence of their inflammatory role has raised numerous questions based on the ability of platelets to respond to complex stimuli. Our investigations to answer these questions were realized in the context of platelet component tra...

  10. 23 Étude de la compétitivité de complexation des métaux issus des ...

    African Journals Online (AJOL)

    PR BOKO

    par les phénomènes de complexation de l'ion métallique par ses groupements fonctionnels. En plus, l'EDTA possède 4 groupements carboxyliques (tétraacide) dont les pKa sont 1,99 pour la premiere acidité et 2,67 pour la deuxième acidité. Ces deux valeurs de pKa montrent que l'EDTA se comporte comme un acide fort.

  11. Finite Volumes for Complex Applications VII

    CERN Document Server

    Ohlberger, Mario; Rohde, Christian

    2014-01-01

    The methods considered in the 7th conference on "Finite Volumes for Complex Applications" (Berlin, June 2014) have properties which offer distinct advantages for a number of applications. The second volume of the proceedings covers reviewed contributions reporting successful applications in the fields of fluid dynamics, magnetohydrodynamics, structural analysis, nuclear physics, semiconductor theory and other topics. The finite volume method in its various forms is a space discretization technique for partial differential equations based on the fundamental physical principle of conservation. Recent decades have brought significant success in the theoretical understanding of the method. Many finite volume methods preserve further qualitative or asymptotic properties, including maximum principles, dissipativity, monotone decay of free energy, and asymptotic stability. Due to these properties, finite volume methods belong to the wider class of compatible discretization methods, which preserve qualitative propert...

  12. Metal Complexes for Organic Optoelectronic Applications

    Science.gov (United States)

    Huang, Liang

    Organic optoelectronic devices have drawn extensive attention by over the past two decades. Two major applications for Organic optoelectronic devices are efficient organic photovoltaic devices(OPV) and organic light emitting diodes (OLED). Organic Solar cell has been proven to be compatible with the low cost, large area bulk processing technology and processed high absorption efficiencies compared to inorganic solar cells. Organic light emitting diodes are a promising approach for display and solid state lighting applications. To improve the efficiency, stability, and materials variety for organic optoelectronic devices, several emissive materials, absorber-type materials, and charge transporting materials were developed and employed in various device settings. Optical, electrical, and photophysical studies of the organic materials and their corresponding devices were thoroughly carried out. In this thesis, Chapter 1 provides an introduction to the background knowledge of OPV and OLED research fields presented. Chapter 2 discusses new porphyrin derivatives- azatetrabenzylporphyrins for OPV and near infrared OLED applications. A modified synthetic method is utilized to increase the reaction yield of the azatetrabenzylporphyrin materials and their photophysical properties, electrochemical properties are studied. OPV devices are also fabricated using Zinc azatetrabenzylporphyrin as donor materials. Pt(II) azatetrabenzylporphyrin were also synthesized and used in near infra-red OLED to achieve an emission over 800 nm with reasonable external quantum efficiencies. Chapter 3, discusses the synthesis, characterization, and device evaluation of a series of tetradentate platinum and palladium complexesfor single doped white OLED applications and RGB white OLED applications. Devices employing some of the developed emitters demonstrated impressively high external quantum efficiencies within the range of 22%-27% for various emitter concentrations. And the palladium complex, i

  13. Application of solar chargers to prospection instruments; Application des chargeurs solaires aux appareils de prospection

    Energy Technology Data Exchange (ETDEWEB)

    Caille, G [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    The use of conventional batteries has certain disadvantages, and for this reason high-voltage batteries have been gradually replaced in all prospection instruments by transistor supply systems, using less cumbersome sources of energy. All the same low voltages are still necessary, and in hot or damp countries the use of these batteries leads to consumptions out of all proportion to the services rendered. This is why the use of solar energy possesses real advantages. After a brief review of the basic ideas on semiconductors, this article describes a selenium solar battery which was developed by the Westinghouse brakes and signals society. (author) [French] L'utilisation de piles classiques presente certains inconvenients. C'est pourquoi, dans tous les appareils de prospection, les piles fournissant des tensions elevees ont ete remplacees au fur et a mesure par des alimentations a base de transistors, utilisant des sources d'energie moins encombrantes. Toutefois, il faut tout de meme avoir des tensions faibles et l'utilisation de ces piles entraine dans les pays chauds ou humides une consommation disproportionnee par rapport aux services rendus. C'est pourquoi l'emploi de l'energie solaire presente de reels avantages. Cet expose decrit, apres un rappel de notion de base sur les semi-conducteurs, une batterie solaire a base de selenium qui a ete realisee par la Societe des freins et signaux Westinghouse. (auteur)

  14. Complex networks principles, methods and applications

    CERN Document Server

    Latora, Vito; Russo, Giovanni

    2017-01-01

    Networks constitute the backbone of complex systems, from the human brain to computer communications, transport infrastructures to online social systems and metabolic reactions to financial markets. Characterising their structure improves our understanding of the physical, biological, economic and social phenomena that shape our world. Rigorous and thorough, this textbook presents a detailed overview of the new theory and methods of network science. Covering algorithms for graph exploration, node ranking and network generation, among the others, the book allows students to experiment with network models and real-world data sets, providing them with a deep understanding of the basics of network theory and its practical applications. Systems of growing complexity are examined in detail, challenging students to increase their level of skill. An engaging presentation of the important principles of network science makes this the perfect reference for researchers and undergraduate and graduate students in physics, ...

  15. Nouvelle application de control des cavités 200 MHz RF du PS (CERN)

    CERN Document Server

    Cotte, D

    2011-01-01

    Le système Radio Fréquence (RF) 200MHz du PS est un outil essentiel pour la préparation des faisceaux haute intensité du PS. Dans l’anneau PS on trouve 6 cavités 200 MHz utilisées pour contrôler : • l’émittance longitudinale des « bunches » • le processus de « Rebunching » du faisceau avant de l’envoyer au SPS. Chaque cavité est pilotée par des événements appelés « timing » et suit une fonction de tension programmée. Cependant, l’électronique utilisée pour piloter les cavités 200 MHz du PS est obsolète et sa fiabilité non garantie pour cause du manque de pièces de rechange. Ce document décrit le fonctionnement du nouveau programme d’application qui fait abstraction de l’ancienne matrice hardware. Elle suit les recommandations décrites dans l’étude d’une nouvelle structure pour le système RF 200MHz du PS. [1

  16. The application of radioactive isotopes to the study of motion of silt and pebbles in the rivers and in the sea; Application des isotopes radioactifs a l'etude des mouvements des sediments et des galets dans les cours d'eau et en mer

    Energy Technology Data Exchange (ETDEWEB)

    Hours, R [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires; Jaffry, P [Electricite de France (EDF), 78 - Chatou (France). Lab. National d' Hydraulique

    1959-07-01

    The application of radioactive tracers to the study of sediments drift has received considerable attention since 1954 in various countries. A comparative review is made of a number of techniques of labelling, immersing and detecting silts, sands, and pebbles. The influence of the burying of the active material is emphasized. The different experiments which have been so far carried out are described. (author) [French] L'application des traceurs radioactifs a l'etude des deplacements de sediments a fait depuis 1954 l'objet de travaux nombreux dans divers pays. On passe en revue et on compare differentes techniques de marquage, d'immersion et de detection des vases, sables et galets; on insiste sur l'influence de l'enfouissement du materiau actif. On decrit les differentes experiences effectuees jusqu'a ce jour. (auteur)

  17. Thermodynamic Aspects of Supercritical Fluids Processing: Applications of Polymers and Wastes Treatment Aspects thermodynamiques des procédés mettant en oeuvre des fluides supercritiques : applications aux traitements des polymères et des déchets

    Directory of Open Access Journals (Sweden)

    Beslin P.

    2006-11-01

    Full Text Available Supercritical fluid processes are of increasing interest for many fields : in supercritical fluid separation (petroleum-chemistry separation and purification, food industry and supercritical fluid chromatography (analytical and preparative separation, determination of physicochemical properties; as reaction media with continuously adjustable properties from gas to liquid (low-density polyethylene, waste destruction, polymer recycling; in geology and mineralogy (volcanoes, geothermal energy, hydrothermal synthesis; in particle, fibber and substrate formations (pharmaceuticals, explosives, coatings; in drying materials (gels. This paper presents the unusual physicochemical properties of supercritical fluids in relation to their engineering applications. After a short report of fundamental concepts of critical behavior in pure fluids, we develop in more details the tunable physicochemical properties of fluid in the supercritical domain. The second part of this paper describes the engineering applications of supercritical fluids relevant of chemical reactions and polymer processing. Each application presentation is divided in two parts : the first one recalls the basic concepts including general background, physicochemical properties and the second one develops the engineering applications relevant of the advocated domain. La mise en Suvre des fluides supercritiques est d'un intérêt croissant dans de nombreux domaines : pour la séparation (séparation et purification en pétrochimie, industrie alimentaire et la chromatographie par fluides supercritiques (séparation analytique et préparatoire, détermination des propriétés physicochimiques, comme milieux réactifs aux propriétés continûment ajustables allant du gaz au liquide (polyéthylène de faible densité, élimination des déchets, recyclage des polymères, en géologie et en minéralogie (volcanologie, énergie géothermique, synthèse hydrothermique, dans la formation des particules

  18. PREPARATION DES COMPOSITES BENTONITE-DERIVES DE P4VP APPLICATION A LA RETENTION DES COLORANTS TEXTILE

    OpenAIRE

    GADIRI, ANISSA

    2014-01-01

    Les industries du textile rejettent de grandes quantités d‘eaux usées présentant un risque de toxicité. Il existe déjà des traitements tels que l‘adsorption sur charbon actif qui est un processus efficace mais onéreux et qui produit une boue constituant elle même une menace environnementale. Les argiles, les poly (4-vinylpyridine) et ses dérivées pourraient être des matériaux adsorbants alternatifs à la fois économiques et moins polluants. Beaucoup d‘auteurs ont étudié l‘adsorptio...

  19. The theory of discrete barriers and its applications to linear boundary-value problems of the 'Dirichlet type'; Theorie des barrieres discretes et applications a des problemes lineaires elliptiques du ''type de dirichlet''

    Energy Technology Data Exchange (ETDEWEB)

    Jamet, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    This report gives a general presentation of barrier theory for finite difference operators, with its applications to some boundary value problems. (author) [French] Ce rapport est un expose synthetique de la theorie des barrieres pour les operateurs aux differences finies et ses applications a certaines classes de problemes lineaires elliptiques du 'type de Dirichlet'. (auteur)

  20. Ion-molecule interactions of biological importance. A vibrational spectroscopic study of magnesium complexes with hydroxylated quinones; Interactions ions-molecules d'interet biologique. Etude par spectrometrie de vibrations de la complexation du magnesium avec des molecules quinoniques hydroxylees

    Energy Technology Data Exchange (ETDEWEB)

    Kirszenbaum, Marek

    1976-06-14

    Luteoskyrin and rugulosin are two naturally occurring yellow pigments with hydroxylated bis-anthraquinonic structures. They cause serious liver disorders in man due to the formation of complexes of the type pigment-Mg{sup 2+}-DNA. In order to elucidate the structure of these complexes we have studied the vibrational spectra of some model systems, namely 1-hydroxy- and 1,4-dihydroxyanthraquinone, their magnesium chelate complexes, and a series of simpler complexes as the acetylacetonates of some divalent metals. Complete vibrational assignment are proposed for anthraquinone-9,10, the two hydroxylated and deureroxylated derivatives and their magnesium complexes. The substitution of {sup 26}Mg in place of {sup 24}Mg in these complexes enabled us to assign the Mg-O vibrations; their number corresponds to a hexa-coordinated metal in the acetylacetonate case and to a tetra-coordinated structure in the anthraquinone-olates complexes. The position of the ν C=0 and ν C-0 vibrations bands in the complexes shows that the bonds in the chelated ring of Mg(1-O-AQ){sub 2} retains their single and double bond characteristic whereas in the CMg(1,4-O{sub 2},-AQ){sub n} a resonating structure appears in the ring. The study of the IR and R spectra of the complexes enabled a tetrahedral structure to be proposed for the oxygens around the magnesium. Finally it was noted that the Mg-O bonds possessed a high degree of covalent character. (author) [French] La luteoskyrine et la rugulosine, deux pigments jaunes de structure de bis-anthraquinones hydroxylees, provoquent des troubles hepatiques graves par la formation des complexes pigment-Mg{sup 2+}-ADN. Dans le but d'eclaircir la structure de ces complexes nous avons etudie, par spectrometrie de vibrations, les systemes-modeles suivants: la 1-hydroxy- et la 1,4-dihydroxyanthraquinones, leurs complexes magnesies et une serie des complexes plus simples, tels que les acetylacetonates. de metaux divalents. Nous avons propose une attribution

  1. Improved Mask Protected DES using RSA Algorithm

    Directory of Open Access Journals (Sweden)

    Asha Latha S.

    2016-01-01

    Full Text Available The data encryption standard is a pioneering and farsighted standard which helped to set a new paradigm for encryption standards. But now DES is considered to be insecure for some application. Asymmetric mask protected DES is an advanced encryption method for effectively protecting the advanced DES. There are still probabilities to improve its security. This paper propose a method, which introduce a RSA key generation scheme in mask protected DES instead of plain key, which result in enhancement in the security of present asymmetric mask protected DES. We further propose a Vedic mathematical method of RSA implementation which reduce the complexity of computation in RSA block thereby resulting in reduced delay (four timesthat improves the performance of overall system. The software implementation was performed using Xilinx 13.2 and Model-Sim was used for the simulation environment.

  2. Very high temperature measurements: Applications to nuclear reactor safety tests; Mesures des tres hautes temperatures: Applications a des essais de surete des reacteurs nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Parga, Clemente-Jose

    2013-09-27

    This PhD dissertation focuses on the improvement of very high temperature thermometry (1100 deg. C to 2480 deg. C), with special emphasis on the application to the field of nuclear reactor safety and severe accident research. Two main projects were undertaken to achieve this objective: - The development, testing and transposition of high-temperature fixed point (HTFP) metal-carbon eutectic cells, from metrology laboratory precision (±0.001 deg. C) to applied research with a reasonable degradation of uncertainties (±3-5 deg. C). - The corrosion study and metallurgical characterization of Type-C thermocouple (service temp. 2300 deg. C) prospective sheath material was undertaken to extend the survivability of TCs used for molten metallic/oxide corium thermometry (below 2000 deg. C)

  3. Synthèses, caractérisations et étude structurale des complexes de nickel et de cuivre

    OpenAIRE

    DAR KEBIRA, Fatma

    2014-01-01

    La condensation d’o-Vanilline avec 1,3-Diamino-2-propanol dans MeOH absolu dans un rapport molaire 2:1 a donné le ligand base Schiff (H2L). Cette base a été utilisé comme ligand tétradentaté pour coordonner les sels de nickel(II) et de cuivre(II) qui mènent aux complexe métallique où le ratio du (métal – ligand) était 1:1. Tous les composés du nickel(II) et du cuivre(II) ont été caractérisés par spectroscopique infrarouge. Analyse élémentaire et diffraction des rayons X ont été...

  4. La gouvernance des risques naturels et la problematique des ...

    African Journals Online (AJOL)

    Depuis quelques années, la gouvernance des risques naturels dus aux inondations remet en cause les processus de mise en oeuvre des politiques urbaines et la qualité de la structure des aménagements dans les grandes villes du Golfe de Guinée. La perception de la gouvernance et l'application des politiques de ...

  5. New applications of radio-isotopes in France; Quelques nouvelles applications des radioelements en France

    Energy Technology Data Exchange (ETDEWEB)

    Leveque, P; Hours, R; Martinelli, P; May, S; Sandier, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Brillant, J [Societe Soletanche (France)

    1958-07-01

    By measuring the transmission of a flat beam of thermal neutrons, the moisture content of a parallelepiped shaped soil sample can be measured to {+-} 4 per cent and the moisture gradient along the longitudinal axis determined. The method permits the determination of chemically bound water and the measurement of diffusion coefficients of water into low hydrogenated materials. By measuring the intensity of fluorescence excited by 13 radiation it is possible to determine the thickness of metal coatings of less than 20 p. for metals of atomic number less than 40. This method has been applied to chromium, manganese, iron, cobalt, nickel, copper and zinc. By using a suitable metal filter it is possible to measure coating thicknesses of metals differing by only one atomic number from the supporting material. By employing labeled cement it is possible to determine the extent or movement of cement grout used for soil stabilization and waterproofing. The kinetic of ion exchange of different ultramarines in aqueous solutions were studied by tracing the movement of labeled ions in the solution or in the exchanger. Values of the diffusion coefficients and activation energies were determined from the exchange studies. (author)Fren. [French] La mesure de la transmission d'un faisceau plat de neutrons thermiques permet d'evaluer a {+-} 4 pour cent l'humidite d'un echantillon parallelepipedique de sol et d'en effectuer une exploration longitudinale systematique. La methode peut s'appliquer a la determination de l'eau de constitution ainsi qu'a la mesure des coefficients de diffusion de l'eau a travers des substances faiblement hydrogenees. En utilisant la fluorescence X excitee au moyen de rayons {beta} il est possible de mesurer des epaisseurs (< 20) de depots metalliques de faible numero atomique (Z < 40). Ces essais ont porte sur: Cr, Mn, Fe, Co, Ni, Cu et Zn. L'emploi d'ecrans metalliques convenables permet de mesurer l'epaisseur d'un metal dont le numero atomique differe de 1

  6. Diffraction des neutrons : principe, dispositifs expérimentaux et applications

    Science.gov (United States)

    Muller, C.

    2003-02-01

    La diffraction de neutrons, sur monocristal ou sur échantillon polycristallin (ou poudre), est une technique très largement utilisée, en science des matériaux comme en biologie, lorsque l'on souhaite déterminer la structure cristalline d'un composé ou d'une molécule. Toutefois, le degré de précision de la détermination structurale est très corrélé au choix de l'instrument utilisé. Il s'en suit que la question “comment choisir l'instrument le mieux adapté au composé et à la problématique ?" apparaît comme fondamentale. L'objectif de ce cours est de tenter de répondre à cette question en décrivant brièvement les caractéristiques instrumentales de différents diffractomètres, en exposant les avantages spécifiques des expériences de diffraction de neutrons et en donnant quelques exemples d'application.

  7. Rock-Eval 6 Applications in Hydrocarbon Exploration, Production, and Soil Contamination Studies Les applications de Rock-Eval 6 dans l'exploration et la production des hydrocarbures, et dans les études de contamination des sols

    Directory of Open Access Journals (Sweden)

    Lafargue E.

    2006-12-01

    Full Text Available Successful petroleum exploration relies on detailed analysis of the petroleum system in a given area. Identification of potential source rocks, their maturity and kinetic parameters, and their regional distribution are best accomplished by rapid screening of rock samples (cores and/or cuttings using the Rock-Eval apparatus. The technique has been routinely used for about fifteen years and has become a standard tool for hydrocarbon exploration. This paper describes how the new functions of the latest version of Rock-Eval (Rock-Eval 6 have expanded applications of the method in petroleum geoscience. Examples of new applications are illustrated for source rock characterization, reservoir geochemistry, and environmental studies, including quantification. Le succès d'une exploration pétrolière repose sur l'analyse détaillée du système pétrolier dans une zone donnée. L'identification des roches mères potentielles, la détermination de leur maturité, de leurs paramètres cinétiques et de leur répartition sont réalisées au mieux à partir d'examens rapides d'échantillons de roches (carottes ou déblais au moyen de la pyrolyse Rock-Eval. Cette technique a été utilisée en routine pendant une quinzaine d'années et elle est devenue un outil standard pour l'exploration des hydrocarbures. Cet article décrit comment les nouvelles fonctionnalités de la dernière version de l'appareil Rock-Eval (Rock-Eval 6 ont permis une expansion des applications de la méthode en géosciences pétrolières. Des exemples d'applications nouvelles sont illustrés dans les domaines de la caractérisation des roches mères, de la géochimie de réservoir et des études environnementales incluant la quantification et la description des hydrocarbures dans des sols contaminés.

  8. Iminoéthers-1 3 cycliques : chimie et applications dans le domaine des additifs pétroliers et des matériaux organiques Cyclic 1,3-Iminoethers: Chemistry and Applications in the Field of Petroleum Additives and Organic Materials

    Directory of Open Access Journals (Sweden)

    Le Perchec P.

    2006-11-01

    Full Text Available Cet article est consacré aux iminoéthers-1,3 cycliques les plus courants : les oxazines-1,3 et oxazolines-1,3. La première partie rappelle les synthèses de ces composés et quelques aspects récents de leur chimie : réactions d'hydrolyse, réactions de déprotonation avec ouverture de cycle, réactions des organométalliques, réactions d'addition des nucléophiles en positions 2 et 5, des sels d'iminoéthers correspondants, propriétés complexantes vis-à-vis des métaux, réactions d'aminolyse et formation de structures tensioactives, enfin polymérisations et copolymérisations cationiques. La seconde partie est consacrée à l'étude des travaux qui traitent des applications. En ce qui concerne le domaine des additifs pétroliers, on s'intéresse à la stabilité du cycle oxazoline et à son caractère polaire. Les dérivés tensioactifs dérivés d'oxazoline portant des chaînes hydrocarbonées ont été revendiqués comme additifs dispersants et multifonctionnels pour les carburants et les lubrifiants. De nombreuses formulations (dispersants, antioxydants antirouilles, antiusures, extrême pressions, réducteurs de frictions. . . ont été proposées. Certains dérivés d'hydroxyméthyl oxazolines présentent des propriétés lubrifiantes et d'autres ont un intérêt dans les formulations de boues de forage. En ce qui concerne le domaine des matériaux, on s'intéresse à la réactivité du cycle oxazoline pour réaliser soit des extensions de chaînes des thermoplastiques, soit des réticulations pour des applications de peintures et revêtements. Les homopolymères d'oxazoline qui ont un caractère polaire très marqué peuvent trouver des applications comme promoteur d'adhésion, ou tensioactifs pour les polymérisations en émulsion. Enfin, l'utilisation d'oxazolines stables a été revendiquée dans des formulations de vernis d'émaillage. This article deals with the most common cyclic 1,3-iminoethers, i. e. 1,3-oxazines and 1

  9. Wave Separation. Part Two: Applications La séparation des ondes. Deuxième partie : applications

    Directory of Open Access Journals (Sweden)

    Glangeaud F.

    2006-11-01

    qui doit être de plus grande amplitude. Le filtrage est effectué sans effet de bord et les variations d'amplitude de l'onde sont préservées. Il permet de séparer les données en un espace signal et un espace bruit. Le filtre SMF (matrice spectrale est coûteux en temps de calcul. Il fait l'hypothèse que l'onde est localement stable. Il ne nécessite pas la mise à plat des données. Il permet de séparer des ondes très voisines sans faire appel à des hypothèses a priori fortes. Il donne une mesure des écarts de temps. Il donne une mesure des variations de spectre d'amplitude et de phase lors de la propagation bien supérieure à celle fournie par la méthode de Wiener puisqu'il opère sur l'ensemble des traces. Il permet également de séparer les données en un espace signal et un espace bruit. La méthode paramétrique est la plus coûteuse en temps. Elle est simple à mettre en oeuvre et ne nécessite ni mise à plat ni préparation de données. Elle extrait les ondes en fonction des paramètres retenus, notamment les écarts de temps. Elle est particulièrement recommandée en profil sismique déporté où la lenteur des ondes montantes n'est pas connue. Elle est robuste vis-à-vis de quelques paramètres d'entrée si le bruit est faible par le rapport au signal à extraire. Les multiples applications à des données réelles ont illustré l'efficacité de ces techniques de séparation d'ondes. Par contre, l'application à un nouveau type de données nécessite souvent un contrôle des performances pour choisir la meilleure méthode.

  10. Formulation and applications of complex network theory

    Science.gov (United States)

    Park, Juyong

    In recent years, there has been a great surge of interest among physicists in modeling social, technological, or biological systems as networks. Analyses of large-scale networks such as the Internet have led to discoveries of many unexpected network properties, including power-law degree distributions. These discoveries have prompted physicists to devise novel ways to model networks, both computational and theoretical. In this dissertation, we present several network models and their applications. First, we study the theory of Exponential Random Graphs. We derive it from the principle of maximum entropy, thereby showing that it is the equivalent of the Gibbs ensemble for networks. Using tools of statistical physics, we solve well-known and new examples that include power-law networks and the two-star model. Our solutions confirm the existence of a first-order phase transition for the latter whose exact behavior has not been presented previously. We also study degree correlations and clustering in networks. Degrees of adjacent vertices are positively correlated in social networks, whereas they are negatively correlated in other types of networks. We demonstrate that a negative degree correlation is a more natural state of a network, and therefore that social networks are an exception. We argue that variations in the number of vertices in social groups cause positive degree correlations, and analyze a model that incorporates such a mechanism. The model indeed shows a high level of degree correlation and clustering that is similar in value to those of real networks. Finally, we develop algorithms for ranking vertices in networks that represent pairwise comparisons. The first algorithm is based on the familiar concept of indirect wins and losses. The second algorithm is based on the concept of retrodictive accuracy, which is maximized by positioning as many winners above the losers as possible. We compare the rankings of American college football teams generated by our

  11. Application des techniques de diffusion de la lumière des rayons X et des neutrons à l'étude des systèmes colloïdaux. Première partie : Présentation théorique des trois techniques Application of Light, X-Ray and Neutron Diffusion Techniques to the Study of Colloidal Systems. Part One : Theoretical Description of Three Techniques

    Directory of Open Access Journals (Sweden)

    Espinat D.

    2006-11-01

    Full Text Available Les techniques de diffusion, des rayons X, des neutrons et de la lumière, jouent un rôle très important pour la compréhension des milieux colloïdaux. Peu d'articles de la littérature s'attachent à présenter conjointement les trois méthodes. Nous avons, dans la première partie de cet article, détaillé les principes théoriques en insistent tout particulièrement sur les spécificités de chacune. Après les rappels concernant la diffusion par les systèmes dilués, nous nous sommes intéressés aux systèmes concentrés pour lesquels les entités diffusantes sont en interaction. Les milieux dispersés montrent souvent une certaine polydispersité que l'on cherche à mesurer; les techniques de diffusion permettent cette mesure. Nous terminerons cette revue par une description des appareillages utilisés. La deuxième partie de cet article concernera une large illustration des possibilités de ces méthodes d'analyse à l'étude des systèmes colloïdaux, sur la base de travaux effectués à I'IFP (Institut Français du Pétrole ou dans de nombreux laboratoires de recherche extérieurs. This article aims to describe X-ray, neutron and light scattering techniques with emphasis on their specific nature and their scope of application. Indeed, whereas light diffusion has been used for a long time in research laboratories, in particular for characterizing polymers in solution, small angle X-ray scattering has been the subject of renewed interest in recent years. Neutron scattering, which is obviously more difficultly accessible, has proven to be extremely useful for studying various systems for which light and X-ray scattering remain relatively powerless. Whereas there is an abundant literature concerning various applications of the three methods, it should be noted that only a few articles have attempted to describe all three techniques at the same time. In this article we have tried to make up for this lack, and as such it was

  12. Complexation studies of actinides (U, Pu, Am) with linear polyamino-carboxylate ligands and sidero-chelates; Etudes de la chelation d'actinides (U, Pu, Am) par des ligands polyaminocarboxylate lineaires et des siderochelates d'interet environnemental

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, L.V.

    2010-11-25

    As part of our research endeavour aimed at developing and improving decontamination processes of wastewater containing alpha emitters, physico-chemical complexation studies of actinides (U, Pu, Am) with organic open-chain ligands such as poly-aminocarboxylic acids (H{sub 4}EDTA) and sidero-chelates (di-hydroxamic acids and desferrioxamine B) have been carried out. Gaining a clear understanding of the coordination properties of the targeted actinides is an essential step towards the selection of the most appropriate chelating agents that will exhibit high uptake efficiencies. EXAFS (Extended X-ray Absorption Fine Structure) measurements at the ESRF synchrotron enabled to elucidate the coordination scheme of uranium and plutonium complexes. Solution thermodynamic investigations were intended to provide valuable information about the nature and the stability of the uranium(VI) and americium(III) complexes prevailing at a given pH in solution. The set of stability constants determined from potentiometric and UV-visible spectrophotometric titrations, allowed to predict the speciation of the selected actinides in presence of the aforementioned ligands and to determine the pH range required for achieving 'ultimate' decontamination. (author) [French] Dans le cadre du developpement et de l'amelioration des procedes de decontamination d'effluents aqueux contamines par des radioelements emetteurs alpha, des etudes physico-chimiques sur la complexation des actinides (U, Pu, Am) avec des ligands organiques tels que des acides polyaminocarboxyliques lineaires (H{sub 4}EDTA) et des siderochelates (acides dihydroxamiques et desferrioxamine B) ont ete effectuees. La comprehension des proprietes de coordination est une etape essentielle pour selectionner les meilleurs agents chelatants qui se montreront efficaces dans le traitement des effluents. Les schemas de coordination des complexes d'uranium et de plutonium avec ces ligands ont ete determines a l

  13. Applications of Nonlinear Dynamics Model and Design of Complex Systems

    CERN Document Server

    In, Visarath; Palacios, Antonio

    2009-01-01

    This edited book is aimed at interdisciplinary, device-oriented, applications of nonlinear science theory and methods in complex systems. In particular, applications directed to nonlinear phenomena with space and time characteristics. Examples include: complex networks of magnetic sensor systems, coupled nano-mechanical oscillators, nano-detectors, microscale devices, stochastic resonance in multi-dimensional chaotic systems, biosensors, and stochastic signal quantization. "applications of nonlinear dynamics: model and design of complex systems" brings together the work of scientists and engineers that are applying ideas and methods from nonlinear dynamics to design and fabricate complex systems.

  14. Application of mathematical methods to the investigation of uranium deposits; Application des methodes mathematiques a l'etude des gisements d'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Formery, P; Ziegler, V [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    It may be considered approximately that grades, widths and accumulations (grade-width products), in french uranium deposits are distributed according to a lognormal law. This property associated to KRIGE'S and de WIGE'S formulae make a powerful tool in ore deposits surveys. The correlation between radioactivities and grades is realized, in logarithmic coordinates, through a straight line the properties of which are analysed in the paper. MATHERON'S recent works, in association with data of classical statistics and the above mentioned formulae make possible to complete the ore reserves evaluation by computing the accuracy. Statistical methods applied to ore deposits have given birth to a parameter which is as important as the mean grade for characterisation of deposits: the absolute dispersion. (author) [French] On peut considerer en premiere approximation que les teneurs, les puissances et les accumulations se distribuent dans les gisements fran is d'uranium suivant une loi log normale. Cette propriete, associee aux hypotheses de De WIGE et de KRIGE, constitue un puissant instrument d'etude des gisements. La correspondance des radioactivites et des teneurs s'effectue, en coordonnees bilogarithmiques, par une droite dont on etudie les proprietes. Grace aux travaux recents de MATHERON, associes aux donnees de la statistique classique ainsi qu'aux hypotheses enumerees plus haut, il est possible de completer le calcul des reserves d'un gisement par une evaluation de l'erreur commise. Les methodes statistiques ont fait apparaitre un parametre aussi important pour caracteriser un gisement, que la teneur moyenne: la dispersion absolue. (auteur)

  15. How nature works complexity in interdisciplinary research and applications

    CERN Document Server

    Sanayei, Ali; Zenil, Hector; Rössler, Otto

    2014-01-01

    This book is based on the outcome of the “2012 Interdisciplinary Symposium on Complex Systems” held at the island of Kos.  The book consists of 12 selected papers of the symposium starting with a comprehensive overview and classification of complexity problems, continuing by chapters about complexity, its observation, modeling and its applications to solving various problems including real-life applications. More exactly, readers will have an encounter with the structural complexity of vortex flows, the use of chaotic dynamics within evolutionary algorithms, complexity in synthetic biology, types of complexity hidden inside evolutionary dynamics and possible controlling methods, complexity of rugged landscapes, and more. All selected papers represent innovative ideas, philosophical overviews and state-of-the-art discussions on aspects of complexity.  The book will be useful as instructional material for senior undergraduate and entry-level graduate students in computer science, physics, applied mathemat...

  16. Applications of radionuclides in industry; Applications des radioelements a l'industrie

    Energy Technology Data Exchange (ETDEWEB)

    Leveque, P [Commissariat a l' Energie Atomique, Paris (France). Centre d' Etudes Nucleaires

    1955-07-01

    After a brief recall of a few concepts (mass number, charge and beams properties) and the description of used detectors (ionization chamber, Geiger-Mueller counter, scintillation counters), some radionuclides applications are described. In a first part, the well-developed applications are presented in three distinct groups: continuous applications such as {beta} and {gamma} gauges (determination hydrogen content of an hydrocarbon and content of an emulsion; discharge of static electricity), discontinuous applications such as radiography and autoradiography, wear or manufacture problems (distribution of a fungicide on tobacco) and finally, applications in research laboratories such as diffusion, exchange and solubility. It also describes the applications which are still in development such as the action of beams on matter (reticulation and degradation of polymers, monomers polymerisation, cold sterilization). In conclusion, few advices on the opportunity of such applications and the choice of the radionuclides are given. (M.P.)

  17. Détermination des radionucléides dans le repas. Application aux ...

    African Journals Online (AJOL)

    40 sont des radionucléides naturels présents dans les riz, les tubercules, les bouillons et les friandises. Dans les quatre échantillons des repas du Riz analysés, les activités spécifiques en potassium-40 sont différentes. Cette différence est ...

  18. Geologic constraints and speleogenesis of Cova des Pas de Vallgornera, a complex coastal cave from Mallorca Island (Western Mediterranean

    Directory of Open Access Journals (Sweden)

    Joaquín Ginés

    2014-05-01

    Full Text Available The flat areas of eastern and southern Mallorca host a remarkable coastal karst, where Cova des Pas de Vallgornera stands out due to its length (more than 74 km and its special morphological suite. The pattern of the cave is quite heterogeneous showing sharp differences produced by the architecture of the Upper Miocene reef: spongework mazes and collapse chambers dominate in the reef front facies, whereas joint-guided conduits are the rule in the back reef carbonates. Regarding the speleogenesis of the system, a complex situation is envisaged involving three main agents: coastal mixing dissolution, drainage of meteoric diffuse recharge, and hypogene basal recharge related to local geothermal phenomena. The cave system is disposed in two main tiers of passages, of which geomorphologic interpretations are derived from their elevation data. The evolutionary trends as well as the chronology of the different cave sections are difficult to establish owing to the frequent shifting of the coastal base level during the Plio-Quaternary. In this respect, the genesis and evolution of the cave were fully controlled by sea-level fluctuations in the Western Mediterranean basin, with the main phases of cave formation, based on vertebrate paleontological data, going back to mid-Pliocene times.

  19. Theoretical study of the electronic structure of f-element complexes by quantum chemical methods; Analyse de la structure electronique des complexes contenant des elements F par des methodes de la chimie quantique

    Energy Technology Data Exchange (ETDEWEB)

    Vetere, V

    2002-09-15

    This thesis is related to comparative studies of the chemical properties of molecular complexes containing lanthanide or actinide trivalent cations, in the context of the nuclear waste disposal. More precisely, our aim was a quantum chemical analysis of the metal-ligand bonding in such species. Various theoretical approaches were compared, for the inclusion of correlation (density functional theory, multiconfigurational methods) and of relativistic effects (relativistic scalar and 2-component Hamiltonians, relativistic pseudopotentials). The performance of these methods were checked by comparing computed structural properties to published experimental data, on small model systems: lanthanide and actinide tri-halides and on X{sub 3}M-L species (X=F, Cl; M=La, Nd, U; L = NH{sub 3}, acetonitrile, CO). We have thus shown the good performance of density functionals combined with a quasi-relativistic method, as well as of gradient-corrected functionals associated with relativistic pseudopotentials. In contrast, functionals including some part of exact exchange are less reliable to reproduce experimental trends, and we have given a possible explanation for this result . Then, a detailed analysis of the bonding has allowed us to interpret the discrepancies observed in the structural properties of uranium and lanthanides complexes, based on a covalent contribution to the bonding, in the case of uranium(III), which does not exist in the lanthanide(III) homologues. Finally, we have examined more sizeable systems, closer to experimental species, to analyse the influence of the coordination number, of the counter-ions and of the oxidation state of uranium, on the metal-ligand bonding. (author)

  20. Application of colony complex algorithm to nuclear component optimization design

    International Nuclear Information System (INIS)

    Yan Changqi; Li Guijing; Wang Jianjun

    2014-01-01

    Complex algorithm (CA) has got popular application to the region of nuclear engineering. In connection with the specific features of the application of traditional complex algorithm (TCA) to the optimization design in engineering structures, an improved method, colony complex algorithm (CCA), was developed based on the optimal combination of many complexes, in which the disadvantages of TCA were overcame. The optimized results of benchmark function show that CCA has better optimizing performance than TCA. CCA was applied to the high-pressure heater optimization design, and the optimization effect is obvious. (authors)

  1. « Faire clair et vif avec des éléments complexes »

    Directory of Open Access Journals (Sweden)

    Cordula Reichart

    2010-12-01

    Full Text Available Avec le roman Salammbô et le conte Hérodias, Flaubert se tourne vers l’Antiquité préchrétienne afin de montrer à la modernité, sur le mode « clair et vif », sa complexité, son implication dans des discours de pouvoir religieux et historiographiques. C’est en se penchant sur les sources historiographiques et bibliques que Flaubert décline les stratégies d’exclusion et de surécriture, mettant au jour ce qu’elles refoulent, non pas sous forme de signification alternative, explicite, mais en tant que défiguration, réalisation littérale des corps et des signes.Avec Salammbô, Flaubert écrit une histoire du salut. Carthage, représentée dès le début par la protagoniste Salammbô en tant que pars pro toto, expose les figures cachées de Rome, à laquelle est liée, aussi et surtout, la promesse chrétienne de salut. Dans le nom de Salammbô Flaubert réécrit l’origine de cette figure en fait associée à la Rome chrétienne en s’appuyant sur l’exemple de l’histoire antique de Carthage.Dans Hérodias, Flaubert reprend le thème du triomphe de l’Orient annoncé par Renan et redouté par l’Église catholique. Un danger, pourrait-on dire, qui se réalise dans la figure d’Hérodias et qui est conjuré avec la décapitation de Jean. Dans son rapport inversé avec les textes de référence, Hérodias démasque les ambitions et la volonté hégémonique du modèle de pouvoir propre à l’Église en Orient. La translatio de l’empire romain est radicalisée au moyen de la figure d’Aulus. Aulus peut faire l’objet d’une lecture performative en tant que début et fondement de l’histoire française du salut comme histoire romaine de la perversion.In the novel Salammbô and the short story Hérodias, Flaubert turns to pre-Christian antiquity in order to present modernity its complexity, its entwinement in religious and historiographical discourses of power, in a « clair et vif » manner. In Salammb

  2. Development of mercury porosimeter. Application to nuclear graphite studies (1961); Mise au point d'un porosimetre a mercure. Application a l'etude des graphites nucleaires (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Bocquet, M; Genisson, J; Sailleau, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-07-01

    A mercury porosimeter, model IFP-CEA, has been developed for application to nuclear graphite studies. The apparatus is based on the capillary depression phenomenon. The relationship between the radius of a pore and the pressure at which mercury fills it is pr = -2 {sigma} cos {theta} ( {sigma} is the surface tension, {theta} the angle of contact of the mercury). After some theoretical consideration, the apparatus is described. The mercury pressure is increased step-wise from 0 to 1000 kg/cm{sup 2} thus yielding the complete distribution of pores from 92 {mu} to 75 A. Results are, then presented concerning nuclear graphites which show the evolution of the porous structure under the effect of bitumen impregnation. In general, the volume of the large pores decreases while that of the small pores increases. The structure of impregnated products appears to depend to a certain extent on that of the starting materials. It has also been possible to study other products with this porosimeter; the range of measurements possible is such that it may be used for the study of the majority of porous materials. (authors) [French] Un porosimetre a mercure modele IFP-CEA a ete mis au point en vue de son application a l'etude de graphites nucleaires. Le fonctionnement de l'appareil repose sur le phenomene de depression capillaire. On etablit la relation existant entre le rayon r d'un pore et la pression p pour laquelle le mercure peut y penetrer: pr = -2 {sigma} cos {theta} ( {sigma} tension superficielle, {theta} angle de contact du mercure). Apres quelques considerations theoriques, l'appareil utilise est decrit. Il permet de faire varier par palier la pression du mercure entre 0 et 1000 kg/cm{sup 2} et d'etablir ainsi la distribution complete des rayons de pores compris entre 92 {mu} et 75 A. Les resultats d'une etude faite sur des graphites nucleaires sont alors presentes faisant apparaitre l'evolution de la structure poreuse sous l'effet des impregnations au brai. D'une facon

  3. Caractérisation intégrée du vignoble alsacien : aspects méthodologiques et application à l'étude des composantes naturelles des principaux terroirs

    Directory of Open Access Journals (Sweden)

    Éric Lebon

    1993-12-01

    Full Text Available Parmi les méthodes utilisées en vue de la définition des potentialités viticoles, l'approche intégrée des terroirs fondée sur la notion de séquence écogéopédologique développée en Moyenne Vallée de la Loire par l'INRA d'Angers s'est révélée particulièrement performante. Son application à la caractérisation du vignoble d'Alsace, fondamentalement différent sur le plan de sa structure géologique, nécessite un certain nombre d'aménagements méthodologiques liés à une variabilité paysagère marquée. Ainsi, une typologie des paysages s'appuyant sur des paramètres tels que l'ouverture du paysage, la répartition et l'orientation des masques est proposée. Elle vient compléter les descripteurs stationnels classiques (altitude, pente et exposition. Le concept de séquence écogéopédologique reste pertinent dans ce contexte moyennant l'adjonction du paramètre exposition, dans le cas des terroirs sur versants. Dans cette optique, les caractéristiques des composantes naturelles des grands types de terroirs alsaciens sont présentées à partir de l'étude de cas concrets.

  4. Applications des techniques de diffusion de la lumière, des rayons X et des neutrons a l'étude des systèmes colloïdaux. Troisième partie : caractérisation des microémulsions et des composés solides. Étude de différents systèmes d'intérêt industriel Application of Light, X-Ray and Neutron Diffusion Techniques to the Study of Colloidal Systems. Part Three: Microemulsions, Solid Materials, Liquids and Miscellaneous Systems with Industrial Uses

    Directory of Open Access Journals (Sweden)

    Espinat D.

    2006-11-01

    Full Text Available Cette troisième partie clôt une revue bibliographique concernant la caractérisation des systèmes colloïdaux par les techniques de diffusion (lumière, rayons X, neutrons (Rev. Inst. Franç. du Pétrole, Vol. 45, No 6, novembre-décembre 1990. Nous poursuivrons cette présentation en nous intéressant aux microémulsions. Après la présentation des informations que l'on peut obtenir sur les systèmes polymériques, les solutions micellaires ou les systèmes fractals, qui ont fait l'objet de multiples travaux, nous reviendrons sur les applications plus restreintes à des systèmes colloïdaux parfois moins bien définis et d'origine industrielle, telles les fractions lourdes des pétroles, les asphaltènes ou encore les additifs de lubrification. Les possibilités de la diffusion des rayons X et des neutrons à l'étude de matériaux solides seront présentées à travers la caractérisation des solides poreux et en particulier des catalyseurs. Nous terminerons cette présentation par les liquides purs ou les mélanges; les techniques de diffusion ont contribué fortement à la description des structures des phases liquides. This article is the second one (the first one was published in Revue de l'Institut Français du Pétrole No. 6, November-December 1990 concerning the application of techniques of light scattering, X rays and neutrons to the analysis of colloidal systems and more specifically to the theoretical description of the three methods. The aim of this second part is to make a nonexhaustive description of several fields of applications. A special effort is made to describe the potential of these methods for characterizing colloidal or divided systems encountered in a great many activities involving the petroleum industry. The first part of this article takes up polymer and colloidal solutions. Particular attention is paid to the importance of scattering techniques for characterizing polymers in solution and micellar solutions. A

  5. Des SIG-P pour sauver le complexe forestier de la basse rivière Tana?

    International Development Research Centre (IDRC) Digital Library (Canada)

    L'objectif général de ce programme panafricain est de contribuer à rendre disponibles des systèmes d'information de bonne qualité, fiables et accessibles grâce à l'usage de SIG-P en vue d'améliorer la gestion des ressources naturelles (eau, terres, forêts, etc.) et de promouvoir la sécurité alimentaire. Le programme ...

  6. Advances in real and complex analysis with applications

    CERN Document Server

    Cho, Yeol; Agarwal, Praveen; Area, Iván

    2017-01-01

    This book discusses a variety of topics in mathematics and engineering as well as their applications, clearly explaining the mathematical concepts in the simplest possible way and illustrating them with a number of solved examples. The topics include real and complex analysis, special functions and analytic number theory, q-series, Ramanujan’s mathematics, fractional calculus, Clifford and harmonic analysis, graph theory, complex analysis, complex dynamical systems, complex function spaces and operator theory, geometric analysis of complex manifolds, geometric function theory, Riemannian surfaces, Teichmüller spaces and Kleinian groups, engineering applications of complex analytic methods, nonlinear analysis, inequality theory, potential theory, partial differential equations, numerical analysis , fixed-point theory, variational inequality, equilibrium problems, optimization problems, stability of functional equations, and mathematical physics.  It includes papers presented at the 24th International Confe...

  7. Application of Complex Adaptive Systems in Portfolio Management

    Science.gov (United States)

    Su, Zheyuan

    2017-01-01

    Simulation-based methods are becoming a promising research tool in financial markets. A general Complex Adaptive System can be tailored to different application scenarios. Based on the current research, we built two models that would benefit portfolio management by utilizing Complex Adaptive Systems (CAS) in Agent-based Modeling (ABM) approach.…

  8. Choix d'un modèle pluie-ruissellement pour des conditions hydrologiques complexes

    Science.gov (United States)

    Gárfias, Jaime; Verrette, Jean-Louis; Antigüedad, Iñaki; André, Cécile

    1996-03-01

    The main purpose of this study is to compare the application possibilities of different rainfall-runoff models and how to choose that which best corresponds to certain hydrological conditions. The system chosen for analysis lies in the Bolivian highlands. The region is drained by the River Desaguadero, which flows out of Lake Titicaca (altitude 3810 m), and into Lake Poopo (altitude 3686 m). Following an analysis of hydrological models in general, the conclusions are applied to the particular characteristics of the Bolivian highlands. A simulation procedure, based on the decomposition of the basin into elements, was used. Detailed provisions to represent the losses along one of the channel reaches led to significant improvements in the simulation. It is concluded that channel losses are due to the characteristic geographic position and the specific characteristics of the system. The results of the study suggest that modelling of the surface water runoff may be applied with success in the Bolivian highlands but that the present, commonly used, methods are inadequate and adjustments are necessary.

  9. Other applications of neutron beams in material sciences; Autres utilisations des faisceaux de neutrons en science des materiaux

    Energy Technology Data Exchange (ETDEWEB)

    Novion, C.H. de

    1997-12-31

    The various applications of neutron beams are reviewed. The different mechanisms involved in neutron interaction with matter are explained. We notice that generally neutron radiation effects are unfavorable but can be turned into efficient tools to add new structures or properties to materials, silicon doping is an example. The basis principles of neutron activation analysis and neutron radiography are described. (A.C.)

  10. Some applications of semiclassical methods to quantum chaos; Quelques applications des methodes semiclassiques en chaos quantique

    Energy Technology Data Exchange (ETDEWEB)

    Mouchet, A

    1996-11-29

    This thesis is made of four chapters. The first chapter is devoted to the description of the band structure, using the semiclassical periodic orbit theory, for a one electron system in a two-dimensional crystal with a high magnetic field perpendicular to the crystal plane. Complex orbits turn out to be fundamental for a proper description of the band structure since they incorporate conduction processes through tunneling mechanisms. In the second part, the author focuses on the role played in semiclassical expansions by complex orbits. They give exponentially small contribution when h is small only in a precise situation. In all other cases, complex orbits give birth to corrections in powers in h but unlike the extreme case they are hidden in the shadow of usual Gutzwiller contributions of real orbits. In the third chapter, a semiclassical expansion of the Berry two-form in terms of finite number of periodic orbits for a discrete chaotic map defined on a compact phase space and governed by external parameters is given. Besides, when dealing with a toroidal geometry, the author gives a similar expansion for the Chern index of any Bloch band of the quasi-energy spectrum and is thus led to a semiclassical interpretation of the Hall effect. In the last chapter, the author sets out a mechanism to explain how symmetries can create Berry phase shifts higher than 2{pi} in a 3D-adiabatic transport. He shows how one can understand in a topological point of view why these shifts are necessarily integer multiple of 2{pi}. An explicit construction of such arbitrary large phase shifts is finally proposed. (N.T.).

  11. Spectral Matrix Filtering Applied to Vsp Processing Application du filtrage matriciel au traitement des profils sismiques verticaux

    Directory of Open Access Journals (Sweden)

    Glangeaud F.

    2006-11-01

    données et de séparer ces signaux. Nous montrons que les signaux peuvent être automatiquement séparés sans connaissance a priori sur leurs vitesses apparentes, en fonction du produit scalaire (calculé dans le domaine fréquentiel et de l'amplitude relative des signaux. Nous montrons des exemples d'application sur des données de sismique de puits. Le filtrage matriciel est effectué dans le domaine fréquentiel en utilisant la matrice spectrale construite à l'aide des intercorrélations des différents enregistrements constituant les données à traiter. Les méthodes d'estimation de la matrice spectrale sont des méthodes de moyenne : moyenne en fréquence (méthode du périodogramme lissé et/ou moyenne en distance (lissage réalisé le long des diagonales de la matrice spectrale. Le lissage en fréquence est obtenu par l'intermédiaire d'une fonction de pondération (par exemple fenêtre de Hanning élevée à une puissance donnée appliquée à chaque corrélation. Les moyennes sont utilisées pour décorréler les signaux et de ce fait favoriser la séparation. Une fois correctement estimée, la matrice spectrale est diagonalisée sur toutes les fréquences du spectre moyenné, et décomposée selon ses vecteurs propres qui sont orthogonaux entre eux et normalisés. Chaque vecteur propre a une valeur propre associée qui représente la répartition d'énergie en fonction de la fréquence du modèle lié au vecteur propre. Le filtrage est réalisé par projection des données sur les différents vecteurs propres issus de la matrice spectrale. Il est à noter cependant que la séparation des différents signaux (projection sur vecteur propre n'est réalisée en terme d'indicatrice sismique que si les événements sismiques sont naturellement orthogonaux et alignés sur les vecteurs propres. Glangeaud et al (1989 ont étudié l'influence des amplitudes relatives et du produit scalaire de deux ondes. Si la vitesse apparente d'une onde est connue, cette derni

  12. Analytical representation of time correlation functions and application to relaxation problems; Representation analytique des fonctions de correlation temporelle et application a des problemes de relaxation

    Energy Technology Data Exchange (ETDEWEB)

    Dupuis, M [Commissariat a l' Energie Atomique, 91 - Saclay (France). Centre d' Etudes Nucleaires, departement de physico-chimie, services des isotopes stables

    1971-07-01

    Two analytical representations of the Laplace transform of the time autocorrelation of a dynamical variable, namely the moment expansion and Mori's continued fraction expansion, are investigated from the point of view of structure and convergence properties, and the relation between them is established. The general theory is applied first to a dynamical model exactly solvable, the isotopic impurity in a linear chain of coupled harmonic oscillators, and then to two stochastic models recently introduced by Gordon for the rotational diffusion of molecules. In the latter case, the continued fraction expansion yields simple analytical expressions for the infrared absorption band shapes, showing that these models contain all the features of observed shapes in compressed gases, liquids and solutions. (author) [French] Deux representations analytiques de la transformee de Laplace de la fonction d'autocorrelation temporelle d'une variable dynamique, le developpement en moments et le developpement en fraction continue recemment introduit par Mori, sont etudiees du point de vue de leurs proprietes de structure et de convergence, en meme temps que la relation qui existe entre elles est etablie. La theorie generale est appliquee, d'une part, a un modele dynamique exactement soluble, celui d'une particule isotopique dans une chaine lineaire d'oscillateurs harmoniques couples, et, d'autre part, a deux modeles stochastiques recemment proposes par Gordon pour la diffusion rotationnelle des molecules. Dans ce dernier cas, la voie de la fraction continue fournit des expressions analytiques simples pour les formes de bande d'absorption infrarouge, montrant que ces modeles possedent les caracteristiques des formes observees dans les gaz comprimes, les liquides ou les solutions. (auteur)

  13. Application of the chemical properties of ruthenium to decontamination processes; L'application des proprietes chimiques du ruthenium a des procedes de decontamination

    Energy Technology Data Exchange (ETDEWEB)

    Fontaine, A.; Berger, D. [Commissariat a l' Energie Atomique, Centre de Production de Plutonium, Marcoule (France). Centre d' Etudes Nucleaires

    1965-07-01

    The chemical properties of ruthenium in the form of an aqueous solution of the nitrate and of organic tributylphosphate solution are reviewed. From this data, some known examples are given: they demonstrate the processes of separation or of elimination of ruthenium from radioactive waste. (authors) [French] Les proprietes chimiques du ruthenium en solutions aqueuses nitriques et en solutions organiques de tributylphosphate, sont passees en revue. A partir de ces donnees, quelques exemples connus sont cites: ils exposent des procedes de separation ou d'elimination du ruthenium de dechets radioactifs. (auteurs)

  14. Application of the chemical properties of ruthenium to decontamination processes; L'application des proprietes chimiques du ruthenium a des procedes de decontamination

    Energy Technology Data Exchange (ETDEWEB)

    Fontaine, A; Berger, D [Commissariat a l' Energie Atomique, Centre de Production de Plutonium, Marcoule (France). Centre d' Etudes Nucleaires

    1965-07-01

    The chemical properties of ruthenium in the form of an aqueous solution of the nitrate and of organic tributylphosphate solution are reviewed. From this data, some known examples are given: they demonstrate the processes of separation or of elimination of ruthenium from radioactive waste. (authors) [French] Les proprietes chimiques du ruthenium en solutions aqueuses nitriques et en solutions organiques de tributylphosphate, sont passees en revue. A partir de ces donnees, quelques exemples connus sont cites: ils exposent des procedes de separation ou d'elimination du ruthenium de dechets radioactifs. (auteurs)

  15. Applications of prospecting geochemical techniques to the search for and to the study of uranium deposits in metropolitan France; Applications des techniques geochimiques de prospection a la recherche et a l'etude des gites uraniferes en France metropolitaine

    Energy Technology Data Exchange (ETDEWEB)

    Grimbert, Arnold

    1957-07-01

    After having recalled facts which leaded the CEA to use new geochemical techniques for the prospecting of uranium deposits through sampling and analysis of soils and waters, the author describes the organisation and methods implemented for this prospecting activity: team composition for sampling and analysis, role of each engineer and technician in the prospecting stages (preliminary study, routine prospecting, result interpretation), sampling and analysis processes. He also reports campaigns of geochemical prospecting: study of the La Chapelle Largeau deposit (objectives, geological context, preliminary study, routine prospecting, study of geochemical anomalies), tactical research on Verneix indices (study of radioactivity anomaly discovered by radio-prospecting), strategical searches in a non prospected area in the South of Avallon. The author discusses the issues of efficiency and cost price of this geochemical prospecting technique in soils and in waters. Appendices present the equipment and operation modality for soil sampling, and for soil sample preparation, and principles, equipment and products for soil analysis and for water analysis [French] A la suite des resultats satisfaisants obtenus dans la recherche de methodes de dosage adaptees au cas de l'uranium, la Direction des Recherches Minieres du Commissariat a l'Energie atomique a decide, en decembre 1954, d'utiliser, conjointement avec les methodes classiques de prospection, les techniques geochimiques pour la recherche et l'etude des gites uraniferes. Ces applications pratiques ont ete confiees a une Section de Geochimie dont l'organisation, les moyens en personnel et en materiel, ainsi que les methodes de travail, font l'objet d'un expose detaille. Quelques exemples de prospection, en France metropolitaine, montrent la nature des problemes poses (etude d'un gisement connu, recherche tactique sur des indices, recherche strategique dans une region non prospectee), les methodes utilisees pour les

  16. Complex analysis with applications to flows and fields

    CERN Document Server

    Braga da Costa Campos, Luis Manuel

    2012-01-01

    Complex Analysis with Applications to Flows and Fields presents the theory of functions of a complex variable, from the complex plane to the calculus of residues to power series to conformal mapping. The book explores numerous physical and engineering applications concerning potential flows, the gravity field, electro- and magnetostatics, steady heat conduction, and other problems. It provides the mathematical results to sufficiently justify the solution of these problems, eliminating the need to consult external references.The book is conveniently divided into four parts. In each part, the ma

  17. Rôle des complexes ion/neutre dans les décompositions unimoléculaires d'ions [beta]-hydroxy acylium

    Science.gov (United States)

    Morizur, J.-P.; Chapon, E.

    1994-06-01

    Résumé Les réactions des ions [beta]-hydroxy acylium métastables CH3CH(OH)CH2CO+ (1) formés en phase gazeuse par perte de CH3O à partir du méthyl 3-hydroxy butyrate ionisé sont présentées et discutées. Le marquage aux isotopes stables a montré que la formation des ions CH2=CHCH2CO+ et CH3CO+ est précédée d'échanges d'atomes d'hydrogène et d'oxygène. L'utilisation des techniques de spectrométrie de masse a fourni des preuves expérimentales sur les isomérisations et dissociations de l'ion 1. On propose que la perte d'eau s'effectue à partir de CH2=CHCH2C(=O)OH+2, la formation de CH3CO+ implique un complexe ion/neutre [CH3CHO/CH3CO+]. L'interprétation des résultats est étayée par des données thermodynamiques. The reactions of metastable [beta]-hydroxy acylium ions CH3CH(OH)CH2CO+ (1) generated in the gas phase by loss of CH3O from ionized methyl 3-hydroxy butyrate are reported and discussed. Isotopic labelling shows that the dissociation, which produces the acylium ions CH2=CHCH2CO+ and CH3CO+, is preceded by hydrogen and oxygen atom exchange. Mass spectrometry techniques have provided experimental information of the isomerization and dissociation of ion 1. Loss of water is proposed to occur from CH2=CHCH2C(=O)OH+2; formation of CH3CO+ involves an ion/neutral complex [CH3CHO/CH3CO+]. Interpretation of data is supported by thermochemistry.

  18. Determination of the mean free path of the thermal neutrons transport by the measure of a complex diffusion length; Determination du libre parcours moyen de transport des neutrons thermiques par la mesure d'une longueur de diffusion complexe

    Energy Technology Data Exchange (ETDEWEB)

    Raievski, V; Horowitz, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1955-07-01

    The further method is the outcome of a technique used in the study of neutrons in scattering and slowing-down environment. In this technique, we replace the constant sources used in the classic experiences by modulated sources with a variable frequency. The object of this article is to describe the extension of the method for the mean free path for transport of thermal neutrons and also to indicate the possible applications for other sizes, as the slowing length, or the absolute value of the cross-section of the boron. (M.B.) [French] La methode qui va etre decrite est l'aboutissement d'une technique utilisee dans l'etude des milieux ou diffusent et se ralentissent des neutrons. Dans cette technique, on remplace les sources constantes utilisees dans les experiences classiques par des sources modulees, a frequence variable. L'objet de cet article est de decrire l'extension de la methode a la mesure du libre parcours moyen de transport des neutrons thermiques et egalement d'indiquer les applications possibles a la mesure d'autres grandeurs, telles que la longueur de ralentissement, ou la valeur absolue de la section de capture du bore. (M.B.)

  19. Some applications of magnetic resonance imaging in fluid mechanics: Complex flows and complex fluids

    NARCIS (Netherlands)

    Bonn, Daniel; Rodts, Stephane; Groenink, Maarten; Rafai, Salima; Shahidzadeh-Bonn, Noushine; Coussot, Philippe

    2008-01-01

    The review deals with applications of magnetic resonance imaging (MRI) techniques to study flow. We first briefly discuss the principles of flow measurement by MRI and give examples of some applications, such as multiphase flows, the MRI rheology of complex fluid flows, and blood flows in the human

  20. Complex systems and networks dynamics, controls and applications

    CERN Document Server

    Yu, Xinghuo; Chen, Guanrong; Yu, Wenwu

    2016-01-01

    This elementary book provides some state-of-the-art research results on broad disciplinary sciences on complex networks. It presents an in-depth study with detailed description of dynamics, controls and applications of complex networks. The contents of this book can be summarized as follows. First, the dynamics of complex networks, for example, the cluster dynamic analysis by using kernel spectral methods, community detection algorithms in bipartite networks, epidemiological modeling with demographics and epidemic spreading on multi-layer networks, are studied. Second, the controls of complex networks are investigated including topics like distributed finite-time cooperative control of multi-agent systems by applying homogenous-degree and Lyapunov methods, composite finite-time containment control for disturbed second-order multi-agent systems, fractional-order observer design of multi-agent systems, chaos control and anticontrol of complex systems via Parrondos game and many more. Third, the applications of ...

  1. Functions of a complex variable and some of their applications

    CERN Document Server

    Fuchs, B A; Sneddon, I N; Ulam, S

    1961-01-01

    Functions of a Complex Variable and Some of Their Applications, Volume 1, discusses the fundamental ideas of the theory of functions of a complex variable. The book is the result of a complete rewriting and revision of a translation of the second (1957) Russian edition. Numerous changes and additions have been made, both in the text and in the solutions of the Exercises. The book begins with a review of arithmetical operations with complex numbers. Separate chapters discuss the fundamentals of complex analysis; the concept of conformal transformations; the most important of the elementary fun

  2. Complex-valued neural networks advances and applications

    CERN Document Server

    Hirose, Akira

    2013-01-01

    Presents the latest advances in complex-valued neural networks by demonstrating the theory in a wide range of applications Complex-valued neural networks is a rapidly developing neural network framework that utilizes complex arithmetic, exhibiting specific characteristics in its learning, self-organizing, and processing dynamics. They are highly suitable for processing complex amplitude, composed of amplitude and phase, which is one of the core concepts in physical systems to deal with electromagnetic, light, sonic/ultrasonic waves as well as quantum waves, namely, electron and

  3. Application of microhardness measurements to the study of diffusion zones; Application des mesures de microdurete a l'etude des zones de diffusion

    Energy Technology Data Exchange (ETDEWEB)

    Levy, V; Bouchet, P; Siouffi, J; Adda, Y [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1959-07-01

    It is well known that the concentration fluctuations in diffusion zones can be determined by microhardness tests. It was therefore interesting to define the experimental conditions leading to the best accuracy. To this end, we have studied the influence of the kind of penetrator used, and of the applied load on the reproducibility of the curves plotting the variation of microhardness values against penetration. This work carried out for diffusion zones of various widths, has enabled us to determine in each case the best experimental procedure. (author) [French] On sait que les variations de concentration existant dans les zones de diffusion peuvent etre determinees au moyen de mesures de microdurete. Il etait donc interessant de definir les conditions experimentales conduisant a la meilleure precision. Dans ce but, nous avons etudie l'influence de la nature du penetrateur et celle de la charge appliquee sur la reproductibilite des courbes representant les variations de durete en fonction de la penetration. Ce travail, effectue pour des zones de diffusion de differentes largeurs, nous a permis de determiner dans chaque cas les conditions experimentales les plus favorables. (auteur)

  4. Continuous surveillance of transformers using artificial intelligence methods; Surveillance continue des transformateurs: application des methodes d'intelligence artificielle

    Energy Technology Data Exchange (ETDEWEB)

    Schenk, A.; Germond, A. [Ecole Polytechnique Federale de Lausanne, Lausanne (Switzerland); Boss, P.; Lorin, P. [ABB Secheron SA, Geneve (Switzerland)

    2000-07-01

    The article describes a new method for the continuous surveillance of power transformers based on the application of artificial intelligence (AI) techniques. An experimental pilot project on a specially equipped, strategically important power transformer is described. Traditional surveillance methods and the use of mathematical models for the prediction of faults are described. The article describes the monitoring equipment used in the pilot project and the AI principles such as self-organising maps that are applied. The results obtained from the pilot project and methods for their graphical representation are discussed.

  5. Implementation en VHDl/FPGA d'afficheur video numerique (AVN) pour des applications aerospatiales

    Science.gov (United States)

    Pelletier, Sebastien

    L'objectif de ce projet est de developper un controleur video en langage VHDL afin de remplacer la composante specialisee presentement utilisee chez CMC Electronique. Une recherche approfondie des tendances et de ce qui se fait actuellement dans le domaine des controleurs video est effectuee afin de definir les specifications du systeme. Les techniques d'entreposage et d'affichage des images sont expliquees afin de mener ce projet a terme. Le nouveau controleur est developpe sur une plateforme electronique possedant un FPGA, un port VGA et de la memoire pour emmagasiner les donnees. Il est programmable et prend peu d'espace dans un FPGA, ce qui lui permet de s'inserer dans n'importe quelle nouvelle technologie de masse a faible cout. Il s'adapte rapidement a toutes les resolutions d'affichage puisqu'il est modulaire et configurable. A court terme, ce projet permettra un controle ameliore des specifications et des normes de qualite liees aux contraintes de l'avionique.

  6. Les filtres plantés de roseaux en assainissement : de la compréhension des mécanismes vers l'optimisation des procédés et la diversification des domaines d'application.

    OpenAIRE

    Molle, P.

    2015-01-01

    / L'usage des végétaux aquatiques dans les filières de traitement des eaux provient de l'observation du rôle des zones humides naturelles dans la préservation de la qualité des milieux aquatiques. En France l'expérience a démarré en 1978. Depuis les premières réalisations jusqu'au début des années 2000 la filière a été évaluée principalement par des bilans 24 h à chaque étape de traitement. Si cette méthode considère les systèmes comme une boîte noire et ne donne pas accès à la quantification...

  7. Complex Hollow Nanostructures: Synthesis and Energy-Related Applications.

    Science.gov (United States)

    Yu, Le; Hu, Han; Wu, Hao Bin; Lou, Xiong Wen David

    2017-04-01

    Hollow nanostructures offer promising potential for advanced energy storage and conversion applications. In the past decade, considerable research efforts have been devoted to the design and synthesis of hollow nanostructures with high complexity by manipulating their geometric morphology, chemical composition, and building block and interior architecture to boost their electrochemical performance, fulfilling the increasing global demand for renewable and sustainable energy sources. In this Review, we present a comprehensive overview of the synthesis and energy-related applications of complex hollow nanostructures. After a brief classification, the design and synthesis of complex hollow nanostructures are described in detail, which include hierarchical hollow spheres, hierarchical tubular structures, hollow polyhedra, and multi-shelled hollow structures, as well as their hybrids with nanocarbon materials. Thereafter, we discuss their niche applications as electrode materials for lithium-ion batteries and hybrid supercapacitors, sulfur hosts for lithium-sulfur batteries, and electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions. The potential superiorities of complex hollow nanostructures for these applications are particularly highlighted. Finally, we conclude this Review with urgent challenges and further research directions of complex hollow nanostructures for energy-related applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Static and Dynamic Disorder in Bacterial Light-Harvesting Complex LH2: A 2DES Simulation Study.

    Science.gov (United States)

    Rancova, Olga; Abramavicius, Darius

    2014-07-10

    Two-dimensional coherent electronic spectroscopy (2DES) is a powerful technique in distinguishing homogeneous and inhomogeneous broadening contributions to the spectral line shapes of molecular transitions induced by environment fluctuations. Using an excitonic model of a double-ring LH2 aggregate, we perform simulations of its 2DES spectra and find that the model of a harmonic environment cannot provide a consistent set of parameters for two temperatures: 77 K and room temperature. This indicates the highly anharmonic nature of protein fluctuations for the pigments of the B850 ring. However, the fluctuations of B800 ring pigments can be assumed as harmonic in this temperature range.

  9. Hanford Facility Dangerous Waste Permit Application, 222-S Laboratory Complex

    International Nuclear Information System (INIS)

    WILLIAMS, J.F.

    2000-01-01

    The Hanford Facility Dangerous Waste Permit Application is considered to be a single application organized into a General Information Portion (document number DOE/RL-91-28) and a Unit-Specific Portion. The scope of the Unit-Specific Portion is limited to Part B permit application documentation submitted for individual, operating treatment, storage, and/or disposal units, such as the 222-S Laboratory Complex (this document, DOE/RL-91-27). Both the General Information and Unit-Specific portions of the Hanford Facility Dangerous Waste Permit Application address the content of the Part B permit application guidance prepared by the Washington State Department of Ecology (Ecology 1987 and 1996) and the U.S. Environmental Protection Agency (40 Code of Federal Regulations 270), with additional information needs defined by the Hazardous and Solid Waste Amendments and revisions of Washington Administrative Code 173-303. For ease of reference, the Washington State Department of Ecology alpha-numeric section identifiers from the permit application guidance documentation (Ecology 1996) follow, in brackets, the chapter headings and subheadings. Documentation contained in the General Information Portion is broader in nature and could be used by multiple treatment, storage, and/or disposal units (e.g., the glossary provided in the General Information Portion). Wherever appropriate, the 222-S Laboratory Complex permit application documentation makes cross-reference to the General Information Portion, rather than duplicating text. Information provided in this 222-S Laboratory Complex permit application documentation is current as of August 2000

  10. Brain Tumour Scintigraphy with {sup 99m}Tc-Pertechnetate, {sup 99m}Tc-Fe(II) Complex and {sup 131}I-Labelled Macroaggregated Albumin - Comparison of Results; La Scintigraphie des Tumeurs Cerebrales a l'Aide de Pertechnetate Marque au {sup 99m}Tc, de Complexe {sup 99m}Tc-Fe-II et de Macroagregats d'Albumine Marques au {sup 131}I. Comparaison des Resultats

    Energy Technology Data Exchange (ETDEWEB)

    Haas, J. P.; Dietz, H.; Schmidt, K. J.; Doerr, F.; Brod, K. H.; Wolf, R. [Institut de Radiologie Clinique et Clinique de Neurochirurgie, Universite de Mayence, Federal Republic of Germany (Germany)

    1969-05-15

    {sup 99m}Tc, in the form of pertechnetate, has now gained its place in brain scintigraphy. The present authors and many others have found its diagnostic value equal to that of substances labelled with mercury or iodine. Using {sup 99m}Tc-pertechnetate as the basis of their work, the authors attempted to extend isotopic diagnosis by two methods, namely: intra-arterial introduction of macroaggregated albumin; and intravenous injection of a new substance, the {sup 99m}Tc-Fe(II) complex. Following their publication in 1966 of the results obtained with the first method, the authors now present an account of their experiments carried out on over 100 patients with brain tumours. Compared with scintigraphy involving intravenous injection of {sup 99m}Tc-pertechnetate, this new method gives supplementary information which is often of considerable help in clinical neuroradiological diagnosis of these patients. The findings in a majority of cases were confirmed by operation or by autopsy. The method made it possible for the first time to use scintigraphy to visualize the arterial network of the brain. In view of the ease with which brain scintigraphy can be performed after intravenous injection, and also of our experience with the {sup 99m}Tc-Fe(II) complex in kidney scintigraphy and the evidence of a brief report in the United States literature, the authors decided to try out this substance in the detection of brain tumours. Their first results showed it to be incontestably superior to all others previously applied intravenously. It has the indubitable advantages of {sup 99m}Tc as regards the irradiation dose to the patient and gives an exceptionally precise delineation of the invasive cerebral processes due to a rapid fall in blood concentration. A combination of these two new scintigraphic methods would thus seem to open up new possibilities and greatly enhance the field of application of radioisotopes in the clinical study of brain diseases. The paper contains material

  11. Utilisation sans risque des eaux usées, des excréta et des eaux ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Les responsables de ce projet piloteront l'application et l'adaptation des principes directeurs relatifs à l'utilisation sans risque des eaux usées, des excreta et des eaux grises en agriculture et en aquaculture (Guidelines for the Safe Use of Wastewater, Excreta and Greywater in Agriculture and Aquaculture), que ...

  12. Corrosion in the presence of a complexing agent - application to the continuous determination of hydrofluoric acid in the atmosphere; Corrosion en presence de complexant. - Application a la determination en continu de l'acide fluorhydrique dans l'atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Chapron, J [Commissariat a l' Energie Atomique, Centre d' Etudes Nucleaires de Fontenay-aux-Roses, 92 (France)

    1966-10-01

    After a presentation of the thermodynamics and kinetics involved during corrosion in the presence of a complexing agent, the first part of this report deals with the electrochemical properties of an aluminium electrode in the presence of fluoride solutions. Various physical and chemical parameters have been studied together with their influence on the aforementioned properties. From this first part are deduced the medium and the various parameters which lead to the maximum efficiency for the detection of fluorides by amperometry. The second part is an application of the results of the above work, which has made it possible to develop a cell having an original design. Its performances are described. They show that the cell has a greater sensitivity and a shorter response time than existing equipment. (author) [French] Apres un rappel sur la thermodynamique et la cinetique de la corrosion en presence de complexant, la premiere partie du memoire est consacree a l'etude des proprietes electrochimiques de l'electrode d'aluminium, en presence de solutions de fluorure. Differents parametres physiques et chimiques ont ete etudies ainsi que leurs influences sur les dites proprietes. De cette premiere partie on en a deduit le milieu et les divers parametres a fixer de facon a obtenir un rendement optimum au vue de la detection des fluorures par amperometrie. La deuxieme partie, qui est l'application des renseignements tires du travail deja cite, a permis de mettre au point une cellule de conception nouvelle. Ses performances sont decrites. Elles indiquent une sensibilite plus grande, un temps de reponse plus court que les appareils existants. (auteur)

  13. La PCR quantitative en temps réel : application à la quantification des OGM

    Directory of Open Access Journals (Sweden)

    Alary Rémi

    2002-11-01

    Full Text Available Suite à l’obligation d’étiquetage, au seuil de 1 %, des aliments contenant des OGM autorisés, il est nécessaire de disposer de méthodes fiables de quantification. Pour répondre à cette obligation, la technique de PCR quantitative en temps réel semble actuellement la mieux adaptée. Son principe, ses avantages et sa mise en oeuvre pour la détermination de la teneur en OGM de farines de soja sont présentés. Les PCR simplex et duplex sont comparées.

  14. Application of transducers to the control of temperatures and of alternating and direct voltages (1962); Application des transducteurs a la regulation des temperatures et des tensions alternatives et continues (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Raoult, N [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1960-11-15

    The temperature regulator and the voltage regulators described have been studied with a view to conferring a high degree of safety to the apparatuses in which they are used. They make use almost exclusively of Transducers which are passive elements acting mainly in these apparatuses as amplifiers and which are entirely satisfactory, ensuring that the regulators studied keep their essential qualities i.e accuracy, reliability, stability and sensitivity. (author) [French] Le regulateur de temperature et les regulateurs de tension decrits ont ete etudies pour donner aux ensembles dans lesquels ils sont inseres une grande securite d'exploitation. Ils utilisent presque exclusivement comme constituants des TRANSDUCTEURS qui sont des elements passifs assurant principalement dans ces appareils une fonction d'amplification ou ils donnent entiere satisfaction en conservant aux regulateurs etudies leurs qualites essentielles qui sont: la precision, la fidelite, la stabilite et la sensibilite. (auteur)

  15. Application de principes cognitivistes et constructivistes à l'enseignement de l'écrit assisté par ordinateur : perceptions des étudiants

    Directory of Open Access Journals (Sweden)

    Catherine Caws

    2005-09-01

    Full Text Available Cet article traite des apports des théories cognitives et constructivistes à l'enseignement de l'écrit assisté par ordinateur, en milieu universitaire, chez des apprenants de français langue seconde. À partir des premiers résultats d'un projet pilote mené à l'université de Victoria, au Canada, l'auteure cherche à montrer comment, par le biais d'exercices collaboratifs en réseau Internet, l'application de certains principes-clés des recherches récentes en didactique du français langue seconde peuvent contribuer à un renouveau de l'engagement des étudiants, à une hausse notable de leur motivation et à une prise de conscience de leurs stratégies d'apprentissage. Une analyse des réactions des étudiants face à ce nouveau type d'apprentissage nous permet d'analyser, d'une part, les aspects de l'outil que les étudiants perçoivent comme étant utiles pour leur apprentissage et, d'autre part, les éléments qu'ils voudraient voir améliorer dans l'avenir. La prise de conscience même de ces stratégies nous montre à quel point l'apprenant s'engage activement dans la découverte de la L2, répondant ainsi inconsciemment à un des principes-clés de la psychologie cognitive.

  16. Complexity of Configurators Relative to Integrations and Field of Application

    DEFF Research Database (Denmark)

    Kristjansdottir, Katrin; Shafiee, Sara; Battistello, Loris

    . Moreover, configurators are commonly integrated to various IT systems within companies. The complexity of configurators is an important factor when it comes to performance, development and maintenance of the systems. A direct comparison of the complexity based on the different application...... integrations to other IT systems. The research method adopted in the paper is based on a survey followed with interviews where the unit of analysis is based on operating configurators within a company.......Configurators are applied widely to automate the specification processes at companies. The literature describes the industrial application of configurators supporting both sales and engineering processes, where configurators supporting the engineering processes are described more challenging...

  17. La Boîte à Outils Sur L'Application Des Connaissances

    International Development Research Centre (IDRC) Digital Library (Canada)

    219. 11. Le résumé de deux pages : Rédaction d'un précis politique. 221. 12. ...... Pour élaborer une stratégie d'AC, plusieurs approches et outils peuvent être utilisés. ...... Le recrutement d'un consultant exige des vérifications approfondies.

  18. Absolute measurement of {beta} activities and application to the determination of neutronic densities; Mesure absolue d'activites {beta} et application a la determination des densites neutronique

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, R [Commissariat a l' Energie Atomique, Lab. du Fort de Chatillon, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1951-01-15

    M. Berthelot, to my entrance to the ''Commissariat a l 'Energie Atomique'', proposed me to study the absolute measurement of neutron densities. Very quickly the problem of the absolute activity of {beta} sources became the central object of this work. In a first part, we will develop the methods of absolute determination for {beta} activities. The use of a 4{pi} counter permits to get the absolute activity of all beta radioactive source, susceptible to be put as thin leaf and of period superior than some minutes. The method is independent of the spectra of the measured radioelement. we will describe in the second part some applications which use neutron densities measurement, neutron sources intensities and ratio of cross sections of capture of thermal neutrons. (M.B.) [French] M. Berthelot, a mon entree au ''Commissariat a l 'Energie Atomique'', m'a propose d'etudier la mesure absolue des densites neutroniques. Tres rapidement le probleme de l'activite absolue des sources beta est devenu l'objet central de ce travail. Dans une premiere partie, on abordera les methodes de determination absolue des activites beta. L'utilisation d'un compteur 4{pi} permet d 'obtenir l'activite absolue de toute source radioactive beta, susceptible d'etre mise sous forme de feuille mince et de periode superieure a quelques minutes. La methode est independante du spectre du radioelement mesure. On decrira dans la seconde partie quelques applications a des mesures de densites neutroniques, d'intensites de sources de neutrons et de rapport de sections efficaces de capture de neutrons thermiques. (M.B.)

  19. Absolute measurement of {beta} activities and application to the determination of neutronic densities; Mesure absolue d'activites {beta} et application a la determination des densites neutronique

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, R. [Commissariat a l' Energie Atomique, Lab. du Fort de Chatillon, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1951-01-15

    M. Berthelot, to my entrance to the ''Commissariat a l 'Energie Atomique'', proposed me to study the absolute measurement of neutron densities. Very quickly the problem of the absolute activity of {beta} sources became the central object of this work. In a first part, we will develop the methods of absolute determination for {beta} activities. The use of a 4{pi} counter permits to get the absolute activity of all beta radioactive source, susceptible to be put as thin leaf and of period superior than some minutes. The method is independent of the spectra of the measured radioelement. we will describe in the second part some applications which use neutron densities measurement, neutron sources intensities and ratio of cross sections of capture of thermal neutrons. (M.B.) [French] M. Berthelot, a mon entree au ''Commissariat a l 'Energie Atomique'', m'a propose d'etudier la mesure absolue des densites neutroniques. Tres rapidement le probleme de l'activite absolue des sources beta est devenu l'objet central de ce travail. Dans une premiere partie, on abordera les methodes de determination absolue des activites beta. L'utilisation d'un compteur 4{pi} permet d 'obtenir l'activite absolue de toute source radioactive beta, susceptible d'etre mise sous forme de feuille mince et de periode superieure a quelques minutes. La methode est independante du spectre du radioelement mesure. On decrira dans la seconde partie quelques applications a des mesures de densites neutroniques, d'intensites de sources de neutrons et de rapport de sections efficaces de capture de neutrons thermiques. (M.B.)

  20. Dental Encounter System (DES)

    Data.gov (United States)

    Department of Veterans Affairs — Dental Encounter System (DES) is an automated health care application designed to capture critical data about the operations of VA Dental Services. Information on...

  1. Properties- and applications of quasicrystals and complex metallic alloys.

    Science.gov (United States)

    Dubois, Jean-Marie

    2012-10-21

    This article aims at an account of what is known about the potential for applications of quasicrystals and related compounds, the so-called family of Complex Metallic Alloys (CMAs‡). Attention is focused at aluminium-based CMAs, which comprise a large number of crystalline compounds and quasicrystals made of aluminium alloyed with transition metals (like Fe or Cu) or normal metals like Mg. Depending on composition, the structural complexity varies from a few atoms per unit cell up to thousands of atoms. Quasicrystals appear then as CMAs of ultimate complexity and exhibit a lattice that shows no periodicity anymore in the usual 3-dimensional space. Properties change dramatically with lattice complexity and turn the metal-type behaviour of simple Al-based crystals into a far more complex behaviour, with a fingerprint of semi-conductors that may be exploited in various applications, potential or realised. An account of the ones known to the author is given in the light of the relevant properties, namely light absorption, reduced adhesion and friction, heat insulation, reinforcement of composites for mechanical devices, and few more exotic ones. The role played by the search for applications of quasicrystals in the development of the field is briefly addressed in the concluding section.

  2. Fractures of the atlantoaxial complex in the elderly: assessment of radiological spectrum of fractures and factors influencing imaging diagnosis; Frakturen des Atlas und Axis bei aelteren Patienten: Untersuchung des Radiologischen Spektrums der Frakturen und bedeutsamer Faktoren fuer die Bildgebende Diagnostik

    Energy Technology Data Exchange (ETDEWEB)

    Lomoschitz, F.M. [Universitaetsklinik fuer Radiodiagnostik, AKH Wien, Wien (Germany); Dept. of Radiology, Harborview Medical Center, Univ. of Washington, Seattle, WA (United States); Blackmore, C.C.; Linnau, K.F.; Mann, F.A. [Dept. of Radiology, Harborview Medical Center, Univ. of Washington, Seattle, WA (United States); Stadler, A. [Universitaetsklinik fuer Radiodiagnostik, AKH Wien, Wien (Germany)

    2004-02-01

    Objective: to describe patterns of atlantoaxial fractures in a population of consecutive elderly patients, including assessment of type, distribution and associated clinical and radiological findings, and to analyze any influence of the causative trauma mechanism on the individual fracture pattern. Materials and methods: the distribution and type of 123 atlantoaxial fractures in 95 subjects older than 65 years (range: 65-102; mean age: 79 years) were retrospectively assessed. For each subject, trauma mechanism and clinical and neurological status were recorded at admission. Initial imaging studies of the cervical spine were reviewed. Preexistent degenerative changes were assessed and the atlantoaxial fractures classified. Data were evaluated for the frequency of different types of fractures of C1 and C2 and for accompanying fractures of cervical vertebrae or the occipital condyles, respectively. Results: the majority of patients with injuries of the atlantoaxial complex had fractures of C2 (90 of 95, 95%). A large proportion of these patients (67 of 90, 74%) had odontoid fractures. An isolated fracture of C1 was present in only 5 (5%) patients. Associated fractures of the occipital condyles or other cervical vertebrae were rare (10 of 95, 11%). The main trauma mechanism for atlantoaxial injuries was a fall (56 of 95, 59%). Elderly patients injured in motor vehicle accidents were more likely to have isolated fractures of C2 and Type III fractures of the odontoid (p < 0.02). Conclusion: in elderly patients, fractures of the atlantoaxial complex are mainly caused by falls and almost always involve C2. The trauma mechanism influences the fracture pattern (orig.) [German] Untersuchung von Frakturen des Atlas (C1) und Axis (C2) in einer konsekutiven Population aelterer Patienten ({>=} 65 Jahre) hinsichtlich Fraktur-Typus, -Haeufigkeit, und -Kombinationen, und Analyse von assoziierter Klinik sowie Einfluss von unfall-ursaechlichen Faktoren auf Frakturen des atlanto

  3. Complex Time-Delay Systems Theory and Applications

    CERN Document Server

    Atay, Fatihcan M

    2010-01-01

    Time delays in dynamical systems arise as an inevitable consequence of finite speeds of information transmission. Realistic models increasingly demand the inclusion of delays in order to properly understand, analyze, design, and control real-life systems. The goal of this book is to present the state-of-the-art in research on time-delay dynamics in the framework of complex systems and networks. While the mathematical theory of delay equations is quite mature, its application to the particular problems of complex systems and complexity is a newly emerging field, and the present volume aims to play a pioneering role in this perspective. The chapters in this volume are authored by renowned experts and cover both theory and applications in a wide range of fields, with examples extending from neuroscience and biology to laser physics and vehicle traffic. Furthermore, all chapters include sufficient introductory material and extensive bibliographies, making the book a self-contained reference for both students and ...

  4. Economic Decision Making: Application of the Theory of Complex Systems

    Science.gov (United States)

    Kitt, Robert

    In this chapter the complex systems are discussed in the context of economic and business policy and decision making. It will be showed and motivated that social systems are typically chaotic, non-linear and/or non-equilibrium and therefore complex systems. It is discussed that the rapid change in global consumer behaviour is underway, that further increases the complexity in business and management. For policy making under complexity, following principles are offered: openness and international competition, tolerance and variety of ideas, self-reliability and low dependence on external help. The chapter contains four applications that build on the theoretical motivation of complexity in social systems. The first application demonstrates that small economies have good prospects to gain from the global processes underway, if they can demonstrate production flexibility, reliable business ethics and good risk management. The second application elaborates on and discusses the opportunities and challenges in decision making under complexity from macro and micro economic perspective. In this environment, the challenges for corporate management are being also permanently changed: the balance between short term noise and long term chaos whose attractor includes customers, shareholders and employees must be found. The emergence of chaos in economic relationships is demonstrated by a simple system of differential equations that relate the stakeholders described above. The chapter concludes with two financial applications: about debt and risk management. The non-equilibrium economic establishment leads to additional problems by using excessive borrowing; unexpected downturns in economy can more easily kill companies. Finally, the demand for quantitative improvements in risk management is postulated. Development of the financial markets has triggered non-linearity to spike in prices of various production articles such as agricultural and other commodities that has added market

  5. Contribution to the study of influences in emission spectrography on solutions. Application to a general analysis method for stainless steels (1961); Contribution a l'etude des influences en spectographie d'emission sur solution. Application a une methode generale d'analyse des aciers inoxydables (1961)

    Energy Technology Data Exchange (ETDEWEB)

    Baudin, G [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1961-11-15

    In order to establish a general method of analysis of stainless steels, by means of spark spectroscopy on solutions, a systematic study has been made of the factors involved. The variations in acidity of the solutions, or in the ratio of concentrations of two acids at constant pH, lead to a displacement of the calibration curve. Simple relations have been established between the concentration of the extraneous elements, and the effects produced, for the constituents Fe, Ti, Ni, Cr, Mn; a general method using abacus is proposed for steels containing only these elements. The interactions in the case of the elements Mo, Nb, Ta, W, were more complex, so that the simultaneous separation was studied with the help of ion-exchange resins. A general method of analysis is proposed for stainless steels. (author) [French] En vue d'etablir une methode generale d'analyse des aciers inoxydables par spectrographie d'etincelles sur solution, on a effectue une etude systematique des influences. Les variations de l'acidite des solutions ou du rapport des concentrations de deux acides a pH constant, entrainent un deplacement des courbes d'etalonnage. On a etabli des relations simples entre la teneur des tiers elements et les effets produits pour les constituants Fe, Ti, Ni, Cr, Mn; une methode generale avec abaques est proposee pour les aciers contenant ces seuls elements. Les influences dans le cas des elements Mo, Nb, Ta, W etant plus complexes, on eut a etudier la separation simultanee a l'aide de resines echangeuses d'ions. On propose une methode generale d'analyse des aciers inoxydables. (auteur)

  6. Application des ondelettes à l'analyse de texture et à l'inspection de surface industrielle

    Science.gov (United States)

    Wolf, D.; Husson, R.

    1993-11-01

    This paper presents a method of texture analysis based on multiresolution wavelets analysis. We discuss the problem of theoretical and experimental choice of the wavelet. Statistical modelling of wavelet images is treated and it results in considering statistical distribution to be a generalized Gaussian law. An algorithm for texture classification is developed with respect of the variances of different wavelet images. An industrial application of this algorithm illustrates its quality and proves its aptitude for automation of certain tasks in industrial control. Nous présentons une méthode d'analyse de texture fondée sur l'analyse multirésolution par ondelettes. Nous discutons du problème du choix théorique et expérimental de l'ondelette. Le problème de la modélisation statistique des images d'ondelettes est traité et aboutit à considérer la distribution statistique comme une loi de Gauss généralisée. Un algorithme de classification de texture est construit à l'aide de la variance des différentes images d'ondelettes. Enfin, une application industrielle de cet algorithme illustre ses qualités et démontre son aptitude à l'automatisation de certaines tâches de contrôle industriel.

  7. Photonique des Morphos

    CERN Document Server

    Berthier, Serge

    2010-01-01

    La photonique est déjà présente dans notre vie quotidienne, et on attend maintenant que la manipulation des photons permette aussi le traitement logique des informations. Cependant, l’élément de base qui permet cette manipulation de la lumière, le cristal photonique, est d’une réalisation complexe et mal contrôlée. Dans la course à la maîtrise de la lumière, les structures photoniques naturelles ont beaucoup à nous apprendre. C’est ce que nous montre Serge Berthier qui étudie dans ce livre la structure des écailles des Morphos. Tenant compte de l’essor récent des approches biomimétiques, il présente de manière détaillée plus de dix-huit techniques expérimentales utilisées pour ses analyses, ainsi que les diverses approches théoriques développées pour la modélisation de structures multi-échelles complexes. Première étude quasi-exhaustive des structures fines d’un genre et des propriétés optiques ainsi que colorimétriques générées, ce livre fournit aux entomologiste...

  8. Application of the geophysical and geochemical methods to the research for uranium; Application a la recherche de l'uranium des methodes geophysiques et geochimiques

    Energy Technology Data Exchange (ETDEWEB)

    Gangloff, A M; Collin, C R; Grimbert, A; Sanselme, H [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    Since 1954, at the Commissariat a l'energie atomique, geophysics and geochemistry have been added to routine geological surveying and radiometric observations. Geophysical prospecting reveals the tectonic structures linked with French uranium deposits and gives an idea of favorable zones. Geochemistry adds to the geophysical indirect methods further details on the distribution of uranium traces in the soils. This method is direct and specific. Uranium assay in waters and alluvial deposits find its use in preliminary exploration. (author) [French] Depuis 1954, au CEA, a l'observation geologique directe et aux mesures radiometriques, sont venues s'ajouter des methodes relevant de la geophysique et de la geochimie. La prospection geophysique apporte des precisions sur les structures tectoniques auxquelles sont lies les gisements d'uranium fran is et sur la notion de zones favorables. Aux methodes indirectes de la geophysique, la prospection geochimique ajoute des precisions sur la repartition de l'uranium en traces dans les sols, cette methode est directe et specifique. Le dosage de l'uranium dans les eaux et les alluvions trouve son application dans la prospection de reconnaissance. (auteur)

  9. Partenariat Mexique-Canada en vue de l'application des ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Le Mexique met en oeuvre de plus en plus de réformes de son système de santé en se fondant directement sur des données probantes découlant de recherches. Toutefois, l'Instituto Nacional de Salud Pública (INSP) du Mexique a récemment modifié les visées de son programme de recherche sur les systèmes de santé ...

  10. Élaboration de protocoles facilitant l'application des lois en matière ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    En Inde, les crimes contre les femmes sont à la hausse. Selon des chiffres récents de l'office national de statistiques sur la criminalité (National Crime Records Bureau), un viol est perpétré toutes les 26 minutes; une agression sexuelle, toutes les 14 minutes; un acte de cruauté de la part du mari ou de la famille, toutes les 6 ...

  11. 10 Détermination des radionucléides dans le repas. Application aux ...

    African Journals Online (AJOL)

    ASIMANANA

    On réalise du tic au tac à l'Agriculture et un système expert des aides aux culinaires. Le Malgache a un art culinaire. Les étrangers, certes, connaissent seulement quelques plats. Malgaches à commencer par le Romazava et le Ravitoto. Or, on constatera que cette cuisine compte de nombreux plats. 2. Matériel et méthodes.

  12. Spectrophotometric study of the complexes of cerium and uranides with diethylenetetraaminepentaacetic acid (DTPA); Contribution a l'etude de la complexation du cerium et des uranides par l'acide diethylenetetraminepentaacetique (DTPA)

    Energy Technology Data Exchange (ETDEWEB)

    Hafez, M B [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-03-01

    A spectrophotometric determination was made of the complexes of cerium and uranides in their different degrees of oxidation with diethylenetriaminepentaacetic acid (DTPA). Two physico-chemical states, the ionic and hydrolysis ones, were considered. In the former case, we studied the influence of the pH on the formation of the complex, and whenever the complexes were stable, we determined the molecular ratio and calculated their stability constants. In the latter case, we studied the conditions of solubilization of the precipitate by formation of complexes soluble in water as a function of pH, age of the precipitate and time of precipitate-chelate contact. (authors) [French] Etude spectrophotometrique de la complexation du cerium et des uranides (uranium, neptunium, plutonium et americium) dans leurs differents etats d'oxydation par l'acide diethylenetriaminepentaacetique (DTPA). Deux etats physicochimiques ont retenu notre attention, l'etat ionique et l'etat precipite d'hydrolyse. Dans le premier cas, nous avons etudie l'influence du pH sur la formation du complexe, et dans tous les cas ou le complexe est stable, nous avons determine le rapport moleculaire (5) [element]/[chelatant] du complexe forme et nous avons calcule leurs constantes de stabilite. Dans le deuxieme cas, l'etat de precipite d'hydrolyse, nous avons etudie les conditions de solubilisation du precipite, par formation du complexe, en fonction du pH, de l'age du precipite et du temps de contact precipite - chelatant. (auteurs)

  13. Investigations on the structure of complex compounds by radioisotope exchange. The structure of cyanonitrosyl complexes; Recherches sur la structure des complexes par echange de radioisotopes - Structure des complexes cyanonitrosyliques; Issledovanie struktury slozhnykh soedinenij pri pomoshchi radioizotopnogo obmena - struktura slozhnykh tsianonitrozilovykh soedinenij; Estudio de la estructura de complejos por intercambio radioisotopico - Estructura de los complejos cianonitrosilicos

    Energy Technology Data Exchange (ETDEWEB)

    Jezowska-Trzeblatowska, B; Ziolkowski, J [University of Wroclaw (Poland)

    1962-03-15

    cyanonitrosylique est particulierement interessant en raison de sa structure et de son aptitude a former des groupes NO{sup -} ou NO{sup +}. Pour etudier la structure electronique du K{sub 3}Mn(CN){sub 6} et du K{sub 3}Mn(CN){sub 5}NO, la valence du metaf et le type de liaison, des recherches ont ete faites au moyen de la methode de l'echange de radioisotopes, ainsi que par d'autres methodes physicochimiques. On a constate qu'en introduisant le groupe nitrosyle dans l'ion d'hexacyanate, la stabilite du complexe est sensiblement renforcee, a l'etat solide comme a l'etat de solution. Cette observation s'est trouvee confirmee par des recherches sur la cinetique des echanges intervenant dans les systemes suivants: (I) K{sub 3}Mn(CN){sub 6} + KC{sup 14}N (II) K{sub 3}Mn(CN){sub 5}NO + KC{sup 14}N. Dans les deux cas, les reactions d'echange sont du premier ordre, mais leurs vitesses et leurs energies d'activation sout extremement differentes. L'anion Mn(CN){sub 5}NO{sub 3} etant sensible a la lumiere, la reaction d'echange est de caractere photochimique. Le rapportdes constantes de vitesse d'echange dans l'obscurite et sous eclairage normalise est de 1:100. La premiere reaction d'echange (I) se produit conformement au mecanisme d'association, tandis que la seconde (II) suit un mecanisme combine association/ dissociation. L'analyse de la distribution de l'activite, dans les groupes cyanure qui subissent un echange a l'etat d'equilibre isotopique, a revele l'existence d'au moins quatre groupes cyanure distincts. La grande stabilite du complexe nitrosylique, en comparaison de celle de l'hexacyanate, a ete prouvee par differentes methodes. Tout cela semble indiquer une structure NO{sup -} dans le complexe. Des recherches anterieures ont montre que le groupe nitrosyle est coordonne sous forme de NO{sup +}. Cela donne a penser que le complexe possede une structure de resonance, si l'on admet la resonance d'une paire d'electrons entre la couche T{sub 2g} de l'atome central et la couche p de l

  14. Chimie organométallique des éléments f : vers de nouveaux développements : complexes cyanures des éléments f

    OpenAIRE

    Hervé, Alexandre

    2014-01-01

    The cyanide ligand is one of the most widely used ligands in coordination chemistry of d-transition metals. The low number of cyanide complexes of lanthanides and actinides incited us to develop this field for reactivity and theoretical aspects, and also for their potentially interesting physicochemical properties. In this Ph.D., we investigated the reactivity of [An(Cot)₂] (An = Th, U ; Cot = C₈H₈²⁻) and [Mf(N*)₃]ʲ˖ (j = 0, 1; Mf = Ce, U ; N* = ⁻N(SiMe₃)₂) precursors toward the cyanide ion. ...

  15. Amélioration des méthodes de protection anticorrosion des structures métalliques : Sous-sujet : Application des systèmes dits de "maintenance" sur préparation de surface UHP

    OpenAIRE

    MAIRE, G; CENTRE D'ETUDES TECHNIQUES DE L'EQUIPEMENT NORMANDIE-CENTRE - CETE NORMANDIE-CENTRE; LABORATOIRE REGIONAL DES PONTS ET CHAUSSEES DE BLOIS - CETE NORMANDIE-CENTRE - LRPC BLOIS

    2005-01-01

    Le problème actuel de l'entretien de la protection anticorrosion des structures métalliques est l'augmentation du coût découlant des contraintes règlementaires récentes sur l'évacuation et le traitement des déchets. Lors d'un chantier d'entretien, le principal poste générateur de déchets est le décapage. Toutes les solutions techniques permettant de diminuer la quantité et/ou la nocivité des déchets de décapage sont donc intéressantes aussi bien du point de vue économique que de celui de la p...

  16. 6th international symposium on finite volumes for complex applications

    CERN Document Server

    Halama, Jan; Herbin, Raphaèle; Hubert, Florence; Fort, Jaroslav; FVCA 6; Finite Volumes for Complex Applications VI : Problems and perspectives

    2011-01-01

    Finite volume methods are used for various applications in fluid dynamics, magnetohydrodynamics, structural analysis or nuclear physics. A closer look reveals many interesting phenomena and mathematical or numerical difficulties, such as true error analysis and adaptivity, modelling of multi-phase phenomena or fitting problems, stiff terms in convection/diffusion equations and sources. To overcome existing problems and to find solution methods for future applications requires many efforts and always new developments. The goal of The International Symposium on Finite Volumes for Complex Applica

  17. 5th International Workshop on Complex Networks and their Applications

    CERN Document Server

    Gaito, Sabrina; Quattrociocchi, Walter; Sala, Alessandra

    2017-01-01

    This book highlights cutting-edge research in the field of network science, offering scientists, researchers and graduate students a unique opportunity to catch up on the latest advances in theory and a multitude of applications. It presents the peer-reviewed proceedings of the fifth International Workshop on Complex Networks & their Applications (COMPLEX NETWORKS 2016), which took place in Milan during the last week of November 2016. The carefully selected papers are divided into 11 sections reflecting the diversity and richness of research areas in the field. More specifically, the following topics are covered: Network models; Network measures; Community structure; Network dynamics; Diffusion, epidemics and spreading processes; Resilience and control; Network visualization; Social and political networks; Networks in finance and economics; Biological and ecological networks; and Network analysis.

  18. A complex autoregressive model and application to monthly temperature forecasts

    Directory of Open Access Journals (Sweden)

    X. Gu

    2005-11-01

    Full Text Available A complex autoregressive model was established based on the mathematic derivation of the least squares for the complex number domain which is referred to as the complex least squares. The model is different from the conventional way that the real number and the imaginary number are separately calculated. An application of this new model shows a better forecast than forecasts from other conventional statistical models, in predicting monthly temperature anomalies in July at 160 meteorological stations in mainland China. The conventional statistical models include an autoregressive model, where the real number and the imaginary number are separately disposed, an autoregressive model in the real number domain, and a persistence-forecast model.

  19. Extraction, fractionnement et concentration des huiles marines

    Directory of Open Access Journals (Sweden)

    Linder Michel

    2004-03-01

    Full Text Available Les huiles marines représentent des sources potentielles d’acides gras polyinsaturés (AGPI dont les implications au niveau de la nutrition et de la santé sont avérées. Ces molécules sont extraites à partir de poissons, algues ou co-produits de la filière halieutique par des procédés de cuisson-pression, en présence de solvants ou par des techniques enzymatiques beaucoup moins drastiques. Des fractions plus ou moins purifiées en AGPI sont obtenues par cristallisation à froid, en présence de solvants organiques, complexation avec de l’urée, distillation moléculaire ou extraction par fluide supercritique. L’utilisation de lipases stéréospécifiques dans des procédés d’hydrolyse et d’estérification conduit à une diversité de molécules d’acylglycérols riches en AGPI trouvant de nombreuses applications dans le domaine de l’agroalimentaire et de la santé.

  20. Définition et développement des applications pour smartphones en différentes plateformes (windows8, IOS)

    OpenAIRE

    Lisicic Lopátegui, Claudia

    2013-01-01

    Innovation d’une application d’entreprise, déjà existante et développement de cette application dans une nouvelle plateforme. Gestion et management d’un projet de développement et innovation d’une application pour Smartphones, à travers des études ergonomiques, d’utilisateurs et d’état de l’art.

  1. New Complexity Scalable MPEG Encoding Techniques for Mobile Applications

    Directory of Open Access Journals (Sweden)

    Stephan Mietens

    2004-03-01

    Full Text Available Complexity scalability offers the advantage of one-time design of video applications for a large product family, including mobile devices, without the need of redesigning the applications on the algorithmic level to meet the requirements of the different products. In this paper, we present complexity scalable MPEG encoding having core modules with modifications for scalability. The interdependencies of the scalable modules and the system performance are evaluated. Experimental results show scalability giving a smooth change in complexity and corresponding video quality. Scalability is basically achieved by varying the number of computed DCT coefficients and the number of evaluated motion vectors but other modules are designed such they scale with the previous parameters. In the experiments using the “Stefan” sequence, the elapsed execution time of the scalable encoder, reflecting the computational complexity, can be gradually reduced to roughly 50% of its original execution time. The video quality scales between 20 dB and 48 dB PSNR with unity quantizer setting, and between 21.5 dB and 38.5 dB PSNR for different sequences targeting 1500 kbps. The implemented encoder and the scalability techniques can be successfully applied in mobile systems based on MPEG video compression.

  2. Complex variables a physical approach with applications and Matlab

    CERN Document Server

    Krantz, Steven G

    2007-01-01

    PREFACEBASIC IDEAS Complex ArithmeticAlgebraic and Geometric PropertiesThe Exponential and ApplicationsHOLOMORPHIC AND HARMONIC FUNCTIONS Holomorphic FunctionsHolomorphic and Harmonic Functions Real and Complex Line Integrals Complex DifferentiabilityThe LogarithmTHE CAUCHY THEORY The Cauchy Integral TheoremVariants of the Cauchy Formula The Limitations of the Cauchy FormulaAPPLICATIONS OF THE CAUCHY THEORY The Derivatives of a Holomorphic FunctionThe Zeros of a Holomorphic FunctionISOLATED SINGULARITIES Behavior near an Isolated SingularityExpansion around Singular PointsExamples of Laurent ExpansionsThe Calculus of ResiduesApplications to the Calculation of IntegralsMeromorphic FunctionsTHE ARGUMENT PRINCIPLE Counting Zeros and PolesLocal Geometry of Functions Further Results on Zeros The Maximum PrincipleThe Schwarz LemmaTHE GEOMETRIC THEORY The Idea of a Conformal Mapping Mappings of the DiscLinear Fractional Transformations The Riemann Mapping Theorem Conformal Mappings of AnnuliA Compendium of Useful Co...

  3. Contribution to the study of physico-chemical properties of surfaces modified by laser treatment. Application to the enhancement of localized corrosion resistance of stainless steels; Contribution a l'etude des proprietes physico-chimiques des surfaces modifiees par traitement laser. Application a l'amelioration de la resistance a la corrosion localisee des aciers inoxydables

    Energy Technology Data Exchange (ETDEWEB)

    Pacquentin, W.

    2011-11-25

    Metallic materials are more and more used in severe conditions with particularly strong request for improving their behavior in aggressive environment and especially over long periods. The objective of this PhD work is to estimate the potentiality of a laser surface melting treatment on the improvement of the stainless steel 304L corrosion resistance, surface treatments by laser can be revisited on the basis of a recent change in the laser technology. In the frame of this work, a nano-pulsed laser fiber was chosen: it allows the treated surface to be melted for few microns in depth, followed by an ultra-fast solidification occurring with cooling rates up to 1011 K/s. The combination of these processes leads to the elimination of the surface defects, the formation (trapping) of metastable phases, the segregation of chemical elements and the growth of a new oxide layer which properties are governed by the laser parameters. To correlate these latter to the electrochemical reactivity of the surface, the influence of two laser parameters on the physico-chemical properties of the surface was studied: the laser power and the overlap of the laser impacts. To support this approach, the pitting corrosion resistance of the samples was determined by standard electrochemical tests. For specific laser parameters, the pitting potential of a 304L stainless steel was increased by more than 500 mV corresponding to an important enhancement in localized corrosion resistance in chloride environment. The interdependence of the different phenomena resulting from the laser treatment lead to a quite complex prioritization of their role on the sensibility of the 304L. However, it was demonstrated that the nature of the thermal oxide formed during the laser surface melting and the induced defects are first-order parameters for the initiation of pits. (author) [French] Les materiaux metalliques sont utilises dans des conditions de plus en plus severes et doivent presenter une parfaite

  4. Applications of the automatic meter reading techniques at the Brazilian gas domestic market; Application des techniques de releve automatique des compteurs sur le marche domestique Bresilien du gaz

    Energy Technology Data Exchange (ETDEWEB)

    Venancio, J.; Monteiro, F. [Comgas, Sao Paulo (Brazil); D' Oliveira, R.D. [ORBIS, Curitiba (Brazil)

    2000-07-01

    This article will describe applications of the automation and automatic meter reading techniques at the internal gas pipes installations design, considering residential and commercial buildings, and taking in account the tendency of rapid growth of the activities related to the natural gas industry in Brazil, as well as the recently development of new technologies that can be applied with affordable prices. It will be analysed the application of an automatic meter reading technology in a building of several floors in Sao Paulo, which gas installations design is being carried up, with be purpose of making a comparative cost-effectiveness study with the traditional constructive methods applied in Brazil. As a result, it will be purposed a new commercialization model for the gas in Brazil at the residential and commercial market. (authors)

  5. Influence des melanges complexes organiques sur le sort des dioxines et furanes: Implications dans le developpement de facteurs de caracterisation en analyse du cycle de vie

    Science.gov (United States)

    Taing, Eric

    The environmental fate of dioxins and furans, or polychlorodibenzo-p-dioxins and -furans (PCDD/Fs), leaching from wood poles treated with pentachlorophenol (PCP) oil is modified by the presence of oil. Interactions between co-contaminants, which also exist for other pollutants within the mixtures, were shown in the specific context of risk analysis, but have never been taken into account for the generic context of life cycle assessment (LCA). This decision-making tool relies on characterization factors (CF) to estimate the potential impacts of an emitted amount of a pollutant in different impact categories such as aquatic ecotoxicity and human toxicity. For these two impact categories, CFs are calculated from a cause-effect chain that models the environmental fate, exposure and effects of the pollutant (represented by a matrix of fate FF, exposure XF and effect EF, respectively), meaning that a modification of PCDD/Fs fate induces a change in PCDD/Fs CFs. The research question is therefore as follows: In life cycle impact assessment (LCIA), to what extent would the potential impacts of PCDD/Fs on aquatic ecotoxicity and human toxicity change when taking into account the influence of a complex organic mixture on PCDD/Fs fate?. Thus, the main objective is to develop CFs of PCDD/Fs when their fate is influenced by PCP oil and compare them with the CFs of PCDD/Fs without oil for the aquatic ecotoxicity and human toxicity impact categories. A mathematic approach is established to determine the new environmental distribution of PCDD/Fs in the presence of oil and a new FF' matrix is calculated from this new distribution to obtain new CFs' integrating oil influence. FF' and CF' are then compared to FF and CF of PCDD/Fs without the oil. Finally, potential (eco)toxic impacts of the PCDD/F Canadian emissions are calculated with the new CFs' of PCDD/Fs in presence of oil. By only focusing on the results for an emission into air, freshwater and natural soil on a continental

  6. L'application des normes IAS/IFRS par les entreprises françaises cotées : une décision sous influence institutionnelle

    OpenAIRE

    Barbu, Elena

    2006-01-01

    International audience; Cet article cherche à démontrer le rôle des facteurs institutionnels dans l'application des normes comptables internationales par les entreprises françaises cotées. Pour cela, nous avons analysé les réponses à un questionnaire fondé sur l'approche néo-institutionnelle, envoyé en 2005 aux directeurs financiers des entreprises du CAC 40 et Euronext 100. Les résultats obtenus ont permis de mettre en évidence que la décision d'appliquer les IAS/IFRS est influencée par l'en...

  7. Application of the pulsed neutron technique on the reactors ALIZE - AQUILON (1963); Application de la methode des neutrons pulses sur les piles ALIZE et AQUILON (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Jacquemart, R. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    Different methods of measuring the ratio effective delayed fraction / prompt neutron lifetime, {alpha}{sub c}, are described. According to the classic pulsed neutron technique the negative reactivity due to a localized absorber is given by {rho} / {beta}{sub eff} = {alpha} / {alpha}{sub c} -1 Experiments are reported which show that in this case {alpha}{sub c} can not be considered constant for large reactivities. The absorber element distorts the flux in the system, increasing the importance of the reflector. An application of the pulsed neutron method to the measurement of critical distributed boron concentrations of various absorber elements is described. Less time is required than for the usual super-critical techniques, and the experimental analysis is simplified. It is interesting to note that the results are not influenced by the spectral sensitivity of the control element. A modified pulsed neutron method has been tried out. This procedure was used to determine by measurements at sub-critical the critical water level of uranium-heavy water lattices with a high precision. (author) [French] Differents modes operatoires pour definir la valeur du rapport pourcentage effectif de neutrons retardes / temps de vie, {alpha}{sub c}, sont exposes. La methode classique par neutrons pulses definit l'anti-reactivite d'un element absorbant a partir de la relation: {rho} / {beta}{sub eff} {alpha} / {alpha}{sub c} -1 Les manipulations effectuees montrent qu'on ne peut considerer dans ce cas {alpha}{sub c} constant pour de tres grandes anti-reactivites. L'absorbant introduit dans la pile deforme le flux et augmente l'importance du reflecteur. Une application de la methode des neutrons pulses pour mesurer le titre critique en mg de B/l de divers absorbants est signalee. Les operations sont effectuees en regime sous-critique avec un certain gain de temps et une grande facilite de depouillement. Il est interessant de noter que les resultats ne sont pas

  8. Application of the pulsed neutron technique on the reactors ALIZE - AQUILON (1963); Application de la methode des neutrons pulses sur les piles ALIZE et AQUILON (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Jacquemart, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    Different methods of measuring the ratio effective delayed fraction / prompt neutron lifetime, {alpha}{sub c}, are described. According to the classic pulsed neutron technique the negative reactivity due to a localized absorber is given by {rho} / {beta}{sub eff} = {alpha} / {alpha}{sub c} -1 Experiments are reported which show that in this case {alpha}{sub c} can not be considered constant for large reactivities. The absorber element distorts the flux in the system, increasing the importance of the reflector. An application of the pulsed neutron method to the measurement of critical distributed boron concentrations of various absorber elements is described. Less time is required than for the usual super-critical techniques, and the experimental analysis is simplified. It is interesting to note that the results are not influenced by the spectral sensitivity of the control element. A modified pulsed neutron method has been tried out. This procedure was used to determine by measurements at sub-critical the critical water level of uranium-heavy water lattices with a high precision. (author) [French] Differents modes operatoires pour definir la valeur du rapport pourcentage effectif de neutrons retardes / temps de vie, {alpha}{sub c}, sont exposes. La methode classique par neutrons pulses definit l'anti-reactivite d'un element absorbant a partir de la relation: {rho} / {beta}{sub eff} {alpha} / {alpha}{sub c} -1 Les manipulations effectuees montrent qu'on ne peut considerer dans ce cas {alpha}{sub c} constant pour de tres grandes anti-reactivites. L'absorbant introduit dans la pile deforme le flux et augmente l'importance du reflecteur. Une application de la methode des neutrons pulses pour mesurer le titre critique en mg de B/l de divers absorbants est signalee. Les operations sont effectuees en regime sous-critique avec un certain gain de temps et une grande facilite de depouillement. Il est interessant de noter que les resultats ne sont pas affectes par la

  9. L’Application des Codes de Costas et des Codes a Congruences Quadratiques a la Compression d’Impulsion Numerique (The Application of Cost, Codes and Quadratic Congruence Codes to the Compression of Numeric Impulsion)

    Science.gov (United States)

    1991-12-01

    de produire des diagrammes d’ambigult& en forme de punaise avec de faibles lobes...particularit& de produire des diagrammes d’ambiguiLt6 en forme de punaise tout en ayant de faibles lobes secondaires. Ce rapport traite des diff6rentes m6thodes...les codes de Costas, les r~sultats obtenus mantrent que les codes de Golomb of frent de mains bonnes possibi- lit ~s que les codes de Welch pour

  10. Passer de la connaissance à l'action pour résoudre des problèmes complexes : aperçu de l'examen de neuf cas internationaux

    Directory of Open Access Journals (Sweden)

    B. L. Riley

    2015-01-01

    Full Text Available Introduction: La résolution de problèmes complexes du type de la prévention des maladies chroniques présente des défis particuliers pour la création et le transfert de connaissances, soit le passage de la connaissance à l'action (PCA. Les approches axées sur le PCA respectant les principes de la pensée systémique sont jugées prometteuses,mais les stratégies pour les mettre en place ne sont pas bien comprises. Dans cet article, nous présentons les résultats d'une analyse de plusieurs approches systémiques axées sur le PCA dans le but de déterminer comment optimiser leur mise en œuvre et leur efficacité. Méthodologie: Un groupe consultatif de cinq personnes a choisi neuf initiatives représentant une diversité d'enjeux et de formes organisationnelles. Pour chaque cas, l'information a été recueillie à partir de documents et par l'entremise d'entrevues téléphoniques avec des personnes-ressources de chaque organisation. Aprés la vérification des descriptions de cas, une analyse inductive a été effectuée à la fois pour chaque cas et entre les cas. Résultats: Ces cas ont révélé cinq lignes directrices permettant de passer de la conception de systémes de PCA à leur mise en œuvre : établir et entretenir des relations, coproduire et organiser les connaissances, créer des boucles de rétroaction, les encadrer comme des interventions systémiques plutôt que comme des projets et envisager des variations dans le temps et selon les lieux. Conclusion: Les résultats de cette analyse contextuelle constituent un départ modeste pour transformer en résultats concrets les concepts systémiques de PCA. L'utilisation des stratégies mises au jour pourrait améliorer le PCA pour la résolution de problèmes complexes en matière de santé publique. Les stratégies elles-mêmes pourront bénéficier de l'évolution d'une science visant à comprendre l'adaptation et l'apprentissage constant des politiques et des interventions

  11. Improving Weak Lensing Mass Map Reconstructions using Gaussian and Sparsity Priors: Application to DES SV

    Science.gov (United States)

    Jeffrey, N.; Abdalla, F. B.; Lahav, O.; Lanusse, F.; Starck, J.-L.; Leonard, A.; Kirk, D.; Chang, C.; Baxter, E.; Kacprzak, T.; Seitz, S.; Vikram, V.; Whiteway, L.; Abbott, T. M. C.; Allam, S.; Avila, S.; Bertin, E.; Brooks, D.; Rosell, A. Carnero; Kind, M. Carrasco; Carretero, J.; Castander, F. J.; Crocce, M.; Cunha, C. E.; D'Andrea, C. B.; da Costa, L. N.; Davis, C.; De Vicente, J.; Desai, S.; Doel, P.; Eifler, T. F.; Evrard, A. E.; Flaugher, B.; Fosalba, P.; Frieman, J.; García-Bellido, J.; Gerdes, D. W.; Gruen, D.; Gruendl, R. A.; Gschwend, J.; Gutierrez, G.; Hartley, W. G.; Honscheid, K.; Hoyle, B.; James, D. J.; Jarvis, M.; Kuehn, K.; Lima, M.; Lin, H.; March, M.; Melchior, P.; Menanteau, F.; Miquel, R.; Plazas, A. A.; Reil, K.; Roodman, A.; Sanchez, E.; Scarpine, V.; Schubnell, M.; Sevilla-Noarbe, I.; Smith, M.; Soares-Santos, M.; Sobreira, F.; Suchyta, E.; Swanson, M. E. C.; Tarle, G.; Thomas, D.; Walker, A. R.

    2018-05-01

    Mapping the underlying density field, including non-visible dark matter, using weak gravitational lensing measurements is now a standard tool in cosmology. Due to its importance to the science results of current and upcoming surveys, the quality of the convergence reconstruction methods should be well understood. We compare three methods: Kaiser-Squires (KS), Wiener filter, and GLIMPSE. KS is a direct inversion, not accounting for survey masks or noise. The Wiener filter is well-motivated for Gaussian density fields in a Bayesian framework. GLIMPSE uses sparsity, aiming to reconstruct non-linearities in the density field. We compare these methods with several tests using public Dark Energy Survey (DES) Science Verification (SV) data and realistic DES simulations. The Wiener filter and GLIMPSE offer substantial improvements over smoothed KS with a range of metrics. Both the Wiener filter and GLIMPSE convergence reconstructions show a 12% improvement in Pearson correlation with the underlying truth from simulations. To compare the mapping methods' abilities to find mass peaks, we measure the difference between peak counts from simulated ΛCDM shear catalogues and catalogues with no mass fluctuations (a standard data vector when inferring cosmology from peak statistics); the maximum signal-to-noise of these peak statistics is increased by a factor of 3.5 for the Wiener filter and 9 for GLIMPSE. With simulations we measure the reconstruction of the harmonic phases; the phase residuals' concentration is improved 17% by GLIMPSE and 18% by the Wiener filter. The correlation between reconstructions from data and foreground redMaPPer clusters is increased 18% by the Wiener filter and 32% by GLIMPSE.

  12. Improving Weak Lensing Mass Map Reconstructions using Gaussian and Sparsity Priors: Application to DES SV

    Energy Technology Data Exchange (ETDEWEB)

    Jeffrey, N.; et al.

    2018-01-26

    Mapping the underlying density field, including non-visible dark matter, using weak gravitational lensing measurements is now a standard tool in cosmology. Due to its importance to the science results of current and upcoming surveys, the quality of the convergence reconstruction methods should be well understood. We compare three different mass map reconstruction methods: Kaiser-Squires (KS), Wiener filter, and GLIMPSE. KS is a direct inversion method, taking no account of survey masks or noise. The Wiener filter is well motivated for Gaussian density fields in a Bayesian framework. The GLIMPSE method uses sparsity, with the aim of reconstructing non-linearities in the density field. We compare these methods with a series of tests on the public Dark Energy Survey (DES) Science Verification (SV) data and on realistic DES simulations. The Wiener filter and GLIMPSE methods offer substantial improvement on the standard smoothed KS with a range of metrics. For both the Wiener filter and GLIMPSE convergence reconstructions we present a 12% improvement in Pearson correlation with the underlying truth from simulations. To compare the mapping methods' abilities to find mass peaks, we measure the difference between peak counts from simulated {\\Lambda}CDM shear catalogues and catalogues with no mass fluctuations. This is a standard data vector when inferring cosmology from peak statistics. The maximum signal-to-noise value of these peak statistic data vectors was increased by a factor of 3.5 for the Wiener filter and by a factor of 9 using GLIMPSE. With simulations we measure the reconstruction of the harmonic phases, showing that the concentration of the phase residuals is improved 17% by GLIMPSE and 18% by the Wiener filter. We show that the correlation between the reconstructions from data and the foreground redMaPPer clusters is increased 18% by the Wiener filter and 32% by GLIMPSE. [Abridged

  13. The structure of complex networks theory and applications

    CERN Document Server

    Estrada, Ernesto

    2012-01-01

    This book deals with the analysis of the structure of complex networks by combining results from graph theory, physics, and pattern recognition. The book is divided into two parts. 11 chapters are dedicated to the development of theoretical tools for the structural analysis of networks, and 7 chapters are illustrating, in a critical way, applications of these tools to real-world scenarios. The first chapters provide detailed coverage of adjacency and metric and topologicalproperties of networks, followed by chapters devoted to the analysis of individual fragments and fragment-based global inva

  14. Les métamatériaux, des micro-ondes à l'optique : théorie et applications

    Science.gov (United States)

    Kante, B.

    2010-04-01

    Cet article constitue une contribution originale et importante à la compréhension à la fois théorique et expérimentale des métamatériaux en micro-ondes et en infrarouge. Nous avons réalisé et caractérisé sur silicium des nano-structures metallo-diélectriques, briques de base des métamatériaux infrarouge et optique. Des caractérisations optiques exhaustives ont été réalisées pour la première fois sur ces structures en amplitude et en phase par interférométrie. Des topologies plus simples de métamatériaux d’un point de vue technologique et des performances optiques ont été introduites, et leur potentiel démontré dans la réalisation de fonctions aussi complexes que la réfraction négative, le couplage de mode plasmoniques, les nano senseurs pour la biologie et l’invisibilité électromagnétique en infrarouge. Les transformations d’espace, et le nouveau paradigme qu’elles offrent à l’optique, rendant possible une ingénierie de l’espace pour les photons ainsi que leur implémentation par métamatériaux ont été présentés par la première démonstration expérimentale d’une cape d’invisibilité non magnétique.

  15. Measurement and Statistics of Application Business in Complex Internet

    Science.gov (United States)

    Wang, Lei; Li, Yang; Li, Yipeng; Wu, Shuhang; Song, Shiji; Ren, Yong

    Owing to independent topologies and autonomic routing mechanism, the logical networks formed by Internet application business behavior cause the significant influence on the physical networks. In this paper, the backbone traffic of TUNET (Tsinghua University Networks) is measured, further more, the two most important application business: HTTP and P2P are analyzed at IP-packet level. It is shown that uplink HTTP and P2P packets behavior presents spatio-temporal power-law characteristics with exponents 1.25 and 1.53 respectively. Downlink HTTP packets behavior also presents power-law characteristics, but has more little exponents γ = 0.82 which differs from traditional complex networks research result. Moreover, downlink P2P packets distribution presents an approximate power-law which means that flow equilibrium profits little from distributed peer-to peer mechanism actually.

  16. Self-consistent random phase approximation - application to systems of strongly correlated fermions; Approximation des phases aleatoires self-consistante - applications a des systemes de fermions fortement correles

    Energy Technology Data Exchange (ETDEWEB)

    Jemai, M

    2004-07-01

    In the present thesis we have applied the self consistent random phase approximation (SCRPA) to the Hubbard model with a small number of sites (a chain of 2, 4, 6,... sites). Earlier SCRPA had produced very good results in other models like the pairing model of Richardson. It was therefore interesting to see what kind of results the method is able to produce in the case of a more complex model like the Hubbard model. To our great satisfaction the case of two sites with two electrons (half-filling) is solved exactly by the SCRPA. This may seem a little trivial but the fact is that other respectable approximations like 'GW' or the approach with the Gutzwiller wave function yield results still far from exact. With this promising starting point, the case of 6 sites at half filling was considered next. For that case, evidently, SCRPA does not any longer give exact results. However, they are still excellent for a wide range of values of the coupling constant U, covering for instance the phase transition region towards a state with non zero magnetisation. We consider this as a good success of the theory. Non the less the case of 4 sites (a plaquette), as indeed all cases with 4n sites at half filling, turned out to have a problem because of degeneracies at the Hartree Fock level. A generalisation of the present method, including in addition to the pairs, quadruples of Fermions operators (called second RPA) is proposed to also include exactly the plaquette case in our approach. This is therefore a very interesting perspective of the present work. (author)

  17. Complexation of biological ligands with lanthanides(III) for MRI: Structure, thermodynamic and methods; Complexation des cations lanthanides trivalents par des ligands d'origine biologique pour l'IRM: Structure, thermodynamique et methodes

    Energy Technology Data Exchange (ETDEWEB)

    Bonnet, C

    2006-07-15

    New cyclic ligands derived from sugars and amino-acids form a scaffold carrying a coordination sphere of oxygen atoms suitable to complex Ln(III) ions. In spite of their rather low molecular weights, the complexes display surprisingly high relaxivity values, especially at high field. The ACX and BCX ligands, which are acidic derivatives of modified and cyclo-dextrins, form mono and bimetallic complexes with Ln(III). The LnACX and LnBCX complexes show affinities towards Ln(III) similar to those of tri-acidic ligands. In the bimetallic Lu2ACX complex, the cations are deeply embedded in the cavity of the ligand, as shown by the X-ray structure. In aqueous solution, the number of water molecules coordinated to the cation in the LnACX complex depends on the nature and concentration of the alkali ions of the supporting electrolyte, as shown by luminescence and relaxometric measurements. There is only one water molecule coordinated in the LnBCX complex, which enables us to highlight an important second sphere contribution to relaxivity. The NMR study of the RAFT peptidic ligand shows the complexation of Ln(III), with an affinity similar to those of natural ligands derived from calmodulin. The relaxometric study also shows an important second sphere contribution to relaxivity. To better understand the intricate molecular factors affecting relaxivity, we developed new relaxometric methods based on probe solutes. These methods allow us to determine the charge of the complex, weak affinity constants, trans-metallation constants, and the electronic relaxation rate. (author)

  18. Complexation of biological ligands with lanthanides(III) for MRI: Structure, thermodynamic and methods; Complexation des cations lanthanides trivalents par des ligands d'origine biologique pour l'IRM: Structure, thermodynamique et methodes

    Energy Technology Data Exchange (ETDEWEB)

    Bonnet, C

    2006-07-15

    New cyclic ligands derived from sugars and amino-acids form a scaffold carrying a coordination sphere of oxygen atoms suitable to complex Ln(III) ions. In spite of their rather low molecular weights, the complexes display surprisingly high relaxivity values, especially at high field. The ACX and BCX ligands, which are acidic derivatives of modified and cyclo-dextrins, form mono and bimetallic complexes with Ln(III). The LnACX and LnBCX complexes show affinities towards Ln(III) similar to those of tri-acidic ligands. In the bimetallic Lu2ACX complex, the cations are deeply embedded in the cavity of the ligand, as shown by the X-ray structure. In aqueous solution, the number of water molecules coordinated to the cation in the LnACX complex depends on the nature and concentration of the alkali ions of the supporting electrolyte, as shown by luminescence and relaxometric measurements. There is only one water molecule coordinated in the LnBCX complex, which enables us to highlight an important second sphere contribution to relaxivity. The NMR study of the RAFT peptidic ligand shows the complexation of Ln(III), with an affinity similar to those of natural ligands derived from calmodulin. The relaxometric study also shows an important second sphere contribution to relaxivity. To better understand the intricate molecular factors affecting relaxivity, we developed new relaxometric methods based on probe solutes. These methods allow us to determine the charge of the complex, weak affinity constants, trans-metallation constants, and the electronic relaxation rate. (author)

  19. Ionizing radiation sources: very diversified means, multiple applications and a changing regulatory environment. Conference proceedings; Les sources de rayonnements ionisants: des moyens tres diversifies, des applications multiples et une reglementation en evolution. Recueil des presentations

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-11-15

    This document brings together the available presentations given at the conference organised by the French society of radiation protection about ionizing radiation source means, applications and regulatory environment. Twenty eight presentations (slides) are compiled in this document and deal with: 1 - Overview of sources - some quantitative data from the national inventory of ionizing radiation sources (Yann Billarand, IRSN); 2 - Overview of sources (Jerome Fradin, ASN); 3 - Regulatory framework (Sylvie Rodde, ASN); 4 - Alternatives to Iridium radiography - the case of pressure devices at the manufacturing stage (Henri Walaszek, Cetim; Bruno Kowalski, Welding Institute); 5 - Dosimetric stakes of medical scanner examinations (Jean-Louis Greffe, Charleroi hospital of Medical University); 6 - The removal of ionic smoke detectors (Bruno Charpentier, ASN); 7 - Joint-activity and reciprocal liabilities - Organisation of labour risk prevention in case of companies joint-activity (Paulo Pinto, DGT); 8 - Consideration of gamma-graphic testing in the organization of a unit outage activities (Jean-Gabriel Leonard, EDF); 9 - Radiological risk control at a closed and independent work field (Stephane Sartelet, Areva); 10 - Incidents and accidents status and typology (Pascale Scanff, IRSN); 11 - Regional overview of radiation protection significant events (Philippe Menechal, ASN); 12 - Incident leading to a tritium contamination in and urban area - consequences and experience feedback (Laurence Fusil, CEA); 13 - Experience feedback - loss of sealing of a calibration source (Philippe Mougnard, Areva); 14 - Blocking incident of a {sup 60}Co source (Bruno Delille, Salvarem); 15 - Triggering of gantry's alarm: status of findings (Philippe Prat, Syctom); 16 - Non-medical electric devices: regulatory changes (Sophie Dagois, IRSN; Jerome Fradin, ASN); 17 - Evaluation of the dose equivalent rate in pulsed fields: method proposed by the IRSN and implementation test (Laurent Donadille

  20. Collaborative crew performance in complex operational systems: L'Efficacité du travail en équipage dans des systèmes opérationnel complexes

    National Research Council Canada - National Science Library

    1999-01-01

    .... As we progress towards the next millennium, complex operations will increasingly require consideration and integration of the collaborative element wherein crew performance becomes a critical factor for success...

  1. Injectabilite des coulis de ciment dans des milieux fissures

    Science.gov (United States)

    Mnif, Thameur

    Le travail presente ici est un bilan du travaux de recherche effectues sur l'injectabilite des coulis de ciment dans lu milieux fissures. Un certain nombre de coulis a base de ciment Portland et microfin ont ete selectionnes afin de caracteriser leur capacite a penetrer des milieux fissures. Une partie des essais a ete menee en laboratoire. L'etude rheologique des differents melanges a permis de tester l'influence de l'ajout de superplastifiant et/ou de fumee de silice sur la distribution granulometrique des coulis et par consequent sur leur capacite a injecter des colonnes de sable simulant un milieu fissure donne. La classe granulometrique d'un coulis, sa stabilite et sa fluidite sont apparus comme les trois facteurs principaux pour la reussite d'une injection. Un facteur de finesse a ete defini au cours de cette etude: base sur la classe granulometrique du ciment et sa stabilite, il peut entrer dans la formulation theorique du debit d'injection avant application sur chantier. La deuxieme et derniere partie de l'etude presente les resultats de deux projets de recherche sur l'injection realises sur chantier. L'injection de dalles de beton fissurees a permis le suivi de l'evolution des pressions avec la distance au point d'injection. L'injection de murs de maconnerie a caractere historique a montre l'importance de la definition de criteres de performance des coulis a utiliser pour traiter un milieu donne et pour un objectif donne. Plusieurs melanges peuvent ainsi etre predefinis et mis a disposition sur le chantier. La complementarite des ciments traditionnels et des ciments microfins devient alors un atout important. Le choix d'utilisation de ces melanges est fonction du terrain rencontre. En conclusion, cette recherche etablit une methodologie pour la selection des coulis a base de ciment et des pressions d'injection en fonction de l'ouverture des fissures ou joints de construction.

  2. La recherche en action : des solutions locales, des effets durables ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    15 déc. 2010 ... Le Centre de recherches pour le développement international (CRDI) appuie la production et l'application de connaissances qui améliorent de façon notable la situation des habitants des pays en développement.

  3. Biological Dosimetry Methods Employed at the Boris Kidric Institute of Nuclear Sciences; Application de Quelques Methodes Particulieres de Dosimetrie Biologique a l'Institut des Sciences Nucleaires Boris Kidric

    Energy Technology Data Exchange (ETDEWEB)

    Aleksic, B.; Veljkovic, D.; Djordjevic, O.; Djukic, Z. [Institut des Sciences Nucleaires Boris Kidric, Belgrade, Yugoslavia (Serbia)

    1971-06-15

    In addition to the more usual methods, the following methods are used at the Boris Kidric Institute of Nuclear Sciences in the medical supervision of occupationally exposed staff: analysis of bi nucleated lymphocytes and chromosome aberrations; physical examination (for example, determination of the pain sensitivity threshold, adaptation to pain, discrimination of sensitivity); capillaroscopy. These methods are described briefly and their practical application discussed. (author) [French] Outre les methodes habituelles, on a utilise a l'Institut Boris Kidric, pour le controle medical des travailleurs professionnellement exposes, des methodes d'analyse des lymphocytes binuclees et des aberrations chromosomiques, ainsi que des methodes d'examen physique telles que la determination du seuil de sensibilite douloureuse, de l'adaptation a la douleur et de la discrimination de la sensibilite, et la capillaroscopie. Ces methodes sont brievement decrites et leurs applications pratiques discutees. (author)

  4. High temperature elastic constant measurements: application to plutonium; Mesure des constantes elastiques a haute temperature application au plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Bouchet, J M [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-03-01

    We present an apparatus with which we have measured the Young's modulus and the Poisson's ratio of several compounds from the resonance frequency of cylinders in the temperature range 0 deg. C-700 deg. C. We especially studied the elastic constants of plutonium and measured for the first time to our knowledge the Young's modulus of Pu{sub {delta}} and Pu{sub {epsilon}}. E{sub {delta}} 360 deg. C = 1.6 10{sup 11} dy/cm{sup 2}; E{sub {epsilon}} 490 deg. C = 1.1 10{sup 11} dy/cm{sup 2}, {sigma}{sub {epsilon}} = 0.25 {+-} 0.03 Using our results, we have calculated the compressibility, the Debye temperature, the Grueneisen constant and the electronic specific heat of Pu{sub {epsilon}}. (author) [French] Nous decrivons un appareil qui permet de mesurer les constantes elastiques (module de Young et module de Poisson) jusqu'a 700 deg. C a partir des frequences de resonance de barreaux cylindriques. Nous avons plus specialement etudie le plutonium et determine pour la premiere fois a notre connaissance le module de Young des phases {delta} et {epsilon}: E{sub {delta}} 360 deg. C = 1.6 10{sup 11} dy/cm{sup 2}; E{sub {epsilon}} 490 deg. C = 1.1 10{sup 11} dy/cm{sup 2}, {sigma}{sub {epsilon}} = 0.25 {+-} 0.03 Nos mesures nous ont permis de calculer la compressibilite, la temperature de Debye, la constante de Gruneisen et la chaleur specifique electronique de Pu{sub {epsilon}}. (auteur)

  5. Application des fluides supercritiques à la production d'hydrocarbures. Exploitation des gisements par récupération assistée et applications diverses : pétrole, sables, schistes, charbons Application of Supercritical Fluids to Hydrocarbon Production. Enhanced Oi Recovery and Miscellaneous Applications: Oil, Tar Sands, Shales, Coals

    Directory of Open Access Journals (Sweden)

    Behar E.

    2006-11-01

    Full Text Available Le taux moyen de récupération par drainage naturel des gisements pétroliers atteint à peine 30 %. La récupération assistée désigne l'ensemble des procédés d'exploitation qui permettent d'accroître très sensiblement ce taux. Parmi ces procédés, l'injection de fluides supercritiques joue un rôle prometteur. Les principaux fluides actuellement utilisés sont : le méthane (ou plus généralement les gaz hydrocarbures dits pauvres , l'azote et enfin le gaz carbonique. Les domaines d'application et les mécanismes thermodynamiques mis en jeu sont brièvement exposés, les sources de fluides supercritiques disponibles au voisinage des gisements pétroliers sont rapidement répertoriées et certains problèmes d'exploitation évoqués. Outre leur application en récupération assistée, les fluides supercritiques sont également impliqués dans des procédés de raffinage et d'extraction divers. C'est le procédé de désasphaltage de fractions pétrolières lourdes qui, en 1956, a fait l'objet de la première application industrielle exploitant les fortes variations du pouvoir solvant d'un fluide au voisinage de son point critique. Ce procédé connaît, depuis une dizaine d'années, un regain d'intérêt du fait de l'économie d'énergie qu'il permet de réaliser. D'autre part, les schistes bitumineux, les sables asphaltiques et les charbons, sources d'hydrocarbures considérables pour l'avenir, constituent des domaines d'applications potentielles originales des fluides supercritiques. Les procédés spécifiques, pour la plupart en cours de développement au stade pilote, sont passés en revue. The average recovery by natural drainage from oil fields is barely 30%. Enhanced recovery includes all production processes which appreciably increase this rate. Among such processes, supercritical fluid flooding is quite promising. The main fluids now used are methane (or, more generally, so-called leangaseous hydrocarbons, nitrogen and carbon

  6. Contribution to the automatic command in robotics - Application to the command by microprocessors of the articulated systems; Contribution a la commande automatique en robotique. Application a la commande par microprocesseurs des manipulateurs articules

    Energy Technology Data Exchange (ETDEWEB)

    Al Mouhamed, Mayez

    1982-01-29

    The first part of the present paper deals with the main methods of changing the coordinates for a general articulated system. After a definition of the coordinates changing, we propose a coordination system designed for easy programming of the movements. Its characteristic is to permit the action anywhere on the manipulated object. The second part deals with the force regulation problem. For this purpose we have developed a general force sensor. The informations delivered by the sensor are used by force regulators which are intended for the automatic assembly of subsystems. In the third part the dynamic problem of the articulated systems is exposed. We present a new method which allows to determine dynamic parameters from appropriate motions of the robot. These parameters are then used to implement the dynamic control. Several applications, using the powerful microprocessor INTEL 8086 and its arithmetic coprocessor 8087, are presented, in order to demonstrate the performances gained. (author) [French] Dans la premiere partie de ce memoire, nous exposons les principales methodes de changement de coordonnees pour un systeme articule general. Apres une definition adequate de ce dernier, nous proposons un systeme de coordination permettant une programmation facile des mouvements. Sa caracteristique est de prendre comme centre d'action un point quelconque de l'objet manipule. Dans la deuxieme partie, nous etudions la regulation en effort. Pour cela nous avons developpe un capteur de forces general. Les informations que delivre ce dernier sont utilisees par des regulateurs d'effort adaptes au contexte de l'assemblage automatique des pieces. Dans la troisieme partie, nous exposons une nouvelle methode de commande dynamique des systemes articules. Nous obtenons des parametres dynamiques du robot a partir de mouvements appropries. Ces derniers sont ensuite utilises dans l'elaboration des commandes. Des applications utilisant le microprocesseur INTEL 8086 avec son

  7. A new Volcanic managEment Risk Database desIgn (VERDI): Application to El Hierro Island (Canary Islands)

    Science.gov (United States)

    Bartolini, S.; Becerril, L.; Martí, J.

    2014-11-01

    One of the most important issues in modern volcanology is the assessment of volcanic risk, which will depend - among other factors - on both the quantity and quality of the available data and an optimum storage mechanism. This will require the design of purpose-built databases that take into account data format and availability and afford easy data storage and sharing, and will provide for a more complete risk assessment that combines different analyses but avoids any duplication of information. Data contained in any such database should facilitate spatial and temporal analysis that will (1) produce probabilistic hazard models for future vent opening, (2) simulate volcanic hazards and (3) assess their socio-economic impact. We describe the design of a new spatial database structure, VERDI (Volcanic managEment Risk Database desIgn), which allows different types of data, including geological, volcanological, meteorological, monitoring and socio-economic information, to be manipulated, organized and managed. The root of the question is to ensure that VERDI will serve as a tool for connecting different kinds of data sources, GIS platforms and modeling applications. We present an overview of the database design, its components and the attributes that play an important role in the database model. The potential of the VERDI structure and the possibilities it offers in regard to data organization are here shown through its application on El Hierro (Canary Islands). The VERDI database will provide scientists and decision makers with a useful tool that will assist to conduct volcanic risk assessment and management.

  8. Thermodynamic study on the complexation of Trivalent actinide and lanthanide cation by N-donor ligands in homogeneous conditions; Etude thermodynamique de la complexation des ions actinide (III) et lanthanide (III) par des ligands polyazotes en milieu homogene

    Energy Technology Data Exchange (ETDEWEB)

    Miguirditchian, M

    2004-07-01

    Polydentate N-donor ligands, alone or combined with a synergic acid, may selectively extract minor actinides(III) from lanthanide(III) ions, allowing to develop separation processes of long-live radioelements. The aim of the researches carried out during this thesis was to better understand the chemical mechanisms of the complexation of f-elements by Adptz, a tridentate N-donor ligand, in homogeneous conditions. A thermodynamic approach was retained in order to estimate, from an energetic point of view, the influence of the different contributions to the reaction, and to acquire a complete set of thermodynamic data on this reaction. First, the influence of the nature of the cation on the thermodynamics was considered. The stability constants of the 1/1 complexes were systematically determined by UV-visible spectrophotometry for every lanthanide ion (except promethium) and for yttrium in a mixed solvent methanol/water in volume proportions 75/25%. The thermodynamic parameters ({delta}H{sup 0} {delta}{sup S}) of complexation were estimated by the van't Hoff method and by micro-calorimetry. The trends of the variations across the lanthanide series are compared with similar studies. The same methods were applied to the study of three actinide(III) cations: plutonium, americium and curium. The comparison of these values with those obtained for the lanthanides highlights the increase of stability of these complexes by a factor of 20 in favor of the actinide cations. This gap is explained by a more exothermic reaction and is associated, in the data interpretation, to a higher covalency of the actinide(III)-nitrogen bond. Then, the influence of the change of solvent composition on the thermodynamic of complexation was studied. The thermodynamic parameters of the complexation of europium(III) by Adptz were determined for several fractions of methanol. The stability of the complex formed increases with the percentage of methanol in the mixed solvent, owing to an

  9. Developpement d'une methode calorimetrique de mesure des pertes ac pour des rubans supraconducteurs a haute temperature critique

    Science.gov (United States)

    Dolez, Patricia

    supraconductrice qui restent fixes a l'interface coeur-enveloppe, et le revetement en alliage d'argent. L'interet d'une methode calorimetrique par rapport a la technique electrique, plus rapide, plus sensible et maintenant fiable, reside dans la possibilite de realiser des mesures de pertes ac dans des environnements complexes, reproduisant la situation presente par exemple dans un cable de transport d'energie ou dans un transformateur. En particulier, la superposition d'un courant dc en plus du courant ac habituel nous a permis d'observer experimentalement, pour la premiere fois a notre connaissance, un comportement particulier des pertes ac en fonction de la valeur du courant dc decrit theoriquement par LeBlanc. Nous avons pu en deduire la presence d'un courant d'ecrantage Meissner de 16 A, ce qui nous permet de determiner les conditions dans lesquelles une reduction du niveau de pertes ac pourrait etre obtenue par application d'un courant dc, phenomene denomme "vallee de Clem".

  10. Structural study of the uranyl and rare earth complexation functionalized by the CMPO; Etude structurale de la complexation de l'uranyle et des ions lanthanides par des calixarenes fonctionnalises par le CMPO

    Energy Technology Data Exchange (ETDEWEB)

    Cherfa, S

    1998-12-10

    In view of reducing the volume of nuclear waste solutions, a possible way is to extract simultaneously actinide and lanthanide ions prior to their ulterior separation.. Historically, the two extractant families used for nuclear waste reprocessing are the phosphine oxides and the CMPO (Carbamoyl Methyl Phosphine Oxide). For a better understanding of the complexes formed during extraction, we undertook structural studies of the complexes formed between uranyl and lanthanide (III) ions and the two classes of ligands cited above. These studies have been performed by X-ray diffraction on single crystals. Recently, a new type of extractants of lanthanide (III) and actinide (III) ions has been developed. When the Organic macrocycle called calixarene (an oligomeric compound resulting from the poly-condensation of phenolic units) is functionalized by a CMPO ligand, the extracting power, in terms of yield and selectivity towards lightest lanthanides, is greatly enhanced compared to the one measured for the single CMPO. Our X-ray diffraction studies allowed us to characterise, in terms of stoichiometry and monodentate or bidentate coordination mode of the CMPO functions, the complexes of calix[4]arene-CMPO (with four phenolic units) with lanthanide nitrates and uranyl. These different steps of characterisation enabled us to determine the correlation between the structures of the complexes and both selectivity and exacerbation of the extracting power measured in the liquid phase. (author)

  11. 8th conference on Finite Volumes for Complex Applications

    CERN Document Server

    Omnes, Pascal

    2017-01-01

    This first volume of the proceedings of the 8th conference on "Finite Volumes for Complex Applications" (Lille, June 2017) covers various topics including convergence and stability analysis, as well as investigations of these methods from the point of view of compatibility with physical principles. It collects together the focused invited papers comparing advanced numerical methods for Stokes and Navier–Stokes equations on a benchmark, as well as reviewed contributions from internationally leading researchers in the field of analysis of finite volume and related methods, offering a comprehensive overview of the state of the art in the field. The finite volume method in its various forms is a space discretization technique for partial differential equations based on the fundamental physical principle of conservation, and recent decades have brought significant advances in the theoretical understanding of the method. Many finite volume methods preserve further qualitative or asymptotic properties, including m...

  12. Study of radionuclides complexes formation by organic compounds in intermediate and low-level radioactive wastes; Etude de la mobilisation, par des complexants organiques, des radionucleides contenus dans les dechets radioactifs de faible et moyenne activite

    Energy Technology Data Exchange (ETDEWEB)

    Bourbon, X.

    1994-12-01

    In the general framework of the safety of nuclear wastes of low and intermediate activity, we studied the effects of organic compounds on the solubilization of metallic cations. Organic compounds originate from the degradation of cellulose in concrete interstitial waters. Degradation reactions generate a number of products, among which carboxylic acids. These acids are known for their chelating properties. We first analysed the degradation of cellulose in alkaline conditions: we qualitatively and quantitatively determined the degradation products for various reaction progress indices, including a dozen of carboxylic acids. The principal goal of our work was the prediction of the behaviour of metallic cations in such cellulose degradation solutions. Owing the complexity of the system, a priori theoretical calculation are not possible. We have thus decided to choose tetra hydroxy pentanoic acid as a reference compound in order to simulate as accurately as possible the behaviour of more complex acids which contain similar functional groups. We have experimentally determined the complexing properties of this reference acid toward divalent cobalt and copper, and trivalent samarium and europium. Simple and mixed complex (hydroxyl) have been evidenced in alkaline medium. Their stability constants have been determined and extrapolated at zero ionic strength using the SIT theory. These results allowed us to theoretically predict the behaviour of our four reference cations in cellulose degradation products formed in concrete interstitial waters. In parallel, we have measured their solubility in real cellulose degradation solutions. Solubility predictions are correct for transition metals, but not for rare earth cations. In this case the complexes which have been identified with tetra hydroxy pentanoic acid are not stable enough to dissolve metallic hydroxides. In real degradation solutions, other compounds would account for the enhancement of rare earth elements solubility.

  13. Application des techniques de diffusion de la lumière des rayons x et des neutrons à l'étude des systèmes colloïdaux. Deuxième partie : étude des différents systèmes : polymères en solution à l'état solide, solutions micellaires, systèmes fractals Application of Light, X-Ray and Neutron Diffusion Techniques to the Study of Colloidal Systems. Part Two: Research on Different Systems: Polymers in Solution in the Solid State, Micellar Solutions, Fractals Systems

    Directory of Open Access Journals (Sweden)

    Espinat D.

    2006-11-01

    Full Text Available Cet article fait suite à la première partie (Revue Inst. Franç. du Pétrole, vol. 45, n°6, novembre-décembre 1990 concernant l'application des techniques de diffusion de la lumière, des rayons X et des neutrons à l'étude des systèmes colloïdaux et plus précisément à la présentation théorique des trois méthodes. L'objet de cette deuxième partie est la présentation non exhaustive de quelques domaines d'applications. Nous nous attacherons tout particulièrement à présenter les potentialités des méthodes pour la caractérisation de systèmes colloïdaux ou divisés rencontrés dans de nombreuses branches d'activité de l'industrie pétrolière. Nous aborderons dans une première partie les solutions polymériques et colloïdales. En particulier nous nous attarderons sur l'importance des techniques de diffusion pour la caractérisation des polymères en solution et des solutions micellaires. Nous verrons également quelles informations la diffusion centrale peut apporter sur la macrostructure des polymères cristallisés ou amorphes à l'état solide. De nombreux systèmes présentent une structure de type fractal ; après présentation de quelques exemples, nous montrerons que les méthodes de diffusion peuvent apporter certaines informations sur ces matériaux, notamment la dimension fractale. This article is the second one (the first one was published in Revue de l'Institut Français du Pétrole No. 6, NovemberDecember 1990 concerning the application of techniques of light scattering, X rays and neutrons to the analysis of colloidal systems and more specifically to the theoretical description of the three methods. The aim of this second part is to make a nonexhaustive description of several fields of applications. A special effort is made to describe the potential of these methods for characterizing colloidal or divided systems encountered in a great many activities involving the petroleum industry. The first part of this

  14. Perception des bruits d'impact
    Application au bruit de fermeture de porte automobile

    OpenAIRE

    Bezat, Marie-Céline

    2007-01-01

    The industrial field of door closing sounds consists in translating drivers' expectations into specifications for the mechanical components of the door. A client who manipulates a door in a showroom and perceives from the door closing sound that it is indeed closed also induces complex evocations of quality and solidity to which the manufacturer is particularly attentive. The translation of these complex evocations into technical rules is not an immediate process. A first step consists in cha...

  15. The step complexity measure - its meaning and applications

    International Nuclear Information System (INIS)

    Park, Jin Kyun; Jung, Won Dea; Kim, Jae Whan; Ha, Jae Joo

    2003-01-01

    According to related studies, it was revealed that the procedural deviation plays a significant role in initiating accidents or incidents. This means that, to maximize safety, it is indispensable to be able to answer the question of 'why the operators deviate from procedures?' In this study, the SC(Step Complexity) measure is introduced to investigate its applicability for studying the procedural deviation, since it was shown that the change of the operators' performance is strongly correlated with the change of SC scores. This means that the SC measure could play an important role for researches related to the procedural deviation, since it is strongly believed that complicated procedures would affect both the operators' performance and the possibility of the procedural deviation. Thus, to ensure this expectation, the meaning of the SC measure is investigated through brief explanations including the necessity, theoretical basis and verification activities of the SC measure. As a result, it is confirmed that the SC measure can be used to explain the change of the operators' performance due to the task complexity implied by procedures. In addition, it seems that the SC measure may be useful for various purposes, particularly for scrutinizing the relationship between the procedural deviation and complicated procedures

  16. Informational analysis involving application of complex information system

    Science.gov (United States)

    Ciupak, Clébia; Vanti, Adolfo Alberto; Balloni, Antonio José; Espin, Rafael

    The aim of the present research is performing an informal analysis for internal audit involving the application of complex information system based on fuzzy logic. The same has been applied in internal audit involving the integration of the accounting field into the information systems field. The technological advancements can provide improvements to the work performed by the internal audit. Thus we aim to find, in the complex information systems, priorities for the work of internal audit of a high importance Private Institution of Higher Education. The applied method is quali-quantitative, as from the definition of strategic linguistic variables it was possible to transform them into quantitative with the matrix intersection. By means of a case study, where data were collected via interview with the Administrative Pro-Rector, who takes part at the elaboration of the strategic planning of the institution, it was possible to infer analysis concerning points which must be prioritized at the internal audit work. We emphasize that the priorities were identified when processed in a system (of academic use). From the study we can conclude that, starting from these information systems, audit can identify priorities on its work program. Along with plans and strategic objectives of the enterprise, the internal auditor can define operational procedures to work in favor of the attainment of the objectives of the organization.

  17. Rational Formulation of Alternative Fuels using QSPR Methods: Application to Jet Fuels Développement d’un outil d’aide à la formulation des carburants alternatifs utilisant des méthodes QSPR (Quantitative Structure Property Relationship: application aux carburéacteurs

    Directory of Open Access Journals (Sweden)

    Saldana D.A.

    2013-06-01

    from the literature, from experimental measurements and from molecular simulations for complex molecules. The interest of such models in the selection of molecules can be shown for example by the trade-off between cold flow properties and density of paraffinic compounds. If the carbon chain length is too high, the cold flow properties are compromised. One solution can be to increase branching or incorporate fuel base with good cold flow properties such as naphthenic or aromatic compounds. However, this leads to a decrease in density below the jet fuel specification. Again, using naphthenic of alkyl-aromatic compounds produced from biomass can help. Le développement des carburants alternatifs est en plein essor, notamment dans le domaine aéronautique. Cela se concrétise par la possibilité d’incorporer jusqu’à 50 % de carburants de synthèse de type Fischer- Tropsch (FT ou hydroprocessed esters and fatty acids (HEFA dans du carburéacteur. De même, ces carburants paraffiniques se développent pour le transport terrestre en parallèle des biocarburants à base d’esters ou d’alcool actuellement disponibles. La formulation de ces carburants alternatifs est actuellement basée sur une sélection des produits via des critères physiques. L’atteinte de ces critères se fait souvent par des formulations empiriques et ce type de fonctionnement ne s’avère pas très efficace et montre ses limites. En effet, les carburants alternatifs présentent des propriétés chimiques qui peuvent être différentes en fonction du procédé (répartition n-paraffines/iso-paraffines, longueur de chaîne, ramification, etc. et donc modulable. Ainsi, une nouvelle voie pourrait être envisagée visant à déterminer par le calcul, la molécule (ou le mélange de molécules la plus à même de répondre au cahier des charges du carburant, puis à étudier ou à optimiser les voies de synthèse permettant d’accéder à ces produits. Le travail présenté a pour objectif le d

  18. Complex basis functions for molecular resonances: Methodology and applications

    Science.gov (United States)

    White, Alec; McCurdy, C. William; Head-Gordon, Martin

    The computation of positions and widths of metastable electronic states is a challenge for molecular electronic structure theory because, in addition to the difficulty of the many-body problem, such states obey scattering boundary conditions. These resonances cannot be addressed with naïve application of traditional bound state electronic structure theory. Non-Hermitian electronic structure methods employing complex basis functions is one way that we may rigorously treat resonances within the framework of traditional electronic structure theory. In this talk, I will discuss our recent work in this area including the methodological extension from single determinant SCF-based approaches to highly correlated levels of wavefunction-based theory such as equation of motion coupled cluster and many-body perturbation theory. These approaches provide a hierarchy of theoretical methods for the computation of positions and widths of molecular resonances. Within this framework, we may also examine properties of resonances including the dependence of these parameters on molecular geometry. Some applications of these methods to temporary anions and dianions will also be discussed.

  19. Study of the alkaline cations complexation by photo-isomerizable calixarenes; Etude de la complexation de cations alcalins par des calixarenes photoisomerisables

    Energy Technology Data Exchange (ETDEWEB)

    Reynier, N.

    1996-04-25

    The first step to reduce the volume and the toxicity of radioactive waste coming from the spent fuel reprocessing is to separate long life radioisotopes from others ones with a shorter period. The aim of this study is to show that the control of the two phenomenons, complexation of the cation by the calixarenes and its de-complexation, can be envisaged by the introduction on the molecule of a chromophore group, azo benzene, able to modify the complexing site structure of the calixarenes with an isomerization trans-cis induced by ultraviolet radiation, and isomerization cis-trans thermally induced by a visible radiation. (N.C.). 112 refs., 78 figs., 23 tabs.

  20. Evaluation des risques-projet par une approche AHP/WPM: Application à un projet réel BTP

    OpenAIRE

    LMOUSSAOUI , Hafida; JAMOULI , Hicham

    2015-01-01

    International audience; La complexité et l'incertitude de l'environnement sont à l'origine de nouveaux défis auxquels les entreprises du domaine BTP font face quotidiennement. La maîtrise des paramètres des projets devient donc une nécessité pour leur pérennité. L'objectif du management des risques est de maîtriser ces paramètres pendant toutes les phases du projet. Il s'appuie sur un processus continu et itératif permettant successivement d'identifier et analyser les risques encourus, les év...

  1. Quantum Mechanical Simulations of Complex Nanostructures for Photovoltaic Applications

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Zhigang [Colorado School of Mines, Golden, CO (United States)

    2017-05-31

    A quantitative understanding of the electronic excitations in nanostructures, especially complex nanostructures, is crucial for making new-generation photovoltaic (PV) cells based on nanotechnology, which have high efficiency and low cost. Yet current quantum mechanical simulation methods are either computationally too expensive or not accurate and reliable enough, hindering the rational design of the nanoscale PV cells. The PI seeks to develop new methodologies to overcome the challenges in this very difficult and long-lasting problem, pushing the field forward so that electronic excitations can be accurately predicted for systems involving thousands of atoms. The primary objective of this project is to develop new approaches for electronic excitation calculations that are more accurate than traditional density functional theory (DFT) and are applicable to systems larger than what current beyond-DFT methods can treat. In this proposal, the PI will first address the excited-state problem within the DFT framework to obtain quasiparticle energies from both Kohn-Sham (KS) eigenvalues and orbitals; and the electron-hole binding energy will be computed based on screened Coulomb interaction of corresponding DFT orbitals. The accuracy of these approaches will be examined against many-body methods of GW/BSE and quantum Monte Carlo (QMC). The PI will also work on improving the accuracy and efficiency of the GW/BSE and QMC methods in electronic excitation computations by using better KS orbitals obtained from orbital-dependent DFT as inputs. Then an extended QMC database of ground- and excited-state properties will be developed, and this will be spot checked and supplemented with data from GW/BSE calculations. The investigation will subsequently focus on the development of an improved exchange-correlation (XC) density functional beyond the current generalized gradient approximation (GGA) level of parameterization, with parameters fitted to the QMC database. This will allow

  2. Thermoluminescence du quartz naturel et artificiel pur ou dopé des ions Fe++ et Fe+++: application à la datation des poteries

    Directory of Open Access Journals (Sweden)

    1978-01-01

    Full Text Available La thermoluminescence constatée sur les échantillons de poteries et conduisant à la datation archéologique de celles-ci, est due aux inclusions de quartz initialement contenues dans l'argile. Nous présentons une étude de la thermoluminescence d'échantillons de quartz monocristallin synthétique dans lesquels des impuretés ont été volontairement ajoutées et appliquons les résultats à une nouvelle technique de datation, la méthode DATE (différence d'atténuation temporelle des émissions. La termoluminiscencia constatada en muestras de cerámica permite una datación arqueológica es debida a las inclusiones de cuarzo inicialmente contenidas en la arcilla. Se presenta un estudio de la termoluminiscencia de muestras de cuarzo monocristalino sintético en las cuales han sido colocadas voluntariamente impurezas se han aplicado los resultados de una nueva técnica de fechado, el método DATE (Diferencia de atenuación temporal de emisiones. The thermoluminescence observed on samples of pottery and leading to their archaeological dating is a result of the presence of quartz particles originally enclosed in the clay. We offer a study of the termoluminescence of samples of synthetic mono-crystalline quartz doped in with impurities and apply the results to a new dating technique, the 'DATE' method, based upon difference in time attenuation of the emissions.

  3. L'evolution thermique de la matière organique des sédiments : applications d'une simulation mathématique. Potentiel pétrolier des bassins sédimentaires de reconstitution de l'histoire thermique des sédiments Thermal Evolution of Organic Matter in Sediments : Application of a Mathematical Simulation. Petrleum Potential of Sedimentary Basins and Reconstructing the Thermal History of Sediments

    Directory of Open Access Journals (Sweden)

    Tissot B.

    2006-11-01

    Full Text Available Au moyen d'un modèle mathématique, on simule la dégradation thermique de la matière organique des sédiments. Les applications possibles de ce modèle concernent la recherche des zones favorables pour la prospection de l'huile ou du gaz, la détermination de l'époque de formation des hydrocarbures pour la comparer avec l'âge des pièges et celui des couvertures, l'évaluation des réserves ultimes d'un bassin, ainsi que la pyrogénation des schistes bitumineux. Le type de matière organique est représenté dans le modèle par un jeu de constantes qui sont déterminées par des essais de laboratoire; on discute en particulier la distribution des énergies d'activation et sa signification en rapport avec la composition du kérogène. Les autres données nécessaires sont la reconstitution géologique de l'enfouissement et le gradient géothermique. La reconstitution de la géothermie ancienne pose un problème particulier. En associant la mesure de la réflectance de la vitrinite et la loi d'enfouissement, on peut, au moyen d'un modèle d'évolution de la vitrinite, rétablir dans la plupart des cas l'histoire thermique de la matière organique. Ce résultat présente certes un grand intérêt pour l'exploration pétrolière, mais son champ d'application dépasse largement ce domaine et s'étend aux problèmes de géologie générale géothermie, diagenèse des sédiments, tectonique globale, etc. A mathematical model is used to simulate the thermal degradation of the organic matter in sediments. The possible applications of this model have to do with the seorch for favorable ail or gas prospection zones, determining the period when hydrocarbons were formed so as to compare it with the age of traps and caprocks, and estimating the ultimate reserves of a basin a well as the pyrogenation of ail shales. The type of organic matter is represented in the model by a set of constants that are determined by laboratory tests. This article in

  4. Oligomerization of ethylene catalysed by nickel complexes associated with nitrogen ligands in ionic liquids; Oligomerisation de l'ethylene catalysee par des complexes du nickel associes a des ligands azotes dans les liquides ioniques

    Energy Technology Data Exchange (ETDEWEB)

    Lecocq, V.

    2003-09-01

    We report here the use of a new class of catalytic systems based on a nickel active center associated with nitrogen ligands, such as di-imines, or imino-pyridines, for the oligomerization of ethylene in a biphasic medium using ionic liquids as the catalyst solvent. The nickel catalyst is immobilized in the ionic liquid phase in which the olefinic reaction products are poorly miscible. This biphasic system makes possible an easy separation and recycle of the catalyst. Numerous di-imine and imino-pyridine ligands with different steric and electronic properties have been synthesized and their corresponding nickel complexes isolated and characterized. Different ionic liquids, based on chloro-aluminates or non-chloro-aluminates anions, have also been prepared and characterized. The effect of the nature of the ligand, the ionic liquid, the nickel precursor and its mode of activation have been studied and correlated with the selectivity and activity of the transformation of ethylene. (author)

  5. Trends in the choice of refrigerants according to the applications; Tendances dans le choix des frigorigenes selon les applications

    Energy Technology Data Exchange (ETDEWEB)

    Billiard, F.

    2002-07-01

    No general rules exist in the choice of refrigerants but five classical criteria: thermo-physical, technological, economical, safety, environmental, some regulations and local standards, and the 'cultural' criteria linked with the professional habits and with the personnel training. The best approach to present the evolutions and trends in this domain consists in reasoning application by application. In this document, 8 applications are analyzed: domestic, commercial, and industrial refrigeration, terrestrial and maritime refrigerating transport, air conditioning and heat pumps, air conditioning with water cooling groups, and mobile air conditioning. For each application, national and worldwide statistical data are given which allow to characterize the economical importance of the sector of application and the trends in the choice of refrigerants (HFC, ammonia, hydrocarbons, CO{sub 2} etc..). Finally, some future trends are briefly evoked. (J.S.)

  6. Light ions radiobiological effects on human tumoral cells: measurements modelling and application to hadron-therapy; Mesures et modelisation des effets radiobiologiques des ions legers sur des cellules tumorales humaines: application a l'hadrontherapie

    Energy Technology Data Exchange (ETDEWEB)

    Jalade, P

    2005-11-15

    In classical radiotherapy, the characteristics of photons interactions undergo limits for the treatment of radioresistant and not well located tumours. Pioneering treatments of patients at the Lawrence Laboratory at Berkeley has demonstrated two advantages of hadrons beams: the Relative Biologic Effect (the RBE) and the ballistic of the beams. Since 1994, the clinical centre at Chiba, has demonstrated successfully the applicability of the method. A physics group, managed by G. Kraft, at Darmstadt in Germany, has underlined the advantages of carbon beams. An European pool, called ENGIGHT (European Network for LIGHt ion Therapy) has been created in which the French ETOILE project appeared. The purpose of the thesis concerns measurements and models of 'in vitro' human cells survival. In the first part, the nowadays situation in particles interactions, tracks and cells structures and radiobiology is presented here. The second is devoted to the models based on the beam tracks and localization of the physical dose. Discussion of sensitivity to various parameters of the model has been realized with the help of numerical simulations. Finally the predictions of the improved model has been compared to experimental irradiations of human cells with argon and carbon beams of the GANIL machine. Conclusion of such study shows the performance and limits of a local model for predicting the radiobiological efficiency of light ions in hadron-therapy. (author)

  7. Light ions radiobiological effects on human tumoral cells: measurements modelling and application to hadron-therapy; Mesures et modelisation des effets radiobiologiques des ions legers sur des cellules tumorales humaines: application a l'hadrontherapie

    Energy Technology Data Exchange (ETDEWEB)

    Jalade, P

    2005-11-15

    In classical radiotherapy, the characteristics of photons interactions undergo limits for the treatment of radioresistant and not well located tumours. Pioneering treatments of patients at the Lawrence Laboratory at Berkeley has demonstrated two advantages of hadrons beams: the Relative Biologic Effect (the RBE) and the ballistic of the beams. Since 1994, the clinical centre at Chiba, has demonstrated successfully the applicability of the method. A physics group, managed by G. Kraft, at Darmstadt in Germany, has underlined the advantages of carbon beams. An European pool, called ENGIGHT (European Network for LIGHt ion Therapy) has been created in which the French ETOILE project appeared. The purpose of the thesis concerns measurements and models of 'in vitro' human cells survival. In the first part, the nowadays situation in particles interactions, tracks and cells structures and radiobiology is presented here. The second is devoted to the models based on the beam tracks and localization of the physical dose. Discussion of sensitivity to various parameters of the model has been realized with the help of numerical simulations. Finally the predictions of the improved model has been compared to experimental irradiations of human cells with argon and carbon beams of the GANIL machine. Conclusion of such study shows the performance and limits of a local model for predicting the radiobiological efficiency of light ions in hadron-therapy. (author)

  8. Quantum Google algorithm. Construction and application to complex networks

    Science.gov (United States)

    Paparo, G. D.; Müller, M.; Comellas, F.; Martin-Delgado, M. A.

    2014-07-01

    We review the main findings on the ranking capabilities of the recently proposed Quantum PageRank algorithm (G.D. Paparo et al., Sci. Rep. 2, 444 (2012) and G.D. Paparo et al., Sci. Rep. 3, 2773 (2013)) applied to large complex networks. The algorithm has been shown to identify unambiguously the underlying topology of the network and to be capable of clearly highlighting the structure of secondary hubs of networks. Furthermore, it can resolve the degeneracy in importance of the low-lying part of the list of rankings. Examples of applications include real-world instances from the WWW, which typically display a scale-free network structure and models of hierarchical networks. The quantum algorithm has been shown to display an increased stability with respect to a variation of the damping parameter, present in the Google algorithm, and a more clearly pronounced power-law behaviour in the distribution of importance among the nodes, as compared to the classical algorithm.

  9. Applications of STEM-EELS to complex oxides

    KAUST Repository

    Gá zquez, Jaume; Sá nchez-Santolino, Gabriel; Biškup, Neven; Roldá n, Manuel A.; Cabero, M.; Pennycook, Stephen J.; Varela, Marí a

    2016-01-01

    In this chapter we will review a few examples of applications of atomic resolution aberration corrected scanning transmission electron microscopy (STEM) and electron energy-loss spectroscopy (EELS) to complex oxide materials. These are most challenging systems where subtle changes in structure or chemistry may result in colossal responses in macroscopic physical behavior. Here, we will review how atomic resolution compositional mapping can be achieved in manganite thin films and single crystals, highlighting the importance of considering artifacts during quantification. Besides, minor changes in near edge fine structure may take place when the crystalline environment, and hence nearest neighbor configuration, is modified. These can also be tracked by atomic resolution EELS, as will be shown through the study of binary Fe oxides. Also, examples regarding the study of distributions of point defects such as O vacancies in cobaltite thin films will be discussed. In these materials, a combination of epitaxial strain and defects may promote physical behaviors not present in bulk, such as the stabilization of unexpected spin state superlattices. Last, a study of extended defects such as dislocation lines will be reviewed. In particular, we will show how chemical segregation at dislocation cores in yttria-stabilized zirconia grain boundaries results in the generation of static O vacancies that affect the local electrostatic potential and hence, the macroscopic ionic conduction properties. © 2016.

  10. Applications of STEM-EELS to complex oxides

    KAUST Repository

    Gázquez, Jaume

    2016-06-26

    In this chapter we will review a few examples of applications of atomic resolution aberration corrected scanning transmission electron microscopy (STEM) and electron energy-loss spectroscopy (EELS) to complex oxide materials. These are most challenging systems where subtle changes in structure or chemistry may result in colossal responses in macroscopic physical behavior. Here, we will review how atomic resolution compositional mapping can be achieved in manganite thin films and single crystals, highlighting the importance of considering artifacts during quantification. Besides, minor changes in near edge fine structure may take place when the crystalline environment, and hence nearest neighbor configuration, is modified. These can also be tracked by atomic resolution EELS, as will be shown through the study of binary Fe oxides. Also, examples regarding the study of distributions of point defects such as O vacancies in cobaltite thin films will be discussed. In these materials, a combination of epitaxial strain and defects may promote physical behaviors not present in bulk, such as the stabilization of unexpected spin state superlattices. Last, a study of extended defects such as dislocation lines will be reviewed. In particular, we will show how chemical segregation at dislocation cores in yttria-stabilized zirconia grain boundaries results in the generation of static O vacancies that affect the local electrostatic potential and hence, the macroscopic ionic conduction properties. © 2016.

  11. Determinatin dúne application des betons de balles de riz dans le ...

    African Journals Online (AJOL)

    The obtained concretes are light and have compressive strength between 1 and 8 MPa. An application of these concretes is their use for the manufacture of masonry blocks and interjoists entering in the realization of walls and coffer floor. Key words: Rice husks, lightweight concrete, compressive strength, Masonry blocks, ...

  12. Applications analytiques des films minces de mercure protégés par ...

    African Journals Online (AJOL)

    Analytical application of fibrinogen-coated mercury film electrodes for the detection of lead and cadmium in water samples. The aim of this study was the development of sensor based on fibrinogen (Fbg) coated mercury film electrodes at carbon paste electrode in the perspective of in-field stripping analysis of heavy metals ...

  13. Calorimetric approach of lanthanides (3) complexation and extraction by malonamides; Approche calorimetrique de la complexation et de l'extraction des lanthanides (3) par les malonamides

    Energy Technology Data Exchange (ETDEWEB)

    Flandin, J.L

    2001-07-01

    In the field of long lived radionuclides separation, diamides are interesting extractants because of their ability to co-extract trivalent lanthanides and actinides, which is a preliminary and essential step in high level radioactive waste reprocessing. The research carried out contributes to a better understanding of the mechanisms and the aim is the determination of thermodynamics properties ({delta}{sub r}G, {delta}{sub r}H et {delta}{sub r}S) related to the complexation and the extraction of lanthanides(III) by malonamides. The first part of the document deals with the complexation of lanthanides(III) by an hydrosoluble diamide. The experimental results obtained by UV-visible spectrometry, TRLIF, NMR and microcalorimetric titration proved that lanthanides(III)-TEMA interactions in aqueous medium are very weak and that the complexation reaction is endothermic. The TEMA ligand still stays in the second coordination sphere of coordination of the lanthanide ion. The second part of this study focuses on the extraction of neodymium(III) nitrate by a lipophilic diamide which is an exothermic reaction. The influence of the composition of aqueous and organic phases on the thermodynamics properties {delta}{sub r}G et {delta}{sub r}H has been studied by microcalorimetric titration. The most influent parameter is the total concentration in extractant. As a consequence, thermodynamic values are very dependent on the organic phase organisation before and alter extraction. At the same time, this study showed the interest of the calorimetric approach for the analysis of basic reactions like diamide dilution and their organisation as oligomeric aggregates. (author)

  14. Applicability of ICRP principles for safety analysis of radioactive waste geological storage; Etude de l'applicabilite des principes de la CIPR a l'analyse de surete du stockage geologique des dechets radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    Lombard, J; Hubert, P; Pages, P

    1987-07-01

    modalites de stockage) doit etre determine par un processus comparatif visant a selectionner le niveau conduisant au meilleur compromis entre es depenses de protection et les risques residuels. Ces recommandations, particulierement Ia seconde, s'ecartent des principes des analyses de surete suivis jusqu'a present en France et a l'etranger; cette etude envisage les avantages et inconvenients potentiels lies a l'introduction de ce second principe. Dans ce but on se base sur differentes analyses realisees au niveau international integrant partiellement au moms ces principes. II ressort de cet examen que ces principes sont applicables mais que leur mise en oeuvre necessite une reorientation de modeles d'evaluation en particulier pour s'affranchir d'hypotheses trop conservatrices. Cette mise en oeuvre necessite par ailleurs davantage d'informations que dans le cas d'une approche deterministe de Ia surete puisqu'il faut estimer les consequences et les probabilites de I'ensemble des evenements possibles et ce pour es diverses modalites de stockage que l'on se propose de comparer. L'integration d'evaluation de ce type est cependant plus riche d'enseignements et constitue de ce fait une aide a Ia decision qui peut etre feconde. On peut enfin souligner que cette approche permet un meilleur dialogue entre les differentes instances decisionnelles et plus generalement entre les acteurs du debat, dans Ia mesure ou elle apporte un langage de discussion commun. On notera d'ailleurs que ce souci de clarification s'exprime quelle que soit I'optique de surete adopte (deterministe ou probabiliste), comme en temoignent les interrogations sur le sens du 'scenario central' de I'etude KBS. Par ailleurs, ii semble que ces principes seront vraisemblablement suivis au plan international afin d'uniformiser en outre les modes de gestion de Ia radioprotection dans ses diff?rentes composantes. (author)

  15. Les lipases sont des hydrolases atypiques : principales caractéristiques et applications

    Directory of Open Access Journals (Sweden)

    Fickers P.

    2008-01-01

    Full Text Available ipases are atypical hydrolases: principal characteristics and applications. Due to their kinetic and substrate specificities, triacylglycerol acyl-hydrolases or lipases are atypical enzymes. In function of their microenvironment, lipases are able to act as hydrolases in aqueous solution or as biocatalysts in organic synthesis. As hydrolases, they are responsible of the triglycerids catabolism into fatty acids and glycerol. In many organisms, this reaction plays a major role in the fat and lipid metabolism. In addition, lipases are also able to hydrolyse phospholipids and cholesterol esters. In organic solvent, lipases could catalyse reactions such as esterifications, acidolysis or alcoolysis with enantio-, regio- and chimioselectivity. Lipases form a mixed class of enzyme due to their animal, vegetal or microbial origins. All those properties led to the development of many applications in the food and chemical industries but also in the medical and therapeutic field.

  16. Formation et application des nanoparticules dans les fibres optiques en silice

    OpenAIRE

    Blanc , Wilfried; Dussardier , Bernard

    2016-01-01

    International audience; Optical fibers are the basis for applications that have grown considerably in recent years (telecommunications, sensors, fiber lasers, etc). Despite undeniable successes, it is necessary to develop new generations of amplifying optical fibers that will overcome some limitations typical of silica glass. In this sense, the amplifying Transparent Glass Ceramics (TGC), and particularly the fibers based on this technology, open new perspectives that combine the mechanical a...

  17. Use of tri-laurylamine during the retreatment of irradiated fuels; Utilisation de la trilaurylamine au retraitement des combustibles irradies

    Energy Technology Data Exchange (ETDEWEB)

    Bathellier, A; Koehly, G; Perez, J J; Chesne, A [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1964-07-01

    The purification of aqueous solutions of plutonium can be made by extraction of the Pu (IV) nitrate complex using trilaurylamine in dodecane. The principal physical properties of this solution are considered along with its extractive properties and the influence of foreign ions on the extraction. The application of this method of extraction in a processing cycle for irradiated material is proposed: either for a final purification process or for auxiliary cycles for recovering plutonium from metal production wastes, oxalate precipitation supernatants, or any general aqueous plutonium waste solution. Also proposed are clean-up procedures for regeneration of an extractive solution which has undergone chemical or radiolytic degradation. (authors) [French] La purification du plutonium contenu dans des solutions aqueuses peut etre effectuee par extraction du nitrate de l'ion tetravalent par la trilaurylamine diluee dans du dodecane. Les principales proprietes physiques de ce solvant sont passees en revue ainsi que ses proprietes extractives et l'influence des ions etrangers sur celles-ci. L'application de cette methode d'extraction dans le cycle de traitement des combustibles irradies est envisagee: soit dans le traitement de purification finale, soit dans les cycles annexes ayant trait a la recuperation de plutonium a partir des scories d'elaboration du metal, des eaux-meres oxaliques et d'une facon generale des solutions aqueuses contenant du plutonium. Des traitements de regeneration du solvant ayant subi des degradations chimique ou radiolytique, sont proposes. (auteurs)

  18. Use of tri-laurylamine during the retreatment of irradiated fuels; Utilisation de la trilaurylamine au retraitement des combustibles irradies

    Energy Technology Data Exchange (ETDEWEB)

    Bathellier, A.; Koehly, G.; Perez, J.J.; Chesne, A. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1964-07-01

    The purification of aqueous solutions of plutonium can be made by extraction of the Pu (IV) nitrate complex using trilaurylamine in dodecane. The principal physical properties of this solution are considered along with its extractive properties and the influence of foreign ions on the extraction. The application of this method of extraction in a processing cycle for irradiated material is proposed: either for a final purification process or for auxiliary cycles for recovering plutonium from metal production wastes, oxalate precipitation supernatants, or any general aqueous plutonium waste solution. Also proposed are clean-up procedures for regeneration of an extractive solution which has undergone chemical or radiolytic degradation. (authors) [French] La purification du plutonium contenu dans des solutions aqueuses peut etre effectuee par extraction du nitrate de l'ion tetravalent par la trilaurylamine diluee dans du dodecane. Les principales proprietes physiques de ce solvant sont passees en revue ainsi que ses proprietes extractives et l'influence des ions etrangers sur celles-ci. L'application de cette methode d'extraction dans le cycle de traitement des combustibles irradies est envisagee: soit dans le traitement de purification finale, soit dans les cycles annexes ayant trait a la recuperation de plutonium a partir des scories d'elaboration du metal, des eaux-meres oxaliques et d'une facon generale des solutions aqueuses contenant du plutonium. Des traitements de regeneration du solvant ayant subi des degradations chimique ou radiolytique, sont proposes. (auteurs)

  19. Measurement and analysis of high energy radiation through activation detectors. Application in dosimetry; Sur la mesure et l'analyse des rayonnements de haute energie par detecteurs a activation. Application a la dosimetrie

    Energy Technology Data Exchange (ETDEWEB)

    Sklavenitis, L. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-10-15

    This work is concerned with the possibility of measurement and analysis of radiation fluences within objects of small volume submitted to a high energy proton beam. The first part, consecrated to the establishment of a method of analysis, comprises a detailed study of the radiation nature and energy spectra as well as of the various dosimetry methods. In order to select a group of detectors, high energy nuclear reactions were systematically studied and for some of them cross sections were measured or calculated: for example the cross section of the reaction {sup 11}B (p,n) {sup 11}C between 150 and 3000 MeV and of the reaction {sup 34}S (p,2pn) {sup 32}P between 50 and 3000 MeV. The second part is relative to the application of the fore-mentioned analysis to radiation within a tissue equivalent phantom irradiated by 3 GeV protons. This analysis is sufficiently detailed to allow the reconstitution of the absorbed doses, the dose equivalent and, contingent on a better knowledge of the dose due to heavy particles, the quality factors. It allowed also to follow the evolution of the various dosimetric data as a function of the depth inside the phantom and to verify calculations already done by other researchers. The comparison of the measured doses and the corresponding detector activities revealed the possibility that some detectors could give directly the absorbed dose, or even the dose equivalent, by a simple activity measurement. (author) [French] Le travail porte sur la possibilite de mesure et d'analyse, a l'aide de detecteurs a activation, des fluences de rayonnements a l'interieur d'un objet de petit volume soumis a un faisceau de protons de tres haute energie. La premiere partie, consacree a la mise au point de la methode d'analyse des fluences, comporte une etude detaillee de la nature des rayonnements et de leurs spectres energetiques ainsi que des differentes methodes de dosimetrie. Pour arriver au choix d'un groupe de

  20. Measurement and analysis of high energy radiation through activation detectors. Application in dosimetry; Sur la mesure et l'analyse des rayonnements de haute energie par detecteurs a activation. Application a la dosimetrie

    Energy Technology Data Exchange (ETDEWEB)

    Sklavenitis, L [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-10-15

    This work is concerned with the possibility of measurement and analysis of radiation fluences within objects of small volume submitted to a high energy proton beam. The first part, consecrated to the establishment of a method of analysis, comprises a detailed study of the radiation nature and energy spectra as well as of the various dosimetry methods. In order to select a group of detectors, high energy nuclear reactions were systematically studied and for some of them cross sections were measured or calculated: for example the cross section of the reaction {sup 11}B (p,n) {sup 11}C between 150 and 3000 MeV and of the reaction {sup 34}S (p,2pn) {sup 32}P between 50 and 3000 MeV. The second part is relative to the application of the fore-mentioned analysis to radiation within a tissue equivalent phantom irradiated by 3 GeV protons. This analysis is sufficiently detailed to allow the reconstitution of the absorbed doses, the dose equivalent and, contingent on a better knowledge of the dose due to heavy particles, the quality factors. It allowed also to follow the evolution of the various dosimetric data as a function of the depth inside the phantom and to verify calculations already done by other researchers. The comparison of the measured doses and the corresponding detector activities revealed the possibility that some detectors could give directly the absorbed dose, or even the dose equivalent, by a simple activity measurement. (author) [French] Le travail porte sur la possibilite de mesure et d'analyse, a l'aide de detecteurs a activation, des fluences de rayonnements a l'interieur d'un objet de petit volume soumis a un faisceau de protons de tres haute energie. La premiere partie, consacree a la mise au point de la methode d'analyse des fluences, comporte une etude detaillee de la nature des rayonnements et de leurs spectres energetiques ainsi que des differentes methodes de dosimetrie. Pour arriver au choix d'un groupe de detecteurs, une etude systematique des

  1. Models for the Behavior of Offshore Structure Foundations. Part Two: Applications to Structural Design and Quality Assurance Processes Modèles pour le comportement des fondations d'ouvrages types marins. Deuxième partie : applications au calcul d'ouvrage et processus d'assurance qualité

    Directory of Open Access Journals (Sweden)

    Meimon Y.

    2006-11-01

    structure. Prospects opened up by the research are discussed. La conception des fondations de grands ouvrages est une tâche complexe qui requiert à la fois l'expérience de l'expert et l'utilisation de modèles numériques adéquats pour assurer la sécurité et optimiser les coûts de dimensionnement. En fait, prévoir le comportement d'une fondation nécessite de bien évaluer les effets combinés de la technique de mise en place, de la variabilité spatiale des propriétés mécaniques, de l'incertitude sur les chargements et des techniques de modélisation du comportement mécanique des géomatériaux. Ceci est particulièrement vrai pour les plates-formes marines, qu'elles soient destinées à l'exploration ou à la production du pétrole, dans la mesure où les chargements non-monotones dus à l'environnement marin, souvent très sévère, peuvent avoir des effets très néfastes sur le comportement de ces structures. On présente, en deux parties, la synthèse d'une dizaine d'années d'activités de recherche, menées par une équipe de l'Institut Français du Pétrole (IFP, en collaboration avec plusieurs équipes universitaires et des centres techniques et industriels, pour la mise au point de méthodologies et d'outils adaptés au calcul du comportement des fondations d'ouvrages types marins durant toute la durée de vie de la plate-forme. Cet article concerne la deuxième partie qui est dévolue à l'application des modèles développés au calcul d'ouvrage par la méthode des éléments finis et à l'exposé d'un processus de validation des modèles, étape d'une démarche d'assurance qualité. Méthodes pour le calcul des fondations marines : Le système de programmes FONDOF utilisant la méthode des éléments finis a été développé. Il comprend (fig. 1. 1 des interfaces interactives de mise en données et de dépouillement des résultats ainsi que des modules de calcul, opérationnels comme FONGEO pour les calculs bi et tridimensionnels ou FONDAX pour le

  2. Complexation des acides aminés basiques arginine, histidine et lysine avec l'ADN plasmidique en solution aqueuse : participation à la capture de radicaux sous irradiation X à 1,5 keV

    Science.gov (United States)

    Tariq Khalil, Talat; Taillefumier, Baptiste; Boulanouar, Omar; Mavon, Christophe; Fromm, Michel

    2016-09-01

    L'environnement chimique de l'ADN en situation biologique est complexe notam-ment en raison de la présence d'histones, protéines nucléaires, associées en quantité approximativement égales à l'ADN pour former la chromatine. Les histones possèdent de nombreux radicaux basiques arginine et lysine chargés positivement et dont la majorité se trouve sur les chaînes émergentes, l'ADN présente quant à lui des charges négatives sur ses groupements phosphates localisés tout au long de la double hélice. Dans cette étude, la complexité de la structure de la chromatine nucléaire est dans un premier temps mimée en solution aqueuse par la formation de complexes entre un ADN plasmidique sonde et les trois acides aminés basiques, Arg, His, Lys, qui, mis à part His, sont protonés au pH physiologique. Ces acides aminés libres en solution sont réputés être des capteurs efficaces de radicaux libres, notamment pour le radical hydroxyle, conférant ainsi un pouvoir protecteur vis-à-vis des effets indirects sur l'ADN en situation d'exposition aux rayonnements ionisants. A concentration fixée, les capacités de capture des acides aminés libres, σ, pour le radical hydroxyle sont typiquement les suivantes σHis ≈σArg > σLys (σLys ≈ 0,1 × σArg). Nous avons mesuré les taux de cassures simple brin par plasmide et par Gray (χ) lors d'expositions de solutions aqueuses de complexes [acide aminé - ADN plasmidique] aux rayons X ultra-mous (1,5 keV). A concentrations égales, les trois acides aminés complexés et présents en large excès ne manifestent pas une capacité de protection de l'ADN proportionnelle à leur capacité de capture libre et en solution ; on trouve en effet des taux de cassures dans l'ordre suivant χHis > χArg > χLys (χLys ≈ 0,01 χArg). Après avoir détaillé le mode opératoire de ces mesures, nous analyserons sur des bases bibliographiques, les modes spécifiques d'interaction des acides aminés basiques avec l'ADN. La sp

  3. Application of Artificial Neural Networks to Complex Groundwater Management Problems

    International Nuclear Information System (INIS)

    Coppola, Emery; Poulton, Mary; Charles, Emmanuel; Dustman, John; Szidarovszky, Ferenc

    2003-01-01

    As water quantity and quality problems become increasingly severe, accurate prediction and effective management of scarcer water resources will become critical. In this paper, the successful application of artificial neural network (ANN) technology is described for three types of groundwater prediction and management problems. In the first example, an ANN was trained with simulation data from a physically based numerical model to predict head (groundwater elevation) at locations of interest under variable pumping and climate conditions. The ANN achieved a high degree of predictive accuracy, and its derived state-transition equations were embedded into a multiobjective optimization formulation and solved to generate a trade-off curve depicting water supply in relation to contamination risk. In the second and third examples, ANNs were developed with real-world hydrologic and climate data for different hydrogeologic environments. For the second problem, an ANN was developed using data collected for a 5-year, 8-month period to predict heads in a multilayered surficial and limestone aquifer system under variable pumping, state, and climate conditions. Using weekly stress periods, the ANN substantially outperformed a well-calibrated numerical flow model for the 71-day validation period, and provided insights into the effects of climate and pumping on water levels. For the third problem, an ANN was developed with data collected automatically over a 6-week period to predict hourly heads in 11 high-capacity public supply wells tapping a semiconfined bedrock aquifer and subject to large well-interference effects. Using hourly stress periods, the ANN accurately predicted heads for 24-hour periods in all public supply wells. These test cases demonstrate that the ANN technology can solve a variety of complex groundwater management problems and overcome many of the problems and limitations associated with traditional physically based flow models

  4. Virtual Reality: State of Military Research and Applications in Member Countries (La realite virutelle: L’etat actuel des travaux de recherche et des applications militaires dans les pays membres de l’Alliance)

    Science.gov (United States)

    2003-02-01

    avec des réglages ergonomiques) avec un casque de Réalité Virtuelle (Kaiser Proview 60) en 1999. Cette équipe est également le chef de file du projet...7B.7.2 Activité Image - ENSAM L’activité Image propose un mastère spécialisé en simulation et Réalité Virtuelle. Le but est de former des chefs de...Large-Scale Virtual Worlds. Conference Companion ACM SIGCHI 󈨣, 45-46. Darken, R.P. (1994). Hands-Off Interaction With Menus in Virtual Spaces

  5. Processing of data issued from {gamma} spectrometer. Application to the study of decay schemes; Traitement des informations issues d'un spectrometre {gamma}. Application a l'etude de schemas de desintegration

    Energy Technology Data Exchange (ETDEWEB)

    Boulanger, J P; Legrand, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    The main purpose of the following report is the study of a generation method of {gamma} spectra corresponding to any energy, from a library of some basic spectra. Then we point out how to establish the decay scheme of a radio-nuclide, in using an accurate analysis of full-energy peaks which appear in its complex spectrum, followed by a generation of plain spectra corresponding to the energies of the different transitions, and ending with a least-squares fitting procedure of the complex spectrum. The accuracy of the process is examined comparing the calculated spectra to the ones issued from two kinds of spectrometers (Na I(Tl) and Ge(Li)). The method is then applied to the study of {sup 134}Cs and {sup 95}Zr - {sup 95}Nb. (authors) [French] Le present rapport a pour principal objet l'etude d'une methode de generation de spectres {gamma} correspondant a n'importe quelle energie, a partir d'une bibliotheque de quelques spectres de reference. On montre ensuite comment on peut etablir le schema de desintegration d'un radionucleide, a l'aide d'une analyse precise des pics d'absorption totale apparaissant dans son spectre complexe, suivie d'une generation des spectres simples correspondant aux energies des diverses transitions, et en terminant par une decomposition du spectre complexe par la methode des moindres carres. On examine la validite du procede en comparant les spectres calcules a ceux obtenus avec deux types de detecteurs (scintillateurs et semi-conducteurs). On applique alors la methode a l'etude du {sup 134}Cs et du {sup 95}Zr - {sup 95}Nb. (auteurs)

  6. L’IMPACT DE L’APPLICATION DES REFORMES BALE III SUR L’INDUSTRIE BANCAIRE ROUMAINE

    Directory of Open Access Journals (Sweden)

    Maria Halep

    2012-12-01

    Full Text Available Le début du XXIème a connu un essor remarquable des marchés financiers, de l’innovation et des processus de déréglementation. L’inflation faible, la liquidité abondante, la confiance dans les marchés efficaces et autorégulateurs ont conduit à une perception généralisée de risque faible, incitant les acteurs à une prise accrue de risque. Face aux crises qui s’enchaînent depuis maintenant cinq ans, des mesures de ré-réglementation du système ont été proposées, communément appelées Reformes de Bâle.L’article analyse l’évolution des recommandations de Bâle en lien avec l’évolution économique et des marchés financiers et évalue l’impact de ces dernières sur le secteur bancaire roumain.

  7. Sync in Complex Dynamical Networks: Stability, Evolution, Control, and Application

    OpenAIRE

    Li, Xiang

    2005-01-01

    In the past few years, the discoveries of small-world and scale-free properties of many natural and artificial complex networks have stimulated significant advances in better understanding the relationship between the topology and the collective dynamics of complex networks. This paper reports recent progresses in the literature of synchronization of complex dynamical networks including stability criteria, network synchronizability and uniform synchronous criticality in different topologies, ...

  8. Olefins hydro-formylation catalysed by rhodium complexes using ionic liquids; Hydroformylation des olefines par les complexes du rhodium dans les liquides ioniques

    Energy Technology Data Exchange (ETDEWEB)

    Favre, F.

    2000-10-26

    Biphasic long chain olefins hydro-formylation catalysed by rhodium complexes using ionic liquids allows a selective reaction and an easy separation of the products from the catalyst. This study reports the synthesis of ionic liquids that were used as the catalyst's solvent. Their physical and chemical properties (melting point, solubility of organic substrates) can be varied with the structure of the organic cation (imidazolium, pyridinium, pyrrolydinium) and with its substituents (nature, length, number). It depends also on the nature of the inorganic anion (hexa-fluoro-phosphate, tetrafluoroborate, tri-fluoro-acetate, triflate, bistriflylamidure...). The use of phosphorus ligands bearing ionic functions proved to be efficient to maintain the onerous rhodium catalyst in the ionic liquid phase. Phosphines, phosphites and phosphinites including anionic (sulfonate, carboxylate) or cationic (imidazolium, pyridinium, guanidinium, phosphonium) groups have been synthesised. Finally, the influences of the ligand and of the ionic liquid on the catalytic system performances are described. Selectivities in aldehydes and reaction rates proved to be highly dependent on the nature of the ligand and of the ionic liquid. The different possibilities of recycling the ionic phase containing the rhodium catalyst have been also studied. (author)

  9. Theoretical study of trivalent element complexes for the nuclear waste reprocessing; Etude theorique de complexes d'elements f trivalents pour le retraitement des dechets nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Petit, L

    2007-10-15

    Current energetic and environmental concerns have made the nuclear waste reprocessing to be a major issue in numerous countries. One avenue to treat nuclear spent fuel requires separating selectively trivalent minor actinides An (Am{sup 3+}, Cm{sup 3+}) from lanthanides Ln. In this regard, nitrogen extractants are under study. Their selectivity toward actinides is still unclear, but could be the result of enhanced covalency effects with trivalent minor actinides with respect to lanthanides (III). In this thesis, we have performed DFT calculations (Density Functional Theory) to study covalency effects within the actinide-ligand bond, following three main axes of research: advanced study of the nature of the chemical bonding, spectroscopic characterization of covalency, and preliminary tests of ab initio molecular dynamics for future calculations in solvent. Methods that are not regularly applied to trivalent actinides complexes have been used: topological methods, TDDFT, LDDFT, ab initio molecular dynamics. We have managed to show that the selectivity of the BTP ligand - the most effective An/Ln extractant to date - comes at least for a part from stronger covalency effects within the An-BTP bond with respect to the Ln-BTP bond, which has never been proved before. (author)

  10. Workshop on the applications of new computer tools to thermal engineering; Applications a la thermique des nouveaux outils informatiques

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-31

    This workshop on the applications of new computer tools to thermal engineering has been organized by the French society of thermal engineers. Seven papers have been presented, from which two papers dealing with thermal diffusivity measurements in materials and with the optimization of dryers have been selected for ETDE. (J.S.)

  11. Developments based on stochastic and determinist methods for studying complex nuclear systems; Developpements utilisant des methodes stochastiques et deterministes pour l'analyse de systemes nucleaires complexes

    Energy Technology Data Exchange (ETDEWEB)

    Giffard, F.X

    2000-05-19

    In the field of reactor and fuel cycle physics, particle transport plays and important role. Neutronic design, operation and evaluation calculations of nuclear system make use of large and powerful computer codes. However, current limitations in terms of computer resources make it necessary to introduce simplifications and approximations in order to keep calculation time and cost within reasonable limits. Two different types of methods are available in these codes. The first one is the deterministic method, which is applicable in most practical cases but requires approximations. The other method is the Monte Carlo method, which does not make these approximations but which generally requires exceedingly long running times. The main motivation of this work is to investigate the possibility of a combined use of the two methods in such a way as to retain their advantages while avoiding their drawbacks. Our work has mainly focused on the speed-up of 3-D continuous energy Monte Carlo calculations (TRIPOLI-4 code) by means of an optimized biasing scheme derived from importance maps obtained from the deterministic code ERANOS. The application of this method to two different practical shielding-type problems has demonstrated its efficiency: speed-up factors of 100 have been reached. In addition, the method offers the advantage of being easily implemented as it is not very to the choice of the importance mesh grid. It has also been demonstrated that significant speed-ups can be achieved by this method in the case of coupled neutron-gamma transport problems, provided that the interdependence of the neutron and photon importance maps is taken into account. Complementary studies are necessary to tackle a problem brought out by this work, namely undesirable jumps in the Monte Carlo variance estimates. (author)

  12. Developments based on stochastic and determinist methods for studying complex nuclear systems; Developpements utilisant des methodes stochastiques et deterministes pour l'analyse de systemes nucleaires complexes

    Energy Technology Data Exchange (ETDEWEB)

    Giffard, F X

    2000-05-19

    In the field of reactor and fuel cycle physics, particle transport plays and important role. Neutronic design, operation and evaluation calculations of nuclear system make use of large and powerful computer codes. However, current limitations in terms of computer resources make it necessary to introduce simplifications and approximations in order to keep calculation time and cost within reasonable limits. Two different types of methods are available in these codes. The first one is the deterministic method, which is applicable in most practical cases but requires approximations. The other method is the Monte Carlo method, which does not make these approximations but which generally requires exceedingly long running times. The main motivation of this work is to investigate the possibility of a combined use of the two methods in such a way as to retain their advantages while avoiding their drawbacks. Our work has mainly focused on the speed-up of 3-D continuous energy Monte Carlo calculations (TRIPOLI-4 code) by means of an optimized biasing scheme derived from importance maps obtained from the deterministic code ERANOS. The application of this method to two different practical shielding-type problems has demonstrated its efficiency: speed-up factors of 100 have been reached. In addition, the method offers the advantage of being easily implemented as it is not very to the choice of the importance mesh grid. It has also been demonstrated that significant speed-ups can be achieved by this method in the case of coupled neutron-gamma transport problems, provided that the interdependence of the neutron and photon importance maps is taken into account. Complementary studies are necessary to tackle a problem brought out by this work, namely undesirable jumps in the Monte Carlo variance estimates. (author)

  13. Fundamental study of ionization and dissociation processes caused by electron impact in aromatic molecules; application of the quasi-equilibrium theory to phenanthrene and to methylphenanthrenes; Etudes fondamentales des processus d'ionisation et de dissociation des molecules aromatiques par impact electronique et application de la theorie du quasi-equilibre au phenanthrene et aux methyl-phenanthrenes

    Energy Technology Data Exchange (ETDEWEB)

    Nounou, P [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    pas moins l'interet que presentait l'application de cette theorie a de grosses molecules aromatiques. De plus, les resultats auxquels aboutit ce travail donnent d'interessants renseignements sur le comportement des composes etudies vis-a-vis des radiations ionisantes. (auteur)

  14. Le management des risques de l'entreprise cadre de référence, techniques d'application

    CERN Document Server

    Committee of sponsoring organizations of the Treadway commission (Etats-Unis)

    2005-01-01

    Traduction en français du second rapport COSO, ce livre est un véritable outil pour les dirigeants confrontés à la complexité opérationnelle du management des risques. Adaptable à toutes les organisations, il constitue un socle méthodologique indispensable pour tous les professionnels de la gestion des risques ainsi que pour les auditeurs et consultants internes et externes. Il est également un manuel incontournable pour les étudiants et les enseignants. Dans un environnement économique fortement concurrentiel et en constante évolution, cet ouvrage ne s'intéresse pas uniquement à la gestion des risques mais contribue aussi à identifier puis exploiter les opportunités nouvelles, source d'avantages concurrentiels.

  15. Image processing. A system for the automatic sorting of chromosomes; Traitement d'images - Applications au classement des chromosomes

    Energy Technology Data Exchange (ETDEWEB)

    Najai, Amor

    1977-05-27

    The present paper deals with two aspects of the system: - an automata (specialized hardware) dedicated to image processing. Images are digitized, divided into sub-units and computations are carried out on their main parameters. - A software for the automatic recognition and sorting of chromosomes is implemented on a Multi-20 minicomputer, connected to the automata. (author) [French] Nous decrivons un systeme automatique de classification de chromosomes. Il se compose de: - l'A.S.T.I., Automate Specialise de Traitement d'Images permettant de numeriser celles-ci, d'isoler des sous-images, d'effectuer des calculs sur leurs parametres principaux. - Un programme de reconnaissance et de classification automatique des chromosomes implante sur un mini-ordinateur MULTI-20, couple a l'A.S.T.I. (auteur)

  16. Characterization of complex networks : Application to robustness analysis

    NARCIS (Netherlands)

    Jamakovic, A.

    2008-01-01

    This thesis focuses on the topological characterization of complex networks. It specifically focuses on those elementary graph measures that are of interest when quantifying topology-related aspects of the robustness of complex networks. This thesis makes the following contributions to the field of

  17. Protein complex finding and ranking: An application to Alzheimer's

    Indian Academy of Sciences (India)

    Protein complexes are known to play a major role in controlling cellular activity in a living being. Identifying complexesfrom raw protein–protein interactions (PPIs) is an important area of research. Earlier work has been limited mostly to yeastand a few other model organisms. Such protein complex identification methods, ...

  18. Principle of the determination of neutron multiplication coefficients by the Monte Carlo method. Application. Description of a code for ibm 360-75; Principe de la determination des coefficients de multiplication neutronique par methode de Monte-Carlo. Application. Description d'un code pour IBM 360-75

    Energy Technology Data Exchange (ETDEWEB)

    Moreau, J; Parisot, B [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    The determination of neutron multiplication coefficients by the Monte Carlo method can be carried out in different ways; the are first examined particularly complex geometries; it makes use of multi-group isotropic cross sections. The performances of this code are illustrated by some examples. (author) [French] La determination des coefficients de multiplication neutronique par methode de Monte Carlo peut se faire par differentes voies, elles sont successivement examinees et comparees. On en deduit un code rapide pour des geometries particulierement complexes, il utilise des sections efficaces multigroupes isotropes. Les performances de ce code sont demontrees par quelques exemples. (auteur)

  19. Possibilities of gas-phase radio-chromatography application to permanent-gas analysis; Possibilites de la radiochromatographie en phase gazeuse applications a l'analyse des gaz permanents

    Energy Technology Data Exchange (ETDEWEB)

    Dupuis, M C; Charrier, G; Alba, C; Massimino, D [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes

    1970-07-01

    The gas-phase radio-chromatography technique has been applied to the rapid analysis of permanent gases (H{sub 2}, O{sub 2}, N{sub 2}, A, Kr, Xe, CO, CH{sub 4}) labelled with radioactive indicators ({sup 3}H, {sup 37}A, {sup 85}Kr, {sup 133}Xe). After calibration, the components of such a mixture can be identified and their concentrations measured in less than two hours, using a sample volume of from 0.1 to 10 cm{sup 3}. The minimum detectable activity is of the order of 10{sup -4} {mu}C for each radioactive isotope. The measurements are reproducible to about 2 to 3 per cent. This work has been mainly concerned with the influence of parameters affecting the response of the radioactivity detector (ionization chamber or gas flow proportional counter). The method has very numerous applications both theoretically, for the study of chromatographic phenomena under ideal conditions (infinitesimal concentrations made possible by the use of radioactive tracers), and practically, for rapid and accurate radiochemical analysis of radioactive gas mixtures. (authors) [French] La technique de radiochromatographie en phase gazeuse est appliquee a l'analyse rapide de gaz permanents (H{sub 2}, O{sub 2}, N{sub 2}, A, Kr, Xe, CO, CH{sub 4}) marques par des indicateurs radioactifs ({sup 3}H, {sup 37}A, {sup 85}Kr, {sup 133}Xe). Apres etalonnage, l'identification et la mesure des concentrations des constituants d'un tel melange requierent moins de deux heures, sur un volume d'echantillon de 0.1 a 10 cm{sup 3}. L'activite minimum detectable est de l'ordre de 10{sup -4} {mu}C pour chaque isotope radioactif. La reproductibilite des mesures est de l'ordre de 2 a 3 pour cent. L'etude porte principalement sur l'influence des parametres affectant la reponse du detecteur de radioactivite (chambre d'ionisation, ou compteur proportionnel a circulation). La methode est extremement fertile en applications tant sur le plan theorique pour l'etude du phenomene chromatographique dans les conditions

  20. Possibilities of gas-phase radio-chromatography application to permanent-gas analysis; Possibilites de la radiochromatographie en phase gazeuse applications a l'analyse des gaz permanents

    Energy Technology Data Exchange (ETDEWEB)

    Dupuis, M.C.; Charrier, G.; Alba, C.; Massimino, D. [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes

    1970-07-01

    The gas-phase radio-chromatography technique has been applied to the rapid analysis of permanent gases (H{sub 2}, O{sub 2}, N{sub 2}, A, Kr, Xe, CO, CH{sub 4}) labelled with radioactive indicators ({sup 3}H, {sup 37}A, {sup 85}Kr, {sup 133}Xe). After calibration, the components of such a mixture can be identified and their concentrations measured in less than two hours, using a sample volume of from 0.1 to 10 cm{sup 3}. The minimum detectable activity is of the order of 10{sup -4} {mu}C for each radioactive isotope. The measurements are reproducible to about 2 to 3 per cent. This work has been mainly concerned with the influence of parameters affecting the response of the radioactivity detector (ionization chamber or gas flow proportional counter). The method has very numerous applications both theoretically, for the study of chromatographic phenomena under ideal conditions (infinitesimal concentrations made possible by the use of radioactive tracers), and practically, for rapid and accurate radiochemical analysis of radioactive gas mixtures. (authors) [French] La technique de radiochromatographie en phase gazeuse est appliquee a l'analyse rapide de gaz permanents (H{sub 2}, O{sub 2}, N{sub 2}, A, Kr, Xe, CO, CH{sub 4}) marques par des indicateurs radioactifs ({sup 3}H, {sup 37}A, {sup 85}Kr, {sup 133}Xe). Apres etalonnage, l'identification et la mesure des concentrations des constituants d'un tel melange requierent moins de deux heures, sur un volume d'echantillon de 0.1 a 10 cm{sup 3}. L'activite minimum detectable est de l'ordre de 10{sup -4} {mu}C pour chaque isotope radioactif. La reproductibilite des mesures est de l'ordre de 2 a 3 pour cent. L'etude porte principalement sur l'influence des parametres affectant la reponse du detecteur de radioactivite (chambre d'ionisation, ou compteur proportionnel a circulation). La methode est extremement fertile en applications tant sur le plan theorique pour l

  1. Group 4 Metalloporphyrin diolato Complexes and Catalytic Application of Metalloporphyrins and Related Transition Metal Complexes

    Energy Technology Data Exchange (ETDEWEB)

    Du, Guodong [Iowa State Univ., Ames, IA (United States)

    2003-01-01

    In this work, the first examples of group 4 metalloporphyrin 1,2-diolato complexes were synthesized through a number of strategies. In general, treatment of imido metalloporphyrin complexes, (TTP)M=NR, (M = Ti, Zr, Hf), with vicinal diols led to the formation of a series of diolato complexes. Alternatively, the chelating pinacolate complexes could be prepared by metathesis of (TTP)MCl2 (M = Ti, Hf) with disodium pinacolate. These complexes were found to undergo C-C cleavage reactions to produce organic carbonyl compounds. For titanium porphyrins, treatment of a titanium(II) alkyne adduct, (TTP)Ti(η2-PhC≡CPh), with aromatic aldehydes or aryl ketones resulted in reductive coupling of the carbonyl groups to produce the corresponding diolato complexes. Aliphatic aldehydes or ketones were not reactive towards (TTP)Ti(η2-PhC≡CPh). However, these carbonyl compounds could be incorporated into a diolato complex on reaction with a reactive precursor, (TTP)Ti[O(Ph)2C(Ph)2O] to provide unsymmetrical diolato complexes via cross coupling reactions. In addition, an enediolato complex (TTP)Ti(OCPhCPhO) was obtained from the reaction of (TTP)Ti(η2-PhC≡CPh) with benzoin. Titanium porphyrin diolato complexes were found to be intermediates in the (TTP)Ti=O-catalyzed cleavage reactions of vicinal diols, in which atmospheric oxygen was the oxidant. Furthermore, (TTP)Ti=O was capable of catalyzing the oxidation of benzyl alcohol and α-hydroxy ketones to benzaldehyde and α-diketones, respectively. Other high valent metalloporphyrin complexes also can catalyze the oxidative diol cleavage and the benzyl alcohol oxidation reactions with dioxygen. A comparison of Ti(IV) and Sn(IV) porphyrin chemistry was undertaken. While chelated diolato complexes were invariably obtained for titanium porphyrins on treatment with 1,2-diols, the reaction of vicinal diols with tin porphyrins gave a number of products, including mono

  2. Applications of Computer Technology in Complex Craniofacial Reconstruction

    Directory of Open Access Journals (Sweden)

    Kristopher M. Day, MD

    2018-03-01

    Conclusion:. Modern 3D technology allows the surgeon to better analyze complex craniofacial deformities, precisely plan surgical correction with computer simulation of results, customize osteotomies, plan distractions, and print 3DPCI, as needed. The use of advanced 3D computer technology can be applied safely and potentially improve aesthetic and functional outcomes after complex craniofacial reconstruction. These techniques warrant further study and may be reproducible in various centers of care.

  3. Terpyridine and Quaterpyridine Complexes as Sensitizers for Photovoltaic Applications

    Directory of Open Access Journals (Sweden)

    Davide Saccone

    2016-02-01

    Full Text Available Terpyridine and quaterpyridine-based complexes allow wide light harvesting of the solar spectrum. Terpyridines, with respect to bipyridines, allow for achieving metal-complexes with lower band gaps in the metal-to-ligand transition (MLCT, thus providing a better absorption at lower energy wavelengths resulting in an enhancement of the solar light-harvesting ability. Despite the wider absorption of the first tricarboxylate terpyridyl ligand-based complex, Black Dye (BD, dye-sensitized solar cell (DSC performances are lower if compared with N719 or other optimized bipyridine-based complexes. To further improve BD performances several modifications have been carried out in recent years affecting each component of the complexes: terpyridines have been replaced by quaterpyridines; other metals were used instead of ruthenium, and thiocyanates have been replaced by different pinchers in order to achieve cyclometalated or heteroleptic complexes. The review provides a summary on design strategies, main synthetic routes, optical and photovoltaic properties of terpyridine and quaterpyridine ligands applied to photovoltaic, and focuses on n-type DSCs.

  4. Light cones in relativity: Real, complex, and virtual, with applications

    International Nuclear Information System (INIS)

    Adamo, T. M.; Newman, E. T.

    2011-01-01

    We study geometric structures associated with shear-free null geodesic congruences in Minkowski space-time and asymptotically shear-free null geodesic congruences in asymptotically flat space-times. We show how in both the flat and asymptotically flat settings, complexified future null infinity I C + acts as a ''holographic screen,'' interpolating between two dual descriptions of the null geodesic congruence. One description constructs a complex null geodesic congruence in a complex space-time whose source is a complex worldline, a virtual source as viewed from the holographic screen. This complex null geodesic congruence intersects the real asymptotic boundary when its source lies on a particular open-string type structure in the complex space-time. The other description constructs a real, twisting, shear-free or asymptotically shear-free null geodesic congruence in the real space-time, whose source (at least in Minkowski space) is in general a closed-string structure: the caustic set of the congruence. Finally we show that virtually all of the interior space-time physical quantities that are identified at null infinity I + (center of mass, spin, angular momentum, linear momentum, and force) are given kinematic meaning and dynamical descriptions in terms of the complex worldline.

  5. Energetic lanthanide complexes: coordination chemistry and explosives applications

    International Nuclear Information System (INIS)

    Manner, V W; Barker, B J; Sanders, V E; Laintz, K E; Scott, B L; Preston, D N; Sandstrom, M; Reardon, B L

    2014-01-01

    Metals are generally added to organic molecular explosives in a heterogeneous composite to improve overall heat and energy release. In order to avoid creating a mixture that can vary in homogeneity, energetic organic molecules can be directly bonded to high molecular weight metals, forming a single metal complex with Angstrom-scale separation between the metal and the explosive. To probe the relationship between the structural properties of metal complexes and explosive performance, a new series of energetic lanthanide complexes has been prepared using energetic ligands such as NTO (5-nitro-2,4-dihydro-1,2,4-triazole-3-one). These are the first examples of lanthanide NTO complexes where no water is coordinated to the metal, demonstrating novel control of the coordination environment. The complexes have been characterized by X-ray crystallography, NMR and IR spectroscopies, photoluminescence, and sensitivity testing. The structural and energetic properties are discussed in the context of enhanced blast effects and detection. Cheetah calculations have been performed to fine-tune physical properties, creating a systematic method for producing explosives with 'tailor made' characteristics. These new complexes will be benchmarks for further study in the field of metalized high explosives.

  6. Additional application areas of the 3D process information display; Weiterfuehrende Einsatzgebiete des 3-D-Prozessinformationsdisplays

    Energy Technology Data Exchange (ETDEWEB)

    Meissner, K. [Institut fuer Automatisierung und Informatik GmbH, Zentrum fuer industrielle Forschung und Entwicklung, Wernigerode (Germany); Hensel, H. [Hochschule Harz, Fachbereich Automatisierung und Informatik, Wernigerode (Germany)

    2007-07-01

    The current technological progress in the process industry results in a significant increase of the complexity of control systems. The amount of supervised information grows constantly for each operator because of a higher level of automation and an optimized information acquisition of the control systems. This development results in a cognitive overload of the operator which causes incorrect behaviour and responses in alert situations. In technical literature, several approaches are discussed to counteract this problem. This paper presents the newly developed 3-D Process Information Display (3D-PID) and describes which additional application areas as a primary representation method to the supervision of complex process conditions are imaginable. The 3D-PID is based on a cognitive scenic representation of the process values within a 3-D process room. Particularly the problem of the overview and detail presentation known from the literature is discussed. (orig.)

  7. Where to from here? Future applications of mental models of complex performance

    International Nuclear Information System (INIS)

    Hahn, H.A.; Nelson, W.R.; Blackman, H.S.

    1988-01-01

    The purpose of this paper is to raise issues for discussion regarding the applications of mental models in the study of complex performance. Applications for training, expert systems and decision aids, job selection, workstation design, and other complex environments are considered. 1 ref

  8. Corrosion in the presence of a complexing agent - application to the continuous determination of hydrofluoric acid in the atmosphere; Corrosion en presence de complexant. - Application a la determination en continu de l'acide fluorhydrique dans l'atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Chapron, J. [Commissariat a l' Energie Atomique, Centre d' Etudes Nucleaires de Fontenay-aux-Roses, 92 (France)

    1966-10-01

    After a presentation of the thermodynamics and kinetics involved during corrosion in the presence of a complexing agent, the first part of this report deals with the electrochemical properties of an aluminium electrode in the presence of fluoride solutions. Various physical and chemical parameters have been studied together with their influence on the aforementioned properties. From this first part are deduced the medium and the various parameters which lead to the maximum efficiency for the detection of fluorides by amperometry. The second part is an application of the results of the above work, which has made it possible to develop a cell having an original design. Its performances are described. They show that the cell has a greater sensitivity and a shorter response time than existing equipment. (author) [French] Apres un rappel sur la thermodynamique et la cinetique de la corrosion en presence de complexant, la premiere partie du memoire est consacree a l'etude des proprietes electrochimiques de l'electrode d'aluminium, en presence de solutions de fluorure. Differents parametres physiques et chimiques ont ete etudies ainsi que leurs influences sur les dites proprietes. De cette premiere partie on en a deduit le milieu et les divers parametres a fixer de facon a obtenir un rendement optimum au vue de la detection des fluorures par amperometrie. La deuxieme partie, qui est l'application des renseignements tires du travail deja cite, a permis de mettre au point une cellule de conception nouvelle. Ses performances sont decrites. Elles indiquent une sensibilite plus grande, un temps de reponse plus court que les appareils existants. (auteur)

  9. Preparation, description and properties of {sup 3}H- DNA - {sup 131}I-ribonuclease complexes; Preparation, caracterisation et proprietes des complexes ADN{sup 3}H - RNase {sup 131}I

    Energy Technology Data Exchange (ETDEWEB)

    Tshitenge, G. [Centre nucléaire TRICO, Kinshasa (Congo, The Democratic Republic of the); Ledoux, L. [Centre d’étude de l' énergie nucléaire Mol (Belgium)

    1970-01-15

    Bacterial DNA, both radioactive and non-radioactive, and pancreatic ribonuclease labelled with iodine-131 are mixed together at a high ion strength and neutral pH. They are then dialysed against 0.009M sodium chloride. During dialysis a precipitate is formed, which is then separated with a centrifuge and redissolved at a neutral pH in a 0.1M phosphate buffer solution, or in 0.15M sodium chloride and 0.015M sodium citrate solution adjusted to pH 7. This solution is then analysed: (1) by DEAE-cellulose paper chromatography using a centrifuge; (2) by sedimentation of caesium chloride along a gradient; (3) by electrophoresis in agar gel. The results obtained show that a stable complex is formed between the DNA and ribonuclease. The properties of this complex are such that it can be compared with natural nucleoproteins. (author) [French] Des ADN bactériens radioactifs ou non et de la ribonucléase pancréatique marquée a l'iode-131 sont mélangés, à force ionique élevée et à pH neutre. Ils sont ensuite dialyses contre du NaCl 0.009M. Au cours de cette dialyse, un précipité se forme. Ce précipité est séparé par centrifugation et redissous à pH neutre dans du tampon phosphate 0,1M, ou dans une solution 0.015M en citrate de Na et 0,15M en NaCl ajustée à pH 7. Cette solution a été analysée: 1) par Chromatographie centrifugée sur pulpe de papier de DEAE- cellulose; 2) par sédimentation en gradient de CsCl; 3) par électrophorèse en gel d'agar. Les résultats obtenus montrent qu'un complexe stable sfest formé entre l'ADN et la RNase. Les propriétés de ce complexe permettent de le comparer aux nucléoprotéines naturelles. (author)

  10. Synthesis, crystal structure and applications of palladium thiosalicylate complexes

    Directory of Open Access Journals (Sweden)

    S.B. Moosun

    2017-05-01

    Full Text Available Three palladium thiosalicylate complexes [Pd(tb(bipy]·3H2O (1, [Pd2(tb2(bipy2]·(dtdb2 (2 and [Pd2(tb2(phen2]·dtdb·H2O (3 (bipy = bipyridine; phen = phenanthroline were prepared from the reaction of PdCl2(CH3CN2 with dithiosalicylic acid (dtdb which underwent cleavage to form thiobenzoate anion (tb in DMF/MeOH. Square planar geometries of the complexes with a N2SO coordination type were proposed on the basis of single crystal X-ray structural study. The presence of trapped and uncoordinated dtdb was observed in complexes 2 and 3. Complexes 1–3 were evaluated as catalysts for Heck coupling reactions of methyl acrylate with iodobenzene, and showed moderate activities at a very low catalyst loading. Complex 1 was found to inhibit the growth of bacteria and scavenge free radicals efficiently.

  11. Clinical applications of proton magnetic resonance spectroscopy of the brain; Klinische Anwendungen der Protonen-Magnetresonanzspektroskopie des Gehirns

    Energy Technology Data Exchange (ETDEWEB)

    Laubenberger, J.; Bayer, S.; Thiel, T.; Hennig, J.; Langer, M. [Radiologische Universitaetsklinik Freiburg (Germany). Abt. Roentgendiagnostik

    1998-06-01

    In spite of all the scientific advances of the past few years, proton magnetic resonance spectroscopy of the brain has not attained the status of a routine examination technique with clinically accepted indications. The method should be considered as an additional option to MR imaging for inherited and acquired encephalopathic changes as well as, in future, for localization diagnosis of epilepsies. A proton magnetic resonance spectroscopic investigation without a prior intensive clinical and imaging investigation is not useful. Above all, factors influencing metabolite distribution such as for example, serum osmolability must be known. Methodological prerequisites for the clinical application of proton resonance spectroscopy are, first of all, a high stability of the chosen technique as well as a sufficiently certain quantification of metabolites and the availability of a reference group. The use of short echo times is necessary for the quantification of glutamine and the osmolyte myo-inositol. Indications for individual cases in which clinical investigations and MR topography cannot provide sufficient certainty and spectroscopy can furnish additional information are, in addition to uses in neuropediatrics, the suspicion of Alzheimer`s dementia, HIV encephalopathy in early manifestations, and unclarified depressions of consciousness accompanying liver cirrhosis. (orig.) [Deutsch] Die Protonen-Magnetresonanzspektroskopie des Gehirns ist trotz aller wissenschaftlicher Fortschritte der letzten Jahre noch nicht zu einer Routineuntersuchung mit anerkannter klinischer Indikationsstellung geworden. Die Untersuchung muss bei angeborenen und erworbenen enzephalopathischen Veraenderungen sowie in Zukunft in der Lokalisationsdiagnostik von Epilepsien als Zusatzoption zur MR-Bildgebung erachtet werden. Eine protonenspektroskopische Untersuchung ohne ausgiebige klinische und bildgebende Basisuntersuchung ist nicht sinnvoll. Insbesondere muessen Einflussfaktoren, wie z

  12. Energetics and Defect Interactions of Complex Oxides for Energy Applications

    Science.gov (United States)

    Solomon, Jonathan Michael

    The goal of this dissertation is to employ computational methods to gain greater insights into the energetics and defect interactions of complex oxides that are relevant for today's energy challenges. To achieve this goal, the development of novel computational methodologies are required to handle complex systems, including systems containing nearly 650 ions and systems with tens of thousands of possible atomic configurations. The systems that are investigated in this dissertation are aliovalently doped lanthanum orthophosphate (LaPO4) due to its potential application as a proton conducting electrolyte for intermediate temperature fuel cells, and aliovalently doped uranium dioxide (UO2) due to its importance in nuclear fuel performance and disposal. First we undertake density-functional-theory (DFT) calculations on the relative energetics of pyrophosphate defects and protons in LaPO4, including their binding with divalent dopant cations. In particular, for supercell calculations with 1.85 mol% Sr doping, we investigate the dopant-binding energies for pyrophosphate defects to be 0.37 eV, which is comparable to the value of 0.34 eV calculated for proton-dopant binding energies in the same system. These results establish that dopant-defect interactions further stabilize proton incorporation, with the hydration enthalpies when the dopants are nearest and furthest from the protons and pyrophosphate defects being -1.66 eV and -1.37 eV, respectively. Even though our calculations show that dopant binding enhances the enthalpic favorability of proton incorporation, they also suggest that such binding is likely to substantially lower the kinetic rate of hydrolysis of pyrophosphate defects. We then shift our focus to solid solutions of fluorite-structured UO 2 with trivalent rare earth fission product cations (M3+=Y, La) using a combination of ionic pair potential and DFT based methods. Calculated enthalpies of formation with respect to constituent oxides show higher

  13. Big and complex data analysis methodologies and applications

    CERN Document Server

    2017-01-01

    This volume conveys some of the surprises, puzzles and success stories in high-dimensional and complex data analysis and related fields. Its peer-reviewed contributions showcase recent advances in variable selection, estimation and prediction strategies for a host of useful models, as well as essential new developments in the field. The continued and rapid advancement of modern technology now allows scientists to collect data of increasingly unprecedented size and complexity. Examples include epigenomic data, genomic data, proteomic data, high-resolution image data, high-frequency financial data, functional and longitudinal data, and network data. Simultaneous variable selection and estimation is one of the key statistical problems involved in analyzing such big and complex data. The purpose of this book is to stimulate research and foster interaction between researchers in the area of high-dimensional data analysis. More concretely, its goals are to: 1) highlight and expand the breadth of existing methods in...

  14. Homogeneous Catalysis with Metal Complexes Fundamentals and Applications

    CERN Document Server

    Duca, Gheorghe

    2012-01-01

    The book about homogeneous catalysis with metal complexes deals with the description of the reductive-oxidative, metal complexes  in a liquid phase (in polar solvents, mainly in water, and less in nonpolar solvents). The exceptional importance of the redox processes in chemical systems, in the reactions occuring in living organisms, the environmental processes, atmosphere, water, soil, and in industrial technologies (especially in food-processing industries) is discussed. The detailed practical aspects of the established regularities are explained for solving the specific practical tasks in various fields of industrial chemistry, biochemistry, medicine, analytical chemistry and ecological chemistry. The main scope of the book is the survey and systematization of the latest advances in homogeneous catalysis with metal complexes. It gives an overview of the research results and practical experience accumulated by the author during the last decade.

  15. Period mappings with applications to symplectic complex spaces

    CERN Document Server

    Kirschner, Tim

    2015-01-01

    Extending Griffiths’ classical theory of period mappings for compact Kähler manifolds, this book develops and applies a theory of period mappings of “Hodge-de Rham type” for families of open complex manifolds. The text consists of three parts. The first part develops the theory. The second part investigates the degeneration behavior of the relative Frölicher spectral sequence associated to a submersive morphism of complex manifolds. The third part applies the preceding material to the study of irreducible symplectic complex spaces. The latter notion generalizes the idea of an irreducible symplectic manifold, dubbed an irreducible hyperkähler manifold in differential geometry, to possibly singular spaces. The three parts of the work are of independent interest, but intertwine nicely.

  16. Ordinal optimization and its application to complex deterministic problems

    Science.gov (United States)

    Yang, Mike Shang-Yu

    1998-10-01

    We present in this thesis a new perspective to approach a general class of optimization problems characterized by large deterministic complexities. Many problems of real-world concerns today lack analyzable structures and almost always involve high level of difficulties and complexities in the evaluation process. Advances in computer technology allow us to build computer models to simulate the evaluation process through numerical means, but the burden of high complexities remains to tax the simulation with an exorbitant computing cost for each evaluation. Such a resource requirement makes local fine-tuning of a known design difficult under most circumstances, let alone global optimization. Kolmogorov equivalence of complexity and randomness in computation theory is introduced to resolve this difficulty by converting the complex deterministic model to a stochastic pseudo-model composed of a simple deterministic component and a white-noise like stochastic term. The resulting randomness is then dealt with by a noise-robust approach called Ordinal Optimization. Ordinal Optimization utilizes Goal Softening and Ordinal Comparison to achieve an efficient and quantifiable selection of designs in the initial search process. The approach is substantiated by a case study in the turbine blade manufacturing process. The problem involves the optimization of the manufacturing process of the integrally bladed rotor in the turbine engines of U.S. Air Force fighter jets. The intertwining interactions among the material, thermomechanical, and geometrical changes makes the current FEM approach prohibitively uneconomical in the optimization process. The generalized OO approach to complex deterministic problems is applied here with great success. Empirical results indicate a saving of nearly 95% in the computing cost.

  17. Contribution to the study of aerosol photometers, application to the measurement of filter efficiency; Contribution a l'etude des photometres a aerosols, application a la mesure de l'efficacite des filtres

    Energy Technology Data Exchange (ETDEWEB)

    Billard, F; Hadelaine, G

    1968-01-01

    The measurement of the quantity of diffused light by particulates in suspension in a gas allows to determine the concentration and the size of an aerosol. The aim of this work is to check the answer of the usual photometer in the laboratories, the Phoenix-Sinclair and the Royco-230. The minimum diameter of the particulates detected by these photometers is about 0.3 microns. [French] La mesure de la quantite de lumiere diffusee par des particules en suspension dans un gaz permet de determiner la concentration et les dimensions d'un aerosol. Le but de ce travail est de verifier la reponse du photometres d'usage courant dans les laboratoires, le Phoenix-Sinclair et le Royco-230. Le diametre minimum des particules detectees par ces photometres est d'environ 0, 3 microns. (auteurs)

  18. Complexity of Monadic inf-datalog. Application to temporal logic.

    OpenAIRE

    Foustoucos , Eugénie; Guessarian , Irene

    2003-01-01

    In [11] we defined Inf-Datalog and characterized the fragments of Monadic inf-Datalog that have the same expressive power as Modal Logic (resp. $CTL$, alternation-free Modal $\\mu$-calculus and Modal $\\mu$-calculus). We study here the time and space complexity of evaluation of Monadic inf-Datalog programs on finite models. We deduce a new unified proof that model checking has 1. linear data and program complexities (both in time and space) for $CTL$ and alternation-free Modal $\\mu$-calculus, a...

  19. Application of resistivity measurements to research on structural elements in the Nord-Limousin (France) uraniferous basin (1960); Application des mesures de resistivite a la recherche des elements structuraux dans le bassin uranifere du Nord-Limousin (France) (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Sarcia, J A; Bonnet, J; Combe, R [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    The authors discuss the difficulties encountered in the exploration of a typical deposit in the Nord-Limousin, using the resistivity measurement method. In the zone in question the over-thrust was very variable and difficult to predict. The uraniferous deposits had two types of aspect, the passage from one to the other being often very sudden: long thin veins without gangue; short and thick lens-shape deposits which were strongly contaminated by clay towards their edges. After several unsatisfactory attempts, the device known as the 'rectangular map' was adopted and gave an acceptable structural representation rapidly and cheaply. For the placing of the probes however, methods are required which are more refined and sensitive. It is in any case useless to expect to obtain a satisfactory representation and a sufficient accuracy using a single technique; especially in the region under consideration. (author) [French] Les auteurs exposent les difficultes rencontrees pour l'exploration, par la methode des mesures de resistivite, d'un gisement type du Nord-Limousin: il s'agissait d'une zone a recouvrement tres variable et difficilement previsible. Les occurences uraniferes y affectaient deux facies passant brutalement de l'un a l'autre: longs filonnets minces et sans gangue; lentilles courtes et puissantes avec alteration argileuses tres etendue aux epontes. Apres plusieurs essais peu satisfaisants, le dispositif dit 'carte des rectangles' a ete adopte pour obtenir rapidement et a bon compte un schema structural suffisant. Mais des methodes plus fines et plus sensibles sont necessaires pour guider l'implantation des sondages. Il est d'ailleurs vain d'esperer trouver a la fois la representativite d'ensemble et la precision, dans l'utilisation d'une seule technique, surtout dans la region envisagee. (auteur)

  20. Application of Microwave Irradiation to Rapid Organic Inclusion Complex

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    @@ Microwave irradiation has been used in chemical laboratories for moisture analysis and wet asking procedures of biological and geological materials for a number of years [1]. More recently the microwave irradiation also widely used for rapid organic synthesis [2]. However, there have not yet been any reports concerning the ultilisatioin of microwave ovens in the routine organic inclusion complex regularly in chemical research.

  1. Measuring viscosity with a levitating magnet: application to complex fluids

    International Nuclear Information System (INIS)

    Even, C; Bouquet, F; Deloche, B; Remond, J

    2009-01-01

    As an experimental project proposed to students in fourth year of university, a viscometer was developed, consisting of a small magnet levitating in a viscous fluid. The viscous force acting on the magnet is directly measured: viscosities in the range 10-10 6 mPa s are obtained. This experiment is used as an introduction to complex fluids and soft matter physics

  2. Application of functional derivatives to analysis of complex systems

    Czech Academy of Sciences Publication Activity Database

    Beran, Zdeněk; Čelikovský, Sergej

    2013-01-01

    Roč. 350, č. 10 (2013), s. 2982-2993 ISSN 0016-0032 R&D Projects: GA ČR GA13-20433S Institutional support: RVO:67985556 Keywords : complex systems * linear equation * modeling Subject RIV: BC - Control Systems Theory Impact factor: 2.260, year: 2013 http://library.utia.cas.cz/separaty/2013/TR/beran-0398123.pdf

  3. The detectability lemma and its applications to quantum Hamiltonian complexity

    International Nuclear Information System (INIS)

    Aharonov, Dorit; Arad, Itai; Vazirani, Umesh; Landau, Zeph

    2011-01-01

    Quantum Hamiltonian complexity, an emerging area at the intersection of condensed matter physics and quantum complexity theory, studies the properties of local Hamiltonians and their ground states. In this paper we focus on a seemingly specialized technical tool, the detectability lemma (DL), introduced in the context of the quantum PCP challenge (Aharonov et al 2009 arXiv:0811.3412), which is a major open question in quantum Hamiltonian complexity. We show that a reformulated version of the lemma is a versatile tool that can be used in place of the celebrated Lieb-Robinson (LR) bound to prove several important results in quantum Hamiltonian complexity. The resulting proofs are much simpler, more combinatorial and provide a plausible path toward tackling some fundamental open questions in Hamiltonian complexity. We provide an alternative simpler proof of the DL that removes a key restriction in the original statement (Aharonov et al 2009 arXiv:0811.3412), making it more suitable for the broader context of quantum Hamiltonian complexity. Specifically, we first use the DL to provide a one-page proof of Hastings' result that the correlations in the ground states of gapped Hamiltonians decay exponentially with distance (Hastings 2004 Phys. Rev. B 69 104431). We then apply the DL to derive a simpler and more intuitive proof of Hastings' seminal one-dimensional (1D) area law (Hastings 2007 J. Stat. Mech. (2007) P8024) (both these proofs are restricted to frustration-free systems). Proving the area law for two and higher dimensions is one of the most important open questions in the field of Hamiltonian complexity, and the combinatorial nature of the DL-based proof holds out hope for a possible generalization. Indeed, soon after the first publication of the methods presented here, they were applied to derive exponential improvements to Hastings' result (Arad et al 2011, Aharonov et al 2011) in the case of frustration-free 1D systems. Finally, we also provide a more general

  4. Contrôle hormonal des caractéristiques des fibres musculaires après la naissance

    OpenAIRE

    Cassar-Malek, Isabelle; Listrat, Anne; Picard, Brigitte

    1998-01-01

    Après la naissance, la croissance et les propriétés contractiles et métaboliques des fibres musculaires sont soumises à une régulation endocrinienne complexe. A l’exception des glucocorticoïdes, la plupart des hormones présente une action anabolique sur le tissu musculaire. Leur influence sur les caractéristiques des fibres est cependant très différente. Ainsi, les hormones somatotropes affectent peu la composition en fibres des muscles. La GH, comme l’IGF-1, régulerait cependant l’expression...

  5. Ingénierie systèmes basée sur les modèles appliquée à la gestion et l'intégration des données de conception et de simulation : application aux métiers d'intégration et de simulation de systèmes aéronautiques complexes

    OpenAIRE

    Vosgien , Thomas

    2015-01-01

    The aim of this doctoral thesis is to contribute to the facilitation of design, integration and simulation activities in the aeronautics industry, but more generally in the context of collaborative complex product development. This objective is expected to be achieved through the use and improvement of digital engineering capabilities. During the last decade, the Digital Mock-Up (DMU) – supported by Product Data Management (PDM) systems – became a key federating environment to exchange/share ...

  6. Lattice Boltzmann methods for complex micro-flows: applicability and limitations for practical applications

    Energy Technology Data Exchange (ETDEWEB)

    Suga, K, E-mail: suga@me.osakafu-u.ac.jp [Department of Mechanical Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531 (Japan)

    2013-06-15

    The extensive evaluation studies of the lattice Boltzmann method for micro-scale flows ({mu}-flow LBM) by the author's group are summarized. For the two-dimensional test cases, force-driven Poiseuille flows, Couette flows, a combined nanochannel flow, and flows in a nanochannel with a square- or triangular cylinder are discussed. The three-dimensional (3D) test cases are nano-mesh flows and a flow between 3D bumpy walls. The reference data for the complex test flow geometries are from the molecular dynamics simulations of the Lennard-Jones fluid by the author's group. The focused flows are mainly in the slip and a part of the transitional flow regimes at Kn < 1. The evaluated schemes of the {mu}-flow LBMs are the lattice Bhatnagar-Gross-Krook and the multiple-relaxation time LBMs with several boundary conditions and discrete velocity models. The effects of the discrete velocity models, the wall boundary conditions, the near-wall correction models of the molecular mean free path and the regularization process are discussed to confirm the applicability and the limitations of the {mu}-flow LBMs for complex flow geometries. (invited review)

  7. Lattice Boltzmann methods for complex micro-flows: applicability and limitations for practical applications

    International Nuclear Information System (INIS)

    Suga, K

    2013-01-01

    The extensive evaluation studies of the lattice Boltzmann method for micro-scale flows (μ-flow LBM) by the author's group are summarized. For the two-dimensional test cases, force-driven Poiseuille flows, Couette flows, a combined nanochannel flow, and flows in a nanochannel with a square- or triangular cylinder are discussed. The three-dimensional (3D) test cases are nano-mesh flows and a flow between 3D bumpy walls. The reference data for the complex test flow geometries are from the molecular dynamics simulations of the Lennard-Jones fluid by the author's group. The focused flows are mainly in the slip and a part of the transitional flow regimes at Kn < 1. The evaluated schemes of the μ-flow LBMs are the lattice Bhatnagar–Gross–Krook and the multiple-relaxation time LBMs with several boundary conditions and discrete velocity models. The effects of the discrete velocity models, the wall boundary conditions, the near-wall correction models of the molecular mean free path and the regularization process are discussed to confirm the applicability and the limitations of the μ-flow LBMs for complex flow geometries. (invited review)

  8. Administration et gestion des contrats XL

    CERN Document Server

    Senouf, J

    2000-01-01

    Les grands contrats de travaux génèrent un grand nombre de commandes (OSVC) passées par un grand nombre de responsables techniques. Ils sont généralement basés sur des bordereaux de prix associés à un éventail de conditions économiques adaptées aux besoins complexes et variés des multiples utilisateurs du CERN nécessitant des calculs sophistiqués. L'administration des commandes, le suivi des travaux et de la facturation doivent répondre aux besoins de tous les acteurs. Les responsables techniques doivent jouir de la plus large indépendance administrative dans le respect des règlements CERN et des conditions contractuelles. Le contrôle des métrés et décomptes doit être rigoureux et d'une traçabilité complète. L'utilisation des bases de données Oracle a déjà permis l'intégration des données administratives et techniques. Le Web nous invite à une communication totale et transparente entre les utilisateurs, les services techniques et les contractants. De nouveaux types de contrat so...

  9. Réseau des développeurs - logiciels d'exploitation libre pour ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Un atelier technique réunissant des utilisateurs, des développeurs et des promoteurs des logiciels libres sera organisé pour mettre au point une application prototype - des formulaires électroniques permettant de saisir des données au moyen d'un ANP puis de les transférer dans un ordinateur - pouvant combler les ...

  10. Coordinating complex decision support activities across distributed applications

    Science.gov (United States)

    Adler, Richard M.

    1994-01-01

    Knowledge-based technologies have been applied successfully to automate planning and scheduling in many problem domains. Automation of decision support can be increased further by integrating task-specific applications with supporting database systems, and by coordinating interactions between such tools to facilitate collaborative activities. Unfortunately, the technical obstacles that must be overcome to achieve this vision of transparent, cooperative problem-solving are daunting. Intelligent decision support tools are typically developed for standalone use, rely on incompatible, task-specific representational models and application programming interfaces (API's), and run on heterogeneous computing platforms. Getting such applications to interact freely calls for platform independent capabilities for distributed communication, as well as tools for mapping information across disparate representations. Symbiotics is developing a layered set of software tools (called NetWorks! for integrating and coordinating heterogeneous distributed applications. he top layer of tools consists of an extensible set of generic, programmable coordination services. Developers access these services via high-level API's to implement the desired interactions between distributed applications.

  11. Application of complexing agent for lanthanoides separation by solvent extraction

    International Nuclear Information System (INIS)

    Jedinakova, V.; Dvorak, Z.; Blazek, P.

    1988-01-01

    The general characteristics are given of extraction separation of lanthanides by liquid separation in the presence of complex forming agents and the effects are discussed of the composition of the liquid and organic phase on their selective separation. Simple expressions may be derived on the basis of stability constants, for predicting the effects of the applied complex forming agents. The validity of the proposed mathematical models was confronted with experimental data and the confrontation confirmed that they may be used for modelling real systems. The proesented method allows to simulate the refining process from the known relationship of D Mi/Ma =f(c ma o ). (author). 3 figs., 3 tabs., 11 refs

  12. Photochemical Approaches to Complex Chemotypes: Applications in Natural Product Synthesis

    Science.gov (United States)

    2016-01-01

    The use of photochemical transformations is a powerful strategy that allows for the formation of a high degree of molecular complexity from relatively simple building blocks in a single step. A central feature of all light-promoted transformations is the involvement of electronically excited states, generated upon absorption of photons. This produces transient reactive intermediates and significantly alters the reactivity of a chemical compound. The input of energy provided by light thus offers a means to produce strained and unique target compounds that cannot be assembled using thermal protocols. This review aims at highlighting photochemical transformations as a tool for rapidly accessing structurally and stereochemically diverse scaffolds. Synthetic designs based on photochemical transformations have the potential to afford complex polycyclic carbon skeletons with impressive efficiency, which are of high value in total synthesis. PMID:27120289

  13. Synthesis of conjugated polymers with complex architecture for photovoltaic applications

    DEFF Research Database (Denmark)

    Kiriy, Anton; Krebs, Frederik C

    2017-01-01

    A common approach to bulk heterojunction solar cells involves a “trialand- error” approach in finding optimal kinetically unstable morphologies. An alternative approach assumes the utilization of complex polymer architectures, such as donor–acceptor block copolymers. Because of a covalent preorga...... preorganization of the donor and acceptor components, these materials may form desirable morphologies at thermodynamic equilibrium. This chapter reviews synthetic approaches to such architectures and shows the first photovoltaic results....

  14. Iridium complexes for the application of photodynamic therapy

    Directory of Open Access Journals (Sweden)

    SHI Min

    2015-10-01

    Full Text Available Photodynamic therapy can destruct tumor cells by singlet oxygen which is generated via a photodynamic reaction of the photosensitizer under a specfic excitation wavelength.Due to the heavy atom effect of metal iridium,iridiumcomplexes are excited by suitable light and then reach their excited triple state through intersystem crossing.The excited iridium complexes transfer energy to oxygen molecules to produce singlet oxygen for photodynamic therapy.

  15. Fonctionnalisation de la bentonite traitement et applications à léxtraction des colorants et colorants pour mordants.

    OpenAIRE

    MOULESSEHOUL, Hidayet

    2015-01-01

    L'objectif de notre étude est d'améliorer les propriétés de désorption de la bentonite vis à vis les colorants qui sont classés parmi les plus toxiques. La première partie du travail concerne la préparation et la caractérisation des bentonites modifiées avec les sels de diphosphate (porte-parapluie)TPhPMB.

  16. Applications of Qualitative Microanalysis to the Determination of Secondary Species Associated with Uranium; Application de la microanalyse qualitative a la determination des especes secondaires d'uranium

    Energy Technology Data Exchange (ETDEWEB)

    Agrinier, H

    1959-02-01

    Microanalytical techniques are described which allow rapid determinations of secondary species associated with uranium. They consist in exposing the constituent elements of the ores by means of characteristic microchemical reactions. Because of their rapidity and the small amount of apparatus needed, these techniques can be used either in the field or in the laboratory. (author) [French] Les techniques de microanalyse decrites dans cet ouvrage permettent la determination rapide des especes secondaires d'uranium. Elles consistent a mettre en evidence les elements constitutifs des mineraux par des reactions microchimiques caracteristiques. En raison de leur rapidite et du peu de materiel qu'elles necessitent, ces techniques peuvent etre utilisees aussi bien sur le terrain qu'au laboratoire. (auteur)

  17. Time extrapolation of radiolytic degradation product kinetics: the case of polyurethane; Extrapolation dans le temps des cinetiques de production des produits de degradation radiolytique: application a un polyurethane

    Energy Technology Data Exchange (ETDEWEB)

    Dannoux, A

    2007-02-15

    The prediction of the environmental impact of organic materials in nuclear waste geological storage needs knowledge of radiolytic degradation mechanisms and kinetics in aerobic and anaerobic conditions. In this framework, the effect of high doses (> MGy) and the variation of dose rate have to be considered. The material studied is a polyurethane composed of polyether soft segment and aromatic hard segments. Mechanisms were built on the analysis of material submitted to irradiations of simulation (high energy electrons and gamma radiation) by FTIR spectroscopy and gaseous and liquid degradation products by gas mass spectrometry and size exclusion chromatography. The electron paramagnetic resonance study of radical process and the determination of oxygen consumption and gas formation radiolytic yields allowed us to acquire kinetic data and to estimate dose rate and high doses effects. The polyurethane radio-oxidation mainly concerns soft segments and induced cross-linkings and production by scissions of oxidised compounds (esters, alcohols, carboxylic acids). The kinetic of radical termination is rapid and the dose rate effect is limited. After 10 MGy, branching and scission reactions are in equilibrium and low molecular weight products accumulate. At last, the degradation products release in water is influenced by the oxidation rate and the temperature. After 10 MGy, the soluble fraction is stabilised at 25%. The water soluble products identified by electro-spray ionisation mass spectrometry (alcohols, aldehydes, carboxylic acids) potentially formed complexes with radionuclides. (author)

  18. Probes and their application to the study of H.F. plasmoids; Les sondes et leur application dans l'etude des plasmoides H.F

    Energy Technology Data Exchange (ETDEWEB)

    Brunet, A; Geller, R [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    In the first part of this paper, we study the single Langmuir probe and the double-probe method. In the second part, we describe the probe-technique in connection with R.F. plasmoids. (author) [French] Dans la premiere partie de cet article, nous rappelons les principes d'utilisation de la sonde simple de Langmuir ainsi que la methode de la sonde double. La seconde partie est consacree a la pratique des sondes dans l'etude des plasmoides H.F. (auteur)

  19. Green-emitting MADF complex for OLED applications

    Science.gov (United States)

    Klimes, Kody; Zhu, Zhi-Qiang; Holloway, Sean; Li, Jian

    2016-09-01

    In this article, we demonstrated an exceptional palladium complex that exhibits both phosphorescence and delayed fluorescence for use as an efficient emitter in OLEDs. Devices employing PdN3N achieved external quantum efficiencies in excess of 22% and remarkable device operational lifetime to 90% initial luminance estimated at over 30,000 h at a practical luminance of 100 cd/m2. Further tuning of the phosphorescent and delayed fluorescent emission should have a great impact in the development of efficient and stable emitters for deep blue or white OLEDs.

  20. Analysis and application of classification methods of complex carbonate reservoirs

    Science.gov (United States)

    Li, Xiongyan; Qin, Ruibao; Ping, Haitao; Wei, Dan; Liu, Xiaomei

    2018-06-01

    There are abundant carbonate reservoirs from the Cenozoic to Mesozoic era in the Middle East. Due to variation in sedimentary environment and diagenetic process of carbonate reservoirs, several porosity types coexist in carbonate reservoirs. As a result, because of the complex lithologies and pore types as well as the impact of microfractures, the pore structure is very complicated. Therefore, it is difficult to accurately calculate the reservoir parameters. In order to accurately evaluate carbonate reservoirs, based on the pore structure evaluation of carbonate reservoirs, the classification methods of carbonate reservoirs are analyzed based on capillary pressure curves and flow units. Based on the capillary pressure curves, although the carbonate reservoirs can be classified, the relationship between porosity and permeability after classification is not ideal. On the basis of the flow units, the high-precision functional relationship between porosity and permeability after classification can be established. Therefore, the carbonate reservoirs can be quantitatively evaluated based on the classification of flow units. In the dolomite reservoirs, the average absolute error of calculated permeability decreases from 15.13 to 7.44 mD. Similarly, the average absolute error of calculated permeability of limestone reservoirs is reduced from 20.33 to 7.37 mD. Only by accurately characterizing pore structures and classifying reservoir types, reservoir parameters could be calculated accurately. Therefore, characterizing pore structures and classifying reservoir types are very important to accurate evaluation of complex carbonate reservoirs in the Middle East.

  1. Contribution a la caracterisation des betons endommages par des methodes de l'acoustique non lineaire. Application a la reaction alcalis-silice

    Science.gov (United States)

    Kodjo, Apedovi

    The aim of this thesis is to contribute to the non-destructive characterization of concrete materials damaged by alkali-silica reaction (ASR). For this purpose, some nonlinear characterization techniques have been developed, as well as a nonlinear resonance test device. In order to optimize the sensitivity of the test device, the excitation module and signal processing have been improved. The nonlinear tests were conducted on seven samples of concrete damaged by ASR, three samples of concrete damaged by heat, three concrete samples damaged mechanically and three sound concrete samples. Since, nonlinear behaviour of the material is often attribute to its micro-defects hysteretic behaviour, it was shown at first that concrete damaged by ASR exhibits an hysteresis behaviour. To conduct this study, an acoustoelastic test was set, and then nonlinear resonance test device was used for characterizing sound concrete and concrete damaged by ASR. It was shown that the nonlinear technique can be used for characterizing the material without knowing its initial state, and also for detecting early damage in the reactive material. Studies were also carried out on the effect of moisture regarding the nonlinear parameters; they allowed understanding the low values of nonlinear parameters measured on concrete samples that were kept in high moisture conditions. In order to find a specific characteristic of damage caused by ASR, the viscosity of ASR gel was used. An approach, based on static creep analysis, performed on the material, while applying the nonlinear resonance technique. The spring-damping model of Maxwell was used for the interpretation of the results. Then, the creep time was analysed on samples damaged by ASR. It appears that the ASR gel increases the creep time. Finally, the limitations of the nonlinear resonance technique for in situ application have been explained and a new applicable nonlinear technique was initiated. This technique use an external source such as a

  2. Solvent purification using a current of water vapour. A continuous process applicable to chemical plants treating irradiated fuels; Purification des solvants par entrainement a la vapeur d'eau. Procede continu applicable aux usines chimiques de traitement des combustibles irradies

    Energy Technology Data Exchange (ETDEWEB)

    Auchapt, P R; Sautray, R R; Girard, B R [Commissariat a l' Energie Atomique, Centre de Production de Plutonium, Marcoule (France). Centre d' Etudes Nucleaires

    1964-07-01

    The pilot plant described in this report is intended for the continuous purification of the solvent used in the plutonium extraction plant at Marcoule, by separating the impurities (fission products). This physical separation is operated by carrying over in a water vapour stream. The contaminating products, only slightly volatile, remain in the form of the droplets and are separated; the vaporised solvent and the water vapour used are condensed and then separated. The originality of the installation resides in the system for pulverising the liquid and in the operating conditions: low working pressure and temperature. The systematic analysis of the various parameters (percentage of residue; flow, pressure and temperature ratios etc...) has shown their influence on the decontamination. The activity due to the zirconium-niobium is undetectable after treatment, and it is easy to obtain decontamination factors of 300 for the ruthenium. The, presence of uranium is favorable for the decontamination. As a conclusion, some extra-technical considerations are given concerning in particular the approximate cost price of the treated solvent per litre. (authors) [French] L'installation pilote decrite dans ce rapport est destinee a purifier, en continu, le solvant utilise a l'usine d'extraction du plutonium de Marcoule, en separant les impuretes (produits de fission). Cette separation physique est realisee par entrainement a la vapeur d'eau. Les produits contaminants, peu volatils, restant sous forme de gouttelettes, sont separes; le solvant vaporise ainsi que la vapeur d'entrainement sont condenses puis separes. L'originalite de l'installation reside dans le systeme de pulverisation du liquide et dans les conditions operatoires: faible pression et basse temperature de fonctionnement. L'analyse systematique des differents parametres (pourcentage de residus, rapport de debits, pression et temperature, etc...) a mis en evidence leur influence sur la decontamination. L'activite en

  3. Application of cerium(IV)/EDTA complex for future biotechnology

    International Nuclear Information System (INIS)

    Sumaoka, Jun; Chen Wen; Kitamura, Yoshihito; Tomita, Takafumi; Yoshida, Junya; Komiyama, Makoto

    2006-01-01

    A new artificial system for site-selective hydrolysis of single-stranded DNAs was prepared. By using two oligonucleotide additives that bear a monophosphate group at the termini, gap structures were formed at predetermined positions in substrate DNA. The phosphodiester linkages in the gap were efficiently and selectively hydrolyzed by Ce(IV)/EDTA complex (EDTA, ethylenediamine-N,N,N',N'-tetraacetate) at pH 7.0 and 37 deg. C. Furthermore, the fragments formed by the site-selective scission were connected with various oligonucleotides by using T4 DNA ligase, producing desired recombinant DNAs. A new tool for manipulation of single-stranded DNA in biotechnology has been successfully obtained

  4. Theory and Application of Photoelectron Diffraction for Complex Oxide Systems

    Science.gov (United States)

    Chassé, Angelika; Chassé, Thomas

    2018-06-01

    X-ray photoelectron diffraction (XPD) has been used to investigate film structures and local sites of surface and dopant atoms in complex oxide materials. We have performed angular-resolved measurements of intensity distribution curves (ADCs) and patterns (ADPs) of elemental core level intensities from binary to quaternary mixed oxide samples and compared them to multiple-scattering cluster (MSC) calculations in order to derive information on structural models and related parameters. MSC calculations permitted to describe both bulk diffraction features of binary oxide MnO(001) and the thickness-dependence of the tetragonal distortion of epitaxial MnO films on Ag(001). XPD was further used to investigate the surface termination of perovskite SrTiO3 and BaTiO3 substrates in order to evaluate influence of different ex situ and in situ preparation procedures on the surface layers, which are crucial for quality of following film growth. Despite the similarity of local environments of Sr (Ba) and Ti atoms in the perovskite film structure an angular region in the ADCs was identified as a fingerprint with the help of MSC simulations which provided clear conclusions on the perovskite oxide surfaces. Dopant sites in quaternary perovskite manganites La1-xCaxMnO3, La1-xSrxMnO3, and La1-xCexMnO3 were studied with polar angle scans of the photoemission intensities of host and dopant atoms. Both direct comparison of experimental ADCs and to the simulations within MSC models confirm the occupation of A sites by the dopants and the structural quality of the complex oxide films.

  5. How we are building a complex Angular 2 application at Inspire

    CERN Multimedia

    CERN. Geneva

    2017-01-01

    In this talk, at first we will talk about some basic and advanced Angular 2 concepts, then we will share our experiences with Angular 2 that we had so far while building a complex library and web applications at Inspire.

  6. Complex Problems in Entrepreneurship Education: Examining Complex Problem-Solving in the Application of Opportunity Identification

    Directory of Open Access Journals (Sweden)

    Yvette Baggen

    2017-01-01

    Full Text Available In opening up the black box of what entrepreneurship education (EE should be about, this study focuses on the exploration of relationships between two constructs: opportunity identification (OI and complex problem-solving (CPS. OI, as a domain-specific capability, is at the core of entrepreneurship research, whereas CPS is a more domain-general skill. On a conceptual level, there are reasons to believe that CPS skills can help individuals to identify potential opportunities in dynamic and nontransparent environments. Therefore, we empirically investigated whether CPS relates to OI among 113 masters students. Data is analyzed using multiple regressions. The results show that CPS predicts the number of concrete ideas that students generate, suggesting that having CPS skills supports the generation of detailed, potential business ideas of good quality. The results of the current study suggest that training CPS, as a more domain-general skill, could be a valuable part of what should be taught in EE.

  7. Complex Algebraic Varieties

    CERN Document Server

    Peternell, Thomas; Schneider, Michael; Schreyer, Frank-Olaf

    1992-01-01

    The Bayreuth meeting on "Complex Algebraic Varieties" focussed on the classification of algebraic varieties and topics such as vector bundles, Hodge theory and hermitian differential geometry. Most of the articles in this volume are closely related to talks given at the conference: all are original, fully refereed research articles. CONTENTS: A. Beauville: Annulation du H(1) pour les fibres en droites plats.- M. Beltrametti, A.J. Sommese, J.A. Wisniewski: Results on varieties with many lines and their applications to adjunction theory.- G. Bohnhorst, H. Spindler: The stability of certain vector bundles on P(n) .- F. Catanese, F. Tovena: Vector bundles, linear systems and extensions of (1).- O. Debarre: Vers uns stratification de l'espace des modules des varietes abeliennes principalement polarisees.- J.P. Demailly: Singular hermitian metrics on positive line bundles.- T. Fujita: On adjoint bundles of ample vector bundles.- Y. Kawamata: Moderate degenerations of algebraic surfaces.- U. Persson: Genus two fibra...

  8. Application of a Complex Lead Compensator for a Laser Guided Missile

    Science.gov (United States)

    Akhila, M. R.; Gopika, S.; Abraham, R. J.

    2013-01-01

    This paper discusses the application of a lead compensator with complex pole and complex zero for a missile. It is compared with a lead compensator with real pole and real zero. A typical laser guided missile control system is considered for the performance comparison of both the compensators. Simulation studies carried out with MATLAB brings out the scope of using complex compensator in missile guided systems.

  9. New possibilities of complex "Thermodyn" application for contactless remote diagnostics in medical practice

    Science.gov (United States)

    Belov, M. Ye.; Shayko-Shaykovskiy, O. G.; Makhrova, Ye. G.; Kramar, V. M.; Oleksuik, I. S.

    2018-01-01

    We represent here the theoretical justifications, block scheme and experimental sample of a new automated complex "Thermodyn" for remote contactless diagnostics of inflammatory processes of the surfaces and in subcutaneous areas of human body. Also we described here the methods and results of diagnostic measurements, and results of practical applications of this complex.

  10. Learning Science in a Virtual Reality Application: The Impacts of Animated-Virtual Actors' Visual Complexity

    Science.gov (United States)

    Kartiko, Iwan; Kavakli, Manolya; Cheng, Ken

    2010-01-01

    As the technology in computer graphics advances, Animated-Virtual Actors (AVAs) in Virtual Reality (VR) applications become increasingly rich and complex. Cognitive Theory of Multimedia Learning (CTML) suggests that complex visual materials could hinder novice learners from attending to the lesson properly. On the other hand, previous studies have…

  11. The application of value analysis techniques for complex problems

    International Nuclear Information System (INIS)

    Chiquelin, W.R.; Cossel, S.C.; De Jong, V.J.; Halverson, T.W.

    1986-01-01

    This paper discusses the application of the Value Analysis technique to the transuranic package transporter (TRUPACT). A team representing five different companies or organizations with diverse technical backgrounds was formed to analyze and recommend improvements. The results were a 38% systems-wide savings, if incorporated, and a shipping container which is volumetrically and payload efficient as well as user friendly. The Value Analysis technique is a proven tool widely used in many diverse areas both in the government and the private sector. Value Analysis uses functional diagramming of a piece of equipment or process to discretely identify every facet of the item being analyzed. A standard set of questions is then asked: What is it?, What does it do?, What does it cost?, What else will do the task?, and What would that cost? Using logic and a disciplined approach, the result of the Value Analysis performs the necessary functions at a high quality and the lowest overall cost

  12. Study and industrial applications of the external slowing-down {beta}{sup -} radiation of the yttrium - 90; Etude et applications industrielles du rayonnement de freinage externe des {beta}{sup -} de l'yttrium - 90

    Energy Technology Data Exchange (ETDEWEB)

    Leveque, P; Martinelli, P; Chauvin, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1955-07-01

    Inelastic scattering of the {beta}{sup -} particles on the nucleus gives place to the emission of a X-ray Bremsstrahlung radiation. In view of possible industrial applications, we studied the slowing-down radiation of {sup 90}(Sr + Y) sources in various materials. This pure {beta}{sup -} emitter of long period is in the fission products of uranium. Among of the industrial applications, these sources of weak X-rays energy can be used for the radiography of thin pieces, for measuring the thickness, or for the analysis by fluorescence. (M.B.) [French] La diffusion inelastique des particules {beta}{sup -} sur les noyaux donne lieu a l'emission d'un rayonnement X de freinage. En vue de possibles applications industrielles, nous avons etudie le rayonnement de freinage des sources {sup 90}(Sr + Y) dans divers materiaux. Cet emetteur {beta}{sup -} pur a longue periode se trouve dans les produits de fission de l'uranium. Parmi les applications industrielles a l'etude, ces sources de rayons X de faible energie peuvent etre utilisees pour la radiographie de pieces minces, la mesure d'epaisseurs, ou encore pour l'analyse par fluorescence. (M.B.)

  13. Étude du vieillissement des batteries lithium-ion dans les applications "véhicule électrique" : Combinaison des effets de vieillissement calendaire et de cyclage.

    OpenAIRE

    REDONDO-IGLESIAS, Eduardo

    2017-01-01

    L'étude du vieillissement des batteries est nécessaire car la dégradation de leurs caractéristiques détermine en grande partie le coût, les performances et l'impact environnemental des véhicules électrifiés, notamment des véhicules 100 % électriques. La méthodologie choisie pour cette thèse consiste en deux étapes bien différenciées, à savoir la caractérisation et la modélisation. Pour la première étape, on s'appuie sur des essais de vieillissement accéléré d'éléments de batterie. Malgré leur...

  14. Radio catalysis application in degradation of complex organic samples

    International Nuclear Information System (INIS)

    Moreno L, A.

    2014-01-01

    The generation of wastewater is a consequence of human activities, industries to be the generators of a large part of these discharges. These contaminated waters can be processed for their remediation; however the recalcitrant organic compounds are hardly removed through conventional treatments applied, so that new technologies have been developed for disposal such as the advanced oxidation technologies or processes. With the aim of the study is to apply ionizing radiation as a method of remediation in wastewater, in this work were carried out experiments of radiolysis and radio catalysis, which are techniques considered advanced oxidation technologies, that consist in irradiate with 60 Co gamma radiation solutions of 4- chloro phenol and methylene blue, applied at different concentrations and using as process control measurements of the compound not degraded by UV-vis spectrophotometry at 507 and 664 nm for 4-chloro phenol and methylene blue respectively. At doses greater than 2.5 kGy were near-zero degradation. Degradation experiments were also conducted by photo catalysis by irradiation with a UV lamp of 354 nm wavelength. For 4-chloro phenol results showed that degradation is efficient (39%). With those previous results, these techniques were applied to degrade complex mixtures of organic compounds from samples of wastewater from a sewage treatment plant, where was considered as process control measurement of the dissolved organic carbon obtained by a spectrophotometric analysis at 254 nm, and a maximum of 26% degradation was obtained by applying 80 kGy. On the other hand, a series of experiments fractionating the irradiations at intervals of 20 kGy to obtain a cumulative dose of 80 kGy, which was 2.8 times greater with respect to degradation by radio catalysis with continuous irradiation. (Author)

  15. Application of Lattice Boltzmann Methods in Complex Mass Transfer Systems

    Science.gov (United States)

    Sun, Ning

    Lattice Boltzmann Method (LBM) is a novel computational fluid dynamics method that can easily handle complex and dynamic boundaries, couple local or interfacial interactions/reactions, and be easily parallelized allowing for simulation of large systems. While most of the current studies in LBM mainly focus on fluid dynamics, however, the inherent power of this method makes it an ideal candidate for the study of mass transfer systems involving complex/dynamic microstructures and local reactions. In this thesis, LBM is introduced to be an alternative computational method for the study of electrochemical energy storage systems (Li-ion batteries (LIBs) and electric double layer capacitors (EDLCs)) and transdermal drug design on mesoscopic scale. Based on traditional LBM, the following in-depth studies have been carried out: (1) For EDLCs, the simulation of diffuse charge dynamics is carried out for both the charge and the discharge processes on 2D systems of complex random electrode geometries (pure random, random spheres and random fibers). Steric effect of concentrated solutions is considered by using modified Poisson-Nernst-Plank (MPNP) equations and compared with regular Poisson-Nernst-Plank (PNP) systems. The effects of electrode microstructures (electrode density, electrode filler morphology, filler size, etc.) on the net charge distribution and charge/discharge time are studied in detail. The influence of applied potential during discharging process is also discussed. (2) For the study of dendrite formation on the anode of LIBs, it is shown that the Lattice Boltzmann model can capture all the experimentally observed features of microstructure evolution at the anode, from smooth to mossy to dendritic. The mechanism of dendrite formation process in mesoscopic scale is discussed in detail and compared with the traditional Sand's time theories. It shows that dendrite formation is closely related to the inhomogeneous reactively at the electrode-electrolyte interface

  16. Optimization of the scintillation parameters of the lead tungstate crystals for their application in high precision electromagnetic calorimetry; Optimisation des parametres de scintillation des cristaux de tungstate de plomb pour leur application dans la calorimetrie electromagnetique de haute precision

    Energy Technology Data Exchange (ETDEWEB)

    Drobychev, G

    2000-04-12

    In the frame of this dissertation work scintillation properties of the lead tungstate crystals (PWO) and possibilities of their use were studied foreseeing their application for electromagnetic calorimetry in extreme radiation environment conditions of new colliders. The results of this work can be summarized in the following way. 1. A model of the scintillations origin in the lead tungstate crystals which includes processes influencing on the crystals radiation hardness and presence of slow components in scintillations was developed. 2. An analysis of the influences of the PWO scintillation properties changes on the parameters of the electromagnetic calorimeter was done. 3. Methods of the light collection from the large scintillation elements of complex shape made of the birefringent scintillation crystal with high refraction index and low light yield in case of signal registration by a photodetector with sensitive surface small in compare with the output face of scintillator were Studied. 4. Physical principles of the methodology of the scintillation crystals certification during their mass production foreseeing their installation into a calorimeter electromagnetic were developed. Correlations between the results of measurements of the PWO crystals parameters by different methods were found. (author)

  17. Complexity Science Applications to Dynamic Trajectory Management: Research Strategies

    Science.gov (United States)

    Sawhill, Bruce; Herriot, James; Holmes, Bruce J.; Alexandrov, Natalia

    2009-01-01

    The promise of the Next Generation Air Transportation System (NextGen) is strongly tied to the concept of trajectory-based operations in the national airspace system. Existing efforts to develop trajectory management concepts are largely focused on individual trajectories, optimized independently, then de-conflicted among each other, and individually re-optimized, as possible. The benefits in capacity, fuel, and time are valuable, though perhaps could be greater through alternative strategies. The concept of agent-based trajectories offers a strategy for automation of simultaneous multiple trajectory management. The anticipated result of the strategy would be dynamic management of multiple trajectories with interacting and interdependent outcomes that satisfy multiple, conflicting constraints. These constraints would include the business case for operators, the capacity case for the Air Navigation Service Provider (ANSP), and the environmental case for noise and emissions. The benefits in capacity, fuel, and time might be improved over those possible under individual trajectory management approaches. The proposed approach relies on computational agent-based modeling (ABM), combinatorial mathematics, as well as application of "traffic physics" concepts to the challenge, and modeling and simulation capabilities. The proposed strategy could support transforming air traffic control from managing individual aircraft behaviors to managing systemic behavior of air traffic in the NAS. A system built on the approach could provide the ability to know when regions of airspace approach being "full," that is, having non-viable local solution space for optimizing trajectories in advance.

  18. Easy access to heterobimetallic complexes for medical imaging applications via microwave-enhanced cycloaddition

    Directory of Open Access Journals (Sweden)

    Nicolas Desbois

    2015-11-01

    Full Text Available The Cu(I-catalysed Huisgen cycloaddition, known as “click” reaction, has been applied to the synthesis of a range of triazole-linked porphyrin/corrole to DOTA/NOTA derivatives. Microwave irradiation significantly accelerates the reaction. The synthesis of heterobimetallic complexes was easily achieved in up to 60% isolated yield. Heterobimetallic complexes were easily prepared as potential MRI/PET (SPECT bimodal contrast agents incorporating one metal (Mn, Gd for the enhancement of contrast for MRI applications and one “cold” metal (Cu, Ga, In for future radionuclear imaging applications. Preliminary relaxivity measurements showed that the reported complexes are promising contrast agents (CA in MRI.

  19. Application of statistical physics approaches to complex organizations

    Science.gov (United States)

    Matia, Kaushik

    The first part of this thesis studies two different kinds of financial markets, namely, the stock market and the commodity market. Stock price fluctuations display certain scale-free statistical features that are not unlike those found in strongly-interacting physical systems. The possibility that new insights can be gained using concepts and methods developed to understand scale-free physical phenomena has stimulated considerable research activity in the physics community. In the first part of this thesis a comparative study of stocks and commodities is performed in terms of probability density function and correlations of stock price fluctuations. It is found that the probability density of the stock price fluctuation has a power law functional form with an exponent 3, which is similar across different markets around the world. We present an autoregressive model to explain the origin of the power law functional form of the probability density function of the price fluctuation. The first part also presents the discovery of unique features of the Indian economy, which we find displays a scale-dependent probability density function. In the second part of this thesis we quantify the statistical properties of fluctuations of complex systems like business firms and world scientific publications. We analyze class size of these systems mentioned above where units agglomerate to form classes. We find that the width of the probability density function of growth rate decays with the class size as a power law with an exponent beta which is universal in the sense that beta is independent of the system studied. We also identify two other scaling exponents, gamma connecting the unit size to the class size and gamma connecting the number of units to the class size, where products are units and firms are classes. Finally we propose a generalized preferential attachment model to describe the class size distribution. This model is successful in explaining the growth rate and class

  20. ANALYSE DES PERCEPTIONS LOCALES ET DES FACTEURS ...

    African Journals Online (AJOL)

    AISA

    1Faculté des Sciences Agronomiques (FSA), Université d'Abomey-Calavi (UAC), 01 BP 526 Cotonou Bénin. Email : cgbemavo@yahoo.fr. 2Institut National des Recherches Agricoles du Bénin, Centre de Recherches Agricoles d'Agonkanmey (CRA-A),. Laboratoire des Sciences du Sol, Eau et Environnement (LSSEE).

  1. X-spectrographic method for plutonium detection. Application to contamination measurements in humans; Etude d'une methode de detection du plutonium par spectrographie X. Application a la mesure des contaminations sur l'homme

    Energy Technology Data Exchange (ETDEWEB)

    Trouble, Michel [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    After reviewing the radio-toxicology of plutonium 239 and conventional detection methods using its {alpha}-radiation, the author considers the measurement of the X emission spectrum of plutonium 239 using a proportional counter filled with argon under pressure. This preliminary work leads to the third part of this research involving the detailed study of the possibilities of applying thin alkali halide crystal scintillators to the detection of soft plutonium X-rays; there follows a systematic study of all the parameters liable to render the detection as sensitive as possible: movement due to the photomultiplier itself and its accessory electronic equipment, nature and size of the crystal scintillator as well as its mode of preparation, shielding against external parasitic radiation. Examples of some applications to the measurement of contamination in humans give an idea of the sensitivity of this method. (author) [French] Apres un apercu de la radiotoxicologie du plutonium 239 et des methodes classiques de detection par son rayonnement {alpha}, on etudie le spectre d'emission X du plutonium 239 avec un compteur proportionnel rempli avec de l'argon sous pression. Ce travail preliminaire permet d'aborder la troisieme partie de cette etude dans laquelle nous examinons d'une fagon approfondie les possibilites d'application des cristaux scintillateurs minces d'halogenure alcalin a la detection du rayonnement X mou du plutonium; suit une etude systematique de tous les parametres susceptibles de rendre la detection aussi sensible que possible: mouvement propre du photomultiplicateur et de l'electronique associee, nature et dimensions du cristal scintillateur ainsi que son mode de fabrication, blindage contre les rayonnements parasites exterieurs. Quelques applications a la mesure des contaminations sur l'homme permettent d'apprecier la sensibilite de cette methode. (auteur)

  2. utilisation des donnees pour l'evaluation de l'heterogeneite des sols

    African Journals Online (AJOL)

    AISA

    étude a permis de caractériser l'hétérogénéité des sols ferrallitiques, à travers sa couleur. Mots-clés : Couleur ... ainsi qu'à l'application des recommandations des doses de fertilisant. ..... de « système sol » en zone de contact forêt- savane du ...

  3. Homogenization of complex flows in porous media and applications

    International Nuclear Information System (INIS)

    Hutridurga-Ramaiah, Harsha

    2013-01-01

    Our work is a contribution to the understanding of transport of solutes in a porous medium. It has applications in groundwater contaminant transport, CO 2 sequestration, underground storage of nuclear waste, oil reservoir simulations. We derive expressions for the effective Taylor dispersion taking into account convection, diffusion, heterogeneous geometry of the porous medium and reaction phenomena. Microscopic phenomena at the pore scale are up-scaled to obtain effective behaviour at the observation scale. Method of two-scale convergence with drift from the theory of homogenization is employed as an up-scaling technique. In the first part of our work, we consider reactions of mass exchange type, adsorption/desorption, at the fluid-solid interface of the porous medium. Starting with coupled convection-diffusion equations for bulk and surface concentrations of a single solute, coupled via adsorption isotherms, at a microscopic scale we derive effective equations at the macroscopic scale. We consider the microscopic system with highly oscillating coefficients in a strong convection regime i.e., large Peclet regime. The presence of strong convection in the microscopic model leads to the induction of a large drift in the concentration profiles. Both linear and nonlinear adsorption isotherms are considered and the results are compared. In the second part of our work we generalize our results on single component flow to multicomponent flow in a linear setting. In the latter case, the effective parameters are obtained using Factorization principle and two-scale convergence with drift. The behaviour of effective parameters with respect to Peclet number and Damkohler number are numerically studied. Freefem++ is used to perform numerical tests in two dimensions. (author)

  4. Etude fondamentale des mecanismes de gravure par plasma de materiaux de pointe: Application a la fabrication de dispositifs photoniques

    Science.gov (United States)

    Stafford, Luc

    Advances in electronics and photonics critically depend upon plasma-based materials processing either for transferring small lithographic patterns into underlying materials (plasma etching) or for the growth of high-quality films. This thesis deals with the etching mechanisms of materials using high-density plasmas. The general objective of this work is to provide an original framework for the plasma-material interaction involved in the etching of advanced materials by putting the emphasis on complex oxides such as SrTiO3, (Ba,Sr)TiO 3 and SrBi2Ta2O9 films. Based on a synthesis of the descriptions proposed by different authors to explain the etching characteristics of simple materials in noble and halogenated plasma mixtures, we propose comprehensive rate models for physical and chemical plasma etching processes. These models have been successfully validated using experimental data published in literature for Si, Pt, W, SiO2 and ZnO. As an example, we have been able to adequately describe the simultaneous dependence of the etch rate on ion and reactive neutral fluxes and on the ion energy. From an exhaustive experimental investigation of the plasma and etching properties, we have also demonstrated that the validity of the proposed models can be extended to complex oxides such as SrTiO3, (Ba,Sr)TiO 3 and SrBi2Ta2O9 films. We also reported for the first time physical aspects involved in plasma etching such as the influence of the film microstructural properties on the sputter-etch rate and the influence of the positive ion composition on the ion-assisted desorption dynamics. Finally, we have used our deep investigation of the etching mechanisms of STO films and the resulting excellent control of the etch rate to fabricate a ridge waveguide for photonic device applications. Keywords: plasma etching, sputtering, adsorption and desorption dynamics, high-density plasmas, plasma diagnostics, advanced materials, photonic applications.

  5. Statistical methods for anomaly detection in the complex process; Methodes statistiques de detection d'anomalies de fonctionnement dans les processus complexes

    Energy Technology Data Exchange (ETDEWEB)

    Al Mouhamed, Mayez

    1977-09-15

    In a number of complex physical systems the accessible signals are often characterized by random fluctuations about a mean value. The fluctuations (signature) often transmit information about the state of the system that the mean value cannot predict. This study is undertaken to elaborate statistical methods of anomaly detection on the basis of signature analysis of the noise inherent in the process. The algorithm presented first learns the characteristics of normal operation of a complex process. Then it detects small deviations from the normal behavior. The algorithm can be implemented in a medium-sized computer for on line application. (author) [French] Dans de nombreux systemes physiques complexes les grandeurs accessibles a l'homme sont souvent caracterisees par des fluctuations aleatoires autour d'une valeur moyenne. Les fluctuations (signatures) transmettent souvent des informations sur l'etat du systeme que la valeur moyenne ne peut predire. Cette etude est entreprise pour elaborer des methodes statistiques de detection d'anomalies de fonctionnement sur la base de l'analyse des signatures contenues dans les signaux de bruit provenant du processus. L'algorithme presente est capable de: 1/ Apprendre les caracteristiques des operations normales dans un processus complexe. 2/ Detecter des petites deviations par rapport a la conduite normale du processus. L'algorithme peut etre implante sur un calculateur de taille moyenne pour les applications en ligne. (auteur)

  6. Incidence du contexte sur l'efficacité des think tanks dans les pays ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    indicateurs quantitatifs de mesures clés du contexte et de l'efficacité à la lumière des résultats des études de cas. Le projet devrait aboutir à la formulation de recommandations concrètes et applicables à l'intention des think tanks, des bailleurs de fonds ...

  7. Molecular dynamics simulations of ter-pyridine and bis-triazinyl-pyridine complexes with lanthanide cations; Etude de dynamique moleculaire de complexes de la bis-triazinyl-pyridine (BTP) et de la terpyridine avec des lanthanides(3)

    Energy Technology Data Exchange (ETDEWEB)

    Guilbaud, Ph. [CEA Valrho, (DCC/DRRV/SEMP), 30 - Marcoule (France)

    2000-07-01

    The search for ligands which specifically separate actinides(III) from lanthanides(III) by liquid-liquid extraction has prompted considerable research in the Process Design and Modeling Department ('Service d'Etude et de Modelisation des Procedes'- SEMP). Ligands with soft donor atoms AS) that are able to perform this separation have already been investigated and research is currently under way to improve their performance for high acidic feeds. Theoretical chemistry research is conducted in the Theoretical and Structural Chemistry Laboratory ('Laboratoire de Chimie Theorique et Structurale') to improve our understanding of the complexation and extraction of these cations with such ligands. Theoretical studies were first carried out for the ter-pyridine (TPY) and bis-triazinyl-pyridine (BTP) ligands that display fairly good ability to separate and extract actinide(III) from lanthanide(III) ions. Molecular dynamics simulations were performed on ter-pyridine and bis-triazinyl-pyridine complexes with three lanthanide cations (La{sup 3+}, Eu{sup 3+} and Lu{sup 3+}) for vacuum and for water solutions. These calculations were carried out without counter-ions, with three nitrate (NO{sub 3}{sup -}) ions, and, in the case of ter-pyridine, with three {alpha}-bromo-caprate anions that are likely to be used experimentally as synergistic agents for the separation and extraction of An(III) from Ln(III). Molecular dynamics simulations were first performed for vacuum to evaluate the distances between nitrogen and lanthanide atoms (Ln{sup 3+},N) and intrinsic interaction energies to poly-nitrogenous ligands with or without NO{sub 3} ions, and for both ligands. The (Ln{sup 3+},N) distances decrease and the cation/ligand interaction energies increase along the La{sup 3+}, Eu{sup 3+}, Lu{sup 3+} series, with decreasing Ln(III) ion radii. The introduction of nitrate counter-ions makes the (Ln{sup 3+},N) distances slightly higher, and the TPY/Ln{sup 3+} and BTP

  8. L'introduction d'espèces allochtones de grenouilles vertes en France, deux problèmes différents : celui de R. Catesbeiana et celui des taxons non présents du complexe Esculenta

    Directory of Open Access Journals (Sweden)

    NEVEU A.

    1997-01-01

    Full Text Available Depuis quelques années, la grenouille taureau (Rana catesbeiana est signalée en France dans une zone limitée de gravières près de Bordeaux. Elle est aussi présente depuis peu aux Pays-Bas et, dans les deux cas, la reproduction est effective. Cette espèce existe déjà en Europe depuis les années 30, à la suite d'introductions volontaires en Italie, sans pour cela avoir été signalée dans la partie ouest. La grenouille taureau est la plus grande des espèces nord-américaines et est considérée comme un prédateur éclectique. De ce fait, elle peut présenter un danger pour d'autres animaux, en particulier les grenouilles autochtones. Mais aucune donnée ne permet d'estimer cet éventuel impact en France et les données de la littérature ont souvent surestimé ce dernier. Par précaution, des mesures pourraient être prises pour réduire les populations actuelles présentes dans une aire pour le moment limitée. Les importations de grenouilles vivantes pour la consommation humaine, surtout à partir des pays du sud de l'Europe, sont l'occasion d'introductions de nouveaux taxons. Mais ces grenouilles font partie du même complexe et sont proches sur le plan morphologique, biologique et écologique. Les risques potentiels pour les populations locales sont les introductions de gènes, mais en ce qui concerne un éventuel avantage compétitif aucune donnée ne permet de conclure.

  9. Applications of sub-optimality in dynamic programming to location and construction of nuclear fuel processing plant; Application de la sous-optimalite en programmation dynamique a la localisation et la cadence optimales de construction des equipements

    Energy Technology Data Exchange (ETDEWEB)

    Thiriet, L; Deledicq, A [Commissariat a l' Energie Atomique, 92 - Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires, section des etudes economiques generales

    1968-09-01

    First, the point of applying Dynamic Programming to optimization and Operational Research problems in chemical industries are recalled, as well as the conditions in which a dynamic program is illustrated by a sequential graph. A new algorithm for the determination of sub-optimal politics in a sequential graph is then developed. Finally, the applications of sub-optimality concept is shown when taking into account the indirect effects related to possible strategies, or in the case of stochastic choices and of problems of the siting of plants... application examples are given. (authors) [French] On rappelle d'abord l'interet de la Programmation Dynamique dans les problemes d'optimisation et de Recherche Operationnelle dans les industries chimiques, et les conditions de representation d'un programme dynamique par un graphe sequentiel. On expose ensuite un nouvel algorithme de determination de politiques sous-optimales dans un graphe sequentiel. On montre enfin les applications du concept de sous-optimalite a la prise en compte d'effets indirects lies aux politiques possibles, aux choix dans l'aleatoire, a des problemes de localisation optimale d'usines... et on donne des exemples d'utilisation. (auteurs)

  10. Use of charge storage tube in the building of a buffer memory; Application des tubes a memoire a la realisation d'une memoire tampon

    Energy Technology Data Exchange (ETDEWEB)

    Marcovici, C [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    The apparatus manufactured is a buffer memory to be located between a detector and a multichannel pulse height analyser which received the pulses at regular times. The buffer memory and the detector have the same order of dead time, then the whole is equivalent to a detector plus an analyser without dead time, but that is true only if the mean time between two consecutive pulses from the detector is greater than the analyser time resolution. The apparatus used two electrostatic barrier grid tubes; the first one stores temporarily the data from the detector during the time necessary to analyse the data recorded on the other one. At the end of the analysis, the roles of the two tubes are permuted. The advantage on similar other apparatus is the uninterrupted recording of the pulse height informations from the detector and the uninterrupted analysis. In addition, the transistorization is interesting for reliability and maintainability. The document presents principles and data on the barrier grid storage tube, considers its conventional uses in nuclear electronics studies statistically the reduction of counting losses. It describes the test equipment and the tests which permits the screening of the best cathode ray storage tube for this application. Finally, it describes the item and gives the wave shapes in various points of the buffer memory. (author) [French] Le dispositif realise est une memoire tampon destinee a etre placee entre un detecteur et un selecteur d'amplitude multicanaux. Elle permet a ce dernier de recevoir et analyser les impulsions a intervalles de temps reguliers. Son temps de resolution est comparable a celui du detecteurs, l'ensemble est donc equivalent a un systeme constitue d'un detecteur suivi d'un selecteur sans temps mort, mais ceci n'est valable que tant que l'intervalle de temps moyen entre deux impulsions issues du detecteur est superieur au temps d'analyse necessite par le selecteur. Ce dispositif est constitue de deux tubes a memoire

  11. Molecular Dynamics Simulation of Spontaneous Imbibition in Nanopores and Recovery of Asphaltenic Crude Oils Using Surfactants for EOR Applications Simulations de dynamique moléculaire d’imbibition spontanée dans des nanopores et pour la récupération d’huiles brutes asphalténiques en utilisant des agents tensioactifs pour des applications d’EOR

    Directory of Open Access Journals (Sweden)

    Stukan M.R.

    2012-12-01

    Full Text Available We present Molecular Dynamics (MD simulations of the imbibition process in nanopores in case of two different mechanisms of the wettability modification. We compare the imbibition of an aqueous surfactant solution into an oil-wet pore driven by surfactant adsorption onto the oil-wet rock surface (coating mechanism and the imbibition of an aqueous surfactants solution driven by surfactants removing the contaminant molecules from the originally water-wet surface (cleaning mechanism. Our results show qualitative difference in the imbibition dynamics in these two cases and indicate that MD simulation is a useful tool to investigate details of the imbibition mechanisms at the pore scale with direct implications for Enhanced Oil Recovery (EOR operations. Nous presentons des simulations de Dynamique Moleculaire (DM du processus d’imbibition dans des nanopores dans le cas de deux mecanismes differents de modification de mouillabilite. Nous comparons l’imbibition d’une solution aqueuse d’agent tensioactif dans un pore mouille d’huile entrainee par une adsorption d’agent tensioactif sur la surface de roche mouillee d’huile (mecanisme de revetement et l’imbibition d’une solution aqueuse d’agent tensioactif entrainee par des agents tensioactifs eliminant les molecules contaminantes de la surface originellement mouillee d’eau (mecanisme de nettoyage. Nos resultats montrent une difference qualitative en matiere de dynamique d’imbibition dans ces deux cas et indiquent que la simulation de DM constitue un outil utile pour etudier les mecanismes d’imbibition a l’echelle des pores avec des implications directes pour des operations de recuperation renforcee d’huile (EOR, Enhanced Oil Recovery.

  12. Dictionnaire d'analyse et de gestion des risques

    CERN Document Server

    Desroches, Alain

    2005-01-01

    Ce dictionnaire présente les principaux termes utilisés en analyse et gestion des risques, pour tous les secteurs d'activité industrielle ou de service. Il permet de clarifier des terminologies existantes présentant des variations plus ou moins importantes et parfois des contradictions de sens. Il propose : premièrement, la définition des auteurs, définition correspondant à l'usage le plus courant du terme , deuxièmement, les différences avec les terminologies existantes (essentiellement des normes) , troisièmement, des compléments à la définition, lorsque cela semble nécessaire et notamment lorsqu'il est important de préciser le contexte d'utilisation du terme , en dernier lieu, des exemples pratiques d'application, lorsque cela peut apporter un éclairage complémentaire pertinent.

  13. Detection of {alpha} particles using semiconductors. Application to the control of plutonium extraction; Detection des particules {alpha} par semiconducteurs application au controle de l'extraction du plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Tanguy, J [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1968-03-01

    A study is made of a particles produced by thick sources, using either diffused junction or surface barrier semiconductor detectors for controlling continuously the plutonium extraction process. For this, a presenting apparatus is described in which the solutions to be analyzed flow in contact with the detector protected by a thin mica membrane. A method is described which gives a precise recording of the spectra and which thus allows the separation of two or more {alpha} emitters present in the same solution. This method has been applied to the measurement of {sup 239}Pu in the the presence of {sup 241}Am with an accuracy of {+-}5 per cent. In the second part of the report is considered the detection of plutonium in solutions of {beta} - {gamma} emitting fission products. Pile-up is reduced by using a fast amplification chain associated to totally depleted thin detectors. Under these conditions a few mg of {sup 239}Pu can be detected in solutions of fission products having an activity of 100 curies/liter. A method is given for discriminating {alpha} and {beta} particles, it is based on the difference in the collection times for the charges liberated by these particles in the detector. (author) [French] On etudie la detection de particules {alpha} issues de sources epaisses par detecteurs semiconducteurs a jonction diffusee ou a barriere de surface pour le controle continu du procede d'extraction du plutonium. A cet effet on decrit un appareil presentateur dans lequel les solutions a analyser circulent au contact du detecteur protege par une membrane mince de mica. On decrit une methode qui permet par le trace precis des spectres de separer deux ou plusieurs emetteurs {alpha} presents dans une meme solution. Cette methode a ete appliquee a la mesure du {sup 239}Pu en presence de {sup 241}Am avec une precision de {+-} 5 pour cent. Dans la deuxieme partie on traite de la detection du plutonium dans des solutions de produits de fission emetteurs {beta} and {gamma}. On

  14. Gestion des risques, valorisation et stratégie : applications aux industries agro-alimentaire et de transport aérien

    OpenAIRE

    Hassane Amadou, Rahila

    2014-01-01

    Ce travail de recherche apporte des éléments de compréhension supplémentaires sur l’impact des stratégies de gestion des risques sur la valeur et sur la stratégie des entreprises. Une première analyse examine un échantillon de 378 observations d’entreprises du secteur agroalimentaire sur 5 ans. Il ressort de cette analyse que l’intensité d’utilisation des produits dérivés pour couvrir les risques de change, taux d’intérêt et prix des matières premières n’influence pas sensiblement la valeur d...

  15. Rhenium carbene complexes and their applications; Rhenium-Carben-Komplexe und ihre Anwendungen

    Energy Technology Data Exchange (ETDEWEB)

    Hille, Claudia Heidi

    2016-01-25

    New pharmaceutically suitable metal complexes play an important role in the development of diagnostic and therapeutic agents for cancer treatment. One option concerning new radiopharmaceuticals, is the application of the rhenium isotopes {sup 186}Re and {sup 188}Re. Therefore, water soluble but at the same time stable complexes, which can be synthesized straightforward, are required. In this thesis, several synthetic pathways to such rhenium complexes bearing Nheterocyclic carbenes are presented and applicability tests of literature known complexes conducted. The selected target structures based on monocarbenes turned out to be inappropriate for use in radiopharmaceutical applications, due to their long reaction times and purification issues. Additionally, sterical and electronical effects of the carbene ligands concerning complex formation have been investigated. Possibilities of functionalization at different positions on the heterocycle as well as hydrophilic wingtips - to achieve a better stability in an aqueous media - have been examined to gain information about chemical and physical properties of the resulting complexes. Furthermore, experiments regarding the coordination of various biscarbene ligands, which provides besides the stable chelatisation additionally the possibility of varying the linking bridge, to rhenium(I/V) precursors, have been performed. Dioxo-bis-(1,1{sup '}-methylene-bis(3,3{sup '}-diisopropylimidazolium-2-ylidene)) rhenium(V )-hexafluorophosphate was synthesized via a transmetalation reaction of the corresponding silver carbene with ReOCl{sub 3}(PPh{sub 3}){sub 2} and silver hexafluorophosphate. This complex provided the basis for the first radiolabeled {sup 188}Rhenium NHC complex later on. An enhancement of the kinetic and thermodynamic stability of potential rhenium biscarbene complexes based on modifications concerning the length and character of the bridging moiety between the chelating NHC rings as well as the nature of

  16. Mathematical study of chemical kinetics schemes. Application to air pollution models; Etude mathematique de schemas de cinetique chimique. Application a des modeles de pollution atmospherique

    Energy Technology Data Exchange (ETDEWEB)

    Billette, E.

    1997-06-23

    Complex chemical kinetics modelling is relevant in numerous fields related to the petroleum industry, for instance engine combustion, petrochemistry and atmospheric pollution. Many numerical difficulties are encountered in the computation of these models, mainly due to the large size, the non-linearity and the stiffness of the associated ordinary differential systems. We first studied systems that have an asymptotic behaviour which may be derived from an algebraic analysis. Then we reviewed different methods that make possible the reduction of size and stiffness for chemical kinetics-related differential systems, and suggest possible improvements for some of those methods. We also studied their application to atmospheric chemistry models. Finally, we started to extend those reduction methods to partial differential systems that include, in addition to chemical kinetics, other phenomena such as species emission, advection or diffusion. (author) 44 refs.

  17. Study of the anodic process in the electrolysis of molten chlorides. Application to the chlorine electrode; Contribution a l'etude du processus anodique dans l'electrolyse des chlorures fondus. Application a l'electrode de chlore

    Energy Technology Data Exchange (ETDEWEB)

    Fondanaiche, J C [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1967-05-01

    The oxidation reaction of Cl{sup -} ions on a carbon electrode occurs with a very low over-voltage in molten LiCl-KCl, NaCl-KCl, CaCl{sub 2} and AgCl electrolytes and therefore the properties of the electrode 'polarized' anodically with a current density I are, as a first approximation, identical to those which it possesses at a chlorine pressure P (produced by the addition of external chlorine). This property of the Cl{sup -} ion oxidation reaction has enabled us to propose an electrochemical method for the study of the absorption equilibrium of the chlorine between a solid and a liquid phase. We can in effect replace this addition of outside chlorine at a pressure P by an electrolysis at a current density I. We have developed a mechanism which accounts for the reaction kinetic of the discharge of Cl{sup -} ions. It has been checked with the help of intensity-potential curves and potential-time curves which characterize the carbon depolarization in an open circuit. Two methods have been used for measuring the amount of chlorine adsorbed on the carbon. It has been possible to determine the nature of the bonds linking the adsorbed chlorine to the carbon, and the electrode-electrolyte surface exchange by varying the temperature and the nature of the electrode and of the electrolyte. Certain anomalies and in particular certain transient phenomena have been explained by the influence of the oxygen present in the molten salt in the form of O{sup 2-} ions and, on the electrode surface, in the form of chemisorption complexes. (author) [French] La reaction d'oxydation des ions Cl{sup -} sur une electrode de carbone s'effectue avec une surtension tres faible dans les electrolytes fondus LiCl-KCl, NaCl-KCl, CaCl{sub 2} et AgCl et par consequent les proprietes de l'electrode ''polarisee'' anodiquement avec une densite de courant I sont, en premiere approximation, identiques a celles qu'elle possede sous une pression de chlore P (creee par un apport exterieur de chlore). Cette

  18. Finance computationnelle et gestion des risques ingénierie financière avec applications Excel (Visual Basic) et Matlab

    CERN Document Server

    Racicot, François-Éric

    2006-01-01

    Ce manuel propose un exposé rigoureux de la gestion des risques en finance. Les aspects théoriques de la question sont abordés par des démonstrations claires et des rappels élaborés des bases mathématiques de la finance computationnelle. Le texte est émaillé de nombreux programmes écrits en langages Visual Basic (Excel), Matlab et EViews qui prépareront l'étudiant à sa carrière de spécialiste en ingénierie financière.

  19. Current algebra; Algebre des courants

    Energy Technology Data Exchange (ETDEWEB)

    Jacob, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-07-01

    The first three chapters of these lecture notes are devoted to generalities concerning current algebra. The weak currents are defined, and their main properties given (V-A hypothesis, conserved vector current, selection rules, partially conserved axial current,...). The SU (3) x SU (3) algebra of Gell-Mann is introduced, and the general properties of the non-leptonic weak Hamiltonian are discussed. Chapters 4 to 9 are devoted to some important applications of the algebra. First one proves the Adler- Weisberger formula, in two different ways, by either the infinite momentum frame, or the near-by singularities method. In the others chapters, the latter method is the only one used. The following topics are successively dealt with: semi leptonic decays of K mesons and hyperons, Kroll- Ruderman theorem, non leptonic decays of K mesons and hyperons ( {delta}I = 1/2 rule), low energy theorems concerning processes with emission (or absorption) of a pion or a photon, super-convergence sum rules, and finally, neutrino reactions. (author) [French] La premiere partie de ce cours (trois premiers chapitres), traite des generalites concernant l'algebre de courants. Apres une definition rapide des courants faibles et un rappel de leurs proprietes (hypothese V-A, conservation du courant vecteur, regles de selection, courant axial partiellement conserve,...), l'on introduit l'algebre de Gell-Mann SU (3) x SU (3), et discute les proprietes generales de l'Hamiltonien faible non leptonique. Les chapitres IV a IX sont consacres a des applications importantes de l'algebre des courants. En premier lieu l'on demontre la formule de Adler et Weisberger, par deux methodes differentes, celle dite du repere de moment infini et celle des singularites proches. Cette derniere est seule utilisee dans la suite. Puis, l'on traite successivement les problemes suivants: desintegrations semi-leptoniques des mesons K et des hyperons, theoreme de Kroll-Ruderman, desintegrations non leptoniques des mesons

  20. Des universitaires de l'Asie et de l'Afrique échangent des ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    17 oct. 2017 ... Depuis 2007, des conférences de CPRsouth ont eu lieu chaque année; ... de la recherche sur les télécommunications, et des technologies de ... la façon dont les applications mobiles peuvent stimuler l'utilisation d'Internet.

  1. Modelisation des effets physico-techniques pour la conception des ...

    African Journals Online (AJOL)

    automatisation dans les installations industrielles a besoin d'une régulation automatique des commandes des processus technologiques pour lesquelles certaines contraintes sont à relever compte tenu des exigences des innovations scientifiques de ...

  2. The application of {beta}-ray excitation fluorescence to the measurement of the thickness of deposits and to analysis; Applications de la fluorescence excitee au moyen des rayons {beta} a la mesure des epaisseurs des depots et a l'analyse

    Energy Technology Data Exchange (ETDEWEB)

    Martinelli, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Seibel, G [Institut de Recherches de la Siderurgie Francaise (IRSID), 78 - Saint-Germain-en-Laye (France)

    1961-07-01

    Principles of the method are first outlined and the instrumentation used is described. The different types of radiation detectors are subject of a detailed study. As a source of {beta}-radiation {sup 90}(Sr + Y) was used as well as {sup 147}Pm. Great care was taken to eliminate back-diffused electrons by deflection by a strong permanent magnet. The method was applied to the measurement of the thickness of deposits of Cr, Zn, Sn, Cd and Cu on iron as well as Zn, Cr, Ag and Au on copper and the results obtained are discussed. An attempt was made, to use {beta}-X-ray fluorescence for the analysis of minerals, iron ore and glass and for routine control of Si-Mn, Si-Ca, Fe-Mn and Fe-W. Finally the method of {beta}-X-ray fluorescence is compared with normal-X-ray fluorescence and possibilities of further development are cited. (author) [French] Les principes de la methode et l'instrumentation utilisee sont presentes. On decrit en particulier les detecteurs de rayonnement utilises. Comme source de rayonnement on utilise {sup 90}(Sr + Y) et {sup 147}Pm. Pour eliminer les electrons retrodiffuses on utilise un aimant permanent place sur le trajet du faisceau. La methode est appliquee a la mesure des epaisseurs des depots metalliques tels que le Cr, Zn, Sn, Cd et Cu sur fer et le Zn, Cr, Ag et Au sur cuivre. D'autre part, la fluorescence {beta}-X etait utilisee pour l'analyse des minerais et des verres et pour le controle des alliages Fe-Mn, Fe-W, Si-Mn, Si-Ca. Enfin, on passe a une comparaison entre la fluorescence {beta}-X et la fluorescence X normale et on discute les possibilites d'un developpement futur. (auteur)

  3. Measurements and Application of Partition Coefficients of Compounds Suitable for Tracing Gas Injected Into Oil Reservoirs Mesures et applications des coefficients de partage de composants utilisables comme gaz traceurs injectés dans des réservoirs de pétrole

    Directory of Open Access Journals (Sweden)

    Dugstad O.

    2006-11-01

    Full Text Available Tracing of injection gas in oil reservoirs is a technique used to improve the description of permeability distributions in situ. Results from dynamic laboratory experiments of gas tracers are reported. Gas tracers are delayed when flooding through a reservoir by the partitioning into the oil phase. A knowledge of this effect is important to optimize the interpretation of field tracer tests. The partition is quantified by the partition coefficient K. Two chemical tracers perfluoromethylcyclopentane (PMCP and perfluoromethylcyclohexane (PMCH and the radioactive 14C labelled ethane have been studied here. The two chemical compounds are new as reservoir tracers and no field results with these tracers are reported in the open literature. Our group has, however, recently applied these compound successfully as tracers in a North Sea reservoir. Les traceurs représentent un outil précieux pour améliorer la description des gisements. On les a utilisés pour obtenir des renseignements sur la configuration de l'écoulement des fluides injectés et sur leur vitesse, sur l'instant de percé des venues d'eau et sur leur origine précise, sur les traitements d'amélioration du balayage, sur les hétérogénéités importantes telles que fractures, barrières d'écoulement et stratifications de la perméabilité. Dans les gisements importants comportant plusieurs puits de production et plusieurs puits d'injection, il est donc souhaitable de disposer de plusieurs traceurs afin de pouvoir injecter différents traceurs ou mélanges de traceurs dans les différents puits. L'article présenté ici est une contribution a l'effort fait pour étendre le nombre de gaz traceurs fiables applicables aux gisements. L'article présente les résultats d'essais dynamiques en laboratoires dans lesquels on injecte des traceurs à travers un milieu poreux. Lorsqu'ils traversent un réservoir, les gaz traceurs sont retardés du fait de leur ségrégation dans la phase huile. La

  4. Calculation of control rods in rectangular reactor, and applications (1960); Calcul des barres de conteole dans un reacteur rectangulaire et applications (1960)

    Energy Technology Data Exchange (ETDEWEB)

    Goshen, S; Pazy, A [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    The aim of this report is to find a method for estimating the anti-reactivity of control rods perpendicular to the axis in a cylindrical pile. The paper is divided into two parts. In the first is given a method of calculating control rods in a rectangular pile, similar to the Nordheim-Scalettar method for cylindrical piles. As an example the formulas are given for the theories of one and two neutron groups, the generalisation for several groups being evident. In the second part we find by a variation method a formula for estimating the Laplacian of a pile, which may be divided into parallelepipeds for which the Laplacian are given. Finally, this formula is used to calculate the anti-reactivity of rods perpendicular to the axis in a cylindrical pile. (author) [French] Le but de ce rapport est de trouver une methode pour estimer l'antireactivite des barres de controle perpendiculaires a l'axe dans pile cylindrique. Le rapport se divise en deux parties. Dans la premiere nous donnons une methode de calcul des barres de controle dans une pile rectangulaire, analogue a la methode de Nordheim-Scalettar pour les piles cylindriques. A titre d'exemple, nous donnons les formules de theories a un et deux groupes de neutrons, la generalisation pour plusieurs groupes est evidente. Dans la deuxieme partie, nous trouvons, par une methode de variation, une formule qui permet d'estimer le laplacien d'une pile, qui peut etre divisee en parallelepipedes dont les laplaciens sont donnes. Nous utilisons enfin, cette formule pour calculer l'antireactivite des barres perpendiculaires a l'axe dans une pile cylindrique. (auteur)

  5. Algebra of Complex Vectors and Applications in Electromagnetic Theory and Quantum Mechanics

    Directory of Open Access Journals (Sweden)

    Kundeti Muralidhar

    2015-08-01

    Full Text Available A complex vector is a sum of a vector and a bivector and forms a natural extension of a vector. The complex vectors have certain special geometric properties and considered as algebraic entities. These represent rotations along with specified orientation and direction in space. It has been shown that the association of complex vector with its conjugate generates complex vector space and the corresponding basis elements defined from the complex vector and its conjugate form a closed complex four dimensional linear space. The complexification process in complex vector space allows the generation of higher n-dimensional geometric algebra from (n — 1-dimensional algebra by considering the unit pseudoscalar identification with square root of minus one. The spacetime algebra can be generated from the geometric algebra by considering a vector equal to square root of plus one. The applications of complex vector algebra are discussed mainly in the electromagnetic theory and in the dynamics of an elementary particle with extended structure. Complex vector formalism simplifies the expressions and elucidates geometrical understanding of the basic concepts. The analysis shows that the existence of spin transforms a classical oscillator into a quantum oscillator. In conclusion the classical mechanics combined with zeropoint field leads to quantum mechanics.

  6. Uncertainty and sensitivity analysis of applications of the PARK program system; Unsicherheits- und Sensitivitaetsanalyse von Anwendungen des Programmsystems PARK

    Energy Technology Data Exchange (ETDEWEB)

    Luczak-Urlik, D.; Bleher, M.; Jacob, P.; Mueller, H. [GSF - Forschungszentrum fuer Umwelt und Gesundheit Neuherberg GmbH, Oberschleissheim (Germany). Inst. fuer Strahlenschutz; Hofer, E.; Krzykacz, B. [Gesellschaft fuer Reaktorsicherheit mbH (Greece)

    1997-11-01

    The (PARK) program package for assessment and abatement of off-site radiological consequences of nuclear accidents establishes radiologic analyses and prognoses on the basis of the measured data obtained by the IMIS system for ambient radiation monitoring. A probabilistic uncertainty and sensitivity analysis has been performed of the PARK-based mean specific activities of fodder and food and the potential radiation exposure of the population. Uncertainties were expressed in model input parameters, i.e. in measured values and radioecologic parameters via subjective probability distributions, within the framework of various emission scenarios (nuclide spectra describing two release modes, dry and wet deposition, and at three times over a one-year period). The resulting output data distributions were determined by Monte Carlo simulations. As a rule, the results of the analyses depend on the selected emission scenario. Measured values proved to be the major source of uncertainties (especially from in-situ soil activity measurements), and also the activity transfer data from fodder to food. As for wet deposition, uncertainties were added by the parameters used for determination of the interception factors. As the measuring stations cannot correlate their measured gamma dose rates with meteorologic data (precipitations), derived information relating to larger areas such as a ``Kreis`` (administrative district) is very much subject to uncertainties. The uncertainties of the PARK results are increasing with assessed increases in rainfall. (orig.) [Deutsch] Das Programmsystem zur Abschaetzung und Begrenzung radiologischer Konsequenzen (PARK) erstellt radiologische Analysen und Prognosen aufgrund von Messdaten, welche im Rahmen des Integrierten Mess- und Informationssystems zur Ueberwachung der Umweltradioaktivitaet (IMIS) erhoben werden. Es wurde eine probabilistische Unsicherheits- und Sensitivitaetsanalyse fuer die in PARK berechneten mittleren spezifischen Aktivitaeten

  7. Chemistry of complexing molecules and environment. Report of the working group of the Cea ''mission environment''; Chimie des complexants en environnements. Rapport du groupe de travail de la mission environnement

    Energy Technology Data Exchange (ETDEWEB)

    Petit, J.C

    1998-07-01

    The Working group 'Chemistry of Complexing Molecules and Environment' of the Mission Environment (AG/ENV) identified themes for an original positioning of CEA on important issues of environmental research if a sufficiently strong demand appears. The research of CEA on the environment should be complementary to actions undertaken by other partners (official institutions, research organizations and industrial firms). The themes suggested are: the synthesis of new chelating molecules and new materials having specific properties, with the support of theoretical chemistry and modeling, analytical physical chemistry and speciation of species in relation to their eco-toxicity and their biogeochemical mobility in the natural environment. These themes, illustrated by examples of actions in progress at CEA or likely to be launched quickly, draw largely from recognized competences of the teams, generally developed for finalized nuclear applications: experimental, theoretical and instrumental competences. (author)

  8. Chemistry of complexing molecules and environment. Report of the working group of the Cea ''mission environment''; Chimie des complexants en environnements. Rapport du groupe de travail de la mission environnement

    Energy Technology Data Exchange (ETDEWEB)

    Petit, J C

    1998-07-01

    The Working group 'Chemistry of Complexing Molecules and Environment' of the Mission Environment (AG/ENV) identified themes for an original positioning of CEA on important issues of environmental research if a sufficiently strong demand appears. The research of CEA on the environment should be complementary to actions undertaken by other partners (official institutions, research organizations and industrial firms). The themes suggested are: the synthesis of new chelating molecules and new materials having specific properties, with the support of theoretical chemistry and modeling, analytical physical chemistry and speciation of species in relation to their eco-toxicity and their biogeochemical mobility in the natural environment. These themes, illustrated by examples of actions in progress at CEA or likely to be launched quickly, draw largely from recognized competences of the teams, generally developed for finalized nuclear applications: experimental, theoretical and instrumental competences. (author)

  9. Study of the magnetic characteristics of ferrites with a view to their application in a proton synchrotron; Etudes des caracteristiques magnetiques des ferrites en vue de leur application dans un synchrotron a protons

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, K C [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1966-10-01

    In this report magnetic properties of some Ni Zn ferrites available in France are investigated for the purpose of their use in accelerating cavities of proton synchrotron. An attempt is made to measure permeability and quality factor of ferrite versus various physical parameters such as frequency F, the induction B, the magnetic bias field Hp and the temperature, the investigation ranges being: F {<=} 40 Mc/s; B {<=} 10{sup -2} Tesla; Hp {<=} 5000 AT/m; T {<=} 100 C. The measurements were carried out with the one hand, conventional impedance bridge (Q-meter, RX-meter) and on the other hand, with resonating method using an inductive ferrite loaded cavity in parallel with an external capacity. The latter method is of particular interest for the measurements in function of induction and magnetic bias field. (author) [French] Ce travail consiste a etudier les proprietes magnetiques d'un certain nombre de ferrites de Ni Zn disponibles sur le marche francais en vue de leur utilisation dans les cavites acceleratrices d'un synchrotron a protons. On se propose de mesurer la permeabilite et le facteur de qualite du ferrite en fonction de divers parametres physiques tels que la frequence F, l'induction B, le champ magnetique de polarisation Hp et la temperature T, avec: F {<=} 40 Mc/s; B {<=} 10{sup -2} Tesla; Hp {<=} 5000 AT/m; T {<=} 100 C. On effectue les mesures d'une part a l'aide des ponts d'impedance classiques (Q-metre, RX-metre) et d'autre part par la methode du resonateur qui consiste a mettre en parallele une cavite inductive chargee de ferrite et une capacite exterieure. Cette derniere methode est particulierement interessante pour les mesures en fonction de l'induction et du champ magnetique polarisant. (auteur)

  10. Tubes légers à haute résistance pour des applications pétrolières marines Light High Strength Tubes for Offshore Petroeleum Applications

    Directory of Open Access Journals (Sweden)

    Corteville J.

    2006-11-01

    Full Text Available Les besoins nouveaux en tubes à haute résistance, créés par le développement actuel des gisements pétroliers marins, nous ont conduits à étudier des tubes composites particuliers, élaborés par enrouiement hélicoïdal de rubans d'acier minces à haute résistance enrobés d'une résine époxy polymérisable. Un mode de recouvrement adapté des rubans d'acier confère au composite une bonne étanchéité et des caractéristiques mécaniques élevées. Les propriétés physiques et chimiques de la matrice de résine permettent également d'obtenir une faible densité et une résistance convenable à la corrosion par les fluides pétroliers, l'eau de mer ou les boues de forage. Cette étude préliminaire comporte une analyse théorique simplifiée de ce type de structure composite, puis une partie expérimentale destinée a sélectionner les caractéristiques optimales de l'acier et de la résine et à vérifier les propriétés mécaniques et physico-chimiques obtenues sur ces tubes. Enfin, des exemples d'application en mer profonde destinés à comparer ces tubes composites aux tubes en acier sont présentés. Les premières conclusions de cette étude semblent confirmer l'intérêt de ce type de matériau pour ces applications. The new requirements for high-strength tubes created by thé current development of offshore oilfields led thé authors ta study thé development ot spécial composite tubes formed by thé spiral winding of high-strength thin steel strips coated with a polymerïzable epoxy resin. A particular method of overlapping thé steel strips makes the composite leakproof and leads to good mechanical properties: The physical and chemical properties of thé resin matrix also make for a low specific gravity and suitable résistance to corrosion coused by petroleum fluids, seawater or drilling mud. This preliminary article presents a simplified theoretical analysis of this type of composite structure, followed by an exp

  11. Interest of uranium complexes for the mechanism study of the McMurry reaction; Interet des complexes de l`uranium pour l`etude du mecanisme de la reaction de McMurry

    Energy Technology Data Exchange (ETDEWEB)

    Maury, O

    1997-07-04

    The reducing coupling reactions of ketones in diols and olefins are generally carried out with titanium or samarium compounds. In this work uranium complexes have been used. They have allowed to study the chemical reaction mechanism. This thesis is divided into three parts: 1) the reduction mechanism of uranium tetrachloride by cyclic voltametry has been studied at first. It has been shown that this reduction is followed by a transfer reaction of chlorides between the reduced specie of the higher electronic density and UCl . 2) In the second part is described: the synthesis, the crystal structure, the reactivity of the chemical agents, the stereochemistry of diols and alkenes formation and the pinacolisation reaction catalysis. 3) In the last part, the limits of the McMurry reaction are given by the study of the aromatic ketones pinacolisation reaction by-products. The obtained results show that the complexes of the metals which present a high reducing and oxo-philic (Ti, Sm, U..) character react in a similar way with the carbonyl compounds. If the uranium compounds are less used than those of the titanium in the field of the organic synthesis applications, they are precious auxiliaries and excellent models for reactions mechanisms study and for the synthesis methods optimization. (O.M.). 284 refs.

  12. Gyrodactylidae et Gyrodactylose des Salmonidae

    Directory of Open Access Journals (Sweden)

    MALMBERG G.

    1993-01-01

    ées. Une dérive génétique peut résulter de nouvelles formes pathogènes. Ainsi les piscicultures peuvent agir comme des centres de développement et de propagation des Gyrodactylus. La truite Arc en Ciel, O. mikiss est indéniablement l'unique nouvel hôte potentiel pour nombre d'espèces de Gyrodactylus. En conclusion, il est recommandé de poursuivre sur les stocks de Salmonidae, des études concernant leur résistance aux Gyrodactylus pathogènes, d'étudier de manière comparative les blessures causées par différentes espèces de Gyrodactylus, d'étudier leur viviparité si spécifique, ainsi que les interactions complexes des conditions micro et macro environnementales.

  13. Study of a micro-sublimation apparatus with removal of the vapours by pumping; application to the analysis of fluorinated products (1963); Etude d'un appareillage de microsublimation avec entrainement des vapeurs par pompage et application a l'analyse des produits fluores (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Delvalle, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1963-07-01

    Micro-sublimation analysis presents definite advantages both from the qualitative and quantitative points of view. An automatic micro-sublimation analysis apparatus has been developed for the analysis of fluorinated products (ClF{sub 3}, HF, UF{sub 6}, etc.) but this is only one particular application of a method which has a far wider field of possible applications. We give first the most favorable conditions for the operation of such an apparatus. These conditions are the use of a detector which is linear and independent of the nature of the gas, the flow of the sublimed vapours in the conditions of molecular flow, and finally a reproducible and linear re-heating of the separating trap. The apparatus thus built has the advantage of yielding any analysis without prior calibration. It also makes possible the easy identification of an unknown product by the determination of its vapour pressure curve and its molecular weight. The analysis of fluorinated products with this apparatus has shown that the experimental results agree well with what is expected. (author) [French] L'analyse par microsublimation presente un interet certain tant au point de vue qualitatif que quantitatif. Nous avons mis au point un appareillage automatique d'analyse par microsublimation pour l'analyse des produits fluores (CIF{sub 3}, HF, UF{sub 6}, etc.) mais il ne s'agit que de l'application a un cas particulier d'une methode ayant un champ d'applications bien plus vaste. Nous exposons tout d'abord les conditions les plus favorables au bon fonctionnement d'un tel appareil. Ces conditions sont l'emploi d'un detecteur lineaire et independant de la nature du gaz, l'ecoulement des vapeurs sublimees en regime moleculaire et enfin un rechauffage reproductible et lineaire du piege separateur. L'appareil ainsi realise presente l'avantage d'effectuer une analyse quelconque sans etalonnage prealable. Il permet en outre d'identifier aisement un corps inconnu par la determination de sa courbe de tension

  14. Statutes of limitations: the special problem of DES suits

    International Nuclear Information System (INIS)

    Feigin, C.A.

    1981-01-01

    In 1971, medical studies determined that DES causes a rare type of vaginal cancer in a small number of daughters of mothers who took DES during pregnancy. Subsequently, medical studies determined that exposure to DES can cause other vaginal abnormalities in the daughters, some of which may be precancerous. As a result of these discoveries, many lawsuits have been filed by these daughters against DES manufacturers. Many DES suits may be barred by statutes of limitations, both because the number of years between the daughters' exposure to DES in utero and the discovery that DES can cause injuries exceeds the statutory period, and because the cancer or other injuries caused by DES may not develop for many additional years. This Note discusses two methods that DES plaintiffs may be able to use to overcome the potential statutes of limitations bar: the discovery rule, and state provisions which toll the statute of limitations for minors. The Note contends that courts should apply an expanded discovery rule to DES suits to avoid the unfair result of barring a claim before the plaintiff could have known that she had a cause of action. In addition, the Note argues that the injury which causes the statute of limitations to begin to run in DES suits should not be rigidly defined. Finally, the Note urges that courts allow eligible DES plaintiffs to take advantage of applicable state provisions that toll the statute of limitations for minors

  15. variabilite des productions et des revenus des exploitations

    African Journals Online (AJOL)

    3Centre de coopération internationale en recherche agronomique pour le développement (CIRAD), UMR Innovation,. Montpellier, France. Doubangolo COULIBALY, Email kone_b@yahoo.fr. RESUME. La durabilité des systèmes de production à base de coton dans un contexte de variabilité des prix aux producteurs et de ...

  16. The thin layer technique and its application to electron microscopy; La technique des couches minces et son application a la microscopie electronique

    Energy Technology Data Exchange (ETDEWEB)

    Ranc, G. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1957-10-15

    This work deals with the technique of thin layers obtained by evaporation under vacuum, in the thickness range extending from a few monoatomic layers to several hundred angstroms. The great theoretical and practical interest of these layers has, it is well known, given rise to many investigations from Faraday onwards. Within the necessarily restricted limits of this study, we shall approach the problem more particularly from the point of view of: - their production; - their use in electron microscopy. A critical appraisal is made, in the light of present-day knowledge, based on our personal experience and on an extensive bibliography which we have collected on the subject. (author) [French] Le present travail concerne la technique des couches minces obtenues par evaporation sous vide, dans le domaine d'epaisseur qui s'etend de quelques couches monoatomiques a plusieurs centaines d'angstroms. L'interet theorique et pratique considerable de ces couches a suscite, comme on sait, de nombreux travaux depuis Faraday. Dans le cadre necessairement restreint de cette these, nous aborderons plus particulierement le point de vue de: - leur obtention; - leur utilisation en microscopie electronique. Il s'agit d'une mise au point critique, a la lumiere des connaissances actuelles, appuyee sur notre experience personnelle et sur une importante bibliographie, qu'il nous a ete donne de reunir a ce sujet. (auteur)

  17. The thin layer technique and its application to electron microscopy; La technique des couches minces et son application a la microscopie electronique

    Energy Technology Data Exchange (ETDEWEB)

    Ranc, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1957-10-15

    This work deals with the technique of thin layers obtained by evaporation under vacuum, in the thickness range extending from a few monoatomic layers to several hundred angstroms. The great theoretical and practical interest of these layers has, it is well known, given rise to many investigations from Faraday onwards. Within the necessarily restricted limits of this study, we shall approach the problem more particularly from the point of view of: - their production; - their use in electron microscopy. A critical appraisal is made, in the light of present-day knowledge, based on our personal experience and on an extensive bibliography which we have collected on the subject. (author) [French] Le present travail concerne la technique des couches minces obtenues par evaporation sous vide, dans le domaine d'epaisseur qui s'etend de quelques couches monoatomiques a plusieurs centaines d'angstroms. L'interet theorique et pratique considerable de ces couches a suscite, comme on sait, de nombreux travaux depuis Faraday. Dans le cadre necessairement restreint de cette these, nous aborderons plus particulierement le point de vue de: - leur obtention; - leur utilisation en microscopie electronique. Il s'agit d'une mise au point critique, a la lumiere des connaissances actuelles, appuyee sur notre experience personnelle et sur une importante bibliographie, qu'il nous a ete donne de reunir a ce sujet. (auteur)

  18. Chirurgie des grassmanniennes

    CERN Document Server

    Lafforgue, Laurent

    2003-01-01

    Les compactifications diverses de variétés de modules sont un thème important et récurrent des mathématiques modernes, et elles connaissent un grand nombre d'applications. Ce livre traite le cas de cellules de Schubert minces, qui sont de sous-variétés naturelles de grassmanniennes. L'auteur a été amené à traiter ces questions par un cas particulier lié à ses travaux sur le programme de Langlands. Dans cette monographie, il en développe une théorie plus systématique, présentant le fortes similarités avec celle des modules du courbes stables. The various compactifications of moduli spaces are an important recurrent theme of modern mathematics, and they have a large number of applications. This book treats the case of thin Schubert varieties, which are natural subvarieties of Grassmannians. The author was led to these questions by a particular case linked to his work on the Langlands program. In this monograph, he develops the theory in a more systematic way, which exhibits strong similarities...

  19. Évaluation des paysages de l'Hérault: une approche méthodologique et une application SIG adaptée

    Directory of Open Access Journals (Sweden)

    Marie-Cécile FALQUE

    1995-06-01

    Full Text Available L’élaboration d’un outil d’évaluation des paysages a été rendue possible grâce à un partenariat entre l’INRA, la DIREN et l’Observatoire du Territoire, avec le souci commun d’intégrer la réflexion sur les paysages dans les problématiques de gestion de l’espace. Les modules d’analyse élaborés à partir des fonctionnalités des Systèmes d’Information Géographique produisent des résultats très prometteurs en vue de la sensibilisation au paysage des partenaires et acteurs et laissent entrevoir d’intéressantes perspectives de valorisation.

  20. Theoretical and experimental study of a calorimetric technique for measuring energy deposition in materials caused by complex pile irradiation; Etude theorique et experimentale d'une technique calorimetrique de mesure des depots d'energie dans les materiaux dus au rayonnement complexe de pile

    Energy Technology Data Exchange (ETDEWEB)

    Mas, P; Sciers, P; Droulers, Y [Commissariat a l' Energie Atomique. Centre d' Etudes Nucleaires, 38 - Grenoble (France)

    1962-07-01

    Calorimetric methods may be used to measure gamma fluxes greater than 10{sup 6} r/h near the cores of swimming pool reactors. The theory, design, and properties of isothermal calorimeters are discussed, and experimental results obtained with two types are presented. Measurement of energy deposition in materials and the long term integration of energy depositions are other uses of these devices. Results of measurements on heat deposition in steel and water are given. Fluxes were also measured. (authors) [French] Une premiere partie traite de la theorie des calorimetres isothermes mis en oeuvre au C.K.N. Grenoble. La puissance deposee dans le calorimetre par les flux de rayonnement echauffe celui-ci. L'echauffement est mesure a l'aide d'un thermocouple. On montre que l'on a ainsi une mesure absolue de cette puissance. Une deuxieme partie traite de l'etude experimentale de: deux types d'appareils utilises: leur construction, les resultats experimentaux, leurs utilisations. Trois de celles-ci sont particulierement interessantes: - la mesure des hauts flux gamma, - la mesure du depot d'energie dans les materiaux, - l'integration pendant une longue duree des depots d'energie (un modele de calorimetre a fonctionne a ce jour 2 500 heures et a integre 9 x 10 puissance 10 rads gamma et 6 x 10 puissance 18 neutrons rapides). La troisieme partie est consacree a l'etude des qualites de l'appareil: robustesse, fidelite, precision, sensibilite, gamme de mesure. Enfin dans la derniere partie sont decrites deux applications de la methode calorimetrique a la mesure du depot d'energie dans un acier special et dans l'eau. (auteurs)

  1. Application of 3D Laser Scanning Technology in Complex Rock Foundation Design

    Science.gov (United States)

    Junjie, Ma; Dan, Lu; Zhilong, Liu

    2017-12-01

    Taking the complex landform of Tanxi Mountain Landscape Bridge as an example, the application of 3D laser scanning technology in the mapping of complex rock foundations is studied in this paper. A set of 3D laser scanning technologies are formed and several key engineering problems are solved. The first is 3D laser scanning technology of complex landforms. 3D laser scanning technology is used to obtain a complete 3D point cloud data model of the complex landform. The detailed and accurate results of the surveying and mapping decrease the measuring time and supplementary measuring times. The second is 3D collaborative modeling of the complex landform. A 3D model of the complex landform is established based on the 3D point cloud data model. The super-structural foundation model is introduced for 3D collaborative design. The optimal design plan is selected and the construction progress is accelerated. And the last is finite-element analysis technology of the complex landform foundation. A 3D model of the complex landform is introduced into ANSYS for building a finite element model to calculate anti-slide stability of the rock, and provides a basis for the landform foundation design and construction.

  2. A new synthesis route for Os-complex modified redox polymers for potential biofuel cell applications.

    Science.gov (United States)

    Pöller, Sascha; Beyl, Yvonne; Vivekananthan, Jeevanthi; Guschin, Dmitrii A; Schuhmann, Wolfgang

    2012-10-01

    A new synthesis route for Os-complex modified redox polymers was developed. Instead of ligand exchange reactions for coordinative binding of suitable precursor Os-complexes at the polymer, Os-complexes already exhibiting the final ligand shell containing a suitable functional group were bound to the polymer via an epoxide opening reaction. By separation of the polymer synthesis from the ligand exchange reaction at the Os-complex, the modification of the same polymer backbone with different Os-complexes or the binding of the same Os-complex to a number of different polymer backbones becomes feasible. In addition, the Os-complex can be purified and characterized prior to its binding to the polymer. In order to further understand and optimize suitable enzyme/redox polymer systems concerning their potential application in biosensors or biofuel cells, a series of redox polymers was synthesized and used as immobilization matrix for Trametes hirsuta laccase. The properties of the obtained biofuel cell cathodes were compared with similar biocatalytic interfaces derived from redox polymers obtained via ligand exchange reaction of the parent Os-complex with a ligand integrated into the polymer backbone during the polymer synthesis. Copyright © 2011 Elsevier B.V. All rights reserved.

  3. Functional analytic methods in complex analysis and applications to partial differential equations

    International Nuclear Information System (INIS)

    Mshimba, A.S.A.; Tutschke, W.

    1990-01-01

    The volume contains 24 lectures given at the Workshop on Functional Analytic Methods in Complex Analysis and Applications to Partial Differential Equations held in Trieste, Italy, between 8-19 February 1988, at the ICTP. A separate abstract was prepared for each of these lectures. Refs and figs

  4. Processing of complex shapes with single-mode resonant frequency microwave applicators

    International Nuclear Information System (INIS)

    Fellows, L.A.; Delgado, R.; Hawley, M.C.

    1994-01-01

    Microwave processing is an alternative to conventional composite processing techniques. Single-mode microwave applicators efficiently couple microwave energy into the composite. The application of the microwave energy is greatly affected by the geometry of the composite. In the single mode microwave applicator, two types of modes are available. These modes are best suited to processing flat planar samples or cylindrical samples with geometries that align with the electric fields. Mode-switching is alternating between different electromagnetic modes with the intelligent selection of the modes to alleviate undesirable temperature profiles. This method has improved the microwave heating profiles of materials with complex shapes that do not align with either type of electric field. Parts with two different complex geometries were fabricated from a vinyl toluene/vinyl ester resin with a continuous glass fiber reinforcement by autoclaving and by microwave techniques. The flexural properties of the microwave processed samples were compared to the flexural properties of autoclaved samples. The trends of the mechanical properties for the complex shapes were consistent with the results of experiments with flat panels. This demonstrated that mode-switching techniques are as applicable for the complex shapes as they are for the simpler flat panel geometry

  5. Application of models for exchange of electronic documents in complex administrative services

    International Nuclear Information System (INIS)

    Glavev, Victor

    2015-01-01

    The report presents application of models for exchange of electronic documents between different administrations in government and business sectors. It shows the benefits of implementing electronic exchange of documents between different local offices of one administration in government sector such as a municipality and the way it is useful for implementing complex administrative services

  6. Application of models for exchange of electronic documents in complex administrative services

    Energy Technology Data Exchange (ETDEWEB)

    Glavev, Victor

    2015-11-30

    The report presents application of models for exchange of electronic documents between different administrations in government and business sectors. It shows the benefits of implementing electronic exchange of documents between different local offices of one administration in government sector such as a municipality and the way it is useful for implementing complex administrative services.

  7. Application of NASA management approach to solve complex problems on earth

    Science.gov (United States)

    Potate, J. S.

    1972-01-01

    The application of NASA management approach to solving complex problems on earth is discussed. The management of the Apollo program is presented as an example of effective management techniques. Four key elements of effective management are analyzed. Photographs of the Cape Kennedy launch sites and supporting equipment are included to support the discussions.

  8. A review on versatile applications of transition metal complexes incorporating Schiff bases

    Directory of Open Access Journals (Sweden)

    Ahmed M. Abu-Dief

    2015-06-01

    Full Text Available Schiff bases and their complexes are versatile compounds synthesized from the condensation of an amino compound with carbonyl compounds and widely used for industrial purposes and also exhibit a broad range of biological activities including antifungal, antibacterial, antimalarial, antiproliferative, anti-inflammatory, antiviral, and antipyretic properties. Many Schiff base complexes show excellent catalytic activity in various reactions and in the presence of moisture. Over the past few years, there have been many reports on their applications in homogeneous and heterogeneous catalysis. The high thermal and moisture stabilities of many Schiff base complexes were useful attributes for their application as catalysts in reactions involving at high temperatures. The activity is usually increased by complexation therefore to understand the properties of both ligands and metal can lead to the synthesis of highly active compounds. The influence of certain metals on the biological activity of these compounds and their intrinsic chemical interest as multidentate ligands has prompted a considerable increase in the study of their coordination behaviour. Development of a new chemotherapeutic Schiff bases and their metal complexes is now attracting the attention of medicinal chemists. This review compiles examples of the most promising applied Schiff bases and their complexes in different areas.

  9. Multi-complexity ensemble measures for gait time series analysis: application to diagnostics, monitoring and biometrics.

    Science.gov (United States)

    Gavrishchaka, Valeriy; Senyukova, Olga; Davis, Kristina

    2015-01-01

    Previously, we have proposed to use complementary complexity measures discovered by boosting-like ensemble learning for the enhancement of quantitative indicators dealing with necessarily short physiological time series. We have confirmed robustness of such multi-complexity measures for heart rate variability analysis with the emphasis on detection of emerging and intermittent cardiac abnormalities. Recently, we presented preliminary results suggesting that such ensemble-based approach could be also effective in discovering universal meta-indicators for early detection and convenient monitoring of neurological abnormalities using gait time series. Here, we argue and demonstrate that these multi-complexity ensemble measures for gait time series analysis could have significantly wider application scope ranging from diagnostics and early detection of physiological regime change to gait-based biometrics applications.

  10. New trends in the optical and electronic applications of polymers containing transition-metal complexes.

    Science.gov (United States)

    Liu, Shu-Juan; Chen, Yang; Xu, Wen-Juan; Zhao, Qiang; Huang, Wei

    2012-04-13

    Polymers containing transition-metal complexes exhibit excellent optical and electronic properties, which are different from those of polymers with a pure organic skeleton and combine the advantages of both polymers and metal complexes. Hence, research about this class of polymers has attracted more and more interest in recent years. Up to now, a number of novel polymers containing transition-metal complexes have been exploited, and significant advances in their optical and electronic applications have been achieved. In this article, we summarize some new research trends in the applications of this important class of optoelectronic polymers, such as chemo/biosensors, electronic memory devices and photovoltaic devices. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Functional proteomic of Matrix Metallo-proteinases (MMP) dedicated to the detection of active forms of MMP in complex proteome; Proteomique fonctionnelle dediee aux Metalloproteases Matricelles (MMPs): developpement d'une methode extremement sensible permettant la detection des formes actives des MMPs dans des proteomes complexes

    Energy Technology Data Exchange (ETDEWEB)

    David, A

    2007-07-15

    The Matrix Metallo-proteinases (M.M.P.) represent a family of Zinc dependent extracellular proteinases able to cleave collectively all the proteins constituting the extracellular matrix. Currently, 23 human M.M.P. have been identified and are characterized by their sequence in amino-acids and their highly conserved 3 D structure. These enzymes are expressed constitutively during the tissue remodeling process. Their over-expression in various diseases tightly related to inflammatory processes (arthritis, emphysema, cancer) described M.M.P. as choice therapeutic targets. However, as the tissue remodeling implicates modification of cellular contacts, M.M.P. appear currently as proteins involved in signalling pathways. Recent works demonstrating that M.M.P. are able to cleave substrates, which are different than proteins constituting the extracellular matrix, reinforce this vision. In order to identify the individual role and the protein expression level of M.M.P. in pathological context, we developed a new technique of functional proteomics dedicated to the detection of active forms of M.M.P. in tumour samples. This technique relied on the development of a new photoaffinity probe, based on the structure of a potent phosphinic inhibitor of M.M.P., allowing targeting and isolating active forms of M.M.P. by photoaffinity labelling. Furthermore, as the new developed probe incorporated a radioactive element, photoaffinity labelling permitted to radiolabel the targeted proteins. This probe demonstrated in vitro its remarkable ability to covalently modify the h M.M.P.-12, with a singular cross-linking yield, determined at 42 %, displaying an extremely sensitive detection (2.5 fmoles of h M.M.P.-12). When added to complex proteome, the photoaffinity probe presents the same sensibility of detection for the h M.M.P.-12 (5 fmoles); importantly, in this case, h M.M.P.-12 represents only 0.001 % of the totality of the proteins present in the sample. Moreover, this technique allows

  12. Functional proteomic of Matrix Metallo-proteinases (MMP) dedicated to the detection of active forms of MMP in complex proteome; Proteomique fonctionnelle dediee aux Metalloproteases Matricelles (MMPs): developpement d'une methode extremement sensible permettant la detection des formes actives des MMPs dans des proteomes complexes

    Energy Technology Data Exchange (ETDEWEB)

    David, A

    2007-07-15

    The Matrix Metallo-proteinases (M.M.P.) represent a family of Zinc dependent extracellular proteinases able to cleave collectively all the proteins constituting the extracellular matrix. Currently, 23 human M.M.P. have been identified and are characterized by their sequence in amino-acids and their highly conserved 3 D structure. These enzymes are expressed constitutively during the tissue remodeling process. Their over-expression in various diseases tightly related to inflammatory processes (arthritis, emphysema, cancer) described M.M.P. as choice therapeutic targets. However, as the tissue remodeling implicates modification of cellular contacts, M.M.P. appear currently as proteins involved in signalling pathways. Recent works demonstrating that M.M.P. are able to cleave substrates, which are different than proteins constituting the extracellular matrix, reinforce this vision. In order to identify the individual role and the protein expression level of M.M.P. in pathological context, we developed a new technique of functional proteomics dedicated to the detection of active forms of M.M.P. in tumour samples. This technique relied on the development of a new photoaffinity probe, based on the structure of a potent phosphinic inhibitor of M.M.P., allowing targeting and isolating active forms of M.M.P. by photoaffinity labelling. Furthermore, as the new developed probe incorporated a radioactive element, photoaffinity labelling permitted to radiolabel the targeted proteins. This probe demonstrated in vitro its remarkable ability to covalently modify the h M.M.P.-12, with a singular cross-linking yield, determined at 42 %, displaying an extremely sensitive detection (2.5 fmoles of h M.M.P.-12). When added to complex proteome, the photoaffinity probe presents the same sensibility of detection for the h M.M.P.-12 (5 fmoles); importantly, in this case, h M.M.P.-12 represents only 0.001 % of the totality of the proteins present in the sample. Moreover, this technique allows

  13. Computational Redox Potential Predictions: Applications to Inorganic and Organic Aqueous Complexes, and Complexes Adsorbed to Mineral Surfaces

    Directory of Open Access Journals (Sweden)

    Krishnamoorthy Arumugam

    2014-04-01

    Full Text Available Applications of redox processes range over a number of scientific fields. This review article summarizes the theory behind the calculation of redox potentials in solution for species such as organic compounds, inorganic complexes, actinides, battery materials, and mineral surface-bound-species. Different computational approaches to predict and determine redox potentials of electron transitions are discussed along with their respective pros and cons for the prediction of redox potentials. Subsequently, recommendations are made for certain necessary computational settings required for accurate calculation of redox potentials. This article reviews the importance of computational parameters, such as basis sets, density functional theory (DFT functionals, and relativistic approaches and the role that physicochemical processes play on the shift of redox potentials, such as hydration or spin orbit coupling, and will aid in finding suitable combinations of approaches for different chemical and geochemical applications. Identifying cost-effective and credible computational approaches is essential to benchmark redox potential calculations against experiments. Once a good theoretical approach is found to model the chemistry and thermodynamics of the redox and electron transfer process, this knowledge can be incorporated into models of more complex reaction mechanisms that include diffusion in the solute, surface diffusion, and dehydration, to name a few. This knowledge is important to fully understand the nature of redox processes be it a geochemical process that dictates natural redox reactions or one that is being used for the optimization of a chemical process in industry. In addition, it will help identify materials that will be useful to design catalytic redox agents, to come up with materials to be used for batteries and photovoltaic processes, and to identify new and improved remediation strategies in environmental engineering, for example the

  14. The study by means of a photomultiplier of the scintillations produced by {alpha} particles striking a zinc sulphide screen; Etude, au photomultiplicateur, des scintillations produites par les particules {alpha} dans un ecran de sulfure de zinc. Application a la numeration precise des particules {alpha}

    Energy Technology Data Exchange (ETDEWEB)

    Anthony, J P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1955-06-15

    The object of the study is the accurate counting of {alpha} particles by p-m. detection of their scintillations upon impact with a zinc sulphide screen. The main advantage of the method is the extreme simplicity of the electronics used: the possibility of obtaining a utilizable pulse from the p-m. (EMI5311) without any amplification, and in linear response, is demonstrated. The scintillation produced by an impact on Zn-S has also been studied experimentally. The decrease of light intensity in relation to time may be interpreted by the exponential relation: I = I{sub 0} exp (-t / {tau}) whereby {tau} = (39 {+-} 0,1) 10{sup -6} s. The relation between scintillation intensity and remaining trajectory after travel through a given air-space has also been determined. Possible suitable applications of this method of {alpha} counting are those where good stability and low background are necessary. Results stated bear on air contamination studies, isotopic composition variation measurement of uranium, bismuth content measurement in alloys by irradiation of specimens in a thermal neutron flux and {alpha} count on the Po formed. (author) [French] Ce travail est consacre a l'etude de la numeration precise des particules {alpha} par detection au photomultiplicateur des scintillations produites par ces particules dans un ecran de sulfure de zinc. Le principal avantage de cette methode reside dans l'extreme simplicite de l'appareillage electronique; il est en effet montre qu'il est possible, tout en convoyant une reponse lineaire, d'obtenir du photomultiplicateur (EMI5311) un signal electrique utilisable sans aucune amplification. La scintillation produite par l'impact des particules {alpha} sur un ecran de Zn-S est etudiee experimentalement. La decroissance de l'intensite lumineuse en fonction du temps est interpretable par la relation exponentielle I = I{sub 0} exp (-t / {tau}) avec {tau} = (39 {+-} 0,1) 10{sup -6} s. La relation entre l'intensite de la scintillation et le

  15. Application of Intervention Mapping to the Development of a Complex Physical Therapist Intervention.

    Science.gov (United States)

    Jones, Taryn M; Dear, Blake F; Hush, Julia M; Titov, Nickolai; Dean, Catherine M

    2016-12-01

    Physical therapist interventions, such as those designed to change physical activity behavior, are often complex and multifaceted. In order to facilitate rigorous evaluation and implementation of these complex interventions into clinical practice, the development process must be comprehensive, systematic, and transparent, with a sound theoretical basis. Intervention Mapping is designed to guide an iterative and problem-focused approach to the development of complex interventions. The purpose of this case report is to demonstrate the application of an Intervention Mapping approach to the development of a complex physical therapist intervention, a remote self-management program aimed at increasing physical activity after acquired brain injury. Intervention Mapping consists of 6 steps to guide the development of complex interventions: (1) needs assessment; (2) identification of outcomes, performance objectives, and change objectives; (3) selection of theory-based intervention methods and practical applications; (4) organization of methods and applications into an intervention program; (5) creation of an implementation plan; and (6) generation of an evaluation plan. The rationale and detailed description of this process are presented using an example of the development of a novel and complex physical therapist intervention, myMoves-a program designed to help individuals with an acquired brain injury to change their physical activity behavior. The Intervention Mapping framework may be useful in the development of complex physical therapist interventions, ensuring the development is comprehensive, systematic, and thorough, with a sound theoretical basis. This process facilitates translation into clinical practice and allows for greater confidence and transparency when the program efficacy is investigated. © 2016 American Physical Therapy Association.

  16. Consumption estimation in system design for real time embedded applications; Estimation de la consommation dans la conception systeme des applications embarquees temps reel

    Energy Technology Data Exchange (ETDEWEB)

    Laurent, J.

    2002-12-15

    Today, power and energy consumption have become, as time and area, an important constraint when you design a system. Indeed modern applications use more and more processing and memory resources so these lead a significant increase of consumption. Furthermore, embedded software impact is preponderant in real time system so the code optimisation has a great impact onto the consumption constraint. Several research teams have already developed estimation methodologies for processor but almost are at instruction level (ILPA). With this kind of method you have to measure the consumption of each instruction of the instruction set and also the inter-instruction consumption overhead. For complex architecture, this kind of methodology is not adapted due to the prohibitive number of consumption measures. So the characterisation time of this kind of architecture is too important furthermore with this method is very difficult to take into account the external environment. For actual architecture another method is needed to reduce the characterisation time while preserving the accuracy. The reduction of the characterisation time have to be realized by increasing the abstraction level. So, we propose here a new approach based on a functional and architectural analysis of the target in consumption point of view (FLPA). Our methodology has two steps: the first one is a modeling step and the second is estimation step. (author)

  17. Photogrammetric Recording in a Context of Preventive Archaeology : the "Place des Martyrs" Excavation (Algiers, Algeria)

    OpenAIRE

    SEGUIN, Maxime; Souq, François; Stiti, Kemal

    2014-01-01

    International audience; The construction of the underground station called Place des Martyrs in Algiers required preventive excavation. The context led us to favour recording methods leading to the rapid and exhaustive acquisition of data. Indeed digital photogrammetry made it possible to measure complex elements simply and rapidly. The originality of the solution implemented resided in the use of a free and open-source applications suite dedicated to scientific usage and making it possible t...

  18. Decompositions of the polyhedral product functor with applications to moment-angle complexes and related spaces.

    Science.gov (United States)

    Bahri, A; Bendersky, M; Cohen, F R; Gitler, S

    2009-07-28

    This article gives a natural decomposition of the suspension of a generalized moment-angle complex or partial product space which arises as the polyhedral product functor described below. The introduction and application of the smash product moment-angle complex provides a precise identification of the stable homotopy type of the values of the polyhedral product functor. One direct consequence is an analysis of the associated cohomology. For the special case of the complements of certain subspace arrangements, the geometrical decomposition implies the homological decomposition in earlier work of others as described below. Because the splitting is geometric, an analogous homological decomposition for a generalized moment-angle complex applies for any homology theory. Implied, therefore, is a decomposition for the Stanley-Reisner ring of a finite simplicial complex, and natural generalizations.

  19. An Appraisal of Analytical Methods for Plutonium and their Applications to the Analysis of Nuclear Materials; Evaluation des Methodes Analytiques de Dosage du Plutonium et de Leur Application a l'Analyse des Matieres Nucleaires; Otsenka analiticheskikh metodov opredeleniya plutoniya i ikh primenenie dlya analiza yadernykh materialov; Metodos Analiticos de Determinacion del Plutonio y su Empleo en el Analisis de Materiales Nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Milner, G. W.C.; Phillips, G. [Atomic Energy Research Establishment, Harwell, Berks. (United Kingdom)

    1966-02-15

    programmes for new nuclear fuels. (author) [French] Il existe plusieurs methodes de dosage de la teneur en plutonium des matieres nucleaires. Pour les quantites de l'ordre du milligramme, les methodes utilisables sont la spectro- photometiie differentielle fondee sur la couleur de Pu (III), la gravimetrie fondee sur PuO{sub 2}, le comptage gamma et les methodes de reduction/oxydation comprenant les titrages poientiometriques et amperemetriques et la coulombmetrie a potentiel constant. Pour les quantites de Tordre du microgramme, le comptage alpha, la dilution isotopique et les methodes polarigraphiques sont a utiliser. Certaines methodes conviennent mieux que d'autres a des types determines d'echantillons et l'analyste soucieux d'obtenir les meilleurs resultats se heurte a un choix difficile. Les auteurs exposent les avantages et les inconvenients des methodes citees tels qu'ils se sont degages de l'experience acquise au cours des annees a l'Atomic Energy Research Establishment, et ils discutent l'exactitude, la precision, la sensibilite de ces methodes, et d'autres caracteristiques presentant un interet particulier. Certaines methodes ne peuvent etre utilisees si l'on n'a, dans une certaine mesure, separe le plutonium des autres constituants de l'echantillon et le memoire commente l'experience acquise avec l'echange d'anions et les procedes de chromatographie a phase inversee utilises a cette fin, en insistant surtout sur la mesure dans laquelle cette methode convient aux echantillons radioactifs. Les auteurs etudient en outre les nombreux problemes qui se sont poses lors de l'application (d'ailleurs couronnee de succes) de ces methodes a l'analyse des alliages de plutonium, des ceramiques et des cermets dans differentes combinaisons contenant de l'uranium, du thorium, du fer, du chrome, du molybdene, du cerium et du cobalt. Us exposent les difficultes de la dissolution des echantillons et de la reduction du plutonium a l'etat de valence voulu, ainsi que les avantages

  20. Impact de la preparation des anodes crues et des conditions de cuisson sur la fissuration dans des anodes denses

    Science.gov (United States)

    Amrani, Salah

    classifier les differentes fissurations en plusieurs categories en se basant sur certains criteres tels que le type de fissures (horizontale, verticale et inclinee), leurs localisations longitudinales (bas, milieu et haut de l'anode) et transversales (gauche, centrale et droite). Les effets de la matiere premiere, les parametres de fabrication des anodes crues ainsi que les conditions de cuisson sur la fissuration ont ete etudies. La fissuration des anodes denses en carbones cause un serieux probleme pour l'industrie d'aluminium primaire. La realisation de ce projet a permis la revelation de differents mecanismes de fissuration, la classification de fissuration par plusieurs criteres (position, types localisation) et l'evaluation de l'impact de differents parametres sur la fissuration. Les etudes effectuees dans le domaine de cuisson ont donne la possibilite d'ameliorer l'operation et reduire la fissuration des anodes. Le travail consiste aussi a identifier des techniques capables d'evaluer la qualite d'anodes (l'ultrason, la tomographie et la distribution de la resistivite electrique). La fissuration des anodes en carbone est consideree comme un probleme complexe, car son apparition depend de plusieurs parametres repartis sur toute la chaine de production. Dans ce projet, plusieurs nouvelles etudes ont ete realisees, et elles permettent de donner de l'originalite aux travaux de recherches faits dans le domaine de la fissuration des anodes de carbone pour l'industrie de l'aluminium primaire. Les etudes realisees dans ce projet permettent d'ajouter d'un cote, une valeur scientifique pour mieux comprendre le probleme de fissuration des anodes et d'un autre cote, d'essayer de proposer des methodes qui peuvent reduire ce probleme a l'echelle industrielle.

  1. De l’oléochimie à la bioraffinerie : continuité de développement pour le secteur des corps gras ?

    Directory of Open Access Journals (Sweden)

    Rous Jean-François

    2016-09-01

    Full Text Available L’oléochimie est une science très ancienne dont l’objectif est de transformer les corps gras animaux ou les huiles végétales pour produire des molécules chimiques, telles que des alcools gras, des acides gras, des esters plus ou moins complexes, entrant dans de multiples applications telles que les savons, les lubrifiants, les tensio-actifs, les agents de rhéologie, et bien d’autres applications. Depuis le début des années 90, grâce au développement des technologies et notamment à la transposition dans le domaine des huiles et corps gras de technologies préalablement développées pour la pétrochimie (comme la métathèse par exemple (Poels EK, Moulijn JA, Sibeijn MJ. 1994. Am. Oil Chem. Soc. 71 : 553, cette science évolue pour produire des molécules de plus en plus complexes, et notamment des intermédiaires de synthèse qui entrent dans la préparation de polymères (par exemple des acides dimères, ou des diacides, qui sont modifiés -ou pas- en diols ou diamines ou autres molécules bifonctionnelles de type amino-acides. La bioraffinerie quant à elle, à l’instar de la raffinerie, vise à développer le meilleur usage possible des différentes fractions d’une plante. Le premier exemple (et meilleur à ce jour est l’amidonnerie, qui au-delà du développement des dérivés de l’amidon, fractionne complètement la graine de blé ou de maïs afin d’en tirer le maximum de valeur possible. Bien qu’un certain nombre de développements aient été menés depuis quelques années, les unités de trituration et raffinage des graines oléagineuses sont encore loin de s’apparenter à ce degré de fractionnement. L’objectif de cet article est de montrer que même si les développements successifs des usages faisables à partir des corps gras et des huiles ont suivi des choix parfois politiques, il n’en reste pas moins que ces choix ne peuvent être considérés que comme des « déclencheurs » et qu’à termes c

  2. Study of deuterons induced nuclear reactions on light elements (N, Al and Si): Application to containment materials of radioactive wastes; Etude des reactions nucleaires induites par des deuterons sur des elements legers (N, Al, Si): application aux materiaux de confinement des dechets radioactifs

    Energy Technology Data Exchange (ETDEWEB)

    Pellegrino, St

    2004-03-01

    Nuclear reaction analysis is well adapted to the quantification of light element. Profiles of concentration in order to follow elements migration into materials can be undertaken. This technique is used to study the behavior of the future matrices for nuclear waste containment. This technique is isotopic, characterized by a good signal-to-background ratio and a very low detection limit. The probability of a nuclear reaction is linked to a parameter called 'cross section' we have to know in order to carry out quantitative analysis. We have determined excitation curves for nitrogen, aluminium and silicon. These experiments were done with deuterons from 0.5 to 2 MeV. Two methods for the cross section characterization are presented and are in agreement with each other. The second one reduces uncertainty. Data are incorporated in the simulation software SIMNRA. We have compared the results obtained on different samples when we use data in literature or data of the study. We have noticed a great fit improvement with the data of this study. The new cross sections of this work will be integrated in the general data base SIGMABASE. Applications on materials such as Si{sub 3}N{sub 4}, nano-metric powders, WCN and nuclear glass YLaMgSiAlON studied for radioactive waste containment are also presented. (author)

  3. Anatomy of the cerebellopontine angle; Anatomie des Kleinhirnbrueckenwinkels

    Energy Technology Data Exchange (ETDEWEB)

    Grunwald, I.Q.; Papanagiotou, P.; Politi, M.; Reith, W. [Universitaetsklinikum des Saarlandes, Homburg/Saar (Germany). Klinik fuer Diagnostische und Interventionelle Neuroradiologie; Nabhan, A. [Universitaetsklinikum des Saarlandes, Homburg/Saar (Germany). Neurochirurgische Klinik

    2006-03-15

    The cerebellopontine angle (CPA) is an anatomically complex region of the brain. In this article we describe the anatomy of the CPA cisterns, of the internal auditory canal, the topography of the cerebellum and brainstem, and the neurovascular structures of this area. (orig.) [German] Der Kleinhirnbrueckenwinkel ist eine umschriebene anatomische Region. Im diesem Artikel werden die Subarachnoidalraeume im Kleinhirnbrueckenwinkel, die Anatomie der Felsenbeinflaeche, Anatomie und Topographie des Kleinhirns und des Hirnstamms, die arteriellen Beziehungen und venoese Drainage des Kleinhirnbrueckenwinkels besprochen. (orig.)

  4. Civili, langue des Baloango

    DEFF Research Database (Denmark)

    Mavoungou, Paul Achille; Ndinga-Koumba-Binza, Hugues Steve

    , Congo, Angola, etc.) issus de la décolonisation. Il présente de façon succincte quelques phénomènes historiques, phonologiques, morphosyntaxiques, homonymiques et analogiques de la langue. Des faits sémantiques des emprunts linguistiques y sont également décrits dans le cadre des changements...

  5. Development and application of incrementally complex tools for wind turbine aerodynamics

    Science.gov (United States)

    Gundling, Christopher H.

    Advances and availability of computational resources have made wind farm design using simulation tools a reality. Wind farms are battling two issues, affecting the cost of energy, that will make or break many future investments in wind energy. The most significant issue is the power reduction of downstream turbines operating in the wake of upstream turbines. The loss of energy from wind turbine wakes is difficult to predict and the underestimation of energy losses due to wakes has been a common problem throughout the industry. The second issue is a shorter lifetime of blades and past failures of gearboxes due to increased fluctuations in the unsteady loading of waked turbines. The overall goal of this research is to address these problems by developing a platform for a multi-fidelity wind turbine aerodynamic performance and wake prediction tool. Full-scale experiments in the field have dramatically helped researchers understand the unique issues inside a large wind farm, but experimental methods can only be used to a limited extent due to the cost of such field studies and the size of wind farms. The uncertainty of the inflow is another inherent drawback of field experiments. Therefore, computational fluid dynamics (CFD) predictions, strategically validated using carefully performed wind farm field campaigns, are becoming a more standard design practice. The developed CFD models include a blade element model (BEM) code with a free-vortex wake, an actuator disk or line based method with large eddy simulations (LES) and a fully resolved rotor based method with detached eddy simulations (DES) and adaptive mesh refinement (AMR). To create more realistic simulations, performance of a one-way coupling between different mesoscale atmospheric boundary layer (ABL) models and the three microscale CFD solvers is tested. These methods are validated using data from incrementally complex test cases that include the NREL Phase VI wind tunnel test, the Sexbierum wind farm and the

  6. Perancangan Enkripsi Pada Citra Bitmap Dengan Algoritma Des, Triple Des, dan Idea

    Directory of Open Access Journals (Sweden)

    Agustinna Yosanny

    2010-12-01

    Full Text Available Rapid development of Information Technology causes information can access easier without space boundaries. Image is a form of information, which contains many information. Some image contains confidential information that cannot distribute to unauthorized persons. Therefore, image encryption application is create to encrypt part of image that has confidential information. The image encryption application is encrypt image by applying DES, Triple DES, and IDEA algorithms. The research was applying analysis and design methodology. The analysis methodology was undertaken through literature study and algorithm research and testing. The design methodology was undertaken through database, features, system, and screen layout design. Results of the research are image encryption application that can encrypt part of image and or all of image by applying three algorithms such as DES, Triple DES, and IDEA. This application is show comparation of these algorithms. In conclusion, method of encryption can apply to image, so that confidential information of the image can protect from unauthorized person. 

  7. Utilisation des mousses et des pâtes syntactiques pour combler les lacunes des poteries archéologiques

    Directory of Open Access Journals (Sweden)

    Viviane Bechoux

    2008-10-01

    Full Text Available Filling potteries missing parts with plaster raises now complex problems during the de-restoration treatments. Ceramics restorers have recurrently questions on the use of plaster in the field of archaeological ceramics restoration. Some researches point to the choice of other filling materials. At the present time other methods can be devised by proposing plaster replacement by a lightened composite material: syntactic foams and pastes.Le comblement des lacunes des poteries à partir du plâtre pose actuellement des problèmes complexes lors des traitements de dérestauration. Les restaurateurs de céramiques s'interrogent de manière récurrente sur l'utilisation du plâtre dans le domaine de la restauration des céramiques archéologiques. Des recherches s'orientent vers le choix d'autres matériaux d'obturation. Actuellement, d'autres méthodes peuvent être mises en place en proposant le remplacement du plâtre par un matériau composite allégé, les mousses et les pâtes syntactiques.

  8. Des racines et des ailes

    Directory of Open Access Journals (Sweden)

    Stéphanie Vincent-Geslin

    2012-05-01

    Full Text Available Les mobilités pendulaires semblent être en augmentation en Europe depuis une dizaine d’années. Cette croissance du temps passé à se déplacer amène à remettre en question la conjecture de Zahavi et apparaît relativement inexplicable en regard du paradigme classique de l’acteur rationnel traditionnellement utilisé dans le champ des transports. Si, dans la littérature, les temps de déplacements sont principalement expliqués par le contexte résidentiel, la forme urbaine et le travail, ce cadre explicatif ne dit rien des processus de décision eux-mêmes qui amènent aux pendularités intensives.À partir d’une enquête qualitative menée auprès de pendulaires français, suisses et belges, cette contribution propose d’analyser les arbitrages et les éléments déterminants des processus de la grande pendularité. Les mobilités quotidiennes pendulaires apparaissent comme le résultat de compromis entre activité professionnelle, attachement résidentiel et choix de vie et prennent ainsi la forme de stratégies de conciliation entre vie privée et vie professionnelle. Ces mobilités spatiales permettent alors paradoxalement la préservation des ancrages résidentiels, sociaux et familiaux.Roots and wings. Long-distance commuting patterns, or how to conciliate professional and personal lifeLong-distance commuting patterns appear to be increasing in Europe over the last ten years. These raising mobility patterns lead to reappraise the Zahavi conjecture and appear largely inexplicable by the classical rational actor paradigm traditionally used in transportation research. In literature, commuting is mainly explained by residential contexts, urban forms and job. Nevertheless this theoretical frame says little about the decision-making processes themselves. Based on a qualitative survey conducted in three European countries - France, Belgium and Switzerland – among a population of high commuters, this paper proposes an analysis of

  9. Automation of ultrasonic testing, instrumentation and rules for application and evaluation. Proceedings; Automatisierung der Ultraschallpruefung, Geraetetechnik und Regeln zur Anwendung und Auswertung. Vortraege des Seminars

    Energy Technology Data Exchange (ETDEWEB)

    Wuestenberg, H. [comp.

    1997-12-31

    The proceedings volume contains 18 lectures of the seminar addressing the following (selected) aspects: Requirements to be met by PC cards for US testing applications, defined by producers and appliers; digital technology and its impact on multichannel US testing instruments; the ALOK and array systems combined into one very efficient testing system (SAPHIR); a testing system combining US radiation source arrays and the pulsed eddy current method by means of highly integrated microelectronics (ASICs); regulatory standards and specifications for automated US testing; requirements for automated US testing in compliance with nuclear engineering codes; state of the art in standardisation for definition of required properties of US testing systems; critical review of the proposed standard relating to the TOFD method; automated evaluation shown with the example of US testing of pipelines. (orig./CB) [Deutsch] Dieser Band enthaelt 18 Vortraege mit folgenden Themen (Auswahl): Anforderungen an Ultraschall-PC-Karten aus der Sicht von Hersteller und Betreiber; Einfluss der Digitaltechnik auf Mehrkanal-Ultraschall-Pruefanlagen; Vereinigung der ALOK- und der Gruppenstrahler-Technik in einem leistungsfaehigen Pruefsystem (SAPHIR); Ein kombiniertes Pruefsystem fuer die Ultraschall-Gruppenstrahler- und Impuls-Wirbelstrom-Technik auf der Basis von hochintegrierter Mikroelektronik (ASICs); Regelwerke und Spezifikationen fuer die automatisierte Ultraschallpruefung; Anforderungen der kerntechnischen Regelwerke an die automatisierte Ultraschallpruefung; Stand der Normung bei der Charakterisierung der Eigenschaften von Ultraschall-Pruefsystemen; Kritische Bewertung des Normungsvorschlages zur Beugungslaufzeittechnik (TOFD); und Automatisierte Auswertung am Beispiel der Ultraschallpruefung von Fernrohrleitungen. (orig.)

  10. Fluctuations Magnetiques des Gaz D'electrons Bidimensionnels: Application AU Compose Supraconducteur LANTHANE(2-X) Strontium(x) Cuivre OXYGENE(4)

    Science.gov (United States)

    Benard, Pierre

    Nous presentons une etude des fluctuations magnetiques de la phase normale de l'oxyde de cuivre supraconducteur La_{2-x}Sr _{x}CuO_4 . Le compose est modelise par le Hamiltonien de Hubbard bidimensionnel avec un terme de saut vers les deuxiemes voisins (modele tt'U). Le modele est etudie en utilisant l'approximation de la GRPA (Generalized Random Phase Approximation) et en incluant les effets de la renormalisation de l'interaction de Hubbard par les diagrammes de Brueckner-Kanamori. Dans l'approche presentee dans ce travail, les maximums du facteur de structure magnetique observes par les experiences de diffusion de neutrons sont associes aux anomalies 2k _{F} de reseau du facteur de structure des gaz d'electrons bidimensionnels sans interaction. Ces anomalies proviennent de la diffusion entre particules situees a des points de la surface de Fermi ou les vitesses de Fermi sont tangentes, et conduisent a des divergences dont la nature depend de la geometrie de la surface de Fermi au voisinage de ces points. Ces resultats sont ensuite appliques au modele tt'U, dont le modele de Hubbard usuel tU est un cas particulier. Dans la majorite des cas, les interactions ne determinent pas la position des maximums du facteur de structure. Le role de l'interaction est d'augmenter l'intensite des structures du facteur de structure magnetique associees a l'instabilite magnetique du systeme. Ces structures sont souvent deja presentes dans la partie imaginaire de la susceptibilite sans interaction. Le rapport d'intensite entre les maximums absolus et les autres structures du facteur de structure magnetique permet de determiner le rapport U_ {rn}/U_{c} qui mesure la proximite d'une instabilite magnetique. Le diagramme de phase est ensuite etudie afin de delimiter la plage de validite de l'approximation. Apres avoir discute des modes collectifs et de l'effet d'une partie imaginaire non-nulle de la self-energie, l'origine de l'echelle d'energie des fluctuations magnetiques est examinee

  11. Ruthenium (II) complexes of thiosemicarbazone: Synthesis, biosensor applications and evaluation as antimicrobial agents

    Energy Technology Data Exchange (ETDEWEB)

    Yildirim, Hatice [Dokuz Eylul University, The Graduate School of Natural and Applied Sciences, Department of Chemistry, 35160 Buca, Izmir (Turkey); Guler, Emine [Ege University, Faculty of Science, Department of Biochemistry, 35100 Bornova, Izmir (Turkey); Yavuz, Murat, E-mail: myavuz@dicle.edu.tr [Ege University, Faculty of Science, Department of Biochemistry, 35100 Bornova, Izmir (Turkey); Dicle University, Faculty of Science, Department of Chemistry, 21280 Diyarbakir (Turkey); Ozturk, Nurdan; Kose Yaman, Pelin [Dokuz Eylul University, The Graduate School of Natural and Applied Sciences, Department of Chemistry, 35160 Buca, Izmir (Turkey); Subasi, Elif; Sahin, Elif [Dokuz Eylul University, Faculty of Science, Department of Chemistry, 35160 Buca, Izmir (Turkey); Timur, Suna [Ege University, Faculty of Science, Department of Biochemistry, 35100 Bornova, Izmir (Turkey); Ege University, Institute on Drug Abuse, Toxicology and Pharmaceutical Science (BATI), 35100 Bornova, Izmir (Turkey)

    2014-11-01

    A conformationally rigid half-sandwich organoruthenium (II) complex [(η{sup 6}-p-cymene)RuClTSC{sup N–S}]Cl, (1) and carbonyl complex [Ru(CO)Cl(PPh{sub 3}){sub 2}TSC{sup N–S}] (2) have been synthesized from the reaction of [{(η"6-p-cymene)RuCl}{sub 2}(μ-Cl){sub 2}] and [Ru(H)(Cl)(CO)(PPh{sub 3}){sub 3}] with thiophene-2-carboxaldehyde thiosemicarbazon (TSC) respectively and both novel ruthenium (II) complexes have been characterized by elemental analysis, FT-IR and NMR spectroscopy. The peripheral TSC in the complexes acts as an electrochemical coupling unit providing the ability to carry out electrochemical deposition (ED) and to form an electro-deposited film on a graphite electrode surface. The biosensing applicability of complexes 1 and 2 was investigated by using glucose oxidase (GOx) as a model enzyme. Electrochemical measurements at − 0.9 V versus Ag/AgCl electrode by following the ED Ru(II) reduction/oxidation due to from the enzyme activity, in the presence of glucose substrate. The designed biosensor showed a very good linearity for 0.01–0.5 mM glucose. The in vitro antimicrobial activities of complexes 1 and 2 were also investigated against nine bacterial strains and one fungus by the disc diffusion test method. No activity was observed against the Gram-negative strains and fungus, whereas complex 1 showed moderate antibacterial activities against Gram-positive bacterial strains. - Highlights: • Novel Ru (II) thiosemicarbazone complexes were synthesized and characterized. • Electrochemical depositions were performed. • Rigid half-sandwich Ru (II) complex showed enhanced antibacterial activity.

  12. Ruthenium (II) complexes of thiosemicarbazone: Synthesis, biosensor applications and evaluation as antimicrobial agents

    International Nuclear Information System (INIS)

    Yildirim, Hatice; Guler, Emine; Yavuz, Murat; Ozturk, Nurdan; Kose Yaman, Pelin; Subasi, Elif; Sahin, Elif; Timur, Suna

    2014-01-01

    A conformationally rigid half-sandwich organoruthenium (II) complex [(η 6 -p-cymene)RuClTSC N–S ]Cl, (1) and carbonyl complex [Ru(CO)Cl(PPh 3 ) 2 TSC N–S ] (2) have been synthesized from the reaction of [{(η 6 -p-cymene)RuCl} 2 (μ-Cl) 2 ] and [Ru(H)(Cl)(CO)(PPh 3 ) 3 ] with thiophene-2-carboxaldehyde thiosemicarbazon (TSC) respectively and both novel ruthenium (II) complexes have been characterized by elemental analysis, FT-IR and NMR spectroscopy. The peripheral TSC in the complexes acts as an electrochemical coupling unit providing the ability to carry out electrochemical deposition (ED) and to form an electro-deposited film on a graphite electrode surface. The biosensing applicability of complexes 1 and 2 was investigated by using glucose oxidase (GOx) as a model enzyme. Electrochemical measurements at − 0.9 V versus Ag/AgCl electrode by following the ED Ru(II) reduction/oxidation due to from the enzyme activity, in the presence of glucose substrate. The designed biosensor showed a very good linearity for 0.01–0.5 mM glucose. The in vitro antimicrobial activities of complexes 1 and 2 were also investigated against nine bacterial strains and one fungus by the disc diffusion test method. No activity was observed against the Gram-negative strains and fungus, whereas complex 1 showed moderate antibacterial activities against Gram-positive bacterial strains. - Highlights: • Novel Ru (II) thiosemicarbazone complexes were synthesized and characterized. • Electrochemical depositions were performed. • Rigid half-sandwich Ru (II) complex showed enhanced antibacterial activity

  13. Datamart use for complex data retrieval in an ArcIMS application

    Energy Technology Data Exchange (ETDEWEB)

    Scherma, S. (Steven); Bolivar, Stephen L.

    2004-01-01

    This paper describes the use of datamarts and data warehousing concepts to expedite retrieval and display of complex attribute data from multi-million record databases. Los Alamos National Laboratory has developed an Internet application (SMART) using ArcIMS that relies on datamarts to quickly retrieve attribute data, associated with, but not contained within GIS layers. The volume of data and the complex relationships within the transactional database made data display within ArcIMS impractical without the use of datamarts. The technical issues and solutions involved in the development are discussed.

  14. The thermodynamic approach of the pilot-scale purification of refractory metals; Application de la thermodynamique a la mise au point des methodes de purification industrielle des metaux et semi-metaux refractaires

    Energy Technology Data Exchange (ETDEWEB)

    Accary, A [Commissariat a l' Energie Atomique, Dir. des Piles Atomiques, Saclay (France). Centre d' Etudes Nucleaires

    1967-06-15

    The author shows how the thermodynamic can be applied to the prediction of the evolution of impurities from a metal or an alloy being melted and cast at the pilot-scale using electron bombardment and continuous casting in a water cooled copper. He studies this possibility on two examples: - the melting vanadium, - the melting of the uranium monocarbide. He shows using only the constants available in the literature and a few special runs in the pilot-equipment itself it is possible to determine: - the possibility of elimination of anyone impurity by keeping the material in the melting state under vacuum as well as the limit of purification which is achievable under given technological conditions, - the proportion of an impure metal which should be vaporized in order to bring the level of a given impurity down to a predetermined level and the necessary duration of heating. (author) [French] L'auteur montre comment la thermodynamique peut etre appliquee a la prevision de l'evolution d'un metal ou d'un alliage fondu a l'echelle pilote par bombardement d'electrons et coule en continu dans un creuset de cuivre refroidi. Il etudie cette possibilite sur deux cas particuliers: - la fusion de vanadium, - la fusion du monocarbure d'uranium. Il montre que, grace aux constantes disponibles dans la litterature et a des essais simples faits a l'aide de l'appareillage pilote lui-meme, on peut determiner: - la possibilite d'eliminer une impurete par maintien a l'etat fondu ainsi que la limite de purification dans des conditions technologiques donnees, - la proportion d'un metal brut qu'il faut evaporer pour amener sa teneur en une impurete a un niveau donne ainsi que la duree de chauffage necessaire, - la nature des additions propres a favoriser le depart d'une impurete et l'efficacite comparee des additions possibles. (auteur)

  15. Translocation of {sup 3}H-DNA, {sup 131}I-ribonuclease and {sup 3}H-DNA {sup 131}I-ribonuclease complexes in germinated barley grains; Translocation des ADN{sup 3}H, RNase{sup 131}I et complexes ADN{sup 3}H - RNase {sup 131}I dans les orges en germination

    Energy Technology Data Exchange (ETDEWEB)

    Tshitenge, G. [Centre nucléaire TRICO, Kinshasa (Congo, The Democratic Republic of the); Ledoux, L. [Centre d’étude de l' énergie nucléaire Mol (Belgium)

    1970-01-15

    Barley grains, after germinating for 11 hours in the presence of water, were cut into sections at the end opposite the embryo. They were incubated in solutions of {sup 3}H-DNA, {sup 13I}I-ribonuclease, and {sup 3}H-DNA {sup 131}I-ribonuclease complex for three hours. They were then placed in a water-saturated atmosphere for 24 hours. At this stage the different organs of the seedlings were separated and homogenized in a solution containing 0.15M sodium chloride and 0.1 M sodium ethylenediaminetetraacetate at pH 7. By measuring the radioactivity found in the homogenates one can estimate the penetration of the macromolecules under study. The results show that the quantity found varies from one case to the other and depends both on the nature of the macromolecule and of the organ studied. (author) [French] Des orges qui ont germé pendant 11 h en présence d’eau sont sectionnées au bout opposé à l’embryon. Elles sont incubées avec des solutions d’ADN{sup 3}H, de RNase{sup 131}1 et de complexe ADN{sup 3}H - RNase {sup 131}I, pendant 3 h. Elles sont ensuite placées dans une atmosphère saturée d'eau pendant 24 h. A ce moment, les différents organes des plantules sont séparés et homogénéisés en présence d'une solution 0,15M en NaCl et 0,1M en éthylènediamine-tétracétate de Na à pH 7. La mesure de la radioactivité retrouvée dans les homogénats permet d'évaluer la pénétration des macromolécules considérées. Les résultats montrent que la quantité retrouvée varie d'un cas â l'autre et dépend à la fois de la nature de la macromolécule et de l'organe considéré. (author)

  16. Parallelization of learning problems by artificial neural networks. Application in external radiotherapy; Parallelisation de problemes d'apprentissage par des reseaux neuronaux artificiels. Application en radiotherapie externe

    Energy Technology Data Exchange (ETDEWEB)

    Sauget, M

    2007-12-15

    This research is about the application of neural networks used in the external radiotherapy domain. The goal is to elaborate a new evaluating system for the radiation dose distributions in heterogeneous environments. The al objective of this work is to build a complete tool kit to evaluate the optimal treatment planning. My st research point is about the conception of an incremental learning algorithm. The interest of my work is to combine different optimizations specialized in the function interpolation and to propose a new algorithm allowing to change the neural network architecture during the learning phase. This algorithm allows to minimise the al size of the neural network while keeping a good accuracy. The second part of my research is to parallelize the previous incremental learning algorithm. The goal of that work is to increase the speed of the learning step as well as the size of the learned dataset needed in a clinical case. For that, our incremental learning algorithm presents an original data decomposition with overlapping, together with a fault tolerance mechanism. My last research point is about a fast and accurate algorithm computing the radiation dose deposit in any heterogeneous environment. At the present time, the existing solutions used are not optimal. The fast solution are not accurate and do not give an optimal treatment planning. On the other hand, the accurate solutions are far too slow to be used in a clinical context. Our algorithm answers to this problem by bringing rapidity and accuracy. The concept is to use a neural network adequately learned together with a mechanism taking into account the environment changes. The advantages of this algorithm is to avoid the use of a complex physical code while keeping a good accuracy and reasonable computation times. (author)

  17. Reduction of uranium and plutonium oxides by aluminum. Application to the recycling of plutonium; Reduction des oxydes d'uranium et de plutonium par l'aluminium application au recyclage du plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Gallay, J [Commissariat a l' Energie Atomique, Valduc (France). Centre d' Etudes

    1968-07-01

    A process for treating plutonium oxide calcined at high temperatures (1000 to 2000 deg. C) with a view to recovering the metal consists in the reduction of this oxide dissolved in a mixture of aluminium, sodium and calcium fluorides by aluminium at about 1180 deg. C. The first part of the report presents the results of reduction tests carried out on the uranium oxides UO{sub 2} and U{sub 3}O{sub 8}; these are in agreement with the thermodynamic calculations of the exchange reaction at equilibrium. The second part describes the application of this method to plutonium oxides. The Pu-Al alloy obtained (60 per cent Pu) is then recycled in an aqueous medium. (author) [French] Un procede de traitement de l'oxyde de plutonium calcine a haute temperature (1000 deg. C a 2000 deg. C), en vue de la recuperation du metal, consiste a reduire cet oxyde dissous dans un melange de fluorures d'aluminium, de sodium et de calcium, par l'aluminium vers 1180 deg. C. Une premiere partie du rapport presente les resultats des essais de reduction des oxydes d'uranium UO{sub 2} et U{sub 3}O{sub 8}, en accord avec les resultats du calcul thermodynamique de la reaction d'echange a l'equilibre. Une seconde partie rend compte de l'application de cette methode a l'oxyde de plutonium. L'alliage Pu-Al obtenu (60 pour cent Pu) est ensuite recycle par voie aqueuse. (auteur)

  18. Study of application technology of ultra-high speed computer to the elucidation of complex phenomena

    International Nuclear Information System (INIS)

    Sekiguchi, Tomotsugu

    1996-01-01

    The basic design of numerical information library in the decentralized computer network was explained at the first step of constructing the application technology of ultra-high speed computer to the elucidation of complex phenomena. Establishment of the system makes possible to construct the efficient application environment of ultra-high speed computer system to be scalable with the different computing systems. We named the system Ninf (Network Information Library for High Performance Computing). The summary of application technology of library was described as follows: the application technology of library under the distributed environment, numeric constants, retrieval of value, library of special functions, computing library, Ninf library interface, Ninf remote library and registration. By the system, user is able to use the program concentrating the analyzing technology of numerical value with high precision, reliability and speed. (S.Y.)

  19. Structure of simple liquids; Structure des liquides simples

    Energy Technology Data Exchange (ETDEWEB)

    Blain, J F [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-07-01

    The results obtained by application to argon and sodium of the two important methods of studying the structure of liquids: scattering of X-rays and neutrons, are presented on one hand. On the other hand the principal models employed for reconstituting the structure of simple liquids are exposed: mathematical models, lattice models and their derived models, experimental models. (author) [French] On presente d'une part les resultats obtenus par application a l'argon et au sodium des deux principales methodes d'etude de la structure des liquides: la diffusion des rayons X et la diffusion des neutrons; d'autre part, les principaux modeles employes pour reconstituer la structure des liquides simples sont exposes: modeles mathematiques, modeles des reseaux et modeles derives, modeles experimentaux. (auteur)

  20. Peptide-mediated vectorization of metal complexes: conjugation strategies and biomedical applications.

    Science.gov (United States)

    Soler, Marta; Feliu, Lidia; Planas, Marta; Ribas, Xavi; Costas, Miquel

    2016-08-16

    The rich chemical and structural versatility of transition metal complexes provides numerous novel paths to be pursued in the design of molecules that exert particular chemical or physicochemical effects that could operate over specific biological targets. However, the poor cell permeability of metallodrugs represents an important barrier for their therapeutic use. The conjugation between metal complexes and a functional peptide vector can be regarded as a versatile and potential strategy to improve their bioavailability and accumulation inside cells, and the site selectivity of their effect. This perspective lies in reviewing the recent advances in the design of metallopeptide conjugates for biomedical applications. Additionally, we highlight the studies where this approach has been directed towards the incorporation of redox active metal centers into living organisms for modulating the cellular redox balance, as a tool with application in anticancer therapy.

  1. Engineering a large application software project: the controls of the CERN PS accelerator complex

    International Nuclear Information System (INIS)

    Benincasa, G.P.; Daneels, A.; Heymans, P.; Serre, Ch.

    1985-01-01

    The CERN PS accelerator complex has been progressively converted to full computer controls without interrupting its full-time operation (more than 6000 hours per year with on average not more than 1% of the total down-time due to controls). The application software amounts to 120 man-years and 450'000 instructions: it compares with other large software projects, also outside the accelerator world: e.g. Skylab's ground support software. This paper outlines the application software structure which takes into account technical requirements and constraints (resulting from the complexity of the process and its operation) and economical and managerial ones. It presents the engineering and management techniques used to promote implementation, testing and commissioning within budget, manpower and time constraints and concludes with experience gained

  2. A survey of atmospheric dispersion models applicable to risk studies for nuclear facilities in complex terrain

    International Nuclear Information System (INIS)

    Wittek, P.

    1985-09-01

    Atmospheric dispersion models are reviewed with respect to their application to the consequence assessment within risk studies for nuclear power plants located in complex terrain. This review comprises: seven straight-line Gaussian models, which have been modified in order to take into account in a crude way terrain elevations, enhanced turbulence and some others effects; three trajectory/puff-models, which can handle wind direction changes and the resulting plume or puff trajectories; five three-dimensional wind field models, which calculate the wind field in complex terrain for the application in a grid model; three grid models; one Monte-Carlo-model. The main features of the computer codes are described, along with some informations on the necessary computer time and storage capacity. (orig.) [de

  3. High performance parallel computing of flows in complex geometries: II. Applications

    International Nuclear Information System (INIS)

    Gourdain, N; Gicquel, L; Staffelbach, G; Vermorel, O; Duchaine, F; Boussuge, J-F; Poinsot, T

    2009-01-01

    Present regulations in terms of pollutant emissions, noise and economical constraints, require new approaches and designs in the fields of energy supply and transportation. It is now well established that the next breakthrough will come from a better understanding of unsteady flow effects and by considering the entire system and not only isolated components. However, these aspects are still not well taken into account by the numerical approaches or understood whatever the design stage considered. The main challenge is essentially due to the computational requirements inferred by such complex systems if it is to be simulated by use of supercomputers. This paper shows how new challenges can be addressed by using parallel computing platforms for distinct elements of a more complex systems as encountered in aeronautical applications. Based on numerical simulations performed with modern aerodynamic and reactive flow solvers, this work underlines the interest of high-performance computing for solving flow in complex industrial configurations such as aircrafts, combustion chambers and turbomachines. Performance indicators related to parallel computing efficiency are presented, showing that establishing fair criterions is a difficult task for complex industrial applications. Examples of numerical simulations performed in industrial systems are also described with a particular interest for the computational time and the potential design improvements obtained with high-fidelity and multi-physics computing methods. These simulations use either unsteady Reynolds-averaged Navier-Stokes methods or large eddy simulation and deal with turbulent unsteady flows, such as coupled flow phenomena (thermo-acoustic instabilities, buffet, etc). Some examples of the difficulties with grid generation and data analysis are also presented when dealing with these complex industrial applications.

  4. MULTIENZYME COMPLEX APPLICATION WHEN RECEIVING OF ETHYL ALCOHOL FROM THE PROBLEM OF RAW MATERIAL

    Directory of Open Access Journals (Sweden)

    A. N. Yakovlev

    2012-01-01

    Full Text Available Influence of the complex enzyme preparation of Bruzaime BGX on viscosity of a rye batter was probed. Dynamics of accumulation of a weight fraction of dry and reducing materials in a batter, and also possibility of decrease in a dosage glucoamilase is shown at using of multienzymic complex at a stage of water-thermal processing. It was set that multienzymic complex application on stages of water-thermal processing allows to increase the glucose maintenance in a wort by 34,7 % in comparison with the control that raises an alcohol yield on 1,4 dal/tonn conditional starch, reduces duration of fermentation till 50-52 h and reduces the general screenings content in a fermented wash by 10 %.

  5. Complex Systems Models and Their Applications: Towards a New Science of Verification, Validation & Uncertainty Quantification

    Energy Technology Data Exchange (ETDEWEB)

    Tsao, Jeffrey Y. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Trucano, Timothy G. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Kleban, Stephen D. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Naugle, Asmeret Bier [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Verzi, Stephen Joseph [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Swiler, Laura Painton [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Johnson, Curtis M. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Smith, Mark A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Flanagan, Tatiana Paz [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Vugrin, Eric D. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Gabert, Kasimir Georg [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Lave, Matthew Samuel [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Chen, Wei [Northwestern Univ., Evanston, IL (United States); DeLaurentis, Daniel [Purdue Univ., West Lafayette, IN (United States); Hubler, Alfred [Univ. of Illinois, Urbana, IL (United States); Oberkampf, Bill [WLO Consulting, Austin, TX (United States)

    2016-08-01

    This report contains the written footprint of a Sandia-hosted workshop held in Albuquerque, New Mexico, June 22-23, 2016 on “Complex Systems Models and Their Applications: Towards a New Science of Verification, Validation and Uncertainty Quantification,” as well as of pre-work that fed into the workshop. The workshop’s intent was to explore and begin articulating research opportunities at the intersection between two important Sandia communities: the complex systems (CS) modeling community, and the verification, validation and uncertainty quantification (VVUQ) community The overarching research opportunity (and challenge) that we ultimately hope to address is: how can we quantify the credibility of knowledge gained from complex systems models, knowledge that is often incomplete and interim, but will nonetheless be used, sometimes in real-time, by decision makers?

  6. RutheniumII Complexes bearing Fused Polycyclic Ligands: From Fundamental Aspects to Potential Applications

    Directory of Open Access Journals (Sweden)

    Ludovic Troian-Gautier

    2014-04-01

    Full Text Available In this review, we first discuss the photophysics reported in the literature for mononuclear ruthenium complexes bearing ligands with extended aromaticity such as dipyrido[3,2-a:2',3'-c]phenazine (DPPZ, tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]-phenazine (TPPHZ,  tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]acridine (TPAC, 1,10-phenanthrolino[5,6-b]1,4,5,8,9,12-hexaazatriphenylene (PHEHAT 9,11,20,22-tetraaza- tetrapyrido[3,2-a:2',3'-c:3'',2''-l:2''',3'''-n]pentacene (TATPP, etc. Photophysical properties of binuclear and polynuclear complexes based on these extended ligands are then reported. We finally develop the use of binuclear complexes with extended π-systems for applications such as photocatalysis.

  7. Advances in statistical monitoring of complex multivariate processes with applications in industrial process control

    CERN Document Server

    Kruger, Uwe

    2012-01-01

    The development and application of multivariate statistical techniques in process monitoring has gained substantial interest over the past two decades in academia and industry alike.  Initially developed for monitoring and fault diagnosis in complex systems, such techniques have been refined and applied in various engineering areas, for example mechanical and manufacturing, chemical, electrical and electronic, and power engineering.  The recipe for the tremendous interest in multivariate statistical techniques lies in its simplicity and adaptability for developing monitoring applica

  8. [The application of combined physiotherapeutic methods for the complex treatment of patients with dyscirculatory encephalopathy].

    Science.gov (United States)

    Shiman, A G; Klocheva, E G; Kaiumov, S F; Shoferova, S D; Zhukova, M V

    2012-01-01

    This article reports the results of applying basic pharmacotherapy (enalapril, cytoflavin) and its combination with physical factors (transcranial electrostimulation, combined application oftranscranial electrostimulation and low-frequency magnetic therapy) in the complex treatment of patients with stage I-II dyscirculatory encephalopathy. The study has demonstrated that the combined treatment with cytoflavin, enalapril, transcranial electrostimulation and low-frequency magnetic therapy produced the most pronounced therapeutic effect (82.5%), as confirmed by positive dynamics of clinical and functional parameters.

  9. Application of complex programmable logic devices in memory radiation effects test system

    International Nuclear Information System (INIS)

    Li Yonghong; He Chaohui; Yang Hailiang; He Baoping

    2005-01-01

    The application of the complex programmable logic device (CPLD) in electronics is emphatically discussed. The method of using software MAX + plus II and CPLD are introduced. A new test system for memory radiation effects is established by using CPLD devices-EPM7128C84-15. The old test system's function are realized and, moreover, a number of small scale integrated circuits are reduced and the test system's reliability is improved. (authors)

  10. Rôle des germes parasites des bactéries pathogènes dans l'autoépuration des eaux

    Directory of Open Access Journals (Sweden)

    GUELIN A.

    1969-04-01

    Full Text Available Existence dans les eaux polluées de germes parasites qui s'attaquent aux bactéries pathogènes. Le pouvoir bactéricide des eaux polluées dû, en grande partie à la présence dans ces eaux de différents représentants des germes parasites. Possibilité d'application pratique des germes parasites pour l'assainissement des eaux polluées.

  11. Chrono-potentiometry in molten chlorides. Application to the study of the electrochemical properties of uranium and plutonium in the LiCl-KCl eutectic; Chronopotentiometrie dans les chlorures fondus. Application a l'etude des proprietes electrochimiques de l'uranium et du plutonium dans l'eutectique LiCl-KCl

    Energy Technology Data Exchange (ETDEWEB)

    Leseur, A. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1969-05-01

    Using solutions of cadmium chloride in the eutectic LiCl-KCl, a chrono-potentiometric method has been developed with a view to its application to the study of molten solutions. Particular attention has been paid to the choice of the indicator electrodes. The method makes it possible to analyze molten solutions quantitatively and to determine diffusion coefficients and their activation energies; it yields furthermore information about the nature and the behaviour of ionic species in solution. The method has been applied to the study of solutions of uranium and plutonium chloride in the eutectic LiCl-KCl. Linear chrono-amperometry has been used for studying these solutions quantitatively, but chrono-potentiometry, of which the theory is better developed, is better suited to a quantitative study. The results obtained have made it possible to determine the diffusion coefficients of the ions Cd{sup 2+}, U{sup 3+}, U{sup 4+} and U(IV) in the presence of F{sup -} and Pu{sup 3+} ions, as well as the activation energy of the diffusion coefficients. (author) [French] La mise au point de la chronopotentiometrie comme moyen d'etude des solutions fondues a ete effectuee avec des solutions de chlorure de cadmium dans l'eutectique LiCl-KCl. Le probleme du choix des electrodes indicatrices a ete particulierement etudie. La methode permet l'analyse quantitative des solutions fondues ainsi que la determination des coefficients de diffusion et de leurs energies d'activation: elle donne en outre des renseignements sur la nature et le comportement des especes ioniques en solution. Elle a ete appliquee a l'etude des solutions des chlorures d'uranium et de plutonium dans l'eutectique LiCl-KCl. La chronoamperometrie lineaire a ete utilisee pour l'etude qualitative de ces solutions, mais la chronopotentiometrie, dont la theorie est plus complete, convient mieux pour l'etude quantitative. Les resultats obtenus ont permis de determiner les

  12. Kinetics of transuranium element oxidation-reduction reactions in solution; Cinetique des reactions d'oxydo-reduction des elements transuraniens en solution

    Energy Technology Data Exchange (ETDEWEB)

    Gourisse, D. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-09-01

    A review of the kinetics of U, Np, Pu, Am oxidation-reduction reactions is proposed. The relations between the different activation thermodynamic functions (compensatory effect, formal entropy of the activated complex, magnitude of reactions velocities) are considered. The effects of acidity, ionic strength deuterium and mixed solvents polarity on reactions rates are described. The effect of different anions on reactions rates are explained by variations of the reaction standard free energy and variations of the activation free energy (coulombic interactions) resulting from the complexation of dissolved species by these anions. (author) [French] Une revue systematique de la cinetique des reactions d'oxydo-reduction des elements U, Np, Pu, Am, en solution perchlorique est proposee. Des considerations relatives aux grandeurs thermodynamiques d'activation associees aux actes elementaires (effet de compensation, entropie standard des complexes actives, rapidite des reactions) sont developpees. L'influence de l'acidite, de la force ionique, de l'eau lourde et de la polarite des solvants mixtes sur la vitesse des reactions est decrite. Enfin l'influence des differents anions sur la vitesse des reactions est expliquee par les variations de l'enthalpie libre standard de la reaction et de l'enthalpie libre d'activation (travail des forces electrostatiques) resultant de la complexation des especes dissoutes dans la solution. (auteur)

  13. Kinetics of transuranium element oxidation-reduction reactions in solution; Cinetique des reactions d'oxydo-reduction des elements transuraniens en solution

    Energy Technology Data Exchange (ETDEWEB)

    Gourisse, D [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1966-09-01

    A review of the kinetics of U, Np, Pu, Am oxidation-reduction reactions is proposed. The relations between the different activation thermodynamic functions (compensatory effect, formal entropy of the activated complex, magnitude of reactions velocities) are considered. The effects of acidity, ionic strength deuterium and mixed solvents polarity on reactions rates are described. The effect of different anions on reactions rates are explained by variations of the reaction standard free energy and variations of the activation free energy (coulombic interactions) resulting from the complexation of dissolved species by these anions. (author) [French] Une revue systematique de la cinetique des reactions d'oxydo-reduction des elements U, Np, Pu, Am, en solution perchlorique est proposee. Des considerations relatives aux grandeurs thermodynamiques d'activation associees aux actes elementaires (effet de compensation, entropie standard des complexes actives, rapidite des reactions) sont developpees. L'influence de l'acidite, de la force ionique, de l'eau lourde et de la polarite des solvants mixtes sur la vitesse des reactions est decrite. Enfin l'influence des differents anions sur la vitesse des reactions est expliquee par les variations de l'enthalpie libre standard de la reaction et de l'enthalpie libre d'activation (travail des forces electrostatiques) resultant de la complexation des especes dissoutes dans la solution. (auteur)

  14. Application of «Sensor signal analysis network» complex for distributed, time synchronized analysis of electromagnetic radiation

    Science.gov (United States)

    Mochalov, Vladimir; Mochalova, Anastasia

    2017-10-01

    The paper considers a developing software-hardware complex «Sensor signal analysis network» for distributed and time synchronized analysis of electromagnetic radiations. The areas of application and the main features of the complex are described. An example of application of the complex to monitor natural electromagnetic radiation sources is considered based on the data recorded in VLF range. A generalized functional scheme of stream analysis of signals by a complex functional node is suggested and its application for stream detection of atmospherics, whistlers and tweaks is considered.

  15. Survey of Applications of Complex Event Processing (CEP in Health Domain

    Directory of Open Access Journals (Sweden)

    Nadeem Mahmood

    2017-12-01

    Full Text Available It is always difficult to manipulate the production of huge amount of data which comes from multiple sources and to extract meaningful information to make appropriate decisions. When data comes from various input resources, to get required streams of events form this complex input network, the one of the strong functionality of Business Intelligence (BI the Complex Event Processing (CEP is the appropriate solution for the above mention problems. Real time processing, pattern matching, stream processing, big data management, sensor data processing and many more are the application areas of CEP. Health domain itself is a multi-dimension domain such as hospital supply chain, OPD management, disease diagnostic, In-patient, out-patient management, and emergency care etc. In this paper, the main focus is to discuss the application areas of Complex Event Processing (CEP in health domain by using sensor device, such that how CEP manipulate health data set events coming from sensor devices such as blood pressure, heart rate, fall detection, sugar level, temperature or any other vital signs and how this systems respond to these events as quickly as possible. Different existing models and application using CEP are discussed and summarized according to different characteristics.

  16. International Conference on Finite or Infinite Dimensional Complex Analysis and Applications

    CERN Document Server

    Tutschke, W; Yang, C

    2004-01-01

    There is almost no field in Mathematics which does not use Mathe­ matical Analysis. Computer methods in Applied Mathematics, too, are often based on statements and procedures of Mathematical Analysis. An important part of Mathematical Analysis is Complex Analysis because it has many applications in various branches of Mathematics. Since the field of Complex Analysis and its applications is a focal point in the Vietnamese research programme, the Hanoi University of Technology organized an International Conference on Finite or Infinite Dimensional Complex Analysis and Applications which took place in Hanoi from August 8 - 12, 2001. This conference th was the 9 one in a series of conferences which take place alternately in China, Japan, Korea and Vietnam each year. The first one took place th at Pusan University in Korea in 1993. The preceding 8 conference was th held in Shandong in China in August 2000. The 9 conference of the was the first one which took place above mentioned series of conferences in Vietnam....

  17. Computer Applications in Counselor Education: Developing Cultural Competencies Through Online Collaboration of Future School Counselors / L’informatique dans l’éducation des orienteurs : le développement du savoir-faire culturel par la collaboration en

    Directory of Open Access Journals (Sweden)

    Vessela Ilieva

    2012-07-01

    Full Text Available This study examined the applications of computer-mediated student collaboration in a graduate multicultural counseling course. The course work included a reflective cultural competency building assignment that utilized online communication and collaboration using a wiki to extend and improve students’ multicultural counseling and social justice advocacy skills. The online assignment design was aligned with the current call for utilizing technology in the counseling profession. It further considered the needs of the future counselors, the current levels of exposure to and experience with available technology of the class members, and the opportunities for utilization of a variety of online-based tools to extend in-class and out-of-class discussions. Students’ response to this new form of class work and communication confirmed the potential of the online component to other aspects of counselor preparation, and the data analysis showed that the computer-mediated assignment was a valuable addition to developing students’ skills as multiculturally competent professionals. Cette étude a examiné les applications de la collaboration entre étudiants par l’entremise de l’informatique dans le cadre d’un cours d’études supérieures sur l’orientation en contexte multiculturel. Les travaux du cours comprenaient un travail de réflexion pour renforcer le savoir-faire culturel grâce à la communication et à la collaboration en ligne, en utilisant un wiki pour accroître et améliorer les aptitudes des étudiants en orientation en contexte multiculturel et en défense de la justice sociale. La conception du travail en ligne s’alignait sur la tendance actuelle pour une utilisation accrue de la technologie dans le métier de conseiller en orientation. On y tenait également compte des besoins des futurs conseillers, de leur degré d’exposition à la technologie et de leur expérience avec celle-ci, ainsi que des occasions pour l

  18. Effets des electrons secondaires sur l'ADN

    Science.gov (United States)

    Boudaiffa, Badia

    Les interactions des electrons de basse energie (EBE) representent un element important en sciences des radiations, particulierement, les sequences se produisant immediatement apres l'interaction de la radiation ionisante avec le milieu biologique. Il est bien connu que lorsque ces radiations deposent leur energie dans la cellule, elles produisent un grand nombre d'electrons secondaires (4 x 104/MeV), qui sont crees le long de la trace avec des energies cinetiques initiales bien inferieures a 20 eV. Cependant, il n'y a jamais eu de mesures directes demontrant l'interaction de ces electrons de tres basse energie avec l'ADN, du principalement aux difficultes experimentales imposees par la complexite du milieu biologique. Dans notre laboratoire, les dernieres annees ont ete consacrees a l'etude des phenomenes fondamentaux induits par impact des EBE sur differentes molecules simples (e.g., N2, CO, O2, H2O, NO, C2H 4, C6H6, C2H12) et quelques molecules complexes dans leur phase solide. D'autres travaux effectues recemment sur des bases de l'ADN et des oligonucleotides ont montre que les EBE produisent des bris moleculaires sur les biomolecules. Ces travaux nous ont permis d'elaborer des techniques pour mettre en evidence et comprendre les interactions fondamentales des EBE avec des molecules d'interet biologique, afin d'atteindre notre objectif majeur d'etudier l'effet direct de ces particules sur la molecule d'ADN. Les techniques de sciences des surfaces developpees et utilisees dans les etudes precitees peuvent etre etendues et combinees avec des methodes classiques de biologie pour etudier les dommages de l'ADN induits par l'impact des EBE. Nos experiences ont montre l'efficacite des electrons de 3--20 eV a induire des coupures simple et double brins dans l'ADN. Pour des energies inferieures a 15 eV, ces coupures sont induites par la localisation temporaire d'un electron sur une unite moleculaire de l'ADN, ce qui engendre la formation d'un ion negatif transitoire

  19. Localization of alpha emitters by damage production in a thin film. Application to the study of alpha emitter diffusion in irradiated samples; Localisation des emetteurs alpha par creation de dommages dans un film mince. Application a l'etude de la diffusion des emetteurs alpha dans des echantillons irradies

    Energy Technology Data Exchange (ETDEWEB)

    Houdaille, B; Perrot, M [Commissariat a l' Energie Atomique, 91 - Saclay (France). Centre d' Etudes Nucleaires

    1968-07-01

    The process of recording {alpha} particles on cellulose nitrate films, called alpha-graphy, is applied to the study of the diffusion of {alpha}-emitting elements in irradiated alloys. The existence of diffusion is shown by attacking the film with concentrated caustic soda after exposition. The insensitivity of the recorder to {beta} {gamma} radiation emitted by the sample after passing in the reactor makes it possible to operate with long exposure times and to detect small diffusions. The concentration-penetration curves are drawn up after carrying out a densitometric analysis of the alpha-graphies. - As the cellulose nitrate is affected only by {alpha} particles of energies of between 0.5 and 4 MeV, it was first necessary to determine the yield of the recorder for {alpha} particles emitted by a thick source, i.e. whose energy varies between 0 and E{sub 0}, E{sub 0} being the energy of the alpha emitter. - The concentration C of the {alpha}-emitter, as a function of the optical density D of the alpha-graphy, and of the exposure time t is given by a simple relationship: C = D/at where a is an experimental constant determined by calibration. It depends on the nature of the cellulose nitrate, of the {alpha}-emitting element and of the alloy studied. (authors) [French] Le procede d'enregistrement des particules alpha sur film de nitrate de cellulose, ou alphagraphie, est applique a l'etude de la diffusion d'elements emetteurs alpha dans des alliages irradies. La diffusion est mise en evidence par une attaque du film de nitrate, apres exposition, dans de la soude concentree. L'insensibilite de l'enregistreur au rayonnement {beta} {gamma}, emis par l'echantillon apres son sejour en pile, permet d'operer sur de longs temps de pose et de detecter des diffusions faibles. Les courbes concentration - penetration sont etablies par exploitation densitometrique des alphagraphies. - Comme le nitrate de cellulose n'est impressionne que par des particules alpha dont l'energie est

  20. Code des baux 2018

    CERN Document Server

    Vial-Pedroletti, Béatrice; Kendérian, Fabien; Chavance, Emmanuelle; Coutan-Lapalus, Christelle

    2017-01-01

    Le code des baux 2018 vous offre un contenu extrêmement pratique, fiable et à jour au 1er août 2017. Cette 16e édition intègre notamment : le décret du 27 juillet 2017 relatif à l’évolution de certains loyers dans le cadre d’une nouvelle location ou d’un renouvellement de bail, pris en application de l’article 18 de la loi n° 89-462 du 6 juillet 1989 ; la loi du 27 janvier 2017 relative à l’égalité et à la citoyenneté ; la loi du 9 décembre 2016 relative à la transparence, à la lutte contre la corruption et à la modernisation de la vie économique ; la loi du 18 novembre 2016 de modernisation de la justice du xxie siècle

  1. Étude des impacts écologiques du dynamisme spatio-temporel des ...

    African Journals Online (AJOL)

    Cette recherche menée dans le Complexe Zones Humides Mahavavy - Kinkony a pour but d'évaluer les impacts écologiques du changement des habitats naturels sur les espèces menacées de sa faune. Des outils tels que le SIG, la télédétection ainsi que Marxan ont été combinés avec les études bibliographiques et les ...

  2. Preparation and characterization of Schiff base Cu(II) complex and its applications on textile materials

    Science.gov (United States)

    Oylumluoglu, G.; Oner, J.

    2017-10-01

    Schiff base ligands are regarded as an important class of organic compounds on account of the fact that their complexation ability with transition metal ions. A new monomeric Schiff base Cu(II) complex, [Cu(HL)2], 1 [H2L = 2-((E)-(2-hydroxypropylimino)methyl)-4-nitrophenol] has been synthesized and characterized by elemental analysis, UV and IR spectroscopy, single crystal X-ray diffraction and photoluminescence study. While the Schiff base ligand and its Cu(II) complex are excited at λex = 349 nm in UV region, the Schiff base ligand shows a blue emission band at λmax = 480 nm whereas its Cu(II) complex shows a strong green emission band at λmax = 520 nm in the solid state at room temperature. The luminescent properties showed that the Schiff base ligand and its Cu(II) complex can be used as novel potential candidates for applications in textile such as UV-protection, antimicrobial, laundry and functional bleaching treatments.

  3. Application of adjustable pulse lasers to studying rapid reaction kinetics of excited lanthanide complexing

    Energy Technology Data Exchange (ETDEWEB)

    Gruzdev, V.P. (Gosudarstvennyj Opticheskij Inst., Leningrad (USSR))

    1983-12-01

    Using some europium (3) ion complexes new possibilities to be opened by application of adjustable pulse lasers for studying rapid reactions of electron-excited metal ion complexing are demonstrated. The 6Zh rhodamine pulse laser is used as a source of nonequilibrium photoexcitation of an array of Eu/sup 3 +/ complexes in the luminescent kinetic spectroscopy method. The following results are obtained: for the first time the rate of reaction of acetate ion substitution for water molecules of an excited (/sup 5/D/sub 0/) ion of Eu/sup 3 +/ was measured to be (0.7+-0.2)x10/sup 7/ s/sup -1/; using direct experiments the lower limit for the rate of transition of one isomeric form of the excited Eu x EDTA complex into another one in an aqueous solution is determined to be 5x10/sup 5/ s/sup -1/ at 295 K; the kinetics of the excitation energy migration beteen aqueous solvates of Eu/sup 3 +/ and EuxEDTA complexes is investigated.

  4. A primer on complex systems with applications to astrophysical and laboratory plasmas

    CERN Document Server

    Sánchez, Raúl

    2018-01-01

    The purpose of this book is to illustrate the fundamental concepts of complexity and complex behavior and the best methods to characterize this behavior by means of their applications to some current research topics from within the fields of fusion, earth and solar plasmas. In this sense, it is a departure from the many books already available that discuss general features of complexity. The book is divided in two parts. In the first part the most important properties and features of complex systems are introduced, discussed and illustrated. The second part discusses several instances of possible complex phenomena in magnetized plasmas and some of the analysis tools that were introduced in the first part are used to characterize the dynamics in these systems. A list of problems is proposed at the end of each chapter. This book is intended for graduate and post-graduate students with a solid college background in mathematics and classical physics, who intend to work in the field of plasma physics and, in parti...

  5. Determination of a PWR key neutron parameters uncertainties and conformity studies applications; Determination des incertitudes liees aux grandeurs neutroniques d'interet des reacteurs a eau pressurisee a plaques combustible et applications aux etudes de conformite

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, D

    2002-07-01

    The aim of this thesis was to evaluate uncertainties of key neutron parameters of slab reactors. Uncertainties sources have many origins, technologic origin for parameters of fabrication and physical origin for nuclear data. First, each contribution of uncertainties is calculated and finally, a factor of uncertainties is associated to key slab parameter like reactivity, isotherm reactivity coefficient, control rod efficiency, power form factor before irradiation and lifetime. This factors of uncertainties were computed by Generalized Perturbations Theory in case of step 0 and by directs calculations in case of irradiation problems. One of neutronic conformity applications was about fabrication and nuclear data targets precision adjustments. Statistic (uncertainties) and deterministic (deviations) approaches were studied. Then neutronics key slab parameters uncertainties were reduced and so nuclear performances were optimised. (author)

  6. Determination of a PWR key neutron parameters uncertainties and conformity studies applications; Determination des incertitudes liees aux grandeurs neutroniques d'interet des reacteurs a eau pressurisee a plaques combustible et applications aux etudes de conformite

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, D

    2002-07-01

    The aim of this thesis was to evaluate uncertainties of key neutron parameters of slab reactors. Uncertainties sources have many origins, technologic origin for parameters of fabrication and physical origin for nuclear data. First, each contribution of uncertainties is calculated and finally, a factor of uncertainties is associated to key slab parameter like reactivity, isotherm reactivity coefficient, control rod efficiency, power form factor before irradiation and lifetime. This factors of uncertainties were computed by Generalized Perturbations Theory in case of step 0 and by directs calculations in case of irradiation problems. One of neutronic conformity applications was about fabrication and nuclear data targets precision adjustments. Statistic (uncertainties) and deterministic (deviations) approaches were studied. Then neutronics key slab parameters uncertainties were reduced and so nuclear performances were optimised. (author)

  7. Transport and deposition of nano-particles. Application to the free action of short-lived radon daughters; Transport et depot des aerosols nanometriques. Application a la fraction libre des descendants a vie courte du radon

    Energy Technology Data Exchange (ETDEWEB)

    Malet, J

    1997-10-10

    Short-lived radon daughters ({sup 218}Po, {sup 214}Pb, {sup 214}Bi, and {sup 214}Po) are important contributors to the natural average annual individual dose. The models describing the evolution of these aerosol in a house depend critically on a parameter, the {sup 218}Po deposition velocity, which, although aerosol deposition has been extensively studied, is poorly known. A numerical and experimental study is thus carried out for a simple case: deposition in a cylindrical tube under laminar flow condition. The numerical results help understanding the difference between the transport and deposition of these radionuclides and those of non radioactive aerosols. Comparison of these well environment does not give satisfactory correlation, requiring the study of phenomena that may affect deposition. The first of these is the possible variation in the e {sup 218}Po diffusion coefficient. Furthermore, experiments coupled with numerical calculations show that this variation could be due to {sup 218}Po neutralization. The second phenomenon concerns the effect of the surface type, which is also shown experimentally. By modelling the neutralization and using results with a piratically smooth surface, good numerical/experimental correlations are obtained. Understanding this simple case than makes possible studying a more complex case: deposition in controlled turbulent flow. Two theories are thus experimentally validated. In addition, a {sup 218}Po deposition velocity representative of our experimental conditions is determined. Finally, we report a feasibility study of radon daughters transport and deposition in a ventilated chamber taking into account all the involved phenomena. (author)

  8. Olefins transformation catalysis by zirconium and tungsten complexes in organic and non-aqueous ionic media; Catalyse de transformation des olefines par les complexes du zirconium et du tungstene en milieux organique et ionique non aqueux

    Energy Technology Data Exchange (ETDEWEB)

    Laurent-Gerot, P

    1997-06-30

    Molten salts are suitable solvents for biphasic catalysis: melting butyl-1 methyl-3 imidazolium chloride and aluminium chloride gives a polar and aprotic ionic liquid which is not miscible with hydrocarbons but dissolves organometallic complexes. Two types of complexes have been tested in molten salts with ethyl-aluminium dichloride: zirconium complexes to synthesize light {alpha} olefins from ethene; mono-imido complexes of tungsten VI (Cl{sub 4}W = NAr) to dimerize ethene in but-1 ene and propene in dimethyl-2,3-but-1-ene. For both of these complexes, biphasic catalysis principle is always respected: the active species is present only in the ionic phase and not in the organic phase. The first complexes, biphasic principle is always respected: the active species is present only in the ionic phase and not in the organic phase. The first complexes oligomerize ethene in molten salts with low activity and the {alpha} olefins selectivity is weak. Mono-imido complexes of tungsten VI are proved to be equivalent to the systems composed with WCl{sub 6} and aniline, and they dimerize ethene in but-1 ene and propene in dimethyl-2,3-but-1 ene more efficiently in organic medium than in ionic liquid. The characterization of the active species of the system Cl{sub 4}W=NAr / EtAlCl{sub 2} shows that it is the corresponding mono-imido complex of tungsten 4. (author) 129 refs.

  9. Application d’une approche inspirée des colonies de fourmis pour la recommandation des chemins d’apprentissage dans un cours en ligne : modèle et expérience

    Directory of Open Access Journals (Sweden)

    Aziz Dahbi

    2014-01-01

    Full Text Available Dans cet article, nous présentons la mise en œuvre, l’expérimentation et l’évaluation d’une approche pour la recommandation des chemins d’apprentissage dans un cours en ligne. Le processus de recommandation est inspiré de l’intelligence en essaim et plus particulièrement de l’optimisation par colonies de fourmis (OCF (ant colony optimization [ACO]. Dans ce contexte, nous avons considéré une différenciation des chemins d’apprentissage en fonction de l’activité explorée pour l’apprentissage d’un cours. Dans l’objectif de recommander des chemins d’apprentissage considérés optimaux et d’évaluer ainsi leur impact sur l’apprentissage d’un cours en ligne, l’approche proposée est basée à la fois sur la recommandation de chemins pertinents par l’enseignant et sur les résultats stockés au fur et à mesure par les apprenants sur les chemins empruntés. Notre approche a été validée expérimentalement et les résultats obtenus ont montré l’émergence d’un chemin d’apprentissage favorisant la réussite d’un nombre d’apprenants relativement considérable.

  10. Représentations cartographiques des facteurs de vulnérabilité des populations exposées à une menace volcanique. Application à la région du volcan Cotopaxi (Equateur

    Directory of Open Access Journals (Sweden)

    1996-01-01

    Full Text Available Suivant une définition sociale, la vulnérabilité est la propension plus ou moins prononcée à subir des dommages. L’atténuation des risques naturels auxquels les hommes sont confrontés suppose la réduction de la vulnérabilité en matière de vies humaines, de biens et d’activités. Il s’agit au préalable d’identifier les facteurs de vulnérabilité, d’en mesurer la portée, et de localiser dans l’espace les secteurs les plus sensibles. La cartographie de la vulnérabilité et de ses facteurs est une étape indispensable vers une cartographie globale du risque à laquelle de nombreux chercheurs et décideurs aspirent. À partir de l’exemple des régions des provinces du Pichincha et du Cotopaxi exposées aux conséquences de l’activité du volcan Cotopaxi, l’article propose quelques jalons méthodologiques pour une cartographie de la vulnérabilité des populations menacées. Des typologies spatiales de vulnérabilité sont représentées à partir d’une analyse factorielle. La carte intégrée des facteurs de vulnérabilité permet la réalisation de diagnostics locaux, tandis qu’une troisième carte fournit des orientations pour des actions de préparation. Une réflexion est également menée sur l’intérêt et sur les limites d’utilisation de ces cartes. CARTOGRAFÍA DE LOS FACTORES DE VULNERABILIDAD DE LAS POBLACIONES EXPUESTAS A UNA AMENAZA VOLCÁNICA. APLICACIÓN A LA REGIÓN DEL VOLCÁN COTOPAXI (ECUADOR. Según una definición social, la vulnerabilidad es la propensión más o menos pronunciada a sufrir perjuicios cuando ocurre un fenómeno natural destructor. La mitigación de los riesgos naturales que enfrentan los hombres supone la reducción de la vulnerabilidad de éstos, de sus bienes y actividades económicas. Se trata previamente de identificar los factores de vulnerabilidad, medir sus consecuencias y localizar los sectores más sensibles. La cartografía de la vulnerabilidad y sus factores constituye una

  11. Des (bio)nano-composites utilisés dans le traitement d'eaux contaminées par de l'arsenic/gentamicine ou pour des applications médicales

    OpenAIRE

    HE, Jing

    2013-01-01

    Les composés dits 'bionano' (bionanocomposites) apparaissent comme un nouveau groupe de matériaux hybrides nano-structurés. Ils sont issus de la combinaison de polymères naturels et de solides inorganiques et sont de l'ordre du nanomètre dans au moins une direction. Ces matériaux hybrides conservent les structures et les propriétés fonctionnelles des polymères et matériaux inorganiques dont ils sont composés. Parallèlement, la présence de biopolymères permet de diminuer les risques environnem...

  12. Heat and mass transfer in multi-scale porous structures: application to Diesel particulate filters modelling; Transferts de chaleur et de masse dans des structures poreuses multi-echelles: application a l'etude des filtres a particules Diesel

    Energy Technology Data Exchange (ETDEWEB)

    Oxarango, L.

    2004-09-15

    Ceramic filters appear to be the most promising solution to deal with the future emission standard requirements for diesel powered vehicles. Indeed, this type of Diesel Particulate Filters provides suitable characteristics for high efficiency soot collection. However, this filtration process is characterised by a dramatic increase of the pressure drop imposed in the exhaust line. Thus, the filter has to be cleaned periodically to insure the proper engine operating conditions. This regeneration phase is based on the oxidation of the carbon particles within the apparatus. This complex thermal process is critical for the safety working of Diesel Particulate Filters. Indeed, thermal stresses induced by the heat released during soot oxidation are involved in most of the filter breaking scenario. Numerous geometrical parameters defining the complex multi-scale structure of the apparatus could influence its thermal response. Thus, the geometrical optimization of these filters is a major problematic for the development of new products. This study aims at modelling heat and mass transfer phenomenon within Diesel Particulate Filters. The studied geometrical configuration is based on a ceramic honeycomb with porous walls and alternately plugged channel known as wall-flow DPF. In a first part, the gas flow, particles transport and collection are considered. Given the apparatus particular structure, the problem has to be treated considering various spatial length-scales. The filtering walls are characterised by a micrometric porous structure. The flow modelling with the Darcy law requires determining a particular effective permeability. The laminar flow problem in millimetric channels with wall suction (or injection) is studied. The asymptotic solution for flow in two-dimensional channels is used to derive a one-dimensional system preserving mass and momentum balances. This approach is then extended to the square channel configuration using direct numerical simulations. The

  13. EpiCollect+: linking smartphones to web applications for complex data collection projects.

    Science.gov (United States)

    Aanensen, David M; Huntley, Derek M; Menegazzo, Mirko; Powell, Chris I; Spratt, Brian G

    2014-01-01

    Previously, we have described the development of the generic mobile phone data gathering tool, EpiCollect, and an associated web application, providing two-way communication between multiple data gatherers and a project database. This software only allows data collection on the phone using a single questionnaire form that is tailored to the needs of the user (including a single GPS point and photo per entry), whereas many applications require a more complex structure, allowing users to link a series of forms in a linear or branching hierarchy, along with the addition of any number of media types accessible from smartphones and/or tablet devices (e.g., GPS, photos, videos, sound clips and barcode scanning). A much enhanced version of EpiCollect has been developed (EpiCollect+). The individual data collection forms in EpiCollect+ provide more design complexity than the single form used in EpiCollect, and the software allows the generation of complex data collection projects through the ability to link many forms together in a linear (or branching) hierarchy. Furthermore, EpiCollect+ allows the collection of multiple media types as well as standard text fields, increased data validation and form logic. The entire process of setting up a complex mobile phone data collection project to the specification of a user (project and form definitions) can be undertaken at the EpiCollect+ website using a simple 'drag and drop' procedure, with visualisation of the data gathered using Google Maps and charts at the project website. EpiCollect+ is suitable for situations where multiple users transmit complex data by mobile phone (or other Android devices) to a single project web database and is already being used for a range of field projects, particularly public health projects in sub-Saharan Africa. However, many uses can be envisaged from education, ecology and epidemiology to citizen science.

  14. The reprocessing-recycling of spent nuclear fuel. Actinides separation - Application to wastes management; Le traitement-recyclage du combustible nucleaire use. La separation des actinides - Application a la gestion des dechets

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    After its use in the reactor, the spent fuel still contains lot of recoverable material for an energetic use (uranium, plutonium), but also fission products and minor actinides which represent the residues of nuclear reactions. The reprocessing-recycling of the spent fuel, as it is performed in France, implies the chemical separation of these materials. The development and the industrial implementation of this separation process represent a major contribution of the French science and technology. The reprocessing-recycling allows a good management of nuclear wastes and a significant saving of fissile materials. With the recent spectacular rise of uranium prices, this process will become indispensable with the development of the next generation of fast neutron reactors. This book takes stock of the present and future variants of the chemical process used for the reprocessing of spent fuels. It describes the researches in progress and presents the stakes and recent results obtained by the CEA. content: the separation of actinides, a key factor for a sustainable nuclear energy; the actinides, a discovery of the 20. century; the radionuclides in nuclear fuels; the aquo ions of actinides; some redox properties of actinides; some complexing properties of actinide cations; general considerations about treatment processes; some characteristics of nuclear fuels in relation with their reprocessing; technical goals and specific constraints of the PUREX process; front-end operations of the PUREX process; separation and purification operations of the PUREX process; elaboration of finite products in the framework of the PUREX process; management and treatment of liquid effluents; solid wastes of the PUREX process; towards a joint management of uranium and plutonium: the COEX{sup TM} process; technical options of treatment and recycling techniques; the fuels of generation IV reactors; front-end treatment processes of advanced fuels; hydrometallurgical processes for future fuel

  15. Decision threshold associated with multiple measurements. Application to the synthesis of the environment monitoring results; Seuil de decision associe a des mesures multiples. Application a la synthese des resultats de surveillance de l'environnement

    Energy Technology Data Exchange (ETDEWEB)

    Vivier, A. [CEA, Institut national des sciences et techniques nucleaires, Centre de Saclay, 91191 Gif-sur-Yvette Cedex (France); Manificat, G. [IRSN, Direction de l' environnement et de l' intervention, Service d' etude et de surveillance de la radioactivite dans l' environnement, BP 40035, 78116 Le Vesinet Cedex (France); Picolo, J.L.; Fleury, S. [IRSN, Direction de l' environnement et de l' intervention, Service de traitement des echantillons et de metrologie pour l' environnement, BP 40035, 78116 Le Vesinet Cedex (France); Mokili, M. [Laboratoire SUBATECH - UMR 6457, ecole des Mines de Nantes, IN2P3/CNRS, Universite de Nantes, 4 rue Alfred Kastler, La Chantrerie, BP 20722, 44307 Nantes Cedex 03 (France); Guo, X. [ORTEC-AMETEK Inc, 801 S. Illinois Ave., Oak Ridge, TN 37830 (United States)

    2012-01-15

    When the sample activity is measured for various reasons several times, then with each measurement can be associated an individual decision threshold and limit of detection. Each measurement can be analyzed through its own decision threshold. The whole measurements can sometimes present contradictory results, some measurements being lower than the decision threshold and other higher. The problem then arises to build a decision threshold and a detection limit taking into account all the individual results, and to decide if the radioactivity is finally detected or not. It is interesting to note that it is possible sometimes that the decision threshold taking account all results makes it possible to decide that the radioactivity is present whereas the totality of the individual results are negative in terms of individual decision threshold. The purpose of this article is to show how these thresholds and these coherent limits cumulated can be determined in way according to the experimental conditions. In a general way a rigorous method of cumulating makes it possible to systematically decrease the decision threshold and limit of detection in terms of activity. This approach has interesting applications in gamma spectrometry with multi-emitters, discharge or periodical environmental measurements. On the basis of measurements realized by the IRSN within the framework of the national monitoring of the environment, we will see the potential impact of these methods on the final assessments. (authors)

  16. Methods for determining thermal stresses values. Some examples relating to nuclear reactors; Methodes de determination des contraintes thermiques. Quelques exemples d'application aux reacteurs

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, J; Gautier, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Peres, A [Israel Institute of Technology, Dept. of Nuclear Science Technion (Israel)

    1958-07-01

    As modern techniques develop more elaborate machines, and make their way towards higher and higher temperatures and pressures, the thermal stresses become a matter of major importance in the design of mechanical structures. In the first part of this paper, the authors examine the problem from a theoretical standpoint, and try to evaluate the aptitude and limitation of mathematical techniques to attain the quantitative values of thermal stresses. This paper deals mainly with the experimental methods to measure thermal stresses. The authors show some examples relating to nuclear reactors. (author)Fren. [French] Au fur et a mesure que la technique moderne developpe des machines plus poussees et s'oriente vers des temperatures et des pressions toujours plus elevees, les contraintes thermiques deviennent un facteur d'importance capitale dans le calcul des structures mecaniques. Les auteurs examinent d'abord l'aspect theorique du probleme, ainsi que l'aptitude et les limites du calcul pour exprimer quantitativement la valeur des contraintes thermiques. Les auteurs exposent principalement, ensuite, les methodes experimentales qui permettent de mesurer ces contraintes, et illustrent cet expose de quelques exemples relatifs aux installations nucleaires. (auteur)

  17. Application of a Dual-Arm Robot in Complex Sample Preparation and Measurement Processes.

    Science.gov (United States)

    Fleischer, Heidi; Drews, Robert Ralf; Janson, Jessica; Chinna Patlolla, Bharath Reddy; Chu, Xianghua; Klos, Michael; Thurow, Kerstin

    2016-10-01

    Automation systems with applied robotics have already been established in industrial applications for many years. In the field of life sciences, a comparable high level of automation can be found in the areas of bioscreening and high-throughput screening. Strong deficits still exist in the development of flexible and universal fully automated systems in the field of analytical measurement. Reasons are the heterogeneous processes with complex structures, which include sample preparation and transport, analytical measurements using complex sensor systems, and suitable data analysis and evaluation. Furthermore, the use of nonstandard sample vessels with various shapes and volumes results in an increased complexity. The direct use of existing automation solutions from bioscreening applications is not possible. A flexible automation system for sample preparation, analysis, and data evaluation is presented in this article. It is applied for the determination of cholesterol in biliary endoprosthesis using gas chromatography-mass spectrometry (GC-MS). A dual-arm robot performs both transport and active manipulation tasks to ensure human-like operation. This general robotic concept also enables the use of manual laboratory devices and equipment and is thus suitable in areas with a high standardization grade. © 2016 Society for Laboratory Automation and Screening.

  18. Hanford Central Waste Complex: Radioactive mixed waste storage facility dangerous waste permit application

    International Nuclear Information System (INIS)

    1991-10-01

    The Hanford Site is owned by the US Government and operated by the US Department of Energy Field Office, Richland. The Hanford Site manages and produces dangerous waste and mixed waste (containing both radioactive and dangerous components). The dangerous waste is regulated in accordance with the Resource Conversation and Recovery Act of 1976 and the State of Washington Hazardous Waste Management Act of 1976. The radioactive component of mixed waste is interpreted by the US Department of Energy to be regulated under the Atomic Energy Act of 1954; the nonradioactive dangerous component of mixed waste is interpreted to be regulated under the Resource Conservation and Recovery Act of 1976 and Washington Administrative Code 173--303. Westinghouse Hanford Company is a major contractor to the US Department of Energy Field Office, Richland and serves as co-operator of the Hanford Central Waste Complex. The Hanford Central Waste Complex is an existing and planned series of treatment, storage, and/or disposal units that will centralize the management of solid waste operations at a single location on the Hanford facility. The Hanford Central Waste Complex units include the Radioactive Mixed Waste Storage Facility, the unit addressed by this permit application, and the Waste Receiving and Processing Facility. The Waste Receiving and Processing Facility is covered in a separate permit application submittal

  19. Global dynamics of shaft lines of turbo-machineries coupled to surrounding fluids: application to the case of fluid sheets; Dynamique globale des lignes d'arbres de turbomachines couplees aux fluides environnants: application au cas des lames fluides

    Energy Technology Data Exchange (ETDEWEB)

    Lornage, D.

    2001-12-15

    Shaft lines of turbo-machineries have to stand increasing reliability, efficiency and safety requirements. A precise modeling of the rotating parts with all possible coupling has become necessary. In this context, this work aims to develop a global modeling of rotating wheel/shaft system inside a surrounding fluid in order to foresee its dynamical behaviour. The use and advantage of Eulerian, Lagrangian and mixed (arbitrary Lagrangian Eulerian - ALE) formulations is recalled first. A bibliographic synthesis of the classical techniques used in structure mechanics and of coupling techniques for rotating machines is presented. The coupling technique retained is presented. It uses fluid and structure models independently developed and validated. The structure domain is discretized by the finite-element method. The fluid domain is discretized by the finite-difference method taking into consideration the hypotheses linked with thin films. A modal base projection combined with a mesh at the fluid-structure interface allows an efficient, adaptable and evolutive coupling. Finally, the method is applied to 3 test-cases. The first two ones comprise a shaft/disc system coupled to a fluid sheet between the disc and the casing and to an hydrodynamic bearing. Both cases allow a first validation of the coupling method. The third case aims to study a structure closer to a real system made of a shaft and a wheel coupled to a fluid sheet between a flange and a casing. These three applications allow to show the trends linked with the fluid effects and the coupling between the flexible sub-parts of the structure. (J.S.)

  20. RATING MODELS AND INFORMATION TECHNOLOGIES APPLICATION FOR MANAGEMENT OF ADMINISTRATIVE-TERRITORIAL COMPLEXES

    Directory of Open Access Journals (Sweden)

    O. M. Pshinko

    2016-12-01

    . At this the control of separate elements is realized by the way of individual mental models construction and application of functioning processes. The procedure for evaluating of the prediction reliability based on multivariate linear extrapolation method was proposed. Practical value. The proposed method of strategic planning of the complex systems’ development based on rating models and developed information technology are representing the complex of automated tools to ensure effective economical and technological control of non-uniform sets of multiparameter objects. The new solutions of typical tasks of strategic planning and development of complex objects management procedure are implemented in the information technology of rating estimation (rating definition, sensitivity analysis, clustering, diagnostics, forecasting, resource allocation, multi-criteria analysis etc.. Application of the proposed information technology can automate the task of analysis and strategic planning of the administrative-territorial complexes. The technology can be used for monitoring, analysis, strategic planning and management of several complex system types simultaneously.

  1. Couches minces electrochromiques d'oxyde de tungstene dense et poreux pour des applications de controle energetique

    Science.gov (United States)

    Camirand, Hubert

    Nanotechnology has modified the landscape of energy generation, energy storage and energy saving devices. Architectural fenestration can extensively benefit from green nanotechnologies. Amongst them, active fenestration or "smart" windows are able to modify their coloration state upon the application of a small electrical voltage, when based on electrochromic materials. In fact, the amount of visible and near-infrared light that can penetrate through the window can be altered. Therefore, their implementation can allow for a significant reduction in energy consumption in buildings. Furthermore, the capability of optimizing indoor comfort is user-controlled, thus an additional degree of freedom is given by electrochromic-based technology. It is worth mentioning that such devices can be largely advantageous in countries with variable seasons, such as here in Canada. As a matter of fact, the large temperature difference between the hot and cold season influences the requirement of impeding or enabling visible and thermal radiation to pass through. This master's thesis is entirely devoted to tungsten trioxide (WO 3), which is the most widely studied electrochromic material. In the present case, WO3 thin films are synthesized by radiofrequency magnetron sputtering. By varying the deposition pressure and power, the porosity content/packing density of the films is modified. This work's main topic is the characterization of electrochromic samples by in situ spectroscopic ellipsometry simultaneously with the application of an electrical voltage in an aqueous electrolytic medium made of sulfuric acid (H2SO 4). The methodology developed here allows for an in-depth study of electro-active materials. To corroborate this, optical properties of WO3 are obtained for a wide range of coloration levels, and these are subsequently used to model the resulting coloration of electrochromic multilayer systems. However, the interface between the dense and porous films affects the coloration

  2. Les possibilités des turbines de détente dans les industries gazière et pétrolière Application of Expansion Turbines in the Gas and Oil Industry

    Directory of Open Access Journals (Sweden)

    Verneau A.

    2006-11-01

    Full Text Available Utilisées depuis longtemps dans l'industrie cryogénique, les turbines de détente voient leur intérêt augmenter actuellement en tant que turbines de récupération de l'énergie des laminages. Cette énergie peut servir à l'entraînement de compresseurs, pompes ou générateurs électriques. Il existe surtout des turbines dans la gamme de 200 à 20 000 ch. Deux types principaux sont développés : les turbines axiales et les turbines radiales. Les particularités techniques et les domaines d'emploi de chaque type sont discutés. Ue intérêt particulier est porté au domaine des petites puissances (de 100 kW jusqu'à quelques centaines de watts. L'évolution du rendement en fonction de la puissance est étudiée et quelques types spéciaux bien adaptés à cette gamme, tels que les turbines périphériques, sont présentés. Quelques indications sur la récupération de l'énergie des liquides par turbines sont également données. Ensuite, plusieurs exemples d'applications sont exposés tels que : récupération de fractions condensables du gaz naturel (butane, propane, éthane, récupération de gaz perdu, récupération de l'énergie des laminages lors de la distribution et au niveau des stockages souterrains, turbine hydraulique de lavage de gaz, récupération de l'énergie des fumées de cracking catalytique, entraînement de petits générateurs électriques dans la gamme de quelques kilowatts à quelques centaines de watts. Enfin, nous abordons la technologie et les dispositions constructives particulières en nous attachant plus spécialement aux problèmes de régulation, étanchéité, paliers. Des techniques nouvelles telles que l'emploi de paliers à gaz et leurs avantages sont décrites. Les difficultés dues aux basses températures et à la condensation sont examinées. Nous terminons par quelques considérations d'ordre économique destinées à prévoir la rentabilité d'une installation de récupération d

  3. Application de la théorie des graphes au traitement de la carte géologique Applying the Theory of Graphs to the Treatment of Geological Maps

    Directory of Open Access Journals (Sweden)

    Bouillé F.

    2006-11-01

    Full Text Available La saisie des informations d'une carte géologique par les méthodes classiques (grilles ou relevés aléatoires de courbes ne constitue pas une base de données opérationnelle. Par contre, l'assimilation des limites géologiques à un graphe orienté répond aux critères d'optimalité (encombrement très réduit, temps minimal, fiabilité, et permet une digitalisation rationnelle de la carte, une bonne structuration du fichier, et la réalisation d'applications intéressantes : restitutions graphiques sélectives à toutes échelles, calculs de pendages, surfaces, volumes, études de corrélation. Nous avons donc établi une chaîne de traitement de la carte géologique dont chaque maillon (saisie des informations; contrôle, mise à jour, consultation, application opère sur un ou plusieurs graphes. Obtaining data from geological maps by conventional methods (grids or random curve plotting is not an operational data base. However, the comparison of geological boundaries with a directional graph meets criteria of optimalness (very small bulk, minimum time, reliability and makes it possible to digitize the map rationally, to structure the file properly and to achieve significant applications such as selective graph plotting on all scales, calculating dips, areas and volumes, and making correlotion analyses. Therefore, we worked out a geological map processing sequence in which each element (data acquisition, checking, updating, consulting, applications operates on one or several graphs.

  4. Photoactivatable metal complexes: from theory to applications in biotechnology and medicine.

    Science.gov (United States)

    Smith, Nichola A; Sadler, Peter J

    2013-07-28

    This short review highlights some of the exciting new experimental and theoretical developments in the field of photoactivatable metal complexes and their applications in biotechnology and medicine. The examples chosen are based on some of the presentations at the Royal Society Discussion Meeting in June 2012, many of which are featured in more detail in other articles in this issue. This is a young field. Even the photochemistry of well-known systems such as metal-carbonyl complexes is still being elucidated. Striking are the recent developments in theory and computation (e.g. time-dependent density functional theory) and in ultrafast-pulsed radiation techniques which allow photochemical reactions to be followed and their mechanisms to be revealed on picosecond/nanosecond time scales. Not only do some metal complexes (e.g. those of Ru and Ir) possess favourable emission properties which allow functional imaging of cells and tissues (e.g. DNA interactions), but metal complexes can also provide spatially controlled photorelease of bioactive small molecules (e.g. CO and NO)--a novel strategy for site-directed therapy. This extends to cancer therapy, where metal-based precursors offer the prospect of generating excited-state drugs with new mechanisms of action that complement and augment those of current organic photosensitizers.

  5. Des Connaissances Aux Politiques

    International Development Research Centre (IDRC) Digital Library (Canada)

    Les synergies ont été mises en commun au fur et à mesure des progrès de la recherche. .... Recherche normative (sur le rôle et la performance des institutions .... Système national d'information sur la gestion environnementale connecté à 19 ...... Un fort contrôle centralisé sur l'élaboration des politiques nationales peut ...

  6. Long term developments in irradiated natural uranium processing costs. Optimal size and siting of plants; Perspectives a long terme des couts de traitement de l'uranium naturel irradie. Tailles et localisations optimales des usines

    Energy Technology Data Exchange (ETDEWEB)

    Thiriet, L [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Oger, C; Vaumas, P de [Saint-Gobain Nucleaire, 92 - Courbevoie (France)

    1964-07-01

    processing plants are shown, different from those in part two. The indirect effect of these reprocessing programmes on the availability of plutonium, and therefore on the possibility.of undertaking plutonium burning reactor programmes, must be taken into account. (authors) [French] L'objet de cette communication est d'apporter une contribution a la solution du probleme du choix des tailles et des localisations optimales des usines de traitement des combustibles nucleaires irradies, associees a des programmes de puissance electrique installee. Dans une premiere partie, on etudie la structure des couts d'investissements et d'exploitation des usines de traitement de l'uranium naturel irradie, l'influence de la taille des usines sur ces couts et ces structures de couts. Au cout de traitement de l'uranium naturel irradie s'ajoute d'autre part le cout du transport des combustibles irradies des lieux de production aux sites des usines de traitement. La recherche du cout minimum pour la production d'un pays ou d'un ensemble de pays fait donc intervenir a la fois la taille et la localisation des usines. On indique les couts de transport previsibles pour l'uranium naturel irradie et la structure de ces couts (transport, assurance, couts et amortissement des containers). Dans une deuxieme partie, et pour differents echeanciers de combustibles irradies a traiter chaque annee, on determine les tailles et les localisations optimales des usines de traitement et la sensibilite de ces resultats, aux hypotheses de base concernant le cout du traitement, le cout du transport, l'annee de demarrage du programme d'usines, l'horizon choisi. - le probleme de nature combinatoire, assez complexe, est resolu par l'application des methodes de la programmation dynamique. - on montre que les methodes sont egalement applicables au probleme du choix des tailles et des localisations optimales des usines de traitement des elements du type MTR, associees aux programmes de reacteurs de recherche ainsi qu

  7. Structure et stabilité des bancs et agrégations de poissons pélagiques côtiers tropicaux : application halieutique

    OpenAIRE

    Soria, Marc

    1994-01-01

    Afin de cerner le rôle du comportement animal dans les problèmes rencontrés lors de l'estimation des stocks de poissons pélagiques en halieutique par les méthodes d'évaluation directes (acoustique) et indirectes, nous avons entrepris l'étude, en milieu naturel, de la structure et de la stabilité des bancs de petits poissons pélagiques côtiers tropicaux (Clupéidés, Engraulidés). Cette étude est basée sur des observations acoustiques et visuelles (aériennes et sous-marines) simultanées... Nous ...

  8. Generalized Bloch Theorem for Complex Periodic Potentials - A Powerful Application to Quantum Transport Calculations

    International Nuclear Information System (INIS)

    Zhang, Xiaoguang; Varga, Kalman; Pantelides, Sokrates T

    2007-01-01

    Band-theoretic methods with periodically repeated supercells have been a powerful approach for ground-state electronic structure calculations, but have not so far been adapted for quantum transport problems with open boundary conditions. Here we introduce a generalized Bloch theorem for complex periodic potentials and use a transfer-matrix formulation to cast the transmission probability in a scattering problem with open boundary conditions in terms of the complex wave vectors of a periodic system with absorbing layers, allowing a band technique for quantum transport calculations. The accuracy and utility of the method is demonstrated by the model problems of the transmission of an electron over a square barrier and the scattering of a phonon in an inhomogeneous nanowire. Application to the resistance of a twin boundary in nanocrystalline copper yields excellent agreement with recent experimental data

  9. Complexity of EEG-signal in Time Domain - Possible Biomedical Application

    Science.gov (United States)

    Klonowski, Wlodzimierz; Olejarczyk, Elzbieta; Stepien, Robert

    2002-07-01

    Human brain is a highly complex nonlinear system. So it is not surprising that in analysis of EEG-signal, which represents overall activity of the brain, the methods of Nonlinear Dynamics (or Chaos Theory as it is commonly called) can be used. Even if the signal is not chaotic these methods are a motivating tool to explore changes in brain activity due to different functional activation states, e.g. different sleep stages, or to applied therapy, e.g. exposure to chemical agents (drugs) and physical factors (light, magnetic field). The methods supplied by Nonlinear Dynamics reveal signal characteristics that are not revealed by linear methods like FFT. Better understanding of principles that govern dynamics and complexity of EEG-signal can help to find `the signatures' of different physiological and pathological states of human brain, quantitative characteristics that may find applications in medical diagnostics.

  10. Electro-activity of cobalt and nickel complexes for the reduction of protons into di-hydrogen; Electroactivite de complexes de cobalt et nickel pour la reduction des protons en di-hydrogene

    Energy Technology Data Exchange (ETDEWEB)

    Pantani, O.; Anxolabehere-Mallart, E.; Aukauloo, A.; Millet, P. [Paris-11 Univ., Equipe de Chimie Inorganique, UMR 8182, ICMMO, 91 - Orsay (France)

    2007-07-01

    In this study, the results obtained with different cobalt and nickel glyoximes are presented. These complexes have been characterized by various spectroscopies (UV-visible, ESR) and by electrochemistry (cyclic voltametry, spectro-electrochemistry). Their efficiency to electrochemically reduce the protons into dihydrogen in acid medium is discussed. More particularly, studies on solid support are carried out. At last, these complexes are being tested inside PEM electrolysis. (O.M.)

  11. Problématique de la valorisation agricole des biodéchets dans la ...

    African Journals Online (AJOL)

    SARAH

    30 avr. 2014 ... Conclusion et application de la recherche : La gestion des déchets ... la ville de Lubumbashi, les outils de diagnostic des ... développement participatif des technologies .... sites I, II, IV, V, VI et VII caractérisés par les acteurs.

  12. Inventaire et incidence des insectes inféodes à la culture du fonio ...

    African Journals Online (AJOL)

    importance des insectes capturés sur le fonio est liée à la multitude des adventices qui infestent le fonio et qui favorisent le développement des insectes nuisibles. Conclusion et application : La culture de fonio est infestée par un nombre ...

  13. 7th international conference on Nuclear microprobe technology and applications; 7. conference internationale sur la technologie et les applications des microsondes nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    This colloquium gives an up-to-date report on the continuously advancing applications and development of microbeam technology. It presents abstracts and oral contributions in the following domains: microprobes facilities, analysis techniques, imaging techniques, micro-ion beam modification of materials, microelectronics, applications in Material Sciences in Biology in Medicine in earth and planetary Sciences in environment in art in archaeology, alternative techniques. (A.L.B.)

  14. Contribution à la conception et à la commande des machines synchrones à double excitation. Application au véhicule hybride.

    OpenAIRE

    AMARA , Yacine

    2001-01-01

    This Thesis concerns the design of hybrid excited synchronous machines used for hybrid and/or electric vehicles traction.; Les travaux présentés dans ce mémoire concernent la conception et la commande des machines synchrones à double excitation. Ce concept apparaît viable et améliore les performances des machines synchrones et plus globalement les systèmes d’entraînement où elles s’intègrent.

  15. Caractérisation et simulation des mouvements d'atteinte par un opérateur humain en position assise en vue d'applications ergonomiques

    OpenAIRE

    CHEVALOT, N

    2006-01-01

    La simulation de mouvements d'atteinte effectués par un opérateur assis est particulièrement utile pour les constructeurs d'automobiles. Elle permet d'améliorer l'ergonomie de l'habitacle et des commandes, le plus en amont possible dans la conception. Elle consiste à simuler un mouvement et à prédire son inconfort. Cependant, ce type de simulation se heurte à des problèmes pratiques et théoriques. Pour la partie pratique, une méthode de simulation générique et stable pour tout type de mouveme...

  16. Theoretical Study of Copper Complexes: Molecular Structure, Properties, and Its Application to Solar Cells

    Directory of Open Access Journals (Sweden)

    Jesus Baldenebro-Lopez

    2013-01-01

    Full Text Available We present a theoretical investigation of copper complexes with potential applications as sensitizers for solar cells. The density functional theory (DFT and time-dependent DFT were utilized, using the M06 hybrid meta-GGA functional with the LANL2DZ (D95V on first row and DZVP basis sets. This level of calculation was used to find the optimized molecular structure, the absorption spectra, the molecular orbitals energies, and the chemical reactivity parameters that arise from conceptual DFT. Solvent effects have been taken into account by an implicit approach, namely, the polarizable continuum model (PCM, using the nonequilibrium version of the IEF-PCM model.

  17. Évaluation des pratiques agricoles des légumes feuilles : le cas des ...

    African Journals Online (AJOL)

    SARAH

    30 sept. 2017 ... ... de Biochimie et Immunologie Appliquée, Centre de Recherche en Sciences Biologiques, Alimentaires et .... l'intoxication des agriculteurs et des consommateurs, ... source d'alimentation en eau et au pouvoir d'achat des.

  18. The ``Grey System`` theory and its application to target cost forecasting at Chinese collieries; Die Theorie des grauen Systems und ihre Anwendung bei der Prognose der Zielkosten des gesamten Bergwerks

    Energy Technology Data Exchange (ETDEWEB)

    Ding Rijia; Yi Maosheng; Wang Shiyuan

    1997-09-01

    A production-cost forecasting system has been developed for use at Chinese collieries. Known as the `Grey System`, the theory and model-based process distinguishes between `white` information, which is human controlled, `black` information, which cannot be controlled by human actions, and `grey information`, which forms the majority component and comprises information which can only be partly or not completely collected. A grey system is therefore one in which the necessary information is absent. Future developments in the system can be forecast by analysing the regularity of the time-series values for the technical and economic characteristics of previous periods. The system employs the GM (1.1) prognostic model, which is a `grey` systematic forecasting model with one variable and one linear differential equation. It can be applied to systems which are affected simultaneously be several factors, with no overriding main factor, or in which no marked regularity exists between the controlling factors. The mathematical model constructed on the basis of the `Grey theory` is designed for large-scale economic systems which are affected by several control factors. A bigger system makes for a greater randomness element, which in turn lessens the influence of subjective interference factors and increases the accuracy of the prognosis. (orig./MSK) [Deutsch] Mit Hilfe der Theorie und von Modellen des `grauen Systems` wird eine Prognose der Produktionskosten von chinesischen Bergwerken erstellt. Die Theorie des `grauen Systems` unterscheidet zwischen den von den Menschen beherrschbaren `weissen` Informationen, den von den Menschen nicht beherrschbaren `schwarzen` Informationen und der ueberwiegenden Anzahl der Informationen, die nur teilweise oder nicht vollstaendig erfasst werden koennen und als `graue` Informationen bezeichnet werden. Ein graues System ist folglich ein System, in dem es an notwendigen Informationen fehlt. Die zukuenftige Entwicklung des Systems kann dadurch

  19. Determination of the form of very short luminous pulses. Application to scintillation phenomena (1962); Determination de la forme des impulsions lumineuses tres breves. Application aux phenomenes de scintillation (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Koechlin, Y [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1961-12-15

    During studies on photomultipliers and scintillators we have developed a new method of measurement making it possible to determine with precision the form of luminous pulses whose duration may be less that of an anodic photomultiplier pulse. This method, which can be applied to non-recurrent pulses, makes possible the study of scintillations caused by particles of photons in the case where it is possible to operate on a large number of pulses having the same form. We have thus determined the form of the scintillations of various fluorescent liquids excited by {alpha} particles and {gamma} photons. The results obtained are in agreement with the energy transfer theory for organic liquids elaborated by H. Kallmann and M. FURST. The results are used to determine exactly the parameters occurring in the theory. (author) [French] A l'occasion d'etudes sur les photomultiplicateurs et les scintillateurs nous avons mis au point une nouvelle methode de mesure permettant de determiner avec precision la forme des impulsions lumineuses dont la duree peut etre inferieure a celle d'une impulsion anodique de photomultiplicateur. Cette methode, qui peut s'appliquer a des impulsions non recurrentes, permet d'etudier les scintillations provoquees par des particules ou des photons, a la seule condition que l'on puisse operer sur un grand nombre d'impulsions ayant la meme forme. Nous avons determine ainsi la forme des scintillations des divers liquides fluorescents excites par des particules {alpha} et des photons {gamma} Les resultats obtenus sont en accord avec la theorie des transferts d'energie dans les scintillateurs organiques, elaboree par H. KALLMANN et M. FURST. Ils conduisent a une determination precise des parameters intervenant dans cette theorie. (auteur)

  20. The application of method supplier’s complex evaluation. Case study

    Directory of Open Access Journals (Sweden)

    Ekaterina Chytilová

    2012-01-01

    Full Text Available The main goal of this article includes the illustration of selecting bidders evaluation with help Method of complex evaluation of suppliers (MCE. Nowadays the evaluation of suppliers has more importance is in the supply chain management. For SMEs with discontinuous custom manufacturing supplier evaluation at first stage becomes a priority to maintain and enhance the competitiveness of farm output and overall competitiveness. This article presents results of control MCE. The results of this article are results of suppliers’ evaluation conditions and eliminations of MCE application on the base of real enterprise data. MCE is oriented to small and medium-sized enterprises with discontinue manufacturing to order. Research is oriented to selecting procedure of existing suppliers at the first stage of supply chain. Nationality and geographic location haven’t importance to MCE application. Illustrative case study presents the evaluation process to the specific conditions and subsequently demonstrated viability of MCE.

  1. Application of fibrous complexing sorbents for trace elements preconcentration and separation

    International Nuclear Information System (INIS)

    Zakhartchenko, E.A.; Myasoedova, G.V.

    2003-01-01

    This article demonstrates the application of the 'filled' fibrous sorbents for preconcentration and separation of platinum metals, as well as heavy metals and radionuclides. The POLYORGS complexing sorbents and ion-exchangers were used as fillers. Dynamic preconcentration conditions should be set for complete sorption of the elements: diameter and mass of the sorbent disk or the column as well as flow rate of the solution. These conditions depend on specific features of materials to be analysed and the requirements of the experimental task or detection method. Extensive alteration of features as well as perfect kinetic properties and high selectivity of the 'filled' sorbents confirm their applicability for trace elements preconcentration and separation in technology and analytical chemistry. (authors)

  2. La transmission efficace des compétences via Internet : exemple pratique

    NARCIS (Netherlands)

    Caniëls, M.C.J.

    2005-01-01

    Les universités sont de plus en plus nombreuses à adopter des modèles pédagogiques novateurs, plutôt axés sur le développement des compétences que sur la reproduction des connaissances. Ces nouveaux modèles pédagogiques soulignent l’importance de la mise en application des connaissances et du

  3. Influence of extranuclear fields on angular correlations; Influence des champs extranucleaires sur les correlations angulaires

    Energy Technology Data Exchange (ETDEWEB)

    Abragam, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    A general formalism is given for the description of the perturbation of angular correlations by extranuclear fields. An application is made to the case of static interactions in solids and time dependent interactions in liquids. (author) [French] On donne un formalisme general pour la description de la perturbation des correlations angulaires par des champs extranucleaires. Ce formalisme est applique aux cas des interactions statiques dans les solides et des interactions dependantes du temps dans les liquides. (auteur)

  4. Environmental monitoring of the La Grande complex (2003-2004) : evolution of mercury levels in the flesh of fish; Reseau de suivi environnemental du complexe La Grande (2003-2004) : evolution du mercure dans la chair des poissons

    Energy Technology Data Exchange (ETDEWEB)

    Therrien, J. [Genivar SEC, Quebec, PQ (Canada); Schetagne, R. [Hydro-Quebec Production, Baie-Comeau, PQ (Canada)

    2005-11-15

    The results of surveys conducted to assess the duration of temporary mercury levels in piscivorous species in the La Grande Complex were presented. A 2003 survey conducted in the easter sector and a 2004 survey conducted in the western sector of the complex showed that for non-piscivorous fishes of standardized length, a return to mean natural mercury levels will be achieved between 10 and 20 years after impounding. For piscivorous fishes, the evolution pattern of the mean mercury levels suggested that a return to background levels will occur after 20 to 30 years. Mercury levels for northern pike in the Robert-Bourassa Reservoir are expected to return to normal levels after 30 to 35 years. The surveys indicated that mean mercury levels in non-piscivorous fishes were often higher immediately below the La Grande generating stations. Similar observations were made for northern pike and lake trout downstream of the generating stations in the eastern sector of the complex. Mean mercury levels were significantly higher for fishes in the complex than fishes in the natural lakes of the region. Results of the surveys suggested that additional consumption restrictions for piscivorous fishes in the reservoirs are needed. Consumption guidelines for varieties of non-piscivorous and piscivorous fishes from the complex were included.

  5. Hydro mechanical deep-drawing and high pressure sheet metal forming as forming technologies for the production of complex parts made of magnesium sheet metal AZ31B-0; Hydromechanisches Tiefziehen und Hochdruckblechumformung als Verfahren zur Herstellung komplexer Bauteile aus Magnesiumfeinblechen des Typs AZ31B-0

    Energy Technology Data Exchange (ETDEWEB)

    Viehweger, B.; Richter, G.; Duering, M.; Karabet, A. [Lehrstuhlleiter, BTU Cottbus, Lehrstuhl Konstruktion und Fertigung, Konrad-Wachsmann Allee 1, 03046 Cottbus (Germany); Sviridov, A.; Hartmann, H.; Richter, U. [Forschungs- und Qualitaetszentrum Oderbruecke gGmbH Eisenhuettenstadt (Germany)

    2004-07-01

    Semi - finished sheet - metal products made of magnesium alloys such as AZ31B are known as better deformable at temperatures in the range of 175 C - 240 C. By means of hydroforming technologies, as there are hydro mechanical deep-drawing and high pressure sheet metal forming, the influence of different forming parameters on the forming results has been investigated. A more complex experimental geometry was deformed applying forming temperatures of 175 C, 200 C, 225 C and 240 C and accordingly adjusted forces of the blank holder. Concerning the applied forming - methods and experimental parameters the forming results have been evaluated and compared regarding the decrease of sheet thickness and the development of small radii. For some experimental parts, which have been deformed by means of high pressure sheet metal forming at temperatures of 175 C and 225 C, supplementary investigations have been carried out in order to determine the evolution of characteristic surface values in dependence on the forming operation. On the basis of these results practical recommendations for the limits of application of aforementioned forming technologies for AZ31B-0 magnesium sheet metal are given. (Abstract Copyright [2004], Wiley Periodicals, Inc.) [German] Eine gute Umformbarkeit von Blechhalbzeugen aus Magnesiumknetlegierungen stellt sich bekanntlich bei Anwendung von Umformtemperaturen im Bereich von 175 C - 240 C ein. Anhand der wirkmedienbasierten Umformverfahren hydromechanisches Tiefziehen und Hochdruckblechumformung ist an handelsueblichen AZ31B-0 Feinblechen die Einstellung unterschiedlicher Umformparameter erprobt worden. Unter Verwendung von Umformtemperaturen von 175 C, 200 C, 225 C und 240 C und entsprechend angepassten Niederhalterdruecken ist eine praxisnahe Versuchsgeometrie ''Minihood'' ausgeformt worden. Im Hinblick auf angewendete Umformverfahren und Versuchsparameter wurde an den Versuchsbauteilen die Blechdickenabnahme und die

  6. 1170-MW(t) HTGR-PS/C plant application study report: Geismar, Louisiana refinery/chemical complex application

    International Nuclear Information System (INIS)

    McMain, A.T. Jr.; Stanley, J.D.

    1981-05-01

    This report summarizes a study to apply an 1170-MW(t) high-temperature gas-cooled reactor - process steam/cogeneration (HTGR-PS/C) to an industrial complex at Geismar, Louisiana. This study compares the HTGR with coal and oil as process plant fuels. This study uses a previous broad energy alternative study by the Stone and Webster Corporation on refinery and chemical plant needs in the Gulf States Utilities service area. The HTGR-PS/C was developed by General Atomic (GA) specifically for industries which require both steam and electric energy. The GA 1170-MW(t) HTGR-PC/C design is particularly well suited to industrial applications and is expected to have excellent cost benefits over other energy sources

  7. A novel sort of adaptive complex synchronizations of two indistinguishable chaotic complex nonlinear models with uncertain parameters and its applications in secure communications

    Science.gov (United States)

    Mahmoud, Emad E.; Abood, Fatimah S.

    In this paper, we will demonstrate the adaptive complex anti-lag synchronization (CALS) of two indistinguishable complex chaotic nonlinear systems with the parameters which are uncertain. The significance of CALS is not advised well in the literature yet. The CALS contains or consolidate two sorts of synchronizations (anti-lag synchronization ALS and lag synchronization LS). The state variable of the master system synchronizes with an alternate state variable of the slave system. Depending on the function of Lyapunov, a plan is orchestrated to achieve CALS of chaotic attractors of complex systems with unverifiable parameters. CALS of two indistinguishable complexes of Lü systems is viewed as, for example, an occasion for affirming the likelihood of the plan exhibited. In physics, we can see complex chaotic systems in numerous different applications, for example, applied sciences or engineering. With a specific end goal to affirm the proposed synchronization plan viability and demonstrate the hypothetical outcomes, we can compute the numerical simulation. The above outcomes will give the hypothetical establishment to the secure communication applications. CALS of complex chaotic systems in which a state variable of the master system synchronizes with an alternate state variable of the slave system is an encouraging sort of synchronization as it contributes excellent security in secure communication. Amid this secure communication, the synchronization between transmitter and collector is shut and message signals are recouped. The encryption and restoration of the signals are simulated numerically.

  8. L’incertitude dans l’utilisation des médias géolocalisés : étude de deux applications reliées à la mobilité urbaine

    Directory of Open Access Journals (Sweden)

    Julia Salles

    2015-12-01

    Full Text Available À partir de la différentiation entre les pratiques stratégiques et tactiques, développée par Michel de Certeau (1990, et du concept de l’espace hybride (De Souza et Silva, 2006 ; Nova, 2009, ce travail distinguera les différents rapports à l’incertitude lors du déplacement en milieu urbain par les utilisateurs des médias géolocalisés, notamment par l’étude de deux applications pour appareils mobiles, Foursquare/Swarm et Walking the Edit.

  9. Tritium/3He measurements in young groundwater: Progress in applications to complex hydrogeological systems

    Science.gov (United States)

    Schlosser, Peter; Shapiro, Stephanie D.; Stute, Martin; Plummer, Niel

    2000-01-01

    Tritium/3He dating has been applied to many problems in groundwater hydrology including, for example, determination of circulation patterns, mean residence times, recharge rates, or bank infiltration. Here, we discuss recent progress in the application of the tritium/3He dating method to sites with complex hydrogeological settings. Specifically, we report on tritium/3He dating at sites with (a) river infiltration into the basaltic fractured rock aquifer of the Eastern Snake River Plain, and (b) river infiltration through sinkholes into the karstic limestone Upper Floridian aquifer near Valdosta, Georgia.Tritium/3He dating has been applied to many problems in groundwater hydrology including, for example, determination of circulation patterns, mean residence times, recharge rates, or bank infiltration. Here, we discuss recent progress in the application of the tritium/3He dating method to sites with complex hydrogeological settings. Specifically, we report on tritium/3He dating at sites with (a) river infiltration into the basaltic fractured rock aquifer of the Eastern Snake River Plain, and (b) river infiltration through sinkholes into the karstic limestone Upper Floridian aquifer near Valdosta, Georgia.

  10. Complex Adaptive System of Systems (CASoS) Engineering Applications. Version 1.0.

    Energy Technology Data Exchange (ETDEWEB)

    Linebarger, John Michael; Maffitt, S. Louise (New Mexico Institute of Mining and Technology, Albuquerque, NM); Glass, Robert John, Jr.; Beyeler, Walter Eugene; Brown, Theresa Jean; Ames, Arlo Leroy

    2011-10-01

    Complex Adaptive Systems of Systems, or CASoS, are vastly complex eco-socio-economic-technical systems which we must understand to design a secure future for the nation and the world. Perturbations/disruptions in CASoS have the potential for far-reaching effects due to highly-saturated interdependencies and allied vulnerabilities to cascades in associated systems. The Phoenix initiative approaches this high-impact problem space as engineers, devising interventions (problem solutions) that influence CASoS to achieve specific aspirations. CASoS embody the world's biggest problems and greatest opportunities: applications to real world problems are the driving force of our effort. We are developing engineering theory and practice together to create a discipline that is grounded in reality, extends our understanding of how CASoS behave, and allows us to better control those behaviors. Through application to real-world problems, Phoenix is evolving CASoS Engineering principles while growing a community of practice and the CASoS engineers to populate it.

  11. Hanford Central Waste Complex: Waste Receiving and Processing Facility dangerous waste permit application

    International Nuclear Information System (INIS)

    1991-10-01

    The Hanford Central Waste Complex is an existing and planned series of treatment, and/or disposal (TSD) unites that will centralize the management of solid waste operations at a single location on the Hanford Facility. The Complex includes two units: the WRAP Facility and the Radioactive Mixed Wastes Storage Facility (RMW Storage Facility). This Part B permit application addresses the WRAP Facility. The Facility will be a treatment and storage unit that will provide the capability to examine, sample, characterize, treat, repackage, store, and certify radioactive and/or mixed waste. Waste treated and stored will include both radioactive and/or mixed waste received from onsite and offsite sources. Certification will be designed to ensure and demonstrate compliance with waste acceptance criteria set forth by onsite disposal units and/or offsite facilities that subsequently are to receive waste from the WRAP Facility. This permit application discusses the following: facility description and general provisions; waste characterization; process information; groundwater monitoring; procedures to prevent hazards; contingency plant; personnel training; exposure information report; waste minimization plan; closure and postclosure requirements; reporting and recordkeeping; other relevant laws; certification

  12. Neutron Activation for Studying Hydroelectrolytic Disorders in Child Pathology; Application de l'Activation Neutronique a l'Etude des Troubles Hydroelectrolytiques en Pathologie Infantile

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, J. [Hopital Universitaire St-Pierre, Bruxelles (Belgium); Colard, J. [Centre d' Etude de l' Energie Nucleaire, Mol (Belgium); Vis, H. L. [Institut pour la Recherche Scientifique en Afrique Centrale, Bukavu (Congo, The Democratic Republic of the)

    1967-10-15

    The authors describe a method of determining electrolytes (Na, K, CI) and phosphorus in small fragments of muscle taken from child patients by needle biopsy. This method has been used to study muscular disturbances in hydroelectrolytic illnesses of childhood, whether acute, such as dehydration or toxicosis in infants, or chronic, such as malnutrition or marasmus. The results are discussed in the light of parallel data obtained by other methods of investigation. The authors also discuss the possibility of using this method to estimate intra-cellular hydroelectrolytic disorders in child pathology. (author) [French] Les auteurs presentent la description d'une methode permettant le dosage des electrolytes (Na, K, Cl) et du phosphore sur de petits fragments musculaires preleves par ponction-biopsie chez l'enfant. Cette methode a ete appliquee a l'etude des perturbations du milieu musculaire dans des troubles hydroelectrolytiques aigus (deshydratation et toxicose des nourrissons) et chroniques (malnutrition et denutrition) de l'enfance. Les resultats obtenus sont discutes a la lumiere de donnees recueillies parallelement par d'autres methodes d'investigation. Les auteurs discutent egalement la possibilite d'estimer par cette methode les perturbations hydroelectrolytiques intra-cellulaires en pathologie pediatrique. (author)

  13. The Economical Application of Non-Destructive Testing to Reactor Components, Especially Jacket Tubing; Avantages Economiques du Controle Non Destructif des Pieces de Reacteurs, Notamment des Tubes de Gainage; Ehkonomicheskoe primenenie nedestruktivnykh ispytanij dlya reaktornykh komponentov, v chastnosti obolochechnykh trub; Aplicacion en Condiciones Economicas de Ensayos No Destructivos a las Piezas de los Reactores, en Especial a los Tubos de Revestimiento

    Energy Technology Data Exchange (ETDEWEB)

    Renken, C. J. [Metallurgy Division Argonne National Laboratory Argonne, IL (United States)

    1965-10-15

    electro-magnetic method for technical as well as economic reasons. The optimum area of application of these two methods is explained as well as the large area of overlap where results produced by well- designed and properly operated equipment of both types are essentially equivalent. Spurious defect indications contribute directly to increased component costs, so an evaluation of these effects for both the ultrasonic and the electromagnetic test methods is included for several commonly encountered sources of spurious defect signals. The experience in the application of these methods at Argonne National Laboratory on relatively large quantities of tubing from various sources are recounted from the standpoint of the lowest possible inspection cost per unit length of tubing. This section also summarizes experience gained at Argonne with the newer pulsed electromagnetic test methods. The critical but generally unappreciated role of tube diameter and wall thickness on tube inspection cost is discussed. Since the question of economical inspection is closely related to allowable defect levels, defect levels and standards in use at Argonne are covered. Finally, the practical and theoretical barriers to reduced component inspection costs are enumerated and a projection of what possible reductions in cost might be attainable in the future with the ultrasonic and electromagnetic test methods is attempted. (author) [French] Le reacteur ideal aurait entre autres caracteristiques celle de ne pas exiger de controles non destructifs. Cet ideal, comme tant d'autres, ne sera probablement jamais atteint. Dans l'etude de tout reacteur pour lequel le prix de revient constitue un facteur important, il faudrait envisager la question de savoir si les pieces de ce reacteur pourront etre essayees de facon economique en meme temps que l'on examine les possibilites de fabrication. Cette partie du memoire contient quelques considerations a ce propos ainsi qu'un expose de l'importance des essais non

  14. Computer simulation of protein—carbohydrate complexes: application to arabinose-binding protein and pea lectin

    Science.gov (United States)

    Rao, V. S. R.; Biswas, Margaret; Mukhopadhyay, Chaitali; Balaji, P. V.

    1989-03-01

    The CCEM method (Contact Criteria and Energy Minimisation) has been developed and applied to study protein-carbohydrate interactions. The method uses available X-ray data even on the native protein at low resolution (above 2.4 Å) to generate realistic models of a variety of proteins with various ligands. The two examples discussed in this paper are arabinose-binding protein (ABP) and pea lectin. The X-ray crystal structure data reported on ABP-β- L-arabinose complex at 2.8, 2.4 and 1.7 Å resolution differ drastically in predicting the nature of the interactions between the protein and ligand. It is shown that, using the data at 2.4 Å resolution, the CCEM method generates complexes which are as good as the higher (1.7 Å) resolution data. The CCEM method predicts some of the important hydrogen bonds between the ligand and the protein which are missing in the interpretation of the X-ray data at 2.4 Å resolution. The theoretically predicted hydrogen bonds are in good agreement with those reported at 1.7 Å resolution. Pea lectin has been solved only in the native form at 3 Å resolution. Application of the CCEM method also enables us to generate complexes of pea lectin with methyl-α- D-glucopyranoside and methyl-2,3-dimethyl-α- D-glucopyranoside which explain well the available experimental data in solution.

  15. Molecular electrophosphorescence in (Sm, Gd)-{beta}-diketonate complex blend for OLED applications

    Energy Technology Data Exchange (ETDEWEB)

    Reyes, R., E-mail: fisicaplic@hotmail.com [Facultad de Ingenieria Quimica y Textil, Universidad Nacional de Ingenieria, UNI, Av. Tupac Amaru 210, Lima 31, Peru (Peru); Cremona, M. [DIMAT - Divisao de Metrologia de Materiais, Instituto Nacional de Metrologia, Normalizacao e Qualidade Industrial, INMETRO, Duque de Caxias, RJ (Brazil); Departamento de Fisica, Pontificia Universidade Catolica do Rio de Janeiro, PUC-Rio, C.P. 38071, Rio de Janeiro, RJ, CEP 22453-970 (Brazil); Teotonio, E.E.S. [Departamento de Quimica, CCEN, Universidade Federal da Paraiba, UFPB, C.P. 5093, Joao Pessoa, PB, CEP 5805-970 (Brazil); Brito, H.F. [Instituto de Quimica, Universidade de Sao Paulo, USP, C.P. 26077, Sao Paulo, SP, CEP 05599-970 (Brazil); Malta, O.L. [Departamento de Quimica Fundamental, CCEN, Universidade Federal de Pernambuco, Cidade Universitaria, Recife, PE, CEP 50670-901 (Brazil)

    2013-02-15

    In this work the preparation and characterization of the triple-layer organic light-emitting diode (OLED) using a mixture of the samarium and gadolinium {beta}-diketonate complexes [Sm{sub 0.5}Gd{sub 0.5}(TTA){sub 3}(TPPO){sub 2}] as emitting layer is reported. The OLED's devices contain 1-(3-methylphenyl)-1,2,3,4-tetrahydroquinoline-6-carboxyaldehyde-1, 1'-diphenylhydrazone (MTCD) as hole-transporting layer and tris(8-hydroxyquinoline aluminum) (Alq{sub 3}) as electron transporting layer. The electroluminescence spectrum present emission narrow bands from the {sup 4}G{sub 5/2}{yields}{sup 6}H{sub J} transitions (where J=5/2, 7/2 and 9/2) characteristic of the Sm{sup 3+} ion. These sharp lines are overlapped with a broad band attributed to the electrophosphorescence from the T{sub 1}{yields}S{sub 0} transition in the ligand TTA. The intramolecular energy transfer is discussed and applied on the change of the emission color of the organic LEDs at different bias voltages. - Highlights: Black-Right-Pointing-Pointer Samarium and gadolinium complexes. Black-Right-Pointing-Pointer OLED with complex blend (Sm,Gd). Black-Right-Pointing-Pointer Electrophosphorescence emission detection. Black-Right-Pointing-Pointer Application in OLED changing the color emission.

  16. Application of fluorescent monocytes for probing immune complexes on antigen microarrays.

    Directory of Open Access Journals (Sweden)

    Zoltán Szittner

    Full Text Available Microarrayed antigens are used for identifying serum antibodies with given specificities and for generating binding profiles. Antibodies bind to these arrayed antigens forming immune complexes and are conventionally identified by secondary labelled antibodies.In the body immune complexes are identified by bone marrow derived phagocytic cells, such as monocytes. In our work we were looking into the possibility of replacing secondary antibodies with monocytoid cells for the generation of antibody profiles. Using the human monocytoid cell line U937, which expresses cell surface receptors for immune complex components, we show that cell adhesion is completely dependent on the interaction of IgG heavy chains and Fcγ receptors, and this recognition is susceptible to differences between heavy chain structures and their glycosylation. We also report data on a possible application of this system in autoimmune diagnostics.Compared to secondary antibodies, fluorescent monocytesas biosensors are superior in reflecting biological functions of microarray-bound antibodies and represent an easy and robust alternative for profiling interactions between serum proteins and antigens.

  17. Molecular electrophosphorescence in (Sm, Gd)-β-diketonate complex blend for OLED applications

    International Nuclear Information System (INIS)

    Reyes, R.; Cremona, M.; Teotonio, E.E.S.; Brito, H.F.; Malta, O.L.

    2013-01-01

    In this work the preparation and characterization of the triple-layer organic light-emitting diode (OLED) using a mixture of the samarium and gadolinium β-diketonate complexes [Sm 0.5 Gd 0.5 (TTA) 3 (TPPO) 2 ] as emitting layer is reported. The OLED's devices contain 1-(3-methylphenyl)-1,2,3,4-tetrahydroquinoline-6-carboxyaldehyde-1, 1'-diphenylhydrazone (MTCD) as hole-transporting layer and tris(8-hydroxyquinoline aluminum) (Alq 3 ) as electron transporting layer. The electroluminescence spectrum present emission narrow bands from the 4 G 5/2 → 6 H J transitions (where J=5/2, 7/2 and 9/2) characteristic of the Sm 3+ ion. These sharp lines are overlapped with a broad band attributed to the electrophosphorescence from the T 1 →S 0 transition in the ligand TTA. The intramolecular energy transfer is discussed and applied on the change of the emission color of the organic LEDs at different bias voltages. - Highlights: ► Samarium and gadolinium complexes. ► OLED with complex blend (Sm,Gd). ► Electrophosphorescence emission detection. ► Application in OLED changing the color emission.

  18. Possible Utilization of Nitronitrosylruthenium Complexes as Tracers in Hydrology; Note sur l'utilisation eventuelle des complexes de nitronitrosylruthenium comme traceurs en hydrologie; O vozmozhnom ispol'zovanii kompleksa nitronitrozilruteniya v kachestve indikatorov v gidrologii; Nota sobre el posible empleo de los complejos de nitronitrosilrutenio como indicadores en hidrologia

    Energy Technology Data Exchange (ETDEWEB)

    Gailledreau, C. [Commissariat a l' Energie Atomique (France)

    1963-08-15

    Ru{sup 106} might be a useful tracer in hydrology. Its half-life of about one year is in a range in which there are few radioisotopes which can be used as tracers. There are a great variety of complexes of Ru{sup 106}, the nitro-complexes of nitrosylruthenium being amongst the most stable. Percolation tests have been made with nitronitrosylruthenium diluted in water from the mains, on columns of aquilerous sand and a very argillaceous soil. (author) [French] Le {sup 106}Ru pourrait etre un traceur interessant en hydrologie. Sa vie moyenne, environ un an, se situe dans une gamme ou il existe peu d'autres radioisotopes susceptibles d'etre utilises comme traceurs. Il existe une grande variete de complexes du les complexes nitro de nitrosylruthenium etant parmi les plus stables. Des essais de percolation ont ete effectues avec du nitronitrosylruthenium dilue dans de l'eau de ville, sur des colonnes de sable aquifere et d'un sol tres argileux. (author) [Spanish] El ''1''0''6Ru podria emplearse en calidad de indicador en hidrologia. Tiene un periodo del orden de un ano que le situa en una gama en la que existen muy pocos radioisotopos utilisable: como indicadores. El {sup 106}Ru puede formar una gran variedad de complejos, siendo los mas estables los nitrocomplejos de nitrosilrutenio. El autor ha realizado ensayos de percolacion con nitronitrosilrutenio diluido en agua de grifo, en columnas de arena acuifera y de suelo muy arcilloso. (author) [Russian] Ru{sup 106} mozhet byt' ispol'zovan v kachestve indikatora, predstavlyayushchego opredelennyj interes dlya gidrologii. Ego period poluraspada (priblizitel'n o 1'god) raspolagaetsj v gamme, gde sushchestvuet malo drugikh radioizotopov, kotorye mogut byt' ispol'zovany v kachestve indikatorov. Sushchestvuet bol'shoe mnogoobrazie kompleksov Ru{sup 106}, prichem kompleksy nitronitrozilruteniya otnosyatsya k naibolee stabil'nym. Provodilis ' opyty po perkolyatsii s nitronitrozilruteniem, rastvorennym v vodoprovodnoj vode, na

  19. Gestion des risques

    CERN Document Server

    Louisot, Jean-Paul

    2009-01-01

    Depuis le début du lie siècle, la gestion des risques connaît une véritable révolution culturelle. Jusqu'alors fonction technique, centrée autour de l'achat de couverture d'assurances, elle est devenue une discipline managériale et transversale : une valise d'instruments que chaque manager doit connaître et appliquer quels que soient son domaine de compétence et ses missions au sein de l'organisation. En effet, la gestion des risques est une culture qui doit être assimilée par chacun des acteurs. C'est précisément l'ambition des 101 questions rassemblées dans cet ouvrage : apporter à chaque manager d'entreprise, de collectivité, d'établissement de santé..., des réponses claires au " pourquoi " et au " comment " : Comment identifier les risques ? Comment analyser les risques ? Quels sont les objectifs de la gestion des risques ? Une carte des risques pour quoi faire ? Pourquoi faut-il financer les risques ? Les entreprises ont-elles des responsabilités pénales ? En quoi consiste la gestion...

  20. Synthesis of amino acid rare earth complexes and its application in agriculture

    International Nuclear Information System (INIS)

    Luo, G.-T.; Lian, P.; Hu, Y.H.; Guo, G.-R.

    1998-01-01

    Full text: The application of rare-earth compounds in agriculture has been widely reported. So far, most rare-earth compounds used in agriculture were inorganic salt and they were difficult to be absorbed by croup. The synthesis method and structure of amino acid rare-earth complexes have been reported. In this paper, we reported the preparation of mixed amino acids rare-earth complexes and their application in agriculture. The mixed amino acids were obtained by hydrolysis of waste natural protein. Rare earth was lanthanum oxide(99%). Mixed amino acids lanthanum complexes(MALa) was prepared according to the previous method. Investigation to the effect of croup by MALa, we have make tests of citrus, rice and mung bean. The results show as follows: 1) When the experiment group citrus was sprinkled twice 400ppm MALa at bouquet stage and young fruit stage, the sugar, morose, sucrose, soluble solid matter and vitamin C of fruit were increased 21%, 20%, 22%, 22% and 6% as compared to the control group, respectively. The area of leaf and foliage branch in Spring were also increased 4.6% and 2.2%. 2) When the rice was sprinkled 300ppm MALa at early tillering stage, the productively of rice was addition to 10-15%, and the relative effect of prevention was 45.61% for sheath and culm blight of rice. 3) In the test of mungbean growth, the low consistency of MALa ( 250ppm) retain from sprouting seed. As the same time, it was similar action to seeding growth. Preliminary results indicated MLAa could used as the plant growth regulation agent on the croup. Investigation to the effect of MALa on other croup and the mechanism of biological effect on the croup are still going on

  1. Sur la reconnaissance de la compétence exclusive des groupements religieux afin d‘instaurer leur structure intrinsèque et les normes intérieures des relations en tant qu’une des garanties ...

    Directory of Open Access Journals (Sweden)

    Philip Ryabykh

    2012-11-01

    SOMMAIRE: 1. Brève histoire de l’affaire – 2. Préambule – 3. Protection de la compétence exclusive des groupements religieux en vue d’instaurer leur structure intrinsèque et les normes intérieures des relations au point de vue de la législation de la Roumanie – 4. Application du principe de l’autonomie des groupements religieux et du principe de l’inadmissibilité d’intervenir pour l’État aux affaires intérieures des groupements religieux – 5. Non-contradiction de la Convention des exigences intérieures des groupements religieux sur la loyauté et la conformité des personnes se trouvant dans les relations de service avec le groupement religieux – 6. Absence des raisons fournies par les faits juridiques suffisantes et justifiant réellement l’assimilation (la mise au même niveau des groupements religieux avec n’importe quelles autres organisations-employeurs dans la sphère de la réglementation des relations de travail – 7. Légalité de l’instauration des restrictions à la création et les activités des syndicats dans les certaines sphères des relations publiques – 8. Compétence de la Roumanie de fixer dans la législation les restrictions à la liberté des syndicats conformément à la sphère des relations religieuses – 9. Signification des résultats du jugement de l’affaire «Syndicat “Le Bon Pasteur” c. Roumanie» (requête 2330/09 pour L’Église Orthodoxe Russe- 10. Conclusion.

  2. Comparing Theory and Practice: An Application of Complexity Theory to General Ridgway’s Success in Korea

    Science.gov (United States)

    2010-12-02

    will face in an uncertain future. Complexity Theory , History, Practice, Military Theory , Leadership 14. SUBJECT TERMS 70 15. NUMBER OF PAGES...complexity theory : scale, adaptive leadership , and bottom up feedback from the agents (the soldiers in the field). These are all key sub components of...Approved for Public Release; Distribution is Unlimited COMPARING THEORY AND PRACTICE: AN APPLICATION OF COMPLEXITY THEORY TO GENERAL RIDGWAY’S

  3. Automatic definition of targeted biological volumes for the radiotherapy applications; Definition automatique des volumes biologiques cibles pour les applications de radiotherapie

    Energy Technology Data Exchange (ETDEWEB)

    Hatt, M.; Visvikis, D. [LaTIM, U650 Inserm, 29 - Brest (France); Cheze-Le-Rest, C. [Service de medecine nucleaire, 29 - Brest (France); Pradier, O. [Service de radiotherapie, 29 - Brest (France)

    2009-10-15

    The proposed method: Fuzzy locally adaptive Bayesian (F.L.A.B.) showed its reliability and its precision on very complete collection of realistic simulated and real data. Its use in the context of radiotherapy allows to consider easily the studies implementation and scenari of dose painting or dose escalation, including in complex cases of heterogenous fixations. It is conceivable to apply F.L.A.B. on PET images with F.M.I.S.O. ({sup 18}F fluoro misonidazole) or F.L.T. (fluoro-L-thymidine) to complete the definition of the biological target volume. (N.C.)

  4. Télémonitorage des grandes fonctions physiologiques chez les primates vigiles Remote monitoring of physiologic functions in monkeys

    Directory of Open Access Journals (Sweden)

    Guy Germain

    2011-02-01

    Full Text Available Les caractéristiques communes à l'étude des primates non-humains sont proches des contraintes que l'on rencontre dans l'application des principes de la télémédecine humaine. Elles découlent de l’éloignement des animaux et de leur dispersion géographique pour les études en milieu naturel, elles découlent aussi du besoin de contrôler au laboratoire les traitements expérimentaux en perturbant le moins possible le comportement social des animaux. Les ondes radio sont un excellent signal de transmission pour le suivi des animaux parce qu'elles peuvent propager des informations rapidement et sur de longues distances dans l'air. Tous les dispositifs télémétriques consistent en un ou plusieurs capteurs couplés à un émetteur encodeur radio et d'un système d'antenne couplé à un récepteur décodeur, analogique ou numérique. Le progrès des télétransmissions résulte par ailleurs de la miniaturisation des dispositifs électroniques d'acquisition et d'émission qui sont de moins en moins gourmands en énergie et acquièrent des durées d'autonomie beaucoup plus grande. De nombreux dispositifs télémétriques très souvent totalement implantables dans le corps de l'animal sont aujourd'hui commercialement disponibles. Ils permettent une surveillance détaillée des paramètres physiologiques des systèmes cardiovasculaire, nerveux, locomoteur, métabolique, respiratoire et reproducteur chez les primates non-humains entièrement libres de leurs mouvements. Ils sont très largement exploités dans les études pharmacologiques et toxicologiques. D'autres dispositifs encore au stade expérimental intègrent également la combinaison de l'enregistrement télémétrique des pressions, biopotentiels musculaires ou nerveux, température, avec des enregistrements audio et vidéo pouvant être eux-mêmes acquis et transmis, partiellement ou en totalité, par télémétrie. Le développement des systèmes futurs sera probablement axé sur les

  5. Calcul des propriétés élastiques des tissus utilisés dans les matériaux composites Computation of Elastic Properties of Fabrics Used in Composite Materials

    Directory of Open Access Journals (Sweden)

    Dal Maso F.

    2006-12-01

    Full Text Available Les renforts textiles s'imposent dès qu'il faut réaliser des structures massives ou complexes en matériaux composites, comme certains raccords et jonctions de tubes, des panneaux d'habitation légère, des carters de protection de têtes de puits en fond de mer, etc. Cet article expose les caractéristiques générales d'un renfort textile, puis différentes approches micromécaniques analytiques représentant les tissus à tissage bidimensionnel sont présentées. En partant du plus simple et en allant vers le plus complexe, ces modèles sont l'analogie à un stratifié [0°/90°], la mosaïque en série et en parallèle, les ondulations 1D et les ondulations 2D série-parallèle et parallèle-série. Toutes ces approches sont fondées sur la théorie mécanique des stratifiés. En analysant les résultats d'applications numériques de ces modèles et les résultats expérimentaux, on constate que les modèles des ondulations en 2D procurent les meilleures valeurs estimées des modules élastiques. Les autres modèles n'indiquent que des ordres de grandeurs. Woven fabric reinforcements are irreplaceable from the moment that heavy or complex composite structures should be manufactured, such as some pipe connections or flanges, light panels for housing, subsea well head protection panels, etc. In this paper overall characteristics of woven fabrics are described, followed by the review of different micromechanical analytical approaches. Starting with the simplest and continueing with the more complex, these models are : the analogy with a [0°/90°] laminate, the series and parallel mosaic models, the 1D fiber undulation model, and the 2D series-parallel and parallel-series fiber undulation models. All these approaches are based on the classical laminated plate theory. Analyzing the results of numerical applications of the models and experimental results, one can notice that both 2D fiber undulation models give the best estimated values for

  6. Bringing content understanding into usability testing in complex application domains—a case study in eHealth

    DEFF Research Database (Denmark)

    Andersen, Simon Bruntse; Rasmussen, Claire Kirchert; Frøkjær, Erik

    2017-01-01

    A usability evaluation technique, Cooperative Usability Testing with Questions of Understanding (CUT with QU) intended to illuminate users’ ability to understand the content information of an application is proposed. In complex application domains as for instance the eHealth domain, this issue...... the participation of four physiotherapists and four clients in a period of 3.5 months, it was demonstrated how CUT with QU can complement conventional usability testing and provide insight into users’ challenges with understanding of a new complex eHealth application. More experiments in other complex application...... domains involving different kinds of users and evaluators are needed before we can tell whether CUT with QU is an effective usability testing technique of wider applicability. Performing CUT with QU is very demanding by drawing heavily on the evaluators’ ability to respond effectively to openings...

  7. Application of Soluplus to Improve the Flowability and Dissolution of Baicalein Phospholipid Complex

    Directory of Open Access Journals (Sweden)

    Junting Fan

    2017-05-01

    Full Text Available In this study, a novel ternary complex system (TCS composed of baicalein, phospholipids, and Soluplus was prepared to improve the flowability and dissolution for baicalein phospholipid complex (BPC. TCS was characterized using differential scanning calorimetry (DSC, infrared spectroscopy (IR, powder X-ray diffraction (PXRD, and scanning electron microscopy (SEM. The flowability, solubility, oil–water partition coefficient, in vitro dissolution, and in vivo pharmacokinetics of the system were also evaluated. DSC, IR, PXRD, and SEM data confirmed that the crystal form of baicalein disappeared in BPC and TCS. Furthermore, the angle of repose of TCS of 35° indicated an improvement in flowability, and solubility increased by approximately eight-fold in distilled water when TCS was compared with BPC (41.00 ± 4.89 μg/mL vs. 5.00 ± 0.16 μg/mL. Approximately 91.24% of TCS was released at the end of 60 min in 0.5% SDS (pH = 6.8, which suggested that TCS could improve the dissolution velocity and extent. Moreover, TCS exhibited a considerable enhancement in bioavailability with higher peak plasma concentration (25.55 μg/mL vs. 6.05 μg/mL and increased AUC0–∞ (62.47 μg·h/mL vs. 50.48 μg·h/mL with 123.75% relative bioavailability compared with BPC. Thus, Soluplus achieved the purpose of improving the flowability and solubility of baicalein phospholipid complexes. The application of Soluplus to phospholipid complexes has great potential.

  8. Application of complex discrete wavelet transform in classification of Doppler signals using complex-valued artificial neural network.

    Science.gov (United States)

    Ceylan, Murat; Ceylan, Rahime; Ozbay, Yüksel; Kara, Sadik

    2008-09-01

    In biomedical signal classification, due to the huge amount of data, to compress the biomedical waveform data is vital. This paper presents two different structures formed using feature extraction algorithms to decrease size of feature set in training and test data. The proposed structures, named as wavelet transform-complex-valued artificial neural network (WT-CVANN) and complex wavelet transform-complex-valued artificial neural network (CWT-CVANN), use real and complex discrete wavelet transform for feature extraction. The aim of using wavelet transform is to compress data and to reduce training time of network without decreasing accuracy rate. In this study, the presented structures were applied to the problem of classification in carotid arterial Doppler ultrasound signals. Carotid arterial Doppler ultrasound signals were acquired from left carotid arteries of 38 patients and 40 healthy volunteers. The patient group included 22 males and 16 females with an established diagnosis of the early phase of atherosclerosis through coronary or aortofemoropopliteal (lower extremity) angiographies (mean age, 59 years; range, 48-72 years). Healthy volunteers were young non-smokers who seem to not bear any risk of atherosclerosis, including 28 males and 12 females (mean age, 23 years; range, 19-27 years). Sensitivity, specificity and average detection rate were calculated for comparison, after training and test phases of all structures finished. These parameters have demonstrated that training times of CVANN and real-valued artificial neural network (RVANN) were reduced using feature extraction algorithms without decreasing accuracy rate in accordance to our aim.

  9. Parallelization of applications for networks with homogeneous and heterogeneous processors; Parallelisation d`applications pour des reseaux de processeurs homogenes ou heterogenes

    Energy Technology Data Exchange (ETDEWEB)

    Colombet, L

    1994-10-07

    The aim of this thesis is to study and develop efficient methods for parallelization of scientific applications on parallel computers with distributed memory. The first part presents two libraries of PVM (Parallel Virtual Machine) and MPI (Message Passing Interface) communication tools. They allow implementation of programs on most parallel machines, but also on heterogeneous computer networks. This chapter illustrates the problems faced when trying to evaluate performances of networks with heterogeneous processors. To evaluate such performances, the concepts of speed-up and efficiency have been modified and adapted to account for heterogeneity. The second part deals with a study of parallel application libraries such as ScaLAPACK and with the development of communication masking techniques. The general concept is based on communication anticipation, in particular by pipelining message sending operations. Experimental results on Cray T3D and IBM SP1 machines validates the theoretical studies performed on basic algorithms of the libraries discussed above. Two examples of scientific applications are given: the first is a model of young stars for astrophysics and the other is a model of photon trajectories in the Compton effect. (J.S.). 83 refs., 65 figs., 24 tabs.

  10. Dynamic Complexity Study of Nuclear Reactor and Process Heat Application Integration

    International Nuclear Information System (INIS)

    Taylor, J'Tia Patrice; Shropshire, David E.

    2009-01-01

    This paper describes the key obstacles and challenges facing the integration of nuclear reactors with process heat applications as they relate to dynamic issues. The paper also presents capabilities of current modeling and analysis tools available to investigate these issues. A pragmatic approach to an analysis is developed with the ultimate objective of improving the viability of nuclear energy as a heat source for process industries. The extension of nuclear energy to process heat industries would improve energy security and aid in reduction of carbon emissions by reducing demands for foreign derived fossil fuels. The paper begins with an overview of nuclear reactors and process application for potential use in an integrated system. Reactors are evaluated against specific characteristics that determine their compatibility with process applications such as heat outlet temperature. The reactor system categories include light water, heavy water, small to medium, near term high-temperature, and far term high temperature reactors. Low temperature process systems include desalination, district heating, and tar sands and shale oil recovery. High temperature processes that support hydrogen production include steam reforming, steam cracking, hydrogen production by electrolysis, and far-term applications such as the sulfur iodine chemical process and high-temperature electrolysis. A simple static matching between complementary systems is performed; however, to gain a true appreciation for system integration complexity, time dependent dynamic analysis is required. The paper identifies critical issues arising from dynamic complexity associated with integration of systems. Operational issues include scheduling conflicts and resource allocation for heat and electricity. Additionally, economic and safety considerations that could impact the successful integration of these systems are considered. Economic issues include the cost differential arising due to an integrated system

  11. Dynamic Complexity Study of Nuclear Reactor and Process Heat Application Integration

    Energy Technology Data Exchange (ETDEWEB)

    J' Tia Patrice Taylor; David E. Shropshire

    2009-09-01

    Abstract This paper describes the key obstacles and challenges facing the integration of nuclear reactors with process heat applications as they relate to dynamic issues. The paper also presents capabilities of current modeling and analysis tools available to investigate these issues. A pragmatic approach to an analysis is developed with the ultimate objective of improving the viability of nuclear energy as a heat source for process industries. The extension of nuclear energy to process heat industries would improve energy security and aid in reduction of carbon emissions by reducing demands for foreign derived fossil fuels. The paper begins with an overview of nuclear reactors and process application for potential use in an integrated system. Reactors are evaluated against specific characteristics that determine their compatibility with process applications such as heat outlet temperature. The reactor system categories include light water, heavy water, small to medium, near term high-temperature, and far term high temperature reactors. Low temperature process systems include desalination, district heating, and tar sands and shale oil recovery. High temperature processes that support hydrogen production include steam reforming, steam cracking, hydrogen production by electrolysis, and far-term applications such as the sulfur iodine chemical process and high-temperature electrolysis. A simple static matching between complementary systems is performed; however, to gain a true appreciation for system integration complexity, time dependent dynamic analysis is required. The paper identifies critical issues arising from dynamic complexity associated with integration of systems. Operational issues include scheduling conflicts and resource allocation for heat and electricity. Additionally, economic and safety considerations that could impact the successful integration of these systems are considered. Economic issues include the cost differential arising due to an integrated

  12. Feature evaluation of complex hysteresis smoothing and its practical applications to noisy SEM images.

    Science.gov (United States)

    Suzuki, Kazuhiko; Oho, Eisaku

    2013-01-01

    Quality of a scanning electron microscopy (SEM) image is strongly influenced by noise. This is a fundamental drawback of the SEM instrument. Complex hysteresis smoothing (CHS) has been previously developed for noise removal of SEM images. This noise removal is performed by monitoring and processing properly the amplitude of the SEM signal. As it stands now, CHS may not be so utilized, though it has several advantages for SEM. For example, the resolution of image processed by CHS is basically equal to that of the original image. In order to find wide application of the CHS method in microscopy, the feature of CHS, which has not been so clarified until now is evaluated correctly. As the application of the result obtained by the feature evaluation, cursor width (CW), which is the sole processing parameter of CHS, is determined more properly using standard deviation of noise Nσ. In addition, disadvantage that CHS cannot remove the noise with excessively large amplitude is improved by a certain postprocessing. CHS is successfully applicable to SEM images with various noise amplitudes. © Wiley Periodicals, Inc.

  13. PROSPECTS FOR APPLICATION OF COMPLEX-MODIFIED SAND ASPHALT CONCRETE IN ROAD CONSTRUCTION

    Directory of Open Access Journals (Sweden)

    D. Yu. Alexandrov

    2017-01-01

    Full Text Available The paper considers a possibility to use sand asphalt concrete as a material for protection of asphalt concrete and cement concrete road pavements against affection of external destructive factors. Advantages and disadvantages of sand asphalt concrete road pavements have been determined in the paper. The paper provides recommendations on improvement of sand asphalt concrete properties and contains an analysis of possible variants for usage of complex-modified sand asphalt concrete in the road construction. It has been noted that according to its potentially possible physical and mechanical properties activated quartz sand being micro-reinforced by dispersive industrial wastes is considered as an efficient component for creation of constructive layers in road asphalt concrete pavements. The paper reveals only specific aspects of the efficient application of quartz sand in road asphalt concrete. The subject of the paper loоks rather interesting for regions where there are no rock deposits for obtaining broken-stone ballast but there is rather significant spreading of local quarts sand. Its successful application is connected with the necessity to develop special equipment for physical and chemical activation of sand grain surface that permits strongly to increase an adhesive strength in the area of phase separation within the “bitumen–SiO2” system. The considered problem is a topical one and its solution will make it possible to local sand in a maximum way and partially to exclude application of broken stone in road construction.

  14. The diode pump: its application to nuclear particle counting and to the detection of rapid neutronic power excursions in atomic piles (1962); La pompe a diodes, son application au comptage de particules nucleaires et a la detection des excursions rapides de puissance neutronique d'une pile atomique (1962)

    Energy Technology Data Exchange (ETDEWEB)

    Nicolo, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1962-05-15

    This work deals in particular with three applications of an electronic device whose principle is based on that of the diode pump. 1- Linear response circuit 2- Logarithmic response circuit 3- Detection of neutronic power excursions in atomic piles using a circuit or a combination of several circuits of the linear response type. Each of the applications has been studied theoretically and experimentally. Finally, the detection of rapid power excursions is extensively discussed with reference to the many methods available, emphasis being laid on the rapidity of the electronic response. (author) [French] Cet ouvrage traite plus particulierement de trois applications d'un dispositif electronique dont le principe de fonctionnement est base sur celui de la pompe a diodes. 1- Circuit a reponse lineaire 2- Circuit a reponse logarithmique 3- Detection des excursions de puissance neutronique d'une pile atomique a l'aide d'un circuit ou d'une association de plusieurs circuits a reponse lineaire. Chacune des applications fait l'objet d'une etude theorique et experimentale. Enfin, la detection des excursions rapides de puissance est tres largement discutee a travers plusieurs methodes, notamment sur la partie concernant la rapidite de reponse de l'electronique. (auteur)

  15. Study of the selectivity of poly-nitrogenous extracting molecules in the complexation of actinides (III) and lanthanides (III) in solution in anhydrous pyridine; Etude de la selectivite de molecules extractantes polyazotees dans la complexation des actinides (III) et des lanthanides (III) en solution dans la pyridine anhydre

    Energy Technology Data Exchange (ETDEWEB)

    Riviere, Ch

    2000-10-05

    The aim of this work is to better understand the factors which contribute to the separation of lanthanides(III) and actinides(III). Polydentate nitrogenous molecules present an interesting selectivity. A thermodynamic study of the complexation in pyridine of lanthanide and uranium by the bipyridine ligand (bipy) has been carried out. The formation constants and the thermodynamic values of the different complexes have been determined. It has been shown that the bipy complexes formation is controlled by the enthalpy and unfavored by the entropy. The conductometry has revealed too a significant difference in the uranium and lanthanides complexation by the bipyridine ligand. The use of the phenanthroline ligand induces a better complexation of the metallic ions but the selectivity is not improved. On the other hand, the decrease of the basicity and the increase of the ligand denticity (for instance in the case of the use of ter-pyridine) favour the selectivity without improving the complexation. The selectivity difference for the complexation of actinides(III) and lanthanides(III) by the different studied ligands (independent systems) has been confirmed by experiments of inter-metals competition. (O.M.)

  16. Development and application of the discrete ordinate method in orthogonal curvilinear coordinates; Developpement et application de la methode des ordonnees discretes en coordonnees curvilignes orthogonales

    Energy Technology Data Exchange (ETDEWEB)

    Vaillon, R; Lallemand, M; Lemonnier, D [Ecole Nationale Superieure de Mecanique et d` Aerotechnique (ENSMA), 86 - Poitiers (France)

    1997-12-31

    The method of discrete ordinates, which is more and more widely used in radiant heat transfer studies, is mainly developed in Cartesian, (r,z) and (r,{Theta}) cylindrical, and spherical coordinates. In this study, the approach of this method is performed in orthogonal curvilinear coordinates: determination of the radiant heat transfer equation, treatment of the angular redistribution terms, numerical procedure. Some examples of application are described in 2-D geometry defined in curvilinear coordinates along a curve and at the thermal equilibrium. A comparison is made with the discrete ordinates method in association with the finite-volumes method in non structured mesh. (J.S.) 27 refs.

  17. Development and application of the discrete ordinate method in orthogonal curvilinear coordinates; Developpement et application de la methode des ordonnees discretes en coordonnees curvilignes orthogonales

    Energy Technology Data Exchange (ETDEWEB)

    Vaillon, R.; Lallemand, M.; Lemonnier, D. [Ecole Nationale Superieure de Mecanique et d`Aerotechnique (ENSMA), 86 - Poitiers (France)

    1996-12-31

    The method of discrete ordinates, which is more and more widely used in radiant heat transfer studies, is mainly developed in Cartesian, (r,z) and (r,{Theta}) cylindrical, and spherical coordinates. In this study, the approach of this method is performed in orthogonal curvilinear coordinates: determination of the radiant heat transfer equation, treatment of the angular redistribution terms, numerical procedure. Some examples of application are described in 2-D geometry defined in curvilinear coordinates along a curve and at the thermal equilibrium. A comparison is made with the discrete ordinates method in association with the finite-volumes method in non structured mesh. (J.S.) 27 refs.

  18. State of the art of parallel scientific visualization applications on PC clusters; Etat de l'art des applications de visualisation scientifique paralleles sur grappes de PC

    Energy Technology Data Exchange (ETDEWEB)

    Juliachs, M

    2004-07-01

    In this state of the art on parallel scientific visualization applications on PC clusters, we deal with both surface and volume rendering approaches. We first analyze available PC cluster configurations and existing parallel rendering software components for parallel graphics rendering. CEA/DIF has been studying cluster visualization since 2001. This report is part of a study to set up a new visualization research platform. This platform consisting of an eight-node PC cluster under Linux and a tiled display was installed in collaboration with Versailles-Saint-Quentin University in August 2003. (author)

  19. State of the art of parallel scientific visualization applications on PC clusters; Etat de l'art des applications de visualisation scientifique paralleles sur grappes de PC

    Energy Technology Data Exchange (ETDEWEB)

    Juliachs, M

    2004-07-01

    In this state of the art on parallel scientific visualization applications on PC clusters, we deal with both surface and volume rendering approaches. We first analyze available PC cluster configurations and existing parallel rendering software components for parallel graphics rendering. CEA/DIF has been studying cluster visualization since 2001. This report is part of a study to set up a new visualization research platform. This platform consisting of an eight-node PC cluster under Linux and a tiled display was installed in collaboration with Versailles-Saint-Quentin University in August 2003. (author)

  20. Effect of Ash on Oxygen Carriers for the Application of Chemical Looping Combustion to a High Carbon Char Effet des cendres sur l’activité des porteurs d’oxygène dans la combustion du charbon en boucle chimique

    Directory of Open Access Journals (Sweden)

    Rubel A.

    2011-02-01

    activity of the OCs and both OCs performed well. The results were promising for the application of CLC directly to solid fuels. L’application de la combustion en boucle chimique (CLC aux combustibles solides est actuellement étudiée à l’Université du Kentucky, au Centre de Recherche de l’Energie Appliquée (CAER dans le but de développer un procédé de gazéification/combustion en boucle chimique pressurisé (PCLC/G afin de générer de l’électricité à partir de charbon. Un des principaux aspects de la combustion en boucle chimique de combustibles solides est la compréhension de l’effet des cendres sur la réactivité des porteurs d’oxygène (OCs. L’effet des cendres sur la capacité de transfert d’oxygène et sur l’aptitude à oxyder le charbon est étudié avec deux porteurs d’oxygène à base d’oxydes de fer. Les cendres utilisées sont des cendres volantes provenant d’une centrale thermique au charbon. Les expériences sont réalisées dans un système composé d’une thermo-balance couplée à un spectrographe de masse (TGMS dans lequel on utilise d’abord 500 mg d’un mélange de cendres/porteurs d’oxygène à différentes concentrations de cendres allant jusqu’à 75 %. Le gaz réducteur est composé de 10 % de H2, 15 % de CO, 20 % de CO2 et de 55 % de Ar; et le gaz oxydant est composé de 20 % de O2 dans Ar. Les réactions d’oxydation/réduction sont quasi totales. D’après ces expériences, les cendres ont une activité propre de porteur d’oxygène, liée à la présence de fer dans les cendres, confirmée par les analyses DRX. Cela génère une augmentation du gain ou de la perte de masse du mélange pendant l’oxydation/réduction. Les vitesses d’oxydation/réduction augmentent avec la concentration des cendres à cause de l’augmentation de la porosité du mélange de porteurs d’oxygène avec les cendres, ce qui permet un meilleur accès des gaz réactifs sur les sites actifs des porteurs d’oxygène. Dans un

  1. Thermoluminescent properties of CVD diamond: applications to ionising radiation dosimetry; Proprietes thermoluminescentes du diamant CVD: applications a la dosimetrie des rayonnements ionisants

    Energy Technology Data Exchange (ETDEWEB)

    Petitfils, A

    2007-09-15

    Remarkable properties of synthetic diamond (human soft tissue equivalence, chemical stability, non-toxicity) make this material suitable for medical application as thermoluminescent dosimeter (TLD). This work highlights the interest of this material as radiotherapy TLD. In the first stage of this work, we looked after thermoluminescent (TL) and dosimetric properties of polycrystalline diamond made by Chemically Vapor Deposited (CVD) synthesis. Dosimetric characteristics are satisfactory as TLD for medical application. Luminescence thermal quenching on diamond has been investigated. This phenomenon leads to a decrease of dosimetric TL peak sensitivity when the heating rate increases. The second part of this work analyses the use of synthetic diamond as TLD in radiotherapy. Dose profiles, depth dose distributions and the cartography of an electron beam obtained with our samples are in very good agreement with results from an ionisation chamber. It is clearly shown that CVD) diamond is of interest to check beams of treatment accelerators. The use of these samples in a control of treatment with Intensity Modulated Radiation Therapy underlines good response of synthetic diamond in high dose gradient areas. These results indicate that CVD diamond is a promising material for radiotherapy dosimetry. (author)

  2. The development and application of composite complexity models and a relative complexity metric in a software maintenance environment

    Science.gov (United States)

    Hops, J. M.; Sherif, J. S.

    1994-01-01

    A great deal of effort is now being devoted to the study, analysis, prediction, and minimization of software maintenance expected cost, long before software is delivered to users or customers. It has been estimated that, on the average, the effort spent on software maintenance is as costly as the effort spent on all other software costs. Software design methods should be the starting point to aid in alleviating the problems of software maintenance complexity and high costs. Two aspects of maintenance deserve attention: (1) protocols for locating and rectifying defects, and for ensuring that noe new defects are introduced in the development phase of the software process; and (2) protocols for modification, enhancement, and upgrading. This article focuses primarily on the second aspect, the development of protocols to help increase the quality and reduce the costs associated with modifications, enhancements, and upgrades of existing software. This study developed parsimonious models and a relative complexity metric for complexity measurement of software that were used to rank the modules in the system relative to one another. Some success was achieved in using the models and the relative metric to identify maintenance-prone modules.

  3. La quête des températures ultrabasses

    OpenAIRE

    Suchet , Daniel

    2018-01-01

    International audience; Des vendeurs de glace à l'industrie cryogénique, le froid est souvent perçu comme un produit. Pour le physicien, le froid, réduction de l'agitation aléatoire des particules, apparaît plutôt comme une force productrice, capable de faire émerger des structures complexes et de métamorphoser les propriétés des objets. Les basses températures ont été l'enjeu d'une course effrénée dont la première phase a pris fin en 1908 avec la liquéfaction de l'ensemble des gaz connus. Lo...

  4. Droit des organisations internationales

    CERN Document Server

    Sorel, Jean-Marc; Ndior, Valère

    2013-01-01

    Cet ouvrage collectif offre aux enseignants et chercheurs en droit international, aux praticiens et aux étudiants, une analyse actualisée du droit des organisations internationales. Il dresse en cinq parties un tableau, illustré par des exemples variés, des problématiques que soulève le phénomène polymorphe d institutionnalisation de la société internationale. La première partie est consacrée au phénomène des « organisations internationales », sous l angle à la fois de l institutionnalisation progressive des relations internationales et de la difficulté à cerner une catégorie unifiée. La deuxième partie rend compte de la création, de la disparition et des mutations des organisations internationales, ici envisagées comme systèmes institutionnels et ordres juridiques dérivés. La troisième partie analyse l autonomie que l acquisition de la personnalité juridique et de privilèges et immunités, un organe administratif intégré, un personnel ou un budget propres confèrent aux organi...

  5. Cluster-Expansion Model for Complex Quinary Alloys: Application to Alnico Permanent Magnets

    Science.gov (United States)

    Nguyen, Manh Cuong; Zhou, Lin; Tang, Wei; Kramer, Matthew J.; Anderson, Iver E.; Wang, Cai-Zhuang; Ho, Kai-Ming

    2017-11-01

    An accurate and transferable cluster-expansion model for complex quinary alloys is developed. Lattice Monte Carlo simulation enabled by this cluster-expansion model is used to investigate temperature-dependent atomic structure of alnico alloys, which are considered as promising high-performance non-rare-earth permanent-magnet materials for high-temperature applications. The results of the Monte Carlo simulations are consistent with available experimental data and provide useful insights into phase decomposition, selection, and chemical ordering in alnico. The simulations also reveal a previously unrecognized D 03 alloy phase. This phase is very rich in Ni and exhibits very weak magnetization. Manipulating the size and location of this phase provides a possible route to improve the magnetic properties of alnico, especially coercivity.

  6. Application of the decoupling scheme on complex neutron-gamma shielding problems

    Energy Technology Data Exchange (ETDEWEB)

    Feher, S. [Institute of Nuclear Technology, Technical University of Budapest, Budapest (Hungary); Leege, P.F.A. de; Hoogenboom, J.E.; Kloosterman, J.L. [Interfaculty Reactor Institute, Delft University of Technology, Delft (Netherlands)

    2000-03-01

    Coupled neutron-gamma shielding calculations using S{sub n} transport theory can be time consuming, especially for two- and three-dimensional geometries. In general, the CPU time of these calculations increases stronger than linear with increasing number of neutron and gamma energy groups, and depends on the order of Legendre expansion and number of S{sub n} directions used. This fact induced the idea of the decoupling method, which seems applicable to accelerate coupled neutron-gamma shielding calculations. The data included in a combined neutron-gamma library can be readily separated into a library containing neutron data only and another library containing gamma data only. Separate calculations for neutrons and gammas are performed on complex geometries using a different Legendre order expansion for neutrons and gammas. CPU savings of 60 to 85% can be achieved for the two-dimensional DORT and three-dimensional TORT calculations respectively. (author)

  7. Design of experiments for identification of complex biochemical systems with applications to mitochondrial bioenergetics.

    Science.gov (United States)

    Vinnakota, Kalyan C; Beard, Daniel A; Dash, Ranjan K

    2009-01-01

    Identification of a complex biochemical system model requires appropriate experimental data. Models constructed on the basis of data from the literature often contain parameters that are not identifiable with high sensitivity and therefore require additional experimental data to identify those parameters. Here we report the application of a local sensitivity analysis to design experiments that will improve the identifiability of previously unidentifiable model parameters in a model of mitochondrial oxidative phosphorylation and tricaboxylic acid cycle. Experiments were designed based on measurable biochemical reactants in a dilute suspension of purified cardiac mitochondria with experimentally feasible perturbations to this system. Experimental perturbations and variables yielding the most number of parameters above a 5% sensitivity level are presented and discussed.

  8. Development of the vitrification compositional envelope to support complex-wide application of MAWS technology

    International Nuclear Information System (INIS)

    Mazer, J.J.; Muller, I.S.; Gan, H.; Buechele, A.C.; Lai, S.T.; Pegg, I.L.

    1996-09-01

    This report presents the results from a study of the application of the Minimum Additive Waste Stabilization (MAWS) approach using vitrification as a treatment technology to a variety of waste streams across the DOE complex. This work has involved both experimental vitrification work using actual mixed wastes and surrogate waste streams from several DOE sites (Hanford, Idaho, and Oak Ridge) as well as the development of a computer-based, integrated glass property-composition database. The long-term objective is that this data base will assist glass formulation studies with single waste streams or combinations of waste streams subject to a variety of user-imposed constraints including waste stream usage priorities, process related constraints (e.g., melt viscosity, electrical conductivity, etc.), and waste form performance related constraints (e.g., TCLP and PCT leaching results). 79 refs., 143 figs., 65 tabs

  9. Nonlinear Dynamics in Complex Systems Theory and Applications for the Life-, Neuro- and Natural Sciences

    CERN Document Server

    Fuchs, Armin

    2013-01-01

    With many areas of science reaching across their boundaries and becoming more and more interdisciplinary, students and researchers in these fields are confronted with techniques and tools not covered by their particular education. Especially in the life- and neurosciences quantitative models based on nonlinear dynamics and complex systems are becoming as frequently implemented as traditional statistical analysis. Unfamiliarity with the terminology and rigorous mathematics may discourage many scientists to adopt these methods for their own work, even though such reluctance in most cases is not justified.This book bridges this gap by introducing the procedures and methods used for analyzing nonlinear dynamical systems. In Part I, the concepts of fixed points, phase space, stability and transitions, among others, are discussed in great detail and implemented on the basis of example elementary systems. Part II is devoted to specific, non-trivial applications: coordination of human limb movement (Haken-Kelso-Bunz ...

  10. Optimal sensor configuration for complex systems with application to signal detection in structures

    DEFF Research Database (Denmark)

    Sadegh, Payman; Spall, J. C.

    2000-01-01

    sensor outputs. Secondly, we describe an efficient and practical algorithm to achieve the optimization goals, based on simultaneous perturbation stochastic approximation (SPSA). SPSA avoids the need for detailed modeling of the sensor response by simply relying on observed responses as obtained......The paper considers the problem of sensor configuration for complex systems. The contribution of the paper is twofold. Firstly, we define an appropriate criterion that is based on maximizing overall sensor responses while minimizing redundant information as measured by correlations between multiple...... by limited experimentation with test sensor configurations. We illustrate the application of the approach to optimal placement of acoustic sensors for signal detection in structures. This includes both a computer simulation study for an aluminum plate, and real experimentations on a steel I-beam....

  11. Investigation and analytical application of thorium and uranium complexes with amino acids

    International Nuclear Information System (INIS)

    Korenman, I.M.; Sergeev, G.M.

    1979-01-01

    The coordination is investigated of thorium (4) and uranium (6) with aminoacids, particularly, with aspartic acid. With the latter the metals form chelates, which have a particular structure and a stationary inner sphere. A description is made of the composition, conditions of formation (gr H), and a stability of some asparaginate complexes of actinoids, the coordination methods of aspartic acid. An asparaginatometric method is proposed for a direct complexometric titration of microgram amounts of thorium in the presence of uranium, zirconium and rare earth elements with photometric indication. As metal-chromic indicators the sulfophthaleins are applied. The given procedure allows measurement of impurities of accompanying elements, viz., beryllium (up to 1%) in thorium preparations. Application of aspartic acid and arsenazo 1 indicator permits us to define Be(2) with a relative error not higher than 5% in thorium compounds, which exclude the analysis by other methods

  12. Evidence of different stoichiometries for the limiting carbonate complexes of lanthanides(3); Mise en evidence d'un changement de stoechiometrie du complexe carbonate limite au sein de la serie des lanthanides(3)

    Energy Technology Data Exchange (ETDEWEB)

    Philippini, V

    2007-12-15

    Two stoichiometries have been proposed by different laboratories to interpret measurements on the limiting carbonate complexes of An{sup 3+} and Ln{sup 3+} cations. The study of the solubility of double carbonates (AlkLn(CO{sub 3}){sub 2},xH{sub 2}O) in concentrated carbonate solutions at room temperature and high ionic strengths has shown that on the one hand the lightest lanthanides (La and Nd) form Ln(CO{sub 3}){sub 4}{sup 5-} whereas the heaviest (Eu and Dy) form Ln(CO{sub 3}){sub 3}{sup 3-} in the studied chemical conditions, and on the other hand, that the kinetics of precipitation of double carbonates depends on the alkali metal and the lanthanide ions. The existence of two stoichiometries for the limiting carbonate complexes was confirmed by capillary electrophoresis hyphenated to an inductively coupled plasma mass spectrometer (CE-ICP-MS), used to extend the study to the whole series of lanthanides (except Ce, Pm and Yb). Two behaviours have been put forward comparing the electrophoretic mobilities: La to Tb form Ln(CO{sub 3}){sub 4}{sup 5-} while Dy to Lu form Ln(CO{sub 3}){sub 3}{sup 3-}. Measurements by time resolved laser fluorescence spectroscopy (TRLFS) on Eu(III) indicate small variations of the geometry of Eu(CO{sub 3}){sub 3}{sup 3-} complex, specially with Cs{sup +}. Although analogies are currently used among the 4f-block trivalent elements, different aqueous speciations are evidenced in concentrated carbonate solutions across the lanthanide series. (author)

  13. Organisation des travaux ST-CV

    CERN Document Server

    Martel, C; CERN. Geneva. ST Division

    2003-01-01

    Débutée il y a deux ans, la phase de construction des installations de refroidissement du LHC a atteint en 2003 son apogée. De nombreux autres projets sont également gérés par le groupe dans divers secteurs du laboratoire. La spécificité du groupe est de réaliser des installations complexes impliquant des spécificités diverses telles qu’aéraulique, hydraulique, électrique, etc. Pour faire face à ces demandes la section travaux du groupe ST CV a adopté une structure capable de réaliser ces divers projets avec un minimum de personnel. La première partie de ce document décrit l’organisation de la section travaux ST CV. Dans une deuxième partie, les auteurs dressent un état des lieux des chantiers par projet en décrivant plus particulièrement les activités dans les domaines du traitement d’air et de refroidissement par eau.

  14. Demonstration of the 3D PANTHERE software for the simulation of gamma dose rates for complex nuclear installations; Demonstration du logiciel 3D panthere pour la simulation des debits de doses gamma pour installations nucleaires complexes

    Energy Technology Data Exchange (ETDEWEB)

    Longeot, M.; Dupont, B. [EDFISEPTENITE, 12-14 avenue Dutrievoz, 69628 Villeurbanne Cedex (France); Schumm, A.; Zweers, M. [EDF/R and D/SINETICS, 1 avenue du General de Gaulle, 92141 Clamart Cedex (France); Malvagi, F.; Trama, J.C. [CEA Saclay, SERMA, 91 - Gif-sur-Yvette (France)

    2010-07-01

    The authors present the two successive versions of the PANTHERE simulation software developed by EDF-SEPTEN to determine gamma dose flow rate in complex industrial installations. This software predicts dose rates and thus enables interventions in irradiating environment to be optimized. The authors report the demonstration of the industrial version (PANTHEREv1) and of the currently under development version (PANTHEREv2). They outline the evolutions brought to the first version to develop the second one such as the direct importation of CAD models, ergonomic improvements, etc.

  15. The sequential application of macroalgal biosorbents for the bioremediation of a complex industrial effluent.

    Directory of Open Access Journals (Sweden)

    Joel T Kidgell

    Full Text Available Fe-treated biochar and raw biochar produced from macroalgae are effective biosorbents of metalloids and metals, respectively. However, the treatment of complex effluents that contain both metalloid and metal contaminants presents a challenging scenario. We test a multiple-biosorbent approach to bioremediation using Fe-biochar and biochar to remediate both metalloids and metals from the effluent from a coal-fired power station. First, a model was derived from published data for this effluent to predict the biosorption of 21 elements by Fe-biochar and biochar. The modelled outputs were then used to design biosorption experiments using Fe-biochar and biochar, both simultaneously and in sequence, to treat effluent containing multiple contaminants in excess of water quality criteria. The waste water was produced during ash disposal at an Australian coal-fired power station. The application of Fe-biochar and biochar, either simultaneously or sequentially, resulted in a more comprehensive remediation of metalloids and metals compared to either biosorbent used individually. The most effective treatment was the sequential use of Fe-biochar to remove metalloids from the waste water, followed by biochar to remove metals. Al, Cd, Cr, Cu, Mn, Ni, Pb, Zn were reduced to the lowest concentration following the sequential application of the two biosorbents, and their final concentrations were predicted by the model. Overall, 17 of the 21 elements measured were remediated to, or below, the concentrations that were predicted by the model. Both metalloids and metals can be remediated from complex effluent using biosorbents with different characteristics but derived from a single feedstock. Furthermore, the extent of remediation can be predicted for similar effluents using additive models.

  16. The sequential application of macroalgal biosorbents for the bioremediation of a complex industrial effluent.

    Science.gov (United States)

    Kidgell, Joel T; de Nys, Rocky; Paul, Nicholas A; Roberts, David A

    2014-01-01

    Fe-treated biochar and raw biochar produced from macroalgae are effective biosorbents of metalloids and metals, respectively. However, the treatment of complex effluents that contain both metalloid and metal contaminants presents a challenging scenario. We test a multiple-biosorbent approach to bioremediation using Fe-biochar and biochar to remediate both metalloids and metals from the effluent from a coal-fired power station. First, a model was derived from published data for this effluent to predict the biosorption of 21 elements by Fe-biochar and biochar. The modelled outputs were then used to design biosorption experiments using Fe-biochar and biochar, both simultaneously and in sequence, to treat effluent containing multiple contaminants in excess of water quality criteria. The waste water was produced during ash disposal at an Australian coal-fired power station. The application of Fe-biochar and biochar, either simultaneously or sequentially, resulted in a more comprehensive remediation of metalloids and metals compared to either biosorbent used individually. The most effective treatment was the sequential use of Fe-biochar to remove metalloids from the waste water, followed by biochar to remove metals. Al, Cd, Cr, Cu, Mn, Ni, Pb, Zn were reduced to the lowest concentration following the sequential application of the two biosorbents, and their final concentrations were predicted by the model. Overall, 17 of the 21 elements measured were remediated to, or below, the concentrations that were predicted by the model. Both metalloids and metals can be remediated from complex effluent using biosorbents with different characteristics but derived from a single feedstock. Furthermore, the extent of remediation can be predicted for similar effluents using additive models.

  17. Instructions for the use of the methodological tools applicable to polluted sites and soils; Mode d'emploi des outils methodologiques applicables aux sites et sols pollues

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    The French policy in the domain of polluted sites and soils is based on a limited number of principles which are: the prevention of future pollutions, the identification of all possible potential risks, a well-suited treatment process which depends on the effective environmental impact and on the intended use of the site. This document aims at identifying the main questions raised by a given situation. It proposed useful methodological tools for the construction of answers to the problems encountered: 1 - general approach (main guidelines for the different steps of the management of a polluted site, different possible approaches); 2 - examples of application (industrial site in use, closing down of an industrial site, accidental situation (recent pollution), fortuitous discovery of a pollution on a site, pollutions with limited surface extension, site involved in a land transaction, polluted site with a sensible use, industrial waste lands). (J.S.)

  18. Industrial applications of membrane processes in chemistry and energy generation; Applications industrielles des procedes membranaires en chimie et production d'energie

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    The French membranes club (CFM), with the sustain of the French institute of petroleum (IFP) has organized this meeting which aims to present the most recent industrial realizations in the domain of membrane processes in the chemistry and energy generation sectors. This document gathers the abstracts of the presentations: 1 - hydrogen purification and CO{sub 2} extraction: development of polymer matrix and metal nano-particulate hybrid membranes for selective membrane applications; study of silicone-based mixed matrix membranes for hydrogen purification via inverse selectivity principle; CO{sub 2} capture from gaseous effluents for its sequestration: role and limitations of membrane processes; membranes and processes for the abatement of the acid gas content of smokes; new structural model for Nafion{sup R} membranes, the benchmark polymer for low temperature fuel cells; 2 - molecular screen-based membranes: MFI-alumina nano-composite ceramic membranes: preparation and characterization, gaseous transport and separation; characterization and permeation properties of supported MFI membranes; in-situ measurement of butane isomers diffusion in MFI zeolite membranes through transient permeation tests; 3 - vapors separation: stability of silver particulates in PA12-PTMO/AgBF{sub 4} composite membranes and its effect on the easier ethylene transport inside these membranes; 4 - separation of liquid organic mixtures: isomers separation using cyclo-dextrins bearing membranes: application to the extraction and separation of xylene isomers; electrodialysis in organic environment: application to the electro-synthesis; study of polymer materials permeability; 5 - treatment of industrial waters: use of NanoFlux software in the modeling of nano-filtration membrane processes in the chemical industry: elimination of sulfate impurities from 'Chloralkali' brines; ultra-filtration of a wastewater containing partially emulsified oil; efficiency of a hybrid membrane separation

  19. Application of simplified Complexity Theory concepts for healthcare social systems to explain the implementation of evidence into practice.

    Science.gov (United States)

    Chandler, Jacqueline; Rycroft-Malone, Jo; Hawkes, Claire; Noyes, Jane

    2016-02-01

    To examine the application of core concepts from Complexity Theory to explain the findings from a process evaluation undertaken in a trial evaluating implementation strategies for recommendations about reducing surgical fasting times. The proliferation of evidence-based guidance requires a greater focus on its implementation. Theory is required to explain the complex processes across the multiple healthcare organizational levels. This social healthcare context involves the interaction between professionals, patients and the organizational systems in care delivery. Complexity Theory may provide an explanatory framework to explain the complexities inherent in implementation in social healthcare contexts. A secondary thematic analysis of qualitative process evaluation data informed by Complexity Theory. Seminal texts applying Complexity Theory to the social context were annotated, key concepts extracted and core Complexity Theory concepts identified. These core concepts were applied as a theoretical lens to provide an explanation of themes from a process evaluation of a trial evaluating the implementation of strategies to reduce surgical fasting times. Sampled substantive texts provided a representative spread of theoretical development and application of Complexity Theory from late 1990's-2013 in social science, healthcare, management and philosophy. Five Complexity Theory core concepts extracted were 'self-organization', 'interaction', 'emergence', 'system history' and 'temporality'. Application of these concepts suggests routine surgical fasting practice is habituated in the social healthcare system and therefore it cannot easily be reversed. A reduction to fasting times requires an incentivised new approach to emerge in the surgical system's priority of completing the operating list. The application of Complexity Theory provides a useful explanation for resistance to change fasting practice. Its utility in implementation research warrants further attention and

  20. Bringing content understanding into usability testing in complex application domains—a case study in eHealth

    DEFF Research Database (Denmark)

    Andersen, Simon Bruntse; Rasmussen, Claire Kirchert; Frøkjær, Erik

    2017-01-01

    A usability evaluation technique, Cooperative Usability Testing with Questions of Understanding (CUT with QU) intended to illuminate users’ ability to understand the content information of an application is proposed. In complex application domains as for instance the eHealth domain, this issue...... of users’ content understanding is sometimes crucial, and thus should be carefully evaluated. Unfortunately, conventional usability evaluation techniques do not address challenges of content understanding. In a case study within eHealth, specifically the setting of a rehabilitation clinic involving...... the participation of four physiotherapists and four clients in a period of 3.5 months, it was demonstrated how CUT with QU can complement conventional usability testing and provide insight into users’ challenges with understanding of a new complex eHealth application. More experiments in other complex application...