Comparison of seismic sources for shallow seismic: sledgehammer and pyrotechnics

Directory of Open Access Journals (Sweden)

Brom Aleksander

2015-10-01

Full Text Available The pyrotechnic materials are one of the types of the explosives materials which produce thermal, luminous or sound effects, gas, smoke and their combination as a result of a self-sustaining chemical reaction. Therefore, pyrotechnics can be used as a seismic source that is designed to release accumulated energy in a form of seismic wave recorded by tremor sensors (geophones after its passage through the rock mass. The aim of this paper was to determine the utility of pyrotechnics for shallow seismic engineering. The work presented comparing the conventional method of seismic wave excitation for seismic refraction method like plate and hammer and activating of firecrackers on the surface. The energy released by various sources and frequency spectra was compared for the two types of sources. The obtained results did not determine which sources gave the better results but showed very interesting aspects of using pyrotechnics in seismic measurements for example the use of pyrotechnic materials in MASW.

Uranium Pyrophoricity Phenomena and Prediction (FAI/00-39)

International Nuclear Information System (INIS)

PLYS, M.G.

2000-01-01

The purpose of this report is to provide a topical reference on the phenomena and prediction of uranium pyrophoricity for the Hanford Spent Nuclear Fuel (SNF) Project with specific applications to SNF Project processes and situations. Spent metallic uranium nuclear fuel is currently stored underwater at the K basins in the Hanford 100 area, and planned processing steps include: (1) At the basins, cleaning and placing fuel elements and scrap into stainless steel multi-canister overpacks (MCOs) holding about 6 MT of fuel apiece; (2) At nearby cold vacuum drying (CVD) stations, draining, vacuum drying, and mechanically sealing the MCOs; (3) Shipping the MCOs to the Canister Storage Building (CSB) on the 200 Area plateau; and (4) Welding shut and placing the MCOs for interim (40 year) dry storage in closed CSB storage tubes cooled by natural air circulation through the surrounding vault. Damaged fuel elements have exposed and corroded fuel surfaces, which can exothermically react with water vapor and oxygen during normal process steps and in off-normal situations, A key process safety concern is the rate of reaction of damaged fuel and the potential for self-sustaining or runaway reactions, also known as uranium fires or fuel ignition. Uranium metal and one of its corrosion products, uranium hydride, are potentially pyrophoric materials. Dangers of pyrophoricity of uranium and its hydride have long been known in the U.S. Department of Energy (Atomic Energy Commission/DOE) complex and will be discussed more below; it is sufficient here to note that there are numerous documented instances of uranium fires during normal operations. The motivation for this work is to place the safety of the present process in proper perspective given past operational experience. Steps in development of such a perspective are: (1) Description of underlying physical causes for runaway reactions, (2) Modeling physical processes to explain runaway reactions, (3) Validation of the method

Hazard-Free Pyrotechnic Simulator

Science.gov (United States)

Mcalister, William B., Jr.

1988-01-01

Simulator evaluates performance of firing circuits for electroexplosive devices (EED's) safely and inexpensively. Tests circuits realistically when pyrotechnic squibs not connected and eliminates risks of explosions. Used to test such devices as batteries where test conditions might otherwise degrade them.

Uranium Pyrophoricity Phenomena and Prediction (FAI/00-39)

Energy Technology Data Exchange (ETDEWEB)

PLYS, M.G.

2000-10-10

The purpose of this report is to provide a topical reference on the phenomena and prediction of uranium pyrophoricity for the Hanford Spent Nuclear Fuel (SNF) Project with specific applications to SNF Project processes and situations. Spent metallic uranium nuclear fuel is currently stored underwater at the K basins in the Hanford 100 area, and planned processing steps include: (1) At the basins, cleaning and placing fuel elements and scrap into stainless steel multi-canister overpacks (MCOs) holding about 6 MT of fuel apiece; (2) At nearby cold vacuum drying (CVD) stations, draining, vacuum drying, and mechanically sealing the MCOs; (3) Shipping the MCOs to the Canister Storage Building (CSB) on the 200 Area plateau; and (4) Welding shut and placing the MCOs for interim (40 year) dry storage in closed CSB storage tubes cooled by natural air circulation through the surrounding vault. Damaged fuel elements have exposed and corroded fuel surfaces, which can exothermically react with water vapor and oxygen during normal process steps and in off-normal situations, A key process safety concern is the rate of reaction of damaged fuel and the potential for self-sustaining or runaway reactions, also known as uranium fires or fuel ignition. Uranium metal and one of its corrosion products, uranium hydride, are potentially pyrophoric materials. Dangers of pyrophoricity of uranium and its hydride have long been known in the U.S. Department of Energy (Atomic Energy Commission/DOE) complex and will be discussed more below; it is sufficient here to note that there are numerous documented instances of uranium fires during normal operations. The motivation for this work is to place the safety of the present process in proper perspective given past operational experience. Steps in development of such a perspective are: (1) Description of underlying physical causes for runaway reactions, (2) Modeling physical processes to explain runaway reactions, (3) Validation of the method

Pyrotechnic Tubing Connector

Science.gov (United States)

Graves, Thomas J.; Yang, Robert A.

1988-01-01

Tool forms mechanical seal at joint without levers or hydraulic apparatus. Proposed tool intended for use in outer space used on Earth by heavily garbed workers to join tubing in difficult environments. Called Pyrotool, used with Lokring (or equivalent) fittings. Piston slides in cylinder when pushed by gas from detonating pyrotechnic charge. Impulse of piston compresses fittings, sealing around butting ends of tubes.

Tethered Pyrotechnic Apparatus for Acquiring a Ground Sample

Science.gov (United States)

Jones, Jack; Zimmerman, Wayne; Wu, Jiunn Jenq; Badescu, Mircea; Sherrit, Stewart

2009-01-01

A proposed alternative design for the balloon-borne ground-sampling system described in the immediately preceding article would not rely on free fall to drive a harpoonlike sample-collecting device into the ground. Instead, the harpoon-like sample-collecting device would be a pyrotechnically driven, tethered projectile. The apparatus would include a tripod that would be tethered to the gondola. A gun for shooting the projectile into the ground would be mounted at the apex of the tripod. The gun would include an electronic trigger circuit, a chamber at the breech end containing a pyrotechnic charge, and a barrel. A sabot would be placed in the barrel just below the pyrotechnic charge, and the tethered projectile would be placed in the barrel just below the sabot. The tripod feet would be equipped with contact sensors connected to the trigger circuit. In operation, the tripod would be lowered to the ground on its tether. Once contact with the ground was detected by the sensors on all three tripod feet, the trigger circuit would fire the pyrotechnic charge to drive the projectile into the ground. (Requiring contact among all three tripod feet and the ground would ensure that the projectile would be fired into the ground, rather than up toward the gondola or the balloon.) The tethered projectile would then be reeled back up to the gondola for analysis of the sample.

Morphology and composition of pyrotechnic residues formed at different levels of confinement.

Science.gov (United States)

Vermeij, Erwin; Duvalois, Willem; Webb, Rutger; Koeberg, Mattijs

2009-04-15

Post explosion residues (PER) are residues from pyrotechnic compositions or explosives that are generated during an explosion. In the recent past SEM/EDX was used several times to analyze PER from pyrotechnic compositions. The results from these studies suggest that there might be a difference in morphology and composition of pyrotechnic residues formed at different levels of confinement. Also because of general thermodynamic principles it is believed that at higher levels of confinement the final pressure and temperature during the explosion is probably (but not necessarily) higher, eventually resulting in smaller and more spherical particles and a more homogeneous elemental composition. If there is a relation between morphology and composition of pyrotechnic residues and the level of confinement at which these are formed, it would be possible to draw conclusions about the conditions at which pyrotechnic residues were formed and the kind and construction of the device used. This may aid forensic scientists not only in the determination of the original explosive composition, but also of the explosive device. To perform controlled experiments with pyrotechnic charges at, at least, two pre-set levels of confinement a test vessel was built by TNO Defence, Security and Safety. For this study, three different flash powder compositions and black powder were selected. The generated residues were sampled on collecting plates and Nucleopore filters connected to a pump system in the immediate vicinity of the venting area for further analyses by SEM/EDX and XRD. From the results it follows that in the pressure range studied, the level of confinement seems to have a minor effect on the features of the generated residue particles. Because passive sampling by means of collector plates seemed doubtful and because the number of experiments had to be limited it is impossible to draw definitive conclusions. In addition to the level of confinement several other variables may affect

Management of waste cladding hulls. Part II. An assessment of zirconium pyrophoricity and recommendations for handling waste hulls

International Nuclear Information System (INIS)

Kullen, B.J.; Levitz, N.M.; Steindler, M.J.

1977-11-01

This report reviews experience and research related to the pyrophoricity of zirconium and zirconium alloys. The results of recent investigations of the behavior of Zircaloy and some observations of industrial handling and treatment of Zircaloy tubing and scrap are also discussed. A model for the management of waste Zircaloy cladding hulls from light water reactor fuel reprocessing is offered, based on an evaluation of the reviewed information. It is concluded that waste Zircaloy cladding hulls do not constitute a pyrophoric hazard if, following the model flow sheet, finely divided metal is oxidized during the management procedure. Steps alternative to the model are described which yield zirconium in deactivated form and also accomplish varying degrees of transuranic decontamination. Information collected into appendixes is (1) a collation of zirconium pyrophoricity data from the literature, (2) calculated radioactivity contents in Zircaloy cladding hulls from spent LWR fuels, and (3) results of a laboratory study on volatilization of zirconium from Zircaloy using HCl or Cl 2

Impact of Pyrotechnics over the Architectonic Heritage

Directory of Open Access Journals (Sweden)

Angel T. Lloret

2017-01-01

Full Text Available The use of pyrotechnics near to the historical heritage such as walls, facades, church, or fortifications of a city is nowadays a topic of discussion. There is not a clear legislation about the use of pyrotechnics near to these buildings and how they can be affected by the expansive wave generated by the use of harquebusiers, fireworks, and cannons during the simulation of a battle. For this reason, this paper presents some practical tests that measure the vibroacoustic effect when these types of pyrotechnics are used near to the architectonical heritage. In order to collect these data, we have used several sound level meters and accelerometers placed on two different scenarios. The first one was placed near to the beach and the other one was placed in a building of a narrow alley. The tests were carried out during the festival of Moors and Christians of Villajoyosa (Spain which is a famous festival. Along these tests, we reproduce the worse cases that may affect the building, using harquebusiers shots, fireworks, and cannons shots. Results show that the house placed near to the beach does not suffer important vibroacoustic impacts. However, the old building placed in the alley is very affected.

Morphology and composition of pyrotechnic residues formed at different levels of confinement

NARCIS (Netherlands)

Vermeij, E.; Duvalois, W.; Webb, R.; Koeberg, M.

2009-01-01

Post explosion residues (PER) are residues from pyrotechnic compositions or explosives that are generated during an explosion. In the recent past SEM/EDX was used several times to analyze PER from pyrotechnic compositions. The results from these studies suggest that there might be a difference in

Qualification of Magnesium/Teflon/Viton Pyrotechnic Composition Used in Rocket Motors Ignition System

Directory of Open Access Journals (Sweden)

Luciana de Barros

2016-04-01

Full Text Available The application of fluoropolymers in high-energy-release pyrotechnic compositions is common in the space and defense areas. Pyrotechnic compositions of magnesium/Teflon/Viton are widely used in military flares and pyrogen igniters for igniting the solid propellant of a rocket motor. Pyrotechnic components are considered high-risk products as they may cause catastrophic accidents if initiated or ignited inadvertently. To reduce the hazards involved in the handling, storage and transportation of these devices, the magnesium/Teflon/Viton composition was subjected to various sensitivity tests, DSC and had its stability and compatibility tested with other materials. This composition obtained satisfactory results in all the tests, which qualifies it as safe for production, handling, use, storage and transportation.

Standard guide for pyrophoricity/combustibility testing in support of pyrophoricity analyses of metallic uranium spent nuclear fuel

CERN Document Server

American Society for Testing and Materials. Philadelphia

2007-01-01

1.1 This guide covers testing protocols for testing the pyrophoricity/combustibility characteristics of metallic uranium-based spent nuclear fuel (SNF). The testing will provide basic data for input into more detailed computer codes or analyses of thermal, chemical, and mechanical SNF responses. These analyses would support the engineered barrier system (EBS) design bases and safety assessment of extended interim storage facilities and final disposal in a geologic repository. The testing also could provide data related to licensing requirements for the design and operation of a monitored retrievable storage facility (MRS) or independent spent fuel storage installation (ISFSI). 1.2 This guide describes testing of metallic uranium and metallic uranium-based SNF in support of transportation (in accordance with the requirements of 10CFR71), interim storage (in accordance with the requirements of 10CFR72), and geologic repository disposal (in accordance with the requirements of 10CFR60/63). The testing described ...

76 FR 37876 - Hours of Service (HOS) of Drivers; Renewal of American Pyrotechnics Association (APA) Exemption...

Science.gov (United States)

2011-06-28

...-28043] Hours of Service (HOS) of Drivers; Renewal of American Pyrotechnics Association (APA) Exemption... announces the renewal of the exemption of specified members of the American Pyrotechnics Association (APA... of this exemption in effect, designated APA-member motor carriers will maintain a level of safety...

76 FR 30232 - Hours of Service (HOS) of Drivers; Application of American Pyrotechnics Association (APA) for...

Science.gov (United States)

2011-05-24

...-28043] Hours of Service (HOS) of Drivers; Application of American Pyrotechnics Association (APA) for... American Pyrotechnics Association (APA) has applied for a limited exemption from FMCSA's regulation that... exemption would apply solely to the operation of CMVs by 9 designated APA-member motor carriers in...

77 FR 38378 - Hours of Service (HOS) of Drivers; Revision of Exemption; American Pyrotechnics Association (APA)

Science.gov (United States)

2012-06-27

...-28043] Hours of Service (HOS) of Drivers; Revision of Exemption; American Pyrotechnics Association (APA... Pyrotechnics Association (APA) that were granted an exemption from FMCSA's prohibition on driving commercial...-July 8, inclusive, in 2011 and 2012. The exemption covered renewal of 53 APA-member motor carriers and...

76 FR 37880 - Hours of Service (HOS) of Drivers; Granting of Exemption; American Pyrotechnics Association (APA)

Science.gov (United States)

2011-06-28

...-28043] Hours of Service (HOS) of Drivers; Granting of Exemption; American Pyrotechnics Association (APA... exemption from the American Pyrotechnics Association (APA) on behalf of 9 member motor carriers seeking... such exemption'' (49 U.S.C. 31315(b)(1)). The initial APA application for waiver or exemption relief...

Towards decomposition of live chemical agents by pyrotechnic mixtures

NARCIS (Netherlands)

Bouma, R.H.B.; Noort, D.

2012-01-01

The aim of this study is to contribute to improved EOD neutralisation techniques against improvised explosive devices (IEDs) containing chemical agents. The decomposition of dimethyl methylphosphonate (DMMP) when exposed to a burning aluminum/potassium nitrate pyrotechnic mixture is studied

Study of the pyrophoric characteristics of uranium-iron alloys

International Nuclear Information System (INIS)

Duplessis, X.

2000-01-01

The objective of the study is to understand the pyrophoric characteristics of uranium-iron alloys. In order to carry out this research we have elected to use uranium-iron alloy powder with granules of 200 μm and 1000 μm diameter with 4%, 10.8% and 14% iron content. The experiments were performed on small samples of few milligrams and on larger quantities of few hundred grams. The main conclusions obtained are the followings: -The reaction start at 453 K (180 deg. C) and the ignition at 543 K (270 deg. C) - The influence of the specific area seems more important than the iron concentration in the alloys - When the alloy ignites, the fire spreads quickly and the alloy rapidly consumes. (author)

Corrosion and pyrophoricity of ZPPR fuel plates: Implications for basin storage

International Nuclear Information System (INIS)

Totemeier, T.C.; Hayes, S.L.; Pahl, R.G.; Crawford, D.C.

1997-01-01

This paper presents the results of recent experimentation and analysis of the pyrophoric behavior of corroded Zero Power Physics Reactor (ZPPR) HEU fuel plates and the implications of these results for the handling, drying, and passivation of uranium metal fuels stored in water basins. The ZPPR plates were originally clad in 1980; crevice corrosion of the uranium metal in a dry storage environment has occurred due to the use of porous cladding end plugs. The extensive corrosion has resulted in bulging and, in some cases, breaching of the cladding over a 15 year storage period. Processing of the plates has been initiated to recover the highly enriched uranium metal and remove the storage vulnerability identified with the corroded plates, which have been shown to contain significant quantities of the pyrophoric compound uranium hydride (UH 3 ). Experiments were undertaken to determine effective passivation techniques for the corrosion product; analysis and modeling was performed to determine whether heat generated by rapid hydride re-oxidation could ignite the underlying metal plates. The results of the initial passivation experiment showed that simple exposure of the hydride-containing corrosion product to an Ar-3 vol.% O 2 environment was insufficient to fully passivate the hydride--flare-up of the product occurred during subsequent vigorous handling in air. A second experiment demonstrated that corrosion product was fully stable following grinding of the product to a fine powder in the Ar-3 vol.% O 2 atmosphere. Numerical modeling of a corroded plate indicated that ignition of the plate due to the heat from hydride re-oxidation was likely if hydride fractions in the corrosion product exceeded 30%

Pyrophoricity of uranium in long-term storage environments

International Nuclear Information System (INIS)

Solbrig, C.W.; Krsul, J.R.; Olsen, D.N.

1994-01-01

A corrosion cycle for uranium is postulated which can be used to assess whether a given storage situation might produce fire hazards and/or continual uranium corrosion. A significant reaction rate of uranium and moisture occurs at room temperature which produces uranium oxide and hydrogen. If the hydrogen cannot escape, it will react slowly with uranium to form uranium hydride. The hydride is pyrophoric at room temperature when exposed to air. Either the hydrogen or the hydride can produce a dangerous situation as demonstrated by two different incidents described here. Long-term corrosion will occur even if the normal precautions are taken as is demonstrated by the long-term storage of stainless steel clad uranium fuel plates. The major initiator of these problems is attributed to any moisture condensed on the metal or any brought in by the cover gas. The postulated corrosion cycle is used to suggest ways to circumvent these problems

Low hygroscopicity of ambient fresh carbonaceous aerosols from pyrotechnics smoke

Science.gov (United States)

Carrico, Christian M.; Gomez, Samantha L.; Dubey, Manvendra K.; Aiken, Allison C.

2018-04-01

Pyrotechnics (fireworks) displays are common for many cultures worldwide, with Independence Day celebrations occurring annually on July 4th as the most notable in the U.S. Given an episodic nature, fireworks aerosol properties are poorly characterized. Here we report observations of optical properties of fresh smoke emissions from Independence Day fireworks smoke sampled at Los Alamos National Laboratory, New Mexico U.S.A. on 4-5 July 2016. Aerosol optical properties were measured with a photoacoustic extinctiometer (PAX, DMT, Inc., Model 870 nm) at low RH laboratory testing with ground-level sparklers showed that pyrotechnics smoke can generate a strong hygroscopic response, however. As confirmed with chemical analysis, the chemistry of the fireworks was key to defining the hygroscopic response. Sparkler smoke was dominated by salt species such as hygroscopic potassium chloride while it lacked the black powder explosives in aerial fireworks that contribute organic and elemental carbon to its non-hygroscopic smoke.

Studies on the ageing of a magnesium-strontium nitrate pyrotechnic composition using isothermal microcalorimetry and thermal analysis techniques

International Nuclear Information System (INIS)

Tuukkanen, I.; Brown, S.D.; Charsley, E.L.; Goodall, S.J.; Rooney, J.J.; Griffiths, T.T.; Lemmetyinen, H.

2004-01-01

The ageing behaviour of a pyrotechnic composition containing equal parts by mass of magnesium and strontium nitrate has been followed by isothermal microcalorimetry. The measurements were carried out on the samples at 50 deg. C and 65% relative humidity in air using closed ampoules. The results have been compared to those obtained for magnesium powder under the same conditions. Following an initial induction period, the pyrotechnic compositions reacted at a much faster rate than magnesium powder alone. The main reaction products were found to be magnesium hydroxide and strontium nitrite; the amounts formed have been correlated with the cumulative heats of ageing. In addition, the influence of the ageing process on the pyrotechnic reaction has been studied by high temperature differential scanning calorimetry (DSC) and by modulated temperature DSC

Combustion of powdery tungsten in pyrotechnic mixtures

International Nuclear Information System (INIS)

Ivanov, G.V.; Reshetov, A.A.; Viktorenko, A.M.; Surkov, V.G.; Karmadonov, L.N.

1982-01-01

The basic regularities of tungsten burning (powder 2-5 μm) with oxidizers most typical for pyrotechnics: nitrates, lead and barium peroxides (powder, 2-8 μm) and potassium perchlorate (powder, 2-8 μm) are studied. Dependences of burning rate as a function of pressure and ratio of components are established. It is supposed that tungsten burning in mixtures with the mentioned nitrates is a complex and multistage process the rate of which is determined by tungsten dissolution in nitrate melts. Analysis of burning products using available methods is complex

Laser-generated shock wave attenuation aimed at microscale pyrotechnic device design

Directory of Open Access Journals (Sweden)

Hyeonju Yu

2016-05-01

Full Text Available To meet the rising demand for miniaturizing the pyrotechnic device that consists of donor/acceptor pair separated by a bulkhead or a thin gap, the shock initiation sensitivity in the microscale gap test configuration is investigated. For understanding the shock attenuation within a gap sample (304 stainless steel thickness of 10∼800 μm, the laser-generated shock wave in water confinement is adopted. The shock properties are obtained from the free surface velocity by making use of a velocity interferometer system for any reflector (VISAR. Analytical models for plasma generation in a confined geometry and for evolution and decay of shock waves during the propagation are considered. The shape and amplitude of the laser-driven initial pressure load and its attenuation pattern in the gap are effectively controlled for targeting the microscale propagation distance and subsequent triggering pressure for the acceptor charge. The reported results are important in the precise controlling of the shock strength during the laser initiation of microscale pyrotechnic devices.

Pyrotechnical production of labelled aerosols and their use in the ground atmosphere

International Nuclear Information System (INIS)

Kuehn, W.K.G.; Alps, W.

1977-01-01

As the emission of radioactive substances in the atmosphere is only allowed for a few short-lined radionuclides, the possibility of producing aerosols pyrotechnically and to simultaneously label them with easily activated tracers was investigated. It has the following advantages: 1) The activation analysis guarantees a high detection sensitivity with a tracer element of large cross section. 2) There is no danger to the environment due to radioactivity during testing. 3) In general, there are no limits to the amount of indicator substance used. 4) The pyrotechnically produced aerosol can be used at any position of the atmosphere whereby line sources, point sources and pulse sources can be produced with the generator. The generator can be shot by a signal pistol to the desired height in order to label harmful substances or other (emission) points as well. 5) The source is extremely mobile due to the small measurements and uncomplicated construction of the generator. (orig./RW) [de

A survey of combustible metals, thermites, and intermetallics for pyrotechnic applications

Energy Technology Data Exchange (ETDEWEB)

Fischer, S.H.; Grubelich, M.C.

1996-08-01

Thermite mixtures, intermetallic reactants, and metal fuels have long been used in pyrotechnics. Advantages include high energy density, impact insensitivity, high combustion temperature, and a wide range of gas production. They generally exhibit high temperature stability and possess insensitive ignition properties. This paper reviews the applications, benefits, and characteristics of thermite mixtures, intermetallic reactants, and metal fuels. 50 refs, tables.

Design of facilities for processing pyrophoric radioactive material

International Nuclear Information System (INIS)

Bristow, H.A.S.; Hunter, S.D.

1976-01-01

The safe processing of large quantities of plutonium-bearing material poses difficult problems the solution of which sometimes involves conflicting requirements. The difficulties are increased when plutonium of a high burnup is used and the position becomes considerably more complicated when the chemical nature of the material being handled is such that it is pyrophoric. This paper describes the design principles and methods used to establish a facility capable of manufacturing large quantities of mixed plutonium/uranium carbide. The facility which included process stages such as milling, granulation, pellet pressing, furnacing and pin filling, was largely a conversion of an existing processing line. The paper treats the major plant hazards individually and indicates the methods used to counter them, outlining the main design principles employed and describing their application to selected items of equipment. Examples of the problems encountered with typical items of equipment are discussed. Some guide-lines are listed which should be of general value to designers and developers working on equipment for processing plutonium-bearing solids. The methods described have been successfully employed to provide a plant for the manufacture of mixed plutonium/uranium carbide on a scale of many hundreds of kilograms with no serious incident.(author)

Illicit utilization of arsenic compounds in pyrotechnics? An analysis of the suspended particle emission during Vienna’s New Year fireworks

International Nuclear Information System (INIS)

Sterba, J.H.; Georg Steinhauser; Fritz Grass

2013-01-01

In the course of an investigation of an electrostatic precipitation technique as a sampling method for airborne dust particles, elevated concentrations of As were found in the data collected during New Years Eve celebrations in Vienna. The original study confirmed the applicability of the new sampling device as a useful sampling method, showing elevated values for the elements Na, Mg, Al, Si, S, K, Cu, As, Br, Rb, Sr, Sb, Te and Ba, all associated with the use of pyrotechnics. The measured values for As could not be explained as a impurity in some other substances used. Thus, several unburned pyrotechnic products were investigated to find the source of As in the dust collected. The results showed only one product with higher than expected As contents (1.4 μg g -1 ), leading to the assumption of intentional - but illicit - use of arsenic compounds in pyrotechnics as a colouring agent for the production of blue light. (author)

The water gas shift reaction for automotive applications: preparation and testing of non pyrophoric copper catalysts

Energy Technology Data Exchange (ETDEWEB)

Quiney, A.S.; Germani, G.; Schuurman, Y.; Mirodatos, C. [Institut de Recherches sur la Catalyse - CNRS, 69 - Villeurbanne (France); Masset, A.S.F. [PSA Peugeot Citroen, 78 - Velizy Villacoublay (France)

2003-09-01

The aim of this study are: 1)to compare the performance of a non-pyrophoric catalyst (CuO/CeO{sub 2}/Al{sub 2}O{sub 3}) to that of a commercial copper catalyst (CuO/ZnO/Al{sub 2}O{sub 3}). 2)to develop a kinetic expression that fits the experimental data in order to design a WGS reactor. The comparison between the two catalysts shows that the latter (CuO/CeO{sub 2}/Al{sub 2}O{sub 3}) needs to be run at temperatures about 100 degrees Celsius higher. (O.M.)

Characterization of uranium corrosion products involved in the March 13, 1998 fuel manufacturing facility pyrophoric event

International Nuclear Information System (INIS)

Totemeier, T.C.

1999-01-01

Uranium metal corrosion products from ZPPR fuel plates involved in the March 13, 1998 pyrophoric event in the Fuel Manufacturing Facility at Argonne National Laboratory-West were characterized using thermo-gravimetric analysis, X-ray diffraction, and BET gas sorption techniques. Characterization was performed on corrosion products in several different conditions: immediately after separation from the source metal, after low-temperature passivation, after passivation and extended vault storage, and after burning in the pyrophoric event. The ignition temperatures and hydride fractions of the corrosion product were strongly dependent on corrosion extent. Corrosion products from plates with corrosion extents less than 0.7% did not ignite in TGA testing, while products from plates with corrosion extents greater than 1.2% consistently ignited. Corrosion extent is defined as mass of corrosion products divided by the total mass of uranium. The hydride fraction increased with corrosion extent. There was little change in corrosion product properties after low-temperature passivation or vault storage. The burned products were not reactive and contained no hydride; the principal constituents were UO 2 and U 3 O 7 . The source of the event was a considerable quantity of reactive hydride present in the corrosion products. No specific ignition mechanism could be conclusively identified. The most likely initiator was a static discharge in the corrosion product from the 14th can as it was poured into the consolidation can. The available evidence does not support scenarios in which the powder in the consolidation can slowly self-heated to the ignition point, or in which the powder in the 14th can was improperly passivated

Characterization of uranium corrosion products involved in the March 13, 1998 fuel manufacturing facility pyrophoric event.

Energy Technology Data Exchange (ETDEWEB)

Totemeier, T.C.

1999-04-26

Uranium metal corrosion products from ZPPR fuel plates involved in the March 13, 1998 pyrophoric event in the Fuel Manufacturing Facility at Argonne National Laboratory-West were characterized using thermo-gravimetric analysis, X-ray diffraction, and BET gas sorption techniques. Characterization was performed on corrosion products in several different conditions: immediately after separation from the source metal, after low-temperature passivation, after passivation and extended vault storage, and after burning in the pyrophoric event. The ignition temperatures and hydride fractions of the corrosion product were strongly dependent on corrosion extent. Corrosion products from plates with corrosion extents less than 0.7% did not ignite in TGA testing, while products from plates with corrosion extents greater than 1.2% consistently ignited. Corrosion extent is defined as mass of corrosion products divided by the total mass of uranium. The hydride fraction increased with corrosion extent. There was little change in corrosion product properties after low-temperature passivation or vault storage. The burned products were not reactive and contained no hydride; the principal constituents were UO{sub 2} and U{sub 3}O{sub 7}. The source of the event was a considerable quantity of reactive hydride present in the corrosion products. No specific ignition mechanism could be conclusively identified. The most likely initiator was a static discharge in the corrosion product from the 14th can as it was poured into the consolidation can. The available evidence does not support scenarios in which the powder in the consolidation can slowly self-heated to the ignition point, or in which the powder in the 14th can was improperly passivated.

Ignition and combustion of pyrotechnics at low pressures and at temperature extremes

Directory of Open Access Journals (Sweden)

Clive Woodley

2017-06-01

Full Text Available Rapid and effective ignition of pyrotechnic countermeasure decoy flares is vitally important to the safety of expensive military platforms such as aircraft. QinetiQ is conducting experimental and theoretical research into pyrotechnic countermeasure decoy flares. A key part of this work is the development and application of improved models to increase the understanding of the ignition processes occurring for these flares. These models have been implemented in a two-dimensional computational model and details are described in this paper. Previous work has conducted experiments and validated the computational model at ambient temperature and pressure. More recently the computational model has been validated at pressures down to that equivalent to 40,000 feet but at ambient temperature (∼290 K. This paper describes further experimental work in which the ignition delays of the priming material in inert countermeasure decoy flares were determined for pressures down to 40,000 feet and at temperature extremes of −40 °C and 100 °C. Also included in this paper is a comparison of the measured and predicted ignition delays at low pressures and temperature extremes. The agreement between the predicted and measured ignition delays is acceptable.

Behaviour modelling of two aluminas in divergent spherical pyrotechnical experiments

International Nuclear Information System (INIS)

Malaise, F.; Tranchet, J.Y.; Collombet, F.

1997-01-01

Two pure aluminas of different characteristics have been subjected to the propagation of a longitudinal divergent spherical shock wave through pyrotechnical experiments. An approach combining a phenomenological analysis and numerical 1D-calculations is proposed to study the behaviour of these aluminas submitted to that type of wave loading. The modelling, proposed in a previous paper, is refined and gives satisfying experimentation-calculation correlations. An analysis of the influence exerted by the various encountered phenomena (plastic activity, pore closure, microcracking) is performed. The significant consequence of the activation of damage with an extension criterion is also underlined. (orig.)

78 FR 26690 - Hours of Service (HOS) of Drivers; Application for Renewal and Expansion of American Pyrotechnics...

Science.gov (United States)

2013-05-07

... Association (APA) Exemption From the 14-Hour Rule During Independence Day Celebrations AGENCY: Federal Motor... exemption; request for comments. SUMMARY: The American Pyrotechnics Association (APA) has requested a renewal of its exemption for 48 APA member-companies from FMCSA's regulation that drivers of commercial...

Stochastic shock response spectrum decomposition method based on probabilistic definitions of temporal peak acceleration, spectral energy, and phase lag distributions of mechanical impact pyrotechnic shock test data

Science.gov (United States)

Hwang, James Ho-Jin; Duran, Adam

2016-08-01

Most of the times pyrotechnic shock design and test requirements for space systems are provided in Shock Response Spectrum (SRS) without the input time history. Since the SRS does not describe the input or the environment, a decomposition method is used to obtain the source time history. The main objective of this paper is to develop a decomposition method producing input time histories that can satisfy the SRS requirement based on the pyrotechnic shock test data measured from a mechanical impact test apparatus. At the heart of this decomposition method is the statistical representation of the pyrotechnic shock test data measured from the MIT Lincoln Laboratory (LL) designed Universal Pyrotechnic Shock Simulator (UPSS). Each pyrotechnic shock test data measured at the interface of a test unit has been analyzed to produce the temporal peak acceleration, Root Mean Square (RMS) acceleration, and the phase lag at each band center frequency. Maximum SRS of each filtered time history has been calculated to produce a relationship between the input and the response. Two new definitions are proposed as a result. The Peak Ratio (PR) is defined as the ratio between the maximum SRS and the temporal peak acceleration at each band center frequency. The ratio between the maximum SRS and the RMS acceleration is defined as the Energy Ratio (ER) at each band center frequency. Phase lag is estimated based on the time delay between the temporal peak acceleration at each band center frequency and the peak acceleration at the lowest band center frequency. This stochastic process has been applied to more than one hundred pyrotechnic shock test data to produce probabilistic definitions of the PR, ER, and the phase lag. The SRS is decomposed at each band center frequency using damped sinusoids with the PR and the decays obtained by matching the ER of the damped sinusoids to the ER of the test data. The final step in this stochastic SRS decomposition process is the Monte Carlo (MC

Technical investigation of a pyrophoric event involving corrosion products from HEU ZPPR fuel plates

International Nuclear Information System (INIS)

Totemeier, T. C.

2000-01-01

A pyrophoric event recently occurred which involved corrosion products collected from highly-enriched uranium (HEU) fuel plates used in the Zero Power Physics Reactor (ZPPR). This paper summarizes the event and its background, and presents the results of an investigation into its source and mechanism. The investigation focused on characterization of corrosion product samples similar to those involved in the event using thermo-gravimetric analysis (TGA). Burning curve TGA tests were performed to measure the ignition temperature and hydride fractions of corrosion products in several different conditions to assess the effects of passivation treatment and long-term storage on chemical reactivity. The hydride fraction and ignition temperature of the corrosion products were found to be strongly dependent on the corrosion extent of the source metal. The results indicate that the energy source for the event was a considerable quantity of uranium hydride present in the corrosion products, but the specific ignition mechanism could not be identified

Study of the pyrophoric characteristics of uranium-iron alloys; Etude du caractere pyrophorique des alliages uranium fer

Energy Technology Data Exchange (ETDEWEB)

Duplessis, X

2000-02-23

The objective of the study is to understand the pyrophoric characteristics of uranium-iron alloys. In order to carry out this research we have elected to use uranium-iron alloy powder with granules of 200 {mu}m and 1000 {mu}m diameter with 4%, 10.8% and 14% iron content. The experiments were performed on small samples of few milligrams and on larger quantities of few hundred grams. The main conclusions obtained are the followings: -The reaction start at 453 K (180 deg. C) and the ignition at 543 K (270 deg. C) - The influence of the specific area seems more important than the iron concentration in the alloys - When the alloy ignites, the fire spreads quickly and the alloy rapidly consumes. (author)

Optimized Analytical Method to Determine Gallic and Picric Acids in Pyrotechnic Samples by Using HPLC/UV (Reverse Phase)

International Nuclear Information System (INIS)

Garcia Alonso, S.; Perez Pastor, R. M.

2013-01-01

A study on the optimization and development of a chromatographic method for the determination of gallic and picric acids in pyrotechnic samples is presented. In order to achieve this, both analytical conditions by HPLC with diode detection and extraction step of a selected sample were studied. (Author)

The development of laser ignited deflagration-to-detonation transition (DDT) detonators and pyrotechnic actuators

Energy Technology Data Exchange (ETDEWEB)

Merson, J.A.; Salas, F.J.; Harlan, J.G.

1993-11-01

The use of laser ignited explosive components has been recognized as a safety enhancement over existing electrical explosive devices (EEDs). Sandia has been pursuing the development of optical ordnance for many years with recent emphasis on developing optical deflagration-to-detonation (DDT) detonators and pyrotechnic actuators. These low energy optical ordnance devices can be ignited with either a semiconductor diode laser, laser diode arrays or a solid state rod laser. By using a semiconductor laser diode, the safety improvement can be made without sacrificing performance since the input energy required for the laser diode and the explosive output are similar to existing electrical systems. The use of higher powered laser diode arrays or rod lasers may have advantages in fast DDT applications or lossy optical environments such as long fiber applications and applications with numerous optical connectors. Recent results from our continued study of optical ignition of explosive and pyrotechnic materials are presented. These areas of investigation can be separated into three different margin categories: (1) the margin relative to intended inputs (i.e. powder performance as a function of laser input variation), (2) the margin relative to anticipated environments (i.e. powder performance as a function of thermal environment variation), and (3) the margin relative to unintended environments (i.e. responses to abnormal environments or safety).

Investigation of the thermal decomposition of magnesium–sodium nitrate pyrotechnic composition (SR-524 and the effect of accelerated aging

Directory of Open Access Journals (Sweden)

Zaheer-ud-din Babar

2017-03-01

Full Text Available The aging behavior of the pyrotechnics is influenced by the storage atmosphere and more specifically on the temperature and humidity levels. The investigated composition SR 524 is a military pyrotechnic composition that is used as a tracer. The accelerated aging of the SR 524 composition has been carried out at a temperature of 70 °C and relative humidity of 70 percent. The results indicate that there is significant change in the thermal behavior, kinetic parameters and the morphology of the aged composition. The decomposition temperature and the activation energy were found to be lowered in the aged composition. The activation energy of the aged composition decreased nearly 57 percent. SEM micrographs of the aged composition revealed the development of micro cracks as a result of accelerated aging. XRD spectra of the aged composition showed the presence of magnesium hydroxide indicating the reaction between magnesium and water vapors present in the highly humid atmosphere.

Using the Chemistry of Fireworks to Engage Students in Learning Basic Chemical Principles: A Lesson in Eco-Friendly Pyrotechnics

Science.gov (United States)

Steinhauser, Georg; Klapotke, Thomas M.

2010-01-01

Fascination with fireworks and pyrotechnics can be used for educational purposes. Several aspects of pyrochemistry such as redox reactions, flame colors, or the theory of combustion can be incorporated in the curriculum to illustrate some basic chemical principles, guaranteeing a lesson that will be engaging and memorable. Beyond classic…

Implications of Dynamic Pressure Transducer Mounting Variations on Measurements in Pyrotechnic Test Apparatus

Science.gov (United States)

Dibbern, Andreas; Crisafulli, Jeffrey; Hagopia, Michael; McDougle, Stephen H.; Saulsberry, Regor L.

2009-01-01

Accurate dynamic pressure measurements are often difficult to make within small pyrotechnic devices, and transducer mounting difficulties can cause data anomalies that lead to erroneous conclusions. Delayed initial pressure response followed by data ringing has been observed when using miniaturized pressure transducer mounting adapters required to interface transducers to small test chambers. This delayed pressure response and ringing, combined with a high data acquisition rate, has complicated data analysis. This paper compares the output signal characteristics from different pressure transducer mounting options, where the passage distance from the transducer face to the pyrotechnic chamber is varied in length and diameter. By analyzing the data and understating the associated system dynamics, a more realistic understanding of the actual dynamic pressure variations is achieved. Three pressure transducer mounting configurations (elongated, standard, and face/flush mount) were simultaneously tested using NASA standard initiators in closed volume pressure bombs. This paper also presents results of these pressure transducer mounting configurations as a result of a larger NASA Engineering and Safety Center pyrovalve test project. Results from these tests indicate the improved performance of using face/flush mounted pressure transducers in this application. This type of mounting improved initial pressure measurement response time by approximately 19 s over standard adapter mounting, eliminating most of the lag time; provided a near step-function type initial pressure increase; and greatly reduced data ringing in high data acquisition rate systems. The paper goes on to discuss other issues associated with the firing and instrumentation that are important for the tester to understand.

Supercritical water oxidation of colored smoke, dye, and pyrotechnic compositions. Final report: Pilot plant conceptual design

Energy Technology Data Exchange (ETDEWEB)

LaJeunesse, C.A.; Chan, Jennifer P.; Raber, T.N.; Macmillan, D.C.; Rice, S.F.; Tschritter, K.L.

1993-11-01

The existing demilitarization stockpile contains large quantities of colored smoke, spotting dye, and pyrotechnic munitions. For many years, these munitions have been stored in magazines at locations within the continental United States awaiting completion of the life-cycle. The open air burning of these munitions has been shown to produce toxic gases that are detrimental to human health and harmful to the environment. Prior efforts to incinerate these compositions have also produced toxic emissions and have been unsuccessful. Supercritical water oxidation (SCWO) is a rapidly developing hazardous waste treatment method that can be an alternative to incineration for many types of wastes. The primary advantage SCWO affords for the treatment of this selected set of obsolete munitions is that toxic gas and particulate emissions will not occur as part of the effluent stream. Sandia is currently designing a SCWO reactor for the US Army Armament Research, Development & Engineering Center (ARDEC) to destroy colored smoke, spotting dye, and pyrotechnic munitions. This report summarizes the design status of the ARDEC reactor. Process and equipment operation parameters, process flow equations or mass balances, and utility requirements for six wastes of interest are developed in this report. Two conceptual designs are also developed with all process and instrumentation detailed.

From non-disposable to disposable, treatment of pyrophoric or gas forming waste forms for disposal - Thermal treatment of pyrophoric or gas-forming metals

International Nuclear Information System (INIS)

Oesterberg, Carl; Lindberg, Maria

2014-01-01

In order to dispose of waste in either a deep geological disposal or in a shallower repository there are several demands that the waste and its package must fulfil, one is that it is not to react with oxygen or the waste package or backfill in the repository, i.e. concrete or grout. The waste forms that do not fulfil this particular criterion must be treated in some way to render the waste non-reactive. One of these waste are metallic uranium. Metallic uranium is not only an issue originating from the nuclear industry, as old types of fuel, it is also present in, for example, transport flasks and as samples used in schools, which all has to be disposed of sooner or later. Another waste that arise is magnesium doped with thorium, originating from the aviation, aerospace and missile industry. These alloys are now being replaced with others without thorium so they are in need of handling and possibly treatment before disposal. Magnesium metal is also pyrophoric, in particular in molten or powder form. In order to evaluate thermally treating these metals in a very controlled environment, such as a pyrolysis vessel, experimental work has been performed. The aim of the thermal treatment is to oxidise the metals and obtain an oxide with low leachability. Inactive trials were performed, first using small amount of magnesium tape followed by using Cerium instead of uranium, to check the ability of controlling the process. After the process had been deemed safe the next step was to test the process first with metallic uranium and thereafter with magnesium thorium alloy. The first results show that the oxidation process can be totally controlled and safe. The results show that the metals are oxidised and no longer reactive and can in principle be disposed of. The test will continue and further results will be reported. (authors)

Ignition delays, heats of combustion, and reaction rates of aluminum alkyl derivatives used as ignition and combustion enhancers for supersonic combustion

Science.gov (United States)

Ryan, Thomas W., III; Schwab, S. T.; Harlowe, W. W.

1992-01-01

The subject of this paper is the design of supersonic combustors which will be required in order to achieve the needed reaction rates in a reasonable sized combustor. A fuel additive approach, which is the focus of this research, is the use of pyrophorics to shorten the ignition delay time and to increase the energy density of the fuel. Pyrophoric organometallic compounds may also provide an ignition source and flame stabilization mechanism within the combustor, thus permitting use of hydrocarbon fuels in supersonic combustion systems. Triethylaluminum (TEA) and trimethylaluminum (TMA) were suggested for this application due to their high energy density and reactivity. The objective here is to provide comparative data for the ignition quality, the energy content, and the reaction rates of several different adducts of both TEA and TMA. The results of the experiments indicate the aluminum alkyls and their more stable derivatives reduce the ignition delay and total reaction time to JP-10 jet fuel. Furthermore, the temperature dependence of ignition delay and total reaction time of the blends of the adducts are significantly lower than in neat JP-10.

High-Nitrogen-Based Pyrotechnics: Longer- and Brighter-Burning, Perchlorate-Free, Red-Light Illuminants for Military and Civilian Applications

Science.gov (United States)

2011-01-01

combustion of these materials. To address the aforementioned perchlorate issues, an effort was initiated by ARDEC to remove potassium per- chlorate ...with acceptable burn times for pyrotechnic applications by using potassium nitrate– amorphous boron–crystalline boron/boron carbide–epoxy binder mixtures...3,4] Moreover, it was discovered by ARDEC that a potassium nitrate–boron carbide–epoxy binder mix- ture alone was able to generate suitable green

The Theoretical Basis of the Concept of Using the Controlled Pyrotechnical Reaction Method as an Energy Source in Transportation from the Sea Bed

Directory of Open Access Journals (Sweden)

Wiktor Filipek

2017-12-01

Full Text Available In recent years we have observed the global growing interest in undersea exploitation of mineral deposits. Research on various concepts of operating systems on the seabed has been conducted, where different methods of transporting excavated material from the bottom to the surface are used. Great depths, where there are the most interesting resources (eg. IOM lot for the Clarion-Clipperton 4500 m set very high technical and technological demands which results in intensive search for solutions. The authors of the paper want to explain the concept of the use of pyrotechnic materials for transportation in the aquatic environment. The presented method is designed for the cyclic transport from great depths (less than 200 m from the seabed. The principle of operation of the relay unit is based on the change in the average density of the entire module which is inseparably connected with the force of buoyancy acting on the submerged body. Changing the density of the whole module to the given depth of immersion is strictly dependent on the amount of energy supplied to the system by a power source in the form of a controlled pyrotechnic reaction. However, during the ascent energy demand decreases. The problem of transport of spoil from depth not only boils down to such considerations as initiation of the process of ascent. One should also consider how to use the excess energy occurring during the movement of the object toward the surface. The authors of the paper present the concept of making the transport of cyclic depths (less than 200 m from the seabed taking into account the optimal use of energy from controlled pyrotechnic reaction.

Preparation and Characterization of Pyrotechnics Binder-Coated Nano-Aluminum Composite Particles

Science.gov (United States)

Ye, Mingquan; Zhang, Shuting; Liu, Songsong; Han, Aijun; Chen, Xin

2017-07-01

The aim of this article is to protect the activity of nano-aluminum (Al) particles in solid rocket propellants and pyrotechnics. The morphology, structure, active aluminum content, and thermal and catalytic properties of the coated samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), thermogravimetry-differential scanning calorimetry (TG-DSC), and oxidation-reduction titration methods. The results indicated that nano-Al particles could be effectively coated with phenolic resin (PF), fluororubber (Viton B), and shellac through a solvent/nonsolvent method. The energetic composite particles have core-shell structures and the thickness of the coating film is about 5-15 nm. Analysis of the active Al content revealed that Viton B coating had a much better protective effect. The TG-DSC results showed that the energy amount and energy release rate of PF-, Viton B-, and shellac-coated Al particles were larger than those of the raw nano-Al particles. The catalytic effects of coated Al particles on the thermal decomposition of ammonium perchlorate (AP) were better than those of raw nano-Al particles, and the effect of shellac-coated Al particles was significantly better than that of Viton B-coated Al particles.

Influence of interface conditions on laser diode ignition of pyrotechnic mixtures: application to the design of an ignition device

Energy Technology Data Exchange (ETDEWEB)

Opdebeck, Frederic; Gillard, Philippe [Laboratoire Energetique Explosions et Structures de l' Universite d' Orleans, 63 boulevard de Lattre de Tassigny, 18020 cedex, Bourges (France); Radenac, D' Erwann [Laboratoire de combustion et de detonique, ENSMA, BP 109, 86960 cedex, Futuroscope (France)

2003-01-01

This paper treats of numerical modelling which simulates the laser ignition of pyrotechnic mixtures. The computation zone is divided into two fields. The first is used to take account of the heat loss with the outside. It can represent an optical fibre or a sapphire protective porthole. The second field represents the reactive tablet which absorbs the laser diode's beam. A specific feature of the model is that it incorporates a thermal contact resistance R{sub c} between the two computation fields. Through knowledge of the thermal, optical and kinetic properties, this code makes it possible to compute the ignition conditions. The latter are defined by the energy E{sub 50} and the time t{sub i} of ignition of any pyrotechnic mixture and for various ignition systems.This work was validated in the case of an ignition system consisting of a laser diode with an optical lens re-focussing system. The reactive tablet contains 62% by mass of iron and 38% by mass of KClO{sub 4}. Its porosity is 25.8%. After an evaluation of the laser's coefficient of absorption, the variations of the ignition parameters E{sub 50} and t{sub i} are studied as a function of the thermal contact resistance R{sub c}. Temperature profiles are obtained as a function of time and for various values of the thermal contact resistance R{sub c}. More fundamental observations are made concerning the position of the hot spot corresponding to priming. From this study, which concerns the heat exchange between the two media, several practical conclusions are given concerning the design of an ignition device. By evaluation of the thermal contact resistance R{sub c}, comparison with test results becomes possible and the results of the computations are in reasonable agreement with the test measurements. (authors)

Metal hydride and pyrophoric fuel additives for dicyclopentadiene based hybrid propellants

Science.gov (United States)

Shark, Steven C.

The purpose of this study is to investigate the use of reactive energetic fuel additives that have the potential to increase the combustion performance of hybrid rocket propellants in terms of solid fuel regression rate and combustion efficiency. Additives that can augment the combustion flame zone in a hybrid rocket motor by means of increased energy feedback to the fuel grain surface are of great interest. Metal hydrides have large volumetric hydrogen densities, which gives these materials high performance potential as fuel additives in terms of specifc impulse. The excess hydrogen and corresponding base metal may also cause an increase in the hybrid rocket solid fuel regression rate. Pyrophoric additives also have potential to increase the solid fuel regression rate by reacting more readily near the burning fuel surface providing rapid energy feedback. An experimental performance evaluation of metal hydride fuel additives for hybrid rocket motor propulsion systems is examined in this study. Hypergolic ignition droplet tests and an accelerated aging study revealed the protection capabilities of Dicyclopentadiene (DCPD) as a fuel binder, and the ability for unaided ignition. Static hybrid rocket motor experiments were conducted using DCPD as the fuel. Sodium borohydride (NabH4) and aluminum hydride (AlH3) were examined as fuel additives. Ninety percent rocket grade hydrogen peroxide (RGHP) was used as the oxidizer. In this study, the sensitivity of solid fuel regression rate and characteristic velocity (C*) efficiency to total fuel grain port mass flux and particle loading is examined. These results were compared to HTPB combustion performance as a baseline. Chamber pressure histories revealed steady motor operation in most tests, with reduced ignition delays when using NabH4 as a fuel additive. The addition of NabH4 and AlH3 produced up to a 47% and 85% increase in regression rate over neat DCPD, respectively. For all test conditions examined C* efficiency ranges

Mass flow discharge and total temperature characterisation of a pyrotechnic gas generator formulation for airbag systems

Energy Technology Data Exchange (ETDEWEB)

Neutz, Jochen; Koenig, Andreas [Fraunhofer Institut fuer Chemische Technologie ICT, Pfinztal (Germany); Knauss, Helmut; Jordan, Sebastian; Roediger, Tim; Smorodsky, Boris [Universitaet Stuttgart (Germany). Institut fuer Aerodynamik und Gasdynamik; Bluemcke, Erich Walter [AUDI AG, Department I/EK-523, Ingolstadt (Germany)

2009-06-15

The mass flow characteristics of gas generators for airbag applications have to comply with a number of requirements for an optimal deployment of the airbag itself. Up to now, the mass flow was determined from pressure time histories of so-called can tests. This procedure suffers from the missing knowledge on the temperature of the generated gas entering the can. A new test setup described in this paper could overcome this problem by providing highly time resolved information on the gas's total temperature and the mass flow of the generator. The test setup consisted of a combustion chamber with a specially designed Laval nozzle in combination with a temperature sensor of high time resolution. The results showed a high time resolved temperature signal, which was disturbed by the formation of a slag layer on the sensor. Plausibility considerations with experimentally and thermodynamically determined combustion temperatures led to satisfying results for the overall temperature as characteristic parameter of airbag inflating gases flows from pyrotechnics. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

Optimized Analytical Method to Determine Gallic and Picric Acids in Pyrotechnic Samples by Using HPLC/UV (Reverse Phase); Optimizacion del Metodo Analitico mediante HPLC/UV Operando en Fase Inversa para la Determinacion de Acido Galico y Acido Picrico en Muestras de Origen Pirotecnico

Energy Technology Data Exchange (ETDEWEB)

Garcia Alonso, S.; Perez Pastor, R. M.

2013-10-01

A study on the optimization and development of a chromatographic method for the determination of gallic and picric acids in pyrotechnic samples is presented. In order to achieve this, both analytical conditions by HPLC with diode detection and extraction step of a selected sample were studied. (Author)

Understanding pyrotechnic shock dynamics and response attenuation over distance

Science.gov (United States)

Ott, Richard J.

Pyrotechnic shock events used during stage separation on rocket vehicles produce high amplitude short duration structural response that can lead to malfunction or degradation of electronic components, cracks and fractures in brittle materials, local plastic deformation, and can cause materials to experience accelerated fatigue life. These transient loads propagate as waves through the structural media losing energy as they travel outward from the source. This work assessed available test data in an effort to better understand attenuation characteristics associated with wave propagation and attempted to update a historical standard defined by the Martin Marietta Corporation in the late 1960's using out of date data acquisition systems. Two data sets were available for consideration. The first data set came from a test that used a flight like cylinder used in NASA's Ares I-X program, and the second from a test conducted with a flat plate. Both data sets suggested that the historical standard was not a conservative estimate of shock attenuation with distance, however, the variation in the test data did not lend to recommending an update to the standard. Beyond considering attenuation with distance an effort was made to model the flat plate configuration using finite element analysis. The available flat plate data consisted of three groups of tests, each with a unique charge density linear shape charge (LSC) used to cut an aluminum plate. The model was tuned to a representative test using the lowest charge density LSC as input. The correlated model was then used to predict the other two cases by linearly scaling the input load based on the relative difference in charge density. The resulting model predictions were then compared with available empirical data. Aside from differences in amplitude due to nonlinearities associated with scaling the charge density of the LSC, the model predictions matched the available test data reasonably well. Finally, modeling best

Environmental biotechnology and microbiology of (per)chlorate reducing bacteria

NARCIS (Netherlands)

Mehboob, F.; Schraa, G.; Stams, A.J.M.

2011-01-01

Perchlorates are the salts derived from perchloric acid (HClO4). They occur both naturally and through manufacturing. They have been used as a medicine for more than 50 years to treat thyroid gland disorders and are used extensively within the pyrotechnics industry, and ammonium perchlorate is also

Fire Safety Consideration in the Pre-conceptual Design State of Pyro-Facillity

Energy Technology Data Exchange (ETDEWEB)

Jeon, Hong Rae; Seo, Seok Jun; Lee, Hyo Jik [KAERI, Daejeon (Korea, Republic of)

2016-05-15

The government, in order to solve this problem, has organized a public engagement committee and is searching for a solution. To use sustainable nuclear energy, our country is also pursuing research and development of fast breeder reactor and pyroprocessing technology in accordance with the international movement of spent fuel recycling and efforts towards nuclear non-proliferation which is centered on the development and demonstration of recycling spent fuel and fast breeder reactors. Pyro-facility has different features with nuclear power plant. In the pyroprocess, chemical and electrochemical separation were took place in the hot cells and material at risk (MAR) is distributed in many working areas. In this paper, we conducted the fire modeling of hot cells to see the stability of pyrophoric materials which is considered as one of the potential hazardous materials in the main process cell. Based on modeling results, consideration of fire safety pyrofacility will be discussed. We performed preliminary hazard analysis for pyrofacility and summarized potential fire hazard. Pyrophoric material fire is the dominant hazard in the main process hot cell and fire modeling of cable tray in the cell was analyzed to see the stability of pyrophoric materials. Analysis results clearly shows that pyrophoric materials are prone to be affected.

Analysis of Hazards Associated with a Process Involving Uranium Metal and Uranium Hydride Powders

Energy Technology Data Exchange (ETDEWEB)

Bullock, J.S.

2000-05-01

An analysis of the reaction chemistry and operational factors associated with processing uranium and uranium hydride powders is presented, focusing on a specific operation in the Development Division which was subjected to the Job Hazard Analysis (JHA) process. Primary emphasis is on the thermodynamic factors leading to pyrophoricity in common atmospheres. The discussion covers feed powders, cold-pressed and hot-pressed materials, and stray material resulting from the operations. The sensitivity of the various forms of material to pyrophoricity in common atmospheres is discussed. Operational recommendations for performing the work described are given.

Thermogravimetric experiments with titanium

International Nuclear Information System (INIS)

Porter, L.J.; Longhurst, G.R.

1991-02-01

In the process of preparing for pyrophoricity experiments involving uranium, we conducted hydriding and air-exposure experiments on titanium. In these experiments the hydriding reactions and response to air-exposure was generally within the range expected based on work reported by others. One aberrant behavior was a sudden weight gain followed by a significant weight loss. We speculate that loss may be due to hydrogen evolution from the TiH 2 resulting from local heating by oxidation reactions. We verified that titanium is not pyrophoric at temperatures less than 750 degree C. 18 refs. 1 fig

Methodological approach for the assessment of acute inhalation toxicity of smoke ammunitions by in silico, in vitro and in vivo modelling

NARCIS (Netherlands)

Pradines, E.; Glacial, F.; Medus, D.; Stiee, E.; Fedou, F.; Hulst, M. van; Klerk, W.P.C. de

2015-01-01

Assessing the toxicity of military pyrotechnic products is a growing challenge in the current context of Human and Environment protection. The Allied Ordnance Publication (AOP) 45 and the Standard NATO Agreement (STANAG) 4588 “Guidelines for toxicity testing of smokes, obscurants and pyrotechnics

46 CFR 160.066-12 - Operational tests.

Science.gov (United States)

2010-10-01

... provided by a sealed plastic bag or other waterproof packaging, submersion under 25 mm (1 in.) of water for... operating instructions. The following data as observed must be recorded for each signal: (1) Burning time of the pyrotechnic candle; (2) Color; (3) Whether the pyrotechnic candle burns out above, at, or below...

40 CFR 262.102 - What special definitions are included in this subpart?

Science.gov (United States)

2010-07-01

... Management Plan (EMP) means a written program developed and implemented by the university which sets forth..., explosive, flammable, an organic peroxide, an oxidizer, pyrophoric, unstable (reactive) or water-reactive. A...

PERSPECTIVE: Fireworks and radioactivity

Science.gov (United States)

Breitenecker, Katharina

2009-09-01

Katharina Breitenecker Fireworks, the one and only amongst all other pyrotechnic applications, have pleased the hearts and minds of billions of people all over the world for almost 1000 years. Even though pyrotechnics were originally developed in order to fulfil the needs of military purposes, fireworks began to form a unique part of the cultural heritage of many countries, presumably starting in ancient China during the Song Dynasty (960-1280 AD). Festivities like New Year's Eve, national holidays or activities like music festivals and parish fairs are crowned by a firework display. Fireworks have traditionally been associated with Independence Day celebrations, like 4 July in the United States, Guy Fawkes' Night (5 November) in Britain, or Bastille Day (14 July) in France. Much of Chinese culture is associated with the use of firecrackers to celebrate the New Year and other important occasions. The fascination of fireworks and firecrackers is due to the brilliant colours and booming noises, which have a universal appeal to our basic senses [1]. The basic components of any traditional civil firework is black powder, a mixture of about 75% potassium nitrate, 15% charcoal, and about 10% sulfur [2]. Without the addition of a colouring agent, the fuel would provide an almost white light. Therefore, several metal salts can be added to cause colourful luminescence upon combustion. In general barium is used to obtain a green coloured flame, strontium for red, copper for blue and sodium for yellow [2, 3]. The use of pyrotechnics has raised issues pertaining to health concerns. The health aspects are not only restricted to injuries by accidental ignition of certain devices. Moreover, several recent works identified fireworks and pyrotechnics as causing environmental pollution, which might result in a potential hazard concerning health aspects. The fundamental problem in this respect is that all chemicals used are dispersed in the environment by combustion. This includes

Dissolution of metallic uranium and its alloys. Part II. Screening study results: Identification of an effective non-thermal uranium dissolution method

International Nuclear Information System (INIS)

Laue, C.A.; Gates-Anderson, D.; Fitch, T.E.

2004-01-01

Screening experiments were performed to evaluate reagent systems that deactivate pyrophoric, metallic depleted uranium waste streams at ambient temperature. The results presented led to the selection of two systems, which would be investigated further, for the design of the LLNL onsite treatment process of metallic depleted uranium wastes. The two feasible systems are: (a) 7.5 mol/l H 2 SO 4 - 1 mol/l HNO 3 and (b) 3 mol/l HCl - 1 mol/l H 3 PO 4 . The sulfuric acid system dissolves uranium metal completely, while the hydrochloric-phosphoric acid system converts the metal completely into a solid, which might be suitable for direct disposal. Both systems combine oxidation of metallic uranium with complexation of the uranium ions formed to effectively deactivate uranium.s pyrophoricity at ambient temperature. (author)

Estimation of the thermal characteristics of a bridgewire environment by an electrothermal response test

International Nuclear Information System (INIS)

Donaldson, A.B.; Strasburg, A.C.

1976-01-01

The electrothermal response of an electroexplosive device is determined by applying a subcritical square wave current pulse to the bridgewire and monitoring the resultant temperature excursion. The temperature profile, thus obtained, can be utilized with a mathematical model called the ''Probe Method'' for approximating thermal properties. It is possible to estimate the thermal conductivity and specific heat of the pyrotechnic and the thermal contact conductance at the bridgewire/pyrotechnic interface by this technique

Nitride Coating Effect on Oxidation Behavior of Centrifugally Atomized U-Mo Fuel

Energy Technology Data Exchange (ETDEWEB)

Jeong, Yong Jin; Cho, Woo Hyoung; Park, Jong Man; Lee, Yoon Sang; Yang, Jae Ho [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2011-10-15

Uranium metal and uranium compounds are being used as nuclear fuel materials and generally known as pyrophoric materials. Nowadays the importance of nuclear fuel about safety is being emphasized due to the vigorous exchanges and co-operations among the international community. According to the reduced enrichment for research and test reactors (RERTR) program, the international research reactor community has decided to use low-enriched uranium instead of high-enriched uranium. As a part of the RERTR program, KAERI has developed centrifugally atomized U-Mo alloys as a promising candidate of research reactor fuel. Kang et al. studied the oxidation behavior of centrifugally atomized U-10wt% Mo alloy and it showed better oxidation resistance than uranium. In this study, the oxidation behavior of nitride coated U-7wt% Mo alloy is investigated to enhance the safety against pyrophoricity

Normally-Closed Zero-Leak Valve with Magnetostrictive Actuator

Science.gov (United States)

Ramspacher, Daniel J. (Inventor); Richard, James A. (Inventor)

2017-01-01

A non-pyrotechnic, normally-closed, zero-leak valve is a replacement for the pyrovalve used for both in-space and launch vehicle applications. The valve utilizes a magnetostrictive alloy for actuation, rather than pyrotechnic charges. The alloy, such as Terfenol-D, experiences magnetostriction, i.e. a gross elongation, when exposed to a magnetic field. This elongation fractures a parent metal seal, allowing fluid flow through the valve. The required magnetic field is generated by redundant coils that are isolated from the working fluid.

Measurements of pressure for the TiH/sub x//KClO4 system

International Nuclear Information System (INIS)

Chong, C.H.H.; Glaub, J.E.

1978-01-01

An investigation was conducted to measure the pressure obtained when the pyrotechnic mixture TiH/sub x//KClO 4 was ignited in a confined variable-volume system. It was possible to derive an expression of the form PV/sup γ/ = k for the pressure-volume relationship obtained. This expression is a polytropic expansion of the ideal gas equation that best fits the data generated. For this particular work, values of γ = 0.53 and k = 69.3 were obtained where P is in megapascals and V is in cubic centimeters. In addition, estimates of the reaction rates were calculated based on the times to achieve maximum pressure for a given volume system. An explicit expression relating rate to pressure was derived by a simplified least-squares fit of the data obtained

Structural and mechanical design challenges of space shuttle solid rocket boosters separation and recovery subsystems

Science.gov (United States)

Woodis, W. R.; Runkle, R. E.

1985-01-01

The design of the space shuttle solid rocket booster (SRB) subsystems for reuse posed some unique and challenging design considerations. The separation of the SRBs from the cluster (orbiter and external tank) at 150,000 ft when the orbiter engines are running at full thrust meant the two SRBs had to have positive separation forces pushing them away. At the same instant, the large attachments that had reacted launch loads of 7.5 million pounds thrust had to be servered. These design considerations dictated the design requirements for the pyrotechnics and separation rocket motors. The recovery and reuse of the two SRBs meant they had to be safely lowered to the ocean, remain afloat, and be owed back to shore. In general, both the pyrotechnic and recovery subsystems have met or exceeded design requirements. In twelve vehicles, there has only been one instance where the pyrotechnic system has failed to function properly.

Self-ignition of explosive substance. Comparison between analytical and numerical calculations in order to optimize safety in a pyrotechnic context; Auto-inflammation de substances explosives. Comparaison entre calcul analytique et numerique en vue d`une optimisation dans le domaine de la pyrotechnie

Energy Technology Data Exchange (ETDEWEB)

Gillard, Ph. [Centre National de la Recherche Scientifique (CNRS), 86 - Poitiers (France)

1998-04-01

Self-ignition of energetic material was investigated in order to optimize safety in the field of pyrotechnic applications. Two approaches were used; the first one is relative to Frank-Kamenetskii stationary thermal explosion theory. The second approach consists of a choice of some numerical solutions of heat conduction equations in a non-stationary state. Comparison between these results was carried out in order to find the numerical scheme which is the most compatible with Frank-Kamenetskii stationary thermal explosion theory. Numerical data were used for three explosive substances. One of them was studied by the author. In all cases, the numerical stationary state is in agreement with the Frank-Kamenetskii stationary thermal explosion theory, more or less accurately. From this comparison, it may be concluded that it is preferable, for this kind of problem, to use an implicit scheme with linearization of the heat source term. Explicit numerical methods, with or without the addition of the heat term with the Zinn and Mader scheme are revealed to be less accurate and to need a greater optimization of spatial and temporal meshing. (author) 7 refs.

Compaction of Chemically Prepared Amorphous Fe-B nanoparticles

DEFF Research Database (Denmark)

Hendriksen, P.V.; Bødker, Franz; Mørup, Steen

1997-01-01

We report on attempts to compact chemically prepared amorphous iron-boron particles. The praticles have a size of about 100 nm and are pyrophoric. We have made a special die for uniaxial pressing in which the compaction can be performed at elevated temperature without exposing the powder to air...

Rapidly Degradable Pyrotechnic System

Science.gov (United States)

2009-02-01

material system (structural polymer and degradation agent ) for producing a high strength, non-corroding, highly inert, environmentally safe, extended...polymer sites in the active enzyme center differs dramatically between alkyl and aromatic polyesters. More specifically, as the degree of backbone...capped and centrifuged at 3,000 g. This procedure was repeated twice. To the remaining biomass pellet 15 mL of 1 mg/mL solution of N-ethyl-N- nitrosourea

49 CFR 173.181 - Pyrophoric materials (liquids).

Science.gov (United States)

2010-10-01

... inner receptacles of glass or metal, not over 1 L (0.3 gallon) capacity each, having positive screwcap... be closed by positive means, not by friction. (c) Steel drums (1A2) or fiber drums (1G) not exceeding... each, closed by positive means, not friction. (1) Inner packagings must have no opening exceeding 25 mm...

UO2/sodium thermal interaction experiments at AWRE foulness since January 1972

International Nuclear Information System (INIS)

Darby, K.I.; Pottinger, R.C.; Turner, R.G.; Rees, N.J.M.

With an interaction rig described in an earlier report a number of performance tests were carried out. The unwanted gas content of the pyrotechnic charge has been identified as adsorbed water vapor. Calorimetric firings have confirmed the total theoretical energy release and chemical analyses of the debris showed that the pyrotechnic reaction had burnt to completion: experiments to correlate rate of charge burning with the pressure rise are proceeding. Charges with UO 2 diluent instead of the previously used Al 2 O 3 have been fired under sodium and water producing identical effects. One tries to separate debris from sodium by distillation. Pyrotechnic charges diluted with aluminium or silver were fired in a viewing cell, the design of which is described. A very high gas blanket pressure probably due to vapor pressure effects from the charge were observed. One frictional plate has been used with a negligible effect on measured gas blanket pressure. As a means to limit the first bubble excursion same firings were made with an increased gas blanket pressure

Immobilization of fission products in phosphate ceramic waste forms

International Nuclear Information System (INIS)

Singh, D.; Wagh, A.

1997-01-01

Argonne National Laboratory (ANL) is developing chemically bonded phosphate ceramics (CBPCs) to treat low-level mixed wastes, particularly those containing volatiles and pyrophorics that cannot be treated by conventional thermal processes. This work was begun under ANL''s Laboratory Directed Research and Development funds, followed by further development with support from EM-50''s Mixed Waste Focus Area

A Study on the Pressure-Composition Isotherm for the Reaction of ZrCo with Hydrogen

International Nuclear Information System (INIS)

Kim, Sunmi; Paek, Seungwoo; Lee, Minsoo; Kim, Sihyung; Kim, Kwangrag; Ahn, Dohee; Sohn, Soonhwan; Song, Kyumin

2007-01-01

The intermetallic compound of ZrCo which is one of the promising getters for the handling, transport, and storage of tritium has been extensively studied and widely used due to its attractive properties as a tritium getter. At a typical storage temperature of room temperature, the ZrCo-H system has an equilibrium pressure of about 10 -3 Pa for an absorption. The immobilized gas can be recovered at a moderate temperature. Also, from the point of view of safety, the ZrCo and its hydrides have proven to be much less pyrophoric than uranium and its hydrides are the most widely used as a tritium getter. In the current study, the pressure-composition isotherm for the reaction of ZrCo with hydrogen was derived to evaluate its absorption and release characteristics. This provides useful information on the stability and the storage capabilities of ZrCo and the subsequent release of the hydrogen on a heating

A Study on the Pressure-Composition Isotherm for the Reaction of ZrCo with Hydrogen

Energy Technology Data Exchange (ETDEWEB)

Kim, Sunmi; Paek, Seungwoo; Lee, Minsoo; Kim, Sihyung; Kim, Kwangrag; Ahn, Dohee [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Sohn, Soonhwan; Song, Kyumin [Electric Power Research Institute, Daejeon (Korea, Republic of)

2007-10-15

The intermetallic compound of ZrCo which is one of the promising getters for the handling, transport, and storage of tritium has been extensively studied and widely used due to its attractive properties as a tritium getter. At a typical storage temperature of room temperature, the ZrCo-H system has an equilibrium pressure of about 10{sup -3} Pa for an absorption. The immobilized gas can be recovered at a moderate temperature. Also, from the point of view of safety, the ZrCo and its hydrides have proven to be much less pyrophoric than uranium and its hydrides are the most widely used as a tritium getter. In the current study, the pressure-composition isotherm for the reaction of ZrCo with hydrogen was derived to evaluate its absorption and release characteristics. This provides useful information on the stability and the storage capabilities of ZrCo and the subsequent release of the hydrogen on a heating.

Pyrophoric Nanoparticles and Nanoporous Foils for Defense Applications

Science.gov (United States)

2008-12-01

bombs, low-flying aircrafts , and unmanned aerial vehicles are some of these threats that soldiers are often subjected to in a war zone. Nanotechnology...for making flares to distract the enemy or signal fellow soldiers in combat zone, infrared countermeasure decoy flares for low flying aircrafts , and...Pierre, A.C., Baret, G., 2005: Preparation and characterization of transperent Eu doped Y2O3 aerogel monoliths, for application in luminescence, J

Pyrophoric behaviour of uranium hydride and uranium powders

Science.gov (United States)

Le Guyadec, F.; Génin, X.; Bayle, J. P.; Dugne, O.; Duhart-Barone, A.; Ablitzer, C.

2010-01-01

Thermal stability and spontaneous ignition conditions of uranium hydride and uranium metal fine powders have been studied and observed in an original and dedicated experimental device placed inside a glove box under flowing pure argon. Pure uranium hydride powder with low amount of oxide (Oxidation mechanisms are proposed.

Long-life mission reliability for outer planet atmospheric entry probes

Science.gov (United States)

Mccall, M. T.; Rouch, L.; Maycock, J. N.

1976-01-01

The results of a literature analysis on the effects of prolonged exposure to deep space environment on the properties of outer planet atmospheric entry probe components are presented. Materials considered included elastomers and plastics, pyrotechnic devices, thermal control components, metal springs and electronic components. The rates of degradation of each component were determined and extrapolation techniques were used to predict the effects of exposure for up to eight years to deep space. Pyrotechnic devices were aged under accelerated conditions to an equivalent of eight years in space and functionally tested. Results of the literature analysis of the selected components and testing of the devices indicated that no severe degradation should be expected during an eight year space mission.

Risk Characterization for Future Training Scenarios at the Massachusetts Military Reservation (MMR)

National Research Council Canada - National Science Library

Zakikhani, Mansour

2004-01-01

This study was conducted to evaluate potential human and ecological health risks associated with emission of pyrotechnic compounds during future training exercises at the Massachusetts Military Reservation...

Risk Characterization for Future Training Scenarios at the Massachusetts Military Reservation (MMR), Final Results

National Research Council Canada - National Science Library

Zakikhani, Mansour; Dortch, Mark S; Gerald, Jeffrey A; Hawkins, Melanie S

2005-01-01

This study was conducted to evaluate potential human and ecological health risks associated with emission of pyrotechnic compounds during future training exercises at the Massachusetts Military Reservation...

SEM facility for examination of reactive and radioactive materials

International Nuclear Information System (INIS)

Downs, G.L.; Tucker, P.A.

1977-01-01

A scanning electron microscope (SEM) facility for the examination of tritium-containing materials is operational at Mound Laboratory. The SEM is installed with the sample chamber incorporated as an integral part of an inert gas glovebox facility to enable easy handling of radioactive and pyrophoric materials. A standard SEM (ETEC Model B-1) was modified to meet dimensional, operational, and safety-related requirements. a glovebox was designed and fabricated which permitted access with the gloves to all parts of the SEM sample chamber to facilitate director and accessory replacement and repairs. A separate console combining the electron optical column and specimen chamber was interfaced to the glovebox by a custom-made, neoprene bellows so that the vibrations normally associated with the blowers and pumps were damped. Photomicrographs of tritiated pyrophoric materials show the usefulness of this facility. Some of the difficulties involved in the investigation of these materials are also discussed. The SEM is also equipped with an energy dispersive x-ray detector (ORTEC) and a Secondary Ion Mass Spectrometer (3M) attachments. This latter attachment allows analysis of secondary ions with masses ranging from 1-300 amu. (Auth.)

Energetic Materials - Technology, Manufacturing and Processing, 27th International Annual Conference of ICT June 25 - June 28, 1996 Karisruhe, Federal Republic of Germany

National Research Council Canada - National Science Library

1997-01-01

.... The 27th International ICT Annual Conference centers at the discussion of the art in research and development of modern rocket propellants, explosives, gun propellants and pyrotechnics emphasizing...

A comparative study on uranium and ZrCo for the storage of tritium

Energy Technology Data Exchange (ETDEWEB)

Kim, Summi; Paek, Seungwoo; Lee, Minsoo; Kim, Kwangrag; Ahn, Dohee [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Sohn, Soonhwan; Song, Kyumin [Korea Electric Power Research Institute, Daejeon (Korea, Republic of)

2007-07-01

Safe handling, transport, and storage of tritium requires several condition: very low equilibrium pressures over the tritide at room temperature, high dissociation pressure at moderate temperatures, existence of plateau regions in the loading/deloading isotherms, fast adsorption/desorption kinetics, no disproportionation, low reactivity of the metal/tritide system towards air and the major contaminants, low pyrophoricity, and low aging effects caused by the accumulated of He-3.

A comparative study on uranium and ZrCo for the storage of tritium

International Nuclear Information System (INIS)

Kim, Summi; Paek, Seungwoo; Lee, Minsoo; Kim, Kwangrag; Ahn, Dohee; Sohn, Soonhwan; Song, Kyumin

2007-01-01

Safe handling, transport, and storage of tritium requires several condition: very low equilibrium pressures over the tritide at room temperature, high dissociation pressure at moderate temperatures, existence of plateau regions in the loading/deloading isotherms, fast adsorption/desorption kinetics, no disproportionation, low reactivity of the metal/tritide system towards air and the major contaminants, low pyrophoricity, and low aging effects caused by the accumulated of He-3

Global Derivatives

DEFF Research Database (Denmark)

Andersen, Torben Juul

approaches to dealing in the global business environment." - Sharon Brown-Hruska, Commissioner, Commodity Futures Trading Commission, USA. "This comprehensive survey of modern risk management using derivative securities is a fine demonstration of the practical relevance of modern derivatives theory to risk......" provides comprehensive coverage of different types of derivatives, including exchange traded contracts and over-the-counter instruments as well as real options. There is an equal emphasis on the practical application of derivatives and their actual uses in business transactions and corporate risk...... management situations. Its key features include: derivatives are introduced in a global market perspective; describes major derivative pricing models for practical use, extending these principles to valuation of real options; practical applications of derivative instruments are richly illustrated...

Approximate *-derivations and approximate quadratic *-derivations on C*-algebras

Directory of Open Access Journals (Sweden)

Park Choonkil

2011-01-01

Full Text Available Abstract In this paper, we prove the stability of *-derivations and of quadratic *-derivations on Banach *-algebras. We moreover prove the superstability of *-derivations and of quadratic *-derivations on C*-algebras. 2000 Mathematics Subject Classification: 39B52; 47B47; 46L05; 39B72.

Simulating the DIRCM engagement: component and system level performance

CSIR Research Space (South Africa)

Willers, CJ

2012-11-01

Full Text Available , spectrally matched, pyrophoric. Jammers with arc lamps and steered (directional) beams. Early directional laser beams: soft- kill - jamming & dazzling. Single head, complex gimbals. Advanced direction- al laser beams: hard kill - power levels cause damage... countermeasures (DIRCM), employing high power lamps or lasers as sources of infrared energy. The larger aircraft self-protection scenario, comprising the missile, aircraft and DIRCM hardware is a complex system. In this system, each component presents major...

A review of uranium corrosion by hydrogen and the formation of uranium hydride

OpenAIRE

Banos, A.; Harker, N. J.; Scott, T. B.

2018-01-01

Uranium hydride (UH3) is the direct product of the reaction between uranium metal and gaseous hydrogen. In the context of uranium storage, this corrosion reaction is considered deleterious, not just because the structure of the metal may become significantly degraded but also because the resulting hydride is pyrophoric and therefore potentially flammable in air if present in significant quantity. The current review draws from the literature surrounding the uranium-hydrogen system accrued over...

Health and environmental problems of using depleted uranium

International Nuclear Information System (INIS)

Matousek, J.

2006-01-01

In the 1970's, a core of depleted uranium (DU) began to be introduced into the break through anti-tank munitions to enhance their effectiveness. The health and environmental threats of DU stem from the pyrophoric character of the core, burnt when penetrating armour to an aerosol of uranium oxides deposited in tissues after inhalation or ingestion. Their delayed effects are due to internal alpha irradiation by daughter products and toxicity of uranium. (authors)

Pyrotechnic Smoke Compositions Containing Boron Carbide

Science.gov (United States)

2012-06-10

smoke. Experimentation and thermodynamic modeling were used in conjunction to develop the compositions which were then evaluated both visually and by...fuel to produce thick clouds of white smoke. Experimentation and thermodynamic modeling were used in conjunction to develop the compositions which...Transmittance-based measurements may be used to quantify the effectiveness of screening smokes. The Beer -Lambert law is used to define the figures of merit

Europa Lander Material Selection Considerations

Energy Technology Data Exchange (ETDEWEB)

Tappan, Alexander S. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Heller, Mellisa [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2017-01-10

Energetic materials (EMs, explosives, pyrotechnics, propellants) provide high-power output of high temperature reaction products. These products can be solid, liquid, or gaseous during reaction or after the products have equilibrated with the surroundings. For example, high explosives typically consist of carbon, hydrogen, nitrogen, and oxygen bonded within a single molecule, and produce almost exclusively gaseous products. Conversely, intermetallics consist of physical mixtures of metals and metalloids, and produce almost exclusively condensed products. Other materials such as pyrotechnics and propellants have intermediate behavior. All energetic materials react in a self-propagating manner that after ignition, does not necessarily require energy input from the surroundings. The range of reaction velocities can range from mm/s for intermetallics, to km/s for high explosives. Energetic material selection depends on numerous requirements specific to the needs of a system. High explosives are used for applications where high pressure gases are necessary for pushing or fracturing materials (e.g., rock, metal) or creating shock waves or air blast. Propellants are used to produce moderate-pressure, high-temperature products without a shock wave. Pyrotechnics are used to produce numerous effects including: high-temperature products, gases, light, smoke, sound, and others. Thermites are used to produce heat, high-temperature products, materials, and other effects that require condensed products. Intermetallics are used to produce high-temperature condensed products and materials, with very little gas production. Numerous categories of energetic materials exist with overlapping definitions, effects, and properties.

Green colorants based on energetic azole borates.

Science.gov (United States)

Glück, Johann; Klapötke, Thomas M; Rusan, Magdalena; Stierstorfer, Jörg

2014-11-24

The investigation of green-burning boron-based compounds as colorants in pyrotechnic formulations as alternative for barium nitrate, which is a hazard to health and to the environment, is reported. Metal-free and nitrogen-rich dihydrobis(5-aminotetrazolyl)borate salts and dihydrobis(1,3,4-triazolyl)borate salts have been synthesized and characterized by NMR spectroscopy, elemental analysis, mass spectrometry, and vibrational spectroscopy. Their thermal and energetic properties have been determined as well. Several pyrotechnic compositions using selected azolyl borate salts as green colorants were investigated. Formulations with ammonium dinitramide and ammonium nitrate as oxidizers and boron and magnesium as fuels were tested. The burn time, dominant wavelength, spectral purity, luminous intensity, and luminous efficiency as well as the thermal and energetic properties of these compositions were measured. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

High Energy Materials

Indian Academy of Sciences (India)

IAS Admin

Propellants used in rockets, pyrotechnics used in festivities, explosives used for .... In World War II, Wernher von Braun designed the. V-2 rockets which were ... A. Solid Propellants. A solid propellant is made from low or diluted high explosives.

Effect of Strontium Nitrate on Extremely Slow Strobe Compositions

Science.gov (United States)

2017-01-01

Kauzlarich RESEARCH AND TECHNOLOGY DIRECTORATE January 2017 Approved for public release; distribution unlimited. Disclaimer The...g of a nitrate-based starter mixture was included on the top of each cube, with 3 in. of quick match (Precocious Pyrotechnics, Inc., Belgrade, MN

MEASUREMENT OF PERCHLORATE IN WATER BY USE OF AN 18O-ENRICHED ISOTOPIC STANDARD AND ION CHROMATOGRAPHY WITH MASS SPECTROMETRIC DETECTION

Science.gov (United States)

Perchlorate (ClO4-) is a drinking water contaminant originating from the dissolution of the salts of ammonium, potassium, magnesium, or sodium in water. It is used primarily as an oxidant in solid propellant for rockets, missiles, pyrotechnics, as a compone...

Financial Derivatives

DEFF Research Database (Denmark)

Wigan, Duncan

2013-01-01

Contemporary derivatives mark the development of capital and constitute a novel form of ownership. By reconfiguring the temporal, spatial and legal character of ownership derivatives present a substantive challenge to the tax collecting state. While fiscal systems are nationally bounded...... and inherently static, capital itself is unprecedentedly mobile, fluid and fungible. As such derivatives raise the specter of ‘financial weapons of mass destruction’....

Interest rate derivatives

DEFF Research Database (Denmark)

Svenstrup, Mikkel

This Ph.D. thesis consists of four self-contained essays on valuation of interest rate derivatives. In particular derivatives related to management of interest rate risk care are considered.......This Ph.D. thesis consists of four self-contained essays on valuation of interest rate derivatives. In particular derivatives related to management of interest rate risk care are considered....

UO$sub 2$/sodium thermal interaction experiments at A.W.R.E. Foulness since January 1972

Energy Technology Data Exchange (ETDEWEB)

Darby, K. I.; Pottinger, R. C.; Turner, R. G.; Rees, N. J.M.

1974-01-15

From 2nd specialist meeting on sodium fuel interaction in fast reactors; Ispra-Varese, Italy (21 Nov 1973). Work has continued to refine the experimental techniques. The unwanted gas content of the pyrotechnic charge has been identified as absorbed water vapor and a dry glove box assembly system is being constructed to remove it from the pyrotechnic charges. Some bomb calorimeter firings of both burst and unburst charges have confirmed the total theoretical energy release, and recent chemical analyses of the debris recovered from sodium (by chemical extraction with alcohol) showed the pyrotechnic reaction had substantially burnt to completion. Experiments to correlate rate of charge burning with the pressure nise in the charge container are proceeding using a transparent quartz charge holder and photography together with attempted thermocouple measurements. Charges with UO/sub 2/ diluent have been fired under sodium and water producing effects identical to previously reported experiments using Al/sub 2/O/sub 3/ diluent. Steps are currently being taken to separate debris from sodium by the purely physical process of distillation. Pyrotechnic charges diluted with finely divided aluminium metal and separately with silver have been fired under water in a viewing vessel to see if a metal/water thermal interaction could be demonstrated in this rig. This new vessel retains the original internal cylindrical geometry with optical correction on the viewing window for the cylindrical lens effect. These experiments produced very much higher gas blanket pressures on the first bubble expansion but this is thought to be a vapor pressure effect from the charge. The main debris engulfment is seen to take place shortly after the first peak gas blanket pressure and there is some evidence of a variation in the gas blanket pressure decay at this point in time. This may be evidence of a thermal interaction. One frictional plate has been constructed and used (50% void area) wtth a

78 FR 38835 - Safety Zone: City of Vallejo Fourth of July Fireworks Display, Mare Island Strait, Vallejo, CA

Science.gov (United States)

2013-06-28

... submitting material to the docket, call Program Manager, Docket Operations, telephone (202) 366-9826... Atmospheric Administration (NOAA) Chart 18655. Upon the commencement of the fireworks display, the safety zone... protect spectators, vessels, and other property from the hazards associated with the pyrotechnics. C...

Financial Derivatives

OpenAIRE

Janečková, Alena

2011-01-01

1 Abstract/ Financial derivatives The purpose of this thesis is to provide an introduction to financial derivatives which has been, from the legal perspective, described in a not satisfactory manner as quite little literature that can be found about this topic. The main objectives of this thesis are to define the term "financial derivatives" and its particular types and to analyse legal nature of these financial instruments. The last objective is to try to draft future law regulation of finan...

Derivation of activity limits for the disposal of radioactive waste in near surface disposal facilities

International Nuclear Information System (INIS)

2003-12-01

Radioactive waste must be managed safely, consistent with internationally agreed safety standards. The disposal method chosen for the waste should be commensurate with the hazard and longevity of the waste. Near surface disposal is an option used by many countries for the disposal of radioactive waste containing mainly short lived radionuclides and low concentrations of long lived radionuclides. The term 'near surface disposal' encompasses a wide range of design options, including disposal in engineered structures at or just below ground level, disposal in simple earthen trenches a few metres deep, disposal in engineered concrete vaults, and disposal in rock caverns several tens of metres below the surface. The use of a near surface disposal option requires design and operational measures to provide for the protection of human health and the environment, both during operation of the disposal facility and following its closure. To ensure the safety of both workers and the public (both in the short term and the long term), the operator is required to design a comprehensive waste management system for the safe operation and closure of a near surface disposal facility. Part of such a system is to establish criteria for accepting waste for disposal at the facility. The purpose of the criteria is to limit the consequences of events which could lead to radiation exposures and in addition, to prevent or limit hazards, which could arise from non-radiological causes. Waste acceptance criteria include limits on radionuclide content concentration in waste materials, and radionuclide amounts in packages and in the repository as a whole. They also include limits on quantity of free liquids, requirements for exclusion of chelating agents and pyrophoric materials, and specifications of the characteristics of the waste containers. Largely as a result of problems encountered at some disposal facilities operated in the past, in 1985 the IAEA published guidance on generic acceptance

21 CFR 184.1685 - Rennet (animal-derived) and chymosin preparation (fermentation-derived).

Science.gov (United States)

2010-04-01

... (fermentation-derived). 184.1685 Section 184.1685 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF... (animal-derived) and chymosin preparation (fermentation-derived). (a)(1) Rennet and bovine rennet are... clear solution containing the active enzyme chymosin (E.C. 3.4.23.4). It is derived, via fermentation...

Safety Protocols at MAT Lab

International Nuclear Information System (INIS)

Wadawale, A.; Chopade, S.; Chaudhury, K.; Pal, M.K.; Kushwah, N.; Shah, A.Y.; Kedarnath, G.; Priyadarsini, K.I.; Jain, V.K.

2017-01-01

MAT Lab of Chemistry Division, BARC (A Class 10000 Clean room laboratory) has been in operation since 2004 for process development of ultra-purification of several strategically important materials (Ga, As, Sb, In, CsI and Ge) and synthesis of their organometallic compounds. Of these, work related to purification of As, Sb, and In, has been discontinued. Due to high toxicity and pyrophoric nature of some of the compounds, stringent safety regulations were formulated and subsequently implemented by the division

Review of DREV uranium research

International Nuclear Information System (INIS)

Drolet, J.P.; Erickson, W.H.; Tardif, H.P.

1976-01-01

This report presents a brief review of the DREV uranium research carried out on various aspects of the physical metallurgy of depleted uranium alloys. It includes (1) a survey of the early work on polynary alloys, (2) recent metallurgical investigations on various alloy systems and (3) miscellaneous studies on grain size refinement, grain growth, powder metallurgy, pyrophoricity and directional casting of uranium alloys. A general summary of most of the studies carried out during the last ten years is also presented

Theoretical Studies of Nanoclusters (Briefing Charts)

Science.gov (United States)

2015-07-23

nanoclusters. However, scanning transmission electron microscopy ( STEM ) measures show cluster inversion occurred to produce MgyCux(!) a) copper atoms b...methane (née CLL -1) as a potential explosive ingredient: a theoretical study”, Propellants, Explosives, Pyrotechnics 38, 9-13 (2013). Jesus Paulo L

DETERMINATION OF PERCHLORATE BY ION CHROMATOGRAPHY, SUPPRESSED CONDUCTIVITY AND MASS SPECTROMETRIC DETECTION USING AN OXYGEN-18 ENRICHED ISOTROPIC INTERNAL STANDARD

Science.gov (United States)

Perchlorate (ClO4 -) is a drinking water contaminant originating from the dissolution of the salts of ammonium, potassium, magnesium, or sodium in water. It is used primarily as an oxidant in solid propellant for rockets, missiles, pyrotechnics, as a component in air bag infla...

MEASUREMENT OF PERCHLORATE IN WATER USING AN OXYGEN-18 ENRICHED ISOTOPE STANDARD AND ION CHROMATOGRAPHY MASS SPECTROMETRIC DETECTION

Science.gov (United States)

Perchlorate (ClO4 -) is a drinking water contaminant originating from the dissolution of the salts of ammonium, potassium, magnesium, or sodium in water. It is used primarily as an oxidant in solid propellant for rockets, missiles, pyrotechnics, as a component in air bag infla...

SUB-PPB QUANTITATION AND CONFIRMATION OF PERCHLORATE IN DRINKING WATERS CONTAINING HIGH TOTAL DISSOLVED SOLIDS USING ION CHROMATOGRAPHY WITH MASS SPECTROMETRIC DETECTION

Science.gov (United States)

Perchlorate (ClO4 -) is a drinking water contaminant originating from the dissolution of the salts of ammonium, potassium, magnesium, or sodium in water. It is used primarily as an oxidant in solid propellant for rockets, missiles, pyrotechnics, as a component in air bag infla...

76 FR 38053 - Clarification of the Fireworks Approvals Policy

Science.gov (United States)

2011-06-29

.... Background The pyrotechnic industry is a global logistics supply chain comprised of mostly foreign fireworks... between these two entities. All participants throughout the supply chain will be held accountable for... document. One commenter requests PHMSA consider waste management of used or defective fireworks when...

Thermal decomposition of phase-stabilised ammonium nitrate (PSAM), HTPB based propellants. The effect of iron(III)oxide burning-rate catalyst

NARCIS (Netherlands)

Carvalheira, P.; Gadiot, G.M.H.J.L.; Klerk, W.P.C. de

1995-01-01

Phase-stabilised ammonium nitrate (PSAN) and hydroxyl-terminated polybutadiene (HTPB) are the main ingredients of propellants used with success in some pyrotechnic igniter components of the VULCAIN liquid rocket engine for the ARIANE 5. Small amounts of selected additives play an important role in

Derivative chameleons

International Nuclear Information System (INIS)

Noller, Johannes

2012-01-01

We consider generalized chameleon models where the conformal coupling between matter and gravitational geometries is not only a function of the chameleon field φ, but also of its derivatives via higher order co-ordinate invariants (such as ∂ μ φ∂ μ φ,□φ,...). Specifically we consider the first such non-trivial conformal factor A(φ,∂ μ φ∂ μ φ). The associated phenomenology is investigated and we show that such theories have a new generic mass-altering mechanism, potentially assisting the generation of a sufficiently large chameleon mass in dense environments. The most general effective potential is derived for such derivative chameleon setups and explicit examples are given. Interestingly this points us to the existence of a purely derivative chameleon protected by a shift symmetry for φ → φ+c. We also discuss potential ghost-like instabilities associated with mass-lifting mechanisms and find another, mass-lowering and instability-free, branch of solutions. This suggests that, barring fine-tuning, stable derivative models are in fact typically anti-chameleons that suppress the field's mass in dense environments. Furthermore we investigate modifications to the thin-shell regime and prove a no-go theorem for chameleon effects in non-conformal geometries of the disformal type

Derivative chameleons

Energy Technology Data Exchange (ETDEWEB)

Noller, Johannes, E-mail: johannes.noller08@imperial.ac.uk [Theoretical Physics, Blackett Laboratory, Imperial College London, Prince Consort Road, London, SW7 2BZ (United Kingdom)

2012-07-01

We consider generalized chameleon models where the conformal coupling between matter and gravitational geometries is not only a function of the chameleon field φ, but also of its derivatives via higher order co-ordinate invariants (such as ∂{sub μ}φ∂{sup μ}φ,□φ,...). Specifically we consider the first such non-trivial conformal factor A(φ,∂{sub μ}φ∂{sup μ}φ). The associated phenomenology is investigated and we show that such theories have a new generic mass-altering mechanism, potentially assisting the generation of a sufficiently large chameleon mass in dense environments. The most general effective potential is derived for such derivative chameleon setups and explicit examples are given. Interestingly this points us to the existence of a purely derivative chameleon protected by a shift symmetry for φ → φ+c. We also discuss potential ghost-like instabilities associated with mass-lifting mechanisms and find another, mass-lowering and instability-free, branch of solutions. This suggests that, barring fine-tuning, stable derivative models are in fact typically anti-chameleons that suppress the field's mass in dense environments. Furthermore we investigate modifications to the thin-shell regime and prove a no-go theorem for chameleon effects in non-conformal geometries of the disformal type.

78 FR 74010 - Safety Zone: Sausalito Lighted Boat Parade Fireworks Display, San Francisco Bay, Sausalito, CA

Science.gov (United States)

2013-12-10

... [email protected] . If you have questions on viewing or submitting material to the docket... Administration (NOAA) Chart 18653. This safety zone establishes a temporary restricted area on the waters 100..., vessels, and other property from the hazards associated with pyrotechnics. C. Discussion of the Final Rule...

An intriguing oscillating combustion phenomenon

NARCIS (Netherlands)

Corbel, J.M.L.; Lingen, J.N.J.; Zevenbergen, J.F.; Gijzeman, O.L.J.; Meijerink, A.

2012-01-01

Strobes are pyrotechnic compositions that emit bright flashes of white or colored light at regular time intervals. The strobe effect has applications in various fields, most notably in the fireworks industry and in the military area (signaling – missile decoys – crowd control). However, the chemical

2005 International Infantry and Joint Services Small Arms Systems Annual Symposium Exhibition and Firing Demonstration

Science.gov (United States)

2005-05-19

important factor! Movies and computer games… 4By watching movies and playing computer games some soldiers believe that a hit anywhere will bring the...Description Non-toxic/ biodegradable payload/no pyrotechnics 40mm ctg fired from the M203 grenade launcher Utilizes chem-illuminescent materials found in

Can fireworks-related injuries to children during festivities be ...

African Journals Online (AJOL)

Consumer fireworks cause serious but preventable injuries to children, either as users or bystanders. Children and their families should be encouraged to enjoy pyrotechnical displays conducted by professionals at designated areas. All fireworks for individual private use should either be supervised by an adult or banned.

49 CFR 171.7 - Reference material.

Science.gov (United States)

2010-10-01

.../publications.com; AAR Manual of Standards and Recommended Practices, Section C—Part III, Specifications for... Edition, March 1996 172.102. American Pyrotechnics Association (APA), P.O. Box 30438, Bethesda, MD 20824, (301) 907-8181, www.americanpyro.com: APA Standard 87-1, Standard for Construction and Approval for...

77 FR 69927 - Safety Advisory Notice: Safety Advisory for Shippers and Carriers of Air Bags

Science.gov (United States)

2012-11-21

... to devices containing unapproved explosives; and (4) provide the next steps that PHMSA will take to... parts. Some of these devices look nearly identical to legitimate products, including the branding of... pyrotechnic device, known as an initiator or electric match, consisting of an electrical conductor cocooned in...

75 FR 59963 - Safety Zone: Monte Foundation Firework Display, Monterey, CA

Science.gov (United States)

2010-09-29

...-AA00 Safety Zone: Monte Foundation Firework Display, Monterey, CA AGENCY: Coast Guard, DHS. ACTION... Monte Foundation Firework Display. This safety zone is established to ensure the safety of participants... be completed. Because of the dangers posed by the pyrotechnics used in this fireworks display, the...

Neutron radiography in Indian space programme

CERN Document Server

Viswanathan, K

1999-01-01

Pyrotechnic devices are indispensable in any space programme to perform such critical operations as ignition, stage separation, solar panel deployment, etc. The nature of design and configuration of different types of pyrotechnic devices, and the type of materials that are put in their construction make the inspection of them with thermal neutrons more favourable than any other non destructive testing methods. Although many types of neutron sources are available for use, generally the radiographic quality/exposure duration and cost of source run in opposite directions even after four decades of research and development. But in the area of space activity, by suitably combining the X-ray and neutron radiographic requirements, the inspection of the components can be made economically viable. This is demonstrated in the Indian space programme by establishing a 15 MeV linear accelerator based neutron generator facility to inspect medium to giant solid propellant boosters by X-ray inspection and all types of critic...

Investigations of mechanical properties and Debye temperature of U2Ti

International Nuclear Information System (INIS)

Chattaraj, D.; Dash, Smruti; Kulkarni, S.G.

2012-01-01

U 2 Ti is a potential solid state material for safe storage, supply and recovery of hydrogen isotopes. It is not pyrophoric and its hydride is resistance to powdering upon hydrogenation. These two properties made this alloy advantageous over the conventionally used uranium as tritium getter material. Hence, thorough study of material properties like thermodynamic and elastic properties of U 2 Ti is important. Recently, present authors have reported thermodynamic functions for U 2 Ti. However, elastic moduli of this alloy have not been reported. The second derivatives of the internal energy with respect to strain, gives adiabatic elastic constants. Thus adiabatic elastic constants are related to interatomic potentials of material. They are also related to the thermal properties of a solid through the Debye theory. For metal hydride material, the elastic constants are useful for an evaluation of the elastic contribution to the hydrogen-hydrogen interaction energy and the elastic energy associated with the precipitation of hydride phases. The present paper reports the ultrasonic measurement of the elastic moduli and Debye temperature of U 2 Ti at room temperature using 38 DL plus ultrasonic velocitymeter

Taxation of Derivatives

DEFF Research Database (Denmark)

Dyppel, Katja Joo

2013-01-01

The main objective for this thesis is to analyse and systematise the Danish legislation on taxation of derivatives. According to financial terminology, a derivative is a financial instrument. Its value is derived from changes in the value of one or more underlying assets.The most common derivatives...... in the Danish tax legislation. However, contracts known as forwards (terminskontrakter) and options (aftaler om køberetter og salgsretter) are generally included in the term financials contracts covered by the Danish Act on Taxation of Gains and Losses on Claims and Debt. The main part of the analysis deals...... with the scope of sections 29-33 of the Danish Act on Taxation of Gains and Losses on Claims and Debt and the tax consequences for the covered financial contracts. In the analysis of taxation of derivatives, the fundamental issues of qualification and tax treatment of the instruments are dealt with....

Experts' understanding of partial derivatives using the Partial Derivative Machine

OpenAIRE

Roundy, David; Dorko, Allison; Dray, Tevian; Manogue, Corinne A.; Weber, Eric

2014-01-01

Partial derivatives are used in a variety of different ways within physics. Most notably, thermodynamics uses partial derivatives in ways that students often find confusing. As part of a collaboration with mathematics faculty, we are at the beginning of a study of the teaching of partial derivatives, a goal of better aligning the teaching of multivariable calculus with the needs of students in STEM disciplines. As a part of this project, we have performed a pilot study of expert understanding...

Global Derivatives Market

Directory of Open Access Journals (Sweden)

Stankovska Aleksandra

2017-06-01

Full Text Available Globalization of financial markets led to the enormous growth of volume and diversification of financial transactions. Financial derivatives were the basic elements of this growth. Derivatives play a useful and important role in hedging and risk management, but they also pose several dangers to the stability of financial markets and thereby the overall economy. Derivatives are used to hedge and speculate the risk associated with commerce and finance.

75 FR 79085 - Notice and Request for Comments on the Clarification of the Fireworks Approvals Policy

Science.gov (United States)

2010-12-17

...., Washington, DC 20590. Background The pyrotechnic industry is a global logistics supply chain comprised of... position in the supply chain. It is unclear as to what was the justification for this action. Regardless... Docket Management System (FDMS), including any personal information. Docket: For access to the dockets to...

36 CFR 327.13 - Explosives, firearms, other weapons and fireworks.

Science.gov (United States)

2010-07-01

... weapons and fireworks. 327.13 Section 327.13 Parks, Forests, and Public Property CORPS OF ENGINEERS... ADMINISTERED BY THE CHIEF OF ENGINEERS § 327.13 Explosives, firearms, other weapons and fireworks. (a) The... explosives or explosive devices of any kind, including fireworks or other pyrotechnics, is prohibited unless...

Development of an FPGA-based multipoint laser pyroshock measurement system for explosive bolts

International Nuclear Information System (INIS)

Abbas, Syed Haider; Lee, Jung-Ryul; Jang, Jae-Kyeong; Kim, Zaeill

2016-01-01

Pyroshock can cause failure to the objective of an aerospace structure by damaging its sensitive electronic equipment, which is responsible for performing decisive operations. A pyroshock is the high intensity shock wave that is generated when a pyrotechnic device is explosively triggered to separate, release, or activate structural subsystems of an aerospace architecture. Pyroshock measurement plays an important role in experimental simulations to understand the characteristics of pyroshock on the host structure. This paper presents a technology to measure a pyroshock wave at multiple points using laser Doppler vibrometers (LDVs). These LDVs detect the pyroshock wave generated due to an explosive-based pyrotechnical event. Field programmable gate array (FPGA) based data acquisition is used in the study to acquire pyroshock signals simultaneously from multiple channels. This paper describes the complete system design for multipoint pyroshock measurement. The firmware architecture for the implementation of multichannel data acquisition on an FPGA-based development board is also discussed. An experiment using explosive bolts was configured to test the reliability of the system. Pyroshock was generated using explosive excitation on a 22-mm-thick steel plate. Three LDVs were deployed to capture the pyroshock wave at different points. The pyroshocks captured were displayed as acceleration plots. The results showed that our system effectively captured the pyroshock wave with a peak-to-peak magnitude of 303 741 g. The contribution of this paper is a specialized architecture of firmware design programmed in FPGA for data acquisition of large amount of multichannel pyroshock data. The advantages of the developed system are the near-field, multipoint, non-contact, and remote measurement of a pyroshock wave, which is dangerous and expensive to produce in aerospace pyrotechnic tests.

Development of an FPGA-based multipoint laser pyroshock measurement system for explosive bolts

Energy Technology Data Exchange (ETDEWEB)

Abbas, Syed Haider; Lee, Jung-Ryul [Department of Aerospace Engineering, Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of); Jang, Jae-Kyeong [The Engineering Institute-Korea, Chonbuk National University, Jeonju (Korea, Republic of); Kim, Zaeill [The 4th R& D Institute-1st directorate, Agency for Defense Development, Daejeon (Korea, Republic of)

2016-07-15

Pyroshock can cause failure to the objective of an aerospace structure by damaging its sensitive electronic equipment, which is responsible for performing decisive operations. A pyroshock is the high intensity shock wave that is generated when a pyrotechnic device is explosively triggered to separate, release, or activate structural subsystems of an aerospace architecture. Pyroshock measurement plays an important role in experimental simulations to understand the characteristics of pyroshock on the host structure. This paper presents a technology to measure a pyroshock wave at multiple points using laser Doppler vibrometers (LDVs). These LDVs detect the pyroshock wave generated due to an explosive-based pyrotechnical event. Field programmable gate array (FPGA) based data acquisition is used in the study to acquire pyroshock signals simultaneously from multiple channels. This paper describes the complete system design for multipoint pyroshock measurement. The firmware architecture for the implementation of multichannel data acquisition on an FPGA-based development board is also discussed. An experiment using explosive bolts was configured to test the reliability of the system. Pyroshock was generated using explosive excitation on a 22-mm-thick steel plate. Three LDVs were deployed to capture the pyroshock wave at different points. The pyroshocks captured were displayed as acceleration plots. The results showed that our system effectively captured the pyroshock wave with a peak-to-peak magnitude of 303 741 g. The contribution of this paper is a specialized architecture of firmware design programmed in FPGA for data acquisition of large amount of multichannel pyroshock data. The advantages of the developed system are the near-field, multipoint, non-contact, and remote measurement of a pyroshock wave, which is dangerous and expensive to produce in aerospace pyrotechnic tests.

High energy materials. Propellants, explosives and pyrotechnics

Energy Technology Data Exchange (ETDEWEB)

Agrawal, Jai Prakash

2010-07-01

Authored by an insider with over 40 years of high energy materials (HEMs) experience in academia, industry and defence organizations, this handbook and ready reference covers all important HEMs from the 1950s to the present with their respective properties and intended purposes. Written at an attainable level for professionals, engineers and technicians alike, the book provides a comprehensive view of the current status and suggests further directions for research and development. An introductory chapter on the chemical and thermodynamic basics allows the reader to become acquainted with the fundamental features of explosives, before moving on to the important safety aspects in processing, handling, transportation and storage of high energy materials. With its collation of results and formulation strategies hitherto scattered in the literature, this should be on the shelf of every HEM researcher and developer. (orig.)

Advanced Technology for Pyrotechnic Mixtures and Munitions

Science.gov (United States)

1977-07-01

or at ambient I ,/ BLENDING AND CASTING CURING REMOVING MOLD WAFER MANUFACTURING ? / I / SI ,/ iAUTOMATIC LOADING Figure 1. Plastic Bonded Starter Mix...material (fines) is recycled through the compacting rollers. asshwn The Chilsonator used at EA consisted only of the compaction rollers and the controls ...standardized process controls . Oversize material is pulverized and combined with the undersize material for s" ,regranulation in another batch. 2 ,Both the

Pyrotechnic Shock Analysis Using Statistical Energy Analysis

Science.gov (United States)

2015-10-23

SEA subsystems. A couple of validation examples are provided to demonstrate the new approach. KEY WORDS : Peak Ratio, phase perturbation...Ballistic Shock Prediction Models and Techniques for Use in the Crusader Combat Vehicle Program,” 11th Annual US Army Ground Vehicle Survivability

Derivatives in emerging markets

OpenAIRE

Dubravko Mihaljek; Frank Packer

2010-01-01

Turnover of derivatives has grown more rapidly in emerging markets than in developed countries. Foreign exchange derivatives are the most commonly traded of all risk categories, with increasingly frequent turnover in emerging market currencies and a growing share of cross-border transactions. As the global reach of the financial centres in emerging Asia has expanded, the offshore trading of many emerging market currency derivatives has risen as well. Growth in derivatives turnover is positive...

fq-Derivations of G-Algebra

Directory of Open Access Journals (Sweden)

Deena Al-Kadi

2016-01-01

Full Text Available We introduce the notion of fq-derivation as a new derivation of G-algebra. For an endomorphism map f of any G-algebra X, we show that at least one fq-derivation of X exists. Moreover, for such a map, we show that a self-map dqf of X is fq-derivation of X if X is an associative medial G-algebra. For a medial G-algebra X, dqf is fq-derivation of X if dqf is an outside fq-derivation of X. Finally, we show that if f is the identity endomorphism of X then the composition of two fq-derivations of X is a fq-derivation. Moreover, we give a condition to get a commutative composition.

Electricity derivatives

CERN Document Server

Aïd, René

2015-01-01

Offering a concise but complete survey of the common features of the microstructure of electricity markets, this book describes the state of the art in the different proposed electricity price models for pricing derivatives and in the numerical methods used to price and hedge the most prominent derivatives in electricity markets, namely power plants and swings. The mathematical content of the book has intentionally been made light in order to concentrate on the main subject matter, avoiding fastidious computations. Wherever possible, the models are illustrated by diagrams. The book should allow prospective researchers in the field of electricity derivatives to focus on the actual difficulties associated with the subject. It should also offer a brief but exhaustive overview of the latest techniques used by financial engineers in energy utilities and energy trading desks.

77 FR 52636 - Hazardous Materials: Revision to Fireworks Regulations (RRR)

Science.gov (United States)

2012-08-30

....4G consumer fireworks complies with the American Pyrotechnics Association's (APA) Standard 87-1 (IBR... processing of consumer fireworks applications, resulting in faster time to market for each firework device... industry, 50 percent of records will be stored in paper format and 50 percent of records will be stored in...

75 FR 81854 - Safety Zone; New Year's Celebration for the City of San Francisco, Fireworks Display, San...

Science.gov (United States)

2010-12-29

... display is for entertainment purposes. From 11 a.m. until 11 p.m. on December 31, 2010, pyrotechnics will... Standards The National Technology Transfer and Advancement Act (NTTAA) (15 U.S.C. 272 note) directs agencies... changing Regulated Navigation Areas and security or safety zones. An environmental analysis checklist and a...

Versatile Boron Carbide-Based Visual Obscurant Compositions for Smoke Munitions

Science.gov (United States)

2015-04-17

volatilize and disperse reaction products and inert diluents. Unlike the refractory oxides of common pyrotechnic fuels such as magnesium and aluminum, boron...peaks marked. [1] Akagi, R.; Ohtori, N.; Umesaki, N. Raman spectra of K2O–B2O3 glasses and melts. Journal of Non-Crystalline Solids. 2001

Low Mass Ions in Laser Desorption/Ionization Mass Spectrometry of 1-Methoxy-5-aminotetrazole

Energy Technology Data Exchange (ETDEWEB)

Cho, Soo Gyeong; Bae, Kwang Tae; Goh, Eun Mee; Bae, Se Won [Agency for Defense Development, Daejeon (Korea, Republic of); Shin, Ik-Soo [Soongsil University, Seoul (Korea, Republic of)

2016-01-15

The development of novel energetic molecules (EMs) with high power, good safety features, great chemical stability, and environmentally less harmful nature is of great interest in the satellite launcher, missile warhead, ammunition, and pyrotechnic researches. Recently, many researchers have focused on aromatic nitrogen heterocycles such as pyrazole, imidazole, triazole, tetrazole, and pentazole as promising candidates to replace the current EMs used in civilian and military applications. We performed MALDI and LDI experiments with energetic tetrazole derivatives which were of great interest for the application of high performance explosives and fast burning propellants. Particularly, LDI experiments provided low mass ion peaks from decomposition of MAT, which were useful to analyze decomposition mechanism of tetrazoles at TOF MS in high vacuum. The LDI experiments showed various decomposed ion products, which implied several decomposition mechanisms including the detachment of side function groups and the fragmentation of tetrazole ring. The high-level DFT calculations also supported the peaks obtained from LDI experiments.

SYNTHESIS OF FLAVANONE-6-CARBOXYLIC ACID DERIVATIVES FROM SALICYLIC ACID DERIVATIVE

Directory of Open Access Journals (Sweden)

Muhammad Idham Darussalam Mardjan

2012-02-01

Full Text Available Synthesis of flavanone-6-carboxylic acid derivatives had been conducted via the route of chalcone. The synthesis was carried out from salicylic acid derivative, i.e. 4-hydroxybenzoic acid, via esterification, Fries rearrangement, Claisen-Schmidt condensation and 1,4-nucleophilic addition reactions. Structure elucidation of products was performed using FT-IR, 1H-NMR, GC-MS and UV-Vis spectrometers. Reaction of 4-hydroxybenzoic acid with methanol catalyzed with sulfuric acid produced methyl 4-hydroxybenzoate in 87% yield. The acid-catalyzed-acetylation of the product using acetic anhydride gave methyl 4-acetoxybenzoate in 75% yield. Furthermore, solvent-free Fries rearrangement of methyl 4-acetoxybenzoate in the presence of AlCl3 produced 3-acetyl-4-hydroxybenzoic acid as the acetophenone derivatives in 67% yield. Then, Claisen-Schmidt condensation of the acetophenone and benzaldehyde derivatives of p-anisaldehyde and veratraldehyde in basic condition gave 2'-hydroxychalcone-5'-carboxylic acid derivatives  in 81 and 71 % yield, respectively. Finally, the ring closure reaction of the chalcone yielded the corresponding flavanone-6-carboxylic acids in 67 and 59% yield, respectively.

New group III precursors for the MOVPE of GaAs and InP based material

International Nuclear Information System (INIS)

Hostaler, M.; Pohl, L.; Brauers, A.; Balk, P.; Frese, V.; Hovel, R.; Regel, G.K.; Hardtdegen, H.

1989-01-01

This paper presents proposals for the synthesis of several group III metal organics (In, Ga, Al compounds) and preliminary results on their use in the MOVPE (metal organic vapor phase epitaxy) of III-V semiconductors. The common feature of all these precursors is that they are saturated by inter- or intramolecular coordination. They are even non-pyrophoric and air resistant which is an interesting aspect with respect to safe handling. In addition, the compounds are liquid at room temperature with a low but sufficient vapor pressure for MOVPE without additional heating of the source

Dissolution of metallic uranium and its alloys. Part 1. Review of analytical and process-scale metallic uranium dissolution

International Nuclear Information System (INIS)

Laue, C.A.; Gates-Anderson, D.; Fitch, T.E.

2004-01-01

This review focuses on dissolution/reaction systems capable of treating uranium metal waste to remove its pyrophoric properties. The primary emphasis is the review of literature describing analytical and production-scale dissolution methods applied to either uranium metal or uranium alloys. A brief summary of uranium's corrosion behavior is included since the corrosion resistance of metals and alloys affects their dissolution behavior. Based on this review, dissolution systems were recommended for subsequent screening studies designed to identify the best system to treat depleted uranium metal wastes at Lawrence Livermore National Laboratory (LLNL). (author)

Superstability for Generalized Module Left Derivations and Generalized Module Derivations on a Banach Module (I

Directory of Open Access Journals (Sweden)

Rassias JM

2009-01-01

Full Text Available We discuss the superstability of generalized module left derivations and generalized module derivations on a Banach module. Let be a Banach algebra and a Banach -module, and . The mappings , and are defined and it is proved that if (resp., is dominated by then is a generalized (resp., linear module- left derivation and is a (resp., linear module- left derivation. It is also shown that if (resp., is dominated by then is a generalized (resp., linear module- derivation and is a (resp., linear module- derivation.

Adaptive synchronization of the complex dynamical network with non-derivative and derivative coupling

Energy Technology Data Exchange (ETDEWEB)

Xu Yuhua, E-mail: yuhuaxu2004@163.co [College of Information Science and Technology, Donghua University, Shanghai 201620 (China) and Department of Maths, Yunyang Teachers' College, Hubei 442000 (China); Zhou Wuneng, E-mail: wnzhou@163.co [College of Information Science and Technology, Donghua University, Shanghai 201620 (China); Fang Jian' an [College of Information Science and Technology, Donghua University, Shanghai 201620 (China); Sun Wen [School of Mathematics and Information, Yangtze University, Hubei Jingzhou 434023 (China)

2010-04-05

This Letter investigates the synchronization of a general complex dynamical network with non-derivative and derivative coupling. Based on LaSalle's invariance principle, adaptive synchronization criteria are obtained. Analytical result shows that under the designed adaptive controllers, a general complex dynamical network with non-derivative and derivative coupling can asymptotically synchronize to a given trajectory, and several useful criteria for synchronization are given. What is more, the coupling matrix is not assumed to be symmetric or irreducible. Finally, simulations results show the method is effective.

Credit derivatives in emerging markets

OpenAIRE

Romain Rancière

2002-01-01

Credit Derivatives are securities that offer protection against credit or default risk of bonds or loans. The credit derivatives emerging market has grown rapidly and credit derivatives are widely used. This paper describes the emerging credit derivatives market structure. The current market activity is analyzed through elementary pricing dynamics and the study of the term structure of default risk. Focusing on the performance of credit derivatives in stress situation, including legal and mar...

Vitamin D derivatives

International Nuclear Information System (INIS)

Deluca, H.F.; Schnoes, H.K.; Napoli, J.L.; Fivizzani, M.A.

1982-01-01

The chemical preparation of 26,27-isotopically labelled vitamin D 3 derivatives of high specific activity is described. These labelled vitamin D derivatives are useful in the determination of vitamin D metabolite levels in the blood and tissues of man and animals. (U.K.)

Credit derivatives and risk management

OpenAIRE

Michael S. Gibson

2007-01-01

The striking growth of credit derivatives suggests that market participants find them to be useful tools for risk management. I illustrate the value of credit derivatives with three examples. A commercial bank can use credit derivatives to manage the risk of its loan portfolio. An investment bank can use credit derivatives to manage the risks it incurs when underwriting securities. An investor, such as an insurance company, asset manager, or hedge fund, can use credit derivatives to align its...

Toward Multi-scale Modeling and simulation of conduction in heterogeneous materials

Energy Technology Data Exchange (ETDEWEB)

Lechman, Jeremy B. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Battaile, Corbett Chandler. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Bolintineanu, Dan [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Cooper, Marcia A. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Erikson, William W. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Foiles, Stephen M. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Kay, Jeffrey J [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Phinney, Leslie M. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Piekos, Edward S. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Specht, Paul Elliott [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Wixom, Ryan R. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Yarrington, Cole [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

2015-01-01

This report summarizes a project in which the authors sought to develop and deploy: (i) experimental techniques to elucidate the complex, multiscale nature of thermal transport in particle-based materials; and (ii) modeling approaches to address current challenges in predicting performance variability of materials (e.g., identifying and characterizing physical- chemical processes and their couplings across multiple length and time scales, modeling information transfer between scales, and statically and dynamically resolving material structure and its evolution during manufacturing and device performance). Experimentally, several capabilities were successfully advanced. As discussed in Chapter 2 a flash diffusivity capability for measuring homogeneous thermal conductivity of pyrotechnic powders (and beyond) was advanced; leading to enhanced characterization of pyrotechnic materials and properties impacting component development. Chapter 4 describes success for the first time, although preliminary, in resolving thermal fields at speeds and spatial scales relevant to energetic components. Chapter 7 summarizes the first ever (as far as the authors know) application of TDTR to actual pyrotechnic materials. This is the first attempt to actually characterize these materials at the interfacial scale. On the modeling side, new capabilities in image processing of experimental microstructures and direct numerical simulation on complicated structures were advanced (see Chapters 3 and 5). In addition, modeling work described in Chapter 8 led to improved prediction of interface thermal conductance from first principles calculations. Toward the second point, for a model system of packed particles, significant headway was made in implementing numerical algorithms and collecting data to justify the approach in terms of highlighting the phenomena at play and pointing the way forward in developing and informing the kind of modeling approach originally envisioned (see Chapter 6). In

16 CFR 1507.11 - Party poppers.

Science.gov (United States)

2010-01-01

... 16 Commercial Practices 2 2010-01-01 2010-01-01 false Party poppers. 1507.11 Section 1507.11... FIREWORKS DEVICES § 1507.11 Party poppers. Party poppers (also known by other names such as “Champagne Party Poppers,” and “Party Surprise Poppers,”) shall not contain more than 0.25 grains of pyrotechnic...

Theoretical Energy Release of Thermites, Intermetallics, and Combustible Metals

Energy Technology Data Exchange (ETDEWEB)

Fischer, S.H.; Grubelich, M.C.

1999-05-14

Thermite mixtures, intermetallic reactants, and metal fuels have long been used in pyrotechnic applications. Advantages of these systems typically include high energy density, high combustion temperature, and a wide range of gas production. They generally exhibit high temperature stability and possess insensitive ignition properties. For the specific applications of humanitarian demining and disposal of unexploded ordnance, these pyrotechnic formulations offer additional benefits. The combination of high thermal input with low brisance can be used to neutralize the energetic materials in mines and other ordnance without the "explosive" high-blast-pressure events that can cause extensive collateral damage to personnel, facilities, and the environment. In this paper, we review the applications, benefits, and characteristics of thermite mixtures, intermetallic reactants, and metal fuels. Calculated values for reactant density, heat of reaction (per unit mass and per unit volume), and reaction temperature (without and with consideration of phase changes and the variation of specific heat values) are tabulated. These data are ranked in several ways, according to density, heat of reaction, reaction temperature, and gas production.

Sol-Gel Manufactured Energetic Materials

Science.gov (United States)

Simpson, Randall L.; Lee, Ronald S.; Tillotson, Thomas M.; Hrubesh, Lawrence W.; Swansiger, Rosalind W.; Fox, Glenn A.

2005-05-17

Sol-gel chemistry is used for the preparation of energetic materials (explosives, propellants and pyrotechnics) with improved homogeneity, and/or which can be cast to near-net shape, and/or made into precision molding powders. The sol-gel method is a synthetic chemical process where reactive monomers are mixed into a solution, polymerization occurs leading to a highly cross-linked three dimensional solid network resulting in a gel. The energetic materials can be incorporated during the formation of the solution or during the gel stage of the process. The composition, pore, and primary particle sizes, gel time, surface areas, and density may be tailored and controlled by the solution chemistry. The gel is then dried using supercritical extraction to produce a highly porous low density aerogel or by controlled slow evaporation to produce a xerogel. Applying stress during the extraction phase can result in high density materials. Thus, the sol-gel method can be used for precision detonator explosive manufacturing as well as producing precision explosives, propellants, and pyrotechnics, along with high power composite energetic materials.

CERN in the spotlight at the Geneva Festival

CERN Document Server

2004-01-01

CERN will be the guest of honour at the Geneva Festival, which takes place from 29 July to 8 August. The Organization will be involved in two big events: the curtain-raising firework display and the end-of-festival concert. Come and see the creation of the Universe... acted out by fireworks! CERN, celebrating its 50th anniversary, will raise the curtain on the annual Geneva Festival (Fêtes de Genève) on Friday 30 July at 10.15 p.m. with a pyrotechnical and musical extravaganza. The display will be accompanied by a narration explaining the different stages of creation, written by CERN physicist Rolf Landua. Pyro-musical design is by Catherine Walder, overall firework design by René Gousset and pyrotechnical design by Pierre-Alain Beretta (Pyrostars). For further information see: www.cern.ch/cern50/events/Fireworks/Fireworks-en.html. At the end of the Festival, the CERN choir, itself celebrating its thirtieth year, joins forces with the Annecy choir Pro Musica to give a special performance of Jo...

4-Aminoquinoline derivatives

DEFF Research Database (Denmark)

Singh, Shailja; Agarwal, Drishti; Sharma, Kumkum

2016-01-01

and found them to be effective against Plasmodium falciparum under in vitro conditions. Further, we selected four most active derivatives 1m, 1o, 2c and 2j and evaluated their antimalarial potential against Plasmodium berghei in vivo. These 4-aminoquinolines cured BALB/c mice infected with P. berghei......Synthetic quinoline derivatives continue to be considered as candidates for new drug discovery if they act against CQ-resistant strains of malaria even after the widespread emergence of resistance to CQ. In this study, we explored the activities of two series of new 4-aminoquinoline derivatives...... for structure activity relationship to find lead molecules for treating multidrug-resistant Plasmodium falciparum and Plasmodium vivax....

49 CFR 173.418 - Authorized packages-pyrophoric Class 7 (radioactive) materials.

Science.gov (United States)

2010-10-01

... must not be fissile unless excepted by § 173.453; (b) Contained in sealed and corrosion resistant receptacles with positive closures (friction or slip-fit covers or stoppers are not authorized); (c) Free of...

Chemistry of high-energy materials. 2. ed.

Energy Technology Data Exchange (ETDEWEB)

Klapoetke, Thomas M. [Munich Univ. (Germany). Chair of Inorganic Chemistry; Maryland Univ., College Park, MD (United States). Center of Energetic Concepts Development (CECD)

2012-07-01

This graduate-level textbook treats the basic chemistry of high energy materials - primary and secondary explosives, propellants, rocket fuel and pyrotechnics - and provides a review of new research developments. Applications in both military and civil fields are discussed. The book also offers new insights into ''green'' chemistry requirements and strategies for military applications.

Suitability of Tophet C-Alloy 52/Kovar components to hydrogen environments

International Nuclear Information System (INIS)

Gebhart, J.M.; Kelly, M.D.

1976-01-01

The suitability of Tophet C-Alloy 52/Kovar weldments to hydrogen embrittlement were investigated because of their potential as candidate materials in fabrication of minaturized initiators for pyrotechnics. Cathodic charged samples were statically loaded for extended periods of time resulting in no load failures and in ductile fracture surfaces indicating resistance to hydrogen embrittlement. 20 figures

Studies on Synthesis of Some Novel Heterocyclic Azlactone Derivatives and Imidazolinone Derivatives and their Antimicrobial Activity

Directory of Open Access Journals (Sweden)

Rakesh N. Mistry

2005-01-01

Full Text Available p - Methyl benzoic acid on reaction with phosphorus pentachloride gives p - methyl benzoyl chloride derivative which on condensation with glycine gives p - methyl benzoyl glycine derivative. Now, this p - methyl benzoyl glycine derivative on condensation with various substituted aldehydes gives corresponding substituted 4 - [aryl methylidine] - 2 - [p - methyl phenyl] - oxazole - 5 - one derivatives [1(a-j]. Further, these derivatives [1(a-j] on condensation with 4 , 4’ - diamino diphenyl sulphone gives corresponding substituted imidazolinone - dibenzsulphone derivatives [2(a-j], on condensation with 4 , 4’ - diamino diphenyl methane gives corresponding substituted imidazolinone - dibenzmethane derivatives [3(a-j], on condensation with 4,4’- diamino benzanilide gives corresponding substituted imidazolinone - benzanilide derivatives [4(a-j] and on condensation with 2 - amino pyridine gives corresponding substituted imidazolinone - pyridine derivatives [5(a-j] respectively. Structure elucidation of synthesised compounds has been made on the basis of elemental analysis, I.R. spectral studies and 1H N.M.R. spectral studies. The antimicrobial activity of the synthesised compounds has been studied against the cultures “Staphylococcus aureus”, “Escherichia coli” and “Candela albicans”.

Effect of chondrocyte-derived early extracellular matrix on chondrogenesis of placenta-derived mesenchymal stem cells.

Science.gov (United States)

Park, Yong-Beom; Seo, Sinji; Kim, Jin-A; Heo, Jin-Chul; Lim, Young-Cheol; Ha, Chul-Won

2015-06-24

The extracellular matrix (ECM) surrounding cells contains a variety of proteins that provide structural support and regulate cellular functions. Previous studies have shown that decellularized ECM isolated from tissues or cultured cells can be used to improve cell differentiation in tissue engineering applications. In this study we evaluated the effect of decellularized chondrocyte-derived ECM (CDECM) on the chondrogenesis of human placenta-derived mesenchymal stem cells (hPDMSCs) in a pellet culture system. After incubation with or without chondrocyte-derived ECM in chondrogenic medium for 1 or 3 weeks, the sizes and wet masses of the cell pellets were compared with untreated controls (hPDMSCs incubated in chondrogenic medium without chondrocyte-derived ECM). In addition, histologic analysis of the cell pellets (Safranin O and collagen type II staining) and quantitative reverse transcription-PCR analysis of chondrogenic markers (aggrecan, collagen type II, and SOX9) were carried out. Our results showed that the sizes and masses of hPDMSC pellets incubated with chondrocyte-derived ECM were significantly higher than those of untreated controls. Differentiation of hPDMSCs (both with and without chondrocyte-derived ECM) was confirmed by Safranin O and collagen type II staining. Chondrogenic marker expression and glycosaminoglycan (GAG) levels were significantly higher in hPDMSC pellets incubated with chondrocyte-derived ECM compared with untreated controls, especially in cells precultured with chondrocyte-derived ECM for 7 d. Taken together, these results demonstrate that chondrocyte-derived ECM enhances the chondrogenesis of hPDMSCs, and this effect is further increased by preculture with chondrocyte-derived ECM. This preculture method for hPDMSC chondrogenesis represents a promising approach for cartilage tissue engineering.

Energy derivatives, experiences in derivative trading from the natural gas industry : back to basics

International Nuclear Information System (INIS)

Dittmer, G.; Coyle, T.

1998-01-01

Some basic facts regarding derivatives in the electric power industry were discussed based on experiences in the natural gas industry. Derivatives were described as financial instruments that have no value of their own but derive their value from other assets, such as commodities. Futures and Options are the two forms of derivatives. Electricity as a commodity was characterized, and a historical parallel was drawn between deregulation in the natural gas and electric power industry. Short term and long term factors impacting the market and market dynamics impacting derivatives were identified. The latter include: (1) volatility, (2) liquidity, (3) correlations, and (4) price discovery. In contrast to the natural gas market, the electricity market is considered as lacking liquidity and in need of moving farther along the maturity timeline. The question of natural gas/ electricity convergence was also addressed refs., tabs., figs

Synthesis of samarium, europium and ytterbium acetylenides

International Nuclear Information System (INIS)

Bochkarev, M.N.; Fedorova, E.A.; Glushkova, N.V.; Protchenko, A.V.; Druzhkov , O.N.; Khorshev, S.Ya.

1995-01-01

Ethynyl complexes of samarium, europium and ytterbium were prepared by interaction of naphthalinides of metals with acetylene in tetrahydrofuran. The compounds are isolated in the form of dark-coloured pyrophore powders. Data of magnetic measurements suggest that in the course of the reaction Sm(2) is oxidized completely to Sm(3), Yb(2) transforms into Yb(3) partially, whereas europium preserves its initial bivalent state. Hydrolysis of the compounds prepared provides acetylene, ethylene, ethane and hydrogen which indicates the presence of acethylenide Ln 2 C 2 and hydride LnH groupings (Ln = Sm, Eu, Yb). 9 refs., 2 tabs

Stabilization of low-level mixed waste in chemically bonded phosphate ceramics

International Nuclear Information System (INIS)

Wagh, A.S.; Singh, D.; Sarkar, A.V.

1994-06-01

Mixed waste streams, which contain both chemical and radioactive wastes, are one of the important categories of DOE waste streams needing stabilization for final disposal. Recent studies have shown that chemically bonded phosphate ceramics may have the potential for stabilizing these waste streams, particularly those containing volatiles and pyrophorics. Such waste streams cannot be stabilized by conventional thermal treatment methods such as vitrification. Phosphate ceramics may be fabricated at room temperature into durable, hard and dense materials. For this reason room-temperature-setting phosphate ceramic waste forms are being developed to stabilize these to ''problem waste streams.''

A New Grünwald-Letnikov Derivative Derived from a Second-Order Scheme

Directory of Open Access Journals (Sweden)

B. A. Jacobs

2015-01-01

Full Text Available A novel derivation of a second-order accurate Grünwald-Letnikov-type approximation to the fractional derivative of a function is presented. This scheme is shown to be second-order accurate under certain modifications to account for poor accuracy in approximating the asymptotic behavior near the lower limit of differentiation. Some example functions are chosen and numerical results are presented to illustrate the efficacy of this new method over some other popular choices for discretizing fractional derivatives.

Structure activity relationships of quinoxalin-2-one derivatives as platelet-derived growth factor-beta receptor (PDGFbeta R) inhibitors, derived from molecular modeling.

Science.gov (United States)

Mori, Yoshikazu; Hirokawa, Takatsugu; Aoki, Katsuyuki; Satomi, Hisanori; Takeda, Shuichi; Aburada, Masaki; Miyamoto, Ken-ichi

2008-05-01

We previously reported a quinoxalin-2-one compound (Compound 1) that had inhibitory activity equivalent to existing platelet-derived growth factor-beta receptor (PDGFbeta R) inhibitors. Lead optimization of Compound 1 to increase its activity and selectivity, using structural information regarding PDGFbeta R-ligand interactions, is urgently needed. Here we present models of the PDGFbeta R kinase domain complexed with quinoxalin-2-one derivatives. The models were constructed using comparative modeling, molecular dynamics (MD) and ligand docking. In particular, conformations derived from MD, and ligand binding site information presented by alpha-spheres in the pre-docking processing, allowed us to identify optimal protein structures for docking of target ligands. By carrying out molecular modeling and MD of PDGFbeta R in its inactive state, we obtained two structural models having good Compound 1 binding potentials. In order to distinguish the optimal candidate, we evaluated the structural activity relationships (SAR) between the ligand-binding free energies and inhibitory activity values (IC50 values) for available quinoxalin-2-one derivatives. Consequently, a final model with a high SAR was identified. This model included a molecular interaction between the hydrophobic pocket behind the ATP binding site and the substitution region of the quinoxalin-2-one derivatives. These findings should prove useful in lead optimization of quinoxalin-2-one derivatives as PDGFb R inhibitors.

12 CFR 403.4 - Derivative classification.

Science.gov (United States)

2010-01-01

... SAFEGUARDING OF NATIONAL SECURITY INFORMATION § 403.4 Derivative classification. (a) Use of derivative classification. (1) Unlike original classification which is an initial determination, derivative classification... 12 Banks and Banking 4 2010-01-01 2010-01-01 false Derivative classification. 403.4 Section 403.4...

Amphetamine derivative related deaths.

Science.gov (United States)

Lora-Tamayo, C; Tena, T; Rodríguez, A

1997-02-28

Amphetamine its methylendioxy (methylendioxyamphetamine methylenedioxymethylamphetamine, methylenedioxyethylamphetamine) and methoxy derivatives (p-methoxyamphetamine and p-methoxymethylamphetamine) are widely abused in Spanish society. We present here the results of a systematic study of all cases of deaths brought to the attention of the Madrid department of the Instituto Nacional de Toxicologia from 1993 to 1995 in which some of these drugs have been found in the cadaveric blood. The cases were divided into three categories: amphetamine and derivatives, amphetamines and alcohol, amphetamines and other drugs. Data on age, sex, clinical symptoms, morphological findings, circumstances of death, when known, and concentration of amphetamine derivatives, alcohol and other drugs in blood are given for each group. The information provided here may prove to be useful for the forensic interpretation of deaths which are directly or indirectly related to abuse of amphetamine derivatives.

Isotope-labelled folic acid derivatives

International Nuclear Information System (INIS)

Lewin, N.; Wong, E.T.

1976-01-01

The suggestion deals with the production of folic acid derivatives suitable as indicators or tracers for analyses of serum folates. These folic acid derivatives contain folic acid which is bound by one or both carboxyl groups to the amino nitrogen of compounds such as, e.g., tyramine, glycyl tyrosine, tyrosine, or the methyl ester of tyrosine. The derivative obtained can be substituted by a gamma emitter, e.g. the iodine isotope I 125. The radioactive derivative is used in the method for the competitive protein bonding to determine endogenic folates in the serum. (UWI) [de

Performance of small-scale aero-derivative industrial gas turbines derived from helicopter engines

Directory of Open Access Journals (Sweden)

Barinyima Nkoi

2013-12-01

Full Text Available This paper considers comparative assessment of simple and advanced cycle small-scale aero-derivative industrial gas turbines derived from helicopter engines. More particularly, investigation was made of technical performance of the small-scale aero-derivative engine cycles based on existing and projected cycles for applications in industrial power generation, combined heat and power concept, rotating equipment driving, and/or allied processes. The investigation was done by carrying out preliminary design and performance simulation of a simple cycle (baseline two-spool small-scale aero-derivative turboshaft engine model, and some advanced counterpart aero-derivative configurations. The advanced configurations consist of recuperated and intercooled/recuperated engine cycles of same nominal power rating of 1.567 MW. The baseline model was derived from the conversion of an existing helicopter engine model. In doing so, design point and off-design point performances of the engine models were established. In comparing their performances, it was observed that to a large extent, the advanced engine cycles showed superior performance in terms of thermal efficiency, and specific fuel consumption. In numerical terms, thermal efficiencies of recuperated engine cycle, and intercooled/recuperated engine cycles, over the simple cycle at DP increased by 13.5%, and 14.5% respectively, whereas specific fuel consumption of these cycles over simple cycle at DP decreased by 12.5%, and 13% respectively. This research relied on open access public literature for data.

Pyrotechnically Generated and Disseminated Aerosol for Bioagent Defeat

Science.gov (United States)

2016-12-01

blend), aluminum, copper, iron, and ferrotitanium (an iron/ titanium blend) provides an additional layer of antimicrobial effect because each of these...Free Trade Agreements program. The work was started in October 2014 and completed in January 2016. The use of either trade or manufacturers ’ names...perform the same amount of decontamination; are lower in toxicity; require no additional equipment to operate; and are small, man-portable devices

Alternatives to Pyrotechnic Distress Signals; Additional Signal Evaluation

Science.gov (United States)

2017-06-01

device performance standard that addresses Coast Guard project sponsor and stakeholders needs. 17. Key Words Visual Distress Signal Device (VDSD...devices. The report discussed the concept of “effective intensity,” as used by the International Association of Marine Aids to Navigation and Lighthouse...efficacy of Cyan as a signal color. In order to move forward, the RDC project team met with CG-ENG-4 and other Coast Guard stakeholders (Offices of

Suitability of Potential Alternatives to Pyrotechnic Distress Signals

Science.gov (United States)

2012-02-01

the following convolution : )()()( tqtIti  Equation (1) Given that  2 )( ta a tq   Equation (2) Where a = 0.2 for night time use...military five-finger gloves, equipped with a three-layer laminate insert. The back of the gloves is made from five-color camouflage fabric; the

Data Collection using the MetalMapper in Dynamic Data Acquisition and Cued Modes

Science.gov (United States)

2017-07-01

Control EM electromagnetic ESTCP Environmental Security Technology Certification Program FM titanium tetrachloride ft foot/feet GPS global...electromagnetic ( EM ) induction sensor array showing the position of the four sensors is also illustrated. The orientation of the sensor cubes are indicated...land mines, pyrotechnics, bombs , and demolition materials. Surface sweeps identified MEC items throughout Units 11 and 12, including 37mm, 40mm

Department of the Navy (DON) Additive Manufacturing (AM) Implementation Plan V2.0 (2017)

Science.gov (United States)

2017-05-04

aligned to advance AM of explosives, propellants, pyrotechnics and structures.  Makerspaces deployed throughout the warfighter and civilian communities...to conduct broad AM familiarization training and STEM activities 2. Introduce new makerspaces into DON to expand access and education of AM...technologies 3. Ensure makerspaces become a vital part of workforce training by developing communication plan to inform leadership of current and future

Things That Go Boom!: Noise and Toxic Exposures Associated with Weapon Systems

Science.gov (United States)

2010-06-17

Munitions Pyrotechnics Tracers Spot ing Charges Oxidizers Delay Elements Propellatl s Fuses De· onators Pr~n1ers Constituent of Concern BariL ...r11 chromate Potassium perchlorate lead oxide BariL m chromate P a tass ~L m perch I o r,ate l e ad chromate An1n1onil tll perch lara e P a

Gunner's Mate G 3 and 2; Rate Training Manual. Revised.

Science.gov (United States)

Naval Education and Training Command, Pensacola, FL.

The rate training manual has been prepared for men of the regular Navy and of the Naval Reserve for the purpose of advancement to increase knowledge in the various aspects of the Gunner's Mate rating (G 3 and 2). Chapters 1 through 14 deal with the following topics: the requirements of the Gunner's Mate G Rating, explosives and pyrotechnics,…

Gorenstein derived functions

DEFF Research Database (Denmark)

Holm, Henrik Granau

2004-01-01

Over any associative ring R it is standard to derive HomR(􀀀;􀀀) using projective resolutions in the rst variable, or injective resolutions in the second variable, and doing this, one obtains Extn R(􀀀;􀀀) in both cases. We examine the situation where projective...... and injective modules are replaced by Gorenstein projective and Gorenstein injective ones, respectively. Furthermore, we derive the tensor product 􀀀 R 􀀀 using Gorenstein at modules....

Financial Derivatives in China

Institute of Scientific and Technical Information of China (English)

无

2006-01-01

Francis Repka sees bright prospects for the future development of the financial derivatives market in China. Repka,Vice President of the Asian Bond Finance Department of Societe Generale, says the situation in France just after the birth of derivatives was very similar to the situation in China today.

Derivative spectrophotometry of cobalt alloys

International Nuclear Information System (INIS)

Spitsyn, P.K.

1985-01-01

The method of derivative spectrophotometry is briefly described, and derivative absorption spectra are presented for samarium, cobalt, and commercial Sm-Co alloys. It is shown that the use of derivative spectrophotometry not only improves the accuracy and selectivity of element determinations but also simplifies the analysis of alloys. Results of a statistical evaluation of the metrological characteristics of the analytical procedure described here are presented. 8 references

Superstability for Generalized Module Left Derivations and Generalized Module Derivations on a Banach Module (I

Directory of Open Access Journals (Sweden)

Huai-Xin Cao

2009-01-01

Full Text Available We discuss the superstability of generalized module left derivations and generalized module derivations on a Banach module. Let 𝒜 be a Banach algebra and X a Banach 𝒜-module, f:X→X and g:𝒜→𝒜. The mappings Δf,g1, Δf,g2, Δf,g3, and Δf,g4 are defined and it is proved that if ∥Δf,g1(x,y,z,w∥ (resp., ∥Δf,g3(x,y,z,w,α,β∥ is dominated by φ(x,y,z,w, then f is a generalized (resp., linear module-𝒜 left derivation and g is a (resp., linear module-X left derivation. It is also shown that if ∥Δf,g2(x,y,z,w∥ (resp., ∥Δf,g4(x,y,z,w,α,β∥ is dominated by φ(x,y,z,w, then f is a generalized (resp., linear module-𝒜 derivation and g is a (resp., linear module-X derivation.

Risk and Derivative Price

OpenAIRE

Yusuke Osaki

2007-01-01

We consider an asset market traded three types of assets: the risk–free asset, the market portfolio and derivatives written on the market portfolio return. We determine a sufficient condition to guarantee that noise risk monotonically changes their derivatives. The condition is that Arrow–Pratt absolute risk aversion is decreasing and convex.

Neutron radiography in Indian space programme

International Nuclear Information System (INIS)

Viswanathan, K.

1999-01-01

Pyrotechnic devices are indispensable in any space programme to perform such critical operations as ignition, stage separation, solar panel deployment, etc. The nature of design and configuration of different types of pyrotechnic devices, and the type of materials that are put in their construction make the inspection of them with thermal neutrons more favourable than any other non destructive testing methods. Although many types of neutron sources are available for use, generally the radiographic quality/exposure duration and cost of source run in opposite directions even after four decades of research and development. But in the area of space activity, by suitably combining the X-ray and neutron radiographic requirements, the inspection of the components can be made economically viable. This is demonstrated in the Indian space programme by establishing a 15 MeV linear accelerator based neutron generator facility to inspect medium to giant solid propellant boosters by X-ray inspection and all types of critical pyro and some electronic components by neutron radiography. Since the beam contains unacceptable gamma, transfer imaging technique has been evolved and the various parameters have been optimised to get a good quality image

Environmentally benign destruction of waste energetic materials (EMs)

International Nuclear Information System (INIS)

Schneider, R. L.; Donahue, B. A.

1998-01-01

Studies by the U. S. Army Corps of Engineers during 1991-1997 involving various methods for the destruction of waste generated by pyrotechnic, explosive and propellant materials are described. The methods assessed and evaluated include controlled incineration (CI), wet air oxidation (WAO), and hydrothermal oxidation (HTO), using a U.S. Army triple-base propellant as the initial common standard for all destructor comparative testing. All three of these methods has special feed line restrictions requiring mechanical diminution and comminution of the energetic material which, for safety reasons, cannot be used with contaminated heterogeneous production wastes. Supercritical fluid extraction with carbon dioxide, alkaline hydrolysis, electrolysis and fluid cutting with very high pressure water jets and liquid nitrogen are alternate technologies that were evaluated as pre-treatment for production wastes. Wet air oxidation and electrochemical reduction studies were conducted using the U.S. Navy double propellant NOSIH-AA2, which contains a lead-based ballistic modifier. Wet air oxidation and hydrothermal oxidation studies were done using potassium dinitramide phase-stabilized nitrate as an oxidizer. All of these technologies are considered to be suitable for the environmentally benign destruction of pyrotechnic materials, including fireworks. 17 refs., 8 tabs., 4 figs

Asymptotic aspect of derivations in Banach algebras

Directory of Open Access Journals (Sweden)

Jaiok Roh

2017-02-01

Full Text Available Abstract We prove that every approximate linear left derivation on a semisimple Banach algebra is continuous. Also, we consider linear derivations on Banach algebras and we first study the conditions for a linear derivation on a Banach algebra. Then we examine the functional inequalities related to a linear derivation and their stability. We finally take central linear derivations with radical ranges on semiprime Banach algebras and a continuous linear generalized left derivation on a semisimple Banach algebra.

5 CFR 1312.7 - Derivative classification.

Science.gov (United States)

2010-01-01

..., DOWNGRADING, DECLASSIFICATION AND SAFEGUARDING OF NATIONAL SECURITY INFORMATION Classification and Declassification of National Security Information § 1312.7 Derivative classification. A derivative classification... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Derivative classification. 1312.7 Section...

Optimal economic order quantity for buyer-distributor-vendor supply chain with backlogging derived without derivatives

Science.gov (United States)

Teng, Jinn-Tsair; Cárdenas-Barrón, Leopoldo Eduardo; Lou, Kuo-Ren; Wee, Hui Ming

2013-05-01

In this article, we first complement an inappropriate mathematical error on the total cost in the previously published paper by Chung and Wee [2007, 'Optimal the Economic Lot Size of a Three-stage Supply Chain With Backlogging Derived Without Derivatives', European Journal of Operational Research, 183, 933-943] related to buyer-distributor-vendor three-stage supply chain with backlogging derived without derivatives. Then, an arithmetic-geometric inequality method is proposed not only to simplify the algebraic method of completing prefect squares, but also to complement their shortcomings. In addition, we provide a closed-form solution to integral number of deliveries for the distributor and the vendor without using complex derivatives. Furthermore, our method can solve many cases in which their method cannot, because they did not consider that a squared root of a negative number does not exist. Finally, we use some numerical examples to show that our proposed optimal solution is cheaper to operate than theirs.

Asia Pacific energy derivatives

International Nuclear Information System (INIS)

Fusaro, P.C.

1997-09-01

Asia Pacific Energy Derivatives, from FT Energy, is the first report of its kind to examine the growth of energy derivatives within Asia Pacific and their increasing importance within this region. It provides a comprehensive overview of the subject, including analysis of: deregulation as a market driver; the impact of privatisation; the future for energy risk management tools; the unique characteristics of the Asia Pacific energy market; the role of futures exchanges in Asia; existing indexes and their performance; the differences between the Asia Pacific markets and their more mature counterparts in London and New York; non-oil derivatives, project finance and cross commodity arbitrage; the thriving Pacific Rim Over the Counter (OTC) markets. (author)

DEVELOPMENT OF DERIVATIVE MARKET IN 2000-2012

Directory of Open Access Journals (Sweden)

Evgeniya V. Vasina

2014-01-01

Full Text Available At the end of XIX century futures exchange emerged, in the early 70-ies XX century - option exchange of financial derivatives. These exchanges gave a huge boost to the development of market of the operations with derivative financial instruments. In fact, in the 1970-1980-ies a new market segment was actually formed - the stock and financial derivatives. Trade in financial derivatives began in the OTC market, which accounts for most of the trade of derivatives. Today volumes of the OTC market of derivatives are several times greater than the volume of world trade and world GDP. From 2000 to 2007 derivative OTC market grew rapidly. In 2007-2008 there is a decline in trade of derivatives, but already in 2009 the world market of OTC derivatives returned to pre-crisis growth rates. Among all the instruments of the OTC market of derivatives swaps on interest rates stand out in the volumes, which even in the crisis of2007-2008 slightly, but increased. Analysis of indicators of the global OTC market of derivatives reveals the predominance of instruments on interest rates: their share in the total world market in 2012 amounted to about 77%. If we consider the structure of the OTC market of derivatives on type contracts, in 2012 most of the contracts (66% belonged to the swaps. As regards the structure of the world market of exchange derivatives, in 2012 the options had the largest share - 54 %, futures accounted for 46 %. Among all the exchange instruments on interest rates held 92%.

Development Of Derivative Market In 2000-2012

Directory of Open Access Journals (Sweden)

Evgeniya V. Vasina

2014-01-01

Full Text Available At the end of XIX century futures exchange emerged, in the early 70-ies XX century - option exchange of financial derivatives. These exchanges gave a huge boost to the development of market of the operations with derivative financial instruments. In fact, in the 1970-1980-ies a new market segment was actually formed - the stock and financial derivatives. Trade in financial derivatives began in the OTC market, which accounts for most of the trade of derivatives. Today volumes of the OTC market of derivatives are several times greater than the volume of world trade and world GDP. From 2000 to 2007 derivative OTC market grew rapidly. In 2007-2008 there is a decline in trade of derivatives, but already in 2009 the world market of OTC derivatives returned to pre-crisis growth rates. Among all the instruments of the OTC market of derivatives swaps on interest rates stand out in the volumes, which even in the crisis of2007-2008 slightly, but increased. Analysis of indicators of the global OTC market of derivatives reveals the predominance of instruments on interest rates: their share in the total world market in 2012 amounted to about 77%. If we consider the structure of the OTC market of derivatives on type contracts, in 2012 most of the contracts (66% belonged to the swaps. As regards the structure of the world market of exchange derivatives, in 2012 the options had the largest share - 54 %, futures accounted for 46 %. Among all the exchange instruments on interest rates held 92%.

The combinatorial derivation

Directory of Open Access Journals (Sweden)

Igor V. Protasov

2013-09-01

$\\Delta(A=\\{g\\in G:|gA\\cap A|=\\infty\\}$. The mapping $\\Delta:\\mathcal{P}_G\\rightarrow\\mathcal{P}_G$, $A\\mapsto\\Delta(A$, is called a combinatorial derivation and can be considered as an analogue of the topological derivation $d:\\mathcal{P}_X\\rightarrow\\mathcal{P}_X$, $A\\mapsto A^d$, where $X$ is a topological space and $A^d$ is the set of all limit points of $A$. Content: elementary properties, thin and almost thin subsets, partitions, inverse construction and $\\Delta$-trajectories,  $\\Delta$ and $d$.

22 CFR 9.6 - Derivative classification.

Science.gov (United States)

2010-04-01

... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Derivative classification. 9.6 Section 9.6 Foreign Relations DEPARTMENT OF STATE GENERAL SECURITY INFORMATION REGULATIONS § 9.6 Derivative classification. (a) Definition. Derivative classification is the incorporating, paraphrasing, restating or...

Clearing and settlement of exchange traded derivatives

OpenAIRE

John McPartland

2009-01-01

Derivatives are a class of financial instruments that derive their value from some underlying commodity, security, index, or other asset. Futures and options are common forms of derivatives. This article explains how clearing and settlement systems for exchange traded derivatives work.

6 CFR 7.26 - Derivative classification.

Science.gov (United States)

2010-01-01

... 6 Domestic Security 1 2010-01-01 2010-01-01 false Derivative classification. 7.26 Section 7.26 Domestic Security DEPARTMENT OF HOMELAND SECURITY, OFFICE OF THE SECRETARY CLASSIFIED NATIONAL SECURITY INFORMATION Classified Information § 7.26 Derivative classification. (a) Derivative classification is defined...

DEMONSTRATION REPORT: Demonstration of Advanced Geophysics and Classification Technologies on Munitions Response Sites Former Fort Ord, Monterey County, CA

Science.gov (United States)

2017-06-01

DGM Digital Geophysical Mapping DTSC California Department of Toxic Substances Control EM Electromagnetic EPA U.S. Environmental...land mines, pyrotechnics, bombs , and demolition materials. Surface sweeps identified MEC items throughout Units 11 and 12, including 37mm, 40mm, 57mm...electromagnetic ( EM ) data are being collected. If no GPS readings are collected during that period, the most recent GPS position and the platform

Fractional derivatives. An introduction; Derivate frazionarie. Che cosa sono, a cosa servono

Energy Technology Data Exchange (ETDEWEB)

Dattoli, G. [ENEA, Div. Fisica Applicata, Centro Ricerche Frascati, Rome (Italy)

2001-07-01

In this item is presented a brief survey of fractional calculus and of the relevant applications. In the work are discussed different points of view of the operation of fractional derivative and present a unifying definition. The role played by fractional derivatives and integrals within the framework of integral transform is analyzed. [Italian] In questo articolo si traccia un profilo del cosidetto calcolo frazionario e delle relative applicazioni a problemi di matematica pura ed applicata. Si discutono varie definizioni dell'operazione di derivata frazionaria, non tutte coincidenti fra loro, e si mostra come sia possibile proporre una definizione univoca che inglobi tutte le altre. Si analizza infine il ruolo giocato dalle derivate e dagli integrali frazionari e, piu' in generale, quello degli operatori differenziali ad esponente frazionario, nell'ambito della teoria delle rappresentazioni integrali.

45 CFR 601.5 - Derivative classification.

Science.gov (United States)

2010-10-01

... CLASSIFICATION AND DECLASSIFICATION OF NATIONAL SECURITY INFORMATION § 601.5 Derivative classification. Distinct... 45 Public Welfare 3 2010-10-01 2010-10-01 false Derivative classification. 601.5 Section 601.5... classification guide, need not possess original classification authority. (a) If a person who applies derivative...

40 CFR 721.1820 - Bisphenol derivative.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Bisphenol derivative. 721.1820 Section... Substances § 721.1820 Bisphenol derivative. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as bisphenol derivative (PMN No. P-92-509) is...

12 CFR 563.172 - Financial derivatives.

Science.gov (United States)

2010-01-01

... underlying assets, indices, or reference rates. The most common types of financial derivatives are futures, forward commitments, options, and swaps. A mortgage derivative security, such as a collateralized mortgage... 12 Banks and Banking 5 2010-01-01 2010-01-01 false Financial derivatives. 563.172 Section 563.172...

Development trends of the international derivatives market

OpenAIRE

Motorniuk, U.; Terebukh, M.; Kharchuk, V.

2016-01-01

The factors forming international derivatives market trends are researched in this article. The history of the formation of the global derivatives market was analyzed, in particular, events which have led to the growth of the derivatives market. Global derivatives market has revealed major changes in its trends and witnessed the gradual transformation of its structure, observed in recent years. Global derivatives market has revealed major changes in its trends and witnessed the gradual transf...

Stability of gas atomized reactive powders through multiple step in-situ passivation

Science.gov (United States)

Anderson, Iver E.; Steinmetz, Andrew D.; Byrd, David J.

2017-05-16

A method for gas atomization of oxygen-reactive reactive metals and alloys wherein the atomized particles are exposed as they solidify and cool in a very short time to multiple gaseous reactive agents for the in-situ formation of a protective reaction film on the atomized particles. The present invention is especially useful for making highly pyrophoric reactive metal or alloy atomized powders, such as atomized magnesium and magnesium alloy powders. The gaseous reactive species (agents) are introduced into the atomization spray chamber at locations downstream of a gas atomizing nozzle as determined by the desired powder or particle temperature for the reactions and the desired thickness of the reaction film.

Hazardous waste treatment facility and skid-mounted treatment systems at Los Alamos

International Nuclear Information System (INIS)

Lussiez, G.W.; Zygmunt, S.J.

1993-01-01

To centralize treatment, storage, and staging areas for hazardous wastes, Los Alamos National Laboratory has designed a 12,000-ft 2 hazardous waste treatment facility. The facility will house a treatment room for each of four kinds of wastes: nonradioactive characteristic wastes, nonradioactive listed wastes radioactive characteristic wastes, and radioactive listed wastes. The facility will be used for repacking labpacks, bulking small organic waste volumes, processing scintillation vials, treating reactives such as lithium hydride and pyrophoric uranium, treating contaminated solids such as barium sand, and treating plating wastes. The treated wastes will then be appropriately disposed of. This report describes the integral features of the hazardous waste treatment facility

Do measures matter? Comparing surface-density-derived and census-tract-derived measures of racial residential segregation

Directory of Open Access Journals (Sweden)

Waller Lance A

2010-06-01

Full Text Available Abstract Background Racial residential segregation is hypothesized to affect population health by systematically patterning health-relevant exposures and opportunities according to individuals' race or income. Growing interest into the association between residential segregation and health disparities demands more rigorous appraisal of commonly used measures of segregation. Most current studies rely on census tracts as approximations of the local residential environment when calculating segregation indices of either neighborhoods or metropolitan areas. Because census tracts are arbitrary in size and shape, reliance on this geographic scale limits understanding of place-health associations. More flexible, explicitly spatial derivations of traditional segregation indices have been proposed but have not been compared with tract-derived measures in the context of health disparities studies common to social epidemiology, health demography, or medical geography. We compared segregation measured with tract-derived as well as GIS surface-density-derived indices. Measures were compared by region and population size, and segregation measures were linked to birth record to estimate the difference in association between segregation and very preterm birth. Separate analyses focus on metropolitan segregation and on neighborhood segregation. Results Across 231 metropolitan areas, tract-derived and surface-density-derived segregation measures are highly correlated. However overall correlation obscures important differences by region and metropolitan size. In general the discrepancy between measure types is greatest for small metropolitan areas, declining with increasing population size. Discrepancies in measures are greatest in the South, and smallest in Western metropolitan areas. Choice of segregation index changed the magnitude of the measured association between segregation and very preterm birth. For example among black women, the risk ratio for very

32 CFR 2400.16 - Derivative classification markings.

Science.gov (United States)

2010-07-01

... SECURITY PROGRAM Derivative Classification § 2400.16 Derivative classification markings. (a) Documents... 32 National Defense 6 2010-07-01 2010-07-01 false Derivative classification markings. 2400.16..., as described in § 2400.12 of this part, the information may not be used as a basis for derivative...

Push-outs of derivations

Indian Academy of Sciences (India)

extension as a limit of operators b ↦→ D(ba) − b.D(a), a ∈ A in an appropriate operator topology, the main point in the proof being to show that the limit map is in fact a derivation. In this paper we make clear which part of this approach is analytic and which algebraic by presenting an algebraic scheme that gives derivations ...

MODERN TRENDS OF DEVELOPMENT OF INTERNATIONAL DERIVATIVES MARKET

Directory of Open Access Journals (Sweden)

V. Shelydko

2014-09-01

Full Text Available Article is devoted to analysis of structure and peculiarities of development of the international derivatives market. The history of formation of the international derivatives market is investigated. The nature, functions and advantages of use of derivatives, and also their role in the modern international securities market are defined. Classification of financial derivatives is considered. Product lines of financial derivatives are analyzed. The regional structure of the international derivatives market and dynamics of its development are investigated. The comparative characteristic of volumes and structure of exchange and over-the-counter segments of international derivatives market are carried out. Dynamics and structure of international markets of interest-bearing derivatives and currency derivatives are analyzed. The fundamental trends of development of the modern international derivatives market are defined.

INTEGRATION OF IMAGE-DERIVED AND POS-DERIVED FEATURES FOR IMAGE BLUR DETECTION

Directory of Open Access Journals (Sweden)

T.-A. Teo

2016-06-01

Full Text Available The image quality plays an important role for Unmanned Aerial Vehicle (UAV’s applications. The small fixed wings UAV is suffering from the image blur due to the crosswind and the turbulence. Position and Orientation System (POS, which provides the position and orientation information, is installed onto an UAV to enable acquisition of UAV trajectory. It can be used to calculate the positional and angular velocities when the camera shutter is open. This study proposes a POS-assisted method to detect the blur image. The major steps include feature extraction, blur image detection and verification. In feature extraction, this study extracts different features from images and POS. The image-derived features include mean and standard deviation of image gradient. For POS-derived features, we modify the traditional degree-of-linear-blur (blinear method to degree-of-motion-blur (bmotion based on the collinear condition equations and POS parameters. Besides, POS parameters such as positional and angular velocities are also adopted as POS-derived features. In blur detection, this study uses Support Vector Machines (SVM classifier and extracted features (i.e. image information, POS data, blinear and bmotion to separate blur and sharp UAV images. The experiment utilizes SenseFly eBee UAV system. The number of image is 129. In blur image detection, we use the proposed degree-of-motion-blur and other image features to classify the blur image and sharp images. The classification result shows that the overall accuracy using image features is only 56%. The integration of image-derived and POS-derived features have improved the overall accuracy from 56% to 76% in blur detection. Besides, this study indicates that the performance of the proposed degree-of-motion-blur is better than the traditional degree-of-linear-blur.

Risk management, derivatives and shariah compliance

Science.gov (United States)

Bacha, Obiyathulla Ismath

2013-04-01

Despite the impressive growth of Islamic Banking and Finance (IBF), a number of weaknesses remain. The most important of this is perhaps the lack of shariah compliant risk management tools. While the risk sharing philosophy of Islamic Finance requires the acceptance of risk to justify returns, the shariah also requires adherents to avoid unnecessary risk-maysir. The requirement to avoid maysir is in essence a call for the prudent management of risk. Contemporary risk management revolves around financial engineering, the building blocks of which are financial derivatives. Despite the proven efficacy of derivatives in the management of risk in the conventional space, shariah scholars appear to be suspicious and uneasy with their use in IBF. Some have imposed outright prohibition of their use. This paper re-examines the issue of contemporary derivative instruments and shariah compliance. The shariah compatibility of derivatives is shown in a number of ways. First, by way of qualitative evaluation of whether derivatives can be made to comply with the key prohibitions of the sharia. Second, by way of comparing the payoff profiles of derivatives with risk sharing finance and Bai Salam contracts. Finally, the equivalence between shariah compliant derivatives like the IPRS and Islamic FX Currency Forwards with conventional ones is presented.

Development of Derivatives Reporting

OpenAIRE

Pejčochová, Kristina

2012-01-01

This thesis aims to summarise the theoretical principles, concepts and considerations pertaining to accounting for and reporting of derivatives and to describe and analyse the development of major accounting standards dealing with related issues. Sections 1 and 2 provide a basic overview of derivative instruments'categorisation, mechanics, valuation and uses. Section 3 studies the principles that ensure the provision of useful financial information, with specific focus on financial instrument...

Quantum derivatives and the Schroedinger equation

International Nuclear Information System (INIS)

Ben Adda, Faycal; Cresson, Jacky

2004-01-01

We define a scale derivative for non-differentiable functions. It is constructed via quantum derivatives which take into account non-differentiability and the existence of a minimal resolution for mean representation. This justify heuristic computations made by Nottale in scale-relativity. In particular, the Schroedinger equation is derived via the scale-relativity principle and Newton's fundamental equation of dynamics

32 CFR 2400.14 - Use of derivative classification.

Science.gov (United States)

2010-07-01

... SECURITY PROGRAM Derivative Classification § 2400.14 Use of derivative classification. (a) Derivative... 32 National Defense 6 2010-07-01 2010-07-01 false Use of derivative classification. 2400.14... person who applies derivative classification markings believes that the paraphrasing, restating, or...

Generalized Fractional Derivative Anisotropic Viscoelastic Characterization

Directory of Open Access Journals (Sweden)

Harry H. Hilton

2012-01-01

Full Text Available Isotropic linear and nonlinear fractional derivative constitutive relations are formulated and examined in terms of many parameter generalized Kelvin models and are analytically extended to cover general anisotropic homogeneous or non-homogeneous as well as functionally graded viscoelastic material behavior. Equivalent integral constitutive relations, which are computationally more powerful, are derived from fractional differential ones and the associated anisotropic temperature-moisture-degree-of-cure shift functions and reduced times are established. Approximate Fourier transform inversions for fractional derivative relations are formulated and their accuracy is evaluated. The efficacy of integer and fractional derivative constitutive relations is compared and the preferential use of either characterization in analyzing isotropic and anisotropic real materials must be examined on a case-by-case basis. Approximate protocols for curve fitting analytical fractional derivative results to experimental data are formulated and evaluated.

Sol-gel derived sorbents

Science.gov (United States)

Sigman, Michael E.; Dindal, Amy B.

2003-11-11

Described is a method for producing copolymerized sol-gel derived sorbent particles for the production of copolymerized sol-gel derived sorbent material. The method for producing copolymerized sol-gel derived sorbent particles comprises adding a basic solution to an aqueous metal alkoxide mixture for a pH.ltoreq.8 to hydrolyze the metal alkoxides. Then, allowing the mixture to react at room temperature for a precalculated period of time for the mixture to undergo an increased in viscosity to obtain a desired pore size and surface area. The copolymerized mixture is then added to an immiscible, nonpolar solvent that has been heated to a sufficient temperature wherein the copolymerized mixture forms a solid upon the addition. The solid is recovered from the mixture, and is ready for use in an active sampling trap or activated for use in a passive sampling trap.

Essays on Derivatives Pricing

DEFF Research Database (Denmark)

Kokholm, Thomas

. With the existence of a liquid market for derivatives with variance as underlying, such as VIX options, VIX futures and a well-developed over-the-counter market for options on variance swaps, it is important to consider models that are able to fit these markets while consistently pricing vanilla options...... financial models, and most importantly, to be aware of their limitations. Following that belief, this thesis consists of three independent and self-contained papers, all dealing with topics in derivatives pricing. The first paper considers the pricing of traffic light options, which are appropriate...... the market for multivariate credit instruments, we take a step back and focus on single-name default modeling and introduce two new model classes for modeling of the default time of a company. Finally, in the third paper we propose a consistent pricing model for index and volatility derivatives...

Financial Derivatives (Based on Two Supports Evaluation

Directory of Open Access Journals (Sweden)

Tiberiu Socaciu

2016-07-01

Full Text Available In this paper we build a PDE like Black-Scholes equation in hypothesis of a financial derivative that is dependent on two supports (usual is dependent only on one support, like amoption based on gold, when national currency has a great float.Keywords: Financial derivatives, derivatives evaluation, derivatives based on two supports, extended Itō like lemma.

On higher derivative gravity

International Nuclear Information System (INIS)

Accioly, A.J.

1987-01-01

A possible classical route conducting towards a general relativity theory with higher-derivatives starting, in a sense, from first principles, is analysed. A completely causal vacuum solution with the symmetries of the Goedel universe is obtained in the framework of this higher-derivative gravity. This very peculiar and rare result is the first known vcuum solution of the fourth-order gravity theory that is not a solution of the corresponding Einstein's equations.(Author) [pt

Brain derived neurotrophic factor

DEFF Research Database (Denmark)

Mitchelmore, Cathy; Gede, Lene

2014-01-01

Brain Derived Neurotrophic Factor (BDNF) is a neurotrophin with important functions in neuronal development and neuroplasticity. Accumulating evidence suggests that alterations in BDNF expression levels underlie a variety of psychiatric and neurological disorders. Indeed, BDNF therapies are curre......Brain Derived Neurotrophic Factor (BDNF) is a neurotrophin with important functions in neuronal development and neuroplasticity. Accumulating evidence suggests that alterations in BDNF expression levels underlie a variety of psychiatric and neurological disorders. Indeed, BDNF therapies...

Derivation and characterization of a pig embryonic stem cell-derived exocrine pancreatic cell line

Science.gov (United States)

The establishment and initial characterization of a pig embryonic stem cell-derived pancreatic cell line, PICM-31, and a colony-cloned derivative cell line, PICM-31A, is described. The cell lines were propagated for several months at split ratios of 1:3 or 1:5 at each passage on STO feeder cells af...

51st Annual Fuze Conference

Science.gov (United States)

2007-05-27

in progress • EOD: Supportability documents submitted • AFSRB: Interim Safety Certification Presentation ( March 07) Pyrotechnic Self Destruct Fuze...d i a n W a t e r G a p , m m WIWEB Sep. 2003 WIWEB Mai 2004 WIWEB 2004 corrected TNO March 2002 TNO Okt. 2002 Polynomisch (Trendline...scale 1/1 Rotation + aerodynamic pressure Aerodynamic efficiency validation on all flight domain Cinematic analysis of airbrake deployment

JPRS Report, Soviet Union, Foreign Military Review, No. 10, October 1987

Science.gov (United States)

1988-05-09

inattention to the social interests of the working people, abuses of official position, wage- levelling, unjustified restrictions in the organization...from a position of class and nation-state egoism , of shameless militarism. The U.S. administration has not renounced the imperialist poli- cies of...1) differs from its predecessor, the Mk84 (mod 0), primarily by virtue of the fact that the pyrotechnic cartridge used to restrict the possibility

Quantile driven identification of structural derivatives

OpenAIRE

Andrew Chesher

2001-01-01

Conditions are derived under which there is local nonparametric identification of derivatives of structural equations in nonlinear triangular simultaneous equations systems. The attack on this problem is via conditional quantile functions and exploits local quantile independence conditions. The identification conditions include local analogues of the order and rank conditions familiar in the analysis of linear simultaneous equations models. The objects whose identification is sought are deriv...

Drug Nanoparticle Formulation Using Ascorbic Acid Derivatives

Directory of Open Access Journals (Sweden)

Kunikazu Moribe

2011-01-01

Full Text Available Drug nanoparticle formulation using ascorbic acid derivatives and its therapeutic uses have recently been introduced. Hydrophilic ascorbic acid derivatives such as ascorbyl glycoside have been used not only as antioxidants but also as food and pharmaceutical excipients. In addition to drug solubilization, drug nanoparticle formation was observed using ascorbyl glycoside. Hydrophobic ascorbic acid derivatives such as ascorbyl mono- and di-n-alkyl fatty acid derivatives are used either as drugs or carrier components. Ascorbyl n-alkyl fatty acid derivatives have been formulated as antioxidants or anticancer drugs for nanoparticle formulations such as micelles, microemulsions, and liposomes. ASC-P vesicles called aspasomes are submicron-sized particles that can encapsulate hydrophilic drugs. Several transdermal and injectable formulations of ascorbyl n-alkyl fatty acid derivatives were used, including ascorbyl palmitate.

Central Clearing of OTC Derivatives

DEFF Research Database (Denmark)

Cont, Rama; Kokholm, Thomas

2014-01-01

netting agreements. When a CCP exists for interest rate derivatives, adding a CCP for credit derivatives is shown to decrease overall exposures. These findings are shown to be robust to the statistical assumptions of the model as well as the choice of risk measure used to quantify exposures....

Higher-derivative generalization of conformal mechanics

Science.gov (United States)

Baranovsky, Oleg

2017-08-01

Higher-derivative analogs of multidimensional conformal particle and many-body conformal mechanics are constructed. Their Newton-Hooke counterparts are derived by applying appropriate coordinate transformations.

Survey on the Use of Derivatives in Indonesia

Directory of Open Access Journals (Sweden)

I Wayan Nuka Lantara

2010-09-01

Full Text Available This paper provides survey evidence on the use of derivatives among firms listed on the Indonesian Stock Exchange. The finding shows that the participation rate in the use of derivatives is 28.8 percent, much lower than those found in developed countries. For the derivatives non-users, insignificant risk exposure is reported as the most important rationale for not using derivatives. Consumer goods industry constitutes the largest proportion of firms using derivatives. The majority of respondents utilize derivatives to hedge against financial risks rather than to speculate. Foreign currency risk and interest rate risk are the most important types of risks faced with by respondents. Using the Chi-square and the Fisher’s exact tests, the result corroborates the size effect hypothesis, where the use of derivatives is more popular among large firms than small firms. A SURVEY ON THE USE OF DERIVATIVES IN INDONESIA Keywords: derivatives; hedging; risk management

Perturbative reduction of derivative order in EFT

Science.gov (United States)

Glavan, Dražen

2018-02-01

Higher derivative corrections are ubiquitous in effective field theories, which seemingly introduces new degrees of freedom at successive orders. This is actually an artefact of the implicit local derivative expansion defining effective field theories. We argue that higher derivative corrections that introduce additional degrees of freedom should be removed and their effects captured either by lower derivative corrections, or special combinations of higher derivative corrections not propagating extra degrees of freedom. Three methods adapted for this task are examined and field redefinitions are found to be most appropriate. First order higher derivative corrections in a scalar tensor theory are removed by field redefinition and it is found that their effects are captured by a subset of Horndeski theories. A case is made for restricting the effective field theory expansions in principle to only terms not introducing additional degrees of freedom.

Preparation of 7-substituted ginkgolide derivatives

DEFF Research Database (Denmark)

Vogensen, Stine Byskov; Strømgaard, Kristian; Shindou, Hideo

2003-01-01

alpha-fluoro ginkgolide B was equipotent to ginkgolide B underlining the critical importance of the 7-position of ginkgolides for PAF receptor activity. Herein we describe the synthesis of a series of ginkgolide B derivatives with modifications at the 7-position and the pharmacological evaluation...... of these derivatives as assayed by cloned PAF receptors. In two cases nucleophilic attack on a 7beta-O-triflate ginkgolide B did not lead to the expected products, but gave rise to two unprecedented ginkgolide derivatives, one with a novel rearranged skeleton. Furthermore, standard reduction of 7alpha-azido ginkgolide......-chloro ginkgolide B, the most potent nonaromatic ginkgolide derivative described to date with a K(i) value of 110 nM....

Human induced pluripotent stem cell (hiPSC)-derived neurons respond to convulsant drugs when co-cultured with hiPSC-derived astrocytes.

Science.gov (United States)

Ishii, Misawa Niki; Yamamoto, Koji; Shoji, Masanobu; Asami, Asano; Kawamata, Yuji

2017-08-15

Accurate risk assessment for drug-induced seizure is expected to be performed before entering clinical studies because of its severity and fatal damage to drug development. Induced pluripotent stem cell (iPSC) technology has allowed the use of human neurons and glial cells in toxicology studies. Recently, several studies showed the advantage of co-culture system of human iPSC (hiPSC)-derived neurons with rodent/human primary astrocytes regarding neuronal functions. However, the application of hiPSC-derived neurons for seizure risk assessment has not yet been fully addressed, and not at all when co-cultured with hiPSC-derived astrocytes. Here, we characterized hiPSC-derived neurons co-cultured with hiPSC-derived astrocytes to discuss how hiPSC-derived neurons are useful to assess seizure risk of drugs. First, we detected the frequency of spikes and synchronized bursts hiPSC-derived neurons when co-cultured with hiPSC-derived astrocytes for 8 weeks. This synchronized burst was suppressed by the treatment with 6-cyano-7-nitroquinoxaline-2,3-dione, α-amino-3-hydroxy-5-methylisoxazole-4-propionic acid (AMPA) receptor antagonist, and D-(-)-2-amino-5-phosphonopentanoic acid, an N-Methyl-d-aspartate (NMDA) receptor antagonist. These data suggested that co-cultured hiPSC-derived neurons formed synaptic connections mediated by AMPA and NMDA receptors. We also demonstrated that co-cultured hiPSC-derived neurons showed epileptiform activity upon treatment with gabazine or kaliotoxin. Finally, we performed single-cell transcriptome analysis in hiPSC-derived neurons and found that hiPSC-derived astrocytes activated the pathways involved in the activities of AMPA and NMDA receptor functions, neuronal polarity, and axon guidance in hiPSC-derived neurons. These data suggested that hiPSC-derived astrocytes promoted the development of action potential, synaptic functions, and neuronal networks in hiPSC-derived neurons, and then these functional alterations result in the epileptiform

14 CFR 1203.501 - Applying derivative classification markings.

Science.gov (United States)

2010-01-01

... INFORMATION SECURITY PROGRAM Derivative Classification § 1203.501 Applying derivative classification markings. Persons who apply derivative classification markings shall: (a) Observe and respect original... 14 Aeronautics and Space 5 2010-01-01 2010-01-01 false Applying derivative classification markings...

Synthesis of octahedral like Cu-BTC derivatives derived from MOF calcined under different atmosphere for application in CO oxidation

Science.gov (United States)

Yang, Yiqiong; Dong, Han; Wang, Yin; He, Chi; Wang, Yuxin; Zhang, Xiaodong

2018-02-01

A series of octahedral structure Cu-BTC derivatives were successfully achieved through direct calcination of copper based metal organic framework Cu-BTC under different atmosphere (CO reaction gas, oxidizing gas O2, reducing gas H2, inert gas Ar). The Cu-BTC derivatives were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), laser Raman spectroscopy (LRS), N2 adsorption-desorption isotherm, element analysis, H2-temperature program reduction (H2-TPR) and X-ray photoelectron spectroscopic (XPS). It is found that Cu-BTC derivative derived from MOF calcined under reaction gas/O2 (Cu-BTC-CO/Cu-BTC-O) only retain Cu2O and CuO species. In addition, a weak Cu-BTC structure and Cu particles were observed on Cu-BTC derivative derived from MOF calcined under H2 (Cu-BTC-H). Obviously differently, Cu-BTC derivative derived from MOF calcined under Ar (Cu-BTC-Ar) still retains good MOF structure. The catalytic performance for CO oxidation over Cu-BTC derivatives was studied. It was found that Cu-BTC-CO showed a smaller specific surface area (8.0 m2/g), but presented an excellent catalytic performance, long-term stability and cycling stability with a complete CO conversion temperature (T100) of 140 °C, which was ascribed to the higher Cu2O/CuO ratio, good low temperature reduction behavior and a high quantity of surface active oxygen species.

Synthesis of Substituted α-Trifluoromethyl Piperidinic Derivatives

Directory of Open Access Journals (Sweden)

Sarah Rioton

2017-03-01

Full Text Available A comprehensive survey of pathways leading to the generation of α-trifluoromethyl monocyclic piperidinic derivatives is provided (65 references. These compounds have been synthesized either from 6-membered rings e.g., pipecolic acid or lactam derivatives by introduction a trifluoromethyl group, from pyridine or pyridinone derivatives by reduction, and from 5-membered rings e.g., prolinol derivatives by ring expansion, from linear amines by cyclization or from dienes/dienophiles by [4 + 2]-cycloaddition.

Comparison of human adipose-derived stem cells and bone marrow-derived stem cells in a myocardial infarction model

DEFF Research Database (Denmark)

Rasmussen, Jeppe; Frøbert, Ole; Holst-Hansen, Claus

2014-01-01

Background: Treatment of myocardial infarction with bone marrow-derived mesenchymal stem cells and recently also adipose-derived stem cells has shown promising results. In contrast to clinical trials and their use of autologous bone marrow-derived cells from the ischemic patient, the animal...... myocardial infarction models are often using young donors and young, often immune-compromised, recipient animals. Our objective was to compare bone marrow-derived mesenchymal stem cells with adipose-derived stem cells from an elderly ischemic patient in the treatment of myocardial infarction, using a fully...... grown non-immunecompromised rat model. Methods: Mesenchymal stem cells were isolated from adipose tissue and bone marrow and compared with respect to surface markers and proliferative capability. To compare the regenerative potential of the two stem cell populations, male Sprague-Dawley rats were...

Human umbilical cord blood-derived stem cells and brain-derived neurotrophic factor protect injured optic nerve: viscoelasticity characterization

Directory of Open Access Journals (Sweden)

Xue-man Lv

2016-01-01

Full Text Available The optic nerve is a viscoelastic solid-like biomaterial. Its normal stress relaxation and creep properties enable the nerve to resist constant strain and protect it from injury. We hypothesized that stress relaxation and creep properties of the optic nerve change after injury. More-over, human brain-derived neurotrophic factor or umbilical cord blood-derived stem cells may restore these changes to normal. To validate this hypothesis, a rabbit model of optic nerve injury was established using a clamp approach. At 7 days after injury, the vitreous body re-ceived a one-time injection of 50 µg human brain-derived neurotrophic factor or 1 × 106 human umbilical cord blood-derived stem cells. At 30 days after injury, stress relaxation and creep properties of the optic nerve that received treatment had recovered greatly, with patho-logical changes in the injured optic nerve also noticeably improved. These results suggest that human brain-derived neurotrophic factor or umbilical cord blood-derived stem cell intervention promotes viscoelasticity recovery of injured optic nerves, and thereby contributes to nerve recovery.

Alchemical derivatives of reaction energetics

Science.gov (United States)

Sheppard, Daniel; Henkelman, Graeme; von Lilienfeld, O. Anatole

2010-08-01

Based on molecular grand canonical ensemble density functional theory, we present a theoretical description of how reaction barriers and enthalpies change as atoms in the system are subjected to alchemical transformations, from one element into another. The change in the energy barrier for the umbrella inversion of ammonia is calculated along an alchemical path in which the molecule is transformed into water, and the change in the enthalpy of protonation for methane is calculated as the molecule is transformed into a neon atom via ammonia, water, and hydrogen fluoride. Alchemical derivatives are calculated analytically from the electrostatic potential in the unperturbed system, and compared to numerical derivatives calculated with finite difference interpolation of the pseudopotentials for the atoms being transformed. Good agreement is found between the analytical and numerical derivatives. Alchemical derivatives are also shown to be predictive for integer changes in atomic numbers for oxygen binding to a 79 atom palladium nanoparticle, illustrating their potential use in gradient-based optimization algorithms for the rational design of catalysts.

Fields of rational constants of cyclic factorizable derivations

Directory of Open Access Journals (Sweden)

Janusz Zielinski

2015-12-01

Full Text Available We describe all rational constants of a large family of four-variable cyclic factorizable derivations. Thus, we determine all rational first integrals of their corresponding systems of differential equations. Moreover, we give a characteristic of all four-variable Lotka-Volterra derivations with a nontrivial rational constant. All considerations are over an arbitrary field of characteristic zero. Our main tool is the investigation of the cofactors of strict Darboux polynomials. Factorizable derivations are important in derivation theory. Namely, we may associate the factorizable derivation with any given derivation of a polynomial ring and that construction helps to determine rational constants of arbitrary derivations. Besides, Lotka-Volterra systems play a significant role in population biology, laser physics and plasma physics.

Non-destructive visualization of linear explosive-induced Pyroshock using phase arrayed laser-induced shock in a space launcher composite

International Nuclear Information System (INIS)

Jang, Jae Kyeong; Lee, Jung Ryul

2015-01-01

Separation mechanism of Space launch vehicles are used in various separation systems and pyrotechnic devices. The operation of these pyrotechnic devices generates Pyroshock that can cause failures in electronic components. The prediction of high frequency structural response, especially the shock response spectrum (SRS), is important. This paper presents a non-destructive visualization and simulation of linear explosive-induced Pyroshock using phase arrayed Laser-induced shock. The proposed method includes a laser shock test based on laser beam and filtering zone conditioning to predict the SRS of Pyroshock. A ballistic test based on linear explosive and non-contact Laser Doppler Vibrometers and a nondestructive Laser shock measurement using laser excitation and several PZT sensors, are performed using a carbon composite sandwich panel. The similarity of the SRS of the conditioned laser shock to that of the real explosive Pyroshock is evaluated with the Mean Acceleration Difference. The average of MADs over the two training points was 33.64%. And, MAD at verification point was improved to 31.99%. After that, experimentally found optimal conditions are applied to any arbitrary points in laser scanning area. Finally, it is shown that linear explosive-induced real Pyroshock wave propagation can be visualized with high similarity based on the proposed laser technology. (paper)

Wireless device for activation of an underground shock wave absorber

Science.gov (United States)

Chikhradze, M.; Akhvlediani, I.; Bochorishvili, N.; Mataradze, E.

2011-10-01

The paper describes the mechanism and design of the wireless device for activation of energy absorber for localization of blast energy in underground openings. The statistics shows that the greatest share of accidents with fatal results associate with explosions in coal mines due to aero-methane and/or air-coal media explosion. The other significant problem is terrorist or accidental explosions in underground structures. At present there are different protective systems to reduce the blast energy. One of the main parts of protective Systems is blast Identification and Registration Module. The works conducted at G. Tsulukidze Mining Institute of Georgia enabled to construct the wireless system of explosion detection and mitigation of shock waves. The system is based on the constant control on overpressure. The experimental research continues to fulfill the system based on both threats, on the constant control on overpressure and flame parameters, especially in underground structures and coal mines. Reaching the threshold value of any of those parameters, the system immediately starts the activation. The absorber contains a pyrotechnic device ensuring the discharge of dispersed water. The operational parameters of wireless device and activation mechanisms of pyrotechnic element of shock wave absorber are discussed in the paper.

Anisotropic inflation with derivative couplings

Science.gov (United States)

Holland, Jonathan; Kanno, Sugumi; Zavala, Ivonne

2018-05-01

We study anisotropic power-law inflationary solutions when the inflaton and its derivative couple to a vector field. This type of coupling is motivated by D-brane inflationary models, in which the inflaton, and a vector field living on the D-brane, couple disformally (derivatively). We start by studying a phenomenological model where we show the existence of anisotropic solutions and demonstrate their stability via a dynamical system analysis. Compared to the case without a derivative coupling, the anisotropy is reduced and thus can be made consistent with current limits, while the value of the slow-roll parameter remains almost unchanged. We also discuss solutions for more general cases, including D-brane-like couplings.

36th International Pyrotechnics Seminar 2009 in Rotterdam - Editorial

NARCIS (Netherlands)

Klerk, W.P.C. de; Lingen, J.L. van

2010-01-01

From August 23 to 28, 2009, TNO Defence, Security and Safety organized the 36th IPS Congress in De Doelen in Rotterdam. The program consisted of 4 days of scientific presentations, a tour of the ports of Rotterdam and a final tour at TNO Defence, Security and Safety in Rijswijk and Ypenburg. The

Alternatives to Pyrotechnic Distress Signals; Laboratory and Field Studies

Science.gov (United States)

2015-03-01

distance for positive identity and location. The spectral characteristics (“color”) of the light are important, as daytime and nighttime vision are most...ambient illumination. Figure 10. Laboratory setup. 5.2.1 Projector Specifications The scene projector was a Panasonic PT-AE80000U home cinema ...three were identical to lab signals: 4Hz group/interrupt in white, red, and cyan. For the field testing, experimenters mounted the signal generator

Weather Derivatives – Origin, Types and Application

Directory of Open Access Journals (Sweden)

Piotr Binkowski

2008-01-01

Full Text Available The number of companies that are exposed to the revenues loss risk caused by weather variability is still increasing. The businesses that are mostly exposed to weather risk are following: energy, agriculture, constructions and transport. That situation has initiated dynamic growth of weather derivatives markets as well as the awareness of the weather risk among the market participants. Presently, the weather derivatives markets evaluate rapidly in all the mature economies: USA, Asia and Europe. Constructing weather derivatives relies on qu- antifying climate factors in the form of indexes, what is quite simple task, more difficultly can be gathering precise historical data of required climate factors. Taking into consideration so far development of derivatives especially the financial derivatives based on different types of indexes financial market has at disposal wide range of different types of proved derivatives (futures, forward, options, swaps, which can be successfully utilised on the weather-driven markets both for hedging weather risk and speculating.

17 CFR 240.16a-4 - Derivative securities.

Science.gov (United States)

2010-04-01

... 17 Commodity and Securities Exchanges 3 2010-04-01 2010-04-01 false Derivative securities. 240.16a....16a-4 Derivative securities. (a) For purposes of section 16 of the Act, both derivative securities and... securities, except that the acquisition or disposition of any derivative security shall be separately...

Nanocarbon materials obtained of coniferous trees in the composition of black powder

Directory of Open Access Journals (Sweden)

Zulkhair Mansurov

2012-03-01

Full Text Available Obtained black powders from coniferous wood. The carbon content of up to 90% can be used in warfare, pyrotechnics and industries. In the Republic of Kazakhstan does not produce gunpowder. In the energy-intensive materials laboratory, developed industrial black powders (ordinary, composed of components produced in the republic of Kazakhstan. Sulfur, activated carbon, based on apricot seeds and rice husks, softwood sawdust, which have lower costs than their foreign counterparts.

Nature of the basic financial derivatives

OpenAIRE

Kats, Svetlana

2014-01-01

The article reveals the essence of basic derivatives. Studied by various authors approaches to defining derivatives and their definitions in the legislation and proposed his own definition of the most appropriate for use in accounting practice.

Separation of [Rh-103m]-rhodocene-derivatives from the parent [103Ru]ruthenocen-derivatives and their organ distribution

International Nuclear Information System (INIS)

Wenzel, M.; Wu, Y.

1987-01-01

The radioactive decay of [ 103 Ru]ruthenocene derivatives leads to sup(103m)Rh labelled rhodocinium derivatives, which can be separated by the extraction of a lipophilic solution of the ruthenocen derivate with water. The separation factor sup(103m)Rh/ 103 Ru reaches values of 32:1 Rh 3+ ions are not liberated and extracted. The organ distribution of the sup(103m)Rh labelled rhodocinium derivatives gained from ruthenocene and from N-isopropyl-ruthenocene amphetamine is different from the distribution of the parent ruthenocene compound. The liver and kidney uptake of the rhodocinium-amphetamine is much higher than the uptake with ruthenocene amphetamine. (author)

Computation of Mie derivatives.

Science.gov (United States)

Li, Yang; Bowler, Nicola

2013-07-10

Analytical expressions are obtained for the derivatives of Mie scattering coefficients with respect to the electrical radius of the spherical scattering particle, and to the relative permittivity and permeability of both the particle and the surrounding medium. Their corresponding approximate expressions are developed to avoid numerical overflow based on the logarithmic derivative of Riccati-Bessel functions. The analytical expressions have been verified by comparing their results with those calculated by analytical expressions developed by Mathematica. Compared with the numerical derivative, the analytical expressions and approximate expressions show a higher accuracy and are 2.0 and 2.8 times, respectively, faster in the case of a single magnetodielectric sphere. Generally, for spheres with an electrical radius in a large range, the approximate expressions can yield acceptable accuracy and computation time up to a high order. This work can be used in the design of nonmetallic metamaterials, and in the retrieval of aerosol properties from remote sensing data. An example calculation is given for the design of an optical, all-dielectric, mu-negative metamaterial consisting of a simple cubic array of tellurium nanoparticles.

Multifunctional Cinnamic Acid Derivatives

Directory of Open Access Journals (Sweden)

Aikaterini Peperidou

2017-07-01

Full Text Available Our research to discover potential new multitarget agents led to the synthesis of 10 novel derivatives of cinnamic acids and propranolol, atenolol, 1-adamantanol, naphth-1-ol, and (benzylamino ethan-1-ol. The synthesized molecules were evaluated as trypsin, lipoxygenase and lipid peroxidation inhibitors and for their cytotoxicity. Compound 2b derived from phenoxyphenyl cinnamic acid and propranolol showed the highest lipoxygenase (LOX inhibition (IC50 = 6 μΜ and antiproteolytic activity (IC50 = 0.425 μΜ. The conjugate 1a of simple cinnamic acid with propranolol showed the higher antiproteolytic activity (IC50 = 0.315 μΜ and good LOX inhibitory activity (IC50 = 66 μΜ. Compounds 3a and 3b, derived from methoxylated caffeic acid present a promising combination of in vitro inhibitory and antioxidative activities. The S isomer of 2b also presented an interesting multitarget biological profile in vitro. Molecular docking studies point to the fact that the theoretical results for LOX-inhibitor binding are identical to those from preliminary in vitro study.

Langmuir-Blodgett Films of Graphene Derivatives

DEFF Research Database (Denmark)

Petersen, Søren Vermehren

The work presented in this PhD thesis can be divided into two main categories: 1) Syn-thesis and Langmuir-Blodgett assembly of graphene derivatives and 2) Application and characterization of graphene derivatives as an interface material in molecular electron-ics. While the first category could...... be divided further, the synthesis and Langmuir-Blodgett results are intertwined in such a way that it would be more confusing to pre-sent them separately. The Langmuir-Blodgett deposition also played a crucial, but more isolated, part in the investigation of graphene derivatives as interface material....... Solution processable graphene in the form of chemically derived graphene has been synthesized through the modified Hummers method with subsequent reduction into reduced graphene oxide with hydrazine. The completeness of oxidation, the effect of the refinement steps and the reduction of the graphene oxide...

Quinazoline derivatives: synthesis and bioactivities

OpenAIRE

Wang, Dan; Gao, Feng

2013-01-01

Owing to the significant biological activities, quinazoline derivatives have drawn more and more attention in the synthesis and bioactivities research. This review summarizes the recent advances in the synthesis and biological activities investigations of quinazoline derivatives. According to the main method the authors adopted in their research design, those synthetic methods were divided into five main classifications, including Aza-reaction, Microwave-assisted reaction, Metal-mediated reac...

A class of constitutive relations with internal variable derivatives. Derivation from homogenization and initial value problem

International Nuclear Information System (INIS)

Andrieux, S.; Joussemet, M.; Lorentz, E.

1996-01-01

A general framework for deriving and using a class of constitutive laws incorporating spatial gradients of internal variables is presented. It uses two basic ingredients: a derivation of such models by homogenization techniques and a reformulation of the evolution equation at the scale of the whole structure. (orig.)

Derivative analyticity relations and asymptotic energies

International Nuclear Information System (INIS)

Fischer, J.

1976-01-01

On the basis of general principles of the S-matrix theory theorems are derived showing that derivative analyticity relations analogous to those of Bronzen, Kane and Sukhatme hold at asymptotic energies if the high-energy limits of certain physical quantities exist

28 CFR 17.26 - Derivative classification.

Science.gov (United States)

2010-07-01

... 28 Judicial Administration 1 2010-07-01 2010-07-01 false Derivative classification. 17.26 Section 17.26 Judicial Administration DEPARTMENT OF JUSTICE CLASSIFIED NATIONAL SECURITY INFORMATION AND ACCESS TO CLASSIFIED INFORMATION Classified Information § 17.26 Derivative classification. (a) Persons...

Lie n-derivations on 7 -subspace lattice algebras

Indian Academy of Sciences (India)

all x ∈ K and all A ∈ Alg L. Based on this result, a complete characterization of linear n-Lie derivations on Alg L is obtained. Keywords. J -subspace lattice algebras; Lie derivations; Lie n-derivations; derivations. 2010 Mathematics Subject Classification. 47B47, 47L35. 1. Introduction. Let A be an algebra. Recall that a linear ...

Weather derivatives: Business hedge instrument from weather risks

Directory of Open Access Journals (Sweden)

Đorđević Bojan S.

2014-01-01

Full Text Available In the late 1990s, a new financial market was developed - a market for weather derivatives, so that the risk managers could hedge their exposure to weather risk. After a rather slow start, the weather derivatives market had started to grow rapidly. Risk managers could no longer blame poor financial results on the weather. Weather risk could now be removed by hedging procedure. This paper will explain briefly what the weather derivatives are and will point out at some of the motives for use of derivatives. Thereafter we will look at the history of the weather risk market, how the weather derivatives market has developed in recent years and also who are the current and potential players in the weather derivatives market.

A New Method to Find Fuzzy Nth Order Derivation and Applications to Fuzzy Nth Order Arithmetic Based on Generalized H-Derivation

Directory of Open Access Journals (Sweden)

Laleh Hooshangian

2014-07-01

Full Text Available In this paper, fuzzy nth-order derivative for n in N is introduced. To do this, nth-order derivation under generalized Hukuhara derivative here in discussed. Calculations on the fuzzy nth-order derivative on fuzzy functions and their relationships, in general, are introduced. Then, the fuzzy nth-order differential equations is solved, for n in N.

Satellite-Derived Bathymetry: Accuracy Assessment on Depths Derivation Algorithm for Shallow Water Area

Science.gov (United States)

Said, N. M.; Mahmud, M. R.; Hasan, R. C.

2017-10-01

Over the years, the acquisition technique of bathymetric data has evolved from a shipborne platform to airborne and presently, utilising space-borne acquisition. The extensive development of remote sensing technology has brought in the new revolution to the hydrographic surveying. Satellite-Derived Bathymetry (SDB), a space-borne acquisition technique which derives bathymetric data from high-resolution multispectral satellite imagery for various purposes recently considered as a new promising technology in the hydrographic surveying industry. Inspiring by this latest developments, a comprehensive study was initiated by National Hydrographic Centre (NHC) and Universiti Teknologi Malaysia (UTM) to analyse SDB as a means for shallow water area acquisition. By adopting additional adjustment in calibration stage, a marginal improvement discovered on the outcomes from both Stumpf and Lyzenga algorithms where the RMSE values for the derived (predicted) depths were 1.432 meters and 1.728 meters respectively. This paper would deliberate in detail the findings from the study especially on the accuracy level and practicality of SDB over the tropical environmental setting in Malaysia.

Elementary derivation of Kepler's laws

International Nuclear Information System (INIS)

Vogt, E.

1995-02-01

A simple derivation of all three so-called Kepler Laws is presented in which the orbits, bound and unbound, follow directly and immediately from conservation of energy and angular momentum. The intent is to make this crowning achievement of Newtonian Mechanics easily accessible to students in introductory physics courses. The method is also extended to simplify the derivation of the Rutherford Scattering Law. (author). 4 refs., 3 figs

Synthesis and anticancer evaluation of imidazolinone and benzoxazole derivatives

Directory of Open Access Journals (Sweden)

Heba A. El-Hady

2017-05-01

Full Text Available A series of imidazolinone and benzoxazole derivatives (3 and 5 have been synthesized by the condensation of oxazolinone derivatives (2a–c with aniline and 2-hydroxyaniline. Acetyl derivatives (4, 6 and 7 were prepared via acetylation of compounds 3 and 5 with acetic anhydride and chloroacetyl chloride. The results revealed that imidazolinone and benzoxazole derivatives are potent against the cancer cell lines MCF-7 and HePG2. In particular, benzoxazole derivatives are more potent than imidazolinone derivatives.

New uracil derivatives and their biological activity

International Nuclear Information System (INIS)

Hudecova, D.; Striganova, J.; Chovanec, P.; Uher, M.

1998-01-01

Present study is concentrated to the research of antimicrobial activity of some derivatives of the uracil and 1,3-dimethyluracyl. The antimicrobial effects of these compounds have been tested on various strains of bacteria, yeasts, and filamentous fungi. The highest antimicrobial effects were found with dithiocarbamato-derivatives, which were effective against pathogenic and non-pathogenic bacteria (IC 50 = 7-25 μg cm -3 ), yeasts (IC 50 = 9-60 μg cm -3 ) and filamentous fungi.The most sensitive fungus to dithiocarbamato-derivatives was Botritis cinerea. It seems to be apparent that the presence of the -NH-C(S)-S- group in molecules of derivatives of uracil and and 1,3-dimethyluracyl influencing the incorporation rate [ 14 ]-adenine and 14 ]-leucine into the biomolecules and also markedly inhibits oxygen consumption (IC 50 = 58 μg cm -3 ). The same derivative demonstrated no mutagenic activity. (authors)

5 CFR 2500.5 - Derivative classification.

Science.gov (United States)

2010-01-01

... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Derivative classification. 2500.5 Section 2500.5 Administrative Personnel OFFICE OF ADMINISTRATION, EXECUTIVE OFFICE OF THE PRESIDENT INFORMATION SECURITY REGULATION § 2500.5 Derivative classification. The Office of Administration serves only as the...

46 CFR 503.55 - Derivative classification.

Science.gov (United States)

2010-10-01

... Security Program § 503.55 Derivative classification. (a) In accordance with Part 2 of Executive Order 12958 and directives of the Information Security Oversight Office, the incorporation, paraphrasing... 46 Shipping 9 2010-10-01 2010-10-01 false Derivative classification. 503.55 Section 503.55...

PROCEDURES FOR THE DERIVATION OF EQUILIBRIUM ...

Science.gov (United States)

This equilibrium partitioning sediment benchmark (ESB) document describes procedures to derive concentrations for 32 nonionic organic chemicals in sediment which are protective of the presence of freshwater and marine benthic organisms. The equilibrium partitioning (EqP) approach was chosen because it accounts for the varying biological availability of chemicals in different sediments and allows for the incorporation of the appropriate biological effects concentration. This provides for the derivation of benchmarks that are causally linked to the specific chemical, applicable across sediments, and appropriately protective of benthic organisms. EqP can be used to calculate ESBs for any toxicity endpoint for which there are water-only toxicity data; it is not limited to any single effect endpoint. For the purposes of this document, ESBs for 32 nonionic organic chemicals, including several low molecular weight aliphatic and aromatic compounds, pesticides, and phthalates, were derived using Final Chronic Values (FCV) from Water Quality Criteria (WQC) or Secondary Chronic Values (SCV) derived from existing toxicological data using the Great Lakes Water Quality Initiative (GLI) or narcosis theory approaches. These values are intended to be the concentration of each chemical in water that is protective of the presence of aquatic life. For nonionic organic chemicals demonstrating a narcotic mode of action, ESBs derived using the GLI approach specifically for fres

Chromatic Derivatives, Chromatic Expansions and Associated Spaces

OpenAIRE

Ignjatovic, Aleksandar

2009-01-01

This paper presents the basic properties of chromatic derivatives and chromatic expansions and provides an appropriate motivation for introducing these notions. Chromatic derivatives are special, numerically robust linear differential operators which correspond to certain families of orthogonal polynomials. Chromatic expansions are series of the corresponding special functions, which possess the best features of both the Taylor and the Shannon expansions. This makes chromatic derivatives and ...

On δ-derivations of n-ary algebras

International Nuclear Information System (INIS)

Kaygorodov, Ivan B

2012-01-01

We give a description of δ-derivations of (n+1)-dimensional n-ary Filippov algebras and, as a consequence, of simple finite-dimensional Filippov algebras over an algebraically closed field of characteristic zero. We also give new examples of non-trivial δ-derivations of Filippov algebras and show that there are no non-trivial δ-derivations of the simple ternary Mal'tsev algebra M 8 .

Higher-derivative Lee-Wick unification

International Nuclear Information System (INIS)

Carone, Christopher D.

2009-01-01

We consider gauge coupling unification in Lee-Wick extensions of the Standard Model that include higher-derivative quadratic terms beyond the minimally required set. We determine how the beta functions are modified when some Standard Model particles have two Lee-Wick partners. We show that gauge coupling unification can be achieved in such models without requiring the introduction of additional fields in the higher-derivative theory and we comment on possible ultraviolet completions.

Magnetocaloric effect in potassium doped lanthanum manganite perovskites prepared by a pyrophoric method

Science.gov (United States)

Das, Soma; Dey, T. K.

2006-08-01

The magnetocaloric effect (MCE) in fine grained perovskite manganites of the type La1-xKxMnO3 (0value of 3.00 J kg-1 K-1 at 310 K amongst the compounds investigated. Moreover, the maximum magnetic entropy change exhibits a linear dependence with applied magnetic field. The estimated adiabatic temperature change at TC and at 1 T field also increases with K doping, being a maximum of 2.1 K for the La0.85K0.15MnO3 compound. The relative cooling power (RCP) of La1-xKxMnO3 compounds is estimated to be about one-third of that of the prototype magnetic refrigerant material (pure Gd). However, La1-xKxMnO3 compounds possess an MCE around room temperature, which is comparable to that of Gd. Further, tailoring of their TC, higher chemical stability, lower eddy current heating and lower cost of synthesis are some of the attractive features of K doped lanthanum manganites that are advantageous for a magnetic refrigerant. The temperature dependence of the magnetic entropy change (ΔSM) measured under various magnetic fields is explained fairly well using the Landau theory of phase transitions. Contributions of magnetoelastic and electron interaction are found to have a strong influence in the magnetocaloric effect of manganites.

Nanomaterials derived from metal-organic frameworks

Science.gov (United States)

Dang, Song; Zhu, Qi-Long; Xu, Qiang

2018-01-01

The thermal transformation of metal-organic frameworks (MOFs) generates a variety of nanostructured materials, including carbon-based materials, metal oxides, metal chalcogenides, metal phosphides and metal carbides. These derivatives of MOFs have characteristics such as high surface areas, permanent porosities and controllable functionalities that enable their good performance in sensing, gas storage, catalysis and energy-related applications. Although progress has been made to tune the morphologies of MOF-derived structures at the nanometre scale, it remains crucial to further our knowledge of the relationship between morphology and performance. In this Review, we summarize the synthetic strategies and optimized methods that enable control over the size, morphology, composition and structure of the derived nanomaterials. In addition, we compare the performance of materials prepared by the MOF-templated strategy and other synthetic methods. Our aim is to reveal the relationship between the morphology and the physico-chemical properties of MOF-derived nanostructures to optimize their performance for applications such as sensing, catalysis, and energy storage and conversion.

Higher-Derivative Supergravity and Moduli Stabilization

International Nuclear Information System (INIS)

Ciupke, David; Westphal, Alexander; Louis, Jan; Hamburg Univ.

2015-05-01

We review the ghost-free four-derivative terms for chiral superfields in N=1 supersymmetry and supergravity. These terms induce cubic polynomial equations of motion for the chiral auxiliary fields and correct the scalar potential. We discuss the different solutions and argue that only one of them is consistent with the principles of effective field theory. Special attention is paid to the corrections along flat directions which can be stabilized or destabilized by the higher-derivative terms. We then compute these higher-derivative terms explicitly for the type IIB string compactified on a Calabi-Yau orientifold with fluxes via Kaluza-Klein reducing the (α') 3 R 4 corrections in ten dimensions for the respective N=1 Kaehler moduli sector. We prove that together with flux and the known (α') 3 -corrections the higher-derivative term stabilizes all Calabi-Yau manifolds with positive Euler number, provided the sign of the new correction is negative.

Separation of (Rh-103m)-rhodocene-derivatives from the parent (/sup 103/Ru)ruthenocen-derivatives and their organ distribution

Energy Technology Data Exchange (ETDEWEB)

Wenzel, M.; Wu, Y.

1987-01-01

The radioactive decay of (/sup 103/Ru)ruthenocene derivatives leads to sup(103m)Rh labelled rhodocinium derivatives, which can be separated by the extraction of a lipophilic solution of the ruthenocen derivate with water. The separation factor sup(103m)Rh//sup 103/Ru reaches values of 32:1 Rh/sup 3 +/ ions are not liberated and extracted. The organ distribution of the sup(103m)Rh labelled rhodocinium derivatives gained from ruthenocene and from N-isopropyl-ruthenocene amphetamine is different from the distribution of the parent ruthenocene compound. The liver and kidney uptake of the rhodocinium-amphetamine is much higher than the uptake with ruthenocene amphetamine.

Jordan and left derivations on locally C*-algebras

International Nuclear Information System (INIS)

Shahzad, Naseer

2002-07-01

We show that left derivations as well as Jordan derivations on locally G*-algebras are always continuous. We also obtain some noncommutative extensions of the classical Singer-Wermer theorem for locally C*-algebras: (1) Every left derivation D on a locally (7*-algebra A is identically zero. (2) Every Jordan derivation D on a locally C*-algebra A which satisfies [D(x), x]D(x]=0 for all x in A, is identically zero. (author)

A note on derivations in semiprime rings

Directory of Open Access Journals (Sweden)

Joso Vukman

2005-01-01

Full Text Available We prove in this note the following result. Let n>1 be an integer and let R be an n!-torsion-free semiprime ring with identity element. Suppose that there exists an additive mapping D:R→R such that D(xn=∑j=1nxn−jD(xxj−1 is fulfilled for all x∈R. In this case, D is a derivation. This research is motivated by the work of Bridges and Bergen (1984. Throughout, R will represent an associative ring with center Z(R. Given an integer n>1, a ring R is said to be n-torsion-free if for x∈R, nx=0 implies that x=0. Recall that a ring R is prime if for a,b∈R, aRb=(0 implies that either a=0 or b=0, and is semiprime in case aRa=(0 implies that a=0. An additive mapping D:R→R is called a derivation if D(xy=D(xy+xD(y holds for all pairs x,y∈R and is called a Jordan derivation in case D(x2=D(xx+xD(x is fulfilled for all x∈R. Every derivation is a Jordan derivation. The converse is in general not true. A classical result of Herstein (1957 asserts that any Jordan derivation on a prime ring with characteristic different from two is a derivation. A brief proof of Herstein's result can be found in 1988 by Brešar and Vukman. Cusack (1975 generalized Herstein's result to 2-torsion-free semiprime rings (see also Brešar (1988 for an alternative proof. For some other results concerning derivations on prime and semiprime rings, we refer to Brešar (1989, Vukman (2005, Vukman and Kosi-Ulbl (2005.

Mesogenic benzothiazole derivatives with methoxy substituents

Indian Academy of Sciences (India)

Unknown

2003-10-11

Oct 11, 2003 ... literature. Barbera et al14 have synthesized 2-pyr- azoline derivatives and also studied the optical,. NLO and mesogenic properties of such materials. Highly polar thiophene-based liquid crystals have also been reported15 in the literature. However, fused ring heterocyclic derivatives which are two conden-.

Precision Orbit Derived Atmospheric Density: Development and Performance

Science.gov (United States)

McLaughlin, C.; Hiatt, A.; Lechtenberg, T.; Fattig, E.; Mehta, P.

2012-09-01

Precision orbit ephemerides (POE) are used to estimate atmospheric density along the orbits of CHAMP (Challenging Minisatellite Payload) and GRACE (Gravity Recovery and Climate Experiment). The densities are calibrated against accelerometer derived densities and considering ballistic coefficient estimation results. The 14-hour density solutions are stitched together using a linear weighted blending technique to obtain continuous solutions over the entire mission life of CHAMP and through 2011 for GRACE. POE derived densities outperform the High Accuracy Satellite Drag Model (HASDM), Jacchia 71 model, and NRLMSISE-2000 model densities when comparing cross correlation and RMS with accelerometer derived densities. Drag is the largest error source for estimating and predicting orbits for low Earth orbit satellites. This is one of the major areas that should be addressed to improve overall space surveillance capabilities; in particular, catalog maintenance. Generally, density is the largest error source in satellite drag calculations and current empirical density models such as Jacchia 71 and NRLMSISE-2000 have significant errors. Dynamic calibration of the atmosphere (DCA) has provided measurable improvements to the empirical density models and accelerometer derived densities of extremely high precision are available for a few satellites. However, DCA generally relies on observations of limited accuracy and accelerometer derived densities are extremely limited in terms of measurement coverage at any given time. The goal of this research is to provide an additional data source using satellites that have precision orbits available using Global Positioning System measurements and/or satellite laser ranging. These measurements strike a balance between the global coverage provided by DCA and the precise measurements of accelerometers. The temporal resolution of the POE derived density estimates is around 20-30 minutes, which is significantly worse than that of accelerometer

Turbulence modeling with fractional derivatives: Derivation from first principles and initial results

Science.gov (United States)

Epps, Brenden; Cushman-Roisin, Benoit

2017-11-01

Fluid turbulence is an outstanding unsolved problem in classical physics, despite 120+ years of sustained effort. Given this history, we assert that a new mathematical framework is needed to make a transformative breakthrough. This talk offers one such framework, based upon kinetic theory tied to the statistics of turbulent transport. Starting from the Boltzmann equation and ``Lévy α-stable distributions'', we derive a turbulence model that expresses the turbulent stresses in the form of a fractional derivative, where the fractional order is tied to the transport behavior of the flow. Initial results are presented herein, for the cases of Couette-Poiseuille flow and 2D boundary layers. Among other results, our model is able to reproduce the logarithmic Law of the Wall in shear turbulence.

Anterior cruciate ligament-derived cells have high chondrogenic potential.

Science.gov (United States)

Furumatsu, Takayuki; Hachioji, Motomi; Saiga, Kenta; Takata, Naoki; Yokoyama, Yusuke; Ozaki, Toshifumi

2010-01-01

Anterior cruciate ligament (ACL)-derived cells have a character different from medial collateral ligament (MCL)-derived cells. However, the critical difference between ACL and MCL is still unclear in their healing potential and cellular response. The objective of this study was to investigate the mesenchymal differentiation property of each ligament-derived cell. Both ligament-derived cells differentiated into adipogenic, osteogenic, and chondrogenic lineages. In chondrogenesis, ACL-derived cells had the higher chondrogenic property than MCL-derived cells. The chondrogenic marker genes, Sox9 and alpha1(II) collagen (Col2a1), were induced faster in ACL-derived pellets than in MCL-derived pellets. Sox9 expression preceded the increase of Col2a1 in both pellet-cultured cells. However, the expression level of Sox9 and a ligament/tendon transcription factor Scleraxis did not parallel the increase of Col2a1 expression along with chondrogenic induction. The present study demonstrates that the balance between Sox9 and Scleraxis have an important role in the chondrogenic differentiation of ligament-derived cells. Copyright 2009 Elsevier Inc. All rights reserved.

On Functional Inequalities Originating from Module Jordan Left Derivations

OpenAIRE

Kang Sheon-Young; Chang Ick-Soon; Kim Hark-Mahn

2008-01-01

Abstract We first examine the generalized Hyers-Ulam stability of functional inequality associated with module Jordan left derivation (resp., module Jordan derivation). Secondly, we study the functional inequality with linear Jordan left derivation (resp., linear Jordan derivation) mapping into the Jacobson radical.

Prospective analysis of ambiental and weather effects on conform displaying of fireworks

Directory of Open Access Journals (Sweden)

Jitea Ciprian

2017-01-01

Full Text Available The paper presents the results of research on theoretical and practical relating to establishing and analysis of effects of ambiental and weather effects on conform displaying of fireworks used to organizing fireworks. Scientific research highlighted in this article was conducted in the project no. PN 16 43 03 04, study conducted through Nucleu program entitled -„ Research on the influence of microclimate factors on parameters of the products, while testing the functioning of pyrotechnic articles”.

MJERENJE SILE UDARNOG VALA INDIREKTNIM METODAMA

OpenAIRE

Dobrilović, Mario; Ester, Zvonimir; Kujundžić, Trpimir

2005-01-01

Tests have been conducted at the “Laboratory for testing of civil explosives, detonators, electrical detonators and pyrotechnical materials”, Department for mining and geotechnics of the Faculty of mining, geology and petroleum engineering, University of Zagreb with the purpose of designing a detonator that would unite advantages of a non-electric system and the precision in regulation of time delay in electronic initiation system. Sum of energy released by the wave force in shock tube is a p...

Sur la modélisation et la simulation de liaisons soumises à des chocs pyrotechniques

OpenAIRE

Derumaux , Marc

2004-01-01

The presented work deals with fast dynamic simulation of non linear joints. An original industrial context illustrates the process, consisting in analyzing, with an eye to prediction, consequences of a stage separation on the Ariane 5 launcher. A pyrotechnic device cuts the structure along a breaking split, which generates a strong shock wave propagating up to the satellites. A two scales approach is proposed to perform an accurate calculation of the joints behavior (place of strong non linea...

Spot Ignition of Natural Fuels by Hot Metal Particles

OpenAIRE

Urban, James Linwood

2017-01-01

The spot ignition of combustible material by hot metal particles is an important pathway by which wildland and urban spot fires and smolders are started. Upon impact with a fuel, such as dry grass, duff, or saw dust, these particles can initiate spot fires by direct flaming or smoldering which can transition to a flame. These particles can be produced by processes such as welding, powerline interactions, fragments from bullet impacts, abrasive cutting, and pyrotechnics. There is little publi...

Anthraquinones and Derivatives from Marine-Derived Fungi: Structural Diversity and Selected Biological Activities

Directory of Open Access Journals (Sweden)

Mireille Fouillaud

2016-03-01

Full Text Available Anthraquinones and their derivatives constitute a large group of quinoid compounds with about 700 molecules described. They are widespread in fungi and their chemical diversity and biological activities recently attracted attention of industries in such fields as pharmaceuticals, clothes dyeing, and food colorants. Their positive and/or negative effect(s due to the 9,10-anthracenedione structure and its substituents are still not clearly understood and their potential roles or effects on human health are today strongly discussed among scientists. As marine microorganisms recently appeared as producers of an astonishing variety of structurally unique secondary metabolites, they may represent a promising resource for identifying new candidates for therapeutic drugs or daily additives. Within this review, we investigate the present knowledge about the anthraquinones and derivatives listed to date from marine-derived filamentous fungi′s productions. This overview highlights the molecules which have been identified in microorganisms for the first time. The structures and colors of the anthraquinoid compounds come along with the known roles of some molecules in the life of the organisms. Some specific biological activities are also described. This may help to open doors towards innovative natural substances.

Anthraquinones and Derivatives from Marine-Derived Fungi: Structural Diversity and Selected Biological Activities.

Science.gov (United States)

Fouillaud, Mireille; Venkatachalam, Mekala; Girard-Valenciennes, Emmanuelle; Caro, Yanis; Dufossé, Laurent

2016-03-25

Anthraquinones and their derivatives constitute a large group of quinoid compounds with about 700 molecules described. They are widespread in fungi and their chemical diversity and biological activities recently attracted attention of industries in such fields as pharmaceuticals, clothes dyeing, and food colorants. Their positive and/or negative effect(s) due to the 9,10-anthracenedione structure and its substituents are still not clearly understood and their potential roles or effects on human health are today strongly discussed among scientists. As marine microorganisms recently appeared as producers of an astonishing variety of structurally unique secondary metabolites, they may represent a promising resource for identifying new candidates for therapeutic drugs or daily additives. Within this review, we investigate the present knowledge about the anthraquinones and derivatives listed to date from marine-derived filamentous fungi's productions. This overview highlights the molecules which have been identified in microorganisms for the first time. The structures and colors of the anthraquinoid compounds come along with the known roles of some molecules in the life of the organisms. Some specific biological activities are also described. This may help to open doors towards innovative natural substances.

Usefulness Of Derivative Instruments In Emerging Markets: Turkish Experience

OpenAIRE

Cem Saatcioglu; Iskender Karagul; Ara G. Volkan

2011-01-01

This article presents an overview of derivative markets, definitions of derivative investment instruments, development of global derivative markets and the applicability of derivative markets in Turkey, given their economic value added to the Turkish economy. Readers will acquire insight into investing in various investment instruments and hedging against risk. Turkish derivative markets will be described, supportive statistical data will be presented, and readers will be introduced to the de...

Derivative financial instruments and nonprofit health care providers.

Science.gov (United States)

Stewart, Louis J; Owhoso, Vincent

2004-01-01

This article examines the extent of derivative financial instrument use among US nonprofit health systems and the impact of these financial instruments on their cash flows, reported operating results, and financial risks. Our examination is conducted through a case study of New Jersey hospitals and health systems. We review the existing literature on interest rate derivative instruments and US hospitals and health systems. This literature describes the design of these derivative financial instruments and the theoretical benefits of their use by large health care provider organizations. Our contribution to the literature is to provide an empirical evaluation of derivative financial instruments usage among a geographically limited sample of US nonprofit health systems. We reviewed the audited financial statements of the 49 community hospitals and multi-hospital health systems operating in the state of New Jersey. We found that 8 percent of New Jersey's nonprofit health providers utilized interest rate derivatives with an aggregate principle value of $229 million. These derivative users combine interest rate swaps and caps to lower the effective interest costs of their long-term debt while limiting their exposure to future interest rate increases. In addition, while derivative assets and liabilities have an immaterial balance sheet impact, derivative related gains and losses are a material component of their reported operating results. We also found that derivative usage among these four health systems was responsible for generating positive cash flows in the range of 1 percent to 2 percent of their total 2001 cash flows from operations. As a result of our admittedly limited samples we conclude that interest rate swaps and caps are effective risk management tools. However, we also found that while these derivative financial instruments are useful hedges against the risks of issuing long-term financing instruments, they also expose derivative users to credit, contract

Derivatives Trading and Negative Voting

OpenAIRE

Spamann, Holger

2012-01-01

This paper exposits a model of parallel trading of corporate securities (shares, bonds) and derivatives in which a large trader can sometimes profitably acquire securities with their corporate control rights for the sole purpose of reducing the corporations value and gaining on a net short position created through off-setting derivatives. At other times, the large trader profitably takes a net long position. The large trader requires no private information beyond its own trades. The problem i...

Year-end seasonality in one-month LIBOR derivatives

OpenAIRE

Christopher J. Neely; Drew B. Winters

2005-01-01

We examine the markets for one-month LIBOR futures contracts and options on those futures for a year-end price effect consistent with the previously identified year-end rate increase in one-month LIBOR. The cash market rate increase appears in forward rates and derivative prices, which allows the derivatives to properly hedge year-end interest rate risk. However, while the year-end effect appears in the derivative contract, these derivative contracts provide biased forecasts of both future in...

On Functional Inequalities Originating from Module Jordan Left Derivations

Directory of Open Access Journals (Sweden)

Kang Sheon-Young

2008-01-01

Full Text Available Abstract We first examine the generalized Hyers-Ulam stability of functional inequality associated with module Jordan left derivation (resp., module Jordan derivation. Secondly, we study the functional inequality with linear Jordan left derivation (resp., linear Jordan derivation mapping into the Jacobson radical.

14 CFR 1203.500 - Use of derivative classification.

Science.gov (United States)

2010-01-01

... 14 Aeronautics and Space 5 2010-01-01 2010-01-01 false Use of derivative classification. 1203.500 Section 1203.500 Aeronautics and Space NATIONAL AERONAUTICS AND SPACE ADMINISTRATION INFORMATION SECURITY PROGRAM Derivative Classification § 1203.500 Use of derivative classification. The application of...

On the gravitational seesaw in higher-derivative gravity

Energy Technology Data Exchange (ETDEWEB)

Accioly, Antonio; Giacchini, Breno L. [Centro Brasileiro de Pesquisas Fisicas, Rio de Janeiro, RJ (Brazil); Shapiro, Ilya L. [Universidade Federal de Juiz de Fora, Departamento de Fisica, ICE, Juiz de Fora, MG (Brazil); Tomsk State Pedagogical University, Tomsk (Russian Federation); Tomsk State University, Tomsk (Russian Federation)

2017-08-15

Local gravitational theories with more than four derivatives are superrenormalizable. They also may be unitary in the Lee-Wick sense. Thus it is relevant to study the low-energy properties of these theories, especially to identify observables which might be useful for experimental detection of higher derivatives. Using an analogy with the neutrino physics, we explore the possibility of a gravitational seesaw mechanism in which several dimensional parameters of the same order of magnitude produce a hierarchy in the masses of propagating particles. Such a mechanism could make a relatively light degree of freedom detectable in low-energy laboratory and astrophysical observations, such as torsion-balance experiments and the bending of light. We demonstrate that such a seesaw mechanism in the six- and more-derivative theories is unable to reduce the lightest mass more than in the simplest four-derivative model. Adding more derivatives to the four-derivative action of gravity makes heavier masses even greater, while the lightest massive ghost is not strongly affected. This fact is favorable for protecting the theory from instabilities but makes the experimental detection of higher derivatives more difficult. (orig.)

Introduction of Credit Derivatives and Valuation of Credit Default Swap

OpenAIRE

Han, Lu

2006-01-01

The credit derivative market was established at the beginning of the 1990s since the emergence of credit derivatives fits the rapid development of the whole derivatives market. However, compare to other derivative market, this market is still small and incomplete. As with other derivatives, credit derivatives can be used to either take more risk or hedge it, hence various credit derivatives instruments are accepted and widely used by market participants such as banks, insurance companies, etc...

45 CFR 1630.12 - Applicability to derivative income.

Science.gov (United States)

2010-10-01

..., regulations, guidelines, and instructions, the Accounting Guide for LSC recipients, the terms and conditions... 45 Public Welfare 4 2010-10-01 2010-10-01 false Applicability to derivative income. 1630.12... CORPORATION COST STANDARDS AND PROCEDURES § 1630.12 Applicability to derivative income. (a) Derivative income...

Haenamindole, an unusual diketopiperazine derivative from a marine-derived Penicillium sp. KCB12F005.

Science.gov (United States)

Kim, Jong Won; Ko, Sung-Kyun; Son, Sangkeun; Shin, Kee-Sun; Ryoo, In-Ja; Hong, Young-Soo; Oh, Hyuncheol; Hwang, Bang Yeon; Hirota, Hiroshi; Takahashi, Shunji; Kim, Bo Yeon; Osada, Hiroyuki; Jang, Jae-Hyuk; Ahn, Jong Seog

2015-11-15

During the chemical investigation of marine-derived fungus, an unusual diketopiperazine (DKP) alkaloid, haenamindole (1), was isolated from a culture of the marine-derived fungus Penicillium sp. KCB12F005. The structure of 1, which possesses benzyl-hydroxypiperazindione and phenyl-pyrimidoindole rings system in the molecule, was elucidated by analysis of NMR and MS data. The stereochemistry of 1 was determined by ROESY and advanced Marfey's method. Copyright © 2015 Elsevier Ltd. All rights reserved.

Inflationary models with non-minimally derivative coupling

International Nuclear Information System (INIS)

Yang, Nan; Fei, Qin; Gong, Yungui; Gao, Qing

2016-01-01

We derive the general formulae for the scalar and tensor spectral tilts to the second order for the inflationary models with non-minimally derivative coupling without taking the high friction limit. The non-minimally kinetic coupling to Einstein tensor brings the energy scale in the inflationary models down to be sub-Planckian. In the high friction limit, the Lyth bound is modified with an extra suppression factor, so that the field excursion of the inflaton is sub-Planckian. The inflationary models with non-minimally derivative coupling are more consistent with observations in the high friction limit. In particular, with the help of the non-minimally derivative coupling, the quartic power law potential is consistent with the observational constraint at 95% CL. (paper)

Derivative pricing based on local utility maximization

OpenAIRE

Jan Kallsen

2002-01-01

This paper discusses a new approach to contingent claim valuation in general incomplete market models. We determine the neutral derivative price which occurs if investors maximize their local utility and if derivative demand and supply are balanced. We also introduce the sensitivity process of a contingent claim. This process quantifies the reliability of the neutral derivative price and it can be used to construct price bounds. Moreover, it allows to calibrate market models in order to be co...

Deriváty a rodinné finance

OpenAIRE

Varecha, Martin

2010-01-01

This thesis focuses on the derivatives market. The goal is to choose ones that are suitable for use for the benefit of family finances and planning. Mapping the world market derivatives, and then describes the basic characteristics of the main types of contracts. After the general characteristics of the derivatives in the introduction, are briefly described two types (forwads and swaps) that are not directly used in the family finances. In their description, however, are pointed out the funda...

Carnitine derivatives: clinical usefulness.

Science.gov (United States)

Malaguarnera, Mariano

2012-03-01

Carnitine and its derivatives are natural substances involved in both carbohydrate and lipid metabolism. This review summarizes the recent progress in the field in relation to the molecular mechanisms. The pool of different carnitine derivatives is formed by acetyl-L-carnitine (ALC), propionyl-L-carnitine (PLC), and isovaleryl-carnitine. ALC may have a preferential effect on the brain tissue. ALC represents a compound of great interest for its wide clinical application in various neurological disorders: it may be of benefit in treating Alzheimer's dementia, depression in the elderly, HIV infection, chronic fatigue syndrome, peripheral neuropathies, ischemia and reperfusion of the brain, and cognitive impairment associated with various conditions. PLC has been demonstrated to replenish the intermediates of the tricarboxylic acid cycle by the propionyl-CoA moiety, a greater affinity for the sarcolemmal carrier, peripheral vasodilator activity, a greater positive inotropism, and more rapid entry into myocytes. Most studies of the therapeutic use of PLC are focused on the prevention and treatment of ischemic heart disease, congestive heart failure, hypertrophic heart disease, and peripheral arterial disease. ALC and PLC are considered well tolerated without significant side-effects. A number of therapeutic effects possibly come from the interaction of carnitine and its derivatives with the elements of cellular membranes.

Derivative spectrophotometry applied to solutions of complex composition

International Nuclear Information System (INIS)

Perfil'ev, V.A.

1986-01-01

The authors consider not only the basic principles of derivative spectrophotometry but also survey the data on its use in research on the properties of materials, the compositions of compounds, and the structures of complex chemical systems. Recording methods by which derivative spectra can be generated include descriptions of electronic differentiation, computer spectrum differentiation, wavelength modulation, and the two-way derivative method. A section on the advantages of derivative spectrophotometry presents a discussion on features enabling one to determine various substances from their characteristic absorption spectra without performing complicated operations to isolate or separate the components. Other topics include research on the structures of substances and metal-ion complexing in solutions, derivative spectrophotometry in gas analysis, gas determination, and determining organic and compounds

Bounded Densities and Their Derivatives

DEFF Research Database (Denmark)

Kozine, Igor; Krymsky, V.

2009-01-01

This paper describes how one can compute interval-valued statistical measures given limited information about the underlying distribution. The particular focus is on a bounded derivative of a probability density function and its combination with other available statistical evidence for computing ...... quantities of interest. To be able to utilise the evidence about the derivative it is suggested to adapt the ‘conventional’ problem statement to variational calculus and the way to do so is demonstrated. A number of examples are given throughout the paper....

Hydroxyurea derivatives of irofulven with improved antitumor efficacy.

Science.gov (United States)

Staake, Michael D; Kashinatham, Alisala; McMorris, Trevor C; Estes, Leita A; Kelner, Michael J

2016-04-01

Irofulven is a semi-synthetic derivative of Illudin S, a toxic sesquiterpene isolated from the mushroom Omphalotus illudens. Irofulven has displayed significant antitumor activity in various clinical trials but displayed a limited therapeutic index. A new derivative of irofulven was prepared by reacting hydroxyurea with irofulven under acidic conditions. Acetylation of this new compound with acetic anhydride produced a second derivative. Both of these new derivatives displayed significant antitumor activity in vitro and in vivo comparable to or exceeding that of irofulven. Copyright © 2016 Elsevier Ltd. All rights reserved.

21 CFR 184.1317 - Garlic and its derivatives.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Garlic and its derivatives. 184.1317 Section 184... Listing of Specific Substances Affirmed as GRAS § 184.1317 Garlic and its derivatives. (a) Garlic is the... derivatives include essential oils, oleo-resins, and natural extractives obtained from garlic. (b) Garlic oil...

Radiological protection optimization using derivatives

International Nuclear Information System (INIS)

Freitas Acosta Perez, C. de; Sordi, G.M.A.A.

2006-01-01

The aim of this paper is to provide a different approach related to the integral cost-benefit and extended cost-benefit analysis used in the decision-aiding techniques. In the ICRP publication 55 the annual protection cost is envisaged as a set of points, each of them representing an option, linked by a straight line. The detriment cost function is considered a linear function whose angular coefficient is determined by the alpha value. In this paper the uranium mine example considered in the ICRP publication 55 was used. But the potential curve was introduced both in the integral cost benefit analysis and in the extended cost-benefit analysis, which the individual dose distribution attribute is added. The result was obtained using derivatives. The detriment cost, Y, is not necessary because the alpha value is known. The Y derivative dS/dY is the alpha value itself and so, the attention is directed to the derivative -dX/dS on the points that, along with the alpha value, present the optimum option. The results makes clear that the prevailing factor in the optimum option selection is the alpha value imputed, and those a single alpha value, as suggested now, probably as little efficiency on the optimization process. Obtaining a curve for the alpha value and using the derivative technique introduced in this paper, the analytical solution is more convenient and reliable compared to the one used now. (authors)

17 CFR 240.16b-6 - Derivative securities.

Science.gov (United States)

2010-04-01

... 17 Commodity and Securities Exchanges 3 2010-04-01 2010-04-01 false Derivative securities. 240.16b... Exchange Act of 1934 Exemption of Certain Transactions from Section 16(b) § 240.16b-6 Derivative securities...). Note to paragraph (b): The exercise or conversion of a derivative security that does not satisfy the...

Deriving Case, Agreement and Voice Phenomena in Syntax

Science.gov (United States)

Sigurdsson, Einar Freyr

2017-01-01

This dissertation places case, agreement and Voice phenomena in syntax. It argues that the derivation is driven by so-called derivational features, that is, structure-building features (Merge) and probe features (Agree) (Heck and Muller 2007 and Muller 2010; see also Chomsky 2000, 2001). Both types are essential in deriving case and agreement in…

LCCT-derived three-level three-phase inverters

DEFF Research Database (Denmark)

Shults, Tatiana; Husev, Oleksandr; Blaabjerg, Frede

2017-01-01

Solutions for a family of the novel three-level neutral-point-clamped (NPC) inductor-capacitor-capacitor-transformer (LCCT)-derived three-phase inverters are described and compared. Component design guidelines and steady state analysis, current and voltage waveforms are given. The authors......' simulation results confirm the theoretical predictions. It was found that an asymmetrical three-level NPC LCCT-derived inverter with a single diode in the impedance source network is the most promising solution. Experimental results for an asymmetrical three-level NPC LCCT-derived inverter with a single...

Effects of sulfate chitosan derivatives on nonalcoholic fatty liver disease

Science.gov (United States)

Yu, Mingming; Wang, Yuanhong; Jiang, Tingfu; Lv, Zhihua

2014-06-01

Sulfate chitosan derivatives have good solubility and therapeutic effect on the cell model of NAFLD. The aim of this study was to examine the therapeutic effect of sulfate chitosan derivatives on NAFLD. The male Wistar rats were orally fed high fat emulsion and received sulfate chitosan derivatives for 5 weeks to determine the pre-treatment effect of sulfate chitosan derivatives on NAFLD. To evaluate the therapeutic effect of sulfate chitosan derivatives on NAFLD, the rats were orally fed with high concentration emulsion for 5 weeks, followed by sulfate chitosan derivatives for 3 weeks. Histological analysis and biomedical assays showed that sulfate chitosan derivatives can dramatically prevent the development of hepatic steatosis in hepatocyte cells. In animal studies, pre-treatment and treatment with sulfate chitosan derivatives significantly protected against hepatic steatohepatitis induced by high fat diet according to histological analysis. Furthermore, increased TC, ALT, MDA, and LEP in NAFLD were significantly ameliorated by pre-treatment and treatment with sulfate chitosan derivatives. Furthermore, increased TG, AST, and TNF-α in NAFLD were significantly ameliorated by treatment with sulfate chitosan derivatives. Sulfate chitosan derivatives have good pre-treatment and therapeutic effect on NAFLD.

Analytical application of derivative spectrophotometry

Directory of Open Access Journals (Sweden)

VIOLETA M. STEFANOVIC

2000-07-01

Full Text Available 1. Introduction 2. Basic characteristics of derivative spectrophotometry 2.1. Increase of spectra resolution 2.2. Elimination of the influence of baseline shift and matrix interferences 2.3. Enhancement of the detectability of minor spectral features 2.4. Precise determination of the positions of absorption maxima 2.5. Signal-to-noise ratio (SNR 2.6. Quantitative analysis 3. Analytical applications 3.1. Inorganic analysis 3.2. Organic and pharmaceutical analysis 3.3. Analysis of food and water 3.4. Application of derivative spectrophotometry for the determination of equilibrium constants

Fire protection for clean rooms

International Nuclear Information System (INIS)

Kirson, D.

1990-01-01

The fire protection engineer often must decide what size fire can be tolerated before automatic fire suppression systems actuate. Is it a wastepaper basket fire, a bushel basket fire...? In the case of state-of-the-art clean rooms, the answer clearly is not even an incipient fire. Minor fires in clean rooms can cause major losses. This paper discusses what a clean room is and gives a brief overview of the unique fire protection challenges encountered. The two major causes of fire related to clean rooms in the semiconductor industry are flammable/pyrophoric gas fires in plastic ducts and polypropylene wet bench fires. This paper concentrates on plastic ductwork in clean rooms, sprinkler protection in ductwork, and protection for wet benches

Optimization of a water-gas shift reactor over a Pt/ceria/alumina monolith

Energy Technology Data Exchange (ETDEWEB)

Quiney, A.S.; Germani, G.; Schuurman, Y. [Institut de Recherches sur la Catalyse-CNRS, 2 Avenue A. Einstein, 69626 Villeurbanne (France)

2006-10-06

The water-gas shift (WGS) reaction is an important step in the purification of hydrogen for fuel cells. It lowers the carbon monoxide content and produces extra hydrogen. The constraints of automotive applications render the commercial WGS catalysts unsuitable. Pt/ceria catalysts are cited as promising catalysts for onboard applications as they are highly active and non-pyrophoric. This paper reports on a power law rate expression for a Pt/CeO{sub 2}/Al{sub 2}O{sub 3} catalyst. This rate equation is used to compare different reactor configurations for an onboard water-gas shift reactor. A one-dimensional heterogeneous model that accounts for the interfacial and intraparticle gradients has been used to optimize a dual stage adiabatic monolith reactor. (author)

Unprecedented selective aminolysis: Aminopropyl phosphine as a building block for a new family of air stable mono-, bis-, and tris-primary phosphines

Energy Technology Data Exchange (ETDEWEB)

Prabhu, K.R.; Pillarsetty, N.; Gali, H.; Katti, K.V.

2000-02-23

A serious impediment to using primary and secondary phosphines as general-purpose reagents to develop new chemistry is associated with their unpleasant pyrophoric nature and extreme hydrolytic, thermal, and oxidative instabilities. In particular, primary phosphines with ``user friendly'' properties (e.g., good oxidative/thermal stability, low volatility) would be extremely important not only from the synthetic point of view but also for potential application (e.g., in dendrimers formation). As part of ongoing research on the fundamental main group and organic chemistry of functionalized phosphorus compounds, the authors report, herein, unprecedented selectivity in the reaction of 3-aminopropyl primary phosphine 3, with the methyl ester in the presence of free acid, amide, and thiol to produce air stable amide, carboxylate, and thiol functionalized primary phosphines.

DNA-Compatible Nitro Reduction and Synthesis of Benzimidazoles.

Science.gov (United States)

Du, Huang-Chi; Huang, Hongbing

2017-10-18

DNA-encoded chemical libraries have emerged as a cost-effective alternative to high-throughput screening (HTS) for hit identification in drug discovery. A key factor for productive DNA-encoded libraries is the chemical diversity of the small molecule moiety attached to an encoding DNA oligomer. The library structure diversity is often limited to DNA-compatible chemical reactions in aqueous media. Herein, we describe a facile process for reducing aryl nitro groups to aryl amines. The new protocol offers simple operation and circumvents the pyrophoric potential of the conventional method (Raney nickel). The reaction is performed in aqueous solution and does not compromise DNA structural integrity. The utility of this method is demonstrated by the versatile synthesis of benzimidazoles on DNA.

Leghemoglobin-derived radicals. Evidence for multiple protein-derived radicals and the initiation of peribacteroid membrane damage

DEFF Research Database (Denmark)

Moreau, S; Davies, Michael Jonathan; Mathieu, C

1996-01-01

, with the consequent generation of lipid-derived radicals. The formation of such radicals may result in the depletion of membrane antioxidants and the initiation of lipid peroxidation. This transfer of damage from the heme center via the protein surface to neighboring membranes may be of considerable biological......-derived phenoxyl radical present at Tyr-133 in the soybean protein and Tyr-138 in the lupin protein. To obtain further information on these protein radicals and their potential interaction with the physiologically important peribacteroid membrane (which surrounds the microsymbiont in vivo), EPR spin trapping......); these radicals may be side chain- or alpha-carbon-derived, their exact sites have not been determined. Some of these radicals are on the protein surface and may be key intermediates in the formation of protein dimers. These radicals have been shown to be capable of reacting with peribacteroid membrane fractions...

Penetratin and derivatives acting as antifungal agents

NARCIS (Netherlands)

Masman, Marcelo F.; Rodriguez, Ana M.; Raimondi, Marcela; Zacchino, Susana A.; Luiten, Paul G. M.; Somlai, Csaba; Kortvelyesi, Tamas; Penke, Botond; Enriz, Ricardo D.

The synthesis, in vitro evaluation, and conformational study of RQIKTWFQNRRMKWKK-NH(2) (penetratin) and related derivatives acting as antifungal agents are reported. Penetratin and some of its derivatives displayed antifungal activity against the human opportunistic pathogenic standardized ATCC

Synthesis and Antimicrobial Activities of Some Novel Quinoxalinone Derivatives

Directory of Open Access Journals (Sweden)

Y. A. Ammar

2000-06-01

Full Text Available Condensation of 4-benzoyl-1,2-phenylenediamine with sodium pyruvate in acetic acid furnished two products which were identified as 6-benzoyl and 7-benzoyl-3-methyl-2(1Hquinoxalinones (1a,b. Fusion of 1a with aromatic aldehydes furnished the styryl derivatives 2a-c. Alkylation of 1a,b with dimethyl sulphate or ethyl chloroacetate produced the N-alkyl derivatives 3a,b and 4a,b. Hydrazinolysis of the ester derivative 4a with hydrazine hydrate afforded the hydrazide derivative 5 which underwent condensation with aldehydes to give the corresponding hydrazone derivatives 6a,b. In addition, chlorination of 1a with thionyl chloride afforded the 2-chloro derivative 7 which was subjected to reaction with sodium azide and n-butylamine to yield the corresponding tetrazolo (8 and n-butylamino (9 derivatives, respectively. The structures of the compounds prepared were confirmed by analytical and spectral data. Also, some of the synthesized compounds were screened for antimicrobial activity.

Synthesis of Lipophilic Guanine N-9 Derivatives

DEFF Research Database (Denmark)

Wamberg, Michael C; Pedersen, Pernille L; Löffler, Philipp M G

2017-01-01

the synthesis of five new guanine-N9 derivatives bearing alkyl chains with different attachment chemistries, exploiting a synthesis pathway that allows a flexible choice of hydrophobic anchor moiety. In this study, these guanine derivatives were functionalized with C10 chains for insertion into decanoic acid...... bilayer structures, in which both alkyl chain length and attachment chemistry determined their interaction with the membrane. Incubation of these guanine conjugates, as solids, with a decanoic acid vesicle suspension, showed that ether- and triazole-linked C10 anchors yielded an increased partitioning...... of the guanine derivative into the membranous phase compared to directly N-9-linked saturated alkyl anchors. Decanoic acid vesicle membranes could be loaded with up to 5.5 mol % guanine derivative, a 6-fold increase over previous limits. Thus, anchor chemistries exhibiting favorable interactions with a bilayer...

Derivation of GFDM Based on OFDM Principles

Energy Technology Data Exchange (ETDEWEB)

Hussein Moradi; Behrouz Farhang-Boroujeny

2015-06-01

This paper starts with discussing the principle based on which the celebrated orthogonal frequency division multiplexing (OFDM) signals are constructed. It then extends the same principle to construct the newly introduced generalized frequency division multiplexing (GFDM) signals. This novel derivation sheds light on some interesting properties of GFDM. In particular, our derivation seamlessly leads to an implementation of GFDM transmitter which has significantly lower complexity than what has been reported so far. Our derivation also facilitates a trivial understanding of how GFDM (similar to OFDM) can be applied in MIMO channels.

Mechanism of Platinum Derivatives Induced Kidney Injury

Directory of Open Access Journals (Sweden)

Feifei YAN

2015-09-01

Full Text Available Platinum derivatives are the most widely used chemotherapeutic agents to treat solid tumors including ovarian, head and neck, and testicular germ cell tumors, lung cancer, and colorectal cancer. Two major problems exist, however, in the clinic use of platinum derivatives. One is the development of tumor resistance to the drug during therapy, leading to treatment failure. The other is the drug’s toxicity such as the cisplatin’s nephrotoxicity, which limits the dose that can be administered. This paper describes the mechanism of platinum derivatives induced kidney injury.

Ineffective higher derivative black hole hair

Science.gov (United States)

Goldstein, Kevin; Mashiyane, James Junior

2018-01-01

Inspired by the possibility that the Schwarzschild black hole may not be the unique spherically symmetric vacuum solution to generalizations of general relativity, we consider black holes in pure fourth order higher derivative gravity treated as an effective theory. Such solutions may be of interest in addressing the issue of higher derivative hair or during the later stages of black hole evaporation. Non-Schwarzschild solutions have been studied but we have put earlier results on a firmer footing by finding a systematic asymptotic expansion for the black holes and matching them with known numerical solutions obtained by integrating out from the near-horizon region. These asymptotic expansions can be cast in the form of trans-series expansions which we conjecture will be a generic feature of non-Schwarzschild higher derivative black holes. Excitingly we find a new branch of solutions with lower free energy than the Schwarzschild solution, but as found in earlier work, solutions only seem to exist for black holes with large curvatures, meaning that one should not generically neglect even higher derivative corrections. This suggests that one effectively recovers the nonhair theorems in this context.

Ferroquine and its derivatives: new generation of antimalarial agents.

Science.gov (United States)

Wani, Waseem A; Jameel, Ehtesham; Baig, Umair; Mumtazuddin, Syed; Hun, Lee Ting

2015-08-28

Malaria has been teasing human populations from a long time. Presently, several classes of antimalarial drugs are available in market, but the issues of toxicity, lower efficacy and the resistance by malarial parasites have decreased their overall therapeutic indices. Thus, the search for new promising antimalarials continues, however, the battle against malaria is far from over. Ferroquine is a derivative of chloroquine with antimalarial properties. It is the most successful of the chloroquine derivatives. Not only ferroquine, but also its derivatives have shown promising potential as antimalarials of clinical interest. Presently, much research is dedicated to the development of ferroquine derivatives as safe alternatives to antimalarial chemotherapy. The present article describes the structural, chemical and biological features of ferroquine. Several classes of ferroquine derivatives including hydroxyferroquines, trioxaferroquines, chloroquine-bridged ferrocenophanes, thiosemicarbazone derivatives, ferrocene dual conjugates, 4-N-substituted derivatives, and others have been discussed. Besides, the mechanism of action of ferroquine has been discussed. A careful observation has been made into pharmacologically significant ferroquine derivatives with better or equal therapeutic effects to that of chloroquine and ferroquine. A brief discussion of the toxicities of ferroquine derivatives has been made. Finally, efforts have been made to discuss the current challenges and future perspectives of ferroquine-based antimalarial drug development. Copyright © 2015 Elsevier Masson SAS. All rights reserved.

Neutralising ordnance with non-extending elements

Directory of Open Access Journals (Sweden)

Alexander I. Golodyaev

2014-04-01

Full Text Available The method of neutralising ordnance by rinsing explosive materials with a solution enables significant cost saving while reducing the risk pyrotechnic personnel is exposed to, especially during ammunition transport to recycling sites.  Costs for necessary special equipment are minimal. The technology is easy to be automated using an electronic and remotely controlled drilling process which reduces the risk of explosion to the minimum. This demining method will prove effective especially for operations against guerrilla mine warfare.

Residual stresses estimation in tubes after rapid heating of surface

International Nuclear Information System (INIS)

Serikov, S.V.

1992-01-01

Results are presented on estimation of residual stresses in tubes of steel types ShKh15, EhP836 and 12KIMF after heating by burning pyrotechnic substance inside tubes. External tube surface was heated up to 400-450 deg C under such treatment. Axial stresses distribution over tube wall thickness was determined for initial state, after routine heat treatment and after heating with the use of fireworks. Inner surface heating was shown to essentially decrease axial stresses in tubes

Ultraweak Continuity of σ-derivations on von Neumann Algebras

International Nuclear Information System (INIS)

Mirzavaziri, Madjid; Moslehian, Mohammad Sal

2009-01-01

Let σ be a surjective ultraweakly continuous *-linear mapping and d be a σ-derivation on a von Neumann algebra. We show that there are a surjective ultraweakly continuous *-homomorphism and a Σ-derivation such that D is ultraweakly continuous if and only if so is d. We use this fact to show that the σ-derivation d is automatically ultraweakly continuous. We also prove the converse in the sense that if σ is a linear mapping and d is an ultraweakly continuous *-σ-derivation, then there is an ultraweakly continuous linear mapping such that d is a *-Σ-derivation

Systemic T Cells Immunosuppression of Glioma Stem Cell-Derived Exosomes Is Mediated by Monocytic Myeloid-Derived Suppressor Cells.

Directory of Open Access Journals (Sweden)

Rossana Domenis

Full Text Available A major contributing factor to glioma development and progression is its ability to evade the immune system. Nano-meter sized vesicles, exosomes, secreted by glioma-stem cells (GSC can act as mediators of intercellular communication to promote tumor immune escape. Here, we investigated the immunomodulatory properties of GCS-derived exosomes on different peripheral immune cell populations. Healthy donor peripheral blood mononuclear cells (PBMCs stimulated with anti-CD3, anti-CD28 and IL-2, were treated with GSC-derived exosomes. Phenotypic characterization, cell proliferation, Th1/Th2 cytokine secretion and intracellular cytokine production were analysed by distinguishing among effector T cells, regulatory T cells and monocytes. In unfractionated PBMCs, GSC-derived exosomes inhibited T cell activation (CD25 and CD69 expression, proliferation and Th1 cytokine production, and did not affect cell viability or regulatory T-cell suppression ability. Furthermore, exosomes were able to enhance proliferation of purified CD4+ T cells. In PBMCs culture, glioma-derived exosomes directly promoted IL-10 and arginase-1 production and downregulation of HLA-DR by unstimulated CD14+ monocytic cells, that displayed an immunophenotype resembling that of monocytic myeloid-derived suppressor cells (Mo-MDSCs. Importantly, the removal of CD14+ monocytic cell fraction from PBMCs restored T-cell proliferation. The same results were observed with exosomes purified from plasma of glioblastoma patients. Our results indicate that glioma-derived exosomes suppress T-cell immune response by acting on monocyte maturation rather than on direct interaction with T cells. Selective targeting of Mo-MDSC to treat glioma should be considered with regard to how immune cells allow the acquirement of effector functions and therefore counteracting tumor progression.

Higher derivative regularization and chiral anomaly

International Nuclear Information System (INIS)

Nagahama, Yoshinori.

1985-02-01

A higher derivative regularization which automatically leads to the consistent chiral anomaly is analyzed in detail. It explicitly breaks all the local gauge symmetry but preserves global chiral symmetry and leads to the chirally symmetric consistent anomaly. This regularization thus clarifies the physics content contained in the consistent anomaly. We also briefly comment on the application of this higher derivative regularization to massless QED. (author)

Mass Spectrometric Characteristics of Prenylated Indole Derivatives from Marine-Derived Penicillium sp. NH-SL.

Science.gov (United States)

Ding, Hui; Ding, Wanjing; Ma, Zhongjun

2017-03-22

Two prenylated indole alkaloids were isolated from the ethyl acetate extracts of a marine-derived fungus Penicillium sp. NH-SL and one of them exhibited potent cytotoxic activity against mouse hepa 1c1c7 cells. In order to detect other bioactive analogs, we used liquid chromatogram tandem mass spectrometry (LC-MS/MS) to analyze the mass spectrometric characteristics of the isolated compounds as well as the crude extracts. As a result, three other analogs were detected, and their structures were deduced according to the similar fragmentation patterns. This is the first systematic report on the mass spectrometric characteristics of prenylated indole derivatives.

Derivation of Hamiltonians for accelerators

Energy Technology Data Exchange (ETDEWEB)

Symon, K.R.

1997-09-12

In this report various forms of the Hamiltonian for particle motion in an accelerator will be derived. Except where noted, the treatment will apply generally to linear and circular accelerators, storage rings, and beamlines. The generic term accelerator will be used to refer to any of these devices. The author will use the usual accelerator coordinate system, which will be introduced first, along with a list of handy formulas. He then starts from the general Hamiltonian for a particle in an electromagnetic field, using the accelerator coordinate system, with time t as independent variable. He switches to a form more convenient for most purposes using the distance s along the reference orbit as independent variable. In section 2, formulas will be derived for the vector potentials that describe the various lattice components. In sections 3, 4, and 5, special forms of the Hamiltonian will be derived for transverse horizontal and vertical motion, for longitudinal motion, and for synchrobetatron coupling of horizontal and longitudinal motions. Hamiltonians will be expanded to fourth order in the variables.

Investigation - Derived Waste Program

International Nuclear Information System (INIS)

Beardsley, C.; Anderson, R.

1998-06-01

The Investigation-Derived Waste Program is a software application that was developed to identify the groundwater monitoring wells at the Savannah River Site that require containerization and treatment for purge water generated during sampling

Structure-activity relationships of bumetanide derivatives

DEFF Research Database (Denmark)

Pedersen, Kasper Lykke; Töllner, Kathrin; Römermann, Kerstin

2015-01-01

of diuretics such as bumetanide. Bumetanide was discovered by screening ∼5000 3-amino-5-sulfamoylbenzoic acid derivatives, long before NKCC2 was identified in the kidney. Therefore, structure-activity studies on effects of bumetanide derivatives on NKCC2 are not available. EXPERIMENTAL APPROACH: In this study......, the effect of a series of diuretically active bumetanide derivatives was investigated on human NKCC2 variant A (hNKCC2A) expressed in Xenopus laevis oocytes. KEY RESULTS: Bumetanide blocked hNKCC2A transport with an IC50 of 4 μM. There was good correlation between the diuretic potency of bumetanide and its...... of the structural requirements that determine relative potency of loop diuretics on human NKCC2 splice variants, and may lead to the discovery of novel high-ceiling diuretics....

Derivative Securities and Financial Crisis in Romania

OpenAIRE

Gogoncea Ramona

2012-01-01

This paper aims to investigate the impact of the global financial crisis on the young Romanian market of derivative securities. It also describes the recent developments within Romanian capital market, in general, with focus on innovation in the field of derivative products.

Acquisition of noun derivation in Estonian and Russian L1

Directory of Open Access Journals (Sweden)

Reili Argus

2018-04-01

Full Text Available Acquisition of derivation is not a well-studied area in first language research and a comparative approach to the acquisition of derivation in different languages doesn’t exist. There is no information on how a child acquires derivation in a language with a rich and regular system of derivational patterns, or in a language where derivation is productive, but the system of derivational patterns is opaque. According to general ideas of complexity in a language, the child should start to use simplex stems first and, only after that, complex ones, that is, complexity should increase in the course of acquisition. Our paper is intended to address these issues, based on longitudinal child data from typologically different languages, Estonian and Russian. The results revealed significant differences in the acquisition of noun derivation in the two languages under observation. The system of noun derivation is acquired at a faster pace in Russian, while Estonian children have far fewer noun derivatives in their speech and they use different derivation suffixes with less regularity. Even so, the so-called building block model may be applied for both languages only partially.

Synthesis of specific deuterium labeled tyrosine and phenylalanine derivatives and their use in the total synthesis of [8-arginine]vasopressin derivatives: the separation of diastereomeric [8-arginine]vasopressin derivatives by partition chromatography

International Nuclear Information System (INIS)

Yamamoto, D.M.; Upson, D.A.; Linn, D.K.; Hruby, V.J.

1977-01-01

Derivatives of tyrosine specifically deuterated at the α carbon ([α- 2 H 1 ]tyrosine) and at both the α and β carbons ([α,β,β- 2 H 3 ]tyrosine) and a derivative of phenylalanine specifically deuterated at the α carbon ([α- 2 H 1 ]phenylalanine) have been synthesized in high yield. These labeled compounds have been resolved enzymatically, and the enantiomers and racemates have been converted to N-tert-butyloxycarbonyl derivatives. The deuterium labels were not exchanged under the conditions of the syntheses. The protected derivatives as well as specifically deuterated derivatives of S-benzylcysteine and of glycine were used to prepare specifically deuterated analogues of [8-arginine] vasopressin using solid phase peptide procedures. The use of improved synthetic procedures resulted in considerable improvements in the yields of [8-arginine]vasopressin compared with previous reports. In addition, new solvent systems for partition chromatography purification of [8-arginine]vasopressin on Sephadex were developed which allowed a facile one-step separation of diastereomers of [8-arginine]vasopressin containing a racemic amino acid at either the 1-hemicystine or the 2-tyrosine positions of the hormone

Platelet-derived stromal cell-derived factor-1 is required for the transformation of circulating monocytes into multipotential cells.

Directory of Open Access Journals (Sweden)

Noriyuki Seta

Full Text Available BACKGROUND: We previously described a primitive cell population derived from human circulating CD14(+ monocytes, named monocyte-derived multipotential cells (MOMCs, which are capable of differentiating into mesenchymal and endothelial lineages. To generate MOMCs in vitro, monocytes are required to bind to fibronectin and be exposed to soluble factor(s derived from circulating CD14(- cells. The present study was conducted to identify factors that induce MOMC differentiation. METHODS: We cultured CD14(+ monocytes on fibronectin in the presence or absence of platelets, CD14(- peripheral blood mononuclear cells, platelet-conditioned medium, or candidate MOMC differentiation factors. The transformation of monocytes into MOMCs was assessed by the presence of spindle-shaped adherent cells, CD34 expression, and the potential to differentiate in vitro into mesenchymal and endothelial lineages. RESULTS: The presence of platelets or platelet-conditioned medium was required to generate MOMCs from monocytes. A screening of candidate platelet-derived soluble factors identified stromal cell-derived factor (SDF-1 as a requirement for generating MOMCs. Blocking an interaction between SDF-1 and its receptor CXCR4 inhibited MOMC generation, further confirming SDF-1's critical role in this process. Finally, circulating MOMC precursors were found to reside in the CD14(+CXCR4(high cell population. CONCLUSION: The interaction of SDF-1 with CXCR4 is essential for the transformation of circulating monocytes into MOMCs.

Syntheses and spectral studies of novel ciprofloxacin derivatives

Directory of Open Access Journals (Sweden)

Pradeep Yadav

2008-12-01

Full Text Available Reaction of 1-cyclopropyl-6-fluoro-4-oxo-7-(piperazin-1-yl-1,4-dihydroquinoline-3-carboxylic acid (ciprofloxacin with thiazole/benzothiazole diazonium chloride afforded piperazine substituted ciprofloxacin derivative. The acid part of these derivatives was further condensed with various β-diketones to get 1-cyclopropyl-6-fluoro-4-oxo-7-(4-(thiazol-2-yldiazenylpiperazin-1-yl-1,4-dihydroquinoline-3-carboxylic acid derivatives (5a-e and 7-(4-(benzo[d]thiazol-2-yldiazenylpiperazin-1-yl-1-cyclopropyl-6-fluoro-4-oxo-1,4-dihydroquinoline-3-carboxylic acid derivatives (5f-j. Structures of these compounds were established on the basis of spectral studies.

Superstability of Generalized Derivations

Directory of Open Access Journals (Sweden)

Ansari-Piri Esmaeil

2010-01-01

Full Text Available We investigate the superstability of the functional equation , where and are the mappings on Banach algebra . We have also proved the superstability of generalized derivations associated to the linear functional equation , where .

Synthesis of 2-phosphaadamantane derivatives

International Nuclear Information System (INIS)

Zemlyanoi, V.N.; Aleksandrov, A.M.; Kukhar', V.P.

1986-01-01

The authors describe the synthesis and properties of 2-phosphadamantane derivatives. For the synthesis of 2-phosphaadamantane derivatives they decided to use the methodology of the synthesis of 2-thiaadamantane. The IR spectra were determined on CHCl 3 solutions with a Specord 711R spectrometer, the PMR spectra were determined on Tesla BS-467 (60 MHz) and Bruker WP-200 (200 MHz) spectrometers, external standard hexamethyldisiloxane, the 31 P NMR spectra were determined on Tesla BS-487 C (30 MHz) and Bruker WP-200 (81 MHz) spectrometers, external standard 85% phosphoric acid, and the mass spectra were determined on an MS-1302 spectrometer

Risk Factors in Derivatives Markets

Directory of Open Access Journals (Sweden)

Raimonda Martinkutė-Kaulienė

2015-02-01

Full Text Available The objective of the article is to analyse and present the classification of risks actual to derivative securities. The analysis is based on classical and modern literature findings and analysis of newest statistical data. The analysis led to the conclusion, that the main risks typical for derivatives contracts and their traders are market risk, liquidity risk, credit and counterparty risk, legal risk and transactions risk. Pricing risk and systemic risk is also quite important. The analysis showed that market risk is the most important kind of risk that in many situations influences the level of remaining risks.

Recent updates on lignocellulosic biomass derived ethanol - A review

Directory of Open Access Journals (Sweden)

Rajeev Kumar

2016-03-01

Full Text Available Lignocellulosic (or cellulosic biomass derived ethanol is the most promising near/long term fuel candidate. In addition, cellulosic biomass derived ethanol may serve a precursor to other fuels and chemicals that are currently derived from unsustainable sources and/or are proposed to be derived from cellulosic biomass. However, the processing cost for second generation ethanol is still high to make the process commercially profitable and replicable. In this review, recent trends in cellulosic biomass ethanol derived via biochemical route are reviewed with main focus on current research efforts that are being undertaken to realize high product yields/titers and bring the overall cost down.

18 CFR 367.2440 - Account 244, Derivative instrument liabilities.

Science.gov (United States)

2010-04-01

..., Derivative instrument liabilities. This account must include the change in the fair value of all derivative instrument liabilities not designated as cash flow or fair value hedges. Account 426.5, Other deductions... the fair value of the derivative instrument. ...

On derived groups of division rings II

International Nuclear Information System (INIS)

Mahdavi Hezavehi, M.; Akbari Feyzaabaadi, S.; Mehraabaadi, M.; Hajie Abolhassan, H.

1995-05-01

Let D be a division ring with centre F and denote by D' the derived group (commutator subgroup) of D * = D - {0}. It is shown that if each element of D' is algebraic over F, then D is algebraic over F. It is also proved that each finite separable extension of F in D is of the form F(c) for some element c in the derived group D'. Using these results, it is shown that if each element of the derived group D' is of bounded degree over F, then D is finite dimensional over F. (author). 5 refs

First Total Syntheses and Antimicrobial Evaluation of Penicimonoterpene, a Marine-Derived Monoterpenoid, and Its Various Derivatives

Directory of Open Access Journals (Sweden)

Jian-Chun Zhao

2014-06-01

Full Text Available The first total synthesis of marine-derived penicimonoterpene (±-1 has been achieved in four steps from 6-methylhept-5-en-2-one using a Reformatsky reaction as the key step to construct the basic carbon skeleton. A total of 24 new derivatives of 1 have also been designed and synthesized. Their structures were characterized by analysis of their 1H NMR, 13C NMR and HRESIMS data. Some of them showed significant antibacterial activity against Aeromonas hydrophila, Escherichia coli, Micrococcus luteus, Staphylococcus aureus, Vibrio anguillarum, V. harveyi and/or V. parahaemolyticus, and some showed activity against plant-pathogenic fungi (Alternaria brassicae, Colletotrichum gloeosporioides and/or Fusarium graminearum. Some of the derivatives exhibited antimicrobial MIC values ranging from 0.25 to 4 μg/mL, which were stronger than those of the positive control. Notably, Compounds 3b and 10 showed extremely high selectively against plant-pathogenic fungus F. graminearum (MIC 0.25 μg/mL and pathogenic bacteria E. coli (MIC 1 μg/mL, implying their potential as antimicrobial agents. SAR analysis of 1 and its derivatives indicated that modification of the carbon-carbon double bond at C-6/7, of groups on the allylic methylene unit and of the carbonyl group at C-1, effectively enhanced the antimicrobial activity.

Comparison Of Quantitative Precipitation Estimates Derived From Rain Gauge And Radar Derived Algorithms For Operational Flash Flood Support.

Science.gov (United States)

Streubel, D. P.; Kodama, K.

2014-12-01

To provide continuous flash flood situational awareness and to better differentiate severity of ongoing individual precipitation events, the National Weather Service Research Distributed Hydrologic Model (RDHM) is being implemented over Hawaii and Alaska. In the implementation process of RDHM, three gridded precipitation analyses are used as forcing. The first analysis is a radar only precipitation estimate derived from WSR-88D digital hybrid reflectivity, a Z-R relationship and aggregated into an hourly ¼ HRAP grid. The second analysis is derived from a rain gauge network and interpolated into an hourly ¼ HRAP grid using PRISM climatology. The third analysis is derived from a rain gauge network where rain gauges are assigned static pre-determined weights to derive a uniform mean areal precipitation that is applied over a catchment on a ¼ HRAP grid. To assess the effect of different QPE analyses on the accuracy of RDHM simulations and to potentially identify a preferred analysis for operational use, each QPE was used to force RDHM to simulate stream flow for 20 USGS peak flow events. An evaluation of the RDHM simulations was focused on peak flow magnitude, peak flow timing, and event volume accuracy to be most relevant for operational use. Results showed RDHM simulations based on the observed rain gauge amounts were more accurate in simulating peak flow magnitude and event volume relative to the radar derived analysis. However this result was not consistent for all 20 events nor was it consistent for a few of the rainfall events where an annual peak flow was recorded at more than one USGS gage. Implications of this indicate that a more robust QPE forcing with the inclusion of uncertainty derived from the three analyses may provide a better input for simulating extreme peak flow events.

The derivative-free Fourier shell identity for photoacoustics.

Science.gov (United States)

Baddour, Natalie

2016-01-01

In X-ray tomography, the Fourier slice theorem provides a relationship between the Fourier components of the object being imaged and the measured projection data. The Fourier slice theorem is the basis for X-ray Fourier-based tomographic inversion techniques. A similar relationship, referred to as the 'Fourier shell identity' has been previously derived for photoacoustic applications. However, this identity relates the pressure wavefield data function and its normal derivative measured on an arbitrary enclosing aperture to the three-dimensional Fourier transform of the enclosed object evaluated on a sphere. Since the normal derivative of pressure is not normally measured, the applicability of the formulation is limited in this form. In this paper, alternative derivations of the Fourier shell identity in 1D, 2D polar and 3D spherical polar coordinates are presented. The presented formulations do not require the normal derivative of pressure, thereby lending the formulas directly adaptable for Fourier based absorber reconstructions.

Pulmonary Effects of Pyrotechnically Disseminated Titanium Dioxide Smoke in Rats

National Research Council Canada - National Science Library

Anthony, J. S; Kristovich, Robert L; McCaskey, David A; Davis, Emily A; Matson, Kathy L; Burnett, David; Gaviola, Bernardita P; Crouse, Charles L; Horsmon, Michael S; Kimmel, Edgar C

2007-01-01

The Fast Obscurant Grenade (FOG) is a bursting type grenade that has been developed within the Family of Tactical Obscuration Devices to fulfill the small through medium area screening obscuration need...

Alternative for Perchlorates in Incendiary and Pyrotechnic Formulations for Projectiles

Science.gov (United States)

2009-08-01

rats fed PTFE at up to 25% in the diet for 90 days. Exposure to dust may cause irritation of the eyes, skin or the digestive tract, while aspiration...been reported. Acute L(E)C50s for fluorides in aquatic organisms range from 50 to 500 mg dm -3. Twenty-day L(E)C50s for rainbow trout ranged from

Pulmonary Effects of Pyrotechnically Disseminated Titanium Dioxide Smoke in Rats

Science.gov (United States)

2007-05-01

Series Perkin Elmer AA (Boston, MA) with a nitrous oxide/acetylene burner head. Hollow cathode lamp elements specific for each metal were used. The primary...supematant was removed from the cell pellet . The pellet was resuspended in 1 mL of 50% bovine serum albumin and total cell counts were taken on a ZBI

On left (θ,ϕ-derivations in BCI-algebras

Directory of Open Access Journals (Sweden)

G. Muhiuddin

2014-07-01

Full Text Available The notion of (regular left (θ,ϕ-derivations of a BCI-algebra is introduced, some useful examples are discussed, and related properties are investigated. Conditions for a left (θ,ϕ-derivation to be regular are provided. The concepts of a d(θ,ϕ-invariant left (θ,ϕ-derivation and θ-ideal are introduced, and their relations are discussed. Furthermore, some more interesting results are established.

On a linear-quadratic problem with Caputo derivative

Directory of Open Access Journals (Sweden)

Dariusz Idczak

2016-01-01

Full Text Available In this paper, we study a linear-quadratic optimal control problem with a fractional control system containing a Caputo derivative of unknown function. First, we derive the formulas for the differential and gradient of the cost functional under given constraints. Next, we prove an existence result and derive a maximum principle. Finally, we describe the gradient and projection of the gradient methods for the problem under consideration.

76 FR 51878 - Modifications of Certain Derivative Contracts; Correction

Science.gov (United States)

2011-08-19

...) * * * (1) Both the party transferring or assigning its rights and obligations under the derivative contract... Modifications of Certain Derivative Contracts; Correction AGENCY: Internal Revenue Service (IRS), Treasury... temporary regulations (TD 9538) that address when a transfer or assignment of certain derivative contracts...

Options, Futures, and Other Derivatives in Russia: An Overview

OpenAIRE

Rotfuß, Waldemar

2007-01-01

This work provides a descriptive overview of Russian markets for financial derivatives. Available figures for the exchange-traded and over-the-counter-traded derivatives in Russia show that the Russian derivatives markets experienced enormous growth rates since the financial crisis in 1998. Starting from a very low level, turnover of exchange-traded derivatives in Russia rose from 2000 to 2006 on average 168 percent per year and reached a total turnover of EUR 102 billion in 2006. Among futur...

Integrated tuning of PID-derivative load frequency controller for two ...

African Journals Online (AJOL)

Results of the proposed derivative controller have been compared with conventional proportional integral derivative controller in time domain analysis. A remarkable improvement in stability of the system has ... the feasibility of the proposed PID-derivative filter controller. Keywords: controller; derivative filter; tie line; two area ...

Synthesis and characterization of mixed ligand Cu(II) complexes of salicylic acid derivatives with 2-aminobenzotiyazol derivatives

OpenAIRE

İlkimen, Halil; Yenikaya, Cengiz

2018-01-01

In thisstudy, mixed ligand transitionmetal complexes of Cu(II)have been prepared between salicylic acid derivatives [salicylic acid (H2sal) or acetylsalicylic acid (Hasal)] and 2-aminobenzothiazole derivatives[2-aminobenzothiazole (abt) or 2-amino-6-chlorobenzothiazole (Clabt) or2-amino-6-methylbenzothiazole (Meabt)]. The structures of amorphous metalcomplexes have been proposed by evaluating the data obtained from elementalanalysis, ICP-OES, FT-IR, UV-Vis, thermal analysis, magnetic suscepti...

1,3-Oxazin-6-one Derivatives and Bohemamine-Type Pyrrolizidine Alkaloids from a Marine-Derived Streptomyces spinoverrucosus.

Science.gov (United States)

Fu, Peng; La, Scott; MacMillan, John B

2016-03-25

Two new 1,3-oxazin-6-one derivatives (1 and 2) and six new bohemamine-type pyrrolizidine alkaloids (3-8) were isolated from the marine-derived Streptomyces spinoverrucosus strain SNB-048. Their structures including the absolute configurations were fully elucidated on the basis of spectroscopic analysis, ECD spectra, quantum chemical calculations, and chemical methods. Compounds 1 and 2 possess a γ-lactam moiety and a 1,3-oxazin-6-one system.

Pleuromutilin and its derivatives-the lead compounds for novel antibiotics.

Science.gov (United States)

Tang, Y-Z; Liu, Y-H; Chen, J-X

2012-01-01

Due to the rapid onset of resistance to most antibacterial drugs, research efforts are focusing on new classes of antibacterials with different mechanisms of action from clinically used antibacterials. Pleuromutilin derivatives have received more and more scientific attention for their unique mechanism of action. Two pleuromutilin derivatives, tiamulin and valnemulin have been successfully developed as antibiotics for veterinary use. Retapamulin, another pleuromutilin derivative has been approved for use in humans in April 2007 by Food and Drug Administration (FDA). It has been shown that there is rarely cross-resistance between pleuromutilin derivatives and other antimicrobial agents, and the development of resistance bacterial is still low. This review will demonstrate mechanism of action of pleuromutilin derivatives and reveal the structure-activity relationship (SAR) of pleuromutilin derivatives. Additionally, the pleuromutilin antibacterial derivative agents in the market, such as tiamulin, valnemulin and retapamulin, will be discussed. It is proposed that new antibacterial agents might be developed from pleuromutilin derivatives in the future.

Weyl and Marchaud derivatives: a forgotten history

OpenAIRE

Ferrari, Fausto

2017-01-01

In this paper, we recall the contribution given by Hermann Weyl and André Marchaud to the notion of fractional derivative. In addition, we discuss some relationships between the fractional Laplace operator and Marchaud derivative in the perspective to generalize these objects to different fields of the mathematics.

Vulnerable Derivatives and Good Deal Bounds: A Structural Model

DEFF Research Database (Denmark)

Murgoci, Agatha

2013-01-01

We price vulnerable derivatives -- i.e. derivatives where the counterparty may default. These are basically the derivatives traded on the over-the-counter (OTC) markets. Default is modeled in a structural framework. The technique employed for pricing is good deal bounds (GDBs). The method imposes...

INTEREST RATE DERIVATIVES IN DEVELOPING COUNTRIES IN EUROPE

OpenAIRE

SLOBODAN CEROVIC; MARINA PEPIC

2011-01-01

Financial derivatives (interest rate futures, options and swaps) are a very simple way to minimize interest rate risk and therefore are extremely popular. The value of interest rate derivatives transactions in the world is increasing dramatically. Unfortunately, this is not the case with developing countries in Europe. Although significantly increased in the last decade, interest rate derivatives markets in developing countries are still in nascent stage. In most developing countries still t...

18 CFR 367.1750 - Account 175, Derivative instrument assets.

Science.gov (United States)

2010-04-01

... the corresponding amount of the change in the fair value of the derivative instrument. ... instrument assets. This account must include the amounts paid for derivative instruments, and the change in the fair value of all derivative instrument assets not designated as cash flow or fair value hedges...

21 CFR 172.275 - Synthetic paraffin and succinic derivatives.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Synthetic paraffin and succinic derivatives. 172... FOOD FOR HUMAN CONSUMPTION Coatings, Films and Related Substances § 172.275 Synthetic paraffin and succinic derivatives. Synthetic paraffin and succinic derivatives identified in this section may be safely...

Additive derivations on algebras of measurable operators

International Nuclear Information System (INIS)

Ayupov, Sh.A.; Kudaybergenov, K.K.

2009-08-01

Given a von Neumann algebra M we introduce the so-called central extension mix(M) of M. We show that mix(M) is a *-subalgebra in the algebra LS(M) of all locally measurable operators with respect to M, and this algebra coincides with LS(M) if and only if M does not admit type II direct summands. We prove that if M is a properly infinite von Neumann algebra then every additive derivation on the algebra mix(M) is inner. This implies that on the algebra LS(M), where M is a type I ∞ or a type III von Neumann algebra, all additive derivations are inner derivations. (author)

"Nonmorphological Derivations" and the Four Main English ...

African Journals Online (AJOL)

This article addresses the problem of "nonmorphological derivations" in English and its consequences for pedagogical lexicography, i.e. learner's dictionaries. The term "nonmorphological derivation" refers to cases such as sun — solar, moon — lunar, cat — feline, and in general to all cases where instead of, or in addition ...

Weyl and Marchaud Derivatives: A Forgotten History

Directory of Open Access Journals (Sweden)

Fausto Ferrari

2018-01-01

Full Text Available In this paper, we recall the contribution given by Hermann Weyl and André Marchaud to the notion of fractional derivative. In addition, we discuss some relationships between the fractional Laplace operator and Marchaud derivative in the perspective to generalize these objects to different fields of the mathematics.

Derived equivalences for group rings

CERN Document Server

König, Steffen

1998-01-01

A self-contained introduction is given to J. Rickard's Morita theory for derived module categories and its recent applications in representation theory of finite groups. In particular, Broué's conjecture is discussed, giving a structural explanation for relations between the p-modular character table of a finite group and that of its "p-local structure". The book is addressed to researchers or graduate students and can serve as material for a seminar. It surveys the current state of the field, and it also provides a "user's guide" to derived equivalences and tilting complexes. Results and proofs are presented in the generality needed for group theoretic applications.

Shoot-derived abscisic acid promotes root growth.

Science.gov (United States)

McAdam, Scott A M; Brodribb, Timothy J; Ross, John J

2016-03-01

The phytohormone abscisic acid (ABA) plays a major role in regulating root growth. Most work to date has investigated the influence of root-sourced ABA on root growth during water stress. Here, we tested whether foliage-derived ABA could be transported to the roots, and whether this foliage-derived ABA had an influence on root growth under well-watered conditions. Using both application studies of deuterium-labelled ABA and reciprocal grafting between wild-type and ABA-biosynthetic mutant plants, we show that both ABA levels in the roots and root growth in representative angiosperms are controlled by ABA synthesized in the leaves rather than sourced from the roots. Foliage-derived ABA was found to promote root growth relative to shoot growth but to inhibit the development of lateral roots. Increased root auxin (IAA) levels in plants with ABA-deficient scions suggest that foliage-derived ABA inhibits root growth through the root growth-inhibitor IAA. These results highlight the physiological and morphological importance, beyond the control of stomata, of foliage-derived ABA. The use of foliar ABA as a signal for root growth has important implications for regulating root to shoot growth under normal conditions and suggests that leaf rather than root hydration is the main signal for regulating plant responses to moisture. © 2015 John Wiley & Sons Ltd.

Structure Activity Relationship of Brevenal Hydrazide Derivatives

Directory of Open Access Journals (Sweden)

Allan Goodman

2014-03-01

Full Text Available Brevenal is a ladder frame polyether produced by the dinoflagellate Karenia brevis. This organism is also responsible for the production of the neurotoxic compounds known as brevetoxins. Ingestion or inhalation of the brevetoxins leads to adverse effects such as gastrointestinal maladies and bronchoconstriction. Brevenal shows antagonistic behavior to the brevetoxins and shows beneficial attributes when administered alone. For example, in an asthmatic sheep model, brevenal has been shown to increase tracheal mucosal velocity, an attribute which has led to its development as a potential treatment for Cystic Fibrosis. The mechanism of action of brevenal is poorly understood and the exact binding site has not been elucidated. In an attempt to further understand the mechanism of action of brevenal and potentially develop a second generation drug candidate, a series of brevenal derivatives were prepared through modification of the aldehyde moiety. These derivatives include aliphatic, aromatic and heteroaromatic hydrazide derivatives. The brevenal derivatives were tested using in vitro synaptosome binding assays to determine the ability of the compounds to displace brevetoxin and brevenal from their native receptors. A sheep inhalation model was used to determine if instillation of the brevenal derivatives resulted in bronchoconstriction. Only small modifications were tolerated, with larger moieties leading to loss of affinity for the brevenal receptor and bronchoconstriction in the sheep model.

Multiscale analysis of the CMB temperature derivatives

Energy Technology Data Exchange (ETDEWEB)

Marcos-Caballero, A.; Martínez-González, E.; Vielva, P., E-mail: marcos@ifca.unican.es, E-mail: martinez@ifca.unican.es, E-mail: vielva@ifca.unican.es [Instituto de Física de Cantabria, CSIC-Universidad de Cantabria, Avda. de los Castros s/n, 39005 Santander, Spain. (Spain)

2017-02-01

We study the Planck CMB temperature at different scales through its derivatives up to second order, which allows one to characterize the local shape and isotropy of the field. The problem of having an incomplete sky in the calculation and statistical characterization of the derivatives is addressed in the paper. The analysis confirms the existence of a low variance in the CMB at large scales, which is also noticeable in the derivatives. Moreover, deviations from the standard model in the gradient, curvature and the eccentricity tensor are studied in terms of extreme values on the data. As it is expected, the Cold Spot is detected as one of the most prominent peaks in terms of curvature, but additionally, when the information of the temperature and its Laplacian are combined, another feature with similar probability at the scale of 10{sup o} is also observed. However, the p -value of these two deviations increase above the 6% when they are referred to the variance calculated from the theoretical fiducial model, indicating that these deviations can be associated to the low variance anomaly. Finally, an estimator of the directional anisotropy for spinorial quantities is introduced, which is applied to the spinors derived from the field derivatives. An anisotropic direction whose probability is <1% is detected in the eccentricity tensor.

Treating autoimmune disorders with venom-derived peptides.

Science.gov (United States)

Shen, Bingzheng; Cao, Zhijian; Li, Wenxin; Sabatier, Jean-Marc; Wu, Yingliang

2017-09-01

The effective treatment of autoimmune diseases remains a challenge. Voltage-gated potassium Kv1.3 channels, which are expressed in lymphocytes, are a new therapeutic target for treating autoimmune disease. Consequently, Kv1.3 channel-inhibiting venom-derived peptides are a prospective resource for new drug discovery and clinical application. Area covered: Preclinical and clinical studies have produced a wealth of information on Kv1.3 channel-inhibiting venom-derived peptides, especially from venomous scorpions and sea anemones. This review highlights the advances in screening and design of these peptides with diverse structures and potencies. It focuses on representative strategies for improving peptide selectivity and discusses the preclinical research on those venom-derived peptides as well as their clinical developmental status. Expert opinion: Encouraging results indicate that peptides isolated from the venom of venomous animals are a large resource for discovering immunomodulators that act on Kv1.3 channels. Since the structural diversity of venom-derived peptides determines the variety of their pharmacological activities, the design and optimization of venom-peptides for improved Kv1.3 channel-specificity has been advanced through some representative strategies, such as peptide chemical modification, amino acid residue truncation and binding interface modulation. These advances should further accelerate research, development and the future clinical application of venom-derived peptides selectively targeting Kv1.3 channels.

Generalised boundary terms for higher derivative theories of gravity

Energy Technology Data Exchange (ETDEWEB)

Teimouri, Ali; Talaganis, Spyridon; Edholm, James [Consortium for Fundamental Physics, Lancaster University,North West Drive, Lancaster, LA1 4YB (United Kingdom); Mazumdar, Anupam [Consortium for Fundamental Physics, Lancaster University,North West Drive, Lancaster, LA1 4YB (United Kingdom); Kapteyn Astronomical Institute, University of Groningen,9700 AV Groningen (Netherlands)

2016-08-24

In this paper we wish to find the corresponding Gibbons-Hawking-York term for the most general quadratic in curvature gravity by using Coframe slicing within the Arnowitt-Deser-Misner (ADM) decomposition of spacetime in four dimensions. In order to make sure that the higher derivative gravity is ghost and tachyon free at a perturbative level, one requires infinite covariant derivatives, which yields a generalised covariant infinite derivative theory of gravity. We will be exploring the boundary term for such a covariant infinite derivative theory of gravity.

Ethanolamine derivatives of dysprosium and holmium

International Nuclear Information System (INIS)

Gharia, K.S.; Singh, M.; Mathur, S.; Sankhla, B.S.

1981-01-01

The preparation and properties of dysprosium and holmium derivatives of mono-, di- and tri-ethanolamine derivatives are described. Compounds of general formulae: Ln(OPrsup(i)) 2 (mea), Ln(OPrsup(i))(mea) 2 , Ln(mea) 3 , Ln(OPrsup(i))(dea), Ln 2 (dea) 3 , Ln(dea)(deaH) and Ln(tea) (where Ln = Dy or Ho and mea, dea and tea are the anions of respective ethanolamine) were obtained and characterized by elemental analysis and IR spectra. (author)

Evaluation of antituberculosis activity and DFT study on dipyrromethane-derived hydrazone derivatives

Science.gov (United States)

Rawat, Poonam; Singh, R. N.; Niranjan, Priydarshni; Ranjan, Alok; Holguín, Norma Rosario Flores

2017-12-01

This paper evaluates the anti-tubercular activity of dipyrromethane-derived hydrazones derivatives (3a-d) against strain of Mycobacterium tuberculosis H37Rv. The newly synthesized compounds have been obtained in good yield based on the condensation of aromatic aldehyde derivatives with pyrrole hydrazone in presence of catalyst and well characterized with spectroscopic methods (1H, 13C NMR, Mass spectrometry) and elemental analysis. The singlet observed in the experimental 1H and 13C NMR spectra in the range of 5.3-5.7 ppm and 30-33.86 ppm, respectively, indicating that two pyrrole units are joined at meso position. The electronic transitions observed in the experimental spectra are n→π* and π →π* in nature. Experimental and theoretical findings corroborate well with each other. The substitution of acceptor group (-NO2) at ortho- and meta-positions of benzene ring, present at meso-position of dipyrromethane is responsible for variation in β0 values. The calculated NLO of (3a-d) are much greater than those of p-nitroaniline (PNA). The solvent induced effects on the non-linear optical properties were studied and found to enhance NLO properties of the molecules as dielectric constants of the solvents increases. On the basis of results it is anticipated that these dipyrromethanes will be useful for both antimicrobial and non-linear optical (NLO) applications. With the help of Microplate Alamar Blue assay (MABA) method all (3a-d) compounds were screened for their anti-tubercular activity and found that 3b and 3d have higher inhibitory activity against strain of M. tuberculosis H37Rv.

Cloud vertical profiles derived from CALIPSO and CloudSat and a comparison with MODIS derived clouds

Science.gov (United States)

Kato, S.; Sun-Mack, S.; Miller, W. F.; Rose, F. G.; Minnis, P.; Wielicki, B. A.; Winker, D. M.; Stephens, G. L.; Charlock, T. P.; Collins, W. D.; Loeb, N. G.; Stackhouse, P. W.; Xu, K.

2008-05-01

CALIPSO and CloudSat from the a-train provide detailed information of vertical distribution of clouds and aerosols. The vertical distribution of cloud occurrence is derived from one month of CALIPSO and CloudSat data as a part of the effort of merging CALIPSO, CloudSat and MODIS with CERES data. This newly derived cloud profile is compared with the distribution of cloud top height derived from MODIS on Aqua from cloud algorithms used in the CERES project. The cloud base from MODIS is also estimated using an empirical formula based on the cloud top height and optical thickness, which is used in CERES processes. While MODIS detects mid and low level clouds over the Arctic in April fairly well when they are the topmost cloud layer, it underestimates high- level clouds. In addition, because the CERES-MODIS cloud algorithm is not able to detect multi-layer clouds and the empirical formula significantly underestimates the depth of high clouds, the occurrence of mid and low-level clouds is underestimated. This comparison does not consider sensitivity difference to thin clouds but we will impose an optical thickness threshold to CALIPSO derived clouds for a further comparison. The effect of such differences in the cloud profile to flux computations will also be discussed. In addition, the effect of cloud cover to the top-of-atmosphere flux over the Arctic using CERES SSF and FLASHFLUX products will be discussed.

Variational problems with fractional derivatives: Euler-Lagrange equations

International Nuclear Information System (INIS)

Atanackovic, T M; Konjik, S; Pilipovic, S

2008-01-01

We generalize the fractional variational problem by allowing the possibility that the lower bound in the fractional derivative does not coincide with the lower bound of the integral that is minimized. Also, for the standard case when these two bounds coincide, we derive a new form of Euler-Lagrange equations. We use approximations for fractional derivatives in the Lagrangian and obtain the Euler-Lagrange equations which approximate the initial Euler-Lagrange equations in a weak sense

8 CFR 207.7 - Derivatives of refugees.

Science.gov (United States)

2010-01-01

... 8 Aliens and Nationality 1 2010-01-01 2010-01-01 false Derivatives of refugees. 207.7 Section 207... REFUGEES § 207.7 Derivatives of refugees. (a) Eligibility. A spouse, as defined in section 101(a)(35) of..., shall be granted refugee status if accompanying or following-to-join the principal alien. An...

Characterization of buffy coat-derived granulocytes for clinical use: a comparison with granulocyte colony-stimulating factor/dexamethasone-pretreated donor-derived products.

Science.gov (United States)

van de Geer, A; Gazendam, R P; Tool, A T J; van Hamme, J L; de Korte, D; van den Berg, T K; Zeerleder, S S; Kuijpers, T W

2017-02-01

Buffy coat-derived granulocytes have been described as an alternative to the apheresis product from donors pretreated with dexamethasone and granulocyte colony-stimulating factor (G-CSF). The latter is - dependent on the local and national settings - obtained following a demanding and time-consuming procedure, which is undesirable in critically ill septic patients. In contrast, buffy coat-derived products have a large volume and are often heavily contaminated with red cells and platelets. We developed a new pooled buffy coat-derived product with high purity and small volume, and performed a comprehensive functional characterization of these granulocytes. We pooled ten buffy coats following the production of platelet concentrates. Saline 0·9% was added to decrease the viscosity and the product was split into plasma, red cells and a 'super' buffy coat. Functional data of the granulocytes were compared to those obtained with granulocytes from healthy controls and G-CSF/dexamethasone-pretreated donors. Buffy coat-derived granulocytes showed adhesion, chemotaxis, reactive oxygen species production, degranulation, NETosis and in vitro killing of Staphylococcus aureus, Escherichia coli and Aspergillus species comparable to control and G-CSF/dexamethasone-derived granulocytes. Candida killing was superior compared to G-CSF/dexamethasone-derived granulocytes. Immunophenotyping was normal; especially no signs of activation in the buffy coat-derived granulocytes were seen. Viability was reduced. Buffy coats are readily available in the regular blood production process and would take away the concerns around the apheresis product. The product described appears a promising alternative for transfusion purposes. © 2017 International Society of Blood Transfusion.

A multivector derivative approach to Lagrangian field theory

International Nuclear Information System (INIS)

Lasenby, A.; Gull, S.; Doran, C.

1993-01-01

A new calculus, based upon the multivector derivative, is developed for Lagrangian mechanics and field theory, providing streamlined and rigorous derivations of the Euler-Lagrange equations. A more general form of Noether's theorem is found which is appropriate to both discrete and continuous symmetries. This is used to find the conjugate currents of the Dirac theory, where it improves on techniques previously used for analyses of local observables. General formulas for the canonical stress-energy and angular-momentum tensors are derived, with spinors and vectors treated in a unified way. It is demonstrated that the antisymmetric terms in the stress-energy tensor are crucial to the correct treatment of angular momentum. The multivector derivative is extended to provide a functional calculus for linear functions which is more compact and more powerful than previous formalisms. This is demonstrated in a reformulation of the functional derivative with respect to the metric, which is then used to recover the full canonical stress-energy tensor. Unlike conventional formalisms, which result in a symmetric stress-energy tensor, this reformulation retains the potentially important antisymmetric contribution. 23 refs

Frequency-domain waveform inversion using the phase derivative

KAUST Repository

Choi, Yun Seok

2013-09-26

Phase wrapping in the frequency domain or cycle skipping in the time domain is the major cause of the local minima problem in the waveform inversion when the starting model is far from the true model. Since the phase derivative does not suffer from the wrapping effect, its inversion has the potential of providing a robust and reliable inversion result. We propose a new waveform inversion algorithm using the phase derivative in the frequency domain along with the exponential damping term to attenuate reflections. We estimate the phase derivative, or what we refer to as the instantaneous traveltime, by taking the derivative of the Fourier-transformed wavefield with respect to the angular frequency, dividing it by the wavefield itself and taking the imaginary part. The objective function is constructed using the phase derivative and the gradient of the objective function is computed using the back-propagation algorithm. Numerical examples show that our inversion algorithm with a strong damping generates a tomographic result even for a high ‘single’ frequency, which can be a good initial model for full waveform inversion and migration.

Deriving a Bilingual Lexicon for Cross-Language Information Retrieval

NARCIS (Netherlands)

Hiemstra, Djoerd

1997-01-01

In this paper we describe a systematic approach to derive a bilingual lexicon automatically from parallel corpora. Following this approach, a lexicon was derived from the English and Dutch version of the Agenda 21 corpus. With the lexicon and a part of the corpus that was not used to derive the

New Metabolites and Bioactive Chlorinated Benzophenone Derivatives Produced by a Marine-Derived Fungus Pestalotiopsis heterocornis

Directory of Open Access Journals (Sweden)

Hui Lei

2017-03-01

Full Text Available Four new compounds, including two isocoumarins, pestaloisocoumarins A and B (1, 2, one sesquiterpenoid degradation, isopolisin B (4, and one furan derivative, pestalotiol A (5, together with one known isocoumarin, gamahorin (3, and three chlorinated benzophenone derivatives, pestalachloride B (6, pestalachloride E (7 and a mixture of pestalalactone atropisomers (8a/8b, were isolated from a culture of the fungus Pestalotiopsis heterocornis associated with sponge Phakellia fusca. These new chemical structures were established using NMR and MS spectroscopic data, as well as single-crystal X-ray crystallographic analysis and CD Cotton effects. All of the isolated compounds were evaluated for their antimicrobial and cytotoxic activities. Isocoumarins 1–3, showed antibacterial activities against Gram-positive bacteria Staphylococcus aureus and Bacillus subtilis with MIC values ranging from 25 to 100 μg/mL and weak antifungal activities. Chlorinated benzophenone derivatives 6–8 exhibited antibacterial activities against S. aureus and B. subtilis with MIC values ranging from 3.0 to 50 μg/mL and cytotoxicities against four human cancer cell lines with IC50 values of 6.8–87.8 μM.

Ventil

OpenAIRE

Schmidt, U.; Schuetz, H.G.; Meinel, M.; Buehling, H.

1998-01-01

The valve, especially as an overload safety valve for a mechanical press, has a mechanical lock on the valve piston (1) in the pressure medium flow path between an entry (7) and outlet (9) opening. The lock is a screw which is broken by a pyrotechnic or explosive action. The valve piston (1) has the structure of a step piston, where it is under loading from the pressure medium. USE - The safety valve is for protection of a mechanical press from damage through overloading. ADVANTAGE - The stru...

Clean and Green Synthesis of New Benzothiazole Derivatives via Electrochemical Oxidation of Catechol Derivatives

Directory of Open Access Journals (Sweden)

Mansour Arab Chamjangali

2016-06-01

Full Text Available Electrochemical oxidation of the catechols 1a and 1b is studied in the presence of 6-methyl-2-thouracil (3b and 6-propyl-2-thiouracil (3a as nucleophiles in a phosphate buffer (0.15 mol L−1, pH = 6.8/DMF (95:5 solution using cyclic voltammetry and controlled-potential coulometry. The results obtained indicate that the quinones derived from the catechols participate in 1,4-Michael-addition reactions with the nucleophiles to form the corresponding new benzothiazole compounds. In this work, we derive a variety of products with good yields using controlled potential at graphite electrodes in an undivided cell. This work is licensed under a Creative Commons Attribution 4.0 International License.

Novel Trolox derivatives as antioxidant: A DFT investigation

Directory of Open Access Journals (Sweden)

Farmanzadeh Dvood

2016-01-01

Full Text Available In this paper the antioxidant activity of Trolox derivatives were investigated by density function theory and polarization continuum model as solvent model in order to propose the novel derivatives with higher antioxidant activity from a theoretical viewpoint. The effects of various ortho and meta substituents on the reaction enthalpies of antioxidant mechanisms of Trolox were investigated. Also the effect of reducing the number of atoms in the heterocyclic ring and effect of replacing the oxygen heteroatom of Trolox with other heteroatoms on the antioxidant activity of Trolox were evaluated. Results show that the NH2, OH and NHMe substituents in meta and ortho positions decrease the BDE and IP values and also increase the antioxidant activity of Trolox from the theoretical viewpoint. The derivatives e, c and d with NH, S and Se instead of O have higher antioxidant activity from the theoretical viewpoint. Obtained results show that reducing the number of atom in the heterocyclic ring (derivatives a and b decrease the BDE and IP values and also increase the antioxidant activity of Trolox from the theoretical viewpoint. The linear dependencies between BDE of OH bond and IP values of studied Trolox derivatives and corresponding EHOMO and R(O-H values can be useful to propose novel derivatives with higher antioxidant activity from the theoretical viewpoint.

Jordan (α,β-Derivations on Operator Algebras

Directory of Open Access Journals (Sweden)

Quanyuan Chen

2017-01-01

Full Text Available Let A be a CSL subalgebra of a von Neumann algebra acting on a Hilbert space H. It is shown that any Jordan (α,β-derivation on A is an (α,β-derivation, where α,β are any automorphisms on A. Moreover, the nth power (α,β-maps on A are investigated.

Merged/integrated Bathymetric Data Derived from Multibeam Sonar, LiDAR, and Satellite-derived Bathymetry

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — Gridded multibeam bathymetry is integrated with derived bathymetry from alternate sources to provide a GIS layer with expanded spatial coverage. Integrated products...

Photoinduced electron-transfer from imidazole derivative to nano-semiconductors.

Science.gov (United States)

Karunakaran, C; Jayabharathi, J; Jayamoorthy, K; Devi, K Brindha

2012-04-01

Bioactive imidazole derivative absorbs in the UV region at 305 nm. The interaction of imidazole derivative with nanoparticulate WO3, Fe2O3, Fe3O4, CuO, ZrO2 and Al2O3 has been studied by UV-visible absorption, FT-IR and fluorescence spectroscopies. The imidazole derivative adsorbs strongly on the surfaces of nanosemiconductor, the apparent binding constants for the association between nanomaterials and imidazole derivative have been determined from the fluorescence quenching. In the case of nanocrystalline insulator, fluorescence quenching through electron transfer from the excited state of the imidazole derivative to alumina is not possible. However, a possible mechanism for the quenching of fluorescence by the insulator is energy transfer, that is, energy transferred from the organic molecule to the alumina lattice. Based on Forster's non-radiation energy transfer theory, the distance between the imidazole derivative and nanoparticles (r0∼2.00 nm) as well as the critical energy transfer distance (R0∼1.70 nm) has been calculated. The interaction between the imidazole derivative and nanosurfaces occurs through static quenching mechanism. The free energy change (ΔGet) for electron transfer process has been calculated by applying Rehm-Weller equation. Copyright © 2012 Elsevier B.V. All rights reserved.

Derivative instruments a guide to theory and practice

CERN Document Server

Eales, Brian

2003-01-01

The authors concentrate on the practicalities of each class of derivative, so that readers can apply the techniques in practice. Product descriptions are supported by detailed spreadsheet models, illustrating the techniques employed, some which are available on the accompanying companion website. This book is ideal reading for derivatives traders, salespersons, financial engineers, risk managers, and other professionals involved to any extent in the application and analysis of OTC derivatives.* Combines theory with valuation to provide overall coverage of the topic area* Pr

Chain Rule Approach for Calculating the Time-Derivative of Flux

Energy Technology Data Exchange (ETDEWEB)

Langenbrunner, James R. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Booker, Jane M. [Booker Scientific, Fredericksburg, TX (United States)

2017-10-03

The reaction history (gamma-flux observable) is mathematically studied by using the chain rule for taking the total-time derivatives. That is, the total time-derivative of flux is written as the product of the ion temperature derivative with respect to time and the derivative of the flux with respect to ion temperature. Some equations are derived using the further simplification that the fusion reactivity is a parametrized function of ion temperature, T. Deuterium-tritium (D-T) fusion is used as the application with reactivity calculations from three established reactivity parametrizations.

An alternative to the flutter derivatives

DEFF Research Database (Denmark)

Andersen, Michael Styrk; Brandt, Anders

A new simplified framework to study flutter and assess the full scale flutter wind speed is suggested. The flutter instability problem is reduced from a problem involving 8 flutter derivatives to only 4 coefficients. With this method it is possible to estimate the self-excited forces with increased...... precision by using stability diagrams. Furthermore, the physical transparency of the aerodynamic damping and stiffness terms is increased because the development in vertical and torsional damping and stiffness is analysed instead of flutter derivatives....

Corporate derivatives use and firm value: Evidence from Turkey

Directory of Open Access Journals (Sweden)

Yusuf Ayturk

2016-06-01

Full Text Available This paper examines use of financial derivatives (currency, interest rate and commodity and its effect on firm value of non-financial Turkish firms for period of 2007–2013. Only 36.41% of companies in our sample use derivatives to hedge their currency, interest rate or commodity price risks. We have used Tobin's Q ratio analysis with panel data models, Fama-French three-factor time-series analysis and single sector analysis to investigate whether corporate derivatives use is value relevant or not. Except Tobin's Q ratio analysis with system GMM estimators, we cannot find significant hedging premium or discount for all Turkish non-financial firms. We find a positive relationship between derivatives use and firm value, only when we use Tobin's Q ratio analysis with system GMM estimators. We also test the effects of currency hedging, interest rate hedging and commodity price hedging separately and find similar results as in the case of general derivatives use. Overall, majority of our results imply that use of financial derivatives does not affect firm value in Turkish market.

Geochemical Constraints for Mercury's PCA-Derived Geochemical Terranes

Science.gov (United States)

Stockstill-Cahill, K. R.; Peplowski, P. N.

2018-05-01

PCA-derived geochemical terranes provide a robust, analytical means of defining these terranes using strictly geochemical inputs. Using the end members derived in this way, we are able to assess the geochemical implications for Mercury.

Acclimation of aerobic-activated sludge degrading benzene derivatives and co-metabolic degradation activities of trichloroethylene by benzene derivative-grown aerobic sludge.

Science.gov (United States)

Wang, Shizong; Yang, Qi; Bai, Zhiyong; Wang, Shidong; Wang, Yeyao; Nowak, Karolina M

2015-01-01

The acclimation of aerobic-activated sludge for degradation of benzene derivatives was investigated in batch experiments. Phenol, benzoic acid, toluene, aniline and chlorobenzene were concurrently added to five different bioreactors which contained the aerobic-activated sludge. After the acclimation process ended, the acclimated phenol-, benzoic acid-, toluene-, aniline- and chlorobenzene-grown aerobic-activated sludge were used to explore the co-metabolic degradation activities of trichloroethylene (TCE). Monod equation was employed to simulate the kinetics of co-metabolic degradation of TCE by benzene derivative-grown sludge. At the end of experiments, the mixed microbial communities grown under different conditions were identified. The results showed that the acclimation periods of microorganisms for different benzene derivatives varied. The maximum degradation rates of TCE for phenol-, benzoic acid-, toluene-, aniline- and chlorobenzene-grown aerobic sludge were 0.020, 0.017, 0.016, 0.0089 and 0.0047 mg g SS(-1) h(-1), respectively. The kinetic of TCE degradation in the absence of benzene derivative followed Monod equation well. Also, eight phyla were observed in the acclimated benzene derivative-grown aerobic sludge. Each of benzene derivative-grown aerobic sludge had different microbial community composition. This study can hopefully add new knowledge to the area of TCE co-metabolic by mixed microbial communities, and further the understanding on the function and applicability of aerobic-activated sludge.

Antioxidant Activity of Novel Fused Heterocyclic Compounds Derived from Tetrahydropyrimidine Derivative.

Science.gov (United States)

Salem, Marwa Sayed; Farhat, Mahmoud; Errayes, Asma Omar; Madkour, Hassan Mohamed Fawzy

2015-01-01

6-(Benzo[d][1,3]dioxol-5-yl)-4-oxo-2-thioxo-1,2,3,4-tetrahydropyrimidine-5-carbonitrile has been utilized for synthesis of the fused heterocyclic compounds namely thiazolopyrimidines, tetrazolopyrimidine, pyrimidoquinazoline, pyrimidothiazolopyrimidine, pyrimidothiazolotriazine and pyrrolothiazolopyrimidine derivatives. The newly synthesized compounds were characterized by IR, (1)H-NMR, (13)C-NMR, and mass spectral data. Antioxidant activities of all synthesized compounds were investigated.

Hybrid approximations via second order combined dynamic derivatives on time scales

Directory of Open Access Journals (Sweden)

Qin Sheng

2007-09-01

Full Text Available This article focuses on the approximation of conventional second order derivative via the combined (diamond-$\\alpha$ dynamic derivative on time scales with necessary smoothness conditions embedded. We will show the constraints under which the second order dynamic derivative provides a consistent approximation to the conventional second derivative; the cases where the dynamic derivative approximates the derivative only via a proper modification of the existing formula; and the situations in which the dynamic derivative can never approximate consistently even with the help of available structure correction methods. Constructive error analysis will be given via asymptotic expansions for practical hybrid modeling and computational applications.

5S rRNA-derived and tRNA-derived SINEs in fruit bats.

Science.gov (United States)

Gogolevsky, Konstantin P; Vassetzky, Nikita S; Kramerov, Dmitri A

2009-05-01

Most short retroposons (SINEs) descend from cellular tRNA of 7SL RNA. Here, four new SINEs were found in megabats (Megachiroptera) but neither in microbats nor in other mammals. Two of them, MEG-RS and MEG-RL, descend from another cellular RNA, 5S rRNA; one (MEG-T2) is a tRNA-derived SINE; and MEG-TR is a hybrid tRNA/5S rRNA SINE. Insertion locus analysis suggests that these SINEs were active in the recent fruit bat evolution. Analysis of MEG-RS and MEG-RL in comparison with other few 5S rRNA-derived SINEs demonstrates that the internal RNA polymerase III promoter is their most invariant region, while the secondary structure is more variable. The mechanisms underlying the modular structure of these and other SINEs as well as their variation are discussed. The scenario of evolution of MEG SINEs is proposed.

P-Splines Using Derivative Information

KAUST Repository

Calderon, Christopher P.

2010-01-01

Time series associated with single-molecule experiments and/or simulations contain a wealth of multiscale information about complex biomolecular systems. We demonstrate how a collection of Penalized-splines (P-splines) can be useful in quantitatively summarizing such data. In this work, functions estimated using P-splines are associated with stochastic differential equations (SDEs). It is shown how quantities estimated in a single SDE summarize fast-scale phenomena, whereas variation between curves associated with different SDEs partially reflects noise induced by motion evolving on a slower time scale. P-splines assist in "semiparametrically" estimating nonlinear SDEs in situations where a time-dependent external force is applied to a single-molecule system. The P-splines introduced simultaneously use function and derivative scatterplot information to refine curve estimates. We refer to the approach as the PuDI (P-splines using Derivative Information) method. It is shown how generalized least squares ideas fit seamlessly into the PuDI method. Applications demonstrating how utilizing uncertainty information/approximations along with generalized least squares techniques improve PuDI fits are presented. Although the primary application here is in estimating nonlinear SDEs, the PuDI method is applicable to situations where both unbiased function and derivative estimates are available.

Quinazolin-4-one derivatives

DEFF Research Database (Denmark)

Mosley, Cara A; Acker, Timothy M; Hansen, Kasper Bø

2010-01-01

We describe a new class of subunit-selective antagonists of N-methyl D-aspartate (NMDA)-selective ionotropic glutamate receptors that contain the (E)-3-phenyl-2-styrylquinazolin-4(3H)-one backbone. The inhibition of recombinant NMDA receptor function induced by these quinazolin-4-one derivatives...

Hydraulic Apparatus for Mechanical Testing of Nuts

Science.gov (United States)

Hinkel, Todd J.; Dean, Richard J.; Hacker, Scott C.; Harrington, Douglas W.; Salazar, Frank

2004-01-01

The figure depicts an apparatus for mechanical testing of nuts. In the original application for which the apparatus was developed, the nuts are of a frangible type designed for use with pyrotechnic devices in spacecraft applications in which there are requirements for rapid, one-time separations of structures that are bolted together. The apparatus can also be used to test nonfrangible nuts engaged without pyrotechnic devices. This apparatus was developed to replace prior testing systems that were extremely heavy and immobile and characterized by long setup times (of the order of an hour for each nut to be tested). This apparatus is mobile, and the setup for each test can now be completed in about five minutes. The apparatus can load a nut under test with a static axial force of as much as 6.8 x 10(exp 5) lb (3.0 MN) and a static moment of as much as 8.5 x 10(exp 4) lb in. (9.6 x 10(exp 3) N(raised dot)m) for a predetermined amount of time. In the case of a test of a frangible nut, the pyrotechnic devices can be exploded to break the nut while the load is applied, in which case the breakage of the nut relieves the load. The apparatus can be operated remotely for safety during an explosive test. The load-generating portion of the apparatus is driven by low-pressure compressed air; the remainder of the apparatus is driven by 110-Vac electricity. From its source, the compressed air is fed to the apparatus through a regulator and a manually operated valve. The regulated compressed air is fed to a pneumatically driven hydraulic pump, which pressurizes oil in a hydraulic cylinder, thereby causing a load to be applied via a hydraulic nut (not to be confused with the nut under test). During operation, the hydraulic pressure is correlated with the applied axial load, which is verified by use of a load cell. Prior to operation, one end of a test stud (which could be an ordinary threaded rod or bolt) is installed in the hydraulic nut. The other end of the test stud passes

A comparison of hydrogen storage capacity of commercial and fly ash-derived zeolite X together with their respective templated carbon derivatives

CSIR Research Space (South Africa)

Musyoka, Nicholas M

2015-10-01

Full Text Available This paper presents comparative results of structural, morphological and hydrogen sorption properties between commercial and fly ash-derived zeolite X including their respective templated carbon derivatives. The surface area of commercial zeolite...

In defense of derivations

Science.gov (United States)

Mungan, Carl E.

2016-05-01

At the 2015 AAPT Summer Meeting, I presented four derivations of the formula for motional emf. Such physics derivations involve the construction of explanatory frameworks involving diagrams and mathematical models. Although textbooks devote considerable space to such explanations, many teachers and students spend their time on worksheets, end-of-chapter problems, and the like. The book is reduced to a bank of solved (i.e., example) and unsolved (i.e., homework) questions, along with equations in colored boxes that presumably are to be used to answer those questions. Such an approach encourages fragmentation of knowledge, the view that there is only one right answer to a problem with the goal of physics being to find that answer (neatly boxed of course), and the inability to reason about even a slightly different (much less a novel) situation. If we are to develop scientific literacy, significant course time must be devoted to explaining the structure of and support for the models and equations we use.

Recognition by symmetry derivatives and the generalized structure tensor.

Science.gov (United States)

Bigun, Josef; Bigun, Tomas; Nilsson, Kenneth

2004-12-01

We suggest a set of complex differential operators that can be used to produce and filter dense orientation (tensor) fields for feature extraction, matching, and pattern recognition. We present results on the invariance properties of these operators, that we call symmetry derivatives. These show that, in contrast to ordinary derivatives, all orders of symmetry derivatives of Gaussians yield a remarkable invariance: They are obtained by replacing the original differential polynomial with the same polynomial, but using ordinary coordinates x and y corresponding to partial derivatives. Moreover, the symmetry derivatives of Gaussians are closed under the convolution operator and they are invariant to the Fourier transform. The equivalent of the structure tensor, representing and extracting orientations of curve patterns, had previously been shown to hold in harmonic coordinates in a nearly identical manner. As a result, positions, orientations, and certainties of intricate patterns, e.g., spirals, crosses, parabolic shapes, can be modeled by use of symmetry derivatives of Gaussians with greater analytical precision as well as computational efficiency. Since Gaussians and their derivatives are utilized extensively in image processing, the revealed properties have practical consequences for local orientation based feature extraction. The usefulness of these results is demonstrated by two applications: 1) tracking cross markers in long image sequences from vehicle crash tests and 2) alignment of noisy fingerprints.

High precision pulsar timing and spin frequency second derivatives

Science.gov (United States)

Liu, X. J.; Bassa, C. G.; Stappers, B. W.

2018-05-01

We investigate the impact of intrinsic, kinematic and gravitational effects on high precision pulsar timing. We present an analytical derivation and a numerical computation of the impact of these effects on the first and second derivative of the pulsar spin frequency. In addition, in the presence of white noise, we derive an expression to determine the expected measurement uncertainty of a second derivative of the spin frequency for a given timing precision, observing cadence and timing baseline and find that it strongly depends on the latter (∝t-7/2). We show that for pulsars with significant proper motion, the spin frequency second derivative is dominated by a term dependent on the radial velocity of the pulsar. Considering the data sets from three Pulsar Timing Arrays, we find that for PSR J0437-4715 a detectable spin frequency second derivative will be present if the absolute value of the radial velocity exceeds 33 km s-1. Similarly, at the current timing precision and cadence, continued timing observations of PSR J1909-3744 for about another eleven years, will allow the measurement of its frequency second derivative and determine the radial velocity with an accuracy better than 14 km s-1. With the ever increasing timing precision and observing baselines, the impact of the, largely unknown, radial velocities of pulsars on high precision pulsar timing can not be neglected.

Deriving stellar parameters with the SME software package

Science.gov (United States)

Piskunov, N.

2017-09-01

Photometry and spectroscopy are complementary tools for deriving accurate stellar parameters. Here I present one of the popular packages for stellar spectroscopy called SME with the emphasis on the latest developments and error assessment for the derived parameters.

Kojyl cinnamate ester derivatives promote adiponectin production during adipogenesis in human adipose tissue-derived mesenchymal stem cells.

Science.gov (United States)

Rho, Ho Sik; Hong, Soo Hyun; Park, Jongho; Jung, Hyo-Il; Park, Young-Ho; Lee, John Hwan; Shin, Song Seok; Noh, Minsoo

2014-05-01

The subcutaneous fat tissue mass gradually decreases with age, and its regulation is a strategy to develop anti-aging compounds to ameliorate the photo-aging of human skin. The adipogenesis of human adipose tissue-mesenchymal stem cells (hAT-MSCs) can be used as a model to discover novel anti-aging compounds. Cinnamomum cassia methanol extracts were identified as adipogenesis-promoting agents by natural product library screening. Cinnamates, the major chemical components of Cinnamomum cassia extracts, promoted adipogenesis in hAT-MSCs. We synthesized kojyl cinnamate ester derivatives to improve the pharmacological activity of cinnamates. Structure-activity studies of kojyl cinnamate derivatives showed that both the α,β-unsaturated carbonyl ester group and the kojic acid moiety play core roles in promoting adiponectin production during adipogenesis in hAT-MSCs. We conclude that kojyl cinnamate ester derivatives provide novel pharmacophores that can regulate adipogenesis in hAT-MSCs. Copyright © 2014 Elsevier Ltd. All rights reserved.

Synthesis and Cytotoxicity of Novel Hexahydrothienocycloheptapyridazinone Derivatives

Directory of Open Access Journals (Sweden)

Irene Marchesi

2009-09-01

Full Text Available Designed as a new group of tricyclic molecules containing the thienocycloheptapyridazinone ring system, a number of 2N-substituted-hexahydrothienocycloheptapyridazinone derivatives were synthesized and their biological activity evaluated. Among the synthesized compounds, derivatives 7d and 7h were found to possess cytotoxic activity against non-small cell lung cancer and central nervous system cancer cell lines, respectively.

Deriving force field parameters for coordination complexes

DEFF Research Database (Denmark)

Norrby, Per-Ola; Brandt, Peter

2001-01-01

The process of deriving molecular mechanics force fields for coordination complexes is outlined. Force field basics are introduced with an emphasis on special requirements for metal complexes. The review is then focused on how to set up the initial model, define the target, refine the parameters......, and validate the final force field, Alternatives to force field derivation are discussed briefly....

Contact allergy to isoeugenol and its derivatives

DEFF Research Database (Denmark)

Tanaka, Susumu; Royds, C; Buckley, Christopher D

2004-01-01

A total of 2261 (808 male, 1453 female) consecutive patients attending contact dermatitis clinics were patch tested to isoeugenol and its derivatives listed in the EU Inventory of Fragrance Ingredients. Positive reactions were found to isoeugenol in 40, transisoeugenol in 40, isoeugenyl acetate...... and 15/16 of those to isoeugenyl phenylacetate but in none of those 6 positive to isoeugenyl methyl ether and in neither of those 2 positive to benzyl isoeugenyl ether. Concomitant contact allergy between isoeugenol and its derivatives may occur through chemical cross-reactivity or local skin metabolism...... of the derivatives. It is more commonly observed with the esters rather than the ethers. Isoeugenyl acetate has been proposed as an alternative to isoeugenol, but there is a high degree of concomitant reactivity with isoeugenol....

A spatial structural derivative model for ultraslow diffusion

Directory of Open Access Journals (Sweden)

Xu Wei

2017-01-01

Full Text Available This study investigates the ultraslow diffusion by a spatial structural derivative, in which the exponential function ex is selected as the structural function to construct the local structural derivative diffusion equation model. The analytical solution of the diffusion equation is a form of Biexponential distribution. Its corresponding mean squared displacement is numerically calculated, and increases more slowly than the logarithmic function of time. The local structural derivative diffusion equation with the structural function ex in space is an alternative physical and mathematical modeling model to characterize a kind of ultraslow diffusion.

Cinnamic Acid Derivatives as Antidiabetics Agents

Directory of Open Access Journals (Sweden)

Teni Ernawati

2017-04-01

Full Text Available Diabetes mellitus is a metabolic disorder of carbohydrate metabolism. Treatment of type II diabetes is usually done by prescribing diet and exercise for the patient however it can also be treated with antidiabetic drugs. The purpose of this paper is to illustrate some cinnamic acid derivative compounds which are either isolated from natural materials or the results of the chemical synthesis. In addition, their biological activities as an agent of α-glucosidase inhibitors have also been evaluated. Chemically, cinnamic acid has three main functional groups:  first is the substitution on the phenyl group, second is the additive reaction into the α-β unsaturated, and third is the chemical reaction with carboxylic acid functional groups. Chemical aspects of cinnamic acid derivative compounds have received much attention in the research and development of drugs, especially modifications within three functional groups are very influential. In the last 10 years, a lot of research and development of cinnamic acid derivatives as inhibitors of the α-glucosidase enzyme has been done. One example of the research done in this field is the modification of para position in the structure of cinnamic acid and addition of alkyl groups in the carboxylic group which would increase the activity of the α-glucosidase enzyme therefore the level of inhibition is 100 times higher than that of cinnamic acid compound itself. The novelty of this review article is to focus on the antidiabetic activity of cinnamic acid derivatives.

Opto-electronic DNA chip-based integrated card for clinical diagnostics.

Science.gov (United States)

Marchand, Gilles; Broyer, Patrick; Lanet, Véronique; Delattre, Cyril; Foucault, Frédéric; Menou, Lionel; Calvas, Bernard; Roller, Denis; Ginot, Frédéric; Campagnolo, Raymond; Mallard, Frédéric

2008-02-01

Clinical diagnostics is one of the most promising applications for microfluidic lab-on-a-chip or lab-on-card systems. DNA chips, which provide multiparametric data, are privileged tools for genomic analysis. However, automation of molecular biology protocol and use of these DNA chips in fully integrated systems remains a great challenge. Simplicity of chip and/or card/instrument interfaces is amongst the most critical issues to be addressed. Indeed, current detection systems for DNA chip reading are often complex, expensive, bulky and even limited in terms of sensitivity or accuracy. Furthermore, for liquid handling in the lab-on-cards, many devices use complex and bulky systems, either to directly manipulate fluids, or to ensure pneumatic or mechanical control of integrated valves. All these drawbacks prevent or limit the use of DNA-chip-based integrated systems, for point-of-care testing or as a routine diagnostics tool. We present here a DNA-chip-based protocol integration on a plastic card for clinical diagnostics applications including: (1) an opto-electronic DNA-chip, (2) fluid handling using electrically activated embedded pyrotechnic microvalves with closing/opening functions. We demonstrate both fluidic and electric packaging of the optoelectronic DNA chip without major alteration of its electronical and biological functionalities, and fluid control using novel electrically activable pyrotechnic microvalves. Finally, we suggest a complete design of a card dedicated to automation of a complex biological protocol with a fully electrical fluid handling and DNA chip reading.

Australian OTC Derivatives Markets: Insights from the BIS Semiannual Survey

OpenAIRE

Jason Ahn; Mihovil Matic; Christian Vallence

2012-01-01

The Reserve Bank of Australia recently commenced surveying participants in Australian over-the-counter (OTC) derivatives markets as part of the Bank for International Settlements’ (BIS) semiannual global OTC derivatives survey. Australia’s contribution to the survey complements regulatory efforts to improve the resilience and transparency of Australia’s OTC derivatives markets. It also facilitates a higher frequency comparison of the Australian and foreign OTC derivatives markets. The survey ...

Hardface coating systems and methods for metal alloys and other materials for wear and corrosion resistant applications

Science.gov (United States)

Seals, Roland D.

2015-08-18

The present disclosure relates generally to hardface coating systems and methods for metal alloys and other materials for wear and corrosion resistant applications. More specifically, the present disclosure relates to hardface coatings that include a network of titanium monoboride (TiB) needles or whiskers in a matrix, which are formed from titanium (Ti) and titanium diboride (TiB.sub.2) precursors by reactions enabled by the inherent energy provided by the process heat associated with coating deposition and, optionally, coating post-heat treatment. These hardface coatings are pyrophoric, thereby generating further reaction energy internally, and may be applied in a functionally graded manner. The hardface coatings may be deposited in the presence of a number of fluxing agents, beta stabilizers, densification aids, diffusional aids, and multimode particle size distributions to further enhance their performance characteristics.

Conditioning of high activity solid waste: fuel claddings and dissolution residues

International Nuclear Information System (INIS)

Anon.

1982-01-01

This chapter reports on experimental studies of embedding into matrix material, the melting and conversion of zircaloy, and waste properties and characterization. Methods are developed for embedding the waste scrap into a solid and resistant matrix material in order to confine the radioactivity and to prevent it from dispersion. The matrix materials investigated are lead alloys, ceramics and compacted graphite or aluminium powder. The treatment of fuel hulls by melting or chemical conversion is described. Cemented hulls are characterized and the pyrophoricity of zircaloy fines is investigated. Topics considered include the embedding of hulls into graphite and aluminium, the embedding of hulls and dissolution residues into alumino-ceramics, the solidification of alpha-bearing wastes into a ceramic matrix, and the conditioning of cladding waste by eutectoidic melting and by embedding in glass

Riddle of depleted uranium

International Nuclear Information System (INIS)

Hussein, A.S.

2005-01-01

Depleted Uranium (DU) is the waste product of uranium enrichment from the manufacturing of fuel rods for nuclear reactors in nuclear power plants and nuclear power ships. DU may also results from the reprocessing of spent nuclear reactor fuel. Potentially DU has both chemical and radiological toxicity with two important targets organs being the kidney and the lungs. DU is made into a metal and, due to its availability, low price, high specific weight, density and melting point as well as its pyrophoricity; it has a wide range of civilian and military applications. Due to the use of DU over the recent years, there appeared in some press on health hazards that are alleged to be due to DU. In these paper properties, applications, potential environmental and health effects of DU are briefly reviewed

78 FR 32191 - Derivatives

Science.gov (United States)

2013-05-29

... rate risk. This proposed rule applies to federal credit unions and any federally insured, state... risk to the National Credit Union Share Insurance Fund (NCUSIF). \\1\\ A derivative is an instrument... degrees of risk to a credit union. Accordingly, this risk calls for a more robust asset/ liability...

Derived limits and their practical applications

International Nuclear Information System (INIS)

Minarik, F.

1982-01-01

Attention is devoted to the approach and methodological procedure in determining derived limits for surface contamination with special regard to external exposure of hands, inhalation of resuspended activity, contamination of the skin and with regard to ingestion of radioactive material from the skin. In the practical part of the article, results are given of measuring contamination by radionuclides 134 Cs, 133 Cs and 60 Co, and the resulting annual equivalent dose rates and their comparison with derived air contamination in the sense of ICRP Publ. No. 30. (author)

Antihypertensive properties of lactoferricin B-derived peptides.

Science.gov (United States)

Ruiz-Giménez, Pedro; Ibáñez, Aida; Salom, Juan B; Marcos, Jose F; López-Díez, Jose Javier; Vallés, Salvador; Torregrosa, Germán; Alborch, Enrique; Manzanares, Paloma

2010-06-09

A set of eight lactoferricin B (LfcinB)-derived peptides was examined for inhibitory effects on angiotensin I-converting enzyme (ACE) activity and ACE-dependent vasoconstriction, and their hypotensive effect in spontaneously hypertensive rats (SHR). Peptides were derived from different elongations both at the C-terminal and N-terminal ends of the representative peptide LfcinB(20-25), which is known as the LfcinB antimicrobial core. All of the eight LfcinB-derived peptides showed in vitro inhibitory effects on ACE activity with different IC(50) values. Moreover, seven of them showed ex vivo inhibitory effects on ACE-dependent vasoconstriction. No clear correlation between in vitro and ex vivo inhibitory effects was found. Only LfcinB(20-25) and one of its fragments, F1, generated after a simulated gastrointestinal digestion, showed significant antihypertensive effects in SHR after oral administration. Remarkably, F1 did not show any effect on ACE-dependent vasoconstriction in contrast to the inhibitory effect showed by LfcinB(20-25). In conclusion, two LfcinB-derived peptides lower blood pressure and exhibit potential as orally effective antihypertensive compounds, yet a complete elucidation of the mechanism(s) involved deserves further ongoing research.

Enabling quaternion derivatives: the generalized HR calculus

Science.gov (United States)

Xu, Dongpo; Jahanchahi, Cyrus; Took, Clive C.; Mandic, Danilo P.

2015-01-01

Quaternion derivatives exist only for a very restricted class of analytic (regular) functions; however, in many applications, functions of interest are real-valued and hence not analytic, a typical case being the standard real mean square error objective function. The recent HR calculus is a step forward and provides a way to calculate derivatives and gradients of both analytic and non-analytic functions of quaternion variables; however, the HR calculus can become cumbersome in complex optimization problems due to the lack of rigorous product and chain rules, a consequence of the non-commutativity of quaternion algebra. To address this issue, we introduce the generalized HR (GHR) derivatives which employ quaternion rotations in a general orthogonal system and provide the left- and right-hand versions of the quaternion derivative of general functions. The GHR calculus also solves the long-standing problems of product and chain rules, mean-value theorem and Taylor's theorem in the quaternion field. At the core of the proposed GHR calculus is quaternion rotation, which makes it possible to extend the principle to other functional calculi in non-commutative settings. Examples in statistical learning theory and adaptive signal processing support the analysis. PMID:26361555

Numerical estimation of aircrafts' unsteady lateral-directional stability derivatives

Directory of Open Access Journals (Sweden)

Maričić N.L.

2006-01-01

Full Text Available A technique for predicting steady and oscillatory aerodynamic loads on general configuration has been developed. The prediction is based on the Doublet-Lattice Method, Slender Body Theory and Method of Images. The chord and span wise loading on lifting surfaces and longitudinal bodies (in horizontal and vertical plane load distributions are determined. The configuration may be composed of an assemblage of lifting surfaces (with control surfaces and bodies (with circular cross sections and a longitudinal variation of radius. Loadings predicted by this method are used to calculate (estimate steady and unsteady (dynamic lateral-directional stability derivatives. The short outline of the used methods is given in [1], [2], [3], [4] and [5]. Applying the described methodology software DERIV is developed. The obtained results from DERIV are compared to NASTRAN examples HA21B and HA21D from [4]. In the first example (HA21B, the jet transport wing (BAH wing is steady rolling and lateral stability derivatives are determined. In the second example (HA21D, lateral-directional stability derivatives are calculated for forward- swept-wing (FSW airplane in antisymmetric quasi-steady maneuvers. Acceptable agreement is achieved comparing the results from [4] and DERIV.

Derivatives in energy project finance

International Nuclear Information System (INIS)

Spencer, Lloyd

1999-01-01

This chapter focuses on risk management of merchant power generation projects and describes project finance as balancing risk and reward over time. The historical background to risk management is traced, and the case for derivatives in energy project finance is put forward with the hedging of forward output, and forwards and power purchase agreements discussed. Current and prospective usage, and the implementation issues of market liquidity, margin calls, letters of credit, derivative counterparty credit risk, and accounting policy are considered. A detailed example of a gas-fired plant in the US is presented with details given of the distribution of project earnings before tax. Oil field operating cashflows are examined, with reserved flow models, leverage effects, and price hedging addressed

Eulerian derivations of non-inertial Navier-Stokes equations

CSIR Research Space (South Africa)

Combrinck, MA

2014-09-01

Full Text Available The paper presents an Eulerian derivation of the non-inertial Navier-Stokes equations as an alternative to the Lagrangian fluid parcel approach. This work expands on the work of Kageyama and Hyodo [1] who derived the incompressible momentum equation...

Pricing and Hedging of Derivatives in Contagious Markets

DEFF Research Database (Denmark)

Kokholm, Thomas

2016-01-01

It is well documented that stock markets are contagious. A negative shock to one market increases the probability of adverse shocks to other markets. We model this contagion effect by including mutually exciting jump processes in the dynamics of the indexes' log-returns. On top of this we add...... a stochastic volatility component to the dynamics. It is important to take the contagion effect into account if derivatives written on a basket of assets are to be priced or hedged. Due to the affine model specification the joint characteristic function of the log-returns is known analytically, and for two......-asset derivatives prices and show how for certain derivatives the impact is heavy. Moreover, we derive hedge ratios for European put and call options and perform a numerical experiment, which illustrates the impact of contagious jumps on option prices and hedge ratios. Mutually exciting processes have been analyzed...

Strategy for management of investigation-derived waste

International Nuclear Information System (INIS)

Russell, Laura E.; Hopkins, Gregory G.; Smith, Edward H.; Innis, Pamela S.; Stewart, Robert K.

1992-01-01

Large quantities of wastes containing hazardous and/or radiological constituents are being generated as part of the field investigations at the U.S. Department of Energy's Hanford Site in Richland, Washington. A problem exists with the integration of regulations under the Comprehensive Environmental Response, Compensation, and Liability Act of 1980, the Resource Conservation and Recovery Act of 1976, the Washington Hazardous Waste Management Act of 1976, and the Washington Administrative Code Waste management criteria under these regulations need to be consolidated into a single, acceptable management approach that can reasonably be applied to the Hanford Site cleanup effort. In response to this need, a Technical Task Team of representatives from the Washington Department of Ecology, U.S. Environmental Protection Agency, U.S. Department of Energy, and Westinghouse Hanford Company was organized. As a result of nearly two years of negotiations the Technical Task Team produced a specific waste management plan which is presented in the paper as the Strategy for Management of Investigation-Derived Waste. The paper outlines the strategy for handling and storing investigation-derived waste within a given operable unit until a waste unit-specific Record of Decision can be issued. To date, the Strategy for Management of Investigation-Derived Waste has not been finalized. However, formal approval by the U.S. Environmental Protection Agency is expected soon and will result in implementation of the management strategy at waste sites in which they have been identified as the lead regulatory agency. Negotiations with the Washington State Department of Ecology are ongoing. At the time of this writing, it is uncertain what the Washington State Department of Ecology's position will be regarding investigation-derived waste. Both the U.S. Environmental Protection Agency and the U.S. Department of Energy believe the Strategy for Management of Investigation-Derived Waste to be

General hybrid projective complete dislocated synchronization with non-derivative and derivative coupling based on parameter identification in several chaotic and hyperchaotic systems

International Nuclear Information System (INIS)

Sun Jun-Wei; Shen Yi; Zhang Guo-Dong; Wang Yan-Feng; Cui Guang-Zhao

2013-01-01

According to the Lyapunov stability theorem, a new general hybrid projective complete dislocated synchronization scheme with non-derivative and derivative coupling based on parameter identification is proposed under the framework of drive-response systems. Every state variable of the response system equals the summation of the hybrid drive systems in the previous hybrid synchronization. However, every state variable of the drive system equals the summation of the hybrid response systems while evolving with time in our method. Complete synchronization, hybrid dislocated synchronization, projective synchronization, non-derivative and derivative coupling, and parameter identification are included as its special item. The Lorenz chaotic system, Rössler chaotic system, memristor chaotic oscillator system, and hyperchaotic Lü system are discussed to show the effectiveness of the proposed methods. (general)

Animal derived products may conflict with religious patients' beliefs.

Science.gov (United States)

Eriksson, Axelina; Burcharth, Jakob; Rosenberg, Jacob

2013-12-01

Implants and drugs with animal and human derived content are widely used in medicine and surgery, but information regarding ingredients is rarely obtainable by health practitioners. A religious perspective concerning the use of animal and human derived drug ingredients has not thoroughly been investigated. The purpose of this study was to clarify which parts of the medical and surgical treatments offered in western world-hospitals that conflicts with believers of major religions. Religious and spiritual leaders of the six largest religions worldwide (18 branches) were contacted. A standardised questionnaire was sent out regarding their position on the use of human and animal derived products in medical and surgical treatments. Of the 18 contacted religious branches, 10 replied representing the 6 largest religions worldwide. Hindus and Sikhs did not approve of the use of bovine or porcine derived products, and Muslims did not accept the use of porcine derived drugs, dressings or implants. Christians (including Jehovah's Witnesses), Jews and Buddhists accepted the use of all animal and human derived products. However, all religions accepted the use of all these products in case of an emergency and only if alternatives were not available. The views here suggest that religious codes conflict with some treatment regimens. It is crucial to obtain informed consent from patients for the use of drugs and implants with animal or human derived content. However, information on the origin of ingredients in drugs is not always available to health practitioners.

FINANCIAL DERIVATIVES - MEANINGS BEYOND SUBPRIME CRISIS STIGMA

Directory of Open Access Journals (Sweden)

FELICIA RAMONA BIRĂU

2012-12-01

Full Text Available Derivatives are designed as complex financial instruments and their main aim is to manage the risk associated with the underlying asset, in order to ensure against fluctuations in value, or to profit from periods of inactivity, instability or decline. In recent years financial derivatives have experienced a fulminant development and also they have been perceived as an effective lever of the modern economy. The subprime crisis was triggered by a quite significant financial infrastructure glitch, which coalesced around certain factors influence, such as : highly permissive regulation of financial markets, speculative bubbles, underperforming risk management, liquidity injections and structural imbalances. Despite the fact that is a innovative segment and quite difficult affordable as understanding level of the operation mechanisms, financial derivatives were only the tool triggering this global dimension crisis.

Modelling ocean-colour-derived chlorophyll a

Directory of Open Access Journals (Sweden)

S. Dutkiewicz

2018-01-01

Full Text Available This article provides a proof of concept for using a biogeochemical/ecosystem/optical model with a radiative transfer component as a laboratory to explore aspects of ocean colour. We focus here on the satellite ocean colour chlorophyll a (Chl a product provided by the often-used blue/green reflectance ratio algorithm. The model produces output that can be compared directly to the real-world ocean colour remotely sensed reflectance. This model output can then be used to produce an ocean colour satellite-like Chl a product using an algorithm linking the blue versus green reflectance similar to that used for the real world. Given that the model includes complete knowledge of the (model water constituents, optics and reflectance, we can explore uncertainties and their causes in this proxy for Chl a (called derived Chl a in this paper. We compare the derived Chl a to the actual model Chl a field. In the model we find that the mean absolute bias due to the algorithm is 22 % between derived and actual Chl a. The real-world algorithm is found using concurrent in situ measurement of Chl a and radiometry. We ask whether increased in situ measurements to train the algorithm would improve the algorithm, and find a mixed result. There is a global overall improvement, but at the expense of some regions, especially in lower latitudes where the biases increase. Not surprisingly, we find that region-specific algorithms provide a significant improvement, at least in the annual mean. However, in the model, we find that no matter how the algorithm coefficients are found there can be a temporal mismatch between the derived Chl a and the actual Chl a. These mismatches stem from temporal decoupling between Chl a and other optically important water constituents (such as coloured dissolved organic matter and detrital matter. The degree of decoupling differs regionally and over time. For example, in many highly seasonal regions, the timing of initiation

Polymer-Derived Boron Nitride: A Review on the Chemistry, Shaping and Ceramic Conversion of Borazine Derivatives.

Science.gov (United States)

Bernard, Samuel; Miele, Philippe

2014-11-21

Boron nitride (BN) is a III-V compound which is the focus of important research since its discovery in the early 19th century. BN is electronic to carbon and thus, in the same way that carbon exists as graphite, BN exists in the hexagonal phase. The latter offers an unusual combination of properties that cannot be found in any other ceramics. However, these properties closely depend on the synthesis processes. This review states the recent developments in the preparation of BN through the chemistry, shaping and ceramic conversion of borazine derivatives. This concept denoted as Polymer-Derived Ceramics (PDCs) route allows tailoring the chemistry of precursors to elaborate complex BN shapes which cannot be obtained by conventional process. The effect of the chemistry of the molecular precursors, i.e. , borazine and trichloroborazine, and their polymeric derivatives i.e. , polyborazylene and poly[tri(methylamino)borazine], in which the specific functional groups and structural motifs determine the shaping potential by conventional liquid-phase process and plastic-forming techniques is discussed. Nanotubes, nano-fibers, coatings, monoliths and fiber-reinforced matrix composites are especially described. This leads to materials which are of significant engineering interest.

Polymer-Derived Boron Nitride: A Review on the Chemistry, Shaping and Ceramic Conversion of Borazine Derivatives

Directory of Open Access Journals (Sweden)

Samuel Bernard

2014-11-01

Full Text Available Boron nitride (BN is a III-V compound which is the focus of important research since its discovery in the early 19th century. BN is electronic to carbon and thus, in the same way that carbon exists as graphite, BN exists in the hexagonal phase. The latter offers an unusual combination of properties that cannot be found in any other ceramics. However, these properties closely depend on the synthesis processes. This review states the recent developments in the preparation of BN through the chemistry, shaping and ceramic conversion of borazine derivatives. This concept denoted as Polymer-Derived Ceramics (PDCs route allows tailoring the chemistry of precursors to elaborate complex BN shapes which cannot be obtained by conventional process. The effect of the chemistry of the molecular precursors, i.e., borazine and trichloroborazine, and their polymeric derivatives i.e., polyborazylene and poly[tri(methylaminoborazine], in which the specific functional groups and structural motifs determine the shaping potential by conventional liquid-phase process and plastic-forming techniques is discussed. Nanotubes, nano-fibers, coatings, monoliths and fiber-reinforced matrix composites are especially described. This leads to materials which are of significant engineering interest.

Evaluation of satellite derived spectral diffuse attenuation coefficients

Digital Repository Service at National Institute of Oceanography (India)

Suresh, T.; Talaulikar, M.; Desa, E.; Mascarenhas, A.A.M.Q.; Matondkar, S.G.P.

, 443, 490, 510, 555 and 670 nm derived from the ocean color satellite sensor, SeaWiFS with the in-situ measured values from the Arabian Sea is compared. The satellite derived values are found to be comparable to the measured values in the lower...

RDT&E for Emerging Contaminants

Science.gov (United States)

2010-06-01

Perchlorate ● NDMA ● 1,4-Dioxane ● PFCs 8 Perchlorate Issue ● Broad Use & Occurrence  DoD - Rocket propellant - Insensitive munitions  Pyrotechnics and...and 18O -20 -15 -10 -5.0 0.0 5.0 -30 -25 -20 -15 -10 -5 0 5 10 Laboratory Military Natural Herbicides Gunpowder Road Flares Taiwan 3 7 C l 18 O 27 NDMA ...Toxicology  NDMA is a potent mutagen, teratogen, & carcinogen.  EPA 10-6 Lifetime Cancer Risk = 0.7 ng/L.  California DHS; 10 ng/L Action

Multi-channel near infrared spectroradiometer

International Nuclear Information System (INIS)

Joseph, G.B.; Biddles, B.J.; D'silva, R.A.; Picot, A.J.; Ackerman, M.J.

1988-01-01

A multichannel spectroradiometer has been developed by Sira Ltd. for the study of rapidly varying events in the near infrared. The instrument is being used in the examination of gun flashes, rocket motor exhaust efflux analysis and ordnance or pyrotechnic flash studies. The spectral range of about 1.4 to 5.2 microns is covered in two bands with the first order dispersion from a pair of ruled blazed gratings being imaged onto a pair of detector arrays. Data may be logged at a rate of 1000 complete spectra per second

Advanced Instrumentation for Aero Engine Components: Conference Proceedings of the Propulsion and Energetics Panel Symposium (67th) Held in Philadelphia, Pennsylvania on 19-23 May 1986.

Science.gov (United States)

1986-11-01

8217 un melange do 1 % do DOP dana 1 acool doitudonner uno granulom ~trie plus fine do 0,2 &’m peu diaporshe. Leo ptntes dos courbos u fr x) au travers d’ un...Figu-e 3). Thermal SAPPHIREO CAt IBERS radiation is collected directly from the PTICl F pyrotechnic and guided to a set of calcium fluoride lenses. The...station- naires. Cat article pr6mante donc lea mnoe itudi~s at r~aliS 4 a Par ILONERA (essats soufflerie) at La SNECMA (esas aur machines A 106chelle

Guidelines of the Design of Electropyrotechnic Firing Circuit for Unmanned Flight and Ground Test Projects

Science.gov (United States)

Gonzalez, Guillermo A.; Lucy, Melvin H.; Massie, Jeffrey J.

2013-01-01

The NASA Langley Research Center, Engineering Directorate, Electronic System Branch, is responsible for providing pyrotechnic support capabilities to Langley Research Center unmanned flight and ground test projects. These capabilities include device selection, procurement, testing, problem solving, firing system design, fabrication and testing; ground support equipment design, fabrication and testing; checkout procedures and procedure?s training to pyro technicians. This technical memorandum will serve as a guideline for the design, fabrication and testing of electropyrotechnic firing systems. The guidelines will discuss the entire process beginning with requirements definition and ending with development and execution.

Microwave Synthesis, Characterization, and Antimicrobial Activity of Some Novel Isatin Derivatives

Directory of Open Access Journals (Sweden)

Ayman El-Faham

2015-01-01

Full Text Available Three series of isatin derivatives [3-hydrazino, 3-thiosemicarbazino, and 3-imino carboxylic acid derivatives] were synthesized employing microwave irradiation. The prepared compounds were characterized by FT-IR, NMR, elemental analysis, and X-ray crystallography for derivatives 5b. The synthesized compounds were screened for antimicrobial activity against selected bacteria and fungi. The results revealed that the N-alkyl isatin derivatives were biologically active with different spectrums activity. Most of the 3-hydrazino and 3-thiosemicarbazino isatin derivatives were biologically inactive and generally the active derivatives showed weak to moderate activity mainly against Gram-positive bacteria. The imino isatin carboxylic acid derivatives (2-[4-(1-benzyl-5-bromo-2-oxoindolin-3-ylideneamino phenyl]acetic acid, 5d showed promising activity against all tested Gram-positive bacteria and against fungal pathogens.

Benzoxazole derivatives suppress lipopolysaccharide-induced mast cell activation.

Science.gov (United States)

Cho, Kyung-Ah; Park, Minhwa; Kim, Yu-Hee; Choo, Hea-Young Park; Lee, Kyung Ho

2018-05-01

Mast cells are central regulators of allergic inflammation that function by releasing various proallergic inflammatory mediators, including histamine, eicosanoids and proinflammatory cytokines. Occasionally, bacterial infections may initiate or worsen allergic inflammation. A number of studies have indicated that activation of lipoxygenase in mast cells positive regulates allergic inflammatory responses by generating leukotrienes and proinflammatory cytokines. In the present study, the effects of benzoxazole derivatives on the lipopolysaccharide (LPS)‑induced expression of proinflammatory cytokines, production of histamine and surface expression of co‑stimulatory molecules on bone marrow-derived mast cells (BMMCs) were studied. The benzoxazole derivatives significantly reduced the expression of interleukin (IL)‑1β, IL‑6, IL‑13, tumor necrosis factor‑α, perilipin (PLIN) 2, and PLIN3 in BMMCs treated with LPS. Furthermore, histamine production was suppressed in BMMCs treated with LPS, or treated with phorbol-12-myristate-13-acetate/ionomycin. Benzoxazole derivatives marginally affected the surface expression of cluster of differentiation (CD)80 and CD86 on BMMCs in the presence of LPS, although LPS alone did not increase the expression of those proteins. Therefore, benzoxazole derivatives inhibited the secretion of proinflammatory cytokines in mast cells and may be potential candidate anti‑allergic agents to suppress mast cell activation.

Holographic entanglement entropy for the most general higher derivative gravity

International Nuclear Information System (INIS)

Miao, Rong-Xin; Guo, Wu-zhong

2015-01-01

The holographic entanglement entropy for the most general higher derivative gravity is investigated. We find a new type of Wald entropy, which appears on entangling surface without the rotational symmetry and reduces to usual Wald entropy on Killing horizon. Furthermore, we obtain a formal formula of HEE for the most general higher derivative gravity and work it out exactly for some squashed cones. As an important application, we derive HEE for gravitational action with one derivative of the curvature when the extrinsic curvature vanishes. We also study some toy models with non-zero extrinsic curvature. We prove that our formula yields the correct universal term of entanglement entropy for 4d CFTs. Furthermore, we solve the puzzle raised by Hung, Myers and Smolkin that the logarithmic term of entanglement entropy derived from Weyl anomaly of CFTs does not match the holographic result even if the extrinsic curvature vanishes. We find that such mismatch comes from the ‘anomaly of entropy’ of the derivative of curvature. After considering such contributions carefully, we resolve the puzzle successfully. In general, we need to fix the splitting problem for the conical metrics in order to derive the holographic entanglement entropy. We find that, at least for Einstein gravity, the splitting problem can be fixed by using equations of motion. How to derive the splittings for higher derivative gravity is a non-trivial and open question. For simplicity, we ignore the splitting problem in this paper and find that it does not affect our main results.

Pricing of Traffic Light Options and other Correlation Derivatives

DEFF Research Database (Denmark)

Kokholm, Thomas

This paper considers derivatives with payoffs that depend on a stock index and underlying LIBOR rates. A traffic light option pricing formula is derived under lognormality assumptions on the underlying processes. The traffic light option is aimed at the Danish life and pension sector to help...... the pricing of a hybrid derivative known as the EUR Sage Note. The approach can be used to price many existing structured products....

Derivative-Based Trapezoid Rule for the Riemann-Stieltjes Integral

Directory of Open Access Journals (Sweden)

Weijing Zhao

2014-01-01

Full Text Available The derivative-based trapezoid rule for the Riemann-Stieltjes integral is presented which uses 2 derivative values at the endpoints. This kind of quadrature rule obtains an increase of two orders of precision over the trapezoid rule for the Riemann-Stieltjes integral and the error term is investigated. At last, the rationality of the generalization of derivative-based trapezoid rule for Riemann-Stieltjes integral is demonstrated.

Brevianamides and Mycophenolic Acid Derivatives from the Deep-Sea-Derived Fungus Penicillium brevicompactum DFFSCS025

Directory of Open Access Journals (Sweden)

Xinya Xu

2017-02-01

Full Text Available Four new compounds (1–4, including two brevianamides and two mycochromenic acid derivatives along with six known compounds were isolated from the deep-sea-derived fungus Penicillium brevicompactum DFFSCS025. Their structures were elucidated by spectroscopic analysis. Moreover, the absolute configurations of 1 and 2 were determined by quantum chemical calculations of the electronic circular dichroism (ECD spectra. Compound 9 showed moderate cytotoxicity against human colon cancer HCT116 cell line with IC50 value of 15.6 μM. In addition, 3 and 5 had significant antifouling activity against Bugula neritina larval settlement with EC50 values of 13.7 and 22.6 μM, respectively. The NMR data of 6, 8, and 9 were assigned for the first time.

A classical approach to higher-derivative gravity

International Nuclear Information System (INIS)

Accioly, A.J.

1988-01-01

Two classical routes towards higher-derivative gravity theory are described. The first one is a geometrical route, starting from first principles. The second route is a formal one, and is based on a recent theorem by Castagnino et.al. [J. Math. Phys. 28 (1987) 1854]. A cosmological solution of the higher-derivative field equations is exhibited which in a classical framework singles out this gravitation theory. (author) [pt

Higher order derivatives via Hamilton-Jacobi approach

International Nuclear Information System (INIS)

Bertin, M.C.; Pimentel, B.M.; Pompeia, P.J.

2006-01-01

In this work we will show how can be derived a general method for dealing with Lagrangians containing high order derivatives using the Hamilton-Jacobi Formalism for singular systems. By the expansion the configuration space of a n dimensional system we will be able to introduce first order actions and build the equations of motion of the system. We will work with the Generalized Electrodynamics of Podolsky as an example. (author)

A new derivation of Dirac's magnetic monopole strength

International Nuclear Information System (INIS)

Panat, P V

2003-01-01

A new derivation of the strength of Dirac's magnetic monopole is presented which does not require an explicit form of the magnetic induction in terms of g, the magnetic pole strength. The derivation essentially uses a modification of Faraday's law of induction and quantization of angular momentum

Boronate Derivatives of Functionally Diverse Catechols: Stability Studies

Directory of Open Access Journals (Sweden)

Kamal Aziz Ketuly

2010-03-01

Full Text Available Benzeneboronate of catecholic carboxyl methyl esters, N-acetyldopamine, coumarin and catechol estrogens were prepared as crystalline derivatives in high yield. Related catechol compounds with extra polar functional group(s (OH, NH2 do not form or only partially form unstable cyclic boronate derivatives.

76 FR 43892 - Modifications of Certain Derivative Contracts

Science.gov (United States)

2011-07-22

... obligations under the derivative contract and the party to which the rights and obligations are transferred or... assigning its rights and obligations under the contract and the party to which the rights and obligations... Modifications of Certain Derivative Contracts AGENCY: Internal Revenue Service (IRS), Treasury. ACTION: Final...

Application of artificial intelligence for detecting derived viruses

CSIR Research Space (South Africa)

Asiru, OF

2017-06-01

Full Text Available they infect files and systems is still the same. Hence, such viruses cannot be argued to be new. In this paper, the authors refer to such viruses as derived viruses. Just like new viruses, derived viruses are hard to detect with current scanning...

Anti-Inflammatory and Immunoregulatory Functions of Artemisinin and Its Derivatives

Directory of Open Access Journals (Sweden)

Chenchen Shi

2015-01-01

Full Text Available Artemisinin and its derivatives are widely used in the world as the first-line antimalarial drug. Recently, growing evidences reveal that artemisinin and its derivatives also possess potent anti-inflammatory and immunoregulatory properties. Meanwhile, researchers around the world are still exploring the unknown bioactivities of artemisinin derivatives. In this review, we provide a comprehensive discussion on recent advances of artemisinin derivatives affecting inflammation and autoimmunity, the underlying molecular mechanisms, and also drug development of artemisinins beyond antimalarial functions.

Spatial Rotation of the Fractional Derivative in Two-Dimensional Space

Directory of Open Access Journals (Sweden)

Ehab Malkawi

2015-01-01

Full Text Available The transformations of the partial fractional derivatives under spatial rotation in R2 are derived for the Riemann-Liouville and Caputo definitions. These transformation properties link the observation of physical quantities, expressed through fractional derivatives, with respect to different coordinate systems (observers. It is the hope that such understanding could shed light on the physical interpretation of fractional derivatives. Also it is necessary to be able to construct interaction terms that are invariant with respect to equivalent observers.

ncRNA consensus secondary structure derivation using grammar strings.

Science.gov (United States)

Achawanantakun, Rujira; Sun, Yanni; Takyar, Seyedeh Shohreh

2011-04-01

Many noncoding RNAs (ncRNAs) function through both their sequences and secondary structures. Thus, secondary structure derivation is an important issue in today's RNA research. The state-of-the-art structure annotation tools are based on comparative analysis, which derives consensus structure of homologous ncRNAs. Despite promising results from existing ncRNA aligning and consensus structure derivation tools, there is a need for more efficient and accurate ncRNA secondary structure modeling and alignment methods. In this work, we introduce a consensus structure derivation approach based on grammar string, a novel ncRNA secondary structure representation that encodes an ncRNA's sequence and secondary structure in the parameter space of a context-free grammar (CFG) and a full RNA grammar including pseudoknots. Being a string defined on a special alphabet constructed from a grammar, grammar string converts ncRNA alignment into sequence alignment. We derive consensus secondary structures from hundreds of ncRNA families from BraliBase 2.1 and 25 families containing pseudoknots using grammar string alignment. Our experiments have shown that grammar string-based structure derivation competes favorably in consensus structure quality with Murlet and RNASampler. Source code and experimental data are available at http://www.cse.msu.edu/~yannisun/grammar-string.

Novel Aflatoxin Derivatives and Protein Conjugates

Directory of Open Access Journals (Sweden)

Reinhard Niessner

2007-03-01

Full Text Available Aflatoxins, a group of structurally related mycotoxins, are well known for their toxic and carcinogenic effects in humans and animals. Aflatoxin derivatives and protein conjugates are needed for diverse analytical applications. This work describes a reliable and fast synthesis of novel aflatoxin derivatives, purification by preparative HPLC and characterisation by ESI-MS and one- and two-dimensional NMR. Novel aflatoxin bovine serum albumin conjugates were prepared and characterised by UV absorption and MALDI-MS. These aflatoxin protein conjugates are potentially interesting as immunogens for the generation of aflatoxin selective antibodies with novel specificities.

Special relativity derived from spacetime magma.

Science.gov (United States)

Greensite, Fred

2014-01-01

We present a derivation of relativistic spacetime largely untethered from specific physical considerations, in constrast to the many physically-based derivations that have appeared in the last few decades. The argument proceeds from the inherent magma (groupoid) existing on the union of spacetime frame components [Formula: see text] and Euclidean [Formula: see text] which is consistent with an "inversion symmetry" constraint from which the Minkowski norm results. In this context, the latter is also characterized as one member of a class of "inverse norms" which play major roles with respect to various unital [Formula: see text]-algebras more generally.

Special relativity derived from spacetime magma.

Directory of Open Access Journals (Sweden)

Fred Greensite

Full Text Available We present a derivation of relativistic spacetime largely untethered from specific physical considerations, in constrast to the many physically-based derivations that have appeared in the last few decades. The argument proceeds from the inherent magma (groupoid existing on the union of spacetime frame components [Formula: see text] and Euclidean [Formula: see text] which is consistent with an "inversion symmetry" constraint from which the Minkowski norm results. In this context, the latter is also characterized as one member of a class of "inverse norms" which play major roles with respect to various unital [Formula: see text]-algebras more generally.

Quantum computational finance: Monte Carlo pricing of financial derivatives

OpenAIRE

Rebentrost, Patrick; Gupt, Brajesh; Bromley, Thomas R.

2018-01-01

Financial derivatives are contracts that can have a complex payoff dependent upon underlying benchmark assets. In this work, we present a quantum algorithm for the Monte Carlo pricing of financial derivatives. We show how the relevant probability distributions can be prepared in quantum superposition, the payoff functions can be implemented via quantum circuits, and the price of financial derivatives can be extracted via quantum measurements. We show how the amplitude estimation algorithm can...

Hedging Yield with Weather Derivatives: A Role for Options

OpenAIRE

Manfredo, Mark R.; Richards, Timothy J.

2005-01-01

While there are few risk management alternatives available to specialty crop growers, weather derivatives provide an important advancement. As with the use of any derivatives contract, the behavior of the basis will ultimately determine the net-hedged outcome. However, when using weather derivatives to hedge yield risks for specialty crops, growers face a unique form of basis risk because weather (temperature) and yield are nonlinearly related. Using the forecast encompassing principle, this ...

Metal borohydrides and derivatives

DEFF Research Database (Denmark)

Paskevicius, Mark; Haarh Jepsen, Lars; Schouwink, Pascal

2017-01-01

major classes of metal borohydride derivatives have also been discovered: anion-substituted compounds where the complex borohydride anion, BH4 -, is replaced by another anion, i.e. a halide or amide ion; and metal borohydrides modified with neutral molecules, such as NH3, NH3BH3, N2H4, etc. Here, we...

Push-outs of derivations

DEFF Research Database (Denmark)

Grønbæk, Niels

2008-01-01

Let A be a Banach algebra and let X be a Banach A-bimodule. In studying H¹(A,X) it is often useful to extend a given derivation D: A->X to a Banach algebra B containing A as an ideal, thereby exploiting (or establishing) hereditary properties. This is usually done using (bounded/unbounded) approx...

Fundamentals of futures, options, basis and derivatives

Energy Technology Data Exchange (ETDEWEB)

Jones, D. [TD Securities Inc., Toronto, ON (Canada)

1997-08-01

Characteristic features of futures and options contracts, basis differentials and derivatives were defined and explained. A futures contract refers to an exchange-traded supply contract between a buyer and a seller where the buyer is obligated to take delivery and the seller is obligated to provide delivery of a fixed amount of a commodity at a predetermined price at a specified location. In contrast, an option contract gives the purchaser the right, but not the obligation, to buy or sell the underlying commodity at a certain price on or before an agreed date. Basis differential refers to the discount between two distinct delivery points to reflect the relative value of a commodity, such as natural gas, at those points. Advantages and disadvantages of futures and options contacts, the factors affecting options pricing, and basis differentials, and the methods of calculating basis differentials were described. The nature and intricacies of derivatives, their benefits, in particular their use as a tool for the effective management of the volatilities associated with the oil and gas industry were explained. Their shortcomings such as the high liquidity risk, were also described. Examples of derivative transactions were provided to illustrate the interrelationships of futures/options/derivatives, and their role in financial risk management.

Fundamentals of futures, options, basis and derivatives

International Nuclear Information System (INIS)

Jones, D.

1997-01-01

Characteristic features of futures and options contracts, basis differentials and derivatives were defined and explained. A futures contract refers to an exchange-traded supply contract between a buyer and a seller where the buyer is obligated to take delivery and the seller is obligated to provide delivery of a fixed amount of a commodity at a predetermined price at a specified location. In contrast, an option contract gives the purchaser the right, but not the obligation, to buy or sell the underlying commodity at a certain price on or before an agreed date. Basis differential refers to the discount between two distinct delivery points to reflect the relative value of a commodity, such as natural gas, at those points. Advantages and disadvantages of futures and options contacts, the factors affecting options pricing, and basis differentials, and the methods of calculating basis differentials were described. The nature and intricacies of derivatives, their benefits, in particular their use as a tool for the effective management of the volatilities associated with the oil and gas industry were explained. Their shortcomings such as the high liquidity risk, were also described. Examples of derivative transactions were provided to illustrate the interrelationships of futures/options/derivatives, and their role in financial risk management

Chemistry of aliphatic sulfurpentafluoride derivatives

International Nuclear Information System (INIS)

Bissell, E.R.

1975-01-01

This report summarizes the literature through 1974 on aliphatic sulfurpentafluoride compounds. Methods of preparation and methods of transforming one pentafluorothio compound into another are briefly discussed. The physical properties of all known derivatives are tabulated

Funding climate adaptation strategies with climate derivatives

Directory of Open Access Journals (Sweden)

L. Richard Little

2015-01-01

Full Text Available Climate adaptation requires large capital investments that could be provided not only by traditional sources like governments and banks, but also by derivatives markets. Such markets would allow two parties with different tolerances and expectations about climate risks to transact for their mutual benefit and, in so doing, finance climate adaptation. Here we calculate the price of a derivative called a European put option, based on future sea surface temperature (SST in Tasmania, Australia, with an 18 °C strike threshold. This price represents a quantifiable indicator of climate risk, and forms the basis for aquaculture industries exposed to the risk of higher SST to finance adaptation strategies through the sale of derivative contracts. Such contracts provide a real incentive to parties with different climate outlooks, or risk exposure to take a market assessment of climate change.

SYNTHESIS OF METHACRYLATES FROM COAL-DERIVED SYNGAS

Energy Technology Data Exchange (ETDEWEB)

Jang, B.W.L.; Spivey, J.J.; Gogate, M.R.; Zoeller, J.R.; Colberg, R.D.; Choi, G.N.

1999-12-01

Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel have developed a novel process for synthesis of methyl methacrylate (MMA) from coal-derived syngas, under a contract from the US Department of Energy/Fossil Energy Technology Center (DOE/FETC). This project has resulted in five US patents (four already published and one pending publication). It has served as the basis for the technical and economic assessment of the production of this high-volume intermediate from coal-derived synthesis gas. The three-step process consists of the synthesis of a propionate from ethylene carbonylation using coal-derived CO, condensation of the propionate with formaldehyde to form methacrylic acid (MAA); and esterification of MAA with methanol to yield MMA. The first two steps, propionate synthesis and condensation catalysis, are the key technical challenges and the focus of the research presented here.

Weather Derivatives – Origin, Types and Application

OpenAIRE

Piotr Binkowski

2008-01-01

The number of companies that are exposed to the revenues loss risk caused by weather variability is still increasing. The businesses that are mostly exposed to weather risk are following: energy, agriculture, constructions and transport. That situation has initiated dynamic growth of weather derivatives markets as well as the awareness of the weather risk among the market participants. Presently, the weather derivatives markets evaluate rapidly in all the mature economies: USA, Asia and Europ...

Photochemistry and photopolymerisation activity of novel thioxanthone derivatives

International Nuclear Information System (INIS)

Nik Ghazali Salleh; Allen, N.S.; Edge, M.; Shah, M.; Green, A.

1999-01-01

In this paper, we aim to examine the influence of a range of 4-oxy substituted groups on the photochemical and photopolymerization of 1-chloro- and 1-phenylthio-thioxanhone. Here we have examined the effect of a number of acyloxy groups attached to the ring 4-position. The study includes a spectroscopic and photoinitiated polymerization evaluation using real time infrared and photocalorimetry. The photoactivities of the initiators are compared with those of the standard industrial system such as the 4-n-propoxy derivative and the basic compound like the 1-chloro-4-hydroxyl derivative which was used to synthesise all the derivatives examined here

Molecular Docking Study on Galantamine Derivatives as Cholinesterase Inhibitors.

Science.gov (United States)

Atanasova, Mariyana; Yordanov, Nikola; Dimitrov, Ivan; Berkov, Strahil; Doytchinova, Irini

2015-06-01

A training set of 22 synthetic galantamine derivatives binding to acetylcholinesterase was docked by GOLD and the protocol was optimized in terms of scoring function, rigidity/flexibility of the binding site, presence/absence of a water molecule inside and radius of the binding site. A moderate correlation was found between the affinities of compounds expressed as pIC50 values and their docking scores. The optimized docking protocol was validated by an external test set of 11 natural galantamine derivatives and the correlation coefficient between the docking scores and the pIC50 values was 0.800. The derived relationship was used to analyze the interactions between galantamine derivatives and AChE. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

21 CFR 173.140 - Esterase-lipase derived from Mucor miehei.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Esterase-lipase derived from Mucor miehei. 173.140... HUMAN CONSUMPTION Enzyme Preparations and Microorganisms § 173.140 Esterase-lipase derived from Mucor miehei. Esterase-lipase enzyme, consisting of enzyme derived from Mucor miehei var. Cooney et Emerson by...

Superstability of Generalized Derivations

Directory of Open Access Journals (Sweden)

Esmaeil Ansari-Piri

2010-01-01

Full Text Available We investigate the superstability of the functional equation f(xy=xf(y+g(xy, where f and g are the mappings on Banach algebra A. We have also proved the superstability of generalized derivations associated to the linear functional equation f(γx+βy=γf(x+βf(y, where γ,β∈ℂ.

Synthesis and Antibacterial Screening of Novel Derivatives of Embelin

Science.gov (United States)

Subramanian, L.; Leema, M.; Pradeep, N. S.; Joy, B.; Pillai, Z. S.

2018-02-01

Embelin, a naturally occurring compound extracted from Embelia ribes is used in Ayurvedic system of medicine owing to its wide spectrum of biological activities. In the present work, we have aimed at improving the efficacy of Embelin by appropriate structural modifications. A few novel derivatives of Embelin have been prepared. The antibacterial screening of these derivatives were carried out and compared with a well known antibiotic, Streptomycin. The derivatives exhibited better activity than Streptomycin and the lead molecule, Embelin.

The Pricing of Traffic Light Options and other Correlation Derivatives

DEFF Research Database (Denmark)

Kokholm, Thomas

This paper considers the valuation of European style derivatives with payoffs depending on both a stock index and underlying LIBOR rates. The model has the attractive feature that it is based on observable market quantities which makes it very easy to calibrate. A closed form solution is derived...... for the price of the correlation derivative known as the traffic light option under lognormality assumptions for the underlying processes. A pricing approach for more general payoffs is presented, and an illustration is performed with Monte Carlo simulation by the pricing of a specific hybrid derivative...

Higher derivatives in gauge transformations

International Nuclear Information System (INIS)

Gogilidze, S.A.; Sanadze, V.V.; Tkebuchava, F.G.

1992-01-01

The mechanism of appearance of highher derivatives of coordinates in the symmetry transformation law of the second Noether's theorem is established. It is shown that the corresponding transformations are canonical in the extended phase space. 15 refs

Fabrication and Characterization of Nanoenergetic Hollow Spherical Hexanitrostibene (HNS Derivatives

Directory of Open Access Journals (Sweden)

Xiong Cao

2018-05-01

Full Text Available The spherization of nanoenergetic materials is the best way to improve the sensitivity and increase loading densities and detonation properties for weapons and ammunition, but the preparation of spherical nanoenergetic materials with high regularization, uniform size and monodispersity is still a challenge. In this paper, nanoenergetic hollow spherical hexanitrostibene (HNS derivatives were fabricated via a one-pot copolymerization strategy, which is based on the reaction of HNS and piperazine in acetonitrile solution. Characterization results indicated the as-prepared reaction nanoenergetic products were HNS-derived oligomers, where a free radical copolymerization reaction process was inferred. The hollow sphere structure of the HNS derivatives was characterized by scanning electron microscopy (SEM, transmission electron microscope (TEM, and synchrotron radiation X-ray imaging technology. The properties of the nanoenergetic hollow spherical derivatives, including thermal decomposition and sensitivity are discussed in detail. Sensitivity studies showed that the nanoenergetic derivatives exhibited lower impact, friction and spark sensitivity than raw HNS. Thermogravimetric-differential scanning calorimeter (TG-DSC results showed that continuous exothermic decomposition occurred in the whole temperature range, which indicated that nanoenergetic derivatives have a unique role in thermal applications. Therefore, nanoenergetic hollow spherical HNS derivatives could provide a new way to modify the properties of certain energetic compounds and fabricate spherical nanomaterials to improve the charge configuration.

18 CFR 367.2450 - Account 245, Derivative instrument liabilities-Hedges

Science.gov (United States)

2010-04-01

..., Derivative instrument liabilities—Hedges (a) This account must include the change in the fair value of... service company must record the change in the fair value of a derivative instrument liability related to a... change in the fair value of a derivative instrument liability related to a fair value hedge in this...

18 CFR 367.1760 - Account 176, Derivative instrument assets-Hedges.

Science.gov (United States)

2010-04-01

... change in the fair value of derivative instrument assets designated by the service company as cash flow... flow hedge it will record the change in the fair value of the derivative instrument in this account... must record the change in the fair value of the derivative instrument in this account with a concurrent...

12 CFR 223.33 - What rules apply to derivative transactions?

Science.gov (United States)

2010-01-01

... Requirements Under Section 23A § 223.33 What rules apply to derivative transactions? (a) Market terms... with affiliates comply with the market terms requirement of § 223.51. (c) Credit derivatives. A credit... 12 Banks and Banking 3 2010-01-01 2010-01-01 false What rules apply to derivative transactions...

Bioactive Phenylalanine Derivatives and Cytochalasins from the Soft Coral-Derived Fungus, Aspergillus elegans

Directory of Open Access Journals (Sweden)

Xue-Ping Sun

2013-06-01

Full Text Available One new phenylalanine derivative 4′-OMe-asperphenamate (1, along with one known phenylalanine derivative (2 and two new cytochalasins, aspochalasin A1 (3 and cytochalasin Z24 (4, as well as eight known cytochalasin analogues (5–12 were isolated from the fermentation broth of Aspergillus elegans ZJ-2008010, a fungus obtained from a soft coral Sarcophyton sp. collected from the South China Sea. Their structures and the relative configurations were elucidated using comprehensive spectroscopic methods. The absolute configuration of 1 was determined by chemical synthesis and Marfey’s method. All isolated metabolites (1–12 were evaluated for their antifouling and antibacterial activities. Cytochalasins 5, 6, 8 and 9 showed strong antifouling activity against the larval settlement of the barnacle Balanus amphitrite, with the EC50 values ranging from 6.2 to 37 μM. This is the first report of antifouling activity for this class of metabolites. Additionally, 8 exhibited a broad spectrum of antibacterial activity, especially against four pathogenic bacteria Staphylococcus albus, S. aureus, Escherichia coli and Bacillus cereus.

17 CFR 240.16c-4 - Derivative securities.

Science.gov (United States)

2010-04-01

... 17 Commodity and Securities Exchanges 3 2010-04-01 2010-04-01 false Derivative securities. 240.16c-4 Section 240.16c-4 Commodity and Securities Exchanges SECURITIES AND EXCHANGE COMMISSION (CONTINUED... Exchange Act of 1934 Exemption of Certain Transactions from Section 16(c) § 240.16c-4 Derivative securities...

Characterization of the Lovelock gravity by Bianchi derivative

Indian Academy of Sciences (India)

We prove the theorem: The second-order quasilinear differential operator as a second-rank divergence-free tensor in the equation of motion for gravitation could always be derived from the trace of the Bianchi derivative of the fourth-rank tensor, which is a homogeneous polynomial in curvatures. The existence of such a ...

Kinetic Theory Derivation of the Adiabatic Law for Ideal Gases.

Science.gov (United States)

Sobel, Michael I.

1980-01-01

Discusses how the adiabatic law for ideal gases can be derived from the assumption of a Maxwell-Boltzmann (or any other) distribution of velocities--in contrast to the usual derivations from thermodynamics alone, and the higher-order effect that leads to one-body viscosity. An elementary derivation of the adiabatic law is given. (Author/DS)

Characterization Of Bovine Adipose-Derived Stem Cells

OpenAIRE

Daniel Cebo

2017-01-01

Bovine adipose-derived stem cells were obtained from the subcutaneous abdominal adipose tissue. The cells were cultured by the modified tissue-explants method developed in our laboratory and then analyzed using optical microscopy and flow cytometry. These cells were able to replicate in our cell culture conditions. cell Flow cytometry showed that bovine adipose-derived stem cells expressed mesenchymal stem cell markers CD73 and CD90. Meanwhile haematopoietic markers CD45 and CD34 are absent f...

Complexes of salicylic acid and its derivatives

Energy Technology Data Exchange (ETDEWEB)

Tel' zhenskaya, P N; Shvarts, E M [AN Latvijskoj SSR, Riga. Inst. Neorganicheskoj Khimii

1977-01-01

A generalization and systematization have been made of literature data on complexing of various elements, including beryllium, cadmium, boron, indium, rare-earth elements, actinides, and transition elements with salicylic acid and it derivatives (amino-, nitro- and halosalicylic acids). The effect of the position and nature of the substitute, in the case of salicylic acid derivatives, on the complexing process is discussed. Certain physicochemical properties of the complexes under consideration are described along with data indicative of their stability.

On computing Laplace's coefficients and their derivatives.

Science.gov (United States)

Gerasimov, I. A.; Vinnikov, E. L.

The algorithm of computing Laplace's coefficients and their derivatives is proposed with application of recurrent relations. The A.G.M.-method is used for the calculation of values L0(0), L0(1). The FORTRAN-program corresponding to the algorithm is given. The precision control was provided with numerical integrating by Simpsons method. The behavior of Laplace's coefficients and their third derivatives whith varying indices K, n for fixed values of the α-parameter is presented graphically.

Deriving Trading Rules Using Gene Expression Programming

Directory of Open Access Journals (Sweden)

Adrian VISOIU

2011-01-01

Full Text Available This paper presents how buy and sell trading rules are generated using gene expression programming with special setup. Market concepts are presented and market analysis is discussed with emphasis on technical analysis and quantitative methods. The use of genetic algorithms in deriving trading rules is presented. Gene expression programming is applied in a form where multiple types of operators and operands are used. This gives birth to multiple gene contexts and references between genes in order to keep the linear structure of the gene expression programming chromosome. The setup of multiple gene contexts is presented. The case study shows how to use the proposed gene setup to derive trading rules encoded by Boolean expressions, using a dataset with the reference exchange rates between the Euro and the Romanian leu. The conclusions highlight the positive results obtained in deriving useful trading rules.

5-Nitroimidazole Derivatives and their Antimicrobial Activity

International Nuclear Information System (INIS)

Khan, K.M.; Salar, U.; Yousuf, S.; Naz, F.

2016-01-01

5-Nitroimidazole derivatives 2-8 were synthesized from secnidazole. The syntheses were accomplished in two steps which start from the oxidation of secnidazole to the secnidazolone 1. Secnidazolone 1 was converted into its hydrazone derivative 2-8 by treating with different substituted acid hydrazide. Compounds 2-8 were evaluated for their antimicrobial activity against Gram-positive and Gram-negative bacteria, compounds 3 and 4 showed the significant activity against Staphylococcus epidermidis, however, compound 2 showed good inhibitions against Corynebacterium diphtheria when compared with the standard. Compound 3 showed good inhibitory potential against tested Gram-negative bacterial strains i.e. Enterobacter aerogene, Escherichia coli, Salmonella typhi, Salmonella paratyphi A, Shigella flexeneri and Vibrio choleriae. All synthetic derivatives were also tested against eight fungal stains, however, they were weekly active against Aspergillus flavus and Candida albican. The synthesized compounds were characterized by different spectroscopy techniques. (author)

Distributed order reaction-diffusion systems associated with Caputo derivatives

Science.gov (United States)

Saxena, R. K.; Mathai, A. M.; Haubold, H. J.

2014-08-01

This paper deals with the investigation of the solution of an unified fractional reaction-diffusion equation of distributed order associated with the Caputo derivatives as the time-derivative and Riesz-Feller fractional derivative as the space-derivative. The solution is derived by the application of the joint Laplace and Fourier transforms in compact and closed form in terms of the H-function. The results derived are of general nature and include the results investigated earlier by other authors, notably by Mainardi et al. ["The fundamental solution of the space-time fractional diffusion equation," Fractional Calculus Appl. Anal. 4, 153-202 (2001); Mainardi et al. "Fox H-functions in fractional diffusion," J. Comput. Appl. Math. 178, 321-331 (2005)] for the fundamental solution of the space-time fractional equation, including Haubold et al. ["Solutions of reaction-diffusion equations in terms of the H-function," Bull. Astron. Soc. India 35, 681-689 (2007)] and Saxena et al. ["Fractional reaction-diffusion equations," Astrophys. Space Sci. 305, 289-296 (2006a)] for fractional reaction-diffusion equations. The advantage of using the Riesz-Feller derivative lies in the fact that the solution of the fractional reaction-diffusion equation, containing this derivative, includes the fundamental solution for space-time fractional diffusion, which itself is a generalization of fractional diffusion, space-time fraction diffusion, and time-fractional diffusion, see Schneider and Wyss ["Fractional diffusion and wave equations," J. Math. Phys. 30, 134-144 (1989)]. These specialized types of diffusion can be interpreted as spatial probability density functions evolving in time and are expressible in terms of the H-function in compact forms. The convergence conditions for the double series occurring in the solutions are investigated. It is interesting to observe that the double series comes out to be a special case of the Srivastava-Daoust hypergeometric function of two variables

A review on mathematical methods of conventional and Islamic derivatives

Science.gov (United States)

Hisham, Azie Farhani Badrol; Jaffar, Maheran Mohd

2014-12-01

Despite the impressive growth of risk management tools in financial institutions, Islamic finance remains miles away behind the conventional institutions. Islamic finance products need to comply with the syariah law and prohibitions, therefore they can use fewer of the available risk management tools compared to conventional. Derivatives have proven to be the effective hedging technique and instrument that broadly being used in the conventional institutions to manage their risks. However, derivatives are not generally accepted as the legitimate products in Islamic finance and they remain controversial issues among the Islamic scholars. This paper reviews the evolution of derivatives such as forwards, futures and options and then explores the mathematical models that being used to solve derivatives such as random walk model, asset pricing model that follows Brownian motion and Black-Scholes model. Other than that, this paper also critically discuss the perspective of derivatives from Islamic point of view. In conclusion, this paper delivers the traditional Islamic products such as salam, urbun and istijrar that can be used to create building blocks of Islamic derivatives.

Platelet-derived growth factor inhibits platelet activation in heparinized whole blood.

Science.gov (United States)

Selheim, F; Holmsen, H; Vassbotn, F S

1999-08-15

We previously have demonstrated that human platelets have functionally active platelet-derived growth factor alpha-receptors. Studies with gel-filtered platelets showed that an autocrine inhibition pathway is transduced through this tyrosine kinase receptor during platelet activation. The physiological significance of this inhibitory effect of platelet-derived growth factor on gel-filtered platelets activation is, however, not known. In the present study, we investigated whether platelet-derived growth factor inhibits platelet activation under more physiological conditions in heparinized whole blood, which represents a more physiological condition than gel-filtered platelets. Using flow cytometric assays, we demonstrate here that platelet-derived growth factor inhibits thrombin-, thrombin receptor agonist peptide SFLLRN-, and collagen-induced platelet aggregation and shedding of platelet-derived microparticles from the platelet plasma membrane during platelet aggregation in stirred heparinized whole blood. The inhibitory effect of platelet-derived growth factor was dose dependent. However, under nonaggregating conditions (no stirring), we could not demonstrate any significant effect of platelet-derived growth factor on thrombin- and thrombin receptor agonist peptide-induced platelet surface expression of P-selectin. Our results demonstrate that platelet-derived growth factor appears to be a true antithrombotic agent only under aggregating conditions in heparinized whole blood.

WEATHER INDEX- THE BASIS OF WEATHER DERIVATIVES

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Botos Horia Mircea

2011-07-01

Full Text Available This paper approaches the subject of Weather Derivatives, more exactly their basic element the weather index. The weather index has two forms, the Heating Degree Day (HDD and the Cooling Degree Day (CDD. We will try to explain their origin, use and the relationship between the two forms of the index. In our research we started from the analysis of the weather derivatives and what they are based on. After finding out about weather index, we were interested in understanding exactly how they work and how they influence the value of the contract. On the national level the research in the field is scares, but foreign materials available. The study for this paper was based firstly on reading about Weather Derivative, and then going in the meteorogical field and determining the way by which the indices were determined. After this, we went to the field with interest in the indices, such as the energy and gas industries, and figured out how they determined the weather index. For the examples we obtained data from the weather index database, and calculated the value for the period. The study is made on a period of five years, in 8 cities of the European Union. The result of this research is that we can now understand better the importance of the way the indices work and how they influence the value of the Weather Derivatives. This research has an implication on the field of insurance, because of the fact that weather derivative are at the convergence point of the stock markets and the insurance market. The originality of the paper comes from the personal touch given to the theoretical aspect and through the analysis of the HDD and CDD index in order to show their general behaviour and relationship.

Structural studies of 4-aminoantipyrine derivatives

Science.gov (United States)

Cunha, Silvio; Oliveira, Shana M.; Rodrigues, Manoel T.; Bastos, Rodrigo M.; Ferrari, Jailton; de Oliveira, Cecília M. A.; Kato, Lucília; Napolitano, Hamilton B.; Vencato, Ivo; Lariucci, Carlito

2005-10-01

Reaction of 4-aminoantipyrine with acetylacetone, ethyl acetoacetate, benzoyl isothiocyanate, phenyl isothiocyanate, maleic anhydride and methoxymethylene Meldrum's acid afforded a series of new antipyrine derivatives. The antibacterial activity of the synthesized compounds against Micrococcus luteus ATCC 9341, Staphilococcus aureus ATCC 29737, and Escherichia coli ATCC 8739 was evaluated and the minimal inhibitory concentration determined. Modest activity was found only to the maleamic acid obtained from the reaction of 4-aminoantipyrine and maleic anhydride. 1H NMR investigation of this maleamic acid showed that it is slowly converted to the corresponding toxic maleimide. The structures of three derivatives were determined by X-ray diffraction analysis.

Urinary Derivations: Radiological Anatomy and Complications

International Nuclear Information System (INIS)

Rodriguez, A.; Escartin, I.; Zapater, C.; Riazuelo, G.; Canon, R.; Solanas, S.; Garcia de Jalon, A.

2003-01-01

Cystectomy with urine derivation is a common procedure in the treatment of transition cell carcinoma of the bladder. We present radiological findings (ultrasound scan, computerized tomography (CT) and urography) from the surgical reconstruction techniques most often performed by the Urology staff of our hospital as well as some of the complications which occur. The above-mentioned techniques are basically divided into two types: incontinent derivations, of which we highlight the Bicker-Wallace technique and continent ones. The latter can either be ortho topic, with urethral anastomosis (Hauptmann's technique), or heterotopic, with urine excretion through the anus (Mains II technique) or employing a self-catheter (Mainz I technique). (Author) 7 refs